Sample records for column design retention

  1. Electrochemically-modulated liquid chromatography (EMLC): Column design, retention processes, and applications

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    Ting, En -Yi [Iowa State Univ., Ames, IA (United States)


    This work describes the continued development of a new separation technique, electrochemically-modulated liquid chromatography (EMLC), from column design, retention mechanisms to pharmaceutical applications. The introduction section provides a literature review of the technique as well as a brief overview of the research in each of the chapters. This section is followed by four chapters which investigate the issues of EMLC column design, the retention mechanism of monosubstituted aromatic compounds, and the EMLC-based applications to two important classes of pharmaceutical compounds (i.e., corticosteroids and benzodiazepines). These four sections have been removed to process separately for inclusion on the database. The dissertation concludes with a general summary, a prospectus, and a list of references cited in the General Introduction. 32 refs.

  2. Retention Models on Core-Shell Columns. (United States)

    Jandera, Pavel; Hájek, Tomáš; Růžičková, Marie


    A thin, active shell layer on core-shell columns provides high efficiency in HPLC at moderately high pressures. We revisited three models of mobile phase effects on retention for core-shell columns in mixed aqueous-organic mobile phases: linear solvent strength and Snyder-Soczewiński two-parameter models and a three-parameter model. For some compounds, two-parameter models show minor deviations from linearity due to neglect of possible minor retention in pure weak solvent, which is compensated for in the three-parameter model, which does not explicitly assume either the adsorption or the partition retention mechanism in normal- or reversed-phase systems. The model retention equation can be formulated as a function of solute retention factors of nonionic compounds in pure organic solvent and in pure water (or aqueous buffer) and of the volume fraction of an either aqueous or organic solvent component in a two-component mobile phase. With core-shell columns, the impervious solid core does not participate in the retention process. Hence, the thermodynamic retention factors, defined as the ratio of the mass of the analyte mass contained in the stationary phase to its mass in the mobile phase in the column, should not include the particle core volume. The values of the thermodynamic factors are lower than the retention factors determined using a convention including the inert core in the stationary phase. However, both conventions produce correct results if consistently used to predict the effects of changing mobile phase composition on retention. We compared three types of core-shell columns with C18-, phenyl-hexyl-, and biphenyl-bonded phases. The core-shell columns with phenyl-hexyl- and biphenyl-bonded ligands provided lower errors in two-parameter model predictions for alkylbenzenes, phenolic acids, and flavonoid compounds in comparison with C18-bonded ligands.


    Energy Technology Data Exchange (ETDEWEB)

    Nelson, E


    The potential use of a peat bed to treat the H-12 Outfall discharge to bring it to new compliance limits was previously investigated and reported utilizing a 7 hour retention time. The influence of retention time (contact time) of water with peat moss on the removal of copper from the water was investigated under laboratory conditions using vertical flow peat moss columns. Reduction of the necessary retention time has a large influence on the design sizing of any peat bed that would be constructed to treat the H-12 discharge on a full scale basis. Retention times of 5 hours, 3 hours and 1 hour were tested to determine the copper removal by the peat columns using vertical flow. Water samples were collected after 4, 8, 12, and 16 water volumes had passed through the columns and analyzed for a suite of metals, with quantitative emphasis on copper. Laboratory results indicated that copper removal was very high at each of the 3 retention times tested, ranging from 99.6 % removal at 5 and 3 hours to 98.8% removal at 1 hour. All these values are much lower that the new compliance limit for the outfall. The results also indicated that most divalent metals were removed to their normal reporting detection limit for the analytical methods used, including zinc. Lead levels in the H-12 discharge used in this study were below PQL in all samples analyzed. While each of the retention times studied removed copper very well, there were indications that 1 hour is probably too short for an operational, long-term facility. At that retention time, there was about 6% compaction of the peat in the column due to the water velocity, and this may affect long term hydraulic conductivity of the peat bed. At that retention time, copper concentration in the effluent was higher than the other times tested, although still very low. Because of the potential compacting and somewhat reduced removal efficiency at a 1 hour retention time, it would be prudent to design to at least a 3 hour retention

  4. Practical design of stepped columns

    NARCIS (Netherlands)

    Girao Coelho, A.M.; Simao, P.D.; Bijlaard, F.S.K.


    This paper deals with buckling aspects of the design of stepped columns in heavy mill buildings. In these structures, columns have to carry significant axial loads that usually act eccentrically and strength reducing bending moments due to lateral loads. A simple physical model for buckling behaviou

  5. Exclusion and retention of compensatory kosmotropes by HPLC columns. (United States)

    Lever, M


    With water as the elution solvent, zwitterionic solutes and polyols were retained on HPLC columns, more than was water, by totally hydrophobic packing materials. Relative retentions were systematically affected by oxygen functional groups in the packing material, explicable as specific retention of water. Reproducible elution sequences of 20 solutes at a variety of hydrophobic surfaces (aromatic and both long- and short-alkyl aliphatic surfaces) showed there is a general process, consistent with interactions with hydration water at the surface having solvent properties distinct from bulk water. Early eluting solutes included glycine, sarcosine and taurine. Glycine betaine followed both these and N,N-dimethylglycine. The natural betaines propionobetaine and dimethylsulfoniopropionate also preceded glycine betaine. Dimethylsulfoxide was strongly retained, as (to a lesser extent) was proline betaine. Polyols eluted in the sequence sorbitol, trehalose, glycerol. Changes in the chemical nature of the surface or base material affected relative retentions of water and solutes. The presence of hydrogen-bonding functions increased retention of polyols, as well as water, relative to zwitterionic solutes. Specific effects retention, constraining models based on the formation of low-density water.

  6. Cross-column prediction of gas-chromatographic retention indices of saturated esters. (United States)

    D'Archivio, Angelo Antonio; Maggi, Maria Anna; Ruggieri, Fabrizio


    We combine computational molecular descriptors and variables related with the gas-chromatographic stationary phase into a comprehensive model able to predict the retention of solutes in external columns. To explore the quality of various approaches based on alternative column descriptors, we analyse the Kováts retention indices (RIs) of 90 saturated esters collected with seven columns of different polarity (SE-30, OV-7, DC-710, OV-25, XE-60, OV-225 and Silar-5CP). Cross-column retention prediction is evaluated on an internal validation set consisting of data of 40 selected esters collected with each of the seven columns, sequentially excluded from calibration. The molecular descriptors are identified by a genetic algorithm variable selection method applied to a large set of non-empirical structural quantities aimed at finding the best multi-linear quantitative structure-retention relationship (QSRR) for the column OV-25 having intermediate polarity. To describe the columns, we consider the sum of the first five McReynolds phase constants and, alternatively, the coefficients of the corresponding QSRRs. Moreover, the mean RI value for the subset of esters used in QSRR calibration or RIs of a few selected compounds are used as column descriptors. For each combination of solute and column descriptors, the retention model is generated both by multi-linear regression and artificial neural network regression. Copyright © 2014 Elsevier B.V. All rights reserved.

  7. Leaching and retention of dissolved metals in particulate loaded pervious concrete columns. (United States)

    Vadas, Timothy M; Smith, Malcolm; Luan, Hongwei


    This study examined metal leaching and retention in pervious concrete with or without embedded particulate matter. Particulate matter was collected from an adjacent parking lot and from a nearby parking garage as examples of weathered and un-weathered particulate matter. Particle size distributions were similar, but metal content was 3-35-fold higher and organic matter content was 3-fold higher in the parking garage particulate matter compared to the parking lot particulate matter. Replicate columns were established with either no particulate added as the control, or 20 g of parking lot or parking garage particulate matter. Synthetic rainwater was passed through the columns at variable rainfall intensity or fixed intensity to assess leaching. Metals were leached at higher concentrations from the parking garage particulate amended column, but from all columns less than 1% of the metal mass leached. Rainfall intensity did not have a large effect on leached metal concentrations, only varying effluent by about 2-fold. Synthetic stormwater with elevated dissolved Cu, Zn, Cd and Pb concentrations was passed through the same columns and metal removal efficiencies were on the order of 85-95%, 30-95%, 60-90%, and 95+% for each metal, respectively. After loading the column with a year's worth of stormwater metal exposure, removal efficiencies in the no particulate and parking lot particulate amended columns decreased, while parking garage particulate amended columns performed similarly with a small drop in Cu and Pb removal efficiencies. Generally, columns with no particulate and parking lot particulate amendments performed similarly, suggesting the pervious concrete is responsible for the majority of the initial metal retention. The parking garage particulate amended columns retained more metals from stormwater, perhaps due to an increase in pH that promoted surface precipitation as hydroxides or carbonate species on the pervious concrete, or due to complexation in the

  8. From Single Droplet to Column Design

    Institute of Scientific and Technical Information of China (English)


    The technique state to design counter-current extraction columns is based on the performance of pilot plant experiments. The modelling is then either with the equilibrium or dispersion model, whereas in the latter the dispersion coefficient accounts for all hydrodynamic non-idealities. A new approach uses single droplet experiments to obtain the basic laws and functions governing droplet breakage, coalescence,relative velocity, and axial dispersion when using droplet populance balance models (DPBM). The hydrodynamics simulation results show that the mean Sauter diameter, hold-up, and concentration profiles could be well predicted, which promotes the use of DPBM models for further applications in industrial scale.

  9. Refreshment topics II: Design of distillation columns

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    Milojević Svetomir


    Full Text Available For distillation column design it is necessary to define all the variable parameters such as component concentrations in different streams temperatures, pressures, mass and energy flow, which are used to represent the separation process of some specific system. They are related to each other according to specific laws, and if the number of such parameters exceeds the number of their relationships, in order to solve a problem some of them must be specified in advance or some constraints assumed for the mass balance, the balance of energy, phase equilibria or chemical equilibria. Knowledge of specific elements which are the constituents of a distillation unit must be known to define the number of design parameters as well as some additional apparati also necessary to realize the distilation. Each separate apparatus might be designed and constructed only if all the necessary and variable parameters for such a unit are defined. This is the right route to solve a distilation unit in many different cases. The construction of some distillation unit requires very good knowledge of mass, heat and momentum transfer phenomena. Moreover, the designer needs to know which kind of apparatus will be used in the distillation unit to realize a specific production process. The most complicated apparatus in a rectification unit is the distillation column. Depending on the complexity of the separation process one, two or more columns are often used. Additional equipment are heat exchangers (reboilers, condensers, cooling systems, heaters, separators, tanks for reflux distribution, tanks and pumps for feed transportation, etc. Such equipment is connected by pipes and valves, and for the normal operation of a distillation unit other instruments for measuring the flow rate, temperature and pressure are also required. Problems which might arise during the determination and selection of such apparati and their number requires knowledge of the specific systems which must

  10. Study on the Retention Behavior of Aromatic Carboxylic and Sulfonic acid on a New Anion Exchange Column

    Institute of Scientific and Technical Information of China (English)

    SHI,Ya-Li; CAI,Ya-Qi; MOU,Shi-Fen


    Ion chromatography (IC) has gradually developed into a preferred method for the determination of inorganic anions. And in recent years some low molecular aliphatic acid can be also separated in the ion exchange column with the development of stationary phase. But for the determination of aromatic ionic compounds there are some problems. The aromatic anions show enhanced retention due to interaction with the π electrons of the aromatic backbone. Although the addition of an organic modifier can alleviate the difficulty, it is not the ultimate solution.IonPac AS20 column was developed using a unique polymer bonding technology and its substrate coating is aliphatic backbone. The polymer is completely free of any π electron-containing substituents in the AS20 column. In this paper, the retention behavior of aromatic carboxylic and sulfonic acid on two hydroxide-selective columns,IonPac AS11-HC, AS16, and the new column AS20 was also studied. The result showed that the retentions of ten compounds on three columns were different with each other because of their different column characteristics.Among them 4-chlorobenzene sulfonic acid, 3,5-dihydric benzoic acid and salicylic acid obviously exhibited the weakest retention on the IonPac AS20. It was showed that π-π bond function between anion and stationary phases was weakened in AS20 column because its polymer was completely free of any π electron-containing substituents.So in this paper the AS20 was selected as an analytical column to separate ten aromatic ionic compounds, fumaric acid with conjugate bond included. The retention behavior, separation of the ten compounds and effect of temperature on their retention in the anion-exchange column AS20 (2 mm) were studied. The result showed that those compounds could be separated with each other when running in gradient program and the organic modifier was unnecessary during the separation. So it is showed that AS20 column can be used as a separating column because its

  11. Evaluations of Mechanisms for Pu Uptake and Retention within Spherical Resorcinol-Formaldehyde Resin Columns

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    Delegard, Calvin H. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Levitskaia, Tatiana G. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fiskum, Sandra K. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)


    The unexpected uptake and retention of plutonium (Pu) onto columns containing spherical resorcinol-formaldehyde (sRF) resin during ion exchange testing of Cs (Cs) removal from alkaline tank waste was observed in experiments at both the Pacific Northwest National Laboratory (PNNL) and the Savannah River National Laboratory (SRNL). These observations have raised concern regarding the criticality safety of the Cs removal unit operation within the low-activity waste pretreatment system (LAWPS). Accordingly, studies have been initiated at Washington River Protection Solutions (WRPS), who manages the operations of the Hanford Site tank farms, including the LAWPS, PNNL, and elsewhere to investigate these findings. As part of these efforts, PNNL has prepared the present report to summarize the laboratory testing observations, evaluate these phenomena in light of published and unpublished technical information, and outline future laboratory testing, as deemed appropriate based on the literature studies, with the goal to elucidate the mechanisms for the observed Pu uptake and retention.

  12. Bacteria transport and retention in intact calcareous soil columns under saturated flow conditions

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    Farrokhian Firouzi Ahmad


    Full Text Available Study of bacterial transport and retention in soil is important for various environmental applications such as groundwater contamination and bioremediation of soil and water. The main objective of this research was to quantitatively assess bacterial transport and deposition under saturated conditions in calcareous soil. A series of leaching experiments was conducted on two undisturbed soil columns. Breakthrough curves of Pseudomonas fluorescens and Cl were measured. After the leaching experiment, spatial distribution of bacteria retention in the soil columns was determined. The HYDRUS-1D one- and two-site kinetic models were used to predict the transport and deposition of bacteria in soil. The results indicated that the two-site model fits the observed data better than one-site kinetic model. Bacteria interaction with the soil of kinetic site 1 revealed relatively fast attachment and slow detachment, whereas attachment to and detachment of bacteria from kinetic site 2 was fast. Fast attachment and slow detachment of site 1 can be attributed to soil calcium carbonate that has favorable attachment sites for bacteria. The detachment rate was less than 0.02 of the attachment rate, indicating irreversible attachment of bacteria. High reduction rate of bacteria was also attributed to soil calcium carbonate.

  13. Suspension column for recovery and separation of substances using ultrasound-assisted retention of bead sorbents. (United States)

    Spivakov, Boris Ya; Shkinev, Valeriy M; Danilova, Tatiana V; Knyazkov, Nikolai N; Kurochkin, Vladimir E; Karandashev, Vasiliy K


    A novel approach to sorption recovery and separation of different substances is proposed which is based on the use of suspended bead sorbents instead of conventional packed beds of such sorbents. This makes it possible to employ small-sized beads which are trapped in a low-pressure column due to ultrasound-assisted retention, without any frits to hold the sorption material. A flow system including a separation mini-column, named herein a suspension column, has been developed and tested by the studies of solid phase extraction (SPE) of trace metals from bi-distilled water and sea water using a 150-μL column with a silica-based sorbent containing iminodiacetic groups (DIAPAK IDA) and having a grain size of 6 μm. The adsorption properties of DIAPAK IDA suspension (9.5mg) were evaluated through adsorption/desorption experiments, where the effect of solution pH and eluent on the SPE of trace metals were examined by ICP-MS or ICP-AES measurements. When sample solution was adjusted to pH 8.0 and 1 mol L(-1) nitric acid was used as eluent, very good recoveries of more than 90% were obtained for a number of elements in a single-step extraction. To demonstrate the versatility of the approach proposed and to show another advantage of ultrasonic field (acceleration of sorbate/sorbent interaction), a similar system was used for heterogeneous immunoassays of some antigens in ultrasonic field using agarose sorbents modified by corresponding antibodies. It has been shown that immunoglobulins, chlamidia, and brucellos bacteria can be quantitatively adsorbed on 15-μm sorbent (15 particles in 50 μL) and directly determined in a 50-μL mini-chamber using fluorescence detection.

  14. The temperature dependence of the retention index for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns

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    Full Text Available The temperature dependence of the retention index was studied for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns. The study was performed over various temperature ranges depending on the volatility of the ester. Two linear equations of the temperature dependence of the retention data on the column temperature and its reciprocal as variables were studied. Agood linearity of the retention index versus column temperature was found.

  15. Designing Online Courses to Promote Student Retention (United States)

    Dietz-Uhler, Beth; Fisher, Amy; Han, Andrea


    Although the issue of student retention is a campus-wide one, it is of special interest in online distance learning courses, where retention rates are reported to be lower than in face-to-face classes. Among the explanations and theories of retention rates in online courses, one that struck us as most useful is a structural one, namely, course…

  16. Alignment of retention time obtained from multicapillary column gas chromatography used for VOC analysis with ion mobility spectrometry. (United States)

    Perl, Thorsten; Bödeker, Bertram; Jünger, Melanie; Nolte, Jürgen; Vautz, Wolfgang


    Multicapillary column (MCC) ion mobility spectrometers (IMS) are increasingly in demand for medical diagnosis, biological applications and process control. In a MCC-IMS, volatile compounds are differentiated by specific retention time and ion mobility when rapid preseparation techniques are applied, e.g. for the analysis of complex and humid samples. Therefore, high accuracy in the determination of both parameters is required for reliable identification of the signals. The retention time in the MCC is the subject of the present investigation because, for such columns, small deviations in temperature and flow velocity may cause significant changes in retention time. Therefore, a universal correction procedure would be a helpful tool to increase the accuracy of the data obtained from a gas-chromatographic preseparation. Although the effect of the carrier gas flow velocity and temperature on retention time is not linear, it could be demonstrated that a linear alignment can compensate for the changes in retention time due to common minor deviations of both the carrier gas flow velocity and the column temperature around the MCC-IMS standard operation conditions. Therefore, an effective linear alignment procedure for the correction of those deviations has been developed from the analyses of defined gas mixtures under various experimental conditions. This procedure was then applied to data sets generated from real breath analyses obtained in clinical studies using different instruments at different measuring sites for validation. The variation in the retention time of known signals, especially for compounds with higher retention times, was significantly improved. The alignment of the retention time--an indispensable procedure to achieve a more precise identification of analytes--using the proposed method reduces the random error caused by small accidental deviations in column temperature and flow velocity significantly.

  17. Evaluation of the retention pattern on ionic liquid columns for gas chromatographic analyses of fatty acid methyl esters. (United States)

    Lin, Chen-Chen; Wasta, Ziar; Mjøs, Svein A


    Fatty acid methyl esters from marine sources were analyzed by gas chromatography-mass spectrometry on three ionic liquid columns, SLB-IL61, SLB-IL82 and SLB-IL100 (Supelco). Retention indices (equivalent chain lengths) are reported for more than 100 compounds and the overlap patterns are evaluated from these data. The influence of chromatographic conditions on the retention indices of unsaturated fatty acid methyl esters is also evaluated. Compared to typical alternative phases the retention patterns on all three columns are highly dependent on the conditions. The SLB-IL61 phase had overlaps between nutritionally important fatty acids that could not be resolved by changing the chromatographic conditions. This column is therefore regarded as unsuitable for clinical and nutritional studies of the fatty acid composition, but similar overlaps may be avoided on IL82 and IL100. On all three columns double bonds close to the carboxyl group in the analytes contribute with limited retention, which makes it challenging to predict the retention of polyunsaturated fatty acid methyl esters.

  18. 207-A retention basins system design description

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    Wahlquist, R.A.


    The 242-A Evaporator is a waste treatment facility designed to reduce liquid waste volumes currently stored in the Hanford Area double shell Waste Storage Tanks. The evaporator uses evaporative concentration to achieve this volume reduction, returning the concentrated slurry to the double-shell tanks for storage. The process effluent is transferred to various retention/treatment facilities for eventual release to the environment. The process utilizes an evaporator vessel and various supporting systems for heating, evaporating, and condensing low-heat-generating liquid waste produced it the Hanford Site. The process reduces the total volume of the liquid waste requiring storage in a double shell tank, making it more manageable for current storage as well as for future treatment and disposal. The main components of the 242-A Evaporator are the Reboiler, Vapor-Liquid Separator, Recirculation Pump and Pump Loop, Slurry System, Condenser System, Steam Jet Vacuum System, Condensate Collection Tank, and Ion Exchange System.

  19. Transport and retention of TiO2 and polystyrene nanoparticles during drainage from tall heterogeneous layered columns (United States)

    Hoggan, James L.; Sabatini, David A.; Kibbey, Tohren C. G.


    Recent developments in nanotechnology have seen an increase in the use of manufactured nanomaterials. Although their unique physicochemical properties are desirable for many products and applications, concern continues to exist about their environmental fate and potential to cause risk to human and ecological health. The purpose of this work was to examine one aspect of nanomaterial environmental fate: transport and retention in the unsaturated zone during drainage. The work made use of tall segmented columns packed with layers of two different porous media, one medium sand and one fine sand. The use of tall columns allowed drainage experiments to be conducted where the water table remained within the height of the column, permitting control of final saturation profiles without the need for capillary barrier membranes which can potentially complicate analyses. Experiments were conducted with titanium dioxide (TiO2) and polystyrene nanomaterials. For the strongly negatively-charged polystyrene nanomaterials, little retention was observed under the conditions studied. For the TiO2 nanomaterials, results of the work suggest that while saturated fine sand layers may retain more nanomaterials than saturated coarse sand layers, significantly greater retention is possible in unsaturated media. Furthermore, unsaturated medium sand layers exhibited significantly greater retention than adjacent saturated fine sand layers when present at low saturations high above the water table. Retention by unsaturated media were found to correlate strongly with elevation. Free drainage experiments including both primary and secondary drainages in homogeneous columns showed evidence of redistribution during imbibition and secondary drainage, but still showed substantial unsaturated retention of TiO2 nanoparticles high in the column, despite re-saturation with- and drainage of nanoparticle-free water.

  20. Design, testing, and simulation of microscale gas chromatography columns

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    Hudson, M.L.; Kottenstette, R.; Matzke, C.M.; Frye-Mason, G.C.; Shollenberger, K.A.; Adkins, D.R.; Wong, C.C.


    A microscale gas chromatography column is one component in a microscale chemistry laboratory for detecting chemical agents. Several columns were fabricated using the Bosch etch process which allows deep, high aspect ratio channels of rectangular cross-section. A design tool, based on analytical models, was developed to evaluate the effects of operating conditions and column specifications on separation resolution and time. The effects of slip flow, channel configuration, and cross-sectional shape were included to evaluate the differences between conventional round, straight columns and the microscale rectangular, spiral columns. Experimental data were obtained and compared with the predicted flowrates and theoretical number of plates. The design tool was then employed to select more optimum channel dimensions and operating conditions for high resolution separations.

  1. Enhanced retention of linuron, alachlor and metalaxyl in sandy soil columns intercalated with wood barriers. (United States)

    Rodríguez-Cruz, M S; Ordax, J M; Arienzo, M; Sánchez-Martín, M J


    A study has been made of the effect a reactive barrier made of pine (softwood) or oak (hardwood) wood intercalated in a sandy soil column has on the retention of linuron, alachlor and metalaxyl (pesticides with contrasting physicochemical characteristics). The leaching of pesticides has been carried out under a saturated flow regime and breakthrough curves (BTCs) have been obtained at flow rates of 1 m Lmin(-1) (all pesticides) and 3 m Lmin(-1) (linuron). The cumulative curves in the unmodified soil indicate a leaching of pesticides >80% of the total amount of compound added. After barrier intercalation, linuron leaching decreases significantly and a modification of the leaching kinetics of alachlor and metalaxyl has been observed. The theoretical R factors increased ∼2.6-3.3, 1.2-1.6-fold, and 1.4-1.7-fold and the concentration of the maximum peak decreased ∼6-12-fold, 2-4-fold and 1.2-2-fold for linuron, alachlor and metalaxyl, respectively. When considering the three pesticides, significant correlations have been found between the theoretical retardation factor (R) and the pore volume corresponding to the maximum peaks of the BTCs (r=0.77; pmetalaxyl. Copyright © 2010 Elsevier Ltd. All rights reserved.

  2. Retention in treated wastewater affects survival and deposition of Staphylococcus aureus and Escherichia coli in sand columns. (United States)

    Li, Jiuyi; Zhao, Xiaokang; Tian, Xiujun; Li, Jin; Sjollema, Jelmer; Wang, Aimin


    The fate and transport of pathogenic bacteria from wastewater treatment facilities in the Earth's subsurface have attracted extensive concern over recent decades, while the impact of treated-wastewater chemistry on bacterial viability and transport behavior remains unclear. The influence of retention time in effluent from a full-scale municipal wastewater treatment plant on the survival and deposition of Staphylococcus aureus and Escherichia coli strains in sand columns was investigated in this paper. In comparison to the bacteria cultivated in nutrient-rich growth media, retention in treated wastewater significantly reduced the viability of all strains. Bacterial surface properties, e.g., zeta potential, hydrophobicity, and surface charges, varied dramatically in treated wastewater, though no universal trend was found for different strains. Retention in treated wastewater effluent resulted in changes in bacterial deposition in sand columns. Longer retention periods in treated wastewater decreased bacterial deposition rates for the strains evaluated and elevated the transport potential in sand columns. We suggest that the wastewater quality should be taken into account in estimating the fate of pathogenic bacteria discharged from wastewater treatment facilities and the risks they pose in the aquatic environment.


    Directory of Open Access Journals (Sweden)

    Belokur K. A.


    Full Text Available Original screw designs of buildings and columns are offered. Frameworks of these buildings and columns are the bearing elements and means of external and internal decoration of buildings and constructions. Originality of such buildings and columns frameworks is ensured by the fact that their design is decorated on the outer surface with broken or smooth screw edges and screw surfaces. Versatility of the offered screw columns trunks designs, as well as the possibility of performance of their left or right screwing allows reaching certain symmetry or their repeatability in the form of harmonious alternation of the bearing trunks of screw columns and spaces between them. Giving to numerous sides of trunks of screw columns of a certain invoice, or their coloring in different colors, will contribute even more to their expressiveness and beauty. Durability and vibration resistance (including seismic of such trunks of screw columns at the same volumes of construction materials, in comparison with round and rectangular trunks is higher

  4. System maps for retention of small neutral compounds on a superficially porous particle column in reversed-phase liquid chromatography. (United States)

    Atapattu, Sanka N; Poole, Colin F; Praseuth, Mike B


    The system constants of the solvation parameter model are used to prepare system maps for the retention of small neutral molecules on the ocadecylsiloxane-bonded silica superficially porous particle stationary phase (Kinetex C18) for aqueous-organic solvent mobile phases containing 10-70% (v/v) methanol or acetonitrile. A comparison of the system constants with eight commercially available octadecylsiloxane-bonded silica columns for the same separation conditions confirms that the general retention properties of Kinetex C-18 are similar to totally porous octadecylsiloxane-bonded silica stationary phases and that method transfer should be no more difficult than that usually observed when substituting one octadecylsiloxane-bonded silica column for another.

  5. Novel design for centrifugal counter-current chromatography: VI. Ellipsoid column. (United States)

    Gu, Dongyu; Yang, Yi; Xin, Xuelei; Aisa, Haji Akber; Ito, Yoichiro


    A novel ellipsoid column was designed for centrifugal counter-current chromatography. Performance of the ellipsoid column with a capacity of 3.4 mL was examined with three different solvent systems composed of 1-butanol-acetic acid-water (4:1:5, v/v) (BAW), hexane-ethyl acetate-methanol-0.1 M HCl (1:1:1:1, v/v) (HEMH), and 12.5% (w/w) PEG1000 and 12.5% (w/w) dibasic potassium phosphate in water (PEG-DPP) each with suitable test samples. In dipeptide separation with BAW system, both stationary phase retention (Sf) and peak resolution (Rs) of the ellipsoid column were much higher at 0° column angle (column axis parallel to the centrifugal force) than at 90° column angle (column axis perpendicular to the centrifugal force), where elution with the lower phase at a low flow rate produced the best separation yielding Rs at 2.02 with 27.8% Sf at a flow rate of 0.07 ml/min. In the DNP-amino acid separation with HEMW system, the best results were obtained at a flow rate of 0.05 ml/min with 31.6% Sf yielding high Rs values at 2.16 between DNP-DL-glu and DNP-β-ala peaks and 1.81 between DNP-β-ala and DNP-L-ala peaks. In protein separation with PEG-DPP system, lysozyme and myolobin were resolved at Rs of 1.08 at a flow rate of 0.03 ml/min with 38.9% Sf. Most of those Rs values exceed those obtained from the figure-8 column under similar experimental conditions previously reported.

  6. Design of Earthquake Resistant Bridges Using Rocking Columns


    Barthes, Clement Benjamin


    The California Department of Transportation (CalTrans) is urging researchers and contractors to develop the next generation highway bridge design. New design solutions should favor the use of modular construction techniques over conventional cast-in-place reinforced concrete in order to reduce the cost of the projects and the amount of constructions on site. Earthquake resistant bridges are designed such that the columns are monolithically connected to the girder and the foundations. Hence, d...

  7. Effect of phase ratio and column type on retention in SFC (supercritical fluid chromatography)

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    Yonker, C.R.; Smith, R.D.


    Extensive discussion continues regarding the relative merits of capillary and packed columns for supercritical fluid chromatography (SFC). Columns of interest typically include commercially available i.d. capillaries having an /approximately/ film thickness and packed columns containing or diameter developed for HPLC. It has been demonstrated that packed columns can offer advantages in terms of speed because the properties of fluids high linear velocities to be utilized, but the lower pressure drop with open tubular capillary columns allows a greater number of effective theoretical plates through the use of longer columns. Much discussion has centered about the comparison of columns under various operating conditions of practical interest (e.g., pressure programming for capillaries or isobaric operation for packed columns). It is the purpose of this report to show the importance of column phase ratio (i.e., the ratio of stationary to mobile phase volumes. V/sub s/ and V/sub m/, respectively in the selection of columns for specific SFC applications.

  8. Methanol Distillation System: Process Analysis and Column Design

    Institute of Scientific and Technical Information of China (English)

    Sun Jinsheng; Tian Yufeng; Xu Shimin; Ding Hui; Wang Tao; Li Xingang; Zheng Yanmei


    Base on industrial research and experience, the process of methanol distillation is analyzed,and above all, a new concept of high pressure flowsheet and low pressure flowsheet is defined. The new configuration helps to handle problems encountered in many factories in China. The inter influence between process and column internal pattern is also pointed out. Recommendation of new column internal designs is given. Finally, industrial examples tell the how the new concept works and the possibility of combining process to give more opens to solve engineering problems.

  9. Combined column-mobile phase mixture statistical design optimization of high-performance liquid chromatographic analysis of multicomponent systems. (United States)

    Breitkreitz, Márcia C; Jardim, Isabel C S F; Bruns, Roy E


    A statistical approach for the simultaneous optimization of the mobile and stationary phases used in reversed-phase liquid chromatography is presented. Mixture designs using aqueous mixtures of acetonitrile (ACN), methanol (MeOH) and tetrahydrofuran (THF) organic modifiers were performed simultaneously with column type optimization, according to a split-plot design, to achieve the best separation of compounds in two sample sets: one containing 10 neutral compounds with similar retention factors and another containing 11 pesticides. Combined models were obtained by multiplying a linear model for column type, C8 or C18, by quadratic or special cubic mixture models. Instead of using an objective response function, combined models were built for elementary chromatographic criteria (retention factors, resolution and relative retention) of each solute or pair of solutes and, after their validation, the global separation was accomplished by means of Derringer's desirability functions. For neutral compounds a 37:12:8:43 (v/v/v/v) percentage mixture of ACN:MeOH:THF:H2O with the C18 column and for pesticides a 15:15:70 (v/v/v) ACN:THF:H2O mixture with the C8 column provide excellent resolution of all peaks.

  10. Retention of pesticides in sandy soil columns modified with a wood barrier

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez-Martin, M. J.; Rodriguez-Cruz, M. S.; Ordax, J. M.; Arienzo, M.


    Wood residues can be used as low-cost potential sorbents of hydrophobic pesticides in technologies aimed to prevent soil and water contamination and reduce the risk of environmental pollution produced by point pollution sources of these compounds. The objective of this work was to study the effect of a pine or oak sawdust barrier on the retention of Iinuron, alachlor and metalaxyl, with different hydrophobic character, in a sandy soil. (Author)

  11. Three-dimensional topographic index applied to the prediction of acyclic C5-C8 alkenes Kováts retention indices on polydimethylsiloxane and squalane columns. (United States)

    Ren, Yueying; Liu, Huanxiang; Yao, Xiaojun; Liu, Mancang


    A novel approach is described for the prediction of gas chromatographic Kováts retention indices of 150 acyclic C5-C8 alkenes on two stationary phases (polydimethylsiloxane, PDMS, and squalane, SQ). The heuristic method was used to build multiple linear regression models using descriptors calculated by MODLESLAB software and CODESSA program. The resulting quantitative structure-retention relationship (QSRR) models were well-correlated, with predictive R2 values of 0.970 and 0.958 for retention indices on PDMS and SQ columns, respectively. 1Omegap, a three-dimensional (3D) topographic index, was found to play the most important role in the description of the chromatographic retention behavior of the alkenes in these two stationary phases. Moreover, this index could completely distinguish different isomers of alkene. Therefore, it can also be extended to distinguish different isomers of other compounds so that can well describe their quantitative structure-retention relationships.

  12. CFD based extraction column design-Chances and challenges

    Institute of Scientific and Technical Information of China (English)

    Mark W Hlawitschka; Menwer M Attarakih; Samer S Alzyod; Hans-Jrg Bart


    This paper shows that one-dimensional (1-D) [and three-dimensional (3-D) computational fluid dynamics (CFD)] simulations can replace the state-of-the-art usage of pseudo-homogeneous dispersion or back mixing models. This is based on standardized lab-scale cel experiments for the determination of droplet rise, breakage, coalescence and mass transfer parameters in addition to a limited number of additional mini-plant experiments with original fluids. Alternatively, the hydrodynamic parameters can also be derived using more sophisticated 3-D CFD simulations. Computational 1-D modeling served as a basis to replace pilot-plant experiments in any column geometry. The combination of 3-D CFD simulations with droplet population balance models (DPBM) increased the accuracy of the hydrodynamic simulations and gave information about the local droplet size. The high computational costs can be reduced by open source CFD codes when using a flexible mesh generation. First combined simulations using a three way coupled CFD/DPBM/mass-transfer solver pave the way for a safer design of industrial-sized columns, where no correlations are available.

  13. Description of the Retention and Peak Profile for Chromolith Columns in Isocratic and Gradient Elution Using Mobile Phase Composition and Flow Rate as Factors

    Directory of Open Access Journals (Sweden)

    Elsa Cabo-Calvet


    Full Text Available The effect of the modifier concentration and flow rate on the chromatographic performance of a second generation Chromolith® RP-18e column, under isocratic and gradient elution with acetonitrile-water mixtures, was examined using four sulphonamides as probe compounds. The acetonitrile concentration was varied between 5 and 55% (v/v, and the flow rate between 0.1 and 5.0 mL/min, keeping the other factors constant. The changes in both retention and peak profile were modelled, and used to build simple plots, where the logarithm of the retention factor was represented against the modifier concentration (in gradient elution, against the initial modifier concentration, and the half-widths or widths against the retention time (in gradient elution, against the time at the column outlet. A particular plot was needed for describing the retention of each sulphonamide, but due to the similar interaction kinetics, a unique plot described the changes in the half-widths for all four sulphonamides. The changes in retention with the flow showed that allegedly in the second generation Chromolith, the column deformation observed for the first generation Chromolith, with the applied pressure at increasing flow, is decreased.

  14. Correlation of retention times on liquid crystal capillary column with reported vapor pressures and half-lives of compounds used in pheromone formulations. (United States)

    Heath, R R; Tumlinson, J H


    A method has been developed to determine by capillary gas chromatography on liquid crystal stationary phases the relative vapor pressures and half-lives of many compounds used as insect pheromones. This study demonstrated that the retention time of seven acetates on a liquid crystal column (cholesteryl-p-chlorocinnamate) could be correlated closely to the reported vapor pressures of the compounds. For 13 additional pheromonal acetates and alcohols, reported half-lives showed a high degree of correlation with their retention times on the liquid crystal column. Thus chromatography on capillary liquid crystal gas Chromatographie columns appears to be a useful method for determining the relative volatilities of many pheromones to facilitate the development of more precise formulations.


    Directory of Open Access Journals (Sweden)

    L. K. Omray


    Full Text Available Gastro retentive drug delivery system of diltiazem hydrochloride was designed and evaluated for its effectiveness for the management of mild to moderate hypertension. Gastro retentive drug delivery system were prepared using polyvinyl alcohol and sodium carboxy methyl cellulose as the polymers and sodium bicarbonate as a gas generating agent for the reduction of floating lag time. Gastro retentive drug delivery system tablets were prepared by wet granulation method by compression in tablet compression machine. Formulations DL1, DL2, DL3, DL4 and DL5 were developed which differed in the ratio of polyvinyl alcohol and sodium carboxy methyl cellulose polymers. All the formulations were evaluated for hardness, weight variation, friability, drug content, swelling index, buoyancy studies and in vitro drug release study. In vitro drug release study was performed using United State Pharmacopoeia 23 type 2 dissolution test apparatus employing paddle stirrer at 50 r/pm. Dissolution medium was 900 ml of 0.1N hydrochloric acid at 37ºC ± 3ºC. Formulations DL3 was found to be better as compared to other formulation.

  16. [Influences of the mobile phase constitution, salt concentration and pH value on retention characters of proteins on the metal chelate column]. (United States)

    Li, R; Di, Z M; Chen, G L


    The effects of the nature and concentration of salts, pH value and competitive eluent in the mobile phase on the protein retention have been systematically investigated. A mathematical expression describing the protein retention in metal chelate chromatography has been derived. It is proposed that the eluting power of the salt solution can be expressed by the eluent strength exponent epsilon. According to the retention characters of protein under different chromatographic conditions, the interaction between the various metal chelate ligands and proteins is discussed. The protein retention on the metal chelate column is a cooperative interactions of coordination, electrostatic and hydrophobic interaction. For the strong combined metal column with proteins such as IDA-Cu, the coordination is the most important, and the electrostatic interaction is secondary in chromatographic process. However, for the weak combined metal columns with proteins such as IDA-Ni, IDA-Co and IDA-Zn, the electrostatic interaction between the metal chelate ligands and proteins is the chief one, while the coordination is the next in importance. When the mobile phase contains high concentration of salt which can't form complex with the immobilized metal, the hydrophobic interaction between the protein and stationary phase will be increased. As the interaction between the metal chelate ligand and proteins relates to chromatographic operating conditions closely, different elution processes may be selected for different metal chelate columns. The gradient elution is generally performed by the low concentration of salt or different pH for weakly combined columns with proteins, however the competitive elution procedure is commonly utilized for strongly combined column. The experiment showed that NH3 is an excellent competitive eluent. It isn't only give the efficient separation of proteins, but also has the advantages of cheapness, less bleeding of the immobilized metals and ease of controlling NH3

  17. Tools for Reactive Distillation Column Design: Graphical and Stage-to-Stage Computation Methods

    DEFF Research Database (Denmark)

    Sanchez Daza, O.; Cisneros, Eduardo Salvador P.; Hostrup, Martin


    Based on the element mass balance concept, a graphical design method and a stage-to-stage multicomponent design method for reactive distillation columns have been developed. For distillation columns comprising reactive and non-reactive stages, a simple design strategy based on reactive and non......-reactive bubble point calculations is proposed. This strategy tracks the conversion and temperature between the feed and the end stages of the column. An illustrative example highlights the verification of the design strategy through rigorous simulation....

  18. Mini-columns for Conducting Breakthrough Experiments. Design and Construction

    Energy Technology Data Exchange (ETDEWEB)

    Dittrich, Timothy M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Reimus, Paul William [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Ware, Stuart Douglas [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    Experiments with moderately and strongly sorbing radionuclides (i.e., U, Cs, Am) have shown that sorption between experimental solutions and traditional column materials must be accounted for to accurately determine stationary phase or porous media sorption properties (i.e., sorption site density, sorption site reaction rate coefficients, and partition coefficients or Kd values). This report details the materials and construction of mini-columns for use in breakthrough columns to allow for accurate measurement and modeling of sorption parameters. Material selection, construction techniques, wet packing of columns, tubing connections, and lessons learned are addressed.

  19. design chart procedures for polygonal concrete-filled steel columns ...

    African Journals Online (AJOL)


    hexagonal and octagonal steel-concrete composite columns subjected to uniaxial bending. Comparative ... cold-formed and welded sections are generally avoided in .... selected for drawing the chart as this range utilizes comparatively less ...


    Directory of Open Access Journals (Sweden)



    Full Text Available Most of the real systems exhibit non-linear nature; conventional controllers are not always able to provide good and acceptable results. This paper presents a hybrid control strategy of Model Predictive Control (MPC and Fuzzy Logic Control (FLC. The Fuzzy Model Predictive Control (FMPC approach is developed to control various distillation column models. The performance measures like settling time, peak overshoot, Integral Square Error (ISE and Integral Absolute Error (IAE of FMPC is validated with MPC, FLC and conventional multi loop PI controller. The simulation results shows that the FMPC has better performance than other controller on various distillation column models.

  1. A straightforward methodology for designing continuous monoclonal antibody capture multi-column chromatography processes. (United States)

    Gjoka, Xhorxhi; Rogler, Karl; Martino, Richard Alexander; Gantier, Rene; Schofield, Mark


    A simple process development strategy for continuous capture multi-column chromatography (MCC) is described. The approach involves a few single column breakthrough experiments, based on several simplifying observations that enable users to rapidly convert batch processes into well-designed multi-column processes. The method was validated using a BioSMB(®) (Pall Life Sciences) lab scale multi-column system and a mAb capture process employing Protein A resin. The approach enables users to optimize MCC processes based on their internal preferences and constraints without requiring any mathematical modeling expertise.

  2. A Shortcut Design for Kaibel Columns Based on Minimum Energy Diagrams


    Ghadrdan, Maryam; Halvorsen, Ivar Johan; Skogestad, Sigurd


    In this paper, a shortcut procedure is proposed to design a 4-product dividing-wall column. It is based on the information derived from Vmin diagram. This has the advantage of having more meaningful guesses for energy requirements and impurity flows in the column. An example is used for illustration.

  3. Improved micromachined column design and fluidic interconnects for programmed high-temperature gas chromatography separations. (United States)

    Gaddes, David; Westland, Jessica; Dorman, Frank L; Tadigadapa, Srinivas


    This work focuses on the development and experimental evaluation of micromachined chromatographic columns for use in a commercial gas chromatography (GC) system. A vespel/graphite ferrule based compression sealing technique is presented using which leak-proof fluidic interconnection between the inlet tubing and the microchannel was achieved. This sealing technique enabled separation at temperatures up to 350°C on a μGC column. This paper reports the first high-temperature separations in microfabricated chromatographic columns at these temperatures. A 2m microfabricated column using a double Archimedean spiral design with a square cross-section of 100μm×100μm has been developed using silicon microfabrication techniques. The microfabricated column was benchmarked against a 2m 100μm diameter commercial column and the performance between the two columns was evaluated in tests performed under identical conditions. High temperature separations of simulated distillation (ASTM2887) and polycyclic aromatic hydrocarbons (EPA8310) were performed using the μGC column in temperature programmed mode. The demonstrated μGC column along with the high temperature fixture offers one more solution toward potentially realizing a portable μGC device for the detection of semi-volatile environmental pollutants and explosives without the thermal limitations reported to date with μGC columns using epoxy based interconnect technology.

  4. Design model and recommendations of column-foundation connection through socket with rough interfaces

    Directory of Open Access Journals (Sweden)

    R. M. F. Canha

    Full Text Available The present work proposes design models and recommendations for column-foundation connection through socket with rough interfaces, including the shear key configuration, the socket and the precast column base. In the experimental investigations, the behavior of socket and column as a monolithic connection was verified. However, for this to occur, the shear key dimensions must be between the limits suggested by the study. Considering the total transfer of internal forces in the connections, the vertical reinforcement should be designed based on the bending theory. The proposed model for the design of the transverse horizontal reinforcement, considering monolithic behavior of the connection, was found to be in good agreement with the observed experimental results. With adjustments to this model for the socket, a new model for the design of precast column bases is proposed and compared with other model adapted for rough interfaces.

  5. More rational design of bubble columns; Kihoto sekkei no genjo to kadai

    Energy Technology Data Exchange (ETDEWEB)

    Kawase, Y.; Shimizu, K. [Toyo University, Saitama (Japan)


    Design and scale-up of bubble columns are not easy even at present. For not the conventional empirical design and scale-up by 1-D dispersion model or vessel line model but more rational approach, simulation is essential. This paper outlines approaches to design and scale-up of bubble columns from the viewpoints of gas dispersion as an important factor for design of bubble columns, and flow analysis of bubble columns. A large part of the design and scale-up of bubble columns is dependent on previous experiences. However, for more precise design and scale-up of bubble columns, those should be conducted through simulation. More precise simulation should be based on simultaneous solution of a motion equation on flow in gas-liquid two-phase system, a diffusion equation of mass transfer including a reaction term, and a heat transmission equation on heat transfer, reducing participation of an empirical correlation equation as much as possible. The importance of simulation will surely increase in the future. 14 refs., 5 figs.

  6. Preparation of hybrid monolithic columns via "one-pot" photoinitiated thiol-acrylate polymerization for retention-independent performance in capillary liquid chromatography. (United States)

    Zhang, Haiyang; Ou, Junjie; Liu, Zhongshan; Wang, Hongwei; Wei, Yinmao; Zou, Hanfa


    A novel "one-pot" approach was developed for ultrarapid preparation of various hybrid monolithic columns in UV-transparent fused-silica capillaries via photoinitiated thiol-acrylate polymerization of an acrylopropyl polyhedral oligomertic silsesquioxane (acryl-POSS) and a monothiol monomer (1-octadecanethiol or sodium 3-mercapto-1-propanesulfonate) within 5 min, in which the acrylate not only homopolymerizes, but also couples with the thiol. This unique combination of two types of free-radical reaction mechanisms offers a simple way to fabricate various acrylate-based hybrid monoliths. The physical characterization, including scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy, and thermal gravimetric analysis was performed. The results indicated that the monothiol monomers were successfully incorporated into acryl-POSS-based hybrid monoliths. The column efficiencies for alkylbenzenes on the C18-functionalized hybrid monolithic column reached to 60 000-73 500 plates/m at the velocity of 0.33 mm/s in capillary liquid chromatography, which was far higher than that of previously reported POSS-based columns prepared via thermal-initiated free-radical polymerization without adding any thiol monomers. By plotting the plate height (H) of the alkylbenzenes versus the linear velocity (u) of the mobile phase, the results revealed a retention-independent efficient performance of small molecules in the isocratic elution. These results indicated that more homogeneous hybrid monoliths formed via photoinitiated thiol-acrylate polymerization; particularly, the use of the multifunctional cross-linker possibly prevented the generation of gel-like micropores, reducing mass transfer resistance (C-term). Another sulfonate-containing hybrid monolithic column also exhibited hydrophobicity and ion-exchange mechanism, and the dynamic binding capacity was calculated as 71.1 ng/cm (75 μm i.d.).

  7. Plant-Scale Concentration Column Designs for SHINE Target Solution Utilizing AG 1 Anion Exchange Resin

    Energy Technology Data Exchange (ETDEWEB)

    Stepinski, Dominique C. [Argonne National Lab. (ANL), Argonne, IL (United States); Vandegrift, G. F. [Argonne National Lab. (ANL), Argonne, IL (United States)


    Argonne is assisting SHINE Medical Technologies (SHINE) in their efforts to develop SHINE, an accelerator-driven process that will utilize a uranyl-sulfate solution for the production of fission product Mo-99. An integral part of the process is the development of a column for the separation and recovery of Mo-99, followed by a concentration column to reduce the product volume from 15-25 L to <1 L. Argonne has collected data from batch studies and breakthrough column experiments to utilize the VERSE (Versatile Reaction Separation) simulation program (Purdue University) to design plant-scale product recovery and concentration processes.

  8. Development and design of a multi-column experimental setup for Kr/Xe separation

    Energy Technology Data Exchange (ETDEWEB)

    Garn, Troy G. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Greenhalgh, Mitchell [Idaho National Lab. (INL), Idaho Falls, ID (United States); Watson, Tony [Idaho National Lab. (INL), Idaho Falls, ID (United States)


    As a precursor to FY-15 Kr/Xe separation testing, design modifications to an existing experimental setup are warranted. The modifications would allow for multi-column testing to facilitate a Xe separation followed by a Kr separation using engineered form sorbents prepared using an INL patented process. A new cooling apparatus capable of achieving test temperatures to -40° C and able to house a newly designed Xe column was acquired. Modifications to the existing setup are being installed to allow for multi-column testing and gas constituent analyses using evacuated sample bombs. The new modifications will allow for independent temperature control for each column enabling a plethora of test conditions to be implemented. Sample analyses will be used to evaluate the Xe/Kr selectivity of the AgZ-PAN sorbent and determine the Kr purity of the effluent stream following Kr capture using the HZ-PAN sorbent.

  9. Rational design of the column of a heavy multipurpose machining center (United States)

    Atapin, V. V.; Kurlaev, N. V.


    The main purpose in the design of supporting constructions of heavy multipurpose machining center is the reduction of mass at the given precision and productivity of machining. Accomplish these ends the technology of rational design of supporting constructions is offered. This technology is based on the decomposition method and the finite elements method in the combination with optimization methods. The technology has four stages: 1) calculation of external forces and loads, 2) as a result the boundary conditions (force, kinematics) for individual supporting constructions are formed, 3) a problem about final optimal distribution of a material by the individual supporting constructions with the real cross-section is solved; 4) dynamic analysis. By the example of design of the column of a heavy multipurpose machining center the main stages of rational design of the individual supporting constructions are shown. At a design stage of the carrying system consisting of load-bearing structures with simplified geometry, optimum overall dimensions of the column are identified. For the admitted system of preferences, it is necessary to accept the fact that the carrying system with the column with the sizes of cross section of 1.8 m (along x axis) and 2.6 m (along y axis) is the best. The analysis of the work of the column under the torsion condition with the use of method of mechanics shows that the column with square cross sections = 2.46·2.46 m which rigidity on torsion is 26 % higher in comparison with a production version is the best. The results of calculation show that a production-release design of the column with longitudinal and transverse edges of rigidity is 24 % heavier than the column with the edges located on a diagonally at equal rigidity.

  10. Mooring Design for the Floating Oscillating Water Column Reference Model

    Energy Technology Data Exchange (ETDEWEB)

    Brefort, Dorian [Univ. of Michigan, Ann Arbor, MI (United States); Bull, Diana L. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)


    To reduce the price of the reference Backward Bent Duct Buoy (BBDB), a study was done analyzing the effects of reducing the mooring line length, and a new mooring design was developed. It was found that the overall length of the mooring lines could be reduced by 1290 meters, allowing a significant price reduction of the system. In this paper, we will first give a description of the model and the storm environment it will be subject to. We will then give a recommendation for the new mooring system, followed by a discussion of the severe weather simulation results, and an analysis of the conservative and aggressive aspects of the design.

  11. Building Store Satisfaction Centred on Customer Retention in Clothing Retailing: Store Design and Ease of Shopping

    Directory of Open Access Journals (Sweden)

    Gulden Turhan


    Full Text Available The study’s research model suggests that store design and ease of shopping are associated with customer retention through a mediated pathway in which store design and ease of shopping influence perceived store satisfaction, which in turn, influences customer retention. This survey was administered to two separate clothing stores offered to either females or males (in total, 533 participants. Using structural equation modelling methodology, data was analysed to explain the interrelations among the variables in the model. The results of an empirical study of a sample of store shoppers revealed that store design and ease of shopping influence customer retention in an indirect way through customer perception of satisfaction with the store. In building store satisfaction that is centred on customer retention, store design and shopping ease differ in their relative influences. This difference is high for females, but for men as low as to be considered negligible in males. As a result, improving customers’ perceptions of store design and ease of shopping is a way to ensure store satisfaction support customer retention. The results of the study provide a new insight into the relationships by suggesting indirect effects of shopping ease and store design on consumer retention by their impacts on store satisfaction, rather than direct effects.

  12. Optimal synthesis and design of extractive distillation systems for bioethanol separation: From simple to complex columns

    DEFF Research Database (Denmark)

    Errico, M.; Rong, B. G.; Tola, G.


    Bioethanol has been considered as a green fuel and a valid alternative to reduce the dependence on fossil distillates. The development of an optimal separation process is considered as a key element in the design of an efficient process able to be cost effective and competitive. Despite many...... are investigated. The complex column subspace is generated introducing one or more thermal couplings and considering the possibility to intensify the process combining the column sections performing the same separation task. All the configurations considered, simulated by means of Aspen Plus V 7.3, are compared...... considering the total condenser and reboiler duty as energy index. The capital costs and the solvent consumption are also taken into account in the final selection. Among all the complex configurations considered the two-column sequence can reduce the capital cost above 10% compared to the best simple column...

  13. Column flotation

    Energy Technology Data Exchange (ETDEWEB)

    Kohmuench, J.N.; Norrgran, D.A.; Luttrell, E.; Luttrell, G.H. [Virginia Tech. (United States)


    Over the last decade, column flotation has been recognised in the industry to be most efficient and economical means of recovering fine coal while maximizing product grade. When designed properly, flotation columns provide a high combustible recovery while maintaining a low product ash. The paper looks at the benefits of using column flotation for fine coal recovery. 2 refs., 5 figs.

  14. Capture chromatography for Mo-99 recovery from uranyl sulfate solutions: minimum-column-volume design method. (United States)

    Ling, Lei; Chung, Pei-Lun; Youker, Amanda; Stepinski, Dominique C; Vandegrift, George F; Wang, Nien-Hwa Linda


    Molybdenum-99 (Mo-99), generated from the fission of Uranium-235 (U-235), is the radioactive parent of the most widely used medical isotope, technetium-99m (Tc-99m). An efficient, robust, low-pressure process is developed for recovering Mo-99 from uranyl sulfate solutions. The minimum column volume and the maximum column length for required yield, pressure limit, and loading time are determined using a new graphical method. The method is based on dimensionless groups and intrinsic adsorption and diffusion parameters, which are estimated using a small number of experiments and simulations. The design is tested with bench-scale experiments with titania columns. The results show a high capture yield and a high stripping yield (95±5%). The design can be adapted to changes in design constraints or the variations in feed concentration, feed volume, or material properties. The graph shows clearly how the column utilization is affected by the required yield, loading time, and pressure limit. The cost effectiveness of various sorbent candidates can be evaluated based on the intrinsic parameters. This method can be used more generally for designing other capture chromatography processes. Published by Elsevier B.V.

  15. Flat-Twisted Tubing: Novel Column Design for Spiral High-Speed Counter-Current Chromatography (United States)

    Yang, Yi; Aisa, Haji Akber; Ito, Yoichiro


    The original spiral tube assembly for high-speed counter-current chromatography (HSCCC) is further improved by a new tube configuration called “flat-twisted tubing” which was made by extruding the tube (1.6 mm I.D.) through a narrow slot followed by twisting along its axis forming about 1 cm twisted screw pitch. This modification interrupts the laminar flow of the mobile phase through the tube and continuously mixes the two phases through the column. The performance of this spiral tube assembly was tested by three types of two-phase solvent systems with different polarity each with a set of suitable test samples such as DNP-amino acids, dipeptides and proteins at the optimal elution modes. In general all these test samples yielded higher resolution with the lower mobile phase than the upper mobile phase. In the most hydrophobic two-phase solvent system composed of hexane-ethyl acetate-metanol-0.1M hydrochloric acid (1:1:1:1, v/v), DNP-amino acids were separated with Rs-a (peak resolution based on the same column capacity adjusted for comparison) at 4.40 and 73 % of stationary phase retention at a flow rate of 0.5 ml/min with the lower mobile phase. In the polar solvent system composed of 1-butanol-acetic acid-water (4: 1: 5, v/v), dipeptide samples were resolved with Rs-a at 4.06, compared to 2.79 with the cross-pressed tube assembly at 45 % stationary phase retention, each at a flow rate of 1 ml/min. Finally in the aqueous-aqueous polymer phase systems composed of polyethylene glycol 1000 – dibasic potassium phosphate each 12.5% (w/w) in water, protein samples were resolved with Rs-a at 2.53 compared to 1.10 with the cross-pressed tube assembly at 52 % of stationary phase retention, each at a flow rate of 1 ml/min. These results indicate that the present system substantially improves the partition efficiency with a satisfactory level of stationary phase retention by the lower mobile phase. PMID:19486987


    Directory of Open Access Journals (Sweden)

    A. Narvaes-Garcia


    Full Text Available AbstractIn this paper, three quality or performance indices (Luyben's capacity factor, total annual costs, and annual profit were applied for the design of a batch distillation column working at variable reflux. This work used the Fenske-Underwood-Gilliland short-cut method to solve a problem of four components (benzene, toluene, ethyl-benzene, and ortho-xylene that needed to be separated and purified to a mole fraction of 0.97 or better. The performance of the system was evaluated using distillation columns with 10, 20, 30, 40 and 50 theoretical stages with a boil-up vapor flow set at 100 kmol/h. It was found that the annual profit was the best quality index, while the best case for variable reflux was the column with 50 stages. It was confirmed that the best case always required a reflux ratio close to the minimum.

  17. Direct Down-scale Experiments of Concentration Column Designs for SHINE Process

    Energy Technology Data Exchange (ETDEWEB)

    Youker, Amanda J. [Argonne National Lab. (ANL), Argonne, IL (United States); Stepinski, Dominique C. [Argonne National Lab. (ANL), Argonne, IL (United States); Vandegrift, George F. [Argonne National Lab. (ANL), Argonne, IL (United States)


    Argonne is assisting SHINE Medical Technologies in their efforts to become a domestic Mo-99 producer. The SHINE accelerator-driven process uses a uranyl-sulfate target solution for the production of fission-product Mo-99. Argonne has developed a molybdenum recovery and purification process for this target solution. The process includes an initial Mo recovery column followed by a concentration column to reduce the product volume from 15-25 L to < 1 L prior to entry into the LEU Modified Cintichem (LMC) process for purification.1 This report discusses direct down-scale experiments of the plant-scale concentration column design, where the effects of loading velocity and temperature were investigated.

  18. Review of design codes of concrete encased steel short columns under axial compression

    Directory of Open Access Journals (Sweden)

    K.Z. Soliman


    Full Text Available In recent years, the use of encased steel concrete columns has been increased significantly in medium-rise or high-rise buildings. The aim of the present investigation is to assess experimentally the current methods and codes for evaluating the ultimate load behavior of concrete encased steel short columns. The current state of design provisions for composite columns from the Egyptian codes ECP203-2007 and ECP-SC-LRFD-2012, as well as, American Institute of Steel Construction, AISC-LRFD-2010, American Concrete Institute, ACI-318-2008, and British Standard BS-5400-5 was reviewed. The axial capacity portion of both the encased steel section and the concrete section was also studied according to the previously mentioned codes. Ten encased steel concrete columns have been investigated experimentally to study the effect of concrete confinement and different types of encased steel sections. The measured axial capacity of the tested ten composite columns was compared with the values calculated by the above mentioned codes. It is concluded that non-negligible discrepancies exist between codes and the experimental results as the confinement effect was not considered in predicting both the strength and ductility of concrete. The confining effect was obviously influenced by the shape of the encased steel section. The tube-shaped steel section leads to better confinement than the SIB section. Among the used codes, the ECP-SC-LRFD-2012 led to the most conservative results.

  19. Design and Construction of the 3.2 Mev High Voltage Column for Darht II

    CERN Document Server

    Peters, C; Yu, S; Eylon, S; Henestroza, E


    A 3.2 MeV injector has been designed and built for the Darht II Project at Los Alamos Lab. The installation of the complete injector system is nearing completion at this time. The requirements for the injector are to produce a 3.2 MeV, 2000 ampere electron pulse with a flattop width of at least 2-microseconds and emittance of less than 0.15 p cm-rad normalized. A large high voltage column has been built and installed. The column is vertically oriented, is 4.4 meters long, 1.2 meters in diameter, and weights 5700 kilograms. A novel method of construction has been employed which utilizes bonded mycalex insulating rings. This paper will describe the design, construction, and testing completed during construction. Mechanical aspects of the design will be emphasized.

  20. Design and Implementation of a Micron-Sized Electron Column Fabricated by Focused Ion Beam Milling

    CERN Document Server

    Wicki, Flavio; Escher, Conrad; Fink, Hans-Werner


    We have designed, fabricated and tested a micron-sized electron column with an overall length of about 700 microns comprising two electron lenses; a micro-lens with a minimal bore of 1 micron followed by a second lens with a bore of up to 50 microns in diameter to shape a coherent low-energy electron wave front. The design criteria follow the notion of scaling down source size, lens-dimensions and kinetic electron energy for minimizing spherical aberrations to ensure a parallel coherent electron wave front. All lens apertures have been milled employing a focused ion beam and could thus be precisely aligned within a tolerance of about 300 nm from the optical axis. Experimentally, the final column shapes a quasi-planar wave front with a minimal full divergence angle of 4 mrad and electron energies as low as 100 eV.

  1. Computer-Aided Construction at Designing Reinforced Concrete Columns as Per Ec

    Directory of Open Access Journals (Sweden)

    Zielińska M.


    Full Text Available The article presents the authors’ computer program for designing and dimensioning columns in reinforced concrete structures taking into account phenomena affecting their behaviour and information referring to design as per EC. The computer program was developed with the use of C++ programming language. The program guides the user through particular dimensioning stages: from introducing basic data such as dimensions, concrete class, reinforcing steel class and forces affecting the column, through calculating the creep coefficient taking into account the impact of imperfection depending on the support scheme and also the number of mating members at load shit, buckling length, to generating the interaction curve graph. The final result of calculations provides two dependence points calculated as per methods of nominal stiffness and nominal curvature. The location of those points relative to the limit curve determines whether the column load capacity is assured or has been exceeded. The content of the study describes in detail the operation of the computer program and the methodology and phenomena which are indispensable at designing axially and eccentrically the compressed members of reinforced concrete structures as per the European standards.

  2. The Design and Control of Distillation Column with Side Reactors for Chlorobenzene Production

    Institute of Scientific and Technical Information of China (English)

    薄翠梅; 汤吉海; 柏杨进; 乔旭; 丁良辉; 张湜


    The distillation column with side reactors (SRC) can overcome the temperature/pressure mismatch in the traditional reactive distillation, the column operates at temperature/pressure favorable for vapor-liquid separation, while the reactors operate at temperatures/pressures favorable for reaction kinetics. According to the smooth operation and automatic control problem of the distillation column with side reactors (SRC), the design, simulation calculation and dynamic control of the SCR process for chlorobenzene production are discussed in the paper. Firstly, the mechanism models, the integrated structure optimal design and process simulation systems are established, respectively. And then multivariable control schemes are designed, the controllability of SRC process based on the optimal steady-state integrated structure is explored. The dynamic response performances of closed-loop system against several disturbances are discussed to verify the effectiveness of control schemes for the SRC process. The simulating results show that the control structure using conventional control strategies can effectively overcome feeding disturbances in a specific range.

  3. Shear wave velocity-based evaluation and design of stone column improved ground for liquefaction mitigation

    Institute of Scientific and Technical Information of China (English)

    Zhou Yanguo; Sun Zhengbo; Chen Jie; Chen Yunmin; Chen Renpeng


    The evaluation and design of stone column improvement ground for liquefaction mitigation is a challenging issue for the state of practice.In this paper,a shear wave velocity-based approach is proposed based on the well-defined correlations of liquefaction resistance (CRR)-shear wave velocity (Vs)-void ratio (e) of sandy soils,and the values of parameters in this approach are recommended for preliminary design purpose when site specific values are not available.The detailed procedures of pre-and post-improvement liquefaction evaluations and stone column design are given.According to this approach,the required level of ground improvement will be met once the target Vs of soil is raised high enough (i.e.,no less than the critical velocity) to resist the given earthquake loading according to the CRR-Vs relationship,and then this requirement is transferred to the control of target void ratio (i.e.,the critical e) according to the Vs-e relationship.As this approach relies on the densification of the surrounding soil instead of the whole improved ground and is conservative by nature,specific considerations of the densification mechanism and effect are given,and the effects of drainage and reinforcement of stone columns are also discussed.A case study of a thermal power plant in Indonesia is introduced,where the effectiveness of stone column improved ground was evaluated by the proposed Vs-based method and compared with the SPT-based evaluation.This improved ground performed well and experienced no liquefaction during subsequent strong earthquakes.

  4. Shear wave velocity-based evaluation and design of stone column improved ground for liquefaction mitigation (United States)

    Zhou, Yanguo; Sun, Zhengbo; Chen, Jie; Chen, Yunmin; Chen, Renpeng


    The evaluation and design of stone column improvement ground for liquefaction mitigation is a challenging issue for the state of practice. In this paper, a shear wave velocity-based approach is proposed based on the well-defined correlations of liquefaction resistance (CRR)-shear wave velocity ( V s)-void ratio ( e) of sandy soils, and the values of parameters in this approach are recommended for preliminary design purpose when site specific values are not available. The detailed procedures of pre- and post-improvement liquefaction evaluations and stone column design are given. According to this approach, the required level of ground improvement will be met once the target V s of soil is raised high enough (i.e., no less than the critical velocity) to resist the given earthquake loading according to the CRR- V s relationship, and then this requirement is transferred to the control of target void ratio (i.e., the critical e) according to the V s- e relationship. As this approach relies on the densification of the surrounding soil instead of the whole improved ground and is conservative by nature, specific considerations of the densification mechanism and effect are given, and the effects of drainage and reinforcement of stone columns are also discussed. A case study of a thermal power plant in Indonesia is introduced, where the effectiveness of stone column improved ground was evaluated by the proposed V s-based method and compared with the SPT-based evaluation. This improved ground performed well and experienced no liquefaction during subsequent strong earthquakes.

  5. Design and implementation of a micron-sized electron column fabricated by focused ion beam milling

    Energy Technology Data Exchange (ETDEWEB)

    Wicki, Flavio, E-mail:; Longchamp, Jean-Nicolas; Escher, Conrad; Fink, Hans-Werner


    We have designed, fabricated and tested a micron-sized electron column with an overall length of about 700 microns comprising two electron lenses; a micro-lens with a minimal bore of 1 micron followed by a second lens with a bore of up to 50 microns in diameter to shape a coherent low-energy electron wave front. The design criteria follow the notion of scaling down source size, lens-dimensions and kinetic electron energy for minimizing spherical aberrations to ensure a parallel coherent electron wave front. All lens apertures have been milled employing a focused ion beam and could thus be precisely aligned within a tolerance of about 300 nm from the optical axis. Experimentally, the final column shapes a quasi-planar wave front with a minimal full divergence angle of 4 mrad and electron energies as low as 100 eV. - Highlights: • Electron optics • Scaling laws • Low-energy electrons • Coherent electron beams • Micron-sized electron column.

  6. Full scale numerical analysis of high performance concrete columns designed to withstand severe blast impact

    DEFF Research Database (Denmark)

    Riisgaard, Benjamin; Georgakis, Christos; Stang, Henrik;


    Polymer reinforced Compact Reinforced Composite, PCRC, is a Fiber reinforced Densified Small Particle system, FDSP, combined with a high strength longitudinal flexural rebar arrangement laced together with polymer lacing to avoid shock initiated disintegration of the structural element under blast...... load. Scaled experimental and numerical results of PCRC columns (200x200x1600mm) subjected to close-in detonation are presented in this paper. Based on these results and the use of geometrical scaling lows, a full scale column (800x800x6400mm) is designed and verified numerically to withstand 486.5 kg...... of PETN (85/15) High Explosives at stand off 1600 mm. Additionally, a LS-DYNA material model suitable for predicting the response of Polymer reinforced Compact Reinforced Concrete improved for close-in detonation and a description of the LS-DYNA multi-material Eulerian method for modeling the blast event...

  7. Experimental Evaluation of the Failure of a Seismic Design Category - B Precast Concrete Beam-Column Connection System (United States)


    specimen to examine the specimen, but not inside the reaction frame . 8. The load will removed from the stub column, and the specimen will be braced to...experiment to test a precast concrete beam-column system to failure. This experiment was designed to evaluate the performance of precast frame ...54  Figure 81. Strains in top lateral steel brace beam

  8. Experimental design and statistical analysis in Rotating Disc Contactor (RDC) column (United States)

    Ismail, Wan Nurul Aiffah; Zakaria, Siti Aisyah; Noor, Nor Fashihah Mohd; Ariffin, Wan Nor Munirah


    The purpose of this paper is to examine the performance of the liquid-liquid extraction in Rotating Disc Contactor (RDC) Column that being used in industries. In this study, the performance of small diameter column RDC using the chemical system involving cumene/isobutryric asid/water are analyzed by the method of design of the experiments (DOE) and also Multiple Linear Regression (MLR). The DOE method are used to estimated the effect of four independent. Otherwise, by using Multiple Linear Regression (MLR) is to justify the relationship between the input variables and output variables and also to determine which variable are more influence for both output variable. The input variables for both method include rotor speed (Nr); ratio of flow (Fd); concentration of continuous inlet (Ccin); concentration of dispersed inlet (Cdin); interaction between Nr with Fd; interaction between Nr with Ccin; interaction Nr with Cdin. Meanwhile the output variables are concentration of continuous outlet (Ccout) and concentration of dispersed outlet (Cdout) on RDC column performance. By using this two method, we have two linear model represent two output of Ccout and Cdout for MLR. Lastly, the researcher want to determine which input variable that give more influence to output variable by using this two method. Based on the result, we obtained that rotor speed (Nr) more influence to dependent variable, Ccout and concentration of continuous inlet (Ccin) more influence to dependent variable, Cdout according the two method that was used.

  9. Modeling the effects of type and concentration of organic modifiers, column type and chemical structure of analytes on the retention in reversed phase liquid chromatography using a single model. (United States)

    Jouyban, Abolghasem; Soltani, Somaieh; Shayanfar, Ali; Pappa-Louisi, Adriani


    A previously proposed model for representing the retention factor (k) of an analyte in mixed solvent mobile phases was extended to calculate the k of different analytes with respect to the nature of analyte, organic modifier, its concentration and type of the stationary phase. The accuracy of the proposed method was evaluated by calculating mean percentage deviation (MPD) as accuracy criterion. The predicted vs. observed plots were also provided as goodness of fit criteria. The developed model prediction capability compared with a number of previous models (i.e. LSER, general LSER and Oscik equation) through MPD and fitting plots. The proposed method provided acceptable predictions with the advantage of modeling the effects of organic modifiers, mobile phase compositions, columns and analytes using a single equation. The accuracy of developed model was checked using the one column and one analyte out cross validation analyses and the results showed that the developed model was able to predict the unknown analyte retention and the analytes retentions on unknown column accurately.

  10. Design of Mixed Batch Reactor and Column Studies at Oak Ridge National Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Weimin [Stanford Univ., CA (United States); Criddle, Craig S. [Stanford Univ., CA (United States)


    We (the Stanford research team) were invited as external collaborators to contribute expertise in environmental engineering and field research at the ORNL IFRC, Oak Ridge, TN, for projects carried out at the Argonne National Laboratory and funded by US DOE. Specifically, we assisted in the design of batch and column reactors using ORNL IFRC materials to ensure the experiments were relevant to field conditions. During the funded research period, we characterized ORNL IFRC groundwater and sediments in batch microcosm and column experiments conducted at ANL, and we communicated with ANL team members through email and conference calls and face-to-face meetings at the annual ERSP PI meeting and national meetings. Microcosm test results demonstrated that U(VI) in sediments was reduced to U(IV) when amended with ethanol. The reduced products were not uraninite but unknown U(IV) complexes associated with Fe. Fe(III) in solid phase was only partially reduced. Due to budget reductions at ANL, Stanford contributions ended in 2011.

  11. Manual for the thermal and hdyraulic design of direct contract spray columns for use in extracting heat from geothermal brines (United States)

    Jacobs, H. R.


    This report outlines the current methods being used in the thermal and hydraulic design of spray column type, direct contact heat exchangers. It provides appropriate referenced equations for both preliminary design and detailed performance. The design methods are primarily empirical and are applicable for use in the design of such units for geothermal application and for application with solar ponds. Methods for design, for both preheater and boiler sections of the primary heat exchangers, for direct contact binary powers plants are included.


    NARCIS (Netherlands)



    Experiments were carried out in bubble columns for a number of liquids at pressures between 0.1 and 2.0 MPa for two column sizes. Based on the experimental results as well as extensive literature data, the extent of the effect column dimensions have on gas holdup were determined, both at low and hig

  13. Chromatofocusing using micropellicular column packings with computer-aided design of the elution buffer composition. (United States)

    Kang, Xuezhen; Frey, Douglas D


    Micropellicular, anion-exchange column packings are used in chromatofocusing to demonstrate the resolution and speed achieved when proteins are separated under these conditions. Linear or concave pH gradients are produced with simple mixtures containing four or fewer individual buffering species instead of the more commonly used polyampholyte buffers. Computer-aided design methods are demonstrated for selecting the composition of the elution buffer to produce a pH gradient of a desired shape. The method is applied to high-resolution, analytical- and preparative-scale separations involving horse myoglobin, human hemoglobin variants, and bovine carbonic anhydrase. A useful selection of buffering species is described capable of producing pH gradients of a variety of shapes in the range between pH 9.5 and 5.5.

  14. Design and simulation of dividing wall column for ternary heterogeneous distillation


    Le, Quang Khoa


    Heterogeneous azeotropic distillation is routinely used in chemical industry to separate close boiling point mixtures and azeotropes, which are not easily separated in a normal distillation process. Dividing wall column is one of the most promising technologies to minimize the energy consumption that leads to minimize the operating cost. Dividing wall column provide a large potential energy saving up to more than 30% compared to the conventional column sequences. The aim of this work is...

  15. Design, recruitment, and retention of African-American smokers in a pharmacokinetic study

    Directory of Open Access Journals (Sweden)

    Mayo Matthew S


    Full Text Available Abstract Background African-Americans remain underrepresented in clinical research despite experiencing a higher burden of disease compared to all other ethnic groups in the United States. The purpose of this article is to describe the study design and discuss strategies used to recruit and retain African-American smokers in a pharmacokinetic study. Methods The parent study was designed to evaluate the differences in the steady-state concentrations of bupropion and its three principal metabolites between African-American menthol and non-menthol cigarette smokers. Study participation consisted of four visits at a General Clinical Research Center (GCRC over six weeks. After meeting telephone eligibility requirements, phone-eligible participants underwent additional screening during the first two GCRC visits. The last two visits (pharmacokinetic study phase required repeated blood draws using an intravenous catheter over the course of 12 hours. Results Five hundred and fifteen African-American smokers completed telephone screening; 187 were phone-eligible and 92 were scheduled for the first GCRC visit. Of the 81 who attended the first visit, 48 individuals were enrolled in the pharmacokinetic study, and a total of 40 individuals completed the study (83% retention rate. Conclusions Although recruitment of African-American smokers into a non-treatment, pharmacokinetic study poses challenges, retention is feasible. The results provide valuable information for investigators embarking on non-treatment laboratory-based studies among minority populations.

  16. Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems (DE-EE0002961)

    Energy Technology Data Exchange (ETDEWEB)

    Spitler, J. D.; Culling, J. R.; Conjeevaram, K.; Ramesh, M.; Selvakumar, M.


    Ground-source heat pump (GSHP) systems are perhaps the most widely used “sustainable” heating and cooling systems, with an estimated 1.7 million installed units with total installed heating capacity on the order of 18 GW. They are widely used in residential, commercial, and institutional buildings. Standing column wells (SCW) are one form of ground heat exchanger that, under the right geological conditions, can provide excellent energy efficiency at a relatively low capital cost. Closed-loop surface water heat pump (SWHP) systems utilize surface water heat exchangers (SWHE) to reject or extract heat from nearby surface water bodies. For building near surface water bodies, these systems also offer a high degree of energy efficiency at a low capital cost. However, there have been few design tools available for properly sizing standing column wells or surface water heat exchangers. Nor have tools for analyzing the energy consumption and supporting economics-based design decisions been available. The main contributions of this project lie in providing new tools that support design and energy analysis. These include a design tool for sizing surface water heat exchangers, a design tool for sizing standing column wells, a new model of surface water heat pump systems implemented in EnergyPlus and a new model of standing column wells implemented in EnergyPlus. These tools will better help engineers design these systems and determine the economic and technical feasibility.

  17. Preliminary Design of a Multi-Column TLP Foundation for a 5-MW Offshore Wind Turbine

    Directory of Open Access Journals (Sweden)

    Yanping He


    Full Text Available Currently, floating wind turbines (FWTs may be the more economical and suitable systems with which to exploit offshore wind energy in deep waters. Among the various types of floating foundations for offshore wind farms, a tension leg platform (TLP foundation can provide a relatively stable platform for currently available offshore wind turbines without requiring major modifications. In this study, a new multi-column TLP foundation (WindStar TLP was developed for the NREL 5-MW offshore wind turbine according to site-specific environmental conditions, which are the same as the OC3-Hywind (NREL conditions. The general arrangement, main structure and mooring system were also designed and investigated through hydrodynamic and natural frequency analyses. The complete system avoids resonance through the rotor excitations. An aero-hydro-servo-elastic coupled analysis was carried out in the time domain with the numerical tool FAST. Statistics of the key parameters were obtained and analysed and comparisons to MIT/NREL TLP are made. As a result, the design requirements were shown to be satisfied, and the proposed WindStar TLP was shown to have favourable motion characteristics under extreme wind and wave conditions with a lighter and smaller structure. The new concept holds great potential for further development.

  18. Design of Macroscopically Ordered Liquid Crystalline Hydrogel Columns Knitted with Nanosilver for Topical Applications. (United States)

    Lali Raveendran, Reshma; Kumar Sasidharan, Nishanth; Devaki, Sudha J


    The design of liquid crystalline hydrogels knitted with silver nanoparticles in macroscopic ordering is becoming a subject of research interest due to their promising multifunctional applications in biomedical and optoelectronic applications. The present work describes the development of liquid crystalline Schiff-based hydrogel decorated with silver nanoparticles and the demonstration of its antifungal applications. Schiff base was prepared from polyglucanaldehyde and chitosan, and the former was prepared by the oxidation of amylose (polyglucopyranose) isolated from abundantly available unutilized jackfruit seed starch. Self-assembled silver columns decorated with macroscopically ordered networks were prepared in a single step of in situ condensation and a reduction/complexation process. The various noncovalent interactions among the -OH, -C═O, and -NH impart rigidity and ordering for the formation of macroscopically ordered liquid crystalline hydrogel and the Ag(I) complexation evidenced from the studies made by FT-IR spectroscopy in combination with rheology and microscopic techniques such as SEM, TEM, AFM, XRD, and PLM. The antifungal studies were screened using species of Candida by disc diffusion method. The MIC and MFC values, in vitro antifungal studies, reactive oxygen species (ROS) production, and propidium iodide (PI) uptake results suggest that the present macroscopically ordered liquid crystalline hydrogel system can be considered an excellent candidate for topical applications. All these results suggest that this design strategy can be exploited for the incorporation of biologically relevant metal nanoparticles for developing unique robust hydrogels for multifunctional applications.

  19. Comparison of batch and continuous multi-column protein A capture processes by optimal design. (United States)

    Baur, Daniel; Angarita, Monica; Müller-Späth, Thomas; Steinebach, Fabian; Morbidelli, Massimo


    Multi-column capture processes show several advantages compared to batch capture. It is however not evident how many columns one should use exactly. To investigate this issue, twin-column CaptureSMB, 3- and 4-column periodic counter-current chromatography (PCC) and single column batch capture are numerically optimized and compared in terms of process performance for capturing a monoclonal antibody using protein A chromatography. Optimization is carried out with respect to productivity and capacity utilization (amount of product loaded per cycle compared to the maximum amount possible), while keeping yield and purity constant. For a wide range of process parameters, all three multi-column processes show similar maximum capacity utilization and performed significantly better than batch. When maximizing productivity, the CaptureSMB process shows optimal performance, except at high feed titers, where batch chromatography can reach higher productivity values than the multi-column processes due to the complete decoupling of the loading and elution steps, albeit at a large cost in terms of capacity utilization. In terms of trade-off, i.e. how much the capacity utilization decreases with increasing productivity, CaptureSMB is optimal for low and high feed titers, whereas the 3-column process is optimal in an intermediate region. Using these findings, the most suitable process can be chosen for different production scenarios.

  20. Stability of Antenna-Column of Neglectable Own Weight in Design of Wireless Traffic Network

    Directory of Open Access Journals (Sweden)

    Juraj Saucha


    Full Text Available The paper deals with the problem of elas1ic stability of antenna-column ofneglec/able own weight subjected to the actionof effective load on its lop. The determination of critical bucklingforce is based upon the derived exact solution to !he equilibriumequation of the column of continuously variable crosssection loaded with conswnl compressive force.

  1. A Simple Design to Realize Micro-column Separation by Conventional Analytical HPLC

    Institute of Scientific and Technical Information of China (English)

    GONG,Wenjun; ZHANG,Junxia; ZHANG,Yuping; ZHANG,Yijun; TIAN,Mengkui; WU,Dafu


    The conventional analytical HPLC was successfully developed for micro-column separation by using a simple eluate splitting system,self-preparation of packing column and on-capillary column detector in our laboratory.Porous inlet frit in fused silica capillary was rapidly prepared by sintering stainless steel powders under 500 meshes for about 20 s.The use of such frits or metal meshes in capillary to retain C18 particles of chromatographic packing was demonstrated to be stable and specially robust with continuous packing and long chromatographic runs.Furthermore,the chromatographic behavior was detailedly evaluated by changing the flow rate and the percentage of mobile phase using the prepared capillary column.Under the optimal experimental conditions,baseline separation of the model analytes including thiourea,benzene,toluene,ethylbenzene was obtained with a high column efficiency near 70000N (plates/m) by the developed capillary-HPLC.

  2. Advanced in-vessel retention design for next generation risk management

    Energy Technology Data Exchange (ETDEWEB)

    Suh, Kune Y.; Hwang, Il Soon [Seoul National University, Seoul (Korea, Republic of)


    In the TMI-2 accident, approximately twenty (20) tons of molten core material drained into the lower plenum. Early advanced light water reactor (LWR) designs assumed a lower head failure and incorporated various measures for ex-vessel accident mitigation. However,one of the major findings from the TMI-2 Vessel Investigation Project was that one part of the reactor lower head wall estimated to have attained a temperature of 1100 deg C for about 30 minutes has seemingly experienced a comparatively rapid cooldown with no major threat to the vessel integrity. In this regard, recent empirical and analytical studies have shifted interests to such in-vessel retention designs or strategies as reactor cavity flooding, in-vessel flooding and engineered gap cooling of the vessel. Accurate thermohydrodynamic and creep deformation modeling and rupture prediction are the key to the success in developing practically useful in-vessel accident/risk management strategies. As an advanced in-vessel design concept, this work presents the COrium Attack Syndrome Immunization Structures (COASIS) that are being developed as prospective in-vessel retention devices for a next-generation LWR in concert with existing ex-vessel management measures. Both the engineered gap structures in-vessel (COASISI) and ex-vessel (COASISO) are demonstrated to maintain effective heat transfer geometry during molten core debris attack when applied to the Korean Standard Nuclear Power Plant (KSNPP) reactor. The likelihood of lower head creep rupture during a severe accident is found to be significantly suppressed by the COASIS options. 15 refs., 5 figs., 1 tab. (Author)

  3. A Column Generation Approach to Solve Multi-Team Influence Maximization Problem for Social Lottery Design (United States)

    Jois, Manjunath Holaykoppa Nanjunda

    The conventional Influence Maximization problem is the problem of finding such a team (a small subset) of seed nodes in a social network that would maximize the spread of influence over the whole network. This paper considers a lottery system aimed at maximizing the awareness spread to promote energy conservation behavior as a stochastic Influence Maximization problem with the constraints ensuring lottery fairness. The resulting Multi-Team Influence Maximization problem involves assigning the probabilities to multiple teams of seeds (interpreted as lottery winners) to maximize the expected awareness spread. Such a variation of the Influence Maximization problem is modeled as a Linear Program; however, enumerating all the possible teams is a hard task considering that the feasible team count grows exponentially with the network size. In order to address this challenge, we develop a column generation based approach to solve the problem with a limited number of candidate teams, where new candidates are generated and added to the problem iteratively. We adopt a piecewise linear function to model the impact of including a new team so as to pick only such teams which can improve the existing solution. We demonstrate that with this approach we can solve such influence maximization problems to optimality, and perform computational study with real-world social network data sets to showcase the efficiency of the approach in finding lottery designs for optimal awareness spread. Lastly, we explore other possible scenarios where this model can be utilized to optimally solve the otherwise hard to solve influence maximization problems.

  4. Numerical investigation of a bubble-column photo-bioreactor design for biodiesel production from microalgae

    Energy Technology Data Exchange (ETDEWEB)

    Seo, I.H.; Lee, I.B.; Hwang, H.S.; Hong, S.W.; Bitog, J.P.; Kwon, K.S.; Choi, J.S.; Song, S.H. [Seoul National Univ., Seoul (Korea, Democratic People' s Republic of). Dept. of Rural Systems Engineering and Research Inst. for Agriculture and Life Sciences


    Biodiesel made from vegetable oil is among the most desirable of renewable energy sources because it can be a substitute for diesel oil. However, biodiesel from soybean or corn can be confronted with a food crisis. Microalgae is a new biodiesel source which contains high oil lipids with a high growth rate, and which also offers value-added products from the residue, such as cosmetics, health functional food or pharmaceuticals. Microalgae are best cultivated in photo-bioreactors (PBRs) where light, nutrients, carbon dioxide and temperature can be controlled. Despite the current availability of PBRs, only a few can be practically used for mass production. Computational fluid dynamics (CFD) was used in this study to design an optimum bubble-column PBR for mass production of microalgae. Multi-phase models including bubble movement, meshes and time step independent tests were considered to develop the 3-dimensional CFD model. Particle Image Velocimetry (PIV) tests were used to enhance and validate the model. Different types of PBRs were simulated and compared quantitatively with the microalgae's growth model.

  5. A hydrologic retention system and water quality monitoring program for a human decomposition research facility: concept and design. (United States)

    Wozniak, Jeffrey R; Thies, Monte L; Bytheway, Joan A; Lutterschmidt, William I


    Forensic taphonomy is an essential research field; however, the decomposition of human cadavers at forensic science facilities may lead to nutrient loading and the introduction of unique biological compounds to adjacent areas. The infrastructure of a water retention system may provide a mechanism for the biogeochemical processing and retention of nutrients and compounds, ensuring the control of runoff from forensic facilities. This work provides a proof of concept for a hydrologic retention system and an autonomous water quality monitoring program designed to mitigate runoff from The Southeast Texas Applied Forensic Science (STAFS) Facility. Water samples collected along a sample transect were analyzed for total phosphorous, total nitrogen, NO3-, NO2-, NH4, F(-), and Cl(-). Preliminary water quality analyses confirm the overall effectiveness of the water retention system. These results are discussed with relation to how this infrastructure can be expanded upon to monitor additional, more novel, byproducts of forensic science research facilities.

  6. Manual for the thermal and hydraulic design of direct contact spray columns for use in extracting heat from geothermal brines

    Energy Technology Data Exchange (ETDEWEB)

    Jacobs, H.R.


    This report outlines the current methods being used in the thermal and hydraulic design of spray column type, direct contact heat exchangers. It provides appropriate referenced equations for both preliminary design and detailed performance. The design methods are primarily empirical and are applicable for us in the design of such units for geothermal application and for application with solar ponds. Methods for design, for both preheater and boiler sections of the primary heat exchangers, for direct contact binary powers plants are included. 23 refs., 8 figs.

  7. Characterize Behaviour of Emerging Pollutants in Artificial Recharge: Column Experiments - Experiment Design and Results of Preliminary Tests (United States)

    Wang, H.; Carrera, J.; Ayora, C.; Licha, T.


    Emerging pollutants (EPs) have been detected in water resources as a result of human activities in recent years. They include pharmaceuticals, personal care products, dioxins, flame retardants, etc. They are a source of concern because many of them are resistant to conventional water treatment, and they are harmful to human health, even in low concentrations. Generally, this study aims to characterize the behaviour of emerging pollutants in reclaimed water in column experiments which simulates artificial recharge. One column set includes three parts: influent, reactive layer column (RLC) and aquifer column (AC). The main influent is decided to be Secondary Effluent (SE) of El Prat Wastewater Treatment Plant, Barcelona. The flow rate of the column experiment is 0.9-1.5 mL/min. the residence time of RLC is designed to be about 1 day and 30-40 days for AC. Both columns are made of stainless steel. Reactive layer column (DI 10cm * L55cm) is named after the filling material which is a mixture of organic substrate, clay and goethite. One purpose of the application of the mixture is to increase dissolve organic carbon (DOC). Leaching test in batchs and columns has been done to select proper organic substrate. As a result, compost was selected due to its long lasting of releasing organic matter (OM). The other purpose of the application of the mixture is to enhance adsorption of EPs. Partition coefficients (Kow) of EPs indicate the ability of adsorption to OM. EPs with logKow>2 could be adsorbed to OM, like Ibuprofen, Bezafibrate and Diclofenac. Moreover, some of EPs are charged in the solution with pH=7, according to its acid dissociation constant (Ka). Positively charged EPs, for example Atenolol, could adsorb to clay. In the opposite, negatively charged EPs, for example Gemfibrozil, could adsorb to goethite. Aquifer column (DI 35cm * L1.5m) is to simulate the processes taking place in aquifer in artificial recharge. The filling of AC has two parts: silica sand and

  8. Robust design of adenovirus purification by two-column, simulated moving-bed, size-exclusion chromatography. (United States)

    Nestola, Piergiuseppe; Silva, Ricardo J S; Peixoto, Cristina; Alves, Paula M; Carrondo, Manuel J T; Mota, José P B


    A simple, yet efficient, two-column simulated moving-bed (2CSMB) process for purifying adenovirus serotype 5 (Ad5) by size-exclusion chromatography (SEC) is presented and validated experimentally, and a general procedure for its robust design under parameter uncertainty is described. The pilot-scale run yielded a virus recovery of 86 percent and DNA and HCP clearances of 90 and 89 percent, respectively, without any fine tuning of the operating parameters. This performance compares very favorably against that of single-column batch chromatography for the same volume of size-exclusion resin. To improve the robustness of the 2CSMB-SEC process the best set of operating parameters is selected only among candidate solutions that are robust feasible, that is, remain feasible for all parameter perturbations within their uncertainty intervals. This robust approach to optimal design replaces the nominal problem by a worst case problem. Computational tractability is ensured by formulating the robust design problem with only the vertices of the uncertainty region that have the worst effect on the product purity and recovery. The robust design is exemplified on the case where the column volume and interparticle porosity are subject to uncertainty. As expected, to increase the robustness of the 2CSMB-SEC process it is necessary to reduce its productivity and increase its solvent consumption. Nevertheless, the design solution given by our robust approach is the least detrimental of all feasible operating conditions for the 2CSMB-SEC process.

  9. Assessment of precast beam-column using capacity demand response spectrum subject to design basis earthquake and maximum considered earthquake (United States)

    Ghani, Kay Dora Abd.; Tukiar, Mohd Azuan; Hamid, Nor Hayati Abdul


    Malaysia is surrounded by the tectonic feature of the Sumatera area which consists of two seismically active inter-plate boundaries, namely the Indo-Australian and the Eurasian Plates on the west and the Philippine Plates on the east. Hence, Malaysia experiences tremors from far distant earthquake occurring in Banda Aceh, Nias Island, Padang and other parts of Sumatera Indonesia. In order to predict the safety of precast buildings in Malaysia under near field ground motion the response spectrum analysis could be used for dealing with future earthquake whose specific nature is unknown. This paper aimed to develop of capacity demand response spectrum subject to Design Basis Earthquake (DBE) and Maximum Considered Earthquake (MCE) in order to assess the performance of precast beam column joint. From the capacity-demand response spectrum analysis, it can be concluded that the precast beam-column joints would not survive when subjected to earthquake excitation with surface-wave magnitude, Mw, of more than 5.5 Scale Richter (Type 1 spectra). This means that the beam-column joint which was designed using the current code of practice (BS8110) would be severely damaged when subjected to high earthquake excitation. The capacity-demand response spectrum analysis also shows that the precast beam-column joints in the prototype studied would be severely damaged when subjected to Maximum Considered Earthquake (MCE) with PGA=0.22g having a surface-wave magnitude of more than 5.5 Scale Richter, or Type 1 spectra.

  10. The Effect of abutment wall modification, filling material & copying design on retention of cement retained implant supported crown

    Directory of Open Access Journals (Sweden)

    Shima Aalaei


    Full Text Available Background and aim: Factors which can effect of tooth supported crowns are well known. On the other side, low information are existed about retention of implant supported crowns. The aim of the present study was to evaluate the effect of abutment wall modification, filling material & copying design on retention of cement retained implant supported crown. Materials and methods: In this study, 4 straight abutments were attached to their implant analogues and were embedded in the acrylic resin block. Abutments were modified to one, two, three and four walls. Then, two type copying were made: conventional and with metal extension in two screw access cavity. Access cavities were filled incompletely by three methods: copying with extension spread into the access cavity without material and conventional copying with polytetrafluoroethylene (PTFE or composite. Then cemented with temporary agent (TempBond. Required tensile force for separation of copying was measured by universal testing machine. Data were analyzed using ANOVA as statistical test. Results: About findings of this research, no significant difference were detected among two methods of filling of access cavity and engaging screw access channel (P>0.05. Four wall abutment shown significantly higher retention than the others (P<0.05 and three other abutments have no significant difference in retention. Conclusion: The type of filling material of access cavity (PTFE and composite and engaging of the copying design have no significant effects on the cemented retained of implant supported restoration but existence of all four septums increase the veneer retention significantly.

  11. Design and Prototype of an Automated Column-Switching HPLC System for Radiometabolite Analysis. (United States)

    Vasdev, Neil; Collier, Thomas Lee


    Column-switching high performance liquid chromatography (HPLC) is extensively used for the critical analysis of radiolabeled ligands and their metabolites in plasma. However, the lack of streamlined apparatus and consequently varying protocols remain as a challenge among positron emission tomography laboratories. We report here the prototype apparatus and implementation of a fully automated and simplified column-switching procedure to allow for the easy and automated determination of radioligands and their metabolites in up to 5 mL of plasma. The system has been used with conventional UV and coincidence radiation detectors, as well as with a single quadrupole mass spectrometer.

  12. Design and Prototype of an Automated Column-Switching HPLC System for Radiometabolite Analysis

    Directory of Open Access Journals (Sweden)

    Neil Vasdev


    Full Text Available Column-switching high performance liquid chromatography (HPLC is extensively used for the critical analysis of radiolabeled ligands and their metabolites in plasma. However, the lack of streamlined apparatus and consequently varying protocols remain as a challenge among positron emission tomography laboratories. We report here the prototype apparatus and implementation of a fully automated and simplified column-switching procedure to allow for the easy and automated determination of radioligands and their metabolites in up to 5 mL of plasma. The system has been used with conventional UV and coincidence radiation detectors, as well as with a single quadrupole mass spectrometer.

  13. Novel Procedure for Assessment of Feasible Design Parameters of Dividing-Wall Columns: Application to Non-azeotropic Mixtures


    Benyounes, Hassiba; Benyahia, Khadidja; Shen,Weifeng; Gerbaud, Vincent; Dong, Lichun; Wei, Shun'an


    International audience; Dividing wall columns (DWCs), as a subset of fully thermally coupled distillation systems (FTCDS), is considered as one of most appealing distillation technologies to the chemical industry, because it can bring about substantial reduction in the capital investment, as well as savings in the operating costs. This study targets on how to improve the energy efficiency of DWCs by achieving their well-designed feasible parameters. Two methods are applied to study the effect...

  14. Optimal Design of Safety Instrumented Systems for Pressure Control of Methanol Separation Columns in the Bisphenol a Manufacturing Process

    Directory of Open Access Journals (Sweden)

    In-Bok Lee


    Full Text Available A bisphenol A production plant possesses considerable potential risks in the top of the methanol separation column, as pressurized acetone, methanol, and water are processed at an elevated temperature, especially in the event of an abnormal pressure increase due to a sudden power outage. This study assesses the potential risks in the methanol separation column through hazard and operability assessments and evaluates the damages in the case of fire and explosion accident scenarios. The study chooses three leakage scenarios: a 5-mm puncture on the methanol separation column, a 50-mm diameter fracture of a discharge pipe and a catastrophic rupture, and, simulated using Phast (Ver. 6.531, the concentration distribution of scattered methanol, thermal radiation distribution of fires, and overpressure distribution of vapor cloud explosions. Implementation of a safety-instrumented system equipped with two-out-of-three voting as a safety measure can detect overpressure at the top of the column and shut down the main control valve and the emergency shutoff valve simultaneously. By applying a safety integrity level of three, the maximal release volume of the safety relief valve can be reduced and, therefore, the design capacity of the flare stack can also be reduced. Such integration will lead to improved safety at a reduced cost.

  15. Chemometric study of the retention mechanism on butyl column:effect and relation of pH and pKa

    Institute of Scientific and Technical Information of China (English)

    KOUSKOURA Maria G; MITANI Constantina V; MARKOPOULOU Catherine K


    Reversed phase chromatographic separations are optimized for analytes containing ionizable groups by adjustment of pH of mobile phases. As it seems the pKa values of compounds affect their retention because of the variety in their solvation. However,it is of stressful need to predict their behavior taking into account also a series of other parameters. This work focuses on the development of ten different models,using partial least squares regression,which will identify and quantify the impact of several factors in the chromatographic behavior of 104 analytes. The combined effect of their numerous characteristics is obvious since along with pH ( at 2. 3 and 6. 2),factors such as lipophilicity,molecular volume,polar surface area and the presence of spe-cific moieties in their structures are not diminished. On the contrary,they work increasing or counterbalancing several effects on the retention time. The models compiled can be applied to predict with reliability(R2>0. 865 and Q2>0. 777)the behavior of unknown drugs.

  16. Design and optimization of gastro-retentive microballoons for enhanced bioavailability of cinnarizine. (United States)

    Ammar, Hussein O; Ghorab, Mahmoud; Kamel, Rabab; Salama, Alaa H


    This study is focused on the design of gastro-retentive drug delivery system composed of hollow microspheres (microballoons) for the sustained delivery of cinnarizine (CIN). The microballoons (MBs) were prepared by the emulsion solvent diffusion method using cellulose acetate butyrate (CAB) as the hosting polymer and absolute ethanol (ETH) and dichloromethane (DCM) as solvents. A 3(3) full factorial experimental design was adopted to study the effect of different variables and to find an optimum formula with desired properties. Prepared microballoons showed high drug loading capacities and controlled release behaviour. The optimum formulation was chosen on the basis of achieving maximum values for both drug loading capacity and release efficiency as well as having suitable size. The optimized MB (MB-F21) was composed of 200 mg CIN and 400 mg CAB with a DCM/ETH ratio of 2:1. Scanning electron microscopy for the optimum formulation showed a spherical outline with internal porous structure. An in vivo study using human volunteers was performed by determination of CIN concentration in the plasma using the liquid chromatography-mass spectrometry (LC-MS) method. Results proved the superiority of the designed formulation over the market product Stuval® tablets in bioavailability parameters comprising T max as well as area under the plasma CIN concentration-time curve (AUC0-24 h) and AUC0-∞ values. Also, the significantly greater value of mean residence time (MRT) in case of MB-F21 indicates its higher gastric residence time and proves the advantages of micro-multiparticulate dosage forms over conventional one.

  17. Causes and implications of colloid and microorganism retention hysteresis (United States)

    Experiments were designed to better understand the causes and implications of colloid and microorganism retention hysteresis with transients in solution ionic strength (IS). Saturated packed column experiments were conducted using two sizes of carboxyl modified latex (CML) microspheres (0.1 and 1.1...

  18. Reactive dividing wall column for hydrolysis of methyl acetate:Design and control☆

    Institute of Scientific and Technical Information of China (English)

    Lumin Li; Lanyi Sun; Delian Yang; Wang Zhong; Yi Zhu; Yuanyu Tian


    Reactive distillation and dividing wall column distillation are two kinds of effective separation technologies, and their integrated configuration, reactive dividing wall column (RDWC), presents attractive advantages. In this study, the rigorous simulation of RDWC for methyl acetate hydrolysis is performed, and sensitivity analysis is conducted to obtain the minimum reboiler duty. Then a comparison is made between the conventional process and RDWC process, and it shows that 20.1%energy savings can be achieved by RDWC process. In addition, the dynamic characteristic of RDWC is studied and an effective control strategy is proposed. The simple PI control scheme with three temperature loops can obtain reasonable control performance and maintain products at de-sired purities. It is proved that this RDWC process is an energy efficiency alternative with good controllability. © 2016 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. Al rights reserved.

  19. A novel CE microchip with micro pillars column & double-L injection design for Capacitance Coupled Contactless Conductivity detection technology (United States)

    Wang, Yineng; Messina, Walter; Cao, Xi; Hogan, Anna; van Zalen, Ed; Moore, Eric


    This novel capillary electrophoresis microchip, or also known as μTAS (micro total analysis system) was designed to separate complex aqueous based compounds, similar to commercial CE & microchip (capillary electrophoresis) systems, but more compact. This system can be potentially used for mobile/portable chemical analysis equipment. Un-doped silicon wafer & ultra-thin borofloat glass (Pyrex) wafers have been used to fabricate the device. Double-L injection feature, micro pillars column, bypass separation channel & hybrid- referenced C4D electrodes were designed to achieve a high SNR (signal to noise ratio), easy- separation, for a durable and reusable μTAS for CE use.

  20. Design of thin-walled steel column with partially closed cross-section


    Veljkovic, Milan, ed. lit.; JOHANSSON, Bernt


    Cold formed sections can be optimized for different purposes and they are fairly inexpensive to produce in small series. They have an inherent weakness in their small torsional stiffness, which is unfavourable for columns. The solution presented here is to make closed section by adding a thin cover plate connected with self-tapping screws. It is here called a partially closed cross-section because it is not continuously and rigidly connected. The aim of this paper is to evaluate the efficienc...

  1. Design of Batch Distillation Columns Using Short-Cut Method at Constant Reflux

    Directory of Open Access Journals (Sweden)

    Asteria Narvaez-Garcia


    Full Text Available A short-cut method for batch distillation columns working at constant reflux was applied to solve a problem of four components that needed to be separated and purified to a mole fraction of 0.97 or better. Distillation columns with 10, 20, 30, 40, and 50 theoretical stages were used; reflux ratio was varied between 2 and 20. Three quality indexes were used and compared: Luyben’s capacity factor, total annual cost, and annual profit. The best combinations of theoretical stages and reflux ratio were obtained for each method. It was found that the best combinations always required reflux ratios close to the minimum. Overall, annual profit was the best quality index, while the best combination was a distillation column with 30 stages, and reflux ratio’s of 2.0 for separation of benzene (i, 5.0 for the separation of toluene (ii, and 20 for the separation of ethylbenzene (iii and purification of o-xylene (iv.

  2. An in vitro investigation into retention strength and fatigue resistance of various designs of tooth/implant supported overdentures. (United States)

    Fatalla, Abdalbseet A; Song, Ke; Du, Tianfeng; Cao, Yingguang


    Previously, the choice of prosthetic implant-retained overdentures has depended on data from previous studies about the retention-fatigue strength of the attachment system selected. Little or no data have been available on the correlation between the attachment system selected and the overdenture support configuration. The purpose of the present study was to evaluate the retention force and fatigue resistance of three attachment systems and four support designs of overdenture prosthesis. Four lower edentulous acrylic models were prepared and eight combinations of attachments groups were investigated in the study. These included: O-Rings with mini-dental implants (MDIs), Dalbo elliptic with Dalbo Rotex and fabricated flexible acrylic attachments with both MDI and Dalbo Rotex. The study was divided into four test groups: groups A and B, controls, and groups C and D, experimental groups. Control group A contained three overdenture supports: two free standing MDIs in the canine region and at the midline, and one simulated tooth root with Dalbo Rotex screwed in. Control group B contained four overdenture support foundations: two free standing MDIs in the right canine region and the first premolar region, and two simulated tooth roots with Dalbo Rotex screwed in at the same MDI position, but on the left side of the model. Experimental group C contained three overdenture support foundations: two free standing MDIs in the canine region and at the midline, and one simulated tooth root with MDI screwed in. Experimental group D contained four overdenture support foundations: two free standing MDIs in the right canine region and the first premolar region, and two simulated tooth roots with MDIs screwed in at the same MDI position, but on the left side of the model. Each group was further divided into two subgroups according to attachment type used. Five samples were prepared for each group. Retention force (N) values were recorded initially (0 cycles) and after 360, 720, 1440

  3. SHINE and Mini-SHINE Column Designs for Recovery of Mo from 140 g-U/L Uranyl Sulfate

    Energy Technology Data Exchange (ETDEWEB)

    Stepinski, Dominique C. [Argonne National Lab. (ANL), Argonne, IL (United States); Vandegrift, George F. [Argonne National Lab. (ANL), Argonne, IL (United States)


    Argonne is assisting SHINE Medical Technologies (SHINE) in their efforts to develop an accelerator-driven process that utilizes a uranyl-sulfate solution for the production of fission Mo-99. In an effort to design a Mo-recovery system for the SHINE project using low-enriched uranium (LEU), we conducted batch, breakthrough, and pulse tests to determine the Mo isotherm, mass-transfer zone (MTZ), and system parameters for a 130 g-U/L uranyl sulfate solution at pH 1 and 80°C, as described previously. The VERSE program was utilized to calculate the MTZ under various loading times and velocities. The results were then used to design Mo separation and recovery columns employing a pure titania sorbent (110-μm particles, S110, and 60 Å pore size). The plant-scale column designs assume Mo will be separated from 271 L of a 141 g-U/L uranyl sulfate solution, pH 1, containing 0.0023 mM Mo. The VERSE-designed recovery systems have been tested and verified in laboratory-scale experiments, and this approach was found to be very successful.

  4. A Design of a New Column-Parallel Analog-to-Digital Converter Flash for Monolithic Active Pixel Sensor. (United States)

    Chakir, Mostafa; Akhamal, Hicham; Qjidaa, Hassan


    The CMOS Monolithic Active Pixel Sensor (MAPS) for the International Linear Collider (ILC) vertex detector (VXD) expresses stringent requirements on their analog readout electronics, specifically on the analog-to-digital converter (ADC). This paper concerns designing and optimizing a new architecture of a low power, high speed, and small-area 4-bit column-parallel ADC Flash. Later in this study, we propose to interpose an S/H block in the converter. This integration of S/H block increases the sensitiveness of the converter to the very small amplitude of the input signal from the sensor and provides a sufficient time to the converter to be able to code the input signal. This ADC is developed in 0.18 μm CMOS process with a pixel pitch of 35 μm. The proposed ADC responds to the constraints of power dissipation, size, and speed for the MAPS composed of a matrix of 64 rows and 48 columns where each column ADC covers a small area of 35 × 336.76 μm(2). The proposed ADC consumes low power at a 1.8 V supply and 100 MS/s sampling rate with dynamic range of 125 mV. Its DNL and INL are 0.0812/-0.0787 LSB and 0.0811/-0.0787 LSB, respectively. Furthermore, this ADC achieves a high speed more than 5 GHz.

  5. The Design and Analysis of Split Row-Column Addressing Array for 2-D Transducer

    Directory of Open Access Journals (Sweden)

    Xu Li


    Full Text Available For 3-D ultrasound imaging, the row-column addressing (RCA with 2N connections for an N × N 2-D array makes the fabrication and interconnection simpler than the fully addressing with N2 connections. However, RCA degrades the image quality because of defocusing in signal channel direction in the transmit event. To solve this problem, a split row-column addressing scheme (SRCA is proposed in this paper. Rather than connecting all the elements in the signal channel direction together, this scheme divides the elements in the signal channel direction into several disconnected blocks, thus enables focusing beam access in both signal channel and switch channel directions. Selecting an appropriate split scheme is the key for SRCA to maintaining a reasonable tradeoff between the image quality and the number of connections. Various split schemes for a 32 × 32 array are fully investigated with point spread function (PSF analysis and imaging simulation. The result shows the split scheme with five blocks (4, 6, 12, 6, and 4 elements of each block can provide similar image quality to fully addressing. The splitting schemes for different array sizes from 16 × 16 to 96 × 96 are also discussed.

  6. Practical fire design of partially encased composite steel-concrete columns according to Eurocode 4

    Directory of Open Access Journals (Sweden)

    Sadaoui Arezki


    Full Text Available A practical method based on Campus-Massonet criteria which is developed initially to steel structures with combined compression and bending is adapted for the calculation of the buckling resistance of eccentrically loaded columns. The latter at room temperature or in fire situation is expressed by a simple formula as a function of an equivalent buckling coefficient taking into account the amount the eccentricity of the compressive applied load. The method proposed combines accuracy, efficiency and convenience obviating the need of M-N interaction diagrams and long iteration process. Otherwise, the estimation of the fire resistance for a given loading is made on the assumption based on the linearity with the level applied compressive load. It was found that the fire resistance of a column subjected to an eccentric load decreases gradually with the increase in the load level (ƞ , the slenderness ratio (λ or the amount of the eccentricity. For a fire resistance of one hour, time enough to evacuate the building of all its occupants, it recommended to use η≤ 0.5 and λ ≤45. The range of values of reinforcement cover (u suggested by Eurocode 4 leads to a better fire resistance except for u = 60 mm where there is a decline of the about 10%.

  7. Empowering employees with chronic diseases; development of an intervention aimed at job retention and design of a randomised controlled trial


    Heutink Annelies; de Vries Gabe; Varekamp Inge; van Dijk Frank JH


    Abstract Background Persons with a chronic disease are less often employed than healthy persons. If employed, many of them experience problems at work. Therefore, we developed a training programme aimed at job retention. The objective of this paper is to describe this intervention and to present the design of a study to evaluate its effectiveness. Development and description of intervention A systematic review, a needs assessment and discussions with Dutch experts led to a pilot group trainin...

  8. In-Vessel Retention Technology Development and Use for Advanced PWR Designs in the USA and Korea

    Energy Technology Data Exchange (ETDEWEB)

    T.G. Theofanous; S.J. Oh; J.H. Scobel


    In-Vessel Retention (IVR) of molten core debris by means of external reactor vessel flooding is a cornerstone of severe accident management for Westinghouse's AP600 (advanced passive light water reactor) design. The case for its effectiveness (made in previous work by the PI) has been thoroughly documented, reviewed as part of the licensing certification, and accepted by the US Nuclear Regulatory Commission. A successful IVR would terminate a severe accident, passively, with the core in a stable, coolable configuration (within the lower head), thus avoiding the largely uncertain accident evolution with the molten debris on the containment floor. This passive plant design has been upgraded by Westinghouse to the AP1000, a 1000 MWe plant very similar to the AP600. The severe accident management approach is very similar too, including In-Vessel Retention as the cornerstone feature, and initial evaluations indicated that this would be feasible at the higher power as well. A similar strategy is adopted in Korea for the APR1400 plant. The overall goal of this project is to provide experimental data and develop the necessary basic understanding so as to allow the robust extension of the AP600 In-Vessel Retention strategy for severe accident management to higher power reactors, and in particular, to the AP1000 advanced passive design.

  9. Design and simulation of a 30 kV, 60 kW electron optical column for melting applications

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, Sachin; Kandaswamy, E.; Bapat, A.V., E-mail: [Bhabha Atomic Research Centre, Mumbai (India)


    Electron beam offers unique advantages as a heat source for melting of refractory metals. It provides contamination free homogeneous melting with precise heat control on the melt target. This paper reports the complete electron optics design procedure for a 30 kV, 60 kW melting gun. The design objective of the electron optical column is to obtain the required power density on the target (10{sup 3}-10{sup 4} W/cm{sup 2}) using electrostatic and electromagnetic lenses. The design constrains are to minimize the high voltage discharges in the gun and beam losses in the beam transport. The challenging task of reducing the electrical discharges in the gun during high power melting with the help of twin electromagnetic lenses is presented in the paper. (author)


    Gibs, J.; Wicklund, A.; Suffet, I.H.


    The 'rule of thumb' that large volumes of water can be sampled for trace organic pollutants by XAD resin columns which are designed by small column laboratory studies or pure compounds is examined and shown to be a problem. A theory of multicomponent breakthrough is presented as a frame of reference to help solve the problem and develop useable criteria to aid the design of resin columns. An important part of the theory is the effect of humic substances on the breakthrough character of multicomponent chemical systems.

  11. Design of an epithermal column for BNCT based on D D fusion neutron facility (United States)

    Durisi, E.; Zanini, A.; Manfredotti, C.; Palamara, F.; Sarotto, M.; Visca, L.; Nastasi, U.


    Boron Neutron Capture Therapy (BNCT) is currently performed on patients at nuclear reactors. At the same time the international BNCT community is engaged in the development of alternative facilities for in-hospital treatments. This paper investigates the potential of a novel high-output D-D neutron generator, developed at Lawrence Berkeley National Laboratory (CA, USA), for BNCT. The simulation code MCNP-4C is used to realize an accurate study of the epithermal column in view of the treatment of deep tumours. Different materials and Beam Shaping Assemblies (BSA) are investigated and an optimized configuration is proposed. The neutron beam quality is defined by the standard free beam parameters, calculated averaging over the collimator aperture. The results are discussed and compared with the performances of other facilities.

  12. Development of a rapid design procedure for emergency repair of bridge columns using fiber-reinforced polymers


    Slater, Susan E.


    Fiber reinforced polymers (FRP) are increasingly used for seismic retrofit of undamaged bridge columns. The addition of a confining jacket increases overall strength and ductility of the column. However, FRPs can also be used for repair of a damaged bridge column after a seismic event. This research project explores the application of FRPs for retrofit of damaged circular columns. A decision tree for the emergency repair of damaged columns is presented. The decision tree aids field engineers ...

  13. Effect of system variables involved in packed column SFC of nevirapine as model analyte using response surface methodology: application to retention thermodynamics, solute transfer kinetic study and binary diffusion coefficient determination. (United States)

    Kaul, Neerej; Agrawal, Himani; Paradkar, A R; Mahadik, K R


    A multifactor optimization technique is successfully applied to study the effect of simultaneously varying the system variables on feasibility of nevirapine analysis by packed column supercritical fluid chromatography (PC-SFC). The optimal conditions were determined with the aid of the response surface methodology using 3(3) factorial designs. The method is based on methanol-modified carbon dioxide as the mobile phase at flow rate of 3.0 ml/min with elution through a JASCO Finepak SIL-5, [C18 (5-micron, 25 cm x 4.6 mm, i.d.)] column using photodiode array detection. The method has been successfully used to analyze commercial solid dosage form to assess the chromatographic performance of SFC system. The present work briefs the thermodynamic applications of PC-SFC with an emphasis on the results of nevirapine. The foremost of such applications is the determination of solute diffusion coefficient in supercritical mobile phase by Taylor-Aris peak broadening technique.

  14. Study of the retention and release of {sup 99m} Tc in several chromatographic columns through the elution with different solvents; Estudo da retencao e liberacao do tecnecio metaestavel ({sup 99m} Tc) em diversas colunas cromatograficas usando diferentes solventes

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Katia N.; Osso Junior, Joao A. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail:


    About 80% of the radiopharmaceuticals used in Nuclear Medicine is labelled with {sup 99m} Tc due to its physical properties such as short half-life of 6h, gamma photon emission of 140 keV and easy attainment through generators of {sup 99}Mo/{sup 99m} Tc. The Center of Radiopharmacy (CR) of the IPEN-CNEN/SP developed a type generator production of {sup 99}Mo/{sup 99m} Tc through the reaction {sup 98}Mo(n,a) {sup 99}Mo that it occurs in the nuclear reactor IEA-R1 of the IPEN-CNEN/SP, using the technique of elution of a gel of zirconium molybdate for the production of a MoZr gel type chromatographic generator. Although all the efforts used in the study of optimization of the conditions of preparation of the gel of MoZr, this generator possess a low to medium specific activity (925 MBq/mL) lower than the fission generator (1850 MBq/mL) used currently for the Brazilian medical costumers, as expected by this technology. The main objective of this work is the study of the retention and release of {sup 99m}-Tc in several chromatographic columns through the elution with different solvents. This is the first step for the attainment of a radioactive concentration of {sup 99m} Tc in order to attend the demand of the market without losing the quality and proving its clinical effectiveness. The initial results of adsorption and elution of {sup 99m} Tc from ion exchanging columns with different solvents will be presented. (author)

  15. Introduction of prognostic rain in ECHAM5: design and single column model simulations (United States)

    Posselt, R.; Lohmann, U.


    Prognostic equations for the rain mass mixing ratio and the rain drop number concentration are introduced into the large-scale cloud microphysics parameterization of the ECHAM5 general circulation model (ECHAM5-PROG). To this end, a rain flux from one level to the next with the appropriate fall speed is introduced. This maintains rain water in the atmosphere to be available for the next time step. Rain formation in ECHAM5-PROG is, therefore, less dependent on the autoconversion rate than the standard ECHAM5 but shifts the emphasis towards the accretion rates in accordance with observations. ECHAM5-PROG is tested and evaluated with Single Column Model (SCM) simulations for two cases: the marine stratocumulus study EPIC (October 2001) and the continental mid-latitude ARM Cloud IOP (shallow frontal cloud case - March 2000). In case of heavy precipitation events, the prognostic equations for rain hardly affect the amount and timing of precipitation at the surface in different SCM simulations because heavy rain depends mainly on the large-scale forcing. In case of thin, drizzling clouds (i.e., stratocumulus), surface precipitation is sensitive to the number of sub-time steps used in the prognostic rain scheme. Cloud microphysical quantities, such as cloud liquid and rain water within the atmosphere, are sensitive to the number of sub-time steps in both considered cases. This results from the decreasing autoconversion rate and increasing accretion rate.

  16. Introduction of prognostic rain in ECHAM5: design and Single Column Model simulations

    Directory of Open Access Journals (Sweden)

    R. Posselt


    Full Text Available Prognostic equations for the rain mass mixing ratio and the rain drop number concentration are introduced into the large-scale cloud microphysics parameterization of the ECHAM5 general circulation model (ECHAM5-RAIN. For this a rain flux from one level to the next with the appropriate fall speed is introduced. This maintains rain water in the atmosphere to be available for the next time step. Rain formation in ECHAM5-RAIN is, therefore, less dependent on the autoconversion rate than the standard ECHAM5 but shifts the emphasis towards the accretion rates in accordance with observations. ECHAM5-RAIN is tested and evaluated with two cases: the continental mid-latitude ARM Cloud IOP (shallow frontal cloud case – March 2000 and EPIC (a marine stratocumulus study – October 2001. The prognostic equations for rain hardly affect the amount and timing of precipitation at the surface in different Single Column Model (SCM simulations for heavy precipitating clouds because heavy rain depends mainly on the large-scale forcing. In case of thin, drizzling clouds (i.e., stratocumulus, an increase in surface precipitation is caused by more sub-time steps used in the prognostic rain scheme until convergence is reached. Cloud microphysical quantities, such as liquid and rain water, are more sensitive to the number of sub-time steps for light precipitation. This results from the decreasing autoconversion rate and increasing accretion rate.

  17. Introduction of prognostic rain in ECHAM5: design and single column model simulations

    Directory of Open Access Journals (Sweden)

    R. Posselt


    Full Text Available Prognostic equations for the rain mass mixing ratio and the rain drop number concentration are introduced into the large-scale cloud microphysics parameterization of the ECHAM5 general circulation model (ECHAM5-PROG. To this end, a rain flux from one level to the next with the appropriate fall speed is introduced. This maintains rain water in the atmosphere to be available for the next time step. Rain formation in ECHAM5-PROG is, therefore, less dependent on the autoconversion rate than the standard ECHAM5 but shifts the emphasis towards the accretion rates in accordance with observations. ECHAM5-PROG is tested and evaluated with Single Column Model (SCM simulations for two cases: the marine stratocumulus study EPIC (October 2001 and the continental mid-latitude ARM Cloud IOP (shallow frontal cloud case – March 2000. In case of heavy precipitation events, the prognostic equations for rain hardly affect the amount and timing of precipitation at the surface in different SCM simulations because heavy rain depends mainly on the large-scale forcing. In case of thin, drizzling clouds (i.e., stratocumulus, surface precipitation is sensitive to the number of sub-time steps used in the prognostic rain scheme. Cloud microphysical quantities, such as cloud liquid and rain water within the atmosphere, are sensitive to the number of sub-time steps in both considered cases. This results from the decreasing autoconversion rate and increasing accretion rate.

  18. Variables influencing the retention of designated employees in a platinum mine / Carla Radloff


    Radloff, Carla


    Retention of key employees is becoming an increasingly important challenge faced by many organisations. With every employee that leaves the company, cost of recruitment and appointment, as well as training and development cost subsequent to that, are lost. The situation is aggravated by the fact that it is usually the higher performing employee who is more mobile from a career point of view, or the employee who has completed his/her training and who is more marketable, that is ...

  19. Robust Transceiver Design for AF MIMO Relay Systems with Column Correlations

    CERN Document Server

    Xing, Chengwen; Wu, Yik-Chung; Ma, Shaodan; Kuang, Jingming


    In this paper, we investigate the robust transceiver design for dual-hop amplify-and-forward (AF) MIMO relay systems with Gaussian distributed channel estimation errors. Aiming at maximizing the mutual information under imperfect channel state information (CSI), source precoder at source and forwarding matrix at the relay are jointly optimized. Using some elegant attributes of matrix-monotone functions, the structures of the optimal solutions are derived first. Then based on the derived structure an iterative waterfilling solution is proposed. Several existing algorithms are shown to be special cases of the proposed solution. Finally, the effectiveness of the proposed robust design is demonstrated by simulation results.

  20. The influence of design parameters on clogging of stormwater biofilters: a large-scale column study. (United States)

    Le Coustumer, Sébastien; Fletcher, Tim D; Deletic, Ana; Barraud, Sylvie; Poelsma, Peter


    A large-scale laboratory study was conducted to test the influence of design and operating conditions on the lifespan of stormwater biofilters. The evolution of hydraulic conductivity over time was studied in relation to a number of key design parameters (media type, filter depth, vegetation type, system sizing, etc). The biofilters were observed to clog over time, with average hydraulic conductivity decreasing by a factor of 3.6 over the 72 weeks of testing. The choice of plant species appears to have a significant effect on the rate of decrease in permeability, with plants with thick roots (e.g. Melaleuca) demonstrating an ability to maintain permeability over time. Other species studied, with finer roots, had no such beneficial effects. As expected, small systems relative to their catchment (and thus which are subjected to high loading rates) are more prone to clogging, as increases in hydraulic and sediment loading can lead to extremely low hydraulic conductivities. Sizing and the appropriate choice of vegetation are thus key elements in design because they can limit clogging, and therefore, indirectly increase annual load treated by limiting the volume of water bypassing the system.

  1. Retention of Information as a Function of Lesson Design for Middle School Studies of Wetlands in New Jersey (United States)

    Parsekian, A.; Cimiluca, C.; Gates, A. E.; Calderon, I.


    Considering the breadth of innovative teaching strategies available, it is helpful to identify which will be best suited for a particular subject. With students that have a variety of interests, it is important to engage as many as possible in the lab activity, especially those who might not identify science as their preferred interest. Here we test the retention of information by middle school students after a problem-based learning (PBL) style lesson compared with an investigation where the students were given no role-playing problem. Both lessons were designed around wetlands in New Jersey: the first being a pond-edge ecosystem in a park near the middle school in Newark, NJ that the students are familiar with and the second being small, isolated peat bogs in the Pinelands of southern New Jersey that are the subject of ongoing scientific research. Days after both hands-on lessons, the students were given short, carefully designed multiple choice quizzes that tested the retention of knowledge about each of the learning objectives set forth. Results of the quizzes are nearly normally distributed, indicating a similar average performance. A higher number of students preformed better on the problem-based learning post-quiz suggesting the inclusion of a role playing scenario is useful for engaging the most students in hands-on wetlands laboratory experiments. Future work should test the retention of this type of information over time and explore other teaching strategies. We also present new ideas for an inexpensive hands-on lesson as implemented for the peat bog wetlands example that introduces basic soil science concepts to middle school and high school students.

  2. 连续梁墩柱合理设计的影响因素分析%Factor Analysis of Continuous Beam Pier Columns Rational Design

    Institute of Scientific and Technical Information of China (English)

    张帅; 肖锋文; 赵杰丽


    随着连续梁桥的广泛应用,连续梁桥墩柱的合理设计值得深入研究.从影响连续梁桥墩柱设计的主要因素出发,深入分析各影响因素的重要性,为连续梁桥墩柱合理设计提供参考.%With the wide application of the continuous beam bridge, the rational design of continuous beam pier column worthy of further study. In this article, starting from the main factors affecting the continuous beam bridge pier column design. In-depth analysis of the importance of each factor in order to give reference for the rational design of continuous beam bridge pier column.

  3. Reading Columns


    Coutts, Marion


    Reading Columns are twin permanent public sculptures commissioned as part of a £245m scheme for the redevelopment of the Chatham Place area in Reading. Dimensions: 3.5m high x 1.3m diameter each Field of knowledge: The work consists of twin bespoke columns of stainless steel and glass over digital colour transparencies. The piece revisits and reworks the idea of the Morris Column, a 19th C feature characteristic of major European metropolitan centres. A wraparound image on each of ...

  4. Quality by design approach for the separation of naproxcinod and its related substances by fused core particle technology column. (United States)

    Inugala, Ugandar Reddy; Pothuraju, Nageswara Rao; Vangala, Ranga Reddy


    This paper describes the development of a rapid, novel, stability-indicating gradient reversed-phase high-performance liquid chromatographic method and associated system suitability parameters for the analysis of naproxcinod in the presence of its related substances and degradents using a quality-by-design approach. All of the factors that affect the separation of naproxcinod and its impurities and their mutual interactions were investigated and robustness of the method was ensured. The method was developed using an Ascentis Express C8 150 × 4.6 mm, 2.7 µm column with a mobile phase containing a gradient mixture of two solvents. The eluted compounds were monitored at 230 nm, the run time was 20 min within which naproxcinod and its eight impurities were satisfactorily separated. Naproxcinod was subjected to the stress conditions of oxidative, acid, base, hydrolytic, thermal and photolytic degradation. Naproxcinod was found to degrade significantly in acidic and basic conditions and to be stable in thermal, photolytic, oxidative and aqueous degradation conditions. The degradation products were satisfactorily resolved from the primary peak and its impurities, proving the stability-indicating power of the method. The developed method was validated as per International Conference on Harmonization guidelines with respect to specificity, linearity, limit of detection, limit of quantification, accuracy, precision and robustness.

  5. Mathematical Simulation and Design of Three-Phase Bubble Column Reactor for Direct Synthesis of Dimethyl Ether from Syngas

    Institute of Scientific and Technical Information of China (English)

    Dianhua Liu; Xing Hua; Dingye Fang


    A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether (DME) from syngas, considering both the influence of part inert carrier backmixing on transfer and the influence of catalyst grain sedimentation on reaction. On the basis of this model, the influences of the size and reaction conditions of a 100000 t/a DME reactor on capacity were investigated. The optimized size of the 10000 t/a DME synthesis reactor was proposed as follows: diameter 3.2 m, height 20 m, built-in 400 tube heat exchanger (φ 38×2 mm),and inert heat carrier paraffin oil 68 t and catalyst 34.46 t. Reaction temperature and pressure were important factors influencing the reaction conversion for different size reactors. Under the condition of uniform catalyst concentration distribution, higher pressure and temperature were proposed to achieve a higher production capacity of DME. The best ratio of fresh syngas for DME synthesis was 2.04.

  6. The effect of denture design and fixatives on the retention of mandibular complete dentures tested on a novel in-vitro edentulous model. (United States)

    Johnson, A; Al-Kaisy, N; Miller, C A; Martin, N


    The aim of this study was to evaluate the effect of the design (extension and adaptation) of a mandibular complete acrylic denture and the use of denture adhesives using a novel in-vitro edentulous model. The model is a highly anatomically accurate replica based on a moderately resorbed human mandibular edentulous arch. The model has been designed and fabricated by means of an elaborate clinical and technical process that employs synthetic elastomeric materials with properties that attempts to reproduce in-vitro characteristics of the soft tissues overlying the ridges and immediate reflected tissues. This model was used to measure and compare the retention of mandibular dentures ofvarying designs (well-fitting, over- and under-extended) with and without the aid of denture fixatives. Retention tests were conducted with different volumes of artificial saliva at a cross head speed of 50 mm/min with 4 equidistant holding points on the denture occlusal surface, using a universal tensile testing machine in an axial pull direction. The effect of three denture adhesives on denture retention was also tested on the same denture types at different times over a period of 5 hours and beyond. The in-vitro model presented can be effectively used to test the retention of mandibular complete dentures. The speed of dislodgement force and amount of saliva are important variables in mandibular denture retention. The retention of well-fitting dentures was statistically higher than that of ill-fitting dentures. A significantly higher retention force was needed to dislodge mandibular dentures (well and ill-fitting dentures) when using a denture adhesive.

  7. Compact electron beam focusing column

    Energy Technology Data Exchange (ETDEWEB)

    Persaud, Arun; Leung, Ka-Ngo; Reijonen, Jani


    A novel design for an electron beam focusing column has been developed at LBNL. The design is based on a low-energy spread multicusp plasma source which is used as a cathode for electron beam production. The focusing column is 10 mm in length. The electron beam is focused by means of electrostatic fields. The column is designed for a maximum voltage of 50 kV. Simulations of the electron trajectories have been performed by using the 2-D simulation code IGUN and EGUN. The electron temperature has also been incorporated into the simulations. The electron beam simulations, column design and fabrication will be discussed in this presentation.

  8. The Ticket to Retention: A Classroom Assessment Technique Designed to Improve Student Learning (United States)

    Divoll, Kent A.; Browning, Sandra T.; Vesey, Winona M.


    Classroom assessment techniques (CATs) or other closure activities are widely promoted for use in college classrooms. However, research on whether CATs improve student learning are mixed. The authors posit that the results are mixed because CATs were designed to "help teachers find out what students are learning in the classroom and how well…

  9. Predicting infiltration and pollutant retention in sustainable drainage systems: Experiments, modelling and design


    Quinn, Ruth; Dussaillant, Alejandro


    A major problem of increasing urbanization is the rise in pollution caused by runoff, affecting water quality directly and due to combined sewer overflows. Among alternative strategies, Sustainable Drainage Systems (SuDS) such as rain gardens and other bioretention facilities is becoming more widespread. Previous research has focused primarily on hydrologic design, including the degree to which groundwater is replenished by these systems, and models have been developed to quantify the extent ...

  10. PULSE COLUMN (United States)

    Grimmett, E.S.


    This patent covers a continuous countercurrent liquidsolids contactor column having a number of contactor states each comprising a perforated plate, a layer of balls, and a downcomer tube; a liquid-pulsing piston; and a solids discharger formed of a conical section at the bottom of the column, and a tubular extension on the lowest downcomer terminating in the conical section. Between the conical section and the downcomer extension is formed a small annular opening, through which solids fall coming through the perforated plate of the lowest contactor stage. This annular opening is small enough that the pressure drop thereacross is greater than the pressure drop upward through the lowest contactor stage. (AEC)

  11. Column: lef

    NARCIS (Netherlands)

    Reep, Frans van der


    1e alinea column: Ook in je beleggingsbeslissingen is het voor echte performance wellicht tijd om eens voorbij best practices (dan word je namelijk hoogstens tweede) te kijken naar next practices. Als je op zeker speelt, verdien je weinig geld. Want anderen gingen je al voor. Maar kun je nog meer op

  12. The Design and Development of a Regenerative Separatory Column Using Calixarenes as a Polymeric Backbone for the Purification of Water from Urine (United States)

    Polk, M.


    The objective of this research project is to design calixarenes, cup-shaped molecules, with the specific binding sites to the sodium chloride and nitrogen containing components of urine, such as urea and uric acid, in urine. The following partition of the research accomplishes this objective: (1) functionalization of calixarene, (2) development of a calixarene based medium for the separatory process, (3) design of the column regeneration protocol. Work was also accomplished in the area of temperature sensitive paint (TSP). Research was undertaken to design a TSP with insulating propertites. An important part of this research project is to discover the thermal conductivity of polymers for TSP.

  13. Utilização do índice de retenção linear para caracterização de compostos voláteis em café solúvel utilizando GC-MS e coluna HP-Innowax Linear retention index for characterization of volatile compounds in soluble coffee using GC-MS and HP-Innowax column

    Directory of Open Access Journals (Sweden)

    Marcelo Caldeira Viegas


    Full Text Available Gas chromatography coupled with mass spectrometry (GC-MS is widely used for the characterization of volatile compounds. However, due to the complexity of the soluble coffee matrix, a complete identification of the components should not be based on mass spectra interpretation only. The linear index of retention (LRI is frequently used to give support to mass spectra. The aim of this work is to investigate the characterization of the volatile compounds in soluble coffee samples by GC-MS using LRI values found with a HP-INNOWAX column. The method used allows a significant increase of the reliability of identifying compounds.

  14. Empowering employees with chronic diseases; development of an intervention aimed at job retention and design of a randomised controlled trial (United States)

    Varekamp, Inge; de Vries, Gabe; Heutink, Annelies; van Dijk, Frank JH


    Background Persons with a chronic disease are less often employed than healthy persons. If employed, many of them experience problems at work. Therefore, we developed a training programme aimed at job retention. The objective of this paper is to describe this intervention and to present the design of a study to evaluate its effectiveness. Development and description of intervention A systematic review, a needs assessment and discussions with Dutch experts led to a pilot group training, tested in a pilot study. The evaluation resulted in the development of a seven-session group training combined with three individual counselling sessions. The training is based on an empowerment perspective that aims to help individuals enhance knowledge, skills and self-awareness. These advances are deemed necessary for problem solving in three stages: exploration and clarification of work related problems, communication at the workplace, and development and implementation of solutions. Seven themes are discussed and practised in the group sessions: 1) Consequences of a chronic disease in the workplace, 2) Insight into feelings and thoughts about having a chronic disease, 3) Communication in daily work situations, 4) Facilities for disabled employees and work disability legislation, 5) How to stand up for oneself, 6) A plan to solve problems, 7) Follow-up. Methods Participants are recruited via occupational health services, patient organisations, employers, and a yearly national conference on chronic diseases. They are eligible when they have a chronic physical medical condition, have a paid job, and experience problems at work. Workers on long-term, 100% sick leave that is expected to continue during the training are excluded. After filling in the baseline questionnaire, the participants are randomised to either the control or the intervention group. The control group will receive no care or care as usual. Post-test mail questionnaires will be sent after 4, 8, 12 and 24 months

  15. Empowering employees with chronic diseases; development of an intervention aimed at job retention and design of a randomised controlled trial. (United States)

    Varekamp, Inge; de Vries, Gabe; Heutink, Annelies; van Dijk, Frank J H


    Persons with a chronic disease are less often employed than healthy persons. If employed, many of them experience problems at work. Therefore, we developed a training programme aimed at job retention. The objective of this paper is to describe this intervention and to present the design of a study to evaluate its effectiveness. DEVELOPMENT AND DESCRIPTION OF INTERVENTION: A systematic review, a needs assessment and discussions with Dutch experts led to a pilot group training, tested in a pilot study. The evaluation resulted in the development of a seven-session group training combined with three individual counselling sessions. The training is based on an empowerment perspective that aims to help individuals enhance knowledge, skills and self-awareness. These advances are deemed necessary for problem solving in three stages: exploration and clarification of work related problems, communication at the workplace, and development and implementation of solutions. Seven themes are discussed and practised in the group sessions: 1) Consequences of a chronic disease in the workplace, 2) Insight into feelings and thoughts about having a chronic disease, 3) Communication in daily work situations, 4) Facilities for disabled employees and work disability legislation, 5) How to stand up for oneself, 6) A plan to solve problems, 7) Follow-up. Participants are recruited via occupational health services, patient organisations, employers, and a yearly national conference on chronic diseases. They are eligible when they have a chronic physical medical condition, have a paid job, and experience problems at work. Workers on long-term, 100% sick leave that is expected to continue during the training are excluded. After filling in the baseline questionnaire, the participants are randomised to either the control or the intervention group. The control group will receive no care or care as usual. Post-test mail questionnaires will be sent after 4, 8, 12 and 24 months. Primary outcome

  16. Empowering employees with chronic diseases; development of an intervention aimed at job retention and design of a randomised controlled trial

    Directory of Open Access Journals (Sweden)

    Heutink Annelies


    Full Text Available Abstract Background Persons with a chronic disease are less often employed than healthy persons. If employed, many of them experience problems at work. Therefore, we developed a training programme aimed at job retention. The objective of this paper is to describe this intervention and to present the design of a study to evaluate its effectiveness. Development and description of intervention A systematic review, a needs assessment and discussions with Dutch experts led to a pilot group training, tested in a pilot study. The evaluation resulted in the development of a seven-session group training combined with three individual counselling sessions. The training is based on an empowerment perspective that aims to help individuals enhance knowledge, skills and self-awareness. These advances are deemed necessary for problem solving in three stages: exploration and clarification of work related problems, communication at the workplace, and development and implementation of solutions. Seven themes are discussed and practised in the group sessions: 1 Consequences of a chronic disease in the workplace, 2 Insight into feelings and thoughts about having a chronic disease, 3 Communication in daily work situations, 4 Facilities for disabled employees and work disability legislation, 5 How to stand up for oneself, 6 A plan to solve problems, 7 Follow-up. Methods Participants are recruited via occupational health services, patient organisations, employers, and a yearly national conference on chronic diseases. They are eligible when they have a chronic physical medical condition, have a paid job, and experience problems at work. Workers on long-term, 100% sick leave that is expected to continue during the training are excluded. After filling in the baseline questionnaire, the participants are randomised to either the control or the intervention group. The control group will receive no care or care as usual. Post-test mail questionnaires will be sent after 4, 8

  17. Effect of differing PowerPoint slide design on multiple-choice test scores for assessment of knowledge and retention in a theriogenology course. (United States)

    Root Kustritz, Margaret V


    Third-year veterinary students in a required theriogenology diagnostics course were allowed to self-select attendance at a lecture in either the evening or the next morning. One group was presented with PowerPoint slides in a traditional format (T group), and the other group was presented with PowerPoint slides in the assertion-evidence format (A-E group), which uses a single sentence and a highly relevant graphic on each slide to ensure attention is drawn to the most important points in the presentation. Students took a multiple-choice pre-test, attended lecture, and then completed a take-home assignment. All students then completed an online multiple-choice post-test and, one month later, a different online multiple-choice test to evaluate retention. Groups did not differ on pre-test, assignment, or post-test scores, and both groups showed significant gains from pre-test to post-test and from pre-test to retention test. However, the T group showed significant decline from post-test to retention test, while the A-E group did not. Short-term differences between slide designs were most likely unaffected due to required coursework immediately after lecture, but retention of material was superior with the assertion-evidence slide design.

  18. Dynamics and control designs for internal thermally coupled distillation columns with different purities, Part 1: Open loop dynamic behaviors

    Institute of Scientific and Technical Information of China (English)


    The open loop dynamic behaviors of internal thermally coupled distillation column with four different purities (low-,moderate-, high- and very high-purity) are studied. These dynamic behaviors are characterized by strong asymmetric non-linearity, high sensitivity to operation conditions change and distinct inverse response. With the increase of purity, these dynamic behaviors are intensified and become more complex, which easily lead to the mismatch between linear model and plant and also change the relationship between manipulated and controlled variables.

  19. 新型双柱立式车床设计与实验%Design and Experiment of the New Double Column Vertical Lathe

    Institute of Scientific and Technical Information of China (English)

    杨振宇; 王勇; 黄绍伟; 刘发英


    Aiming at the traditional double column vertical lathe has the problems of the complex structure,column heavy and bulky beam,the speed of the rotary table can not be further improved,and so on,a new type of double column vertical lathe was designed to satisfy the premise of performance requirements in same applications.By the evaluation index as the values of the straightness,circle run-out,flatness and surface roughness of the processed part,the parts to be measured were processed for roughing and semi-finishing with the new double column vertical lathe and the same specifications of traditional double column vertical lathe C6235,the processed parts quality was analyzed comparatively.Result shows that the quality of roughing machine parts of the new double column vertical lathe is lower than that of the ordinary double column vertical lathe,but it can meet the necessary requirements of machining accuracy for vertical lathe machining parts.The quality of semi-finishing machine parts with the new double column vertical lathe is better than that of the ordinary double column vertical lathe.Therefore,the application of the new double column vertical lathe has good prospects.%在满足相同使用性能要求的前提下,针对传统双柱立式车床存在结构复杂、立柱和横梁笨重以及回转工作台转速无法进一步提高等情况,设计了新型双柱立式车床.以被加工工件的直线度、圆跳动、平面度和表面粗糙度值为评价指标,使用新型双柱立式车床和同规格的传统C6235双柱立式车床对被测零件进行粗加工和半精加工,然后对加工后零件质量进行比较分析.结果显示使用新型双柱立式车床粗加工后的零件质量低于普通双柱立式车床加工后的零件质量,但能够满足立式车床加工零件后所需达到的加工精度要求,半精加工后的零件质量优于普通双柱立式车床加工后的零件质量.因此新型双柱立式车床具有较好的应用前景.

  20. Slender CRC Columns

    DEFF Research Database (Denmark)

    Aarup, Bendt; Jensen, Lars Rom; Ellegaard, Peter


    CRC is a high-performance steel fibre reinforced concrete with a typical compressive strength of 150 MPa. Design methods for a number of structural elements have been developed since CRC was invented in 1986, but the current project set out to further investigate the range of columns for which...

  1. 隔壁塔设计与控制的研究进展%Progress in design method and controllability of dividing wall column

    Institute of Scientific and Technical Information of China (English)

    胡雨奇; 方静; 李春利


    隔壁塔作为一种利用完全热耦合技术的精馏塔,其在一个塔壳内实现多组分的清晰分离,避免了在常规精馏塔序列中出现的返混现象,具有热力学效率高、能耗低、投资费用低等优点。着重阐述了隔壁塔在设计与控制方面的研究进展,包括初值估算设计、严格模拟设计、优化设计、控制方案、参数控制操作性等,指出在模拟和应用中隔壁塔的设计与控制存在的问题及后续研究的方向。%Dividing wall column is one kind of distillation column applying fully thermally coupled technology. It can sepa-rate multi-components sharply in one shell and avoid the remixing phenomenon appeared in the conventional distillation sequences. It has the advantage of high thermodynamic efficiency, low energy consumption and low equipment investment. In this paper, the progress in design method and controllability of dividing wall column is reviewed, including the initial estimate design, rigorous simulation design, optimal design, control schemes, operability of controlled parameters. The problems of design method and controllability in simulation and practice are pointed out, which provides the reference for further researches.

  2. Enhancing retention of partial dentures using elastomeric retention rings

    Directory of Open Access Journals (Sweden)

    Kakkirala Revathi


    Full Text Available This report presents an alternative method for the retention of partial dentures that relies on the engagement of tooth undercuts by a lining material. The lab procedures are also presented. A new maxillary and mandibular acrylic partial dentures were fabricated using elastomeric retention technique for a partially dentate patient. A partially dentate man reported difficulty in retaining his upper removable partial denture (RPD. The maxillary RPD was designed utilizing elastomeric retention technique. During follow-up, it was necessary to replace the retention rings due to wear. The replacement of the retention rings, in this case, was done through a chairside reline technique. Elastomeric retention technique provides exceptionally good retention can be indicated to stabilize, cushion, splint periodontally involved teeth, no enough undercut for clasps, eliminate extractions, single or isolated teeth.

  3. Rapid Method Development in Hydrophilic Interaction Liquid Chromatography for Pharmaceutical Analysis Using a Combination of Quantitative Structure-Retention Relationships and Design of Experiments. (United States)

    Taraji, Maryam; Haddad, Paul R; Amos, Ruth I J; Talebi, Mohammad; Szucs, Roman; Dolan, John W; Pohl, Chris A


    A design-of-experiment (DoE) model was developed, able to describe the retention times of a mixture of pharmaceutical compounds in hydrophilic interaction liquid chromatography (HILIC) under all possible combinations of acetonitrile content, salt concentration, and mobile-phase pH with R(2) > 0.95. Further, a quantitative structure-retention relationship (QSRR) model was developed to predict retention times for new analytes, based only on their chemical structures, with a root-mean-square error of prediction (RMSEP) as low as 0.81%. A compound classification based on the concept of similarity was applied prior to QSRR modeling. Finally, we utilized a combined QSRR-DoE approach to propose an optimal design space in a quality-by-design (QbD) workflow to facilitate the HILIC method development. The mathematical QSRR-DoE model was shown to be highly predictive when applied to an independent test set of unseen compounds in unseen conditions with a RMSEP value of 5.83%. The QSRR-DoE computed retention time of pharmaceutical test analytes and subsequently calculated separation selectivity was used to optimize the chromatographic conditions for efficient separation of targets. A Monte Carlo simulation was performed to evaluate the risk of uncertainty in the model's prediction, and to define the design space where the desired quality criterion was met. Experimental realization of peak selectivity between targets under the selected optimal working conditions confirmed the theoretical predictions. These results demonstrate how discovery of optimal conditions for the separation of new analytes can be accelerated by the use of appropriate theoretical tools.

  4. Using theory and formative research to design interventions to improve community health worker motivation, retention and performance in Mozambique and Uganda


    Strachan, DL; Källander, K; Nakirunda, M; Ndima, S.; Muiambo, A.; Hill, Z; InSCALE Study Group, (incd. Kirkwood, B; Soremekun, S; Vassall, A.


    Background Community health workers (CHWs) are increasingly being used in low-income countries to address human resources shortages, yet there remain few effective, evidence-based strategies for addressing the enduring programmatic constraints of worker motivation, retention and performance. This paper describes how two interventions were designed by the Innovations at Scale for Community Access and Lasting Effects (inSCALE) project to address these constraints in Uganda and Mozambique drawin...

  5. Using theory and formative research to design interventions to improve community health worker motivation, retention and performance in Mozambique and Uganda


    Strachan, D. L.; Hill, Z; Källander, K; Nakirunda, M; Ndima, S.; Muiambo, A.


    Background: Community health workers (CHWs) are increasingly being used in low-income countries to address human resources shortages, yet there remain few effective, evidence-based strategies for addressing the enduring programmatic constraints of worker motivation, retention and performance. This paper describes how two interventions were designed by the Innovations at Scale for Community Access and Lasting Effects (inSCALE) project to address these constraints in Uganda and Mozambique drawi...

  6. An Undergraduate Column Chromatography Experiment. (United States)

    Danot, M.; And Others


    Background information, list of materials needed, and procedures used are provided for an experiment designed to introduce undergraduate students to the theoretical and technical aspects of column chromatography. The experiment can also be shortened to serve as a demonstration of the column chromatography technique. (JN)

  7. Upgrading Design of Non-column Awning of Shenyangbei Station%浅析沈阳北站无站台柱雨篷改造设计

    Institute of Scientific and Technical Information of China (English)



    以沈阳北站改造工程为例,分析沈阳北站既有无站台柱雨篷的现状和存在的问题,研究在对其进行更新改造的设计过程中,采用增加既有雨篷屋面板覆盖范围来改善既有雨篷的防飘雨雪效果,采用增设与既有雨篷同弧度、同材质的新增雨篷来实现既有与新建部分一体化设计的目的,再通过这两种设计手法的可行性,来总结一些富有一定前瞻性的无站台柱雨篷的改造策略。%The author, by taking Shenyangbei station reconstruction project as an example, analyzes the status quo and existing problems of Shenyangbei station relating to non-column awning, and studies the upgrading issues during the design by increasing awning roofing board coverage to improve the existing cozy snow prevention effect, and by adding new awning to the existing one with same arch and same material to form an integrated design. Furthermore, the feasibilities of these two designs are analyzed to formulate forward-looking strategies for upgrading non-column awning.

  8. On the Design and Innovation of Academic Columns%浅议学术期刊的栏目策划与创新

    Institute of Scientific and Technical Information of China (English)



    面时市场经济的激烈竞争与办刊环境的变化,学术期刊要提高竞争力,彰显期刊的特色,必须在坚持学术性的前提下,加强刊物的个性策划,实现栏目创新。做好栏目策划是提高期刊质量,彰显期刊特色的重要环节。在学术期刊的栏目策划中应处理好深度与广度、冷点与热点、传承与创新、个性与整体的关系。%A journal musl has its own special designs and new columns. Only that, the journal can have a strong competition faced with the serever market economy competition and changes of environment. Good design of a column is an important part of better quality and feature. When designing, the relationships should be cared between depth and width, cold and hot point, heritage and newness and individual and wholeness.

  9. The CGILS experimental design to investigate low cloud feedbacks in general circulation models by using single-column and large-eddy simulation models (United States)

    Zhang, Minghua; Bretherton, Christopher S.; Blossey, Peter N.; Bony, Sandrine; Brient, Florent; Golaz, Jean-Christophe


    A surrogate climate change is designed to investigate low cloud feedbacks in the northeastern Pacific by using Single Column Models (SCMs), Cloud Resolving Models (CRMs), and Large Eddy Simulation models (LES), as part of the CGILS study (CFMIP-GASS Intercomparison of LES and SCM models). The constructed large-scale forcing fields, including subsidence and advective tendencies, and their perturbations in the warmer climate are shown to compare well with conditions in General Circulation Models (GCMs), but they are free from the impact of any GCM parameterizations. The forcing fields in the control climate are also shown to resemble the mean conditions in the ECMWF-Interim Reanalysis. Applications of the forcing fields in SCMs are presented. It is shown that the idealized design can offer considerable insight into the mechanisms of cloud feedbacks in the models. Caveats and advantages of the design are also discussed.

  10. 双导柱运卷小车设计方法分析%Analysis of Design Method of Double Column Coil Car

    Institute of Scientific and Technical Information of China (English)



    Combined with a case study, the paper analyzed design proposal of typical guide column coil car; it discussed design selection, functional configuration and design method of mechanical and structural parameters;it demonstrated essential calculation and verification for key parts.%文章通过实例,对一种典型的导柱式运卷小车的设计方案进行分析,论述了运卷小车的选型、功能配置以及力能参数与结构参数的设计方法,并对关键零部件进行必要的校核和验算。

  11. The Application of Aspen Plus in the Design of Distillation Column%流程模拟软件Aspen Plus在精馏塔设计中的应用

    Institute of Scientific and Technical Information of China (English)

    李峰; 赵新堂; 万宝锋


    The simple design and rigorous accounting on the distillation column has been performed by Aspen Plus in this paper. Also, the analysis of the influence factors on the design of distillation column was completed. In addition, the economic accounting of distillation column was discussed preliminarily.%以Aspen Plus流程模拟软件对精馏塔进行了简捷设计和严格核算,对精馏塔设计的影响因素进行了分析,并对精馏塔的经济核算进行了初步说明。

  12. Quality of Research Design Moderates Effects of Grade Retention on Achievement: A Meta-Analytic, Multilevel Analysis (United States)

    Allen, Chiharu S.; Chen, Qi; Willson, Victor L.; Hughes, Jan N.


    The present meta-analysis examines the effect of grade retention on academic outcomes and investigates systemic sources of variability in effect sizes. Using multilevel modeling (MLM), the authors investigate characteristics of 207 effect sizes across 22 studies published between 1990 and 2007 at two levels: the study (between) and individual…

  13. Supporting "Slumping" Sophomores: Programmatic Peer Initiatives Designed to Enhance Retention in the Crucial Second Year of College (United States)

    Sanchez-Leguelinel, Caridad


    Previous research and retention interventions have been primarily targeted towards the freshmen, first-year experience (Gardner, Pattengale, & Schreiner, 2000; Pattengale & Schreiner, 2000) and yet, sophomores are a uniquely vulnerable group with increasing levels of dissatisfaction and attrition (Boivin, Fountain, & Baylis, 2000).This article…

  14. Design of slurry bubble column reactors: novel technique for optimum catalyst size selection contractual origin of the invention (United States)

    Gamwo, Isaac K [Murrysville, PA; Gidaspow, Dimitri [Northbrook, IL; Jung, Jonghwun [Naperville, IL


    A method for determining optimum catalyst particle size for a gas-solid, liquid-solid, or gas-liquid-solid fluidized bed reactor such as a slurry bubble column reactor (SBCR) for converting synthesis gas into liquid fuels considers the complete granular temperature balance based on the kinetic theory of granular flow, the effect of a volumetric mass transfer coefficient between the liquid and the gas, and the water gas shift reaction. The granular temperature of the catalyst particles representing the kinetic energy of the catalyst particles is measured and the volumetric mass transfer coefficient between the gas and liquid phases is calculated using the granular temperature. Catalyst particle size is varied from 20 .mu.m to 120 .mu.m and a maximum mass transfer coefficient corresponding to optimum liquid hydrocarbon fuel production is determined. Optimum catalyst particle size for maximum methanol production in a SBCR was determined to be in the range of 60-70 .mu.m.

  15. Determination of theoretical retention times for peptides analyzed by reversed- -phase high-performance liquid chromatography

    Directory of Open Access Journals (Sweden)

    Jerzy Dziuba


    Full Text Available   Background. Peptides are important components of foods mainly due to their biological activity. The basic method of their identification is reversed phase high-performance liquid chromatography coupled with electrospray-ionization mass spectrometry (RP-HPLC-ESI-MS. Retention time (tR prediction in silico is very helpful in analysis of multicomponent peptide mixtures. One of problems associated with RP-HPLC-ESI-MS is deterioration of mass spectra quality by trifluoroacetic acid (TFA. This problem can be avoided through the use of chromatographic columns designed for work with low TFA concentrations in mobile phase. The objective of this study was to determine the correlations between peptide retention times predicted with the use of a program available on-line and experimental retention times obtained using the column working with low TFA concentrations. Material and methods. The set of synthetic peptides and bovine α-lactalbumin fragments (18 peptides was used in the experiment. Theoretical retention times were calculated using Sequence Specific Retention Calculator (SSRC program. The experimental retention times were measured via RP-HPLC-ESI-MS method using column working with low TFA content. The dependence between theoretical and experimental tR was expressed via empirical equations. Results. The best correlation between theoretical and experimental retention times of peptides containing at least four amino acid residues has been obtained when third order polynomial (R² = 0.9536. Prediction quality for di- and tripeptides was significantly lower. The method described can be applied for cysteine-containing peptides although our sample preparation procedure did not include modification of this amino acid, taken into attention by SSRC program. Conclusions. The results of this study validate the usefulness of a third degree polynomial as a simple function describing the correlation between peptide retention times predicted by an on

  16. Extension of the system constants database for open-tubular columns: system maps at low and intermediate temperatures for four new columns. (United States)

    Atapattu, Sanka N; Eggers, Kimberly; Poole, Colin F; Kiridena, Waruna; Koziol, Wladyslaw W


    The solvation parameter model is used to characterize the separation properties of four open-tubular columns for gas chromatography at low and intermediate column temperatures covering the range 60-240 degrees C. Solute descriptors for compounds suitable for characterizing columns over the intermediate temperature range are optimized using an iterative procedure. These compounds, and those previously recommended for the lower temperature range, are used to provide system constant maps for Rxi-5Sil MS, Rxi-17, Rtx-TNT and Rtx-TNT2 columns suitable for merging with a system constants database with entries for more than 50 columns. The Rxi-5Sil MS column is shown to have separation properties similar to the silphenylene-dimethylsiloxane copolymer stationary phase (DB-5ms) but these two columns are not selectivity equivalent. The Rxi-17 column has similar separation properties to the Rxi-50 column but is not selectivity equivalent to it. Rxi-17 is a poly(dimethyldiphenylsiloxane) stationary phase containing 50% diphenylsiloxane monomer and Rxi-50 a poly(methylphenylsiloxane) stationary phase with the same nominal composition but a different monomer structure. The difference in monomer structure results in only small changes in selectivity, and for all but the most demanding separations, the columns are interchangeable. The application-specific column (energetic materials) Rtx-TNT is shown to be selectivity equivalent to columns coated with the poly(dimethyldiphenylsiloxane) stationary phases containing 5% diphenylsiloxane monomer. The Rtx-TNT2 column is selectivity equivalent to the proprietary Rtx-OPPesticides column. Rtx-OPPesticides is a low bleed stationary phase, possibly based on silarylene-siloxane chemistry, with a composition designed to mimic the separation properties of the poly(dimethylmethyltrifluoropropylsiloxane) stationary phases containing 35% methyltrifluoropropylsiloxane monomer. Selectivity equivalence of columns is determined by the statistical

  17. Novel expandable gastro retentive system by unfolding mechanism of levetiracetam using simple lattice design – Formulation optimization and in vitro evaluation

    Directory of Open Access Journals (Sweden)

    S. Sivaneswari


    Full Text Available The aim of the present study was to develop and characterize a novel expandable gastro-retentive dosage form (GRDF, based on unfolding mechanism. The dosage form consists of a drug loaded the polymeric patch, folded into a hard gelatin capsule. Gastro retention obtained from unfolding and swelling of the patch and its adhesion to the gastric mucosa. Therefore in this work, a gastro retentive patch of levetiracetam was developed using simple lattice design considering concentration of Hydroxy Propyl Methyl Cellulose, Carbopol 934P and Xanthan gum as independent variables. A response surface plot and multiple regression equations were used to evaluate the effect of independent variables on dependent variables such as mucoadhesive strength (g/cm2 and t90 (h. The prepared patches were evaluated for weight and thickness variation, mechanical properties, in vitro drug release and unfolding behavior. The absence of drug-polymer interaction and uniform drug dispersion in the polymeric patches was revealed by FT-IR, DSC, XRD and SEM. The results indicates, the novel GRDF based on unfolding mechanism can be alternative for other mucoadhesive dosage forms which will provide sustained release for 12 h.

  18. Monolithic molecularly imprinted polymeric capillary columns for isolation of aflatoxins. (United States)

    Szumski, Michał; Grzywiński, Damian; Prus, Wojciech; Buszewski, Bogusław


    Monolithic molecularly imprinted polymers extraction columns have been prepared in fused-silica capillaries by UV or thermal polymerization in a two-step process. First, a poly-(trimethylolpropane trimethacrylate) (polyTRIM) core monolith was synthesized either by UV or thermal polymerization. Then it was grafted with the mixture of methacrylic acid (MAA) as a functional monomer, ethylene dimethacrylate (EDMA) as a cross-linking agent, 5,7-dimethoxycoumarin (DMC) as an aflatoxin-mimicking template, toluene as a porogen solvent and 2,2-azobis-(2-methylpropionitrile) (AIBN) as an initiator of the polymerization reaction. Different thermal condition of the photografting and different concentrations of the grafting mixture were tested during polymerization. The extraction capillary columns were evaluated in the terms of their hydrodynamic and chromatographic properties. Retention coefficients for aflatoxin B1 and DMC were used for assessment of the selectivity and imprinting factor. The obtained results indicate that the temperature of photografting and concentration of the grafting mixture are key parameters that determine the quality of the prepared MIPs. From the MIP columns characterized by the highest permeability the column of the highest imprinting factor was applied for isolation of aflatoxins B1, B2, G1 and G2 from the model aqueous sample followed by on-line chromatographic separation. The process was performed using a micro-MISPE-microLC-LIF system of a novel design, which allowed for detection of the eluates from the sample preparation part as well as from the chromatographic separation.

  19. Influence of hydrologic loading rate on phosphorus retention and ecosystem productivity in created wetlands. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Mitsch, W.J.; Cronk, J.K.


    Four 2- to 3-ha constructed freshwater riparian wetlands in Lake County, Illinois, were subjected to two hydrologic regimes of pumped river water to simulate nonpoint source pollution. The experimental wetlands at the Des Plaines River Wetland Demonstration Project were designed to develop and test wetland design principles, construction methods, and management programs needed to create and maintain wetlands for the purposes of water quality management, flood control, and fish and wildlife habitat. High-flow wetlands (HFW) with short retention times received 34 to 38 cm of river water per week, and low-flow wetlands (LFW) with high retention times received 10 to 15 cm per week. This report summarizes research results for phosphorus dynamics and retention, macrophyte development, periphyton productivity, and overall water column metabolism through 1992. All of these functions were hypothesized to be related to hydrologic conditions.

  20. Design of an Extractive Distillation Column for the Environmentally Benign Separation of Zirconium and Hafnium Tetrachloride for Nuclear Power Reactor Applications

    Directory of Open Access Journals (Sweden)

    Le Quang Minh


    Full Text Available Nuclear power with strengthened safety regulations continues to be used as an important resource in the world for managing atmospheric greenhouse gases and associated climate change. This study examined the environmentally benign separation of zirconium tetrachloride (ZrCl4 and hafnium tetrachloride (HfCl4 for nuclear power reactor applications through extractive distillation using a NaCl-KCl molten salt mixture. The vapor–liquid equilibrium behavior of ZrCl4 and HfCl4 over the molten salt system was correlated with Raoult’s law. The molten salt-based extractive distillation column was designed optimally using a rigorous commercial simulator for the feasible separation of ZrCl4 and HfCl4. The molten salt-based extractive distillation approach has many potential advantages for the commercial separation of ZrCl4 and HfCl4 compared to the conventional distillation because of its milder temperatures and pressure conditions, smaller number of required separation trays in the column, and lower energy requirement for separation, while still taking the advantage of environmentally benign feature by distillation. A heat-pump-assisted configuration was also explored to improve the energy efficiency of the extractive distillation process. The proposed enhanced configuration reduced the energy requirement drastically. Extractive distillation can be a promising option competing with the existing extraction-based separation process for zirconium purification for nuclear power reactor applications.

  1. Soil Water Retention Curve (United States)

    Johnson, L. E.; Kim, J.; Cifelli, R.; Chandra, C. V.


    Potential water retention, S, is one of parameters commonly used in hydrologic modeling for soil moisture accounting. Physically, S indicates total amount of water which can be stored in soil and is expressed in units of depth. S can be represented as a change of soil moisture content and in this context is commonly used to estimate direct runoff, especially in the Soil Conservation Service (SCS) curve number (CN) method. Generally, the lumped and the distributed hydrologic models can easily use the SCS-CN method to estimate direct runoff. Changes in potential water retention have been used in previous SCS-CN studies; however, these studies have focused on long-term hydrologic simulations where S is allowed to vary at the daily time scale. While useful for hydrologic events that span multiple days, the resolution is too coarse for short-term applications such as flash flood events where S may not recover its full potential. In this study, a new method for estimating a time-variable potential water retention at hourly time-scales is presented. The methodology is applied for the Napa River basin, California. The streamflow gage at St Helena, located in the upper reaches of the basin, is used as the control gage site to evaluate the model performance as it is has minimal influences by reservoirs and diversions. Rainfall events from 2011 to 2012 are used for estimating the event-based SCS CN to transfer to S. As a result, we have derived the potential water retention curve and it is classified into three sections depending on the relative change in S. The first is a negative slope section arising from the difference in the rate of moving water through the soil column, the second is a zero change section representing the initial recovery the potential water retention, and the third is a positive change section representing the full recovery of the potential water retention. Also, we found that the soil water moving has traffic jam within 24 hours after finished first

  2. Retention models for programmed gas chromatography. (United States)

    Castello, G; Moretti, P; Vezzani, S


    The models proposed by many authors for the prediction of retention times and temperatures, peak widths, retention indices and separation numbers in programmed temperature and pressure gas chromatography by starting from preliminary measurements of the retention in isothermal and isobaric conditions are reviewed. Several articles showing the correlation between retention data and thermodynamic parameters and the determination of the optimum programming rate are reported. The columns of different polarity used for the experimental measurement and the main equations, mathematical models and calculation procedures are listed. An empirical approach was used in the early models, followed by the application of thermodynamic considerations, iterative calculation procedures and statistical methods, based on increased computing power now available. Multiple column arrangements, simultaneous temperature and pressure programming, applications of two-dimensional and fast chromatography are summarised.

  3. Heavy metal composition in stormwater and retention in ponds dependent on pond age, design and catchment type

    DEFF Research Database (Denmark)

    Egemose, Sara; Sønderup, Melanie J.; Grudinina, Anna


    . The concentrations varied considerably depending on the catchment type, with the highest concentrations coming from industrial areas and the lowest from uncultivated and rural areas. Ponds can effectively remove heavy metals in particulate forms through sedimentation processes, but the dissolved forms are more...... such as pH, oxygen and organic matter. Input of metals to the ponds was reflected in the sediment content, but not significantly for all heavy metals probably due to low or varying retention caused by mineralization and re-suspension. The heavy metal concentration in the outlets was reduced to non...

  4. Optimization of Skill Retention in the U. S. Army through Initial Training Analysis and Design: Skill Sustainment Exercises. Volume 3. (United States)


    well. 3. Screws the M605 fuze into fuze well. 4. Buries the mine up to the bottom of the release pin ring. S. Removes the locking safety pin . 6...positive safety pin . MGA SSE-3 TRIAL "- d 7D-Rl31 988 OPTIMIZATION OF SKILL RETENTION IN THE U S RRMY THROUJGH 216 INITIAL TRAINING..(U) MCFANN GRAY...DATE: TASK NO.: 051-192-1012 PAGE I OF I GO NO GO I. Checks mine for boobytraps. 2. Uncovers top of mine. 3. Inserts original safety pin , if available

  5. Optimization of a divided wall column for the separation of C4-C6 normal paraffin mixture using Box-Behnken design

    Directory of Open Access Journals (Sweden)

    Sangal Vikas K.


    Full Text Available In the present study, simulation of a divided wall column (DWC was carried out to study the product quality and energy efficiency as a function of reflux rate, liquid spilt and vapour split for the separation of C4-C6 normal paraffin ternary mixture. Rigorous simulation of the DWC was carried out using Multifrac model of ASPEN Plus software. Box-Behnken design (BBD was used for the optimization of parameters and to evaluate the effects and interaction of the process parameters such as reflux rate (r, liquid split (l and vapour split (v. It was found that the number of simulation runs reduced significantly for the optimization of DWC by BBD. Optimization by BBD under response surface methodology (RSM vividly underscores interactions between variables and their effects. The predictions agree well with the results of the rigorous simulation.

  6. Precision of fit and retention force of cast non-precious-crowns on standard titanium implant-abutment with different design and height. (United States)

    Enkling, Norbert; Ueda, Takayuki; Gholami, Hadi; Bayer, Stefan; Katsoulis, Joannis; Mericske-Stern, Regina


    The cost-effectiveness of cast nonprecious frameworks has increased their prevalence in cemented implant crowns. The purpose of this study was to assess the effect of the design and height of the retentive component of a standard titanium implant abutment on the fit, possible horizontal rotation and retention forces of cast nonprecious alloy crowns prior to cementation. Two abutment designs were examined: Type A with a 6° taper and 8 antirotation planes (Straumann Tissue-Level RN) and Type B with a 7.5° taper and 1 antirotation plane (SICace implant). Both types were analyzed using 60 crowns: 20 with a full abutment height (6 mm), 20 with a medium abutment height (4 mm), and 20 with a minimal (2.5 mm) abutment height. The marginal and internal fit and the degree of possible rotation were evaluated by using polyvinylsiloxane impressions under a light microscope (magnification of ×50). To measure the retention force, a custom force-measuring device was employed. one-sided Wilcoxon rank-sum tests with Bonferroni-Holm corrections, Fisher's exact tests, and Spearman's rank correlation coefficient. Type A exhibited increased marginal gaps (primary end-point: 55 ± 20 μm vs. 138 ± 59 μm, P fit was also better for Type A than for Type B (P force of Type A (2.49 ± 3.2 N) was higher (P = 0.019) than that of Type B (1.27 ± 0.84 N). Reduction in abutment height did not affect the variables observed. Less-tapered abutments with more antirotation planes provide an increase in the retention force, which confines the horizontal rotation but widens the marginal gaps of the crowns. Thus, casting of nonprecious crowns with Type A abutments may result in clinically unfavorable marginal gaps. © 2013 John Wiley & Sons A/S. Published by Blackwell Publishing Ltd.

  7. Minimizing ultraviolet noise due to mis-matches between detector flow cell and post column mobile phase temperatures in supercritical fluid chromatography: effect of flow cell design. (United States)

    Berger, Terry A


    A mis-match between the post-column mobile phase temperature and the UV detector flow cell temperature can cause significant UV noise in supercritical fluid chromatography (SFC). Deviations as little as 5 °C can increase noise as much as 5 times, making the detector unsuited for trace analysis. Two approaches were used to minimize this noise. When a flow cell was in direct thermal contact (metal on metal) with the detector optical bench, the mobile phase temperature was actively controlled to the measured flow cell temperature, by using one of the heat exchangers (HX) in the column compartment. However, with some older, but still widely used flow cell designs, this required repeated, hourly monitoring of the flow cell temperature and repeated manual adjustment of the heat exchanger temperature, due to thermal drift. Flow cell design had a strong influence on susceptibility to this thermally induced noise. Thermally insulating the flow cell from the optical bench made some cells much less susceptible to such thermally induced noise. Five different flow cells, some insulated, some un-insulated, were evaluated. Most had a truncated conical flow path, but one had a cylindrical flow path. Using either approach, the ASTM noise, with a 10mm, 13 μL conical flow cell, could be optimized to ≈0.007 mAU at 2.5 Hz, in SFC, which is very near the 0.006 mAU manufacturer's specification for HPLC. The insulated version of this flow cell required far less optimization, compared to the un-insulated version. At 150 bar, an experimental 3mm, 2 μL flow cell, with only one side insulated, yielded noise slightly too high (≈0.16-0.18 mAU) for trace analysis, at 80 Hz. However, at 200 bar, noise at 80 Hz was noise ratio (S/N) >10. Even partially un-insulated, this flow cell design was much less susceptible to thermally induced noise. Further insulating this flow cell design failed to improve performance.

  8. Slurry bubble column hydrodynamics (United States)

    Rados, Novica

    Slurry bubble column reactors are presently used for a wide range of reactions in both chemical and biochemical industry. The successful design and scale up of slurry bubble column reactors require a complete understanding of multiphase fluid dynamics, i.e. phase mixing, heat and mass transport characteristics. The primary objective of this thesis is to improve presently limited understanding of the gas-liquid-solid slurry bubble column hydrodynamics. The effect of superficial gas velocity (8 to 45 cm/s), pressure (0.1 to 1.0 MPa) and solids loading (20 and 35 wt.%) on the time-averaged solids velocity and turbulent parameter profiles has been studied using Computer Automated Radioactive Particle Tracking (CARPT). To accomplish this, CARPT technique has been significantly improved for the measurements in highly attenuating systems, such as high pressure, high solids loading stainless steel slurry bubble column. At a similar set of operational conditions time-averaged gas and solids holdup profiles have been evaluated using the developed Computed Tomography (CT)/Overall gas holdup procedure. This procedure is based on the combination of the CT scans and the overall gas holdup measurements. The procedure assumes constant solids loading in the radial direction and axially invariant cross-sectionally averaged gas holdup. The obtained experimental holdup, velocity and turbulent parameters data are correlated and compared with the existing low superficial gas velocities and atmospheric pressure CARPT/CT gas-liquid and gas-liquid-solid slurry data. The obtained solids axial velocity radial profiles are compared with the predictions of the one dimensional (1-D) liquid/slurry recirculation phenomenological model. The obtained solids loading axial profiles are compared with the predictions of the Sedimentation and Dispersion Model (SDM). The overall gas holdup values, gas holdup radial profiles, solids loading axial profiles, solids axial velocity radial profiles and solids

  9. 离子交换柱自动化升级设计实例%Ion exchange column automatic upgrade design example

    Institute of Scientific and Technical Information of China (English)

    刘明艳; 卞晓红; 陈晓亭


    阴阳离子交换柱是离子交换层析(Ion Exchange Chromatography简称为IEC)的一种,在我国的应用时间比较久远,具有灵敏度高,重复性、选择性好,分离速度快等优点,是当前最常用的层析法之一,常用于多种离子型生物分子的分离,包括蛋白质、氨基酸、多肽及核酸等。但是很难实现自动化,造成运行成本高,人工操作失误率高等缺点,现根据近几年的设计经验对离子交换柱的自控方式做论述。%Ion Exchange column of Yin and Yang is one of the Ion Exchange Chromatography,application time is long in our country,has a high sensitivity,good repeatability,selectivity,separation of the advantages of fast speed,is currently one of the most commonly used Chromatography,often used in a variety of ionic separation of biological molecules,including proteins,amino acids, peptides and nucleic acids.But it is difficult to realize automation,high operating costs,manual operation errors higher shortcomings, according to the design experience of recent years to ion exchange column control way to do this.

  10. Automated Composite Column Wrapping


    ECT Team, Purdue


    The Automated Composite Column Wrapping is performed by a patented machine known as Robo-Wrapper. Currently there are three versions of the machine available for bridge retrofit work depending on the size of the columns being wrapped. Composite column retrofit jacket systems can be structurally just as effective as conventional steel jacketing in improving the seismic response characteristics of substandard reinforced concrete columns.

  11. Using theory and formative research to design interventions to improve community health worker motivation, retention and performance in Mozambique and Uganda. (United States)

    Strachan, Daniel Llywelyn; Källander, Karin; Nakirunda, Maureen; Ndima, Sozinho; Muiambo, Abel; Hill, Zelee


    Community health workers (CHWs) are increasingly being used in low-income countries to address human resources shortages, yet there remain few effective, evidence-based strategies for addressing the enduring programmatic constraints of worker motivation, retention and performance. This paper describes how two interventions were designed by the Innovations at Scale for Community Access and Lasting Effects (inSCALE) project to address these constraints in Uganda and Mozambique drawing on behavioural theory and formative research results. A review of the work motivation and CHW motivation literature--incorporating influences on retention and performance--was conducted on articles sourced through electronic web searches. Formative research with a focus on the barriers and facilitators to CHW motivation, retention and performance was conducted with community health workers and key stakeholders in Uganda and Mozambique. An analytical induction approach to the thematic analysis of transcripts from 98 in-depth interviews and 26 focus group discussions was adopted across the country settings. From the theoretical review, it was determined that the interventions should promote CHWs as members of a collective by highlighting a sense of shared experience, focus on alignment between worker and programme goals, and emphasise the actions that lead to good performance. The Social Identity Approach was selected as the theory most likely to lead to the development of effective, scalable and sustainable interventions by addressing the identified gap in the literature of the influence of CHW working context. The formative research indicated that CHWs value feedback and feeling connected to the health system and their community, are motivated by status and community standing, and want to be provided with the necessary tools to perform. Two interventions based on these results were developed: a participatory, local community approach and an information communication technology (ICT

  12. Dynamics and control designs for internal thermally coupled distillation columns with different purities, Part 2: close loop analysis and control designs

    Institute of Scientific and Technical Information of China (English)

    ZHU Yu; LIU Xinggao; CHU Jian


    Interaction between overhead and bottom composition loops of internal thermally coupled distillation columns (ITCDIC)with four purities are analyzed by means of relative gain array, condition number and singular value decomposition, which indicates that high- and very high-purity ITCDIC are well coupled and ill-conditioned systems with severe gain directionality problem. Based on the above dynamic behaviors, suitable control schemes of four different purity systems are studied. In low-purity system, internal model control (IMC) is better than decentralized proportion integral differential (D-PID) control in terms of response speed and remaining errors. Inmoderate-purity system, D-PID can effectively reject large load disturbances while IMC fails due to severe mismatch between model and plant. In high-purity system, neither IMC nor D-PID can provide satisfactory control so that modified IMC and multivariable PID with singular value decomposition scheme are presented respectively to improve control performances. Finally, in very high-purity systems, the combined feed-forward and feedback control scheme is proposed to deal with extremely sluggish responses to load disturbances.


    Directory of Open Access Journals (Sweden)

    Nélio Teixeira MACHADO


    Full Text Available In this work the separation of multicomponent mixtures in counter-current columns with supercritical carbon dioxide has been investigated using a process design methodology. First the separation task must be defined, then phase equilibria experiments are carried out, and the data obtained are correlated with thermodynamic models or empirical functions. Mutual solubilities, Ki-values, and separation factors aij are determined. Based on this data possible operating conditions for further extraction experiments can be determined. Separation analysis using graphical methods are performed to optimize the process parameters. Hydrodynamic experiments are carried out to determine the flow capacity diagram. Extraction experiments in laboratory scale are planned and carried out in order to determine HETP values, to validate the simulation results, and to provide new materials for additional phase equilibria experiments, needed to determine the dependence of separation factors on concetration. Numerical simulation of the separation process and auxiliary systems is carried out to optimize the number of stages, solvent-to-feed ratio, product purity, yield, and energy consumption. Scale-up and cost analysis close the process design. The separation of palmitic acid and (oleic+linoleic acids from PFAD-Palm Fatty Acids Distillates was used as a case study.

  14. 竖向框排架厂房柱间支撑设计%On support design for column bracing at workshops of vertical frame-bent structures

    Institute of Scientific and Technical Information of China (English)

    尹航; 张矿三


    Taking the vertical frame-bent structure of compressor in some project of Xinjiang as the example,the paper analyzes the modeling cal-culation of the workshop,and explores the column bracing design principle and calculation methods for the vertical frame-bent structure at high earthquake intensity areas by combining with the national regulations and rules,so as to provide some reference for related engineering design.%以新疆某工程中压缩机厂房竖向框排架结构设计为例,通过对此厂房的建模计算分析,结合国家规范条文,探讨了在高地震烈度地区竖向框排架结构的柱间支撑设计原则与计算方法,为相关工程设计提供参考。

  15. 某超限高层建筑钢管混凝土柱设计%Design of steel tube concrete column of the out-of-codes high-rise building

    Institute of Scientific and Technical Information of China (English)



    This paper analyzes the advantages of steel tube concrete column used in the out-of-codes high-rise building,and mainly explores the technological design points of steel tube concrete beam-column joint.Through rational design,the high-rise building achieves good economic benefits by applying steel tube concrete column.%对钢管混凝土柱用于超高层建筑的优势进行了分析,着重对钢管混凝土梁柱节点设计技术要点进行了探讨,通过合理的设计,超高层建筑采用钢管混凝土柱可取得较可观的经济效益。

  16. Column Selection for Biomedical Analysis Supported by Column Classification Based on Four Test Parameters. (United States)

    Plenis, Alina; Rekowska, Natalia; Bączek, Tomasz


    This article focuses on correlating the column classification obtained from the method created at the Katholieke Universiteit Leuven (KUL), with the chromatographic resolution attained in biomedical separation. In the KUL system, each column is described with four parameters, which enables estimation of the FKUL value characterising similarity of those parameters to the selected reference stationary phase. Thus, a ranking list based on the FKUL value can be calculated for the chosen reference column, then correlated with the results of the column performance test. In this study, the column performance test was based on analysis of moclobemide and its two metabolites in human plasma by liquid chromatography (LC), using 18 columns. The comparative study was performed using traditional correlation of the FKUL values with the retention parameters of the analytes describing the column performance test. In order to deepen the comparative assessment of both data sets, factor analysis (FA) was also used. The obtained results indicated that the stationary phase classes, closely related according to the KUL method, yielded comparable separation for the target substances. Therefore, the column ranking system based on the FKUL-values could be considered supportive in the choice of the appropriate column for biomedical analysis.

  17. Turnover: strategies for staff retention. (United States)

    SnowAntle, S


    This discussion has focused on a number of areas where organizations may find opportunities for more effectively managing employee retention. Given the multitude of causes and consequences, there is no one quick fix. Effective management of employee retention requires assessment of the entire human resources process, that is, recruitment, selection, job design, compensation, supervision, work conditions, etc. Regular and systematic diagnosis of turnover and implementation of multiple strategies and evaluation are needed (Mobley, 1982).

  18. Simplified design method and seismic performance of space trusses with consideration of the influence of the stiffness of their lower supporting columns (United States)

    Fan, Feng; Sun, Menghan; Zhi, Xudong


    Static and dynamic force performance of two types of space truss structures i.e. square pyramid space truss (SPST) and diagonal on square pyramid space truss (DSPST), are studied to determine the effect of stiffness of their lower supporting members. A simplified model for the supporting columns and the equivalent spring mass system are presented. Furthermore, the feasibility of the simplified model is demonstrated through theoretical analysis and examples of comparative analysis of the simplified model with the entire model. Meanwhile, from the elastic analysis under frequently occurring earthquakes and elasto-plastic analysis under seldom occurring earthquakes subjected to TAFT and EL-Centro seismic oscillation it is shown that the simplified method can be encompassed in the results from the normal model. It also showed good agreement between the two methods, as well as greatly improved the computational efficiency. This study verified that the dynamic effect of the supporting structures was under considered in space truss design in the past. The method proposed in the paper has important significance for other space truss structures.

  19. Plate column biosorption of Cu(II) on membrane-type biosorbent (MBS) of Penicillium biomass: optimization using statistical design methods. (United States)

    Xiao, Gang; Zhang, Xin; Su, Haijia; Tan, Tianwei


    Based on the coupling of biosorption and membrane separation, a low cost membrane-type biosorbent (MBS) of Penicillium biomass was prepared. The surface morphology, pore properties and functional groups were studied via the characterization of MBS. Batch biosorption experiments indicated the maximum biosorption capacity of Cu(II) on MBS was 126.58 mg/g and about 90% of that on chitosan membrane. A plate column reactor filled with multi-layer of MBS was built for treatment of wastewater contaminated by Cu(II). The biosorption process factors were screened using Plackett-Burman design and three significant variables were selected for further optimization via response surface methodology (RSM) based on Box-Behnken model. A statistically second-order polynomial model was constructed with the error below 1.22%, on the basis of which the three-dimensional response surfaces were plotted. The prepared membrane-type biosorbent could be used successfully for 10 biosorption-desorption-regeneration cycles without decreasing its biosorption ability obviously.

  20. Modeling Stone Columns

    Directory of Open Access Journals (Sweden)

    Jorge Castro


    Full Text Available This paper reviews the main modeling techniques for stone columns, both ordinary stone columns and geosynthetic-encased stone columns. The paper tries to encompass the more recent advances and recommendations in the topic. Regarding the geometrical model, the main options are the “unit cell”, longitudinal gravel trenches in plane strain conditions, cylindrical rings of gravel in axial symmetry conditions, equivalent homogeneous soil with improved properties and three-dimensional models, either a full three-dimensional model or just a three-dimensional row or slice of columns. Some guidelines for obtaining these simplified geometrical models are provided and the particular case of groups of columns under footings is also analyzed. For the latter case, there is a column critical length that is around twice the footing width for non-encased columns in a homogeneous soft soil. In the literature, the column critical length is sometimes given as a function of the column length, which leads to some disparities in its value. Here it is shown that the column critical length mainly depends on the footing dimensions. Some other features related with column modeling are also briefly presented, such as the influence of column installation. Finally, some guidance and recommendations are provided on parameter selection for the study of stone columns.

  1. Modeling Stone Columns (United States)


    This paper reviews the main modeling techniques for stone columns, both ordinary stone columns and geosynthetic-encased stone columns. The paper tries to encompass the more recent advances and recommendations in the topic. Regarding the geometrical model, the main options are the “unit cell”, longitudinal gravel trenches in plane strain conditions, cylindrical rings of gravel in axial symmetry conditions, equivalent homogeneous soil with improved properties and three-dimensional models, either a full three-dimensional model or just a three-dimensional row or slice of columns. Some guidelines for obtaining these simplified geometrical models are provided and the particular case of groups of columns under footings is also analyzed. For the latter case, there is a column critical length that is around twice the footing width for non-encased columns in a homogeneous soft soil. In the literature, the column critical length is sometimes given as a function of the column length, which leads to some disparities in its value. Here it is shown that the column critical length mainly depends on the footing dimensions. Some other features related with column modeling are also briefly presented, such as the influence of column installation. Finally, some guidance and recommendations are provided on parameter selection for the study of stone columns. PMID:28773146

  2. Enhanced methodology for porting ion chromatography retention data. (United States)

    Park, Soo Hyun; Shellie, Robert A; Dicinoski, Greg W; Schuster, Georg; Talebi, Mohammad; Haddad, Paul R; Szucs, Roman; Dolan, John W; Pohl, Christopher A


    Porting is a powerful methodology to recalibrate an existing database of ion chromatography (IC) retention times by reflecting the changes of column behavior resulting from either batch-to-batch variability in the production of the column or the manufacture of new versions of a column. This approach has been employed to update extensive databases of retention data of inorganic and organic anions forming part of the "Virtual Column" software marketed by Thermo Fisher Scientific, which is the only available commercial optimization tool for IC separation. The current porting process is accomplished by performing three isocratic separations with two representative analyte ions in order to derive a porting equation which expresses the relationship between old and new data. Although the accuracy of retention prediction is generally enhanced on new columns, errors were observed on some columns. In this work, the porting methodology was modified in order to address this issue, where the porting equation is now derived by using six representative analyte ions (chloride, bromide, iodide, perchlorate, sulfate, and thiosulfate). Additionally, the updated porting methodology has been applied on three Thermo Fisher Scientific columns (AS20, AS19, and AS11HC). The proposed approach showed that the new porting methodology can provide more accurate and robust retention prediction on a wide range of columns, where average errors in retention times for ten test anions under three eluent conditions were less than 1.5%. Moreover, the retention prediction using this new approach provided an acceptable level of accuracy on a used column exhibiting changes in ion-exchange capacity.

  3. Optimization of SHINE Process: Design and Verification of Plant-Scale AG 1 Anion-Exchange Concentration Column and Titania Sorbent Pretreatment

    Energy Technology Data Exchange (ETDEWEB)

    Stepinski, Dominique C. [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Abdul, Momen [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Youker, Amanda J. [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Rotsch, David A. [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Tkac, Peter [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Chemerisov, Sergey [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Vandegrift, George F. [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division


    Argonne National Laboratory has developed a Mo-recovery and -purification system for the SHINE medical technologies process, which uses a uranyl sulfate solution for the accelerator-driven production of Mo-99. The objective of this effort is to reduce the processing time for the acidification of the Mo-99 product prior to loading onto a concentration column and concentration of the Mo-99 product solution. Two methods were investigated: (1) the replacement of the titania concentration column by an anion-exchange column to decrease processing time and increase the radioiodine-decontamination efficiency and (2) pretreatment of the titania sorbent to improve its effectiveness for the Mo-recovery and -concentration columns. Promising results are reported for both methods.

  4. Evaluating Design Parameters for Breakthrough Curve Analysis and Kinetics of Fixed Bed Columns for Cu(II) Cations Using Lignocellulosic Wastes


    Zaira Zaman Chowdhury; Sharifah Bee Abd Hamid; Sharifuddin Mohd Zain


    A continuous adsorption study for removal of Cu(II) cations from wastewater using a fixed-bed column was conducted. A granular carbonaceous activated adsorbent produced by carbonization of the outer rind, or exocarp, of mangostene fruit shell was used for column packing. The effects of feed flow rate, influent cation concentration, and bed depth on the breakthrough curve were investigated at pH 5.5. Experimental analysis confirmed that the breakthrough curves were dependent on flow rate, init...

  5. Column Liquid Chromatography. (United States)

    Majors, Ronald E.; And Others


    Reviews literature covering developments of column liquid chromatography during 1982-83. Areas considered include: books and reviews; general theory; columns; instrumentation; detectors; automation and data handling; multidimensional chromatographic and column switching techniques; liquid-solid chromatography; normal bonded-phase, reversed-phase,…

  6. No difference in gait between posterior cruciate retention and the posterior stabilized design after total knee arthroplasty

    NARCIS (Netherlands)

    van den Boom, Lennard G. H.; Halbertsma, Jan P. K.; van Raaij, Jos J. A. M.; Brouwer, Reinoud W.; Bulstra, Sjoerd K.; van den Akker-Scheek, Inge


    In the present study, knee joint kinematics (e.g. knee flexion/extension) and kinetics (e.g. knee flexion moments) are assessed after total knee arthroplasty (TKA) between patients implanted with either a unilateral posterior stabilized (PS) and a posterior cruciate-retaining (PCR) design. It was hy

  7. No difference in gait between posterior cruciate retention and the posterior stabilized design after total knee arthroplasty

    NARCIS (Netherlands)

    van den Boom, Lennard G. H.; Halbertsma, Jan P. K.; van Raaij, Jos J. A. M.; Brouwer, Reinoud W.; Bulstra, Sjoerd K.; van den Akker-Scheek, Inge


    In the present study, knee joint kinematics (e.g. knee flexion/extension) and kinetics (e.g. knee flexion moments) are assessed after total knee arthroplasty (TKA) between patients implanted with either a unilateral posterior stabilized (PS) and a posterior cruciate-retaining (PCR) design. It was hy

  8. Gas Chromatograph Method Optimization Trade Study for RESOLVE: 20-meter Column v. 8-meter Column (United States)

    Huz, Kateryna


    RESOLVE is the payload on a Class D mission, Resource Prospector, which will prospect for water and other volatile resources at a lunar pole. The RESOLVE payload's primary scientific purpose includes determining the presence of water on the moon in the lunar regolith. In order to detect the water, a gas chromatograph (GC) will be used in conjunction with a mass spectrometer (MS). The goal of the experiment was to compare two GC column lengths and recommend which would be best for RESOLVE's purposes. Throughout the experiment, an Inficon Fusion GC and an Inficon Micro GC 3000 were used. The Fusion had a 20m long column with 0.25mm internal diameter (Id). The Micro GC 3000 had an 8m long column with a 0.32mm Id. By varying the column temperature and column pressure while holding all other parameters constant, the ideal conditions for testing with each column length in their individual instrument configurations were determined. The criteria used for determining the optimal method parameters included (in no particular order) (1) quickest run time, (2) peak sharpness, and (3) peak separation. After testing numerous combinations of temperature and pressure, the parameters for each column length that resulted in the most optimal data given my three criteria were selected. The ideal temperature and pressure for the 20m column were 95 C and 50psig. At this temperature and pressure, the peaks were separated and the retention times were shorter compared to other combinations. The Inficon Micro GC 3000 operated better at lower temperature mainly due to the shorter 8m column. The optimal column temperature and pressure were 70 C and 30psig. The Inficon Micro GC 3000 8m column had worse separation than the Inficon Fusion 20m column, but was able to separate water within a shorter run time. Therefore, the most significant tradeoff between the two column lengths was peak separation of the sample versus run time. After performing several tests, it was concluded that better

  9. Influence of tray hydraulics on tray column

    NARCIS (Netherlands)

    Betlem, Bernardus H.L.; Rijnsdorp, J.E.; Rijnsdorp, J.E.; Azink, R.F.


    To column control, in contrast to column design, tray hold-up and dependencies of tray hold-up on the operating conditions play an important role. The essence of this article is the development of an improved model of tray hydraulics over a broad operating range and its experimental validation by

  10. Stone Rome column 3 d model design based on Solidworks%基于Solidworks石材罗马柱三维模型设计

    Institute of Scientific and Technical Information of China (English)

    赵晓旭; 张静; 赵民; 齐震楠


    This paper draws three-dimensional model of the stone Roman column by using Solidworks 3D drawing software,and it mainly introduce some basic knowledge of Solidworks software such as drawing, excision, scanning, mirror, etc. in the process of drawing Roman column. The basic process of drawing Roman column has been detailed description:divided into the stigma, the column foot, the pillar to draw. when drawing completed,try to assemble and produce the formation of the Roman column three-dimensional model.%本文利用Solidworks三维制图软件绘制石材罗马柱的三维立体模型,主要介绍了绘制罗马柱过程中所用到的Solidworks软件的一些基础知识,如拉伸、切除、扫描、镜像等;详细说明了绘制罗马柱的基本过程:分为柱头、柱脚、柱身进行绘制,绘制完成后在进行装配,形成最后的罗马柱三维模型。

  11. The jet flotation column control system

    Energy Technology Data Exchange (ETDEWEB)

    Xu Zhiqiang; Ming Shangzhi; Liu Lijian; Huangfu Jinghua; Huo Sen; Zhang Rongzeng [China Univ. of Mining and Technology, Beijing (China). Mineral Processing Dept.; Yang Hongjun [Hebi Coal Mine Administrative (China)


    Compared with the conventional mechanical flotation column, the jet flotation column has the advantages of high selectivity of separation, low investment and production cost, low floor space requirement, low dosage of reagent, easy control; it is more suitable to process fine particles. Recently, many new types of flotation columns have been developed with new methods. Mineral Processing Dept., China University of Mining and Technology (Beijing) designed an aerated, double-jet flotation column in the lab and the industrial trial will be put into operation. One of the significant characteristics of the new type of flotation column is high selectivity of separation, fast bubble mineralization speed. As it is sensitive to various factors, a control system for flotation column has been developed to stabilize the working condition, and this set of control system has been operated in the lab experiment.

  12. Compression-bending of multi-component semi-rigid columns in response to axial loads and conjugate reciprocal extension-prediction of mechanical behaviours and implications for structural design. (United States)

    Lau, Ernest W


    The mathematical modelling of column buckling or beam bending under an axial or transverse load is well established. However, the existent models generally assume a high degree of symmetry in the structure of the column and minor longitudinal and transverse displacements. The situation when the column is made of several components with different mechanical properties asymmetrically distributed in the transverse section, semi-rigid, and subjected to multiple axial loads with significant longitudinal and transverse displacements through compression and bending has not been well characterised. A more comprehensive theoretical model allowing for these possibilities and assuming a circular arc contour for the bend is developed, and used to establish the bending axes, balance between compression and bending, and equivalent stiffness of the column. In certain situations, such as with pull cable catheters commonly used for minimally invasive surgical procedures, the compression loads are applied via cables running through channels inside a semi-rigid column. The model predicts the mathematical relationships between the radius of curvature of the bend and the tension in and normal force exerted by such cables. Conjugate extension with reciprocal compression-bending is a special structural arrangement for a semi-rigid column such that extension of one segment is linked to compression-bending of another by inextensible cables running between them. Leads are cords containing insulated electrical conductor coil and cables between the heart muscle and cardiac implantable electronic devices. Leads can behave like pull cable catheters through differential component pulling, providing a possible mechanism for inside-out abrasion and conductor cable externalisation. Certain design features may predispose to this mode of structural failure. Copyright © 2012 Elsevier Ltd. All rights reserved.

  13. Fission-product retention in HTGR fuels

    Energy Technology Data Exchange (ETDEWEB)

    Homan, F.J.; Kania, M.J.; Tiegs, T.N.


    Retention data for gaseous and metallic fission products are presented for both Triso-coated and Biso-coated HTGR fuel particles. Performance trends are established that relate fission product retention to operating parameters, such as temperature, burnup, and neutron exposure. It is concluded that Biso-coated particles are not adequately retentive of fission gas or metallic cesium, and Triso-coated particles which retain cesium still lose silver. Design implications related to these performance trends are identified and discussed.

  14. Design, baseline characteristics, and retention of African American light smokers into a randomized trial involving biological data

    Directory of Open Access Journals (Sweden)

    Okuyemi Kolawole S


    Full Text Available Abstract Background African Americans experience significant tobacco-related health disparities despite the fact that over half of African American smokers are light smokers (use ≤10 cigarettes per day. African Americans have been under-represented in smoking cessation research, and few studies have evaluated treatment for light smokers. This paper describes the study design, measures, and baseline characteristics from Kick It at Swope III (KIS-III, the first treatment study of bupropion for African American light smokers. Methods Five hundred forty African American light smokers were randomly assigned to receive bupropion (150mg bid (n = 270 or placebo (n = 270 for 7 weeks. All participants received written materials and health education counseling. Participants responded to survey items and provided blood samples for evaluation of phenotype and genotype of CYP2A6 and CYP2B6 enzymes involved in nicotine and bupropion metabolism. Primary outcome was cotinine-verified 7-day point prevalence smoking abstinence at Week 26 follow-up. Results Of 2,628 individuals screened, 540 were eligible, consented, and randomized to treatment. Participants had a mean age of 46.5 years and 66.1% were women. Participants smoked an average of 8.0 cigarettes per day, had a mean exhaled carbon monoxide of 16.4ppm (range 1-55 and a mean serum cotinine of 275.8ng/ml. The mean Fagerström Test for Nicotine Dependence was 3.2, and 72.2% of participants smoked within 30 minutes of waking. The average number of quit attempts in the past year was 3.7 and 24.2% reported using pharmacotherapy in their most recent quit attempt. Motivation and confidence to quit were high. Conclusion KIS-III is the first study designed to examine both nicotine and bupropion metabolism, evaluating CYP2A6 and CYP2B6 phenotype and genotype in conjunction with psychosocial factors, in the context of treatment of African American light smokers. Of 1629 smokers screened for study participation, only

  15. Evaluation of Gas Retention in Waste Simulants: Tall Column Experiments

    Energy Technology Data Exchange (ETDEWEB)

    Schonewill, Philip P.; Gauglitz, Phillip A.; Shimskey, Rick W.; Denslow, Kayte M.; Powell, Michael R.; Boeringa, Gregory K.; Bontha, Jagannadha R.; Karri, Naveen K.; Fifield, Leonard S.; Tran, Diana N.; Sande, Susan; Heldebrant, David J.; Meacham, Joseph E.; Smet, Dave; Bryan, Wesley E.; Calmus, Ronald B.


    Gas generation in Hanford’s underground waste storage tanks can lead to gas accumulation within the layer of settled solids (sludge) at the tank bottom. The gas, which typically has hydrogen as the major component together with other flammable species, is formed principally by radiation-driven chemical reactions. Accumulation of these gases within the sludge in a waste tank is undesirable and limits the amount of tank volume for waste storage. Further, accumulation of large amounts of gas in the sludge may potentially result in an unacceptable release of the accumulated gas if the sludge-layer density is reduced to less than that of the overlying sludge or that of the supernatant liquid. Rapid release of large amounts of flammable gases could endanger personnel and equipment near the tank. For this reason, a thorough understanding of the circumstances that can lead to a potentially problematic gas accumulation in sludge layers is needed. To respond to this need, the Deep Sludge Gas Release Event Program (DSGREP) was commissioned to examine gas release behavior in sludges.

  16. Spiral multicapillary columns (United States)

    Efimenko, A. P.; Naumenko, I. I.; Soboleva, V. K.


    It was shown in a theoretical study and confirmed by experiment that a spiral multicapillary column had maximum efficiency if the bunch of capillaries was additionally coiled around its longitudinal axis to produce an integral number of coils. This technique made it possible to manufacture gas-chromatographic columns with performance as high as 12 to 16 thousand theoretical plates. These columns can find various applications, especially if quick separation is required.

  17. Reactive transport modeling for Cs retention: from batch to field experiments (United States)

    De Pourcq, K.; Ayora, C.; Carrera, J.; García-Gutiérrez, M.; Missana, T.; Mingarro, M.


    A Permeable Reactive Barrier has been designed to treat 137Cs polluted groundwater. In order to check both reactivity and permeability, laboratory batch and column tests combined with reactive transport modeling have been performed. The trapping mechanism is based on the sorption of cesium mainly on illite-containing clays. Batch experiments were conducted to obtain the partition coefficients (Kd) of different clay samples in solutions with different potassium concentration. A clear correlation of Kd values with potassium content was observed. The results were modeled with a cation-exchange model. The permeability of the reactive material is provided by the dispersion of the clay on a matrix of wooden shavings. Constant head tests allowed obtaining permeability values. Several column experiments with different flow rates were conducted to confirm the 137Cs retention under different conditions. A blind 1D reactive transport model based on the cation-exchange model was able to predict reasonably well the results of column experiments. The reactive transport model, validated with the column experiments, was used to investigate the performance and duration of 1m thick barrier under different scenarios (flow, clay proportion, 137Cs and K concentration). As expected, the sensitivity tests proved that the retention capacity of dissolved 137Cs in groundwater depends linearly on the amount of clay used in the filling material. As well, the operation time increases linearly when decreasing the flow rate. Finally, the concentration of potassium in inflow water has a remarkable and non-linear influence in the retention of 137Cs. Very high concentrations of potassium are the greatest threat and can lead to the unfeasibility of a permeable reactive barrier. Due to the Cs-K competition, the barrier is comparatively more efficient to treat high concentrations of 137Cs. Up to now, preliminary results from a field scale experiment have confirmed the reactivity and permeability


    Directory of Open Access Journals (Sweden)

    Nina Fauziah


    Full Text Available Studies were carried out to design a collimator which results in epithermal neutron beam for IN VITRO and IN VIVO of Boron Neutron Capture Therapy (BNCT at the Kartini research reactor by means of Monte Carlo N-Particle (MCNP codes. Reactor within 100 kW of thermal power was used as the neutron source. The design criteria were based on recommendation from the International Atomic Energy Agency (IAEA. All materials used were varied in size, according to the value of mean free path for each material. MCNP simulations indicated that by using 5 cm thick of Ni as collimator wall, 60 cm thick of Al as moderator, 15 cm thick of 60Ni as filter, 2 cm thick of Bi as γ-ray shielding, 3 cm thick of 6Li2CO3-polyethylene as beam delimiter, with 1 to 5 cm varied aperture size, epithermal neutron beam with maximum flux of 7.65 x 108 could be produced. The beam has minimum fast neutron and γ-ray components of, respectively, 1.76 x 10-13 Gy.cm2.n-1 and 1.32 x 10-13 Gy.cm2.n-1, minimum thermal neutron per epithermal neutron ratio of 0.008, and maximum directionality of 0.73. It did not fully pass the IAEA’s criteria, since the epithermal neutron flux was below the recommended value, 1.0 x 109 Nonetheless, it was still usable with epithermal neutron flux exceeding 5.0 x 108 When it was assumed that the graphite inside the thermal column was not discharged but only the part which was going to be replaced by the collimator, the performance of the collimator became better within the positive effect from the surrounding graphite that the beam resulted passed all criteria with epithermal neutron flux up to 1.68 x 109 Keywords: design, collimator, epithermal neutron beam, BNCT, MCNP, criteria   Telah dilakukan penelitian tentang desain kolimator yang menghasilkan radiasi netron epitermal untuk uji in vitro dan in vivo pada Boron Neutron Capture Therapy (BNCT di Reaktor Riset Kartini dengan menggunakan program Monte

  19. 基于FEM的数控弧齿铣齿机立柱结构静、动态设计%FEM-Based Static & Dynamic Design of Computer Numerical Control Bevel Gear Machine Tool Column

    Institute of Scientific and Technical Information of China (English)

    李翼龙; 郭志全; 刘明涛; 李彦启


    借助有限元分析软件,运用结构动态设计原理和基于有限元法的变量化分析技术对数控弧齿铣齿机立柱部件进行动、静态特性分析,并以立柱结构的侧板宽度为几何参数进行灵敏度分析,找出原设计中的不足,并在结构及尺寸上加以改进.结果表明,改进后立柱的动、静态性能得到显著的提高,为机床设计和改造提供了依据.%By using finite element analysis software, structural dynamic design principle,and variational analysis technique based on finite element method (FEM), a static and dynamic characteristic analysis was carried out on the column structure of numerical control bevel gear machine tool. Sensitivity analysis was also conducted according to the geometric parameters of the column structure. The deficiencies in the original design were found out and then improved in both the structure and measure. The results show that the static and dynamic performance of the improved column has been increased significantly, so this method can offer bases for the design and renovation of machine tools.

  20. A design study for the isolation of the 281-3H retention basin at the Savannah River Site using the viscous liquid barrier technology

    Energy Technology Data Exchange (ETDEWEB)

    Moridis, G.J.; Persoff, P.; Apps, J.; James, A.; Oldenburg, C.; McGrath, A.; Myer, L.; Pellerin, L.; Pruess, K. [Lawrence Berkeley National Lab., CA (United States). Earth Sciences Div.


    This report is a description of the design study for a pilot-scale field demonstration of the Viscous Liquid Barrier (VLB) technology, a new subsurface containment technology for waste isolation using a new generation of barrier liquids. The demonstration site was Retention Basin 281-3H, a shallow catchment basin at the Savannah River Site, which is contaminated mainly by radionuclides ({sup 137}Cs, {sup 90}Sr, and {sup 238}Pu). The goals of the field demonstration were (a) to demonstrate the ability to create a continuous subsurface barrier in order to isolate the contaminants, and (b) to demonstrate the continuity, performance, and integrity of the barrier. The site was characterized, and preliminary hydraulic conductivity data were obtained from core samples. Based on the site characteristics and the functional requirements, a conceptual model was developed, the barrier specifications were defined, and lance injection was selected as the emplacement method. The injection strategy for the subsurface conditions at the site was determined using numerical simulations. An appropriate variant of Colloidal Silica (CS) was selected as the barrier liquid based on its relative insensitivity to interactions with the site soils, and the formulation for optimum site performance was determined. A barrier verification strategy, including hydraulic, pneumatic, tracer, and geophysical methods, was developed. A lance water injection test was conducted in order to obtain representative estimates of the hydraulic conductivity and its distribution for the design of the barrier emplacement. The water injection test demonstrated the lack of permeable zones for CS injection, and a decision not to proceed with the barrier emplacement was reached.

  1. Fuel nozzle tube retention

    Energy Technology Data Exchange (ETDEWEB)

    Cihlar, David William; Melton, Patrick Benedict


    A system for retaining a fuel nozzle premix tube includes a retention plate and a premix tube which extends downstream from an outlet of a premix passage defined along an aft side of a fuel plenum body. The premix tube includes an inlet end and a spring support feature which is disposed proximate to the inlet end. The premix tube extends through the retention plate. The spring retention feature is disposed between an aft side of the fuel plenum and the retention plate. The system further includes a spring which extends between the spring retention feature and the retention plate.

  2. Causes and implications of colloid and microorganism retention hysteresis (United States)

    Bradford, Scott A.; Kim, Hyunjung


    Experiments were designed to better understand the causes and implications of colloid and microorganism retention hysteresis with transients in solution ionic strength (IS). Saturated packed column experiments were conducted using two sizes of carboxyl modified latex (CML) microspheres (0.1 and 1.1 μm) and microorganisms (coliphage φX174 and E. coli D21g) under various transient solution chemistry conditions, and 360 μm Ottawa sand that was subject to different levels of cleaning, namely, a salt cleaning procedure that removed clay particles, and a salt + acid cleaning procedure that removed clay and reduced microscopic heterogeneities due to metal oxides and surface roughness. Comparison of results from the salt and salt + acid treated sand indicated that microscopic heterogeneity was a major contributor to colloid retention hysteresis. The influence of this heterogeneity increased with IS and decreasing colloid/microbe size on salt treated sand. These trends were not consistent with calculated mean interaction energies (the secondary minima), but could be explained by the size of the electrostatic zone of influence (ZOI) near microscopic heterogeneities. In particular, the depth of local minima in the interaction energy has been predicted to increase with a decrease in the ZOI when the colloid size and/or the Debye length decreased (IS increased). The adhesive interaction was therefore largely irreversible for smaller sized 0.1 μm CML colloids, whereas it was reversible for larger 1.1 μm CML colloids. Similarly, the larger E. coli D21g exhibited greater reversibility in retention than φX174. However, direct comparison of CML colloids and microbes was not possible due to differences in size, shape, and surface properties. Retention and release behavior of CML colloids on salt + acid treated sand was much more consistent with mean interaction energies due to reduction in microscopic heterogeneities.

  3. Reliability of simulated robustness testing in fast liquid chromatography, using state-of-the-art column technology, instrumentation and modelling software. (United States)

    Kormány, Róbert; Fekete, Jenő; Guillarme, Davy; Fekete, Szabolcs


    The goal of this study was to evaluate the accuracy of simulated robustness testing using commercial modelling software (DryLab) and state-of-the-art stationary phases. For this purpose, a mixture of amlodipine and its seven related impurities was analyzed on short narrow bore columns (50×2.1mm, packed with sub-2μm particles) providing short analysis times. The performance of commercial modelling software for robustness testing was systematically compared to experimental measurements and DoE based predictions. We have demonstrated that the reliability of predictions was good, since the predicted retention times and resolutions were in good agreement with the experimental ones at the edges of the design space. In average, the retention time relative errors were software, we proved that the separation was feasible on all columns within the same analysis time (less than 4min), by proper adjustments of variables. Copyright © 2013 Elsevier B.V. All rights reserved.

  4. JCE Feature Columns (United States)

    Holmes, Jon L.


    The Features area of JCE Online is now readily accessible through a single click from our home page. In the Features area each column is linked to its own home page. These column home pages also have links to them from the online Journal Table of Contents pages or from any article published as part of that feature column. Using these links you can easily find abstracts of additional articles that are related by topic. Of course, JCE Online+ subscribers are then just one click away from the entire article. Finding related articles is easy because each feature column "site" contains links to the online abstracts of all the articles that have appeared in the column. In addition, you can find the mission statement for the column and the email link to the column editor that I mentioned above. At the discretion of its editor, a feature column site may contain additional resources. As an example, the Chemical Information Instructor column edited by Arleen Somerville will have a periodically updated bibliography of resources for teaching and using chemical information. Due to the increase in the number of these resources available on the WWW, it only makes sense to publish this information online so that you can get to these resources with a simple click of the mouse. We expect that there will soon be additional information and resources at several other feature column sites. Following in the footsteps of the Chemical Information Instructor, up-to-date bibliographies and links to related online resources can be made available. We hope to extend the online component of our feature columns with moderated online discussion forums. If you have a suggestion for an online resource you would like to see included, let the feature editor or JCE Online ( know about it. JCE Internet Features JCE Internet also has several feature columns: Chemical Education Resource Shelf, Conceptual Questions and Challenge Problems, Equipment Buyers Guide, Hal's Picks, Mathcad

  5. Glass-silicon column

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Conrad M.


    A glass-silicon column that can operate in temperature variations between room temperature and about C. The glass-silicon column includes large area glass, such as a thin Corning 7740 boron-silicate glass bonded to a silicon wafer, with an electrode embedded in or mounted on glass of the column, and with a self alignment silicon post/glass hole structure. The glass/silicon components are bonded, for example be anodic bonding. In one embodiment, the column includes two outer layers of silicon each bonded to an inner layer of glass, with an electrode imbedded between the layers of glass, and with at least one self alignment hole and post arrangement. The electrode functions as a column heater, and one glass/silicon component is provided with a number of flow channels adjacent the bonded surfaces.

  6. 独柱盖梁上、下双抱箍托架设计及施工%Design and Construction of Single - column Capping Beam Upper and Lower Double Embracing Hoop Brackets

    Institute of Scientific and Technical Information of China (English)



    根据独柱盖梁对称浇筑的施工特点,结合连续刚构(梁)0号块托架法现浇施工和双柱抱箍法盖梁施工的相关经验,设计了上、下双抱箍加设三角托架的独柱盖梁支撑结构;并对其主要构件设计、施工流程、质量安全方面注意事项进行了分析和总结,为类似工程提供参考和借鉴。%According to construction characteristics of single - column capping beam symmetric casting and in combination with relevant experience of cast construction through continuous rigid frame ( beam ) No. 0 block bracket method and capping beam construction through double - column embracing hoop method, single - column capping beam support structure of upper and lower double embracing hoop with triangle brackets is designed and the main component design, construction process, and matters needing attention in the aspect of quality safety are analyzed and summarized, providing reference for similar projects.

  7. Separation of Oil from Wastewater by Column Flotation

    Institute of Scientific and Technical Information of China (English)


    A new type of device, a dissolved-air flotation column, was developed for separation of oily wastewater.The unique design idea of the dissolved-air flotation column is the combined use of dissolved-air flotation and column flotation.The dissolved air release occurred within the column separation system.As a potential application the column was investigated for its performance in separating emulsified oil droplets in oily wastewater.A high separation efficiency was obtained in a series of tests.The aeration performance of the bubble generator used in the dissolved-air flotation column was also studied in particular.

  8. 基于AVR单片机的柱架控制器的设计%Column Frame Controller Design Based on the AVR MCU

    Institute of Scientific and Technical Information of China (English)

    蒋平; 韩震宇; 李程


    This paper introduces a ATmega16 microcontroller as the core column frame control system, the system using a com?pilation of programming, and the use of structured programming method. The system includes a battery voltage detection and column inclination angle detection, in the column frame in special situation, adopt automatic control. This paper discusses the hardware structure of the system, and gives the software flow chart.%该文介绍了一种ATmega16单片机为核心的柱架控制系统,该系统利用汇编编程,并采用结构化的编程方法.该系统包含了电池电压的检测和柱架倾斜角的检测,能够在柱架处于特殊情况时,采取自动控制.该文论述了该系统的硬件结构,并给出了软件流程图.

  9. Mobile Learning and Student Retention

    Directory of Open Access Journals (Sweden)

    Bharat Inder Fozdar


    Full Text Available Student retention in open and distance learning (ODL is comparatively poor to traditional education and, in some contexts, embarrassingly low. Literature on the subject of student retention in ODL indicates that even when interventions are designed and undertaken to improve student retention, they tend to fall short. Moreover, this area has not been well researched. The main aim of our research, therefore, is to better understand and measure students’ attitudes and perceptions towards the effectiveness of mobile learning. Our hope is to determine how this technology can be optimally used to improve student retention at Bachelor of Science programmes at Indira Gandhi National Open University (IGNOU in India. For our research, we used a survey. Results of this survey clearly indicate that offering mobile learning could be one method improving retention of BSc students, by enhancing their teaching/ learning and improving the efficacy of IGNOU’s existing student support system. The biggest advantage of this technology is that it can be used anywhere, anytime. Moreover, as mobile phone usage in India explodes, it offers IGNOU easy access to a larger number of learners. This study is intended to help inform those who are seeking to adopt mobile learning systems with the aim of improving communication and enriching students’ learning experiences in their ODL institutions.

  10. Enhanced retention of bacteria by TiO2 nanoparticles in saturated porous media (United States)

    Gentile, Guillermina J.; Fidalgo de Cortalezzi, María M.


    The simultaneous transport of TiO2 nanoparticles and bacteria Pseudomonas aeruginosa in saturated porous media was investigated. Nanoparticle and bacterium size and surface charge were measured as a function of electrolyte concentration. Sand column breakthrough curves were obtained for single and combined suspensions, at four different ionic strengths. DLVO and classical filtration theories were employed to model the interactions between particles and between particles and sand grains. Attachment of TiO2 to the sand was explained by electrostatic forces and these nanoparticles acted as bonds between the bacteria and the sand, leading to retention. Presence of TiO2 significantly increased the retention of bacteria in the sand bed, but microorganisms were released when nanomaterial influx ceased. The inclusion of nanomaterials in saturated porous media may have implications for the design and operation of sand filters in water treatment.

  11. Distillation Column Flooding Predictor

    Energy Technology Data Exchange (ETDEWEB)

    George E. Dzyacky


    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid

  12. Research of Design and Application of Girdling-Column Steel Beam%钢结构抱柱梁的设计与应用研究

    Institute of Scientific and Technical Information of China (English)

    吉伯海; 徐声亮; 袁爱民; 周超; 郑宏


    针对目前在桥梁整体同步顶升改造中普遍使用的混凝土抱柱梁施工周期长、墩柱界面连接强度弱、环境不友好、适用范围受限等不足,提出一种新型钢结构抱柱梁.钢结构抱柱梁采用可预制拼装的分离式钢结构,通过设置剪力键与双向预应力提高墩梁界面的承载力,并在抱柱梁承受集中力区域及应力集中部位设置加劲肋.结合浙江省某航道桥的整体顶升改造,对钢结构抱柱梁的结构布置及受力性能进行分析,并与相应的混凝土抱柱梁进行对比.分析结果表明,钢结构抱柱梁各部分受力均满足规范要求,与混凝土抱柱梁相比,钢结构抱柱梁高宽比较小、墩梁接触界面连接力大、结构可循环使用、施工效率大大提高.%Seeing the deficiency that the construction time schedule of the girdling-column (pier column) concrete beam extensively used for the current bridge retrofitting of integral and synchronous jack-up is long, the strength of connection between the column and the beam is week, the utilization of the beam is environment-unfriendly and is limited as well, a new type of the girdling-column steel beam is brought forward. The steel beam is a separated steel structure that can be prefabricated and preassembled, the bearing capacity at the interface between the column and the beam can be enhanced via setting of the shear studs and two-way prestressing tendons and the stiffeners can be set in the area of the beam which will sustain concentrated force or in the part of the beam of stress concentration. With reference to the retrofitting of integral and synchronous jacking-up for a shipping channel bridge in Zhejiang Province, the structural layout and force conditions of the girdling-column steel beam are analyzed and are compared to those of a corresponding concrete beam. The results of the analysis indicate that the force conditions of various parts of the steel beam can satisfy the relevant

  13. Sleep physiology predicts memory retention after reactivation

    National Research Council Canada - National Science Library

    Macdonald, Kevin J; Cote, Kimberly A


    ...) received reminders designed to leave these memories in a stable state. No significant differences in memory retention were found between blocks or groups the following morning. Frontal delta (0.5–4 Hz...

  14. Anchoring FRP laminates for the seismic strengthening of RC columns


    Sadone, Raphaëlle; Quiertant, Marc; FERRIER, Emmanuel; Chataigner, Sylvain; Mercier, Julien


    This paper aims to examine the effectiveness of seismic strengthening of reinforced concrete (RC) columns by externally bonded Fibre Reinforced Polymer (FRP). Particularly, a novel strengthening system, designed for the flexural strengthening of columns is studied. This flexural strengthening is achieved by FRP plates bonded longitudinally and anchored at the column-stub junction. The proposed system is validated through an experimental campaign carried out on full-scale RC columns. Different...

  15. Flexural strength enhancement of confined reinforced concrete columns


    Pam, HJ; Ho, JCM


    As part of a continuing research study, this paper proposes a new design aid to calculate the actual moment capacity of confined reinforced concrete columns. Up to now the moment capacity of a reinforced concrete column is calculated based on the code's guidelines for an unconfined section. As most reinforced concrete columns contain transverse or confining reinforcement, which will enhance the column moment capacity, the actual moment capacity will be much higher than the unconfined moment c...

  16. Behavior of high strength concrete columns under eccentric loads

    Directory of Open Access Journals (Sweden)

    Hany A. Kottb


    Full Text Available In recent decades, high strength concrete (HSC has been widely accepted by designers and contractors to be used in concrete structures, especially in high compressive stress elements. The research aims to study the behavior of high strength concrete columns under eccentric compression using experimental and analytical programs. The research is divided into two main parts; the first part is an experimental investigation for ten square columns tested at the Cairo University Concrete Research Laboratory. The main studied parameters were eccentricity of the applied load, column slenderness ratio; and ratios of longitudinal and transverse reinforcement. The second part is analytical analysis using nonlinear finite element program ANSYS11 on nineteen columns (ten tested square columns and nine rectangular section columns to study the effect of the previous parameters on the column ultimate load, mid-height displacement, and column cracking patterns. The analyzed columns revealed a good agreement with the experimental results with an average difference of 16% and 17% for column ultimate load and mid-height displacement respectively. Results showed an excellent agreement for cracking patterns. Predictions of columns capacities using the interaction diagrams based on ACI 318-08 stress block parameters indicated a safe design procedure of HSC columns under eccentric compression, with ACI 318-08 being more conservative for moderate reinforced HSC columns.

  17. Oscillating water column structural model

    Energy Technology Data Exchange (ETDEWEB)

    Copeland, Guild [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Bull, Diana L [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Jepsen, Richard Alan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Gordon, Margaret Ellen [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)


    An oscillating water column (OWC) wave energy converter is a structure with an opening to the ocean below the free surface, i.e. a structure with a moonpool. Two structural models for a non-axisymmetric terminator design OWC, the Backward Bent Duct Buoy (BBDB) are discussed in this report. The results of this structural model design study are intended to inform experiments and modeling underway in support of the U.S. Department of Energy (DOE) initiated Reference Model Project (RMP). A detailed design developed by Re Vision Consulting used stiffeners and girders to stabilize the structure against the hydrostatic loads experienced by a BBDB device. Additional support plates were added to this structure to account for loads arising from the mooring line attachment points. A simplified structure was designed in a modular fashion. This simplified design allows easy alterations to the buoyancy chambers and uncomplicated analysis of resulting changes in buoyancy.

  18. Design and study of heat transfer across the wall of the dividing-wall columns%隔离壁精馏塔水平传热设计与研究

    Institute of Scientific and Technical Information of China (English)

    李丽娜; 黄克谨


    Further energy reduction can be achieved with internal heat exchange between the wall of the dividing-wall columns( DWC). A hypothetical three-component mixture of A,B,C was considered,the initial operating parameters were carried out by shortcut three-column model, and further adjusted to achieve the optimal design by using the software of Mathematica. Horizontal heat transfer between the prefractionator and main column was studied. The results show the DWC can be obtained a 0. 9% highest energy saving compared with a DWC with no heat-integration. The number of the coupling plates and the heat transfer areas can affect the energy efficiency of DWC.%通过将隔离壁精馏塔(DWC)的隔板两侧进行水平传热,可以进一步降低DWC的能量消耗.本文以假想的三组分混合物A,B,C为例,在三塔简捷计算初值的基础上,利用Mathematica对DWC进行最终的优化设计,并进行了主塔和副塔间水平传热的研究.结果表明,与未耦合的DWC对比,耦合DWC最大能够节能0.9%,且耦合塔板数与耦合面积能够影响DWC的节能效果.

  19. Two-dimensional ion chromatography using tandem ion-exchange columns with gradient-pulse column switching. (United States)

    Johns, Cameron; Shellie, Robert A; Pohl, Christopher A; Haddad, Paul R


    A two-dimensional ion chromatography (2D-IC) approach has been developed which provides greater resolution of complex samples than is possible currently using a single column. Two columns containing different stationary phases are connected via a tee-piece, which enables an additional eluent flow and independent control of eluent concentration on each column. The resultant mixed eluent flow at the tee-piece can be varied to produce a different eluent concentration on the second column. This allows analytes strongly retained on the first column to be separated rapidly on the second column, whilst maintaining a highly efficient, well resolved separation of analytes retained weakly on the first column. A group of 18 inorganic anions has been separated to demonstrate the utility of this approach and the proposed 2D-IC method provided separation of this mixture with resolution of all analytes greater than 1.3. Careful optimisation of the eluent profiles on both columns resulted in run times of less than 28 min, including re-equilibration. Separations were performed using isocratic or gradient elution on the first column, with an isocratic separation being used on the second column. Switching of the analytes onto the second column was performed using a gradient pulse of concentrated eluent to quickly elute strongly retained analytes from the first column onto the second column. The separations were highly repeatable (RSD of 0.01-0.12% for retention times and 0.08-2.9% for peak areas) and efficient (typically 8000-260,000 plates). Detection limits were 3-80 ppb.

  20. Hysteresis of Colloid Retention and Release in Saturated Porous Media During Transients in Solution Chemistry (United States)

    Saturated packed column and micromodel transport studies wereconducted to gain insightonmechanismsof colloid retention and release under unfavorable attachment conditions. The initial deposition of colloids in porous media was found to be a strongly coupled process that depended on solution chemistr...

  1. Inner-pipe structure to improve column heterogeneity and peak shape. (United States)

    Hu, Di; Mei, Xiang; Shi, Pengchao; Zhou, Xin


    Column heterogeneity plays an important role in peak tailing and asymmetric profiles. We have designed a novel column structure (concentric column structure) that has a concentric inner-pipe nested in a column. This structure was studied by a number calculation method and wider diameter column experiments. The results showed that column heterogeneity and column efficiency were improved by inner-pipe structure. Moreover, the results showed that high-efficiency columns were stronger influenced by inner-pipe structure than low-efficiency columns. The influence of an inner-pipe was related to its size. The optimal inner-pipe diameter was nearly 0.625 times of column diameter. By using inner-pipe structure in this way, it was possible to decrease column heterogeneity and increase column efficiency of a wide-diameter column. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please email:

  2. [Ion-pair chromatography-indirect ultraviolet detection for determination of tetraethyl ammonium using a monolithic column and a packed column]. (United States)

    Zou, Chunmiao; Zhang, Xiaodong; Yu, Hong; Guan, Chao; Wang, Miaoyu


    Two methods were developed for the determination of tetraethyl ammonium by ion-pair chromatography-indirect ultraviolet detection using a monolithic column and a packed column with ionic liquid as additive in mobile phase. Chromatographic separations were performed on a monolithic column and a packed column both on reversed phase using imidazolium ionic liquid aqueous solution-ion-pair reagent-organic solvent as mobile phase. The effects of the background ultraviolet absorption reagent, detection wavelength, ion-pair reagent, organic solvent, column temperature and flow rate on the determination of tetraethyl ammonium were investigated. The difference between the two chromatographic columns was compared and the retention rules were discussed. Under the optimized chromatographic conditions, for tetraethyl ammonium on monolithic column and packed column, the retention times were 2.40 and 3.02 min; the detection limits (S/N=3), 0.04 and 0.07 mg/L; the RSDs (n = 5) for peak areas, 0.16% and 0.11%; and the RSDs (n=5) for retention times, 0.02% and 0.01%, respectively. The two methods have been successfully applied to the determination of tetraethyl ammonium ionic liquids synthesized by laboratory. The recoveries of the tetraethyl ammonium after spiking were 98.2% and 99.1%, respectively. The two methods can meet the requirements for the quantitative analysis of tetraethyl ammonium.

  3. 基于有限元分析的2MN四柱液压机液压缸设计%Design of Hydraulic Cylinder for 2 MN Four-column Hydraulic Press Based on FEM Analysis

    Institute of Scientific and Technical Information of China (English)

    卜匀; 王会刚; 刘晓雯


    The hydraulic cylinder is a widely used actuators.Based on the design theory for hydraulic press,the structure design method of four-column hydraulic press hydraulic cylinder was introduced.Static finite element analysis of cylinder part was done.Then optimization scheme was proposed.The finite element analysis results show that the improvement design is reasonable.%液压缸是一种应用广泛的执行元件。依据液压机设计理论,介绍四柱式液压机液压缸结构设计方法,对缸筒部件进行静态有限元分析,提出优化改进方案,有限元分析结果表明改进设计合理。

  4. Experimental Testing Of Partially Encased Composite Beam Columns

    Directory of Open Access Journals (Sweden)

    Ehab M. Hanna


    Full Text Available The past few decades have seen outstanding advances in the use of composite materials in structural applications. There can be little doubt that, within engineering circles, composites have revolutionized traditional design concepts and made possible an unparalleled range of new and exciting possibilities as viable materials for construction. In addition to the well-known advantages of composite columns, partially encased composite columns offered simplified beam-to-column connection as well as reduced or omitted shuttering thus achieved more cost effective construction. Some companies have patented these new types of partially encased composite column made of light welded steel shapes; moreover, the Canadian Institute of Steel construction CISC has recognized and codified this type of columns. In This paper, Partially Encased Composite Beam Columns is introduced; experimental studies are made on five partially encased beam columns to investigate the behavior of eccentrically loaded partially encased composite columns using different parameters.

  5. Eruption column physics

    Energy Technology Data Exchange (ETDEWEB)

    Valentine, G.A.


    In this paper the author focuses on the fluid dynamics of large-scale eruption columns. The dynamics of these columns are rooted in multiphase flow phenomena, so a major part of the paper sets up a foundation on that topic that allows one to quickly assess the inherent assumptions made in various theoretical and experimental approaches. The first part is centered on a set of complex differential equations that describe eruption columns, but the focus is on a general understanding of important physical processes rather than on the mathematics. The author discusses briefly the relative merits and weaknesses of different approaches, emphasizing that the largest advances in understanding are made by combining them. He then focuses on dynamics of steady eruption columns and then on transient phenomena. Finally he briefly reviews the effects of varying behavior of the ambient medium through which an eruption column moves. These final sections will emphasize concepts and a qualitative understanding of eruption dynamics. This paper relies on principles of continuum mechanics and transport processes but does not go into detail on the development of those principles. 36 refs., 36 figs., 3 tabs.

  6. Thermodynamic-based retention time predictions of endogenous steroids in comprehensive two-dimensional gas chromatography. (United States)

    Silva, Aline C A; Ebrahimi-Najafadabi, Heshmatollah; McGinitie, Teague M; Casilli, Alessandro; Pereira, Henrique M G; Aquino Neto, Francisco R; Harynuk, James J


    This work evaluates the application of a thermodynamic model to comprehensive two-dimensional gas chromatography (GC × GC) coupled with time-of-flight mass spectrometry for anabolic agent investigation. Doping control deals with hundreds of drugs that are prohibited in sports. Drug discovery in biological matrices is a challenging task that requires powerful tools when one is faced with the rapidly changing designer drug landscape. In this work, a thermodynamic model developed for the prediction of both primary and secondary retention times in GC × GC has been applied to trimethylsilylated hydroxyl (O-TMS)- and methoxime-trimethylsilylated carbonyl (MO-TMS)-derivatized endogenous steroids. This model was previously demonstrated on a pneumatically modulated GC × GC system, and is applied for the first time to a thermally modulated GC × GC system. Preliminary one-dimensional experiments allowed the calculation of thermodynamic parameters (ΔH, ΔS, and ΔC p ) which were successfully applied for the prediction of the analytes' interactions with the stationary phases of both the first-dimension column and the second-dimension column. The model was able to predict both first-dimension and second-dimension retention times with high accuracy compared with the GC × GC experimental measurements. Maximum differences of -8.22 s in the first dimension and 0.4 s in the second dimension were encountered for the O-TMS derivatives of 11β-hydroxyandrosterone and 11-ketoetiocholanolone, respectively. For the MO-TMS derivatives, the largest discrepancies were from testosterone (9.65 ) for the first-dimension retention times and 11-keto-etiocholanolone (0.4 s) for the second-dimension retention times.

  7. Psychologist Retention Factors. (United States)


  8. Ion chromatographic separation of inorganic ions using a combination of hydrophilic interaction chromatographic column and cation-exchange resin column. (United States)

    Arai, Kaori; Mori, Masanobu; Hironaga, Takahiro; Itabashi, Hideyuki; Tanaka, Kazuhiko


    A combination of hydrophilic interaction chromatographic (HILIC) column and a weakly acidic cation-exchange resin (WCX) column was used for simultaneous separation of inorganic anions and cations by ion chromatography (IC). Firstly, the capability of HILIC column for the separation of analyte ions was evaluated under acidic eluent conditions. The columns used were SeQuant ZIC-HILIC (ZIC-HILIC) with a sulfobetaine-zwitterion stationary phase (ZIC-HILIC) and Acclaim HILIC-10 with a diol stationary phase (HILIC-10). When using tartaric acid as the eluent, the HILIC columns indicated strong retentions for anions, based on ion-pair interaction. Especially, HILIC-10 could strongly retain anions compared with ZIC-HILIC. The selectivity for analyte anions of HILIC-10 with 5 mmol/L tartaric acid eluent was in the order of I(-) > NO3(-) > Br(-) > Cl(-) > H2PO4(-). However, since HILIC-10 could not separate analyte cations, a WCX column (TSKgel Super IC-A/C) was connected after the HILIC column in series. The combination column system of HILIC and WCX columns could successfully separate ten ions (Na+, NH4+, K+, Mg2+, Ca2+, H2PO4(-), Cl(-), Br(-), NO3(-) and I(-)) with elution of 4 mmol/L tartaric acid plus 8 mmol/L 18-crown-6. The relative standard deviations (RSDs) of analyte ions by the system were in the ranges of 0.02% - 0.05% in retention times and 0.18% - 5.3% in peak areas through three-time successive injections. The limits of detection at signal-to-noise ratio of 3 were 0.24 - 0.30 micromol/L for the cations and 0.31 - 1.2 micromol/L for the anions. This system was applied for the simultaneous determination of the cations and the anions in a vegetable juice sample with satisfactory results.

  9. Modelling of acid mine drainage (AMD in columns

    Directory of Open Access Journals (Sweden)

    C. M. Bernardes de Souza


    Full Text Available A model is proposed in this paper to describe the generation of acid mine drainage (AMD in leaching columns. The model considers: (i Water flow through the column, which is calculated using the 1 - D analytic solution of the Richards' equation assuming the existence of a similarity relationship between the water retention function and the water content profiles at a given time; and (ii Pyrite oxidation weighted by microbiological effects occurring in spherical particles according to the shrinking core model. Mass balances of oxygen and pyrite were derived in order to evaluate the intrinsic oxidation rate and the pyrite fraction reacted with time and column position. The model was used to simulate a six month operation of a leaching column, which comprised successive weekly cycles of dry and wet periods. Simulation results demonstrated that AMD generation is strongly affected by the presence of microorganisms. A relative deviation of 5% between simulation and experimental data was obtained.

  10. Implicit characteristic parameter of a programmed temperature retention index database

    Institute of Scientific and Technical Information of China (English)

    孙亦梁; 黄爱今; 王青清; 韦平


    In a programmed temperature retention index (PTRI) database, there exists a characteristic parameter rt0/β that can be calculated if the experimental parameters are clearly given. This characteristic parameter can be used to flexibly reproduce the original PTRI data under chromatographic conditions different from those originally given. As this characteristic parameter is not explicitly given, it is suggested to name this parameter as the implicit characteristic parameter (TCP) of a PTRI database. The ICP in White’s PTRI database was easily found and used satisfactorily to reproduce PTRI of some test compounds using either a Hewlett-Packard ultra-performance OV-1 column or a self-coated OV-1 column. The reproduction of PTRI could not be realized on columns of different materials. The fact that several PTRI databases measured on glass capillary columns could not satisfactorily be reproduced on fused silica column is explained.

  11. Columns in Clay (United States)

    Leenhouts, Robin


    This article describes a clay project for students studying Greece and Rome. It provides a wonderful way to learn slab construction techniques by making small clay column capitols. With this lesson, students learn architectural vocabulary and history, understand the importance of classical architectural forms and their influence on today's…

  12. A practical approach for predicting retention time shifts due to pressure and temperature gradients in ultra-high-pressure liquid chromatography. (United States)

    Åsberg, Dennis; Chutkowski, Marcin; Leśko, Marek; Samuelsson, Jörgen; Kaczmarski, Krzysztof; Fornstedt, Torgny


    Large pressure gradients are generated in ultra-high-pressure liquid chromatography (UHPLC) using sub-2μm particles causing significant temperature gradients over the column due to viscous heating. These pressure and temperature gradients affect retention and ultimately result in important selectivity shifts. In this study, we developed an approach for predicting the retention time shifts due to these gradients. The approach is presented as a step-by-step procedure and it is based on empirical linear relationships describing how retention varies as a function of temperature and pressure and how the average column temperature increases with the flow rate. It requires only four experiments on standard equipment, is based on straightforward calculations, and is therefore easy to use in method development. The approach was rigorously validated against experimental data obtained with a quality control method for the active pharmaceutical ingredient omeprazole. The accuracy of retention time predictions was very good with relative errors always less than 1% and in many cases around 0.5% (n=32). Selectivity shifts observed between omeprazole and the related impurities when changing the flow rate could also be accurately predicted resulting in good estimates of the resolution between critical peak pairs. The approximations which the presented approach are based on were all justified. The retention factor as a function of pressure and temperature was studied in an experimental design while the temperature distribution in the column was obtained by solving the fundamental heat and mass balance equations for the different experimental conditions. We strongly believe that this approach is sufficiently accurate and experimentally feasible for this separation to be a valuable tool when developing a UHPLC method. After further validation with other separation systems, it could become a useful approach in UHPLC method development, especially in the pharmaceutical industry where

  13. Unsaturated hydraulic conductivity of sandy soil columns packed to different bulk densities and water uptake by plantroots

    NARCIS (Netherlands)

    Rossi-Pisa, P.


    This paper describes a laboratory metbod used to determine both the soil moisture retention curve and the unsaturated hydraulic conductivity in soil columns under transient flow conditions during evaporation.

  14. Utilization of a diol-stationary phase column in ion chromatographic separation of inorganic anions. (United States)

    Arai, Kaori; Mori, Masanobu; Kozaki, Daisuke; Nakatani, Nobutake; Itabashi, Hideyuki; Tanaka, Kazuhiko


    We describe the ion chromatographic separation of inorganic anions using a diol-stationary phase column (-CH(OH)CH(2)OH; diol-column) without charged functional groups. Anions were separated using acidic eluent as in typical anion-exchange chromatography. The retention volumes of anions on the diol-column increased with increasing H(+) concentration in the eluent. The anion-exchange capacities of diol-columns in the acidic eluent (pH 2.8) were larger than that of zwitterionic stationary phase column but smaller than that of an anion-exchange column. The separation of anions using the diol-column was strongly affected by the interaction of H(+) ions with the diol-functional groups and by the types of the eluents. In particular, the selection of the eluent was very important for controlling the retention time and resolution. Good separation was obtained using a diol-column (HILIC-10) with 5 mM phthalic acid as eluent. The limits of detection at a signal-to-noise ratio of 3 ranged from 1.2 to 2.7 μM with relative standard deviations (RSD, n=5) of 0.04-0.07% for the retention time and 0.4-2.0% for the peak areas. This method was successfully applied to the determination of H(2)PO(4)(-), Cl(-), and NO(3)(-) in a liquid fertilizer sample.

  15. Rational design method for mixed structure with steel beams and reinforced concrete column. Part 1. Experimental study on beam-column joint; Hashira RC hari S kongo kozo no goriteki sekkeiho ni kansuru kenkyu. 1. Hari kantsu keishiki no setsugobu jikken

    Energy Technology Data Exchange (ETDEWEB)

    Takami, S.; Masuda, Y.; Yoshioka, K. [Obayashi Corp., Tokyo (Japan)


    Mixed structural systems of steel beams and a reinforced concrete column have been used in practical application. Several joint types have been developed, one of which is the standard steel beams passing through a reinforced concrete column. Local compressive failure (bearing failure) often occurs in this type of joint. A loading test was carried out on a beam-column joint to develop methods for reinforcing the bending strength of columns. The results are summarized as follows; (1) Bearing behavior can be improved by constructing Pre-Columns. (2) Maximum load can be increased and ductility can be improved by covering the top and bottom of columns with steel plates. 2 refs., 6 figs., 4 tabs.

  16. HPLC retention thermodynamics of grape and wine tannins. (United States)

    Barak, Jennifer A; Kennedy, James A


    The effect of grape and wine tannin structure on retention thermodynamics under reversed-phase high-performance liquid chromatography conditions on a polystyrene divinylbenzene column was investigated. On the basis of retention response to temperature, an alternative retention factor was developed to approximate the combined temperature response of the complex, unresolvable tannin mixture. This alternative retention factor was based upon relative tannin peak areas separated by an abrupt change in solvent gradient. Using this alternative retention factor, retention thermodynamics were calculated. Van't Hoff relationships of the natural log of the alternative retention factor against temperature followed Kirchoff's relationship. An inverse quadratic equation was fit to the data, and from this the thermodynamic parameters for tannin retention were calculated. All tannin fractions exhibited exothermic, spontaneous interaction, with enthalpy-entropy compensation observed. Normalizing for tannin size, distinct tannin compositional effects on thermodynamic parameters were observed. The results of this study indicate that HPLC can be valuable for measuring the thermodynamics of tannin interaction with a hydrophobic surface and provides a potentially valuable alternative to calorimetry. Furthermore, the information gathered may provide insight into understanding red wine astringency quality.

  17. The handedness of historiated spiral columns. (United States)

    Couzin, Robert


    Trajan's Column in Rome (AD 113) was the model for a modest number of other spiral columns decorated with figural, narrative imagery from antiquity to the present day. Most of these wind upwards to the right, often with a congruent spiral staircase within. A brief introductory consideration of antique screw direction in mechanical devices and fluted columns suggests that the former may have been affected by the handedness of designers and the latter by a preference for symmetry. However, for the historiated columns that are the main focus of this article, the determining factor was likely script direction. The manner in which this operated is considered, as well as competing mechanisms that might explain exceptions. A related phenomenon is the reversal of the spiral in a non-trivial number of reproductions of the antique columns, from Roman coinage to Renaissance and baroque drawings and engravings. Finally, the consistent inattention in academic literature to the spiral direction of historiated columns and the repeated publication of erroneous earlier reproductions warrants further consideration.

  18. 浮选柱中蜂窝管高效充填的设计与研究%Design and study of high-efficient honeycomb tube filling in flotation column

    Institute of Scientific and Technical Information of China (English)

    翟爱峰; 刘炯天


    In order to realize the laminar flow separation environment of the column flotation and strengthen the countercurrent collision mineralization effects of bubbles with mineral in the flotation column,after selecting and designing of main parameters of filling structure such as channel type,aperture,layer number and arrangement mode,the paper developed regular hexagon honeycomb tube packing medium used as the material of filling the column flotation section,which had the best boundary cost and had completely filling effects.CFD hydrodynamics simulation results showed that compared with sieving plate filling previously used in the flotation column,the honeycomb tube fillings could effectively limit the tangential velocity and radial velocity of the fluid from bottom to up in the flotation column.The gas holdup test results in clean water showed that the decreasing tendency of the gas holdup in honeycomb tube filling was less than that in sieve plate filling and without filling.The industrial application indexes of a copper sulphide ore showed that the honeycomb tube filling flotation column obtained basically equal concentrate grade with sieving plate filling,the copper recovery of honeycomb tube filling reached 92.92%,which was 1% above that of sieve plate filling,the separation index of copper sulphide ore improved.%以实现柱浮选段的层流分选环境,促进浮选柱中气泡与矿物的逆流碰撞矿化效果为出发点,通过充填结构的通道形式、孔径、层数及布置方式等主要参数的选择与设计,开发了边界成本最优且能完全充填的正六边形蜂窝管填料对浮选柱的柱浮选段进行充填。CFD流体力学数值模拟结果表明,蜂窝管充填与原先浮选柱中采用的筛板充填相比,更能有效地对柱体中由下而上流体的切向速度和径向速度进行限制。清水条件下的气含率测试。试验结果表明,蜂窝管充填的气含率降低趋势小于筛板充填和无充填的情况

  19. Study of clean up procedures using Charcoal-Alumina-Celite column, immunoaffinity column and strata x column to determine deoxynivalenol by high performance liquid chromatography in wheat

    Directory of Open Access Journals (Sweden)

    Jacqueline Cea


    extraction solvent was acetonitrile- water (84+16. Column was conditioned with methanol 100% and water. Prior to pass an aliquot of the extract through the column it was necessary to reduce the acetonitrile to 10% using vacuum. Column was washed using methanol 15 %, and DON eluated using methanol 100%. An internal reference flour material (2010  g/kg was analysed following the three procedures. For PEC.TOX.063 the historical recovery percentage of 91% was maintained, for immunoaffinity column protocol 84 % average was obtained, and for Strata X column 101% was obtained. Chromatograms and spectrums showed appropriated results. As the recoveries were acceptable it was decided to start with wheat samples analysis. Taking approval of the reference material and the IAC, the reuse of the columns was also estimated. Columns were regenerated with phosphate buffer solution (PBS and storage in the fridge for 24 hours. At least three uses were undertaken with accepted recovery results (91, 69 and 104% respectively. A total of 21 samples including wheat and reference internal material were analysed following PEC.TOX.063 (charcoal-alumina-celite and immunoaffinity column method (first, second and third use . Nine samples from the 21 were also analysed using Strata X columns. PEC.TOX 063 and the immunoaffinity method showed appropriate chromatograms. This didn't occur with Strata X columns method. Chromatograms presented interferences at DON retention time. Due to chromatograms and results obtained no more samples were passed through Strata X columns. As conclusion charcoal-alumina-celite (7+5+3, as well as immunoaffinity column would be a good option to analysed wheat samples by HPLC. For the Strata X Phenomenex columns more studies need to be done in order to optimize the elution solvent.

  20. Distributed Revisiting: An Analytic for Retention of Coherent Science Learning (United States)

    Svihla, Vanessa; Wester, Michael J.; Linn, Marcia C.


    Designing learning experiences that support the development of coherent understanding of complex scientific phenomena is challenging. We sought to identify analytics that can also guide such designs to support retention of coherent understanding. Based on prior research that distributing study of material over time supports retention, we explored…



    Nina Fauziah; Andang Widiharto; Yohannes Sardjono


    Studies were carried out to design a collimator which results in epithermal neutron beam for IN VITRO and IN VIVO of Boron Neutron Capture Therapy (BNCT) at the Kartini research reactor by means of Monte Carlo N-Particle (MCNP) codes. Reactor within 100 kW of thermal power was used as the neutron source. The design criteria were based on recommendation from the International Atomic Energy Agency (IAEA). All materials used were varied in size, according to the value of mean free path for each ...

  2. Retention--A Pseudo-Problem? (United States)

    Geis, George L.


    Discusses retention of learning; training methods; maintenance issues; the effect of punishment; reinforcement; the performance environment; transfer of training; forgetting; implications for designers of instructional materials or designers of training programs; and the division between training and on-the-job performance. (LRW)

  3. Temperature-compensated 8-bit column driver for AMLCD (United States)

    Dingwall, Andrew G. F.; Lin, Mark L.


    An all-digital, 5 V input, 50 Mhz bandwidth, 10-bit resolution, 128- column, AMLCD column driver IC has been designed and tested. The 10-bit design can enhance display definition over 6-bit nd 8-bit column drivers. Precision is realized with on-chip, switched-capacitor DACs plus transparently auto-offset-calibrated, opamp outputs. Increased resolution permits multiple 10-bit digital gamma remappings in EPROMs over temperature. Driver IC features include externally programmable number of output column, bi-directional digital data shifting, user- defined row/column/pixel/frame inversion, power management, timing control for daisy-chained column drivers, and digital bit inversion. The architecture uses fewer reference power supplies.

  4. Transport and retention of bacteria and viruses in biochar-amended sand. (United States)

    Sasidharan, Salini; Torkzaban, Saeed; Bradford, Scott A; Kookana, Rai; Page, Declan; Cook, Peter G


    The transport and retention of Escherichia coli and bacteriophages (PRD1, MS2 and ФX174), as surrogates for human pathogenic bacteria and viruses, respectively, were studied in the sand that was amended with several types of biochar produced from various feedstocks. Batch and column studies were conducted to distinguish between the role of attachment and straining in microbe retention during transport. Batch experiments conducted at various solution chemistries showed negligible attachment of viruses and bacteria to biochar before or after chemical activation. At any given solution ionic strength, the attachment of viruses to sand was significantly higher than that of biochar, whereas bacteria showed no attachment to either sand or biochar. Consistent with batch results, biochar addition (10% w/w) to sand reduced virus retention in the column experiments, suggesting a potential negative impact of biochar application to soil on virus removal. In contrast, the retention of bacteria was enhanced in biochar-amended sand columns. However, elimination of the fine fraction (bacteria retention. Results from batch and column experiments suggest that land application of biochar may only play a role in microbe retention via straining, by alteration of pore size distribution, and not via attachment. Consequently, the particle size distribution of biochar and sediments is a more important factor than type of biochar in determining whether land application of biochar enhances or diminishes microbial retention.

  5. Drug Retention Times

    Energy Technology Data Exchange (ETDEWEB)

    Center for Human Reliability Studies


    The purpose of this monograph is to provide information on drug retention times in the human body. The information provided is based on plausible illegal drug use activities that might be engaged in by a recreational drug user.

  6. Drug Retention Times

    Energy Technology Data Exchange (ETDEWEB)

    Center for Human Reliability Studies


    The purpose of this monograph is to provide information on drug retention times in the human body. The information provided is based on plausible illegal drug use activities that might be engaged in by a recreational drug user

  7. Liquid Effluent Retention Facility (United States)

    Federal Laboratory Consortium — The Liquid Effluent Retention Facility (LERF) is located in the central part of the Hanford Site. LERF is permitted by the State of Washington and has three liquid...

  8. 80MN双柱式预应力结构快速锻造液压机的设计研发%Design and development of 80 MN double columns high speed forging hydraulic press in pre-stress structure

    Institute of Scientific and Technical Information of China (English)

    张亦工; 陈峰


    The technical characteristics and design methods of 8O MN double columns high speed forging hydraulic press in pre-stress structure which is driven directly by pump have been introduced. The innovations in structure, drive mode, and control technology for large open-die forging hydraulic press have been realized. The application shows that the overall performance parameters of the forging hydraulic press reach the worldwide advanced level.%阐述了80MN油泵直接传动、双柱式预应力结构快速锻造液压机技术特点及设计方法,实现了大型自由锻造液压机结构、传动方式和控制技术的创新.工程应用表明,该锻造液压机整机性能指标达到国际先进水平.

  9. Behavior of Columns During Earthquakes (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The behavior of columns during earthquakes is very important since column failures may lead to additional structural failures and result in total building collapses....

  10. Determination of Two Columns Performance

    Institute of Scientific and Technical Information of China (English)


    When protein is analyzed by high performance liquid chromatography (HPLC), the selection of column is one of the most important factors. There are four quality control parameters for the column, which are theoretical plates n, capacity facto

  11. NMFS Water Column Sonar Database (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Water column sonar data are an important component of fishery independent surveys, habitat studies and other research. NMFS water column sonar data are archived here.

  12. 应用隔壁式精馏塔分离煤制烯烃设计%Design of Separation Process with Dividing-Wall Column for Light Olefins Based Coal

    Institute of Scientific and Technical Information of China (English)

    李俊龙; 陈超; 倪欣怡; 王丹丹; 孙强; 郭绪强


    利用 Aspen HYSYS 流程模拟软件完成隔壁式精馏塔的设计,设计过程中引用逻辑操作单元将隔壁式精馏塔的预分离塔与主精馏塔进行了耦合,逻辑操作单元的引入可以减少隔壁式精馏塔的自由度,从而降低了精馏塔模拟达到稳态时的难度。在完成精馏塔设计并得到结果的基础上,对稳态工艺过程模拟结果进行灵敏度分析,考察了隔壁式精馏塔侧线抽出流量、回流比、进料温度、气相回流流量和液相回流流量对隔壁式精馏塔塔顶、中间以及塔底组成的影响,得到优化后的工艺操作参数。同时根据隔壁式精馏塔分离产物的组成提出并联分离顺序,与原有的顺序分离相比流程更加紧凑,对实际的烯烃分离流程的设计工作具有参考意义。%A design about application of dividing-wall to separate light olefins based coal was accomplished in software Aspen HYSYS.The logic recycle operation units coupled the pre-fractionator with main fractionator,which could reduce the number of column freedom.The sensitivity analyses were made on the base of stable process design,which included the relationship between middle stream mole flow rate drown out of main column,reflex ratio,feed stream temperature,vapor mole flow rate recycle back to pre-fractionator,liquid recycle back to pre-fractionator and main column top,middle and bottom composition, then optimized operation parameters were obtained.And a novel separation process was addressed according to the mole fraction of three production stream,which was more compact than traditional separation process.

  13. Robust Geometric Control of a Distillation Column

    DEFF Research Database (Denmark)

    Kymmel, Mogens; Andersen, Henrik Weisberg


    A frequency domain method, which makes it possible to adjust multivariable controllers with respect to both nominal performance and robustness, is presented. The basic idea in the approach is that the designer assigns objectives such as steady-state tracking, maximum resonance peaks, bandwidth, m...... is used to examine and improve geometric control of a binary distillation column....

  14. Probability theory for number of mixture components resolved by n independent columns. (United States)

    Davis, Joe M; Blumberg, Leonid M


    A general theory is proposed for the probability of different outcomes of success and failure of component resolution, when complex mixtures are partially separated by n independent columns. Such a separation is called an n-column separation. An outcome of particular interest is component resolution by at least one column. Its probability is identified with the probability of component resolution by a single column, thereby defining the effective saturation of the n-column separation. Several trends are deduced from limiting expressions of the effective saturation. In particular, at low saturation the probability that components cluster together as unresolved peaks decreases exponentially with the number of columns, and the probability that components cluster together on addition of another column decreases by a factor equal to twice the column saturation. The probabilities of component resolution by n-column and two-dimensional separations also are compared. The theory is applied by interpreting three sets of previously reported retention indices of the 209 polychlorinated biphenyls (PCBs), as determined by GC. The origin of column independence is investigated from two perspectives. First, it is suggested that independence exists when the difference between indices of the same compound on two columns is much larger than the interval between indices required for separation. Second, it is suggested that independence exists when the smaller of the two intervals between a compound and its adjacent neighbors is not correlated with its counterpart on another column.

  15. 隔壁精馏塔的设计、模拟与优化%Design,Simulation and Optimization of Divided Wall Column

    Institute of Scientific and Technical Information of China (English)

    黄国强; 靳权


    针对隔壁精馏塔节能工艺,提供了一套完整的设计优化方法。首先基于 Fenske-Underwood-Gilliland-Kirkbride 方程建立了完整的简捷设计方法,得到了隔壁精馏塔塔实际理论板数、适宜的进料位置、侧线采出位置及回流比等参数。然后在简捷计算的基础之上,选用 Multifrac 模型对隔壁塔进行了严格计算模拟,同时利用 Aspen Plus 进行单因素优化分析得到最优设计参数。最后利用响应面优化法(RSM)中的箱线图设计(BBD)方法对隔壁精馏塔设计参数进行了实验设计,在验证模型有效的基础上运用Design-Expert软件进行数据处理,预测出了最优设计参数,并将预测值进行实验验证,将验证结果与单因素优化结果进行对比,结果表明响应面优化法得到的最优设计参数使隔壁塔的能耗较低、纯度较高。%A set of comprehensive methods was proposed for the design and optimization of divided wall col-umn(DWC). A short-cut design method based on Fenske-Underwood-Gilliland-Kirkbride equations for DWC was used to get initial values of design parameters of theoretical stages,feed stage,side-product stage,reflux ratio and so on. With the initial values of all parameters from short-cut design,rigorous simulation of DWC was carried out using Multifrac model. The optimization result was obtained through single-factor experiment using Aspen Plus. In the last stage,Box-Behnken design(BBD)under response surface methodology(RSM)was used for the optimization of DWC and to evaluate the effects of parameters and their interactions on energy efficiency and product purity. Design-Expert software was used to tackle experiment data and predict optimization result based on significant model. Com-paring the optimization result of single-factor experiment and RSM,we found that RSM could render more optimized result in respect of energy saving and high purity.

  16. Packed column supercritical fluid chromatography using stainless steel particles and water as a stationary phase. (United States)

    Murakami, Jillian N; Thurbide, Kevin B


    Stainless steel (SS) particles were demonstrated as a novel useful support for a water stationary phase in packed column supercritical fluid chromatography using a CO2 mobile phase. Separations employed flame ionization detection, and the system was operated over a range of temperatures and pressures. Retention times reproduced well with RSD values of 2.6% or less. Compared to analogous separations employing a water stationary phase coated onto a SS capillary column, the packed column method provided separations that were about 10× faster, with nearly 8-fold larger analyte retention factors, while maintaining good peak shape and comparable column efficiency. Under normal operating conditions, the packed column contains about 131 ± 4 μL/m of water phase (around a 5% m/m coating), which is over 25× greater than the capillary column and also affords it a 20-fold larger sample capacity. Several applications of the packed column system are examined, and the results indicate that it is a useful alternative to the capillary column mode, particularly where analyte loads or sample matrix interference is a concern. Given its high sample capacity, this packed column method may also be useful to explore on a more preparative scale in the future.

  17. Column: Every Last Byte

    Directory of Open Access Journals (Sweden)

    Simson Garfinkel


    Full Text Available Inheritance powder is the name that was given to poisons, especially arsenic, that were commonly used in the 17th and early 18th centuries to hasten the death of the elderly. For most of the 17th century, arsenic was deadly but undetectable, making it nearly impossible to prove that someone had been poisoned. The first arsenic test produced a gas—hardly something that a scientist could show to a judge. Faced with a growing epidemic of poisonings, doctors and chemists spent decades searching for something better.(see PDF for full column

  18. Retention and resistance of preparations for cast restorations. (United States)

    Potts, R G; Shillingburg, H T; Duncanson, M G


    Five preparation designs were tested for retention and resistance. Retention values for all partial veneer crowns were significantly lower than those for the complete veneer crown. Resistance values increased significantly with the addition of grooves and/or extension of axial surface coverage. Addition of grooves and/or extension of axial surface coverage produced small increases in retention values but marked increases in resistance values.

  19. Best practices in doctoral retention: Mentoring

    Directory of Open Access Journals (Sweden)

    Judie L. Brill


    Full Text Available The aim of this critical literature review is to outline best practices in doctoral retention and the successful approach of one university to improve graduation success by providing effective mentorship for faculty and students alike. The focus of this literature review is on distance learning relationships between faculty and doctoral students, regarding retention, persistence, and mentoring models. Key phrases and words used in the search and focusing on mentoring resulted in over 20,000 sources. The search was narrowed to include only doctoral study and mentoring. Research questions of interest were: Why do high attrition rates exist for doctoral students? What are the barriers to retention? What are the benefits of doctoral mentoring? What programs do institutions have in place to reduce attrition? The researchers found a key factor influencing doctoral student retention and success is effective faculty mentorship. In particular, the design of a mentoring and faculty training program to increase retention and provide for success after graduation is important. This research represents a key area of interest in the retention literature, as institutions continue to search for ways to better support students during their doctoral programs and post-graduation. DOI: 10.18870/hlrc.v4i2.186

  20. Retention of the posterior cruciate ligament versus the posterior stabilized design in total knee arthroplasty : a prospective randomized controlled clinical trial

    NARCIS (Netherlands)

    van den Boom, L.G.H.; Brouwer, R.W.; van den Akker-Scheek, I.; Bulstra, S.K.; van Raaij, J.J.A.M.


    Background: Prosthetic design for the use in primary total knee arthroplasty has evolved into designs that preserve the posterior cruciate ligament (PCL) and those in which the ligament is routinely sacrificed (posterior stabilized). In patients with a functional PCL the decision which design is cho

  1. Design and implementation of automatic welding system for column-wing-type radiators of steel combined with aluminum%钢铝复合柱翼型散热器自动焊接系统设计与实现

    Institute of Scientific and Technical Information of China (English)

    张冠; 赵冬梅; 梁楚华


    为实现钢铝复合柱翼型散热器连续自动焊接,设计了一种基于工业PC机和运动控制卡的多轴联动控制系统。上位机软件实时调用PCI1040运动控制卡自身函数并接收传感器、限位开关的反馈信号来规划并控制焊接动作。为解决顺序焊接过程中焊接变形累积问题,该控制系统新增了位置检测模块。实验证明,该专用自动焊接系统在进行钢铝复合柱翼型散热器焊接过程中能够持续稳定可靠地焊接,达到了良好的焊接效果。%To achieve continuous automatic welding of column-wing-type radiators of steel combined with aluminum ,a multi-axis control system is designed based on IPC and motion control card .PC software can call the function of motion control card PCI1040 real-time and receive feedback signals of the sensors ,and limit switches for the plan and control of welding .The control system adds a position detection module to solve the problem of welding deformation accumulation during welding process in succession .Experimental results prove that the special automatic welding system can satisfy the welding of column-wing-type radiators of steel combined with aluminum steadily and reliably ,achieving a good welding effect .

  2. High-performance liquid chromatography separation of unsaturated organic compounds by a monolithic silica column embedded with silver nanoparticles. (United States)

    Zhu, Yang; Morisato, Kei; Hasegawa, George; Moitra, Nirmalya; Kiyomura, Tsutomu; Kurata, Hiroki; Kanamori, Kazuyoshi; Nakanishi, Kazuki


    The optimization of a porous structure to ensure good separation performances is always a significant issue in high-performance liquid chromatography column design. Recently we reported the homogeneous embedment of Ag nanoparticles in periodic mesoporous silica monolith and the application of such Ag nanoparticles embedded silica monolith for the high-performance liquid chromatography separation of polyaromatic hydrocarbons. However, the separation performance remains to be improved and the retention mechanism as compared with the Ag ion high-performance liquid chromatography technique still needs to be clarified. In this research, Ag nanoparticles were introduced into a macro/mesoporous silica monolith with optimized pore parameters for high-performance liquid chromatography separations. Baseline separation of benzene, naphthalene, anthracene, and pyrene was achieved with the theoretical plate number for analyte naphthalene as 36,000 m(-1). Its separation function was further extended to cis/trans isomers of aromatic compounds where cis/trans stilbenes were chosen as a benchmark. Good separation of cis/trans-stilbene with separation factor as 7 and theoretical plate number as 76,000 m(-1) for cis-stilbene was obtained. The trans isomer, however, is retained more strongly, which contradicts the long- established retention rule of Ag ion chromatography. Such behavior of Ag nanoparticles embedded in a silica column can be attributed to the differences in the molecular geometric configuration of cis/trans stilbenes.

  3. Temperature-assisted on-column solute focusing: a general method to reduce pre-column dispersion in capillary high performance liquid chromatography. (United States)

    Groskreutz, Stephen R; Weber, Stephen G


    Solvent-based on-column focusing is a powerful and well known approach for reducing the impact of pre-column dispersion in liquid chromatography. Here we describe an orthogonal temperature-based approach to focusing called temperature-assisted on-column solute focusing (TASF). TASF is founded on the same principles as the more commonly used solvent-based method wherein transient conditions are created that lead to high solute retention at the column inlet. Combining the low thermal mass of capillary columns and the temperature dependence of solute retention TASF is used effectively to compress injection bands at the head of the column through the transient reduction in column temperature to 5°C for a defined 7mm segment of a 6cm long 150μm I.D. column. Following the 30s focusing time, the column temperature is increased rapidly to the separation temperature of 60°C releasing the focused band of analytes. We developed a model to simulate TASF separations based on solute retention enthalpies, focusing temperature, focusing time, and column parameters. This model guides the systematic study of the influence of sample injection volume on column performance. All samples have solvent compositions matching the mobile phase. Over the 45-1050nL injection volume range evaluated, TASF reduces the peak width for all solutes with k' greater than or equal to 2.5, relative to controls. Peak widths resulting from injection volumes up to 1.3 times the column fluid volume with TASF are less than 5% larger than peak widths from a 45nL injection without TASF (0.07 times the column liquid volume). The TASF approach reduced concentration detection limits by a factor of 12.5 relative to a small volume injection for low concentration samples. TASF is orthogonal to the solvent focusing method. Thus, it can be used where on-column focusing is required, but where implementation of solvent-based focusing is difficult.

  4. Simulating a fuzzy level controller for flotation columns

    Institute of Scientific and Technical Information of China (English)

    Liao Yinfei; Liu Jiongtian; Wang Yongtian; Cao Yijun


    Level control in flotation columns is an important factor that influences the recovery and the grade of concentrate from the column.A flotation column is a nonlinear,multi-variable problem with changeable parameters that traditional methods have difficulty controlling.We have applied fuzzy control methods to the flotation column and tested the performance of the design by Matlab/Simulink simulation.The simulations show that level control in the flotation column becomes smoother and more rapid with the fuzzy controller.Compared to PID control methods the overshoot in valve position,the adjustment time,and the robustness of the controller are all improved.This indicates that it is suitable to model fuzzy controllers in applications for the study of automatic control of flotation column.


    Institute of Scientific and Technical Information of China (English)

    舒赣平; 郑宝锋; 沈晓明


    Test results of the stainless steel material property indicate that: considerable difference exists among different states of the same type stainless steel and also exists among varieties of type. However this difference is not directly considered in the typical design codes existing in the world. Based on the verified FEM model, total 30 column curves are calculated that covered the range of material properties in common use. The concept of modification slenderness ratio is utilized to modify the Perry formula and the K&R formula; at last, new design formula is obtained for calculating the buckling strength of stainless steel columns. Comparisons between the available test resuh and the proposed approach are conducted. The comparisons indicated that the proposed approach could fit the test results well. This approach could be used as a reference for the first version of stainless steel design code of China.%国内外不锈钢材料力学性能的试验资料表明:不同牌号不锈钢材料的力学性能差别较大;同牌号不锈钢材料的力学性能也有一定差别,而材料力学性能变化对轴心受压不锈钢柱的稳定性系数的影响在国外典型不锈钢结构设计规范中均无明确的规定。基于经验证的有限元模型,计算了30种典型不锈钢材料的稳定系数曲线,采用修正正则化长细比概念对Perry公式及K&R公式进行改进,得到适用于常用不锈钢材料力学性能的轴心受压柱稳定系数表达式,并与国内外已有的试验数据进行对比,结果表明,此表达式具有较高的精度,可供我国不锈钢结构设计规程中轴心受压构件设计条文编制参考。

  6. Meningitis retention syndrome

    Directory of Open Access Journals (Sweden)

    Abhishek Krishna


    Full Text Available A 50-year-old Caucasian woman presented with signs and symptoms of meningitis preceded by a 3 day history of flu-like symptoms and progressive difficulty with urination. Cerebrospinal Fluid (CSF analysis was consistent with aseptic meningitis. She was found to have a significant urinary retention secondary to atonic bladder. MRI of the brain and spine were normal and CSF-PCR (polymerase chain reaction was positive for HSV-2. Urinary retention in the context of meningitis and CSF pleocytosis is known as Meningitis Retention Syndrome (MRS. MRS is a rare but important complication of meningitis most commonly associated with HSV-2. Involvement of central pathways may have a role in the pathogenesis of MRS but this is poorly documented. MRS is different from Elsberg syndrome wherein patients display features of lumbosacral polyradiculitis or radiculomyelitis. Early treatment with antiviral therapy was associated with a favorable outcome in our patient.

  7. An artificial neural network approach for aerodynamic performance retention in airframe noise reduction design of a 3D swept wing model

    Institute of Scientific and Technical Information of China (English)

    Tao Jun; Sun Gang


    With the progress of high-bypass turbofan and the innovation of silencing nacelle in engine noise reduction, airframe noise has now become another important sound source besides the engine noise. Thus, reducing airframe noise makes a great contribution to the overall noise reduction of a civil aircraft. However, reducing airframe noise often leads to aerodynamic perfor-mance loss in the meantime. In this case, an approach based on artificial neural network is intro-duced. An established database serves as a basis and the training sample of a back propagation (BP) artificial neural network, which uses confidence coefficient reasoning method for optimization later on. Then the most satisfactory configuration is selected for validating computations through the trained BP network. On the basis of the artificial neural network approach, an optimization pro-cess of slat cove filler (SCF) for high lift devices (HLD) on the Trap Wing is presented. Aerody-namic performance of both the baseline and optimized configurations is investigated through unsteady detached eddy simulations (DES), and a hybrid method, which combines unsteady DES method with acoustic analogy theory, is employed to validate the noise reduction effect. The numerical results indicate not merely a significant airframe noise reduction effect but also excel-lent aerodynamic performance retention simultaneously.

  8. An artificial neural network approach for aerodynamic performance retention in airframe noise reduction design of a 3D swept wing model

    Directory of Open Access Journals (Sweden)

    Tao Jun


    Full Text Available With the progress of high-bypass turbofan and the innovation of silencing nacelle in engine noise reduction, airframe noise has now become another important sound source besides the engine noise. Thus, reducing airframe noise makes a great contribution to the overall noise reduction of a civil aircraft. However, reducing airframe noise often leads to aerodynamic performance loss in the meantime. In this case, an approach based on artificial neural network is introduced. An established database serves as a basis and the training sample of a back propagation (BP artificial neural network, which uses confidence coefficient reasoning method for optimization later on. Then the most satisfactory configuration is selected for validating computations through the trained BP network. On the basis of the artificial neural network approach, an optimization process of slat cove filler (SCF for high lift devices (HLD on the Trap Wing is presented. Aerodynamic performance of both the baseline and optimized configurations is investigated through unsteady detached eddy simulations (DES, and a hybrid method, which combines unsteady DES method with acoustic analogy theory, is employed to validate the noise reduction effect. The numerical results indicate not merely a significant airframe noise reduction effect but also excellent aerodynamic performance retention simultaneously.

  9. Why Hexagonal Basalt Columns? (United States)

    Hofmann, Martin; Anderssohn, Robert; Bahr, Hans-Achim; Weiß, Hans-Jürgen; Nellesen, Jens


    Basalt columns with their preferably hexagonal cross sections are a fascinating example of pattern formation by crack propagation. Junctions of three propagating crack faces rearrange such that the initial right angles between them tend to approach 120°, which enables the cracks to form a pattern of regular hexagons. To promote understanding of the path on which the ideal configuration can be reached, two periodically repeatable models are presented here involving linear elastic fracture mechanics and applying the principle of maximum energy release rate. They describe the evolution of the crack pattern as a transition from rectangular start configuration to the hexagonal pattern. This is done analytically and by means of three-dimensional finite element simulation. The latter technique reproduces the curved crack path involved in this transition.

  10. Column: File Cabinet Forensics

    Directory of Open Access Journals (Sweden)

    Simson Garfinkel


    Full Text Available Researchers can spend their time reverse engineering, performing reverse analysis, or making substantive contributions to digital forensics science. Although work in all of these areas is important, it is the scientific breakthroughs that are the most critical for addressing the challenges that we face.Reverse Engineering is the traditional bread-and-butter of digital forensics research. Companies like Microsoft and Apple deliver computational artifacts (operating systems, applications and phones to the commercial market. These artifacts are bought and used by billions. Some have evil intent, and (if society is lucky, the computers end up in the hands of law enforcement. Unfortunately the original vendors rarely provide digital forensics tools that make their systems amenable to analysis by law enforcement. Hence the need for reverse engineering.(see PDF for full column

  11. European Analytical Column

    DEFF Research Database (Denmark)

    Karlberg, B.; Grasserbauer, M.; Andersen, Jens Enevold Thaulov


    The European Analytical Column has once more invited a guest columnist to give his views on various matters related to analytical chemistry in Europe. This year, we have invited Professor Manfred Grasserbauer of the Vienna University of Technology to present some of the current challenges...... for European analytical chemistry. During the period 2002–07, Professor Grasserbauer was Director of the Institute for Environment and Sustainability, Joint Research Centre of the European Commission (EC), Ispra, Italy. There is no doubt that many challenges exist at the present time for all of us representing...... a major branch of chemistry, namely analytical chemistry. The global financial crisis is affecting all branches of chemistry, but analytical chemistry, in particular, since our discipline by tradition has many close links to industry. We have already noticed decreased industrial commitment with respect...


    Cooley, C.R.


    The patented extraction apparatus includes a column, perforated plates extending across the column, liquid pulse means connected to the column, and an imperforate spiral ribbon along the length of the column.

  13. 抽柱门式刚架结构设计要点及对厂房经济性影响分析%Structure Design Points of the Steel Column-removed Portal Frame and Analysis of the Economic Impact on Plant Building

    Institute of Scientific and Technical Information of China (English)

    段潇川; 王小龙


    Taking the continuous multi-span and multi-slope portal frame as example,this paper analyzed the steel column-removed portal frame.Combined with China current code,the design methods and points of steel column-re-moved portal frame were illustrated.The steel quantity was compared between column-removed portal frame and none column-removed portal frame model.The conclusion was get that the structure form of steel column-removed portal frame is better than traditional none column-removed portal frame.%文章以连续多跨多坡门式刚架为算例,对抽柱门式刚架进行分析,提出了抽柱门式刚架的设计方法。结合我国现行规范对抽柱门式刚架的设计要点进行了说明,同时对比门式刚架中间抽柱和非抽柱模型的用钢量。得出结论:抽柱门式刚架结构形式优于传统非抽柱门刚。

  14. Pressure Tuning of First Dimension Columns in Comprehensive Two-Dimensional Gas Chromatography. (United States)

    Sharif, Khan M; Kulsing, Chadin; Marriott, Philip J


    The experimental approach and mechanism of pressure tuning (PT) are introduced for the first stage of a comprehensive two-dimensional gas chromatography (GC × GC) separation. The PT-GC × GC system incorporates a first dimension ((1)D) coupled column ensemble comprising a pair of (1)D columns ((1)D1 and (1)D2) connected via a microfluidic splitter device, allowing variable decompression of carrier gas across each (1)D column, and a conventional (2)D narrow bore column. By variation of junction pressure between the (1)D1 and (1)D2 columns, tunable total (1)D retentions of analytes are readily derived. Separations of a standard mixture comprising a number of different chemical classes (including alkanes, monoaromatics, alcohols, aldehydes, ketones, and esters) and Australian tea tree oil (TTO) were studied as practical examples of the PT-GC × GC system application. This illustrated the change of analyte retention time with experimental conditions depending on void time and retention on the different columns. In addition to void time change, variation of carrier gas relative decompression in the (1)D ensemble leads to tunable contribution of the (1)D1/(1)D2 columns that changes apparent polarity and selectivity of the ensemble. The resulting changes in (1)D elution order further altered elution temperature and thus retention of each analyte on the (2)D column in temperature-programmed GC × GC. 2D orthogonality measurements were then conducted to evaluate overall separation performance under application of different (1)D junction pressure. As a result, distribution and selectivity of particular target compounds, monoterpenes, sesquiterpenes, and oxygenated terpenes in 2D space, and thus orthogonality, could be adequately tuned. This indicates the potential of PT-GC × GC to be applicable for practical sample separation and provides a general approach to tune selectivity of target compounds.

  15. Evaluation of {sup 131}I retention in several adsorbers

    Energy Technology Data Exchange (ETDEWEB)

    Catanoso, Marcela F.; Osso Junior, Joao Alberto, E-mail:, E-mail: jaosso@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Diretoria de Radiofarmacia


    Several iodine radioisotopes are used in nuclear medicine for treatment and diagnostic purposes. The radioisotope {sup 131}I is used both in diagnosis and therapy due to its physical characteristics of decay by {beta}{sup -} and its {gamma}-ray emissions suitable for diagnosis. It is routinely produced at IPEN through the irradiation of TeO{sub 2} targets in the IEA-R1m nuclear reactor. After the irradiation, the {sup 131}I is separated by dry distillation, where the targets are put in an oven, heated at 760 deg C for 2 hours and the {sup 131}I, volatile, is carried by an O{sub 2} gas stream. The aim of this work was to evaluate the retention and elution of {sup 131}I samples produced at IPEN in several adsorbers as part of a project aiming the purification of these radioisotopes, allowing the labeling of biomolecules. Samples of {sup 131}I were used for retention and elution studies with the following adsorbers: commercial cartridges, anionic resin columns and cationic resin column. The results showed that Ag cartridges and anionic resins Dowex 1X8, Dowex 3 and IRA 400 had a great iodine retention but no elution after using specific eluents. The QMA light, acid alumina, neutral alumina and cationic resin Dowex 50WX4 showed high retention and elution and QMA plus and cationic resin Dowex 50WX8 and Dowex 50WX12 had a good retention but lower elution. Regarding to the better retention and elution, Ag cartridges and resins showed a higher percentage of iodine retention but lower elution yield and QMA light, acid and neutral alumina cartridges showed better results. (author)

  16. Sum of ranking differences to rank stationary phases used in packed column supercritical fluid chromatography. (United States)

    West, Caroline; Khalikova, Maria A; Lesellier, Eric; Héberger, Károly


    The identification of a suitable stationary phase in supercritical fluid chromatography (SFC) is a major source of difficulty for those with little experience in this technique. Several protocols have been suggested for column classification in high-performance liquid chromatography (HPLC), gas chromatography (GC), and SFC. However, none of the proposed classification schemes received general acceptance. A fair way to compare columns was proposed with the sum of ranking differences (SRD). In this project, we used the retention data obtained for 86 test compounds with varied polarity and structure, analyzed on 71 different stationary phases encompassing the full range in polarity of commercial packed columns currently available to the SFC chromatographer, with a single set of mobile phase and operating conditions (carbon dioxide-methanol mobile phase, 25°C, 150bar outlet pressure, 3ml/min). First, a reference column was selected and the 70 remaining columns were ranked based on this reference column and the retention data obtained on the 86 analytes. As these analytes previously served for the calculation of linear solvation energy relationships (LSER) on the 71 columns, SRD ranks were compared to LSER methodology. Finally, an external comparison based on the analysis of 10 other analytes (UV filters) related the observed selectivity to SRD ranking. Comparison of elution orders of the UV filters to the SRD rankings is highly supportive of the adequacy of SRD methodology to select similar and dissimilar columns.

  17. Recruitment and Retention of Latino Children in a Lifestyle Intervention (United States)

    Guzman, Angelica; Richardson, Irma M.; Gesell, Sabina; Barkin, Shari L.


    Objective: To describe promising recruitment and retention strategies for transient Latino populations, assisting investigators who work with this population in their research design and implementation. Methods: Strategies in recruitment and retention from a year-long intervention in children and their families are described. Results: Of the 159…

  18. Water retention in mushroom during sustainable processing

    NARCIS (Netherlands)

    Paudel, E.


    This thesis deals with the understanding of the water holding capacity of mushroom, in the context of a redesign of their industrial processing. For designing food process the retention of food quality is of the utmost importance. Water holding capacity is an important quality aspect of mushrooms. A

  19. Water retention in mushroom during sustainable processing

    NARCIS (Netherlands)

    Paudel, E.


    This thesis deals with the understanding of the water holding capacity of mushroom, in the context of a redesign of their industrial processing. For designing food process the retention of food quality is of the utmost importance. Water holding capacity is an important quality aspect of mushrooms. A

  20. Effects of Emotional Intelligence on Teacher Retention (United States)

    Gerald, Grant Ronald


    This mixed methods, explanatory design study focused on determining if the emotional intelligence of principals affects the retention of new teachers. In phase one, a non-random cluster sample of 138 public school principals in the state of Louisiana was surveyed using a quantitative instrument. A Factor Analysis, Analysis of Variance (ANOVA), and…

  1. Dissolved nutrients and atrazine removal by column-scale monophasic and biphasic rain garden model systems. (United States)

    Yang, Hanbae; McCoy, Edward L; Grewal, Parwinder S; Dick, Warren A


    Rain gardens are bioretention systems that have the potential to reduce peak runoff flow and improve water quality in a natural and aesthetically pleasing manner. We compared hydraulic performance and removal efficiencies of nutrients and atrazine in a monophasic rain garden design versus a biphasic design at a column-scale using simulated runoff. The biphasic rain garden was designed to increase retention time and removal efficiency of runoff pollutants by creating a sequence of water saturated to unsaturated conditions. We also evaluated the effect of C substrate availability on pollutant removal efficiency in the biphasic rain garden. Five simulated runoff events with various concentrations of runoff pollutants (i.e. nitrate, phosphate, and atrazine) were applied to the monophasic and biphasic rain gardens once every 5d. Hydraulic performance was consistent over the five simulated runoff events. Peak flow was reduced by approximately 56% for the monophasic design and 80% for the biphasic design. Both rain garden systems showed excellent removal efficiency of phosphate (89-100%) and atrazine (84-100%). However, significantly (p<0.001) higher removal of nitrate was observed in the biphasic (42-63%) compared to the monophasic rain garden (29-39%). Addition of C substrate in the form of glucose increased removal efficiency of nitrate significantly (p<0.001), achieving up to 87% removal at a treatment C/N ratio of 2.0. This study demonstrates the importance of retention time, environmental conditions (i.e. saturated/unsaturated conditions), and availability of C substrate for bioremediation of pollutants, especially nitrates, in rain gardens.


    Energy Technology Data Exchange (ETDEWEB)

    Lee, S.; King, W.


    Models have been developed to simulate the thermal characteristics of Crystalline Silicotitanate (CST) ion exchange media fully loaded with radioactive cesium in a column configuration and distributed within a waste storage tank. This work was conducted to support the Small Column Ion Exchange (SCIX) program which is focused on processing dissolved, high-sodium salt waste for the removal of specific radionuclides (including Cs-137, Sr-90, and actinides) within a High Level Waste (HLW) storage tank at the Savannah River Site. The SCIX design includes CST columns inserted and supported in the tank top risers for cesium removal. Temperature distributions and maximum temperatures across the column were calculated with a focus on process upset conditions. A two-dimensional computational modeling approach for the in-column ion-exchange domain was taken to include conservative, bounding estimates for key parameters such that the results would provide the maximum centerline temperatures achievable under the design configurations using a feed composition known to promote high cesium loading on CST. The current full-scale design for the CST column includes one central cooling pipe and four outer cooling tubes. Most calculations assumed that the fluid within the column was stagnant (i.e. no buoyancy-induced flow) for a conservative estimate. A primary objective of these calculations was to estimate temperature distributions across packed CST beds immersed in waste supernate or filled with dry air under various accident scenarios. Accident scenarios evaluated included loss of salt solution flow through the bed, inadvertent column drainage, and loss of active cooling in the column. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature.

  3. Intermittent Filtration of Bacteria and Colloids at Pore and Column Scales (United States)

    Auset, M.; Keller, A. A.; Brissaud, F.; Lazarova, V.


    Intermittent sand filters used for water and wastewater treatment can achieve high disinfection performance if properly designed and operated. Soil filtration can also play a significant role in pathogen removal. In order to help predict removal of pathogenic bacteria in sand filters and natural porous media, the effects of cyclic infiltration and draining events (transient unsaturated flow) on microorganism fate were investigated. We visualized bacterial transport in unsaturated porous media at the pore scale using micromodels. Column experiments provided quantitative measurements of the phenomena observed at the pore scale. Escherichia coli and a conservative tracer (NaI) were applied once in a pulse to a 1.5 m sand column. Outflow concentrations during subsequent tracer-free pulses were monitored for 4 days. The reproducibility of the breakthrough curve was established in five repeated experiments. We observed earlier breakthrough of bacteria compared to the dissolved tracer, as predicted from pore scale studies. Transport of bacteria and tracer was influenced by the temporal variations in pore water velocity and moisture content. Advancement of the wetting front remobilized bacteria either attached to the air-water interface (AWI) or entrapped in stagnant pore water between gas bubbles. Remobilization leads to successive concentration peaks of bacteria and tracer in the effluent. Overall microbial retention rate was high, 99.972 %. Observations at the pore-scale showed that bacteria retention was due to reversible bacteria entrapment in stagnant regions and sorption onto the AWI and essentially irreversible attachment onto solid-water interface (SWI). Bacterial detachment from the AWI was only observed during complete gas bubble dissolution or if bubble interface stress occurred during the dissolution process.

  4. Impact on Model Uncertainty of Diabatization in Distillation Columns

    DEFF Research Database (Denmark)

    Bisgaard, Thomas; Huusom, Jakob Kjøbsted; Abildskov, Jens


    This work provides uncertainty and sensitivity analysis of design of conventional and heat integrated distillation columns using Monte Carlo simulations. Selected uncertain parameters are relative volatility, heat of vaporization, the overall heat transfer coefficient , tray hold-up, and adiabat ...

  5. Ion chromatographic separation of inorganic ions using a combination of hydrophilic interaction chromatographic column and cation-exchange resin column

    Institute of Scientific and Technical Information of China (English)

    Kaori ARAI; Masanobu MORI; Takahiro HIRONAGA; Hideyuki ITABASHI; Kazuhiko TANAKA


    A combination of hydrophilic interaction chromatographic ( HILIC ) column and a weakly acidic cation-exchange resin (WCX) column was used for simultaneous separation of inorganic anions and cations by ion chromatography ( IC ).Firstly,the capability of HILIC column for the separation of analyte ions was evaluated under acidic eluent conditions.The columns used were SeQuant ZIC-HILIC (ZIC-HILIC) with a sulfobetainezwitterion stationary phase (ZIC-HILIC) and Acclaim HILIC-10 with a diol stationary phase (HILIC-10).When using tartaric acid as the eluent,the HILIC columns indicated strong retentions for anions,based on ion-pair interaction.Especially,HILIC-10 could strongly retain anions compared with ZIC-HILIC. The selectivity for analyte anions of HILIC-10 with 5 mmol/L tartaric acid eluent was in the order of I- > NO3- > Br- > Cl- >H2PO4-.However,since HILIC-10 could not separate analyte cations,a WCX column (TSKgel Super IC-A/C) was connected after the HILIC column in series.The combination column system of HILIC and WCX columns could successfully separate ten ions (Na+,NH4+,K+,Mg2+,Ca2+,H2PO4-,Cl-,Br-,NO3- and I-) with elution of 4 mmol/L tartaric acid plus 8 mmol/L 18-crown-6.The relative standard deviations (RSDs) of analyte ions by the system were in the ranges of 0.02% - 0.05% in retention times and 0.18% - 5.3% in peak areas through three-time successive injections.The limits of detection at signal-to-noise ratio of 3 were 0.24 - 0.30 μmol/L for the cations and 0.31 - 1.2 μmol/L for the anions.This system was applied for the simultaneous determination of the cations and the anions in a vegetable juice sample with satisfactory results.

  6. General Reviews of Vocabulary Retention

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yuan


    This paper will try to review two important theories (repletion and retrieval) which are crucial for vocabulary retention. These two methods are well connected and each of them cannot lead to successful vocabulary retention without sensible utilization of the other.

  7. phosphorus retention data and metadata (United States)

    U.S. Environmental Protection Agency — phosphorus retention in wetlands data and metadata. This dataset is associated with the following publication: Lane , C., and B. Autrey. Phosphorus retention of...

  8. Comprehensive analysis of fatty alcohol ethoxylates by ultra high pressure hydrophilic interaction chromatography coupled with ion mobility spectrometry mass spectrometry using a custom-designed sub-2 μm column. (United States)

    Ma, Qiang; Ma, Wei; Chen, Xi; Wang, Ziming; Bai, Hua; Zhang, Lanwei; Li, Wentao; Wang, Chao; Li, Xinshi


    Comprehensive analysis of fatty alcohol ethoxylates has been conducted by coupling ultra high pressure hydrophilic interaction chromatography and ion mobility spectrometry mass spectrometry. A custom-designed sub-2 μm column was used for the chromatographic separation of fatty alcohol ethoxylates by hydrophilic interaction chromatography. Ion mobility spectrometry provided a post-ionization resolution during a very short period of 6.4 ms. Distinguishable families of singly, doubly, and triply charged fatty alcohol ethoxylates were clearly observed. By virtue of the combination of hydrophilic interaction chromatography and ion mobility spectrometry, comprehensive resolution based on both hydrophobicity difference and mobility disparity has been achieved for fatty alcohol ethoxylates. The orthogonality of the developed separation and analysis system was evaluated with the correlation coefficient and peak spreading angle of 0.0224 and 88.72°, respectively. The actual peak capacity obtained was individually 40 and 193 times than those when hydrophilic interaction chromatography and ion mobility spectrometry were used alone. The collision cross-sections of fatty alcohol ethoxylates were calculated by calibrating the traveling wave ion mobility device with polyalanine.

  9. 基于PLC和WinCC的化工精馏塔控制系统设计%Control System Design for Chemical Rectification Column Based on PLC and WinCC

    Institute of Scientific and Technical Information of China (English)

    何益; 胡姗姗; 刘增强


    Taking the practice in a chemical factory as an example, a monitor system which employs Siemens S7-300 PLC as the data collection and control unit for the chemical rectification column was designed to collect temperature, pressure and flow data and then has them modified with PID in PLC program. The principal PC exchanges data with each station through the WinCC to achieve a centralized control.%化工精馏塔控制系统以SIEMENS公司的S7-300 PLC作为数据采集及控制单元,配合各种检测和控制设备时温度、压力、流量等检测量进行数据采集,在PLC程序中用PID对检测量进行调整.上位机通过西门子的上位监控软件WinCC和PLC进行数据交换,从而实现集中控制.

  10. Retention of the posterior cruciate ligament versus the posterior stabilized design in total knee arthroplasty: a prospective randomized controlled clinical trial

    Directory of Open Access Journals (Sweden)

    van den Akker-Scheek Inge


    Full Text Available Abstract Background Prosthetic design for the use in primary total knee arthroplasty has evolved into designs that preserve the posterior cruciate ligament (PCL and those in which the ligament is routinely sacrificed (posterior stabilized. In patients with a functional PCL the decision which design is chosen depends largely on the favour and training of the surgeon. The objective of this study is to determine whether the patient's perceived outcome and speed of recovery differs between a posterior cruciate retaining total knee arthroplasty and a posterior stabilized total knee arthroplasty. Methods/Design A randomized controlled trial will be conducted. Patients who are admitted for primary unilateral TKA due to primary osteoarthrosis are included when the following inclusion criteria are met: non-fixed fixed varus or valgus deformity less than 10 degrees, age between 55 and 85 years, body mass index less than 35 kg/m2 and ASA score (American Society of Anaesthesiologists I or II. Patients are randomized in 2 groups. Patients in the posterior cruciate retaining group will receive a prosthesis with a posterior cut-out for the posterior cruciate ligament and relatively flat topography. In patients allocated to the posterior stabilized group, in which the posterior cruciate ligament is excised, the design may substitute for this function by an intercondylar tibial prominence that articulates with the femur in flexion. Measurements will take place preoperatively and 6 weeks, 3 months, 6 months and 1 year postoperatively. At all measurement points patient's perceived outcome will be assessed using the Western Ontario and McMaster Universities Osteoarthritis Index (WOMAC. Secondary outcome measures are quality of life (SF-36 and physician reported functional status and range of motion as determined with the Knee Society Clinical Rating System (KSS. Discussion In the current practice both posterior cruciate retaining and posterior stabilized designs

  11. 在脂肪酸-水流动相中小分子在反相高效液相色谱中的保留表征%The Characterization of Retention Behaviours of Small Molecules on Reversed-phase Liquid Chromatographic Column in Mobile Phase of n-Fatty Acid-Water System

    Institute of Scientific and Technical Information of China (English)

    张养军; 张维平; 高娟; 耿信笃


    The retention behaviours of n-aliphatic alcohols with mobilephase of n-aliphatic acids-water in reversed-phase liquid chromatography (RPLC) were studied with stoichiometric displacement model for retention (SDM-R) and Snyder′s empirical equation. The results obtained showed that SDM-R was superior to Snyder′s empirical equation when they were employed to characterize the retention behaviours of homologue and the solvent strength of homologous displacers. The slope, 1/q, of the plot of logK0w versus S has no clear physical meaning and can not be measured accurately, while the slope, j (a constant relating to the affinity of 1 mole solvent to bonded stationary phase ), of the plot of logI (a constant relating to the affinity of 1 mole of solute to bonded stationary phase) versus Z (the number of solvent molecules released from the contact surface region of 1 mole of solvated solute absorbed onto solvated bonded stationary phase) is not only determined accurately but also has a clear physical meaning and follows the rule of carbon number. Therefore, if it is possible, j can be used to characterize the solvent strength employed in RPLC. The conclusion is that with a given displacer, the retention of homologue in RPLC increases with their Z and logI increasing. If a solute is given, with the increment in carbon chain of homologous displacers, the values of Z and logI of the solute decrease and thus lead to the decrease of the solute retention, and the elution strength of a solvent becomes strong as the j value of a homologous displacer becomes small.%在反相液相色谱(RPLC)中用Snyder经验方程和计量置换保留模型(SDM-R)中的参数对溶质为脂肪醇同系物,流动相为脂肪酸同系物时溶质的保留行为进行了研究,结果表明用SDM-R参数具有明显的优越性。另外,由于用Snyder经验公式中二参数之间的作图无法准确求得斜率,且其不具有明确的物理意义,而由SDM-R二参数作图,

  12. The breakthrough curve combination for xenon sampling dynamics in a carbon molecular sieve column. (United States)

    Shu-jiang, Liu; Zhan-ying, Chen; Yin-zhong, Chang; Shi-lian, Wang; Qi, Li; Yuan-qing, Fan; Huai-mao, Jia; Xin-jun, Zhang; Yun-gang, Zhao


    In the research of xenon sampling and xenon measurements, the xenon breakthrough curve plays a significant role in the xenon concentrating dynamics. In order to improve the theoretical comprehension of the xenon concentrating procedure from the atmosphere, the method of the breakthrough curve combination for sampling techniques should be developed and investigated under pulse injection conditions. In this paper, we describe a xenon breakthrough curve in a carbon molecular sieve column, the combination curve method for five conditions is shown and debated in detail; the fitting curves and the prediction equations are derived in theory and verified by the designed experiments. As a consequence, the curves of the derived equations are in good agreement with the fitting curves by tested. The retention times of the xenon in the column are 61.2, 42.2 and 23.5 at the flow rate of 1200, 1600 and 2000 mL min(-1), respectively, but the breakthrough times are 51.4, 38.6 and 35.1 min.

  13. Derringer desirability and kinetic plot LC-column comparison approach for MS-compatible lipopeptide analysis

    Directory of Open Access Journals (Sweden)

    Matthias D’Hondt


    In total, the performance of four different C18 columns, including one UPLC column, were evaluated using two parallel approaches. First, a Derringer desirability function was used, whereby six single and multiple chromatographic response values were rescaled into one overall D-value per column. Using this approach, the YMC Pack Pro C18 column was ranked as the best column for general MS-compatible lipopeptide separation. Secondly, the kinetic plot approach was used to compare the different columns at different flow rate ranges. As the optimal kinetic column performance is obtained at its maximal pressure, the length elongation factor λ (Pmax/Pexp was used to transform the obtained experimental data (retention times and peak capacities and construct kinetic performance limit (KPL curves, allowing a direct visual and unbiased comparison of the selected columns, whereby the YMC Triart C18 UPLC and ACE C18 columns performed as best. Finally, differences in column performance and the (disadvantages of both approaches are discussed.

  14. Surface modification of polytetrafluoroethylene column for two-stationary phase separations by counter-current chromatography. (United States)

    Quan, Kai-jun; Huang, Xin-yi; Li, Xiao-ting; Wang, Gao-hong; Liu, Yan-juan; Duan, Wen-da; Di, Duo-long


    To improve the separation capability of CCC, a novel solid-liquid two-stationary phases CCC (ASP-CCC) column was prepared employing graphene oxide (GO) conjugated poly-dopamine (PD) coating (GO/PD) as auxiliary stationary phase (ASP). The results of Scanning electron microscopy (SEM), contact angle and X-ray photoelectron spectroscopy (XPS) indicated that nanostructured GO and PD were successfully grafted on the inner wall of the PTFE column. Three alkaloid compounds were selected as the target analytes to evaluate the performance of the novel column. Because of the intermolecular force (hydrogen bond, electrostatic interaction and π-π interaction) between the ASP and model compounds, three analytes were well separated with this novel ASP-CCC column. Additionally, the novel column exhibited higher stationary phase retention ratio, about 8%, than original column without changing the chromatographic condition. Furthermore, the eluotropic sequence of analytes on novel column was in accordance with that in the original column. This suggested that the novel column is a CCC column with auxiliary stationary phase (ASP) in its own right, and the present separation mode is the combination of partition chromatography and adsorption chromatography.

  15. Mitigation of Liquefaction in Sandy Soils Using Stone Columns (United States)

    Selcuk, Levent; Kayabalı, Kamil


    Soil liquefaction is one of the leading causes of earthquake-induced damage to structures. Soil improvement methods provide effective solutions to reduce the risk of soil liquefaction. Thus, soil ground treatments are applied using various techniques. However, except for a few ground treatment methods, they generally require a high cost and a lot of time. Especially in order to prevent the risk of soil liquefaction, stone columns conctructed by vibro-systems (vibro-compaction, vibro-replacement) are one of the traditional geotechnical methods. The construction of stone columns not only enhances the ability of clean sand to drain excess pore water during an earthquake, but also increases the relative density of the soil. Thus, this application prevents the development of the excess pore water pressure in sand during earthquakes and keeps the pore pressure ratio below a certain value. This paper presents the stone column methods used against soil liquefaction in detail. At this stage, (a) the performances of the stone columns were investigated in different spacing and diameters of columns during past earthquakes, (b) recent studies about design and field applications of stone columns were presented, and (c) a new design method considering the relative density of soil and the capacity of drenage of columns were explained in sandy soil. Furthermore, with this new method, earthquake performances of the stone columns constructed at different areas were investigated before the 1989 Loma Prieta and the 1994 Northbridge earthquakes, as case histories of field applications, and design charts were compiled for suitable spacing and diameters of stone columns with consideration to the different sandy soil parameters and earhquake conditions. Key Words: Soil improvement, stone column, excess pore water pressure

  16. Evaluation of superficially porous and fully porous columns for analysis of drugs in plasma samples by UHPLC-MS/MS. (United States)

    Acquaro, Vinicius Ricardo; Lanças, Fernando Mauro; Queiroz, Maria Eugênia Costa


    This work compares the performance of recently introduced C18 superficially porous columns (four columns) and C18 fully porous columns (two columns), with different particle sizes, during the analysis of drugs in plasma samples by MS/MS detection. The following chromatographic parameters were evaluated for all the columns: reduced plate height (h) vs reduced linear velocity (v), impedance vs v, chromatographic run time vs flow rate (mLmin(-1)), backpressure vs flow rate (mLmin(-1)), resolution, peak capacity, asymmetry, and retention factor. By using DAD detection, hydrophobicity, silanol activity, and metal impurities were also assessed for the columns. The columns with charged surface displayed improved chromatographic efficiency for the drugs in their ionized form. The columns with particles smaller than 2μm (Cortecs 1.6μm, Acquity 1.7μm, and Kinetex 1.7μm) presented higher chromatographic efficiency for the drugs, which were in their partially ionized form. The generated mathematical models were able to predict the backpressure and chromatographic run time at different flow rates for all the columns. Considering the efficiency, impedance, resolution, peak capacity, retention factor, and hydrophobicity, Cortecs 1.6μm and Acquity 1.7μm were the columns that given the best performance during analysis of the target drugs in plasma samples.

  17. Reducing axial mixing in flotation columns

    Energy Technology Data Exchange (ETDEWEB)

    Al Taweel, A.M.; Ramadan, A.M. [Technical Univ. of Nova Scotia, Halifax (Canada). Chemical Engineering Dept.; Moharam, M.R.; Hassan, T.A. [Al Azhar Univ., Cairo (Egypt); El Mofty, S.M. [Cairo Univ., Giza (Egypt)


    The axial mixing characteristics of a pilot-scale flotation column were investigated with the objective of identifying means to mitigate the extent of axial mixing that adversely affects its grade/recovery performance. A wide range of design and operating conditions wa investigated and the experimental results, obtained using the dynamic response method, were analyzed using three axial mixing models. The dynamic response of the column can best be described using the axial dispersion model. The results obtained suggest that the value of the axial dispersion coefficient, E{sub L}, can be significantly reduced by judicial selection of hydrodynamic conditions and/or the use of column inserts that suppress the onset of hydrodynamic instabilities inherent to the operation of conventional flotation columns. Up to 40% reduction in the value of E{sub L} was thus obtained by using spargers that produce more uniform bubble sizes, while up to 30% reductions were obtained by controlling the residual frother concentration. 33 refs., 7 figs.

  18. Mush Column Magma Chambers (United States)

    Marsh, B. D.


    Magma chambers are a necessary concept in understanding the chemical and physical evolution of magma. The concept may well be similar to a transfer function in circuit or time series analysis. It does what needs to be done to transform source magma into eruptible magma. In gravity and geodetic interpretations the causative body is (usually of necessity) geometrically simple and of limited vertical extent; it is clearly difficult to `see' through the uppermost manifestation of the concentrated magma. The presence of plutons in the upper crust has reinforced the view that magma chambers are large pots of magma, but as in the physical representation of a transfer function, actual magma chambers are clearly distinct from virtual magma chambers. Two key features to understanding magmatic systems are that they are vertically integrated over large distances (e.g., 30-100 km), and that all local magmatic processes are controlled by solidification fronts. Heat transfer considerations show that any viable volcanic system must be supported by a vertically extensive plumbing system. Field and geophysical studies point to a common theme of an interconnected stack of sill-like structures extending to great depth. This is a magmatic Mush Column. The large-scale (10s of km) structure resembles the vertical structure inferred at large volcanic centers like Hawaii (e.g., Ryan et al.), and the fine scale (10s to 100s of m) structure is exemplified by ophiolites and deeply eroded sill complexes like the Ferrar dolerites of the McMurdo Dry Valleys, Antarctica. The local length scales of the sill reservoirs and interconnecting conduits produce a rich spectrum of crystallization environments with distinct solidification time scales. Extensive horizontal and vertical mushy walls provide conditions conducive to specific processes of differentiation from solidification front instability to sidewall porous flow and wall rock slumping. The size, strength, and time series of eruptive behavior

  19. A comprehensive study to protein retention in hydrophobic interaction chromatography. (United States)

    Baca, Martyna; De Vos, Jelle; Bruylants, Gilles; Bartik, Kristin; Liu, Xiaodong; Cook, Ken; Eeltink, Sebastiaan


    The effect of different kosmotropic/chaotropic salt systems on retention characteristics of intact proteins has been examined in hydrophobic interaction chromatography (HIC). The performance was assessed using different column chemistries, i.e., polyalkylamide, alkylamine incorporating hydrophobic moieties, and a butyl chemistry. Selectivity in HIC is mainly governed by the salt concentration and by the molal surface tension increment of the salt. Typically, a linear relationship between the natural logarithm of the retention factor and the salt concentration is obtained. Using a 250mm long column packed with 5μm polyalkylamide functionalized silica particles and applying a 30min linear salt gradient, a peak capacity of 78 was achieved, allowing the baseline separation of seven intact proteins. The hydrophobicity index appeared to be a good indicator to predict the elution order of intact proteins in HIC mode. Furthermore, the effect of adding additives in the mobile phase, such as calcium chloride (stabilizing the 3D conformation of α-lactalbumin) and isopropanol, on retention properties has been assessed. Results indicate that HIC retention is also governed by conformational in the proteins which affect the number of accessible hydrophobic moieties.

  20. Fire response of composite columns subject to sway

    DEFF Research Database (Denmark)

    Virdi, Kuldeep

    conditions is adequately covered in the relevant standard, Eurocode 4, simplified design of unbraced composite columns for the fire limit state has not been included. Recognising this, a collaborative research project was undertaken with funding from the Research Fund for Coal and Steel. The paper describes......Composite columns, using profiled steel sections encased in concrete or steel tubes filled with concrete, are increasingly used in practice taking advantage of speed of erection as well as offering cost-effective solutions. While the design of braced and unbraced composite columns under ambient...... the scope of the project which covered control tests under ambient conditions, carried out by the author while at City University London. Other aspects covered in the project included fire tests carried out by CTICM in France, on isolated columns and on two frames designed by Leibniz Universität Hannover...

  1. Optimization based on retention prediction and information theory for liquid-chromatographic analysis of alkylbenzenes

    Energy Technology Data Exchange (ETDEWEB)

    Matsuda, Rieko; Hayashi Yuzuru; Suzuki Takashi; Saito Yukio (National Inst. of Hygienic Sciences, Tokyo (Japan)); Jinno Kiyokatsu (Toyohashi Univ. of Technology (Japan))


    The mobile phase composition and column length are optimized for analyses of six alkylbenzenes in reversed-phase liquid chromatography with the aid of retention prediction and information theory. Optimal conditions selected according to the resolution Rs and information theory are evaluated from the viewpoint of the precision and analytical efficiency (rapidity) of chromatography. The combination of the information-theoretical optimization with the retention prediction will accelerate the development in the automation of liquid-chromatographic analysis.

  2. Natural Water Retention Measures (NWRM): from Design to Implementation through European Projects; Las Medidas Naturales de Retencion de Agua: del diseno a la implementacion a traves de proyectos europeos

    Energy Technology Data Exchange (ETDEWEB)

    Magdaleno Mas, F.; Dalacamara Andres, G.


    The Centre for Applied Technique Studies (CETA) of CEDEX has been working over the last few years in different European projects related with the design and development of natural water retention measures (NWRM). These are a number of measures, boosted by the Water Unit of the Environment Directorate-General of the European Commission. with close links to green infrastructures, which try to integrate, from a multifunctional approach, different legal and technical requirements aimed at a better adaptation to extreme hydro meteorological events, environmental protection and conservation, and maintenance of ecosystem services. This paper reviews the underpinning foundations of the concept and the mechanisms for designing and implementing NWRM. It also shows the way they can be applied, by presenting different initiatives developed by CETA since 2008 in Navarra (Arga-Aragon rivers system). For fulfilling those works, CETA has collaborated with environmental and hydraulic authorities of Navarra. It has also actively cooperated with research centres, such as the Institute IMDEA Water. specifically in a European project devoted to the diffusion, assessment, and presentation of NWRM within the context of the EU River Basin Districts. (Author)

  3. 40 CFR 265.74 - Availability, retention, and disposition of records. (United States)


    ... officer, employee, or representative of EPA who is duly designated by the Administrator. (b) The retention... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Availability, retention, and... Availability, retention, and disposition of records. (a) All records, including plans, required under this part...

  4. Breastfeeding reduces postpartum weight retention

    DEFF Research Database (Denmark)

    Baker, Jennifer Lyn; Gamborg, Michael; Heitmann, Berit L


    BACKGROUND: Weight gained during pregnancy and not lost postpartum may contribute to obesity in women of childbearing age. OBJECTIVE: We aimed to determine whether breastfeeding reduces postpartum weight retention (PPWR) in a population among which full breastfeeding is common and breastfeeding...... duration is long. DESIGN: We selected women from the Danish National Birth Cohort who ever breastfed (>98%), and we conducted the interviews at 6 (n = 36 030) and 18 (n = 26 846) mo postpartum. We used regression analyses to investigate whether breastfeeding (scored to account for duration and intensity......) reduced PPWR at 6 and 18 mo after adjustment for maternal prepregnancy body mass index (BMI) and gestational weight gain (GWG). RESULTS: GWG was positively (P Breastfeeding was negatively associated with PPWR in all women but those...

  5. A review on process intensification in internally heat-integrated distillation columns

    NARCIS (Netherlands)

    Kiss, Anton Alexandru; Olujic, Zarko


    Internally heat-integrated distillation column (HIDiC) is the most radical approach of a heat pump design, making efficient use of internal heat-integration: the rectifying section of a distillation column operating at a higher pressure becomes the heat source, while the stripping part of the column

  6. A review on process intensification in internally heat-integrated distillation columns

    NARCIS (Netherlands)

    Kiss, Anton A.; Olujic, Zarko


    Internally heat-integrated distillation column (HIDiC) is the most radical approach of a heat pump design, making efficient use of internal heat-integration: the rectifying section of a distillation column operating at a higher pressure becomes the heat source, while the stripping part of the column

  7. QSRR Modeling for Metabolite Standards Analyzed by Two Different Chromatographic Columns Using Multiple Linear Regression

    Directory of Open Access Journals (Sweden)

    Chrysostomi Zisi


    Full Text Available Modified quantitative structure retention relationships (QSRRs are proposed and applied to describe two retention data sets: A set of 94 metabolites studied by a hydrophilic interaction chromatography system under organic content gradient conditions and a set of tryptophan and its major metabolites analyzed by a reversed-phase chromatographic system under isocratic as well as pH and/or simultaneous pH and organic content gradient conditions. According to the proposed modification, an additional descriptor is added to a conventional QSRR expression, which is the analyte retention time, tR(R, measured under the same elution conditions, but in a second chromatographic column considered as a reference one. The 94 metabolites were studied on an Amide column using a Bare Silica column as a reference. For the second dataset, a Kinetex EVO C18 and a Gemini-NX column were used, where each of them was served as a reference column of the other. We found in all cases a significant improvement of the performance of the QSRR models when the descriptor tR(R was considered.

  8. Evaluation of a silicon oxynitride hydrophilic interaction liquid chromatography column in saccharide and glycoside separations. (United States)

    Wan, Huihui; Sheng, Qianying; Zhong, Hongmin; Guo, Xiujie; Fu, Qing; Liu, Yanfang; Xue, Xingya; Liang, Xinmiao


    The retention characteristics of a silicon oxynitride stationary phase for carbohydrate separation were studied in hydrophilic interaction chromatography mode. Four saccharides including mono-, di-, and trisaccharides were employed to investigate the effects of water content and buffer concentration in the mobile phase on hydrophilic interaction liquid chromatography retention. For the tested saccharides, the silicon oxynitride column demonstrated excellent performance in terms of separation efficiency, hydrophilicity, and interesting separation selectivity for carbohydrates compared to the bare silica stationary phase. Finally, the silicon oxynitride hydrophilic interaction liquid chromatography column was employed in the separation of complex samples of fructooligosaccharides, saponins, and steviol glycoside from natural products. The resulting chromatograms demonstrated good separation efficiency and longer retention compared with silica, which further confirmed the advantages and potential application of silicon oxynitride stationary phase for hydrophilic interaction liquid chromatography separation.

  9. 几何非线性新梁柱单元及结构程序设计%A geometric nonlinear new beam-column element and structure program design

    Institute of Scientific and Technical Information of China (English)

    张俊峰; 王利娟; 郝际平; 李天


    基于更新拉格朗日构形的增量虚位移原理,在其势能项中引入了全部6个应力分量,采用可计人单元剪切变形影响的三次多项式插值函数,详细推导了考虑剪切变形及翘曲的空间梁一柱单元几何非线性切线刚度矩阵.根据面向对象的程序设计思想,将整个有限元域划分为8个基本类,在单元基类的基础上派生了新的单元类,采用C++语言编制了面向对象的空间钢结构分析程序.几何非线性算例分析结果表明,本文提出的理论分析方法和计算程序是正确的和高效的.%According to the increment virtual displacement principle based on the updated Lagrange configuration,the potential energy associated with all six stress components was taken into account. The cubic interpolation function which can be used to consider the shear deformation effects has been applied to derive the geometrical nonlinear stiffness matrix of the space beam-column element considering the shear deformation and warping effects. Based on the object-oriented design conception, the finite element analysis domain is divided into eight classes. A new class is derived from the base element class. Using C+ + language,the spatial steel frame advanced analysis program is complied. Numerical examples including both geometric and material nonlinearities are used to demonstrate the accuracy and efficiency of the proposed analytical method and computer program.

  10. A Tentative Exploration on the Strength Design of the Geogrid in Geosynthetic-encased Stone Columns%加筋碎石桩格栅强度设计初探

    Institute of Scientific and Technical Information of China (English)

    唐承铁; 刘猛


    分析了加筋碎石桩复合地基的承载机理,探讨了加筋碎石桩复合地基的2种主要破坏模式,破坏模式1由格栅套筒抗拉强度控制,破坏模式2由非加筋段桩侧土强度控制.采用极限平衡理论分别导出了两种不同的破坏模式下加筋碎石桩单桩极限承载力计算公式.基于2种破坏模式下的承载力计算公式,在加筋深度一定的情况下给出了格栅合理设计强度解析解.最后,运用本文方法对某工程实例进行计算,计算结果与实测数据吻合较好.%The bearing mechanism of geosynthetic-encased stone columns was analyzed and two primary kinds of failure modes was investigated. Failure mode 1 is mainly controlled by the strength of geogrid sleeve, and failure mode 2 is controlled by the strength of the soil along the no-reinforced section. Based on the two failure modes, the method of the limit equilibrium is employed to deduce the formulas of the ultimate bearing capacity by which, the expression of the optimal design strength of the geogrid is presented in this paper. At last, when the method was used to analyze the practical project, its feasibility was proved by the reasonable agreement between the calculated and the measured values.

  11. Plant practices in fine coal column flotation

    Energy Technology Data Exchange (ETDEWEB)

    Davis, V.L. Jr.; Bethell, P.J.; Stanley, F.L. [Pittston Coal Management Co., Lebanon, VA (United States); Luttrell, G.H. [Virginia Polytechnic Institute and State Univ., Blacksburg, VA (United States). Dept. of Mining and Minerals Engineering


    Five 3 m (10 ft) diameter Microcel{trademark} flotation columns were installed at Clinchfield Coal Company`s Middle Fork preparation facility in order to reduce product ash and increase recovery and plant capacity. The Middle Fork facility is utilized for the recovery of fine coal from a feed stream that consists primarily of 1.5 mm x 0 material. The columns replaced conventional flotation cells for the treatment of the minus 150 {micro}m fraction while spirals are used to upgrade the plus 150 {micro}m material in the plant feed. The addition of the column flotation circuit resulted in an increase in plant capacity in excess of 20 percent while reducing the flotation product ash content by approximately 7 percentage points. Flotation circuit combustible recovery wa increased by 17 percentage points. This paper discusses circuit design, commissioning, and sparging system design. Circuit instrumentation, level control, reagent system control, performance comparisons with conventional flotation, and general operating procedures are also discussed.

  12. Evaluation of column hardware on liquid chromatography-mass spectrometry of phosphorylated compounds. (United States)

    Sakamaki, Hiroshi; Uchida, Takeharu; Lim, Lee Wah; Takeuchi, Toyohide


    The influences of column hardware, such as chromatographic tubes and frits, on liquid chromatography-mass spectrometry (LC-MS) analysis of phosphorylated compounds were evaluated. The signal to noise ratio (S/N) and the intensity of flavin adenine dinucleotide (FAD) using a glass lined tube and polyethylene frit (GL-PE) column was approximately 170 and 90 times higher, respectively, than those using conventional stainless steel tube and stainless steel frit (S-S) column. In addition, the retention time of FAD using GL-PE column was the shortest compared to other columns. Interaction between phosphorylated compounds and metal ions in the flow path in the S-S column was stronger than that between them and the GL-PE column. Thus, the metal ions in the flow path in GL-PE column were low. Since the specific surface area of a pair of frits was 70 times larger than that of a chromatographic tube (150 mm×2.1 mm), the frits were found to have more effective improvement of the S/N as well as the intensity than the chromatographic tubes, when phosphorylated compounds were analyzed by LC-MS. When the evaluated phosphorylated compounds were analyzed by LC-MS(/MS) using a GL-PE column, the intensity and S/N were increased.

  13. The Dissipative Column: A New Hysteretic Damper

    Directory of Open Access Journals (Sweden)

    Bruno Palazzo


    Full Text Available A new replaceable hysteretic damper to better control seismic building damage, consisting of two or more adjacent steel vertical elements connected to each other with continuous mild/low strength steel shear links, is proposed and investigated in this paper. New Dampers, called Dissipative Columns (DC, continuously linked with X-shaped steel plates, provide additional stiffness and damping to a lateral system by using a basic and minimally invasive construction element: the column. Working in a way similar to coupled shear walls, the proposed element behavior is theoretically analyzed at linear and non-linear ranges. In fact, considering different restrained cases, a parametric analysis is developed in order both to evaluate the effect of the main geometrical and structural parameters and to provide the design capacity curves of this new damper. The DC can be considered a new damping device, easy to install in new as well as existing buildings in order to protect them from seismic damage.

  14. Modeling of Crystalline Silicotitanate Ion Exchange Columns

    Energy Technology Data Exchange (ETDEWEB)

    Walker, D.D.


    Non-elutable ion exchange is being considered as a potential replacement for the In-Tank Precipitation process for removing cesium from Savannah River Site (SRS) radioactive waste. Crystalline silicotitanate (CST) particles are the reference ion exchange medium for the process. A major factor in the construction cost of this process is the size of the ion exchange column required to meet product specifications for decontaminated waste. To validate SRS column sizing calculations, SRS subcontracted two reknowned experts in this field to perform similar calculations: Professor R. G. Anthony, Department of Chemical Engineering, Texas A&038;M University, and Professor S. W. Wang, Department of Chemical Engineering, Purdue University. The appendices of this document contain reports from the two subcontractors. Definition of the design problem came through several meetings and conference calls between the participants and SRS personnel over the past few months. This document summarizes the problem definition and results from the two reports.

  15. Water Column Sonar Data Collection (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The collection and analysis of water column sonar data is a relatively new avenue of research into the marine environment. Primary uses include assessing biological...

  16. 滚珠丝杠副精度保持性加载装置的设计与对比∗%Design and Comparison of Loading Device for Accuracy Retention of Ball Screw

    Institute of Scientific and Technical Information of China (English)

    丁聪; 冯虎田; 欧屹


    On the base of analyzing the influence factors of accuracy retention of ball screw,the biaxial load-ing and external loading testing program were proposed and both of the three—dimensional models of the test bed were designed by aiming at key influence factors and simplifying programs design. The two loading de-sign principle and components were introduced by making a comparison. The result indicated that the biaxial loading is novel, the efficiency is high, but it has the hidden danger which under the big load condition car-ries;and the external loading is traditional, the efficiency is low, but the loading strength is big and stable, expanding the test sample.%在分析了滚珠丝杠副精度保持性影响因素的基础上,针对关键影响因素,从简化方案设计的角度出发,提出了双向加载方案和外力加载方案并进行了试验台的三维设计。对两种加载设计分别进行了原理阐述和组件介绍,并对两种加载方式做了对比。结果表明双向加载方式新颖,试验效率高,但存在大载荷条件下偏载的隐患;外力加载方式传统,试验效率低,但提供的加载力大且稳定,可扩大试验样本。

  17. Hydrophilic interaction liquid chromatography in analysis of granisetron HCl and its related substances. Retention mechanisms and method development. (United States)

    Maksić, Jelena; Tumpa, Anja; Stajić, Ana; Jovanović, Marko; Rakić, Tijana; Jančić-Stojanović, Biljana


    In this paper separation of granisetron and its two related substances in HILIC mode is presented. Separation was done on silica column derivatized with sulfoalkylbetaine groups (ZIC-HILIC). Firstly, retention mechanisms were assessed whereby retention factors of substances were followed in wide range of acetonitrile content (80-97%), at constant concentration of aqueous buffer (10mM) as well as at constant pH value of 3.0. Further, in order to developed optimal HILIC method, Design of Experiments (DoE) methodology was applied. For optimization full factorial design 3(2) was employed. Influence of acetonitrile content and ammonium acetate concentration were investigated while pH of the water phase was kept at 3.3. Adequacy of obtained mathematical models was confirmed by ANOVA. Optimization goals (α>1.15 and minimal run time) were accomplished with 94.7% of acetonitrile in mobile phase and 70 mM of ammonium acetate in water phase. Optimal point was in the middle of defined Design Space. In the next phase, robustness was experimetally tested by Rechtschaffen design. The investigated factors and their levels were: acetonitrile content (±1%), ammonium acetate molarity in water phase (±2 mM), pH value of water phase (±0.2) and column temperature (±4 °C). The validation scope included selectivity, linearity, accuracy and precision as well as determination of limit of detection (LOD) and limit of quantification (LOQ) for the related substances. Additionally, the validation acceptance criteria were met in all cases. Finally, the proposed method could be successfully utilized for estimation of granisetron HCl and its related substances in tablets and parenteral dosage forms, as well as for monitoring degradation under various stress conditions.


    Energy Technology Data Exchange (ETDEWEB)

    Lee, S.


    The objective of the present work is to model the resin particles within the column during fluidization and sedimentation processes using computation fluid dynamics (CFD) approach. The calculated results will help interpret experimental results, and they will assist in providing guidance on specific details of testing design and establishing a basic understanding of particle’s hydraulic characteristics within the column. The model is benchmarked against the literature data and the test data (2003) conducted at Savannah River Site (SRS). The paper presents the benchmarking results and the modeling predictions of the SRS resin column using the improved literature correlations applicable for liquid-solid granular flow.

  19. Stone Columns - Determination of the soil improvement factor (United States)

    Pivarč, J.


    A stone column is one of the soil stabilizing methods that is used to increase strength, decrease the compressibility of soft and loose fine graded soils, accelerate a consolidation effect and reduce the liquefaction potential of soils. The columns consist of compacted gravel or crushed stone arranged by a vibrator. This paper deals with Priebe's theory (1976) on the design of an improvement factor, which belongs among the most used analytical methods and also describes the numerical and laboratory models of stone columns. The improvement factors calculated from numerical and laboratory models are compared with the improvement factors resulting from Priebe's theory.

  20. Improved immunoadsorption procedure with anion-exchange bacterial cell columns. (United States)

    McKinney, R M; Thacker, L; Wong, M C; Hebert, G A


    Bacterial cell columns for immunoadsorption were prepared with Streptococcus cells and triethylaminoethyl cellulose (Cellex-T) matrix material as a model system. Good column flow properties and satisfactory retention of the cells were obtained with ratios as high as 2 ml of packed cells/3 g dry weight of cellulose. Anion-exchange fractionation of whole serum by the Cellex-T was prevented by using 0.25 M NaCl in the developing buffer. Antibodies were adsorbed directly from whole serum and recovered in high yield by desorption at pH 2.3. Pre-exposing bacterial cells to formalin and washing them with acetone was necessary to ensure that they remained on the columns. One strain of Streptococcus salivarius (SS 908) was satisfactorily retained on a column only after cells were labeled with fluorescein isothiocyanate and washed with acetone. The means by which Cellex-T retains bacterial cells appears to be a combination of electronic attraction and physical entrapment.

  1. HPLC analysis of synthetic polymers on short monolithic columns. (United States)

    Maksimova, Elena; Vlakh, Evgenia; Sinitsyna, Ekaterina; Tennikova, Tatiana


    Ultrashort monolithic columns (disks) were thoroughly studied as efficient stationary phases for precipitation-dissolution chromatography of synthetic polymers. Gradient elution mode was applied in all chromatographic runs. The mixtures of different flexible chain homopolymers, such as polystyrenes, poly(methyl methacrylates), and poly(tert-butylmethacrylates) were separated according to their molecular weights on both commercial poly(styrene-co-divinylbenzene) disks (12 id × 3 mm and 5 × 5 mm) and lab-made monolithic columns (4.6 id × 50 mm) filled with supports of different hydrophobicity. The experimental conditions were optimized to reach fast and highly efficient separation. It was observed that, similar to the separation of monoliths of other classes of (macro)molecules (proteins, DNA, oligonucleotides), the length of column did not affect the peak resolution. A comparison of the retention properties of the poly(styrene-co-divinylbenzene) disk-shaped monoliths with those based on poly(lauryl methacrylate-co-ethylene dimethacrylate), poly(butyl methacrylate-co-ethylene dimethacrylate), and poly(glycidyl methacrylate-co-ethylene dimethacrylate) supports demonstrated the obvious effect of surface chemistry on the resolution factor. Additionally, the results of the discussed chromatographic mode on the fast determination of the molecular weights of homopolymers used in this study were compared to those established by SEC on columns packed with sorbent beads of a similar nature to the monoliths. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Associations between the Cervical Vertebral Column and Craniofacial Morphology


    Sonnesen, L.


    Aim. To summarize recent studies on morphological deviations of the cervical vertebral column and associations with craniofacial morphology and head posture in nonsyndromic patients and in patients with obstructive sleep apnoea (OSA). Design. In these recent studies, visual assessment of the cervical vertebral column and cephalometric analysis of the craniofacial skeleton were performed on profile radiographs of subjects with neutral occlusion, patients with severe skeletal malocclusions a...

  3. Effects of a 6-month multimodal training intervention on retention of functional fitness in older adults: A randomized-controlled cross-over design

    Directory of Open Access Journals (Sweden)

    Gudlaugsson Janus


    Full Text Available Abstract Background Older adults have the highest rates of disability, functional dependence and use of healthcare resources. Training interventions for older individuals are of special interest where regular physical activity (PA has many health benefits. The main purpose of this study was to assess the immediate and long-term effects of a 6-month multimodal training intervention (MTI on functional fitness in old adults. Methods For this study, 117 participants, 71 to 90 years old, were randomized in immediate intervention group and a control group (delayed intervention group. The intervention consisted of daily endurance and twice-a-week strength training. The method was based on a randomized-controlled cross-over design. Short Physical Performance Battery (SPPB, 8 foot up-and-go test, strength performance, six min walking test (6 MW, physical activity, BMI and quality of life were obtained at baseline, after a 6-month intervention- and control phase, again after 6-month crossover- and delayed intervention phase, and after anadditional 6-month follow-up. Results After 6 months of MTI, the intervention group improved in physical performance compared with the control group via Short Physical Performance Battery (SPPB score (mean diff = 0.6, 95 % CI: 0.1, 1.0 and 8-foot up-and-go test (mean diff = −1.0 s, 95 % CI: -1.5, -0.6, and in endurance performance via 6-minute walking test (6 MW (mean diff = 44.2 meters, 95 % CI: 17.1, 71.2. In strength performance via knee extension the intervention group improved while control group declined (mean diff = 55.0 Newton, 95 % CI: 28.4, 81.7, and also in PA (mean diff = 125.9 cpm, 95 % CI: 96.0, 155.8. Long-term effects of MTI on the particpants was assesed by estimating the mean difference in the variables measured between time-point 1 and 4: SPPB (1.1 points, 95 % CI: 0.8, 1.4; 8-foot up-and-go (−0.9 s, 95 % CI: -1.2, -0.6; 6 MW (18.7 m, 95 % CI: 6.5, 31.0; knee extension (4.2 Newton

  4. Radiotracer Imaging of Sediment Columns (United States)

    Moses, W. W.; O'Neil, J. P.; Boutchko, R.; Nico, P. S.; Druhan, J. L.; Vandehey, N. T.


    Nuclear medical PET and SPECT cameras routinely image radioactivity concentration of gamma ray emitting isotopes (PET - 511 keV; SPECT - 75-300 keV). We have used nuclear medical imaging technology to study contaminant transport in sediment columns. Specifically, we use Tc-99m (T1/2 = 6 h, Eγ = 140 keV) and a SPECT camera to image the bacteria mediated reduction of pertechnetate, [Tc(VII)O4]- + Fe(II) → Tc(IV)O2 + Fe(III). A 45 mL bolus of Tc-99m (32 mCi) labeled sodium pertechnetate was infused into a column (35cm x 10cm Ø) containing uranium-contaminated subsurface sediment from the Rifle, CO site. A flow rate of 1.25 ml/min of artificial groundwater was maintained in the column. Using a GE Millennium VG camera, we imaged the column for 12 hours, acquiring 44 frames. As the microbes in the sediment were inactive, we expected most of the iron to be Fe(III). The images were consistent with this hypothesis, and the Tc-99m pertechnetate acted like a conservative tracer. Virtually no binding of the Tc-99m was observed, and while the bolus of activity propagated fairly uniformly through the column, some inhomogeneity attributed to sediment packing was observed. We expect that after augmentation by acetate, the bacteria will metabolically reduce Fe(III) to Fe(II), leading to significant Tc-99m binding. Imaging sediment columns using nuclear medicine techniques has many attractive features. Trace quantities of the radiolabeled compounds are used (micro- to nano- molar) and the half-lives of many of these tracers are short (Image of Tc-99m distribution in a column containing Rifle sediment at four times.

  5. Kinetic performance evaluation and perspectives of contemporary packed column capillary electrochromatography. (United States)

    De Smet, Seppe; Lynen, Frederic


    Capillary electrochromatography (CEC) is in essence a highly efficient and fast separation technique but practical constraints limit the current performance, robustness and routine implementation of the technique. In this work the kinetic performance limit (KPL) curve was used to evaluate commercial packed column CEC; this firstly in order to assess the broader applicability of the kinetic plot approach in electrodriven chromatographic techniques, and secondly to allow a more general unbiased comparison with HPLC performance. Evaluations were performed with a mixture of well retained and electrophoretically neutral phenones, to allow the observation of only chromatographic processes. Initial CEC retention time irreproducibility issues were solved by applying high acetonitrile content (80%) in the mobile phase, and solute retention was increased by increasing the phenone chain length. Comparison was performed with HPLC, with a column packed with an identical stationary phase to allow measurement of the performance under optimal conditions, and not with μ-LC on the CEC column as extra column peak broadening phenomena would thereby negatively affect the μ-LC performance. This comparison demonstrated that current HPLC performance largely outcompetes what is achievable with contemporary packed column CEC. Interestingly, significantly improved CEC performance could be obtained at lower temperatures (10°C) indicating a persistent degree of joule heating phenomena taking place in the contemporary packed column (100μm) CEC approach. Effective suppression of the latter opens possibilities for increasing the applicable voltage and outperforming HPLC and UHPLC.

  6. Prediction of axial limit capacity of stone columns using dimensional analysis (United States)

    Nazaruddin A., T.; Mohamed, Zainab; Mohd Azizul, L.; Hafez M., A.


    Stone column is the most favorable method used by engineers in designing work for stabilization of soft ground for road embankment, and foundation for liquid structure. Easy installation and cheaper cost are among the factors that make stone column more preferable than other method. Furthermore, stone column also can acts as vertical drain to increase the rate of consolidation during preloading stage before construction work started. According to previous studied there are several parameters that influence the capacity of stone column. Among of them are angle friction of among the stones, arrangement of column (two pattern arrangement most applied triangular and square), spacing center to center between columns, shear strength of soil, and physical size of column (diameter and length). Dimensional analysis method (Buckingham-Pi Theorem) has used to carry out the new formula for prediction of load capacity stone columns. Experimental data from two previous studies was used for analysis of study.

  7. Genetic programming based quantitative structure-retention relationships for the prediction of Kovats retention indices. (United States)

    Goel, Purva; Bapat, Sanket; Vyas, Renu; Tambe, Amruta; Tambe, Sanjeev S


    The development of quantitative structure-retention relationships (QSRR) aims at constructing an appropriate linear/nonlinear model for the prediction of the retention behavior (such as Kovats retention index) of a solute on a chromatographic column. Commonly, multi-linear regression and artificial neural networks are used in the QSRR development in the gas chromatography (GC). In this study, an artificial intelligence based data-driven modeling formalism, namely genetic programming (GP), has been introduced for the development of quantitative structure based models predicting Kovats retention indices (KRI). The novelty of the GP formalism is that given an example dataset, it searches and optimizes both the form (structure) and the parameters of an appropriate linear/nonlinear data-fitting model. Thus, it is not necessary to pre-specify the form of the data-fitting model in the GP-based modeling. These models are also less complex, simple to understand, and easy to deploy. The effectiveness of GP in constructing QSRRs has been demonstrated by developing models predicting KRIs of light hydrocarbons (case study-I) and adamantane derivatives (case study-II). In each case study, two-, three- and four-descriptor models have been developed using the KRI data available in the literature. The results of these studies clearly indicate that the GP-based models possess an excellent KRI prediction accuracy and generalization capability. Specifically, the best performing four-descriptor models in both the case studies have yielded high (>0.9) values of the coefficient of determination (R(2)) and low values of root mean squared error (RMSE) and mean absolute percent error (MAPE) for training, test and validation set data. The characteristic feature of this study is that it introduces a practical and an effective GP-based method for developing QSRRs in gas chromatography that can be gainfully utilized for developing other types of data-driven models in chromatography science.


    Energy Technology Data Exchange (ETDEWEB)

    Bernard A. Toseland, Ph.D.


    The major technical objectives of this program are threefold: (1) to develop the design tools and a fundamental understanding of the fluid dynamics of a slurry bubble column reactor to maximize reactor productivity, (2) to develop the mathematical reactor design models and gain an understanding of the hydrodynamic fundamentals under industrially relevant process conditions, and (3) to develop an understanding of the hydrodynamics and their interaction with the chemistries occurring in the bubble column reactor. Successful completion of these objectives will permit more efficient usage of the reactor column and tighter design criteria, increase overall reactor efficiency, and ensure a design that leads to stable reactor behavior when scaling up to large diameter reactors.

  9. Engineering Development of Slurry Bubble Column Reactor (SBCR) Technology

    Energy Technology Data Exchange (ETDEWEB)

    Toseland, B.A.


    The major technical objectives of this program are threefold: (1) to develop the design tools and a fundamental understanding of the fluid dynamics of a slurry bubble column reactor to maximize reactor productivity, (2) to develop the mathematical reactor design models and gain an understanding of the hydrodynamic fundamentals under industrially relevant process conditions, and (3) to develop an understanding of the hydrodynamics and their interaction with the chemistries occurring in the bubble column reactor. Successful completion of these objectives will permit more efficient usage of the reactor column and tighter design criteria, increase overall reactor efficiency, and ensure a design that leads to stable reactor behavior when scaling up to large diameter reactors.


    Energy Technology Data Exchange (ETDEWEB)

    Bernard A. Toseland


    The major technical objectives of this program are threefold: (1) to develop the design tools and a fundamental understanding of the fluid dynamics of a slurry bubble column reactor to maximize reactor productivity, (2) to develop the mathematical reactor design models and gain an understanding of the hydrodynamic fundamentals under industrially relevant process conditions, and (3) to develop an understanding of the hydrodynamics and their interaction with the chemistries occurring in the bubble column reactor. Successful completion of these objectives will permit more efficient usage of the reactor column and tighter design criteria, increase overall reactor efficiency, and ensure a design that leads to stable reactor behavior when scaling up to large diameter reactors.

  11. Rapid tandem-column micro-gas chromatography based on optofluidic ring resonators with multi-point on-column detection. (United States)

    Sun, Yuze; Liu, Jing; Howard, Daniel J; Frye-Mason, Greg; Thompson, Aaron K; Ja, Shiou-jyh; Fan, Xudong


    We demonstrated a novel tandem-column micro-gas chromatography (microGC) based on optofluidic ring resonator (OFRR). The OFRR is a thin-walled fused silica capillary whose interior surface is coated with a polymeric stationary phase. The circular cross section of the OFRR forms the micro-ring resonator and supports whispering gallery modes (WGMs). Via tapered optical fibers in contact with the OFRR, the WGM can be excited externally at any positions along the OFRR capillary, thus enabling multi-point, on-column, real-time detection of vapor molecules flowing through the OFRR. In the present OFRR-based tandem-column-based microGC implementation, a 180 cm long conventional GC column coated with a nonpolar stationary phase was followed by a relatively short OFRR column coated with a polar phase. Two detection positions, one at the inlet of the OFRR and the other a few centimeters downstream, were used to monitor the separation achieved by the first and the second column, respectively. Owing to the multi-point on-column detection that provides complementary retention time information on each chemical compound, co-eluted analytes can be well separated and identified on at least one detection channel and no modulation is needed at the interface of tandem columns. Separation and detection of twelve analytes with various volatilities and polarities within four minutes were demonstrated. In addition, the chromatograms obtained from three different locations along the OFRR column demonstrated the system's capability of on-column monitoring of the separation process for the target analyte in a vapor mixture. Our results will lead to the development of a rapid, simple, and portable microGC system with significantly improved selectivity and chemical identification capabilities.

  12. Drug Retention Times

    Energy Technology Data Exchange (ETDEWEB)

    None, None


    The purpose of this monograph is to provide information on drug retention times in the human body. The information provided is based on plausible illegal drug use activities that might be engaged in by a recreational drug user. Based on anecdotal evidence, most people “party” during extended time away from the work environment. Therefore, the following scenarios were envisioned: (1) a person uses an illicit drug at a party on Saturday night (infrequent user); (2) a person uses a drug one time on Friday night and once again on Saturday night (infrequent user); and (3) a person uses a drug on Friday night, uses a drug twice on Saturday night, and once again on Sunday (frequent user).

  13. Transport, retention, and long-term release behavior of ZnO nanoparticle aggregates in saturated quartz sand: Role of solution pH and biofilm coating (United States)

    The transport, retention, and long-term fate of zinc oxide nanoparticles (ZnO-NPs) were investigated in saturated, bare and biofilm (Pseudomonas putida) coated sand packed columns. Almost complete retention of ZnO-NPs occurred in bare and biofilm coated sand when the influent solution pH was 9 and t...

  14. An air-cooled gradient resistor column for the KFUPM 350 kV ion accelerator

    Energy Technology Data Exchange (ETDEWEB)

    Raashid, M. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia). Energy Res. Lab.; Abdel-Aal, R.E. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia). Energy Res. Lab.; Naqvi, A.A. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia). Energy Res. Lab.; Al-Ohali, M.A. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia). Energy Res. Lab.; Nagadi, M.M. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia). Energy Res. Lab.


    An air-cooled gradient resistor column has been designed and implemented for the KFUPM 350 kV ion accelerator. The air-cooled column overcomes operational limitations on the acceleration voltages obtained with the old water-cooled column and improves on reliability and maintainability. The new column consists of five sections, each having sixteen 8 M{Omega} 15 W resistors connected in a series-parallel combination. Corona shields defining equipotential circular planes have been incorporated to maintain a uniform potential difference across the column sections. In order to protect the gradient column and accelerator tube against arcing, spark gaps are provided on each corona shield. The new column has been tested over the full range of 0-320 kV across the accelerator tube for extended durations without arcing. Both electrical and mechanical aspects of the new design are discussed, measurement techniques used during installation and testing are described, and performance data are given. (orig.).

  15. 5 CFR 9901.356 - Pay retention. (United States)


    ... retention. (b) Pay retention will be based on the employee's rate of base salary in effect immediately... the range of rates of base salary applicable to the employee's position. (c) Pay retention will be... the 104-week retention limit. (d) Under NSPS, pay retention will be granted when an employee's base...

  16. Sensitivity of the transport and retention of stabilized silver nanoparticles to physicochemical factors (United States)

    Saturated sand-packed column experiments were conducted to investigate the influence of physicochemical factors on the transport and retention of surfactant stabilized silver nanoparticles (AgNPs). The normalized concentration in breakthrough curves (BTCs) of AgNPs increased with a decrease in solut...

  17. Retention and remobilization of stabilized silver nanoparticles in an undisturbed loamy sand soil (United States)

    Column experiments were conducted with undisturbed loamy sand soil under unsaturated conditions (around 90% saturation degree) to investigate the retention of surfactant stabilized silver nanoparticles (AgNPs) with various input concentration (Co), flow velocity, and ionic strength (IS), and the rem...

  18. Simulation of arsenic retention in constructed wetlands. (United States)

    Valles-Aragón, M C; Alarcón-Herrera, M T; Llorens, E; Obradors-Prats, J; Leyva, A


    The software RCB-arsenic was developed previously to simulate the metalloid behavior in a constructed wetland (CW). The model simulates water flow and reactive transport by contemplating the major processes of arsenic (As) retention inside of CW. The objective of this study was to validate the RCB-arsenic model by simulating the behavior of horizontal flow CW for As removal from water. The model validation was made using data from a 122-day experiment. Two CWs prototypes were used: one planted with Eleocharis macrostachya (CW_planted) and another one unplanted (CW_unplanted) as a control. The prototypes were fed with synthetic water prepared using well water and sodium arsenite (NaAsO2). In the RCB-arsenic model, a CW prototype was represented using a 2D mesh sized in accordance with the experiment. For simulation of As retention in CW, data addition was established in two stages that considered the mechanisms in the system: (1) aqueous complexation, precipitation/dissolution, and adsorption on granular media and (2) retention by plants: uptake (absorption) and rhizofiltration (adsorption). Simulation of As outlet (μg/L) in stage_1 was compared with CW_unplanted; the experimental mean was 40.79 ± 7.76 and the simulated 39.96 ± 6.32. As concentration (μg/L) in stage_2 was compared with CW_planted, the experimental mean was 9.34 ± 4.80 and the simulated 5.14 ± 0.72. The mass-balance simulation and experiment at 122 days of operation had a similar As retention rate (94 and 91%). The calibrated model RCB-arsenic adequately simulated the As retention in a CW; therefore, it constitutes a powerful tool of design.

  19. Toward a Record Retention Policy (United States)

    Vaughan, Jason


    An academic library working group was charged in 2005 to create a records retention schedule and policy applicable to records containing personally identifiable information of library patrons. This group conducted a survey and extensive research, culminating in an adopted library records retention schedule and policy implemented in 2006.

  20. Military Retention. A Comparative Outlook

    Directory of Open Access Journals (Sweden)

    Vasile Sminchise


    Full Text Available One of the main goals for human resources management structures and for armed forces leaders is to maintain all necessary personnel, both qualitatively and quantitatively for operational needs or for full required capabilities. The retention of military personnel is essential to keep morale and unit readiness and to reduce the costs for recruiting, training, replacement of manpower. Retention rates depend not only on money or other social measures. The goal for retention is to keep in use the most valuable resource that belongs to an organization: the human beings and their knowledge. The aim pf this paper is to provide a comparative analysis of retention measures in various countries based on Research and Technology Organisation report released in 2007 and, thus, provide more examples of retention measures as far as the Romanian military system is concerned.

  1. Faster Energy Efficient Column Compression Multiplication

    CERN Document Server

    Ramkumar, B


    In this work we demonstrate that faster, energy efficient, column compression multiplication, can be achieved by using a combination of two design techniques: partitioning of the partial products into two parts for independent parallel column compression and acceleration of the final addition using a hybrid adder proposed in this work. In order to demonstrate the efficacy of the techniques we have chosen the Dadda multiplier as an example. Based on the proposed techniques 8, 16, 32 and 64-bit Dadda multipliers are developed and compared with the regular Dadda multiplier. The performance of the proposed multiplier is analyzed by evaluating the delay, area and power, with 180 nm process technologies on interconnect and layout using industry standard design and layout tools. The result analysis shows that the 64-bit regular Dadda multiplier is as much as 41.1% slower than the proposed multiplier and requires only 1.4% and 3.7% less area and power respectively. Also the power-delay product of the proposed design ...

  2. Using a box instead of a column for process chromatography. (United States)

    Ghosh, Raja


    Columns with relatively short bed-height to diameter ratios are frequently used for process-scale chromatography applications such as biopharmaceutical purification. Non-uniform flow distribution within such columns could result in broad and poorly resolved eluted peaks, which could in turn affect purity, recovery and productivity of the process. Different strategies centered on improved column header design have been proposed for addressing this problem. This paper describes a radically different approach, i.e. the use of a chromatography box (or chromato-box) instead of a column, for addressing the challenges posed by flow mal-distribution in process-scale, packed-bed chromatography devices. The design of the chromatography box devices used in this study is based on a laterally-fed membrane chromatography (or LFMC) device, that has been described and discussed in several recent papers. The performances of two chromatography box devices were compared with their equivalent columns in terms of sharpness and asymmetry of flow-through and eluted peaks, number of theoretical plates per metre, and peak resolution in binary and ternary protein separations. In each of the above comparisons, the chromatography box devices performed better than their equivalent columns, clearly indicating their potential as an alternative in process-scale chromatography applications. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. Seismic Behavior of Short Concrete Columns with Prestressing Steel Wires

    Directory of Open Access Journals (Sweden)

    Deng Zong-Cai


    Full Text Available The seismic behavior of short circular reinforced concrete columns was studied by testing seven columns retrofitted with prestressing steel wire (PSW, subjected to combined constant axial compression and lateral cyclic load. The main test parameters were configuration index of PSW, prestressing level of PSW, and axial compression ratio. An analysis and discussion of the test results including failure mode, hysteresis curves, skeleton curves, ductility, and degradation of stiffness was done. The results show that the seismic performance of the retrofitted specimens could be effectively enhanced even if the axial compression ratio of columns reached 0.81. The ductility index and the energy absorption capacity of the retrofitted specimens increase with the prestressing level of PSW. The formulas for calculating shear capacity of RC short columns strengthened with PSW were proposed which may be useful for future engineering designs and researches.

  4. A Modelling Framework for Conventional and Heat Integrated Distillation Columns

    DEFF Research Database (Denmark)

    Bisgaard, Thomas; Huusom, Jakob Kjøbsted; Abildskov, Jens


    Diabatic operation of distillation columns can lead to signicant reductions in energy utilization and operation cost compared to conventional (adiabatic) distillation columns, at an expense of an increased complexity of design and operation. The earliest diabatic distillation conguration dates back...... to the late 70s, and various dierent congurations have appeared since. However, at present, no full-scale diabatic distillation columns are currently operating in the industry. Current studies related to alternative distillation congurations report very dierent gures for potential energy savings which...... constitutes a problem in relations to achieving industrial acceptance. There is clearly a need for research and comparative studies which can help to provide analysis of the pros and cons of novel and intensied distillation processes compared to conventional columns for a range of separations. These studies...

  5. Prediction of liquid chromatography retention factors for α-branched phenylsulfonyl acetates using quantum chemical descriptors

    Institute of Scientific and Technical Information of China (English)


    The logarithms of retention factors normalized to a hypothetical pure water eluent( log kw ) were determined on a reversed-phase highperformance liquid chromatography(RP-HPLC) column (Li Chrosorb RP-18 column) for 20 new α-branched phenylsulfonyl acetates. The atomic charge method was applied to develop quantitative structure-retention relationships (QSRRs). Among the available geometric and electronic descriptors, surface area (S), ovality (O), and the charge of carboxyl group(Qoc ) are significant. In the model, the contribution of surface area (S) is the greatest. The molecular mechanism of retention was demonstrated through the model. With the correlation coefficient ( r2adj, adjusted for degrees of freedom) of 0. 964, the standard error of 0. 164 and the F-value of 170.39, the model has good predictive capacity.

  6. Leadership training to improve nurse retention. (United States)

    Wallis, Allan; Kennedy, Kathy I


    This paper discusses findings from an evaluation of a training programme designed to promote collaborative, team-based approaches to improve nurse retention within health care organizations. A year-long leadership training programme was designed and implemented to develop effective teams that could address retention challenges in a diverse set of organizations in Colorado ranging from public, private to non-profit. An evaluation, based on a combination of participant observation, group interviews, and the use of standardized tests measuring individual emotional intelligence and team dynamics was conducted to assess the effectiveness of the training programme. What role do the emotional intelligence of individual members and organizational culture play in team effectiveness? Out of five teams participating in the training programme, two performed exceptionally well, one experienced moderate success and two encountered significant problems. Team dynamics were significantly affected by the emotional intelligence of key members holding supervisory positions and by the existing culture and structure of the participating organizations. Team approaches to retention hold promise but require careful development and are most likely to work where organizations have a collaborative problem-solving environment. © 2012 Blackwell Publishing Ltd.

  7. Column Holdup Formula of Soil Solute Transport

    Institute of Scientific and Technical Information of China (English)


    The shortcomings of the present two formulae for describing column holdup are analyzed and deductions are made to find a new formula. The column holdup, Hw, described by the new formula is dimensional,and related to soil solute transport kinesis and column physical properties. Compared with the other two column holdups, Hw is feasible to describe dimensional column holdup during solute transport process. The relationships between Hw and retardation factor, R, in different solute transport boundary conditions are established.

  8. Partially saturated granular column collapse (United States)

    Turnbull, Barbara; Johnson, Chris


    Debris flows are gravity-driven sub-aerial mass movements containing water, sediments, soil and rocks. These elements lead to characteristics common to dry granular media (e.g. levee formation) and viscous gravity currents (viscous fingering and surge instabilities). The importance of pore fluid in these flows is widely recognised, but there is significant debate over the mechanisms of build up and dissipation of pore fluid pressure within debris flows, and the resultant effect this has on dilation and mobility of the grains. Here we specifically consider the effects of the liquid surface in the flow. We start with a simple experiment constituting a classical axisymmetric granular column collapse, but with fluid filling the column up to a depth comparable to the depth of grains. Thus, as the column collapses, capillary forces may be generated between the grains that prevent dilation. We explore a parameter space to uncover the effects of fluid viscosity, particle size, column size, aspect ratio, grain shape, saturation level, initial packing fraction and significantly, the effects of fine sediments in suspension which can alter the capillary interaction between wetted macroscopic grains. This work presents an initial scaling analysis and attempts to relate the findings to current debris flow modelling approaches.

  9. Transport and retention of fullerene (C60) nanoparticles in natural soils (United States)

    Wang, Y.; Li, Y.; Abriola, L. M.; Pennell, K. D.


    Although several column studies have investigated the transport and deposition of fullerene (C60) nanoparticles in ideal porous media, such as washed quartz sands and glass beads, far less attention has been directed toward natural soils. To address this issue, a series of column experiments was performed to quantify the transport and retention of C60 nanoparticles in a borosilicate glass column (10 cm length x 2.5 cm dia.) packed with either Appling soil or Webster soil. Introduction of a C60 suspension containing 1 mM calcium chloride as background electrolyte for up to 65 pore volumes resulted in 100 percent retention of injected mass. Retained C60 nanoparticles were concentrated within 6 cm of the column from inlet, with solid phase concentrations approaching 130 μg/g. The presence of Suwannee River humic acid (20 mg/L) in the C60 suspension slightly enhanced mobility of nC60, although effluent breakthrough was not observed. However, when mixed with 1,000 mg/L polyethoxylate (20) sorbitan monooleate (Tween 80), C60 nanoparticles were readily transported through Appling soil, with less than 40 percent of injected mass retained. Retentions profiles of nC60 exhibited gradual ascent and descent, but not symmetrically, with distance from inlet. A mathematic transport model incorporating classical filtration theory, non-linear sorption process, and straining was utilized to capture C60 effluent breakthrough curves and retention profiles observed in the column experiments. These findings indicate that Appling soil and Webster soil exhibit large retention capacity for C60 nanoparticle, and that transport of C60 is greatly enhanced in the presence of stabilizing agents.

  10. Analytic solutions for colloid transport with time- and depth-dependent retention in porous media (United States)

    Leij, Feike J.; Bradford, Scott A.; Sciortino, Antonella


    Elucidating and quantifying the transport of industrial nanoparticles (e.g. silver, carbon nanotubes, and graphene oxide) and other colloid-size particles such as viruses and bacteria is important to safeguard and manage the quality of the subsurface environment. Analytic solutions were derived for aqueous and solid phase colloid concentrations in a porous medium where colloids were subject to advective transport and reversible time and/or depth-dependent retention. Time-dependent blocking and ripening retention were described using a Langmuir-type equation with a rate coefficient that respectively decreased and increased linearly with the retained concentration. Depth-dependent retention was described using a rate coefficient that is a power-law function of distance. The stream tube modeling concept was employed to extend these analytic solutions to transport scenarios with two different partitioning processes (i.e., two types of retention sites). The sensitivity of concentrations was illustrated for the various time- and/or depth-dependent retention model parameters. The developed analytical models were subsequently used to describe breakthrough curves and, in some cases, retention profiles from several published column studies that employed nanoparticle or pathogenic microorganisms. Simulations results provided valuable insights on causes for many observed complexities associated with colloid transport and retention, including: increasing or decreasing effluent concentrations with continued colloid application, delayed breakthrough, low concentration tailing, and retention profiles that are hyper-exponential, exponential, linear, or non-monotonic with distance.

  11. Retention in orthodontics. (United States)

    Johnston, C D; Littlewood, S J


    Retention is necessary following orthodontic treatment to prevent relapse of the final occlusal outcome. Relapse can occur as a result of forces from the periodontal fibres around the teeth which tend to pull the teeth back towards their pre-treatment positions, and also from deflecting occlusal contacts if the final occlusion is less than ideal. Age changes, in the form of ongoing dentofacial growth, as well as changes in the surrounding soft tissues, can also affect the stability of the orthodontic outcome. It is therefore essential that orthodontists, patients and their general dental practitioners understand the importance of wearing retainers after orthodontic treatment. This article will update the reader on the different types of removable and fixed retainers, including their indications, duration of wear, and how they should be managed in order to minimise any unwanted effects on oral health and orthodontic outcomes. The key roles that the general dental practitioner can play in supporting their patients wearing orthodontic retainers are also emphasised.

  12. Temperature-based on-column solute focusing in capillary liquid chromatography reduces peak broadening from pre-column dispersion and volume overload when used alone or with solvent-based focusing. (United States)

    Groskreutz, Stephen R; Horner, Anthony R; Weber, Stephen G


    On-column focusing is essential for satisfactory performance using capillary scale columns. On-column focusing results from generating transient conditions at the head of the column that lead to high solute retention. Solvent-based on-column focusing is a well-known approach to achieve this. Temperature-assisted on-column focusing (TASF) can also be effective. TASF improves focusing by cooling a short segment of the column inlet to a temperature that is lower than the column temperature during the injection and then rapidly heating the focusing segment to the match the column temperature. A troublesome feature of an earlier implementation of TASF was the need to leave the capillary column unpacked in that portion of the column inside the fitting connecting it to the injection valve. We have overcome that problem in this work by packing the head of the column with solid silica spheres. In addition, technical improvements to the TASF instrumentation include: selection of a more powerful thermo-electric cooler to create faster temperature changes and electronic control for easy incorporation into conventional capillary instruments. Used in conjunction with solvent-based focusing and with isocratic elution, volumes of paraben samples (esters of p-hydroxybenzoic acid) up to 4.5-times the column liquid volume can be injected without significant bandspreading due to volume overload. Interestingly, the shapes of the peaks from the lowest volume injections that we can make, 30nL, are improved when using TASF. TASF is very effective at reducing the detrimental effects of pre-column dispersion using isocratic elution. Finally, we show that TASF can be used to focus the neuropeptide galanin in a sample solvent with elution strength stronger than the mobile phase. Here, the stronger solvent is necessitated by the need to prevent peptide adsorption prior to and during analysis.

  13. Data Retention and Anonymity Services (United States)

    Berthold, Stefan; Böhme, Rainer; Köpsell, Stefan

    The recently introduced legislation on data retention to aid prosecuting cyber-related crime in Europe also affects the achievable security of systems for anonymous communication on the Internet. We argue that data retention requires a review of existing security evaluations against a new class of realistic adversary models. In particular, we present theoretical results and first empirical evidence for intersection attacks by law enforcement authorities. The reference architecture for our study is the anonymity service AN.ON, from which we also collect empirical data. Our adversary model reflects an interpretation of the current implementation of the EC Directive on Data Retention in Germany.

  14. Polymethacrylate monolithic and hybrid particle-monolithic columns for reversed-phase and hydrophilic interaction capillary liquid chromatography. (United States)

    Jandera, Pavel; Urban, Jirí; Skeríková, Veronika; Langmaier, Pavel; Kubícková, Romana; Planeta, Josef


    We prepared hybrid particle-monolithic polymethacrylate columns for micro-HPLC by in situ polymerization in fused silica capillaries pre-packed with 3-5microm C(18) and aminopropyl silica bonded particles, using polymerization mixtures based on laurylmethacrylate-ethylene dimethacrylate (co)polymers for the reversed-phase (RP) mode and [2-(methacryloyloxy)ethyl]-dimethyl-(3-sulfopropyl) zwitterionic (co)polymers for the hydrophilic interaction (HILIC) mode. The hybrid particle-monolithic columns showed reduced porosity and hold-up volumes, approximately 2-2.5 times lower in comparison to the pure monolithic columns prepared in the whole volume of empty capillaries. The elution volumes of sample compounds are also generally lower in comparison to packed or pure monolithic columns. The efficiency and permeability of the hybrid columns are intermediate in between the properties of the reference pure monolithic and particle-packed columns. The chemistries of the embedded solid particles and of the interparticle monolithic moiety in the hybrid capillary columns contribute to the retention to various degrees, affecting the selectivity of separation. Some hybrid columns provided improved separations of proteins in comparison to the reference particle-packed columns in the reversed-phase mode. Zwitterionic hybrid particle-monolithic columns show dual mode retention HILIC/RP behaviour depending on the composition of the mobile phase and allow separations of polar compounds such as phenolic acids in the HILIC mode at lower concentrations of acetonitrile and, often in shorter analysis time in comparison to particle-packed and full-volume monolithic columns.

  15. Columns

    Institute of Scientific and Technical Information of China (English)

    于晓悠; 丁燕燕; 韩多妮; Ray; Carrie; 未冉


    <正>New York Whitney艺术双年展今年第75届纽约Whitney双年展不设题目,但以"2010"指示策展方向,继续以发掘年轻艺术家、展示创作实验为目标。参展的55位艺术家,最年轻的是23岁摄影师Tam Tran,最老资历的是75岁的概念艺术家Lorraine O’Grady。这届的另一先创性,是每位艺术家只限一件或一个系列的作品,避免了去届双年展的"小型个人回顾展"现象,而五层楼的展场各有特色,如录像及短片将独立于三楼展出,而美术馆馆藏则移师五楼。这届双年展由著名的意大利策展人Francesco Bonami联同助手Gary Carrion-Murayarn共同制作,两位策展人说明,双年展的重要性是预示未来,创新及前瞻性依然是取决原则。

  16. Columns

    Institute of Scientific and Technical Information of China (English)

    Carrie Tsang; 丁燕燕; 韩多妮; RAY


    <正>Paris承诺的展现33岁的墨西哥艺术家Mario Garcia Torres是近年国际艺坛炙手可热的新星,他以录象、摄影、幻灯及装置为创作形式,透过个人视点及独特演绎手法来重新思考历史。他是一个思考型艺术家,同时又是一个淘气的大孩子,作品往往反映了他的双重性格——嬉戏中带有深沉的历史感。这次是GarciaTorres首次在法国的国家博物馆举行展览,整合出版了他过往两年间在

  17. Relating pressure tuned coupled column ensembles with the solvation parameter model for tunable selectivity in gas chromatography. (United States)

    Sharif, Khan M; Kulsing, Chadin; Chin, Sung-Tong; Marriott, Philip J


    The differential pressure drop of carrier gas by tuning the junction point pressure of a coupled column gas chromatographic system leads to a unique selectivity of the overall separation, which can be tested using a mixture of compounds with a wide range of polarity. This study demonstrates a pressure tuning (PT) GC system employing a microfluidic Deans switch located at the mid-point of the two capillary columns. This PT system allowed variations of inlet-outlet pressure differences of the two columns in a range of 52-17psi for the upstream column and 31-11psi for the downstream column. Peak shifting (differential migration) of compounds due to PT difference are related to a first order regression equation in a Plackett-Burman factorial study. Increased first (upstream) column pressure drop makes the second column characteristics more significant in the coupled column retention behavior, and conversely increased second (downstream) column pressure drop makes the first column characteristics more apparent; such variation can result in component swapping between polar and non-polar compounds. The coupled column system selectivity was evaluated in terms of linear solvation energy relationship (LSER) parameters, and their relation with different pressure drop effects has been constructed by applying multivariate principle component analysis (PCA). It has been found that the coupled column PT system descriptors provide a result that shows a clear clustering of different pressure settings, somewhat intermediate between those of the two commercial columns. This is equivalent to that obtained from a conventional single-column GC analysis where the interaction energy contributed from the stationary phases can be significantly adjusted by choice of midpoint PT. This result provides a foundation for pressure differentiation for selectivity enhancement.

  18. Methodology for optimally sized centrifugal partition chromatography columns. (United States)

    Chollet, Sébastien; Marchal, Luc; Jérémy Meucci; Renault, Jean-Hugues; Legrand, Jack; Foucault, Alain


    Centrifugal Partition Chromatography (CPC) is a separation process based on the partitioning of solutes between two partially miscible liquid phases. There is no solid support for the stationary phase. The centrifugal acceleration is responsible for both stationary phase retention and mobile phase dispersion. CPC is thus a process based on liquid-liquid mass transfer. The separation efficiency is mainly influenced by the hydrodynamics of the phases in each cell of the column. Thanks to a visualization system, called "Visual CPC", it was observed that the mobile phase can flow through the stationary phase as a sheet, or a spray. Hydrodynamics, which directly governs the instrument efficiency, is directly affected during scale changes, and non-linear phenomena prevent the successful achievement of mastered geometrical scale changes. In this work, a methodology for CPC column sizing is proposed, based on the characterization of the efficiency of advanced cell shapes, taking into account the hydrodynamics. Knowledge about relationship between stationary phase volume, cell efficiency and separation resolution in CPC allowed calculating the optimum cell number for laboratory and industrial scale CPC application. The methodology is highlighted with results on five different geometries from 25 to 5000 mL, for two applications: the separation of alkylbenzene by partitioning with heptane/methanol/water biphasic system; and the separation of peptides by partitioning with n-butanol/acetic acid/water (4/1/5) biphasic system. With this approach, it is possible to predict the optimal CPC column length leading to highest productivity.

  19. Gas chromatographic retention characteristics of different polysiloxane oligomers

    Energy Technology Data Exchange (ETDEWEB)

    Van Lenten, F. J.; Conaway, J. E.; Rogers, L. B.


    The effects on the Kovats and McReynolds indices for a modified set of Rohrschneider solutes have been examined using two different batches of a commercial polysiloxane stationary phase, Dow-Corning DC-710, and five pure oligomers isolated from the mixture. The significant differences that were found between batches appear to be due primarily to changes in the percentage of one oligomer, the cyclic pentamer. This finding emphasizes the desirability of using a pure stationary phase as well as carefully specifying the column temperature in order to improve intra- and inter- laboratory comparisons of retention indices.

  20. A novel molecular distance edge vector as applied to chemical modeling of quantitative structure-retention relationships: Various gas chromatographic retention behaviors of polychlorinated dibenzo-furans on different polarity-varying stationary phases

    Institute of Scientific and Technical Information of China (English)

    DENG Hong; HUANG Ping; HU Yinyu; YE Nancy; LI Zhiliang


    Based on the identical group as a pseudo atom instead of a typical atom, a novel modified molecular distance-edge (MDE) vector μ was developed in our laboratory to characterize chemical structure of polychlorinated dibenzofurans (PCDFs) congeners and/or isomers. Quantitative structure-retention relationships (QSRRs) between the new VMDE parameters and gas chromatographic (GC) retention behavior of PCDFs were then generated by multiple linear regression (MLR) method for non-polar, moderately polar, and polar stationary phases. Four excellent models with high correlation coefficients, R=0.984-0.995, were proposed for non-polar columns (DB-5, SE-54, OV-101). For the moderately polar columns (OV-1701), the correlation coefficient of the developed good model is only 0.958. For the polar columns (SP-2300), the QSRR model is poor with R=0.884. Then cross validation with leave-one out of procedure (CV) is performed in high correlation with the non-polar (Rcv=992-0.974) and weakly polar (Rcv=921) columns and in little correlation (Rcv=0.834) with the polar columns. These results show that the new μ vector is suitable for describing the retention behaviors of PCDFs on non-polar and moderately polar stationary phases and not for the various gas chromatographic retention behaviors of PCDFs on the different polarity-varying stationary phases.

  1. Intermittent counter-current extraction-Equilibrium cell model, scaling and an improved bobbin design. (United States)

    Hewitson, Peter; Sutherland, Ian; Kostanyan, Artak E; Voshkin, Andrei A; Ignatova, Svetlana


    This paper describes an equilibrium cell model for intermittent counter-current extraction that is analytically solved for the first time for continuous sample injection between a pair of columns. The model is compared with practice for injections of a model mixture of compounds on a standard high-performance counter-current chromatography instrument giving good agreement for compound elution order and the times to maximum concentration for the eluted components. An improved design of end fittings for the counter-current chromatography bobbins is described which permits on-column switching of the mobile and stationary phases. This on-column switching successfully eliminates the displaced stationary phase seen in fractions when operating ICcE with standard flying leads and gives a 6% reduction in the retention time of compounds and improved resolution due to the elimination of the time delay required to pump the previous mobile phase from standard flying leads.

  2. On column density thresholds and the star formation rate

    CERN Document Server

    Clark, Paul C


    We present the results of a numerical study designed to address the question of whether there is a column density threshold for star formation within molecular clouds. We have simulated a large number of different clouds, with volume and column densities spanning a wide range of different values, using a state-of-the-art model for the coupled chemical, thermal and dynamical evolution of the gas. We show that for low-mass clouds, around 1000 solar masses and below, star formation is only possible if the mean cloud column density exceeds 10^21 cm^-2. In more massive clouds, the required mean column density is a factor of a few lower. We demonstrate that this behaviour is well-described by a simple Jeans mass argument: clouds must contain multiple Jeans masses in order to form stars, and hence star-forming clouds cannot have arbitrarily low column densities. We have also examined the question of whether there is a column density threshold for the regions within clouds where star formation occurs. We show that th...

  3. Effects of grain size and structural heterogeneity on the transport and retention of nano-TiO2 in saturated porous media. (United States)

    Lv, Xueyan; Gao, Bin; Sun, Yuanyuan; Dong, Shunan; Wu, Jichun; Jiang, Beilei; Shi, Xiaoqing


    Accurately predicting the fate and transport of nano-TiO2 in porous media is critical to assess its environmental impact. This study was designed to understand the effects of gain size and structural heterogeneity under different ionic strength (IS) on the fate and transport of nano-TiO2 in saturated porous media. In the columns packed homogenously with sand of different grain sizes (920, 550, 390, and 275μm), the transport of nano-TiO2 decreased when the IS increased from 0.1 to 1 or 10mM. For all the three IS conditions, the retention of the nano-TiO2 particles in the columns increased when the gain size decreased, and the mobility of the nano-TiO2 was the lowest in the sand at size of 275μm with recovery rates of 0.30% to 1.72%. The mass recovery rates of TiO2 in other homogeneous columns were higher and ranged from 0.37% to 59.9%. Structural heterogeneity created two flow domains for the retention and transport of nano-TiO2 particles in the saturated porous media. The fast-flow domain dominated the flow and transport processes of the nano-TiO2 in the heterogeneous columns under the tested conditions. As a result, the transport of nano-TiO2 in the heterogeneous porous media was faster and higher than that in the homogeneous columns under similar experimental conditions. Because of the dominance of the fast-flow domain, the recovery rates of the nano-TiO2 in the heterogeneous columns were similar and ranged from 59.8% to 66.9%. These results reflected the importance of preferential flow to the fate and transport of nano-TiO2 particle in porous media. Simulations from a two-domain model matched the experimental breakthrough curves very well. Copyright © 2015 Elsevier B.V. All rights reserved.

  4. Fuzzy indicators for customer retention

    National Research Council Canada - National Science Library

    Valenzuela-Fernández, Leslier; Nicolas, Carolina; Gil-Lafuente, Jaime; Merigó, José M


    .... Nevertheless, one cannot ignore the existence of a gap on how to measure this relationship. Following this idea, this study proposes six fuzzy key performance indicators that aims to measure customer retention and loyalty of the portfolio...

  5. Post-operative urinary retention. (United States)

    Steggall, Martin; Treacy, Colm; Jones, Mark

    Urinary retention is a common complication of surgery and anaesthesia. The risk of post-operative urinary retention is increased following certain surgical procedures and anaesthetic modalities, and with patients' advancing age. Patients at increased risk of post-operative urinary retention should be identified before surgery or the condition should be identified and treated in a timely manner following surgery. If conservative measures do not help the patient to pass urine, the bladder will need to be drained using either an intermittent catheter or an indwelling urethral catheter, which can result in catheter-associated urinary tract infections. This article provides an overview of normal bladder function, risk factors for developing post-operative urinary retention, and treatment options. Guidance drawn from the literature aims to assist nurses in identifying at-risk patients and inform patient care.

  6. A comparison study of commercially-available column flotation technologies

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q.; Mohanty, M.K.; Paul, B.C. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining Engineering; Ho, K. [Illinois Clean Coal Inst., Carterville, IL (United States)


    A direct comparison of three commercially-available column flotation technologies, i.e., Jameson Cell, Microcel, and Packed-Column, has been conducted using a {minus}100 mesh Illinois No. 5 flotation feed coal sample. The separation performance of each flotation technology was optimized and their performance levels compared on the basis of both ash rejection, sulfur rejection, and throughput capacities. A parametric study using a statistically-designed experimental program was conducted to optimize the critical operating parameter values of each column. The ultimate performance curves for each column were generated by conducting additional tests using the optimized operating parameter values. The throughput capacity of each flotation cell was determined by conducting tests over a range of feed rates at the maximum superficial gas rate while maintaining the other parameters at their optimum values. The separation performance achieved by each of the three flotation cells was found to be comparable to the idealistic flotation performance predicted by release analysis. However, the fraction of wash water reporting to tailings (bias factor) was found to be critical in achieving the near idealistic performance. The bias factor required for the Packed-Column was found to be less than that required by the other two flotation cells. The sulfur rejection achieved by the Microcel and the Packed-Column were found to be greater than that achieved by the Jameson Cell and all three produced sulfur rejections exceeding the values obtained from release analysis. The throughput capacity, on the other hand, differed among the three flotation columns. The Jameson Cell and the Microcel were found to have comparable throughput capacities while the Packed-Column was found to have a lower capacity.

  7. [Rapid determination of propranolol enantiomers in rat plasma by column-switching-high performance liquid chromatography]. (United States)

    Wu, Xiaoyu; Wang, Rong; Xie, Hua; Wang, Jianfeng; Jia, Zhengping; Zhang, Qiang; Wang, Xianhua


    A high performance liquid chromatographic (HPLC) method with column-switching was developed and validated for rapid determination of two propranolol enantiomers in rat plasma. The column of restricted-access media was used as a pre-treatment column and a Chiralcel OD-RH was used as analytical column. The plasma samples were injected directly into the pretreatment column to remove plasma protein and endogenous constituents as well as to retent the propranolol enantiomers in the column using the mobile phase of borate buffer (pH 8.5)-methanol (95:5, v/v) at the flow rate of 1.0 mL/min. Then the propranolol enantiomers were transferred to the Chiralcel OD-RH column using the mobile phase of isopropanol-ethanol-0.2 mmol/L borate buffer (pH 8.5) (30: 30: 40, v/v/v) at a flow rate of 0.8 mL/min by column-switching technology. The column-switching time was 3.0 min, the used wavelength was 293 nm and the column temperature was set at 25 degrees C. The calibration curve showed excellent linear relationship (r = 0.999 5) in the concentration range from 25 mg/L to 500 mg/L for propranolol enantiomers in plasma. The intra-day and inter-day assay precisions and accuracies were well and the relative standard deviations (RSDs) were less than 5%. The average recoveries (n = 6) of the two enantiomers at 3 spiked levels were from 97.89% to 101.56%. All the values of the method validation were within the generally accepted criteria for biological sample analysis. The results show that the method is convenient, quick, sensitive and accurate. The method was successfully applied in the determination of propranolol enantiomers in rat blood pharmacokinetics study.

  8. Associations between the Cervical Vertebral Column and Craniofacial Morphology

    DEFF Research Database (Denmark)

    Sonnesen, Ane Liselotte


    Aim. To summarize recent studies on morphological deviations of the cervical vertebral column and associations with craniofacial morphology and head posture in nonsyndromic patients and in patients with obstructive sleep apnoea (OSA). Design. In these recent studies, visual assessment of the cerv......Aim. To summarize recent studies on morphological deviations of the cervical vertebral column and associations with craniofacial morphology and head posture in nonsyndromic patients and in patients with obstructive sleep apnoea (OSA). Design. In these recent studies, visual assessment...... that fusion of the cervical vertebral column is associated with development and function of the craniofacial morphology. This finding is expected to have importance for diagnostics and elucidation of aetiology and thereby for optimal treatment....

  9. Modeling of column apparatus processes

    CERN Document Server

    Boyadjiev, Christo; Boyadjiev, Boyan; Popova-Krumova, Petya


    This book presents a new approach for the modeling of chemical and interphase mass transfer processes in industrial column apparatuses, using convection-diffusion and average-concentration models. The convection-diffusion type models are used for a qualitative analysis of the processes and to assess the main, small and slight physical effects, and then reject the slight effects. As a result, the process mechanism can be identified. It also introduces average concentration models for quantitative analysis, which use the average values of the velocity and concentration over the cross-sectional area of the column. The new models are used to analyze different processes (simple and complex chemical reactions, absorption, adsorption and catalytic reactions), and make it possible to model the processes of gas purification with sulfur dioxide, which form the basis of several patents.

  10. Measuring Predictors of Student Retention Rates

    Directory of Open Access Journals (Sweden)

    Allen L. Webster


    Full Text Available Problem statement: Colleges and universities place more emphasis on student retention rates than ever before. Educational institutions are intensifying efforts to discourage student departure and preserve their established student base. Economic pressures that bear heavily on academic administration make such efforts highly critical for institutional success. Research on this vital issue is especially important due to the vigorous competition among college and universities to recruit students and maintain enrollment levels. This pressure is heightened by the fact that it costs more to attract students than it does to retain them. Approach: This study uses institutional-based data to examine student attrition levels with the intent to identify their chief determinants and provide the foundation for post-secondary institutions to explore the viability of their own retention programs. Discriminant analysis is used to distinguish those schools that exhibit a higher degree of success in retaining student enrollments from those who suffer higher departure trends. Results: Tuition, student/teacher ratio and the amount of dollar aid offered the students all play substantial roles in encouraging persistence. The acceptance rate and enrollment levels were found to provide less discriminatory power. Conclusion: Students are influenced by the personal attention they receive and the manner in which their chosen institution of higher education caters to their individual needs, problems and concerns. Colleges and universities concerned with student retention would benefit from concentrated programs designed to provide individualized student services that address immediate student needs.

  11. Comparison of drug substance impurity profiles generated with extended length columns during packed-column SFC. (United States)

    Roston, D A; Ahmed, S; Williams, D; Catalano, T


    The current study assesses the effect of extending column length during gradient packed column sub/supercritical fluid chromatography (PCSFC) experiments on the detection of known and unknown impurities in a drug substance sample. Quantitative drug substance impurity profiles were generated and compared using multiple column PCSFC and HPLC conditions. Also, chromatographic figures of merit were estimated and compared for components of a standard mixture during PCSFC experiments, which used one column, four columns, and six columns in series.

  12. Beam Studies with Electron Columns

    Energy Technology Data Exchange (ETDEWEB)

    Shiltsev, V.; Valishev, A.; Kuznetsov, G.; /Fermilab; Kamerdzhiev, V.; /Julich, Forschungszentrum; Romanov, A.; /Novosibirsk, IYF


    We report preliminary results of experimental studies of 'electron columns' in the Tevatron and in a specialized test setup. In the Tevatron, a beam of 150 GeV protons ionizes residual gas and ionization electrons are stored in an electrostatic trap immersed into strong longitudinal magnetic field. Shifts of proton betatron frequencies are observed. In the test setup, we observe effects pointing to accumulation and escape of ionization electrons.

  13. Water Column Methylation in Estuaries (United States)

    Schartup, A. T.; Calder, R.; Soerensen, A. L.; Mason, R. P.; Balcom, P. H.; Sunderland, E. M.


    Methylmercury (MeHg) is a neurotoxin that bioaccumulates in aquatic food webs and affects humans and wildlife through fish consumption. Many studies have measured active methylation/demethylation in ocean margin sediments but few have reported similar rates for the marine water column. This presentation will review available evidence for water column methylation in estuaries, including new experimental measurements of methylation/demethylation rates from a deep subarctic fjord in Labrador Canada collected in Spring and Fall of 2012-2013. We used these and other data to construct a mass budget for MeHg in the estuary and show that water column methylation (with rates ranging from 1.5 to 2.8 % day-1), is the largest contributor, followed by inputs from rivers (4.9 mol year-1), to the in situ pool of MeHg available for uptake by biota. By contrast, the sediment in this system is a net sink for MeHg (-1.5 mol year-1). We discuss the relationship between observed MeHg and other ancillary environmental factors (organic carbon, sulfur and nutrients) as well as implications for the response time of fish to future changes in mercury inputs.

  14. The role of sand, marble chips and Typha latifolia in domestic wastewater treatment - a column study on constructed wetlands. (United States)

    Kadaverugu, Rakesh; Shingare, Rita P; Raghunathan, Karthik; Juwarkar, Asha A; Thawale, Prashant R; Singh, Sanjeev K


    The relative importance of sand, marble chips and wetland plant Typha latifolia is evaluated in constructed wetlands (CWs) for the treatment of domestic wastewater intended for reuse in agriculture. The prototype CWs for the experiments are realized in polyvinyl chloride columns, which are grouped into four treatments, viz. sand (<2 mm) + Typha latifolia (cattail), sand, marble chips (5-20 mm) + cattail and marble chips. The removal percentage of organic and nutritional pollutants from the wastewater is measured at varying hydraulic retention time in the columns. The statistical analysis suggests that the main effects of sand and cattail are found to be significant (p < .05) for the removal of biological oxygen demand and chemical oxygen demand from the wastewater. The presence of cattail significantly (p < .01) contributes to the conversion of total nitrogen in wastewater into [Formula: see text] by fostering the growth of favorable microbes for the nitrification. The removal of [Formula: see text] and turbidity from the wastewater is significantly (p < .01) influenced by sand than the presence of cattail. The maximum [Formula: see text] adsorption capacity of the sand is estimated to be 2.5 mg/g. Marble chips have significantly (p < .01) influenced the removal of [Formula: see text]and its maximum removal capacity is estimated to be 9.3 mg/g. The negative correlation between the filter media biofilm and column hydraulic conductivity is also reported for all the treatments. Thus, the findings of this study elucidate the role of low-cost and easily available filter media and it will guide the environmental practitioners in designing cost-effective CWs for wastewater treatment.

  15. Theoretical research on the shear bearing capacity of exposed steel column foot (United States)

    LIU, Xijin


    This paper makes an overview on the domestic research on the steel column shear capacity in detail. On such basis, in accordance with the 4th theory of strength and the flexural vibration of straight bar, it makes theoretical analysis on the shear-bearing capacity of the steel column foot with the shear key and without the shear key respectively. It proposes the methods for calculating the shear-bearing capacity of steel column foot under two situations. It suggests that Code for Design of Steel Structures should raise the separation point of exposed steel column foot, which would reduce the construction difficulty of the exposed steel column foot, shorten the construction period, improve the construction quality and provide certain theoretical references for the design and research on the steel column foot.

  16. Retention of radium from thermal waters on sand filters and adsorbents

    Energy Technology Data Exchange (ETDEWEB)

    Elejalde, C. [Dpto. de Ingenieria Nuclear y Mecanica de Fluidos, Escuela Tecnica Superior de Ingenieria, Alameda de Urquijo s/n, 48013 Bilbao (Spain)]. E-mail:; Herranz, M. [Dpto. de Ingenieria Nuclear y Mecanica de Fluidos, Escuela Tecnica Superior de Ingenieria, Alameda de Urquijo s/n, 48013 Bilbao (Spain); Idoeta, R. [Dpto. de Ingenieria Nuclear y Mecanica de Fluidos, Escuela Tecnica Superior de Ingenieria, Alameda de Urquijo s/n, 48013 Bilbao (Spain); Legarda, F. [Dpto. de Ingenieria Nuclear y Mecanica de Fluidos, Escuela Tecnica Superior de Ingenieria, Alameda de Urquijo s/n, 48013 Bilbao (Spain); Romero, F. [Dpto. de Ingenieria Quimica y del Medio Ambiente, Escuela Tecnica Superior de Ingenieria, Alameda de Urquijo s/n, 48013 Bilbao (Spain); Baeza, A. [Dpto. de Fisica, Facultad de Veterinaria, Universidad de Extremadura, Avda. Universidad s/n, 10071 Caceres (Spain)


    This study was focussed on laboratory experiences of retention of radium from one thermal water on sand filters and adsorbents, trying to find an easy method for the elimination in drinkable waters polluted with this natural radio-nuclide. A thermal water from Cantabria (Spain) was selected for this work. Retention experiences were made with columns of 35 mm of diameter containing 15 cm layers of washed river sand or 4 cm layers of zeolite A3, passing known volumes of thermal water at flows between 4 and 40 ml/min with control of the retained radium by determining the amount in the water after the treatment. The statistical analysis of data suggests that retention depends on the flow and the volume passed through the columns. As additional adsorbents were used kaolin and a clay rich in illite. Jar-test experiences were made agitating known weights of adsorbents with the selected thermal water, with addition of flocculants and determination of radium in filtrated water after the treatment. Data suggest that retention is related to the weight of adsorbent used, but important quantities of radium seem remain in solution for higher amounts of adsorbents, according to the statistical treatment of data. The elution of retained radium from columns or adsorbents, previously used in experiences, should be the aim of a future research.

  17. Lixiviation of heavy metals of hazardous industrial wastes by means of thermostatized columns and design of a pilot plant; Lixiviacion de metales pesados de residuos industriales peligrosos por medio de columnas termostatizadas y diseno de una planta piloto

    Energy Technology Data Exchange (ETDEWEB)

    Vite T, J.; Leon, C.C. de [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico); Vite T, M.; Soto T, J.L. [IPN, SEPI, ESIME 07738 Mexico D.F. (Mexico)]. e-mail:


    purpose of this work was to evaluate the efficiency of lixiviation of heavy metals, using thermostatized columns and hazardous industrial residual wastes: those by the volume with which are generated and its high toxicity, its represent a great problem for it treatment and disposition, in this work a diagram of a pilot plant for extraction of heavy metals is included. The process and equipment were patented in United States and in Mexico. For the development of this study four thermostated columns were used that were coupled. The waste were finely milled and suspended in an aqueous pulp adding of 10 - 40gL{sup -1} of mineral acid or sodium hydroxide until reaching an interval of pH of 2,5,7 and 10. Its were used of 4-10 gL{sup -1} of a reducer agent and of 0.3-1.5 g of a surfactant agent. In some cases with this method was possible to remove until 100% of heavy metals. It was used Plasma Emission Spectroscopy to determine the concentrations of the cations in the lixiviation liquors. For studying the metallic alloys the X-ray diffraction technique was used. (Author)

  18. Monitoring the contents of six steroidal and phenolic endocrine disrupting chemicals in chicken, fish and aquaculture pond water samples using pre-column derivatization and dispersive liquid-liquid microextraction with the aid of experimental design methodology. (United States)

    Wu, Hongliang; Li, Guoliang; Liu, Shucheng; Hu, Na; Geng, Dandan; Chen, Guang; Sun, Zhiwei; Zhao, Xianen; Xia, Lian; You, Jinmao


    This research established a sensitive and efficient pre-column derivatization HPLC method based on dispersive liquid-liquid microextraction (DLLME) for the simultaneous determination of six steroidal and phenolic endocrine disrupting chemicals (EDCs). In this study, EDCs were firstly labeled by the derivatization reagent 2-(11H-benzo[a]carbazol-11-yl) ethyl carbonochloridate (BCEC-Cl) and then extracted by DLLME. The response surface methodology was employed to investigate the key parameters of pre-column derivatization and DLLME. Under the optimal conditions, a good linear relationship between the peak area and the concentration of analytes was observed with correlation coefficients of >0.9991. Limits of detection for all EDCs derivatives were achieved within the range of 0.02-0.07 μg L(-1). The proposed method has the advantages of simple operation, low consumption of organic solvent, saving time, low output limit and good selectivity. When applied to several food and water samples analysis, it demonstrated good applicability for the determination of EDCs.

  19. Uncertainty in Loading and Control of an Active Column Critical to Buckling

    Directory of Open Access Journals (Sweden)

    G.C. Enss


    Full Text Available Buckling of load-carrying column structures is an important design constraint in light-weight structures as it may result in the collapse of an entire structure. When a column is loaded by an axial compressive load equal to its individual critical buckling load, a critically stable equilibrium occurs. When loaded above its critical buckling load, the passive column may buckle. If the actual loading during usage is not fully known, stability becomes highly uncertain.

  20. Exact Stability Calculation for Timber Beams and Columns

    NARCIS (Netherlands)

    Van der Put, T.A.C.M.


    A derivation is given of simplified, exact stability design rules according to limit analysis, applied to timber beam-columns. These rules are lacking but are necessary to be able to provide real and calculable reliability as is required according to European pacts and laws. Necessary therefore are

  1. Retrofitting Of Reinforced Concrete Column by Steel Jacketing

    Directory of Open Access Journals (Sweden)

    Abhishek Jodawat


    Full Text Available Reinforced concrete structures often require strengthening to increase their capacity to sustain additional loads, due to change in use that resulted in additional live loads, deterioration of the load carrying elements, design errors, construction problems during erection, aging of structure itself or upgrading to confirm to current code requirements. These situations may require additional concrete elements or the entire concrete structure to be strengthened, repaired or retrofitted. Common methods for strengthening columns include concrete jacketing, fiber reinforced polymer (FRP jacketing and steel jacketing. All these methods have been shown to effectively increase the axial load capacity of columns. The experimental study was carried out on RC column on designed and detailed using IS 456:2000 provisions. The concrete mix design being performed after conducting numerous material test and cube test to validate expected strength as per specified grade of concrete. The trial testing conducted to estimate load at 1st crack and failure load for normal RC column with capturing displacement using dial gauges at regular load increment in UTM. The loading conditions are decided based on failure load to induce cracks in column under 85% loading of the failure one. In all fifteen specimen casted and tested with three samples for failure load estimation, three samples each for plate jacketing & angle battening system and three samples each for plate jacketing & angle battening with column preloaded to 85% of its failure load. The angle batten system proves to be better compared to full plate retrofitting in terms of load carrying capacity and enhancing confinement effect.

  2. Retention Initiatives are Employed in Academic Libraries, Although not Necessarily for this Purpose. A Review of: Strothmann, M., & Ohler, L. A. (2011. Retaining academic librarians: By chance or by design? Library Management, 32(3, 191-208. doi: 10.1108/01435121111112907

    Directory of Open Access Journals (Sweden)

    Laura Newton Miller


    Full Text Available Objective – To study methods that support retention of academic librarians.Design – Exploratory research using an online survey; non-random sample.Setting – Academic libraries, nearly all located within the U.S. (97.2%. Subjects – A total of 895 professional academic librarians.Methods – The researchers sent an online survey link to professional electronic mail lists and directly to heads of Association of Research Libraries (ARL member libraries. The 23-item survey was available from February 19, 2007, through March 9, 2007, and contained questions about the professional experience of respondents, their libraries, and their universities. Subjects were asked to identify retention activities that were currently offered at their workplaces (both library-specific and university-wide and to rate their satisfaction for each available initiative. The list contained fifteen initiatives based on the researchers’ literature review.Main Results – Almost half (46.3% of respondents were 50 or older and 7.5% under 30 years old, leaving 46.2% between the ages of 30-50 years old (although this percentage is not explicitly stated in the paper except in a table. Nearly half of the subjects were in the first ten years of their careers. 80.2% had held between one and four professional positions in their careers, and even when length of professional experience was factored out, age had no effect on the number of positions held. Most job turnover within the past three years (3 or fewer open positions was in public service, while other areas of the library (i.e., technical services, systems, and administration reported zero open positions. Only 11.3% of respondents noted that their libraries have deliberate, formal retention programs in place. Despite this, there are several library- and university-based initiatives that can be considered to help with retention. The most reported available library-based retention initiative was the provision of funding

  3. Updated systematic review identifies substantial number of retention strategies: using more strategies retains more study participants. (United States)

    Robinson, Karen A; Dinglas, Victor D; Sukrithan, Vineeth; Yalamanchilli, Ramakrishna; Mendez-Tellez, Pedro A; Dennison-Himmelfarb, Cheryl; Needham, Dale M


    The retention of participants in studies is important for the validity of research. We updated our prior systematic review (2005) to assess retention strategies for in-person follow-up in health care studies. We searched PubMed, Cumulative Index of Nursing and Allied Health Literature, Cochrane Controlled Trials Register, Cochrane Methodology Register, and Embase (August 2013) for English-language reports of studies that described retention strategies for in-person follow-up in health care studies. We abstracted each retention strategy, and two authors independently classified each retention strategy with one of the themes developed in our prior review. We identified 88 studies (67 newly identified studies), six of which were designed to compare retention strategies, whereas the remainder described retention strategies and retention rates. There were 985 strategies abstracted from the descriptive studies (617 from new studies), with a median (interquartile range) number of strategies per study of 10 (7 to 17) and a median (interquartile range) number of themes per study of 6 (4 to 7). Financial incentives were used in 47 (57%) of the descriptive studies. We classified 28% of the strategies under the theme of "contact and scheduling methods," with 83% of the identified studies using at least one strategy within this theme. The number of strategies used was positively correlated with retention rate (P = 0.027), but the number of themes was not associated with retention rate (P = 0.469). The number of studies describing retention strategies has substantially increased since our prior review. However, the lack of comparative studies and the heterogeneity in the types of strategies, participant population and study designs, prohibits synthesis to determine the types of cohort retention strategies that were most effective. However, using a larger number of retention strategies, across five or six different themes, appears to retain more study participants. Copyright

  4. Size exclusion chromatography of synthetic polymers and biopolymers on common reversed phase and hydrophilic interaction chromatography columns. (United States)

    Caltabiano, Anna M; Foley, Joe P; Barth, Howard G


    This work describes the applicability of common reversed phase and HILIC columns for size exclusion chromatography of synthetic and natural polymers. Depending on the nature of the solute and column stationary phase, a "non-retention" condition must be created with the aid of the mobile phase to achieve a unique size-based separation in isocratic mode. The various bonded phases show remarkable differences in size separations that are controlled by mobile phase conditions. Polymer-mobile phase and column-mobile phase solvation interactions determine polymer hydrodynamic volume (or solute bulkiness) and polymer-column steric interaction. Solvation interactions in turn depend on polymer, mobile phase and stationary phase polarities. Column-mobile phase solvation interactions determine the structural order of the bonded ligands that can vary from ordered (extended, aligned away from the silica substrate) to disordered (folded, pointing toward the silica substrate). Chain order increases with increased solvent penetration into the bonded phase. Increased chain order reduces pore volume, and therefore decreases the size-separation efficiency of a column. Conversely, decreased chain order increases pore volume and therefore increases the size-separation efficiency. The thermodynamic quality of the mobile phase also plays a significant role in the separation of polymers. "Poor" solvents can significantly reduce the hydrodynamic diameter of a solute and thus change their retention behavior. Medium polarity stationary phases, such as fluoro-phenyl and cyano, exhibit a unique retention behavior. With an appropriate polarity mobile phase, polar and non-polar synthetic polymers of the same molecular masses can be eluted at the same retention volumes.

  5. Education and training column: the learning collaborative. (United States)

    MacDonald-Wilson, Kim L; Nemec, Patricia B


    This column describes the key components of a learning collaborative, with examples from the experience of 1 organization. A learning collaborative is a method for management, learning, and improvement of products or processes, and is a useful approach to implementation of a new service design or approach. This description draws from published material on learning collaboratives and the authors' experiences. The learning collaborative approach offers an effective method to improve service provider skills, provide support, and structure environments to result in lasting change for people using behavioral health services. This approach is consistent with psychiatric rehabilitation principles and practices, and serves to increase the overall capacity of the mental health system by structuring a process for discovering and sharing knowledge and expertise across provider agencies. (PsycINFO Database Record (c) 2015 APA, all rights reserved).

  6. Near shore floating oscillating wave column

    Energy Technology Data Exchange (ETDEWEB)



    Three different types of floating buoys, using oscillating wave columns, have been considered for generating electric power in an Atlantic environment. The study considered the situation close to the shore, but in the ultimate it was hoped to deploy units offshore. Although other designs would have greater power capture efficiency, the Spar Buoy was studied in greatest depth as it was expected to have the edge in terms of building cost and operating economics. A risk assessment was carried out for both concrete and steel buoys. The report covers (1) history of the project development; (2) project definition; (3) power generation and sensitivities and (4) lessons learned. The study was sponsored by Great Britain's DTI.

  7. Analysis and behaviour of FRP-confined short concrete columns subjected to eccentric loading

    Institute of Scientific and Technical Information of China (English)


    Fibre-reinforced polymer (FRP) composites were widely utilized in civil engineering structures as the retrofit of reinforced concrete (RC) columns. To design FRP jackets safely and economically, the behaviour of such columns should be predicted first. This paper is concerned with the analysis and behaviour of FRP-confined RC circular and rectangular short columns subjected to eccentric loading. A simple design-oriented stress-strain model for FRP-confined concrete in a section analysis was first proposed. The accuracy was then proved by two test data. Following that, a parametric study including amount of FRP confinement, FRP strain capacity, unconfined concrete strength and shape of column section is provided. Some conclusions were obtained at the end of the paper. The work here will provide a comprehensive understanding of the behaviour of FRP-confined concrete columns. The simplicity of the model also enables a simple equivalent stress block to be developed for direct use in practical design.

  8. Particle Residence Time in Column Flotation Based on Cyclonic Separation

    Institute of Scientific and Technical Information of China (English)

    ZHOU Xiao-hua; LIU Jiong-tian


    The cyclonic static micro-bubble column flotation (FCSMC) is an effective separation device for fine particle treatment. The high mineralization rate and short flotation time of this equipment can be attributed to its unique cyclonic force field. It also has been observed that the presence of a cyclonic force field leads to a lower bottom separation size limit and a reduction of unselective entrainment. The collection zone of the column is considered to consist of two parts, a column separation zone and a cyclonic zone. Total recovery of the collection zone was developed. For our study, we analyzed the particle movement in the cyclonic zone. Particle residence time equations for the cyclonic zone were derived by force analysis. Results obtained in this study provide a theoretical foundation for the design and scale-up of the FCSMC.

  9. Uncertain Buckling Load and Reliability of Columns with Uncertain Properties

    DEFF Research Database (Denmark)

    Köylüoglu, H. U.; Nielsen, Søren R. K.; Cakmak, A. S.

    Continuous and finite element methods are utilized to determine the buckling load of columns with material and geometrical uncertainties considering deterministic, stochastic and interval models for the bending rigidity of columns. When the bending rigidity field is assumed to be deterministic......, the ordinary finite element method slightly overestimates the buckling load, and with a very few number of elements high rate of convergence to the exact results is observed. If the bending rigidity field is modelled using random fields, stochastic finite element method is utilized. The discretization...... is performed using weighted intergrals. Then, the buckling load becomes a random variable. The sensitivity of the lower order moments of the buckling load with respect to the mesh size, the correlation length and coefficient of variation of the random field are examined. The reliability of columns designed...

  10. Modified posterior vertebral column resection for Kümmell disease (United States)

    Liu, Feng-Yu; Huo, Li-Shuang; Liu, Sen; Wang, Hui; Zhang, Li-Jun; Yang, Da-Long; Ding, Wen-Yuan


    Abstract Rationale: Kümmell's disease is defined as delayed traumatic vertebral collapse disease in which patients develop a kyphosis after asymptomatic minor spinal trauma. Both anterior approach and posterior approach have been reported, however, there is no standard treatment for Kümmell's disease. Patient concerns: We described a successful modified posterior vertebral column resection in a patient with Kümmell's disease. A 65-year-old woman reported persistent back pain for almost three months. Diagnoses: Kümmell's disease was diagnosed based on computer tomography (CT) and magnetic resonance imaging (MRI). Interventions: Modified posterior vertebral column resection combined with short-segment fixation was designed to treat this disease. Outcomes: The procedure was successful without any complications. Patient reported that symptoms were obviously improved in one week after operation. Lessons: Modified posterior vertebral column resection combined with short-segment fixation is an effective treatment option for Kümmell's disease. PMID:28151882

  11. Preparation and evaluation of a novel hybrid monolithic column based on pentafluorobenzyl imidazolium bromide ionic liquid. (United States)

    Shan, Yuanhong; Qiao, Lizhen; Shi, Xianzhe; Xu, Guowang


    To develop a novel hybrid monolithic column based on pentafluorobenzyl imidazolium bromide ionic liquid, a new ionic liquid monomer was synthesized from 1-vinylimidazole and pentafluorobenzyl bromide. By employing a facile one-step copolymerization of polyhedral-oligomeric-silsesquioxane-type (POSS) cross-linking agent and the home-made ionic liquid monomer, the hybrid monolithic columns were in situ fabricated in fused-silica capillary. The morphology of monolithic column was characterized by scanning electron microscope (SEM) and the chemical composition was confirmed by Fourier-transform infrared spectroscopy (FT-IR) and elemental analysis. Excellent mechanical stability and slight swelling propensity were exhibited which was ascribed to the rigid hybrid monolithic skeleton. Reproducibility results of run-to-run, column-to-column, batch-to-batch and day-to-day were investigated and the RSDs were less than 0.46%, 1.84%, 3.96% and 3.17%, respectively. The mixed-mode retention mechanism with hydrophobic interaction, π-π stacking, ion-exchange, electrostatic interaction and dipole-dipole interaction was explored systematically using analytes with different structure types. Satisfied separation capability and column efficiency were achieved for the analysis of small molecular compounds such as alkylbenzenes, polycyclic aromatic hydrocarbons, nucleosides and halogenated compounds. Copyright © 2014 Elsevier B.V. All rights reserved.

  12. Fate of linear alkylbenzene sulfonate in agricultural soil columns during inflow of surfactant pulses (United States)

    Boluda-Botella, N.; León, V. M.; Cases, V.; Gomis, V.; Prats, D.


    The transport and reaction processes of linear alkylbenzene sulfonate (LAS) were characterised in columns of agricultural soil with a constant inflow of irrigation water. A pulse input of commercial LAS was performed with different mixtures of soil and sea sand (0/100%, 25/75% and 50/50%) and a continuous water flow of approximately 0.5 mL/min. LAS homologue retention was favoured at a higher soil rate, due mainly to higher clay and organic matter contents. C 10LAS and C 11LAS were less retained in soil columns, and were eluted faster and in higher proportion through soil columns than other homologues. C 12LAS and C 13LAS showed stronger interactions with soil due to their higher sorption capacity, and a lower proportion was eluted than the lightest homologues. In general, sorption of LAS was reversible and significant fractions were desorbed when the LAS input ceased and they were transported to deeper layers in the soil column, especially for short-chain homologues. Longer LAS homologues were eluted from soil columns, but required an elution of >10 pore-volumes. When there was biodegradation in the soil column, >25% of LAS could be removed, reducing percolation to deeper layers.

  13. Parametric study and simulation of microbubble column flotation



    A study based on a statistically designed set of experiments (Box-Behnken design) has been conducted to determine the optimum conditions for advanced physical fine coal cleaning using microbubble column flotation. The dependent variables in these experiments were mass yield and product quality (ash, sulfur and btu), while the independent variables were feed solids content, collector dosage, frother dosage, feed rate, aeration rate, and wash water rate. The most important operating parameters ...

  14. Some effects of temperature on multiple column metal oxide devices

    Energy Technology Data Exchange (ETDEWEB)

    Kresge, J.S.; Lambert, S.R.; Sakshaug, E.C. [Power Technologies, Inc., Schenectady, NY (United States); Porter, J.W. [Electric Power Research Inst., Palo Alto, CA (United States)


    Metal oxide elements are capable of dissipating considerable energy in terms of joules per cubic centimeter or joules per gram, and elements of reasonable size are capable of discharging the energy associated with most surge arrester applications. Surge arresters designed using metal oxide elements have been in service since 1976. However, a single column consisting of elements of usual diameter is not capable of discharging a long, 500-kV or 800-kV transmission line under all of the switching conditions generally considered; therefore, metal oxide arresters for application at these voltages are usually designed with two columns of elements in parallel. Furthermore, devices for series capacitors protection or protection of valves and filters in dc converter stations and similar applications are often required to discharge several tens of times more energy than required by station applications, and are hence designed using several columns of elements in parallel. The objective of this paper is to describe some of the effects of temperature on the operation of parallel multiple column devices.

  15. FRP Composites Strengthening of Concrete Columns under Various Loading Conditions

    Directory of Open Access Journals (Sweden)

    Azadeh Parvin


    Full Text Available This paper provides a review of some of the progress in the area of fiber reinforced polymers (FRP-strengthening of columns for several loading scenarios including impact load. The addition of FRP materials to upgrade deficiencies or to strengthen structural components can save lives by preventing collapse, reduce the damage to infrastructure, and the need for their costly replacement. The retrofit with FRP materials with desirable properties provides an excellent replacement for traditional materials, such as steel jacket, to strengthen the reinforced concrete structural members. Existing studies have shown that the use of FRP materials restore or improve the column original design strength for possible axial, shear, or flexure and in some cases allow the structure to carry more load than it was designed for. The paper further concludes that there is a need for additional research for the columns under impact loading senarios. The compiled information prepares the ground work for further evaluation of FRP-strengthening of columns that are deficient in design or are in serious need for repair due to additional load or deterioration.

  16. Thermal Analysis for Ion-Exchange Column System

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Si Y.; King, William D.


    Models have been developed to simulate the thermal characteristics of crystalline silicotitanate ion exchange media fully loaded with radioactive cesium either in a column configuration or distributed within a waste storage tank. This work was conducted to support the design and operation of a waste treatment process focused on treating dissolved, high-sodium salt waste solutions for the removal of specific radionuclides. The ion exchange column will be installed inside a high level waste storage tank at the Savannah River Site. After cesium loading, the ion exchange media may be transferred to the waste tank floor for interim storage. Models were used to predict temperature profiles in these areas of the system where the cesium-loaded media is expected to lead to localized regions of elevated temperature due to radiolytic decay. Normal operating conditions and accident scenarios (including loss of solution flow, inadvertent drainage, and loss of active cooling) were evaluated for the ion exchange column using bounding conditions to establish the design safety basis. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature. In-tank modeling results revealed that an idealized hemispherical mound shape leads to the highest tank floor temperatures. In contrast, even large volumes of CST distributed in a flat layer with a cylindrical shape do not result in significant floor heating.

  17. Ionic liquid-based zwitterionic organic polymer monolithic column for capillary hydrophilic interaction chromatography. (United States)

    Wang, Tingting; Chen, Yihui; Ma, Junfeng; Zhang, Xiaodan; Zhang, Lihua; Zhang, Yukui


    In the current study, a novel ionic liquid-based zwitterionic organic polymer monolithic column was developed by copolymerizing 1-vinyl-3-(butyl-4-sulfonate) imidazolium, acrylamide and N,N'-methylenebisacrylamide in a quaternary porogenic solvent consisting of formamide, dimethyl sulphoxide, polyethylene glycol 8000 and polyethylene glycol 10,000 for capillary hydrophilic interaction chromatography. The monolithic stationary phase was optimized by adjusting the amount of monomer in the polymerization solution along with the composition of porogenic solvent. The optimized monolith exhibited excellent selectivity and favorable retention for nucleosides and benzoic acid derivatives. The primary factors affecting the separation efficiency of the monolithic column (including acetonitrile content, pH, and buffer salt concentration in the mobile phase) have been thoroughly evaluated. Excellent reproducibility of the retention times for five nucleosides was achieved, with relative standard deviations of run-to-run (n = 3), column-to-column (n = 3) and batch-to-batch (n = 3) in the range of 0.18-0.48%, 2.33-4.20% and 3.07-6.50%, respectively.

  18. Comparison of monometal and multimetal adsorption in Mississippi River alluvial wetland sediment: batch and column experiments. (United States)

    Seo, Dong Cheol; Yu, Kewei; DeLaune, Ronald D


    Monometal and multimetal adsorption of selected heavy metals in a sediment from a coastal Louisiana forested swamp used for wastewater treatment was studied. Results from the batch experiments show that the maximum adsorption capacities of the metals by the sediment were in the order of Pb>Hg>Cr>CdCuZn>As based on monometal adsorption isotherm, and Hg>Cr>CuCd approximately Pb>As approximately Zn based on multimetal adsorption isotherm, respectively. Batch experimental data best fit the Langmuir model rather than the Freundlich isotherms. In the column experiments, the maximum adsorption capacities of the metals were in the order of Pb>Hg>Cr>Cd>Cu>Zn>As in monometal conditions, and Hg>Cr>Pb>CuZn approximately Cd>As in multimetal conditions. The metals became more mobile in multimetal than in monometal conditions. Results from both the batch and column experiments show that competitive adsorption among metals increases the mobility of these metals. Particularly, in this study, Pb in multimetal conditions lost it adsorption capacity most significantly. In both monometal and multimetal conditions, the maximum adsorption capacity of the metals in the column experiments was higher than that in the batch experiment indicating other metal retention mechanisms rather than adsorption may be involved. Therefore, both column and batch experiments are needed for estimating retention capacities and removal efficiencies of metals in sediments.

  19. Elastic stability of non-uniform columns (United States)

    Lee, S. Y.; Kuo, Y. H.


    A simple and efficient method is proposed to investigate the elastic stability of three different tapered columns subjected to uniformly distributed follower forces. The influences of the boundary conditions and taper ratio on critical buckling loads are investigated. The critical buckling loads of columns of rectangular cross section with constant depth and linearly varied width ( T1), constant width and linearly varied depth ( T2) and double taper ( T3) are investigated. Among the three different non-uniform columns considered, taper ratio has the greatest influence on the critical buckling load of column T3 and the lowest influence on that of column T1. The types of instability mechanisms for hinged-hinged and cantilever non-uniform columns are divergence and flutter respectively. However, for clamped-hinged and clamped-clamped non-uniform columns, the type of instability mechanism for column T1 is divergence, while that for columns T2 and T3 is divergence only when the taper ratio of the columns is greater than certain critical values and flutter for the rest value of taper ratio. When the type of instability mechanism changes from divergence to flutter, there is a finite jump for the critical buckling load. The influence of taper ratio on the elastic stability of cantilever column T3 is very sensitive for small values of the taper ratio and there also exist some discontinieties in the critical buckling loads of flutter instability. For a hinged-hinged non-uniform column ( T2 or T3) with a rotational spring at the left end of the column, when the taper ratio is less than the critical value the instability mechanism changes from divergence to flutter as the rotational spring constant is increased. For a clamped-elastically supported non-uniform column, when the taper ratio is greater than the critical value the instability mechanism changes from flutter to divergence as the translational spring constant is increased.

  20. Retentivity, selectivity and thermodynamic behavior of polycyclic aromatic hydrocarbons on charge-transfer and hypercrosslinked stationary phases under conditions of normal phase high performance liquid chromatography. (United States)

    Jiang, Ping; Lucy, Charles A


    Charge-transfer and hypercrosslinked polystyrene phases offer retention and separation for polycyclic aromatic hydrocarbons (PAHs) and thus have potential for petroleum analysis. The size, shape and planarity selectivity for PAH standards on charge-transfer (DNAP column) and hypercrosslinked polystyrene (HC-Tol and 5HGN columns) phases are different under normal phase liquid chromatography (NPLC). The HC-Tol column behaves like a conventional NPLC column with low retention of PAHs. Retention of PAHs on the DNAP and 5HGN are strong and increases with the number of aromatic rings. The main retention mechanism is through π-π interactions and dipole-induced dipole interaction. Thermodynamics indicates that the retention mechanism of PAHs remains unchanged over the temperature range 20-60°C. In addition, on either DNAP or 5HGN column, both linear and bent PAHs are retained through the same mechanism. But DNAP possesses smaller π-π interaction and higher planarity selectivity than 5HGN for PAHs. This is suggestive that DNAP interacts with PAHs through a disordered phase arrangement, while 5HGN behaves as an ordered adsorption phase.

  1. Mass transfer kinetics, band broadening and column efficiency. (United States)

    Gritti, Fabrice; Guiochon, Georges


    Important progress was recently made in our understanding of the physico-chemical aspects of mass transfer kinetics in chromatographic columns, in methods used for accurate determination of the different contributions to the height equivalent to a theoretical plate (HETP), and in the application of these advances to the elucidation of mass transfer mechanisms in columns packed with recent chromatographic supports (sub-2 μm fully porous particles, sub-3 μm core-shell particles, and monoliths). The independent contributions to the HETP are longitudinal diffusion, eddy dispersion, liquid-solid mass transfer (including trans-particle or trans-skeleton mass transfer and external film mass transfer), and the contributions caused by the thermal heterogeneity of the column. The origin and importance of these contributions are investigated in depth. This work underlines the areas in which improvements are needed, an understanding of the contribution of the external film mass transfer term, a better design of HPLC instruments providing a decrease of the extra-column band broadening contributions to the apparent HETP, the development of better packing procedures giving more radially homogeneous column beds, and new packing materials having a higher thermal conductivity to eliminate the nefarious impact of heat effects in very high pressure liquid chromatography (vHPLC) and supercritical fluid chromatography (SFC).

  2. Effect of feed characteristics on the controllability of binary distillation columns

    Energy Technology Data Exchange (ETDEWEB)

    Cantrell, J.G.; Elliott, T.R.; Luyben, W.L. [Lehigh Univ., Bethlehem, PA (United States)


    The design and control of binary distillation columns have been the focus of a great deal of industrial and academic research. However, the effect of the feed characteristics on the controllability of the column has remained unclear. This paper first examines how feed tray location affects the inherent controllability of a binary distillation column. It is shown that controllability can be significantly improved by feeding on a nonoptimum tray. The effects of feed thermal condition are also explored. Generic rules are proposed to improve the controllability of the column by changing the thermal condition of the feed.

  3. Artisan retention in an organisation in South Africa

    Directory of Open Access Journals (Sweden)

    Lariska van Rooyen


    Full Text Available Orientation: South Africa is facing a critical shortage of artisans. Therefore it is important to investigate which factors contribute to the retention of artisans by organisations.Research purpose: The objective of this study was to investigate the factors that are important for artisan retention at a South African organisation.Motivation for the study: Organisations that employ artisans need to understand what the main reasons are for keeping or losing artisans from the perspective of the artisans themselves. This information can be used to plan and implement interventions to deal with artisan retention in organisations.Research design, approach and method: A qualitative design was used and a purposive sample was taken (n = 14. A biographical questionnaire was administered and semi-structured interviews were conducted to gather data from artisans.Main findings: Remuneration had the highest rank of all the factors for the retention of artisans, closely followed by development opportunities. Other factors that were perceived as important for artisan retention included equality, recognition, management and the working environment, and working relationships.Practical implications: Organisations that employ artisans should especially attend to their remuneration and development opportunities.Contribution: The results of this study add to the knowledge of why artisans remain with a specific organisation.

  4. Dynamics and control of a heat pump assisted extractive dividing-wall column for bioethanol dehydration

    NARCIS (Netherlands)

    Patraşcu, Iulian; Bildea, Costin Sorin; Kiss, Anton A.

    Recently, a novel heat-pump-assisted extractive distillation process taking place in a dividing-wall column was proposed for bioethanol dehydration. This integrated design combines three distillation columns into a single unit that allows over 40% energy savings and low specific energy requirements

  5. Intrinsic advantages of packed capillaries over narrow-bore columns in very high-pressure gradient liquid chromatography. (United States)

    Gritti, Fabrice; McDonald, Thomas; Gilar, Martin


    250μm×100mm fused silica glass capillaries were packed with 1.8μm high-strength silica (HSS) fully porous particles. They were prepared without bulky stainless steel endfittings and metal frits, which both generate significant sample dispersion. The isocratic efficiencies and gradient peak capacities of these prototype capillary columns were measured for small molecules (n-alkanophenones) using a home-made ultra-low dispersive micro-HPLC instrument. Their resolution power was compared to that of standard 2.1mm×100mm very high-pressure liquid chromatography (vHPLC) narrow-bore columns packed with the same particles. The results show that, for the same column efficiency (25000 plates) and gradient steepness (0.04min(-1)), the peak capacity of the 250μm i.d. capillary columns is systematically 15-20% higher than that of the 2.1mm i.d. narrow-bore columns. A validated model of gradient chromatography enabled one to predict accurately the observed peak capacities of the capillary columns for non-linear solvation strength retention behavior and under isothermal conditions. Thermodynamics applied to the eluent quantified the temperature difference for the thermal gradients in both capillary and narrow-bore columns. Experimental data revealed that the gradient peak capacity is more affected by viscous heating than the column efficiency. Unlike across 2.1mm i.d. columns, the changes in eluent composition across the 250μm i.d. columns during the gradient is rapidly relaxed by transverse dispersion. The combination of (1) the absence of viscous heating and (2) the high uniformity of the eluent composition across the diameter of capillary columns explains the intrinsic advantage of capillary over narrow-bore columns in gradient vHPLC.


    Why work was done? To be able to identify, on a proteomic level, cytochromes P450 (CYP) and UDP-glucuronosyltransferases (UGT) in mouse liver microsomes for the conazole exposure study IRP # NHEERL-ECD-SCN-CZ-2002-01-R1_Addendum 1. The new enrichment method was necessary beca...

  7. Retention of proteins and metalloproteins in open tubular capillary electrochromatography with etched chemically modified columns. (United States)

    Pesek, Joseph J; Matyska, Maria T; Salgotra, Vasudha


    Etched chemically modified capillaries with two different bonded groups (pentyl and octadecyl) are compared for their migration behavior of several common proteins and metalloproteins as well as metalloproteinases. Migration times, efficiency and peak shape are evaluated over the pH range of 2.1-8.1 to determine any effects of the bonded group on the electrochromatographic behavior of these compounds. One goal was to determine if the relative hydrophobicity of the stationary phase has a significant effect on proteins in the open tubular format of capillary electrochromatography as it does in HPLC. Reproducibility of the migration times is also investigated.

  8. Retention of Proteins and Metalloproteins in Open Tubular Capillary Electrochromatography with Etched Chemically Modified Columns (United States)

    Pesek, Joseph J.; Matyska, Maria T.; Salgotra, Vasudha


    Etched chemically modified capillaries with two different bonded groups (pentyl and octadecyl) are compared for their migration behavior of several common proteins and metalloproteins as well as metalloproteinases. Migration times, efficiency and peak shape are evaluated over the pH range of 2.1 to 8.1 to determine any effects of the bonded group on the electrochromatographic behavior of these compounds. One goal was to determine if the relative hydrophobicity of the stationary phase has a significant effect on proteins in the open tubular format of capillary electrochromatography as it does in HPLC. Reproducibility of the migration times is also investigated. PMID:18850653

  9. Combination of Slag, Limestone and Sedimentary Apatite in Columns for Phosphorus Removal from Sludge Fish Farm Effluents

    Directory of Open Access Journals (Sweden)

    Florent Chazarenc


    Full Text Available Laboratory scale studies have repeatedly reported high P-retention in slag, a by-product of the steel manufacturing industry. Thus, it has emerged as a potential material to increase P-removal from constructed wetlands (CWs. However, several limitations were highlighted by field experiments, including the high pH of treated water and clogging. We hypothesized that the addition of sedimentary rocks to slag would preserve P-removal properties while reducing the pH of treated water. Four 2.5 L-columns were filled with 100% apatite (column A; a 50% weight each mixture of limestone with apatite (column B; 10% steel slag located at the inlet, plus 45% limestone mixed with 45% apatite (column C; and a mixture of steel slag (10%, limestone (45% apatite (45% (column D. A synthetic effluent (26 mg P/L and a reconstituted sludge fish farm effluent containing 97 mg/L total suspended solids (TSS, 220 mg/L chemical oxygen demand (COD and 23.5 mg P/L phosphorus (P were applied sequentially during 373 and 176 days, under saturated flow conditions and 12–24 hours hydraulic residence time (HRT, respectively. Treatment performance, P-removal, pH and calcium (Ca2+ were monitored. Results indicated that columns that contained 10% weight steel slag resulted in a higher P retention capacity than the columns without steel slag. The highest P removal was achieved in column C, containing a layer of slag in the inlet zone, 45% apatite and 45% limestone. Feeding the columns with a reconstituted fish farm effluent led to biofilm development, but this had little effect on the P-removal. A combination of slag and sedimentary rocks represents a promising filtration material that could be useful downstream of CWs to further increase P-removal.


    Energy Technology Data Exchange (ETDEWEB)

    Bernard A. Toseland


    The major technical objectives of this program are threefold: (1) to develop the design tools and a fundamental understanding of the fluid dynamics of a slurry bubble column reactor to maximize reactor productivity, (2) to develop the mathematical reactor design models and gain an understanding of the hydrodynamic fundamentals under industrially relevant process conditions, and (3) to develop an understanding of the hydrodynamics and their interaction with the chemistries occurring in the bubble column reactor. Successful completion of these objectives will permit more efficient usage of the reactor column and tighter design criteria, increase overall reactor efficiency, and ensure a design that leads to stable reactor behavior when scaling up to large-diameter reactors. Washington University's work during the reporting period involved the implementation of the automated calibration device, which will provide an advanced method of determining liquid and slurry velocities at high pressures. This new calibration device is intended to replace the original calibration setup, which depended on fishing lines and hooks to position the radioactive particle. The report submitted by Washington University contains a complete description of the new calibration device and its operation. Improvements to the calibration program are also discussed. Iowa State University utilized air-water bubble column simulations in an effort to determine the domain size needed to represent all of the flow scales in a gas-liquid column at a high superficial velocity. Ohio State's report summarizes conclusions drawn from the completion of gas injection phenomena studies, specifically with respect to the characteristics of bubbling-jetting at submerged single orifices in liquid-solid suspensions.

  11. Studies on the behavior of Reinforced Concrete Short Column subjected to fire

    Directory of Open Access Journals (Sweden)

    Aneesha Balaji


    Full Text Available The paper investigates the axial capacity of reinforced columns exposed to fire. The simplified method namely 500 °C isotherm method explained in Eurocode 2 is used to assess the capacity of the column. Finite element software ANSYS is used to perform the thermal analysis. A set of numerical studies were carried out to quantify the effect of various parameters on short columns subjected to fire. The study is performed on columns of different cross-sections to investigate the effect of eight parameters, namely the thermal boundary conditions, grades of concrete, grades of steel, types of aggregate, distribution of reinforcement on column faces, concrete cover, load eccentricity and support conditions. The fire ratings based on various failure criteria are determined, and minimum rating is accepted as design fire rating. A simplified interaction curve to predict the failure of columns under fire subjected to axial load and uniaxial moment for square cross-sections was also developed.

  12. Finding the buckling load of non-uniform columns using the iteration perturbation method

    Directory of Open Access Journals (Sweden)

    Aref Afsharfard


    Full Text Available The aim of this study is to calculate the critical load of variable inertia columns. The example studied in this paper can be used as a paradigm for other non-uniform columns. The wavelength of equivalent vibratory system is used to calculate the critical load of the trigonometrically varied inertia column. In doing so, the equilibrium equation of the column is theoretically studied using the perturbation method. Accuracy of the calculated results is evaluated by comparing the solution with numerical results. Effect of improving the initial guess on the solution accuracy is investigated. Effects of varying parameters of the trigonometrically varied inertia and the uniformly tapered columns on their stability behavior are studied. Finally, using the so-called “perfectibility” parameter, two design goals, i.e., being lightweight and being strong, are studied for the discussed columns.

  13. Seismic performance of recycled concrete-filled square steel tube columns (United States)

    Chen, Zongping; Jing, Chenggui; Xu, Jinjun; Zhang, Xianggang


    An experimental study on the seismic performance of recycled concrete-filled square steel tube (RCFST) columns is carried out. Six specimens were designed and tested under constant axial compression and cyclic lateral loading. Two parameters, replacement percentage of recycled coarse aggregate (RCA) and axial compression level, were considered in the test. Based on the experimental data, the hysteretic loops, skeleton curves, ductility, energy dissipation capacity and stiffness degradation of RCFST columns were analyzed. The test results indicate that the failure modes of RCFST columns are the local buckling of the steel tube at the bottom of the columns, and the hysteretic loops are full and their shapes are similar to normal CFST columns. Furthermore, the ductility coefficient of all specimens are close to 3.0, and the equivalent viscous damping coefficient corresponding to the ultimate lateral load ranges from 0.323 to 0.360, which demonstrates that RCFST columns exhibit remarkable seismic performance.

  14. Effect of the Silanization Conditions on Chromatographic Behavior of an Open-tubular Capillary Column Coated with a Modified Silica-gel Thin Layer


    Yusuke, Nakano; Shinya, Kitagawa; Kanji, Miyabe; Takao, Tsuda


    The performance of an open-tubular capillary column coated with a modified silica-gel thin layer was investigated, particularly concerning the effect of the silanization process on it. Although the increase in the octadecyltriethoxysilane (ODTES) concentration in the silanization process could enhance the retention factor of naphthalene, its theoretical plate number was significantly reduced (ODTES, 5 to 50%; k, 0.2 to 4.3; N, 79600 to 2600 m-1). Namely, the increase in the retention factor w...

  15. Retention Among North American HIV–infected Persons in Clinical Care, 2000–2008 (United States)

    Rebeiro, Peter; Althoff, Keri N.; Buchacz, Kate; Gill, M. John; Horberg, Michael; Krentz, Hartmut; Moore, Richard; Sterling, Timothy R.; Brooks, John T.; Gebo, Kelly A.; Hogg, Robert; Klein, Marina; Martin, Jeffrey; Mugavero, Michael; Rourke, Sean; Silverberg, Michael J.; Thorne, Jennifer; Gange, Stephen J.


    Background Retention in care is key to improving HIV outcomes. Our goal was to describe “churn” in patterns of entry, exit, and retention in HIV care in the US and Canada. Methods Adults contributing ≥1 CD4 count or HIV-1 RNA (HIV-lab) from 2000–2008 in North American Cohort Collaboration on Research and Design (NA-ACCORD) clinical cohorts were included. Incomplete retention was defined as lack of 2 HIV-labs (≥90 days apart) within 12 months, summarized by calendar year. We used beta-binomial regression models to estimate adjusted odds ratios (OR) and 95% confidence intervals (CI) of factors associated with incomplete retention. Results Among 61,438 participants, 15,360 (25%) with incomplete retention significantly differed in univariate analyses (pchurn. In addition to the programmatic and policy implications, our findings identify patient groups who may benefit from focused retention efforts. PMID:23242158

  16. Retention among North American HIV-infected persons in clinical care, 2000-2008. (United States)

    Rebeiro, Peter; Althoff, Keri N; Buchacz, Kate; Gill, John; Horberg, Michael; Krentz, Hartmut; Moore, Richard; Sterling, Timothy R; Brooks, John T; Gebo, Kelly A; Hogg, Robert; Klein, Marina; Martin, Jeffrey; Mugavero, Michael; Rourke, Sean; Silverberg, Michael J; Thorne, Jennifer; Gange, Stephen J


    Retention in care is key to improving HIV outcomes. The goal of this study was to describe 'churn' in patterns of entry, exit, and retention in HIV care in the United States and Canada. Adults contributing ≥1 CD4 count or HIV-1 RNA (HIV-lab) from 2000 to 2008 in North American AIDS Cohort Collaboration on Research and Design clinical cohorts were included. Incomplete retention was defined as lack of 2 HIV-laboratories (≥90 days apart) within 12 months, summarized by calendar year. Beta-binomial regression models were used to estimate adjusted odds ratios (OR) and 95% confidence intervals (CI) of factors associated with incomplete retention. Among 61,438 participants, 15,360 (25%) with incomplete retention significantly differed in univariate analyses (P churn. In addition to the programmatic and policy implications, the findings of this study identify patient groups who may benefit from focused retention efforts.

  17. Transport, retention, and size perturbation of graphene oxide in saturated porous media: Effects of input concentration and grain size (United States)

    Accurately predicting the fate and transport of graphene oxide (GO) in porous media is critical to assess its environmental impact. In this work, sand column experiments were conducted to determine the effect of input concentration and grain size on transport, retention, and size perturbation of GO ...

  18. Colloid Transport and Retention

    DEFF Research Database (Denmark)

    Yuan, Hao; Shapiro, Alexander


    Book Description: Colloidal science and technology is one of the fastest growing research and technology areas. This book explores the cutting edge research in colloidal science and technology that will be usefull in almost every aspect of modern society. This book has a depth of information...... related to historical prospective, synthesis, characterization, theoretical modeling and application of unique class of colloidal materials starting from colloidal gold to coated silica colloid and platinum, titania colloids. This book is unique in its design, content, providing depth of science about...... different colloidal materials and their applications in chemistry, physics, biological, medical sciences and environment. Graduate students, academic and industrial researchers and medical professionals will discover recently developed colloidal materials and their applications in many areas of human...

  19. Produced fluids separation using a coalascer column

    Energy Technology Data Exchange (ETDEWEB)

    Renouf, G.; Soveran, D.; Soveran, L. [Saskatchewan Research Council, Saskatoon, SK (Canada)


    This paper reports the results of a laboratory study in which a coalescer column was used to successfully remove water from produced heavy oil emulsions. The coalescer column is a simple, inexpensive, and environmentally friendly technology that can improve basic sediment and water values after 4 hours of settling time by about 38 per cent. The laboratory study tested the use of the column, and the effects of column length, column packing size, temperature, flow rate, demulsifier concentration, and water addition. More than 100 tests were conducted and 24 pairs of tests compared the treating effects with and without the column. The use of the coalescer column in the treatment facility resulted in a a reduction of demulsifier concentration from 250 ppm to 70 ppm, translating to an annual cost savings of $320,000 to $1,100,000 per battery. Incorporating the coalescer column also allowed operators to reduce both temperatures and demulsifier concentrations. The column also promoted faster treating. Water droplets grew by as much as 34 per cent, suggesting that treating time could be faster by 21 to 80 per cent. It was concluded that the coalescer column was very successful at improving water removal from heavy oil battery emulsions. 22 refs., 9 tabs., 7 figs.

  20. Column flotation testing at Suncor Energy Inc.

    Energy Technology Data Exchange (ETDEWEB)

    Cleyle, P.; Lee, L. [Suncor Energy Inc. Oil Sands, Fort McMurray, AB (Canada)


    The operations at Suncor's primary extraction plant were reviewed with reference to the column flotation process and the history of column flotation testing at Suncor. Tertiary bitumen recovery processes were also reviewed. In March and August 2005, an in-plant pilot scale column flotation test was conducted at Suncor's Millennium Primary Extraction plant near Fort McMurray, Alberta. The purpose was to evaluate the feasibility of using column flotation for tertiary bitumen recovery from cyclone overflow. The test was performed in a 4 ft diameter by 25 ft high column to determine the effects of column feed flow rate, froth wash water supply, and froth depth. The feed ranged from 0.14 to 3.79 wt per cent bitumen. Feed flow rate ranged from 59 to 237 USGPM. The test results indicated that wash water reduced froth mineral content. Increasing the wash water did not make any difference in mineral rejection. Although bitumen upgrading improved when the test column was operated at a deeper froth depth, the mineral content was not reduced. Both mechanical cell and flotation column tailings samples were collected in the flotation column tests. The average tailings composition for the last cell in the tertiary mechanical bank was 0.22 per cent bitumen, 12.10 per cent mineral, and 87.66 per cent water. At an average test column feed rate of 158 USGPM, the average tailings composition was 0.23 per cent bitumen, 12.13 per cent mineral, and 87.62 per cent water. It was concluded that flotation columns are capable of producing a tailings product similar to that of the tertiary mechanical bank. Therefore, it is feasible to use flotation columns as an alternative to mechanical cells. In fact, since there are no rotating parts requiring off-line maintenance work, flotation columns may be a better alternative from a maintenance and operations perspective. tabs., figs.

  1. Encouraging Enrollment and Retention of Women in Computer Science Classes. (United States)

    Sturm, Deborah; Moroh, Marsha

    Women computer science students at the College of Staten Island (CSI) in New York have a substantially higher pass rate than their male classmates; however, their enrollment and retention rates are low. During the last year and a half women on the computer science faculty at CSI developed two projects designed to increase the enrollment and…

  2. Building Bridges: Higher Degree Student Retention and Counselling Support (United States)

    Pearson, Mark


    This paper aims to contribute to the discussion on increasing retention rates in higher degree students. It presents evidence from the literature on the value of increasing counselling and mentoring care for higher degree research students. The creation of, and rationale for, a designated higher degree student counsellor-mentor role is described.…

  3. Employee retention--what can the benefits professional do? (United States)

    Ryan, C


    Employee retention, a primary concern for many firms in the current business environment, is most effectively viewed as a strategic problem, one that demands a team approach. The benefits professional should be a vital member of that team, helping to design an employment proposition that will allow an employer to attract and retain the most competitive workforce.

  4. Redundancy Effect on Retention of Vocabulary Words Using Multimedia Presentation (United States)

    Samur, Yavuz


    This study was designed to examine the effect of the redundancy principle in a multimedia presentation constructed for foreign language vocabulary learning on undergraduate students' retention. The underlying hypothesis of this study is that when the students are exposed to the material in multiple ways through animation, concurrent narration,…

  5. Redundancy Effect on Retention of Vocabulary Words Using Multimedia Presentation (United States)

    Samur, Yavuz


    This study was designed to examine the effect of the redundancy principle in a multimedia presentation constructed for foreign language vocabulary learning on undergraduate students' retention. The underlying hypothesis of this study is that when the students are exposed to the material in multiple ways through animation, concurrent narration,…

  6. "Read the Text, as if!"The Reading Retention Strategy (United States)

    Divoll, Kent; Browning, Sandra


    Students do not always read what is expected in college courses (Berry, Cook, Hill, & Stevens, 2010; Phillips & Phillips, 2007; Sikorski et al., 2002) or they read to cram for an exam or quiz (Clump, Bauer, & Bradley, 2004). The Reading Retention Strategy (RRS) is designed to motivate students to read and assist students in…

  7. Special Diabetes Program for Indians: Retention in Cardiovascular Risk Reduction (United States)

    Manson, Spero M.; Jiang, Luohua; Zhang, Lijing; Beals, Janette; Acton, Kelly J.; Roubideaux, Yvette


    Purpose: This study examined the associations between participant and site characteristics and retention in a multisite cardiovascular disease risk reduction project. Design and Methods: Data were derived from the Special Diabetes Program for Indians Healthy Heart Demonstration Project, an intervention to reduce cardiovascular risk among American…

  8. Maslow's Hierarchy and Student Retention. (United States)

    Brookman, David M.


    Abraham Maslow's hierarchy of needs offers perspective on student motivation and a rationale for college retention programing. Student affairs and faculty interventions addressing student safety needs and engaging students' sense of purpose reinforce persistence. A mentor program is a possible cooperative effort between student personnel and…

  9. Lake retention of manufactured nanoparticles

    NARCIS (Netherlands)

    Koelmans, A.A.; Quik, J.T.K.; Velzeboer, I.


    For twenty-five world lakes and three engineered nanoparticles (ENP), lake retention was calculated using a uniformly mixed lake mass balance model. This follows similar approaches traditionally used in water quality management. Lakes were selected such that lake residence times, depths and areal hy

  10. Strategies for improving employee retention. (United States)

    Verlander, Edward G; Evans, Martin R


    This article proposes a solution to the perennial problem of talent retention in the clinical laboratory. It includes the presentation of 12 strategies that may be used to significantly improve institutional identity formation and establishment of the psychological contract that employees form with laboratory management. Identity formation and psychological contracting are deemed as essential in helping reduce employee turnover and increase retention. The 12 conversational strategies may be used as a set of best practices for all employees, but most importantly for new employees, and should be implemented at the critical moment when employees first join the laboratory. This time is referred to as "retention on-boarding"--the period of induction and laboratory orientation. Retention on-boarding involves a dialogue between employees and management that is focused on the psychological, practical, cultural, and political dimensions of the laboratory. It is placed in the context of the modern clinical laboratory, which is faced with employing and managing Generation X knowledge workers. Specific topics and broad content areas of those conversations are outlined.

  11. Lake retention of manufactured nanoparticles

    NARCIS (Netherlands)

    Koelmans, A.A.; Quik, J.T.K.; Velzeboer, I.


    For twenty-five world lakes and three engineered nanoparticles (ENP), lake retention was calculated using a uniformly mixed lake mass balance model. This follows similar approaches traditionally used in water quality management. Lakes were selected such that lake residence times, depths and areal hy

  12. Institutionalization of a Retention Model (United States)

    Davis, E. J.; Campbell, A.


    Bowie State University and NASA Goddard Space Flight Center have, for the past 10 years, worked diligently together to enhance the science, mathematics, engineering and technology (SMET) domain. Efforts made, because of a Model Institutions for Excellence (MIE) Award, have changed the landscape of the SMET domain by increasing the retention and graduation rates, the number of students entering graduate and professional schools, and the number of students entering SMET related careers for minorities and women. Several initiatives a Scholarship Program, PRISEM Tutoring Center, Safety-net Program, Research emphasis, Focused Mentoring, a Summer Academy for accepted incoming students, a Bridge Program for students needing assistance being admitted to the University, the RISE Program and the Bowie State Satellite Operations and Control Center (BSOCC) provide the nurturing, mentoring, and opportunities for our students. As a result of efforts made, the retention rate has increase to approximately 80%, the graduation rate has increased 40%, and 85% of the SMET students are now interested or entering graduate and professional schools. Successes that have been documented by various assessment activities have led to the institutionalization of the Retention Model of the MIE Initiative. It is anticipated that University-wide application of the retention model will prove the incentives necessary to obtain similar results as the MIE Initiative.

  13. Maslow's Hierarchy and Student Retention. (United States)

    Brookman, David M.


    Abraham Maslow's hierarchy of needs offers perspective on student motivation and a rationale for college retention programing. Student affairs and faculty interventions addressing student safety needs and engaging students' sense of purpose reinforce persistence. A mentor program is a possible cooperative effort between student personnel and…

  14. Water Column Exploration Field Trial I (EX0904, EM302) aboard the NOAA Ship Okeanos Explorer in the Gorda Ridge, off the coasts of Oregon and California (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This cruise is a water column exploration field trial cruise, designed to test and refine operations for conducting water column exploration using NOAA Ship Okeanos...

  15. Measure and Design of the Structure of Small-Sized Experimental Deinked Pulp Flotation Column%实验用脱墨浆渣浮选柱结构设计

    Institute of Scientific and Technical Information of China (English)

    孙丽英; 李琼砚; 周皆庆; 高崇


    Since the deinked pulp flotation column has been invented for more than a century, it mainly was used in mineral processing. Hydrophobic ore can be captured when pulp and bubble contact inversely, and then form mineral foam. Ore grain shed off after miner%浮选柱自发明一百多年来,主要被应用在选矿方面,矿浆和气泡逆流接触,疏水性矿粒被捕获,附着在气泡上,形成矿化泡沫层,泡沫层被冲洗水流清洗,使进入泡沫层的脉石颗粒从泡沫层中脱落,从而达到选矿的目的。本实验利用选矿的原理进行废纸纤维回收,将浮选柱用在废纸二次纤维回收领域。介绍了实验用脱墨浆渣浮选柱的工作原理和浮选柱各部分的组成结构,并绘制浮选柱机械结构部分的三维立体图,分析了脱墨浆渣浮选柱工业化的难点。

  16. Design of Measurement System for Ram Tilt of Heavy -duty CNC Double Column Vertical Lathe%大型双柱立式车床滑枕倾斜测量系统的设计

    Institute of Scientific and Technical Information of China (English)

    李锋; 杨建国


    The online measurement system for ram tilt value of a CNC double column vertical lathe was established by visual instrument technology. High-precision eddy current sensor was used to detect the micro-offset of ram, and a PCI card with 16-bits ADC resolution was used to acquire signal. To ensure the measurement accuracy, filtering, shielding and RMS were adopted to overcome the on-site interferences.%针对某工厂大型双柱立式车床,基于数据采集卡和LabVIEW软件建立了在线监测滑枕倾斜量的虚拟仪器测量系统,并进行试验.该系统采用高精度电涡流传感器检测偏移距离,并采用滤波、均值和屏蔽等措施,有效克服了现场干扰,保证了测量的准确性.

  17. Tunable separation of anions and cations by column switching in ion chromatography. (United States)

    Amin, Muhammad; Lim, Lee Wah; Takeuchi, Toyohide


    A convenient ion chromatography method has been proposed for the routine and simple determination of anions (Cl(-), SO(4)(2-) and NO(3)(-)) and/or cations (Na(+), NH(4)(+), K(+), Mg(2+) and Ca(2+)) using a single pump, a single eluent and a single detector. The present system used cation-exchange and anion-exchange columns connected in series via two 6-port switching valves or a single 10-port valve. The connection order of the ion-exchange columns could be varied by switching the valve(s). The present system therefore allowed the separation of either cations or anions in a single chromatographic run. While one ion-exchange column is being operated, the other ion-exchange column is being conditioned, i.e., the columns are always ready for analysis at any time. When 2.4mM 5-sulfosalicylic acid was used as the eluent, the three anions and the five cations could be separated on the anion-exchange column and cation-exchange column, respectively. In order to obtain the separations of the target ions, the injection valve was placed between the two columns. Complete separations of the above anions or cations were demonstrated within 10min each. The detection limits at S/N=3 were 19-50ppb (mug/l) for cations and 10-14ppb for anions. The relative standard deviations of the analyte ions were less than 1.1, 2.9 and 2.8% for retention time, peak area and peak height, respectively. This proposed technique was applied to the determination of common anions and cations in river water samples.

  18. Conceptual analysis of single-feed heterogeneous distillation columns

    Directory of Open Access Journals (Sweden)

    Carlos Arturo Martinez Riascos


    Full Text Available Separation in heterogeneous distillation columns is attained by interaction of two liquid and one vapor phases, interaction of three phases involves complexities due to the determination of vapor-liquid-liquid equilibrium and hence, in the design of separation units. Nevertheless, the liquid-liquid equilibrium allows developing separations that may be unfeasible by vapor-liquid equilibrium. In this way, heterogeneous azeotropic distillation is a useful operation for the separation of azeotropic and close-boiling mixtures. In this work, a new methodology for evaluating the feasibility of this process is developed. This methodology is an extension of that proposed by Castillo et al. (1998 for homogeneous systems. Operation leaves for heterogeneous systems are calculated using the concept of pinch point curves in order to establish the process feasibility. Heterogeneous columns with external decanter are considered as the only heterogeneous stage (OHED: only heterogeneous external decanter. The initialization process for the column calculation requires the selection of the distillate composition using thermodynamic criteria in order to guarantee homogeneous phases within the column. A system with industrial and academic relevance was considered as case study: water-acetic acid-amyl acetate. Results show that the developed shortcut method allows evaluating process feasibility and estimating design parameters, without the use of trial and error procedures implemented, with the aid of simulation tools. 

  19. Study on a continuous heat integrated distillation column

    Energy Technology Data Exchange (ETDEWEB)

    Glenchur, T.; Govind, R.


    A novel continuous heat integrated distillation column called a concentric column has been studied using computer simulation. It is shown that a concentric column is a novel implementation of a thermodynamically reversible distillation column and has a lower energy loss than an ordinary distillation column. Their studies show that a concentric column has reduced column height, since the stripping section is configured concentrically around the rectifying section, and uses less utilities than a conventional column.

  20. Determinations of gas-liquid partition coefficients using capillary chromatographic columns. Alkanols in squalane. (United States)

    Tascon, Marcos; Romero, Lílian M; Acquaviva, Agustín; Keunchkarian, Sonia; Castells, Cecilia


    This study focused on an investigation into the experimental quantities inherent in the determination of partition coefficients from gas-liquid chromatographic measurements through the use of capillary columns. We prepared several squalane - (2,6,10,15,19,23-hexamethyltetracosane) - containing columns with very precisely known phase ratios and determined solute retention and hold-up times at 30, 40, 50 and 60°C. We calculated infinite dilution partition coefficients from the slopes of the linear regression of retention factors as a function of the reciprocal of the phase ratio by means of fundamental chromatographic equations. In order to minimize gas-solid and liquid-solid interface contributions to retention, the surface of the capillary inner wall was pretreated to guarantee a uniform coat of stationary phase. The validity of the proposed approach was first tested by estimating the partition coefficients of n-alkanes between n-pentane and n-nonane, for which compounds data from the literature were available. Then partition coefficients of sixteen aliphatic alcohols in squalane were determined at those four temperatures. We deliberately chose these highly challenging systems: alcohols in the reference paraffinic stationary phase. These solutes exhibited adsorption in the gas-liquid interface that contributed to retention. The corresponding adsorption constant values were estimated. We fully discuss here the uncertainties associated with each experimental measurement and how these fundamental determinations can be performed precisely by circumventing the main drawbacks. The proposed strategy is reliable and much simpler than the classical chromatographic method employing packed columns.

  1. SNAP-TITE Composite Column Reinforcement


    ECT Team, Purdue


    Recent earthquakes throughout the world have demonstrated the vulnerabilities of older reinforced concrete columns to seismic deformation demands. The Snap Tite Composite Column Reinforcement strengthens a concrete column by confining it in an external composite jacket, which prevents the concrete from expanding during seismic activity or prolonged freeze-thaw cycles. The pre-manufactured fiberglass jacket is comprised of glass fibers and corrosion resistant isopolyester resins.

  2. Parametric resonance in concrete beam-columns


    Sharma,Mamta R.; Singh,Arbind K; Benipal,Gurmail S


    A dynamic instability, called parametric resonance, is exhibited by undampedelastic beam-columns when under the action of pulsating axial force. The scope of the existing theory of parametric resonance is restricted to physically linear beam-columns undergoing finite lateral displacements. In this Paper, the dynamic behaviour of physically nonlinear elastic cracked concrete beam-columns under pulsating axial force and constant lateral force is investigated. The constitutive equations derived ...

  3. Experimental research on fire resistance of circular steel tube column filled with steel-reinforced high-strength concrete



    Circular steel tube filled with steel-reinforced high-strength concrete is a new model of composite column design.The fire resistance of this composite column was investigated experimentally.One circular steel tube column filled with steel-reinforced high-strength concrete and one circular steel tube column filled with high- strength concrete were tested under axial load and fire.The test results show that the axial deformations of both kinds of the composite columns under the same load level...

  4. Porous media augmented with biochar for the retention of E. coli (United States)

    Kolotouros, Christos A.; Manariotis, Ioannis D.; Karapanagioti, Hrissi K.


    A significant number of epidemic outbreaks has been attributed to waterborne fecal-borne pathogenic microorganisms from contaminated ground water. The transport of pathogenic microorganisms in groundwater is controlled by physical and chemical soil properties like soil structure, texture, percent water saturation, soil ionic strength, pore-size distribution, soil and solution pH, soil surface charge, and concentration of organic carbon in solution. Biochar can increase soil productivity by improving both chemical and physical soil properties. The mixing of biochar into soils may stimulate microbial population and activate dormant soil microorganisms. Furthermore, the application of biochar into soil affects the mobility of microorganisms by altering the physical and chemical properties of the soil, and by retaining the microorganisms on the biochar surface. The aim of this study was to investigate the effect of biochar mixing into soil on the transport of Escherichia coli in saturated porous media. Initially, batch experiments were conducted at two different ionic strengths (1 and 150 mM KCl) and at varying E. coli concentrations in order to evaluate the retention of E. coli on biochar in aqueous solutions. Kinetic analysis was conducted, and three isotherm models were employed to analyze the experimental data. Column experiments were also conducted in saturated sand columns augmented with different biochar contents, in order to examine the effect of biochar on the retention of E. coli. The Langmuir model fitted better the retention experimental data, compared to Freundlich and Tempkin models. The retention of E. coli was enhanced at lower ionic strength. Finally, biochar-augmented sand columns were more capable in retaining E. coli than pure sand columns.

  5. Potential possibilities of water retention in agricultural loess catchments

    Directory of Open Access Journals (Sweden)

    Zubala Tomasz


    Full Text Available The growing water deficit and the increased demand for water, as well as economic problems and inadequate spatial planning in many regions indicate a necessity of developing more effective rules of programming and realisation of works concerning the water management in small catchments. The paper presents a sample analysis of the possibilities of increasing water retention in the agricultural loess catchments with periodic streams. The scope of the study included the determination of physical parameters of selected sub-catchments (geometry, soil cover, land use, etc. and of the sources of threat to water resources, resulting from construction and geomorphological conditions. Pre-design assumptions of dammings were developed, taking into account anti-erosion protective measures, and treatments increasing the landscape retention of water were proposed. Creating surface retention objects should be an important source of water in simplified agroecosystems, especially in regions, where productivity to a great extent depends on natural weather conditions. Proper management of the fourth-order loess basin of the Ciemięga River (area of about 150 km2, the presence of 50 lateral valleys could give a temporary reservoir retention reaching 500 thousand m3. Farmers should be encouraged to seek “own water sources” (including the accumulation of water within wasteland, using appropriate economic instruments (tax reliefs for the documented volume of retained water, e.g. in small retention reservoirs.

  6. 5 CFR 351.404 - Retention register. (United States)


    ... FORCE Scope of Competition § 351.404 Retention register. (a) When a competing employee is to be released from a competitive level under this part, the agency shall establish a separate retention register for... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Retention register. 351.404 Section 351...

  7. Sedimentation retention basin utilization for best management practice

    Institute of Scientific and Technical Information of China (English)

    Zaheer Iqbal; CUI Guang-bo; ZHANG Li-qiong


    Approaches to the artificial impoundment and theoretical design of sedimentation retention basin are reviewed with particular attention to best management practice(BMP) to control agriculture and surface runoff. Sediments retention basins are the small version of farm pond used where a criteria of farm pond is not met. Such basin traps the pollutants and suspended solids prior to entry into streams and lakes. The study is focused with special reference to the assessment and control of non-point source pollution(NPSP) from the sub-basin area of Tai Lake in the Xishan County of Wuxi City of China. The author suggested two different approaches to conduct this study including theoretical design for sedimentation retention basin and computation of flow, sediment transport and deposition during the artificial impoundment of retention basin for BMP's utilization. Theoretical design will provide a useful function as a first line defense against the movement of sediments and transport of pollutants into the Tai Lake while the assessment of sediments deposition will help to make its proper use and periodic cleanup.

  8. A data-driven framework for investigating customer retention


    Mgbemena, Chidozie Simon


    This thesis was submitted for the degree of Doctor of Philosophy and awarded by Brunel University London. This study presents a data-driven simulation framework in order to understand customer behaviour and therefore improve customer retention. The overarching system design methodology used for this study is aligned with the design science paradigm. The Social Media Domain Analysis (SoMeDoA) approach is adopted and evaluated to build a model on the determinants of customer satisfaction ...

  9. Retention behavior of selected alkaloids in Reversed Phase micellar chromatographic systems

    Directory of Open Access Journals (Sweden)

    Petruczynik Anna


    Full Text Available In this work, the effects of sodium dodecyl sulfate (SDS concentrations on retention, separation selectivity, peak shapes and systems efficiency were investigated. Herein, the retention data for 11 alkaloids were determined on an RP18 silica column with mobile phases containing methanol as organic modifier, with acetate buffer at pH 3.5, and, subsequently, with the addition of sodium dodecyl sulfate (SDS. The results of this study indicate that the retention of alkaloids decreases with the increase of SDS concentration in the mobile phase. The increase of SDS concentration, however, leads to the significantly improvement of peak symmetry and the increase of theoretical plate number in all cases. The best system efficiency for most of the investigated alkaloids was obtained in a mobile phase containing 0.1 M SDS, while most symmetrical peaks were obtained through the addition of 0.3 M of SDS to the mobile phase.

  10. Retention of Root Canal Posts

    DEFF Research Database (Denmark)

    Sahafi, A; Benetti, Ana Raquel; Flury, S;


    The aim of this study was to investigate the effect of the cement film thickness of a zinc phosphate or a resin cement on retention of untreated and pretreated root canal posts. Prefabricated zirconia posts (CosmoPost: 1.4 mm) and two types of luting cements (a zinc phosphate cement [DeTrey Zinc......] and a self-etch adhesive resin cement [Panavia F2.0]) were used. After removal of the crowns of 360 extracted premolars, canines, or incisors, the root canals were prepared with a parallel-sided drill system to three different final diameters. Half the posts did not receive any pretreatment. The other half...... received tribochemical silicate coating according to the manufacturer's instructions. Posts were then luted in the prepared root canals (n=30 per group). Following water storage at 37°C for seven days, retention of the posts was determined by the pull-out method. Irrespective of the luting cement...

  11. Cyclic performance and simplified pushover analyses of precast segmental concrete bridge columns with circular section (United States)

    Bu, Zhanyu; Guo, Jian; Zheng, Rongyue; Song, Jianwei; Lee, George C.


    In recent years, precast segmental concrete bridge columns became prevalent because of the benefits of accelerated construction, low environmental impact, high quality and low life cycle costs. The lack of a detailed configuration and appropriate design procedure to ensure a comparable performance with monolithic construction has impeded this structural system from being widely used in areas of high seismicity. In this study, precast segmental bridge column cyclic loading tests were conducted to investigate the performance of unbonded post-tensioned segmental bridge columns. One monolithic and two precast segmental columns were tested. The precast segmental column exhibited minor damage and small residual displacement after the maximum 7% cyclic drift; energy dissipation (ED) can be enhanced byadding ED bars. The experimental results were modeled by a simplified pushover method (SPOM), as well as a fiber model (FIBM) finite element method. Forty-five cases of columns with different aspect ratios, axial load ratios and ED bar ratios were analyzed with the SPOM and FIBM, respectively. Using these parametric results, a simplified design method was suggested by regressive analysis. Satisfactory correlation was found between the experimental results and the simplified design method for precast segmental columns with different design parameters.

  12. Column: Factors Affecting Data Decay

    Directory of Open Access Journals (Sweden)

    Kevin Fairbanks


    Full Text Available In nuclear physics, the phrase decay rate is used to denote the rate that atoms and other particles spontaneously decompose. Uranium-235 famously decays into a variety of daughter isotopes including Thorium and Neptunium, which themselves decay to others. Decay rates are widely observed and wildly different depending on many factors, both internal and external. U-235 has a half-life of 703,800,000 years, for example, while free neutrons have a half-life of 611 seconds and neutrons in an atomic nucleus are stable.We posit that data in computer systems also experiences some kind of statistical decay process and thus also has a discernible decay rate. Like atomic decay, data decay fluctuates wildly. But unlike atomic decay, data decay rates are the result of so many different interplaying processes that we currently do not understand them well enough to come up with quantifiable numbers. Nevertheless, we believe that it is useful to discuss some of the factors that impact the data decay rate, for these factors frequently determine whether useful data about a subject can be recovered by forensic investigation.(see PDF for full column

  13. Cr(VI) retention and transport through Fe(III)-coated natural zeolite. (United States)

    Du, Gaoxiang; Li, Zhaohui; Liao, Libing; Hanson, Renee; Leick, Samantha; Hoeppner, Nicole; Jiang, Wei-Teh


    Cr(VI) is a group A chemical based on the weight of evidence of carcinogenicity. Its transport and retention in soils and groundwater have been studied extensively. Zeolite is a major component in deposits originated from volcanic ash and tuff after alteration. In this study, zeolite aggregates with the particle size of 1.4-2.4mm were preloaded with Fe(III). The influence of present Fe(III) on Cr(VI) retention by and transport through zeolite was studied under batch and column experiments. The added Fe(III) resulted in an enhanced Cr(VI) retention by the zeolite with a capacity of 82mg/kg. The Cr(VI) adsorption on Fe(III)-zeolite followed a pseudo-second order kinetically and the Freundlich adsorption isotherm thermodynamically. Fitting the column experimental data to HYDRUS-1D resulted in a retardation factor of 3 in comparison to 5 calculated from batch tests at an initial Cr(VI) concentration of 3mg/L. The results from this study showed that enhanced adsorption and retention of Cr(VI) may happen in soils derived from volcanic ash and tuff that contains significant amounts of zeolite with extensive Fe(III) coating. Copyright © 2012 Elsevier B.V. All rights reserved.

  14. Stud Reinforcement in Beam-Column Joints under Seismic Loads (United States)

    Ibrahim, Hatem Hassan Ali

    Current codes recommend large amounts of shear reinforcement for reinforced concrete beam-column joints causing significant congestion. This research aims at investigating experimentally and numerically the efficiency of using studs with a head at each end in lieu of conventional closed hoops in reinforced concrete beam-column joints. The proposed reinforcement reduces congestion and ensures easier assembly of the reinforcing cage, saving labour cost and enhancing performance of the joint. Based on this research, a recommended arrangement and detailing of headed studs and their design for exterior beam-column joint are presented. The experimental investigation consisted of testing ten full-scale beam-column joint specimens under quasi-static cyclic loading. The specimens represented an exterior beam-column joint subassembly isolated at the points of contra-flexure from a typical multi-storey, multi-bay reinforced concrete frame. A test setup was developed to simulate the lateral inter-storey drift. The test parameters included: the type, arrangement and amount of shear reinforcement, the load history and rate of loading, and the amount of reinforcement for out-of-plane confinement of the joint. Envelopes of the hysteretic behaviour of the specimens and the joint deformation under shear stress are presented. The stiffness degradation, the strain levels in the joint reinforcement, the contribution of joint, beam, and column to the inter-storey drift, and the energy dissipation were compared. All the test specimens reinforced with headed studs in the joint achieved considerable enhancement in their behaviour under cyclic loads and exhibited a performance close to that of a joint reinforced with closed hoops and cross ties according to the code. All the specimens with adequate out-of-plane confinement had an equivalent behaviour compared with the code-based specimen and achieved a desirable mode of failure. Use of double-headed studs proved to be a viable option for

  15. Rapid and simultaneous determination of imidazolium and pyridinium ionic liquid cations by ion-pair chromatography using a monolithic column

    Institute of Scientific and Technical Information of China (English)

    Xu Huang; Hong Yu; Ying Jie Dong


    A method for rapid and simultaneous determination of imidazolium and pyridinium ionic liquid cations by ion-pair chromatography with ultraviolet detection was developed.Chromatographic separations were performed on a reversed-phase silica-based monolithic column using 1-heptanesulfonic acid sodium-acetonitrile as mobile phase.The effects of ion-pair reagent and acetonitrile concentration on retention of the cations were investigated.The retention times of the cations accord with carbon number rule.The method has been successfully applied to the determination of four ionic liquids synthesized by organic chemistry laboratory.

  16. Prediction of peptide retention times in high-pressure liquid chromatography on the basis of amino acid composition. (United States)

    Meek, J L


    Analysis of peptides by reverse-phase high-pressure liquid chromatography would be simplified if retention times could be predicted by summing the contribution to retention of each of the peptide's amino acid side chains. This paper describes the derivation of values ("retention coefficients") that represent the contribution to retention of each of the common amino acids and end groups. Peptide retention times were determined on a Bio-Rad "ODS" column at room temperature with a linear gradient from 0.1 M NaclO(4), pH 7.4 or 2.1, at 0 min to 60% acetonitrile/0.1 M NaclO(4) at 80 min. The NaclO(4), a chaotropic agent, was added to improve peak shape and to minimize conformational effects. Retention coefficients for the amino acids were computed by using a Hewlett-Packard 9815A calculator programmed to change the retention coefficients for all amino acids sequentially to obtain a maximum correlation between actual and predicted retention times. Correlations of 0.999 at pH 7.4 and 0.997 at pH 2.1 were obtained for 25 peptides including glucagon, oxytocin, [Met]enkephalin, neurotensin, and somatostatin. This high degree of correlation suggests that, for peptides containing up to 20 residues, retention is primarily due to partition processes that involve all the residues. Although steric or conformational factors do have some effect on retention, the data suggest that under the above chromatographic conditions the retention of peptides containing up to 20 residues can be predicted solely on the basis of their amino acid composition. This possibility was tested by using data taken from the literature.

  17. Experimental Study on CFRP Strengthened Cold Formed Channel Columns

    Directory of Open Access Journals (Sweden)

    Sreedhar Kalavagunta


    Full Text Available Cold-formed steel members usually display local-global buckling interaction which strongly effects the structural strength of columns. Through strengthening web of the members this buckling can be controlled to some extent. In this investigation, Carbon Fibre Reinforced Polymers (CFRP is used for strengthening cold formed steel channel member. This paper presents compression tests of cold-formed plain and CFRP strengthened steel channel section columns. This paper also proposes a design method based on Direct Strength Method provisions specified in American Iron and Steel Institute (AISI, for determining the axial compression strength. Results obtained from the proposed design method are compared with experimental test data and are found to be in good agreement.

  18. Rasch models with exchangeable rows and columns

    DEFF Research Database (Denmark)

    Lauritzen, Steffen Lilholt

    The article studies distributions of doubly infinite binary matrices with exchangeable rows and columns which satify the further property that the probability of any $m \\times n$ submatrix is a function of the row- and column sums of that matrix. We show that any such distribution is a (unique...... of existence of measures with given marginals....

  19. Circulation in gas-slurry column reactors

    Energy Technology Data Exchange (ETDEWEB)

    Clark, N.; Kuhlman, J.; Celik, I.; Gross, R.; Nebiolo, E.; Wang, Yi-Zun.


    Circulation in bubble columns, such as those used in fischer-tropsch synthesis, detracts from their performance in that gas is carried on average more rapidly through the column, and the residence time distribution of the gas in the column is widened. Both of these factors influence mass-transfer operations in bubble columns. Circulation prediction and measurement has been undertaken using probes, one-dimensional models, laser Doppler velocimetry, and numerical modeling. Local void fraction was measured using resistance probes and a newly developed approach to determining air/water threshold voltage for the probe. A tall column of eight inch diameter was constructed of Plexiglas and the distributor plate was manufactured to distribute air evenly through the base of the column. Data were gathered throughout the volume at three different gas throughputs. Bubble velocities proved difficult to measure using twin probes with cross-correlation because of radial bubble movement. A series of three-dimensional mean and RMS bubble and liquid velocity measurements were also obtained for a turbulent flow in a laboratory model of a bubble column. These measurements have been made using a three-component laser Doppler velocimeter (LDV), to determine velocity distributions non-intrusively. Finally, the gas-liquid flow inside a vertically situated circular isothermal column reactor was simulated numerically. 74 refs., 170 figs., 5 tabs.

  20. Simultaneous determination of peroxydisulfate and conventional inorganic anions by ion chromatography with the column-switching technique. (United States)

    Huang, Zhongping; Ni, Chengzhu; Wang, Fengli; Zhu, Zuoyi; Subhani, Qamar; Wang, Muhua; Zhu, Yan


    The application of ion chromatography with the column-switching technique for the simultaneous analysis of peroxydisulfate and conventional inorganic anions in a single run is described. With this method, conventional inorganic anions were separated by consecutive elution through both the guard column and separation column, but peroxydisulfate that only passed through the guard column had a good peak shape and short retention time. A series of standard solutions consisting of target anions of various concentrations from 0.01 to 75 mg/L were analyzed, with a correlation coefficient (r) ≥ 0.9990. The limits of detection were in the range of 0.49-9.84 μg/L based on the S/N of 3 and a 25 μL injection volume. RSDs for retention time, peak area, and peak height were all <1.77%. A spiking study was performed with satisfactory recoveries between 97.6 and 103.4% for all anions. The quantitative determination of peroxydisulfate and conventional inorganic anions in surface waters was accomplished within 18 min by this column-switching technique.

  1. Terazosin versus alfuzosin in treatment of acute urinary retention in patients with benign prostatic hypertrophy

    National Research Council Canada - National Science Library

    Tang, HN; Lui, CT; Tsui, KL; Fung, HT


    Objective: To compare the efficacy and adverse reactions of terazosin and alfuzosin in treatment of acute urinary retention in patients with benign prostatic hypertrophy. Design: Case control study. Setting...

  2. Improved Rock Core Sample Break-off, Retention and Ejection System Project (United States)

    National Aeronautics and Space Administration — The proposed effort advances the design of an innovative core sampling and acquisition system with improved core break-off, retention and ejection features. Phase 1...

  3. Improved Rock Core Sample Break-off, Retention and Ejection System Project (United States)

    National Aeronautics and Space Administration — The proposed effort advances the design of an innovative core sampling and acquisition system with improved core break-off, retention and ejection features. The...

  4. Power Plant Emission Monitoring in Munich Using Differential Column Measurements (United States)

    Chen, Jia; Nguyen, Hai; Toja-Silva, Francisco; Heinle, Ludwig; Hase, Frank; Butz, André


    Differential column measurements using compact Fourier transform spectrometers (EM27/SUN) have shown to be an effective method to determine the greenhouse gas emissions. Citywide measurement campaigns were carried out in Boston, Indianapolis, San Francisco, etc., focusing on city (e.g. emissions from natural gas infrastructure) and local sources. We are particularly working on validating this novel method for attributing and quantifying local emission sources. Optimal strategies are developed for measuring in different seasons with various sun elevations. We have deployed two spectrometers to monitor the CO2 and CH4 emission rates (kg s-1) of a natural gas fired combined heat-and-power plant in Munich, Germany (Heizkraftwerk Süd). We placed our spectrometers in the vicinity (differential column measurements for determining power plant emissions and explore their sensitivities to meteorological and model parameters. In addition, we present measurement strategies and experimental design criteria for different meteorological conditions and time of the year, including winter when the sun elevation is low and the column inclination becomes very important. Differential column measurements using compact spectrometers are shown to be a reliable method to monitor power plant emissions.

  5. Failure mode classification of reinforced concrete column using Fisher method

    Institute of Scientific and Technical Information of China (English)

    戚永乐; 韩小雷; 季静


    In order to apply the performance-based seismic design, an engineer must first find out whether the column is expected to fail in shear before or after flexural yielding. According to column failure characteristics and failure mode of reinforced concrete column, the UW-PEER structure performance database was discussed and analyzed. In order to investigate the relevance of failure mode and factors such as longitudinal reinforcement ratio, transverse reinforcement ratio, hoop spacing to depth ratio, aspect ratio, shearing resistance demand to shear capacity ratio and axial load ratio, Fisher’s discriminant analysis(FDA) of the above factors was carried out. A discriminant function was developed to identify column failure mode. Results show that three factors, i.e., Vp /Vn, hoop spacing to depth ratio and aspect ratio have important influence on the failure mode. The failure mode has less to do with longitudinal reinforcement ratio, transverse reinforcement ratio and axial load ratio. Through using these three factors and the model proposed, over 85.6% of the original grouped cases were correctly classified. The value of coefficient of Vp /Vn is the largest, which means that discriminant equation is most sensitive to the shearing resistance demand to shear capacity ratio.

  6. Bubble Size Distribution in a Vibrating Bubble Column (United States)

    Mohagheghian, Shahrouz; Wilson, Trevor; Valenzuela, Bret; Hinds, Tyler; Moseni, Kevin; Elbing, Brian


    While vibrating bubble columns have increased the mass transfer between phases, a universal scaling law remains elusive. Attempts to predict mass transfer rates in large industrial scale applications by extrapolating laboratory scale models have failed. In a stationary bubble column, mass transfer is a function of phase interfacial area (PIA), while PIA is determined based on the bubble size distribution (BSD). On the other hand, BSD is influenced by the injection characteristics and liquid phase dynamics and properties. Vibration modifies the BSD by impacting the gas and gas-liquid dynamics. This work uses a vibrating cylindrical bubble column to investigate the effect of gas injection and vibration characteristics on the BSD. The bubble column has a 10 cm diameter and was filled with water to a depth of 90 cm above the tip of the orifice tube injector. BSD was measured using high-speed imaging to determine the projected area of individual bubbles, which the nominal bubble diameter was then calculated assuming spherical bubbles. The BSD dependence on the distance from the injector, injector design (1.6 and 0.8 mm ID), air flow rates (0.5 to 5 lit/min), and vibration conditions (stationary and vibration conditions varying amplitude and frequency) will be presented. In addition to mean data, higher order statistics will also be provided.

  7. Numerical Evaluation on the Different Shapes of Gravelly Sand Columns to Increase the Loading Capacity of Soft Clay

    Directory of Open Access Journals (Sweden)

    Meghzili Sif Allah


    Full Text Available Improvement on soft clay by the installation of stone column is one of the most popular methods followed worldwide. Different analytical and numerical solutions have already been developed for understanding the load transfer mechanism of soft soil reinforced with stone column. This study investigated a bearing capacity of the gravelly sand column, installed in soft clay bed at 15kpa of undrained shear strength. The column variable of length and diameter ratio at 7, 8 and 9 were evaluated. On top of that, the combination of two diameters in single column was tested and the uniform diameter was used as a control. In the numerical analysis, Mohrcoulomb model was adopted in the idealization of the behaviour of the gravelly sand column and soft clay materials. The results revealed that the optimum design that gave the highest loading capacity of the combination 11=12 of column diameter was the length and diameter ratio of 8.

  8. Design and Application of a New Recoil Water Device for the Dense Fixed-bed Ion-exchange Column in Uranium Hydrometallurgy%铀水冶密实固定床离子交换塔新型反冲出水装置的研制

    Institute of Scientific and Technical Information of China (English)

    雷林; 丁德馨; 雷泽勇


    A new recoil water device was designed and processed after analysing the existing problem of the installation now using the dense fixed-bed ion-exchange column in uranium hydrometallurgy,which can reduce pressure in container effectively and decrease the leakage and the breakage rate of resin.%通过对现有铀水冶密实固定床离子交换塔的反冲出水装置所存在的问题进行分析,提出一种新型反冲出水装置,可有效降低塔内和反冲出水装置所承受压力,达到减少装置泄漏和树脂破损率的目的.

  9. Effects on nurse retention. An experiment with scheduling. (United States)

    Choi, T; Jameson, H; Brekke, M L; Podratz, R O; Mundahl, H


    Four randomly selected nursing groups were assigned to three experimental groups and one control group to test the relative impact of three experimental nursing schedules, using a before-after design. The three experimental treatments were straight shifts; regular schedule but with unlimited requests for changes; and individual station-designed schedules. Before treatment, score differences between the experimental and control groups were limited to one of 36 highly reliable scales specifically constructed and pretested to gauge effects of scheduling. This single difference was judged not to be significantly related to experimental outcomes. Because of a poor job market situation, retention was not affected significantly by any of the three treatments, but root causes of turnover were. Results of the experiment showed that individual station-designed schedules triggered the most changes that favor retention. In contrast, the other two treatments unexpectedly increased nurses' own sense of marketability and reduced teamwork among nurses. Reasons accounting for the results are discussed in the text.

  10. Prediction of Peak Shape and Characterization of Column Performance in Liquid Chromatography as a Function of Flow Rate

    Directory of Open Access Journals (Sweden)

    Juan José Baeza-Baeza


    Full Text Available Traditionally, column performance in liquid chromatography has been studied using information from the elution of probe compounds at different flow rates through van Deemter plots, which relate the column plate height to the linear mobile phase velocity. A more recent approach to characterize columns is the representation of the peak widths (or the right and left peak half-widths for a set of compounds versus their retention times, which, for isocratic elution, give rise to almost linear plots. In previous work, these plots have been shown to facilitate the prediction of peak profiles (width and asymmetry with optimization purposes. In this work, a detailed study on the dependence of the peak widths (or half-widths on the flow rate is reported. A new approach to quantify the deterioration of column performance for slow and fast flow rates and to characterize chromatographic columns is proposed. The approach makes use of the width (or half-widths for a set of compounds with similar interaction kinetics and does not require knowledge of the extra-column contributions to the total variance. The chromatographic data of two sets of compounds of different natures (sulfonamides and β-blockers, eluted from Spherisorb and Chromolith columns with acetonitrile-water mixtures, are used to illustrate the approach.

  11. Stability analysis of large diameter thin-walled tube beam-columns

    Institute of Scientific and Technical Information of China (English)


    Based on a blind spot in the current design standard of steel structures,the large diameter thin-walled tube beam-columns are analyzed using nonlinear finite element method in this paper.The influence of several factors on stability capacity of the large diameter thinwalled tube beam-columns is taken into account.Thus,according to the correlative design standard of steel structures,and on the basis of the numerical analytical results by the finite element methods,the calculation formulas of the stability bearing capacity are presented for beam-column members of the large diameter thin-walled tubes.Three tests of thin-walled steel tube beam-columns were reported.Test results for deformations and ultimate strength are found to be in a good agreement with the corresponding values predicted by the calculation formulas,and the proposed methods can be used in design practice.

  12. Arsenic retention and transport behavior in the presence of typical anionic and nonionic surfactants. (United States)

    Liang, Chuan; Wang, Xianliang; Peng, Xianjia


    The massive production and wide use of surfactants have resulted in a large amount of surfactant residuals being discharged into the environment, which could have an impact on arsenic behavior. In the present study, the influence of the anionic surfactant sodium dodecyl benzene sulfonate (SDBS) and nonionic surfactant polyethylene glycol octylphenyl ether (Triton X-100) on arsenic behavior was investigated in batch and column tests. The presence of SDBS and Triton X-100 reduced arsenic retention onto ferrihydrite (FH), enhanced arsenic transport through FH coated sand (FH-sand) columns and promoted arsenic release from the FH surface. With coexisting surfactants in solution, the equilibrium adsorbed amount of arsenic on FH decreased by up to 29.7% and the adsorption rate decreased by up to 52.3%. Pre-coating with surfactants caused a decrease in the adsorbed amount and adsorption rate of arsenic by up to 15.1% and 58.3%, respectively. Because of the adsorption attenuation caused by surfactants, breakthrough of As(V) and As(III) with SDBS in columns packed with FH-sand was 23.8% and 14.3% faster than that in those without SDBS, respectively. In columns packed with SDBS-coated FH-sand, transport of arsenic was enhanced to a greater extent. Breakthrough of As(V) and As(III) was 52.4% and 43.8% faster and the cumulative retention amount was 44.5% and 57.3% less than that in pure FH-sand column systems, respectively. Mobilization of arsenic by surfactants increased with the increase of the initial adsorbed amount of arsenic. The cumulative release amount of As(V) and As(III) from the packed column reached 10.8% and 36.0%, respectively.

  13. E-beam exposure system using multi column cell (MCC) with CP for mask writing (United States)

    Yamada, Akio; Yasuda, Hiroshi; Yamabe, Masaki


    In the Mask D2I project at ASET, the authors designed a novel electron beam exposure system using the concepts of MCC (multi column cell), CP (character projection), and VSB (variable shaped beam) to improve the throughput of electron beam exposure systems. They presented outlines of a proof-of-concept system of MCC, and have shown the performances of VSB and CP in the system. They evaluated the impacts on beam position in one column cell caused by deflections in another column cell. The impacts were found to be less than 0.1nm in presence of major deflections in the neighboring column cell. Hence it was concluded that there was no noticeable impact on deflections cause by the neighboring column cells in the MCC system.

  14. Temperature of Steel Columns under Natural Fire

    Directory of Open Access Journals (Sweden)

    F. Wald


    Full Text Available Current fire design models for time-temperature development within structural elements as well as for structural behaviour are based on isolated member tests subjected to standard fire regimes, which serve as a reference heating, but do not model natural fire. Only tests on a real structure under a natural fire can evaluate future models of the temperature developments in a fire compartment, of the transfer of heat into the structure and of the overall structural behaviour under fire.To study overall structural behaviour, a research project was conducted on an eight storey steel frame building at the  Cardington Building Research Establishment laboratory on January 16, 2003. A fire compartment 11×7 m was prepared on the fourth floor. A fire load of 40 kg/m2 was applied with 100 % permanent mechanical load and 65 % of imposed load. The paper summarises the experimental programme and shows the temperature development of the gas in the fire compartment and of the fire protected columns bearing the unprotected floors.

  15. Highly efficient capillary columns packed with superficially porous particles via sequential column packing. (United States)

    Treadway, James W; Wyndham, Kevin D; Jorgenson, James W


    Highly efficient capillary columns packed with superficially porous particles were created for use in ultrahigh pressure liquid chromatography. Superficially porous particles around 1.5μm in diameter were packed into fused silica capillary columns with 30, 50, and 75μm internal diameters. To create the columns, several capillary columns were serially packed from the same slurry, with packing progress plots being generated to follow the packing of each column. Characterization of these columns using hydroquinone yielded calculated minimum reduced plate heights as low as 1.24 for the most efficient 30μm internal diameter column, corresponding to over 500,000plates/m. At least one highly efficient column (minimum reduced plate height less than 2) was created for all three of the investigated column inner diameters, with the smallest diameter columns having the highest efficiency. This study proves that highly efficient capillary columns can be created using superficially porous particles and shows the efficiency potential of these particles.

  16. Using the hydrophobic subtraction model to choose orthogonal columns for online comprehensive two-dimensional liquid chromatography

    DEFF Research Database (Denmark)

    Græsbøll, Rune; Nielsen, Nikoline Juul; Christensen, Jan H.


    A method for choosing orthogonal columns for a specific sample set in on-line comprehensive two-dimensional liquid chromatography (LC×LC) was developed on the basis of the hydrophobic subtraction model. The method takes into account the properties of the sample analytes by estimating new F...... by Gilroy et al. [1], (3) F-weights determined from the retention of sample analytes but using principal component analysis (PCA) for the estimation, and (4) the Gilroy F-weights modified by excluding the C-term in the hydrophobic subtraction model, as suggested by Dolan and Snyder [2]. The retention of 13...... neutral and 4 acidic oxygenated polycyclic aromatic compounds (PACs) and 3 nitrogen-containing PAC bases was measured isocratically on 12 columns. The isocratic runs were used to determine the hydrophobic subtraction model analyte parameters, and these were used to estimate new F-weights and predict...

  17. Miniature electron microscope beam column optics (United States)

    Loyd, Jody Stuart

    This investigation is in the area of electrostatic lens design with the overarching goal of contributing to the creation of a miniaturized scanning electron microscope (SEM) for use in mineralogical analysis or detection of signs of life on the surface of Mars. Such an instrument could also have application in the exploration of Earth's moon, planetary moons, asteroids, or comets. Other embodiments could include tabletop or field portable SEMs for use on Earth. The scope of this research is in the design of a beam column that attains focusing, demagnification, and aberration control within the smallest achievable package. The goals of planetary exploration and of spaceflight in general impose severe constraints on the instrument's mass and electrical power consumption, while favoring a robust design of small size and high rigidity that is also simple to align. To meet these requirements a design using electrostatic lenses was favored because of the lower power requirement and mass of electrostatic versus magnetic lenses, their relatively simple construction, as well as inherently easier shielding from extraneous fields. In modeling the lens field, a hybrid of a Boundary Element Method (BEM) and a Fourier series solution was employed, whereby an initial solution from the BEM is used to derive the bounding potential of a cylindrical subdomain for the subsequent Fourier series solution. The approach is applicable to many problems in physics and combines the inherent precision of this series solution with the flexibility of BEM to describe practical, non-idealized electrode shapes. The resulting lens field in the Fourier series subdomain is of higher precision, thereby allowing smaller errors in subsequent calculations of electron ray paths. The effects of aberrations are thus easier to observe in tracing non-paraxial rays. A significant speed increase in tracing rays is also observed. The modeling technique has been validated by reproducing example ray-traces through

  18. The effect of retentive groove, sandblasting and cement type on the retentive strength of stainless steel crowns in primary second molars - An in vitro comparative study

    Directory of Open Access Journals (Sweden)

    M M Veerabadhran


    Full Text Available Purpose: This in vitro study was conducted to find out the effect of retentive groove, sand blasting and cement type on the retentive strength of stainless steel crowns in primary second molars. Materials and Methods: Thirty-two extracted intact human maxillary and mandibular primary second molars were embedded in aluminum blocks utilizing autopolymerising acrylic resin. After tooth preparation, the 3M stainless steel crown was adjusted to the prepared tooth. Then weldable buccal tubes were welded on the buccal and lingual surfaces of each crown as an attachment for the testing machine. A full factorial design matrix for four factors (retentive groove placement on the tooth, cement type, sandblasting and primary second molar at two levels each was developed and the study was conducted as dictated by the matrix. The lower and upper limits for each factor were without and with retentive groove placement on the tooth, GIC and RMGIC, without and with sandblasting of crown, maxillary and mandibular second primary molar. For those teeth for which the design matrix dictated groove placement, the retentive groove was placed on the middle third of the buccal surface of the tooth horizontally and for those crowns for which sandblasting of the crowns are to be done, sandblasting was done with aluminium oxide with a particle size of 250 mm. The crowns were luted with either GIC or RMGIC, as dictated by the design matrix. Then the retentive strength of each sample was evaluated by means of an universal testing machine. The obtained data was analyzed using ANOVA for statistical analysis of the data and ′t′- tests for pairwise comparison. Results: The mean retentive strength in kg/cm 2 stainless steel crowns luted with RMGIC was 19.361 and the mean retentive strength of stainless steel crowns luted with GIC was 15.964 kg/cm 2 with a mean difference of 3.397 kg/cm 2 and was statistically significant. The mean retentive strength in kg/cm 2 of stainless steel

  19. Experimental and analytical behavior of strengthened reinforced concrete columns with steel angles and strips (United States)

    Khalifa, Essam S.; Al-Tersawy, Sherif H.


    The need of strengthening reinforced concrete columns, due to loss of strength and/or stiffness, is an essential requirement due to variation of the loads and environmental conditions applied on these columns. Steel jackets around the reinforced concrete (RC) columns are usually made by means of steel plates covering all over the column surface area. For the value of engineering purposes, another technique was developed using steel angles at the corners of the RC columns connected with discrete steel strips. In this paper, an experimental program is designed to evaluate the improvement in load-carrying capacity, stiffness and ductility of strengthened RC columns, concomitant with steel angles and strips. Despite of prevailing a substantially increased loading capacity and strength a pronounced enhancement in ductility and stiffness has been reported. A need for experimental test results with low value of concrete strength to mimic the local old-age structures condition that required strengthening in local countries. Seven columns specimens are tested to evaluate the strength improvement provided by steel strengthening of columns. The method of strengthened steel angles with strips is compared with another strengthening technique. This technique includes connected and unconnected steel-casing specimens. The observed experimental results describe load-shortening curves, horizontal strains in stirrups and steel strips, as well as description of failure mode. The extra-confinement pressure, due to existence of steel cage, of the strengthened RC column can be also observed from experimental results. The code provisions that predict the load-carrying capacity of the strengthened RC composite column has a discrepancy in the results. For this reason, an analytical model is developed in this paper to compare the code limit with experimental observed results. The proposed model accounts for the composite action for concrete confinement and enhancement of the local buckling

  20. Gastro retention using polymer cocoons. (United States)

    Arnold, Julien; Hunkeler, David


    A gastro-retentive capsule has been prepared which is retained in the stomach for a period of 24h, providing a vehicle for the controlled delivery to the upper intestines. These "gastro cocoons" can resist passage through the sphincter of the stomach, and can retain a high drug payload (30%). They are made from oppositely charged polyelectrolytes and can swell to twice their initial volume. They are strong and also can resist 550 N of compressive force. They are based on filled pharmaceutical capsules which are visible to X-rays. Using ambroxol hydrochloride as a model drug linear, zero-order, release curves were obtained.

  1. Dynamic Effects of Diabatization in Distillation Columns

    DEFF Research Database (Denmark)

    Bisgaard, Thomas; Huusom, Jakob Kjøbsted; Abildskov, Jens


    The dynamic eects of diabatization in distillation columns are investigated in simulation with primary focus on the heat-integrated distillation column (HIDiC). A generic, dynamic, rst-principle model has been formulated, which is exible to describe various diabatic distillation congurations....... Dynamic Relative Gain Array and Singular Value Analysis have been applied in a comparative study of a conventional distillation column and a HIDiC. The study showed increased input-output coupling due to diabatization. Feasible SISO control structures for the HIDiC were also found. Control...

  2. Dynamic effects of diabatization in distillation columns

    DEFF Research Database (Denmark)

    Bisgaard, Thomas; Huusom, Jakob Kjøbsted; Abildskov, Jens


    The dynamic effects of diabatization in distillation columns are investigated in simulation emphasizing the heat-integrated distillation column (HIDiC). A generic, dynamic, first-principle model has been formulated, which is flexible enough to describe various diabatic distillation configurations....... Dynamic Relative Gain Array and Singular Value Analysis have been applied in a comparative study of a conventional distillation column and a HIDiC. The study showed increased input-output coupling due to diabatization. Feasible SISO control structures for the HIDiC were also found and control...

  3. Plum and soy aglycon extracts superior at increasing bone calcium retention in ovariectomized Sprague Dawley rats. (United States)

    Pawlowski, Jessica W; Martin, Berdine R; McCabe, George P; Ferruzzi, Mario G; Weaver, Connie M


    Plant-derived polyphenols have been shown to influence bone turnover and bone properties in the estrogen-depleted state. We used a crossover design in ovariectomized rats (n = 16 rats for each diet) to investigate the effect of supplementation of two doses each of blueberry, plum, grape, grape seed extract, and resveratrol on bone. We tested the aglycon and glucoside forms of genistein to quantify differences in efficacy on bone calcium retention. Rats were given an intravenous dose of ⁴⁵Ca to prelabel bone, and bone calcium retention was assessed by urinary excretion of ⁴⁵Ca:Ca ratio during an intervention period compared with nonintervention. Genistein aglycon increased bone calcium retention significantly (pcalcium retention by 20% (p=0.0153) and 14% (p=0.0012), respectively. Several polyphenolic-rich diets improved bone calcium retention.

  4. 29 CFR 1926.756 - Beams and columns. (United States)


    ... (.46 m) from the extreme outer face of the column in each direction at the top of the column shaft. (e) Perimeter columns. Perimeter columns shall not be erected unless: (1) The perimeter columns extend a minimum of 48 inches (1.2 m) above the finished floor to permit installation of perimeter safety cables prior...

  5. Design

    DEFF Research Database (Denmark)

    Volf, Mette

    This publication is unique in its demystification and operationalization of the complex and elusive nature of the design process. The publication portrays the designer’s daily work and the creative process, which the designer is a part of. Apart from displaying the designer’s work methods...... and design parameters, the publication shows examples from renowned Danish design firms. Through these examples the reader gets an insight into the designer’s reality....

  6. Model Experiment on Integral Seismic Behavior of Reinforced Concrete Frame with Split Columns

    Institute of Scientific and Technical Information of China (English)

    LI Zhongxian; JING Meng; HAO Yongchang; KANG Guyi


    Based on a series of previous studies, an experiment on the integral seismic behavior of a 1/3 scaled model of two-bay and three-story reinforced concrete frame with split columns at lower two stories is performed under cyclic loading. The original columns at lower two stories of the model frame are short columns and they are replaced by the split columns. The hysteresis curves between the horizontal cyclic load and the lateral displacement at the top of the model frame, indicate that under the cyclic loading, the model frame undergoes the process of cracking, yielding, and maximum loading before being destroyed at the ultimate load. They also indicate that the model frame has better ductility, and the ratio of the ultimate displacement to the yielding displacement, reaches 6.0. The yielding process of the model frame shows that for the frame with split columns, plastic hinges are generated at the ends of beams and then the columns begin yielding while the frame still possesses the bearing and deformation capacity. The design idea of directly changing the short column to long one in the reinforced concrete frame may be realized by replacing the short column with the split one.

  7. Analysis of Multi-Loop Control Structures of Dividing-Wall Distillation Columns Using a Fundamental Model


    Salvador Tututi-Avila; Arturo Jiménez-Gutiérrez; Juergen Hahn


    Dividing-wall columns (DWCs) have significant potential as energy-efficient processes for the separation of multicomponent mixtures. However, in addition to an efficient steady state design, dynamics and control also play a major part for the success of a technology. This is especially so for complex distillation systems. This paper investigates the dynamics of a dividing wall column used for the separation of ternary mixtures. A detailed dynamic first principles-based model of the column I ...

  8. Normal-phase high performance liquid chromatography of estradiol derivatives on amino- and diol- columns

    Directory of Open Access Journals (Sweden)



    Full Text Available The retention behaviour of estradiol derivatives was studied by HPLC on chemically bonded polar stationary phases: commercially available amino- and diol- columns, as a function of the heptane-propan-1-ol as the mobile phase, when the volume fraction of propan-1-ol in the binary mobile phase was low, even less than 5 %. The relationship between the logarithm of the retention constant (log k and the logarithm of the volume fraction of propan-1-ol (–log j in the eluent was linear for all solutes studied. The results are discussed in terms of the solute and stationary phase properties and compared with the results of the same derivatives obtained in earlier investigations.

  9. Dynamic analysis of composite columns in Inelastic state

    Directory of Open Access Journals (Sweden)

    Mohsen Rezaie Hajidehi


    Full Text Available The main objective of this study is analyzing Seismic behavior of composite columns in frame in inelastic state under dynamic load. Therefore, three type of composite column have been used in this paper. IPB Steel section embedded in concrete (type 1, Concrete-filled thin-walled steel sections (type 2, half concreted IPB sections (type 3 which are designed for 3 and 8 floor frame tenement in plastic way. Three earthquake accelerogram have been used for analyzing model seismic behavior and model analysis has been done in non-linear dynamic analysis with Seismostruct application. The results demonstrated that frame designed by composite columns type 1 and 3 in the flexural behavior, have similar construction behavior in the way that plasticity, softness and good function to dispose lateral forces are the same.  Although Type 2 composite model have large sections, have poor performance in tolerating flexural moment. This event refers to poor role of concrete in tension. On the other hand, the amount of concrete is important in Withstand compressive forces and in constructions with high compressive forces, type 1 and 2 have better performance.

  10. Pathways to URM Retention: IBP's Professional Development and Mentoring Activities (United States)

    Johnson, A.; Williamson Whitney, V.; Ricciardi, L.; Detrick, L.; Siegfried, D.; Fauver, A.; Ithier-Guzman, W.; Thomas, S. H.; Valaitis, S.


    As a not for profit organization, the Institute for Broadening Participation (IBP) hosts a variety of initiatives designed to increase the retention of underrepresented minority (URM) students pursuing pathways in STEM. IBP also assists with formative program evaluation design and implementation to help strengthen URM recruitment and retention elements. Successful initiatives include virtual and face-to-face components that bring together URM students with established URM and other scientists in academia, government and industry. These connections provide URMs with mentoring, networking opportunities, and professional skill development contributing to an improved retention rate of URM students. IBP's initiatives include the NASA One Stop Shopping Initiative (NASA OSSI), Pathways to Ocean Science and Engineering, and the Minorities Striving and Pursuing Higher Degrees of Success (MS PHD'S) in Earth System Science (ESS) Professional Development Program. The NASA OSSI recruits and facilitates student engagement in NASA education and employment opportunities. Pathways to Ocean Science connects and supports URM students with Ocean Science REU programs and serves as a resource for REU program directors. Pathways to Engineering has synthesized mentoring resources into an online mentoring manual for URM students that has been extensively vetted by mentoring experts throughout the country. The mentoring manual, which is organized by roles, provides undergraduates, graduates, postdocs, faculty and project directors with valuable resources. MS PHD'S, one of IBP's longest running and most successful initiatives, focuses on increasing the retention rate of URM students receiving advanced degrees in ESS. The program addresses barriers to retention in ESS including isolation, lack of preparation and professional development, and lack of mentoring. Program activities center on peer-to-peer community building, professional development exercises, networking experiences, one

  11. Comparison of Limiting Width-Thickness Ratios of Steel Columns in Sino-foreign Seismic Design Codes%中外抗震设计规范关于钢柱板件宽厚比限值的比较

    Institute of Scientific and Technical Information of China (English)

    邓椿森; 施刚; 张勇; 王元清; 石永久


    板件宽厚比对钢结构的抗震性能有着重要影响,同时也是影响钢结构用钢量的一项重要指标,对钢结构的安全性和经济性均有着很重要的意义.目前国内已有不少文献认为我国现行抗震设计规范对梁柱截面板件宽厚比限值的规定尚不够严谨和完善,并对此提出了设计建议.结合中国抗震规范GB50011—2001、美国钢结构抗震规范ANSI/AISC 341—05、日本抗震规范BCJ和欧洲抗震规范Eurocode 8的相关规定,比较研究了中外抗震设计规范对工形截面和箱形截面钢柱板件宽厚比限值规定的异同,分析了中国抗震规范GB50011—2001关于钢柱板件宽厚比限值的合理性,为相关设计和研究提供了参考.%The limiting width-thickness ratio plays an important role in steel structures' safety and economy,as it not only has a significant influence on steel structures' seismic performance,but also is an important index of steel consumption for steel structures.At present,many domestic research results show that the limiting width-thickness ratios in our country's seismic design code are not adequate or reasonable and have presented corresponding design recommendation.The limiting width-thickness ratios in the related Chinese code GB50011—2001,American code ANSI/AISC 341—05,Japanese code BCJ and European code Eurocode 8 are compared and analyzed,which provides a reference for the relevant steel structure design and research.

  12. Radionuclide Retention in Concrete Wasteforms

    Energy Technology Data Exchange (ETDEWEB)

    Wellman, Dawn M.; Jansik, Danielle P.; Golovich, Elizabeth C.; Cordova, Elsa A.


    Assessing long-term performance of Category 3 waste cement grouts for radionuclide encasement requires knowledge of the radionuclide-cement interactions and mechanisms of retention (i.e., sorption or precipitation); the mechanism of contaminant release; the significance of contaminant release pathways; how wasteform performance is affected by the full range of environmental conditions within the disposal facility; the process of wasteform aging under conditions that are representative of processes occurring in response to changing environmental conditions within the disposal facility; the effect of wasteform aging on chemical, physical, and radiological properties; and the associated impact on contaminant release. This knowledge will enable accurate prediction of radionuclide fate when the wasteforms come in contact with groundwater. Data collected throughout the course of this work will be used to quantify the efficacy of concrete wasteforms, similar to those used in the disposal of LLW and MLLW, for the immobilization of key radionuclides (i.e., uranium, technetium, and iodine). Data collected will also be used to quantify the physical and chemical properties of the concrete affecting radionuclide retention.

  13. The research of subsection parabolic interpolation applied to the design of rectifying column%分段抛物插值算法在精馏塔设计中的应用研究

    Institute of Scientific and Technical Information of China (English)

    李俊妮; 栗秀萍; 刘有智; 涂传璞


    在精馏塔设计中,计算理论塔板数的方法有图解法、逐板计算法和简捷法等,其中图解法因快捷直观而常被使用.图解法用于精馏塔设计,通常与MATLAB、Aspen Plus、CAD、Excel等软件结合使用.在其设计过程中,先根据较有限的气液平衡数据和方程绘制相应的曲线,这样可能会造成一定的误差且曲线的光滑度也较差,从而导致精馏塔理论塔板数的计算精度不高.为提高其精度,本文采用数值分析方法——分段抛物插值法对二元理想体系的气液平衡曲线进行模拟,并结合MATLAB软件和图解法对精馏段操作线、q线和提馏段操作线进行数值计算和绘制曲线以计算精馏塔理论塔板数,从而完成精馏塔的设计.文中选用苯-甲苯物系作为应用实例,计算得出其q点坐标为(0.3626,0.5495),该物系的理论塔板数N为13.3739块(包括再沸器),其中第6.3589块板为加料板.%In the design of rectifying tower, there are three methods used in calculating theoretical plate: graphic method, calculating step by step and shortcut method, and graphic method is intuitive and simple. Graphic method is usually combined with MATLAB, Aspen Plus, CAD or Excel software in the design of rectifying tower. In the design process, vapor-liquid equilibrium curve is drawn according to vapor-liquid equilibrium data and equation. This will cause a certain error and the smoothness degree of curve is poor. At last, calculative accuracy of theoretical plate in rectifying tower is not precise. In order to improve the accuracy, the method of numerical analysis-subsection parabolic interpolation is used for curve-fitting of vapor-liquid equilibrium in the binary ideal mixtures. To calculate the theoretical plates in rectifying tower, the g line and the curves of rectifying section and stripping section are numerical calculated and drawn combined MATLAB with the graphic method. So the design of rectifying tower is tompletsd

  14. Modeling the retention mechanism for high-performance liquid chromatography with a chiral ligand mobile phase and enantioseparation of mandelic acid derivatives. (United States)

    Tong, Shengqiang; Shen, Mangmang; Zhang, Hu; Cheng, Dongping; Yan, Jizhong


    The chromatographic retention mechanism describing relationship between retention factor and concentration of Cu(2+) (l-phenylalanine)2 using chiral ligand mobile phase was investigated and eight mandelic acid derivatives were enantioseparated by chiral ligand exchange chromatography. The relationship between retention factor and concentration of the Cu(2+) (l-phenylalanine)2 complex was proven to be in conformity with chromatographic retention mechanism in which chiral discrimination occurred both in mobile and stationary phase. Different copper(II) salts, chiral ligands, organic modifier, pH of aqueous phase, and conventional temperature on retention behavior were optimized. Eight racemates were successfully enantioseparated on a common reversed-phase column with an optimized mobile phase composed of 6 mmol/L of l-phenylalanine or N,N-dimethyl-l-phenylalanine and 3 mmol/Lof copper(II) acetate or copper(II) sulfate aqueous solution and methanol. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Liquid-Phase Back mixing in Bubble Columns

    Directory of Open Access Journals (Sweden)

    Burhan S. Abdulrazak


    Full Text Available Liquid-phase axial dispersion coefficients have been measured for air-water system in bubble columns of 10, 15 and 30 cm diameter. The experiments are carried out using a transient method (the tracer response method.  Dispersion coefficient is obtained by adjusting the experimental profiles of tracer concentration with the predictions of the model. The experimental results show that one-dimensional axial dispersion coefficient, Dax,L, reveal strong scale dependence. Backmixing of liquid phase increases with the increase of reactor diameter and superficial gas velocity.  Axial dispersion coefficient for large column reactors can be easily predicted from the developed relation . Comparison of calculated with the experimental data and with the published data of other authors shows good agreement which ensure the reliability and confusability of the adopted correlations to be used in further design and scale-up purposes. 

  16. A Study on Employee Retention Techniques


    Savarimuthu, Dr. A; Hemalatha, N


    The objective of perusing this study is to assess the level of satisfaction of employee retention techniques at GB Engineering Enterprises PVT Limited., Trichy.This study gains significance because of employee retention techniques can be approached from various angles. It is desirable state of existence involving retention strategies generally fall in to one of four categories salary, working conditions, job enrichment and education. These four elements together constitute. The structure of e...

  17. Tree retention in boreal pine forest


    Santaniello, Francesca


    Tree retention forestry aims at increasing structural diversity in managed forests. In this study, I have investigated the influence of tree retention forestry on delivery of two ecosystem services (wood production and carbon sequestration) and dead wood (as a proxy for biodiversity). Furthermore, habitat requirements of lichens dependent on dead wood were investigated. The study was conducted in 15 Scots pine forest stands with five various tree retention levels, in which four...

  18. Electroosmotic Driving Liquid Using Nanosilica Packed Column

    Institute of Scientific and Technical Information of China (English)

    Ling Xin CHEN; Guo An LUO; Tao WEN


    The electroosmotic pump (EOP) using nanosilica particles packed-bed column was experimentally studied. The relationship between flowrate, pressure and applied voltage of the pump, and pressure-flowrate (P-Q) characteristic were investigated.

  19. Early development of the vertebral column. (United States)

    Scaal, Martin


    The segmental organization of the vertebrate body is most obviously visible in the vertebral column, which consists of a series of vertebral bones and interconnecting joints and ligaments. During embryogenesis, the vertebral column derives from the somites, which are the primary segments of the embryonic paraxial mesoderm. Anatomical, cellular and molecular aspects of vertebral column development have been of interest to developmental biologists for more than 150 years. This review briefly summarizes the present knowledge on early steps of vertebral column development in amniotes, starting from sclerotome formation and leading to the establishment of the anatomical bauplan of the spine composed of vertebral bodies, vertebral arches, intervertebral discs and ribs, and their specific axial identities along the body axis.

  20. Modeling Tropical Precipitation in a Single Column. (United States)

    Sobel, Adam H.; Bretherton, Christopher S.


    A modified formulation of the traditional single column model for representing a limited area near the equator is proposed. This formulation can also be considered a two-column model in the limit as the area represented by one of the columns becomes very large compared to the other. Only a single column is explicitly modeled, but its free tropospheric temperature, rather than its mean vertical velocity, is prescribed. This allows the precipitation and vertical velocity to be true prognostic variables, as in prior analytical theories of tropical precipitation. Two models developed by other authors are modified according to the proposed formulation. The first is the intermediate atmospheric model of J. D. Neelin and N. Zeng, but with the horizontal connections between columns broken, rendering it a set of disconnected column models. The second is the column model of N. O. Rennó, K. A. Emanuel, and P. H. Stone. In the first model, the set of disconnected column models is run with a fixed temperature that is uniform in the Tropics, and insolation, SST, and surface wind speed taken from a control run of the original model. The column models produce a climatological precipitation field that is grossly similar to that of the control run, despite that the circulation implied by the column models is not required to conserve mass. The addition of horizontal moisture advection by the wind from the control run substantially improves the simulation in dry regions. In the second model the sensitivity of the modeled steady-state precipitation and relative humidity to varying SST and wind speed is examined. The transition from shallow to deep convection is simulated in a `Lagrangian' calculation in which the column model is subjected to an SST that increases in time. In this simulation, the onset of deep convection is delayed to a higher SST than in the steady-state case, due to the effect of horizontal moisture advection (viewed in a Lagrangian reference frame). In both of the