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Sample records for cimarron plutonium production plant

  1. Plutonium Finishing Plant

    Data.gov (United States)

    Federal Laboratory Consortium — The Plutonium Finishing Plant, also known as PFP, represented the end of the line (the final procedure) associated with plutonium production at Hanford.PFP was also...

  2. Plutonium Finishing Plant safety evaluation report

    Energy Technology Data Exchange (ETDEWEB)

    1995-01-01

    The Plutonium Finishing Plant (PFP) previously known as the Plutonium Process and Storage Facility, or Z-Plant, was built and put into operation in 1949. Since 1949 PFP has been used for various processing missions, including plutonium purification, oxide production, metal production, parts fabrication, plutonium recovery, and the recovery of americium (Am-241). The PFP has also been used for receipt and large scale storage of plutonium scrap and product materials. The PFP Final Safety Analysis Report (FSAR) was prepared by WHC to document the hazards associated with the facility, present safety analyses of potential accident scenarios, and demonstrate the adequacy of safety class structures, systems, and components (SSCs) and operational safety requirements (OSRs) necessary to eliminate, control, or mitigate the identified hazards. Documented in this Safety Evaluation Report (SER) is DOE`s independent review and evaluation of the PFP FSAR and the basis for approval of the PFP FSAR. The evaluation is presented in a format that parallels the format of the PFP FSAR. As an aid to the reactor, a list of acronyms has been included at the beginning of this report. The DOE review concluded that the risks associated with conducting plutonium handling, processing, and storage operations within PFP facilities, as described in the PFP FSAR, are acceptable, since the accident safety analyses associated with these activities meet the WHC risk acceptance guidelines and DOE safety goals in SEN-35-91.

  3. Plutonium Finishing Plant. Interim plutonium stabilization engineering study

    Energy Technology Data Exchange (ETDEWEB)

    Sevigny, G.J.; Gallucci, R.H.; Garrett, S.M.K.; Geeting, J.G.H.; Goheen, R.S.; Molton, P.M.; Templeton, K.J.; Villegas, A.J. [Pacific Northwest Lab., Richland, WA (United States); Nass, R. [Nuclear Fuel Services, Inc. (United States)

    1995-08-01

    This report provides the results of an engineering study that evaluated the available technologies for stabilizing the plutonium stored at the Plutonium Finishing Plant located at the hanford Site in southeastern Washington. Further processing of the plutonium may be required to prepare the plutonium for interim (<50 years) storage. Specifically this document provides the current plutonium inventory and characterization, the initial screening process, and the process descriptions and flowsheets of the technologies that passed the initial screening. The conclusions and recommendations also are provided. The information contained in this report will be used to assist in the preparation of the environmental impact statement and to help decision makers determine which is the preferred technology to process the plutonium for interim storage.

  4. Design-Only Conceptual Design Report: Plutonium Immobilization Plant

    Energy Technology Data Exchange (ETDEWEB)

    DiSabatino, A.; Loftus, D.

    1999-01-01

    This design-only conceptual design report was prepared to support a funding request by the Department of Energy Office of Fissile Materials Disposition for engineering and design of the Plutonium Immobilization Plant, which will be used to immobilize up to 50 tonnes of surplus plutonium. The siting for the Plutonium Immobilization Plant will be determined pursuant to the site-specific Surplus Plutonium Disposition Environmental Impact Statement in a Plutonium Deposition Record of Decision in early 1999. This document reflects a new facility using the preferred technology (ceramic immobilization using the can-in-canister approach) and the preferred site (at Savannah River). The Plutonium Immobilization Plant accepts plutonium from pit conversion and from non-pit sources and, through a ceramic immobilization process, converts the plutonium into mineral-like forms that are subsequently encapsulated within a large canister of high-level waste glass. The final immobilized product must make the plutonium as inherently unattractive and inaccessible for use in nuclear weapons as the plutonium in spent fuel from commercial reactors and must be suitable for geologic disposal. Plutonium immobilization at the Savannah River Site uses: (1) A new building, the Plutonium Immobilization Plant, which will convert non-pit surplus plutonium to an oxide form suitable for the immobilization process, immobilize plutonium in a titanate-based ceramic form, place cans of the plutonium-ceramic forms into magazines, and load the magazines into a canister; (2) The existing Defense Waste Processing Facility for the pouring of high-level waste glass into the canisters; and (3) The Actinide Packaging and Storage Facility to receive and store feed materials. The Plutonium Immobilization Plant uses existing Savannah River Site infra-structure for analytical laboratory services, waste handling, fire protection, training, and other support utilities and services. The Plutonium Immobilization Plant

  5. Plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Miner, William N

    1964-01-01

    This pamphlet discusses plutonium from discovery to its production, separation, properties, fabrication, handling, and uses, including use as a reactor fuel and use in isotope power generators and neutron sources.

  6. Plutonium Finishing Plant (PFP) Final Safety Analysis Report (FSAR) [SEC 1 THRU 11

    Energy Technology Data Exchange (ETDEWEB)

    ULLAH, M K

    2001-02-26

    The Plutonium Finishing Plant (PFP) is located on the US Department of Energy (DOE) Hanford Site in south central Washington State. The DOE Richland Operations (DOE-RL) Project Hanford Management Contract (PHMC) is with Fluor Hanford Inc. (FH). Westinghouse Safety Management Systems (WSMS) provides management support to the PFP facility. Since 1991, the mission of the PFP has changed from plutonium material processing to preparation for decontamination and decommissioning (D and D). The PFP is in transition between its previous mission and the proposed D and D mission. The objective of the transition is to place the facility into a stable state for long-term storage of plutonium materials before final disposition of the facility. Accordingly, this update of the Final Safety Analysis Report (FSAR) reflects the current status of the buildings, equipment, and operations during this transition. The primary product of the PFP was plutonium metal in the form of 2.2-kg, cylindrical ingots called buttoms. Plutonium nitrate was one of several chemical compounds containing plutonium that were produced as an intermediate processing product. Plutonium recovery was performed at the Plutonium Reclamation Facility (PRF) and plutonium conversion (from a nitrate form to a metal form) was performed at the Remote Mechanical C (RMC) Line as the primary processes. Plutonium oxide was also produced at the Remote Mechanical A (RMA) Line. Plutonium processed at the PFP contained both weapons-grade and fuels-grade plutonium materials. The capability existed to process both weapons-grade and fuels-grade material through the PRF and only weapons-grade material through the RMC Line although fuels-grade material was processed through the line before 1984. Amounts of these materials exist in storage throughout the facility in various residual forms left from previous years of operations.

  7. History and stabilization of the Plutonium Finishing Plant (PFP) complex, Hanford Site

    Energy Technology Data Exchange (ETDEWEB)

    Gerber, M.S., Fluor Daniel Hanford

    1997-02-18

    The 231-Z Isolation Building or Plutonium Metallurgy Building is located in the Hanford Site`s 200 West Area, approximately 300 yards north of the Plutonium Finishing Plant (PFP) (234-5 Building). When the Hanford Engineer Works (HEW) built it in 1944 to contain the final step for processing plutonium, it was called the Isolation Building. At that time, HEW used a bismuth phosphate radiochemical separations process to make `AT solution,` which was then dried and shipped to Los Alamos, New Mexico. (AT solution is a code name used during World War II for the final HEW product.) The process was carried out first in T Plant and the 224-T Bulk Reduction Building and B Plant and the 224-B Bulk Reduction Building. The 224-T and -B processes produced a concentrated plutonium nitrate stream, which then was sent in 8-gallon batches to the 231-Z Building for final purification. In the 231-Z Building, the plutonium nitrate solution underwent peroxide `strikes` (additions of hydrogen peroxide to further separate the plutonium from its carrier solutions), to form the AT solution. The AT solution was dried and shipped to the Los Alamos Site, where it was made into metallic plutonium and then into weapons hemispheres.` The 231-Z Building began `hot` operations (operations using radioactive materials) with regular runs of plutonium nitrate on January 16, 1945.

  8. Plutonium

    Science.gov (United States)

    Clark, David L.; Hecker, Siegfried S.; Jarvinen, Gordon D.; Neu, Mary P.

    The element plutonium occupies a unique place in the history of chemistry, physics, technology, and international relations. After the initial discovery based on submicrogram amounts, it is now generated by transmutation of uranium in nuclear reactors on a large scale, and has been separated in ton quantities in large industrial facilities. The intense interest in plutonium resulted fromthe dual-use scenario of domestic power production and nuclear weapons - drawing energy from an atomic nucleus that can produce a factor of millions in energy output relative to chemical energy sources. Indeed, within 5 years of its original synthesis, the primary use of plutonium was for the release of nuclear energy in weapons of unprecedented power, and it seemed that the new element might lead the human race to the brink of self-annihilation. Instead, it has forced the human race to govern itself without resorting to nuclear war over the past 60 years. Plutonium evokes the entire gamut of human emotions, from good to evil, from hope to despair, from the salvation of humanity to its utter destruction. There is no other element in the periodic table that has had such a profound impact on the consciousness of mankind.

  9. Plutonium Finishing Plant (PFP) Dangerous Waste Training Plan

    Energy Technology Data Exchange (ETDEWEB)

    ENTROP, G.E.

    1999-12-03

    This training plan describes general requirements, worker categories, and provides course descriptions for operation of the plutonium finishing plant (PFP) waste generation facilities, permitted treatment, storage and disposal (TSD) units, and the 90-Day Accumulation Areas.

  10. Plutonium: The first 50 years. United States plutonium production, acquisition, and utilization from 1944 through 1994

    Energy Technology Data Exchange (ETDEWEB)

    None

    1996-02-01

    The report contains important newly declassified information regarding the US production, acquisition, and removals of plutonium. This new information, when combined with previously declassified data, has allowed the DOE to issue, for the first time, a truly comprehensive report on the total DOE plutonium inventory. At the December 7, 1993, Openness Press Conference, the DOE declassified the plutonium inventories at eight locations totaling 33.5 metric tons (MT). This report declassifies the remainder of the DOE plutonium inventory. Newly declassified in this report is the quantity of plutonium at the Pantex Site, near Amarillo, Texas, and in the US nuclear weapons stockpile of 66.1 MT, which, when added to the previously released inventory of 33.5 MT, yields a total plutonium inventory of 99.5 MT. This report will document the sources which built up the plutonium inventory as well as the transactions which have removed plutonium from that inventory. This report identifies four sources that add plutonium to the DOE/DoD inventory, and seven types of transactions which remove plutonium from the DOE/DoD inventory. This report also discusses the nuclear material control and accountability system which records all nuclear material transactions, compares records with inventory and calculates material balances, and analyzes differences to verify that nuclear materials are in quantities as reported. The DOE believes that this report will aid in discussions in plutonium storage, safety, and security with stakeholders as well as encourage other nations to declassify and release similar data. These data will also be available for formulating policies with respect to disposition of excess nuclear materials. The information in this report is based on the evaluation of available records. The information contained in this report may be updated or revised in the future should additional or more detailed data become available.

  11. Determination of Trace Plutonium in Uranium Product by ID-ICP-MS

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Plutonium is strictly limited in the uranium product of spent fuel reprocessing. The analysis of plutonium in uranium product is the key point of product quality control. Plutonium concentration is limited below

  12. USING 3-D MODELING TO IMPROVE THE EFFICIENCY FOR REMOVING PLUTONIUM PROCESSING EQUIMENT FROM GLOVEBOXES AT THE PLUTONIUM FINISHANG PLANT

    Energy Technology Data Exchange (ETDEWEB)

    CROW SH; KYLE RN; MINETTE MJ

    2008-07-15

    The Plutonium Finishing Plant at the Department of Energy's Hanford Site in southeastern Washington State began operations in 1949 to process plutonium and plutonium products. Its primary mission was to produce plutonium metal, fabricate weapons parts, and stabilize reactive materials. These operations, and subsequent activities, were performed in production lines, consisting primarily of hundreds of gloveboxes. Over the years, these gloveboxes and attendant processes have been continuously modified. The plant is currently inactive and Fluor Hanford has been tasked with cleaning out contaminated equipment and gloveboxes from the facility so it can be demolished in the near future. Approximately 100 gloveboxes at PFP have been cleaned out in the past four years and about 90 gloveboxes remain to be cleaned out. Because specific commitment dates for this work have been established with the State of Washington and other entities, it is important to adopt work practices that increase the safety and speed of this effort. The most recent work practice to be adopted by Fluor Hanford D and D workers is the use of 3-D models to make the process of cleaning out the radioactive gloveboxes more efficient. The use of 3-D models has significantly improved the work-planning process by giving workers a clear image of glovebox construction and composition, which in turn is used to determine cleanout methods and work sequences. The 3-D visual products also enhance safety by enabling workers to more easily identify hazards and implement controls. Further, the ability to identify and target the removal of radiological material early in the D and D process provides substantial dose reduction for the workers.

  13. Plutonium immobilization plant using glass in existing facilities at the Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    DiSabatino, A., LLNL

    1998-06-01

    The Plutonium Immobilization Plant (PIP) accepts plutonium (Pu) from pit conversion and from non-pit sources and, through a glass immobilization process, converts the plutonium into an immobilized form that can be disposed of in a high level waste (HLW) repository. The objective is to make an immobilized form, suitable for geologic disposal, in which the plutonium is as inherently unattractive and inaccessible as the plutonium in spent fuel from commercial reactors.

  14. Thermal Stability Studies of Candidate Decontamination Agents for Hanford’s Plutonium Finishing Plant Plutonium-Contaminated Gloveboxes

    Energy Technology Data Exchange (ETDEWEB)

    Scheele, Randall D.; Cooper, Thurman D.; Jones, Susan A.; Ewalt, John R.; Compton, James A.; Trent, Donald S.; Edwards, Matthew K.; Kozelisky, Anne E.; Scott, Paul A.; Minette, Michael J.

    2005-09-29

    This report provides the results of PNNL's and Fluor's studies of the thermal stabilities of potential wastes arising from decontamination of Hanford's Plutonium Finishing Plant's plutonium contaminated gloveboxes. The candidate wastes arising from the decontamination technologies ceric nitrate/nitric acid, RadPro, Glygel, and Aspigel.

  15. Preliminary Materials Transport Plan for the Plutonium Immobilization Plant

    Energy Technology Data Exchange (ETDEWEB)

    Gilkison, J.M.; Dyches, G.M.; Randall, W.J.; Steed, J.H.

    2000-01-26

    This Materials Transport Plan defines the methodology for moving process and non-process materials within the Plutonium Immobilization Plant (PIP) operations. The scope of the plan includes the movement of materials between plant operational units (gloveboxes or operational areas/rooms within the plant). The movements of materials within the various plant operational units are described in the System Design Description prepared for the individual units. The plan provides a design concept for transporting each type of material including the containerization used during the movements. Further, the plan identifies the high-level functions and requirements for movements of the materials.

  16. Plutonium immobilization plant using glass in new facilities at the Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    DiSabatino, A.

    1998-06-01

    The Plutonium Immobilization Plant (PIP) accepts plutonium (Pu) from pit conversion and from non-pit sources and, through a glass immobilization process, converts the plutonium into an immobilized form that can be disposed of in a high level waste (HLW) repository. This immobilization process is shown conceptually in Figure 1-1. The objective is to make an immobilized form, suitable for geologic disposal, in which the plutonium is as inherently unattractive and inaccessible as the plutonium in spent fuel from commercial reactors.

  17. Plutonium in a grassland ecosystem. [Rocky Flats Plant

    Energy Technology Data Exchange (ETDEWEB)

    Little, C.A.

    1976-08-01

    A study was made of plutonium contamination of grassland at the Rocky Flats plant northwest of Denver, Colorado. Of interest were: the definition of major plutonium-containing ecosystem compartments; the relative amounts in those compartments; how those values related to studies done in other geographical areas; whether or not the predominant isotopes, /sup 238/Pu and /sup 239/Pu, behaved differently; and what mechanisms might have allowed for the observed patterns of contamination. Samples of soil, litter, vegetation, arthropods, and small mammals were collected for Pu analysis and mass determination from each of two macroplots. Small aliquots (5 g or less) were analyzed by a rapid liquid scintillation technique and by alpha spectrometry. Of the compartments sampled, greater than 99 percent of the total plutonium was contained in the soil and the concentrations were significantly inversely correlated with distance from the contamination source, depth of the sample, and particle size of the sieved soil samples. The soil data suggested that the distribution of contamination largely resulted from physical transport processes.

  18. THE DEACTIVATION DECONTAMINATION & DECOMMISSIONING OF THE PLUTONIUM FINISHING PLANT (PFP) A FORMER PLUTONIUM PROCESSING FACILITY AT DOE HANFORD SITE

    Energy Technology Data Exchange (ETDEWEB)

    CHARBONEAU, S.L.

    2006-02-01

    The Plutonium Finishing Plant (PFP) was constructed as part of the Manhattan Project during World War II. The Manhattan Project was developed to usher in the use of nuclear weapons to end the war. The primary mission of the PFP was to provide plutonium used as special nuclear material (SNM) for fabrication of nuclear devices for the war effort. Subsequent to the end of World War II, the PFP's mission expanded to support the Cold War effort through plutonium production during the nuclear arms race and later the processing of fuel grade mixed plutonium-uranium oxide to support DOE's breeder reactor program. In October 1990, at the close of the production mission for PFP, a shutdown order was prepared by the Department of Energy (DOE) in Washington, DC and issued to the Richland DOE field office. Subsequent to the shutdown order, a team from the Defense Nuclear Facilities Safety Board (DNFSB) analyzed the hazards at PFP associated with the continued storage of certain forms of plutonium solutions and solids. The assessment identified many discrete actions that were required to stabilize the different plutonium forms into stable form and repackage the material in high integrity containers. These actions were technically complicated and completed as part of the PFP nuclear material stabilization project between 1995 and early 2005. The completion of the stabilization project was a necessary first step in deactivating PFP. During stabilization, DOE entered into negotiations with the U.S. Environmental Protection Agency (EPA) and the State of Washington and established milestones for the Deactivation and Decommissioning (D&D) of the PFP. The DOE and its contractor, Fluor Hanford (Fluor), have made great progress in deactivating, decontaminating and decommissioning the PFP at the Hanford Site as detailed in this paper. Background information covering the PFP D&D effort includes descriptions of negotiations with the State of Washington concerning consent

  19. Kr-85 signatures for various plutonium production schemes

    Energy Technology Data Exchange (ETDEWEB)

    Stanoszek, Paul [Carl Friedrich von Weizsaecker-Centre for Science and Peace Research (Germany)

    2009-07-01

    Kr-85 is considered to be the best atmospheric indicator of unreported weapon-grade material production. This fact is based on the half-life of 10.76 years of Kr-85 and its chemical inactivity, which makes it even detectable after extended periods of cooling time. Kr-85 is produced as fission product during nuclear reactor operation and remains in the fuel until reprocessing starts. In order to determine the detectability of plutonium production the Kr-85 source term has to be assessed. The important issue of this presentation is the question on the minimum signal that an inspector can expect under the assumption that a proliferator minimizes his Kr-85 generation in order to circumvent a Kr-85 detection. A further assumption is that for nuclear weapon production a burn-up of typically around 2 MWd/kg is used. In addition, if clandestine plutonium production takes place, the source term might be used to estimate the amount of separated plutonium. The methodology of this study is based on a linkage between MCNPX and MATLAB. All results for actinide concentrations and Kr-85 are evaluated for different enrichments of U-235 and compared to known literature data. The Kr-85 source term per kilogram plutonium depends on the enrichments. As a result the lowest Kr-85 source term is found for depleted uranium.

  20. ORNL review of TRUEX flowsheet proposed for deployment at the Rockwell Hanford Plutonium Finishing Plant

    Energy Technology Data Exchange (ETDEWEB)

    Bond, W.D.; Bell, J.T.; Campbell, D.O.; Collins, E.D.

    1987-03-01

    The Transuranium Extraction (TRUEX) process will be installed at the Rockwell Hanford Operations (RHO) Plutonium Finishing Plant (PFP). The purposes are to process the PFP waste to recover the plutonium, to isolate the americium, and to have the remaining waste converted to a non-TRU waste. Rockwell requested that ORNL provide an outside review of the process and its implementation. This review addresses the generation of the TRUEX feed, the chemical flowsheet, and the products and raffinates. It suggests that present PFP operations be modified to reduce the amount of transuranium elements that will be in the TRUEX process feed. This review also includes an assessment of the TRUEX solvent extraction flowsheet on the bases of material balance, adequate extraction and stripping stages, and solvent cleanup. The final part of the review includes results of three-party discussions (RHO, ORNL, and Argonne National Laboratory (ANL)) of some major issues.

  1. Plutonium immobilization plant using ceramic in existing facilities at the Savannah River site

    Energy Technology Data Exchange (ETDEWEB)

    DiSabatino, A., LLNL

    1998-06-01

    The Plutonium Immobilization Plant (PIP) accepts plutonium (Pu) from pit conversion and from non-pit sources, and through a ceramic immobilization process converts the plutonium into an immobilized form that can be disposed of in a high level waste (HLW) repository. This immobilization process is shown conceptually in Figure 1-1. The objective is to make an immobilized form, suitable for geologic disposal, in which the plutonium is as inherently unattractive and inaccessible as the plutonium in spent fuel from commercial reactors. The ceramic immobilization alternative presented in this report consists of first converting the surplus material to an oxide, followed by incorporating the plutonium oxide into a titanate-based ceramic material that is placed in metal cans.

  2. Experience gained with the Synroc demonstration plant at ANSTO and its relevance to plutonium immobilization

    Energy Technology Data Exchange (ETDEWEB)

    Jostsons, A.; Ridal, A.; Mercer, D.J.; Vance, E.R.L. [Australian Nuclear Science and Technology Organisation, Menai (Australia)

    1996-05-01

    The Synroc Demonstration Plant (SDP) was designed and constructed at Lucas Heights to demonstrate the feasibility of Synroc production on a commercial scale (10 kg/hr) with simulated Purex liquid HLW. Since commissioning of the SDP in 1987, over 6000 kg of Synroc has been fabricated with a range of feeds and waste loadings. The SDP utilises uniaxial hot-pressing to consolidate Synroc. Pressureless sintering and hot-isostatic pressing have also been studied at smaller scales. The results of this extensive process development have been incorporated in a conceptual design for a radioactive plant to condition HLW from a reprocessing plant with a capacity to treat 800 tpa of spent LWR fuel. Synroic containing TRU, including Pu, and fission products has been fabricated and characterised in a glove-box facility and hot cells, respectively. The extensive experience in processing of Synroc over the past 15 years is summarised and its relevance to immobilization of surplus plutonium is discussed.

  3. Idaho Chemical Processing Plant and Plutonium-Uranium Extraction Plant phaseout/deactivation study

    Energy Technology Data Exchange (ETDEWEB)

    Patterson, M.W. [Westinghouse Idaho Nuclear Co., Idaho Falls, ID (United States); Thompson, R.J. [Westinghouse Hanford Co., Richland, WA (United States)

    1994-01-01

    The decision to cease all US Department of Energy (DOE) reprocessing of nuclear fuels was made on April 28, 1992. This study provides insight into and a comparison of the management, technical, compliance, and safety strategies for deactivating the Idaho Chemical Processing Plant (ICPP) at Westinghouse Idaho Nuclear Company (WINCO) and the Westinghouse Hanford Company (WHC) Plutonium-Uranium Extraction (PUREX) Plant. The purpose of this study is to ensure that lessons-learned and future plans are coordinated between the two facilities.

  4. 10 CFR 140.13a - Amount of financial protection required for plutonium processing and fuel fabrication plants.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Amount of financial protection required for plutonium... of financial protection required for plutonium processing and fuel fabrication plants. (a) Each holder of a license issued pursuant to part 70 of this chapter to possess and use plutonium at...

  5. Sludge stabilization at the Plutonium Finishing Plant, Hanford Site, Richland, Washington

    Energy Technology Data Exchange (ETDEWEB)

    1994-10-01

    This Environmental Assessment evaluates the proposed action to operate two laboratory-size muffle furnaces in glovebox HC-21C, located in the Plutonium Finishing Plant (PFP), Hanford Site, Richland, Washington. The muffle furnaces would be used to stabilize chemically reactive sludges that contain approximately 25 kilograms (55 pounds) of plutonium by heating to approximately 500 to 1000{degrees}C (900 to 1800{degrees}F). The resulting stable powder, mostly plutonium oxide with impurities, would be stored in the PFP vaults. The presence of chemically reactive plutonium-bearing sludges in the process gloveboxes poses a risk to workers from radiation exposure and limits the availability of storage space for future plant cleanup. Therefore, there is a need to stabilize the material into a form suitable for long-term storage. This proposed action would be an interim action, which would take place prior to completion of an Environmental Impact Statement for the PFP which would evaluate stabilization of all plutonium-bearing materials and cleanout of the facility. However, only 10 percent of the total quantity of plutonium in reactive materials is in the sludges, so this action will not limit the choice of reasonable alternatives or prejudice the Record of Decision of the Plutonium Finishing Plant Environmental Impact Statement.

  6. A review of plutonium oxalate decomposition reactions and effects of decomposition temperature on the surface area of the plutonium dioxide product

    Science.gov (United States)

    Orr, R. M.; Sims, H. E.; Taylor, R. J.

    2015-10-01

    Plutonium (IV) and (III) ions in nitric acid solution readily form insoluble precipitates with oxalic acid. The plutonium oxalates are then easily thermally decomposed to form plutonium dioxide powder. This simple process forms the basis of current industrial conversion or 'finishing' processes that are used in commercial scale reprocessing plants. It is also widely used in analytical or laboratory scale operations and for waste residues treatment. However, the mechanisms of the thermal decompositions in both air and inert atmospheres have been the subject of various studies over several decades. The nature of intermediate phases is of fundamental interest whilst understanding the evolution of gases at different temperatures is relevant to process control. The thermal decomposition is also used to control a number of powder properties of the PuO2 product that are important to either long term storage or mixed oxide fuel manufacturing. These properties are the surface area, residual carbon impurities and adsorbed volatile species whereas the morphology and particle size distribution are functions of the precipitation process. Available data and experience regarding the thermal and radiation-induced decompositions of plutonium oxalate to oxide are reviewed. The mechanisms of the thermal decompositions are considered with a particular focus on the likely redox chemistry involved. Also, whilst it is well known that the surface area is dependent on calcination temperature, there is a wide variation in the published data and so new correlations have been derived. Better understanding of plutonium (III) and (IV) oxalate decompositions will assist the development of more proliferation resistant actinide co-conversion processes that are needed for advanced reprocessing in future closed nuclear fuel cycles.

  7. Disposition of plutonium-239 via production of fission molybdenum-99.

    Science.gov (United States)

    Mushtaq, A

    2011-04-01

    A heritage of physical consequences of the U.S.-Soviet arms race has accumulated, the weapons-grade plutonium (WPu), which will become excess as a result of the dismantlement of the nuclear weapons under the arms reduction agreements. Disposition of Pu has been proposed by mixing WPu with high-level radioactive waste with subsequent vitrification into large, highly radioactive glass logs or fabrication into mixed oxide fuel with subsequent irradiation in existing light water reactors. A potential option may be the production of medical isotope molybdenum-99 by using Pu-239 targets.

  8. Fire hazard analysis for Plutonium Finishing Plant complex

    Energy Technology Data Exchange (ETDEWEB)

    MCKINNIS, D.L.

    1999-02-23

    A fire hazards analysis (FHA) was performed for the Plutonium Finishing Plant (PFP) Complex at the Department of Energy (DOE) Hanford site. The scope of the FHA focuses on the nuclear facilities/structures in the Complex. The analysis was conducted in accordance with RLID 5480.7, [DOE Directive RLID 5480.7, 1/17/94] and DOE Order 5480.7A, ''Fire Protection'' [DOE Order 5480.7A, 2/17/93] and addresses each of the sixteen principle elements outlined in paragraph 9.a(3) of the Order. The elements are addressed in terms of the fire protection objectives stated in paragraph 4 of DOE 5480.7A. In addition, the FHA also complies with WHC-CM-4-41, Fire Protection Program Manual, Section 3.4 [1994] and WHC-SD-GN-FHA-30001, Rev. 0 [WHC, 1994]. Objectives of the FHA are to determine: (1) the fire hazards that expose the PFP facilities, or that are inherent in the building operations, (2) the adequacy of the fire safety features currently located in the PFP Complex, and (3) the degree of compliance of the facility with specific fire safety provisions in DOE orders, related engineering codes, and standards.

  9. 10 CFR Appendix J to Part 110 - Illustrative List of Uranium Conversion Plant Equipment and Plutonium Conversion Plant Equipment...

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Illustrative List of Uranium Conversion Plant Equipment and Plutonium Conversion Plant Equipment Under NRC Export Licensing Authority J Appendix J to Part 110.... 110, App. J Appendix J to Part 110—Illustrative List of Uranium Conversion Plant Equipment...

  10. Vitrification of plutonium at Rocky Flats the argument for a pilot plant

    Energy Technology Data Exchange (ETDEWEB)

    Moore, L. [Rocky Mountain Peace Center, Boulder, CO (United States)

    1996-05-01

    Current plans for stabilizing and storing the plutonium at Rocky Flats Plant fail to put the material in a form suitable for disposition and resistant to proliferation. Vitrification should be considered as an alternate technology. The vitrification should begin with a small-scale pilot plant.

  11. Enzymatic degradation of plutonium-contaminated cellulose products

    Energy Technology Data Exchange (ETDEWEB)

    Heintz, C.E.; Rainwater, K.A.; Swift, L.M. [Texas Tech Univ., Lubbock, TX (United States); Barnes, D.L. [Amarillo National Resource Center for Plutonium, TX (United States); Worl, L.; Avens, L. [Los Alamos National Lab., NM (United States)

    1999-03-01

    Enzyme solutions produced for commercial purposes unrelated to waste management have the potential for reducing the volume of wastes in streams containing cellulose, lipid and protein materials. For example, the authors have shown that cellulases used in denim production and in detergent formulations are able to digest cellulose-containing sorbents and other cellulose-based wastes contaminated either with crude oil or with radionuclides. This presentation describes the use of one such enzyme preparation (Rapidase{trademark}) for the degradation of cotton sorbents intentionally contaminated with low levels of plutonium. This is part of a feasibility study to determine if such treatments have a role in reducing the volume of low level and transuranic wastes to minimize the amount of radionuclide-contaminated waste that must be disposed of in secured storage areas.

  12. Enzymatic degradation of plutonium-contaminated cellulose products

    Energy Technology Data Exchange (ETDEWEB)

    Heintz, C.E.; Rainwater, K.A.; Swift, L.M. [Texas Tech Univ., Lubbock, TX (United States); Barnes, D.L. [Amarillo National Resource Center for Plutonium, TX (United States); Worl, L.A. [Los Alamos National Lab., NM (United States)

    1999-06-01

    Enzyme solutions produced for commercial purposes unrelated to waste management have the potential for reducing the volume of wastes in streams containing cellulose, lipid and protein materials. For example, the authors have shown previously that cellulases used in denim production and in detergent formulations are able to digest cellulose-containing sorbents and other cellulose-based wastes contaminated either with crude oil or with uranium. This presentation describes the use of one such enzyme preparation (Rapidase{trademark}, manufactured by Genencor, Rochester, NY) for the degradation of cotton sorbents intentionally contaminated with low levels of plutonium. This is part of a feasibility study to determine if such treatments have a role in reducing the volume of low level and transuranic wastes to minimize the amount of radionuclide-contaminated waste destined for costly disposal options.

  13. Plutonium production story at the Hanford site: processes and facilities history

    Energy Technology Data Exchange (ETDEWEB)

    Gerber, M.S., Westinghouse Hanford

    1996-06-20

    This document tells the history of the actual plutonium production process at the Hanford Site. It contains five major sections: Fuel Fabrication Processes, Irradiation of Nuclear Fuel, Spent Fuel Handling, Radiochemical Reprocessing of Irradiated Fuel, and Plutonium Finishing Operations. Within each section the story of the earliest operations is told, along with changes over time until the end of operations. Chemical and physical processes are described, along with the facilities where these processes were carried out. This document is a processes and facilities history. It does not deal with the waste products of plutonium production.

  14. Plutonium Story

    Science.gov (United States)

    Seaborg, G. T.

    1981-09-01

    The first nuclear synthesis and identification (i.e., the discovery) of the synthetic transuranium element plutonium (isotope /sup 238/Pu) and the demonstration of its fissionability with slow neutrons (isotope /sup 239/Pu) took place at the University of California, Berkeley, through the use of the 60-inch and 37-inch cyclotrons, in late 1940 and early 1941. This led to the development of industrial scale methods in secret work centered at the University of Chicago's Metallurgical Laboratory and the application of these methods to industrial scale production, at manufacturing plants in Tennessee and Washington, during the World War II years 1942 to 1945. The chemical properties of plutonium, needed to devise the procedures for its industrial scale production, were studied by tracer and ultramicrochemical methods during this period on an extraordinarily urgent basis. This work, and subsequent investigations on a worldwide basis, have made the properties of plutonium very well known. Its well studied electronic structure and chemical properties give it a very interesting position in the actinide series of inner transition elements.

  15. Literature review: Phytoaccumulation of chromium, uranium, and plutonium in plant systems

    Energy Technology Data Exchange (ETDEWEB)

    Hossner, L.R.; Loeppert, R.H.; Newton, R.J. [Texas A& M Univ., College Station, TX (United States); Szaniszlo, P.J. [Univ. of Texas, Austin, TX (United States)

    1998-05-01

    Phytoremediation is an integrated multidisciplinary approach to the cleanup of contaminated soils, which combines the disciplines of plant physiology, soil chemistry, and soil microbiology. Metal hyperaccumulator plants are attracting increasing attention because of their potential application in decontamination of metal-polluted soils. Traditional engineering technologies may be too expensive for the remediation of most sites. Removal of metals from these soils using accumulator plants is the goal of phytoremediation. The emphasis of this review has been placed on chromium (Cr), plutonium (Pu), and uranium (U). With the exception of Cr, these metals and their decay products exhibit two problems, specifically, radiation dose hazards and their chemical toxicity. The radiation hazard introduces the need for special precautions in reclamation beyond that associated with non-radioactive metals. The uptake of beneficial metals by plants occurs predominantly by way of channels, pores, and transporters in the root plasma membrane. Plants characteristically exhibit a remarkable capacity to absorb what they need and exclude what they don`t need. But most vascular plants absorb toxic and heavy metals through their roots to some extent, though to varying degrees, from negligible to substantial. Sometimes absorption occurs because of the chemical similarity between beneficial and toxic metals. Some plants utilize exclusion mechanisms, where there is a reduced uptake by the roots or a restricted transport of the metal from root to shoot. At the other extreme, hyperaccumulator plants absorb and concentrate metals in both roots and shoots. Some plant species endemic to metalliferous soils accumulate metals in percent concentrations in the leaf dry matter.

  16. MA Doping Analysis on Breeding Capability and Protected Plutonium Production of Large FBR

    Science.gov (United States)

    Permana, Sidik; Suzuki, Mitsutoshi; Kuno, Yusuke

    2010-06-01

    Spent fuel from LWR can be seen as long-live waste if it is not recycled or as a "new fuel" resource if it is recycled into the reactors. Uranium and plutonium have been used for "new fuel" resources from LWR spent fuel as MOX fuel type which is loaded into thermal reactor or fast reactor types. Other actinides from the spent fuel such as neptunium, americium and curium as minor actinide (MA) are considered to be loaded into the reactors for specific purposes, recently. Those purposes such as for increasing protected plutonium production and breeding capability for protected plutonium as well as in the same time those amount of MA can be reduced to a small quantity as a burner or transmutation purpose. Some investigations and scientific approaches are performed in order to increase a material "barrier" in plutonium isotope composition by increasing the even mass number of plutonium isotope such as Pu-238, Pu-240 and Pu-242 as plutonium protected composition. Higher material barrier which related to intrinsic properties of plutonium isotopes with even mass number (Pu-238, Pu-240 and Pu-242), are recognized because of their intense decay heat (DH) and high spontaneous fission neutron (SFN) rates. Those even number mass of plutonium isotope contribute to some criteria of plutonium characterization which will be adopted for present study such as IAEA, Pellaud and Kessler criteria (IAEA, 1972; Pellaud, 2002; and Kessler, 2007). The present paper intends to evaluate the breeding capability as a fuel sustainability index of the reactors and to analyze the composition of protected plutonium production of large power reactor based on the FaCT FBR as reference (Ohki, et al., 2008). Three dimensional FBR core configuration has been adopted which is based on the core optimization calculation of SRAC-CITATION code as reactor core analysis and JENDL-3.3 is adopted for nuclear data library. Some MA doping materials are loaded into the blanket regions which can be considered as

  17. EIS Data Call Report: Plutonium immobilization plant using ceramic in new facilities at the Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    DiSabatino, A.

    1998-06-01

    The Plutonium Immobilization Plant (PIP) accepts plutonium (Pu) from pit conversion and from non-pit sources and, through a ceramic immobilization process, converts the plutonium into an immobilized form that can be disposed of in a high level waste (HLW) repository. This immobilization process is shown conceptually in Figure 1-1. The objective is to make an immobilized form, suitable for geologic disposal, in which the plutonium is as inherently unattractive and inaccessible as the plutonium in spent fuel from commercial reactors. The ceramic immobilization alternative presented in this report consists of first converting the surplus material to an oxide, followed by incorporating the plutonium oxide into a titanate-based ceramic material that is placed in metal cans.

  18. Characterization of past and present solid waste streams from the Plutonium-Uranium Extraction Plant

    Energy Technology Data Exchange (ETDEWEB)

    Pottmeyer, J.A.; Weyns, M.I.; Lorenzo, D.S.; Vejvoda, E.J. [Los Alamos Technical Associates, Inc., NM (US); Duncan, D.R. [Westinghouse Hanford Co., Richland, WA (US)

    1993-04-01

    During the next two decades the transuranic wastes, now stored in the burial trenches and storage facilities at the Hanford Site, are to be retrieved, processed at the Waste Receiving and Processing Facility, and shipped to the Waste Isolation Pilot Plant near Carlsbad, New Mexico for final disposal. Over 7% of the transuranic waste to be retrieved for shipment to the Waste Isolation Pilot Plant has been generated at the Plutonium-Uranium Extraction (PUREX) Plant. The purpose of this report is to characterize the radioactive solid wastes generated by PUREX using process knowledge, existing records, and oral history interviews. The PUREX Plant is currently operated by the Westinghouse Hanford Company for the US Department of Energy and is now in standby status while being prepared for permanent shutdown. The PUREX Plant is a collection of facilities that has been used primarily to separate plutonium for nuclear weapons from spent fuel that had been irradiated in the Hanford Site`s defense reactors. Originally designed to reprocess aluminum-clad uranium fuel, the plant was modified to reprocess zirconium alloy clad fuel elements from the Hanford Site`s N Reactor. PUREX has provided plutonium for research reactor development, safety programs, and defense. In addition, the PUREX was used to recover slightly enriched uranium for recycling into fuel for use in reactors that generate electricity and plutonium. Section 2.0 provides further details of the PUREX`s physical plant and its operations. The PUREX Plant functions that generate solid waste are as follows: processing operations, laboratory analyses and supporting activities. The types and estimated quantities of waste resulting from these activities are discussed in detail.

  19. SEPARATION OF PLUTONIUM

    Science.gov (United States)

    Maddock, A.G.; Smith, F.

    1959-08-25

    A method is described for separating plutonium from uranium and fission products by treating a nitrate solution of fission products, uranium, and hexavalent plutonium with a relatively water-insoluble fluoride to adsorb fission products on the fluoride, treating the residual solution with a reducing agent for plutonium to reduce its valence to four and less, treating the reduced plutonium solution with a relatively insoluble fluoride to adsorb the plutonium on the fluoride, removing the solution, and subsequently treating the fluoride with its adsorbed plutonium with a concentrated aqueous solution of at least one of a group consisting of aluminum nitrate, ferric nitrate, and manganous nitrate to remove the plutonium from the fluoride.

  20. Characterization of past and present solid waste streams from the plutonium finishing plant

    Energy Technology Data Exchange (ETDEWEB)

    Duncan, D R; Mayancsik, B A [Westinghouse Hanford Co., Richland, WA (United States); Pottmeyer, J A; Vejvoda, E J; Reddick, J A; Sheldon, K M; Weyns, M I [Los Alamos Technical Associates, Kennewick, WA (United States)

    1993-02-01

    During the next two decades the transuranic (TRU) wastes now stored in the burial trenches and storage facilities at the Hanford Site are to be retrieved, processed at the Waste Receiving and Processing (WRAP) Facility, and shipped to the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico for final disposal. Over 50% of the TRU waste to be retrieved for shipment to the WIPP has been generated at the Plutonium Finishing Plant (PFP), also known as the Plutonium Processing and Storage Facility and Z Plant. The purpose of this report is to characterize the radioactive solid wastes generated by the PFP since its construction in 1947 using process knowledge, existing records, and history-obtained from interviews. The PFP is currently operated by Westinghouse Hanford Company (WHC) for the US Department of Energy (DOE).

  1. Plutonium contamination issues in Hanford soils and sediments: Discharges from the Z-Plant (PFP) complex

    Science.gov (United States)

    Felmy, Andrew R.; Cantrell, Kirk J.; Conradson, Steven D.

    Beginning in 1945, weapons production activities at the Hanford Nuclear Reservation resulted in the discharge of large quantities of Pu and other transuranic elements to the subsurface. The vast majority of the transuranics was disposed in the Hanford central plateau (200 areas) predominately associated with activities at the Z-Plant (Plutonium Finishing Plant) complex. In the past Pu and Am migrated deep into the subsurface at certain locations, although Pu and other transuranics are not currently being detected in significant concentration in any associated groundwaters. Evaluation of the chemical form of the transuranics in the subsurface along with determining the mechanism(s) of the past subsurface migration is important in establishing strategies for long-term site management practices. Unfortunately, the chemical form of the transuranics in the deep subsurface sediments and the past mechanism of vertical migration remain largely unknown. However, initial studies performed as part of this research indicate that the chemical form of Pu can vary from disposal site to disposal site depending upon the waste type and the chemical form can also differ between surface sediments and deep subsurface sediments at the same site. This paper present a summary of the different waste types and locations where transuranics were disposed, the factors that could have lead to subsurface migration via different transport vectors, the information currently available on the chemical form of Pu in the subsurface, and a summary of current research needs.

  2. Plutonium Contamination Issues in Hanford Soils and Sediments: Discharges from the Z-Plant (PFP) Complex

    Energy Technology Data Exchange (ETDEWEB)

    Felmy, Andrew R.; Cantrell, Kirk J.; Conradson, Steven D.

    2010-08-23

    Beginning in 1945, weapons production activities at the Hanford Nuclear Reservation resulted in the discharge of large quantities of Pu and other transuranic elements to the subsurface. The vast majority of the transuranics were disposed in the Hanford central plateau (200 areas) predominately associated with activities at the Z-Plant (Plutonium Finishing Plant) complex. In the past the Pu and Am migrated deep into the subsurface at certain locations, although the Pu and other transuranics are not currently being detected in significant concentration in any associated groundwaters. Evaluation of the chemical form of the transuranics in the subsurface along with determining the mechanism(s) of the past subsurface migration is important in establishing strategies for long-term site management practices. Unfortunately, the chemical form of the transuranics in the deep subsurface sediments and the past mechanism of vertical migration remain largely unknown. This paper present a summary of the different waste types and locations where transuranics were disposed, the factors that could have lead to subsurface migration via different transport vectors, the information currently available on the chemical form of Pu in the subsurface, and a summary of current research needs.

  3. Project Plan Remove Special Nuclear Material (SNM) from Plutonium Finishing Plant (PFP) Project

    Energy Technology Data Exchange (ETDEWEB)

    BARTLETT, W.D.

    1999-09-14

    This plan presents the overall objectives, description, justification and planning for the Plutonium Finishing Plant (PFP) Remove SNM Materials. The intent of this plan is to describe how this project will be managed and integrated with other facility stabilization and deactivation activities. This plan supplements the overall integrated plan presented in the Plutonium Finishing Plant Integrated Project Management Plan (IPMP), HNF-3617, Rev.0. This project plan is the top-level definitive project management document for the PFP Remove SNM Materials project. It specifies the technical, schedule, requirements and the cost baseline to manage the execution of the Remove SNM Materials project. Any deviation to the document must be authorized through the appropriate change control process. The Remove SNM Materials project provides the necessary support and controls required for DOE-HQ, DOE-RL, BWHC, and other DOE Complex Contractors the path forward to negotiate shipped/receiver agreements, schedule shipments, and transfer material out of PFP to enable final deactivation.

  4. Plutonium Finishing Plant (PFP) Standards/Requirements Identification Document (S/RID)

    Energy Technology Data Exchange (ETDEWEB)

    Maddox, B.S.

    1996-01-01

    This Standards/Requirements Identification Document (S/RID) sets forth the Environmental Safety and Health (ESH) standards/requirements for the Plutonium Finishing Plant (PFP). This S/RID is applicable to the appropriate life cycle phases of design, construction, operation, and preparation for decommissioning. These standards/requirements are adequate to ensure the protection of the health and safety of workers, the public, and the environment.

  5. Structural evaluation of existing plutonium buildings and auxiliary structures at Rocky Flats Plant

    Energy Technology Data Exchange (ETDEWEB)

    1980-02-01

    Existing plutonium handling and storage buildings at the DOE Rocky Flats Plant were evaluated for their structural resistance to seismic, tornado, and extreme wind loadings and the impact of tornado-driven missiles. This report presents the summary results of the study for all the buildings included in the study and makes preliminary general recommendations for upgrading where needed. Detailed analyses and backup calculations performed for the several buildings are presented in separate reports.

  6. Total Measurement Uncertainty for the Plutonium Finishing Plant (PFP) Segmented Gamma Scan Assay System

    CERN Document Server

    Fazzari, D M

    2001-01-01

    This report presents the results of an evaluation of the Total Measurement Uncertainty (TMU) for the Canberra manufactured Segmented Gamma Scanner Assay System (SGSAS) as employed at the Hanford Plutonium Finishing Plant (PFP). In this document, TMU embodies the combined uncertainties due to all of the individual random and systematic sources of measurement uncertainty. It includes uncertainties arising from corrections and factors applied to the analysis of transuranic waste to compensate for inhomogeneities and interferences from the waste matrix and radioactive components. These include uncertainty components for any assumptions contained in the calibration of the system or computation of the data. Uncertainties are propagated at 1 sigma. The final total measurement uncertainty value is reported at the 95% confidence level. The SGSAS is a gamma assay system that is used to assay plutonium and uranium waste. The SGSAS system can be used in a stand-alone mode to perform the NDA characterization of a containe...

  7. The chemistry of tributyl phosphate at elevated temperatures in the Plutonium Finishing Plant Process Vessels

    Energy Technology Data Exchange (ETDEWEB)

    Barney, G.S.; Cooper, T.D.

    1994-06-01

    Potentially violent chemical reactions of the tributyl phosphate solvent used by the Plutonium Finishing Plant at the Hanford Site were investigated. There is a small probability that a significant quantity of this solvent could be accidental transferred to heated process vessels and react there with nitric acid or plutonium nitrate also present in the solvent extraction process. The results of laboratory studies of the reactions show that exothermic oxidation of tributyl phosphate by either nitric acid or actinide nitrates is slow at temperatures expected in the heated vessels. Less than four percent of the tributyl phosphate will be oxidized in these vented vessels at temperatures between 125{degrees}C and 250{degrees}C because the oxidant will be lost from the vessels by vaporization or decomposition before the tributyl phosphate can be extensively oxidized. The net amounts of heat generated by oxidation with concentrated nitric acid and with thorium nitrate (a stand-in for plutonium nitrate) were determined to be about -150 and -220 joules per gram of tributyl phosphate initially present, respectively. This is not enough heat to cause violent reactions in the vessels. Pyrolysis of the tributyl phosphate occurred in these mixtures at temperatures of 110{degrees}C to 270{degrees}C and produced mainly 1-butene gas, water, and pyrophosphoric acid. Butene gas generation is slow at expected process vessel temperatures, but the rate is faster at higher temperatures. At 252{degrees}C the rate of butene gas generated was 0.33 g butene/min/g of tributyl phosphate present. The measured heat absorbed by the pyrolysis reaction was 228 J/g of tributyl phosphate initially present (or 14.5 kcal/mole of tributyl phosphate). Release of flammable butene gas into process areas where it could ignite appears to be the most serious safety consideration for the Plutonium Finishing Plant.

  8. ASSESSING CHEMICAL HAZARDS AT THE PLUTONIUM FINISHING PLANT (PFP) FOR PLANNING FUTURE D&D

    Energy Technology Data Exchange (ETDEWEB)

    HOPKINS, A.M.; KLOS, D.B.; MINETT, M.J.

    2007-01-25

    This paper documents the fiscal year (FY) 2006 assessment to evaluate potential chemical and radiological hazards associated with vessels and piping in the former plutonium process areas at Hanford's Plutonium Finishing Plant (PFP). Evaluations by PFP engineers as design authorities for specific systems and other subject-matter experts were conducted to identify the chemical hazards associated with transitioning the process areas for the long-term layup of PFP before its eventual final decontamination and decommissioning (D and D). D and D activities in the main process facilities were suspended in September 2005 for a period of between 5 and 10 years. A previous assessment conducted in FY 2003 found that certain activities to mitigate chemical hazards could be deferred safely until the D and D of PFP, which had been scheduled to result in a slab-on-grade condition by 2009. As a result of necessary planning changes, however, D and D activities at PFP will be delayed until after the 2009 time frame. Given the extended project and plant life, it was determined that a review of the plant chemical hazards should be conducted. This review to determine the extended life impact of chemicals is called the ''Plutonium Finishing Plant Chemical Hazards Assessment, FY 2006''. This FY 2006 assessment addresses potential chemical and radiological hazard areas identified by facility personnel and subject-matter experts who reevaluated all the chemical systems (items) from the FY 2003 assessment. This paper provides the results of the FY 2006 chemical hazards assessment and describes the methodology used to assign a hazard ranking to the items reviewed.

  9. 78 FR 1848 - Plutonium-238 Production for Radioisotope Power Systems for National Aeronautics and Space...

    Science.gov (United States)

    2013-01-09

    ... Plutonium-238 Production for Radioisotope Power Systems for National Aeronautics and Space Administration...-238 (Pu-238) for radioisotope power systems (RPSs) to support the National Aeronautics and Space... Radioisotope Power Systems (Draft Consolidation EIS) in 2005 to consolidate the nuclear operations related...

  10. Accelerator-based conversion (ABC) of weapons plutonium: Plant layout study and related design issues

    Energy Technology Data Exchange (ETDEWEB)

    Cowell, B.S.; Fontana, M.H. [Oak Ridge National Lab., TN (United States); Krakowski, R.A.; Beard, C.A.; Buksa, J.J.; Davidson, J.W.; Sailor, W.C.; Williamson, M.A. [Los Alamos National Lab., NM (United States)

    1995-04-01

    In preparation for and in support of a detailed R and D Plan for the Accelerator-Based Conversion (ABC) of weapons plutonium, an ABC Plant Layout Study was conducted at the level of a pre-conceptual engineering design. The plant layout is based on an adaptation of the Molten-Salt Breeder Reactor (MSBR) detailed conceptual design that was completed in the early 1070s. Although the ABC Plant Layout Study included the Accelerator Equipment as an essential element, the engineering assessment focused primarily on the Target; Primary System (blanket and all systems containing plutonium-bearing fuel salt); the Heat-Removal System (secondary-coolant-salt and supercritical-steam systems); Chemical Processing; Operation and Maintenance; Containment and Safety; and Instrumentation and Control systems. Although constrained primarily to a reflection of an accelerator-driven (subcritical) variant of MSBR system, unique features and added flexibilities of the ABC suggest improved or alternative approaches to each of the above-listed subsystems; these, along with the key technical issues in need of resolution through a detailed R&D plan for ABC are described on the bases of the ``strawman`` or ``point-of-departure`` plant layout that resulted from this study.

  11. Uptake and translocation of plutonium in two plant species using hydroponics.

    Science.gov (United States)

    Lee, J H; Hossner, L R; Attrep, M; Kung, K S

    2002-01-01

    This study presents determinations of the uptake and translocation of Pu in Indian mustard (Brassica juncea) and sunflower (Helianthus annuus) from Pu contaminated solution media. The initial activity levels of Pu were 18.50 and 37.00 Bq ml(-1), for Pu-nitrate [239Pu(NO3)4] and for Pu-citrate [239Pu(C6H5O7)+] in nutrient solution. Plutonium-diethylenetriaminepentaacetic acid (DTPA: [239Pu-C14H23O10N3] solution was prepared by adding 0, 5, 10, and 50 microg of DTPA ml(-1) with 239Pu(NO3)4 in nutrient solution. Concentration ratios (CR, Pu concentration in dry plant material/Pu concentration in nutrient solution) and transport indices (Tl, Pu content in the shoot/Pu content in the whole plant) were calculated to evaluate Pu uptake and translocation. All experiments were conducted in hydroponic solution in an environmental growth chamber. Plutonium concentration in the plant tissue was increased with increased Pu contamination. Plant tissue Pu concentration for Pu-nitrate and Pu-citrate application was not correlated and may be dependent on plant species. For plants receiving Pu-DTPA, the Pu concentration was increased in the shoots but decreased in the roots resulting in a negative correlation between the Pu concentrations in the plant shoots and roots. The Pu concentration in shoots of Indian mustard was increased for application rates up to 10 microg DTPA ml(-1) and up to 5 microg DTPA ml(-1) for sunflower. Similar trends were observed for the CR of plants compared to the Pu concentration in the shoots and roots, whereas the Tl was increased with increasing DTPA concentration. Plutonium in shoots of Indian mustard was up to 10 times higher than that in shoots of sunflower. The Pu concentration in the apparent free space (AFS) of plant root tissue of sunflower was more affected by concentration of DTPA than that of Indian mustard.

  12. Effects Influencing Plutonium-Absorber Interactions and Distributions in Routine and Upset Waste Treatment Plant Operations

    Energy Technology Data Exchange (ETDEWEB)

    Delegard, Calvin H. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Sinkov, Sergey I. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fiskum, Sandra K. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-05-01

    This report is the third in a series of analyses written in support of a plan to revise the Hanford Waste Treatment and Immobilization Plant (WTP) Preliminary Criticality Safety Evaluation Report (CSER) that is being implemented at the request of the U.S. Department of Energy (DOE) Criticality Safety Group. A report on the chemical disposition of plutonium in Hanford tank wastes was prepared as Phase 1 of this plan (Delegard and Jones 2015). Phase 2 is the provision of a chemistry report to describe the potential impacts on criticality safety of waste processing operations within the WTP (Freer 2014). In accordance with the request from the Environmental and Nuclear Safety Department of the WTP (Miles and Losey 2012), the Phase 2 report assessed the potential for WTP process conditions within and outside the range of normal control parameters to change the ratio of fissile material to neutron-absorbing material in the waste as it is processed with an eye towards potential implications for criticality safety. The Phase 2 study also considered the implications should WTP processes take place within the credible range of chemistry upset conditions. In the present Phase 3 report, the 28 phenomena described in the Phase 2 report were considered with respect to the disposition of plutonium and various absorber elements. The phenomena identified in the Phase 2 report are evaluated in light of the Phase 1 report and other resources to determine the impacts these phenomena might have to alter the plutonium/absorber dispositions and ratios. The outcomes of the Phase 3 evaluations then can be used to inform subsequent engineering decisions and provide reasonable paths forward to mitigate or overcome real or potential criticality concern in plant operations.

  13. Introduction to Decommissioning of Plutonium Production Reactors%钚生产堆退役简介

    Institute of Scientific and Technical Information of China (English)

    王永仙; 安凯媛; 刘东

    2013-01-01

      简要阐述几个国家钚生产堆的退役情况,以期对我国今后生产堆的退役提供借鉴。%  The paper provides briefly the information on the decommissiong of plutonium production reactors in several countries across the world and some suggestions for possible future decommissioning of production reac -tors in our country .

  14. Determination of filter pore size for use in HB line phase II production of plutonium oxide

    Energy Technology Data Exchange (ETDEWEB)

    Shehee, T. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Crowder, M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Rudisill, T. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2014-08-01

    H-Canyon and HB-Line are tasked with the production of plutonium oxide (PuO2) from a feed of plutonium (Pu) metal. The PuO2 will provide feed material for the Mixed Oxide (MOX) Fuel Fabrication Facility. After dissolution of the Pu metal in H-Canyon, plans are to transfer the solution to HB-Line for purification by anion exchange. Anion exchange will be followed by plutonium(IV) oxalate precipitation, filtration, and calcination to form PuO2. The filtrate solutions, remaining after precipitation, contain low levels of Pu ions, oxalate ions, and may include solids. These solutions are transferred to H-Canyon for disposition. To mitigate the criticality concern of Pu solids in a Canyon tank, past processes have used oxalate destruction or have pre-filled the Canyon tank with a neutron poison. The installation of a filter on the process lines from the HB-Line filtrate tanks to H-Canyon Tank 9.6 is proposed to remove plutonium oxalate solids. This report describes SRNL’s efforts to determine the appropriate pore size for the filters needed to perform this function. Information provided in this report aids in developing the control strategies for solids in the process.

  15. 75 FR 38809 - Southern Turner Cimarron I, LLC; Notice of Filing

    Science.gov (United States)

    2010-07-06

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Southern Turner Cimarron I, LLC; Notice of Filing June 25, 2010. Take notice that on June 24, 2010, Southern Turner Cimarron I, LLC filed a supplement confirming passive...

  16. Stop plutonium; Stop plutonium

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-02-01

    This press document aims to inform the public on the hazards bound to the plutonium exploitation in France and especially the plutonium transport. The first part is a technical presentation of the plutonium and the MOX (Mixed Oxide Fuel). The second part presents the installation of the plutonium industry in France. The third part is devoted to the plutonium convoys safety. The highlight is done on the problem of the leak of ''secret'' of such transports. (A.L.B.)

  17. THE CREATIVE APPLICATION OF SCIENCE TECHNOLOGY & WORK FORCE INNOVATIONS TO THE D&D OF PLUTONIUM FINISHING PLANT (PFP) AT THE HANFORD NUCLEAR RESERVATION

    Energy Technology Data Exchange (ETDEWEB)

    CHARBONEAU, S.L.

    2006-02-01

    The Plutonium Finishing Plant (PFP) consists of a number of process and support buildings for handling plutonium. Building construction began in the late 1940's to meet national priorities and became operational in 1950 producing refined plutonium salts and metal for the United States nuclear weapons program. The primary mission of the PFP was to provide plutonium used as special nuclear material for fabrication into a nuclear device for the war effort. Subsequent to the end of World War II, the PFP's mission expanded to support the Cold War effort through plutonium production during the nuclear arms race. PFP has now completed its mission and is fully engaged in deactivation, decontamination and decommissioning (D&D). At this time the PFP buildings are planned to be reduced to ground level (slab-on-grade) and the site remediated to satisfy national, Department of Energy (DOE) and Washington state requirements. The D&D of a highly contaminated plutonium processing facility presents a plethora of challenges. PFP personnel approached the D&D mission with a can-do attitude. They went into D&D knowing they were facing a lot of challenges and unknowns. There were concerns about the configuration control associated with drawings of these old process facilities. There were unknowns regarding the location of electrical lines and process piping containing chemical residues such as strong acids and caustics. The gloveboxes were highly contaminated with plutonium and chemical residues. Most of the glovebox windows were opaque with splashed process chemicals that coated the windows or etched them, reducing visibility to near zero. Visibility into the glovebox was a serious worker concern. Additionally, all the gloves in the gloveboxes were degraded and unusable. Replacing gloves in gloveboxes was necessary to even begin glovebox cleanout. The sheer volume of breathing air needed was also an issue. These and other challenges and PFP's approach to overcome these

  18. Definition and means of maintaining the emergency notification and evacuation system portion of the plutonium finishing plant safety envelope

    Energy Technology Data Exchange (ETDEWEB)

    WHITE, W.F.

    1999-05-20

    The Emergency Evacuation and Notification System provides information to the Plutonium Finishing Plant (PFP) Building Emergency Director to assist in determining appropriate emergency response, notifies personnel of the required response, and assists in their response. The report identifies the equipment in the Safety Envelope (SE) for this System and the Administrative, Maintenance, and Surveillance Procedures used to maintain the SE Equipment.

  19. Plan for the Startup of HA-21I Furnace Operations at the Plutonium Finishing Plant (PFP)

    Energy Technology Data Exchange (ETDEWEB)

    WILLIS, H.T.

    2000-02-17

    Achievement of Thermal Stabilization mission elements require the installation and startup of three additional muffle furnaces for the thermal stabilization of plutonium and plutonium bearing materials at the Plutonium Finishing Plant (PFP). The release to operate these additional furnaces will require an Activity Based Startup Review. The conduct of the Activity Based Startup Review (ABSR) was approved by Fluor Daniel Hanford on October 15, 1999. This plan has been developed with the objective of identifying those activities needed to guide the controlled startup of five furnaces from authorization to unrestricted operations by adding the HA-211 furnaces in an orderly and safe manner after the approval to Startup has been given. The Startup Plan provides a phased approach that bridges the activities between the completion of the Activity Based Startup Review authorizing the use of the three additional furnaces and the unrestricted operation of the five thermal stabilization muffle furnaces. The four phases are: (1) the initiation of five furnace operations using three empty (simulated full) boat charges from HA-211 and two full charges from HC-21C; (2) three furnace operations (one full charge from HA-211 and two full charges from HC-21C); (3) four furnace operations (two full charges from HA-211 and two full charges from HC-21C); and (4) integrated five furnace operations and unrestricted operations. Phase 1 of the Plan will be considered as the cold runs. This Plan also provides management oversight and administrative controls that are to be implemented until unrestricted operations are authorized. It also provides a formal review process for ensuring that all preparations needed for full five furnace operations are completed and formally reviewed prior to proceeding to the increased activity levels associated with five furnace operations. Specific objectives include: (1) To ensure that activities are conducted in a safe manner. (2) To provide supplemental

  20. Notice of Construction for the Magnesium Hydroxide Precipitation Process at the Plutonium Finishing Plant (PFP)

    Energy Technology Data Exchange (ETDEWEB)

    JANSKY, M.T.

    1999-12-01

    The following description and any attachments and references are provided to the Washington State Department of Health (WDOH), Division of Radiation Protection, Air Emissions & Defense Waste (WAC) 246-247, Radiation Protection-Air Emissions. The WAC 246-247-060, ''Applications, registration, and licensing'', states ''This section describes the information requirements for approval to construct, modify, and operate an emission unit. Any NOC requires the submittal of information listed in Appendix A.'' Appendix A (WAC 246-247-1 10) lists the requirements that must be addressed. Additionally, the following description, attachments and references are provided to the US Environmental Protection Agency (EPA) as an NOC, in accordance with Title 40, Code of Federal Regulations (CFR), Part 61, ''National Emission Standards for Hazardous Air Pollutants.'' The information required for submittal to the EPA is specified in 40 CFR 61.07. The potential emissions from this activity are estimated to provide greater than 0.1 millirem per year total effective dose equivalent (TEDE) to the hypothetical offsite maximally exposed individual (MEI), and commencement is needed within a short time. Therefore, this application also is intended to provide notification of the anticipated date of initial startup in accordance with the requirement listed in 40 CFR 61.09(a)(1), and it is requested that approval of this application also will constitute EPA acceptance of this initial startup notification. Written notification of the actual date of initial startup, in accordance with the requirement listed in 40 CFR 61.09(a)(2) will be provided at a later date. This NOC covers the activities associated with the Construction and operation activities involving the magnesium hydroxide precipitation process of plutonium solutions within the Plutonium Finishing Plant (PFP).

  1. CONTAMINATED PROCESS EQUIPMENT REMOVAL FOR THE D&D OF THE 232-Z CONTAMINATED WASTE RECOVERY PROCESS FACILITY AT THE PLUTONIUM FINISHING PLANT (PFP)

    Energy Technology Data Exchange (ETDEWEB)

    HOPKINS, A.M.; MINETTE, M.J.; KLOS, D.B.

    2007-01-25

    This paper describes the unique challenges encountered and subsequent resolutions to accomplish the deactivation and decontamination of a plutonium ash contaminated building. The 232-Z Contaminated Waste Recovery Process Facility at the Plutonium Finishing Plant was used to recover plutonium from process wastes such as rags, gloves, containers and other items by incinerating the items and dissolving the resulting ash. The incineration process resulted in a light-weight plutonium ash residue that was highly mobile in air. This light-weight ash coated the incinerator's process equipment, which included gloveboxes, blowers, filters, furnaces, ducts, and filter boxes. Significant airborne contamination (over 1 million derived air concentration hours [DAC]) was found in the scrubber cell of the facility. Over 1300 grams of plutonium held up in the process equipment and attached to the walls had to be removed, packaged and disposed. This ash had to be removed before demolition of the building could take place.

  2. Summary of Plutonium-238 Production Alternatives Analysis Final Report

    Energy Technology Data Exchange (ETDEWEB)

    James Werner; Wade E. Bickford; David B. Lord; Chadwick D. Barklay

    2013-03-01

    The Team implemented a two-phase evaluation process. During the first phase, a wide variety of past and new candidate facilities and processing methods were assessed against the criteria established by DOE for this assessment. Any system or system element selected for consideration as an alternative within the project to reestablish domestic production of Pu-238 must meet the following minimum criteria: Any required source material must be readily available in the United States, without requiring the development of reprocessing technologies or investments in systems to separate material from identified sources. It must be cost, schedule, and risk competitive with existing baseline technology. Any identified facilities required to support the concept must be available to the program for the entire project life cycle (notionally 35 years, unless the concept is so novel as to require a shorter duration). It must present a solution that can generate at least 1.5 Kg of Pu-238 oxide per year, for at least 35 years. It must present a low-risk, near-term solution to the National Aeronautics and Space Administration’s urgent mission need. DOE has implemented this requirement by eliminating from project consideration any alternative with key technologies at less than Technology Readiness Level 5. The Team evaluated the options meeting these criteria using a more detailed assessment of the reasonable facility variations and compared them to the preferred option, which consists of target irradiation at the Advanced Test Reactor (ATR) and the High Flux Isotope Reactor (HFIR), target fabrication and chemical separations processing at the ORNL Radiochemical Engineering Development Center, and neptunium 237 storage at the Materials and Fuels Complex at INL. This preferred option is consistent with the Records of Decision from the earlier National Environmental Policy Act (NEPA) documentation

  3. Powder detergents production plant

    Directory of Open Access Journals (Sweden)

    Stanković Mirjana S.

    2003-01-01

    Full Text Available The IGPC Engineering Department designed basic projects for powder detergent production plant, using technology developed in the IGPC laboratories, in 1998. - 2000. Several projects were completed: technological, machine, electrical, automation. On the basis of these projects, a production plant with a capacity of 25,000 t/y was manufactured, at "Delta In", Zrenjanin, in 2000.This technology was an innovation, because new approach in mixing a powder materials was used, as well as introducing a new type of dryer in detergent production. The product meets all quality demands for detergents with high specific weight (1000 g/l, as well as environmental regulations. The detergent production process is fully automatized, and the product has uniform quality. There is no waste material in detergent zeolite production, because all products with unsatisfactory quality are returned to the process. The production process can be controlled manually, which is necessary during start-up, and repairs.

  4. Terrestrial plant methane production

    DEFF Research Database (Denmark)

    Mikkelsen, Teis Nørgaard; Bruhn, Dan; Møller, Ian M.

    We evaluate all experimental work published on the phenomenon of aerobic methane (CH4) generation in terrestrial plants. We conclude that the phenomenon is true. Four stimulating factors have been observed to induce aerobic plant CH4 production, i.e. cutting injuries, increasing temperature...

  5. Radioactive Air Emission Notice of Construction (NOC) for Plutonium Finishing Plant (PFP) Project W-460 Plutonium Stabilization and Handling

    Energy Technology Data Exchange (ETDEWEB)

    JANSKY, M.T.

    2000-05-01

    The following description and any attachments and references are provided to the Washington State Department of Health (WDOH), Division of Radiation Protection, Air Emissions & Defense Waste Section as a notice of construction (NOC) in accordance with Washington Administrative Code (WAC) 246-247, Radiation Protection-Air Emissions. The WAC 246-247-060, ''Applications, registration, and licensing'', states ''This section describes the information requirements for approval to construct, modify, and operate an emission unit. Any NOC requires the submittal of information listed in Appendix A.'' Additionally, the following description, attachments, and references are provided to the US Environmental Protection Agency (EPA) as an NOC, in accordance with Title 40 Code of Federal Regulations (CFR), Part 61, ''National Emission Standards for Hazardous Air Pollutants''. The information required for submittal to the EPA is specified in 40 CFR 61.07. The potential emissions from this activity are estimated to provide greater than 0.1 millirem year total effective dose equivalent (TEDE) to the hypothetical offsite maximally exposed individual (MEI) and commencement is needed within a short time. Therefore, this application also is intended to provide notification of the anticipated date of initial startup in accordance with the requirement listed in 40 CFR 61.09(a)(1), and it is requested that approval of this application also constitutes EPA acceptance of this initial startup notification. Written notification of the actual date of initial startup, in accordance with the requirement listed in 40 CFR 61.09(a)(2), will be provided later. This NOC covers the activities associated with the construction and operation activities involving stabilization and/or repackaging of plutonium in the 2736-ZB Building. A new exhaust stack will be built and operated at the 2736-ZB Building to handle the effluents associated with the

  6. Radioactive Air Emission Notice of Construction for (NOC) Plutonium Finishing Plant (PFP) Project W-460 Plutonium Stabilization and Handling

    Energy Technology Data Exchange (ETDEWEB)

    JANSKY, M.T.

    2000-03-01

    The following description and any attachments and references are provided to the Washington State Department of Health (WDOH), Division of Radiation Protection, Air Emissions & Defense Waste Section as a notice of construction (NOC) in accordance with Washington Administrative Code (WAC) 246-247, Radiation Protection-Air Emissions. The WAC 246-247-060, ''Applications, registration, and licensing'', states ''This section describes the information requirements for approval to construct, modify, and operate an emission unit. Any NOC requires the submittal of information listed in Appendix A,'' Appendix A (WAC 246-247-1 IO) lists the requirements that must be addressed. Additionally, the following description, attachments, and references are provided to the U.S. Environmental Protection Agency (EPA) as an NOC, in accordance with Title 40 Code of Federal Regulations (CFR), Part 61, ''National Emission Standards for Hazardous Air Pollutants.'' The information required for submittal to the EPA is specified in 40 CFR 61.07. The potential emissions from this activity are estimated to provide greater than 0.1 millirem year total effective dose equivalent (TEDE) to the hypothetical offsite maximally exposed individual (MEI) and commencement is needed within a short time. Therefore, this application also is intended to provide notification of the anticipated date of initial startup in accordance with the requirement listed in 40 CFR 61.09(a)(1), and it is requested that approval of this application also constitutes EPA acceptance of this initial startup notification. Written notification of the actual date of initial startup, in accordance with the requirement listed in 40 CFR 61.09(a)(2), will be provided later. This NOC covers the activities associated with the construction and operation activities involving stabilization and/or repackaging of plutonium in the 2736-ZB Building. An operations support trailer will be

  7. Estimate of airborne release of plutonium from Babcock and Wilcox plant as a result of severe wind hazard and earthquake

    Energy Technology Data Exchange (ETDEWEB)

    Mishima, J.; Schwendiman, L.C.; Ayer, J.E.

    1978-10-01

    As part of an interdisciplinary study to evaluate the potential radiological consequences of wind hazard and earthquake upon existing commercial mixed oxide fuel fabrication plants, the potential mass airborne releases of plutonium (source terms) from such events are estimated. The estimated souce terms are based upon the fraction of enclosures damaged to three levels of severity (crush, puncture penetrate, and loss of external filter, in order of decreasing severity), called damage ratio, and the airborne release if all enclosures suffered that level of damage. The discussion of damage scenarios and source terms is divided into wind hazard and earthquake scenarios in order of increasing severity. The largest airborne releases from the building were for cases involving the catastrophic collapse of the roof over the major production areas--wind hazard at 110 mph and earthquakes with peak ground accelerations of 0.20 to 0.29 g. Wind hazards at higher air velocities and earthquakes with higher ground acceleration do not result in significantly greater source terms. The source terms were calculated as additional mass of respirable particles released with time up to 4 days; and, under these assumptions, approximately 98% of the mass of material of concern is made airborne from 2 h to 4 days after the event. The overall building source terms from the damage scenarios evaluated are shown in a table. The contribution of individual areas to the overall building source term is presented in order of increasing severity for wind hazard and earthquake.

  8. Properties of plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Ahn, Jin Su; Yoon, Hwan Ki; Min, Kyung Sik; Kim, Hyun Tae; Ahn, Jong Sung; Kwag, Eon Ho; Ryu, Keon Joong [Korea Atomic Energy Research Institute, Daeduk (Korea, Republic of)

    1996-03-01

    Plutonium has unique chemical and physical properties. Its uniqueness in use has led to rare publications, in Korea. This report covers physical aspects of phase change of metal plutonium, mechanical properties, thermal conductivity, etc, chemical aspects of corrosion, oxidation, how to produce plutonium from spent fuels by describing various chemical treatment methods, which are currently used and were used in the past. It also contains characteristics of the purex reprocessing process which is the most widely used nowadays. And show processes to purify and metalize from recovered plutonium solution. Detection and analysis methods are introduced with key pints for handling, critical safety, toxicity, and effects on peoples. This report gives not only a general idea on what plutonium is, rather than deep technical description, but also basic knowledge on plutonium production and safeguards diversion from the view point of nonproliferation. 18 refs. (Author) .new.

  9. Solutions to criticality problems in a plutonium extraction plant; Solutions apportees aux problemes de criticite d'une usine d'extraction du plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Jouannaud, C.; Rodier, J.; Fruchard, Y.; Peyresblanques, H.; Papault, C.; Tabardel-Brian, R. [Commissariat a l' Energie Atomique, Chusclan (France). Centre de Production de Plutonium de Marcoule, service d' extraction du plutonium, service de protection contre les radiations et d' assainissement radioactif

    1968-08-01

    There are two aspects to nuclear criticality safety: prevention of criticality and protection against the consequences of a possible accident: this report considers these two aspects in the case of the Marcoule Plutonium Extraction Plant. After briefly recalling the various techniques used for avoiding criticality (mass, geometry, concentration, poisoning), the authors describe their application in the plant and show in particular that, a rational use of a favorable geometry is a factor both for security and from an economic point of view. The authors then describe the inside organisation which makes it possible to obtain the necessary intrinsic safety standard right from the advance project stage, and to control the workshop safety during the operation of the plant. The second part of the report deals with the system of protection against the consequences of a possible accident: definition of a typical accident, fixing of the boundaries of a critical zone, safety alarm device, individual and collective dosimetry, evacuation plan and safety instructions. (authors) [French] La securite vis-a-vis des risques de criticite revet deux aspects: la prevention de la criticite et la protection contre les consequences d'un accident eventuel: le present rapport developpe ces deux aspects dans le cas de l'Usine d'Extraction du Plutonium de Marcoule. Apres avoir rappele les differentes techniques de prevention de la criticite (masse, geometrie, concentration, empoisonnement), les auteurs decrivent leur application a l'Usine et montrent notamment que l'utilisation rationnelle de la geometrie favorable est un double facteur de securite et d'economie. Les auteurs decrivent ensuite l'organisation interieure qui permet de realiser la securite intrinseque des le stade d'un avant projet et de controler la securite des ateliers au cours de la vie de l'Usine. La deuxieme partie du rapport est consacree au systeme de protection contre les

  10. Dry alcohol production plant

    Directory of Open Access Journals (Sweden)

    Stanković Mirjana S.

    2003-01-01

    Full Text Available The IGPC Engineering Department designed basic projects for dry alcohol production plant, using technology developed in the IGPC laboratories. Several projects were completed: technological, machine, electrical, automation. On the basis of these projects a production plant with a capacity of 40 m3/y was manufactured, at "Zorka Pharma", Šabac in 1995-1996. The product meets all quality demands, as well as environmental regulations. The dry alcohol production process is fully automatized. There is no waste in the process, neither gaseous, nor liquid. The chosen process provides safe operation according to temperature regime and resistance in the pipes, air purification columns and filters. Working at increased pressure is suitable for evaporation and condensation at increased temperatures. The production process can be controlled manually, which is necessary during start-up, and repairs.

  11. Plutonium, americium and radiocaesium in the marine environment close to the Vandellos I nuclear power plant before decommissioning

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez-Cabeza, J.A. E-mail: joanalbert.sanchez@uab.es; Molero, J

    2000-11-01

    The Vandellos nuclear power plant (NPP), releasing low-level radioactive liquid waste to the Mediterranean Sea, is the first to be decommissioned in Spain, after an incident which occurred in 1989. The presence, distribution and uptake of various artificial radionuclides (radiocaesium, plutonium and americium) in the environment close to the plant were studied in seawater, bottom sediments and biota, including Posidonia oceanica, fish, crustaceans and molluscs. Seawater, sediments and Posidonia oceanica showed enhanced levels in the close vicinity of the NPP, although the effect was restricted to its near environment. Maximum concentrations in seawater were 11.6{+-}0.5 Bq m{sup -3} and 16.9{+-}1.2 mBq m{sup -3} for {sup 137}Cs and {sup 239,240}Pu, respectively. When sediment concentrations were normalized to excess {sup 210}Pb, they showed both the short-distance transport of artificial radionuclides from the Vandellos plant and the long-distance transport of {sup 137}Cs from the Asco NPP. Posidonia oceanica showed the presence of various gamma-emitters attributed to the impact of the Chernobyl accident, on which the effect of the NPP was superimposed. Seawater, sediment and Posidonia oceanica collected near the plant also showed an enhancement of the plutonium isotopic ratio above the fallout value. The uptake of these radionuclides by marine organisms was detectable but limited. Pelagic fish showed relatively higher {sup 137}Cs concentrations and only in the case of demersal fish was the plutonium isotopic ratio increased. The reported levels constitute a set of baseline values against which the impact of the decommissioning operations of the Vandellos I NPP can be studied.

  12. 77 FR 2718 - CPV Cimarron Renewable Energy Company, LLC; Supplemental Notice That Initial Market-Based Rate...

    Science.gov (United States)

    2012-01-19

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission CPV Cimarron Renewable Energy Company, LLC; Supplemental Notice That Initial... notice in the above-referenced proceeding of CPV Cimarron Renewable Energy Company, LLC's application...

  13. 77 FR 23476 - Cimarron Windpower II, LLC; Supplemental Notice That Initial Market-Based Rate Filing Includes...

    Science.gov (United States)

    2012-04-19

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Cimarron Windpower II, LLC; Supplemental Notice That Initial Market-Based... above-referenced proceeding of Cimarron Windpower II, LLC's application for market-based rate...

  14. 75 FR 16098 - Southern Turner Cimarron I, LLC; Supplemental Notice That Initial Market-Based Rate Filing...

    Science.gov (United States)

    2010-03-31

    ... From the Federal Register Online via the Government Publishing Office ] DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Southern Turner Cimarron I, LLC; Supplemental Notice That Initial... supplemental notice in the above-referenced proceeding of Southern Turner Cimarron I, LLC's application...

  15. The United States Plutonium Balance, 1944 - 2009

    Energy Technology Data Exchange (ETDEWEB)

    None

    2012-06-01

    This report updates the report -Plutonium: The first 50 years- which was released by the U.S.Department of Energy (DOE) in 1996. The topic of both reports is plutonium, sometimes referred to as Pu-239, which is capable of sustaining a nuclear chain reaction and is used in nuclear weapons and for nuclear power production. This report updates 1994 data through 2009. The four most significant changes since 1994 include: (a) the completion of cleanup activities at the Rocky Flats Plant in 2005; (b) material consolidation and disposition activities, especially shipments from Hanford to the Savannah River Site; (c) the 2007 declaration of an additional 9.0 MT of weapons grade plutonium to be surplus to defense needs in the coming decades; and (d) the opening of the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico in 1999.

  16. Plutonium controversy

    Energy Technology Data Exchange (ETDEWEB)

    Richmond, C.R.

    1980-01-01

    The toxicity of plutonium is discussed, particularly in relation to controversies surrounding the setting of radiation protection standards. The sources, amounts of, and exposure pathways of plutonium are given and the public risk estimated. (ACR)

  17. PLUTONIUM FINISHING PLANT (PFP) 241-Z LIQUID WASTE TREATMENT FACILITY DEACTIVATION AND DEMOLITION

    Energy Technology Data Exchange (ETDEWEB)

    JOHNSTON GA

    2008-01-15

    Fluor Hanford, Inc. (FH) is proud to submit the Plutonium Finishing Plant (PFP) 241-Z liquid Waste Treatment Facility Deactivation and Demolition (D&D) Project for consideration by the Project Management Institute as Project of the Year for 2008. The decommissioning of the 241-Z Facility presented numerous challenges, many of which were unique with in the Department of Energy (DOE) Complex. The majority of the project budget and schedule was allocated for cleaning out five below-grade tank vaults. These highly contaminated, confined spaces also presented significant industrial safety hazards that presented some of the most hazardous work environments on the Hanford Site. The 241-Z D&D Project encompassed diverse tasks: cleaning out and stabilizing five below-grade tank vaults (also called cells), manually size-reducing and removing over three tons of process piping from the vaults, permanently isolating service utilities, removing a large contaminated chemical supply tank, stabilizing and removing plutonium-contaminated ventilation ducts, demolishing three structures to grade, and installing an environmental barrier on the demolition site . All of this work was performed safely, on schedule, and under budget. During the deactivation phase of the project between November 2005 and February 2007, workers entered the highly contaminated confined-space tank vaults 428 times. Each entry (or 'dive') involved an average of three workers, thus equaling approximately 1,300 individual confined -space entries. Over the course of the entire deactivation and demolition period, there were no recordable injuries and only one minor reportable skin contamination. The 241-Z D&D Project was decommissioned under the provisions of the 'Hanford Federal Facility Agreement and Consent Order' (the Tri-Party Agreement or TPA), the 'Resource Conservation and Recovery Act of 1976' (RCRA), and the 'Comprehensive Environmental Response, Compensation, and

  18. PLUTONIUM FINISHING PLANT (PFP) 241-Z LIQUID WASTE TREATMENT FACILITY DEACTIVATION AND DEMOLITION

    Energy Technology Data Exchange (ETDEWEB)

    JOHNSTON GA

    2008-01-15

    Fluor Hanford, Inc. (FH) is proud to submit the Plutonium Finishing Plant (PFP) 241-Z liquid Waste Treatment Facility Deactivation and Demolition (D&D) Project for consideration by the Project Management Institute as Project of the Year for 2008. The decommissioning of the 241-Z Facility presented numerous challenges, many of which were unique with in the Department of Energy (DOE) Complex. The majority of the project budget and schedule was allocated for cleaning out five below-grade tank vaults. These highly contaminated, confined spaces also presented significant industrial safety hazards that presented some of the most hazardous work environments on the Hanford Site. The 241-Z D&D Project encompassed diverse tasks: cleaning out and stabilizing five below-grade tank vaults (also called cells), manually size-reducing and removing over three tons of process piping from the vaults, permanently isolating service utilities, removing a large contaminated chemical supply tank, stabilizing and removing plutonium-contaminated ventilation ducts, demolishing three structures to grade, and installing an environmental barrier on the demolition site . All of this work was performed safely, on schedule, and under budget. During the deactivation phase of the project between November 2005 and February 2007, workers entered the highly contaminated confined-space tank vaults 428 times. Each entry (or 'dive') involved an average of three workers, thus equaling approximately 1,300 individual confined -space entries. Over the course of the entire deactivation and demolition period, there were no recordable injuries and only one minor reportable skin contamination. The 241-Z D&D Project was decommissioned under the provisions of the 'Hanford Federal Facility Agreement and Consent Order' (the Tri-Party Agreement or TPA), the 'Resource Conservation and Recovery Act of 1976' (RCRA), and the 'Comprehensive Environmental Response, Compensation, and

  19. Plutonium isotopes and their decay products in civil nuclear engineering; Les isotopes du plutonium et leurs descendants dans le nucleaire civil

    Energy Technology Data Exchange (ETDEWEB)

    Dautray, R

    2005-07-01

    This book is the continuation and conclusion of a previous book from the same author, entitled 'civil nuclear energy in the temporal framework of climatic changes' (Tec and Doc editions). It focusses on plutonium and on its daughter products. A synthesis of the scientific and technical data gathered so far is presented, together with the different choices offered to political authorities in the light of present-day knowledge. The authors starts from existing and firmly implemented scientific and technical data and presents some ways to solve the pending questions about the management of radioactive wastes. He shows that in our democratic system, the choice belongs to people. Beside the storage and deep disposal facilities, still necessary, some processes and problems are reviewed and explored. Of course new scientific data will be obtained, which would change the ways to discover and evaluate the ways to follow up. (J.S.)

  20. PLUTONIUM SEPARATION METHOD

    Science.gov (United States)

    Beaufait, L.J. Jr.; Stevenson, F.R.; Rollefson, G.K.

    1958-11-18

    The recovery of plutonium ions from neutron irradiated uranium can be accomplished by bufferlng an aqueous solutlon of the irradiated materials containing tetravalent plutonium to a pH of 4 to 7, adding sufficient acetate to the solution to complex the uranyl present, adding ferric nitrate to form a colloid of ferric hydroxide, plutonlum, and associated fission products, removing and dissolving the colloid in aqueous nitric acid, oxldizlng the plutonium to the hexavalent state by adding permanganate or dichromate, treating the resultant solution with ferric nitrate to form a colloid of ferric hydroxide and associated fission products, and separating the colloid from the plutonlum left in solution.

  1. Evaluation of the Magnesium Hydroxide Treatment Process for Stabilizing PFP Plutonium/Nitric Acid Solutions

    Energy Technology Data Exchange (ETDEWEB)

    Gerber, Mark A.; Schmidt, Andrew J.; Delegard, Calvin H.; Silvers, Kurt L.; Baker, Aaron B.; Gano, Susan R.; Thornton, Brenda M.

    2000-09-28

    This document summarizes an evaluation of the magnesium hydroxide [Mg(OH)2] process to be used at the Hanford Plutonium Finishing Plant (PFP) for stabilizing plutonium/nitric acid solutions to meet the goal of stabilizing the plutonium in an oxide form suitable for storage under DOE-STD-3013-99. During the treatment process, nitric acid solutions bearing plutonium nitrate are neutralized with Mg(OH)2 in an air sparge reactor. The resulting slurry, containing plutonium hydroxide, is filtered and calcined. The process evaluation included a literature review and extensive laboratory- and bench-scale testing. The testing was conducted using cerium as a surrogate for plutonium to identify and quantify the effects of key processing variables on processing time (primarily neutralization and filtration time) and calcined product properties.

  2. Plutonium Immobilization Project Baseline Formulation

    Energy Technology Data Exchange (ETDEWEB)

    Ebbinghaus, B.

    1999-02-01

    A key milestone for the Immobilization Project (AOP Milestone 3.2a) in Fiscal Year 1998 (FY98) is the definition of the baseline composition or formulation for the plutonium ceramic form. The baseline formulation for the plutonium ceramic product must be finalized before the repository- and plant-related process specifications can be determined. The baseline formulation that is currently specified is given in Table 1.1. In addition to the baseline formulation specification, this report provides specifications for two alternative formulations, related compositional specifications (e.g., precursor compositions and mixing recipes), and other preliminary form and process specifications that are linked to the baseline formulation. The preliminary specifications, when finalized, are not expected to vary tremendously from the preliminary values given.

  3. 10 CFR 140.107 - Appendix G-Form of indemnity agreement with licensees processing plutonium for use in plutonium...

    Science.gov (United States)

    2010-01-01

    ... processing plutonium for use in plutonium processing and fuel fabrication plants and furnishing insurance... § 140.107 Appendix G—Form of indemnity agreement with licensees processing plutonium for use in plutonium processing and fuel fabrication plants and furnishing insurance policies as proof of...

  4. 10 CFR 140.108 - Appendix H-Form of indemnity agreement with licensees possessing plutonium for use in plutonium...

    Science.gov (United States)

    2010-01-01

    ... possessing plutonium for use in plutonium processing and fuel fabrication plants and furnishing proof of... Appendixes to Part 140 § 140.108 Appendix H—Form of indemnity agreement with licensees possessing plutonium for use in plutonium processing and fuel fabrication plants and furnishing proof of...

  5. Plutonium Vulnerability Management Plan

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    This Plutonium Vulnerability Management Plan describes the Department of Energy`s response to the vulnerabilities identified in the Plutonium Working Group Report which are a result of the cessation of nuclear weapons production. The responses contained in this document are only part of an overall, coordinated approach designed to enable the Department to accelerate conversion of all nuclear materials, including plutonium, to forms suitable for safe, interim storage. The overall actions being taken are discussed in detail in the Department`s Implementation Plan in response to the Defense Nuclear Facilities Safety Board (DNFSB) Recommendation 94-1. This is included as Attachment B.

  6. Investigation Of In-Line Monitoring Options At H Canyon/HB Line For Plutonium Oxide Production

    Energy Technology Data Exchange (ETDEWEB)

    Sexton, L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-10-14

    H Canyon and HB Line have a production goal of 1 MT per year of plutonium oxide feedstock for the MOX facility by FY17 (AFS-2 mission). In order to meet this goal, steps will need to be taken to improve processing efficiency. One concept for achieving this goal is to implement in-line process monitoring at key measurement points within the facilities. In-line monitoring during operations has the potential to increase throughput and efficiency while reducing costs associated with laboratory sample analysis. In the work reported here, we mapped the plutonium oxide process, identified key measurement points, investigated alternate technologies that could be used for in-line analysis, and initiated a throughput benefit analysis.

  7. In Plant Measurement and Analysis of Mixtures of Uranium and Plutonium TRU-Waste Using a {sup 252}Cf Shuffler Instrument

    Energy Technology Data Exchange (ETDEWEB)

    Hurd, J.R.

    1998-11-02

    The active-passive {sup 252}Cf shuffler instrument, installed and certified several years ago in Los Alamos National Laboratory's plutonium facility, has now been calibrated for different matrices to measure Waste Isolation Pilot Plant (WIPP)-destined transuranic (TRU)-waste. Little or no data currently exist for these types of measurements in plant environments where sudden large changes in the neutron background radiation can significantly distort the results. Measurements and analyses of twenty-two 55-gallon drums, consisting of mixtures of varying quantities of uranium and plutonium in mostly noncombustible matrices, have been recently completed at the plutonium facility. The calibration and measurement techniques, including the method used to separate out the plutonium component, will be presented and discussed. Calculations used to adjust for differences in uranium enrichment from that of the calibration standards will be shown. Methods used to determine various sources of both random and systematic error will be indicated. Particular attention will be directed to those problems identified as arising from the plant environment. The results of studies to quantify the aforementioned distortion effects in the data will be presented. Various solution scenarios will be outlined, along with those adopted here.

  8. AN APPROACH TO CHARACTERIZING & EVALUATING ALTERNATIVES FOR THE DECOMMISSIONING OF SUB-GRADE STRUCTURES AT THE PLUTONIUM FINISHING PLANT (PFP)

    Energy Technology Data Exchange (ETDEWEB)

    HOPKINS, A.M.; KLOS, D.B.

    2007-01-25

    In 2002, the Richland Operations Office (RL) of the US Department of Energy (DOE), the US Environmental Protection Agency (EPA), and the Washington State Department of Ecology (Ecology) developed milestones for transitioning the Plutonium Finishing Plant (PFP) facility to a clean slab-on-grade configuration. These milestones required developing an engineering evaluation/cost analysis (EF/CA) for the facility's sub-grade structures and installations as part of a series of evaluations intended to provide for the transition of the facility to a clean slab-on-grade configuration. In addition to supporting decisions for interim actions, the analyses of sub-grade structures and installations performed through this EE/CA will contribute to the remedial investigation feasibility study(ies) and subsequently to the final records of decision for the relevant operable units responsible for site closure in the 200 West Area of the Hanford Site.

  9. Concentration of Plutonium in Desert Plants From Contaminated Area%钚在放射性污染区沙漠植物中的含量

    Institute of Scientific and Technical Information of China (English)

    徐辉; 金玉仁; 田梅; 李伟平; 王耀芹; 王煜; 曾可

    2012-01-01

    研究沙漠植物中钚的含量,对于评估沙漠植物受钚污染状况,寻找钚指示和超积累植物有重要意义.本文采集某放射性污染区内的植物并分析其中239 Pu的含量,获得7种沙漠植物受239Pu污染的数据,据此分析影响植物体内核素含量的因素.所研究沙漠植物体内239 Pu含量平均值为(1.8士4.9)Bq/kg(干重),明显受到钚的污染.再悬浮是造成植物表面污染严重的重要因素之一.植物体内钚的含量与植物种类、生长期、地表污染程度等密切相关.所研究沙漠植物中钚含量的大小顺序为:河西苣>芦苇>盐穗木>盐生草>黑果枸杞>刚毛柽柳>沙拐枣,其中草本植物中钚的含量均大于木本植物.%The investigation of plutonium in desert plants from contaminated sites contributes to the evaluation of its pollution situation and to the survey of plutonium hyperaccumulator. The concentration of 239Pu in desert plants collected from a contaminated site was determined, and the influence factors were studied. The concentration of 239Pu in plants was (1. 8 + 4. 9) Bq/kg in dry weight, and it means that the plants were contaminated, moreover, the resuspension results in dramatic plutonium pollution of plant surface. The concentration of plutonium in plants depends on species, live stages and the content of plutonium in the rhizosphere soil. The concentration of plutonium in herbage is higher than that in woody plant, and for the seven species of desert plants investigated, it decreases in the order of Hexinia polydichotoma, Phragmites austra-lis, Halostashys caspica, Halogeton arachnoideus, Lycium ruthenicum ,Tamarix hispida and Calligonum aphyllum.

  10. Plutonium interaction with a bacterial strain isolated from the waste isolation pilot plant (WIPP) environment

    Energy Technology Data Exchange (ETDEWEB)

    Strietelmeier, B.A.; Kraus, S.M.; Leonard, P.A.; Triay, I.R. [Los Alamos National Lab., NM (United States)] [and others

    1996-12-31

    This work was conducted as part of a series of experiments to determine the association and interaction of various actinides with bacteria isolated from the WIPP site. The majority of bacteria that exist at the site are expected to be halophiles, or extreme halophiles, due to the high concentration of salt minerals at the location. Experiments were conducted to determine the toxicity of plutonium-n-239, neptunium-237 and americium-243 to several species of these halophiles and the results were reported elsewhere. As an extension of these experiments, we report an investigation of the type of association that occurs between {sup 239}Pu and the isolate WIPP-1A, isolated by staff at Brookhaven National Laboratory, when grown in a high-salt, defined medium. Using scanning electron microscopy (SEM) techniques, we demonstrate a surface association of the {sup 239}Pu with the bacterial cells.

  11. Thermal Safety Analyses for the Production of Plutonium-238 at the High Flux Isotope Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Hurt, Christopher J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Freels, James D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Hobbs, Randy W. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jain, Prashant K. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Maldonado, G. Ivan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-08-01

    There has been a considerable effort over the previous few years to demonstrate and optimize the production of plutonium-238 (238Pu) at the High Flux Isotope Reactor (HFIR). This effort has involved resources from multiple divisions and facilities at the Oak Ridge National Laboratory (ORNL) to demonstrate the fabrication, irradiation, and chemical processing of targets containing neptunium-237 (237Np) dioxide (NpO2)/aluminum (Al) cermet pellets. A critical preliminary step to irradiation at the HFIR is to demonstrate the safety of the target under irradiation via documented experiment safety analyses. The steady-state thermal safety analyses of the target are simulated in a finite element model with the COMSOL Multiphysics code that determines, among other crucial parameters, the limiting maximum temperature in the target. Safety analysis efforts for this model discussed in the present report include: (1) initial modeling of single and reduced-length pellet capsules in order to generate an experimental knowledge base that incorporate initial non-linear contact heat transfer and fission gas equations, (2) modeling efforts for prototypical designs of partially loaded and fully loaded targets using limited available knowledge of fabrication and irradiation characteristics, and (3) the most recent and comprehensive modeling effort of a fully coupled thermo-mechanical approach over the entire fully loaded target domain incorporating burn-up dependent irradiation behavior and measured target and pellet properties, hereafter referred to as the production model. These models are used to conservatively determine several important steady-state parameters including target stresses and temperatures, the limiting condition of which is the maximum temperature with respect to the melting point. The single pellet model results provide a basis for the safety of the irradiations, followed by parametric analyses in the initial prototypical designs that were necessary due to the

  12. Plutonium Oxide Process Capability Work Plan

    Energy Technology Data Exchange (ETDEWEB)

    Meier, David E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Tingey, Joel M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2014-02-28

    Pacific Northwest National Laboratory (PNNL) has been tasked to develop a Pilot-scale Plutonium-oxide Processing Unit (P3U) providing a flexible capability to produce 200g (Pu basis) samples of plutonium oxide using different chemical processes for use in identifying and validating nuclear forensics signatures associated with plutonium production. Materials produced can also be used as exercise and reference materials.

  13. Recovery studies for plutonium machining oil coolant

    Energy Technology Data Exchange (ETDEWEB)

    Navratil, J. D.; Baldwin, C. E.

    1977-04-27

    Lathe coolant oil, contaminated with plutonium and having a carbon tetrachloride diluent, is generated in plutonium machining areas at Rocky Flats. A research program was initiated to determine the nature of plutonium in this mixture of oil and carbon tetrachloride. Appropriate methods then could be developed to remove the plutonium and to recycle the oil and carbon tetrachloride. Studies showed that the mixtures of spent oil and carbon tetrachloride contained particulate plutonium and plutonium species that are soluble in water or in oil and carbon tetrachloride. The particulate plutonium was removed by filtration; the nonfilterable plutonium was removed by adsorption on various materials. Laboratory-scale tests indicated the lathe-coolant oil mixture could be separated by distilling the carbon tetrachloride to yield recyclable products.

  14. Plutonium behavior during the early diagenesis of marine sediments: applications to two marine environments labelled by radionuclides released from reprocessing plants; Etude du comportement du plutonium au cours de la diagenese precoce des sediments marins: applications a deux environnements marins marques par les rejets issus d'usines de retraitement de combustibles uses

    Energy Technology Data Exchange (ETDEWEB)

    Gouzy, A

    2004-12-15

    The plutonium released into the English Channel and the Irish Sea by nuclear fuel reprocessing plants is mainly associated to sediments. Nevertheless, this association is partially reversible. This work combines a field study, carried out on the Cumbrian mud patch and the Esk estuary (Eastern Irish Sea), and laboratory experiments performed on carbonaceous coarse-grained sediments collected in the Central Channel. It presents new data on the plutonium solid partition in sediments and suggests realistic scenarios for describing its release from sediments to the water column. The role of reactive sulphides acting as temporary sink phases is shown in anoxic sediments; those sulphides are liable to release dissolved plutonium upon their oxidation. The plutonium is also bound to carbonates within the carbonaceous matrix and as carbonate surface complexes. Conceptual schemes of the behaviour of the plutonium in marine sediments are proposed; they highlight the strong remobilization potential of plutonium from marine sediments to the interstitial water. Its plutonium content can be injected into the overlying water column. (author)

  15. Plutonium Proliferation: The Achilles Heel of Disarmament

    Energy Technology Data Exchange (ETDEWEB)

    Leventhal, Paul (President, Nuclear Control Institute, Washington D.C.)

    2001-02-07

    Plutonium is a byproduct of nuclear fission, and it is produced at the rate of about 70 metric tons a year in the world's nuclear power reactors. Concerns about civilian plutonium ran high in the 1970s and prompted enactment of the Nuclear Non-Proliferation Act of 1978 to give the United States a veto over separating plutonium from U.S.-supplied uranium fuel. Over the years, however, so-called reactor-grade plutonium has become the orphan issue of nuclear non-proliferation, largely as a consequence of pressures from plutonium-separating countries. The demise of the fast breeder reactor and the reluctance of utilities to introduce plutonium fuel in light-water reactors have resulted in large surpluses of civilian, weapons-usable plutonium, which now approach in size the 250 tons of military plutonium in the world. Yet reprocessing of spent fuel for recovery and use of plutonium proceeds apace outside the United States and threatens to overwhelm safeguards and security measures for keeping this material out of the hands of nations and terrorists for weapons. A number of historical and current developments are reviewed to demonstrate that plutonium commerce is undercutting efforts both to stop the spread of nuclear weapons and to work toward eliminating existing nuclear arsenals. These developments include the breakdown of U.S. anti-plutonium policy, the production of nuclear weapons by India with Atoms-for-Peace plutonium, the U.S.-Russian plan to introduce excess military plutonium as fuel in civilian power reactors, the failure to include civilian plutonium and bomb-grade uranium in the proposed Fissile Material Cutoff Treaty, and the perception of emerging proliferation threats as the rationale for development of a ballistic missile defense system. Finally, immobilization of separated plutonium in high-level waste is explored as a proliferation-resistant and disarmament-friendly solution for eliminating excess stocks of civilian and military plutonium.

  16. Particle Generation by Laser Ablation in Support of Chemical Analysis of High Level Mixed Waste from Plutonium Production Operations

    Energy Technology Data Exchange (ETDEWEB)

    J. Thomas Dickinson; Michael L. Alexander

    2001-11-30

    Investigate particles produced by laser irradiation and their analysis by Laser Ablation Inductively Coupled Plasma Mass Spectroscopy (LA/ICP-MS), with a view towards optimizing particle production for analysis of high level waste materials and waste glass. LA/ICP-MS has considerable potential to increase the safety and speed of analysis required for the remediation of high level wastes from cold war plutonium production operations. In some sample types, notably the sodium nitrate-based wastes at Hanford and elsewhere, chemical analysis using typical laser conditions depends strongly on the details of sample history composition in a complex fashion, rendering the results of analysis uncertain. Conversely, waste glass materials appear to be better behaved and require different strategies to optimize analysis.

  17. Modular Engineering of Production Plants

    DEFF Research Database (Denmark)

    Miller, Thomas Dedenroth

    1998-01-01

    Based on a case-study on design of pharmaceutical production plants, this paper suggests that modularity may support business efficiency for companies with one-of-a-kind production and without in-house manufacturing. Modularity may support efficient management of design knowledge and may facilitate...

  18. Study of the Effect of (U0.8Pu0.2O2 Uranium–Plutonium Mixed Fuel Fission Products on a Living Organism

    Directory of Open Access Journals (Sweden)

    Ayagoz Baimukhanova

    2016-08-01

    Full Text Available The article describes the results of experiments conducted on pigs to determine the effect of plutonium, which is the most radiotoxic and highly active element in the range of mixed fuel (U0.8Pu0.2O2 fission products, on living organisms. The results will allow empirical prediction of the emergency plutonium radiation dose for various organs and tissues of humans in case of an accident in a reactor running on mixed fuel (U0.8Pu0.2O2.

  19. Simultaneous measurements of plutonium and uranium in spent-fuel dissolver solutions

    Energy Technology Data Exchange (ETDEWEB)

    Li, T.K. [Los Alamos National Lab., NM (United States); Kuno, T.; Kitagawa, O.; Sato, S.; Kurosawa, A.; Kuno, Y. [Power Reactor and Nuclear Fuel Development Corp., Tokai, Ibaraki (Japan)

    1997-11-01

    The authors have studied the isotope dilution gamma-ray spectrometry (IDGS) technique for simultaneous measurements of elemental concentrations and isotopic compositions for both plutonium and uranium in input spent-fuel dissolver solutions at a reprocessing plant. The technique under development includes both sample preparation and analysis methods. For simultaneous measurements of both plutonium and uranium, a critical issue is to develop a new method to keep both plutonium and uranium in the sample after they are separated from fission products. Furthermore, it is equally important to improve the analysis method so that the precision and accuracy of the plutonium analysis remain unaffected while uranium is retained in the sample. To keep both plutonium and uranium in the sample for simultaneous measurements, extraction chromatography is being studied and shows promise to achieve the goal of cosegregation of the plutonium and uranium. The technique uses U/TEVA{center_dot}Spec resin to separate fission products and recover both uranium and plutonium in the resin from dissolver solutions for subsequent measuring using high-resolution gamma-ray spectrometry. Owing to the fact that the U/Pu ratio is altered during the fission product separation phase, it is necessary to develop a method which could accurately correct for this effect. Such a method was developed using the unique decay properties of {sup 241}Pu to {sup 237}U and shows considerable promise in allowing for accurate determination of the {sup 235}U concentrations before the chemical extraction.

  20. Comparison of actinides and fission products recycling scheme with the normal plutonium recycling scheme in fast reactors

    Directory of Open Access Journals (Sweden)

    Salahuddin Asif

    2013-01-01

    Full Text Available Multiple recycling of actinides and non-volatile fission products in fast reactors through the dry re-fabrication/reprocessing atomics international reduction oxidation process has been studied as a possible way to reduce the long-term potential hazard of nuclear waste compared to that resulting from reprocessing in a wet PUREX process. Calculations have been made to compare the actinides and fission products recycling scheme with the normal plutonium recycling scheme in a fast reactor. For this purpose, the Karlsruhe version of isotope generation and depletion code, KORIGEN, has been modified accordingly. An entirely novel fission product yields library for fast reactors has been created which has replaced the old KORIGEN fission products library. For the purposes of this study, the standard 26 groups data set, KFKINR, developed at Forschungszentrum Karlsruhe, Germany, has been extended by the addition of the cross-sections of 13 important actinides and 68 most important fission products. It has been confirmed that these 68 fission products constitute about 95% of the total fission products yield and about 99.5% of the total absorption due to fission products in fast reactors. The amount of fissile material required to guarantee the criticality of the reactor during recycling schemes has also been investigated. Cumulative high active waste per ton of initial heavy metal is also calculated. Results show that the recycling of actinides and fission products in fast reactors through the atomics international reduction oxidation process results in a reduction of the potential hazard of radioactive waste.

  1. State power plant productivity programs

    Energy Technology Data Exchange (ETDEWEB)

    1981-02-01

    The findings of a working group formed to review the status of efforts by utilities and utility regulators to increase the availability and reliability of generating units are presented. Representatives from nine state regulatory agencies, NRRI, and DOE, participated on the Working Group. The Federal government has been working cooperatively with utilities, utility organizations, and with regulators to encourage and facilitate improvements in power plant productivity. Cooperative projects undertaken with regulatory and energy commissions in California, Illinois, New York, Ohio, Texas, North Carolina and Mighigan are described. Following initiation of these cooperative projects, DOE funded a survey to determine which states were explicitly addressing power plant productivity through the regulatory process. The Working Group was formed following completion of this survey. The Working Group emphasized the need for those power plant productivity improvements which are cost effective. The cost effectiveness of proposed availability improvement projects should be determined within the context of opportunities for operating and capital improvements available to an entire utility. The Working Group also identified the need for: allowing for plant designs that have a higher construction cost, but are also more reliable; allowing for recovery and reducing recovery lags for productivity-related capital expenditures; identifying and reducing disincentives in the regulatory process; ascertaining that utilities have sufficient money available to undertake timely maintenance; and support of EPRI and NERC to develop a relevant and accurate national data base. The DOE views these as extremely important aspects of any regulatory program to improve power plant productivity.

  2. Radioecology of natural systems. Fifteenth annual progress report, August 1, 1976--July 31, 1977. [Plutonium transport in terrestrial ecosystems at Rocky Flats Plant with emphasis on biological effects on mule deer and coyotes

    Energy Technology Data Exchange (ETDEWEB)

    Whicker, F.W.

    1977-08-01

    This report summarizes project activities during the period August 1, 1976 through July 31, 1977. Four major areas of effort are reported, namely plutonium behavior in a terrestrial ecosystem at Rocky Flats, mule deer and coyote studies at Rocky Flats, ecological consequences of transuranics in the terrestrial environment, and lead geochemistry of an alpine lake ecosystem. Much of the first area of effort involved the synthesis of data and preparation of manuscripts, although some new data are reported on plutonium levels in small mammals, plant uptake of plutonium from contaminated soil, and plutonium deposition rates on macroplot 1. The mule deer studies generated a substantial body of new information which will permit quantitative assessment of plutonium dispersion by deer that utilize contaminated areas. These studies involve population dynamics, movement and use patterns, food habits, ingestion rates of contaminated soil and vegetation and plutonium burdens of deer tissues. A related study of coyote food habits in summer at Rocky Flats is reported. A manuscript dealing with the question of ecological effects of transuranics was prepared. This manuscript incorporates data from Rocky Flats on characteristics of natural populations which occupy ecologically similar areas having differing levels of plutonium contamination. The lead geochemistry studies continued to generate new data but the data are not yet reported.

  3. PLUTONIUM UPTAKE AND BEHAVIOR IN PLANTS OF THE DESERT SOUTHWEST: A PRELIMINARY ASSESSMENT

    Energy Technology Data Exchange (ETDEWEB)

    Caldwell, E.; Duff, M.; Ferguson, C.

    2011-03-01

    Eight species of desert vegetation and associated soils were collected from the Nevada National Security Site (N2S2) and analyzed for 238Pu and 239+240Pu concentrations. Amongst the plant species sampled were: atmospheric elemental accumulators (moss and lichen), the very slow growing, long-lived creosote bush and the rapidly growing, short-lived cheatgrass brome. The diversity of growth strategies provided insight into the geochemical behavior and bio-availability of Pu at the N2S2. The highest concentrations of Pu were measured in the onion moss (24.27 Bq kg-1 238Pu and 52.78 Bq kg-1 239+240Pu) followed by the rimmed navel lichen (8.18 Bq kg-1 and 18.4 Bq kg-1 respectively), pointing to the importance of eolian transport of Pu. Brome and desert globemallow accumulated between 3 and 9 times higher concentrations of Pu than creosote and sage brush species. These results support the importance of species specific elemental accumulation strategies rather than exposure duration as the dominant variable influencing Pu concentrations in these plants. Total vegetation elemental concentrations of Ce, Fe, Al, Sm and others were also analyzed. Strong correlations were observed between Fe and Pu. This supports the conclusion that Pu was accumulated as a consequence of the active accumulation of Fe and other plant required nutrients. Cerium and Pu are considered to be chemical analogs. Strong correlations observed in plants support the conclusion that these elements displayed similar geochemical behavior in the environment as it related to the biochemical uptake process of vegetation. Soils were also sampled in association with vegetation samples. This allowed for the calculation of a concentration ratio (CR). The CR values for Pu in plants were highly influenced by the heterogeneity of Pu distribution among sites. Results from the naturally occurring elements of concern were more evenly distributed between sample sites. This allowed for the development of a pattern of plant

  4. Alert Systems for production Plants

    DEFF Research Database (Denmark)

    Nielsen, Thomas Dyhre; Jensen, Finn Verner

    2005-01-01

    We present a new methodology for detecting faults and abnormal behavior in production plants. The methodology stems from a joint project with a Danish energy consortium. During the course of the project we encountered several problems that we believe are common for projects of this type. Most...... system operation, i.e., it does not rely on information about the possible faults. We illustrate the proposed method using real-world data from a coal driven power plant as well as simulated data from an oil production facility....

  5. Natural products for plant protection

    Directory of Open Access Journals (Sweden)

    Čeković Živorad

    2006-01-01

    Full Text Available The advantage applying natural products, such as a secondary metabolites, in plant protection is shortly presented. Acceptable solutions for the enhanced ecological criteria, which are requested by the users of pesticides and consumers of agricultural goods, could be the replacement of classical pesticides by natural products in plant protection. Some natural products are already in use as insecticides, herbicides and fungicides because new biotechnological processes, fermentation and biotransformations provide procedures for their industrial production. In addition to biotechnical processes natural compounds possessing pesticide activities are also prepared by chemical synthesis. An active secondary metabolite must first be isolated from natural sauces and then, based on biological toxicological and ecological studies, acceptable compounds are selected for laboratory and industrial chemical synthesis. Several compounds possessing insecticidal, herbicidal and fungicidal activities, which have been successfully applied for plan protection are presented.

  6. Wet water glass production plant

    Directory of Open Access Journals (Sweden)

    Stanković Mirjana S.

    2003-01-01

    Full Text Available The IGPC Engineering Department designed basic projects for a wet hydrate dissolution plant, using technology developed in the IGPC laboratories. Several projects were completed: technological, machine, electrical, automation. On the basis of these projects, a production plant of a capacity of 75,000 t/y was manufactured, at "Zeolite Mira", Mira (VE, Italy, in 1997. and 1998, increasing detergent zeolite production, from 50,000 to 100,000 t/y. Several goals were realized by designing a wet hydrate dissolution plant. The main goal was increasing the detergent zeolite production. The technological cycle of NaOH was closed, and no effluents emitted, and there is no pollution (except for the filter cake. The wet water glass production process is fully automatized, and the product has uniform quality. The production process can be controlled manually, which is necessary during start - up, and repairs. By installing additional process equipment (centrifugal pumps and heat exchangers technological bottlenecks were overcome, and by adjusting the operation of autoclaves, and water glass filters and also by optimizing the capacities of process equipment.

  7. Plant senescence and crop productivity

    DEFF Research Database (Denmark)

    Gregersen, Per L.; Culetic, Andrea; Boschian, Luca

    2013-01-01

    Senescence is a developmental process which in annual crop plants overlaps with the reproductive phase. Senescence might reduce crop yield when it is induced prematurely under adverse environmental conditions. This review covers the role of senescence for the productivity of crop plants. With the......Senescence is a developmental process which in annual crop plants overlaps with the reproductive phase. Senescence might reduce crop yield when it is induced prematurely under adverse environmental conditions. This review covers the role of senescence for the productivity of crop plants....... With the aim to enhance productivity, a number of functional stay-green cultivars have been selected by conventional breeding, in particular of sorghum and maize. In many cases, a positive correlation between leaf area duration and yield has been observed, although in a number of other cases, stay......-green cultivars do not display significant effects with regards to productivity. In several crops, the stay-green phenotype is observed to be associated with a higher drought resistance and a better performance under low nitrogen conditions. Among the approaches used to achieve stay-green phenotypes in transgenic...

  8. Cimarrones y palenques en las provincias al norte del Nuevo Reino de Granada siglo XVII

    Directory of Open Access Journals (Sweden)

    María Cristina Navarrete P.

    2001-01-01

    Full Text Available A finales del siglo XVII, ya existían comunidades de cimarrones en varias provincias de la jurisdicción de la Audiencia del Nuevo Reino de Granada. Hacia 1598, en Zaragoza, y en 1607, en Remedios, provincia de Antioquia, esclavos negros de las rancherías mineras se levantaron violentamente y fortificaron en palenques, causando perjuicios en el comercio, la vida de las ciudades y la labor de las minas. Otro de los más importantes alzamientos de esclavos fue el dirigido por Domingo Biohó quien se refugió con sus seguidores en la Ciénaga de la Matuna. Asimismo, las Sierras de María y la Serranía de San Lucas fueron espacios de establecimiento de palenques. Los cimarrones intentaron reconstruir organizaciones sociales con base en la herencia cultural africana, en la permanencia en las haciendas y minas al contacto con amos, capataces y compañeros de circunstancias y, en las nuevas condiciones que les ofrecía la vida de los palenques.

  9. Dairy Product Manufacturing Costs at Cooperative Plants

    OpenAIRE

    Ling, K. Charles

    1983-01-01

    Cost data are summarized for 14 plants manufacturing cheese, butter, and powder and average costs are presented for each product. Average cost curves are estimated for each plant. The scale of plant for least-cost operations is identified for plants of each product type. Plant capacity utilization and seasonal volume variation and their impacts on manufacturing cost are delineated.

  10. 77 FR 14010 - Rocky Ridge Wind Project, LLC, Blackwell Wind, LLC, CPV Cimarron Renewable Energy Company, LLC...

    Science.gov (United States)

    2012-03-08

    ... Cimarron Renewable Energy Company, LLC, Minco Wind Interconnection Services, LLC, Shiloh III Lessee, LLC, California Ridge Wind Energy LLC, Perrin Ranch Wind, LLC, Erie Wind, LLC: Notice of Effectiveness of Exempt... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY...

  11. 78 FR 29318 - Pike and San Isabel National Forests and Cimarron and Comanche National Grasslands, Colorado and...

    Science.gov (United States)

    2013-05-20

    ... Forest Service Pike and San Isabel National Forests and Cimarron and Comanche National Grasslands.... ACTION: Notice of intent to prepare an environmental impact statement. SUMMARY: The Pike and San Isabel... provides public meeting addresses, dates and times. ADDRESSES: Send written comments to: Pike and...

  12. Transfer of Plutonium-Uranium Extraction Plant and N Reactor irradiated fuel for storage at the 105-KE and 105-KW fuel storage basins, Hanford Site, Richland Washington

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    The U.S. Department of Energy (DOE) needs to remove irradiated fuel from the Plutonium-Uranium Extraction (PUREX) Plant and N Reactor at the Hanford Site, Richland, Washington, to stabilize the facilities in preparation for decontamination and decommissioning (D&D) and to reduce the cost of maintaining the facilities prior to D&D. DOE is proposing to transfer approximately 3.9 metric tons (4.3 short tons) of unprocessed irradiated fuel, by rail, from the PUREX Plant in the 200 East Area and the 105 N Reactor (N Reactor) fuel storage basin in the 100 N Area, to the 105-KE and 105-KW fuel storage basins (K Basins) in the 100 K Area. The fuel would be placed in storage at the K Basins, along with fuel presently stored, and would be dispositioned in the same manner as the other existing irradiated fuel inventory stored in the K Basins. The fuel transfer to the K Basins would consolidate storage of fuels irradiated at N Reactor and the Single Pass Reactors. Approximately 2.9 metric tons (3.2 short tons) of single-pass production reactor, aluminum clad (AC) irradiated fuel in four fuel baskets have been placed into four overpack buckets and stored in the PUREX Plant canyon storage basin to await shipment. In addition, about 0.5 metric tons (0.6 short tons) of zircaloy clad (ZC) and a few AC irradiated fuel elements have been recovered from the PUREX dissolver cell floors, placed in wet fuel canisters, and stored on the canyon deck. A small quantity of ZC fuel, in the form of fuel fragments and chips, is suspected to be in the sludge at the bottom of N Reactor`s fuel storage basin. As part of the required stabilization activities at N Reactor, this sludge would be removed from the basin and any identifiable pieces of fuel elements would be recovered, placed in open canisters, and stored in lead lined casks in the storage basin to await shipment. A maximum of 0.5 metric tons (0.6 short tons) of fuel pieces is expected to be recovered.

  13. Methane production from plant biomass

    Energy Technology Data Exchange (ETDEWEB)

    Zauner, E.

    1985-01-01

    Methane fermentations of plant biomass were performed to increase basic knowledge necessary for development of suitable conversion technologies. Effects of bacterial inoculants, substrate compounds and varied process conditions were analyzed in batch and continuous fermentation experiments. Use of enriched bacterial populations precultured and adapted to plant materials was proved to be advantageous for inoculation. Methane yields and productivities as well as chemical and bacterial composition of digester fluids were determined at various loading rates and retention times during fermentation of different grass and maize silages. Recycling for favorable amounts of decomposed effluent for neutralization of supplied acid raw materials was important to achieve high methane yields. Quantity and composition of acido-, aceto- and methanogenic bacteria were not essentially influenced by changed fermentation conditions. Results of these laboratory examinations have to be completed by long run and scale up experiments to develop control parameters for plant biogas digesters.

  14. Aqueous Chloride Operations Overview: Plutonium and Americium Purification/Recovery

    Energy Technology Data Exchange (ETDEWEB)

    Kimball, David Bryan [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Skidmore, Bradley Evan [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-06-22

    Acqueous Chloride mission is to recover plutonium and americium from pyrochemical residues (undesirable form for utilization and storage) and generate plutonium oxide and americium oxide. Plutonium oxide is recycled into Pu metal production flowsheet. It is suitable for storage. Americium oxide is a valuable product, sold through the DOE-OS isotope sales program.

  15. 238Pu: accumulation, tissue distribution, and excretion in Mayak workers after exposure to plutonium aerosols.

    Science.gov (United States)

    Suslova, Klara G; Sokolova, Alexandra B; Khokhryakov, Viktor V; Miller, Scott C

    2012-03-01

    The alpha spectrometry measurements of specific activity of 238Pu and 239Pu in urine from bioassay examinations of 1,013 workers employed at the radiochemical and plutonium production facilities of the Mayak Production Association and in autopsy specimens of lung, liver, and skeleton from 85 former nuclear workers who died between 1974-2009, are summarized.The accumulation fraction of 238Pu in the body and excreta has not changed with time in workers involved in production of weapons-grade plutonium production (e.g., the plutonium production facility and the former radiochemical facility). The accumulation fraction of 238Pu in individuals exposed to plutonium isotopes at the newer Spent Nuclear Fuel Reprocessing Plant ranged from 0.13% up to 27.5% based on the autopsy data. No statistically significant differences between 238Pu and 239Pu in distribution by the main organs of plutonium deposition were found in the Mayak workers. Based on the bioassay data,the fraction of 238Pu activity in urine is on average 38-69% of the total activity of 238Pu and 239Pu, which correlates with the isotopic composition in workplace air sampled at the Spent Nuclear Fuel Reprocessing Plant. In view of the higher specific activity of 238Pu, the contribution of 238Pu to the total internal dose, particularly in the skeleton and liver, might be expected to continue to increase, and continued surveillance is recommended.

  16. Seaborg's Plutonium ?

    CERN Document Server

    Norman, Eric B; Telhami, Kristina E

    2014-01-01

    Passive x-ray and gamma-ray analysis was performed on UC Berkeley's EH&S Sample S338. The object was found to contain Pu-239 and no other radioactive isotopes. The mass of Pu-239 contained in this object was determined to be 2.0 +- 0.3 micrograms. These observations are consistent with the identification of this object being the 2.77-microgram plutonium oxide sample described by Glenn Seaborg and his collaborators as the first sample of Pu-239 that was large enough to be weighed.

  17. Digital data sets that describe aquifer characteristics of the alluvial and terrace deposits along the Cimarron River from Freedom to Guthrie in northwestern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digital aquifer boundaries for the alluvial and terrace deposits along the Cimarron River from Freedom to Guthrie in northwestern Oklahoma....

  18. Digital data sets that describe aquifer characteristics of the alluvial and terrace deposits along the Cimarron River from Freedom to Guthrie in northwestern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digital polygons of constant hydraulic conductivity values for the alluvial and terrace deposits along the Cimarron River from Freedom to...

  19. Digital data sets that describe aquifer characteristics of the alluvial and terrace deposits along the Cimarron River from Freedom to Guthrie in northwestern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digital water-level elevation contours for the alluvial and terrace deposits along the Cimarron River in northwestern Oklahoma during...

  20. Digital data sets that describe aquifer characteristics of the alluvial and terrace deposits along the Cimarron River from Freedom to Guthrie in northwestern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digital polygons of a constant recharge rate for the alluvial and terrace deposits along the Cimarron River from Freedom to Guthrie in...

  1. Plutonium, {sup 137}Cs and {sup 90}Sr in selected invertebrates from some areas around Chernobyl nuclear power plant

    Energy Technology Data Exchange (ETDEWEB)

    Mietelski, Jerzy W., E-mail: jerzy.mietelski@ifj.edu.p [Henryk Niewodniczanski Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego 152, 31-342 Krakow (Poland); Maksimova, Svetlana, E-mail: soilzool@biobel.bas-net.b [Institute of Zoology, National Academy of Sciences, Akademicheskaya 27, 220072 Minsk (Belarus); Szwalko, Przemyslaw [Institute of Systematics and Evolution of Animals, Polish Academy of Sciences, Slawkowska 17, 31-016 Krakow (Poland); Wnuk, Katarzyna [Holycross Cancer Center, Department on Nuclear Medicine, Artwinskiego 3, 25-734 Kielce (Poland); Zagrodzki, Pawel [Henryk Niewodniczanski Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego 152, 31-342 Krakow (Poland); Department of Food Chemistry and Nutrition, Medical College, Jagiellonian University, Medyczna 9, 30-688 Krakow (Poland); Blazej, Sylwia; Gaca, Pawel; Tomankiewicz, Ewa [The Henryk Niewodniczanski Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego 152, 31-342 Krakow (Poland); Orlov, Olexandr, E-mail: station@zt.ukrpack.ne [Poleskiy Branch of Ukrainian Scientific Research Institute of Forestry and Agro-Forest-Amelioration, Prospect Mira 38, Zhytomyr 10004 (Ukraine)

    2010-06-15

    Results are presented for {sup 137}Cs, {sup 90}Sr and plutonium activity concentrations in more than 20 samples of terrestrial invertebrates, including species of beetles, ants, spiders and millipedes, collected in the highly contaminated area of the Chernobyl exclusion zone. The majority of samples were collected in Belarus, with some also collected in the Ukraine. Three other samples were collected in an area of lower contamination. Results show that seven samples exceed an activity concentration of 100 kBq/kg (ash weight - a.w.) for {sup 137}Cs. The maximum activity concentration for this isotope was 1.52 +- 0.08 MBq/kg (a.w.) determined in ants (Formica cynerea). Seven results for {sup 90}Sr exceeded 100 kBq/kg (a.w.), mostly for millipedes. Relatively high plutonium activity concentrations were found in some ants and earth-boring dung beetles. Analyses of activity ratios showed differences in transfer of radionuclides between species. To reveal the correlation structure of the multivariate data set, the Partial Least-Squares method (PLS) was used. Results of the PLS model suggest that high radiocesium activity concentrations in animal bodies can be expected mainly for relatively small creatures living on the litter surface. In contrast, high strontium activity concentrations can be expected for creatures which conduct their lives within litter, having mixed trophic habits and a moderate lifespan. No clear conclusions could be made for plutonium.

  2. Selecting a plutonium vitrification process

    Energy Technology Data Exchange (ETDEWEB)

    Jouan, A. [Centre d`Etudes de la Vallee du Rhone, Bagnols sur Ceze (France)

    1996-05-01

    Vitrification of plutonium is one means of mitigating its potential danger. This option is technically feasible, even if it is not the solution advocated in France. Two situations are possible, depending on whether or not the glass matrix also contains fission products; concentrations of up to 15% should be achievable for plutonium alone, whereas the upper limit is 3% in the presence of fission products. The French continuous vitrification process appears to be particularly suitable for plutonium vitrification: its capacity is compatible with the required throughout, and the compact dimensions of the process equipment prevent a criticality hazard. Preprocessing of plutonium metal, to convert it to PuO{sub 2} or to a nitric acid solution, may prove advantageous or even necessary depending on whether a dry or wet process is adopted. The process may involve a single step (vitrification of Pu or PuO{sub 2} mixed with glass frit) or may include a prior calcination step - notably if the plutonium is to be incorporated into a fission product glass. It is important to weigh the advantages and drawbacks of all the possible options in terms of feasibility, safety and cost-effectiveness.

  3. Plutonium release from Fukushima Daiichi fosters the need for more detailed investigations.

    Science.gov (United States)

    Schneider, Stephanie; Walther, Clemens; Bister, Stefan; Schauer, Viktoria; Christl, Marcus; Synal, Hans-Arno; Shozugawa, Katsumi; Steinhauser, Georg

    2013-10-18

    The contamination of Japan after the Fukushima accident has been investigated mainly for volatile fission products, but only sparsely for actinides such as plutonium. Only small releases of actinides were estimated in Fukushima. Plutonium is still omnipresent in the environment from previous atmospheric nuclear weapons tests. We investigated soil and plants sampled at different hot spots in Japan, searching for reactor-borne plutonium using its isotopic ratio ²⁴⁰Pu/²³⁹Pu. By using accelerator mass spectrometry, we clearly demonstrated the release of Pu from the Fukushima Daiichi power plant: While most samples contained only the radionuclide signature of fallout plutonium, there is at least one vegetation sample whose isotope ratio (0.381 ± 0.046) evidences that the Pu originates from a nuclear reactor (²³⁹⁺²⁴⁰Pu activity concentration 0.49 Bq/kg). Plutonium content and isotope ratios differ considerably even for very close sampling locations, e.g. the soil and the plants growing on it. This strong localization indicates a particulate Pu release, which is of high radiological risk if incorporated.

  4. Productivity growth patterns in US dairy products manufacturing plants

    NARCIS (Netherlands)

    Geylani, P.C.; Stefanou, S.E.

    2011-01-01

    We analyse the productivity growth patterns in the US dairy products industry using the Census Bureau's plant-level data set. We decompose Total Factor Productivity (TFP) growth into the scale and technical change components and analyse variability of plants' productivity by constructing transition

  5. Assessment of plutonium in the Savannah River Site environment. Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    Carlton, W.H.; Evans, A.G.; Geary, L.A.; Murphy, C.E. Jr.; Pinder, J.E.; Strom, R.N.

    1992-12-31

    Plutonium in the Savannah River Site Environment is published as a part of the Radiological Assessment Program (RAP). It is the fifth in a series of eight documents on individual radioisotopes released to the environment as a result of Savannah River Site (SRS) operations. These are living documents, each to be revised and updated on a two-year schedule. This document describes the sources of plutonium in the environment, its release from SRS, environmental transport and ecological concentration of plutonium, and the radiological impact of SRS releases to the environment. Plutonium exists in the environment as a result of above-ground nuclear weapons tests, the Chernobyl accident, the destruction of satellite SNAP 9-A, plane crashes involving nuclear weapons, and small releases from reactors and reprocessing plants. Plutonium has been produced at SRS during the operation of five production reactors and released in small quantities during the processing of fuel and targets in chemical separations facilities. Approximately 0.6 Ci of plutonium was released into streams and about 12 Ci was released to seepage basins, where it was tightly bound by clay in the soil. A smaller quantity, about 3.8 Ci, was released to the atmosphere. Virtually all releases have occurred in F- and H-Area separation facilities. Plutonium concentration and transport mechanisms for the atmosphere, surface water, and ground water releases have been extensively studied by Savannah River Technology Center (SRTC) and ecological mechanisms have been studied by Savannah River Ecology Laboratory (SREL). The overall radiological impact of SRS releases to the offsite maximum individual can be characterized by a total dose of 15 mrem (atmospheric) and 0.18 mrem (liquid), compared with the dose of 12,960 mrem from non-SRS sources during the same period of time (1954--1989). Plutonium releases from SRS facilities have resulted in a negligible impact to the environment and the population it supports.

  6. Water quality and possible sources of nitrate in the Cimarron Terrace Aquifer, Oklahoma, 2003

    Science.gov (United States)

    Masoner, Jason R.; Mashburn, Shana L.

    2004-01-01

    Water from the Cimarron terrace aquifer in northwest Oklahoma commonly has nitrate concentrations that exceed the maximum contaminant level of 10 milligrams per liter of nitrite plus nitrate as nitrogen (referred to as nitrate) set by the U.S. Environmental Protection Agency for public drinking water supplies. Starting in July 2003, the U.S. Geological Survey, in cooperation with the Oklahoma Department of Environmental Quality, conducted a study in the Cimarron terrace aquifer to assess the water quality and possible sources of nitrate. A qualitative and quantitative approach based on multiple lines of evidence from chemical analysis of nitrate, nitrogen isotopes in nitrate, pesticides (indicative of cropland fertilizer application), and wastewater compounds (indicative of animal or human wastewater) were used to indicate possible sources of nitrate in the Cimarron terrace aquifer. Nitrate was detected in 44 of 45 ground-water samples and had the greatest median concentration (8.03 milligrams per liter) of any nutrient analyzed. Nitrate concentrations ranged from nitrate concentrations exceeding the maximum contaminant level of 10 milligrams per liter. Nitrate concentrations in agricultural areas were significantly greater than nitrate concentrations in grassland areas. Pesticides were detected in 15 of 45 ground-water samples. Atrazine and deethylatrazine, a metabolite of atrazine, were detected most frequently. Deethylatrazine was detected in water samples from 9 wells and atrazine was detected in samples from 8 wells. Tebuthiuron was detected in water samples from 5 wells; metolachlor was detected in samples from 4 wells; prometon was detected in samples from 4 wells; and alachlor was detected in 1 well. None of the detected pesticide concentrations exceeded the maximum contaminant level or health advisory level set by the U.S. Environmental Protection Agency. Wastewater compounds were detected in 28 of 45 groundwater samples. Of the 20 wastewater compounds

  7. Development of an Efficient Approach to Perform Neutronics Simulations for Plutonium-238 Production

    Energy Technology Data Exchange (ETDEWEB)

    Chandler, David [ORNL; Ellis, Ronald James [ORNL

    2016-01-01

    Conversion of 238Pu decay heat into usable electricity is imperative to power National Aeronautics and Space Administration (NASA) deep space exploration missions; however, the current stockpile of 238Pu is diminishing and the quality is less than ideal. In response, the US Department of Energy and NASA have undertaken a program to reestablish a domestic 238Pu production program and a technology demonstration sub-project has been initiated. Neutronics simulations for 238Pu production play a vital role in this project because the results guide reactor safety-basis, target design and optimization, and post-irradiation examination activities. A new, efficient neutronics simulation tool written in Python was developed to evaluate, with the highest fidelity possible with approved tools, the time-dependent nuclide evolution and heat deposition rates in 238Pu production targets irradiated in the High Flux Isotope Reactor (HFIR). The Python Activation and Heat Deposition Script (PAHDS) was developed specifically for experiment analysis in HFIR and couples the MCNP5 and SCALE 6.1.3 software quality assured tools to take advantage of an existing high-fidelity MCNP HFIR model, the most up-to-date ORIGEN code, and the most up-to-date nuclear data. Three cycle simulations were performed with PAHDS implementing ENDF/B-VII.0, ENDF/B-VII.1, and the Hybrid Library GPD-Rev0 cross-section libraries. The 238Pu production results were benchmarked against VESTA-obtained results and the impact of various cross-section libraries on the calculated metrics were assessed.

  8. Medical Radioisotope Production in a Power-Flattened ADS Fuelled with Uranium and Plutonium Dioxides

    Directory of Open Access Journals (Sweden)

    Gizem Bakır

    2016-01-01

    Full Text Available This study presents the medical radioisotope production performance of a conceptual accelerator driven system (ADS. Lead-bismuth eutectic (LBE is selected as target material. The subcritical fuel core is conceptually divided into ten equidistant subzones. The ceramic (natural U, PuO2 fuel mixture and the materials used for radioisotope production (copper, gold, cobalt, holmium, rhenium, thulium, mercury, palladium, thallium, molybdenum, and yttrium are separately prepared as cylindrical rods cladded with carbon/carbon composite (C/C and these rods are located in the subzones. In order to obtain the flattened power density, percentages of PuO2 in the mixture of UO2 and PuO2 in the subzones are adjusted in radial direction of the fuel zone. Time-dependent calculations are performed at 1000 MW thermal fission power (Pth for one hour using the BURN card. The neutronic results show that the investigated ADS has a high neutronic capability, in terms of medical radioisotope productions, spent fuel transmutation and energy multiplication. Moreover, a good quasiuniform power density is achieved in each material case. The peak-to-average fission power density ratio is in the range of 1.02–1.28.

  9. Plutonium Training Opportunities

    Energy Technology Data Exchange (ETDEWEB)

    Balatsky, Galya Ivanovna [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Wolkov, Benjamin [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-03-26

    This report was created to examine the current state of plutonium training in the United States and to discover ways in which to ensure that the next generation of plutonium workers are fully qualified.

  10. PLUTONIUM-THORIUM ALLOYS

    Science.gov (United States)

    Schonfeld, F.W.

    1959-09-15

    New plutonium-base binary alloys useful as liquid reactor fuel are described. The alloys consist of 50 to 98 at.% thorium with the remainder plutonium. The stated advantages of these alloys over unalloyed plutonium for reactor fuel use are easy fabrication, phase stability, and the accompanying advantuge of providing a means for converting Th/sup 232/ into U/sup 233/.

  11. PLUTONIUM CLEANING PROCESS

    Science.gov (United States)

    Kolodney, M.

    1959-12-01

    A method is described for rapidly removing iron, nickel, and zinc coatings from plutonium objects while simultaneously rendering the plutonium object passive. The method consists of immersing the coated plutonium object in an aqueous acid solution containing a substantial concentration of nitrate ions, such as fuming nitric acid.

  12. Determination of Uranium and Plutonium Concentration in 1AF by Isotopic Dilution Mass Spectrometry Methods

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>It is important data to measure uranium and plutonium concentration for the reprocessing plant control analysis. The determination of uranium and plutonium concentration in 1AF by isotopic dilution mass

  13. Photovoltaic power plants: production calculation

    Energy Technology Data Exchange (ETDEWEB)

    Cirillo, E.; Lazzarin, R.

    Rational sizing of a photovoltaic plant requires a good evaluation of the obtainable electric energy as a function of the many meteorological and plant parameters. A computing procedure is described in detail together with a fully developed numerical example. The procedure is based on monthly usability. It is reliable and it allows designers to take into account the influence of the main plant parameters within rather wide ranges.

  14. Interaction of Plutonium with Bacteria in the Repository Environment

    Energy Technology Data Exchange (ETDEWEB)

    Gillow, J. B.; Francis, A. J.; Lucero, D. A.; Papenguth, H. W.

    2000-07-01

    Microorganisms in the nuclear waste repository environment may interact with plutonium through (1) sorption, (2) intracellular accumulation, and (3) transformation speciation. These interactions may retard or enhance the mobility of Pu by precipitation reactions, biocolloid formation, or production of more soluble species. Current and planned radioactive waste repository environments, such as deep subsurface halite and granite formations, are considered extreme relative to life processes in the near-surface terrestrial environment. There is a paucity of information on the biotransformation of radionuclides by microorganisms present in such extreme environments. In order to gain a better understanding of the interaction of plutonium with microorganisms present in the waste repository sites we investigated a pure culture (Halomonas sp.) and a mixed culture of bacteria (Haloarcula sinaiiensis, Marinobacter hydrocarbonoclasticus, Altermonas sp., and a {gamma}-proteobacterium) isolated from the Waste Isolation Pilot Plant (WIPP) site and an Acetobacterium sp. from alkaline groundwater at the Grimsel Test Site in Switzerland.

  15. Iron nutrition, biomass production, and plant product quality.

    Science.gov (United States)

    Briat, Jean-François; Dubos, Christian; Gaymard, Frédéric

    2015-01-01

    One of the grand challenges in modern agriculture is increasing biomass production, while improving plant product quality, in a sustainable way. Of the minerals, iron (Fe) plays a major role in this process because it is essential both for plant productivity and for the quality of their products. Fe homeostasis is an important determinant of photosynthetic efficiency in algae and higher plants, and we review here the impact of Fe limitation or excess on the structure and function of the photosynthetic apparatus. We also discuss the agronomic, plant breeding, and transgenic approaches that are used to remediate Fe deficiency of plants on calcareous soils, and suggest ways to increase the Fe content and bioavailability of the edible parts of crops to improve human diet.

  16. AVLIS Production Plant Project Management Plan

    Energy Technology Data Exchange (ETDEWEB)

    1984-11-15

    The AVLIS Production Plant is designated as a Major System Acquisition (in accordance with DOE Order 4240.IC) to deploy Atomic Vapor Laser Isotope Separation (AVLIS) technology at the Oak Ridge, Tennessee site, in support of the US Uranium Enrichment Program. The AVLIS Production Plant Project will deploy AVLIS technology by performing the design, construction, and startup of a production plant that will meet capacity production requirements of the Uranium Enrichment Program. The AVLIS Production Plant Project Management Plan has been developed to outline plans, baselines, and control systems to be employed in managing the AVLIS Production Plant Project and to define the roles and responsibilities of project participants. Participants will develop and maintain detailed procedures for implementing the management and control systems in agreement with this plan. This baseline document defines the system that measures work performed and costs incurred. This plan was developed by the AVLIS Production Plant Project staff of Martin Marietta Energy Systems, Inc. and Lawrence Livermore National Laboratory in accordance with applicable DOE directives, orders and notices. 38 figures, 19 tables.

  17. Modifying plants for biofuel and biomaterial production.

    Science.gov (United States)

    Furtado, Agnelo; Lupoi, Jason S; Hoang, Nam V; Healey, Adam; Singh, Seema; Simmons, Blake A; Henry, Robert J

    2014-12-01

    The productivity of plants as biofuel or biomaterial crops is established by both the yield of plant biomass per unit area of land and the efficiency of conversion of the biomass to biofuel. Higher yielding biofuel crops with increased conversion efficiencies allow production on a smaller land footprint minimizing competition with agriculture for food production and biodiversity conservation. Plants have traditionally been domesticated for food, fibre and feed applications. However, utilization for biofuels may require the breeding of novel phenotypes, or new species entirely. Genomics approaches support genetic selection strategies to deliver significant genetic improvement of plants as sources of biomass for biofuel manufacture. Genetic modification of plants provides a further range of options for improving the composition of biomass and for plant modifications to assist the fabrication of biofuels. The relative carbohydrate and lignin content influences the deconstruction of plant cell walls to biofuels. Key options for facilitating the deconstruction leading to higher monomeric sugar release from plants include increasing cellulose content, reducing cellulose crystallinity, and/or altering the amount or composition of noncellulosic polysaccharides or lignin. Modification of chemical linkages within and between these biomass components may improve the ease of deconstruction. Expression of enzymes in the plant may provide a cost-effective option for biochemical conversion to biofuel.

  18. Natural products – learning chemistry from plants

    NARCIS (Netherlands)

    Staniek, A.; Bouwmeester, H.J.; Fraser, P.D.; Kayser, O.; Martens, S.; Tissier, A.; Krol, van der A.R.; Wessjohann, L.; Warzecha, H.

    2014-01-01

    Plant natural products (PNPs) are unique in that they represent a vast array of different structural features, ranging from relatively simple molecules to very complex ones. Given the fact that many plant secondary metabolites exhibit profound biological activity, they are frequently used as fragran

  19. Characterization of plutonium-bearing wastes by chemical analysis and analytical electron microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Behrens, R.G. [Los Alamos National Lab., NM (United States); Buck, E.C.; Dietz, N.L.; Bates, J.K.; Van Deventer, E.; Chaiko, D.J. [Argonne National Lab., IL (United States)

    1995-09-01

    This report summarizes the results of characterization studies of plutonium-bearing wastes produced at the US Department of Energy weapons production facilities. Several different solid wastes were characterized, including incinerator ash and ash heels from Rocky Flats Plant and Los Alamos National Laboratory; sand, stag, and crucible waste from Hanford; and LECO crucibles from the Savannah River Site. These materials were characterized by chemical analysis and analytical electron microscopy. The results showed the presence of discrete PuO{sub 2}PuO{sub 2{minus}x}, and Pu{sub 4}O{sub 7} phases, of about 1{mu}m or less in size, in all of the samples examined. In addition, a number of amorphous phases were present that contained plutonium. In all the ash and ash heel samples examined, plutonium phases were found that were completely surrounded by silicate matrices. Consequently, to achieve optimum plutonium recovery in any chemical extraction process, extraction would have to be coupled with ultrafine grinding to average particle sizes of less than 1 {mu}m to liberate the plutonium from the surrounding inert matrix.

  20. Assessment of PWR plutonium burners for nuclear energy centers

    Energy Technology Data Exchange (ETDEWEB)

    Frankel, A J; Shapiro, N L

    1976-06-01

    The purpose of the study was to explore the performance and safety characteristics of PWR plutonium burners, to identify modifications to current PWR designs to enhance plutonium utilization, to study the problems of deploying plutonium burners at Nuclear Energy Centers, and to assess current industrial capability of the design and licensing of such reactors. A plutonium burner is defined to be a reactor which utilizes plutonium as the sole fissile addition to the natural or depleted uranium which comprises the greater part of the fuel mass. The results of the study and the design analyses performed during the development of C-E's System 80 plant indicate that the use of suitably designed plutonium burners at Nuclear Energy Centers is technically feasible.

  1. Solar Thermochemical Hydrogen Production Plant Design

    OpenAIRE

    Littlefield, Jesse

    2012-01-01

    A plant was designed that uses a solar sulfur-ammonia thermochemical water-splitting cycle for the production of hydrogen. Hydrogen is useful as a fuel for stationary and mobile fuel cells. The chemical process simulator Aspen Plus® was used to model the plant and conduct simulations. The process utilizes the electrolytic oxidation of aqueous ammonium sulfite in the hydrogen production half cycle and the thermal decomposition of molten potassium pyrosulfate and gaseous sulfur trioxide in t...

  2. PLUTONIUM-ZIRCONIUM ALLOYS

    Science.gov (United States)

    Schonfeld, F.W.; Waber, J.T.

    1960-08-30

    A series of nuclear reactor fuel alloys consisting of from about 5 to about 50 at.% zirconium (or higher zirconium alloys such as Zircaloy), balance plutonium, and having the structural composition of a plutonium are described. Zirconium is a satisfactory diluent because it alloys readily with plutonium and has desirable nuclear properties. Additional advantages are corrosion resistance, excellent fabrication propenties, an isotropie structure, and initial softness.

  3. Study of the effect of (U{sub 0.8}Pu{sub 0.2})O{sub 2} Uranium-Plutonium mixed fuel fission products on a living organism

    Energy Technology Data Exchange (ETDEWEB)

    Baimukhanova, Ayagoz; Kim, Dmitriy [Dept. of Radiation Protection, Institute of Nuclear Physics of the Ministry of Energy of the Republic of Kazakhstan, Almaty (Kazakhstan); Zhumagulova, Roza; Tazhigulova, Bibnur; Zharaspayeva, Gulzhanar; Azhiyeva, Galiya [Faculty of Engineering Technologies, Infrastructure and Management, International Educational Corporation, Almaty (Kazakhstan)

    2016-08-15

    The article describes the results of experiments conducted on pigs to determine the effect of plutonium, which is the most radiotoxic and highly active element in the range of mixed fuel (U{sub 0.8}Pu{sub 0.2})O{sub 2} fission products, on living organisms. The results will allow empirical prediction of the emergency plutonium radiation dose for various organs and tissues of humans in case of an accident in a reactor running on mixed fuel (U{sub 0.8}Pu{sub 0.2})O{sub 2}.

  4. Technical progress report on the metabolic studies of plutonium for month of August 1945

    Energy Technology Data Exchange (ETDEWEB)

    Hamilton, J.G.

    1945-12-31

    This monthly report briefly describes ongoing studies including urinary and fecal excretion of Plutonium 238 by human subjects and by rats, exploring way to facilitate the removal of Plutonium 238 from rat bone, the absorption of Plutonium 238 by barley plants, and use of inert iodine to block absorption of Iodine-131 in the rat.

  5. Industrial wastewater treatment plant of sugar production

    OpenAIRE

    Čad, Luka

    2016-01-01

    Sugar as product in our every day’s life’s been consumed in enormous quantities as one of main resources in food and drink industry. Production processes of sugar from sugar beet bring significant environmental impacts with it’s waste waters as the biggest pollutant. The thesis deals with sugar production waste water’s treatment process by presenting an example of waste water treatment plant of sugar factory, therefor presenting the production processes in sugar factories and their environmen...

  6. Plant biotechnology for lignocellulosic biofuel production.

    Science.gov (United States)

    Li, Quanzi; Song, Jian; Peng, Shaobing; Wang, Jack P; Qu, Guan-Zheng; Sederoff, Ronald R; Chiang, Vincent L

    2014-12-01

    Lignocelluloses from plant cell walls are attractive resources for sustainable biofuel production. However, conversion of lignocellulose to biofuel is more expensive than other current technologies, due to the costs of chemical pretreatment and enzyme hydrolysis for cell wall deconstruction. Recalcitrance of cell walls to deconstruction has been reduced in many plant species by modifying plant cell walls through biotechnology. These results have been achieved by reducing lignin content and altering its composition and structure. Reduction of recalcitrance has also been achieved by manipulating hemicellulose biosynthesis and by overexpression of bacterial enzymes in plants to disrupt linkages in the lignin-carbohydrate complexes. These modified plants often have improved saccharification yield and higher ethanol production. Cell wall-degrading (CWD) enzymes from bacteria and fungi have been expressed at high levels in plants to increase the efficiency of saccharification compared with exogenous addition of cellulolytic enzymes. In planta expression of heat-stable CWD enzymes from bacterial thermophiles has made autohydrolysis possible. Transgenic plants can be engineered to reduce recalcitrance without any yield penalty, indicating that successful cell wall modification can be achieved without impacting cell wall integrity or plant development. A more complete understanding of cell wall formation and structure should greatly improve lignocellulosic feedstocks and reduce the cost of biofuel production.

  7. APPLICATION OF COLUMN EXTRACTION METHOD FOR IMPURITIES ANALYSIS ON HB-LINE PLUTONIUM OXIDE IN SUPPORT OF MOX FEED PRODUCT SPECIFICATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Jones, M.; Diprete, D.; Wiedenman, B.

    2012-03-20

    The current mission at H-Canyon involves the dissolution of an Alternate Feedstocks 2 (AFS-2) inventory that contains plutonium metal. Once dissolved, HB-Line is tasked with purifying the plutonium solution via anion exchange, precipitating the Pu as oxalate, and calcining to form plutonium oxide (PuO{sub 2}). The PuO{sub 2} will provide feed product for the Mixed Oxide (MOX) Fuel Fabrication Facility, and the anion exchange raffinate will be transferred to H-Canyon. The results presented in this report document the potential success of the RE resin column extraction application on highly concentrated Pu samples to meet MOX feed product specifications. The original 'Hearts Cut' sample required a 10000x dilution to limit instrument drift on the ICP-MS method. The instrument dilution factors improved to 125x and 250x for the sample raffinate and sample eluent, respectively. As noted in the introduction, the significantly lower dilutions help to drop the total MRL for the analyte. Although the spike recoveries were half of expected in the eluent for several key elements, they were between 94-98% after Nd tracer correction. It is seen that the lower ICD limit requirements for the rare earths are attainable because of less dilution. Especially important is the extremely low Ga limit at 0.12 {mu}g/g Pu; an ICP-MS method is now available to accomplish this task on the sample raffinate. While B and V meet the column A limits, further development is needed to meet the column B limits. Even though V remained on the RE resin column, an analysis method is ready for investigation on the ICP-MS, but it does not mean that V cannot be measured on the ICP-ES at a low dilution to meet the column B limits. Furthermore, this column method can be applicable for ICP-ES as shown in Table 3-2, in that it trims the sample of Pu, decreasing and sometimes eliminating Pu spectral interferences.

  8. Plant cell culture strategies for the production of natural products.

    Science.gov (United States)

    Ochoa-Villarreal, Marisol; Howat, Susan; Hong, SunMi; Jang, Mi Ok; Jin, Young-Woo; Lee, Eun-Kyong; Loake, Gary J

    2016-03-01

    Plants have evolved a vast chemical cornucopia to support their sessile lifestyles. Man has exploited this natural resource since Neolithic times and currently plant-derived chemicals are exploited for a myriad of applications. However, plant sources of most high-value natural products (NPs) are not domesticated and therefore their production cannot be undertaken on an agricultural scale. Further, these plant species are often slow growing, their populations limiting, the concentration of the target molecule highly variable and routinely present at extremely low concentrations. Plant cell and organ culture constitutes a sustainable, controllable and environmentally friendly tool for the industrial production of plant NPs. Further, advances in cell line selection, biotransformation, product secretion, cell permeabilisation, extraction and scale-up, among others, are driving increases in plant NP yields. However, there remain significant obstacles to the commercial synthesis of high-value chemicals from these sources. The relatively recent isolation, culturing and characterisation of cambial meristematic cells (CMCs), provides an emerging platform to circumvent many of these potential difficulties. [BMB Reports 2016; 49(3): 149-158].

  9. Radio-ecological researches in the Sea of Japan and northwestern part of the Pacific Ocean after accident on the Japanese nuclear power plant 'Fukushima-1': the content of plutonium isotopes and strontium-90 in sea water

    Energy Technology Data Exchange (ETDEWEB)

    Fedorova, A. [Research and Production Association - RPA Typhoon (Russian Federation)

    2014-07-01

    In April-May 2011 and in August-September 2012 'Roshydromet' has conducted radio ecological researches in the Sea of Japan and on the water area of northwestern part of the Pacific Ocean (Kuril-Kamchatka area and the area of the Kuroshio current), which had purpose to make assessment of contamination hazard that can be caused to the coast of Russian Far East because of emergency releases of radioactive materials on the nuclear power plant 'Fukushima-1'. During the research works was done the sampling and processing of sea water samples not only for detection of Cs{sup 134}, Cs{sup 137}, but also for such radio-ecological significant long-living radionuclides, as {sup 90}Sr, plutonium isotopes ({sup 239,240}Pu) and tritium. Information about radionuclides was required for correct assessment of nuclear power plant 'Fukushima-1' aftermath on the Far Eastern sea water areas, but was not available in the beginning of research. In the present report the radiochemical measuring results on content of plutonium isotopes and {sup 90}Sr in the sea water from researched areas are presented. Sampling was done from the various horizons. Surface and deep water samples were filtered via the compound filter which made it possible to filter particles bigger than 1 micron. Radiochemical testing of the {sup 90}Sr and plutonium isotopes content was done separately on a suspension and in a filtrate of sea water samples. The content of {sup 90}Sr in the filtrate of the sea water that had been selected in 2011, ranges 0,7-2,4 Bq/m{sup 3}, in suspensions the interval makes 0,0013-0,021 Bq/m3. The results received in researches in 2012 are in range of 0,5-2,6 Bq/m{sup 3} of the sea water filtrate. According to results of IAEA in 2000, the average content of {sup 90}Sr in surface water of the Sea of Japan made 1,6 Bq/m{sup 3}. Hereby, the data obtained in researches in 2011-2012 agrees with results which had been presented by IAEA before the accident. The

  10. Plant protection products in organic grapevine growing

    Directory of Open Access Journals (Sweden)

    Sivčev Branislava V.

    2010-01-01

    Full Text Available Pests and grapevine diseases in organic production are suppressed by preventive measures with a view to reducing the impact of the attack. Allowed substances acting on patogenous fungi, insects, mites and other harmful organisms are used, if appropriate. Insecticides of plant origin are used in the organic production of grapevine, as well as vegetable oils, powders and insecticidal soaps that are selective, with a narrow range of effects and of lower toxicity, as well as biological products. As a rule, such plant protection products require a more frequent application. Copper-based and sulphur-based fungicides are still leading products in suppressing grapevine diseases. Researches are directed to decrease the quantity of application and to find their replacement by also efficient fungicides. A special emphasis is put on researching the efficient fungicides for suppressing Botrytis bunch rot and factors causing grapevine wood diseases (Esca and Eutypa in organic production. Along with copper and sulphur, different substances such as bicarbonates, plant extracts and oils, biological products being parasites, patogenous or diseases agent antagonists, and natural products such as milk and whey are applied in the organic production of grapevine.

  11. Plutonium storage criteria

    Energy Technology Data Exchange (ETDEWEB)

    Chung, D. [Scientech, Inc., Germantown, MD (United States); Ascanio, X. [Dept. of Energy, Germantown, MD (United States)

    1996-05-01

    The Department of Energy has issued a technical standard for long-term (>50 years) storage and will soon issue a criteria document for interim (<20 years) storage of plutonium materials. The long-term technical standard, {open_quotes}Criteria for Safe Storage of Plutonium Metals and Oxides,{close_quotes} addresses the requirements for storing metals and oxides with greater than 50 wt % plutonium. It calls for a standardized package that meets both off-site transportation requirements, as well as remote handling requirements from future storage facilities. The interim criteria document, {open_quotes}Criteria for Interim Safe Storage of Plutonium-Bearing Solid Materials{close_quotes}, addresses requirements for storing materials with less than 50 wt% plutonium. The interim criteria document assumes the materials will be stored on existing sites, and existing facilities and equipment will be used for repackaging to improve the margin of safety.

  12. Plutonium bioaccumulation in seabirds.

    Science.gov (United States)

    Strumińska-Parulska, Dagmara I; Skwarzec, Bogdan; Fabisiak, Jacek

    2011-12-01

    The aim of the paper was plutonium (²³⁸Pu and ²³⁹⁺²⁴⁰Pu) determination in seabirds, permanently or temporarily living in northern Poland at the Baltic Sea coast. Together 11 marine birds species were examined: 3 species permanently residing in the southern Baltic, 4 species of wintering birds and 3 species of migrating birds. The obtained results indicated plutonium is non-uniformly distributed in organs and tissues of analyzed seabirds. The highest plutonium content was found in the digestion organs and feathers, the smallest in skin and muscles. The plutonium concentration was lower in analyzed species which feed on fish and much higher in herbivorous species. The main source of plutonium in analyzed marine birds was global atmospheric fallout.

  13. PLUTONIUM-CERIUM-COBALT AND PLUTONIUM-CERIUM-NICKEL ALLOYS

    Science.gov (United States)

    Coffinberry, A.S.

    1959-08-25

    >New plutonium-base teroary alloys useful as liquid reactor fuels are described. The alloys consist of 10 to 20 atomic percent cobalt with the remainder plutonium and cerium in any desired proportion, with the plutonium not in excess of 88 atomic percent; or, of from 10 to 25 atomic percent nickel (or mixture of nickel and cobalt) with the remainder plutonium and cerium in any desired proportion, with the plutonium not in excess of 86 atomic percent. The stated advantages of these alloys over unalloyed plutonium for reactor fuel use are a lower melting point and a wide range of permissible plutonium dilution.

  14. Mo99 Production Plant Layout

    Energy Technology Data Exchange (ETDEWEB)

    Woloshun, Keith Albert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dale, Gregory E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Naranjo, Angela Carol [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-06-25

    The NorthStar Medical Technologies 99Mo production facility configuration is envisioned to be 8 accelerator pairs irradiating 7 100Mo targets (one spare accelerator pair undergoing maintenance while the other 7 pairs are irradiating targets). The required shielding in every direction for the accelerators is initially estimated to be 10 feet of concrete. With the accelerator pairs on one (ground) level and spaced with the required shielding between adjacent pairs, the only practical path for target insertion and removal while minimizing floor space is vertical. The current scheme then requires a target vertical lift of nominally 10 feet through a shield stack. It is envisioned that the lift will be directly into a hot cell where an activated target can be removed from its holder and a new target attached and lowered. The hot cell is on a rail system so that a single hot cell can service all active target locations, as well as deliver the ready targets to the separations lab. On this rail system, coupled to the hot cell, will be a helium recovery and clean-up system. All helium coolant equipment is located on the upper level near to the target removal point.

  15. Pesticide productivity, host-plant resistance and productivity in China

    OpenAIRE

    Widawsky, David; Rozelle, Scott; Jin, Songqing; Huang, Jikun

    1998-01-01

    Pesticides are used as the primary method of pest control in Asian rice production. Conditions in China have led to demand for high and increasing rice yields, resulting in intensive cultivation and adoption of fertilizer responsive varieties. The consequence has been widespread pest infestations. Many studies have estimated pesticide productivity, but few have estimated the productivity of alternative methods of pest control, namely host-plant resistance. None have estimated the substitutabi...

  16. Recommended plutonium release fractions from postulated fires. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Kogan, V.; Schumacher, P.M.

    1993-12-01

    This report was written at the request of EG&G Rocky Flats, Inc. in support of joint emergency planning for the Rocky Flats Plant (RFP) by EG&G and the State of Colorado. The intent of the report is to provide the State of Colorado with an independent assessment of any respirable plutonium releases that might occur in the event of a severe fire at the plant. Fire releases of plutonium are of interest because they have been used by EG&G to determine the RFP emergency planning zones. These zones are based on the maximum credible accident (MCA) described in the RFP Final Environmental Impact Statement (FEIS) of 1980, that MCA is assumed to be a large airplane crashing into a RFP plutonium building.The objective of this report was first, to perform a worldwide literature review of relevant release experiments from 1960 to the present and to summarize those findings, and second, to provide recommendations for application of the experimental data to fire release analyses at Rocky Flats. The latter step requires translation between experimental and expected RFP accident parameters, or ``scaling.`` The parameters of particular concern are: quantities of material, environmental parameters such as the intensity of a fire, and the physico-chemical forms of the plutonium. The latter include plutonium metal, bulk plutonium oxide powder, combustible and noncombustible wastes contaminated with plutonium oxide powder, and residues from plutonium extraction processes.

  17. Maximum entropy production and plant optimization theories.

    Science.gov (United States)

    Dewar, Roderick C

    2010-05-12

    Plant ecologists have proposed a variety of optimization theories to explain the adaptive behaviour and evolution of plants from the perspective of natural selection ('survival of the fittest'). Optimization theories identify some objective function--such as shoot or canopy photosynthesis, or growth rate--which is maximized with respect to one or more plant functional traits. However, the link between these objective functions and individual plant fitness is seldom quantified and there remains some uncertainty about the most appropriate choice of objective function to use. Here, plants are viewed from an alternative thermodynamic perspective, as members of a wider class of non-equilibrium systems for which maximum entropy production (MEP) has been proposed as a common theoretical principle. I show how MEP unifies different plant optimization theories that have been proposed previously on the basis of ad hoc measures of individual fitness--the different objective functions of these theories emerge as examples of entropy production on different spatio-temporal scales. The proposed statistical explanation of MEP, that states of MEP are by far the most probable ones, suggests a new and extended paradigm for biological evolution--'survival of the likeliest'--which applies from biomacromolecules to ecosystems, not just to individuals.

  18. Plant-Based Vaccines: Production and Challenges

    Directory of Open Access Journals (Sweden)

    Erna Laere

    2016-01-01

    Full Text Available Plant-based vaccine technologies involve the integration of the desired genes encoding the antigen protein for specific disease into the genome of plant tissues by various methods. Agrobacterium-mediated gene transfer and transformation via genetically modified plant virus are the common methods that have been used to produce effective vaccines. Nevertheless, with the advancement of science and technology, new approaches have been developed to increase the efficiency of former methods such as biolistic, electroporation, agroinfiltration, sonication, and polyethylene glycol treatment. Even though plant-based vaccines provide many benefits to the vaccine industry, there are still challenges that limit the rate of successful production of these third-generation vaccines. Even with all the limitations, continuous efforts are still ongoing in order to produce efficient vaccine for many human and animals related diseases owing to its great potentials. This paper reviews the existing conventional methods as well as the development efforts by researchers in order to improve the production of plant-based vaccines. Several challenges encountered during and after the production process were also discussed.

  19. Pinellas Plant facts. [Products, processes, laboratory facilities

    Energy Technology Data Exchange (ETDEWEB)

    1986-09-01

    This plant was built in 1956 in response to a need for the manufacture of neutron generators, a principal component in nuclear weapons. The neutron generators consist of a miniaturized linear ion accelerator assembled with the pulsed electrical power supplies required for its operation. The ion accelerator, or neutron tube, requires ultra clean, high vacuum technology: hermetic seals between glass, ceramic, glass-ceramic, and metal materials: plus high voltage generation and measurement technology. The existence of these capabilities at the Pinellas Plant has led directly to the assignment of the lightning arrester connector, specialty capacitor, vacuum switch, and crystal resonator. Active and reserve batteries and the radioisotopically-powered thermoelectric generator draw on the materials measurement and controls technologies which are required to ensure neutron generator life. A product development and production capability in alumina ceramics, cermet (electrical) feedthroughs, and glass ceramics has become a specialty of the plant; the laboratories monitor the materials and processes used by the plant's commercial suppliers of ferroelectric ceramics. In addition to the manufacturing facility, a production development capability is maintained at the Pinellas Plant.

  20. Production of renewable polymers from crop plants.

    Science.gov (United States)

    van Beilen, Jan B; Poirier, Yves

    2008-05-01

    Plants produce a range of biopolymers for purposes such as maintenance of structural integrity, carbon storage, and defense against pathogens and desiccation. Several of these natural polymers are used by humans as food and materials, and increasingly as an energy carrier. In this review, we focus on plant biopolymers that are used as materials in bulk applications, such as plastics and elastomers, in the context of depleting resources and climate change, and consider technical and scientific bottlenecks in the production of novel or improved materials in transgenic or alternative crop plants. The biopolymers discussed are natural rubber and several polymers that are not naturally produced in plants, such as polyhydroxyalkanoates, fibrous proteins and poly-amino acids. In addition, monomers or precursors for the chemical synthesis of biopolymers, such as 4-hydroxybenzoate, itaconic acid, fructose and sorbitol, are discussed briefly.

  1. Plutonium radiation surrogate

    Science.gov (United States)

    Frank, Michael I.

    2010-02-02

    A self-contained source of gamma-ray and neutron radiation suitable for use as a radiation surrogate for weapons-grade plutonium is described. The source generates a radiation spectrum similar to that of weapons-grade plutonium at 5% energy resolution between 59 and 2614 keV, but contains no special nuclear material and emits little .alpha.-particle radiation. The weapons-grade plutonium radiation surrogate also emits neutrons having fluxes commensurate with the gamma-radiation intensities employed.

  2. Progress on plutonium stabilization

    Energy Technology Data Exchange (ETDEWEB)

    Hurt, D. [Defense Nuclear Facilities Safety Board, Washington, DC (United States)

    1996-05-01

    The Defense Nuclear Facilities Safety Board has safety oversight responsibility for most of the facilities where unstable forms of plutonium are being processed and packaged for interim storage. The Board has issued recommendations on plutonium stabilization and has has a considerable influence on DOE`s stabilization schedules and priorities. The Board has not made any recommendations on long-term plutonium disposition, although it may get more involved in the future if DOE develops plans to use defense nuclear facilities for disposition activities.

  3. PLUTONIUM ELECTROREFINING CELLS

    Science.gov (United States)

    Mullins, L.J. Jr.; Leary, J.A.; Bjorklund, C.W.; Maraman, W.J.

    1963-07-16

    Electrorefining cells for obtaining 99.98% plutonium are described. The cells consist of an impure liquid plutonium anode, a molten PuCl/sub 3/-- alkali or alkaline earth metal chloanode, a molten PuCl/sub 3/-alkali or alkaline earth metal chloride electrolyte, and a nonreactive cathode, all being contained in nonreactive ceramic containers which separate anode from cathode by a short distance and define a gap for the collection of the purified liquid plutonium deposited on the cathode. Important features of these cells are the addition of stirrer blades on the anode lead and a large cathode surface to insure a low current density. (AEC)

  4. Separation Method of Uranium and Plutonium From Large Amount of Neptunium

    Institute of Scientific and Technical Information of China (English)

    SU; Yu-lan; JIN; Hua; YING; Zhe-cong; ZHAO; Sheng-yang

    2013-01-01

    Uranium and plutonium are limited strictly in the neptunium product.To eliminate the influence of neptunium matrix on determination of uranium and plutonium,a new separation method of uranium and plutonium from large amount of neptunium by TEVA column has been developed,which is illustrated in Fig.1.

  5. CSER 97-004: PFP production denitration calciner system

    Energy Technology Data Exchange (ETDEWEB)

    Hillesland, K.E.

    1997-09-11

    The plutonium stabilization program at the Plutonium Finishing Plant (PFP) includes conversion of acidic plutonium nitrate solution into plutonium oxide. Conversion is facilitated through use of a vertical calciner installed in Glovebox HC-23OC-2, which is located in RM 230C of this facility. This evaluation supports the Criticality Prevention Specification for the calcining process inside this glovebox. As the product of the calciner is a high density plutonium oxide, a number of limits are required to insure criticality safety. The containers allowed are product receiver vessels and 0.5 C slip lid cans and polyjars. The limits allow for two ``unit masses`` of 2 V total volume each, separated by a distance of at least 25.4 cm (10 in.). This evaluation allows for operation of the calciner for product densities not in excess of 5.5 g Pu/cm{sup 3}.

  6. 9 CFR 355.21 - Products entering inspected plants.

    Science.gov (United States)

    2010-01-01

    ... 9 Animals and Animal Products 2 2010-01-01 2010-01-01 false Products entering inspected plants... Products entering inspected plants. All products of a kind certified under this part or materials to be used in the preparation of such products when brought into an inspected plant shall be identified...

  7. Plutonium dissolution process

    Science.gov (United States)

    Vest, Michael A.; Fink, Samuel D.; Karraker, David G.; Moore, Edwin N.; Holcomb, H. Perry

    1996-01-01

    A two-step process for dissolving plutonium metal, which two steps can be carried out sequentially or simultaneously. Plutonium metal is exposed to a first mixture containing approximately 1.0M-1.67M sulfamic acid and 0.0025M-0.1M fluoride, the mixture having been heated to a temperature between 45.degree. C. and 70.degree. C. The mixture will dissolve a first portion of the plutonium metal but leave a portion of the plutonium in an oxide residue. Then, a mineral acid and additional fluoride are added to dissolve the residue. Alteratively, nitric acid in a concentration between approximately 0.05M and 0.067M is added to the first mixture to dissolve the residue as it is produced. Hydrogen released during the dissolution process is diluted with nitrogen.

  8. Terrestrial plant methane production and emission.

    Science.gov (United States)

    Bruhn, Dan; Møller, Ian M; Mikkelsen, Teis N; Ambus, Per

    2012-03-01

    In this minireview, we evaluate all experimental work published on the phenomenon of aerobic methane (CH(4) ) generation in terrestrial plants and plant. Clearly, despite much uncertainty and skepticism, we conclude that the phenomenon is true. Four stimulating factors have been observed to induce aerobic plant CH(4) production, i.e. cutting injuries, increasing temperature, ultraviolet radiation and reactive oxygen species. Further, we analyze rates of measured emission of aerobically produced CH(4) in pectin and in plant tissues from different studies and argue that pectin is very far from the sole contributing precursor. In consequence, scaling up of aerobic CH(4) emission needs to take into consideration other potential sources than pectin. Due to the large uncertainties related to effects of stimulating factors, genotypic responses and type of precursors, we conclude that current attempts for upscaling aerobic CH(4) into a global budget is inadequate. Thus it is too early to draw the line under the aerobic methane emission in plants. Future work is needed for establishing the relative contribution of several proven potential CH(4) precursors in plant material.

  9. COLLABORATIVE NEGOTIATIONS A SUCCESSFUL APPROACH FOR NEGOTIATING COMPLIANCE MILESTONES FOR THE TRANSITION OF THE PLUTONIUM FINISHING PLANT (PFP), HANFORD NUCLEAR RESERVATION, AND HANFORD, WASHINGTON

    Energy Technology Data Exchange (ETDEWEB)

    Hebdon, J.; Yerxa, J.; Romine, L.; Hopkins, AM; Piippo, R.; Cusack, L.; Bond, R.; Wang, Oliver; Willis, D.

    2003-02-27

    The Hanford Nuclear Reservation is a former U. S. Department of Energy Defense Production Site. The site is currently listed on the National Priorities List of the Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA) and is undergoing cleanup and environmental restoration. The PFP is a former Plutonium metal production facility. The operating mission of the PFP ended with a DOE Headquarters shutdown letter in October of 1996. Generally, the receipt of a shutdown letter initiates the start of Transition (as the first step of Decommissioning) of a facility. The Hanford site is subject to the Hanford Federal Facilities Compliance Act and Consent Order (HFFCCO), an order on consent signed by the DOE, the U. S. Environmental Protection Agency, (EPA) and the Washington Department of Ecology (WDOE). Under the HFFCCO, negotiations for transition milestones begin within six months after the issuance of a shutdown order. In the case of the PFP, the Nuclear Materials disposition and stabilization activities, a DOE responsibility, were necessary as precursor activities to Transition. This situation precipitated a crisis in the negotiations between the agencies, and formal negotiations initiated in 1997 ended in failure. The negotiations reached impasse on several key regulatory and operational issues. The 1997 negotiation was characterized by a strongly positional style. DOE and the regulatory personnel took hard lines early in the negotiations and were unable to move to resolution of key issues after a year and a half. This resulted in unhappy stakeholders, poor publicity and work delays as well as wounded relationships between DOE and the regulatory community. In the 2000-2001 PFP negotiations, a completely different approach was suggested and eventually initiated: Collaborative Negotiations. The collaborative negotiation style resulted in agreement between the agencies on all key issues within 6 months of initiation. All parties were very

  10. Terrestrial plant production and climate change.

    Science.gov (United States)

    Friend, Andrew D

    2010-03-01

    The likely future increase in atmospheric CO(2) and associated changes in climate will affect global patterns of plant production. Models integrate understanding of the influence of the environment on plant physiological processes and so enable estimates of future changes to be made. Moreover, they allow us to assess the consequences of different assumptions for predictions and so stimulate further research. This paper is a review of the sensitivities of one such model, Hybrid6.5, a detailed mechanistic model of terrestrial primary production. This model is typical of its type, and the sensitivities of the global distribution of predicted production to model assumptions and possible future CO(2) levels and climate are assessed. Sensitivity tests show that leaf phenology has large effects on mean C(3) crop and needleleaved cold deciduous tree production, reducing potential net primary production (NPP) from that obtained using constant maximum annual leaf area index by 32.9% and 41.6%, respectively. Generalized Plant Type (GPT) specific parameterizations, particularly photosynthetic capacity per unit leaf N, affect mean predicted NPP of higher C(3) plants by -22.3% to 27.9%, depending on the GPT, compared to NPP predictions obtained using mean parameter values. An increase in atmospheric CO(2) concentrations from current values to 720 ppm by the end of this century, with associated effects on climate from a typical climate model, is predicted to increase global NPP by 37.3%. Mean increases range from 43.9-52.9% across different C(3) GPTs, whereas the mean NPP of C(4) grass and crop increases by 5.9%. Significant uncertainties concern the extent to which acclimative processes may reduce any potential future increase in primary production and the degree to which any gains are transferred to durable, and especially edible, biomass. Experimentalists and modellers need to work closely together to reduce these uncertainties. A number of research priorities are suggested

  11. Pilot plant study for ethanol production

    Energy Technology Data Exchange (ETDEWEB)

    Kim, J.S. [Korea Inst. of Science and Technology, Seoul (Korea, Republic of)

    1996-02-01

    Most of domestic alcohol fermentation factory adopt batch process of which productivity is lower than continuous fermentation process. They have made great effort to increase productivity by means of partial unit process automatization and process improvement with their accumulated experience but there is technical limitation in productivity of batch fermentation process. To produce and supply fuel alcohol, economic aspects must be considered first of all. Therefore, development of continuous fermentation process, of which productivity is high, is prerequisite to produce and use fuel alcohol but only a few foreign company possess continuous fermentation technic and use it in practical industrial scale fermentation. We constructed pilot plant (5 Stage CSTR 1 kl 99.5 v/v% ethanol/Day scale) to study some aspects stated below and our ultimate aims are production of industrial scale fuel alcohol and construction of the plant by ourselves. Some study concerned with energy saving separation and contamination control technic were entrusted to KAIST, A-ju university and KIST respectively. (author) 67 refs., 100 figs., 58 tabs.

  12. Ceramification: A plutonium immobilization process

    Energy Technology Data Exchange (ETDEWEB)

    Rask, W.C. [Dept. of Energy, Golden, CO (United States); Phillips, A.G. [Rocky Flats Environmental Technology Site, Golden, CO (United States)

    1996-05-01

    This paper describes a low temperature technique for stabilizing and immobilizing actinide compounds using a combination process/storage vessel of stainless steel, in which measured amounts of actinide nitrate solutions and actinide oxides (and/or residues) are systematically treated to yield a solid article. The chemical ceramic process is based on a coating technology that produces rare earth oxide coatings for defense applications involving plutonium. The final product of this application is a solid, coherent actinide oxide with process-generated encapsulation that has long-term environmental stability. Actinide compounds can be stabilized as pure materials for ease of re-use or as intimate mixtures with additives such as rare earth oxides to increase their degree of proliferation resistance. Starting materials for the process can include nitrate solutions, powders, aggregates, sludges, incinerator ashes, and others. Agents such as cerium oxide or zirconium oxide may be added as powders or precursors to enhance the properties of the resulting solid product. Additives may be included to produce a final product suitable for use in nuclear fuel pellet production. The process is simple and reduces the time and expense for stabilizing plutonium compounds. It requires a very low equipment expenditure and can be readily implemented into existing gloveboxes. The process is easily conducted with less associated risk than proposed alternative technologies.

  13. Chemical species of plutonium in Hanford radioactive tank waste

    Energy Technology Data Exchange (ETDEWEB)

    Barney, G.S.

    1997-10-22

    Large quantities of radioactive wastes have been generated at the Hanford Site over its operating life. The wastes with the highest activities are stored underground in 177 large (mostly one million gallon volume) concrete tanks with steel liners. The wastes contain processing chemicals, cladding chemicals, fission products, and actinides that were neutralized to a basic pH before addition to the tanks to prevent corrosion of the steel liners. Because the mission of the Hanford Site was to provide plutonium for defense purposes, the amount of plutonium lost to the wastes was relatively small. The best estimate of the amount of plutonium lost to all the waste tanks is about 500 kg. Given uncertainties in the measurements, some estimates are as high as 1,000 kg (Roetman et al. 1994). The wastes generally consist of (1) a sludge layer generated by precipitation of dissolved metals from aqueous wastes solutions during neutralization with sodium hydroxide, (2) a salt cake layer formed by crystallization of salts after evaporation of the supernate solution, and (3) an aqueous supernate solution that exists as a separate layer or as liquid contained in cavities between sludge or salt cake particles. The identity of chemical species of plutonium in these wastes will allow a better understanding of the behavior of the plutonium during storage in tanks, retrieval of the wastes, and processing of the wastes. Plutonium chemistry in the wastes is important to criticality and environmental concerns, and in processing the wastes for final disposal. Plutonium has been found to exist mainly in the sludge layers of the tanks along with other precipitated metal hydrous oxides. This is expected due to its low solubility in basic aqueous solutions. Tank supernate solutions do not contain high concentrations of plutonium even though some tanks contain high concentrations of complexing agents. The solutions also contain significant concentrations of hydroxide which competes with other

  14. METHOD OF PRODUCING PLUTONIUM TETRAFLUORIDE

    Science.gov (United States)

    Tolley, W.B.; Smith, R.C.

    1959-12-15

    A process is presented for preparing plutonium tetrafluoride from plutonium(IV) oxalate. The oxalate is dried and decomposed at about 300 deg C to the dioxide, mixed with ammonium bifluoride, and the mixture is heated to between 50 and 150 deg C whereby ammonium plutonium fluoride is formed. The ammonium plutonium fluoride is then heated to about 300 deg C for volatilization of ammonium fluoride. Both heating steps are preferably carried out in an inert atmosphere.

  15. [Efficacy of plant products against herpetic infections].

    Science.gov (United States)

    Schnitzler, P; Reichling, J

    2011-12-01

    Essential oils from various aromatic medicinal plants are highly active against some viral infections, e.g. labial herpes caused by herpes simplex virus type 1. Balm oil, tea tree oil and peppermint oil demonstrate in vitro a significant antiherpetic activity, mainly related to a direct drug-virus particle interaction, some essential oils also act directly virucidal. Interestingly, these essential oils are also highly active against acyclovir-resistant herpes simplex virus strains. In clinical studies, tea tree oil has been shown to possess antiherpetic, anti-inflammatory and pain-relieving properties, as well as to accelerate the healing process of herpes labialis. Applying diluted essential oils three to four times daily for the antiherpetic treatment of affected areas is recommended. Some companies have marketed plant products, e.g. from Melissa, for the treatment of recurrent herpetic infections.

  16. Biofuel production from plant biomass derived sugars

    Energy Technology Data Exchange (ETDEWEB)

    Cripps, R.

    2007-03-15

    This report details the results of a project that aimed to develop a recombinant thermophilic microorganism able to produce ethanol in a commercial yield from mixed C5 (xylose and arabinose) and C6 (mainly glucose) sugar substrates typically found in biomass hydrolysates. The main focus of the project was on producing a stable recombinant which formed ethanol as its major product and did not produce significant quantities of by-products. The costs of bioethanol could be substantially reduced if cheap plant-based feedstocks could be utilised. This study focussed on a strain of Geobacillus thermoglucosidasius known to be a thermophilic ethanol producer and developed the genetic manipulation techniques necessary to engineer its metabolism such that unwanted products (mainly organic acids) were no longer formed and ethanol became the overwhelming product. An appropriate genetic took kit to allow the required metabolic engineering was acquired and used to inactivate the genes of the metabolic pathways involved in the formation of the organic acids (e.g. lactic acid) and to up-regulate genes concerned with the formation of ethanol. This allowed the flow of metabolites derived from the sugar substrates to be redirected to the desired product. Stable mutants lacking the ability to form lactic acid were created and shown to give enhanced levels of ethanol, with yields from glucose approaching those achieved in yeast fermentations and low by-product formation.

  17. Role of Osmotic Adjustment in Plant Productivity

    Energy Technology Data Exchange (ETDEWEB)

    Gebre, G.M.

    2001-01-11

    Successful implementation of short rotation woody crops requires that the selected species and clones be productive, drought tolerant, and pest resistant. Since water is one of the major limiting factors in poplar (Populus sp.) growth, there is little debate for the need of drought tolerant clones, except on the wettest of sites (e.g., lower Columbia River delta). Whether drought tolerance is compatible with productivity remains a debatable issue. Among the many mechanisms of drought tolerance, dehydration postponement involves the maintenance of high leaf water potential due to, for example, an adequate root system. This trait is compatible with productivity, but requires available soil moisture. When the plant leaf water potential and soil water content decline, the plant must be able to survive drought through dehydration tolerance mechanisms, such as low osmotic potential or osmotic adjustment. Osmotic adjustment and low osmotic potential are considered compatible with growth and yield because they aid in the maintenance of leaf turgor. However, it has been shown that turgor alone does not regulate cell expansion or stomatal conductance and, therefore, the role of osmotic adjustment is debated. Despite this finding, osmotic adjustment has been correlated with grain yield in agronomic crop species, and gene markers responsible for osmotic adjustment are being investigated to improve drought tolerance in productive progenies. Although osmotic adjustment and low osmotic potentials have been investigated in several forest tree species, few studies have investigated the relationship between osmotic adjustment and growth. Most of these studies have been limited to greenhouse or container-grown plants. Osmotic adjustment and rapid growth have been specifically associated in Populus and black spruce (Picea mariuna (Mill.) B.S.P.) progenies. We tested whether these relationships held under field conditions using several poplar clones. In a study of two hybrid poplar

  18. Interannual variability of plant phenology in tussock tundra: modelling interactions of plant productivity, plant phenology, snowmelt and soil thaw

    NARCIS (Netherlands)

    Wijk, van M.T.; Williams, M.; Laundre, J.A.; Shaver, G.R.

    2003-01-01

    We present a linked model of plant productivity, plant phenology, snowmelt and soil thaw in order to estimate interannual variability of arctic plant phenology and its effects on plant productivity. The model is tested using 8 years of soil temperature data, and three years of bud break data of Betu

  19. A PILOT PLANT FOR THE BIOGAS PRODUCTION

    Directory of Open Access Journals (Sweden)

    A. Omrani

    1988-08-01

    Full Text Available Manure and Putreseible garbage are some of the main sources of pathogenic germs in countryside’s. On the other hand, demand for fertilizer and energy increases in rural areas every day. To study Potential of cow manure for these requirements a 16,5m3 pilot plant was designed and constructed as fermentation tank near animal husbandry of karaj Agriculture Faculty. Some 260kg cow manure and water with the ratio of 4 and 7 was fed to fermentation tank every day. Average daily biogas production was 3.4m3, which was burned successfully in a gas range. Gas production was reduced by 86% during coldest winter days. Design for control of gas pressure and reservation of excessive gas was successful. Concentration of nitrate in sludge increased by 1.6 folds compared to row material. Some bacteria and Parasites were reduced drastically.

  20. Anticipated Radiological Dose to Worker for Plutonium Stabilization and Handling at PFP - Project W-460

    CERN Document Server

    Weiss, E V

    2000-01-01

    This report provides estimates of the expected whole body and extremity radiological dose, expressed as dose equivalent (DE), to workers conducting planned plutonium (Pu) stabilization processes at the Hanford Site Plutonium Finishing Plant (PFP). The report is based on a time and motion dose study commissioned for Project W-460, Plutonium Stabilization and Handling, to provide personnel exposure estimates for construction work in the PFP storage vault area plus operation of stabilization and packaging equipment at PFP.

  1. Electrochemically Modulated Separation for Plutonium Safeguards

    Energy Technology Data Exchange (ETDEWEB)

    Pratt, Sandra H.; Breshears, Andrew T.; Arrigo, Leah M.; Schwantes, Jon M.; Duckworth, Douglas C.

    2013-12-31

    Accurate and timely analysis of plutonium in spent nuclear fuel is critical in nuclear safeguards for detection of both protracted and rapid plutonium diversions. Gamma spectroscopy is a viable method for accurate and timely measurements of plutonium provided that the plutonium is well separated from the interfering fission and activation products present in spent nuclear fuel. Electrochemically modulated separation (EMS) is a method that has been used successfully to isolate picogram amounts of Pu from nitric acid matrices. With EMS, Pu adsorption may be turned "on" and "off" depending on the applied voltage, allowing for collection and stripping of Pu without the addition of chemical reagents. In this work, we have scaled up the EMS process to isolate microgram quantities of Pu from matrices encountered in spent nuclear fuel during reprocessing. Several challenges have been addressed including surface area limitations, radiolysis effects, electrochemical cell performance stability, and chemical interferences. After these challenges were resolved, 6 µg Pu was deposited in the electrochemical cell with approximately an 800-fold reduction of fission and activation product levels from a spent nuclear fuel sample. Modeling showed that these levels of Pu collection and interference reduction may not be sufficient for Pu detection by gamma spectroscopy. The main remaining challenges are to achieve a more complete Pu isolation and to deposit larger quantities of Pu for successful gamma analysis of Pu. If gamma analyses of Pu are successful, EMS will allow for accurate and timely on-site analysis for enhanced Pu safeguards.

  2. Estimated discard limits for plutonium-238 recovery processing in the plutonium processing building

    Energy Technology Data Exchange (ETDEWEB)

    Luthy, D.F.; Bond, W.H.

    1975-03-26

    This manual is intended as a basis for plutonium-238 recovery costs and as a guide for removal of plutonium-bearing wastes from the gloveboxes to be safely and economically discarded. Waste materials contaminated with plutonium-238 are generated from in-house production, analytical, process development, recovery and receipts from off-site. The contaminated materials include paper, rags, alpha-box gloves, piping, valves, filters, etc. General categories for all types of plutonium waste have been established by the ERDA and are reflected in this manual. There are numerous processes used in plutonium recovery, such as dissolution, ultrasonic cleaning, ion exchange, etc. One or more of these processes are needed to extract the plutonium-238 from waste materials, purify it and convert it to an oxide acceptable for reuse. This manual is presented in two parts: Part I gives a breakdown and brief explanation of the direct costs for plutonium-238 I recovery, derived from budget data. Direct costs include direct labor (operating personnel), operational materials and supplies, health physics direct labor, calorimetry labor, analytical labor, and engineering direct labor (total costs for Method I). Budgeted costs for labor and material were used in the derivation of discard limits. The data presented is then used to calculate the cost per hour for recovery, as it applies to the three different methods of calculating discard limits referred to, in this manual, as Method I (calculation stated above), Method II and Method III. The cost for Method II is derived by adding to the cost of Method I, payroll related expenses. Method III is then calculated by adding over-head expenses to the total cost of Method II.

  3. Analytic determination of plutonium in the environment; Determination analytique du plutonium dans l'environnement

    Energy Technology Data Exchange (ETDEWEB)

    Ballada, J. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1967-07-01

    The work described in this report was undertaken with a view to determining the plutonium content in the fall-out from nuclear explosions. In the first part are described in turn the importance of the problems due to the plutonium, the physico-chemical properties of the radioelement and the biological dangers which it presents. A detailed and critical analysis is made of the radio-toxicological determination of the plutonium as reported in the literature prior to this report. The second part consists in the presentation of a judicious choice of techniques making it possible to determine plutonium in air, rain-water, soils and ash. After a detailed description of the measurement equipment and the operational techniques which have been developed, a justification of these techniques is given with particular reference to their sensitivity and specificity. After a brief conclusion concerning the preceding chapters, the results are presented. These are then discussed in the ease of each element in which the plutonium has been determined. This discussion is concluded by a consideration of the importance of the occurrence of fall-out plutonium on problems relating to public health. From a consideration of 200 analyses carried out, it is concluded that the contribution of plutonium to the exposure of populations is still very small compared to that of natural radiation and that due to such fission products as strontium 90. The report includes 63 literature references, 26 figures and 11 tables. (author) [French] Les travaux decrits dans ce memoire ont ete entrepris et eflectues dans le but de mettre en evidence le plutonium des retombees radioactives consecutives aux explosions nucleaires. Dans la premiere partie nous etudions successivement l'importance des problemes poses par le plutonium puis les proprietes physicochimiques du radioelement et les dangers qu'il presente du point de vue biologique. Nous effectuons une analyse detaillee et critique des techniques

  4. High-Temperature Oxidation of Plutonium Surrogate Metals and Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Sparks, Joshua C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Krantz, Kelsie E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Christian, Jonathan H. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Washington, II, Aaron L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-07-27

    The Plutonium Management and Disposition Agreement (PMDA) is a nuclear non-proliferation agreement designed to remove 34 tons of weapons-grade plutonium from Russia and the United States. While several removal options have been proposed since the agreement was first signed in 2000, processing the weapons-grade plutonium to mixed-oxide (MOX) fuel has remained the leading candidate for achieving the goals of the PMDA. However, the MOX program has received its share of criticisms, which causes its future to be uncertain. One alternative pathway for plutonium disposition would involve oxidizing the metal followed by impurity down blending and burial in the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico. This pathway was investigated by use of a hybrid microwave and a muffle furnace with Fe and Al as surrogate materials. Oxidation occurred similarly in the microwave and muffle furnace; however, the microwave process time was significantly faster.

  5. Preparation of fused chloride salts for use in pyrochemical plutonium recovery operations at Los Alamos

    Energy Technology Data Exchange (ETDEWEB)

    Fife, K.W.; Bowersox, D.F.; Christensen, D.C.; Williams, J.D.

    1986-07-01

    The Plutonium Metal Technology Group at Los Alamos routinely uses pyrochemical processes to produce and purify plutonium from impure sources. The basic processes (metal production, metal purification, and residue treatment) involve controlling oxidation and reduction reactions between plutonium and its compounds in molten salts. Current production methods are described, as well as traditional approaches and recent developments in the preparation of solvent salts for electrorefining, molten salt extraction, lean metal (pyroredox) purification, and direct oxide reduction.

  6. Preparation of plutonium hexafluoride. Recovery of plutonium from waste dross (1962); Preparation de l'hexafluorure de plutonium. Recuperation du plutonium des scories d'elaboration (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Gendre, R. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-07-01

    The object of this work is to study the influence of various physical factors on the rate of fluorination of solid plutonium tetrafluoride by fluorine. In a horizontal oven with a circulation for pure fluorine at atmospheric pressure and 520 deg. C, at a fluorine rate of 9 litres/hour, it is possible to transform 3 g of tetrafluoride to hexafluoride with about 100 per cent transformation and a recovery yield of over 90 per cent, in 4 to 5 hours. The fluorination rate is a function of the temperature, of the fluorine flow-rate, of the crucible surface, of the depth of the tetrafluoride layer and of the reaction time. It does not depend on the diffusion of the fluorine into the solid but is determined by the reaction at the gas-solid interface and obeys the kinetic law (1 - T{sub T}){sup 1/3} = kt + 1. The existence of intermediate fluorides, in particular Pu{sub 4} F{sub 17}, is confirmed by a break in the Arrhenius plot at about 370 deg. C, by differences in the fluorination rates inside the tetrafluoride layer, and by reversible colour changes. The transformation to hexafluoride occurs with a purification with respect of the foreign elements present in the initial plutonium. Recovery of plutonium from waste dross: The study is based on the transformation of occluded plutonium particles to gaseous hexafluoride which is then decomposed thermally to the tetrafluoride which can be reintroduced directly in the production circuit. Under the conditions considered this process is not applicable industrially. After milling, it is possible to separate the dross into enriched (75 per cent Pu in 2.6 per cent by weight of dross) and depleted portions. By prolonged fluorination (16 hours) of the various fractions it is possible to recover about 80 per cent of the plutonium. A treatment plant using fluidization, as described at the end of this study, should make it possible to substantially improve the yield. (author) [French] L'objet de l'etude est l

  7. Risk assessment of plant protection products

    Directory of Open Access Journals (Sweden)

    Hardy T

    2012-10-01

    Full Text Available

    EFSA’s Panel on Plant Protection Products and their Residues (PPR Panel provides independent scientific advice in the field of risk assessment of plant protection products (PPPs, pesticides. Since its establishment in 2003 under Regulation (EC No 178/2002, it has delivered a series of scientific outputs in support of evaluation of pesticide active substances, establishing scientific principles and guidance documents in the field of pesticide risk assessment and in support of decision making of European Union (EU law makers. Next to a series of scientific opinions evaluating specific adverse effects of PPPs for human health (like for instance carcinogenicity the Panel also delivered scientific opinions on general principles in the field of human health risk assessment (like reference value setting and is, in particular over the last years, very much engaged in development of methodologies to meet new challenges in regulatory risk assessments such as assessment of toxicity of pesticide metabolites and potential cumulative effects of pesticides to human health. Fate, behaviour and transformation of pesticides after their application and consequent release to the environment are a major aspect of pesticide risk assessment. The PPR Panel has achieved major accomplishments by delivering guidance and scientific opinions on degradation in soil, exposure of soil organisms and assessment of environmental risks by use of pesticides in greenhouses or grown under cover. A series of scientific opinions have been delivered also in the field of environmental risk assessment of pesticides. Scientific output covered specific issues arising in the peer review of specific active substances, revision of data requirements, development of risk assessment methodologies and the development of guidance documents. A major milestone of the PPR Panel was the development of the methodological framework for deriving specific protection goals for environmental risk

  8. LITERATURE REVIEW ON THE SORPTION OF PLUTONIUM, URANIUM, NEPTUNIUM, AMERICIUM AND TECHNETIUM TO CORROSION PRODUCTS ON WASTE TANK LINERS

    Energy Technology Data Exchange (ETDEWEB)

    Li, D.; Kaplan, D.

    2012-02-29

    The Savannah River Site (SRS) has conducted performance assessment (PA) calculations to determine the risk associated with closing liquid waste tanks. The PA estimates the risk associated with a number of scenarios, making various assumptions. Throughout all of these scenarios, it is assumed that the carbon-steel tank liners holding the liquid waste do not sorb the radionuclides. Tank liners have been shown to form corrosion products, such as Fe-oxyhydroxides (Wiersma and Subramanian 2002). Many corrosion products, including Fe-oxyhydroxides, at the high pH values of tank effluent, take on a very strong negative charge. Given that many radionuclides may have net positive charges, either as free ions or complexed species, it is expected that many radionuclides will sorb to corrosion products associated with tank liners. The objective of this report was to conduct a literature review to investigate whether Pu, U, Np, Am and Tc would sorb to corrosion products on tank liners after they were filled with reducing grout (cementitious material containing slag to promote reducing conditions). The approach was to evaluate radionuclides sorption literature with iron oxyhydroxide phases, such as hematite ({alpha}-Fe{sub 2}O{sub 3}), magnetite (Fe{sub 3}O{sub 4}), goethite ({alpha}-FeOOH) and ferrihydrite (Fe{sub 2}O{sub 3} {center_dot} 0.5H{sub 2}O). The primary interest was the sorption behavior under tank closure conditions where the tanks will be filled with reducing cementitious materials. Because there were no laboratory studies conducted using site specific experimental conditions, (e.g., high pH and HLW tank aqueous and solid phase chemical conditions), it was necessary to extend the literature review to lower pH studies and noncementitious conditions. Consequently, this report relied on existing lower pH trends, existing geochemical modeling, and experimental spectroscopic evidence conducted at lower pH levels. The scope did not include evaluating the appropriateness

  9. Plutonium in the environment - bibliographic study and quantification; Impacts environnemental et sanitaire des isotopes du plutonium, etude bibliographique et quantification

    Energy Technology Data Exchange (ETDEWEB)

    Guetat, Ph.; Monfort, M.; Ansoborlo, E. [CEA Marcoule, Dir. de l' Energie Nucleaire, 30 (France); Bion, L.; Moulin, V.; Reiller, P.; Vercouter, Th. [CEA Saclay, Dir. de l' Energie Nucleaire, 91 - Gif sur Yvette (France); Boucher, L.; Jourdain, F.; Van Dorpe, F. [CEA Cadarache, Dir. de l' Energie Nucleaire, 13 - Saint Paul lez Durance (France); Comte, A.; Flury Heard, A.; Fritsch, P.; Menetrier, F. [CEA Fontenay-aux-Roses, Dir. des Sciences du Vivant, 92 (France)

    2008-07-01

    This document deals with the different isotopes of plutonium. It intends to summarize the main features of plutonium behaviour from sources inside installation to the environment and man, and is expected to report the current knowledge about the different parameters used in the models for environmental and radiological impact assessment. The objective is to gather scientific information useful for deciders in case of accident or for regulation purposes. It gives main information on radiological and chemical characteristics which are necessary to understand transfers between compartments. Then it reports information on normal and accidental historical sources and present releases. The next part deals with transfer parameters in the installations and in environment. Parameters that influence its behaviour are examined, inside installations (physico-chemical forms and events that lead to releases), and outside in the environment for deposition to soils and transfer to plants, and animal products. A full chapter is dedicated to presentation of typical assessments, for each isotope and for mixture, and correspondence between activity, mass and dose reference levels are presented and discussed. Transfer and behaviour in man and effects on health are finally presented. (author)

  10. Sequential Determination of Free Acidity and Plutonium Concentration in the Dissolver Solution of Fast-Breeder Reactor Spent Fuels in a Single Aliquot.

    Science.gov (United States)

    Dhamodharan, K; Pius, Anitha

    2016-01-01

    A simple potentiometric method for determining the free acidity without complexation in the presence of hydrolysable metal ions and sequentially determining the plutonium concentration by a direct spectrophotometric method using a single aliquot was developed. Interference from the major fission products, which are susceptible to hydrolysis at lower acidities, had been investigated in the free acidity measurement. This method is applicable for determining the free acidity over a wide range of nitric acid concentrations as well as the plutonium concentration in the irradiated fuel solution prior to solvent extraction. Since no complexing agent is introduced during the measurement of the free acidity, the purification step is eliminated during the plutonium estimation, and the resultant analytical waste is free from corrosive chemicals and any complexing agent. Hence, uranium and plutonium can be easily recovered from analytical waste by the conventional solvent extraction method. The error involved in determining the free acidity and plutonium is within ±1% and thus this method is superior to the complexation method for routine analysis of plant samples and is also amenable for remote analysis.

  11. Editorial: from plant biotechnology to bio-based products.

    Science.gov (United States)

    Stöger, Eva

    2013-10-01

    From plant biotechnology to bio-based products - this Special Issue of Biotechnology Journal is dedicated to plant biotechnology and is edited by Prof. Eva Stöger (University of Natural Resources and Life Sciences, Vienna, Austria). The Special Issue covers a wide range of topics in plant biotechnology, including metabolic engineering of biosynthesis pathways in plants; taking advantage of the scalability of the plant system for the production of innovative materials; as well as the regulatory challenges and society acceptance of plant biotechnology.

  12. Manufacturing of Plutonium Tensile Specimens

    Energy Technology Data Exchange (ETDEWEB)

    Knapp, Cameron M [Los Alamos National Laboratory

    2012-08-01

    Details workflow conducted to manufacture high density alpha Plutonium tensile specimens to support Los Alamos National Laboratory's science campaigns. Introduces topics including the metallurgical challenge of Plutonium and the use of high performance super-computing to drive design. Addresses the utilization of Abaqus finite element analysis, programmable computer numerical controlled (CNC) machining, as well as glove box ergonomics and safety in order to design a process that will yield high quality Plutonium tensile specimens.

  13. Design criteria -- Reactor plant modifications for increased production and 100-C Area Alterations (Sections A and B) CG-558. Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    Russ, M.H.

    1954-08-10

    This document defines the basic criteria to be used in the preparation of detailed design for Project CG-558, Reactor Plant Modification for Increased Production and for Project CG-600, 100-C Area Alterations. It has been determined that the most economical method of increasing plutonium production within the next five years is by the modernization and improvement of the 100-B, 100-C, 100-D, 100-DR, 100-F, and 100-H reactor plants. These reactors are currently incapable of operating at their maximum potential power levels because of a limited availability of process cooling water. As a result of this programs, it is estimated that 1650-2350 megawatts of total additional production will be achieved. The purpose of this document is to set forth the design for certain modifications and additions to Hanford reactors and their supporting facilities as required to obtain higher power levels and improve the safety of reactor operation.

  14. Biomass Production System (BPS) Plant Growth Unit

    Science.gov (United States)

    Morrow, R. C.; Crabb, T. M.

    The Biomass Production System (BPS) was developed under the Small Business Innovative Research (SBIR) program to meet science, biotechnology and commercial plant growth needs in the Space Station era. The BPS is equivalent in size to a double middeck locker, but uses it's own custom enclosure with a slide out structure to which internal components mount. The BPS contains four internal growth chambers, each with a growing volume of more than 4 liters. Each of the growth chambers has active nutrient delivery, and independent control of temperature, humidity, lighting, and CO2 set-points. Temperature control is achieved using a thermoelectric heat exchanger system. Humidity control is achieved using a heat exchanger with a porous interface which can both humidify and dehumidify. The control software utilizes fuzzy logic for nonlinear, coupled temperature and humidity control. The fluorescent lighting system can be dimmed to provide a range of light levels. CO2 levels are controlled by injecting pure CO2 to the system based on input from an infrared gas analyzer. The unit currently does not scrub CO2, but has been designed to accept scrubber cartridges. In addition to providing environmental control, a number of features are included to facilitate science. The BPS chambers are sealed to allow CO2 and water vapor exchange measurements. The plant chambers can be removed to allow manipulation or sampling of specimens, and each chamber has gas/fluid sample ports. A video camera is provided for each chamber, and frame-grabs and complete environmental data for all science and hardware system sensors are stored on an internal hard drive. Data files can also be transferred to 3.5-inch disks using the front panel disk drive

  15. Functional Design Criteria plutonium stabilization and handling (PUSH) project W-460

    Energy Technology Data Exchange (ETDEWEB)

    NELSON, D.W.

    1999-09-02

    This Functional Design Criteria (FDC) contains information to guide the design of the Stabilization and Packaging Equipment necessary to oxidize and package the remaining plutonium-bearing Special Nuclear Materials (SNM) currently in the Plutonium Finishing Plant (PFP) inventory. The FDC also guides the design of vault modifications to allow storage of 3013 packages of stabilized SNM for up to 50 years.

  16. Instrumentation for studying binder burnout in an immobilized plutonium ceramic wasteform

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, M; Pugh, D; Herman, C

    2000-04-21

    The Plutonium Immobilization Program produces a ceramic wasteform that utilizes organic binders. Several techniques and instruments were developed to study binder burnout on full size ceramic samples in a production environment. This approach provides a method for developing process parameters on production scale to optimize throughput, product quality, offgas behavior, and plant emissions. These instruments allow for offgas analysis, large-scale TGA, product quality observation, and thermal modeling. Using these tools, results from lab-scale techniques such as laser dilametry studies and traditional TGA/DTA analysis can be integrated. Often, the sintering step of a ceramification process is the limiting process step that controls the production throughput. Therefore, optimization of sintering behavior is important for overall process success. Furthermore, the capabilities of this instrumentation allows better understanding of plant emissions of key gases: volatile organic compounds (VOCs), volatile inorganics including some halide compounds, NO{sub x}, SO{sub x}, carbon dioxide, and carbon monoxide.

  17. Controllability of plutonium concentration for FBR fuel at a solvent extraction process in the PUREX process

    Energy Technology Data Exchange (ETDEWEB)

    Enokida, Youichi; Kitano, Motoki; Sawada, Kayo [Nagoya University, 1 Furo-cho, Chikusa-ku, Nagoya-shi, Aichi-ken, 4630052 (Japan)

    2013-07-01

    Typical Purex solvent extraction systems for the reprocessing of spent nuclear fuel have a feed material containing dilute, 1% in weight, plutonium, along with uranium and fission products. Current reprocessing proposals call for no separation of the pure plutonium. The work described in this paper studied, by computer simulation, the fundamental feasibility of preparing a 20% concentrated plutonium product solution from the 1% feed by adjusting only the feed rates and acid concentrations of the incoming streams and without the addition of redox reagents for the plutonium. A set of process design flowsheets has been developed to realize a concentrated plutonium solution of a 20% stream from the dilute plutonium feed without using redox reagents. (authors)

  18. Plutonium worker dosimetry.

    Science.gov (United States)

    Birchall, Alan; Puncher, M; Harrison, J; Riddell, A; Bailey, M R; Khokryakov, V; Romanov, S

    2010-05-01

    Epidemiological studies of the relationship between risk and internal exposure to plutonium are clearly reliant on the dose estimates used. The International Commission on Radiological Protection (ICRP) is currently reviewing the latest scientific information available on biokinetic models and dosimetry, and it is likely that a number of changes to the existing models will be recommended. The effect of certain changes, particularly to the ICRP model of the respiratory tract, has been investigated for inhaled forms of (239)Pu and uncertainties have also been assessed. Notable effects of possible changes to respiratory tract model assumptions are (1) a reduction in the absorbed dose to target cells in the airways, if changes under consideration are made to the slow clearing fraction and (2) a doubling of absorbed dose to the alveolar region for insoluble forms, if evidence of longer retention times is taken into account. An important factor influencing doses for moderately soluble forms of (239)Pu is the extent of binding of dissolved plutonium to lung tissues and assumptions regarding the extent of binding in the airways. Uncertainty analyses have been performed with prior distributions chosen for application in epidemiological studies. The resulting distributions for dose per unit intake were lognormal with geometric standard deviations of 2.3 and 2.6 for nitrates and oxides, respectively. The wide ranges were due largely to consideration of results for a range of experimental data for the solubility of different forms of nitrate and oxides. The medians of these distributions were a factor of three times higher than calculated using current default ICRP parameter values. For nitrates, this was due to the assumption of a bound fraction, and for oxides due mainly to the assumption of slower alveolar clearance. This study highlights areas where more research is needed to reduce biokinetic uncertainties, including more accurate determination of particle transport rates

  19. Aromatic plant production on metal contaminated soils

    Energy Technology Data Exchange (ETDEWEB)

    Zheljazkov, Valtcho D. [Mississippi State, Department of Plant and Soil Sciences and North Mississippi Research and Extension Center, 5421 Highway 145 South, Verona, MS 38879 (United States)], E-mail: vj40@pss.msstate.edu; Craker, Lyle E.; Xing Baoshan [Department of Plant and Soil Sciences, 12 Stockbridge Hall, University of Massachusetts, Amherst, MA 01003 (United States); Nielsen, Niels E. [Plant Nutrition and Soil Fertility Lab, Department of Agricultural Sciences, Royal Veterinary and Agricultural University, Thorvaldsensvej 40, DK1871, Copenhagen (Denmark); Wilcox, Andrew [Harper Adams University College, Newport, Shropshire, TF10 8NB (United Kingdom)

    2008-06-01

    Field and container experiments were conducted to assess the feasibility of growing aromatic crops in metal contaminated areas and the effect of metals on herbage and oil productivity. The field experiments were conducted in the vicinities of the Non-Ferrous Metals Combine (Zn-Cu smelter) near Plovdiv, Bulgaria using coriander, sage, dill, basil, hyssop, lemon balm, and chamomile grown at various distances from the smelter. Herbage essential oil yields of basil, chamomile, dill, and sage were reduced when they were grown closer to the smelter. Metal removal from the site with the harvestable plant parts was as high as 180 g ha{sup -1} for Cd, 660 g ha{sup -1} for Pb, 180 g ha{sup -1} for Cu, 350 g ha{sup -1} for Mn, and 205 g ha{sup -1} for Zn. Sequential extraction of soil demonstrated that metal fractionation was affected by the distance to the smelter. With decreasing distance to the smelter, the transfer factor (TF) for Cu and Zn decreased but increased for Cd, while the bioavailability factor (BF) for Cd, Pb, Cu, Mn, and Zn decreased. Scanning electron microscopy and X-ray microanalyses of contaminated soil verified that most of the Pb, Cd, Mn, Cu, and Zn were in the form of small (< 1 {mu}m) particles, although there were larger particles (1-5 {mu}m) with high concentrations of individual metals. This study demonstrated that high concentrations of heavy metals in soil or growth medium did not result in metal transfer into the essential oil. Of the tested metals, only Cu at high concentrations may reduce oil content. Our results demonstrated that aromatic crops may not have significant phytoremediation potential, but growth of these crops in metal contaminated agricultural soils is a feasible alternative. Aromatic crops can provide economic return and metal-free final product, the essential oil.

  20. Managing plutonium in Britain. Current options[Mixed oxide nuclear fuels; Nuclear weapons

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    This is the report of a two day meeting to discuss issues arising from the reprocessing of plutonium and production of mixed oxide nuclear fuels in Britain. It was held at Charney Manor, near Oxford, on June 25 and 26, 1998, and was attended by 35 participants, including government officials, scientists, policy analysts, representatives of interested NGO's, journalists, a Member of Parliament, and visiting representatives from the US and Irish governments. The topic of managing plutonium has been a consistent thread within ORG's work, and was the subject of one of our previous reports, CDR 12. This particular seminar arose out of discussions earlier in the year between Dr. Frank Barnaby and the Rt. Hon. Michael Meacher MP, Minister for the Environment. With important decisions about the management of plutonium in Britain pending, ORG undertook to hold a seminar at which all aspects of the subject could be aired. A number of on-going events formed the background to this initiative. The first was British Nuclear Fuels' [BNFL] application to the Environment Agency to commission a mixed oxide fuel [MOX] plant at Sellafield. The second was BNFL's application to vary radioactive discharge limits at Sellafield. Thirdly, a House of Lords Select Committee was in process of taking evidence, on the disposal of radioactive waste. Fourthly, the Royal Society, in a recent report entitled Management of Separated Plutonium, recommended that 'the Government should commission a comprehensive review... of the options for the management of plutonium'. Four formal presentations were made to the meeting, on the subjects of Britain's plutonium policy, commercial prospects for plutonium use, problems of plutonium accountancy, and the danger of nuclear terrorism, by experts from outside the nuclear industry. It was hoped that the industry's viewpoint would also be heard, and BNFL were invited to present a paper, but declined on the grounds that they

  1. Standard specification for sintered (Uranium-Plutonium) dioxide pellets

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2001-01-01

    1.1 This specification covers finished sintered and ground (uranium-plutonium) dioxide pellets for use in thermal reactors. It applies to uranium-plutonium dioxide pellets containing plutonium additions up to 15 % weight. This specification may not completely cover the requirements for pellets fabricated from weapons-derived plutonium. 1.2 This specification does not include (1) provisions for preventing criticality accidents or (2) requirements for health and safety. Observance of this specification does not relieve the user of the obligation to be aware of and conform to all applicable international, federal, state, and local regulations pertaining to possessing, processing, shipping, or using source or special nuclear material. Examples of U.S. government documents are Code of Federal Regulations Title 10, Part 50Domestic Licensing of Production and Utilization Facilities; Code of Federal Regulations Title 10, Part 71Packaging and Transportation of Radioactive Material; and Code of Federal Regulations Tit...

  2. Crystalline ceramics: Waste forms for the disposal of weapons plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Ewing, R.C.; Lutze, W. [New Mexico Univ., Albuquerque, NM (United States); Weber, W.J. [Pacific Northwest Lab., Richland, WA (United States)

    1995-05-01

    At present, there are three seriously considered options for the disposition of excess weapons plutonium: (i) incorporation, partial burn-up and direct disposal of MOX-fuel; (ii) vitrification with defense waste and disposal as glass ``logs``; (iii) deep borehole disposal (National Academy of Sciences Report, 1994). The first two options provide a safeguard due to the high activity of fission products in the irradiated fuel and the defense waste. The latter option has only been examined in a preliminary manner, and the exact form of the plutonium has not been identified. In this paper, we review the potential for the immobilization of plutonium in highly durable crystalline ceramics apatite, pyrochlore, monazite and zircon. Based on available data, we propose zircon as the preferred crystalline ceramic for the permanent disposition of excess weapons plutonium.

  3. Terrestrial plant methane production and emission

    DEFF Research Database (Denmark)

    Bruhn, Dan; Møller, Ian M.; Mikkelsen, Teis Nørgaard

    2012-01-01

    In this minireview, we evaluate all experimental work published on the phenomenon of aerobic methane (CH4) generation in terrestrial plants and plant. Clearly, despite much uncertainty and skepticism, we conclude that the phenomenon is true. Four stimulating factors have been observed to induce...... aerobic CH4 into a global budget is inadequate. Thus it is too early to draw the line under the aerobic methane emission in plants. Future work is needed for establishing the relative contribution of several proven potential CH4 precursors in plant material....

  4. Recovery of plutonium from electrorefining anode heels at Savannah River

    Energy Technology Data Exchange (ETDEWEB)

    Gray, J H; Gray, L W; Karraker, D G

    1987-03-01

    In a joint effort, the Savannah River Laboratory (SRL), Savannah River Plant (SRP), and the Rocky Flats Plant (RFP) have developed two processes to recover plutonium from electrorefining anode heel residues. Aqueous dissolution of anode heel metal was demonstrated at SRL on a laboratory scale and on a larger pilot scale using either sulfamic acid or nitric acid-hydrazine-fluoride solutions. This direct anode heel metal dissolution requires the use of a geometrically favorable dissolver. The second process developed involves first diluting the plutonium in the anode heel residues by alloying with aluminum. The alloyed anode heel plutonium can then be dissolved using a nitric acid-fluoride-mercury(II) solution in large non-geometrically favorable equipment where nuclear safety is ensured by concentration control.

  5. Metabolic engineering for the production of plant isoquinoline alkaloids.

    Science.gov (United States)

    Diamond, Andrew; Desgagné-Penix, Isabel

    2016-06-01

    Several plant isoquinoline alkaloids (PIAs) possess powerful pharmaceutical and biotechnological properties. Thus, PIA metabolism and its fascinating molecules, including morphine, colchicine and galanthamine, have attracted the attention of both the industry and researchers involved in plant science, biochemistry, chemical bioengineering and medicine. Currently, access and availability of high-value PIAs [commercialized (e.g. galanthamine) or not (e.g. narciclasine)] is limited by low concentration in nature, lack of cultivation or geographic access, seasonal production and risk of overharvesting wild plant species. Nevertheless, most commercial PIAs are still extracted from plant sources. Efforts to improve the production of PIA have largely been impaired by the lack of knowledge on PIA metabolism. With the development and integration of next-generation sequencing technologies, high-throughput proteomics and metabolomics analyses and bioinformatics, systems biology was used to unravel metabolic pathways allowing the use of metabolic engineering and synthetic biology approaches to increase production of valuable PIAs. Metabolic engineering provides opportunity to overcome issues related to restricted availability, diversification and productivity of plant alkaloids. Engineered plant, plant cells and microbial cell cultures can act as biofactories by offering their metabolic machinery for the purpose of optimizing the conditions and increasing the productivity of a specific alkaloid. In this article, is presented an update on the production of PIA in engineered plant, plant cell cultures and heterologous micro-organisms.

  6. Thermal and Physical Properties of Plutonium Dioxide Produced from the Oxidation of Metal: a Data Summary

    Energy Technology Data Exchange (ETDEWEB)

    Wayne, David M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-01-13

    The ARIES Program at the Los Alamos National Laboratory removes plutonium metal from decommissioned nuclear weapons, and converts it to plutonium dioxide in a specially-designed Direct Metal Oxidation furnace. The plutonium dioxide is analyzed for specific surface area, particle size distribution, and moisture content. The purpose of these analyses is to certify that the plutonium dioxide powder meets or exceeds the specifications of the end-user, and the specifications for the packaging and transport of nuclear materials. Analytical results from plutonium dioxide from ARIES development activities, from ARIES production activities, from muffle furnace oxidation of metal, and from metal that was oxidized over a lengthy time interval in air at room temperature, are presented. The processes studied produce plutonium dioxide powder with distinct differences in measured properties, indicating the significant influence of oxidation conditions on physical properties.

  7. Probing Phonons in Plutonium

    Science.gov (United States)

    Wong, Joe

    2004-03-01

    The phonon spectra of plutonium and its alloys have been sought after in the past few decades following the discovery of this actinide element in 1941, but with no success. This was due to a combination of the high neutron absorption cross section of 239Pu, the common isotope, and non-availability of large single crystals of any Pu-bearing materials. We have recent designed a high resolution inelastic x-ray scattering experiment using a bright synchrotron x-ray beam at the European Sychrotron Radiation Facility (ESRF), Grenoble and mapped the full phonon dispersion curves of an fcc delta-phase polycrystalline Pu-Ga alloy (1). Several unusual features including, a large elastic anisotropy, a small shear elastic modulus C', a Kohn-like anomaly in the T1[011] branch, and a pronounced softening of the [111] transverse modes are found. These features can be related to the phase transitions of plutonium and to strong coupling between the lattice structure and the 5f valence instabilities. Our results also provide a critical test for theoretical treatments of highly correlated 5f electron systems as exemplified by recent dynamical mean field theory (DMFT) calculations for d-plutonium.(2) This work was performed in collaboration with Dr. M. Krisch (ESRF)) and Prof. T.-C. Chiang (UIU), and under the auspices of the U. S. Department of Energy by the University of California, Lawrence Livermore National Laboratory under Contract No. W-7405-Eng-48. 1. Joe Wong et al. Science, vol.301, 1078 (2003) 2. X. Dai et al. Science, vol.300, 953 (2003)

  8. Conceptual Design for the Pilot-Scale Plutonium Oxide Processing Unit in the Radiochemical Processing Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Lumetta, Gregg J.; Meier, David E.; Tingey, Joel M.; Casella, Amanda J.; Delegard, Calvin H.; Edwards, Matthew K.; Jones, Susan A.; Rapko, Brian M.

    2014-08-05

    This report describes a conceptual design for a pilot-scale capability to produce plutonium oxide for use as exercise and reference materials, and for use in identifying and validating nuclear forensics signatures associated with plutonium production. This capability is referred to as the Pilot-scale Plutonium oxide Processing Unit (P3U), and it will be located in the Radiochemical Processing Laboratory at the Pacific Northwest National Laboratory. The key unit operations are described, including plutonium dioxide (PuO2) dissolution, purification of the Pu by ion exchange, precipitation, and conversion to oxide by calcination.

  9. Plutonium and the risk of cancer. A comparative analysis of Pu-body burdens due to releases from nuclear plants (Chelyabinsk-65, Gomel area) and global fallout.

    Science.gov (United States)

    Hohryakov, V F; Syslova, C G; Skryabin, A M

    1994-03-01

    Results of the analysis of dynamic body burdens of Pu in adult inhabitants of Chelyabinsk-65 (not occupationally exposed) and different areas of the Gomel region are presented for 1990-1991. The data are based on radiochemical analyses of Pu in human organs and tissues. Comparison with the published data on global Pu and our data for human autopsies (Ufa, Russia) revealed that estimates of Pubody burdens in Chelyabinsk-65 residents were up to 30 times higher than global levels and depended on the period of residence in town. The Pu body contents of Gomel citizens 4-5 years after the Chernobyl accident are on average 3-4 times higher than the global levels. Activity of Pu-238 in various organs constitutes 4.7-26.0% (on the average 13.5 +/- 5.0%) of the total alpha-activity of Pu-238 and Pu-239, 240. The expected number of cancers induced by incorporated plutonium is approximately the same for the two population groups despite their different sizes and does not differ from the global level by more than one order of magnitude.

  10. Plants and endophytes: equal partners in secondary metabolite production?

    Science.gov (United States)

    Ludwig-Müller, Jutta

    2015-07-01

    Well known plant production systems should be re-evaluated due to findings that the interesting metabolite might actually be produced by microbes intimately associated with the plant, so-called endophytes. Endophytes can be bacteria or fungi and they are characterized usually by the feature that they do not cause any harm to the host. Indeed, in some cases, such as mycorrhizal fungi or other growth promoting endophytes, they can be beneficial for the plant. Here some examples are reviewed where the host plant and/or endophyte metabolism can be induced by the other partner. Also, partial or complete biosynthesis pathways for plant secondary metabolites can be attributed to such endophytes. In other cases the host plant is able to metabolize substances from fungal origin. The question of the natural role of such metabolic changes for the endophyte will be briefly touched. Finally, the consequences for the use of plant cultures for secondary metabolite production is discussed.

  11. Solar Cogeneration Facility: Cimarron River Station, Central Telephone and Utilities-Western Power

    Science.gov (United States)

    1981-08-01

    A site-specific conceptual design and evaluation of a solar central receiver system integrated with an existing cogeneration facility are described. The system generates electricity and delivers a portion of that electricity and process steam to a natural gas processing plant. Early in the project, tradeoff studies were performed to establish key system characteristics. As a result of these studies the use of energy storage was eliminated, the size of the solar facility was established at 37.13 MW (sub t), and other site-specific features were selected. The conceptual design addressed critical components and system interfaces. The result is a hybrid solar/fossil central receiver facility which utilizes a collector system of Department of Energy second generation heliostats.

  12. Role of root microbiota in plant productivity.

    Science.gov (United States)

    Tkacz, Andrzej; Poole, Philip

    2015-04-01

    The growing human population requires increasing amounts of food, but modern agriculture has limited possibilities for increasing yields. New crop varieties may be bred to have increased yields and be more resistant to environmental stress and pests. However, they still require fertilization to supplement essential nutrients that are normally limited in the soil. Soil microorganisms present an opportunity to reduce the requirement for inorganic fertilization in agriculture. Microorganisms, due to their enormous genetic pool, are also a potential source of biochemical reactions that recycle essential nutrients for plant growth. Microbes that associate with plants can be considered to be part of the plant's pan-genome. Therefore, it is essential for us to understand microbial community structure and their 'metagenome' and how it is influenced by different soil types and crop varieties. In the future we may be able to modify and better utilize the soil microbiota potential for promoting plant growth.

  13. Plant Design for the Production of DUAGG

    Energy Technology Data Exchange (ETDEWEB)

    Ferrada, J.J.

    2003-02-04

    The cost of producing DUAGG is an important consideration for any interested private firm in determining whether DUCRETE is economically viable as a material of construction in next-generation spent nuclear fuel casks. This study analyzed this project as if it was a stand-alone project. The capital cost includes engineering design, equipment costs and installation, start up, and management; the study is not intended to be a life-cycle cost analysis. The costs estimated by this study are shown in Table ES.1, and the conclusions of this study are listed in Table ES.2. The development of DUAGG and DUCRETE is a major thrust of the Depleted Uranium Uses Research and Development Project. An obvious use of depleted uranium is as a shielding material (e.g., DUCRETE). DUCRETE is made by replacing the conventional stone aggregate in concrete with DUAGG. One objective of this project is to bring the development of DUCRETE to a point at which a demonstrated basis exists for its commercial deployment. The estimation of the costs to manufacture DUAGG is an important part of this effort. Paul Lessing and William Quapp developed DUAGG and DUCRETE as part of an Idaho National Engineering and Environmental Laboratory (INEEL) program to find beneficial uses for depleted uranium (DU). Subsequently, this technology was licensed to Teton Technologies, Inc. The DUAGG process mixes DUO{sub 2} with sintering materials and additives to form pressed briquettes. These briquettes are sintered at 1300 C, and the very dense sintered briquettes are then crushed and classified into gap-graded size fractions. The graded DUAGG is then ready to be used to make high-strength heavy DUCRETE. The DUCRETE shielding will be placed into an annular steel cask-shell mold, which has internal steel reinforcing bars. The objectives of this study are to (1) use previous DUAGG process developments to design a plant that will produce DUAGG at a baseline rate, (2) determine the size of the equipment required to meet

  14. Vertical distributions of plutonium isotopes in marine sediment cores off the Fukushima coast after the Fukushima Dai-ichi Nuclear Power Plant accident

    Directory of Open Access Journals (Sweden)

    W. T. Bu

    2013-04-01

    Full Text Available The Fukushima Dai-ichi Nuclear Power Plant (FDNPP accident led to the release of large amounts of radionuclides into the atmosphere as well as direct discharges into the sea. In contrast to the intensive studies on the distribution of the released high volatility fission products, such as 131I, 134Cs and 137Cs, similar studies of the actinides, especially the Pu isotopes, are limited. To obtain the vertical distribution of Pu isotopes in marine sediments and to better assess the possible contamination of Pu from the FDNPP accident in the marine environment, we determined the activities of 239+240Pu and 241Pu as well as the atom ratios of 240Pu/239Pu and 241Pu/239Pu in sediment core samples collected in the western North Pacific off Fukushima from July 2011 to July 2012. We also measured surface sediment samples collected from seven Japanese estuaries before the FNDPP accident to establish the comprehensive background baseline data. The observed results of both the Pu activities and the Pu atom ratios for the sediments in the western North Pacific were comparable to the baseline data, suggesting that the FDNPP accident did not cause detectable Pu contamination to the studied regions prior to the sampling time. The Pu isotopes in the western North Pacific 30 km off the Fukushima coast originated from global fallout and Pacific Proving Ground close-in fallout.

  15. Plant nutrition in future greenhouse production

    NARCIS (Netherlands)

    Sonneveld, C.; Voogt, W.

    2009-01-01

    In the introduction chapter it was claimed that greenhouse production has no longer arguments as a supply market. The products of the greenhouse industry became in free competition with those from field production from all over the world. In this competition the greenhouse industry has developed int

  16. Learning more about plutonium; En savoir plus sur le plutonium

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    This digest brochure explains what plutonium is, where it comes from, how it is used, its recycling into Mox fuel, its half life, historical discovery, its presence in the environment, toxicity and radioactivity. (J.S.)

  17. Application of plant cell and tissue culture for the production of phytochemicals in medicinal plants.

    Science.gov (United States)

    Pant, Bijaya

    2014-01-01

    Approximately 80% of the world inhabitants depend on the medicinal plants in the form of traditional formulations for their primary health care system well as in the treatment of a number of diseases since the ancient time. Many commercially used drugs have come from the information of indigenous knowledge of plants and their folk uses. Linking of the indigenous knowledge of medicinal plants to modern research activities provides a new reliable approach, for the discovery of novel drugs much more effectively than with random collection. Increase in population and increasing demand of plant products along with illegal trade are causing depletion of medicinal plants and many are threatened in natural habitat. Plant tissue culture technique has proved potential alternative for the production of desirable bioactive components from plants, to produce the enough amounts of plant material that is needed and for the conservation of threatened species. Different plant tissue culture systems have been extensively studied to improve and enhance the production of plant chemicals in various medicinal plants.

  18. Determination of plutonium isotopes in marine sediments off the Fukushima coast following the Fukushima Dai-ichi Nuclear Power Plant accident

    Directory of Open Access Journals (Sweden)

    W. T. Bu

    2013-01-01

    Full Text Available The Fukushima Dai-ichi Nuclear Power Plant (FDNPP accident led to the release of large amounts of radionuclides into the atmosphere as well as direct discharges into the sea. In contrast to the intensive studies on the distribution of the released high volatility fission products, such as 131I, 134Cs and 137Cs, similar studies of the actinides, especially the Pu isotopes, are limited. To obtain the vertical distribution of Pu isotopes in marine sediments and to better assess the possible contamination of Pu from the FDNPP accident in the marine environment, we determined the activities of 239+240Pu and 241Pu as well as the atom ratios of 240Pu / 239Pu and 241Pu / 239Pu in sediment core samples collected in the western North Pacific off Fukushima from July 2011 to July 2012. We also measured surface sediment samples collected from seven Japanese estuaries before the FNDPP accident to establish the comprehensive background baseline data. The observed results of both the Pu activities and the Pu atom ratios for the sediments in the western North Pacific were comparable to the baseline data, suggesting that the FDNPP accident did not cause detectable Pu contamination to the studied regions prior to the sampling time. The Pu isotopes in the western North Pacific 30 km off Fukushima coast originated from global fallout and Pacific Proving Ground close-in fallout.

  19. Enhanced methanol production in plants provides broad spectrum insect resistance.

    Directory of Open Access Journals (Sweden)

    Sameer Dixit

    Full Text Available Plants naturally emit methanol as volatile organic compound. Methanol is toxic to insect pests; but the quantity produced by most of the plants is not enough to protect them against invading insect pests. In the present study, we demonstrated that the over-expression of pectin methylesterase, derived from Arabidopsis thaliana and Aspergillus niger, in transgenic tobacco plants enhances methanol production and resistance to polyphagous insect pests. Methanol content in the leaves of transgenic plants was measured using proton nuclear spectroscopy (1H NMR and spectra showed up to 16 fold higher methanol as compared to control wild type (WT plants. A maximum of 100 and 85% mortality in chewing insects Helicoverpa armigera and Spodoptera litura larvae was observed, respectively when fed on transgenic plants leaves. The surviving larvae showed less feeding, severe growth retardation and could not develop into pupae. In-planta bioassay on transgenic lines showed up to 99 and 75% reduction in the population multiplication of plant sap sucking pests Myzus persicae (aphid and Bemisia tabaci (whitefly, respectively. Most of the phenotypic characters of transgenic plants were similar to WT plants. Confocal microscopy showed no deformities in cellular integrity, structure and density of stomata and trichomes of transgenic plants compared to WT. Pollen germination and tube formation was also not affected in transgenic plants. Cell wall enzyme transcript levels were comparable with WT. This study demonstrated for the first time that methanol emission can be utilized for imparting broad range insect resistance in plants.

  20. Plants for water recycling, oxygen regeneration and food production

    Science.gov (United States)

    Bubenheim, D. L.

    1991-01-01

    During long-duration space missions that require recycling and regeneration of life support materials the major human wastes to be converted to usable forms are CO2, hygiene water, urine and feces. A Controlled Ecological Life Support System (CELSS) relies on the air revitalization, water purification and food production capabilities of higher plants to rejuvenate human wastes and replenish the life support materials. The key processes in such a system are photosynthesis, whereby green plants utilize light energy to produce food and oxygen while removing CO2 from the atmosphere, and transpiration, the evaporation of water from the plant. CELSS research has emphasized the food production capacity and efforts to minimize the area/volume of higher plants required to satisfy all human life support needs. Plants are a dynamic system capable of being manipulated to favour the supply of individual products as desired. The size and energy required for a CELSS that provides virtually all human needs are determined by the food production capacity. Growing conditions maximizing food production do not maximize transpiration of water; conditions favoring transpiration and scaling to recycle only water significantly reduces the area, volume, and energy inputs per person. Likewise, system size can be adjusted to satisfy the air regeneration needs. Requirements of a waste management system supplying inputs to maintain maximum plant productivity are clear. The ability of plants to play an active role in waste processing and the consequence in terms of degraded plant performance are not well characterized. Plant-based life support systems represent the only potential for self sufficiency and food production in an extra-terrestrial habitat.

  1. The mycorrhizal contribution to plant productivity, plant nutrition and soil structure in experimental grassland.

    Science.gov (United States)

    van der Heijden, Marcel G A; Streitwolf-Engel, Ruth; Riedl, Ralph; Siegrist, Sabine; Neudecker, Angelica; Ineichen, Kurt; Boller, Thomas; Wiemken, Andres; Sanders, Ian R

    2006-01-01

    Previous studies have shown that arbuscular mycorrhizal fungi (AMF) can influence plant diversity and ecosystem productivity. However, little is known about the effects of AMF and different AMF taxa on other important community properties such as nutrient acquisition, plant survival and soil structure. We established experimental grassland microcosms and tested the impact of AMF and of different AMF taxa on a number of grassland characteristics. We also tested whether plant species benefited from the same or different AMF taxa in subsequent growing seasons. AMF enhanced phosphorus acquisition, soil aggregation and survival of several plant species, but AMF did not increase total plant productivity. Moreover, AMF increased nitrogen acquisition by some plant species, but AMF had no effect on total N uptake by the plant community. Plant growth responses to AMF were temporally variable and some plant species obtained the highest biomass with different AMF in different years. Hence the results indicate that it may be beneficial for a plant to be colonized by different AMF taxa in different seasons. This study shows that AMF play a key role in grassland by improving plant nutrition and soil structure, and by regulating the make-up of the plant community.

  2. Preliminary safety evaluation for the plutonium stabilization and packaging system

    Energy Technology Data Exchange (ETDEWEB)

    Shapley, J.E., Fluor Daniel Hanford

    1997-03-14

    This Preliminary Safety Evaluation (PSE) describes and analyzes the installation and operation of the Plutonium Stabilization and Packaging System (SPS) at the Plutonium Finishing Plant (PFP). The SPS is a combination of components required to expedite the safe and timely storage of Plutonium (Pu) oxide. The SPS program will receive site Pu packages, process the Pu for storage, package the Pu into metallic containers, and safely store the containers in a specially modified storage vault. The location of the SPS will be in the 2736- ZB building and the storage vaults will be in the 2736-Z building of the PFP, as shown in Figure 1-1. The SPS will produce storage canisters that are larger than those currently used for Pu storage at the PFP. Therefore, the existing storage areas within the PFP secure vaults will require modification. Other modifications will be performed on the 2736-ZB building complex to facilitate the installation and operation of the SPS.

  3. The transports in the French Plutonium Industry. A high risk activity

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-02-01

    This study throws light on the scale of transport of plutonium in France nuclear industry, an activity involving quantities of high risk materials often unknown to the public. The study is a significantly extended update of the one carried out by WISE-Paris in 1995 for the Plutonium Forum. It was motivated by important developments in the French plutonium industry and the publication of numerous data concerning transport activities since 1995. The 2003 study presents, in particular, all of the flows of plutonium crossing France every year, as well as analysis of the risks associated with this particular transport activity. Putting these data into perspective in terms of a rapidly and permanently changing political and industrial context, and a description of the regulatory framework within which shipments of plutonium take place, serve as a guide and source of reference to help readers better understand the issues. The importance of transport in the plutonium ''chain'', i.e. the stages corresponding to various industrial processes, is often under-estimated, even by the nuclear industry itself. Transport is, in fact, the activity which involves the greatest quantities of plutonium in the entire nuclear chain. Plutonium, produced during the fission reactions in the cores of nuclear reactors, is transported, contained in the irradiated fuel, to the facilities at La Hague where reprocessing separates it from the other radioactive components of the spent fuel. Part of the plutonium, now isolated in powder form, is then shipped to one of the three plants able to produce the fuel known as MOX. These are located at Cadarache and Marcoule, in France, and at Dessel in Belgium. Once in the MOX form, this plutonium has to be re-transported to reactor sites to be used. Once irradiated, the spent MOX will return to the La Hague installations to be stored for an unknown period; the plutonium contained in the spent MOX is not, at present, destined to be re

  4. Catalytic production of aromatics and olefins from plant materials

    Energy Technology Data Exchange (ETDEWEB)

    Haag, W.O.; Rodewald, P.G.; Weisz, P.B.

    1980-08-01

    Hydrocarbons and hydrocarbon-like plant materials offer the possibility of relatively simple and energy-efficient processing to liquid fuels or petrochemicals. The use of such highly reduced photosynthesis products as potential fuels has been advocated by Calvin and coworkers, and Buchanan and coworkers have evaluated several hundred plant species for the presence of hydrocarbons. The yield of extracted oils may exceed 10 wt % of the plant dry weight. Some field growth studies of the most promising of these plants are underway, e.g., by Calvin in California, by Native Plants, Inc., and by the Diamond Shamrock Co., in conjunction with the University of Arizona, mostly with Euphorbia and related genera. Exploratory studies were performed to determine if direct catalytic upgrading of the hydrocarbon-like plant constituents could be carried out. A preliminary report has been published recently. A variety of plant materials were shown to be upgraded to liquid premium fuels by relatively simple catalytic processing over Mobil's shape selective zeolite, ZSM-5. The present paper contains additional information on the conversion of a variety of plant materials with special emphasis on the production of petrochemicals, and discusses key mechanistic aspects of the reactions. Feedstocks were chosen to represent different types of plant materials: corn oil, castor oil and jojoba seed oil; plant extracts from Euphorbia lathyrus and Grindelia squarrosa; and hydrocarbons obtained by tapping of trees such as copaiba oil and natural rubber latex.

  5. Energy Resiliency for Marine Corps Logistics Base Production Plant Barstow

    Science.gov (United States)

    2014-12-01

    feasible microgrid and on-site energy generation options to provide power infrastructure resiliency aboard Production Plant Barstow (PPB), such that the...for selecting a cost-effective, resilient and scalable alternative energy portfolio, and creates a levelized cost for a microgrid and its...thesis is to examine feasible microgrid and on-site energy generation options to provide power infrastructure resiliency aboard Production Plant Barstow

  6. Secondary Broccoli Production Depending On Sowing And Planting Dates

    OpenAIRE

    Todorova, Desislava

    2014-01-01

    The investigation was carried out during the period of 2009-2011 at the Institute of Agriculture – Kyustendil, located in the Southwest Bulgaria. Four broccoli (Brassica oleracea var. italica Plenck) hybrids were grown by the technology of late field production with different sowing and planting dates. The aim of the research was to establish a relationship between planting time and secondary yield of broccoli. Some morphological characteristics and production traits of an additional yield of...

  7. Plant Products for Pharmacology: Application of Enzymes in Their Transformations

    Directory of Open Access Journals (Sweden)

    Marie Zarevúcka

    2008-12-01

    Full Text Available Different plant products have been subjected to detailed investigations due to their increasing importance for improving human health. Plants are sources of many groups of natural products, of which large number of new compounds has already displayed their high impact in human medicine. This review deals with the natural products which may be found dissolved in lipid phase (phytosterols, vitamins etc.. Often subsequent convenient transformation of natural products may further improve the pharmacological properties of new potential medicaments based on natural products. To respect basic principles of sustainable and green procedures, enzymes are often employed as efficient natural catalysts in such plant product transformations. Transformations of lipids and other natural products under the conditions of enzyme catalysis show increasing importance in environmentally safe and sustainable production of pharmacologically important compounds. In this review, attention is focused on lipases, efficient and convenient biocatalysts for the enantio- and regioselective formation / hydrolysis of ester bond in a wide variety of both natural and unnatural substrates, including plant products, eg. plant oils and other natural lipid phase compounds. The application of enzymes for preparation of acylglycerols and transformation of other natural products provides big advantage in comparison with employing of conventional chemical methods: Increased selectivity, higher product purity and quality, energy conservation, elimination of heavy metal catalysts, and sustainability of the employed processes, which are catalyzed by enzymes. Two general procedures are used in the transformation of lipid-like natural products: (a Hydrolysis/alcoholysis of triacylglycerols and (b esterification of glycerol. The reactions can be performed under conventional conditions or in supercritical fluids/ionic liquids. Enzyme-catalyzed reactions in supercritical fluids combine the

  8. State regulation and power plant productivity: background and recommendations

    Energy Technology Data Exchange (ETDEWEB)

    1980-09-01

    This report was prepared by representatives of several state regulatory agencies. It is a guide to some of the activities currently under way in state agencies to promote increased availability of electrical generating power plants. Standard measures of plant performance are defined and the nature of data bases that report such measures is discussed. It includes reviews of current state, federal, and industry programs to enhance power plant productivity and provides detailed outlines of programs in effect in California, Illinois, Michigan, New York, North Carolina, Ohio, and Texas. A number of actions are presented that could be adopted by state regulatory agencies, depending on local conditions. They include: develop a commission position or policy statement to encourage productivity improvements by utilities; coordinate state efforts with ongoing industry and government programs to improve the acquisition of power plant performance data and the maintenance of quality information systems; acquire the capability to perform independent analyses of power plant productivity; direct the establishment of productivity improvement programs, including explicit performance objectives for both existing and planned power plants, and a performance program; establish a program of incentives to motivate productivity improvement activities; and participate in ongoing efforts at all levels and initiate new actions to promote productivity improvements.

  9. MICROBIAL TRANSFORMATIONS OF PLUTONIUM AND IMPLICATIONS FOR ITS MOBILITY.

    Energy Technology Data Exchange (ETDEWEB)

    FRANCIS, A.J.

    2000-09-30

    The current state of knowledge of the effect of plutonium on microorganisms and microbial activity is reviewed, and also the microbial processes affecting its mobilization and immobilization. The dissolution of plutonium is predominantly due to their production of extracellular metabolic products, organic acids, such as citric acid, and sequestering agents, such as siderophores. Plutonium may be immobilized by the indirect actions of microorganisms resulting in changes in Eh and its reduction from a higher to lower oxidation state, with the precipitation of Pu, its bioaccumulation by biomass, and bioprecipitation reactions. In addition, the abundance of microorganisms in Pu-contaminated soils, wastes, natural analog sites, and backfill materials that will be used for isolating the waste and role of microbes as biocolloids in the transport of Pu is discussed.

  10. Production of Aromatic Plant Terpenoids in Recombinant Baker's Yeast.

    Science.gov (United States)

    Emmerstorfer-Augustin, Anita; Pichler, Harald

    2016-01-01

    Plant terpenoids are high-value compounds broadly applied as food additives or fragrances in perfumes and cosmetics. Their biotechnological production in yeast offers an attractive alternative to extraction from plants. Here, we provide two optimized protocols for the production of the plant terpenoid trans-nootkatol with recombinant S. cerevisiae by either (I) converting externally added (+)-valencene with resting cells or (II) cultivating engineered self-sufficient production strains. By synthesis of the hydrophobic compounds in self-sufficient production cells, phase transfer issues can be avoided and the highly volatile products can be enriched in and easily purified from n-dodecane, which is added to the cell broth as second phase.

  11. Health physics manual of good practices for plutonium facilities. [Contains glossary

    Energy Technology Data Exchange (ETDEWEB)

    Brackenbush, L.W.; Heid, K.R.; Herrington, W.N.; Kenoyer, J.L.; Munson, L.F.; Munson, L.H.; Selby, J.M.; Soldat, K.L.; Stoetzel, G.A.; Traub, R.J.

    1988-05-01

    This manual consists of six sections: Properties of Plutonium, Siting of Plutonium Facilities, Facility Design, Radiation Protection, Emergency Preparedness, and Decontamination and Decommissioning. While not the final authority, the manual is an assemblage of information, rules of thumb, regulations, and good practices to assist those who are intimately involved in plutonium operations. An in-depth understanding of the nuclear, physical, chemical, and biological properties of plutonium is important in establishing a viable radiation protection and control program at a plutonium facility. These properties of plutonium provide the basis and perspective necessary for appreciating the quality of control needed in handling and processing the material. Guidance in selecting the location of a new plutonium facility may not be directly useful to most readers. However, it provides a perspective for the development and implementation of the environmental surveillance program and the in-plant controls required to ensure that the facility is and remains a good neighbor. The criteria, guidance, and good practices for the design of a plutonium facility are also applicable to the operation and modification of existing facilities. The design activity provides many opportunities for implementation of features to promote more effective protection and control. The application of ''as low as reasonably achievable'' (ALARA) principles and optimization analyses are generally most cost-effective during the design phase. 335 refs., 8 figs., 20 tabs.

  12. ``Distribution and behaviour of plutonium in the waters of the channel and of the seine estuary``; ``Distribution et comportement du plutonium dans les eaux de la manche et de l`estuaire de la seine``

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, K.

    1997-12-31

    Excess dissolved plutonium has been measured in the coastal waters of the Channel, from Granville to Boulogne, probably due to sorption-desorption processus. In the Seine estuary, in situ measurements and experimental studies showed that the plutonium desorbs himself from particles in low salinity waters. The desorbed plutonium originates in marine and/or fluvial dissolved Pu. Marine dissolved Pu(V), originating from La Hague plant discharges and from atlantic waters, is reduced and sorbed when the salinity decreases onto estuarial particles: Isotopic Activity Ration {sup 238}Pu/{sup 239}, Pu(IR) of marine dissolved Pu(V) is about 0.7. Fluvial dissolved plutonium originates from atmospheric fallout and from an internal river source: fallout plutonium (IR=0.05) is unreactive with salinity while 45% of river plutonium (IR>1.7) flocculates at 0.5 g l{sup -1}. Desorbed plutonium may have various origins, depending on the Seine liquid discharges and on the tidal coefficient. When the marine waters do not migrate upstream, the low salinity waters encounters particles marked essentially with marine plutonium and the IR of desorbed Pu is about 0.7. The activities of desorbed plutonium are too low to have any influence on the distribution of plutonium in the coastal waters on the Seine Bay. When the marine waters migrate upstream, the low salinity waters meet particles marked essentially with river plutonium (IR>1.7) and desorbed plutonium has a very high IR. These estuarine conditions are encountered five to seven month a year and implicate an increase of the IR of 0.1 of the plutonium present in the coastal waters of the Seine bay (1.2.-1.3.). (author).

  13. Using Hairy Roots for Production of Valuable Plant Secondary Metabolites.

    Science.gov (United States)

    Tian, Li

    2015-01-01

    Plants synthesize a wide variety of natural products, which are traditionally termed secondary metabolites and, more recently, coined specialized metabolites. While these chemical compounds are employed by plants for interactions with their environment, humans have long since explored and exploited plant secondary metabolites for medicinal and practical uses. Due to the tissue-specific and low-abundance accumulation of these metabolites, alternative means of production in systems other than intact plants are sought after. To this end, hairy root culture presents an excellent platform for producing valuable secondary metabolites. This chapter will focus on several major groups of secondary metabolites that are manufactured by hairy roots established from different plant species. Additionally, the methods for preservations of hairy roots will also be reviewed.

  14. Plant diversity surpasses plant functional groups and plant productivity as driver of soil biota in the long term.

    Directory of Open Access Journals (Sweden)

    Nico Eisenhauer

    Full Text Available BACKGROUND: One of the most significant consequences of contemporary global change is the rapid decline of biodiversity in many ecosystems. Knowledge of the consequences of biodiversity loss in terrestrial ecosystems is largely restricted to single ecosystem functions. Impacts of key plant functional groups on soil biota are considered to be more important than those of plant diversity; however, current knowledge mainly relies on short-term experiments. METHODOLOGY/PRINCIPAL FINDINGS: We studied changes in the impacts of plant diversity and presence of key functional groups on soil biota by investigating the performance of soil microorganisms and soil fauna two, four and six years after the establishment of model grasslands. The results indicate that temporal changes of plant community effects depend on the trophic affiliation of soil animals: plant diversity effects on decomposers only occurred after six years, changed little in herbivores, but occurred in predators after two years. The results suggest that plant diversity, in terms of species and functional group richness, is the most important plant community property affecting soil biota, exceeding the relevance of plant above- and belowground productivity and the presence of key plant functional groups, i.e. grasses and legumes, with the relevance of the latter decreasing in time. CONCLUSIONS/SIGNIFICANCE: Plant diversity effects on biota are not only due to the presence of key plant functional groups or plant productivity highlighting the importance of diverse and high-quality plant derived resources, and supporting the validity of the singular hypothesis for soil biota. Our results demonstrate that in the long term plant diversity essentially drives the performance of soil biota questioning the paradigm that belowground communities are not affected by plant diversity and reinforcing the importance of biodiversity for ecosystem functioning.

  15. Plant Diversity Surpasses Plant Functional Groups and Plant Productivity as Driver of Soil Biota in the Long Term

    Science.gov (United States)

    Eisenhauer, Nico; Milcu, Alexandru; Sabais, Alexander C. W.; Bessler, Holger; Brenner, Johanna; Engels, Christof; Klarner, Bernhard; Maraun, Mark; Partsch, Stephan; Roscher, Christiane; Schonert, Felix; Temperton, Vicky M.; Thomisch, Karolin; Weigelt, Alexandra; Weisser, Wolfgang W.; Scheu, Stefan

    2011-01-01

    Background One of the most significant consequences of contemporary global change is the rapid decline of biodiversity in many ecosystems. Knowledge of the consequences of biodiversity loss in terrestrial ecosystems is largely restricted to single ecosystem functions. Impacts of key plant functional groups on soil biota are considered to be more important than those of plant diversity; however, current knowledge mainly relies on short-term experiments. Methodology/Principal Findings We studied changes in the impacts of plant diversity and presence of key functional groups on soil biota by investigating the performance of soil microorganisms and soil fauna two, four and six years after the establishment of model grasslands. The results indicate that temporal changes of plant community effects depend on the trophic affiliation of soil animals: plant diversity effects on decomposers only occurred after six years, changed little in herbivores, but occurred in predators after two years. The results suggest that plant diversity, in terms of species and functional group richness, is the most important plant community property affecting soil biota, exceeding the relevance of plant above- and belowground productivity and the presence of key plant functional groups, i.e. grasses and legumes, with the relevance of the latter decreasing in time. Conclusions/Significance Plant diversity effects on biota are not only due to the presence of key plant functional groups or plant productivity highlighting the importance of diverse and high-quality plant derived resources, and supporting the validity of the singular hypothesis for soil biota. Our results demonstrate that in the long term plant diversity essentially drives the performance of soil biota questioning the paradigm that belowground communities are not affected by plant diversity and reinforcing the importance of biodiversity for ecosystem functioning. PMID:21249208

  16. Separation of Plutonium from Irradiated Fuels and Targets

    Energy Technology Data Exchange (ETDEWEB)

    Gray, Leonard W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Holliday, Kiel S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Murray, Alice [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Thompson, Major [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Thorp, Donald T. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Yarbro, Stephen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Venetz, Theodore J. [Hanford Site, Benton County, WA (United States)

    2015-09-30

    Spent nuclear fuel from power production reactors contains moderate amounts of transuranium (TRU) actinides and fission products in addition to the still slightly enriched uranium. Originally, nuclear technology was developed to chemically separate and recover fissionable plutonium from irradiated nuclear fuel for military purposes. Military plutonium separations had essentially ceased by the mid-1990s. Reprocessing, however, can serve multiple purposes, and the relative importance has changed over time. In the 1960’s the vision of the introduction of plutonium-fueled fast-neutron breeder reactors drove the civilian separation of plutonium. More recently, reprocessing has been regarded as a means to facilitate the disposal of high-level nuclear waste, and thus requires development of radically different technical approaches. In the last decade or so, the principal reason for reprocessing has shifted to spent power reactor fuel being reprocessed (1) so that unused uranium and plutonium being recycled reduce the volume, gaining some 25% to 30% more energy from the original uranium in the process and thus contributing to energy security and (2) to reduce the volume and radioactivity of the waste by recovering all long-lived actinides and fission products followed by recycling them in fast reactors where they are transmuted to short-lived fission products; this reduces the volume to about 20%, reduces the long-term radioactivity level in the high-level waste, and complicates the possibility of the plutonium being diverted from civil use – thereby increasing the proliferation resistance of the fuel cycle. In general, reprocessing schemes can be divided into two large categories: aqueous/hydrometallurgical systems, and pyrochemical/pyrometallurgical systems. Worldwide processing schemes are dominated by the aqueous (hydrometallurgical) systems. This document provides a historical review of both categories of reprocessing.

  17. Plant-Derived Natural Products for Parkinson's Disease Therapy.

    Science.gov (United States)

    Sengupta, T; Vinayagam, J; Singh, R; Jaisankar, P; Mohanakumar, K P

    2016-01-01

    Plant-derived natural products have made their own niche in the treatment of neurological diseases since time immemorial. Parkinson's disease (PD), the second most prevalent neurodegenerative disorder, has no cure and the treatment available currently is symptomatic. This chapter thoughtfully and objectively assesses the scientific basis that supports the increasing use of these plant-derived natural products for the treatment of this chronic and progressive disorder. Proper considerations are made on the chemical nature, sources, preclinical tests and their validity, and mechanisms of behavioural or biochemical recovery observed following treatment with various plants derived natural products relevant to PD therapy. The scientific basis underlying the neuroprotective effect of 6 Ayurvedic herbs/formulations, 12 Chinese medicinal herbs/formulations, 33 other plants, and 5 plant-derived molecules have been judiciously examined emphasizing behavioral, cellular, or biochemical aspects of neuroprotection observed in the cellular or animal models of the disease. The molecular mechanisms triggered by these natural products to promote cell survivability and to reduce the risk of cellular degeneration have also been brought to light in this study. The study helped to reveal certain limitations in the scenario: lack of preclinical studies in all cases barring two; heavy dependence on in vitro test systems; singular animal or cellular model to establish any therapeutic potential of drugs. This strongly warrants further studies so as to reproduce and confirm these reported effects. However, the current literature offers scientific credence to traditionally used plant-derived natural products for the treatment of PD.

  18. Production of Virus-free Carnation Plants through Heat Therapy

    Directory of Open Access Journals (Sweden)

    Manisha Mangal

    2004-01-01

    Full Text Available The effect of exposure of carnation plants infected with carnation, latent virus (CLV to two temperature regimes (35 + 2 "C and 40 +2 "C for different periods (1 to 4 weeks revealed thatthe exposure to different temperatures for different periods has a negative correlation with the survival of plants. Whereas only 33.33 per cent plants survived after 4 weeks at 35 + 2 "C, the plants when exposed to 40+ 2 "C for the same period could not tolerate the heat shock. However, only those plants which were exposed to 35 + 2 "C for 4 weeks and those exposed to 40 + 2 "C for 3 weeks were free from CLV. However, because of better survival rate, the higher temperature regime of 40 + 2 "C is recommended for production of virus-tested carnation plants.

  19. Measurement of plutonium in spent nuclear fuel by self-induced x-ray fluorescence

    Energy Technology Data Exchange (ETDEWEB)

    Hoover, Andrew S [Los Alamos National Laboratory; Rudy, Cliff R [Los Alamos National Laboratory; Tobin, Steve J [Los Alamos National Laboratory; Charlton, William S [Los Alamos National Laboratory; Stafford, A [TEXAS A& M; Strohmeyer, D [TEXAS A& M; Saavadra, S [ORNL

    2009-01-01

    Direct measurement of the plutonium content in spent nuclear fuel is a challenging problem in non-destructive assay. The very high gamma-ray flux from fission product isotopes overwhelms the weaker gamma-ray emissions from plutonium and uranium, making passive gamma-ray measurements impossible. However, the intense fission product radiation is effective at exciting plutonium and uranium atoms, resulting in subsequent fluorescence X-ray emission. K-shell X-rays in the 100 keV energy range can escape the fuel and cladding, providing a direct signal from uranium and plutonium that can be measured with a standard germanium detector. The measured plutonium to uranium elemental ratio can be used to compute the plutonium content of the fuel. The technique can potentially provide a passive, non-destructive assay tool for determining plutonium content in spent fuel. In this paper, we discuss recent non-destructive measurements of plutonium X-ray fluorescence (XRF) signatures from pressurized water reactor spent fuel rods. We also discuss how emerging new technologies, like very high energy resolution microcalorimeter detectors, might be applied to XRF measurements.

  20. Concepts in production ecology for analysis and design of animal and plant-animal production systems

    NARCIS (Netherlands)

    Ven, van de G.W.J.; Ridder, de N.; Keulen, van H.; Ittersum, van M.K.

    2003-01-01

    The use of a hierarchy in growth factors (defining, limiting and reducing growth factors), as developed for plant production has shown its usefulness in the analysis and design of plant production systems. This hierarchy presents a theoretical framework for the analysis of biophysical conditions in

  1. Capabilities for managing high-volume production of electric engineering equipment at the Electrochemical Production Plant

    Energy Technology Data Exchange (ETDEWEB)

    Podlednev, V.M.

    1996-04-01

    The Electromechanical Production Plant is essentially a research center with experimental facilities and power full testing base. Major products of the plant today include heat pipes and devices of their basis of different functions and power from high temperature ranges to cryogenics. This report describes work on porous titanium and carbon-graphite current collectors, electrocatalyst synthesis, and electrocatalyst applications.

  2. Fertiliser products from biogas plants; Biokaasulaitosten lopputuotteet lannoitevalmisteina

    Energy Technology Data Exchange (ETDEWEB)

    Marttinen, S.; Paavola, T.; Ervasti, S. [and others

    2013-02-01

    The use of end-products from biogas plants was studied from the perspective of plant nutrition and agriculture. The tasks included development of generally applicable methods for determining nitrogen and phosphorus in different fertiliser products in order to predict their fertiliser effect. The degradation of the products in soil was also studied. The work included both laboratory and field scale experiments. Additionally, the stability and possible phytotoxicity of the products was studied. The content of harmful contaminants and microbiological risks of the products were determined. The aim was to offer information on the characteristics and usability of the products for producers and users of the products and for supervising officials. Of the analysis methods tested, 1:60 water extraction was the best general method to describe the content of soluble, plant-available nitrogen in different organic fertiliser products. In liquid fertiliser products, nitrogen is more readily available for plants than in solid products and the fertilising effect is comparable to that of mineral fertilisers. The fertilising effect of solid organic fertiliser products is somewhat lower than that of mineral fertilisers due to surface application and mixing into the cultivation layer. This results in lower plant-availability than with mineral fertilisers which are injected into soil. Solid products contain significant amounts of total phosphorus, the solubility of which is low. As it may be solubilised over long periods of time, the 1:5 water extraction required by the current Finnish legislation of fertiliser products underestimates the usability of phosphorus. Due to the more sensitive yield response of organic fertiliser products to changes in conditions, as opposed to mineral fertilisers, it is also recommended to use an application strategy in which part of the soluble nitrogen originates from organic fertilisers and part from mineral fertilisers. Also due to legislative

  3. Biodiversity influences plant productivity through niche-efficiency.

    Science.gov (United States)

    Liang, Jingjing; Zhou, Mo; Tobin, Patrick C; McGuire, A David; Reich, Peter B

    2015-05-05

    The loss of biodiversity is threatening ecosystem productivity and services worldwide, spurring efforts to quantify its effects on the functioning of natural ecosystems. Previous research has focused on the positive role of biodiversity on resource acquisition (i.e., niche complementarity), but a lack of study on resource utilization efficiency, a link between resource and productivity, has rendered it difficult to quantify the biodiversity-ecosystem functioning relationship. Here we demonstrate that biodiversity loss reduces plant productivity, other things held constant, through theory, empirical evidence, and simulations under gradually relaxed assumptions. We developed a theoretical model named niche-efficiency to integrate niche complementarity and a heretofore-ignored mechanism of diminishing marginal productivity in quantifying the effects of biodiversity loss on plant productivity. Based on niche-efficiency, we created a relative productivity metric and a productivity impact index (PII) to assist in biological conservation and resource management. Relative productivity provides a standardized measure of the influence of biodiversity on individual productivity, and PII is a functionally based taxonomic index to assess individual species' inherent value in maintaining current ecosystem productivity. Empirical evidence from the Alaska boreal forest suggests that every 1% reduction in overall plant diversity could render an average of 0.23% decline in individual tree productivity. Out of the 283 plant species of the region, we found that large woody plants generally have greater PII values than other species. This theoretical model would facilitate the integration of biological conservation in the international campaign against several pressing global issues involving energy use, climate change, and poverty.

  4. Earthworms increase plant production: a meta- analysis

    NARCIS (Netherlands)

    Groenigen, van J.W.; Lubbers, I.M.; Vos, H.M.J.; Brown, G.G.; Deyn, de G.B.; Groenigen, van K.J.

    2014-01-01

    To meet the challenge of feeding a growing world population with minimal environmental impact, we need comprehensive and quantitative knowledge of ecological factors affecting crop production. Earthworms are among the most important soil dwelling invertebrates. Their activity affects both biotic and

  5. Convergence of terrestrial plant production across global climate gradients.

    Science.gov (United States)

    Michaletz, Sean T; Cheng, Dongliang; Kerkhoff, Andrew J; Enquist, Brian J

    2014-08-07

    Variation in terrestrial net primary production (NPP) with climate is thought to originate from a direct influence of temperature and precipitation on plant metabolism. However, variation in NPP may also result from an indirect influence of climate by means of plant age, stand biomass, growing season length and local adaptation. To identify the relative importance of direct and indirect climate effects, we extend metabolic scaling theory to link hypothesized climate influences with NPP, and assess hypothesized relationships using a global compilation of ecosystem woody plant biomass and production data. Notably, age and biomass explained most of the variation in production whereas temperature and precipitation explained almost none, suggesting that climate indirectly (not directly) influences production. Furthermore, our theory shows that variation in NPP is characterized by a common scaling relationship, suggesting that global change models can incorporate the mechanisms governing this relationship to improve predictions of future ecosystem function.

  6. Technical report for the generic site add-on facility for plutonium polishing

    Energy Technology Data Exchange (ETDEWEB)

    Collins, E. D.

    1998-06-01

    The purpose of this report is to provide environmental data and reference process information associated with incorporating plutonium polishing steps (dissolution, impurity removal, and conversion to oxide powder) into the genetic-site Mixed-Oxide Fuel Fabrication Facility (MOXFF). The incorporation of the plutonium polishing steps will enable the removal of undesirable impurities, such as gallium and americium, known to be associated with the plutonium. Moreover, unanticipated impurities can be removed, including those that may be contained in (1) poorly characterized feed materials, (2) corrosion products added from processing equipment, and (3) miscellaneous materials contained in scrap recycle streams. These impurities will be removed to the extent necessary to meet plutonium product purity specifications for MOX fuels. Incorporation of the plutonium polishing steps will mean that the Pit Disassembly and Conversion Facility (PDCF) will need to produce a plutonium product that can b e dissolved at the MOXFF in nitric acid at a suitable rate (sufficient to meet overall production requirements) with the minimal usage of hydrofluoric acid, and its complexing agent, aluminum nitrate. This function will require that if the PDCF product is plutonium oxide powder, that powder must be produced, stored, and shipped without exceeding a temperature of 600 C.

  7. Development of Remote Plutonium Valence State Analyzer

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>In the Purex process of spent fuel reprocessing, the separation of uranium and plutonium depends on the capability extracting state plutonium ions with various valence by TBP. The separate degree of

  8. Plutonium focus area

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-08-01

    To ensure research and development programs focus on the most pressing environmental restoration and waste management problems at the U.S. Department of Energy (DOE), the Assistant Secretary for the Office of Environmental Management (EM) established a working group in August 1993 to implement a new approach to research and technology development. As part of this new approach, EM developed a management structure and principles that led to the creation of specific Focus Areas. These organizations were designed to focus the scientific and technical talent throughout DOE and the national scientific community on the major environmental restoration and waste management problems facing DOE. The Focus Area approach provides the framework for intersite cooperation and leveraging of resources on common problems. After the original establishment of five major Focus Areas within the Office of Technology Development (EM-50, now called the Office of Science and Technology), the Nuclear Materials Stabilization Task Group (EM-66) followed the structure already in place in EM-50 and chartered the Plutonium Focus Area (PFA). The following information outlines the scope and mission of the EM, EM-60, and EM-66 organizations as related to the PFA organizational structure.

  9. Modelling energy consumption in a manufacturing plant using productivity KPIs

    Energy Technology Data Exchange (ETDEWEB)

    Gallachoir, Brian O.; Cahill, Caiman (Sustainable Energy Research Group, Dept. of Civil and Environmental Engineering, Univ. College Cork (Ireland))

    2009-07-01

    Energy efficiency initiatives in industrial plants are often focused on getting energy-consuming utilities and devices to operate more efficiently, or on conserving energy. While such device-oriented energy efficiency measures can achieve considerable savings, greater energy efficiency improvement may be achieved by improving the overall productivity and quality of manufacturing processes. The paper highlights the observed relationship between productivity and energy efficiency using aggregated data on unit consumption and production index data for Irish industry. Past studies have developed simple top-down models of final energy consumption in manufacturing plants using energy consumption and production output figures, but these models do not help identify opportunities for energy savings that could achieved through increased productivity. This paper proposes an improved and innovative method of modelling plant final energy demand that introduces standard productivity Key Performance Indicators (KPIs) into the model. The model demonstrates the relationship between energy consumption and productivity, and uses standard productivity metrics to identify the areas of manufacturing activity that offer the most potential for improved energy efficiency. The model provides a means of comparing the effect of device-oriented energy efficiency measures with the potential for improved energy efficiency through increased productivity.

  10. HB-Line Plutonium Oxide Data Collection Strategy

    Energy Technology Data Exchange (ETDEWEB)

    Watkins, R. [Savannah River Nuclear Solutions; Varble, J. [Savannah River Nuclear Solutions; Jordan, J. [Savannah River Nuclear Solutions

    2015-05-26

    HB-Line and H-Canyon will handle and process plutonium material to produce plutonium oxide for feed to the Mixed Oxide Fuel Fabrication Facility (MFFF). However, the plutonium oxide product will not be transferred to the MFFF directly from HB-Line until it is packaged into a qualified DOE-STD-3013-2012 container. In the interim, HB-Line will load plutonium oxide into an inner, filtered can. The inner can will be placed in a filtered bag, which will be loaded into a filtered outer can. The outer can will be loaded into a certified 9975 with getter assembly in compliance with onsite transportation requirement, for subsequent storage and transfer to the K-Area Complex (KAC). After DOE-STD-3013-2012 container packaging capabilities are established, the product will be returned to HB-Line to be packaged into a qualified DOE-STD-3013-2012 container. To support the transfer of plutonium oxide to KAC and then eventually to MFFF, various material and packaging data will have to be collected and retained. In addition, data from initial HB-Line processing operations will be needed to support future DOE-STD-3013-2012 qualification as amended by the HB-Line DOE Standard equivalency. As production increases, the volume of data to collect will increase. The HB-Line data collected will be in the form of paper copies and electronic media. Paper copy data will, at a minimum, consist of facility procedures, nonconformance reports (NCRs), and DCS print outs. Electronic data will be in the form of Adobe portable document formats (PDFs). Collecting all the required data for each plutonium oxide can will be no small effort for HB-Line, and will become more challenging once the maximum annual oxide production throughput is achieved due to the sheer volume of data to be collected. The majority of the data collected will be in the form of facility procedures, DCS print outs, and laboratory results. To facilitate complete collection of this data, a traveler form will be developed which

  11. Conceptual design report, plutonium stabilization and handling,project W-460

    Energy Technology Data Exchange (ETDEWEB)

    Weiss, E.V.

    1997-03-06

    Project W-460, Plutonium Stabilization and Handling, encompasses procurement and installation of a Stabilization and Packaging System (SPS) to oxidize and package for long term storage remaining plutonium-bearing special nuclear materials currently in inventory at the Plutonium Finishing Plant (PFP), and modification of vault equipment to allow storage of resulting packages of stabilized SNM for up to fifty years. This Conceptual Design Report (CDR) provides conceptual design details for the vault modification, site preparation and site interface with the purchased SPS. Two concepts are described for vault configuration; acceleration of this phase of the project did not allow completion of analysis which would clearly identify a preferred approach.

  12. The role of troublesome components in plutonium vitrification

    Energy Technology Data Exchange (ETDEWEB)

    Li, Hong; Vienna, J.D.; Peeler, D.K.; Hrma, P.; Schweiger, M.J. [Pacific Northwest National Lab., Richland, WA (United States)

    1996-05-01

    One option for immobilizing surplus plutonium is vitrification in a borosilicate glass. Two advantages of the glass form are (1) high tolerance to feed variability and, (2) high solubility of some impurity components. The types of plutonium-containing materials in the United States inventory include: pits, metals, oxides, residues, scrap, compounds, and fuel. Many of them also contain high concentrations of carbon, chloride, fluoride, phosphate, sulfate, and chromium oxide. To vitrify plutonium-containing scrap and residues, it is critical to understand the impact of each component on glass processing and chemical durability of the final product. This paper addresses glass processing issues associated with these troublesome components. It covers solubility limits of chlorine, fluorine, phosphate, sulfate, and chromium oxide in several borosilicate based glasses, and the effect of each component on vitrification (volatility, phase segregation, crystallization, and melt viscosity). Techniques (formulation, pretreatment, removal, and/or dilution) to mitigate the effect of these troublesome components are suggested.

  13. Automated production of plant-based vaccines and pharmaceuticals.

    Science.gov (United States)

    Wirz, Holger; Sauer-Budge, Alexis F; Briggs, John; Sharpe, Aaron; Shu, Sudong; Sharon, Andre

    2012-12-01

    A fully automated "factory" was developed that uses tobacco plants to produce large quantities of vaccines and other therapeutic biologics within weeks. This first-of-a-kind factory takes advantage of a plant viral vector technology to produce specific proteins within the leaves of rapidly growing plant biomass. The factory's custom-designed robotic machines plant seeds, nurture the growing plants, introduce a viral vector that directs the plant to produce a target protein, and harvest the biomass once the target protein has accumulated in the plants-all in compliance with Food and Drug Administration (FDA) guidelines (e.g., current Good Manufacturing Practices). The factory was designed to be time, cost, and space efficient. The plants are grown in custom multiplant trays. Robots ride up and down a track, servicing the plants and delivering the trays from the lighted, irrigated growth modules to each processing station as needed. Using preprogrammed robots and processing equipment eliminates the need for human contact, preventing potential contamination of the process and economizing the operation. To quickly produce large quantities of protein-based medicines, we transformed a laboratory-based biological process and scaled it into an industrial process. This enables quick, safe, and cost-effective vaccine production that would be required in case of a pandemic.

  14. A mechanism for plutonium pyrophoricity

    Science.gov (United States)

    Martz, Joseph C.; Haschke, John M.; Stakebake, Jerry L.

    1994-06-01

    A proposed mechanism for plutonium pyrophoricity quantitatively predicts the ignition temperature of plutonium as a function of surface : mass ratio and particle size. Plutonium must exceed 475°C before self-ignition occurs. External heating of massive samples is necessary to achieve this condition, while finely divided materials can reach the ignition point by an alternative, two-step mechanism. First, the thin layer of surface PuO 2 on the metal undergoes kinetically controlled reduction to Pu 2O 3 near 150°C. Second, the trivalent Pu 2O 3 reacts with gas-phase oxygen to reform PuO 2. Heat generated from the second reaction is sufficient to raise the temperature of small particles or thin foils above the 475°C ignition point. Details of this mechanism are given, including a discussion of plutonium oxidation and a calculation of adiabatic temperature increase due to oxidation of the Pu 2O 3 surface layer. Plutonium pyrophoricity data are summarized and compared to model results.

  15. Zone refining of plutonium metal

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    The purpose of this study was to investigate zone refining techniques for the purification of plutonium metal. The redistribution of 10 impurity elements from zone melting was examined. Four tantalum boats were loaded with plutonium impurity alloy, placed in a vacuum furnace, heated to 700{degrees}C, and held at temperature for one hour. Ten passes were made with each boat. Metallographic and chemical analyses performed on the plutonium rods showed that, after 10 passes, moderate movement of certain elements were achieved. Molten zone speeds of 1 or 2 inches per hour had no effect on impurity element movement. Likewise, the application of constant or variable power had no effect on impurity movement. The study implies that development of a zone refining process to purify plutonium is feasible. Development of a process will be hampered by two factors: (1) the effect on impurity element redistribution of the oxide layer formed on the exposed surface of the material is not understood, and (2) the tantalum container material is not inert in the presence of plutonium. Cold boat studies are planned, with higher temperature and vacuum levels, to determine the effect on these factors. 5 refs., 1 tab., 5 figs.

  16. From separations to reconstitution - a short history of Plutonium in the U.S. and Russia

    Energy Technology Data Exchange (ETDEWEB)

    Gray, L W

    1999-04-15

    During the cold war plutonium was produced in reactors in both the US and Russia. It was then separated from the residual uranium and fission products by a variety of precipitation processes, such as Bismuth Phosphate, Redox, Butex, Purex, etc. in the US and uranium acetate and Purex in Russia. After a period of time in the field, plutonium weapons were recycled and the plutonium re-purified and returned to weapons. purification was accomplished by a variety of aqueous and molten salt processes, such as nitric-hydrofluoric acid dissolution followed by anion exchange, Purex modifications, molten salt extraction, electrorefining, etc. in the US and nitric acid dissolution or sodium hydroxide fusion followed by anion exchange in Russia. At the end of the Cold War, plutonium production of weapons-grade plutonium was cut off in the US and is expected to be cut off in Russia shortly after the turn of the century. Now both countries are looking at methods to reconstitute plutonium with fission products to render it no longer useful for nuclear weapons. These methods include immobilization in a ceramic matrix and then encasement in fission product laden glass, irradiation of MOX fuel, and disposal as waste in WIPP in the US and irradiation of MOX fuel in Russia. This paper details the contrast between the treatment of plutonium during the cold war and after the cold war was over.

  17. DOE Plutonium Disposition Study: Pu consumption in ALWRs. Volume 1, Final report

    Energy Technology Data Exchange (ETDEWEB)

    1993-05-15

    The Department of Energy (DOE) has contracted with Asea Brown Boveri-Combustion Engineering (ABB-CE) to provide information on the capability of ABB-CE`s System 80 + Advanced Light Water Reactor (ALWR) to transform, through reactor burnup, 100 metric tonnes (MT) of weapons grade plutonium (Pu) into a form which is not readily useable in weapons. This information is being developed as part of DOE`s Plutonium Disposition Study, initiated by DOE in response to Congressional action. This document, Volume 1, presents a technical description of the various elements of the System 80 + Standard Plant Design upon which the Plutonium Disposition Study was based. The System 80 + Standard Design is fully developed and directly suited to meeting the mission objectives for plutonium disposal. The bass U0{sub 2} plant design is discussed here.

  18. Gene Delivery into Plant Cells for Recombinant Protein Production

    Directory of Open Access Journals (Sweden)

    Qiang Chen

    2015-01-01

    Full Text Available Recombinant proteins are primarily produced from cultures of mammalian, insect, and bacteria cells. In recent years, the development of deconstructed virus-based vectors has allowed plants to become a viable platform for recombinant protein production, with advantages in versatility, speed, cost, scalability, and safety over the current production paradigms. In this paper, we review the recent progress in the methodology of agroinfiltration, a solution to overcome the challenge of transgene delivery into plant cells for large-scale manufacturing of recombinant proteins. General gene delivery methodologies in plants are first summarized, followed by extensive discussion on the application and scalability of each agroinfiltration method. New development of a spray-based agroinfiltration and its application on field-grown plants is highlighted. The discussion of agroinfiltration vectors focuses on their applications for producing complex and heteromultimeric proteins and is updated with the development of bridge vectors. Progress on agroinfiltration in Nicotiana and non-Nicotiana plant hosts is subsequently showcased in context of their applications for producing high-value human biologics and low-cost and high-volume industrial enzymes. These new advancements in agroinfiltration greatly enhance the robustness and scalability of transgene delivery in plants, facilitating the adoption of plant transient expression systems for manufacturing recombinant proteins with a broad range of applications.

  19. 49 CFR 175.704 - Plutonium shipments.

    Science.gov (United States)

    2010-10-01

    ... Regulations Applicable According to Classification of Material § 175.704 Plutonium shipments. Shipments of plutonium which are subject to 10 CFR 71.88(a)(4) must comply with the following: (a) Each package... 49 Transportation 2 2010-10-01 2010-10-01 false Plutonium shipments. 175.704 Section...

  20. Control of Listeria monocytogenes in food production plants

    Directory of Open Access Journals (Sweden)

    Dimitrijević Mirjana

    2008-01-01

    Full Text Available L. monocytogenes has been established in different plants for the production of food, including dairy plants, abattoirs, plants for the processing of fish, as well as those for the production of ready-to-eat (RTE food and this fact is being considered as the primary mechanism of food contamination with this bacteria. There is also the factor of numerous and diverse contaminated production equipment, because it has certain parts that are inaccessible for the necessary cleaning and disinfection. The temperature, position, as well as the material of the work surface are also linked to the contamination of plants with this bacteria. Investigations carried out so far have helped toward the better understanding of the manner and time of contamination of food items in the course of the production process, but there are still unresolved problems, including most certainly the biggest one - the adherence of bacteria and the creation of a biofilm, when the bacteria is in that condition more resistant to so-called stress factors which are usually used in the food industry for the purpose of decontamination of the surfaces with which foods come into contact. The control of L. monocytogenes in food production plants is possible primarily by using an integrated programme, compatible with the systems Hazard Analysis Critical Control Point (HACCP and Good Hygiene Practice (GHP, necessary in the production of food that is safe for the consumer. Essentially, the control measures that can contribute to reducing the incidence of findings of L.monocytogenes in the finished product, as well as the reducing of the level of contamination with this bacteria are linked, on the one hand, with hygiene procedures in the production process, and, on the other, with the applied technological procedures.

  1. Existing large steam power plant upgraded for hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Galanti, L.; Franzoni, A.; Traverso, A.; Massardo, A.F. [University of Genoa, Genoa (Italy)

    2011-05-15

    This paper presents and discusses the results of a complete thermoeconomic analysis of an integrated power plant for co-production of electricity and hydrogen via pyrolysis and gasification processes fed by various coals and mixture of coal and biomass, applied to an existing large steam power plant (ENEL Brindisi power plant - 660 MWe). Two different technologies for the syngas production section are considered: pyrolysis process and direct pressurized gasification. Moreover, the proximity of a hydrogen production and purification plants to an existing steam power plant favors the inter-exchange of energy streams, mainly in the form of hot water and steam, which reduces the costs of auxiliary equipment. The high quality of the hydrogen would guarantee its usability for distributed generation and for public transport. The results were obtained using WTEMP thermoeconomic software, developed by the Thermochemical Power Group of the University of Genoa, and this project has been carried out within the framework of the FISR National project 'Integrated systems for hydrogen production and utilization in distributed power generation'.

  2. Root traits contributing to plant productivity under drought

    Directory of Open Access Journals (Sweden)

    Louise eComas

    2013-11-01

    Full Text Available Geneticists and breeders are positioned to breed plants with root traits that improve productivity under drought. However, a better understanding of root functional traits and how traits are related to whole plant strategies to increase crop productivity under different drought conditions is needed. Root traits associated with maintaining plant productivity under drought include small fine root diameters, long specific root length (SRL, and considerable root length density, especially at depths in soil with available water. In environments with late season water deficits, small xylem diameters in targeted seminal roots save soil water deep in the soil profile for use during crop maturation and result in improved yields. Capacity for deep root growth and large xylem diameters in deep roots may also improve root acquisition of water when ample water at depth is available. Xylem pit anatomy that makes xylem less ‘leaky’ and prone to cavitation warrants further exploration holding promise that such traits may improve plant productivity in water-limited environments without negatively impacting yield under adequate water conditions. Rapid resumption of root growth following soil rewetting may improve plant productivity under episodic drought. Genetic control of many of these traits through breeding appears feasible. Several recent reviews have covered methods for screening root traits but an appreciation for the complexity of root systems (e.g. functional differences between fine and coarse roots needs to be paired with these methods to successfully identify relevant traits for crop improvement. Screening of root traits at early stages in plant development can proxy traits at mature stages but verification is needed on a case by case basis that traits are linked to increased crop productivity under drought. Examples in lesquerella (Physaria and rice (Oryza show approaches to phenotyping of root traits and current understanding of root trait

  3. Root traits contributing to plant productivity under drought.

    Science.gov (United States)

    Comas, Louise H; Becker, Steven R; Cruz, Von Mark V; Byrne, Patrick F; Dierig, David A

    2013-11-05

    Geneticists and breeders are positioned to breed plants with root traits that improve productivity under drought. However, a better understanding of root functional traits and how traits are related to whole plant strategies to increase crop productivity under different drought conditions is needed. Root traits associated with maintaining plant productivity under drought include small fine root diameters, long specific root length, and considerable root length density, especially at depths in soil with available water. In environments with late season water deficits, small xylem diameters in targeted seminal roots save soil water deep in the soil profile for use during crop maturation and result in improved yields. Capacity for deep root growth and large xylem diameters in deep roots may also improve root acquisition of water when ample water at depth is available. Xylem pit anatomy that makes xylem less "leaky" and prone to cavitation warrants further exploration holding promise that such traits may improve plant productivity in water-limited environments without negatively impacting yield under adequate water conditions. Rapid resumption of root growth following soil rewetting may improve plant productivity under episodic drought. Genetic control of many of these traits through breeding appears feasible. Several recent reviews have covered methods for screening root traits but an appreciation for the complexity of root systems (e.g., functional differences between fine and coarse roots) needs to be paired with these methods to successfully identify relevant traits for crop improvement. Screening of root traits at early stages in plant development can proxy traits at mature stages but verification is needed on a case by case basis that traits are linked to increased crop productivity under drought. Examples in lesquerella (Physaria) and rice (Oryza) show approaches to phenotyping of root traits and current understanding of root trait genetics for breeding.

  4. Process simulation and economical evaluation of enzymatic biodiesel production plant.

    Science.gov (United States)

    Sotoft, Lene Fjerbaek; Rong, Ben-Guang; Christensen, Knud V; Norddahl, Birgir

    2010-07-01

    Process simulation and economical evaluation of an enzymatic biodiesel production plant has been carried out. Enzymatic biodiesel production from high quality rapeseed oil and methanol has been investigated for solvent free and cosolvent production processes. Several scenarios have been investigated with different production scales (8 and 200 mio. kg biodiesel/year) and enzyme price. The cosolvent production process is found to be most expensive and is not a viable choice, while the solvent free process is viable for the larger scale production of 200 mio. kg biodiesel/year with the current enzyme price. With the suggested enzyme price of the future, both the small and large scale solvent free production proved viable. The product price was estimated to be 0.73-1.49 euro/kg biodiesel with the current enzyme price and 0.05-0.75 euro/kg with the enzyme price of the future for solvent free process.

  5. Graphical analysis of French nuclear power plant production date

    Energy Technology Data Exchange (ETDEWEB)

    Jourdan, J.P. [Electricite de France (EDF), Projet Production EPR 1, 93 - Saint-Denis (France)

    2001-07-01

    The analysis of values of plant production uses here an original method of graphical analysis. This method clarifies various difficulties of analysing big experience feedback databases among which the language interpretation and distinctions between scarce events and multi-annual events. In general, the method shows the logical processes that production values obey (pure chance logic, administrative logic, and willpower) This method of graphical analysis provides a tool to observe and question in a concrete way so that each person involved can put the events in which he played a role into the general context of other plants. It is a deductible method to improve this big and complex system. (author)

  6. Water use, productivity and interactions among desert plants

    Energy Technology Data Exchange (ETDEWEB)

    Ehleringer, J.R.

    1992-11-17

    Productivity, stability, and competitive interactions among ecosystem components within aridlands are key processes related directly to water in deserts. This project assumes that integrated aspects of plant metabolism provide insight into the structure and function of plant communities and ecosystems. While it is difficult to extrapolate from instantaneous physiological observations to higher scales, such as whole plant performance or to the interactions between plants as components of ecosystems, several key aspects of plant metabolism are scalable. Analyses of stable isotopic composition in plant tissues at natural abundance levels provide a useful tool that can provide insight into the consequences of physiological processes over temporal and spatial scales. Some plant processes continuously fractionate among light and heavy stable isotopic forms of an element; over time this results in integrated measures of plant metabolism. For example, carbon isotope fractionation during photosynthesis results in leaf carbon isotopic composition that is a measure of the set-point for photosynthetic metabolism and of water-use efficiency. Thus it provides information on the temporal scaling of a key physiological process.

  7. Water use, productivity and interactions among desert plants. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Ehleringer, J.R.

    1992-11-17

    Productivity, stability, and competitive interactions among ecosystem components within aridlands are key processes related directly to water in deserts. This project assumes that integrated aspects of plant metabolism provide insight into the structure and function of plant communities and ecosystems. While it is difficult to extrapolate from instantaneous physiological observations to higher scales, such as whole plant performance or to the interactions between plants as components of ecosystems, several key aspects of plant metabolism are scalable. Analyses of stable isotopic composition in plant tissues at natural abundance levels provide a useful tool that can provide insight into the consequences of physiological processes over temporal and spatial scales. Some plant processes continuously fractionate among light and heavy stable isotopic forms of an element; over time this results in integrated measures of plant metabolism. For example, carbon isotope fractionation during photosynthesis results in leaf carbon isotopic composition that is a measure of the set-point for photosynthetic metabolism and of water-use efficiency. Thus it provides information on the temporal scaling of a key physiological process.

  8. INFLUENCE OF VITAMIN MORPHOGENESIS REGENERATED PLANTS POTATO IN VITRO TO INTENSIFY PRODUCTION OF ELITE PLANTING MATERIAL

    Directory of Open Access Journals (Sweden)

    E. P. Miakisheva

    2016-08-01

    Full Text Available The paper identifies the need to use the techniques of modern biotechnology in primary seed potatoes in the Russian Federation. At present time, the playback of potatoes does not meet current phytosanitary requirements, moreover, there is a low yield of potatoes in the whole country and the region for a long period of time. The potato yield that annually produced in Russia is much lower than the world's, and does not meet the genetic capabilities of used varieties. Modern methods of biotechnology have undeniable advantages and make it possible to carry out year-round operation for the production of elite planting material of potato. Effective implementation of such activities is provided by careful selection of plant cultivation conditions in vitro, selection of breeding gound and environmental components for each variety in order to provide the maximum parameters of plant growth and productivity. During research we examined the effect of vitamin component of breeding ground according to the formula of  Murashige and Skoog, containing thiamine, pyridoxine, and niacin (the co-enzymes that involved in biochemical reactions of the plants. The effect of vitamin complex on the above-ground plant parts (plant height and number of internodes, as well as indicators of root formation (number and length of roots was studied for regenerated plants of four potato varieties: Adretta, Red Scarlett, Lubava, and Kuznechanka. We proved a positive effect of vitamin component on plant morphogenesis. For each variety we determined the optimal ratio in nutriculture medium.

  9. Water use, productivity and interactions among desert plants

    Energy Technology Data Exchange (ETDEWEB)

    Ehleringer, J.R.

    1992-11-17

    Water plays a central role affecting all aspects of the dynamics in aridland ecosystems. Productivity, stability, and competitive interactions among ecosystem components within aridlands are key processes related directly to water in deserts. The ecological studies in this project revolve around one fundamental premise: that integrated aspects of plant metabolism provide insight into the structure and function of plant communities and ecosystems. While it is difficult to extrapolate from instantaneous physiological observations to higher scales, such as whole plant performance or to interactions between plants as components of ecosystems, several key aspects of plant metabolism are scalable. Analyses of stable isotopic composition in plant tissues at natural abundance levels provide a useful tool that can provide insight into the consequences of physiological processes over temporal and spatial scales. Some plant processes continuously fractionate among light and heavy stable isotopic forms of an element; over time this results in integrated measures of plant metabolism. For example, carbon isotope fractionation during photosynthesis results in leaf carbon isotopic composition that is a measure of the set-point for photosynthetic metabolism and of water-use efficiency. Thus it provides information on the temporal scaling of a key physiological process. In contrast, hydrogen is not fractionated during water uptake through the root. Soil water availability in shallow, deep, and/or groundwater layers vary spatially; therefore hydrogen isotope ratios of xylem sap provide a direct measure of the water source currently used by a plant. The longer-term record of carbon and hydrogen isotope ratios is recorded annually in xylem tissues (tree rings). The research in this project addresses variation in stable isotopic composition of aridland plants and its consequences for plant performance and community-level interactions.

  10. 9 CFR 590.24 - Egg products plants requiring continuous inspection.

    Science.gov (United States)

    2010-01-01

    ... 9 Animals and Animal Products 2 2010-01-01 2010-01-01 false Egg products plants requiring..., DEPARTMENT OF AGRICULTURE EGG PRODUCTS INSPECTION INSPECTION OF EGGS AND EGG PRODUCTS (EGG PRODUCTS INSPECTION ACT) Scope of Inspection § 590.24 Egg products plants requiring continuous inspection. No plant...

  11. AMS of the Minor Plutonium Isotopes.

    Science.gov (United States)

    Steier, P; Hrnecek, E; Priller, A; Quinto, F; Srncik, M; Wallner, A; Wallner, G; Winkler, S

    2013-01-01

    VERA, the Vienna Environmental Research Accelerator, is especially equipped for the measurement of actinides, and performs a growing number of measurements on environmental samples. While AMS is not the optimum method for each particular plutonium isotope, the possibility to measure (239)Pu, (240)Pu, (241)Pu, (242)Pu and (244)Pu on the same AMS sputter target is a great simplification. We have obtained a first result on the global fallout value of (244)Pu/(239)Pu = (5.7 ± 1.0) × 10(-5) based on soil samples from Salzburg prefecture, Austria. Furthermore, we suggest using the (242)Pu/(240)Pu ratio as an estimate of the initial (241)Pu/(239)Pu ratio, which allows dating of the time of irradiation based solely on Pu isotopes. We have checked the validity of this estimate using literature data, simulations, and environmental samples from soil from the Salzburg prefecture (Austria), from the shut down Garigliano Nuclear Power Plant (Sessa Aurunca, Italy) and from the Irish Sea near the Sellafield nuclear facility. The maximum deviation of the estimated dates from the expected ages is 6 years, while relative dating of material from the same source seems to be possible with a precision of less than 2 years. Additional information carried by the minor plutonium isotopes may allow further improvements of the precision of the method.

  12. Ethylene production throughout growth and development of plants

    Science.gov (United States)

    Wheeler, Raymond M.; Peterson, Barbara V.; Stutte, Gary W.

    2004-01-01

    Ethylene production by 10 or 20 m2 stands of wheat, soybean, lettuce, potato, and tomato was monitored throughout growth and development in an atmospherically closed plant chamber. Chamber ethylene levels varied among species and rose during periods of canopy expansion and rapid growth for all species. Following this, ethylene levels either declined during seed fill and maturation for wheat and soybean, or remained relatively constant for potato and tomato (during flowering and early fruit development). Lettuce plants were harvested during rapid growth and peak ethylene production. Chamber ethylene levels increased rapidly during tomato ripening, reaching concentrations about 10 times that measured during vegetative growth. The highest ethylene production rates during vegetative growth ranged from 1.6 to 2.5 nmol m-2 d-1 during rapid growth of lettuce and wheat stands, or about 0.3 to 0.5 nmol g-1 fresh weight per hour. Estimates of stand ethylene production during tomato ripening showed that rates reached 43 nmol m-2 d-1 in one study and 93 nmol m-2 d-1 in a second study with higher lighting, or about 50x that of the rate during vegetative growth of tomato. In a related test with potato, the photoperiod was extended from 12 to 24 hours (continuous light) at 58 days after planting (to increase tuber yield), but this change in the environment caused a sharp increase in ethylene production from the basal rate of 0.4 to 6.2 nmol m-2 d-1. Following this, the photoperiod was changed back to 12 h at 61 days and ethylene levels decreased. The results suggest three separate categories of ethylene production were observed with whole stands of plants: 1) production during rapid vegetative growth, 2) production during climacteric fruit ripening, and 3) production from environmental stress.

  13. Plutonium stabilization and packaging system

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-05-01

    This document describes the functional design of the Plutonium Stabilization and Packaging System (Pu SPS). The objective of this system is to stabilize and package plutonium metals and oxides of greater than 50% wt, as well as other selected isotopes, in accordance with the requirements of the DOE standard for safe storage of these materials for 50 years. This system will support completion of stabilization and packaging campaigns of the inventory at a number of affected sites before the year 2002. The package will be standard for all sites and will provide a minimum of two uncontaminated, organics free confinement barriers for the packaged material.

  14. Plant traits mediate consumer and nutrient control on plant community productivity and diversity.

    Science.gov (United States)

    Eskelinen, Anu; Harrison, Susan; Tuomi, Maria

    2012-12-01

    The interactive effects of consumers and nutrients on terrestrial plant communities, and the role of plant functional traits in mediating these responses, are poorly known. We carried out a six-year full-factorial field experiment using mammalian herbivore exclusion and fertilization in two habitat types (fertile and infertile alpine tundra heaths) that differed in plant functional traits related to resource acquisition and palatability. Infertile habitats were dominated by species with traits indicative of a slow-growing strategy: high C:N ratio, low specific leaf area, and high condensed tannins. We found that herbivory counteracted the effect of fertilization on biomass, and that this response differed between the two habitats and was correlated with plant functional traits. Live biomass dominated the treatment responses in infertile habitats, whereas litter accumulation dominated the treatment responses in fertile habitats and was strongly negatively associated with resident community tannin concentration. Species richness declined under herbivore exclusion and fertilization in fertile habitats, where litter accumulation was greatest. Community means of plant C:N ratio predicted treatment effects on diversity: fertilization decreased and herbivory increased dominance in communities originally dominated by plants with high C:N, while fertilization increased and herbivory diminished dominance in communities where low C:N species were abundant. Our results highlight the close interdependence between consumer effects, soil nutrients, and plant functional traits and suggest that plant traits may provide an improved understanding of how consumers and nutrients influence plant community productivity and diversity.

  15. Cameroonian medicinal plants: Pharmacology and derived natural products

    Directory of Open Access Journals (Sweden)

    Thomas Efferth

    2010-10-01

    Full Text Available Many developing countries including Cameroon have mortality patterns that reflect high levels of infectious diseases and the risk of death during pregnancy and childbirth, in addition to cancers, cardiovascular diseases and chronic respiratory diseases that account for most deaths in the developed world. Several medicinal plants are used traditionally for their treatment. In this review, plants used in Cameroonian traditional medicine with evidence for the activities of their crude extracts and/or derived products have been discussed. A considerable number of plant extracts and isolated compounds possess significant antimicrobial, antiparasitic including anti-malarial, anti-proliferative, anti-inflammatory, anti-diabetes, and antioxidant effects. Most of the biologically active compounds belong to terpenoids, phenolics and alkaloids. Terpenoids from Cameroonian plants showed best activities as anti-parasitic, but rather poor antimicrobial effects. The best antimicrobial, anti-proliferative and antioxidant compounds were phenolics. In conclusion, many medicinal plants traditionally used in Cameroon to treat various ailments displayed good activities in vitro. This explains the endeavor of Cameroonian research institutes in drug discovery from indigenous medicinal plants. However, much work is still to be done to standardize methodologies and to study the mechanisms of action of isolated natural products.

  16. Plant triacylglycerols as feedstocks for the production of biofuels.

    Science.gov (United States)

    Durrett, Timothy P; Benning, Christoph; Ohlrogge, John

    2008-05-01

    Triacylglycerols produced by plants are one of the most energy-rich and abundant forms of reduced carbon available from nature. Given their chemical similarities, plant oils represent a logical substitute for conventional diesel, a non-renewable energy source. However, as plant oils are too viscous for use in modern diesel engines, they are converted to fatty acid esters. The resulting fuel is commonly referred to as biodiesel, and offers many advantages over conventional diesel. Chief among these is that biodiesel is derived from renewable sources. In addition, the production and subsequent consumption of biodiesel results in less greenhouse gas emission compared to conventional diesel. However, the widespread adoption of biodiesel faces a number of challenges. The biggest of these is a limited supply of biodiesel feedstocks. Thus, plant oil production needs to be greatly increased for biodiesel to replace a major proportion of the current and future fuel needs of the world. An increased understanding of how plants synthesize fatty acids and triacylglycerols will ultimately allow the development of novel energy crops. For example, knowledge of the regulation of oil synthesis has suggested ways to produce triacylglycerols in abundant non-seed tissues. Additionally, biodiesel has poor cold-temperature performance and low oxidative stability. Improving the fuel characteristics of biodiesel can be achieved by altering the fatty acid composition. In this regard, the generation of transgenic soybean lines with high oleic acid content represents one way in which plant biotechnology has already contributed to the improvement of biodiesel.

  17. Method of separating thorium from plutonium

    Science.gov (United States)

    Clifton, D.G.; Blum, T.W.

    A method of chemically separating plutonium from thorium is claimed. Plutonium and thorium to be separated are dissolved in an aqueous feed solution, preferably as the nitrate salts. The feed solution is acidified and sodium nitrite is added to the solution to adjust the valence of the plutonium to the +4 state. A chloride salt, preferably sodium chloride, is then added to the solution to induce formation of an anionic plutonium chloride complex. The anionic plutonium chloride complex and the thorium in solution are then separated by ion exchange on a strong base anion exchange column.

  18. 福岛核事故向环境释放的 Pu研究进展%Plutonium Isotopes Released f rom Fukushima Daiichi Nuclear Power Plant Accident into Environment

    Institute of Scientific and Technical Information of China (English)

    倪有意; 卜文庭; 郭秋菊; 胡丹; 许宏

    2015-01-01

    福岛核事故向环境释放的放射性核素中包含了锕系元素Pu ,其中以极毒组的239 Pu、240 Pu和高毒组的241 Pu为主。本文总结并分析了针对福岛核事故向环境释放的 Pu的相关研究。据估计,福岛核事故向环境中排放的239+240 Pu总量约为109 Bq ,是切尔诺贝利核事故排放量的万分之一。此次事故排放的Pu同位素原子比(240 Pu/239 Pu和241 Pu/239 Pu)及活度比(A (238 Pu)/A (239+240 Pu))明显异于全球沉降值,可作为事故中Pu溯源的判定依据。事故所排放的Pu全部来源于核电站1~3号反应堆堆芯而非乏燃料池。现有研究报道的数据表明,在福岛核电站周围30 km范围内的陆地环境中存在来自核事故排放的Pu污染,污染相对严重的“热点”区域和该地区与核电站的相对位置没有明显关联,主要是受地形和降水的影响。而对于人们关心的海洋环境,来自福岛核事故的Pu污染非常小。核事故向海洋中排放的Pu相对于核事故前海洋环境中的Pu污染水平可忽略不计。%On March 11 , 2011 , a catastrophic tsunami induced by a magnitude 9.0 earthquake caused the terrible Fukushima Daiichi Nuclear Power Plant (FDNPP) acci‐dent ,leading to the release of a large amount of radionuclides into the environment .T he published studies on plutonium isotopes in the environment after the FDNPP accident were reviewed in this paper .The total atmospheric released amounts of Pu from the FDNPP accident were estimated to be 109 Bq ,that is only 1/10 000 of that released from the Chernobyl accident .The Pu isotopes were released from the damaged reactors ,not from the spent fuel pools in the FDNPP .The Pu isotopic ratios (240 Pu/239 Pu ,241 Pu/239 Pu) and activity ratios of A(238 Pu)/A(239+ 240 Pu) were significantly different from that of global fallout ,serving as powerful fingerprints for Pu source identification .To date , the plutonium

  19. Gene Delivery into Plant Cells for Recombinant Protein Production

    OpenAIRE

    Qiang Chen; Huafang Lai

    2015-01-01

    Recombinant proteins are primarily produced from cultures of mammalian, insect, and bacteria cells. In recent years, the development of deconstructed virus-based vectors has allowed plants to become a viable platform for recombinant protein production, with advantages in versatility, speed, cost, scalability, and safety over the current production paradigms. In this paper, we review the recent progress in the methodology of agroinfiltration, a solution to overcome the challenge of transgene d...

  20. Plant characters of broccoli determinants of head production

    OpenAIRE

    Fernanda Daniela Brandelero; Betania Brum; Lindolfo Storck; Jessica Cardoso; Talita Slota Kutz; Thiago de Oliveira Vargas

    2016-01-01

    ABSTRACT: The increasing consumption of single-head broccoli is due to several factors, among them there are food production in minimally processing form and the existence of hybrids that adapt to various climates, in addition to the simple harvesting of this typical architecture.This study aimed to identify the most relevant plant characters of broccoli, represented by growth characters, which are determinant in the production and canopy area. The study was conducted in an experimental area ...

  1. Influence of plant community composition on biomass production in planted grasslands.

    Science.gov (United States)

    Henschell, Max A; Webster, Christopher R; Flaspohler, David J; Fortin, Chad R

    2015-01-01

    United States energy policy mandates increased use of renewable fuels. Restoring grasslands could contribute to a portion of this requirement through biomass harvest for bioenergy use. We investigated which plant community characteristics are associated with differences in biomass yield from a range of realistic native prairie plantings (n = 11; i.e., conservation planting, restoration, and wildlife cover). Our primary goal was to understand whether patterns in plant community composition and the Floristic Quality Index (FQI) were related to productivity as evidenced by dormant season biomass yield. FQI is an objective measure of how closely a plant community represents that of a pre-European settlement community. Our research was conducted in planted fields of native tallgrass prairie species, and provided a gradient in floristic quality index, species richness, species diversity, and species evenness in south-central Wisconsin during 2008 and 2009. We used a network of 15 randomly located 1 m2 plots within each field to characterize the plant community and estimate biomass yield by clipping the plots at the end of each growing season. While plant community composition and diversity varied significantly by planting type, biomass yield did not vary significantly among planting types (ANOVA; P >0.05). Biomass yield was positively correlated with plant community evenness, richness, C4 grass cover, and floristic quality index, but negatively correlated with plant species diversity in our multi-season multiple linear mixed effects models. Concordantly, plots with biomass yield in the lowest quartile (biomass yield biomass yield > 5800 kh/ha). Our results suggest that promoting the establishment of fields with high species evenness and floristic quality may increase biomass yield, while simultaneously supporting biodiversity.

  2. Nuclear driven water decomposition plant for hydrogen production

    Science.gov (United States)

    Parker, G. H.; Brecher, L. E.; Farbman, G. H.

    1976-01-01

    The conceptual design of a hydrogen production plant using a very-high-temperature nuclear reactor (VHTR) to energize a hybrid electrolytic-thermochemical system for water decomposition has been prepared. A graphite-moderated helium-cooled VHTR is used to produce 1850 F gas for electric power generation and 1600 F process heat for the water-decomposition process which uses sulfur compounds and promises performance superior to normal water electrolysis or other published thermochemical processes. The combined cycle operates at an overall thermal efficiency in excess of 45%, and the overall economics of hydrogen production by this plant have been evaluated predicated on a consistent set of economic ground rules. The conceptual design and evaluation efforts have indicated that development of this type of nuclear-driven water-decomposition plant will permit large-scale economic generation of hydrogen in the 1990s.

  3. Plutonium Immobilization Project Binder Burnout and Sintering Studies (Milestone 6.6a)

    Energy Technology Data Exchange (ETDEWEB)

    Chandler, G.

    1999-10-28

    The Plutonium Immobilization Team has developed an integrated test program to understand and optimize the controlling variables for the sintering step of the plutonium immobilization process. Sintering is the key process step that controls the product minerology. It is expected that the sintering will be the limiting process step that controls the throughput of the production line. The goal of the current sintering test program is to better understand factors that affect the sintering process.

  4. Plutonium inventories for stabilization and stabilized materials

    Energy Technology Data Exchange (ETDEWEB)

    Williams, A.K.

    1996-05-01

    The objective of the breakout session was to identify characteristics of materials containing plutonium, the need to stabilize these materials for storage, and plans to accomplish the stabilization activities. All current stabilization activities are driven by the Defense Nuclear Facilities Safety Board Recommendation 94-1 (May 26, 1994) and by the recently completed Plutonium ES&H Vulnerability Assessment (DOE-EH-0415). The Implementation Plan for accomplishing stabilization of plutonium-bearing residues in response to the Recommendation and the Assessment was published by DOE on February 28, 1995. This Implementation Plan (IP) commits to stabilizing problem materials within 3 years, and stabilizing all other materials within 8 years. The IP identifies approximately 20 metric tons of plutonium requiring stabilization and/or repackaging. A further breakdown shows this material to consist of 8.5 metric tons of plutonium metal and alloys, 5.5 metric tons of plutonium as oxide, and 6 metric tons of plutonium as residues. Stabilization of the metal and oxide categories containing greater than 50 weight percent plutonium is covered by DOE Standard {open_quotes}Criteria for Safe Storage of Plutonium Metals and Oxides{close_quotes} December, 1994 (DOE-STD-3013-94). This standard establishes criteria for safe storage of stabilized plutonium metals and oxides for up to 50 years. Each of the DOE sites and contractors with large plutonium inventories has either started or is preparing to start stabilization activities to meet these criteria.

  5. Dominant plant taxa predict plant productivity responses to CO2 enrichment across precipitation and soil gradients

    Science.gov (United States)

    Fay, Philip A.; Newingham, Beth A.; Polley, H. Wayne; Morgan, Jack A.; LeCain, Daniel R.; Nowak, Robert S.; Smith, Stanley D.

    2015-01-01

    The Earth's atmosphere will continue to be enriched with carbon dioxide (CO2) over the coming century. Carbon dioxide enrichment often reduces leaf transpiration, which in water-limited ecosystems may increase soil water content, change species abundances and increase the productivity of plant communities. The effect of increased soil water on community productivity and community change may be greater in ecosystems with lower precipitation, or on coarser-textured soils, but responses are likely absent in deserts. We tested correlations among yearly increases in soil water content, community change and community plant productivity responses to CO2 enrichment in experiments in a mesic grassland with fine- to coarse-textured soils, a semi-arid grassland and a xeric shrubland. We found no correlation between CO2-caused changes in soil water content and changes in biomass of dominant plant taxa or total community aboveground biomass in either grassland type or on any soil in the mesic grassland (P > 0.60). Instead, increases in dominant taxa biomass explained up to 85 % of the increases in total community biomass under CO2 enrichment. The effect of community change on community productivity was stronger in the semi-arid grassland than in the mesic grassland, where community biomass change on one soil was not correlated with the change in either the soil water content or the dominant taxa. No sustained increases in soil water content or community productivity and no change in dominant plant taxa occurred in the xeric shrubland. Thus, community change was a crucial driver of community productivity responses to CO2 enrichment in the grasslands, but effects of soil water change on productivity were not evident in yearly responses to CO2 enrichment. Future research is necessary to isolate and clarify the mechanisms controlling the temporal and spatial variations in the linkages among soil water, community change and plant productivity responses to CO2 enrichment. PMID

  6. Biogas and mineral fertiliser production from plant residues of phytoremediation

    Energy Technology Data Exchange (ETDEWEB)

    Chu, Thi Thu Ha

    2011-07-01

    The former uranium mining site in Ronneburg, Thuringia, Germany was known as a big source of uranium with more than 113,000 tons of uranium mined from 1946 to 1990. This area has been remediated since the nineties of the last century. However, nowadays the site in Ronneburg is still specially considered because of the heterogeneous contamination by many heavy metals and the vegetation can be affected. Three plant species including Indian mustard - Brassica juncea L., triticale - x. Triticosecale Wittmaek and sunflower - Helianthus annuus L. were seeded as accumulators of heavy metals and radionuclides in the phytoremediation process in 2009 and 2010 in Ronneburg. The subsequent utilization of the plant residues after phytoremediation is of special consideration. Batch fermentation of harvested plant materials under the mesophilic condition showed that all of the investigated plant materials had much higher biogas production than liquid cow manure except triticale root, of which biogas yield per volatile solid was not significantly higher than the one of sludge. The highest biogas yields (311 L{sub N}/kg FM and 807 L{sub N}/kg VS) were achieved from the spica of triticale after 42 days of retention of anaerobic digestion. Triticale shoot residues generated higher biogas and methane yields than the previously reported triticale materials that were harvested from the uncontaminated soil Triticale was considered as the highest potential species in biogas production, beside the best growth ability on the acidic soil at the test field site with highest biomass production. Biogas yield of Indian mustard shoot was also high but dramatically varied from 2009 to 2010. Digestates after anaerobic digestion of plant residues contained various macronutrients such as nitrogen, potassium, phosphorus and sulphur, and various micronutrients such as iron, manganes, zinc, etc. The accumulation levels of heavy metals in the investigated plant materials were not the hindrance factors

  7. Plant biotechnology for sustainable production of energy and co-products

    Energy Technology Data Exchange (ETDEWEB)

    Scheffran, Juergen [Hamburg Univ. (Germany). Inst. for Geography; Widholm, Jack M. (eds.) [Illinois Univ., Urbana, IL (United States). Dept. of Crop Sciences; Mascia, Peter N.

    2010-07-01

    The successful use of plant biomass for the sustainable production of energy and co-products such as chemicals is critically important for the future of humanity. Large scale exploitation of biomass is needed to decrease the production of greenhouse gases and help mitigate global warming, to provide energy security in the face of declining petroleum reserves, to improve balance of payment imbalances, and to spur local economic development. This volume discusses such uses of plant biomass as well as ways to improve the productivity and composition of plant species, including trees, perennial and annual grasses, oil-producing plants and algae, that have the potential to produce substrates such as sugar, starch, oil and cell walls, as well as energy and co-product substrates. The problems of invasiveness and gene dispersal are discussed, as are ways to mitigate these. Among the topics covered are models for integrated biorefineries to produce many co-product chemicals, the use of corn stover to power ethanol plants, life cycle analysis of biofuels, and criteria for biomass sustainability and certification. This is indeed an exciting and fast-moving time for advocates of plant biomass-based technology. (orig.)

  8. The first weighing of plutonium

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1967-09-10

    The following text, transcribed from the remarks of those scientists who gathered at the University of Chicago on September 10, 1967, to celebrate the 25th anniversary of the first weighing of plutonium, tells an important part of the story of this fascinating new element that is destined to play an increasingly significant role in the future of man.

  9. A perspective on the proliferation risks of plutonium mines

    Energy Technology Data Exchange (ETDEWEB)

    Lyman, E.S. [Nuclear Control Institute, Washington, DC (United States)

    1996-05-01

    The program of geologic disposal of spent fuel and other plutonium-containing materials is increasingly becoming the target of criticism by individuals who argue that in the future, repositories may become low-cost sources of fissile material for nuclear weapons. This paper attempts to outline a consistent framework for analyzing the proliferation risks of these so-called {open_quotes}plutonium mines{close_quotes} and putting them into perspective. First, it is emphasized that the attractiveness of plutonium in a repository as a source of weapons material depends on its accessibility relative to other sources of fissile material. Then, the notion of a {open_quotes}material production standard{close_quotes} (MPS) is proposed: namely, that the proliferation risks posed by geologic disposal will be acceptable if one can demonstrate, under a number of reasonable scenarios, that the recovery of plutonium from a repository is likely to be as difficult as new production of fissile material. A preliminary analysis suggests that the range of circumstances under which current mined repository concepts would fail to meet this standard is fairly narrow. Nevertheless, a broad application of the MPS may impose severe restrictions on repository design. In this context, the relationship of repository design parameters to easy of recovery is discussed.

  10. Phytotoxicity and Plant Productivity Analysis of Tar-Enriched Biochars

    Science.gov (United States)

    Keller, M. L.; Masiello, C. A.; Dugan, B.; Rudgers, J. A.; Capareda, S. C.

    2008-12-01

    Biochar is one of the three by-products obtained by the pyrolysis of organic material, the other two being syngas and bio-oil. The pyrolysis of biomass has generated a great amount of interest in recent years as all three by-products can be put toward beneficial uses. As part of a larger project designed to evaluate the hydrologic impact of biochar soil amendment, we generated a biochar through fast pyrolysis (less than 2 minutes) of sorghum stock at 600°C. In the initial biochar production run, the char bin was not purged with nitrogen. This inadvertent change in pyrolysis conditions produced a fast-pyrolysis biochar enriched with tars. We chose not to discard this batch, however, and instead used it to test the impact of tar-enriched biochars on plants. A suite of phytotoxicity tests were run to assess the effects of tar-rich biochar on plant germination and plant productivity. We designed the experiment to test for negative effects, using an organic carbon and nutrient-rich, greenhouse- optimized potting medium instead of soil. We used Black Seeded Simpson lettuce (Lactuca sativa) as the test organism. We found that even when tars are present within biochar, biochar amendment up to 10% by weight caused increased lettuce germination rates and increased biomass productivity. In this presentation, we will report the statistical significance of our germination and biomass data, as well as present preliminary data on how biochar amendment affects soil hydrologic properties.

  11. Genetic evidence for natural product-mediated plant-plant allelopathy in rice (Oryza sativa).

    Science.gov (United States)

    Xu, Meimei; Galhano, Rita; Wiemann, Philipp; Bueno, Emilio; Tiernan, Mollie; Wu, William; Chung, Ill-Min; Gershenzon, Jonathan; Tudzynski, Bettina; Sesma, Ane; Peters, Reuben J

    2012-02-01

    • There is controversy as to whether specific natural products play a role in directly mediating antagonistic plant-plant interactions - that is, allelopathy. If proved to exist, such phenomena would hold considerable promise for agronomic improvement of staple food crops such as rice (Oryza sativa). • However, while substantiated by the presence of phytotoxic compounds at potentially relevant concentrations, demonstrating a direct role for specific natural products in allelopathy has been difficult because of the chemical complexity of root and plant litter exudates. This complexity can be bypassed via selective genetic manipulation to ablate production of putative allelopathic compounds, but such an approach previously has not been applied. • The rice diterpenoid momilactones provide an example of natural products for which correlative biochemical evidence has been obtained for a role in allelopathy. Here, we apply reverse genetics, using knock-outs of the relevant diterpene synthases (copalyl diphosphate synthase 4 (OsCPS4) and kaurene synthase-like 4 (OsKSL4)), to demonstrate that rice momilactones are involved in allelopathy, including suppressing growth of the widespread rice paddy weed, barnyard grass (Echinochloa crus-galli). • Thus, our results not only provide novel genetic evidence for natural product-mediated allelopathy, but also furnish a molecular target for breeding and metabolic engineering of this important crop plant.

  12. Characteriztion of particulate plutonium released in fuel cycle operations

    Energy Technology Data Exchange (ETDEWEB)

    Seefeldt, W.B.; Mecham, W.J.; Steindler, M.J.

    1976-05-01

    An estimate of the plutonium source terms is made for the fuel cycles of three reactor types on the basis of currently applied, currently available, and estimated future technology. The three reactors are LWR-U, LWR-Pu, and LMFBR. The source terms are characterized as to quantity, form, and particle size distribution. Historical operating data for existing plants and the state of the art of the technology of air cleaning are reviewed.

  13. Algorithms for short-term production planning of cogeneration plants

    Energy Technology Data Exchange (ETDEWEB)

    Dotzauer, E.

    1998-03-01

    A cogeneration plant, feeding its output water into a district-heating network, may include several types of energy producing units. The most important being the Co-generation unit, which produces both heat and electricity. Most plants also have a Heat water storage. Finding the optimal production of both heat and electricity and the optimal use of the storage is a challenging mixed integer nonlinear optimization problem. The calculations may be divided into two sub-problems. The unit commitment problem is the problem to determine when a unit should be producing (on) or not (off). To solve the economic dispatch problem is to find the optimal production plan given which units are producing in each time interval. Together the solution of these two problems form the solution of the short-term production-planning problem. In this thesis a general approach for the mathematical modeling of a co-generation plant is presented. The model objective function is nonlinear, with nonlinear constraints. Internal plant temperatures, mass flows, storage losses, minimal up and down times and time dependent start-up costs are considered. The demand for heat, the forward temperature from the plant, the return temperature to the plant and the price of electricity are assumed to be known quantities. The net electric power produced is sold for the estimated current market price of electricity. The unit commitment problem is solved with an algorithm based on Lagrangian relaxation. The dual search direction is computed by the sub gradient method and the step length by the Polyak rule II. A heuristic method for the generation of primal feasible solutions is developed. The economic dispatch problem is solved using a combination of dynamic programming and general-purpose solvers. Algorithms to find starting values for the problem are developed. The model and the algorithms are implemented in MATLAB, illustrated with numerical examples and analyzed with numerical tests

  14. Novel fermentation processes for manufacturing plant natural products.

    Science.gov (United States)

    Zhou, Jingwen; Du, Guocheng; Chen, Jian

    2014-02-01

    Microbial production of plant natural products (PNPs), such as terpenoids, flavonoids from renewable carbohydrate feedstocks offers sustainable and economically attractive alternatives to their petroleum-based production. Rapid development of metabolic engineering and synthetic biology of microorganisms shows many advantages to replace the current extraction of these useful high price chemicals from plants. Although few of them were actually applied on a large scale for PNPs production, continuous research on these high-price chemicals and the rapid growing global market of them, show the promising future for the production of these PNPs by microorganisms with a more economic and environmental friendly way. Introduction of novel pathways and optimization of the native cellular processes by metabolic engineering of microorganisms for PNPs production are rapidly expanding its range of cell-factory applications. Here we review recent progress in metabolic engineering of microorganisms for the production of PNPs. Besides, factors restricting the yield improvement and application of lab-scale achievements to industrial applications have also been discussed.

  15. Plant Glutathione Biosynthesis: Diversity in Biochemical Regulation and Reaction Products

    Directory of Open Access Journals (Sweden)

    Ashley eGalant

    2011-09-01

    Full Text Available In plants, exposure to temperature extremes, heavy metal-contaminated soils, drought, air pollutants, and pathogens results in the generation of reactive oxygen species that alter the intracellular redox environment, which in turn influences signaling pathways and cell fate. As part of their response to these stresses, plants produce glutathione. Glutathione acts as an antioxidant by quenching reactive oxygen species, and is involved in the ascorbate-glutathione cycle that eliminates damaging peroxides. Plants also use glutathione for the detoxification of xenobiotics, herbicides, air pollutants (sulfur dioxide and ozone, and toxic heavy metals. Two enzymes catalyze glutathione synthesis: glutamate-cysteine ligase (GCL, and glutathione synthetase (GS. Glutathione is a ubiquitous protective compound in plants, but the structural and functional details of the proteins that synthesize it, as well as the potential biochemical mechanisms of their regulation, have only begun to be explored. As discussed here, the core reactions of glutathione synthesis are conserved across various organisms, but plants have diversified both the regulatory mechanisms that control its synthesis and the range of products derived from this pathway. Understanding the molecular basis of glutathione biosynthesis and its regulation will expand our knowledge of this component in the plant stress response network.

  16. Plant glutathione biosynthesis: diversity in biochemical regulation and reaction products.

    Science.gov (United States)

    Galant, Ashley; Preuss, Mary L; Cameron, Jeffrey C; Jez, Joseph M

    2011-01-01

    In plants, exposure to temperature extremes, heavy metal-contaminated soils, drought, air pollutants, and pathogens results in the generation of reactive oxygen species that alter the intracellular redox environment, which in turn influences signaling pathways and cell fate. As part of their response to these stresses, plants produce glutathione. Glutathione acts as an anti-oxidant by quenching reactive oxygen species, and is involved in the ascorbate-glutathione cycle that eliminates damaging peroxides. Plants also use glutathione for the detoxification of xenobiotics, herbicides, air pollutants (sulfur dioxide and ozone), and toxic heavy metals. Two enzymes catalyze glutathione synthesis: glutamate-cysteine ligase, and glutathione synthetase. Glutathione is a ubiquitous protective compound in plants, but the structural and functional details of the proteins that synthesize it, as well as the potential biochemical mechanisms of their regulation, have only begun to be explored. As discussed here, the core reactions of glutathione synthesis are conserved across various organisms, but plants have diversified both the regulatory mechanisms that control its synthesis and the range of products derived from this pathway. Understanding the molecular basis of glutathione biosynthesis and its regulation will expand our knowledge of this component in the plant stress response network.

  17. The optimization of an AP1000 fuel assembly for the transmutation of plutonium and minor actinides

    Science.gov (United States)

    Washington, Jeremy A.

    The average nuclear power plant produces twenty metric tons of used nuclear fuel per year, containing approximately 95 wt% uranium, 1 wt% plutonium, and 4 wt% fission products and transuranic elements. Fast reactors are a preferred option for the transmutation of plutonium and minor actinides; however, an optimistic deployment time of at least 20 years indicates a need for a near-term solution. The goal of this thesis is to examine the potential of light water reactors for plutonium and minor actinides transmutation as a near-term solution. This thesis screens the available nuclear isotope database to identify potential absorbers as coatings on a transmutation fuel in a light water reactor. A spectral shift absorber coating tunes the neutron energy spectrum experienced by the underlying target fuel. Eleven different spectral shift absorbers (B4C, CdO, Dy2O3, Er 2O3, Eu2O3, Gd2O3, HfO2, In2O3, Lu2O3, Sm2O3, and TaC) have been selected for further evaluation. A model developed using the NEWT module of SCALE 6.1 code provided performance data for the burnup of the target fuel rods. Irradiation of the target fuels occurs in a Westinghouse 17x17 XL Robust Fuel Assembly over a 1400 Effective Full Power Days (EFPD) interval. The fuels evaluated in this thesis include PuO2, Pu3Si2, PuN, MOX, PuZrH, PuZrHTh, PuZrO 2, and PuUZrH. MOX (5 wt% PuO2), Pu0.31ZrH 1.6Th1.08, and PuZrO2MgO (8 wt%) are selected for detailed analysis in a multi-pin transmutation assembly. A coupled model optimized the resulting transmutation fuel elements. The optimization considered three stages of fuel assemblies containing target fuel pins. The first stage optimized four target fuel pins adjacent to the central instrumentation channel. The second stage evaluated a variety of assemblies with multiple target fuel pins and the third stage re-optimized target fuel pins in the second-stage assembly. A PuZrO2MgO (8 wt%) target fuel with a coating of Lu 2O3 resulted in the greatest reduction in curium-244

  18. Separation Techniques for Uranium and Plutonium at Trace Levels for the Thermal Ionization Mass Spectrometric Determination

    Energy Technology Data Exchange (ETDEWEB)

    Suh, M. Y.; Han, S. H.; Kim, J. G.; Park, Y. J.; Kim, W. H

    2005-12-15

    This report describes the state of the art and the progress of the chemical separation and purification techniques required for the thermal ionization mass spectrometric determination of uranium and plutonium in environmental samples at trace or ultratrace levels. Various techniques, such as precipitation, solvent extraction, extraction chromatography, and ion exchange chromatography, for separation of uranium and plutonium were evaluated. Sample preparation methods and dissolution techniques for environmental samples were also discussed. Especially, both extraction chromatographic and anion exchange chromatographic procedures for uranium and plutonium in environmental samples, such as soil, sediment, plant, seawater, urine, and bone ash were reviewed in detail in order to propose some suitable methods for the separation and purification of uranium and plutonium from the safeguards environmental or swipe samples. A survey of the IAEA strengthened safeguards system, the clean room facility of IAEA's NWAL(Network of Analytical Laboratories), and the analytical techniques for safeguards environmental samples was also discussed here.

  19. Preparation of reference material for uranium and plutonium measurements using cellulose compound as a stabilizer

    Energy Technology Data Exchange (ETDEWEB)

    Surugaya, Naoki; Sato, Soichi; Hina, Tetsuro; Hiyama, Toshiaki [Japan Nuclear Cycle Development Inst., Tokai Works, Tokai, Ibaraki (Japan)

    2003-03-01

    Isotope dilution mass spectrometry, considered the most reliable analytical technique for input accountancy measurements of uranium and plutonium in spent fuel reprocessing plants, requires a well-characterized uranium/plutonium spike. Solid spikes containing {sup 235}U and {sup 239}Pu have been successfully utilized in safeguards inspections and in accountability analysis. They contain relatively large amounts of uranium and plutonium isotopically different to the uranium and plutonium of the sample, and are usually in the dried nitrate form. However, it is difficult to maintain and guarantee the integrity of the spike over long periods as they are in the dried nitrate form that can flake off the glass ampoule surface. Organic coatings were investigated using cellulose acetate butyrate as a stabilizer. The cellulose acetate butyrate had good characteristics, maintaining a thin film for a long time. (author)

  20. Determination of plutonium resent in highly radioactive irradiated fuel solution by spectrophotometric method

    Energy Technology Data Exchange (ETDEWEB)

    Dhamodharam, Krishnan [Reprocessing Group, Indira Gandhi Centre for Atomic Research, Kalpakkam (India); Pius, Anitha [The Gandhigram Rural Institute - Deemed University, Gandhigram (India)

    2016-06-15

    A simple and rapid spectrophotometric method has been developed to enable the determination of plutonium concentration in an irradiated fuel solution in the presence of all fission products. An excess of ceric ammonium nitrate solution was employed to oxidize all the valence states of plutonium to +6 oxidation state. Interference due to the presence of fission products such as ruthenium and zirconium, and corrosion products such as iron in the envisaged concentration range, as in the irradiated fuel solution, was studied in the determination of plutonium concentration by the direct spectrophotometric method. The stability of plutonium in +6 oxidation state was monitored under experimental conditions as a function of time. Results obtained are reproducible, and this method is applicable to radioactive samples resulting before the solvent extraction process during the reprocessing of fast reactor spent fuel. An analysis of the concentration of plutonium shows a relative standard deviation of <1.2% in standard as well as in simulated conditions. This reflects the fast reactor fuel composition with respect to uranium, plutonium, fission products such as ruthenium and zirconium, and corrosion products such as iron.

  1. Processing biogas plant digestates into value-added products - BIOVIRTA

    Energy Technology Data Exchange (ETDEWEB)

    Paavola, T. (MTT Agrifood Research Finland, Jokioinen (Finland)), e-mail: teija.paavola@mtt.fi; Torniainen, M. (Finnish Food Safety Authority, EVIRA, Helsinki (Finland)), e-mail: merja.torniainen@evira.fi; Kaparaju, P. (Jyvaeskylae Univ. (Finland)), e-mail: prasad.kaparaju@jyu.fi (and others)

    2011-11-15

    The objective of BIOVIRTA project is to develop technologies and practices with which digestates, originating from anaerobic digestion of different organic wastes and by-products can be refined to value-added and safe products for various end-uses. It is expected that the operational preconditions for biogas plants will be significantly enhanced when the end-products are proven safe and applicable. Selection of the raw materials for anaerobic co-digestion is the main operational strategy that could influence the nutrient content in the digestate. This has been clearly established in the laboratory and full-scale studies with various digestates originating from different raw materials. The nutrient content in the digestate also affects the opportunities to produce refined digestate products. In this project, the possibilities for several processing technologies, e.g. mechanical separation, stripping, and struvite production have been intensively evaluated for the production of different digestate products. Their mass balances have also been estimated. The feasibility for the use of the digestate products has been assessed based on their chemical and hygienic quality and for various end-uses, including as organic fertiliser and/or soil improver in crop production. The results of these field-experiments showed that the yield of barley fertilised with digestate products was comparable to inorganic fertilisers. (orig.)

  2. The effect of economic variables over a biodiesel production plant

    Energy Technology Data Exchange (ETDEWEB)

    Marchetti, J.M., E-mail: jmarchetti@plapiqui.edu.ar [Planta Piloto de Ingenieria Quimica (UNS-CONICET), Camino La Carrindanga km 7, 8000 Bahia Blanca (Argentina)

    2011-09-15

    Highlights: {yields} Influence of the mayor economic parameters for biodiesel production. {yields} Variations of profitability of a biodiesel plant due to changes in the market scenarios. {yields} Comparison of economic indicators of a biodiesel production facility when market variables are modified. - Abstract: Biodiesel appears as one of the possible alternative renewable fuels to substitute diesel fuel derived from petroleum. Several researches have been done on the technical aspects of biodiesel production in an attempt to develop a better and cleaner alternative to the conventional process. Economic studies have been carried out to have a better understanding of the high costs and benefits of different technologies in the biodiesel industry. In this work it is studied the effect of the most important economic variables of a biodiesel production process over the general economy of a conventional plant which employs sodium methoxide as catalyst. It has been analyzed the effect of the oil price, the amount of free fatty acid, the biodiesel price, the cost of the glycerin, the effect due to the modification on the methanol price, the washing water price, and several others. Small variations on some of the major market variables would produce significant effects over the global economy of the plant, making it non profitable in some cases.

  3. Integrated development and testing plan for the plutonium immobilization project

    Energy Technology Data Exchange (ETDEWEB)

    Kan, T.

    1998-07-01

    This integrated plan for the DOE Office of Fissile Materials Disposition (MD) describes the technology development and major project activities necessary to support the deployment of the immobilization approach for disposition of surplus weapons-usable plutonium. The plan describes details of the development and testing (D&T) tasks needed to provide technical data for design and operation of a plutonium immobilization plant based on the ceramic can-in-canister technology (''Immobilization Fissile Material Disposition Program Final Immobilization Form Assessment and Recommendation'', UCRL-ID-128705, October 3, 1997). The plan also presents tasks for characterization and performance testing of the immobilization form to support a repository licensing application and to develop the basis for repository acceptance of the plutonium form. Essential elements of the plant project (design, construction, facility activation, etc.) are described, but not developed in detail, to indicate how the D&T results tie into the overall plant project. Given the importance of repository acceptance, specific activities to be conducted by the Office of Civilian Radioactive Waste Management (RW) to incorporate the plutonium form in the repository licensing application are provided in this document, together with a summary of how immobilization D&T activities provide input to the license activity. The ultimate goal of the Immobilization Project is to develop, construct, and operate facilities that will immobilize from about 18 to 50 tonnes (MT) of U.S. surplus weapons usable plutonium materials in a manner that meets the ''spent fuel'' standard (Fissile Materials Storage and Disposition Programmatic Environmental Impact Statement Record of Decision, ''Storage and Disposition Final PEIS'', issued January 14, 1997, 62 Federal Register 3014) and is acceptable for disposal in a geologic repository. In the can-in-canister technology

  4. Efficacy of Specific Plant Products on Microorganisms Causing Dental Caries

    Science.gov (United States)

    Kanth, M Rajini; Prakash, A Ravi; Sreenath, G; Reddy, Vikram Simha

    2016-01-01

    Introduction Dental caries and periodontal diseases are the most common oral diseases seen globally, both in developed and developing countries. Oral microorganisms that is gram positive and gram negative bacteria are known to be involved in causation of these diseases. Nowadays commercially available dentrifices and mouth rinses are known to contain ingredients that can alter the oral microbial flora and have undesirable side effects such as vomiting, diarrhoea, disarrangement of oral, intestinal flora and tooth staining. Naturally available plant products are known to be less harmful with fewer side effects and also economical for the patient. Aim The aim of this study was to determine the antimicrobial properties of 10 naturally available plant products against oral microorganisms causing caries and to check the efficacy of these products in-vitro and to use these in mouth washes and dentrifices. Materials and Methods Sample of caries material was scrapped out from the extracted teeth and transferred to liquid broth, streaked over the agar media to allow for the growth of microorganisms. Plant products like clove oil, neem, ginger-garlic paste, tea tree oil, ginger, garlic, cinnamon oil, green tea, eucalyptus oil and turmeric were used. Antimicrobial efficacy of these products, was estimated by measuring zones of inhibition in the nutrient agar media. Results Clove oil was the most effective of all products against microorganisms causing caries with zone of inhibition - 30mm followed by ginger-garlic paste - 25mm, Neem - 15mm, tea tree oil - 15mm. Conclusion Based on the above results, it can be inferred that these natural products have the maximum efficacy against microorganisms and can be recommended in dentifrices, mouth rinses, topical gels, etc. PMID:28209019

  5. Africanos, tráfico atlántico y cimarrones en las fronteras entre la Guyana Francesa y la América portuguesa, siglo XVIII

    Directory of Open Access Journals (Sweden)

    Flávio dos Santos Gomes

    2011-01-01

    Full Text Available El artículo analiza las experiencias históricas de los cimarrones en un área de fronter atlántica continental entre la Guyana Francesa y la América portuguesa durante el siglo XVII. Las expectativas de los fugitivos africanos se abordan relacionando el movimiento del tráfico atlántico de esclavos-sus variaciones, los volúmenes y las procedencias-. De esta forma se reflexiona sobre los ambientes sociales, étnicos y geográficos que fueron encontrados y recreados en las selvas de estas zonas fronterizas. En un territorio de conflictos, enfrentamientos, disputas coloniales y expectativas de identidades, surgieron espacios de cooperación, donde los colonos europeos y las poblaciones de indígenas y de africanos se reinventaron como culturas y comunidades. Los circuitos demográficos del tráfico atlántico estaban conectados a la experiencia de africanos de diversas procedencias y a la posibilidad de encuentro de estos, a través de las fugas y de las comunidades transétnicas en una zona de frontera transnacional durante la Colonia.

  6. Bibliography on plutonium and its compounds; Bibliographie sur le plutonium et ses composes

    Energy Technology Data Exchange (ETDEWEB)

    Dirian, J.; Choquet, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Collection of bibliographical references on plutonium and its principal compounds from 1942 to end of 1957. (author) [French] Compilation de references bibliographiques sur le plutonium et ses principaux composes de 1942 a fin 1957. (auteur)

  7. Classification of explosives transformation products in plant tissue

    Energy Technology Data Exchange (ETDEWEB)

    Larson, S.L.; Jones, R.P. (Army Corps of Engineers, Vicksburg, MI (United States). Waterways Experiment Station); Escalon, L.; Parker, D. (AScI Corp., McLean, VA (United States))

    1999-06-01

    Explosives contamination in surface or groundwater used for the irrigation of food crops and phytoremediation of explosives-contaminated soil or water using plant-assisted biodegradation have brought about concerns as to the fate of explosives in plants. Liquid scintillation counting, high-performance liquid chromatography, and gel permeation chromatography were utilized to characterize explosives (hexahydro-1,3,5-trinitro-1,3,5-triazine and trinitrotoluene) and their metabolites in plant tissues obtained from three separate studies. Analyzing tissues of yellow nutsedge (Cyperus esculentus), corn (Zea mays), lettuce (Lacuta sativa), tomato (Lyopersicum esculentum), radish (Raphanus sativus), and parrot feather (Myriophyllum aquaticum) from three studies where exposure to explosives at nontoxic levels occurred showed that extensive transformation of the explosive contaminant occurred, variations were noted in uptake and transformation between terrestrial and aquatic plants, the products had significantly higher polarity and water solubility than the parent compounds, and the molecular sizes of the transformation products were significantly greater than those of the parent compounds.

  8. Production of therapeutic proteins through plant tissue and cell culture

    Directory of Open Access Journals (Sweden)

    Reza S. Gharelo

    2016-04-01

    Full Text Available Nowadays, pharmaceutical recombinant protein is increasingly used in treatment of many diseases such as hepatitis, anemia, diabetes and cancer. Different protein expression systems have been used for the expression of recombinant proteins in which each of them face obstacles that make utilizing them as comprehensive expression system in order to express wide variety of proteins difficult. Plant cell as a eukaryotic expression system have many advantages compared to other hosts. They are very "safe" and significantly decrease concerns about the contamination of recombinant proteins with human pathogens. In addition to this, plants as eukaryotic expression system perform proper post-translational modification, in case of eukaryotic proteins, and appropriate folding resulting in right function in biological environments. Therefore, the production of pharmaceutical protein through plant cells can be absolutely promising approach. In this review, the production of pharmaceutical protein in plant cells, advantages and disadvantages, offered methods and techniques for developing recombinant protein yields, and affective factors on the whole process of pharmaceutical protein expression in the molecular level will be reviewed.

  9. Production of plant virus inhibitor by Phytolacca americana suspension culture.

    Science.gov (United States)

    Misawa, M; Hayashi, M; Tanaka, H

    1975-09-01

    The inhibitory activity of tobacco mosaic virus (TMV) infection was assayed with the extracts of various callus tissues derived from the intact plants. Phytolacca americana callus was selected as a producer of the virus inhibitor and its cultural conditions in suspension were examined for cell growth and the inhibitor production. A modified liquid medium containing twofold concentrations of all components in that of Murashige and Skoog plus2,4-D (1.0 mg/liter) and sucrose (6%), but without any vitamins and glycine was chosen for production of higher levels of the inhibitor. TMV infections in tobacco, bean, and tomato plants were markedly inhibited by the introduction of the disrupted whole broth of suspension cultured P. americana.

  10. Genetic improvement of plants for enhanced bio-ethanol production.

    Science.gov (United States)

    Saha, Sanghamitra; Ramachandran, Srinivasan

    2013-04-01

    The present world energy situation urgently requires exploring and developing alternate, sustainable sources for fuel. Biofuels have proven to be an effective energy source but more needs to be produced to meet energy goals. Whereas first generation biofuels derived from mainly corn and sugarcane continue to be used and produced, the contentious debate between "feedstock versus foodstock" continues. The need for sources that can be grown under different environmental conditions has led to exploring newer sources. Lignocellulosic biomass is an attractive source for production of biofuel, but pretreatment costs to remove lignin are high and the process is time consuming. Genetically modified plants that have increased sugar or starch content, modified lignin content, or produce cellulose degrading enzymes are some options that are being explored and tested. This review focuses on current research on increasing production of biofuels by genetic engineering of plants to have desirable characteristics. Recent patents that have been filed in this area are also discussed.

  11. MODERN WAYS OF INULIN PRODUCTION FROM PLANT MATERIALS

    Directory of Open Access Journals (Sweden)

    Lisovoy V. V.

    2016-04-01

    Full Text Available The article presents the results of the patent research in the field of modern production technologies of Inulin from plant material. It has been established that the differences of the currently known methods of production of inulin are concluded in selecting raw materials pretreatment inulin-containing modes type extractant and extraction methods, methods of purification inulincontaining extract and methods for producing the final product. A significant amount of Inulin production methods is based on use of freshly feedstock. A number of methods have been patented involving the extraction Inulin from plant raw materials previously stabilized by drying. In most of the methods, inulin extraction is carried out at elevated temperatures with water or aqueous salt solutions. Several technologies involve extraction with organic solvents at low temperatures. Have been patented several processes in which the extraction is replaced by a separation process using inulincontaining juice and physical and mechanical methods. Some of the known processes provide for the extraction process to further operations, such as blanching vegetable raw materials, sonication, vibration impact, processing enzymes. The most promising direction to improve manufacturing technology of inulin from fresh plant raw materials is to conduct research on the use of electromagnetic fields at microwave frequencies, the inactivating effects of which on enzyme systems is an established fact that, in turn, would eliminate the use of chemical agents for inactivation of oxidative enzymes. In addition, considering that more effective are the methods for the preparation of inulin from freshly harvested plant material, are relevant researches on development of innovative technologies to prepare it for storage and its storage, which will provide inhibition of unwanted biochemical and microbiological processes that occur during storage and lead to a loss of inulin

  12. Research of beekeeping products using as radioprotectors for plants

    Directory of Open Access Journals (Sweden)

    I. О. Oginova

    2006-12-01

    Full Text Available Research conducted on a winter wheat, which was cultivated in a 30-km area in the year ofChernobylaccident, allowed to ascertain that complex use of sodium humate and beekeeping products is ineffective for diminishing the negative irradiation influence on the early growth processes of plants. Only the simultaneous use of humic preparations and anodic extraction of propolis has permanent positive effect.

  13. Power plant project success through total productive generation

    Energy Technology Data Exchange (ETDEWEB)

    Kaivola, R.; Tamminen, L.

    1996-11-01

    The Total Productive Generation concept (TPG) defines the lines of action adopted by IVO Generation Services Ltd (IGS) for the operation and maintenance of power plants. The TPG concept is based on procedures tested in practice. The main idea of TPG is continuous development of quality, which is a joint effort of the entire staff. Its objective is to benefit IGS`s own staff and, in particular, the company`s customers. (orig.)

  14. Opportunities for Products of New Plant Breeding Techniques.

    Science.gov (United States)

    Schaart, Jan G; van de Wiel, Clemens C M; Lotz, Lambertus A P; Smulders, Marinus J M

    2016-05-01

    Various new plant breeding techniques (NPBT) have a similar aim, namely to produce improved crop varieties that are difficult to obtain through traditional breeding methods. Here, we review the opportunities for products created using NPBTs. We categorize products of these NPBTs into three product classes with a different degree of genetic modification. For each product class, recent examples are described to illustrate the potential for breeding new crops with improved traits. Finally, we touch upon the future applications of these methods, such as cisgenic potato genotypes in which specific combinations of Phytophthora infestans resistance genes have been stacked for use in durable cultivation, or the creation of new disease resistances by knocking out or removing S-genes using genome-editing techniques.

  15. Surprising coordination for plutonium in the first plutonium(III) borate.

    Science.gov (United States)

    Wang, Shuao; Alekseev, Evgeny V; Depmeier, Wulf; Albrecht-Schmitt, Thomas E

    2011-03-21

    The first plutonium(III) borate, Pu(2)[B(12)O(18)(OH)(4)Br(2)(H(2)O)(3)]·0.5H(2)O, has been prepared by reacting plutonium(III) with molten boric acid under strictly anaerobic conditions. This compound contains a three-dimensional polyborate network with triangular holes that house the plutonium(III) sites. The plutonium sites in this compound are 9- and 10-coordinate and display atypical geometries.

  16. Enhancement of Plant Productivity in the Post-Genomics Era.

    Science.gov (United States)

    Thao, Nguyen Phuong; Tran, Lam-Son Phan

    2016-08-01

    Obtaining high plant yield is not always achievable in agricultural activity as it is determined by various factors, including cultivar quality, nutrient and water supplies, degree of infection by pathogens, natural calamities and soil conditions, which affect plant growth and development. More noticeably, sustainable plant productivity to provide sufficient food for the increasing human population has become a thorny issue to scientists in the era of unpredictable global climatic changes, appearance of more tremendous or multiple stresses, and land restriction for cultivation. Well-established agricultural management by agrotechnological means has shown no longer to be effective enough to confront with this challenge. Instead, in order to maximize the production, it is advisable to implement such practices in combination with biological applications. Nowadays, high technologies are widely adopted into agricultural production, biological diversity conservation and crop improvement. Wang et al. has nicely outlined the utilization of DNA-based technologies in this field. Among these are the applications of (i) DNA markers into cultivar identification, seed purity analysis, germplasm resource evaluation, heterosis prediction, genetic mapping, cloning and breeding; and (ii) gene expression data in supporting the description of crop phenology, the analytic comparison of crop growth under stress versus non-stress conditions, or the study of fertilizer effects. Besides, various purposes of using transgenic technologies in agriculture, such as generating cultivars with better product quality, better tolerance to biotic or abiotic stress, are also discussed in the review. One of the important highlights in this issue is the review of the benefits brought by high-throughput sequencing technology, which is also known as next-generation sequencing (NGS). It is not so difficult to recognize that its application has allowed us to carry out biological studies at much deeper level

  17. Biokinetics of Plutonium in Nonhuman Primates.

    Science.gov (United States)

    Poudel, Deepesh; Guilmette, Raymond A; Gesell, Thomas F; Harris, Jason T; Brey, Richard R

    2016-10-01

    A major source of data on metabolism, excretion and retention of plutonium comes from experimental animal studies. Although old world monkeys are one of the closest living relatives to humans, certain physiological differences do exist between these nonhuman primates and humans. The objective of this paper was to describe the metabolism of plutonium in nonhuman primates using the bioassay and retention data obtained from macaque monkeys injected with plutonium citrate. A biokinetic model for nonhuman primates was developed by adapting the basic model structure and adapting the transfer rates described for metabolism of plutonium in adult humans. Significant changes to the parameters were necessary to explain the shorter retention of plutonium in liver and skeleton of the nonhuman primates, differences in liver to bone partitioning ratio, and significantly higher excretion of plutonium in feces compared to that in humans.

  18. Productivity of sugarcane plants of ratooning with fertilizing treatment

    Directory of Open Access Journals (Sweden)

    MUHADIONO

    2010-01-01

    Full Text Available Latief AS, Syarief R, Pramudya B, Muhadiono. 2010. Productivity of sugarcane plants of ratooning with various fertilizing treatments. Nusantara Bioscience 2: 43-47. This research aims to determine the sugarcane plants of ratooning productivity with low external input of fertilization treatment towards farmers can increase profits. The method used is the Completely Randomized Block Design (CRBD with four treatments and three repetitions (4x3. Sugarcane varieties R 579 planted in each patch experiment 5x5 m2. Dosage of fertilizer: P0 = 3.6 kg/year plot experiment was 100% dosage usage of chemical fertilizers used by farmers. Further dosages were P1 (75% = 2.7 kg/plot, P2 (50% = 1.8 kg/plot and P3 (0.25% = 0.9 kg/plot, each supplemented with fertilizer 5 mL of liquid organic/patch a year. Sugarcane crops with a variety of treatment showed no significant difference. The highest productivity was achieved at dosages of P2 (50% chemical fertilizers plus organic fertilizer is 21.67 kg per square meter. Chemical fertilizers can be saved 7 quintals per hectare a year or Rp 997,500 per year. Additional costs of liquid organic fertilizer Rp. 100,000 per hectare year and labor Rp 100,000 per hectare, so the additional advantage of saving farmers fertilizer Rp. 797,500 per year.

  19. Plant characters of broccoli determinants of head production

    Directory of Open Access Journals (Sweden)

    Fernanda Daniela Brandelero

    2016-06-01

    Full Text Available ABSTRACT: The increasing consumption of single-head broccoli is due to several factors, among them there are food production in minimally processing form and the existence of hybrids that adapt to various climates, in addition to the simple harvesting of this typical architecture.This study aimed to identify the most relevant plant characters of broccoli, represented by growth characters, which are determinant in the production and canopy area. The study was conducted in an experimental area in Pato Branco city, PR. The 11 characters were evaluated for 365 plants, spaced with 0.8x0.5m, on a blank experiment. The characters of group 1 (height, number of leaves, stem height, stem diameter were evaluated on the 21 and 58 day after transplanting (DAT, and the leaf area was evaluated on the 17 and 32 DAT. The characters of group 2 were quantity of fresh head mass and canopy area. At the initial stage of cultivation, on the 17 and 21 DAT, variations in the plants characters did not lead toany variation in production. The higher number of leaves and the larger stem diameter on the 58 DAT determined the greater mass of the broccoli heads.

  20. PLUTONIUM METAL: OXIDATION CONSIDERATIONS AND APPROACH

    Energy Technology Data Exchange (ETDEWEB)

    Estochen, E.

    2013-03-20

    Plutonium is arguably the most unique of all metals when considered in the combined context of metallurgical, chemical, and nuclear behavior. Much of the research in understanding behavior and characteristics of plutonium materials has its genesis in work associated with nuclear weapons systems. However, with the advent of applications in fuel materials, the focus in plutonium science has been more towards nuclear fuel applications, as well as long term storage and disposition. The focus of discussion included herein is related to preparing plutonium materials to meet goals consistent with non-proliferation. More specifically, the emphasis is on the treatment of legacy plutonium, in primarily metallic form, and safe handling, packaging, and transport to meet non-proliferation goals of safe/secure storage. Elevated temperature oxidation of plutonium metal is the treatment of choice, due to extensive experiential data related to the method, as the oxide form of plutonium is one of only a few compounds that is relatively simple to produce, and stable over a large temperature range. Despite the simplicity of the steps required to oxidize plutonium metal, it is important to understand the behavior of plutonium to ensure that oxidation is conducted in a safe and effective manner. It is important to understand the effect of changes in environmental variables on the oxidation characteristics of plutonium. The primary purpose of this report is to present a brief summary of information related to plutonium metal attributes, behavior, methods for conversion to oxide, and the ancillary considerations related to processing and facility safety. The information provided is based on data available in the public domain and from experience in oxidation of such materials at various facilities in the United States. The report is provided as a general reference for implementation of a simple and safe plutonium metal oxidation technique.

  1. Zone refining of plutonium metal

    Energy Technology Data Exchange (ETDEWEB)

    Blau, Michael S. [Univ. of Idaho, Moscow, ID (United States)

    1994-08-01

    The zone refining process was applied to Pu metal containing known amounts of impurities. Rod specimens of plutonium metal were melted into and contained in tantalum boats, each of which was passed horizontally through a three-turn, high-frequency coil in such a manner as to cause a narrow molten zone to pass through the Pu metal rod 10 times. The impurity elements Co, Cr, Fe, Ni, Np, U were found to move in the same direction as the molten zone as predicted by binary phase diagrams. The elements Al, Am, and Ga moved in the opposite direction of the molten zone as predicted by binary phase diagrams. As the impurity alloy was zone refined, {delta}-phase plutonium metal crystals were produced. The first few zone refining passes were more effective than each later pass because an oxide layer formed on the rod surface. There was no clear evidence of better impurity movement at the slower zone refining speed. Also, constant or variable coil power appeared to have no effect on impurity movement during a single run (10 passes). This experiment was the first step to developing a zone refining process for plutonium metal.

  2. ARRAYS OF BOTTLES OF PLUTONIUM NITRATE SOLUTION

    Energy Technology Data Exchange (ETDEWEB)

    Margaret A. Marshall

    2012-09-01

    In October and November of 1981 thirteen approaches-to-critical were performed on a remote split table machine (RSTM) in the Critical Mass Laboratory of Pacific Northwest Laboratory (PNL) in Richland, Washington using planar arrays of polyethylene bottles filled with plutonium (Pu) nitrate solution. Arrays of up to sixteen bottles were used to measure the critical number of bottles and critical array spacing with a tight fitting Plexiglas® reflector on all sides of the arrays except the top. Some experiments used Plexiglas shells fitted around each bottles to determine the effect of moderation on criticality. Each bottle contained approximately 2.4 L of Pu(NO3)4 solution with a Pu content of 105 g Pu/L and a free acid molarity H+ of 5.1. The plutonium was of low 240Pu (2.9 wt.%) content. These experiments were sponsored by Rockwell Hanford Operations because of the lack of experimental data on the criticality of arrays of bottles of Pu solution such as might be found in storage and handling at the Purex Facility at Hanford. The results of these experiments were used “to provide benchmark data to validate calculational codes used in criticality safety assessments of [the] plant configurations” (Ref. 1). Data for this evaluation were collected from the published report (Ref. 1), the approach to critical logbook, the experimenter’s logbook, and communication with the primary experimenter, B. Michael Durst. Of the 13 experiments preformed 10 were evaluated. One of the experiments was not evaluated because it had been thrown out by the experimenter, one was not evaluated because it was a repeat of another experiment and the third was not evaluated because it reported the critical number of bottles as being greater than 25. Seven of the thirteen evaluated experiments were determined to be acceptable benchmark experiments. A similar experiment using uranyl nitrate was benchmarked as U233-SOL-THERM-014.

  3. Accelerator mass spectrometry (AMS) in plutonium analysis.

    Science.gov (United States)

    Strumińska-Parulska, Dagmara I

    The paper summarizes the results of the (240)Pu/(239)Pu atomic ratio studies in atmospheric fallout samples collected in 1986 over Gdynia (Poland) as well as three Baltic fish species collected in 1997 using the accelerator mass spectrometry. A new generation of AMS has been developed during last years and this method is an efficient and good technique to measure long-lived radioisotopes in the environment and provides the most accurate determination of the atomic ratios between (240)Pu and (239)Pu. The nuclide compositions of plutonium in filter samples correspond to their means of production. AMS measurements of atmospheric fallout collected in April showed sufficient increase of the (240)Pu/(239)Pu atomic ratio from 0.28 from March to 0.47. Also such high increase of (240)Pu/(239)Pu atomic ratio, close to reactor core (240)Pu/(239)Pu atomic ratio, was observed in September and equaled 0.47.

  4. Peculiar dynamical properties of plutonium hydrides

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    In the present work, the structure and spectra of PuH and PuH2 are defined by B3LYP/SDD method, from which the analytic potential energy function of PuH2 is derived. The analysis of quasi-classical molecular reaction dynamics is performed to study the state-state process of pu(7Fg) + H2(X1∑+g ). It is found that the reaction pu(7Fg) + H2(X1∑+g )→PuH2(X7B1) has no threshold. The simultaneous hydrogenation process of plutonium with the main product of PuH2 is theoretically proved for the first time.

  5. Characterisation of radioactive waste products associated with plant decommissioning.

    Science.gov (United States)

    Sejvar, J; Fero, A H; Gil, C; Hagler, R J; Santiago, J L; Holgado, A; Swenson, R

    2005-01-01

    The inventory of radioactivity that must be considered in the decommissioning of a typical 1000 MWe Spanish pressurised water reactor (PWR) was investigated as part of a generic plant decommissioning study. Analyses based on DORT models (in both R-Z and R-theta geometries) were used with representative plant operating history and core power distribution data in defining the expected neutron environment in regions near the reactor core. The activation analyses were performed by multiplying the DORT scalar fluxes by energy-dependent reaction cross sections (based on ENDF/B-VI data) to generate reaction rates on a per atom basis. The results from the ORIGEN2 computer code were also used for determining the activities associated with certain nuclides where multi-group cross section data were not available. In addition to the bulk material activation of equipment and structures near the reactor, the activated corrosion-product (or 'crud') deposits on system and equipment surfaces were considered. The projected activities associated with these sources were primarily based on plant data and experience from operating PWR plants.

  6. Plant compounds insecticide activity against Coleoptera pests of stored products

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Marcio Dionizio; Picanco, Marcelo Coutinho; Guedes, Raul Narciso Carvalho; Campos, Mateus Ribeiro de; Silva, Gerson Adriano; Martins, Julio Claudio [Universidade Federal de Vicosa (UFV), MG (Brazil). Dept. de Biologia Animal]. E-mail: marcio.dionizio@gmail.com; picanco@ufv.br; guedes@ufv.br; mateusc3@yahoo.com.br; agronomiasilva@yahoo.com.br

    2007-07-15

    The objective of this work was to screen plants with insecticide activity, in order to isolate, identify and assess the bioactivity of insecticide compounds present in these plants, against Coleoptera pests of stored products: Oryzaephilus surinamensis L. (Silvanidae), Rhyzopertha dominica F. (Bostrichidae) and Sitophilus zeamais Mots. (Curculionidae). The plant species used were: basil (Ocimum selloi Benth.), rue (Ruta graveolens L.), lion's ear (Leonotis nepetifolia (L.) R.Br.), jimson weed (Datura stramonium L.), baleeira herb (Cordia verbenacea L.), mint (Mentha piperita L.), wild balsam apple (Mormodica charantia L.), and billy goat weed or mentrasto (Ageratum conyzoides L.). The insecticide activity of hexane and ethanol extracts from those plants on R. dominica was evaluated. Among them, only hexane extract of A. conyzoides showed insecticide activity; the hexane extract of this species was successively fractionated by silica gel column chromatography, for isolation and purification of the active compounds. Compounds 5,6,7,8,3',4',5'-heptamethoxyflavone; 5,6,7,8,3'-pentamethoxy-4',5'-methilenedioxyflavone and coumarin were identified. However, only coumarin showed insecticide activity against three insect pests (LD{sub 50} from 2.72 to 39.71 mg g{sup -1} a.i.). The increasing order of insects susceptibility to coumarin was R. dominica, S. zeamais and O. surinamensis. (author)

  7. Invasive plants as feedstock for biochar and bioenergy production.

    Science.gov (United States)

    Liao, Rui; Gao, Bin; Fang, June

    2013-07-01

    In this work, the potential of invasive plant species as feedstock for value-added products (biochar and bioenergy) through pyrolysis was investigated. The product yield rates of two major invasive species in the US, Brazilian Pepper (BP) and Air Potato (AP), were compared to that of two traditional feedstock materials, water oak and energy cane. Three pyrolysis temperatures (300, 450, and 600°C) and four feedstock masses (10, 15, 20, and 25 g) were tested for a total of 12 experimental conditions. AP had high biochar and low oil yields, while BP had a high oil yield. At lower temperatures, the minimum feedstock residence time for biochar and bioenergy production increased at a faster rate as feedstock weight increased than it did at higher temperatures. A simple mathematical model was successfully developed to describe the relationship between feedstock weight and the minimum residence time.

  8. Indicators of energy efficiency in ammonia productions plants

    Directory of Open Access Journals (Sweden)

    Flavio V. Tavares

    2013-07-01

    Full Text Available This paper presents and analyzes tools for the assessment of energy efficiency in ammonia production plants using key performance indicators (KPI. Monitoring the consumption of inputs in the industry could generate reductions in greenhouse gas emissions while simultaneously producing gains in energy efficiency in industrial operations. The continuous monitoring of performance indicators relative to emissions data and the consumption of natural resources allows for effective and direct intervention, resulting in improvements in production processes and operating practices. The use of such information by operating teams, in conjunction with management actions focused on continuous improvement, could lead to energy efficiency gains, a reduction in greenhouse gas emissions, and make production processes more profitable.

  9. Antioxidant Capacity Determination in Plants and Plant-Derived Products: A Review

    OpenAIRE

    2016-01-01

    The present paper aims at reviewing and commenting on the analytical methods applied to antioxidant and antioxidant capacity assessment in plant-derived products. Aspects related to oxidative stress, reactive oxidative species’ influence on key biomolecules, and antioxidant benefits and modalities of action are discussed. Also, the oxidant-antioxidant balance is critically discussed. The conventional and nonconventional extraction procedures applied prior to analysis are also presented, as th...

  10. Algorithm of actions to identify and reduce risks in the production of milk and plant products

    Directory of Open Access Journals (Sweden)

    L. E. Glagoleva

    2016-01-01

    Full Text Available Foods with a new generation of functional and improved consumer properties, corresponds to the modern concepts of nutrition science and consumer needs. functional food production is a major global trend in food science and the subject of innovation. One of the important trends is the use of plant complexes and plant food systems. Using the plant complexes (PC and plant food systems (PFS provides a number of benefits: improved consumer properties of the product, do not need to change the process, it is possible to control directional rheological properties and consistency of the finished products, reduced the number of risk points in the production cycle. This paper describes the development of an algorithm of action to identify and mitigate risks in the production of milk and plant products. Also conducted a risk analysis, identified and assessed the risks in the process of production, installed capacity of available resources to reduce the level of risk. Established and submitted to the critical control points in production processes, as well as the critical limits for each critical control points, and the procedure for corrective action in case of violations of the past. During the study, measured changes in the quantitative and qualitative composition of microflora of semi-finished and Quantity of Mesophilic Aerobic and Facultative Anaerobic Microorganisms (QMAFAnM. To determine QMAFAnM samples were taken: 1 – cheesecakes (control, 2 – cheesecakes with RPS. Microbiological studies analyzed frozen-conjugated semi-finished products was determined within 90 days. It is clear from the data that the cottage cheese with semi-finished products have a lower RPM 11.7%. Analyzing the data, it is possible to conclude that the physico-chemical, organoleptic and microbiological indicators of products was developed to set standards on cheese semi-finished products. multilevel structure that characterizes the quality indicators has been developed and is

  11. Plant ecology. Worldwide evidence of a unimodal relationship between productivity and plant species richness.

    Science.gov (United States)

    Fraser, Lauchlan H; Pither, Jason; Jentsch, Anke; Sternberg, Marcelo; Zobel, Martin; Askarizadeh, Diana; Bartha, Sandor; Beierkuhnlein, Carl; Bennett, Jonathan A; Bittel, Alex; Boldgiv, Bazartseren; Boldrini, Ilsi I; Bork, Edward; Brown, Leslie; Cabido, Marcelo; Cahill, James; Carlyle, Cameron N; Campetella, Giandiego; Chelli, Stefano; Cohen, Ofer; Csergo, Anna-Maria; Díaz, Sandra; Enrico, Lucas; Ensing, David; Fidelis, Alessandra; Fridley, Jason D; Foster, Bryan; Garris, Heath; Goheen, Jacob R; Henry, Hugh A L; Hohn, Maria; Jouri, Mohammad Hassan; Klironomos, John; Koorem, Kadri; Lawrence-Lodge, Rachael; Long, Ruijun; Manning, Pete; Mitchell, Randall; Moora, Mari; Müller, Sandra C; Nabinger, Carlos; Naseri, Kamal; Overbeck, Gerhard E; Palmer, Todd M; Parsons, Sheena; Pesek, Mari; Pillar, Valério D; Pringle, Robert M; Roccaforte, Kathy; Schmidt, Amanda; Shang, Zhanhuan; Stahlmann, Reinhold; Stotz, Gisela C; Sugiyama, Shu-ichi; Szentes, Szilárd; Thompson, Don; Tungalag, Radnaakhand; Undrakhbold, Sainbileg; van Rooyen, Margaretha; Wellstein, Camilla; Wilson, J Bastow; Zupo, Talita

    2015-07-17

    The search for predictions of species diversity across environmental gradients has challenged ecologists for decades. The humped-back model (HBM) suggests that plant diversity peaks at intermediate productivity; at low productivity few species can tolerate the environmental stresses, and at high productivity a few highly competitive species dominate. Over time the HBM has become increasingly controversial, and recent studies claim to have refuted it. Here, by using data from coordinated surveys conducted throughout grasslands worldwide and comprising a wide range of site productivities, we provide evidence in support of the HBM pattern at both global and regional extents. The relationships described here provide a foundation for further research into the local, landscape, and historical factors that maintain biodiversity.

  12. Antioxidant Capacity Determination in Plants and Plant-Derived Products: A Review

    Directory of Open Access Journals (Sweden)

    Aurelia Magdalena Pisoschi

    2016-01-01

    Full Text Available The present paper aims at reviewing and commenting on the analytical methods applied to antioxidant and antioxidant capacity assessment in plant-derived products. Aspects related to oxidative stress, reactive oxidative species’ influence on key biomolecules, and antioxidant benefits and modalities of action are discussed. Also, the oxidant-antioxidant balance is critically discussed. The conventional and nonconventional extraction procedures applied prior to analysis are also presented, as the extraction step is of pivotal importance for isolation and concentration of the compound(s of interest before analysis. Then, the chromatographic, spectrometric, and electrochemical methods for antioxidant and antioxidant capacity determination in plant-derived products are detailed with respect to their principles, characteristics, and specific applications. Peculiarities related to the matrix characteristics and other factors influencing the method’s performances are discussed. Health benefits of plants and derived products are described, as indicated in the original source. Finally, critical and conclusive aspects are given when it comes to the choice of a particular extraction procedure and detection method, which should consider the nature of the sample, prevalent antioxidant/antioxidant class, and the mechanism underlying each technique. Advantages and disadvantages are discussed for each method.

  13. Equipment specifications for an electrochemical fuel reprocessing plant

    Energy Technology Data Exchange (ETDEWEB)

    Hemphill, Kevin P [Los Alamos National Laboratory

    2010-01-01

    Electrochemical reprocessing is a technique used to chemically separate and dissolve the components of spent nuclear fuel, in order to produce new metal fuel. There are several different variations to electrochemical reprocessing. These variations are accounted for by both the production of different types of spent nuclear fuel, as well as different states and organizations doing research in the field. For this electrochemical reprocessing plant, the spent fuel will be in the metallurgical form, a product of fast breeder reactors, which are used in many nuclear power plants. The equipment line for this process is divided into two main categories, the fuel refining equipment and the fuel fabrication equipment. The fuel refining equipment is responsible for separating out the plutonium and uranium together, while getting rid of the minor transuranic elements and fission products. The fuel fabrication equipment will then convert this plutonium and uranium mixture into readily usable metal fuel.

  14. Evolutionary history and the effect of biodiversity on plant productivity.

    Science.gov (United States)

    Cadotte, Marc W; Cardinale, Bradley J; Oakley, Todd H

    2008-11-04

    Loss of biological diversity because of extinction is one of the most pronounced changes to the global environment. For several decades, researchers have tried to understand how changes in biodiversity might impact biomass production by examining how biomass correlates with a number of biodiversity metrics (especially the number of species and functional groups). This body of research has focused on species with the implicit assumption that they are independent entities. However, functional and ecological similarities are shaped by patterns of common ancestry, such that distantly related species might contribute more to production than close relatives, perhaps by increasing niche breadth. Here, we analyze 2 decades of experiments performed in grassland ecosystems throughout the world and examine whether the evolutionary relationships among the species comprising a community predict how biodiversity impacts plant biomass production. We show that the amount of phylogenetic diversity within communities explained significantly more variation in plant community biomass than other measures of diversity, such as the number of species or functional groups. Our results reveal how evolutionary history can provide critical information for understanding, predicting, and potentially ameliorating the effects of biodiversity loss and should serve as an impetus for new biodiversity experiments.

  15. Solar enriched methane production: Assessment of plant potentialities and applications

    Directory of Open Access Journals (Sweden)

    Vincenzo Piemonte

    2010-04-01

    Full Text Available The crucial environmental issue due to fossil fuel use in our society and industries and more and more perceived by the communities is stimulating the development of innovative technologies with the scope of reducing GHGs and pollutants emissions, improving plants efficiency and exploiting renewable energy sources. The idea proposed in the present work links this context: a novel hybrid plant for the production of a mixture of methane and hydrogen (20%vol, called enriched-methane, from a steam reforming reactor whose heat duty is supplied by a concentrating solar power (CSP plant by means of a molten salt stream is here conceived, modelled and assessed. The enriched-methane mixture can be applied in methane internal combustion engines (ICE reducing CO, CO2, unburned emissions and improving engine efficiency. Moreover, the residual sensible heat of solar-heated molten salt stream can be used to generate medium-pressure steam and to produce electricity by a steam-turbine. Therefore, the plant proposed is co-generative, producing both hydrogen and electricity from a solar source. The behaviour of methane steam reforming reactor is simulated by means of a 2D mathematical model and the design of a cogenerative solar plant is proposed, evaluating its potentialities in terms of MWh of electricity produced and number of vehicles fed by enriched-methane. A single CSP module (surface requirement = 1.5 hectares coupled with a 4-tubes-and-shell shaped reactor is able to produce 686 tons/year of hydrogen, equivalent to 3.430 tons/year of 20%vol H2-CH4 mixture and 3.097 MWh/year of clean electricity.

  16. Plutonium contamination in soils in open space and residential areas near Rocky Flats, Colorado.

    Science.gov (United States)

    Litaor, M I

    1999-02-01

    Spatial analysis of the 240Pu:239Pu isotopic ratio of 42 soil samples collected around Rocky Flats Plant near Golden, Colorado, was conducted to assess the effect of Rocky Flats Plant activity on the soil environment. Two probability maps that quantified the uncertainty of the spatial distribution of plutonium isotopic ratios were constructed using the sequential Gaussian simulation technique (sGs). Assuming a plutonium isotopic ratio range of 0.152+/-0.003 to 0.169+/-0.009 is characteristic to global fallout in Colorado, and a mean value of 0.155 is representative for the Rocky Flats Plant area, the main findings of the current work were (1) the areas northwest and southwest of Rocky Flats Plant exhibited a plutonium ratio > or = 0.155, thus were minimally impacted by the plant activity; (2) the study area east of Rocky Flats Plant (approximately 120 km2) exhibited a plutonium isotopic ratio open space and residential areas amounted to 111.2 GBq, with a standard error of estimate of 50.8 GBq.

  17. Measuring NO Production by Plant Tissues and Suspension Cultured Cells

    Institute of Scientific and Technical Information of China (English)

    Jan Vitecek; Vilem Reinohl; Russell L.Jones

    2008-01-01

    We describe an inexpensive and reliable detector for measuring NO emitted in the gas phase from plants.The method relies on the use of a strong oxidizer to convert NO to NO2 and subsequent capture of NO2 by a Griess reagent trap.The set-up approaches the sensitivity for NO comparable to that of instruments based on chemiluminescence and photoacoustic detectors.We demonstrate the utility of our set-up by measuring NO produced by a variety of well established plant sources.NO produced by nitrate reductase (NR) in tobacco leaves and barley aleurone was readily detected,as was the production of NO from nitrite by the incubation medium of barley aleurone.Arabidopsis mutants that overproduce NO or lack NO-synthase (AtNOS1) also displayed the expected NO synthesis phenotype when assayed by our set-up.We could also measure NO production from elicitor-treated suspension cultured cells using this set-up.Further,we have focused on the detection of NO by a widely used fluorescent probe 4-amino-5-methylamino-2',7'-difluorofluorescein (DAF-FM).Our work points to the pitfalls that must be avoided when using DAF-FM to detect the production of NO by plant tissues.In addition to the dramatic effects that pH can have on fluorescence from DAF-FM,the widely used NO scavengers 2-phenyl-4,4,5,5-tetramethylimidazoline-l-oxyl-3-oxide (PTIO) and 2-(4-carboxyphenyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide (cPTIO) can produce anomalous and unexpected results.Perhaps the most serious drawback of DAF-FM is its ability to bind to dead cells and remain NO-sensitive.

  18. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    Energy Technology Data Exchange (ETDEWEB)

    John Groppo; Thomas Robl

    2006-09-30

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station.

  19. Subchronic inhalation of carbon tetrachloride alters the tissue retention of acutely inhaled plutonium-239 nitrate in F344 rats and syrian golden hamsters

    Energy Technology Data Exchange (ETDEWEB)

    Benson, J.M.; Barr, E.B.; Lundgren, D.L. [and others

    1995-12-01

    Carbon tetrachloride (CCl{sub 4}) has been used extensively in the nuclear weapons industry, so it is likely that nuclear plant workers have been exposed to both CCl{sub 4} and plutonium compounds. Future exposures may occur during {open_quotes}cleanup{close_quotes} operations at weapons productions sites such as the Hanford, Washington, and Rocky Flats, Colorado, facilities. Inhalation of 20 and 100 ppm CCl{sub 4} by hamsters reduces uptake of {sup 239}Pu solubilized from lung, shunting the {sup 239}Pu to the skeleton.

  20. A Study of a nuclear hydrogen production demonstration plant

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Jong Hwa and others [KAERI, Daejeon (Korea, Republic of); Bae, Ki Kwang [Korea Institute of Energy Research, Daejeon (Korea, Republic of); Jung, Kwang Deog [Korea Institute od Science and Technology, Seoul (Korea, Republic of)

    2007-03-15

    The current energy supply system is burdened environmental and supply problems. The concept of a hydrogen economy has been actively discussed worldwide. KAERI has set up a plan to demonstrate massive production of hydrogen using a VHTR by the early 2020s. The technological gap to meet this goal was identified during the past few years. The hydrogen production process, a process heat exchanger, the efficiency of an I/S thermochemical cycle, the manufacturing of components, the analysis tools of VHTR, and a coated particle fuel are key areas that require urgent development. Candidate NHDD plant designs based on a 200 MWth VHTR core and I/S thermochemical process have been studied and some of analysis results are presented in this paper.

  1. Natural products from resurrection plants: potential for medical applications.

    Science.gov (United States)

    Gechev, Tsanko S; Hille, Jacques; Woerdenbag, Herman J; Benina, Maria; Mehterov, Nikolay; Toneva, Valentina; Fernie, Alisdair R; Mueller-Roeber, Bernd

    2014-11-01

    Resurrection species are a group of land plants that can tolerate extreme desiccation of their vegetative tissues during harsh drought stress, and still quickly - often within hours - regain normal physiological and metabolic functions following rehydration. At the molecular level, this desiccation tolerance is attributed to basal cellular mechanisms including the constitutive expression of stress-associated genes and high levels of protective metabolites present already in the absence of stress, as well as to transcriptome and metabolome reconfigurations rapidly occurring during the initial phases of drought stress. Parts of this response are conferred by unique metabolites, including a diverse array of sugars, phenolic compounds, and polyols, some of which accumulate to high concentrations within the plant cell. In addition to drought stress, these metabolites are proposed to contribute to the protection against other abiotic stresses and to an increased oxidative stress tolerance. Recently, extracts of resurrection species and particular secondary metabolites therein were reported to display biological activities of importance to medicine, with e.g. antibacterial, anticancer, antifungal, and antiviral activities, rendering them possible candidates for the development of novel drug substances as well as for cosmetics. Herein, we provide an overview of the metabolite composition of resurrection species, summarize the latest reports related to the use of natural products from resurrection plants, and outline their potential for medical applications.

  2. Micropropagation of tulip: production of virus-free stock plants.

    Science.gov (United States)

    Podwyszyńska, Małgorzata; Sochacki, Dariusz

    2010-01-01

    We describe here a new tulip micropropagation method based on the cyclic shoot multiplication in presence of the thidiazuron (TDZ), which enables the production of virus-free stock plants, speeds up breeding, and provides new genotypes for the market. In our novel protocol, cyclic shoot multiplication can be performed for 2-3 years by using TDZ instead of other cytokinins, as 6-benzylaminopurine (BAP) and N(6)-(-isopentyl)adenine (2iP). It makes possible to produce 500-2,000 microbulbs from one healthy plant. There are six main stages of tulip micropropagation. Stage 0 is the selection of true-to-type and virus-free plants, confirmed by ELISA. Fragments of flower stems isolated from bulbs are used as initial explants. Shoot multiplication is based on the regeneration of adventitious shoots, which are sub-cultured every 8 weeks. In the Stage 3, the specially prepared shoots are induced by low temperature treatment to form bulbs which finally develop on a sucrose-rich medium at 20 degrees C. Bulbs are then dried for 6 weeks and rooted in vivo. The number of multiplication subcultures should be limited to 5-10 cycles in order to lower the risk of mutation. Virus indexing should be repeated 3-4 times, at the initial stage and then during shoot multiplication. Genetic stability of micropropagated shoots can be confirmed using molecular markers.

  3. In plant activation: an inducible, hyperexpression platform for recombinant protein production in plants.

    Science.gov (United States)

    Dugdale, Benjamin; Mortimer, Cara L; Kato, Maiko; James, Tess A; Harding, Robert M; Dale, James L

    2013-07-01

    In this study, we describe a novel protein production platform that provides both activation and amplification of transgene expression in planta. The In Plant Activation (INPACT) system is based on the replication machinery of tobacco yellow dwarf mastrevirus (TYDV) and is essentially transient gene expression from a stably transformed plant, thus combining the advantages of both means of expression. The INPACT cassette is uniquely arranged such that the gene of interest is split and only reconstituted in the presence of the TYDV-encoded Rep/RepA proteins. Rep/RepA expression is placed under the control of the AlcA:AlcR gene switch, which is responsive to trace levels of ethanol. Transgenic tobacco (Nicotiana tabacum cv Samsun) plants containing an INPACT cassette encoding the β-glucuronidase (GUS) reporter had negligible background expression but accumulated very high GUS levels (up to 10% total soluble protein) throughout the plant, within 3 d of a 1% ethanol application. The GUS reporter was replaced with a gene encoding a lethal ribonuclease, barnase, demonstrating that the INPACT system provides exquisite control of transgene expression and can be adapted to potentially toxic or inhibitory compounds. The INPACT gene expression platform is scalable, not host-limited, and has been used to express both a therapeutic and an industrial protein.

  4. Plant-microbe interactions: Plant hormone production by phylloplane fungi. Research report

    Energy Technology Data Exchange (ETDEWEB)

    Tuomi, T.; Ilvesoksa, J.; Rosenqvist, H.

    1993-06-23

    The molds Botrytis cinerea, Cladosporium cladosporioides and the yeast Aureobasidium pullulans, isolated from the leaves of three short-rotation Salix clones, were found to produce indole-3-acetic acid (a growth promoter of plants). Abscisic acid (a growth inhibitor of plants) production was detected in B. cinerea. The contents of indole-3-acetic acid and abscisic acid in the leaves of the Salix clones and the amounts of fungal propagules in these leaves were also measured, in order to evaluate whether the amounts of plant growth regulators produced by the fungi would make a significant contribution to the hormonal quantities of the leaves. The content of abscisic acid, and to a lesser degree that of indole-3-acetic acid, showed a positive correlation with the frequency of infection by the hormone producing organisms. The amounts of hormone producing fungi on leaves that bore visible colonies were, however, not sufficiently high to support the argument that neither the fungal production of abscisic nor indole-3-acetic acid would to a significant degree contribute to the hormonal contents of the leaves of the Salix clones.

  5. REMOVAL OF LEGACY PLUTONIUM MATERIALS FROM SWEDEN

    Energy Technology Data Exchange (ETDEWEB)

    Dunn, Kerry A. [Savannah River National Laboratory; Bellamy, J. Steve [Savannah River National Laboratory; Chandler, Greg T. [Savannah River National Laboratory; Iyer, Natraj C. [U.S. Department of Energy, National Nuclear Security Administration, Office of; Koenig, Rich E.; Leduc, D. [Savannah River National Laboratory; Hackney, B. [Savannah River National Laboratory; Leduc, Dan R. [Savannah River National Laboratory

    2013-08-18

    U.S. Department of Energy’s National Nuclear Security Administration (NNSA) Office of Global Threat Reduction (GTRI) recently removed legacy plutonium materials from Sweden in collaboration with AB SVAFO, Sweden. This paper details the activities undertaken through the U.S. receiving site (Savannah River Site (SRS)) to support the characterization, stabilization, packaging and removal of legacy plutonium materials from Sweden in 2012. This effort was undertaken as part of GTRI’s Gap Materials Program and culminated with the successful removal of plutonium from Sweden as announced at the 2012 Nuclear Security Summit. The removal and shipment of plutonium materials to the United States was the first of its kind under NNSA’s Global Threat Reduction Initiative. The Environmental Assessment for the U.S. receipt of gap plutonium material was approved in May 2010. Since then, the multi-year process yielded many first time accomplishments associated with plutonium packaging and transport activities including the application of the of DOE-STD-3013 stabilization requirements to treat plutonium materials outside the U.S., the development of an acceptance criteria for receipt of plutonium from a foreign country, the development and application of a versatile process flow sheet for the packaging of legacy plutonium materials, the identification of a plutonium container configuration, the first international certificate validation of the 9975 shipping package and the first intercontinental shipment using the 9975 shipping package. This paper will detail the technical considerations in developing the packaging process flow sheet, defining the key elements of the flow sheet and its implementation, determining the criteria used in the selection of the transport package, developing the technical basis for the package certificate amendment and the reviews with multiple licensing authorities and most importantly integrating the technical activities with the Swedish partners.

  6. INNOVATIVE FRESH WATER PRODUCTION PROCESS FOR FOSSIL FUEL PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    James F. Klausner; Renwei Mei; Yi Li; Mohamed Darwish; Diego Acevedo; Jessica Knight

    2003-09-01

    This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system, which is powered by the waste heat from low pressure condensing steam in power plants. The desalination is driven by water vapor saturating dry air flowing through a diffusion tower. Liquid water is condensed out of the air/vapor mixture in a direct contact condenser. A thermodynamic analysis demonstrates that the DDD process can yield a fresh water production efficiency of 4.5% based on a feed water inlet temperature of only 50 C. An example is discussed in which the DDD process utilizes waste heat from a 100 MW steam power plant to produce 1.51 million gallons of fresh water per day. The main focus of the initial development of the desalination process has been on the diffusion tower. A detailed mathematical model for the diffusion tower has been described, and its numerical implementation has been used to characterize its performance and provide guidance for design. The analysis has been used to design a laboratory scale diffusion tower, which has been thoroughly instrumented to allow detailed measurements of heat and mass transfer coefficient, as well as fresh water production efficiency. The experimental facility has been described in detail.

  7. PLUTONIUM LOADING CAPACITY OF REILLEX HPQ ANION EXCHANGE COLUMN - AFS-2 PLUTONIUM FLOWSHEET FOR MOX

    Energy Technology Data Exchange (ETDEWEB)

    Kyser, E.; King, W.; O' Rourke, P.

    2012-07-26

    Radioactive plutonium (Pu) anion exchange column experiments using scaled HB-Line designs were performed to investigate the dependence of column loading performance on the feed composition in the H-Canyon dissolution process for plutonium oxide (PuO{sub 2}) product shipped to the Mixed Oxide (MOX) Fuel Fabrication Facility (MFFF). These loading experiments show that a representative feed solution containing {approx}5 g Pu/L can be loaded onto Reillex{trademark} HPQ resin from solutions containing 8 M total nitrate and 0.1 M KF provided that the F is complexed with Al to an [Al]/[F] molar ratio range of 1.5-2.0. Lower concentrations of total nitrate and [Al]/[F] molar ratios may still have acceptable performance but were not tested in this study. Loading and washing Pu losses should be relatively low (<1%) for resin loading of up to 60 g Pu/L. Loading above 60 g Pu/L resin is possible, but Pu wash losses will increase such that 10-20% of the additional Pu fed may not be retained by the resin as the resin loading approaches 80 g Pu/L resin.

  8. The effect of the composition of plutonium loaded on the reactivity change and the isotopic composition of fuel produced in a fast reactor

    Science.gov (United States)

    Blandinskiy, V. Yu.

    2014-12-01

    This paper presents the results of a numerical investigation into burnup and breeding of nuclides in metallic fuel consisting of a mixture of plutonium and depleted uranium in a fast reactor with sodium coolant. The feasibility of using plutonium contained in spent nuclear fuel from domestic thermal reactors and weapons-grade plutonium is discussed. It is shown that the largest production of secondary fuel and the least change in the reactivity over the reactor lifetime can be achieved when employing plutonium contained in spent nuclear fuel from a reactor of the RBMK-1000 type.

  9. Modeling and control for closed environment plant production systems

    Science.gov (United States)

    Fleisher, David H.; Ting, K. C.; Janes, H. W. (Principal Investigator)

    2002-01-01

    A computer program was developed to study multiple crop production and control in controlled environment plant production systems. The program simulates crop growth and development under nominal and off-nominal environments. Time-series crop models for wheat (Triticum aestivum), soybean (Glycine max), and white potato (Solanum tuberosum) are integrated with a model-based predictive controller. The controller evaluates and compensates for effects of environmental disturbances on crop production scheduling. The crop models consist of a set of nonlinear polynomial equations, six for each crop, developed using multivariate polynomial regression (MPR). Simulated data from DSSAT crop models, previously modified for crop production in controlled environments with hydroponics under elevated atmospheric carbon dioxide concentration, were used for the MPR fitting. The model-based predictive controller adjusts light intensity, air temperature, and carbon dioxide concentration set points in response to environmental perturbations. Control signals are determined from minimization of a cost function, which is based on the weighted control effort and squared-error between the system response and desired reference signal.

  10. Preconceptual design for separation of plutonium and gallium by ion exchange

    Energy Technology Data Exchange (ETDEWEB)

    DeMuth, S.F.

    1997-09-30

    The disposition of plutonium from decommissioned nuclear weapons, by incorporation into commercial UO{sub 2}-based nuclear reactor fuel, is a viable means to reduce the potential for theft of excess plutonium. This fuel, which would be a combination of plutonium oxide and uranium oxide, is referred to as a mixed oxide (MOX). Following power generation in commercial reactors with this fuel, the remaining plutonium would become mixed with highly radioactive fission products in a spent fuel assembly. The radioactivity, complex chemical composition, and large size of this spent fuel assembly, would make theft difficult with elaborate chemical processing required for plutonium recovery. In fabricating the MOX fuel, it is important to maintain current commercial fuel purity specifications. While impurities from the weapons plutonium may or may not have a detrimental affect on the fuel fabrication or fuel/cladding performance, certifying the effect as insignificant could be more costly than purification. Two primary concerns have been raised with regard to the gallium impurity: (1) gallium vaporization during fuel sintering may adversely affect the MOX fuel fabrication process, and (2) gallium vaporization during reactor operation may adversely affect the fuel cladding performance. Consequently, processes for the separation of plutonium from gallium are currently being developed and/or designed. In particular, two separation processes are being considered: (1) a developmental, potentially lower cost and lower waste, thermal vaporization process following PuO{sub 2} powder preparation, and (2) an off-the-shelf, potentially higher cost and higher waste, aqueous-based ion exchange (IX) process. While it is planned to use the thermal vaporization process should its development prove successful, IX has been recommended as a backup process. This report presents a preconceptual design with material balances for separation of plutonium from gallium by IX.

  11. Options for converting excess plutonium to feed for the MOX fuel fabrication facility

    Energy Technology Data Exchange (ETDEWEB)

    Watts, Joe A [Los Alamos National Laboratory; Smith, Paul H [Los Alamos National Laboratory; Psaras, John D [Los Alamos National Laboratory; Jarvinen, Gordon D [Los Alamos National Laboratory; Costa, David A [Los Alamos National Laboratory; Joyce, Jr., Edward L [Los Alamos National Laboratory

    2009-01-01

    The storage and safekeeping of excess plutonium in the United States represents a multibillion-dollar lifecycle cost to the taxpayers and poses challenges to National Security and Nuclear Non-Proliferation. Los Alamos National Laboratory is considering options for converting some portion of the 13 metric tons of excess plutonium that was previously destined for long-term waste disposition into feed for the MOX Fuel Fabrication Facility (MFFF). This approach could reduce storage costs and security ri sks, and produce fuel for nuclear energy at the same time. Over the course of 30 years of weapons related plutonium production, Los Alamos has developed a number of flow sheets aimed at separation and purification of plutonium. Flow sheets for converting metal to oxide and for removing chloride and fluoride from plutonium residues have been developed and withstood the test oftime. This presentation will address some potential options for utilizing processes and infrastructure developed by Defense Programs to transform a large variety of highly impure plutonium into feedstock for the MFFF.

  12. Feasibility Study of Hydrogen Production at Existing Nuclear Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Schey

    2009-07-01

    Cooperative Agreement DE-FC07-06ID14788 was executed between the U.S. Department of Energy, Electric Transportation Applications, and Idaho National Laboratory to investigate the economics of producing hydrogen by electrolysis using electricity generated by nuclear power. The work under this agreement is divided into the following four tasks: Task 1 – Produce Data and Analyses Task 2 – Economic Analysis of Large-Scale Alkaline Electrolysis Task 3 – Commercial-Scale Hydrogen Production Task 4 – Disseminate Data and Analyses. Reports exist on the prospect that utility companies may benefit from having the option to produce electricity or produce hydrogen, depending on market conditions for both. This study advances that discussion in the affirmative by providing data and suggesting further areas of study. While some reports have identified issues related to licensing hydrogen plants with nuclear plants, this study provides more specifics and could be a resource guide for further study and clarifications. At the same time, this report identifies other area of risks and uncertainties associated with hydrogen production on this scale. Suggestions for further study in some of these topics, including water availability, are included in the report. The goals and objectives of the original project description have been met. Lack of industry design for proton exchange membrane electrolysis hydrogen production facilities of this magnitude was a roadblock for a significant period. However, recent design breakthroughs have made costing this facility much more accurate. In fact, the new design information on proton exchange membrane electrolyzers scaled to the 1 kg of hydrogen per second electrolyzer reduced the model costs from $500 to $100 million. Task 1 was delayed when the original electrolyzer failed at the end of its economic life. However, additional valuable information was obtained when the new electrolyzer was installed. Products developed during this study

  13. Is plutonium really necessary

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, V.

    1976-09-09

    Not all activities associated with nuclear power contribute equally to proliferation potential, but some fuel-cycle activities (i.e., reprocessing) are considered too dangerous to be permitted in non-weapons countries. This paper assesses the feasibility of keeping Pu out of the nuclear fuel cycle. It is pointed out that there is no technical necessity of using Pu as nuclear fuel so long as /sup 235/U is available. Analysis of the economics of recycling spent fuel products in LWRs in the U.S. shows that the net economic benefit of recycle is uncertain and might even be negative; it will have an insignificant effect on the cost of nuclear power. It is argued that reprocessing of spent fuel be deferred until recycle in LWRs can be shown to yield economic benefits sufficiently large to compensate for the risks, or the viability of the breeder as an important commercial source of power has been demonstrated. According to the low estimate of U requirements, the world would have enough U resources well into the 21st century, although if the high estimate is used, the world would exhaust its reserves by the year 2000. Evidence indicates that nuclear power will grow more slowly than the forecasts of the nuclear advocates. Thus, there may be no need for an early decision to undertake recycling, and research on breeder development can proceed at a slower rate. (DLC)

  14. INNOVATIVE FRESH WATER PRODUCTION PROCESS FOR FOSSIL FUEL PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight

    2004-09-01

    An innovative Diffusion Driven Desalination (DDD) process was recently described where evaporation of mineralized water is driven by diffusion within a packed bed. The energy source to drive the process is derived from low pressure condensing steam within the main condenser of a steam power generating plant. Since waste heat is used to drive the process, the main cost of fresh water production is attributed to the energy cost of pumping air and water through the packed bed. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A combined thermodynamic and dynamic analysis demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3'' Hg. Throughout the past year, the main focus of the desalination process has been on the diffusion tower and direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. An experimental DDD facility has been fabricated, and temperature and humidity data have been collected over a range of flow and thermal conditions. The analyses agree quite well with the current data and the information available in the literature. Direct contact condensers with and without packing have been investigated. It has been experimentally observed that the fresh water production rate is significantly enhanced when packing is added to the direct contact condensers.

  15. Plutonium focus area. Technology summary

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-09-01

    The Assistant Secretary for the Office of Environmental Management (EM) at the U.S. Department of Energy (DOE) chartered the Plutonium Focus Area (PFA) in October 1995. The PFA {open_quotes}...provides for peer and technical reviews of research and development in plutonium stabilization activities...{close_quotes} In addition, the PFA identifies and develops relevant research and technology. The purpose of this document is to focus attention on the requirements used to develop research and technology for stabilization, storage, and preparation for disposition of nuclear materials. The PFA Technology Summary presents the approach the PFA uses to identify, recommend, and review research. It lists research requirements, research being conducted, and gaps where research is needed. It also summarizes research performed by the PFA in the traditional research summary format. This document encourages researchers and commercial enterprises to do business with PFA by submitting research proposals or {open_quotes}white papers.{close_quotes} In addition, it suggests ways to increase the likelihood that PFA will recommend proposed research to the Nuclear Materials Stabilization Task Group (NMSTG) of DOE.

  16. Studies on saponin production in tropical medicinal plants Maesa argentea and Maesa lanceolata

    Science.gov (United States)

    Faizal, Ahmad; Geelen, Danny

    2015-09-01

    The continuous need for new compounds with important medicinal activities has lead to the identification and characterization of various plant-derived natural products. As a part of this program, we studied the saponin production from two tropical medicinal plants Maesa argentea and M. lanceolata and evaluated several treatments to enhance their saponin production. In this experiment, we present the analyses of saponin production from greenhouse grown plants by means of TLC and HPLC-MS. We observed that the content of saponin from these plants varied depending on organ and physiological age of the plants. In addition, the impact of elicitors on saponin accumulation on in vitro grown plants was analyzed using TLC. The production of saponin was very stable and not affected by treatment with methyl jasmonate, and salicylic acid. In conclusion, Maesa saponins are constitutively produced in plants and the level of these compounds in plants is mainly affected by the developmental or physiological stage.

  17. In vitro study of natural plant products against oral bacteria

    Institute of Scientific and Technical Information of China (English)

    Siddiqui R; Siti AsmaH; Tang L; Jie CC; Rosliza AR; Roziawati Y

    2009-01-01

    Objective:To analyze the effect of selected plant product against several bacterial which commonly causes oral infection.It was hope that in future,this product will become the remedy for treatment of oral infection and with the hope that it can substitute antibiotics.Methods:A total of 5 species of oral bacteria from American Type Culture Collection (ATCC)were employed in this study(S.mutans,S.aureus,P.aeruginosa,S.sobri-nus and L.salivarius).Three types of natural plants crude extracts were used (garlic,curry leaves and cloves).Bactericidal and bacteriostatic effects of these herbs were tested.Results:It was shown garlic had an-tibacterial effects on all bacteria.The Minimal Inhibitory Concentration (MIC in g/mL)of garlic towards S. aureus,P.aeruginosa,S.mutans,S.sobrinus and L.salivarius were 0.3,1.8,1.2,0.5 and 1.8,respectively. There was significant difference among the MIC of garlic on tested bacteria.It was more potent toward S.au-reus.The curry leaf solution on the other hand,did not show any zone of inhibition in all bacteria plates but adversely showed enhanced growth of those bacteria.Clove had shown its antibacterial effects on S.aureus and P.aeruginosa.The clove was more potent toward S.aureus with the MIC of 0.45 g/mL.P.aeruginosa was more sensitive to clove compared to garlic.For S.aureus,it was more sensitive to garlic compared to clove. Conclusion:The antibacterial activity of garlic and clove crude extracts shown in our study further confirm these natural plants'potential usage in therapeutic use for oral diseases or infections.This could be the platform for the interested party to do research and development on it and to produce oral health products which are more affordable for lower economic income groups and with fewer side effects as seen in synthetic drug.

  18. Effect of Pot Size on Various Characteristics Related to Photosynthetic Matter Production in Soybean Plants

    OpenAIRE

    Minobu Kasai; Keisuke Koide; Yuya Ichikawa

    2012-01-01

    Despite the wide uses of potted plants, information on how pot size affects plant photosynthetic matter production is still considerably limited. This study investigated with soybean plants how transplantation into larger pots affects various characteristics related to photosynthetic matter production. The transplantation was analyzed to increase leaf photosynthetic rate, transpiration rate, and stomatal conductance without affecting significantly leaf intercellular CO2 concentration, implica...

  19. Influence of ingredients of motor transport exhausts on the seed productivity of adornment flowering plants

    Directory of Open Access Journals (Sweden)

    О. P. Pryimak

    2009-03-01

    Full Text Available Basic descriptions of the seminal productivity for some ornamental flowering plants under influence of cars’ emissions are presented. Decreasing of the seminal productivity, germinating capacity of seeds and mass of thousand seeds was found. Recommendations on plants using for planting of the cities environment polluted by vehicles emissions are proposed.

  20. Plutonium isotopes in the terrestrial environment at the Savannah River Site, USA: a long-term study.

    Science.gov (United States)

    Armstrong, Christopher R; Nuessle, Patterson R; Brant, Heather A; Hall, Gregory; Halverson, Justin E; Cadieux, James R

    2015-02-01

    This work presents the findings of a long-term plutonium (Pu) study at Savannah River Site (SRS) conducted between 2003 and 2013. Terrestrial environmental samples were obtained at the Savannah River National Laboratory (SRNL) in the A-Area. Plutonium content and isotopic abundances were measured over this time period by α particle and thermal ionization mass spectrometry (3STIMS). We detail the complete process of the sample collection, radiochemical separation, and measurement procedure specifically targeted to trace plutonium in bulk environmental samples. Total plutonium activities were determined to be not significantly above atmospheric global fallout. However, the (238)Pu/(239+240)Pu activity ratios attributed to SRS are substantially different than fallout due to past (238)Pu production on the site. The (240)Pu/(239)Pu atom ratios are reasonably consistent from year to year and are lower than fallout indicating an admixture of weapons-grade material, while the (242)Pu/(239)Pu atom ratios are higher than fallout values, again due to actinide production activities. Overall, the plutonium signatures obtained in this study reflect a distinctive mixture of weapons-grade, heat source, and higher burn-up plutonium with fallout material. This study provides a unique opportunity for developing and demonstrating a blue print for long-term low-level monitoring of trace plutonium in the environment.

  1. Altered sucrose metabolism impacts plant biomass production and flower development.

    Science.gov (United States)

    Coleman, Heather D; Beamish, Leigh; Reid, Anya; Park, Ji-Young; Mansfield, Shawn D

    2010-04-01

    Nicotiana tabacum (tobacco) was transformed with three genes involved in sucrose metabolism, UDP-glucose pyrophosphorylase (UGPase, EC 2.7.7.9), sucrose synthase (SuSy, EC 2.4.1.13) and sucrose phosphate synthase (SPS, EC 2.4.1.14). Plants harbouring the single transgenes were subsequently crossed to produce double and triple transgenic lines, including: 2 x 35S::UGPase x SPS, 4CL::UGPase x SPS, 2 x 35S::SuSy x SPS, 4CL::SuSy x SPS, 2 x 35S::UGPase x SuSy x SPS, and 4CL::UGPase x SuSy x SPS. The ultimate aim of the study was to examine whether it is possible to alter cellulose production through the manipulation of sucrose metabolism genes. While altering sucrose metabolism using UGPase, SuSy and SPS does not have an end effect on cellulose production, their simultaneous overexpression resulted in enhanced primary growth as seen in an increase in height growth, in some cases over 50%. Furthermore, the pyramiding strategy of simultaneously altering the expression of multiple genes in combination resulted in increased time to reproductive bud formation as well as altered flower morphology and foliar stipule formation in 4CL lines. Upregulation of these sucrose metabolism genes appears to directly impact primary growth and therefore biomass production in tobacco.

  2. Management of pests and diseases of tropical sericultural plants by using plant-derived products:a review

    Institute of Scientific and Technical Information of China (English)

    R T Gahukar

    2015-01-01

    Host plants of domesticated silkworms in tropical countries are attacked by an array of insect pests, disease pathogens and nematodes. In order to reduce resulting plant damage, chemicals have been extensively used. In recent years, products extracted/isolated from 47 plant species have been tested as replacements for or to minimize the use of hazardous chemicals. Bioefficacy of the extract in water or chemical solvent, crude seed/leaf oil, and cake is discussed, and integrated management of major and occasional pests and plant diseases is proposed in sericultural plants in order to produce chemical-free foliage.

  3. Study of Pu consumption in Advanced Light Water Reactors. Evaluation of GE Advanced Boiling Water Reactor plants

    Energy Technology Data Exchange (ETDEWEB)

    1993-05-13

    Timely disposal of the weapons plutonium is of paramount importance to permanently safeguarding this material. GE`s 1300 MWe Advanced Boiling Water Reactor (ABWR) has been designed to utilize fill] core loading of mixed uranium-plutonium oxide fuel. Because of its large core size, a single ABWR reactor is capable of disposing 100 metric tons of plutonium within 15 years of project inception in the spiking mode. The same amount of material could be disposed of in 25 years after the start of the project as spent fuel, again using a single reactor, while operating at 75 percent capacity factor. In either case, the design permits reuse of the stored spent fuel assemblies for electrical energy generation for the remaining life of the plant for another 40 years. Up to 40 percent of the initial plutonium can also be completely destroyed using ABWRS, without reprocessing, either by utilizing six ABWRs over 25 years or by expanding the disposition time to 60 years, the design life of the plants and using two ABWRS. More complete destruction would require the development and testing of a plutonium-base fuel with a non-fertile matrix for an ABWR or use of an Advanced Liquid Metal Reactor (ALMR). The ABWR, in addition, is fully capable of meeting the tritium target production goals with already developed target technology.

  4. Review of current research on hydrocarbon production by plants

    Energy Technology Data Exchange (ETDEWEB)

    Benedict, H. M.; Inman, B.

    1979-01-01

    This review assesses the status of research and development in the area of plants that produce hydrocarbons as a possible replacement for traditional fossil fuels. The information is meant to be used as a basis for determining the scope of a possible R and D program by DOE/FFB. Except in the case of guayule (Parthenium argentatum Gray), research on hydrocarbon species generally has not advanced beyond preliminary screening, extraction, and growth studies. Virtually no field studies have been initiated; hydrocarbon component extraction, separation, identification, and characterization have been only timidly approached; the biochemistry of hydrocarbon formation remains virtually untouched; and potential market analysis has been based on insufficient data. Research interest is increasing in this area, however. Industrial interest understandably centers about guayule prospects and is supplemented by NSF and DOE research funds. Additional support for other research topics has been supplied by DOE and USDA and by certain university systems. Due to the infant state of technology in this area of energy research, it is not possible to predict or satisfactorily assess at this time the potential contribution that plant hydrocarbons might make toward decreasing the nation's dependence upon petroleum. However, the general impression received from experts interviewed during this review was that the major thrust of research should be directed toward the manufacture of petrochemical substitutes rather than fuel production.

  5. Ultrapure Gases — From the Production Plant to the Laboratory

    Science.gov (United States)

    Simgen, H.; Zuzel, G.

    2007-03-01

    Radioactive noble gas isotopes are a potential source of background in low-level physics experiments, since they are present in the atmosphere and also in widely used gases produced from the atmosphere. We have studied the 39Ar, 85Kr and 222Rn contamination of commercially available nitrogen using low background proportional counters and a rare gas mass spectrometer. It was found that air separation plants are very effective in removing traces of radioactive noble gases and that the available purity can be significantly higher than commercial specifications. On the other hand the gas handling processes which are necessary to deliver gases from the production plant to the customer are a possible source of re-contaminations and determine in most cases the achievable purity. By simulating these processes under realistic conditions we have establish together with the Italian company `SOL group' a well controlled delivery path which can hold the purity. For the short-lived 222Rn the initial contamination is less critical, because it decays away. Instead the emanation rate of the cryogenic tank was found to determine the achievable purity, since it permanently delivers new 222Rn.

  6. PREVENTION AND CONTROL OF DIMETHYLAMINE VAPORS EMISSION: HERBICIDE PRODUCTION PLANT

    Directory of Open Access Journals (Sweden)

    Zorana Arsenijević

    2008-11-01

    Full Text Available The widely used herbicide, dimethylamine salt of 2,4-dichlorophenoxy acetic acid (2,4-D-DMA, is usually prepared by mixing a dimethylamine (DMA aqueous solution with a solid 2,4-dichlorophenoxy acetic acid (2,4-D. The vapors of the both, reactants and products, are potentially hazardous for the environment. The contribution of DMA vapors in overall pollution from this process is most significant, concerning vapor pressures data of these pollutants. Therefore, the control of the air pollution in the manufacture and handling of methylamines is very important. Within this paper, the optimal air pollution control system in preparation of 2,4-D-DMA was developed for the pesticides manufacturing industry. This study employed the simple pollution prevention concept to reduce the emission of DMA vapors at the source. The investigations were performed on the pilot plant scale. To reduce the emission of DMA vapors, the effluent gases from the herbicide preparation zone were passed through the packed bed scrubber (water - scrubbing medium, and the catalytic reactor in sequence. The end result is a substantially improved air quality in the working area, as well as in the urbanized areas located near the chemical plant.

  7. [Instrumental analysis of medicinal plants and their drug products].

    Science.gov (United States)

    Petri, G; Lemberkovics, E

    1994-05-01

    The experiences obtained during the development of gas chromatographic and other (GC, TLC and infrared spectrophotometric) methods for the 7th edition of the Hungarian Pharmacopoeia for essential oils and drugs containing essential oils are summarized with emphasis on the selection of suitable internal standard for the gas chromatographic assays. The qualitative and quantitative estimation of bitter compounds and polyphenoles e.g. flavonoids and procyanidines by means of ultraviolet and infrared spectrophotometry and HPLC is also described. Some HPLC methods for the determination of anthocyan and carotinoid derivatives are also presented. These are not yet included in the pharmacopoeia but are successfully used for the analytical investigation of commercially available medicinal plants and drug products made thereof.

  8. Excess Weapons Plutonium Immobilization in Russia

    Energy Technology Data Exchange (ETDEWEB)

    Jardine, L.; Borisov, G.B.

    2000-04-15

    The joint goal of the Russian work is to establish a full-scale plutonium immobilization facility at a Russian industrial site by 2005. To achieve this requires that the necessary engineering and technical basis be developed in these Russian projects and the needed Russian approvals be obtained to conduct industrial-scale immobilization of plutonium-containing materials at a Russian industrial site by the 2005 date. This meeting and future work will provide the basis for joint decisions. Supporting R&D projects are being carried out at Russian Institutes that directly support the technical needs of Russian industrial sites to immobilize plutonium-containing materials. Special R&D on plutonium materials is also being carried out to support excess weapons disposition in Russia and the US, including nonproliferation studies of plutonium recovery from immobilization forms and accelerated radiation damage studies of the US-specified plutonium ceramic for immobilizing plutonium. This intriguing and extraordinary cooperation on certain aspects of the weapons plutonium problem is now progressing well and much work with plutonium has been completed in the past two years. Because much excellent and unique scientific and engineering technical work has now been completed in Russia in many aspects of plutonium immobilization, this meeting in St. Petersburg was both timely and necessary to summarize, review, and discuss these efforts among those who performed the actual work. The results of this meeting will help the US and Russia jointly define the future direction of the Russian plutonium immobilization program, and make it an even stronger and more integrated Russian program. The two objectives for the meeting were to: (1) Bring together the Russian organizations, experts, and managers performing the work into one place for four days to review and discuss their work with each other; and (2) Publish a meeting summary and a proceedings to compile reports of all the excellent

  9. Ultra-Small Plutonium Oxide Nanocrystals: An Innovative Material in Plutonium Science

    OpenAIRE

    HUDRY DAMIEN; Griveau, Jean-Christophe; Apostolidis, Christos; WALTER OLAF; Janssen, Arne; Manara, Dario; Colineau, Eric; VITOVA T.; Wang, Di; KUEBEL Christian; MEYER D.j.m.

    2013-01-01

    Apart from its sensitive technological importance, plutonium (Pu) is also one of the most intriguing elements because of its non-conventional physical properties and fascinating chemistry. Those fundamental aspects are particularly interesting when dealing with the challenging study of plutonium-based nanomaterials. Here we show that ultra-small (3.2  0.9 nm) and highly crystalline plutonium oxide (PuO2) nanocrystals (NCs) can be synthesized by the thermal decomposition of plutonyl nitrate (...

  10. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    Energy Technology Data Exchange (ETDEWEB)

    Thomas Robl; John Groppo

    2005-09-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. A mobile demonstration unit has been designed and constructed for field demonstration. The demonstration unit was hauled to the test site on trailers that were place on a test pad located adjacent to the ash pond and re-assembled. The continuous test unit will be operated at the Ghent site and will evaluate three processing configurations while producing sufficient products to facilitate thorough product testing. The test unit incorporates all of the unit processes that will be used in the commercial design and is self sufficient with respect to water, electricity and processing capabilities. Representative feed ash for the operation of the filed testing unit was excavated from a location within the lower ash pond determined from coring activities. Approximately 150 tons of ash was excavated and pre-screened to remove +3/8 inch material that could cause plugging problems during operation of the demonstration unit.

  11. Innovative Fresh Water Production Process for Fossil Fuel Plants

    Energy Technology Data Exchange (ETDEWEB)

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight; Venugopal Jogi

    2005-09-01

    This project concerns a diffusion driven desalination (DDD) process where warm water is evaporated into a low humidity air stream, and the vapor is condensed out to produce distilled water. Although the process has a low fresh water to feed water conversion efficiency, it has been demonstrated that this process can potentially produce low cost distilled water when driven by low grade waste heat. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A dynamic analysis of heat and mass transfer demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3 Hg. The optimum operating condition for the DDD process with a high temperature of 50 C and sink temperature of 25 C has an air mass flux of 1.5 kg/m{sup 2}-s, air to feed water mass flow ratio of 1 in the diffusion tower, and a fresh water to air mass flow ratio of 2 in the condenser. Operating at these conditions yields a fresh water production efficiency (m{sub fW}/m{sub L}) of 0.031 and electric energy consumption rate of 0.0023 kW-hr/kg{sub fW}. Throughout the past year, the main focus of the desalination process has been on the direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. The analyses agree quite well with the current data. Recently, it has been recognized that the fresh water production efficiency can be significantly enhanced with air heating. This type of configuration is well suited for power plants utilizing air-cooled condensers. The experimental DDD facility has been modified with an air heating section, and temperature and humidity data have been collected over a range of flow and thermal conditions. It has been experimentally observed that the fresh water production rate is enhanced when air

  12. Chemical composition of buckwheat plant parts and selected buckwheat products

    Directory of Open Access Journals (Sweden)

    Petra Vojtíšková

    2014-11-01

    Full Text Available Chemical composition plant parts (roots, stalks, leaves, blossoms of common buckwheat (Fagopyrum esculentum Moench and selected products made from its seeds (peels, whole seed, wholemeal flour, broken seeds, crunchy products Natural and Cocoa, flour, and pasta was determined. Samples were dried and ground to a fine powder. All analyses were performed according to the Commission Regulation no. 152/2009, while rutin concentration was determined by the modified HPLC method. The lowest content of moisture was found in roots (4.3% and in peels (almost 8% and the highest moisture (nearly 11% was discovered in seeds. The lowest amount of crude protein (3.5% was found in peels, the highest crude protein amount (>13% in both flours and leaves (23%. The starch content (>50% in dry matter differs from one sample to another. Only in peels the content of starch was about 3.5%. From all examined samples, the lowest content of fat was found in crunchy products Cocoa, 1.7%. The lowest amount of histidine was determined in all studied samples, except peels, the highest content of glutamic acid was determined in almost all samples, except peels. Whole-meal flour is very rich source of Ca and Fe. The content of these elements was 1172 mg.kg-1 and 45.9 mg.kg-1, respectively. On the other hand, the highest content of Pb (>1 mg.kg-1 was found in broken seeds. The greatest concentration of rutin was determined in blossoms and leaves (83.6 and 69.9 mg.g-1, respectively. On the other hand, the lowest concentrations of rutin were found in buckwheat products (generally less then 1 mg.g-1, i.e. in wholemeal flour, 702 μg.kg-1, the lowest almost 10 μg.kg-1 in pasta.

  13. 9 CFR 590.26 - Egg products entering or prepared in official plants.

    Science.gov (United States)

    2010-01-01

    ... 9 Animals and Animal Products 2 2010-01-01 2010-01-01 false Egg products entering or prepared in..., DEPARTMENT OF AGRICULTURE EGG PRODUCTS INSPECTION INSPECTION OF EGGS AND EGG PRODUCTS (EGG PRODUCTS INSPECTION ACT) Scope of Inspection § 590.26 Egg products entering or prepared in official plants. Eggs...

  14. Production of hydroxylated fatty acids in genetically modified plants

    Energy Technology Data Exchange (ETDEWEB)

    Somerville, Chris (Portola Valley, CA); Broun, Pierre (Burlingame, CA); van de Loo, Frank (Weston, AU); Boddupalli, Sekhar S. (Manchester, MI)

    2011-08-23

    This invention relates to plant fatty acyl hydroxylases. Methods to use conserved amino acid or nucleotide sequences to obtain plant fatty acyl hydroxylases are described. Also described is the use of cDNA clones encoding a plant hydroxylase to produce a family of hydroxylated fatty acids in transgenic plants. In addition, the use of genes encoding fatty acid hydroxylases or desaturases to alter the level of lipid fatty acid unsaturation in transgenic plants is described.

  15. Plants with modified lignin content and methods for production thereof

    Science.gov (United States)

    Zhao, Qiao; Chen, Fang; Dixon, Richard A.

    2014-08-05

    The invention provides methods for decreasing lignin content and for increasing the level of fermentable carbohydrates in plants by down-regulation of the NST transcription factor. Nucleic acid constructs for down-regulation of NST are described. Transgenic plants are provided that comprise reduced lignin content. Plants described herein may be used, for example, as improved biofuel feedstock and as highly digestible forage crops. Methods for processing plant tissue and for producing ethanol by utilizing such plants are also provided.

  16. Modelling production processes in a vehicle recycling plant.

    Science.gov (United States)

    Simic, Vladimir; Dimitrijevic, Branka

    2012-09-01

    The European Directive on end-of-life vehicles (ELVs) fundamentally changed the business philosophy of the European vehicle recycling system, which was exclusively profit-oriented. As the dominant participants of this system, vehicle recycling plants (VRPs) are especially affected by its implementation. For VRPs to successfully respond to the prescribed eco-efficiency quotas, investment will be needed to procure modern sorting equipment as well as to achieve full transformation of their production process. However, before VRPs decide to make this very important investment decision, it is necessary to determine the adequacy of such a decision in detail. Consequently, the following questions become unavoidable: Can modernly equipped VRPs conduct profitable business? Are eco-efficiency quotas actually attainable? How will the new changes in vehicle design influence VRPs? To provide answers to these essential questions, a production planning model of a modernly equipped VRP was first developed and then tested extensively using real data. Based on the answers provided by the proposed model testing analysis it was concluded that VRP transformation is not only necessary but completely justified and that the final success of the ELV Directive is realistic.

  17. FORM AND AGING OF PLUTONIUM IN SAVANNAH RIVER SITE WASTE TANK 18

    Energy Technology Data Exchange (ETDEWEB)

    Hobbs, D.

    2012-02-24

    This report provides a summary of the effects of aging on and the expected forms of plutonium in Tank 18 waste residues. The findings are based on available information on the operational history of Tank 18, reported analytical results for samples taken from Tank 18, and the available scientific literature for plutonium under alkaline conditions. These findings should apply in general to residues in other waste tanks. However, the operational history of other waste tanks should be evaluated for specific conditions and unique operations (e.g., acid cleaning with oxalic acid) that could alter the form of plutonium in heel residues. Based on the operational history of other tanks, characterization of samples from the heel residues in those tanks would be appropriate to confirm the form of plutonium. During the operational period and continuing with the residual heel removal periods, Pu(IV) is the dominant oxidation state of the plutonium. Small fractions of Pu(V) and Pu(VI) could be present as the result of the presence of water and the result of reactions with oxygen in air and products from the radiolysis of water. However, the presence of Pu(V) would be transitory as it is not stable at the dilute alkaline conditions that currently exists in Tank 18. Most of the plutonium that enters Savannah River Site (SRS) high-level waste (HLW) tanks is freshly precipitated as amorphous plutonium hydroxide, Pu(OH){sub 4(am)} or hydrous plutonium oxide, PuO{sub 2(am,hyd)} and coprecipitated within a mixture of hydrous metal oxide phases containing metals such as iron, aluminum, manganese and uranium. The coprecipitated plutonium would include Pu{sup 4+} that has been substituted for other metal ions in crystal lattice sites, Pu{sup 4+} occluded within hydrous metal oxide particles and Pu{sup 4+} adsorbed onto the surface of hydrous metal oxide particles. The adsorbed plutonium could include both inner sphere coordination and outer sphere coordination of the plutonium. PuO{sub 2

  18. PLUTONIUM METALLOGRAPHY AT LOS ALAMOS

    Energy Technology Data Exchange (ETDEWEB)

    PEREYRA, RAMIRO A. [Los Alamos National Laboratory; LOVATO, DARRYL [Los Alamos National Laboratory

    2007-01-08

    From early days of the Manhattan program to today, scientists and engineers have continued to investigate the metallurgical properties of plutonium (Pu). Although issues like aging was not a concern to the early pioneers, today the reliability of our aging stockpile is of major focus. And as the country moves toward a new generation of weapons similar problems that the early pioneers faced such as compatibility, homogeneity and malleability have come to the forefront. And metallography will continue to be a principle tool for the resolution of old and new issues. Standard metallographic techniques are used for the preparation of plutonium samples. The samples are first cut with a slow speed idamond saw. After mounting in Epon 815 epoxy resin, the samples are ground through 600 grit silicon carbide paper. PF 5070 (a Freon substitute) is used as a coolant, lubricant, and solvent for most operations. Rough mechanical polished is done with 9-{mu} diamond using a nap less cloth, for example nylon or cotton. Final polish is done with 1-{mu} diamond on a nappy cloth such as sylvet. Ethyl alcohol is then used ultrasonically to clean the samples before electro polishing. The sample is then electro-polished and etched in an electrolyte containing 10% nitric acid, and 90% dimethyleneformalmide. Ethyl alcohol is used as a final cleaning agent. Although standard metallographic preparation techniques are used, there are several reasons why metallography of Pu is difficult and challenging. Firstly, because of the health hazards associated with its radioactive properties, sample preparation is conducted in glove boxes. Figure 1 shows the metallography line, in an R and D facility. Since they are designed to be negative in pressure to the laboratory, cross-contamination of abrasives is a major problem. In addition, because of safety concerns and waste issues, there is a limit to the amount of solvent that can be used. Secondly, Pu will readily hydride or oxidize when in contact

  19. Biofuel Production by Fermentation of Water Plants and Agricultural Lignocellulosic by-Products

    Directory of Open Access Journals (Sweden)

    Anker Yaakov

    2016-01-01

    Full Text Available While at present most energy crops are depriving human feedstock, fermentation of agricultural residues and fast growing water plants possesses a good prospect to become a significant source for bio-fuel; as both substrates are widely available and do not require agricultural areas. Water hyacinth for instance can be cultivated in fresh, brackish or wastewater and owing to its rapid growth and availability. Since owing to its natural abundance it is considered to be an invasive plant in most continents, its utilization and use as a renewable energy source may also contribute for its dilution and control. Agricultural lignocellulosic surplus by-products are also a promising fermentable substrate for bioethanol production, as it decreases both disposal expenses and greenhouse gases emissions. This paper describes a scheme and methodology for transformation of any lignocellulosic biomass into biofuel by simple cost effective operation scheme, integrating an innovative process of mechanochemical activation pre-treatment followed by fermentation of the herbal digest and ethanol production through differential distillation. Under this approach several complex and costly staged of conventional ethanol production scheme may be replaced and by genetic engineering of custom fermenting microorganisms the fermentation process becomes a fully continuous industrial process.

  20. Plutonium focus area: Technology summary

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    To ensure research and development programs focus on the most pressing environmental restoration and waste management problems at the U.S. Department of Energy (DOE), the Assistant Secretary for the Office of Environmental Management (EM) established a working group in August 1993 to implement a new approach to research and technology development. As part of this approach, EM developed a management structure and principles that led to creation of specific focus areas. These organizations were designed to focus scientific and technical talent throughout DOE and the national scientific community on major environmental restoration and waste management problems facing DOE. The focus area approach provides the framework for inter-site cooperation and leveraging of resources on common problems. After the original establishment of five major focus areas within the Office of Technology Development (EM-50), the Nuclear Materials Stabilization Task Group (NMSTG, EM-66) followed EM-50`s structure and chartered the Plutonium Focus Area (PFA). NMSTG`s charter to the PFA, described in detail later in this book, plays a major role in meeting the EM-66 commitments to the Defense Nuclear Facilities Safety Board (DNFSB). The PFA is a new program for FY96 and as such, the primary focus of revision 0 of this Technology Summary is an introduction to the Focus Area; its history, development, and management structure, including summaries of selected technologies being developed. Revision 1 to the Plutonium Focus Area Technology Summary is slated to include details on all technologies being developed, and is currently planned for release in August 1996. The following report outlines the scope and mission of the Office of Environmental Management, EM-60, and EM-66 organizations as related to the PFA organizational structure.

  1. Indirect drivers of plant diversity-productivity relationship in semiarid sandy grasslands

    Directory of Open Access Journals (Sweden)

    X. A. Zuo

    2012-04-01

    Full Text Available Although patterns between plant diversity and ecosystem productivity have been much studied, a consistent relationship has not yet emerged. Differing patterns between plant diversity and productivity have been observed in response to spatial variability of environmental factors and vegetation composition. In this study, we measured vegetation cover, plant diversity, productivity, soil properties and site characteristics along an environmental gradient (mobile dune, semi-fixed dune, fixed dune, dry meadow, wet meadow and flood plain grasslands of natural sandy grasslands in semiarid areas of northern China. We used multivariate analysis to examine the relationships between environmental factors, vegetation composition, plant diversity and productivity. We found a positive correlation between plant diversity and productivity. Vegetation composition aggregated by the ordination technique of non-metric multidimensional scaling had also a significantly positive correlation with plant diversity and productivity. Environmental gradients in relation to soil and topography affected the distribution patterns of vegetation composition, species diversity and productivity. However, environmental gradients were a better determinant of vegetation composition and productivity than of plant diversity. Structural equation modeling suggested that environmental factors determine vegetation composition, which in turn independently drives both plant diversity and productivity. Thus, the positive correlation between plant diversity and productivity is indirectly driven by vegetation composition, which is determined by environmental gradients in soil and topography.

  2. Interaction between stainless steel and plutonium metal

    Energy Technology Data Exchange (ETDEWEB)

    Dunwoody, John T [Los Alamos National Laboratory; Mason, Richard E [Los Alamos National Laboratory; Freibert, Franz J [Los Alamos National Laboratory; Willson, Stephen P [Los Alamos National Laboratory; Veirs, Douglas K [Los Alamos National Laboratory; Worl, Laura A [Los Alamos National Laboratory; Archuleta, Alonso [Los Alamos National Laboratory; Conger, Donald J [Los Alamos National Laboratory

    2010-01-01

    Long-term storage of excess plutonium is of great concern in the U.S. as well as abroad. The current accepted configuration involves intimate contact between the stored material and an iron-bearing container such as stainless steel. While many safety scenario studies have been conducted and used in the acceptance of stainless steel containers, little information is available on the physical interaction at elevated temperatures between certain forms of stored material and the container itself. The bulk of the safety studies has focused on the ability of a package to keep the primary stainless steel containment below the plutonium-iron eutectic temperature of approximately 410 C. However, the interactions of plutonium metal with stainless steel have been of continuing interest. This paper reports on a scoping study investigating the interaction between stainless steel and plutonium metal in a pseudo diffusion couple at temperatures above the eutectic melt-point.

  3. Laboratory Building for Accurate Determination of Plutonium

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>The accurate determination of plutonium is one of the most important assay techniques of nuclear fuel, also the key of the chemical measurement transfer and the base of the nuclear material balance. An

  4. The effects of smoking and lung health on the organ retention of different plutonium compounds in the Mayak PA workers.

    Science.gov (United States)

    Suslova, K G; Sokolova, A B; Krahenbuhl, M P; Miller, S C

    2009-03-01

    The purpose of this study was to determine the effects of smoking and lung health on the pulmonary and extrapulmonary retention after inhalation of different chemical forms of plutonium with different solubilities in workers from the Mayak Production Association (Ozersk, Russia). Samples of lung, pulmonary lymph nodes, liver and skeleton were obtained from 800 workers who died between 1962-2000. The chemical form of plutonium aerosols, smoking history and presence of lung disease were determined. In workers with normal lung status, all plutonium chemical classes were about equally distributed between the lung parenchyma and pulmonary lymph nodes. The more insoluble chemical forms of plutonium had a greater retention in pulmonary than systemic tissues regardless of smoking history or lung health status. A history of smoking did, however, result in a significantly greater retention of less soluble chemical forms of plutonium in pulmonary tissues of workers with no lung disease. In workers with lung disease, smoking did not significantly influence the terminal organ retention of the different chemical forms of plutonium. These initial data can be used to modify dosimetry and biokinetics models used for estimating radiation risks from plutonium in humans.

  5. The Impact of Implementation of Total quality Management on Plants' Productivity: Evidence from Poultry Processing Plants- Saudi Arabia- Central Region

    Directory of Open Access Journals (Sweden)

    ELHAJ ABDELMOULA.ELSIDDIG MUSA,

    2011-05-01

    Full Text Available Productivity index as an important business determinant factor for profitability and business performance has been studied in this research versus TQM varibles. The study highlighted out the impacts ofimplementation of TQM on productivity in poultry processing plants in Saudi Arabia – Central Region. The significance of this research represented in exploring the impact of TQM practices on Poultry Processing Plants' productivity. Seven determinants of TQM practices and their impacts were measured against productivity. The determinants included top management commitment, customer focus, rewards & training, continual improvement, cooperation & teamwork, prevention focus and measurement system. Data was collected by using Questionnaire tool. The Questionnaire is of closed ended questions. It consists of three parts, the first part is demographic information about the study sample, the second part about implementation of the total quality management and the third part is to measure productivity. A sample of three poultry processing plants that effectively implemented total quality management were purposively chosen out of eight plants in Saudi Arabia Central Region. The study respondents are purposively chosen which consists quality team, production supervisors, Total quality management and production managers. 73 respondents out 75 participated in the survey. The finding indicated that the TQM practices have positive impact on poultry processing plants' productivity.

  6. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    Energy Technology Data Exchange (ETDEWEB)

    John Groppo; Thomas Robl

    2005-06-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. Filter media candidates were evaluated for dewatering the ultrafine ash (UFA) product. Media candidates were selected based on manufacturer recommendations and evaluated using standard batch filtration techniques. A final media was selected; 901F, a multifilament polypropylene. While this media would provide adequate solids capture and cake moisture, the use of flocculants would be necessary to enable adequate filter throughput. Several flocculant chemistries were also evaluated and it was determined that polyethylene oxide (PEO) at a dosage of 5 ppm (slurry basis) would be the most suitable in terms of both settling rate and clarity. PEO was evaluated on a continuous vacuum filter using 901F media. The optimum cycle time was found to be 1.25 minutes which provided a 305% moisture cake, 85% solids capture with a throughput of 115 lbs dry solids per hour and a dry cake rate of 25 lb/ft2/hr. Increasing cycle time not did not reduce cake moisture or increase throughput. A mobile demonstration unit has been designed and constructed for field demonstration. The continuous test unit will be operated at the Ghent site and will evaluate three processing configurations while producing sufficient products to facilitate thorough product testing. The test unit incorporates all of the unit processes that will be used in the commercial design and is self sufficient with respect to water, electricity and processing capabilities.

  7. Effect of Plant Spacing in the Nursery on the Production of Planting Materials for Field Establishment of Vetiver Grass

    Directory of Open Access Journals (Sweden)

    Jimba, SC.

    2003-01-01

    Full Text Available A study was conducted between June and October, 2001, at the Teaching and Research Farm of the University of Ibadan (7° 24' N, 3° 54' E, Nigeria, to evaluate the effect of plant spacing in the nursery on the growth of vetiver grass (Vetiveria zizanioides L. so as to determine the optimum plant spacing in the nursery for the production of planting materials for field establishment. Four spacings, 20 x 30 cm2, 15 x 40 cm2, 20 x 40 cm2 and 40 x 40 cm2, were replicated four times and laid out in a randomized complete block design. Treatment plots measured 4 m x 4 m. Per stand, two vetiver tillers were planted on flat seedbeds. Parameters assessed included plant height, dry matter yield and tiller production. Shoot, root and total plant dry matter and tiller count were measured at 16 weeks after planting (WAP. Spacing had no effect (P< 0.05 on plant height but impacted very significantly (P< 0.01 on root, shoot and total plant dry matter production, which increased with wider spacing. In a spatial context, dry matter yield per hectare was least in the widest spacing. Spacing had no effect (P< 0.05 on number of tillers produced per planted tiller (multiplication rate but it had a very significant effect (P< 0.01 on the number of tillers produced per unit area. The closest spacings, 20 x 30 cm2 and 15 x 40 cm2, which gave the highest number of tillers per hectare (203.3 x 104 and 196.7 x 104, respectively, were recommended for production of planting materials in the nursery.

  8. Bench to batch: advances in plant cell culture for producing useful products.

    Science.gov (United States)

    Weathers, Pamela J; Towler, Melissa J; Xu, Jianfeng

    2010-02-01

    Despite significant efforts over nearly 30 years, only a few products produced by in vitro plant cultures have been commercialized. Some new advances in culture methods and metabolic biochemistry have improved the useful potential of plant cell cultures. This review will provide references to recent relevant reviews along with a critical analysis of the latest improvements in plant cell culture, co-cultures, and disposable reactors for production of small secondary product molecules, transgenic proteins, and other products. Some case studies for specific products or production systems are used to illustrate principles.

  9. Anthropogenic plutonium-244 in the environment: Insights into plutonium’s longest-lived isotope

    Science.gov (United States)

    Armstrong, Christopher R.; Brant, Heather A.; Nuessle, Patterson R.; Hall, Gregory; Cadieux, James R.

    2016-01-01

    Owing to the rich history of heavy element production in the unique high flux reactors that operated at the Savannah River Site, USA (SRS) decades ago, trace quantities of plutonium with highly unique isotopic characteristics still persist today in the SRS terrestrial environment. Development of an effective sampling, processing, and analysis strategy enables detailed monitoring of the SRS environment, revealing plutonium isotopic compositions, e.g., 244Pu, that reflect the unique legacy of plutonium production at SRS. This work describes the first long-term investigation of anthropogenic 244Pu occurrence in the environment. Environmental samples, consisting of collected foot borne debris, were taken at SRS over an eleven year period, from 2003 to 2014. Separation and purification of trace plutonium was carried out followed by three stage thermal ionization mass spectrometry (3STIMS) measurements for plutonium isotopic content and isotopic ratios. Significant 244Pu was measured in all of the years sampled with the highest amount observed in 2003. The 244Pu content, in femtograms (fg = 10−15 g) per gram, ranged from 0.31 fg/g to 44 fg/g in years 2006 and 2003 respectively. In all years, the 244Pu/239Pu atom ratios were significantly higher than global fallout, ranging from 0.003 to 0.698 in years 2014 and 2003 respectively. PMID:26898531

  10. Production of Drought and Salt Tolerant Transgenic Cereal Plants

    Institute of Scientific and Technical Information of China (English)

    A. Garg; R. Wu

    2007-01-01

    @@ Genetic transformation of cereal plants is a powerful method for producing agronomically useful transgenic plants. Salt and drought stress result in substantial yield losses, which amounts to many billions of dollars each year.

  11. A vision for environmentally conscious plutonium processing

    Energy Technology Data Exchange (ETDEWEB)

    Avens, L.R.; Eller, P.G.; Christensen, D.C. [Los Alamos National Lab., NM (United States). Nuclear Materials Technology Div.; Miller, W.L. [Univ. of Florida, Gainesville, FL (United States). Dept. of Environmental Engineering Sciences

    1998-12-31

    Regardless of individual technical and political opinions about the uses of plutonium, it is virtually certain that plutonium processing will continue on a significant global scale for many decades for the purposes of national defense, nuclear power and remediation. An unavoidable aspect of plutonium processing is that radioactive contaminated gas, liquid, and solid streams are generated. These streams need to be handled in a manner that is not only in full compliance with today`s laws,but also will be considered environmentally and economically responsible now and in the future. In this regard, it is indeed ironic that the multibillion dollar and multidecade radioactive cleanup mortgage that the US Department of Energy (and its Russian counterpart) now owns resulted from waste management practices that were at the time in full legal compliance. The theme of this paper is that recent dramatic advances in actinide science and technology now make it possible to drastically minimize or even eliminate the problematic waste streams of traditional plutonium processing operations. Advanced technology thereby provides the means to avoid passing on to our children and grandchildren significant environmental and economic legacies that traditional processing inevitably produces. This paper will describe such a vision for plutonium processing that could be implemented fully within five years at a facility such as the Los Alamos Plutonium Facility (TA55). As a significant bonus, even on this short time scale, the initial technology investment is handsomely returned in avoided waste management costs.

  12. A DGT technique for plutonium bioavailability measurements.

    Science.gov (United States)

    Cusnir, Ruslan; Steinmann, Philipp; Bochud, François; Froidevaux, Pascal

    2014-09-16

    The toxicity of heavy metals in natural waters is strongly dependent on the local chemical environment. Assessing the bioavailability of radionuclides predicts the toxic effects to aquatic biota. The technique of diffusive gradients in thin films (DGT) is largely exploited for bioavailability measurements of trace metals in waters. However, it has not been applied for plutonium speciation measurements yet. This study investigates the use of DGT technique for plutonium bioavailability measurements in chemically different environments. We used a diffusion cell to determine the diffusion coefficients (D) of plutonium in polyacrylamide (PAM) gel and found D in the range of 2.06-2.29 × 10(-6) cm(2) s(-1). It ranged between 1.10 and 2.03 × 10(-6) cm(2) s(-1) in the presence of fulvic acid and in natural waters with low DOM. In the presence of 20 ppm of humic acid of an organic-rich soil, plutonium diffusion was hindered by a factor of 5, with a diffusion coefficient of 0.50 × 10(-6) cm(2) s(-1). We also tested commercially available DGT devices with Chelex resin for plutonium bioavailability measurements in laboratory conditions and the diffusion coefficients agreed with those from the diffusion cell experiments. These findings show that the DGT methodology can be used to investigate the bioaccumulation of the labile plutonium fraction in aquatic biota.

  13. Determination of origin and intended use of plutonium metal using nuclear forensic techniques.

    Science.gov (United States)

    Rim, Jung H; Kuhn, Kevin J; Tandon, Lav; Xu, Ning; Porterfield, Donivan R; Worley, Christopher G; Thomas, Mariam R; Spencer, Khalil J; Stanley, Floyd E; Lujan, Elmer J; Garduno, Katherine; Trellue, Holly R

    2017-01-19

    Nuclear forensics techniques, including micro-XRF, gamma spectrometry, trace elemental analysis and isotopic/chronometric characterization were used to interrogate two, potentially related plutonium metal foils. These samples were submitted for analysis with only limited production information, and a comprehensive suite of forensic analyses were performed. Resulting analytical data was paired with available reactor model and historical information to provide insight into the materials' properties, origins, and likely intended uses. Both were super-grade plutonium, containing less than 3% (240)Pu, and age-dating suggested that most recent chemical purification occurred in 1948 and 1955 for the respective metals. Additional consideration of reactor modeling feedback and trace elemental observables indicate plausible U.S. reactor origin associated with the Hanford site production efforts. Based on this investigation, the most likely intended use for these plutonium foils was (239)Pu fission foil targets for physics experiments, such as cross-section measurements, etc.

  14. In-Situ Propellant Production on Mars: A Sabatier/Electrolysis Demonstration Plant

    Science.gov (United States)

    Clark, David L.

    1997-01-01

    An efficient, reliable propellant production plant has been developed for use on Mars. Using a Sabatier reactor in conjunction with a water electrolysis system, a complete demonstration plant has produced methane and liquid oxygen from simulated Martian atmosphere. The production plant has demonstrated high efficiency, extended duration production and autonomous operations. This paper presents the results and conclusions relating to eventual use in a Mars sample return mission. This work was funded by the Jet Propulsion Laboratory (JPL). The production plant was built and tested at the Propulsion Center of Lockheed Martin at the Denver Colorado facility.

  15. FORM AND AGING OF PLUTONIUM IN SAVANNAH RIVER SITE WASTE TANK 18

    Energy Technology Data Exchange (ETDEWEB)

    Hobbs, D.

    2012-02-24

    This report provides a summary of the effects of aging on and the expected forms of plutonium in Tank 18 waste residues. The findings are based on available information on the operational history of Tank 18, reported analytical results for samples taken from Tank 18, and the available scientific literature for plutonium under alkaline conditions. These findings should apply in general to residues in other waste tanks. However, the operational history of other waste tanks should be evaluated for specific conditions and unique operations (e.g., acid cleaning with oxalic acid) that could alter the form of plutonium in heel residues. Based on the operational history of other tanks, characterization of samples from the heel residues in those tanks would be appropriate to confirm the form of plutonium. During the operational period and continuing with the residual heel removal periods, Pu(IV) is the dominant oxidation state of the plutonium. Small fractions of Pu(V) and Pu(VI) could be present as the result of the presence of water and the result of reactions with oxygen in air and products from the radiolysis of water. However, the presence of Pu(V) would be transitory as it is not stable at the dilute alkaline conditions that currently exists in Tank 18. Most of the plutonium that enters Savannah River Site (SRS) high-level waste (HLW) tanks is freshly precipitated as amorphous plutonium hydroxide, Pu(OH){sub 4(am)} or hydrous plutonium oxide, PuO{sub 2(am,hyd)} and coprecipitated within a mixture of hydrous metal oxide phases containing metals such as iron, aluminum, manganese and uranium. The coprecipitated plutonium would include Pu{sup 4+} that has been substituted for other metal ions in crystal lattice sites, Pu{sup 4+} occluded within hydrous metal oxide particles and Pu{sup 4+} adsorbed onto the surface of hydrous metal oxide particles. The adsorbed plutonium could include both inner sphere coordination and outer sphere coordination of the plutonium. PuO{sub 2

  16. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    Energy Technology Data Exchange (ETDEWEB)

    John Groppo; Thomas Robl

    2006-06-30

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utility's 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The secondary classification testing was concluded using a continuous demonstration-scale lamella classifier that was operated at a feed rate of 0.3 to 1.5 tons/hr. Feed to the secondary classifier was generated by operating the primary classifier at the conditions shown to be effective previously. Samples were taken while the secondary classifier was operated under a variety of conditions in order to determine the range of conditions where the unit could be efficiently operated. A Topical Report was prepared and included all of the pertinent processing data generated during Budget Period 1 of the project as well as results of beneficiated ash product evaluations in mortar and concrete, schematic plant designs with mass and water balances for the four flowsheets tested with equipment lists, capital and installation costs, expected product outputs and equipment justifications. A proposal for continuation of the project to Budget Period 2 was also prepared and submitted, with the exception of a Letter of Commitment from Cemex. The proposal is currently under internal review with Cemex and a decision is expected by the end of September, 2006.

  17. External radiation assessment in a wet phosphoric acid production plant

    Energy Technology Data Exchange (ETDEWEB)

    Bolivar, J.P.; Perez-Moreno, J.P. [Dept. Fisica Aplicada, Facultad de Ciencias Experimentales, Universidad de Huelva, 21012 Huelva (Spain); Mas, J.L. [Dept. Fisica Aplicada I, Escuela Universitaria Politecnica, Universidad de Sevilla, 41012 Sevilla (Spain)], E-mail: ppmasb@us.es; Martin, J.E.; San Miguel, E.G. [Dept. Fisica Aplicada, Facultad de Ciencias Experimentales, Universidad de Huelva, 21012 Huelva (Spain); Garcia-Tenorio, R. [Dept. Fisica Aplicada II, Escuela Tecnica Superior de Arquitectura, Universidad de Sevilla, 41012 Sevilla (Spain)

    2009-10-15

    The factories dedicated to the production of phosphoric acid by the so-called wet acid method are usually considered typical NORM industries, because the phosphate rock used as raw material usually contains high concentrations of {sup 238}U-series radionuclides. The magnitude and behaviour of the radionuclides involved in the production process revealed the need to determine its dosimetric impact on workers. This work aims to partially compensate this lack of knowledge through the determination of external effective dose rates at different zones in the process at a typical plant located in the southwest of Spain. To this end, two dosimetric sampling campaigns have been carried out at this phosphoric acid production plant. The first sampling was carried out when phosphate rocks originating in Morocco were processed, and the second one when phosphate rock processed came from the Kola Peninsula (Russia Federation). This differentiation was necessary because the activity concentrations are almost one order of magnitude higher in Moroccan phosphate rock than in Kola phosphate rock. The results obtained have reflected external dose rate enhancements as high as 1.4 {mu}Sv h{sup -1} (i.e., up to thirty times the external exposition due to radionuclides in unperturbed soils) at several points in the facility, particularly where the digested rock (pulp) is filtered. However, the most problematic points are characterised by a small occupation factor. That means that the increment in the annual effective external gamma dose received by the most-exposed worker is clearly below 1 mSv (European Commission limit for the general population) under normal production. Nevertheless, special care in the design and schedule of cleaning and maintaining work in the areas with high doses should be taken in order to avoid any possibility of exceeding the previously mentioned general population limit. In addition, the results of the dosimetric campaign showed no clear correlation between {sup

  18. Destruction of plutonium using non-uranium fuels in pressurized water reactor peripheral assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Chodak, III, Paul [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

    1996-05-01

    This thesis examines and confirms the feasibility of using non-uranium fuel in a pressurized water reactor (PWR) radial blanket to eliminate plutonium of both weapons and civilian origin. In the equilibrium cycle, the periphery of the PWR is loaded with alternating fresh and once burned non-uranium fuel assemblies, with the interior of the core comprised of conventional three batch UO2 assemblies. Plutonium throughput is such that there is no net plutonium production: production in the interior is offset by destruction in the periphery. Using this approach a 50 MT WGPu inventory could be eliminated in approximately 400 reactor years of operation. Assuming all other existing constraints were removed, the 72 operating US PWRs could disposition 50 MT of WGPu in 5.6 years. Use of a low fissile loading plutonium-erbium inert-oxide-matrix composition in the peripheral assemblies essentially destroys 100% of the 239Pu and ≥90% {sub total}Pu over two 18 month fuel cycles. Core radial power peaking, reactivity vs EFPD profiles and core average reactivity coefficients were found to be comparable to standard PWR values. Hence, minimal impact on reload licensing is anticipated. Examination of potential candidate fuel matrices based on the existing experience base and thermo-physical properties resulted in the recommendation of three inert fuel matrix compositions for further study: zirconia, alumina and TRISO particle fuels. Objective metrics for quantifying the inherent proliferation resistance of plutonium host waste and fuel forms are proposed and were applied to compare the proposed spent WGPu non-uranium fuel to spent WGPu MOX fuels and WGPu borosilicate glass logs. The elimination disposition option spent non-uranium fuel product was found to present significantly greater barriers to proliferation than other plutonium disposal products.

  19. Destruction of plutonium using non-uranium fuels in pressurized water reactor peripheral assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Chodak, P. III

    1996-05-01

    This thesis examines and confirms the feasibility of using non-uranium fuel in a pressurized water reactor (PWR) radial blanket to eliminate plutonium of both weapons and civilian origin. In the equilibrium cycle, the periphery of the PWR is loaded with alternating fresh and once burned non-uranium fuel assemblies, with the interior of the core comprised of conventional three batch UO{sub 2} assemblies. Plutonium throughput is such that there is no net plutonium production: production in the interior is offset by destruction in the periphery. Using this approach a 50 MT WGPu inventory could be eliminated in approximately 400 reactor years of operation. Assuming all other existing constraints were removed, the 72 operating US PWRs could disposition 50 MT of WGPu in 5.6 years. Use of a low fissile loading plutonium-erbium inert-oxide-matrix composition in the peripheral assemblies essentially destroys 100% of the {sup 239}Pu and {ge}90% {sub total}Pu over two 18 month fuel cycles. Core radial power peaking, reactivity vs EFPD profiles and core average reactivity coefficients were found to be comparable to standard PWR values. Hence, minimal impact on reload licensing is anticipated. Examination of potential candidate fuel matrices based on the existing experience base and thermo-physical properties resulted in the recommendation of three inert fuel matrix compositions for further study: zirconia, alumina and TRISO particle fuels. Objective metrics for quantifying the inherent proliferation resistance of plutonium host waste and fuel forms are proposed and were applied to compare the proposed spent WGPu non-uranium fuel to spent WGPu MOX fuels and WGPu borosilicate glass logs. The elimination disposition option spent non-uranium fuel product was found to present significantly greater barriers to proliferation than other plutonium disposal products.

  20. Experimental critical parameters of plutonium metal cylinders flooded with water

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-01

    Forty-nine critical configurations are reported for experiments involving arrays of 3 kg plutonium metal cylinders moderated and reflected by water. Thirty-four of these describe systems assembled in the laboratory, while 15 others are derived critical parameters inferred from 46 subcritical cases. The arrays included 2x2xN, N = 2, 3, 4, and 5, in one program and 3x3x3 configurations in a later study. All were three-dimensional, nearly square arrays with equal horizontal lattice spacings but a different vertical lattice spacing. Horizontal spacings ranged from units in contact to 180 mm center-to-center; and vertical spacings ranged from about 80 mm to almost 400 mm center-to-center. Several nearly-equilateral 3x3x3 arrays exhibit an extremely sensitive dependence upon horizontal separation for identical vertical spacings. A line array of unreflected and essentially unmoderated canned plutonium metal units appeared to be well subcritical based on measurements made to assure safety during the manual assembly operations. All experiments were performed at two widely separated times in the mid-1970s and early 1980s under two programs at the Rocky Flats Plant`s Critical Mass Laboratory.

  1. Application of curium measurements for safeguarding at reprocessing plants. Study 1: High-level liquid waste and Study 2: Spent fuel assemblies and leached hulls

    Energy Technology Data Exchange (ETDEWEB)

    Rinard, P.M.; Menlove, H.O.

    1996-03-01

    In large-scale reprocessing plants for spent fuel assemblies, the quantity of plutonium in the waste streams each year is large enough to be important for nuclear safeguards. The wastes are drums of leached hulls and cylinders of vitrified high-level liquid waste. The plutonium amounts in these wastes cannot be measured directly by a nondestructive assay (NDA) technique because the gamma rays emitted by plutonium are obscured by gamma rays from fission products, and the neutrons from spontaneous fissions are obscured by those from curium. The most practical NDA signal from the waste is the neutron emission from curium. A diversion of waste for its plutonium would also take a detectable amount of curium, so if the amount of curium in a waste stream is reduced, it can be inferred that there is also a reduced amount of plutonium. This report studies the feasibility of tracking the curium through a reprocessing plant with neutron measurements at key locations: spent fuel assemblies prior to shearing, the accountability tank after dissolution, drums of leached hulls after dissolution, and canisters of vitrified high-level waste after separation. Existing pertinent measurement techniques are reviewed, improvements are suggested, and new measurements are proposed. The authors integrate these curium measurements into a safeguards system.

  2. Soil microbes contribute to the classic plant diversity-productivity pattern

    NARCIS (Netherlands)

    Schnitzer, S.A.; Klironomos, J.N.; HilleRisLambers, J.; Kinkel, L.L.; Reich, P.B.; Nes, van E.H.; Scheffer, M.

    2011-01-01

    Ecosystem productivity commonly increases asymptotically with plant species diversity, and determining the mechanisms responsible for this well-known pattern is essential to predict potential changes in ecosystem productivity with ongoing species loss. Previous studies attributed the asymptotic dive

  3. Antimicrobial peptide production and plant-based expression systems for medical and agricultural biotechnology.

    Science.gov (United States)

    Holaskova, Edita; Galuszka, Petr; Frebort, Ivo; Oz, M Tufan

    2015-11-01

    Antimicrobial peptides (AMPs) are vital components of the innate immune system of nearly all living organisms. They generally act in the first line of defense against various pathogenic bacteria, parasites, enveloped viruses and fungi. These low molecular mass peptides are considered prospective therapeutic agents due to their broad-spectrum rapid activity, low cytotoxicity to mammalian cells and unique mode of action which hinders emergence of pathogen resistance. In addition to medical use, AMPs can also be employed for development of innovative approaches for plant protection in agriculture. Conferred disease resistance by AMPs might help us surmount losses in yield, quality and safety of agricultural products due to plant pathogens. Heterologous expression in plant-based systems, also called plant molecular farming, offers cost-effective large-scale production which is regarded as one of the most important factors for clinical or agricultural use of AMPs. This review presents various types of AMPs as well as plant-based platforms ranging from cell suspensions to whole plants employed for peptide production. Although AMP production in plants holds great promises for medicine and agriculture, specific technical limitations regarding product yield, function and stability still remain. Additionally, establishment of particular stable expression systems employing plants or plant tissues generally requires extended time scale for platform development compared to certain other heterologous systems. Therefore, fast and promising tools for evaluation of plant-based expression strategies and assessment of function and stability of the heterologously produced AMPs are critical for molecular farming and plant protection.

  4. Increased plant productivity and decreased microbial respiratory C loss by plant growth-promoting rhizobacteria under elevated CO₂.

    Science.gov (United States)

    Nie, Ming; Bell, Colin; Wallenstein, Matthew D; Pendall, Elise

    2015-03-18

    Increased plant productivity and decreased microbial respiratory C loss can potentially mitigate increasing atmospheric CO₂, but we currently lack effective means to achieve these goals. Soil microbes may play critical roles in mediating plant productivity and soil C/N dynamics under future climate scenarios of elevated CO₂ (eCO₂) through optimizing functioning of the root-soil interface. By using a labeling technique with (13)C and (15)N, we examined the effects of plant growth-promoting Pseudomonas fluorescens on C and N cycling in the rhizosphere of a common grass species under eCO₂. These microbial inoculants were shown to increase plant productivity. Although strong competition for N between the plant and soil microbes was observed, the plant can increase its capacity to store more biomass C per unit of N under P. fluorescens addition. Unlike eCO₂ effects, P. fluorescens inoculants did not change mass-specific microbial respiration and accelerate soil decomposition related to N cycling, suggesting these microbial inoculants mitigated positive feedbacks of soil microbial decomposition to eCO₂. The potential to mitigate climate change by optimizing soil microbial functioning by plant growth-promoting Pseudomonas fluorescens is a prospect for ecosystem management.

  5. Towards high-yield production of pharmaceutical proteins with plant cell suspension cultures.

    Science.gov (United States)

    Xu, Jianfeng; Ge, Xumeng; Dolan, Maureen C

    2011-01-01

    "Molecular farming" in plants with significant advantages in cost and safety is touted as a promising platform for the production of complex pharmaceutical proteins. While whole-plant produced biopharmaceuticals account for a significant portion of the preclinical and clinical pipeline, plant cell suspension culture, which integrates the merits of whole-plant systems with those of microbial fermentation, is emerging as a more compliant alternative "factory". However, low protein productivity remains a major obstacle that limits extensive commercialization of plant cell bioproduction platform. This review highlights the advantages and recent progress in plant cell culture technology and outlines viable strategies at both the biological and process engineering levels for advancing the economic feasibility of plant cell-based protein production. Approaches to overcome and solve the associated challenges of this culture system that include non-mammalian glycosylation and genetic instability will also be discussed.

  6. A co-beneficial system using aquatic plants: bioethanol production from free-floating aquatic plants used for water purification.

    Science.gov (United States)

    Soda, S; Mishima, D; Inoue, D; Ike, M

    2013-01-01

    A co-beneficial system using constructed wetlands (CWs) planted with aquatic plants is proposed for bioethanol production and nutrient removal from wastewater. The potential for bioethanol production from aquatic plant biomass was experimentally evaluated. Water hyacinth and water lettuce were selected because of their high growth rates and easy harvestability attributable to their free-floating vegetation form. The alkaline/oxidative pretreatment was selected for improving enzymatic hydrolysis of the aquatic plants. Ethanol was produced with yields of 0.14-0.17 g-ethanol/ g-biomass in a simultaneous saccharification and fermentation mode using a recombinant Escherichia coli strain or a typical yeast strain Saccharomyces cerevisiae. Subsequently, the combined benefits of the CWs planted with the aquatic plants for bioethanol production and nutrient removal were theoretically estimated. For treating domestic wastewater at 1,100 m(3)/d, it was inferred that the anoxic-oxic activated sludge process consumes energy at 3,200 MJ/d, whereas the conventional activated sludge process followed by the CW consumes only 1,800 MJ/d with ethanol production at 115 MJ/d.

  7. Production and identification of salt_tolerant transgenic rice plants

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    @@To relieve the damage of salt to the cell, many plants accumulated some low_molecular weight organic compounds, which were called osmoprotectant, such as betaine, mannitol, and sorbitol. Therefore if the gene_encoding enzyme responsible for synthesizing the osmoprotectant was transformed into rice plants, the salt_tolerance capacity of the transgenic plants would be increased, and the enormous loss caused by salinization of soil would be reduced.

  8. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    Energy Technology Data Exchange (ETDEWEB)

    Andrew Jackura; John Groppo; Thomas Robl

    2006-12-31

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The market study for the products of the processing plant (Subtask 1.6), conducted by Cemex, is reported herein. The study incorporated simplifying assumptions and focused only on pozzolan and ultra fine fly ash (UFFA). It found that the market for pozzolan in the Ghent area was oversupplied, with resultant poor pricing structure. Reachable export markets for the Ghent pozzolan market were mostly locally served with the exception of Florida. It was concluded that a beneficiated material for that market may be at a long term disadvantage. The market for the UFFA was more complex as this material would compete with other beneficiated ash and potential metakaolin and silica fume as well. The study concluded that this market represented about 100,000 tons of sales per year and, although lucrative, represented a widely dispersed niche market.

  9. ADVANCED MULTI-PRODUCT COAL UTILIZATION BY-PRODUCT PROCESSING PLANT

    Energy Technology Data Exchange (ETDEWEB)

    Robert Jewell; Thomas Robl; John Groppo

    2005-03-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. The ash produced by the plant was found to be highly variable as the plant consumes high and low sulfur bituminous coal, in Units 1 and 2 and a mixture of subbituminous and bituminous coal in Units 3 and 4. The ash produced reflected this consisting of an iron-rich ({approx}24%, Fe{sub 2}O{sub 3}), aluminum rich ({approx}29% Al{sub 2}O{sub 3}) and high calcium (6%-7%, CaO) ash, respectively. The LOI of the ash typically was in the range of 5.5% to 6.5%, but individual samples ranged from 1% to almost 9%. The lower pond at Ghent is a substantial body, covering more than 100 acres, with a volume that exceeds 200 million cubic feet. The sedimentation, stratigraphy and resource assessment of the in place ash was investigated with vibracoring and three-dimensional, computer-modeling techniques. Thirteen cores to depths reaching nearly 40 feet, were retrieved, logged in the field and transported to the lab for a series of analyses for particle size, loss on ignition, petrography, x-ray diffraction, and x-ray fluorescence. Collected data were processed using ArcViewGIS, Rockware, and Microsoft Excel to create three-dimensional, layered iso-grade maps, as well as stratigraphic columns and profiles, and reserve estimations. The ash in the pond was projected to exceed 7 million tons and contain over 1.5 million tons of coarse carbon, and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. The size, quality and consistency of the ponded material suggests that it is the better feedstock for the beneficiation plant.

  10. HEAVY METALS IN PRODUCTIVE PARTS OF AGRICULTURAL PLANTS

    Directory of Open Access Journals (Sweden)

    Július Árvay

    2012-02-01

    Full Text Available The contents of heavy metals in plants were not in relation to contents of heavy metals in soil. Increased content of heavy metals in soils was not in consistency with content in plants. Usually content of heavy metals in plants according to our results were lower than their content in soil. Only the over limit contents of copper and cadmium were assessed in grain of barley and oat. The results of heavy metals content showed that dominant part on content of elements in plants have their mobile forms what depends on pH, content of organic matter in soil and portion of clay parts.

  11. HEAVY METALS IN PRODUCTIVE PARTS OF AGRICULTURAL PLANTS

    OpenAIRE

    Július Árvay; Ján Tomáš; Tomáš Tóth

    2012-01-01

    The contents of heavy metals in plants were not in relation to contents of heavy metals in soil. Increased content of heavy metals in soils was not in consistency with content in plants. Usually content of heavy metals in plants according to our results were lower than their content in soil. Only the over limit contents of copper and cadmium were assessed in grain of barley and oat. The results of heavy metals content showed that dominant part on content of elements in plants have their mobil...

  12. Improvements in human health through production of human milk proteins in transgenic food plants.

    Science.gov (United States)

    Arakawa, T; Chong, D K; Slattery, C W; Langridge, W H

    1999-01-01

    Plants are particularly suitable bioreactors for the production of proteins, as their eukaryotic nature frequently directs the appropriate post-translational modifications of recombinant proteins to retain native biological activity. The autotrophic growth of plants makes this in vivo biosynthesis system economically competitive for supplementation or replacement of conventional production systems in the future. For the production of biologically active proteins, food plants provide the advantage of direct delivery via consumption of transformed plant tissues. Here we describe the production of recombinant human milk proteins in food plants for improvements in human nutrition and health, with emphasis on enhanced nutrition for non-breast fed infants as well as children and adults. Nutritional improvements in edible plants generated through advancements in recombinant DNA technology are rapidly repositioning the world for enjoyment of a more healthful diet for humans in all age groups.

  13. Arbuscular mycorrhizal symbiosis influences strigolactone production under salinity and alleviates salt stress in lettuce plants.

    Science.gov (United States)

    Aroca, Ricardo; Ruiz-Lozano, Juan Manuel; Zamarreño, Angel María; Paz, José Antonio; García-Mina, José María; Pozo, María José; López-Ráez, Juan Antonio

    2013-01-01

    Arbuscular mycorrhizal (AM) symbiosis can alleviate salt stress in plants. However the intimate mechanisms involved, as well as the effect of salinity on the production of signalling molecules associated to the host plant-AM fungus interaction remains largely unknown. In the present work, we have investigated the effects of salinity on lettuce plant performance and production of strigolactones, and assessed its influence on mycorrhizal root colonization. Three different salt concentrations were applied to mycorrhizal and non-mycorrhizal plants, and their effects, over time, analyzed. Plant biomass, stomatal conductance, efficiency of photosystem II, as well as ABA content and strigolactone production were assessed. The expression of ABA biosynthesis genes was also analyzed. AM plants showed improved growth rates and a better performance of physiological parameters such as stomatal conductance and efficiency of photosystem II than non-mycorrhizal plants under salt stress since very early stages - 3 weeks - of plant colonization. Moreover, ABA levels were lower in those plants, suggesting that they were less stressed than non-colonized plants. On the other hand, we show that both AM symbiosis and salinity influence strigolactone production, although in a different way in AM and non-AM plants. The results suggest that AM symbiosis alleviates salt stress by altering the hormonal profiles and affecting plant physiology in the host plant. Moreover, a correlation between strigolactone production, ABA content, AM root colonization and salinity level is shown. We propose here that under these unfavourable conditions, plants increase strigolactone production in order to promote symbiosis establishment to cope with salt stress.

  14. [Pilot plant and experimental laboratory production. The role in biotechnology industry development].

    Science.gov (United States)

    Volkov, H L

    2000-01-01

    A stage-phase approach can contribute to unnecessarily long product development time. A simultaneous approach that integrates all development resources through an effectively managed pilot plant can significantly shorten the product development cycle. An intensive development of the domestic biotechnology manufacturing is impossible without creation of the real pilot plant market in Ukraine.

  15. The European role on traditional herbal medicinal products and traditional plant food supplements.

    Science.gov (United States)

    Serafini, Mauro; Stanzione, Alessandra; Foddai, Sebastiano; Anton, Robert; Delmulle, Luc

    2012-10-01

    Herbs are used in Europe as medicinal products, food, food supplements, and related products. This paper will discuss the concepts of Traditional Herbal Medicines and Traditional Plant Food Supplements, defined in European legislation under differing legal frameworks, regarding Traditional Plant Food Supplements (including Claims Regulation) and the role of the European Food Safety Authority in health claims.

  16. Photon attenuation properties of some thorium, uranium and plutonium compounds

    Energy Technology Data Exchange (ETDEWEB)

    Singh, V. P.; Badiger, N. M. [Karnatak University, Department of Physics, Dharwad-580003, Karnataka (India); Vega C, H. R., E-mail: kudphyvps@rediffmail.com [Universidad Autonoma de Zacatecas, Unidad Academica de Estudios Nucleares, Cipres No. 10, Fracc. La Penuela, 98068 Zacatecas, Zac. (Mexico)

    2015-10-15

    Mass attenuation coefficients, effective atomic numbers, effective electron densities for nuclear materials; thorium, uranium and plutonium compounds have been studied. The photon attenuation properties for the compounds have been investigated for partial photon interaction processes by photoelectric effect, Compton scattering and pair production. The values of these parameters have been found to change with photon energy and interaction process. The variations of mass attenuation coefficients, effective atomic number and electron density with energy are shown graphically. Moreover, results have shown that these compounds are better shielding and suggesting smaller dimensions. The study would be useful for applications of these materials for gamma ray shielding requirement. (Author)

  17. Do plant population and planting date make a difference in corn production?

    Science.gov (United States)

    One management practice that can positively or negatively impact corn yield is plant population. Yield potential can also be influenced by the date of planting, which is strongly linked to the at-planting and in-season weather and climatic conditions. Even when considering management changes, we nee...

  18. Effect of compositional variation in plutonium on process shielding design

    Energy Technology Data Exchange (ETDEWEB)

    Brown, T.H.

    1997-11-01

    Radiation dose rate from plutonium with high {sup 239}Pu content varies with initial nuclidic content, radioactive decay time, and impurity elemental content. The two idealized states of old plutonium and clean plutonium, whose initial compositions are given, provide approximate upper and lower bounds on dose rate variation. Whole-body dose rates were calculated for the two composition states, using unshielded and shielded plutonium spheres of varying density. The dose rates from these variable density spheres are similar to those from expanded plutonium configurations encountered during processing. The dose location of 40 cm from the sphere center is representative of operator standoff for direct handling of plutonium inside a glove box. The results have shielding implications for glove boxes with only structurally inherent shielding, especially for processing of old plutonium in an expanded configuration. Further reduction in total dose rate by using lead to reduce photon dose rate is shown for two density cases representing compact and expanded plutonium configurations.

  19. Neptunium and plutonium complexes with a sterically encumbered triamidoamine (TREN) scaffold.

    Science.gov (United States)

    Brown, Jessie L; Gaunt, Andrew J; King, David M; Liddle, Stephen T; Reilly, Sean D; Scott, Brian L; Wooles, Ashley J

    2016-04-07

    The syntheses and characterisation of isostructural neptunium(iv) and plutonium(iv) complexes [An(IV)(TREN(TIPS))(Cl)] [An = Np, Pu; TREN(TIPS) = {N(CH2CH2NSiPr(i)3)3}(3-)] are reported, along with the demonstration that they are likely reduced to the corresponding neptunium(iii) and plutonium(iii) products [An(III)(TREN(TIPS))]; this chemistry provides new platforms from which to target a plethora of unprecedented molecular functionalities in transuranic chemistry and the neptunium(iv) molecule is the first structurally characterised neptunium(iv)-amide complex.

  20. Design of the Laboratory-Scale Plutonium Oxide Processing Unit in the Radiochemical Processing Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Lumetta, Gregg J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Meier, David E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Tingey, Joel M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Casella, Amanda J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Delegard, Calvin H. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Edwards, Matthew K. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Orton, Robert D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Rapko, Brian M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Smart, John E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-05-01

    This report describes a design for a laboratory-scale capability to produce plutonium oxide (PuO2) for use in identifying and validating nuclear forensics signatures associated with plutonium production, as well as for use as exercise and reference materials. This capability will be located in the Radiochemical Processing Laboratory at the Pacific Northwest National Laboratory. The key unit operations are described, including PuO2 dissolution, purification of the Pu by ion exchange, precipitation, and re-conversion to PuO2 by calcination.

  1. Seasons and planting densities interaction on forage production of eight hybrids maize, Ecuador

    Directory of Open Access Journals (Sweden)

    Álvaro Cañadas L.

    2015-12-01

    Full Text Available Objective. To assess the interaction effect of the season and planting densities on the production of eight INIAP corn hybrids. Materials and methods. A research process was conducted in 2013. It was applied a split - split plot design with three replication and Tukey test was used. It was evaluated two planting seasons (28 January and 8 April, they were placed in large plots. Two planting densities (65,500 y 125,000 plants/ha, that were located in the subplots and eight INIAP corn hybrids arranged in the sub- subplots. The evaluated variables were Fresh Matter, Dry Matter, Plant Height and Crude Protein Results. Fresh Matter and Crude Protein productions were influenced by planting seasons. Plant densities affected the production of Fresh Matter, Dry Matter and Plant Height, as well as the interaction season by corn INIAP hybrids. While INIAP corn hybrids showed statistical differences in the production of Fresh, Dry Matter, Plant Height and Crude Protein. The eight INIAP hybrids productions were: Fresh Matter (58.86 ton/ha ±5.19; Dry Matter (21.45 ton/ha ±4.71; Plant Height (2.46 m ±0.16 and Crude Protein (10.6±1.12. Conclusions. The performance showed by hybrids INIAP CML-172, INIAP 6021 and INIAP 551 were very acceptable forage material and could be used for silage purposes.

  2. Radiation damage in gallium-stabilized δ-plutonium with helium bubbles

    Science.gov (United States)

    Wu, FengChao; Wang, Pei; Liu, XiaoYi; Wu, HengAn

    2017-02-01

    To understand the role of helium on self-irradiation effects in δ-plutonium, microstructure evolutions due to α-decay events near pre-existing helium bubbles in gallium-stabilized δ-plutonium are investigated using molecular dynamics simulations. Bubble promoting effect plays a dominating role in point defects production, resulting in increasing number of point defects. When lightweight helium atoms act as media, energy transfer discrepancy and altered spatial morphology of point defects induced by mass effect are revealed. The evolution of stacking faults surrounding the disordered core is studied and their binding effect on the propagation of point defects are presented. The cascade-induced bubble coalescence, resolution and re-nucleation driven by internal pressure are obtained in the investigation on helium behaviors. The intrinsic tendency in our simulated self-irradiation with helium bubbles is significant for understanding the underlying mechanism of aging in plutonium and its alloys.

  3. Disposition of PUREX facility tanks D5 and E6 uranium and plutonium solutions. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Harty, D.P.

    1993-12-01

    Approximately 9 kilograms of plutonium and 5 metric tons of uranium in a 1 molar nitric acid solution are being stored in two PUREX facility vessels, tanks D5 and E6. The plutonium was accumulated during cleanup activities of the plutonium product area of the PUREX facility. Personnel at PUREX recently completed a formal presentation to the Surplus Materials Peer Panel (SMPP) regarding disposition of the material currently in these tanks. The peer panel is a group of complex-wide experts who have been chartered by EM-64 (Office of Site and Facility Transfer) to provide a third party independent review of disposition decisions. The information presented to the peer panel is provided in the first section of this report. The panel was generally receptive to the information provided at that time and the recommendations which were identified.

  4. On the Burning of Plutonium Originating from Light Water Reactor Use in a Fast Molten Salt Reactor—A Neutron Physical Study

    Directory of Open Access Journals (Sweden)

    Bruno Merk

    2015-11-01

    Full Text Available An efficient burning of the plutonium produced during light water reactor (LWR operation has the potential to significantly improve the sustainability indices of LWR operations. The work offers a comparison of the efficiency of Pu burning in different reactor configurations—a molten salt fast reactor, a LWR with mixed oxide (MOX fuel, and a sodium cooled fast reactor. The calculations are performed using the HELIOS 2 code. All results are evaluated against the plutonium burning efficiency determined in the Consommation Accrue de Plutonium dans les Réacteurs à Neutrons RApides (CAPRA project. The results are discussed with special view on the increased sustainability of LWR use in the case of successful avoidance of an accumulation of Pu which otherwise would have to be forwarded to a final disposal. A strategic discussion is given about the unavoidable plutonium production, the possibility to burn the plutonium to avoid a burden for the future generations which would have to be controlled.

  5. Plutonium Chemistry in the UREX+ Separation Processes

    Energy Technology Data Exchange (ETDEWEB)

    ALena Paulenova; George F. Vandegrift, III; Kenneth R. Czerwinski

    2009-10-01

    The project "Plutonium Chemistry in the UREX+ Separation Processes” is led by Dr. Alena Paulenova of Oregon State University under collaboration with Dr. George Vandegrift of ANL and Dr. Ken Czerwinski of the University of Nevada at Las Vegas. The objective of the project is to examine the chemical speciation of plutonium in UREX+ (uranium/tributylphosphate) extraction processes for advanced fuel technology. Researchers will analyze the change in speciation using existing thermodynamics and kinetic computer codes to examine the speciation of plutonium in aqueous and organic phases. They will examine the different oxidation states of plutonium to find the relative distribution between the aqueous and organic phases under various conditions such as different concentrations of nitric acid, total nitrates, or actinide ions. They will also utilize techniques such as X-ray absorbance spectroscopy and small-angle neutron scattering for determining plutonium and uranium speciation in all separation stages. The project started in April 2005 and is scheduled for completion in March 2008.

  6. The Growth Condition and Oil Production of Microalgae with Several Kinds of Plant Hormones

    Institute of Scientific and Technical Information of China (English)

    QIU Chen

    2016-01-01

    Microalgae as an important marine resources, rich in high content of polysaccharide, protein, fatty acids. The fatty acid content of microalgae is high, and its propagation speed is faster than herbaceous plants. It also has a high use value. The experiment tried on the basis of the screening of high yield oil microalgae, add different commonly used plant hormone, using growth monitoring, analysis of product components. Select several plant hormones to improve microalgae products production, provides guidance on the deep research and commercial production.

  7. Standard test method for plutonium assay by plutonium (III) diode array spectrophotometry

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2002-01-01

    1.1 This test method describes the determination of total plutonium as plutonium(III) in nitrate and chloride solutions. The technique is applicable to solutions of plutonium dioxide powders and pellets (Test Methods C 697), nuclear grade mixed oxides (Test Methods C 698), plutonium metal (Test Methods C 758), and plutonium nitrate solutions (Test Methods C 759). Solid samples are dissolved using the appropriate dissolution techniques described in Practice C 1168. The use of this technique for other plutonium-bearing materials has been reported (1-5), but final determination of applicability must be made by the user. The applicable concentration range for plutonium sample solutions is 10–200 g Pu/L. 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropria...

  8. Interactive effects of mycorrhizae and a root hemiparasite on plant community productivity and diversity.

    Science.gov (United States)

    Stein, Claudia; Rissmann, Cornelia; Hempel, Stefan; Renker, Carsten; Buscot, François; Prati, Daniel; Auge, Harald

    2009-02-01

    Plant communities can be affected both by arbuscular mycorrhizal fungi (AMF) and hemiparasitic plants. However, little is known about the interactive effects of these two biotic factors on the productivity and diversity of plant communities. To address this question, we set up a greenhouse study in which different AMF inocula and a hemiparasitic plant (Rhinanthus minor) were added to experimental grassland communities in a fully factorial design. In addition, single plants of each species in the grassland community were grown with the same treatments to distinguish direct AMF effects from indirect effects via plant competition. We found that AMF changed plant community structure by influencing the plant species differently. At the community level, AMF decreased the productivity by 15-24%, depending on the particular AMF treatment, mainly because two dominant species, Holcus lanatus and Plantago lanceolata, showed a negative mycorrhizal dependency. Concomitantly, plant diversity increased due to AMF inoculation and was highest in the treatment with a combination of two commercial AM strains. AMF had a positive effect on growth of the hemiparasite, and thereby induced a negative impact of the hemiparasite on host plant biomass which was not found in non-inoculated communities. However, the hemiparasite did not increase plant diversity. Our results highlight the importance of interactions with soil microbes for plant community structure and that these indirect effects can vary among AMF treatments. We conclude that mutualistic interactions with AMF, but not antagonistic interactions with a root hemiparasite, promote plant diversity in this grassland community.

  9. Micro Ion Source Program NA22 Plutonium Detection Portfolio Final Report

    Energy Technology Data Exchange (ETDEWEB)

    James E. Delmore

    2010-09-01

    The purpose of the micro ion source program was to enhance the performance of thermal ionization mass spectrometry (TIMS) for various actinides and fission products. The proposal hypothesized that when ions are created at the ion optic center of the mass spectrometer, ion transmission is significantly increased and the resulting ion beam is more sharply focused. Computer modeling demonstrated this logic. In order to prove this hypothesis it was first necessary to understand the chemistry and physics governing the particular ion production process that concentrates the emission of ions into a small area. This has been achieved for uranium and technetium, as was shown in the original proposal and the improvement of both the beam transmission and sharpness of focus were proven. Significantly improved analytical methods have been developed for these two elements based upon this research. The iodine portion of the proposal turned out to be impractical due to volatility of iodine and its compounds. We knew this was a possibility prior to research and we proceeded anyway but did not succeed. Plutonium is a potential option, but is not quite up to the performance level of resin beads. Now, we more clearly understand the chemical and physical issues for plutonium, but have not yet translated this knowledge into improved analytical processes. The problems are that plutonium is considerably more difficult to convert to the required intermediate species, plutonium carbide, and the chemical method we developed that works with uranium functions only moderately well with plutonium. We are of the opinion that, with this knowledge, similar progress can be made with plutonium.

  10. Plutonium behavior after pulmonary administration according to solubility properties, and consequences on alveolar macrophage activation.

    Science.gov (United States)

    Van der Meeren, Anne; Gremy, Olivier; Renault, Daniel; Miroux, Amandine; Bruel, Sylvie; Griffiths, Nina; Tourdes, Françoise

    2012-01-01

    The physico-chemical form in which plutonium enters the body influences the lung distribution and the transfer rate from lungs to blood. In the present study, we evaluated the early lung damage and macrophage activation after pulmonary contamination of plutonium of various preparation modes which produce different solubility and distribution patterns. Whatever the solubility properties of the contaminant, macrophages represent a major retention compartment in lungs, with 42 to 67% of the activity from broncho-alveolar lavages being associated with macrophages 14 days post-contamination. Lung changes were observed 2 and 6 weeks post-contamination, showing inflammatory lesions and accumulation of activated macrophages (CD68 positive) in plutonium-contaminated rats, although no increased proliferation of pneumocytes II (TTF-1 positive cells) was found. In addition, acid phosphatase activity in macrophages from contaminated rats was enhanced 2 weeks post-contamination as compared to sham groups, as well as inflammatory mediator levels (TNF-α, MCP-1, MIP-2 and CINC-1) in macrophage culture supernatants. Correlating with the decrease in activity remaining in macrophages after plutonium contamination, inflammatory mediator production returned to basal levels 6 weeks post-exposure. The production of chemokines by macrophages was evaluated after contamination with Pu of increasing solubility. No correlation was found between the solubility properties of Pu and the activation level of macrophages. In summary, our data indicate that, despite the higher solubility of plutonium citrate or nitrate as compared to preformed colloids or oxides, macrophages remain the main lung target after plutonium contamination and may participate in the early pulmonary damage.

  11. 10 CFR 71.63 - Special requirement for plutonium shipments.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Special requirement for plutonium shipments. 71.63 Section... MATERIAL Package Approval Standards § 71.63 Special requirement for plutonium shipments. Shipments containing plutonium must be made with the contents in solid form, if the contents contain greater than...

  12. Integration of chemical product development, process design and operation based on a kilo-plant

    Institute of Scientific and Technical Information of China (English)

    QIAN Yu; WU Zhihui; JIANG Yanbin

    2006-01-01

    Presented in this paper is an integrated approach of computer-aided product development, process design and operation analysis based on a kilo-plant. The implemented kilo-plant, as a research platform to manufacture product in kilogram-scale, was designed especially for fine and specialty chemicals. The characteristics of product synthesis, process operation and product quality control are investigated coupled with computer-aided monitoring, online modeling, simulation and operation process optimization. In this way, chemical product discovery, process design and operation are integrated in a systematic approach, in the aim to respond to rapid changing marketplace demands to new products.

  13. The beryllium production at Ulba metallurgical plant (Ust-Kamenogrsk, Kazakhstan)

    Energy Technology Data Exchange (ETDEWEB)

    Dvinskykh, E.M.; Savchuk, V.V.; Tuzov, Y.V. [Ulba Metallurgical Plant (Zavod), Ust-Kamenogorsk, Abay prospect 102 (Kazakhstan)

    1998-01-01

    The Report includes data on beryllium production of Ulba metallurgical plant, located in Ust-Kamenogorsk (Kazakhstan). Beryllium production is showed to have extended technological opportunities in manufacturing semi-products (beryllium ingots, master alloys, metallic beryllium powders, beryllium oxide) and in production of structural beryllium and its parts. Ulba metallurgical plant owns a unique technology of beryllium vacuum distillation, which allows to produce reactor grades of beryllium with a low content of metallic impurities. At present Ulba plant does not depend on raw materials suppliers. The quantity of stored raw materials and semi-products will allow to provide a 25-years work of beryllium production at a full capacity. The plant has a satisfactory experience in solving ecological problems, which could be useful in ITER program. (author)

  14. EFFECTS OF PLANTING DENSITYAND ORGANIC FERTILIZATION DOSES ON PRODUCTIVE EFFICIENCY OF CACTUS PEAR

    Directory of Open Access Journals (Sweden)

    NALÍGIA GOMES DE MIRANDA E SILVA

    2016-01-01

    Full Text Available Cactus is crucial for the livestock of semi - arid regions in Brazil. This plant has shown the high productivity of forage, which is influenced by several management factors. This study aimed to evaluate the effect of organic fertilization doses (20, 40 and 80 t/ ha of bovine manure/ha/two years and planting densities (20, 40, 80 and 160 thousand plants/ha on the productivity of cactus pear Clone IPA - 20 ( Opuntia ficus - indica Mill. At the Experimental Station of Caruaru at the Agronomic Institute of Pernambuco, IPA has conducted the experiment. The experimental design was randomized blocks, with split plot arrangements. Higher shoot productivity was observed with increased population density and the application of manure at 80 t ha - 1two years - 1 with values of 61, 90, 117 and 139 t DM ha - 1 two years - 1 at densities of 20, 40, 80 and 160,000 plants ha - 1. The planting density influenced the productivity of cladode - plant and root dry weight, showing exponential responses, with higher cladode - plant and roots weight by area observed with increased plant density. The efficiency of organic fertilization decreased with the increase in manure doses. For increase cactus productivity, 40 t of bovine manure ha - 1 two years - 1 for plantations with 160,000 plants/ha is recommended.

  15. Use of plutonium in PWR-type reactors; Utilisation du plutonium dans les REP

    Energy Technology Data Exchange (ETDEWEB)

    Berthet, A. [Electricite de France (EDF), 75 - Paris (France). Direction de l' Equipement

    1999-04-01

    The plutonium is used, as fuel, in the pressurized water reactors. It does not exist in nature; butit is fabricated in the reactor by neutrons capture. The MOX (Mixed Oxides) is its usual name. A part is consumed by the fission, the remainder is found in the used fuel released from the reactor. The paper deals with the plutonium specificities, the research and development programs about this fuel. The technical specifications of the PWR recycling the plutonium are also included (radiation protection, reactor fueling). (A.L.B.)

  16. Alternating layers of plutonium and lead or indium as surrogate for plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Rudin, Sven P, E-mail: srudin@lanl.gov [Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2010-03-15

    Elemental plutonium (Pu) assumes more crystal structures than other elements, plausibly due to bonding f electrons becoming non-bonding. Complex geometries hamper understanding of the transition in Pu, but calculations predict this transition in a system with simpler geometry: alternating layers either of plutonium and lead or of plutonium and indium. Here the transition occurs via a pairing-up of atoms within Pu layers. Calculations stepping through this pairing-up reveal valuable details of the transition, for example that the transition from bonding to non-bonding proceeds smoothly.

  17. Alternating layers of plutonium and lead or indium as surrogate for plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Rudin, Sven Peter [Los Alamos National Laboratory

    2009-01-01

    Elemental plutonium (Pu) assumes more crystal structures than other elements, plausibly due to bonding f electrons becoming non-bonding. Complex geometries hamper understanding of the transition in Pu, but calculations predict this transition in a system with simpler geometry: alternating layers either of plutonium and lead or of plutonium and indium. Here the transition occurs via a pairing-up of atoms within Pu layers. Calculations stepping through this pairing-up reveal valuable details of the transition, for example that the transition from bonding to non-bonding proceeds smoothly.

  18. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    Energy Technology Data Exchange (ETDEWEB)

    John Groppo; Thomas Robl; Robert Rathbone

    2006-06-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The secondary classification testing was concluded using a continuous demonstration-scale lamella classifier that was operated at a feed rate of 0.3 to 1.5 tons/hr. Feed to the secondary classifier was generated by operating the primary classifier at the conditions shown to be effective previously. Samples were taken while the secondary classifier was operated under a variety of conditions in order to determine the range of conditions where the unit could be efficiently operated. Secondary classification was effective for producing an ultra-fine ash (UFA) product. Inclined lamella plates provided an effective settling surface for coarser ash particles and plate spacing was shown to be an important variable. Results showed that the closer the plate spacing, the finer the size distribution of the UFA product. Flotation of the secondary classifier feed provided a lower LOI UFA product (2.5% LOI vs. 4.5% LOI) and a dispersant dosage of 2 to 2.5 g/kg was adequate to provide UFA grade (3.8 to 4.4 {micro}m) and recovery (53 to 68% 5{micro}m recovery). The UFA yield without flotation was {approx}33% and lower ({approx}20%) with flotation. Demonstration plant product evaluations showed that water requirements in mortar were reduced and 100% of control strength was achieved in 28 days for the coarser products followed by further strength gain of up to 130% in 56 days. The highest strengths of 110% of control in 7 days and 140% in 56 days were achieved with the finer products. Mortar air requirements for processed products were essentially the same as those for standard mortar, suggesting that the unburned carbon remaining does not have

  19. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    Energy Technology Data Exchange (ETDEWEB)

    Thomas Robl; John Groppo

    2009-06-30

    The overall objective of this project is to design, construct, and operate an ash beneficiation facility that will generate several products from coal combustion ash stored in a utility ash pond. The site selected is LG&E's Ghent Station located in Carroll County, Kentucky. The specific site under consideration is the lower ash pond at Ghent, a closed landfill encompassing over 100 acres. Coring activities revealed that the pond contains over 7 million tons of ash, including over 1.5 million tons of coarse carbon and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. These potential products are primarily concentrated in the lower end of the pond adjacent to the outlet. A representative bulk sample was excavated for conducting laboratory-scale process testing while a composite 150 ton sample was also excavated for demonstration-scale testing at the Ghent site. A mobile demonstration plant with a design feed rate of 2.5 tph was constructed and hauled to the Ghent site to evaluate unit processes (i.e. primary classification, froth flotation, spiral concentration, secondary classification, etc.) on a continuous basis to determine appropriate scale-up data. Unit processes were configured into four different flowsheets and operated at a feed rate of 2.5 tph to verify continuous operating performance and generate bulk (1 to 2 tons) products for product testing. Cementitious products were evaluated for performance in mortar and concrete as well as cement manufacture process addition. All relevant data from the four flowsheets was compiled to compare product yields and quality while preliminary flowsheet designs were generated to determine throughputs, equipment size specifications and capital cost summaries. A detailed market study was completed to evaluate the potential markets for cementitious products. Results of the study revealed that the Ghent local fly ash market is currently oversupplied by more than 500,000 tpy and distant markets (i

  20. Modeling, simulation, and control of an extraterrestrial oxygen production plant

    Science.gov (United States)

    Schooley, L.; Cellier, F.; Zeigler, B.; Doser, A.; Farrenkopf, G.

    1991-01-01

    The immediate objective is the development of a new methodology for simulation of process plants used to produce oxygen and/or other useful materials from local planetary resources. Computer communication, artificial intelligence, smart sensors, and distributed control algorithms are being developed and implemented so that the simulation or an actual plant can be controlled from a remote location. The ultimate result of this research will provide the capability for teleoperation of such process plants which may be located on Mars, Luna, an asteroid, or other objects in space. A very useful near-term result will be the creation of an interactive design tool, which can be used to create and optimize the process/plant design and the control strategy. This will also provide a vivid, graphic demonstration mechanism to convey the results of other researchers to the sponsor.

  1. Recombinant biologic products versus nutraceuticals from plants - a regulatory choice?

    Science.gov (United States)

    Drake, Pascal M W; Szeto, Tim H; Paul, Mathew J; Teh, Audrey Y-H; Ma, Julian K-C

    2017-01-01

    Biotechnology has transformed the potential for plants to be a manufacturing source of pharmaceutical compounds. Now, with transgenic and transient expression techniques, virtually any biologic, including vaccines and therapeutics, could be manufactured in plants. However, uncertainty over the regulatory path for such new pharmaceuticals has been a deterrent. Consideration has been given to using alternative regulatory paths, including those for nutraceuticals or cosmetic agents. This review will consider these possibilities, and discuss the difficulties in establishing regulatory guidelines for new pharmaceutical manufacturing technologies.

  2. Possibilities for using plant extracts added to ruminant feed aimed at improving production results

    Directory of Open Access Journals (Sweden)

    Grdović Svetlana

    2010-01-01

    Full Text Available The use of plant extracts with the objective of improving production results and the quality of food articles of animal origin is an area which is acquiring increasing scientific importance. Numerous investigations carried out so far on ruminants and other species of domestic animals have been aimed at examining specific bioactive matter of plants. The results of these investigations have demonstrated a positive influence on the production results. A large number of data indicate that plant extracts added to animal feed contribute to increasing overall productivity. Furthermore, plant extracts as additives in animal feed have a positive effect also on the health condition of the animals. A large number of plants have characteristics which potentially improve consumption, digestibility and conversion of food, and also growth. Examinations have been performed of the effects of different plant extracts on food consumption, wool growth, growth and composition of the trunk, milk production, reproductive parameters, agents for wool shearing, preventing bloat, methane production, as well as the influence of plants on curbing nematode infestations of ruminants. This work presents a review of scientific investigations of different plant species and their effects on the production characteristics of ruminants. .

  3. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    Energy Technology Data Exchange (ETDEWEB)

    Thomas Robl; John Groppo

    2007-03-31

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. Phase 1 was completed successfully, but the project did not continue on to Phase 2 due to withdrawal of CEMEX from the project. Attempts at replacing CEMEX were not successful. Problematic to the continuation of the project was its location in the Ohio Valley which is oversupplied and has low prices for fly ash and the change in CEMEX priorities due to merger and acquisitions. Thus, CAER concurred with the DOE to conclude the project at the end of Budget Period 1, March 31, 2007.

  4. Thermal disposal of products of animal meal production plants; Thermische Verwertung von Produkten der Tierkoerperbeseitigungsanlagen

    Energy Technology Data Exchange (ETDEWEB)

    Meyer-Pittroff, R.; Stammel, V.

    2001-07-01

    The operation of animal meal and fat production plants is regulated by German and EC law. Thermal processing by combustion or co-combustion is the better alternative in view of the problem of foot-and-mouth disease in several European countries. [German] Die Verarbeitung von Tierkoerpern, Tierkoerperteilen und Schlachtabfaellen zu Tiermehl und Tierfett ist durch das Tierkoerperbeseitigungsgesetz vorgeschrieben. Neben dem Verfuetterungs- und Exportverbot fuer Produkte der Tierkoerperbeseitigungsanlagen, schraenken EU-Vorschriften zusaetzlich die Verwertung von Tiermehl und Tierfetten zu industriellen Produkten ein. Daher ist die thermische Verwertung durch Verbrennung und Mitverbrennung die wesentliche technisch durchfuehrbare Alternative. Mit dem zusaetzlichen Ausbrechen der Maul- und Klauenseuche in mehreren Laendern der Europaeischen Union besteht zudem die Gefahr, dass auch in Deutschland in Zukunft noch mehr Tierkoerper entsorgt werden muessen. (orig.)

  5. Production of novel biopolymers in plants: recent technological advances and future prospects.

    Science.gov (United States)

    Snell, Kristi D; Singh, Vijay; Brumbley, Stevens M

    2015-04-01

    The production of novel biopolymers in plants has the potential to provide renewable sources of industrial materials through agriculture. In this review we will highlight recent progress with plant-based production of polyhydroxyalkanoates (PHAs), silk, elastin, collagen, and cyanophycin with an emphasis on the synthesis of poly[(R)-3-hydroxybutyrate] (PHB), a renewable biodegradable PHA polymer with potential commercial applications in plastics, chemicals, and feed markets. Improved production of PHB has required manipulation of promoters driving expression of transgenes, reduction in activity of endogenous enzymes in competing metabolic pathways, insertion of genes to increase carbon flow to polymer, and basic plant biochemistry to understand metabolic limitations. These experiments have increased our understanding of carbon availability and partitioning in different plant organelles, cell types, and organs, information that is useful for the production of other novel molecules in plants.

  6. Plutonium transport in the environment.

    Science.gov (United States)

    Kersting, Annie B

    2013-04-01

    The recent estimated global stockpile of separated plutonium (Pu) worldwide is about 500 t, with equal contributions from nuclear weapons and civilian nuclear energy. Independent of the United States' future nuclear energy policy, the current large and increasing stockpile of Pu needs to be safely isolated from the biosphere and stored for thousands of years. Recent laboratory and field studies have demonstrated the ability of colloids (1-1000 nm particles) to facilitate the migration of strongly sorbing contaminants such as Pu. In understanding the dominant processes that may facilitate the transport of Pu, the initial source chemistry and groundwater chemistry are important factors, as no one process can explain all the different field observations of Pu transport. Very little is known about the molecular-scale geochemical and biochemical mechanisms controlling Pu transport, leaving our conceptual model incomplete. Equally uncertain are the conditions that inhibit the cycling and mobility of Pu in the subsurface. Without a better mechanistic understanding for Pu at the molecular level, we cannot advance our ability to model its transport behavior and achieve confidence in predicting long-term transport. Without a conceptual model that can successfully predict long-term Pu behavior and ultimately isolation from the biosphere, the public will remain skeptical that nuclear energy is a viable and an attractive alternative to counter global warming effects of carbon-based energy alternatives. This review summarizes our current understanding of the relevant conditions and processes controlling the behavior of Pu in the environment, gaps in our scientific knowledge, and future research needs.

  7. REVIEW OF PLUTONIUM OXIDATION LITERATURE

    Energy Technology Data Exchange (ETDEWEB)

    Korinko, P.

    2009-11-12

    A brief review of plutonium oxidation literature was conducted. The purpose of the review was to ascertain the effect of oxidation conditions on oxide morphology to support the design and operation of the PDCF direct metal oxidation (DMO) furnace. The interest in the review was due to a new furnace design that resulted in oxide characteristics that are different than those of the original furnace. Very little of the published literature is directly relevant to the DMO furnace operation, which makes assimilation of the literature data with operating conditions and data a convoluted task. The oxidation behavior can be distilled into three regimes, a low temperature regime (RT to 350 C) with a relatively slow oxidation rate that is influenced by moisture, a moderate temperature regime (350-450 C) that is temperature dependent and relies on more or less conventional oxidation growth of a partially protective oxide scale, and high temperature oxidation (> 500 C) where the metal autocatalytically combusts and oxidizes. The particle sizes obtained from these three regimes vary with the finest being from the lowest temperature. It is surmised that the slow growth rate permits significant stress levels to be achieved that help break up the oxides. The intermediate temperatures result in a fairly compact scale that is partially protective and that grows to critical thickness prior to fracturing. The growth rate in this regime may be parabolic or paralinear, depending on the oxidation time and consequently the oxide thickness. The high temperature oxidation is invariant in quiescent or nearly quiescent conditions due to gas blanketing while it accelerates with temperature under flowing conditions. The oxide morphology will generally consist of fine particles (<15 {micro}m), moderately sized particles (15 < x < 250 {micro}m) and large particles (> 250 {micro}m). The particle size ratio is expected to be < 5%, 25%, and 70% for fine, medium and large particles, respectively, for

  8. Measurement of Plutonium Isotopic Composition - MGA

    Energy Technology Data Exchange (ETDEWEB)

    Vo, Duc Ta [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-08-21

    In this module, we will use the Canberra InSpector-2000 Multichannel Analyzer with a high-purity germanium detector (HPGe) and the MGA isotopic anlysis software to assay a variety of plutonium samples. The module provides an understanding of the MGA method, its attributes and limitations. You will assess the system performance by measuring a range of materials similar to those you may assay in your work. During the final verification exercise, the results from MGA will be combined with the 240Pueff results from neutron coincidence or multiplicity counters so that measurements of the plutonium mass can be compared with the operator-declared (certified) values.

  9. Diffusion in the uranium - plutonium system and self-diffusion of plutonium in epsilon phase; Diffusion dans le systeme uranium-plutonium et autodiffusion du plutonium epsilon

    Energy Technology Data Exchange (ETDEWEB)

    Dupuy, M. [Commissariat a l' Energie Atomique, Fontenay-Aux-Roses (France). Centre d' Etudes Nucleaires

    1967-07-01

    A survey of uranium-plutonium phase diagram leads to confirm anglo-saxon results about the plutonium solubility in {alpha} uranium (15 per cent at 565 C) and the uranium one in {zeta} phase (74 per cent at 565 C). Interdiffusion coefficients, for concentration lower than 15 per cent had been determined in a temperature range from 410 C to 640 C. They vary between 0.2 and 6 10{sup 12} cm{sup 2} s{sup -1}, and the activation energy between 13 and 20 kcal/mole. Grain boundary, diffusion of plutonium in a uranium had been pointed out by micrography, X-ray microanalysis and {alpha} autoradiography. Self-diffusion of plutonium in {epsilon} phase (bcc) obeys Arrhenius law: D = 2. 10{sup -2} exp -(18500)/RT. But this activation energy does not follow empirical laws generally accepted for other metals. It has analogies with 'anomalous' bcc metals ({beta}Zr, {beta}Ti, {beta}Hf, U{sub {gamma}}). (author) [French] Une etude du diagramme d'equilibre uranium-plutonium conduit a confirmer les resultats anglo-saxons relatifs a la solubilite du plutonium dans l'uranium {alpha} (15 pour cent a 565 C) et de l'uranium dans la phase {zeta} (74 pour cent a 565 C). Les coefficients de diffusion chimique, pour des concentrations inferieures a 15 pour cent ont ete determines a des temperatures comprises entre 410 et 640 C. Ils se situent entre 0.2 et 6. 10{sup 12} cm{sup 2} s{sup -1}. L'energie d'activation varie entre 13 et 20 kcal/mole. La diffusion intergranulaire du plutonium dans l'uranium a a ete mise en evidence par micrographie, microanalyse X et autoradiographie {alpha}. L' autodiffusion du plutonium {beta} cubique centree obeit a la loi d'Arrhenius D = 2. 10{sup -2} exp - (18500)/RT. Son energie d'activation n'obeit pas aux lois empiriques generalement admises pour les autres metaux. Elle possede des analogies avec les cubiques centres ''anormaux'' (Zr{beta}, Ti{beta}, Hf{beta}, U{gamma}). (auteur)

  10. Commercial Plant Production and Consumption Still Follow the Latitudinal Gradient in Species Diversity despite Economic Globalization.

    Science.gov (United States)

    Nelson, Erik J; Helmus, Matthew R; Cavender-Bares, Jeannine; Polasky, Stephen; Lasky, Jesse R; Zanne, Amy E; Pearse, William D; Kraft, Nathan J B; Miteva, Daniela A; Fagan, William F

    2016-01-01

    Increasing trade between countries and gains in income have given consumers around the world access to a richer and more diverse set of commercial plant products (i.e., foods and fibers produced by farmers). According to the economic theory of comparative advantage, countries open to trade will be able to consume more-in terms of volume and diversity-if they concentrate production on commodities that they can most cost-effectively produce, while importing goods that are expensive to produce, relative to other countries. Here, we perform a global analysis of traded commercial plant products and find little evidence that increasing globalization has incentivized agricultural specialization. Instead, a country's plant production and consumption patterns are still largely determined by local evolutionary legacies of plant diversification. Because tropical countries harbor a greater diversity of lineages across the tree of life than temperate countries, tropical countries produce and consume a greater diversity of plant products than do temperate countries. In contrast, the richer and more economically advanced temperate countries have the capacity to produce and consume more plant species than the generally poorer tropical countries, yet this collection of plant species is drawn from fewer branches on the tree of life. Why have countries not increasingly specialized in plant production despite the theoretical financial incentive to do so? Potential explanations include the persistence of domestic agricultural subsidies that distort production decisions, cultural preferences for diverse local food production, and that diverse food production protects rural households in developing countries from food price shocks. Less specialized production patterns will make crop systems more resilient to zonal climatic and social perturbations, but this may come at the expense of global crop production efficiency, an important step in making the transition to a hotter and more

  11. Commercial Plant Production and Consumption Still Follow the Latitudinal Gradient in Species Diversity despite Economic Globalization

    Science.gov (United States)

    Nelson, Erik J.; Helmus, Matthew R.; Cavender-Bares, Jeannine; Polasky, Stephen; Lasky, Jesse R.; Zanne, Amy E.; Pearse, William D.; Kraft, Nathan J. B.; Miteva, Daniela A.; Fagan, William F.

    2016-01-01

    Increasing trade between countries and gains in income have given consumers around the world access to a richer and more diverse set of commercial plant products (i.e., foods and fibers produced by farmers). According to the economic theory of comparative advantage, countries open to trade will be able to consume more–in terms of volume and diversity–if they concentrate production on commodities that they can most cost-effectively produce, while importing goods that are expensive to produce, relative to other countries. Here, we perform a global analysis of traded commercial plant products and find little evidence that increasing globalization has incentivized agricultural specialization. Instead, a country’s plant production and consumption patterns are still largely determined by local evolutionary legacies of plant diversification. Because tropical countries harbor a greater diversity of lineages across the tree of life than temperate countries, tropical countries produce and consume a greater diversity of plant products than do temperate countries. In contrast, the richer and more economically advanced temperate countries have the capacity to produce and consume more plant species than the generally poorer tropical countries, yet this collection of plant species is drawn from fewer branches on the tree of life. Why have countries not increasingly specialized in plant production despite the theoretical financial incentive to do so? Potential explanations include the persistence of domestic agricultural subsidies that distort production decisions, cultural preferences for diverse local food production, and that diverse food production protects rural households in developing countries from food price shocks. Less specialized production patterns will make crop systems more resilient to zonal climatic and social perturbations, but this may come at the expense of global crop production efficiency, an important step in making the transition to a hotter and more

  12. Direct vitrification of plutonium-containing materials (PCM`s) with the glass material oxidation and dissolution system (GMODS)

    Energy Technology Data Exchange (ETDEWEB)

    Forsberg, C.W. Beahm, E.C.; Parker, G.W.; Rudolph, J.C.; Haas, P.A.; Malling, G.F.; Elam, K.; Ott, L.

    1995-10-30

    The end of the cold war has resulted in excess PCMs from nuclear weapons and associated production facilities. Consequently, the US government has undertaken studies to determine how best to manage and dispose of this excess material. The issues include (a) ensurance of domestic health, environment, and safety in handling, storage, and disposition, (b) international arms control agreements with Russia and other countries, and (c) economics. One major set of options is to convert the PCMs into glass for storage or disposal. The chemically inert characteristics of glasses make them a desirable chemical form for storage or disposal of radioactive materials. A glass may contain only plutonium, or it may contain plutonium along with other radioactive materials and nonradioactive materials. GMODS is a new process for the direct conversion of PCMs (i.e., plutonium metal, scrap, and residues) to glass. The plutonium content of these materials varies from a fraction of a percent to pure plutonium. GMODS has the capability to also convert other metals, ceramics, and amorphous solids to glass, destroy organics, and convert chloride-containing materials into a low-chloride glass and a secondary clean chloride salt strewn. This report is the initial study of GMODS for vitrification of PCMs as input to ongoing studies of plutonium management options. Several tasks were completed: initial analysis of process thermodynamics, initial flowsheet analysis, identification of equipment options, proof-of-principle experiments, and identification of uncertainties.

  13. Plant Secondary Metabolites in some Medicinal Plants of Mongolia Used for Enhancing Animal Health and Production

    Directory of Open Access Journals (Sweden)

    Makkar, HPS.

    2009-01-01

    Full Text Available The levels and activities of a number of plant secondary metabolites (PSMs are known to increase in response to increase in stress. The Mongolian plants considered to possess medicinal properties may contain novel compounds since they are exposed to severe conditions; such plants could become good candidates for modern drug discovery programmes. Information on distribution, palatability to livestock and opinion of local people on their nutritive and medicinal values was compiled for 15 plant materials from 14 plant species considered important for medicinal purposes. These plants were evaluated for nutritive value and PSMs: tannins, saponins, lectins, alkaloids and cyanogens. High levels of tannins were found in roots of Bergenia crassifolia and in leaves of B. crassifolia, Vaccinium vitisidaea and Rheum undulatum. High lectin activity (haemagglutination was present in B. crassifolia roots, and leaves of R. undulatum, Iris lacteal and Thymus gobicus contained weak lectin activity. Tanacetum vulgare, Serratula centauroids, Taraxacum officinale and Delphinum elatum leaves contained saponin activity (haemolysis. Alkaloids and cyanogens were not present in any of the samples. The paper discusses the known medicinal uses of these plants in light of the PSMs levels, and identifies plant samples for future applications in human and livestock health, welfare and safety.

  14. New Challenges for the Design of High Value Plant Products: Stabilization of Anthocyanins in Plant Vacuoles

    NARCIS (Netherlands)

    Passeri, V.; Koes, R.; Quattrocchio, F.M.

    2016-01-01

    In the last decade plant biotechnologists and breeders have made several attempt to improve the antioxidant content of plant-derived food. Most efforts concentrated on increasing the synthesis of antioxidants, in particular anthocyanins, by inducing the transcription of genes encoding the synthesizi

  15. Gas exchange rates, plant height, yield components, and productivity of upland rice as affected by plant regulators

    Directory of Open Access Journals (Sweden)

    Rita de Cássia Félix Alvarez

    2012-10-01

    Full Text Available The objective of this work was to evaluate gas exchange rates, plant height, yield components, and productivity of upland rice, as affected by type and application time of plant growth regulators. A randomized block design, in a 4x2 factorial arrangement, with four replicates was used. Treatments consisted of three growth regulators (mepiquat chloride, trinexapac-ethyl, and paclobutrazol, besides a control treatment applied at two different phenological stages: early tillering or panicle primordial differentiation. The experiment was performed under sprinkler-irrigated field conditions. Net CO2 assimilation, stomatal conductance, plant transpiration, and water-use efficiency were measured four times in Primavera upland rice cultivar, between booting and milky grain phenophases. Gas exchange rates were neither influenced by growth regulators nor by application time. There was, however, interaction between these factors on the other variables. Application of trinexapac-ethyl at both tillering and differentiation stages reduced plant height and negatively affected yield components and rice productivity. However, paclobutrazol and mepiquat chloride applied at tillering, reduced plant height without affecting rice yield. Mepiquat chloride acted as a growth stimulator when applied at the differentiation stage, and significantly increased plant height, panicle number, and grain yield of upland rice.

  16. Design and construction of an in-plant activation cassette for transgene expression and recombinant protein production in plants.

    Science.gov (United States)

    Dugdale, Benjamin; Mortimer, Cara L; Kato, Maiko; James, Tess A; Harding, Robert M; Dale, James L

    2014-05-01

    Virus-based transgene expression systems have become particularly valuable for recombinant protein production in plants. The dual-module in-plant activation (INPACT) expression platform consists of a uniquely designed split-gene cassette incorporating the cis replication elements of Tobacco yellow dwarf geminivirus (TYDV) and an ethanol-inducible activation cassette encoding the TYDV Rep and RepA replication-associated proteins. The INPACT system is essentially tailored for recombinant protein production in stably transformed plants and provides both inducible and high-level transient transgene expression with the potential to be adapted to diverse crop species. The construction of a novel split-gene cassette, the inducible nature of the system and the ability to amplify transgene expression via rolling-circle replication differentiates this system from other DNA- and RNA-based virus vector systems used for stable or transient recombinant protein production in plants. Here we provide a detailed protocol describing the design and construction of a split-gene INPACT cassette, and we highlight factors that may influence optimal activation and amplification of gene expression in transgenic plants. By using Nicotiana tabacum, the protocol takes 6-9 months to complete, and recombinant proteins expressed using INPACT can accumulate to up to 10% of the leaf total soluble protein.

  17. Exotic new oxides of plutonium found by using gas thermochromatography

    Energy Technology Data Exchange (ETDEWEB)

    Domanov, V.P.; Buklanov, G.V.; Lobanov, Yu.V [Joint Institute for Nuclear Research, Flerov Laboratory of Nuclear Reactions, Dubna, Moscow (Russian Federation)

    2002-11-01

    The volatility of compounds formed during heating of trace quantities of {sup 238}Pu or {sup 239}Pu in a stream of helium and oxygen mixture was studied by gas thermochromatography. Under certain conditions plutonium forms four adsorption zones with the centers at 450{+-}25degC, 250{+-}25degC, 130{+-}50degC and -105{+-}25degC in quartz thermochromatographic(TC) columns. For the interpretation of the results, model experiments with carrier-free radioisotopes of Os, Re, Ru and Tc were performed. It was found that in the stream of He with a small amounts of O{sub 2}, products were adsorbed at 450-500degC and at 250-300degC in the form of dioxides and trioxides. The results of the TC isolation of volatile oxygen-containing compounds of U and {sup 249}Cf are also presented. Based on the data obtained with Pu, we assume that the first adsorption zone (450{+-}25degC) is due to PuO{sub 2} formation, the second one is due to PuO{sub 3} formation and the third may be due to formation of a plutonium acid H{sub 2}PuO{sub 4} (proposed formula). Comparison of the adsorption zone of OsO{sub 4} with the fourth deposition zone for Pu indicates their similarity. We conclude that at -105{+-}25degC, octovalent plutonium deposits in the form of tetraoxide. (author)

  18. Excess Weapons Plutonium Disposition: Plutonium Packaging, Storage and Transportation and Waste Treatment, Storage and Disposal Activities

    Energy Technology Data Exchange (ETDEWEB)

    Jardine, L J; Borisov, G B

    2004-07-21

    A fifth annual Excess Weapons Plutonium Disposition meeting organized by Lawrence Livermore National Laboratory (LLNL) was held February 16-18, 2004, at the State Education Center (SEC), 4 Aerodromnya Drive, St. Petersburg, Russia. The meeting discussed Excess Weapons Plutonium Disposition topics for which LLNL has the US Technical Lead Organization responsibilities. The technical areas discussed included Radioactive Waste Treatment, Storage, and Disposal, Plutonium Oxide and Plutonium Metal Packaging, Storage and Transportation and Spent Fuel Packaging, Storage and Transportation. The meeting was conducted with a conference format using technical presentations of papers with simultaneous translation into English and Russian. There were 46 Russian attendees from 14 different Russian organizations and six non-Russian attendees, four from the US and two from France. Forty technical presentations were made. The meeting agenda is given in Appendix B and the attendance list is in Appendix C.

  19. Using magnetization measurements to detect small amounts of plutonium hydride formation in plutonium metal

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jae Wook [Rutgers Univ., New Brunswick, NJ (United States); Mielke, Charles H. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Zapf, Vivien [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Baiardo, Joseph P. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mitchell, Jeremy N. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Richmond, Scott [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Schwartz, Daniel S. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mun, Eun D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Smith, Alice Iulia [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-10-20

    We report the formation of plutonium hydride in 2 at % Ga-stabilized δ-Pu, with 1 atomic % H charging. We show that magnetization measurements are a sensitive, quantitative measure of ferromagnetic plutonium hydride against the nonmagnetic background of plutonium. It was previously shown that at low hydrogen concentrations, hydrogen forms super-abundant vacancy complexes with plutonium, resulting in a bulk lattice contraction. Here we use magnetization, X-ray and neutron diffraction measurements to show that in addition to forming vacancy complexes, at least 30% of the H atoms bond with Pu to precipitate PuHx, largely on the surface of the sample with x ~ 1.9. We observe magnetic hysteresis loops below 40 K with magnetic remanence, consistent with precipitates of ferromagnetic PuH1.9.

  20. Role of plants and plant based products towards the control of insect pests and vectors:A novel review

    Institute of Scientific and Technical Information of China (English)

    Elumalai Kuppusamy; Saranya Jayakumar

    2016-01-01

    Insect pests bear harmful effects causing great loss to the agricultural crops, stored agricultural products and vector mosquitoes can cause diseases to human. Plants possess an array of vast repository of phytochemicals and have been used to cure many diseases and to control the infestation of insect pests from time immemorial. Plants are easily biodegradable and ecologically safe for treating on the stored or on the field crops against pests to prevent from further damage or loss of stored products or preventing human from mosquito bites, thus preventing the spreading of dreadful diseases such as chikungunya and malaria. Hence, this review can give a clear insecticidal, pesticidal and mosquitocidal property of several plants against the insect pests and vectors.

  1. UPVapor: Cofrentes nuclear power plant production results analysis software

    Energy Technology Data Exchange (ETDEWEB)

    Curiel, M. [Logistica y Acondicionamientos Industriales SAU, Sorolla Center, local 10, Av. de las Cortes Valencianas No. 58, 46015 Valencia (Spain); Palomo, M. J. [ISIRYM, Universidad Politecnica de Valencia, Camino de Vera s/n, Valencia (Spain); Baraza, A. [Iberdrola Generacion S. A., Central Nuclear Cofrentes, Carretera Almansa Requena s/n, 04662 Cofrentes, Valencia (Spain); Vaquer, J., E-mail: m.curiel@lainsa.co [TITANIA Servicios Tecnologicos SL, Sorolla Center, local 10, Av. de las Cortes Valencianas No. 58, 46015 Valencia (Spain)

    2010-10-15

    UPVapor software version 02 has been developed for the Cofrentes nuclear power plant Data Analysis Department (Spain). It is an analysis graphical environment in which users have available all the plant variables registered in the process computer system (SIEC). In order to perform this, UPVapor software has many advanced graphic tools for work simplicity, as well as a friendly environment easy to use and with many configuration possibilities. Plant variables are classified in the same way that they are in SIEC computer and these values are taken from it through the network of Iberdrola. UPVapor can generate two different types of graphics: evolution graphs and X Y graphs. The first ones analyse the evolution up to twenty plant variables in a user's defined time period and according to historic plant files. Many tools are available: cursors, graphic configuration, mobile means, non valid data visualization ... Moreover, a particular analysis configuration can be saved, as a pre selection, giving the possibility of charging pre selection directly and developing quick monitoring of a group of preselected plant variables. In X Y graphs, it is possible to analyse a variable value against another variable in a defined time. As an option, users can filter previous data depending on a variable certain range, with the possibility of programming up to five filters. As well as the other graph, X Y graph has many configurations, saving and printing options. With UPVapor software, data analysts can save a valuable time during daily work and, as it is of easy utilization, it permits to other users to perform their own analysis without ask the analysts to develop. Besides, it can be used from any work centre with access to network framework. (Author)

  2. New solutions for by-products plants developed by Koksoprojekt

    Energy Technology Data Exchange (ETDEWEB)

    S. Tomal; R. Zajdel; H. Zembala

    2002-07-01

    The paper focuses on recent and current activities of KOKSOPROJEKT Company oriented towards up-to-dating and optimization of its own developed processes and technical solutions. As a result of these activities the investment and operation cost have been decreased and European standards in environmental protection have not only been met, but even exceeded. From among many developments in this field this paper only presents three reliable and efficient processes for coke oven gas desulfurizing: ammonia process, potash-vacuum process and catalytic-soda (KAT-SOD) process. All of mentioned technologies have been implemented in Polish coking plants, and the desulfurization plants operate with good results. 1 tab.

  3. Weapons-grade plutonium dispositioning. Volume 2: Comparison of plutonium disposition options

    Energy Technology Data Exchange (ETDEWEB)

    Brownson, D.A.; Hanson, D.J.; Blackman, H.S. [and others

    1993-06-01

    The Secretary of Energy requested the National Academy of Sciences (NAS) Committee on International Security and Arms Control to evaluate disposition options for weapons-grade plutonium. The Idaho National Engineering Laboratory (INEL) offered to assist the NAS in this evaluation by investigating the technical aspects of the disposition options and their capability for achieving plutonium annihilation levels greater than 90%. This report was prepared for the NAS to document the gathered information and results from the requested option evaluations. Evaluations were performed for 12 plutonium disposition options involving five reactor and one accelerator-based systems. Each option was evaluated in four technical areas: (1) fuel status, (2) reactor or accelerator-based system status, (3) waste-processing status, and (4) waste disposal status. Based on these evaluations, each concept was rated on its operational capability and time to deployment. A third rating category of option costs could not be performed because of the unavailability of adequate information from the concept sponsors. The four options achieving the highest rating, in alphabetical order, are the Advanced Light Water Reactor with plutonium-based ternary fuel, the Advanced Liquid Metal Reactor with plutonium-based fuel, the Advanced Liquid Metal Reactor with uranium-plutonium-based fuel, and the Modular High Temperature Gas-Cooled Reactor with plutonium-based fuel. Of these four options, the Advanced Light Water Reactor and the Modular High Temperature Gas-Cooled Reactor do not propose reprocessing of their irradiated fuel. Time constraints and lack of detailed information did not allow for any further ratings among these four options. The INEL recommends these four options be investigated further to determine the optimum reactor design for plutonium disposition.

  4. Halomethane production in plants: Structure of the biosynthetic SAM-dependent halide methyltransferase from Arabidopsis thaliana**

    Science.gov (United States)

    Schmidberger, Jason W.; James, Agata B.; Edwards, Robert; Naismith, James H.; O’Hagan, David

    2012-01-01

    A product structure of the halomethane producing enzyme in plants (Arabidopsis thaliana) is reported and a model for presentation of chloride/bromide ion to the methyl group of S-adenosyl-L-methionine (SAM) is presented to rationalise nucleophilic halide attack for halomethane production, gaseous natural products that are produced globally. PMID:20376845

  5. Polyol production during heterofermentative growth of the plant isolate Lactobacillus florum 2F

    NARCIS (Netherlands)

    C.A. Tyler; L. Kopit; C. Doyle; A.O. Yu; J. Hugenholtz; M.L. Marco

    2016-01-01

    AIMS: This study examined the fermentative growth and polyol production of Lactobacillus florum and other plant-associated lactic acid bacteria (LAB). METHODS AND RESULTS: Sugar consumption and end-product production were measured for Lact. florum 2F in the presence of fructose, glucose and both sug

  6. Decay Heat Calculations for PWR and BWR Assemblies Fueled with Uranium and Plutonium Mixed Oxide Fuel using SCALE

    Energy Technology Data Exchange (ETDEWEB)

    Ade, Brian J [ORNL; Gauld, Ian C [ORNL

    2011-10-01

    In currently operating commercial nuclear power plants (NPP), there are two main types of nuclear fuel, low enriched uranium (LEU) fuel, and mixed-oxide uranium-plutonium (MOX) fuel. The LEU fuel is made of pure uranium dioxide (UO{sub 2} or UOX) and has been the fuel of choice in commercial light water reactors (LWRs) for a number of years. Naturally occurring uranium contains a mixture of different uranium isotopes, primarily, {sup 235}U and {sup 238}U. {sup 235}U is a fissile isotope, and will readily undergo a fission reaction upon interaction with a thermal neutron. {sup 235}U has an isotopic concentration of 0.71% in naturally occurring uranium. For most reactors to maintain a fission chain reaction, the natural isotopic concentration of {sup 235}U must be increased (enriched) to a level greater than 0.71%. Modern nuclear reactor fuel assemblies contain a number of fuel pins potentially having different {sup 235}U enrichments varying from {approx}2.0% to {approx}5% enriched in {sup 235}U. Currently in the United States (US), all commercial nuclear power plants use UO{sub 2} fuel. In the rest of the world, UO{sub 2} fuel is still commonly used, but MOX fuel is also used in a number of reactors. MOX fuel contains a mixture of both UO{sub 2} and PuO{sub 2}. Because the plutonium provides the fissile content of the fuel, the uranium used in MOX is either natural or depleted uranium. PuO{sub 2} is added to effectively replace the fissile content of {sup 235}U so that the level of fissile content is sufficiently high to maintain the chain reaction in an LWR. Both reactor-grade and weapons-grade plutonium contains a number of fissile and non-fissile plutonium isotopes, with the fraction of fissile and non-fissile plutonium isotopes being dependent on the source of the plutonium. While only RG plutonium is currently used in MOX, there is the possibility that WG plutonium from dismantled weapons will be used to make MOX for use in US reactors. Reactor-grade plutonium

  7. Integration of oxygen membranes for oxygen production in cement plants

    DEFF Research Database (Denmark)

    Puig Arnavat, Maria; Søgaard, Martin; Hjuler, Klaus;

    2015-01-01

    The present paper describes the integration of oxygen membranes in cement plants both from an energy, exergy and economic point of view. Different configurations for oxygen enrichment of the tertiary air for combustion in the pre-calciner and full oxy-fuel combustion in both pre-calciner and kiln...

  8. Insulating wool production plant of reduced environmental impact

    Energy Technology Data Exchange (ETDEWEB)

    Ratti, A.

    1990-11-09

    A plant for producing insulating wool, such as glass wool and/or rock wool, comprises at least one forming machine, at least one polymerization oven, and first and second air treatment means. The total air load of the forming machine and the total air load of the polymerization oven are fed to the first air treament means, from the buffer vessel of which a recycle air load is drawn off. Both the forming machine and the polymerization oven introduce infiltration air loads, which result in the need for a bleed air load to be discharged into the atmosphere through the second air treatment means. In addition, in plants of sufficiently high capacity, it is economically attractive to feed the total air load of the forming machine and polymerization oven separately to the first air treatment means so that the temperature of the forming machine air load undergoes temperature control while the oven air load not only retains its entire heat content, but if possible increases it by heat exchange with other points of the plant at higher temperature. For example, it is possible to increase the temperature of the oven air load with heat recovery downstream of the incinerator furnace so as to recycle it to the oven and reduce or eliminate fuel consumption there. An example of the air load and energy savings possible at a typical plant is included. 2 figs., 1 tab.

  9. Evaluating Sustainability: Soap versus Biodiesel Production from Plant Oils

    Science.gov (United States)

    Pohl, Nicola L. B.; Streff, Jennifer M.; Brokman, Steve

    2012-01-01

    Herein we describe a series of experiments for the undergraduate organic laboratory curriculum in which various plant oils (soybean, rapeseed, and olive) are subjected to saponification and transesterification reactions to create a set of compounds that can function as soaps or as fuels. The experiments introduce students to and asks them to…

  10. Anaerobic digestion of manure - consequences for plant production

    DEFF Research Database (Denmark)

    Løes, Anne-Kristin; Pommeresche, Reidun; Johansen, Anders

    2013-01-01

    methane (CH4) emissions during manure storage. Co-digestion of substrates rich in energy increases the economic viability of the biogas plant, and off-farm substrates such as fish silage or household waste may add nutrients to the farming system. AD may also ease manure handling, while reducing the amount...

  11. NADPH Oxidase-Dependent Superoxide Production in Plant Reproductive Tissues.

    Science.gov (United States)

    Jiménez-Quesada, María J; Traverso, José Á; Alché, Juan de Dios

    2016-01-01

    In the life cycle of a flowering plant, the male gametophyte (pollen grain) produced in the anther reaches the stigmatic surface and initiates the pollen-pistil interaction, an important step in plant reproduction, which ultimately leads to the delivery of two sperm cells to the female gametophyte (embryo sac) inside the ovule. The pollen tube undergoes a strictly apical expansion characterized by a high growth rate, whose targeting should be tightly regulated. A continuous exchange of signals therefore takes place between the haploid pollen and diploid tissue of the pistil until fertilization. In compatible interactions, theses processes result in double fertilization to form a zygote (2n) and the triploid endosperm. Among the large number of signaling mechanisms involved, the redox network appears to be particularly important. Respiratory burst oxidase homologs (Rbohs) are superoxide-producing enzymes involved in a broad range of processes in plant physiology. In this study, we review the latest findings on understanding Rboh activity in sexual plant reproduction, with a particular focus on the male gametophyte from the anther development stages to the crowning point of fertilization. Rboh isoforms have been identified in both the male and female gametophyte and have proven to be tightly regulated. Their role at crucial points such as proper growth of pollen tube, self-incompatibility response and eventual fertilization is discussed.

  12. Some theoretical and practical approaches to the production of candied fruit based on raw plant materials

    Directory of Open Access Journals (Sweden)

    Nepochatykh Tetyana

    2016-06-01

    Full Text Available This article deals with studying the impact of external physical factors on the acceleration of the process of candied fruit production. It is proved, that the diffusion of sugar syrup into raw plant carried in by capillary forces or the forces of wetting. The porosity of materials affects this process the most. To reduce cooking time is possible by artificial increasing the porosity of plant material or by the destruction of the cell membrane of the plant material.

  13. Cultivation of Herbs and Medicinal Plants in Norway - Essential Oil Production and Quality Control

    OpenAIRE

    Rohloff, Jens

    2003-01-01

    Essential oils (EO) are plant secondary metabolites that are known for their fragrance and food flavour properties. They consist of a complex mixture of mono- and sesquiterpenes, phenyl propanoids and oxygenated compounds. EOs can be present in different plant organs and materials, and their storage is related to specialised secretory structures. The yield of EOs from plant raw materials by distillation or pressing may on average vary from 0.1 – 1%, thus restricting the major EO production to...

  14. Plutonium 238/239 Decorporation Model

    Science.gov (United States)

    2014-10-01

    Ionizing Radiation, 3rd ed. Philadelphia, Saunders. Maydew RC, Bush J. 1997. America’s Lost H-Bomb: Palomares, Spain, 1966. Sunflower University Press...3 ∗ The movement of plutonium particulates within the respiratory tract is depicted in Figure 6 and can be represented by the following

  15. Plutonium isotope ratio variations in North America

    Energy Technology Data Exchange (ETDEWEB)

    Steiner, Robert E [Los Alamos National Laboratory; La Mont, Stephen P [Los Alamos National Laboratory; Eisele, William F [Los Alamos National Laboratory; Fresquez, Philip R [Los Alamos National Laboratory; Mc Naughton, Michael [Los Alamos National Laboratory; Whicker, Jeffrey J [Los Alamos National Laboratory

    2010-12-14

    Historically, approximately 12,000 TBq of plutonium was distributed throughout the global biosphere by thermo nuclear weapons testing. The resultant global plutonium fallout is a complex mixture whose {sup 240}Pu/{sup 239}Pu atom ratio is a function of the design and yield of the devices tested. The average {sup 240}Pu/{sup 239}Pu atom ratio in global fallout is 0.176 + 014. However, the {sup 240}Pu/{sup 239}Pu atom ratio at any location may differ significantly from 0.176. Plutonium has also been released by discharges and accidents associated with the commercial and weapons related nuclear industries. At many locations contributions from this plutonium significantly alters the {sup 240}Pu/{sup 239}Pu atom ratios from those observed in global fallout. We have measured the {sup 240}Pu/{sup 239}Pu atom ratios in environmental samples collected from many locations in North America. This presentation will summarize the analytical results from these measurements. Special emphasis will be placed on interpretation of the significance of the {sup 240}Pu/{sup 239}Pu atom ratios measured in environmental samples collected in the Arctic and in the western portions of the United States.

  16. Overview of surplus weapons plutonium disposition

    Energy Technology Data Exchange (ETDEWEB)

    Rudy, G.

    1996-05-01

    The safe disposition of surplus weapons useable plutonium is a very important and urgent task. While the functions of long term storage and disposition directly relate to the Department`s weapons program and the environmental management program, the focus of this effort is particularly national security and nonproliferation.

  17. Use of a Geothermal-Solar Hybrid Power Plant to Mitigate Declines in Geothermal Resource Productivity

    Energy Technology Data Exchange (ETDEWEB)

    Dan Wendt; Greg Mines

    2014-09-01

    Many, if not all, geothermal resources are subject to decreasing productivity manifested in the form of decreasing brine temperature, flow rate, or both during the life span of the associated power generation project. The impacts of resource productivity decline on power plant performance can be significant; a reduction in heat input to a power plant not only decreases the thermal energy available for conversion to electrical power, but also adversely impacts the power plant conversion efficiency. The reduction in power generation is directly correlated to a reduction in revenues from power sales. Further, projects with Power Purchase Agreement (PPA) contracts in place may be subject to significant economic penalties if power generation falls below the default level specified. A potential solution to restoring the performance of a power plant operating from a declining productivity geothermal resource involves the use of solar thermal energy to restore the thermal input to the geothermal power plant. There are numerous technical merits associated with a renewable geothermal-solar hybrid plant in which the two heat sources share a common power block. The geo-solar hybrid plant could provide a better match to typical electrical power demand profiles than a stand-alone geothermal plant. The hybrid plant could also eliminate the stand-alone concentrated solar power plant thermal storage requirement for operation during times of low or no solar insolation. This paper identifies hybrid plant configurations and economic conditions for which solar thermal retrofit of a geothermal power plant could improve project economics. The net present value of the concentrated solar thermal retrofit of an air-cooled binary geothermal plant is presented as functions of both solar collector array cost and electricity sales price.

  18. Assessement of Codes and Standards Applicable to a Hydrogen Production Plant Coupled to a Nuclear Reactor

    Energy Technology Data Exchange (ETDEWEB)

    M. J. Russell

    2006-06-01

    This is an assessment of codes and standards applicable to a hydrogen production plant to be coupled to a nuclear reactor. The result of the assessment is a list of codes and standards that are expected to be applicable to the plant during its design and construction.

  19. 77 FR 1920 - Second Amended Notice of Intent To Modify the Scope of the Surplus Plutonium Disposition...

    Science.gov (United States)

    2012-01-12

    ... (MOX) Fuel Fabrication Facility (MFFF), which DOE is constructing at the Savannah River Site (SRS) in... the other alternatives. The MOX fuel alternative is DOE's preferred alternative for surplus plutonium... suitable for MOX fuel fabrication is disposal at the Waste Isolation Pilot Plant (WIPP) in New...

  20. MAFFRA. Report for first years results of screening of antibacterial plant products for replacing antibiotica

    OpenAIRE

    Højberg, Ole; Canibe, Nuria; Lauridsen, Charlotte

    2017-01-01

    This is the first year internal work report by AU ANIS reporting on the experiments in 2016 with screening of selected antibacterial plant products against E coli, using a piglet stomach and ileum model.

  1. Electrochemical studies on plutonium in molten salts

    Energy Technology Data Exchange (ETDEWEB)

    Bourges, G. [CEA-Centre d' etudes de Valduc, 21 120 Is sur Tille (France)], E-mail: gilles.bourges@cea.fr; Lambertin, D.; Rochefort, S. [CEA-Centre d' etudes de Valduc, 21 120 Is sur Tille (France); Delpech, S.; Picard, G. [Laboratoire d' Electrochimie et de Chimie Analytique (UMR7575, CNRS), ENSCP, 11 rue Pierre et Marie Curie, 75231 Paris (France)

    2007-10-11

    Electrochemical studies on plutonium have been supporting the development of pyrochemical processes involving plutonium at CEA. The electrochemical properties of plutonium have been studied in molten salts - ternary eutectic mixture NaCl-KCl-BaCl{sub 2}, equimolar mixture NaCl-KCl and pure CaCl{sub 2} - and in liquid gallium at 1073 K. The formal, or apparent, standard potential of Pu(III)/Pu redox couple in eutectic mixture of NaCl-KCl-BaCl{sub 2} at 1073 K determined by potentiometry is equal to -2.56 V (versus Cl{sub 2}, 1 atm/Cl{sup -} reference electrode). In NaCl-KCl eutectic mixture and in pure CaCl{sub 2} the formal standard potentials deduced from cyclic voltammetry are respectively -2.54 V and -2.51 V. These potentials led to the calculation of the activity coefficients of Pu(III) in the molten salts. Chronoamperometry on plutonium in liquid gallium using molten chlorides - CaCl{sub 2} and equimolar NaCl/KCl - led to the determination of the activity coefficient of Pu in liquid Ga, log {gamma} = -7.3. This new data is a key parameter to assess the thermodynamic feasibility of a process using gallium as solvent metal. By comparing gallium with other solvent metals - cadmium, bismuth, aluminum - gallium appears to be, with aluminum, more favorable for the selectivity of the separation at 1073 K of plutonium from cerium. In fact, compared with a solid tungsten electrode, none of these solvent liquid metals is a real asset for the selectivity of the separation. The role of a solvent liquid metal is mainly to trap the elements.

  2. Plutonium and americium contamination in Rocky Flats soil, 1973

    Energy Technology Data Exchange (ETDEWEB)

    Krey, P.; Hardy, E.; Volchok, H.; Toonkel, L.; Knuth, R.; Coppes, M.; Tamura, T.

    1976-03-01

    The plutonium mass isotopic analysis and the Am-241 analysis of soil samples from Rocky Flats identify the contamination as Pu which was processed in 1958. The Am-241 activity in the soil will reach its maximum in 2033 and represent 18 percent of the Pu-239-240 activity. Nuclide ratios indicate that current operations at Rocky Flats contribute little to the airborne Pu concentrations which are due to resuspension of the contaminated soil. Root uptake of Pu or Am by vegetation is slight or shows no discrimination among the isotopes and nuclides studied. The relationship between Pu deposition contour and the area enclosed by that contour has been verified for contour values extending over 7 orders of magnitude. This gives confidence to our calculations of the quantities of Pu released on and off the Rocky Flats plant site. (auth)

  3. Hydrogen Production from Hydrogen Sulfide in IGCC Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Elias Stefanakos; Burton Krakow; Jonathan Mbah

    2007-07-31

    IGCC power plants are the cleanest coal-based power generation facilities in the world. Technical improvements are needed to help make them cost competitive. Sulfur recovery is one procedure in which improvement is possible. This project has developed and demonstrated an electrochemical process that could provide such an improvement. IGCC power plants now in operation extract the sulfur from the synthesis gas as hydrogen sulfide. In this project H{sub 2}S has been electrolyzed to yield sulfur and hydrogen (instead of sulfur and water as is the present practice). The value of the byproduct hydrogen makes this process more cost effective. The electrolysis has exploited some recent developments in solid state electrolytes. The proof of principal for the project concept has been accomplished.

  4. High-value products from plants: the challenges of process optimization.

    Science.gov (United States)

    Fischer, Rainer; Vasilev, Nikolay; Twyman, Richard M; Schillberg, Stefan

    2015-04-01

    Plants can be used to produce a diverse repertoire of complex small-molecule compounds and recombinant proteins that are valuable as industrial and pharmaceutical products. But as we move from proof-of-principle experiments and begin to consider the realistic prospects of commercial production, the focus must shift from the achievement of target molecule production and move towards quality, purity and yield aspects that determine commercial feasibility. This review describes some of the recent advances that have been implemented to improve the development of integrated production processes for high-value molecules expressed in plants, including the introduction of novel procedures to increase the likelihood of regulatory acceptance.

  5. UF6 overfilling prevention at Eurodif production Georges Besse plant

    Energy Technology Data Exchange (ETDEWEB)

    Reneaud, J.M. [Eurodif Production, Pierrelatte (France)

    1991-12-31

    Risk of overfilling exists on different equipments of Georges BESSE Plant: cylinders, desublimers and intermediate tanks. The preventive measures are composed of technical devices: desublimers weighing, load monitoring alarms, automatic controls ... and procedures, training, safety organization. In thirteen years of operation, some incidents have occurred but none of them has caused any personal injuries. They are related and discussed. The main factors involved in the Sequoyah fuel facility accident on 1/4/1986 have been analyzed and taken into account.

  6. Production of tetraploid plants of non apomictic citrus genotypes.

    Science.gov (United States)

    Aleza, Pablo; Juárez, José; Ollitrault, Patrick; Navarro, Luis

    2009-12-01

    Ploidy manipulation in Citrus is a major issue of current breeding programs aiming to develop triploid seedless mandarins to address consumer demands for seedless fruits. The most effective method to obtain triploid hybrids is to pollinate tetraploid non apomictic cultivars with pollen of diploid varieties. Such non apomictic tetraploid lines are not found in the citrus germplasm and need to be created. In this work we describe a new methodology based on in vitro shoot-tip grafting combined with treatment of the micro-grafted shoot-tip with colchicine and oryzalin to achieve chromosome doubling and a dechimerization procedure assisted by flow cytometry. Stable tetraploid plants of Clemenules, Fina and Marisol clementines and Moncada mandarin have been obtained directly from shoot tip grafting combined with colchicine and oryzalin treatments or after dechimerization of mixoploids plants (2x-4x). These stable tetraploid plants have been used in 4x x 2x hybridizations, to recover over 3,250 triploid hybrids in 3 years.

  7. Plutonium emission from the Fukushima accident

    Energy Technology Data Exchange (ETDEWEB)

    Bossew, P., E-mail: pbossew@bfs.de [German Federal Office for Radiation Protection, Berlin (Germany)

    2013-07-01

    A strong earthquake and subsequent tsunami on 11{sup th} March 2011 initiated a severe accident in units 1 to 4 of Fukushima Dai-ichi nuclear power plant, resulting in substantial releases of radionuclides. While much has since been published 00 environmental contamination and exposure to radio--iodine and radio-caesium, little is known about releases of plutonium and other non-volatile elements. Although the total activities of released {sup 131}I, {sup 134}Cs and {sup 137}Cs are of the same order of magnitude as of the Chernobyl accident in 1986, the contribution of little volatile elements, including Pu, is much smaller in Fukushima fallout. The reason is the different physical nature of the accident sequence which led to a release of some 10{sup -}5% of the core inventories only (to be compared with 3.5% from Chernobyl). In this contribution the available data on Pu in Fukushima fallout will be reviewed. Data sources are mainly reports and press releases by Japanese authorities and a few scientific articles. The mean ratio {sup 239+240}Pu: {sup 137}Cs in the near field around the NPP (mainly part of Fukushima prefecture and districts of adjacent prefectures) can be assumed about 3 x 10{sup -}7{sup ,} to be compared to nearly 0.01 in the vicinity of Chernobyl, down to about 3 x 10 {sup -6} in Central Europe. Isotopic ratios {sup 238}Pu: {sup 239+240} Pu are about 2.2 (0.46 and 0.035 in Chemobyl and global fallout, respectively). Activity concentrations of Fukushima- {sup 239+240} Pu in surface soil were found up to above 0.1 Bq/kg d.m. in the immediate vicinity of the Fukushima NPP and about one order of magnitude less in Fukushima city, about 60 km away. The {sup 239+240} Pu activity released into the atmosphere is roughly estimated some 10{sup 9} Bq (Chemobyl : almost 10{sup 14} Bq). (author)

  8. Combined evaluation. Plutonium transports in France. Problems of safety and reliability of transport container FS47; Evaluation Conjointe. Transports de plutonium en France. Problemes de surete et de securite du container de transport FS47

    Energy Technology Data Exchange (ETDEWEB)

    Marignac, Y.; Coeytaux, X. [Wise-Paris, 75 (France); Large, J.H. [Nuclear Engineer, Large and Associates, Londres (United Kingdom)

    2004-09-15

    This report concerns the safety and the protection of plutonium dioxide transported from Cogema La Hague to the mixed oxide fuel plant of Marcoule and Cadarache. The French approach of the transport safety is based on the combining of two essential principles: the first one affirms that the performances of the FS47 container in regard of containment (norms TS-R-1 from IAEA for the accidental conditions) is conceived to resist in any situation even terrorism or sabotage. In fact, the IAEA norm follows a probabilistic study without a voluntary attack such a terrorist one. The second principle rests on the ability to prevent the treat of terrorism acts, because of a secrecy policy on the plutonium transport. It appeared that the Green peace association has succeeded several times to know exactly the hours, the trips of the plutonium transport and this simple thing raises more questions than it solves. (N.C.)

  9. New Challenges for the Design of High Value Plant Products: Stabilization of Anthocyanins in Plant Vacuoles.

    Science.gov (United States)

    Passeri, Valentina; Koes, Ronald; Quattrocchio, Francesca M

    2016-01-01

    In the last decade plant biotechnologists and breeders have made several attempt to improve the antioxidant content of plant-derived food. Most efforts concentrated on increasing the synthesis of antioxidants, in particular anthocyanins, by inducing the transcription of genes encoding the synthesizing enzymes. We present here an overview of economically interesting plant species, both food crops and ornamentals, in which anthocyanin content was improved by traditional breeding or transgenesis. Old genetic studies in petunia and more recent biochemical work in brunfelsia, have shown that after synthesis and compartmentalization in the vacuole, anthocyanins need to be stabilized to preserve the color of the plant tissue over time. The final yield of antioxidant molecules is the result of the balance between synthesis and degradation. Therefore the understanding of the mechanism that determine molecule stabilization in the vacuolar lumen is the next step that needs to be taken to further improve the anthocyanin content in food. In several species a phenomenon known as fading is responsible for the disappearance of pigmentation which in some case can be nearly complete. We discuss the present knowledge about the genetic and biochemical factors involved in pigment preservation/destabilization in plant cells. The improvement of our understanding of the fading process will supply new tools for both biotechnological approaches and marker-assisted breeding.

  10. New challenges for the design of high value plant products: stabilization of anthocyanins in plant vacuoles

    Directory of Open Access Journals (Sweden)

    Valentina ePasseri

    2016-02-01

    Full Text Available In the last decade plant biotechnologists and breeders have made several attempt to improve the antioxidant content of plant-derived food. Most efforts concentrated on increasing the synthesis of antioxidants, in particular anthocyanins, by inducing the transcription of genes encoding the synthesizing enzymes. We present here an overview of economically interesting plant species, both food crops and ornamentals, in which anthocyanin content was improved by traditional breeding or transgenesis. Old genetic studies in petunia and more recent biochemical work in brunfelsia, have shown that after synthesis and compartmentalization in the vacuole, anthocyanins need to be stabilized to preserve the color of the plant tissue over time. The final yield of antioxidant molecules is the result of the balance between synthesis and degradation. Therefore the understanding of the mechanism that determine molecule stabilization in the vacuolar lumen is the next step that needs to be taken to further improve the anthocyanin content in food.In several species a phenomenon known as fading is responsible for the disappearance of pigmentation which in some case can be nearly complete. We discuss the present knowledge about the genetic and biochemical factors involved in pigment preservation/destabilization in plant cells.The improvement of our understanding of the fading process will supply new tools for both biotechnological approaches and marker-assisted breeding.

  11. Criticality investigations for the fixed bed nuclear reactor using thorium fuel mixed with plutonium or minor actinides

    Energy Technology Data Exchange (ETDEWEB)

    Sahin, Suemer [Beykoz Lojistik Meslek Yueksekokulu, Beykoz, Istanbul (Turkey)], E-mail: sumer@gazi.edu.tr; Sahin, Haci Mehmet; Acir, Adem [Beykoz Lojistik Meslek Yueksekokulu, Istanbul (Turkey); Al-Kusayer, Tawfik Ahmed [King Saud University, College of Engineering, P.O. Box 800, Riyadh 11421 (Saudi Arabia)

    2009-08-15

    Prospective fuels for a new reactor type, the so called fixed bed nuclear reactor (FBNR) are investigated with respect to reactor criticality. These are (1) low enriched uranium (LEU); (2) weapon grade plutonium + ThO{sub 2}; (3) reactor grade plutonium + ThO{sub 2}; and (4) minor actinides in the spent fuel of light water reactors (LWRs) + ThO{sub 2}. Reactor grade plutonium and minor actinides are considered as highly radio-active and radio-toxic nuclear waste products so that one can expect that they will have negative fuel costs. The criticality calculations are conducted with SCALE5.1 using S{sub 8}-P{sub 3} approximation in 238 neutron energy groups with 90 groups in thermal energy region. The study has shown that the reactor criticality has lower values with uranium fuel and increases passing to minor actinides, reactor grade plutonium and weapon grade plutonium. Using LEU, an enrichment grade of 9% has resulted with k{sub eff} = 1.2744. Mixed fuel with weapon grade plutonium made of 20% PuO{sub 2} + 80% ThO{sub 2} yields k{sub eff} = 1.2864. Whereas a mixed fuel with reactor grade plutonium made of 35% PuO{sub 2} + 65% ThO{sub 2} brings it to k{sub eff} = 1.267. Even the very hazardous nuclear waste of LWRs, namely minor actinides turn out to be high quality nuclear fuel due to the excellent neutron economy of FBNR. A relatively high reactor criticality of k{sub eff} = 1.2673 is achieved by 50% MAO{sub 2} + 50% ThO{sub 2}. The hazardous actinide nuclear waste products can be transmuted and utilized as fuel in situ. A further output of the study is the possibility of using thorium as breeding material in combination with these new alternative fuels.

  12. B-Plant fission product flowsheets: Part 2

    Energy Technology Data Exchange (ETDEWEB)

    Rey, G.

    1961-09-29

    The technical bases for Phase I of the Fission Product Program have previously been presented for Phase I design. This report represents its sequel for Phase II of the program. Phase I provides the means of segregating, concentrating, and aging crude fission product fractions with market value. Phase II is to provide the means for single-line purification and packaging of megacurie quantities of fission products (principally strontium-90). The technical bases for Phase II project scoping studies are presented herein in the form of process flowsheets and tabulated data. Equipment needs are also described. Conceptual processes and flow diagrams for Phase III are presented for the Waste Management Program and the Fission Product Program.

  13. Plutonium, Mineralogy and Radiation Effects

    Science.gov (United States)

    Ewing, R. C.

    2006-05-01

    During the past fifty years, more than 1,800 metric tonnes of Pu and substantial quantities of other "minor" actinides, such as Np, Am and Cm, have been generated in nuclear reactors. Some of these transuranic elements can be a source of energy in fission reactions (e.g., 239Pu), a source of fissile material for nuclear weapons (e.g., 239Pu and 237Np), or are of environmental concern because of their long half- lives and radiotoxicity (e.g., 239Pu, t1/2 = 24,100 years, and 237Np, t1/2 = 2.1 million years). There are two basic strategies for the disposition of these elements: 1.) to "burn" or transmute the actinides using nuclear reactors or accelerators; 2.) to "sequester" the actinides in chemically durable, radiation-resistant materials that are suitable for geologic disposal. There has been substantial interest in the use of actinide-bearing minerals, such as zircon or isometric pyrochlore, A2B2O7 (A = rare earths; B = Ti, Zr, Sn, Hf; Fd3m; Z=8), for the immobilization of actinides, particularly plutonium. One of the principal concerns has been the accumulation of structural damage caused by alpha-decay events, particularly from the recoil nucleus. Systematic ion beam irradiation studies of rare-earth pyrochlores have led to the discovery that certain compositions (B = Zr, Hf) are stable to very high fluences of alpha-decay event damage. Some compositions, Gd2Ti2O7, are amorphized at relatively low doses (0.2 displacements per atom, dpa, at room temperature), while other compositions, Gd2Zr2O7, do not amorphize (even at doses of > 40 dpa at 25K), but instead disorder to a defect fluorite structure. By changing the composition of the A-site (e.g., substitution of different rare earth elements), the temperature above which the pyrochlore composition can no longer be amorphized, Tc, varies by >600 K (e.g., Lu2Ti2O7: Tc = 480 K; Gd2Ti2O7: Tc = 1120 K). The variation in response to irradiation as a function of composition can be used to model the long

  14. Potential for polyhydroxyalkanoate production on German or European municipal waste water treatment plants.

    Science.gov (United States)

    Pittmann, T; Steinmetz, H

    2016-08-01

    Biopolymers, which are made of renewable raw materials and/or biodegradable residual materials present a possible alternative to common plastic. A potential analysis, based on experimental results in laboratory scale and detailed data from German waste water treatment plants, showed that the theoretically possible production of biopolymers in Germany amounts to more than 20% of the 2015 worldwide biopolymer production. In addition a profound estimation regarding all European Union member states showed that theoretically about 115% of the actual worldwide biopolymer production could be produced on European waste water treatment plants. With an upgraded biopolymer production and a theoretically reachable biopolymer proportion of around 60% of the cell dry weight a total of 1,794,656tPHAa or approximately 236% of today's biopolymer production could be produced on waste water treatment plants in the European Union, using primary sludge as raw material only.

  15. Biosynthesis and molecular actions of specialized 1,4-naphthoquinone natural products produced by horticultural plants

    Science.gov (United States)

    Widhalm, Joshua R; Rhodes, David

    2016-01-01

    The 1,4-naphthoquinones (1,4-NQs) are a diverse group of natural products found in every kingdom of life. Plants, including many horticultural species, collectively synthesize hundreds of specialized 1,4-NQs with ecological roles in plant–plant (allelopathy), plant–insect and plant–microbe interactions. Numerous horticultural plants producing 1,4-NQs have also served as sources of traditional medicines for hundreds of years. As a result, horticultural species have been at the forefront of many basic studies conducted to understand the metabolism and function of specialized plant 1,4-NQs. Several 1,4-NQ natural products derived from horticultural plants have also emerged as promising scaffolds for developing new drugs. In this review, the current understanding of the core metabolic pathways leading to plant 1,4-NQs is provided with additional emphasis on downstream natural products originating from horticultural species. An overview on the biochemical mechanisms of action, both from an ecological and pharmacological perspective, of 1,4-NQs derived from horticultural plants is also provided. In addition, future directions for improving basic knowledge about plant 1,4-NQ metabolism are discussed. PMID:27688890

  16. Late-occurring pulmonary pathologies following inhalation of mixed oxide (uranium + plutonium oxide) aerosol in the rat.

    Science.gov (United States)

    Griffiths, N M; Van der Meeren, A; Fritsch, P; Abram, M-C; Bernaudin, J-F; Poncy, J L

    2010-09-01

    Accidental exposure by inhalation to alpha-emitting particles from mixed oxide (MOX: uranium and plutonium oxide) fuels is a potential long-term health risk to workers in nuclear fuel fabrication plants. For MOX fuels, the risk of lung cancer development may be different from that assigned to individual components (plutonium, uranium) given different physico-chemical characteristics. The objective of this study was to investigate late effects in rat lungs following inhalation of MOX aerosols of similar particle size containing 2.5 or 7.1% plutonium. Conscious rats were exposed to MOX aerosols and kept for their entire lifespan. Different initial lung burdens (ILBs) were obtained using different amounts of MOX. Lung total alpha activity was determined by external counting and at autopsy for total lung dose calculation. Fixed lung tissue was used for anatomopathological, autoradiographical, and immunohistochemical analyses. Inhalation of MOX at ILBs ranging from 1-20 kBq resulted in lung pathologies (90% of rats) including fibrosis (70%) and malignant lung tumors (45%). High ILBs (4-20 kBq) resulted in reduced survival time (N = 102; p MOX, similar to results for industrial plutonium oxide alone (1.9% Gy). Staining with antibodies against Surfactant Protein-C, Thyroid Transcription Factor-1, or Oct-4 showed differential labeling of tumor types. In conclusion, late effects following MOX inhalation result in similar risk for development of lung tumors as compared with industrial plutonium oxide.

  17. The Conceptual Design of an Integrated Nuclearhydrogen Production Plant Using the Sulfur Cycle Water Decomposition System

    Science.gov (United States)

    Farbman, G. H.

    1976-01-01

    A hydrogen production plant was designed based on a hybrid electrolytic-thermochemical process for decomposing water. The sulfur cycle water decomposition system is driven by a very high temperature nuclear reactor that provides 1,283 K helium working gas. The plant is sized to approximately ten million standard cubic meters per day of electrolytically pure hydrogen and has an overall thermal efficiently of 45.2 percent. The economics of the plant were evaluated using ground rules which include a 1974 cost basis without escalation, financing structure and other economic factors. Taking into account capital, operation, maintenance and nuclear fuel cycle costs, the cost of product hydrogen was calculated at $5.96/std cu m for utility financing. These values are significantly lower than hydrogen costs from conventional water electrolysis plants and competitive with hydrogen from coal gasification plants.

  18. Exploiting plant-microbe partnerships to improve biomass production and remediation

    Energy Technology Data Exchange (ETDEWEB)

    Weyens, N.; van der Lelie, D.; Taghavi, S.; Newman, L.; Vangronsveld, J.

    2009-10-01

    Although many plant-associated bacteria have beneficial effects on their host, their importance during plant growth and development is still underestimated. A better understanding of their plant growth-promoting mechanisms could be exploited for sustainable growth of food and feed crops, biomass for biofuel production and feedstocks for industrial processes. Such plant growth-promoting mechanisms might facilitate higher production of energy crops in a more sustainable manner, even on marginal land, and thus contribute to avoiding conflicts between food and energy production. Furthermore, because many bacteria show a natural capacity to cope with contaminants, they could be exploited to improve the efficiency of phytoremediation or to protect the food chain by reducing levels of agrochemicals in food crops.

  19. Probiotic fermentation of plant based products: possibilities and opportunities.

    Science.gov (United States)

    Gupta, Shilpi; Abu-Ghannam, Nissreen

    2012-01-01

    Functional foods are claimed to have several health-specific advantages. In addition to their basic nutritive value, they contain a proper balance of ingredients which help in the prevention and treatment of illnesses and diseases. Within this category, products containing lactic acid bacteria or probiotics are increasingly gaining importance. The recognition of the beneficial effects of dairy products containing probiotics has been well established. The allergy to dairy products