Sample records for chrysoberyl

  1. Heat capacities and thermodynamic functions for beryl, Be3Al2Si6O18, phenakite, Be2SiO4, euclase, BeAlSiO4(OH), bertrandite, Be4Si2O7(OH)2, and chrysoberyl, BeAl2O4. (United States)

    Hemingway, B.S.; Barton, M.D.; Robie, R.A.; Haselton, H.T.


    The heat capacities of beryl, phenakite, euclase and bertrandite have been measured between approx 5 and 800 K by combined quasi-adiabatic cryogenic calorimetry and differential scanning calorimetry. The heat capacities of chrysoberyl have been measured from 340 to 800 K. The resulting data have been combined with solution and phase-equilibrium experimental data and simultaneously adjusted using the programme PHAS20 to provide an internally consistent set of thermodynamic properties for several important beryllium phases. The experimental heat capacities and tables of derived thermodynamic properties are presented.-J.A.Z.

  2. Physical properties of BeAl6O10 single crystals (United States)

    Pestryakov, E. V.; Petrov, V. V.; Zubrinov, I. I.; Semenov, V. I.; Trunov, V. I.; Kirpichnikov, A. V.; Alimpiev, A. I.


    Single crystals of BeAl6O10, beryllium hexaaluminate, were grown by the Czochralski method. The optical, acousto-optical, elastic, and a number of thermo-mechanical properties of bulk crystals of BeAl6O10 were investigated in comparison with crystal of BeAl2O4, chrysoberyl. It has been demonstrated that this material is the promising host for active media of tunable solid state lasers.

  3. Physical properties of BeAl{sub 6}O{sub 10} single crystals

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    Pestryakov, E.V.; Petrov, V.V.; Zubrinov, I.I.; Semenov, V.I.; Trunov, V.I.; Kirpichnikov, A.V. [Department of Quantum Electronics, Institute of Semiconductor Physics, Novosibirsk 630090 (Russia); Alimpiev, A.I. [Design and Technological Institute of Monocrystals, Novosibirsk 630058 (Russia)


    Single crystals of BeAl{sub 6}O{sub 10}, beryllium hexaaluminate, were grown by the Czochralski method. The optical, acousto-optical, elastic, and a number of thermo-mechanical properties of bulk crystals of BeAl{sub 6}O{sub 10} were investigated in comparison with crystal of BeAl{sub 2}O{sub 4}, chrysoberyl. It has been demonstrated that this material is the promising host for active media of tunable solid state lasers. {copyright} {ital 1997 American Institute of Physics.}

  4. Solution of rocks and refractory minerals by acids at high temperatures and pressures. Determination of silica after decomposition with hydrofluoric acid (United States)

    May, I.; Rowe, J.J.


    A modified Morey bomb was designed which contains a removable nichromecased 3.5-ml platinium crucible. This bomb is particularly useful for decompositions of refractory samples for micro- and semimicro-analysis. Temperatures of 400-450?? and pressures estimated as great as 6000 p.s.i. were maintained in the bomb for periods as long as 24 h. Complete decompositions of rocks, garnet, beryl, chrysoberyl, phenacite, sapphirine, and kyanite were obtained with hydrofluoric acid or a mixture of hydrofluoric and sulfuric acids; the decomposition of chrome refractory was made with hydrochloric acid. Aluminum-rich samples formed difficultly soluble aluminum fluoride precipitates. Because no volatilization losses occur, silica can be determined on sample solutions by a molybdenum-blue procedure using aluminum(III) to complex interfering fluoride. ?? 1965.

  5. Electron magnetic resonance investigation of chromium diffusion in yttria powders

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    Biasi, R.S. de, E-mail: rsbiasi@ime.eb.b [Secao de Engenharia Mecanica e de Materiais, Instituto Militar de Engenharia, Pr. General Tiburcio, 80, 22290-270 Rio de Janeiro, RJ (Brazil); Grillo, M.L.N., E-mail: mluciag@uerj.b [Instituto de Fisica, Universidade do Estado do Rio de Janeiro, 20550-013 Rio de Janeiro, RJ (Brazil)


    The electron magnetic resonance (EMR) technique was used to investigate the diffusion of chromium in yttria (Y{sub 2}O{sub 3}) powders. The EMR absorption intensity was measured for several annealing times and three different temperatures of isothermal annealing: 1273, 1323 and 1373 K. The activation temperature for diffusion, calculated from the experimental data using a theoretical model based on the Fick equation, was found to be E{sub A}=342+-5 kJ mol{sup -1}. This value is larger than the activation energy for the diffusion of chromium in rutile (TiO{sub 2}), periclase (MgO) and cobalt monoxide (CoO) and smaller than the activation energy for the diffusion of chromium in chrysoberyl (BeAl{sub 2}O{sub 4}).

  6. The geology, mineralogy and rare element geochemistry of the gem deposits of Sri Lanka

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    C. B. Dissanayake


    Full Text Available The gem deposits of Sri Lanka are studied from the point of view of their geology, mineralogy and geochemistry. Nearly all the gem formations are located in the central high-grade metamorphic terrain of the Highland Complex. The gem deposits are classified as sedimentary, metamorphic and magmatic; the sedimentary types being the most abundant. The mineralogy of the gem deposits varies widely with, among others, corundum, chrysoberyl, beryl, spinel, topaz,zircon, tourmaline, garnet and sphene being common.Rare element concentrations in sediments from the three main gem fields of Sri Lanka, namely Ratnapura, Elahera and Walawe, were studied. It was found that some sediments are considerably enriched in certain elements compared to their average continental crustal abundances. The Walawe Ganga sediments show anomalous enrichments of the high field strength and associated elements, particularly Zr, Hf, W and Ti. This is attributed to the presence of accessory mineralssuch as zircon, monazite and rutile. Some of these heavy minerals comprise as much as 50 wt% of sediment. The geochemical enrichment of some trace elements compared to their average crustal abundances indicates that highly differentiated granites and associated pegmatites have provided the source materials for enrichment.

  7. Investigation of synthesized Be-bearing silicate glass as laboratory reference sample at X-ray electron probe microanalysis of silicates (United States)

    Belozerova, Olga Yu.; Mikhailov, Mikhail A.; Demina, Tamara V.


    The article discusses estimates of the stability and homogeneity in Be-Mg-Al-silicate glass produced by the authors and its applicability as a laboratory reference sample for X-ray electron probe microanalysis (EPMA) of Be-bearing silicate matters: crystals and quenching melt (glasses), silicates and oxides. The results were obtained using Superprobe-733 and Superprobe JXA-8200 (JEOL Ltd, Japan) devices. The sample homogeneity was studied on macro (10-100 μm) and micro (1-10 μm) levels and was evaluated by the scheme of dispersion analysis. The applicability of Be-bearing silicate glass as a reference sample for Mg, Al, Si determinations was tested on the international certified reference glasses and laboratory reference samples of minerals with a known composition. The obtained experimental metrological characteristics correspond to the "applied geochemistry" type of analysis (second category) and suggest that Be-bearing silicate glass is appropriate as a laboratory reference sample for EPMA of Be-bearing silicate matters, silicates and oxides. Using Be-Mg-Al-silicate glass as a reference sample we obtained satisfactory data on the composition of both some minerals including cordierite and beryllium cordierite, beryllium indialite, beryl and metastable phases (chrysoberyl, compounds with structure of β-quartz and petalite).

  8. Thermo-optical properties of beryllium containing oxide crystals as materials for high power laser systems (United States)

    Pestryakov, E. V.; Petrov, V. V.; Trunov, V. I.; Kirpichnikov, A. V.; Laptev, A. V.; Matrosov, V. N.


    The elastic and thermo-optical properties of chrysoberyl, beryllium hexaaluminate and beryllium-lanthanum hexaaluminate crystals have been experimentally studied. The velocities of elastic-wave propagation in the crystals are measured by acousto-optic interference method. The values of all the independent components of elastic-constant tensor are determined and used to calculate a number of important dynamic parameters of the crystals such as the Young's and shear moduli, the modulus of volume elasticity, Poisson's ratio, the Debye temperature. Also measurements of refractive indices in 25 - 75 C temperature range in VIS spectral region were performed. Using experimental data the dispersion of thermal optical coefficients (dn/dT) was calculated, these data were employed to evaluate the thermal lens in beryllium containing laser crystals. The experimental and calculated data are compared with similar parameters for well-known laser hosts. Some of beryllium containing oxide crystals was shown to be candidates for master oscillator and amplifying stages of high power femtosecond laser systems.

  9. Pegmatites of the Crystal Mountain district, Larimer County, Colorado (United States)

    Thurston, William R.


    The Front Range of Colorado is composed chiefly of schists of the pre-Cambrian Idaho Springs formation which have been intruded by a variety of granitic batholiths. In the Crystal Mountain district the Mount Olympus granite, a satellite of the Longs Peak batholith, forms sills and essentially concordant multiple intrusions in quartz-mica schist that dips southward at moderate to steep angles. A great number of pegmatites accompanied and followed the intrusion of the sills, and formed concordant and discordant bodies in schist and granite. Over 1,300 pegmatites in the Hyatt area north of the Big Thompson River are mapped and individually described. There are 27 pegmatites in the area that are made up of a wall zone and a core, and one, the pegmatite at the Hyatt mine, is composed of five zones. The largest pegmatites in the area are discordant in schist and occupy zones that are interpreted to be tear faults and tension fractures produced by the successive intrusions of granite that formed multiple sills. The majority of pegmatites in the large multiple sills were emplaced along the foliation and fractures. The composition of 96 percent of the pegmatites is granitic, 3.5 percent are quartz-rich pegmatites, and a few are tourmaline-rich. The pegmatites were intruded over a period of time and probably were derived from a granitic magma at different stages during differentiation. Solutions escaping from many of the pegmatites tournalinized and silicified the wall rocks for a few inches to two feet, but chemical and spectrographic analyses fail to show the transport of any other constituents. Perthite, plagioclase, and quartz are the essential minerals of the pegmatites, and muscovite is a minor but widespread constituent. Tourmaline, garnet, beryl, and apatite are common accessory minerals, and lithiophillitite-triphylite, bismuthinite, uraninite, columbite-tantalite, and chrysoberyl are rare constituents. Beryl is found in 250 or 27 percent of the pegmatites and makes