WorldWideScience

Sample records for coal drying techniques

  1. Dry piston coal feeder

    Science.gov (United States)

    Hathaway, Thomas J.; Bell, Jr., Harold S.

    1979-01-01

    This invention provides a solids feeder for feeding dry coal to a pressurized gasifier at elevated temperatures substantially without losing gas from the gasifier by providing a lock having a double-acting piston that feeds the coals into the gasifier, traps the gas from escaping, and expels the trapped gas back into the gasifier.

  2. Low-activity spectrometric gamma-ray logging technique for delineation of coal/rock interfaces in dry blast holes

    International Nuclear Information System (INIS)

    Asfahani, J.; Borsaru, M.

    2007-01-01

    A low-activity spectrometric gamma-ray logging technique is proposed in this paper as a sensitive tool for the delineation of coal/rock interfaces in dry blast holes. The advantages and superiority of this technique over traditional micro-density non-spectrometric gamma-ray tools are demonstrated

  3. Development of dry coal feeders

    Science.gov (United States)

    Bonin, J. H.; Cantey, D. E.; Daniel, A. D., Jr.; Meyer, J. W.

    1977-01-01

    Design and fabrication of equipment of feed coal into pressurized environments were investigated. Concepts were selected based on feeder system performance and economic projections. These systems include: two approaches using rotating components, a gas or steam driven ejector, and a modified standpipe feeder concept. Results of development testing of critical components, design procedures, and performance prediction techniques are reviewed.

  4. Inclined fluidized bed system for drying fine coal

    Science.gov (United States)

    Cha, Chang Y.; Merriam, Norman W.; Boysen, John E.

    1992-02-11

    Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

  5. Coal preparation and coal cleaning in the dry process; Kanshiki sentaku to coal cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, Z; Morikawa, M; Fujii, Y [Okayama University, Okayama (Japan). Faculty of Engineering

    1996-09-01

    Because the wet process has a problem such as waste water treatment, coal cleaning in the dry process was discussed. When a fluidized bed (using glass beads and calcium carbonate) is utilized instead of the heavy liquid, the fluidized bed will have apparent density as the liquid does, whereas the relative relationship therewith determines whether a substance having been put into the fluidized bed will float or sink. This is utilized for coals. In addition, two powder constituents of A and B may be wanted to be separated using the fluidized extraction process (similar to the liquid-liquid extraction process). In such a case, a fluidized bed in which both constituents are mixed is added with a third constituent C (which will not mix with A, but mix well with B), where the constituents are separated into A and (B + C), and the (B + C) constituent is separated further by using a sieve. If coal has the coal content mixed with ash content and pulverized, it turns into particle groups which have distributions in grain size and density. Groups having higher density may contain more ash, and those having lower density less ash. In addition, the ash content depends also on the grain size. The ash content may be classified by using simultaneously wind classification (for density and grain size) and a sieve (for grain size). This inference may be expanded to consideration of constructing a multi-stage fluidized bed classification tower. 12 figs., 5 tabs.

  6. Fluidized bed dry dense medium coal beneficiation

    CSIR Research Space (South Africa)

    North, Brian C

    2017-10-01

    Full Text Available medium beneficiation using a fluidized bed was investigated. Bed materials of sand, magnetite and ilmenite were used in a laboratory sized cylindrical fluidized bed. The materials were individually tested, as were mixes of sand and heavy minerals. Coal...

  7. EFFECT OF MICROWAVE DRYING ON THE GRINDABILITY OF LIGNITE COAL

    OpenAIRE

    Güngören, Can; Özkan, Şafak Gökhan; Hacıfazlıoğlu, Hasan

    2016-01-01

    In this study, the representative lignite coal samples supplied from Kastamonu-Tosya region were dried in a conventional drying oven and a microwave oven, and then they were ground by a laboratory rod mill. The particle size analyses of the ground samples at various grinding times (10, 20, 30, and 60 minutes) were carried out, and the results were compared. As a result, the d80 particle sizes of the samples, dried in the conventional drying oven, were determined as 350, 183, 180, and 100 µm a...

  8. Dry processing versus dense medium processing for preparing thermal coal

    CSIR Research Space (South Africa)

    De Korte, GJ

    2013-10-01

    Full Text Available of the final product. The separation efficiency of dry processes is, however, not nearly as good as that of dense medium and, as a result, it is difficult to effectively beneficiate coals with a high near-dense content. The product yield obtained from some raw...

  9. Nuclear techniques in coal and chemical industries

    International Nuclear Information System (INIS)

    Elbern, A.W.; Leal, C.A.

    1980-01-01

    The use of nuclear techniques for the determination of important parameters in industrial installations is exemplified; advantages of these techniques over other methods conventionally used are pointed out. The use of radiotracers in the study of physical and chemical phenomena occurring in the chemical industry is discussed. It is also shown that, using certain radioisotopes, it is possible to construct devices which enable, for example, the determination of the ash content in coal samples. These devices are economical and easy to be installed for the on-line control during coal transportation. (C.L.B.) [pt

  10. Albendazole Microparticles Prepared by Spray Drying Technique ...

    African Journals Online (AJOL)

    Purpose: To enhance the dissolution of albendazole (ABZ) using spray-drying technique. Method: ABZ binary mixtures with Kollicoat IR® (KL) and polyvinyl pyrrolidone (PVP) in various drug to polymer ratios (1: 1, 1: 2 and 1; 4) were prepared by spray-drying. The spray-dried particles were characterized for particle shape, ...

  11. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T. [Virginia Polytechnic Institute and State Univ., Blacksburg, VA (United States)

    1995-11-01

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both the ash and sulfur contents of run-of-mine coals. The extent of cleaning depends on the liberation characteristics of the coal, which generally improve with reducing particle size. however, since most of the advanced technologies are wet processes, the clean coal product must be dewatered before it can be transported and burned in conventional boilers. This additional treatment step significantly increases the processing cost and makes the industrial applicability of these advanced technologies much less attractive. In order to avoid problems associated with fine coal dewatering, researchers at the Pittsburgh Energy Technology Center (PETC) developed a novel triboelectrostatic separation (TES) process that can remove mineral matter from dry coal. In this technique, finely pulverized coal is brought into contact with a material (such as copper) having a work function intermediate to that of the carbonaceous material and associated mineral matter. Carbonaceous particles having a relatively low work function become positively charged, while particles of mineral matter having significantly higher work functions become negatively charged. once the particles become selectively charged, a separation can be achieved by passing the particle stream through an electrically charged field. Details related to the triboelectrostatic charging phenomenon have been discussed elsewhere (Inculet, 1984).

  12. Drying kinetics characteristic of Indonesia lignite coal (IBC) using lab scale fixed bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Kang, TaeJin; Jeon, DoMan; Namkung, Hueon; Jang, DongHa; Jeon, Youngshin; Kim, Hyungtaek [Ajou Univ., Suwon (Korea, Republic of). Div. of Energy Systems Research

    2013-07-01

    Recent instability of energy market arouse a lot of interest about coal which has a tremendous amount of proven coal reserves worldwide. South Korea hold the second rank by importing 80 million tons of coal in 2007 following by Japan. Among various coals, there is disused coal. It's called Low Rank Coal (LRC). Drying process has to be preceded before being utilized as power plant. In this study, drying kinetics of LRC is induced by using a fixed bed reactor. The drying kinetics was deduced from particle size, the inlet gas temperature, the drying time, the gas velocity, and the L/D ratio. The consideration on Reynold's number was taken for correction of gas velocity, particle size, and the L/D ratio was taken for correction packing height of coal. It can be found that active drying of free water and phase boundary reaction is suitable mechanism through the fixed bed reactor experiments.

  13. Possibilities of employing saliferous raw brown coal for technical fodder drying

    Energy Technology Data Exchange (ETDEWEB)

    Koerdel, P; Haeusler, W

    1978-09-01

    The successful utilization of saliferous brown coal is demonstrated with a sodium oxide content greater than 0.5% in dry substance, but with high calorific value (2300 to 3000 kcal/kg) for fodder drying (sugar beets and green fodder). Details of the fodder dryer and its performance, and combustion and drying parameters of 11 dryers using saliferous coal are presented. Hot air enters the dryer with temperatures between 300 and 800 C depending on the operation, and dries the fodder to 88-92% dry substance. Chemical analysis showed no significant increase in sulfur dioxide, hydrogen sulfide, chlorine, or sodium content in the dry fodder, which is recognized as safe to feed to ruminants. The substitution of ordinary brown coal by saliferous coal led to a savings of 4.000 Marks/kt coal in drying. (8 refs.) (In German)

  14. Atmospheric particulate emissions from dry abrasive blasting using coal slag

    Energy Technology Data Exchange (ETDEWEB)

    Bhaskar Kura; Kalpalatha Kambham; Sivaramakrishnan Sangameswaran; Sandhya Potana [University of New Orleans, New Orleans, LA (United States). Department of Civil and Environmental Engineering

    2006-08-15

    Coal slag is one of the widely used abrasives in dry abrasive blasting. Atmospheric emissions from this process include particulate matter (PM) and heavy metals, such as chromium, lead, manganese, nickel. Quantities and characteristics of PM emissions depend on abrasive characteristics and process parameters. Emission factors are key inputs to estimate emissions. Experiments were conducted to study the effect of blast pressure, abrasive feed rate, and initial surface contamination on total PM (TPM) emission factors for coal slag. Rusted and painted mild steel surfaces were used as base plates. Blasting was carried out in an enclosed chamber, and PM was collected from an exhaust duct using U.S. Environment Protection Agency source sampling methods for stationary sources. Results showed that there is significant effect of blast pressure, feed rate, and surface contamination on TPM emissions. Mathematical equations were developed to estimate emission factors in terms of mass of emissions per unit mass of abrasive used, as well as mass of emissions per unit of surface area cleaned. These equations will help industries in estimating PM emissions based on blast pressure and abrasive feed rate. In addition, emissions can be reduced by choosing optimum operating conditions. 40 refs., 5 figs., 2 tabs.

  15. Experimental investigations on drying behaviour of Bulgarian brown coal in steam fluidized bed

    International Nuclear Information System (INIS)

    Buschsieweke, F.; Koenig, J.

    1999-01-01

    The main targets were: to investigate the parameters for optimizing the drying process as steam pressure, fluidization velocity and particle size; to identify the cost of drying and combustion processes considering the necessity of milling the coal (raw or dried). Test series with Bulgarian brown coal from Maritsa-East has been made. Two fractions with different particle size was got: A from 0 to 1.6 mm (0.5 mm average) and B, resp. 1.6 to 6.3 (1.7 mm). The particle size is depending on the coal moisture. The fluidized bed process with the both fractions was performed at variations of the following parameters: steam velocity (0.07 to 1.7 m/s); raw coal feed rate (4 to 16 kg/h); raw moisture (18 to 43 wt %) and pressure (1.3 and 5 bar). Also the shrinking behaviour of the coal in different pore sizes was tested. Comparing pore size of the oven dried coal to the fluidized bed dried coal, significantly higher inner surface for the oven dried coal was established. To indicate the pore size of raw coal samples were made by freeze drying. Ice expanding should cause higher inner surface compared to oven drying method but no significant difference was established. A significant increase of heat transfer of the particles from A fraction (300 to 350 W/m 2 K0 compared to B (200 to 230 W/m 2 K) was determined. The heat transfer coefficient increased at increasing of the raw coal feed rate, mostly significant for A, due to higher particle contact. In conclusion: the particle convective mechanism is predominant for the heat transfer; development of pressurized fluidized bed drying is not of interest and the question about the total expenditure for crushing and milling remains open

  16. A Novel Environmental Route to Ambient Pressure Dried Thermal Insulating Silica Aerogel via Recycled Coal Gangue

    Directory of Open Access Journals (Sweden)

    Pinghua Zhu

    2016-01-01

    Full Text Available Coal gangue, one of the main hazardous emissions of purifying coal from coalmine industry, is rich in silica and alumina. However, the recycling of the waste is normally restricted by less efficient techniques and low attractive output; the utilization of such waste is still staying lower than 15%. In this work, the silica aerogel materials were synthesized by using a precursor extracted from recycled silicon-rich coal gangue, followed by a single-step surface silylation and ambient pressure drying. A low density (~0.19 g/cm3 nanostructured aerogel with a 3D open porous microstructure and high surface area (~690 m2/g was synthesized, which presents a superior thermal insulation performance (~26.5 mW·m−1·K−1 of a plane packed of 4-5 mm granules which was confirmed by transient hot-wire method. This study offers a new facile route to the synthesis of insulating aerogel material by recycling solid waste coal gangue and presents a potential cost reduction of industrial production of silica aerogels.

  17. Development of a dry-feed system for a coal-fired gas turbine

    Energy Technology Data Exchange (ETDEWEB)

    Rothrock, J.W. Jr.; Smith, C.F.

    1993-11-01

    The objective of the reported of the reported work is to develop a dry coal feed system that provides smooth, controllable flow of coal solids into the high pressure combustor of the engine and all test rigs. The system must start quickly and easily, run continuously with automatic transfer of coal from low pressure hoppers to the high pressure delivery system, and offer at least a 3:1 smooth turn-down ratio. cost of the equipment must be minimized to maintain the economic attractiveness of the whole system. Before the current contract started some work was done with dry powder coal. For safety and convenience reasons, coal water slurry was selected as the fuel for all work on the program. Much of the experimental work, including running the Allison 501-KM engine was done with coal slurry. Recent economic analysis led to a change to powdered coal.

  18. Survey on development of brown coal liquefaction techniques; Kattan ekika gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-09-01

    Described herein are results of literature survey on brown coal liquefaction reactions and elementary techniques. Liquefaction of brown coal in the presence of CO and steam, or CO, H{sub 2} and steam has been investigated. It is not clear by the literature survey whether it is superior to the normal process which uses hydrogen. Brown coal contains moisture at high contents, and the drying techniques are necessary to be developed for its liquefaction. The future coal liquefaction plant will be much larger than the past one, and there are a number of problems to be solved, such as those involved in the designs of large-sized high-pressure slurry pumps, heat exchangers and preheaters. It is also necessary to develop the materials of and production techniques for large reactors which are serviceable under severe conditions. The solid-liquid separation for liquefaction products involves a number of the elementary techniques characteristic of coal liquefaction processes, and needs many technological developments. The one-stage brown coal liquefaction process is compared with the two-stage process for the secondary hydrogenation of SCR, but no clear conclusions are reached. (NEDO)

  19. Study on coal dust wettability measurement using cold briquetting technique

    Energy Technology Data Exchange (ETDEWEB)

    Li, M.; Xu, H.; Shu, X. [North China Institute of Science and Technology, Beijing (China). Department of Resource and Environmental Engineering

    2008-12-15

    Quantitative measuring of coal dust wettability is essential for the research and development of chemical coal dust suppressants in the field of dust control with wetting-agent-added water. The causes of low repeat rate and poor consistency in present lab testing of coal dust wettability are discussed. The influence of different briquetting pressure (from 0 to 6.5108 Pa) on the wet behavior of coal dust is investigated as a new way to quantitatively evaluate coal dust wettability. The study shows that there is a fairly high coincidence between the coal dust wettability data measured by the briquetting technique and the results gained from the lab dust suppression tests using an MCYZ apparatus designed by the authors. 9 refs., 8 figs., 2 tabs.

  20. Evaluation of alternative drying techniques for the earthworm flour processing

    Directory of Open Access Journals (Sweden)

    Laura Suárez Hernández

    2016-01-01

    Full Text Available Production of earthworm flour includes several steps, among which the most critical is the drying process due to factors such as time and energ y requirements. In addition, the information available about this process is relquite limited. Thus, this work evaluated four drying techniques likely to be implemented by lombricultores: sun drying, oven drying, drying tunnel and microwave assisted drying. Drying kinetics values were obtained for all drying techniques, and specific parameters as the following were evaluated: drying tray material (stainless and ceramic steel for sun drying, microwave power (30 %, 50 % and 80 % and amount of material to be dried (72 and 100 g for microwave assisted drying, temperature (50, 65, 90 and 100 °C for oven drying, and temperature (50 and 63 °C and air speed (2.9 to 3.6 m/s for tunnel drying. It was determined that the most efficient technique is the drying tunnel, because this allows the combination of heat transfer by conduction and convection, and enables controlling the operating parameters. Finally, nutritional analyzes were performed in samples obtained by each drying technique evaluated. The crude protein content for sun drying, microwave assisted drying, oven drying and tunnel drying were 66.36 %, 67.91 %, 60.35 % and 62.33 % respectively, indicating that the drying method and operating parameters do not significantly affect the crude protein content.

  1. Chromatographic methods and techniques used in studies of coals, their progenitors and coal-derived materials

    Energy Technology Data Exchange (ETDEWEB)

    Zubkova, Valentina [Jan Kochanowski University of Humanities and Sciences, Institute of Chemistry, Kielce (Poland)

    2011-03-15

    The use of chromatography in studies of coals, their progenitors and coal-related products was reviewed. The specificity of the coal structure was discussed. The use of extraction in preparing study samples was discussed paying special attention to the occurrence of undesirable phenomena such as aggregation of coal derivate molecules, resulting from the formation of their dimers and trimers, and degradation of polar solvents at temperatures above 350 C. The following ways of fractionating samples of coal materials were considered: thermal, solvent, column with the use of preparative size exclusive chromatography and preparative thin layer chromatography as well as membrane separation. The use of chromatography coupled with experimental techniques such as mass spectrometry, infrared spectroscopy, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and pyrolysis was analysed. (orig.)

  2. Nuclear assay of coal. Volume 4. Moisture determination in coal: survey of electromagnetic techniques. Final report

    International Nuclear Information System (INIS)

    Bevan, R.; Luckie, P.; Gozani, T.; Brown, D.R.; Bozorgmanesh, H.; Elias, E.

    1979-01-01

    This survey consists of two basic parts. The first consists of a survey of various non-nuclear moisture determination techniques. Three techniques are identified as promising for eventual on-line application with coal; these are the capacitance, microwave attenuation, and nuclear magnetic resonance (NMR) techniques. The second part is devoted to an in-depth analysis of these three techniques and the current extent to which they have been applied to coal. With a given coal type, accuracies of +- 1% absolute in moisture content are achievable with all three techniques. The accuracy of the two electromagnetic techniques has been demonstrated in the laboratory and on-line in coal burning plants, whereas only small samples have been analyzed with NMR. The current shortcoming of the simple electromagnetic techniques is the sensitivity of calibrations to physical parameters and coal type. NMR is currently limited by small sample sizes and non-rugged design. These findings are summarized and a list of manufacturers of moisture analyzers is given in the Appendix

  3. Effects of drying methods on the low temperature reactivity of Victorian brown coal to oxygen

    Energy Technology Data Exchange (ETDEWEB)

    Unal, S.; Wood, D.G.; Harris, I.J. (University of Marmara, Istanbul (Turkey). Ataturk Faculty of Education, Division of Science Education)

    1992-02-01

    The effects of air drying and thermal dewatering on the low temperature oxygen reactivity of Victorian brown coal have been investigated in the temperature range 35-55{degree}C and at 100 kPa oxygen pressure using coal samples ground to {lt} 100 mesh. An attempt has also been made to relate the low temperature oxygen reactivity of the coal to its free radical concentration as measured prior to oxidation. Two rate models, the Schmidt and Winmill models, have been adapted to include the initial free radical concentration of the coal samples as the drying method sensitivity parameter in lieu of the concentration of oxygen-reactive sites in the coal material. The experimental results show that air drying, which reduces the free radical concentration of the coal, causes a decline in its oxygen reactivity whereas thermal dewatering, which causes an increase in the free radical concentration of the coal, enhances its oxygen reactivity. Air drying does not affect the distribution of the consumed oxygen in the oxidation products. A difference is observed in the case of the thermally dewatered coal samples. The correlation of the two rate models adopted is considered equally satisfactory. However, only the values obtained for the two activation energies in the Winmill model reflect the changes caused by thermal dewatering in the oxidation pattern of the coal. The activation energy values obtained from the two models are within the range of those quoted in the literature for the abstraction of hydrogen from various arene structures by free radicals. 35 refs., 10 figs., 8 tabs.

  4. Nigerian coal analysis by PIXE and HEBS techniques

    International Nuclear Information System (INIS)

    Olabanji, S.O.

    1989-05-01

    PIXE and HEBS techniques were employed for the measurement of the concentrations of the major, minor and trace elements in Nigerian coal samples from a major deposit. The samples were irradiated with 2.55 MeV protons from the 3 MeV tandem accelerator (NEC 3 UDH) in Lund. The PIXE results are reported and compared with an earlier work on Nigerian coal using FNAA and INAA analytical techniques while the HEBS results are compared with ASTM previous results. The results corroborate the assertion that Nigerian coals are of weak and noncoking grades with low sulphur (0.82-0.99%) and relatively high hydrogen (4.49-5.16%) contents. The motivation for this work is partly due to the projected usage of coal as metallurgical feedstocks and as fuel, and partly because of the genuine concern about the concomitant environmental effects of the increased burning of coal. The knowledge of the concentration of all elements is important for the characterization of coal and the determination and control of its products. Economic parameters such as the ash contents and calorific values are associated with the concentrations of coal's constituents. (author). 11 refs, 1 fig., 4 tabs

  5. Technique of solar drying the linden

    International Nuclear Information System (INIS)

    Fonseca Fonseca, Susana; Andión Torres, Ronald; Espinosa Borges, Ruberlando; Torres Ten, Alonso; Arzuaga Machado, Yusnel; Fuentes lombá, Osmay

    2017-01-01

    In Santiago of Cuba exists interest in the utilization of medicinal plants for the manufacture of flowed abstract and Tinturas, and this requires the dry product. At the present time this process is done in houses roofed. This product will be dried at 10 or 12 days. Having in account than in the Center of investigation of Solar Energy was developed a prototype of solar drier, which enables the drying of the anamu with the required quality, in this work is done a study, for the utilization of the aforementioned drier, for the drying of others medicinal plants. It is determine and evaluated experimentally a Procedure of drying of linden in this solar drier. The dry plants were sent to the UBPC La Rosita of medicinal plants, which manifested conformity with the obtained results, showing contentment with the quality of the dry product. (author)

  6. Dry cooling for coal fired power plants: the new state-of-the-art

    Energy Technology Data Exchange (ETDEWEB)

    Souvenir, C.; Nagel, P. [SPX Cooling Technologies (Belgium)

    2008-07-01

    In the first part of this paper an update is provided regarding the use of dry cooling in power plants. The evolution of the reasons leading to this technical solution, the trends in the market place, and the growth over the last 15 years are described. In the second part, the use of current advanced dry cooling technologies for coal-fired plants in China is illustrated. 34 figs.

  7. Application of dry separative methods for decreasing content the residues unburned coal and separation Fe from black coal flies ash

    Directory of Open Access Journals (Sweden)

    František Kaľavský

    2008-06-01

    Full Text Available Main obstacle using of fly ashes in building, that is its main consumer, is the residue of unburned coal; it is expressed of loss onignition - LOI. In present, the valid STN and EU standard limits the content of LOI to 3 – 5 %, in national conditions maximum 7 %.Application of processing technologies also has to assure utilization of fly ash that provides a possibility of complex utilizationof individual products obtained by modification.By means of corona separation, based on different conductivity of individual fly ash elements, it is possible to separate unburnedcoal particles. The fly ash sample from black coal burning in melting boiler that was deposited on fly ash deposit, content of LOIof dielectric particle 6,45 % at 61 % weight yield was achieved. In the samples taken from dry taking of fly ash the non-conductingproduct contained 7,72 % of LOI at 73 % of weight yield.

  8. Novel technique for coal pyrolysis and hydrogenation production analysis

    Energy Technology Data Exchange (ETDEWEB)

    Pfefferle, L.D.

    1990-01-01

    The overall objective of this study is to establish vacuum ultraviolet photoionization-MS and VUV pulsed EI-MS as useful tools for a simpler and more accurate direct mass spectrometric measurement of a broad range of hydrocarbon compounds in complex mixtures for ultimate application to the study of the kinetics of coal hydrogenation and pyrolysis processes. The VUV-MS technique allows ionization of a broad range of species with minimal fragmentation. Many compounds of interest can be detected with the 118 nm wavelength, but additional compound selectivity is achievable by tuning the wavelength of the photo-ionization source in the VUV. Resonant four wave mixing techniques in Hg vapor will allow near continuous tuning from about 126 to 106 nm. This technique would facilitate the scientific investigation of coal upgrading processes such as pyrolysis and hydrogenation by allowing accurate direct analysis of both stable and intermediate reaction products.

  9. Burnout prediction using advance image analysis coal characterization techniques

    Energy Technology Data Exchange (ETDEWEB)

    Edward Lester; Dave Watts; Michael Cloke [University of Nottingham, Nottingham (United Kingdom). School of Chemical Environmental and Mining Engineering

    2003-07-01

    The link between petrographic composition and burnout has been investigated previously by the authors. However, these predictions were based on 'bulk' properties of the coal, including the proportion of each maceral or the reflectance of the macerals in the whole sample. Combustion studies relating burnout with microlithotype analysis, or similar, remain less common partly because the technique is more complex than maceral analysis. Despite this, it is likely that any burnout prediction based on petrographic characteristics will become more accurate if it includes information about the maceral associations and the size of each particle. Chars from 13 coals, 106-125 micron size fractions, were prepared using a Drop Tube Furnace (DTF) at 1300{degree}C and 200 millisecond and 1% Oxygen. These chars were then refired in the DTF at 1300{degree}C 5% oxygen and residence times of 200, 400 and 600 milliseconds. The progressive burnout of each char was compared with the characteristics of the initial coals. This paper presents an extension of previous studies in that it relates combustion behaviour to coals that have been characterized on a particle by particle basis using advanced image analysis techniques. 13 refs., 7 figs.

  10. Overview Of Dry-Etch Techniques

    Science.gov (United States)

    Salzer, John M.

    1986-08-01

    With pattern dimensions shrinking, dry methods of etching providing controllable degrees of anisotropy become a necessity. A number of different configurations of equipment - inline, hex, planar, barrel - have been offered, and within each type, there are numerous significant variations. Further, each specific type of machine must be perfected over a complex, interactive parameter space to achieve suitable removal of various materials. Among the most critical system parameters are the choice of cathode or anode to hold the wafers, the chamber pressure, the plasma excitation frequency, and the electrode and magnetron structures. Recent trends include the use of vacuum load locks, multiple chambers, multiple electrodes, downstream etching or stripping, and multistep processes. A major percentage of etches in production handle the three materials: polysilicon, oxide and aluminum. Recent process developments have targeted refractory metals, their silicides, and with increasing emphasis, silicon trenching. Indeed, with new VLSI structures, silicon trenching has become the process of greatest interest. For stripping, dry processes provide advantages other than anisotropy. Here, too, new configurations and methods have been introduced recently. While wet processes are less than desirable from a number of viewpoints (handling, safety, disposal, venting, classes of clean room, automatability), dry methods are still being perfected as a direct, universal replacement. The paper will give an overview of these machine structures and process solutions, together with examples of interest. These findings and the trends discussed are based on semiannual survey of manufacturers and users of the various types of equipment.

  11. Studies on coal flotation in flotation column using statistical technique

    Energy Technology Data Exchange (ETDEWEB)

    M.S. Jena; S.K. Biswal; K.K. Rao; P.S.R. Reddy [Institute of Minerals & Materials Technology (IMMT), Orissa (India)

    2009-07-01

    Flotation of Indian high ash coking coal fines to obtain clean coal has been reported earlier by many authors. Here an attempt has been made to systematically analyse factors influencing the flotation process using statistical design of experiments technique. Studies carried out in a 100 mm diameter column using factorial design to establish weightage of factors such as feed rate, air rate and collector dosage indicated that all three parameters have equal influence on the flotation process. Subsequently RSM-CCD design was used to obtain best result and it is observed that 94% combustibles can be recovered with 82.5% weight recovery at 21.4% ash from a feed containing 31.3% ash content.

  12. VLF surface-impedance modelling techniques for coal exploration

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, G.; Thiel, D.; O' Keefe, S. [Central Queensland University, Rockhampton, Qld. (Australia). Faculty of Engineering and Physical Systems

    2000-10-01

    New and efficient computational techniques are required for geophysical investigations of coal. This will allow automated inverse analysis procedures to be used for interpretation of field data. In this paper, a number of methods of modelling electromagnetic surface impedance measurements are reviewed, particularly as applied to typical coal seam geology found in the Bowen Basin. At present, the Impedance method and the finite-difference time-domain (FDTD) method appear to offer viable solutions although both have problems. The Impedance method is currently slightly inaccurate, and the FDTD method has large computational demands. In this paper both methods are described and results are presented for a number of geological targets. 17 refs., 14 figs.

  13. Dried fruit breadfruit slices by Refractive Window™ technique

    Directory of Open Access Journals (Sweden)

    Diego F. Tirado

    2016-01-01

    Full Text Available A large amount of products are dried due several reasons as preservation, weight reduction and improvement of stability. However, on the market are not offered low-cost and high quality products simultaneously. Although there are effective methods of dehydrating foods such as freeze drying, which preserves the flavor, color and vitamins, they are poor accessibility technologies. Therefore, alternative processes are required to be efficient and economical. The aim of this research was compare drying kinetics of sliced of breadfruit (Artocarpus communis using the technique of Refractive Window® (VR with the tray drying. To carry out this study, sliced of 1 and 2 mm thick were used. Refractive window drying was performed with the water bath temperature to 92 °C; and tray drying at 62 °C and an air velocity of 0.52 m/s. During the Refractive window drying technique, the moisture content reached the lower than tray drying levels. Similarly it happened with samples of 1 mm, which, having a smaller diameter reached lower moisture levels than samples 2 mm. The higher diffusivities were obtained during drying sliced VR 1 and 2 mm with coefficients of 6.13 and 3.90*10-9 m2/s respectively.

  14. Dry boxes and inert atmosphere techniques

    International Nuclear Information System (INIS)

    Bartak, D.E.

    1987-01-01

    Practitioners need to conduct experiments with molten salts in an inert atmosphere owing to the chemical reactivity of these media. Most fused salt solvent systems show reactivity to water and/or oxygen, which results in significant chemical changes in the properties of these solvents. Although several studies on the nature of an oxygen/oxide electrode in this melt have been reported, the reactions have not been fully understood because of apparent water contamination in many cases. Nitrate melt systems are also hygroscopic; for example, the LiNO 3 -KNO 3 eutectic (177 0 C) absorbs water to at least 0.2% by weight. The result is that the electrochemistry of heavier, electropositive metal ions has been significantly altered. In addition, trace amounts of water have been shown to significantly affect the oxygen-oxide redox chemistry in NaNO 3 -KNO 3 melts (250 0 C). The haloaluminates, which include AlCl 3 -NaCl (175 0 C), as well as AlCl 3 -organic salt binaries are particularly sensitive to the presence of both oxygen and moisture. Oxygen is a strong oxidant in the fused hydroxide systems with formation of superoxide ion from either oxide or water. This chapter describes general, inert atmosphere techniques which can be used by the molten salt experimentalist. Because of the limitations of volatility, vacuum manipulations are not considered. Rather, the use of glove boxes, glove bags, and inert bench-top techniques are discussed. The areas covered are: glove box and bag equipment, operation and maintenance of glove boxes and glove bags, and common operations conducted inside glove boxes

  15. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    Energy Technology Data Exchange (ETDEWEB)

    R.H. Yoon; G.H. Luttrell; E.S. Yan; A.D. Walters

    2001-04-30

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both ash- and sulfur-forming minerals from coal. However, most of the processes involve fine grinding and use water as the cleaning medium; therefore, the clean coal products must be dewatered before they can be transported and burned. Unfortunately, dewatering fine coal is costly, which makes it difficult to deploy advanced coal cleaning processes for commercial applications. As a means of avoiding problems associated with the fine coal dewatering, the National Energy Technology Laboratory (NETL) developed a dry coal cleaning process in which mineral matter is separated from coal without using water. In this process, pulverized coal is subjected to triboelectrification before being placed in an electric field for electrostatic separation. The triboelectrification is accomplished by passing a pulverized coal through an in-line mixer made of copper. Copper has a work function that lies between that of carbonaceous material (coal) and mineral matter. Thus, coal particles impinging on the copper wall lose electrons to the metal thereby acquiring positive charges, while mineral matter impinging on the wall gain electrons to acquire negative charges. The charged particles then pass through an electric field where they are separated according to their charges into two or more products depending on the configuration of the separator. The results obtained at NETL showed that it is capable of removing more than 90% of the pyritic sulfur and 70% of the ash-forming minerals from a number of eastern U.S. coals. However, the BTU recoveries were less than desirable. The laboratory-scale batch triboelectrostatic separator (TES) used by NETL relied on adhering charged particles on parallel electrode surfaces and scraping them off. Therefore, its throughput will be proportional to the electrode surface area. If this laboratory device is scaled-up as is, it would

  16. New approach for dry formulation techniques for rhizobacteria

    Science.gov (United States)

    Elchin, A. A.; Mashinistova, A. V.; Gorbunova, N. V.; Muratov, V. S.; Kydralieva, K. A.; Jorobekova, Sh. J.

    2009-04-01

    Two beneficial Pseudomonas isolates selected from rhizosphere of abundant weed - couch-grass Elytrigia repens L. Nevski have been found to have biocontrol activity. An adequate biocontrol effect requires high yield and long stability of the bacterial preparation [1], which could be achieved by an effective and stable formulation. This study was aimed to test various approaches to dry formulation techniques for Pseudomonas- based preparations. To reach this goal, two drying formulation techniques have been tested: the first one, spray drying and the second, low-temperature contact-convective drying in fluidized bed. The optimal temperature parameters for each technique were estimated. Main merits of the selected approach to dry technique are high yield, moderate specific energy expenditures per 1 kg of evaporated moisture, minimal time of contact of the drying product with drying agent. The technological process for dry formulation included the following stages: the obtaining of cell liquids, the low-temperature concentrating and the subsequent drying of a concentrate. The preliminary technological stages consist in cultivation of the rhizobacteria cultures and concentrating the cell liquids. The following requirements for cultivation regime in laboratory conditions were proposed: optimal temperatures are 26-28°С in 3 days, concentration of viable cells in cell liquid makes 1010-1011 cell/g of absolutely dry substance (ADS). For concentrating the cell liquids the method of a vacuum evaporation, which preserves both rhizobacteria cells and the secondary metabolites of cell liquid, has been used. The process of concentrating was conducted at the minimum possible temperature, i.e. not above 30-33°С. In this case the concentration of viable cells has decreased up to 109-1010 cell/g of ADS. For spray drying the laboratory up-dated drier BUCHI 190, intended for the drying of thermolabile products, was used. The temperatures of an in- and outcoming air did not exceed

  17. Novel technique for coal pyrolysis and hydrogenation product analysis

    Energy Technology Data Exchange (ETDEWEB)

    Pfefferle, L.D.; Boyle, J.

    1993-03-15

    A microjet reactor coupled to a VUV photoionization time-of-flight mass spectrometer has been used to obtain species measurements during high temperature pyrolysis and oxidation of a wide range of hydrocarbon compounds ranging from allene and acetylene to cyclohexane, benzene and toluene. Initial work focused on calibration of the technique, optimization of ion collection and detection and characterization of limitations. Using the optimized technique with 118 nm photoionization, intermediate species profiles were obtained for analysis of the hydrocarbon pyrolysis and oxidation mechanisms. The soft'' ionization, yielding predominantly molecular ions, allowed the study of reaction pathways in these high temperature systems where both sampling and detection challenges are severe. Work has focused on the pyrolysis and oxidative pyrolysis of aliphatic and aromatic hydrocarbon mixtures representative of coal pyrolysis and hydropyrolysis products. The detailed mass spectra obtained during pyrolysis and oxidation of hydrocarbon mixtures is especially important because of the complex nature of the product mixture even at short residence times and low primary reactant conversions. The combustion community has advanced detailed modeling of pyrolysis and oxidation to the C4 hydrocarbon level but in general above that size uncertainties in rate constant and thermodynamic data do not allow us to a priori predict products from mixed hydrocarbon pyrolyses using a detailed chemistry model. For pyrolysis of mixtures of coal-derived liquid fractions with a large range of compound structures and molecular weights in the hundreds of amu the modeling challenge is severe. Lumped models are possible from stable product data.

  18. Environmental assessment of coal waste mounds in Japan using remote sensing techniques

    Energy Technology Data Exchange (ETDEWEB)

    Lewis, A J; Gotoh, K; Aoyama, K; Aoki, S [Louisiana State University, Baton Rouge, LA (United States). Department of Geography and Anthropology

    1993-01-01

    Focuses on the application of remote sensing techniques to the study of coal waste mounds. The situation at the coal waste mounds in Fukuoka, Japan is cited. Guidelines on film parameters, photographic keys and tasks required to inventory, monitor and manage coal waste mounds in Japan are addressed. Application of photogrammetry, remote sensing, aerial photography and satellite imagery techniques in monitoring spoil banks is reviewed. Applicability of the techniques is discussed. 24 refs.

  19. Application status of on-line nuclear techniques in analysis of coal quality

    International Nuclear Information System (INIS)

    Cai Shaohui

    1993-01-01

    Nuclear techniques are favourable for continuous on-line analysis, because they are fast, non-intrusive. They can be used in the adverse circumstances in coal industry. The paper reviews the application status of on-line nuclear techniques in analysis of coal quality and economic benefits derived from such techniques in developed countries

  20. Novel technique for coal pyrolysis and hydrogenation product analysis

    Energy Technology Data Exchange (ETDEWEB)

    Pfefferle, L.D.

    1992-01-01

    This report covers the last quarter of the last year of the three-year grant period. In the final project year, we concentrated on the pyrolysis and oxidative pyrolysis of large hydrocarbons and mixtures of large and small hydrocarbons in order to develop the VUV-MS technique for compounds more representative of those in coal pyrolysis applications. Special focus was directed at the pyrolysis and oxidative pyrolysis of benzene and benzene acetylene mixtures. The acetylene/benzene mixtures were used to gain a better understanding of the mechanisms of molecular growth in such systems specifically to look at the kinetics of aryl-aryl reactions as opposed to small molecule addition to phenyl radicals. Sarofim and coworkers at MIT have recently demonstrated the importance of these reactions in coal processing environments. In the past, the growth mechanism for the formation of midsized PAH has been postulated to involve primarily successive acetylene additions to phenyl-type radicals, our work confmns this as an important mechanism especially for smaller PAH but also investigates conditions where biaryl formation can play an important role in higher hydrocarbon formation.

  1. Uranium content of coal ashes from Southern Brazil coal fueled power stations, by the fission track registration technique

    International Nuclear Information System (INIS)

    Morales, R.K.

    1981-01-01

    The feasibility of the application of the fission track registration technique for the determination of uranium in coal ashes was shown. The wet method was employed using as detector the Makrofol KG=10 μm, manufactured by Bayer. The coal ashes were originated from coal-fueled power stations localized in Southern Brazil. The results obtained ranged from 10 to 27 mg U/kg. Since the total error variation was from 18,4% to 23,8%, the method used was considered excellent. The determination of the uranium content in coal ashes is of considerable interest in environmental control in power stations, in their vicinity and wherever these ashes are used or stored. The technique used is the work proved to be very appropriate for the purpose aimed at. (Author) [pt

  2. Development of a Temperature Programmed Identification Technique to Characterize the Organic Sulphur Functional Groups in Coal

    Directory of Open Access Journals (Sweden)

    Moinuddin Ghauri

    2017-06-01

    Full Text Available The Temperature Programmed Reduction (TPR technique is employed for the characterisation of various organic sulphur functional groups in coal. The TPR technique is modified into the Temperature Programmed Identification technique to investigate whether this method can detect various functional groups corresponding to their reduction temperatures. Ollerton, Harworth, Silverdale, Prince of Wales coal and Mequinenza lignite were chosen for this study. High pressure oxydesulphurisation of the coal samples was also done. The characterization of various organic sulphur functional groups present in untreated and treated coal by the TPR method and later by the TPI method confirmed that these methods can identify the organic sulphur groups in coal and that the results based on total sulphur are comparable with those provided by standard analytical techniques. The analysis of the untreated and treated coal samples showed that the structural changes in the organic sulphur matrix due to a reaction can be determined.

  3. Nuclear techniques in the coal industry. Proceedings of a final research co-ordination meeting

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    With the aim of promoting advanced research and facilitating a more extensive application of nuclear techniques for environmental protection in the exploration and exploitation of coal, the IAEA established the present co-ordinated research programme (CRP) in 1989. This report includes an assessment of the current status and trends in nuclear techniques in the coal industry and the results obtained by the participants at the CRP. Proceedings of the final CRP on ``Nuclear Techniques in Exploration and Exploitation of Coal: On-line and Bulk Analysis and Evaluation of Potential Environmental Pollutants in Coal and Coke``, was held in Krakow, Poland, from 9 to 12 May 1994. Refs, figs, tabs.

  4. Process and apparatus to dry and to preheat coal or coal mixtures and the subsequent coking by the use of non- or weakly baking bituminous coals and/or carbon sources. Verfahren und Vorrichtung zur Trocknung bzw. Vorerhitzung von Kohle oder Kohlemischungen und anschliessender Verkokung unter Verwendung nicht oder nur schwachbackender Steinkohlen und/oder Kohlenstofftraegern

    Energy Technology Data Exchange (ETDEWEB)

    Echterhoff, J.; Frick, H.; Schaper, A.; Mohmeyer, H.

    1982-03-25

    A process and an apparatus for the drying and the subsequent coking of non- or weakly baking bituminous coals is described. The coal is compressed by stamping. For preventing the oxidation of the coal grain the coal is kept in contact with an inert medium on the entire path to the coke oven. Water vapor from the coal drying is used as the inert medium.

  5. Analysis of the use of waste heat obtained from coal-fired units in Organic Rankine Cycles and for brown coal drying

    International Nuclear Information System (INIS)

    Łukowicz, Henryk; Kochaniewicz, Andrzej

    2012-01-01

    The ever-increasing restrictions on greenhouse gas emissions have created a need for new energy technologies. One way to meet these new requirements is to optimise the efficiency of power units. This paper presents two energy technologies that, if used, will increase the efficiency of electricity generation. One of the most effective ways to improve the efficiency of brown coal-fired units is by drying the coal that is fed into the boiler. Here, we describe a technology that uses the waste heat obtained from exhaust gases. This paper also presents an analysis of the feasibility of and potential for using waste heat obtained from exhaust gases to feed Organic Rankine Cycles (ORCs). Several low-temperature working fluids were considered, which were selected based on properties that were best suited for these types of cycles. The impact of these working fluids on the efficiency and capacity of the ORC was also examined. The calculations for ORCs fed with waste heat obtained from exhaust gases from hard coal- and brown coal-fired boilers were compared. -- Highlights: ► We describe a technology that uses the waste heat obtained from exhaust gases. ► The impact of using different working fluids with a low boiling point is examined. ► We describe integrating the ORC with the power unit. ► The use of waste heat from boiler exhaust gases to dry brown coal is proposed. ► We demonstrate a possible increase in power unit efficiency.

  6. Exploring Oven-drying Technique in Producing Pineapple Powder

    OpenAIRE

    Cyril John A. Domingo; Wilma M. De Vera; Raquel C. Pambid

    2017-01-01

    Pineapple puree and juice of 11 to 12 °Brix were used to obtain pineapple powder using oven-drying technique. Addition of maltodextrin in treatments 2 and 4 yielded good quality powder, however addition of sugar and maltodextrin in treatments 1 and 3 resulted to sticky product which was processed to pineapple leather. Treatment 2 composed of pineapple puree and maltodextrin resulted to significantly higher powder recovery compared with treatment 4 which composed of pineapple juice...

  7. POC-scale testing of an advanced fine coal dewatering equipment/technique

    Energy Technology Data Exchange (ETDEWEB)

    Groppo, J.G.; Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Rawls, P. [Department of Energy, Pittsburgh, PA (United States)

    1995-11-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. As the contract title suggests, the main focus of the program is on proof-of-concept testing of a dewatering technique for a fine clean coal product. The coal industry is reluctant to use the advanced fine coal recovery technology due to the non-availability of an economical dewatering process. in fact, in a recent survey conducted by U.S. DOE and Battelle, dewatering of fine clean coal was identified as the number one priority for the coal industry. This project will attempt to demonstrate an efficient and economic fine clean coal slurry dewatering process.

  8. Development of the dry decontamination technique using plasma

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Yong Soo; Seo, Yong Dae; Lee, Dong Uk; Jeon, Sang Hwan; Jung, Young Suk [Hanyang University, Seoul (Korea)

    2001-04-01

    In order to develop an advanced dry decontamination method, dry decontamination technique using gaseous plasma is studied. Scopes of the research are 1) literature survey and case studies of the international R and D activities and industrial application, 2) contaminant characteristics analysis, 3) feasibility and applicability study of the unit techniques, 4) process development study on the plasma decontamination, 5) plasma diagnostics and quantitative analysis by QMS and OES, and 6) design of (microwave) plasma torch system. The major research results are as belows. The maximum etching rate of UO{sub 2} is achieved to be 0.8 {mu}m/min. under 300 deg C, 150 W CF{sub 4}/O{sub 2}/N{sub 2} r.f. plasma maintaining the optimum ratio of CF{sub 4}/O{sub 2} of four, and that of Co and Mo is 0.06 {mu}m/min. and 1.9 {mu}m/min., respectively, under 380 deg C, 220 W CF{sub 4}/O{sub 2} r.f. plasma. The optimum process for the dry decontamination of TRU, CP, and or FP nuclides, therefore, requires the optimum gas composition above 350 deg C and 220W power. It is also demonstrated that this optimum process can be extrapolated to atmospheric high power torch system. In conclusion, if plasma power and temperature increases with maintaining the optimum gas composition, this dry decontamination techniques must be definitely effective and efficient. 17 refs., 62 figs., 4 tabs. (Author)

  9. Exploring Oven-drying Technique in Producing Pineapple Powder

    Directory of Open Access Journals (Sweden)

    Cyril John A. Domingo

    2017-11-01

    Full Text Available Pineapple puree and juice of 11 to 12 °Brix were used to obtain pineapple powder using oven-drying technique. Addition of maltodextrin in treatments 2 and 4 yielded good quality powder, however addition of sugar and maltodextrin in treatments 1 and 3 resulted to sticky product which was processed to pineapple leather. Treatment 2 composed of pineapple puree and maltodextrin resulted to significantly higher powder recovery compared with treatment 4 which composed of pineapple juice and maltodextrin. The solubility of pineapple powder improved as maltodextrin concentration is increased from 40.00 % to 60.00 %.Addition of maltodextrin also reduced stickiness of the final product. An instant pineapple powder of 5.47 and 5.33 % moisture content could be produced by oven-drying.This level of moisture content will prohibit bacterial growth in the pineapple powder but may have mold or yeast growth with increase storage period at environments with high humidity. Molds were observed on the 17th day at 89.00 % relative humidity as exhibited by the moisture sorption isotherm data. This suggests that appropriate packaging with moisture barrier is recommended for pineapple powder. This study showedthat by using appropriate ratio of juice, puree, and maltodextrin and appropriate oven drying conditions, a good oven-dried pineapple powder could be obtained.

  10. Gamma, X-ray and neutron techniques for the coal industry

    International Nuclear Information System (INIS)

    1986-01-01

    Nuclear techniques play a prominent role in all aspects of the coal industry, from exploration through mine development to testing of coal quality during production. The advent of on-line nuclear techniques allows continuous, near real time appraisal of coal quality free from the errors inherent in conventional techniques based on discrete samples. The Advisory Group Meeting reviews the latest developments in this area and makes recommendations on the most promising areas and priorities for future research and development activities. This report records the proceedings of the Advisory Group Meeting. Separate abstracts were prepared for each of the 13 papers in this report

  11. Application of nuclear techniques for analysis of Vietnamese coal and embedding rocks

    International Nuclear Information System (INIS)

    Vo Dac Bang; Pham Van Duong; Nguyen Thanh Binh; Le Tien Quan; Nguyen Manh Hung; Nguyen Thi Hong; Vu Hoang Lam

    1995-01-01

    In the paper the result of elemental analysis by Nuclear Techniques of Coal and Embedded rocks samples from Vietnamese Quang Ninh and Thai Nguyen basins were presented. Methods used were: Neutron activation Analysis at Dalat Reactor, low counting with HP-Ge and NaJ detectors and X-ray fluorescent analysis with planar Si (Si) detector. Mean concentrations of 19 elements in coal and 9 in rocks were determined. Correlation between concentrations of elements were found. It appears that the correlation between ash content and U, K, Th, concentrations was poor for Quang Ninh antracitecoal. Correlation coefficient was found to be 0,63 for ash range 0-40%. Content of Th in anthracite Quang Ninh coal was much higher than reported in literature for subbituminous, bituminous and lignite coals, while Thai Nguyen fat coal contains considerable amount of Cu, Pb, Zn. Obtained data were useful for evaluation of potential hazard for environment from using coal as fuel for coal fired power plants, for estimation of possibility of using nuclear technique in coal industry in Vietnam. They could be used also for geochemical investigations. The simple of-line coal ash gauge basing on attenuation of soft gamma radiation from Fe-55 was also described. (author). 6 refs, 3 figs, 8 tabs

  12. Coal

    International Nuclear Information System (INIS)

    Teissie, J.; Bourgogne, D. de; Bautin, F.

    2001-12-01

    Coal world production represents 3.5 billions of tons, plus 900 millions of tons of lignite. 50% of coal is used for power generation, 16% by steel making industry, 5% by cement plants, and 29% for space heating and by other industries like carbo-chemistry. Coal reserves are enormous, about 1000 billions of tons (i.e. 250 years of consumption with the present day rate) but their exploitation will be in competition with less costly and less polluting energy sources. This documents treats of all aspects of coal: origin, composition, calorific value, classification, resources, reserves, production, international trade, sectoral consumption, cost, retail price, safety aspects of coal mining, environmental impacts (solid and gaseous effluents), different technologies of coal-fired power plants and their relative efficiency, alternative solutions for the recovery of coal energy (fuel cells, liquefaction). (J.S.)

  13. Detection of the incipient oxidation of coal by petrographic techniques

    CSIR Research Space (South Africa)

    Kruszewska, KJ

    1996-05-01

    Full Text Available Two petrographic methods, namely long-wave fluorescence intensity measurements and a vitrinite elasticity index were developed and used to detect incipient oxidation in coals subjected to simulated weathering conditions. The two methods are based...

  14. Biodesulfurization techniques: Application of selected microorganisms for organic sulfur removal from coals. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Elmore, B.B.

    1993-08-01

    As an alternative to post-combustion desulfurization of coal and pre-combustion desulfurization using physicochemical techniques, the microbial desulfurization of coal may be accomplished through the use of microbial cultures that, in an application of various microbial species, may remove both the pyritic and organic fractions of sulfur found in coal. Organisms have been isolated that readily depyritize coal but often at prohibitively low rates of desulfurization. Microbes have also been isolated that may potentially remove the organic-sulfur fraction present in coal (showing promise when acting on organic sulfur model compounds such as dibenzothiophene). The isolation and study of microorganisms demonstrating a potential for removing organic sulfur from coal has been undertaken in this project. Additionally, the organisms and mechanisms by which coal is microbially depyritized has been investigated. Three cultures were isolated that grew on dibenzothiophene (DBT), a model organic-sulfur compound, as the sole sulfur source. These cultures (UMX3, UMX9, and IGTS8) also grew on coal samples as the sole sulfur source. Numerous techniques for pretreating and ``cotreating`` coal for depyritization were also evaluated for the ability to improve the rate or extent of microbial depyritization. These include prewashing the coal with various solvents and adding surfactants to the culture broth. Using a bituminous coal containing 0.61% (w/w) pyrite washed with organic solvents at low slurry concentrations (2% w/v), the extent of depyritization was increased approximately 25% in two weeks as compared to controls. At slurry concentrations of 20% w/v, a tetrachloroethylene treatment of the coal followed by depyritization with Thiobacillus ferrooxidans increased both the rate and extent of depyritization by approximately 10%.

  15. On-line nuclear ash gauge for coal based on gamma-ray transmission techniques

    International Nuclear Information System (INIS)

    Rizk, R.A.M.; El-Kateb, A.H.; Abdul-Kader, A.M.

    1999-01-01

    Developments and applications of on-line nuclear gauges in the coal industry are highly requested. A nuclear ash gauge for coal, based on γ-ray transmission techniques is developed. Single and dual energy γ-ray beams are used to determine the ash content of coal. The percentage ash content as a function of the γ-ray intensities transmitted through coal samples is measured and sensitivity curves are obtained. An empirical formulation relating the ash content values to the γ-ray intensities is derived. Preliminary results show that both single and dual energy γ-ray transmission techniques can be used to give a rapid on-line estimation of the ash concentration values in coal with low cost and reasonable accuracy, but the dual one is much preferable. (author)

  16. Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

    Energy Technology Data Exchange (ETDEWEB)

    Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri, John; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Liber, Pawel; Lopez-Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

    2012-03-30

    The purpose of this project was to evaluate the ability of advanced low rank coal gasification technology to cause a significant reduction in the COE for IGCC power plants with 90% carbon capture and sequestration compared with the COE for similarly configured IGCC plants using conventional low rank coal gasification technology. GE’s advanced low rank coal gasification technology uses the Posimetric Feed System, a new dry coal feed system based on GE’s proprietary Posimetric Feeder. In order to demonstrate the performance and economic benefits of the Posimetric Feeder in lowering the cost of low rank coal-fired IGCC power with carbon capture, two case studies were completed. In the Base Case, the gasifier was fed a dilute slurry of Montana Rosebud PRB coal using GE’s conventional slurry feed system. In the Advanced Technology Case, the slurry feed system was replaced with the Posimetric Feed system. The process configurations of both cases were kept the same, to the extent possible, in order to highlight the benefit of substituting the Posimetric Feed System for the slurry feed system.

  17. REAL TIME PULVERISED COAL FLOW SOFT SENSOR FOR THERMAL POWER PLANTS USING EVOLUTIONARY COMPUTATION TECHNIQUES

    Directory of Open Access Journals (Sweden)

    B. Raja Singh

    2015-01-01

    Full Text Available Pulverised coal preparation system (Coal mills is the heart of coal-fired power plants. The complex nature of a milling process, together with the complex interactions between coal quality and mill conditions, would lead to immense difficulties for obtaining an effective mathematical model of the milling process. In this paper, vertical spindle coal mills (bowl mill that are widely used in coal-fired power plants, is considered for the model development and its pulverised fuel flow rate is computed using the model. For the steady state coal mill model development, plant measurements such as air-flow rate, differential pressure across mill etc., are considered as inputs/outputs. The mathematical model is derived from analysis of energy, heat and mass balances. An Evolutionary computation technique is adopted to identify the unknown model parameters using on-line plant data. Validation results indicate that this model is accurate enough to represent the whole process of steady state coal mill dynamics. This coal mill model is being implemented on-line in a 210 MW thermal power plant and the results obtained are compared with plant data. The model is found accurate and robust that will work better in power plants for system monitoring. Therefore, the model can be used for online monitoring, fault detection, and control to improve the efficiency of combustion.

  18. Coal thickness gauge using RRAS techniques, part 1. [radiofrequency resonance absorption

    Science.gov (United States)

    Rollwitz, W. L.; King, J. D.

    1978-01-01

    A noncontacting sensor having a measurement range of 0 to 6 in or more, and with an accuracy of 0.5 in or better is needed to control the machinery used in modern coal mining so that the thickness of the coal layer remaining over the rock is maintained within selected bounds. The feasibility of using the radiofrequency resonance absorption (RRAS) techniques of electron magnetic resonance (EMR) and nuclear magnetic resonance (NMR) as the basis of a coal thickness gauge is discussed. The EMR technique was found, by analysis and experiments, to be well suited for this application.

  19. Determination of mineral matter distribution in a coal seam using O sub 2 chemisorption technique

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, A.D.; Goulet, J.-C.; Grandsen, J.; Price, J.T.; Furimsky, E. (CANMET, Ottawa, ON (Canada). Energy Research Laboratories)

    1990-08-01

    A series of samples taken from different depths of the seam of a bituminous coal in Western Canada was used to determine the mineral matter distribution. The measurements were carried out using the O{sub 2} chemisorption based on a thermogravimetric technique. The O{sub 2} chemisorption increased with decreasing mineral matter content. The employed technique was found to be suitable for identifying the portion of coal seam least contaminated with mineral matter. 5 refs., 3 figs., 1 tab.

  20. Co-combustion of low rank coal/waste biomass blends using dry air or oxygen

    International Nuclear Information System (INIS)

    Haykiri-Acma, H.; Yaman, S.; Kucukbayrak, S.

    2013-01-01

    Biomass species such as the rice husk and the olive milling residue, and a low quality Turkish coal, Soma Denis lignite, were burned in a thermal analyzer under pure oxygen and dry air up to 900 °C, and differential thermal analysis (DTA) and derivative thermogravimetric (DTG) analysis profiles were obtained. Co-combustion experiments of lignite/biomass blends containing 5–20 wt% of biomass were also performed. The effects of the oxidizer type and the blending ratio of biomass were evaluated considering some thermal reactivity indicators such as the maximum burning rate and its temperature, the maximum heat flow temperature, and the burnout levels. FTIR (Fourier transform infrared) spectroscopy and SEM (scanning electron microscopy) were used to characterize the samples, and the variations in the combustion characteristics of the samples were interpreted based on the differences in the intrinsic properties of the samples. - Highlights: ► Co-combustion of lignite/biomass blends. ► The effects of the oxidizer type and the blending ratio. ► Effects of intrinsic properties on combustion characteristics.

  1. Determine the feasibility of techniques for simulating coal dust explosions

    CSIR Research Space (South Africa)

    Kirsten, JT

    1994-07-01

    Full Text Available The primary objective of this work is to assess the feasibility of reliably simulating the coal dust explosion process taking place in the Kloppersbos tunnel with a computer model. Secondary objectives are to investigate the viability of simulating...

  2. Elemental composition of coal fly ash: Malta coal power station in the Mpumalanga province in South Africa case study using nuclear and related analytical techniques

    International Nuclear Information System (INIS)

    Eze, Ch.P.; Fatoba, O.; Madzivire, G.; Petrik, L.F.; Ostrovnaya, T.M.; Frontas'eva, M.V.; Nechaev, A.N.

    2013-01-01

    Epithermal neutron activation analysis along with ICP-OES, LA ICP-MS, and XRF were used to determine the elemental composition of coal fly ash from the Malta coal power station in the Mpumalanga province of South Africa. A total of 54 major, trace and rare-earth elements were obtained by the four analytical techniques. The results were compared and the discrepancies discussed to show the merits and drawbacks of each of the techniques. It was shown that the elemental content of this particular coal fly ash is of the same order as the NIST standard reference material Coal Fly Ash 1633b

  3. Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

    Energy Technology Data Exchange (ETDEWEB)

    Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri,; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

    2012-11-30

    This report describes the development of the design of an advanced dry feed system that was carried out under Task 4.0 of Cooperative Agreement DE-FE0007902 with the US DOE, “Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the use of Low- Rank Coal.” The resulting design will be used for the advanced technology IGCC case with 90% carbon capture for sequestration to be developed under Task 5.0 of the same agreement. The scope of work covered coal preparation and feeding up through the gasifier injector. Subcomponents have been broken down into feed preparation (including grinding and drying), low pressure conveyance, pressurization, high pressure conveyance, and injection. Pressurization of the coal feed is done using Posimetric1 Feeders sized for the application. In addition, a secondary feed system is described for preparing and feeding slag additive and recycle fines to the gasifier injector. This report includes information on the basis for the design, requirements for down selection of the key technologies used, the down selection methodology and the final, down selected design for the Posimetric Feed System, or PFS.

  4. Analytical Technique of Gravel Propensity in Coal pit

    OpenAIRE

    Kovačič, Blaž; Zupančič, Borislav; Potočnik, Damir

    2011-01-01

    In terms of surrounding rock with rock burst tendency in coal mine, the rock burst occur when elastic energy accumulation of rock mass system for rock mass deformation reached the limit of rock mass energy storage, and the condition that the factors effected elastic energy accumulation needed to meet can be laid out. The rock burst tendency analysis can be defined as a progress as following: making sure the stress condition of surrounding rock and the. For the purpose of forecasting rock burs...

  5. Survey on peripheral techniques of brown coal liquefaction techniques; Kattan ekika gijutsu ni kansuru shuhen gijutsu no chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-09-01

    Described herein are results of survey on brown coal liquefaction techniques and peripheral techniques, centered by COSTEAM process under development in USA, solubilization by alcohol and liquefaction and cracking with the aid of tetrahydroquinoline as the hydrogen donor under development in Japan, and low-temperature carbonization and new promising techniques. The COSTEAM process shows higher reaction rates, conversions and oil yields for brown coal liquefaction than the one using hydrogen gas. Some of the problems involved in this process high viscosity and oxygenated compound content of the product oil. The product oil is acceptable as fuel for power generating plants and can be produced at a moderate cost, but may be unsuitable as vehicle fuel. Coal liquefaction and solubilization processes are mainly represented by those which use hydrogen. The hydrogen cost, which is high, determines the product price. The processes which use alcohol or tetrahydroquinoline are still in the experimental stage. (NEDO)

  6. Process to dry and preheat fine-grained bituminous coal using non- or weakly baking coal and/or carbon materials. Verfahren zur Trocknung und Vorerhitzung von feinkoerniger Steinkohle unter Verwendung nicht oder nur schwach backender Kohle und/oder Kohlenstofftraegern

    Energy Technology Data Exchange (ETDEWEB)

    Echterhoff, J.; Frick, H.; Schaper, A.; Mohmeyer, H.

    1982-11-04

    Fine-grained bituminous coal is dried and preheated in an inert gas to prevent its oxidation. The inert gas consists essentially of steam which originates from the coal to be dried. The coal is heated besides by using steam intensively but gently. The drying is carried out in a drying drum in co-current flow. The coal is mixed with a binding agent in the presence of steam. The dried and preheated coal is taken out and, after being covered with a binding agent, transported without further safety measures to the atmosphere, stored and further processed. (KHH).

  7. Dry sorbent injection of trona to control acid gases from a pilot-scale coal-fired combustion facility

    Directory of Open Access Journals (Sweden)

    Tiffany L. B. Yelverton

    2016-01-01

    Full Text Available  Gaseous and particulate emissions from the combustion of coal have been associated with adverse effects on human and environmental health, and have for that reason been subject to regulation by federal and state governments. Recent regulations by the United States Environmental Protection Agency have further restricted the emissions of acid gases from electricity generating facilities and other industrial facilities, and upcoming deadlines are forcing industry to consider both pre- and post-combustion controls to maintain compliance. As a result of these recent regulations, dry sorbent injection of trona to remove acid gas emissions (e.g. HCl, SO2, and NOx from coal combustion, specifically 90% removal of HCl, was the focus of the current investigation. Along with the measurement of HCl, SO2, and NOx, measurements of particulate matter (PM, elemental (EC, and organic carbon (OC were also accomplished on a pilot-scale coal-fired combustion facility. Gaseous and particulate emissions from a coal-fired combustor burning bituminous coal and using dry sorbent injection were the focus of the current study. From this investigation it was shown that high levels of trona were needed to achieve the goal of 90% HCl removal, but with this increased level of trona injection the ESP and BH were still able to achieve greater than 95% fine PM control. In addition to emissions reported, measurement of acid gases by standard EPA methods were compared to those of an infrared multi-component gas analyzer. This comparison revealed good correlation for emissions of HCl and SO2, but poor correlation in the measurement of NOx emissions.

  8. Supercritical fluid processing: a new dry technique for photoresist developing

    Science.gov (United States)

    Gallagher-Wetmore, Paula M.; Wallraff, Gregory M.; Allen, Robert D.

    1995-06-01

    Supercritical fluid (SCF) technology is investigated as a dry technique for photoresist developing. Because of their unique combination of gaseous and liquid-like properties, these fluids offer comparative or improved efficiencies over liquid developers and, particularly carbon dioxide, would have tremendous beneficial impact on the environment and on worker safety. Additionally, SCF technology offers the potential for processing advanced resist systems which are currently under investigation as well as those that may have been abandoned due to problems associated with conventional developers. An investigation of various negative and positive photoresist systems is ongoing. Initially, supercritical carbon dioxide (SC CO2) as a developer for polysilane resists was explored because the exposure products, polysiloxanes, are generally soluble in this fluid. These initial studies demonstrated the viability of the SCF technique with both single layer and bilayer systems. Subsequently, the investigation focused on using SC CO2 to produce negative images with polymers that would typically be considered positive resists. Polymers such as styrenes and methacrylates were chemically modified by fluorination and/or copolymerization to render them soluble in SC CO2. Siloxane copolymers and siloxane-modified methacrylates were examined as well. The preliminary findings reported here indicate the feasibility of using SC CO2 for photoresist developing.

  9. Designing on-line analyzer for coal on belt conveyor using neutron activation technique

    International Nuclear Information System (INIS)

    Rony Djokorayono; Agus Cahyono

    2014-01-01

    Basic design of on-line analyzer for coal on belt conveyor using neutron activation technique has been carried out. Compared with sampling technique, this neutron activation technique has some advantages in term of analysis accuracy and time. The design activities performed include the establishment of design requirements, functional requirements, technical requirements, technical specification, detection sub-system design, data acquisition subsystem design, and operator computer console design. This program will use Nal(Tl) scintillation detector to detect gamma-rays emitted by elements in coal due to neutron activation of a neutron source, "2"5"2Cf (Californium-252). This basic design of on-line analyzer for coal on belt conveyor using neutron activation technique should be followed up with the development of detailed design, prototype construction, and field testing. (author)

  10. Thermodynamic analysis and economic evaluation of a 1000 MW bituminous coal fired power plant incorporating low-temperature pre-drying (LTPD)

    International Nuclear Information System (INIS)

    Xu, Cheng; Xu, Gang; Zhu, Mingming; Dong, Wei; Zhang, Yang; Yang, Yongping; Zhang, Dongke

    2016-01-01

    Highlights: • An improved design of coal pre-drying using flue gas waste heat was proposed. • 0.4% energy efficiency increase was achieved with the proposed system. • The additional net economic benefit of the proposed system is $1.91 M per year. • Proposed concept can be widely applied to improve coal-fired power plant efficiency. - Abstract: Low-temperature pre-drying (LTPD) of lignite has been identified as an effective approach to improve the efficiency of lignite fired power plants. In this study, an improved concept for the pre-drying of medium moisture bituminous coals using flue gas waste heat was proposed and its feasibility was assessed. In the proposed configuration, the boiler exhaust flue gas is drawn to dryers to heat and pre-dry the raw coal, removing a large proportion of the coal moisture and leading to an improvement in the energy efficiency of the power plant. Thermodynamic analysis and economic evaluation were performed based on a typical 1000 MW bituminous coal fired power plant incorporating the proposed LTPD concept. The results showed that the net power plant efficiency gain is as much as 0.4 percentage point with additional net power output of 9.3 MW as compared to the reference plant without coal pre-drying. This was attributed to the reduction in the moisture content from 10.3 to 2.7 wt%. The additional net economic benefit attained due to the coal pre-drying was estimated to reach $1.91 M per year. This work provides a broadly applicable and economically feasible approach to further improve the energy efficiency of power plants firing coals with medium moisture contents.

  11. Elemental characterization of coal ash and its leachates using sequential extraction techniques

    International Nuclear Information System (INIS)

    Landsberger, S.; Cerbus, J.F.; Larson, S.

    1995-01-01

    Over 50 million tons of coal ash are produced annually in North America. Technological improvements in air pollution control have decreased stack emissions but have also increased contaminant concentrations in the ash of coal-fired boiler applications. The leaching of heavy metals and other elements during regulatory tests may cause coal ash to be classified as hazardous waste, complicating land disposal. The hazardous nature of coal ash remains unclear because current toxicity tests fail to effectively characterize the elemental distribution and chemical solubility of trace metals in the landfill environment. Leaching characteristics of ash samples can be investigated with various laboratory extraction procedures in association with multi-elemental analytical techniques (e.g., neutron activation analysis and inductively coupled plasma - atomic emission spectroscopy). Such methods provide more thorough analyses of coal ash leaching dynamics than the regulatory assessments can demonstrate. Regulatory elements including Ag, As, Ba, Cd, Cr, Hg, Pb, and Se were shown to remain in largely insoluble forms while elements such as B and S leached at higher levels. Experimental results may assist operators of coal-fired boiler industries in selecting coal types and disposal options to curtail the leaching of potentially toxic inorganic contaminants. (author) 12 refs.; 4 figs.; 3 tabs

  12. A novel solar energy integrated low-rank coal fired power generation using coal pre-drying and an absorption heat pump

    International Nuclear Information System (INIS)

    Xu, Cheng; Bai, Pu; Xin, Tuantuan; Hu, Yue; Xu, Gang; Yang, Yongping

    2017-01-01

    Highlights: •An improved solar energy integrated LRC fired power generation is proposed. •High efficient and economic feasible solar energy conversion is achieved. •Cold-end losses of the boiler and condenser are reduced. •The energy and exergy efficiencies of the overall system are improved. -- Abstract: A novel solar energy integrated low-rank coal (LRC) fired power generation using coal pre-drying and an absorption heat pump (AHP) was proposed. The proposed integrated system efficiently utilizes the solar energy collected from the parabolic trough to drive the AHP to absorb the low-grade waste heat of the steam cycle, achieving larger amount of heat with suitable temperature for coal’s moisture removal prior to the furnace. Through employing the proposed system, the solar energy could be partially converted into the high-grade coal’s heating value and the cold-end losses of the boiler and the steam cycle could be reduced simultaneously, leading to a high-efficient solar energy conversion together with a preferable overall thermal efficiency of the power generation. The results of the detailed thermodynamic and economic analyses showed that, using the proposed integrated concept in a typical 600 MW LRC-fired power plant could reduce the raw coal consumption by 4.6 kg/s with overall energy and exergy efficiencies improvement of 1.2 and 1.8 percentage points, respectively, as 73.0 MW th solar thermal energy was introduced. The cost of the solar generated electric power could be as low as $0.044/kW h. This work provides an improved concept to further advance the solar energy conversion and utilisation in solar-hybrid coal-fired power generation.

  13. Zero-Headspace Coal-Core Gas Desorption Canister, Revised Desorption Data Analysis Spreadsheets and a Dry Canister Heating System

    Science.gov (United States)

    Barker, Charles E.; Dallegge, Todd A.

    2005-01-01

    Coal desorption techniques typically use the U.S. Bureau of Mines (USBM) canister-desorption method as described by Diamond and Levine (1981), Close and Erwin (1989), Ryan and Dawson (1993), McLennan and others (1994), Mavor and Nelson (1997) and Diamond and Schatzel (1998). However, the coal desorption canister designs historically used with this method have an inherent flaw that allows a significant gas-filled headspace bubble to remain in the canister that later has to be compensated for by correcting the measured desorbed gas volume with a mathematical headspace volume correction (McLennan and others, 1994; Mavor and Nelson, 1997).

  14. Nuclear techniques for analysis of coal for calorific value, ash and moisture

    International Nuclear Information System (INIS)

    Dains, Margaret

    1976-03-01

    This bibliography includes references on nuclear techniques for analysis of coal for calorific value, ash and moisture content. As the search was directed particularly towards measurement of the ash content of coal using x- and gamma-ray methods, references covering only β-ray techniques have been placed in a separate section. References from Chemical Abstracts prior vol.62 (1965) do not cite the language of the original article. The language of the original has been given for all other articles not in English. (author)

  15. Quantitative determination of mineral coal impurities from Brazil through optical emission spectrography technique

    International Nuclear Information System (INIS)

    Clain, Almir Faria

    1982-01-01

    The aim of the present research was to develop a spectrographic technique to determine the highest possible number of the chemical elements micro-constituents of Brazilian mineral coals. The experimental technique developed corresponds to the so called total-burning procedure. Coal samples were calcined to ashes at 400°C and then totally burned in graphite electrodes by a DC arc. The spectrographic measurements were made in a Jarrell-Ash emission spectrograph, Ebert mounting type, model Mark IV. An inert atmosphere chamber (for a gaseous mixture 20% 0 2 and 80% air) and a seven step rotating sector were used as main accessories. The analytical curves for the different elements, were obtained using synthetic standards in the concentration range of 10 to 1.000 ppm, and the standards as well as the coal ashes were diluted with spectrographically pure graphite in 1:1 ratio. Seventeen coal samples from different shells and strata of Morungava and Charqueadas mines - Rio Grande do Sul State - were analyzed to test the proposed technique, being possible to determine the following elements: B, Be, Bi, Cd, Co, Cr, Cu, Ga,Pb, Ge, Mn, Mo, Ni, Sn, Sb, V, Y, Zn and Zr. The coefficient of variation was 14% in average for all the elements and the sensitivity was so that the majority of the impurities present in the coals were analyzed. (author)

  16. evaluation of the effect of various drying techniques

    African Journals Online (AJOL)

    Preferred Customer

    However, dried leaves have received less attention among the .... The dried and ground samples were packed in to polyethylene bag and kept in .... As shown in Figure 6A the fresh leaves is mainly composed of cathinone, i.e. cathine and.

  17. Effect of different drying techniques on the volatile compounds ...

    African Journals Online (AJOL)

    Purpose: To examine the volatile compounds, thermal stability and morphological characteristics of stevia (Stevia rebaudiana Bertoni) leaves after sun, oven and microwave drying. Methods: Gas chromatography-mass spectrometry with a spectral analysis manager was used to separate the volatile compounds. Dried stevia ...

  18. Coal upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Nunes, S. [IEA Clean Coal Centre, London (United Kingdom)

    2009-10-15

    This report examines current technologies and those likely to be used to produce cleaner coal and coal products, principally for use in power generation and metallurgical applications. Consideration is also given to coal production in the leading coal producing countries, both with developed and developing industries. A range of technologies are considered. These include the coal-based liquid fuel called coal water mixture (CWM) that may compete with diesel, the production of ultra-clean coal (UCC) and coal liquefaction which competes with oil and its products. Technologies for upgrading coal are considered, especially for low rank coals (LRC), since these have the potential to fill the gap generated by the increasing demand for coal that cannot be met by higher quality coals. Potential advantages and downsides of coal upgrading are outlined. Taking into account the environmental benefits of reduced pollution achieved through cleaner coal and reduced transport costs, as well as other positive aspects such as a predictable product leading to better boiler design, the advantages appear to be significant. The drying of low rank coals improves the energy productively released during combustion and may also be used as an adjunct or as part of other coal processing procedures. Coal washing technologies vary in different countries and the implications of this are outlined. Dry separation technologies, such as dry jigging and electrostatic separation, are also described. The demonstration of new technologies is key to their further development and demonstrations of various clean coal technologies are considered. A number of approaches to briquetting and pelletising are available and their use varies from country to country. Finally, developments in upgrading low rank coals are described in the leading coal producing countries. This is an area that is developing rapidly and in which there are significant corporate and state players. 81 refs., 32 figs., 3 tabs.

  19. Research on the drying kinetics of household food waste for the development and optimization of domestic waste drying technique.

    Science.gov (United States)

    Sotiropoulos, A; Malamis, D; Michailidis, P; Krokida, M; Loizidou, M

    2016-01-01

    Domestic food waste drying foresees the significant reduction of household food waste mass through the hygienic removal of its moisture content at source. In this manuscript, a new approach for the development and optimization of an innovative household waste dryer for the effective dehydration of food waste at source is presented. Food waste samples were dehydrated with the use of the heated air-drying technique under different air-drying conditions, namely air temperature and air velocity, in order to investigate their drying kinetics. Different thin-layer drying models have been applied, in which the drying constant is a function of the process variables. The Midilli model demonstrated the best performance in fitting the experimental data in all tested samples, whereas it was found that food waste drying is greatly affected by temperature and to a smaller scale by air velocity. Due to the increased moisture content of food waste, an appropriate configuration of the drying process variables can lead to a total reduction of its mass by 87% w/w, thus achieving a sustainable residence time and energy consumption level. Thus, the development of a domestic waste dryer can be proved to be economically and environmentally viable in the future.

  20. Effect of different drying techniques on the volatile compounds ...

    African Journals Online (AJOL)

    Tropical Journal of Pharmaceutical Research June 2017; 16 (6): 1399-1406 ... Original Research Article ... and compact while the sun- and oven dried particles resembled angular bricks. ... better preserve the quality of medicinal plants.

  1. Adjustments of microwave-based measurements on coal moisture using natural radioactivity techniques

    Energy Technology Data Exchange (ETDEWEB)

    Prieto-Fernandez, I.; Luengo-Garcia, J.C.; Alonso-Hidalgo, M.; Folgueras-Diaz, B. [University of Oviedo, Gijon (Spain)

    2006-01-07

    The use of nonconventional on-line measurements of moisture and ash content in coal is presented. The background research is briefly reviewed. The possibilities of adjusting microwave-based moisture measurements using natural radioactive techniques, and vice versa, are proposed. The results obtained from the simultaneous analysis of moisture and ash content as well as the correlation improvements are shown.

  2. Comparative study of two drying techniques used in radioactive source preparation: Freeze-drying and evaporation using hot dry nitrogen jets

    International Nuclear Information System (INIS)

    Branger, T.; Bobin, C.; Iroulart, M.-G.; Lepy, M.-C.; Le Garreres, I.; Morelli, S.; Lacour, D.; Plagnard, J.

    2008-01-01

    Quantitative solid sources are used widely in the field of radionuclide metrology. With the aim to improve the detection efficiency for electrons and x-rays, a comparative study between two source drying techniques has been undertaken at LNE-Laboratoire National Henri Becquerel (LNE-LNHB, France). In this paper, freeze-drying using commercial equipment is compared with a system of drying using hot jets of nitrogen developed at Institute for Reference Materials and Measurements (IRMM, Belgium). In order to characterize the influence of self-absorption, the detection efficiencies for 51 Cr sources have been measured by coincidence counting and photon spectrometry

  3. Use of nuclear techniques for coal analysis in exploration, mining and processing

    International Nuclear Information System (INIS)

    Clayton, C.G.; Wormald, M.R.

    1982-01-01

    Nuclear techniques have a long history of application in the coal industry, during exploration and especially during coal preparation, for the measurement of ash content. The preferred techniques are based on X- and gamma-ray scattering and borehole logging, and on-line equipment incorporating these techniques are now in world-wide routine use. However, gamma-ray techniques are mainly restricted to density measurement and X-ray techniques are principally used for ash determinations. They have a limited range and when used on-line some size reduction of the coal is usually required and a full elemental analysis is not possible. In particular, X- and gamma-ray techniques are insensitive to the principal elements in the combustible component and to many of the important elements in the mineral fraction. Neutron techniques on the other hand have a range which is compatible with on-line requirements and all elements in the combustible component and virtually all elements in the mineral component can be observed. A complete elemental analysis of coal then allows the ash content and the calorific value to be determined on-line. This paper surveys the various nuclear techniques now in use and gives particular attention to the present state of development of neutron methods and to their advantages and limitations. Although it is shown that considerable further development and operational experience are still required, equipment now being introduced has a performance which matches many of the identified requirements and an early improvement in specification can be anticipated

  4. Effects of vegetable drying techniques on nutrient content: a case ...

    African Journals Online (AJOL)

    Vegetables are important in most of the daily diets and can be used to alleviate most of the micronutrient deficiencies. Vegetables are only available during the rainy season in rural areas. Therefore, it is necessary to preserve them and use them during the dry season when they are scarce. The objective of this study was to ...

  5. evaluation of the effect of various drying techniques on the ...

    African Journals Online (AJOL)

    Preferred Customer

    Thus, the objective of this work was to investigate the effect of different sample preservative conditions (air drying ... Ethiopia over night in the ice box. As soon as it ... The multiplicity and chemical shifts in the 1H NMR, 13 C NMR spectra as.

  6. Uranium trace and alpha activity characterization of coal and fly ash using particle track etch technique

    International Nuclear Information System (INIS)

    Chakravarti, S.K.

    1991-01-01

    Uranium is extensively found in carbonaceous components of sedimentary rocks and is considered to be accumulated in coals during the coalification process through the geological times. Burning of coal is mainly responsible for a manifold increase in the concentration of radioactive nuclides in atmosphere precipitates. Fly ash being an incombustible residue and formed from 90% of the inorganic material in coal, escapes into the atmosphere and constitutes a potential hazard. Also its use as one of the pozzolanic materials in the products of concrete, bricks etc and filling of ground cavities is even more hazardous because of the wall radioactivity, besides emission and diffusion of radon. This paper reports a simple method called Particle Track Etch (PTE) technique, for trace determination of uranium content in coal and fly ash samples by making use of low cost and versatile plastic detectors known as Solid State Nuclear Track Detectors (SSNTDs). Total alpha activity has also been estimated using these SSNTDs. The values of uranium concentration in coal samples are found to range from 1.1 to 3.6 ppm (uniform component) and 33 to 46 ppm (non-uniform part) whereas in fly ash, it varies from 8 to 11 ppm (uniform) and 55 to 71 ppm in non-uniform range. It is also observed that the alpha activity is a function of uranium concentration for most of the natural samples of coal studied except for mixtures of fly ash samples where relationship is found to be on higher side. (author). 13 refs., 2 tabs., 1 fig

  7. Use of clean coal technology by-products as agricultural liming techniques

    Energy Technology Data Exchange (ETDEWEB)

    Stehouwer, R.C.; Sutton, P.; Dick, W.A. [Ohio Agricultural Research and Development Center, Wooster, OH (United States). Dept. of Agronomy

    1995-03-01

    Dry flue gas desulfurization (FGD) by-products are mixtures of coal fly-ash, anhydrite (CaCO{sub 4}), and unspent lime- or limestone-based sorbent. Dry FGD by-products frequently have neutralizing values greater than 50% CaCO{sub 3} equivalency and thus have potential for neutralizing acidic soils. Owing to the presence of soluble salts and various trace elements, however, soil application of dry FGD by-products may have adverse effects on plant growth and soil quality. The use of a dry FGD by-product as a limestone substitute was investigated in a field study on three acidic agricultural soils (pH 4.6, 4.8, and 5.8) in eastern Ohio. The by-product (60% CaCO{sub 3} equivalency) was applied in September, 1992, at rates of 0, 0.5, 1.0, and 2.0 times the lime requirement of the soils, and alfalfa (Medicago sativa L.) and corn (Zea mays L.) were planted. Soils were sampled immediately after FGD application and three more times every six months thereafter. Samples were analyzed for pH and water soluble concentrations of 28 elements. Soil pH was increased by all FGD rates in the zone of incorporation (0--10 cm), with the highest rates giving a pH slightly above 7. Within one year pH increases could be detected at depths up to 30 cm. Calcium, Mg, and S increased, and Al, Mn, and Fe decreased with increasing dry FGD application rates. No trace element concentrations were changed by dry FGD application except B which was increased in the zone of incorporation. Dry FGD increased alfalfa yield on all three soils, and had no effect on corn yield. No detrimental effects on soil quality were observed.

  8. Nuclear techniques for in situ evaluation of coal and mineral deposits

    International Nuclear Information System (INIS)

    Borsaru, M.

    1993-01-01

    This paper reviews developments in in situ analysis of minerals and coal by nuclear borehole logging. Developments in the oil, gas and uranium industries are not discussed in the present paper unless they have direct applications in the mineral industry (e.g. multi-element analysis and development of spectral litho-density tools). The review covers techniques developed mostly in the last decade and is based on work published in North America, Europe and Australia. (author)

  9. Trace uranium analysis in Indian coal samples using the fission track technique

    International Nuclear Information System (INIS)

    Jojo, P.J.; Rawat, A.; Kumar, Ashavani; Prasad, Rajendra

    1993-01-01

    The ever-growing demand for energy has resulted in the extensive use of fossil fuels, especially coal, for power generation. Coal and its by-products often contain significant amounts of radionuclides, including uranium, which is the ultimate source of the radioactive gas Radon-222. The present study gives the concentration of uranium in coal samples of different collieries in India, collected from various thermal power plants in the state of Uttar Pradesh. The estimates were made using the fission track technique. Latent damage tracks were not found to be uniformly distributed but showed sun bursts and clusters. Non-uniform distributions of trace elements are a very common phenomenon in rocks. The levels of uranium in the coal samples were found to vary from 2.0 to 4.9 ppm in uniform distributions and from 21.3 to 41.0 ppm in non-uniform distributions. Measurements were also made on fly ash samples where the average uranium concentration was found to be 8.4 and 49.3 ppm in uniform and non-uniform distributions, respectively. (author)

  10. Design and optimization of the large span dry-coal-shed latticed shell in Liyuan of Henan province

    Directory of Open Access Journals (Sweden)

    Du Wenfeng

    2017-01-01

    Full Text Available The design and optimization about the large span dry-coal-shed latticed shell in Liyuan of Henan province were studied. On the basis of the structural scheme of double-layer cylindrical reticulated shell, the optimization scheme of the folding double-layer cylindrical reticulated shell was proposed. Through the analysis of a plurality of calculation models, the optimal geometric parameters were obtained after discussing the influence of different slopes of folding lines and shell thickness on the structural bearing capacity and the amount of steel. The research results show that in the case of the same amount of steel, the ultimate bearing capacity of the double-layer folding cylindrical reticulated shell whose folding line slope is 9% and the shell thickness is about 4.4m can be increased 27.3% compared with the original design scheme.

  11. New coal

    Energy Technology Data Exchange (ETDEWEB)

    1979-07-01

    Specially dedicated to coal, this edition comprises a series of articles of general interest dealing with the position of the French coalmining industry (interview with M.P. Gardent), the coal market in France, the work of CERCHAR, etc. New techniques, in-situ gasification of deep coal, gasification of coal by nuclear methods, the conversion of coal into petrol, the Emile Huchet power plant of Houilleres du Bassin de Lorraine, etc., are dealt with.

  12. Recommended procedures and techniques for the petrographic description of bituminous coals

    Science.gov (United States)

    Chao, E.C.T.; Minkin, J.A.; Thompson, C.L.

    1982-01-01

    bed. The use of bulk-specific-gravity determinations is alo recommended for identification and characterization of the distinctive lithologic units. The availability of an AIAS also enhances the capability to acquire textural information. Ranges of size of maceral and mineral grains can be quickly and precisely determined by use of an AIAS. We assume that shape characteristics of coal particles can also be readily evaluated by automated image analysis, although this evaluation has not yet been attempted in our laboratory. Definitive data on the particulate mineral content of coal constitute another important segment of petrographic description. Characterization of mineral content may be accomplished by optical identification, electron microprobe analysis, X-ray diffraction, and scanning and transmission electron microscopy. Individual mineral grains in place in polished blocks or polished this sections, or separated from the coal matrix by sink-float methods are studied by analytical techniques appropriate to the conditions of sampling. Finally, whenever possible, identification of the probable genus or plant species from which a given coal component is derived will add valuable information and meaning to the petrographic description. ?? 1982.

  13. Quantitative characterization of pulverized coal and biomass–coal blends in pneumatic conveying pipelines using electrostatic sensor arrays and data fusion techniques

    International Nuclear Information System (INIS)

    Qian, Xiangchen; Wang, Chao; Yan, Yong; Shao, Jiaqing; Wang, Lijuan; Zhou, Hao

    2012-01-01

    Quantitative data about the dynamic behaviour of pulverized coal and biomass–coal blends in fuel injection pipelines allow power plant operators to detect variations in fuel supply and oscillations in the flow at an early stage, enable them to balance fuel distribution between fuel feeding pipes and ultimately to achieve higher combustion efficiency and lower greenhouse gas emissions. Electrostatic sensor arrays and data fusion algorithms are combined to provide a non-intrusive solution to the measurement of fuel particle velocity, relative solid concentration and flow stability under pneumatic conveying conditions. Electrostatic sensor arrays with circular and arc-shaped electrodes are integrated in the same sensing head to measure ‘averaged’ and ‘localized’ characteristics of pulverized fuel flow. Data fusion techniques are applied to optimize and integrate the results from the sensor arrays. Experimental tests were conducted on the horizontal section of a 150 mm bore pneumatic conveyor circulating pulverized coal and sawdust under various flow conditions. Test results suggest that pure coal particles travel faster and carry more electrostatic charge than biomass–coal blends. As more biomass particles are added to the flow, the overall velocity of the flow reduces, the electrostatic charge level on particles decreases and the flow becomes less stable compared to the pure coal flow. (paper)

  14. Quantitative characterization of pulverized coal and biomass-coal blends in pneumatic conveying pipelines using electrostatic sensor arrays and data fusion techniques

    Science.gov (United States)

    Qian, Xiangchen; Yan, Yong; Shao, Jiaqing; Wang, Lijuan; Zhou, Hao; Wang, Chao

    2012-08-01

    Quantitative data about the dynamic behaviour of pulverized coal and biomass-coal blends in fuel injection pipelines allow power plant operators to detect variations in fuel supply and oscillations in the flow at an early stage, enable them to balance fuel distribution between fuel feeding pipes and ultimately to achieve higher combustion efficiency and lower greenhouse gas emissions. Electrostatic sensor arrays and data fusion algorithms are combined to provide a non-intrusive solution to the measurement of fuel particle velocity, relative solid concentration and flow stability under pneumatic conveying conditions. Electrostatic sensor arrays with circular and arc-shaped electrodes are integrated in the same sensing head to measure ‘averaged’ and ‘localized’ characteristics of pulverized fuel flow. Data fusion techniques are applied to optimize and integrate the results from the sensor arrays. Experimental tests were conducted on the horizontal section of a 150 mm bore pneumatic conveyor circulating pulverized coal and sawdust under various flow conditions. Test results suggest that pure coal particles travel faster and carry more electrostatic charge than biomass-coal blends. As more biomass particles are added to the flow, the overall velocity of the flow reduces, the electrostatic charge level on particles decreases and the flow becomes less stable compared to the pure coal flow.

  15. Coal ash fusion temperatures -- New characterization techniques, and associations with phase equilibria

    Energy Technology Data Exchange (ETDEWEB)

    Wall, T.F.; Gupta, R.P.; Gupta, S. [Univ. of Newcastle, New South Wales (Australia). Dept. of Chemical Engineering; Creelman, R.A. [R.A. Creelman and Associates, Epping, New South Wales (Australia); Coin, C. [ACIRL Ipswich, Booval, Queensland (Australia); Lowe, A. [Pacific Power, Sydney, New South Wales (Australia)

    1996-12-31

    The well-documented shortcomings of the standard technique for estimating the fusion temperature of coal ash are its subjective nature and poor accuracy. Alternative measurements based on the shrinkage and electrical conductivity of heating samples are therefore examined with laboratory ash prepared at about 800 C in crucibles, as well as combustion ash sampled from power stations. Sensitive shrinkage measurements indicate temperatures of rapid change which correspond to the formation of liquid phases that can be identified on ternary phase diagrams. The existence and extent of formation of these phases, as quantified by the magnitude of peaks in the test, provide alternative ash fusion temperatures. The peaks from laboratory ashes and corresponding combustion ashes derived from the same coals show clear differences which may be related to the evaporation of potassium during combustion and the reactions of the mineral residues to form combustion ash.

  16. Coal ash fusion temperatures - new characterization techniques and implications for slagging and fouling

    Energy Technology Data Exchange (ETDEWEB)

    Wall, T.F.; Creelman, R.A.; Gupta, R.P.; Gupta, S.K.; Coin, C.; Lowe, A. [University of Newcastle, Newcastle, NSW (Australia). CRC for Black Coal Utilisation

    1998-09-01

    The ash fusion test (AFT) is the accepted test for the propensity of coal ash to slag in the furnace. The well-documented shortcomings of this technique for estimating the fusion temperature of coal ash are its subjective nature and poor accuracy. Alternative measurements based on the shrinkage and electrical conductivity of heating samples are therefore examined here with laboratory ash prepared at about 800{degree}C in crucibles, as well as combustion ash samples from power stations. Sensitive shrinkage measurements indicate temperatures of rapid change which correspond to the formation of liquid phases that can be identified on ternary phase diagrams. The existence and extent of formation of these phases, as quantified by the magnitude of `peaks` in the test, provide alternative ash fusion temperatures. The peaks from laboratory ashes and corresponding combustion ashes derived from the same coals show clear differences which may be related to the evaporation of potassium during combustion and the reactions of the mineral residues to form combustion ash. A preliminary evaluation of data from nine power stations indicates that shrinkage measurements can provide an alternative approach to characterizing slagging. 15 refs., 9 figs., 2 tabs.

  17. Coal dust symposium

    Energy Technology Data Exchange (ETDEWEB)

    1981-03-01

    This paper gives a report of the paper presented at the symposium held in Hanover on 9 and 10 February 1981. The topics include: the behaviour of dust and coal dust on combustion and explosion; a report on the accidents which occurred at the Laegerdorf cement works' coal crushing and drying plant; current safety requirements at coal crushing and drying plant; and coal crushing and drying. Four papers are individually abstracted. (In German)

  18. Prediction method of unburnt carbon for coal fired utility boiler using image processing technique of combustion flame

    International Nuclear Information System (INIS)

    Shimoda, M.; Sugano, A.; Kimura, T.; Watanabe, Y.; Ishiyama, K.

    1990-01-01

    This paper reports on a method predicting unburnt carbon in a coal fired utility boiler developed using an image processing technique. The method consists of an image processing unit and a furnace model unit. temperature distribution of combustion flames can be obtained through the former unit. The later calculates dynamics of the carbon reduction from the burner stages to the furnace outlet using coal feed rate, air flow rate, chemical and ash content of coal. An experimental study shows that the prediction error of the unburnt carbon can be reduced to 10%

  19. Effect of drying technique on quality of UO2 sintered spheres

    International Nuclear Information System (INIS)

    Benadik, A.; Becvar, J.; Jakesova, L.

    1978-01-01

    A comparison was made of the appearance and quality of UO 2 sintered spheres prepared from gel particles by drying in the air saturated with gaseous products of thermal decomposition at 225 degC, and by azeotropic distillation. The quality of the end product was controlled by the gel particle size and drying technique. Coarser particles (0.95 mm in diameter) were of inhomogeneous structure and after drying by azeotropic distillation had a lower specific density. Particles 0.82 and 0.75 mm in diameter had a specific density >= 98.2% of theoretical value and a homogeneous structure. (author)

  20. Tensile bond strength of hydroxyethyl methacrylate dentin bonding agent on dentin surface at various drying techniques

    Directory of Open Access Journals (Sweden)

    Kun Ismiyatin

    2010-06-01

    Full Text Available Background: There are several dentin surface drying techniques to provide a perfect resin penetration on dentin. There are two techniques which will be compared in this study. The first technique was by rubbing dentin surface gently using cotton pellet twice, this technique is called blot dry technique. The second technique is by air blowing dentin surface for one second and continued by rubbing dentin surface gently using moist cotton. Purpose: This experiment was aimed to examine the best dentin surface drying techniques after 37% phosphoric acid etching to obtain the optimum tensile bond strength between hydroxyethyl methacrylate (HEMA and dentin surface. Method: Bovine teeth was prepared flat to obtain the dentin surface and than was etched using 37% phosphoric acid for 15 seconds. After etching the dentin was cleaned using 20 cc plain water and dried with blot dry techniques (group I, or dried with air blow for one second (group II, or dried with air blow for one second, and continued with rubbing gently using moist cotton pellet (group III, and without any drying as control group (group IV. After these drying, the dentin surfaces were applied with resin dentin bonding agent and put into plunger facing the composite mould. The antagonist plunger was filled with composite resin. After 24 hours, therefore bond strength was measured using Autograph. Result: Data obtained was analyzed using One-Way ANOVA with 95% confidence level and continued with LSD test on p≤0.05. The result showed that the highest tensile bond strength was on group I, while the lowest on group IV. Group II and IV, III and IV, II and III did not show signigicant difference (p>0.05. Conclusion: Dentin surface drying techniques through gentle rubbing using cotton pellet twice (blot dry technique gave the greatest tensile bond strength.Latar belakang masalah: Tehnik pengeringan permukaan dentin agar resin dapat penetrasi dengan sempurna adalah dengan cara pengusapan secara

  1. Coal at the crossroads

    International Nuclear Information System (INIS)

    Scaroni, A.W.; Davis, A.; Schobert, H.; Gordon, R.L.; Ramani, R.V.; Frantz, R.L.

    1992-01-01

    Worldwide coal reserves are very large but coal suffers from an image of being an environmentally unfriendly and inconvenient fuel. Aspects discussed in the article include: coal's poor image; techniques for coal analysis, in particular instrumented techniques; developments in clean coal technology e.g. coal liquefaction, fluidized bed combustion, co-generation and fuel slurries; the environmental impact of mining and land reclamation; and health aspects. It is considered that coal's future depends on overcoming its poor image. 6 photos

  2. The effect of petrographical composition of coals and bituminous sediments on the material and isotopic composition of dry natural gases from artificial recoalification reactions. 2

    International Nuclear Information System (INIS)

    Maass, I.; Huebner, H.; Nitzsche, H.-M.; Schuetze, H.; Zschiesche, M.

    1975-01-01

    Experimental results indicate that on the basis of the material and isotopic composition of natural gases conclusions can be drawn with regard to the character (humic or bituminous) of the parent rock. Thus, genetic relations assumed to exist between humic sediments (e.g. coal seams) and dry natural gases as well as bituminous rocks and wet natural gases are experimentally confirmed. In addition, from analyses of the materials approximate data can be derived on the degree of carbonization of coal or bituminous sediments in the main phase of gas separation. Furthermore, these analyses were used to elucidate the question whether authochthonous or allochthonous deposits are present. It could be shown that the maceral composition of coals and of the organo-petrographical inclusions in bituminous sediments determines the isotopic composition of methane in recoalification gases to a considerable degree. (author)

  3. Novel technique for coal pyrolysis and hydrogenation product analysis. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Pfefferle, L.D.; Boyle, J.

    1993-03-15

    A microjet reactor coupled to a VUV photoionization time-of-flight mass spectrometer has been used to obtain species measurements during high temperature pyrolysis and oxidation of a wide range of hydrocarbon compounds ranging from allene and acetylene to cyclohexane, benzene and toluene. Initial work focused on calibration of the technique, optimization of ion collection and detection and characterization of limitations. Using the optimized technique with 118 nm photoionization, intermediate species profiles were obtained for analysis of the hydrocarbon pyrolysis and oxidation mechanisms. The ``soft`` ionization, yielding predominantly molecular ions, allowed the study of reaction pathways in these high temperature systems where both sampling and detection challenges are severe. Work has focused on the pyrolysis and oxidative pyrolysis of aliphatic and aromatic hydrocarbon mixtures representative of coal pyrolysis and hydropyrolysis products. The detailed mass spectra obtained during pyrolysis and oxidation of hydrocarbon mixtures is especially important because of the complex nature of the product mixture even at short residence times and low primary reactant conversions. The combustion community has advanced detailed modeling of pyrolysis and oxidation to the C4 hydrocarbon level but in general above that size uncertainties in rate constant and thermodynamic data do not allow us to a priori predict products from mixed hydrocarbon pyrolyses using a detailed chemistry model. For pyrolysis of mixtures of coal-derived liquid fractions with a large range of compound structures and molecular weights in the hundreds of amu the modeling challenge is severe. Lumped models are possible from stable product data.

  4. Use of artificial intelligence techniques for optimisation of co-combustion of coal with biomass

    Energy Technology Data Exchange (ETDEWEB)

    Tan, C.K.; Wilcox, S.J.; Ward, J. [University of Glamorgan, Pontypridd (United Kingdom). Division of Mechanical Engineering

    2006-03-15

    The optimisation of burner operation in conventional pulverised-coal-fired boilers for co-combustion applications represents a significant challenge This paper describes a strategic framework in which Artificial Intelligence (AI) techniques can be applied to solve such an optimisation problem. The effectiveness of the proposed system is demonstrated by a case study that simulates the co-combustion of coal with sewage sludge in a 500-kW pilot-scale combustion rig equipped with a swirl stabilised low-NOx burner. A series of Computational Fluid Dynamics (CFD) simulations were performed to generate data for different operating conditions, which were then used to train several Artificial Neural Networks (ANNs) to predict the co-combustion performance. Once trained, the ANNs were able to make estimations of unseen situations in a fraction of the time taken by the CFD simulation. Consequently, the networks were capable of representing the underlying physics of the CFD models and could be executed efficiently for a large number of iterations as required by optimisation techniques based on Evolutionary Algorithms (EAs). Four operating parameters of the burner, namely the swirl angles and flow rates of the secondary and tertiary combustion air were optimised with the objective of minimising the NOx and CO emissions as well as the unburned carbon at the furnace exit. The results suggest that ANNs combined with EAs provide a useful tool for optimising co-combustion processes.

  5. Microbiological evaluation of anatomical organs submitted to glycerinization and freeze-drying techniques

    Directory of Open Access Journals (Sweden)

    Marianna Justo

    2016-06-01

    Full Text Available Alternatives conservation techniques are being requested with the proposal of formaldehyde substitution. Formaldehyde results in excessive anatomical specimens' weight and it can cause serious health problems to the manipulator, such as cancer. However, it provides an efficient germicide and fungicide action depending on concentration. The substitute techniques are glicerinization and freeze-drying which have advantages such as non-production of smells, lightness of the organs and dispenses the use of fixatives in conservation. As well as both intrinsic and extrinsic factors interfere in microbial growth, microbiological analyzes are essential to detect possible deteriorative microorganisms in organs and concluding effectively the technique used. Formalinized, glycerinated and freeze-drying organs were collected in three different times which were intercalated by two months, except formalinization that had one evaluation. The procedure required the use of sterilized swabs wetted in peptone water and molds measuring 5,0 cm x 10,0 cm positioned on two different piece's local resulting in 100 cm2 of area, to spread plate of total moulds, mesophiles (except in freeze-drying, psychrophilic (only in freeze-drying and Pseudomonas sp (except in formalinization. All the plates were counted and compared between each technique's evaluations by variance analyzes. Both alternatives techniques resulted in zero or in very low microbial quantity to cause health problems as well as it preserve pieces morphology. All values of all analyzes resulted below 1/ml, showing that glicerinization and freeze-drying techniques are so as efficient as formaldehyde. Keywords: Organs conservation, Anatomical techniques, Microbiology, Microbial growth

  6. Protection of fish oil from oxidation by microencapsulation using freeze-drying techniques

    DEFF Research Database (Denmark)

    Heinzelmann, K.; Franke, K.; Jensen, Benny

    2000-01-01

    (N-3)-Polyunsaturated fatty acids (PUFAs) reduce the risk of coronary heart disease. Cold sea water plankton and plankton- consuming fish are known sources of (n-3)-PUFAs. Enriching normal food components with fish oil is a tool for increasing the intake of (n-3)-PUFAs. Due to the high sensitivity...... different freezing techniques and subsequently freeze-dried. Several parameters regarding formulation and process (addition of antioxidants to the fish oil, use of carbohydrates, homogenisation and freezing conditions, initial freeze-drying temperature, grinding) were varied to evaluate their influence...... on the oxidative stability of dried microencapsulated fish oil. The shelf life of the produced samples was determined by measuring the development of volatile oxidation products vs. storage time. It could be shown that the addition of antioxidants to fish oil was necessary to produce dried microencapsulated fish...

  7. Measurement techniques in dry-powdered processing of spent nuclear fuels

    International Nuclear Information System (INIS)

    Bowers, D. L.; Hong, J.-S.; Kim, H.-D.; Persiani, P. J.; Wolf, S. F.

    1999-01-01

    High-performance liquid chromatography (HPLC) with inductively coupled plasma mass spectrometry (ICPMS) detection, α-spectrometry (α-S), and γ-spectrometry (γ-S) were used for the determination of nuclide content in five samples excised from a high-burnup fuel rod taken from a pressurized water reactor (PWR). The samples were prepared for analysis by dissolution of dry-powdered samples. The measurement techniques required no separation of the plutonium, uranium, and fission products. The sample preparation and analysis techniques showed promise for in-line analysis of highly-irradiated spent fuels in a dry-powdered process. The analytical results allowed the determination of fuel burnup based on 148 Nd, Pu, and U content. A goal of this effort is to develop the HPLC-ICPMS method for direct fissile material accountancy in the dry-powdered processing of spent nuclear fuel

  8. Novel technique for coal pyrolysis and hydrogenation product analysis. Quarterly report, June 1, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Pfefferle, L.D.

    1992-12-31

    This report covers the last quarter of the last year of the three-year grant period. In the final project year, we concentrated on the pyrolysis and oxidative pyrolysis of large hydrocarbons and mixtures of large and small hydrocarbons in order to develop the VUV-MS technique for compounds more representative of those in coal pyrolysis applications. Special focus was directed at the pyrolysis and oxidative pyrolysis of benzene and benzene acetylene mixtures. The acetylene/benzene mixtures were used to gain a better understanding of the mechanisms of molecular growth in such systems specifically to look at the kinetics of aryl-aryl reactions as opposed to small molecule addition to phenyl radicals. Sarofim and coworkers at MIT have recently demonstrated the importance of these reactions in coal processing environments. In the past, the growth mechanism for the formation of midsized PAH has been postulated to involve primarily successive acetylene additions to phenyl-type radicals, our work confmns this as an important mechanism especially for smaller PAH but also investigates conditions where biaryl formation can play an important role in higher hydrocarbon formation.

  9. A Technique for Decreasing Reactivity of Coal Material to Suppress the Oxygen Absorption Process

    OpenAIRE

    Timofeeva, S. S.; Lugovtsova, Nataliya Yurievna; Gubanova, А. R.

    2016-01-01

    The paper describes the mechanisms of self-ignition formation in coal liable to spontaneous combustion, on the basis of experimental works performed to analyze heat and mass transfer in the coal-air system. A new approach was developed to the coal self-heating suppression and thermodynamic control of the oxidation process. The influence of coal moisture content and thermal behaviour of air in the cooling process was studied during moisture evaporation.

  10. Technique of complex slime water treatment of coal-mining branch

    OpenAIRE

    Solodov, G. А.; Zhbyr, Е. V.; Papin, А. V.; Nevedrov, А. V.

    2007-01-01

    The possibility of complex slime water treatment at coal-mining and coal-treating plants producing marketable products: power-generating concentrate, coal-water fuel, magnetic fraction, industrial water is shown. A basic process flowsheet of slime water treatment presenting a united technological complex is suggested.

  11. Evaluation of paramagnetic species in coals with iodine doping technique; Yoso tenkaho wo mochiita sekitanchu no jojiseishu no hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Aizawa, S.; Kumagai, H.; Chiba, T. [Hokkaido University, Sapporo (Japan). Center for Advanced Research of Energy Technology

    1996-10-28

    Electron paramagnetic resonance (EPR) of coals was considered by using iodine doping technique. Sub-bituminous coal (WA) and bituminous coal (UF) were used to observe EPR spectra using microwaves. With the UF coal, strength of the narrow component of the spectra was found constant regardless of amount of the doped iodine, wherein radicals without interaction with iodine were detected. Strength of the broad component increased with the iodine doping amount, where in deviation of {pi} electrons was detected, which have been generated as a result of interaction between aromatic rings and iodine in the coals. Spin concentration of the WA coal with low coalification degree is constant regardless of the iodine doping amount, and the interaction of the iodine with the aromatic rings was found small. The higher the coalification degree, the more the aromatic ring structure grows, and electron donor capability for the iodine increases. In a system with the entire spin being uniform, the spectrum height shows a saturation phenomenon against increase in microwave output. A non-uniform system, in which the oriented spin forms small groups and is in local thermal equilibrium, does not show saturation, but increases monotonously. 2 refs., 5 figs.

  12. Microwave treatment of a brown coal concentrate from Mugunsk coal for the manufacture of sponge iron

    Energy Technology Data Exchange (ETDEWEB)

    A.A. Khaidurova; P.N. Konovalov; N.P. Konovalov [Irkutsk State Technical University, Irkutsk (Russia)

    2008-04-15

    A technique for the production of a finely dispersed dry brown coal concentrate with the use of microwave energy is proposed to prepare a charge mixture for the manufacture of sponge iron. The advantages of this technique over analogous industrial processes are demonstrated. The results of experiments on the briquetting of the charge mixture of brown coal and iron ore concentrates without the use of an additional binding agent are described.

  13. Comparison of three-dimensional printing and vacuum freeze-dried techniques for fabricating composite scaffolds

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Kai [Tianjin First Center Hospital, No. 24 Fukang Road, Tianjin, TJ 300192 (China); Li, Ruixin [Institute of Medical Equipment, Academy of Military and Medical Sciences, No. 106, Wandong Street, Hedong District, Tianjin 300000 (China); Jiang, Wenxue, E-mail: jiangortholivea@sina.cn [Tianjin First Center Hospital, No. 24 Fukang Road, Tianjin, TJ 300192 (China); Sun, Yufu [Tianjin First Center Hospital, No. 24 Fukang Road, Tianjin, TJ 300192 (China); Li, Hui [Tianjin Medical University General Hospital, No. 154 Anshan Road, Tianjin, TJ 300052 (China)

    2016-09-02

    In this study, the performances of different preparation methods of the scaffolds were analyzed for chondrocyte tissue engineering. Silk fibroin/collagen (SF/C) was fabricated using a vacuum freeze-dried technique and by 3D printing. The porosity, water absorption expansion rates, mechanical properties, and pore sizes of the resulting materials were evaluated. The proliferation and metabolism of the cells was detected at different time points using an MTT assay. Cell morphologies and distributions were observed by histological analysis and scanning electron microscopy (SEM). The porosity, water absorption expansion rate, and Young’s modulus of the material obtained via 3D printing were significantly higher than those obtained by the freeze-dried method, while the pore size did not differ significantly between the two methods. MTT assay results showed that the metabolism of cells seeded on the 3D printed scaffolds was more viable than the metabolism on the freeze-dried material. H&E staining of the scaffolds revealed that the number of cells in the 3D printed scaffold was higher in comparison to a similar measurement on the freeze-dried material. Consequently, stem cells grew well inside the 3D printed scaffolds, as measured by SEM, while the internal structure of the freeze-dried scaffold was disordered. Compared with the freeze-dried technique, the 3D printed scaffold exhibited better overall performance and was more suitable for cartilage tissue engineering. - Highlights: • Silk fibroin/collagen was fabricated using 3D printing. • Physical characterization and Cell compatibility were compared. • 3D printed scaffold exhibited better overall performance.

  14. Comparison of three-dimensional printing and vacuum freeze-dried techniques for fabricating composite scaffolds

    International Nuclear Information System (INIS)

    Sun, Kai; Li, Ruixin; Jiang, Wenxue; Sun, Yufu; Li, Hui

    2016-01-01

    In this study, the performances of different preparation methods of the scaffolds were analyzed for chondrocyte tissue engineering. Silk fibroin/collagen (SF/C) was fabricated using a vacuum freeze-dried technique and by 3D printing. The porosity, water absorption expansion rates, mechanical properties, and pore sizes of the resulting materials were evaluated. The proliferation and metabolism of the cells was detected at different time points using an MTT assay. Cell morphologies and distributions were observed by histological analysis and scanning electron microscopy (SEM). The porosity, water absorption expansion rate, and Young’s modulus of the material obtained via 3D printing were significantly higher than those obtained by the freeze-dried method, while the pore size did not differ significantly between the two methods. MTT assay results showed that the metabolism of cells seeded on the 3D printed scaffolds was more viable than the metabolism on the freeze-dried material. H&E staining of the scaffolds revealed that the number of cells in the 3D printed scaffold was higher in comparison to a similar measurement on the freeze-dried material. Consequently, stem cells grew well inside the 3D printed scaffolds, as measured by SEM, while the internal structure of the freeze-dried scaffold was disordered. Compared with the freeze-dried technique, the 3D printed scaffold exhibited better overall performance and was more suitable for cartilage tissue engineering. - Highlights: • Silk fibroin/collagen was fabricated using 3D printing. • Physical characterization and Cell compatibility were compared. • 3D printed scaffold exhibited better overall performance.

  15. Reduction in energy consumption and operating cost in a dried corn warehouse using logistics techniques

    Directory of Open Access Journals (Sweden)

    Korrakot Y. Tippayawong

    2013-06-01

    Full Text Available Corn is one of the major economic crops in Thailand. Corn postharvest operation involves various practices that consume a large amount of energy. Different energy conservation measures have been implemented but logistics consideration is not normally employed. In this work, attempt has been made to demonstrate that logistics techniques can offer a significant reduction in energy and cost. The main objective of this work is to identify and demonstrate possible approaches to improving energy efficiency and reducing operating cost for a dried corn warehouse operator. Three main problems are identified: (i relatively high fuel consumption for internal transfer process, (ii low quality of dried corn, and (iii excess expenditure on outbound transportation. Solutions are proposed and implemented using logistics operations. Improvement is achieved using plant layout and shortest path techniques, resulting in a reduction of almost 50% in energy consumption for the internal transfer process. Installation of an air distributor in the grain storage unit results in a decrease in loss due to poor-quality dried corn from 17% to 10%. Excess expenditure on dried corn distribution is reduced by 6% with application of a global positioning system.

  16. Study of Photosensitive Dry Films Absorption for Printed Circuit Boards by Photoacoustic Technique

    Science.gov (United States)

    Hernández, R.; Zaragoza, J. A. Barrientos; Jiménez-Pérez, J. L.; Orea, A. Cruz; Correa-Pacheco, Z. N.

    2017-08-01

    In this work, the study of photosensitive dry-type films by photoacoustic technique is proposed. The dry film photoresist is resistant to chemical etching for printed circuit boards such as ferric chloride, sodium persulfate or ammonium, hydrochloric acid. It is capable of faithfully reproducing circuit pattern exposed to ultraviolet light (UV) through a negative. Once recorded, the uncured portion is removed with alkaline solution. It is possible to obtain good results in surface mount circuits with tracks of 5 mm. Furthermore, the solid resin films are formed by three layers, two protective layers and a UV-sensitive optical absorption layer in the range of 325 nm to 405 nm. By means of optical absorption of UV-visible rays emitted by a low-power Xe lamp, the films transform this energy into thermal waves generated by the absorption of optical radiation and subsequently no-radiative de-excitation occurs. The photoacoustic spectroscopy is a useful technique to measure the transmittance and absorption directly. In this study, the optical absorption spectra of the three layers of photosensitive dry-type films were obtained as a function of the wavelength, in order to have a knowledge of the absorber layer and the protective layers. These analyses will give us the physical properties of the photosensitive film, which are very important in curing the dry film for applications in printed circuit boards.

  17. Preparation and characterization of etoricoxib solid dispersions using lipid carriers by spray drying technique

    OpenAIRE

    Chauhan, Bhaskar; Shimpi, Shyam; Paradkar, Anant

    2005-01-01

    The basic objectives of this study were to prepare and characterize solid dispersions of poorly water-soluble drug etoricoxib using lipid carriers by spray drying technique. The properties of solid dispersions were studied by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), differential scanning calorimetry (DSC), hotstage microscopy (HSM), radiograph powder diffraction (XRPD), and dissolution studies. The absence of etoricoxib peaks in XRPD profiles of solid dispersions ...

  18. Development of clean coal and clean soil technologies using advanced agglomeration techniques

    International Nuclear Information System (INIS)

    Ignasiak, B.; Ignasiak, T.; Szymocha, K.

    1990-01-01

    Three major topics are discussed in this report: (1) Upgrading of Low Rank Coals by the Agflotherm Process. Test data, procedures, equipment, etc., are described for co-upgrading of subbituminous coals and heavy oil; (2) Upgrading of Bituminous Coals by the Agflotherm Process. Experimental procedures and data, bench and pilot scale equipments, etc., for beneficiating bituminous coals are described; (3) Soil Clean-up and Hydrocarbon Waste Treatment Process. Batch and pilot plant tests are described for soil contaminated by tar refuse from manufactured gas plant sites. (VC)

  19. Coal - 96

    International Nuclear Information System (INIS)

    Sparre, C.

    1996-09-01

    The report deals mainly with coal consumption, but also gives some information about technology, environmental aspects and markets. Data have been collected by questionnaires or via telephone. The use of steam coal for heating was 0.8 Mtons (down 20% from 1994). Cogeneration plants were the main users. Taxes and environmental reasons cause a reduction of the coal use that will probably continue the next years. Use of steam coal in industry has been constant at a level of 0.7 Mtons. The import of metallurgical coal rests constant at a level of 1.6 Mtons. 1.2 Mtons of coke was produced, and 0.3 Mtons imported. The PFBC-plant at Vaertan, Stockholm used 0.13 Mtons of coal, while some coal fired power plants have been converted to peat and wood fuels. The average price of steam coal imported to Sweden in 1995 was 333 SEK/ton, 6% higher than in 1994. The contract prices for delivery 1996 are about the same as at the end of 1995. All cogeneration plants have some sort of SO 2 removal system, mostly wet-dry. The largest plant, at Vaesteraas, has recently invested in a SCR system for NO x removal. Most other plants are using low NO x burners or SNCR systems, based on ammonia or urea, which reduce the emissions 50 - 70%. Some statistic about the world coal market is also given in the report

  20. Coal -94

    International Nuclear Information System (INIS)

    Sparre, C.

    1994-05-01

    This report deals with use of coal and coke during 1993; information about techniques, environmental questions and markets are also given. Use of steamcoal for heating purposes has been reduced about 3 % during 1993 to 1,0 mill tons. This is the case especially for the heat generating boilers. Production in co-generation plants has been constant and has increased for electricity production. Minor plants have increased their use of forest fuels, LPG and NG. Use of steamcoal will probably go down in the immediate years both in heat generating and co-generating plants. Coal-based electricity has been imported from Denmark during 1993 corresponding to about 400 000 tons of coal, when several of our nuclear plants were stopped. Use of steamcoal in the industry has been constant at 700 000 tons. This level is supposed to be constant or to vary with business cycles. The import of metallurgical coal in 1993 was 1,6 mill tons like the year before. 1,2 mill tons coke were produced. Coke consumption in industry was 1,4 mill tons. 0,2 mill tons of coke were imported. Average price of steamcoal imported to Sweden in 1993 was 308 SEK/ton or 13 % higher than in 1992; this can be explained by the dollar price level increasing 34% in 1993. For the world, the average import price was 50,0 USD/ton, a decrease of 6 %. The coal market during 1993 was affected by less consumption in Europe, shut downs of European mines and decreasing prices. High freight price raises in Russia has affected the Russian export and the market in northern Europe. The prices have been stabilized recently. All Swedish plants meet emission limits of dust, SO 2 and NO x . Co-generation plants all have some sort of SO 2 -removal system; the wet-dry method is mostly used. A positive effect of the recently introduced NO x -duties is a 40% reduction

  1. Utilization of spray drying technique for improvement of dissolution and anti-inflammatory effect of Meloxicam.

    Science.gov (United States)

    Shazly, Gamal; Badran, Mohamed; Zoheir, Khairy; Alomrani, Abdullah

    2015-01-01

    Meloxicam (MLX) is a poorly water-soluble non steroidal anti-inflammatory drug (NSAID). The main objective of the present work was to enhance the dissolution of MLX and thus its bioavailability by the aid of additives. The novelty of this work rises from the utilization of spray drying technology to produce micro particulates solid dispersion systems containing MLX in the presence of small amount of additives. Differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FT-IR), and Scan Electron Microscope (SEM) were used for studying the physico-chemical and morphological properties of MLX samples. The dissolution of MLX samples was investigated in two different pH media. The morphology of MLX solid dispersion micro-particles was spherical in shape according to SEM. FT-IR profiles indicated that a complex was formed between MLX and the additives. DSC patterns of the MLX micro-particles suggested a reduction in the crystallinity of MLX and probability of presence of an interaction between MLX and the additives. The rate of dissolution of the spray-dried MLX enhanced as compared with the unprocessed MLX in both acidic and neutral media. It was found that 100% of the added MLX released within 5 min in phosphate buffer dissolution medium (pH 7.4) compared to that of the unprocessed MLX (15% in 60 min). Such increase rate in the dissolution of the spray dried MLX could be attributed to the increase in wettability of MLX particles and the hydrophilic nature of the additives. The anti-inflammatory effect of the spray dried MLX was explored using formalin induced rat paw edema model. The spray-dried samples showed an increase in the anti-inflammatory activity of MLX as compared to the unprocessed MLX. This work reveals that the spray drying technique is suitable for preparation of micro-particles with improved dissolution and anti-inflammatory effect of MLX.

  2. Investigation of flow behaviour of coal particles in a pilot-scale fluidized bed gasifier (FBG) using radiotracer technique.

    Science.gov (United States)

    Pant, H J; Sharma, V K; Kamudu, M Vidya; Prakash, S G; Krishanamoorthy, S; Anandam, G; Rao, P Seshubabu; Ramani, N V S; Singh, Gursharan; Sonde, R R

    2009-09-01

    Knowledge of residence time distribution (RTD), mean residence time (MRT) and degree of axial mixing of solid phase is required for efficient operation of coal gasification process. Radiotracer technique was used to measure the RTD of coal particles in a pilot-scale fluidized bed gasifier (FBG). Two different radiotracers i.e. lanthanum-140 and gold-198 labeled coal particles (100 gm) were independently used as radiotracers. The radiotracer was instantaneously injected into the coal feed line and monitored at the ash extraction line at the bottom and gas outlet at the top of the gasifier using collimated scintillation detectors. The measured RTD data were treated and MRTs of coal/ash particles were determined. The treated data were simulated using tanks-in-series model. The simulation of RTD data indicated good degree of mixing with small fraction of the feed material bypassing/short-circuiting from the bottom of the gasifier. The results of the investigation were found useful for optimizing the design and operation of the FBG, and scale-up of the gasification process.

  3. Material accountancy measurement techniques in dry-powdered processing of nuclear spent fuels

    International Nuclear Information System (INIS)

    Wolf, S. F.

    1999-01-01

    The paper addresses the development of inductively coupled plasma-mass spectrometry (ICPMS), thermal ionization-mass spectrometry (TIMS), alpha-spectrometry, and gamma spectrometry techniques for in-line analysis of highly irradiated (18 to 64 GWD/T) PWR spent fuels in a dry-powdered processing cycle. The dry-powdered technique for direct elemental and isotopic accountancy assay measurements was implemented without the need for separation of the plutonium, uranium and fission product elements in the bulk powdered process. The analyses allow the determination of fuel burn-up based on the isotopic composition of neodymium and/or cesium. An objective of the program is to develop the ICPMS method for direct fissile nuclear materials accountancy in the dry-powdered processing of spent fuel. The ICPMS measurement system may be applied to the KAERI DUPIC (direct use of spent PWR fuel in CANDU reactors) experiment, and in a near-real-time mode for international safeguards verification and non-proliferation policy concerns

  4. MERCURY CONTROL IN MUNICIPAL WASTE COMBUSTORS AND COAL-FIRED UTILITIES

    Science.gov (United States)

    Control of mercury (Hg) emissions from municipal waste combustors (MWCs) and coal-fired utilities has attracted attention due to current and potential regulations. Among several techniques evaluated for Hg control, dry sorbent injection (primarily injection of activated carbon) h...

  5. Spherical nanostructured Si/C composite prepared by spray drying technique for lithium ion batteries anode

    International Nuclear Information System (INIS)

    Chen Libao; Xie Xiaohua; Wang Baofeng; Wang Ke; Xie Jingying

    2006-01-01

    Spherical nanostructured Si/C composite was prepared by spray drying technique, followed by heat treatment, in which nanosized silicon and fine graphite particles were homogeneously embedded in carbon matrix pyrolyzed by phenol formaldehyde resin. Cyclic voltammetry tests showed two pairs of redox peaks corresponding to lithiation and delithiation of Si/C composite. The Si/C composite exhibited a reversible capacity of 635 mAh g -1 and good cycle performance used in lithium ion batteries. To improve cycle performance of this Si/C composite further, the carbon-coated Si/C composite was synthesized by the second spray drying and heat treatment processing. The cycle performance of carbon-coated Si/C composite was improved significantly, which was attributed to the formation of stable SEI passivation layers on the outer surface of carbon shell which protected the bared silicon from exposing to electrolyte directly

  6. Spherical nanostructured Si/C composite prepared by spray drying technique for lithium ion batteries anode

    Energy Technology Data Exchange (ETDEWEB)

    Chen Libao [Energy Science and Technology Laboratory, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Graduate School of Chinese Academy of Sciences, Beijing 100049 (China); Xie Xiaohua [Energy Science and Technology Laboratory, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Graduate School of Chinese Academy of Sciences, Beijing 100049 (China); Wang Baofeng [Department of Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Wang Ke [Energy Science and Technology Laboratory, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Xie Jingying [Energy Science and Technology Laboratory, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China) and Graduate School of Chinese Academy of Sciences, Beijing 100049 (China)]. E-mail: jyxie@mail.sim.ac.cn

    2006-07-15

    Spherical nanostructured Si/C composite was prepared by spray drying technique, followed by heat treatment, in which nanosized silicon and fine graphite particles were homogeneously embedded in carbon matrix pyrolyzed by phenol formaldehyde resin. Cyclic voltammetry tests showed two pairs of redox peaks corresponding to lithiation and delithiation of Si/C composite. The Si/C composite exhibited a reversible capacity of 635 mAh g{sup -1} and good cycle performance used in lithium ion batteries. To improve cycle performance of this Si/C composite further, the carbon-coated Si/C composite was synthesized by the second spray drying and heat treatment processing. The cycle performance of carbon-coated Si/C composite was improved significantly, which was attributed to the formation of stable SEI passivation layers on the outer surface of carbon shell which protected the bared silicon from exposing to electrolyte directly.

  7. Drying of lucuma (Pouteria obovata using the technique of Refracting WindowTM

    Directory of Open Access Journals (Sweden)

    Diego Gamboa

    2014-06-01

    Full Text Available Lucuma is a fruit that is experiencing a growing trend in commercial ground into flour for use in the food industry. This study aimed to obtain lucuma flour using the method of refractive window drying and evaluate the effect of the thickness of lucuma pulp and drying time on flour moisture and color. It was used a Composite Design Central Rotary (DCCR with time between 10 and 50 min and the thickness between 1 and 3 mm. A fixed temperature of 95 °C and mylar film (metallized polyethylene terephthalate as a refractory film of 0.1 mm was used. It was determined that the optimal conditions for lucuma flour (9.8% moisture with this technique is when the thickness was 1.3 mm and with a time of 15 minutes; in these conditions, the effective diffusivity of water is 2.53 E-7 m2 /s.

  8. Effect of different drying techniques on bioactive components, fatty acid composition, and volatile profile of robusta coffee beans.

    Science.gov (United States)

    Dong, Wenjiang; Hu, Rongsuo; Chu, Zhong; Zhao, Jianping; Tan, Lehe

    2017-11-01

    This study investigated the effect of different drying techniques, namely, room-temperature drying (RTD), solar drying (SD), heat-pump drying (HPD), hot-air drying (HAD), and freeze drying (FD), on bioactive components, fatty acid composition, and the volatile compound profile of robusta coffee beans. The data showed that FD was an effective method to preserve fat, organic acids, and monounsaturated fatty acids. In contrast, HAD was ideal for retaining polyunsaturated fatty acids and amino acids. Sixty-two volatile compounds were identified in the differently dried coffee beans, representing 90% of the volatile compounds. HPD of the coffee beans produced the largest number of volatiles, whereas FD resulted in the highest volatile content. A principal component analysis demonstrated a close relationship between the HPD, SD, and RTD methods whereas the FD and HAD methods were significantly different. Overall, the results provide a basis for potential application to other similar thermal sensitive materials. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Microparticles containing guaraná extract obtained by spray-drying technique: development and characterization

    Directory of Open Access Journals (Sweden)

    Traudi Klein

    Full Text Available AbstractGuaraná (Paullinia cupana Kunth, Sapindaceae is well known for its dietary and pharmaceutical potential, and the semipurified extract of guaraná shows antidepressant and panicolytic effects. However, the low solubility, bioavailability and stability of the semipurified extract limit its use as a component of pharmaceutical agents. Delivery of the semipurified extract in a microparticle form could help to optimize its stability. In this study, microparticles containing semipurified extract of guaraná were obtained by the spray-drying technique, using a combination of maltodextrin and gum arabic. The raw materials and microparticles produced were characterized by particle size analysis, differential scanning calorimetry, thermogravimetric analysis, and scanning electron microscopy. The drug content and antioxidant capacity were also evaluated. In vitrodissolution tests using flow cell dissolution apparatus, were carried out to investigate the influence of formulation parameters on the release of semipurified extract of guaraná from the microparticles. The spray-drying technique and the processing conditions selected gave satisfactory encapsulation efficiency (80–110% and product yield (55–60%. The mean diameter of microparticles was around 4.5 µm. The DPPH radical scavenging capacity demonstrated that microparticles can protect the semipurified extract of guaraná from the effect of high temperatures during the process maintained the antioxidant capacity. Differential scanning calorimetry results indicated an interaction between semipurified extract of guaraná and gum arabic: maltodextrin in the microparticles, and thermogravimetric analysis indicate that the profile curves of the microparticles are similar to the adjuvants used in drying, probably due to the higher proportion of adjuvants compared to semipurified extract of guaraná. In vitro dissolution tests demonstrate that all formulations complete dissolution within 60 min

  10. Trace elements and As speciation analysis of fly ash samples from an Indonesian coal power plant by means of neutron activation analysis and synchrotron based techniques

    International Nuclear Information System (INIS)

    Muhayatun Santoso; Diah Dwiana Lestiani; Endah Damastuti; Syukria Kurniawat; Bennett, J.W.; Juan Jose Leani; Mateusz Czyzycki; Alessandro Migliori; Germanos Karydas, Andreas

    2016-01-01

    The elemental characterization of coal fly ash samples is required to estimate the coal burning emissions into the environment and to assess the potential impact into the biosphere. Fly ash samples collected from a coal fired power plant in center Java, Indonesia were characterized by instrumental neutron activation analysis at two different facilities (BATAN, ANSTO) and synchrotron based techniques at Elettra Italy. Assessment of thirty (30) elements and an investigation of the potential toxicity of As species in coal fly ash were presented. The results obtained are discussed and compared with those reported from other regions of the world. (author)

  11. Preparation of redispersible liposomal dry powder using an ultrasonic spray freeze-drying technique for transdermal delivery of human epithelial growth factor.

    Science.gov (United States)

    Yin, Fei; Guo, Shiyan; Gan, Yong; Zhang, Xinxin

    2014-01-01

    In this work, an ultrasonic spray freeze-drying (USFD) technique was used to prepare a stable liposomal dry powder for transdermal delivery of recombinant human epithelial growth factor (rhEGF). Morphology, particle size, entrapment efficiency, in vitro release, and skin permeability were systematically compared between rhEGF liposomal dry powder prepared using USFD and that prepared using a conventional lyophilization process. Porous and spherical particles with high specific area were produced under USFD conditions. USFD effectively avoided formation of ice crystals, disruption of the bilayer structure, and drug leakage during the liposome drying process, and maintained the stability of the rhEGF liposomal formulation during storage. The reconstituted rhEGF liposomes prepared from USFD powder did not show significant changes in morphology, particle size, entrapment efficiency, or in vitro release characteristics compared with those of rhEGF liposomes before drying. Moreover, the rhEGF liposomal powder prepared with USFD exhibited excellent enhanced penetration in ex vivo mouse skin compared with that for powder prepared via conventional lyophilization. The results suggest that ultrasonic USFD is a promising technique for the production of stable protein-loaded liposomal dry powder for application to the skin.

  12. Development and application of a dry ultramicrotomy technique for the preparation of galvanneal sheet coatings.

    Science.gov (United States)

    Barreto, M P; Veillette, R; L'Espérance, G

    1995-07-01

    The formability of galvanneal steel sheets used in the automotive industry is influenced by the presence and distribution of brittle and difficult to distinguish Zn-Fe intermetallics in the coating. Characterization of these intermetallics requires a high spatial resolution technique such as analytical transmission electron microscopy (ATEM). Sample preparation by ion milling is impossible due to iron redeposition, and traditional ultramicrotomy using water affects the coating chemistry. A technique based on dry ultramicrotomy has therefore been developed. To optimize the technique, different parameters (knife angle, cutting medium, thickness setting on the ultramicrotome, cutting speed) have been investigated for the preparation of galvanneal coatings and pure A1 sections. Results show that dry cutting does not affect the coating chemistry but shortens the life of the knife. Knife quality (cleanliness, sharpness and absence of defects) is a major factor to obtain good dry sections. The best results for the more ductile pure A1 are obtained with a 35 degrees knife whilst for the harder galvanneal coating it is recommended to use a 55 degrees knife. These results suggest that the sectioning mechanism for the harder material involves more a cleavage-fracture mechanism whilst a greater amount of shear is involved when sectioning relatively ductile A1. The optimum parameters for sectioning galvanneal coatings are established and results obtained by parallel electron energy loss spectrum imaging and energy dispersive X-ray spectrometry in the TEM are given. This study shows that with a good control of all the sectioning parameters it is possible to obtain good sections repeatedly and rapidly.

  13. Neutron and gamma-ray transmission technique for the on-line determination of moisture in coal and coke

    International Nuclear Information System (INIS)

    Sowerby, B.D.; Millen, M.J.; Rafter, P.T.

    1985-01-01

    A fast neutron and gamma-ray transmission technique is being developed for the on-line analysis of moisture in coal and coke. The technique utilises 252 Cf and 137 Cs sources and 3 He and NaI(Tl) detectors. Laboratory measurements on single coal samples have shown that moisture can be determined to better than 1 wt% over the range 0 to 16 wt% moisture and 5 to 17cm thickness. Reduced errors were obtained for restricted ranges of moisture and thickness. Preliminary measurements on coke of thickness 30 to 50cm have shown that moisture can be determined to within 0.26 wt% over the range 1 to 16 wt% moisture

  14. Chemical stability of fluorine-containing coatings of cold drying for radiation - protection technique articles

    International Nuclear Information System (INIS)

    Shigorina, I.I.; Zvyagintseva, N.V.; Egorov, B.N.

    1977-01-01

    The chemical stability of fluorolon coatings, which are not subjected to heat treatment or hot drying during application, has been studied. The test for layer life-time has been performed by submerging specimens in agressive medium. The time for one upper removable layer to fail under steady action of agressive liquid is found to be: > 12 months at 20 deg C, 6-9 months at 40 deg C; at 60 deg C the time of layer stability depends upon medium: 1 month for nitric, 2 months for acetic, 2-3 months for sulphuric and hydrochloric acid. The coatings are recommended for practical application in radiation-protective technique

  15. Structural characterization of graphene layers in various Indian coals by X-Ray Diffraction technique

    Science.gov (United States)

    Manoj, B.; Kunjomana, A. G.

    2015-02-01

    The results of the structural investigation of three Indian coals showed that, the structural parameters like fa & Lc increased where as interlayer spacing d002 decreased with increase in carbon content, aromaticity and coal rank. These structural parameters change just opposite with increase in volatile matter content. Considering the 'turbostratic' structure for coals, the minimum separation between aromatic lamellae was found to vary between 3.34 to 3.61 A° for these coals. As the aromaticity increased, the interlayer spacing decreased an indication of more graphitization of the sample. Volatile matter and carbon content had a strong influence on the aromaticity, interlayer spacing and stacking height on the sample. The average number of carbon atoms per aromatic lamellae and number of layers in the lamellae was found to be 16-21 and 7-8 for all the samples.

  16. Experimental techniques for characterising water in wood covering the range from dry to fully water-saturated

    DEFF Research Database (Denmark)

    Thybring, Emil Engelund; Kymäläinen, Maija; Rautkari, Lauri

    2018-01-01

    focuses on selected experimental techniques that can give deeper insights into various aspects of water in wood in the entire moisture domain from dry to fully water-saturated. These techniques fall into three broad categories: (1) gravimetric techniques that determine how much water is absorbed, (2...

  17. Dry sliding wear behavior of heat treated hybrid metal matrix composite using Taguchi techniques

    International Nuclear Information System (INIS)

    Kiran, T.S.; Prasanna Kumar, M.; Basavarajappa, S.; Viswanatha, B.M.

    2014-01-01

    Highlights: • ZA-27 alloy is used as matrix material and reinforced with SiC and Gr particles. • Heat treatment was carried out for all specimen. • Dry sliding wear test was done on pin-on-disc apparatus by Taguchi technique. • ZA-27/9SiC–3Gr showed superior wear resistance over the base alloy. • Ceramic mixed mechanical layer on contact surface of composite was formed. - Abstract: Dry sliding wear behavior of zinc based alloy and composite reinforced with SiCp (9 wt%) and Gr (3 wt%) fabricated by stir casting method was investigated. Heat treatment (HT) and aging of the specimen were carried out, followed by water quenching. Wear behavior was evaluated using pin on disc apparatus. Taguchi technique was used to estimate the parameters affecting the wear significantly. The effect of HT was that it reduced the microcracks, residual stresses and improved the distribution of microconstituents. The influence of various parameters like applied load, sliding speed and sliding distance on wear behavior was investigated by means and analysis of variance (ANOVA). Further, correlation between the parameters was determined by multiple linear regression equation for each response. It was observed that the applied load significantly influenced the wear volume loss (WVL), followed by sliding speed implying that increase in either applied load or sliding speed increases the WVL. Whereas for composites, sliding distance showed a negative influence on wear indicating that increase in sliding distance reduces WVL due to the presence of reinforcements. The wear mechanism of the worn out specimen was analyzed using scanning electron microscopy. The analysis shows that the formation and retention of ceramic mixed mechanical layer (CMML) plays a major role in the dry sliding wear resistance

  18. Color measurement of tea leaves at different drying periods using hyperspectral imaging technique.

    Science.gov (United States)

    Xie, Chuanqi; Li, Xiaoli; Shao, Yongni; He, Yong

    2014-01-01

    This study investigated the feasibility of using hyperspectral imaging technique for nondestructive measurement of color components (ΔL*, Δa* and Δb*) and classify tea leaves during different drying periods. Hyperspectral images of tea leaves at five drying periods were acquired in the spectral region of 380-1030 nm. The three color features were measured by the colorimeter. Different preprocessing algorithms were applied to select the best one in accordance with the prediction results of partial least squares regression (PLSR) models. Competitive adaptive reweighted sampling (CARS) and successive projections algorithm (SPA) were used to identify the effective wavelengths, respectively. Different models (least squares-support vector machine [LS-SVM], PLSR, principal components regression [PCR] and multiple linear regression [MLR]) were established to predict the three color components, respectively. SPA-LS-SVM model performed excellently with the correlation coefficient (rp) of 0.929 for ΔL*, 0.849 for Δa*and 0.917 for Δb*, respectively. LS-SVM model was built for the classification of different tea leaves. The correct classification rates (CCRs) ranged from 89.29% to 100% in the calibration set and from 71.43% to 100% in the prediction set, respectively. The total classification results were 96.43% in the calibration set and 85.71% in the prediction set. The result showed that hyperspectral imaging technique could be used as an objective and nondestructive method to determine color features and classify tea leaves at different drying periods.

  19. Color measurement of tea leaves at different drying periods using hyperspectral imaging technique.

    Directory of Open Access Journals (Sweden)

    Chuanqi Xie

    Full Text Available This study investigated the feasibility of using hyperspectral imaging technique for nondestructive measurement of color components (ΔL*, Δa* and Δb* and classify tea leaves during different drying periods. Hyperspectral images of tea leaves at five drying periods were acquired in the spectral region of 380-1030 nm. The three color features were measured by the colorimeter. Different preprocessing algorithms were applied to select the best one in accordance with the prediction results of partial least squares regression (PLSR models. Competitive adaptive reweighted sampling (CARS and successive projections algorithm (SPA were used to identify the effective wavelengths, respectively. Different models (least squares-support vector machine [LS-SVM], PLSR, principal components regression [PCR] and multiple linear regression [MLR] were established to predict the three color components, respectively. SPA-LS-SVM model performed excellently with the correlation coefficient (rp of 0.929 for ΔL*, 0.849 for Δa*and 0.917 for Δb*, respectively. LS-SVM model was built for the classification of different tea leaves. The correct classification rates (CCRs ranged from 89.29% to 100% in the calibration set and from 71.43% to 100% in the prediction set, respectively. The total classification results were 96.43% in the calibration set and 85.71% in the prediction set. The result showed that hyperspectral imaging technique could be used as an objective and nondestructive method to determine color features and classify tea leaves at different drying periods.

  20. Production of dried shrimp mixed with turmeric and salt by Spouted Bed technique enter the rectangular chamber.

    Science.gov (United States)

    Thanthong, P.; Mustafa, Y.; Ngamrungroj, D.

    2017-09-01

    Today, dried shrimp in the market were refused food colour and drying until shrimp are colourful and tasty. Meanwhile, Community groups, women’s health trying to produce food products come from herbs. As an alternative to consumers. The production process is also a traditional way to dry. In order to extend the shelf life longer. Sometimes, potential risks, both in quality and quantity of products. As a result, consumers are enormous. Thus, this research aims to study the possibility to produce shrimp dried mixed with turmeric and salt. Then dried shrimp mixed with turmeric and salt to keep up the quality criteria of the Food and Drug Administration-FDA It can reduce the risk of the consumer and can keep up in a kitchen Thailand. When buying shrimp from the fisherman’s boat Will be made clear, clean impurities and shaking the sand to dry. Prepare a mixture of turmeric and salt. The shrimp were dipped into a beef with stirrer for 3 minutes. And scoop up centrifugal shrimp with dried. Measurement of initial moisture content averaging 78%wb. Then drying technique Spouted enter the rectangular chamber a continuous manner. Until average moisture content to 17%wb. The air temperature in the drying chamber at 180 °C and hot air speed 4.5 m/s, a state heat transfer Mass and moisture within the shrimp. In chamber when drying, the shrimp have moved freely behaviour can spit water out faster does not burn. Shaving legs of shrimp shell fragments lightweight is sorting out the top of drying chamber. Private shrimp were dried out to the front of the quad drying chamber. Power consumption 27.5 MJ/kg, divided into electrical energy 12.3 MJ/kg and thermal energy is 15.2 MJ/kg. The hot air comes from burning LPG gas burner with dual automatic. And can adjustable to room temperature drying characteristics modulation setting.

  1. Reduction of SO{sub 2} Emissions in coal power plants by means of spray-drying RESOX; Reduccion de Emisiones de SO{sub 2} en Centrales Termicas de Carbon Mediante Spary Drying

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-31

    In this experimental study, two important matters concerning the spray-drying technology for the desulphurisation of combustion gases, from pulverized coal boilers, have been analyzed: (1) the behaviour of the spray-dryer absorber under different operating conditions and (2) the behaviour of an electrostatic precipitator that operates downstream from a spray-dryer. The results of this project are of great interest for evaluating the application of this semi-dry desulphurisation technology in existing power plants that already have electrostatic precipitators. Additionally, the conclusions drawn are useful for establishing the optimum design and operating conditions for an integrated SD-ESP flue gas treatment facility. More than 45 experimental tests have been conducted on a 10,000 Nm``3/h spray-drying desulphurisation pilot plant. The effects of SO{sub 2} and fly ash concentration, Ca/s ratio, approach to saturation temperature, density of the slurry and unit load changes on both spray dryer behaviour and treated flue gas properties have been analyzed. In two additional specific tests, the effect of injecting calcium chloride and of preparing the slurry with seawater has also been studied. The impact of spray-dryer desulphurization on the behaviour of the electrostatic precipitators has been evaluated comparing experimental data (Efficiency, emission level, electrical consumption) for the behaviour of the electrostatic precipitator, obtained in two different experimental conditions: with and without desulphurization. Additionally, the possibility of reducing the power consumption of the precipitator by means of intermittent energization has been analyzed. (Author)

  2. Summary of FY 1980 results of Sunshine Project. Development of coal liquefaction techniques; 1980 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho. Sunshine keikaku itaku kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    This report summarizes the results of the 3 R and D themes for coal liquefaction techniques, pursued by the Sunshine Project; (1) development of solvent extraction type liquefaction plant, and brown coal liquefaction technique R and D demonstration surveys, (2) development of solvolysis type liquefaction plant, and (3) development of direct hydrogenation type liquefaction plant. For the theme (1), the 1 T/D test plant, solid/liquid separator and small-size continuous settlement separator are constructed, and partly completed. The elementary studies include solvent extraction type liquefaction process, materials for coal liquefaction plant and solid/liquid separation. Australia's Victoria brown coal and Chinese coal are studied to clarify the possible problems involved in liquefaction of these coal species for commercialization of the liquefaction techniques in the early stage. The elementary techniques studied include dehydration of brown coal, milling at high temperature in oil, de-ashing, and secondary and primary hydrogenation. For the theme (2), the 1 T/D plant is inspected and maintained to clarify the problems involved in the continuous operation, revamped and repaired as necessary, given preventive maintenance, and tested for operability confirmation. The elementary studies include solvolysis type liquefaction process, scale-up, hydrogenation plant for solvolysis pitch. For the item (3), the 2.4 T/D test plant is constructed, and the elementary studies are conducted, for, e.g., liquefaction reactions in the presence of an iron-based catalyst. (NEDO)

  3. Summary of FY 1980 results of Sunshine Project. Development of coal liquefaction techniques; 1980 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho. Sunshine keikaku itaku kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    This report summarizes the results of the 3 R and D themes for coal liquefaction techniques, pursued by the Sunshine Project; (1) development of solvent extraction type liquefaction plant, and brown coal liquefaction technique R and D demonstration surveys, (2) development of solvolysis type liquefaction plant, and (3) development of direct hydrogenation type liquefaction plant. For the theme (1), the 1 T/D test plant, solid/liquid separator and small-size continuous settlement separator are constructed, and partly completed. The elementary studies include solvent extraction type liquefaction process, materials for coal liquefaction plant and solid/liquid separation. Australia's Victoria brown coal and Chinese coal are studied to clarify the possible problems involved in liquefaction of these coal species for commercialization of the liquefaction techniques in the early stage. The elementary techniques studied include dehydration of brown coal, milling at high temperature in oil, de-ashing, and secondary and primary hydrogenation. For the theme (2), the 1 T/D plant is inspected and maintained to clarify the problems involved in the continuous operation, revamped and repaired as necessary, given preventive maintenance, and tested for operability confirmation. The elementary studies include solvolysis type liquefaction process, scale-up, hydrogenation plant for solvolysis pitch. For the item (3), the 2.4 T/D test plant is constructed, and the elementary studies are conducted, for, e.g., liquefaction reactions in the presence of an iron-based catalyst. (NEDO)

  4. [Preparation of citrulline microspheres by spray drying technique for colonic targeting].

    Science.gov (United States)

    Bahri, S; Zerrouk, N; Lassoued, M-A; Tsapis, N; Chaumeil, J-C; Sfar, S

    2014-03-01

    Citrulline is an amino acid that becomes essential in situations of intestinal insufficiency such as short bowel syndrome. It is therefore interesting to provide the patients with dosage forms for routing citrulline to the colon. The aim of this work is to formulate microspheres of citrulline for colonic targeting by the technique of spray drying. Eudragit(®) FS 30D was selected as polymer to encapsulate citrulline using the spray drying technique. Citrulline and Eudragit(®) FS 30D were dissolved in water and ethanol, respectively. The aqueous and the ethanolic solutions were then mixed in 1:2 (v/v) ratio. Microspheres were obtained by nebulizing the citrulline-Eudragit(®) FS 30D solution using a Mini spray dryer equipped with a 0.7mm nozzle. The microspheres have been formulated using citrulline and Eudragit(®) FS 30D. The size distribution of microspheres was determined by light diffraction. The morphology of the microspheres was studied by electron microscopy. Manufacturing yields, encapsulation rate and dissolution profiles were also studied. The microspheres obtained had a spherical shape with a smooth surface and a homogeneous size except for the microspheres containing the highest concentration of polymer (90 %). The formulation showed that the size and morphology of the microspheres are influenced by the polymer concentration. Manufacturing yields were about 51 % but encapsulation rate were always very high (above 90 %). The in vitro dissolution study showed that the use of the Eudragit(®) FS 30D under these conditions is not appropriate to change the dissolution profile of the citrulline. This technique has led to the formulation of microspheres with good physical properties in terms of morphology and size. The compression of the microspheres should help to control citrulline release for colonic targeting. Copyright © 2013 Elsevier Masson SAS. All rights reserved.

  5. Development of effective means of propaganda of safety techniques for coal mines

    Energy Technology Data Exchange (ETDEWEB)

    Galushko, A.L.; Brusilovskiy, V.I.; Popov, I.I.

    1979-01-01

    Information letters about accidents in coal mines are systematically developed and sent to enterprises and organizations of the branch for practical use in preventive work on work protection and work safety. Information materials on advanced experience in prevention of accidents and traumatism are published in large quantities. Principal measures which have dramatically affected the reduction of the level of production traumatism are listed which merit dissemination in the branch. It is noted that the use of these means of propaganda of work safety makes it possible to improve preventive work on work safety and production sanitation in enterprises of the coal industry.

  6. Rapid quality control for coal seams by gamma ray transmission technique

    CERN Document Server

    Raja-Sekhar, N; Nageswara-Rao, A S

    1999-01-01

    The quality of coal expressed as useful heat value (UHV) depends on various parameters such as fixed carbon, volatiles, ash and moisture. These factors have been assessed and the detailed dependence of UHV on these parameters has been studied for samples of coal from a local mine. The samples were subjected to collimated low energy gamma beams and correlation was obtained between the attenuation coefficient and UHV. The method is reliable, fast and non-destructive and can be used in the field for estimating UHV.

  7. Surface coal mine land reclamation using a dry flue gas desulfurization product: Short-term and long-term water responses.

    Science.gov (United States)

    Chen, Liming; Stehouwer, Richard; Tong, Xiaogang; Kost, Dave; Bigham, Jerry M; Dick, Warren A

    2015-09-01

    Abandoned coal-mined lands are a worldwide concern due to their potential negative environmental impacts, including erosion and development of acid mine drainage. A field study investigated the use of a dry flue gas desulfurization product for reclamation of abandoned coal mined land in USA. Treatments included flue gas desulfurization product at a rate of 280 Mg ha(-1) (FGD), FGD at the same rate plus 112 Mg ha(-1) yard waste compost (FGD/C), and conventional reclamation that included 20 cm of re-soil material plus 157 Mg ha(-1) of agricultural limestone (SOIL). A grass-legume sward was planted after treatment applications. Chemical properties of surface runoff and tile water (collected from a depth of 1.2m below the ground surface) were measured over both short-term (1-4 yr) and long-term (14-20 yr) periods following reclamation. The pH of surface runoff water was increased from approximately 3, and then sustained at 7 or higher by all treatments for up to 20 yr, and the pH of tile flow water was also increased and sustained above 5 for 20 yr. Compared with SOIL, concentrations of Ca, S and B in surface runoff and tile flow water were generally increased by the treatments with FGD product in both short- and long-term measurements and concentrations of the trace elements were generally not statistically increased in surface runoff and tile flow water over the 20-yr period. However, concentrations of As, Ba, Cr and Hg were occasionally elevated. These results suggest the use of FGD product for remediating acidic surface coal mined sites can provide effective, long-term reclamation. Copyright © 2015. Published by Elsevier Ltd.

  8. Assessment of carbon sequestration potential of revegetated coal mine overburden dumps: A chronosequence study from dry tropical climate.

    Science.gov (United States)

    Ahirwal, Jitendra; Maiti, Subodh Kumar

    2017-10-01

    Development of secondary forest as post-mining land use in the surface coal mining degraded sites is of high research interest due to its potential to sequester atmospheric carbon (C). The objectives of this study were to assess the improvement in mine soil quality and C sequestration potential of the post-mining reclaimed land with time. Hence, this study was conducted in reclaimed chronosequence sites (young, intermediate and old) of a large open cast coal project (Central Coal Fields Limited, Jharkhand, India) and results were compared to a reference forest site (Sal forest, Shorea robusta). Mine soil quality was assessed in terms of accretion of soil organic carbon (SOC), available nitrogen (N) and soil CO 2 flux along with the age of revegetation. After 14 years of revegetation, SOC and N concentrations increased three and five-fold, respectively and found equivalent to the reference site. Accretion of SOC stock was estimated to be 1.9 Mg C ha -1 year -1 . Total ecosystem C sequestered after 2-14 years of revegetation increased from 8 Mg C ha -1 to 90 Mg C ha -1 (30-333 Mg CO 2 ha -1 ) with an average rate of 6.4 Mg C ha -1 year -1 . Above ground biomass contributes maximum C sequestrate (50%) in revegetated site. CO 2 flux increased with age of revegetation and found 11, 33 and 42 Mg CO 2 ha -1 year -1 in younger, intermediate and older dumps, respectively. Soil respiration in revegetated site is more influenced by the temperature than soil moisture. Results of the study also showed that trees like, Dalbergia sissoo and Heterophragma adenophyllum should be preferred for revegetation of mine degraded sites. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Determination of Effective Criteria for Location Selection of Kiln Wood Drying Plants by AHP Technique

    Directory of Open Access Journals (Sweden)

    Rahim Mohebbi

    2011-12-01

    Full Text Available This study was aimed at determining the effective criteria for location selection of wood drying plants in Iran. For this purpose, after review and field visit of the industries, 35 key indicators were identified. These criteria were divided into five major groups as: materials, infrastructure, technical, economical and instructional indices. The priority rates of these criteria and sub-criteria were evaluated by AHP technique. The results indicated that among 35 effective sub-criteria in location selection of the plants, the sub-criteria of quality of raw materials(0.152, purchasing raw materials, land cost, profitability, reliability of supply, and sales had the highest priorities, which were rated as 0.118, 0.105, 0.067, 0.061 and 0.057, respectively

  10. Experimental investigation of ash deposits characteristics of co-combustion of coal and rice hull using a digital image technique

    International Nuclear Information System (INIS)

    Qiu, Kunzan; Zhang, Hailong; Zhou, Hao; Zhou, Bin; Li, Letian; Cen, Kefa

    2014-01-01

    This paper investigated the ash deposit characteristics during the co-firing Da Tong (DA) coal with different proportions of rice hull (0%, 5%, 10%, and 20%, based on weight) in a pilot-scale furnace. The growth of ash deposit with a four-stage mode was presented. The stable thickness values of DA coal, 5% rice hull, 10% rice hull, and 20% rice hull were 0.5, 1.4, 2.9, 5.7 cm, with stable heat flux values of 230, 200, 175, and 125 kW/m 2 , respectively. According to the results of scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX), the amount of Si in the deposits increased with the increasing proportion of rice hull rich in SiO 2 . The X-ray diffraction (XRD) analysis results indicated that most elements except Si were in the amorphous state because of the formation of eutectics. The stable thicknesses of deposits increased exponentially with the proportion of rice hull. The deposit was loose, easy removable but it reduced the heat transfer significantly. Consequently, sootblowing timely was necessary when co-firing DA coal with rice hull. - Highlights: • Digital image technique was used to monitor deposits growth process. • A type of four stages mode of ash deposit growth was presented. • The heat flux of ash deposits fit a three-stage mode. • The addition of rice hull increased the porosity of deposits

  11. Coal option. [Shell Co

    Energy Technology Data Exchange (ETDEWEB)

    1978-01-01

    This paper notes the necessity of developing an international coal trade on a very large scale. The role of Shell in the coal industry is examined; the regions in which Shell companies are most active are Australia, Southern Africa, Indonesia; Europe and North America. Research is being carried out on marketing and transportation, especially via slurry pipelines; coal-oil emulsions; briquets; fluidized-bed combustion; recovery of coal from potential waste material; upgrading of low-rank coals; unconventional forms of mining; coal conversion (the Shell/Koppers high-pressure coal gasification process). Techniques for cleaning flue gas (the Shell Flue Gas Desulfurization process) are being examined.

  12. Prospects for coal: technical developments

    Energy Technology Data Exchange (ETDEWEB)

    Kaye, W G; Peirce, T J

    1983-07-01

    This article summarises the reasons for predicting an increase in the use of coal as an industrial energy source in the United Kingdom. The development of efficient and reliable coal-burning techniques is therefore of great importance. Various techniques are then discussed, including conventional combustion systems, fluidised bed combustion systems, fluidised bed boilers and furnaces, coal and ash handling, coal-liquid mixtures, coal gasification and coal liquefaction. (4 refs.)

  13. Characterization of the CO2 fluid adsorption in coal as a function of pressure using neutron scattering techniques (SANS and USANS)

    Science.gov (United States)

    Melnichenko, Y.B.; Radlinski, A.P.; Mastalerz, Maria; Cheng, G.; Rupp, J.

    2009-01-01

    Small angle neutron scattering techniques have been applied to investigate the phase behavior of CO2 injected into coal and possible changes in the coal pore structure that may result from this injection. Three coals were selected for this study: the Seelyville coal from the Illinois Basin (Ro = 0.53%), Baralaba coal from the Bowen Basin (Ro = 0.67%), and Bulli 4 coal from the Sydney Basin (Ro = 1.42%). The coals were selected from different depths to represent the range of the underground CO2 conditions (from subcritical to supercritical) which may be realized in the deep subsurface environment. The experiments were conducted in a high pressure cell and CO2 was injected under a range of pressure conditions, including those corresponding to in-situ hydrostatic subsurface conditions for each coal. Our experiments indicate that the porous matrix of all coals remains essentially unchanged after exposure to CO2 at pressures up to 200??bar (1??bar = 105??Pa). Each coal responds differently to the CO2 exposure and this response appears to be different in pores of various sizes within the same coal. For the Seelyville coal at reservoir conditions (16????C, 50??bar), CO2 condenses from a gas into liquid, which leads to increased average fluid density in the pores (??pore) with sizes (r) 1 ?? 105 ??? r ??? 1 ?? 104???? (??pore ??? 0.489??g/cm3) as well as in small pores with size between 30 and 300???? (??pore ??? 0.671??g/cm3). These values are by a factor of three to four higher than the density of bulk CO2 (??CO2) under similar thermodynamic conditions (??CO2 ??? 0.15??g/cm3). At the same time, in the intermediate size pores with r ??? 1000???? the average fluid density is similar to the density of bulk fluid, which indicates that adsorption does not occur in these pores. At in situ conditions for the Baralaba coal (35 OC, 100??bar), the average fluid density of CO2 in all pores is lower than that of the bulk fluid (??pore / ??CO2 ??? 0.6). Neutron scattering from the

  14. The use of coal refuse bike substratoun in cultivate techniques without soils; Utilizacion de los Esteriles de Carbon como Sustratos en Cultivos sin Suelo 2 Fase

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    Coal refuse poses several problems as regards both their storage and environmental impact: landscape alteration, pollution, high costs, an increasing difficulty in finding appropriate places for storage, etc. Therefore, the companies HUMOSA, HORPLASA and the C. S. I. C. Centre for Environmental Sciences carried out a joint study financed by OCICARBON. This study, completing other ones carried out previously, was aimed at determining the use as both a soilless medium for growing other vegetables than tomatoes and a basic component for container gardening. Then, based on previous experiments, two types of coal refuse were selected: coal refuse from dumps and burnt coal refuse. The characterization of the coal refuse was carried out and the investigation-line was established: (I) the adaption of techniques and know-how obtained up to that moment to the production of kidney beans faba de la granja, green beans and pepper; (II) to study the possibilities of coal refuse as basic components of substrates for container gardening of decorative outdoor plants different from the already investigated conifers in order examine thoroughly the cultivation techniques and, in particular, the methods of fertilization by irrigation. Exhaustive controls were carried out with both types of cultivation using as reference other cultivations with conventional substrates. The results obtained proved that coal refuse can be used as soilles growing medium for vegetables and for container gardening of decorative plants.

  15. Electrostatic beneficiation of coal

    Energy Technology Data Exchange (ETDEWEB)

    Mazumder, M.K.; Tennal, K.B.; Lindquist, D.

    1994-10-01

    Dry physical beneficiation of coal has many advantages over wet cleaning methods and post combustion flue gas cleanup processes. The dry beneficiation process is economically competitive and environmentally safe and has the potential of making vast amounts of US coal reserves available for energy generation. While the potential of the electrostatic beneficiation has been studied for many years in laboratories and in pilot plants, a successful full scale electrostatic coal cleaning plant has not been commercially realized yet. In this paper the authors review some of the technical problems that are encountered in this method and suggest possible solutions that may lead toward its full utilization in cleaning coal.

  16. Determination of intensity functions for predicting subsidence from coal mining, potash mining, and groundwater withdrawal using the influence function technique

    Energy Technology Data Exchange (ETDEWEB)

    Triplett, T; Yurchak, D [Twin Cities Research Center, Bureau of Mines, US Dept. of the Interior, Minneapolis, MN (United States)

    1997-12-31

    This paper presents research, conducted by the Bureau of Mines, on modifying the influence function method to predict subsidence. According to theory, this technique must incorporate an intensity function to represent the relative significance of the causes of subsidence. This paper shows that the inclusion of a reasonable intensity function increases the accuracy of the technique, then presents the required functions for case studies of longwall coal mining subsidence in Illinois, USA, potash mining subsidence in new Mexico, USA, and subsidence produced by ground water withdrawal in California, USA. Finally, the paper discusses a method to predict the resultant strain from a simply measured site constant and ground curvatures calculated by the technique. (orig.)

  17. Determination of intensity functions for predicting subsidence from coal mining, potash mining, and groundwater withdrawal using the influence function technique

    Energy Technology Data Exchange (ETDEWEB)

    Triplett, T.; Yurchak, D. [Twin Cities Research Center, Bureau of Mines, US Dept. of the Interior, Minneapolis, MN (United States)

    1996-12-31

    This paper presents research, conducted by the Bureau of Mines, on modifying the influence function method to predict subsidence. According to theory, this technique must incorporate an intensity function to represent the relative significance of the causes of subsidence. This paper shows that the inclusion of a reasonable intensity function increases the accuracy of the technique, then presents the required functions for case studies of longwall coal mining subsidence in Illinois, USA, potash mining subsidence in new Mexico, USA, and subsidence produced by ground water withdrawal in California, USA. Finally, the paper discusses a method to predict the resultant strain from a simply measured site constant and ground curvatures calculated by the technique. (orig.)

  18. Preparation and characterization of hydroxyapatite-coated iron oxide particles by spray-drying technique

    Directory of Open Access Journals (Sweden)

    karina Donadel

    2009-06-01

    Full Text Available Magnetic particles of iron oxide have been increasingly used in medical diagnosis by magnetic resonance imaging and in cancer therapies involving targeted drug delivery and magnetic hyperthermia. In this study we report the preparation and characterization of iron oxide particles coated with bioceramic hydroxyapatite by spray-drying. The iron oxide magnetic particles (IOMP were coated with hydroxyapatite (HAp by spray-drying using two IOMP/HAp ratios (0.7 and 3.2. The magnetic particles were characterized by way of scanning electronic microscopy, energy dispersive X-ray, X-ray diffraction, Fourier transformed infrared spectroscopy, flame atomic absorption spectrometry,vibrating sample magnetometry and particle size distribution (laser diffraction. The surface morphology of the coated samples is different from that of the iron oxide due to formation of hydroxyapatite coating. From an EDX analysis, it was verified that the surface of the coated magnetic particles is composed only of HAp, while the interior containsiron oxide and a few layers of HAp as expected. The results showed that spray-drying technique is an efficient and relatively inexpensive method for forming spherical particles with a core/shell structure.As partículas de óxido de ferro têm sido extensivamente usadas em diagnósticos médicos como agente de contraste para imagem por ressonância magnética e na terapia do câncer, dentre estas, liberação de fármacos em sitos alvos e hipertermia magnética. Neste estudo nós reportamos a preparação e caracterização de partículas magnéticas de óxido de ferro revestidas com a biocerâmica hidroxiapatita. As partículas magnéticasde óxido de ferro (PMOF foram revestidas com hidroxiapatita por spray-drying usando duas razões PMOF/HAp (0,7 e 3,2. As partículas magnéticas foram caracterizadas por microscopia eletrônica de varredura, energia dispersiva de raios X, difração de raios X, espectroscopia de absorção no infra

  19. Immersion freezing induced by different kinds of coal fly ash: Comparing particle generation methods and measurement techniques

    Science.gov (United States)

    Grawe, Sarah; Augustin-Bauditz, Stefanie; Clemen, Hans-Christian; Eriksen-Hammer, Stine; Lubitz, Jasmin; Schneider, Johannes; Stratmann, Frank; Wex, Heike

    2017-04-01

    To date, a lot of effort has been put into the identification and characterization of atmospheric ice nucleating particles (INPs), which may influence both weather and climate. The majority of studies focuses on INPs from natural origin such as biological particles or mineral dust particles (Hoose and Möhler 2012, Murray et al. 2012). Combustion ashes, being possible sources of anthropogenic INPs, have rarely been investigated in the past. Ash particles may be emitted into the atmosphere either by the action of wind from ash deposits on the ground (bottom ash), or during the combustion process (fly ash). Two recent studies (Umo et al., 2015; Grawe et al., 2016) identified fly ash from coal combustion as the most efficient of the investigated samples (including also bottom ashes from wood and coal combustion). These results motivate the here presented study in which we investigated the immersion freezing behavior of four coal fly ash samples taken from the filters of different coal-fired power plants in Germany. A combination of two instruments was used to capture the temperature range from 0 °C to the homogeneous freezing limit at around -38 °C. Firstly, the new Leipzig Ice Nucleation Array (LINA) was used, where droplets from an ash-water suspension are pipetted onto a cooled plate. Secondly, we used the Leipzig Aerosol Cloud Interaction Simulator (LACIS; Hartmann et al., 2011), a laminar flow tube in which every droplet contains a single size-segregated ash particle. Here, it was possible to study the effect of different kinds of particle generation, i.e., atomization of an ash-water suspension, and aerosolization of dry ash material. The composition of the ash particles was investigated by means of single particle aerosol mass spectrometry and particles were sampled on filters for environmental scanning electron microscope analysis. Our measurements show that all four fly ash samples feature a similar immersion freezing behavior (ice fractions vary by a

  20. Dry syngas purification process for coal gas produced in oxy-fuel type integrated gasification combined cycle power generation with carbon dioxide capturing feature.

    Science.gov (United States)

    Kobayashi, Makoto; Akiho, Hiroyuki

    2017-12-01

    Electricity production from coal fuel with minimizing efficiency penalty for the carbon dioxide abatement will bring us sustainable and compatible energy utilization. One of the promising options is oxy-fuel type Integrated Gasification Combined Cycle (oxy-fuel IGCC) power generation that is estimated to achieve thermal efficiency of 44% at lower heating value (LHV) base and provide compressed carbon dioxide (CO 2 ) with concentration of 93 vol%. The proper operation of the plant is established by introducing dry syngas cleaning processes to control halide and sulfur compounds satisfying tolerate contaminants level of gas turbine. To realize the dry process, the bench scale test facility was planned to demonstrate the first-ever halide and sulfur removal with fixed bed reactor using actual syngas from O 2 -CO 2 blown gasifier for the oxy-fuel IGCC power generation. Design parameter for the test facility was required for the candidate sorbents for halide removal and sulfur removal. Breakthrough test was performed on two kinds of halide sorbents at accelerated condition and on honeycomb desulfurization sorbent at varied space velocity condition. The results for the both sorbents for halide and sulfur exhibited sufficient removal within the satisfactory short depth of sorbent bed, as well as superior bed conversion of the impurity removal reaction. These performance evaluation of the candidate sorbents of halide and sulfur removal provided rational and affordable design parameters for the bench scale test facility to demonstrate the dry syngas cleaning process for oxy-fuel IGCC system as the scaled up step of process development. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. Coal 99; Kol 99

    Energy Technology Data Exchange (ETDEWEB)

    Sparre, C

    2000-07-01

    The following report deals with the use of coal and coke during 1998. Some information about techniques, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from Statistics Sweden have also been used. The use of steam coal for heating purposes during 1998 was 680 000 tons and somewhat lower than in 1997. The extremely high figures of 1996 were due to twice the production of electricity because of lack of waterpower. The co-generation plants were the main users of coal. The minor plants have increased their use of forest fuels. Probably the use of steam coal will go down in the immediate years both in the heat generating and the co-generating plants. During the top year 1987 coal was used in 18 hot water plants and 11 co-generation plants. During 1998 these figures are 1 and 8. Taxes and environmental reasons explain this trend. The use of steam coal in the industry has been constant at the level 700 000 tons. This level is supposed to be constant or to vary with business cycles. Steel-works, however, increase their use of steam coal in order to replace the more expensive coke. The import of metallurgical coal in 1998 was 1.6 mill tons like the year before. 1.1 mill tons of coke were produced. The coke consumption in the industry was 1.4 mill tons from which 0.3 mill tons were imported. Several other plants have plans to replace the coal with forest fuels, waste fuels and NG. Even the biggest plant, Vaesteraas, has ordered a block for bio fuels. Helsingborg has started to use wood pellets. The pellets replace most of the coal for the heat production in the co-generation plant. Norrkoeping Kraft AB has put a fluid bed boiler for various fuels into operation, leading to more than half the coal consumption compared with previous years. They have also rebuilt one of their travelling grates for bio fuels. Stockholm Energi, Haesselbyverket, has invested

  2. Processes, Techniques, and Successes in Welding the Dry Shielded Canisters of the TMI-2 Reactor Core Debris

    International Nuclear Information System (INIS)

    Zirker, L.R.; Rankin, R.A.; Ferrell, L.J.

    2002-01-01

    The Idaho National Engineering and Environmental Laboratory (INEEL) is operated by Bechtel-BWXT Idaho LLC (BBWI), which recently completed a very successful $100 million Three-Mile Island-2 (TMI-2) program for the Department of Energy (DOE). This complex and challenging program used an integrated multidisciplinary team approach that loaded, welded, and transported an unprecedented 25 dry shielded canisters (DSC) in seven months, and did so ahead of schedule. The program moved over 340 canisters of TMI-2 core debris that had been in wet storage into a dry storage facility at the INEEL. The main thrust of this paper is relating the innovations, techniques, approaches, and lessons learned associated to welding of the DSC's. This paper shows the synergism of elements to meet program success and shares these lessons learned that will facilitate success with welding of dry shielded canisters in other DOE complex dry storage programs

  3. An injection technique for in-situ remediation of abandoned underground coal mines

    International Nuclear Information System (INIS)

    Canty, G.A.; Everett, J.W.

    1998-01-01

    Remediation of underground mines can prove to be a difficult task, given the physical constraints associated with introducing amendments to a subterranean environment. An acid mine abatement project involving in-situ chemical treatment method was conducted by the University of Oklahoma. The treatment method involved the injection of an alkaline coal combustion by-product (CCB) slurry into a flooded mine void (pH 4.4) to create a buffered zone. Injection of the CCB slurry was possible through the use of equipment developed by the petroleum industry for grouting recovery wells. This technology was selected because the CCB slurry could be injected under significant pressure and at a high rate. With higher pressure and rates of injection, a large quantity of slurry can be introduced into the mine within a limited amount of time. Theoretically, the high pressure and rate would improve dispersal of the slurry within the void. In addition, the high pressure is advantageous in fracturing or breaking-down obstructions to injection. During the injection process, a total of 418 tons of CCB was introduced within 15 hours. The mine did not refuse any of the material, and it is likely that a much larger mass could have been added. One injection well was drilled into a pillar of coal. Normally this would pose a problem when introducing a slurry; however, the coal pillar was easily fractured during the injection process. Currently, the pH of the mine discharge is above 6.5 and the alkalinity is approximately 100 mg/L as CACO 3

  4. Comparison of coarse coal dust sampling techniques in a laboratory-simulated longwall section.

    Science.gov (United States)

    Patts, Justin R; Barone, Teresa L

    2017-05-01

    Airborne coal dust generated during mining can deposit and accumulate on mine surfaces, presenting a dust explosion hazard. When assessing dust hazard mitigation strategies for airborne dust reduction, sampling is done in high-velocity ventilation air, which is used to purge the mining face and gallery tunnel. In this environment, the sampler inlet velocity should be matched to the air stream velocity (isokinetic sampling) to prevent oversampling of coarse dust at low sampler-to-air velocity ratios. Low velocity ratios are often encountered when using low flow rate, personal sampling pumps commonly used in underground mines. In this study, with a goal of employing mine-ready equipment, a personal sampler was adapted for area sampling of coarse coal dust in high-velocity ventilation air. This was done by adapting an isokinetic nozzle to the inlet of an Institute of Occupational Medicine (Edinburgh, Scotland) sampling cassette (IOM). Collected dust masses were compared for the modified IOM isokinetic sampler (IOM-MOD), the IOM without the isokinetic nozzle, and a conventional dust sampling cassette without the cyclone on the inlet. All samplers were operated at a flow rate typical of personal sampling pumps: 2 L/min. To ensure differences between collected masses that could be attributed to sampler design and were not influenced by artifacts from dust concentration gradients, relatively uniform and repeatable dust concentrations were demonstrated in the sampling zone of the National Institute for Occupational Safety and Health experimental mine gallery. Consistent with isokinetic theory, greater differences between isokinetic and non-isokinetic sampled masses were found for larger dust volume-size distributions and higher ventilation air velocities. Since isokinetic sampling is conventionally used to determine total dust concentration, and isokinetic sampling made a difference in collected masses, the results suggest when sampling for coarse coal dust the IOM-MOD may

  5. Coal Recycling from Tailings using Flotation with 2-Level Experimental Design Techniques

    Directory of Open Access Journals (Sweden)

    Sajjad Jannesar Malakooti

    2012-12-01

    Full Text Available In this study, the possibility of producing coal with less than 11% ash from tailings of flotation process was investigated. The effect of six flotation parameters: collector type, collector consumption, frother type, frother consumption, pulp density and mixing rate were studied on a sample from a tailing dam. A software based experimental design approach (DX7 was applied to determine and model effective parameters as well as flotation optimization through fractional factorial. It was shown that collector type and flotation machine mixing rate were the most effective parameters on ash content of concentrate. The results indicated that the production of a desired ash content concentrate, i.e.

  6. Technique for reinforcing development working in lower strata of thick coal seams

    Energy Technology Data Exchange (ETDEWEB)

    Andranovich, V A; Gromov, Yu V; Kurglikov, V P

    1981-01-15

    This device is to be used by mining industry, specifically for reinforcing development work in bottom strata of thick coal seams having a layer depression. Reinforcing consists of drilling a hole, or making cutting slits and lowering support props for the stratum below through them, as well as lowering the roof timber on the ground. To cut back expenditures on installation and removal of equipment, drilling or making cutting slits is done to a depth equal to the total height of the substrata, and the support props are laid for all of the substrata. Only the roof timber is lowered on the ground during work on the layers.

  7. Development of the ultra-clean dry cleanup process for coal-based syngases: pilot-scale evaluation

    Energy Technology Data Exchange (ETDEWEB)

    R.B. Slimane; P.V. Bush; J.L. Aderhold, Jr.; B.G. Bryan; R.A. Newby; D. A. Horazak; S.C. Jain [Gas Technology Institute, Des Plaines, IL (United States)

    2005-07-01

    This paper reports on a recent successful pilot-scale evaluation of the Ultra-Clean Process performance at a 10-ton/day coal gasifier facility. In these tests, carbonaceous feedstocks were gasified, using GTI's fluidized bed U-GAS{reg_sign} gasification technology, to generate syngas. The raw syngas was then conditioned and fed to the UCP test section for deep cleaning to meet very stringent cleaning requirements for chemical feedstocks or liquid-fuel synthesis applications, or for fuel-cell power generation. Fine particle sorbents for sulfur, halide, and mercury removal were injected into the syngas upstream of two stages of particulate controlled devices, 'barrier filter-reactors', coupling efficient particle capture with an effective entrained and filter cake reaction environment for very effective multiple contaminant removal. The goal of the test program was to confirm sorbent selection, filter-reactor operating parameters and sorbent-to-contaminant ratios, which were previously determined in the laboratory to have potential to reduce contaminant concentrations to very low levels. The pilot-scale data developed are being used to update conceptual evaluations, which have shown the technical feasibility, cost effectiveness and commercial merit for the Ultra-Clean Process compared to conventional, Rectisol-based syngas cleaning. 10 refs., 5 figs.

  8. Coal background paper. Coal demand

    International Nuclear Information System (INIS)

    1997-01-01

    Statistical data are presented on coal demands in IEA and OECD member countries and in other countries. Coal coaking and coaking coal consumption data are tabulated, and IEA secretariat's coal demand projections are summarized. Coal supply and production data by countries are given. Finally, coal trade data are presented, broken down for hard coal, steam coal, coking coal (imports and export). (R.P.)

  9. Synthesis, microstructure and mechanical properties of ceria stabilized tetragonal zirconia prepared by spray drying technique

    International Nuclear Information System (INIS)

    Sharma, S.C.; Gokhale, N.M.; Dayal, Rajiv; Lazl, Ramji

    2002-01-01

    Ceria stabilized zirconia powders with ceria concentration varying from 6 to 16 mol% were synthesized using spray drying technique. Powders were characterized for their particle size distribution and specific surface area. The dense sintered ceramics fabricated using these powders were characterized for their microstructure, crystallite size and phase composition. The flexural strength, fracture toughness and micro-hardness of sintered ceramics were measured. High fracture toughness and flexural strength were obtained for sintered bodies with 12 mol% of CeO 2 . Flexural strength and fracture toughness were dependent on CeO 2 concentration, crystallite size and phase composition of sintered bodies. Correlation of data has indicated that the transformable tetragonal phase is the key factor in controlling the fracture toughness and strength of ceramics. It has been demonstrated that the synthesis method is effective to prepare nanocrystalline tetragonal ceria stabilized zirconia powders with improved mechanical properties. Ce-ZrO 2 with 20 wt% alumina was also prepared with flexural strength, 1200 MPa and fracture toughness 9.2 MPa√m. (author)

  10. Effect of drying techniques on the retention of antioxidant activities of Saskatoon berries

    Directory of Open Access Journals (Sweden)

    Pranabendu Mitra

    2013-10-01

    Full Text Available The main objective of this research was to compare the retention of antioxidant activity and total anthocyanin content of Saskatoon berries dried by freeze drying, microwave-vacuum drying, thin layer hot air drying and vacuum drying. Antioxidant activity of berry samples was determined by DPPH radical scavenging and ABTS radical scavenging, and the pH differential method was used to determine total anthocyanin content of the berry samples. The results showed that the freeze dried Saskatoon berries exhibited the highest retention of anthocyanin and antioxidant activity among the dried samples, followed by microwave-vacuum dried berries, thin layer hot air dried berries and vacuum dried berries. There were significant differences between the berry samples at P<0.05.  DPPH radical scavenging and ABTS radical scavenging were correlated linearly with an R2 value of 0.99 at P<0.05 showing their effectiveness for the determination of the antioxidant activity of the Saskatoon berries. However, the DPPH radical scavenging assay was more effective than the ABTS radical scavenging assay. The results also showed that antioxidant activity of the berries was highly correlated with the total anthocyanin content of the fruit. The reduction of anthocyanin in dried berry samples was linearly correlated with the reduction of DPPH radical scavenging with an R2 value of 0.97 at P<0.05 and, also, linearly correlated with the reduction of ABTS radical scavenging with an R2 value of 0.88 at P<0.05.

  11. Development of an integrated MOX-scrap recycling flow-sheet by dry and wet routes using microwave heating techniques

    Energy Technology Data Exchange (ETDEWEB)

    Mallik, G K; Malav, R K; Karande, A P; Bhargava, V K; Kamath, H S [Advanced Fuel Fabrication Facility, Bhabha Atomic Research Centre, Tarapur (India)

    1999-01-01

    A simple, short and efficient scrap, recycling flow-sheet, which is exclusively based on microwave heating techniques and, includes both dry and wet routes, for (U,Pu)O{sub 2} fuel scrap recycling has been developed and evaluated. (author) 6 refs., 1 tab.

  12. Estimation of Moisture Content in Coal in Coal Mills

    DEFF Research Database (Denmark)

    Odgaard, Peter Fogh; Mataji, B.

    the moisture content of the coal is proposed based on a simple dynamic energy model of a coal mill, which pulverizes and dries the coal before it is burned in the boiler. An optimal unknown input observer is designed to estimate the moisture content based on an energy balance model. The designed moisture...

  13. Estimation of Moisture Content in Coal in Coal Mills

    DEFF Research Database (Denmark)

    Odgaard, Peter Fogh; Mataji, Babak

    2006-01-01

    the moisture content of the coal is proposed based on a simple dynamic energy model of a coal mill, which pulverizes and dries the coal before it is burned in the boiler. An optimal unknown input observer is designed to estimate the moisture content based on an energy balance model. The designed moisture...

  14. Application of remote-sensing techniques to hydrologic studies in selected coal-mine areas of southeastern Kansas

    Science.gov (United States)

    Kenny, J.F.; McCauley, J.R.

    1983-01-01

    Disturbances resulting from intensive coal mining in the Cherry Creek basin of southeastern Kansas were investigated using color and color-infrared aerial photography in conjunction with water-quality data from simultaneously acquired samples. Imagery was used to identify the type and extent of vegetative cover on strip-mined lands and the extent and success of reclamation practices. Drainage patterns, point sources of acid mine drainage, and recharge areas for underground mines were located for onsite inspection. Comparison of these interpretations with water-quality data illustrated differences between the eastern and western parts of the Cherry Creek basin. Contamination in the eastern part is due largely to circulation of water from unreclaimed strip mines and collapse features through the network of underground mines and subsequent discharge of acidic drainage through seeps. Contamination in the western part is primarily caused by runoff and seepage from strip-mined lands in which surfaces have frequently been graded and limed but are generally devoid of mature stands of soil-anchoring vegetation. The successful use of aerial photography in the study of Cherry Creek basin indicates the potential of using remote-sensing techniques in studies of other coal-mined regions. (USGS)

  15. Processing of Polysulfone to Free Flowing Powder by Mechanical Milling and Spray Drying Techniques for Use in Selective Laser Sintering

    Directory of Open Access Journals (Sweden)

    Nicolas Mys

    2016-04-01

    Full Text Available Polysulfone (PSU has been processed into powder form by ball milling, rotor milling, and spray drying technique in an attempt to produce new materials for Selective Laser Sintering purposes. Both rotor milling and spray drying were adept to make spherical particles that can be used for this aim. Processing PSU pellets by rotor milling in a three-step process resulted in particles of 51.8 μm mean diameter, whereas spray drying could only manage a mean diameter of 26.1 μm. The resulting powders were characterized using Differential Scanning Calorimetry (DSC, Gel Permeation Chromatography (GPC and X-ray Diffraction measurements (XRD. DSC measurements revealed an influence of all processing techniques on the thermal behavior of the material. Glass transitions remained unaffected by spray drying and rotor milling, yet a clear shift was observed for ball milling, along with a large endothermic peak in the high temperature region. This was ascribed to the imparting of an orientation into the polymer chains due to the processing method and was confirmed by XRD measurements. Of all processed powder samples, the ball milled sample was unable to dissolve for GPC measurements, suggesting degradation by chain scission and subsequent crosslinking. Spray drying and rotor milling did not cause significant degradation.

  16. FY 1980 Report on results of Sunshine Project. Development of coal liquefaction techniques (Development of materials for the coal liquefaction plant); 1980 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho. Sekitan ekika plant zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    A 1 T/D solvent-extraction type coal liquefaction test plant was constructed and operated to obtain the technical data for the design of, and establish the techniques for, an efficient coal liquefaction plant. The FY 1980 program includes surveys on the materials for coal liquefaction plants, covering those already developed and under development, to clarify the problematical points; drafting the test schedules; and conceptual designs of the material testing facilities. The major problems involved in the materials for coal liquefaction plants include erosion by fluidizing coal slurry, hydrogen embrittlement of the reactor materials, and corrosion by the liquefaction products (e.g., stress-corrosion cracking of austenitic steel, and corrosion by organic acids). The surveys on materials research trends suggest that USA seems to concentrate their research efforts on the reactor materials. The corrosion tests are mostly of in-plant tests, but the stress corrosion and slurry erosion tests are conducted on a laboratory scale. The conceptual designs are drawn for some testing units, e.g., the loop type material testing unit and basic testing unit for jet-spray type slurry erosion. (NEDO)

  17. Development of a photogrammetry technique for large-area deformation monitoring in coal mining areas

    International Nuclear Information System (INIS)

    Redweik, P.M.

    1993-01-01

    The investigations of ground movements in coal mining areas during the past 10 years have been performed by methods of aerial photogrammetry. The ground points used for the determination of the movement in urban areas are manhole covers. The measurements must be repeated every three or four years. These facts have motivated the development of a new automatic method for measuring photo coordinates. This method is implemented on the Rollei RS1 (Reseau-Scanner Monocomparator. The approximate photo coordinates that are needed for this instrument can be computed from the old ground coordinates of each point. The manhole cover will be first recognised with a sort of template matching. Its central point will then be computed by using an ellipse operator. (orig.) [de

  18. Preparation and characterization of fast dissolving flurbiprofen and esomeprazole solid dispersion using spray drying technique.

    Science.gov (United States)

    Pradhan, Roshan; Tran, Tuan Hiep; Kim, Sung Yub; Woo, Kyu Bong; Choi, Yong Joo; Choi, Han-Gon; Yong, Chul Soon; Kim, Jong Oh

    2016-04-11

    We aimed to develop an immediate-release flurbiprofen (FLU) and esomeprazole (ESO) combination formulation with enhanced gastric aqueous solubility and dissolution rate. Aqueous solubility can be enhanced by formulating solid dispersions (SDs) with a polyvinylpyrrolidone (PVP)-K30 hydrophilic carrier, using spray-drying technique. Aqueous and gastric pH dissolution can be achieved by macro-environmental pH modulation using sodium bicarbonate (NaHCO3) and magnesium hydroxide (Mg(OH)2) as the alkaline buffer. FLU/ESO-loaded SDs (FLU/ESO-SDs) significantly improved aqueous solubility of both drugs, compared to each drug powder. Dissolution studies in gastric pH and water were compared with the microenvironmental pH modulated formulations. The optimized FLU/ESO-SD powder formulation consisted of FLU/ESO/PVP-K30/sodium carbonate (Na2CO3) in a weight ratio 1:0.22:1.5:0.3, filled in the inner capsule. The outer capsule consisted of NaHCO3 and Mg(OH)2, which created the macro-environmental pH modulation. Increased aqueous and gastric pH dissolution of FLU and ESO from the SD was attributed to the alkaline buffer effects and most importantly, to drug transformation from crystalline to amorphous SD powder, clearly revealed by scanning electron microscopy, differential scanning calorimetry, and powder X-ray diffraction studies. Thus, the combined FLU and ESO SD powder can be effectively delivered as an immediate-release formulation using the macro-environmental pH modulation concept. Copyright © 2016. Published by Elsevier B.V.

  19. Innovative Coal Solids-Flow Monitoring and Measurement Using Phase-Doppler and Mie Scattering Techniques

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Seong Lee

    2010-01-19

    Fuel flow to individual burners is complicated and difficult to determine on coal fired boilers, since coal solids were transported in a gas suspension that is governed by the complex physics of two-phase flow. The objectives of the project were the measurements of suspended coal solids-flows in the simulated test conditions. Various extractive methods were performed manually and can give only a snapshot result of fuel distribution. In order to measure particle diameter & velocity, laser based phase-Doppler particle analyzer (PDPA) and particle image velocimetry (PIV) were carefully applied. Statistical methods were used to analyze particle characteristics to see which factors have significant effect. The transparent duct model was carefully designed and fabricated for the laser-based-instrumentation of solids-flow monitoring (LISM). The experiments were conducted with two different kinds of particles with four different particle diameters. The particle types were organic particles and saw dust particles with the diameter range of 75-150 micron, 150-250 micron, 250-355 micron and 355-425 micron. The densities of the particles were measured to see how the densities affected the test results. Also the experiment was conducted with humid particles and fog particles. To generate humid particles, the humidifier was used. A pipe was connected to the humidifier to lead the particle flow to the intersection of the laser beam. The test results of the particle diameter indicated that, the mean diameter of humid particles was between 6.1703 microns and 6.6947 microns when the humid particle flow was low. When the humid particle flow was high, the mean diameter was between 6.6728 microns and 7.1872 microns. The test results of the particle mean velocity indicated that the mean velocity was between 1.3394 m/sec and 1.4556 m/sec at low humid particle flow. When the humid particle flow was high, the mean velocity was between 1.5694 m/sec and 1.7856 m/sec. The Air Flow Module, TQ

  20. Coal - 97

    International Nuclear Information System (INIS)

    Sparre, C.

    1997-01-01

    The report deals with the use of coal and coke during 1996. Some information about techniques, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from SCB have also been used. The use of steam coal for heating purposes during 1996 was 1,2 mill tons and 50% higher than in 1995. The increase is probably temporary and due to high prices of electricity because of lack of water power. The co-generation plants were the main users of coal. The minor plants have increased their use of forest fuels. Probably the use of steam coal will go down in the immediate years both in the heat generating and the co-generation plants. During the top year 1987 coal was used in 18 hotwater plants and 11 co-generation plants. 1996 these figures are 3 and 12. Taxes and environmental reasons explain this trend. The use of steam coal in the industry has been constant at the level 700 000 tons. This level is supposed to be constant or to vary with business cycles. The import of metallurgical coal in 1996 was 1,6 mill tons like the year before. 1,2 mill tons coke were produced. The coke consumption in the industry was 1,5 mill tons. 0,3 mill tons of coke were imported. The average price of steam coal imported in Sweden in 1996 was 340 SEK/ton or 2% higher than in 1995. For the world, the average import price was 51,5 USD/ton, nearly the same as the year before. The contract prices for delivery during 1997 are about equal as the end of 1996. All Swedish plants meet their emission limits of dust, SO 2 and NO x given by county administrations or concession boards

  1. Construction of prototype of on-line analyzer detection system for coal on belt conveyor using neutron activation technique

    International Nuclear Information System (INIS)

    Rony Djokorayono; Agus Cahyono; MP Indarzah; SG Usep; Sukandar

    2015-01-01

    The use of on-line neutron activation technique for coal analysis is proposed as an alternative method for analysis based on sampling technique. Compared to this conventional technique, the on-line neutron activation technique has much shorter time of analysis and more accurate results. The construction of detection system prototype for the on-line analyzer is described in this paper. This on-line analyzer consists of detection system, data acquisition system, and computer console. This detection system comprises several modules, i.e. NaI(Tl) scintillation detector completed with a photomultiplier tube (PMT), pre-amplifier, single channel analyzer (SCA), and analog signal transmitter and pulse counter processor. The construction processes of these four modules include the development of configuration block, lay out, and selection of electronic components. The modules have been integrated and tested. This detection system was tested using radioactive element Zn-65 having energy of 1115.5 keV and activity of 1 μCi. The test results show that the prototype of the on-line analyzer detection system has functioned as expected. (author)

  2. Freeze-drying and related preparation techniques for biological microprobe analysis

    International Nuclear Information System (INIS)

    Wroblewski, R.; Wroblewski, J.; Anniko, M.; Edstroem, L.P.

    1985-01-01

    An X-ray microanalytical and morphological investigation has been carried out on rapidly frozen, freeze-dried or freeze-substituted tissues. A comparison was made between different embedding and polymerization procedures following freeze-substitution and freeze-drying. The investigation also included an analysis of specimens infiltrated, embedded and polymerized by ultraviolet irradiation at low temperatures with Lowicryl HM20. The morphological preservation of Lowicryl embedded tissue was adequate for the identification of different cell structures like nuclei, mitochondria, lysosomes and different types of endoplasmic reticulum. X-ray microanalytical investigation of low temperature embedded material displayed an elemental composition of cells and organelles similar to that found in freeze-dried cyosections. Compared with freeze-dried cryosections, low temperature embedded material could be sectioned for light microscopy and area of interest chosen for further thin sectioning. This is of great importance in work with tissues with complicated morphology and heterogenous cell populations

  3. Coal -98

    International Nuclear Information System (INIS)

    Sparre, C.

    1998-01-01

    Energi, Haesselbyverket, has now invested in equipment for burning pellets instead of coal. In Linkoeping wastes of rubber are mixed with coal. Also Soederenergi AB has rebuilt their three coal boilers and replaced 100 % of the coal by peat and wood fuels. Coal is a reserve fuel. Several co-generation plants like Linkoeping, Norrkoeping, Uppsala and Oerebro use both coal and forest fuels. The use of coal is then concentrated to the electricity production. The average price of steam coal imported in Sweden in 1997 was 370 SEK/ton or 10 per cent higher than in 1996. For the world, the average import price fell to 46 USD/ton. The price fall was concentrated to the 4th quarter. The prices have continued to fall during 1998 as a result of the crisis in Asia. All Swedish plants meet their emission limits of dust, SO 2 and NO x given by county administrations or concession boards. The co-generation plants have all some sort of SO 2 -removal system. Mostly used is the wet-dry method. The biggest co-generation plant, Vaesteraas, has newly invested in a ca talytic NO x -cleaning system type SCR, which is reducing the emission level 80-90 %. Most other plants are using low NO x -burners or injection systems type SNCR, based on ammonium or urea, which are reducing the emissions 50-70 %. A positive effect of the recently introduced NO x -duties is a 60 % reduction compared to some years ago, when the duties were introduced. World hard coal production was about 3 800 tons in 1997, a minor increase compared to 1996. The coal demand in the OECD-countries has increased about 1.7 % yearly during the last ten years. The coal share of the energy supply is about 20% in the OECD-countries and 27% in the whole world. Several sources estimate a continuing growth during the next 20 years in spite of an increasing use of natural gas and nuclear power. The reason is a strong demand for electrical power in the Asian countries and the developing countries. However, greater efforts to minimize the

  4. Shelf-life extension of dried shrimps by irradiation and packaging techniques

    International Nuclear Information System (INIS)

    Warunee Varanyanond; Hirata, Takashi; Ishitani, Takasuke

    2000-01-01

    Dried shrimps were air-packaged or N2-packaged in the flexible pouch of oriented polypropylene (OPP), polyvinylidene chloride coated polypropylene (KOP) and ethylene vinyl alcohol copolymer (EVOH). The packages were irradiated with gamma ray from cobalt 60 at 3 and 8 kGy. Non-irradiated dried shrimps were used as a control. The samples were stored at 30 deg C and 70+-5 percent RH for 4 months. Non-enzymatic browning induced the discoloration of dried shrimps, and oxidation of astaxanthin proceeded after irradiation and during storage. The hunter color difference, delta E, of all the samples was increased, especially in the non-irradiated air-packages samples. The decrease in astaxanthin content was found in both air - and N2-packaged samples during storage. The number of microorganisms was reduced by irradiation dose of 3 and 8 kGy from 6.5 to 4.2 and 2.7 log CFU/g, respectively. The decreased concentration of O2 in the package also reduced the number of microorganisms. The air packaged dried shrimps in the OPP pouch deteriorated during storage. Shrinkage of the pouches and growth of halophilic bacteria on the surface of dried shrimps were found at a sub(w) of 0.75. The discoloration of dried shrimps in the OPP pouch was more significant than that in other pouches. Irradiation at 3 and 8 kGy in combination with packaging in KOP and EVOH pouches containing N2 atmosphere was one of the promising methods for prolonging shelf-life of dried shrimps at room temperature

  5. Mathematical optimization techniques for managing selective catalytic reduction for a fleet of coal-fired power plants

    Science.gov (United States)

    Alanis Pena, Antonio Alejandro

    Major commercial electricity generation is done by burning fossil fuels out of which coal-fired power plants produce a substantial quantity of electricity worldwide. The United States has large reserves of coal, and it is cheaply available, making it a good choice for the generation of electricity on a large scale. However, one major problem associated with using coal for combustion is that it produces a group of pollutants known as nitrogen oxides (NO x). NOx are strong oxidizers and contribute to ozone formation and respiratory illness. The Environmental Protection Agency (EPA) regulates the quantity of NOx emitted to the atmosphere in the United States. One technique coal-fired power plants use to reduce NOx emissions is Selective Catalytic Reduction (SCR). SCR uses layers of catalyst that need to be added or changed to maintain the required performance. Power plants do add or change catalyst layers during temporary shutdowns, but it is expensive. However, many companies do not have only one power plant, but instead they can have a fleet of coal-fired power plants. A fleet of power plants can use EPA cap and trade programs to have an outlet NOx emission below the allowances for the fleet. For that reason, the main aim of this research is to develop an SCR management mathematical optimization methods that, with a given set of scheduled outages for a fleet of power plants, minimizes the total cost of the entire fleet of power plants and also maintain outlet NO x below the desired target for the entire fleet. We use a multi commodity network flow problem (MCFP) that creates edges that represent all the SCR catalyst layers for each plant. This MCFP is relaxed because it does not consider average daily NOx constraint, and it is solved by a binary integer program. After that, we add the average daily NOx constraint to the model with a schedule elimination constraint (MCFPwSEC). The MCFPwSEC eliminates, one by one, the solutions that do not satisfy the average daily

  6. Dry diamond wire sawing techniques to be used in an active environment

    International Nuclear Information System (INIS)

    Loftus, S.

    2003-01-01

    Dry diamond wire sawing techniques usable in an active environment has the following benefits: - Reduced personnel exposure time due the remote control and operation of the cutting equipment, the operator is positioned outside the active cell when controlling the equipment; - The equipment will be reusable with only the diamond cutting wire and the drive wheel rubber inserts coming into contact with potentially contaminated material; - The reduced impact on the existing ventilation systems from fumes or particulate blinding in-cell filters. - No dismantling work has to be carried out on the object to make it suitable for cutting using diamond wire cutting; - The diamond wire is the only piece of equipment subject to short-term replacement due to wear. The paper presents the following issues: The project the equipment is to be used on; -The equipment to be used; - Cutting machine support frame; - Drive units; - Wire coolant device. The seconds part of the paper deals with in-active cutting trials. To produce a strategy for cutting up a vessel in an active facility, the cutting technique proposed for size reducing the vessel to be tested implies establishing its suitability before developing the cutting rig that will be used for the actual task. A mock-up of the vessel was manufactured and size reduced using an existing cutting rig located at the supplies works. This sets out and records the results of the trials performed to functionally demonstrate the adequacy of using a diamond wire to cut the vessel into several pieces. The trials were performed at Diamant Boart test facility in Brussels.The objectives of the vessel cutting trials were: - To assess if a double skinned mock-up of the vessel can be cut successfully, dry, using Diamant Boart diamond wire cooled using liquid nitrogen; - To optimise the cutting process to achieve maximum cutting speed, minimum nitrogen usage and optimise wire life; - To identify any changes to the cutting rig, heat exchanger or

  7. NMR imaging studies of coal

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Z.R.; Zhang, P.Z.; Ding, G.L.; Li, L.Y.; Ye, C.H. [University of Science and Technology, Beijing (China). Dept. of Chemistry

    1996-06-01

    The permeation transportation and swelling behavior of solvents into coal are investigated by NMR imaging using pyridine-d{sub 5} and acetone-d{sub 6}. Images of coal swollen with deuterated solvents illuminate proton distributions of mobile phases within the coal macromolecular networks. More information about the chemical and physical structure of coal can be obtained using NMR imaging techniques.

  8. A novel collagen film with micro-rough surface structure for corneal epithelial repair fabricated by freeze drying technique

    International Nuclear Information System (INIS)

    Liu, Yang; Ren, Li; Wang, Yingjun

    2014-01-01

    Highlights: • Collagen film with micro-rough surface is fabricated by freeze drying technique. • The film has suitable water uptake capability and toughness performance. • The film has good optical performance. • Human corneal epithelial cells studies confirmed the biocompatibility of the film. - Abstract: Corneal epithelial defect is a common disease and keratoplasty is a common treatment method. A collagen film with micro-rough surface was fabricated through a simple freeze drying technique in this study. Compared with the air-dried collagen film (AD-Col), this freeze-dried collagen film (FD-Col) has a more suitable water uptake capability (about 85.5%) and toughness performance. Both of the two films have good optical properties and the luminousness of them is higher than 80%. Besides, the adhesion and proliferation rate of human corneal epithelial cells on the micro-rough surface of FD-Col film is higher than that on the smooth surface of AD-Col film. The results indicate that this FD-Col film may have potential applications for corneal epithelial repair

  9. A novel collagen film with micro-rough surface structure for corneal epithelial repair fabricated by freeze drying technique

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yang [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641 (China); National Engineering Research Center for Tissue Restoration and Reconstruction, Guangzhou 510006 (China); Guangdong Province Key Laboratory of Biomedical Engineering, South China University of Technology, Guangzhou 510006 (China); Ren, Li, E-mail: psliren@scut.edu.cn [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641 (China); National Engineering Research Center for Tissue Restoration and Reconstruction, Guangzhou 510006 (China); Guangdong Province Key Laboratory of Biomedical Engineering, South China University of Technology, Guangzhou 510006 (China); Wang, Yingjun, E-mail: imwangyj@163.com [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641 (China); National Engineering Research Center for Tissue Restoration and Reconstruction, Guangzhou 510006 (China); Guangdong Province Key Laboratory of Biomedical Engineering, South China University of Technology, Guangzhou 510006 (China)

    2014-05-01

    Highlights: • Collagen film with micro-rough surface is fabricated by freeze drying technique. • The film has suitable water uptake capability and toughness performance. • The film has good optical performance. • Human corneal epithelial cells studies confirmed the biocompatibility of the film. - Abstract: Corneal epithelial defect is a common disease and keratoplasty is a common treatment method. A collagen film with micro-rough surface was fabricated through a simple freeze drying technique in this study. Compared with the air-dried collagen film (AD-Col), this freeze-dried collagen film (FD-Col) has a more suitable water uptake capability (about 85.5%) and toughness performance. Both of the two films have good optical properties and the luminousness of them is higher than 80%. Besides, the adhesion and proliferation rate of human corneal epithelial cells on the micro-rough surface of FD-Col film is higher than that on the smooth surface of AD-Col film. The results indicate that this FD-Col film may have potential applications for corneal epithelial repair.

  10. Techniques to determine ignition, flame stability and burnout of blended coals in p.f. power station boilers

    Energy Technology Data Exchange (ETDEWEB)

    Su, S.; Pohl, J.H.; Holcombe, D.; Hart, J.A. [University of Queensland, Brisbane, Qld. (Australia). Dept. of Chemical Engineering

    2001-07-01

    The blending of coals has become popular to improve the performance of coals, to meet specifications of power plants and to reduce the cost of coals. This article reviews the results and provides new information on ignition, flame stability, and carbon burnout studies of blended coals. The reviewed studies were conducted in laboratory-, pilot-, and full-scale facilities. The new information was taken in pilot-scale studies. The results generally show that blending a high-volatile coal with a low-volatile coal or anthracite can improve the ignition, flame stability and burnout of the blends. This paper discusses two general methods to predict the performance of blended coals: (1) experiment; and (2) indices. Laboratory- and pilot-scale tests, at least, provide a relative ranking of the combustion performance of coal/blends in power station boilers. Several indices, volatile matter content, heating value and a maceral index, can be used to predict the relative ranking of ignitability and flame stability of coals and blends. The maceral index, fuel ratio, and vitrinite reflectance can also be used to predict the absolute carbon burnout of coal and blends within limits. 59 refs., 20 figs., 4 tabs.

  11. Self-scrubbing coal

    International Nuclear Information System (INIS)

    Kindig, J.K.

    1992-01-01

    More than 502 million tons - 65 percent of all coal shipped to utilities in 1990 - were above 1.2 pounds of sulfur dioxide per million Btu. Most of the coal, even though cleaned in conventional coal preparation plants, still does not meet the emission limitation the Clean Air Act Amendments mandate for the year 2000. To cope with this fact, most utilities plan to switch to low sulfur (western U.S. or Central Appalachian) coal or install scrubbers. Both solutions have serous drawbacks. Switching puts local miners out of work and weakens the economy in the utility's service territory. Scrubbing requires a major capital expenditure by the utility. Scrubbers also increase the operating complexity and costs of the generating station and produce yet another environmental problem, scrubber sludge. Employing three new cost-effective technologies developed by Customer Coals International (CCl), most non-compliance coals east of the Mississippi River can be brought into year-2000 compliance. The compliance approach employed, depends upon the characteristics of the raw coal. Three types of raw coal are differentiated, based upon the amount of organic sulfur in the coals and the ease (or difficultly) of liberating the pyrite. They are: Low organic sulfur content and pyrite that liberates easily. Moderate organic sulfur content and pyrite that liberates easily. High organic sulfur content or the pyrite liberates with difficulty. In this paper examples of each type of raw coal are presented below, and the compliance approach employed for each is described. The names of the beneficiated coal products produced from each type of raw coal give above are: Carefree Coal, Self-Scrubbing Coal and Dry-Scrubbing Coal

  12. Comparing and assessing different measurement techniques for mercury in coal systhesis gas

    Energy Technology Data Exchange (ETDEWEB)

    Maxwell, D.P.; Richardson, C.F. [Radian Corporation, Austin, TX (United States)

    1995-11-01

    Three mercury measurement techniques were performed on synthesis gas streams before and after an amine-based sulfur removal system. The syngas was sampled using (1) gas impingers containing a nitric acid-hydrogen peroxide solution, (2) coconut-based charcoal sorbent, and (3) an on-line atomic absorption spectrophotometer equipped with a gold amalgamation trap and cold vapor cell. Various impinger solutions were applied upstream of the gold amalgamation trap to remove hydrogen sulfide and isolate oxidized and elemental species of mercury. The results from these three techniques are compared to provide an assessment of these measurement techniques in reducing gas atmospheres.

  13. Drying of lucuma (Pouteria obovata) using the technique of Refracting WindowTM

    OpenAIRE

    Diego Gamboa; Deiner Ibáñez; Marcela Meléndez; Edgar Paredes; Raúl Siche

    2014-01-01

    Lucuma is a fruit that is experiencing a growing trend in commercial ground into flour for use in the food industry. This study aimed to obtain lucuma flour using the method of refractive window drying and evaluate the effect of the thickness of lucuma pulp and drying time on flour moisture and color. It was used a Composite Design Central Rotary (DCCR) with time between 10 and 50 min and the thickness between 1 and 3 mm. A fixed temperature of 95 °C and mylar film (metallized polyethylene te...

  14. Coal preparation

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    The acid rain control legislation has prompted the Department of Energy (DOE) to seek new technology using the Clean Coal Technology program solicitation. The main goal of the program is to reduce SO 2 emissions below 9 Mt/a (10 million stpy) and NO x emission below 5.4 Mt/a (6 million stpy) by the year 2000. This would be accomplished by using precombustion, combustion, post combustion and conversion technology. Utilities are considering installing new scrubbers, switching fuel or possibly deep clean. However, the time required to implement the control technology is short. Due to the legislation, about 110 plants will have to adopt one of the approaches. This paper reports that in characterization of coal, Ames Laboratory used a scanning electron microscope- based, automated image analysis (SEM-AIA) technique to identify coal and mineral matter association. Various forms of organic sulfur were identified using peroxyacetic acid oxidation of coal. This was followed by subsequent microscopic, GC-MS, and HRMS analysis by Southern Illinois University. In ultrafine grinding of coal, it was reported by the Mining and Mineral Institute of Alabama that silica sand or flint shot used less energy compared to steel ball mills

  15. The application of an isotopic ratio technique to a study of the atmospheric oxidation of sulfur dioxide in the plume from a coal fired power plant

    International Nuclear Information System (INIS)

    Newman, L.; Forrest, J.; Manowitz, B.

    1975-01-01

    The extent of oxidation of sulfur dioxide to sulfate in the plume of a coal fired plant has been studied by using sampling with a single engine aircraft. A technique employing isotopic ratio measurements was utilized in conjunction with simultaneous concentration measurements of sulfur dioxide and sulfate. The use of sulfur hexafluroide as a conservative tracer was explored. The heterogeneous mechanism postulated in an oil fired plume study appears to pertain to the coal fired plume. However, the extent of oxidation seldom exceeded 5% and is limited by the relatively low particulate content of the coal fired plume. Evidence is presented for the apparent dropping out of sulfate from the plume. Implications pertaining to the ambient oxidation of sulfur dioxide are presented. (author)

  16. Comparative study of DNA encapsulation into PLGA microparticles using modified double emulsion methods and spray drying techniques.

    Science.gov (United States)

    Oster, C G; Kissel, T

    2005-05-01

    Recently, several research groups have shown the potential of microencapsulated DNA as adjuvant for DNA immunization and in tissue engineering approaches. Among techniques generally used for microencapsulation of hydrophilic drug substances into hydrophobic polymers, modified WOW double emulsion method and spray drying of water-in-oil dispersions take a prominent position. The key parameters for optimized microspheres are particle size, encapsulation efficiency, continuous DNA release and stabilization of DNA against enzymatic and mechanical degradation. This study investigates the possibility to encapsulate DNA avoiding shear forces which readily degrade DNA during this microencapsulation. DNA microparticles were prepared with polyethylenimine (PEI) as a complexation agent for DNA. Polycations are capable of stabilizing DNA against enzymatic, as well as mechanical degradation. Further, complexation was hypothesized to facilitate the encapsulation by reducing the size of the macromolecule. This study additionally evaluated the possibility of encapsulating lyophilized DNA and lyophilized DNA/PEI complexes. For this purpose, the spray drying and double emulsion techniques were compared. The size of the microparticles was characterized by laser diffractometry and the particles were visualized by scanning electron microscopy (SEM). DNA encapsulation efficiencies were investigated photometrically after complete hydrolysis of the particles. Finally, the DNA release characteristics from the particles were studied. Particles with a size of <10 microm which represent the threshold for phagocytic uptake could be prepared with these techniques. The encapsulation efficiency ranged from 100-35% for low theoretical DNA loadings. DNA complexation with PEI 25?kDa prior to the encapsulation process reduced the initial burst release of DNA for all techniques used. Spray-dried particles without PEI exhibited high burst releases, whereas double emulsion techniques showed continuous

  17. FY 1981 Report on the results of Sunshine Project. Research and development of techniques for liquefaction of coal (Development of extraction type liquefaction plant using brown coal-based solvent and researches on milling at high temperature in oil); 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu, kattankei yozai chushutsu ekika plant no kaihatsu seika hokokusho. Koon yuchu funsai no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    This program is aimed at establishment of the techniques for milling of brown coal treated by primary dehydration and slurry adjustment, and secondary hydration plant, as part of the project for developing the techniques for liquefaction of brown coal. Brown coal (Australian Yallourn coal) treated by primary dehydration, solvents (creosote and decrystallized anthracene), and catalysts are used as the stock samples, to investigate the coal characteristics with respect to milling crushability, dehydration and liquefaction reactivity, and the slurries are prepared by changing coal charge rate, solvent and preparation temperature, to collect the data regarding, e.g., coal concentration, coal particle size, moisture level and liquefaction reactivity. It is found that milling crushability tends to decrease as coal charge rate or solvent/coal ratio increases whether creosote or decrystallized anthracene is used as the solvent. Milling crushability is unaffected by slurry preparation temperature. Content of residual moisture in the slurry decreases to 1% or less, when slurry preparation temperature is increased to 100 degrees C or higher. Liquefaction reactivity of the slurry shows slight dependence on slurry preparation temperature, when it is increased to 180 degrees C. (NEDO)

  18. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Topical report, LNCFS Levels 1 and 3 test results

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-17

    This report presents results from the third phase of an Innovative Clean Coal Technology (ICC-1) project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The purpose of this project was to study the NO{sub x} emissions characteristics of ABB Combustion Engineering`s (ABB CE) Low NO{sub x} Concentric Firing System (LNCFS) Levels I, II, and III. These technologies were installed and tested in a stepwise fashion at Gulf Power Company`s Plant Lansing Smith Unit 2. The objective of this report is to provide the results from Phase III. During that phase, Levels I and III of the ABB C-E Services Low NO{sub x} Concentric Firing System were tested. The LNCFS Level III technology includes separated overfire air, close coupled overfire air, clustered coal nozzles, flame attachment coal nozzle tips, and concentric firing. The LNCFS Level I was simulated by closing the separated overfire air nozzles of the LNCFS Level III system. Based upon long-term data, LNCFS Level HI reduced NO{sub x} emissions by 45 percent at full load. LOI levels with LNCFS Level III increased slightly, however, tests showed that LOI levels with LNCFS Level III were highly dependent upon coal fineness. After correcting for leakage air through the separated overfire air system, the simulated LNCFS Level I reduced NO{sub x} emissions by 37 percent. There was no increase in LOI with LNCFS Level I.

  19. Effect of different drying techniques on flowability characteristics and chemical properties of natural carbohydrate-protein Gum from durian fruit seed

    Directory of Open Access Journals (Sweden)

    Mirhosseini Hamed

    2013-01-01

    Full Text Available Abstract Background A natural carbohydrate biopolymer was extracted from the agricultural biomass waste (durian seed. Subsequently, the crude biopolymer was purified by using the saturated barium hydroxide to minimize the impurities. Finally, the effect of different drying techniques on the flow characteristics and functional properties of the purified biopolymer was investigated. The present study elucidated the main functional characteristics such as flow characteristics, water- and oil-holding capacity, solubility, and foaming capacity. Results In most cases except for oven drying, the bulk density decreased, thus increasing the porosity. This might be attributed to the increase in the inter-particle voids of smaller sized particles with larger contact surface areas per unit volume. The current study revealed that oven-dried gum and freeze-dried gum had the highest and lowest compressibility index, thus indicating the weakest and strongest flowability among all samples. In the present work, the freeze-dried gum showed the lowest angle of repose, bulk, tapped and true density. This indicates the highest porosity degree of freeze dried gum among dried seed gums. It also exhibited the highest solubility, and foaming capacity thus providing the most desirable functional properties and flow characteristics among all drying techniques. Conclusion The present study revealed that freeze drying among all drying techniques provided the most desirable functional properties and flow characteristics for durian seed gum.

  20. Sludge derived fuel technique of sewage sludge by oil vacuum evaporation drying

    International Nuclear Information System (INIS)

    Kim, Seokhwan; Lim, Byungran; Lee, Sookoo

    2010-01-01

    Sewage sludge contains high content of organic materials and its water content is also very high about 80% even after filtration process. Landfill as a sludge treatment methods can cause odor problem and leachate production which can derive the secondary contamination of soil and groundwater. The ocean dumping will be prohibited according to the London Convention and domestic stringent environmental regulation. Based on domestic agenda on organic sewage sludge treatment, the ocean disposal will be prohibited from 2012, thus alternative methods are demanded. Sludge derived fuel (SDF) technology can alleviate the emission of greenhouse gas and recover energy from sludge. For proper treatment and SDF production from sludge, the vacuum evaporation and immersion frying technology was adopted in this research. This technology dries moisture in sludge after mixing with oil such as Bunker C oil, waste oil or waste food oil etc. Mixing sludge and oil secures liquidity of organic sludge to facilitate handling throughout the drying process. The boiling temperature could be maintained low through vacuum condition in whole evaporation process. This study was performed to find the optimum operating temperature and pressure, the mixing ratio of sludge and oil. Finally, we could obtained SDF which moisture content was less than 5%, its heating value was over 4,500 kcal/ kg sludge. This heating value could satisfy the Korean Fuel Standard for the Recycle Products. Assessed from the perspective of energy balance and economic evaluation, this sludge drying system could be widely used for the effective sludge treatment and the production of SDF. (author)

  1. 6th Conference on Coal Utilization Technology; Dai 6 kai sekitan riyo gijutsu kaigi koenshu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-09-01

    The paper compiled the papers presented in the 6th Conference on Coal Utilization Technology held in September 1996. With relation to the fluidized bed boiler, reported were Field operation test of Wakamatsu PFBC combined cycle power plant and Development of pressurized internally circulating fluidized bed combustion technology. Regarding the coal reformation, Development of advanced coal cleaning process, Coal preparation and coal cleaning in the dry process, etc. Concerning the combustion technology, Study of the O2/CO2 combustion technology, Development of pressurized coal partial combustor, etc. About the CWM, Development of low rank coals upgrading and their CWM producing technology, Technique of CWM distribution system, etc. Relating to the coal ash, Engineering characteristics of the improved soil by deep mixing method using coal ash, Employment of fluidized bed ash as a basecourse material, On-site verification trials using fly ash for reclamation behind bulkheads, Water permeabilities of pulverized fuel ash, Separation of unburned carbon from coal fly ash through froth flotation, Practical use technology of coal ash (POZ-O-TEC), etc

  2. Coal geopolitics

    International Nuclear Information System (INIS)

    Giraud, P.N.; Suissa, A.; Coiffard, J.; Cretin, D.

    1991-01-01

    This book divided into seven chapters, describes coal economic cycle. Chapter one: coals definition; the principle characteristics and properties (origin, calorific power, international classification...) Chapter two: the international coal cycle: coal mining, exploration, coal reserves estimation, coal handling coal industry and environmental impacts. Chapter three: the world coal reserves. Chapter four: the consumptions, productions and trade. Chapter five: the international coal market (exporting mining companies; importing companies; distributors and spot market operators) chapter six: the international coal trade chapter seven: the coal price formation. 234 refs.; 94 figs. and tabs [fr

  3. Inorganic Constituents in Coal

    Directory of Open Access Journals (Sweden)

    Rađenović A.

    2006-02-01

    Full Text Available Coal contains not only organic matter but also small amounts of inorganic constituents. More thanone hundred different minerals and virtually every element in the periodic table have been foundin coal. Commonly found group minerals in coal are: major (quartz, pyrite, clays and carbonates,minor, and trace minerals. Coal includes a lot of elements of low mass fraction of the orderof w=0.01 or 0.001 %. They are trace elements connected with organic matter or minerals comprisedin coal. The fractions of trace elements usually decrease when the rank of coal increases.Fractions of the inorganic elements are different, depending on the coal bed and basin. A varietyof analytical methods and techniques can be used to determine the mass fractions, mode ofoccurrence, and distribution of organic constituents in coal. There are many different instrumentalmethods for analysis of coal and coal products but atomic absorption spectroscopy – AAS is theone most commonly used. Fraction and mode of occurrence are one of the main factors that haveinfluence on transformation and separation of inorganic constituents during coal conversion.Coal, as an important world energy source and component for non-fuels usage, will be continuouslyand widely used in the future due to its relatively abundant reserves. However, there is aconflict between the requirements for increased use of coal on the one hand and less pollution onthe other. It’s known that the environmental impacts, due to either coal mining or coal usage, canbe: air, water and land pollution. Although, minor components, inorganic constituents can exert asignificant influence on the economic value, utilization, and environmental impact of the coal.

  4. Investigation of karst collapse based on 3-D seismic technique and DDA method at Xieqiao coal mine, China

    Energy Technology Data Exchange (ETDEWEB)

    Zuo, Jian-Ping; Chen, Zhong-Hui [State Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology, Beijing 100083 (China); Institute of Rock Mechanical and Fractals, China University of Mining and Technology, Beijing 100083 (China); Peng, Su-Ping; Li, Yong-Jun [State Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology, Beijing 100083 (China); Xie, He-Ping [Institute of Rock Mechanical and Fractals, China University of Mining and Technology, Beijing 100083 (China)

    2009-06-01

    Karst collapse is a serious geological problem in most of the coal mines in the north of China, but recently it has been found in the south as well. The present study is aimed at investigating subsidence mechanism and deformation field of a karst collapse column at Xieqiao, in the south of China. A method of three-dimensional (3-D) seismic technique has been successful in exploring the spatial morphology of the karst collapse at Xieqiao, and the discontinuous deformation analysis (DDA) method is used to calculate the deformation field and analyze the subsidence mechanism. The results indicated that DDA could approximately simulate and back analyze the subsidence process and strata deformation fields. The subsidence processes of the collapse column depend on the sizes of the karst caves. With the continuous expansion of the karst caves, a semi-elliptic stress field, local separation strata and fracture zone will be formed around the karst cave. Moreover, they will gradually expand upwards along the vertical direction. The paper also indicates that the subsidence failure stage may trigger a sudden collapse of the karst column because of the sudden energy release. Also, it will make a great impact on the vicinity working face so as to cause a rock burst. The effects of the friction angle of rock strata on the subsidence mechanism were reported firstly based on DDA. (author)

  5. Freeze-drying technology: A separation technique for liquid nuclear materials

    International Nuclear Information System (INIS)

    Musgrave, J.A.; Efurd, D.W.; Banar, J.C.

    1997-01-01

    Freeze-drying technology (FDT) has been around for several decades as a separation technology. Most commonly, FDT is associated with the processing of food, but the largest industrial-scale use of FDT is in the pharmaceutical industry. Through a Cooperative Research and Development Agreement (CRADA) with BOC Edwards Calumatic, we are demonstrating the feasibility of FDT as a waste minimization and pollution prevention technology. This is a novel and innovative application of FDT. In addition, we plan to demonstrate that the freeze-dried residue is an ideal feed material for ceramic stabilization of radioactive waste and excess fissile material. The objective of this work is to demonstrate the feasibility of FDT for the separation of complex radioactive and nonradioactive materials, including liquids, slurries, and sludges containing a wide variety of constituents in which the separation factors are >10 8 . This is the first application of FDT in which the condensate is of primary importance. Our focus is applying this technology to the elimination of radioactive liquid discharges from facilities at Los Alamos National Laboratory (LANL) and within the U.S. Department of Energy complex; however, successful demonstration will lead to nuclear industry-wide applications

  6. Dry sliding wear behaviour of organo-modified montmorillonite filled epoxy nanocomposites using Taguchi's techniques

    International Nuclear Information System (INIS)

    Rashmi; Renukappa, N.M.; Suresha, B.; Devarajaiah, R.M.; Shivakumar, K.N.

    2011-01-01

    Highlights: → Successful fabrication of OMMT filled epoxy nanocomposites by high-shear mixing mehod. → Systematic tribological behaviour of the nanocomposites was made using Taguchi method. → Worn surface morphologies of the samples were discussed for different wear mechanisms. → Generation of wear data for sliding/bearing parts for different industries. -- Abstract: The aim of the research article is to study the dry sliding wear behaviour of epoxy with different wt.% of organo-modified montmorillonite (OMMT) filled nanocomposites. An orthogonal array (L 9 ) was used to investigate the influence of tribological parameters. The results indicate that the sliding distance emerges as the most significant factor affecting wear rate of epoxy nanocomposites. Experimental results showed that the inclusion of 5 wt.% OMMT nanofiller increased the wear resistance of the epoxy nanocomposite significantly. Furthermore, the worn surfaces of the samples were analyzed by scanning electron microscopy (SEM) to study the wear mechanisms and to correlate them with the wear test results.

  7. Fluidised bed gasification of low grade South African coals

    CSIR Research Space (South Africa)

    North, BC

    2006-09-01

    Full Text Available gasifiers. Fluidised bed Entrained flow Coal particle size 0.5 mm – 5 mm 0 – 0.5 mm Coal moisture Dry Dry/slurry Coal type Non-caking coals Any coal Ash in coal < 60% < 30% Gasification agents Air/steam/oxygen Steam/oxygen Gasification... properties important for fluidised bed gasification are: square4 Coal reactivity in atmospheres of CO2 and H2O square4 Caking index and free swelling index (FSI) square4 Ash fusion temperature (AFT) 5.1 Coal reactivity The gasifcation reactions (1...

  8. Dependence between fusion temperatures and chemical components of a certain type of coal using classical, non-parametric and bootstrap techniques

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez-Manteiga, W.; Prada-Sanchez, J.M.; Fiestras-Janeiro, M.G.; Garcia-Jurado, I. (Universidad de Santiago de Compostela, Santiago de Compostela (Spain). Dept. de Estadistica e Investigacion Operativa)

    1990-11-01

    A statistical study of the dependence between various critical fusion temperatures of a certain kind of coal and its chemical components is carried out. As well as using classical dependence techniques (multiple, stepwise and PLS regression, principal components, canonical correlation, etc.) together with the corresponding inference on the parameters of interest, non-parametric regression and bootstrap inference are also performed. 11 refs., 3 figs., 8 tabs.

  9. Enhanced dissolution and oral bioavailability of valsartan solid dispersions prepared by a freeze-drying technique using hydrophilic polymers.

    Science.gov (United States)

    Xu, Wei-Juan; Xie, Hong-Juan; Cao, Qing-Ri; Shi, Li-Li; Cao, Yue; Zhu, Xiao-Yin; Cui, Jing-Hao

    2016-01-01

    This study aimed to improve the dissolution rate and oral bioavailability of valsartan (VAL), a poorly soluble drug using solid dispersions (SDs). The SDs were prepared by a freeze-drying technique with polyethylene glycol 6000 (PEG6000) and hydroxypropylmethylcellulose (HPMC 100KV) as hydrophilic polymers, sodium hydroxide (NaOH) as an alkalizer, and poloxamer 188 as a surfactant without using any organic solvents. In vitro dissolution rate and physicochemical properties of the SDs were characterized using the USP paddle method, differential scanning calorimetry (DSC), X-ray diffractometry (XRD) and Fourier transform-infrared (FT-IR) spectroscopy, respectively. In addition, the oral bioavailability of SDs in rats was evaluated by using VAL (pure drug) as a reference. The dissolution rates of the SDs were significantly improved at pH 1.2 and pH 6.8 compared to those of the pure drug. The results from DSC, XRD showed that VAL was molecularly dispersed in the SDs as an amorphous form. The FT-IR results suggested that intermolecular hydrogen bonding had formed between VAL and its carriers. The SDs exhibited significantly higher values of AUC 0-24 h and Cmax in comparison with the pure drug. In conclusion, hydrophilic polymer-based SDs prepared by a freeze-drying technique can be a promising method to enhance dissolution rate and oral bioavailability of VAL.

  10. Preparation of sustained-release coated particles by novel microencapsulation method using three-fluid nozzle spray drying technique.

    Science.gov (United States)

    Kondo, Keita; Niwa, Toshiyuki; Danjo, Kazumi

    2014-01-23

    We prepared sustained-release microcapsules using a three-fluid nozzle (3N) spray drying technique. The 3N has a unique, three-layered concentric structure composed of inner and outer liquid nozzles, and an outermost gas nozzle. Composite particles were prepared by spraying a drug suspension and an ethylcellulose solution via the inner and outer nozzles, respectively, and mixed at the nozzle tip (3N-PostMix). 3N-PostMix particles exhibited a corrugated surface and similar contact angles as ethylcellulose bulk, thus suggesting encapsulation with ethylcellulose, resulting in the achievement of sustained release. To investigate the microencapsulation process via this approach and its usability, methods through which the suspension and solution were sprayed separately via two of the four-fluid nozzle (4N) (4N-PostMix) and a mixture of the suspension and solution was sprayed via 3N (3N-PreMix) were used as references. It was found that 3N can obtain smaller particles than 4N. The results for contact angle and drug release corresponded, thus suggesting that 3N-PostMix particles are more effectively coated by ethylcellulose, and can achieve higher-level controlled release than 4N-PostMix particles, while 3N-PreMix particles are not encapsulated with pure ethylcellulose, leading to rapid release. This study demonstrated that the 3N spray drying technique is useful as a novel microencapsulation method. Copyright © 2013 Elsevier B.V. All rights reserved.

  11. Antioxidant activity, the content of total phenols and flavonoids in the ethanol extracts of Mentha longifolia (L. Hudson dried by the use of different techniques

    Directory of Open Access Journals (Sweden)

    Stanisavljević Dragana M.

    2012-01-01

    Full Text Available In this study, we have examined the yield of extracted substances obtained by means of extraction using 70 % ethanol (v/v, the content of total phenols and flavonoids, as well as the antioxidant activity of the extracts obtained from the samples of the herbs dried by means of different techniques. Wild mint Mentha longifolia (L. Hudson was dried naturally in a laboratory oven at a temperature of 45 °C and in an absorptive low temperature condensation oven at 35°C. The highest yield of extracts was obtained from the naturally dried herbs and the lowest from the herbs dried in the low temperature condensation drying oven. The content of total phenols and flavonoids was determined by spectrophotometric methods with an FC reagent and by the complexation reaction with aluminium-chloride, respectively. The extract of the naturally dried herbs had the highest overall content of phenols (113.8±2.0 mg of gallic acid/g of the dry extract and flavonoids (106.7±0.3 mg of rutin/g of the dry extract. The highest antioxidant activity determined by the FRAP and DPPH assay was determined in the extracts obtained from naturally dried herbs (2.76±0.15 mmol Fe2+/mg of the dry extract and EC50=0.022±0.001 mg/ml, while the lowest was obtained from the extracts of herbs dried in the laboratory oven (1.13±0.11 mmol Fe2+/mg of the dry extract and EC50=0.033±0.001 mg/ml. The HPLC-DAD analysis result show that the greatest content of phenolic compounds show extract obtained from naturally dried plant material. The dominant phenolic component in the all extracts is Kaempferol 3-O-glucoside. The content of all phenolic compound strongly depend on the drying conditions.

  12. Development of biodegradable methylprednisolone microparticles for treatment of articular pathology using a spray-drying technique

    Directory of Open Access Journals (Sweden)

    Tobar-Grande B

    2013-05-01

    Full Text Available Blanca Tobar-Grande,1 Ricardo Godoy,1 Paulina Bustos,2 Carlos von Plessing,1 Elias Fattal,3,4 Nicolas Tsapis,3,4 Claudia Olave,1 Carolina Gómez-Gaete11Departamento de Farmacia, Facultad de Farmacia, Universidad de Concepción, Concepción, Chile; 2Departamento de Bioquímica Clínica e Inmunología, Facultad de Farmacia, Universidad de Concepción, Concepción, Chile; 3Univ Paris-Sud, Institut Galien Paris-Sud, Faculté de Pharmacie, Châtenay-Malabry, France; 4CNRS, UMR 8612, Faculté de Pharmacie, Châtenay-Malabry, FranceAbstract: In this work, microparticles were prepared by spray-drying using albumin, chondroitin sulfate, and hyaluronic acid as excipients to create a controlled-release methylprednisolone system for use in inflammatory disorders such as arthritis. Scanning electron microscopy demonstrated that these microparticles were almost spherical, with development of surface wrinkling as the methylprednisolone load in the formulation was increased. The methylprednisolone load also had a direct influence on the mean diameter and zeta potential of the microparticles. Interactions between formulation excipients and the active drug were evaluated by x-ray diffraction, differential scanning calorimetry, and thermal gravimetric analysis, showing limited amounts of methylprednisolone in a crystalline state in the loaded microparticles. The encapsulation efficiency of methylprednisolone was approximately 89% in all formulations. The rate of methylprednisolone release from the microparticles depended on the initial drug load in the formulation. In vitro cytotoxic evaluation using THP-1 cells showed that none of the formulations prepared triggered an inflammatory response on release of interleukin-1ß, nor did they affect cellular viability, except for the 9.1% methylprednisolone formulation, which was the maximum test concentration used. The microparticles developed in this study have characteristics amenable to a therapeutic role in

  13. Molecular accessibility in solvent swelled coals. Quarterly report, [April--June 1993

    Energy Technology Data Exchange (ETDEWEB)

    Kispert, L.D.

    1993-08-01

    The effect of weathering (oxidation and dehydration upon exposure to air) on the molecular accessibility of potential catalysts was studied by the EPR spin probe technique. Fresh samples of all 8 APCS coals were exposed to air for periods up to 36 days. Weathering produced significant effects on the retention of spin probes in most of the APCS coals under 91 % carbon (dmmf). It was determined that the lower ranked coal (Beulah Zap and Wyodak) under went a structural collapse which precluded retention of even spin probe VIII. However, medium ranked coals exhibited improved retention upon weathering when swelled in toluene. Swelling with pyridine opened up small pores for 81--86% carbon which is not observed for swelling with toluene. Changes in coal structure were successfully followed by the EPR spin probe method. A detailed analysis of the data collected from the swelling of coals oxidized in a moisture free environment was completed to differentiate between weathering and oxidation. Eight vacuum dried APCS coals were oxidized in an enclosed, pure oxygen, moisture free environment, and the effects of oxidation alone on coal structure were studied by the intercalation of EPR spin probes. The data shows a factor of 5 increase in spin probe retention for some coals oxidized in O{sub 2} versus air., suggesting a large increase in oxidized material. Particular care was taken during the swelling procedures to avoid exposure of the coal samples to air or moisture. EPR spectra were then obtained for these 300 samples.

  14. COAL OF THE FUTURE (Supply Prospects for Thermal Coal by 2030-2050)

    OpenAIRE

    2007-01-01

    The report, produced by Messrs. Energy Edge Ltd. (the U.K.) for the JRC Institute for Energy, aims at making a techno-economic analysis of novel extraction technologies for coal and their potential contribution to the global coal supply. These novel extraction technologies include: advanced coal mapping techniques, improved underground coal mining, underground coal gasification and utilisation of coalmine methane gas.

  15. Nanospray Drying as a Novel Technique for the Manufacturing of Inhalable NSAID Powders

    Directory of Open Access Journals (Sweden)

    Aquino Rita Patrizia

    2014-01-01

    Full Text Available The aim of this research was to evaluate the potential of the nanospray drier as a novel apparatus for the manufacturing of a dry powder for inhalation containing ketoprofen lysinate, a nonsteroidal anti-inflammatory drug able to control the inflammation in cystic fibrosis patients. We produced several ketoprofen lysinate and leucine powder batches by means of nanospray dryer, studying the influence of process parameters on yield, particle properties (size distribution and morphology, and, mainly, aerodynamic properties of powders. Micronized particles were prepared from different hydroalcoholic solutions (alcohol content from 0 to 30% v/v using ketoprofen in its lysine salt form and leucine as dispersibility enhancer in different ratios (from 5 to 15% w/w with a total solid concentration ranging from 1 to 7% w/v. Results indicated that the spray head equipped with a 7 µm nozzle produced powders too big to be inhaled. The reduction of nozzle size from 7 to 4 µm led to smaller particles suitable for inhalation but, at the same time, caused a dramatic increase in process time. The selection of process variables, together with the nozzle pretreatment with a surfactant solution, allowed us to obtain a free flowing powder with satisfying aerosol performance, confirming the usefulness of the nanospray drier in the production of powder for inhalation.

  16. Identifying tropical dry forests extent and succession via the use of machine learning techniques

    Science.gov (United States)

    Li, Wei; Cao, Sen; Campos-Vargas, Carlos; Sanchez-Azofeifa, Arturo

    2017-12-01

    Information on ecosystem services as a function of the successional stage for secondary tropical dry forests (TDFs) is scarce and limited. Secondary TDFs succession is defined as regrowth following a complete forest clearance for cattle growth or agriculture activities. In the context of large conservation initiatives, the identification of the extent, structure and composition of secondary TDFs can serve as key elements to estimate the effectiveness of such activities. As such, in this study we evaluate the use of a Hyperspectral MAPper (HyMap) dataset and a waveform LIDAR dataset for characterization of different levels of intra-secondary forests stages at the Santa Rosa National Park (SRNP) Environmental Monitoring Super Site located in Costa Rica. Specifically, a multi-task learning based machine learning classifier (MLC-MTL) is employed on the first shortwave infrared (SWIR1) of HyMap in order to identify the variability of aboveground biomass of secondary TDFs along a successional gradient. Our paper recognizes that the process of ecological succession is not deterministic but a combination of transitional forests types along a stochastic path that depends on ecological, edaphic, land use, and micro-meteorological conditions, and our results provide a new way to obtain the spatial distribution of three main types of TDFs successional stages.

  17. Development of biodegradable methylprednisolone microparticles for treatment of articular pathology using a spray-drying technique

    Science.gov (United States)

    Tobar-Grande, Blanca; Godoy, Ricardo; Bustos, Paulina; von Plessing, Carlos; Fattal, Elias; Tsapis, Nicolas; Olave, Claudia; Gómez-Gaete, Carolina

    2013-01-01

    In this work, microparticles were prepared by spray-drying using albumin, chondroitin sulfate, and hyaluronic acid as excipients to create a controlled-release methylprednisolone system for use in inflammatory disorders such as arthritis. Scanning electron microscopy demonstrated that these microparticles were almost spherical, with development of surface wrinkling as the methylprednisolone load in the formulation was increased. The methylprednisolone load also had a direct influence on the mean diameter and zeta potential of the microparticles. Interactions between formulation excipients and the active drug were evaluated by x-ray diffraction, differential scanning calorimetry, and thermal gravimetric analysis, showing limited amounts of methylprednisolone in a crystalline state in the loaded microparticles. The encapsulation efficiency of methylprednisolone was approximately 89% in all formulations. The rate of methylprednisolone release from the microparticles depended on the initial drug load in the formulation. In vitro cytotoxic evaluation using THP-1 cells showed that none of the formulations prepared triggered an inflammatory response on release of interleukin-1β, nor did they affect cellular viability, except for the 9.1% methylprednisolone formulation, which was the maximum test concentration used. The microparticles developed in this study have characteristics amenable to a therapeutic role in inflammatory pathology, such as arthritis. PMID:23737670

  18. Use of variance techniques to measure dry air-surface exchange rates

    Science.gov (United States)

    Wesely, M. L.

    1988-07-01

    The variances of fluctuations of scalar quantities can be measured and interpreted to yield indirect estimates of their vertical fluxes in the atmospheric surface layer. Strong correlations among scalar fluctuations indicate a similarity of transfer mechanisms, which is utilized in some of the variance techniques. The ratios of the standard deviations of two scalar quantities, for example, can be used to estimate the flux of one if the flux of the other is measured, without knowledge of atmospheric stability. This is akin to a modified Bowen ratio approach. Other methods such as the normalized standard-deviation technique and the correlation-coefficient technique can be utilized effectively if atmospheric stability is evaluated and certain semi-empirical functions are known. In these cases, iterative calculations involving measured variances of fluctuations of temperature and vertical wind velocity can be used in place of direct flux measurements. For a chemical sensor whose output is contaminated by non-atmospheric noise, covariances with fluctuations of scalar quantities measured with a very good signal-to-noise ratio can be used to extract the needed standard deviation. Field measurements have shown that many of these approaches are successful for gases such as ozone and sulfur dioxide, as well as for temperature and water vapor, and could be extended to other trace substances. In humid areas, it appears that water vapor fluctuations often have a higher degree of correlation to fluctuations of other trace gases than do temperature fluctuations; this makes water vapor a more reliable companion or “reference” scalar. These techniques provide some reliable research approaches but, for routine or operational measurement, they are limited by the need for fast-response sensors. Also, all variance approaches require some independent means to estimate the direction of the flux.

  19. Dry-plasma-free chemical etch technique for variability reduction in multi-patterning (Conference Presentation)

    Science.gov (United States)

    Kal, Subhadeep; Mohanty, Nihar; Farrell, Richard A.; Franke, Elliott; Raley, Angelique; Thibaut, Sophie; Pereira, Cheryl; Pillai, Karthik; Ko, Akiteru; Mosden, Aelan; Biolsi, Peter

    2017-04-01

    Scaling beyond the 7nm technology node demands significant control over the variability down to a few angstroms, in order to achieve reasonable yield. For example, to meet the current scaling targets it is highly desirable to achieve sub 30nm pitch line/space features at back-end of the line (BEOL) or front end of line (FEOL); uniform and precise contact/hole patterning at middle of line (MOL). One of the quintessential requirements for such precise and possibly self-aligned patterning strategies is superior etch selectivity between the target films while other masks/films are exposed. The need to achieve high etch selectivity becomes more evident for unit process development at MOL and BEOL, as a result of low density films choices (compared to FEOL film choices) due to lower temperature budget. Low etch selectivity with conventional plasma and wet chemical etch techniques, causes significant gouging (un-intended etching of etch stop layer, as shown in Fig 1), high line edge roughness (LER)/line width roughness (LWR), non-uniformity, etc. In certain circumstances this may lead to added downstream process stochastics. Furthermore, conventional plasma etches may also have the added disadvantage of plasma VUV damage and corner rounding (Fig. 1). Finally, the above mentioned factors can potentially compromise edge placement error (EPE) and/or yield. Therefore a process flow enabled with extremely high selective etches inherent to film properties and/or etch chemistries is a significant advantage. To improve this etch selectivity for certain etch steps during a process flow, we have to implement alternate highly selective, plasma free techniques in conjunction with conventional plasma etches (Fig 2.). In this article, we will present our plasma free, chemical gas phase etch technique using chemistries that have high selectivity towards a spectrum of films owing to the reaction mechanism ( as shown Fig 1). Gas phase etches also help eliminate plasma damage to the

  20. Effect of Microencapsulation by Spray-Drying and Freeze-Drying Technique on the Antioxidant Properties of Blueberry (Vaccinium myrtillus Juice Polyphenolic Compounds

    Directory of Open Access Journals (Sweden)

    Wilkowska Agnieszka

    2016-03-01

    Full Text Available Blueberry juice with high polyphenol concentration was spray- or freeze-dried using different coating materials: HP-β-cyclodextrin and β-cyclodextrin. The quality of the obtained powders was characterised by their anthocyanin content, total polyphenols and antioxidant capacity. SEM was used for monitoring structures and size (2–20 μm of the microparticles. The losses of total phenolic compounds during spray-drying reached 76–78% on average, while these of anthocyanins about 57%. Freeze-dried powders showed better retention values of anthocyanins, which was about 1.5-fold higher than for the spray-dried counterparts. All blueberry preparations studied were characterised by very high radical scavenging activity.

  1. Optimal coal import strategy

    International Nuclear Information System (INIS)

    Chen, C.Y.; Shih, L.H.

    1992-01-01

    Recently, the main power company in Taiwan has shifted the primary energy resource from oil to coal and tried to diversify the coal supply from various sources. The company wants to have the imported coal meet the environmental standards and operation requirements as well as to have high heating value. In order to achieve these objectives, establishment of a coal blending system for Taiwan is necessary. A mathematical model using mixed integer programming technique is used to model the import strategy and the blending system. 6 refs., 1 tab

  2. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide emissions from coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Sorge, J.N.; Larrimore, C.L.; Slatsky, M.D.; Menzies, W.R.; Smouse, S.M.; Stallings, J.W.

    1997-12-31

    This paper discusses the technical progress of a US Department of Energy Innovative Clean Coal Technology project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The primary objectives of the demonstration is to determine the long-term NOx reduction performance of advanced overfire air (AOFA), low NOx burners (LNB), and advanced digital control optimization methodologies applied in a stepwise fashion to a 500 MW boiler. The focus of this paper is to report (1) on the installation of three on-line carbon-in-ash monitors and (2) the design and results to date from the advanced digital control/optimization phase of the project.

  3. Present state in coal preparation. Stanje u pripremi uglja

    Energy Technology Data Exchange (ETDEWEB)

    Jevremovic, C. (Rudarsko-Geoloski Fakultet, Tuzla (Yugoslavia))

    1990-01-01

    Describes the low technological state of Yugoslav coal enterprises,in particular of those that exploit low grade lignite and brown coal with high ash and sulfur content. Unadjusted coal prices (almost the same price level for low and high energy coal) and absence of stringent laws on environmental pollution are regarded as main reasons for the low technological level of coal preparation and beneficiation plants. Modern preparation equipment for coal classification, coal washing, coal drying and briquetting is pointed out. Advanced coal carbonization and gasification should have a wider application in Yugoslavia for reducing environmental pollution and producing clean fuel.

  4. Pipe Wall Thickness Monitoring Using Dry-Coupled Ultrasonic Waveguide Technique

    International Nuclear Information System (INIS)

    Cheong, Yong Moo; Kim, Ha Nam; Kim, Hong Pyo

    2012-01-01

    In order to monitor a corrosion or FAC (Flow Accelerated Corrosion) in a pipe, there is a need to measure pipe wall thickness at high temperature. Ultrasonic thickness gauging is the most commonly used non-destructive testing technique for wall thickness measurement. However, current commonly available ultrasonic transducers cannot withstand high temperatures, such as above 200 .deg. C. It is therefore necessary to carry out manual measurements during plant shutdowns. The current method thus reveals several disadvantages: inspection have to be performed during shutdowns with the possible consequences of prolonging down time and increasing production losses, insulation has to be removed and replaced for each manual measurement, and scaffolding has to be installed to inaccessible areas, resulting in considerable cost for interventions. It has been suggested that a structural health monitoring approach with permanently installed ultrasonic thickness gauges could have substantial benefits over current practices. The main reasons why conventional piezoelectric ultrasonic transducers cannot be used at high temperatures are that the piezo-ceramic becomes depolarized at temperature above the Curie temperature and because differential thermal expansion of the substrate, couplant, and piezoelectric materials cause failure. In this paper, a shear horizontal waveguide technique for wall thickness monitoring at high temperature is investigated. Two different designs for contact to strip waveguide are shown and the quality of output signal is compared and reviewed. After a success of acquiring high quality ultrasonic signal, experiment on the wall thickness monitoring at high temperature is planned

  5. Coal Field Fire Fighting - Practiced methods, strategies and tactics

    Science.gov (United States)

    Wündrich, T.; Korten, A. A.; Barth, U. H.

    2009-04-01

    achieved. For an effective and efficient fire fighting optimal tactics are requiered and can be divided into four fundamental tactics to control fire hazards: - Defense (digging away the coal, so that the coal can not begin to burn; or forming a barrier, so that the fire can not reach the not burning coal), - Rescue the coal (coal mining of a not burning seam), - Attack (active and direct cooling of burning seam), - Retreat (only monitoring till self-extinction of a burning seam). The last one is used when a fire exceeds the organizational and/or technical scope of a mission. In other words, "to control a coal fire" does not automatically and in all situations mean "to extinguish a coal fire". Best-practice tactics or a combination of them can be selected for control of a particular coal fire. For the extinguishing works different extinguishing agents are available. They can be applied by different application techniques and varying distinctive operating expenses. One application method may be the drilling of boreholes from the surface or covering the surface with low permeability soils. The mainly used extinction agents for coal field fire are as followed: Water (with or without additives), Slurry, Foaming mud/slurry, Inert gases, Dry chemicals and materials and Cryogenic agents. Because of its tremendous dimension and its complexity the worldwide challenge of coal fires is absolutely unique - it can only be solved with functional application methods, best fitting strategies and tactics, organisation and research as well as the dedication of the involved fire fighters, who work under extreme individual risks on the burning coal fields.

  6. Nuclear techniques for the on-line bulk analysis of carbon in coal-fired power stations.

    Science.gov (United States)

    Sowerby, B D

    2009-09-01

    Carbon trading schemes usually require large emitters of CO(2), such as coal-fired power stations, to monitor, report and be audited on their CO(2) emissions. The emission price provides a significant additional incentive for power stations to improve efficiency. In the present paper, previous work on the bulk determination of carbon in coal is reviewed and assessed. The most favourable method is that based on neutron inelastic scattering. The potential role of on-line carbon analysers in improving boiler efficiency and in carbon accounting is discussed.

  7. Effective pretreatment of coal for briquetting

    Energy Technology Data Exchange (ETDEWEB)

    Sunami, Y; Nishioka, K; Sugimoto, Y

    1980-01-01

    The pretreatment of coal for briquetting is considered in an attempt to improve the quality of the briquets produced. Crushing of coal to obtain a size distribution suitable for close packing was found to be effective in improving coking properties while drying of coal was found to be effective in increasing briquet density. (In Japanese)

  8. Effect of microwave radiation on coal flotation

    Energy Technology Data Exchange (ETDEWEB)

    Ozbayoglu, G.; Depci, T.; Ataman, N. [Middle East Technical University, Ankara (Turkey). Mining Engineering Department

    2009-07-01

    Most low-rank coals are high in moisture and acid functional groups, therefore showing poor floatability. Drying, which removes the water molecules trapped in the pores and adsorbed at the surface of coal, decreases the hydrophilic character and improves the floatability. Microwave heating, whose simplest application is drying, was applied at 0.9 kW power level for 60 sec exposure time in the experiments to decrease the moisture content of coal in order to enhance the hydrophobicity. The flotation tests of microwave-treated coal by using heptanol and octanol lead to a higher flotation yield and ash removal than original coal.

  9. Extrafibrillar collagen demineralization-based chelate-and-rinse technique bridges the gap between wet and dry dentin bonding.

    Science.gov (United States)

    Mai, Sui; Wei, Chin-Chuan; Gu, Li-Sha; Tian, Fu-Cong; Arola, Dwayne D; Chen, Ji-Hua; Jiao, Yang; Pashley, David H; Niu, Li-Na; Tay, Franklin R

    2017-07-15

    Limitations associated with wet-bonding led to the recent development of a selective demineralization strategy in which dentin was etched with a reduced concentration of phosphoric acid to create exclusive extrafibrillar demineralization of the collagen matrix. However, the use of acidic conditioners removes calcium via diffusion of very small hydronium ions into the intrafibrillar collagen water compartments. This defeats the purpose of limiting the conditioner to the extrafibrillar space to create a collagen matrix containing only intrafibrillar minerals to prevent collapse of the collagen matrix. The present work examined the use of polymeric chelators (the sodium salt of polyacrylic acid) of different molecular weights to selectively demineralize extrafibrillar dentin. These polymeric chelators exhibit different affinities for calcium ions (isothermal titration calorimetry), penetrated intrafibrillar dentin collagen to different extents based on their molecular sizes (modified size-exclusion chromatography), and preserve the dynamic mechanical properties of mineralized dentin more favorably compared with completely demineralized phosphoric acid-etched dentin (nanoscopical dynamic mechanical analysis). Scanning and transmission electron microscopy provided evidence for retention of intrafibrillar minerals in dentin surfaces conditioned with polymeric chelators. Microtensile bond strengths to wet-bonded and dry-bonded dentin conditioned with these polymeric chelators showed that the use of sodium salts of polyacrylic acid for chelating dentin prior to bonding did not result in significant decline in resin-dentin bond strength. Taken together, the findings led to the conclusion that a chelate-and-rinse conditioning technique based on extrafibrillar collagen demineralization bridges the gap between wet and dry dentin bonding. The chelate-and-rinse dental adhesive bonding concept differentiates from previous research in that it is based on the size

  10. Upgrading of brown coal by slurry-dewatering; Kattan no yuchu dassui ni yoru clean kotai nenryo no seizo

    Energy Technology Data Exchange (ETDEWEB)

    Okuma, O.; Shimizu, T.; Inoue, T.; Shigehisa, T.; Deguchi, T.; Katsushima, S. [Kobe Steel, Ltd., Kobe (Japan)

    1996-10-28

    This paper describes an outline of solid fuel production process from brown coal and the investigation results of its elemental techniques. Dried coal is produced by this process which consists of a dewatering of crushed brown coal in oil-based solvent, a solid and liquid separation of slurry, and a remained oil recovery by heating. This process is characterized by the higher thermal efficiency compared with usual drying and the restraint of spontaneous combustion of product coal. It was revealed that solid fuel with low moisture, low ash, low sulfur, and suppressed spontaneous combustion property can be produced from Australian brown coal through this process. From the comparison between kerosene and fuel oil A, it was confirmed that the oil content during dewatering was smaller and the oil recovery by heating was easier by using a solvent with lower boiling point. It was also confirmed that the spontaneous combustion property can be suppressed using small amount of asphalt by solving asphalt in the solvent and adsorbing asphalt on the surface of brown coal. From these results, low rank coals including brown coal, which are difficult to use, are expected to be used as clean coal with low ash and low sulfur through this process. 2 refs., 7 figs., 2 tabs.

  11. Comparative study of the performance of conventional and column flotation when treating coking coal fines

    Energy Technology Data Exchange (ETDEWEB)

    Jena, M.S.; Biswal, S.K.; Das, S.P.; Reddy, P.S.R. [Institute of Minerals and Materials Technology (CSIR), Bhubaneswar - 751 013 (India)

    2008-12-15

    Investigations were carried out on coking coal fines by conventional cell and column flotation techniques. The effects of different operating parameters were evaluated for both conventional and column flotation. The coal fines were collected from Bhojudih washery, India. These coal fines averaged 24.4% ash, 19.8% volatile matter and 53.8% fixed carbon on a dry basis. A commercial grade sodium silicate, light diesel oil and pine oil were used as depressant, collector and frother respectively. The flotation performance was compared with release analysis. The conventional flotation results indicated that a clean coal with 14.4% ash could be obtained at 78.0% yield with 88.4% combustible recovery. The ash of the clean coal could be further reduced to 10.1% at 72.0% yield with 85.6% combustible recovery by using column flotation. The column flotation results were close to those obtained by release analysis. (author)

  12. A RANDOMIZED TRIAL TO STUDY THE COMPARISON OF TRIGGER POINT DRY NEEDLING VERSUS KINESIO TAPING TECHNIQUE IN MYOFASCIAL PAIN SYNDROME DURING A 3-MONTH FOLLOW UP

    Directory of Open Access Journals (Sweden)

    Emrullah Hayta

    2016-10-01

    Full Text Available Background: Managemen of myofascial pain syndrome (MPS is a current research subject since there is a small number of randomized studies comparing different management techniques. Multiple studies attempted to assess various treatment options including trigger point dry needling and kinesiotaping. We compared the effects of trigger point dry needling and kinesiotaping in the management of myofascial pain syndome during a 3-month follow-up period. Methods: In this prospective randomized studyin MPS patients with upper trapezius muscle trigger points, the effects of dry needling (n=28 and kinesiotaping (n=27 was compared with regard to the visual analog scale (VAS, neck disability index (NDI, and Nottingham health profile (NHP scores measured at the weeks 0, 4, and 12. Results: Both dry needling and kinesiotaping comparably reduced VAS scores measured at the weeks 4 and 12 and their efficacies were more remarkable at the week 12 (p<0.05. These interventions significantly reduced the NDI and NHP score and their effects were also more remarkable at the week 12; however, dry needling was found more effective (p<0.05. Conclusion: Overall, in current clinical settings, during the management of MPS, pain can be reduced comparably by both dry needling and kinesiotaping; however, restriction in the range of motionin neck region and quality of life are more remarkably reduced by dry needling. Both dry needling and kinesiotaping can provide an increasing effectiveness up to 12 weeks.

  13. Proximate Analysis of Coal

    Science.gov (United States)

    Donahue, Craig J.; Rais, Elizabeth A.

    2009-01-01

    This lab experiment illustrates the use of thermogravimetric analysis (TGA) to perform proximate analysis on a series of coal samples of different rank. Peat and coke are also examined. A total of four exercises are described. These are dry exercises as students interpret previously recorded scans. The weight percent moisture, volatile matter,…

  14. Coal Corporation of Victoria annual report 1986

    Energy Technology Data Exchange (ETDEWEB)

    1986-01-01

    Information is presented on operations, strategic planning, brown coal production and finance. Divisional reports are presented for the following divisions of the Coal Corporation of Victoria: marketing, technical marketing and special projects, research and development, and corporate services. The activities of the technical marketing and special projects division are discussed under the following headings: the coal for industry programme, the Brown Coal Liquefaction (Victoria) Pty. Ltd. project, dried brown coal activities, and resource development planning and policy activities. The corporation is currently conducting research into the following areas: ion exchange materials, activated carbons, and horticultural and agricultural applications of brown coal.

  15. Reduction of SO{sub 2} Emissions in Coal Power Plants by means of Spray-Drying RESOX Research Project; Acondicionamiento de Gases de Combustion para la Reduccion de Emisiones de Particulas en Centrales Termicas de Carbon

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-01

    In this experimental study, two important matters concerning the spray-drying technology for the desulphurisation of combustion gases, from pulverized coal boilers, have been analyzed: (1) the behaviour of the spray-dryer absorber under different operating conditions and (2) the behaviour of an electrostatic precipitator that operates downstream form a spray-dryer. The results of this project are of great interest for evaluating the application of this semi-dry desulphurisation technology in existing power plants that already have electrostatic precipitators. Additionally, the conclusions drawn are useful for establishing the optimum design and operating conditions for an integrated SD-ESP flue gas treatment facility. More than 45 experimental tests have been conducted on a 10,000 Nm``3/h spray-drying desulphurisation pilot plant. The effects of SO{sub 2} and fly ash concentration, Ca/S ratio, approach to saturation temperature, density of the slurry and unit load changes on both spray dryer behaviour and treated flue gas properties have been analyzed. In two additional specific tests, the effect of injecting calcium chloride and of preparing the slurry with seawater has also been studied. The impact of spray-dryer desulphurization on the behaviour of the electrostatic precipitators ha been evaluated comparing experimental data (efficiency, emission level, electrical consumption) for the behaviour of the electrostatic precipitator, obtained in two different experimental conditions: with and without desulphurization. Additionally, the possibility of reducing the power consumption of the precipitator by means of intermittent energization has been analyzed. (Author)

  16. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

    1995-04-01

    Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

  17. State and performance of on-stream ash content determination in lignite and black coal using 2-energy transmission technique

    International Nuclear Information System (INIS)

    Thuemmel, H.W.; Koerner, G.; Leonhardt, J.

    1986-01-01

    The total r.m.s. ash error of the 2-energy transmission on-stream ash gauges KRAS-2 (CIIRR, GDR) and SIROASH (Australia) are 4 weight percentage for raw lignite and 0.5 weight percentage for black coal, respectively. A detailed error analysis shows that this difference is due to the high water content and to strong variations in the ash composition of raw lignite. Both gauges show essentially the same radiometric performance. (author)

  18. Research on and Design of a Self-Propelled Nozzle for the Tree-Type Drilling Technique in Underground Coal Mines

    Directory of Open Access Journals (Sweden)

    Yiyu Lu

    2015-12-01

    Full Text Available Due to the increasing depths of coal mines and the low permeability of some coal seams, conventional methods of gas drainage in underground mines are facing many problems. To improve gas extraction, a new technique using water jets to drill tree-type boreholes in coal seams is proposed. A self-propelled water-jet drilling nozzle was designed to drill these boreholes. The configuration of the self-propelled nozzle was optimized by conducting drilling experiments and self-propelling force measurements. Experimental results show that the optimal self-propelled nozzle has a forward orifice axial angle at 25°, a radial angle at 90°, a center distance of 1.5 mm, and backward pointing orifices with an axial angle of 25°. The self-propelling force generated by the jets of the nozzle with 30 MPa pump pressure can reach 29.8 N, enough to pull the hose and the nozzle forward without any external forces. The nozzle can drill at speeds up to 41.5 m/h with pump pressures at 30 MPa. The radial angles of the forward orifices improve the rock breaking performance of the nozzle and, with the correct angle, the rock breaking area of the orifices overlap to produce a connecting hole. The diameter of boreholes drilled by this nozzle can reach 35.2 mm. The nozzle design can be used as the basis for designing other self-propelled nozzles. The drilling experiments demonstrate the feasibility of using the tree-type drilling technique in underground mines.

  19. Surface chemical problems in coal flotation

    Science.gov (United States)

    Taylor, S. R.; Miller, K. J.; Deurbrouck, A. W.

    1981-02-01

    As the use of coal increases and more fine material is produced by mining and processing, the need for improved methods of coal beneficiation increases. While flotation techniques can help meet these needs, the technique is beset with many problems. These problems involve surface chemical and interfacial properties of the coal-mineral-water slurry systems used in coal flotation. The problems associated with coal flotation include non-selectivity, inefficient reagent utilization, and excessive variablity of results. These problems can be broadely classified as a lack of predictability. The present knowledge of coal flotation is not sufficient, in terms of surface chemical parameters, to allow prediction of the flotation response of a given coal. In this paper, some of the surface chemical properties of coal and coal minerals that need to be defined will be discussed in terms of the problems noted above and their impact on coal cleaning.

  20. Coal-92

    International Nuclear Information System (INIS)

    Hillring, B.; Sparre, C.

    1992-11-01

    Swedish consumption of coal and coke during 1991 and trends in technology, environment and market aspects of coal use are reported. Steam coal use in the heating sector was unchanged from 1991, 1.2 Mtons. Reduced consumption in smaller district heating units (due to conversion to biofuels and gas) was compensated by increased use for power generation in cogeneration plants. Coal consumption in industry fell 0.10 Mton to 0.84 Mton due to lower production in one industry branch. Import of steam coal was 1.1 Mton (down 0.5 Mton from 1990) since new rules for strategic reserves allowed a reduction of stocks. During the last five years stocks have been reduced by 2 Mtons. Import of metallurgical coal was 1.6 Mton, unchanged from 1990. The report also gives statistics for the coal using plants in Sweden, on coal R and D, and on emission laws for coal firing. (9 tabs., 2 figs.)

  1. Development and Application of Blast Casting Technique in Large-Scale Surface Mines: A Case Study of Heidaigou Surface Coal Mine in China

    Directory of Open Access Journals (Sweden)

    Li Ma

    2016-01-01

    Full Text Available Blast casting is a high-efficiency technique applied in surface mines for overburden removal and results in stripping cost savings. According to ballistic theory and center-of-mass frame basic movement principles, key factors influencing blast casting effect were analyzed, which include bench height and mining panel width, inclined angle of blast holes, explosive unit consumption (EUC, delay-time interval, presplitting, and blast hole pattern parameters. An intelligent design software was developed for obtaining better breaking and casting effect, and the error rates predicted with actual result can be controlled with 10%. Blast casting technique was successfully applied in Heidaigou Surface Coal Mine (HSCM with more than 34% of material casted into the inner dump. A ramp ditch was set within the middle inner dump for coal transportation. The procedure of stripping and excavating was implemented separately and alternately in the two sections around the middle ramp ditch. An unconstrained-nonlinear model was deduced for optimizing the shift distance of the middle ramp. The calculation results show that optimum shift distance of HSCM is 480 m, and the middle ditch should be shifted after 6 blast casting mining panels being stripped.

  2. Oesophageal fistula/tritium-labelled water technique for determining dry matter intake and saliva secretion rates of grazing herbivores

    International Nuclear Information System (INIS)

    Luick, J.R.

    1982-01-01

    Seven assumptions on which the use of tritium-labelled water and oesophageal fistula depend, for determining the dry matter intake and saliva secretion rates of grazing herbivores, were tested experimentally. It is concluded that many of the possible sources of error can be ignored, but that a correction is necessary for the saliva dry matter content when calculating the dry matter of ingested food from fistula samples. (author)

  3. Low-temperature, low-loss zero level packaging techniques for RF applications by using a photopatternable dry film

    International Nuclear Information System (INIS)

    Kim, J; Seok, S; Rolland, N; Rolland, P-A

    2012-01-01

    This paper presents a low-temperature zero-level packaging technique using a dry film type of PerMX polymer for RF devices. Silicon cap packaging with PerMX sealing ring and PerMX cap packaging through multilayer lamination have been implemented. All of the fabrication process has been performed at temperature less than 150 °C. The influence of each packaging cap on the packaged coplanar waveguide was first investigated using the HFSS electromagnetic simulation. The RF measurement results showed that both packaging caps did not have significant influence on the performance of transmission lines. The insertion loss changes before and after packaging were almost negligible up to 30 GHz, and the return losses were better than 20 dB. Also, the deformation of PerMX structures concerning the packaging processes has been studied. For silicon capping, the volumetric compression of PerMX sealing ring by the bonding process has been observed. For PerMX cap packaging, the deflection of the polymer cap has been investigated as a function of sealing ring width for the different cap size. Measured results had good agreement with the ANSYS simulated ones. (paper)

  4. Analysis of coal by neutron activation

    International Nuclear Information System (INIS)

    Burtner, D.R.

    1983-01-01

    The development of a thermal-neutron activation analysis procedure for determining elemental concentrations in whole coal samples, and the goal of combining this technique with other nuclear methods for determining a total mass balance in these and similar complex materials, is described. Problems of applying a fast-neutron activation analysis method for nitrogen are discussed, as well as an efficient procedure for drying and packaging coal samples. A thermal-neutron activation analysis (TNAA) procedure was developed for determining up to 27 elements in coal samples from the US, China, Nigeria, and Brazil. The comparator form of TNAA was applied, using a unique multielement standard, which contained 48 elements. The difference in net photopeak counts between sample and standard, due to γ-ray attenuation, was reduced by preparing this standard in an organic matrix, which simulates the composition and physical structure of the coal material. The simultaneous irradiation of several aliquots of this standard enabled high precision and accuracy to be attained. An accurate value for oxygen, determined by fast-neutron activation analysis, is used to correct for this effect in the nitrogen determination method

  5. Evidence for network formation during the carbonization of coal from the combination of rheometry and {sup 1}H NMR techniques

    Energy Technology Data Exchange (ETDEWEB)

    Karen M. Steel; Miguel C. Diaz; John W. Patrick; Colin E. Snape [University of Nottingham, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

    2006-09-15

    High-temperature rheometry and {sup 1}H NMR have been combined to assess the microstructural changes taking place during carbonization of a number of different coals. A linear relationship exists between the logarithm of the material's complex viscosity ({eta}{sup {asterisk}}) and the fraction of hydrogen present in rigid structures ({phi}{sub rh}) for the resolidification region in which the material is liquid-like with small amounts of dispersed solid. The relationship is best characterized by the Arrhenius viscosity equation given by {eta}{sup {asterisk}} = {eta}{sub 0}{sup {asterisk}} exp(({eta}){phi}{sub rh}) where {eta}{sub 0}{sup {asterisk}} is the complex viscosity of the liquid medium and {eta} is the intrinsic viscosity of the resolidified material. Attempts to fit the Krieger-Dougherty suspension equation showed that the solid regions formed do not pack together like a normal suspension. Instead, it is more likely that cross-linking and cyclization reactions within the liquid medium give rise to a network structure of solid material and a characteristic gel point. The ratio of hydrogen present in rigid structures to that still present in liquid form at the gel point is approximately 2:3. The resolidified material was found to have a higher {eta} than the components of the coal that remained unsoftened, which suggests that while the unsoftened components have a fairly equant shape, the resolidified components have a much higher hydrodynamic volume. The resolidification process bears similarity with thermosetting polymer networks and the measurements taken for a blend of two coals follow a common two-component polymer blending rule. 35 refs., 13 figs., 4 tabs.

  6. Coal and coke applied to metallurgy. Vol. 2. Carvao e coque aplicados a metalurgia

    Energy Technology Data Exchange (ETDEWEB)

    Masuda, H.

    1983-01-01

    Papers include: coking; control of pollution from coking plants; handling and storage of coal; preparation of coal for coking; politics of the supply of coal; coke for blast furnaces; selective preparation and briquetting of coal for coking; cooling and drying of coke; preheating of coal for coking; formed coke.

  7. Coal 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    ACR's Coal 1992, the successor to the ACR Coal Marketing Manual, contains a comprehensive set of data on many aspects of the Australian coal industry for several years leading up to 1992. Tables and text give details of coal production and consumption in New South Wales, Queensland and other states. Statistics of the Australian export industry are complemented by those of South Africa, USA, New Zealand, Canada, Indonesia, China, Colombia, Poland and ex-USSR. Also listed are prices of Australian coking and non-coking coal, Australian coal stocks (and those of other major countries), loading port capacities, freight rates and coal quality requirements (analysis of coals by brand and supplier). A listing of Australian coal exporting companies is provided. A description of the spot Coal Screen Dealing System is given. World hard coal imports are listed by country and coal imports by major Asian countries tabulated. A forecast of demand by coal type and country up to the year 2000 is included.

  8. The new deal of coal

    International Nuclear Information System (INIS)

    Kalaydjian, F.; Cornot-Gandolphe, S.

    2008-01-01

    While coal appears as an inescapable resource to answer the energy needs of the 21. century, its highly CO 2 emitting combustion represents a major risk with respect to the requirements of the fight against climate change. In the first part of this book, the basic aspects of energy markets are explained and in particular the role that coal is going to play in the world's energy supplies. In the second part, the new coal usages are presented, which, combined with CO 2 capture and sequestration techniques, should allow to conciliate a massive use of coal and the respect of environmental constraints. This book is based on the works presented in February 2008 by the French institute of petroleum (IFP) about the new outlets of coal and the risks for climate change. Content: 1 - coal, energy of the 21. century: abundant and well distributed reserves; growing up world production; exponential world demand; international trade: still limited but in full expansion; 2 - Technologies for a CO 2 -free coal: CO 2 capture and sequestration technologies; towards poly-generation; production of coal-derived liquid fuels; 3 - Appendices: coals formation; coal in China: status and perspectives; coal in the USA: status and perspectives; coal in India: status and perspectives; COACH: an ambitious European project; CBM - E-CBM, status and perspectives. (J.S.)

  9. Development of a dual-tracer real-time particle dry-deposition measurement technique for simple and complex terrain

    International Nuclear Information System (INIS)

    Sehmel, G.A.; Hodgson, W.H.; Campbell, J.A.

    1979-01-01

    Detectors are being developed and tested for measuring the airborne concentrations of lithium particles and SF 6 gas in real time. The airborne lithium detector will be used for real-time measurements of both particle dry-deposition velocities and resuspension rates. Both the lithium and SF 6 detectors will be used for measuring dry deposition in field experiments

  10. Improvement of Physico-mechanical Properties of Partially Amorphous Acetaminophen Developed from Hydroalcoholic Solution Using Spray Drying Technique

    Science.gov (United States)

    Sadeghi, Fatemeh; Torab, Mansour; Khattab, Mostafa; Homayouni, Alireza; Afrasiabi Garekani, Hadi

    2013-01-01

    Objective(s): This study was performed aiming to investigate the effect of particle engineering via spray drying of hydroalcoholic solution on solid states and physico-mechanical properties of acetaminophen. Materials and Methods: Spray drying of hydroalcoholic solution (25% v/v ethanol/water) of acetaminophen (5% w/v) in the presence of small amounts of polyninylpyrrolidone K30 (PVP) (0, 1.25, 2.5 and 5% w/w based on acetaminophen weight) was carried out. The properties of spray dried particles namely morphology, surface characteristics, particle size, crystallinity, dissolution rate and compactibility were evaluated. Results: Spray drying process significantly changed the morphology of acetaminophen crystals from acicular (rod shape) to spherical microparticle. Differential scanning calorimetery (DSC) and x-ray powder diffraction (XRPD) studies ruled out any polymorphism in spray dried samples, however, a major reduction in crystallinity up to 65%, especially for those containing 5% w/w PVP was observed. Spray dried acetaminophen particles especially those obtained in the presence of PVP exhibited an obvious improvement of the dissolution and compaction properties. Tablets produced from spray dried samples exhibited excellent crushing strengths and no tendency to cap. Conclusions: The findings of this study revealed that spray drying of acetaminophen from hydroalcoholic solution in the presence of small amount of PVP produced partially amorphous particles with improved dissolution and excellent compaction properties. PMID:24379968

  11. Innovative clean coal technology: 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Final report, Phases 1 - 3B

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-01-01

    This report presents the results of a U.S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project was conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The technologies demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NOx burner. The primary objective of the demonstration at Hammond Unit 4 was to determine the long-term effects of commercially available wall-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology were also performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications was established for the project. Short-term and long-term baseline testing was conducted in an {open_quotes}as-found{close_quotes} condition from November 1989 through March 1990. Following retrofit of the AOFA system during a four-week outage in spring 1990, the AOFA configuration was tested from August 1990 through March 1991. The FWEC CF/SF low NOx burners were then installed during a seven-week outage starting on March 8, 1991 and continuing to May 5, 1991. Following optimization of the LNBs and ancillary combustion equipment by FWEC personnel, LNB testing commenced during July 1991 and continued until January 1992. Testing in the LNB+AOFA configuration was completed during August 1993. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NOx burners and advanced overfire systems.

  12. Practical use of dry desulfurization equipment using coal ash and effective use of used desulfurizer. Sekitanbai riyo kanshiki datsuryu sochi no jitsuyoka to shiyozumi datsuryuzai no yukoriyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, T.; Ueno, T. (The Hokkaido Electric Power CO. Inc., Hokkaido (Japan))

    1992-01-30

    Practical use of dry desulfurization equipment using coal ash installed in Atsuma power plant no.1 is explained. Outline of dry desulferization process is consisted of basic principles and structure of the process which includes desulfurizer production equipment and absorption equipment. When compared with conventional wet process, equipments for waste water and for reheating of exhaust gas are not necessary, and operation maintenance has been more convenient with the simplification of the system and absorber has graded up the elimination function. Advantages of simplification of treatment of used desulfurizer, and absorption of sulfurdioxide by desulfurizer together with characteristics of desulfurizer production are given. As far as practical macineries are concerned, outline of instrument facilities, construction technology and results of experimental operation are reported. Effective Use of desulfurizer using deodorant and hedro treatment has been verified from ammonium absorption experiment and practical investigation results. However use of hedro material has required, conformity of surface caking technology, under water caking technology, under water covering technology and effect on under water living environment. 13 figs., 4 tabs.

  13. Steam coal processing technology: handling, high-order processing, COM, meth-coal

    Energy Technology Data Exchange (ETDEWEB)

    Kamata, H.; Onodera, J.

    1982-01-01

    Topics covered include: various handling techologies (overland and marine transport, storage, water removal, drying, comminution and sizing); various coal processing technologies (gravity concentration, magnetic separation, multi-stage flotation, liquid-phase pelletizing, chemical processing); production methods for coal-oil mixtures (COM), their physical properties, stability, storage, transport, advantages, plus recent trends in research and development; production of coal-methanol slurry (meth-coal), its stability, storage, transport, utilization and environmental problems, plus latest trends in research and development. (In Japanese)

  14. FY 1980 Report on results of Sunshine Project by Coal Group. Basic researches on coal liquefaction techniques by solvolysis; 1980 nendo sunshine keikaku sekitanhan hokokusho. Sekitan no solvolysis ekika gijutsu no kiso kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-07-01

    The basic experimental researches were carried out for coal liquefaction by solvolysis. The studied items include hydrogenation conditions for treating the primary liquefied products, asphalt, pitch and model solvents (e.g., anthracene oil) in the presence of a commercial catalyst, solvolysis conditions for finely divided, molten coal using a hydrogenation recycled solvent, hydrotreating solvents, analysis of solvolysis-liquefied products, and liquefaction capacity of fractionated solvents for finely divided, molten coal. The studied items for separation of minerals include settlement at high temperature of the solid residue from the first liquefaction stage, and changed coal particle size distribution as a result of the first-stage liquefaction reactions in the presence of a hydrogenation solvent. The experimental study results indicate that conversion of finely divided molten coal into asphaltenes and preasphaltenes is notably accelerated in the phase-II coal liquefaction process by solvolysis, when a hydrotreating solvent is used for the first stage solvolysis process. (NEDO)

  15. Demonstration of advanced combustion NO(sub X) control techniques for a wall-fired boiler. Project performance summary, Clean Coal Technology Demonstration Program

    International Nuclear Information System (INIS)

    None

    2001-01-01

    The project represents a landmark assessment of the potential of low-NO(sub x) burners, advanced overtire air, and neural-network control systems to reduce NO(sub x) emissions within the bounds of acceptable dry-bottom, wall-fired boiler performance. Such boilers were targeted under the Clean Air Act Amendments of 1990 (CAAA). Testing provided valuable input to the Environmental Protection Agency ruling issued in March 1994, which set NO(sub x) emission limits for ''Group 1'' wall-fired boilers at 0.5 lb/10(sup 6) Btu to be met by January 1996. The resultant comprehensive database served to assist utilities in effectively implementing CAAA compliance. The project is part of the U.S. Department of Energy's Clean Coal Technology Demonstration Program established to address energy and environmental concerns related to coal use. Five nationally competed solicitations sought cost-shared partnerships with industry to accelerate commercialization of the most advanced coal-based power generation and pollution control technologies. The Program, valued at over$5 billion, has leveraged federal funding twofold through the resultant partnerships encompassing utilities, technology developers, state governments, and research organizations. This project was one of 16 selected in May 1988 from 55 proposals submitted in response to the Program's second solicitation. Southern Company Services, Inc. (SCS) conducted a comprehensive evaluation of the effects of Foster Wheeler Energy Corporation's (FWEC) advanced overfire air (AOFA), low-NO(sub x) burners (LNB), and LNB/AOFA on wall-fired boiler NO(sub x) emissions and other combustion parameters. SCS also evaluated the effectiveness of an advanced on-line optimization system, the Generic NO(sub x) Control Intelligent System (GNOCIS). Over a six-year period, SCS carried out testing at Georgia Power Company's 500-MWe Plant Hammond Unit 4 in Coosa, Georgia. Tests proceeded in a logical sequence using rigorous statistical analyses to

  16. Coal pump

    Science.gov (United States)

    Bonin, John H.; Meyer, John W.; Daniel, Jr., Arnold D.

    1983-01-01

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  17. Fast-neutron and gamma-ray transmission technique for the on-line determination of moisture in coal and coke

    International Nuclear Information System (INIS)

    Sowerby, B.D.; Millen, M.J.; Rafter, P.T.

    1988-01-01

    A fast neutron and γ-ray transmission technique is being developed for the on-line analysis of moisture. Calculations show that the technique is capable of determining coke moisture to better than 0.2 wt% over a wide range of coke thicknesses. The favoured technique uses a thick Li-glass detector surrounded by a neutron moderator to determine simultaneously the fast neutron and γ-ray intensities. Laboratory measurements on single coke samples showed that moisture can be determined to within 0.2 wt% over the range 3-13 wt% moisture and 300-500 mm thickness. Measurements on a range of coke samples showed that the increase in r.m.s. error due to bound H variations is less than about 0.4 wt% moisture. Applications of the technique, to moisture determination in black and brown coal are also investigated, both by calculation and experiment. Further potential applications of the technique are discussed, including the determination of C in steel. (author)

  18. The influence of microwave-assisted drying techniques on the rehydration behavior of blueberries (Vaccinium corymbosum L.).

    Science.gov (United States)

    Zielinska, Magdalena; Markowski, Marek

    2016-04-01

    The aim of this study was to determine the effect of: (a) different drying methods, (b) hot air temperature in a convection oven, and (c) the moisture content of fruits dehydrated by multi-stage drying which involves a transition between different stages of drying, on the rehydration kinetics of dry blueberries. Models describing rehydration kinetics were also studied. Blueberries dehydrated by multi-stage microwave-assisted drying, which involved a hot air pre-drying step at 80 °C until the achievement of a moisture content of 1.95 kg H2O kg(-1)DM, were characterized by significantly higher rates of initial and successive rehydration as well as smaller initial loss of soluble solids in comparison with the samples dried by other methods. The highest initial rehydration rate and the smallest loss of soluble solids after 30 min of soaking were determined at 0.46 min(-1) and 0.29 kg DM kg(-1)DM, respectively. The Peleg model and the first-order-kinetic model fit the experimental data well. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. Identification of the compositional changes in Orthosiphon stamineus leaves triggered by different drying techniques using 1 H NMR metabolomics.

    Science.gov (United States)

    Pariyani, Raghunath; Ismail, Intan Safinar; Ahmad Azam, Amalina; Abas, Faridah; Shaari, Khozirah

    2017-09-01

    Java tea is a well-known herbal infusion prepared from the leaves of Orthosiphon stamineus (OS). The biological properties of tea are in direct correlation with the primary and secondary metabolite composition, which in turn largely depends on the choice of drying method. Herein, the impact of three commonly used drying methods, i.e. shade, microwave and freeze drying, on the metabolite composition and antioxidant activity of OS leaves was investigated using proton nuclear magnetic resonance ( 1 H NMR) spectroscopy combined with multivariate classification and regression analysis tools. A total of 31 constituents comprising primary and secondary metabolites belonging to the chemical classes of fatty acids, amino acids, sugars, terpenoids and phenolic compounds were identified. Shade-dried leaves were identified to possess the highest concentrations of bioactive secondary metabolites such as chlorogenic acid, caffeic acid, luteolin, orthosiphol and apigenin, followed by microwave-dried samples. Freeze-dried leaves had higher concentrations of choline, amino acids leucine, alanine and glutamine and sugars such as fructose and α-glucose, but contained the lowest levels of secondary metabolites. Metabolite profiling coupled with multivariate analysis identified shade drying as the best method to prepare OS leaves as Java tea or to include in traditional medicine preparation. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  20. Fabrication and evaluation of pH-modulated solid dispersion for telmisartan by spray-drying technique.

    Science.gov (United States)

    Marasini, Nirmal; Tran, Tuan Hiep; Poudel, Bijay Kumar; Cho, Hyuk Jun; Choi, Young Keun; Chi, Sang-Cheol; Choi, Han-Gon; Yong, Chul Soon; Kim, Jong Oh

    2013-01-30

    The present study was undertaken to overcome the problems associated with solubility, dissolution and oral bioavailability of a poorly water-soluble ionizable drug, telmisartan (TMS). For these purposes, a solubility test was carried to select the appropriate formulation composition from various carriers and alkalizers. Solid dispersions (SDs) of TMS were prepared at different drug-to-carrier ratios by the spray-drying technique, and were characterized by dissolution and aqueous solubility studies. The optimum formulation was investigated by dissolution studies at different pH and water media and its solid state characterisations were performed by scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and X-ray diffraction (XRD) studies. In solubility and dissolution tests, all TMS-loaded pH-modulated SDs (pH(M)-SDs) exhibited marked improvement in the dissolution behavior when compared with crystalline TMS powder. The optimum formulation of pH(M)-SD consisted of TMS/PVP (polyvinylpyrrolidone) K30/Na(2)CO(3) at a weight ratio of 2/0.5/3 and showed significant improvement in the aqueous solubility and dissolution rate by approximately 40,000- and 3-fold, respectively, compared to TMS powder. Solid-state characterization revealed the changed in crystallinity of TMS into amorphous state. Furthermore, area under the drug concentration time-curve (AUC) of TMS from the pH(M)-SD increased by 13.4- and 2.1-fold, compared with TMS powder and commercial product, respectively. According to these observations, taken together with dissolution and pharmacokinetic behaviors, pH-modulated SD in the presence of an alkalizer for a poorly water-soluble ionizable drug, TMS, appeared to be efficacious for enhancing its bioavailability. Copyright © 2012 Elsevier B.V. All rights reserved.

  1. Application of x-ray diffraction techniques to the understanding of the dry sliding wear behaviour of aluminium and titanium

    International Nuclear Information System (INIS)

    Zoheir, N.; Ahmet, T.A.; Northwood, D.O.

    1996-01-01

    Dry sliding wear tests were performed on polycrystalline f.c.c. Al and h.c.p. Ti specimens using a block-on-ring type wear machine with a rotating ring made of 52100 bearing steel. The sliding speed was 0.13 m.s sup -l and the applied normal load was 10 N. The wear tests were performed on a single specimen in ambient conditions and the texture was evaluated during wear using an X-ray diffraction inverse pole figure technique at a range of sliding distances. Pole density distributions for the [0001] and [111) poles for of Ti and Al, respectively, were then determined from the inverse pole figures. The texture evolution during sliding wear was subsequently related to the friction and wear behaviour. For the aluminum sample, a (111) texture developed parallel to the worn surface with increasing sliding distance (a 6 fold increase in the (111) pole density as the sliding distance increases from 0 to 2714 m). The titanium sample (normal section) which had a preferred orientation with the basal poles, [0001), parallel to the contact surface prior to testing, an increase in wear, i.e. sliding distance, did not change the texture. However, for the transverse section of titanium, the basal pole, [0001), density parallel to the worn surface increased with increasing sliding distance. The shape of the coefficient of friction versus sliding distance curve is strongly influenced by crystallographic texturing. A drop in the coefficient of friction with the progressive development of the [111) and [0001) texture was observed for both Al and Ti (transverse section) specimens, respectively

  2. Simulation techniques of medium or small sized coal mining; Sistema de simulacion de labores de minas subterraneas de carbon de tamano mediano o pequeno

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-01

    Usually an underground mining company designs new production systems in order to reach higher productivity levels, but there is always some uncertainty about reaching the planned figures. This research project, so called Project SimCAR, applies to medium or small sized coal mining companies and tries to become a powerful tool in helping technical staff to answer questions about how future systems will behave. The project`s paradigm is to use computer simulation techniques in order to diminish the implicit uncertainty associated to coal mining activities. As a result, this implies to obtain the best possible scenarios for real economic investments in mine planning. The final programs we have built help technical staff to: 1. Study existing systems in depth. The precision of the resulting model exclusively depends on the correctness of input data and a perfect understanding of the system`s logic processes. 2. Perform several changes on the input system variables over the simulated models in order to allow the technical staff to know the system will react under several conditions. 3. Introduce new strategies on the model construction in order to get a complete optimization under productive and economic viewpoints. (Author)

  3. Non-destructive analysis of sensory traits of dry-cured loins by MRI-computer vision techniques and data mining.

    Science.gov (United States)

    Caballero, Daniel; Antequera, Teresa; Caro, Andrés; Ávila, María Del Mar; G Rodríguez, Pablo; Perez-Palacios, Trinidad

    2017-07-01

    Magnetic resonance imaging (MRI) combined with computer vision techniques have been proposed as an alternative or complementary technique to determine the quality parameters of food in a non-destructive way. The aim of this work was to analyze the sensory attributes of dry-cured loins using this technique. For that, different MRI acquisition sequences (spin echo, gradient echo and turbo 3D), algorithms for MRI analysis (GLCM, NGLDM, GLRLM and GLCM-NGLDM-GLRLM) and predictive data mining techniques (multiple linear regression and isotonic regression) were tested. The correlation coefficient (R) and mean absolute error (MAE) were used to validate the prediction results. The combination of spin echo, GLCM and isotonic regression produced the most accurate results. In addition, the MRI data from dry-cured loins seems to be more suitable than the data from fresh loins. The application of predictive data mining techniques on computational texture features from the MRI data of loins enables the determination of the sensory traits of dry-cured loins in a non-destructive way. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

  4. The impact of drying techniques on phenolic compound, total phenolic content and antioxidant capacity of oat flour tarhana.

    Science.gov (United States)

    Değirmencioğlu, Nurcan; Gürbüz, Ozan; Herken, Emine Nur; Yıldız, Aysun Yurdunuseven

    2016-03-01

    In this study, the changes in phenolic composition, total phenolic content, and antioxidant capacity of tarhanas supplemented with oat flour (OF) at the levels of 20-100% (w/w) after three drying treatments (sun-, oven-, and microwave drying) were investigated. A total of seventeen phenolic standards have been screened in tarhanas, and the most abundant flavonol and phenolic acid compounds were kaempferol (23.62mg/g) and 3-hydroxy-4-metoxy cinnamic acid (9.60mg/g). The total phenolic content amount gradually increased with the addition of OF to tarhana, but decidedly higher total phenolic content was found in samples oven dried at 55°C as compared with other methods. The microwave- and oven dried tarhana samples showed higher TEACDPPH and TEACABTS values than those dried with the other methods, respectively, in higher OF amounts. Consequently, oven- and microwave-drying can be recommended to retain the highest for phenolic compounds as well as maximal antioxidant capacity in OF supplemented tarhana samples. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. Washability characteristics of residual coals obtained from solvent extraction: studies towards developing cleaner coal technology

    Energy Technology Data Exchange (ETDEWEB)

    Giri, C.C.; Sharma, D.K. [Indian Institute of Technology, New Delhi (India). Centre for Energy Studies

    2004-07-01

    The washability characteristics of original Indian coals and solvent-extracted residual coals were studied by the float and sink technique. The following conclusions were drawn on the basis of the present study. Anthracene oil-extracted residual coals have lower percentage of reactions in the specific gravity range of 1.4 to 1.6 than the original coals, which indicates that the mineral matter is disassociated from the organic mass, and the anthracene oil-extracted residual coal is more suitable for washing than the original coal. The floatability behaviour of coal increases during NMP (N-methyl-2-pyrrolidone) extraction. This indicates that coal changes its washability character during NMP extractions. As during NMP extraction the surface area of coal increases by creating fissures in the matrix, the chemical leaching technique would be more suitable to remove the mineral matter in the residual coals. 12 refs., 3 figs., 2 tabs.

  6. Use of moist run-of-mine coal for gasification

    Energy Technology Data Exchange (ETDEWEB)

    Sowka, K.; Duerlich, M.; Rabe, W. (VEB Gaskombinat Fritz Selbmann, Schwarze Pumpe (German Democratic Republic))

    1988-01-01

    A Series of experiments was performed in 1982 and 1986 to assess the feasibility of substituting brown coal briquets by raw brown coal in the fixed bed gasification plant for producing town gas at Schwarze Pumpe, GDR. Raw brown coal (50% coal moisture, screened coal of fractions 20 to 80 mm) had to be mixed with dry briquets to maintain a maximum 35% coal charge moisture. Briquet substitution degree varied from 20 to 50%. Short-term gasification tests were also carried out at an experimental generator examining 80 to 100% substitution degrees. Parameters of generator operation that were achieved are provided. Experiments proved that 50% briquet substitution is technologically feasible in industrial plant operation employing unscreened coal containing all coal fines. An economic assessment is further made that shows substantial energy savings in coal drying and briquetting.

  7. Fiscal 1995 achievement report. Development of entrained bed coal gasification power plant (Part 1 - Studies of key elements and techniques); 1995 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 1. Youso kenkyu hen, gijutsu chosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Element techniques were studied and surveyed for establishing the technology of integrated coal gasification combined cycle. In fiscal 1995, E coal (coal of high ash fluid point) gasification was tested in the 2 tons/day furnace for the effect of its properties on furnace operation and for its properties relating to gasification and slagging and for changes in such properties due to flux admixed with the E coal. It was then found that the ash fluid point was so high as 1500 degrees C and that flux admixing, recovered oxygen reinjection, etc., would be necessary for the assurance of stable slag discharge. In a study using combined cycle system simulation, a comparison was made between results from tests conducted on a real system and results from the simulation, based on the detailed model completed by the preceding fiscal year. The model was reviewed and improved, and simulations were conducted in the respective operating states and operating modes. In the survey of element techniques, information was gathered at a Japan-U.S. joint technical conference held in Japan in October this year. Studies were also made about technical guidelines, or the like, involving coal gasification power generation. (NEDO)

  8. Coal surface control for advanced physical fine coal cleaning technologies

    Energy Technology Data Exchange (ETDEWEB)

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-01-01

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO[sub 2] emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  9. Process for treating moisture laden coal fines

    Science.gov (United States)

    Davis, Burl E.; Henry, Raymond M.; Trivett, Gordon S.; Albaugh, Edgar W.

    1993-01-01

    A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

  10. Lab-scale investigation of Middle-Bosnia coals to achieve high-efficient and clean combustion technology

    Directory of Open Access Journals (Sweden)

    Smajevic Izet

    2014-01-01

    Full Text Available This paper describes full lab-scale investigation of Middle-Bosnia coals launched to support selection an appropriate combustion technology and to support optimization of the boiler design. Tested mix of Middle-Bosnia brown coals is projected coal for new co-generation power plant Kakanj Unit 8 (300-450 MWe, EP B&H electricity utility. The basic coal blend consisting of the coals Kakanj: Breza: Zenica at approximate mass ratio of 70:20:10 is low grade brown coal with very high percentage of ash - over 40%. Testing that coal in circulated fluidized bed combustion technique, performed at Ruhr-University Bohum and Doosan Lentjes GmbH, has shown its inconveniency for fluidized bed combustion technology, primarily due to the agglomeration problems. Tests of these coals in PFC (pulverized fuel combustion technology have been performed in referent laboratory at Faculty of Mechanical Engineering of Sarajevo University, on a lab-scale PFC furnace, to provide reliable data for further analysis. The PFC tests results are fitted well with previously obtained results of the burning similar Bosnian coal blends in the PFC dry bottom furnace technique. Combination of the coals shares, the process temperature and the air combustion distribution for the lowest NOx and SO2 emissions was found in this work, provided that combustion efficiency and CO emissions are within very strict criteria, considering specific settlement of lab-scale furnace. Sustainability assessment based on calculation economic and environmental indicators, in combination with Low Cost Planning method, is used for optimization the power plant design. The results of the full lab-scale investigation will help in selection optimal Boiler design, to achieve sustainable energy system with high-efficient and clean combustion technology applied for given coals.

  11. PHBV/PLLA-based composite scaffolds fabricated using an emulsion freezing/freeze-drying technique for bone tissue engineering: surface modification and in vitro biological evaluation

    International Nuclear Information System (INIS)

    Sultana, Naznin; Wang Min

    2012-01-01

    Tissue engineering combines living cells with biodegradable materials and/or bioactive components. Composite scaffolds containing biodegradable polymers and nanosized osteoconductive bioceramic with suitable properties are promising for bone tissue regeneration. In this paper, based on blending two biodegradable and biocompatible polymers, namely poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) and poly(l-lactic acid) (PLLA) with incorporated nano hydroxyapatite (HA), three-dimensional composite scaffolds with controlled microstructures and an interconnected porous structure, together with high porosity, were fabricated using an emulsion freezing/freeze-drying technique. The influence of various parameters involved in the emulsion freezing/freeze-drying technique was studied for the fabrication of good-quality polymer scaffolds based on PHBV polymers. The morphology, mechanical properties and crystallinity of PHBV/PLLA and HA in PHBV/PLLA composite scaffolds and PHBV polymer scaffolds were studied. The scaffolds were coated with collagen in order to improve wettability. During in vitro biological evaluation study, it was observed that SaOS-2 cells had high attachment on collagen-coated scaffolds. Significant improvement in cell proliferation and alkaline phosphatase activity for HA-incorporated composite scaffolds was observed due to the incorporation of HA. After 3 and 7 days of culture on all scaffolds, SaOS-2 cells also had normal morphology and growth. These results indicated that PHBV/PLLA-based scaffolds fabricated via an emulsion freezing/freeze-drying technique were favorable sites for osteoblastic cells and are promising for the applications of bone tissue engineering.

  12. Australian coal

    Energy Technology Data Exchange (ETDEWEB)

    1985-11-01

    Total export shipments of coal in Australia in the year ending June 30 1985 reached a record of 83.8 Mt. The export trade is expected to bring in an income of 4 billion Australian dollars in the current year making coal Australia's biggest revenue-earning export commodity. This article presents a brief overview of the Australian coal industry with production and export statistics and information on major open pit and underground mines.

  13. Enhanced oral bioavailability of novel mucoadhesive pellets containing valsartan prepared by a dry powder-coating technique

    DEFF Research Database (Denmark)

    Cao, Qing-Ri; Liu, Yan; Xu, Wei-Juan

    2012-01-01

    The aim of this study was to develop novel mucoadhesive pellets containing valsartan (VAL) with enhanced oral bioavailability. Two types of VAL loaded core pellets were prepared by an extrusion/spheronization method, and further dry-coated with a mixture of hydroxypropylmethylcellulose (HPMC...

  14. Venezuelan coal

    International Nuclear Information System (INIS)

    Vazquez, L.U.

    1991-01-01

    The existence of coal deposits in Venezuela has been known since the early nineteenth century, when the Naricual Mines were discovered in the State of Anzoategui Eastern Venezuela. Through the years the Venezuelan coal business had its ups and downs, but it was not until 1988 that we could properly say that our coal began to play a role in the international market. This paper reports that it is only now, in the nineties, that Venezuelan coal projects have come under a planning, promotional and developmental policy preparing the ground for the great projects Venezuela will have in the not-too-distant future

  15. Assessment of two techniques for drying of easily degradable organic bio-waste; Bedoemning av tvaa tekniker foer torkning av laett nedbrytbart organiskt matavfall

    Energy Technology Data Exchange (ETDEWEB)

    Raaholt, Birgitta; Bergstroem, Birgitta; Broberg, Agneta; Holtz, Emma; Nordberg, Ulf; Del Pilar Castillo, Maria; Baky, Andras

    2011-10-15

    In 2010, all food waste from the Swedish food industry would, according to national environmental goals, be recycled through biological treatment. For food waste from households and food establishments, the corresponding goal is at least 35%. The project aims to explore the potential for reducing costs and energy consumption, as well as decreasing the environmental impact, by decreasing the moisture content of food waste. Dried food waste has a long shelf-life and can be used as a bio fuel substrate together with other material of low dry matter content. It is expected to increase the bio fuel potential by improved possibilities to control the organic load. The storage costs are also reduced, as is the collecting frequency. Additionally, collecting can be done from a larger number of collecting points at the same occasion. Furthermore, the collection vehicle does not need to be equipped with collecting trays for silage effluent from the food waste. Since dried food waste can be stored for a longer period, this results in more optimal use of the energy of the food waste. The dried material requires neither decomposition nor sieving, has a very high purity degree (>99%), and does not result in reject material at treatment. The nutritional content of the dried material was also in principle intact. Composting of food waste from households was performed as a practical reference, in laboratory scale. The results show that rehydrated dried food waste works as good as a conventional compost fraction. However, the material has a tendency to dry out faster than conventional compost. Further rehydration may therefore be needed during the process. In this project, an assessment was made of two possible techniques for drying readily biodegradable organic waste: microwave vacuum drying of waste from food establishments and air-drying of food waste from households. The techniques were compared individually with current systems for handling waste, with respect to quality of the

  16. Research of coal flash hydropyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Z.; Zhu, H.; Wu, Y.; Tang, L.; Cheng, L.; Xu, Z. [East China University of Science and Technology, Shanghai (China)

    2001-02-01

    Using x-ray photoelectron spectroscopy (XPS) analyses the organic sufur of seven different Chinese coals and their semi-cokes from flash hydropyrolysis were studied. The results showed that the organic sulfur in coal was alkyal sulfur and thiophene with the peak of XPS located in 163.1-163.5 eV and 164.1-164.5 eV. The relative thiophene content in coal increased with the coal rank. The type of organic sulfur in semi-coke in flash hydropyrolysis was generally thiophene species; its XPS peak also located in 164.1-164.5 eV, and was in accord with its corresponding coal. Total alkyl sulfur and some thiophene sulfur were removed during the flash hydropyrolysis process. The alkyl sulfur had very high activity in hydrogenation reaction. Flash hydropyrolysis was an important new clean-coal technique and had notable desulfurization effect. 13 refs., 2 figs., 4 tabs.

  17. Guidelines for leaching studies on coal fly ash and other solid wastes with special reference to the use of radioanalytical techniques

    International Nuclear Information System (INIS)

    1991-07-01

    Environmental pollution has many causes. One of the most important sources is that associated with the large quantities of solid wastes produced by modern industrial societies - materials such as coal fly ash, incinerator ash, sewage sludge and mine tailings. Not only do these give rise to physical problems of disposal - due to the enormous quantities involved - but also, in the long run, they may pose some serious environmental risks. Questions arise as to what will happen to them as a result of interacting with rain or groundwater. Will their toxic components eventually migrate out of waste depositories and contaminate the environment, including groundwater? Nuclear analytical techniques, such as neutron activation analysis, are not sufficient in themselves to provide a complete answer to the questions. Nevertheless, they have unique properties which enable them to determine many of the important bulk constituents of solid wastes and to explore how toxic and other trace elements can be removed from them by leaching with different kinds of water (e.g. rain water, groundwater and sea water). This report attempts to explore some of these issues and to offer guidance on how nuclear analytical techniques may be applied in a standardized way, thus helping to ensure that the results reported by different laboratories will be compatible and comparable with each other. 20 refs, 10 figs, 3 tabs

  18. Coal summit II

    Energy Technology Data Exchange (ETDEWEB)

    1983-01-01

    Various papers were presented on world coal trade. Papers include: Poland as a producer and exporter of coal; the dynamics of world coal trade; Cerrejon coal production perspectives; present state of the Australian coal industry; present state of the EC coal market and future prospects; prospects of US coal exports to Europe; forecast of Italian coal supply and demand through 1990; statistics from coal transportation outlook; status of world coal ports.

  19. Coal fires in Indonesia

    Energy Technology Data Exchange (ETDEWEB)

    Whitehouse, Alfred E.; Mulyana, Asep A.S. [Office of Surface Mining/Ministry of Energy and Mineral Resources Coal Fire Project, Ministry of Energy and Mineral Resources, Agency for Training and Education, Jl. Gatot Subroto, Kav. 49, Jakarta 12950 (Indonesia)

    2004-07-12

    Indonesia's fire and haze problem is increasingly being ascribed to large-scale forest conversion and land clearing activities making way for pulpwood, rubber and oil palm plantations. Fire is the cheapest tool available to small holders and plantation owners to reduce vegetation cover and prepare and fertilize extremely poor soils. Fires that escaped from agricultural burns have ravaged East Kalimantan forests on the island of Borneo during extreme drought periods in 1982-1983, 1987, 1991, 1994 and 1997-1998. Estimates based on satellite data and ground observations are that more than five million hectares were burned in East Kalimantan during the 1997/1998 dry season. Not only were the economic losses and ecological damage from these surface fires enormous, they ignited coal seams exposed at the ground surface along their outcrops.Coal fires now threaten Indonesia's shrinking ecological resources in Kutai National Park and Sungai Wain Nature Reserve. Sungai Wain has one of the last areas of unburned primary rainforest in the Balikpapan-Samarinda area with an extremely rich biodiversity. Although fires in 1997/1998 damaged nearly 50% of this Reserve and ignited 76 coal fires, it remains the most valuable water catchment area in the region and it has been used as a reintroduction site for the endangered orangutan. The Office of Surface Mining provided Indonesia with the capability to take quick action on coal fires that presented threats to public health and safety, infrastructure or the environment. The US Department of State's Southeast Asia Environmental Protection Initiative through the US Agency for International Development funded the project. Technical assistance and training transferred skills in coal fire management through the Ministry of Energy and Mineral Resource's Training Agency to the regional offices; giving the regions the long-term capability to manage coal fires. Funding was also included to extinguish coal fires as

  20. Effects of wheat dried distillers' grains with solubles and cinnamaldehyde on in vitro fermentation and protein degradation using the Rusitec technique.

    Science.gov (United States)

    Lia, Yangling; He, Maolong; Li, Chun; Forster, Robert; Beauchemin, Karen Anne; Yang, Wenzhu

    2012-04-01

    This study was conducted to evaluate the effect of wheat dried distillers' grains with solubles (DDGS) and cinnamaldehyde (CIN) on in vitro fermentation and microbial profiles using the rumen simulation technique. The control substrate (10% barley silage, 85% barley grain and 5% supplement, on dry matter basis) and the wheat DDGS substrate (30% wheat DDGS replaced an equal portion of barley grain) were combined with 0 and 300 mg CIN/l of culture fluid. The inclusion of DDGS increased (p fermentation pattern changed to greater acetate and less propionate proportions (p fermentability and potentially increase protein flows to the intestine. Supplementation of high-grain substrates with CIN reduced methane production and potentially increased the true protein reaching the small intestine; however, overall reduction of feed fermentation may lower the feeding value of a high-grain diet.

  1. Improved L-cysteine electrocatalysis through a sequential drop dry technique using multi-walled carbon nanotubes and cobalt tetraaminophthalocyanine conjugates

    International Nuclear Information System (INIS)

    Nyoni, Stephen; Mugadza, Tawanda; Nyokong, Tebello

    2014-01-01

    Graphical abstract: A sequential drop dry modification of a glassy carbon electrode where by multiwalled carbon nanotubes are first placed on to the electrode followed by cobalt tetraaminophthalocyanine gave a better catalytic response towards the oxidation of L-cysteine than when the two components were mixed, due to the higher catalytic activity of the former as judged by scanning electrochemical microscopy. - Highlights: • A glassy carbon electrode modified with multi-walled carbon nanotubes and cobalt tetraaminophthalocyanine by a sequential drop dry method. • The modified surface gave a better catalytic response towards the oxidation of L-cysteine than when the individual components were mixed. • Scanning electrochemical microscopy was employed for surface characterization. - Abstract: Voltammetry, chronoamperometry, scanning electrochemical microscopy and electrochemical impedance spectroscopy methods are used for characterization of a glassy carbon electrode modified with multi-walled carbon nanotubes (MWCNTs)–cobalt tetraaminophthalocyanine (CoTAPc) mixture or sequential drop dry modification technique whereby the MWCNTs are first placed on to the electrode followed by CoTAPc. The sequential drop dry CoTAPc–MWCNTs modified surface gave better catalytic responses with a catalytic rate constant of 2.2 × 10 5 M −1 s −1 , apparent electron transfer rate constant of 0.073 cm s −1 , and a limit of detection of 2.8 × 10 −7 M. Scanning electrochemical microscopy (SECM) surface characterization (topography and reactivity) further gave proof the better catalytic perfomance of the sequential drop dry CoTAPc–MWCNTs modified surface

  2. International Coal Report's coal year 1991

    Energy Technology Data Exchange (ETDEWEB)

    McCloskey, G [ed.

    1991-05-31

    Following introductory articles on factors affecting trade in coal and developments in the freight market, tables are given for coal exports and coal imports for major countries worldwide for 1989 and 1990. Figures are also included for coal consumption in Canada and the Eastern bloc,, power station consumption in Japan, coal supply and demand in the UK, electric utility coal consumption and stocks in the USA, coal production in Australia, Canada and USA by state, and world hard coal production. A final section gives electricity production and hard coal deliveries in the EEC, sales of imported and local coal and world production of pig iron and steel.

  3. Identification of bovine material in porcine spray-dried blood derivatives using the Polymerase Chain Reaction technique

    Directory of Open Access Journals (Sweden)

    Sánchez A.

    2004-01-01

    Full Text Available Due to the widely supported theory of bovine spongiform encephalopathy (BSE spread in cattle by contaminated animal feeds, screening of feed products has become essential. For many years, manufacturers have used blood and plasma proteins as high quality ingredients of foods for both pets and farm animals. However, in Europe, the Commission Regulation 1234/2003/EC temporally bans the use of processed animal proteins, including blood-derivative products, in feedstuffs for all farm animals which are fattened or bred for the production of food. This regulation has some exceptions, such as the use of non ruminant blood products into the feed of farm fish. Authorization of the re-introduction of these proteins into animal feed formulations, especially non ruminant proteins into the feed for non ruminant farm animals, is expected when adequate control methods to discriminate ruminant proteins exist. Currently, the number of validated methods to differentiate the species of origin for most of the animal by-products is limited. Here we report the development of a rapid and sensitive polymerase chain reaction (PCR-based assay, which allows detection of bovine or porcine specific mitochondrial DNAfrom spray-dried blood derivate products (plasma, whole blood and red cells, as a marker for bovine contamination in porcine products. Sample extracts, suitable for PCR, were easily and quickly obtained with the commercial PrepManTM Ultra reagent (Applied Biosystems. To confirm the porcine origin of the samples, primers targeting a specific region of 134 bp of the porcine cytochrome b coding sequence were designed (cytbporc1-F and cytbporc2-R. Previously published PCR primers (L8129 and H8357, specific for a 271 bp fragment of the bovine mitochondrial ATPase 8-ATPase 6 genes, were chosen to accomplish amplification of bovine DNA. The limit of detection (LOD of the bovine PCR assay was at least of 0.05% (v/v of bovine inclusion in spray-dried porcine plasma or red

  4. Sahara Coal: the fine art of collecting fines for profit

    Energy Technology Data Exchange (ETDEWEB)

    Schreckengost, D.; Arnold, D.

    1984-09-01

    A considerable increase in the volume of fines in rom coal caused Sahara Coal in Illinois to redesign the fine coal system in their Harrisburg preparation plant. Details of the new design, and particularly the fine refuse system which dewaters and dries 28 mesh x O clean coal, are given. Results have exceeded expectations in reducing product losses, operating costs and slurry pond cleaning costs.

  5. Characterization and supply of coal based fuels

    Energy Technology Data Exchange (ETDEWEB)

    1992-06-01

    Studies and data applicable for fuel markets and coal resource assessments were reviewed and evaluated to provide both guidelines and specifications for premium quality coal-based fuels. The fuels supplied under this contract were provided for testing of advanced combustors being developed under Pittsburgh Energy Technology Center (PETC) sponsorship for use in the residential, commercial and light industrial (RCLI) market sectors. The requirements of the combustor development contractors were surveyed and periodically updated to satisfy the evolving needs based on design and test experience. Available coals were screened and candidate coals were selected for further detailed characterization and preparation for delivery. A team of participants was assembled to provide fuels in both coal-water fuel (CWF) and dry ultrafine coal (DUC) forms. Information about major US coal fields was correlated with market needs analysis. Coal fields with major reserves of low sulfur coal that could be potentially amenable to premium coal-based fuels specifications were identified. The fuels requirements were focused in terms of market, equipment and resource constraints. With this basis, the coals selected for developmental testing satisfy the most stringent fuel requirements and utilize available current deep-cleaning capabilities.

  6. Physical, physicochemical and nutritional characteristics of Bhoja chaul, a traditional ready-to-eat dry heat parboiled rice product processed by an improvised soaking technique.

    Science.gov (United States)

    Dutta, Himjyoti; Mahanta, Charu Lata; Singh, Vasudeva; Das, Barnali Baruah; Rahman, Narzu

    2016-01-15

    Bhoja chaul is a traditional whole rice product processed by the dry heat parboiling technique of low amylose/waxy paddy that is eaten after soaking in water and requires no cooking. The essential steps in Bhoja chaul making are soaking paddy in water, roasting with sand, drying and milling. In this study, the product was prepared from a low amylose variety and a waxy rice variety by an improvised laboratory scale technique. Bhoja chaul prepared in the laboratory by this technique was studied for physical, physicochemical, and textural properties. Improvised method shortened the processing time and gave a product with good textural characteristics. Shape of the rice kernels became bolder on processing. RVA studies and DSC endotherms suggested molecular damage and amylose-lipid complex formation by the linear B-chains of amylopectin, respectively. X-ray diffractography indicated formation of partial B-type pattern. Shifting of the crystalline region of the XRD curve towards lower values of Bragg's angle was attributed to the overall increase in inter-planar spacing of the crystalline lamellae. Resistant starch was negligible. Bhoja chaul may be useful for children and people with poor state of digestibility. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Converting coal

    Energy Technology Data Exchange (ETDEWEB)

    Avigliano, A. [Bedeschi (Italy)

    2006-10-15

    In September 2005, Bedeschi was commissioned to design and supply a coal unloading, conveying and storage facility for a new raw coal line system within Hatien II Cement Co. The new plant is composed of a grab unloader, a conveyor system, a storage shed with stacking and reclaiming facilities, a complete dedusting system and civil and steel structure engineering. The scope of supply includes a local fabrication portion; however, main components will be imported. The project will be completed in 21 months. The paper looks into the mechanics of loading and unloading coal. 4 figs., 4 photos.

  8. Bulk analysis of coal

    International Nuclear Information System (INIS)

    Sowerby, B.D.

    1982-01-01

    Nuclear techniques used in the coal industry to determine specific energy, ash and moisture are outlined. Ash analysis by radioisotope X-ray techniques include a single X-ray measurement using a transmission or backscatter geometry and techniques with compensation for iron variations. Neutron techniques can be used to measure the concentration of some specific elements in coal. The measurement of specific energy, ash and moisture then depends on the correlation of the particular parameter with the measured elemental composition. Carbon can be determined by a combination of a measurement of 4.43 MeV 12 C gamma-rays from neutron inelastic scattering with a separate 60 Co gamma-ray scattering measurement. Sulphur meters are based on the measurement of 5.42 MeV neutron capture of gamma rays

  9. Material balance in coal. 2. Oxygen determination and stoichiometry of 33 coals

    International Nuclear Information System (INIS)

    Volborth, A.; Miller, G.E.; Garner, C.K.; Jerabek, P.A.

    1977-01-01

    The chemical analysis of coal can be supplemented by the determination of oxygen in high and low temperature ash, in coal as received and in coal dried at 105 0 C. The rapid method utilizes fast-neutron activation. The reaction 16 O(n,p) 16 N and counting of the 6.1 and 7.1 MeV gammas of 7.3 second half-life are used. A specially designed dual transfer and simultaneous counting system gives very accurate results. Oxygen in 33 coals ranging from lignite to low volatile bituminous coal is determined and compared with ''oxygen by difference.'' Considerable discrepancies are observed. Better stoichiometric results are obtained if oxygen in coal ash, in wet coal and in the dried coal is determined. This permits the estimation of the true material balances using data of the ultimate and the proximate coal analysis. The oxygen determination provides the coal chemist with an accurate basis and can be used to rank coal. The summation of the percent of carbon, nitrogen, hydrogen, sulfur, and oxygen becomes more meaningful and some errors can be detected and the state of completeness of coal analysis thus evaluated. Total sulfur can be estimated and oxidation effects during drying can be detected. These affect the moisture determination. It appears that after more data are collected, the interpretation of solid fuel analyses may be facilitated and will be stoichiometrically more meaningful. It is shown that it may be possible to simplify the present time-consuming methods of coal analysis

  10. Spray Drying as a Processing Technique for Syndiotactic Polystyrene to Powder Form for Part Manufacturing Through Selective Laser Sintering

    Science.gov (United States)

    Mys, N.; Verberckmoes, A.; Cardon, L.

    2017-03-01

    Selective laser sintering (SLS) is a rapidly expanding field of the three-dimensional printing concept. One stumbling block in the evolution of the technique is the limited range of materials available for processing with SLS making the application window small. This article aims at identifying syndiotactic polystyrene (sPS) as a promising material. sPS pellets were processed into powder form with a lab-scale spray dryer with vibrating nozzle. This technique is the focus of this scope as it almost eliminates the agglomeration phenomenon often encountered with the use of solution-based processing techniques. Microspheres obtained were characterized in shape and size by scanning electron microscopy and evaluation of the particle size distribution. The effect the processing technique imparts on the intrinsic properties of the material was examined by differential scanning calorimetry analysis.

  11. The spectrographic analysis of plutonium oxide or mixed plutonium oxide/uranium oxide fuel pellets by the dried residue technique

    International Nuclear Information System (INIS)

    Jarbo, G.J.; Faught, P.; Hildebrandt, B.

    1980-05-01

    An emission spectrographic method for the quantitative determination of metallic impurities in plutonium oxide and mixed plutonium oxide/uranium oxide is described. The fuel is dissolved in nitric acid and the plutonium and/or uranium extracted with tributyl phosphate. A small aliquot of the aqueous residue is dried on a 'mini' pyrolitic graphite plate and excited by high voltage AC spark in an oxygen atmosphere. Spectra are recorded in a region which has been specially selected to record simultaneously lines of boron and cadmium in the 2nd order and all the other elements of interest in the 1st order. Indium is used as an internal standard. The excitation of very small quantities of the uraniumm/plutonium free residue by high voltage spark, together with three separate levels of containment reduce the hazards to personnel and the environment to a minimum with limited effect on sensitivity and accuracy of the results. (auth)

  12. Directly observing catalytic intermediates of methane dry reforming (MDR) on model Ni(111) catalyst via in operando surface techniques

    Science.gov (United States)

    Yuan, Kaidi

    In this work, near ambient pressure x-ray photoelectron spectroscopy was used to trace the in operando catalytic intermediates of methane dry reforming on model Ni(111) catalyst. The following reactive carbon intermediates have been characterized from dissociation of CH4: *CH, *C1 (Ni3C), *Cn (n≥2) and clock-reconstructed Ni2C. They can develop into inert graphene, and the conditions for this transition have been explored. One the other hand, the oxygen intermediates from CO2 dissociation were also studied, which play an important role on restraining graphene growth. Their dynamic coverage decreases with increasing temperature, which is suggested the fundamental mechanism of regional carbon overspill and causes irreversible graphene formation. Therefore, solutions based on Ni-O stabilization were proposed in developing coking resisting catalysts.

  13. Coal competitiveness?

    International Nuclear Information System (INIS)

    Rogeaux, B.

    2006-01-01

    Will coal electrical plants be more competitive in the coming years? Answering this one cannot be limited to merely comparing estimates based on reference electricity production costs. The competitiveness of coal will indeed depend on the final product marketed, as the MWhs are not equal: is the purpose to produce base, half-base MWh? Does the electrical equipment structure require flexible MWh (for instance in the event of significant intermittent renewable energy amounts), and therefore plants able to adjust their power rapidly? But the competitiveness of coal will also depend on many factors that will correct reference cost estimates: uncertainties, risks, externalities. These factors will need to be appreciated on a case by case basis. We introduce some of the reasoning used to better appreciate the future competitiveness of coal, and the main factors conditioning it in three contrasting regions of the world: Europe, USA, china. (author)

  14. A newer concept of setting up coal refineries in coal utilising industries through environmentally sound clean coal technology of organosuper refining of coals

    International Nuclear Information System (INIS)

    Sharma, D.K.

    1994-01-01

    In order to reduce the losses of premium organic matter of coal and its immense potential energy which is present in the form of stronger interatomic and intramolecular bonding energies, a newer and convenient technique of recovering the premium organic matter from low grade coals by organosuper-refining technique which operates under ambient pressure conditions has been developed. The residual coal obtained can be used as environmentally clean fuel or as a feedstock for the industries based on carbonization and gasification. It is suggested that a beginning be made by setting up coal refineries in coal utilizing industries on the basis of the presently developed new technology of organosuper-refining of coals to recover premium grade organic chemical feed stocks from coals before utilizing coal by techniques such as bubble bed or recirculatory fluidized bed or pulverized coal combustion in thermal power stations, carbonization in steel plants or other carbonization units, gasification in fertilizer industries or in integrated coal gasification combined cycle power generation. Thus, coal refineries may produce value added aromatic chemical feed stocks, formed coke or coke manufacturing; and carbon fillers for polymers. (author). 100 refs., 1 fig

  15. Fiscal 1996 achievement report. Development of entrained bed coal gasification power plant (Part 1 - Studies of dismantling and surveys of techniques); 1995 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 1. Kaitai kenkyu hen, gijutsu chosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-01-01

    For the establishment of technology of integrated coal gasification combined cycle, studies were made for the dismantling of the 200 tons/day entrained bed coal gasification pilot plant and surveys were conducted of overseas technologies. In the gasification furnace facility, 40 devices were selected, and dismantled, from the locations corresponding to the factors of damage expected to occur involving important equipment. Although no significant damage was detected in the gasification pressure vessel, peripheral walls, or the like, malfunctions due to corrosion or abrasion were discovered in some pipes and members. In the dry type gas clean-up facility (desulfurization facility), damage due to heat stress or corrosion was detected in the regeneration tower inner cyclone, regeneration tower filter flexible tubes, and in circulation gas cooler cooling tubes. In the dry type gas clean-up facility (dedusting facility), damage was found in the dust collector gas seal valve, dust collector filter materials cut valve, and in the separator A/B. In the gas turbine facility, no abnormality was discovered but for some damage in some initial stage static vanes. (NEDO)

  16. Coal: a revival for France?

    International Nuclear Information System (INIS)

    Brones, W.

    2007-01-01

    All energy consumption forecasts indicate a world production peak of fossil fuels around 2030 followed by a rapid decline. The oil peak should probably occur earlier. In this context the huge worldwide reserves of coal represent a fantastic opportunity to meet the world power demand which should double between 2002 and 2030 with in particular a huge growth in China and India. If promising alternate technologies (coal liquefaction..) exist which would allow to replace petroleum by coal, the main question remains the management of CO 2 . Capture and sequestration techniques are already implemented and tested and the search for new coal deposits is going on, in particular in France in the Nievre area. Economic studies about the profitability of coal exploitation in France stress on the socio-economical advantage that a revival of this activity would represent, in particular in terms of employment. (J.S.)

  17. THE EFFECT OF VARIOUS PARAMETERS ON DRY SLIDING WEAR BEHAVIOR AND SUBSURFACE OF AGED HYBRID METAL MATRIX COMPOSITES USING TAGUCHI TECHNIQUE

    Directory of Open Access Journals (Sweden)

    B.M. Viswanatha

    2017-06-01

    Full Text Available The effects of applied load, sliding speed and sliding distance on the dry sliding wear behavior of aged Al-SiCp-Gr composites were investigated. The specimen were fabricated by stir-casting technique. The pin-on-disc wear testing machine was used to investigate the wear rate by design of experiments based on L27 using Taguchi technique. Sliding distance was the most important variable that influenced the wear rate followed by sliding speed and applied load. The worn out surfaces were analyzed by SEM and EDS to study the subsurface mechanism of wear. The addition of reinforcements showed improved tribological behavior of the composite than base alloy.

  18. Comparison of the Effectiveness of Water-Based Extraction of Substances from Dry Tea Leaves with the Use of Magnetic Field Assisted Extraction Techniques

    Directory of Open Access Journals (Sweden)

    Grzegorz Zaguła

    2017-10-01

    Full Text Available This article presents the findings of a study investigating the feasibility of using a magnetic field assisted technique for the water-based extraction of mineral components, polyphenols, and caffeine from dry black and green tea leaves. The authors present a concept of applying constant and variable magnetic fields in the process of producing water-based infusions from selected types of tea. Analyses investigating the effectiveness of the proposed technique in comparison with conventional infusion methods assessed the contents of selected mineral components—i.e., Al, Ca, Cu, K, Mg, P, S, and Zn—which were examined with the use of ICP-OES. The contents of caffeine and polyphenolic compounds were assessed using the HPLC. A changing magnetic field permitted an increased effectiveness of extraction of the mineral components, caffeine, and polyphenols. The findings support the conclusion that a changing magnetic field assisted extraction method is useful for obtaining biologically valuable components from tea infusions.

  19. Hydrothermal pretreatment of coal

    Energy Technology Data Exchange (ETDEWEB)

    Ross, D.S.

    1989-12-21

    We have examined changes in Argonne Premium samples of Wyodak coal following 30 min treatment in liquid water at autogenous pressures at 150{degrees}, 250{degrees}, and 350{degrees}C. In most runs the coal was initially dried at 60{degrees}C/1 torr/20 hr. The changes were monitored by pyrolysis field ionization mass spectrometry (py-FIMS) operating at 2.5{degrees}C/min from ambient to 500{degrees}C. We recorded the volatility patterns of the coal tars evolved over that temperature range, and in all cases the tar yields were 25%--30% of the starting coal on mass basis. There was essentially no change after the 150{degrees}C treatment. Small increases in volatility were seen following the 250{degrees}C treatment, but major effects were seen in the 350{degrees} work. The tar quantity remained unchanged; however, the volatility increased so the temperature of half volatility for the as-received coal of 400{degrees}C was reduced to 340{degrees}C. Control runs with no water showed some thermal effect, but the net effect from the presence of liquid water was clearly evident. The composition was unchanged after the 150{degrees} and 250{degrees}C treatments, but the 350{degrees} treatment brought about a 30% loss of oxygen. The change corresponded to loss of the elements of water, although loss of OH'' seemed to fit the analysis data somewhat better. The water loss takes place both in the presence and in the absence of added water, but it is noteworthy that the loss in the hydrothermal runs occurs at p(H{sub 2}O) = 160 atm. We conclude that the process must involve the dehydration solely of chemically bound elements of water, the dehydration of catechol is a specific, likely candidate.

  20. Evaluation of three gas chromatography and two direct mass spectrometry techniques for aroma analysis of dried red bell peppers

    NARCIS (Netherlands)

    Ruth, van S.M.; Boscaini, E.; Mayr, D.; Pugh, J.; Posthumus, M.A.

    2003-01-01

    Three gas chromatography methods and two direct mass spectrometry techniques were compared for the analysis of the aroma of rehydrated diced red bell peppers. Gas chromatography methods included systems with olfactometry detection (GC-O), flame ionisation detection (GC-FID) and mass spectrometry

  1. Carbonizing etc. , coal etc

    Energy Technology Data Exchange (ETDEWEB)

    Duckham, A M; Rider, D; Watts, J S

    1924-01-17

    In drying, carbonizing, and distilling coal, shale, etc., by passage through a heated retort, the material is spread in a thin layer over the heating surface by a conveying-screw with a shallow thread. The retort is heated by a bath of molten metal, and the conveyingscrew intermeshes with a scraper screw of smaller diameter, and of a different hand; the screws are mounted on shafts geared together by wheels. The material after passing through the retort is delivered into a chute closed at the bottom by an arc-shaped water seal carried on arms and opened periodically by a lever.

  2. Studies on biosorption of Cr(VI) on a green resin: dry cow dung powder and tracer technique

    International Nuclear Information System (INIS)

    Barot, N.S.; Bagla, H.K.

    2012-01-01

    The present investigation entails the application of dry cow dung powder (DCP) as an indigenous, inexpensive and eco-friendly material for the removal of Cr(VI) from aqueous medium. Batch biosorption experiments were conducted employing 51 Cr(VI) as a tracer and the effect of various process parameters such as optimum pH, temperature, amount of resin, time of equilibration, agitation speed, concentration of metal ions and interfering effect of different salts etc. were studied. The kinetic studies were carried out employing various models but the best fitting was given by Lagergren Pseudo-second order model with high correlation coefficient R 2 value of 0.997 and adsorption capacity of 10.20 mg/g. The thermodynamic parameters for biosorption were evaluated as ΔG = -2.837 kJ/mol, ΔH = -4.757 kJ/mol and ΔS = 16.64 J/mol K, which indicated spontaneous and exothermic process with high affinity of DCP for Cr(VI). Many naturally available materials are used for the biosorption of heavy metal pollutants, where most of them are physically or chemically modified. In this research work, DCP has been utilized without any pre or post chemical treatment. Thus it manifests the principle of green chemistry and proves to be an eco-friendly resin. (orig.)

  3. Studies on biosorption of Cr(VI) on a green resin: dry cow dung powder and tracer technique

    Energy Technology Data Exchange (ETDEWEB)

    Barot, N.S.; Bagla, H.K. [Kishinchand Chellaram College, Mumbai (India). Nuclear and Radiochemistry Dept.

    2012-07-01

    The present investigation entails the application of dry cow dung powder (DCP) as an indigenous, inexpensive and eco-friendly material for the removal of Cr(VI) from aqueous medium. Batch biosorption experiments were conducted employing {sup 51}Cr(VI) as a tracer and the effect of various process parameters such as optimum pH, temperature, amount of resin, time of equilibration, agitation speed, concentration of metal ions and interfering effect of different salts etc. were studied. The kinetic studies were carried out employing various models but the best fitting was given by Lagergren Pseudo-second order model with high correlation coefficient R{sup 2} value of 0.997 and adsorption capacity of 10.20 mg/g. The thermodynamic parameters for biosorption were evaluated as {Delta}G = -2.837 kJ/mol, {Delta}H = -4.757 kJ/mol and {Delta}S = 16.64 J/mol K, which indicated spontaneous and exothermic process with high affinity of DCP for Cr(VI). Many naturally available materials are used for the biosorption of heavy metal pollutants, where most of them are physically or chemically modified. In this research work, DCP has been utilized without any pre or post chemical treatment. Thus it manifests the principle of green chemistry and proves to be an eco-friendly resin. (orig.)

  4. Effect of H/C ratio on coal ignition

    Energy Technology Data Exchange (ETDEWEB)

    Furimsky, E.

    1988-09-01

    The Cahn balance technique was found to be suitable for estimating ignition temperature and its dependence on the H/C ratio of the coal. This temperature decreased with increasing H/C ratio of coals. For coals a linear correlation between H/C ratio and the temperature was established. Chars derived from the coals deviated from the linear correlation established on coals. 17 refs., 4 figs.

  5. Method selection for mercury removal from hard coal

    Directory of Open Access Journals (Sweden)

    Dziok Tadeusz

    2017-01-01

    Full Text Available Mercury is commonly found in coal and the coal utilization processes constitute one of the main sources of mercury emission to the environment. This issue is particularly important for Poland, because the Polish energy production sector is based on brown and hard coal. The forecasts show that this trend in energy production will continue in the coming years. At the time of the emission limits introduction, methods of reducing the mercury emission will have to be implemented in Poland. Mercury emission can be reduced as a result of using coal with a relatively low mercury content. In the case of the absence of such coals, the methods of mercury removal from coal can be implemented. The currently used and developing methods include the coal cleaning process (both the coal washing and the dry deshaling as well as the thermal pretreatment of coal (mild pyrolysis. The effectiveness of these methods various for different coals, which is caused by the diversity of coal origin, various characteristics of coal and, especially, by the various modes of mercury occurrence in coal. It should be mentioned that the coal cleaning process allows for the removal of mercury occurring in mineral matter, mainly in pyrite. The thermal pretreatment of coal allows for the removal of mercury occurring in organic matter as well as in the inorganic constituents characterized by a low temperature of mercury release. In this paper, the guidelines for the selection of mercury removal method from hard coal were presented. The guidelines were developed taking into consideration: the effectiveness of mercury removal from coal in the process of coal cleaning and thermal pretreatment, the synergy effect resulting from the combination of these processes, the direction of coal utilization as well as the influence of these processes on coal properties.

  6. Coal 95

    International Nuclear Information System (INIS)

    Sparre, C.

    1995-01-01

    The report deals with the use of coal and coke in Sweden during 1994. Some information about technology, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from Statistics Sweden have also been used.The use of steam coal for heating purposes has been unchanged during 1994 at a level of 1 Mtons. The production in the cogeneration plants has been constant, but has increased for electricity production. The minor plants have increased their use of forest fuels. The use of steam coal will probably go down in the next years both for heat and cogeneration plants. During the top year 1987 coal was used in 18 hot water and 11 cogeneration plants. 1994 these figures are 3 and 12. Taxes and environmental reasons explain this trend. The use of steam coal in industry has been constant at the level 0.7 Mtons. The import of metallurgical coal in 1993 was 1.6 Mtons, like 1992. Import of 0.3 Mtons of coke gives the total consumption of coke in industry as 1.5 Mtons. the average price of steam coal imported to Sweden was 317 SEK/ton, 3% higher than 1993. All Swedish plants meet their emission limit of dust, SO 2 and NO x as given by county administrations or concession boards. The cogeneration plants all have some SO 2 removal system. The biggest cogeneration plant (Vaesteraas) has recently invested in a SCR NO x cleaning system. Most other plants use low NO x burners or SNR injection systems based on ammonia or urea. 2 figs, 13 tabs

  7. Application of fractal theory to top-coal caving

    International Nuclear Information System (INIS)

    Xie, H.; Zhou, H.W.

    2008-01-01

    The experiences of underground coal mining in China show that coal in a thick hard coal seam with a hard roof, the so-called 'double hard coal seam', is difficult to be excavated by top-coal caving technique. In order to solve the problem, a top-coal weakening technique is proposed in this paper. In the present study, fractal geometry provides a new description of the fracture mechanism for blasting. By means of theoretical analysis of the relationship between the fractal dimension of blasting fragments and the dynamite specific energy, a mechanical model for describing the size distribution of top-coal and the dissipation of blasting energy is proposed. The theoretical results are in agreement with laboratory and in situ test results. Moreover, it is shown that the fractal dimension of coal fragments can be used as an index for optimizing the blasting parameters for a top-coal weakening technique

  8. Coal gasification: A technology in the puberty. Kolenvergassing: Een technologie in de puberteit

    Energy Technology Data Exchange (ETDEWEB)

    Peppink, G. (Sep, Arnhem (Netherlands))

    1994-12-01

    Several aspects of present developments regarding coal gasification are briefly discussed. Attention is paid to the place of the coal gasification in the total electric power generation, its environmental impact, the recently available new coal techniques, coal gasification in the next ten years, cost comparisons, and developments at the coal gasification demonstration plant in Buggenum, Netherlands. 3 figs.

  9. Model documentation coal market module of the National Energy Modeling System

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    This report documents the approaches used in developing the Annual Energy Outlook 1995 (AEO95). This report catalogues and describes the assumptions, methodology, estimation techniques, and source code of the coal market module`s three submodules. These are the Coal Production Submodule (CPS), the Coal Export Submodule (CES), the Coal Expert Submodule (CES), and the Coal Distribution Submodule (CDS).

  10. Model documentation coal market module of the National Energy Modeling System

    International Nuclear Information System (INIS)

    1995-03-01

    This report documents the approaches used in developing the Annual Energy Outlook 1995 (AEO95). This report catalogues and describes the assumptions, methodology, estimation techniques, and source code of the coal market module's three submodules. These are the Coal Production Submodule (CPS), the Coal Export Submodule (CES), the Coal Expert Submodule (CES), and the Coal Distribution Submodule (CDS)

  11. Pelletization of fine coals. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Sastry, K.V.S.

    1995-12-31

    Coal is one of the most abundant energy resources in the US with nearly 800 million tons of it being mined annually. Process and environmental demands for low-ash, low-sulfur coals and economic constraints for high productivity are leading the coal industry to use such modern mining methods as longwall mining and such newer coal processing techniques as froth flotation, oil agglomeration, chemical cleaning and synthetic fuel production. All these processes are faced with one common problem area--fine coals. Dealing effectively with these fine coals during handling, storage, transportation, and/or processing continues to be a challenge facing the industry. Agglomeration by the unit operation of pelletization consists of tumbling moist fines in drums or discs. Past experimental work and limited commercial practice have shown that pelletization can alleviate the problems associated with fine coals. However, it was recognized that there exists a serious need for delineating the fundamental principles of fine coal pelletization. Accordingly, a research program has been carried involving four specific topics: (i) experimental investigation of coal pelletization kinetics, (ii) understanding the surface principles of coal pelletization, (iii) modeling of coal pelletization processes, and (iv) simulation of fine coal pelletization circuits. This report summarizes the major findings and provides relevant details of the research effort.

  12. Nanoencapsulation of water-soluble drug, lamivudine, using a double emulsion spray-drying technique for improving HIV treatment

    Energy Technology Data Exchange (ETDEWEB)

    Tshweu, Lesego, E-mail: tshweull@gmail.com [Council for Scientific and Industrial Research, Materials Science and Manufacturing, Polymers and Composites (South Africa); Katata, Lebogang [North West University, Chemistry Department, Faculty of Agriculture, Science and Technology (South Africa); Kalombo, Lonji; Swai, Hulda [Council for Scientific and Industrial Research, Materials Science and Manufacturing, Polymers and Composites (South Africa)

    2013-11-15

    Current treatments available for human immunodeficiency virus, namely antiretrovirals, do not completely eradicate the virus from the body, leading to life-time commitment. Many antiretrovirals suffer drawbacks from toxicity and unpleasant side effects, causing patience non-compliance. To minimize challenges associated with the antiretrovirals, biodegradable nanoparticles used as drug delivery systems hold tremendous potential to enhance patience compliance. The main objective of this work was to load lamivudine (LAM) into poly(epsilon-caprolactone) (PCL) nanoparticles. LAM is a hydrophilic drug with low plasma half-life of 5–7 h and several unpleasant side effects. LAM was nanoencapsulated into PCL polymer via the double emulsion spray-drying method. Formulation parameters such as the effect of solvent, excipient and drug concentration were optimized for the synthesis of the nanoparticles. Spherical nanoparticles with an average size of 215 ± 3 nm and polydispersity index (PDI) of 0.227 ± 0.01 were obtained, when ethyl acetate and lactose were used in the preparation. However, dichloromethane presented sizes larger than 454 ± 11 nm with PDI of more than 0.4 ± 0.05, irrespective of whether lactose or trehalose was used in the preparation. Some of the nanoparticles prepared with trehalose resulted in crystal formation. UV spectroscopy showed encapsulation efficiency ranging from 68 ± 4 to 78 ± 4 % for LAM depending on the starting drug concentration. Fourier transform infrared spectroscopy and X-ray diffraction confirmed the possibility of preparing amorphous PCL nanoparticles containing LAM. Drug release extended for 4 days in pH 1.3, pH 4.5 and pH 6.8. These results indicated that LAM-loaded PCL nanoparticles show promise for controlled delivery.

  13. Nanoencapsulation of water-soluble drug, lamivudine, using a double emulsion spray-drying technique for improving HIV treatment

    Science.gov (United States)

    Tshweu, Lesego; Katata, Lebogang; Kalombo, Lonji; Swai, Hulda

    2013-11-01

    Current treatments available for human immunodeficiency virus, namely antiretrovirals, do not completely eradicate the virus from the body, leading to life-time commitment. Many antiretrovirals suffer drawbacks from toxicity and unpleasant side effects, causing patience non-compliance. To minimize challenges associated with the antiretrovirals, biodegradable nanoparticles used as drug delivery systems hold tremendous potential to enhance patience compliance. The main objective of this work was to load lamivudine (LAM) into poly(epsilon-caprolactone) (PCL) nanoparticles. LAM is a hydrophilic drug with low plasma half-life of 5-7 h and several unpleasant side effects. LAM was nanoencapsulated into PCL polymer via the double emulsion spray-drying method. Formulation parameters such as the effect of solvent, excipient and drug concentration were optimized for the synthesis of the nanoparticles. Spherical nanoparticles with an average size of 215 ± 3 nm and polydispersity index (PDI) of 0.227 ± 0.01 were obtained, when ethyl acetate and lactose were used in the preparation. However, dichloromethane presented sizes larger than 454 ± 11 nm with PDI of more than 0.4 ± 0.05, irrespective of whether lactose or trehalose was used in the preparation. Some of the nanoparticles prepared with trehalose resulted in crystal formation. UV spectroscopy showed encapsulation efficiency ranging from 68 ± 4 to 78 ± 4 % for LAM depending on the starting drug concentration. Fourier transform infrared spectroscopy and X-ray diffraction confirmed the possibility of preparing amorphous PCL nanoparticles containing LAM. Drug release extended for 4 days in pH 1.3, pH 4.5 and pH 6.8. These results indicated that LAM-loaded PCL nanoparticles show promise for controlled delivery.

  14. The combined use of micro-hydropyrolysis and compound-specific isotope analysis (CSIA) as a novel technique to identify coal-derived biodegraded PAH flux in the complex environment

    Energy Technology Data Exchange (ETDEWEB)

    Cheng-Gong Sun; Gbolagade Olalere; Wisdom Ivwurie; Mick Cooper; Colin Snape [University of Nottingham, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre

    2007-07-01

    A novel analytical methodology combining CSIA and micro-hydropyrolysis (CSIA/micro-HyPy) has been developed to aid unambiguous source apportionment of PAHs in the complex environment where PAH matrices have been heavily biodegraded and/or their isotopic signatures are overlapping for some sources. Asphaltenes retain useful information of biogeochemical significance, which can be accessed via hydropyrolysis. The PAHs released from hydropyrolysis of asphaltenes, the bound PAHs, from different primary sources (e.g. crude oils, low and high temperature coal tars) were characterized and compared to free aromatics in regard to their molecular and 13C-isotopic profiles. It was found that hydropyrolysis of asphaltenes can generate molecular and isotopic profiles highly representative of their primary sources. For both low and high temperature coal tar, the bound aromatics have broadly similar molecular distributions to their free aromatic counterparts and have {sup 13}C-isotopic values almost identical to those of UK bituminous coals(-23{per_thousand}), indicating that the asphaltenes are actually released as representative fragments of coal structures during carbonization. As expected, the bound aromatics are more 13C-enriched by 1-3 {per_thousand} (-21 to -23{per_thousand}) compared to free aromatics (-24 to -26{per_thousand}). No significant isotopic difference was observed between free and bound aromatics for a North Sea crude oil, all having similar {sup 13}C-isotopic values (-27.2-30.2 {per_thousand}) that are significantly lighter than those for coal-derived aromatics. Applications of this novel methodological CSIA/micro-HyPy technique to samples previously examined from an area around a former carbonization plant have been successfully demonstrated where unambiguous source apportionment could not be achieved previously for the PAHs due to likely environmental alternation. 3 refs., 2 figs., 2 tabs.

  15. Dry Eye

    Science.gov (United States)

    ... Eye » Facts About Dry Eye Listen Facts About Dry Eye Fact Sheet Blurb The National Eye Institute (NEI) ... and their families search for general information about dry eye. An eye care professional who has examined the ...

  16. Fiscal 2000 project of inviting proposals for international joint research - invitation for international proposal (Power generation No.1). Achievement report on development of novel high-performance dry type desulfurization agent made from coal ash; 2000 nendo kokusai kyodo kenkyu teian kobo jigyo - kokusai teian kobo (hatsuden No.1). Sekitanbai wo genryo to suru shinki koseino kanshiki datsuryuzai no kaihatsu to riyo seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Efforts are made to develop a technology of using quicklime instead of slaked lime for a reduction in desulfurization cost, based on the technology of the coal ash utilizing dry type desulfurization device operating on coal ash, slaked lime, and gypsum, as hardened by hydration. Activities are conducted in the three fields of (1) basic study, (2) desulfurization agent bench-scale manufacturing test, and (3) study for putting the technology to practical application. In field (1), the basics are studied of the lime slaking process in the manufacture of a dry type desulfurization agent from quicklime, the mechanism is elucidated of the generation of active desulfurization substances, and effective utilization is studied of the desulfurization agent after use. In field (3), conceptual designs are prepared, cost efficiency of desulfurization systems are evaluated, simplified absorption systems are studied, and the trends of dry type desulfurization systems are surveyed. The cost of desulfurization under development is equivalent to that of the wet type method (limestone-gypsum system) when the used desulfurization agent is discarded, and is approximately 60% of the wet type method when the whole amount is effectively utilized. (NEDO)

  17. The application of the coal grain analysis method to coal liberation studies

    Energy Technology Data Exchange (ETDEWEB)

    O' Brien, G.; Firth, B.; Adair, B. [CSIRO Earth Science & Resource Engineering Brisbane, Qld. (Australia)

    2011-07-01

    Emerging coal markets such as the use of coal for conversion to liquid fuels and its use in fuels cells and as coal water slurries in diesel engines require coal products with different coal quality specifications than those applicable to traditional coal markets of coke making and conventional power generation. As well as quantifying coals in terms of their chemical and physical properties, detailed knowledge of the mineral inclusions within the coal particles is required to identify coals that are suited to economically produce the low-ash value coals required for these markets. After mining and processing, some particles can consist of essentially pure components of a single maceral or mineral phase whilst others are composite particles that are comprised of varying amounts of macerals and minerals. The proportion of particles that are present as pure components or as composites will be a function of the characteristics of the coal and the particle size. In general, it is considered that size reduction will result in liberation and hence increased yield. The amount of liberation that occurs during crushing or grinding a coal is however coal specific. Particle characterization information provided by an optical microscopic-imaging method, Coal Grain Analysis, was used to identify coals that might benefit from additional crushing to improve recovery of clean coal by new density separation techniques and by flotation. As expected, the results of these studies suggest that the degree of liberation that is obtained is coal specific, and, hence, yield improvements are also coal specific. Hence a quantitative method of investigating this issue is required.

  18. Distilling coal

    Energy Technology Data Exchange (ETDEWEB)

    Blythe, F C

    1914-09-14

    In the destructive distillation of bituminous coal, heavy hydrocarbon oil, such as petroleum, kerosine, shale oil, and heavy tar oil, obtained in some cases during the process, is added to the coal, which is then distilled under pressure and at a comparatively low temperature regulated so as to produce a large proportion of hydrocarbon oils and a small proportion of permanent gas. In one method, about 5 to 10 parts of hydrocarbon oil are mixed with 100 parts of crushed or ground coal, and the mixture is heated in a closed vessel, provided in some cases with an agitator, under a pressure of about 60 lb/in/sup 2/, and the temperature may be gradually raised to 350/sup 0/C and then to about 500/sup 0/C. The heating may be by means of superheated steam with or without external heat.

  19. Rosebud SynCoal Partnership, SynCoal{reg_sign} demonstration technology update

    Energy Technology Data Exchange (ETDEWEB)

    Sheldon, R.W. [Rosebud SynCoal Partnership, Billings, MT (United States)

    1997-12-31

    An Advanced Coal Conversion Process (ACCP) technology being demonstrated in eastern Montana (USA) at the heart of one of the world`s largest coal deposits is providing evidence that the molecular structure of low-rank coals can be altered successfully to produce a unique product for a variety of utility and industrial applications. The product is called SynCoal{reg_sign} and the process has been developed by the Rosebud SynCoal Partnership (RSCP) through the US Department of Energy`s multi-million dollar Clean Coal Technology Program. The ACCP demonstration process uses low-pressure, superheated gases to process coal in vibrating fluidized beds. Two vibratory fluidized processing stages are used to heat and convert the coal. This is followed by a water spray quench and a vibratory fluidized stage to cool the coal. Pneumatic separators remove the solid impurities from the dried coal. There are three major steps to the SynCoal{reg_sign} process: (1) thermal treatment of the coal in an inert atmosphere, (2) inert gas cooling of the hot coal, and (3) removal of ash minerals. When operated continuously, the demonstration plant produces over 1,000 tons per day (up to 300,000 tons per year) of SynCoal{reg_sign} with a 2% moisture content, approximately 11,800b Btu/lb and less than 1.0 pound of SO{sub 2} per million Btu. This product is obtained from Rosebud Mine sub-bituminous coal which starts with 25% moisture, 8,600 Btu/lb and approximately 1.6 pounds of SO{sub 2} per million Btu.

  20. Sustained release vancomycin-coated titanium alloy using a novel electrostatic dry powder coating technique may be a potential strategy to reduce implant-related infection.

    Science.gov (United States)

    Han, Jing; Yang, Yi; Lu, Junren; Wang, Chenzhong; Xie, Youtao; Zheng, Xuebin; Yao, Zhenjun; Zhang, Chi

    2017-07-24

    In order to tackle the implant-related infection, a novel way was developed in this study to coat vancomycin particles mixed with controlled release coating materials onto the surface of titanium alloy by using an electrostatic dry powder coating technique. To characterize this sustained release antibacterial coating, surface morphology, in vitro and in vivo drug release were sequentially evaluated. In vitro cytotoxicity was tested by Cell Counting Kit-8 (CCK-8) assay and cytological changes were observed by inverted microscope. The antibacterial properties against MRSA, including a bacterial growth inhibition assay and a colony-counting test by spread plate method were performed. Results indicated that the vancomycin-coated sample was biocompatible for Human osteoblast cell line MG-63 and displayed effective antibacterial ability against MRSA. The coating film was revealed uniform by scanning electron microscopy. Both the in vitro and in vivo drug release kinetics showed an initially high release rate, followed by an extended period of sustained drug release over 7 days. These results suggest that with good biocompatibility and antibacterial ability, the sustained release antibacterial coating of titanium alloy using our novel electrostatic dry powder coating process may provide a promising candidate for the treatment of orthopedic implant-related infection.

  1. Mathematic modulation of a simulation program for a coal and wood counter-current moving bed gasifier, which includes pyrolysis and drying processes and processes alternatives; Modelagem matematica e simulacao em computador de gaseificador de leito fixo contra-corrente para carvoes e biomassa com inclusao de processos de pirolise, secagem e alternativas do processo

    Energy Technology Data Exchange (ETDEWEB)

    Souza Santos, M.L. de [Instituto de Pesquisas Tecnologicas (IPT), Sao Paulo, SP (Brazil)

    1985-12-31

    A new version of a simulation program for coal and wood counter-current fixed bed gasifier has been completed and provides: all the principal information variables of the process throughout the bed as mass flow and composition for 13 gases and 6 solids, temperature of the gas and solid phases, reaction rates of combustion, gasification, pyrolysis and drying processes; composition, mass flow, temperature, combustion enthalpy and other produced gases physical and chemical properties; possibility of process alternatives analysis as volatiles recycling in order to eliminate tar, double withdrawn of gases and combinations. Comparisons between simulation and experimental results are presented. (author). 26 refs., 1 tab

  2. Thermogravimetric determination of the carbon dioxide reactivity of char from some New Zealand coals and its association with the inorganic geochemistry of the parent coal

    Energy Technology Data Exchange (ETDEWEB)

    Beamish, B.B.; Shaw, K.J.; Rodgers, K.A.; Newman, J. [University of Auckland, Auckland (New Zealand). Dept. of Geology

    1998-02-01

    Thermogravimetrically-determined carbon dioxide reactivities of char formed from New Zealand coals, ranging in rank from lignite to high volatile bituminous, vary from 0.12 to 10.63 mg/h/mg on a dry, ash-free basis. The lowest rank subbituminous coal chars have similar reactivities to the lignite coal chars. Calcium content of the char shows the strongest correlation with reactivity, which increases as the calcium content increases. High calcium per se does not directly imply a high char reactivity. Organically-bound calcium catalyses the conversion of carbon to carbon monoxide in the presence of carbon dioxide, whereas calcium present as discrete minerals in the coal matrix e.g., calcite, fails to significantly affect reactivity. Catalytic effects of magnesium, iron, sodium and phosphorous are not as obvious, but can be recognised for individual chars. The thermogravimetric technique provides a fast, reliable analysis that is able to distinguish char reactivity differences between coals, which may be due to any of the above effects. 27 refs., 6 figs., 4 tabs.

  3. Symbiotic potential: the integration of preheating and dry cooling in cokemaking

    Energy Technology Data Exchange (ETDEWEB)

    Barker, J E [British Carbonization Research Association, England; Bruce, J M; Kemmetmueller, R

    1978-06-01

    The expression closed energy cycle has become popular in the last decade as descriptive of industrial systems in which exhaust heat is recovered from a primary energy-conversion stage and utilized either recuperatively or regeneratively within the overall complex. An old and well-proven means of utilizing the sensible heat of the incandescent coke discharged from coke ovens is known as dry cooling. This is being practiced widely in the USSR and Japan, but not yet to any significant extent in the western world. The waste heat recovered by this system is normally used to raise steam for power generation and process use. A recent advance in the carbonization of coal for the manufacture of metallurgical coke has been the application of the technique of coal drying and preheating as a means of improving both coke quality and oven productivity, and this is usually energized by burning gas as a fuel. An alternative configuration, having practical advantages in relation to efficiency of utilization of recovered energy and to safety in operation, is represented by a combination of coal drying and preheating with dry cooling of the coke. This paper is concerned with the case for this combination and the means whereby it may be effected in practice. The energy cycle of cokemaking would thus be more nearly closed.

  4. Nuclear assay of coal. Volume 7. Coal rheology and its impact on nuclear assay. Final report

    International Nuclear Information System (INIS)

    Hogg, R.; Luckie, P.; Gozani, T.

    1979-01-01

    A number of possible techniques for introducing coal to a continuous on-line nuclear analysis of coal (CONAC) system have been evaluated, including flow methods and nonflow methods. A modified flat-belt feeder system was recommended. The success of such a coal-presentation technique would rely on proper entry to the feed hopper, shape of the withdrawal opening from the feed hopper, and a slow belt speed to minimize demixing

  5. Coal Mines Security System

    OpenAIRE

    Ankita Guhe; Shruti Deshmukh; Bhagyashree Borekar; Apoorva Kailaswar; Milind E.Rane

    2012-01-01

    Geological circumstances of mine seem to be extremely complicated and there are many hidden troubles. Coal is wrongly lifted by the musclemen from coal stocks, coal washeries, coal transfer and loading points and also in the transport routes by malfunctioning the weighing of trucks. CIL —Coal India Ltd is under the control of mafia and a large number of irregularities can be contributed to coal mafia. An Intelligent Coal Mine Security System using data acquisition method utilizes sensor, auto...

  6. Preventing performance drops of coal mills due to high moisture content

    DEFF Research Database (Denmark)

    Odgaard, Peter Fogh; Stoustrup, Jakob; Mataji, B.

    2007-01-01

    Coal mills pulverize and dry the coal dust before it is blown into the furnace in coal-fired power plants. The coal mills can only deliver the requested coal flow if certain conditions are fulfilled. These are normally considered as constraints on individual variables. However, combinations of more...... than one variable might cause problems even though these individually variables are in an acceptable region. This paper deals with such a problem. The combination of a high load of the power plant, a large load change and high moisture content in the coal, can force the coal mill into a state where...... coal is accumulated instead of being blown into the furnace. This paper suggests a simple method for preventing the accumulation of the coal in the mill, by limiting the requested coal flow considering the coal moisture content and the temperature outside the mill.  ...

  7. Mine Water Treatment in Hongai Coal Mines

    OpenAIRE

    Dang Phuong Thao; Dang Vu Chi

    2018-01-01

    Acid mine drainage (AMD) is recognized as one of the most serious environmental problem associated with mining industry. Acid water, also known as acid mine drainage forms when iron sulfide minerals found in the rock of coal seams are exposed to oxidizing conditions in coal mining. Until 2009, mine drainage in Hongai coal mines was not treated, leading to harmful effects on humans, animals and aquatic ecosystem. This report has examined acid mine drainage problem and techniques for acid mine ...

  8. Coal industry annual 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-01

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  9. Coal industry annual 1997

    International Nuclear Information System (INIS)

    1998-12-01

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs

  10. Coal marketing manual 1987

    Energy Technology Data Exchange (ETDEWEB)

    1987-01-01

    This manual provides information on the international coal market in tabulated format. Statistics are presented for the Australian coal industry, exports, currency movements, world coal production, coal and coke imports and exports. Detailed information is provided on the Australian coal industry including mine specific summaries. Pricing summaries for thermal and coking coal in 1987, coal quality standards and specifications, trends in coal prices and stocks. Imports and exports for World coal and coke, details of shipping, international ports and iron and steel production. An exporters index of Australian and overseas companies with industry and government contacts is included. 15 figs., 67 tabs.

  11. Coal industry annual 1996

    International Nuclear Information System (INIS)

    1997-11-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs

  12. Coal industry annual 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-11-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  13. Coal Industry Annual 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  14. Coal Industry Annual 1995

    International Nuclear Information System (INIS)

    1996-10-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995

  15. Coal and Energy.

    Science.gov (United States)

    Bryant, Reba; And Others

    This teaching unit explores coal as an energy resource. Goals, student objectives, background information, and activity options are presented for each major section. The sections are: (1) an introduction to coal (which describes how and where coal was formed and explains the types of coal); (2) the mining of coal (including the methods and ways of…

  16. Increase in efficiency and reduction of generation cost at hard coal-fired power plants. Post-combustion of combustion residues from co-firing of RDF and biomass during dry ash removal

    Energy Technology Data Exchange (ETDEWEB)

    Baur, Guenter [Magaldi Power GmbH, Esslingen (Germany); Spindeldreher, Olaf [RWE Generation SE, Werne (Germany); RWE Generation SE, Essen (Germany)

    2013-09-01

    Secondary as well as substitute fuels are being used in hard coal-fired power plants to improve efficiency and to enlarge fuel flexibility. However, grinding and firing systems of the existing coal-fired plants are not designed for those co-fuels. Any deterioration of the combustion performance would reduce the power output and increase ash disposal costs by increased content of combustion residues. The application of air-cooled ash removal, with simultaneous and controlled post-combustion of unburned residues on the conveyor belt, enlarges the furnace and maintains combustion efficiency even with different fuel qualities. Plant efficiency can also be increased through heat recovery. (orig.)

  17. Organosulphur Compounds in Coals as Determined by Reaction with Raney Nickel and Microscale Pyrolysis Techniques. Quarterly report, January-March, 1996

    International Nuclear Information System (INIS)

    Stalker, L.; Philip, P.

    1997-01-01

    Since the last report, we have concentrated on completing all the chemical degradation experimental work. This has involved the completion of a series of chemical degradation experiments using deuterium labeled sodium borohydride and deuterated methanol . The products of these desulphurization experiments have, as usual, been fractionated into aliphatic and aromatic hydrocarbons and NSO compounds. The aliphatic hydrocarbon fractions of each desulphurization experiment are currently being analysed by gas chromatography(GC) and gas chromatography-mass spectrometry(GCMS). The object of the deuterium labelling experiments is to determine the relative abundance of thioether, triolane, and thiophene organic sulphur units cleaved in the different coal fractions( i.e. pre- extracted coal matrix, asphaltene and free polars from the maltenes)

  18. Dry socket

    Science.gov (United States)

    Alveolar osteitis; Alveolitis; Septic socket ... You may be more at risk for dry socket if you: Have poor oral health Have a ... after having a tooth pulled Have had dry socket in the past Drink from a straw after ...

  19. Nuclear methods in coal research

    International Nuclear Information System (INIS)

    Lyon, W.S.

    1980-01-01

    Nuclear methods, particularly neutron activation analysis (NAA) provide useful information about elemental constituents in coal and fly ash, but often other techniques are required to supplement NAA data. Spark source mass spectrometry and atomic absorption have been studied as methods for determination of certain elements in coal that are not easily measured by NAA. In work concerned with the chemical speciation of elements in fly ash, a number of analytical techniques have been used; these include NAA, chemical etching and separation, optical and electron microscopy and x-ray diffraction

  20. Mine Water Treatment in Hongai Coal Mines

    Science.gov (United States)

    Dang, Phuong Thao; Dang, Vu Chi

    2018-03-01

    Acid mine drainage (AMD) is recognized as one of the most serious environmental problem associated with mining industry. Acid water, also known as acid mine drainage forms when iron sulfide minerals found in the rock of coal seams are exposed to oxidizing conditions in coal mining. Until 2009, mine drainage in Hongai coal mines was not treated, leading to harmful effects on humans, animals and aquatic ecosystem. This report has examined acid mine drainage problem and techniques for acid mine drainage treatment in Hongai coal mines. In addition, selection and criteria for the design of the treatment systems have been presented.

  1. Mine Water Treatment in Hongai Coal Mines

    Directory of Open Access Journals (Sweden)

    Dang Phuong Thao

    2018-01-01

    Full Text Available Acid mine drainage (AMD is recognized as one of the most serious environmental problem associated with mining industry. Acid water, also known as acid mine drainage forms when iron sulfide minerals found in the rock of coal seams are exposed to oxidizing conditions in coal mining. Until 2009, mine drainage in Hongai coal mines was not treated, leading to harmful effects on humans, animals and aquatic ecosystem. This report has examined acid mine drainage problem and techniques for acid mine drainage treatment in Hongai coal mines. In addition, selection and criteria for the design of the treatment systems have been presented.

  2. Characterization of biomasses, concentrates, and permeates of dried powder of Kombucha fermentation of spinach (Amaranthus sp.) and broccoli (Brassica oleracea) with membrane microfiltration and freeze drying techniques for natural sources of folic acid

    Science.gov (United States)

    Nugraha, Tutun; Susilowati, Agustine; Aspiyanto, Lotulung, Puspa Dewi; Maryati, Yati

    2017-11-01

    Fermentation of spinach (Amaranthus sp) and Broccoli (Brassica oleracea) using Kombucha Culture has been shown to produce biomass that has the potential to become natural sources of folic acid. To produce the materials, following the fermentation, the biomass was filtered using membrane microfiltration (0.15 µm) at a pressure of 40 psia, at room temperature, yielding the concentrate and the permeate fractions. Following this step, freeze drying process was done on the biomass feeds, as well as on the concentrate and permeate fractions. For the freeze drying stage, the samples were frozen, and the condenser was kept at -50°C for 40 hours, while the pressure in the chamber was set at 200 Pa. Freeze drying results showed that the final products, have differences in compositions, as well as differences in the dominat monomers of folates. After water content was driven out, freeze drying increased the concentrations of folic acid in the dried products, and was found to be the highest in the concentrate fractions. Freeze drying has been shown to be capable of protecting the folates from heat and oxidative damages that typicaly occur with other types of drying. The final freeze dried concentrates of fermentation of spinach and broccoli were found to contain folic acid at 2531.88 µg/mL and 1626.94 µg/mL, total solids at 87.23% and 88.65 %, total sugar at 22.66 µg/mL and 25.13 µg/mL, total reducing sugar at 34.46 mg/mL and 15.22 mg/mL, as well as disolved protein concentrations at 0.93 mg/mL and 1.45 mg/mL. Liquid Chromatography Mass Spectometry (LC-MS) identification of the folates in the freeze dried concentrates of fermented spinach and broccoli was done using folic acid and glutamic acid standard solutions as the reference materials. The results showed the presence of folic acid and showed that the dominant monomers of molecules of folates with molecular weights of 441.44 Da. and 441.54 Da. for spinach and broccoli respectively. Moreover, the monomers of glutamic

  3. The Czech base of hard coal, problems, possibilities for utilization

    International Nuclear Information System (INIS)

    Cermak, T.; Roubicek, V.

    1993-01-01

    The Czech coal and power engineering base is in a deep restructuring period now. The basic problems represents the changeover from the system of the centrally planned state economy to the market model of the energy resources mining, production and consumption. The Czech economy will have to face to up to now unknown competitive forces on the coal market in Europe where American, Canadian, Australian and South African coals compete. The paper discusses historical aspects of the development of the coal mining industry in the Czechoslavakia, the present coal preparation techniques for coking coals, the coking industry, and the utilization of brown coal. How to utilize the domestic coal base and coal generally is closely connected with the global restructuralization of the Czech economy. The most difficult step of this process is undoubtedly the adaptation of the Czech fuel and energy base to the market economy conditions

  4. Effect of Water on Coal Strength | Singh | Momona Ethiopian Journal ...

    African Journals Online (AJOL)

    Water content is one of the most important factors influencing the rock strength. The present study has been conducted to see how coal strength changes under dry and water saturated conditions. The study reveals that the strength of coal decreases with increasing moisture. For rock mechanics and rock engineering ...

  5. Coal statistics 1977

    Energy Technology Data Exchange (ETDEWEB)

    Statistical Office of the European Communities

    1978-01-01

    Presents tables of data relating to the coal market in the European Community in 1977. The tables cover hard coal production, supply and trade; briquettes; cokes; lignite, brown coal briquettes and peat; and mines and coke ovens.

  6. Australian coal yearbook 1989

    Energy Technology Data Exchange (ETDEWEB)

    Aylward, A [ed.

    1989-01-01

    This yearbook contains a mine directory; details of coal export facilities and ports; annual coal statistics; a buyers' guide; names and addresses of industry organisations and an index of coal mine owners.

  7. Coal industry annual 1993

    Energy Technology Data Exchange (ETDEWEB)

    1994-12-06

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  8. Coal industry annual 1993

    International Nuclear Information System (INIS)

    1994-01-01

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993

  9. Coal trends and prospects in Malaysia. Malaysia no sekitan doko to mitoshi

    Energy Technology Data Exchange (ETDEWEB)

    Husin, T. (Tenaga Nasional Berhad (Malaysia))

    1993-03-01

    This paper describes problems in coal development and coal processing techniques used in Malaysia. Malaysia has a national organization placing importance on maximizing natural gas source development, but no such an organization is available for coal. Necessity exists in developing transportation infrastructures that can transport coal at a competitive price from coal mines to users inside and outside the country. Majority of the Merit Pila coal is produced in mines with relatively thin coal beds, which raise production cost higher. Coal resources are mostly of low calorific power. Since the coal resource development is a new economic activity, it requires training of people in related areas, and frameworks of legislative regulation. Important in coal development is to select technologies that can meet environmental requirements and stand with competitions in the world coal markets. New coal processing technologies available for discussion in coal refining processes include relaxed gasification or pyrolysis, coal liquefaction, coal-water mixture to mix coal powder and water with additives, coal pretreatment techniques, coal cleaning techniques, and fluidized bed combustion. 1 fig., 1 tab.

  10. Australian black coal statistics 1990

    Energy Technology Data Exchange (ETDEWEB)

    1991-01-01

    This second edition of Australian black coal statistics replaces the Joint Coal Board's publication 'Black coal in Australia'. It includes an expanded international coal trade supplement. Sections cover resources of black coal, coal supply and demand, coal production, employment and productivity of mines, export data, coal consumption and a directory of producers.

  11. Prospects for coal and clean coal technologies in Vietnam

    Energy Technology Data Exchange (ETDEWEB)

    Baruya, P. [IEA Clean Coal Centre, London (United Kingdom)

    2010-02-15

    Vietnam's energy economy is largely served by traditional biofuels and oil products. Within the power generating sector, hydropower and gas-fired power dominate. However, Vietnam still maintains a 40 Mt/y coal industry, parts of which have recently undergone a long overdue programme of renovation and expansion. Vietnam has been a successful exporter of anthracite, with more than half of the country's production being shipped or barged to steel mills in Japan or power stations in southern China, as well as most other Far Eastern coal importers. The industry is due to take a different form. Opencast mining has recently accounted for around 60% of production but this mining method could be phased out as reserves become more difficult and costly to extract. A shift to underground mining is expected, with a greater emphasis on more modern and mechanised production techniques. Coal is located mainly in the coalfields in Quang Ninh in the north easternmost province of Vietnam. The lower rank reserves located within the Red River coalfields, close to the existing anthracite operations, may yield many more millions of tonnes of coal for exploitation. Underground coal gasification could possibly be exploited in the deeper reserves of the Red River Basin. While coal production could rapidly change in future years, the power generation sector is also transforming with the country's 12,000 MWe development programme for new coal-fired power capacity. The economy suffers from a threat of power shortages due to a lack of generating and transmission capacity, while inefficiencies blight both energy production and end-users. Delivering power to the regions of growth remains difficult as the economy and the demand for power outpaces power generation. While hydroelectric power is being pursued, coal is therefore becoming a growing factor in the future prosperity of the Vietnamese economy. 111 refs., 33 figs., 11 tabs.

  12. Identification of organic sulfur compounds in coal bitumen obtained by different extraction techniques using comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometric detection

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Maria Elisabete; Cappelli Fontanive, Fernando; Bastos Caramao, Elina; Alcaraz Zini, Claudia [Universidade Federal do Rio Grande do Sul, Instituto de Quimica, Porto Alegre, RS (Brazil); Oliveira, Jose Vladimir de [URI, Universidade Regional Integrada do Alto Uruguai e das Missoes, Erechim, RS (Brazil)

    2011-11-15

    The determination of organic sulfur compounds (OSC) in coal is of great interest. Technically and operationally these compounds are not easily removed and promote corrosion of equipment. Environmentally, the burning of sulfur compounds leads to the emission of SO{sub x} gases, which are major contributors to acid rain. Health-wise, it is well known that these compounds have mutagenic and carcinogenic properties. Bitumen can be extracted from coal by different techniques, and use of gas chromatography coupled to mass spectrometric detection enables identification of compounds present in coal extracts. The OSC from three different bitumens were tentatively identified by use of three different extraction techniques: accelerated solvent extraction (ASE), ultrasonic extraction (UE), and supercritical-fluid extraction (SFE). Results obtained from one-dimensional gas chromatography (1D GC) coupled to quadrupole mass spectrometric detection (GC-qMS) and from two-dimensional gas chromatography with time-of-flight mass spectrometric detection (GC x GC-TOFMS) were compared. By use of 2D GC, a greater number of OSC were found in ASE bitumen than in SFE and UE bitumens. No OSC were identified with 1D GC-qMS, although some benzothiophenes and dibenzothiophenes were detected by use of EIM and SIM modes. GC x GC-TOFMS applied to investigation of OSC in bitumens resulted in analytical improvement, as more OSC classes and compounds were identified (thiols, sulfides, thiophenes, naphthothiophenes, benzothiophenes, and benzonaphthothiophenes). The roof-tile effect was observed for OSC and PAH in all bitumens. Several co-elutions among analytes and with matrix interferents were solved by use of GC x GC. (orig.)

  13. Microfine coal firing results from a retrofit gas/oil-designed industrial boiler

    Energy Technology Data Exchange (ETDEWEB)

    Patel, R.; Borio, R.W.; Liljedahl, G. [Combustion Engineering, Inc., Windsor, CT (United States)] [and others

    1995-11-01

    Under US Department of Energy, Pittsburgh Energy Technology Center (PETC) support, the development of a High Efficiency Advanced Coal Combustor (HEACC) has been in progress since 1987 at the ABB Power Plant Laboratories. The initial work on this concept produced an advanced coal firing system that was capable of firing both water-based and dry pulverized coal in an industrial boiler environment.

  14. Quantitative applications of gamma densitometry in the coal industry: a critique

    International Nuclear Information System (INIS)

    Shea, P.; Sher, R.; Gozani, T.

    1982-01-01

    This paper discusses the use of gamma densitometry to quantitatively assay bulk samples of coal on a continuous basis. Devices using these principles to determine mass flows are on the market, and work is progressing in several countries on instruments to determine ash content. The theoretical limits of applicability and inherent assumptions of these techniques are discussed, primarily as applied to dry bulk coal, but with some discussion of the more complicated problems of slurried coal. Gamma rays are generated by sources, usually a single radioactive element. These have several advantages over XRF, the main one being that no power is required to generate gammas. However, there are a limited number of gamma sources with useful energies, long enough half-lives to be economically useful, and clean spectra (that is, relatively few energies emitted by the source in question). Gamma densitometry measurements by single and multiple-energy transmission and backscatter measurements are discussed. A general formalism for analyzing multiple-energy systems is presented. While multi-energy systems can, in principle, pick out as many groups of elements as energies used, the matrices involved are ill-conditioned and thus require accurate measures of count rate (i.e., long counting times or high source intensities) to achieve acceptable errors. Changes in coal composition and profile of coal on a belt were also seen to be important sources of error. Transmission measurements are more amenable to analysis than backscatter, which are essentially transmission measurements made on a distributed source. In addition, transmission measurements are not restricted to low energy gamma sources, and can survey the entire bulk of coal rather than just the upper portion. The special problems of slurried coal measurements are briefly discussed

  15. 1982 Australian coal conference papers

    Energy Technology Data Exchange (ETDEWEB)

    1982-01-01

    This third Australian coal conference included papers discussing the market for coal, finance and investment, use of computers, mining, coal research, coal preparation and waste disposal, marketing and trade, and the transport of coal. All papers have been individually abstracted.

  16. Power Generation from Coal 2010

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-07-01

    Coal is the biggest single source of energy for electricity production and its share is growing. The efficiency of converting coal into electricity matters: more efficient power plants use less fuel and emit less climate-damaging carbon dioxide. This book explores how efficiency is measured and reported at coal-fired power plants. With many different methods used to express efficiency performance, it is often difficult to compare plants, even before accounting for any fixed constraints such as coal quality and cooling-water temperature. Practical guidelines are presented that allow the efficiency and emissions of any plant to be reported on a common basis and compared against best practice. A global database of plant performance is proposed that would allow under-performing plants to be identified for improvement. Armed with this information, policy makers would be in a better position to monitor and, if necessary, regulate how coal is used for power generation. The tools and techniques described will be of value to anyone with an interest in the more sustainable use of coal.

  17. Thermal Stability of Oil Palm Empty Fruit Bunch (OPEFB) Nanocrystalline Cellulose: Effects of post-treatment of oven drying and solvent exchange techniques

    International Nuclear Information System (INIS)

    Indarti, E; Wanrosli, W D; Marwan

    2015-01-01

    Nanocrystallinecellulose (NCC) from biomass is a promising material with huge potentials in various applications. A big challenge in its utilization is the agglomeration of the NCC's during processing due to hydrogen bonding among the cellulose chains when in close proximity to each other. Obtaining NCC's in a non-agglomerated and non-aqueous condition is challenging. In the present work NCC's was isolated from oil palm empty fruit bunch (OPEFB) using TEMPO-oxidation reaction method. To obtain non-agglomerated and non-aqueous products, the NCC's underwent post-treatment using oven drying (OD) and solvent exchanged (SE) techniques. The thermal stability of all samples was determined from TGA and DTG profiles whilst FTIR was used to analyzethe chemical modifications that occurred under these conditions. NCC-SE has better thermal stability than the NCC-OD and its on-set degradation temperature and residue are also higher. FTIR analysis shows that NCC-SE has a slightly different chemical composition whereby the absorption band at 1300 cm -1 (due to C-O symmetric stretching) is absent as compared to NCC-OD indicating that in NCC-SE the carboxylate group is in acid form which contribute to its thermal stability (paper)

  18. The celebrated écorchés of Honoré Fragonard, part 1: The classical techniques of preparation of dry anatomical specimens in the 18th century.

    Science.gov (United States)

    Degueurce, Christophe; Adds, Philip

    2010-04-01

    The écorchés that Honoré Fragonard created between 1766 and 1771 have miraculously survived the ravages of time due to a technique of preparation which Fragonard never revealed. The present paper and a subsequent article aim to explain the classical methods used by anatomists of the 18th century (Part 1) and to throw light on the details of Fragonard's method (Part 2). Anatomists of the 18th century who wished to preserve their dissections used a method of mummification, which has now fallen into disuse: drying after immersion in alcohol. This article explains the stages of the classical method utilized by French anatomists of the Age of Enlightenment. The cadaver was selected with care before the vascular system was injected with a colored mixture of wax, animal fat, and plant resins. The body was then dehydrated by immersion in a bath of alcohol, after which it was removed and positioned by means of a wooden framework, which held the body in the desired pose while the alcohol evaporated. The vessels were painted, and finally the body was varnished. 2010 Wiley-Liss, Inc.

  19. Continuous bench-scale slurry catalyst testing direct coal liquefaction rawhide sub-bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Bauman, R.F.; Coless, L.A.; Davis, S.M. [and others

    1995-12-31

    In 1992, the Department of Energy (DOE) sponsored research to demonstrate a dispersed catalyst system using a combination of molybdenum and iron precursors for direct coal liquefaction. This dispersed catalyst system was successfully demonstrated using Black Thunder sub-bituminous coal at Wilsonville, Alabama by Southern Electric International, Inc. The DOE sponsored research continues at Exxon Research and Development Laboratories (ERDL). A six month continuous bench-scale program using ERDL`s Recycle Coal Liquefaction Unit (RCLU) is planned, three months in 1994 and three months in 1995. The initial conditions in RCLU reflect experience gained from the Wilsonville facility in their Test Run 263. Rawhide sub-bituminous coal which is similar to the Black Thunder coal tested at Wilsonville was used as the feed coal. A slate of five dispersed catalysts for direct coal liquefaction of Rawhide sub-bituminous coal has been tested. Throughout the experiments, the molybdenum addition rate was held constant at 100 wppm while the iron oxide addition rate was varied from 0.25 to 1.0 weight percent (dry coal basis). This report covers the 1994 operations and accomplishments.

  20. Abundances of polycyclic aromatic hydrocarbons (PAHs) in 14 chinese and american coals and their relation to coal rank and weathering

    Science.gov (United States)

    Wang, R.; Liu, Gaisheng; Zhang, Jiahua; Chou, C.-L.; Liu, J.

    2010-01-01

    The abundances of 16 polycyclic aromatic hydrocarbons (PAHs) on the priority list of the United States Environmental Protection Agency (U.S. EPA) have been determined in 14 Chinese and American coals. The ranks of the samples range from lignite, bituminous coal, anthracite, to natural coke. Soxhlet extraction was conducted on each coal for 48 h. The extract was analyzed on a gas chromatograph-mass spectrometer (GC-MS). The results show that the total PAH content ranged from 0.31 to 57.6 ??g/g of coal (on a dry basis). It varied with coal rank and is highest in the maturity range of bituminous coal rank. High-molecular-weight (HMW) PAHs are predominant in low-rank coals, but low-molecular-weight (LMW) PAHs are predominant in high-rank coals. The low-sulfur coals have a higher PAH content than high-sulfur coals. It may be explained by an increasing connection between disulfide bonds and PAHs in high-sulfur coal. In addition, it leads us to conclude that the PAH content of coals may be related to the depositional environment. ?? 2010 American Chemical Society.

  1. Beneficiation of power grade coals: its relevance to future coal use in India

    International Nuclear Information System (INIS)

    Sachdev, R.K.

    1992-01-01

    With consumption increasing from the current level of 220 mt. to over 600 mt. by the year 2010 A.D., coal will continue to enjoy a prime position in the overall energy scene in India. India being endowed with coal resources of high ash content, the major coal consuming industries have, by and large, adjusted the combustion techniques to suit the quality of coal available. However, wide fluctuations in the quality of coal supplies adversely affect their plant performance. With the coal deposits being localised in the eastern and central parts of peninsular India, the load on railway network in carrying coal to other parts of the country will continue to increase and this will emerge as a major constraint in managing the coal supply to the consuming centres located away from the coal fields. It is in this context, the author has discussed the need of setting up of coal cleaning facilities at the pit heads. The extent to which the transport network will be relieved of carrying avoidable muck in coal has been quantified along with the benefits that will accrue in the form of extra transport capacity, better power plant performance and reduced air pollution and solid waste at consumer end. (author). 5 refs., 6 tabs., 8 figs

  2. Activation analysis of coal with the help of a microtron

    International Nuclear Information System (INIS)

    Sodnom, N.; Gehrbish, Sh.

    1989-01-01

    Activation analysis techniques using microtron bremsstrahlung and photoneutrons have been developed for the multielemental analysis of coal. Analysis data for coals from 17 mines of Mongolia are presented. The chlorine content of coal and the distribution of elements in coal burning products are determined. Control experiments were performed at the reactors IBR-2 and ARGUS. The results of the gamma activation analysis are compared with neutron activation and X-ray fluorescence analyses data. It is shown that the microtron irradiation techniques employed provide a satisfactory multielemental basis for the analysis of coal. (author)

  3. Ambient Dried Aerogels

    Science.gov (United States)

    Jones, Steven M.; Paik, Jong-Ah

    2013-01-01

    A method has been developed for creating aerogel using normal pressure and ambient temperatures. All spacecraft, satellites, and landers require the use of thermal insulation due to the extreme environments encountered in space and on extraterrestrial bodies. Ambient dried aerogels introduce the possibility of using aerogel as thermal insulation in a wide variety of instances where supercritically dried aerogels cannot be used. More specifically, thermoelectric devices can use ambient dried aerogel, where the advantages are in situ production using the cast-in ability of an aerogel. Previously, aerogels required supercritical conditions (high temperature and high pressure) to be dried. Ambient dried aerogels can be dried at room temperature and pressure. This allows many materials, such as plastics and certain metal alloys that cannot survive supercritical conditions, to be directly immersed in liquid aerogel precursor and then encapsulated in the final, dried aerogel. Additionally, the metalized Mylar films that could not survive the previous methods of making aerogels can survive the ambient drying technique, thus making multilayer insulation (MLI) materials possible. This results in lighter insulation material as well. Because this innovation does not require high-temperature or high-pressure drying, ambient dried aerogels are much less expensive to produce. The equipment needed to conduct supercritical drying costs many tens of thousands of dollars, and has associated running expenses for power, pressurized gasses, and maintenance. The ambient drying process also expands the size of the pieces of aerogel that can be made because a high-temperature, high-pressure system typically has internal dimensions of up to 30 cm in diameter and 60 cm in height. In the case of this innovation, the only limitation on the size of the aerogels produced would be in the ability of the solvent in the wet gel to escape from the gel network.

  4. Ultravitrinite coals from Chukotka

    Energy Technology Data Exchange (ETDEWEB)

    Lapo, A.V.; Letushova, I.A.

    1979-03-01

    Chemical and petrographic analysis was conducted on coals from the Anadyrya and Bukhti Ugol'noi deposits. Characteristics of the most prevalent type of vitrinite coals in both regions are presented here. Anadyrya coals belong to a transitional phase between brown coal and long flame. Ultravitrinite coals predominate. Gas coals from Bukti Ugol'noi have a higher carbon content than Anadyrya coals. They also have a higher hydrogen content and yield of initial resin. In several cases there was also a higher yield of volatile substances. Chukotka coals are characterized by a 10 percent higher initial resin yield than equally coalified Donetsk coals, other indicators were equal to those of Donetsk coals. Because of this, Chukotka coals are suitable for fuel in power plants and as raw materials in the chemical industry. (15 refs.) (In Russian)

  5. Thar coal exploration : a radical view

    International Nuclear Information System (INIS)

    Khan, N.A.

    1996-01-01

    Pakistan needs a manpower intensive technology to utilize its immense human resource. This human resource, however, has low literacy rate and thus lower skills and therefore there is a requirement of visualizing an employment technique compatible with the human resource. The vast coal deposits at Thar Coal Field provide an opportunity for development of low cost coal mining technique utilizing this manpower. Our history is filled with examples of effective utilization of human resources in the recent past. 300 years ago a few Muslim Emperors of the subcontinents constructed 40 meters deep wells, by utilizing human power only, to reach drinking water deep down, now in 2000 AD, can we go down 120 meters to dig the coal in Thar Coal Field by utilizing much enlarged manpower? (author)

  6. Coal Tar and Coal-Tar Pitch

    Science.gov (United States)

    Learn about coal-tar products, which can raise your risk of skin cancer, lung cancer, and other types of cancer. Examples of coal-tar products include creosote, coal-tar pitch, and certain preparations used to treat skin conditions such as eczema, psoriasis, and dandruff.

  7. Evaluation of the effect of various drying techniques on the composition of the psychoactive phenylpropylamino alkaloids of khat (Catha edulis Forsk chewing leaves

    Directory of Open Access Journals (Sweden)

    S. Chigome

    2013-09-01

    Full Text Available The study demonstrated that by freezing or drying under different conditions, cathinone could be detected in the khat (Catha edulis Forsk samples that have been harvested for more than four months. Freeze drying or freezing in the refrigerator (-20 oC yielded more than 73% of cathinone. Air drying, sun drying or oven drying at 60 oC resulted in a cathinone composition of 57%, 42% and 36%, respectively. The study confirmed that, freshly harvested tender leaves of khat contained exclusively of cathinone but upon sun drying, part of it decomposes to cathine and norephedrine leaving cathinone as a major component. Thus it is wrong to assume that sun drying the leaves can result complete conversion of cathinone to cathine and norephedrine. Furthermore, the results of the study confirmed that it was possible to preserve khat samples for longer periods after freeze drying or deep freezing without significant loss of cathinone.DOI: http://dx.doi.org/10.4314/bcse.v27i3.3

  8. Evaluation of dry blood spot technique for quantification of an Anti-CD20 monoclonal antibody drug in human blood samples.

    Science.gov (United States)

    Lin, Yong-Qing; Zhang, Yilu; Li, Connie; Li, Louis; Zhang, Kelley; Li, Shawn

    2012-01-01

    To evaluate the dried blood spot (DBS) technique in ELISA quantification of larger biomolecular drugs, an anti-CD20 monoclonal antibody drug was used as an example. A method for the quantification of the anti-CD20 drug in human DBS was developed and validated. The drug standard and quality control samples prepared in fresh human blood were spotted on DBS cards and then extracted. A luminescent ELISA was used for quantification of the drug from DBS samples. The assay range of the anti-CD20 drug standards in DBS was 100-2500ng/mL. The intra-assay precision (%CV) ranged from 0.4% to 10.1%, and the accuracy (%Recovery) ranged from 77.9% to 113.9%. The inter assay precision (%CV) ranged from 5.9% to 17.4%, and the accuracy ranged from 81.5% to 110.5%. The DBS samples diluted 500 and 50-fold yielded recovery of 88.7% and 90.7%, respectively. The preparation of DBS in higher and lower hematocrit (53% and 35%) conditions did not affect the recovery of the drug. Furthermore, the storage stability of the anti-CD20 drug on DBS cards was tested at various conditions. It was found that the anti-CD20 drug was stable for one week in DBS stored at room temperature. However, it was determined that the stability was compro]mised in DBS stored at high humidity, high temperature (55°C), and exposed to direct daylight for a week, as well as for samples stored at room temperature and high humidity conditions for a month. Stability did not change significantly in samples that underwent 3 freeze/thaw cycles. Our results demonstrated a successful use of DBS technique in ELISA quantification of an anti-CD20 monoclonal antibody drug in human blood. The stability data provides information regarding sample storage and shipping for future clinical studies. It is, therefore, concluded that the DBS technique is applicable in the quantification of other large biomolecule drugs or biomarkers. Copyright © 2011 Elsevier Inc. All rights reserved.

  9. Coal Bed Methane Primer

    Energy Technology Data Exchange (ETDEWEB)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of

  10. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS (CFB AND CLB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS

    Energy Technology Data Exchange (ETDEWEB)

    Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thein; Gengsheng Wei; Soyuz Priyadarsan; Senthil Arumugam; Kevin Heflin

    2003-08-28

    Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain-diet diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. The manure could be used as a fuel by mixing it with coal in a 90:10 blend and firing it in an existing coal suspension fired combustion systems. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Reburn is a process where a small percentage of fuel called reburn fuel is injected above the NO{sub x} producing, conventional coal fired burners in order to reduce NO{sub x}. The manure could also be used as reburn fuel for reducing NO{sub x} in coal fired plants. An alternate approach of using animal waste is to adopt the gasification process using a fixed bed gasifier and then use the gases for firing in gas turbine combustors. In this report, the cattle manure is referred to as feedlot biomass (FB) and chicken manure as litter biomass (LB). The report generates data on FB and LB fuel characteristics. Co-firing, reburn, and gasification tests of coal, FB, LB, coal: FB blends, and coal: LB blends and modeling on cofiring, reburn systems and economics of use of FB and LB have also been conducted. The biomass fuels are higher in ash, lower in heat content, higher in moisture, and higher in nitrogen and sulfur (which can cause air pollution) compared to coal. Small-scale cofiring experiments revealed that the biomass blends can be successfully fired, and NO{sub x} emissions will be similar to or lower than pollutant emissions when firing coal. Further experiments showed that biomass is twice or more effective than coal when

  11. Treatment of peat, brown coal, etc

    Energy Technology Data Exchange (ETDEWEB)

    Francke, F C

    1917-11-02

    Treatment of peat, brown coal, lignite, sapropel, oil shale, wood and the like, characterized by the fact, that the material is dried in a drum having side gas-entrance and gas-exit pipes, and is provided in the known way with ledges under slow turning and then is distilled at a temperature below 550/sup 0/ C.

  12. Model documentation Coal Market Module of the National Energy Modeling System

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-04-30

    This report documents objectives and conceptual and methodological approach used in the development of the National Energy Modeling System (NEMS) Coal Market Module (CMM) used to develop the Annual Energy Outlook 1996 (AEO96). This report catalogues and describes the assumptions, methodology, estimation techniques, and source code of CMM`s three submodules: Coal Production Submodule, Coal Export Submodule, and Coal Distribution Submodule.

  13. Multi-element determinations of N,N-dimethylformamide (DMF) coal slurries using ICP-OES

    Energy Technology Data Exchange (ETDEWEB)

    M. Mujuru; R.I. McCrindle; B.M. Botha; P.P. Ndibewu [Tshwane University of Technology, Pretoria (South Africa). Department of Chemistry

    2009-04-15

    A slurry nebulisation technique was applied for elemental analysis of bituminous coals SARM 18, SARM 19 and four coals from three different seams in Witbank, South Africa, by inductively coupled plasma optical emission spectroscopy (ICP-OES). Major elements (Al, Ca, Fe, Mg, S, Si and Ti) and trace elements (Ba, Cr, Mn, Ni, Sr, V, Zn and Zr) in coal were determined. Various slurry preparations were evaluated using two dispersants (glycerol and Triton X-100) and by varying the concentration of dispersants, between 0.1% and 1.0% (v/v). The effect of initially solubilising the ground coal in N,N-dimethylformamide (DMF) was investigated by varying the volume of DMF added. The effect of wet grinding with DMF was investigated. Wet grinding with DMF was shown to drastically reduce particle sizes (50.0% < 0.28 m and 90.0% < 6.17 {mu}m) as compared to dry grinding (50.0% < 5.25 {mu}m and 90.0% < 11.1 {mu}m). The reduced particle sizes and increased transport efficiency of the coal slurries led to improved analytical recoveries of elements in the reference coal, SARM 18. The best analytical recoveries for all elements were achieved using 0.1% Triton X-100 with 10.0% DMF. Results obtained by ICP-OES after wet grinding of the coal with DMF, using 0.1% Triton X-100, also gave excellent recoveries (Al, 100%; Ca, 103%; Cr, 106%; Fe, 102%; Mg, 100%; Mn, 104%; Ni, 109%; Si, 102%; Ti, 95.0%; and V, 108%). The results obtained with 10.0% DMF and 0.1% Triton X-100 were in agreement with certified values for all selected elements according to paired t-test at the 95.0% confidence level. Selected elements (Al, Ca, Fe, Mg, Mn, Si, Ti and V) were also analysed with X-ray fluorescence for comparison with results obtained from ICP-OES. Analysis by ICP-OES of microwave digested coal was also carried out. It is suggested that the DMF slurry technique could be used for routine analysis of bituminous coals. 27 refs., 4 figs., 4 tabs.

  14. Land use and coal technology

    International Nuclear Information System (INIS)

    Anon.

    1978-01-01

    The Arid Lands Ecology Reserve and the Hanford National Environmental Research Park were established to promote the use of the Hanford Site for ecological research, especially studies related to energy technologies and their potential for environmental impacts. Coal is currently regarded as the most dependable interim source of energy in the United States. To meet expected demands, coal needs to be mined in large quantities and may be mined predominantly in locations of sparse precipitation. Often the most economical way to extract coal is through surface mining. It is expected that following coal extraction the pits will be filled with overburden, graded to approximate original contour, native topsoil applied to prescribed depths and planted with climatically adapted herbs, shrubs or trees. Because primary productivity in dry regions is characteristically low, it is realistic to expect, if the above procedure is followed, that the revegetated surfaces will also produce little phytomass in the years following restoration. Appropriate data are needed for accurate estimation of the economic feasibility of a particular restoration practice or its alternative. Research programs are discussed briefly

  15. Management of coal combustion wastes

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2014-02-01

    It has been estimated that 780 Mt of coal combustion products (CCPs) were produced worldwide in 2010. Only about 53.5% were utilised, the rest went to storage or disposal sites. Disposal of coal combustion waste (CCW) on-site at a power plant may involve decades-long accumulation of waste, with hundreds of thousands, if not millions, of tonnes of dry ash or wet ash slurry being stored. In December 2008, a coal combustion waste pond in Kingston, Tennessee, USA burst. Over 4 million cubic metres of ash sludge poured out, burying houses and rivers in tonnes of toxic waste. Clean-up is expected to continue into 2014 and will cost $1.2 billion. The incident drew worldwide attention to the risk of CCW disposal. This caused a number of countries to review CCW management methods and regulations. The report begins by outlining the physical and chemical characteristics of the different type of ashes generated in a coal-fired power plant. The amounts of CCPs produced and regulations on CCW management in selected countries have been compiled. The CCW disposal methods are then discussed. Finally, the potential environmental impacts and human health risks of CCW disposal, together with the methods used to prevent them, are reviewed.

  16. Dissolution of subbituminous coal in tetrahydroquinoline

    Energy Technology Data Exchange (ETDEWEB)

    Silver, H F; Frazee, W S; Broderick, T E; Hurtubise, R J

    1986-05-01

    Two different samples of Wyodak subbituminous coal from the Powder River Basin in Wyoming were liquefied in a two dm/sup 3/ batch reactor using 1,2,3,4 tetrahydroquinoline, THQ, as a solvent. Sufficient sample was produced to determine product boiling ranges by distillation and to measure THQ distribution in the product. Product distillation showed that even at cyclohexane conversions greater than 50%, net distillate yields produced using THQ as a solvent were negative. In some cases, high boiling, coal-derived residue yields were greater than the dry coal charged to the reactor. These observations have been attributed to THQ losses resulting from dimerization of the THQ and reactions between THQ and coal derived components. 5 references.

  17. Underground gasification of coal - possibilities and trends

    International Nuclear Information System (INIS)

    Dushanov, D.; Minkova, V.

    1994-01-01

    A detailed historical review is given on the problem of underground coal gasification (UCG) with emphasis on its physical, chemical, technological and financial aspects. The experience of USA, Japan, former USSR, Belgium, UK and France is described. The feasibility of UCG in the Dobrudzhan Coal Bed in Bulgaria is discussed. The deposit has reserves of about 1.5 billion tones at relatively shallow depths. Almost the whole scale from long flame to dry coal is covered. According to its coalification degree the bed belongs to gas coal - V daf 35-40%; C daf 80-83%, eruption index = 1. Enriched samples has low sulfur content - 0.6-1.5% and low mineral content - 6-12%. Having in mind the lack of domestic natural gas and petroleum resources, the authors state that the utilisation of the bed will alleviate the energy problems in Bulgaria. 24 refs., 5 figs., 1 tab

  18. Basic investigations to improve the refinement process of coal. Grundlagenuntersuchungen zur Erhoehung des Veredlungsverhaltens von Kohlen

    Energy Technology Data Exchange (ETDEWEB)

    Krug, H; Naundorf, W; Trommer, D

    1985-01-01

    In the four articles in this issue, variants of the process for the effective use and improved refinement of brown coal are described. There are reports on the manufacture of special briquettes from briquette coal slack and on the briquetting behaviour of dry brown coal dust and the briquetting and coking behaviour of hard foreign brown coal containing a lot of ash. The four articles are dealt with separately. With 52 figs., 10 tabs.

  19. Record coking coal settlements

    Energy Technology Data Exchange (ETDEWEB)

    Macdonald, C.

    2005-02-01

    The US$100/tonne psychological barrier in coking coal prices has been well and truly smashed. The article examines developments in coal pricing. It includes quotes from many senior executives in the coal industry as collected at McCloskey's Australian Coal.04 conference held in Sydney, 18-19 November 2004. 2 photos.

  20. COAL Conference Poster

    OpenAIRE

    Brown, Taylor Alexander; McGibbney, Lewis John

    2017-01-01

    COAL Conference Poster This archive contains the COAL conference poster for the AGU Fall Meeting 2017 by Taylor Alexander Brown. The Inkscape SVG source is available at https://github.com/capstone-coal/coal-conference-poster/ under the Creative Commons Attribution-ShareAlike 4.0 International license.

  1. Chemical and Pyrolytic Thermogravimetric Characterization of Nigerian Bituminous Coals

    Directory of Open Access Journals (Sweden)

    Nyakuma Bemgba Bevan

    2016-12-01

    Full Text Available The discovery of new coal deposits in Nigeria presents solutions for nation’s energy crises and prospects for socioeconomic growth and sustainable development. Furthermore, the quest for sustainable energy to limit global warming, climate change, and environmental degradation has necessitated the exploration of alternatives using cleaner technologies such as coal pyrolysis. However, a lack of comprehensive data on physico-chemical and thermal properties of Nigerian coals has greatly limited their utilization. Therefore, the physico-chemical properties, rank (classification, and thermal decomposition profiles of two Nigerian bituminous coals – Afuze (AFZ and Shankodi-Jangwa (SKJ – were examined in this study. The results indicate that the coals contain high proportions of C, H, N, S, O and a sufficiently high heating value (HHV for energy conversion. The coal classification revealed that the Afuze (AFZ coal possesses a higher rank, maturity, and coal properties compared to the Shankodi-Jangwa (SKJ coal. A thermal analysis demonstrated that coal pyrolysis in both cases occurred in three stages; drying (30-200 °C, devolatilization (200-600 °C, and char decomposition (600-1000 °C. The results also indicated that pyrolysis at 1000 °C is not sufficient for complete pyrolysis. In general, the thermochemical and pyrolytic fuel properties indicate that the coal from both places can potentially be utilized for future clean energy applications.

  2. Concerning coal: an anthology

    Energy Technology Data Exchange (ETDEWEB)

    Mayer, M.; Hawse, M.L.; Maloney, P.J. [eds.

    1997-12-31

    The anthology takes a humanistic look at coal mining in Illinois. One of its goals is to increase public awareness of coal in American society; it also seeks to enhance understanding of the historical aspects of coal and to study the impact of coal on mining families. Many of the 25 selections in the anthology come from Coal Research Center publications, `Concerning coal` and `Mineral matters`. Articles are arranged in three parts entitled: life in the mining community; mining in folklore, story telling, literature, art and music; and technology as it affected the people of the coal fields. 117 refs., 25 photos. 1 map.

  3. Coal information 1995

    International Nuclear Information System (INIS)

    1996-01-01

    This volume is a comprehensive reference book on current world coal market trends and long-term prospects to 2010. It contains an in-depth analysis of the 1995 international coal market covering prices, demand, trade, supply and production capacity as well as over 450 pages of country specific statistics on OECD and key non-OECD coal producing and consuming countries. The book also includes a summary of environmental policies on climate change and on coal-related air quality issues as well as essential facts on coal-fired power stations in coal-importing regions, on coal ports world-wide and on emission standards for coal-fired boilers in OECD countries. Coal Information is one of a series of annual IEA statistical publications on major energy sources; other reports are Oil and Gas Information and Electricity Information. Coal Information 1995 is published in July 1996. (author)

  4. Coal yearbook 1993

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    This book is the first coal yearbook published by ATIC (France). In a first chapter, economical context of coal worldwide market is analyzed: comparative evaluations on coal exports and imports, coal industry, prices, production in USA, Australia, South Africa, China, former USSR, Poland, Colombia, Venezuela and Indonesia are given. The second chapter describes the french energy context: national coal production, imports, sectorial analysis, maritime transport. The third chapter describes briefly the technologies of clean coal and energy saving developed by Charbonnages de France: fossil-fuel power plants with combined cycles and cogeneration, fluidized beds for the recovery of coal residues, recycling of agricultural wastes (sugar cane wastes) in thermal power plant, coal desulfurization for air pollution abatement. In the last chapter, statistical data on coal, natural gas and crude oil are offered: world production, world imports, world exports, french imports, deliveries to France, coal balance, french consumption of primary energy, power generation by fuel type

  5. Coal dust contiguity-induced changes in the concentration of TNF- and NF- B p65 on the ocular surface

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Z.Y.; Hong, J.; Liu, Z.Y.; Jin, X.D.; Gu, C.H. [China Medical University, Shenyang (China)

    2009-07-01

    To observe the influence of coal dust on ocular surface of coal miners and rabbits with coal dust contiguity on expression TNF- and NF- Bp65 and dry eye occurrence. Expression TNF- and NF- Bp65 in ocular surface were determined. Results showed tear production, BUT and lysozyme decreased for coal miners and rabbits with coal dust contiguity. Coal dust exposure was linked to development of xerophthalmia, and induced a higher expression of NF- B p65 and TNF- perhaps as a mechanism to resist coal dust ocular surface injury.

  6. Coal gasification. Quarterly report, April--June 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-01-01

    The conversion of coal to high-Btu gas requires a chemical and physical transformation of solid coal. However, because coal has widely differing chemical and physical properties, depending on where it is mined, it is difficult to process. Therefore, to develop the most suitable techniques for gasifying coal, ERDA, together with the American Gas Association, is sponsoring the development of several advanced conversion processes. Although the basic coal-gasification chemical reactions are the same for each process, the processes under development have unique characteristics. A number of the processes for converting coal to high Btu and to low Btu gas have reached the pilot plant stage. The responsibility for designing, constructing and operating each of these pilot plants is defined and progress on each during the quarter is described briefly. The accumulation of data for a coal gasification manual and the development of mathematical models of coal gasification processes are reported briefly. (LTN)

  7. Validation and Test-Retest Reliability of New Thermographic Technique Called Thermovision Technique of Dry Needling for Gluteus Minimus Trigger Points in Sciatica Subjects and TrPs-Negative Healthy Volunteers

    Science.gov (United States)

    Rychlik, Michał; Samborski, Włodzimierz

    2015-01-01

    The aim of this study was to assess the validity and test-retest reliability of Thermovision Technique of Dry Needling (TTDN) for the gluteus minimus muscle. TTDN is a new thermography approach used to support trigger points (TrPs) diagnostic criteria by presence of short-term vasomotor reactions occurring in the area where TrPs refer pain. Method. Thirty chronic sciatica patients (n=15 TrP-positive and n=15 TrPs-negative) and 15 healthy volunteers were evaluated by TTDN three times during two consecutive days based on TrPs of the gluteus minimus muscle confirmed additionally by referred pain presence. TTDN employs average temperature (T avr), maximum temperature (T max), low/high isothermal-area, and autonomic referred pain phenomenon (AURP) that reflects vasodilatation/vasoconstriction. Validity and test-retest reliability were assessed concurrently. Results. Two components of TTDN validity and reliability, T avr and AURP, had almost perfect agreement according to κ (e.g., thigh: 0.880 and 0.938; calf: 0.902 and 0.956, resp.). The sensitivity for T avr, T max, AURP, and high isothermal-area was 100% for everyone, but specificity of 100% was for T avr and AURP only. Conclusion. TTDN is a valid and reliable method for T avr and AURP measurement to support TrPs diagnostic criteria for the gluteus minimus muscle when digitally evoked referred pain pattern is present. PMID:26137486

  8. ACR coal 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    This publication is a comprehensive reference document on production, exports, prices and demand of coal in world markets. A forecast of demand by coal type and country up to the year 2000 is provided. Statistics of the Australian export industry are complemented by those of South Africa, USA, Canada, Indonesia, China, C.I.S. and Colombia. A very comprehensive coal quality specification for nearly all the coal brands exported from Australia, as well as leading non-Australian coal brands, is included.

  9. Assessing coal burnout

    Energy Technology Data Exchange (ETDEWEB)

    Lowe, A. [Pacific Power, Sydney, NSW (Australia)

    1999-11-01

    Recent research has allowed a quantitative description of the basic process of burnout for pulverized coals to be made. The Cooperative Research Centre for Black Coal Utilization has built on this work to develop a coal combustion model which will allow plant engineers and coal company representatives to assess their coals for combustion performance. The paper describes the model and its validation and outlines how it is run. 2 figs.

  10. Determination of Kinetic Parameters of Coal Pyrolysis to Simulate the Process of Underground Coal Gasification (UCG

    Directory of Open Access Journals (Sweden)

    Beata Urych

    2014-01-01

    Originality/value: The devolatilization of a homogenous lump of coal is a complex issue. Currently, the CFD technique (Computational Fluid Dynamics is commonly used for the multi-dimensional and multiphase phenomena modelling. The mathematical models, describing the kinetics of the decomposition of coal, proposed in the article can, therefore, be an integral part of models based on numerical fluid mechanics.

  11. Dry Etching

    DEFF Research Database (Denmark)

    Stamate, Eugen; Yeom, Geun Young

    2016-01-01

    generation) to 2,200 × 2,500 mm (eighth generation), and the substrate size is expected to increase further within a few years. This chapter aims to present relevant details on dry etching including the phenomenology, materials to be etched with the different recipes, plasma sources fulfilling the dry...

  12. Geopolymer obtained from coal ash

    International Nuclear Information System (INIS)

    Conte, V.; Bissari, E.S.; Uggioni, E.; Bernardin, A.M.

    2011-01-01

    Geopolymers are three-dimensional alumino silicates that can be rapidly formed at low temperature from naturally occurring aluminosilicates with a structure similar to zeolites. In this work coal ash (Tractebel Energy) was used as source of aluminosilicate according a full factorial design in eight formulations with three factors (hydroxide type and concentration and temperature) and two-levels. The ash was dried and hydroxide was added according type and concentration. The geopolymer was poured into cylindrical molds, cured (14 days) and subjected to compression test. The coal ash from power plants belongs to the Si-Al system and thus can easily form geopolymers. The compression tests showed that it is possible to obtain samples with strength comparable to conventional Portland cement. As a result, temperature and molarity are the main factors affecting the compressive strength of the obtained geopolymer. (author)

  13. An overview of coal preparation initiatives with application to coal conversion in South Africa

    International Nuclear Information System (INIS)

    Reinecke, C.F.; Bunt, J.R.

    1999-01-01

    Coal has for many years been the most important energy resource in South Africa and has contributed to more than 70 % of South Africa's energy needs in 1998. The large in-situ coal deposits (in excess of 120 x 10 9 t) and relatively large recoverable reserves (about 33.5 x 10 9 t) will ensure that coal will for many a year still be South Africa's single biggest energy resource. Biomass burning consumes approximately 11 Mt/a of which 8 Mt/a is natural wood. This equals natural wood production. The use of firewood is considered to be unsustainable. Of the 225 Mt/a of coal extracted in South Africa in 1998, 67.0 Mt/a was exported. Of this, 62.9 Mt/a were exported as steam coal, 2.1 Mt/a as metallurgical coal, and the rest as anthracite. Current exports are conducted via the Richards Bay terminal (63.6 Mt/a), Durban (2.0 Mt/a) and a small amount via Maputo. The Richards Bay terminal is to be expanded to 72 Mt/a by 1999. It is also very important to note that most of the coal resources possess calorific values of below 25 MJ/kg, which limits its utilization to power generation (Eskom) and processes such as fixed bed dry bottom gasification (Sasol). A break-down of production and usage of coal by the various controlling groups in South Africa shows that Sasol (54.2 Mt/a) and Escom (91.0 Mt/a) are major consumers of coal. It has been proposed earlier by Horsfall (1993) that for power generation and coal conversion, the in-situ quality is generally regarded as satisfactory for use. All that is required in the way of processing is crushing to an appropriate top size and, for conversion, screening of the unwashed coal. Most other consumers require some degree of beneficiation, which generally entails the removal of stone/shale and low quality coal. More recently, the introduction of destoning plants at Duvha Colliery (Larcodems) and New Vaal Colliery (Drewboy washers) has significantly reduced the abrasiveness content of these local thermal coals, together with an increase

  14. Coal-water fuels - a clean coal solution for Eastern Europe

    International Nuclear Information System (INIS)

    Ljubicic, B.; Willson, W.; Bukurov, Z.; Cvijanovic, P.; Stajner, K.; Popovic, R.

    1993-01-01

    Eastern Europe currently faces great economic and environmental problems. Among these problems is energy provision. Coal reserves are large but cause pollution while oil and gas need to be used for export. Formal 'clean coal technologies' are simply too expensive to be implemented on a large scale in the current economic crisis. The promised western investment and technological help has simply not taken place, western Europe must help eastern Europe with coal technology. The cheapest such technology is coal-water fuel slurry. It can substitute for oil, but research has not been carried out because of low oil prices. Coal-water fuel is one of the best methods of exploiting low rank coal. Many eastern European low rank coals have a low sulfur content, and thus make a good basis for a clean fuel. Italy and Russia are involved in such a venture, the slurry being transported in a pipeline. This technology would enable Russia to exploit Arctic coal reserves, thus freeing oil and gas for export. In Serbia the exploitation of sub-Danube lignite deposits with dredging mining produced a slurry. This led to the use and development of hot water drying, which enabled the removal of many of the salts which cause problems in pulverized fuel combustion. The system is economic, the fuel safer to transport then oil, either by rail or in pipelines. Many eastern European oil facilities could switch. 24 refs

  15. Coal and nuclear electricity fuels

    International Nuclear Information System (INIS)

    Rahnama, F.

    1982-06-01

    Comparative economic analysis is used to contrast the economic advantages of nuclear and coal-fired electric generating stations for Canadian regions. A simplified cash flow method is used with present value techniques to yield a single levelized total unit energy cost over the lifetime of a generating station. Sensitivity analysis illustrates the effects of significant changes in some of the cost data. The analysis indicates that in Quebec, Ontario, Manitoba and British Columbia nuclear energy is less costly than coal for electric power generation. In the base case scenario the nuclear advantage is 24 percent in Quebec, 29 percent in Ontario, 34 percent in Manitoba, and 16 percent in British Columbia. Total unit energy cost is sensitive to variations in both capital and fuel costs for both nuclear and coal-fuelled power stations, but are not very sensitive to operating and maintenance costs

  16. Initiative hard coal; Initiative Steinkohle

    Energy Technology Data Exchange (ETDEWEB)

    Leonhardt, J.

    2007-08-02

    In order to decrease the import dependence of hard coal in the European Union, the author has submitted suggestions to the director of conventional sources of energy (directorate general for energy and transport) of the European community, which found a positive resonance. These suggestions are summarized in an elaboration 'Initiative Hard Coal'. After clarifying the starting situation and defining the target the presupposition for a better use of hard coal deposits as raw material in the European Union are pointed out. On that basis concrete suggestions for measures are made. Apart from the conditions of the deposits it concerns thereby also new mining techniques and mining-economical developments, connected with tasks for the mining-machine industry. (orig.)

  17. Low-rank coal research. Quarterly report, January--March 1990

    Energy Technology Data Exchange (ETDEWEB)

    1990-08-01

    This document contains several quarterly progress reports for low-rank coal research that was performed from January-March 1990. Reports in Control Technology and Coal Preparation Research are in Flue Gas Cleanup, Waste Management, and Regional Energy Policy Program for the Northern Great Plains. Reports in Advanced Research and Technology Development are presented in Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Reports in Combustion Research cover Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Coal Fuels, Diesel Utilization of Low-Rank Coals, and Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications. Liquefaction Research is reported in Low-Rank Coal Direct Liquefaction. Gasification Research progress is discussed for Production of Hydrogen and By-Products from Coal and for Chemistry of Sulfur Removal in Mild Gas.

  18. Characterizing toxic emissions from a coal-fired power plant demonstrating the AFGD ICCT Project and a plant utilizing a dry scrubber/baghouse system: Bailly Station Units 7 and 8 and AFGD ICCT Project. Final report. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Dismukes, E.B.

    1994-10-20

    This report describes results of assessment of the risk of emissions of hazardous air pollutants at one of the electric power stations, Bailly Station, which is also the site of a Clean Coal Technology project demonstrating the Pure Air Advanced Flue Gas Desulfurization process (wet limestone). This station represents the configuration of no NO{sub x} reduction, particulate control with electrostatic precipitators, and SO{sub 2} control with a wet scrubber. The test was conducted September 3--6, 1993. Sixteen trace metals were determined along with 5 major metals. Other inorganic substances and organic compounds were also determined.

  19. Coal, energy of the future

    International Nuclear Information System (INIS)

    Lepetit, V.; Guezel, J.Ch.

    2006-01-01

    Coal is no longer considered as a 'has been' energy source. The production and demand of coal is growing up everywhere in the world because it has some strategic and technological advantages with respect to other energy sources: cheap, abundant, available everywhere over the world, in particular in countries with no geopolitical problems, and it is independent of supplying infrastructures (pipelines, terminals). Its main drawback is its polluting impact (dusts, nitrogen and sulfur oxides, mercury and CO 2 ). The challenge is to develop clean and high efficiency coal technologies like supercritical steam power plants or combined cycle coal gasification plants with a 50% efficiency, and CO 2 capture and sequestration techniques (post-combustion, oxy-combustion, chemical loop, integrated gasification gas combined cycle (pre-combustion)). Germany, who will abandon nuclear energy by 2021, is massively investing in the construction of high efficiency coal- and lignite-fired power plants with pollution control systems (denitrification and desulfurization processes, dust precipitators). (J.S.)

  20. Coal log pipeline research at the University of Missouri. 1st Quarterly report for 1995, January 1, 1995--March 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Liu, H.

    1995-08-01

    Work continued on the study of coal log pipeline research. Individual projects described include fast compaction of coal logs; effect of cooling on coal log quality; coal log capping; effectiveness of adding fiber to enhance coal log quality; fabrication using hydrophobic binders; cost estimation of different lubricants; automatic control of coal log pipeline system; CLP design; coal log train transport; economics of coal log pipeline; legal aspects; heating, cooling, and drying of logs; vacuum systems to enhance production; design; and effect of piston modification on capping.

  1. Study of coal flash hydropyrolysis denitrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Tang, Lihua; Zhu, Zibin; Zhu, Hongbin; Zhang, Chengfang [Research Institute of Inorganic Chemical Technology, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237 (China)

    2003-05-15

    The hydrodenitrogenation efficiency of 14 types of coals and the reaction mechanism of Zalainouer coal were studied in an experimental entrained bed reactor by flash hydropyrolysis (FHP). The results showed that flash hydropyrolysis is an efficient method for denitrogenation, and that the denitrogenation percentage increases with an increase in temperature and hydrogen pressure. For example, the denitrogenation percentage can reach up to about 60% for Zalainouer coal at 700 C and 6.0 MPa hydrogen pressure. The denitrogenation efficiency of different coal types is related to H/C. According to the conclusion of the study, the denitrogenation percentage increases with the increase in H/C ratio, reaching about 12% when H/C is equal to 0.6, and 40-55% when H/C is above 1.0. The results indicate that FHP is an efficient technique for removing nitrogen in coal.

  2. Characterizing Microbial Mat Morphology with Structure from Motion Techniques in Ice-Covered Lake Joyce, McMurdo Dry Valleys, Antarctica

    Science.gov (United States)

    Mackey, T. J.; Leidman, S. Z.; Allen, B.; Hawes, I.; Lawrence, J.; Jungblut, A. D.; Krusor, M.; Coleman, L.; Sumner, D. Y.

    2015-12-01

    Structure from Motion (SFM) techniques can provide quantitative morphological documentation of otherwise inaccessible benthic ecosystems such as microbial mats in Lake Joyce, a perennially ice-covered lake of the Antarctic McMurdo Dry Valleys (MDV). Microbial mats are a key ecosystem of MDV lakes, and diverse mat morphologies like pinnacles emerge from interactions among microbial behavior, mineralization, and environmental conditions. Environmental gradients can be isolated to test mat growth models, but assessment of mat morphology along these gradients is complicated by their inaccessibility: the Lake Joyce ice cover is 4-5 m thick, water depths containing diverse pinnacle morphologies are 9-14 m, and relevant mat features are cm-scale. In order to map mat pinnacle morphology in different sedimentary settings, we deployed drop cameras (SeaViewer and GoPro) through 29 GPS referenced drill holes clustered into six stations along a transect spanning 880 m. Once under the ice cover, a boom containing a second GoPro camera was unfurled and rotated to collect oblique images of the benthic mats within dm of the mat-water interface. This setup allowed imaging from all sides over a ~1.5 m diameter area of the lake bottom. Underwater lens parameters were determined for each camera in Agisoft Lens; images were reconstructed and oriented in space with the SFM software Agisoft Photoscan, using the drop camera axis of rotation as up. The reconstructions were compared to downward facing images to assess accuracy, and similar images of an object with known geometry provided a test for expected error in reconstructions. Downward facing images identify decreasing pinnacle abundance in higher sedimentation settings, and quantitative measurements of 3D reconstructions in KeckCAVES LidarViewer supplement these mat morphological facies with measurements of pinnacle height and orientation. Reconstructions also help isolate confounding variables for mat facies trends with measurements

  3. Coal information 1996

    International Nuclear Information System (INIS)

    1997-01-01

    Coal Information (1997 edition) is the latest edition of a publication that has been produced annually by the IEA since 1983. The report is intended to provide both Member countries of the OECD and those employed in all sectors of the coal industry with information on current world coal market trends and long-term prospects. It includes information on coal prices, demand, trade, supply, production capacity, transport, environmental issues (including emission standards for coal-fired boilers), coal ports, coal-fired power stations and coal used in non -OECD countries. Part I of the publication contains a wide ranging review of world coal market developments in 1996 and current prospects to 2010. The review is based on historical data of OECD energy supply and demand, data on other world regions, projections of OECD coal supply, demand and trade and information provided by the CIAB. Part II provides, in tabular and graphical form, a more detailed and comprehensive statistical picture of coal developments and future prospects for coal in the OECD, by region and for individual Member countries. Readers interested in projections are strongly advised to read the notes for individual countries in Principles and Definitions in Part II. Coal statistics for non-OECD countries are presented in Part III of the book. Summary data are available on hard coal supply and end-use statistics for about 40 countries and regions world-wide. Data are based on official national submissions to the United Nations in Geneva and New York, national energy publications, information provided to the IEA Secretariat by national statistical offices as well as other unofficial Secretariat sources. Further information on coal used in non-OECD countries is published annually by the IEA in Energy Statistics and Balances of Non-OECD Countries. Also included in Part III are the Survey of Coal Ports world-wide and the Survey of Coal-fired Power Stations in coal-importing countries

  4. Coal and clean coal technology: challenges and opportunities

    Energy Technology Data Exchange (ETDEWEB)

    Minchener, Andrew [IEA Clean Coal Centre, London (United Kingdom)

    2013-07-01

    Globally, there is a growing concern about fuel diversity and security of supply, particularly with regard to oil and natural gas. In contrast, coal is available from a much wider range of sources and has greater price stability. Consequently, coal use is increasing rapidly, and by 2030 may well reach a level of more than 4,500 Mtoe, corresponding to close to a doubling of current levels. However, at the same time, tightening regulations will require better solutions for achieving environmental compliance, for which coal has a number of key issues to address. Most of the coal will be used in the power generation sector. Consequently, the key research challenges are to develop and deploy methods by which coal can be used cleanly, efficiently, and in a sustainable way. These include improvements to existing coal utilisation technologies, particularly to improve operational flexibility and availability, while reducing energy use through higher efficiencies. There is an increasing need to ensure improved emissions control, with the emphasis on achieving ever-lower emissions of particulates, SO{sub 2} and NO{sub x} while also introducing control of trace species, particularly mercury. Alongside this, a key challenge is the integration of techniques that can capture CO{sub 2} then transport and store it within secure geological formations, thereby resulting in near zero emissions of CO{sub 2}. From a power plant perspective, the need is to achieve such integration while minimising any adverse impact on power plant efficiency, performance of existing emissions control systems, operational flexibility and availability. At the same time, means to minimize the additional costs associated with such technology must be established.

  5. Change in surface characteristics of coal in upgrading of low-rank coals; Teihin`itan kaishitsu process ni okeru sekitan hyomen seijo no henka

    Energy Technology Data Exchange (ETDEWEB)

    Oki, A.; Xie, X.; Nakajima, T.; Maeda, S. [Kagoshima University, Kagoshima (Japan). Faculty of Engineering

    1996-10-28

    With an objective to learn mechanisms in low-rank coal reformation processes, change of properties on coal surface was discussed. Difficulty in handling low-rank coal is attributed to large intrinsic water content. Since it contains highly volatile components, it has a danger of spontaneous ignition. The hot water drying (HWD) method was used for reformation. Coal which has been dry-pulverized to a grain size of 1 mm or smaller was mixed with water to make slurry, heated in an autoclave, cooled, filtered, and dried in vacuum. The HWD applied to Loy Yang and Yallourn coals resulted in rapid rise in pressure starting from about 250{degree}C. Water content (ANA value) absorbed into the coal has decreased largely, with the surface made hydrophobic effectively due to high temperature and pressure. Hydroxyl group and carbonyl group contents in the coal have decreased largely with rising reformation treatment temperature (according to FT-IR measurement). Specific surface area of the original coal of the Loy Yang coal was 138 m{sup 2}/g, while it has decreased largely to 73 m{sup 2}/g when the reformation temperature was raised to 350{degree}C. This is because of volatile components dissolving from the coal as tar and blocking the surface pores. 2 refs., 4 figs.

  6. Trends in Japanese coal trade

    Energy Technology Data Exchange (ETDEWEB)

    Nakajima, S

    1986-01-01

    The author discusses 1) the latest forecast for coal demand in Japan; 2) trends in Japanese steam coal demand, with breakdown by industry; 3) the organization of steam coal supply, with details of the distribution network and of the new coal cartridge system; 4) the demand for metallurgical coal. Other topics outlined include the current status of Japanese coal production, Japanese coal trade, and the development of overseas coal resources. 1 figure, 5 tables.

  7. Development of world coal reserves, their registration and their utilization

    Energy Technology Data Exchange (ETDEWEB)

    Bachmann, H

    1979-10-01

    This paper examines statistics on world coal production and world coal reserves with figures from 1860 to 1974 provided in tables and graphs. Eighty percent of the total world coal reserves (92% of world brown coal reserves) lie in the USA and USSR. The recent increase in total coal reserve estimates is due to exploration in western USA and in the USSR east of the Urals. Depth and thickness of the world's coal seams are shown in graphs and variations in coal quality are discussed. Problems associated with the anticipated substantial increase in coal production up to the year 2000 are considered. Encouraging higher coal production is the successful development of highly mechanized underground mining techniques and highly productive heavy surface mining equipment which allows excavation at increased depths. Surface mining is expected to make up 50% of total world mining operations in the near future. More complete deposit exploitation also contributes to higher coal production. Low international ship freight rates would facilitate future world coal trade. Obstacles are seen as: high, long term investments due to the fact that coal reserves lie far from populated and industrialized areas; opening new mines; transportation costs and infrastructure development.

  8. Japan`s sunshine project. 17.. 1992 annual summary of coal liquefaction and gasification

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    This report describes the achievement of coal liquefaction and gasification technology development in the Sunshine Project for FY 1992. It presents the research and development of coal liquefaction which includes studies on reaction mechanism of coal liquefaction and catalysts for coal liquefaction, the research and development of coal gasification technologies which includes studies on gasification characteristics of various coals and improvement of coal gasification efficiency, the development of bituminous coal liquefaction which includes engineering, construction and operation of a bituminous coal liquefaction pilot plant and research by a process supporting unit (PSU), the development of brown coal liquefaction which includes research on brown coal liquefaction with a pilot plant and development of techniques for upgrading coal oil from brown coal, the development of common base technologies which includes development of slurry letdown valves and study on upgrading technology of coal-derived distillates, the development of coal-based hydrogen production technology with a pilot plant, the development of technology for entrained flow coal gasification, the assessment of coal hydrogasification, and the international co-operation. 4 refs., 125 figs., 39 tabs.

  9. Preparation and combustion of coal-water fuel from the Sin Pun coal deposit, southern Thailand

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    In response to an inquiry by the Department of Mineral Resources in Thailand, the Energy & Environmental Research Center (EERC) prepared a program to assess the responsiveness of Sin Pun lignite to the temperature and pressure conditions of hot-water drying. The results indicate that drying made several improvements in the coal, notably increases in heating value and carbon content and reductions in equilibrium moisture and oxygen content. The equilibrium moisture content decreased from 27 wt% for the raw coal to about 15 wt% for the hot-water-dried (HWD) coals. The energy density for a pumpable coal-water fuel (CWF) indicates an increase from 4500 to 6100 Btu/lb by hot-water drying. Approximately 650 lb of HWD Sin Pun CWF were fired in the EERC`s combustion test facility. The fuel burned extremely well, with no feed problems noted during the course of the test. Fouling and slagging deposits each indicated a very low rate of ash deposition, with only a dusty layer formed on the cooled metal surfaces. The combustor was operated at between 20% and 25% excess air, resulting in a flue gas SO{sub 2} concentration averaging approximately 6500 parts per million.

  10. Upgrading and efficiency improvement in coal-fired power plants

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-08-01

    Improving the efficiencies of the large number of older coal-fired power plants operating around the world would give major savings in CO2 emissions together with significant other benefits. This report begins with a summary of the ways efficiency can become degraded and of the means available to combat the decrease in performance. These include improvements to operating and maintenance practices and more major techniques that are available, including boiler and turbine retrofits. There is also an update on fuel drying developments as a route to higher efficiency in plants firing high moisture lignites. The largest chapter of the report contains a number of descriptions of case study improvement projects, to illustrate measures that have been applied, benefits that have been achieved and identify best practices, which are summarised. Major national and international upgrading programmes are described.

  11. Development of Biomimetic Hybrid Porous Scaffold of Chitosan/Polyvinyl Alcohol/Carboxymethyl Cellulose by Freeze-Dried and Salt Leached Technique.

    Science.gov (United States)

    Kanimozhi, K; Basha, S Khaleel; Kumari, V Sugantha; Kaviyarasu, K

    2018-07-01

    Freeze drying and salt leaching methods were applied to fabricate Chitosan/Poly(vinyl alcohol)/Carboxymethyl cellulose (CPCMC) biomimetic porous scaffolds for soft tissue engineering. The properties of these scaffolds were investigated and compared to those by freeze drying and salt leaching methods respectively. The salt-leached CS/PVA/CMC scaffolds were easily formed into desired shapes with a uniformly distributed and interconnected pore structure with an average pore size. The mechanical strength of the scaffolds increased with the porosity, and were easily modulated by the addition of carboxymethyl cellulose. The morphology of the porous scaffolds observed using a SEM exhibited good porosity and interconnectivity of pores. MTT assay using L929 fibroblast cells demonstrated that the cell viability of the porous scaffold was good. Scaffolds prepared by salt leached method show larger swelling capacity, and mechanical strength, potent antibacterial activity and more cell viability than freeze dried method. It is found that salt leaching method has distinguished characteristics of simple, efficient, feasible and less economic than freeze dried scaffolds.

  12. Nitrogen in Chinese coals

    Science.gov (United States)

    Wu, D.; Lei, J.; Zheng, B.; Tang, X.; Wang, M.; Hu, Jiawen; Li, S.; Wang, B.; Finkelman, R.B.

    2011-01-01

    Three hundred and six coal samples were taken from main coal mines of twenty-six provinces, autonomous regions, and municipalities in China, according to the resource distribution and coal-forming periods as well as the coal ranks and coal yields. Nitrogen was determined by using the Kjeldahl method at U. S. Geological Survey (USGS), which exhibit a normal frequency distribution. The nitrogen contents of over 90% Chinese coal vary from 0.52% to 1.41% and the average nitrogen content is recommended to be 0.98%. Nitrogen in coal exists primarily in organic form. There is a slight positive relationship between nitrogen content and coal ranking. ?? 2011 Science Press, Institute of Geochemistry, CAS and Springer Berlin Heidelberg.

  13. Coal marketing manual 1986

    Energy Technology Data Exchange (ETDEWEB)

    1986-01-01

    This manual presents information for the use of marketers, consumers, analysts and investors. The information is presented in a series of tables and figures. Statistics are given for: Australian export tonnages and average export values for 1978-1985; international pig iron production 1976 to 1985; and international crude steel production 1979 to 1985. Trends in Australian export tonnages and prices of coal are reviewed. Details of international loading and discharge ports are given, together with a historical summary of shipping freight-rates since 1982. Long term contract prices for thermal and coking coal to Japan are tabulated. A review of coal and standards is given, together with Australian standards for coal and coke. A section on coal quality is included containing information on consumer coal quality preferences and Australian and Overseas coal brands and qualities. Finally an index is given of contact details of Australian and Overseas exporting companies, government departments, and the Australian Coal Association.

  14. Coal worker's pneumoconiosis

    Science.gov (United States)

    ... this page: //medlineplus.gov/ency/article/000130.htm Coal worker's pneumoconiosis To use the sharing features on this page, please enable JavaScript. Coal worker's pneumoconiosis (CWP) is a lung disease that ...

  15. Analytical methods relating to mineral matter in coal and ash from coal combustion

    Energy Technology Data Exchange (ETDEWEB)

    Creelman, R.A. [Ultra-Systems Technology Pty. Ltd., Indooroopilly, Qld. (Australia)

    2002-07-01

    The paper begins by describing the minerals that occur in coal, as well as trace elements. The testing methods that are then described include those that are in the main the standard tools for the examination and assessment of minerals in coal and ash. The techniques discussed include optical and beam techniques, X-ray methods and a variety of other useful methods. 12 refs.

  16. Coal facies evolution of the main minable coal-bed in the Heidaigou Mine, Jungar Coalfield, Inner Mongolia, northern China

    Energy Technology Data Exchange (ETDEWEB)

    Dai, S.F.; Ren, D.Y.; Li, S.S.; Zhao, L.; Zhang, Y. [China University of Mining & Technology, Beijing (China)

    2007-11-15

    The No. 6 Coal-bed from the Heidaigou Mine, Jungar Coalfield, Inner Mongolia is a super-large Ga deposit. The dominant carrier of Ga is boehmite in coal. The study of coal facies may provide genetic enrichment information of Ga and its carrier (boehmite) in the Ga deposit. On the basis of study on coal petrology and mineralogy, it was found that the No. 6 Coal-bed from the Heidaigou Mine of Jungar was enriched in inertinites and the microlithotypes were dominated by clarodurite. The maceral morphological features and association indicate that the coal-bed was formed in a dry sedimentary environment or in a periodic dry sedimentary environment caused by the alternating variations of groundwater level. The optimum conditions for the enrichment of Ga and its particular carrier (boehmite) were dominated by four transitional conditions: (1) the upper delta plain which was the transitional zone between alluvial and lower delta plains, (2) the transitional zone between the dry and wet forest swamps, being slightly apt to the dry one, (3) the transitional tree density between the thick and loose ones, and (4) the low moor that was the transitional zone between two high moors during peat accumulation.

  17. Coal mine subsidence

    International Nuclear Information System (INIS)

    Darmody, R.G.; Hetzler, R.T.; Simmons, F.W.

    1992-01-01

    Longwall coal mining in southern Illinois occurs beneath some of the best agricultural land in the U.S. This region is characterized by highly productive, nearly level, and somewhat poorly drained soils. Subsidence from longwall mining causes changes in surface topography which alters surface and subsurface hydrology. These changes can adversely affect agricultural land by creating wet or ponded areas that can be deleterious to crop production. While most subsided areas show little impact from subsidence, some areas experience total crop failure. Coal companies are required by law to mitigate subsidence damage to cropland. The objective of this paper is to test the effectiveness of mitigation in restoring grain yields to their pre-mined levels. The research was conducted on sites selected to represent conventional mitigation techniques on the predominate soils in the area. Corn (Zea mays L.) and soybean [Glycine max.(L.) Merr] yields in 1988, 1989, 1990, and 1991 from mitigated areas were compared to yields from nearby undisturbed areas

  18. Fording Canadian Coal Trust

    Energy Technology Data Exchange (ETDEWEB)

    Popowich, J.; Millos, R. [Elk Valley Coal Corporation, Calgary, AB (Canada)

    2004-07-01

    This is the first of five slide/overhead presentations presented at the Fording Canadian Coal Trust and Tech Cominco Ltd. investor day and mine tour. The Fording Canadian Coal Trust is described. The Trust's assets comprise six Elk Valley metallurgical coal mines and six wollastonite operations (in the NYCO Group). Trust structure, corporate responsibility, organizational structure, reserves and resources, management philosophy, operating strategies, steel market dynamics, coal market, production expansion, sales and distribution are outlined. 15 figs., 5 tabs.

  19. Coal. [1987 and 1989

    Energy Technology Data Exchange (ETDEWEB)

    1988-06-01

    Despite increases in recently negotiated coal prices in US dollar terms, unit export returns for Australian coal are expected to rise only marginally in 1988-89 due to the anticipated appreciation of the Australian dollar. Australian coal production is expected to recover in 1988-89, after falling in 1987-88. A table summarising coal statistics in 1985-87 is presented. 2 figs., 1 tab.

  20. Review biodepyritisation of coal

    Energy Technology Data Exchange (ETDEWEB)

    Acharya, C.; Sukla, L.B.; Misra, V.N. [Regional Research Lab., Orissa (India)

    2004-01-01

    This review provides a detailed summary of the recent and past research activities in the area of biodesulfurisation of coal. It provides information about microorganisms important for biodesulfurisation of coal, with the emphasis on Thiobacillus ferrooxidans. The review presents an insight into various methods of desulfurisation of coal combining physical and biological methods. Also, there are discussions on coal structure, distribution, mechanism and kinetics of pyrite oxidation and jarosite precipitation. Finally, areas requiring further research are identified.

  1. Coal world market

    International Nuclear Information System (INIS)

    Anon.

    1996-01-01

    A brief analysis of major tendencies in the world market of coal is presented. It is pointed out that recent years, by and large, were favourable for the development of the world coal industry. Prices for coal (both for power-grade and coking one) in 1995 after many years of depressive state increased by nearly 20 % and reached a maximum of the last decade. International coal trading continues to grow and the tendency may persist in the mext two years

  2. Dry cell battery poisoning

    Science.gov (United States)

    Batteries - dry cell ... Acidic dry cell batteries contain: Manganese dioxide Ammonium chloride Alkaline dry cell batteries contain: Sodium hydroxide Potassium hydroxide Lithium dioxide dry cell batteries ...

  3. Hard coal; Steinkohle

    Energy Technology Data Exchange (ETDEWEB)

    Loo, Kai van de; Sitte, Andreas-Peter [Gesamtverband Steinkohle e.V., Herne (Germany)

    2013-04-01

    The year 2012 benefited from a growth of the consumption of hard coal at the national level as well as at the international level. Worldwide, the hard coal still is the number one energy source for power generation. This leads to an increasing demand for power plant coal. In this year, the conversion of hard coal into electricity also increases in this year. In contrast to this, the demand for coking coal as well as for coke of the steel industry is still declining depending on the market conditions. The enhanced utilization of coal for the domestic power generation is due to the reduction of the nuclear power from a relatively bad year for wind power as well as reduced import prices and low CO{sub 2} prices. Both justify a significant price advantage for coal in comparison to the utilisation of natural gas in power plants. This was mainly due to the price erosion of the inexpensive US coal which partly was replaced by the expansion of shale gas on the domestic market. As a result of this, the inexpensive US coal looked for an outlet for sales in Europe. The domestic hard coal has continued the process of adaptation and phase-out as scheduled. Two further hard coal mines were decommissioned in the year 2012. RAG Aktiengesellschaft (Herne, Federal Republic of Germany) running the hard coal mining in this country begins with the preparations for the activities after the time of mining.

  4. Coal economics and taxation

    Energy Technology Data Exchange (ETDEWEB)

    1978-01-01

    These proceedings contain opening remarks, the luncheon and dinner addresses, list of delegates and the papers presented at the four sessions on Coal Mines cost money - for what.; Coal mines cost money - Where the money comes from; taxation and royalty policies; and the coal industry view on operating costs. Sixteen papers are abstracted separately.

  5. Australian Coal Company Risk Factors: Coal and Oil Prices

    OpenAIRE

    M. Zahid Hasan; Ronald A. Ratti

    2014-01-01

    Examination of panel data on listed coal companies on the Australian exchange over January 1999 to February 2010 suggests that market return, interest rate premium, foreign exchange rate risk, and coal price returns are statistically significant in determining the excess return on coal companies’ stock. Coal price return and oil price return increases have statistically significant positive effects on coal company stock returns. A one per cent rise in coal price raises coal company returns ...

  6. Dynamic measurement of coal thermal properties and elemental composition of volatile matter during coal pyrolysis

    Directory of Open Access Journals (Sweden)

    Rohan Stanger

    2014-01-01

    Full Text Available A new technique that allows dynamic measurement of thermal properties, expansion and the elemental chemistry of the volatile matter being evolved as coal is pyrolysed is described. The thermal and other properties are measured dynamically as a function of temperature of the coal without the need for equilibration at temperature. In particular, the technique allows for continuous elemental characterisation of tars as they are evolved during pyrolysis and afterwards as a function of boiling point. The technique is demonstrated by measuring the properties of maceral concentrates from a coal. The variation in heats of reaction, thermal conductivity and expansion as a function of maceral composition is described. Combined with the elemental analysis, the results aid in the interpretation of the chemical processes contributing to the physical and thermal behaviour of the coal during pyrolysis. Potential applications in cokemaking studies are discussed.

  7. Coal Data: A reference

    International Nuclear Information System (INIS)

    1991-01-01

    The purpose of Coal Data: A Reference is to provide basic information on the mining and use of coal, an important source of energy in the United States. The report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ''Coal Terminology and Related Information'' provides additional information about terms mentioned in the text and introduces new terms. Topics covered are US coal deposits, resources and reserves, mining, production, employment and productivity, health and safety, preparation, transportation, supply and stocks, use, coal, the environment, and more. (VC)

  8. The NOXSO clean coal project

    Energy Technology Data Exchange (ETDEWEB)

    Black, J.B.; Woods, M.C.; Friedrich, J.J.; Browning, J.P. [NOXSO Corp., Bethel Park, PA (United States)

    1997-12-31

    The NOXSO Clean Coal Project will consist of designing, constructing, and operating a commercial-scale flue-gas cleanup system utilizing the NOXSO Process. The process is a waste-free, dry, post-combustion flue-gas treatment technology which uses a regenerable sorbent to simultaneously adsorb sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) from flue gas from coal-fired boilers. The NOXSO plant will be constructed at Alcoa Generating Corporation`s (AGC) Warrick Power Plant near Evansville, Indiana and will treat all the flue gas from the 150-MW Unit 2 boiler. The NOXSO plant is being designed to remove 98% of the SO{sub 2} and 75% of the NO{sub x} when the boiler is fired with 3.4 weight percent sulfur, southern-Indiana coal. The NOXSO plant by-product will be elemental sulfur. The elemental sulfur will be shipped to Olin Corporation`s Charleston, Tennessee facility for additional processing. As part of the project, a liquid SO{sub 2} plant has been constructed at this facility to convert the sulfur into liquid SO{sub 2}. The project utilizes a unique burn-in-oxygen process in which the elemental sulfur is oxidized to SO{sub 2} in a stream of compressed oxygen. The SO{sub 2} vapor will then be cooled and condensed. The burn-in-oxygen process is simpler and more environmentally friendly than conventional technologies. The liquid SO{sub 2} plant produces 99.99% pure SO{sub 2} for use at Olin`s facilities. The $82.8 million project is co-funded by the US Department of Energy (DOE) under Round III of the Clean Coal Technology program. The DOE manages the project through the Pittsburgh Energy Technology Center (PETC).

  9. Sahara Coal: the fine art of collecting fines for profit

    Energy Technology Data Exchange (ETDEWEB)

    Schreckengost, D.; Arnold, D.

    1984-09-01

    Because of a change in underground mining methods that caused a considerable increase in the amount of fine sizes in the raw coal, Sahara Coal Co. designed and constructed a unique and simple fine coal system at their Harrisburg, IL prep plant. Before the new system was built, the overload of the fine coal circuit created a cost crunch due to loss of salable coal to slurry ponds, slurry pond cleaning costs, and operating and maintenance costs--each and every one excessive. Motivated by these problems, Sahara designed a prototype system to dewater the minus 28 mesh refuse. The success of the idea permitted fine refuse to be loaded onto the coarse refuse belt. Sahara also realized a large reduction in pond cleaning costs. After a period of testing, an expanded version of the refuse system was installed to dewater and dry the 28 mesh X 0 clean coal. Clean coal output increased about 30 tph. Cost savings justified the expenditures for the refuse and clean coal systems. These benefits, combined with increased coal sales revenue, paid back the project costs in less than a year.

  10. Advanced physical fine coal cleaning spherical agglomeration. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1990-09-01

    The project included process development, engineering, construction, and operation of a 1/3 tph proof-of-concept (POC) spherical agglomeration test module. The POC tests demonstrated that physical cleaning of ultrafine coal by agglomeration using heptane can achieve: (1) Pyritic sulfur reductions beyond that possible with conventional coal cleaning methods; (2) coal ash contents below those which can be obtained by conventional coal cleaning methods at comparable energy recoveries; (3) energy recoveries of 80 percent or greater measured against the raw coal energy content; (4) complete recovery of the heptane bridging liquid from the agglomerates; and (5) production of agglomerates with 3/8-inch size and less than 30 percent moisture. Test results met or exceeded all of the program objectives. Nominal 3/8-inch size agglomerates with less than 20 percent moisture were produced. The clean coal ash content varied between 1.5 to 5.5 percent by weight (dry basis) depending on feed coal type. Ash reductions of the run-of-mine (ROM) coal were 77 to 83 percent. ROM pyritic sulfur reductions varied from 86 to 90 percent for the three test coals, equating to total sulfur reductions of 47 to 72 percent.

  11. FY 1980 Report on results of Sunshine Project. Development of coal liquefaction techniques (Development of 1 T/D test plant, and researches on the solvent-extraction type liquefaction process); 1980 nendo sekitan ekika gijutsu no kaihatsu, yozai chushutsu ekika plant no kaihatsu seika hokokusho. 1t/nichi jikken plant no kaihatsu, yozai chushutsu ekika process no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    This program is aimed at establishing the techniques for solvent-extraction type coal liquefaction plant by constructing and operating a 1 T/D test plant to obtain the technical data for the efficient plant. The test plant is operated to confirm the effects of temperature and coal slurry concentration on liquefaction conversion by the solvent-extraction for a short time in the furnace for the extraction unit. The extraction type coal liquefaction tests can be conducted for a reaction time of around 1 hour by the test plant. The recycled solvent purification unit is installed, to regenerate the hydrogen donor solvent. For researches on the solvent-extraction type coal liquefaction process, the continuous extraction is conducted, to investigate the effects of extraction reaction rate at relatively low pressure. The optimum hydrogenation conditions are studied for the test plant. It is confirmed that a Mo-based catalyst is suitable for the hydrogenation. The batch type reaction system is operated to investigate the liquid yield of Wandoan coal, and recycled solvent balances and compositions. (NEDO)

  12. Dry storage

    International Nuclear Information System (INIS)

    Arnott, Don.

    1985-01-01

    The environmental movement has consistently argued against disposal of nuclear waste. Reasons include its irretrievability in the event of leakage, the implication that reprocessing will continue and the legitimacy attached to an expanding nuclear programme. But there is an alternative. The author here sets out the background and a possible future direction of a campaign based on a call for dry storage. (author)

  13. Analysis of mineral phases in coal utilizing factor analysis

    International Nuclear Information System (INIS)

    Roscoe, B.A.; Hopke, P.K.

    1982-01-01

    The mineral phase inclusions of coal are discussed. The contribution of these to a coal sample are determined utilizing several techniques. Neutron activation analysis in conjunction with coal washability studies have produced some information on the general trends of elemental variation in the mineral phases. These results have been enhanced by the use of various statistical techniques. The target transformation factor analysis is specifically discussed and shown to be able to produce elemental profiles of the mineral phases in coal. A data set consisting of physically fractionated coal samples was generated. These samples were analyzed by neutron activation analysis and then their elemental concentrations examined using TTFA. Information concerning the mineral phases in coal can thus be acquired from factor analysis even with limited data. Additional data may permit the resolution of additional mineral phases as well as refinement of theose already identified

  14. Coal and public perceptions

    International Nuclear Information System (INIS)

    Porter, R.C.

    1993-01-01

    The Department of Energy's (DOE) clean coal outreach efforts are described. The reason why clean coal technology outreach must be an integral part of coal's future is discussed. It is important that we understand the significance of these advances in coal utilization not just in terms of of hardware but in terms of public perception. Four basic premises in the use of coal are presented. These are: (1) that coal is fundamentally important to this nation's future; (2) that, despite premise number 1, coal's future is by no means assured and that for the last 10 years, coal has been losing ground; (3) that coal's future hinges on the public understanding of the benefits of the public's acceptance of advanced clean coal technology; and (4) hat public acceptance of clean coal technology is not going to be achieved through a nationwide advertising program run by the Federal government or even by the private sector. It is going to be gained at the grassroots level one community at a time, one plant at a time, and one referendum at a time. The Federal government has neither the resources, the staff, nor the mandate to lead the charge in those debates. What is important is that the private sector step up to the plate as individual companies and an individual citizens working one-one-one at the community level, one customer, one civic club, and one town meeting at a time

  15. Indonesian coal export potential

    International Nuclear Information System (INIS)

    Millsteed, Ch.; Jolly, L.; Stuart, R.

    1993-01-01

    Indonesia's coal mining sector is expanding rapidly. Much of the increase in coal production since the mid-1980s has been exported. Indonesian coal mining companies have large expansion programs and continuing strong export growth is projected for the remainder of the 1990s. The low mining costs of indonesian coal, together with proximity to Asian markets, mean that Indonesia is well placed to compete strongly with other thermal coal exporters and win market share in the large and expanding thermal coal market in Asia. However, there is significant uncertainty about the likely future level of Indonesia's exportable surplus of coal. The government's planned expansion in coal fired power generation could constrain export growth, while the ability of producers to meet projected output levels is uncertain. The purpose in this article is to review coal supply and demand developments in Indonesia and, taking account of the key determining factors, to estimate the level of coal exports from Indonesia to the year 2000. This time frame has been chosen because all currently committed mine developments are expected to be on stream by 2000 and because it is difficult to project domestic demand for coal beyond that year. 29 refs., 8 tabs., 7 figs

  16. Coal; Le charbon

    Energy Technology Data Exchange (ETDEWEB)

    Teissie, J.; Bourgogne, D. de; Bautin, F. [TotalFinaElf, La Defense, 92 - Courbevoie (France)

    2001-12-15

    Coal world production represents 3.5 billions of tons, plus 900 millions of tons of lignite. 50% of coal is used for power generation, 16% by steel making industry, 5% by cement plants, and 29% for space heating and by other industries like carbo-chemistry. Coal reserves are enormous, about 1000 billions of tons (i.e. 250 years of consumption with the present day rate) but their exploitation will be in competition with less costly and less polluting energy sources. This documents treats of all aspects of coal: origin, composition, calorific value, classification, resources, reserves, production, international trade, sectoral consumption, cost, retail price, safety aspects of coal mining, environmental impacts (solid and gaseous effluents), different technologies of coal-fired power plants and their relative efficiency, alternative solutions for the recovery of coal energy (fuel cells, liquefaction). (J.S.)

  17. Washability of Australian coals

    Energy Technology Data Exchange (ETDEWEB)

    Whitmore, R L

    1979-06-01

    Australian coals tend to be young in geological age and high in ash by world standards; preparation of the coal before marketing is almost universal. On the basis of float and sink data from 39 locations in the eastern Australian coalfields, the coals are place in four categories representing increasing difficulty in their washability characteristics. These seem to be related neither to the geological age nor the geographical position of the deposit and Hunter Valley coals, for example, span all categories. The influence of crushing on the washability of Australian coals is briefly considered and from limited data it is concluded to be appreciably smaller than for British or North American coals. A strategy for the float and sink analysis of Australian coals is proposed and the influence of washability characteristics on current trends in the selection of separating processes for coking and steaming products is discussed.

  18. Coal consumption and economic growth in China

    International Nuclear Information System (INIS)

    Li, Raymond; Leung, Guy C.K.

    2012-01-01

    The aim of this paper is to re-examine the relationship between coal consumption and real GDP of China with the use of panel data. This paper applies modern panel data techniques to help shed light on the importance of the heterogeneity among different regions within China. Empirical analyses are conducted for the full panel as well as three subgroups of the panel. The empirical results show that coal consumption and GDP are both I(1) and cointegrated in all regional groupings. Heterogeneity is found in the GDP equation of the full panel. The regional causality tests reveal that the coal consumption–GDP relationship is bidirectional in the Coastal and Central regions whereas causality is unidirectional from GDP to coal consumption in the Western region. Thus, energy conservation measures will not adversely affect the economic growth of the Western region but such measures will likely encumber the economy of the Coastal and Central regions, where most of the coal intensive industries are concentrated. - Highlights: ► We investigate the relationship between coal consumption and GDP in China. ► Panel data are used to account for the potential heterogeneity across different regions. ► Bidirectional causality is found in the Eastern and Central regions. ► Unidirectional causality from GDP to coal consumption is found in the Western region.

  19. Characterising the combustion behaviour of New Zealand coals by thermogravimetry

    Energy Technology Data Exchange (ETDEWEB)

    Benfell, K.E.; Beamish, B.B.; Rodgers, K.A. [University of Auckland, Auckland (New Zealand). Dept. of Geology

    1995-12-31

    Thirty-three New Zealand coals were subjected to thermogravimetric analysis (TG) and derivative thermogravimetric analysis (DTG) to evaluate the techniques` applicability to New Zealand coals. Generally, New Zealand sub-bituminous coals have lower burnout temperatures than bituminous coals. However, local and regional differences occur, where some sub-bituminous coals show both higher and lower char burnout temperatures than may be otherwise expected from their rank and T{sub 6} values (the peak temperature where the rate of weight loss of the sample is the greatest). There is a sizeable variations in the char burnout temperature (T{sub 8}) (465 to 636{degree}C) in coals with volatile matter contents above 40%, whereas coals with lower volatile contents have T{sub 8} values around 646{degree}C. The temperature of char burnout gives a better indication of combustion efficiency than rank or volatile matter content alone. Industrial operators could use this technique to provide an indication of burnout performance before a coal is purchased, assisting evaluation of the coal`s suitability for a particular usage. 10 refs., 4 figs., 3 tabs.

  20. Process for hydrogenating coal and coal solvents

    Energy Technology Data Exchange (ETDEWEB)

    Shridharani, K.G.; Tarrer, A.R.

    1983-02-15

    A novel process is described for the hydrogenation of coal by the hydrogenation of a solvent for the coal in which the hydrogenation of the coal solvent is conducted in the presence of a solvent hydrogenation catalyst of increased activity, wherein the hydrogenation catalyst is produced by reacting ferric oxide with hydrogen sulfide at a temperature range of 260/sup 0/ C to 315/sup 0/ C in an inert atmosphere to produce an iron sulfide hydrogenation catalyst for the solvent. Optimally, the reaction temperature is 275/sup 0/ C. Alternately, the reaction can be conducted in a hydrogen atmosphere at 350/sup 0/ C.

  1. Process for hydrogenating coal and coal solvents

    Science.gov (United States)

    Tarrer, Arthur R.; Shridharani, Ketan G.

    1983-01-01

    A novel process is described for the hydrogenation of coal by the hydrogenation of a solvent for the coal in which the hydrogenation of the coal solvent is conducted in the presence of a solvent hydrogenation catalyst of increased activity, wherein the hydrogenation catalyst is produced by reacting ferric oxide with hydrogen sulfide at a temperature range of 260.degree. C. to 315.degree. C. in an inert atmosphere to produce an iron sulfide hydrogenation catalyst for the solvent. Optimally, the reaction temperature is 275.degree. C. Alternately, the reaction can be conducted in a hydrogen atmosphere at 350.degree. C.

  2. Coal use and coal technology study (KIS)

    International Nuclear Information System (INIS)

    Kram, T.; Okken, P.A.; Gerbers, D.; Lako, P.; Rouw, M.; Tiemersma, D.N.

    1991-11-01

    The title study aims to assess the possible role for coal in the Netherlands energy system in the first decades of the next century and the part new coal conversion technologies will play under various conditions. The conditions considered relate to (sectoral) energy demand derived from national scenarios in an international context, to energy prices, to environmental constraints (acidification, solid waste management and disposal) and to the future role for nuclear power production. Targets for reduction of greenhouse gas emissions are not explicitly included, but resulting CO 2 emissions are calculated for each variant case. The part that coal can play in the Dutch energy supply is calculated and analyzed by means

  3. SELECTION OF SUSTAINABLE TECHNOLOGIES FOR COMBUSTION OF BOSNIAN COALS

    Directory of Open Access Journals (Sweden)

    Anes Kazagić

    2010-01-01

    Full Text Available This paper deals with optimization of coal combustion conditions to support selection a sustainable combustion technology and an optimal furnace and boiler design. A methodology for optimization of coal combustion conditions is proposed and demonstrated on the example of Bosnian coals. The properties of Bosnian coals vary widely from one coal basin to the next, even between coal mines within the same basin. Very high percentage of ash (particularly in Bosnian brown coal makes clear certain differences between Bosnian coal types and other world coal types, providing a strong argument for investigating specific problems related to the combustion of Bosnian coals, as well as ways to improve their combustion behaviour. In this work, options of the referent energy system (boiler with different process temperatures, corresponding to the different combustion technologies; pulverised fuel combustion (slag tap or dry bottom furnace and fluidized bed combustion, are under consideration for the coals tested. Sustainability assessment, based on calculation economic and environment indicators, in combination with common low cost planning method, is used for the optimization. The total costs in the lifetime are presented by General index of total costs, calculated on the base of agglomeration of basic economic indicators and the economic indicators derived from environmental indicators. So, proposed methodology is based on identification of those combustion technologies and combustion conditions for coals tested for which the total costs in lifetime of the system under consideration are lowest, provided that all environmental issues of the energy system is fulfilled during the lifetime. Inputs for calculation of the sustainability indicators are provided by the measurements on an experimental furnace with possibility of infinite variation of process temperature, supported by good praxis from the power plants which use the fuels tested and by thermal

  4. Dry matter production, seed yield and water use efficiency of some grain legumes grown under different water regimes using nuclear technique

    International Nuclear Information System (INIS)

    Harb, O.M.S.; Salem, M.S.A.; Abdalla, A.A.; Abd-Elwahed, N.M.

    2007-01-01

    Two field experiments were performed in the experimental farm at the Atomic Energy Authority, Inshas, Egypt, during 2002 and 2004 growing seasons to evaluate the responses of dry matter production, seed yield, water use efficiency and root characteristics for three legumes species, i.e. soybean (Glycine max cv. clark), cowpea (Vigna unguiculata cv. Kafr El-Sheikh) and mungbean (Vigna radiate cv. kawmy 1) grown on a new reclaimed sandy soil under different water regimes. The experiments were laid out using a single line source sprinkler irrigation system which allows a gradual variation of irrigation water, i.e. full irrigation (W1), medium water stress (W2) and severe water stress (W3). The obtained results indicated that normal irrigation (W1) gave the highest above ground dry matter production at flowering stage and total dry matter yield at maturity for the tested legumes. Water stress decreased significantly seed yields for all the tested legume seeds. The seed yield of normal watering condition treatment (W1) out yielded seed yield of those irrigated with medium water stress (W2) and severe water stress (W3). Mungbean and cowpea were more adapted to severe water stress than soybean. Most of the reduction in yield arose from a decrease in pod number. Pod number, number of seeds per pod and the thousand seed weight were significantly affected by water stress. The highest water use efficiency based on seed yield or dry matter yield were obtained by exposing the legume plants to medium water stress (W2), while the lowest value was obtained by exposing the plants to severe water stress (W3). There were significant differences in WUE among the tested species, whereas, mungbean showed the highest value in response to water stress, followed by soybean while cowpea showed the lowest value of water use efficiency. Rooting depth was increased under the severe water stress treatment as compared with well watered condition in the tested legume plants. Mungbean had the

  5. Low temperature distillation of coal, shale, etc

    Energy Technology Data Exchange (ETDEWEB)

    1938-08-12

    A process is disclosed for the low temperature distillation of solid carbonaceous fuels, such as coal, lignite, shale or the like, which comprises feeding or supplying the comminuted fuel in the form of a layer of shallow depth to drying and distilling zones in succession moving the fuel forward through the zones, submitting it to progressively increasing nonuniform heating therein by combustion gases supplied to the distillation zone and traveling thence to the drying zone, the gases heating the distillation zone indirectly and the drying zone both indirectly and then directly such that the fuel retains its solid discrete form during substantially the whole of its travel through the drying and distillation zones, subjecting the fuel for a portion of its travel to a zigzag ploughing and propelling movement on a heated sole, and increasing the heating so as to cause fusion of the fuel immediately prior to its discharge from the distillation zone.

  6. Thermogravimetric studies of New Zealand coals

    Energy Technology Data Exchange (ETDEWEB)

    Beamish, B.B.; Rodgers, K.A.; Benfell, K.E.; Shaw, K.J. [University of Auckland, Auckland (New Zealand). Dept. of Geology

    1997-12-31

    The thermal behaviour of New Zealand coals may be reliably characterised by a series of tightly constrained thermogravimetric (TG) procedures of high repeatability developed in the Department of Geology at The University of Auckland. Proximate, combustion and char reactivity analyses can be routinely obtained for run-of-mine samples. Volatile matter determination by TG produces an acceptable reproducible result compared with the ISO method, whereas further refinement of the technique is necessary to achieve the same level of precision for ash content of New Zealand low rank coals. Combining combustion and char reactivity analyses enables the performance of a coal to be assessed under differing operating conditions, and offers the opportunity to elucidate competing effects of major element geochemistry of the coal. 12 refs., 4 figs., 2 tabs.

  7. Spin-mapping of Coal Structures with ESE and ENDOR

    Science.gov (United States)

    Belford, R. L.; Clarkson, R. B.

    1989-12-01

    The broad goals of this project are to determine by nondestructive magnetic resonance methods chemical and physical structural characteristics of organic parts of native and treated coals. In this project period, we have begun to explore a technique which promises to enable us to follow to course of coal cleaning processes with microscopic spatial resolution. For the past five years, our laboratory has worked on extensions of the EPR technique as applied to coal to address these analytical problems. In this report we (1) describe the world's first nuclear magnetic resonance imaging results from an Illinois {number sign}6 coal and (2) transmit a manuscript describing how organic sulfur affect the very-high-frequency EPR spectra of coals. Magnetic resonance imaging (MRI) is a non-destructive technique that has found wide medical application as a means of visualizing the interior of human bodies. We have used MRI techniques to study the diffusion of an organic solvent (DMSO) into the pores of Illinois {number sign}6 coal. Proton MRI images reveal that this solvent at room temperature does not penetrate approximately 30% of the coal volume. Regions of the coal that exclude solvent could be related to inertinite and mineral components. A multi-technique imaging program is contemplated.

  8. Clean coal technologies

    International Nuclear Information System (INIS)

    Aslanyan, G.S.

    1993-01-01

    According to the World Energy Council (WEC), at the beginning of the next century three main energy sources - coal, nuclear power and oil will have equal share in the world's total energy supply. This forecast is also valid for the USSR which possesses more than 40% of the world's coal resources and continuously increases its coal production (more than 700 million tons of coal are processed annually in the USSR). The stringent environmental regulations, coupled with the tendency to increase the use of coal are the reasons for developing different concepts for clean coal utilization. In this paper, the potential efficiency and environmental performance of different clean coal production cycles are considered, including technologies for coal clean-up at the pre-combustion stage, advanced clean combustion methods and flue gas cleaning systems. Integrated systems, such as combined gas-steam cycle and the pressurized fluidized bed boiler combined cycle, are also discussed. The Soviet National R and D program is studying new methods for coal utilization with high environmental performance. In this context, some basic research activities in the field of clean coal technology in the USSR are considered. Development of an efficient vortex combustor, a pressurized fluidized bed gasifier, advanced gas cleaning methods based on E-beam irradiation and plasma discharge, as well as new catalytic system, are are presented. In addition, implementation of technological innovations for retrofitting and re powering of existing power plants is discussed. (author)

  9. Coal prices rise

    International Nuclear Information System (INIS)

    McLean, A.

    2001-01-01

    Coking and semi hard coking coal price agreements had been reached, but, strangely enough, the reaching of common ground on semi soft coking coal, ultra low volatile coal and thermal coal seemed some way off. More of this phenomenon later, but suffice to say that, traditionally, the semi soft and thermal coal prices have fallen into place as soon as the hard, or prime, coking coal prices have been determined. The rise and rise of the popularity of the ultra low volatile coals has seen demand for this type of coal grow almost exponentially. Perhaps one of the most interesting facets of the coking coal settlements announced to date is that the deals appear almost to have been preordained. The extraordinary thing is that the preordination has been at the prescience of the sellers. Traditionally, coking coal price fixing has been the prerogative of the Japanese Steel Mills (JSM) cartel (Nippon, NKK, Kawasaki, Kobe and Sumitomo) who presented a united front to a somewhat disorganised force of predominantly Australian and Canadian sellers. However, by the time JFY 2001 had come round, the rules of the game had changed

  10. Carbon-free hydrogen production from low rank coal

    Science.gov (United States)

    Aziz, Muhammad; Oda, Takuya; Kashiwagi, Takao

    2018-02-01

    Novel carbon-free integrated system of hydrogen production and storage from low rank coal is proposed and evaluated. To measure the optimum energy efficiency, two different systems employing different chemical looping technologies are modeled. The first integrated system consists of coal drying, gasification, syngas chemical looping, and hydrogenation. On the other hand, the second system combines coal drying, coal direct chemical looping, and hydrogenation. In addition, in order to cover the consumed electricity and recover the energy, combined cycle is adopted as addition module for power generation. The objective of the study is to find the best system having the highest performance in terms of total energy efficiency, including hydrogen production efficiency and power generation efficiency. To achieve a thorough energy/heat circulation throughout each module and the whole integrated system, enhanced process integration technology is employed. It basically incorporates two core basic technologies: exergy recovery and process integration. Several operating parameters including target moisture content in drying module, operating pressure in chemical looping module, are observed in terms of their influence to energy efficiency. From process modeling and calculation, two integrated systems can realize high total energy efficiency, higher than 60%. However, the system employing coal direct chemical looping represents higher energy efficiency, including hydrogen production and power generation, which is about 83%. In addition, optimum target moisture content in drying and operating pressure in chemical looping also have been defined.

  11. The effect of extrusion and drying on roller techniques concerning the rheological characteristics of rice-, corn-, sweet potato-, bean- and cassava root- and leaf- based composite flour

    Directory of Open Access Journals (Sweden)

    Johanna Aristizábal Galvis

    2013-01-01

    Full Text Available Promoting food security in Latin-America and the Caribbean is directly related to agricultural products. The region faces a food crisis which has reduced large population groups’ access to food. This work contributes to the study of obtaining precooked composite flour made from biofortified crops using protein, vitamin A and/or minerals. This study evaluated the effect of precooked flour’s composition and precooking on its solubility in water, water absorption capacity, consistency and viscosity; such flour was obtained by extrusion and drying on rollers. The composite flours were obtained from cassava roots, sweet potato tubers, corn, rice and bean grains and cassava leaves. Four composite flours were formulated taking four- to six-year-old children’s daily nutrient requirements (protein, iron, zinc and beta-carotenes as a basis. The extruder was operated at 90ºC, 300 rpm screw rotation speed, 17.64 g/min feed flow, with 30% moisture mixture. The dryer rollers were operated at 4 rpm roller rotation speed, 90ºC surface temperature and 1 mm separation between rollers. It was determined that flour dried on rollers led to more complete cooking and modified starch granule structure than precooking by extrusion, thereby producing flour having greater solubility in water, less water absorption, higher consistency and smaller viscosity, comparable to that of pattern flour.

  12. South Blackwater Coal`s maintenance program

    Energy Technology Data Exchange (ETDEWEB)

    Nash, J. [South Blackwater Coal Limited, Blackwater, Qld. (Australia)

    1998-09-01

    The South Blackwater operation consists of two opencut mining areas and two underground mines (Laleham and Kenmure) near Blackwater in central Queensland, all of which supply coal to a central coal preparation plant. South Blackwater Coal Ltd. recently developed a maintenance improvement programme, described in this article. The programme involved implementation systems of key performance indicators (KPIs), benchmaking, condition monitoring, work planning and control, failure analysis and maintenance audit. Some improvements became almost immediately apparent, others were quite gradual. Major results included: improved availability (and reliability) of all opencast fleets, improvements in rear dump availability; reduced maintenance man-hours for opencast fleets; and increased availability of the coal handling and preparation plant. The paper is an edited version of that presented at the `Maintenance in mining conference` 16-19 March 1998, held in Bali, Indonesia. 4 figs., 2 photos.

  13. Study of microwave drying of wet materials based on one-dimensional two-phase model

    Science.gov (United States)

    Salomatov, Vl V.; Karelin, V. A.

    2017-11-01

    Currently, microwave is one of the most interesting ways to conduct drying of dielectric materials, in particular coal. In this paper, two processes were considered - heating and drying. The temperature field of the coal semi-mass in the heating mode is found analytically strictly with the use of integral transformations. The drying process is formulated as a nonlinear Stephen problem with a moving boundary of the liquid-vapor phase transformation. The temperature distribution, speed and drying time in this mode are determined approximately analytically. Parametric analysis of the influence of the material and boundary conditions on the dynamics of warming up and drying is revealed.

  14. Electroosmotically enhanced dewatering/deliquoring of fine-particle coal: Final report, January 1--December 31, 1988

    Energy Technology Data Exchange (ETDEWEB)

    Sami, Sedat [Department of Civil Engineering and Mechanics, Southern Illinois Univ., Carbondale, IL (United States); Davis, Philip K. [Department of Civil Engineering and Mechanics, Southern Illinois Univ., Carbondale, IL (United States); Smith, James G. [Department of Electrical Engineering, Southern Illinois Univ., Carbondale, IL (United States)

    1989-03-01

    This research is an investigation of the use of electroosmosis to dewater/deliquor ultrafine coal. Post-beneficiation dewatering/deliquoring methods for ultrafine coal are inadequate and generally require subsequent thermal drying. Thermal drying is not only expensive and time consuming, it also does not recover liquids for reuse in beneficiation processes. The degree of difficulty associated with dewatering increases as surface forces become more important than gravimetric forces. Electroosmotic flow has advantages for dewatering because it is much less sensitive to pore size than hydraulic gradient flow for the 1 to 75 ..mu..m ultrafine size range. The first year of this project focused upon preparation of ultrafine coal samples, development of test equipment and test cells, identification of variables affecting electroosmosis, and trial runs. Techniques and procedures not previously used by researchers of electroosmotic dewatering have revealed important information about the dynamics of the electroosmosis process. The identification of the first few millimeters of the cathode region of the cell as the sink for most of the energy input into the process provides the potential for improving efficiency by concentrating the second year effort on intervention in that region. Information gathered about differences in FTIR spectra as a function of location in the dewatering cell will be investigated. Changes in pH with temperature and by the application of electroosmotic current flow will receive attention, as well. 178 refs., 16 figs.

  15. A Study of Coal Fire Propagation with Remotely Sensed Thermal Infrared Data

    Directory of Open Access Journals (Sweden)

    Hongyuan Huo

    2015-03-01

    Full Text Available Coal fires are a common and serious problem in most coal-bearing countries. Thus, it is very important to monitor changes in coal fires. Remote sensing provides a useful technique for investigating coal fields at a large scale and for detecting coal fires. In this study, the spreading direction of a coal fire in the Wuda Coal Field (WCF, northwest China, was analyzed using multi-temporal Landsat Thematic Mapper (TM and Enhanced Thematic Mapper (ETM+ thermal infrared (TIR data. Using an automated method and based on the land surface temperatures (LST that were retrieved from these thermal data, coal fires related to thermal anomalies were identified; the locations of these fires were validated using a coal fire map (CFM that was developed via field surveys; and the cross-validation of the results was also carried out using the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER thermal infrared images. Based on the results from longtime series of satellite TIR data set, the spreading directions of the coal fires were determined and the coal fire development on the scale of the entire coal field was predicted. The study delineated the spreading direction using the results of the coal fire dynamics analysis, and a coal fire spreading direction map was generated. The results showed that the coal fires primarily spread north or northeast in the central part of the WCF and south or southwest in the southern part of the WCF. In the northern part of the WCF, some coal fires were spreading north, perhaps coinciding with the orientation of the coal belt. Certain coal fires scattered in the northern and southern parts of the WCF were extending in bilateral directions. A quantitative analysis of the coal fires was also performed; the results indicate that the area of the coal fires increased an average of approximately 0.101 km2 per year.

  16. Low-grade coals: a review of some prospective upgrading technologies

    Energy Technology Data Exchange (ETDEWEB)

    Hassan Katalambula; Rajender Gupta [University of Alberta, Edmonton, AB (Canada). Department of Chemical and Materials Engineering

    2009-07-15

    There is a growing need of using low-grade coals because of higher quest for power generation. In the present carbon-constrained environment, there is a need of upgrading these coals in terms of moisture, ash, and/or other trace elements. The current paper reviews technologies used mainly categorized as drying for reducing moisture and cleaning the coal for reducing mineral content of coal and related harmful constituents, such as sulfur and mercury. The earliest upgrading of high-moisture lignite involved drying and manufacturing of briquettes. Drying technologies consist of both evaporative and non-evaporative (dewatering) types. The conventional coal cleaning used density separation in water medium. However, with water being a very important resource, conservation of water is pushing toward the development of dry cleaning of coal. There are also highly advanced coal-cleaning technologies that produce ultra-clean coals and produce coals with less than 0.1% of ash. The paper discusses some of the promising upgrading technologies aimed at improving these coals in terms of their moisture, ash, and other pollutant components. It also attempts to present the current status of the technologies in terms of development toward commercialization and highlights on problems encountered. It is obvious that still the upgrading goal has not been realized adequately. It can therefore be concluded that, because reserves for low-grade coals are quite plentiful, it is important to intensify efforts that will make these coals usable in an acceptable manner in terms of energy efficiency and environmental protection. 68 refs., 7 figs.

  17. Coal comes clean

    International Nuclear Information System (INIS)

    Minchener, A.

    1991-01-01

    Coal's status as the dominant fuel for electricity generation is under threat because of concern over the environmental impacts of acid rain and the greenhouse effect. Sulphur dioxide and nitrogen oxides cause acid rain and carbon dioxide is the main greenhouse gas. All are produced when coal is burnt. Governments are therefore tightening the emission limits for fossil-fuel power plants. In the United Kingdom phased reductions of sulphur dioxide and nitrogen oxides emissions are planned. It will be the responsibility of the power generator to take the necessary steps to reduce the emissions. This will be done using a number of technologies which are explained and outlined briefly - flue gas desulfurization, separation of coal into high and low-sulphur coal, direct desulfurization of coal, circulating fluidised bed combustion, integrated-gasification combined cycle systems and topping cycles. All these technologies are aiming at cleaner, more efficient combustion of coal. (UK)

  18. Cuttability of coal

    Energy Technology Data Exchange (ETDEWEB)

    Sikora, W

    1978-01-01

    The process of cutting dull M, dull bright MB, bright dull BM, and bright B coal under various compressive stress conditions was studied in laboratory tests. The efficiency of ploughs depends much more on the natural mining conditions than does that of shearer-loaders. For seams of medium workability, it is difficult to forecast whether ploughs will be successful. Cuttability tests are a good way of determining whether ploughs can be used. The effort necessary to cut coal in a stressed condition depends not only on such properties as the workability defined by the Protodyakonov index or compressive strength, but also, and mainly, on the petrographic structure and elastic properties of the coal. In bright coals with high elastic strain, and with BM and MB coals, a much greater increment of effort is necessary with increase in compressive stresses. The cuttability of dull coals from difficult mines was not very different.

  19. Coal tar in dermatology

    Energy Technology Data Exchange (ETDEWEB)

    Roelofzen, J.H.J.; Aben, K.K.H.; Van Der Valk, P.G.M.; Van Houtum, J.L.M.; Van De Kerkhof, P.C.M.; Kiemeney, L.A.L.M. [Radboud University Nijmegen Medical Center, Nijmegen (Netherlands). Dept. of Dermatology

    2007-07-01

    Coal tar is one of the oldest treatments for psoriasis and eczema. It has anti-inflammatory, antibacterial, antipruritic and antimitotic effects. The short-term side effects are folliculitis, irritation and contact allergy. Coal tar contains carcinogens. The carcinogenicity of coal tar has been shown in animal studies and studies in occupational settings. There is no clear evidence of an increased risk of skin tumors or internal tumors. Until now, most studies have been fairly small and they did not investigate the risk of coal tar alone, but the risk of coal tar combined with other therapies. New, well-designed, epidemiological studies are necessary to assess the risk of skin tumors and other malignancies after dermatological use of coal tar.

  20. Coal-to-liquid

    Energy Technology Data Exchange (ETDEWEB)

    Cox, A.W.

    2006-03-15

    With crude oil prices rocketing, many of the oil poor, but coal rich countries are looking at coal-to-liquid as an alternative fuel stock. The article outlines the two main types of coal liquefaction technology: direct coal liquefaction and indirect coal liquefaction. The latter may form part of a co-production (or 'poly-generation') project, being developed in conjunction with IGCC generation projects, plus the production of other chemical feedstocks and hydrogen. The main part of the article, based on a 'survey by Energy Intelligence and Marketing Research' reviews coal-to-liquids projects in progress in the following countries: Australia, China, India, New Zealand, the Philippines, Qatar and the US. 2 photos.

  1. Coal, culture and community

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-11-01

    16 papers are presented with the following titles: the miners; municipalisation and the millenium - Bolton-upon-Dearne Urban District Council 1899-1914; the traditional working class community revisited; the cultural capital of coal mining communities; activities, strike-breakers and coal communities; the limits of protest - media coverage of the Orgreave picket during the miners` strike; in defence of home and hearth? Families, friendships and feminism in mining communities; young people`s attitudes to the police in mining communities; the determinants of productivity growth in the British coal mining industry, 1976-1989; strategic responses to flexibility - a case study in coal; no coal turned in Yorkshire?; the North-South divide in the Central Coalfields; the psychological effects of redundancy and worklessness - a case study from the coalfields; the Dearne Valley initiative; the future under labour: and coal, culture and the community.

  2. Coal contract cost reduction through resale of coal

    International Nuclear Information System (INIS)

    Simon, R.

    1990-01-01

    The weak coal market of the 1980's has enabled utilities and other users of coal to enjoy stable or falling prices for coal supplies. Falling prices for coal stimulated the renegotiation of numerous coal contracts in recent years, as buyers look to take advantage of lower fuel prices available in the marketplace. This paper examines the use of coal resale transactions as a means of reducing fuel costs, and analyzes the benefits and risks associated with such transactions

  3. A Comparison between Use of Spray and Freeze Drying Techniques for Preparation of Solid Self-Microemulsifying Formulation of Valsartan and In Vitro and In Vivo Evaluation

    Science.gov (United States)

    Singh, Sanjay Kumar; Vuddanda, Parameswara Rao; Singh, Sanjay; Srivastava, Anand Kumar

    2013-01-01

    The objective of the present study was to develop self micro emulsifying formulation (SMEF) of valsartan to improve its oral bioavailability. The formulations were screened on the basis of solubility, stability, emulsification efficiency, particle size and zeta potential. The optimized liquid SMEF contains valsartan (20% w/w), Capmul MCM C8 (16% w/w), Tween 80 (42.66% w/w) and PEG 400 (21.33% w/w) as drug, oil, surfactant and co-surfactant, respectively. Further, Liquid SMEF was adsorbed on Aerosol 200 by spray and freeze drying methods in the ratio of 2 : 1 and transformed into free flowing powder. Both the optimized liquid and solid SMEF had the particle size valsartan as compared to existing formulations with improved bioavailability. PMID:23971048

  4. Recommended procedures and methodology of coal description

    Science.gov (United States)

    Chao, E.C.; Minkin, J.A.; Thompson, C.L.

    1983-01-01

    This document is the result of a workshop on coal description held for the Branch of Coal Resources of the U.S. Geological Survey in March 1982. It has been prepared to aid and encourage the field-oriented coal scientist to participate directly in petrographic coal-description activities. The objectives and past and current practices of coal description vary widely. These are briefly reviewed and illustrated with examples. Sampling approaches and techniques for collecting columnar samples of fresh coal are also discussed. The recommended procedures and methodology emphasize the fact that obtaining a good megascopic description of a coal bed is much better done in the laboratory with a binocular microscope and under good lighting conditions after the samples have been cut and quickly prepared. For better observation and cross-checking using a petrographic microscope for identification purposes, an in-place polishing procedure (requiring less than 2 min) is routinely used. Methods for using both the petrographic microscope and an automated image analysis system are also included for geologists who have access to such instruments. To describe the material characteristics of a coal bed in terms of microlithotypes or lithotypes, a new nomenclature of (V), (E), (1), (M). (S). (X1). (X2) and so on is used. The microscopic description of the modal composition of a megascopically observed lithologic type is expressed in terms of (VEIM); subscripts are used to denote the volume percentage of each constituent present. To describe a coal-bed profile, semiquantitative data (without microscopic study) and quantitative data (with microscopic study) are presented in ready-to-understand form. The average total composition of any thickness interval or of the entire coal bed can be plotted on a triangular diagram having V, E, and I+ M +S as the apices. The modal composition of any mixed lithologies such as (X1), (X2), and so on can also be plotted on such a triangular ternary diagram

  5. Clean coal technologies

    International Nuclear Information System (INIS)

    Bourillon, C.

    1994-01-01

    In 1993 more than 3.4 billion tonnes of coal was produced, of which half was used to generate over 44 per cent of the world's electricity. The use of coal - and of other fossil fuels- presents several environmental problems such as emissions of sulphur dioxide (SO 2 ), nitrogen oxides (NO 2 ), and carbon dioxide (CO 2 ) into the atmosphere. This article reviews the measures now available to mitigate the environmental impacts of coal. (author)

  6. Marketing Canada's coal

    Energy Technology Data Exchange (ETDEWEB)

    1985-11-01

    The topics are presented which were discussed at the 36th Canadian Coal Conference, held in Vancouver, BC in September 1985. The theme was Challenges, today and tomorrow and the conference sought to examine the primary problems confronting the world coal industry today: overcapacity, soft demand, depressed prices and intense global competition. Coal production in Canada was presented and its role in the steelmaking and electric power industries evaluated. A general mood of optimism prevailed.

  7. Cooperative research program in coal liquefaction. Quarterly report, May 1, 1993--October 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, G.P. [ed.

    1994-07-01

    This report summarizes progress in four areas of research under the general heading of Coal Liquefaction. Results of studies concerning the coliquefaction of coal with waste organic polymers or chemical products of these polymers were reported. Secondly, studies of catalytic systems for the production of clean transportation fuels from coal were discussed. Thirdly, investigations of the chemical composition of coals and their dehydrogenated counterparts were presented. These studies were directed toward elucidation of coal liquefaction processes on the chemical level. Finally, analytical methodologies developed for in situ monitoring of coal liquefaction were reported. Techniques utilizing model reactions and methods based on XAFS, ESR, and GC/MS are discussed.

  8. Enrichment of reactive macerals in coal: its characterization and utilization in coke making

    Science.gov (United States)

    Nag, Debjani; Kopparthi, P.; Dash, P. S.; Saxena, V. K.; Chandra, S.

    2018-01-01

    Macerals in coal are of different types: reactive and inert. These macerals are differ in their physical and chemical properties. Column flotation method has been used to separate the reactive macerals in a non-coking coal. The enriched coal is then characterized in order to understand the changes in the coking potential by different techniques. It is then used in making of metallurgical coke by proper blending with other coals. Enriched coal enhance the properties of metallurgical coke. This shows a path of utilization of non-coking coal in metallurgical coke making.

  9. NOx Control Options and Integration for US Coal Fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

    2006-06-30

    This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected

  10. Certification of the contents (mass fraction) of carbon, hydrogen, nitrogen, chlorine, arsenic, cadmium, manganese, mercury, lead, selenium, vanadium and zinc in three coals. Gas coal CRM No. 180; Coking coal CRM No. 181; Steam coal CRM No. 182

    Energy Technology Data Exchange (ETDEWEB)

    Griepink, B; Colinet, E; Wilkinson, H C

    1986-01-01

    The report first describes the preparation of three coal reference materials: Gas coal (BCR No. 180), Coking coal (BCR No. 181) and Steam coal (BCR No. 182). It deals further with the homogeneity and stability tests for major, minor and trace components. The contents (mass fractions) of the elements: C, H, N, Cl, As, Cd, Mn, Hg, Pb, Se, V and Zn are certified. The analytical techniques used in the certification are summarised. All the individual results are given and recommendations for analysis are made.

  11. Low level of stratospheric ozone near the Jharia coal field in India

    Indian Academy of Sciences (India)

    on the possible impact of coal fires on the stratospheric ozone concentration has been reported so far. ... dry soil and a local rise in the surface tempera- ture. Smoke plumes ..... of the impact on the air environment due to opencast coal mining–.

  12. Foam-mat drying technology: A review.

    Science.gov (United States)

    Hardy, Z; Jideani, V A

    2017-08-13

    This article reviews various aspects of foam-mat drying such as foam-mat drying processing technique, main additives used for foam-mat drying, foam-mat drying of liquid and solid foods, quality characteristics of foam-mat dried foods, and economic and technical benefits for employing foam-mat drying. Foam-mat drying process is an alternative method that allows the removal of water from liquid materials and pureed materials. In this drying process, a liquid material is converted into foam that is stable by being whipped after adding an edible foaming agent. The stable foam is then spread out in sheet or mat and dried by using hot air (40-90°C) at atmospheric pressure. Methyl cellulose (0.25-2%), egg white (3-20%), maltodextrin (0.5-05%), and gum Arabic (2-9%) are the commonly utilized additives for the foam-mat drying process at the given range, either combined together for their effectiveness or individual effect. The foam-mat drying process is suitable for heat sensitive, viscous, and sticky products that cannot be dried using other forms of drying methods such as spray drying because of the state of product. More interest has developed for foam-mat drying because of the simplicity, cost effectiveness, high speed drying, and improved product quality it provides.

  13. Coal export facilitation

    International Nuclear Information System (INIS)

    Eeles, L.

    1998-01-01

    There is a wide range of trade barriers, particularly tariffs, in current and potential coal market. Commonwealth departments in Australia play a crucial role in supporting government industry policies. This article summarises some of more recent activities of the Department of Primary Industries and Energy (DPIE) in facilitating the export of Australian Coals. Coal export facilitation activities are designed to assist the Australian coal industry by directing Commonwealth Government resources towards issues which would be inappropriate or difficult for the industry to address itself

  14. Physicochemical Characterization and Thermal Decomposition of Garin Maiganga Coal

    Directory of Open Access Journals (Sweden)

    Nyakuma Bemgba Bevan

    2016-12-01

    Full Text Available The paper examined physicochemical and thermal characteristics of the newly discovered Garin Maiganga (GMG coal from Nigeria. The physicochemical characterization comprised of elemental, proximate, calorific value, and classification (rank analyses. Thermal analysis was examined using combined Thermogravimetric (TG and Derivative Thermogravimetric analyses (DTG. Hence, the coal was heated from 30°C to 1000°C at 20°C/min under inert conditions to examine its thermal degradation behaviour and temperature profile characteristics (TPC. The results indicated that the GMG coal fuel properties consist of low Ash, Nitrogen, and Sulphur content. Moisture content was > 5%, Volatile Matter > 50%, Fixed Carbon > 22%, and Heating Value (HHV 23.74 MJ/kg. Based on its fuel properties, the GMG coal can be classified as a Sub-Bituminous B, non-agglomerating low rank coal (LRC. The GMG coal TPCs – onset, peak, and offset temperatures – were 382.70°C, 454.60°C, and 527.80°C, respectively. The DTG profile revealed four (4 endothermic peaks corresponding to loss of moisture (drying, volatile matter (devolatization, and coke formation. The residual mass Rm was 50.16%, which indicates that higher temperatures above 1000°C are required for the complete pyrolytic decomposition of the GMG coal. In conclusion, the results indicate that the GMG coal is potentially suitable for future utilization in electric power generation and the manufacture of cement and steel.

  15. Australian coal year book 1986

    Energy Technology Data Exchange (ETDEWEB)

    1986-01-01

    This yearbook presents a review of the Australian coal industry during the 1984-85 financial year. Included are details on mines, future prospects, coal export facilities and ports, annual cost statistics and a index of coal mine owners.

  16. Technology for beneficiation of non-coking coals

    Energy Technology Data Exchange (ETDEWEB)

    Bose, S.K.

    1987-04-01

    This article outlines the need for efficient non-coking coal beneficiation plants in India to cope with mass production from opencast coal mines. The existing use of magnetite in heavy medium separation processes is expensive and not very efficient in respect to removing shales from opencast lump coals. Instead a new technique is proposed using a ROMJIG washing plant developed in the Federal Republic of Germany. This provides a very efficient, low cost washing system for the coals and allows the continued integration with the coal blending plants. This simplified technology allows for flexible working hours to meet demand and will allow new developments to continue including fuel slurry pipelines, automated testing of coals and new pulverized boiler fuels.

  17. Low temperature oxidation and spontaneous combustion characteristics of upgraded low rank coal

    Energy Technology Data Exchange (ETDEWEB)

    Choi, H.K.; Kim, S.D.; Yoo, J.H.; Chun, D.H.; Rhim, Y.J.; Lee, S.H. [Korea Institute of Energy Research, Daejeon (Korea, Republic of)

    2013-07-01

    The low temperature oxidation and spontaneous combustion characteristics of dried coal produced from low rank coal using the upgraded brown coal (UBC) process were investigated. To this end, proximate properties, crossing-point temperature (CPT), and isothermal oxidation characteristics of the coal were analyzed. The isothermal oxidation characteristics were estimated by considering the formation rates of CO and CO{sub 2} at low temperatures. The upgraded low rank coal had higher heating values than the raw coal. It also had less susceptibility to low temperature oxidation and spontaneous combustion. This seemed to result from the coating of the asphalt on the surface of the coal, which suppressed the active functional groups from reacting with oxygen in the air. The increasing upgrading pressure negatively affected the low temperature oxidation and spontaneous combustion.

  18. Australian black coal statistics 1991

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    This third edition of Australian black coal statistics covers anthracite, bituminous and subbituminous coals. It includes maps and figures on resources and coal fields and statistics (mainly based on the calendar year 1991) on coal demand and supply, production, employment and productivity in Australian coal mines, exports, prices and ports, and domestic consumption. A listing of coal producers by state is included. A final section presents key statistics on international world trade in 1991. 54 tabs.

  19. Coal combustion technology in China

    International Nuclear Information System (INIS)

    Huang, Z.X.

    1994-01-01

    Coal is the most important energy source in China, the environmental pollution problem derived from coal burning is rather serious in China. The present author discusses coal burning technologies both in boilers and industrial furnaces and their relations with environmental protection problems in China. The technological situations of Circulating Fluidized Bed Coal Combustor, Pulverized Coal Combustor with Aerodynamic Flame Holder and Coal Water Slurry Combustion have been discussed here as some of the interesting problems in China only. (author). 3 refs

  20. Interrelating the breakage and composition of mined and drill core coal

    Science.gov (United States)

    Wilson, Terril Edward

    Particle size distribution of coal is important if the coal is to be beneficiated, or if a coal sales contract includes particle size specifications. An exploration bore core sample of coal ought to be reduced from its original cylindrical form to a particle size distribution and particle composition that reflects, insofar as possible, a process stream of raw coal it represents. Often, coal cores are reduced with a laboratory crushing machine, the product of which does not match the raw coal size distribution. This study proceeds from work in coal bore core reduction by Australian investigators. In this study, as differentiated from the Australian work, drop-shatter impact breakage followed by dry batch tumbling in steel cylinder rotated about its transverse axis are employed to characterize the core material in terms of first-order and zeroth-order breakage rate constants, which are indices of the propensity of the coal to degrade during excavation and handling. Initial drop-shatter and dry tumbling calibrations were done with synthetic cores composed of controlled low-strength concrete incorporating fly ash (as a partial substitute for Portland cement) in order to reduce material variables and conserve difficult-to-obtain coal cores. Cores of three different coalbeds--Illinois No. 6, Upper Freeport, and Pocahontas No. 5 were subjected to drop-shatter and dry batch tumbling tests to determine breakage response. First-order breakage, characterized by a first-order breakage index for each coal, occurred in the drop-shatter tests. First- and zeroth-order breakage occurred in dry batch tumbling; disappearance of coarse particles and creation of fine particles occurred in a systematic way that could be represented mathematically. Certain of the coal cores available for testing were dry and friable. Comparison of coal preparation plant feed with a crushed bore core and a bore core prepared by drop-shatter and tumbling (all from the same Illinois No.6 coal mining

  1. Coal surface control for advanced physical fine coal cleaning technologies. Final report, September 19, 1988--August 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-12-31

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO{sub 2} emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R&D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  2. Thermal coal utilization for the ESCAP region

    Energy Technology Data Exchange (ETDEWEB)

    1982-01-01

    A selection of papers is presented originating from talks to coal utilization workshops for the ASEAN region in 1981. The papers cover: planning aspects - economic and technical aspects of coal usage, long term planning for fuel coal needs, planning and coal selection for coal-fired power plants, coal availability and marketing, and economic aspects of coal usage in developing countries; combustion and plant - changing from coal to oil, principles and problems of coal combustion, use of indigenous and imported coals and their effects on plant design, coal pulverizing mills, ash and dust disposal, environmental aspects of coal combustion, industrial sized coal-fired boilers; transport and storage -ocean shipment, coal receival facilities and associated operations, shipping and rail transport, coal handling and transport, environmental issue in the transport and handling of coal, coal preparation and blending; testing and properties - coal types, characterization properties and classification; training power plant operators; the cement industry and coal, the Australian black coal industry.

  3. Investigation of trace elements in coal

    International Nuclear Information System (INIS)

    Gluskoter, H.J.; Cahil, R.A.; Miller, W.G.; Ruch, R.R.; Shimp, N.F.

    1976-01-01

    A variety of coal samples is currently being extensively analyzed for constituents, including many trace elements, at the Illinois State Geological Survey. The samples include whole coals, washed coals, and bench samples. Among the many determinations made on each sample are analyses for approximately 60 elements, almost twice the number of elements previously determined. The increase is in part the result of the addition of instrumental neutron activation analysis (INAA) equipment to the laboratory. Twenty-five samples of Herrin (No. 6) Coal that had been analyzed previously were subjected to INAA analysis and were found to include Ba, Ce, Cs, Dy, Eu, Au, Hf, I, In, La, Lu, Rb, Sm, Sc, Ag, Sr, Ta, Tb, Th, W, U, and Yb, none of which were reported by previous techniques. These elements generally are present in very small amounts and, with the exception of barium, exhibit no wide range in concentration. The rare earth elements are among those having the narrowest ranges. Wide variations in element content have been observed in bench sets of coals (samples of vertical segments of the coal seam). Many elements, notably germanium, are concentrated at the top and/or bottom of the seam, the high concentrations of Ge being found there in all four bench sets analyzed to date

  4. Clean fuel-magnesia bonded coal briquetting

    Energy Technology Data Exchange (ETDEWEB)

    Tosun, Yildirim I. [S. Demirel University Eng., Arch. Faculty Mining Eng. Department, Isparta (Turkey)

    2007-10-15

    Benefaction from coal fines as solid fuel in Turkey is very much important for economical development. Beneficiation from washed coal fines in the industry using solid fuel at lump size and in the municipal areas as an household solid fuel may be only provided by hot briquetting of the coal fines. The most practical common way of that benefication from coal fines in our country have been hot binding by sulfite liquor-sulfite liquor-melas and lime mixtures. Harmful the flue content of sulfite liquor-melas may only be eliminated by lime, a type of solid additive. However, cold bonded briquettes produced from coal fines are environmentally free. Just ash contents of these briquettes increase at a certain degree and heat content of them decrease at a certain extent. By using magnesia binder showed in this study, Tuncbilek lignite fines have been briquetted by cold and hot briquetting techniques. The qualities of briquettes produced by cold binders were compared with to those produced by other hot binding methods As a result, magnesia binder showed the similar characteristics with those of the briquettes produced by only cold bonded gypsum. Use of magnesite mixture and gypsum just as only cold binder was not suitable for the requirements from the coal briquettes to be used as solid fuels, particularly from household fuels, but just only as cold additive should be used. (author)

  5. Development and Sliding Wear Response of Epoxy Composites Filled with Coal Mine Overburden Material

    Science.gov (United States)

    Das, Prithika; Satapathy, Alok; Mishra, M. K.

    2018-03-01

    The paper reports on development and characterization of epoxy based composites filled with micro-sized mine overburden material. Coal mine overburden material is typically highly heterogeneous and is considered as waste material. For excavating each ton of coal, roughly 5 tons of overburden materials are removed and is dumped nearby occupying large space. Gainful utilization of this waste is a major challenge. In the present work, this material is used as filler materials in making a new class of epoxy matrix composites. Composites with different weight proportions of fillers (0, 10, 20, 30 and 40) wt. % are prepared by hand layup technique. Compression tests are performed as per corresponding ASTM standards to assess the compressive strength of these composites. Further, dry sliding tests are performed following ASTM G99 standards using a pin on disk machine. A design of experiment approach based on Taguchi’s L16 orthogonal arrays is adopted. Tests are performed at different sliding velocities for multiple sliding distances under varying normal loads. Specific wear rates of the composites under different test conditions are obtained. The analysis of the test results revealed that the filler content and the sliding velocity are the most predominant control factors affecting the wear rate. This work thus, opens up a new avenue for the value added utilization of coal mine overburden material.

  6. Research of coal flash hydropyrolysis. I. Chemical type analysis of nitrogen in coal and semi-coke

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, H.; Ni, Y.; Tang, L.; Zheng, Z.; Zhu, Z. [East China University of Science and Technology, Shanghai (China)

    2001-04-01

    Using XPS analyses the chemical types of nitrogen of ten different types of Chinese coals and their semi-cokes from flash hydropyrolysis (FHP) are studied. The results shows that XPS can effectively determined the chemical types of nitrogen in coal and semi-coke. Peak of XPS located in 398.8 ({plus_minus}0.1) eV and 400.2 ({plus_minus}0.1) eV, which corresponds to pyrrole and pyridine. The nitrogen types are different in coals but mainly are pyrrole and pyridine, and often the pyrrole is more than pyridine. The nitrogen type in coals from FHP is the same as in coal. In FHP, the relative content of pyrrole increases and pyridine reduces. Therefore, it was put forward that flash hydropyrolysis is a new important clean-coal technique and has notable effect of denitrogenation.

  7. The Indonesian coal industry

    International Nuclear Information System (INIS)

    Cook, A.; Daulay, B.

    2000-01-01

    In this comprehensive article the authors describe the origins and progress of the Indonesian coal industry and the role it plays, and will play, in the domestic energy scene and world coal trade. In the '80s, the Indonesian coal industry laid the basis for major expansion such that coal production rose from under a million tonnes in 1983 to 10.6 million tonnes in 1990, 50.9 million tonnes by 1996 and 61.2 million tonnes in 1992. At the same time, exports have increased from 0.4 million tonnes to 44.8 million tonnes. Current export levels are higher than originally expected, due in part to a slow down in the construction of electric power stations and a partial switch to natural gas. This has slowed the rate at which domestic coal demand has built up. The majority of coals currently exported are low rank steam coals, but some of the higher rank and very low ash coals are used for blast furnace injection, and a very small proportion may even be used within coking blends, even though they have poor coking properties. The Indonesian coal industry has developed very rapidly over the last six years to become a significant exporter, especially within the ASEAN context. The resources base appears to be large enough to support further increases in production above those already planned. It is probable that resources and reserves can be increased above the current levels. It is likely that some reserves of high value coals can be found, but it is also probable that the majority of additions to reserves will be lower in rank (and therefore quality) compared with the average of coals currently being mined. Reserves of qualities suitable for export will support that industry for a considerable period of time. However, in the longer term, the emphasis of production will increasingly swing to the domestic market

  8. Flash pyrolysis of coal-solvent slurry prepared from the oxidized coal and the coal dissolved in solvent; Ichibu yokaishita sanka kaishitsutan slurry no jinsoku netsubunkai

    Energy Technology Data Exchange (ETDEWEB)

    Maki, T.; Mae, K.; Okutsu, H.; Miura, K. [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1996-10-28

    In order to develop a high-efficiency coal pyrolysis method, flash pyrolysis was experimented on slurry prepared by using liquid-phase oxidation reformed coal and a methanol-based solvent mixture. Australian Morwell coal was used for the experiment. The oxidized coal, into which carboxyl groups have been introduced, has the condensation structure relaxed largely, and becomes highly fluid slurry by means of the solvent. Char production can be suppressed by making the oxidation-pretreated coal into slurry, resulting in drastically improved pyrolytic conversion. The slurry was divided into dissolved solution, dried substance, extracted residue, and residual slurry, which were pyrolized independently. The dissolved solution showed very high conversion. Improvement in the conversion is contributed by separating the dissolved substances (coal macromolecules) at molecular levels, coagulating the molecules, suppressing cross-link formation, and reducing molecular weight of the dissolved substances. Oxidized coal can be dissolved to 80% or higher by using several kinds of mixed solvents. As a result of the dissolution, a possibility was suggested on pyrolysis which is easy in handling and high in conversion. 7 refs., 6 figs., 2 tabs.

  9. Drying of α-amylase by spray drying and freeze-drying - a comparative study

    Directory of Open Access Journals (Sweden)

    S. S. de Jesus

    2014-09-01

    Full Text Available This study is aimed at comparing two traditional methods of drying of enzymes and at verifying the efficiency of each one and their advantages and disadvantages. The experiments were performed with a laboratory spray dryer and freeze-dryer using α-amylase as the model enzyme. An experimental design in star revealed that spray drying is mainly influenced by the inlet air temperature and feed flow rate, which were considered to be the main factors influencing the enzymatic activity and water activity; the long period of material exposure to high temperatures causes a partial activity loss. In the experiments of freeze drying, three methods of freezing were used (freezer, acetone and dry ice, and liquid nitrogen and samples subsequently freeze-dried for times ranging between 0-24 hours. The product obtained from the two techniques showed high enzymatic activity and low water activity. For the drying of heat-resistant enzymes, in which the product to be obtained does not have high added value, spray drying may be more economically viable because, in the freeze drying process, the process time can be considered as a limiting factor when choosing a technique.

  10. Brown Coal Dewatering Using Poly (Acrylamide-Co-Potassium Acrylic Based Super Absorbent Polymers

    Directory of Open Access Journals (Sweden)

    Sheila Devasahayam

    2015-09-01

    Full Text Available With the rising cost of energy and fuel oils, clean coal technologies will continue to play an important role during the transition to a clean energy future. Victorian brown coals have high oxygen and moisture contents and hence low calorific value. This paper presents an alternative non evaporative drying technology for high moisture brown coals based on osmotic dewatering. This involves contacting and mixing brown coal with anionic super absorbent polymers (SAP which are highly crossed linked synthetic co-polymers based on a cross-linked copolymer of acryl amide and potassium acrylate. The paper focuses on evaluating the water absorption potential of SAP in contact with 61% moisture Loy Yang brown coal, under varying SAP dosages for different contact times and conditions. The amount of water present in Loy Yang coal was reduced by approximately 57% during four hours of SAP contact. The extent of SAP brown coal drying is directly proportional to the SAP/coal weight ratio. It is observed that moisture content of fine brown coal can readily be reduced from about 59% to 38% in four hours at a 20% SAP/coal ratio.

  11. Clean utilization of low-rank coals for low-cost power generation

    International Nuclear Information System (INIS)

    Sondreal, E.A.

    1992-01-01

    Despite the unique utilization problems of low-rank coals, the ten US steam electric plants having the lowest operating cost in 1990 were all fueled on either lignite or subbituminous coal. Ash deposition problems, which have been a major barrier to sustaining high load on US boilers burning high-sodium low-rank coals, have been substantially reduced by improvements in coal selection, boiler design, on-line cleaning, operating conditions, and additives. Advantages of low-rank coals in advanced systems are their noncaking behavior when heated, their high reactivity allowing more complete reaction at lower temperatures, and the low sulfur content of selected deposits. The principal barrier issues are the high-temperature behavior of ash and volatile alkali derived from the coal-bound sodium found in some low-rank coals. Successful upgrading of low-rank coals requires that the product be both stable and suitable for end use in conventional and advanced systems. Coal-water fuel produced by hydrothermal processing of high-moisture low-rank coal meets these criteria, whereas most dry products from drying or carbonizing in hot gas tend to create dust and spontaneous ignition problems unless coated, agglomerated, briquetted, or afforded special handling

  12. Modelling and analysis of global coal markets

    International Nuclear Information System (INIS)

    Trueby, Johannes

    2013-01-01

    International Steam Coal Trade. In this paper, we analyse steam coal market equilibria in the years 2006 and 2008 by testing for two possible market structure scenarios: perfect competition and an oligopoly setup with major exporters competing in quantities. The assumed oligopoly scenario cannot explain market equilibria for any year. While we find that the competitive model simulates market equilibria well in 2006, the competitive model is not able to reproduce real market outcomes in 2008. The analysis shows that not all available supply capacity was utilised in 2008. We conclude that either unknown capacity bottlenecks or more sophisticated non-competitive strategies were the cause for the high prices in 2008. Chapter 4 builds upon the findings of the analysis in chapter 3 and adds a more detailed representation of domestic markets. The corresponding essay is titled Nations as Strategic Players in Global Commodity Markets: Evidence from World Coal Trade. In this chapter we explore the hypothesis that export policies and trade patterns of national players in the steam coal market are consistent with non-competitive market behaviour. We test this hypothesis by developing a static equilibrium model which is able to model coal producing nations as strategic players. We explicitly account for integrated seaborne trade and domestic markets. The global steam coal market is simulated under several imperfect market structure setups. We find that trade and prices of a China - Indonesia duopoly fits the real market outcome best and that real Chinese export quotas in 2008 were consistent with simulated exports under a Cournot-Nash strategy. Chapter 5 looks at the long-term effect of Chinese energy system planning decisions. The time horizon is 2006 to 2030. The analysis in this chapter combines a dynamic equilibrium model with the scenario analysis technique. The corresponding essay is titled Coal Lumps vs. Electrons: How Do Chinese Bulk Energy Transport Decisions Affect the Global

  13. Modelling and analysis of global coal markets

    Energy Technology Data Exchange (ETDEWEB)

    Trueby, Johannes

    2013-01-17

    International Steam Coal Trade. In this paper, we analyse steam coal market equilibria in the years 2006 and 2008 by testing for two possible market structure scenarios: perfect competition and an oligopoly setup with major exporters competing in quantities. The assumed oligopoly scenario cannot explain market equilibria for any year. While we find that the competitive model simulates market equilibria well in 2006, the competitive model is not able to reproduce real market outcomes in 2008. The analysis shows that not all available supply capacity was utilised in 2008. We conclude that either unknown capacity bottlenecks or more sophisticated non-competitive strategies were the cause for the high prices in 2008. Chapter 4 builds upon the findings of the analysis in chapter 3 and adds a more detailed representation of domestic markets. The corresponding essay is titled Nations as Strategic Players in Global Commodity Markets: Evidence from World Coal Trade. In this chapter we explore the hypothesis that export policies and trade patterns of national players in the steam coal market are consistent with non-competitive market behaviour. We test this hypothesis by developing a static equilibrium model which is able to model coal producing nations as strategic players. We explicitly account for integrated seaborne trade and domestic markets. The global steam coal market is simulated under several imperfect market structure setups. We find that trade and prices of a China - Indonesia duopoly fits the real market outcome best and that real Chinese export quotas in 2008 were consistent with simulated exports under a Cournot-Nash strategy. Chapter 5 looks at the long-term effect of Chinese energy system planning decisions. The time horizon is 2006 to 2030. The analysis in this chapter combines a dynamic equilibrium model with the scenario analysis technique. The corresponding essay is titled Coal Lumps vs. Electrons: How Do Chinese Bulk Energy Transport Decisions Affect the Global

  14. Trace elemental composition of Nigerian coal measured by neutron activation analysis

    International Nuclear Information System (INIS)

    Ndiokwere, Ch.L.; Guinn, V.P.; Burtner, D.

    1983-01-01

    The instrumental neutron activation analysis (INAA) technique has been used to determine 17 major, minor and trace elements in samples of the three major sources of Nigerian coal. The NBS Standard Reference Material, Coal SRM 1632, was also analyzed, for the purpose of verifying the accuracy of the method. The concentrations of the major elements determined for the Nigerian coal were found to be much lower than the mean values of those reported for coal samples from other parts of the world. (author)

  15. ACARP Project C10059. ACARP manual of modern coal testing methods. Volume 1: The manual

    Energy Technology Data Exchange (ETDEWEB)

    Sakurovs, R.; Creelman, R.; Pohl, J.; Juniper, L. [CSIRO Energy Technology, Sydney, NSW (Australia)

    2002-07-01

    The Manual summarises the purpose, applicability, and limitations of a range of standard and modern coal testing methods that have potential to assist the coal company technologist to better evaluate coal performance. The first volume sets out the Modern Coal Testing Methods in summarised form that can be used as a quick guide to practitioners to assist in selecting the best technique to solve their problems.

  16. Latest Apple Drying Technologies: A Review

    OpenAIRE

    ÖZDEMİR, Yasin; SAYIN, Emir Olcay; KURULTAY, Şefik

    2009-01-01

    Drying is known as one of the oldest preservation methods and can be applicable to many fruits. Sun drying of apple has been known from ancient times. However, this technique is weather-dependent and has contamination problems such as dust, soil, sand particles and insects. Hot air drying of apples has low energy efficiency and requires longer drying period. The desire to eliminate these problems, prevent quality loss, and achieve fast and effective thermal processing has resulted in an incre...

  17. Development of coal resources

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    It is an important issue to expand stable coal supply areas for Japan, especially to assure stable supply of overseas coals. The investigations on geological structures in foreign countries perform surveys on geological structures in overseas coal producing countries and basic feasibility studies. The investigations select areas with greater business risks in coal producing countries and among private business entities. The geological structure investigations were carried out on China, Indonesia and Malaysia and the basic feasibility studies on Indonesia during fiscal 1994. The basic coal resource development investigations refer to the results of previous physical explorations and drilling tests to develop practical exploration technologies for coal resources in foreign countries. The development feasibility studies on overseas coals conduct technological consultation, surface surveys, physical explorations, and trial drilling operations, and provide fund assistance to activities related thereto. Fiscal 1994 has provided fund assistance to two projects in Indonesia and America. Fund loans are provided on investigations for development and import of overseas coals and other related activities. Liability guarantee for development fund is also described.

  18. Coal in Canada

    International Nuclear Information System (INIS)

    Salaff, S.

    1991-01-01

    This article examines the potential market for coal-fired independent power projects in western Canada. The topics of the article include emissions issues, export potential for power produced, and financial and other assistance to independent power producers offered by British Columbia Hydro and coal mining companies in the region, including financing of projects and power distribution services including connecting to the USA grids

  19. Black coal. [Australia

    Energy Technology Data Exchange (ETDEWEB)

    Pratt, R

    1973-01-01

    Statistics are given for the Australian black coal industry for 1970-3 (production, value, employment, wages and salaries, productivity, trade, stocks, consumption, export contracts, exploration, etc.). In less detail, world coal trade is reviewed and coke production is mentioned briefly. (LTN )

  20. Feasibility analysis and policy recommendations for the development of the coal based SNG industry in Xinjiang

    International Nuclear Information System (INIS)

    Huo, Jinwei; Yang, Degang; Xia, Fuqiang; Tang, Hong; Zhang, Wenbiao

    2013-01-01

    Based on China's basic national energy conditions of “abundant coal and scarce gas reserve”, the development of the coal based SNG industry is considered to be an effective way to solve the conflict between the supply and demand of natural gas and an important direction in the clean use of coal. Xinjiang is rich in coal resources and is listed by the central government as one of the main bases of the coal based SNG industry. Nearly 70% of the coal based SNG projects are being conducted in Xinjiang, with the goal to take advantage of the lower coal price in Xinjiang to promote the development of the coal based SNG industry. However, the coal based SNG industry is subject to the constraints of pollution, immature technology, poor economic returns, water resources and many other factors. Therefore, the development of the coal based SNG industry should be limited to industrial demonstration. Taking into account China's energy security and environmental governance, once the technology matures, the development prospect of the coal based SNG industry is broad. - Highlights: • Booming in the coal based SNG is not oriented to market, but investment-driven. • Coal based SNG is restricted by pollution, technology, economic and water resources. • The positioning of coal based SNG industry should be industrial demonstration. • The immature technique is the biggest obstacle