LLNL Underground-Coal-Gasification Project. Quarterly progress report, July-September 1981

Energy Technology Data Exchange (ETDEWEB)

Stephens, D.R.; Clements, W. (eds.)

1981-11-09

We have continued our laboratory studies of forward gasification in small blocks of coal mounted in 55-gal drums. A steam/oxygen mixture is fed into a small hole drilled longitudinally through the center of the block, the coal is ignited near the inlet and burns toward the outlet, and the product gases come off at the outlet. Various diagnostic measurements are made during the course of the burn, and afterward the coal block is split open so that the cavity can be examined. Development work continues on our mathematical model for the small coal block experiments. Preparations for the large block experiments at a coal outcrop in the Tono Basin of Washington State have required steadily increasing effort with the approach of the scheduled starting time for the experiments (Fall 1981). Also in preparation is the deep gasification experiment, Tono 1, planned for another site in the Tono Basin after the large block experiments have been completed. Wrap-up work continues on our previous gasification experiments in Wyoming. Results of the postburn core-drilling program Hoe Creek 3 are presented here. Since 1976 the Soviets have been granted four US patents on various aspects of the underground coal gasification process. These patents are described here, and techniques of special interest are noted. Finally, we include ten abstracts of pertinent LLNL reports and papers completed during the quarter.

Geochemistry of coal-measure source rocks and natural gases in deep formations in Songliao Basin, NE China

Energy Technology Data Exchange (ETDEWEB)

Mi, Jingkui; Zhang, Shuichang; Hu, Guoyi; He, Kun [State Key Laboratory for Enhanced Oil Recovery, Beijing (China); Petroleum Geology Research and Laboratory Center, Research Institute of Petroleum Exploration and Development, PetroChina (China); Key Laboratory for Petroleum Geochemistry, China National Petroleum Corp. (China)

2010-12-01

The natural gases developed in deep volcanic rock reservoirs of the Songliao Basin, NE China are characterized by enriched {delta}{sup 13}C value for methane and frequently reversal carbon isotopic distribution pattern. Although many researchers consider such gas type as an abiogenic origin, we believe the natural gases have a biogenic origin mainly except little inorganic gases and the reversal carbon isotopic distribution pattern of gases is caused by mixing of different origin gases. Methane carbon isotopic values for majority samples fall in the range from - 24 permille to - 32 permille, which is heavier than typical coal-type gases in other Chinese basins. There are several reasons caused heavy carbon isotope of methane: (1) Carbon isotopic values of source kerogen are 3-5 permille heavier than these from other basins; (2) Source rocks are at extremely high maturity stage with vitrinite reflectance mostly above 3.0%; (3) Portion of gas is derived from basement mudrock or slate with higher maturity. The observation on the organic from deep formation reveals that there is a relatively high content for liptinite, which reaches approximately 8 to 10%. The macerals component of source rock shows that the source rocks have some ability to generate oil. Small portion of oil was generated from high hydrogen content macerals in coals and shales as proof by oil found in microcrack and in micropore of coal and oil-bearing fluid inclusions grown in volcanic reservoir. The occurrence of pyrobitumen in volcanic reservoir indicates preexisted oil had been cracked into wet gas, and this kind of gas had also been found in gas pools. Heavy isotopic methane is derived from coal at extremely high maturity stage. There may be little inorganic alkane gases in deep layers for their geochemistry and special geological setting of Songliao Basin. Artificial mixing experiments of different origins gases confirm that inorganic gas such as gas from well FS1 mixed with other end members

Coal gasification. Quarterly report, April--June 1977

Energy Technology Data Exchange (ETDEWEB)

None

1978-01-01

The conversion of coal to high-Btu gas requires a chemical and physical transformation of solid coal. However, because coal has widely differing chemical and physical properties, depending on where it is mined, it is difficult to process. Therefore, to develop the most suitable techniques for gasifying coal, ERDA, together with the American Gas Association, is sponsoring the development of several advanced conversion processes. Although the basic coal-gasification chemical reactions are the same for each process, the processes under development have unique characteristics. A number of the processes for converting coal to high Btu and to low Btu gas have reached the pilot plant stage. The responsibility for designing, constructing and operating each of these pilot plants is defined and progress on each during the quarter is described briefly. The accumulation of data for a coal gasification manual and the development of mathematical models of coal gasification processes are reported briefly. (LTN)

Quarterly coal report, April--June 1993

Energy Technology Data Exchange (ETDEWEB)

1993-11-26

In the second quarter of 1993, the United States produced 235 million short tons of coal. This brought the total for the first half of 1993 to 477 million short tons, a decrease of 4 percent (21 million short tons) from the amount produced during the first half of 1992. The decrease was due to a 26-million-short-ton decline in production east of the Mississippi River, which was partially offset by a 5-million-short-ton increase in coal production west of the Mississippi River. Compared with the first 6 months of 1992, all States east of the Mississippi River had lower coal production levels, led by West Virginia and Illinois, which produced 9 million short tons and 7 million short tons less coal, respectively. The principal reasons for the drop in coal output for the first 6 months of 1993 compared to a year earlier were: a decrease in demand for US coal in foreign markets, particularly the steam coal markets; a draw-down of electric utility coal stocks to meet the increase in demand for coal-fired electricity generation; and a lower producer/distributor stock build-up. Distribution of US coal in the first half of 1993 was 15 million short tons lower than in the first half of 1992, with 13 million short tons less distributed to overseas markets and 2 million short tons less distributed to domestic markets.

Coal gasification. Quarterly report, January--March 1977

Energy Technology Data Exchange (ETDEWEB)

None

1977-12-01

High-Btu natural gas has a heating value of 950 to 1,000 Btu per standard cubic foot, is composed essentially of methane, and contains virtually no sulfur, carbon monoxide, or free hydrogen. The conversion of coal to high-Btu gas requires a chemical and physical transformation of solid coal. However, because coal has widely differing chemical and physical properties, depending on where it is mined, it is difficult to process. Therefore, to develop the most suitable techniques for gasifying coal, ERDA, together with the American Gas Association is sponsoring the development of several advanced conversion processes. Although the basic coal-gasification chemical reactions are the same for each process, the processes under development have unique characteristics. A number of the processes for converting coal to high Btu and to low Btu gas have reached the pilot plant stage. The responsibility for designing, constructing and operating each of these pilot plants is defined and progress on each during the quarter is described briefly. The accumulation of data for a coal gasification manual and the development of mathematical models of coal gasification processes are reported briefly. (LTN)

Carbon and oxygen isotopic composition of coal and carbon dioxide derived from laboratory coal combustion: A preliminary study

Science.gov (United States)

Warwick, Peter D.; Ruppert, Leslie F.

2016-01-01

The concentration of carbon dioxide (CO2) in the atmosphere has dramatically increased from the start of the industrial revolution in the mid-1700s to present levels exceeding 400 ppm. Carbon dioxide derived from fossil fuel combustion is a greenhouse gas and a major contributor to on-going climate change. Carbon and oxygen stable isotope geochemistry is a useful tool to help model and predict the contributions of anthropogenic sources of CO2 in the global carbon cycle. Surprisingly few studies have addressed the carbon and oxygen isotopic composition of CO2 derived from coal combustion. The goal of this study is to document the relationships between the carbon and oxygen isotope signatures of coal and signatures of the CO2 produced from laboratory coal combustion in atmospheric conditions.Six coal samples were selected that represent various geologic ages (Carboniferous to Tertiary) and coal ranks (lignite to bituminous). Duplicate splits of the six coal samples were ignited and partially combusted in the laboratory at atmospheric conditions. The resulting coal-combustion gases were collected and the molecular composition of the collected gases and isotopic analyses of δ13C of CO2, δ13C of CH4, and δ18O of CO2 were analysed by a commercial laboratory. Splits (~ 1 g) of the un-combusted dried ground coal samples were analyzed for δ13C and δ18O by the U.S. Geological Survey Reston Stable Isotope Laboratory.The major findings of this preliminary work indicate that the isotopic signatures of δ13C (relative to the Vienna Pee Dee Belemnite scale, VPDB) of CO2 resulting from coal combustion are similar to the δ13CVPDB signature of the bulk coal (− 28.46 to − 23.86 ‰) and are not similar to atmospheric δ13CVPDB of CO2 (~ − 8 ‰, see http://www.esrl.noaa.gov/gmd/outreach/isotopes/c13tellsus.html). The δ18O values of bulk coal are strongly correlated to the coal dry ash yields and appear to have little or no influence on the δ18O values of CO2

Low-rank coal research. Quarterly report, January--March 1990

Energy Technology Data Exchange (ETDEWEB)

1990-08-01

This document contains several quarterly progress reports for low-rank coal research that was performed from January-March 1990. Reports in Control Technology and Coal Preparation Research are in Flue Gas Cleanup, Waste Management, and Regional Energy Policy Program for the Northern Great Plains. Reports in Advanced Research and Technology Development are presented in Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Reports in Combustion Research cover Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Coal Fuels, Diesel Utilization of Low-Rank Coals, and Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications. Liquefaction Research is reported in Low-Rank Coal Direct Liquefaction. Gasification Research progress is discussed for Production of Hydrogen and By-Products from Coal and for Chemistry of Sulfur Removal in Mild Gas.

Characterization of coal-derived hydrocarbons and source-rock potential of coal beds, San Juan Basin, New Mexico and Colorado, U.S.A.

Science.gov (United States)

Rice, D.D.; Clayton, J.L.; Pawlewicz, M.J.

1989-01-01

.5 ppt), are chemically wetter (C1/C1-5 values range from 0.85 to 0.95), and contain less CO2 (< 2%). These gases are interpreted to have been derived from type III kerogen dispersed in marine shales of the underlying Lewis Shale and nonmarine shales of the Fruitland Formation. In the underlying Upper Cretaceous Dakota Sandstone and Tocito Sandstone Lentil of the Mancos Shale, another gas type is produced. This gas is associated with oil at intermediate stages of thermal maturity and is isotopically lighter and chemically wetter at the intermediate stage of thermal maturity as compared with gases derived from dispersed type III kerogen and coal; this gas type is interpreted to have been generated from type II kerogen. Organic matter contained in coal beds and carbonaceous shales of the Fruitland Formation has hydrogen indexes from Rock-Eval pyrolysis between 100 and 350, and atomic H:C ratios between 0.8 and 1.2. Oxygen indexes and atomic O:C values are less than 24 and 0.3, respectively. Extractable hydrocarbon yields are as high as 7,000 ppm. These values indicate that the coal beds and carbonaceous shales have good potential for the generation of liquid hydrocarbons. Voids in the coal filled with a fluorescent material that is probably bitumen is evidence that liquid hydrocarbon generation has taken place. Preliminary oil-source rock correlations based on gas chromatography and stable carbon isotope ratios of C15+ hydrocarbons indicate that the coals and (or) carbonaceous shales in the Fruitland Formation may be the source of minor amounts of condensate produced from the coal beds at relatively low levelsof thermal maturity (Rm=0.7). ?? 1989.

Factors affecting cleanup of exhaust gases from a pressurized, fluidized-bed coal combustor

Science.gov (United States)

Rollbuhler, R. J.; Kobak, J. A.

1980-01-01

The cleanup of effluent gases from the fluidized-bed combustion of coal is examined. Testing conditions include the type and feed rate of the coal and the sulfur sorbent, the coal-sorbent ratio, the coal-combustion air ratio, the depth of the reactor fluidizing bed, and the technique used to physically remove fly ash from the reactor effluent gases. Tests reveal that the particulate loading matter in the effluent gases is a function not only of the reactor-bed surface gas velocity, but also of the type of coal being burnt and the time the bed is operating. At least 95 percent of the fly ash particules in the effluent gas are removed by using a gas-solids separator under controlled operating conditions. Gaseous pollutants in the effluent (nitrogen and sulfur oxides) are held within the proposed Federal limits by controlling the reactor operating conditions and the type and quantity of sorbent material.

Coal mining situation in the Federal Republic of Germany. The 1st quarter 2017

International Nuclear Information System (INIS)

2017-01-01

The paper reports on the coal mining in the Federal Republic of Germany in the 1st quarter of 2017. Statistical data are presented for mining, exports and imports of hard coal and lignite and for employees.

Coal mining situation in the Federal Republic of Germany. The 1st quarter 2015

International Nuclear Information System (INIS)

2015-01-01

The paper reports on the coal mining in the Federal Republic of Germany in the 1st quarter of 2015. Statistical data are presented for mining, exports and imports of hard coal and lignite and for employees.

The effect of petrographical composition of coals and bituminous sediments on the material and isotopic composition of dry natural gases from artificial recoalification reactions. 2

International Nuclear Information System (INIS)

Maass, I.; Huebner, H.; Nitzsche, H.-M.; Schuetze, H.; Zschiesche, M.

1975-01-01

Experimental results indicate that on the basis of the material and isotopic composition of natural gases conclusions can be drawn with regard to the character (humic or bituminous) of the parent rock. Thus, genetic relations assumed to exist between humic sediments (e.g. coal seams) and dry natural gases as well as bituminous rocks and wet natural gases are experimentally confirmed. In addition, from analyses of the materials approximate data can be derived on the degree of carbonization of coal or bituminous sediments in the main phase of gas separation. Furthermore, these analyses were used to elucidate the question whether authochthonous or allochthonous deposits are present. It could be shown that the maceral composition of coals and of the organo-petrographical inclusions in bituminous sediments determines the isotopic composition of methane in recoalification gases to a considerable degree. (author)

Coal mining situation in the Federal Republic of Germany. The 1st quarter 2010

International Nuclear Information System (INIS)

2010-01-01

The report on coal mining situation in the Federal Republic of Germany in the 1st quarter 2010 contains the statistical data concerning the following issues: (i) black coal mining: part I: production, resources, accomplishments; employees, part II: marketing and foreign trade; (ii) brown coal mining: part I: production, resources, accomplishments; employees, part II: marketing and foreign trade.

Coal pyrolysis under hydrogen-rich gases

Energy Technology Data Exchange (ETDEWEB)

Liao, H.; Sun, C.; Li, B.; Liu, Z. [Chinese Academy of Sciences, Taiyuan (China). State Key Laboratory of Coal Conversion, Institute of Coal Chemistry

1998-04-01

To improve the economy of the pyrolysis process by reducing the hydrogen cost, it is suggested to use cheaper hydrogen-rich gases such as coke-oven gas (COG) or synthesis gas (SG) instead of pure hydrogen. The pyrolysis of Chinese Xianfeng lignite which was carried out with real COG and SG at 3-5 MPa, a final temperature of 650{degree}C and a heating rate of 5{degree}C/min in a 10g fixed-bed reactor is compared with coal pyrolysis with pure hydrogen and nitrogen under the same conditions. The results indicate that compared with hydropyrolysis at the same total pressure, the total conversion and tar yields from coal pyrolysis with COG and SG decreases while the unwanted water increases. However, at the same H{sub 2} partial pressure, the tar yields and yields of BBTX, PCX and naphthalene from the pyrolysis of coal with COG and SG are all significantly higher than those of hydropyrolysis. Therefore, it is possible to use COG and SG instead of pure hydrogen. 8 refs., 3 figs., 6 tabs.

Chemistry and structure of coal derived asphaltenes and preasphaltenes. Quarterly progress report, April-June 1980

Energy Technology Data Exchange (ETDEWEB)

Yen, T. F.

1980-01-01

It is the objective of this project to isolate the asphaltene and preasphaltene fractions from coal liquids from a number of liquefaction processes. These processes consist of in general: catalytic hydrogenation, staged pyrolysis and solvent refining. These asphaltene fractions may be further separated by both gradient elution through column chromatography, and molecular size distribution through gel permeation chromatography. Those coal-derived asphaltene and preasphaltene fractions will be investigated by various chemical and physical methods for characterization of their structures. After the parameters are obtained, these parameters will be correlated with the refining and conversion variables which control a given type of liquefaction process. The effects of asphaltene in catalysis, ash or metal removal, desulfurization and denitrification will also be correlated. It is anticipated that understanding the role of asphaltenes in liquefaction processes will enable engineers to both improve existing processes, and to make recommendations for operational changes in planned liquefaction units in the United States. The objective of Phase 1 was to complete the isolation and separation of coal liquid fractions and to initiate their characterization. The objective of Phase 2 is to continue the characterization of coal asphaltenes and other coal liquid fractions by use of physical and instrumental methods. The structural parameters obtained will be used to postulate hypothetical average structures for coal liquid fractions. The objective of Phase 3 is to concentrate on the characterization of the preasphaltene (benzene insoluble fraction) of coal liquid fraction by the available physical and chemical methods to obtain a number of structural parameters.

Control of Self Burning in Coal, Piles by Detection of the generated gases; Control de autoencendidos en Parvas de Carbon por Deteccion de los Gases Producidos

Energy Technology Data Exchange (ETDEWEB)

1999-09-01

The purpose of this Research Project is to find the most appropriate method for immediate and remote detection of the phenomena that take place in Thermic Power Plant coal piles, due to the piling up of great quantities of this fuel and its large surface area. These phenomena are: Slow self-oxidation of the coal, producing loss of its calorific power, with its consequent financial loss. Self-combustion of the coal caused when the gases produced by self-oxidation and temperature conditions combine, and they reach a critical point (that of ignition). One of the most recent and novel methods for detection is the Formation of images of Gases, based on the use of laser turned into the vibration wavelengths of the molecules in the gases. This technique, coupled with Thermography, would give as a spatial map of thus distribution and temperatures of gave. It is necessary, in order to extend the use of this equipment to Thermic Power Plant coal piles, to accurately determine which different gases are emanated as well as the minimum concentration of each one of these and the temperature distribution in space. (Author)

Investigation of Adsorbed Gases Content in Coal Beds in Bosnia and Herzegovina

Directory of Open Access Journals (Sweden)

Sadadinovic, J.

2008-09-01

Full Text Available Investigation of the gas fraction in coal beds in Bosnia & Herzegovina has been performed systematically since 1988. Gas in coal beds can be present in free or adsorbed form, and dissolved in water. Methods of investigation are based on the direct approach, according to which the gas fraction is determined in the undisturbed coal bed.The quantity of the adsorbed and free gas in the coal bed is directly proportional to the gas pressure. Dependence is hyperbolic. The quantity of the free gas in mining conditions is being determined by measurement of the desorption index (Δp2. The desorption index for the Srednjobosanski coal basin ranges to 1571 Pa, and the free gas pressure in this coal basin amounts up to 3.75 MPa. The desorption index for coal beds in “Kreka” and “Banoviće” coal basins has negative values, which means that the free gas fraction within the coal beds is negligible, while separation of adsorbed gases is diffuse. The free gas pressure in the mentioned coal basins is below 0.1 MPa. Adsorbed gases within the coal are connected by physical adsorption according to Langmuir’s isothermal adsorption curve. Langmuir’s quantities, for coal bed conditions, ranges as follows: am from 0.826 to 9.52 m3 t–1 pcs, and b from 6.65 10–3 to 0.247 MPa–1. Adsorbed gas within Miocene coal beds contains methane in amounts of 1.49 m3 t–1 čus CH4 andcarbon(IVoxide in amounts of 0.15 m3 t–1 čus CO2. Adsorbed gas within Pliocene coal beds, without methane, dominant is content of carbon(IVoxide.The investigation of the gas content in coal beds of BiH conducted in this article reveal that the coal beds primarily contain methane, while others hydrocarbons such as ethane, ethene, propane, propene and butane are present sporadically in fraction below φ/10–6. Based on the investigation results conducted in this article, simple mathematical forms were obtained for quick calculation of the free gas quantity by measurement of the

Molecular biological enhancement of coal biodesulfurization. Seventh quarter report, May--July 1990

Energy Technology Data Exchange (ETDEWEB)

Kilbane, J.J.; Bielaga, B.A.

1990-07-01

The overall objective of this project is to sue molecular genetics to develop strains of bacteria with enhanced ability to remove sulfur from coal and to obtain data that will allow the performance and economics of a coal biodesulfurization process to be predicted. The work planned for the current quarter (May 1990 to July 1990) includes the following activities: (1) Construct a cloning vector that can be used in Rhodococcus rhodochrous IGTS8 from the small cryptic plasmid found in Rhodococcus rhodochrous ATCC 190607; (2) Develop techniques for the genetic analysis of IGTS8; (3) Continue biochemical experiments, particularly those that may allow the identification of desulfurization-related enzymes; (4) Continue experiments with coal to determine the kinetics of organic sulfur removal.

Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

Science.gov (United States)

Ayala, Raul E.

1993-01-01

This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

DEVELOPMENT OF NOVEL CERAMIC NANOFILM-FIBER INTEGRATED OPTICAL SENSORS FOR RAPID DETECTION OF COAL DERIVED SYNTHESIS GAS

Energy Technology Data Exchange (ETDEWEB)

Junhang Dong; Hai Xiao; Xiling Tang; Hongmin Jiang; Kurtis Remmel; Amardeep Kaur

2012-09-30

The overall goal of this project is to conduct fundamental studies on advanced ceramic materials and fiber optic devices for developing new types of high temperature (>500{degree}C) fiber optic chemical sensors (FOCS) for monitoring fossil (mainly coal) and biomass derived gases in power plants. The primary technical objective is to investigate and demonstrate the nanocrystalline doped-ceramic thin film enabled FOCS that possess desired stability, sensitivity and selectivity for in-situ, rapid gas detection in the syngas streams from gasification and combustion flue gases. This report summarizes research works of two integrated parts: (1) development of metal oxide solid thin films as sensing materials for detection and measurement of important gas components relevant to the coal- and biomass-derived syngas and combustion gas streams at high temperatures; and (2) development of fiber optic devices that are potentially useful for constructing FOCS in combination with the solid oxide thin films identified in this program.

A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, July 1--September 30, 1995

Energy Technology Data Exchange (ETDEWEB)

Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

1995-12-01

The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. Some of the contract activities for this quarter are: We completed many of the analyses on the 81 samples received from HTI bench-scale run CMSL-9, in which coal, coal/mixed plastics, and coal/high density polyethylene were fed; Liquid chromatographic separations of the 15 samples in the University of Delaware sample set were completed; and WRI completed CP/MAS {sup 13}C-NMR analyses on the Delaware sample set.

Coal demonstration plants. Quarterly report, April--June 1977

Energy Technology Data Exchange (ETDEWEB)

None

1978-01-01

The objective of DOE's demonstration plant program is to establish the technical and financial feasibility of coal conversion technologies proven during pilot plant testing. Demonstration plants will minimize the technical and economic risks of commercialization by providing a near commercial size plant for testing and production. Thus, DOE is sponsoring the development of a series of demonstration plants, each of which will be a smaller version of commercial plants envisioned for the 1980's. These plants will be wholly integrated, self-sufficient in terms of heat generation, and dependent only on feedstock of coal, water, and air. Under the DOE program, contracts for designing, constructing, and operating the demonstration plants will be awarded through competitive procedures and will be jointly funded. The conceptual design phase will be funded by the government, with the detailed design, procurement, construction, and operation phases being co-funded, 50% from industry and 50% from the government. The cost involved in building and operating a demonstration plant will probably be between $200 million and $500 million, depending on the size of the plant. Six of these demonstration plant projects are described and progress in the quarter is summarized. Several support and complementary projects are described (fuel feeding system development, performance testing and comparative evaluation, engineering support, coal grinding equipment development and a critical components test facility). (LTN)

Origin of natural waters and gases within the Upper Carboniferous coal-bearing and autochthonous Miocene strata in South-Western part of the Upper Silesian Coal Basin, Poland

International Nuclear Information System (INIS)

Kotarba, Maciej J.; Pluta, Irena

2009-01-01

The molecular and stable isotope compositions of coalbed gases from the Upper Carboniferous strata and natural gases accumulated within the autochthonous Upper Miocene Skawina Formation of the Debowiec-Simoradz gas deposit were determined, as well as the chemical and stable isotope compositions of waters from the Skawina Formation and waters at the top of the Upper Carboniferous strata of the Kaczyce Ridge (the abandoned 'Morcinek' coal mine) in the South-Western part of the Upper Silesian Coal Basin. Two genetic types of natural gases within the Upper Carboniferous coal-bearing strata were identified: thermogenic (CH 4 , small amounts of higher gaseous hydrocarbons, and CO 2 ) and microbial (CH 4 , very small amounts of ethane, and CO 2 ). Thermogenic gases were generated during the bituminous stage of coalification and completed at the end of the Variscan orogeny. Degassing (desorption) of thermogenic gases began at the end of late Carboniferous until the late Miocene time-period and extended to the present-day. This process took place in the Upper Carboniferous strata up to a depth of about 550 m under the sealing Upper Miocene cover. A primary accumulation zone of indigenous, thermogenic gases is present below the degassing zone. Up to 200 m depth from the top of the Upper Carboniferous strata, within the weathered complex, an accumulation zone of secondary, microbial gas occurs. Waters within these strata are mainly of meteoric origin of the infiltration period just before the last sea transgression in the late Miocene and partly of marine origin having migrated from the Upper Miocene strata. Then, both methanogenic archaebacteria and their nutrients were transported by meteoric water into the near-surface Carboniferous strata where the generated microbial CH 4 saturated coal seams. Waters within the Miocene strata of the Debowiec-Simoradz and Zablocie are of marine origin, and natural gases accumulated within autochthonous Miocene strata of the Debowiec

Emission of toxic explosive and fire hazardous gases in coal piles stored under atmospheric conditions. Part I

International Nuclear Information System (INIS)

Grossman, S.L.; Cohen, H.

1998-01-01

Bituminous coal stockpiles stored in open air undergo weathering processes due to low temperature oxidation (40-100 degree C) resulting in quality deterioration. The process is accompanied by emission of hazardous explosive gases such as molecular hydrogen and low molecular weight organic gases. The article describes the process of low temperature oxidation of coal and goes on to report on simulation experiments carried out to assess the oxidation resistance of various coals stored in Israel, performed in small glass batch reactors and on the monitoring of temperatures and gas evolved in large coal piles stored in open air (performed using a portable unit which can penetrate up to 7 meters inside a coal pile). Molecular hydrogen emissions were found in small concentrations, in all types of coal studied. The amount of hydrogen formed in the batch reactors is linearly dependent on the amount of oxygen consumed in the coal oxidation process and also on the temperature. It was only slightly dependent on the coal mass and independent of particle size. Previous published work has only mentioned hydrogen emission at higher temperatures (240 degree C)

Preparation and evaluation of coal-derived activated carbons for removal of mercury vapor from simulated coal combustion flue fases

Science.gov (United States)

Hsi, H.-C.; Chen, S.; Rostam-Abadi, M.; Rood, M.J.; Richardson, C.F.; Carey, T.R.; Chang, R.

1998-01-01

Coal-derived activated carbons (CDACs) were tested for their suitability in removing trace amounts of vapor-phase mercury from simulated flue gases generated by coal combustion. CDACs were prepared in bench-scale and pilot-scale fluidized-bed reactors with a three-step process, including coal preoxidation, carbonization, and then steam activation. CDACs from high-organicsulfur Illinois coals had a greater equilibrium Hg0 adsorption capacity than activated carbons prepared from a low-organic-sulfur Illinois coal. When a low-organic-sulfur CDAC was impregnated with elemental sulfur at 600 ??C, its equilibrium Hg0 adsorption capacity was comparable to the adsorption capacity of the activated carbon prepared from the high-organicsulfur coal. X-ray diffraction and sulfur K-edge X-ray absorption near-edge structure examinations showed that the sulfur in the CDACs was mainly in organic forms. These results suggested that a portion of the inherent organic sulfur in the starting coal, which remained in the CDACs, played an important role in adsorption of Hg0. Besides organic sulfur, the BET surface area and micropore area of the CDACs also influenced Hg0 adsorption capacity. The HgCl2 adsorption capacity was not as dependent on the surface area and concentration of sulfur in the CDACs as was adsorption of Hg0. The properties and mercury adsorption capacities of the CDACs were compared with those obtained for commercial Darco FGD carbon.

Analysis of Index Gases of Coal Spontaneous Combustion Using Fourier Transform Infrared Spectrometer

Directory of Open Access Journals (Sweden)

Xiaojun Tang

2014-01-01

Full Text Available Analysis of the index gases of coal for the prevention of spontaneous combustion is of great importance for the enhancement of coal mine safety. In this work, Fourier Transform Infrared Spectrometer (FTIRS is presented to be used to analyze the index gases of coal in real time to monitor spontaneous combustion conditions. Both the instrument parameters and the analysis method are introduced at first by combining characteristics of the absorption spectra of the target analyte with the analysis requirements. Next, more than ten sets of the gas mixture containing ten components (CH4, C2H6, C3H8, iso-C4H10, n-C4H10, C2H4, C3H6, C2H2, CO, and CO2 are included and analyzed with a Spectrum Two FTIRS made by Perkin Elmer. The testing results show that the detection limit of most analytes is less than 2×10-6. All the detection limits meet the monitoring requirements of coal spontaneous combustion in China, which means that FTIRS may be an ideal instrument and the analysis method used in this paper is sufficient for spontaneous combustion gas monitoring on-line and even in situ, since FTIRS has many advantages such as fast analysis, being maintenance-free, and good safety.

Desulfurization and denitrogenation in copyrolysis of coal with hydrogen-rich gases

Energy Technology Data Exchange (ETDEWEB)

Liao, H.; Li, B.; Zhang, B. [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

1999-06-01

Desulfurization and denitrogenation were systematically investigated by analyzing the chars and tars from copyrolysis of Yanzhou high sulfur bituminous coal with coke-oven gas (COG), synthesis gas (SG) and hydrogen. The results indicated that under the conditions of 3MPa, up to 650{degree}C with a heating rate of 10{degree}C/min, the desulfurization of coal pyrolysis with COG, SG and hydrogen were almost equal (about 80%, w%, ad), the order of denitrogenation were: hydrogen (41%) {gt} SG(35%) {gt} COG(30%). The distributions of sulfur in char, oil and gas was very similar under the three reactive gases, i.e., about 205 in char, 105 in tar and 70% (diff.) in gas, respectively. Compared with hydropyrolysis at the same hydrogen partial pressure, the desulfurization of coal pyrolysis with coke oven gas was increased by about 4.5%, while the denitrogenation was decreased by about 3.5%. There is an important desulfurization advantage for hydropyrolysis using COG and SG instead of pure hydrogen. Compared with the copyrolysis of coal with COG, Yanzhou coal pyrolysis under SG can achieve the same level of desufurization but higher denitrogenation. 11 refs., 3 figs., 4 tabs.

Stable isotope composition of mercury forms in flue gases from a typical coal-fired power plant, Inner Mongolia, northern China

International Nuclear Information System (INIS)

Tang, Shunlin; Feng, Chaohui; Feng, Xinbin; Zhu, Jianming; Sun, Ruoyu; Fan, Huipeng; Wang, Lina; Li, Ruiyang; Mao, Tonghua; Zhou, Ting

2017-01-01

Highlights: • The first speciated Hg isotope ratios in coal combustion flue gases are presented. • Significant Hg isotope kinetic MDF was observed during Hg forms transformation. • Emitted gaseous Hg highly enriches in heavy Hg isotopes relative to feed coal. - Abstract: Mercury forms emitted from coal combustion via air pollution control devices are speculated to carry different Hg isotope signatures. Yet, their Hg isotope composition is still not reported. Here, we present the first onsite Hg isotope data for gaseous elemental Hg (GEM) and gaseous oxidized Hg (GOM) of flue gases from a typical lignite-fired power plant (CFPP). Significant mass dependent fractionation (MDF) and insignificant mass independent fractionation (MIF) are observed between feed coal and coal combustion products. As compared to feed coal (δ 202 Hg = −2.04 ± 0.25‰), bottom ash, GEM and GOM in flue gases before and after wet flue gas desulfurization system significantly enrich heavy Hg isotopes by 0.7–2.6‰ in δ 202 Hg, while fly ash, desulfurization gypsum and waste water show slight but insignificant enrichment of light Hg isotopes. GEM is significantly enriched heavy Hg isotopes compared to GOM and Hg in fly ash. Our observations verify the previous speculation on Hg isotope fractionation mechanism in CFPPs, and suggest a kinetically-controlled mass dependent Hg isotope fractionation during transformation of Hg forms in flue gases. Finally, our data are compared to Hg isotope compositions of atmospheric Hg pools, suggesting that coal combustion Hg emission is likely an important atmospheric Hg contributor.

Stable isotope composition of mercury forms in flue gases from a typical coal-fired power plant, Inner Mongolia, northern China

Energy Technology Data Exchange (ETDEWEB)

Tang, Shunlin, E-mail: tangshunlin@hpu.edu.cn [Institute of Resources and Environment, Henan Polytechnic University, Jiaozuo, Henan Province, 454000 (China); Feng, Chaohui [Institute of Resources and Environment, Henan Polytechnic University, Jiaozuo, Henan Province, 454000 (China); Feng, Xinbin [State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550002 (China); Zhu, Jianming [Institute of Resources and Environment, Henan Polytechnic University, Jiaozuo, Henan Province, 454000 (China); State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing, 100086 (China); Sun, Ruoyu, E-mail: ruoyu.sun@tju.edu.cn [CAS Key Laboratory of Crust-Mantle Materials and Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui 230026 (China); Fan, Huipeng; Wang, Lina; Li, Ruiyang; Mao, Tonghua [Institute of Resources and Environment, Henan Polytechnic University, Jiaozuo, Henan Province, 454000 (China); Zhou, Ting [State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550002 (China)

2017-04-15

Highlights: • The first speciated Hg isotope ratios in coal combustion flue gases are presented. • Significant Hg isotope kinetic MDF was observed during Hg forms transformation. • Emitted gaseous Hg highly enriches in heavy Hg isotopes relative to feed coal. - Abstract: Mercury forms emitted from coal combustion via air pollution control devices are speculated to carry different Hg isotope signatures. Yet, their Hg isotope composition is still not reported. Here, we present the first onsite Hg isotope data for gaseous elemental Hg (GEM) and gaseous oxidized Hg (GOM) of flue gases from a typical lignite-fired power plant (CFPP). Significant mass dependent fractionation (MDF) and insignificant mass independent fractionation (MIF) are observed between feed coal and coal combustion products. As compared to feed coal (δ{sup 202}Hg = −2.04 ± 0.25‰), bottom ash, GEM and GOM in flue gases before and after wet flue gas desulfurization system significantly enrich heavy Hg isotopes by 0.7–2.6‰ in δ{sup 202}Hg, while fly ash, desulfurization gypsum and waste water show slight but insignificant enrichment of light Hg isotopes. GEM is significantly enriched heavy Hg isotopes compared to GOM and Hg in fly ash. Our observations verify the previous speculation on Hg isotope fractionation mechanism in CFPPs, and suggest a kinetically-controlled mass dependent Hg isotope fractionation during transformation of Hg forms in flue gases. Finally, our data are compared to Hg isotope compositions of atmospheric Hg pools, suggesting that coal combustion Hg emission is likely an important atmospheric Hg contributor.

Dew point measurements of flue gases in steam generators with brown coal combustion

Energy Technology Data Exchange (ETDEWEB)

Schinkel, W.

1980-01-01

This paper examines empirical data on sulfuric acid condensation and resulting internal corrosion in brown coal fired steam generators. Due to the high sulfur content in brown coal (0.5% to 5.0%) and relative short duration of the gases in the combustion chamber the concentrations of sulfur trioxide present in the flue gases can condense at the heat exchange surfaces of the steam generators. A number of diagrams show sulfuric acid dew point temperatures depending on brown coal sulfur content, the influence of combustion air supply on the dew point, and condensing speed and the rate of corrosion in relation to different heat exchange surface temperatures. The conclusion is made that a five-fold increase in corrosion can be caused by a 10 K higher flue gas dew point, a 5 K cooling of heating surfaces can also cause heavy corrosion at a certain dew point. Maximum corrosion results at 20 to 50 K differences between flue gas dew point and heat exchange surfaces. Optimum operation of steam generators with minimal internal corrosion requires the consideration of flue gas and heating surface temperatures as well as flue gas sulfur acid dew points. (10 refs.) (In German)

Coal demonstration plants. Quarterly report, July--September 1977

Energy Technology Data Exchange (ETDEWEB)

None

1978-02-01

The objective of DOE's demonstration plant program is to establish the technical and financial feasibility of coal conversion technologies proven during pilot plant testing. Demonstration plants will minimize the technical and economic risks of commercialization by providing a near commercial size plant for testing and production. Thus, DOE is sponsoring the development of a series of demonstration plants, each of which will be a smaller version of commercial plants envisioned for the 1980's. These plants will be wholly integrated, self-sufficient in terms of heat generation, and dependent only on feedstock of coal, water, and air. Contracts for designing, constructing, and operating the demonstration plants will be awarded through competitive procedures and will be jointly funded. The conceptual design phase will be funded by the government, with the detailed design, procurement, construction, and operation phases being co-funded, 50% from industry and 50% from the government. The cost involved in building and operating a demonstration plant will probably be between $200 million and $500 million, depending on the size of the plant. Twenty-two projects involving demonstration plants or support projects for such plants are reviewed, including a summary for each of progress in the quarter. (LTN)

The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report Number 8, 1 July, 1993--30 September, 1993

Energy Technology Data Exchange (ETDEWEB)

1993-10-01

Task 1, the preparation of catalyst materials, is proceeding actively. At WVU, catalysts based on Mo are being prepared using a variety of approaches to alter the oxidation state and environment of the Mo. At UCC and P, copper-based zinc chromite spinel catalysts will be prepared and tested. The modeling of the alcohol-synthesis reaction in a membrane reactor is proceeding actively. Under standard conditions, pressure drop in the membrane reactor has been shown to be negligible. In Task 2, base case designs had previously been completed with a Texaco gasifier. Now, similar designs have been completed using the Shell gasifier. A comparison of the payback periods or production cost of these plants shows significant differences among the base cases. However, a natural gas only design, prepared for comparison purposes, gives a lower payback period or production cost. Since the alcohol synthesis portion of the above processes is the same, the best way to make coal-derived higher alcohols more attractive economically than natural gas-derived higher alcohols is by making coal-derived syngas less expensive than natural gas-derived syngas. The maximum economically feasible capacity for a higher alcohol plant from coal-derived syngas appears to be 32 MM bbl/yr. This is based on consideration of regional coal supply in the eastern US, coal transportation, and regional product demand. The benefits of economics of scale are illustrated for the base case designs. A value for higher alcohol blends has been determined by appropriate combination of RVP, octane number, and oxygen content, using MTBE as a reference. This analysis suggests that the high RVP of methanol in combination with its higher water solubility make higher alcohols more valuable than methanol.

75 FR 39735 - Mandatory Reporting of Greenhouse Gases From Magnesium Production, Underground Coal Mines...

Science.gov (United States)

2010-07-12

... sectors of the economy, including fossil fuel suppliers, industrial gas suppliers, and direct emitters of... Part II Environmental Protection Agency 40 CFR Part 98 Mandatory Reporting of Greenhouse Gases From Magnesium Production, Underground Coal Mines, Industrial Wastewater Treatment, and Industrial...

Thermodynamic model for swelling of unconfined coal due to adsorption of mixed gases

NARCIS (Netherlands)

Liu, J.; Peach, C.J.; Zhou, Hongwei; Spiers, C.J.

2015-01-01

Permeability evolution in coal seams during CO2-Enhanced Coalbed Methane (ECBM) production is strongly influenced by swelling/shrinkage effects related to sorption and desorption of both CO2 and CH4. Other gases, such as N2, have also been proposed for injection in ECBM operations. In addition,

Quarter 9 Mercury information clearinghouse final report

Energy Technology Data Exchange (ETDEWEB)

Laudal, D.L.; Miller, S.; Pflughoeft-Hassett, D.; Ralston, N.; Dunham, G.; Weber, G.

2005-12-15

The Canadian Electricity Association (CEA) identified a need and contracted the Energy & Environmental Research Center (EERC) to create and maintain an information clearinghouse on global research and development activities related to mercury emissions from coal-fired electric utilities. A total of eight reports were completed and are summarized and updated in this final CEA quarterly report. Selected topics were discussed in detail in each quarterly report. Issues related to mercury from coal-fired utilities include the general areas of measurement, control, policy, and transformations. Specific topics that have been addressed in previous quarterly reports include the following: Quarterly 1 - Sorbent Control Technologies for Mercury Control; Quarterly 2 - Mercury Measurement; Quarterly 3 - Advanced and Developmental Mercury Control Technologies; Quarterly 4 - Prerelease of Mercury from Coal Combustion By-Products; Quarterly 5 - Mercury Fundamentals; Quarterly 6 - Mercury Control Field Demonstrations; Quarterly 7 - Mercury Regulations in the United States: Federal and State; and Quarterly 8 - Commercialization Aspects of Sorbent Injection Technologies in Canada. In this last of nine quarterly reports, an update of these mercury issues is presented that includes a summary of each topic, with recent information pertinent to advances made since the quarterly reports were originally presented. In addition to a comprehensive update of previous mercury-related topics, a review of results from the CEA Mercury Program is provided. 86 refs., 11 figs., 8 tabs.

Influence of the gray gases number in the weighted sum of gray gases model on the radiative heat exchange calculation inside pulverized coal-fired furnaces

Directory of Open Access Journals (Sweden)

Crnomarković Nenad Đ.

2016-01-01

Full Text Available The influence of the number of gray gases in the weighted sum in the gray gases model on the calculation of the radiative heat transfer is discussed in the paper. A computer code which solved the set of equations of the mathematical model describing the reactive two-phase turbulent flow with radiative heat exchange and with thermal equilibrium between phases inside the pulverized coal-fired furnace was used. Gas-phase radiative properties were determined by the simple gray gas model and two combinations of the weighted sum of the gray gases models: one gray gas plus a clear gas and two gray gases plus a clear gas. Investigation was carried out for two values of the total extinction coefficient of the dispersed phase, for the clean furnace walls and furnace walls covered by an ash layer deposit, and for three levels of the approximation accuracy of the weighting coefficients. The influence of the number of gray gases was analyzed through the relative differences of the wall fluxes, wall temperatures, medium temperatures, and heat transfer rate through all furnace walls. The investigation showed that there were conditions of the numerical investigations for which the relative differences of the variables describing the radiative heat exchange decrease with the increase in the number of gray gases. The results of this investigation show that if the weighted sum of the gray gases model is used, the complexity of the computer code and calculation time can be reduced by optimizing the number of gray gases. [Projekat Ministarstva nauke Republike Srbije, br. TR-33018: Increase in energy and ecology efficiency of processes in pulverized coal-fired furnace and optimization of utility steam boiler air preheater by using in-house developed software tools

SYNTHESIS OF METHACRYLATES FROM COAL-DERIVED SYNGAS

Energy Technology Data Exchange (ETDEWEB)

Jang, B.W.L.; Spivey, J.J.; Gogate, M.R.; Zoeller, J.R.; Colberg, R.D.; Choi, G.N.

1999-12-01

Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel have developed a novel process for synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the US Department of Energy/Fossil Energy Technology Center (DOE/FETC). This project has resulted in five US patents (four already published and one pending publication). It has served as the basis for the technical and economic assessment of the production of this high-volume intermediate from coal-derived synthesis gas. The three-step process consists of the synthesis of a propionate from ethylene carbonylation using coal-derived CO, condensation of the propionate with formaldehyde to form methacrylic acid (MAA); and esterification of MAA with methanol to yield MMA. The first two steps, propionate synthesis and condensation catalysis, are the key technical challenges and the focus of the research presented here.

Coal mining situation in the Federal Republic of Germany. The 1st quarter 2016; Zur Lage des Kohlenbergbaus in der Bundesrepublik Deutschland. 1. Vierteljahr 2016

Energy Technology Data Exchange (ETDEWEB)

NONE

2016-06-06

The paper reports on the coal mining in the Federal Republic of Germany in the 1st quarter of 2016. Statistical data are presented for mining, exports and imports of hard coal and lignite and for employees.

Coal mining situation in the Federal Republic of Germany. The 1st quarter 2017; Zur Lage des Kohlenbergbaus in der Bundesrepublik Deutschland. 1. Vierteljahr 2017

Energy Technology Data Exchange (ETDEWEB)

NONE

2017-06-14

The paper reports on the coal mining in the Federal Republic of Germany in the 1st quarter of 2017. Statistical data are presented for mining, exports and imports of hard coal and lignite and for employees.

Coal mining situation in the Federal Republic of Germany. The 1st quarter 2015; Zur Lage des Kohlenbergbaus in der Bundesrepublik Deutschland. 1. Vierteljahr 2015

Energy Technology Data Exchange (ETDEWEB)

NONE

2015-07-07

The paper reports on the coal mining in the Federal Republic of Germany in the 1st quarter of 2015. Statistical data are presented for mining, exports and imports of hard coal and lignite and for employees.

Geochemical characteristics of Carboniferous-Permian coal-formed gas in Bohai Bay Basin

Energy Technology Data Exchange (ETDEWEB)

Shipeng Huang; Fengrong Liao; Xiaoqi Wu [PetroChina, Beijing (China). Research Institute of Petroleum Exploration & Development

2010-03-15

Coal-formed gas reservoirs have been found in several depressions in Bohai Bay Basin. The gas was mainly generated by the Carboniferous-Permian coal measures, which are good source rocks. The exploration of coal-formed gas has a broad prospect. The main reservoirs of the coal-formed gas are Ordovician, Carboniferous-Permian, and Paleogene stratum. Coal-formed gas in the Bohai Bay Basin is chiefly composed of hydrocarbon gases. The percentage content of carbon dioxide is more than that of the nitrogen gas. The stable carbon isotope values of the hydrocarbon gases of different depressions and different reservoirs usually reversed. The reversed values of gas samples account for 52.1% of all the samples. Reversion values of the carbon isotope are mainly because of the mixing of gases from same source rocks but with different maturity. Among the three main reservoirs, coal-formed gas preserved in Paleogene stratum has the heaviest carbon isotope, the second is the gas in Carboniferous-Permian stratum, and the Ordovician gas possesses the lightest carbon isotope. Based on the analysis of the characteristics of carbon isotope of hydrocarbon gases in well Qishen-1 and the distribution of the Carboniferous-Permian coal measures, the gas of the well is derived from the high-matured Carboniferous-Permian coal measures.

Competitive reaction in hydrodenitrogenation and hydrodeoxygenation of coal-derived naphtha

Energy Technology Data Exchange (ETDEWEB)

Machida, M. (Idemitsu Kosan Co. Ltd., Tokyo (Japan). Central Research Lab.); Sakao, Y.; Ono, S. (Idemitsu Kosan Co. Ltd., Tokyo (Japan))

1994-03-01

The naphtha fraction derived from coal is expected to be one of the most suitable blending stocks for motor gasoline because of its high contents of cyclic hydrocarbons. However, since the contents of nitrogen and oxygen are high in the coal naphtha, the amounts of these elements must be reduced to acceptable levels. In this study, aiming to clarify the hydrodenitrogenation (HDN) and hydrodeoxygenation (HDO) performances of practical feed stocks, HDN and HDO of coal-derived naphtha and its model compounds were examined by using a catalyst Ni-Mo/Al2O3 group. There are tree types of nitrogen compounds, pyridine, pyrrole and aniline, in the coal-derived naphtha. Aniline type nitrogen compounds in the coal-derived naphtha are more resistant to HDN than pyridine type compounds, though aniline is more reactive than pyridine when the reaction is carried out individually. 14 refs., 7 figs., 3 tabs.

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

Energy Technology Data Exchange (ETDEWEB)

Dady B. Dadyburjor; Mark E. Heavner; Manoj Katakdaunde; Liviu Magean; J. Joshua Maybury; Alfred H. Stiller; Joseph M. Stoffa; John W. Zondlo

2006-08-01

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, and porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, hydrotreatment of solvent was completed in preparation for pitch fabrication for graphite electrodes. Coal digestion has lagged but is expected to be complete by next quarter. Studies are reported on coal dissolution, pitch production, foam synthesis using physical blowing agents, and alternate coking techniques.

A CHARACTERIZATION AND EVALUATION OF COAL LIQUEFACTION PROCESS STREAMS

International Nuclear Information System (INIS)

G.A. Robbins; R.A. Winschel; S.D. Brandes

1999-01-01

This is the first Annual Technical Report of activities under DOE Contract No. DE-AC22-94PC93054. Activities from the first three quarters of the fiscal 1998 year were reported previously as Quarterly Technical Progress Reports (DOE/PC93054-57, DOE/PC93054-61, and DOE/PC93054-66). Activities for the period July 1 through September 30, 1998, are reported here. This report describes CONSOL's characterization of process-derived samples obtained from HTI Run PB-08. These samples were derived from operations with Black Thunder Mine Wyoming subbituminous coal, simulated mixed waste plastics, and pyrolysis oils derived from waste plastics and waste tires. Comparison of characteristics among the PB-08 samples was made to ascertain the effects of feed composition changes. A comparison also was made to samples from a previous test (Run PB-06) made in the same processing unit, with Black Thunder Mine coal, and in one run condition with co-fed mixed plastics

NOVEL SLURRY PHASE DIESEL CATALYSTS FOR COAL-DERIVED SYNGAS

Energy Technology Data Exchange (ETDEWEB)

Dr. Dragomir B. Bukur; Dr. Ketil Hanssen; Alec Klinghoffer; Dr. Lech Nowicki; Patricia O' Dowd; Dr. Hien Pham; Jian Xu

2001-01-07

This report describes research conducted to support the DOE program in novel slurry phase catalysts for converting coal-derived synthesis gas to diesel fuels. The primary objective of this research program is to develop attrition resistant catalysts that exhibit high activities for conversion of coal-derived syngas.

Molecular accessibility in solvent swelled coals. Quarterly report, [September--November, 1993

Energy Technology Data Exchange (ETDEWEB)

Kispert, L.D.

1993-11-01

This quarter, experiments were performed on the use of binary swelling solvents in molecular accessibility in coal conversion. These experiments consisted of accessibility measurements of spin probe VII (TEMPAMINE) in Toluene swelled Illinois No. 6 APCS coal. The toluene was spiked with amounts of pyridine which ranged in concentration from 500 ppm to 10%. The experiments were done in triplicate to gain information about the experimental error involved in the procedure. It was shown that oscillations occur in the concentration of spin probe retained as the amount of pyridine that is added to the swelling solvent is increased. These oscillations decrease in intensity as the concentration of pyridine in the solvent solution is increased up to 2% pyridine (0.2mLs pyridine in 10mLs toluene). From a 2% pyridine concentration to a 5% concentration, there is no significant change in the retention of spin probe VII. An increase in retention is observed when the concentration of pyridine is increased to 6% and 7% successively, followed by a large decrease at 8% and 9% pyridine. The largest changes in spin probe retention are observed for concentrations of pyridine less than 0.5%. A three fold increase in spin probe retention is observed upon the addition of 500 ppm pyridine in the toluene swelling solvent, which indicates that small amounts of a strong swelling solvent could be used to improve molecular accessibility 91% in coals swelled in an otherwise weak swelling solvent.

Application of zeolite-based catalyst to hydrocracking of coal-derived liquids

Energy Technology Data Exchange (ETDEWEB)

Shimada, H.; Sato, T.; Yoshimura, Y.; Hinata, A.; Yoshitomi, S.; Castillo Mares, A.; Nishijima, A. (National Chemical Laboratory for Industry, Tsukuba (Japan))

1990-06-01

Y-zeolite supported catalysts were applied to the hydrocracking of coal-derived liquids. By the introduction of two-stage upgrading consisting of hydrotreating and hydrocracking, Wandoan coal-derived middle distillate was hydrocracked over Ni-Mo/Y-zeolite, producing a high gasoline fraction yield. Zeolite supported catalysts gave little hydrocracked compounds in the hydroprocessing of coal-derived heavy oils, even after hydrotreatment. The reaction inhibitors which seriously poison the active sites of zeolites were found to be small nitrogen-containing molecules. In the hydroprocessing of coal-derived heavy oils, zeolite supported catalysts were inferior to alumina supported catalysts. This is due to the high hydrocracking but low hydrogenation activity of zeolite supported catalysts. 22 refs., 5 figs., 11 tabs.

Production and screening of carbon products precursors from coal. Quarterly progress report, July 1, 1996--September 30, 1996

Energy Technology Data Exchange (ETDEWEB)

Zondlo, J.; Stiller, A.

1996-10-25

This quarterly report covers activities during the period from July 1, 1996 through September 30, 1996 on the development of carbon products precursor materials from coal. The first year of the project ended in February, 1996; however, the WVU research effort continued through August 14, 1997 on a no-cost extension of the original contract. PETC chose to exercise the option for continuation of the projects and $100,000 became available on August 9, 1996. The objective for year two is to focus on development of those carbon products from coal-based solvent extract precursors which have the greatest possibility for commercial success.

Study on the Concentration Measurement of the Pollution Gases from Coal-Fired Power Station

International Nuclear Information System (INIS)

Zheng, L J; Li, W

2006-01-01

CO 2 is a main kind of pollution gases discharged from coal-fired power station. The relationship between gas concentration and pressure, temperature is deduced base on the law of Beer-Lambert and the theory of gas line-shape. The tunable diode laser spectral technology is used to analyze the changing regularity of the peak, half-peak width of the absorption curve with pressure and temperature

Primary migration of Jurassic coal-derived oil in Santanghu basin

Energy Technology Data Exchange (ETDEWEB)

Zhang, W.; Zhong, N.; Ren, D. [China University of Mining and Technology, Beijing (China). Dept of Resource Exploitation Engineering

2000-11-01

It is known that the differential evolution of the multiple macerals results in 'oil generation by stage', and that 'early generation, early expulsion' is one of the preconditions for the efficient accumulation of the coal-derived oil. Based upon the study on the evolution of the physical properties, related to the hydrocarbon expulsion, of the Jurassic organic rock in Santanghu basin during the course of maturation, the mechanism of the primary migration of its coal-derived oil was discussed. The rapid loss of the inherent moisture in the organic rock was not accordant with the main generation stage of the coal-derived oil, so it was unrealistic that the oil migrated by dissolution in the expelled water. It is thought that the special forming mechanism of the continuous 'bitumen network' under the condition of over-pressure and an earlier history of primary migration may be essential to the Jurassic coal-derived oil in Santanghu basin. 17 refs., 4 figs.

Dry sorbent injection of trona to control acid gases from a pilot-scale coal-fired combustion facility

Directory of Open Access Journals (Sweden)

Tiffany L. B. Yelverton

2016-01-01

Full Text Available  Gaseous and particulate emissions from the combustion of coal have been associated with adverse effects on human and environmental health, and have for that reason been subject to regulation by federal and state governments. Recent regulations by the United States Environmental Protection Agency have further restricted the emissions of acid gases from electricity generating facilities and other industrial facilities, and upcoming deadlines are forcing industry to consider both pre- and post-combustion controls to maintain compliance. As a result of these recent regulations, dry sorbent injection of trona to remove acid gas emissions (e.g. HCl, SO2, and NOx from coal combustion, specifically 90% removal of HCl, was the focus of the current investigation. Along with the measurement of HCl, SO2, and NOx, measurements of particulate matter (PM, elemental (EC, and organic carbon (OC were also accomplished on a pilot-scale coal-fired combustion facility. Gaseous and particulate emissions from a coal-fired combustor burning bituminous coal and using dry sorbent injection were the focus of the current study. From this investigation it was shown that high levels of trona were needed to achieve the goal of 90% HCl removal, but with this increased level of trona injection the ESP and BH were still able to achieve greater than 95% fine PM control. In addition to emissions reported, measurement of acid gases by standard EPA methods were compared to those of an infrared multi-component gas analyzer. This comparison revealed good correlation for emissions of HCl and SO2, but poor correlation in the measurement of NOx emissions.

Coal rebounds for the final quarter

Energy Technology Data Exchange (ETDEWEB)

Soras, C.; Stodden, J.

1987-11-01

Coal production in the USA is up 0.3% by the end of September 1987 from the pace of one year ago. Most impressive has been the growth in demand at power plants where coal consumption is up by 13.5 million tons through the month of July. The coal markets turnabout is based upon the entire economic spectrum not upon a single large market. US steel mills represent intense power consuming activities as do the US chemicals, plastics, paper and pulp industries.

Improving the stability of coal slurries: Quarterly progress report for the period Sep. 15, 1986-Dec. 15, 1986. [Adsorption of gum tragacanth on coal particles

Energy Technology Data Exchange (ETDEWEB)

Fogler, H.S.

1986-01-01

The last quarterly progress report focused on the adsorption study of the polystyrene latex spheres with gum tragacanth (GT), and the adsorption mechanism was found to be hydrophobic rather than electrostatic. Also, the effect of the amount of GT adsorbed, the bulk concentration of GT, incubation time and pH on the stability factor was examined, and the results indicated that the conformation of GT on the surface of latex spheres plays an important role in the stabilization. This report presents the results of the coal-water slurries, mainly focusing on the adsorption study of GT by changing pH and ionic strength. It was found from the experiment in which the ionic strength was changed that the adsorption of GT on the coal particles is hindered by the coulombic repulsion between GT and coal. In addition, the experiment in which pH was changed also indicated that the adsorption mechanism is electrostatic in nature. 7 refs., 2 figs.

Power systems development facility. Quarterly technical progress report, January 1, 1994--March 31, 1994

Energy Technology Data Exchange (ETDEWEB)

1994-07-01

This quarterly technical progress report summarizes work completed during the last quarter of the Second Budget Period, January 1 through March 31, 1994, entitled {open_quotes}Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.{close_quotes} The objective of this project is to evaluate hot gas particulate control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size.

Chemistry and structure of coal-derived asphaltenes, Phase III. Quarterly progress report, April--June 1978

Energy Technology Data Exchange (ETDEWEB)

Yen, T. F.

1978-01-01

Solubility parameters may be calculated for coal liquid derived products by use of a semi-empirical relationship between solubility parameter and refractive index. Thermal treatment of Synthoil coal liquid oil + resin solvent fraction at 235 to 300/sup 0/C resulted in the transformation of oil and resin into asphaltene. Further support of structural characterizations was obtained by use of a combined x-ray and NMR structural characterization procedure which relies on the important x-ray structural parameter L/sub a/ (average layer diameter of the aromatic sheet). L/sub a/ values of approx. = 8 to 10 A for asphaltenes, approx. = 13.4 to 14 A for carbenes, and approx. = 14 to 16.5 A for carboids were obtained by the x-ray procedure. These data were used to calculate C/sub Au/ (aromatic carbons per structural unit) and N (number of structural units per molecule) values. For asphaltenes the results agree with those previously deduced from NMR and other techniques. The C/sub Au/ values are generally close to 14 which is the number of aromatic carbons present in a 3-ring kata-system such as anthracene or phenanthrene. The number of structural units per molecule is close to two for all the asphaltenes. Additional data were used to improve the correlation equation between weight percent OH, determined by the silylation method, and the absorbance of the monomeric OH infrared stretching band at 3600 cm/sup -1/ for asphaltenes. A similar correlation between weight percent NH, from elemental analysis of asphaltene samples containing essentially all nitrogen as pyrrolic N-H, and the infrared absorbance of the N-H stretching band at 3470 cm/sup -1/ was developed for asphaltenes.

Properties and Developments of Combustion and Gasification of Coal and Char in a CO2-Rich and Recycled Flue Gases Atmosphere by Rapid Heating

Directory of Open Access Journals (Sweden)

Zhigang Li

2012-01-01

Full Text Available Combustion and gasification properties of pulverized coal and char have been investigated experimentally under the conditions of high temperature gradient of order 200°C·s−1 by a CO2 gas laser beam and CO2-rich atmospheres with 5% and 10% O2. The laser heating makes a more ideal experimental condition compared with previous studies with a TG-DTA, because it is able to minimize effects of coal oxidation and combustion by rapid heating process like radiative heat transfer condition. The experimental results indicated that coal weight reduction ratio to gases followed the Arrhenius equation with increasing coal temperature; further which were increased around 5% with adding H2O in CO2-rich atmosphere. In addition, coal-water mixtures with different water/coal mass ratio were used in order to investigate roles of water vapor in the process of coal gasification and combustion. Furthermore, char-water mixtures with different water/char mass ratio were also measured in order to discuss the generation ratio of CO/CO2, and specified that the source of Hydrocarbons is volatile matter from coal. Moreover, it was confirmed that generations of CO and Hydrocarbons gases are mainly dependent on coal temperature and O2 concentration, and they are stimulated at temperature over 1000°C in the CO2-rich atmosphere.

A permeability model for coal and other fractured, sorptive-elastic media

Energy Technology Data Exchange (ETDEWEB)

Robertson, E.P.; Christiansen, R.L. [Marathon Oil Co., Houston, TX (United States). Research & Development Facility

2008-09-15

This paper describes the derivation of a new equation that can be used to model the permeability behavior of a fractured, sorptive-elastic medium, such as coal, under variable stress conditions. The equation is applicable to confinement pressure schemes commonly used during the collection of permeability data in the laboratory. The model is derived for cubic geometry under biaxial or hydrostatic confining pressures. The model is designed to handle changes in permeability caused by adsorption and desorption of gases onto and from the matrix blocks in fractured media. The model equations can be used to calculate permeability changes caused by the production of methane (CH{sub 4}) from coal as well as the injection of gases, such as carbon dioxide, for sequestration in coal. Sensitivity analysis of the model found that each of the input variables can have a significant impact on the outcome of the permeability forecast as a function of changing pore pressure, thus, accurate input data are essential. The permeability model also can be used as a tool to determine input parameters for field simulations by curve fitting laboratory-generated permeability data. The new model is compared to two other widely used coal-permeability models using a hypothetical coal with average properties.

Zinc isotopic composition of particulate matter generated during the combustion of coal and coal + tire-derived fuels

Science.gov (United States)

Borrok, D.M.; Gieré, R.; Ren, M.; Landa, E.R.

2010-01-01

Atmospheric Zn emissions from the burning of coal and tire-derived fuel (TDF) for power generation can be considerable. In an effort to lay the foundation for tracking these contributions, we evaluated the Zn isotopes of coal, a mixture of 95 wt % coal + 5 wt % TDF, and the particulate matter (PM) derived from their combustion in a power-generating plant. The average Zn concentrations and δ(66)Zn were 36 mg/kg and 183 mg/kg and +0.24‰ and +0.13‰ for the coal and coal + TDF, respectively. The δ(66)Zn of the PM sequestered in the cyclone-type mechanical separator was the lightest measured, -0.48‰ for coal and -0.81‰ for coal+TDF. The δ(66)Zn of the PM from the electrostatic precipitator showed a slight enrichment in the heavier Zn isotopes relative to the starting material. PM collected from the stack had the heaviest δ(66)Zn in the system, +0.63‰ and +0.50‰ for the coal and coal + TDF, respectively. Initial fractionation during the generation of a Zn-rich vapor is followed by temperature-dependent fractionation as Zn condenses onto the PM. The isotopic changes of the two fuel types are similar, suggesting that their inherent chemical differences have only a secondary impact on the isotopic fractionation process.

Use of pyrolysis gases from biogenic fuels as reductionfuels in coal dust furnaces; Einsatz von Pyrolysegasen aus biogenen Brennstoffen als Reduktionsbrennstoff in Kohlestaubfeuerungen

Energy Technology Data Exchange (ETDEWEB)

Ruediger, H; Greul, U; Spliethoff, H; Hein, K R.G. [Stuttgart Univ. (Germany). Inst. fuer Verfahrenstechnik und Dampfkesselwesen (IVD)

1997-12-31

Co-combustion of refuse-derived fuels in the form of pyrolysis gases, with coal as primary fuel, has advantages in terms of fuel ash separation and nitric oxide emissions. Biomass or sewage sludge is degassed in a pyrolysis reactor, and the gas is used as secondary fuel in a coal dust furnace. The authors investigated the influence of reaction temperature, fuel moisture and reaction atmosphere in the pyrolysis stage on the product fractions gas, tar, and residual fuel, as well as the suitability of the resulting pyrolysis gas as secondary fuel in a coal dust furnace for the purpose of reducing nitric oxide emissions. (orig) [Deutsch] Ein am IVD betriebenes Konzept der Mitverbrennung von Brennstoffen in Form von Pyrolysegasen bietet Vorteile bezueglich der Trennung der Brennstoffaschen und Stickoxidemissionen bei der Feuerung des Primaerbrennstoffes Steinkohle. Biomasse oder Klaerschlamm wird hierbei in einem Pyrolysereaktor engast und gasfoermig als Sekundaerbrennstoff in einer Kohlenstaubfeuerung eingesetzt. Untersuchungsschwerpunkte in der Pyrolysestufe des Prozesses waren die Einfluesse von Reaktionstemperatur, Brennstofffeuchte und Reaktionsatmosphaere auf die Produktfraktionen Gas, Teer und Restbrennstoff sowie die Eignung des erzeugten Pyrolysegases als Sekundaerbrennstoff in einer Kohlenstaubfeuerung zur Senkung derKohlendioxidemissione. (orig)

Use of pyrolysis gases from biogenic fuels as reductionfuels in coal dust furnaces; Einsatz von Pyrolysegasen aus biogenen Brennstoffen als Reduktionsbrennstoff in Kohlestaubfeuerungen

Energy Technology Data Exchange (ETDEWEB)

Ruediger, H.; Greul, U.; Spliethoff, H.; Hein, K.R.G. [Stuttgart Univ. (Germany). Inst. fuer Verfahrenstechnik und Dampfkesselwesen (IVD)

1996-12-31

Co-combustion of refuse-derived fuels in the form of pyrolysis gases, with coal as primary fuel, has advantages in terms of fuel ash separation and nitric oxide emissions. Biomass or sewage sludge is degassed in a pyrolysis reactor, and the gas is used as secondary fuel in a coal dust furnace. The authors investigated the influence of reaction temperature, fuel moisture and reaction atmosphere in the pyrolysis stage on the product fractions gas, tar, and residual fuel, as well as the suitability of the resulting pyrolysis gas as secondary fuel in a coal dust furnace for the purpose of reducing nitric oxide emissions. (orig) [Deutsch] Ein am IVD betriebenes Konzept der Mitverbrennung von Brennstoffen in Form von Pyrolysegasen bietet Vorteile bezueglich der Trennung der Brennstoffaschen und Stickoxidemissionen bei der Feuerung des Primaerbrennstoffes Steinkohle. Biomasse oder Klaerschlamm wird hierbei in einem Pyrolysereaktor engast und gasfoermig als Sekundaerbrennstoff in einer Kohlenstaubfeuerung eingesetzt. Untersuchungsschwerpunkte in der Pyrolysestufe des Prozesses waren die Einfluesse von Reaktionstemperatur, Brennstofffeuchte und Reaktionsatmosphaere auf die Produktfraktionen Gas, Teer und Restbrennstoff sowie die Eignung des erzeugten Pyrolysegases als Sekundaerbrennstoff in einer Kohlenstaubfeuerung zur Senkung derKohlendioxidemissione. (orig)

Fuel saving, carbon dioxide emission avoidance, and syngas production by tri-reforming of flue gases from coal- and gas-fired power stations, and by the carbothermic reduction of iron oxide

International Nuclear Information System (INIS)

Halmann, M.; Steinfeld, A.

2006-01-01

Flue gases from coal, gas, or oil-fired power stations, as well as from several heavy industries, such as the production of iron, lime and cement, are major anthropogenic sources of global CO 2 emissions. The newly proposed process for syngas production based on the tri-reforming of such flue gases with natural gas could be an important route for CO 2 emission avoidance. In addition, by combining the carbothermic reduction of iron oxide with the partial oxidation of the carbon source, an overall thermoneutral process can be designed for the co-production of iron and syngas rich in CO. Water-gas shift (WGS) of CO to H 2 enables the production of useful syngas. The reaction process heat, or the conditions for thermoneutrality, are derived by thermochemical equilibrium calculations. The thermodynamic constraints are determined for the production of syngas suitable for methanol, hydrogen, or ammonia synthesis. The environmental and economic consequences are assessed for large-scale commercial production of these chemical commodities. Preliminary evaluations with natural gas, coke, or coal as carbon source indicate that such combined processes should be economically competitive, as well as promising significant fuel saving and CO 2 emission avoidance. The production of ammonia in the above processes seems particularly attractive, as it consumes the nitrogen in the flue gases

Alkaloid-derived molecules in low rank Argonne premium coals.

Energy Technology Data Exchange (ETDEWEB)

Winans, R. E.; Tomczyk, N. A.; Hunt, J. E.

2000-11-30

Molecules that are probably derived from alkaloids have been found in the extracts of the subbituminous and lignite Argonne Premium Coals. High resolution mass spectrometry (HRMS) and liquid chromatography mass spectrometry (LCMS) have been used to characterize pyridine and supercritical extracts. The supercritical extraction used an approach that has been successful for extracting alkaloids from natural products. The first indication that there might be these natural products in coals was the large number of molecules found containing multiple nitrogen and oxygen heteroatoms. These molecules are much less abundant in bituminous coals and absent in the higher rank coals.

Novel technique for coal pyrolysis and hydrogenation product analysis. Quarterly report, June 1, 1992

Energy Technology Data Exchange (ETDEWEB)

Pfefferle, L.D.

1992-12-31

This report covers the last quarter of the last year of the three-year grant period. In the final project year, we concentrated on the pyrolysis and oxidative pyrolysis of large hydrocarbons and mixtures of large and small hydrocarbons in order to develop the VUV-MS technique for compounds more representative of those in coal pyrolysis applications. Special focus was directed at the pyrolysis and oxidative pyrolysis of benzene and benzene acetylene mixtures. The acetylene/benzene mixtures were used to gain a better understanding of the mechanisms of molecular growth in such systems specifically to look at the kinetics of aryl-aryl reactions as opposed to small molecule addition to phenyl radicals. Sarofim and coworkers at MIT have recently demonstrated the importance of these reactions in coal processing environments. In the past, the growth mechanism for the formation of midsized PAH has been postulated to involve primarily successive acetylene additions to phenyl-type radicals, our work confmns this as an important mechanism especially for smaller PAH but also investigates conditions where biaryl formation can play an important role in higher hydrocarbon formation.

Phase-equilibria for design of coal-gasification processes: dew points of hot gases containing condensible tars. Final report

Energy Technology Data Exchange (ETDEWEB)

Prausnitz, J.M.

1980-05-01

This research is concerned with the fundamental physical chemistry and thermodynamics of condensation of tars (dew points) from the vapor phase at advanced temperatures and pressures. Fundamental quantitative understanding of dew points is important for rational design of heat exchangers to recover sensible heat from hot, tar-containing gases that are produced in coal gasification. This report includes essentially six contributions toward establishing the desired understanding: (1) Characterization of Coal Tars for Dew-Point Calculations; (2) Fugacity Coefficients for Dew-Point Calculations in Coal-Gasification Process Design; (3) Vapor Pressures of High-Molecular-Weight Hydrocarbons; (4) Estimation of Vapor Pressures of High-Boiling Fractions in Liquefied Fossil Fuels Containing Heteroatoms Nitrogen or Sulfur; and (5) Vapor Pressures of Heavy Liquid Hydrocarbons by a Group-Contribution Method.

Investigation of pyrite as a contributor to slagging in eastern bituminous coals. Quarterly progress report 9, October 1-December 31, 1983

Energy Technology Data Exchange (ETDEWEB)

Bryers, R.W.

1984-06-01

The objective of this program is to examine slags formed as a result of firing coals with varying concentration levels, size distribution, and orientation of pyrite with regard to mineral matter in the coal in a laboratory furnace. The program tasks are: (1) selection of eight candidate coals; (2) chemical characterization of the coal samples and identification of the pyrite size, distribution, and orientation with respect to other mineral matter and concentration levels; (3) testing of the candidate coals in a laboratory furnace; (4) chemical and physical characterization of the slag and fly ash samples created by the impurities in the coal sample; (5) influence of coal beneficiation on furnace slagging; and (6) analysis of data and identification of parameters influencing the contribution of pyrite to slagging problems. Washing of the Upper Freeport coal from Indiana County, Pennsylvania, was completed by the last quarter of 1983. The washed product was characterized for mineral content, and a combustion test was performed. Kentucky No. 9 from Henderson County, Kentucky, selected as the sixth coal to be investigated, was characterized using size and gravity fractionation techniques and was combusted in the laboratory furnace to evaluate its slagging and fouling potential. The remaining two coals to be characterized and combusted were identified as Illinois No. 5 and Lower Kittanning from Clarion County, Pennsylvania. 80 figures, 27 tables.

Kinetic Theory Derivation of the Adiabatic Law for Ideal Gases.

Science.gov (United States)

Sobel, Michael I.

1980-01-01

Discusses how the adiabatic law for ideal gases can be derived from the assumption of a Maxwell-Boltzmann (or any other) distribution of velocities--in contrast to the usual derivations from thermodynamics alone, and the higher-order effect that leads to one-body viscosity. An elementary derivation of the adiabatic law is given. (Author/DS)

Chromatographic methods and techniques used in studies of coals, their progenitors and coal-derived materials

Energy Technology Data Exchange (ETDEWEB)

Zubkova, Valentina [Jan Kochanowski University of Humanities and Sciences, Institute of Chemistry, Kielce (Poland)

2011-03-15

The use of chromatography in studies of coals, their progenitors and coal-related products was reviewed. The specificity of the coal structure was discussed. The use of extraction in preparing study samples was discussed paying special attention to the occurrence of undesirable phenomena such as aggregation of coal derivate molecules, resulting from the formation of their dimers and trimers, and degradation of polar solvents at temperatures above 350 C. The following ways of fractionating samples of coal materials were considered: thermal, solvent, column with the use of preparative size exclusive chromatography and preparative thin layer chromatography as well as membrane separation. The use of chromatography coupled with experimental techniques such as mass spectrometry, infrared spectroscopy, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and pyrolysis was analysed. (orig.)

Integrated report on the toxicological mitigation of coal liquids by hydrotreatment and other processes. [Petroleum and coal-derived products

Energy Technology Data Exchange (ETDEWEB)

Guerin, M.R.; Griest, W.H.; Ho, C.H.; Smith, L.H.; Witschi, H.P.

1986-06-01

Research here on the toxicological properties of coal-derived liquids focuses on characterizing the refining process and refined products. Principle attention is given to the potential tumorigenicity of coal-derived fuels and to the identification of means to further reduce tumorigenicity should this be found necessary. Hydrotreatment is studied most extensively because it will be almost certainly required to produce commercial products and because it is likely to also greatly reduce tumorigenic activity relative to that of crude coal-liquid feedstocks. This report presents the results of a lifetime C3H mouse skin tumorigenicity assay of an H-Coal series of oils and considers the relationships between tumorigenicity, chemistry, and processing. Lifetime assay results are reported for an H-Coal syncrude mode light oil/heavy oil blend, a low severity hydrotreatment product, a high severity hydrotreatment product, a naphtha reformate, a heating oil, a petroleum-derived reformate, and a petroleum derived heating oil. Data are compared with those for an earlier study of an SRC-II blend and products of its hydrotreatment. Adequate data are presented to allow an independent qualitative assessment of the conclusions while statistical evaluation of the data is being completed. The report also documents the physical and chemical properties of the oils tested. 33 refs., 14 figs., 53 tabs.

In-Situ Microbial Conversion of Sequestered Greenhouse Gases

Energy Technology Data Exchange (ETDEWEB)

Scott, A R; Mukhopadhyay, M; Balin, D F

2012-09-06

The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

Degradation and stabilization of coal derived liquid. (IV). ; Effect of alcohol on coloration of coal derived light oil. Sekitan ekikayu no anteika. (IV). ; Sekitan ekikayu no chakushoku yokusei ni oyobosu alcohol no tenka koka

Energy Technology Data Exchange (ETDEWEB)

Ukegawa, K.; Matsumura, A.; Kondo, T. (National Research Institute for Pollution and Resources, Tsukuba (Japan)); TAhara, N. (Nitto Denko Corp., Osaka (Japan)); Nakamura, E. (New Energy and Industrial Technology Development Organization, Tokyo (Japan)); Niki, E. (The University of Tokyo, Tokyo (Japan). Research Center for ADvanced Science and Technology)

1990-01-20

In order to improve the color stability of a coal derived light oil, the effect of hydrotreating and various additives has been studied. The color stability has been evaluated through measuring changes in absorbance by flow-cell spectrophotometer. Following results have been obtained: The color stabilities of hydrotreated coal derived light oils were improved remarkably with increasing hydrotreating temperature and pressure. Mild hydrotreating made the color stability of the coal derived light oil much better than the fuel oil, even though the nitrogen removal was very small. Phenolic compounds additives could not improve the color stability of the coal derived light oil. Alcohol, especially methanol, made the coloration rate of the coal derived light oil small to a great extent, on account of hydrogen bonding between methanol and nitrogen compounds in the fuel oil. 4 refs., 4 figs., 3 tabs.

Dioxin emissions from coal combustion in domestic stove: Formation in the chimney and coal chlorine content influence

Directory of Open Access Journals (Sweden)

Paradiz Bostjan

2015-01-01

Full Text Available Combustion experiments conducted in domestic stove burning hard coal demonstrated a predominant influence of the coal chlorine content on the PCDD/F emissions, together with a pronounced effect of the flue gas temperature. PCDD/F concentrations of over 100 ng TEQ/m3, three orders of magnitude higher than in a modern waste incinerator, were measured in the flue gases of a domestic stove when combusting high chlorine coal (0.31 %. The PCDD/F concentrations in the flue gases dropped below 0,5 ng TEQ/m3, when low chlorine coal (0.07 % was used. When low chlorine coal was impregnated with NaCl to obtain 0.38 % chlorine content, the emission of the PCDD/Fs increased by two orders of magnitude. Pronounced nonlinearity of the PCDD/F concentrations related to chlorine content in the coal was observed. The combustion of the high chlorine coal yielded PCDD/F concentrations in flue gases one order of magnitude lower in a fan cooled chimney when compared to an insulated one, thus indicating formation in the chimney. The influence of flue gas temperature on the PCDD/F emissions was less pronounced when burning low chlorine coal. The predominant pathway of the PCDD/F emissions is via flue gases, 99 % of the TEQ in the case of the high chlorine coal for insulated chimney.

Hot Gas Cleanup Test Facility for gasification and pressurized combustion. Quarterly report, October--December 1994

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-02-01

The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. The major emphasis during this reporting period was continuing the detailed design of the facility and integrating the particulate control devices (PCDs) into structural and process designs. Substantial progress in underground construction activities was achieved during the quarter. Delivery and construction of coal handling and process structural steel began during the quarter. Delivery and construction of coal handling and process structural steel began during the quarter. MWK equipment at the grade level and the first tier are being set in the structure.

Adsorption of ultra-low concentration malodorous substances using coal-derived granular activated carbons

Energy Technology Data Exchange (ETDEWEB)

Urano, K.; Maeda, T.; Yamashita, H.; Hagio, S.; Arioka, A.

1986-01-01

The experimental adsorption is reported of diosmin and 2-methylisoborneol using two types of coal-derived granular activated carbon and one derived from coconut husk. It was discovered that carbons with more pores below 15 angstroms in size gave a higher equilibrium adsorption of malodorous substances at mg/l concentrations. It was also found that the coal-derived materials, which contained more pores larger than 15 angstroms, gave faster adsorption. Given that the coal-derived carbons have a longer service life, it is concluded that they are suitable for use in full-scale adsorption plant where contact times are short. 3 references, 5 figures, 5 tables.

Improvement of hydrodenitrogenation (HDN) in co-refining of coal-derived liquid and petroleum fraction

Energy Technology Data Exchange (ETDEWEB)

Machida, M.; Ono, S. [Idemitsu Kosan Co. Ltd., Tokyo (Japan); Hattori, H. [Hokkaido University, Sapporo (Japan). Center for Advanced Research of Energy Technology

1997-09-01

The improvement in hydrodenitrogenation (HDN) of coal-derived liquids by co-refining with a petroleum fraction results principally from lowering the nitrogen content of the feedstock (coal-derived liquid) by blending with a nitrogen-free petroleum fraction. Effects of different fractions of coal-derived liquids on HDN and hydrodeoxygenation (HDO) were also examined. The HDN improvement by co-refining could be interpreted in terms of Langmuir-Hinshelwood mechanism. 38 refs., 3 figs., 3 tabs.

Energy Information Administration quarterly coal report, October--December 1992

International Nuclear Information System (INIS)

1993-01-01

The United States produced just over 1 billion short tons of coal in 1992, 0.4 percent more than in 1991. Most of the 4-million-short-ton increase in coal production occurred west of the Mississippi River, where a record level of 408 million short tons of coal was produced. The amount of coal received by domestic consumers in 1992 totaled 887 million short tons. This was 7 million short tons more than in 1991, primarily due to increased coal demand from electric utilities. The average price of delivered coal to each sector declined by about 2 percent. Coal consumption in 1992 was 893 million short tons, only 1 percent higher than in 1991, due primarily to a 1-percent increase in consumption at electric utility plants. Consumer coal stocks at the end of 1992 were 163 million short tons, a decrease of 3 percent from the level at the end of 1991, and the lowest year-end level since 1989. US coal exports fell 6 percent from the 1991 level to 103 million short tons in 1992. Less coal was exported to markets in Europe, Asia, and South America, but coal exports to Canada increased 4 million short tons

Determining air distribution during outbursts of gases and rocks

Energy Technology Data Exchange (ETDEWEB)

Struminski, A; Sikora, M; Urbanski, J [Politechnika Wroclawska (Poland). Instytut Gornictwa

1989-01-01

Discusses use of the KPW-1 iterative and autocorrelation method developed by A. Struminski for forecasting effects of rock bursts on ventilation systems of underground coal mines with increased content of methane or carbon dioxide in coal seams and adjacent rock strata. The method is used for prediction of air flow changes caused by a rock burst accompanied by violent outburst of gases. Directions of air flow, flow rate and concentration of gases emitted from surrounding strata to mine workings are predicted. On the basis of this prediction concentration of gases from a coal outburst is determined for any point in a ventilation network. The prediction method is used for assessing hazards for coal mines during and after a rock burst. Use of the method is explained on the example of the Thorez and Walbrzych coal mines. Computer programs developed for ODRA and IBM/XT computers are discussed. 6 refs.

Prediction of oxy-coal combustion through an optimized weighted sum of gray gases model

International Nuclear Information System (INIS)

Kangwanpongpan, Tanin; Corrêa da Silva, Rodrigo; Krautz, Hans Joachim

2012-01-01

Oxy-fuel combustion is considered as one of promising options for carbon dioxide capture in future coal power plants. Currently models available in CFD codes fail to predict accurately the radiative heat transfer in oxy-fuel cases due to higher pressure of carbon dioxide and water vapor. This paper concerns numerical investigation applying three band formulations aiming an accurate prediction of radiative properties. The radiative heat transfer is calculated by discrete ordinate method coupled with a weighted sum of gray gases model. The first case relates to the domain-based approach using air-fired parameters. In the last two cases, the optimized parameters of 3 and 4 gray gases fitted to oxy-fired conditions are implemented through a non-gray gases approach. Results applying these set of parameters are evaluated through a comparison with experimental data. Discrepancies between the predicted and measured velocity and O 2 concentration are found mainly close to the burner due to shortcomings of the turbulence model and inaccurate thermochemical closure. The gas flame temperatures are better predicted by the optimized parameters for oxy-fuel conditions, which are considerably lower than the values calculated by the air-fired parameters. Similar trends are observed when the radiative heat fluxes at the lateral wall are compared.

Assessment of ground-water contamination by coal-tar derivatives, St. Louis Park area, Minnesota

Science.gov (United States)

Hult, M.F.

1984-01-01

Operation of a coal-tar distillation and wood-preserving facility in St. Louis Park, Minnesota, during 1918-72 contaminated ground water with coal-tar derivatives and inorganic chemicals. Coal-tar derivatives entered the groundwater system through three major paths: (1) Spills and drippings that percolated to the water table, (2) surface runoff and plant process water that was discharged to wetlands south of the former plant site, and (3) movement of coal tar directly into bedrock aquifers through a multiaquifer well on the site.

Solvent refined coal (SRC) process. Quarterly technical progress report, January 1980-March 1980. [In process streams

Energy Technology Data Exchange (ETDEWEB)

1981-01-01

This report summarizes the progress of the Solvent Refined Coal (SRC) project at the SRC Pilot Plant in Fort Lewis, Wahsington, and the Process Development Unit (P-99) in Harmarville, Pennsylvania. After the remaining runs of the slurry preheater survey test program were completed January 14, the Fort Lewis Pilot Plant was shut down to inspect Slurry Preheater B and to insulate the coil for future testing at higher rates of heat flux. Radiographic inspection of the coil showed that the welds at the pressure taps and the immersion thermowells did not meet design specifications. Slurry Preheater A was used during the first 12 days of February while weld repairs and modifications to Slurry Preheater B were completed. Two attempts to complete a material balance run on Powhatan No. 6 Mine coal were attempted but neither was successful. Slurry Preheater B was in service the remainder of the quarter. The start of a series of runs at higher heat flux was delayed because of plugging in both the slurry and the hydrogen flow metering systems. Three baseline runs and three slurry runs of the high heat flux program were completed before the plant was shut down March 12 for repair of the Inert Gas Unit. Attempts to complete a fourth slurry run at high heat flux were unsuccessful because of problems with the coal feed handling and the vortex mix systems. Process Development Unit (P-99) completed three of the four runs designed to study the effect of dissolver L/D ratio. The fourth was under way at the end of the period. SRC yield correlations have been developed that include coal properties as independent variables. A preliminary ranking of coals according to their reactivity in PDU P-99 has been made. Techniques for studying coking phenomenona are now in place.

CO-COMBUSTION OF REFUSE DERIVED FUEL WITH COAL IN A FLUIDISED BED COMBUSTOR

Directory of Open Access Journals (Sweden)

W. A. WAN AB KARIM GHANI

2009-03-01

Full Text Available Power generation from biomass is an attractive technology which utilizes municipal solid waste-based refused derived fuel. In order to explain the behavior of biomass-fired fluidized bed incinerator, biomass sources from refuse derived fuel was co-fired with coal in a 0.15 m diameter and 2.3 m high fluidized bed combustor. The combustion efficiency and carbon monoxide emissions were studied and compared with those from pure coal combustion. This study proved that the blending effect had increased the carbon combustion efficiency up to 12% as compared to single MSW-based RDF. Carbon monoxide levels fluctuated between 200-1600 ppm were observed when coal is added. It is evident from this research that efficient co-firing of biomass with coal can be achieved with minimum modification of existing coal-fired boilers.

Upgrading including heteroatom removal from Victorian brown coal-derived liquids

Energy Technology Data Exchange (ETDEWEB)

Larkins, F.P.; Youings, J.C.; Jackson, W.R.; Park, D. (University of Tasmania, Hobart, Tasmania (Australia))

1989-10-01

It has been shown using model compounds that the hydrodeoxygenation performance of a catalyst is severely inhibited by the presence of nitrogen-containing compounds under conditions of moderate reaction severity. For a low molecular weight coal-derived liquid commercial catalysts were effective for HDO and HDN at 400{degree}C, 10 MPa H{sub 2} for 30 min reaction time. For a coal-derived liquid high in asphaltene commercial catalysts and others prepared and tested in this study were ineffective. Alternative catalysts and hydrotreating conditions of greater severity will be required for such materials to effect acceptable heteroatom removal. 3 refs., 2 figs., 2 tabs.

Gaseous emissions from coal stockpiles

Energy Technology Data Exchange (ETDEWEB)

NONE

2013-01-15

Stockpiled coal undergoes atmospheric oxidation and desorption processes during open air storage. These processes release gases to the environment which may effect health and safety by their toxicity and flammability. In extreme cases, this could lead to a fire. This report discusses gaseous emissions from coal stockpiles. It covers gas emission mechanisms, and gas sampling and testing methods, before examining in more detail the principal gases that have been emitted. It concludes that there is limited research in this area and more data are needed to evaluate the risks of gaseous emissions. Some methods used to prevent coal self-heating and spontaneous combustion can be applied to reduce emissions from coal stockpiles.

Evaluation of coal bed methane potential of coal seams of Sawang ...

Indian Academy of Sciences (India)

This analysis shows that the maximum methane gas adsorbed in the coal sample CG-81 is 17 m3/t (Std. daf), at maximum pressure of 5.92 MPa ... vast coal reserves are ideal reservoirs for the gen- eration and accumulation of CBM. ... of gases in coal seams, such as, compression as free gas in the pore spaces, condensed ...

Development of disposal sorbents for chloride removal from high-temperature coal-derived gases

Energy Technology Data Exchange (ETDEWEB)

Krishnan, G.N.; Wood, B.J.; Canizales, A. [and others

1995-11-01

The objective of this program is to develop alkali-based disposable sorbents capable of reducing HCl vapor concentrations to less than 1 ppmv in coal gas streams at temperatures in the range 400{degrees} to 750{degrees}C and pressures in the range 1 to 20 atm. The primary areas of focus of this program are investigation of different processes for fabricating the sorbents, testing their suitability for different reactor configurations, obtaining kinetic data for commercial reactor design, and updating the economics of the process.

Power Systems Development Facility. Quarterly report, July 1--September 30, 1996

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-12-31

This quarterly technical progress report summarizes the work completed during the third quarter of a project entitled Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion. The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phase expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF).

Industrial gases

International Nuclear Information System (INIS)

Hunter, D.; Jackson, D.; Coeyman, M.

1993-01-01

Industrial gas companies have fought hard to boost sales and hold margins in the tough economic climate, and investments are well down from their 1989-'91 peak. But 'our industry is still very strong long term' says Alain Joly, CEO of industry leader L'Air Liquide (AL). By 1994, if a European and Japanese recovery follows through on one in the U.S., 'we could see major [investment] commitments starting again,' he says. 'Noncryogenic production technology is lowering the cost of gas-making possible new applications, oxygen is getting plenty of attention in the environmental area, and hydrogen also fits into the environmental thrust,' says Bob Lovett, executive v.p./gases and equipment with Air Products ampersand Chemicals (AP). Through the 1990's, 'Industrial gases could grow even faster than in the past decade,' he says. Virtually a new generation of new gases applications should become reality by the mid-1990s, says John Campbell, of industry consultants J.R. Campbell ampersand Associates (Lexington, MA). Big new oxygen volumes will be required for powder coal injection in blast furnaces-boosting a steel mill's requirement as much as 40% and coal gasification/combined cycle (CGCC). Increased oil refinery hydroprocessing needs promise hydrogen requirements

Accumulation of dissolved gases at hydrophobic surfaces in water and sodium chloride solutions: Implications for coal flotation

Energy Technology Data Exchange (ETDEWEB)

Hampton, M.A.; Nguyen, A.V. [University of Queensland, Brisbane, Qld. (Australia). Division of Chemical Engineering

2009-08-15

Dissolved gases can preferentially accumulate at the hydrophobic solid-water interface as revealed by neutron reflectivity measurements. In this paper, atomic force microscopy (AFM) was used to examine accumulation of dissolved gases at a hydrophobic surface in water and sodium chloride solutions. The solvent-exchange method was used to artificially form gaseous domains accumulated at the interface suitable for AFM imaging. Smooth graphite surfaces were used as model surfaces to minimize the secondary effect of surface roughness on the imaging. The concentration of NaCl up to 1 M was found to have a negligible influence on the geometry and population of pre-existing nanobubbles, nanopancakes and nanobubble-nanopancake composites. The implications of the findings on coal flotation in saline water are discussed in terms of attraction between hydrophobic surfaces in water, bubble-particle attachment and hydrophobic coagulation between particles.

Sorption characteristic of coal as regards of gas mixtures emitted in the process of the self-heating of coal

Directory of Open Access Journals (Sweden)

Wojtacha-Rychter Karolina

2017-01-01

Full Text Available One of the most challenging tasks in the coal mining sector is the detection of endogenous fire risks. Under field conditions, the distance between the points where samples for the analyses are collected and the actual place where coal self-heating takes place may be quite remote. Coal is a natural sorbent with a diverse character of pore structures which are surrounded by fractures and cleavage planes constituting ideal spaces for the flow and adsorption of gases. The gases (methane, ethane, ethylene, propane, propylene, acetylene, carbon dioxide, carbon monoxide, hydrogen released from the source of fire migrate through the seam and may be subject to adsorption, or they may cause the desorption of gases accumulated in coal. Therefore, the values of reference sample concentrations may be overstated or understated, respectively. The objective of this experimental study was to investigate the adsorption phenomena accompanying the flow of a multi-component gas mixture through a coal bed which may occur in situ. The research was conducted by means of a method based on a series of calorimetric/chromatographic measurements taken to determine the amount of gases released during coal heating at various temperatures under laboratory conditions. Based on the results obtained in the course of the experiments, it was concluded that the amount of gas adsorbed in the seam depends on the type of coal and the gas. Within the multi-component gas mixture, hydrocarbons demonstrated the largest sorption capacity, especially as concerns propylene.

Comparison of coal/solid recovered fuel (SRF) with coal/refuse derived fuel (RDF) in a fluidised bed reactor

International Nuclear Information System (INIS)

Wagland, S.T.; Kilgallon, P.; Coveney, R.; Garg, A.; Smith, R.; Longhurst, P.J.; Pollard, S.J.T.; Simms, N.

2011-01-01

An experimental study was undertaken to compare the differences between municipal solid waste (MSW) derived solid recovered fuel (SRF) (complying with CEN standards) and refuse derived fuel (RDF). Both fuels were co-combusted with coal in a 50 kW fluidised bed combustor and the metal emissions were compared. Synthetic SRF was prepared in the laboratory by grinding major constituents of MSW such as paper, plastic, textile and wood. RDF was obtained from a local mechanical treatment plant. Heavy metal emissions in flue gas and ash samples from the (coal + 10% SRF) fuel mixture were found to be within the acceptable range and were generally lower than that obtained for coal + 10% RDF fuel mixture. The relative distribution of heavy metals in ash components and the flue gas stream shows the presence of a large fraction (up to 98%) of most of the metals in the ash (except Hg and As). Thermo-gravimetric (TG) analysis of SRF constituents was performed to understand the behaviour of fuel mixtures in the absence and presence of air. The results obtained from the experimental study will enhance the confidence of fuel users towards using MSW-derived SRF as an alternative fuel.

Coal distillation plant

Energy Technology Data Exchange (ETDEWEB)

Overton, P C

1937-05-20

To fractionally condense the vapours derived from the distillation of coal or shale, an apparatus comprises a low temperature carbonisation retort having a plurality of differently heating zones therein which connect with a manifold in which said gas oil vapours can expand. A dephlegmator, cold water jacketted and centrally air heated, causes the heavier matters of the vapours to settle out and the lighter oil gas vapours are conveyed to the bottom of an electrically operated fractionating apparatus comprising a column furnished with a plurality of compartments each heated by electrical elements connected to source of current by lead wires. Annular launders in the compartments collect the derived liquids at the various levels and deliver same by pipes to separate sump while pipe at head of column draws off incondensible gases for return to retort.

Methane in German hard coal mining

International Nuclear Information System (INIS)

Martens, P.N.; Den Drijver, J.

1995-01-01

Worldwide, hard coal mining is being carried out at ever increasing depth, and has, therefore, to cope with correspondingly increasing methane emissions are caused by coal mining. Beside carbon dioxide, chloro-fluoro-carbons (CFCs) and nitrogen oxides, methane is one of the most significant 'greenhouse' gases. It is mainly through the release of such trace gases that the greenhouse effect is brought about. Reducing methane emissions is therefore an important problem to be solved by the coal mining industry. This paper begins by highlighting some of the fundamental principles of methane in hard coal mining. The methane problem in German hard coal mining and the industry's efforts to reduce methane emissions are presented. The future development in German hard coal mining is illustrated by an example which shows how large methane volumes can be managed, while still maintaining high outputs at increasing depth. (author). 7 tabs., 10 figs., 20 refs

Hydrotreating of coal-derived liquids

Energy Technology Data Exchange (ETDEWEB)

Lott, S.E.; Stohl, F.V.; Diegert, K.V. [Sandia National Lab., Albuquerque, NM (United States)] [and others

1995-12-31

To develop a database relating hydrotreating parameters to feed and product quality by experimentally evaluating options for hydrotreating whole coal liquids, distillate cuts of coal liquids, petroleum, and blends of coal liquids with petroleum.

The Tiptop coal-mine fire, Kentucky: Preliminary investigation of the measurement of mercury and other hazardous gases from coal-fire gas vents

Energy Technology Data Exchange (ETDEWEB)

Hower, James C.; Henke, Kevin [University of Kentucky Center for Applied Energy Research, Lexington, KY 40511 (United States); O' Keefe, Jennifer M.K. [Morehead State University, Morehead, KY 40351 (United States); Engle, Mark A. [U.S. Geological Survey, Reston, VA 20192 (United States); Blake, Donald R. [Department of Chemistry, University of California - Irvine, Irvine, CA 92697 (United States); Stracher, Glenn B. [East Georgia College, Swainsboro, GA 30401 (United States)

2009-10-01

The Tiptop underground coal-mine fire in the Skyline coalbed of the Middle Pennsylvanian Breathitt Formation was investigated in rural northern Breathitt County, Kentucky, in May 2008 and January 2009, for the purpose of determining the concentrations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and mercury (Hg) in the vent and for measuring gas-vent temperatures. At the time of our visits, concentrations of CO{sub 2} peaked at 2.0% and > 6.0% (v/v) and CO at 600 ppm and > 700 ppm during field analysis in May 2008 and January 2009, respectively. For comparison, these concentrations exceed the U.S. Occupational Safety and Health Administration (OSHA) eight-hour safe exposure limits (0.5% CO{sub 2} and 50 ppm CO), although the site is not currently mined. Mercury, as Hg{sup 0}, in excess of 500 and 2100 {mu}g/m{sup 3}, in May and January, respectively, in the field, also exceeded the OSHA eight-hour exposure limit (50 {mu}g/m{sup 3}). Carbonyl sulfide, dimethyl sulfide, carbon disulfide, and a suite of organic compounds were determined at two vents for the first sampling event. All gases are diluted by air as they exit and migrate away from a gas vent, but temperature inversions and other meteorological conditions could lead to unhealthy concentrations in the nearby towns. Variation in gas temperatures, nearly 300 C during the January visit to the fire versus < 50 C in May, demonstrates the large temporal variability in fire intensity at the Tiptop mine. These preliminary results suggest that emissions from coal fires may be important, but additional data are required that address the reasons for significant variations in the composition, flow, and temperature of vent gases. (author)

Slag characterization and removal using pulse detonation for coal gasification. Quarterly research report, January 1, 1996--March 31, 1996

Energy Technology Data Exchange (ETDEWEB)

Huque, Z.; Mei, D.; Biney, P.O.; Zhou, J.

1996-03-25

Microbeam Technologies Incorporated (MTI) is working with Prairie View to develop and demonstrate a new method to remove deposits from coal-fired utility boilers. MTI is providing background information on fuel properties, ash formation, ash deposition, and ash removal. In addition, MTI is providing deposits collected from a full scale utility boilers. Ash deposits on fireside heat exchange surfaces of power plants significantly decrease plant efficiency and are aggravated by variability in coal quality. Deposit formation is related to coal quality (chemical and physical characteristics of the inorganic material), system operating conditions, and system design. Variations in coal quality can significantly influence ash deposition on heat transfer surfaces resulting in decreased plant performance and availability. Ash accumulations on heat transfer surfaces require annual or semi-annual shutdowns for cleaning which result in cleaning costs and lost revenues from being off-line. In addition, maintaining slag flow in wet bottom boilers and cyclone-fired boilers can require co-firing of other fuels and outages to remove frozen slag resulting in decreased efficiency and availability. During this reporting period MTI performed analysis of deposits collected from full-scale utility boilers. Deposit samples were obtained from Basin Electric and from Northern States Power (NSP). The analyses were conducted using scanning electron microscopy/microprobe techniques as described in the past quarterly report. The chemical and physical properties of the deposits were determined. The results for sample collected from NSP`s Riverside plant are reported here.

COAL DERIVED MATRIX PITCHES FOR CARBON-CARBON COMPOSITE MANUFACTURE/PRODUCTION OF FIBERS AND COMPOSITES FROM COAL-BASED PRECURSORS

Energy Technology Data Exchange (ETDEWEB)

Peter G. Stansberry; John W. Zondlo

2001-07-01

The Consortium for premium Carbon Products from Coal, with funding from the US Department of Energy, National Energy Technology Laboratory continue with the development of innovative technologies that will allow coal or coal-derived feedstocks to be used in the production of value-added carbon materials. In addition to supporting eleven independent projects during budget period 3, three meetings were held at two separate locations for the membership. The first was held at Nemacolin Woodlands Resort on May 15-16, 2000. This was followed by two meetings at Penn State, a tutorial on August 11, 2000 and a technical progress meeting on October 26-27.

Engineering Graphene Films from Coal

Science.gov (United States)

Vijapur, Santosh H.

temperature operation. Annealing of copper support was required to remove the oxide layer present on its surface and low pressure operation was demonstrated to be suitable for crystalline graphene film formation. The CVD system and the synthesis procedure were modified to address these issues. This was done by increasing the synthesis temperature, incorporating a vacuum pump for low pressure operation, and implementing two step procedure of annealing the copper substrate followed by subsequent coal pyrolysis for the synthesis of crystalline graphene films. The synthesized few layer graphene films were uniform and continuous with thickness in the range of 3-7 nm. The optical transmittance and electrical conductivity measurements demonstrated that the graphene films have >95 % transparency and sheet resistivity of 5.0 kO sq-1, respectively. An investigation of growth mechanism of coal derived graphene films synthesized via CVD was conducted utilizing spectroscopy, microscopy, and chromatography techniques. Gas collection was performed at the graphene synthesis conditions utilizing the CVD reactor without vacuum in operation. Various gases released as products of coal pyrolysis in the CVD reactor were collected and analyzed using gas chromatography. The analysis showed the presence of methane, ethane, ethene, propane, propene, carbon monoxide, and carbon dioxide as coal pyrolysis products. The hydrocarbon gases act as precursors for graphene growth. Raman spectroscopy, selected area electron diffraction (SAED), and X-ray photoelectron spectroscopy (XPS) confirmed the formation of crystalline graphene films at 1055 °C and 18-30 min synthesis. The growth mechanism involves copper catalyzed reaction to produce amorphous carbon film within the first few minutes of synthesis. Raman spectroscopy and SAED validated that lower synthesis times (6-12 min) produced hybrid amorphous carbon films. This is followed by hydrogen catalyzed graphitization of the underlying carbon film to form

US energy industry financial developments, 1991 third quarter

International Nuclear Information System (INIS)

1991-01-01

Net income for the 218 energy companies included in this report was 15 percent lower in the third quarter of 1991 than in the third quarter of 1990. Declining income from oil and natural gas production, chemical operations, and coal operations resulted in a 33-percent fall in income for fossil fuel companies. The other category of energy companies included in this report, rate-regulated utilities, recorded essentially no change in income

Analysis of the use of waste heat obtained from coal-fired units in Organic Rankine Cycles and for brown coal drying

International Nuclear Information System (INIS)

Łukowicz, Henryk; Kochaniewicz, Andrzej

2012-01-01

The ever-increasing restrictions on greenhouse gas emissions have created a need for new energy technologies. One way to meet these new requirements is to optimise the efficiency of power units. This paper presents two energy technologies that, if used, will increase the efficiency of electricity generation. One of the most effective ways to improve the efficiency of brown coal-fired units is by drying the coal that is fed into the boiler. Here, we describe a technology that uses the waste heat obtained from exhaust gases. This paper also presents an analysis of the feasibility of and potential for using waste heat obtained from exhaust gases to feed Organic Rankine Cycles (ORCs). Several low-temperature working fluids were considered, which were selected based on properties that were best suited for these types of cycles. The impact of these working fluids on the efficiency and capacity of the ORC was also examined. The calculations for ORCs fed with waste heat obtained from exhaust gases from hard coal- and brown coal-fired boilers were compared. -- Highlights: ► We describe a technology that uses the waste heat obtained from exhaust gases. ► The impact of using different working fluids with a low boiling point is examined. ► We describe integrating the ORC with the power unit. ► The use of waste heat from boiler exhaust gases to dry brown coal is proposed. ► We demonstrate a possible increase in power unit efficiency.

Investigation of sulfur-polycyclic aromatic hydrocarbon in coal derived tars of pyrolysis and hydropyrolysis

Energy Technology Data Exchange (ETDEWEB)

Chen, H.; Li, B.; Zhang, B. [Chinese Academy of Sciences, Taiyuan (China). State Key Laboratory of Coal Conversion

1999-07-01

A study was undertaken to characterize sulphur forms in coal derived tars from pyrolysis and hydropyrolysis of bituminous coal and lignite. The pyrolysis tars were analyzed for content of polycyclic aromatic sulfur hydrocarbons (PASH). 5 refs., 3 figs., 3 tabs.

Using date stone charcoal as a filtering medium for automobile exhaust gases

Energy Technology Data Exchange (ETDEWEB)

Shahad, H.A.K.; Farhan, A.M. [University of Babylon (Iraq). College of Engineering; Saleh, H.A. [University of Babylon (Iraq). Dept. of Chemistry

1998-12-31

A thermal reactor was designed and built to produce coal from date stones by pyrolysis. Five specimens of coal have been prepared at different maximum charring temperatures. It was found that, as the temperature increases, the properties of coal are improved (the percentage of carbon content increases). It was also found that, at 700{sup o}C, the percentage of carbon content remains constant. The coal prepared at this temperature was used as a filtering medium in an adsorption filter to purify the exhaust gases of a two stroke spark ignition engine. The results showed that the filter has a high adsorption ability for CO and CO{sub 2} gases. An ORSAT apparatus was used to measure the concentration of CO and CO{sub 2} in the exhaust gases before and after the filter. The filter reduced the concentration of CO and CO{sub 2} by 62 and 59%, respectively. (author)

The marriage of gas turbines and coal

International Nuclear Information System (INIS)

Bajura, R.A.; Webb, H.A.

1991-01-01

This paper reports on developing gas turbine systems that can use coal or a coal-based fuel ensures that the United States will have cost-effective environmentally sound options for supplying future power generation needs. Power generation systems that marry coal or a coal-based fuel to a gas turbine? Some matchmakers would consider this an unlikely marriage. Historically, most gas turbines have been operated only on premium fuels, primarily natural gas or distillate oil. The perceived problems from using coal or coal-based fuels in turbines are: Erosion and deposition: Coal ash particles in the hot combustion gases passing through the expander turbine could erode or deposit on the turbine blades. Corrosion: Coal combustion will release alkali compounds form the coal ash. Alkali in the hot gases passing through the expander turbine can cause corrosion of high-temperature metallic surfaces. Emissions: coal contains higher levels of ash, fuel-bound sulfur and nitrogen compounds, and trace contaminants than premium fuels. Meeting stringent environmental regulations for particulates, sulfur dioxide (SO 2 ), nitrogen oxides (NO x ), and trace contaminants will be difficult. Economics: Coal-based systems are expensive to build. The difference in price between coal and premium fuels must be large enough to justify the higher capital cost

Quarterly coal report, April 1996--June 1996

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-11-01

This report provides information about U.S. coal production, distribution; exports, imports, prices, consumption, and stocks. Data on coke production is also provided. This report presents data for April 1996 thru June 1996.

Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels

Energy Technology Data Exchange (ETDEWEB)

Steven Markovich

2010-06-30

This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

Hot coal gas desulfurization with manganese-based sorbents. Final report, September 1992--December 1994

Energy Technology Data Exchange (ETDEWEB)

Hepworth, M.T.; Slimane, R.B.

1994-11-01

The focus of much current work being performed by the Morgantown Energy Technology Center (METC) of the Department of Energy on hot coal-derived fuel gas desulfurization is in the use of zinc-based sorbents. METC has shown interest in formulating and testing manganese-based pellets as alternative effective sulfur sorbents in the 700 to 1200{degree}C temperature range. To substantiate the potential superiority of Mn-based pellets, a systematic approach toward the evaluation of the desulfurizing power of single-metal sorbents is developed based on thermodynamic considerations. This novel procedure considered several metal-based sorbents and singled out manganese oxide as a prime candidate sorbent capable of being utilized under a wide temperature range, irrespective of the reducing power (determined by CO{sub 2}/CO ratio) of the fuel gas. Then, the thermodynamic feasibility of using Mn-based pellets for the removal of H{sub 2}S from hot-coal derived fuel gases, and the subsequent oxidative regeneration of loaded (sulfided) pellets was established. It was concluded that MnO is the stable form of manganese for virtually all commercially available coal-derived fuel gases. In addition, the objective of reducing the H{sub 2}S concentration below 150 ppMv to satisfy the integrated gasification combined cycle system requirement was shown to be thermodynamically feasible. A novel process is developed for the manufacture of Mn-based spherical pellets which have the desired physical and chemical characteristics required.

Molecular accessibility in solvent swelled coals. Quarterly report, [April--June 1993

Energy Technology Data Exchange (ETDEWEB)

Kispert, L.D.

1993-08-01

The effect of weathering (oxidation and dehydration upon exposure to air) on the molecular accessibility of potential catalysts was studied by the EPR spin probe technique. Fresh samples of all 8 APCS coals were exposed to air for periods up to 36 days. Weathering produced significant effects on the retention of spin probes in most of the APCS coals under 91 % carbon (dmmf). It was determined that the lower ranked coal (Beulah Zap and Wyodak) under went a structural collapse which precluded retention of even spin probe VIII. However, medium ranked coals exhibited improved retention upon weathering when swelled in toluene. Swelling with pyridine opened up small pores for 81--86% carbon which is not observed for swelling with toluene. Changes in coal structure were successfully followed by the EPR spin probe method. A detailed analysis of the data collected from the swelling of coals oxidized in a moisture free environment was completed to differentiate between weathering and oxidation. Eight vacuum dried APCS coals were oxidized in an enclosed, pure oxygen, moisture free environment, and the effects of oxidation alone on coal structure were studied by the intercalation of EPR spin probes. The data shows a factor of 5 increase in spin probe retention for some coals oxidized in O{sub 2} versus air., suggesting a large increase in oxidized material. Particular care was taken during the swelling procedures to avoid exposure of the coal samples to air or moisture. EPR spectra were then obtained for these 300 samples.

Intrinsic and extrinsic defects in a family of coal-derived graphene quantum dots

Science.gov (United States)

Singamaneni, Srinivasa Rao; van Tol, Johan; Ye, Ruquan; Tour, James M.

2015-11-01

In this letter, we report on the high frequency (239.2 and 336 GHz) electron spin resonance (ESR) studies performed on graphene quantum dots (GQDs), prepared through a wet chemistry route from three types of coal: (a) bituminous, (b) anthracite, and (c) coke; and from non-coal derived GQDs. The microwave frequency-, power-, and temperature-dependent ESR spectra coupled with computer-aided simulations reveal four distinct magnetic defect centers. In bituminous- and anthracite-derived GQDs, we have identified two of them as intrinsic carbon-centered magnetic defect centers (a broad signal of peak to peak width = 697 (10-4 T), g = 2.0023; and a narrow signal of peak to peak width = 60 (10-4 T), g = 2.003). The third defect center is Mn2+ (6S5/2, 3d5) (signal width = 61 (10-4 T), g = 2.0023, Aiso = 93(10-4 T)), and the fourth defect is identified as Cu2+ (2D5/2, 3d9) (g⊥ = 2.048 and g‖ = 2.279), previously undetected. Coke-derived and non-coal derived GQDs show Mn2+ and two-carbon related signals, and no Cu2+ signal. The extrinsic impurities most likely originate from the starting coal. Furthermore, Raman, photoluminescence, and ESR measurements detected no noticeable changes in the properties of the bituminous GQDs after one year. This study highlights the importance of employing high frequency ESR spectroscopy in identifying the (magnetic) defects, which are roadblocks for spin relaxation times of graphene-based materials. These defects would not have been possible to probe by other spin transport measurements.

Thermal-maturity limit for primary thermogenic-gas generation from humic coals as determined by hydrous pyrolysis

Science.gov (United States)

Lewan, Michael; Kotarba, M.J.

2014-01-01

Hydrous-pyrolysis experiments at 360°C (680°F) for 72 h were conducted on 53 humic coals representing ranks from lignite through anthracite to determine the upper maturity limit for hydrocarbon-gas generation from their kerogen and associated bitumen (i.e., primary gas generation). These experimental conditions are below those needed for oil cracking to ensure that generated gas was not derived from the decomposition of expelled oil generated from some of the coals (i.e., secondary gas generation). Experimental results showed that generation of hydrocarbon gas ends before a vitrinite reflectance of 2.0%. This reflectance is equivalent to Rock-Eval maximum-yield temperature and hydrogen indices (HIs) of 555°C (1031°F) and 35 mg/g total organic carbon (TOC), respectively. At these maturity levels, essentially no soluble bitumen is present in the coals before or after hydrous pyrolysis. The equivalent kerogen atomic H/C ratio is 0.50 at the primary gas-generation limit and indicates that no alkyl moieties are remaining to source hydrocarbon gases. The convergence of atomic H/C ratios of type-II and -I kerogen to this same value at a reflectance of indicates that the primary gas-generation limits for humic coal and type-III kerogen also apply to oil-prone kerogen. Although gas generation from source rocks does not exceed vitrinite reflectance values greater than , trapped hydrocarbon gases can remain stable at higher reflectance values. Distinguishing trapped gas from generated gas in hydrous-pyrolysis experiments is readily determined by of the hydrocarbon gases when a -depleted water is used in the experiments. Water serves as a source of hydrogen in hydrous pyrolysis and, as a result, the use of -depleted water is reflected in the generated gases but not pre-existing trapped gases.

Upgraded coal interest group. Quarterly report, July 1, 1995--September 30, 1995

Energy Technology Data Exchange (ETDEWEB)

Weber, W. [Electric Power Research Inst., Chattanooga, TN (United States); Lebowitz, H.E. [Fossil Fuel Sciences, Palo Alto, CA (United States)

1995-12-31

The objectives of the Upgraded Coal Interest Group (UCIG) are as follows: Review and update the status of various coal upgrading technologies and developments and critically assess the results. Perform engineering screening analyses on various coal upgrading approaches. Perform commercialization analyses that will promote the availability and use of upgraded coal products by quantifying the benefits of using them. Identify market opportunities for introduction of upgraded coals. Perform critical analyses on a variety of coals and technologies in areas important to users but not readily available. Perform critical experiments which will show the differences between technologies.

Mercury transformation and speciation in flue gases from anthropogenic emission sources: a critical review

OpenAIRE

Zhang, Lei; Wang, Shuxiao; Wu, Qingru; Wang, Fengyang; Lin, Che-Jen; Zhang, Leiming; Hui, Mulin; Yang, Mei; Su, Haitao; Hao, Jiming

2016-01-01

Mercury transformation mechanisms and speciation profiles are reviewed for mercury formed in and released from flue gases of coal-fired boilers, non-ferrous metal smelters, cement plants, iron and steel plants, waste incinerators, biomass burning and so on. Mercury in coal, ores, and other raw materials is released to flue gases in the form of Hg0 during combustion or smelting in boilers, kilns or furnaces. Decreasing temperature from over 800 °C to below 300 °C in flue gase...

Newer methods for the characterization of higher molecular mass coal derivatives

International Nuclear Information System (INIS)

Bartle, K.D.

1983-01-01

Recent developments in a number of areas in the analytical chemistry of higher molecular mass coal derivatives are critically reviewed, viz. supercritical fluid chromatography, size-exclusion chromatography, charge-transfer fractionation, nmr spectroscopy, mass spectrometry and electrochemical analysis. (orig.) [de

Pd/activated carbon sorbents for mid-temperature capture of mercury from coal-derived fuel gas.

Science.gov (United States)

Li, Dekui; Han, Jieru; Han, Lina; Wang, Jiancheng; Chang, Liping

2014-07-01

Higher concentrations of Hg can be emitted from coal pyrolysis or gasification than from coal combustion, especially elemental Hg. Highly efficient Hg removal technology from coal-derived fuel gas is thus of great importance. Based on the very excellent Hg removal ability of Pd and the high adsorption abilities of activated carbon (AC) for H₂S and Hg, a series of Pd/AC sorbents was prepared by using pore volume impregnation, and their performance in capturing Hg and H₂S from coal-derived fuel gas was investigated using a laboratory-scale fixed-bed reactor. The effects of loading amount, reaction temperature and reaction atmosphere on Hg removal from coal-derived fuel gas were studied. The sorbents were characterized by N₂ adsorption, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results indicated that the efficiency of Hg removal increased with the increasing of Pd loading amount, but the effective utilization rate of the active component Pd decreased significantly at the same time. High temperature had a negative influence on the Hg removal. The efficiency of Hg removal in the N₂-H₂S-H₂-CO-Hg atmosphere (simulated coal gas) was higher than that in N₂-H₂S-Hg and N₂-Hg atmospheres, which showed that H₂ and CO, with their reducing capacity, could benefit promote the removal of Hg. The XPS results suggested that there were two different ways of capturing Hg over sorbents in N₂-H₂S-Hg and N₂-Hg atmospheres. Copyright © 2014. Published by Elsevier B.V.

Fluidized bed combustion of refuse-derived fuel in presence of protective coal ash

Energy Technology Data Exchange (ETDEWEB)

Ferrer, Eduardo [CIRCE, Universidad de Zaragoza, Maria de Luna, 3, Zaragoza (Spain); Aho, Martti [VTT Processes, P.O. Box 1603, 40101 Jyvaeskylae (Finland); Silvennoinen, Jaani; Nurminen, Riku-Ville [Kvaerner Power, P.O.Box 109, FIN-33101 Tampere (Finland)

2005-12-15

Combustion of refuse-derived fuel (RDF) alone or together with other biomass leads to superheater fouling and corrosion in efficient power plants (with high steam values) due to vaporization and condensation of alkali chlorides. In this study, means were found to raise the portion of RDF to 40% enb without risk to boilers. This was done by co-firing RDF with coal and optimizing coal quality. Free aluminum silicate in coal captured alkalies from vaporized alkali chlorides preventing Cl condensation to superheaters. Strong fouling and corrosion were simultaneously averted. Results from 100 kW and 4 MW CFB reactors are reported. (author)

Evaluation of the ignition behaviour of coals and blends

Energy Technology Data Exchange (ETDEWEB)

J. Faundez; F. Rubiera; X. Garcia; A. Arenillas; A.L. Gordon; J.J. Pis [CSIC, Instituto Nacional del Carbon, Oviedo (Spain). Department of Energy and Environment

2003-07-01

An experimental study about ignition of coals and blends was carried out by using an entrained flow reactor (EFR) with continuous feed. Seven coals of varying rank, from subbituminous to semianthracite, were tested and evolving gases (O{sub 2}, CO, CO{sub 2}, NO) were measured. The ignition temperature was evaluated from the evolution profiles of these gases, and correlated inversely to the reactivity of coals, as reflected by increasing values of ignition temperatures in the sequence subbituminous, high volatile bituminous, low volatile bituminous and semianthracite coals. Mechanism of ignition varied from an heterogeneous mechanism (for subbituminous, low volatile bituminous and semianthracite coals) to an homogeneous mechanism (for high volatile bituminous coal). Experiments with coal blends showed that if a low volatile bituminous coal is blended with a high volatile bituminous coal, the latter determines the value of the ignition temperature and ignition mechanism of the blend, when its percentage in the blend is 50% or higher. For blends of subbituminous and high volatile bituminous coals, the ignition mechanism of the blend is determined by the ignition mechanism of the coal with a higher content in the blend. 12 refs., 9 figs., 1 tab.

THE ECONOMICAL PRODUCTION OF ALCOHOL FUELS FROM COAL-DERIVED SYNTHESIS GAS. Includes quarterly technical progress report No.25 from 10/01/1997-12/31/1997, and quarterly technical progress report No.26 from 01/01/1998-03/31/1998

Energy Technology Data Exchange (ETDEWEB)

None

1999-03-01

This project was divided into two parts. One part evaluated possible catalysts for producing higher-alcohols (C{sub 2} to C{sub 5+}) as fuel additives. The other part provided guidance by looking both at the economics of mixed-alcohol production from coal-derived syngas and the effect of higher alcohol addition on gasoline octane and engine performance. The catalysts studied for higher-alcohol synthesis were molybdenum sulfides promoted with potassium. The best catalysts produced alcohols at a rate of 200 g/kg of catalyst/h. Higher-alcohol selectivity was over 40%. The hydrocarbon by-product was less than 20%. These catalysts met established success criteria. The economics for mixed alcohols produced from coal were poor compared to mixed alcohols produced from natural gas. Syngas from natural gas was always less expensive than syngas from coal. Engine tests showed that mixed alcohols added to gasoline significantly improved fuel quality. Mixed-alcohols as produced by our catalysts enhanced gasoline octane and decreased engine emissions. Mixed-alcohol addition gave better results than adding individual alcohols as had been done in the 1980's when some refiners added methanol or ethanol to gasoline.

Warm Cleanup of Coal-Derived Syngas: Multicontaminant Removal Process Demonstration

Energy Technology Data Exchange (ETDEWEB)

Spies, Kurt A.; Rainbolt, James E.; Li, Xiaohong S.; Braunberger, Beau; Li, Liyu; King, David L.; Dagle, Robert A.

2017-02-15

Warm cleanup of coal- or biomass-derived syngas requires sorbent and catalytic beds to protect downstream processes and catalysts from fouling. Sulfur is particularly harmful because even parts-per-million amounts are sufficient to poison downstream synthesis catalysts. Zinc oxide (ZnO) is a conventional sorbent for sulfur removal; however, its operational performance using real gasifier-derived syngas and in an integrated warm cleanup process is not well reported. In this paper, we report the optimal temperature for bulk desulfurization to be 450oC, while removal of sulfur to parts-per-billion levels requires a lower temperature of approximately 350oC. Under these conditions, we found that sulfur in the form of both hydrogen sulfide and carbonyl sulfide could be absorbed equally well using ZnO. For long-term operation, sorbent regeneration is desirable to minimize process costs. Over the course of five sulfidation and regeneration cycles, a ZnO bed lost about a third of its initial sulfur capacity, however sorbent capacity stabilized. Here, we also demonstrate, at the bench-scale, a process and materials used for warm cleanup of coal-derived syngas using five operations: 1) Na2CO3 for HCl removal, 2) regenerable ZnO beds for bulk sulfur removal, 3) a second ZnO bed for trace sulfur removal, 4) a Ni-Cu/C sorbent for multi-contaminant inorganic removal, and 5) a Ir-Ni/MgAl2O4 catalyst employed for ammonia decomposition and tar and light hydrocarbon steam reforming. Syngas cleanup was demonstrated through successful long-term performance of a poison-sensitive, Cu-based, water-gas-shift catalyst placed downstream of the cleanup process train. The tar reformer is an important and necessary operation with this particular gasification system; its inclusion was the difference between deactivating the water-gas catalyst with carbon deposition and successful 100-hour testing using 1 LPM of coal-derived syngas.

Comparison tests, in a pilot plant, of the performance of a coal-derived granular activated carbon: a comparison with coconut husk derived activated carbon

Energy Technology Data Exchange (ETDEWEB)

Hirata, S.; Kasahara, A.; Tsuruzono, Y.; Gotoh, M.

1986-01-01

A 160 m/sup 3//d pilot plant has been used in a series of comparison tests of the performance of coal-derived and coconut husk derived activated carbons. Activated carbons are used to remove trihalomethane precursors and malodorous substances from city water. A higher mean removal of coloration and COD/sub M//sub n/ was achieved with the coal-derived carbon (by factors of 1.5 and 1.8, respectively). The two activated carbons gave similar performances as regards turbidity, alkalinity, total iron and total manganese. 4 figures, 5 tables.

Solar coal gasification reactor with pyrolysis gas recycle

Science.gov (United States)

Aiman, William R.; Gregg, David W.

1983-01-01

Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

Intrinsic and extrinsic defects in a family of coal-derived graphene quantum dots

Energy Technology Data Exchange (ETDEWEB)

Singamaneni, Srinivasa Rao, E-mail: ssingam@ncsu.edu, E-mail: tour@rice.edu [Materials Science Division, Army Research Office, Research Triangle Park, North Carolina 27709 (United States); Department of Material Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Tol, Johan van [National High Magnetic Field Laboratory, Florida State University, 1800 E. Paul Dirac Drive, Tallahassee, Florida 32310 (United States); Ye, Ruquan [Department of Chemistry, Rice University, MS-222, 6100 Main Street, Houston, Texas 77005 (United States); Tour, James M., E-mail: ssingam@ncsu.edu, E-mail: tour@rice.edu [Department of Chemistry, Rice University, MS-222, 6100 Main Street, Houston, Texas 77005 (United States); Department of Materials Science and NanoEngineering, Rice University, MS-222, 6100 Main Street, Houston, Texas 77005 (United States); Smalley Institute for Nanoscale Science and Technology, Rice University, MS-222, 6100 Main Street, Houston, Texas 77005 (United States)

2015-11-23

In this letter, we report on the high frequency (239.2 and 336 GHz) electron spin resonance (ESR) studies performed on graphene quantum dots (GQDs), prepared through a wet chemistry route from three types of coal: (a) bituminous, (b) anthracite, and (c) coke; and from non-coal derived GQDs. The microwave frequency-, power-, and temperature-dependent ESR spectra coupled with computer-aided simulations reveal four distinct magnetic defect centers. In bituminous- and anthracite-derived GQDs, we have identified two of them as intrinsic carbon-centered magnetic defect centers (a broad signal of peak to peak width = 697 (10{sup −4} T), g = 2.0023; and a narrow signal of peak to peak width = 60 (10{sup −4} T), g = 2.003). The third defect center is Mn{sup 2+} ({sup 6}S{sub 5/2}, 3d{sup 5}) (signal width = 61 (10{sup −4} T), g = 2.0023, A{sub iso} = 93(10{sup −4} T)), and the fourth defect is identified as Cu{sup 2+} ({sup 2}D{sub 5/2}, 3d{sup 9}) (g{sub ⊥} = 2.048 and g{sub ‖} = 2.279), previously undetected. Coke-derived and non-coal derived GQDs show Mn{sup 2+} and two-carbon related signals, and no Cu{sup 2+} signal. The extrinsic impurities most likely originate from the starting coal. Furthermore, Raman, photoluminescence, and ESR measurements detected no noticeable changes in the properties of the bituminous GQDs after one year. This study highlights the importance of employing high frequency ESR spectroscopy in identifying the (magnetic) defects, which are roadblocks for spin relaxation times of graphene-based materials. These defects would not have been possible to probe by other spin transport measurements.

NST Quarterly - January 1997 issue

International Nuclear Information System (INIS)

1997-01-01

NST Quarterly reports current development in Nuclear Science and Technology in Malaysia. In this issue it highlights MINT activities in local heat shrinkable copolymer and electron beam technology for purification of flue gases. It announces an International Nuclear Conference themed ' a new era in nuclear science and technology - the challenge of the 21 century ' will be held in Kuala Lumpur, Malaysia from 29 to 30 Sept 1997

Research of Heating Rates Influence on Layer Coal Gasification of Krasnogorsky And Borodinsky Coal Deposit

Directory of Open Access Journals (Sweden)

Jankovskiy Stanislav

2015-01-01

Full Text Available Experimental research of heating rate influence on coal samples gasification process of Krasnogorsky and Borodinsky coal deposit ranks A and 2B was done to define optimal heating mode in high intensification of dispersal of inflammable gases conditions. Abundance ratio of carbon monoxide and nitrogen monoxide, water vapor, carbon dioxide at four values of heating rate within the range of 5 to 30 K/min. with further definition of optimal heating rate of coals was stated.

Survey on the trend of coal liquefaction/gasification technologies, broken down by application; Sekitan no ekika gas ka no yotobetsu gijutsu no doko chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1983-03-01

To drive forward the development of the above-named technologies efficiently and effectively, it is necessary to clearly define what coal derived products will meet the need of the clientele and to develop coal derived products accordingly. This survey aims to disclose the whole pictures of the oil/gas using areas and enable the study and evaluation of the possibilities of using coal derived products as substitutes in every one of the expected applications. It also aims to clarify product characteristics, use conditions, technical tasks, and problems to accompany actual substitution in the applications where possibilities are high of their serving as substitutes. Chapter 1, explaining the trend of coal liquefaction/gasification technologies, describes projects for the development of coal liquefaction/gasification technologies, trend of the development of coal liquefaction/gasification technologies, and properties of coal liquefaction/gasification products. Chapter 2, explaining the trend of demand for energy for use in the respective applications, analyzes the trend of demands for oil products, gases, and methanol. Chapter 3 summarizes the applications of chemical materials and fuels for studying the use of coal liquefaction/gasification products as substitutes in the respective applications. Chapter 4 collects problems to solve for the enhancement of coal liquefaction/gasification projects. (NEDO)

Quarterly environmental data summary for fourth quarter 1997

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-12-31

The Quarterly Environmental Data Summary (QEDS) for the fourth quarter of 1997 is prepared in support of the Weldon Spring Site Remedial Action Project Federal Facilities Agreement. The data presented constitute the QEDS. The data were received from the contract laboratories, verified by the Weldon Spring Site verification group and, except for air monitoring data and site KPA generated data (uranium analyses), merged into the data base during the fourth quarter of 1997. Air monitoring data presented are the most recent complete sets of quarterly data. Air data are not stored in the data base and KPA data are not merged into the regular data base. Significant data, defined as data values that have exceeded defined ``above normal`` level 2 values, are discussed in this letter for Environmental Monitoring Plan (EMP) generated data only. Above normal level 2 values are based, in ES and H procedures, on historical high values, DOE Derived Concentration Guides (DCGs), NPDES limits and other guidelines. The procedures also establish actions to be taken in response to such data. Data received and verified during the fourth quarter were within a permissible range of variability except for those which are detailed.

Molecular accessibility in solvent swelled coals. Quarterly report

Energy Technology Data Exchange (ETDEWEB)

Kispert, L.D.

1993-02-01

An EPR technique developed in this lab is being used to determine the pore size and number distribution changes after swelling the coal samples with various solvents. Stable nitroxide radical spin probes of different sizes, shapes and reactivity are dissolved in an appropriate solvent, the coal sample is added to the resulting solution, stirred over night at elevated temperature, filtered, washed with a non swelling solvent to eliminate any spin probes that are not trapped in the pores and the spin concentration is measured. Comparing these spin probe measurements to DRIFT data have shown that the relative number distribution of acidic functionalities can be accurately predicted by the spin probe method. The spin probe method had also been used to predict the increase in elongated voids in Pittsburgh No. 8 (APCS No. 4) upon swelling with pyridine in agreement with independent SANS data. NMR relaxation data show that it is possible to deduce the pore (accessibility) distribution as a function of size (up to 6 mn). It has also been possible by variable temperature and ENDOR measurements to determine the presence of hydrogen bonding as a function of pore shape and size. The advantage of the EPR method is that it permits molecules of selected shape and size to be used as probes of accessible regions of coal, thus providing information on the importance of molecular shape.

Power systems development facility. Quarterly technical progress report, July 1--September 30, 1993

Energy Technology Data Exchange (ETDEWEB)

1993-12-31

This quarterly technical progress report summarizes work completed during the Second Quarter of the Second Budget Period, July 1 through September 30, 1993, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scaleup of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the existing Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/Pressurized Circulating Fluidized Bed Gas Source. Hot Gas Cleanup Units to mate to all gas streams; Combustion Gas Turbine; and Fuel Cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during this reporting period was continuing the detailed design of the facility.

THE ECONOMICAL PRODUCTION OF ALCOHOL FUELS FROM COAL-DERIVED SYNTHESIS GAS. Includes quarterly technical progress report No.25 from 10/01/1997-12/31/1997, and quarterly technical progress report No.26 from 01/01/1998-03/31/1998; FINAL

International Nuclear Information System (INIS)

1999-01-01

This project was divided into two parts. One part evaluated possible catalysts for producing higher-alcohols (C(sub 2) to C(sub 5+)) as fuel additives. The other part provided guidance by looking both at the economics of mixed-alcohol production from coal-derived syngas and the effect of higher alcohol addition on gasoline octane and engine performance. The catalysts studied for higher-alcohol synthesis were molybdenum sulfides promoted with potassium. The best catalysts produced alcohols at a rate of 200 g/kg of catalyst/h. Higher-alcohol selectivity was over 40%. The hydrocarbon by-product was less than 20%. These catalysts met established success criteria. The economics for mixed alcohols produced from coal were poor compared to mixed alcohols produced from natural gas. Syngas from natural gas was always less expensive than syngas from coal. Engine tests showed that mixed alcohols added to gasoline significantly improved fuel quality. Mixed-alcohols as produced by our catalysts enhanced gasoline octane and decreased engine emissions. Mixed-alcohol addition gave better results than adding individual alcohols as had been done in the 1980's when some refiners added methanol or ethanol to gasoline

Depolymerization of coal by oxidation and alkylation; Sanka bunkai to alkyl ka ni yoru sekitan kaijugo

Energy Technology Data Exchange (ETDEWEB)

Tomita, H.; Isoda, T.; Kusakabe, K.; Morooka, S. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Hayashi, J. [Hokkaido University, Sapporo (Japan). Center for Advanced Research of Energy Technology

1996-10-28

Change in depolymerization degree and coal structure was studied for depolymerization treatment of coal in various alcohol containing aqueous hydrogen peroxide. In experiment, the mixture of Yallourn coal, alcohol and aqueous hydrogen peroxide was agitated in nitrogen atmosphere of normal pressure at 70{degree}C for 12 hours. As the experimental result, the methanol solubility of only 5% of raw coal increased up to 35.2% by hydrogen peroxide treatment, while the yield of insoluble matters also decreased from 94% to 62%. Most of the gas produced during treatment was composed of inorganic gases such as CO and CO2, and its carbon loss was extremely decreased by adding alcohol. From the analytical result of carbon loss in hydrogen peroxide treatment, it was clarified that alkylation advances with introduction of alkyl group derived from alcohol into coal by hydrogen peroxide treatment under a coexistence of alcohol, and depolymerization reaction of coal itself is thus promoted by alcohol. 4 refs., 7 figs., 1 tab.

A characterization and evaluation of coal liquefaction process streams. Quarterly report, April 1--June 30, 1997

Energy Technology Data Exchange (ETDEWEB)

Brandes, S.D.; Robbins, G.A.; Winschel, R.A.

1997-12-31

This is the Technical Progress Report for the twelfth quarter of activities. Described in this report are the following activities: (1) Thirty-nine samples from four run conditions of HTI Run PB-07 were received. Appropriate samples were characterized by proton NMR spectroscopy, Fourier transform infrared spectroscopy, vacuum distillation, and solvent quality tests. (2) The University of Delaware completed their subcontract this quarter. A meeting was held on April 30, 1997 at the University to close out the subcontract. (3) Twelve sets of samples were chosen from the CONSOL sample bank for the study of the insoluble and presumed unreactive material from process stream samples. Each set consists of the whole process stream and the 454 C{sup +} (850 F{sup +}) distillation resid derived from that process stream. Processing data for all samples were compiled. The samples represent four Wilsonville pilot plant runs and two HTI runs.

Short-term energy outlook, quarterly projections, second quarter 1998

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-04-01

The Energy Information Administration (EIA) prepares quarterly short-term energy supply, demand, and price projections. The details of these projections, as well as monthly updates, are available on the Internet at: www.eia.doe.gov/emeu/steo/pub/contents.html. The paper discusses outlook assumptions; US energy prices; world oil supply and the oil production cutback agreement of March 1998; international oil demand and supply; world oil stocks, capacity, and net trade; US oil demand and supply; US natural gas demand and supply; US coal demand and supply; US electricity demand and supply; US renewable energy demand; and US energy demand and supply sensitivities. 29 figs., 19 tabs.

Purification technology for flue/off gases using electron beams

International Nuclear Information System (INIS)

Kojima, Takuji

2004-01-01

The present paper describes research and development on purification technology using electron beams for flue/off gases containing pollutants: removal of sulfate oxide and nitrogen oxide from flue gases of coal/oil combustion power plants, decomposition of dioxins in waste incineration flue gas, and decomposition/removal of toxic volatile organic compounds from off gas. (author)

Bioprocessing of lignite coals using reductive microorganisms

Energy Technology Data Exchange (ETDEWEB)

Crawford, D.L.

1992-03-29

In order to convert lignite coals into liquid fuels, gases or chemical feedstock, the macromolecular structure of the coal must be broken down into low molecular weight fractions prior to further modification. Our research focused on this aspect of coal bioprocessing. We isolated, characterized and studied the lignite coal-depolymerizing organisms Streptomyces viridosporus T7A, Pseudomonas sp. DLC-62, unidentified bacterial strain DLC-BB2 and Gram-positive Bacillus megaterium strain DLC-21. In this research we showed that these bacteria are able to solubilize and depolymerize lignite coals using a combination of biological mechanisms including the excretion of coal solublizing basic chemical metabolites and extracellular coal depolymerizing enzymes.

Cryogenic method for measuring nuclides and fission gases

Science.gov (United States)

Perdue, P.T.; Haywood, F.F.

1980-05-02

A cryogenic method is provided for determining airborne gases and particulates from which gamma rays are emitted. A special dewar counting vessel is filled with the contents of the sampling flask which is immersed in liquid nitrogen. A vertically placed sodium-iodide or germanium-lithium gamma-ray detector is used. The device and method are of particular use in measuring and identifying the radioactive noble gases including emissions from coal-fired power plants, as well as fission gases released or escaping from nuclear power plants.

Development of Continuous Solvent Extraction Processes For Coal Derived Carbon Products

Energy Technology Data Exchange (ETDEWEB)

Elliot B. Kennel; Dady B. Dadyburjor; Gregory W. Hackett; Manoj Katakdaunde; Liviu Magean; Alfred H. Stiller; Robert C. Svensson; John W. Zondlo

2006-09-30

In this reporting period, tonnage quantities of coal extract were produced but solid separation was not accomplished in a timely manner. It became clear that the originally selected filtration process would not be effective enough for a serious commercial process. Accordingly, centrifugation was investigated as a superior means for removing solids from the extract. Results show acceptable performance. Petrographic analysis of filtered solids was carried out by R and D Carbon Petrography under the auspices of Koppers and consultant Ken Krupinski. The general conclusion is that the material appears to be amenable to centrifugation. Filtered solids shows a substantial pitch component as well as some mesophase, resulting in increased viscosity. This is likely a contributing reason for the difficulty in filtering the material. Cost estimates were made for the hydotreatment and digestion reactors that would be needed for a 20,000 ton per year demonstration plants, with the aid of ChemTech Inc. The estimates show that the costs of scaling up the existing tank reactors are acceptable. However, a strong recommendation was made to consider pipe reactors, which are thought to be more cost effective and potentially higher performance in large scale systems. The alternate feedstocks for coke and carbon products were used to fabricate carbon electrodes as described in the last quarterly report. Gregory Hackett successfully defended his MS Thesis on the use of these electrodes in Direct Carbon Fuel Cell (DCFC), which is excerpted in Section 2.4 of this quarterly report.

Microbial desulfurization of coal

International Nuclear Information System (INIS)

Bos, P.; Boogerd, F.C.; Kuenen, J.G.

1992-01-01

In recent years, studies have been initiated to explore the possibilities of the use of biological systems in coal technology. This chapter discusses the principles behind the bioprocessing of coal, the advantages and disadvantages, and the economic feasibility of the process. For large-scale, coal-using, energy-producing plants, stack gas cleaning should be the treatment of choice. Biodesulfurization is preferable with industrial, small-scale, energy-producing plants. Treatment of the stack gases of these plants is not advisable because of high investment costs. Finally, it should be realized that biodesulfurization produces a waste stream that needs further treatment. 91 refs

Slag processing system for direct coal-fired gas turbines

Science.gov (United States)

Pillsbury, Paul W.

1990-01-01

Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The gas turbine system includes a primary zone for burning coal in the presence of compressed air to produce hot combustion gases and debris, such as molten slag. The turbine system further includes a secondary combustion zone for the lean combustion of the hot combustion gases. The operation of the system is improved by the addition of a cyclone separator for removing debris from the hot combustion gases. The cyclone separator is disposed between the primary and secondary combustion zones and is in pressurized communication with these zones. In a novel aspect of the invention, the cyclone separator includes an integrally disposed impact separator for at least separating a portion of the molten slag from the hot combustion gases.

Energy Conversion Alternatives Study (ECAS), General Electric Phase 1. Volume 1: Executive summary. [using coal or coal derived fuels

Science.gov (United States)

Corman, J. C.

1976-01-01

A data base for the comparison of advanced energy conversion systems for utility applications using coal or coal-derived fuels was developed. Estimates of power plant performance (efficiency), capital cost, cost of electricity, natural resource requirements, and environmental intrusion characteristics were made for ten advanced conversion systems. Emphasis was on the energy conversion system in the context of a base loaded utility power plant. All power plant concepts were premised on meeting emission standard requirements. A steam power plant (3500 psig, 1000 F) with a conventional coal-burning furnace-boiler was analyzed as a basis for comparison. Combined cycle gas/steam turbine system results indicated competitive efficiency and a lower cost of electricity compared to the reference steam plant. The Open-Cycle MHD system results indicated the potential for significantly higher efficiency than the reference steam plant but with a higher cost of electricity.

Applications of micellar enzymology to clean coal technology. Second quarterly report

Energy Technology Data Exchange (ETDEWEB)

Walsh, C.T.

1990-04-27

This project is designed to develop methods for pre-combustion coal remediation by implementing recent advances in enzyme biochemistry. The novel approach of this study is incorporation of hydrophilic oxidative enzymes in reverse micelles in an organic solvent. Enzymes from commercial sources or microbial extracts are being investigated for their capacity to remove organic sulfur from coal by oxidation of the sulfur groups, splitting of C-S bonds and loss of sulfur as sulfuric acid. Dibenzothiophene (DBT) and ethylphenylsulfide (EPS) are serving as models of organic sulfur-containing components of coal in initial studies.

Mercury transformation and speciation in flue gases from anthropogenic emission sources: a critical review

OpenAIRE

L. Zhang; S. X. Wang; Q. R. Wu; F. Y. Wang; C.-J. Lin; L. M. Zhang; M. L. Hui; J. M. Hao

2015-01-01

Mercury transformation mechanisms and speciation profiles are reviewed for mercury formed in and released from flue gases of coal-fired boilers, non-ferrous metal smelters, cement plants, iron and steel plants, municipal solid waste incinerators, and biomass burning. Mercury in coal, ores and other raw materials is released to flue gases in the form of Hg0 during combustion or smelting in boilers, kilns or furnaces. Decreasing temperature from over 800 °C t...

DEVELOPMENT OF DISPOSABLE SORBENTS FOR CHLORIDE REMOVAL FROM HIGH TEMPERATURE COAL-DERIVED GASES

Energy Technology Data Exchange (ETDEWEB)

Gopala Krishnan; Raghubir Gupta

1999-09-01

Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IGFC) systems require the development of high temperature sorbents for the removal of hydrogen chloride (HCl) vapor to less than 1 parts-per-million (ppm) levels. HCl is a highly reactive, corrosive, and toxic gas which must be removed to meet environmental regulations, to protect power generation equipment, and to minimize deterioration of hot gas desulfurization sorbents. The objective of this program was to develop disposable, alkali-based sorbents capable of reducing HCl vapor levels to less than 1 ppm in the temperature range from 400 to 750 C and pressures in the range from 1 to 20 atm. The primary areas of focus of this program were to investigate different methods of sorbent fabrication, testing their suitability for different reactor configurations, obtaining reaction kinetics data, and conducting a preliminary economic feasibility assessment. This program was a joint effort between SRI International (SRI), Research Triangle Institute (RTI), and General Electric Corporate Research and Development (GE-CRD). SRI, the prime contractor and RTI, a major subcontractor, performed most of the work in this program. Thermochemical calculations indicated that sodium-based sorbents were capable of reducing HCl vapor levels to less than 1 ppm at temperatures up to 650 C, but the regeneration of spent sorbents would require complex process steps. Nahcolite (NaHCO{sub 3}), a naturally-occurring mineral, could be used as an inexpensive sorbent to remove HCl vapor in hot coal gas streams. In the current program, nahcolite powder was used to fabricate pellets suitable for fixed-bed reactors and granules suitable for fluidized-bed reactors. Pilot-scale equipment were used to prepare sorbents in large batches: pellets by disk pelletization and extrusion techniques, and granules by granulation and spray-drying techniques. Bench-scale fixed- and fluidized-bed reactors were assembled at

Distilling coal, etc

Energy Technology Data Exchange (ETDEWEB)

Nelson, J

1917-12-21

Coals of various kinds such as shales, bitumens, and oil sand, peat, etc. are distilled at 350 to 450/sup 0/C and in the presence of vapors and gases obtained by cracking hydrocarbon oils, or the gases obtained by separating the condensable hydrocarbons therefrom, and, if desired, with the addition of superheated steam. The hydrocarbons are properly cracked by passing through molten lead as described in Specification 116,304. According to the Provisional Specification, superheated steam alone may be used to effect the distillation.

Process for electrochemically gasifying coal using electromagnetism

Science.gov (United States)

Botts, Thomas E.; Powell, James R.

1987-01-01

A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

Process for low mercury coal

Science.gov (United States)

Merriam, Norman W.; Grimes, R. William; Tweed, Robert E.

1995-01-01

A process for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal.

Rosebud SynCoal Partnership, SynCoal{reg_sign} demonstration technology update

Energy Technology Data Exchange (ETDEWEB)

Sheldon, R.W. [Rosebud SynCoal Partnership, Billings, MT (United States)

1997-12-31

An Advanced Coal Conversion Process (ACCP) technology being demonstrated in eastern Montana (USA) at the heart of one of the world`s largest coal deposits is providing evidence that the molecular structure of low-rank coals can be altered successfully to produce a unique product for a variety of utility and industrial applications. The product is called SynCoal{reg_sign} and the process has been developed by the Rosebud SynCoal Partnership (RSCP) through the US Department of Energy`s multi-million dollar Clean Coal Technology Program. The ACCP demonstration process uses low-pressure, superheated gases to process coal in vibrating fluidized beds. Two vibratory fluidized processing stages are used to heat and convert the coal. This is followed by a water spray quench and a vibratory fluidized stage to cool the coal. Pneumatic separators remove the solid impurities from the dried coal. There are three major steps to the SynCoal{reg_sign} process: (1) thermal treatment of the coal in an inert atmosphere, (2) inert gas cooling of the hot coal, and (3) removal of ash minerals. When operated continuously, the demonstration plant produces over 1,000 tons per day (up to 300,000 tons per year) of SynCoal{reg_sign} with a 2% moisture content, approximately 11,800b Btu/lb and less than 1.0 pound of SO{sub 2} per million Btu. This product is obtained from Rosebud Mine sub-bituminous coal which starts with 25% moisture, 8,600 Btu/lb and approximately 1.6 pounds of SO{sub 2} per million Btu.

Short-Term Energy Outlook: Quarterly projections. Fourth quarter 1993

Energy Technology Data Exchange (ETDEWEB)

1993-11-05

The Energy Information Administration (EIA) prepares quarterly, short-term energy supply, demand, and price projections for publication in February, May, August, and November in the Short-Term Energy Outlook (Outlook). An annual supplement analyzes the performance of previous forecasts, compares recent cases with those of other forecasting services, and discusses current topics related to the short-term energy markets. (See Short-Term Energy Outlook Annual Supplement, DOE/EIA-0202.) The forecast period for this issue of the Outlook extends from the fourth quarter of 1993 through the fourth quarter of 1994. Values for the third quarter of 1993, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in the Weekly Petroleum Status Report) or are calculated from model simulations using the latest exogenous information available (for example, electricity sales and generation are simulated using actual weather data). The historical energy data are EIA data published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications.

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

Energy Technology Data Exchange (ETDEWEB)

Elliot B. Kennel; Philip L. Biedler; Chong Chen; Dady Dadyburjor; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

2005-04-13

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. A process has been developed which results in high quality binder pitch suitable for use in graphite electrodes or carbon anodes. A detailed description of the protocol is given by Clendenin. Briefly, aromatic heavy oils are hydro-treated under mild conditions in order to increase their ability to dissolve coal. An example of an aromatic heavy oil is Koppers Carbon Black Base (CBB) oil. CBB oil has been found to be an effective solvent and acceptably low cost (i.e., significantly below the market price for binder pitch, or about $280 per ton at the time of this writing). It is also possible to use solvents derived from hydrotreated coal and avoid reliance on coke oven recovery products completely if so desired.

Effects of coal-derived trace species on performance of molten carbonate fuel cells

Energy Technology Data Exchange (ETDEWEB)

1992-05-01

The Carbonate Fuel Cell is a very promising option for highly efficient generation of electricity from many fuels. If coal-gas is to be used, the interactions of coal-derived impurities on various fuel cell components need to be understood. Thus the effects on Carbonate Fuel Cell performance due to ten different coal-derived contaminants viz., NH{sub 3}, H{sub 2}S, HC{ell}, H{sub 2}Se, AsH{sub 3}, Zn, Pb, Cd, Sn, and Hg, have been studied at Energy Research Corporation. Both experimental and theoretical evaluations were performed, which have led to mechanistic insights and initial estimation of qualitative tolerance levels for each species individually and in combination with other species. The focus of this study was to investigate possible coal-gas contaminant effects on the anode side of the Carbonate Fuel Cell, using both out-of-cell thermogravimetric analysis by isothermal TGA, and fuel cell testing in bench-scale cells. Separate experiments detailing performance decay in these cells with high levels of ammonia contamination (1 vol %) and with trace levels of Cd, Hg, and Sn, have indicated that, on the whole, these elements do not affect carbonate fuel cell performance. However, some performance decay may result when a number of the other six species are present, singly or simultaneously, as contaminants in fuel gas. In all cases, tolerance levels have been estimated for each of the 10 species and preliminary models have been developed for six of them. At this stage the models are limited to isothermal, benchscale (300 cm{sup 2} size) single cells. The information obtained is expected to assist in the development of coal-gas cleanup systems, while the contaminant performance effects data will provide useful basic information for modeling fuel cell endurance in conjunction with integrated gasifier/fuel-cell systems (IGFC).

21st century energy solutions. Coal and Power Systems FY2001 program briefing

International Nuclear Information System (INIS)

None

2001-01-01

The continued strength of American's economy depends on the availability of affordable energy, which has long been provided by the Nations rich supplies of fossil fuels. Forecasts indicate that fossil fuels will continue to meet much of the demand for economical electricity and transportation fuels for decades to come. It is projected that natural gas, oil, and coal will supply nearly 90% of US energy in 2020, with coal fueling around 50% of the electricity. It is essential to develop ways to achieve the objectives for a cleaner environment while using these low-cost, high-value fuels. A national commitment to improved technologies-for use in the US and abroad-is the solution. The Coal and Power Systems program is responding to this commitment by offering energy solutions to advance the clean, efficient, and affordable use of the Nations abundant fossil fuel resources. These solutions include: (1) Vision 21-A multi-product, pollution-free energy plant-producing electricity, fuels, and/or industry heat-could extract 80% or more of the energy value of coal and 85% or more of the energy value of natural gas; (2) Central Power Systems-Breakthrough turbines and revolutionary new gasification technologies that burn less coal and gas to obtain energy, while reducing emissions; (3) Distributed Generation-Fuel cell technology providing highly efficient, clean modular power; (4) Fuels-The coproduction of coal-derived transportation fuels and power from gasification-based technology; (5) Carbon Sequestration-Capturing greenhouse gases from the exhaust gases of combustion or other sources, or from the atmosphere itself, and storing them for centuries or recycling them into useful products; and (6) Advanced Research-Going beyond conventional thinking in the areas of computational science, biotechnology, and advanced materials

URBAN WOOD/COAL CO-FIRING IN THE BELLEFIELD BOILERPLANT

International Nuclear Information System (INIS)

James T. Cobb, Jr.; Gene E. Geiger; William W. Elder III

2001-01-01

During the second quarter, important preparatory work was continued so that the experimental activities can begin toward the end of the third quarter or early in the fourth quarter. The Environmental Questionnaire was submitted to the U.S. DOE National Energy Technology Laboratory (NETL), after thorough review by the Bellefield Boiler Plant (BBP). Letters were submitted to the Allegheny County Health Department (ACHD) and the Pennsylvania Department of Environmental Protection (PADEP) to seek R and D variances for permits at the BBP, the J. A. Rutter Company (JARC), and Emery Tree Service (ETS) for their portion of the project. Memoranda of understanding were executed by the University of Pittsburgh (University) with the BBP, JARC and ETS. Construction wood was collected from Thompson Properties. Discussions were held with the BBP and Energy Systems Associates (ESA), the BBP's engineering consultant. Presentations describing the University of Pittsburgh Wood/Coal Co-Firing Program were provided to the American Chemical Society (ACS), the Federal Energy Management Program (FEMP), the Upgraded Coal Interest Group (UCIG) of the Electric Power Research Institute (EPRI), the Engineering Center for Environment and Energy (ECEE) of the University of Pittsburgh, the Pittsburgh Coal Conference (PCC), the Pennsylvania Ethanol Workshop, BioEnergy 2000 and the Kick-Off Meeting of the Biomass Cofiring Opportunities Solicitation Projects

Australian coal prospects and response to air quality issues

International Nuclear Information System (INIS)

Cain, D.A.

1992-01-01

Australia is unique in its high dependency on coal as a domestic energy source and as a major export commodity. Coal provides about 41% of Australia's primary energy and is the country's largest export. Australia's domestic air quality issues and standards are reviewed and current Australian research aimed at reducing emissions from both bituminous and brown coal combustion is summarized. Australia's greenhouse policy is also discussed. The future role of coal in the world, particularly in the Asia-Pacific region, where three quarters of Australia's coal exports are sold, is reviewed. Forecasts of the world import demand for both metallurgical coal and thermal coal to the year 2000 are provided. The supply capacity of major coal exporting countries in summarized and estimates of export coal market shares in 2000 given. Finally, the future of Australia's domestic use of coal is discussed, in the light of climate change concerns

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2007-03-17

hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. Emission testing indicates that the coal derived material has more trace metals related to coal than petroleum, as seen in previous runs. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. The co-coking of the runs with the new coal have begun, with the coke yield similar to previous runs, but the gas yield is lower and the liquid yield is higher. Characterization of the products continues. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking.

Coal marketing in Asia: Opportunities and challenges

International Nuclear Information System (INIS)

Klingner, D.

1996-01-01

In Asia, coal currently accounts for over 40 percent of the fossil fuel used for commercial energy. This paper briefly surveys the forces that are likely to decide the future role coal will play as a prime source of energy in the vigorous economies of Asia. As Australia is well placed to profit from Asia's growing need for coal, the challenge to Australian coal suppliers is how to maximize its potential contribution. Four-fifths of all new coal fired electrical generating capacity in the world in the next decade will be located in Asia. Three-quarters of Australia's coal exports are to Asian customers and, conversely, 40 percent of Asian imports are from Australia. Australian coal suppliers have established ties and a depth of marketing experience in the region on which to build. However, pricing policies, and the emergence of the private power producers, together with environmental pressures, will present challenges for the future. (author). 1 fig

Cooperative research program in coal liquefaction. Quarterly report, May 1, 1993--October 31, 1993

Energy Technology Data Exchange (ETDEWEB)

Hoffman, G.P. [ed.

1994-07-01

This report summarizes progress in four areas of research under the general heading of Coal Liquefaction. Results of studies concerning the coliquefaction of coal with waste organic polymers or chemical products of these polymers were reported. Secondly, studies of catalytic systems for the production of clean transportation fuels from coal were discussed. Thirdly, investigations of the chemical composition of coals and their dehydrogenated counterparts were presented. These studies were directed toward elucidation of coal liquefaction processes on the chemical level. Finally, analytical methodologies developed for in situ monitoring of coal liquefaction were reported. Techniques utilizing model reactions and methods based on XAFS, ESR, and GC/MS are discussed.

Coal conversion processes. Quarterly report, December 13, 1983-March 12, 1984

Energy Technology Data Exchange (ETDEWEB)

Cobb, J.T. Jr.; Biloen, P.; Holder, G.D.; Klinzing, G.E.; Tierney, J.W.

1984-05-01

Experimental work is continuing on four separate projects related to coal conversion processes. The direct digital control of exothermic multiphase reactions is being studied in an experimental adiabatic flow reactor. The existence of two stable steady states for the Fischer-Tropsch reaction network at the same temperature and feed condition has been verified and quantified. Various absorbents for SO/sub 2/ and NO/sub X/ are being studied. The absorption of NO/sub 2/ by methanol and N-cyclohexyl-2-pyrrolidone has been extensively examined. Preliminary data have been obtained with triethylene-tetraamine. Hindered amines will be studied next. Procedures for the preparation of liquid membranes have been tested and the incorporation of hindered amines in them will now be examined. Isotopic switching is being used to study the way in which promoters affect supported metal catalysts. With improved resolution from the mass spectrometer, early quantitative results give indications of three different surface species and of non-statistical ingrowth of /sup 13/C into the product molecules. A program for the study of the extraction of coal and oil shale using supercritical fluids is being carried out. The effect of the presence of piperidine on the amount of toluene solubles produced by supercritical extraction of coal with toluene/piperidine mixture has been determined. A new kinetic model for the extraction/liquefaction of coal by supercritical toluene and THF has been developed and proven satisfactory. Bruceton coal and Hi Na lignite have been extracted with supercritical water. 3 references, 7 figures, 6 tables.

Coal-fired high performance power generating system. Quarterly progress report

Energy Technology Data Exchange (ETDEWEB)

1992-07-01

The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of > 47% thermal efficiency; NO{sub x} SO {sub x} and Particulates < 25% NSPS; Cost of electricity 10% lower; coal > 65% of heat input and all solid wastes benign. In order to achieve these goals our team has outlined a research plan based on an optimized analysis of a 250 MW{sub e} combined cycle system applicable to both frame type and aeroderivative gas turbines. Under the constraints of the cycle analysis we have designed a high temperature advanced furnace (HITAF) which integrates several combustor and air heater designs with appropriate ash management procedures. Most of this report discusses the details of work on these components, and the R&D Plan for future work. The discussion of the combustor designs illustrates how detailed modeling can be an effective tool to estimate NO{sub x} production, minimum burnout lengths, combustion temperatures and even particulate impact on the combustor walls. When our model is applied to the long flame concept it indicates that fuel bound nitrogen will limit the range of coals that can use this approach. For high nitrogen coals a rapid mixing, rich-lean, deep staging combustor will be necessary. The air heater design has evolved into two segments: a convective heat exchanger downstream of the combustion process; a radiant panel heat exchanger, located in the combustor walls; The relative amount of heat transferred either radiatively or convectively will depend on the combustor type and the ash properties.

Clean utilization of coal

International Nuclear Information System (INIS)

Yueruem, Y.

1992-01-01

This volume contains 23 lectures presented at the Advanced Study Institute on 'Chemistry and Chemical Engineering of Catalytic Solid Fuel Conversion for the Production of Clean Synthetic Fuels', which was held at Akcay, Edremit, Turkey, between 21 July and August 3, 1991. Three main subjects: structure and reactivity of coal; cleaning of coal and its products, and factors affecting the environmental balance of energy usage and solutions for the future, were discussed in the Institute and these are presented under six groups in the book: Part 1. Structure and reactivity of coal; Part 2. Factors affecting environmental balance; Part 3. Pre-usage cleaning operations and processes; Part 4. Upgrading of coal liquids and gases; Part 5. Oxygen enriched processes; and Part 6. Probable future solution for energy and pollution problems. Separate abstracts have been prepared for all the lectures

Mercury transformation and speciation in flue gases from anthropogenic emission sources: a critical review

Science.gov (United States)

Zhang, Lei; Wang, Shuxiao; Wu, Qingru; Wang, Fengyang; Lin, Che-Jen; Zhang, Leiming; Hui, Mulin; Yang, Mei; Su, Haitao; Hao, Jiming

2016-02-01

Mercury transformation mechanisms and speciation profiles are reviewed for mercury formed in and released from flue gases of coal-fired boilers, non-ferrous metal smelters, cement plants, iron and steel plants, waste incinerators, biomass burning and so on. Mercury in coal, ores, and other raw materials is released to flue gases in the form of Hg0 during combustion or smelting in boilers, kilns or furnaces. Decreasing temperature from over 800 °C to below 300 °C in flue gases leaving boilers, kilns or furnaces promotes homogeneous and heterogeneous oxidation of Hg0 to gaseous divalent mercury (Hg2+), with a portion of Hg2+ adsorbed onto fly ash to form particulate-bound mercury (Hgp). Halogen is the primary oxidizer for Hg0 in flue gases, and active components (e.g., TiO2, Fe2O3, etc.) on fly ash promote heterogeneous oxidation and adsorption processes. In addition to mercury removal, mercury transformation also occurs when passing through air pollution control devices (APCDs), affecting the mercury speciation in flue gases. In coal-fired power plants, selective catalytic reduction (SCR) system promotes mercury oxidation by 34-85 %, electrostatic precipitator (ESP) and fabric filter (FF) remove over 99 % of Hgp, and wet flue gas desulfurization system (WFGD) captures 60-95 % of Hg2+. In non-ferrous metal smelters, most Hg0 is converted to Hg2+ and removed in acid plants (APs). For cement clinker production, mercury cycling and operational conditions promote heterogeneous mercury oxidation and adsorption. The mercury speciation profiles in flue gases emitted to the atmosphere are determined by transformation mechanisms and mercury removal efficiencies by various APCDs. For all the sectors reviewed in this study, Hgp accounts for less than 5 % in flue gases. In China, mercury emission has a higher Hg0 fraction (66-82 % of total mercury) in flue gases from coal combustion, in contrast to a greater Hg2+ fraction (29-90 %) from non-ferrous metal smelting, cement and

Direct estimation of diffuse gaseous emissions from coal fires: current methods and future directions

Science.gov (United States)

Engle, Mark A.; Olea, Ricardo A.; O'Keefe, Jennifer M. K.; Hower, James C.; Geboy, Nicholas J.

2013-01-01

Coal fires occur in nature spontaneously, contribute to increases in greenhouse gases, and emit atmospheric toxicants. Increasing interest in quantifying coal fire emissions has resulted in the adaptation and development of specialized approaches and adoption of numerical modeling techniques. Overview of these methods for direct estimation of diffuse gas emissions from coal fires is presented in this paper. Here we take advantage of stochastic Gaussian simulation to interpolate CO2 fluxes measured using a dynamic closed chamber at the Ruth Mullins coal fire in Perry County, Kentucky. This approach allows for preparing a map of diffuse gas emissions, one of the two primary ways that gases emanate from coal fires, and establishing the reliability of the study both locally and for the entire fire. Future research directions include continuous and automated sampling to improve quantification of gaseous coal fire emissions.

Coal investment and long term supply and demand outlook for coal in the Asia-Pacific Region

International Nuclear Information System (INIS)

Johnson, C.J.

1997-01-01

The theme of this symposium to look ahead almost a quarter century to 2020 gives one the freedom to speculate more than usual in projections for coal. It is important to attempt to take a long term look into the future of coal and energy, so that one can begin to prepare for major changes on the horizon. However, it would be a mistake to believe that the crystal ball for making long term projections is accurate for 2020. Hopefully it can suggest plausible changes that have long term strategic importance to Asia's coal sector. This paper presents the medium scenario of long term projects of coal production, consumption, imports and exports in Asia. The second part of the paper examines the two major changes in Asia that could be most important to the long term role of coal. These include: (1) the impact of strict environmental legislation on energy and technology choices in Asia, and (2) the increased role of the private sector in all aspects of coal in Asia

Alternative reaction routes during coal hydrogenation and coal derived oil upgrading

Energy Technology Data Exchange (ETDEWEB)

Schulz, H.; Kordokuzis, G.; Langner, M. (University of Karlsruhe, Karlsruhe (Germany, F.R.). Engler-Bunte-Institute)

1989-10-01

Alternative reaction routes have been traced for the hydrodenitrogenation and hydrodeoxygenation of coal structure related model compounds. Reaction pathways are very structure specific. It is shown how reaction mechanisms switch from one route to another with changes in reaction conditions and catalyst features. Optimization of coal liquefaction processes can make use of this detailed understanding of selectivity. 5 refs., 7 figs.

Company-level profile of international coal trade: 1985-1990

International Nuclear Information System (INIS)

Rutledge, J.; Wright, P.

1992-01-01

This article profiles the 61 parent companies from 21 countries which, in 1990, were responsible for 88% of world coal exports. The profile categorizes the parent companies according to their principal business activity, establishes the extent to which their operations are transnational, identifies those with the fastest growing coal exports and investigates the relationship between exporting and profitability. Its main findings are that the majority of coal exports are produced by companies for which coal is not their main business activity, that half of the companies in the study are transnationals but only a quarter are transnational in coal and that, in the context of declining profit margins between 1985 and 1990, there is no evidence of a relationship between the profitability of a company's coal operations and its propensity to export

The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report No. 4, July 1, 1992--September 30, 1992

Energy Technology Data Exchange (ETDEWEB)

1993-10-01

A base case flow sheet for the production of higher alcohols from coal derived synthesis gas has been completed, including an economic analysis. The details of the flow sheet and economics are in Appendix 1. The pay back period for the capital investment for the plant has been calculated as a function of the market price of the product, and this figure is also shown as Figure I in Appendix 1. The estimated installed cost is almost $500 MM, and the estimated annual operating cost is $64 MM. At a price in the vicinity of $1.00/gal for the alcohol product, the pay back period for construction of the plant is four years. These values should be considered preliminary, since many of the capital costs were obtained from other paper studies sponsored by DOE and TVA and very few values could be found from actual plants which were built. This issue is currently being addressed. The most expensive capital costs were found to be the gasifier, the cryogenic air separation plant, the steam/power generation plant and the acid gas/sulfur removal processes taken as a whole. It is planned to focus attention on alternatives to the base case. The problem is that it is less expensive to make syngas from natural gas. Therefore, it is essential to reduce the cost of syngas from coal. This is where the energy park concept becomes important. In order for this process to be economical (at current market and political conditions) a method must be found to reduce the cost of syngas manufacture either by producing energy or by-products. Energy is produced in the base case, but the amount and method has not been optimized. The economic arguments for this concept are detailed in Appendix 2.

Evaluation of catalytic combustion of actual coal-derived gas

Science.gov (United States)

Blanton, J. C.; Shisler, R. A.

1982-01-01

The combustion characteristics of a Pt-Pl catalytic reactor burning coal-derived, low-Btu gas were investigated. A large matrix of test conditions was explored involving variations in fuel/air inlet temperature and velocity, reactor pressure, and combustor exit temperature. Other data recorded included fuel gas composition, reactor temperatures, and exhaust emissions. Operating experience with the reactor was satisfactory. Combustion efficiencies were quite high (over 95 percent) over most of the operating range. Emissions of NOx were quite high (up to 500 ppm V and greater), owing to the high ammonia content of the fuel gas.

Treating effluents; recovering coal, etc

Energy Technology Data Exchange (ETDEWEB)

Jones, F B; Bury, E

1920-02-18

Liquor obtained by scrubbing coal gas with sea-water or fresh water, and containing or having added to it finely-divided carbonaceous material in suspension, is subjected to a froth-flotation process to recover the carbonaceous matter and organic materials in the froth, and render the remaining liquor innocuous. Liquor obtained by scrubbing distillation gases, such as coal gas, may be used as a frothing-agent in a froth flotation process for the recovery of carbonaceous substances such as coal from materials containing them, thereby producing a froth containing the coal, etc., and also the organic materials from the liquor. In some cases the effluent may be diluted with sea-water, and, in recovering carbonaceous shales, there may be added to the liquor a small proportion of paraffin oil.

Combustion and emissions characterization of pelletized coal fuels. Technical report, December 1, 1992--February 28, 1993

Energy Technology Data Exchange (ETDEWEB)

Rajan, S. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mechanical Engineering and Energy Processes

1993-05-01

The aim of this project is to demonstrate that sorbent-containing coal pellets made from low grade coal or coal wastes are viable clean burning fuels, and to compare their performance with that of standard run-of-mine coal. Fuels to be investigated are: (a) carbonated pellets containing calcium hydroxide sorbent, (b) coal fines-limestone pellets with cornstarch as binder, (c) pellets made from preparation plant recovered coal containing limestone sorbent and gasification tar as binder, and (d) a standard run-of-mine Illinois seam coal. The fuels will be tested in a laboratory scale 411 diameter circulating fluidized bed combustor. Progress this quarter has centered on the development of a hydraulic press based pellet mill capable of the high compaction pressures necessary to produce the gasification tar containing pellets outlined in (c) above. Limited quantities of the pellets have been made, and the process is being fine tuned before proceeding into the production mode. Tests show that the moisture content of the coal is an important parameter that needs to be fixed within narrow limits for a given coal and binder combination to produce acceptable pellets. Combustion tests with these pellet fuels and the standard coal are scheduled for the next quarter.

DUVAS (derivative uv-absorption spectrometer): instrument description and operating manual

International Nuclear Information System (INIS)

Hawthorne, A.R.; Dougherty, J.M.; Metcalfe, C.E.

1980-11-01

DUVAS is a real-time, field-portable spectrometer capable of monitoring a variety of aromatic organic vapors and inorganic gases at sub-ppM concentrations. The instrument is a prototype, microcomputer-controlled, derivative ultraviolet (UV) absorption spectrometer (DUVAS) developed primarily for area monitoring at coal conversion facilities, although other important occupational and environmental monitoring applications for compounds such as SO 2 , NO/sub x/, NH 3 , and HCHO are also being pursued

Short-term energy outlook: Quarterly projections, fourth quarter 1997

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-10-14

The Energy Information Administration (EIA) prepares quarterly short-term energy supply, demand, and price projections for printed publication in January, April, July, and October in the Short-Term Energy Outlook. The details of these projections, as well as monthly updates on or about the 6th of each interim month, are available on the internet at: www.eia.doe.gov/emeu/steo/pub/contents.html. The forecast period for this issue of the Outlook extends from the fourth quarter of 1997 through the fourth quarter of 1998. Values for the fourth quarter of 1997, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in EIA`s Weekly Petroleum Status Report) or are calculated from model simulations that use the latest exogenous information available (for example, electricity sales and generation are simulated by using actual weather data). The historical energy data, compiled in the fourth quarter 1997 version of the Short-Term Integrated Forecasting System (STIFS) database, are mostly EIA data regularly published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding. The STIFS model is driven principally by three sets of assumptions or inputs: estimates of key macroeconomic variables, world oil price assumptions, and assumptions about the severity of weather. 19 tabs.

The quarter wave resonator as a superconducting linac element

International Nuclear Information System (INIS)

Ben-Zvi, I.; Brennan, J.M.

1983-01-01

The electrical and mechanical properties of quarter wave resonators are derived. A procedure for optimal design of a quarter wave resonator for use in a superconducting heavy ion linac is given. It is concluded that a quarter wave resonator has significant advantages for this application. (orig.)

Hydrotreating of heavy distillate derived from Wandoan coal liquefaction

Energy Technology Data Exchange (ETDEWEB)

Sato, Y. [National Institute for Resources and Environment, Osaka (Japan). Hydrocarbon Research Lab.

1997-12-03

The paper reports how the hydrotreatment of coal-derived heavy distillate, obtained from the liquefaction of Wandoan coal using a 1 t/day bench unit, was performed to clarify the effects of catalyst species, reaction temperature and hydrogen pressure on the chemical composition of the product. Experimental runs were carried out over alumina-supported Go-Mo and Ni-Mo catalysts in a fixed bed reactor of 20 ml in volume at 350-390{degree}C under hydrogen pressure of 50-150 kg/cm{sup 2}G with liquid hourly space velocity (LHSV) of 0.5-2 h{sup -1}. The product, as analyzed by gas chromatography, indicated that larger amounts of alkylbenzenes such as toluene or xylenes were produced at the elevated temperature of 390{degree}C, but the concentrations of condensed aromatics such as naphthalene, biphenyl, fluorene and phenanthrene decreased with the severity of reaction conditions. Pyrene and methylpyrene decreased in amount with a shorter LHSV and higher hydrogen pressure, but increased at higher temperature of 390{degree}C. Shorter LHSV and higher hydrogen pressure are much more effective in hydrogenation, hydrodnitrogenation and hydrodeoxygenation than the higher reaction temperature up to 390{degree}C.

Gasification Characteristics of Coal/Biomass Mixed Fuels

Energy Technology Data Exchange (ETDEWEB)

Mitchell, Reginald [Stanford Univ., CA (United States). Mechanical Engineering Dept.

2014-09-01

A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co-produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle

Short-term energy outlook: Quarterly projections, Third quarter 1992

International Nuclear Information System (INIS)

1992-08-01

The Energy Information Administration (EIA) prepares quarterly, short-term energy supply, demand, and price projections for publication in February, May, August, and November in the Short-Term Energy Outlook (Outlook). An annual supplement analyzes the performance of previous forecasts, compares recent cases with those of other forecasting services, and discusses current topics related to the short-term energy markets. (See Short-Term Energy Outlook Annual Supplement, DOE/EIA-0202.) The principal users of the Outlook are managers and energy analysts in private industry and government. The forecast period for this issue of the Outlook extends from the third quarter of 1992 through the fourth quarter of 1993. Values for the second quarter of 1992, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in the Weekly Petroleum Status Report) or are calculated from model simulations using the latest exogenous information available (for example, electricity sales and generation are simulated using actual weather data). The historical energy data are EIA data published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding

Short-term energy outlook, quarterly projections, first quarter 1998

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-01-01

The forecast period for this issue of the Outlook extends from the first quarter of 1998 through the fourth quarter of 1999. Values for the fourth quarter of 1997, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in EIA`s Weekly Petroleum Status Report) or are calculated from model simulations that use the latest exogenous information available (for example, electricity sales and generation are simulated by using actual weather data). The historical energy data, compiled in the first quarter 1998 version of the Short-Term Integrated Forecasting System (STIFS) database, are mostly EIA data regularly published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding. The STIFS model is driven principally by three sets of assumptions or inputs: estimates of key macroeconomic variables, world oil price assumptions, and assumptions about the severity of weather. Macroeconomic estimates are adjusted by EIA to reflect EIA assumptions which may affect the macroeconomic outlook. By varying the assumptions, alternative cases are produced by using the STIFS model. 24 figs., 19 tabs.

Coal pyrolysis and char burnout under conventional and oxy-fuel conditions

Energy Technology Data Exchange (ETDEWEB)

Al-Makhadmeh, L.; Maier, J.; Scheffknecht, G. [Stuttgart Univ. (Germany). Institut fuer Verfahrenstechnik und Dampfkesselwesen

2009-07-01

Coal utilization processes such as combustion or gasification generally involve several steps i.e., the devolatilization of organic materials, homogeneous reactions of volatile matter with the reactant gases, and heterogeneous reactions of the solid (char) with the reactant gases. Most of the reported work about coal pyrolysis and char burnout were performed at low temperatures under environmental conditions related to the air firing process with single particle tests. In this work, coal combustion under oxy-fuel conditions is investigated by studying coal pyrolysis and char combustion separately in practical scales, with the emphasis on improving the understanding of the effect of a CO{sub 2}-rich gas environment on coal pyrolysis and char burnout. Two coals, Klein Kopje a medium volatile bituminous coal and a low-rank coal, Lausitz coal were used. Coal pyrolysis in CO{sub 2} and N{sub 2} environments were performed for both coals at different temperatures in an entrained flow reactor. Overall mass release, pyrolysis gas concentrations, and char characterization were performed. For char characterization ultimate analysis, particle size, and BET surface area were measured. Chars for both coals were collected at 1150 C in both CO{sub 2} and N{sub 2} environments. Char combustion was performed in a once-through 20 kW test facility in O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} atmospheres. Besides coal quality, oxygen partial pressure was chosen as a variable to study the effect of the gas environment on char burnout. In general, it is found that the CO{sub 2} environment and coal rank have a significant effect on coal pyrolysis and char burnout. (orig.)

Coal in India: current status and outlook - Panorama 2008

International Nuclear Information System (INIS)

2008-01-01

The world cannot do without coal. This energy source covers more than one-quarter (28.4% in 2006) of all primary energy consumption and is used to generate nearly 40% of all electricity consumed worldwide. All scenarios and forecasts agree that coal consumption will be growing substantially, driven mostly by China and India. According to the IEA reference scenario (World Energy Outlook 2007), these two countries are expected to account for 82% of the increase in global coal demand by 2030. The outlook for India gives cause for concern: despite a strong domestic coal industry, it could eventually become a major importer. If so, what will the economic, industrial and environmental consequences be?

Biochemical removal of HAP precursors from coal. Quarterly technical progress report, April--June 1996

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-12-31

Analytical methods were finalized and all analyses completed on shake flask tests with Indiana No. 5 and Pittsburgh No. 8 coal. A column leaching-rotating biological contractor (RBC) unit was used to bioleach pyrite and hazardous air pollutant precursors from Pittsburgh No. 8 coal. Shake flask tests with Rosebud subbituminous coal were begun. In connection with upcoming slurry column reactor tests, coal was prepared and shipped to INEL, and a detailed work plan was developed for operation and sampling for the tests. A manuscript and poster was prepared for presentation at the PETC contractors conference.

Effect of oxidation on the chemical nature and distribution of low-temperature pyrolysis products from bituminous coal

Energy Technology Data Exchange (ETDEWEB)

Furimsky, E.; MacPhee, J.A.; Vancea, L.; Ciavaglia, L.A.; Nandi, B.N.

1983-04-01

Two bituminous coals, a high volatile Eastern Canadian and a medium volatile Western Canadian, were used to investigate the effect of oxidation on yields and chemical composition of gases, liquids and chars produced during coal pyrolysis. Pyrolysis experiments were performed at 500 C using the Fischer assay method. Mild oxidation of coals resulted in a decrease of liquid hydrocarbon yields. Further coal oxidation increased the proportion of aromatic carbon in liquid products as determined by N.M.R. and also increased the content of oxygen in liquid products. The content of oxygen in chars was markedly lower than in corresponding coals. An attempt is made to explain reactions occurring during oxidation and subsequent pyrolysis of coal on the basis of differences in chemical composition of gases, liquids and chars. (19 refs.)

Effect of oxidation on the chemical nature and distribution of low-temperature pyrolysis products from bituminous coal

Energy Technology Data Exchange (ETDEWEB)

Furimsky, E.; Ciavaglia, L.A.; MacPhee, J.A.; Nandi, B.N.; Vancea, L.

1983-04-01

Two bituminous coals, a high volatile Eastern Canadian and a medium volatile Western Canadian, were used to investigate the effect of oxidation on yields and chemical composition of gases, liquids and chars produced during coal pyrolysis. Pyrolysis experiments were performed at 500/sup 0/C using the Fischer assay method. Mild oxidation of coals resulted in a decrease of liquid hydrocarbon yields. Further coal oxidation increased the proportion of aromatic carbon in liquid products as determined by n.m.r., and also increased the content of oxygen in liquid products. The content of oxygen in chars was markedly lower than in corresponding coals. An attempt is made to explain reactions occurring during oxidation and subsequent pyrolysis of coal on the basis of differences in chemical composition of gases, liquids and chars.

Proceedings of the 11th international conference on coal science

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-07-01

The theme of the conference was 'Exploring the horizons of coal'. The proceedings include 370 papers dealing with coal petrography, physical structure and properties, advanced characterization, oxidation and weathering, coal preparation and beneficiation, liquefaction and pyrolysis reactivity and products, combustion and combustion modeling, NOx, SO{sub x} and particulate emissions and controls, gasification fundamentals and processing, coal in iron making processes, chemistry of S, N, and Cl, mineral matter, trace elements and HAPS, chemicals, carbons and carbon products, coal combustion byproducts and ash chemistry, and greenhouse gases and sequestration. Although 'proceedings' are published, the conference was cancelled.

Effects of coal-derived trace species on performance of molten carbonate fuel cells. Final report

Energy Technology Data Exchange (ETDEWEB)

1992-05-01

The Carbonate Fuel Cell is a very promising option for highly efficient generation of electricity from many fuels. If coal-gas is to be used, the interactions of coal-derived impurities on various fuel cell components need to be understood. Thus the effects on Carbonate Fuel Cell performance due to ten different coal-derived contaminants viz., NH{sub 3}, H{sub 2}S, HC{ell}, H{sub 2}Se, AsH{sub 3}, Zn, Pb, Cd, Sn, and Hg, have been studied at Energy Research Corporation. Both experimental and theoretical evaluations were performed, which have led to mechanistic insights and initial estimation of qualitative tolerance levels for each species individually and in combination with other species. The focus of this study was to investigate possible coal-gas contaminant effects on the anode side of the Carbonate Fuel Cell, using both out-of-cell thermogravimetric analysis by isothermal TGA, and fuel cell testing in bench-scale cells. Separate experiments detailing performance decay in these cells with high levels of ammonia contamination (1 vol %) and with trace levels of Cd, Hg, and Sn, have indicated that, on the whole, these elements do not affect carbonate fuel cell performance. However, some performance decay may result when a number of the other six species are present, singly or simultaneously, as contaminants in fuel gas. In all cases, tolerance levels have been estimated for each of the 10 species and preliminary models have been developed for six of them. At this stage the models are limited to isothermal, benchscale (300 cm{sup 2} size) single cells. The information obtained is expected to assist in the development of coal-gas cleanup systems, while the contaminant performance effects data will provide useful basic information for modeling fuel cell endurance in conjunction with integrated gasifier/fuel-cell systems (IGFC).

Emissions of greenhouse gases from the use of transportation fuels and electricity

International Nuclear Information System (INIS)

DeLuchi, M.A.

1991-11-01

This report presents estimates of full fuel-cycle emissions of greenhouse gases from using transportation fuels and electricity. The data cover emissions of carbon dioxide (CO 2 ), methane, carbon monoxide, nitrous oxide, nitrogen oxides, and nonmethane organic compounds resulting from the end use of fuels, compression or liquefaction of gaseous transportation fuels, fuel distribution, fuel production, feedstock transport, feedstock recovery, manufacture of motor vehicles, maintenance of transportation systems, manufacture of materials used in major energy facilities, and changes in land use that result from using biomass-derived fuels. The results for electricity use are in grams of CO 2 -equivalent emissions per kilowatt-hour of electricity delivered to end users and cover generating plants powered by coal, oil, natural gas, methanol, biomass, and nuclear energy. The transportation analysis compares CO 2 -equivalent emissions, in grams per mile, from base-case gasoline and diesel fuel cycles with emissions from these alternative- fuel cycles: methanol from coal, natural gas, or wood; compressed or liquefied natural gas; synthetic natural gas from wood; ethanol from corn or wood; liquefied petroleum gas from oil or natural gas; hydrogen from nuclear or solar power; electricity from coal, uranium, oil, natural gas, biomass, or solar energy, used in battery-powered electric vehicles; and hydrogen and methanol used in fuel-cell vehicles

Quantifying greenhouse gas emissions from coal fires using airborne and ground-based methods

Science.gov (United States)

Engle, Mark A.; Radke, Lawrence F.; Heffern, Edward L.; O'Keefe, Jennifer M.K.; Smeltzer, Charles; Hower, James C.; Hower, Judith M.; Prakash, Anupma; Kolker, Allan; Eatwell, Robert J.; ter Schure, Arnout; Queen, Gerald; Aggen, Kerry L.; Stracher, Glenn B.; Henke, Kevin R.; Olea, Ricardo A.; Román-Colón, Yomayara

2011-01-01

Coal fires occur in all coal-bearing regions of the world and number, conservatively, in the thousands. These fires emit a variety of compounds including greenhouse gases. However, the magnitude of the contribution of combustion gases from coal fires to the environment is highly uncertain, because adequate data and methods for assessing emissions are lacking. This study demonstrates the ability to estimate CO2 and CH4 emissions for the Welch Ranch coal fire, Powder River Basin, Wyoming, USA, using two independent methods: (a) heat flux calculated from aerial thermal infrared imaging (3.7–4.4 t d−1 of CO2 equivalent emissions) and (b) direct, ground-based measurements (7.3–9.5 t d−1 of CO2 equivalent emissions). Both approaches offer the potential for conducting inventories of coal fires to assess their gas emissions and to evaluate and prioritize fires for mitigation.

Weighted sum of gray gases model optimization for numerical investigations of processes inside pulverized coal-fired furnaces

Science.gov (United States)

Crnomarkovic, Nenad; Belosevic, Srdjan; Tomanovic, Ivan; Milicevic, Aleksandar

2017-12-01

The effects of the number of significant figures (NSF) in the interpolation polynomial coefficients (IPCs) of the weighted sum of gray gases model (WSGM) on results of numerical investigations and WSGM optimization were investigated. The investigation was conducted using numerical simulations of the processes inside a pulverized coal-fired furnace. The radiative properties of the gas phase were determined using the simple gray gas model (SG), two-term WSGM (W2), and three-term WSGM (W3). Ten sets of the IPCs with the same NSF were formed for every weighting coefficient in both W2 and W3. The average and maximal relative difference values of the flame temperatures, wall temperatures, and wall heat fluxes were determined. The investigation showed that the results of numerical investigations were affected by the NSF unless it exceeded certain value. The increase in the NSF did not necessarily lead to WSGM optimization. The combination of the NSF (CNSF) was the necessary requirement for WSGM optimization.

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

Energy Technology Data Exchange (ETDEWEB)

Elliot B. Kennel; R. Michael Bergen; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Alfred H. Stiller; W. Morgan Summers; John W. Zondlo

2006-05-12

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, coking and composite fabrication continued using coal-derived samples. These samples were tested in direct carbon fuel cells. Methodology was refined for determining the aromatic character of hydro treated liquid, based on Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FTIR). Tests at GrafTech International showed that binder pitches produced using the WVU solvent extraction protocol can result in acceptable graphite electrodes for use in arc furnaces. These tests were made at the pilot scale.

Coal-water slurry fuel internal combustion engine and method for operating same

Science.gov (United States)

McMillian, Michael H.

1992-01-01

An internal combustion engine fueled with a coal-water slurry is described. About 90 percent of the coal-water slurry charge utilized in the power cycle of the engine is directly injected into the main combustion chamber where it is ignited by a hot stream of combustion gases discharged from a pilot combustion chamber of a size less than about 10 percent of the total clearance volume of main combustion chamber with the piston at top dead center. The stream of hot combustion gases is provided by injecting less than about 10 percent of the total coal-water slurry charge into the pilot combustion chamber and using a portion of the air from the main combustion chamber that has been heated by the walls defining the pilot combustion chamber as the ignition source for the coal-water slurry injected into the pilot combustion chamber.

Synergistic Effect of Co-utilization of Coal and Biomass Char: An Overview

Science.gov (United States)

Paiman, M. E. S.; Hamzah, N. S.; Idris, S. S.; Rahman, N. A.; Ismail, K.

2018-05-01

Global concerns on impact of greenhouse gases emission, mostly released from coal-fired power plant, and the depletion of fossil fuel particularly coal, has led the production of electricity from alternatives resources such as co-utilization technologies. Previous studies proved that the co-utilization of coal and biomass/biomass chars has significantly reduced the emission of greenhouse gases either during the pyrolysis, combustion or gasification process in laboratories, pilots as well as in the industrial scales. Interestingly, most of the studies reported the presence of synergistic effect during the co-utilization processes particularly between coal and biomass char while some are not. Biomass chars were found to have porous and highly disorder carbon structure and belong to the class of most reactive carbon material, resulting to be more reactive than those hard coal and lignite. Up to date, microwave assisted pyrolysis is one of the best and latest techniques employed to produce better quality of biomass chars and it is also reduce the processing cost. Lot of works has been done regarding on the existence of synergistic effects during its co-utilization. However, the knowledge is limited to thermal and product characteristics so far. Even so, the specific reasons behind its existence are yet to understand well. Therefore, in this paper, the emphasis will be given on the synergistic effects on emission characteristics of co-utilization of coal and biomass chars so that it can be apply in energy-based industries to help in reduction of the greenhouse gases emission.

The method of determination of mercury adsorption from flue gases

Directory of Open Access Journals (Sweden)

Budzyń Stanisław

2017-01-01

Full Text Available For several recent years Faculty of Energy and Fuels of the AGH University of Science and Technology in Krakow conduct intensive studies on the occurrence of mercury contained in thermal and coking coals, as well as on the possible reduction of fossil-fuel mercury emissions. This research focuses, among others, on application of sorbents for removal of mercury from flue gases. In this paper we present the methodology for testing mercury adsorption using various types of sorbents, in laboratory conditions. Our model assumes burning a coal sample, with a specific mercury content, in a strictly determined time period and temperature conditions, oxygen or air flow rates, and the flow of flue gases through sorbent in a specific temperature. It was developed for particular projects concerning the possibilities of applying different sorbents to remove mercury from flue gases. Test stand itself is composed of a vertical pipe furnace inside which a quartz tube was mounted for sample burning purposes. At the furnace outlet, there is a heated glass vessel with a sorbent sample through which flue gases are passing. Furnace allows burning at a defined temperature. The exhaust gas flow path is heated to prevent condensation of the mercury vapor prior to contact with a sorbent. The sorbent container is positioned in the heating element, with controlled and stabilized temperature, which allows for testing mercury sorption in various temperatures. Determination of mercury content is determined before (coal and sorbent, as well as after the process (sorbent and ash. The mercury balance is calculated based on the Hg content determination results. This testing method allows to study sorbent efficiency, depending on sorption temperature, sorbent grain size, and flue-gas rates.

The Kyoto Protocol and the coal industry in Colombia

International Nuclear Information System (INIS)

Viana Rubio, Edgar

1998-02-01

In this article is studied the possible incidence of the commitments reached in the Kyoto Protocol on the coal market, making emphasis in the Colombian case. Projections, made in a study of Hill y Associates, points out that in a scenario of greenhouse gases emissions reduction, the market of the thermal coal will be seriously affected by the incidence on their demand

The South African coal industry - a millennium review

Energy Technology Data Exchange (ETDEWEB)

Lind, G.H.; Phillips, H.R. [University of Witwatersrand, Johannesburg (South Africa)

2001-06-01

South Africa is a significant contributor to southern Africa and Europe's coal needs and is expected to remain in this important position for the foreseeable future. This review paper of the South African coal mining industry highlights that, although abundant, the easily mineable reserves will become depleted within the next quarter century. Socio-economic issues of unique, local importance such as the HIV/AIDS pandemic as well as policies propagated by South Africa's post-apartheid government are detailed, as are programmes in research and development that will ensure that South Africa's long term coal industry is, at the every least, maintained. 11 refs., 9 figs., 7 tabs.

Production of reduction gases: partial oxidation of hydrocarbons and coal

Energy Technology Data Exchange (ETDEWEB)

Tippmer, K

1976-04-01

After some general remarks on reduction gas and quality demands, the Texaco process of partial oxidation with scrubbing is dealt with. A comparison of current iron-sponge techniques shows that a heat demand below 3 M kcal/t Fe should be envisaged, which means that heavy fuel oil or coal should be used. The special features of oxygen generation, coal processing, demands made on fuel oil, gasoline, and natural gas, gas generation, soot recovery, hydrogen sulphide-carbon dioxide scrubbing, system Benfield HP process, recycle-carbon dioxide scrubbing, auxiliary steam system, gas preheating, recycle gas cooling and compression, process data and heat balances for natural gas (one-heat system) and heating fuel oil or naphtha (two-heat system) are given.

Gas distributor for fluidized bed coal gasifier

Science.gov (United States)

Worley, Arthur C.; Zboray, James A.

1980-01-01

A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

Short-term energy outlook. Quarterly projections, 2nd quarter 1994

Energy Technology Data Exchange (ETDEWEB)

1994-05-01

The Energy Information Administration (EIA) prepares quarterly, short-term energy supply, demand, and price projections for publication in February, May, August, and November in the Short-Term Energy Outlook (Outlook). An annual supplement analyzes the performance of previous forecasts, compares recent cases with those of other forecasting services, and discusses current topics related to the short-term energy markets. The forecast period for this issue of the Outlook extends from the second quarter of 1994 through the fourth quarter of 1995. Values for the first quarter of 1994, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in the Weekly Petroleum Status Report) or are calculated from model simulations using the latest exogenous information available. The historical energy data, compiled into the second quarter 1994 version of the Short-Term Integrated Forecasting System (STIFS) database, are mostly EIA data regularly published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding. The STIFS database is archived quarterly and is available from the National Technical Information Service. The cases are produced using the STIFS. The STIFS model is driven principally by three sets of assumptions or inputs: estimates of key macroeconomic variables, world oil price assumptions, and assumptions about the severity of weather. Macroeconomic estimates are produced by DRI/McGraw-Hill but are adjusted by EIA to reflect EIA assumptions about the world price of crude oil, energy product prices, and other assumptions which may affect the macroeconomic outlook. The EIA model is available on computer tape from the National Technical Information Service.

Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 2: Appendixes A--S

Energy Technology Data Exchange (ETDEWEB)

DeLuchi, M.A. [Argonne National Lab., IL (United States)]|[Univ. of California, Davis, CA (United States). Inst. of Transportation Studies

1993-11-01

This volume contains the appendices to the report on Emission of Greenhouse Gases from the Use of Transportation Fuels and Electricity. Emissions of methane, nitrous oxide, carbon monoxide, and other greenhouse gases are discussed. Sources of emission including vehicles, natural gas operations, oil production, coal mines, and power plants are covered. The various energy industries are examined in terms of greenhouse gas production and emissions. Those industries include electricity generation, transport of goods via trains, trucks, ships and pipelines, coal, natural gas and natural gas liquids, petroleum, nuclear energy, and biofuels.

Strength Reduction of Coal Pillar after CO2 Sequestration in Abandoned Coal Mines

Directory of Open Access Journals (Sweden)

Qiuhao Du

2017-02-01

Full Text Available CO2 geosequestration is currently considered to be the most effective and economical method to dispose of artificial greenhouse gases. There are a large number of coal mines that will be scrapped, and some of them are located in deep formations in China. CO2 storage in abandoned coal mines will be a potential option for greenhouse gas disposal. However, CO2 trapping in deep coal pillars would induce swelling effects of coal matrix. Adsorption-induced swelling not only modifies the volume and permeability of coal mass, but also causes the basic physical and mechanical properties changing, such as elastic modulus and Poisson ratio. It eventually results in some reduction in pillar strength. Based on the fractional swelling as a function of time and different loading pressure steps, the relationship between volumetric stress and adsorption pressure increment is acquired. Eventually, this paper presents a theory model to analyze the pillar strength reduction after CO2 adsorption. The model provides a method to quantitatively describe the interrelation of volumetric strain, swelling stress, and mechanical strength reduction after gas adsorption under the condition of step-by-step pressure loading and the non-Langmuir isothermal model. The model might have a significantly important implication for predicting the swelling stress and mechanical behaviors of coal pillars during CO2 sequestration in abandoned coal mines.

76 FR 80553 - Mandatory Reporting of Greenhouse Gases: Technical Revisions to the Petroleum and Natural Gas...

Science.gov (United States)

2011-12-23

... permeability gas, shale gas, coal seam, or other tight reservoir rock. For example, wells producing coal bed... separation means one or more of the following processes: forced extraction of natural gas liquids, sulfur and... Mandatory Reporting of Greenhouse Gases: Technical Revisions to the Petroleum and Natural Gas Systems...

DEVELOPMENT OF A VALIDATED MODEL FOR USE IN MINIMIZING NOx EMISSIONS AND MAXIMIZING CARBON UTILIZATION WHEN CO-FIRING BIOMASS WITH COAL

International Nuclear Information System (INIS)

Larry G. Felix; P. Vann Bush

2002-01-01

This is the sixth Quarterly Technical Report for DOE Cooperative Agreement No. DE-FC26-00NT40895. A statement of the project objectives is included in the Introduction of this report. Two additional biomass co-firing test burns were conducted during this quarter. In the first test (Test 10), up to 20% by weight dry hardwood sawdust and switchgrass was compiled with Galatia coal and injected through the dual-register burner. Galatia coal is a medium-sulfur Illinois Basin coal ((approx)1.0% S). The dual-register burner is a generic low-NO(sub x) burner that incorporates two independent wind boxes. In the second test (Test 11), regular ((approx)70% passing 200 mesh) and finely ground ((approx)90% passing 200 mesh) Pratt Seam coal was injected through the single-register burner to determine if coal grind affects NO(sub x) and unburned carbon emissions. The results of these tests are presented in this quarterly report. Significant progress has been made in implementing a modeling approach to combine reaction times and temperature distributions from computational fluid dynamic models of the pilot-scale combustion furnace with char burnout and chemical reaction kinetics to predict NO(sub x) emissions and unburned carbon levels in the furnace exhaust. No additional results of CFD modeling have been received as delivery of the Configurable Fireside Simulator is expected during the next quarter. Preparations are under way for continued pilot-scale combustion experiments with the single-register burner and a low-volatility bituminous coal. Some delays have been experienced in the acquisition and processing of biomass. Finally, a project review was held at the offices of Southern Research in Birmingham, on February 27, 2002

Power Systems Development Facility. Quarterly report, July--September 1995

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-11-01

The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a fimction of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and hot gas cleanup units: carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during this reporting period was continuing the detailed design of the facility towards completion and integrating the balance-of-plant processes and particulate control devices (PCDS) into the structural and process designs. Substantial progress in construction activities was achieved during the quarter. Delivery and construction of the process structural steel is nearing completion. Nearly all equipment are set in its place and the FW equipment and the PCDs are being set in the structure.

Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

Science.gov (United States)

Grindley, Thomas

1989-01-01

A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

30 CFR 71.700 - Inhalation hazards; threshold limit values for gases, dust, fumes, mists, and vapors.

Science.gov (United States)

2010-07-01

... gases, dust, fumes, mists, and vapors. 71.700 Section 71.700 Mineral Resources MINE SAFETY AND HEALTH... limit values for gases, dust, fumes, mists, and vapors. (a) No operator of an underground coal mine and... limit values adopted by the American Conference of Governmental Industrial Hygienists in “Threshold...

Performance effects of coal-derived contaminants on the carbonate fuel cell

Energy Technology Data Exchange (ETDEWEB)

Pigeaud, A. [Energy Research Corp., Danbury, CT (United States); Wilemski, G. [Physical Sciences, Inc., Andover, MA (United States)

1993-05-01

Coal-derived contaminant studies have been pursued at ERC since the early 1980`s when the pace of carbonate fuel cell development began to markedly increase. Initial work was concerned with performance effects on laboratory and bench-scale carbonate fuel cells primarily due to sulfur compounds. Results have now also been obtained with respect to nine additional coal-gas contaminants, including volatile trace metal species. Thermochemical calculations, out-of-cell experiments, and cell performance as well as endurance testshave recently been conducted which have involved the following species: NH{sub 3}, H{sub 2}S [COS], HCl, AsH{sub 3}[As{sub 2}(v)], Zn(v), Pb(v), Cd(v), H{sub 2} Se, Hg(v), Sn(v). Employing thermochemically calculated results, thermogravimetric (TGA) and pre-, and post-test analytical data as well as fuel cell performance observations, it has been shown that there are four main mechanisms of contaminant interaction with the carbonate fuel cell. These have been formulated into performance models for six significant contaminant species, thus providing long-term endurance estimations.

Performance effects of coal-derived contaminants on the carbonate fuel cell

Energy Technology Data Exchange (ETDEWEB)

Pigeaud, A. (Energy Research Corp., Danbury, CT (United States)); Wilemski, G. (Physical Sciences, Inc., Andover, MA (United States))

1993-01-01

Coal-derived contaminant studies have been pursued at ERC since the early 1980's when the pace of carbonate fuel cell development began to markedly increase. Initial work was concerned with performance effects on laboratory and bench-scale carbonate fuel cells primarily due to sulfur compounds. Results have now also been obtained with respect to nine additional coal-gas contaminants, including volatile trace metal species. Thermochemical calculations, out-of-cell experiments, and cell performance as well as endurance testshave recently been conducted which have involved the following species: NH[sub 3], H[sub 2]S [COS], HCl, AsH[sub 3][As[sub 2](v)], Zn(v), Pb(v), Cd(v), H[sub 2] Se, Hg(v), Sn(v). Employing thermochemically calculated results, thermogravimetric (TGA) and pre-, and post-test analytical data as well as fuel cell performance observations, it has been shown that there are four main mechanisms of contaminant interaction with the carbonate fuel cell. These have been formulated into performance models for six significant contaminant species, thus providing long-term endurance estimations.

Current status of U.S. coal utilization and non-fuel uses of fossil fuels

International Nuclear Information System (INIS)

Song, C.S.; Schobert, H.; Scaroni, A.W.

1997-01-01

An understanding of the current situation is important for projecting the future direction of coal utilization. The world's annual consumption of coal in 1995 was 5104.01 million short tons (MST, 1 short ton = 0.907 metric ton). Coal plays a very important role in the US energy supply; US coal production in 1995 totaled 1033 MST, including 611.1 MST of bituminous coal, 328.4 MST of subbituminous coal, 86.1 MST of lignite, and 4.1 MST of anthracite. US coal consumption totaled 940.6 MST, with 88.1% in electric utilities, 3.5% in coke plants, 7.8% for other industrial uses, and only 0.6% in the residential and commercial sectors. The amount of fossil resources used for non-fuel purposes accounted for 8.4% of the total annual consumption in 1995. Non-fuel uses of fossil fuels particularly coal may become more important in the future. The demonstrated coal reserves in the world are large enough for consumption for over 220 years at the 1995 level, while proven oil reserves are only about 40 times the world's 1995 consumption level. Coal has several positive attributes when considered as a feedstock for aromatic chemicals, specialty chemicals, and carbon-based materials. Existing nonfuel uses of coals include (1) high temperature carbonization of bituminous and subbituminous coals to make metallurgical coke; (2) gasification of coal to make synthesis gases and other chemicals; (3) use of coal in manufacturing other materials such as activated carbons, carbon molecular sieves (CMS) and production of phosphorus (phosphoric acid); (4) the use of coal tars from carbonization and gasification for making aromatic and phenolic chemicals; (5) the use of coal tar pitch for making carbon fibers and activated carbon fibers; and (6) other non-fuel products derived from coal including combustion by-products. Coal may become more important both as an energy source and as the source of chemical feedstocks in the 21st century

Extraction with supercritical gases

Energy Technology Data Exchange (ETDEWEB)

Schneider, G M; Wilke, G; Stahl, E

1980-01-01

The contents of this book derives from a symposium on the 5th and 6th of June 1978 in the ''Haus der Technik'' in Essen. Contributions were made to separation with supercritical gases, fluid extraction of hops, spices and tobacco, physicochemical principles of extraction, phase equilibria and critical curves of binary ammonia-hydrocarbon mixtures, a quick method for the microanalytical evaluation of the dissolving power of supercritical gases, chromatography with supercritical fluids, the separation of nonvolatile substances by means of compressed gases in countercurrent processes, large-scale industrial plant for extraction with supercritical gases, development and design of plant for high-pressure extraction of natural products.

Clean Coal Technologies in China: Current Status and Future Perspectives

Directory of Open Access Journals (Sweden)

Shiyan Chang

2016-12-01

Full Text Available Coal is the dominant primary energy source in China and the major source of greenhouse gases and air pollutants. To facilitate the use of coal in an environmentally satisfactory and economically viable way, clean coal technologies (CCTs are necessary. This paper presents a review of recent research and development of four kinds of CCTs: coal power generation; coal conversion; pollution control; and carbon capture, utilization, and storage. It also outlines future perspectives on directions for technology research and development (R&D. This review shows that China has made remarkable progress in the R&D of CCTs, and that a number of CCTs have now entered into the commercialization stage.

The future of coal trading. Part 1: obstacles to coal trading

International Nuclear Information System (INIS)

Schafer, W.; Vaninetti, J.

1998-01-01

'Trading' as used in this article means routine buying and selling of futures contracts or options and other derivatives of future contracts. The variable nature of coal, lack of liquidity, and the coal industry's understanding and acceptance of commodity trading concepts are identified as three major barriers to successful trading of a coal futures contract. The article discusses these obstacles

REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

Energy Technology Data Exchange (ETDEWEB)

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2005-05-18

This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2005-11-17

This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

2004-09-17

This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Molecular biological enhancement of coal biodesulfurization. [Rhodococcus rhodochrous

Energy Technology Data Exchange (ETDEWEB)

Kilbane, J.J.; Bielaga, B.A.

1990-07-01

The overall objective of this project is to sue molecular genetics to develop strains of bacteria with enhanced ability to remove sulfur from coal and to obtain data that will allow the performance and economics of a coal biodesulfurization process to be predicted. The work planned for the current quarter (May 1990 to July 1990) includes the following activities: (1) Construct a cloning vector that can be used in Rhodococcus rhodochrous IGTS8 from the small cryptic plasmid found in Rhodococcus rhodochrous ATCC 190607; (2) Develop techniques for the genetic analysis of IGTS8; (3) Continue biochemical experiments, particularly those that may allow the identification of desulfurization-related enzymes; (4) Continue experiments with coal to determine the kinetics of organic sulfur removal.

[Quantitative spectrum analysis of characteristic gases of spontaneous combustion coal].

Science.gov (United States)

Liang, Yun-Tao; Tang, Xiao-Jun; Luo, Hai-Zhu; Sun, Yong

2011-09-01

Aimed at the characteristics of spontaneous combustion gas such as a variety of gases, lou limit of detection, and critical requirement of safety, Fourier transform infrared (FTIR) spectral analysis is presented to analyze characteristic gases of spontaneous combustion In this paper, analysis method is introduced at first by combing characteristics of absorption spectra of analyte and analysis requirement. Parameter setting method, sample preparation, feature variable abstract and analysis model building are taken into consideration. The methods of sample preparation, feature abstraction and analysis model are introduced in detail. And then, eleven kinds of gases were tested with Tensor 27 spectrometer. CH4, C2H6, C3H8, iC4H10, nC4H10, C2 H4, C3 H6, C3 H2, SF6, CO and CO2 were included. The optical path length was 10 cm while the spectra resolution was set as 1 cm(-1). The testing results show that the detection limit of all analytes is less than 2 x 10(-6). All the detection limits fit the measurement requirement of spontaneous combustion gas, which means that FTIR may be an ideal instrument and the analysis method used in this paper is competent for spontaneous combustion gas measurement on line.

Coal anion structure and chemistry of coal alkylation. Fourth quarterly progress report, December 1, 1977--February 28, 1978. [Carbon atoms in butyl groups

Energy Technology Data Exchange (ETDEWEB)

Stock, L.M.

1978-01-01

Three research problems are in progress. First, work is progressing well concerning the methods appropriate for the reductive alkylation of Illinois No. 6 coal samples. We have investigated the influence of the leaving group on the conversion of the Illinois coal to a soluble material. We find that the n-butyl iodide is more effective than other n-butyl halides. Second, preliminary results have been obtained concerning the distribution of hydrogen and deuterium atoms in the reaction of Illinois No. 6 coal samples with perdeuteriotetralin at 400/sup 0/C. Third, the nuclear magnetic resonance spectra of appropriate model compounds with n-butyl groups have been tabulated for comparison with the spectroscopic results obtained from coal alkylation products. Fourth, the chromatographic procedures necessary for the separation of the coal samples are being developed.

Characterization and supply of coal-based fuels. Quarterly report, February 1, 1989--April 30, 1989

Energy Technology Data Exchange (ETDEWEB)

1989-06-01

Contract objectives are as follows: Develop fuel specifications to serve combustor requirements. Select coals having appropriate compositional and quality characteristics as well as an economically attractive reserve base; Provide quality assurance for both the parent coals and the fuel forms; and deliver premium coal-based fuels to combustor developers as needed for their contract work. Progress is discussed, particulary in slurry fuel preparation and particle size distribution.

Mercury in coal and the impact of coal quality on mercury emissions from combustion systems

International Nuclear Information System (INIS)

Kolker, Allan; Senior, Constance L.; Quick, Jeffrey C.

2006-01-01

The proportion of Hg in coal feedstock that is emitted by stack gases of utility power stations is a complex function of coal chemistry and properties, combustion conditions, and the positioning and type of air pollution control devices employed. Mercury in bituminous coal is found primarily within Fe-sulfides, whereas lower rank coal tends to have a greater proportion of organic-bound Hg. Preparation of bituminous coal to reduce S generally reduces input Hg relative to in-ground concentrations, but the amount of this reduction varies according to the fraction of Hg in sulfides and the efficiency of sulfide removal. The mode of occurrence of Hg in coal does not directly affect the speciation of Hg in the combustion flue gas. However, other constituents in the coal, notably Cl and S, and the combustion characteristics of the coal, influence the species of Hg that are formed in the flue gas and enter air pollution control devices. The formation of gaseous oxidized Hg or particulate-bound Hg occurs post-combustion; these forms of Hg can be in part captured in the air pollution control devices that exist on coal-fired boilers, without modification. For a given coal type, the capture efficiency of Hg by pollution control systems varies according to type of device and the conditions of its deployment. For bituminous coal, on average, more than 60% of Hg in flue gas is captured by fabric filter (FF) and flue-gas desulfurization (FGD) systems. Key variables affecting performance for Hg control include Cl and S content of the coal, the positioning (hot side vs. cold side) of the system, and the amount of unburned C in coal ash. Knowledge of coal quality parameters and their effect on the performance of air pollution control devices allows optimization of Hg capture co-benefit

U.S. origin coking coal in the global market : a seismic shift in the global coal market

International Nuclear Information System (INIS)

Thrasher, E.

2010-01-01

This presentation discussed conditions in the global coal market and its impact on producers in the United States (U.S). The significant factors include the strong recovery in Asia, the switch from annual benchmark pricing to quarterly pricing, and the return of U.S. origin coking coal as a long-term supply source for Asia. The global recovery in manufacturing is strong in Asia and weak in more mature economies. A shift in trade patterns has occurred in that 4 of the top 10 destinations for U.S. coking coal exports are now in Asia, up from 1 in 2009, and the tonnage increases to these destinations are at unprecedented levels. Demand for U.S. origin coal will continue to increase as the economies in Western Europe improve and the emerging economies in Eastern Europe and South America grow. Looking at the U.S. coking coal supply, high volume type A coal will be used in the domestic market while high volume type B coal will be used for international demand. Government regulatory agencies create an uncertain environment for investments. Geology and the effects of regulatory actions have decreased productivity. An improvement to the supply chain is that lower cost ocean freight lowers the cost of delivered coal. The prices of coking coal have stabilized at levels that support reasonable returns on investment. The seaborne coking coal market has changed with China's shift to being a significant importer. Mine, rail, and port capacity will constrain the ability of producers in the U.S. to export coking coal to some degree. 2 tabs., 13 figs.

Forty years of the Weglopochodne Enterprise for Sale of Coal-Derived Products

Energy Technology Data Exchange (ETDEWEB)

Pinkowski, Z.

1986-02-01

Organizational structure of trade in coal-derived products in Poland from 1945 to 1985 is discussed. Fluctuations of organizational structures reflecting phases of centralization and decentralization of the national economy are analyzed. Coordinating role of the Weglopochodne Enterprise in the coking and chemical industries is stressed. Types of products produced by coking plants in Poland, trade and exports are discussed. Effects of organizational structures on development of coking plants are also discussed (increasing wear of coking plants, insufficient investment etc.). 3 references.

Method of burning highly reactive strongly slagging coal dust in a chamber furnace

Energy Technology Data Exchange (ETDEWEB)

Protsaylo, M.Ya.; Kotler, V.R.; Lobov, G.V.; Mechev, V.P.; Proshkin, A.V.; Zhuravlev, Yu.A.

1982-01-01

In the chamber furnace in order to reduce slagging, it is proprosed that, above the coal dust burners, nozzles be installed with inclination downwards through which air is fed in a mixture with flue gases. Under the influence of this flue gas-air mixture, the coal dust flame is deviated downwards. In this case there is an increase in the length of the flame and degree of filling of the volume of the furnace with the flame. This increases the effectiveness of dust burning. The input into the furnace of fuel jointly with the air and flue gases (optimally 10-15% of the total quantity of gases formed during fuel combustion) makes it possible to reduce the temperature in the furnace and the probability of slagging of the furnace walls.

DEVELOPMENT OF A VALIDATED MODEL FOR USE IN MINIMIZING NOx EMISSIONS AND MAXIMIZING CARBON UTILIZATION WHEN CO-FIRING BIOMASS WITH COAL

Energy Technology Data Exchange (ETDEWEB)

Larry G. Felix; P. Vann Bush

2002-01-31

This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No. DE-FC26-00NT40895. A statement of the project objectives is included in the Introduction of this report. One additional biomass co-firing test burn was conducted during this quarter. In this test (Test 9), up to 20% by weight dry hardwood sawdust and switchgrass was injected through the center of the single-register burner with Jacobs Ranch coal. Jacobs Ranch coal is a low-sulfur Powder River Basin coal ({approx} 0.5% S). The results from Test 9 as well as for Test 8 (conducted late last quarter) are presented in this quarterly report. Significant progress has been made in implementing a modeling approach to combine reaction times and temperature distributions from computational fluid dynamic models of the pilot-scale combustion furnace with char burnout and chemical reaction kinetics to predict NO{sub x} emissions and unburned carbon levels in the furnace exhaust. Additional results of CFD modeling efforts have been received and preparations are under way for continued pilot-scale combustion experiments with the dual-register burner. Finally, a project review was held at NETL in Pittsburgh, on November 13, 2001.

NOx Control Options and Integration for US Coal Fired Boilers

Energy Technology Data Exchange (ETDEWEB)

Mike Bockelie; Kevin Davis; Connie Senior Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-09-30

This is the seventeenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. The SCR slipstream reactor was assembled and installed at Plant Gadsden this quarter. Safety equipment for ammonia had not been installed at the end of the quarter, but will be installed at the beginning of next quarter. The reactor will be started up next quarter. Four ECN corrosion probes were reinstalled at Gavin and collected corrosion data for approximately one month. Two additional probes were installed and removed after about 30 hours for future profilometry analysis. Preliminary analysis of the ECN probes, the KEMA coupons and the CFD modeling results all agree with the ultrasonic tube test measurements gathered by AEP personnel.

Experimental investigations on combustion and emission behaviour during oxy-coal combustion

OpenAIRE

Dhungel, Bhupesh

2010-01-01

As the most abundant non-renewable energy source available, coal has traditionally played a major role in ensuring the security of energy, and will continue to play a key role in the world energy mix. The burning of coal has however always been a subject of environmental concern. In recent years, the emission of green house gases and global climate change has emerged as the largest environmental challenge. As coal fired power plants are categorised among the least carbon efficient energy prod...

Update of China economy and coal market

International Nuclear Information System (INIS)

Suen, H.

2010-01-01

This presentation discussed the surge in China's coal imports. The depressed demand for coal worldwide made huge tonnages available for the Chinese to buy at the same time that there was a willingness to sell coal more cheaply to compete with the Chinese domestic supply price and a coal shortage in China resulting from mine closures and consolidations. The Chinese Government is seeking to slow economic growth to control inflation and prevent an overheated economy. The government emphasis is on energy saving and emission reduction, production cuts at high energy consuming plants, the closure of outdated steel mills, and a restriction on power production. Steel production is expected to fall in the second half of the year as a result of surpluses. China's coal imports will increase in 2010; however, the consolidation process is now completed, and the new capacity will begin to be released in the second half of the year, ending the domestic coal shortage. The increase in the domestic market is constraining price increases. Premium hard coking coal (HCC) remains tight, but normal grade coals are in surplus and facing pressure to reduce prices. China's domestic coal prices form the bottom for the world coal market. Chinese import demand will continue, but demand is expected to gradually decline and be lower in 2011 as the domestic supply becomes sufficient. Nevertheless, China will always have a tremendous demand for coal and needs to import premium HCC. China adopted a quarterly price for the first time this year. 5 tabs., 4 figs.

Development of SRC-I product analysis. Volume 3. Documentation of procedures

Energy Technology Data Exchange (ETDEWEB)

Schweighardt, F.K.; Kingsley, I.S.; Cooper, F.E.; Kamzelski, A.Z.; Parees, D.M.

1983-09-01

This section documents the BASIC computer program written to simulate Wilsonville's GC-simulated distillation (GCSD) results at APCI-CRSD Trexlertown. The GC conditions used at APCI for the Wilsonville GCSD analysis of coal-derived liquid samples were described in the SRC-I Quarterly Technical Report, April-June 1981. The approach used to simulate the Wilsonville GCSD results is also from an SRC-I Quarterly Technical Report and is reproduced in Appendix VII-A. The BASIC computer program is described in the attached Appendix VII-B. Analysis of gases produced during coal liquefaction generates key information needed to determine product yields for material balance and process control. Gas samples from the coal process development unit (CPDU) and tubing bombs are the primary samples analyzed. A Carle gas chromatographic system was used to analyze coal liquefaction gas samples. A BASIC computer program was written to calculate the gas chromatographic peak area results into mole percent results. ICRC has employed several analytical workup procedures to determine the amount of distillate, oils, asphaltenes, preasphaltenes, and residue in SRC-I process streams. The ASE procedure was developed using Conoco's liquid column fractionation (LC/F) method as a model. In developing the ASE procedure, ICRC was able to eliminate distillation, and therefore quantify the oils fraction in one extraction step. ASE results were shown to be reproducible within +- 2 wt %, and to yield acceptable material balances. Finally, the ASE method proved to be the least affected by sample composition.

Feasibility studies of in-situ coal gasification in the Warrior coal field. Quarterly report

Energy Technology Data Exchange (ETDEWEB)

Douglas, G.W.; McKinley, M.D.

1979-03-01

Laboratory studies on a research combustor were used in an attempt to determine the length of oxidation and reduction zones. Unfortunately the buoyant effects of the heated gases caused the burn to proceed along the upper portion of the horizontal combustor. This made the interpretation of uncertain value. Methods of measuring the thermal conductivity and chemical reactivity of coke are discussed. A bibliography of the physical and chemical properties of coke is appended. (LTN)

Use of nitrogen stable isotope analysis to understand char nitrogen evolution during the fluidized-bed co-combustion of coal and sewage sludge

Energy Technology Data Exchange (ETDEWEB)

Ana Arenillas; Roberto Garcia; Chenggong Sun; Colin E. Snape; Angel H. Moreno; Fernando Rubiera; Jose J. Pis [University of Nottingham, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

2005-04-01

NOx emissions from sewage sludge combustion are a concern, because of the usually high nitrogen content of this fuel. The interactions during co-combustion in a fluidized-bed reactor of sewage sludge and a bituminous coal were evaluated, in relation to the nitrogen evolution during the combustion process. The nitrogen stable isotope measurements provide novel results regarding the tracing of nitrogen during combustion. Our preliminary results show that the co-combustion chars retain more nitrogen than expected, with the additional nitrogen being mainly derived from the sludge. Additional measurements are planned on the resultant co-combustion gases, to aid source apportionment of the NOx arising from coal/sewage interactions. 14 refs., 3 figs., 2 tabs.

Coal combustion technology in China

International Nuclear Information System (INIS)

Huang, Z.X.

1994-01-01

Coal is the most important energy source in China, the environmental pollution problem derived from coal burning is rather serious in China. The present author discusses coal burning technologies both in boilers and industrial furnaces and their relations with environmental protection problems in China. The technological situations of Circulating Fluidized Bed Coal Combustor, Pulverized Coal Combustor with Aerodynamic Flame Holder and Coal Water Slurry Combustion have been discussed here as some of the interesting problems in China only. (author). 3 refs

Assessment of the content of arsenic in solid by-products from coal combustion

Directory of Open Access Journals (Sweden)

Wierońska Faustyna

2017-01-01

Full Text Available The coal combustion processes constitute one of the major sources of heavy metals emission into the atmosphere. From the point of view of the reduction of the emission of heavy metals and the selection of the correct exhaust gas treatment system, it is important to monitor the amount of trace elements in the solid fuels and in the solid by-products from coal combustion. One of these highly toxic elements is arsenic. The average content of arsenic in Polish hard coals and lignites is 0 ÷ 40 mg/kg [1] and 5 ÷ 15 mg/kg [2], respectively. The world average content of arsenic in hard coals and lignites, is equal to 9.0 ± 0.8 and 7.4 ± 1.4 mg/kg [3], respectively. During coal combustion processes, a significant amount of arsenic enters the atmosphere through gases and fly ashes. The proportions in which those two forms of arsenic occur in exhaust gases depend on the conditions of combustion processes [4]. The aim of the research was to determine the content of arsenic in coal blends and by-products of their combustion (slag, fly ash, gypsum, filter cakes. The determination of the arsenic quantity was performed using the Atomic Absorption Spectrometry with the electrothermal atomization.

Studies of coupled chemical and catalytic coal conversion methods. Tenth quarterly report, January--March 1990

Energy Technology Data Exchange (ETDEWEB)

Stock, L.M.

1990-12-31

This report concerns our research on base-catalyzed coal solubilization and a new approach for hydrogen addition. The work on base-catalyzed, chemical solubilization is continuing. this report is focused on the hydrogenation research. Specifically it deals with the use of arene chromium carbonyl complexes as reagents for the addition of dideuterium to coal molecules. In one phase of the work, he has established that the aromatic hydrocarbons in a representative coal liquid can be converted in very good yield to arene chromium carbonyl compounds. In a second phase of the work directly related to our objective of improved methods for catalytic hydrogenation, he has established that the aromatic constituents of the same coal liquid add dideuterium in the presence of added napththalene chromium carbonyl.

Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

Science.gov (United States)

Grindley, T.

1988-04-05

A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

Hydrothermal pretreatment of coal. Quarterly report No. 1, September 21--December 15, 1989

Energy Technology Data Exchange (ETDEWEB)

Ross, D.S.

1989-12-21

We have examined changes in Argonne Premium samples of Wyodak coal following 30 min treatment in liquid water at autogenous pressures at 150{degrees}, 250{degrees}, and 350{degrees}C. In most runs the coal was initially dried at 60{degrees}C/1 torr/20 hr. The changes were monitored by pyrolysis field ionization mass spectrometry (py-FIMS) operating at 2.5{degrees}C/min from ambient to 500{degrees}C. We recorded the volatility patterns of the coal tars evolved over that temperature range, and in all cases the tar yields were 25%--30% of the starting coal on mass basis. There was essentially no change after the 150{degrees}C treatment. Small increases in volatility were seen following the 250{degrees}C treatment, but major effects were seen in the 350{degrees} work. The tar quantity remained unchanged; however, the volatility increased so the temperature of half volatility for the as-received coal of 400{degrees}C was reduced to 340{degrees}C. Control runs with no water showed some thermal effect, but the net effect from the presence of liquid water was clearly evident. The composition was unchanged after the 150{degrees} and 250{degrees}C treatments, but the 350{degrees} treatment brought about a 30% loss of oxygen. The change corresponded to loss of the elements of water, although loss of ``OH`` seemed to fit the analysis data somewhat better. The water loss takes place both in the presence and in the absence of added water, but it is noteworthy that the loss in the hydrothermal runs occurs at p(H{sub 2}O) = 160 atm. We conclude that the process must involve the dehydration solely of chemically bound elements of water, the dehydration of catechol is a specific, likely candidate.

The Tiptop coal-mine fire, Kentucky: Preliminary investigation of the measurement of mercury and other hazardous gases from coal-fire gas vents

Science.gov (United States)

Hower, James C.; Henke, Kevin R.; O'Keefe, Jennifer M.K.; Engle, Mark A.; Blake, Donald R.; Stracher, Glenn B.

2009-01-01

The Tiptop underground coal-mine fire in the Skyline coalbed of the Middle Pennsylvanian Breathitt Formation was investigated in rural northern Breathitt County, Kentucky, in May 2008 and January 2009, for the purpose of determining the concentrations of carbon dioxide (CO2), carbon monoxide (CO), and mercury (Hg) in the vent and for measuring gas-vent temperatures. At the time of our visits, concentrations of CO2 peaked at 2.0% and > 6.0% (v/v) and CO at 600 ppm and > 700 ppm during field analysis in May 2008 and January 2009, respectively. For comparison, these concentrations exceed the U.S. Occupational Safety & Health Administration (OSHA) eight-hour safe exposure limits (0.5% CO2 and 50 ppm CO), although the site is not currently mined. Mercury, as Hg0, in excess of 500 and 2100 μg/m3, in May and January, respectively, in the field, also exceeded the OSHA eight-hour exposure limit (50 μg/m3). Carbonyl sulfide, dimethyl sulfide, carbon disulfide, and a suite of organic compounds were determined at two vents for the first sampling event. All gases are diluted by air as they exit and migrate away from a gas vent, but temperature inversions and other meteorological conditions could lead to unhealthy concentrations in the nearby towns.

Radiological Impact Study of the Coal-Fired Power Plant of Narcea

Energy Technology Data Exchange (ETDEWEB)

Robles, B.; Baeza, A.; Mora, J. a.; Corbacho, J. a.; Trueba, C.; Guillen, J.; Rodriguez, Miralles, Y.

2014-04-01

Coal, fuel used in thermal power plants for electricity production, contains variable concentrations of naturally occurring radionuclides from natural disintegration series of {sup 2}38U, {sup 2}35U, {sup 2}32Th and also the 40K, which are enhanced in the wastes and coproducts due to the industrial process. For this reason, natural radionuclides which are part of the noncombustible fraction of coal, except those volatiles which incorporate directly to the flue gases, concentrates and are partitioned between fly ashes and bottom ashes. This enhancement could cause, to the workers of the installation and to members of the public around the plant, an increase in the exposure which should be assessed under the radiation protection point of view. Present report collect the results obtained from a screening assessment of the radiological impact derived from the normal operation of the Narcea coal-fired power plant. The project where this assessment was performed is part of a bigger project which is jointly developed by the Unit of Radiation Protection of the Public and the Environment (UPRPYMA) of CIEMAT and the Environmental Radioactivity Laboratory of the Extremadura University (LARUEX) in agreement with the Spanish Association of the Electrical Industry (ENUSA). (Author)

Relations between flash pyrolysis reactivity and oil/gas products from coals of different rank; Sekitankado no kotonaru shushu no sekitan no flash pyrolysis hannosei to gas oyobi eki seiseibutsu no kankei

Energy Technology Data Exchange (ETDEWEB)

Nonaka, T.; Kishino, M.; Sakanishi, K.; Korai, Y.; Mochida, I. [Kyushu University, Fukuoka (Japan). Institute of Advanced Material Study

1996-10-28

Curie point flash pyrolysis (FP) reactivity was studied experimentally using three kinds of coals with different coal ranks such as Yallourn brown coal, Tanitoharum sub-bituminous coal and Wandoan sub-bituminous coal. Experiment was performed using a curie point pyrolyzer in carrier gas of 20ml/min in gas flow rate at 450, 590 and 740{degree}C for 5sec. The experimental results were as follows. Each gas component obviously increased at 450-590{degree}C, however, C4-C6 gases drastically decreased at 590-740{degree}C accompanying reduction of the whole gas quantity. All of each polar component remarkably increased at 450-590{degree}C. Yallourn brown coal with high Owt%, in particular, contained a large amount of alkyl-hydroxybenzene group. The amount of cresol of all of three coal specimens also increased at 740{degree}C. It was thus suggested that this is coal constituent molecules derived from cutting of methylene-ether bridged bond by higher-temperature FP. 8 refs., 5 figs., 3 tabs.

Potential health impacts of burning coal beds and waste banks

Science.gov (United States)

Finkelman, R.B.

2004-01-01

Uncontrolled release of pollutants from burning coal beds and waste banks presents potential environmental and human health hazards. On a global scale, the emissions of large volumes of greenhouse gases from burning coal beds may contribute to climate change that alters ecosystems and patterns of disease occurrence. On regional and local scales, the emissions from burning coal beds and waste banks of acidic gases, particulates, organic compounds, and trace elements can contribute to a range of respiratory and other human health problems. Although there are few published reports of health problems caused by these emissions, the potential for problems can be significant. In India, large numbers of people have been displaced from their homes because of health problems caused by emissions from burning coal beds. Volatile elements such as arsenic, fluorine, mercury, and selenium are commonly enriched in coal deposits. Burning coal beds can volatilize these elements, which then can be inhaled, or adsorbed on crops and foods, taken up by livestock or bioaccumulated in birds and fish. Some of these elements can condense on dust particles that can be inhaled or ingested. In addition, selenium, arsenic, lead, tin, bismuth, fluorine, and other elements condense where the hot gaseous emissions come in contact with ambient air, forming mats of concentrated efflorescent minerals on the surface of the ground. These mats can be leached by rainwater and washed into local water bodies providing other potential routes of exposure. Although there are little data linking burning coal beds and waste banks to known health problems, a possibly analogous situation exists in rural China where mineralized coal burned in a residential environment has caused widespread and severe health problems such as fluorosis and arseniasis. ?? 2004 Elsevier B.V. All rights reserved.

Development of brown coal mining in the Federal Republic of Germany

Energy Technology Data Exchange (ETDEWEB)

Tilmann, W

1985-01-01

The significance of brown coal mining in the Federal Republic of Germany for the development of opencast technology and the power industry is discussed with emphasis on mining in the Rhineland Area. In 1984, 126.7 mt of brown coal were produced in the Federal Republic of Germany. In the development of high-performance equipment it is essential that the efficiency of the bucket-wheel excavator is increased. Trains and conveyors are mainly used for mine transport in the Federal Republic of Germany. A high moral commitment is linked to land claims, recultivation and environmental issues on the part of brown coal mining. In 1984 the percentage share of brown coal supplied to the public power stations was 83.6%, corresponding to 105.9 mt. The installed capacity of all brown coal power stations amounted to 12,764 MW at the end of 1984, providing around one quarter of overall public power output. Charge coal for coal refining has become more important and the production of brown coal dust and brown coal coke has also increased. The share of brown coal in domestic primary energy production is currently around 24% of 151 mt hard-coal units or around 10% of 376.5 mt hard-coal units in terms of energy consumption. 12 references.

[Characterization and supply of coal based fuels]. Quarterly technical report, February 1, 1988--April 30, 1988

Energy Technology Data Exchange (ETDEWEB)

1988-12-31

Contract objectives are as follows: Develop fuel specifications to serve combustor requirements; Select coals having appropriate compositional and quality characteristics as well as an economically attractive reserve base; Provide quality assurance for both the parent coals and the fuel forms; and deliver premium coal-based fuels to combustor developers as needed for their contract work. Progress is described.

Prospects of electron beam treatment of flue gases in the Philippines

International Nuclear Information System (INIS)

Cabalfin, Estelita G.

2005-01-01

Coal-fired and oil-based power plants operated in Philippines are totally 11 and 58 units respectively. The government recognizes the threat of air pollution, because more than one third of the electricity generation is fueled by coal. The Philippines Congress therefore enacted Republic Act 8749 (Clean Air Act of 1999) under which sulfur and nitrogen oxides concentration at the point of emission from stationary sources shall be strictly regulated. Under the UNDP/IAEA regional project on industrial application of radiation, the Philippine Nuclear Research Institute (PNRI) in cooperation with the National Power Corporation hosted two national executive management seminars on electron beam treatment of flue gases in 1990 and 1994. The Philippine Smelting and Refining Corporation (PASAR) has interest in this technology of reducing 90% SO 2 removal efficiency with EB power of 380 kW. PNRI promotes, through training courses and seminars, the applications of nuclear technology and radiation including EB treatment of flue gases. (S. Ohno)

Moderate temperature gas purification system: Application to high calorific coal-derived fuel

Energy Technology Data Exchange (ETDEWEB)

Kobayashi, M.; Shirai, H.; Nunokawa, M. [Central Research Institute of Electric Power Industry, Kanagawa (Japan)

2008-01-15

Simultaneous removal of dust, alkaline and alkaline-earth metals, halides and sulfur compounds is required to enlarge application of coal-derived gas to the high-temperature fuel cells and the fuel synthesis through chemical processing. Because high calorific fuel gas, such as oxygen-blown coal gas, has high carbon monoxide content, high-temperature (above 450{sup o}C) gas purification system is always subjected to the carbon deposition. We suggest moderate temperature (around 300{sup o}C) operation of the gas purification system to avoid the harmful disproportionation reaction and efficient removal of the various contaminants. Because the reaction rate is predominant to the performance of contaminant removal in the moderate temperature gas purification system, we evaluated the chemical removal processes; performance of the removal processes for halides and sulfur compounds was experimentally evaluated. The halide removal process with sodium aluminate sorbent had potential performance at around 300{sup o}C. The sulfur removal process with zinc ferrite sorbent was also applicable to the temperature range, though the reaction kinetics of the sorbent is essential to be approved.

Weldon Spring Site Remedial Action Project Federal Facilities Agreement: Quarterly environmental data summary for third quarter 1998

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-11-06

In support of the Weldon Spring Site Remedial Action Project Federal Facilities Agreement, a copy of the Quarterly Environmental Data Summary (QEDS) for the third quarter of 1998 is enclosed. The data presented in this letter and attachment constitute the QEDS. The data, except for air monitoring data and site KPA generated data (uranium analyses), were received from the contract laboratories, verified by the Weldon Spring Site verification group, and merged into the database during the third quarter of 1998. Air monitoring data presented are the most recent complete sets of quarterly data. Significant data, defined as data values that have exceeded defined above normal Level 2 values, are discussed in this letter for Environmental Monitoring Plan (EMP) generated data only. Above normal Level 2 values are based, in ES and H procedures, on historical high values, DOE Derived Concentration Guides (DCGs), NPDES limits, and other guidelines. The procedures also establish actions to be taken in the event that above normal data occur.

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2008-03-31

The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to

Shale gases, a windfall for France?

International Nuclear Information System (INIS)

Tonnac, Alain de; Perves, Jean-Pierre

2013-11-01

After having recalled the definition and origin of shale gases, the different non conventional gases and their exploitation techniques (hydraulic fracturing and horizontal drilling) this report examines whether these gases are an opportunity for France. Some characteristics and data of the fossil and gas markets are presented and commented: world primary energy consumption, proved reserves of non conventional gases and their locations, European regions which may possess reserves of shale gases and coal-bed methane, origins of gas imports in France. The second part addresses shale gas deposits and their exploitation: discussion of the influence of the various rock parameters, evolution of production. The third part discusses the exploitation techniques and specific drilling tools. The issue of exploitation safety and security is addressed as well as the associated controversies: about the pollution of underground waters, about the fact that deep drillings result in pollution, about the risks associated with hydraulic fracturing and injections of chemical products, about the hold on ground and site degradation, about water consumption, about pollution due to gas pipeline leakage, about seismic risk, about noise drawbacks, about risks for health, about exploration and production authorization and license, and about air pollution and climate. The last part addresses the French situation and its future: status of the energy bill, recommendations made by a previous government, cancellation of authorizations, etc. Other information are provided in appendix about non conventional hydrocarbons, about shale gas exploitation in the USA, and about the Lacq gas

Catalytic hydrotreatment of Illinois No. 6 coal-derived naphtha: comparison of molybdenum nitride and molybdenum sulfide for heteroatom removal

Energy Technology Data Exchange (ETDEWEB)

Raje, A.; Liaw, S.J.; Chary, K.V.R.; Davis, B.H. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

1995-03-16

The hydrotreatment of naphtha derived from Illinois No. 6 coal was investigated using molybdenum sulfide and nitride catalysts. The two catalysts are compared on the basis of total catalyst weight. Molybdenum sulfide is more active than molybdenum nitride for hydrodesulfurization (HDS) of a coal-derived naphtha. The rate of hydrodeoxygenation (HDO) of the naphtha over both catalysts are comparable. For hydrodenitrogenation (HDN), the sulfide is more active than the nitride only at higher temperatures ({gt}325{degree}C). Based upon conversion data, the naphtha can be lumped into a reactive and a less reactive fraction with each following first-order kinetics for heteroatom removal. The HDS and HDN rates and activation energies of the less reactive lump are smaller for the nitride than for the sulfide catalyst.

Coal use and coal technology study (KIS)

International Nuclear Information System (INIS)

Kram, T.; Okken, P.A.; Gerbers, D.; Lako, P.; Rouw, M.; Tiemersma, D.N.

1991-11-01

The title study aims to assess the possible role for coal in the Netherlands energy system in the first decades of the next century and the part new coal conversion technologies will play under various conditions. The conditions considered relate to (sectoral) energy demand derived from national scenarios in an international context, to energy prices, to environmental constraints (acidification, solid waste management and disposal) and to the future role for nuclear power production. Targets for reduction of greenhouse gas emissions are not explicitly included, but resulting CO 2 emissions are calculated for each variant case. The part that coal can play in the Dutch energy supply is calculated and analyzed by means

Phyto-bioconversion of hard coal in the Cynodon dactylon/coal rhizosphere.

Science.gov (United States)

Igbinigie, Eric E; Mutambanengwe, Cecil C Z; Rose, Peter D

2010-03-01

Fundamental processes involved in the microbial degradation of coal and its derivatives have been well documented. A mutualistic interaction between plant roots and certain microorganisms to aid growth of plants such as Cynodon dactylon (Bermuda grass) on hard coal dumps has recently been suggested. In the present study coal bioconversion activity of nonmycorrhizal fungi was investigated in the C. dactylon/coal rhizosphere. Fungal growth on 2% Duff-agar, gutation formation on nitric acid treated coal and submerged culture activity in nitrogen-rich and -deficient broth formed part of the screening and selection of the fungi. The selected fungal isolates were confirmed to be found in pristine C. dactylon/coal rhizosphere. To simulate bioconversion, a fungal aliquot of this rhizosphere was used as inoculum for a Perfusate fixed bed bioreactor, packed with coal. The results demonstrate an enhanced coal bioconversion facilitated by low molecular weight organics and the bioconversion of coal may be initiated by an introduction of nitrogen moieties to the coal substrate. These findings suggest a phyto-bioconversion of hard coal involving plant and microbes occurring in the rhizosphere to promote the growth of C. dactylon. An understanding of this relationship can serve as a benchmark for coal dumps rehabilitation as well as for the industrial scale bioprocessing of hard coal.

Measurement and modeling of advanced coal conversion processes, Volume II

Energy Technology Data Exchange (ETDEWEB)

Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

1993-06-01

A two dimensional, steady-state model for describing a variety of reactive and nonreactive flows, including pulverized coal combustion and gasification, is presented. The model, referred to as 93-PCGC-2 is applicable to cylindrical, axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using a discrete ordinates method. The particle phase is modeled in a lagrangian framework, such that mean paths of particle groups are followed. A new coal-general devolatilization submodel (FG-DVC) with coal swelling and char reactivity submodels has been added.

Coal demonstration plants. Quarterly report, April-June 1979

Energy Technology Data Exchange (ETDEWEB)

None

1980-04-01

The objective of the US DOE demonstration program is to demonstrate and verify second-generation technologies and validate the economic, environmental and productive capacity of a near commercial-size plant by integrating and operating a modular unit using commercial size equipment. These facilities are the final stage in the RD and D process aimed at accelerating and reducing the risks of industrial process implementation. Under the DOE program, contracts for the design, construction, and operation of the demonstration plants are awarded through competitive procedures and are cost shared with the industrial partner. The conceptual design phase is funded by the government, with the detailed design, procurement, construction, and operation phases being co-funded between industry and the government. The government share of the cost involved for a demonstration plant depends on the plant size, location, and the desirability and risk of the process to be demonstrated. The various plants and programs are discussed: Description and status, funding, history, flowsheet and progress during the current quarter. (LTN)

Trends and outlook of coal energy in Malaysia

Energy Technology Data Exchange (ETDEWEB)

Zainal Abidin Husin (Tenaga Nasional Berhad, Kuala Lumpur (Malaysia). Fuel and Materials Management Dept.)

1993-03-01

Current energy policy in Malaysia is directed towards development of natural gas resources although there is a strategy to diversify energy sources to gas, hydro, coal and oil. By the year 2000, however, coal could emerge as a major energy source. The author advocates the need for a policy direction for the coal industry - for exploration, mine planning, mixing methods, transport and regulations to ensure occupational health and safety. Malaysia has abundant coal resources but most are in Sarawak and Sabah whereas the bulk of energy demand is in the Peninsula Malaysia. A table defines known coal resources in Malaysia and a map shows their location. To ensure successful development of the coal industry, technologies must be developed to meet environmental requirements and global market competition. Several emerging technologies are mentioned: production of process-derived fuel and coal-derived liquid from sub-bituminous coal, coal liquefaction, manufacture of coal water mixture, coal beneficiation, and fluidised bed combustion. 1 fig., 1 tab.

Co-gasification of pine and oak biochar with sub-bituminous coal in carbon dioxide.

Science.gov (United States)

Beagle, E; Wang, Y; Bell, D; Belmont, E

2018-03-01

Pine and oak biochars derived as byproducts of demonstration-scale pyrolysis, and blends of these two feedstocks with Powder River Basin coal, were gasified in a carbon dioxide environment using a modified drop tube reactor (MDTR) and a thermogravimetric analyzer (TGA). The impact of gasification temperature on conversion kinetics was evaluated from the temporal evolution of major product gases in the MDTR as measured using a mass spectrometer. Random pore modeling was conducted to simulate gasification in the MDTR with favorable results. The MDTR and TGA were used to conduct gasification for assessment of non-linear additive effects in the blends. Additive analysis of the blends showed deviation from the experimental blend results, indicating inhibiting effects of co-gasifying the biochar and coal. Inhibitory effects are more significant for oak than pine and more pronounced in the TGA at lower gasification temperatures. Results are discussed in the context of feedstock and reactor type. Copyright © 2017 Elsevier Ltd. All rights reserved.

Direct Coal -to-Liquids (CTL) for Jet Fuel Using Biomass-Derived Solvents

Energy Technology Data Exchange (ETDEWEB)

Chauhan, Satya P. [Battelle Memorial Inst., Columbus, OH (United States); Garbark, Daniel B. [Battelle Memorial Inst., Columbus, OH (United States); Taha, Rachid [Battelle Memorial Inst., Columbus, OH (United States); Peterson, Rick [Battelle Memorial Inst., Columbus, OH (United States)

2017-09-30

Battelle has demonstrated a novel and potentially breakthrough technology for a direct coal-to-liquids (CTL) process for producing jet fuel using biomass-derived coal solvents (bio-solvents). The Battelle process offers a significant reduction in capital and operating costs and a substantial reduction in greenhouse gas (GHG) emissions, without requiring carbon capture and storage (CCS). The results of the project are the advancement of three steps of the hybrid coal/biomass-to-jet fuel process to the technology readiness level (TRL) of 5. The project objectives were achieved over two phases. In Phase 1, all three major process steps were explored and refined at bench-scale, including: (1) biomass conversion to high hydrogen-donor bio-solvent; (2) coal dissolution in biomass-derived bio-solvent, without requiring molecular H₂, to produce a synthetic crude (syncrude); and (3) two-stage catalytic hydrotreating/hydrogenation of syncrude to jet fuel and other distillates. In Phase 2, all three subsystems of the CTL process were scaled up to a pre-pilot scale, and an economic analysis was carried out. A total of over 40 bio-solvents were identified and prepared. The most unique attribute of Battelle’s bio-solvents is their ability to provide much-needed hydrogen to liquefy coal and thus increase its hydrogen content so much that the resulting syncrude is liquid at room temperature. Based on the laboratory-scale testing with bituminous coals from Ohio and West Virginia, a total of 12 novel bio-solvent met the goal of greater than 80% coal solubility, with 8 bio-solvents being as good as or better than a well-known but expensive hydrogen-donor solvent, tetralin. The Battelle CTL process was then scaled up to 1 ton/day (1TPD) at a pre-pilot facility operated in Morgantown, WV. These tests were conducted, in part, to produce enough material for syncrude-upgrading testing. To convert the Battelle-CTL syncrude into a form suitable as a blending stock for jet

Noble Gases in Lakes and Ground Waters

OpenAIRE

Kipfer, Rolf; Aeschbach-Hertig, Werner; Peeters, Frank; Stute, Marvin

2002-01-01

In contrast to most other fields of noble gas geochemistry that mostly regard atmospheric noble gases as 'contamination,' air-derived noble gases make up the far largest and hence most important contribution to the noble gas abundance in meteoric waters, such as lakes and ground waters. Atmospheric noble gases enter the meteoric water cycle by gas partitioning during air / water exchange with the atmosphere. In lakes and oceans noble gases are exchanged with the free atmosphere at the surface...

The identification of unusual microscopic features in coal and their derived chars: Influence on coal fluidized bed combustion

Energy Technology Data Exchange (ETDEWEB)

Valentim, B. [Centro de Geologia da Universidade do Porto, Rua do Campo Alegre 687, 4169-007 Porto (Portugal); Lemos de Sousa, M.J. [Centro de Geologia da Universidade do Porto, Praca de Gomes Teixeira, 4099-002 Porto (Portugal); Abelha, P.; Boavida, D.; Gulyurtlu, I. [Departamento de Engenharia Energetica e Controlo Ambiental (DEECA), Instituto Nacional de Engenharia, Tecnologia e Inovacao (INETI), Estrada do Paco do Lumiar, 22, Edif. J, 1649-038, Lisboa (Portugal)

2006-06-06

During the petrographic study of seven feed coals from different origins, it was found that these coals presented microfeatures such as: material size, shape, weathering, thermally affected particles and contamination. After devolatilization under fluidized bed conditions, some chars presented the consequences of the above mentioned microfeatures, i.e., unreacted coal, unswelled particles, coatings and microstratification. Since the amounts of the microfeatures observed were low (less than 1%), the present study is essentially observational/descriptional. However, it seems very likely, from the observations that were made, that the occurrence of one or more of these microfeatures in coal, depending on their kind and abundance, may have significant effect on the coal devolatilization. (author)

Emissions of organic hazardous air pollutants during Chinese coal combustion

Energy Technology Data Exchange (ETDEWEB)

Yan, R.; Zhu, H.J.; Zheng, C.G.; Xu, M.H. [Environmental Technology Institute, Singapore (Singapore). Innovative Center

2002-05-01

The emissions of organic hazardous air pollutants (HAPs) during the combustion of several typical Chinese coals were investigated. First, the distribution of four types of HAP, i.e., aliphatics, cyclic hydrocarbons, monoaromatic compounds and PAHs, in the CH{sub 2}C{sub l2} extracts of six Chinese coals were studied and the influences of the extractive times and coal varieties were also evaluated. Second, the partitioning of these HAPs in the flue gas during coal combustion in a small-scale reactor were investigated, depending on oven temperatures (500, 600, 700, 800, 900{sup o}C) and coal varieties. The behaviors of HAP in the combustion flue gas were compared with those in the CH{sub 2}, Cl{sub 2}, extracts. Finally, combustion was conducted at given conditions in two laboratory-scale reactors: a fluidized bed and a fixed bed. Two coals (Shengmu bituminous coal and Xunhuan anthracite coal) and one coke were considered. The HAP partitioning both in flue gases and in ashes were evaluated and compared between the two combustors.

Bioprocessing of lignite coals using reductive microorganisms. Final technical report, September 30, 1988--March 29, 1992

Energy Technology Data Exchange (ETDEWEB)

Crawford, D.L.

1992-03-29

In order to convert lignite coals into liquid fuels, gases or chemical feedstock, the macromolecular structure of the coal must be broken down into low molecular weight fractions prior to further modification. Our research focused on this aspect of coal bioprocessing. We isolated, characterized and studied the lignite coal-depolymerizing organisms Streptomyces viridosporus T7A, Pseudomonas sp. DLC-62, unidentified bacterial strain DLC-BB2 and Gram-positive Bacillus megaterium strain DLC-21. In this research we showed that these bacteria are able to solubilize and depolymerize lignite coals using a combination of biological mechanisms including the excretion of coal solublizing basic chemical metabolites and extracellular coal depolymerizing enzymes.

Co-pyrolysis of low rank coals and biomass: Product distributions

Energy Technology Data Exchange (ETDEWEB)

Soncini, Ryan M.; Means, Nicholas C.; Weiland, Nathan T.

2013-10-01

Pyrolysis and gasification of combined low rank coal and biomass feeds are the subject of much study in an effort to mitigate the production of green house gases from integrated gasification combined cycle (IGCC) systems. While co-feeding has the potential to reduce the net carbon footprint of commercial gasification operations, the effects of co-feeding on kinetics and product distributions requires study to ensure the success of this strategy. Southern yellow pine was pyrolyzed in a semi-batch type drop tube reactor with either Powder River Basin sub-bituminous coal or Mississippi lignite at several temperatures and feed ratios. Product gas composition of expected primary constituents (CO, CO{sub 2}, CH{sub 4}, H{sub 2}, H{sub 2}O, and C{sub 2}H{sub 4}) was determined by in-situ mass spectrometry while minor gaseous constituents were determined using a GC-MS. Product distributions are fit to linear functions of temperature, and quadratic functions of biomass fraction, for use in computational co-pyrolysis simulations. The results are shown to yield significant nonlinearities, particularly at higher temperatures and for lower ranked coals. The co-pyrolysis product distributions evolve more tar, and less char, CH{sub 4}, and C{sub 2}H{sub 4}, than an additive pyrolysis process would suggest. For lignite co-pyrolysis, CO and H{sub 2} production are also reduced. The data suggests that evolution of hydrogen from rapid pyrolysis of biomass prevents the crosslinking of fragmented aromatic structures during coal pyrolysis to produce tar, rather than secondary char and light gases. Finally, it is shown that, for the two coal types tested, co-pyrolysis synergies are more significant as coal rank decreases, likely because the initial structure in these coals contains larger pores and smaller clusters of aromatic structures which are more readily retained as tar in rapid co-pyrolysis.

Is there a future for coal in Ontario?

International Nuclear Information System (INIS)

Davies, G.

2004-01-01

This PowerPoint presentation examined the efficacy of a governmental decision in 2003 to close all Ontario coal stations by 2007. Coal currently represents one quarter of Ontario's energy and capacity. Projected supply and demand gaps for Ontario were presented for up to 2020. Ontario's supply options were outlined. It was noted that between $30 and $40 billion in investment in the electricity sector will be needed over the next 10 to 15 years. It was observed that closing coal plants may reduce pollution by 6 per cent at a cost of $2 billion. More than half the smog affecting Ontario comes from the United States, while much of the remaining half is caused by transportation emissions. Details of energy strategies related to coal in the United States were discussed. New coal power plant technologies include supercritical combustion; advanced air pollution control; circulating fluidized bed combustion and integrated coal gasification combined cycles. Coal power plant performance criteria were presented. Various research programs in the United States were reviewed, and roadmap performance targets were presented. It was concluded that high prices and uncertainty for natural gas fired options may reinforce views on the need to rethink coal closures. A strategy was recommended in which Ontario pursued economic options for reducing emissions across all sectors. New investments in latest and best technology for emissions reduction in Ontario's coal-fired stations were recommended, as well as a North American agreement on clean air, and increased Canadian participation in U.S. technology development efforts for clean coal and zero emissions plants by 2025. tabs., figs

Hydrogen production from coal gasification for effective downstream CO{sub 2} capture

Energy Technology Data Exchange (ETDEWEB)

Gnanapragasam, Nirmal V.; Reddy, Bale V.; Rosen, Marc A. [Faculty of Engineering and Applied Science, University of Ontario Institute of Technology, 2000 Simcoe Street North, Oshawa, Ontario, L1H 7K4 (Canada)

2010-05-15

The coal gasification process is used in commercial production of synthetic gas as a means toward clean use of coal. The conversion of solid coal into a gaseous phase creates opportunities to produce more energy forms than electricity (which is the case in coal combustion systems) and to separate CO{sub 2} in an effective manner for sequestration. The current work compares the energy and exergy efficiencies of an integrated coal-gasification combined-cycle power generation system with that of coal gasification-based hydrogen production system which uses water-gas shift and membrane reactors. Results suggest that the syngas-to-hydrogen (H{sub 2}) system offers 35% higher energy and 17% higher exergy efficiencies than the syngas-to-electricity (IGCC) system. The specific CO{sub 2} emission from the hydrogen system was 5% lower than IGCC system. The Brayton cycle in the IGCC system draws much nitrogen after combustion along with CO{sub 2}. Thus CO{sub 2} capture and compression become difficult due to the large volume of gases involved, unlike the hydrogen system which has 80% less nitrogen in its exhaust stream. The extra electrical power consumption for compressing the exhaust gases to store CO{sub 2} is above 70% for the IGCC system but is only 4.5% for the H{sub 2} system. Overall the syngas-to-hydrogen system appears advantageous to the IGCC system based on the current analysis. (author)

CAPTO method application to the quality assessment of Slovak brown coal

Directory of Open Access Journals (Sweden)

Turèániová ¼udmila

1998-09-01

Full Text Available This paper describes the principle and application of CAPTO (Controlled - atmosphere programmed - temperature oxidation method for the sulphur content valuation in coal. The principle of CAPTO consists in mixing the coal with an inert material (WO3 and oxidation of the sample by a linear increase of temperature to 1000oC. The evolved gases (CO2, H2O, SO2 and NO2 are analyzed by infrared sensors. The method enables the determination of different sulphur forms (sulphidic, elemental, sulphate, organic aromatic and organic non-aromatic, hydrogen, carbon and humidity. The results on Americal coal Illionois No. 6 and Slovakian brown coal Nováky serve as an illustration of the CAPTO method possibility.

Low-rank coal research. Final technical report, April 1, 1988--June 30, 1989, including quarterly report, April--June 1989

Energy Technology Data Exchange (ETDEWEB)

1989-12-31

This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

Unconventional gases: a North-American energy revolution not without consequences for Europe

International Nuclear Information System (INIS)

2011-01-01

This paper gives a definition of the different existing unconventional gases (coal-bed methane, tight gases, shale gases), and outlines that, although these gases as well as the techniques to extract them have been well known for a long time, it is the combination of two of these techniques (hydraulic fracturing or fracking, and horizontal drilling) which enables the current technological development and the exploitation of these gases. It also outlines that the current situation in terms of natural resources favours such a development. It evokes projects in the United States, China, India, Europe, and more particularly in France, stressing that environmental issues and population density in Europe are obstacles to perform these drillings. The author questions the production cost issue and explains how these developments, notably in the USA, may change completely the world energetic landscape, and therefore entail a review of the European energy agenda. He explores the possible consequences of a durable decrease of gas prices

Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, October 1--December 31, 1991

Energy Technology Data Exchange (ETDEWEB)

Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

1992-03-01

CONSOL R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

Dissolution of subbituminous coal in tetrahydroquinoline

Energy Technology Data Exchange (ETDEWEB)

Silver, H F; Frazee, W S; Broderick, T E; Hurtubise, R J

1986-05-01

Two different samples of Wyodak subbituminous coal from the Powder River Basin in Wyoming were liquefied in a two dm/sup 3/ batch reactor using 1,2,3,4 tetrahydroquinoline, THQ, as a solvent. Sufficient sample was produced to determine product boiling ranges by distillation and to measure THQ distribution in the product. Product distillation showed that even at cyclohexane conversions greater than 50%, net distillate yields produced using THQ as a solvent were negative. In some cases, high boiling, coal-derived residue yields were greater than the dry coal charged to the reactor. These observations have been attributed to THQ losses resulting from dimerization of the THQ and reactions between THQ and coal derived components. 5 references.

Study of greenhouse gases emission factor for nuclear power chain of China

International Nuclear Information System (INIS)

Ma Zhonghai; Pan Ziqiang; Xie Jianlun; Xiu Binglin

2001-01-01

The Greenhouse Gases Emission Factor (GGEF) for nuclear power chain of China is calculated based on Life Cycle Analysis method and the definition of full energy chain. There is no greenhouse gases released directly from nuclear power plant. The greenhouse gases emission from nuclear power plant is mainly from coal-fired electricity supply to nuclear power plant for its normal operation and the production of construction materials those are used in the nuclear power plant. The total GGEF of nuclear power chain in China is 13.71 g-co 2 /kWh. It is necessary to regulate un-rational power source mix and to use the energy sources in rational way for reducing the greenhouse gas effect. Nuclear power for electricity generation is one of effective ways to reduce greenhouse gases emission and retard the greenhouse effect

Study on supported binary sulfide catalysts for secondary hydrogenation of coal-derived liquids; Sekitan ekikayu niji suisoka shokubai no kenkyu

Energy Technology Data Exchange (ETDEWEB)

Shimada, H.; Matsubayashi, N.; Sato, T.; Imamura, M.; Yoshimura, Y.; Nishijima, A. [National Institute of Materials and Chemical Research, Tsukuba (Japan)

1995-07-28

To utilize the high performance of supported catalysts in coal liquefaction processes, one of the promising ways is to apply hydroprocessing sulfide catalysts to the secondary hydrogenation of coal-derived liquids which have undergone the solid separation unit. However, when the product yield from the first-stage liquefaction is maximized, the feed stocks in the secondary hydrogenation contain large amounts of residual fractions with preasphaltenes and metallic components. In this case, the development of a long-life catalyst is essential to establish the two-stage process as a practical one. From this viewpoint, the authors have investigated the deactivation causes of supported Ni-Mo sulfide catalysts through the analysis of the used catalysts in the secondary hydrogenation of coal-derived liquids for long periods. The major cause of the catalyst deactivation has been found to be metallic and carbonaceous deposition on the catalyst, which results thin layer which covers the catalyst particles. The catalysts located at the reactor inlet are more rapidly deactivated than those at the rector exit because of larger amounts of metallic foul ants and the above described shell-like layer. Hydrocracking active sites are much heavily deactivated compared with hydrogenation active sites. It is inferred that the basic or polar compounds contained in coal liquids are permanency adsorbed on the hydrocracking active sites. Spectroscopic analysis of the used catalysts clarified the destruction of the active phase of the binary sulfides, through the segregation and crystal growth. The structural changes of the catalysts are very likely caused by heteroatom compounds in the preasphaltenes. Thus, the primary cause of the catalyst deactivation is the preasphaltenes in the coal liquids. Hydroaromatic compounds in the coal liquids suppress the change of the deposited carbonaceous materials into inert coke which permanently deactivate the catalyst.

Quarterly environmental data summary for third quarter 1999

Energy Technology Data Exchange (ETDEWEB)

McCracken, Stephen H. [Weldon Spring Site, St. Charles, MO (United States)

1999-11-05

A copy of the quarterly Environmental Data Summary (QEDS) for the third quarter of 1999 is enclosed. The data, except for air monitoring data and site KPA generated data (uranium analyses), were received from the contract laboratories, verified by the WSSRAP verification group and merged into the data base during the third quarter of 1999. Selected KPA results for on-site total uranium analyses performed during the quarter are also included. Air monitoring data presented are the most recent complete sets of quarterly data.

Moderate temperature gas purification system: application to high calorific coal derived fuel

Energy Technology Data Exchange (ETDEWEB)

M. Kobayashi; H. Shirai; M. Nunokawa [Central Research Institute of Electric Power Industry (CRIEPI), Kanagawa (Japan)

2005-07-01

Simultaneous removal of dust, alkaline and alkaline-earth metals, halides and sulfur compounds is required to enlarge application of coal-derived gas to the high temperature fuel cells and the fuel synthesis through chemical processing. Because high calorific fuel gas, such as oxygen-blown coal gas, has high carbon monoxide content, high temperature gas purification system is always subjected to the carbon deposition and slippage of contaminant of high vapor pressure. It was suggested that moderate temperature operation of the gas purification system is applied to avoid the harmful disproportionation reaction and efficient removal of the various contaminants. To establish the moderate temperature gas purification system, the chemical-removal processes where the reaction rate is predominant to the performance of contaminant removal should be evaluated. Performance of the removal processes for halides and sulfur compounds were experimentally evaluated. The halide removal process with sodium based sorbent had potential good performance at around 300{sup o}C. The sulfur removal process was also applicable to the temperature range, although the improvement of the sulfidation reaction rate is considered to be essential. 11 refs., 8 figs., 1 tab.

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2006-05-17

This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

quarters

Directory of Open Access Journals (Sweden)

Elena Grigoryeva

2016-10-01

Full Text Available Are there many words combining both space and time? A quarter is one of such rare words: it means both a part of the city space and a period of the year. A regular city has parts bordered by four streets. For example, Chita is a city with an absolutely orthogonal historical center. This Utopian city was designed by Decembrists in the depth of Siberian ore-mines (120. The 130 Quarter in Irkutsk is irregular from its inception because of its triangular form. Located between two roads, the forked quarter was initially bordered by flows along the west-east axis – the main direction of the country. That is why it appreciated the gift for the 350 anniversary of its transit existence – a promenade for an unhurried flow of pedestrians. The quarter manages this flow quite well, while overcoming the difficulties of new existence and gathering myths (102. Arousing many expectations, the “Irkutsk’s Quarters” project continues the theme that was begun by the 130 Quarter and involved regeneration, revival and search for Genius Loci and the key to each single quarter (74. Beaded on the trading axis, these shabby and unfriendly quarters full of rubbish should be transformed for the good of inhabitants, guests and the small business. The triptych by Lidin, Rappaport and Nevlyutov is about happiness of urbanship and cities for people, too (58. The City Community Forum was also devoted to the urban theme (114. Going through the last quarter of the year, we hope that Irkutsk will keep to the right policy, so that in the near future the wooden downtown quarters will become its pride, and the design, construction and investment complexes will join in desire to increase the number of comfortable and lively quarters in our city. The Baikal Beam will get one more landmark: the Smart School (22 for Irkutsk’s children, including orphans, will be built in several years on the bank of Chertugeevsky Bay.

Innovative Clean Coal Technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, third and fourth quarters 1994

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-11-01

The objective of this project is to demonstrate and evaluate commercially available selective catalytic reduction (SCR) catalysts from U.S., Japanese, and European catalyst suppliers on a high-sulfur U.S. Coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and European gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; performance of a wide variety of SCR catalyst compositions, geometries, and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small- scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The demonstration is being performed at Gulf Power Company`s Plant Crist Unit No. 5 (75 MW capacity) near Pensacola, Florida. The project is funded by the U.S. Department of Energy (DOE), Southern Company Services, Inc. (SCS on behalf of the entire Southern electric system), the Electric Power Research Institute (EPRI), and Ontario Hydro. SCS is the participant responsible for managing al aspects of this project. 1 ref., 69 figs., 45 tabs.

Production of High-Hydrogen Content Coal-Derived Liquids [Part 2 of 3

Energy Technology Data Exchange (ETDEWEB)

Stephen Bergin

2011-03-30

The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal

Production of High-Hydrogen Content Coal-Derived Liquids [Part 3 of 3

Energy Technology Data Exchange (ETDEWEB)

Stephen Bergin

2011-03-30

The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal

Production of High-Hydrogen Content Coal-Derived Liquids [Part 1 of 3

Energy Technology Data Exchange (ETDEWEB)

Stephen Bergin

2011-03-30

The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal

Biomass Cofiring in Coal-Fired Boilers

Energy Technology Data Exchange (ETDEWEB)

2004-06-01

Cofiring biomass-for example, forestry residues such as wood chips-with coal in existing boilers is one of the easiest biomass technologies to implement in a federal facility. The current practice is to substitute biomass for up to 20% of the coal in the boiler. Cofiring has many benefits: it helps to reduce fuel costs as well as the use of landfills, and it curbs emissions of sulfur oxide, nitrogen oxide, and the greenhouse gases associated with burning fossil fuels. This Federal Technology Alert was prepared by the Department of Energy's Federal Energy Management Program to give federal facility managers the information they need to decide whether they should pursue biomass cofiring at their facilities.

Permeability changes in coal resulting from gas desorption

Energy Technology Data Exchange (ETDEWEB)

Levine, J.R.; Johnson, P.W.

1992-11-30

This report documents studies on the effects of gas sorption on coal, with the intent of eventually evaluating how sorption and strain affect permeability. These studies were, carried out at the University of Alabama during the period from 1989 through 1992. Two major experimental methods were developed and used. In the strain experiments, electronic strain gauges were attached to polished blocks of coal in order to measure linear and volumetric swelling due to gas sorption. The effects of bedding plane orientation, of gas type, and of coal type were investigated. In the gravimetric experiment the weight of small samples of coal was measured during exposure to high pressure gases. Sample measurements were corrected for buoyancy effects and for sample swelling, and the results were plotted in the form of Langmuir isotherms. Experiments were conducted to determine the effect of grain size, coal type, moisture, and of sorbant gas. The advantage of this method is that it can be applied to very small samples, and it enabled comparison liptinite versus vitrinite concentrates, and kerogen rich versus kerogen depleted oil shales. Also included is a detailed discussion of the makeup of coal and its effect on gas sorption behavior.

High-volume, high-value usage of Flue Gas Desulfurization (FGD) by-products in underground mines Phase 1: Laboratory investigations. Quarterly report, July 1994--September 1994

Energy Technology Data Exchange (ETDEWEB)

NONE

1994-12-01

During the quarter a second series of samples were collected and partially characterized chemically and mineralogically. The samples were collected at the disposal site operated by Freeman United Coal Co. The second collection was necessary because of deterioration due to hydration of the original samples. A study of the hydration characteristics was completed during the quarter. Important reactions included the immediate formation of ettringite and portlandite. The hydration and transformation was found to be a slow process. A second phase of gypsum formation from ettringite deterioration was identified. The slow hydration of anhydrite with its resultant swell is a potential problem which will be addressed further. Geotechnical characterization, during the quarter included completion of the preliminary characterization, analysis of the findings, experimentation with sample preparation for the final characterization/mix design, and design of the final experimental program. The analysis of the coals collected during the core drilling and hydrologic planning were completed. Also during the quarter a meeting was held with representatives of the shotcrete industry to discuss transport systems for emplacement. The pros and cons of pneumatic and hydraulic systems were discussed and plans formulated for further investigations.

NOx Control Options and Integration for US Coal Fired Boilers

Energy Technology Data Exchange (ETDEWEB)

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-06-30

This is the sixteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. During an unplanned outage, damage occurred to the electrochemical noise corrosion probes installed at the AEP Gavin plant; testing is expected to resume in August. The KEMCOP corrosion coupons were not affected by the unplanned outage; the coupons were removed and sent for analysis. BYU conducted a series of tests before the ISSR lab was relocated. Ammonia adsorption experiments provided clear evidence of the types of acidic sites present on catalyst surfaces. Data collected this quarter indicate that surface sulfation decreases Lewis acid site concentrations for all catalysts thus far studied, confirming that catalytic activity under commercial coal-based SCR conditions occurs primarily on Br{o}nsted acid sites and would be susceptible to basic impurities such as alkali and alkaline earth oxides, chlorides, and sulfates. SCR activity tests based on MS analysis showed that increasing sulfation generally increases NO reduction activity for both 0% and 1% vanadia catalysts. During this quarter, the slipstream reactor at Rockport operated for 720 hours on flue gas. Catalyst exposure time reached 4500 hours since installation. The reactor is out of service at the Rockport plant and plans are being made to move it to the Gadsden Plant. At Gadsden, modifications have begun in preparation for installation of the slipstream reactor next quarter.

The Bulgarian coal and the fluid bed technology

International Nuclear Information System (INIS)

Konstantinov, M.; Georgiev, J.; Lebedov, K.; Petrov, N.

2000-01-01

Because of low-quality of the most of Bulgarian coal and more rigorous ecological restrictions for decreasing of greenhouse gases the fluidized bed technology is the most appropriate combustion technology. A study with a pilot plant aiming to establish the values of technological parameters in view to maintain stable process of fluidized bed combustion at the specific burning characteristics of the Bulgarian coal was carried out. Coal of different quality and particle size production of 'Marbas' LTD mines were used. Series of experiments with batches of strictly determined content were carried out at minimal, average and maximal load. The technological factors as: layer's aerodynamics, layer's height, fuel's quantity and quantity of inert material were changed at each batch. The ecological factors were optimized considering coal's quality, plant's parameters, limestone's dosing and layer's aerodynamics. A regressive model for optimization of technological and ecological factors was created. An average coefficient of performance was achieved, resp. 82.27 % at combustion of coal from mines 'Maritsa-West' and 90 % from mine 'Lev'. A coefficient of sulfur oxides' capture 70 % was obtained at coal with sulfur content 3.1-3.9 %. In conclusion the fluidized bed technology is very suitable for combustion's characteristics of the Bulgarian coal

Process for the gas extraction of coal

Energy Technology Data Exchange (ETDEWEB)

Urquhart, D B

1976-05-20

The object of the invention is a process for the hydroextraction of coal is treated with water and carbon monoxide at a temperature in the region of 300 - 380/sup 0/C. After treatment is completed, the gases are separated from the treated gas; the treated coal is then extracted with an extraction medium during the gas phase at a temperature of at least 400/sup 0/C, the remainder is separated from the gas phase and the coal extract is obtained from the extraction medium. Hydrogenation is preferably carried out at a temperature in the region of 320 - 370/sup 0/C and at a pressure of 200 - 400 at. The time required for treatment with carbon monoxide and water is 1/4 - 2 hours, and in special cases 3/4 - 1 1/2 hours. The coal material itself is nutty slack, of which more than 95% of the coal particles pass through a 1.5 mm mesh sieve. After the hydrogenation the extraction is carried out at a temperature in the region of 400 - 450/sup 0/C. The patent claims relate to the types of extraction media used.

Solid fuels. Coal. Economy and resources

International Nuclear Information System (INIS)

Bautin, F.; Martin-Amouroux, J.M.

2007-01-01

The share of coal in the world energy mix (25%) and its possible increase during the next decades is due to its specific use in steelmaking industry and to its excellent competitiveness in fossil-fuel power plants with respect to other energy sources. Its inferior energy efficiency is compensated by lower and more stable prices on international markets. This situation is explained by a strong competition and abundant reserves. However, coal is a strong emitter of greenhouse gases and would be temporarily penalized by the implementation of emission tax or trading systems before the development of carbon sequestration systems. This article presents: the main world markets (consumption per sector of activity, power generation market, coke market, start-up of a synthetic fuels market), the main international coal producers and traders (overview and typology, international trades, transport), the reserves and resources, and the worldwide perspectives (2050 scenarios, climatic risks, CO 2 prices and technological changes). (J.S.)

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption

Science.gov (United States)

Ghate, M.R.; Yang, R.T.

1985-10-03

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high purity hydrogen from gaseous products of coal gasification and as an acid gas scrubber. 2 figs., 2 tabs.

Automated mineralogical logging of coal and coal measure core

Energy Technology Data Exchange (ETDEWEB)

Stephen Fraser; Joan Esterle; Colin Ward; Ruth Henwood; Peter Mason; Jon Huntington; Phil Connor; Reneta Sliwa; Dave Coward; Lew Whitbourn [CSIRO Exploration & Mining (Australia)

2006-06-15

A mineralogical core logging system based on spectral reflectance (HyLogger{trademark}) has been used to detect and quantify mineralogies in coal and coal measure sediments. The HyLogger{trademark} system, as tested, operates in the visible-to-shortwave infrared spectral region, where iron oxides, sulphates, hydroxyl-bearing and carbonate minerals have characteristic spectral responses. Specialized software assists with mineral identification and data display. Three Phases of activity were undertaken. In Phase I, carbonates (siderite, ankerite, calcite) and clays (halloysite, dickite) were successfully detected and mapped in coal. Repeat measurements taken from one of the cores after three months demonstrated the reproducibility of the spectral approach, with some spectral differences being attributed to variations in moisture content and oxidation. Also, investigated was HyLogger{trademark} ability to create a 'brightness-profile' on coal materials, and these results were encouraging. In Phase II, geotechnically significant smectitic clays (montmorillonite) were detected and mapped in cores of clastic roof and floor materials. Such knowledge would be useful for mine planning and design purposes. In Phase III, our attempts at determining whether phosphorus-bearing minerals such as apatite could be spectrally detected were less than conclusive. A spectral index could only be created for apatite, and the relationships between the spectrally-derived apatite-index, the XRD results and the analytically-derived phosphorus measurements were ambiguous.

Unconventional Coal in Wyoming: IGCC and Gasification of Direct Coal Liquefaction Residue

Science.gov (United States)

Schaffers, William Clemens

Two unconventional uses for Wyoming Powder River Basin coal were investigated in this study. The first was the use of coal fired integrated gasification combined cycle (IGCC) plants to generate electricity. Twenty-eight different scenarios were modeled using AspenPlusRTM software. These included slurry, mechanical and dried fed gasifiers; Wyodak and Green River coals, 0%, 70%, and 90% CO2 capture; and conventional evaporative vs air cooling. All of the models were constructed on a feed basis of 6,900 tons of coal per day on an "as received basis". The AspenPlus RTM results were then used to create economic models using Microsoft RTM Excel for each configuration. These models assumed a 3 year construction period and a 30 year plant life. Results for capital and operating costs, yearly income, and internal rates of return (IRR) were compared. In addition, the scenarios were evaluated to compare electricity sales prices required to obtain a 12% IRR and to determine the effects of a carbon emissions tax on the sales price. The second part of the study investigated the gasification potential of residue remaining from solvent extraction or liquefaction of Powder River Basin Coal. Coal samples from the Decker mine on the Wyoming-Montana border were extracted with tetralin at a temperature of 360°C and pressure of 250 psi. Residue from the extraction was gasified with CO2 or steam at 833°C, 900°C and 975°C at pressures of 0.1 and 0.4 MPa. Product gases were analyzed with a mass spectrometer. Results were used to determine activation energies, reaction order, reaction rates and diffusion effects. Surface area and electron microscopic analyses were also performed on char produced from the solvent extraction residue.

Some features of thermobaric investigations of Donbass coals

Energy Technology Data Exchange (ETDEWEB)

Babenko, V.P.; Kosinskii, V.A.; Kosourov, V.I.; Prokopov, N.S.

1979-01-01

The entire metamorphic series in the Donets coalfield was investigated. Since the coals fail to combust throughout the tests, it is possible to examine the sample microscopically after heat treatment, a fact which may be of interest when examining coking charges. An instrument has been designed for qualitative analysis of gases using a coupled chromatograph.

A novel concept for high conversion of coal to liquids. Final report, 1 September 1988--31 August 1992

Energy Technology Data Exchange (ETDEWEB)

Wiser, W.H.; Shabtai, J.

1994-04-01

A batch microreactor was designed and fabricated as a means of investigating maximum yields of liquids obtainable in very short reaction times of the order of a few seconds, and the maximum ratios of liquids/hydrocarbon (HC) gases obtainable under those conditions. A Wyodak sub-bituminous coal, crushed and sieved to {minus}200 mesh particle size, was used in the experiments, with a temperature of 500{degrees}C and a pressure of 1500 psi. The fine coal particles were fed dry to the reactor and heated to reaction temperature in times of one to two seconds. At a time of 3 seconds at reaction temperature, in a single pass a liquid yield of 60% by weight of the coal was obtained, accompanied by a ratio of liquids/(HC) gases of 30/1. When the unreacted solids were recycled to the reactor, and the results combined with those of the first pass, a liquid yield of 82% by weight of the coal was achieved, accompanied by a ratio of liquids/HC gases of 30/1. This ratio represents only about 3 wt percent HC gases, much lower that is produced in current advanced technologies, and represents a large saving in hydrogen consumption. A simulated distillation technique was applied to the liquids. The liquid product contained 86% by weight (of the liquids) total distillables (boiling point below 538{degrees}C), including 70% by weight of low-boiling fractions in the gasoline, kerosene and gas oil range (boiling point up to 325{degrees}C). The liquid product exhibited a H/C ratio of 1.5, which is considerably higher than observed in current advanced technologies for the primary liquids. Several catalysts were investigated. Iron catalysts, specifically ferric chloride hexahydrate and ferric sulfate pentahydrate, each produced these high conversions and high ratios of liquids/HC gases.

Coal surface structure and thermodynamics. Final report

Energy Technology Data Exchange (ETDEWEB)

Larsen, J.W.; Wernett, P.C.; Glass, A.S.; Quay, D.; Roberts, J.

1994-05-01

Coals surfaces were studied using static surface adsorption measurements, low angle x-ray scattering (LAXS), inverse gas chromatography (IGC) and a new {sup 13}C NMR relaxation technique. A comparison of surface areas determined by hydrocarbon gas adsorption and LAXS led to the twin conclusions that the hydrocarbons had to diffuse through the solid to reach isolated pores and that the coal pores do not form interconnected networks, but are largely isolated. This conclusion was confirmed when IGC data for small hydrocarbons showed no discontinuities in their size dependence as usually observed with porous solids. IGC is capable of providing adsorption thermodynamics of gases on coal surfaces. The interactions of non-polar molecules and coal surfaces are directly proportioned to the gas molecular polarizability. For bases, the adsorption enthalpy is equal to the polarizability interaction plus the heat of hydrogen bond formation with phenol. Amphoteric molecules have more complex interactions. Mineral matter can have highly specific effects on surface interactions, but with most of the molecules studied is not an important factor.

Biomass-derived carbon composites for enrichment of dilute methane from underground coal mines.

Science.gov (United States)

Bae, Jun-Seok; Jin, Yonggang; Huynh, Chi; Su, Shi

2018-07-01

Ventilation air methane (VAM), which is the main source of greenhouse gas emissions from coal mines, has been a great challenge to deal with due to its huge flow rates and dilute methane levels (typically 0.3-1.0 vol%) with almost 100% humidity. As part of our continuous endeavor to further improve the methane adsorption capacity of carbon composites, this paper presents new carbon composites derived from macadamia nut shells (MNSs) and incorporated with carbon nanotubes (CNTs). These new carbon composites were fabricated in a honeycomb monolithic structure to tolerate dusty environment and to minimize pressure drop. This paper demonstrates the importance of biomass particle size distributions when formed in a composite and methane adsorption capacities at low pressures relevant to VAM levels. The selectivity of methane over nitrogen was about 10.4 at each relevant partial pressure, which was much greater than that (6.5) obtained conventionally (at very low pressures), suggesting that capturing methane in the presence of pre-adsorbed nitrogen would be a practical option. The equilibrium and dynamic performance of biomass-derived carbon composites were enhanced by 30 and 84%, respectively, compared to those of our previous carbon fiber composites. In addition, the presence of moisture in ventilation air resulted in a negligible effect on the dynamic VAM capture performance of the carbon composites, suggesting that our carbon composites have a great potential for site applications at coal mines because the cost and performance of solid adsorbents are critical factors to consider. Copyright © 2018 Elsevier Ltd. All rights reserved.

Co-pyrolysis of coal with hydrogen-rich gases. 1. Coal pyrolysis under coke-oven gas and synthesis gas

Energy Technology Data Exchange (ETDEWEB)

Liao, H.; Li, B.; Zhang, B. [Chinese Academy of Sciences, Taiyuan (China). State Key Lab. of Coal Conversion

1998-06-01

To improve the economics of the hydropyrolysis process, it has been suggested that cheaper hydrogen-rich gases (such as coke oven gas, synthesis gas) could be used instead of pure hydrogen. Pyrolysis of Chinese Xianfeng lignite was carried out with coke oven gas (COG) and synthesis gas (SG) as reactive gases at 0.1-5 MPa and at a final temperature up to 650{degree}C with a heating rate of 5-25{degree}C min{sup -1} in a 10 g fixed-bed reactor. The results indicate that it is possible to use COG and SG instead of pure hydrogen in hydropyrolysis, but that the experimental conditions must be adjusted to optimize the yields of the valuable chemicals. 14 refs., 3 figs., 6 tabs.

Development of coal partial hydropyrolysis process

Energy Technology Data Exchange (ETDEWEB)

Hideaki Yabe; Takafumi Kawamura; Kohichiroh Gotoh; Akemitsu Akimoto [Nippon Steel Corporation, Chiba (Japan)

2005-07-01

Coal partial hydropyrolysis process aims at co-production of high yield of light oil such as BTX and naphthalene and synthesis gas from a low rank coal under a mild hydropyrolysis condition. The characteristic of this process is in the two-staged entrained hydropyrolysis reactor composed of the reformer and gasifier. This reactor arrangement gives us high heat efficiency of this process. So far, in order to evaluate the process concept a small-scale basic experiment and a 1t/day process development unit study were carried out. The experimental results showed that coal volatiles were partially hydrogenated to increase the light oil and hydrocarbon gases at the condition of partial hydropyrolysis such as pressure of 2-3MPa, temperature of 700-900{sup o}C and hydrogen concentration of 30-50%. This process has a possibility of producing efficiently and economically liquid and gas products as chemicals and fuel for power generation. As a further development in the period of 2003 to 2008, a 20t/day pilot plant study named ECOPRO (efficient co-production with coal flash hydropyrolysis technology) has been started to establish the process technologies for commercialization. 12 refs., 6 figs., 3 tabs.

Effect of H/C ratio on coal ignition

Energy Technology Data Exchange (ETDEWEB)

Furimsky, E.

1988-09-01

The Cahn balance technique was found to be suitable for estimating ignition temperature and its dependence on the H/C ratio of the coal. This temperature decreased with increasing H/C ratio of coals. For coals a linear correlation between H/C ratio and the temperature was established. Chars derived from the coals deviated from the linear correlation established on coals. 17 refs., 4 figs.

Geological and geochemical characteristics of the secondary biogenic gas in coalbed gases, Huainan coalfield

Energy Technology Data Exchange (ETDEWEB)

Xiaojun, Zhang; Zhenglin, Cao; Mingxin, Tao; Wanchun, Wang; Jinlong, Ma

2010-09-15

The research results show that the compositions of coalbed gases in Huainan coalfield have high content methane, low content heavy hydrocarbons and carbon dioxide, and special dry gas. The evolution coal is at the stage of generation of thermogenic gases, but the d13C1 values within the range of biogenic gas (d13C1 values from -56.7{per_thousand} to -67.9{per_thousand}). The d13C2 value of coalbed gases in Huainan coalfield shows not only the features of the thermogenic ethane, but also the mixed features of the biogenic methane and thermogenic ethane. In geological characteristics, Huainan coalfield has favorable conditions of generation of secondary biogenic gas.

Fuels. Deliveries and consumption of fuels during 4th quarter 2002 and year 2002

International Nuclear Information System (INIS)

2003-01-01

The total volume of oil product deliveries (excluded lubricants, bitumen etc.) from the oil companies was 1 per cent lower during 2002 compared with 2001. The deliveries of motor gasoline and diesel oil increased by 2 and 5 per cent. Domestic heating oil and heavy fuel oils decreased by 3 and 5 per cent compared with 2001. Under the 4th quarter 2002 the deliveries of oil products (excluded lubricants, bitumen etc.) was 10 per cent higher compared with the same quarter 2001. The deliveries of domestic heating oil and heavy fuel oils increased by 22 per cent in each case. Motor gasoline was unchanged while the deliveries of diesel oil increased by 7 per cent. The consumption of fuels in mining and manufacturing increased by 3 % during the year 2002. The consumption of hard coal and coke increased by 5 % and the rest of the fossil fuels by 7 %. Renewable fuels decreased by 1 %. During the 4th quarter 2002 increased the fuel consumption in industry by 2 % compared with same quarter 2001. Renewable fuels decreased by 7 % while fossil fuels increased by 18 %. The consumption of fuels in electricity, gas and district heating services increased by 12 % during 2002. The consumption of oils increased by 16 %. During year 2002 the renewable fuels accounts for 68 % of the final consumption. During the 4th quarter the consumption of fuels was almost twice as high as the consumption during the 4th quarter 2001

Destructive distillation of coals

Energy Technology Data Exchange (ETDEWEB)

Rollason, A

1918-08-23

To obtain light oils and ammonia from coals having volatile and oxygen contents, the crushed material is mixed with 5 percent of ground amorphous calcium carbonate and distilled slowly in a cast iron retort to remove the water and light oils, the ammonia being synthesized at a later stage. The crushed residue is gasified in a producer by a blast of air and superheated steam at about 950/sup 0/C. The steam and air are passed very slowly at low pressure through the fuel to cause the dissociation of the atmospheric nitrogen molecules into atoms. The gases are then passed to a heater, having a temperature of 500/sup 0/C, and thence to a continuously working externally-heated retort charged with fuel, such as the hard retort residues, maintained below 850/sup 0/C. The water vapor in the gases is dissociated by the incandescent fuel, the oxygen combining with the carbon, and the lime present in the fuel causes the hydrogen to combine with the free nitrogen atoms, thus forming ammonia. The gases after leaving the retort are cooled down to 85 to 95/sup 0/C and the ammonia may be recovered by conversion into ammonium sulphate. The resultant cooled gases may again be charged with superheated steam and utilized again in the heater and retort.

Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base

International Nuclear Information System (INIS)

Croft, Gregory D.; Patzek, Tad W.

2009-01-01

By applying the multi-Hubbert curve analysis to coal production in the United States, we demonstrate that anthracite production can be modeled with a single Hubbert curve that extends to the practical end of commercial production of this highest-rank coal. The production of bituminous coal from existing mines is about 80% complete and can be carried out at the current rate for the next 20 years. The production of subbituminous coal from existing mines can be carried out at the current rate for 40-45 years. Significant new investment to extend the existing mines and build new ones would have to commence in 2009 to sustain the current rate of coal production, 1 billion tons per year, in 2029. In view of the existing data, we conclude that there is no spare coal production capacity of the size required for massive coal conversion to liquid transportation fuels. Our analysis is independent of other factors that will prevent large-scale coal liquefaction projects: the inefficiency of the process and either emissions of greenhouse gases or energy cost of sequestration

Coal Field Fire Fighting - Practiced methods, strategies and tactics

Science.gov (United States)

Wündrich, T.; Korten, A. A.; Barth, U. H.

2009-04-01

Subsurface coal fires destroy millions of tons of coal each year, have an immense impact to the ecological surrounding and threaten further coal reservoirs. Due to enormous dimensions a coal seam fire can develop, high operational expenses are needed. As part of the Sino-German coal fire research initiative "Innovative technologies for exploration, extinction and monitoring of coal fires in Northern China" the research team of University of Wuppertal (BUW) focuses on fire extinction strategies and tactics as well as aspects of environmental and health safety. Besides the choice and the correct application of different extinction techniques further factors are essential for the successful extinction. Appropriate tactics, well trained and protected personnel and the choice of the best fitting extinguishing agents are necessary for the successful extinction of a coal seam fire. The chosen strategy for an extinction campaign is generally determined by urgency and importance. It may depend on national objectives and concepts of coal conservation, on environmental protection (e.g. commitment to green house gases (GHG) reductions), national funding and resources for fire fighting (e.g. personnel, infrastructure, vehicles, water pipelines); and computer-aided models and simulations of coal fire development from self ignition to extinction. In order to devise an optimal fire fighting strategy, "aims of protection" have to be defined in a first step. These may be: - directly affected coal seams; - neighboring seams and coalfields; - GHG emissions into the atmosphere; - Returns on investments (costs of fire fighting compared to value of saved coal). In a further step, it is imperative to decide whether the budget shall define the results, or the results define the budget; i.e. whether there are fixed objectives for the mission that will dictate the overall budget, or whether the limited resources available shall set the scope within which the best possible results shall be

Coal log pipeline research at the University of Missouri. 1st Quarterly report for 1995, January 1, 1995--March 31, 1995

Energy Technology Data Exchange (ETDEWEB)

Liu, H.

1995-08-01

Work continued on the study of coal log pipeline research. Individual projects described include fast compaction of coal logs; effect of cooling on coal log quality; coal log capping; effectiveness of adding fiber to enhance coal log quality; fabrication using hydrophobic binders; cost estimation of different lubricants; automatic control of coal log pipeline system; CLP design; coal log train transport; economics of coal log pipeline; legal aspects; heating, cooling, and drying of logs; vacuum systems to enhance production; design; and effect of piston modification on capping.

Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

Science.gov (United States)

Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

2005-11-08

A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

Several features of the thermobaric study of Donbass coals. [20 to 800/sup 0/C

Energy Technology Data Exchange (ETDEWEB)

Babenko, V.P.; Kosinskii, V.A.; Kosourov, V.I.; Prokopov, N.S.

1979-11-01

Investigations were carried out to supplement existing knowledge in the thermal analysis of coals. The studies were undertaken in the 20-800 C range at a pressure of N. 10/sup -2/ mm Hg. The qualitative composition of the gases was studied using a gas chromatograph. The coal samples studied in the thermobaric research did not burn away which permitted microscopic study of the samples. The research demonstrated the feasibility of using the method for correct mixing of coking batches. Along with determining the rank of coals, the method gives information on the flow of the process of thermal destruction of coals and information on the cokability of coals. (4 refs.) (In Russian)

Importance of hard coal in electricity generation in Poland

Science.gov (United States)

Plewa, Franciszek; Strozik, Grzegorz

2017-11-01

Polish energy sector is facing a number of challenges, in particular as regards the reconstruction of production potential, diversification of energy sources, environmental issues, adequate fuels supplies and other. Mandatory implementation of Europe 2020 strategy in terms of “3x20” targets (20% reduction of greenhouse gases, 20% of energy from renewable sources, and 20% increase of efficiency in energy production) requires fast decision, which have to be coordinated with energetic safety issues, increasing demands for electric energy, and other factors. In Poland almost 80% of power is installed in coal fired power plants and energy from hard coals is relatively less expensive than from other sources, especially renewable. The most of renewable energy sources power plants are unable to generate power in amounts which can be competitive with coal fires power stations and are highly expensive, what leads o high prices of electric energy. Alternatively, new generation of coal fired coal power plants is able to significantly increase efficiency, reduce carbon dioxide emission, and generate less expensive electric power in amounts adequate to the demands of a country.

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2006-09-17

This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO

Ignition behaviour of different rank coals in an entrained flow reactor

Energy Technology Data Exchange (ETDEWEB)

J. Faundez; A. Arenillas; F. Rubiera; X. Garcia; A.L. Gordon; J.J. Pis [Instituto Nacional del Carbon (INCAR), Oviedo (Spain)

2005-12-01

An experimental study to determine the temperature and mechanism of coal ignition was carried out by using an entrained flow reactor (EFR) at relatively high coal feed rates (0.5 g min{sup -1}). Seven coals ranging in rank from subbituminous to semianthracite, were tested and the evolved gases (O{sub 2}, CO, CO{sub 2}, NO) were measured continuously. The ignition temperature was evaluated from the gas evolution profiles, and it was found to be inversely correlated to the reactivity of the coal, as reflected by the increasing values of the ignition temperature in the sequence: subbituminous, high volatile bituminous, low volatile bituminous and semianthracite coals. The mechanism of ignition varied from a heterogeneous mechanism for subbituminous, low volatile bituminous and semianthracite coals, to a homogeneous mechanism for high volatile bituminous coals. A thermogravimetric analyser (TGA) was also used to evaluate coal ignition behaviour. Both methods, TGA and EFR, were in agreement as regards the mechanism of coal ignition. From the SEM micrographs of the coal particles retrieved from the cyclone, it was possible to observe the external appearance of the particles before, during and after ignition. The micrographs confirmed the mechanism deduced from the gas profiles. 23 refs., 5 figs., 1 tab.

Report on the research achievements in the Sunshine Project in fiscal 1992. Studies on improving the efficiency of coal gasification; 1992 nendo sekitan gas ka no kokoritsuka ni kansuru kenkyu seika hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

1993-03-01

This paper describes the achievements in the Sunshine Project in fiscal 1992 in studies on improving the efficiency of coal gasification. Three kinds of coals were gasified under the atmosphere of hydrogen, He or CO2 by using the TPR method. The sulfur removing rate varies depending on coals even under the same reaction atmosphere, and so does the degree of influence of the atmospheric gases depending on coals. Very little effect of the atmospheric gases was found on the sulfur removing rate in Taiheiyo and Wandoan coals. While Tatung coal presents the same removing rate under the atmosphere of He and CO2, it shows 1.8 times greater removing rate under the hydrogen atmosphere. Generation patterns for H{sub 2}S and COS also vary depending on coal types and atmospheric gases. Inorganic sulfur shows the same behavior in the reaction process regardless of coal type and atmosphere, but organic sulfur behaves differently. The sulfur removing rate is determined by how easily the organic sulfur can be removed, which attributes to the difference in kinds and structures of organic sulfur compounds in the coal, together with the gas generation patterns. In order to discuss gasification of char, investigations were performed on effects of coal types and heat treatment temperatures, with regard to the gasification characteristics that can be estimated from the industrial and element analyses. (NEDO)

Two-stage liquefaction of a Spanish subbituminous coal

Energy Technology Data Exchange (ETDEWEB)

Martinez, M.T.; Fernandez, I.; Benito, A.M.; Cebolla, V.; Miranda, J.L.; Oelert, H.H. (Instituto de Carboquimica, Zaragoza (Spain))

1993-05-01

A Spanish subbituminous coal has been processed in two-stage liquefaction in a non-integrated process. The first-stage coal liquefaction has been carried out in a continuous pilot plant in Germany at Clausthal Technical University at 400[degree]C, 20 MPa hydrogen pressure and anthracene oil as solvent. The second-stage coal liquefaction has been performed in continuous operation in a hydroprocessing unit at the Instituto de Carboquimica at 450[degree]C and 10 MPa hydrogen pressure, with two commercial catalysts: Harshaw HT-400E (Co-Mo/Al[sub 2]O[sub 3]) and HT-500E (Ni-Mo/Al[sub 2]O[sub 3]). The total conversion for the first-stage coal liquefaction was 75.41 wt% (coal d.a.f.), being 3.79 wt% gases, 2.58 wt% primary condensate and 69.04 wt% heavy liquids. The heteroatoms removal for the second-stage liquefaction was 97-99 wt% of S, 85-87 wt% of N and 93-100 wt% of O. The hydroprocessed liquids have about 70% of compounds with boiling point below 350[degree]C, and meet the sulphur and nitrogen specifications for refinery feedstocks. Liquids from two-stage coal liquefaction have been distilled, and the naphtha, kerosene and diesel fractions obtained have been characterized. 39 refs., 3 figs., 8 tabs.

Coal -98

International Nuclear Information System (INIS)

Sparre, C.

1998-01-01

Energi, Haesselbyverket, has now invested in equipment for burning pellets instead of coal. In Linkoeping wastes of rubber are mixed with coal. Also Soederenergi AB has rebuilt their three coal boilers and replaced 100 % of the coal by peat and wood fuels. Coal is a reserve fuel. Several co-generation plants like Linkoeping, Norrkoeping, Uppsala and Oerebro use both coal and forest fuels. The use of coal is then concentrated to the electricity production. The average price of steam coal imported in Sweden in 1997 was 370 SEK/ton or 10 per cent higher than in 1996. For the world, the average import price fell to 46 USD/ton. The price fall was concentrated to the 4th quarter. The prices have continued to fall during 1998 as a result of the crisis in Asia. All Swedish plants meet their emission limits of dust, SO 2 and NO x given by county administrations or concession boards. The co-generation plants have all some sort of SO 2 -removal system. Mostly used is the wet-dry method. The biggest co-generation plant, Vaesteraas, has newly invested in a ca talytic NO x -cleaning system type SCR, which is reducing the emission level 80-90 %. Most other plants are using low NO x -burners or injection systems type SNCR, based on ammonium or urea, which are reducing the emissions 50-70 %. A positive effect of the recently introduced NO x -duties is a 60 % reduction compared to some years ago, when the duties were introduced. World hard coal production was about 3 800 tons in 1997, a minor increase compared to 1996. The coal demand in the OECD-countries has increased about 1.7 % yearly during the last ten years. The coal share of the energy supply is about 20% in the OECD-countries and 27% in the whole world. Several sources estimate a continuing growth during the next 20 years in spite of an increasing use of natural gas and nuclear power. The reason is a strong demand for electrical power in the Asian countries and the developing countries. However, greater efforts to minimize the

MHD power station with coal gasification

International Nuclear Information System (INIS)

Brzozowski, W.S.; Dul, J.; Pudlik, W.

1976-01-01

A description is given of the proposed operating method of a MHD-power station including a complete coal gasification into lean gas with a simultaneous partial gas production for the use of outside consumers. A comparison with coal gasification methods actually being used and full capabilities of power stations heated with coal-derived gas shows distinct advantages resulting from applying the method of coal gasification with waste heat from MHD generators working within the boundaries of the thermal-electric power station. (author)

Potential contribution of the Clean Coal Program to reducing global emissions of greenhouse gases

International Nuclear Information System (INIS)

Blasing, T.J.

1992-01-01

Environmental considerations of Clean Coal Program (CCP) initially focused on reducing emissions of sulfur dioxide (SO 2 ) and nitrogen oxides (NO x ) to the atmosphere. However, it has also become apparent that some Clean Coal Technologies (CCTs) may contribute appreciably to reducing emissions of carbon dioxide (CO 2 ), thereby diminishing the rate of any global warming that may result from greenhouse effects. This is particularly true for CCTs involving replacement of a major portion of an existing facility and/or providing the option of using a different fuel form (the repowering CCTs). Because the subject of global-scale climate warming is receiving increased attention, the effect of CCTs on Co 2 emissions has become a topic of increasing interest. The Final Programmatic Environmental Impact Statement for the Clean Coal Technology Demonstration Program projected that with full implementation of those repowering CCTs that would be most effective at reducing CO 2 emissions (Pressurized Fluidized Bed and Coal Gasification Fuel Cell technologies), the national fossil-fuel Co 2 emissions by the year 2010 would be roughly 90% of the emissions that would occur with no implementation of any CCTs by the same date. It is the purpose of this paper to examine the global effect of such a reduction in greenhouse gas emissions, and to compare that effect with effects of other strategies for reducing global greenhouse gas emissions

Analysis of oxy-fuel combustion power cycle utilizing a pressurized coal combustor

OpenAIRE

Gazzino, Marco; Hong, Jongsup; Chaudhry, Gunaranjan; Brisson II, John G; Field, Randall; Ghoniem, Ahmed F

2009-01-01

Growing concerns over greenhouse gas emissions have driven extensive research into new power generation cycles that enable carbon dioxide capture and sequestration. In this regard, oxy-fuel combustion is a promising new technology in which fuels are burned in an environment of oxygen and recycled combustion gases. In this paper, an oxy-fuel combustion power cycle that utilizes a pressurized coal combustor is analyzed. We show that this approach recovers more thermal energy from the flue gases...

Multisensor system for toxic gases detection generated on indoor environments

Science.gov (United States)

Durán, C. M.; Monsalve, P. A. G.; Mosquera, C. J.

2016-11-01

This work describes a wireless multisensory system for different toxic gases detection generated on indoor environments (i.e., Underground coal mines, etc.). The artificial multisensory system proposed in this study was developed through a set of six chemical gas sensors (MQ) of low cost with overlapping sensitivities to detect hazardous gases in the air. A statistical parameter was implemented to the data set and two pattern recognition methods such as Principal Component Analysis (PCA) and Discriminant Function Analysis (DFA) were used for feature selection. The toxic gases categories were classified with a Probabilistic Neural Network (PNN) in order to validate the results previously obtained. The tests were carried out to verify feasibility of the application through a wireless communication model which allowed to monitor and store the information of the sensor signals for the appropriate analysis. The success rate in the measures discrimination was 100%, using an artificial neural network where leave-one-out was used as cross validation method.

Arsenic concentrations in Chinese coals

International Nuclear Information System (INIS)

Wang Mingshi; Zheng Baoshan; Wang Binbin; Li Shehong; Wu Daishe; Hu Jun

2006-01-01

The arsenic concentrations in 297 coal samples were collected from the main coal-mines of 26 provinces in China were determined by molybdenum blue coloration method. These samples were collected from coals that vary widely in coal rank and coal-forming periods from the five main coal-bearing regions in China. Arsenic content in Chinese coals range between 0.24 to 71 mg/kg. The mean of the concentration of Arsenic is 6.4 ± 0.5 mg/kg and the geometric mean is 4.0 ± 8.5 mg/kg. The level of arsenic in China is higher in northeastern and southern provinces, but lower in northwestern provinces. The relationship between arsenic content and coal-forming period, coal rank is studied. It was observed that the arsenic contents decreases with coal rank in the order: Tertiary > Early Jurassic > Late Triassic > Late Jurassic > Middle Jurassic > Late Permian > Early Carboniferous > Middle Carboniferous > Late Carboniferous > Early Permian; It was also noted that the arsenic contents decrease in the order: Subbituminous > Anthracite > Bituminous. However, compared with the geological characteristics of coal forming region, coal rank and coal-forming period have little effect on the concentration of arsenic in Chinese coal. The average arsenic concentration of Chinese coal is lower than that of the whole world. The health problems in China derived from in coal (arsenism) are due largely to poor local life-style practices in cooking and home heating with coal rather than to high arsenic contents in the coal

A process for briquetting coal with the production of briquets with high resistance to crushing

Energy Technology Data Exchange (ETDEWEB)

Ono, M; Ito, S; Nakagava, K

1983-02-08

Finely ground coal is mixed with a binder with a softening point of greater than or equal to 30 degrees and with heavy coal tar products, the mixture is molded with the formation of briquets in a two roller press. The mixing is conducted in heated steam or waste gases from a horizontal, helical mixer. The coal is subsequently irrigated by the melted binder and heavy coal tar products. The heavy coal tar products are a bottom residue formed by condensation of volatile products in a gas stream from coking which contains particles of coal and coke. Briquets with a point compression strength of 50 plus or minus 4 kilograms per sq. cur. and a bulk tensity of 1.17 grams per cubic centimeter are produced from a mixture which contains 6 percent binder, 80 percent coal and 20 percent heavy coal tar products.

Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Technical progress report, October--December 1993

Energy Technology Data Exchange (ETDEWEB)

Schmidt, E.; Kirby, S.; Song, Chunshan; Schobert, H.H.

1994-04-01

Development of new catalysts is a promising approach to more, efficient coal liquefaction. It has been recognized that dispersed catalysts can be superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires infinite contact between the catalyst and coal. The primary objective of this research is to explore the potential of bimetallic dispersed catalysts from heterometallic molecular precursors in their use in model compound liquefaction reactions. This quarterly report describes the use of three precursors in model compound reactions. The first catalyst is a heterometallic complex consisting of two transition metals, Mo and Ni, and sulfur in a single molecule. The second is a thiocubane type complex consisting of cobalt, molybdenum and sulfur. The third is a thiocubane type cluster consisting of iron and sulfur and the fourth, the pure inorganic salt ammonium tetrathiomolybdate (ATM). It was found that the structure and the ligands in the model complexes affect the activity of the resulting catalyst significantly. The optimum reaction at a pressure of 6.9 MPa hydrogen gas varied for different catalysts. The bimetallic catalysts generated in situ from the organometallic precursor are more active than monometallic catalysts like ATTM and the thiocubane type cluster Fe{sub 4}. Main products are hydrogenated phenanthrene derivatives, like DBP, THP, sym-OHP, cis- and trans-unsym-OHP with minor isomerization products such as sym-OHA. Our results indicate that other transition metal and ligand combinations in the organometallic precursors and the use of another model compound could result in substantially higher conversion activity.

Process for carbonizing, distilling, and vaporizing of coal from any source

Energy Technology Data Exchange (ETDEWEB)

Limberg, T

1916-10-15

A process is described for carbonizing, distilling, and vaporizing coal from any source, especially of humid and bituminous coals as well as bituminous shale and peat for recovering an especially light tar with a large aliphatic hydrocarbon content that is characterized in that it is exposed to internal heating under vacuum at a temperature below dull-red heat. The distillation products of the material are washed away by the heating gases for the whole length of the furnace and are removed immediately and carried into separate condensers.

Study on the Low-Temperature Oxidation Law in the Co-Mining Face of Coal and Oil Shale in a Goaf—A Case Study in the Liangjia Coal Mine, China

Directory of Open Access Journals (Sweden)

Gang Wang

2018-01-01

Full Text Available The low-temperature oxidation law of coal and rock mass is the basis to study spontaneous combustion in goafs. In this paper, the low-temperature oxidation laws of coal, oil shale, and mixtures of coal and oil shale were studied by using laboratory programmed heating experiments combined with a field beam tube monitoring system. The results from the programmed heating experiments showed that the heat released from oil shale was less than that from coal. Coal had a lower carbon monoxide (CO-producing temperature than oil shale, and the mixture showed obvious inhibiting effects on CO production with an average CO concentration of about 38% of that for coal. Index gases were selected in different stages to determine the critical turning point temperature for each stage. The field beam tube monitoring system showed that the temperature field of the 1105 co-mining face of coal and oil shale in the goaf of the Liangjia Coal Mine presented a ladder-like distribution, and CO concentration was the highest for coal and lower for the mixture of coal and oil shale, indicating that the mixture of coal with oil shale had an inhibiting effect on CO production, consistent with the results from the programmed heating experiments.

Soot, unburned carbon and ultrafine particle emissions from air- and oxy-coal flames

International Nuclear Information System (INIS)

Morris, W.J.; Yu, Dunxi; Wendt, J.O.L.

2010-01-01

Oxy-coal combustion is one possible solution for the mitigation of greenhouse gases. In this process coal is burned in oxygen, rather than air, and the temperatures in the boiler are mitigated by recycling flue gases, so that the inlet mixture may contain either 27 % O 2 to match adiabatic flame temperatures, or 32 % O 2 to match gaseous radiation heat fluxes in the combustion chamber. However, a major issue for heat transfer from coal combustion is the radiative heat transmission from soot. For this research, air and oxy coal firing were compared regarding the emission of soot. A 100 kW down-fired laboratory combustor was used to determine effects of switching from air to oxy-firing on soot, unburned carbon and ultrafine particle emissions from practical pulverized coal flames. Of interest here were potential chemical effects of substitution of the N 2 in air by CO 2 in practical pulverized coal flames. The oxy-coal configuration investigated used once-through CO 2 , simulating cleaned flue gas recycle with all contaminants and water removed. Three coals were each burned in: a) air, b) 27 % O 2 / 73 % CO 2 , c) 32 % O 2 / 68 % CO 2 . Tests were conducted at (nominally) 3 %, 2 %, 1 % and 0 % O 2 in the exhaust (dry basis). For each condition, particulate samples were iso kinetically withdrawn far from the radiant zone, and analyzed using a photoacoustic analyzer (PA) for black carbon, a scanning mobility particle sizer (SMPS) for ultrafine particles, and a total sample loss on ignition (LOI) method for unburned carbon in ash. Data suggest that at low stoichiometric ratios, ultrafine particles consist primarily of black carbon, which, for the bituminous coal, is produced in lesser amounts under oxy-fired conditions than under the air-fired condition, even when adiabatic flame temperatures are matched. However, significant changes in mineral matter vaporization were not observed unless the flames were hotter. These and other results are interpreted in the light of

Coal in Europe: what future?: prospects of the coal industry and impacts study of the Kyoto Protocol

International Nuclear Information System (INIS)

Rudianto, E.

2006-12-01

From the industrial revolution to the 1960's, coal was massively consumed in Europe and its utilization was constantly raised. In the aftermath of World War II, coal had also an important part in reconstruction of Western Europe's economy. However, since the late 1960's, its demand has been declining. There is a (mis)conception from a number of policy makers that saying coal mining and utilizations in Europe is unnecessary. Therefore in the European Union (EU) Green Paper 2000, coal is described as an 'undesirable' fuel and the production of coal on the basis of economic criteria has no prospect. Furthermore, the commitment to the Kyoto Protocol in reducing greenhouse gases emission has aggravated this view. Faced with this situation, the quest for the future of coal industry (mining and utilization) in the lines of an energy policy is unavoidable. This dissertation did a profound inquiry trying to seek answers for several questions: Does the European Union still need coal? If coal is going to play a part in the EU, where should the EU get the coal from? What should be done to diminish negative environmental impacts of coal mining and utilization? and finally in regard to the CO 2 emission concerns, what will the state of the coal industry in the future in the EU? To enhance the analysis, a system dynamic model, called the Dynamics Coal for Europe (the DCE) was developed. The DCE is an Energy-Economy-Environment model. It synthesizes the perspectives of several disciplines, including geology, technology, economy and environment. It integrates several modules including exploration, production, pricing, demand, import and emission. Finally, the model emphasizes the impact of delays and feed-back in both the physical processes and the information and decision-making processes of the system. The calibration process for the DCE shows that the model reproduces past numbers on the scale well for several variables. Based on the results of this calibration process, it can

Reduction of particulate emission in two coal-fired power plants; Reduccion de la Emisiones de Particulas Solidas en Centrales Termicas de Carbon Existentes Mediante Acondicionamiento Integral (Fisico y Quimico) de Gases de Combustion

Energy Technology Data Exchange (ETDEWEB)

1999-09-01

Escucha and Cercs are two coal-fired power stations, each with a capacity of 160MW, which belong to FECSA. Tehy came into operation in 1970 and 1971. Their boilers are of the once-through type and both have similar configurations, although they use different types of coal. The power station at Cercs uses a mixture of local lignite, rich in calcium, together with 40% of South African coal, while that of Escucha uses local lignite, the ashes of which are predominantly silicon and aluminium oxides, together with 20% of South African coal. At both power stations, the local lignite has changes during the life of the power stations and presently its quality is clearly inferior th that when the power stations were designed. This change in quality has produced two consequences, on one hand, the characteristics of the ash have changed in that the resistivity of the fly ash produced at present is much higher than when the power stations were designed. On the other hand, the temperature of the gases at the boiler outlet has increased and reaches values of up to 200 degree centigree, which has also led to an increase in resistivity. These two facts have produced, as a consequence, a significant increase in the emission of particulate matter. In order to reduce the emission of particulate matter, two stategies were implantes at both power stations; a reduction in the temperature of the flue gases and a reduction of the resistivity of the fly ash. This was an innovative approach to the problem, as generally either one or the other of these strategies is employed but rarely both of them at the same time. A reduction of flue gas temperature was achieved by modifying the last three tube banks of the boiler by adding another 2500 m``2 of heat exchanging surface. As a result, the temperature of the flue gases decreased to a value of 140 degree centigree, which in turn produced a notable effect on the resistivity of the ash. Furthermore, an increase in the performance of the boiler

Clean Coal Technology Demonstration Program: Program update 1993

Energy Technology Data Exchange (ETDEWEB)

1994-03-01

The Clean Coal Technology Demonstration Program (also referred to as the CCT Program) is a $6.9 billion cost-shared industry/government technology development effort. The program is to demonstrate a new generation of advanced coal-based technologies, with the most promising technologies being moved into the domestic and international marketplace. Technology has a vital role in ensuring that coal can continue to serve U.S. energy interests and enhance opportunities for economic growth and employment while meeting the national committment to a clean and healthy global environment. These technologies are being advanced through the CCT Program. The CCT Program supports three substantive national objectives: ensuring a sustainable environment through technology; enhancing energy efficiency and reliability; providing opportunities for economic growth and employment. The technologies being demonstrated under the CCT Program reduce the emissions of sulfur oxides, nitrogen oxides, greenhouse gases, hazardous air pollutants, solid and liquid wastes, and other emissions resulting from coal use or conversion to other fuel forms. These emissions reductions are achieved with efficiencies greater than or equal to currently available technologies.

Fossil-energy program. Quarterly progress report for June 30, 1983

Energy Technology Data Exchange (ETDEWEB)

McNeese, L.E.

1983-08-01

This quarterly report covers the progress made during the period March 31 through June 30 for the Oak Ridge National Laboratory research and development projects that are carried out in support of the increased utilization of coal and other fossil fuels as sources of clean energy. These projects are supported by various parts of DOE including Fossil Energy, Basic Energy Sciences, Office of Health and Environmental Research, Office of Environmental Compliance and Overview, the Electric Power Research Institute, and by the Tennessee Valley Authority and the EPA Office of Research and Development through inter-agency agreement with DOE.

California community water systems quarterly indicators dataset, 1999-2008

Data.gov (United States)

California Environmental Health Tracking Program — This data set contains quarterly measures of arsenic and nitrates in public drinking water supplies. Data are derived from California Office of Drinking Water (ODW)...

Deuterium as a tracer in coal liquefaction. Pt. 1

International Nuclear Information System (INIS)

Wilson, M.A.; Collin, P.J.; Barron, P.F.; Vassallo, A.M.

1982-01-01

Deuterium has been used to trace the pathways by which hydrogen reacts with an Australian bituminous coal (Liddell) in the presence of a nickel/molybdenum catalyst. The results show that at 400 0 C extensive scrambling of hydrogen and deuterium occurs among aromatic and α to aromatic aliphatic hydrogen and deuterium substituents. Deuterium can enter all structural groups in both asphaltene and hexane-soluble fractions of the coal-derived liquids, but it enters aromatic and α to aromatic groups in preference to alkyl groups remote from aromatic rings. Thus the results indicate that hydrogen atoms are very mobile during coal hydrogenation. Deuterium from deuterium oxide generated during conversion can also be incorporated into the coal-derived liquids. During coal hydrogenation, the eventual fate of much of the hydrogen in the gas phase is to substitute for hydrogen already in the coal. (Auth.)

Adsorption of SO2 on bituminous coal char and activated carbon fiber prepared from phenol formaldehyde

Science.gov (United States)

DeBarr, Joseph A.; Lizzio, Anthony A.; Daley, Michael A.

1996-01-01

Carbon-based materials are used commercially to remove SO2 from coal combustion flue gases. Historically, these materials have consisted of granular activated carbons prepared from lignite or bituminous coal. Recent studies have reported that activated carbon fibers (ACFs) may have potential in this application due to their relatively high SO2 adsorption capacity. In this paper, a comparison of SO2 adsorption for both coal-based carbons and ACFs is presented, as well as ideas on carbon properties that may influence SO2 adsorption

Transport processes in ionized gases

International Nuclear Information System (INIS)

Kremer, G.M.

1997-01-01

Based on kinetic theory of gases and on the combined of Chapman-Enskog and Grad, the laws of Ohm, Fourier and Navier-Stokes are derived for a non-relativistic fully ionized gas. Moreover, the combined method is applied to the BGK model of the relativistic Boltzmann equation and the Ohm's law is derived for a relativistic fully ionized gas. (author)

Relativistic quantum thermodynamics of ideal gases in two dimensions.

Science.gov (United States)

Blas, H; Pimentel, B M; Tomazelli, J L

1999-11-01

In this work we study the behavior of relativistic ideal Bose and Fermi gases in two space dimensions. Making use of polylogarithm functions we derive a closed and unified expression for their densities. It is shown that both type of gases are essentially inequivalent, and only in the non-relativistic limit the spinless and equal mass Bose and Fermi gases are equivalent as known in the literature.

Relativistic Quantum Thermodynamics of Ideal Gases in 2 Dimensions

OpenAIRE

Blas, H.; Pimentel, B. M.; Tomazelli, J. L.

1999-01-01

In this work we study the behavior of relativistic ideal Bose and Fermi gases in two space dimensions. Making use of polylogarithm functions we derive a closed and unified expression for their densities. It is shown that both type of gases are essentially inequivalent, and only in the non-relativistic limit the spinless and equal mass Bose and Fermi gases are equivalent as known in the literature.

Indian coal tars. II

Energy Technology Data Exchange (ETDEWEB)

Basu, A N; Bhatnagar, J N; Roy, A K

1954-01-01

Laboratory experiments were carried out on these efforts: (1) rank and specific-gravity fractions on tar yield; (2) addition of water to the coal charge, or steam during carbonization, on yield of tar and tar acids; (3) the presence of a cracking agent (shale) with and without steam addition on the yield of tar and tar acids (the particular shale used without steam reduced the yield, and the restricted use of steam brought the yield to the former noncatalyzed level); and (4) catalytic effect of three different samples of shale, firebrick, quartz, coke, and silica-alumina on the cracking of tar acids (the most active were two of the shales, a freshly-prepared coke, and the Al/sub 2/O/sub 3/-SiO/sub 2/ catalysts that gave conversion up to 98%). The products were mainly carbon, aromatic hydrocarbons of the naphthalene series and gases (CO and H/sub 2/). The yield of the tar becomes less as coal of lower specific gravity is used or when higher temperatures are used for carbonization. The mineral matter associated with Indian coals acts as a decomposition catalyst for tar acids, as shown by experiments on the decomposition of PhOH at temperatures above 800/sup 0/.

Permeability changes in coal resulting from gas desorption. Final report

Energy Technology Data Exchange (ETDEWEB)

Levine, J.R.; Johnson, P.W.

1992-11-30

This report documents studies on the effects of gas sorption on coal, with the intent of eventually evaluating how sorption and strain affect permeability. These studies were, carried out at the University of Alabama during the period from 1989 through 1992. Two major experimental methods were developed and used. In the strain experiments, electronic strain gauges were attached to polished blocks of coal in order to measure linear and volumetric swelling due to gas sorption. The effects of bedding plane orientation, of gas type, and of coal type were investigated. In the gravimetric experiment the weight of small samples of coal was measured during exposure to high pressure gases. Sample measurements were corrected for buoyancy effects and for sample swelling, and the results were plotted in the form of Langmuir isotherms. Experiments were conducted to determine the effect of grain size, coal type, moisture, and of sorbant gas. The advantage of this method is that it can be applied to very small samples, and it enabled comparison liptinite versus vitrinite concentrates, and kerogen rich versus kerogen depleted oil shales. Also included is a detailed discussion of the makeup of coal and its effect on gas sorption behavior.

Feasibility of a continuous surface mining machine using impact breakers. First quarterly report, October 1-December 31, 1979

Energy Technology Data Exchange (ETDEWEB)

Fisk, A. T.

1980-01-01

This is the first quarterly report on the efforts to evaluate the feasibility of excavating coal and overburden from surface mines using impact breakers. The initial stages of the project are devoted to a literature search, equipment selection, test site selection, and conceptual test system design. Hence, this report details the progress made in these areas; the next quarter will see the finalization of Phase I. Included as appendices to this report are FMA internal reports on the individual mines visited. These reports are the basis of the test site selection, and have been censored here to remove data the mine operators deemed as confidential.

Energy supply the 4th quarter and the whole years 2000 and 2001, corrected version. Preliminary data

International Nuclear Information System (INIS)

2002-01-01

The objective of the presented statistics is to give a total picture of the Swedish energy supply and its development. The efficiency of the final consumption is not considered in the balance sheets. The quantities (recalculated to tera joules = 10 12 joules) as reported under final consumption refer only to the total energy delivered to the consumers. The final consumption of energy in Sweden the 4th quarter 2001 increased by 5 per cent compared to the corresponding period 2000. The rise can be explained with the fact that the 4th quarter 2001 was colder compared with the same quarter 2000. The consumption within industrial sector was unchanged although the consumption within transports diminished. During the year 2001 energy consumption was unchanged compared with the year 2000. The consumption in household and service sector rose by 8 per cent. The highest rise can be find in the use of district heating and domestic fuels. The industry sector used 5 per cent less energy and mainly in the use of electric energy and domestic fuels. The gross supply of energy in Sweden the 4th quarter increased by 3,5 per cent compared to the 4th quarter 2000. The production of electricity from nuclear plants was 23 per cent higher compared with the same quarter 2000. Hydro-electric power production decreased by 4 per cent during the same period. The supply of natural gas rose by 24 per cent and the supply of domestic fuels rose by 4 %, the supply of coal and coke increased by 3 per cent and the same increase occurred in the supply of oil products. The gross supply of energy was 3 per cent higher during 2001 compared with 2000. The increase can be seen in the supply of coal and coke, 7 per cent, natural gas, 15 per cent, and production of electric energy in nuclear plants, 26 per cent. The balance sheets give both the total flow of various sources of energy and specifications of conversion and consumption in the energy producing industries. The contents of the balance sheets are

Statement of nuclear incidents at nuclear installations. Third quarter 2001

International Nuclear Information System (INIS)

2002-01-01

A statement of nuclear incidents at nuclear installations in Britain during the third quarter of 2001 is published today by the Health and Safety Executive. It covers the period 1 July to 30 September 2001. The statement is published under arrangements that came into effect from the first quarter of 1993, derived from the Health and Safety Commission's powers under section 11 of the Health and Safety at Work, etc. Act 1974

How to (really) reduce the greenhouse gases releases

International Nuclear Information System (INIS)

Masurel, J.; Frot, J.

2009-01-01

Based on the last 2008 GIEC report, 'Sauvons le Climat' presupposes the character essentially anthropic of the climatic change and concludes to the requirement to divide by four, between now and 2050, the releases of greenhouse gases of the OECD countries. The world energetic balance is composed, for 80% of carbonaceous energies: petroleum, coal and natural gas. At the world-wide level, the preoccupations of the energetic resources and those of climate protection go therefore hand in hand. It is the same thing for the European Union but not for France whose carbonaceous energies part is only of 50%. That is to say, in France, an energy savings has only one chance of two to improve its energetic independence and to protect the climate. Especially for France, 'Sauvons le Climat' gives then here some advices to really reduce the greenhouse gases releases. (O.M.)

Co-gasification of coal and wood to reduce environmental pollution

Energy Technology Data Exchange (ETDEWEB)

Giovanni Pino; Martino Paolucci; Francesco Geri; F. Tunzio; G. Spazzafumo [APAT - National Agency for Environmental Protection and Technical Services, Rome (Italy)

2005-07-01

After presenting the paper 'Co-firing and Co-gasification Wood and Coal' at the First International Conference on Clean Coal Technologies, the authors thought about studying in depth the gasification process of woody biomass and coal. This would lead, once all the technical difficulties related to hybrid feeding were solved, to bear a system which mainly presents two advantages. The first advantage is derived by knowing that woody biomass contains a mass percentage of sulphur which is hundred times smaller as much when compared to coal. The second advantage derives from the fact that, given a capturing and sequestration system for the carbon dioxide, it is feasible to control the biomass/coal ratio at the feeding state. In doing so, emissions of carbon dioxide which are not captured will quantitatively be equal to the ones that would derive from the plain combustion of the biomass. 3 refs., 4 figs.

Trends in coal use - global, EU and Poland

Science.gov (United States)

Suwała, Wojciech; Wyrwa, Artur; Olkuski, Tadeusz

2017-11-01

That aim of this paper is to compare trends in global, European use of coal with tendencies in Poland, one of heavy coal dependent countries. Polish power generation is unique among OECD countries, the share of both hard coal and lignite in power generation reaches 81% [1]. Climate policy of European Union is to phase out intensive greenhouse gases sectors, thus to transform Polish power generation into less carbon intensive. Although such policy is generally accepted in Poland, the paste and practically proposed regulation that excludes coal generation from capacity mechanisms, is considered as threat to energy security. Coal is the base for generation for one simple reason, abundant in European scale hard coal reserves and significant capacities in lignite. Natural gas reserves allow to supply about 1/3 of consumption, but prices and supplies dependent hitherto on contracts with GAZPROM did not allow to develop significant generation capacities. Renewable resources are limited, there is not much possibilities for hydro, wind and solar. Poland is also one of the countries of poor air quality, traditional coal based space heating systems plus obsolete car fleet generate vast emissions, especially during the winter. Only recently this became top priority of environmental authorities. This situation is subject to transformation, government, managers are aware that the role of coal needs to be decreased, but there are two main questions, the paste of transformation and the future energy mix. The paper attempts to answer the question whether the expected changes in Polish energy mix are comparable or differ from the global and European tendencies.

Prediction of the burnout behaviour of chars derived from coal-biomass blends

Energy Technology Data Exchange (ETDEWEB)

Tao Wu; Mei Gong; Edward Lester [University of Nottingham, Nottingham (United Kingdom). School of Chemical, Environmental and Mining Engineering

2007-07-01

Nowadays, biomass has been considered an alternative fuel to coal and is being used in power plants to replace part of coal used. This study is to investigate the potential of burning biomass with coal and its impacts on burnout levels. Daw Mill coal was selected for burnout modelling together with three biomasses, Cereal, PKE and Olive Cake. Chars were prepared (75-106 micron) and characterised using image analysis methods as in input data into the char burnout model (ChB) which was adapted to allow the prediction of char burnout of biomass-coal blends under typical pf combustion conditions. The burnout performance of four blend compositions for each biomass were modelled (5%, 10%, 20% and 30%). In practice, the low heating-value of biomass produces a lower flame temperature which can lead to lower levels of char burn-out. The effect is closely linked with the type of biomass used. 36 refs., 4 figs., 1 tab.

The new deal of coal

International Nuclear Information System (INIS)

Kalaydjian, F.; Cornot-Gandolphe, S.

2008-01-01

While coal appears as an inescapable resource to answer the energy needs of the 21. century, its highly CO 2 emitting combustion represents a major risk with respect to the requirements of the fight against climate change. In the first part of this book, the basic aspects of energy markets are explained and in particular the role that coal is going to play in the world's energy supplies. In the second part, the new coal usages are presented, which, combined with CO 2 capture and sequestration techniques, should allow to conciliate a massive use of coal and the respect of environmental constraints. This book is based on the works presented in February 2008 by the French institute of petroleum (IFP) about the new outlets of coal and the risks for climate change. Content: 1 - coal, energy of the 21. century: abundant and well distributed reserves; growing up world production; exponential world demand; international trade: still limited but in full expansion; 2 - Technologies for a CO 2 -free coal: CO 2 capture and sequestration technologies; towards poly-generation; production of coal-derived liquid fuels; 3 - Appendices: coals formation; coal in China: status and perspectives; coal in the USA: status and perspectives; coal in India: status and perspectives; COACH: an ambitious European project; CBM - E-CBM, status and perspectives. (J.S.)

Characterization of the coal derived humic acids from Mukah, Sarawak as soil conditioner

Directory of Open Access Journals (Sweden)

Fong Sim Siong

2006-01-01

Full Text Available In Malaysia, abundant coal resources were found in Sarawak and Sabah. The utilization of coal resources, to date, is emphasized on the energy productions. The non-energy utilization as soil conditioner is unexplored. Therefore, this study attempted to characterize the coal humic acids extracted from Mukah coal and to evaluate its properties as soil conditioner. The coal humic acids from the regenerated sample were also assessed. The results revealed that different extractants and concentrations influenced the properties of humic acids. The extraction with KOH at 0.5 mol L-1 produced humic acids with low ash content and high acidic functional groups, which are substantial as soil conditioner. However, the yield was low. Regeneration of coal sample with 10% nitric acids improved the yield to an average of 83.45%. The acidic functional groups of nitrohumic acids were improved with the ash content remained at a low level.

Two kinetic derivations of the law of perfect gases into Spanish physics books during the 19th century

International Nuclear Information System (INIS)

Vaquero Martinez, J. M.

1998-01-01

The political events occurred in the last years of the 18th century, the Independence war and the reign of Fernando VII, ruined the Spanish scientific panorama, physics included. During the 19th century, the national scientific production was restricted to textbooks and popularization works. Two kinetic derivations of the law of perfect gases corresponding to a textbook and a book about steam engines from the viewpoint of thermodynamics are presented and discussed. (Author) 16 refs

A characterization and evaluation of coal liquefaction process streams. Quarterly report, January 1--March 31, 1997

Energy Technology Data Exchange (ETDEWEB)

Robbins, G.A.; Brandes, S.D.; Heunisch, G.W.; Winschel, R.A.

1998-08-01

Described in this report are the following activities: CONSOL characterized process stream samples from HTI Run ALC-2, in which Black Thunder Mine coal was liquefied using four combinations of dispersed catalyst precursors. Oil assays were completed on the HTI Run PB-05 product blend. Fractional distillation of the net product oil of HTI Run POC-1 was completed. CONSOL completed an evaluation of the potential for producing alkylphenyl ethers from coal liquefaction phenols. At the request of DOE, various coal liquid samples and relevant characterization data were supplied to the University of West Virginia and the Federal Energy Technology Center. The University of Delaware is conducting resid reactivity tests and is completing the resid reaction computer model. The University of Delaware was instructed on the form in which the computer model is to be delivered to CONSOL.

Pilot plant experience in electron-beam treatment of iron-ore sintering flue gas and its application to coal boiler flue gas cleanup

International Nuclear Information System (INIS)

Kawamura, K.

1984-01-01

The present development status of the electron-beam flue gas treatment process, which is a dry process capable of removing SOx and NOx simultaneously, is described. The most advanced demonstration of this process was accomplished with a pilot plant in Japan where the maximum gas flow rate of 10,000 Nm 3 /h of an iron-ore sintering machine flue gas was successfully treated. The byproduct produced in this process is collected as a dry powder which is a mixture of ammonia sulfate and ammonium nitrate and is saleable as a fertilizer or a fertilizer component. A preliminary economic projection showed that this process costs less than the lime scrubber which removes SOx but does not remove NOx. Tests using simulated coal combustion gases suggest that this process will be applicable to coal-fired boiler flue gas treatment as well. However, tests on actual coal-fired flue gases are still required for commercial application decisions. A process development unit program consisting of the design, construction and testing of actual coal-fired power station flue gases is underway in the U.S.A. The design and engineering of the test plant is far advanced and the construction phase will be launched in the very near future. (author)

Measurement of biocarbon in flue gases using 14C

Energy Technology Data Exchange (ETDEWEB)

Haemaelaeinen, K.M.; Jungner, H.; Antson, O.; Rasanen, J.; Tormonen, K.; Roine, J. [University of Helsinki, Helsinki (Finland). Radiocarbon Dating Laboratory

2007-07-01

A preliminary investigation of the biocarbon fraction in carbon dioxide emissions of power plants using both fossil- and biobased fuels is presented. Calculation of the biocarbon fraction is based on radiocarbon content measured in power plant flue gases. Samples were collected directly from the chimneys into plastic sampling bags. The C-14 content in CO{sub 2} was measured by accelerator mass spectrometry (AMS). Flue gases from power plants that use natural gas, coal, wood chips, bark, plywood residue, sludge from the pulp factory, peat, and recovered fuel were measured. Among the selected plants, there was one that used only fossil fuel and one that used only biofuel; the other investigated plants burned mixtures of fuels. The results show that C-14 measurement provides the possibility to determine the ratio of bio and fossil fuel burned in power plants.

Flux Jacobian Matrices For Equilibrium Real Gases

Science.gov (United States)

Vinokur, Marcel

1990-01-01

Improved formulation includes generalized Roe average and extension to three dimensions. Flux Jacobian matrices derived for use in numerical solutions of conservation-law differential equations of inviscid flows of ideal gases extended to real gases. Real-gas formulation of these matrices retains simplifying assumptions of thermodynamic and chemical equilibrium, but adds effects of vibrational excitation, dissociation, and ionization of gas molecules via general equation of state.

(Shippingport Atomic Power Station). Quarterly operating report, fourth quarter 1980

Energy Technology Data Exchange (ETDEWEB)

1980-01-01

At the beginning of the fourth quarter of 1980, the Shippingport Atomic Power Station remained shutdown for the normally planned semiannual maintenance and testing program, initiated September 12, 1980. Operational testing began on November 7. Maximum power was achieved November 28 and was maintained throughout the remainder of the quarter except as noted. The LWBR Core has generated 19,046.07 EFPH from start-up through the end of the quarter. During this quarter, approximately 0.000025 curies of Xe 133 activity were released from the station. During the fourth quarter of 1980, 1081 cubic feet of radioactive solid waste was shipped out of state for burial. These shipments contained 0.037 curies of radioactivity.

Evaluation study on rationalization of coal handling in snowy area

Energy Technology Data Exchange (ETDEWEB)

Suesada, Yasuhiko; Yamagata, Keisuke; Kuwahara, Mitsuhiro

1987-09-25

The adhesion of coal to the coal handling facilities in large cool-fired power plants in the snowy area was investigated for siting them in the future. The amount of water derived from melted snow in addition to that from the rain fall were measured and the statistical amounts of rain and snow falls for the past ten years were examined. Then the amount of water derived from melted snow was calculated by regression. The result indicates that the amount of rain fall in summer is larger than that from melted snow. The moisture content of coal in a coal yard reaches the moisture content at which the coal readily adheres to the facilities after snow fall and it penetrates the pile of coal to the bottom with the lapse of time. The penetrating rate of it largely depends upon the particle distribution of coal as well as the ranks of coal. The adhesion of coal to the coal handling facilities is caused mainly by the amount of dust coal and the moisture content of coal. The amount of adhered coal estimated from the shear properties qualitatively agrees with the experimental result using a model of chute. Adding the dusting inhibitor exceeding the normal value increases the amount of of adhesion of coal. (13 figs, 3 tabs)

Catalytic hydrotreatment of coal-derived naphtha using commercial catalysts

Energy Technology Data Exchange (ETDEWEB)

Liaw, S.-J.; Keogh, R.A.; Thomas, G.A.; Davis, B.H. (University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research)

Naphtha samples derived from the liquefaction of a bituminous Illinois No. 6 and a subbituminous Black Thunder coal were hydrotreated using commercial Co-Mo/Al[sub 2]O[sub 3], Ni-Mo/Al[sub 2]O[sub 3], and Ni-W/Al[sub 2]O[sub 3] catalysts. It was easier to remove the N, O and S heteroatoms from Illinois No. 6 naphtha than from the Black Thunder naphtha. Nitrogen and oxygen were more difficult to remove than sulfur in the temperature range 200-400[degree]C. Considerable differences in catalyst activity for the hydrodenitrogenation (HDN), hydrodeoxygenation (HDO), and hydrodesulfurization (HDS) reactions were observed. The Ni-Mo catalyst was found to be the most active catalyst for the HDN and HDO reactions and the least active catalyst for the HDS. The Co-Mo catalyst was the most active catalyst for the sulfur removal. For the Illinois No. 6 naphtha, a first-order reaction applies for the HDN and HDO reactions for all three catalysts. However, for the Black Thunder naphtha, the first-order reaction applies only at the lower space velocities; a large deviation is observed at higher space velocities. 11 refs., 15 figs., 4 tabs.

Pulverized coal firing of aluminum melting furnaces. Quarterly technical progress report, October 1-December 31, 1979

Energy Technology Data Exchange (ETDEWEB)

West, C E

1980-10-01

Heaviest acitivity this quarter has been in the area of system design and specification and purchase of system components. Mechanical design is now complete. The design of electrical power, process control and data acquisition systems has begun. Combustor design meetings with General Electric Space Science Labs have resulted in an increasing awareness that analytical flow field modeling of the cyclonic combustor could not only enhance current understanding of the process but also broaden the future scope of implementation. A proposal to add specific additional modeling tasks was presented to the Department of Energy, and is included herein in Appendix B. Equipment procurement will continue and system construction will begin during the next quarter.

Idaho National Laboratory Quarterly Occurrence Analysis 4th Quarter FY 2016

Energy Technology Data Exchange (ETDEWEB)

Mitchell, Lisbeth Ann [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2016-11-01

This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System, as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of 84 reportable events (29 from the 4th quarter fiscal year 2016 and 55 from the prior three reporting quarters), as well as 39 other issue reports (including events found to be not reportable and Significant Category A and B conditions) identified at INL during the past 12 months (two from this quarter and 37 from the prior three quarters).

Create a Consortium and Develop Premium Carbon Products from Coal

Energy Technology Data Exchange (ETDEWEB)

Frank Rusinko; John Andresen; Jennifer E. Hill; Harold H. Schobert; Bruce G. Miller

2006-01-01

The objective of these projects was to investigate alternative technologies for non-fuel uses of coal. Special emphasis was placed on developing premium carbon products from coal-derived feedstocks. A total of 14 projects, which are the 2003 Research Projects, are reported herein. These projects were categorized into three overall objectives. They are: (1) To explore new applications for the use of anthracite in order to improve its marketability; (2) To effectively minimize environmental damage caused by mercury emissions, CO{sub 2} emissions, and coal impounds; and (3) To continue to increase our understanding of coal properties and establish coal usage in non-fuel industries. Research was completed in laboratories throughout the United States. Most research was performed on a bench-scale level with the intent of scaling up if preliminary tests proved successful. These projects resulted in many potential applications for coal-derived feedstocks. These include: (1) Use of anthracite as a sorbent to capture CO{sub 2} emissions; (2) Use of anthracite-based carbon as a catalyst; (3) Use of processed anthracite in carbon electrodes and carbon black; (4) Use of raw coal refuse for producing activated carbon; (5) Reusable PACs to recycle captured mercury; (6) Use of combustion and gasification chars to capture mercury from coal-fired power plants; (7) Development of a synthetic coal tar enamel; (8) Use of alternative binder pitches in aluminum anodes; (9) Use of Solvent Extracted Carbon Ore (SECO) to fuel a carbon fuel cell; (10) Production of a low cost coal-derived turbostratic carbon powder for structural applications; (11) Production of high-value carbon fibers and foams via the co-processing of a low-cost coal extract pitch with well-dispersed carbon nanotubes; (12) Use of carbon from fly ash as metallurgical carbon; (13) Production of bulk carbon fiber for concrete reinforcement; and (14) Characterizing coal solvent extraction processes. Although some of the

Coal fly ash based carbons for SO2 removal from flue gases.

Science.gov (United States)

Rubio, B; Izquierdo, M T

2010-07-01

Two different coal fly ashes coming from the burning of two coals of different rank have been used as a precursor for the preparation of steam activated carbons. The performance of these activated carbons in the SO(2) removal was evaluated at flue gas conditions (100 degrees C, 1000 ppmv SO(2), 5% O(2), 6% H(2)O). Different techniques were used to determine the physical and chemical characteristics of the samples in order to explain the differences found in their behaviour. A superior SO(2) removal capacity was shown by the activated carbon obtained using the fly ash coming from a sub-bituminous-lignite blend. Experimental results indicated that the presence of higher amount of certain metallic oxides (Ca, Fe) in the carbon-rich fraction of this fly ash probably has promoted a deeper gasification in the activation with steam. A more suitable surface chemistry and textural properties have been obtained in this case which explains the higher efficiency shown by this sample in the SO(2) removal. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

Operational experience of electron beam flue gases treatment pilot installation at the Maritsa East 2 Thermal Power Plant

Energy Technology Data Exchange (ETDEWEB)

Dutskinov, N. [NEK-EAD (Bulgaria)

2011-07-01

The electron beam flue gases treatment process is very versatile and effective technology for simultaneous removal of acidic pollutants i.e. sulfur dioxide (SO{sub 2}) and nitrogen oxide (NO{sub x}) from the flue gas produced in the combustion of fossil fuel. The technology allows decomposition of VOC (volatile organic compound) such as polycyclic aromatic compound (PAC) and persistent organic pollutants (POP). The electron beam flue gases treatment technology for combustion flue gases purification was applied in Maritsa-East 2 Thermal Power Plant. The decision for construction of Electron Beam Pilot Plant at Maritsa-East 2 TPP was taken at the technical meeting in IAEA Vienna, November 1998. The flue gases of 10 000 nm³/h are irradiated by three high energy electron accelerators of 800 keV and 35 kW beam power each. The plant has been operated since November 2003. The removal efficiency 90-99% for SO{sub x} and 85-90% for NO{sub x} was observed. The quality of coals are characterised with high ash content up to 45%, high moisture up to 57%, low calorific value from 1196 kcal/kg up to 1603 kcal/kg and high concentration of sulphur. The Bulgarian lignite coals are unique in their usage as fuel for the thermal power plants in Maritsa East region. (author)

Width design for gobs and isolated coal pillars based on overall burst-instability prevention in coal mines

Directory of Open Access Journals (Sweden)

Junfei Zhang

2016-08-01

Full Text Available An investigation was conducted on the overall burst-instability of isolated coal pillars by means of the possibility index diagnosis method (PIDM. First, the abutment pressure calculation model of the gob in side direction was established to derive the abutment pressure distribution curve of the isolated coal pillar. Second, the overall burst-instability ratio of the isolated coal pillars was defined. Finally, the PIDM was utilized to judge the possibility of overall burst-instability and recoverability of isolated coal pillars. The results show that an overall burst-instability may occur due to a large gob width or a small pillar width. If the width of the isolated coal pillar is not large enough, the shallow coal seam will be damaged at first, and then the high abutment pressure will be transferred to the deep coal seam, which may cause an overall burst-instability accident. This approach can be adopted to design widths of gobs and isolated coal pillars and to evaluate whether an existing isolated coal pillar is recoverable in skip-mining mines.

The Steam Coal Market in 2016: the Supply Shock

International Nuclear Information System (INIS)

Cornot-Gandolphe, Sylvie

2017-03-01

Surprising coal markets: while the world coal demand is diminishing, the steam coal price doubled in 2016. After five years of uninterrupted price decline and a sluggish world demand, this strong price hike might appear as paradoxical. This paper explains the principal reasons for this situation. After five consecutive years of decline, international steam coal prices doubled in 2016. The main reason is not an increase in global coal consumption, which has been declining since 2014, including in 2016, but the tightening of supplies in the narrow international coal market. Policy changes in China have played a key role. To limit production over-capacity and halt the decline in domestic coal prices, the Chinese government has mandated a reduction in the number of working days in Chinese mines from 330 to 276. This decision has led to a fall in domestic production. Faced with rising coal demand in summer 2016, and surging domestic coal prices from end of June, China once again turned to the international market to cover its supply needs. It thus became again the world's largest coal importer, outpacing India. The increase in Chinese imports did not prevent Chinese demand from falling for the third consecutive year. On the supply side, after five years of declining prices, the export capacities of the main coal supplying countries have been reduced by mine closures, corporate bankruptcies and investment reductions in the sector. This led to the scissor effect observed in 2016, characterized by a sudden and unexpected increase in Chinese imports combined with a supply squeeze. Coal prices surged in the third quarter of 2016, before starting to decline. They have stabilized since December 2016, albeit at high levels. The decline could continue after winter 2016-17. The Chinese government intends to control the level of domestic coal prices to limit their impact on electricity prices and inflation. It has, therefore, relaxed its control on coal production, which has had

Center for Coal-Derived Low Energy Materials for Sustainable Construction

Energy Technology Data Exchange (ETDEWEB)

Jewell, Robert; Robl, Tom; Rathbone, Robert

2012-06-30

The overarching goal of this project was to create a sustained center to support the continued development of new products and industries that manufacture construction materials from coal combustion by-products or CCB’s (e.g., cements, grouts, wallboard, masonry block, fillers, roofing materials, etc). Specific objectives includes the development of a research kiln and associated system and the formulation and production of high performance low-energy, low-CO2 emitting calcium sulfoaluminate (CAS) cement that utilize coal combustion byproducts as raw materials.

Quality of Coal in the Deposit Kongora - Tomislavgrad

International Nuclear Information System (INIS)

Zivkovic, S.; Nuic, J.; Krasic, D.

1998-01-01

The document accepted in Kyoto, signed by the republic of Croatia, oblige the signatory countries in view of the Agreement on reducing emissions of noxious gases. These obligations burden the development of the energy sector by high technological requirements which will make energy even more expensive. The basic part of the energy system constitute fossil fuel driven thermal power plants (presently found less hazardous than the nuclear option). The commitment of the republic of Croatia to build up a basic thermal energy system in the years to come has initiated a series of discussions on energy sources, i.e. on the choice of fossil fuels. Possibilities have been studied as regards the import of gas (Siberia, Algeria), coal (Australia, the USA, Colombia, etc.), while at the same time neglecting the resources in immediate vicinity. Major coal deposits in the Dalmatian hinterland (Bosnia and Herzegovina), 70km from the Adriatic coast, deserve the attention of experts and scientists in surveying energy potential, particularly as it is a question of the low caloric value coal with scant sulphur (under 1 percent). So far the experiences are favourable and point to the coal deposit Kongora as a possible energy potential. (author)

(Shippingport Atomic Power Station). Quarterly operating report, third quarter 1980

Energy Technology Data Exchange (ETDEWEB)

Zagorski, J. F.

1980-01-01

At the beginning of the third quarter of 1980, the Shippingport Atomic Power Station was operating with the 1A, 1B, 1C, and 1D reactor coolant loops and the 1AC and 1BD purification loops in service. During the quarter, the Station was operated for Duquesne Light Company System grid including base load and swing load operation. Twelve (12) planned swing load operations were performed on the LWBR Core this quarter to complete the LWBR operating plan of fifty (50) during this operating phase. The Station was shutdown on September 12 for the Fall 1980 Shutdown and remained in this mode through the end of the quarter. The LWBR Core has generated 18,297.98 EFPH from start-up through the end of the quarter. There were no radioactive liquid discharges from the Radioactive Waste Processing System to the river this quarter. The radioactive liquid waste effluent line to the river remained blanked off to prevent inadvertent radioactive liquid waste discharges. During the quarter, approximately 0.001 curies of Xe 133 activity were released from the station. The radioactivity released from Shippingport Station is far too small to have any measurable effect on the general background environmental radioactivity outside the plant.

Coal in India: current status and outlook - Panorama 2008; Le charbon en Inde: etat des lieux et perspectives - Panorama 2008

Energy Technology Data Exchange (ETDEWEB)

NONE

2008-07-01

The world cannot do without coal. This energy source covers more than one-quarter (28.4% in 2006) of all primary energy consumption and is used to generate nearly 40% of all electricity consumed worldwide. All scenarios and forecasts agree that coal consumption will be growing substantially, driven mostly by China and India. According to the IEA reference scenario (World Energy Outlook 2007), these two countries are expected to account for 82% of the increase in global coal demand by 2030. The outlook for India gives cause for concern: despite a strong domestic coal industry, it could eventually become a major importer. If so, what will the economic, industrial and environmental consequences be?.

A Reduced Order Model for the Design of Oxy-Coal Combustion Systems

Directory of Open Access Journals (Sweden)

Steven L. Rowan

2015-01-01

Full Text Available Oxy-coal combustion is one of the more promising technologies currently under development for addressing the issues associated with greenhouse gas emissions from coal-fired power plants. Oxy-coal combustion involves combusting the coal fuel in mixtures of pure oxygen and recycled flue gas (RFG consisting of mainly carbon dioxide (CO2. As a consequence, many researchers and power plant designers have turned to CFD simulations for the study and design of new oxy-coal combustion power plants, as well as refitting existing air-coal combustion facilities to oxy-coal combustion operations. While CFD is a powerful tool that can provide a vast amount of information, the simulations themselves can be quite expensive in terms of computational resources and time investment. As a remedy, a reduced order model (ROM for oxy-coal combustion has been developed to supplement the CFD simulations. With this model, it is possible to quickly estimate the average outlet temperature of combustion flue gases given a known set of mass flow rates of fuel and oxidant entering the power plant boiler as well as determine the required reactor inlet mass flow rates for a desired outlet temperature. Several cases have been examined with this model. The results compare quite favorably to full CFD simulation results.

Low carbon fuel and chemical production from waste gases

Energy Technology Data Exchange (ETDEWEB)

Simpson, S.; Liew, F.M.; Daniell, J.; Koepke, M. [LanzaTech, Ltd., Auckland (New Zealand)

2012-07-01

LanzaTech has developed a gas fermentation platform for the production of alter native transport fuels and commodity chemicals from carbon monoxide, hydrogen and carbon dioxide containing gases. LanzaTech technology uses these gases in place of sugars as the carbon and energy source for fermentation thereby allowing a broad spectrum of resources to be considered as an input for product synthesis. At the core of the Lanzatech process is a proprietary microbe capable of using gases as the only carbon and energy input for product synthesis. To harness this capability for the manufacture of a diverse range of commercially valuable products, the company has developed a robust synthetic biology platform to enable a variety of novel molecules to be synthesised via gas fermentation. LanzaTech initially focused on the fermentation of industrial waste gases for fuel ethanol production. The company has been operating pilot plant that uses direct feeds of steel making off gas for ethanol production for over 24 months. This platform technology has been further successfully demonstrated using a broad range of gas inputs including gasified biomass and reformed natural gas. LanzaTech has developed the fermentation, engineering and control systems necessary to efficiently convert gases to valuable products. A precommercial demonstration scale unit processing steel mill waste gases was commissioned in China during the 2{sup nd} quarter of 2012. Subsequent scale-up of this facility is projected for the 2013 and will represent the first world scale non-food based low carbon ethanol project. More recently LanzaTech has developed proprietary microbial catalysts capable of converting carbon dioxide in the presence of hydrogen directly to value added chemicals, where-in CO{sub 2} is the sole source of carbon for product synthesis. Integrating the LanzaTech technology into a number of industrial facilities, such as steel mills, oil refineries and other industries that emit Carbon bearing

Fast and safe gas detection from underground coal fire by drone fly over.

Science.gov (United States)

Dunnington, Lucila; Nakagawa, Masami

2017-10-01

Underground coal fires start naturally or as a result of human activities. Besides burning away the important non-renewable energy resource and causing financial losses, burning coal seams emit carbon dioxide, carbon monoxide, sulfur oxide and methane, and is a leading cause of smog, acid rain, global warming, and air toxins. In the U.S. alone, the combined cost of coal-fire remediation projects that have been completed, budgeted, or projected by the U.S. Department of the Interior's Office of Surface Mining Remediation and Enforcement (OSM), exceeds $1 billion. It is estimated that these fires generate as much as 3% of the world's annual carbon dioxide emissions and consume as much as 5% of its minable coal. Considering the magnitude of environmental impact and economic loss caused by burning underground coal seams, we have developed a new, safe, reliable surface measurement of coal fire gases to assess the nature of underground coal fires. We use a drone mounted with gas sensors. Drone collected gas concentration data provides a safe alternative for evaluating the rank of a burning coal seam. In this study, a new method of determining coal rank by gas ratios is developed. Coal rank is valuable for defining parameters of a coal seam such as burn temperature, burn rate, and volume of burning seam. Copyright © 2017 Elsevier Ltd. All rights reserved.

NOx Control Options and Integration for US Coal Fired Boilers

Energy Technology Data Exchange (ETDEWEB)

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2003-09-30

This is the thirteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. The corrosion probe task is proceeding: Two plant visits were made to prepare for field testing and shakedown tests for the probes were conducted at the University of Utah''s L1500 furnace. Corrosion probes will be installed at the Gavin Plant site in the next quarter. Laboratory studies of SCR catalyst continued this quarter. FTIR studies of catalyst sulfation and of adsorption of NH3 and NO were continued at BYU. NO activities have been measured for a number of samples of BYU catalyst and insights have been gained from the results. Plans are being detailed to test monolith and plate catalysts exposed in the field. In this quarter, the catalysts in the slipstream reactor at AEP's Rockport plant were exposed to the dusty flue gas for 1695 hours. Thus the cumulative catalyst exposure to flue gas rose from 980 hours last quarter to 2677 hours in this quarter. Loss of catalyst activity was noted between April (when the catalysts were fresh) and August. Further analysis of activity data will be needed.

Rational use of coal from the Kansk-Achinsk basin

Energy Technology Data Exchange (ETDEWEB)

Andreeva, I.A.; Antonova, L.I.; Khapaeva, O.K.

1983-02-01

Brown coal from the Kansk-Achinsk basin will be used as fuel in power plants as well as raw material for production of coke and smokeless fuel. Production of semicoke should amount to 9 Mt/year, 4 Mt of which will be smokeless fuel. A method for coking brown coal from the Kansk-Achinsk basin developed by the MGI Institute is described: semicoke mixed with coal tar used as a binder and polymers (from 2 to 4%), playing the role of a modifier, is carbonized at 850 to 900 C. Briquets produced from brown coal semicoke are characterized by a high carbon content up to 94.7%, emission of volatile matter down to 9.0%, ash content of 8.8% and good mechanical properties. A method for production of coke for removal of sulfurous anhydride from coal power plant emission is described: semicoke is granulated using the heavy fraction of coal tar formed during semicoking, granules are carbonized and activated at a temperature of 900 C. Volume of mesopores and micropores in coke amounts to 0.4 cm/sup 3//g and the specific surface is 28 to 600 m/sup 2//g (with a combustion loss of of 20 to 24 %). This sorbent is also used as carrier for catalysts in metallurgy and for collecting and recovering solvents from industrial gases.

Technological challenges for boosting coal production with environmental sustainability.

Science.gov (United States)

Ghose, Mrinal K

2009-07-01

The global energy requirement has grown at a phenomenon rate and the consumption of primary energy sources has been a very high positive growth. This paper focuses on the consumption of different primary energy sources and it identifies that coal will continue to remain as the prime energy source in foreseeable future. It examines the energy requirement perspective for India and demand of coal as the prime energy source. Economic development and poverty alleviation depend on securing affordable energy sources and Indian coal mining industry offers a bright future for the country's energy security, provided the industry is allowed to develop by supportive government policies and adopts latest technologies for mining. It is an irony that in-spite of having a plentiful reserves, India is not able to jack up coal production to meet its current and future demand. It discusses the strategies to be adopted for growth and meeting the coal demand. But such energy are very much concerned with environmental degradation and must be driven by contemporary managerial acumen addressing environmental and social challenges effectively The paper highlights the emissions of greenhouse gases due to burning of fossil fuels and environmental consequences of global warming and sea-level rise. Technological solutions for environment friendly coal mining and environmental laws for the abatement of environmental degradation are discussed in this paper.

Naturally Occurring Radioactive Materials in Uranium-Rich Coals and Associated Coal Combustion Residues from China.

Science.gov (United States)

Lauer, Nancy; Vengosh, Avner; Dai, Shifeng

2017-11-21

Most coals in China have uranium concentrations up to 3 ppm, yet several coal deposits are known to be enriched in uranium. Naturally occurring radioactive materials (NORM) in these U-rich coals and associated coal combustion residues (CCRs) have not been well characterized. Here we measure NORM (Th, U, 228 Ra, 226 Ra, and 210 Pb) in coals from eight U-rich coal deposits in China and the associated CCRs from one of these deposits. We compared NORM in these U-rich coals and associated CCRs to CCRs collected from the Beijing area and natural loess sediments from northeastern China. We found elevated U concentrations (up to 476 ppm) that correspond to low 232 Th/ 238 U and 228 Ra/ 226 Ra activity ratios (≪1) in the coal samples. 226 Ra and 228 Ra activities correlate with 238 U and 232 Th activities, respectively, and 226 Ra activities correlate well with 210 Pb activities across all coal samples. We used measured NORM activities and ash yields in coals to model the activities of CCRs from all U-rich coals analyzed in this study. The activities of measured and modeled CCRs derived from U-rich coals exceed the standards for radiation in building materials, particularly for CCRs originating from coals with U > 10 ppm. Since beneficial use of high-U Chinese CCRs in building materials is not a suitable option, careful consideration needs to be taken to limit potential air and water contamination upon disposal of U- and Ra-rich CCRs.

Power-generating process of obtaining gas-energy carrier and reducer from coal

International Nuclear Information System (INIS)

Tleugabulov, S.; Duncheva, E.; Zubkevich, M.

1999-01-01

The manufacture of power-generating gas has the important economic value for Kazakhstan having large territory, raw and fuel resources especially power coal and clean coal wastes. The technology of reception of gas-energy carrier and reducer from power coal is developed. The basic product of technological process is heated reducing gas. Reducing potential of the gas is characterized by a volumetric share of components (CO+H 2 )-RC in relation to volume of whole mix of gases received with gasification of coal. The value of parameter RC is regulated by a degree of enrichment of air by oxygen r 0 , and the temperature - by the charge of a parity of endothermic reaction in the chamber of gas regeneration. The dependence of the gas structure and temperature on the degree of enrichment of air by oxygen is shown and the circuit of the gas generator is given. (author)

Evaluation of the effect of macerals on coal permeability in Tazareh and Parvadeh mines

Directory of Open Access Journals (Sweden)

Farhang Sereshki

2016-08-01

Full Text Available In recent decades, the subject of gas emission in underground coal mines in many countries is an important subject. Many factors affect in gas emissions in coal seams. Geological and physical structures of coal are affecting on gas emissions'. Also, composition and mineralization of coal, affect in coal permeability for different gases. In this study, the relationship between maceral composition and coal permeability in Tazareh and Parvadeh mines has been studied. Accordingly, a laboratory studies to investigate the relationship between coal composition and coal permeability was done. In coal samples, with MFORR equipment the permeability test was done. With microscopic analysis, the maceral contents of coal such as Inertinite and Vitrinite have been measured. Accordingly, many coal samples of Parvadeh and Tazareh coal mines have the pyrite as the dominant mineral matter. Parvadeh coal samples has the average percentage of Vitrinite equal 81.34% and 10.52% Inertinite. Also, in the Tazareh coal samples in Eastern Alborz coal mines, the average percentage of Vitrinite is 69.31% and inertinite is 22.47%. The average percentage of Pyrite content in Parvadeh coal samples in Tabas coal mines is 2.38% and in the Tazareh coal samples in Eastern Alborz coal mines is 2.62%.  The permeability test results have been shown, which, with increase of Inertinite contents, the permeability of coal is increasing. Also, test results have been shown, there was a reduction in the coal permeability with increasing of mineral contents and carbonate contents of the coal. So, the coal permeability in Tabas coal samples is more than Eastern Alborz coal samples.

EMSL Quarterly Highlights Report: FY 2008, 3rd Quarter

Energy Technology Data Exchange (ETDEWEB)

Showalter, Mary Ann

2008-09-16

The EMSL Quarterly Highlights Report covers the science, staff and user recognition, and publication activities that occurred during the 1st quarter (October 2007 - December 2007) of Fiscal Year 2008.

EMSL Quarterly Highlights Report: 1st Quarter, FY08

Energy Technology Data Exchange (ETDEWEB)

Showalter, Mary Ann

2008-01-28

The EMSL Quarterly Highlights Report covers the science, staff and user recognition, and publication activities that occurred during the 1st quarter (October 2007 - December 2007) of Fiscal Year 2008.

Possibility of chemical products from coal

Energy Technology Data Exchange (ETDEWEB)

Harris, G A; Sinnett, C E; Swift, H E

1982-01-01

An account of the SRC-II plant, which produces solvent refined coal (SRC), a liquid product. SRC is a raw material with potential as a new source of hydrocarbons. Topics discussed include the possibilities of its use as a petrochemical feedstock; derivatives and the amounts obtained; economic assessments and expected prices. The translator of this article puts forward the view that, due to the difficulty of obtaining the type of coal needed for SRC-II, the best policy for Japanese coal liquefaction is methanol synthesis.

Mining-related environmental impacts of carbon mitigation; Coal-based carbon capture and sequestration and wind-enabling transmission expansion

Energy Technology Data Exchange (ETDEWEB)

Grubert, Emily

2010-09-15

Carbon mitigation can occur by preventing generation of greenhouse gases or by preventing emissions from entering the atmosphere. Accordingly, increasing the use of wind energy or carbon capture and storage (CCS) at coal-fired power plants could reduce carbon emissions. This work compares the direct mining impacts of increased coal demand associated with CCS with those of increased aluminum demand for expanding transmission systems to enable wind power incorporation. Aluminum needs for expanded transmission probably represent a one-time need for about 1.5% of Jamaica's annual bauxite production, while CCS coal needs for the same mitigation could almost double US coal demand.

Regenerable sorbents for mercury capture in simulated coal combustion flue gas.

Science.gov (United States)

Rodríguez-Pérez, Jorge; López-Antón, M Antonia; Díaz-Somoano, Mercedes; García, Roberto; Martínez-Tarazona, M Rosa

2013-09-15

This work demonstrates that regenerable sorbents containing nano-particles of gold dispersed on an activated carbon are efficient and long-life materials for capturing mercury species from coal combustion flue gases. These sorbents can be used in such a way that the high investment entailed in their preparation will be compensated for by the recovery of all valuable materials. The characteristics of the support and dispersion of gold in the carbon surface influence the efficiency and lifetime of the sorbents. The main factor that determines the retention of mercury and the regeneration of the sorbent is the presence of reactive gases that enhance mercury retention capacity. The capture of mercury is a consequence of two mechanisms: (i) the retention of elemental mercury by amalgamation with gold and (ii) the retention of oxidized mercury on the activated carbon support. These sorbents were specifically designed for retaining the mercury remaining in gas phase after the desulfurization units in coal power plants. Copyright © 2013 Elsevier B.V. All rights reserved.

NMR spectroscopy of coal pyrolysis products

Energy Technology Data Exchange (ETDEWEB)

Polonov, V.M.; Kalabin, G.A.; Kushnarev, D.F.; Shevchenko, G.G.

1985-12-01

The authors consider the scope for using H 1 and C 13 NMR spectroscopy to describe the products from coal pyrolysis and hydrogenization. The accuracy of the structural information provided by the best NMR methods is also considered. The stuctural parameters derived from H 1 and C 13 NMR spectra are presented. Results demonstrate the high accuracy and sensitivity of the structural information provided by H 1 AND C 13 NMR spectra for coal products. There are substantial structural differences between the soluble products from medium-temperature coking of Cheremkhov coal and high-speed pyrolysis of Kan-Acha coal, and also differences in behavior during hydrogenation. These differences are related to the structure of the organic matter in the initial coal and to differences in the pyrolysis mechanisms.

Air toxic emissions from the combustion of coal: Identifying and quantifying hazardous air pollutants from US coals

Energy Technology Data Exchange (ETDEWEB)

Szpunar, C.B.

1992-09-01

This report addresses the key air toxic emissions likely to emanate from continued and expanded use of domestic coal. It identifies and quantifies those trace elements specified in the US 1990 Clean Air Act Amendments, by tabulating selected characterization data on various source coals by region, state, and rank. On the basis of measurements by various researchers, this report also identifies those organic compounds likely to be derived from the coal combustion process (although their formation is highly dependent on specific boiler configurations and operating conditions).

Air toxic emissions from the combustion of coal: Identifying and quantifying hazardous air pollutants from US coals

International Nuclear Information System (INIS)

Szpunar, C.B.

1992-09-01

This report addresses the key air toxic emissions likely to emanate from continued and expanded use of domestic coal. It identifies and quantifies those trace elements specified in the US 1990 Clean Air Act Amendments, by tabulating selected characterization data on various source coals by region, state, and rank. On the basis of measurements by various researchers, this report also identifies those organic compounds likely to be derived from the coal combustion process (although their formation is highly dependent on specific boiler configurations and operating conditions)

Measurement and modeling of advanced coal conversion processes. Twenty-first quarterly report, October 1, 1991--December 31, 1991

Energy Technology Data Exchange (ETDEWEB)

Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [Advanced Fuel Research, Inc., East Hartford, CT (United States); Smoot, L.D.; Brewster, B.S. [Brigham Young Univ., Provo, UT (United States)

1991-12-31

The objective of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines.

Measurement and modeling of advanced coal conversion processes. 19th quarterly report, April 1, 1991--June 30, 1991

Energy Technology Data Exchange (ETDEWEB)

Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [Advanced Fuel Research, Inc., East Hartford, CT (United States); Smoot, L.D.; Brewster, B.S. [Brigham Young Univ., Provo, UT (United States)

1991-09-25

The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)

Coal background paper. Coal demand

International Nuclear Information System (INIS)

1997-01-01

Statistical data are presented on coal demands in IEA and OECD member countries and in other countries. Coal coaking and coaking coal consumption data are tabulated, and IEA secretariat's coal demand projections are summarized. Coal supply and production data by countries are given. Finally, coal trade data are presented, broken down for hard coal, steam coal, coking coal (imports and export). (R.P.)

Active methods of mercury removal from flue gases.

Science.gov (United States)

Marczak, Marta; Budzyń, Stanisław; Szczurowski, Jakub; Kogut, Krzysztof; Burmistrz, Piotr

2018-03-23

Due to its adverse impact on health, as well as its global distribution, long atmospheric lifetime and propensity for deposition in the aquatic environment and in living tissue, the US Environmental Protection Agency (US EPA) has classified mercury and its compounds as a severe air quality threat. Such widespread presence of mercury in the environment originates from both natural and anthropogenic sources. Global anthropogenic emission of mercury is evaluated at 2000 Mg year -1 . According to the National Centre for Emissions Management (Pol. KOBiZE) report for 2014, Polish annual mercury emissions amount to approximately 10 Mg. Over 90% of mercury emissions in Poland originate from combustion of coal.The purpose of this paper was to understand mercury behaviour during sub-bituminous coal and lignite combustion for flue gas purification in terms of reduction of emissions by active methods. The average mercury content in Polish sub-bituminous coal and lignite was 103.7 and 443.5 μg kg -1 . The concentration of mercury in flue gases emitted into the atmosphere was 5.3 μg m -3 for sub-bituminous coal and 17.5 μg m -3 for lignite. The study analysed six low-cost sorbents with the average achieved efficiency of mercury removal from 30.6 to 92.9% for sub-bituminous coal and 22.8 to 80.3% for lignite combustion. Also, the effect of coke dust grain size was examined for mercury sorptive properties. The fine fraction of coke dust (CD) adsorbed within 243-277 μg Hg kg -1 , while the largest fraction at only 95 μg Hg kg -1 . The CD fraction physical oxidation of Hg in the flue gas, its effectiveness has increased twofold.

Coal-oil coprocessing at HTI - development and improvement of the technology

Energy Technology Data Exchange (ETDEWEB)

Stalzer, R.H.; Lee, L.K.; Hu, J.; Comolli, A. [Hydrocarbon Technologies, Inc., Lawrenceville, NJ (United States)

1995-12-31

Co-Processing refers to the combined processing of coal and petroleum-derived heavy oil feedstocks. The coal feedstocks used are those typically utilized in direct coal liquefaction: bituminous, subbituminous, and lignites. Petroleum-derived oil, is typically a petroleum residuum, containing at least 70 W% material boiling above 525{degrees}C. The combined coal and oil feedstocks are processed simultaneously with the dual objective of liquefying the coal and upgrading the petroleum-derived residuum to lower boiling (<525{degrees}C) premium products. HTI`s investigation of the Co-Processing technology has included work performed in laboratory, bench and PDU scale operations. The concept of co-processing technology is quite simple and a natural outgrowth of the work done with direct coal liquefaction. A 36 month program to evaluate new process concepts in coal-oil coprocessing at the bench-scale was begun in September 1994 and runs until September 1997. Included in this continuous bench-scale program are provisions to examine new improvements in areas such as: interstage product separation, feedstock concentrations (coal/oil), improved supported/dispersed catalysts, optimization of reactor temperature sequencing, and in-line hydrotreating. This does not preclude other ideas from DOE contracts and other sources that can lead to improved product quality and economics. This research work has led to important findings which significantly increased liquid yields, improved product quality, and improved process economics.

Coal and the greenhouse effect: strategies for the future

Energy Technology Data Exchange (ETDEWEB)

Sullivan, K M [Australian Coal Association, Sydney, NSW (Australia)

1991-07-01

A number of gases, including carbon dioxide, methane, water vapour, nitrous oxide, ozone and chlorofluorocarbons are transparent to incoming short-wave radiation, but are relatively opaque to outgoing longwave radiation. Variations in the concentration of these gases in the troposphere can alter the thermal balance of the earth's atmosphere. Outgoing terrestrial radiation which would otherwise escape to space, is trapped within the inner layer of the atmosphere, resulting in a potential warming and the greenhouse effect. It is estimated that at present greenhouse gases other than carbon dioxide, contribute about 50% to the greenhouse effect. However, in the future, the contribution made by gases other than CO{sub 2} will be become greater. Greenhouse gases arise from a wide range of sources and their escalating increase is largely related to an increase in the world's population, and the standard of living of many areas as well as changes in lifestyle. The effect of increasing man-made greenhouse gases in the troposphere is unknown, but it is proposed that it may increase temperature and may modify climate, agricultural response and land use. The facts and uncertainties relating to potential greenhouse warming are examined. Man-generated emissions are quantified and their source identified. Coal's contribution worldwide is examined in detail and is shown to be small, being about 10% of man-made greenhouse gases. Strategies for minimising emissions, having maximum potential for reduction, with minimum impact on man are suggested. 16 refs., 1 fig., 3 tabs.

Use of pyrolysis gas from coal as reburn fuel. Final report; Einsatz von kohlestaemmigem Pyrolysegas als Reduktionsbrennstoff. Schlussbericht

Energy Technology Data Exchange (ETDEWEB)

Greul, U.; Magel, C.; Moersch, O.; Ruediger, H.; Storm, C.; Schnell, U.; Spliethoff, H.; Hein, K.R.G.

1996-12-31

The research project`s aim was to reduce nitrogen emissions from pulverized-coal furnaces by fuel staging with pyrolysis gas from coal. The test fuels were 6 German and Australian coals. The aim achieved has been the statement that the described method is an adequate means to attain to and remain below emission values of 200 mg/m{sup 3}. The method of fuel staging using coal-original gases was investigated with tests focussing the most important process parameters such as coal type, devolatilization ratio, temperature, residence time, and stoichiometry. The relevant features determined with an entrained flow reactor and with a fluidized-bed reactor were the impact of devolatilization temperatures on carbonized residue and pyrolysis products, the distribution of fuel nitrogen, and the quality of gas and tar, including the respective effects on NO{sub x} formation and reduction in staged combustion. The validation of the mathematical model was done with the experimentally obtained data. The criteria considered fundamental for achieving the NO{sub x} reduction level are temperature, air ratio, and residence time in the reduction zone of the furnace. The pyrolysis tests manifested the strong influence of the coal type and the devolatilization conditions on the composition of the gases and the attainable NO{sub x} reduction. The tars in the pyrolysis gases, with their nitrogen compounds, improve the reducing effect of available nitrogen oxides. By using pyrolysis gases from coal as reburning fuel, NO{sub x} emissions of less than 200 mg/m{sup 3} can be obtained at air ratios around 0.95. (orig./SR) [Deutsch] Das Forschungsprojekt verfolgte das Ziel mit 6 deutschen und australischen Kohlen die Stickoxidemissionen aus Kohlestaubfeuerungen durch Brennstoffstufung mit Pyrolysegas als Reduktionsbrennstoff zu verringern. Das erreichte Ziel war der Nachweis, dass mit dem beschriebenen Verfahren NO{sub x}-Emissionswerte von 200 mg/m{sup 3} erreicht und unterschritten werden

Deformation effects in the heavy ion quarter-point angle

International Nuclear Information System (INIS)

Almeida, F.I.A. de; Hussein, M.S.

1984-01-01

The effects of static and dynamic deformation on the heavy-ion elastic scattering quarter-point angle are discussed and analyzed in the sudden approximation. Simple expressions are derived within the Fresnel model and applications to several heavy-ion systems are presented. (Author) [pt

ESTIMATION OF NEAR SUBSURFACE COAL FIRE GAS EMISSIONS BASED ON GEOPHYSICAL INVESTIGATIONS

Science.gov (United States)

Chen-Brauchler, D.; Meyer, U.; Schlömer, S.; Kus, J.; Gundelach, V.; Wuttke, M.; Fischer, C.; Rueter, H.

2009-12-01

Spontaneous and industrially caused subsurface coal fires are worldwide disasters that destroy coal resources, cause air pollution and emit a large amount of green house gases. Especially in developing countries, such as China, India and Malaysia, this problem has intensified over the last 15 years. In China alone, 10 to 20 million tons of coal are believed to be lost in uncontrolled coal fires. The cooperation of developing countries and industrialized countries is needed to enforce internationally concerted approaches and political attention towards the problem. The Clean Development Mechanism (CDM) under the framework of the Kyoto Protocol may provide an international stage for financial investment needed to fight the disastrous situation. A Sino-German research project for coal fire exploration, monitoring and extinction applied several geophysical approaches in order to estimate the annual baseline especially of CO2 emissions from near subsurface coal fires. As a result of this project, we present verifiable methodologies that may be used in the CDM framework to estimate the amount of CO2 emissions from near subsurface coal fires. We developed three possibilities to approach the estimation based on (1) thermal energy release, (2) geological and geometrical determinations as well as (3) direct gas measurement. The studies involve the investigation of the physical property changes of the coal seam and bedrock during different burning stages of a underground coal fire. Various geophysical monitoring methods were applied from near surface to determine the coal volume, fire propagation, temperature anomalies, etc.

Technology assessment of various coal-fuel options

International Nuclear Information System (INIS)

Coenen, R.; Findling, B.; Klein-Vielhauer, S.; Nieke, E.; Paschen, H.; Tangen, H.; Wintzer, D.

1991-01-01

The technology assessment (TA) study of coal-based fuels presented in this report was performed for the Federal Ministry for Research and Technology. Its goal was to support decision-making of the Federal Ministry for Research and Technology in the field of coal conversion. Various technical options of coal liquefaction have been analyzed on the basis of hard coal as well as lignite -- direct liquefaction of coal (hydrogenation) and different possibilities of indirect liquefaction, that is the production of fuels (methanol, gasoline) by processing products of coal gasification. The TA study takes into consideration the entire technology chain from coal mining via coal conversion to the utilization of coal-based fuels in road transport. The analysis focuses on costs of the various options, overall economic effects, which include effects on employment and public budgets, and on environmental consequences compared to the use of liquid fuels derived from oil. Furthermore, requirements of infrastructure and other problems of the introduction of coal-based fuels as well as prospects for the export of technologies of direct and indirect coal liquefaction have been analyzed in the study. 14 figs., 10 tabs

Idaho National Laboratory Quarterly Occurrence Analysis - 3rd Quarter FY-2016

Energy Technology Data Exchange (ETDEWEB)

Mitchell, Lisbeth Ann [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2016-09-01

This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of 73 reportable events (23 from the 3rd Qtr FY-16 and 50 from the prior three reporting quarters), as well as 45 other issue reports (including events found to be not reportable and Significant Category A and B conditions) identified at INL during the past 12 months (16 from this quarter and 29 from the prior three quarters).

Idaho National Laboratory Quarterly Occurrence Analysis - 1st Quarter FY 2016

Energy Technology Data Exchange (ETDEWEB)

Mitchell, Lisbeth Ann [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2016-03-01

This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of 74 reportable events (16 from the 1st Qtr FY-16 and 58 from the prior three reporting quarters), as well as 35 other issue reports (including events found to be not reportable and Significant Category A and B conditions) identified at INL during the past 12 months (15 from this quarter and 20 from the prior three quarters).

Synthesis on coal gases: exploitation, risks and impacts on the environment

International Nuclear Information System (INIS)

Bonijoly, D.; Fabriol, H.; Bazargan, B.; Defossez, P.; Lary, L. de; Leynet, A.; Schumacher, J.P.; Didier, C.; Andres, S.; Bonnard, R.; Lahaie, F.; Pokryszka, Z.

2013-10-01

After some generalities on coal gas (origin, fracturing, classification, present production in the world, regulatory obligations), this report proposes an overview of present extraction methods and techniques and a simplified analysis of risks and impacts on the environment. It distinguishes between accidental risks (leakages in different locations or components, uncontrolled gas migration), environmental impacts (on water, air quality, soil quality, health, and ecosystems, and greenhouse gas emissions), and other pollutions (traffic, noise, land use, induced seismicity, underground fires). Perspectives for research are discussed in terms of lacks of knowledge, scientific, technical and financial deadlocks

Petrographic characterization of the solid products of coal- pitch coprocessing

Energy Technology Data Exchange (ETDEWEB)

Potter, J.; Kybett, B.D.; McDougall, W.J.; Nambudiri, E.M.V.; Rahimi, P.; Price, J.T.

1986-06-01

Petrographic studies were conducted on four solid residues resulting from the hydrogenation process of 1) Forestburg sub- bituminous coal alone, 2) the coal with a non-coking solvent (anthracene oil), 3) pitch (Cold Lake vacuum-bottom deposits), and 4) a mixture of coal and pitch. The purpose was to determine the amounts of coal and pitch-derived solids in the residues. All the residues were produced under identical severe conditions of liquefaction to promote the formation of solids. The coal processed with anthracene oil gives a residue consisting mainly of isotropic huminitic solids. If the coal is hydrogenated under similar conditions but without a solvent, the predominant residual solids are anisotropic semicokes displaying coarse mosaic textures, which form from vitroplast. The residual products from the hydrogenated Cold Lake vacuum- bottom deposits are also dominantly anisotropic semicokes; these display coarse mosaics and flow textures, and form by the growth and coalescence of mesophase spherules. Both coal- and pitch-derived solids are identified in a residue produced by coprocessing the Forestburg coal with the pitch from the Cold Lake vacuum-bottom deposits. It is concluded that the huminite macerals in the coal generate the fine-grained, mosaic-textured semicokes, whereas the pitch produces the coarse mosaics and flow-textured semicokes.

Relationships between coal-quality and organic-geochemical parameters: A case study of the Hafik coal deposits (Sivas Basin, Turkey)

Energy Technology Data Exchange (ETDEWEB)

Erik, N. Yalcin; Sancar, S. [Cumhuriyet University, Department of Geological Engineering, Sivas (Turkey)

2010-09-01

This study provides coal-quality, organic-petrographic and organic-geochemical data on Tertiary subbituminous coal of the Hafik area, northwestern part of the Sivas Basin, Turkey. Coal-petrological studies along with proximate and ultimate analyses were undertaken to determine the organic-petrographic characteristics of the Hafik coals. Huminite reflectances were found to be between 0.38 and 0.48% (corresponding to an organic-material-rich and coal layers), values characteristic of low maturity. This parameter shows a good correlation with calorific values (average 21,060 kJ/kg) and average T{sub max} (422 C) mineral-matter diagenesis, indicating immaturity. The studied coals and organic material underwent only low-grade transformation, a consequence of low lithostatic pressure. Therefore, the Hafik coals are actually subbituminous in rank. Rock-Eval analysis results show types II/III and III kerogens. The organic fraction of the coals is mostly comprised of humic-group macerals (gelinites), with small percentages derived from the inertinite and liptinite groups. In this study, organic-petrographic, organic-geochemical and coal quality data were compared. The Hafik deposit is a high-ash, high-sulfur coal. The mineral matter of the coals is comprised mainly of calcite and clay minerals. (author)

The magnetohydrodynamics Coal-Fired Flow Facility

Energy Technology Data Exchange (ETDEWEB)

1991-07-01

In this quarterly technical progress report, UTSI summarizes the results of a multi-task research and development project directed toward the development of the technology for the commercialization of the steam bottoming plant for the MHD steam combined cycle power plant. The report covers the final test in a 2000-hour proof-of-concept (POC) test series on eastern coal, the plans and progress for the facility modifications and the conduct of the POC tests to be conducted with western coal. Results summarized in the report include chloride emissions from the particle removal (ESP/BH) processes, nitrogen and sulfur oxide emissions for various tests conditions, measurements of particulate control efficiency and management of the facility holding ponds during testing. Activities relating to corrosion and deposition probe measurements during testing and the fouling of heat transfer tubes and interaction with sootblowing cycles are summarized. The performance of both UTSI and Mississippi State University (MSU) advanced diagnostic systems is reported. Significant administrative and contractual actions are included. 2 refs., 28 figs., 7 tabs.

ETS: free quotas for subsidy coal

International Nuclear Information System (INIS)

Mary, Olivier

2016-01-01

This article comments information published by a NGO according to which less than 10 per cent of investments financed through the 10c article of the ETS European directive have been made on technologies which emit less greenhouse gases, or on a diversification of the energy mix, and 90 pc of these quotas have been used in East European countries to modernize obsolete thermal plants, mainly coal plants, or to build new ones. These facts also highlight a flagrant lack of transparency in the award and use of these quotas

Radiological Impact Study of the Coal-Fired Power Plant of Velilla; Estudio del Impacto Radiologico de la Central Termica de Carbon de Velilla

Energy Technology Data Exchange (ETDEWEB)

Robles, B.; Mora, J. c.; Trueba, C.; Rodriguez, J.; Baeza, A.; Corbacho, J. a.; Guillen, J.; Miralles, Y.

2013-10-01

Coal, fuel used in thermal power plants for electricity production, contains variable concentrations of naturally occurring radionuclides from natural disintegration series of 238U, 235U, 232Th and also the 40K, which are enhanced in the wastes and coproducts due to the industrial process. For this reason, natural radionuclides which are part of the non-combustible fraction of coal, except those volatiles which incorporate directly to the flue gases, concentrates and are partitioned between fly ashes and bottom ashes. This enhancement could cause, to the workers of the installation and to members of the public around the plant, an increase in the exposure which should be assessed under the radiation protection point of view. Present report collect the results obtained from a screening assessment of the radiological impact derived from the normal operation of the Velilla coal-fired power plant. The project where this assessment was performed is part of a bigger project which is jointly developed by the Unit of Radiation Protection of the Public and the Environment (UPRPYMA) of CIEMAT and the Environmental Radioactivity Laboratory of the Extremadura University (LARUEX) in agreement with the Spanish Association of the Electrical Industry (ENUSA). (Author)

Radiological Impact Study of the Coal-Fired Power Plant of Lada; Estudio del Impacto Radiologico de la Central Termica de Carbon de Lada

Energy Technology Data Exchange (ETDEWEB)

Robles, B.; Baeza, A.; Mora, J. C.; Corbacho, J. A.; Trueba, C.; Guillen, J.; Rodriguez, J.; Miralles, Y.

2014-02-01

Coal, fuel used in thermal power plants for electricity production, contains variable concentrations of naturally occurring radionuclides from natural disintegration series of 238{sup U}, 235{sup U}, 232{sup T}h and also the 40K, which are enhanced in the wastes and coproducts due to the industrial process. For this reason, natural radionuclides which are part of the noncombustible fraction of coal, except those volatiles which incorporate directly to the flue gases, concentrates and are partitioned between fly ashes and bottom ashes. This enhancement could cause, to the workers of the installation and to members of the public around the plant, an increase in the exposure which should be assessed under the radiation protection point of view. Present report collect the results obtained from a screening assessment of the radiological impact derived from the normal operation of the Lada coal-fired power plant. The project where this assessment was performed is part of a bigger project which is jointly developed by the Unit of Radiation Protection of the Public and the Environment (UPRPYMA) of CIEMAT and the Environmental Radioactivity Laboratory of the Extremadura University (LARUEX) in agreement with the Spanish Association of the Electrical Industry (ENUSA). (Author)

Coal and Open-pit surface mining impacts on American Lands (COAL)

Science.gov (United States)

Brown, T. A.; McGibbney, L. J.

2017-12-01

Mining is known to cause environmental degradation, but software tools to identify its impacts are lacking. However, remote sensing, spectral reflectance, and geographic data are readily available, and high-performance cloud computing resources exist for scientific research. Coal and Open-pit surface mining impacts on American Lands (COAL) provides a suite of algorithms and documentation to leverage these data and resources to identify evidence of mining and correlate it with environmental impacts over time.COAL was originally developed as a 2016 - 2017 senior capstone collaboration between scientists at the NASA Jet Propulsion Laboratory (JPL) and computer science students at Oregon State University (OSU). The COAL team implemented a free and open-source software library called "pycoal" in the Python programming language which facilitated a case study of the effects of coal mining on water resources. Evidence of acid mine drainage associated with an open-pit coal mine in New Mexico was derived by correlating imaging spectrometer data from the JPL Airborne Visible/InfraRed Imaging Spectrometer - Next Generation (AVIRIS-NG), spectral reflectance data published by the USGS Spectroscopy Laboratory in the USGS Digital Spectral Library 06, and GIS hydrography data published by the USGS National Geospatial Program in The National Map. This case study indicated that the spectral and geospatial algorithms developed by COAL can be used successfully to analyze the environmental impacts of mining activities.Continued development of COAL has been promoted by a Startup allocation award of high-performance computing resources from the Extreme Science and Engineering Discovery Environment (XSEDE). These resources allow the team to undertake further benchmarking, evaluation, and experimentation using multiple XSEDE resources. The opportunity to use computational infrastructure of this caliber will further enable the development of a science gateway to continue foundational COAL

Understanding the effects of sulfur on mercury capture from coal-fired utility flue gases

Energy Technology Data Exchange (ETDEWEB)

Morris, E.A.; Morita, K.; Jia, C.Q. [University of Toronto, Toronto, ON (Canada)

2010-07-01

Coal combustion continues to be a major source of energy throughout the world and is the leading contributor to anthropogenic mercury emissions. Effective control of these emissions requires a good understanding of how other flue gas constituents such as sulfur dioxide (SO{sub 2}) and sulfur trioxide (SO{sub 3}) may interfere in the removal process. Most of the current literature suggests that SO{sub 2} hinders elemental mercury (Hg{sup 0}) oxidation by scavenging oxidizing species such as chlorine (Cl2) and reduces the overall efficiency of mercury capture, while there is evidence to suggest that SO{sub 2} with oxygen (O{sub 2}) enhances Hg{sup 0} oxidation by promoting Cl2 formation below 100{sup o}C. However, studies in which SO{sub 2} was shown to have a positive correlation with Hg{sup 0} oxidation in full-scale utilities indicate that these interactions may be heavily dependent on operating conditions, particularly chlorine content of the coal and temperature. While bench-scale studies explicitly targeting SO{sub 3} are scarce, the general consensus among full-scale coal-fired utilities is that its presence in flue gas has a strong negative correlation with mercury capture efficiency. The exact reason behind this observed correlation is not completely clear, however. While SO{sub 3} is an inevitable product of SO{sub 2} oxidation by O{sub 2}, a reaction that hinders Hg{sup 0} oxidation, it readily reacts with water vapor, forms sulfuric acid (H{sub 2 }SO{sub 4}) at the surface of carbon, and physically blocks active sites of carbon. On the other hand, H{sub 2}SO{sub 4} on carbon surfaces may increase mercury capacity either through the creation of oxidation sites on the carbon surface or through a direct reaction of mercury with the acid. However, neither of these beneficial impacts is expected to be of practical significance for an activated carbon injection system in a real coal-fired utility flue gas.

Development of sustainable coal to liquid processes: Minimising process CO2 emissions

Directory of Open Access Journals (Sweden)

S. Kauchali

2017-12-01

Full Text Available Traditional coal-to-liquid (CTL plants are synonymous with the production of carbon dioxide. Coal may be gasified in the presence of steam and oxygen to produce gas comprising carbon dioxide (CO2, carbon monoxide (CO, methane (CH4, hydrogen (H2 and steam (H2O. The gases can be reacted to a myriad of chemicals and fuels via the Fischer-Tropsch (FT reaction. However, excess carbon dioxide is generated via the Water-Gas-Shift reaction during preparation of CO:H2 ratios for FT. Here, a process development is represented on a CHO phase diagram, where unique regions are identified for autothermal operations for coal conversion. Considerations are given to develop idealised processes for the production of liquid chemicals from coal which emit minimal process CO2, require minimal energy input and do not require steam. This is achieved by co-feeding coal with methane and identifying endothermic-exothermic process pairs for methane-coal dry reforming. Furthermore, it is shown that a preferred method to produce liquid fuels from coal is by first creating dimethyl ether (DME as an intermediate, followed by the dehydration of DME to liquid fuels (gasoline range. For this route, via DME, the CO2 emission was found to be four times less than idealised CTL processes. Keywords: Gasification, Reforming, Coal to liquid, Carbon dioxide, Autothermal, Fischer tropsch

Secondary biogenic coal seam gas reservoirs in New Zealand: A preliminary assessment of gas contents

Energy Technology Data Exchange (ETDEWEB)

Butland, Carol I. [Department of Geological Sciences, University of Canterbury, Private Bag 4800, Christchurch (New Zealand); Moore, Tim A. [Department of Geological Sciences, University of Canterbury, Private Bag 4800, Christchurch (New Zealand); Solid Energy NZ Ltd., P.O. Box 1303, Christchurch (New Zealand)

2008-10-02

Four coal cores, one from the Huntly (Eocene), two from the Ohai (Cretaceous) and one from the Greymouth (Cretaceous) coalfields, were sampled and analysed in terms of gas content and coal properties. The coals vary in rank from subbituminous B-A (Huntly) to subbituminous C-A (Ohai), and high volatile A bituminous (Greymouth). Average gas contents were 1.60 m{sup 3}/t (s 0.2) in the Huntly core, 4.80 m{sup 3}/t (s = 0.8) in the Ohai cores, and 2.39 m{sup 3}/t (s = 0.8) in the Greymouth core. The Ohai core not only contained more gas but also had the highest saturation (75%) compared with the Huntly (33%) and Greymouth (45%) cores. Carbon isotopes indicate that the Ohai gas is more mature, containing higher {delta}{sup 13}C isotopes values than either the Huntly or Greymouth gas samples. This may indicate that the gas was derived from a mixed biogenic and thermogenic source. The Huntly and Greymouth gases appear to be derived solely from a secondary biogenic (by CO{sub 2} reduction) source. Although the data set is limited, preliminary analysis indicates that ash yield is the dominant control on gas volume in all samples where the ash yield was above 10%. Below 10%, the amount of gas variation is unrelated to ash yield. Although organic content has some influence on gas volume, associations are basin and/or rank dependent. In the Huntly core total gas content and structured vitrinite increase together. Although this relationship does not appear for the other core data for the Ohai SC3 core, lost gas and fusinite are associated whereas gelovitrinite (unstructured vitrinite) correlates positively with residual gas for the Greymouth data. (author)

Impact of Contaminants Present in Coal-Biomass Derived Synthesis Gas on Water-gas Shift and Fischer-Tropsch Synthesis Catalysts

Energy Technology Data Exchange (ETDEWEB)

Alptekin, Gokhan [TDA Research, Inc., Wheat Ridge, CO (United States)

2013-02-15

Co-gasification of biomass and coal in large-scale, Integrated Gasification Combined Cycle (IGCC) plants increases the efficiency and reduces the environmental impact of making synthesis gas ("syngas") that can be used in Coal-Biomass-to-Liquids (CBTL) processes for producing transportation fuels. However, the water-gas shift (WGS) and Fischer-Tropsch synthesis (FTS) catalysts used in these processes may be poisoned by multiple contaminants found in coal-biomass derived syngas; sulfur species, trace toxic metals, halides, nitrogen species, the vapors of alkali metals and their salts (e.g., KCl and NaCl), ammonia, and phosphorous. Thus, it is essential to develop a fundamental understanding of poisoning/inhibition mechanisms before investing in the development of any costly mitigation technologies. We therefore investigated the impact of potential contaminants (H₂S, NH₃, HCN, AsH₃, PH₃, HCl, NaCl, KCl, AS₃, NH₄NO₃, NH₄OH, KNO₃, HBr, HF, and HNO₃) on the performance and lifetime of commercially available and generic (prepared in-house) WGS and FT catalysts.

Cleavage and crosslinking of polymeric coal structures during pyrolysis

Energy Technology Data Exchange (ETDEWEB)

McMillen, D.F.; Malhotra, R.

1992-02-01

The ultimate objective of this project was to develop a better understanding of volatiles production to help optimize the yield and character of condensable coproducts during coal pyrolysis or mild gasification. The specific objectives were to (1) Develop pyrolysis procedures that minimize secondary reactions; and (2) Develop coal pretreatments that current knowledge suggests will prorate bond scission or prevent retrograde reactions. Our approach was to study the pyrolysis of coals and tar-loaded coals by using several techniques that span a range of heating rates and pressures. Slow-heating pyrolyses were performed at low pressures in the inlet of a field ionization mass spectrometer and at atmospheric pressures in a thermogravimetric analyzer. Moderately rapid-heating pyrolyses were performed in a vacuum TGA apparatus and in sealed silica ampules heated in a molten-salt bath. The fastest heating rates were achieved with laser pyrolysis at about 30,000 X/s. The high tar yield seen in this work where the entire volume of the coal particle becomes hot and fluid at very nearly the same time, taken together with the evident non-vapor transport of the tar under these conditions, emphasizes the importance of better understanding the development of fluidity during coal heating. This specifically includes the profound effects--long-recognized but poorly understood that mild oxidation has in suppressing coal fluidity. It also includes the more recently recognized fact that heating in the presence of an inert gas produced substantially greater fluidity than does heating in the presence of combustion gases, even if the conditions are very fuel rich and all the oxygen itself has already been consumed when the coal particles are encountered.

Effect of the parameters of a straight-through pulverized coal spray on formation of nitrogen oxides

Energy Technology Data Exchange (ETDEWEB)

Kotler, V.R.

1987-04-01

Experiments were conducted on varying the parameters affecting intensity of the mixing process at the starting point of a pulverized coal spray. Investigations were carried out using Donetsk black coal in a BKZ-210-140FZhSh steam generator equipped with a tangential combustion chamber. The plant featured liquid slag removal and direct blow-in as well as a medium-speed model VSM-140 mill. Four experiments were conducted in which gas samples were taken from the combustion chamber and analyzed for RO/sub 2/ and O/sub 2/ as well as CO and H/sub 2/. A relationship between reducing gases at the starting point of the torch and the initial air feed factor was demonstrated. Experiments were conducted to determine a relationship between NO/sub x/ concentrations in exhaust gases and the initial air feed factor. 5 refs.

Second row transition metal sulfides for the hydrotreatment of coal-derived naphtha. 1. Catalyst preparation, characterization and comparison of rate of simultaneous removal of total sulfur, nitrogen and oxygen

Energy Technology Data Exchange (ETDEWEB)

Raje, A.P.; Liaw, S.-J.; Srinivasan, R.; Davis, B.H. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

1997-03-13

Naphtha derived from an Illinois No. 6 coal contains appreciable quantities of sulfur-, nitrogen- and oxygen-containing compounds. The hydrotreatment of this naphtha was evaluated over unsupported transition metal sulfide catalysts (Ru, Rh, Mo, Pd, Zr, Mb). The catalysts were prepared by a room temperature precipitation reaction. Surface areas, crystalline phase and particle size distributions were determined by Brunauer-Emmet-Teller (BET), X-ray diffraction (XRD) and transmission electron microscopy (TEM), respectively. A comparison of average particle sizes calculated from these three techniques has enable the understanding of the morphology of the transition metal sulfides. The catalysts exhibit a so-called volcano plot for the HDS of dibenzothiophene. Similar so-called volcano plots are also exhibited for the simultaneous hydrodesulfurization (HDS), hydrodenitrogenation (HDN) and the hydrodeoxygenation (HDO) of the coal-derived naphtha containing a mixture of heteroatoms. The order of reactivity of the transition metal catalysts is the same for all three of the processes. Ruthenium sulfide is the most active catalyst for HDS, HDN and HDO of the coal-derived naphtha. 22 refs., 3 figs., 4 tabs.

Using X-ray methods to evaluate the combustion sulfur minerals and graphitic carbon in coals and ashes

International Nuclear Information System (INIS)

Wertz, D.L.; Collins, L.W.

1988-01-01

Coals are complex mixtures of vastly different materials whose combustion kinetics may well exhibit symbiotic effects. Although the sulfur oxide gases produced during the combustion of coals may have a variety of sources, they are frequently caused by the thermal degradation of inorganic minerals to produce ''acid rain''. Since many of the minerals involved either as reactants or products in coal combustion produce well defined x-ray power diffraction (XRPD) patterns, the fate of these minerals may be followed by measuring the XRPD patterns of combustion products. Coal 1368P, a coal with an unusually high pyrite (FeS/sub 2/) fraction, has been the subject materials in our investigations of the fate of the inorganic minerals during combustion. These studies include measuring the fate of pyrite and of graphitic carbon in coal 1368P under varying combustion conditions. The results discussed in this paper were obtained by standard XRPD methods

Special file: non conventional gases at the origin of the gas financial bubble

International Nuclear Information System (INIS)

2010-01-01

This article discusses the development the non-conventional gas market. For instance, these gases (shale gas, tight gas, coal bed methane or CBM) already represent more than a half of domestic production in the United States, and they may therefore disturb the world market and worsen the overproduction situation. Because of them, liquefied natural gas projects tend to be stopped. The involved technologies are briefly evoked, as well as their profitability

Cleaning up coal-fired plants : multi-pollutant technology

Energy Technology Data Exchange (ETDEWEB)

Granson, E.

2009-06-15

Coal is the source of 41 per cent of the world's electricity. Emission reduction technologies are needed to address the rapid growth of coal-fired plants in developing countries. This article discussed a multi-pollutant technology currently being developed by Natural Resources Canada's CANMET Energy Technology Centre. The ECO technology was designed to focus on several types of emissions, including sulfur oxides (SOx), nitrogen oxides (NOx), mercury and particulates, as well as acid gases and other metals from the exhaust gas of coal-fired plants. The ECO process converts and absorbs incoming pollutants in a wet electrostatic precipitator while at the same time producing a valuable fertilizer. The ECO system is installed as part of the plant's existing particulate control device and treats flue gas in 3 process steps: (1) a dielectric barrier discharge reactor oxidizes gaseous pollutants to higher oxides; (2) an ammonia scrubber then removes sulfur dioxide (SO{sub 2}) not converted by the reactor while also removing the NOx; and (3) the wet electrostatic precipitator captures acid aerosols produced by the discharge reactor. A diagram of the ECO process flow was included. It was concluded that the systems will be installed in clean coal plants by 2015. 2 figs.

Coal 99; Kol 99

Energy Technology Data Exchange (ETDEWEB)

Sparre, C

2000-07-01

in equipment for burning pellets instead of coal. In Linkoeping waste of rubber is mixed with coal. Also Soederenergi AB has rebuilt their three coal boilers and replaced 100 % of the coal by peat and wood fuels. Coal is a reserve fuel. Several co-generation plants like Linkoeping, Norrkoeping, Uppsala and Oerebro use both coal and forest fuels. The use of coal is then concentrated to the electricity production. The average price of steam coal imported in Sweden in 1998 was 370 SEK/ton or the same as in 1997. For the world, the average import price fell about 6 USD/ton to 32 USD/ton. The price fall was concentrated to the 4th quarter. The prices have continued to fall during 1999 as a result of the crisis in Asia but are now stabilising as a result of increasing oil prices. All Swedish plants meet their emission limits of dust, SO{sub 2} and NO{sub x}, given by county administrations or concession boards. The co-generation plants have all some sort of SO{sub 2}-removal system. Mostly used is the wet-dry method. The biggest co-generation plant, in Vaesteraas, has recently invested in a catalytic NO{sub x}-cleaning system type SCR, which is reducing the emission level 80-90 %. Most other plants are using low NO{sub x}- burners or injection systems type SNCR, based on ammonium or urea, which are reducing the emissions 50-70 %. A positive effect of the recently introduced NO{sub x}-duties is a 60 % reduction compared to some years ago, when the duties were introduced. World hard coal production was about 3 700 tons in 1998, a minor decrease compared to 1997. The trade, however, has increased about 3 % to 520 mill tons. The coal demand in the OECD-countries has increased about 1,7 % yearly during the last ten years. The coal share of the energy supply is about 20% in the OECD-countries and 27% in the whole world. Several sources estimate a continuing growth during the next 20 years in spite of an increasing use of natural gas and nuclear power. The reason is a strong

Brown coal gasification made easy

International Nuclear Information System (INIS)

Hamilton, Chris

2006-01-01

Few Victorians will be aware that gas derived from coal was first used in 1849 to provide lighting in a baker's shop in Swanston Street, long before electric lighting came to the State. The first commercial 'gas works' came on stream in 1856 and Melbourne then had street lighting run on gas. By 1892 there were 50 such gas works across the State. Virtually all were fed with black coal imported from New South Wales. Brown coal was first discovered west of Melbourne in 1857, and the Latrobe Valley deposits were identified in the early 1870s. Unfortunately, such wet brown coal did not suit the gas works. Various attempts to commercialise Victorian brown coal met with mixed success as it struggled to compete with imported New South Wales black coal. In June 1924 Yallourn A transmitted the first electric power to Melbourne, and thus began the Latrobe Valley's long association with generating electric power from brown coal. Around 1950, the Metropolitan Gas Company applied for financial assistance to build a towns gas plant using imported German gasification technology which had been originally designed for a brown coal briquette feed. The State Government promptly acquired the company and formed the Gas and Fuel Corporation. The Morwell Gasification Plant was opened on 9 December 1956 and began supplying Melbourne with medium heating value towns gas

Coal, energy and environment: Proceedings

International Nuclear Information System (INIS)

Mead, J.S.; Hawse, M.L.

1994-01-01

This international conference held in Czechoslovakia was a bold attempt to establish working relationships among scientists and engineers from three world areas: Taiwan, the United States of America, and Czechoslovakia. The magic words unifying this gathering were ''clean coal utilization.'' For the ten nationalities represented, the common elements were the clean use of coal as a domestic fuel and as a source of carbon, the efficient and clean use of coal in power generation, and other uses of coal in environmentally acceptable processes. These three world areas have serious environmental problems, differing in extent and nature, but sufficiently close to create a working community for discussions. Beyond this, Czechoslovakia is emerging from the isolation imposed by control from Moscow. The need for each of these nations to meet and know one another was imperative. The environmental problems in Czechoslovakia are extensive and deep-seated. These proceedings contain 63 papers grouped into the following sections: The research university and its relationship with accrediting associations, government and private industry; Recent advances in coal utilization research; New methods of mining and reclamation; Coal-derived waste disposal and utilization; New applications of coal and environmental technologies; Mineral and trace elements in coal; Human and environmental impacts of coal production and utilization in the Silesian/Moravian region; and The interrelationships between fossil energy use and environmental objectives. Most papers have been processed separately for inclusion on the data base

EMSL Quarterly Highlights Report: 1st Quarter, Fiscal Year 2009

Energy Technology Data Exchange (ETDEWEB)

Showalter, Mary Ann; Kathmann, Loel E.; Manke, Kristin L.

2009-02-02

The EMSL Quarterly Highlights Report covers the science, staff and user recognition, and publication activities that occurred during the 1st quarter (October 2008 - December 2008) of Fiscal Year 2009.

Bench-scale testing of on-line control of column flotation using a novel analyzer. Third quarterly technical progress report, April 1, 1993--June 30, 1993

Energy Technology Data Exchange (ETDEWEB)

1993-08-24

This document contains the third quarterly technical progress report for PTI`s Bench-Scale Testing Project of a circuit integrating PTI`s KEN-FLOTETM Column Flotation Technology and PTI`s On-Line Quality Monitor and Control System. The twelve-month project involves installation and testing of a 200--300 lb/hr. bench-scale flotation circuit at PETC`s Coal Preparation Process Research Facility (CPPRF) for two bituminous coals (Upper Freeport and Pittsburgh No. 8 Seam Raw Coals). Figure 1 contains the project plan, as well as the approach to completing the major tasks within the twelve-month project schedule. The project is broken down into three phases, which include: Phase I -- Preparation: The preparation phase was performed principally at PTI`s Calumet offices from October through December, 1992. It involved building of the equipment and circuitry, as well as some preliminary design and equipment testing; Phase II -- ET Circuit Installation and Testing: This installation and testing phase of the project was performed at PETC`s CPPRF from January through June, 1993, and was the major focus of the project. It involved testing of the continuous 200--300 lb/hr. circuit; and Phase III -- Project Finalization: The project finalization phase is occurring from July through September, 1993, at PTI`s Calumet offices and involves finalizing analytical work and data evaluation, as well as final project reporting. This Third Quarterly Technical Progress Report principally summarizes the results from the benchscale testing with the second coal (Pittsburgh No. 8 Seam Coal), which occurred in April through June, 1993. It also contains preliminary economic evaluations that will go into the Final Report, as well as the plan for the final reporting task.

A comparison of hydrogen with alternate energy forms from coal and nuclear energy

International Nuclear Information System (INIS)

Cox, K.E.

1976-01-01

Alternate energy forms that can be produced from coal and nuclear energy have been analyzed on efficiency, economic and end-use grounds. These forms include hydrogen, methane, electricity, and EVA-ADAM, a 'chemical heat pipe' approach to energy transmission. The EVA-ADAM system for nuclear heat appears to be economically competitive with the other energy carriers except over very large distances. The cost of hydrogen derived from coal is approximately equal to that of methane derived from the same source when compared on an equal BTU basis. Thermochemically derived hydrogen from nuclear energy shows a break-even range with hydrogen derived from coal at coal costs of from Pound33 to 80/ton depending on the cost of nuclear heat. Electricity and electrolytically derived hydrogen are the most expensive energy carriers and electricity's use should be limited to applications involving work rather than heat. Continued work in thermochemical hydrogen production schemes should be supported as an energy option for the future. (author)

(Pittsburgh Energy Technology Center): Quarterly technical progress report for the period ending June 30, 1987. [Advanced Coal Research and Technology Development Programs

Energy Technology Data Exchange (ETDEWEB)

None

1988-02-01

Research programs on coal and coal liquefaction are presented. Topics discussed are: coal science, combustion, kinetics, surface science; advanced technology projects in liquefaction; two stage liquefaction and direct liquefaction; catalysts of liquefaction; Fischer-Tropsch synthesis and thermodynamics; alternative fuels utilization; coal preparation; biodegradation; advanced combustion technology; flue gas cleanup; environmental coordination, and technology transfer. Individual projects are processed separately for the data base. (CBS)

Short-term energy outlook. Quarterly projections, first quarter 1995

International Nuclear Information System (INIS)

1995-02-01

The Energy Information Administration (EIA) prepares quarterly, short-term energy supply, demand, and price projections for publication in February, May, August, and November in the Short-Term Energy Outlook (Outlook). The forecast period for this issue of the Outlook extends from the first quarter of 1995 through the fourth quarter of 1996. Values for the fourth quarter of 1994, however, are preliminary EIA estimates or are calculated from model simulations using the latest exogenous information available (for example, electricity sales and generation are simulated using actual weather data). The historical energy data, compiled into the first quarter 1995 version of the Short-Term Integrated Forecasting System (STIFS) database, are mostly EIA data regularly published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding. The STIFS database is archived quarterly and is available from the National Technical Information Service. The cases are produced using the Short-Term Integrated Forecasting System (STIFS). The STIFS model is driven principally by three sets of assumptions or inputs: estimates of key macroeconomic variables, world oil price assumptions, and assumptions about the severity of weather. Macroeconomic estimates are produced by DRI/McGraw-Hill but are adjusted by EIA to reflect EIA assumptions about the world price of crude oil, energy product prices, and other assumptions which may affect the macroeconomic outlook. The EIA model is available on computer tape from the National Technical Information Service

Combustion of coal gas fuels in a staged combustor

Science.gov (United States)

Rosfjord, T. J.; Mcvey, J. B.; Sederquist, R. A.; Schultz, D. F.

1982-01-01

Gaseous fuels produced from coal resources generally have heating values much lower than natural gas; the low heating value could result in unstable or inefficient combustion. Coal gas fuels may contain ammonia which if oxidized in an uncontrolled manner could result in unacceptable nitrogen oxide exhaust emission levels. Previous investigations indicate that staged, rich-lean combustion represents a desirable approach to achieve stable, efficient, low nitrogen oxide emission operation for coal-derived liquid fuels contaning up to 0.8-wt pct nitrogen. An experimental program was conducted to determine whether this fuel tolerance can be extended to include coal-derived gaseous fuels. The results of tests with three nitrogen-free fuels having heating values of 100, 250, and 350 Btu/scf and a 250 Btu/scf heating value doped to contain 0.7 pct ammonia are presented.

Fluid Dynamics of Pressurized, Entrained Coal Gasifiers