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Sample records for chemistry agricultural

  1. Compound Identification: A journal of Agricultural and Food Chemistry Perspective

    Science.gov (United States)

    This perspective is designed to summarize the standards that authors of manuscripts submitted to the Journal of Agricultural and Food Chemistry are expected to follow in establishing the structures of either new or unknown compounds identified in the course of a study. It is especially important tha...

  2. Chemistry teaching in the new degrees of Agricultural Engineering

    Science.gov (United States)

    Arce, Augusto; Tarquis, Ana Maria; Castellanos, Maria Teresa; Requejo, Maria Isabel; Cartagena, Maria Carmen

    2013-04-01

    The academic year 2011-12 is the second one implementing Bologna process in ETSI at the subjects of Agricultural Chemistry I and Chemistry II in the new four Degrees: Graduate in Engineering and Agricultural Science, Food Engineering Graduate, Graduate Environmental and engineering Graduate in Biotechnology, for it has been necessary to design and implement new interactive methodologies in the teaching-learning process based on the use of the virtual platform of the UPM, implement new evaluation systems that promote continued participation active student and the development of educational materials to support the subjects of chemistry designed new degrees within the EEES. In addition to the above actions, an assessment test prior chemistry knowledge has been made to all students who enter into Agricultural Grades, improving laboratory practices and the comparative study of academic obtained by the students of the new grades in the subjects of chemistry during the year 2011-12 compared to the 2010-11 academic year. More than 15,000 data have showed a good correlation between the student's prior knowledge, the level test performed, test scores, the overall success rate of the course and the abandonment of the different degrees. Academic results show a higher percentage of students enrolled and presented on a greater number of passes on students enrolled in the 2011-12 academic year for students enrolled in the previous academic year. The improved results have influenced the actions taken and the level of knowledge with students entering. Finally, we propose possible solutions to fix these results in future courses, aiming to improve the degree of efficiency, success and significant absenteeism in the first year as it will condition the dropout rate of these new degrees. Acknowledgements: Proyecto de Innovación Educativa N° IE02054-11/12 UPM. 2012.

  3. One hundred years of the Division of Agricultural and Food Chemistry

    Science.gov (United States)

    The Division of Agricultural and Food Chemistry (AGFD)of the American Chemical Society was 100 years old in 2008. ACS grouped papers into sections at its national meetings starting in 1904, including one dealing with agricultural, biological, and sanitary chemistry. This section became AGFD on Dec...

  4. Chemistry of subsurface drain discharge from an agricultural polder soil

    NARCIS (Netherlands)

    Hesterberg, D.; Vos, de B.; Raats, P.A.C.

    2006-01-01

    Protecting groundwater and surface water quality in drained agricultural lands is aided by an understanding of soil physical and chemical processes affecting leaching of plant nutrients and other chemical constituents, and discharge from subsurface drains. Our objectives were to determine which chem

  5. Water chemistry responses to hydraulic manipulation of an agricultural wetland

    Science.gov (United States)

    Powers, S.; Stanley, E. H.

    2011-12-01

    Small impoundments are often crucial factors for the movement of sediment, organic matter, water-borne nutrients, and toxic materials through river networks. By recent accounting, at least 2.6 million small artificial water bodies exist in the US alone. A large proportion of those structures occur in regions with high intensity of agriculture, such as in the Midwestern grain belt. While small impoundments are aging structures which appear to serve few purposes, some hold ecological and biogeochemical value as artificial wetlands. We documented instantaneous net fluxes of solute (chloride, sulfate, nitrate, ammonium, and soluble reactive phosphorus) through an artificial flow-through wetland in agricultural southern Wisconsin over 6 years which spanned removal of a small dam. Phased dewatering and dam removal ultimately converted the artificial wetland to a canal-like state (increase in mean water velocity from 0.08 to 0.22 m s-1). Mean net flux for chloride across the system averaged nearly 0 g d-1, indicating conservative transport and successful characterization of hydrology. In contrast, net fluxes for other solute forms were altered following loss of the wetland: a persistent net sulfate sink (5-10% of inputs retained), suggestive of sulfate-reducing bacteria, was reduced; seasonal (summer) net sinks for nitrate and ammonium, suggestive of uptake by algae and denitrifying bacteria, were reduced; temporal variability for the net flux of soluble reactive phosphorus was reduced. Overall, loss of the artificial wetland caused by dam removal shifted seasonal and annual net fluxes of biologically available solute toward export. Nutrient retention by artificial wetlands could be important for elemental budgets in regions which have high nutrient loading to surface and ground water.

  6. Knowledge, conservation and sustainable use of soil: agricultural chemistry aspects

    Directory of Open Access Journals (Sweden)

    Paola Adamo

    2011-02-01

    Full Text Available Soil is an environmental resource and plays ecological, social and economic functions which are fundamental for the life. To guarantee its availability to future generations, soil resource needs sustainable management. The CEC Thematic Strategy for Soil Protection identifies a series of soil degradation processes or threats, which must be identified and combated. These include erosion, decline in organic matter, local and diffuse contamination, sealing, compaction, decline in biodiversity, salinisation, floods and landslides. With respect to management of contamination with potentially toxic elements, an approach based on the identification and quantification of the various forms or, at least, the main pools, in which contaminants occur in soil, is envisaged. The residence time of an element in soil depends, indeed, by the mobility of its predominant forms. Speciation studies provide information on the mobility and biological availability of contaminants, and seek to assess not simply the contamination level, but rather the risk/toxicity of a polluted soil and to predict its reduction after application of remediation techniques. Soil degradation is often associated with a decrease in the organic matter content, mainly caused by soil use change and global warming. Improving the accumulation of organic matter in soil or contrasting its reduction has positive effects on soil and water quality, crop yields, biodiversity and climate leading to a reduction of green-house gas emissions from soil to the atmosphere. In order to obtain a real accumulation of organic matter in soil, it is not sufficient to temporarily increase its total content, but it is necessary to favour the main processes which govern organic matter stabilization. This requires an approach at both molecular and multidisciplinary level. The reforestation of agricultural and highly degraded soils or conservative agronomic practices, such as the use of humified compounds characterized by

  7. Knowledge, conservation and sustainable use of soil: agricultural chemistry aspects

    Directory of Open Access Journals (Sweden)

    Paola Adamo

    2009-10-01

    Full Text Available Soil is an environmental resource and plays ecological, social and economic functions which are fundamental for the life. To guarantee its availability to future generations, soil resource needs sustainable management. The CEC Thematic Strategy for Soil Protection identifies a series of soil degradation processes or threats, which must be identified and combated. These include erosion, decline in organic matter, local and diffuse contamination, sealing, compaction, decline in biodiversity, salinisation, floods and landslides. With respect to management of contamination with potentially toxic elements, an approach based on the identification and quantification of the various forms or, at least, the main pools, in which contaminants occur in soil, is envisaged. The residence time of an element in soil depends, indeed, by the mobility of its predominant forms. Speciation studies provide information on the mobility and biological availability of contaminants, and seek to assess not simply the contamination level, but rather the risk/toxicity of a polluted soil and to predict its reduction after application of remediation techniques. Soil degradation is often associated with a decrease in the organic matter content, mainly caused by soil use change and global warming. Improving the accumulation of organic matter in soil or contrasting its reduction has positive effects on soil and water quality, crop yields, biodiversity and climate leading to a reduction of green-house gas emissions from soil to the atmosphere. In order to obtain a real accumulation of organic matter in soil, it is not sufficient to temporarily increase its total content, but it is necessary to favour the main processes which govern organic matter stabilization. This requires an approach at both molecular and multidisciplinary level. The reforestation of agricultural and highly degraded soils or conservative agronomic practices, such as the use of humified compounds characterized by

  8. Proceedings of the frst joint american chemical society agricultural and food chemistry division – american chemical society international chemical sciences chapter in Thailand symposium on agricultural and food chemistry

    Science.gov (United States)

    This Proceedings is a compilation of papers from contributed oral and poster presentations presented at the first joint symposium organized by the American Chemical Society Agricultural and Food Chemistry Division and the American Chemical Society International Chemical Sciences Chapter in Thailand ...

  9. Symposium introduction: the first joint American Chemical Society Agricultural and Food Chemistry Division and the American Chemical Society International Chemical Sciences Chapter in Thailand

    Science.gov (United States)

    The American Chemical Society (ACS) Agricultural and Food Chemistry Division (AGFD) and the ACS International Chemical Sciences Chapter in Thailand (ICSCT) worked together to stage the “1st Joint ACS AGFD - ACS ICSCT Symposium on Agricultural and Food Chemistry,” which was held in Bangkok, Thailand ...

  10. Application, chemistry, and environmental implications of contaminant-immobilization amendments on agricultural soil and water quality.

    Science.gov (United States)

    Udeigwe, Theophilus K; Eze, Peter N; Teboh, Jasper M; Stietiya, Mohammed H

    2011-01-01

    Contaminants such as nitrogen (N), phosphorus (P), dissolved organic carbon (DOC), arsenic (As), heavy metals, and infectious pathogens are often associated with agricultural systems. Various soil and water remediation techniques including the use of chemical amendments have been employed to reduce the risks associated with these contaminants. This paper reviews the use of chemical amendments for immobilizing principal agricultural contaminants, the chemistry of contaminant immobilization, and the environmental consequences associated with the use of these chemical products. The commonly used chemical amendments were grouped into aluminum-, calcium-, and iron-containing products. Other products of interest include phosphorus-containing compounds and silicate clays. Mechanisms of contaminant immobilization could include one or a combination of the following: surface precipitation, adsorption to mineral surfaces (ion exchange and formation of stable complexes), precipitation as salts, and co-precipitation. The reaction pH, redox potential, clay minerals, and organic matter are potential factors that could control contaminant-immobilization processes. Reviews of potential environmental implications revealed that undesirable substances such as trace elements, fluoride, sulfate, total dissolved solids, as well as radioactive materials associated with some industrial wastes used as amendment could be leached to ground water or lost through runoff to receiving water bodies. The acidity or alkalinity associated with some of the industrial-waste amendments could also constitute a substantial environmental hazard. Chemical amendments could introduce elements capable of inducing or affecting the activities of certain lithotrophic microbes that could influence vital geochemical processes such as mineral dissolution and formation, weathering, and organic matter mineralization. PMID:20832118

  11. A Contemporary Introduction to Essential Oils: Chemistry, Bioactivity and Prospects for Australian Agriculture

    OpenAIRE

    Nicholas Sadgrove; Graham Jones

    2015-01-01

    This review is a comprehensive introduction to pertinent aspects of the extraction methodology, chemistry, analysis and pharmacology of essential oils, whilst providing a background of general organic chemistry concepts to readers from non-chemistry oriented backgrounds. Furthermore, it describes the historical aspects of essential oil research whilst exploring contentious issues of terminology. This follows with an examination of essential oil producing plants in the Australian context with ...

  12. Effects of runoff from agricultural catchments on fishpond water chemistry: A long-term study from Třeboň fishponds

    Czech Academy of Sciences Publication Activity Database

    Pechar, Libor; Bastl, J.; Hais, M.; Kröpfelová, L.; Pokorný, Jan; Štíchová, J.; Šulcová, J.

    Wageningen : Wageningen Academic Publishing, 2005 - (Dunne, E.; Reddy, K.; Carton, O.), s. 28-33 ISBN 90-76998612 Institutional research plan: CEZ:AV0Z60870520 Keywords : water chemistry * fishponds * Agricultural catchment Subject RIV: DA - Hydrology ; Limnology

  13. Agriculture

    International Nuclear Information System (INIS)

    The report entitled Climate Change Impacts and Adaptation : A Canadian Perspective, presents a summary of research regarding the impacts of climate change on key sectors over the past five years as it relates to Canada. This chapter on agriculture describes how climate change will affect primary agriculture production in Canada with particular focus on potential adaptation options, and vulnerability of agriculture at the farm level. Agriculture is a vital part of the Canadian economy, although only 7 per cent of Canada's land mass is used for agricultural purposes due to the limitations of climate and soils. Most parts of Canada are expected to experience warmer conditions, longer frost-free seasons and increased evapotranspiration. The impacts of these changes on agriculture will vary depending on precipitation changes, soil conditions, and land use. Northern regions may benefit from longer farming seasons, but poor soil conditions will limit the northward expansion of agricultural crops. Some of the negative impacts associated with climate change on agriculture include increased droughts, changes in pest and pathogen outbreaks, and moisture stress. In general, it is expected that the positive and negative impacts of climate change would offset each other. 74 refs., 2 tabs., 1 fig

  14. Chemistry

    International Nuclear Information System (INIS)

    The chemical research and development efforts related to the design and ultimate operation of molten-salt breeder reactor systems are concentrated on fuel- and coolant-salt chemistry, including the development of analytical methods for use in these systems. The chemistry of tellurium in fuel salt is being studied to help elucidate the role of this element in the intergranular cracking of Hastelloy N. Studies were continued of the effect of oxygen-containing species on the equilibrium between dissolved UF3 and dissolved UF4, and, in some cases, between the dissolved uranium fluorides and graphite, and the UC2. Several aspects of coolant-salt chemistry are under investigation. Hydroxy and oxy compounds that could be formed in molten NaBF4 are being synthesized and characterized. Studies of the chemistry of chromium (III) compounds in fluoroborate melts were continued as part of a systematic investigation of the corrosion of structural alloys by coolant salt. An in-line voltammetric method for determining U4+/U3+ ratios in fuel salt was tested in a forced-convection loop over a six-month period. (LK)

  15. HOW AGRICULTURAL CHEMISTRY CAN CONTRIBUTE TO DEALING WITH PROBLEMS OF ENVIRONMENTAL POLLUTION

    Directory of Open Access Journals (Sweden)

    Carlo Emanuele Gessa

    2010-08-01

    Full Text Available Soil is a complex heterogeneous system whose physical, chemical and biological properties regulate interactions with the chemical species which reach its surface. Soil chemistry is an essential tool for understanding and predicting these interactions. Soil is able to immobilize and transform organic and inorganic molecules by different mechanisms, such as complexing and redox reactions. This behaviour gives soil detoxifying capacities towards pollutants which accumulate in the environment. Pollution by heavy metals is regulated by their solubility in soil solution which in turn depends on soil pH and redox properties and metal speciation. Organic and inorganic colloidal soil fractions can promote the immobilisation, degradation, and diffusion of organic molecules such as agrochemicals, solvents, hydrocarbons and other chemicals which reach the soil by anthropic activities. Predicting the fate of xenobiotics in soil, water, air, and plant ecosystems, the recycling of biomass and the decontamination of polluted soils are of major concern to soil chemistry.

  16. HOW AGRICULTURAL CHEMISTRY CAN CONTRIBUTE TO DEALING WITH PROBLEMS OF ENVIRONMENTAL POLLUTION

    OpenAIRE

    Carlo Emanuele Gessa; Sonia Blasioli; Ilaria Braschi

    2010-01-01

    Soil is a complex heterogeneous system whose physical, chemical and biological properties regulate interactions with the chemical species which reach its surface. Soil chemistry is an essential tool for understanding and predicting these interactions. Soil is able to immobilize and transform organic and inorganic molecules by different mechanisms, such as complexing and redox reactions. This behaviour gives soil detoxifying capacities towards pollutants which accumulate in the environment. Po...

  17. A Contemporary Introduction to Essential Oils: Chemistry, Bioactivity and Prospects for Australian Agriculture

    Directory of Open Access Journals (Sweden)

    Nicholas Sadgrove

    2015-03-01

    Full Text Available This review is a comprehensive introduction to pertinent aspects of the extraction methodology, chemistry, analysis and pharmacology of essential oils, whilst providing a background of general organic chemistry concepts to readers from non-chemistry oriented backgrounds. Furthermore, it describes the historical aspects of essential oil research whilst exploring contentious issues of terminology. This follows with an examination of essential oil producing plants in the Australian context with particular attention to Aboriginal custom use, historical successes and contemporary commercial prospects. Due to the harsh dry environment of the Australian landmass, particularly to the cyclical climatic variation attendant upon repeated glaciation/post-glaciation cycles, the arid regions have evolved a rich assortment of unique endemic essential oil yielding plants. Though some of these aromatic plants (particularly myrtaceous species have given birth to commercially valuable industries, much remains to be discovered. Given the market potential, it is likely that recent discoveries in our laboratory and elsewhere will lead to new product development. This review concludes with an emphasis on the use of chemotaxonomy in selection of commercially viable cultivar chemotypes from the Australian continent. Finally, drawing largely from our own results we propose a list of Australian endemic species with novel commercial potential.

  18. Chemistry

    International Nuclear Information System (INIS)

    Research progress is reported in programs on fuel-salt chemistry, properties of compounds in the Li--Te system, Te spectroscopy UF4--H equilibria, porous electrode studies of molten salts, fuel salt-coolant salt reactions, thermodynamic properties of transition-metal fluorides, and properties of sodium fluoroborate. Developmental work on analytical methods is summarized including in-line analysis of molten MSBR fuel, analysis of coolant-salts for tritium, analysis of molten LiF--BeF2--ThF4 for Fe and analysis of LiF--BeF--ThF4 for Te

  19. 农业院校《基础化学实验》教学中化学史的渗透%Introduction of Chemistry History into the Teaching of Basic Chemistry Experiment of Agricultural Universities

    Institute of Scientific and Technical Information of China (English)

    赵李霞; 付颖; 叶非

    2012-01-01

    基础化学实验课程是高等农业院校基础化学系列课程体系中的重要组成部分。在大一新生《基础化学实验》教学中渗透化学史教育,可以提高学生动手积极性,开拓学生实验思路,改善实验课堂教学效果。%In agricultural universities, basic chemistry experiment is an important part of chemistry curriculums. To freshmen of agricul- tural universities, learning basic chemistry experiment well could make good preparation for their further learning and practices. Introduction chemistry history into the teaching of basic chemistry experiment would improve teaching quality and stimulate students' learning interest.

  20. Chemistry

    International Nuclear Information System (INIS)

    Research and development activities dealing with the chemical problems related to design and ultimate operation of molten-salt reactor systems are described. An experimental test stand was constructed to expose metallurgical test specimens to Te2 vapor at defined temperatures and deposition rates. To better define the chemistry of fluoroborate coolant, several aspects are being investigated. The behavior of hydroxy and oxy compounds in molten NaBF4 is being investigated to define reactions and compounds that may be involved in corrosion and/or could be involved in methods for trapping tritium. Two corrosion products of Hastelloy N, Na3CrF6 and Na5Cr3F14, were identified from fluoroborate systems. The evaluation of fluoroborate and alternate coolants continued. Research on the behavior of hydrogen and its isotopes is summarized. The solubilities of hydrogen, deuterium, and helium in Li2BeF4 are very low. The sorption of tritium on graphite was found to be significant (a few milligrams of tritium per kilogram of graphite), possibly providing a means of sequestering a portion of the tritium produced. Development of analytical methods continued with emphasis on voltammetric and spectrophotometric techniques for the in-line analysis of corrosion products such as Fe2+ and Cr3+ and the determination of the U3+/U4+ ratio in MSBR fuel salt. Similar studies were conducted with the NaBF4--NaF coolant salt. Information developed during the previous operation of the CSTF has been assessed and used to formulate plans for evaluation of in-line analytical methods in future CSTF operations. Electroanalytical and spectrophotometric research suggests that an electroactive protonic species is present in molten NaBF4--NaF, and that this species rapidly equilibrates with a volatile proton-containing species. Data obtained from the CSTF indicated that tritium was concentrated in the volatile species. (JGB)

  1. Effects of runoff from agricultural catchments on fishpond water chemistry. A long term study of Třeboň fishponds, Czech republic

    Czech Academy of Sciences Publication Activity Database

    Šulcová, J.; Štíchová, J.; Pechar, Libor

    Padova : P.A.N. s.r.l.,, 2007 - (Maurizio, B.; Bacelle, S.), s. 202-203 ISBN 978-88-902948-0-8. [Multi functions of wetland systems. Padova (IT), 26.06.2007-29.06.2007] R&D Projects: GA MŽP(CZ) SM/640/18/03 Institutional research plan: CEZ:AV0Z60870520 Keywords : fishpond systems * water chemistry * fishery practises * agricultural practises Subject RIV: GL - Fishing

  2. Evolution of the teachings of chemistry in the new degrees of School of Agricultural Engineering and its importance in the acquisition of competencies

    Science.gov (United States)

    Arce, Augusto; Tarquis, Ana M.; Castellanos, Maria Teresa; Requejo, Maria Isabel; Cartagena, Maria Carmen

    2014-05-01

    The academic year 2012-13 is the third year of implementation of the Bologna process in ETSI Agricultural for the subjects Chemistry I and Chemistry II in the new four Degrees: Graduate in Engineering and Agricultural Science, Food Engineering Graduate, Graduate in Engineering Environmental and Biotechnology graduate. We have implemented new interactive methodologies in the teaching-learning process based on the use of the virtual platform of the UPM, and teaching support materials and new laboratory practice developing has. It has also launched new continuous assessment systems that promote active student participation. A comparative study of academic achievements by students of the new grades in the subjects of chemistry during the last three academic years was performed to correlating the results obtained, the success rate and the drop out, and compare with the level of prior knowledge to those entering students. Possible solutions to try and fix these results in future courses are proposed Finally, the general competencies that contribute this course, how they are acquired and how they should be evaluated correctly are indicated. Acknowledgments: Innovation educative projects Nº IE02054-11/12 UPM. 2012

  3. Morphology, chemistry and distribution of neoformed spherulites in agricultural land affected by metallurgical point-source pollution

    International Nuclear Information System (INIS)

    Metal distribution patterns in superficial soil horizons of agricultural land affected by metallurgical point-source pollution were studied using optical and electron microscopy, synchrotron radiation and spectroscopy analyses. The site is located in northern France, at the center of a former entry lane to a bunker of World War II, temporarily paved with coarse industrial waste fragments and removed at the end of the war. Thin sections made from undisturbed soil samples from A and B horizons were studied. Optical microscopy revealed the occurrence of yellow micrometer-sized (Ap horizon) and red decamicrometer-sized spherulites (AB, B1g horizons) as well as distinct distribution patterns. The chemical composition of the spherulites was dominated by Fe, Mn, Zn, Pb, Ca, and P. Comparison of calculated Zn stocks, both in the groundmass and in spherulites, showed a quasi-exclusive Zn accumulation in these neoformed features. Their formation was related to several factors: (i) liberation of metal elements due to weathering of waste products, (ii) Ca and P supply from fertilizing practices, (iii) co-precipitation of metal elements and Ca and P in a porous soil environment, after slow exudation of a supersaturated soil solution in more confined mineral media. - Metal spherulites may act as high metal-trapping mineral phases in polluted agricultural soils

  4. Network Teaching Platform Construction of Fundamental Chemistry Experiments in Agricultural Universities%农业院校基础化学实验网络教学平台的构建

    Institute of Scientific and Technical Information of China (English)

    赵仲麟; 苏同福; 徐翠莲; 潘振良; 李鑫; 李燕; 袁超

    2012-01-01

    Fundamental chemistry is an important basic experimental course in agricultural universities.In this paper,we discussed the problems of fundamental chemistry experimental teaching in agricultural universities.Experimental network teaching platform was constructed.Network teaching could provide students a creative and independent learning environment.A good fundamental chemistry experimental teaching network resources will improve students' learning efficiency.%基础化学实验是农业类高等院校中一门重要的基础实验课程,通过分析目前农业类高校中传统基础化学实验教学存的问题,结合当前的网络技术,构建了基础化学实验网络平台。计算机网络平台为学生提供了创造性、自主性的实验学习环境,丰富完善的基础化学实验网络资源和课前预习系统大大提高学生的学习效果。

  5. The New Color of Chemistry: Green Chemistry

    OpenAIRE

    Zuhal GERÇEK

    2012-01-01

    Green chemistry which is the new application of chemistry rules provides solutions to problems that mankind is faced with climate changes, sustainable agriculture, energy, toxics, depletion of natural sources e.g. designing new chemicals and processes that production and utilization of hazardous matters. So, it is the indispensible tool for sustainable development. Current and future chemists should consider the human health and ecological issues in their professional life. In order to provid...

  6. The New Color of Chemistry: Green Chemistry

    Directory of Open Access Journals (Sweden)

    Zuhal GERÇEK

    2012-01-01

    Full Text Available Green chemistry which is the new application of chemistry rules provides solutions to problems that mankind is faced with climate changes, sustainable agriculture, energy, toxics, depletion of natural sources e.g. designing new chemicals and processes that production and utilization of hazardous matters. So, it is the indispensible tool for sustainable development. Current and future chemists should consider the human health and ecological issues in their professional life. In order to provide a solution for this requirement, green chemistry rules and under standings should be primarily taken in the university curriculum and at all educational levels.

  7. Green chemistry

    International Nuclear Information System (INIS)

    The depletion of world fossil fuel reserves and the involvement of greenhouse gases in the global warming has led to change the industrial and energy policies of most developed countries. The goal is now to reserve petroleum to the uses where it cannot be substituted, to implement renewable raw materials obtained from plants cultivation, and to consider the biodegradability of molecules and of manufactured objects by integrating the lifetime concept in their expected cycle of use. The green chemistry includes the design, development and elaboration of chemical products and processes with the aim of reducing or eliminating the use and generation of harmful compounds for the health and the environment, by adapting the present day operation modes of the chemical industry to the larger framework of the sustainable development. In addition to biofuels, this book reviews the applications of green chemistry in the different industrial processes in concern. Part 1 presents the diversity of the molecules coming from renewable carbon, in particular lignocellulose and the biotechnological processes. Part 2 is devoted to materials and treats of the overall available technological solutions. Part 3 focusses on functional molecules and chemical intermediates, in particular in sugar- and fats-chemistry. Part 4 treats of biofuels under the aspects of their production and use in today's technologies. The last part deals with the global approaches at the environmental and agricultural levels. (J.S.)

  8. SCIENCE AND EDUCATION ACTUALITY AT THE SOIL SCIENCE AND AGRICULTURAL CHEMISTRY FACULTY: THE 90-TH ANNI-VERSARY OF KUBAN STATE AGRARIAN UNI-VERSITY Актуальность науки и образования на факультете агрохимии и почвоведения: 90-летию Кубанского ГАУ

    Directory of Open Access Journals (Sweden)

    Sheudghen A. H.

    2012-02-01

    Full Text Available This article is dedicated to the memory of the staff of teachers, academicians and students of soil science and agricultural chemistry faculty, who have worked and stud-ied in years of its establishment. It has materials from the history of the oldest Kuban State Agrarian University de-partments’: soil science, agricultural chemistry, inorganic and analytical chemistry, organic chemistry

  9. SCIENCE AND EDUCATION ACTUALITY AT THE SOIL SCIENCE AND AGRICULTURAL CHEMISTRY FACULTY: THE 90-TH ANNI-VERSARY OF KUBAN STATE AGRARIAN UNI-VERSITY Актуальность науки и образования на факультете агрохимии и почвоведения: 90-летию Кубанского ГАУ

    OpenAIRE

    Sheudghen A. H.; Onishchenko L. M.; Terpelets V. I.; Kaigorodova E. A.; Dotsenko S. P.

    2012-01-01

    This article is dedicated to the memory of the staff of teachers, academicians and students of soil science and agricultural chemistry faculty, who have worked and stud-ied in years of its establishment. It has materials from the history of the oldest Kuban State Agrarian University de-partments’: soil science, agricultural chemistry, inorganic and analytical chemistry, organic chemistry

  10. EPA Environmental Chemistry Laboratory

    Science.gov (United States)

    1993-01-01

    The Environmental Protection Agency's (EPA) Chemistry Laboratory (ECL) is a national program laboratory specializing in residue chemistry analysis under the jurisdiction of the EPA's Office of Pesticide Programs in Washington, D.C. At Stennis Space Center, the laboratory's work supports many federal anti-pollution laws. The laboratory analyzes environmental and human samples to determine the presence and amount of agricultural chemicals and related substances. Pictured, ECL chemists analyze environmental and human samples for the presence of pesticides and other pollutants.

  11. Hematologi dan Kimia Klinik Darah Kambing Peranakan Etawah yang Diberi Pakan Produk Sampingan Pertanian dan Enzim Optizym (HEMATOLOGY AND BLOOD CLINICAL CHEMISTRY OF ETAWAH GOAT CROSSBRED-FED AGRICULTURE BY PRODUCTS SUPPLEMENTED WITH OPTIZYM ENZYME

    Directory of Open Access Journals (Sweden)

    Wayan Sayang Yupardhi

    2013-08-01

    Full Text Available In Indonesia including Bali island until now, a lot of Etawah Goat Crossbred raised by farmers. Inthe island, there was  lots of  agriculture by products available which were not much used yet for animalfeed. There is an opportunity the product were supplemented with Optizym enzyme to  feed the animal.The enzyme was a cellulotic one. The objective of this experiment was to study hematology (packaged cellvolume, hemoglobin, erythrocytes, leukocytes, neutrophil, lymphocyte, monocyte, eosinophil, sedimentationrate and clinical chemistry of blood (creatinine, urea, serum glutamic piruvat transaminase, serum glutamicoxaloacetic transaminase, glucose, and cholesterol. The experiment was conducted for 2 months at Bukit-Jimbaran, Badung, Bali. Measurements were conducted  on the packaged cell volume with the method ofmicrohematocrite, hemoglobin with the method of Hematin (Hemoglobinometer or Hemometer Sahli,erythrocytes and leukocytes with the method of Hemocytometer (improved Neubaeur, differential ofleukocytes (neutrophil, lymphocyte, monocyte, eosinophil with the method of slide; and blood sedimentationrate with the method of Westergreen, while measurements of the creatinine, urea, serum glutamic piruvattransaminase, serum glutamic oxaloacetic transaminase, glucose, and cholesterol were conducted with Reflotron Plus modified Reflovet Plus (Roch.Data were analyzed with Analysis of Variance. Results ofthe experiment showed that supplementation of the optizym for 0,25 kg and 0,50 kg in every 100 kg basaldiet of agriculture by products (unconventional were not increased significantly on the packaged cellvolume, hemoglobin, total erythrocytes, total leucocytes, neuthrophil, lymposite, monocyte and the samething was also occurred on serum glutamic piruvat transaminase, serum glutamic oxaloacetictransaminase, glucose, and cholesterol of the animals (P > 0.05 compared to the untreated one; while therest (blood sedimentation rate, creatinine, and urea

  12. Bad chemistry

    OpenAIRE

    Petsko, Gregory A

    2004-01-01

    General chemistry courses haven't changed significantly in forty years. Because most basic chemistry students are premedical students, medical schools have enormous influence and could help us start all over again to create undergraduate chemistry education that works.

  13. Agriculture Oral Presentations

    International Nuclear Information System (INIS)

    This publication contains 23 papers related to the use of nuclear techniques in plant breeding in Turkey, effect of gamma irradiations on growing various plants, mutations and soil chemistry, etc., presented at 4. International Congress of Nuclear Agriculture and Animal Science in Bursa, Turkey, 25-27 Sep 1996. A separate abstract was prepared for each paper

  14. Complex chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Bong Gon; Kim, Jae Sang; Kim, Jin Eun; Lee, Boo Yeon

    2006-06-15

    This book introduces complex chemistry with ten chapters, which include development of complex chemistry on history coordination theory and Warner's coordination theory and new development of complex chemistry, nomenclature on complex with conception and define, chemical formula on coordination compound, symbol of stereochemistry, stereo structure and isomerism, electron structure and bond theory on complex, structure of complex like NMR and XAFS, balance and reaction on solution, an organo-metallic chemistry, biology inorganic chemistry, material chemistry of complex, design of complex and calculation chemistry.

  15. Complex chemistry

    International Nuclear Information System (INIS)

    This book introduces complex chemistry with ten chapters, which include development of complex chemistry on history coordination theory and Warner's coordination theory and new development of complex chemistry, nomenclature on complex with conception and define, chemical formula on coordination compound, symbol of stereochemistry, stereo structure and isomerism, electron structure and bond theory on complex, structure of complex like NMR and XAFS, balance and reaction on solution, an organo-metallic chemistry, biology inorganic chemistry, material chemistry of complex, design of complex and calculation chemistry.

  16. Mathematical Chemistry

    OpenAIRE

    Trinajstić, Nenad; Gutman, Ivan

    2002-01-01

    A brief description is given of the historical development of mathematics and chemistry. A path leading to the meeting of these two sciences is described. An attempt is made to define mathematical chemistry, and journals containing the term mathematical chemistry in their titles are noted. In conclusion, the statement is made that although chemistry is an experimental science aimed at preparing new compounds and materials, mathematics is very useful in chemistry, among other things, to produc...

  17. Combinatorial chemistry

    DEFF Research Database (Denmark)

    Nielsen, John

    1994-01-01

    An overview of combinatorial chemistry is presented. Combinatorial chemistry, sometimes referred to as `irrational drug design,' involves the generation of molecular diversity. The resulting chemical library is then screened for biologically active compounds.......An overview of combinatorial chemistry is presented. Combinatorial chemistry, sometimes referred to as `irrational drug design,' involves the generation of molecular diversity. The resulting chemical library is then screened for biologically active compounds....

  18. Positronium chemistry

    CERN Document Server

    Green, James

    1964-01-01

    Positronium Chemistry focuses on the methodologies, reactions, processes, and transformations involved in positronium chemistry. The publication first offers information on positrons and positronium and experimental methods, including mesonic atoms, angular correlation measurements, annihilation spectra, and statistical errors in delayed coincidence measurements. The text then ponders on positrons in gases and solids. The manuscript takes a look at the theoretical chemistry of positronium and positronium chemistry in gases. Topics include quenching, annihilation spectrum, delayed coincidence

  19. Nuclear analytical chemistry

    International Nuclear Information System (INIS)

    This book covers the general theories and techniques of nuclear chemical analysis, directed at applications in analytical chemistry, nuclear medicine, radiophysics, agriculture, environmental sciences, geological exploration, industrial process control, etc. The main principles of nuclear physics and nuclear detection on which the analysis is based are briefly outlined. An attempt is made to emphasise the fundamentals of activation analysis, detection and activation methods, as well as their applications. The book provides guidance in analytical chemistry, agriculture, environmental and biomedical sciences, etc. The contents include: the nuclear periodic system; nuclear decay; nuclear reactions; nuclear radiation sources; interaction of radiation with matter; principles of radiation detectors; nuclear electronics; statistical methods and spectral analysis; methods of radiation detection; neutron activation analysis; charged particle activation analysis; photon activation analysis; sample preparation and chemical separation; nuclear chemical analysis in biological and medical research; the use of nuclear chemical analysis in the field of criminology; nuclear chemical analysis in environmental sciences, geology and mineral exploration; and radiation protection

  20. Tropical Soil Chemistry

    DEFF Research Database (Denmark)

    Borggaard, Ole K.

    A new book that is particularly relevant as tropical countries experience increased pressure on land resources to improve agricultural production. To ensure sustainable land use, the potentials and limitations of different kinds of tropical soils must be known in relation to crop production...... soil chemical issues are also presented to assess when, why, and how tropical soils differ from soils in other regions. This knowledge can help agricultural specialists in the tropics establish sustainable crop production. Readers are assumed to be familiar with basic chemistry, physics...... and environmental protection. Tropical Soil Chemistry by Ole K. Borggaard provides an overview of the composition, occurrence, properties, processes, formation, and environmental vulnerability of various tropical soil types (using American Soil Taxonomy for classification). The processes and the external factors...

  1. Nuclear analytical chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Brune, D.; Forkman, B.; Persson, B.

    1984-01-01

    This book covers the general theories and techniques of nuclear chemical analysis, directed at applications in analytical chemistry, nuclear medicine, radiophysics, agriculture, environmental sciences, geological exploration, industrial process control, etc. The main principles of nuclear physics and nuclear detection on which the analysis is based are briefly outlined. An attempt is made to emphasise the fundamentals of activation analysis, detection and activation methods, as well as their applications. The book provides guidance in analytical chemistry, agriculture, environmental and biomedical sciences, etc. The contents include: the nuclear periodic system; nuclear decay; nuclear reactions; nuclear radiation sources; interaction of radiation with matter; principles of radiation detectors; nuclear electronics; statistical methods and spectral analysis; methods of radiation detection; neutron activation analysis; charged particle activation analysis; photon activation analysis; sample preparation and chemical separation; nuclear chemical analysis in biological and medical research; the use of nuclear chemical analysis in the field of criminology; nuclear chemical analysis in environmental sciences, geology and mineral exploration; and radiation protection.

  2. Biorefinery, the bridge between agriculture and chemistry

    NARCIS (Netherlands)

    Sanders, J.P.M.; Scott, E.L.; Mooibroek, H.

    2005-01-01

    The depletion in fossil feedstocks, increasing oil prices and the ecological problems associated with CO2 emissions are forcing the development of alternative resources for energy (heat and electricity), transport fuels and chemicals: the replacement of fossil resources with CO2 neutral biomass. Whe

  3. Emerging Agricultural Biotechnologies for Sustainable Agriculture and Food Security.

    Science.gov (United States)

    Anderson, Jennifer A; Gipmans, Martijn; Hurst, Susan; Layton, Raymond; Nehra, Narender; Pickett, John; Shah, Dilip M; Souza, Thiago Lívio P O; Tripathi, Leena

    2016-01-20

    As global populations continue to increase, agricultural productivity will be challenged to keep pace without overtaxing important environmental resources. A dynamic and integrated approach will be required to solve global food insecurity and position agriculture on a trajectory toward sustainability. Genetically modified (GM) crops enhanced through modern biotechnology represent an important set of tools that can promote sustainable agriculture and improve food security. Several emerging biotechnology approaches were discussed in a recent symposium organized at the 13th IUPAC International Congress of Pesticide Chemistry meeting in San Francisco, CA, USA. This paper summarizes the innovative research and several of the new and emerging technologies within the field of agricultural biotechnology that were presented during the symposium. This discussion highlights how agricultural biotechnology fits within the context of sustainable agriculture and improved food security and can be used in support of further development and adoption of beneficial GM crops. PMID:26785813

  4. Social Chemistry

    OpenAIRE

    Lichtfouse, Eric; Schwarzbauer, Jan; Robert, Didier

    2012-01-01

    International audience This article is both an essay to propose social chemistry as a new scientific discipline, and a preface of the book Environmental Chemistry for a Sustainable World. Environmental chemistry is a fast emerging discipline aiming at the understanding the fate of pollutants in ecosystems and at designing novel processes that are safe for ecosystems. Past pollution should be cleaned, future pollution should be predicted and avoided (Lichtfouse et al., 2005a). Such advices ...

  5. Computational chemistry

    OpenAIRE

    Truhlar, Donald G.; McKoy, Vincent

    2000-01-01

    Computational chemistry has come of age. With significant strides in computer hardware and software over the last few decades, computational chemistry has achieved full partnership with theory and experiment as a tool for understanding and predicting the behavior of a broad range of chemical, physical, and biological phenomena. The Nobel Prize award to John Pople and Walter Kohn in 1998 highlighted the importance of these advances in computational chemistry. With massively parallel computers ...

  6. Bioinorganic Chemistry

    OpenAIRE

    Bertini, Ivano; Gray, Harry B.; Lippard, Stephen J.; Valentine, Joan Selverstone

    1994-01-01

    This book covers material that could be included in a one-quarter or one-semester course in bioinorganic chemistry for graduate students and advanced undergraduate students in chemistry or biochemistry. We believe that such a course should provide students with the background required to follow the research literature in the field. The topics were chosen to represent those areas of bioinorganic chemistry that are mature enough for textbook presentation. Although each chapter presents material...

  7. Technetium chemistry

    International Nuclear Information System (INIS)

    Technetium chemistry is a young and developing field. Despite the limited knowledge of its chemistry, technetium is the workhorse for nuclear medicine. Technetium is also a significant environmental concern because it is formed as a byproduct of nuclear weapons production and fission-power generators. Development of new technetium radio-pharmaceuticals and effective environmental control depends strongly upon knowledge of basic technetium chemistry. The authors performed research into the basic coordination and organometallic chemistry of technetium and used this knowledge to address nuclear medicine and environmental applications. This is the final report of a three-year Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL)

  8. Good chemistry

    OpenAIRE

    Petsko, Gregory A

    2004-01-01

    The subject matter in chemistry courses reflects almost nothing of the issues that chemists are interested in. It is important to formulate a set of topics - and a Medical College Admissions Test reflecting them - that would leave chemistry departments no choice but to change their teaching.

  9. Some advances in atmospheric chemistry

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In the recent decade, researches have been carried out by our group on some aspects of atmospheric chemistry through field observation, mechanism analysis and model simulation. Here some main results on greenhouse gas (CH4, N2O) emission from Chinese agricultural fields, aerosol, global carbon cycle and ozone variation in surface laver over China are briefly reported.

  10. Quantum chemistry

    CERN Document Server

    Lowe, John P

    1993-01-01

    Praised for its appealing writing style and clear pedagogy, Lowe's Quantum Chemistry is now available in its Second Edition as a text for senior undergraduate- and graduate-level chemistry students. The book assumes little mathematical or physical sophistication and emphasizes an understanding of the techniques and results of quantum chemistry, thus enabling students to comprehend much of the current chemical literature in which quantum chemical methods or concepts are used as tools. The book begins with a six-chapter introduction of standard one-dimensional systems, the hydrogen atom,

  11. Materials Chemistry

    CERN Document Server

    Fahlman, Bradley D

    2011-01-01

    The 2nd edition of Materials Chemistry builds on the strengths that were recognized by a 2008 Textbook Excellence Award from the Text and Academic Authors Association (TAA). Materials Chemistry addresses inorganic-, organic-, and nano-based materials from a structure vs. property treatment, providing a suitable breadth and depth coverage of the rapidly evolving materials field. The 2nd edition continues to offer innovative coverage and practical perspective throughout. After briefly defining materials chemistry and its history, seven chapters discuss solid-state chemistry, metals, semiconducting materials, organic "soft" materials, nanomaterials, and materials characterization. All chapters have been thoroughly updated and expanded with, for example, new sections on ‘soft lithographic’ patterning, ‘click chemistry’ polymerization, nanotoxicity, graphene, as well as many biomaterials applications. The polymer and ‘soft’ materials chapter represents the largest expansion for the 2nd edition. Each ch...

  12. Introductory Chemistry

    OpenAIRE

    Baron, Mark; Gonzalez-Rodriguez, Jose; Stevens, Gary; Gray, Nathan; Atherton, Thomas; Winn, Joss

    2010-01-01

    Teaching and Learning resources for the 1st Year Introductory Chemistry course (Forensic Science). 30 credits. These are Open Educational Resources (OER), made available for re-use under a Creative Commons license.

  13. Analytical chemistry

    International Nuclear Information System (INIS)

    This book is comprised of nineteen chapters, which describes introduction of analytical chemistry, experimental error and statistics, chemistry equilibrium and solubility, gravimetric analysis with mechanism of precipitation, range and calculation of the result, volume analysis on general principle, sedimentation method on types and titration curve, acid base balance, acid base titration curve, complex and firing reaction, introduction of chemical electro analysis, acid-base titration curve, electrode and potentiometry, electrolysis and conductometry, voltammetry and polarographic spectrophotometry, atomic spectrometry, solvent extraction, chromatograph and experiments.

  14. Cluster Chemistry

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    @@ Cansisting of eight scientists from the State Key Laboratory of Physical Chemistry of Solid Surfaces and Xiamen University, this creative research group is devoted to the research of cluster chemistry and creation of nanomaterials.After three-year hard work, the group scored a series of encouraging progresses in synthesis of clusters with special structures, including novel fullerenes, fullerene-like metal cluster compounds as well as other related nanomaterials, and their properties study.

  15. Green Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Collison, Melanie

    2011-05-15

    Green chemistry is the science of chemistry used in a way that will not use or create hazardous substances. Dr. Rui Resendes is working in this field at GreenCentre Canada, an offshoot of PARTEQ Innovations in Kingston, Ontario. GreenCentre's preliminary findings suggest their licensed product {sup S}witchable Solutions{sup ,} featuring 3 classes of solvents and a surfactant, may be useful in bitumen oil sands extraction.

  16. New trends and developments in radiation chemistry

    International Nuclear Information System (INIS)

    Radiation chemistry is a branch of chemistry that studies chemical transformations in materials exposed to high-energy radiations. It uses radiation as the initiator of chemical reactions. Practical applications of radiation chemistry today extend to many fields, including health care, food and agriculture, manufacturing, industrial pollution abatement, biotechnology and telecommunications. The important advantage of radiation chemistry lies in its ability to be used to produce, and study, almost any reactive atomic and molecular species playing a part in chemical reactions, synthesis, industrial processes, or in biological systems. The techniques are applicable to gaseous, liquid, solid, and heterogeneous systems. By combining different techniques of radiation chemistry with analytical chemistry, the reaction mechanism and kinetics of chemical reactions are studied. In November 1988 in Bologna, Italy, the IAEA convened an advisory group meeting to assess new trends and developments in radiation chemistry. The present publication includes most of the contributions presented at the meeting. Refs, figs and tabs

  17. Promoting sustainability through green chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Kirchhoff, Mary M. [American Chemical Society, 1155 Sixteenth Street, NW, Washington, DC 20036 (United States)

    2005-06-15

    Green chemistry is an important tool in achieving sustainability. The implementation of green chemistry, the design of chemical products and processes that reduce or eliminate the use and generation of hazardous substances, is essential if the expanding global population is to enjoy an increased standard of living without having a negative impact on the health of the planet. Cleaner technologies will allow the chemical enterprise to provide society with the goods and services on which it depends in an environmentally responsible manner. Green chemistry provides solutions to such global challenges as climate change, sustainable agriculture, energy, toxics in the environment, and the depletion of natural resources. A collaborative effort by industry, academia, and government is needed to promote the adoption of the green chemistry technologies necessary to achieve a sustainable society.

  18. Agricultural Geophysics

    Science.gov (United States)

    The four geophysical methods predominantly used for agricultural purposes are resistivity, electromagnetic induction, ground penetrating radar (GPR), and time domain reflectometry (TDR). Resistivity and electromagnetic induction methods are typically employed to map lateral variations of apparent so...

  19. Radiation Chemistry

    Science.gov (United States)

    Wojnárovits, L.

    Ionizing radiation causes chemical changes in the molecules of the interacting medium. The initial molecules change to new molecules, resulting in changes of the physical, chemical, and eventually biological properties of the material. For instance, water decomposes to its elements H2 and O2. In polymers, degradation and crosslinking take place. In biopolymers, e.g., DNS strand breaks and other alterations occur. Such changes are to be avoided in some cases (radiation protection), however, in other cases they are used for technological purposes (radiation processing). This chapter introduces radiation chemistry by discussing the sources of ionizing radiation (radionuclide sources, machine sources), absorption of radiation energy, techniques used in radiation chemistry research, and methods of absorbed energy (absorbed dose) measurements. Radiation chemistry of different classes of inorganic (water and aqueous solutions, inorganic solids, ionic liquids (ILs)) and organic substances (hydrocarbons, halogenated compounds, polymers, and biomolecules) is discussed in concise form together with theoretical and experimental backgrounds. An essential part of the chapter is the introduction of radiation processing technologies in the fields of polymer chemistry, food processing, and sterilization. The application of radiation chemistry to nuclear technology and to protection of environment (flue gas treatment, wastewater treatment) is also discussed.

  20. Quantum chemistry

    CERN Document Server

    Lowe, John P

    2006-01-01

    Lowe's new edition assumes little mathematical or physical sophistication and emphasizes an understanding of the techniques and results of quantum chemistry. It can serve as a primary text in quantum chemistry courses, and enables students and researchers to comprehend the current literature. This third edition has been thoroughly updated and includes numerous new exercises to facilitate self-study and solutions to selected exercises.* Assumes little initial mathematical or physical sophistication, developing insights and abilities in the context of actual problems* Provides thorough treatment

  1. Polymer Chemistry

    Science.gov (United States)

    Williams, Martha; Roberson, Luke; Caraccio, Anne

    2010-01-01

    This viewgraph presentation describes new technologies in polymer and material chemistry that benefits NASA programs and missions. The topics include: 1) What are Polymers?; 2) History of Polymer Chemistry; 3) Composites/Materials Development at KSC; 4) Why Wiring; 5) Next Generation Wiring Materials; 6) Wire System Materials and Integration; 7) Self-Healing Wire Repair; 8) Smart Wiring Summary; 9) Fire and Polymers; 10) Aerogel Technology; 11) Aerogel Composites; 12) Aerogels for Oil Remediation; 13) KSC's Solution; 14) Chemochromic Hydrogen Sensors; 15) STS-130 and 131 Operations; 16) HyperPigment; 17) Antimicrobial Materials; 18) Conductive Inks Formulations for Multiple Applications; and 19) Testing and Processing Equipment.

  2. Organic chemistry

    International Nuclear Information System (INIS)

    The activities of the mycotoxin research group are discussed. This includes the isolation and structure determination of mycotoxins, plant products, the biosyntheris of mycotoxins, the synthesis and characteristics of steroids, the synthesis and mechanistic aspects of heterocyclic chemistry and the functionality of steroids over long distances. Nmr spectra and mass spectroscopy are some of the techniques used

  3. Reinventing Chemistry

    OpenAIRE

    Whitesides, George McClelland

    2015-01-01

    Chemistry is in a period of change, from an era focused on molecules and reactions, to one in which manipulations of systems of molecules and reactions will be essential parts of controlling larger systems. This Essay traces paths from the past to possible futures.

  4. Chemistry Notes

    Science.gov (United States)

    School Science Review, 1972

    1972-01-01

    Short articles on the kinetics of the hydrogen peroxide-iodide ion reaction, simulation of fluidization catalysis, the use of Newman projection diagrams to represent steric relationships in organic chemistry, the use of synthetic substrates for proteolytic enzyme reactions, and two simple clock reactions"--hydrolysis of halogenoalkanes and…

  5. Agricultural sector

    International Nuclear Information System (INIS)

    The applications of nuclear technology in agriculture sector cover the use of the technology at every aspects of agricultural activity, starting from the seed to harvesting as well as the management of plantations itself. In this sector, a total of 55 entities comprising 17 public agencies and 38 private companies were selected for the study. Almost all, 91 % of them are located in Peninsular Malaysia; the rest operates in Sabah and Sarawak. The findings of the study in the public agencies and private companies are presented in the next sections. (author)

  6. Agricultural methanization

    International Nuclear Information System (INIS)

    After having briefly outlined the interest of the development of methanization of agricultural by-products in the context of struggle against climate change, and noticed that France is only now developing this sector as some other countries already did, this publication describes the methanization process also called anaerobic digestion, which produces a digestate and biogas. Advantages for the agriculture sector are outlined, as well as drawbacks and recommendations (required specific technical abilities, an attention to the use of energetic crops, an improved economic balance which still depends on public subsidies, competition in the field of waste processing). Actions undertaken by the ADEME are briefly evoked

  7. Fine chemistry

    International Nuclear Information System (INIS)

    The 1988 progress report of the Fine Chemistry laboratory (Polytechnic School, France) is presented. The research programs are centered on the renewal of the organic chemistry most important reactions and on the invention of new, highly efficient and highly selective reactions, by applying low cost reagents and solvents. An important research domain concerns the study and fabrication of new catalysts. They are obtained by means of the reactive sputtering of the metals and metal oxydes thin films. The Monte Carlo simulations of the long-range electrostatic interaction in a clay and the obtention of acrylamides from anhydrous or acrylic ester are summarized. Moreover, the results obtained in the field of catalysis are also given. The published papers and the congress communications are included

  8. Organometallic chemistry

    OpenAIRE

    Bashkin, James K.; M.L.H. Green; Dr. M. L. H. Green

    1982-01-01

    Transition metal organometallic chemistry is a rapidly expanding field, which has an important relationship to industrial problems of petrochemical catalysis. This thesis describes studies of fundamental organometallic reaction processes, such as C-H and C-C bond formation and cleavage, and investigations of the structure and bonding of organometallic compounds. A number of techniques were used to pursue these studies, including synthesis, X-ray crystallography, and semi-em...

  9. Disk Chemistry*

    OpenAIRE

    Thi Wing-Fai

    2015-01-01

    The chemical species in protoplanetary disks react with each other. The chemical species control part of the thermal balance in those disks. How the chemistry proceeds in the varied conditions encountered in disks relies on detailed microscopic understanding of the reactions through experiments or theoretical studies. This chapter strives to summarize and explain in simple terms the different types of chemical reactions that can lead to complex species. The first part of the chapter deals wit...

  10. Interstellar chemistry

    OpenAIRE

    Klemperer, William

    2006-01-01

    In the past half century, radioastronomy has changed our perception and understanding of the universe. In this issue of PNAS, the molecular chemistry directly observed within the galaxy is discussed. For the most part, the description of the molecular transformations requires specific kinetic schemes rather than chemical thermodynamics. Ionization of the very abundant molecular hydrogen and atomic helium followed by their secondary reactions is discussed. The rich variety of organic species o...

  11. Analytical chemistry

    International Nuclear Information System (INIS)

    The division for Analytical Chemistry continued to try and develope an accurate method for the separation of trace amounts from mixtures which, contain various other elements. Ion exchange chromatography is of special importance in this regard. New separation techniques were tried on certain trace amounts in South African standard rock materials and special ceramics. Methods were also tested for the separation of carrier-free radioisotopes from irradiated cyclotron discs

  12. Computational chemistry

    Science.gov (United States)

    Arnold, J. O.

    1987-01-01

    With the advent of supercomputers, modern computational chemistry algorithms and codes, a powerful tool was created to help fill NASA's continuing need for information on the properties of matter in hostile or unusual environments. Computational resources provided under the National Aerodynamics Simulator (NAS) program were a cornerstone for recent advancements in this field. Properties of gases, materials, and their interactions can be determined from solutions of the governing equations. In the case of gases, for example, radiative transition probabilites per particle, bond-dissociation energies, and rates of simple chemical reactions can be determined computationally as reliably as from experiment. The data are proving to be quite valuable in providing inputs to real-gas flow simulation codes used to compute aerothermodynamic loads on NASA's aeroassist orbital transfer vehicles and a host of problems related to the National Aerospace Plane Program. Although more approximate, similar solutions can be obtained for ensembles of atoms simulating small particles of materials with and without the presence of gases. Computational chemistry has application in studying catalysis, properties of polymers, all of interest to various NASA missions, including those previously mentioned. In addition to discussing these applications of computational chemistry within NASA, the governing equations and the need for supercomputers for their solution is outlined.

  13. Green chemistry

    International Nuclear Information System (INIS)

    A grand challenge facing government, industry, and academia in the relationship of our technological society to the environment is reinventing the use of materials. To address this challenge, collaboration from an interdisciplinary group of stakeholders will be necessary. Traditionally, the approach to risk management of materials and chemicals has been through inerventions intended to reduce exposure to materials that are hazardous to health and the environment. In 1990, the Pollution Prevention Act encouraged a new tact-elimination of hazards at the source. An emerging approach to this grand challenge seeks to embed the diverse set of environmental perspectives and interests in the everyday practice of the people most responsible for using and creating new materials--chemists. The approach, which has come to be known as Green Chemistry, intends to eliminate intrinsic hazard itself, rather than focusing on reducing risk by minimizing exposure. This chapter addresses the representation of downstream environmental stakeholder interests in the upstream everyday practice that is reinventing chemistry and its material inputs, products, and waste as described in the '12 Principles of Green Chemistry'

  14. Agricultural radioecology

    International Nuclear Information System (INIS)

    The problem of radioactive pollution of ecosystems is discussed. The total deposition of 90Sr and 137Cs after the nuclear experiments in 1945-1963 and the contamination rate of main foodstuffs are assessed. Data about radionuclide dynamics in soil, raw materials, forage, milk, milk products and wheat after the Chernobyl accident are presented for various regions of Bulgaria and are compared with the total fallout contamination. The trends in milk and forage contamination for some regions are discussed. Quantitative radiochemical methods for determination of 90Sr and 137Cs are discussed. Migration of 135Cs, 90Sr and 131J is followed in soil, forage, animal organism and human food chains respectively and ways of decontamination are discussed. Radiation effects on biogeocenoses are described. The problem of agriculture management under the conditions of durable soil contamination after nuclear accidents is considered. Recommendations for monitoring and protection of agricultural personnel are presented. 53 refs., 31 tabs., 93 figs

  15. Alternative Agriculture

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Will the popularization of bioenergy, a new source for powering China, trigger another agricultural revolution? Skyrocketing energy prices, especially the oil shock in the first half of 2005, are pushing China to seek more substitutes for gasoline. A number of cities are turning to ethanol-blended gas made from com. Starting this month, the sale of regular gasoline will be brought to an end in nine of China's

  16. Agricultural problems

    International Nuclear Information System (INIS)

    Although there were not reasons to deplore against major activity release from any of the 110 industrial reactors authorized to operate in US, the nuclear incident that occurred at the Three Mile Island Plant in 1979 urged the public conscience toward the necessity of readiness to cope with events of this type. The personnel of the Emergency Planning Office functioning in the frame of US Department of Agriculture has already participated in around 600 intervention drillings on a federal, local or state scale to plan, test or asses radiological emergency plans or to intervene locally. These exercises allowed acquiring a significant experience in elaborating emergency plans, planning the drillings, working out scenarios and evaluation of the potential impact of accidents from the agricultural point of view. We have also taken part in different international drillings among which the most recent are INEX 1 and RADEX 94. We have found on these occasions that the agricultural problems are essential preoccupations in most of the cases no matter if the context is international, national, local or of state level. The paper poses problems specifically related to milk, fruits and vegetables, soils, meat and meat products. Finally the paper discusses issues like drilling planning, alarm and notification, sampling strategy, access authorizations for farmers, removing of contamination wastes. A number of social, political and economical relating problems are also mentioned

  17. Types of agricultural landscape; 1 : 750 000

    International Nuclear Information System (INIS)

    The nature of agricultural landscape is expressed by the length of vegetation period, variants of winter season, need of additional moisture, potential water erosion and chemistry of soils. Each unit is characterised by 35 indicators. Applying mathematical and statistical methods, the agricultural landscape of Slovakia was divided into 8 types by the length of vegetation period, 8 subtypes by the winter period, 8 wards by the need of additional moisture, 4 sub-wards by the potential water erosion, and 22 variants by the soil sorption saturation and chemistry. (authors)

  18. Surface chemistry

    CERN Document Server

    Desai, KR

    2008-01-01

    The surface Chemistry of a material as a whole is crucially dependent upon the Nature and type of surfaces exposed on crystallites. It is therefore vitally important to independently Study different, well - defined surfaces through surface analytical techniques. In addition to composition and structure of surface, the subject also provides information on dynamic light scattering, micro emulsions, colloid Stability control and nanostructures. The present book endeavour to bring before the reader that the understanding and exploitation of Solid state phenomena depended largely on the ability to

  19. Hypercarbon chemistry

    International Nuclear Information System (INIS)

    This text points out the emerging significance of higher-valent carbon compounds. It describes the compounds of carbon with coordination numbers greater than four and explores the delocalized bonds of π aromatic molecules as a basis for rational description of orbitals; localized multicentered orbitals; the interactions of metallic ions with other atoms and molecules; the skeletal electron counts as a guide for synthesis; and the isolobal concept. Illustrated are the ways in which these subjects bring together structure and reactivity in the great diversity of novel carbon chemistry and its relationship to that of boron, lithium, hydrogen, the metals, and others

  20. Theoretical chemistry periodicities in chemistry and biology

    CERN Document Server

    Eyring, Henry

    1978-01-01

    Theoretical Chemistry: Periodicities in Chemistry and Biology, Volume 4 covers the aspects of theoretical chemistry. The book discusses the stably rotating patterns of reaction and diffusion; the chemistry of inorganic systems exhibiting nonmonotonic behavior; and population cycles. The text also describes the mathematical modeling of excitable media in neurobiology and chemistry; oscillating enzyme reactions; and oscillatory properties and excitability of the heart cell membrane. Selected topics from the theory of physico-chemical instabilities are also encompassed. Chemists, mechanical engin

  1. Combustion chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Brown, N.J. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  2. Cyclodextrin chemistry

    International Nuclear Information System (INIS)

    The chemistry of cyclodextrins was studied. This study included synthesising some cyclodextrin derivatives, preparing selected inclusion complexes with cyclodextrin and investigating the effects of gamma irradiation on cyclodextrins and certain linear oligosaccharides. This report presents a brief review of the structure and properties of cyclodextrins, the synthesis of cyclodextrin derivatives, their complexation and applications. This is followed by a description of the synthesis of some cyclodextrin derivatives and the preparation of inclusion complexes of cyclodextrin with some organic compounds. Finally, the effects of gamma irradiation on cyclodextrins, some of their derivatives and certain structurally related carbohydrates are discussed. The gamma irradiation studies were carried out for two reasons: to study the effects of gamma irradiation on cyclodextrins and their derivatives; and to investigate selectivity during the gamma irradiation of cyclodextrin derivatives

  3. Department of Agriculture

    Science.gov (United States)

    ... Safety Forestry Housing Assistance Laws and Regulations Organic Agriculture Outreach Plant Health Research and Science Rural and ... Agricultural Research Agricultural Statistics Economic Research Food and Agriculture Research OPEDA Scholarship Program MARKETING AND TRADE Exporting ...

  4. Science Update: Inorganic Chemistry

    Science.gov (United States)

    Rawls, Rebecca

    1978-01-01

    This first in a series of articles describing the state of the art of various branches of chemistry reviews inorganic chemistry, including bioinorganic, photochemistry, organometallic, and solid state chemistries. (SL)

  5. Why Teach Environmental Chemistry?

    Science.gov (United States)

    Gardner, Marjorie H.

    1974-01-01

    Discusses the importance of teaching environmental chemistry in secondary school science classes, and outlines five examples of environmental chemistry problems that focus on major concepts of chemistry and have critical implications for human survival and well-being. (JR)

  6. International Congress on Analytical Chemistry. Abstracts. V. 2

    International Nuclear Information System (INIS)

    The collection of materials of the international congress on analytical chemistry taken place in Moscow in June 1997 is presented. The main directs of investigations are elucidated in such regions of analytical chemistry as quantitative and qualitative chemical analysis, sample preparation, express test methods of environmental and biological materials, clinical analysis, analysis of food and agricultural products

  7. Integrating UNESCO ICT-Based Instructional Materials in Chemistry Lessons

    OpenAIRE

    CHARLIE P. NACARIO

    2014-01-01

    This study determined the effectiveness of the lessons in Chemistry integrating UNESCO ICT-based instructional material on the achievement of Chemistry students at Central Bicol State University of Agriculture. It aimed to identify lessons that may be developed integrating UNESCO ICT-based instructional materials, determine the effect of the developed lessons using the material on: conceptual understanding; science process skills; and attitude towards chemistry and gather insights...

  8. Public perception of chemistry

    OpenAIRE

    Stražar, Alenka

    2015-01-01

    The thesis deals with the perception of chemistry among the public, which reflects the stereotypes that people have about chemistry. It presents the existing classification of stereotypes about chemistry and their upgrade. An analysis of movies that reflect the existing perception of chemistry in the public is written. Literature on selected aspects of the application of chemistry in movies is collected and analyzed. A qualification of perception of chemistry in the movies is presented based ...

  9. Green polymer chemistry: biocatalysis and biomaterials

    Science.gov (United States)

    This overview briefly surveys the practice of green chemistry in polymer science. Eight related themes can be discerned from the current research activities: 1) biocatalysis, 2) bio-based building blocks and agricultural products, 3) degradable polymers, 4) recycling of polymer products and catalys...

  10. Agriculture ideas and modernization of agriculture

    OpenAIRE

    Li Kangmin

    2011-01-01

    The development of agriculture has its own history from primitive agriculture, traditional agriculture to modem agriculture. Is it a historical road we must follow?Human being had experienced a long history of living on collection and hunting for about 2,000 to 3,000 millenniums since human being appeared on earth. After we settled down, another 10 millenniums passed. Human being began to cultivate crops and raise animals. Thus, we entered the primitive agriculture stage. The primitive agricu...

  11. Science Update: Inorganic Chemistry.

    Science.gov (United States)

    Rawls, Rebecca

    1981-01-01

    Describes areas of inorganic chemistry which have changed dramatically in the past year or two, including photochemistry, electrochemistry, organometallic complexes, inorganic reaction theory, and solid state chemistry. (DS)

  12. Trace Chemistry

    Science.gov (United States)

    Radhakrishnan, Krishnan; Whitefield, Philip

    1999-01-01

    The goals of the trace chemistry group were to identify the processes relevant to aerosol and aerosol precursor formation occurring within aircraft gas turbine engines; that is, within the combustor, turbine, and nozzle. The topics of discussion focused on whether the chemistry of aerosol formation is homogeneous or heterogeneous; what species are important for aerosol and aerosol precursor formation; what modeling/theoretical activities to pursue; what experiments to carry out that both support modeling activities and elucidate fundamental processes; and the role of particulates in aerosol and aerosol precursor formation. The consensus of the group was that attention should be focused on SO2, SO3, and aerosols. Of immediate concern is the measurement of the concentration of the species SO3, SO2, H2SO4 OH, HO2, H2O2, O, NO, NO2, HONO, HNO3, CO, and CO2 and particulates in various engines, both those currently in use and those in development. The recommendation was that concentration measurements should be made at both the combustor exit and the engine exit. At each location the above species were classified into one of four categories of decreasing importance, Priority I through IV, as follows: Combustor exit: Priority I species - SO3:SO2 ratio, SO3, SO2, and particulates; Priority II species: OH and O; Priority III species - NO and NO2; and Priority IV species - CO and CO2. For the Engine exit: Priority I species - SO3:SO2 ratio, SO3, SO2,H2SO4, and particulates; Priority II species: OH,HO2, H2O2, and O; Priority III species - NO, NO2, HONO, and HNO3; and Priority IV species - CO and CO2. Table I summarizes the anticipated concentration range of each of these species. For particulate matter, the quantities of interest are the number density, size distribution, and composition. In order to provide data for validating multidimensional reacting flow models, it would be desirable to make 2-D, time-resolved measurements of the concentrations of the above species and

  13. Migration chemistry

    International Nuclear Information System (INIS)

    Migration chemistry, the influence of chemical -, biochemical - and physico-chemical reactions on the migration behaviour of pollutants in the environment, is an interplay between the actual natur of the pollutant and the characteristics of the environment, such as pH, redox conditions and organic matter content. The wide selection of possible pollutants in combination with varying geological media, as well as the operation of different chemical -, biochemical - and physico-chemical reactions compleactes the prediction of the influence of these processes on the mobility of pollutants. The report summarizes a wide range of potential pollutants in the terrestrial environment as well as a variety of chemical -, biochemical - and physico-chemical reactions, which can be expected to influence the migration behaviour, comprising diffusion, dispersion, convection, sorption/desorption, precipitation/dissolution, transformations/degradations, biochemical reactions and complex formation. The latter comprises the complexation of metal ions as well as non-polar organics to naturally occurring organic macromolecules. The influence of the single types of processes on the migration process is elucidated based on theoretical studies. The influence of chemical -, biochemical - and physico-chemical reactions on the migration behaviour is unambiguous, as the processes apparently control the transport of pollutants in the terrestrial environment. As the simple, conventional KD concept breaks down, it is suggested that the migration process should be described in terms of the alternative concepts chemical dispersion, average-elution-time and effective retention. (AB) (134 refs.)

  14. 农业院校提高生物化学课程教学效果的实践探索%Practice and Search to Improve Biological Chemistry Teaching Effect in Agricultural Colleges

    Institute of Scientific and Technical Information of China (English)

    孙新

    2015-01-01

    Biochemistry is an important basic course for agronomy,horticulture,plant protection,resources and environment protection in the agricultural colleges.This paper introduced the approaches for improving teaching efficiency from identifying teaching goal,improving effective teaching approach,adopting teaching network platform,combinating the practice classes and the theory knowledge and improving evaluation methods in order to improving biochemistry teaching efficiency and quality.%在农业院校生物学科的教学中,生物化学是一门重要的面向农学、植物保护、园艺、资源与环境保护等专业的基础课.从明晰教学目的、改善和采用有效的教学教法和教学技术平台、加强实践与理论教学的有机结合、完善考核评价等方面阐述了提高授课效率的途径,以期为提高生物化学的授课效果提供借鉴.

  15. Sustainable Agriculture: An Update

    OpenAIRE

    Tisdell, Clement A.

    2012-01-01

    Provides some background on concerns about the sustainability of agriculture, outlines and discusses views about what constitutes sustainable agriculture and contrasts the sustainability of modern industrialised agriculture with that of traditional agriculture. Then the question is considered (taking into account the available evidence) whether organic agriculture is more sustainable than non-organic agriculture. Barriers to switching from non-organic to organic agriculture are mentioned. The...

  16. Industrial Chemistry and School Chemistry: Making Chemistry Studies More Relevant

    Science.gov (United States)

    Hofstein, Avi; Kesner, Miri

    2006-01-01

    In this paper, we present the development and implementation over the period of more than 15 years of learning materials focusing on industrial chemistry as the main theme. The work was conducted in the Department of Science Teaching at the Weizmann Institute of Science, Israel. The project's general goal was to teach chemistry concepts in the…

  17. Agricultural Tariff Tracker

    Data.gov (United States)

    Foreign Agricultural Service, Department of Agriculture — The Agricultural Tariff Tool is a web application that queries tariff schedules and rate information resulting from Free Trade Agreements (FTAs). All...

  18. From Matter to Life:Chemistry?Chemistry!

    Institute of Scientific and Technical Information of China (English)

    Jean-Marie; LEHN

    2007-01-01

    1 Results Animate as well as inanimate matter,living organisms as well as materials,are formed of molecules and of the organized entities resulting from the interaction of molecules with each other.Chemistry provides the bridge between the molecules of inanimate matter and the highly complex molecular architectures and systems which make up living organisms. Synthetic chemistry has developed a very powerful set of methods for constructing ever more complex molecules.Supramolecular chemistry seeks to con...

  19. Green chemistry: A tool in Pharmaceutical Chemistry

    OpenAIRE

    Smita Talaviya; Falguni Majumdar

    2012-01-01

    Green chemistry expresses an area of research developing from scientific discoveries about pollution awareness and it utilizes a set of principles that reduces or eliminates the use or generation of hazardous substances in all steps of particular synthesis or process. Chemists and medicinal scientists can greatly reduce the risk to human health and the environment by following all the valuable principles of green chemistry. The most simple and direct way to apply green chemistry in pharmaceut...

  20. Chemistry Rocks: Redox Chemistry as a Geologic Tool.

    Science.gov (United States)

    Burns, Mary Sue

    2001-01-01

    Applies chemistry to earth science, uses rocks in chemistry laboratories, and teaches about transition metal chemistry, oxidation states, and oxidation-reduction reactions from firsthand experiences. (YDS)

  1. Crevice chemistry estimation from bulk water chemistry

    International Nuclear Information System (INIS)

    Since the first PWR plant in Japan started commercial operation in 1970, 22 plants are running in Japan as of the end of 1994. The main purpose of secondary water chemistry control is to minimize the corrosion possibility of the secondary system equipment, especially steam generators (SG). To achieve this objective, much effort has been concentrated on improving secondary water chemistry control. As a result of this effort, the recent secondary water chemistry in Japanese plants is well maintained in every stage of operation. However, to ensure and improve the reliability of SG, it is necessary to control crevice environments, which are located at tube/tube support plate intersections and under the sludge pile on the tube sheet. According to recent crevice monitoring examination results, the concentration behavior impurities in SG bulk water at the crevice is different for each species, and SG bulk water and crevice chemical compositions are not always equal. From these results, to control the crevice chemistry, improving bulk water chemistry control methods and a new type of molar ratio control index is needed. This paper introduces a brief summary of a recent crevice chemistry evaluation technique and bulk water chemistry control method, which is employed for crevice chemistry control, based on crevice monitoring examination results

  2. Green chemistry; La chimie verte

    Energy Technology Data Exchange (ETDEWEB)

    Colonna, P. [Institut National de la Recherche Agronomique, Dept. Caracterisation et Elaboration des Produits, 78 - Versailles (France)

    2006-07-01

    The depletion of world fossil fuel reserves and the involvement of greenhouse gases in the global warming has led to change the industrial and energy policies of most developed countries. The goal is now to reserve petroleum to the uses where it cannot be substituted, to implement renewable raw materials obtained from plants cultivation, and to consider the biodegradability of molecules and of manufactured objects by integrating the lifetime concept in their expected cycle of use. The green chemistry includes the design, development and elaboration of chemical products and processes with the aim of reducing or eliminating the use and generation of harmful compounds for the health and the environment, by adapting the present day operation modes of the chemical industry to the larger framework of the sustainable development. In addition to biofuels, this book reviews the applications of green chemistry in the different industrial processes in concern. Part 1 presents the diversity of the molecules coming from renewable carbon, in particular lignocellulose and the biotechnological processes. Part 2 is devoted to materials and treats of the overall available technological solutions. Part 3 focusses on functional molecules and chemical intermediates, in particular in sugar- and fats-chemistry. Part 4 treats of biofuels under the aspects of their production and use in today's technologies. The last part deals with the global approaches at the environmental and agricultural levels. (J.S.)

  3. Green chemistry: A tool in Pharmaceutical Chemistry

    Directory of Open Access Journals (Sweden)

    Smita Talaviya

    2012-07-01

    Full Text Available Green chemistry expresses an area of research developing from scientific discoveries about pollution awareness and it utilizes a set of principles that reduces or eliminates the use or generation of hazardous substances in all steps of particular synthesis or process. Chemists and medicinal scientists can greatly reduce the risk to human health and the environment by following all the valuable principles of green chemistry. The most simple and direct way to apply green chemistry in pharmaceuticals is to utilize eco-friendly, non-hazardous, reproducible and efficient solvents and catalysts in synthesis of drug molecules, drug intermediates and in researches involving synthetic chemistry. Microwave synthesis is also an important tool of green chemistry by being an energy efficient process.

  4. Handbook of Agricultural Geophysics

    Science.gov (United States)

    Geophysical methods continue to show great promise for use in agriculture. The term “agricultural geophysics” denotes a subdiscipline of geophysics that is focused only on agricultural applications. The Handbook of Agricultural Geophysics was compiled to include a comprehensive overview of the geoph...

  5. Sustainable agriculture - selected papers

    OpenAIRE

    Krasowicz, Stanisław; Wrzaszcz, Wioletta; Zegar, Jozef St.

    2007-01-01

    The concept of research on socially sustainable agriculture. Features of sustainable agriculture. Sustainability of private farms in the light of selected criteria. Subsistence agricultural holdings and the sustainable development of agriculture. Sustainable farms in the light of the FADN data. Description of organic holdings in Poland.

  6. Transforming Vietnamese Agriculture

    OpenAIRE

    World Bank Group

    2016-01-01

    Over the past quarter century, Vietnam’s agricultural sector has made enormous progress. Vietnam’s performance in terms of agricultural yields, output, and exports, however, has been more impressive than its gains in efficiency, farmer welfare, and product quality. Vietnamese agriculture now sits at a turning point. The agricultural sector now faces growing domestic competition - from cities, ...

  7. Organometallic Chemistry of Molybdenum.

    Science.gov (United States)

    Lucas, C. Robert; Walsh, Kelly A.

    1987-01-01

    Suggests ways to avoid some of the problems students have learning the principles of organometallic chemistry. Provides a description of an experiment used in a third-year college chemistry laboratory on molybdenum. (TW)

  8. CHINESE JOURNAL OF CHEMISTRY

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    @@Chinese Journal of Chemistry is an international journal published in English by the Chinese Chemical Society with its editorial office hosted by Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

  9. Environmental chemistry: Volume A

    Energy Technology Data Exchange (ETDEWEB)

    Yen, T.F.

    1999-08-01

    This is an extensive introduction to environmental chemistry for engineering and chemical professionals. The contents of Volume A include a brief review of basic chemistry prior to coverage of litho, atmo, hydro, pedo, and biospheres.

  10. Frontiers in Gold Chemistry

    OpenAIRE

    Mohamed, Ahmed A.

    2015-01-01

    Basic chemistry of gold tells us that it can bond to sulfur, phosphorous, nitrogen, and oxygen donor ligands. The Frontiers in Gold Chemistry Special Issue covers gold complexes bonded to the different donors and their fascinating applications. This issue covers both basic chemistry studies of gold complexes and their contemporary applications in medicine, materials chemistry, and optical sensors. There is a strong belief that aurophilicity plays a major role in the unending applications of g...

  11. Green Chemistry and Education.

    Science.gov (United States)

    Hjeresen, Dennis L.; Schutt, David L.; Boese, Janet M.

    2000-01-01

    Many students today are profoundly interested in the sustainability of their world. Introduces Green Chemistry and its principles with teaching materials. Green Chemistry is the use of chemistry for pollution prevention and the design of chemical products and processes that are environmentally benign. (ASK)

  12. Environmental Chemistry Activities.

    Science.gov (United States)

    Jackland, Thomas; And Others

    The authors of this curriculum supplement believe in a laboratory approach to chemistry and express the feeling that environmental chemistry provides the students an opportunity to apply theoretical chemistry to important practical problems. There are eighteen activities presented, each accompanied with behavioral objectives, one or more suggested…

  13. Facets of coordination chemistry

    CERN Document Server

    Agarwala, BV

    1993-01-01

    A concise account of coordination chemistry since its inception is given here together with some of the newer significant facets. This book covers a broad spectrum of various topics on Environment, Cyclic Voltammetry, Chromatography, Metal Complexes of biological interest, Alkoxides, NMR spectroscopy and others. These are useful to the scientific community engaged in the field of Inorganic Chemistry and Analytical Chemistry.

  14. Advanced radiation chemistry research: Current status

    International Nuclear Information System (INIS)

    Radiation chemistry is a branch of chemistry that studies chemical transformations in materials exposed to high-energy radiations. It is based on the use of ionizing radiation as the initiator or catalyst in chemical reactions. The most significant advantage of radiation chemistry lies in its ability to be used in the production and study of almost any reactive atomic and molecular species playing a part in chemical reaction, synthesis, industrial processes, or in biological systems. Over the the last few years a number of meetings have taken place, under the auspices of the IAEA, in order to evaluate recent developments in radiation chemistry as well as the trends indicated by the results obtained. Radiation chemists from different countries have participated at these meetings. The present publication, a companion to the previous publication - New Trends and Development in Radiation Chemistry, IAEA-TECDOC-527 (1989) - includes some of the important contributions presented at these meetings. It is hoped that it will provide a useful overview of current activities and of emerging trends in this field, thus promoting better understanding of potential contributions of radiation chemistry to other fields of knowledge as well as to practical applications in industry, medicine and agriculture. Refs, figs and tabs

  15. American Association for Clinical Chemistry

    Science.gov (United States)

    ... indispensable patient care tool. Learn more IN CLINICAL CHEMISTRY ddPCR Quantification of Lymphoma Mutations Researchers have developed ... Online Harmonization.net Commission on Accreditation in Clinical Chemistry American Board of Clinical Chemistry Clinical Chemistry Trainee ...

  16. Surface chemistry essentials

    CERN Document Server

    Birdi, K S

    2013-01-01

    Surface chemistry plays an important role in everyday life, as the basis for many phenomena as well as technological applications. Common examples range from soap bubbles, foam, and raindrops to cosmetics, paint, adhesives, and pharmaceuticals. Additional areas that rely on surface chemistry include modern nanotechnology, medical diagnostics, and drug delivery. There is extensive literature on this subject, but most chemistry books only devote one or two chapters to it. Surface Chemistry Essentials fills a need for a reference that brings together the fundamental aspects of surface chemistry w

  17. Fundamentals of reactor chemistry

    International Nuclear Information System (INIS)

    In the Nuclear Engineering School of JAERI, many courses are presented for the people working in and around the nuclear reactors. The curricula of the courses contain also the subject material of chemistry. With reference to the foreign curricula, a plan of educational subject material of chemistry in the Nuclear Engineering School of JAERI was considered, and the fundamental part of reactor chemistry was reviewed in this report. Since the students of the Nuclear Engineering School are not chemists, the knowledge necessary in and around the nuclear reactors was emphasized in order to familiarize the students with the reactor chemistry. The teaching experience of the fundamentals of reactor chemistry is also given. (author)

  18. Annual report 1985 Chemistry Department

    International Nuclear Information System (INIS)

    This report contains a brief survey of the main activities in the Chemistry Department. All particles and reports published and lectures given in 1985 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry, analytical- and organic chemistry, environmental chemistry, polymer chemistry, geochemistry and waste disposal, radical chemistry, positron annihilation, mineral processing, and general. (author)

  19. Annual report 1984 Chemistry Department

    International Nuclear Information System (INIS)

    This report contains a brief survey of the main activities in the Chemistry Department. All articles and reports published and lectures given in 1984 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry, analytical- and organic chemistry , environmental chemistry, polymer chemistry, geochemistry and waste disposal, radical chemistry, positron annihilation, mineral processing, and general. (author)

  20. Annual Report 1984. Chemistry Department

    OpenAIRE

    Funck, Jytte; Nielsen, Ole John

    1985-01-01

    This report contains a brief survey of the main activities in the Chemistry Department. All articles and reports published and lectures given in 1984 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry, analytical- and organic chemistry, environmental chemistry, polymer chemistry, geochemistry and waste disposal, radical chemistry, positron annihilation, mineral processing, and general.

  1. Philosophy of Chemistry or Philosophy with Chemistry?

    OpenAIRE

    Bernadette Bensaude-Vincent

    2014-01-01

    Chemistry deserves more philosophical attention not so much to do justice to a long-neglected science or to enhance its cultural prestige, but to undermine a number of taken-for-granted assumptions about scientific rationality and more importantly to diversify our metaphysical views of nature and reality. In brief, this paper does not make the case for a philosophy of chemistry. It rather urges philosophers of science to listen to chemists and discuss what they learn from them. Because over t...

  2. Knowledge, conservation and sustainable use of soil: agricultural chemistry aspects

    OpenAIRE

    Paola Adamo; Luisella Celi

    2009-01-01

    Soil is an environmental resource and plays ecological, social and economic functions which are fundamental for the life. To guarantee its availability to future generations, soil resource needs sustainable management. The CEC Thematic Strategy for Soil Protection identifies a series of soil degradation processes or threats, which must be identified and combated. These include erosion, decline in organic matter, local and diffuse contamination, sealing, compaction, decline in biodiversity, sa...

  3. Toxicological evaluation of azole fungicides in agriculture and food chemistry

    OpenAIRE

    Trösken, Eva-Regina

    2006-01-01

    Azole sind wichtige Chemikalien, die als Fungizide in der Landwirtschaft und der Medizin eingesetzt werden. Auch als Zytostatika in der Humanmedizin finden sie Anwendung. Die fungizide Wirkung beruht auf der Hemmung der Lanosterol-14α-Demethylase (CYP51), die die Demethylierung von Lanosterol zum „Follicular Fluid Meiosis Activating Steroid (FF-MAS)“ katalysiert. Für Pilze ist das später resultierende Ergosterol ein essentieller Bestandteil der Zellmembran. Exponierten Pilzen fehlt Ergos...

  4. Application of capillary electrophoresis in agricultural and soil chemistry research

    Science.gov (United States)

    As a modern analytical technique, capillary electrophoresis (CE) has become an attractive method for characterizing molecules wit high structural complexity and a wide range of molecular weights. CE can be used to analyze many natural chemical components such as acids, biogenic amines, peptides, pro...

  5. Innovations in urban agriculture

    NARCIS (Netherlands)

    Schans, van der J.W.; Renting, Henk; Veenhuizen, Van René

    2014-01-01

    This issuehighlights innovations in urban agriculture. Innovation and the various forms of innovations are of particular importance because urban agriculture is adapted to specific urban challenges and opportunities. Innovation is taking place continuously, exploring the multiple fundions of urban a

  6. Agricultural policy schemes

    DEFF Research Database (Denmark)

    Hansen, Henning Otte

    2016-01-01

    Agricultural support is a very important element in agricultural policy in many countries. Agricultural support is basically an instrument to meet the overall objectives of the agricultural policy – objectives set by society. There are a great number of instruments and ways of intervention in...... agricultural policy and they have different functions and impacts. Market price support and deficiency payments are two very important instruments in agricultural policy; however, they belong to two different support regimes or support systems. Market price support operates in the so-called high price system...... given by means of direct support, while market prices are left undistorted at, or close to, world market level. The two different support systems have very different implications for agricultural production, financing, markets, and other aspects; still, there is an income transfer to agriculture in both...

  7. Agricultural science policy

    OpenAIRE

    Alston, Julian M.; Pardey, Philip G.; Taylor, Michael J.

    2001-01-01

    Technological advances developed through R&D have supplied the world with not only more food, but better food. This report looks at issues raised by this changing environment for agricultural productivity, agricultural R&D, and natural resource management.

  8. Traditional Agriculture and Permaculture.

    Science.gov (United States)

    Pierce, Dick

    1997-01-01

    Discusses benefits of combining traditional agricultural techniques with the concepts of "permaculture," a framework for revitalizing traditions, culture, and spirituality. Describes school, college, and community projects that have assisted American Indian communities in revitalizing sustainable agricultural practices that incorporate cultural…

  9. Machine vision in agriculture

    OpenAIRE

    Gouws, J.

    1996-01-01

    This paper provides an overview of the use of machine vision in agriculture. Agriculture is practised in a more natural environment than most industrial undertakings, implying that agricultural automation requires robotic systems with well developed sensory abili­ties. For such systems, machine vision is an essential component. In this paper examples are used to show that the use of machine vision is already widespread in agriculture, and that there are many more potential applications for t...

  10. BOOK REVIEWS - Precision agriculture

    OpenAIRE

    Stanisław Samborski; Dariusz Gozdowski

    2007-01-01

    Precision agriculture (PA) is a term, which has recently become very popular in agronomy. In short this term means crop production based on site-specific crop management (SSCM). Precision agriculture is an integrated agricultural management system incorporating different science disciplines e.g. crop science, agricultural engineering and geostatistics. It also uses numerous tools i.e., geographic information system (GIS), Global Positioning System (GPS), remote sensing yield monitors. Because...

  11. Industralization of Animal Agriculture

    OpenAIRE

    Oya S. Erdogdu; David Hennessy

    2003-01-01

    The economic concerns and the technological developments increased control over nature and nurture in the animal agriculture. That changed the seasonality pattern of the supply side and lead to structural change in the animal agriculture together with the demand side factors. In this study we focused on the supply side factors and document the ‘industralization’ of the animal agricultural production.

  12. Cambodian Agriculture in Transition

    OpenAIRE

    World Bank Group

    2015-01-01

    This report seeks to understand the successes, challenges and opportunities of Cambodia’s agricultural transformation over the past decade to derive lessons and insights on how to maintain future agricultural growth, and particularly on the government’s role in facilitating it. It is prepared per the request of the Supreme National Economic Council and the Ministry of Agriculture Forestry ...

  13. Journal of Business Chemistry

    OpenAIRE

    2013-01-01

    The Journal of Business Chemistry examines issues associated with leadership and management for chemists and managers working in chemical research or industry. This journal is devoted to improving and developing the field of Business Chemistry. The Journal of Business Chemistry publishes peer-reviewed papers (including case studies) and essays. Areas for possible publication in include: leadership issues in the chemical and biochemical industry, such as teamwork, team building, mentoring, coa...

  14. Mathematical Thinking in Chemistry

    OpenAIRE

    José L. Villaveces; Guillermo Restrepo

    2012-01-01

    Mathematical chemistry is often thought to be a 20th-century subdiscipline of chemistry, but in this paper we discuss several early chemical ideas and some landmarks of chemistry as instances of the mathematical way of thinking; many of them before 1900. By the mathematical way of thinking, we follow Weyl's description of it in terms of functional thinking, i.e. setting up variables, symbolizing them, and seeking for functions relating them. The cases we discuss are Plato's triangles, Geoffro...

  15. Elementary physical chemistry

    CERN Document Server

    Linder, Bruno

    2010-01-01

    This book is designed for a one-semester course, for undergraduates, not necessarily chemistry majors, who need to know something about physical chemistry. The emphasis is not on mathematical rigor, but subtleties and conceptual difficulties are not hidden. It covers the essential topics in physical chemistry, including the state of matter, thermodynamics, chemical kinetics, phase and chemical equilibria, introduction to quantum theory, and molecular spectroscopy.

  16. Orbital interactions in chemistry

    CERN Document Server

    Albright, Thomas A; Whangbo, Myung-Hwan

    2013-01-01

    Explains the underlying structure that unites all disciplines in chemistry Now in its second edition, this book explores organic, organometallic, inorganic, solid state, and materials chemistry, demonstrating how common molecular orbital situations arise throughout the whole chemical spectrum. The authors explore the relationships that enable readers to grasp the theory that underlies and connects traditional fields of study within chemistry, thereby providing a conceptual framework with which to think about chemical structure and reactivity problems. Orbital Interactions

  17. A Consideration of Agriculture and Agricultural Science

    Institute of Scientific and Technical Information of China (English)

    Liu Gengling

    2006-01-01

    The article explores the importance of agricultulture in line with development of society. It uses examples of high productivity achieved in grain and cotton crops in lnner Mongolia and Xinjiang areas to show that the fundamental objective of agricultural science is to maximize crops through the most effective use of soil, fertilizer and water in gaining the greatest benefit from power of the sun. Agricultural science should take up relevant theories and methodologies from other sciences, such as biological science, earth science and economics. The use of information technology will have great benefits for agricultural science. It hopes the scientific communities of China can make a significant contribution to solving the problems facing our rural areas, farmers and agriculture itself.

  18. The Chemistry Institute

    OpenAIRE

    Fontecave, Marc

    2015-01-01

    Chemistry at the Collège de France has received particular attention over the last few years. After the departures of Profs Jean-Marie Lehn and Jacques Livage, new ambition for developing this discipline has led to the creation of several Chairs: Prof. Marc Fontecave’s Chair of Chemistry of Biological Processes in 2008, Prof. Clément Sanchez’ Chair of Chemistry of Hybrid Materials in 2011, and the Chair of Chemistry of Materials and Energy, which Prof. Jean-Marie Tarascon has held since 2014....

  19. Advances in quantum chemistry

    CERN Document Server

    Sabin, John R

    2013-01-01

    Advances in Quantum Chemistry presents surveys of current topics in this rapidly developing field that has emerged at the cross section of the historically established areas of mathematics, physics, chemistry, and biology. It features detailed reviews written by leading international researchers. This volume focuses on the theory of heavy ion physics in medicine.Advances in Quantum Chemistry presents surveys of current topics in this rapidly developing field that has emerged at the cross section of the historically established areas of mathematics, physics, chemistry, and biology. It features

  20. DOE fundamentals handbook: Chemistry

    International Nuclear Information System (INIS)

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. This volume contains the following modules: reactor water chemistry (effects of radiation on water chemistry, chemistry parameters), principles of water treatment (purpose; treatment processes [ion exchange]; dissolved gases, suspended solids, and pH control; water purity), and hazards of chemicals and gases (corrosives [acids, alkalies], toxic compounds, compressed gases, flammable/combustible liquids)

  1. Group theory and chemistry

    CERN Document Server

    Bishop, David M

    1993-01-01

    Group theoretical principles are an integral part of modern chemistry. Not only do they help account for a wide variety of chemical phenomena, they simplify quantum chemical calculations. Indeed, knowledge of their application to chemical problems is essential for students of chemistry. This complete, self-contained study, written for advanced undergraduate-level and graduate-level chemistry students, clearly and concisely introduces the subject of group theory and demonstrates its application to chemical problems.To assist chemistry students with the mathematics involved, Professor Bishop ha

  2. AGRICULTURAL POLICIES AND COMPETITION IN WORLD AGRICULTURE

    Directory of Open Access Journals (Sweden)

    Raluca Duma

    2011-04-01

    Full Text Available Agricultural policies have had a guiding role inagriculture development and implicitly in their marketing. Usually they belongto each state and government and are issued in accordance with their specificclimate, social-economic and cultural background which includes food andgastronomic traditions. Agricultural policies have in view home and foreignmarket demand, as well as the socio-demographic, political and military contextat a certain point in the socio-economic development

  3. Agricultural science and ethics

    DEFF Research Database (Denmark)

    Gjerris, Mickey; Vaarst, Mette

    2014-01-01

    , about 20 % of the world's coral reefs and 35 % of the mangrove areas were lost (Millennium Ecosystem Assessment 2005). In the following, the development of agricultural science will be sketched out and the role of ethics in agricultural science will be discussed. Then different views of nature that have...... shaped agriculture and the role of science in agriculture will be discussed by analyzing some of the presumptions behind the concept of ecosystem services and the way animals are viewed. Finally, the concepts of animal welfare and sustainability will be explored to show how they make vivid the connection...... between agricultural science and ethics....

  4. Chemistry and sustainable environment (abstract)

    International Nuclear Information System (INIS)

    Chemistry is one of the oldest branches of science; the human beings had ever come across. It has consistently contributed towards meeting the human needs from the dawn of civilization. However, its role has multiplied since the inception of industrial revolution. Although anthropogenic activities have made the human life comfortable and even luxurious yet their impacts on the physical, biological and socio-economic environments had been destructive. Numerous kinds of chemicals have engulfed us and our environment. Modern chemistry has leading role in sculpting the present as well as future of human lifestyle. It is serving the man and other biodiversity by providing countless products in every sphere of life. At the same time it is playing villain role in the destruction of environment at an alarming rate. Today the world is confronted with heinous environmental issues hitherto unknown to the living beings mostly triggered by chemicals. Thousands of chemicals are used in industrial products, agricultural chemicals, persistent organic pollutants, freezers, pharmaceuticals, chemical and radiological warfare, construction industry, synthetic materials, electrical goods, medical gadgets etc. Some natural sources of chemicals are acid rains, volcanic eruptions, eutrophication and photochemical smog. The fact of matter is that chemicals are being consistently added into atmosphere, biosphere and lithosphere. For the sustainable environment it is imperative that the chemicals must not be added into human environment beyond its carrying capacity. It is responsibility of chemists to introduce environmentally benign and biodegradable chemicals. All types of chemistry need to be green and environment friendly. The scientists and engineers should develop chemicals and technologies which do not harm the living creatures during any stage of their life-cycle. (author)

  5. Carbohydrate Green Chemistry: C-Glycoside Ketones as Potential Chiral Building Blocks

    Science.gov (United States)

    "Green chemistry" methods to produce new chemicals from renewable agricultural feedstocks will decrease our dependence on imported petroleum feedstocks and lower the environmental impact of consumer products. Our current research focuses on development of new carbohydrate-based derivatives, "locked...

  6. Open access and medicinal chemistry

    OpenAIRE

    Swain Chris

    2007-01-01

    Abstract Chemistry Central is a new open access website for chemists publishing peer-reviewed research in chemistry from a range of open access journals. A new addition, Chemistry Central Journal, will cover all of chemistry and will be broken down into discipline-specific sections, and Im delighted that Medicinal Chemistry will be a key discipline in this new journal.

  7. Annual report 1988 Chemistry Department

    International Nuclear Information System (INIS)

    This report contains a brief survey of the main activities in the Chemistry Department. The names and abstracts of all articles and reports published and lectures given in 1988 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry, analytical- and organic chemistry, environmental chemistry, polymer chemistry, chemical reactivity, mineral processing, and general. (author)

  8. Annual report 1986 chemistry department

    International Nuclear Information System (INIS)

    This report contains a brief survey of the main activities in the Chemistry Department. All articles and reports published and lectures given in 1986 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry, analytical- and organic chemistry, environmental chemistry, polymer chemistry, radical chemistral, mineral processing, and general. (author)

  9. Annual report 1989 Chemistry Department

    International Nuclear Information System (INIS)

    This report contains a brief survey of the main activities in the Chemistry Department. The names and abstracts of all articles and reports published and lectures given in 1989 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry, analytical- and organic chemistry, environmental chemistry, polymer chemistry, chemical reactivity, mineral processing, and general. (author)

  10. The Breath of Chemistry

    DEFF Research Database (Denmark)

    Josephsen, Jens

    The present preliminary text is a short thematic presentation in biological inorganic chemistry meant to illustrate general and inorganic (especially coordination) chemistry in biochemistry. The emphasis is on molecular models to explain features of the complicated mechanisms essential to breathing...

  11. Movies in Chemistry Education

    Science.gov (United States)

    Pekdag, Bulent; Le Marechal, Jean-Francois

    2010-01-01

    This article reviews numerous studies on chemistry movies. Movies, or moving pictures, are important elements of multimedia and signify a privileged or motivating means of presenting knowledge. Studies on chemistry movies show that the first movie productions in this field were devoted to university lectures or documentaries. Shorter movies were…

  12. Physical Chemistry of Molecular

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    @@ Established in 2009, the group consists of six researchers and more than 70 research assistants and graduate students from the CAS Key Laboratory of Molecular Nanostructures and Nanotechnologies at the CAS Institute of Chemistry.Its research focuses on the physical chemistry involved in molecular assembly, molecular nanostructures, functional nanomaterials and conceptual nano-devices.

  13. Chemistry of americium

    Energy Technology Data Exchange (ETDEWEB)

    Schulz, W.W.

    1976-01-01

    Essential features of the descriptive chemistry of americium are reviewed. Chapter titles are: discovery, atomic and nuclear properties, collateral reading, production and uses, chemistry in aqueous solution, metal, alloys, and compounds, and, recovery, separation, purification. Author and subject indexes are included. (JCB)

  14. Exercises in Computational Chemistry

    DEFF Research Database (Denmark)

    Spanget-Larsen, Jens

    2016-01-01

    A selection of HyperChem© PC-exercises in computational chemistry. Answers to most questions are appended (Roskilde University 2014-16).......A selection of HyperChem© PC-exercises in computational chemistry. Answers to most questions are appended (Roskilde University 2014-16)....

  15. Titanocene sulfide chemistry

    Czech Academy of Sciences Publication Activity Database

    Horáček, Michal

    2016-01-01

    Roč. 314, MAY 2016 (2016), s. 83-102. ISSN 0010-8545 R&D Projects: GA ČR(CZ) GAP207/12/2368 Institutional support: RVO:61388955 Keywords : titanocene sulfide chemistry * photolysis * titanocene hydrosulfides Ti-(SH)n Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 12.239, year: 2014

  16. Chemistry in Microfluidic Channels

    Science.gov (United States)

    Chia, Matthew C.; Sweeney, Christina M.; Odom, Teri W.

    2011-01-01

    General chemistry introduces principles such as acid-base chemistry, mixing, and precipitation that are usually demonstrated in bulk solutions. In this laboratory experiment, we describe how chemical reactions can be performed in a microfluidic channel to show advanced concepts such as laminar fluid flow and controlled precipitation. Three sets of…

  17. Mathematical Thinking in Chemistry

    Directory of Open Access Journals (Sweden)

    José L. Villaveces

    2012-05-01

    Full Text Available Mathematical chemistry is often thought to be a 20th-century subdiscipline of chemistry, but in this paper we discuss several early chemical ideas and some landmarks of chemistry as instances of the mathematical way of thinking; many of them before 1900. By the mathematical way of thinking, we follow Weyl's description of it in terms of functional thinking, i.e. setting up variables, symbolizing them, and seeking for functions relating them. The cases we discuss are Plato's triangles, Geoffroy's affinity table, Lavoisier's classification of substances and their relationships, Mendeleev's periodic table, Cayley's enumeration of alkanes, Sylvester's association of algebra and chemistry, and Wiener's relationship between molecular structure and boiling points. These examples show that mathematical chemistry has much more than a century of history.

  18. Korean Kimchi Chemistry: A Multicultural Chemistry Connection

    Science.gov (United States)

    Murfin, Brian

    2009-01-01

    Connecting science with different cultures is one way to interest students in science, to relate science to their lives, and at the same time to broaden their horizons in a variety of ways. In the lesson described here, students make kimchi, a delicious and popular Korean dish that can be used to explore many important chemistry concepts,…

  19. Reorganization of Agricultural Extension toward Green Agriculture

    Directory of Open Access Journals (Sweden)

    Mohammad S. Allahyari

    2009-01-01

    Full Text Available Problem statement: Considering unsustainable agricultural conditions of Iran and organizational recession and inability of current extension organization to achieve sustainability, it seems that extension systems require a new organizational structure to achieve sustainability objectives. The purpose of the present study was to identify the most appropriate characteristics for extension organization toward green agriculture in Iran context. Approach: To fulfill this objective, a sample of 120 respondents was selected through simple random sampling technique. A survey study was applied as a methodology of research. A mailed questionnaire was used to collect the data. The response rate of questionnaire was 65.83% (N = 79. Appropriate descriptive statistics such as mean scores, standard deviations and variation ratio were used. Results: Extension experts believed that among important organizational characteristics of extension system for supporting green agriculture collaboration among research, extension, education organizations, farmers' associations, NGOs, rural credit agencies, transportation companies, considering local groups and learning organization had very high importance for supporting green agriculture. According to factor analysis, the implications for extension organization were categorized into two groups consisting: (1 Holistic organizations (2 Participatory organizations that those factors explained 67.54% of the total variance of the research variables. Conclusion: Identifying suitable extension mechanisms had important role for developing extension system. Therefore, identifying extension organizational characteristics for supporting green agriculture of Iran is one of the major approaches needs to be carefully thought and accurately implemented for the extension system development.

  20. MODERNIZATION OF AGRICULTURE VS SUSTAINABLE AGRICULTURE

    Directory of Open Access Journals (Sweden)

    Dariusz KUSZ

    2014-04-01

    Full Text Available The paper shows the correlation between the need to modernise agriculture and sustainable development. Modernisation of agriculture aiming only at increasing the efficiency of production, if implemented in accordance with the principles of sustainable development, enabled reduction in the negative external effects. Modernisation of agriculture is supposed to ensure productivity growth without imposing any threats to the natural environment and the well-being of animals, reduced impoverishment in rural areas as well as to ensure food security, growth in the profitability of farms, improvement to the efficiency of use of natural resources. Therefore, in the near future, the agriculture – environment relation will be subject to change taking into account, on the one hand, concern about the natural environment, and, on the other, pressure on increasing the efficiency of production. The above challenges will be addressed by the need to implement efficient and, at the same time, environmentally-friendly production technologies and relevant legal instruments which oblige agricultural producers to protect the natural environment.

  1. Effects of mountain agriculture on nutrient cycling at upstream watersheds

    Science.gov (United States)

    Lin, T.-C.; Shaner, P. L.; Wang, L.-J.; Shih, Y.-T.; Wang, C.-P.; Huang, G.-H.; Huang, J.-C.

    2015-05-01

    The expansion of agriculture to rugged mountains can exacerbate negative impacts of agriculture activities on ecosystem function. In this study, we monitored streamwater chemistry of four watersheds with varying proportions of agricultural lands (0.4, 3, 17, 22%) and rainfall chemistry of two of the four watersheds at Feitsui Reservoir Watershed in northern Taiwan to examine the effects of agriculture on watershed nutrient cycling. We found that the greater the proportions of agricultural lands, the higher the ion concentrations, which is evident for fertilizer-associated ions (NO3-, K+) but not for ions that are rich in soils (SO42-, Ca2+, Mg2+), suggesting that agriculture enriched fertilizer-associated nutrients in streamwater. The watershed with the highest proportion of agricultural lands had higher concentrations of ions in rainfall and lower nutrient retention capacity (i.e. higher output-input ratio of ions) compared to the relatively pristine watershed, suggesting that agriculture can influence atmospheric deposition of nutrients and a system's ability to retain nutrients. Furthermore, we found that a forested watershed downstream of agricultural activities can dilute the concentrations of fertilizer-associated ions (NO3-, K+) in streamwater by more than 70%, indicating that specific landscape configurations help mitigate nutrient enrichment to aquatic systems. We estimated that agricultural lands at our study site contributed approximately 400 kg ha-1 yr-1 of NO3-N and 260 kg ha-1 yr-1 of PO4-P output via streamwater, an order of magnitude greater than previously reported around the globe and can only be matched by areas under intense fertilizer use. Furthermore, we re-constructed watershed nutrient fluxes to show that excessive leaching of N and P, and additional loss of N to the atmosphere via volatilization and denitrification, can occur under intense fertilizer use. In summary, this study demonstrated the pervasive impacts of agriculture activities

  2. Third Chemistry Conference on Recent Trends in Chemistry

    International Nuclear Information System (INIS)

    The third chemistry conference 2011 on recent trends in chemistry was held from October 17-19, 2001 at Islamabad, Pakistan. More than 65 papers and oral presentation. The scope of the conference was wide open and provides and opportunity for participation of broad spectrum of chemists. This forum provided a platform for the dissemination of the latest research followed by discussion pertaining to new trends in chemistry. This con fence covered different aspects of subjects including analytical chemistry, environmental chemistry, polymer chemistry, industrial chemistry, biochemistry and nano chemistry etc. (A.B.)

  3. System approach to chemistry course

    OpenAIRE

    Lorina E. Kruglova; Valentina G. Derendyaeva

    2010-01-01

    The article considers the raise of chemistry profile for engineers and constructors training, discloses the system approach to chemistry course and singles out the most important modules from the course of general chemistry for construction industry.

  4. Machine vision in agriculture

    Directory of Open Access Journals (Sweden)

    J. Gouws

    1996-07-01

    Full Text Available This paper provides an overview of the use of machine vision in agriculture. Agriculture is practised in a more natural environment than most industrial undertakings, implying that agricultural automation requires robotic systems with well developed sensory abili­ties. For such systems, machine vision is an essential component. In this paper examples are used to show that the use of machine vision is already widespread in agriculture, and that there are many more potential applications for this technology. It is also indicated that machine vision in agriculture does not only hold potential financial advantages, but that it can also contribute to improved quality of life for agricultural workers, and even for farm animals.

  5. Agricultural Occupations Programs Planning Guides

    Science.gov (United States)

    Stitt, Thomas R.; And Others

    1977-01-01

    A set of program planning guides that include seven areas (1) Agricultural Production, (2) Agricultural Supplies and Services, (3) Agricultural Mechanics, (4) Agricultural Products, (5) Ornamental Horticulture, (6) Agricultural Resources, and (7) Forestry, were developed and introduced to high school applied biological and agricultural occupations…

  6. Challenges and opportunities in supporting sustainable agriculture and food security

    Science.gov (United States)

    The 2014 IUPAC International Congress of Pesticide Chemistry (San Francisco, August, 2014) included a symposium on “Challenges Associated with Global Adoption of Agricultural Biotechnology” to review current obstacles in promoting GM crops. Challenges identified by symposium presenters included i) ...

  7. Urban Agriculture : Sustainability Multiplier

    OpenAIRE

    Årevall, Agnieszka Janicka

    2013-01-01

    For some years now, the phenomena of urban agriculture have been present in the public discourse on cities and sustainability. It is often assumed that urban agriculture has the potential to contribute to an increased sustainability of the cities. However, many practical and theoretical obstacles might have to be overcome in order to realize this potential. One ambition of this thesis is to analyse urban agriculture as a “sustainability multiplier” – that is, as a practice that can positively...

  8. Agriculture and riparian areas

    OpenAIRE

    Krueger, William C.

    1994-01-01

    Agriculture has historically been based in the subirrigated riparian ecosystems. Often the engineering and agricultural practices have altered the systems and many of the associated ecological processes. In the Western United States, the most common agricultural practices affecting riparian systems has been livestock grazing. Effects have been both positive and negative. Lack of management has deteriorated many of these systems. Current research has shown what types of management have been su...

  9. Biosurfactants in agriculture

    OpenAIRE

    Sachdev, Dhara P.; Cameotra, Swaranjit S.

    2013-01-01

    Agricultural productivity to meet growing demands of human population is a matter of great concern for all countries. Use of green compounds to achieve the sustainable agriculture is the present necessity. This review highlights the enormous use of harsh surfactants in agricultural soil and agrochemical industries. Biosurfactants which are reported to be produced by bacteria, yeasts, and fungi can serve as green surfactants. Biosurfactants are considered to be less toxic and eco-friendly and ...

  10. Vulnerability in Agriculture

    OpenAIRE

    Znaor, Darko

    2009-01-01

    The impact from climate change on agriculture is expected to be significant because of the vulnerability of agriculture to climate conditions in general. Precipitation, temperature, weather extremes and evaporation rates all impact production. Agriculture is important to the economy of Croatia due to its overall value and its impact on food security, vulnerable populations, and the employment it generates. In 2001, 92% of Croatia was classified as rural and 48% of the Croatian population live...

  11. Risk management in agriculture

    OpenAIRE

    Bharat Ramaswami; Shamika Ravi; S.D. Chopra

    2003-01-01

    This monograph was written to be part of the series of studies commissioned by the Ministry of Agriculture under the rubric of "State of Indian Farmer - A Millennium Study". On the basis of existing literature, this study documents the status of our knowledge on risks of agriculture and their management. Chapter 2 discusses the evidence on the nature, type and magnitude of agricultural risks. Chapter 3 discusses farmer strategies to combat risk. In addition to the mechanisms at the level of t...

  12. Measuring agricultural policy bias

    DEFF Research Database (Denmark)

    Jensen, Henning Tarp; Robinson, Sherman; Tarp, Finn

    2010-01-01

    that the agricultural price incentive bias generally perceived to exist during the 1980s was largely eliminated during the 1990s. Results also demonstrate that general equilibrium effects and country-specific characteristics are crucial for determining the sign and magnitude of agricultural bias. Our comprehensive...... protection measure is therefore uniquely suited to capture the full impact of trade policies on relative agricultural price incentives....

  13. Agricultural Development Bank Reform

    OpenAIRE

    Seibel, Hans Dieter

    2001-01-01

    Agricultural development banks (AgDBs), which are not viable, should either be closed, or transformed into self-reliant, sustainable financial intermediaries. Experience shows that reform is possible. Among the prominent cases are Bank Rakyat Indonesia (BRI) and Bank for Agriculture and Agricultural Cooperatives (BAAC, Thailand) as well as ADB/Nepal, which has been transforming its small farmer credit program into financially self-reliant local financial intermediaries owned and managed by th...

  14. Sustainable Agricultural Marketing Initiatives

    OpenAIRE

    Hakan Adanacıoğlu

    2015-01-01

    Sustainable marketing is a holistic approach that puts equal emphasis on environmental, social equity, and economic concerns in the development of marketing strategies. The purpose of the study is to examine and discuss the sustainable agricultural marketing initiatives practiced throughout the World and Turkey, and to put forth suggestions to further improve the performance of agricultural marketing initiatives in Turkey. Some of the sustainable agricultural marketing initiatives practiced a...

  15. Urban Agricultural Event

    OpenAIRE

    Camm, Kevin

    2012-01-01

    Many authors and researchers agree that our youth will benefit from learning about agriculture. “Agricultural literacy is an essential factor for continuing success of the nation. It is important to reach the population when it is most vulnerable and susceptible to learning; this consists of the children of today’s world” (Schmidbauer, Pastor, & Elliot, 2004; p. 2). Ryan and Lockaby suggest that if the population possesses an understanding of agriculture, they are more likely to benefit socie...

  16. Annual report 1987 Chemistry Department

    International Nuclear Information System (INIS)

    This report contains a brief survey of the main activities in the Chemistry Department. The names and abstracts of all articles and reports published and lectures given in 1987 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry, analytical- and organic chemistry, environmental chemistry, polymer chemistry, radical chemistry, mineral processing, and general. 13 ills., (author)

  17. Annual report 1982 chemistry department

    International Nuclear Information System (INIS)

    The work going on in the Risoe National Laboratory, Chemistry Department is briefly surveyed by a presentation of all articles and reports published in 1982. The facilities and equipment are barely mentioned. The papers are divided into eight activities: 1. neutron activation analysis 2. analytical- and organic chemistry 3. environmental chemistry 4. polymer chemistry 5. geochemistry 6. radical chemistry 7. poitron annihilation 8. uranium process chemistry. (author)

  18. Biodiesel from Seeds: An Experiment for Organic Chemistry

    Science.gov (United States)

    Goldstein, Steven W.

    2014-01-01

    Plants can store the chemical energy required by their developing offspring in the form of triglycerides. These lipids can be isolated from seeds and then converted into biodiesel through a transesterification reaction. This second-year undergraduate organic chemistry laboratory experiment exemplifies the conversion of an agricultural energy…

  19. Agriculture - reconciling ancient tensions

    Directory of Open Access Journals (Sweden)

    David Atkinson

    2002-09-01

    Full Text Available Decision-making in agriculture has tended to be driven by factors other than environmental concerns. This may be changing, and perhaps the emphases of the two creation accounts in Genesis (responsible management or 'dominion', and active care may become more important. The paper examines a number of current developments in agriculture (synthetic fertilizers and pesticides, genetic manipulation, and organic versus industrial methodologies and discusses the issues they raise for agricultural productivity and the human communities dependent on farming. The questions raised are complex; we are faced with establishing a new paradigm for agricultural practice.

  20. Malawi - Conservation Agriculture

    Data.gov (United States)

    Millenium Challenge Corporation — The randomized control trial impact evaluation tests different strategies for communicating information about agricultural technologies to smallholder maize farmers...

  1. Regionalisation of Croatian Agriculture

    Directory of Open Access Journals (Sweden)

    Ferdo Bašić

    2007-03-01

    Full Text Available After becoming self-standing state one of new needs of Croatia important for agricultural profession, farmers, policy makers and public needs was regionalization of agriculture. It is the analyse of state of agroecological conditions in agrosphere and based on results identification and territorial separation of agricultural regions as parts of agrosphere with similar conditions for plant and animal growing and similar farming systems. On this track within a special project we fi nished an inventory of agrosphere, result of which is Regionalisation of Croatian Agriculture presented in this paper. Following wise message of old Chinese proverb cited above, the starting approach is the MFCAL concept (Multifunctional Character of Agriculture and Land, which means that apart from very important and primary economic, agriculture and agricultural land (soil in human life play other roles (functions of similar importance; environmental, social, cultural and spatial, as well as the role of shaping the cultural landscape as a factor of rural development. As well, we respect the point of view prevailing in EU that all natural resources used in agriculture but at the fi rst place soil as a major one, need sustainable use and efficient protection. Using the data on Land resource potential based primarily on data of General Soil Map of Croatia (GSM in a scale of 1:50 000 and results of our research in the period 2000 – 2003, the agrosphere of Croatia is divided in three agricultural regions; Pannonian with four, Mountain with two and Adriatic with three subregions.

  2. Moderator Chemistry Program

    International Nuclear Information System (INIS)

    Over the past fifteen months, the Systems Chemistry Group of the Reactor Engineering Department has undertaken a comprehensive study of the Department's moderator chemistry program at Savannah River Site (SRS). An internal review was developed to formalize and document this program. Objectives were as outlined in a mission statement and action plan. In addition to the mission statement and action plan, nine separate task reports have been issued during the course of this study. Each of these task reports is included in this document as a chapter. This document is an organized compilation of the individual reports issued by the Systems Chemistry Group in assessment of SRS moderator chemistry to determine if there were significant gaps in the program as ft existed in October, 1989. While these reviews found no significant gaps in that mode of operation, or any items that adversely affected safety, items were identified that could be improved. Many of the items have already been dear with or are in the process of completion under this Moderator Chemistry Program and other Reactor Restart programs. A complete list of the items of improvement found under this assessment is found in Chapter 9, along with a proposed time table for correcting remaining items that can be improved for the chemistry program of SRS reactors. An additional external review of the moderator chemistry processes, recommendations, and responses to/from the Reactor Corrosion Mitigation Committee is included as Appendix to this compilation

  3. Moderator Chemistry Program

    Energy Technology Data Exchange (ETDEWEB)

    Dewitt, L.V.; Gibbs, A.; Lambert, D.P.; Bohrer, S.R.; Fanning, R.L.; Houston, M.W.; Stinson, S.L.; Deible, R.W.; Abdel-Khalik, S.I.

    1990-11-01

    Over the past fifteen months, the Systems Chemistry Group of the Reactor Engineering Department has undertaken a comprehensive study of the Department's moderator chemistry program at Savannah River Site (SRS). An internal review was developed to formalize and document this program. Objectives were as outlined in a mission statement and action plan. In addition to the mission statement and action plan, nine separate task reports have been issued during the course of this study. Each of these task reports is included in this document as a chapter. This document is an organized compilation of the individual reports issued by the Systems Chemistry Group in assessment of SRS moderator chemistry to determine if there were significant gaps in the program as ft existed in October, 1989. While these reviews found no significant gaps in that mode of operation, or any items that adversely affected safety, items were identified that could be improved. Many of the items have already been dear with or are in the process of completion under this Moderator Chemistry Program and other Reactor Restart programs. A complete list of the items of improvement found under this assessment is found in Chapter 9, along with a proposed time table for correcting remaining items that can be improved for the chemistry program of SRS reactors. An additional external review of the moderator chemistry processes, recommendations, and responses to/from the Reactor Corrosion Mitigation Committee is included as Appendix to this compilation.

  4. Moderator Chemistry Program

    Energy Technology Data Exchange (ETDEWEB)

    Dewitt, L.V.; Gibbs, A.; Lambert, D.P.; Bohrer, S.R.; Fanning, R.L.; Houston, M.W.; Stinson, S.L.; Deible, R.W.; Abdel-Khalik, S.I.

    1990-11-01

    Over the past fifteen months, the Systems Chemistry Group of the Reactor Engineering Department has undertaken a comprehensive study of the Department`s moderator chemistry program at Savannah River Site (SRS). An internal review was developed to formalize and document this program. Objectives were as outlined in a mission statement and action plan. In addition to the mission statement and action plan, nine separate task reports have been issued during the course of this study. Each of these task reports is included in this document as a chapter. This document is an organized compilation of the individual reports issued by the Systems Chemistry Group in assessment of SRS moderator chemistry to determine if there were significant gaps in the program as ft existed in October, 1989. While these reviews found no significant gaps in that mode of operation, or any items that adversely affected safety, items were identified that could be improved. Many of the items have already been dear with or are in the process of completion under this Moderator Chemistry Program and other Reactor Restart programs. A complete list of the items of improvement found under this assessment is found in Chapter 9, along with a proposed time table for correcting remaining items that can be improved for the chemistry program of SRS reactors. An additional external review of the moderator chemistry processes, recommendations, and responses to/from the Reactor Corrosion Mitigation Committee is included as Appendix to this compilation.

  5. Annual Report 1984. Chemistry Department

    DEFF Research Database (Denmark)

    Funck, Jytte; Nielsen, Ole John

    This report contains a brief survey of the main activities in the Chemistry Department. All articles and reports published and lectures given in 1984 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry, an......, analytical- and organic chemistry, environmental chemistry, polymer chemistry, geochemistry and waste disposal, radical chemistry, positron annihilation, mineral processing, and general.......This report contains a brief survey of the main activities in the Chemistry Department. All articles and reports published and lectures given in 1984 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry...

  6. Chemistry in water reactors

    International Nuclear Information System (INIS)

    The international conference Chemistry in Water Reactors was arranged in Nice 24-27/04/1994 by the French Nuclear Energy Society. Examples of technical program areas were primary chemistry, operational experience, fundamental studies and new technology. Furthermore there were sessions about radiation field build-up, hydrogen chemistry, electro-chemistry, condensate polishing, decontamination and chemical cleaning. The conference gave the impression that there are some areas that are going to be more important than others during the next few years to come. Cladding integrity: Professor Ishigure from Japan emphasized that cladding integrity is a subject of great concern, especially with respect to waterside corrosion, deposition and release of crud. Chemistry control: The control of the iron/nickel concentration quotient seems to be not as important as previously considered. The future operation of a nuclear power plant is going to require a better control of the water chemistry than achievable today. One example of this is solubility control via regulation in BWR. Trends in USA: means an increasing use of hydrogen, minimization of SCC/IASCC, minimization of radiation fields by thorough chemistry control, guarding fuel integrity by minimization of cladding corrosion and minimization of flow assisted corrosion. Stellite replacement: The search for replacement materials will continue. Secondary side crevice chemistry: Modeling and practical studies are required to increase knowledge about the crevice chemistry and how it develops under plant operation conditions. Inhibitors: Inhibitors for IGSCC and IGA as well for the primary- (zinc) as for the secondary side (Ti) should be studied. The effects and mode of operation of the inhibitors should be documented. Chemical cleaning: of heat transfer surfaces will be an important subject. Prophylactic cleaning at regular intervals could be one mode of operation

  7. Mathematics for physical chemistry

    CERN Document Server

    Mortimer, Robert G

    2013-01-01

    Mathematics for Physical Chemistry is the ideal supplementary text for practicing chemists and students who want to sharpen their mathematics skills while enrolled in general through physical chemistry courses. This book specifically emphasizes the use of mathematics in the context of physical chemistry, as opposed to being simply a mathematics text. This 4e includes new exercises in each chapter that provide practice in a technique immediately after discussion or example and encourage self-study. The early chapters are constructed around a sequence of mathematical topics, wit

  8. Computational quantum chemistry website

    International Nuclear Information System (INIS)

    This report contains the contents of a web page related to research on the development of quantum chemistry methods for computational thermochemistry and the application of quantum chemistry methods to problems in material chemistry and chemical sciences. Research programs highlighted include: Gaussian-2 theory; Density functional theory; Molecular sieve materials; Diamond thin-film growth from buckyball precursors; Electronic structure calculations on lithium polymer electrolytes; Long-distance electronic coupling in donor/acceptor molecules; and Computational studies of NOx reactions in radioactive waste storage

  9. Gas phase ion chemistry

    CERN Document Server

    Bowers, Michael T

    1979-01-01

    Gas Phase Ion Chemistry, Volume 1 covers papers on the advances of gas phase ion chemistry. The book discusses the advances in flow tubes and the measurement of ion-molecule rate coefficients and product distributions; the ion chemistry of the earth's atmosphere; and the classical ion-molecule collision theory. The text also describes statistical methods in reaction dynamics; the state selection by photoion-photoelectron coincidence; and the effects of temperature and pressure in the kinetics of ion-molecule reactions. The energy distribution in the unimolecular decomposition of ions, as well

  10. Experiments in physical chemistry

    CERN Document Server

    Wilson, J M; Denaro, A R

    1968-01-01

    Experiments in Physical Chemistry, Second Edition provides a compilation of experiments concerning physical chemistry. This book illustrates the link between the theory and practice of physical chemistry. Organized into three parts, this edition begins with an overview of those experiments that generally have a simple theoretical background. Part II contains experiments that are associated with more advanced theory or more developed techniques, or which require a greater degree of experimental skill. Part III consists of experiments that are in the nature of investigations wherein these invest

  11. DOE fundamentals handbook: Chemistry

    International Nuclear Information System (INIS)

    The Chemistry Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. The handbook includes information on the atomic structure of matter; chemical bonding; chemical equations; chemical interactions involved with corrosion processes; water chemistry control, including the principles of water treatment; the hazards of chemicals and gases, and basic gaseous diffusion processes. This information will provide personnel with a foundation for understanding the chemical properties of materials and the way these properties can impose limitations on the operation of equipment and systems

  12. Agricultural Industrialization: It's Inevitable

    OpenAIRE

    Urban, Thomas N.

    1991-01-01

    The industrialization of agriculture is with us. It's driven by consumer and processor needs, supported by new and useful technology, and augmented by the severe agricultural recession of the 1980s, which changed attitudes towards risk. The consequences for farm policy and rural development are significant, and should be favorable.

  13. Agriculture. Pt. 1

    International Nuclear Information System (INIS)

    The study investigates the impact of agriculture on the earth's atmosphere. It describes the natural carbon cycle, the socioeconomic factors that influence it, and the climate effects. The climatic relevance of gaseous sulphur and nitrogen compounds, methane and other hydrocarbons, and ammonia emissions from biological and agricultural process is discussed. (SR)

  14. Managing risk in agriculture

    OpenAIRE

    2015-01-01

    "This book examines the implications of risk management for policy in agriculture. Opening with a chapter on risk management principles and guidelines for policy design in agriculture, the book goes on to look at quantitative analysis of risk and then at policy in various countries." --> Publisher's description.

  15. Agricultural Sector Risk Assessment

    OpenAIRE

    World Bank

    2016-01-01

    In the agricultural sector, risks are inherent and ubiquitous, posing potentially serious consequences for stakeholders and consumers. Risks disrupt supply chains, causing extensive financial and economic losses. Agricultural risks are also the principal cause of transient food insecurity, creating a poverty trap for millions of households across the developing world that enforces a viciou...

  16. Legislature Abolishes Agricultural Tax

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

      China's 2,600-year-old agricultural tax will be rescinded as of Jan. 1,2006, after China's top legislature voted on December 27 to adopt a motion on the regulations revoking the agricultural tax.……

  17. Precision agricultural systems

    Science.gov (United States)

    Precision agriculture is a new farming practice that has been developing since late 1980s. It has been variously referred to as precision farming, prescription farming, site-specific crop management, to name but a few. There are numerous definitions for precision agriculture, but the central concept...

  18. Good Wetland Agricultural Practices

    OpenAIRE

    Hengsdijk, H.; Zingstra, H.L.

    2009-01-01

    Within the Guiding Agriculture Wetland Interaction (GAWI) project the Driver!Pressure!State! Impact!Response (DPSIR) approach has been adopted to describe and analyse agriculture!wetland interactions. The DPSIR approach provides a consistent framework to analyse the complex causal chain among drivers, pressures, state and impacts, and facilitates the targeted identification of response strategies aimed at improving the sustainability of wetlands.

  19. Agricultural risk management

    DEFF Research Database (Denmark)

    Lund, Mogens; Oksen, Arne; Larsen, Torben U.;

    2005-01-01

    A new model for risk management in agriculture is described in the paper. The risk model is constructed as a context dependent process, which includes four main phases. The model is aimed at agricultural advisors, who wish to facilitate and disseminate risk management to farmers. It is developed...

  20. Agriculture and food processing

    International Nuclear Information System (INIS)

    This chapter discuss the application of nuclear technology in agriculture sector. Nuclear Technology has help agriculture and food processing to develop tremendously. Two techniques widely use in both clusters are ionization radiation and radioisotopes. Among techniques for ionizing radiation are plant mutation breeding, SIT and food preservation. Meanwhile radioisotopes use as a tracer for animal research, plant soil relations water sedimentology

  1. Chemistry at large

    OpenAIRE

    Sanders, Jeremy K. M.

    2007-01-01

    A new book introduces young researchers to supramolecular chemistry, starting from the basics and working up to the more complicated aspects of the topic. While the text is inspiring for new graduates, it lacks a critical view.

  2. General Chemistry for Engineers.

    Science.gov (United States)

    Kybett, B. D.

    1982-01-01

    Discusses the relationship between molecular structure, intermolecular forces, and tensile strengths of a polymer and suggests that this is a logical way to introduce polymers into a general chemistry course. (Author/JN)

  3. Bringing chemistry to life

    OpenAIRE

    Boyce, Michael; Bertozzi, Carolyn R.

    2011-01-01

    Bioorthogonal chemistry allows a wide variety of biomolecules to be specifically labeled and probed in living cells and whole organisms. Here we discuss the history of bioorthogonal reactions and some of the most interesting and important advances in the field.

  4. Supplemental instruction in chemistry

    Science.gov (United States)

    Lundeberg, Mary A.

    This study was designed to measure some effects of supplemental instruction in chemistry. Supplemental instruction is a peer-led cooperative learning program that encourages students to develop conceptual understanding by articulating both understandings and misconceptions in a think-aloud fashion. Supplemental instruction was offered three hours weekly outside of class and lab time for students in four classes of General Organic and Biological Chemistry. Over a two-year period 108 students volunteered to participate in this program; 45 students did not participate. As measured by final grades in chemistry and responses to a questionnaire, supplemental instruction was effective in increasing students' achievement in chemistry. Further research is needed to determine the in-depth effects of supplemental instruction on students' learning, problem solving, and self-esteem.

  5. Beauty in chemistry

    Directory of Open Access Journals (Sweden)

    Peter Atkins

    2006-03-01

    Full Text Available Though hard going for the general reader and highly personal in its selectivity, Elegant Solutions: Ten Beautiful Experiments in Chemistry provides reflections of a thoughtful author that will delight chemists

  6. Beauty in chemistry

    OpenAIRE

    Peter Atkins

    2006-01-01

    Though hard going for the general reader and highly personal in its selectivity, Elegant Solutions: Ten Beautiful Experiments in Chemistry provides reflections of a thoughtful author that will delight chemists

  7. Magnetism in Chemistry

    Science.gov (United States)

    Brookes, R. W.; McFadyen, W. D.

    1975-01-01

    Discusses the technical aspects of paramagnetism and an electrostatic model called Crystal Field Theory (CFT), very often used in the case of transition metal compounds. Suggests that this discussion be included as an option for college chemistry courses. (MLH)

  8. Enzymes in Analytical Chemistry.

    Science.gov (United States)

    Fishman, Myer M.

    1980-01-01

    Presents tabular information concerning recent research in the field of enzymes in analytic chemistry, with methods, substrate or reaction catalyzed, assay, comments and references listed. The table refers to 128 references. Also listed are 13 general citations. (CS)

  9. Radiation technology in agriculture

    International Nuclear Information System (INIS)

    The Department of Atomic Energy through its research, development and deployment activities in nuclear science and technology, has been contributing towards enhancing the production of agricultural commodities and their preservation. Radiations and radioisotopes are used in agricultural research to induce genetic variability in crop plants to develop improved varieties, to manage insect pests, monitor fate and persistence of pesticides, to study fertilizer use efficiency and plant micronutrient uptake and also to preserve agricultural produce. Use of radiation and radioisotopes in agriculture which is often referred to as nuclear agriculture is one of the important fields of peaceful applications of atomic energy for societal benefit and BARC has contributed significantly in this area. 41 new crop varieties developed at BARC have been released and Gazette notified by the MoA, GOI for commercial cultivation and are popular among the farming community and grown through out the country

  10. Forensic Chemistry Training

    OpenAIRE

    Zuhal GERÇEK

    2012-01-01

    Increasing the types of terrorism and crime nowadays, the importance of the forensic sciences can be bett er understood. Forensic science is the application of the wide spectrum of science to answer the question of legal system. It contains the application of the principles, techniques and methods of basic sciences and its main aim is the determination of the physical facts which are important in legal situations. Forensic chemistry is the branch of chemistry which performs the chemical analy...

  11. Applications of supramolecular chemistry

    CERN Document Server

    Schneider, Hans-Jörg

    2012-01-01

    ""The time is ripe for the present volume, which gathers thorough presentations of the numerous actually realized or potentially accessible applications of supramolecular chemistry by a number of the leading figures in the field. The variety of topics covered is witness to the diversity of the approaches and the areas of implementation…a broad and timely panorama of the field assembling an eminent roster of contributors.""-Jean-Marie Lehn, 1987 Noble Prize Winner in Chemistry

  12. Fundamentals of quantum chemistry

    CERN Document Server

    House, J E

    2004-01-01

    An introduction to the principles of quantum mechanics needed in physical chemistry. Mathematical tools are presented and developed as needed and only basic calculus, chemistry, and physics is assumed. Applications include atomic and molecular structure, spectroscopy, alpha decay, tunneling, and superconductivity. New edition includes sections on perturbation theory, orbital symmetry of diatomic molecules, the Huckel MO method and Woodward/Hoffman rules as well as a new chapter on SCF and Hartree-Fock methods. * This revised text clearly presents basic q

  13. Impact of surface chemistry

    OpenAIRE

    Somorjai, Gabor A.; Li, Yimin

    2010-01-01

    The applications of molecular surface chemistry in heterogeneous catalyst technology, semiconductor-based technology, medical technology, anticorrosion and lubricant technology, and nanotechnology are highlighted in this perspective. The evolution of surface chemistry at the molecular level is reviewed, and the key roles of surface instrumentation developments for in situ studies of the gas–solid, liquid–solid, and solid–solid interfaces under reaction conditions are emphasized.

  14. Quantitative analysis chemistry

    International Nuclear Information System (INIS)

    This book is about quantitative analysis chemistry. It is divided into ten chapters, which deal with the basic conception of material with the meaning of analysis chemistry and SI units, chemical equilibrium, basic preparation for quantitative analysis, introduction of volumetric analysis, acid-base titration of outline and experiment examples, chelate titration, oxidation-reduction titration with introduction, titration curve, and diazotization titration, precipitation titration, electrometric titration and quantitative analysis.

  15. Gas phase ion chemistry

    CERN Document Server

    Bowers, Michael T

    1979-01-01

    Gas Phase Ion Chemistry, Volume 2 covers the advances in gas phase ion chemistry. The book discusses the stabilities of positive ions from equilibrium gas-phase basicity measurements; the experimental methods used to determine molecular electron affinities, specifically photoelectron spectroscopy, photodetachment spectroscopy, charge transfer, and collisional ionization; and the gas-phase acidity scale. The text also describes the basis of the technique of chemical ionization mass spectrometry; the energetics and mechanisms of unimolecular reactions of positive ions; and the photodissociation

  16. Chemistry and nuclear technology

    International Nuclear Information System (INIS)

    The underlying principles of nuclear sciece and technology as based on the two basic phenomena, namely, radioactivity and nuclear reactions, with their relatively large associated energy changes, are outlined. The most important contributions by chemists in the overall historical development are mentioned and the strong position chemistry has attained in these fields is indicated. It is concluded that chemistry as well as many other scientific discplines (apart from general benefits) have largely benefitted from these nuclear developments

  17. Sustainable Agricultural Marketing Initiatives

    Directory of Open Access Journals (Sweden)

    Hakan Adanacıoğlu

    2015-07-01

    Full Text Available Sustainable marketing is a holistic approach that puts equal emphasis on environmental, social equity, and economic concerns in the development of marketing strategies. The purpose of the study is to examine and discuss the sustainable agricultural marketing initiatives practiced throughout the World and Turkey, and to put forth suggestions to further improve the performance of agricultural marketing initiatives in Turkey. Some of the sustainable agricultural marketing initiatives practiced around the world are carried out through civil organizations. Furthermore; some of these initiatives have also launched by farmers, consumers, food processors and retailers. The long-term strategies to increase these initiatives should be determined due to the fact that examples of successful sustainable agricultural marketing initiatives are inadequate and cannot be spread in Turkey. In this context, first of all, the supports provided by the government to improve agricultural marketing systems, such as EU funds for rural development should be compatible with the goals of sustainable marketing. For this purpose, it should be examined whether all proposed projects related to agricultural marketing meet the social, economic, and environmental principles of sustainable marketing. It is important that supporting organizations, especially civil society organisations, should take an active role for faster dissemination and adoption of sustainable agricultural marketing practices in Turkey. These organizations may provide technical assistance in preparing successful project proposals and training to farm groups. In addition, the other organizations, such as local administrations, producers' associations, cooperatives, can contribute to the success of sustainable agricultural marketing initiatives. The use of direct marketing strategies and vertical integration attempts in sustainable agricultural marketing initiatives that will likely be implemented in Turkey is

  18. Research Implications of a Paradigm Shift in Agriculture: The Case of Organic Farming

    OpenAIRE

    Wynen, Els

    1996-01-01

    It is proposed in this report that organic and conventional agriculture belong to two different paradigms. The first type of agriculture, called conventional farming in this paper, is characterised by an approach of control and reductionism, emphasising treatment of symptoms instead of prevention in management. Solutions to problems within chemistry are an important part of the science involved in conventional agriculture. Although there is awareness of off-farm problems, in general these...

  19. BOOK REVIEWS - Precision agriculture

    Directory of Open Access Journals (Sweden)

    Stanisław Samborski

    2007-01-01

    Full Text Available Precision agriculture (PA is a term, which has recently become very popular in agronomy. In short this term means crop production based on site-specific crop management (SSCM. Precision agriculture is an integrated agricultural management system incorporating different science disciplines e.g. crop science, agricultural engineering and geostatistics. It also uses numerous tools i.e., geographic information system (GIS, Global Positioning System (GPS, remote sensing yield monitors. Because of the multidisciplinary character of precision agriculture, books published on this subject differ in their content. The first books on this topic appeared in the mid 90’ of the last century. The intention of this paper is to present reviews of three books the titles of which each contains the term “precision agriculture”. The books are as follows:1 Handbook of Precision Agriculture – Principles and Applications (2006 edited by Ancha Srinivasan. 2 Precision Agriculture’05 (2005 edited by John V. Stafford 3 Precision Agriculture (2006 by Terry A. Brasse.

  20. Future trends in agricultural engineering.

    OpenAIRE

    Jongebreur, A.A.; Speelman, L.

    1997-01-01

    Beside traditional mechanical engineering, other engineering branches such as electronics, control engineering and physics play their specific role within the agricultural engineering field. Agricultural engineering has affected and stimulated major changes in agriculture. In the last decades agricultural engineering has also focused on environmental aspects. Nowadays knowledge and expertise generated in several agricultural and environmental engineering fields must be integrated with experti...

  1. Atoms in Agriculture

    Energy Technology Data Exchange (ETDEWEB)

    Osborne, Thomas S. [University of Tennessee

    1965-01-01

    Agriculture benefits from the applications of research. Radioactive techniques have been used to study soils, plants, microbes, insects, farm animals, and new ways to use and preserve foodstuffs. Radioactive atoms are not used directly by farmers but are used in research directed by the U. S. Department of Agriculture and Atomic Energy Commission, by the agricultural experiment stations of the various states, and by numerous public and private research institutions. From such research come improved materials and methods which are used on the farm.

  2. Agriculture. Sector 4

    International Nuclear Information System (INIS)

    In Lebanon, emissions of greenhouse gases from agricultural activities occur through the following processes: -enteric fermentation and manure management of the domestic livestock emits methane and nitrous oxide. -agricultural burning of crop residues is of minor importance since field burning of crop residue is not a common practice in Lebanon -agricultural soils are a source of nitrous oxide directly from the soils and from animal production, and indirectly from the nitrogen added to the soils. The following results were obtained for the inventory year 1994: 7.60955 Gg of methane, 3.01478 Gg of nitrous oxide, 0.00146 Gg of nitrogen oxides and 0.04306 Gg of carbon monoxide

  3. Mathematical problems for chemistry students

    CERN Document Server

    Pota, Gyorgy

    2006-01-01

    Mathematical Problems for Chemistry Students has been compiled and written (a) to help chemistry students in their mathematical studies by providing them with mathematical problems really occurring in chemistry (b) to help practising chemists to activate their applied mathematical skills and (c) to introduce students and specialists of the chemistry-related fields (physicists, mathematicians, biologists, etc.) into the world of the chemical applications. Some problems of the collection are mathematical reformulations of those in the standard textbooks of chemistry, other

  4. Annual report 1983 Chemistry Department

    International Nuclear Information System (INIS)

    This report contains a brief survey of the main activities in the Chemistry Department. All articles and reports published and lectures given in 1983 are presented. The facilities and equipment are barely mentioned. The activities are divided into nine groups: 1. radioisotope chemistry 2. analytical- and organic chemistry 3. environmental chemistry 4. polymer chemistry 5. geochemistry and waste disposal 6. radical chemstry 7. positron annihilation 8. mineral processing 9. general. (author)

  5. Chemistry beyond positivism.

    Science.gov (United States)

    Brandt, Werner W

    2003-05-01

    Chemistry is often thought to be quite factual, and therefore might be considered close to the "positivist" ideal of a value-free science. A closer look, however, reveals that the field is coupled to the invisible realm of values, meanings, and purpose in various ways, and chemists interact with that realm loosely and unevenly. Tacit knowledge is one important locus of such interactions. We are concerned in this essay with two questions. What is the nature of the knowledge when we are in the early stages of discovery? and In what ways does the hidden reality we are seeking affect our search for an understanding of it? The first question is partly answered by Polanyi's theory of tacit knowledge, while the second one leads us to realize the limitations of our language when discussing "reality"-or certain chemical experimental results. A strictly positivist approach is of little use, but so is the opposite, the complete disregard of facts. The contrast between positivism and non-formulable aspects of scientific reasoning amounts to a paradox that needs to be analyzed and can lead to a "connected" chemistry. This in turn resembles networks described by Schweber and is more concerned than the chemistry "as it is" with aspects such as the image of chemistry, the challenges chemists face as citizens, and chemistry in liberal education. PMID:12796119

  6. Agricultural Health and Safety

    Science.gov (United States)

    ... health and safety program. Contact your state or territorial health department or use this directory of local ... producers, small business owners, youth, consumers, and rural communities nationwide. NIOSH Agricultural Safety and Health Centers conduct ...

  7. Agriculture and private sector

    DEFF Research Database (Denmark)

    Sahin, Sila; Prowse, Martin Philip; Weigh, Nadia

    looks set to remain for the next two decades at least. The agriculture and growth evidence paper series has been developed to cover a range of issues that are of most relevance to DFID staff. The paper is not intended to be a comprehensive overview of all issues relating to agriculture and the private......Agriculture is and will continue to be critical to the futures of many developing countries. This may or may not be because agriculture can contribute directly and/or indirectly to economic growth. But it will certainly be critical because poverty is still predominantly a rural phenomenon and this...... sector. It concentrates on those areas that are of particular focus for DFID policy and strategy....

  8. Agricultural Drainage Well Intakes

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — Locations of surface intakes for registered agriculture drainage wells according to the database maintained by IDALS. Surface intakes were located from their...

  9. Agricultural Producer Certificates

    Data.gov (United States)

    Montgomery County of Maryland — A Certified Agricultural Producer, or representative thereof, is an individual who wishes to sell regionally-grown products in the public right-of-way. A Certified...

  10. Radioactive contamination and agriculture

    International Nuclear Information System (INIS)

    Some guidelines are presented for the Belgian agriculture to realise three vital objectives in case of a nuclear accident : protection of food quality and public health, radiation protection for farmers and keeping the production apparatus intact. (H.E.)

  11. GREENHOUSE GASES AND AGRICULTURE

    Science.gov (United States)

    Agriculture ranks third in its contribution to Earth's anthropogenically nhanced greenhouse effect. Energy use and production and chlorofluorocarbons are anked first and second, respectively.) pecifically, greenhouse gas sources and inks are increased, and sinks are decreased, by...

  12. The Agriculture Grants Program.

    Science.gov (United States)

    Krogmann, David W.; Key, Joe

    1981-01-01

    Reviews historical background surrounding the origins of the Competitive Research Grants Office, established in 1978 to support basic research related to agriculture. Describes current controversy within the legislature which threatens its existence. (CS)

  13. New Research in Organic Agriculture

    DEFF Research Database (Denmark)

    1996-01-01

    The book is the proceedings from the bi-annual international scientific conference on organic agriculture. The chapters are: - plant and soil interactions, - animal production systems, - traditional knowledge in sustainable agriculture, - research, education and extension in sustainable agriculture...

  14. Overview of organic agriculture

    OpenAIRE

    Kristiansen, P.; Merfield, C.

    2006-01-01

    The acquisition of food, textiles and other resources from plants and animals has been a major concern for human societies, from the earliest days as hunter-gathers, through pastoral and swidden phases, to agrarian societies, with an associated trend away from nomadic to sedentary lifestyles. Yet as agricultural production intensified and expanded, the negative effects on the underlying resource base have also increased. The history of environmental damage caused by agriculture is well docume...

  15. Agricultural Clusters in China

    OpenAIRE

    Kiminami, Lily; Kiminami, Akira

    2009-01-01

    The purpose of this study is to assess the potential of clustering in the development of agriculture and rural communities in China. We shall examine in detail the food industry, which is the link in the food chain that propels the industrialization of agriculture, and identify instances of industrial agglomeration and business collaboration. Next, we shall analyze the externalities (i.e. spillovers) of clusters, demand conditions in cluster formation, and the effectiveness of business collab...

  16. HOMOEOPATHY IN AGRICULTURE

    OpenAIRE

    Singhania, Pawan Kumar; SINGHANIA, ARCHANA

    2014-01-01

    Homoeopathy medicines have been found to be effective in human organisms. Research and application of Homoeopathy drugs in agriculture is slowly finding place. The mode of action of Homoeopathy remedies and simillinum of drug pictures for use in agriculture; basic principles of Homoeopathy and drug administration are discussed. Significant results have been observed using Homoeopathy medicines to fight stress conditions during wet conditions; during hot and dry conditions; in improving germin...

  17. Agriculture Sector Risk Management

    OpenAIRE

    Viktorija Stasytytė; Viktorija Dužinskytė

    2016-01-01

    Agriculture sector is characterized by a particular specificity that is not considered in other fields and because of that agriculture sector is defined as highly risky sector. Response to risk is still very im-portant and responsible activity in this field. According to this, the process and applied strategies of risk management make and ensure that the sector activity and operations are more stable and effective. The aim of the article reflects the need to distinguish the most appropriate a...

  18. TRANSITION AND AGRICULTURE

    OpenAIRE

    Rozelle, Scott D.; Swinnen, Johan F.M.

    2000-01-01

    The overall objectives of our proposed paper is to: (a) systematically document the post-reform trends in agricultural performance in Asia, Europe, and the Former Soviet Union; (b) identify the main reform strategies and institutional innovations that have contributed to the successes and failures of the sector; (c) analyze the mechanisms by which reform policies and initial conditions have affected the transition process in agriculture; and (d) draw lessons and policy implications from the e...

  19. World competitiveness and agriculture

    Directory of Open Access Journals (Sweden)

    J. van Zyl

    1997-07-01

    Full Text Available Against the background of a changing environment in which market factors and greater world trade and competitiveness are increasingly becoming the only criteria for success, a framework for the analysis of world competitiveness is initially developed. This is followed by a discussion on the growth of productivity in agriculture, as well as an exposition of the role of agricultural research. Thirdly, price factors and the terms of trade are discussed, followed by a summary of policy implications.

  20. Brazil Agriculture Policy Review

    OpenAIRE

    Quiroga, Jose; Brooks, Jonathan; Melyukhina, Olga

    2005-01-01

    In June 2005, OECD members met with senior government officials from Brazil to discuss Brazilian agricultural policies and future directions, as a part of a comprehensive agricultural policy review. Ongoing dialogue with Brazil on policy issues is important to fostering a better understanding of global challenges and opportunities that lie ahead. Results of the review will be published by the OECD in 2005. This policy note provides a preview of key findings.

  1. Collaborative Physical Chemistry Projects Involving Computational Chemistry

    Science.gov (United States)

    Whisnant, David M.; Howe, Jerry J.; Lever, Lisa S.

    2000-02-01

    The physical chemistry classes from three colleges have collaborated on two computational chemistry projects using Quantum CAChe 3.0 and Gaussian 94W running on Pentium II PCs. Online communication by email and the World Wide Web was an important part of the collaboration. In the first project, students used molecular modeling to predict benzene derivatives that might be possible hair dyes. They used PM3 and ZINDO calculations to predict the electronic spectra of the molecules and tested the predicted spectra by comparing some with experimental measurements. They also did literature searches for real hair dyes and possible health effects. In the final phase of the project they proposed a synthetic pathway for one compound. In the second project the students were asked to predict which isomer of a small carbon cluster (C3, C4, or C5) was responsible for a series of IR lines observed in the spectrum of a carbon star. After preliminary PM3 calculations, they used ab initio calculations at the HF/6-31G(d) and MP2/6-31G(d) level to model the molecules and predict their vibrational frequencies and rotational constants. A comparison of the predictions with the experimental spectra suggested that the linear isomer of the C5 molecule was responsible for the lines.

  2. Ghana Agricultural Sector Risk Assessment

    OpenAIRE

    Choudhary, Vikas; D'Alessandro, Stephen

    2015-01-01

    Improved agricultural risk management is one of the core enabling actions of the Group of Eight’s (G-8’s) New Alliance for Food Security and Nutrition. The Agricultural Risk Management Team (ARMT) of the Agriculture and Environment Services Department of the World Bank conducted an agricultural sector risk assessment to better understand the dynamics of agricultural risks and identify appropriate responses, incorporate agricultural risk perspective into decision-making, and bui...

  3. FAPRI 2000 World Agricultural Outlook

    OpenAIRE

    Babcock, Bruce A.; Beghin, John C.; Mohanty, Samarendu; Frank H. Fuller; Jacinto F. Fabiosa; Kaus, Phillip J.; Fang, Cheng; Hart, Chad E.; Kovarik, Karen; Womack, Abner W.; Young, Robert E., II; Suhler, Gregg; Patrick C. Westhoff; Trujillo, Joe; Brown, D. Scott

    2000-01-01

    The Food and Agricultural Policy Research Institute (FAPRI) prepares a preliminary agricultural outlook on world agricultural production, consumption, and trade every fall. This is followed by an outside review, re-evaluation of projections, and completion of the final baseline in January. The FAPRI 2000 World Agricultural Outlook presents these final projections for world agricultural markets. A companion volume, the FAPRI 2000 U.S. Agricultural Outlook, presents the U.S. component of the ba...

  4. Indian Agricultural Marketing- A Review

    OpenAIRE

    Shakeel-Ul-Rehman; M. SELVARAJ; M. Syed Ibrahim

    2012-01-01

    Agriculture in India has directly or indirectly continued to be the source of livelihood to majority of the population. Indian agriculture has seen a lot of changes in its structure. India, predominantly an agricultural economy, has healthy signs of transformation in agriculture and allied activities. India has seen agriculture as a precious tool of economic development as other sectors of production depend on it. Efficient backward and forward integration with agriculture has led to globally...

  5. Reaction chemistry of cerium

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-01-01

    It is truly ironic that a synthetic organic chemist likely has far greater knowledge of the reaction chemistry of cerium(IV) than an inorganic colleague. Cerium(IV) reagents have long since been employed as oxidants in effecting a wide variety of organic transformations. Conversely, prior to the late 1980s, the number of well characterized cerium(IV) complexes did not extend past a handful of known species. Though in many other areas, interest in the molecular chemistry of the 4f-elements has undergone an explosive growth over the last twenty years, the chemistry of cerium(IV) has for the most part been overlooked. This report describes reactions of cerium complexes and structure.

  6. Chemistry of plutonium revealed

    International Nuclear Information System (INIS)

    In 1941 one goal of the Manhattan Project was to unravel the chemistry of the synthetic element plutonium as rapidly as possible. In this paper the work carried out at Berkeley from the spring of 1942 to the summer of 1945 is described briefly. The aqueous chemistry of plutonium is quite remarkable. Important insights were obtained from tracer experiments, but the full complexity was not revealed until macroscopic amounts (milligrams) became available. Because processes for separation from fission products were based on aqueous solutions, such solution chemistry was emphasized, particularly precipitation and oxidation-reduction behavior. The latter turned out to be unusually intricate when it was discovered that two more oxidation states existed in aqueous solution than had previously been suspected. Further, an equilibrium was rapidly established among the four aqueous oxidation states, while at the same time any three were not in equilibrium. These and other observations made while doing a crash study of a previously unknown element are reported

  7. Introductory quantum chemistry

    International Nuclear Information System (INIS)

    This book on quantum chemistry is primarily intended for university students at the senior undergraduate level. It serves as an aid to the basic understanding of the important concepts of quantum mechanics introduced in the field of chemistry. Various chapters of the book are devoted to the following : (i) Waves and quanta, (ii) Operator concept in quantum chemistry, (iii) Wave mechanics of some simple systems, (iv) Perturbation theory, (v) Many-electron atoms and angular momenta (vi) Molecular orbital theory and its application to the electronic structure of diatomic molecules, (vii) Chemical bonding in polyatomic molecules and (viii) Chemical applications of Hellmann-Feynman theorem. At the end of each chapter, a set of problems is given and the answers to these problems are given at the end of the book. (A.K.)

  8. Mathematics for physical chemistry

    CERN Document Server

    Mortimer, Robert G

    2005-01-01

    Mathematics for Physical Chemistry, Third Edition, is the ideal text for students and physical chemists who want to sharpen their mathematics skills. It can help prepare the reader for an undergraduate course, serve as a supplementary text for use during a course, or serve as a reference for graduate students and practicing chemists. The text concentrates on applications instead of theory, and, although the emphasis is on physical chemistry, it can also be useful in general chemistry courses. The Third Edition includes new exercises in each chapter that provide practice in a technique immediately after discussion or example and encourage self-study. The first ten chapters are constructed around a sequence of mathematical topics, with a gradual progression into more advanced material. The final chapter discusses mathematical topics needed in the analysis of experimental data.* Numerous examples and problems interspersed throughout the presentations * Each extensive chapter contains a preview, objectives, and ...

  9. Dynamic Combinatorial Chemistry

    DEFF Research Database (Denmark)

    Lisbjerg, Micke

    This thesis is divided into seven chapters, which can all be read individually. The first chapter, however, contains a general introduction to the chemistry used in the remaining six chapters, and it is therefore recommended to read chapter one before reading the other chapters. Chapter 1...... is a general introductory chapter for the whole thesis. The history and concepts of dynamic combinatorial chemistry are described, as are some of the new and intriguing results recently obtained. Finally, the properties of a broad range of hexameric macrocycles are described in detail. Chapter 2 gives...

  10. Cloud chemistry on Jupiter

    OpenAIRE

    Carlson, B. E.; Prather, M. J.; W. B. Rossow

    1987-01-01

    Aqueous chemistry on Uranus affects the atmospheric abundances of NH3 and H2S below the methane cloud base. Here a complete thermochemical equilibrium model for the H2O-NH3-H2S system is presented. Inclusion of H2S increases the aqueous removal of NH3 to 20-30 percent, but aqueous chemistry alone cannot account for the depletion of NH3 in the 150-200-K region of the atmosphere required to fit microwave observations. Formation of NH4SH clouds can account for the observed depletion provided the...

  11. Chemistry of Transactinides

    Science.gov (United States)

    Kratz, J. V.

    In this chapter, the chemical properties of the man-made transactinide elements rutherfordium, Rf (element 104), dubnium, Db (element 105), seaborgium, Sg (element 106), bohrium, Bh (element 107), hassium, Hs (element 108), and copernicium, Cn (element 112) are reviewed, and prospects for chemical characterizations of even heavier elements are discussed. The experimental methods to perform rapid chemical separations on the time scale of seconds are presented and comments are given on the special situation with the transactinides where chemistry has to be studied with single atoms. It follows a description of theoretical predictions and selected experimental results on the chemistry of elements 104 through 108, and element 112.

  12. Solvent effects in chemistry

    CERN Document Server

    Buncel, Erwin

    2015-01-01

    This book introduces the concepts, theory and experimental knowledge concerning solvent effects on the rate and equilibrium of chemical reactions of all kinds.  It begins with basic thermodynamics and kinetics, building on this foundation to demonstrate how a more detailed understanding of these effects may be used to aid in determination of reaction mechanisms, and to aid in planning syntheses. Consideration is given to theoretical calculations (quantum chemistry, molecular dynamics, etc.), to statistical methods (chemometrics), and to modern day concerns such as ""green"" chemistry, where ut

  13. Nanophotonics and supramolecular chemistry

    Science.gov (United States)

    Ariga, Katsuhiko; Komatsu, Hirokazu; Hill, Jonathan P.

    2013-10-01

    Supramolecular chemistry has become a key area in emerging bottom-up nanoscience and nanotechnology. In particular, supramolecular systems that can produce a photonic output are increasingly important research targets and present various possibilities for practical applications. Accordingly, photonic properties of various supramolecular systems at the nanoscale are important in current nanotechnology. In this short review, nanophotonics in supramolecular chemistry will be briefly summarized by introducing recent examples of control of photonic responses of supramolecular systems. Topics are categorized according to the fundamental actions of their supramolecular systems: (i) self-assembly; (ii) recognition; (iii) manipulation.

  14. Revitalizing chemistry laboratory instruction

    Science.gov (United States)

    McBride, Phil Blake

    This dissertation involves research in three major domains of chemical education as partial fulfillment of the requirements for the Ph.D. program in chemistry at Miami University with a major emphasis on chemical education, and concurrent study in organic chemistry. Unit I, Development and Assessment of a Column Chromatography Laboratory Activity, addresses the domain of Instructional Materials Development and Testing. This unit outlines the process of developing a publishable laboratory activity, testing and revising that activity, and subsequently sharing that activity with the chemical education community. A laboratory activity focusing on the separation of methylene blue and sodium fluorescein was developed to demonstrate the effects of both the stationary and mobile phase in conducting a separation. Unit II, Bringing Industry to the Laboratory, addresses the domain of Curriculum Development and Testing. This unit outlines the development of the Chemistry of Copper Mining module, which is intended for use in high school or undergraduate college chemistry. The module uses the learning cycle approach to present the chemistry of the industrial processes of mining copper to the students. The module includes thirteen investigations (three of which are web-based and ten which are laboratory experiments) and an accompanying interactive CD-ROM, which provides an explanation of the chemistry used in copper mining with a virtual tour of an operational copper mine. Unit III, An Alternative Method of Teaching Chemistry. Integrating Lecture and the Laboratory, is a project that addresses the domain of Research in Student Learning. Fundamental Chemistry was taught at Eastern Arizona College as an integrated lecture/laboratory course that met in two-hour blocks on Monday, Wednesday, and Friday. The students taking this integrated course were compared with students taking the traditional 1-hour lectures held on Monday, Wednesday, and Friday, with accompanying 3-hour lab on

  15. Computational organometallic chemistry

    International Nuclear Information System (INIS)

    In this article, the author highlights the tremendous impact that density functional theory has had on computational chemistry over the last decade. This robust and efficient theoretical technique (for which John Pople and Walter Kohn were awarded the Nobel Prize in 1998) has opened up many new possibilities for chemists, allowing to study large systems with a degree of reliability hitherto uncontemplated. Examples which illustrate how both density functional theory and hybrid method have been successfully used in solving difficult problems in quantum chemistry of catalysis are briefly discussed

  16. Spins in chemistry

    CERN Document Server

    McWeeny, Roy

    2004-01-01

    Originally delivered as a series of lectures, this volume systematically traces the evolution of the ""spin"" concept from its role in quantum mechanics to its assimilation into the field of chemistry. Author Roy McWeeny presents an in-depth illustration of the deductive methods of quantum theory and their application to spins in chemistry, following the path from the earliest concepts to the sophisticated physical methods employed in the investigation of molecular structure and properties. Starting with the origin and development of the spin concept, the text advances to an examination of sp

  17. Atmospheric pseudohalogen chemistry

    OpenAIRE

    Lary, D. J.

    2004-01-01

    There are at least three reasons why hydrogen cyanide is likely to be significant for atmospheric chemistry. The first is well known, HCN is a product and marker of biomass burning. However, if a detailed ion chemistry of lightning is considered then it is almost certain than in addition to lightning producing NOx, it also produces HOx and HCN. Unlike NOx and HOx, HCN is long-lived and could therefore ...

  18. Chemistry WebBook

    Science.gov (United States)

    SRD 69 NIST Chemistry WebBook (Web, free access)   The NIST Chemistry WebBook contains: Thermochemical data for over 7000 organic and small inorganic compounds; thermochemistry data for over 8000 reactions; IR spectra for over 16,000 compounds; mass spectra for over 33,000 compounds; UV/Vis spectra for over 1600 compounds; electronic and vibrational spectra for over 5000 compounds; constants of diatomic molecules(spectroscopic data) for over 600 compounds; ion energetics data for over 16,000 compounds; thermophysical property data for 74 fluids.

  19. Chemistry in microelectronics

    CERN Document Server

    Le Tiec, Yannick

    2013-01-01

    Microelectronics is a complex world where many sciences need to collaborate to create nano-objects: we need expertise in electronics, microelectronics, physics, optics and mechanics also crossing into chemistry, electrochemistry, as well as biology, biochemistry and medicine. Chemistry is involved in many fields from materials, chemicals, gases, liquids or salts, the basics of reactions and equilibrium, to the optimized cleaning of surfaces and selective etching of specific layers. In addition, over recent decades, the size of the transistors has been drastically reduced while the functionalit

  20. Environmental chemistry. 3. ed.

    International Nuclear Information System (INIS)

    The book Environmental Chemistry deals with the basic aspects of environmental chemistry, the natural cycles of the environment, composition of atmosphere and various effects in it by pollutants due to human activities, like energy production, industrial endeavours etc. Details pertaining to the effect of various pollutants on ecosystem are also explained. A number of instrumented techniques in environmental chemical analysis including neutron activation analysis, spectroscopic methods are given. The correlation between energy and environment is dealt with consideration to the global aspects of it. Paper relevant to INIS database is indexed separately. (M.K.V.)

  1. The chemistry of silicon

    CERN Document Server

    Rochow, E G; Emeléus, H J; Nyholm, Ronald

    1975-01-01

    Pergamon Texts in Organic Chemistry, Volume 9: The Chemistry of Silicon presents information essential in understanding the chemical properties of silicon. The book first covers the fundamental aspects of silicon, such as its nuclear, physical, and chemical properties. The text also details the history of silicon, its occurrence and distribution, and applications. Next, the selection enumerates the compounds and complexes of silicon, along with organosilicon compounds. The text will be of great interest to chemists and chemical engineers. Other researchers working on research study involving s

  2. Progress in physical chemistry

    CERN Document Server

    Hempelmann, Rolf

    2008-01-01

    Progress in Physical Chemistry is a collection of recent ""Review Articles"" published in the ""Zeitschrift für Physikalische Chemie"". The second volume of Progress in Physical Chemistry is a collection of thematically closely related minireview articles written by the members of the Collaborative Research Centre (SFB) 277 of the German Research Foundation (DFG). These articles are based on twelve years of intense coordinated research efforts. Central topics are the synthesis and the characterization of interface-dominated, i.e. nanostructured materials, mainly in the solid state but also as

  3. Chemistry in Second Life

    Directory of Open Access Journals (Sweden)

    Bradley Jean-Claude

    2009-10-01

    Full Text Available Abstract This review will focus on the current level on chemistry research, education, and visualization possible within the multi-user virtual environment of Second Life. We discuss how Second Life has been used as a platform for the interactive and collaborative visualization of data from molecules and proteins to spectra and experimental data. We then review how these visualizations can be scripted for immersive educational activities and real-life collaborative research. We also discuss the benefits of the social networking affordances of Second Life for both chemists and chemistry students.

  4. Chemistry and lithography

    CERN Document Server

    Okoroanyanwu, Uzodinma

    2011-01-01

    This is a unique book, combining chemistry and physics with technology and history in a way that is both enlightening and lively. No other book in the field of lithography has as much breadth. Highly recommended for anyone interested in the broad application of chemistry to lithography. --Chris Mack, Gentleman Scientist. This book provides a comprehensive treatment of the chemical phenomena in lithography in a manner that is accessible to a wide readership. The book presents topics on the optical and charged particle physics practiced in lithography, with a broader view of how the marriage bet

  5. Frontiers in nuclear chemistry

    International Nuclear Information System (INIS)

    This book contains articles on the landmarks in nuclear and radiochemistry which takes through scientific history spanning over five decades from the times of Roentgen to the middle of this century. Articles on nuclear fission and back end of the nuclear fuel cycle give an insight into the current status of this subject. Reviews on frontier areas like lanthanides, actinides, muonium chemistry, accelerator based nuclear chemistry, fast radiochemical separations and nuclear medicine bring out the multidisciplinary nature of nuclear sciences. This book also includes an article on environmental radiochemistry and safety. Chapters relevant to INIS are indexed separately

  6. Biosurfactants in agriculture.

    Science.gov (United States)

    Sachdev, Dhara P; Cameotra, Swaranjit S

    2013-02-01

    Agricultural productivity to meet growing demands of human population is a matter of great concern for all countries. Use of green compounds to achieve the sustainable agriculture is the present necessity. This review highlights the enormous use of harsh surfactants in agricultural soil and agrochemical industries. Biosurfactants which are reported to be produced by bacteria, yeasts, and fungi can serve as green surfactants. Biosurfactants are considered to be less toxic and eco-friendly and thus several types of biosurfactants have the potential to be commercially produced for extensive applications in pharmaceutical, cosmetics, and food industries. The biosurfactants synthesized by environmental isolates also has promising role in the agricultural industry. Many rhizosphere and plant associated microbes produce biosurfactant; these biomolecules play vital role in motility, signaling, and biofilm formation, indicating that biosurfactant governs plant-microbe interaction. In agriculture, biosurfactants can be used for plant pathogen elimination and for increasing the bioavailability of nutrient for beneficial plant associated microbes. Biosurfactants can widely be applied for improving the agricultural soil quality by soil remediation. These biomolecules can replace the harsh surfactant presently being used in million dollar pesticide industries. Thus, exploring biosurfactants from environmental isolates for investigating their potential role in plant growth promotion and other related agricultural applications warrants details research. Conventional methods are followed for screening the microbial population for production of biosurfactant. However, molecular methods are fewer in reaching biosurfactants from diverse microbial population and there is need to explore novel biosurfactant from uncultured microbes in soil biosphere by using advanced methodologies like functional metagenomics. PMID:23280539

  7. Geogenic and agricultural controls on the geochemical composition of European agricultural soils

    Science.gov (United States)

    Mol, Gerben; Saaltink, Remon; Griffioen, Jasper; Birke, Manfred

    2014-05-01

    Purpose: Concern about the environmental impact of agriculture caused by intensification is growing as large amounts of nutrients and contaminants are introduced into the environment. The aim of this paper is to identify the geogenic and agricultural controls on the elemental composition of European, grazing and agricultural soils. Materials and methods: Robust factor analysis was applied to data series for Al,B,Ca, Cd,Co, Cu, Fe, K, Mg,Mn, Na,Ni, P, S, Se, Sr, U, Zn (ICP-MS) and SiO2, K2O, Na2O, Fe2O3, Al2O3 (XRF) based on the European GEMAS dataset. In addition, the following general soil properties were included: clay content, pH, chemical index of alteration (CIA), loss on ignition (LOI), cation exchange capacity (CEC), total organic carbon (TOC) and total carbon and total sulfur. Furthermore, this dataset was coupled to a dataset containing information of historic P2O5 fertilization across Europe. Also, a mass balance was carried out for Cd, Cu and Zn to determine if concentrations of these elements found in the soils have their origin in historic P2O5 fertilization. Results and discussion: Seven geogenic factors and one agricultural factor were found of which four prominent ones (all geogenic): chemical weathering, reactive iron-aluminum oxide minerals, clay minerals and carbonate minerals. Results for grazing and agricultural soils were near identical, which further proofs the prominence of geogenic controls on the total elemental composition. When the cumulative amount of P2O5 fertilization was considered, no extra agriculture-related factors became visible. The mass balance confirms these observations. Conclusion: Overall, the geological controls are more important for the total soil chemistry in agricultural and grazing land soils than the anthropogenic controls.

  8. A química orgânica na consolidação dos conceitos de átomo e molécula Organic chemistry in the consolidation of the concepts of atom and molecule

    OpenAIRE

    Tânia de Oliveira Camel; Carlos B. G. Koehler; Carlos A. L. Filgueiras

    2009-01-01

    The present work discusses the appearance of the concepts of valence and molecular structure, and describes the appropriation and evolution of the concept of molecule in the period following the publication of Avogadro's Hypothesis. The point of reference is the development of what became known as Organic Chemistry, which encompassed Pharmacy, Physiological Chemistry, Animal and Plant Chemistry, Chemistry of Dyestuffs, Agricultural Chemistry, and the fledgling Organic Synthesis industry in th...

  9. Symposium on chemistry and biotechnology for national development. Proceedings

    International Nuclear Information System (INIS)

    This document is the full proceedings of the symposium on chemistry and biotechnology for national development held at SHESTCO in 1995. It contains the full texts of a forward, opening and special remarks, welcome and keynote addresses and abstracts and texts of 21 technical papers. The subjects covered included information technology,chemistry and biotechnology in agriculture, health care and industrial development. Additionally, the abstracts in respect of 19 other papers are included. We wish to thank the Coordinator of SHESTCO for making available this proceedings

  10. How to teach chemistry? Is Chemistry a new universal language

    OpenAIRE

    López Guerrero, María del Mar; López Guerrero, Gema

    2015-01-01

    Chemistry has been developed greatly throughout the 20th century. Chemistry is included in the curriculum of elementary and secondary education. In general, students are not interested in science, and because of this ,students tend not to make an effort to learn and understand the meaning of concepts and the chemistry language that are being taught to them. If we consider that there is a little bit analogy between chemistry and foreign languages, we should learn the s...

  11. Array processors in chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Ostlund, N.S.

    1980-01-01

    The field of attached scientific processors (''array processors'') is surveyed, and an attempt is made to indicate their present and possible future use in computational chemistry. The current commercial products from Floating Point Systems, Inc., Datawest Corporation, and CSP, Inc. are discussed.

  12. Chromatin chemistry goes cellular.

    OpenAIRE

    W. Fischle; D. Schwarzer; Mootz, H.

    2015-01-01

    Analysing post-translational modifications of histone proteins as they occur within chromatin is challenging due to their large number and chemical diversity. A major step forward has now been achieved by using split intein chemistry to engineer functionalized histones within cells.

  13. Chemistry in Protoplanetary Disks

    OpenAIRE

    Henning, Thomas; Semenov, Dmitry

    2013-01-01

    This comprehensive review summarizes our current understanding of the evolution of gas, solids and molecular ices in protoplanetary disks. Key findings related to disk physics and chemistry, both observationally and theoretically, are highlighted. We discuss which molecular probes are used to derive gas temperature, density, ionization state, kinematics, deuterium fractionation, and study organic matter in protoplanetary disks.

  14. Chemistry Education and Mythology

    OpenAIRE

    Sule Aycan

    2005-01-01

    This study aimed to investigate the effect of mythological story in teaching chemistry. To this end the students in the class were divided into two homogenous groups. While the first group was thought in a traditional way, using a mythological story thought the second group. The story used was based on a Mountain just opposite the faculty.

  15. Chemistry Cook-Off

    Science.gov (United States)

    McCormick, Cynthia

    2012-01-01

    For this activity, high school chemistry students compete in a cooking contest. They must determine the chemical and physical changes that occur in the food they prepare, present their recipe as a step-by-step procedure similar to a lab procedure, identify chemicals in the food, and present all measurements in both metric and English units. The…

  16. Symmetry in chemistry

    CERN Document Server

    Jaffé, Hans H

    1977-01-01

    This book, devoted exclusively to symmetry in chemistry and developed in an essentially nonmathematical way, is a must for students and researchers. Topics include symmetry elements and operations, multiple symmetry operations, multiplication tables and point groups, group theory applications, and crystal symmetry. Extensive appendices provide useful tables.

  17. Nuclear Chemistry, exercises

    International Nuclear Information System (INIS)

    Those exercises have as objective to introduce the student in the basic concepts of nuclear chemistry: a) way of decline b) balances of mass used in nuclear reactions c) how to calculate activities, activity concentrations and specific activity d) radiotracers use in biomedical sciences pharmaceutical

  18. The chemistry of glycerin

    International Nuclear Information System (INIS)

    This book dedicated to chemistry of polyatomic alcohols, in particular, to glycerin and its numerous derivatives. These compounds are very widespread in the natural objects and carry out several functions in alive organism. Big part of these matters are arrange in industry production of base organic synthesis

  19. Online Organic Chemistry

    Science.gov (United States)

    Janowicz, Philip A.

    2010-01-01

    This is a comprehensive study of the many facets of an entirely online organic chemistry course. Online homework with structure-drawing capabilities was found to be more effective than written homework. Online lecture was found to be just as effective as in-person lecture, and students prefer an online lecture format with shorter Webcasts. Online…

  20. Nobel Prize in Chemistry

    Science.gov (United States)

    2000-01-01

    The Royal Swedish Academy has awarded the 1999 Nobel Prize in Chemistry to Ahmed H. Zewail (California Institute of Technology, Pasadena, CA) "for his studies of the transition states of chemical reactions using femtosecond spectroscopy". Zewail's work has taken the study of the rates and mechanisms of chemical reactions to the ultimate degree of detail - the time scale of bond making and bond breaking.

  1. Chemistry and Heritage

    Science.gov (United States)

    Vittoria Barbarulo, Maria

    2014-05-01

    Chemistry is the central science, as it touches every aspect of the society we live in and it is intertwined with many aspects of our culture; in particular, the strong link between Chemistry and Archaeology and Art History is being explored, offering a penetrating insight into an area of growing interest from an educational point of view. A series of vital and vibrant examples (i.e., ancient bronzes composition, colour changes due to natural pigment decomposition, marble degradation) has been proposed, on one hand, to improve student understanding of the relationship between cultural and scientific issues arising from the examination, the conservation, and the maintenance of cultural Heritage, on the other, to illustrate the role of the underlying Chemistry. In some case studies, a survey of the most relevant atmospheric factors, which are involved in the deterioration mechanisms, has also been presented to the students. First-hand laboratory experiences have been providing an invaluable means of discovering the full and varied world of Chemistry. Furthermore, the promotion of an interdisciplinary investigation of a famous painting or fresco, involving the study of its nature and significance, the definition of its historical context, any related literature, the chemical knowledge of the materials used, may be an excellent occasion to experiment the Content and Language Integrated Learning (CLIL). The aim of this approach is to convey the important message that everyone has the responsibility to care for and preserve Heritage for the benefit of present and future generations.

  2. Metaphorical Models in Chemistry.

    Science.gov (United States)

    Rosenfeld, Stuart; Bhusan, Nalini

    1995-01-01

    What happens when students of chemistry fail to recognize the metaphorical status of certain models and interpret them literally? Suggests that such failures lead students to form perceptions of phenomena that can be misleading. Argues that the key to making good use of metaphorical models is a recognition of their metaphorical status. Examines…

  3. Spatially Resolved Artificial Chemistry

    DEFF Research Database (Denmark)

    Fellermann, Harold

    2009-01-01

    made a class of models accessible to the realms of artificial chemistry that represent reacting molecules in a coarse-grained fashion in continuous space. This chapter introduces the mathematical models of Brownian dynamics (BD) and dissipative particle dynamics (DPD) for molecular motion and reaction...

  4. The Chemistry of Griseofulvin

    DEFF Research Database (Denmark)

    Petersen, Asger Bjørn; Rønnest, Mads Holger; Larsen, Thomas Ostenfeld;

    2014-01-01

    Specific synthetic routes are presented in schemes to illustrate the chemistry, and the analogs are presented in a table format to give an accessible overview of the structures. Several patents have been published regarding the properties of griseofulvin and its derivatives including synthesis...

  5. Chemistry Education and Mythology

    Directory of Open Access Journals (Sweden)

    Sule Aycan

    2005-01-01

    Full Text Available This study aimed to investigate the effect of mythological story in teaching chemistry. To this end the students in the class were divided into two homogenous groups. While the first group was thought in a traditional way, using a mythological story thought the second group. The story used was based on a Mountain just opposite the faculty.

  6. Forensic Chemistry Training

    Directory of Open Access Journals (Sweden)

    Zuhal GERÇEK

    2012-01-01

    Full Text Available Increasing the types of terrorism and crime nowadays, the importance of the forensic sciences can be bett er understood. Forensic science is the application of the wide spectrum of science to answer the question of legal system. It contains the application of the principles, techniques and methods of basic sciences and its main aim is the determination of the physical facts which are important in legal situations. Forensic chemistry is the branch of chemistry which performs the chemical analysis of evidences that used in the courts. Forensic chemist is the professional chemist who analyzes the evidences from crime scene and reaches a result by application of tests. Th us, they have to have a special education. In forensic laboratories candidates who have chemistry/biochemistry undergraduate degree and took biology and forensic chemistry lectures are preferred. It is necessary to design graduate and undergraduate education to train a forensic chemist. Science education should be at the core of the undergraduate education. In addition to this strong laboratory education on both science and forensic science should be given. Th e graduate program of forensic science example should contain forensic science subjects, strong academic lectures on special subjects and research and laboratory components.

  7. Analytical Chemistry Laboratory

    Science.gov (United States)

    Anderson, Mark

    2013-01-01

    The Analytical Chemistry and Material Development Group maintains a capability in chemical analysis, materials R&D failure analysis and contamination control. The uniquely qualified staff and facility support the needs of flight projects, science instrument development and various technical tasks, as well as Cal Tech.

  8. Evaluating Environmental Chemistry Textbooks.

    Science.gov (United States)

    Hites, Ronald A.

    2001-01-01

    A director of the Indiana University Center for Environmental Science Research reviews textbooks on environmental chemistry. Highlights clear writing, intellectual depth, presence of problem sets covering both the qualitative and quantitative aspects of the material, and full coverage of the topics of concern. Discusses the director's own approach…

  9. Chemistry between the stars

    Science.gov (United States)

    Gammon, R. H.

    1976-01-01

    A unit is presented for the secondary school teacher of physics, chemistry, astronomy, or earth sciences. Included are a list of reference materials, teaching aids, and projects. Discussion questions and a glossary are also provided. Concepts developed are: the nature of interstellar space, spectroscopy, molecular signals from space and interstellar molecules and other areas of astronomy.

  10. The cultivated agricultural environment

    International Nuclear Information System (INIS)

    Local agricultural practices in the Nordic countries have resulted in a great diversity in agriculture in the Nordic countries. The diversities mean that in the event of contamination of agricultural land by radioactive fallout the consequences may differ greatly from region to region. For crops and soils contaminated directly by radioactive fallout there are five primary causes for concern, namely: 1. short-term internal contamination of man and animals through ingestion of surface-contaminated mature crops; 2. internal contamination of crops through foliar intake; 3. contamination of mature crops from resuspended soil; 4. direct irradiation of agricultural workers; 5. internal irradiation from inhalation of resuspended soil particulates. In the short-term, most of the radionuclides likely to be released to the atmosphere in the event of an accident have a potential to cause problems in agriculture and many have the potential for causing long-term problems. Generally, the magnitude of the problems created will depend on the: deposition mechanism (wet or dry); radionuclide composition of the fallout; type of farming system (i.e. arable or dairy); type of soil (for instance organic soils are more sensitive than mineral soils with respect to radiocaesium); state of development of the crop which in turn is determined by the season of the year. (EG)

  11. THE ECOLOGICAL AGRICULTURE – A MODEL OF DURABLE AGRICULTURE

    OpenAIRE

    TABITA CORNELIA ADAMOV; T. IANCU; ANDREA NAGY; COSMINA-SIMONA TOADER

    2013-01-01

    In the context of the community agriculture politics orientation toward a natural agriculture, where the concept of ecological agriculture has a very well defined place, it is necessary to intensify the efforts to promote the ecological agriculture practices and to inform the farmers about the importance and the role of the ecological technologies and, last but not least, the economical advantages and also the advantages to improve the environment. The ecological agriculture (similar term for...

  12. Agricultural land evaluation in the process of agricultural land consolidation

    OpenAIRE

    Fištravec, Polonca

    2008-01-01

    Agricultural land is limited and therefore needs to be protected, preserved and adequately managed. One of the most important instruments of rural planning as well as agricultural land planning represent agricultural operations, first of all the process of land consolidation. Diploma thesis deals with the process of agricultural land consolidation as a whole, emphasizing the agricultural land evaluation during the process. This is cruicial for just and efficient dealings of the...

  13. Data mining in agriculture

    CERN Document Server

    Mucherino, Antonio; Pardalos, Panos M

    2009-01-01

    Data Mining in Agriculture represents a comprehensive effort to provide graduate students and researchers with an analytical text on data mining techniques applied to agriculture and environmental related fields. This book presents both theoretical and practical insights with a focus on presenting the context of each data mining technique rather intuitively with ample concrete examples represented graphically and with algorithms written in MATLAB®. Examples and exercises with solutions are provided at the end of each chapter to facilitate the comprehension of the material. For each data mining technique described in the book variants and improvements of the basic algorithm are also given. Also by P.J. Papajorgji and P.M. Pardalos: Advances in Modeling Agricultural Systems, 'Springer Optimization and its Applications' vol. 25, ©2009.

  14. Measuring Agricultural Bias

    DEFF Research Database (Denmark)

    Jensen, Henning Tarp; Robinson, Sherman; Tarp, Finn

    The measurement issue is the key issue in the literature on trade policy-induced agri-cultural price incentive bias. This paper introduces a general equilibrium effective rate of protection (GE-ERP) measure, which extends and generalizes earlier partial equilibrium nominal protection measures....... For the 15 sample countries, the results indicate that the agricultural price incentive bias, which was generally perceived to exist during the 1980s, was largely eliminated during the 1990s. The results also demonstrate that general equilibrium effects and country-specific characteristics - including trade...... shares and intersectoral linkages - are crucial for determining the sign and magnitude of trade policy bias. The GE-ERP measure is therefore uniquely suited to capture the full impact of trade policies on agricultural price incentives. A Monte Carlo procedure confirms that the results are robust...

  15. AGRICULTURAL ECONOMICS, INTERDEPENDENCE AND UNCERTAINTY

    OpenAIRE

    Anderson, Jock R.

    1982-01-01

    Interdependence has always been central to economics but assumes pressing importance for agricultural economists as they deal with industrialising agricultures. Continued unresolvable uncertainties, when properly recognised, also add to the challenge of relevant work in agricultural economics. The related roles of interdependence and uncertainty are illustrated through examples from the progress of agricultural technology and enhancement of food security.

  16. Effects of the Cooperative Class Experiment Teaching Method on Secondary School Students' Chemistry Achievement in Kenya's Nakuru District

    Science.gov (United States)

    Wachanga, Samuel W.; Mwangi, John Gowland

    2004-01-01

    Successful teaching and learning of chemistry depends partly on correct use of a teaching method whose activities target most learning senses. Though chemistry enhances students' learning of biology, physics and agriculture on which Kenyan industries and prosperity depend, most secondary school students in Kenya perform poorly on the subject. This…

  17. LAYERED DOUBLE HYDROXIDES: NANOMATERIALS FOR APPLICATIONS IN AGRICULTURE

    Directory of Open Access Journals (Sweden)

    Luíz Paulo Figueredo Benício

    2015-02-01

    Full Text Available The current research aims to introduce Layered Double Hydroxides (LDH as nanomaterials to be used in agriculture, with particular reference to its use as storage and slow release matrix of nutrients and agrochemicals for plant growing. Structural characteristics, main properties, synthesis methods and characterization of LDH were covered in this study. Moreover, some literature data have been reported to demonstrate their potential for storage and slow release of nitrate, phosphate, agrochemicals, besides as being used as adsorbent for the wastewater treatment. This research aims to expand, in near future, the investigation field on these materials, with application in agriculture, increasing the interface between chemistry and agronomy.

  18. Soil physics and agriculture

    International Nuclear Information System (INIS)

    The approach that integrates knowledge is very important in Agriculture, including farmers, extensionists, researchers and professors. The specialists, including the soil physicists, must have a global view of the crop production system. Therefore, their expertise can be useful for the society. The Essence of scientific knowledge is its practical application. The soil physics is a sub area of Agronomy. There are many examples of this specific subject related to Agriculture. This paper will focus, in general, the following cases: (i) erosion, environmental pollution and human health, (ii) plant population and distribution, soil fertility, evapo-transpiration and soil water flux density, and (iii) productivity, effective root depth, water deficit and yield

  19. Mathematical problems for chemistry students

    CERN Document Server

    Pota, Gyorgy

    2011-01-01

    Mathematical Problems for Chemistry Students has been compiled and written (a) to help chemistrystudents in their mathematical studies by providing them with mathematical problems really occurring in chemistry (b) to help practising chemists to activate their applied mathematical skills and (c) to introduce students and specialistsof the chemistry-related fields (physicists, mathematicians, biologists, etc.) intothe world of the chemical applications.Some problems of the collection are mathematical reformulations of those in the standard textbooks of chemistry, others we

  20. Conference 'Chemistry of hydrides' Proceedings

    International Nuclear Information System (INIS)

    This collection of thesis of conference of Chemistry hydrides presents the results of investigations concerning of base questions of chemistry of nonorganic hydrides, including synthesis questions, studying of physical and chemical properties, thermodynamics, analytical chemistry, investigation of structure, equilibriums in the systems of metal-hydrogen, behaviour of nonorganic hydrides in non-water mediums and applying investigations in the chemistry area and technology of nonorganic hydrides

  1. Predictors of General Chemistry Grades.

    Science.gov (United States)

    Ozsogomonyan, Ardas; Loftus, Drew

    1979-01-01

    Chemistry pretest scores, high school chemistry grades and, to a greater extent, math SAT scores were useful predictors of college general chemistry grades. Regression analysis of all these predictors combined was used to construct an expectancy table which is being used to identify and advise underprepared students. (BB)

  2. Division of Analytical Chemistry, 1998

    DEFF Research Database (Denmark)

    Hansen, Elo Harald

    1999-01-01

    The article recounts the 1998 activities of the Division of Analytical Chemistry (DAC- formerly the Working Party on Analytical Chemistry, WPAC), which body is a division of the Federation of European Chemical Societies (FECS). Elo Harald Hansen is the Danish delegate, representing The Danish...... Chemical Society/The Society for Analytical Chemistry....

  3. Combinatorial chemistry and the Grid

    OpenAIRE

    Frey, J G; Bradley, M.; Essex, J.W.; Hursthouse, M. B.; Lewis, S. M.; Luck, M.M.; Moreau, L; De Roure, D C; Surridge, M.; Welsh, A. H.

    2003-01-01

    Chemistry has always made extensive use of the developing computing technology and available computing power though activities such as modelling, simulation and chemical structure interpretational - activities conveniently summarised as computational chemistry. Developing procedures in chemical synthesis and characterisation, particularly in the arena of parallel and combinatorial methodology, have generated ever increasing demands on both Computational Chemistry and Computer Technology. Si...

  4. HMI scientific report - chemistry 1987

    International Nuclear Information System (INIS)

    Results of the R and D activities of the Radiation Chemistry Department, Hahn-Meitner-Institut, are reported, primarily dealing with the following subjects: Interface processes and energy conversion, high-energy photochemistry and radiation chemistry as well as trace elements chemistry. A list of publications and lectures is added and gives a view on results obtained in research and development. (EF)

  5. Annual report 1985 Chemistry Department

    International Nuclear Information System (INIS)

    This annual report describes the activities carried out in 1985 by the Chemistry Department in the following fields: Chemistry, Inorganic Chemistry, Physicochemistry (Interphases, Surfaces), General Chemical Analysis, Active Materials Analysis, X Ray Fluorescence Analysis, Mass Spectroscopy (Isotopic Analysis, Instrumentation) and Optical Spectroscopy. A list of publications is enclosed. (M.E.L.)

  6. Changing Structure of Turkish Agriculture

    OpenAIRE

    Mann, Charles K.

    1983-01-01

    Professor Resat Aktan, whose memory is honoured by this paper, occupied a unique place in the history of Turkish agriculture--teacher, scholar, Minister of Agriculture, and long-time Turkish delegate to the IAAE. Among his many accomplishments, he led two landmark agricultural surveys which serve to chronicle the development of modern Turkish agriculture. While Ataturk had set Turkey on the road to modernization of agriculture, the end of World War II still found Turkish wheat farming little ...

  7. Strategic analysis of Swedish agriculture

    OpenAIRE

    Fogelfors, Håkan; Wivstad, Maria; Eckersten, Henrik; Holstein, Fredrik; Johansson, Susanne; Verwijst, Theo

    2009-01-01

    This strategic analysis of Swedish agriculture – production systems and agricultural landscapes in a time of change – focuses on climate change, future availability of natural resources and economic regulation in a global food market. The background to the project was that the Faculty of Natural Resources and Agriculture of the Swedish University of Agricultural Sciences identified an urgent need to explore the implications and opportunities of coming changes for agricultural production syste...

  8. Agricultural Technology, Risk, and Gender

    DEFF Research Database (Denmark)

    Arndt, Channing; Tarp, Finn

    2000-01-01

    Interactions between agricultural technology improvements, risk-reducing behavior, and gender roles in agricultural production in Mozambique are examined. The analysis employs a computable general equilibrium (CGE) model that explicitly incorporates key features of the economy. These include......: detailed accounting of marketing margins, home consumption, risk, and gender roles in agricultural production. Our results show that agricultural technology improvements benefit both male and female occupants of rural households. Due to economic interactions, agricultural technology improvements...

  9. Cohabitation: Humans & Agriculture

    NARCIS (Netherlands)

    Woodington, W.

    2012-01-01

    This "designers' manual" is made during the TIDO-course AR0531 Smart & Bioclimatic Design. Cohabitation of humans and agriculture can be used to improve building climate, human health and the state of the world. It affects building design and requires new building components. This manual explains w

  10. Knowing Agricultural Biodiversity

    OpenAIRE

    Mulvany, P.

    2001-01-01

    The term "agricultural biodiversity" is relatively recent, perhaps post-CBD. Although, the specific nature of the biodiversity used by people was recognised for a long time, the overwhelming emphasis in the CBD was on general biodiversity, mainly 'wild' flora and fauna that inhabit this fragile biosphere in which people also live.

  11. Agriculture. Sheep Livestock.

    Science.gov (United States)

    Michigan State Univ., East Lansing. Coll. of Agriculture and Natural Resources Education Inst.

    This task-based curriculum guide for agricultural production, specifically for sheep, is intended to help the teacher develop a classroom management system where students learn by doing. Introductory materials include a Dictionary of Occupational Titles job code and title sheet, a task sheet for developing leadership skills, and a task list. Each…

  12. Scrapping Agricultural Tax

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    On March 5,in his government report to the annual session of the country's top legislature,the National People's Congress,Premier Wen Jiabao set the goal to reduce the agricultural tax rate by more than one percentage point each year,

  13. Agriculture and environmental pollution

    International Nuclear Information System (INIS)

    Agriculture came into existence about 15,000 years ago and passed through different stages of food gathering, hunting, hoe culture and sedentary agriculture followed by modem agriculture. It began simultaneously in five world centers concentrating on different crops, most suited to those areas. It was also effected by changes in climate influenced by temperature, drought and magnitude of precipitation, which determined the distribution of populations and occupation of the people. With the increase in population the need for food also progressively increased, necessitating introduction of modern agriculture to enhance production. The indiscriminate and faulty use of advanced technology has added its share in the, destruction of environment. The two approaches that contributed to this were horizontal wand vertical expansion. The former results in deforestation, desertification, soil erosion, land salting and water logging as well as the frequent occurrence of droughts and famines, the latter destroyed soil structure and fertility through decreased microbial populations, fish culture, wildlife and bird sanctuaries, in addition to hazards in human beings and fauna. The real culprit of this global devastation is the high population growth rate, which needs to be contained at safer levels, coupled with sensible use of inputs to produce needed quantities of food and fiber. (author)

  14. Community Supported Agriculture

    OpenAIRE

    Givens, Emily

    2009-01-01

    A report on the definition, history, production, membership and local benefits of community supported agriculture. Editor's note: the following article was written as a class assignment for Dr. Greg Welbaum's Vegetable Production course at Virginia Tech. Emily provides some good history and information on the CSA marketing option for specialty crop growers." "Originally printed in Virginia Vegetable, Small Fruit and Specialty Crops, June 2002

  15. Nanotechnology in Agriculture

    Science.gov (United States)

    An overview is given of the application of nanotechnology to agriculture. This is an active field of R&D, where a large number of findings and innovations have been reported. For example, in soil management, applications reported include nanofertilizers, soil binders, water retention aids, and nut...

  16. Goryachkin's agricultural mechanics

    Science.gov (United States)

    Chinenova, Vera

    2016-03-01

    The paper contributes to the development of applied mechanics by establishing a new discipline, namely, agricultural mechanics by academician Vasilii Prohorovich Goryachkin (1868-1935) who was an apprentice of Nikolay Yegorovich Zhukovsky and a graduate of the Moscow University (current known as Moscow State University) and the Imperial Higher Technical School.

  17. Agricultural Development in Zambia

    DEFF Research Database (Denmark)

    Jeppesen, Søren; Hampwaye, Godfrey; Phiri, Douglas

    Food processing is important to the Zambian economy and entails a set of options for local firms to grow and create employment given the growth potential the country possesses in agriculture. This policy brief summarizes the findings of a study of 38 Zambian owned firms in the food processing...

  18. Mexico Agriculture Policy Review

    OpenAIRE

    Cahill, Carmel; Jotanovic, Aleksandar; Abraham, Cally

    2008-01-01

    As a NAFTA partner and Canada's third largest export market for agri-food products, developments in Mexico are of direct interest to Canada. Rural poverty, low productivity, poor infrastructure and unclear property rights for both land and water still inhibit the efforts of Mexico's government to improve competitiveness of its agricultural sector.

  19. Agriculture, forestry, range resources

    Science.gov (United States)

    Macdonald, R. B.

    1974-01-01

    The necessary elements to perform global inventories of agriculture, forestry, and range resources are being brought together through the use of satellites, sensors, computers, mathematics, and phenomenology. Results of ERTS-1 applications in these areas, as well as soil mapping, are described.

  20. Agricultural nitrate pollution

    DEFF Research Database (Denmark)

    Anker, Helle Tegner

    2015-01-01

    Despite the passing of almost 25 years since the adoption of the EU Nitrates Directive, agricultural nitrate pollution remains a major concern in most EU Member States. This is also the case in Denmark, although a fairly strict regulatory regime has resulted in almost a 50 per cent reduction...

  1. Food and agriculture

    International Nuclear Information System (INIS)

    This chapter discussed the basic principles and techniques of nuclear science and technology applied in food and agricultural study. The following subjects covered: 1) Utilization of radiation in plant breeding, pest control, food irradiation, moisture content, food contamination study; 2) Utilization of radioisotopes in soil and plant studies, animal research

  2. Salary-Trend Studies of Faculty for the Years 1985-86 and 1988-89 in the Following Disciplines/Major Fields: Accounting; Agricultural Production; Anthropology; Architecture and Environmental Design; Area and Ethnic Studies; Audiology and Speech Pathology; Business Administration and Management; Business and Management; Business Economics; Chemistry; Communication Technologies; Communications; Computer and Information Sciences; Curriculum and Instruction; and Dramatic Arts.

    Science.gov (United States)

    Howe, Richard D.; And Others

    This volume provides comparative data for faculty salaries in public and private colleges, based on an annual survey of over 700 colleges and universities. Data cover the following 15 disciplines: accounting, agribusiness and agricultural production, anthropology, architecture and environmental design, area and ethnic studies, audiology and speech…

  3. Carbohydrates in Supramolecular Chemistry.

    Science.gov (United States)

    Delbianco, Martina; Bharate, Priya; Varela-Aramburu, Silvia; Seeberger, Peter H

    2016-02-24

    Carbohydrates are involved in a variety of biological processes. The ability of sugars to form a large number of hydrogen bonds has made them important components for supramolecular chemistry. We discuss recent advances in the use of carbohydrates in supramolecular chemistry and reveal that carbohydrates are useful building blocks for the stabilization of complex architectures. Systems are presented according to the scaffold that supports the glyco-conjugate: organic macrocycles, dendrimers, nanomaterials, and polymers are considered. Glyco-conjugates can form host-guest complexes, and can self-assemble by using carbohydrate-carbohydrate interactions and other weak interactions such as π-π interactions. Finally, complex supramolecular architectures based on carbohydrate-protein interactions are discussed. PMID:26702928

  4. Radiation chemistry of oils

    International Nuclear Information System (INIS)

    Full text : Primary investigations have been conducted at the end of the 1950th years in the area of radiation chemistry of the oils, the physical-chemical properties of crude oil have been investigated the influence of ionizing rays. This report by M. Malikzadeh is about the results of investigations carried out in the field of development of radiation chemistry. The power of the radiation dose and temperature-thermal effect of the collapse of Phentadekan -Oil, and oil fractions (200-400 degrees Celsium, 230-310 degrees Celsium) of radiation-thermal separation of olefins - Conversion of hydrogen from the transormation of black oil, bitumen and tar Kinetics of the above-mentioned processes was studied, the technical-economic indicators of the products were determined

  5. Medicinal chemistry for 2020.

    Science.gov (United States)

    Satyanarayanajois, Seetharama D; Hill, Ronald A

    2011-10-01

    Rapid advances in our collective understanding of biomolecular structure and, in concert, of biochemical systems, coupled with developments in computational methods, have massively impacted the field of medicinal chemistry over the past two decades, with even greater changes appearing on the horizon. In this perspective, we endeavor to profile some of the most prominent determinants of change and speculate as to further evolution that may consequently occur during the next decade. The five main angles to be addressed are: protein-protein interactions; peptides and peptidomimetics; molecular diversity and pharmacological space; molecular pharmacodynamics (significance, potential and challenges); and early-stage clinical efficacy and safety. We then consider, in light of these, the future of medicinal chemistry and the educational preparation that will be required for future medicinal chemists. PMID:22004084

  6. Aqueous chemistry of iodine

    International Nuclear Information System (INIS)

    The chemistry of iodine has been examined in aqueous solutions of pH 6 to 10 containing 2500 ppM boron as H3BO3 at temperatures up to 1500C using absorption spectrophotometry to identify and monitor the iodine species present. Kinetic rate constants for the disproportionation of the HOI intermediate, 3HOI= IO3- + 2I- + 3H+, have been measured as a function of pH even though no direct spectral evidence for HOI itself has been observed. An HOI partition coefficient >104 has been estimated; results of ionic strength tests are consistent with HOI being present as an uncharged triatomic species in solution. Redox and radiation effects on the aqueous iodine chemistry have also been described. 11 refs., 2 figs., 3 tabs

  7. Chemistry space–time

    Directory of Open Access Journals (Sweden)

    David A. Winkler

    2015-12-01

    Full Text Available As Einstein identified so clearly, space and time are intimately related. We discuss the relationship between time and Euclidean space using spectroscopic and radioastronomical studies of interstellar chemistry as an example. Given the finite speed of light, we are clearly studying chemical reactions occurring tens of thousands of years ago that may elucidate the primordial chemistry of this planet several billion years ago. We also explore space of a different kind – chemical space, with many more dimensions than the four we associate as space–time. Vast chemical spaces also need very efficient (computational methods for their exploration to overcome this ‘curse of dimensionality’. We discuss methods by which the time to explore these new spaces can be very substantially reduced, opening the discovery useful new materials that are the key to our future.

  8. Heterogeneous atmospheric chemistry

    Science.gov (United States)

    Schryer, D. R.

    1982-01-01

    The present conference on heterogeneous atmospheric chemistry considers such topics concerning clusters, particles and microparticles as common problems in nucleation and growth, chemical kinetics, and catalysis, chemical reactions with aerosols, electron beam studies of natural and anthropogenic microparticles, and structural studies employing molecular beam techniques, as well as such gas-solid interaction topics as photoassisted reactions, catalyzed photolysis, and heterogeneous catalysis. Also discussed are sulfur dioxide absorption, oxidation, and oxidation inhibition in falling drops, sulfur dioxide/water equilibria, the evidence for heterogeneous catalysis in the atmosphere, the importance of heterogeneous processes to tropospheric chemistry, soot-catalyzed atmospheric reactions, and the concentrations and mechanisms of formation of sulfate in the atmospheric boundary layer.

  9. Organic Chemistry in Space

    Science.gov (United States)

    Charnley, Steven

    2009-01-01

    Astronomical observations, theoretical modeling, laboratory simulation and analysis of extraterrestrial material have enhanced our knowledge of the inventory of organic matter in the interstellar medium (ISM) and on small bodies such as comets and asteroids (Ehrenfreund & Charnley 2000). Comets, asteroids and their fragments, meteorites and interplanetary dust particles (IDPs), contributed significant amounts of extraterrestrial organic matter to the young Earth. This material degraded and reacted in a terrestrial prebiotic chemistry to form organic structures that may have served as building blocks for life on the early Earth. In this talk I will summarize our current understanding of the organic composition and chemistry of interstellar clouds. Molecules of astrobiological relevance include the building blocks of our genetic material: nucleic acids, composed of subunits such as N-heterocycles (purines and pyrimidines), sugars and amino acids. Signatures indicative of inheritance of pristine and modified interstellar material in comets and meteorites will also be discussed.

  10. Quo vadis, analytical chemistry?

    Science.gov (United States)

    Valcárcel, Miguel

    2016-01-01

    This paper presents an open, personal, fresh approach to the future of Analytical Chemistry in the context of the deep changes Science and Technology are anticipated to experience. Its main aim is to challenge young analytical chemists because the future of our scientific discipline is in their hands. A description of not completely accurate overall conceptions of our discipline, both past and present, to be avoided is followed by a flexible, integral definition of Analytical Chemistry and its cornerstones (viz., aims and objectives, quality trade-offs, the third basic analytical reference, the information hierarchy, social responsibility, independent research, transfer of knowledge and technology, interfaces to other scientific-technical disciplines, and well-oriented education). Obsolete paradigms, and more accurate general and specific that can be expected to provide the framework for our discipline in the coming years are described. Finally, the three possible responses of analytical chemists to the proposed changes in our discipline are discussed. PMID:26631024

  11. Supramolecular chemistry and technology

    Directory of Open Access Journals (Sweden)

    HENRIQUE E. TOMA

    2000-03-01

    Full Text Available Supramolecular chemistry deals with the association of several chemical species, in an organized way and according to well defined purposes. Based on a molecular engineering approach, supramolecular structures can be designed from pre-formed building blocks, providing a promising route from chemistry to molecular nanotechnology. New supramolecular systems have been assembled in our laboratory with the use of bridging unities such as tetrapyridylporphyrins, porphyrazines and polypyrazines, connecting transition metal complexes and clusters. These systems display a very exciting electrochemical and catalytic behavior, and interact with DNA, generating ¹O2 and leading to efficient oxidative clivage for photodynamic terapy applications. Molecular interfaces have been developed, exhibiting photocurrent response in the presence of visible-UV light, and rectifying properties in the presence of electroactive species. Successful applications of the supramolecular species in chemical and bio-sensors have been developed.

  12. Muons in chemistry

    Science.gov (United States)

    Clayden, N. J.

    2013-12-01

    Positive muons have long been used as extrinsic probes in chemistry, offering unique properties for the investigation of local magnetism, dynamics, transport and radical kinetics. Exciting new developments in muon beam lines offer the opportunity of extending these studies selectively to surfaces permitting, for example, the detection of increased mobility of polymer chains at the surface of a polymer film. So called pump and probe methods, involving external perturbations by laser irradiation to manipulate vibrational and electronic states, can be followed by muon pulses allowing the probing of the properties of these states. Muoniated radical probes are finding greater use in soft matter. Selectivity is achieved in these complex systems through an appropriate target molecule giving the chance to measure partitioning and interfacial transfer in surfactant systems. Improvements in sample environments allow the observation of muons in increasingly extreme combinations of temperature and pressure, such as supercritical water, allowing the characterization of the chemistry in these systems.

  13. Solvents and sustainable chemistry

    OpenAIRE

    Welton, Tom

    2015-01-01

    Solvents are widely recognized to be of great environmental concern. The reduction of their use is one of the most important aims of green chemistry. In addition to this, the appropriate selection of solvent for a process can greatly improve the sustainability of a chemical production process. There has also been extensive research into the application of so-called green solvents, such as ionic liquids and supercritical fluids. However, most examples of solvent technologies that give improved...

  14. Chemistry of sex attraction.

    OpenAIRE

    Roelofs, W L

    1995-01-01

    The chemical communication system used to attract mates involves not only the overt chemical signals but also indirectly a great deal of chemistry in the emitter and receiver. As an example, in emitting female moths, this includes enzymes (and cofactors, mRNA, genes) of the pheromone biosynthetic pathways, hormones (and genes) involved in controlling pheromone production, receptors and second messengers for the hormones, and host plant cues that control release of the hormone. In receiving ma...

  15. Current ADC Linker Chemistry

    OpenAIRE

    Jain, Nareshkumar; Smith, Sean W.; Ghone, Sanjeevani; Tomczuk, Bruce

    2015-01-01

    The list of ADCs in the clinic continues to grow, bolstered by the success of first two marketed ADCs: ADCETRIS® and Kadcyla®. Currently, there are 40 ADCs in various phases of clinical development. However, only 34 of these have published their structures. Of the 34 disclosed structures, 24 of them use a linkage to the thiol of cysteines on the monoclonal antibody. The remaining 10 candidates utilize chemistry to surface lysines of the antibody. Due to the inherent heterogeneity of conjugati...

  16. Advances in electroanalytical chemistry

    OpenAIRE

    Wang, Yijun; Compton, Richard

    2012-01-01

    This thesis concerns several advances in electroanalytical chemistry which are separated into four parts: the electrochemical investigation of diffusional behaviour, the mechanistic and kinetic study of electrochemistry with room temperature ionic liquids (RTILs), the study of weakly-supported electrochemistry and a comparison of the Butler-Volmer and Marcus-Hush kinetic theories of electron transfer. A study of the diffusional behaviour of electroactive species is essential for further s...

  17. Art and Chemistry

    OpenAIRE

    Walter, Philippe

    2015-01-01

    Philippe Walter’s teaching, which he delivered as holder of the Liliane Bettencourt Annual Chair of Technological Innovation, was completed with two lectures on “practical work” to deal with a real case. The conditions and challenges of interdisciplinary research combining analytical chemistry, art history and archaeology were thus discussed in relation to specific works. The Holy Family, Constantin Abraham (1785-1855) by Raphaël (aka), Sanzio Raffaello (1483-1520), hard porcelain, Sèvres, C...

  18. Chemistry of silybin

    Czech Academy of Sciences Publication Activity Database

    Biedermann, David; Vavříková, Eva; Cvak, L.; Křen, Vladimír

    2014-01-01

    Roč. 31, č. 9 (2014), s. 1138-1157. ISSN 0265-0568 R&D Projects: GA ČR(CZ) GAP301/11/0662; GA MŠk LH13097; GA MŠk(CZ) LD14096; GA MŠk(CZ) LD13042 Institutional support: RVO:61388971 Keywords : silybin * Silybum marianum * separation Subject RIV: CC - Organic Chemistry Impact factor: 10.107, year: 2014

  19. Medicinal chemistry for 2020

    OpenAIRE

    Satyanarayanajois, Seetharama D.; Hill, Ronald A

    2011-01-01

    Rapid advances in our collective understanding of biomolecular structure and, in concert, of biochemical systems, coupled with developments in computational methods, have massively impacted the field of medicinal chemistry over the past two decades, with even greater changes appearing on the horizon. In this perspective, we endeavor to profile some of the most prominent determinants of change and speculate as to further evolution that may consequently occur during the next decade. The five ma...

  20. Learning Chemistry from Bacteria

    OpenAIRE

    Clardy, Jon

    2013-01-01

    Dr. Jon Clardy Department of Biological Chemistry and Molecular Pharmacology, Harvard Medical School, Harvard University All animals, including humans, originated and evolved on a planet already teeming with bacteria, and the two kingdoms of life have been competing and cooperating through their joint history. Although bacteria are most familiar as pathogens, some bacteria produce small molecules that are essential for the biology of animals and other eukaryotes. This lecture explores some of...

  1. Radioanalytical chemistry in Denmark

    International Nuclear Information System (INIS)

    Publications from Denmark in the field of radioanalytical chemistry are presented in 2 groups, one involving neutron activation and similar techniques, and one for other radioanalytical work. Altogether 258 references including books are given for the period 1936-1977, and the overall doubling time is 5.2 years. A significant deviation from a purely exponential growth was caused by the Second World War. (author)

  2. Actinide separative chemistry

    International Nuclear Information System (INIS)

    Actinide separative chemistry has focused very heavy work during the last decades. The main was nuclear spent fuel reprocessing: solvent extraction processes appeared quickly a suitable, an efficient way to recover major actinides (uranium and plutonium), and an extensive research, concerning both process chemistry and chemical engineering technologies, allowed the industrial development in this field. We can observe for about half a century a succession of Purex plants which, if based on the same initial discovery (i.e. the outstanding properties of a molecule, the famous TBP), present huge improvements at each step, for a large part due to an increased mastery of the mechanisms involved. And actinide separation should still focus R and D in the near future: there is a real, an important need for this, even if reprocessing may appear as a mature industry. We can present three main reasons for this. First, actinide recycling appear as a key-issue for future nuclear fuel cycles, both for waste management optimization and for conservation of natural resource; and the need concerns not only major actinide but also so-called minor ones, thus enlarging the scope of the investigation. Second, extraction processes are not well mastered at microscopic scale: there is a real, great lack in fundamental knowledge, useful or even necessary for process optimization (for instance, how to design the best extracting molecule, taken into account the several notifications and constraints, from selectivity to radiolytic resistivity?); and such a need for a real optimization is to be more accurate with the search of always cheaper, cleaner processes. And then, there is room too for exploratory research, on new concepts-perhaps for processing quite new fuels- which could appear attractive and justify further developments to be properly assessed: pyro-processes first, but also others, like chemistry in 'extreme' or 'unusual' conditions (supercritical solvents, sono-chemistry, could be

  3. Quantum mechanics in chemistry

    CERN Document Server

    Schatz, George C

    2002-01-01

    Intended for graduate and advanced undergraduate students, this text explores quantum mechanical techniques from the viewpoint of chemistry and materials science. Dynamics, symmetry, and formalism are emphasized. An initial review of basic concepts from introductory quantum mechanics is followed by chapters examining symmetry, rotations, and angular momentum addition. Chapter 4 introduces the basic formalism of time-dependent quantum mechanics, emphasizing time-dependent perturbation theory and Fermi's golden rule. Chapter 5 sees this formalism applied to the interaction of radiation and matt

  4. Chemistry in Bioinformatics

    OpenAIRE

    Mitchell John; Murray-Rust Peter; Rzepa Henry

    2005-01-01

    Abstract Chemical information is now seen as critical for most areas of life sciences. But unlike Bioinformatics, where data is openly available and freely re-usable, most chemical information is closed and cannot be re-distributed without permission. This has led to a failure to adopt modern informatics and software techniques and therefore paucity of chemistry in bioinformatics. New technology, however, offers the hope of making chemical data (compounds and properties) free during the auth...

  5. Food chemistry. 2. ed.

    International Nuclear Information System (INIS)

    This second edition of the textbook deals with all essential aspects of food chemistry. The revision improved in particular the chapters on food preservation, including irradiation of food, food additives, and pollutants and residues, including radionuclides. The chapter on the German legal regime for foodstuffs has been updated to cover the recent amendments of the law, and the information on processes applied in food technology has been largely enhanced. (VHE) With 153 figs., 78 tabs

  6. Green chemistry: development trajectory

    International Nuclear Information System (INIS)

    Examples of applications of green chemistry methods in heavy organic synthesis are analyzed. Compounds, which can be produced by the processing of the biomass, and the criteria for the selection of the most promising products are summarized. The current status of the ethanol production and processing is considered. The possibilities of the use of high fatty acid triglycerides, glycerol, succinic acid, and isoprene are briefly discussed. The bibliography includes 67 references

  7. Green chemistry: development trajectory

    Science.gov (United States)

    Moiseev, I. I.

    2013-07-01

    Examples of applications of green chemistry methods in heavy organic synthesis are analyzed. Compounds, which can be produced by the processing of the biomass, and the criteria for the selection of the most promising products are summarized. The current status of the ethanol production and processing is considered. The possibilities of the use of high fatty acid triglycerides, glycerol, succinic acid, and isoprene are briefly discussed. The bibliography includes 67 references.

  8. Atmospheric pseudohalogen chemistry

    Directory of Open Access Journals (Sweden)

    D. J. Lary

    2004-09-01

    Full Text Available There are at least three reasons why hydrogen cyanide is likely to be significant for atmospheric chemistry. The first is well known, HCN is a product and marker of biomass burning. However, if a detailed ion chemistry of lightning is considered then it is almost certain than in addition to lightning producing NOx, it also produces HOx and HCN. Unlike NOx and HOx, HCN is long-lived and could therefore be a useful marker of lightning activity. Observational evidence is considered to support this view. Thirdly, the chemical decomposition of HCN leads to the production of small amounts of CN and NCO. NCO can be photolyzed in the visible portion of the spectrum yielding N atoms. The production of N atoms is significant as it leads to the titration of nitrogen from the atmosphere via N+N→N2. Normally the only modelled source of N atoms is NO photolysis which happens largely in the UV Schumann-Runge bands. However, NCO photolysis occurs in the visible and so could be involved in titration of atmospheric nitrogen in the lower stratosphere and troposphere. HCN emission inventories are worthy of attention. The CN and NCO radicals have been termed pseudohalogens since the 1920s. They are strongly bound, univalent, radicals with an extensive and varied chemistry. The products of the atmospheric oxidation of HCN are NO, CO and O3. N+CH4 and N+CH3OH are found to be important sources of HCN. Including the pseudohalogen chemistry gives a small increase in ozone and total reactive nitrogen (NOy.

  9. Green Chemistry for Nanotechnology: Opportunities and Future Challenges

    OpenAIRE

    Preeti Nigam Joshi

    2016-01-01

    Nanotechnology is a paradigm for emerging technologies and much talked about area of science. It is the technology of future and has revolutionized all fields of medicine, agriculture, environmental and electronics by providing abilities that would never have previously dreamt of. It is a unique platform of multidisciplinary approaches integrating diverse fields of engineering, biology, physics and chemistry. In recent years, nanotechnology has seen the fastest pace in its all aspects of synt...

  10. Chemistry of superheavy elements

    Energy Technology Data Exchange (ETDEWEB)

    Schaedel, M. [Japan Atomic Energy Agency, Tokai, Ibaraki (Japan). Advanced Science Research Center; GSI Helmholtz Center for Heavy Ion Research, Darmstadt (Germany)

    2012-07-01

    The chemistry of superheavy elements - or transactinides from their position in the Periodic Table - is summarized. After giving an overview over historical developments, nuclear aspects about synthesis of neutron-rich isotopes of these elements, produced in hot-fusion reactions, and their nuclear decay properties are briefly mentioned. Specific requirements to cope with the one-atom-at-a-time situation in automated chemical separations and recent developments in aqueous-phase and gas-phase chemistry are presented. Exciting, current developments, first applications, and future prospects of chemical separations behind physical recoil separators ('pre-separator') are discussed in detail. The status of our current knowledge about the chemistry of rutherfordium (Rf, element 104), dubnium (Db, element 105), seaborgium (Sg, element 106), bohrium (Bh, element 107), hassium (Hs, element 108), copernicium (Cn, element 112), and element 114 is discussed from an experimental point of view. Recent results are emphasized and compared with empirical extrapolations and with fully-relativistic theoretical calculations, especially also under the aspect of the architecture of the Periodic Table. (orig.)

  11. Chemistry of superheavy elements

    International Nuclear Information System (INIS)

    The chemistry of superheavy elements - or transactinides from their position in the Periodic Table - is summarized. After giving an overview over historical developments, nuclear aspects about synthesis of neutron-rich isotopes of these elements, produced in hot-fusion reactions, and their nuclear decay properties are briefly mentioned. Specific requirements to cope with the one-atom-at-a-time situation in automated chemical separations and recent developments in aqueous-phase and gas-phase chemistry are presented. Exciting, current developments, first applications, and future prospects of chemical separations behind physical recoil separators ('pre-separator') are discussed in detail. The status of our current knowledge about the chemistry of rutherfordium (Rf, element 104), dubnium (Db, element 105), seaborgium (Sg, element 106), bohrium (Bh, element 107), hassium (Hs, element 108), copernicium (Cn, element 112), and element 114 is discussed from an experimental point of view. Recent results are emphasized and compared with empirical extrapolations and with fully-relativistic theoretical calculations, especially also under the aspect of the architecture of the Periodic Table. (orig.)

  12. BWR chromium chemistry

    International Nuclear Information System (INIS)

    This report addresses the concern about higher total specific conductivity in the reactor recirculation loop water due to the chromate ion. This concern is particularly high at plants where all other ionic species have been reduced through careful attention to makeup and condensate polisher operations. An EPRI Chromate Workshop was held in November 1990 to consider the issues raised by observed levels of chromate ion (generally 5 to 50 ppB). While BWRs on normal water chemistry were the only ones observing chromate, even plants on hydrogen water chemistry (HWC) observe sharp spikes of conductivity due to chromate whenever the hydrogen supply was interrupted after a reasonably long HWC operational period. The consensus of the workshop attendees was that chromate was not a concern as an agent causing pipe cracking compared to the more common species such as chloride and sulfate. However, the data are somewhat ambiguous for levels of chromate above 50 ppB. Adjustments to the weighing factors for the various ionic species in the industry chemistry performance index are suggested to allow for the known relative higher aggressiveness of other species relative to that of chromate

  13. Indian Agricultural Marketing- A Review

    Directory of Open Access Journals (Sweden)

    Shakeel-Ul-Rehman

    2012-03-01

    Full Text Available Agriculture in India has directly or indirectly continued to be the source of livelihood to majority of the population. Indian agriculture has seen a lot of changes in its structure. India, predominantly an agricultural economy, has healthy signs of transformation in agriculture and allied activities. India has seen agriculture as a precious tool of economic development as other sectors of production depend on it. Efficient backward and forward integration with agriculture has led to globally competitive production system in terms of cost and quality. Cooperatives seem to be well positioned to coordinate product differentiation at the farm level and to integrate forward into value added processing activities.. Indian agriculture can be balanced and made efficient through proper and better management practices. The present study brings out past and present scenario of agricultural marketing prevailing in India, its challenges and future recommendations. Moreover the opportunities provide by agricultural marketing should be tapped effectively by the marketers.

  14. Researches on Agricultural Cooperative Economic Organization Promoting Agricultural Insurance Development

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    The advantages of cooperative economic organization being the effective carrier of agricultural insurance development are analyzed. Firstly, cooperative economic organization promotes scale management and solves the problem of decentralized operation of small households. Secondly, cooperative economic organization can settle the problem of peasants’ low systematization. Thirdly, cooperative economic organization can largely reduce the costs of agricultural insurance operation. Fourthly, cooperative organization decreases moral risks as well as adverse selection to some extent. Lastly, cooperative organization, to a certain degree, reduces the risks of agricultural production and increases the insurability of agricultural risks. Meanwhile, limitations of agricultural cooperative economic organization being the carrier of agricultural insurance operation are pointed out. Firstly, cooperative economic organization has limited coverage and small size of organization, which is harmful to the diversification of agricultural risks. Secondly, cooperative economic organization lacks capital funds and its development is not standard, which is not perfect for the function exertion as a carrier. Lastly, members of professional cooperative organization have low cultural qualities, which restrict the implementation of agricultural insurance. The modes of farmers’ cooperative economic organization promoting agricultural insurance development are proposed, including mode of agricultural insurance cooperative ( mutual corporation), mode of "leading enterprises (companies) + professional cooperative organization (planting majors) + insurance" and mode of professional cooperatives serving as agricultural insurance agent. Last of all, the promoting role of agricultural insurance in agricultural cooperative economic organization is briefly illustrated.

  15. Allicin: Chemistry and Biological Properties

    Directory of Open Access Journals (Sweden)

    Jan Borlinghaus

    2014-08-01

    Full Text Available Allicin (diallylthiosulfinate is a defence molecule from garlic (Allium sativum L. with a broad range of biological activities. Allicin is produced upon tissue damage from the non-proteinogenic amino acid alliin (S-allylcysteine sulfoxide in a reaction that is catalyzed by the enzyme alliinase. Current understanding of the allicin biosynthetic pathway will be presented in this review. Being a thiosulfinate, allicin is a reactive sulfur species (RSS and undergoes a redox-reaction with thiol groups in glutathione and proteins that is thought to be essential for its biological activity. Allicin is physiologically active in microbial, plant and mammalian cells. In a dose-dependent manner allicin can inhibit the proliferation of both bacteria and fungi or kill cells outright, including antibiotic-resistant strains like methicillin-resistant Staphylococcus aureus (MRSA. Furthermore, in mammalian cell lines, including cancer cells, allicin induces cell-death and inhibits cell proliferation. In plants allicin inhibits seed germination and attenuates root-development. The majority of allicin’s effects are believed to be mediated via redox-dependent mechanisms. In sub-lethal concentrations, allicin has a variety of health-promoting properties, for example cholesterol- and blood pressure-lowering effects that are advantageous for the cardio-vascular system. Clearly, allicin has wide-ranging and interesting applications in medicine and (green agriculture, hence the detailed discussion of its enormous potential in this review. Taken together, allicin is a fascinating biologically active compound whose properties are a direct consequence of the molecule’s chemistry.

  16. General chemistry students' understanding of the chemistry underlying climate science

    Science.gov (United States)

    Versprille, Ashley N.

    The purpose of this study is to investigate first-semester general chemistry students' understanding of the chemistry underlying climate change. The first part of this study involves the collection of qualitative data from twenty-four first-semester general chemistry students from a large Midwestern research institution. The semi-structured interview protocol was developed based on alternative conceptions identified in the research literature and the essential principles of climate change outlined in the U.S. Climate Change Science Program (CCSP) document which pertain to chemistry (CCSP, 2003). The analysis and findings from the interviews indicate conceptual difficulties for students, both with basic climate literacy and underlying chemistry concepts. Students seem to confuse the greenhouse effect, global warming, and the ozone layer, and in terms of chemistry concepts, they lack a particulate level understanding of greenhouse gases and their interaction with electromagnetic radiation, causing them to not fully conceptualize the greenhouse effect and climate change. Based on the findings from these interviews, a Chemistry of Climate Science Diagnostic Instrument (CCSI) was developed for use in courses that teach chemistry with a rich context such as climate science. The CCSI is designed for professors who want to teach general chemistry, while also addressing core climate literacy principles. It will help professors examine their students' prior knowledge and alternative conceptions of the chemistry concepts associated with climate science, which could then inform their teaching and instruction.

  17. Heterogeneous Chemistry in Global Chemistry Transport Models

    Science.gov (United States)

    Stadtler, Scarlet; Simpson, David; Schultz, Martin; Bott, Andreas

    2016-04-01

    The impact of six tropospheric heterogeneous reactions on ozone and nitrogen species was studied using two chemical transport models EMEP MSC-W and ECHAM6-HAMMOZ. Since heterogeneous reactions depend on reactant concentrations (in this study these are N_2O_5, NO_3, NO_2, O_3, HNO_3, HO_2) and aerosol surface area S_a, the modeled surface area of both models was compared to a satellite product retrieving the surface area. This comparison shows a good agreement in global pattern and especially the capability of both models to capture the extreme aerosol loadings in East Asia. Further, the impact of the heterogeneous reactions was evaluated by the simulation of a reference run containing all heterogeneous reactions and several sensitivity runs. One reaction was turned off in each sensitivity run to compare it with the reference run. As previously shown, the analysis of the sensitivity runs shows that the globally most important heterogeneous reaction is the one of N_2O_5. Nevertheless, NO_2, NO_3, HNO3 and HO2 heterogeneous reactions gain relevance particular in East China due to presence of high NOx concentrations and high Sa in the same region. The heterogeneous reaction of O3 itself on dust is compared to the other heterogeneous reactions of minor relevance. Evaluation of the models with northern hemispheric ozone surface observations yields a better agreement of the models with observations when the heterogeneous reactions are incorporated. Impacts of emission changes on the importance of the heterogeneous chemistry will be discussed.

  18. The rise of Brazilian agriculture

    DEFF Research Database (Denmark)

    Jensen, Hans Grinsted; Vink, Nick; Sandrey, Ron

    2014-01-01

    The purpose of this article is to explore some of the possible lessons for South African agriculture from the Brazilian experience. To this end, the article discusses the performance of Brazilian agriculture in terms of land and labour use, production, and exports. This is followed by aspects of...... Brazilian agricultural policies, namely farmer support, the research and technology transfer system and land issues. The implications for South African agriculture can be summarized as the recognition that history, geography, the development path and agricultural policies all matter. The article then...... identifies five important lessons for agricultural development in South Africa....

  19. Agroecology and Sustainable Agriculture

    Directory of Open Access Journals (Sweden)

    Fabio Caporali

    Full Text Available In the framework of the 16th National Meeting of the Italian Ecological Society (“Global Change, Ecological Diversity and Sustainability”, University of Tuscia, Viterbo, 19-22 September 2006, a symposium was devoted to “Agroecology and Sustainable Development”. A major goal of this symposium was to contribute to keeping the dialogue among the experts of the various disciplines alive. Sustainability of agriculture is a challenge for society world wide. Universities and society as a whole have a responsibility in re-examining current perception of nature, of the world and of human society in the light of natural resources depletion, increasing pollution and social inequalities. The urgency to address sustainability issues is increasingly being reflected in the manner in which institutions of higher education around the world are giving priority to the teaching, research and practice of sustainability. The University of Tuscia is involved in international initiatives concerning teaching and research in Agroecology and Sustainable Agriculture.

  20. Agroecology and Sustainable Agriculture

    Directory of Open Access Journals (Sweden)

    Fabio Caporali

    2011-02-01

    Full Text Available In the framework of the 16th National Meeting of the Italian Ecological Society (“Global Change, Ecological Diversity and Sustainability”, University of Tuscia, Viterbo, 19-22 September 2006, a symposium was devoted to “Agroecology and Sustainable Development”. A major goal of this symposium was to contribute to keeping the dialogue among the experts of the various disciplines alive. Sustainability of agriculture is a challenge for society world wide. Universities and society as a whole have a responsibility in re-examining current perception of nature, of the world and of human society in the light of natural resources depletion, increasing pollution and social inequalities. The urgency to address sustainability issues is increasingly being reflected in the manner in which institutions of higher education around the world are giving priority to the teaching, research and practice of sustainability. The University of Tuscia is involved in international initiatives concerning teaching and research in Agroecology and Sustainable Agriculture.

  1. Poll Tax in Agriculture

    Directory of Open Access Journals (Sweden)

    Marina Luminita Sarbovan

    2011-10-01

    Full Text Available Under the crisis constrains, the Romanian government tries to balance the budget, to stop the inflation and decrease unemployment, but its financial possibilities to do so prove to be much smaller than necessary. As far as agriculture is concerned, because of the strong connection of this branch to the European rural mechanism, the state intervention plays the key role in the protection and promoting the national production, in competition with other global producers. The taxation system still owes unexpected effects, influences the prices for the animal and vegetal production, the sales and the profits of this branch, in the context of included fluctuating profit particularities. Is poll tax a possibility or a necessity for agriculture?

  2. Agricultural application of radioisotopes

    International Nuclear Information System (INIS)

    The radiations and isotopic tracers laboratory (R.I.T.L.) is duly approved B-class laboratory for handling radioactivity and functions as a central research facility of our university which has played a very significant role in ushering green revolution in the country. Radiolabelled fertilizers, insecticides and isotopes mostly supplied by Board of Radiation and Isotope Technology, (BRIT) Department of Atomic Energy (DAE) are being used in our university for the last three decades to study the uptake of fertilizers, micro nutrients, photosynthesis and photorespiration studies in different crop plants, soil-water-plant relations and roots activity, pesticides and herbicides mode of action, plants physiology and microbiology. Main emphasis of research so far has been concentrated on the agricultural productivity. The present talk is an attempt to highlight the enormous potential of radioisotopes to evolve better management of crop system for eco-friendly and sustainable agriculture in the next century. (author)

  3. Advanced Agriculture system

    Directory of Open Access Journals (Sweden)

    Shrinivas R. Zanwar

    2012-05-01

    Full Text Available This article addresses the advanced system which improves agriculture processes like cultivation on ploughed land, based on robotic platform. We have developed a robotic vehicle having four wheels and steered by DC motor. The advanced autonomous system architecture gives us the opportunity to develop a complete new range of agricultural equipment based on small smart machines. The machine will cultivate the farm by considering particular rows and specific column at fixed distance depending on crop. The obstacle detection problem will also be considered, sensed by infrared sensor. The whole algorithm, calculation, processing, monitoring are designed with motors & sensor interfaced with microcontroller. The result obtained through example activation unit is also presented. The dc motor simulation with feedforward and feedback technique shows precise output. With the help of two examples, a DC motor and a magnetic levitation system, the use of MATLAB and Simulink for modeling, analysis and control is designed.

  4. Water pollution by agriculture

    OpenAIRE

    Moss, Brian

    2007-01-01

    Agriculture disrupts all freshwater systems hugely from their pristine states. The former reductionist concept of pollution was of examining individual effects of particular substances on individual taxa or sub-communities in freshwater systems, an essentially ecotoxicological concept. It is now less useful than a more holistic approach that treats the impacts on the system as a whole and includes physical impacts such as drainage and physical modification of river channels and modification o...

  5. Agriculture and climate change

    International Nuclear Information System (INIS)

    How will increases in levels of CO2 and changes in temperature affect food production? A recently issued report analyzes prospects for US agriculture 1990 to 2030. The report, prepared by a distinguished Task Force, first projects the evolution of agriculture assuming increased levels of CO2 but no climate change. Then it deals with effects of climate change, followed by a discussion of how greenhouse emissions might be diminished by agriculture. Economic and policy matters are also covered. How the climate would respond to more greenhouse gases is uncertain. If temperatures were higher, there would be more evaporation and more precipitation. Where would the rain fall? That is a good question. Weather in a particular locality is not determined by global averages. The Dust Bowl of the 1930s could be repeated at its former site or located in another region such as the present Corn Belt. But depending on the realities at a given place, farmers have demonstrated great flexibility in choosing what they may grow. Their flexibility has been increased by the numerous varieties of seeds of major crops that are now available, each having different characteristics such as drought resistance and temperature tolerance. In past, agriculture has contributed about 5% of US greenhouse gases. Two large components have involved emissions of CO2 from farm machinery and from oxidation of organic matter in soil due to tillage. Use of diesel fuel and more efficient machinery has reduced emissions from that source by 40%. In some areas changed tillage practices are now responsible for returning carbon to the soil. The report identifies an important potential for diminishing net US emissions of CO2 by growth and utilization of biomass. Large areas are already available that could be devoted to energy crops

  6. Isotopes and agriculture

    International Nuclear Information System (INIS)

    The agriculture is defined as the art of desturbing the ecosystems in economical terms with the minimum of irreversible damage. Man survival in the biosphere will depend on its ability of using four technologies - mechanization, fertilizers, irrigation and pest disease control. The isotopes are usefull to establish means of producing more food and to preserve it; and clains of unbearable damages to the ecosystems caused by fertilizers and pesticides are not true, are presented. (author)

  7. Poll Tax in Agriculture

    OpenAIRE

    Marina Luminita Sarbovan

    2011-01-01

    Under the crisis constrains, the Romanian government tries to balance the budget, to stop the inflation and decrease unemployment, but its financial possibilities to do so prove to be much smaller than necessary. As far as agriculture is concerned, because of the strong connection of this branch to the European rural mechanism, the state intervention plays the key role in the protection and promoting the national production, in competition with other global producers. The taxation system stil...

  8. Research on agricultural research

    OpenAIRE

    Renborg, Ulf

    2010-01-01

    A Cobb-Douglas type production function is estimated for the Swedish agricultural sector over the period 1944/45 - 1986/87. Total production of the sector is the dependent variable. Public research and advisory services are introduced as independent variables together with labour, land, variable capital and inputs bought from other sectors and a yield variable. Research is introduced with lags from 6 to 24 years from research inputs to effects on the total sector production. Research lags of ...

  9. Coffee in world agriculture

    OpenAIRE

    Sochůrková, Iva

    2012-01-01

    Bachelor thesis The coffee in world agricultur in the theoretical part deals with the important historical events associated with coffee. In connection with the coffee and basic concepts associated with the cultivation of coffee trees, the collection and processing of coffee beans. On the basis of data on coffee production were selected countries that are major producers of coffee in the world. For each country were given basic information and data on the areas producing coffee in the country...

  10. Effective monitoring of agriculture.

    Science.gov (United States)

    Lindenmayer, David B; Likens, Gene E

    2011-06-01

    An opinion piece published in Nature proposed a global network for agricultural monitoring [J. Sachs, R. Remans, S. Smukler, L. Winowiecki, S. J. Andelman, K. G. Cassman, D. Castle, R. DeFries, G. Denning, J. Fanzo, L. E. Jackson, R. Leemans, J. Leemans, J. C. Milder, S. Naeem, G. Nziguheba, C. A. Palm, J. P. Reganold, D. D. Richter, S. J. Scherr, J. Sircely, C. Sullivan, T. P. Tomich and P. A. Sanchez, Nature, 2010, 466, 558-560.]. Whilst we agree with Sachs et al. that monitoring of agricultural systems is a critically important activity of global significance, especially given increasing problems with global food security and the potential impacts of agriculture on the environment [J. Cribb, The Coming Famine. The Global Food Crisis and What We Can Do to Avoid It, CSIRO Publishing and University of California Press, Melbourne and Oakland, 2010.], we argue in this paper that their generic, mandated monitoring framework has a high probability of failure or at best will be highly inefficient. We base this conclusion on our recently published examination of the factors influencing the success or failure of monitoring programs worldwide [D. B. Lindenmayer and G. E. Likens, Effective Ecological Monitoring, CSIRO Publishing and Earthscan, Melbourne and London, 2010.]. We briefly outline what we believe are three serious flaws in the monitoring framework proposed by Sachs et al. We then suggest an alternative approach that we argue would be more effective, more efficient, and have a greater chance of successfully addressing key issues in sustainable agriculture. PMID:21479312

  11. Entomophagy and space agriculture

    Science.gov (United States)

    Katayama, N.; Ishikawa, Y.; Takaoki, M.; Yamashita, M.; Nakayama, S.; Kiguchi, K.; Kok, R.; Wada, H.; Mitsuhashi, J.; Space Agriculture Task Force, J.

    Supplying food for human occupants remains one of the primary issues in engineering space habitation Evidently for long-term occupation on a distant planet it is necessary to start agriculture on site Historically humans have consumed a variety of animals and it is required to fill our nutritional need when they live in space Among many candidate group and species of animal to breed in space agriculture insects are of great interest since they have a number of advantages over mammals and other vertebrates or invertebrates About 70-75 of animal species is insects and they play an important role in materials recycle loop of terrestrial biosphere at their various niche For space agriculture we propose several insect species such as the silkworm Bombyx mori the drugstore beetle Stegobium paniceum and the termite Macrotermes subhyalinus Among many advantages these insects do not compete with human in terms of food resources but convert inedible biomass or waste into an edible food source for human The silkworm has been domesticated since 5 000 years ago in China Silk moth has lost capability of flying after its domestication history This feature is advantageous in control of their breeding Silkworm larvae eat specifically mulberry leaves and metamorphose in their cocoon Silk fiber obtained from cocoon can be used to manufacture textile Farming system of the drugstore beetle has been well established Both the drugstore beetle and the termite are capable to convert cellulose or other inedible biomass

  12. Tropospheric Halogen Chemistry

    Science.gov (United States)

    von Glasow, R.; Crutzen, P. J.

    2003-12-01

    Halogens are very reactive chemicals that are known to play an important role in anthropogenic stratospheric ozone depletion chemistry, first recognized by Molina and Rowland (1974). However, they also affect the chemistry of the troposphere. They are of special interest because they are involved in many reaction cycles that can affect the oxidation power of the atmosphere indirectly by influencing the main oxidants O3 and its photolysis product OH and directly, e.g., by reactions of the Cl radical with hydrocarbons (e.g., CH4).Already by the middle of the nineteenth century, Marchand (1852) reported the presence of bromine and iodine in rain and other natural waters. He also mentions the benefits of iodine in drinking water through the prevention of goitres and cretinism. In a prophetic monograph "Air and Rain: The Beginnings of a Chemical Climatology," Smith (1872) describes measurements of chloride in rain water, which he states to originate partly from the oceans by a process that he compares with the bursting of "soap bubbles" which produces "small vehicles" that transfer small spray droplets of seawater to the air. From deviations of the sulfate-to-chloride ratio in coastal rain compared to seawater, Smith concluded that chemical processes occur once the particles are airborne.For almost a century thereafter, however, atmospheric halogens received little attention. One exception was the work by Cauer (1939), who reported that iodine pollution has been significant in Western and Central Europe due to the inefficient burning of seaweed, causing mean gas phase atmospheric concentrations as high as or greater than 0.5 μg m-3. In his classical textbook Air Chemistry and Radioactivity, Junge (1963) devoted less than three pages to halogen gas phase chemistry, discussing chlorine and iodine. As reviewed by Eriksson (1959a, b), the main atmospheric source of halogens is sea salt, derived from the bursting of bubbles of air which are produced by ocean waves and other

  13. Publicising chemistry in a multicultural society through chemistry outreach

    OpenAIRE

    Joyce D. Sewry; Norman, Nicholas C.; Dudley E. Shallcross; Harrison, Timothy G.; Davies-Coleman, Michael T.

    2011-01-01

    Given the emphasis in Higher Education on community engagement in South Africa and the importance of international collaboration, we discuss a joint approach to chemistry outreach in two countries on two continents with widely differing target school audiences. We describe the history of the partnership between the chemistry departments at Rhodes University and the University of Bristol and provide an outline of the chemistry content of their outreach initiatives, the modes of delivery, the a...

  14. Green Chemistry Metrics with Special Reference to Green Analytical Chemistry

    OpenAIRE

    Marek Tobiszewski; Mariusz Marć; Agnieszka Gałuszka; Jacek Namieśnik

    2015-01-01

    The concept of green chemistry is widely recognized in chemical laboratories. To properly measure an environmental impact of chemical processes, dedicated assessment tools are required. This paper summarizes the current state of knowledge in the field of development of green chemistry and green analytical chemistry metrics. The diverse methods used for evaluation of the greenness of organic synthesis, such as eco-footprint, E-Factor, EATOS, and Eco-Scale are described. Both the well-establis...

  15. Urban conservation agriculture with vegetables

    OpenAIRE

    D.I.A. Edralin; Kieu, L.N.; TRAN, D; Creason, S.; Manuel R. Reyes

    2014-01-01

    This poster describes the implementation of a project to promote vegetable gardening with conservation agriculture in urban schools. LTRA-12 (Conservation agriculture for food security in Cambodia and the Philippines)

  16. Nuclear techniques in agriculture

    International Nuclear Information System (INIS)

    Crops provide us food grains and many other products. Demand for food and other agricultural products is increasing. There is also need for improvement of quality of the agricultural produce. There are several technologies in use for achieving the goal of increasing the quantity and quality of agricultural produce. Nuclear techniques provide us with an option which has certain advantages. The characteristics of crop plants are determined by the genetic make up of the plant. Traditionally the genetic make up was modified using conventional breeding techniques such as cross breeding to improve crops for yield, disease resistance, stress tolerance, resistance to insect pests or to improve quality. New varieties of crops are produced which replace the earlier ones and thus the demands are met. The process of development of new varieties is long and time consuming. Nuclear technique called mutation breeding provides an efficient way of breeding new varieties or improving the older ones. This technique merely enhances the process of occurrence of mutations. In nature mutations occur at a rate of approximately one in a million, while when mutations are induced using radiations such as gamma rays the efficiency of inducing mutations is enhanced. Useful mutations are selected, the mutants are evaluated and developed as a new variety. In the Nuclear Agriculture and Biotechnology Division (NA and BTD) this technique has been used to develop mutants of many crop plants. The mutants can be used to develop a variety directly or by using it in further breeding programme. Using these approaches the NA and BTD has developed 40 new varieties of crops such as groundnut, mungbean, urid, pigeon pea, mustard, soybean, sunflower, cowpea, jute. These varieties are developed in collaboration with other agricultural institutions and are popular among the farming community. The method of mutation breeding can be applied to many other crops for improvement. There is increasing interest among

  17. From organic chemistry to fat and oil chemistry*

    OpenAIRE

    Deffense Etienne

    2009-01-01

    With his work on animal fat and identification of fatty acids, Chevreul was a pioneer in organic chemistry. As Chevreul, I had a passion for organic chemistry too. It was then, an honour and a pleasure to present in 2008 at EFL in Athens this presentation entitled “From organic chemistry to fat and oil chemistry” because my background in organic chemistry helped me all along my professional career to understand and implement new developments related to oil and fat technology and processing. A...

  18. Chemistry in Bioinformatics

    Directory of Open Access Journals (Sweden)

    Mitchell John

    2005-06-01

    Full Text Available Abstract Chemical information is now seen as critical for most areas of life sciences. But unlike Bioinformatics, where data is openly available and freely re-usable, most chemical information is closed and cannot be re-distributed without permission. This has led to a failure to adopt modern informatics and software techniques and therefore paucity of chemistry in bioinformatics. New technology, however, offers the hope of making chemical data (compounds and properties free during the authoring process. We argue that the technology is already available; we require a collective agreement to enhance publication protocols.

  19. Optimized random chemistry

    OpenAIRE

    Buzas, Jeffrey S.; Warrington, Gregory S.

    2013-01-01

    The random chemistry algorithm of Kauffman can be used to determine an unknown subset S of a fixed set V. The algorithm proceeds by zeroing in on S through a succession of nested subsets V=V_0,V_1,...,V_m=S. In Kauffman's original algorithm, the size of each V_i is chosen to be half the size of V_{i-1}. In this paper we determine the optimal sequence of sizes so as to minimize the expected run time of the algorithm.

  20. Chemistry of fast electrons

    OpenAIRE

    Maximoff, Sergey N.; Head-Gordon, Martin P.

    2009-01-01

    A chemicurrent is a flux of fast (kinetic energy ≳ 0.5−1.3 eV) metal electrons caused by moderately exothermic (1−3 eV) chemical reactions over high work function (4−6 eV) metal surfaces. In this report, the relation between chemicurrent and surface chemistry is elucidated with a combination of top-down phenomenology and bottom-up atomic-scale modeling. Examination of catalytic CO oxidation, an example which exhibits a chemicurrent, reveals 3 constituents of this relation: The localization of...

  1. Nanoscale surface chemistry

    OpenAIRE

    Madey, Theodore E.; Pelhos, Kalman; WU, QIFEI; Barnes, Robin; Ermanoski, Ivan; Chen, Wenhua; Kolodziej, Jacek J.; Rowe, John E.

    2002-01-01

    We report evidence in several experiments for nanometer-size effects in surface chemistry. The evidence concerns bimetallic systems, monolayer films of Pt or Pd on W(111) surfaces. Pyramidal facets with {211} faces are formed on annealing on physical monolayer of Pt, Pd on a W(111) substrate, and facet sizes increase with annealing temperature. We used synchrotron radiation-based soft x-ray photoemission to show that monolayer films of Pt, Pd, on W “float” on the outer surface, whereas multil...

  2. Radiochemistry and nuclear chemistry

    CERN Document Server

    Choppin, Gregory; RYDBERG, JAN; Ekberg, Christian

    2013-01-01

    Radiochemistry or nuclear chemistry is the study of radiation from an atomic and molecular perspective, including elemental transformation and reaction effects, as well as physical, health and medical properties. This revised edition of one of the earliest and best-known books on the subject has been updated to bring into teaching the latest developments in research and the current hot topics in the field. To further enhance the functionality of this text, the authors have added numerous teaching aids, examples in MathCAD with variable quantities and options, hotlinks to relevant text secti

  3. Principles of quantum chemistry

    CERN Document Server

    George, David V

    2013-01-01

    Principles of Quantum Chemistry focuses on the application of quantum mechanics in physical models and experiments of chemical systems.This book describes chemical bonding and its two specific problems - bonding in complexes and in conjugated organic molecules. The very basic theory of spectroscopy is also considered. Other topics include the early development of quantum theory; particle-in-a-box; general formulation of the theory of quantum mechanics; and treatment of angular momentum in quantum mechanics. The examples of solutions of Schroedinger equations; approximation methods in quantum c

  4. Chemistry in aircraft plumes

    Energy Technology Data Exchange (ETDEWEB)

    Kraabol, A.G.; Stordal, F.; Knudsen, S. [Norwegian Inst. for Air Research, Kjeller (Norway); Konopka, P. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Wessling (Germany). Inst. fuer Physik der Atmosphaere

    1997-12-31

    An expanding plume model with chemistry has been used to study the chemical conversion of NO{sub x} to reservoir species in aircraft plumes. The heterogeneous conversion of N{sub 2}O{sub 5} to HNO{sub 3}(s) has been investigated when the emissions take place during night-time. The plume from an B747 has been simulated. During a ten-hour calculation the most important reservoir species was HNO{sub 3} for emissions at noon. The heterogeneous reactions had little impact on the chemical loss of NO{sub x} to reservoir species for emissions at night. (author) 4 refs.

  5. Arene ruthenium chemistry

    OpenAIRE

    Bates, Richard Simon

    1990-01-01

    This thesis describes the synthesis and reactivity studies of new arene-ruthenium(II) and arene-ruthenium(O) complexes. Ultrasound has been investigated as an alternative energy source, with the overall aim of synthesising arene ruthenium clusters. Chapter 1 gives an introduction and summary of the known arene ruthenium chemistry reported to date. Chapter 2 reports the synthesis of (CGH6)Ru(C2H4)2 and (MeC6H4CHMe2)Ru(C2H4)2. Low temperature protonation studies generated (C6H6)Ru(H)(CZH4...

  6. Introduction to supramolecular chemistry

    CERN Document Server

    Dodziuk, Helena

    2007-01-01

    'A major strength of this work is its inclusion of literally hundreds of clearly drawn structures and diagrams to assist reader understanding of this complex area. In addition, the author has included hundreds of up-to-date references. It also has a useful and extensive index. The book is valuable not only to those working in the field of supramolecular chemistry, but also to chemists in unrelated areas of research who want a refreshingly well-written monograph on an emerging area of important research.' H.T. McKone, Saint Joseph College in Choice, September 2002

  7. Radiochemistry and actinide chemistry

    International Nuclear Information System (INIS)

    The analysis of trace amounts of actinide elements by means of radiochemistry, is discussed. The similarities between radiochemistry and actinide chemistry, in the case of species amount by cubic cm below 1012, are explained. The parameters which allow to define what are the observable chemical reactions, are given. The classification of radionuclides in micro or macrocomponents is considered. The validity of the mass action law and the partition function in the definition of the average number of species for trace amounts, is investigated. Examples illustrating the results are given

  8. Analytical chemistry in space

    CERN Document Server

    Wainerdi, Richard E

    1970-01-01

    Analytical Chemistry in Space presents an analysis of the chemical constitution of space, particularly the particles in the solar wind, of the planetary atmospheres, and the surfaces of the moon and planets. Topics range from space engineering considerations to solar system atmospheres and recovered extraterrestrial materials. Mass spectroscopy in space exploration is also discussed, along with lunar and planetary surface analysis using neutron inelastic scattering. This book is comprised of seven chapters and opens with a discussion on the possibilities for exploration of the solar system by

  9. Introduction to Coordination Chemistry

    CERN Document Server

    Lawrance, Geoffrey Alan

    2010-01-01

    Introduction to Coordination Chemistry examines and explains how metals and molecules that bind as ligands interact, and the consequences of this assembly process. This book describes the chemical and physical properties and behavior of the complex assemblies that form, and applications that may arise as a result of these properties. Coordination complexes are an important but often hidden part of our world?even part of us?and what they do is probed in this book. This book distills the essence of this topic for undergraduate students and for research scientists.

  10. Chemistry in space

    CERN Document Server

    Rehder, Dieter

    2010-01-01

    The dynamic field of extraterrestrial chemistry brings together ideas of chemistr, astrophysics, and biology to the study of molecules between stars, around stars, and on plantes. This book serves as an introduction to chemial processes under ?unearthly? and hence usually extreme conditions (temperature, pressure, high or low density, bombardment by cosmic rays), and their impact on the early development of our solar system, as well as providing a deeper understanding of processes in earthly regions where conditions approach those of extraterrestrial areas.A unique and extraordinary perspe

  11. Radiation chemistry in microemulsion

    International Nuclear Information System (INIS)

    Radiation chemistry can be used to study reactions of free radicals not only in homogeneous medium but also in micro-heterogeneous medium, microemulsion being typical example of this type of medium. This article intends to summarize some radiation chemical studies in microemulsion using pulse radiolysis as a tool. Attempt has been made to show that the reaction and self-decay of hydrated electron can lead to achieve useful results relating to the physical properties of micro-droplets. Moreover, free radical reactions with biomolecules in these media can sometime be extrapolated to living systems. (author)

  12. Quantum chemistry an introduction

    CERN Document Server

    Kauzmann, Walter

    2013-01-01

    Quantum Chemistry: An Introduction provides information pertinent to the fundamental aspects of quantum mechanics. This book presents the theory of partial differentiation equations by using the classical theory of vibrations as a means of developing physical insight into this essential branch of mathematics.Organized into five parts encompassing 16 chapters, this book begins with an overview of how quantum mechanical deductions are made. This text then describes the achievements and limitations of the application of quantum mechanics to chemical problems. Other chapters provide a brief survey

  13. PRESENT FRAMEWORK OF AGRICULTURAL INSURANCE

    OpenAIRE

    Narcis Eduard Mitu

    2007-01-01

    The international agricultural insurance market has an important dimension. The experience of economically developed countries revealed the fact that without a stable development of agricultural insurances, there is no chance for high performance agriculture. This will require the establishment of a framework for responding to severe systemic events affecting agricultural production, and establishing an appropriate regulatory environment to foster private sector innovation and investment in s...

  14. Compaction properties of agricultural soils

    OpenAIRE

    TANG, Anh Minh; CUI, Yu Jun; Eslami, Javad; DEFOSSEZ BERTHOUD, Pauline

    2007-01-01

    The compaction of field soils due to repeated rolling of agricultural vehicles is one of the main reasons for the agricultural soil degradation. A good understanding of the compaction properties of these soils is essential for an optimum organisation of agricultural activities, and therefore for environmental protection in terms of nitrate migrations. In the present work, the compaction properties of agricultural soils from four sites in France are studied after experimental data ...

  15. Conservation agriculture and ecosystem services

    OpenAIRE

    Dillaha, Theo A.; Cheryl B. Heatwole Shenk; Moore, Keith M.

    2010-01-01

    Conservation agriculture has many agricultural and food security benefits. In addition, conservation agriculture has potential on- and off-site ecosystem service benefits that are the focus of this paper. Ecosystem services provided by conservation agriculture fall into three main categories: provisioning services such as increased food production; regulating services such as carbon sequestration and climate regulation, reducing losses of soil, pesticides, nutrients and other potential contam...

  16. Uses of ICT in Agriculture

    OpenAIRE

    Manish Mahant; Abhishek Shukla; Sunil Dixit; Dileshwer Patel

    2012-01-01

    The application of Information and Communication Technology (ICT) in agriculture is increasingly important. E-Agriculture is an emerging field focusing on the enhancement of agriculture and rural development through improved information and communication processes. More specifically, e-agriculture involves the conceptualization, design, development, evaluation and application of innovative ways to use information and communication technologies (ICT) in rural domain, with a primary focus on ag...

  17. From China to the world: Science China Chemistry celebrates the International Year of Chemistry

    Institute of Scientific and Technical Information of China (English)

    ZHU XiaoWen; XUE Zi-Ling

    2012-01-01

    1 Introduction Science China Chemistry is considered the best and most comprehensive chemistry journal in China,Its primary mission is to communicate the results of basic and innovative chemistry research.The subject areas include physical chemistry,organic chemistry,inorganic chemistry,polymer chemistry,biological chemistry,environmental chemistry,and chemical engineering in the form of Feature Articles,Reviews,Communications,Articles,and News & Comments.

  18. Economics, Policy, and Organic Agriculture

    DEFF Research Database (Denmark)

    Ingemann, Jan Holm

    2009-01-01

    Is organic agriculture so special that special social theories and methods are needed? The article investigates the question in two steps: First, the article address the question whether agriculture is special. Second, whether organic agriculture is special. It is concluded that from an economic...... policy recommendations....

  19. Sustainability in the Agricultural sector

    Directory of Open Access Journals (Sweden)

    Anna Forgács

    2011-02-01

    Full Text Available The present study will examine the possible ways of integrating sustainability indicators in assessing the performance of agriculture. We are examining the appropriate ways of calculating the output of the sector including the damages caused by and the benefits of agricultural production. The involvment of environmental pressure into the assessment of agricultural performance does not show significant changes in values.

  20. Sustainability in the Agricultural sector

    OpenAIRE

    Anna Forgács; Judit Beke

    2011-01-01

    The present study will examine the possible ways of integrating sustainability indicators in assessing the performance of agriculture. We are examining the appropriate ways of calculating the output of the sector including the damages caused by and the benefits of agricultural production. The involvment of environmental pressure into the assessment of agricultural performance does not show significant changes in values.

  1. AGRICULTURE IN AN ECOSYSTEMS FRAMEWORK

    OpenAIRE

    Aillery, Marcel P.; Hrubovcak, James; Kramer, Carol S.; Shoemaker, Robbin A.; Tegene, Abebayehu

    1996-01-01

    By broadening the definition of an ecosystem to include economic activities, can we better characterize the interactions and relationships among agricultural activities and important indicators of ecological system health? This paper addresses research approaches for assessing the role of agriculture in an ecosystems context. Environmental regulation and resource management policies have heightened the interest in understanding interactions among agricultural activities and the natural resour...

  2. DYNAMICS OF AGRICULTURAL GROUNDWATER EXTRACTION

    OpenAIRE

    2001-01-01

    Agricultural shallow groundwater extraction can result in desiccation of neighbouring nature reserves and degradation of groundwater quality in the Netherlands, whereas both externalities are often not considered when agricultural groundwater extraction patterns are being determined. A model is developed to study socially optimal agricultural shallow groundwater extraction patterns. It shows the importance of stock size to slow down changes in groundwater quality.

  3. New Research in Organic Agriculture

    DEFF Research Database (Denmark)

    1996-01-01

    The book is the proceedings from the bi-annual international scientific conference on organic agriculture. The chapters are: - plant and soil interactions, - animal production systems, - traditional knowledge in sustainable agriculture, - research, education and extension in sustainable agriculture......, - environmental impact and nature, - potentials of organic farming, - community, consumer and market, and - policy and financial strategies....

  4. MICROSCALE CHEMISTRY IN LATIN AMERICA

    Directory of Open Access Journals (Sweden)

    Jorge G. Ibáñez

    2005-06-01

    Full Text Available A brief account of the development of Microscale Chemistry in Latin America is here presented. The US National Microscale Chemistry Center (Merrimack College, Massachusetts was instrumental in the initiationof several centers. Its Mexican counterpart, the Mexican Microscale Chemistry Center (CMQM, has been a key player in this process. Other participating countries include Argentina, Bolivia, Brazil, Chile, Cuba,Guatemala, Perú and Uruguay.

  5. Six Phases of Cosmic Chemistry

    OpenAIRE

    Lukasz Lamza

    2014-01-01

    The article presents a conceptually unified, quantitative account of the development of chemical phenomena throughout the cosmic history, with a detailed discussion of the cosmological, astrophysical, geological, biological, and anthropological context. The totality of cosmic chemistry is represented by a list of 176 classes of phenomena, drawn from the Universal Decimal Classification (UDC) library cataloguing system, and divided into 6 phases: of no chemistry, of prestellar chemistry, of ga...

  6. NUCLEAR CHEMISTRY ANNUAL REPORT 1970

    Energy Technology Data Exchange (ETDEWEB)

    Authors, Various

    1971-05-01

    Papers are presented for the following topics: (1) Nuclear Structure and Nuclear Properties - (a) Nuclear Spectroscopy and Radioactivity; (b) Nuclear Reactions and Scattering; (c) Nuclear Theory; and (d) Fission. (2) Chemical and Atomic Physics - (a) Atomic and Molecular Spectroscopy; and (b) Hyperfine Interactions. (3) Physical, Inorganic, and Analytical Chemistry - (a) X-Ray Crystallography; (b) Physical and Inorganic Chemistry; (c) Radiation Chemistry; and (d) Chemical Engineering. (4) Instrumentation and Systems Development.

  7. Identification and modelling of processes controlling dissolved phosphorus transfer in an agricultural catchment

    OpenAIRE

    Dupas, Rémi

    2015-01-01

    Phosphorus (P) is a controlling factor of eutrophication. Its presence in water bodies is partly due to agricultural diffuse emissions. The objective of this thesis was to identify and quantify the processes controlling diffuse P transfer, with an approach combining analysis of multi-scale observation data and modelling.Analysis of a water chemistry time series acquired at the outlet of a small agricultural catchment revealed that particulate and dissolved P forms had different spatial origin...

  8. Sixty Years of Chemistry at CAS

    Institute of Scientific and Technical Information of China (English)

    WAN Li-Jun

    2011-01-01

    @@ As one of the fundamental and key disciplines of natural sciences, chemistry deals with the properties, composition, structure, transformation and applications of substances.It could be further divided into several branches, such as inorganic chemistry, organic chemistry, physical chemistry, polymer chemistry, analytical chemistry and chemical engineering.In recent years, many new branches and fields have emerged amide the continuous development of chemistry and its interdisciplinary research with mathematics, physics, astronomy, earth science, biology, medical science, materials science, and environmental science.

  9. Biomass valorisation, a new dynamics for French agriculture. Colloquium proceedings

    International Nuclear Information System (INIS)

    This document brings together the summary of the presentations given at this colloquium on French agriculture and biomass valorisation and the slides of the available presentations as well. The colloquium started with the opening talk by D. Bussereau (Ministry of agriculture and fisheries) who presented an international overview of biomass activities. The colloquium was divided in two parts with presentations and round-tables: 1 - the post-petroleum era: energy context and raw materials market (P. Chalmin, Cyclope); first round-table on biofuels today and tomorrow; back to the basics (C. Roy); 2 - Biomass and industry: second round-table on cellulose - an oldie promised to a bright future; status of biomass valorisation (M. Pappalardo, ADEME); third round-table: the boom of green chemistry; closing talk by C. Roy. Sixteen presentations (slides) are attached to the document: 1 - Opening talk (D. Bussereau, Ministry of agriculture and fisheries); 2 - Biomass, agriculture, forestry and climate, some basics (C. Roy); 3 - Role of biomass in the fight against climate change and in supplies diversification (M. Pappalardo, Ademe); 4 - The 2005/2006 shock on world markets: energy and raw materials (P. Chalmin, Cyclope); 5 - Actions in the energy domain (A. Chosson, CLCV); 6 - Ethanol production (A. Jeanroy); 7 - The 'biofuels' commitment of PSA Peugeot Citroen car maker (Beatrice Perrier-Maurer, PSA); 8 - Bio-diesel development (Bernard Nicol, Diester Industrie); 9 - First round-table on biofuels today and tomorrow: biofuels and conventional fuels - for an harmonious development of resources and outlets (J.B. Sigaud, Petroleum and Engines School); 10 - Agriculture biomass: source of cellulose (C. Burren, Ungrains, Arvalis); 11 - Electrical and thermal valorisations of biomass (C. Jurczak, MINEFI/DGEMP); 12 - Some elements of thought on new uses of biomass as 'material' (Jacques Sturm, Afocel) 13 - Presentation of Agrice (Agriculture for chemistry and energy) research

  10. Complex Protostellar Chemistry

    Science.gov (United States)

    Nuth, Joseph A., III; Johnson, Natasha M.

    2012-01-01

    Two decades ago, our understanding of the chemistry in protostars was simple-matter either fell into the central star or was trapped in planetary-scale objects. Some minor chemical changes might occur as the dust and gas fell inward, but such effects were overwhelmed by the much larger scale processes that occurred even in bodies as small as asteroids. The chemistry that did occur in the nebula was relatively easy to model because the fall from the cold molecular cloud into the growing star was a one-way trip down a well-known temperature-pressure gradient; the only free variable was time. However, just over 10 years ago it was suggested that some material could be processed in the inner nebula, flow outward, and become incorporated into comets (1, 2). This outward flow was confirmed when the Stardust mission returned crystalline mineral fragments (3) from Comet Wild 2 that must have been processed close to the Sun before they were incorporated into the comet. In this week's Science Express, Ciesla and Sandford (4) demonstrate that even the outermost regions of the solar nebula can be a chemically active environment. Their finding could have consequences for the rest of the nebula.

  11. Materials Chemistry Studies

    International Nuclear Information System (INIS)

    In 2006, a new research group has been created at the SCK-CEN in order to focus more specifically on chemical issues relevant to the studies of materials. The integrated staff personnel has a long experience in many different fields of expertise such as radiochemistry (fuel cycles and radioisotopes), organic chemistry, electrochemistry (analytical techniques and corrosion) and sonochemistry. The previously running activities are now being reoriented according to a well-defined work programme. Each research line that was previously running had specific objectives. Fuel cycle studies were axed on the partitioning of lanthanides and actinides in aqueous solutions. Support to corrosion studies was devoted to the development of a new method for the treatment of electrochemical noise data for the detection and the classification of local corrosion events. New objectives for the future put a strong accent on radioisotopes for the pharmaceutical industry as well as the use of non-aqueous chemistry as a tool for several applications among which the treatment and the separation of radioisotopes, analytical measurements as well as the chemical control of impurities in liquid metals

  12. Integrating UNESCO ICT-Based Instructional Materials in Chemistry Lessons

    Directory of Open Access Journals (Sweden)

    CHARLIE P. NACARIO

    2014-08-01

    Full Text Available This study determined the effectiveness of the lessons in Chemistry integrating UNESCO ICT-based instructional material on the achievement of Chemistry students at Central Bicol State University of Agriculture. It aimed to identify lessons that may be developed integrating UNESCO ICT-based instructional materials, determine the effect of the developed lessons using the material on: conceptual understanding; science process skills; and attitude towards chemistry and gather insights from the experiences of the students and teacher. The study used the single group pretest and posttest experimental design. Descriptive, quantitative and qualitative techniques were also utilized. Quantitative data were taken from the pretest-posttest results on the Test on Conceptual Understanding, Science Process Skills and Chemistry Attitudinaire. Qualitative data were drawn from the experts’ assessment of the developed lessons and research instruments, and the insights of students and teacher. The developed lessons integrating UNESCO ICT-based instructional materials were Atomic Model and Structure, Periodic Table of Elements, Chemical Bonding, and Balancing Chemical Equation. These lessons increased the conceptual understanding of the students by topic and skill from very low mastery to average mastery level. The students have slightly improved along the different science process skills. After teaching the lessons, the students’ attitude also improved. The students became more motivated and interested in Chemistry and the lessons were student centered and entailed teacher’s competence and flexibility in computer use.

  13. Solid state chemistry an introduction

    CERN Document Server

    Smart, Lesley E

    2012-01-01

    ""Smart and Moore are engaging writers, providing clear explanations for concepts in solid-state chemistry from the atomic/molecular perspective. The fourth edition is a welcome addition to my bookshelves. … What I like most about Solid State Chemistry is that it gives simple clear descriptions for a large number of interesting materials and correspondingly clear explanations of their applications. Solid State Chemistry could be used for a solid state textbook at the third or fourth year undergraduate level, especially for chemistry programs. It is also a useful resource for beginning graduate

  14. Graduate Education in Environmental Chemistry

    Science.gov (United States)

    Lee, G. Fred

    1974-01-01

    Describes the role chemistry departments should assume in the environmental quality control area. Includes problems of program design, course offerings, research problems, and career qualifications. (GS)

  15. A green chemistry lab course

    International Nuclear Information System (INIS)

    The traditional course content of chemistry classes must change to achieve better awareness of the important issues of sustainability in chemistry within the next generation of professional chemists. To provide the necessary material for the organic chemistry teaching lab course, which is part of almost all study programs in chemistry, material was developed and collected (http://www.oc-praktikum.de/en) that allows students and teachers to assess reactions beyond the experimental set up, reaction mechanism and chemical yield. Additional parameters like atom economy of chemical transformations, energy efficiency, and questions of waste, renewable feed stocks, toxicity and ecotoxicity, as well as the safety measures for the chemicals used are discussed. (author)

  16. Cross-Connections of Chemistry

    Science.gov (United States)

    Mason, Diana S.

    2002-02-01

    We are in desperate need of qualified chemistry teachers. Are the teachers who have biology, physics, or some psychology degrees qualified to teach chemistry? Have they taken enough chemistry to be prepared to teach outside their degree field? If remediation is necessary, what courses should be required? Attracting pre-service science teachers to the study of pure chemistry is not an easy task when more attractive course offerings are available. Maybe we should concentrate on cross-training in-service teachers by providing appropriate graduate courses to encourage them and bring them into the family. Many teachers with degrees outside the traditional discipline of chemistry have adequate backgrounds in the applications of chemistry. Requiring hours of undergraduate education before they enter the hallowed halls of the chemistry building as graduate students only serves to discourage a large segment of in-service teachers who wish to broaden their perspective. The National Science Education Standards make a compelling argument for connecting and integrating science courses for practicing teachers (3). We are at the crossroads. At a time when we so desperately need qualified chemistry teachers, shouldn't we be more open in our graduate teaching programs, inviting those with degrees in other disciplines to start on a graduate degree without insisting on undergraduate or survey coursework first? Many potential chemical education graduate students have a background in chemistry--it is just known by another name.

  17. Food, soil, and agriculture

    International Nuclear Information System (INIS)

    The growing pressures on the world's land resources will result in problems requiring a major research effort.The first group of problems relates to increased soil degradation. The research to alleviate this will have to incorporate not only physical and biological solutions, but also pay much more attention to the socio-economic context in which the conservation programmes need to succeed.The second major area for research on land resource is to make better use of low-capacity or problem soils.This could be by reducing the existing limitations, such as changing physical or chemical characteristics of the soil, or by developing plants and production techniques which reduce the detrimental effects of constraints. Example of these are acidity, salinity, and aluminium toxicity. Finally the broadest and more important area is that of research to enable more intensive use of better-quality land. Research topics here may relate to optimal plant nutrient management, soil moisture management, and developing cultivation techniques with minimum commercial energy requirements. Making plants more productive will involve research aimed at increasing photosynthetic efficiency, nitrogen fixation, disease and pest resistance, improved weed control, and bio-engineering to adjust plant types to maximize production potentials. Improved rotational systems for the achievement of many of the above goals will become increasingly important, as the potential problems or inappropriate cultivation practices become evident. In conclusion, food supplies of the world could meet the rapidly rising demands that are made on them, if agriculture receives sufficient attention and resources. Even with most modern development, land remains the base for agriculture, and optimal use of the world's land resources is thus crucial for future agricultural production

  18. Agricultural Pilot's Audiological Profile

    Directory of Open Access Journals (Sweden)

    Foltz, Lucas

    2010-09-01

    Full Text Available Introduction: The agricultural airplane pilot are daily exposed to intense noises, being susceptible to the noise-induced hearing loss (NIHL and its auditory and extra auditory effects. Objective: To analyze the audiological profile of this population, verifying the work's influence on its hearing. Method: It was realized a retrospective, individual, observational, and cross-sectional study through the data obtained by means of a questionnaire and audiometric thresholds of 41 agricultural pilots. To the statistical analysis were utilized the chi-square, Spearman, and Wilcoxon tests with significance level of 5%. Results: It was verified that 95,1% of the pilots use PPE ( personal protective equipment during flight and 58,5% have contact with pesticides. More than half of individuals referred to feel auditory and extra auditory symptoms, being the buzz the more frequent (29,1%. It has the occurrence of 29,3% of NIHL suggestive hearing loss and 68,3% of normality, taking this presence of unilateral notch in 24,4% and bilateral notch in 31,7%. It was found correlation statistically significant in the associations between time of service and the average of the acute frequencies in the right ear (p=0038, and in the left ear (p=0,010. It has a statistical tendency in the association between audiometric configuration and contact with pesticides (p=0,088. Conclusion: The hearing loss prevalence in this study was showed high. More than half of the sample has normal audiometric thresholds with notch configuration. Such data lead to the conclusion that the agricultural pilots, even with PPE use, they still suffer with the damages caused by noise, needing best proposals of hearing loss prevention.

  19. African agricultural trade

    DEFF Research Database (Denmark)

    Jensen, Hans Grinsted; Sandrey, Ron

    2015-01-01

    This article starts with a profile of African agricultural trade. Using the pre-release version 9.2 of the GTAP database, we then show that the results for tariff elimination on intra-African trade are promising, but these tariff barriers are not as significant as the various trade-related barriers...... elimination, non-tariff barrier reductions and time in transit cost reductions are likely to be cumulative and would generate very large gains to Africa. The policy implications are clear: while cooperation will enhance the gains, much of the benefits will result from unilateral actions and regional...

  20. Biostimulants in Agriculture

    Directory of Open Access Journals (Sweden)

    Patrick eBrown

    2015-08-01

    Full Text Available Biostimulants, which may be derived from a wide range of natural or synthetic processes, are now widely used in agriculture and yet the mode of action of these materials is not well understood. On the basis of available literature, and based upon the diversity of biostimulant responses highlighted in this focus issue, we hypothesize that biostimulants function by directly interacting with plant signaling cascades or act through stimulation of endophytic and non-endophytic bacteria, yeast and fungi to produce molecules of benefit to the plant. The benefit of the biostimulant is derived from the reduction in assimilates that are diverted to non-productive stress response metabolism.

  1. Agricultural futures as becoming

    DEFF Research Database (Denmark)

    Kristensen, Dan Kristian; Kjeldsen, Chris

    This paper explores how the unfolding of an alternative future for agriculture consists of struggles to assemble a heterogeneous network of natural relations and social relations and technological relations. The site of this exploration is a profiled project, where a zero emission and landless...... in the conventional production, regarding animal welfare and working conditions for employees.The exploration accounts for the entanglement and the shape-shifting that happens as the project moves between different settings (administrative, natural, technical, political and locality). It shows how the project gains...

  2. Chapitre IV. Les agricultures

    OpenAIRE

    Galinier, Jacques

    2016-01-01

    Les Otomis tirent l'essentiel de leurs revenus de l'agriculture. Mais la diversité des conditions géographiques et climatiques introduit d'impressionnantes disparités dans la mise en valeur du sol. La frange montagneuse et côtière remarquablement privilégiée contraste avec le haut pays, comme la lande de Texcatepec. Au centre du paysage agricole, le maïs tient la première place. Avec la culture des haricots et du piment, il réalise la triade fondamentale de l'alimentation otomi, comme dans la...

  3. Agriculture and Water Quality. Issues in Agricultural Policy. Agriculture Information Bulletin Number 548.

    Science.gov (United States)

    Crowder, Bradley M.; And Others

    Agriculture generates byproducts that may contribute to the contamination of the United States' water supply. Any effective regulations to ban or restrict agricultural chemical or land use practices in order to improve water quality will affect the farm economy. Some farmers will benefit; some will not. Most agricultural pollutants reach surface…

  4. Influencing College Chemistry Success through High School Chemistry Teaching

    Science.gov (United States)

    Tai, Robert H.; Sadler, Philip M.; Loehr, John F.

    2006-01-01

    The connection between high school chemistry pedagogical experiences and introductory college chemistry performance has been a topic researched in published science education literature since the 1920s. However, analysis techniques have limited the generalizability of these results. This review discusses the findings of a large-scale,…

  5. Introducing Chemistry Students to the "Real World" of Chemistry

    Science.gov (United States)

    Brown, Michael E.; Cosser, Ronald C.; Davies-Coleman, Michael T.; Kaye, Perry T.; Klein, Rosalyn; Lamprecht, Emmanuel; Lobb, Kevin; Nyokong, Tebello; Sewry, Joyce D.; Tshentu, Zenixole R.; van der Zeyde, Tino; Watkins, Gareth M.

    2010-01-01

    A majority of chemistry graduates seek employment in a rapidly changing chemical industry. Our attempts to provide the graduates with skills in entrepreneurship and the ability to understand and communicate with their chemical engineering colleagues, in addition to their fundamental knowledge of chemistry, are described. This is done at…

  6. A Quantum Chemistry Concept Inventory for Physical Chemistry Classes

    Science.gov (United States)

    Dick-Perez, Marilu; Luxford, Cynthia J.; Windus, Theresa L.; Holme, Thomas

    2016-01-01

    A 14-item, multiple-choice diagnostic assessment tool, the quantum chemistry concept inventory or QCCI, is presented. Items were developed based on published student misconceptions and content coverage and then piloted and used in advanced physical chemistry undergraduate courses. In addition to the instrument itself, data from both a pretest,…

  7. Green Chemistry Metrics with Special Reference to Green Analytical Chemistry

    Directory of Open Access Journals (Sweden)

    Marek Tobiszewski

    2015-06-01

    Full Text Available The concept of green chemistry is widely recognized in chemical laboratories. To properly measure an environmental impact of chemical processes, dedicated assessment tools are required. This paper summarizes the current state of knowledge in the field of development of green chemistry and green analytical chemistry metrics. The diverse methods used for evaluation of the greenness of organic synthesis, such as eco-footprint, E-Factor, EATOS, and Eco-Scale are described. Both the well-established and recently developed green analytical chemistry metrics, including NEMI labeling and analytical Eco-scale, are presented. Additionally, this paper focuses on the possibility of the use of multivariate statistics in evaluation of environmental impact of analytical procedures. All the above metrics are compared and discussed in terms of their advantages and disadvantages. The current needs and future perspectives in green chemistry metrics are also discussed.

  8. Green Chemistry Metrics with Special Reference to Green Analytical Chemistry.

    Science.gov (United States)

    Tobiszewski, Marek; Marć, Mariusz; Gałuszka, Agnieszka; Namieśnik, Jacek

    2015-01-01

    The concept of green chemistry is widely recognized in chemical laboratories. To properly measure an environmental impact of chemical processes, dedicated assessment tools are required. This paper summarizes the current state of knowledge in the field of development of green chemistry and green analytical chemistry metrics. The diverse methods used for evaluation of the greenness of organic synthesis, such as eco-footprint, E-Factor, EATOS, and Eco-Scale are described. Both the well-established and recently developed green analytical chemistry metrics, including NEMI labeling and analytical Eco-scale, are presented. Additionally, this paper focuses on the possibility of the use of multivariate statistics in evaluation of environmental impact of analytical procedures. All the above metrics are compared and discussed in terms of their advantages and disadvantages. The current needs and future perspectives in green chemistry metrics are also discussed. PMID:26076112

  9. Workshop on Agricultural Air Quality: State of the science

    Science.gov (United States)

    Aneja, Viney P.; Blunden, Jessica; Roelle, Paul A.; Schlesinger, William H.; Knighton, Raymond; Niyogi, Dev; Gilliam, Wendell; Jennings, Greg; Duke, Clifford S.

    The first Workshop on Agricultural Air Quality: State of the Science was held at the Bolger Center in Potomac, Maryland from 4 to 8 June 2006. This international conference assembled approximately 350 people representing 25 nations from 5 continents, with disciplines ranging from atmospheric chemistry to soil science. The workshop was designed as an open forum in which participants could openly exchange the most current knowledge and learn about numerous international perspectives regarding agricultural air quality. Participants represented many stakeholder groups concerned with the growing need to assess agricultural impacts on the atmosphere and to develop beneficial policies to improve air quality. The workshop focused on identifying methods to improve emissions inventories and best management practices for agriculture. Workshop participants also made recommendations for technological and methodological improvements in current emissions measurement and modeling practices. The workshop commenced with a session on agricultural emissions and was followed by international perspectives from the United States, Europe, Australia, India, and South America. This paper summarizes the findings and issues of the workshop and articulates future research needs. These needs were identified in three general areas: (1) improvement of emissions measurement; (2) development of appropriate emission factors; and (3) implementation of best management practices (BMPs) to minimize negative environmental impacts. Improvements in the appropriate measurements will inform decisions regarding US farming practices. A need was demonstrated for a national/international network to monitor atmospheric emissions from agriculture and their subsequent depositions to surrounding areas. Information collected through such a program may be used to assess model performance and could be critical for evaluating any future regulatory policies or BMPs. The workshop concluded that efforts to maximize

  10. AGRICULTURE DISEASE MITIGATION SYSTEM

    Directory of Open Access Journals (Sweden)

    Sion Hannuna

    2011-06-01

    Full Text Available Around 52% of the population of India rely on farming for their livelihood which accounts for 17% of India’s GDP. Whilst most farmers are familiar with conventional farming practices, they are often ill positioned to promptly deal with diseases and plant infestations affecting their crops. Current advisory systems tend to be generic and are not tailored to specific plots or farms. This work comprises an agriculture advisory call center similar to a modern call center to provide an agriculture disease mitigation system. The information regarding an individual farm is collected using mobile phones. The image of diseased/infected crop is also captured using mobile phones and is made available to the expert to provide the advisory. To scale the advisory, an attempt is also made to automate the disease recognition process using image processing. Unfortunately, the photos taken will be sensitive to a number of factors including camera type and lighting incident on the scene. Ideally, the images would be processed in such a way as to provide the expert with a visual representation of the affected crops that reflects the true nature of the scene. We describe a framework for standardising the colour of plant images taken using both mobile phones and compact cameras within the context of the advisory system.

  11. COMMUNITY SUPPORTED AGRICULTURE (CSA

    Directory of Open Access Journals (Sweden)

    Atănăsoaie George Sebastian

    2013-06-01

    Full Text Available Farms of CSA types are a viable alternative to trade of agricultural products coming from conventional agriculture. These farms are faced with a number of policy issues related to product, price, distribution and promotion. In order to elucidate the issues listed above, we have investigated the literature of specialty. Farmers must make more flexible the content of basket both quantitatively and in terms of the nature of food products offered. Consumers need information on ways of preparation or preservation of products. The growth of the processing degree in farm, and inclusion in the offer of services in ecotourism represent effective options to satisfy consumers. To offset the negative impact of high prices measures should be taken in reducing costs, more flexibility in rescheduling of payments due from customers and compensate for the lack of financial resources with the provision of farm work or subsidize a portion of the basket value from private or government sources. Delivery of baskets should be both at fixed points and at customers domicile. Farmers must provide customers the possibility so that they could harvest themselves the products they will buy. Negative influence of prices will be reduced by establishing an effective communication policy with the market, by organizing events on the farm or nearby towns, through blogs and social networks, and through participation in fairs and exhibitions. A greater customer involvement in farming activities will lead to the implementation of an effective marketing mix.

  12. Advances in nuclear chemistry and its applications in the Philippines

    International Nuclear Information System (INIS)

    Nuclear chemistry was born almost 120 years ago with the discovery of radioactivity by Antoine Henry Becquerel in 1896. Nuclear chemistry is a subfield of chemistry that deals with radioactivity, nuclear reactions and processes, and nuclear properties. The composition of the nucleus and the changes that occur within the nucleus define the properties of the radioisotope and the nuclear reactions and processes it is involved in. Almost six decades ago, nuclear chemistry established its roots in the Philippines under the Philippine Atomic Energy Commission, presently the Philippine Nuclear Research Institute. The main areas of nuclear chemistry, namely, namely radiochemistry, radiation chemistry, radiation biology, and isotopic chemistry have been studies, and have found applications in food and agriculture, medicine and health, in idustry, and in the protection of the environment. Early work in nuclear chemistry utilized the Philippine Research Reactor (PRR-1) for the production of radioisotopes which were used in either research or direct applications in food and agriculture, health and medicine, and industry. The PRR-1 provided neutrons for the non destructive multi element analysis of various samples using the neutron activation analysis technique. Radioactive materials as sources of ionizing radiation are being used extensively to study the chemical and biological effects of radiation on matter. Current studies involve the irradiation of certain plants and insects causing changes in their DNA which result in mutation for better crop varieties and sterility in insects for quarantine treatment and pest management. Radiation can modify the properties of polymers. Natural polymers such as carrageenan, chitosan and cellulose in abaca and water hyacinth fibers are subjected to gamma irradiation changing their properties and resulting in new products such as wound drressing, hemostatic agents, plant growth promoters, and metal-chelating agents. Radioisotopes are also

  13. Clays in prebiological chemistry

    Science.gov (United States)

    Rao, M.; Oro, J.; Odom, D. G.

    1980-01-01

    The ways in which clays have been utilized in studies of prebiological chemistry are reviewed, and an assessment is given of the possible role of clays in prebiological systems. The adsorption of organic molecules on clays has been demonstrated, as has the synthesis of bioorganic monomers in the presence of clays. For instance, amino acids, purines and pyrimidines have been obtained from carbon monoxide and nitric acid in the presence of clays at relatively high temperatures (250-325 C). The oligomerization of biochemical monomers, mediated by clays, has also been shown to result in the formation of polymer molecules basic to life. Clays have also been found to affect the condensation of mononucleotides to oligonucleotides.

  14. Organic chemistry on Titan

    Science.gov (United States)

    Chang, S.; Scattergood, T.; Aronowitz, S.; Flores, J.

    1979-01-01

    Features taken from various models of Titan's atmosphere are combined in a working composite model that provides environmental constraints within which different pathways for organic chemical synthesis are determined. Experimental results and theoretical modeling suggest that the organic chemistry of the satellite is dominated by two processes: photochemistry and energetic particle bombardment. Photochemical reactions of CH4 in the upper atmosphere can account for the presence of C2 hydrocarbons. Reactions initiated at various levels of the atmosphere by cosmic rays, Saturn 'wind', and solar wind particle bombardment of a CH4-N2 atmospheric mixture can account for the UV-visible absorbing stratospheric haze, the reddish appearance of the satellite, and some of the C2 hydrocarbons. In the lower atmosphere photochemical processes will be important if surface temperatures are sufficiently high for gaseous NH3 to exist. It is concluded that the surface of Titan may contain ancient or recent organic matter (or both) produced in the atmosphere.

  15. Advances in analytical chemistry

    Science.gov (United States)

    Arendale, W. F.; Congo, Richard T.; Nielsen, Bruce J.

    1991-01-01

    Implementation of computer programs based on multivariate statistical algorithms makes possible obtaining reliable information from long data vectors that contain large amounts of extraneous information, for example, noise and/or analytes that we do not wish to control. Three examples are described. Each of these applications requires the use of techniques characteristic of modern analytical chemistry. The first example, using a quantitative or analytical model, describes the determination of the acid dissociation constant for 2,2'-pyridyl thiophene using archived data. The second example describes an investigation to determine the active biocidal species of iodine in aqueous solutions. The third example is taken from a research program directed toward advanced fiber-optic chemical sensors. The second and third examples require heuristic or empirical models.

  16. Prebiotic chemistry in clouds

    Science.gov (United States)

    Oberbeck, Verne R.; Marshall, John; Shen, Thomas

    1991-01-01

    The chemical evolution hypothesis of Woese (1979), according to which prebiotic reactions occurred rapidly in droplets in giant atmospheric reflux columns was criticized by Scherer (1985). This paper proposes a mechanism for prebiotic chemistry in clouds that answers Scherer's concerns and supports Woese's hypothesis. According to this mechanism, rapid prebiotic chemical evolution was facilitated on the primordial earth by cycles of condensation and evaporation of cloud drops containing clay condensation nuclei and nonvolatile monomers. For example, amino acids supplied by, or synthesized during entry of meteorites, comets, and interplanetary dust, would have been scavenged by cloud drops containing clay condensation nuclei and would be polymerized within cloud systems during cycles of condensation, freezing, melting, and evaporation of cloud drops.

  17. Prebiotic phosphorus chemistry reconsidered

    Science.gov (United States)

    Schwartz, A. W.; Orgel, L. E. (Principal Investigator)

    1997-01-01

    The available evidence indicates that the origin of life on Earth certainly occurred earlier than 3.5 billion years ago and perhaps substantially earlier. The time available for the chemical evolution which must have preceded this event is more difficult to estimate. Both endogenic and exogenic contributions to chemical evolution have been considered; i.e., from chemical reactions in a primitive atmosphere, or by introduction in the interiors of comets and/or meteorites. It is argued, however, that the phosphorus chemistry of Earth's earliest hydrosphere, whether primarily exogenic or endogenic in origin, was most likely dominated by compounds less oxidized than phosphoric acid and its esters. A scenario is presented for the early production of a suite of reactive phosphonic acid derivatives, the properties of which may have foreshadowed the later appearance of biophosphates.

  18. Rapid automated nuclear chemistry

    International Nuclear Information System (INIS)

    Rapid Automated Nuclear Chemistry (RANC) can be thought of as the Z-separation of Neutron-rich Isotopes by Automated Methods. The range of RANC studies of fission and its products is large. In a sense, the studies can be categorized into various energy ranges from the highest where the fission process and particle emission are considered, to low energies where nuclear dynamics are being explored. This paper presents a table which gives examples of current research using RANC on fission and fission products. The remainder of this text is divided into three parts. The first contains a discussion of the chemical methods available for the fission product elements, the second describes the major techniques, and in the last section, examples of recent results are discussed as illustrations of the use of RANC

  19. Nuclear chemistry progress report

    International Nuclear Information System (INIS)

    During the past year the Nuclear Chemistry Group at Indiana University has concentrated its efforts on (1) the analysis and publication of previous experimental studies and (2) the design and construction of ISiS, a 4π detector for multifragment emission studies. No new experiments were undertaken, rather all of our experimental effort has been directed toward component tests of ISiS, with a goal of beginning measurements with this device in 1992. Research projects that have been largely completed during the last year include: (1) multiple fragment emission studies of the 0.90 and 3.6 GeV 3He + natAg reaction; (2) intermediate-mass-fragment (IMF: 3 ≤ Z ≤ 15) excitation function measurements for the E/A = 20-to-100 MeV 14N + natAg and 197Au reactions, and (3) particle-particle correlation studies for the determination of space-time relationships energy collisions

  20. Beryllium chemistry and processing

    CERN Document Server

    Walsh, Kenneth A

    2009-01-01

    This book introduces beryllium; its history, its chemical, mechanical, and physical properties including nuclear properties. The 29 chapters include the mineralogy of beryllium and the preferred global sources of ore bodies. The identification and specifics of the industrial metallurgical processes used to form oxide from the ore and then metal from the oxide are thoroughly described. The special features of beryllium chemistry are introduced, including analytical chemical practices. Beryllium compounds of industrial interest are identified and discussed. Alloying, casting, powder processing, forming, metal removal, joining and other manufacturing processes are covered. The effect of composition and process on the mechanical and physical properties of beryllium alloys assists the reader in material selection. The physical metallurgy chapter brings conformity between chemical and physical metallurgical processing of beryllium, metal, alloys, and compounds. The environmental degradation of beryllium and its all...

  1. Environmental chemistry of technetium

    International Nuclear Information System (INIS)

    Safe disposal of waste is perceived by public opinion as probably the greatest technical problem of the nuclear industry. This concern derives from the large quantities of radioactivity involved and from the suspicion that man-made barriers are not completely reliable for the lifetime of such waste. Therefore, the biogeochemical cycling of long-lived radionuclides resulting from nuclear power generation represents an important factor influencing decisions regarding the future development of the nuclear industry. As far as technetium is concerned, it should be mentioned that the hazard from the isotope /sup 99/Tc remains practically unchanged for some 30,000 years because of its 2.1x10/sup 5/ year half-life. In this paper the information available on the environmental chemistry of technetium is discussed in order to evaluate the importance of chemical processes in determining the distribution of technetium in the biosphere

  2. Rapid automated nuclear chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, R.A.

    1979-05-31

    Rapid Automated Nuclear Chemistry (RANC) can be thought of as the Z-separation of Neutron-rich Isotopes by Automated Methods. The range of RANC studies of fission and its products is large. In a sense, the studies can be categorized into various energy ranges from the highest where the fission process and particle emission are considered, to low energies where nuclear dynamics are being explored. This paper presents a table which gives examples of current research using RANC on fission and fission products. The remainder of this text is divided into three parts. The first contains a discussion of the chemical methods available for the fission product elements, the second describes the major techniques, and in the last section, examples of recent results are discussed as illustrations of the use of RANC.

  3. Modelling electric discharge chemistry

    International Nuclear Information System (INIS)

    The chemistry occurring in a electric discharge was modelled to predict how it would be influenced by discharge conditions. The discharge was characterized by a calculated Boltzmann electron-energy distribution, from which rate constants for electron-molecule processes in air were determined. These rate constants were used in a chemical kinetics calculation that also included reactions between neutral molecules, ions, free radicals and electronically excited species. The model describes how the discharge chemistry was influenced by humidity, electric field, electron number density, and concentrations of key reagents identified in the study. The use of an electric discharge to destroy airborne contaminant molecules was appraised, the targeted contaminants being CF2Cl2, HCN, and SO2. The modelling results indicate that an electric discharge should be able to remove HCN and CF2Cl2 effectively, especially if the discharge conditions have been optimized. Effective destruction is achieved with a moderate electric field (over 1 x 10-15 V.cm2), a substantial electron number density (over 1 x 1012 cm-3), and the presence of H20 in the process air. The residence time in the discharge was also shown to be important in contaminant destruction. An attempt was made to explain the results of the electric discharge abatement of SO2, a component of a simulated flue-gas mixture. Results from the model indicate that the discharge parameters that increase the concentration of hydroxyl radical also increase the rate of decomposition of SO2. An objective of the study was to explain the apparent enhancement of SO2 destruction by the presence of a small amount of NO2. It was thought that a likely explanation would be the stabilization of HOSO2, an important intermediate in the oxidation of SO2 by NO2. (49 figs., 14 tabs., 75 refs.)

  4. Nanoplasmonics tuned ``click chemistry''

    Science.gov (United States)

    Tijunelyte, I.; Guenin, E.; Lidgi-Guigui, N.; Colas, F.; Ibrahim, J.; Toury, T.; Lamy de La Chapelle, M.

    2016-03-01

    Nanoplasmonics is a growing field of optical condensed matter science dedicated to optical phenomena at the nanoscale level in metal systems. Extensive research on noble metallic nanoparticles (NPs) has emerged within the last two decades due to their ability to keep the optical energy concentrated in the vicinity of NPs, in particular, the ability to create optical near-field enhancement followed by heat generation. We have exploited these properties in order to induce a localised ``click'' reaction in the vicinity of gold nanostructures under unfavourable experimental conditions. We demonstrate that this reaction can be controlled by the plasmonic properties of the nanostructures and we propose two physical mechanisms to interpret the observed plasmonic tuning of the ``click'' chemistry.Nanoplasmonics is a growing field of optical condensed matter science dedicated to optical phenomena at the nanoscale level in metal systems. Extensive research on noble metallic nanoparticles (NPs) has emerged within the last two decades due to their ability to keep the optical energy concentrated in the vicinity of NPs, in particular, the ability to create optical near-field enhancement followed by heat generation. We have exploited these properties in order to induce a localised ``click'' reaction in the vicinity of gold nanostructures under unfavourable experimental conditions. We demonstrate that this reaction can be controlled by the plasmonic properties of the nanostructures and we propose two physical mechanisms to interpret the observed plasmonic tuning of the ``click'' chemistry. Electronic supplementary information (ESI) available: NMR study on reaction initiation, SERS spectra and temperature calculations. See DOI: 10.1039/c5nr09018k

  5. Local Evaluation of Chemistry Journals

    Science.gov (United States)

    Kraus, Joseph R.; Hansen, Rachel

    2008-01-01

    This paper reports on the evaluation of local usage statistics of a specific set of chemistry journals at the University of Denver in Colorado, USA. The objective of the study is to demonstrate that commercial publishers in chemistry charge considerably more for their journals than those from the non-commercial sector. There are three variables…

  6. HMI scientific report - chemistry 1988

    International Nuclear Information System (INIS)

    Results of the R and D activities are reported, dealing with the following subjects: Interface processes and energy conversion, high-energy photochemistry and radiation chemistry as well as trace elements chemistry. A list of publications and lectures is added and gives a view on results obtained in research and development. (EF)

  7. Chemistry Teachers' Views of Creativity

    Science.gov (United States)

    Akkanat, Çigdem; Gökdere, Murat

    2015-01-01

    The purpose of this study was to determine chemistry teachers' views of creativity. In this study, phenomenology method, one of the qualitative research patterns, was used. The participants of this study were 13 chemistry teachers working in Amasya. A semi-structured interview form was used for data collection. By using NVivo 9 qualitative…

  8. News from Online: Green Chemistry

    Science.gov (United States)

    Uffelman, Erich S.

    2004-01-01

    Green chemistry closely relates to energy and environmental problems, and includes the promotion of environmental friendly products and systems within the framework of renewable resources. Various websites on green chemistry are reviewed, one of which lists the 12 commandments of this particular subject.

  9. Introducing Relativity into Quantum Chemistry

    Science.gov (United States)

    Li, Wai-Kee; Blinder, S. M.

    2011-01-01

    It is not often realized by chemists that the special theory of relativity is behind several aspects of quantum chemistry. The Schrdinger equation itself is based on relations between space-time and energy-momentum four vectors. Electron spin is, of course, the most obvious manifestation of relativity. The chemistry of some heavy elements is…

  10. A Cooperative Chemistry Project: Chemsource.

    Science.gov (United States)

    Giles, Catherine Y.

    1994-01-01

    Chemsource is a set of instructional materials designed as a resource for high school chemistry teachers, particularly those not trained in the discipline. Materials consist of a videotape demonstrating both generic and science-specific teaching skills and a textbook on varied chemistry topics, including suggested teaching techniques and…

  11. Contextualising Nanotechnology in Chemistry Education

    Science.gov (United States)

    O'Connor, Christine; Hayden, Hugh

    2008-01-01

    In recent years nanotechnology has become part of the content of many undergraduate chemistry and physics degree courses. This paper deals with the role of contextualisation of nanotechnology in the delivery of the content, as nanotechnology is only now being slowly integrated into many chemistry degree courses in Ireland and elsewhere. An…

  12. Crocodile Chemistry. [CD-ROM].

    Science.gov (United States)

    1999

    This high school chemistry resource is an on-screen chemistry lab. In the program, students can experiment with a huge range of chemicals, choosing the form, quantity and concentrations. Dangerous or difficult experiments can be investigated safely and easily. A vast range of equipment can be set up, and complex simulations can be put together and…

  13. Sustainable Agriculture: Towards a Conflict Management Based Agricultural Extension

    OpenAIRE

    Mostafa Ahmadvand; Ezatollah Karami

    2007-01-01

    This study aims to provide an alternative conceptual framework for agricultural extension, which can deal with environmental scarcity, conflict and challenges in sustainable way. For this purpose, a brief history of agricultural extension and conflict is introduced and then conflict management approaches are reviewed. Finally, an alternative model is proposed to use conflict management approach as a basis for agricultural extension. The implication of conflict management approach in agr...

  14. Comet Halley and interstellar chemistry

    International Nuclear Information System (INIS)

    How complex is the chemistry of the interstellar medium? How far does it evolve and how has it interacted with the chemistry of the solar system? Are the galactic chemical processes destroyed, preserved, or even enhanced in comets? Are biogenic molecules formed in space and have the formation mechanisms interacted in any way with prebiotic organic chemical processes on the early earth? Radio molecular studies of comets are important for probing deep into the coma and nuclear region and thus may help answer these questions. Comets are believed to be pristine samples of the debris left from the formation of the solar system and may have been the carrier between interstellar and terrestrial prebiotic chemistries. Recent observations of Comet Halley and subsequent comets have given the author an excellent opportunity to study the relationship between interstellar molecular chemistry and cometary chemistry

  15. Sustainable Agriculture: Towards a Conflict Management Based Agricultural Extension

    Science.gov (United States)

    Ahmadvand, Mostafa; Karami, Ezatollah

    This study aims to provide an alternative conceptual framework for agricultural extension, which can deal with environmental scarcity, conflict and challenges in sustainable way. For this purpose, a brief history of agricultural extension and conflict is introduced and then conflict management approaches are reviewed. Finally, an alternative model is proposed to use conflict management approach as a basis for agricultural extension. The implication of conflict management approach in agricultural extension is far-reaching: it requires new modes of analysis and different roles and tasks.

  16. Urban agriculture in Botswana

    Directory of Open Access Journals (Sweden)

    Aloysius Clemence Mosha

    2016-02-01

    Full Text Available Botswana, a middle-income country, is experiencing a sluggish economic growth and a rapid urbanisation which has brought in its wake high unemployment, poverty and food insecurity. This has led some people to engage in subsistence and commercial urban and peri-urban agriculture (UPA to address these problems. However, in spite of its known advantages, uptake of UPA has been low for a number of reasons including: high GDP before the economic meltdown of recent years; a harsh climate; lack of water; poor access to land; and over-reliance on generous government handouts. Nevertheless, the extent of its practice and its contribution to food security – albeit modest – shows that it is a sector that needs to be encouraged and supported. Both central and local government can play a big role by providing land and infrastructure, and also by implementing an enabling policy and regulatory environment which promotes small- and medium-scale urban food production.

  17. Agricultural drainage water quality

    International Nuclear Information System (INIS)

    'Full text:' Agricultural drainage systems have been identified as potential contributors of non-point source pollution. Two of the major concerns have been with nitrate-nitrogen (NO3 - -N) concentrations and bacteria levels exceeding the Maximum Acceptable Concentration in drainage water. Heightened public awareness of environmental issues has led to greater pressure to maintain the environmental quality of water systems. In an ongoing field study, three experiment sites, each with own soil properties and characteristics, are divided into drainage plots and being monitored for NO3 - -N and fecal coliforms contamination. The first site is being used to determine the impact of the rate of manure application on subsurface drainage water quality. The second site is being used to determine the difference between hog manure and inorganic fertilizer in relation to fecal coliforms and NO3-N leaching losses under a carrot rotation system. The third site examines the effect of timing of manure application on water quality, and is the only site equipped with a surface drainage system, as well as a subsurface drainage system. Each of the drains from these fields lead to heated outflow buildings to allow for year-round measurements of flow rates and water samples. Tipping buckets wired to data-loggers record the outflow from each outlet pipe on an hourly basis. Water samples, collected from the flowing drains, are analyzed for NO3 - -N concentrations using the colorimetric method, and fecal coliforms using the Most Probable Number (MPN) method. Based on this information, we will be able better positioned to assess agricultural impacts on water resources which will help towards the development on industry accepted farming practices. (author)

  18. Water Depletion Threatens Agriculture

    Science.gov (United States)

    Brauman, K. A.; Richter, B. D.; Postel, S.; Floerke, M.; Malsy, M.

    2014-12-01

    Irrigated agriculture is the human activity that has by far the largest impact on water, constituting 85% of global water consumption and 67% of global water withdrawals. Much of this water use occurs in places where water depletion, the ratio of water consumption to water availability, exceeds 75% for at least one month of the year. Although only 17% of global watershed area experiences depletion at this level or more, nearly 30% of total cropland and 60% of irrigated cropland are found in these depleted watersheds. Staple crops are particularly at risk, with 75% of global irrigated wheat production and 65% of irrigated maize production found in watersheds that are at least seasonally depleted. Of importance to textile production, 75% of cotton production occurs in the same watersheds. For crop production in depleted watersheds, we find that one half to two-thirds of production occurs in watersheds that have not just seasonal but annual water shortages, suggesting that re-distributing water supply over the course of the year cannot be an effective solution to shortage. We explore the degree to which irrigated production in depleted watersheds reflects limitations in supply, a byproduct of the need for irrigation in perennially or seasonally dry landscapes, and identify heavy irrigation consumption that leads to watershed depletion in more humid climates. For watersheds that are not depleted, we evaluate the potential impact of an increase in irrigated production. Finally, we evaluate the benefits of irrigated agriculture in depleted and non-depleted watersheds, quantifying the fraction of irrigated production going to food production, animal feed, and biofuels.

  19. Water and Agriculture

    Directory of Open Access Journals (Sweden)

    Wulf Klohn

    1999-10-01

    Full Text Available The growing scarcity of water resources causes concern, especially with reference to agriculture-related applications. Such scarcity is not due to hydrological reasons, but goes back to the dynamics of human society and the way in which the resource is used. Thisarticle emphasizes the basic facts of this dynamic. For instance, while total quantity of water available yearly on our planet has not changed significantly, the human population has increased greatly –consequently, the quantity of water available per person is inferior.Natural disasters multiply themselves and have a greater resonance, perhaps helped by a climatic change, and their impact on society is dramatic. The human beings affected by disasters are generally not only the poorest, but are constrained to living on steep hills,along river beds that easily flood, and in arid regions of scarce productive potential. Beyond this, the volume of water appropriated in one way or another for human use is already considerable and the rhythm of water appropriation cannot be extended towards the future. Irrigation for agriculture itself amounts to about 70% of all water extraction. Our civilization, capable of exploring the solar system, has the technological solutions to the water problems, but the levels of costs and of the necessary social organization for their application make these solutions available only to the richest societies. The technical, economic and social solutions to overcome the water global crisis exist, but their application requires the existence of a political will, and, in many cases, of international cooperation. At present, such political will appears hesitant, and multilateral international cooperation is undergoing a deep crisis. It is necessary for a public opinion to be formed on these topics so that it can find expression at a political level.

  20. Proceedings of the 17. Annual Meeting of the Brazilian Chemistry Society; 7. National Symposium on Inorganic Chemistry. Abstracts

    International Nuclear Information System (INIS)

    These 17. Annual Meeting of the Brazilian Chemistry Society and 7. National Symposium on Inorganic Chemistry present several subjects of different interests for the participants, including sections about inorganic chemistry; organic chemistry; environmental chemistry; technological chemistry; electrochemistry; physical chemistry; photochemistry; chemical education; natural products; analytical chemistry and biological chemistry. (C.G.C.)

  1. Online educational repositories for promoting agricultural knowledge

    OpenAIRE

    C.I. Costopoulou; M.S. Ntaliani; M.T. Maliappis; R. Georgiades; A.B. Sideridis

    2010-01-01

    Towards promoting sustainable agriculture and economic growth, the development of the agricultural workforce and set up of innovative agricultural systems are required. Agricultural educational repositories are systems used for storing, reusing and sharing agricultural learning resources. They contribute to agricultural education at different educational levels and target groups. Thus, this paper firstly provides an overview of Institutional repositories (IRs) and Open Access Archives (OAAs) ...

  2. Papers of All-Polish Conference on Nuclear Techniques in Industry, Medicine, Agriculture and Environmental Protection

    International Nuclear Information System (INIS)

    These proceedings comprise papers presented at All-Polish Conference on nuclear techniques in industry, medicine, agriculture and environmental protection. Most of the papers are in the field of uses of radiation sources and particle beams in industry, radiation chemistry, nuclear medicine and dosimetry, environmental sciences

  3. Fertilia: a European International Cooperation (INCO EU) project for monitoring trace elements in agricultural ecosystems

    Czech Academy of Sciences Publication Activity Database

    Marmiroli, N.; Maestri, E.; Mucchino, C.; Antonioli, G.; Marmiroli, M.; Izquierdo, C. G.; Hernandez, T.; Waclawek, W.; Mocko, A.; Bozym, M.; Nowak, A.; Nowak, J.; Večeřa, Zbyněk; Dočekal, Bohumil

    2001-01-01

    Roč. 13, č. 1 (2001), s. 41-54. ISSN 1120-4826 Grant ostatní: Copernicus(BE) ERB IC-15-CT98-0124 Institutional research plan: CEZ:AV0Z4031919 Keywords : monitoring * trace elements * agricultural ecosystems Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 0.207, year: 2001

  4. Green chemistry at work

    Energy Technology Data Exchange (ETDEWEB)

    Frost, J. [Michigan State Univ., East Lansing, MI (United States)

    1994-12-31

    The 1.7 billion pounds of benzene produced each year in the US provide one measure of its utility. At the same time, there are a number of environmental reasons for avoiding the use of benzene in chemical manufacture. Perhaps most compelling: benzene is a potent carcinogen. Scrutiny of many of the chemicals derived from benzene reveals that each molecule contains at least one oxygen atom while benzene completely lacks oxygen atoms. Introduction of oxygen to make up for this lack can require processes that are environmentally problematic. One of the steps used to introduce oxygen atoms during manufacture of adipic acid, a component of Nylon 66, is responsible for 10% of the annual global increase in atmospheric nitrous oxide. This by-product is a causative agent of atmospheric ozone depletion and has been implicated in global warming. With support from EPA and the National Science Foundation, alternative manufacturing processes are being explored. By these new methods, chemicals usually created from benzene are made instead from nontoxic glucose, a component of table sugar. Unlike benzene, glucose is obtained from such renewable resources as plant starch and cellulose. ``Green`` manufacturing routes ideally should lead to chemicals that are economically competitive with chemicals produced by traditional methods. For two chemicals of roughly comparable cost, the consumer or producer can then be realistically expected to choose in favor of the chemical produced by a ``green`` process. Projections indicate that catechol and hydroquinone can be biocatalytically produced from glucose at a cost competitive with current market prices. Synthesis of chemicals from glucose using biocatalysis offers the premise of achieving fundamental environmental improvement while increasing the demand for agricultural products. In the final analysis, what is good for the environment can also be good for American agriculture.

  5. Isotopes and radiations in agriculture

    International Nuclear Information System (INIS)

    Some of the spectacular advances in agriculture in developing nations have stimulated wide interest both in basic as well as adaptive research and in harnessing all the tools that science can offer for progress of agriculture. The nuclear tools are relevant in this respect and also offer particular promise in some areas. Ionising radiations and isotopes have immense applications in agriculture. Both radioisotopes and stable isotopes are being used

  6. Photovoltaic application in modern agriculture

    OpenAIRE

    Wang, Huaxin; Muñoz Garcia, Miguel Angel; Moreda Cantero, Guillermo P.

    2015-01-01

    The use of photovoltaic (PV) electricity in modern agriculture has shown its advantages since the 1970s when it was possible to obtain a substantial green energy without the pollution by burning fossil fuels (coal, oil or natural gas) or the threaten of nuclear accident. Due to the price descent of the PV system, some new applications are becoming economically attractive, like the combination of PV and agriculture. Meanwhile, the use of agricultural soils contributes to making photovoltaic a ...

  7. THE ENVIRONMENTAL IMPLICATIONS OF AGRICULTURE

    OpenAIRE

    Bromley, Daniel W.

    1996-01-01

    There are three general classes of environmental implications from agriculture: (1) amenity implications; (2) habitat implications; and (3) ecological implications. Environmental "benefits" or "costs" from agriculture require a prior specification of the norm against which the status quo is to be compared. Agriculture is no longer simply an activity that produces commodities for local, regional, national, or international markets. Indeed, in the OECD countries, commodity abundance, not commod...

  8. Sustainable agriculture in the picture

    International Nuclear Information System (INIS)

    Sustainable agriculture in the picture provides a systematic overview of the available data that are relevant for debate on transitions towards sustainable agriculture. Review for the agrocomplex, greenhouse horticulture, dairy farming and pig farming. Indicators on economy, environment, nature, animal welfare, human and animal health. Results achieved in practice for the three dimensions of sustainable agriculture, namely economics ('profit'), ecology ('planet') and socio-cultural ('people')

  9. Organic Agriculture Research in Uganda

    OpenAIRE

    Ssekyewa, Charles

    2005-01-01

    Development of Organic Agriculture stem from the demand for safe and environmentally friendly food, which arose from outcome mistakes made by the Green Revolution that failed to achieve sustainable food security. Organic Agriculture awareness started from the north where severe negative impacts of the Green Revolution exist. In order to counteract such negative effects to the environment, together with early awareness of the need to conserve the environment, Organic Agriculture spread to the ...

  10. Assessing environmental management in agriculture

    OpenAIRE

    Bachev, Hrabrin

    2012-01-01

    This paper incorporates interdisciplinary New Institutional Economics and suggests a holistic framework for assessing the forms and efficiency of environmental management in agriculture. First, it defines environmental management as a specific system of social order regulating behaviour and relations of various agents related to natural environment, and environmental management in agriculture as eco-management associated with agricultural production. Second, it specifies spectrum of modes and...

  11. Economics, Policy, and Organic Agriculture

    OpenAIRE

    Ingemann, Jan Holm

    2009-01-01

    Is organic agriculture so special that special social theories and methods are needed? The article investigates the question in two steps: First, the article address the question whether agriculture is special. Second, whether organic agriculture is special. It is concluded that from an economic point of view new research suggests that the organic sector can only be conceptualized and understood in the general social context. If the sector is analyzed as independent of general social context,...

  12. Linking nutrition-health-agriculture

    OpenAIRE

    Ghosh, S; Griffiths, J. K.; Webb, P.

    2013-01-01

    Agricultural production is intimately linked with health and nutrition as a form of income, a source of food, and a cause of disease. Citing a variety of previous studies, this presentation demonstrates the complexity of the relationships among agriculture and food consumption, food safety, infection, and stunting. The authors demonstrate that increasing agricultural production does not necessarily result in improved nutrition: Although more food may be available, this greater yield may suppl...

  13. Green Agriculture - features and agricultural policy measures for the transition to a sustainable agriculture

    Directory of Open Access Journals (Sweden)

    Cornelia Nistor

    2015-12-01

    Full Text Available Agriculture is one of the most important economic activities in each country or area, as it is in close correlation with all other the other economic activities, in a whole which must be structured so as to achieve a more efficient planning and organization of the territory. The practice of a traditional agriculture, based on industrialization, affects the natural environment through emissions of pollutants, waste and deforestation which together affects biodiversity. Green Agriculture suppose to empower managers to widespread the use of fertilizers, to improve the crop rotation, to realize a more efficient water consumption, to improve the storage methods and the supply chain of products. Agricultural policies are closely interrelated with environmental policies as agricultural activities have a considerable influence on the environment. The efficiency of agricultural policies is reflected in monetary transfers between agriculture and other economic sectors, in the costs due to the reallocation of the resources between different agricultural and non-agricultural activities and in the realized gains. Currently there is a constant concern of the governments for the transition to a green agriculture, and most countries recognize the importance of achieving sustainable economic development.

  14. Alcohol combustion chemistry

    KAUST Repository

    Sarathy, Mani

    2014-10-01

    Alternative transportation fuels, preferably from renewable sources, include alcohols with up to five or even more carbon atoms. They are considered promising because they can be derived from biological matter via established and new processes. In addition, many of their physical-chemical properties are compatible with the requirements of modern engines, which make them attractive either as replacements for fossil fuels or as fuel additives. Indeed, alcohol fuels have been used since the early years of automobile production, particularly in Brazil, where ethanol has a long history of use as an automobile fuel. Recently, increasing attention has been paid to the use of non-petroleum-based fuels made from biological sources, including alcohols (predominantly ethanol), as important liquid biofuels. Today, the ethanol fuel that is offered in the market is mainly made from sugar cane or corn. Its production as a first-generation biofuel, especially in North America, has been associated with publicly discussed drawbacks, such as reduction in the food supply, need for fertilization, extensive water usage, and other ecological concerns. More environmentally friendly processes are being considered to produce alcohols from inedible plants or plant parts on wasteland. While biofuel production and its use (especially ethanol and biodiesel) in internal combustion engines have been the focus of several recent reviews, a dedicated overview and summary of research on alcohol combustion chemistry is still lacking. Besides ethanol, many linear and branched members of the alcohol family, from methanol to hexanols, have been studied, with a particular emphasis on butanols. These fuels and their combustion properties, including their ignition, flame propagation, and extinction characteristics, their pyrolysis and oxidation reactions, and their potential to produce pollutant emissions have been intensively investigated in dedicated experiments on the laboratory and the engine scale

  15. Bentonite porewater chemistry

    International Nuclear Information System (INIS)

    Porewater composition in a compacted bentonite is dependent on the composition of the surrounding groundwater, and on the characteristics of the bentonite itself. Two mechanisms through which bentonite influences the respective porewater composition are distinguished: surface chemical reactions (ion exchange, surface complexation) on smectite and dissolution of minerals and soluble impurities included in bentonite. This report provides the results of different activities related to the definition of porewater chemistry through the use of geochemical models: 1) review of thermodynamic model on ion exchange reaction, 2) modeling of bentonite-water interactions under aerobic conditions, 3) performance of sensitivity analyses of key parameters in the bentonite model, 4) model simulation of bentonite porewater chemistry in the engineered barrier system under repository conditions. Experimental information of bentonite-water interaction allowed the determination of soluble impurities in the bentonite, and the knowledge of these impurities is important for predictive modeling. For the impurities of Kunigel-V1, 0.38% of CaSO4, 0.0011% of NaCl and 0.0044% of KCl were determined. The sensitivity analyses resulted in that the presence of calcite, CaSO4 and pyrite strongly influences the pH in the compacted bentonite, and the pH in compacted bentonite is buffered by the acid/base equilibria at the Na-smectite surface as well. Through the model calculations, some remarks on the expected trends for the long term behavior can be made like that the pH in compacted bentonite is expected to increase with increasing number of water exchange cycles, as long as CaCO3 contributes to the pH buffering capacity, due to slow depletion of the soluble impurities in the bentonite. The pH of the porewater, however, lies in all cases (but in the presence of CaCo3) between 5.6 and 9.5. Based on the findings discussed above, a large number of calculations were carried out to support the definition

  16. Chemistry of Technetium

    International Nuclear Information System (INIS)

    Precise and reliable thermodynamic constants for the oxidation/reduction relationships of the technetium ions in various environments are necessary to model the transport behaviour of 99 Tc from the nuclear waste repositories to the bio and geosphere. The current knowledge of the Tc chemistry indicates that the most important oxidation states of Tc in natural environment would be VII in oxidant conditions and IV, in an-oxidant media. However, even the value of the formal oxidation potential of the Tc O4-/Tc (IV) couple in simple media is questionable, because it relies only upon one kind of data: the values of the potential of the half electrochemical cell Tc O4-/Tc O2. These potentials are reversible, but sparingly soluble Tc O2 is not in fast equilibrium with other Tc (IV) complexes. The measured potentials are surely Tc O4-/Tc O2 potentials, but not the Tc O4-/Tc(IV) potentials if Tc O2 is not the thermodynamically stable form of Tc (IV). Quantitative data for the Tc O2 equilibria with Tc (IV) complexes are difficult to obtain because of the slowness of the ligand exchange reactions and the general lack of knowledge of the chemistry of the VIIb group tetravalent ions. The present investigation deals with a new approach for the determination of the formal oxidation potential of the Tc O4-/Tc (IV) couple. Tc was used at trace level, in order to avoid the kinetic and thermodynamic sinks made by insoluble Tc O2. Oxidation and reduction of Tc were governed by controlling the ion concentration of a fast electron exchanger couple of which the formal potential has been measured carefully, presently Fe (III)/Fe (II). Distribution ratios of Tc between aqueous and immiscible organic solution of tetra-phenyl arsenic chloride (TPA.Cl) into chloroform served as the probe for the advancement of oxidation and reduction reaction. In these solvent, only Tc (VII) as Tc O4- anions is extracted. (authors)

  17. COST : action chemistry conference on supramolecular chemistry in water

    OpenAIRE

    Magri, David C.

    2014-01-01

    Scientists and chemists from 18 countries gathered in Malta for the 3rd Scientific Meeting on Supramolecular Chemistry in Water between the 9 − 11th of November 2013 at the Old University Building on St Paul Street in Valletta

  18. Incorporation of Medicinal Chemistry into the Organic Chemistry Curriculum

    Science.gov (United States)

    Forbes, David C.

    2004-01-01

    Application of concepts presented in organic chemistry lecture using a virtual project involving the sythesis of medicinally important compounds is emphasized. The importance of reinforcing the concepts from lecture in lab, thus providing a powerful instructional means is discussed.

  19. Advanced Chemistry Basins Model

    Energy Technology Data Exchange (ETDEWEB)

    Blanco, Mario; Cathles, Lawrence; Manhardt, Paul; Meulbroek, Peter; Tang, Yongchun

    2003-02-13

    The objective of this project is to: (1) Develop a database of additional and better maturity indicators for paleo-heat flow calibration; (2) Develop maturation models capable of predicting the chemical composition of hydrocarbons produced by a specific kerogen as a function of maturity, heating rate, etc.; assemble a compositional kinetic database of representative kerogens; (3) Develop a 4 phase equation of state-flash model that can define the physical properties (viscosity, density, etc.) of the products of kerogen maturation, and phase transitions that occur along secondary migration pathways; (4) Build a conventional basin model and incorporate new maturity indicators and data bases in a user-friendly way; (5) Develop an algorithm which combines the volume change and viscosities of the compositional maturation model to predict the chemistry of the hydrocarbons that will be expelled from the kerogen to the secondary migration pathways; (6) Develop an algorithm that predicts the flow of hydrocarbons along secondary migration pathways, accounts for mixing of miscible hydrocarbon components along the pathway, and calculates the phase fractionation that will occur as the hydrocarbons move upward down the geothermal and fluid pressure gradients in the basin; and (7) Integrate the above components into a functional model implemented on a PC or low cost workstation.

  20. Exoplanet Equilibrium Chemistry Calculations

    Science.gov (United States)

    Blumenthal, Sarah; Harrington, J.; Bowman, M.; Blecic, J.

    2013-10-01

    Recently, Agundez et al. (2012, A&A 548, A73) used a chemical kinetics code to study a model HD 209458b (equilibrium temperature of 1450 K, assuming full redistribution and 0 albedo). They found that thermochemistry dominates most of the dayside, but that significant compositional gradients may exist across the dayside. We calculate equilibrium-chemistry molecular abundances for several model exoplanets, using NASA's open-source Chemical Equilibrium Abundances code (McBride and Gordon 1996). We vary the degree of radiation redistribution to the dark side, ranging from total redistribution to instantaneous reradiation. Atomically, both the solar abundance multiple and the carbon fraction vary. Planet substellar temperatures range from just above 1200 K, where photochemistry should no longer be important, to those of hot planets (3000 K). We present synthetic abundance images for the key spectroscopic molecules CO, CH4, and H2O for several hot-Jupiter model planets. This work was supported by the NASA Planetary Atmospheres grant NNX12AI69G.

  1. Nuclear chemistry progress report

    International Nuclear Information System (INIS)

    This is the annual progress report for the Indiana University nuclear chemistry program for the 1992/1993 year. Accomplishments include the construction, testing, and initial experimental runs of the Indiana Silicon Sphere (ISiS) 4π charged particle detector. ISiS is designed to study energy dissipation and multifragmentation phenomena in light-ion-induced nuclear reactions at medium-to-high energies. Its second test run was to examine 3.6 GeV 3He beam reactions at Laboratoire National Saturne (LNS) in Saclay. The development and deployment of this system has occupied a great deal of the groups effort this reporting period. Additional work includes: calculations of isotopic IMF yields in the 4He + 116,124Sn reaction; cross sections for A = 6 - 30 fragments from the 4He + 28Si reaction at 117 and 198 MeV; charging effects of passivated silicon detectors; neck emission of intermediate-mass fragments in the fission of hot heavy nuclei

  2. Atmospheric and aerosol chemistry

    International Nuclear Information System (INIS)

    This series presents critical reviews of the present position and future trends in modern chemical research. Short and concise reports on chemistry, each written by the world renowned experts. Still valid and useful after 5 or 10 years. More information as well as the electronic version of the whole content available at: springerlink.com. Christian George, Barbara D'Anna, Hartmut Herrmann, Christian Weller, Veronica Vaida, D. J. Donaldson, Thorsten Bartels-Rausch, Markus Ammann Emerging Areas in Atmospheric Photochemistry. Lisa Whalley, Daniel Stone, Dwayne Heard New Insights into the Tropospheric Oxidation of Isoprene: Combining Field Measurements, Laboratory Studies, Chemical Modelling and Quantum Theory. Neil M. Donahue, Allen L. Robinson, Erica R. Trump, Ilona Riipinen, Jesse H. Kroll Volatility and Aging of Atmospheric Organic Aerosol. P. A. Ariya, G. Kos, R. Mortazavi, E. D. Hudson, V. Kanthasamy, N. Eltouny, J. Sun, C. Wilde Bio-Organic Materials in the Atmosphere and Snow: Measurement and Characterization V. Faye McNeill, Neha Sareen, Allison N. Schwier Surface-Active Organics in Atmospheric Aerosols.

  3. Chemistry in one dimension.

    Science.gov (United States)

    Loos, Pierre-François; Ball, Caleb J; Gill, Peter M W

    2015-02-01

    We report benchmark results for one-dimensional (1D) atomic and molecular systems interacting via the Coulomb operator |x|(-1). Using various wavefunction-type approaches, such as Hartree-Fock theory, second- and third-order Møller-Plesset perturbation theory and explicitly correlated calculations, we study the ground state of atoms with up to ten electrons as well as small diatomic and triatomic molecules containing up to two electrons. A detailed analysis of the 1D helium-like ions is given and the expression of the high-density correlation energy is reported. We report the total energies, ionization energies, electron affinities and other physical properties of the many-electron 1D atoms and, using these results, we construct the 1D analog of Mendeleev's periodic table. We find that the 1D periodic table contains only two groups: the alkali metals and the noble gases. We also calculate the dissociation curves of several 1D diatomics and study the chemical bond in H2(+), HeH(2+), He2(3+), H2, HeH(+) and He2(2+). We find that, unlike their 3D counterparts, 1D molecules are primarily bound by one-electron bonds. Finally, we study the chemistry of H3(+) and we discuss the stability of the 1D polymer resulting from an infinite chain of hydrogen atoms. PMID:25518906

  4. Computational Chemistry and Lubrication

    Science.gov (United States)

    Zehe, Michael J.

    1998-01-01

    Members of NASA Lewis Research Center's Tribology and Surface Science Branch are applying high-level computational chemistry techniques to the development of new lubrication systems for space applications and for future advanced aircraft engines. The next generation of gas turbine engines will require a liquid lubricant to function at temperatures in excess of 350 C in oxidizing environments. Conventional hydrocarbon-based lubricants are incapable of operating in these extreme environments, but a class of compounds known as the perfluoropolyether (PFAE) liquids (see the preceding illustration) shows promise for such applications. These commercially available products are already being used as lubricants in conditions where low vapor pressure and chemical stability are crucial, such as in satellite bearings and composite disk platters. At higher temperatures, however, these compounds undergo a decomposition process that is assisted (catalyzed) by metal and metal oxide bearing surfaces. This decomposition process severely limits the applicability of PFAE's at higher temperatures. A great deal of laboratory experimentation has revealed that the extent of fluid degradation depends on the chemical properties of the bearing surface materials. Lubrication engineers would like to understand the chemical breakdown mechanism to design a less vulnerable PFAE or to develop a chemical additive to block this degradation.

  5. Computational chemistry research

    Science.gov (United States)

    Levin, Eugene

    1987-01-01

    Task 41 is composed of two parts: (1) analysis and design studies related to the Numerical Aerodynamic Simulation (NAS) Extended Operating Configuration (EOC) and (2) computational chemistry. During the first half of 1987, Dr. Levin served as a member of an advanced system planning team to establish the requirements, goals, and principal technical characteristics of the NAS EOC. A paper entitled 'Scaling of Data Communications for an Advanced Supercomputer Network' is included. The high temperature transport properties (such as viscosity, thermal conductivity, etc.) of the major constituents of air (oxygen and nitrogen) were correctly determined. The results of prior ab initio computer solutions of the Schroedinger equation were combined with the best available experimental data to obtain complete interaction potentials for both neutral and ion-atom collision partners. These potentials were then used in a computer program to evaluate the collision cross-sections from which the transport properties could be determined. A paper entitled 'High Temperature Transport Properties of Air' is included.

  6. Prebiotic chemistry - Lecture 2

    International Nuclear Information System (INIS)

    The nucleic acids and proteins are at the basis of all life. The energy source on the primitive earth acting on the earth's early atmosphere are believed to have produced all the molecules necessary for life. Laboratory experiments over the last four decades have clearly established the prebiotic synthesis of these components, amino acids, purines, pyrimidines, carbohydrates. The mechanisms of polymerization have also been outlined. We thus have a sequence from atoms to small molecules to the large molecules which are necessary for the emergence of life. The analysis of meteorites has given us fresh evidence that these reactions which we have presumed to have taken place on the primitive earth may have also occurred in the early solar system. The analysis of carbonaceous chondrites has given us unmistakable evidence for the presence of these molecules in outer space. Recent observational and theoretical studies have also pointed out that comets may be the location for prebiotic reactions and may also have contributed to organic matter on the primitive earth. The radio astronomers studying interstellar media have also provided us with ample evidence that there are a large number of organic molecules in interstellar space. Organic chemistry appears to be commonplace in the universe. (author)

  7. Pore-water chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Vinsot, A. [Agence Nationale pour la Gestion des Dechets Radioactifs, Lab. de Souterrain de Meuse/Haute-Marne, 55 - Bure (France); Appelo, C.A.J. [Valeriusstraat 11, Amsterdam (Netherlands); Cailteau, C. [LEM, ENSG/INPL, 54 - Vandoeuvre-les-Nancy (France); Cailteau, C. [G2R-CREGU, UMR 7566 CNRS, 54 - Vandoeuvre-les-Nancy (France); Cailteau, C. [Andra - Agence Nationale pour la Gestion des Dechets Radioactifs, 92 - Chatenay Malabry (France); Mettler, S.; Wersin, P. [NAGRA, CH-5430 Wettingen (Switzerland); Canniere, P. de [Studiecentrum voor Kernenergie - Centre d' Etude de l' Energie Nucleaire, Mol (Belgium); Gabler, H.E. [BGR, Hannover (Germany); Gaucher, E.C.; Tournassat, C. [Bureau de Recherches Geologiques et Minieres (BRGM), 45 - Orleans (France); Jacquot, E.; Altmann, S. [Agence Nationale pour la Gestion des Dechets Radioactifs (DS/TR), 92 - Chatenay Malabry (France); Vinsot, A. [Agence Nationale pour la Gestion des Dechets Radioactifs, Lab. de Recherche Souterrain de Meuse/Haute-Marne, 55 - Bure (France); Courdouan, A.; Christl, I.; Kretzschmar, R. [Institute of Biogeochemistry and Pollutant Dynamics, Dept. of Environmental Sciences, ETH Zurich, CHN (Switzerland); Wersin, P. [National Cooperative for the Disposal of Radioactive Waste (Nagra), Wettingen (Switzerland); Savoye, S.; Matray, J.M.; Wittebroodt, Ch.; Cabrera, J.; Bensenouci, F. [Institut de Radioprotection et de Surete Nucleaire, 92 - Fontenay aux Roses (France); Michelot, J.L.; Bensenouci, F. [Paris-11 Univ., UMR IDES CNRS, 91 - Orsay (France); Waber, H.S. [Rock-Water Interaction (RWI), Inst. of Geological Sciences, Bern (Switzerland); Wittebroodt, Ch. [Montpellier-2 Univ., MSE, 34 (France); Lavielle, B.; Gilabert, E.; Thomas, B.; Lavastre, V. [Bordeaux 1-2 Univ., (GdR FORPRO 0788), Chimie Nucleaire Analytique et Bioenvironnementale (CNAB), CNRS, 33 - Gradignan (France); Lavastre, V. [Nimes Univ., Geochimie Isotopique Environnementale (GIS/CEREGE), CNRS-RANCE, 30 (France)

    2007-07-01

    This session gathers 5 articles dealing with: CO{sub 2} data on gas and pore water sampled in-situ in the Opalinus clay at the Mont Terri rock laboratory (A. Vinsot, C.A.J. Appelo, C. Cailteau, S. Mettler, P. Wersin, P. De Canniere, H.E. Gaebler); the improvements in the modelling of the pore water chemistry of the Callovo-Oxfordian formation (E.C. Gaucher, C. Tournassat, E. Jacquot, S. Altmann, A. Vinsot) the nature and reactivity of dissolved organic matter in the Opalinus clay and Callovo-Oxfordian formations (A. Courdouan, I. Christl, P.Wersin, R. Kretzschmar); PH4: a 250 m deep borehole in Tournemire for assessing the reliability of chloride, helium and water stable isotopes profiles in the Toarcian/ Domerian shales (S. Savoye, J.L. Michelot, H.N. Waber, J.M. Matray, F. Bensenouci, Ch. Wittebroodt, J. Cabrera); and the development of a new facility for dating old groundwaters by using {sup 81}Kr (B. Lavielle, E. Gilabert, B. Thomas, V. Lavastre)

  8. Microfluidics in radiopharmaceutical chemistry

    International Nuclear Information System (INIS)

    The increased demand for molecular imaging tracers useful in assessing and monitoring diseases has stimulated research towards more efficient and flexible radiosynthetic routes, including newer technologies. The traditional vessel-based approach suffers from limitations concerning flexibility, reagent mass needed, hardware requirements, large number of connections and valves, repetitive cleaning procedures and overall big footprint to be shielded from radiation. For these reasons, several research groups have started to investigate the application of the fast growing field of microfluidic chemistry to radiosynthetic procedures. After the first report in 2004, many scientific papers have been published and demonstrated the potential for increased process yields, reduced reagent use, improved flexibility and general ease of setup. This review will address definitions occurring in microfluidics as well as analyze the different approaches under two macro-categories: microvessel and microchannel. In this perspective, several works will be collected, involving the use of positron emitting species (11C, 18F, 64Cu) and the fewer examples of gamma emitting radionuclides (99mTc, 125/131I). New directions in microfluidic research applied to PET radiochemistry, future developments and challenges are also discussed. -- Graphical abstract: Display Omitted

  9. Marine fragrance chemistry.

    Science.gov (United States)

    Hügel, Helmut M; Drevermann, Britta; Lingham, Anthony R; Marriott, Philip J

    2008-06-01

    The main marine message in perfumery is projected by Calone 1951 (7-methyl-2H-1,5-benzodioxepin-3(4H)-one). Kraft (Givaudan) and Gaudin (Firmenich) further maximized the marine fragrance molecular membership by extending the carbon chain of the 7-Me group. Our research targeted the polar group of the benzodioxepinone parent compound to investigate how this region of molecular makeup resonates with the dominant marine fragrance of the Calone 1951 structure. The olfactory evaluation of analogues prepared by chemical modification or removal of the CO group resulted in the introduction of aldehydic, sweet and floral-fruity notes with a diluted/diminished potency of the marine odor. To further analyze the olfactory properties of benzodioxepinones containing a diverse range of aromatic ring substituents, a novel synthesis route was developed. We found that a 7-alkyl group in Calone 1951 was essential for the maintenance of the significant marine odor characteristic, and our studies support the concept that the odorant structure occupying the hydrophobic binding pocket adjacent to the aromatic ring-binding site of the olfactory receptor is pivotal in the design and discovery of more potent and characteristic marine fragrances. How the structure of benzodioxepinones connects to marine sea-breeze fragrances is our continuing challenging research focus at the chemistry-biology interface. PMID:18618392

  10. Advances in electron transfer chemistry

    CERN Document Server

    Mariano, Patrick S

    1993-01-01

    Advances in Electron Transfer Chemistry, Volume 3 presents studies that discuss findings in the various aspects of electron chemistry. The book is comprised of four chapters; each chapter reviews a work that tackles an issue in electron transfer chemistry. Chapter 1 discusses the photoinduced electron transfer in flexible biaryl donor-acceptor molecules. Chapter 2 tackles light-induced electron transfer in inorganic systems in homogeneous and heterogeneous phases. The book also covers internal geometry relaxation effects on electron transfer rates of amino-centered systems. The sequential elec

  11. The radiation chemistry of macromolecules

    CERN Document Server

    1973-01-01

    The Radiation Chemistry of Macromolecules, Volume II is a collection of papers that discusses radiation chemistry of specific systems. Part 1 deals with radiation chemistry of substituted vinyl polymers, particularly polypropylene (PP) as its structure is intermediate between polyethylene and polyisobutylene. This part also discusses polypropylene oxide (PPOx) for it can be prepared in the atactic, isotactic, and optically active forms. One paper focuses on the fundamental chemical processes and the changes in physical properties that give rise to many different applications of polystyrene. An

  12. Catalysis and sustainable (green) chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Centi, Gabriele; Perathoner, Siglinda [Dipartimento di Chimica Industriale ed Ingegneria dei Materiali, University of Messina, Salita Sperone 31, 98166 Messina (Italy)

    2003-01-15

    Catalysis is a key technology to achieve the objectives of sustainable (green) chemistry. After introducing the concepts of sustainable (green) chemistry and a brief assessment of new sustainable chemical technologies, the relationship between catalysis and sustainable (green) chemistry is discussed and illustrated via an analysis of some selected and relevant examples. Emphasis is also given to the concept of catalytic technologies for scaling-down chemical processes, in order to develop sustainable production processes which reduce the impact on the environment to an acceptable level that allows self-depuration processes of the living environment.

  13. Uses of ICT in Agriculture

    Directory of Open Access Journals (Sweden)

    Manish Mahant

    2012-03-01

    Full Text Available The application of Information and Communication Technology (ICT in agriculture is increasingly important. E-Agriculture is an emerging field focusing on the enhancement of agriculture and rural development through improved information and communication processes. More specifically, e-agriculture involves the conceptualization, design, development, evaluation and application of innovative ways to use information and communication technologies (ICT in rural domain, with a primary focus on agriculture. E-Agriculture is a relatively new term. E-Agriculture is one of the action lines identified in the declaration and plan of action of the WORLD SUMMIT ON THE INFORMATION SOCIETY. The Food and Agriculture Organization of United Nations (FAO has been assigned the responsibility of organizing activities related to the action line C.7 ICT Applications on E-Agriculture. The main phases of the agriculture industry are : Crop Cultivation, Water Management, Fertilizer Application, Fertigation, Pest Management, Harvesting, Post Harvest Handling, Transporting of Food/Food Products, Packaging, Food Preservation, Food Processing/Value Addition, Food Quality Management, Food Safety, Food Storage, Food marketing. All stakeholders of agriculture industry need information and knowledge about these phases to manage them efficiently. Any system applied for getting information and knowledge for making decisions in any industry should deliver accurate, complete, concise information n time or on time. The information provided by the system must be in user-friendly form, easy to access, cost-effective and well protected from unauthorized access. Information and Communication Technology (ICT can play a significant role in maintaining the above mentioned properties of information as it consists of three main technologies. They are: Computer Technology, Communication Technology and Information Management Technology. These technologies are applied for processing, exchanging

  14. Uses of ICT in Agriculture

    Directory of Open Access Journals (Sweden)

    Manish Mahant

    2012-03-01

    Full Text Available The application of Information and Communication Technology (ICT in agriculture is increasingly important. E-Agriculture is an emerging field focusing on the enhancement of agriculture and rural development through improved information and communication processes. More specifically, e-agriculture involves the conceptualization, design, development, evaluation and application of innovative ways to use information and communication technologies (ICT in rural domain, with a primary focus on agriculture. E-Agriculture is a relatively new term. E-Agriculture is one of the action lines identified in the declaration and plan of action of the WORLD SUMMIT ON THE INFORMATION SOCIETY. The Food and Agriculture Organization of United Nations (FAO has been assigned the responsibility of organizing activities related to the action line C.7 ICT Applications on E-Agriculture. The main phases of the agriculture industry are : Crop Cultivation, Water Management, Fertilizer Application, Fertigation, Pest Management, Harvesting, Post-Harvest Handling, Transporting of Food/Food Products, Packaging, Food Preservation, Food Processing/Value Addition, Food Quality Management, Food Safety, Food Storage, Food marketing. All stakeholders of agriculture industry need information and knowledge about these phases to manage them efficiently. Any system applied for getting information and knowledge for making decisions in any industry should deliver accurate, complete, concise information n time or on time. The information provided by the system must be in user-friendly form, easy to access, cost-effective and well protected from unauthorized access. Information and Communication Technology (ICT can play a significant role in maintaining the above mentioned properties of information as it consists of three main technologies. They are: Computer Technology, Communication Technology and Information Management Technology. These technologies are applied for processing, exchanging

  15. Genetically Modified Crops: Towards Agricultural Growth, Agricultural Development, or Agricultural Sustainability?

    OpenAIRE

    Azadi, Hossein; Ghanian, Mansour; Ghuchani, Omid M.; Rafiaani, Parisa; Taning, Clauvis N. T.; Hajivand, Roghaye Y.; Dogot, Thomas

    2015-01-01

    The present debate on how to increase global food production in a sustainable way has focused on arguments over the pros and cons of genetically modified (GM) crops. Scientists in both public and private sectors clearly regard GM technology as a major new set of tools, whereas industry sees it as an opportunity for increased profits. However, it remains questionable whether GM crops can contribute to agricultural growth, agricultural development, and agricultural sustainability. This review p...

  16. Nuclear energy for sustainable agriculture

    International Nuclear Information System (INIS)

    The use of improved crop plants and applying the concepts of integrated plant nutrient and integrated pest management are some of the ways for sustaining agriculture and developing ecofriendly management techniques. Ionizing radiations and isotopes (both stable and radioactive) have in the past been used for many applications in agriculture and they will have immense applications in future also

  17. ICTs for Agriculture in Africa

    OpenAIRE

    Zyl, Omri Van; Alexander, Trish; Graaf, Liezl De; Mukherjee, Kamal

    2014-01-01

    The strategic application of information and communications technology (ICT) to the agricultural industry, the largest economic sector in most African countries, offers the best opportunity for economic growth and poverty alleviation on the continent. Food security is paramount for the survival of individuals, families, and ultimately nations, yet Africa's agriculture sector has been in de...

  18. Natural resources in the Agriculture

    International Nuclear Information System (INIS)

    The objective of this investigation is identification the relation between the naturals resources degradation, and the Colombian agriculture productive. It's means a way to quantification the influence of a bad utilization in the water and land resources in the agricultural sector, to guide the sector in to a sustainable development. This objective is to make by an empirical exercise where we built four econometrics models (ordinary minims square) based in the Colombia's history statistic of the variables: land erosion, river sedimentation, plaguicides, Insecticides, Fungicides y Herbicides, agriculture productivity and agriculture yield. The resolute of this exercise is that an increase in the erosion area also the river sedimentation gives a decrease in the agriculture productivity. The same situation happens when it use the consumption of the insecticides and the fungicides which in the long time shows an opposite relation with the yield and productivity. At last we have that the aperture of the ninety's, bring to good changes for the agricultural productivity. So that, it concludes that the rivers and lands degradation affect in the long time the agriculture yield and productivity. The best use in the naturals resources, can help to increase the agricultural development, because it can increase the yield while it maintain for the future the possibility curve of production when it conserve the resources

  19. Paraguay Agricultural Sector Risk Assessment

    OpenAIRE

    Arce, Carlos; Arias, Diego

    2015-01-01

    This report is the result of a World Bank mission that visited Paraguay in June 2013 at the request of the Government of Paraguay. The mission’s objective was to identify, quantify, and prioritize agriculture risks that determine the volatility of agriculture gross domestic product (GDP), based on a methodology to assess sector risks developed by the World Bank. The methodology stipulates ...

  20. Preface: Biocatalysis and Agricultural Biotechnology

    Science.gov (United States)

    This book was assembled with the intent of bringing together current advances and in-depth reviews of biocatalysis and agricultural biotechnology with emphasis on bio-based products and agricultural biotechnology. Recent energy and food crises point out the importance of bio-based products from ren...