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Sample records for charbon actif modelisation

  1. Adsorption DU bleu de Telon et DU jaune de Telon EN SOLUTION AQUEUSE sur le charbon actif.

    OpenAIRE

    DAR KEBIRA, Fatma; BELARBI, Zakia

    2015-01-01

    Cette étude a pour objectif d’éliminer le Bleu de Telon et le Jaune de Telon en solution aqueuse par le charbon actif sous l’aspect cinétique et en régime statique confirmant l’intérêt pratique et économique de l’utilisation de charbon actif pour la dépollution des eaux contaminées par les colorants. Les résultats obtenus lors de cette étude à l’échelle laboratoire ont montré que : - Les deux colorants s’adsorbent sur le charbon actif. - Le charbon actif adsorbe plus le Jaune de Telo...

  2. Effets du charbon actif dans le milieu de culture sur l'induction de la ...

    African Journals Online (AJOL)

    SARAH

    30 avr. 2014 ... Conclusion et application de la recherche : L'ajout du charbon actif est bénéfique pour le développement .... développement du système racinaire et de ..... génotypes sélectionnés. Compte rendu. Premier séminaire maghrébin sur la génétique de la résistance du palmier dattier. Projet de lutte contre le.

  3. Possibilities of long duration generation of vapour of iodine 131 in the air for its trapping in French activated carbons; Possibilites de generation de longue duree dans l'air de vapeur d'iode 131 en vue de son piegeage par les charbons actifs francais

    Energy Technology Data Exchange (ETDEWEB)

    Billard, F.; Chevalier, G.; Pradel, J.

    1962-12-17

    As previous studies performed on activated carbon showed that it was necessary to possess a long duration iodine generator to determine the scope of application of some advanced theories concerning the trap mechanism of different forms of radio-iodines, the authors present a generator which uses the high temperature oxidation of sodium iodide by an air stream or an oxygen stream. A version of this apparatus using a 5 Curie source is planned to check the operation of a trap of 100.000 m{sup 3}/h with a purification coefficient of 10{sup 4}, and aimed at being mounted on the venting circuit of a nuclear reactor enclosure [French] Les etudes que nous avons effectuees sur les charbons actifs nous ont montre qu'il etait necessaire de posseder un generateur d'iode de longue duree pour preciser le domaine d'application de certaines theories avancees concernant le mecanisme de piegeage des differentes formes de radioiodes. Un generateur utilisant l'oxydation de l'iodure de sodium a chaud par un courant d'air ou d'oxygene est decrit. Une version de cet appareil utilisant une source de 5 curies est prevue pour verifier le bon fonctionnement d'un piege de 100.000 m{sup 3}/h ayant un coefficient d'epuration de 10{sup 4} est destine a etre place sur le circuit de ventilation de l'enceinte d'un reacteur nucleaire. (auteurs)

  4. Adsorption of gaseous pollutants on activated carbon filters. Modelling of the coupled exchanges of heat and mass; Adsorption de polluants gazeux sur des filtres de charbon actif. Modelisation des echanges couples de matiere et de chaleur

    Energy Technology Data Exchange (ETDEWEB)

    Fiani, E.

    2000-01-27

    The aim of this work is to remove gasoline and odorous molecules vapors. Thermodynamics and kinetics studies have been carried out; they concern the fixation of representative gases on activated carbons. Hydrogen sulfide and n-butane are chosen to represent the odorous molecules. Different activated carbons are considered: only the adsorbent impregnated by KOH has satisfying performance. The adsorption of hydrocarbons on a granulated activated carbon is studied on four original devices specifically perfected for this work: gravimetry, calorimetry, thermal measurements and gaseous phase chromatography. The gravimetric measurements are coupled to thermal measurements inside the granulates. Strong temperature variations have then been observed inside a granulate during the adsorption. These experimental results have been taken into account to adapt the classical Langmuir kinetic model. This new model allows to predict all the curves: setting / internal temperature variation for the adsorption of the hydrocarbons alone. The competitive nature of the adsorption sites allows then to explain qualitatively the adsorption of binary mixtures of hydrocarbons. At last, the classical Langmuir model allows to explain correctly the thermodynamic results, for the hydrocarbons alone or in binary mixture. The proposed modelling allows then to treat both on a kinetic and thermodynamic way the case of a non isothermal adsorption at the scale of an activated carbon granulate and to predict the phenomena at the filter scale. (O.M.)

  5. Active component modeling for analog integrated circuit design. Model parametrization and implementation in the SPICE-PAC circuit simulator; Modelisation de composants actifs pour la CAO de circuits integres analogiques. Parametrage et implantation de modeles dans le simulateur SPICE-PAC

    Energy Technology Data Exchange (ETDEWEB)

    Marchal, Xavier

    1992-06-19

    performants ne donnent des resultats fiables que si les modeles de composants introduits dans le simulateur sont suffisamment precis. Les transistors MOSFET sont les dispositifs les plus frequents; il est propose dans SPICE, 3 modeles differents classes suivant le rapport temps de simulation/precision des resultats. Cependant pour certaines applications, ceux-ci ne modelisent que partiellement les phenomenes physiques reels (effet d'avalanche ou faible inversion); il est alors possible d'affiner les resultats avec le modele a charges distribuees (MCD). Celui-ci, par une description cellulaire du transistor, permet l'evaluation plus fine de parametres physiques le long du canal (charges, mobilite, champs electriques). La modelisation ne peut etre complete et utilisable sans la determination des parametres du modele; les modeles de transistor MOS les plus complets peuvent en comporter plus d'une quarantaine. Nous proposerons differents programmes appeles indifferemment programmes 'd'ajustement', 'de fittage' ou 'de parametrage' qui permettent d'evaluer les parametres d'un modele pour que celui-ci fournisse des caracteristiques electriques calculees en bon accord avec ses caracteristiques electriques experimentales. Ceux-ci sont des programmes d'optimisation multidimensionnelle non lineaire multi-criteres; les criteres etant exprimes sous la forme de fonctions objectifs ayant pour variables les parametres a determiner, dans un domaine hyperrectangulaire. Nous montrerons que dans le cas d'un 'parametrage' en regime DC, seules des mesures directes d'un dispositif sont utilisees; pour obtenir les parametres AC et TRAN, nous avons recours a des mesures indirectes. Dans le premier cas seule la simulation d'un dispositif est effectuee, dans le second il est necessaire de simuler un circuit complexe environnant ce dispositif. Ces taches sont traitees par deux applications differentes FIT-PAC et OPT-PAC, associees au simulateur SPICE-PAC. Nous presentons et discutons les resultats de

  6. Le devenir actif du corps affectif

    Directory of Open Access Journals (Sweden)

    Pascal Séverac

    2005-09-01

    Full Text Available Le but de cet article est de saisir ce que signifie, pour le corps, être actif. À partir de la proposition 49 de la partie IV de l’Éthique, on propose de distinguer deux manières d’appréhender le corps – soit comme corps organique, soit comme corps affectif -, et l’on montre que la question éthique du devenir actif s’adresse à la dimension affective du corps. Il faut penser le devenir actif du corps affectif comme augmentation de son aptitude non seulement à affecter, mais aussi à être affecté. En effet, être affecté pour le corps n’est pas identique à pâtir : au contraire, plus est grande l’ouverture sensible d’un corps aux autres corps, plus est grande son activité éthique.The aim of this paper is to understand how the body can be active. With the proposition 49 of the fourth part of Ethics, two ways of conceiving of the body are distinguished : like an organic body or like an affective body. The ethics question of becoming active is about the affective body. This becoming active must be understood as increasing of the ability to affect, as well as to be affected. To be affected is different from to be passive. On the contrary, the more the body is able to be affected, the more he becomes active.

  7. Préparation et caractérisation d'un charbon actif à partir de la coquille d'amande (Prunus amygdalus amère

    Directory of Open Access Journals (Sweden)

    Trachi, M.

    2014-01-01

    Full Text Available Preparation and characterization of activated coal from bitter almond shells (Prunus amygdalus. Description of the subject. The present study concerns the preparation of activated coal (AC from bitter almond (Prunus amygdalus shells (BASh, a fruit that grows spontaneously in the Setif region (northeast Algeria. Obtaining and characterizing activated coal was the valorization method adopted here. Objectives. The aim of this study was to elucidate the feasibility of the chemical activation of BASh in order to obtain two types of activated coal (AC. Method. The two ACs were obtained from BASh by acid (CAa and basic (CAb activation. The final products were investigated for their different physicochemical characteristics: angle of repose, ash, differential screening calorimetry, etc. In the case of CAa, the modeling of the adsorption kinetic of methylene blue (MB, as well as of adsorption isotherms, was also performed. Results. The activation mode seemed to affect unequally the different physicochemical characteristics of both the obtained coals. On the other hand, the adsorption kinetics of the MB by CAa was correctly described by the pseudo-2nd-order model (R² = 0.999. Concerning the modeling of the adsorption isotherm, of the three models tested, the Freundlich model appeared to be the most appropriate to fit the experimental data (R2 = 0.898, mean relative error (MRE = 38.638 and root mean square error (RMSE = 1.039. In addition, the activated shell showed an interesting capacity for MB adsorption, estimated at 99.05%.

  8. ETUDE CINETIQUE DE L’ADSORPTION D’UN COLORANT CATIONIQUE (VERT DE METHYLE SUR DU CHARBON ACTIF EN MILIEU AQUEUX

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    O BAGHRICHE

    2008-06-01

    substrat, ont permis de constater une amélioration sensible de la capacité et de la vitesse d’adsorption du vert de méthyle sur ce support. Par ailleurs, l’adsorption de ce composé est bien décrit par les modèles cinétiques de Langmuir et Freundlich.

  9. INFLUENCE DES TEMPERATURES OPERATIONNELLES SUR LA PERFORMANCE D’UN REFRIGERATEUR SOLAIRE A ADSORPTION QUI FONCTIONNE AVEC LE COUPLE CHARBON ACTIF-METHANOL

    OpenAIRE

    H SOUALMI; Z SAADI; A RAHMANI

    2014-01-01

    Le séchage des produits alimentaires au soleil est un moyen efficace, facile et économique pour conserver les aliments, en particulier les fruits. Le séchoir solaire est l'équipement le plus populaire pour le séchage des fruits. En raison de la nature intermittente de l'énergie solaire, le stockage de l'énergie thermique est nécessaire pour assurer un fonctionnement prolongé du séchoir. L'objectif principal de cette étude est d'évaluer l'efficacité du séchoir solaire intégré avec un lit en gr...

  10. INFLUENCE DES TEMPERATURES OPERATIONNELLES SUR LA PERFORMANCE D’UN REFRIGERATEUR SOLAIRE A ADSORPTION QUI FONCTIONNE AVEC LE COUPLE CHARBON ACTIF-METHANOL

    Directory of Open Access Journals (Sweden)

    H SOUALMI

    2014-12-01

    Full Text Available Le séchage des produits alimentaires au soleil est un moyen efficace, facile et économique pour conserver les aliments, en particulier les fruits. Le séchoir solaire est l'équipement le plus populaire pour le séchage des fruits. En raison de la nature intermittente de l'énergie solaire, le stockage de l'énergie thermique est nécessaire pour assurer un fonctionnement prolongé du séchoir. L'objectif principal de cette étude est d'évaluer l'efficacité du séchoir solaire intégré avec un lit en gravier comme stockage thermique. L’air dans ce séchoir est sucé naturellement grâce à la cheminé solaire le séchage. Le cabinet de séchage est envisagé théoriquement (CFD.La distribution de la vitesse et de la température de l'air à travers le séchoir solaire ont été présentés durant une journée d’Août et sous les conditions climatiques de Tlemcen (Algérie. L’effet de la présence d'un stockage thermique sur la distribution de la vitesse et de la température du flux d'air et de la température des figues ont été analysés. Les résultats montrent que la conception du séchoir solaire, comportant un stockage thermique augmente les capacités et le rendement du séchoir solaire, par l’augmentation du temps de séchage.

  11. Effets de la production de charbon de bois sur les fourrés xérophiles ...

    African Journals Online (AJOL)

    Randriamalala, J. R., Rabeniala, R. and Masezamana, H. N. 2017. ... cette ville en charbon de bois augmente avec sa popu- lation (Gardner et al. 2015) et accentue davantage encore les pressions exercées sur les fourrés xérophiles des alentours dans ...... The forbidden fuel: Charcoal, urban woodfuel demand and supply.

  12. Type II supernovae modelisation: neutrinos transport simulation

    International Nuclear Information System (INIS)

    Mellor, P.

    1988-10-01

    A modelisation of neutrino transport in type II supernovae is presented. The first part is a description of hydrodynamics and radiative processes responsible of supernovae explosions. Macroscopic aspects of these are displayed in part two. Neutrino transport theory and usual numerical methods are also developed. A new technic of coherent scattering of neutrinos on nuclei or free nucleons is proposed in the frame work of the Lorentz bifluid approximation. This method deals with all numerical artifices (flux limiting schemes, closure relationship of Eddington moments) and allows a complete and consistent determination of the time-dependent neutrino distribution function for any value of the opacity, gradient of opacity and for all (relativistic) velocity fields of the diffusive medium. Part three is dedicated to microscopic phenomena (electronic capture, chimical composition, etc) which rule neutrinos emission-absorption mechanisms. The numerical treatments of those are presented, and some applications are useful for their parametrization. Finally, an extension of the method to inelastic scattering on light particules (electrons) is described in view to study neutrinos thermalization mechanism [fr

  13. Effect of Ash on Oxygen Carriers for the Application of Chemical Looping Combustion to a High Carbon Char Effet des cendres sur l’activité des porteurs d’oxygène dans la combustion du charbon en boucle chimique

    Directory of Open Access Journals (Sweden)

    Rubel A.

    2011-02-01

    activity of the OCs and both OCs performed well. The results were promising for the application of CLC directly to solid fuels. L’application de la combustion en boucle chimique (CLC aux combustibles solides est actuellement étudiée à l’Université du Kentucky, au Centre de Recherche de l’Energie Appliquée (CAER dans le but de développer un procédé de gazéification/combustion en boucle chimique pressurisé (PCLC/G afin de générer de l’électricité à partir de charbon. Un des principaux aspects de la combustion en boucle chimique de combustibles solides est la compréhension de l’effet des cendres sur la réactivité des porteurs d’oxygène (OCs. L’effet des cendres sur la capacité de transfert d’oxygène et sur l’aptitude à oxyder le charbon est étudié avec deux porteurs d’oxygène à base d’oxydes de fer. Les cendres utilisées sont des cendres volantes provenant d’une centrale thermique au charbon. Les expériences sont réalisées dans un système composé d’une thermo-balance couplée à un spectrographe de masse (TGMS dans lequel on utilise d’abord 500 mg d’un mélange de cendres/porteurs d’oxygène à différentes concentrations de cendres allant jusqu’à 75 %. Le gaz réducteur est composé de 10 % de H2, 15 % de CO, 20 % de CO2 et de 55 % de Ar; et le gaz oxydant est composé de 20 % de O2 dans Ar. Les réactions d’oxydation/réduction sont quasi totales. D’après ces expériences, les cendres ont une activité propre de porteur d’oxygène, liée à la présence de fer dans les cendres, confirmée par les analyses DRX. Cela génère une augmentation du gain ou de la perte de masse du mélange pendant l’oxydation/réduction. Les vitesses d’oxydation/réduction augmentent avec la concentration des cendres à cause de l’augmentation de la porosité du mélange de porteurs d’oxygène avec les cendres, ce qui permet un meilleur accès des gaz réactifs sur les sites actifs des porteurs d’oxygène. Dans un

  14. Efficacité de la technique d'induction florale d'Ananas comosus (L. Merr. au moyen de charbon actif enrichi à l'éthylène (TIFBio

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    Lebeau F.

    2009-01-01

    Full Text Available Efficiency of the Ananas comosus (L. Merr. flower induction treatment based on ethylene enriched activated carbon (TIFBio. Pineapple is an important export crop for tropical countries. The flower induction treatments are essential to the pineapple production for economical and social reasons. For conventional agriculture, many chemicals are available but for organic farming ethylene is the only allowed product. A new flower induction method suited to small organic growers has been developed by the Pesticides Initiative Programme of the Coleacp funded by the European Development Fund. The trials conducted proved that the method reaches more than 80% efficiency at 10 weeks for the different application methods evaluated. The wet application trials show a doses response effect as well as effect of the application replication at 2 days interval. The flowering rate culminates at 100% after 8 weeks for the best results, obtained with the wet treatment at 250 mg per plant applied two times at 2 days interval. The different dry treatments tested gave all 85 – 90% flowering rates at 10 weeks, suggesting the presence of an undetermined limitation factor in the conditions prevailing for the trial. The time of application during the day shows no significant effect. It is concluded that the growers can use the TIFBio technique for production control. It is recommended to evaluate the most suited application technique according to their particular case as environmental effect can affect the efficiency.

  15. Hydrogen sulfide adsorption on activated carbon fiber. Tests on Parisian subway; Elimination du sulfure d'hydrogene par adsorption sur tissu de charbon actif. Essais sur site RATP

    Energy Technology Data Exchange (ETDEWEB)

    Bouzaza, A.; Marsteau, St.; Laplanche, A. [Ecole Nationale Superieure de Chimie, Lab. Chimie des Nuissances et Genie de l' Environnement - CNGE, 35 - Rennes (France); Garrot, B. [RATP, Dept. Environnement et Securite-Domaines d' Expertises de l' Environnement-Entite Qualite de l' Air, 75 - Paris (France)

    2003-06-01

    Hydrogen sulfide has an unpleasant odor and may cause damage to the electrical materials of the Parisian subway. The activated carbon has some intrinsic catalytic activity, so the removal of hydrogen sulfide is due to an adsorption-oxidation process. In a laboratory scale, some kinetic parameters were acquired, which allowed us to build up two dynamic reactors. These continuous reactors, equipped with activated carbon fibers, were tested on the Madeleine station of the Parisian subway. The feasibility of the elimination of H{sub 2}S by continuous adsorption-oxidation was confirmed. The relative humidity of the gas phase was found to play an important role in the performance of the elimination. The durability of the pilot tested was compatible with an industrial exploitation of the process. (authors)

  16. Devenir des micropolluants prioritaires et émergents dans les filières conventionnelles de traitement des eaux résiduaires urbaines (files eau et boues), et au cours du traitement tertiaire par charbon actif

    OpenAIRE

    Mailler , Romain

    2015-01-01

    The first chapter is dedicated to the conventional primary and biological treatments. Hence, removals of a wide range of priority and emerging micropollutants were assessed for primary settling, physico-chemical lamellar settling, low load activated sludge process and biofiltration. Hydrophobic compounds and metals, as well as volatile organic compounds and biodegradable pollutants are rather well eliminated by these treatments. Moreover, considering removals normalized with nitrogen removals...

  17. Transient behaviour of an adsorption refrigerator. Experimental study of the alcohol/activated carbon system; Comportement transitoire d`une machine frigorifique a absorption. Etude experimentale du systeme alcool / charbon actif

    Energy Technology Data Exchange (ETDEWEB)

    Luo, L. [Centre National de la Recherche Scientifique (CNRS), 54 - Nancy (France). Lab. des sciences du genie chimique; Feidt, M. [Nancy-1 Univ., 54 - Vandoeuvre-les-Nancy (France)

    1997-03-01

    The objective of this article is to present an experimental study of an adsorption refrigerator, accounting for the transient phenomena in each component of the machine, in particular in the adsorber. The couples adsorbate/adsorbent investigated (activated carbon/methanol or ethanol) have been chosen on the basis of an earlier comparative study. We have performed a full series of experiments to investigate the transient evolution of temperatures, pressures and the cycled mass, in a discontinuous cycle, and along the components of the refrigerating machine. The influence of various parameters is studies by varying one at a time: adsorbate/ adsorbent couple, alcohol load in adsorber, alcohol flowrate, heating power, initial desorption temperature. All these experimental observation are discussed and compared to transient models developed in a separate article. (authors) 12 refs.

  18. Experimental study and modelisation of a pulse tube refrigerator

    International Nuclear Information System (INIS)

    Ravex, A.; Rolland, P.; Liang, J.

    1992-01-01

    A test bench for pulse tube refrigerator characterization has been built. In various configurations (basic pulse tube, orifice pulse tube and double inlet pulse tube), the ultimate temperature and the cooling power have been measured as a function of pressure wave amplitude and frequency for various geometries. A lowest temperature of 28 K has been achieved in a single staged double inlet configuration. A modelisation taking into account wall heat pumping, enthalpy flow and regenerator inefficiency is under development. Preliminary calculation results are compared with experimental data

  19. Les ressources en charbon de l'Amérique du Sud Coal Resources in South America

    Directory of Open Access Journals (Sweden)

    Alvarado B.

    2006-10-01

    Full Text Available L'Amérique du Sud en général est mal pourvue en ressources de charbon puisqu'elle ne représente que 0,5 % des ressources mondiales. Cependant, avec la crise actuelle de l'énergie et le développement rapide de l'industrie sidérurgique locale, tous les pays possesseurs de charbon s'appliquent à faire des recherches tendant à évaluer à sa juste valeur le potentiel charbonnier comme la source d'énergie la plus traditionnelle et la matière première irremplaçable pour la production du coke métallurgique. Dans cet article, il sera question des ressources d'Argentine, du Brésil, du Chili, de Colombie, du Pérou et du Venezuela, seuls pays qui recèlent des réserves reconnues. Les principaux gisements sud-américains se rencontrent dans les sédiments gondwaniens, crétacés, et certains probablement déposés dans des milieux deltaïques et lacustres, avec majorité de charbons bitumineux et sub-bitumineux de haute volatilité. La Colombie est le pays qui a les plus grandes ressources et toutes les catégories de charbon y compris ceux cokéfiables. Du fait que les diverses évaluations nationales ne sont pas comparables, compte tenu de ce qu'elles sont basées sur des concepts géologiques et technologiques avec des niveaux de pronostics et de certitudes variables, l'auteur, pour éviter une plus grande confusion, n'exprimera pas la grandeur des ressources en chiffres absolus. Generally speaking, South America is poor in coal resources, with only 0,50% of the world's supplies. Nonetheless, with the present energy crisis and the rapid development of the local steel industry, all countries possessing coal deposits are undertaking research to evaluate accurately their potential resources of coal, the most traditional energy source and the indispensable raw material for the production of foundry coke. In this paper will be discussed the resources of those South Americon countries known to have coal reserves: Argentina, Brazil, Chile

  20. Thermal tests on UF6 containers and valves modelisation and extrapolation on real fire situations

    International Nuclear Information System (INIS)

    Duret, B.; Warniez, P.

    1988-12-01

    From realistic tests on containers or on valves, we propose a modelisation which we apply to 3 particular problems: resistance of a 48 Y containers, during a fire situation. Influence of the presence of a valve. Evaluation of a leakage through a breach, mechanically created before a fire

  1. Etude de l'auto-adaptivité du filtre actif parallèle aux variations de la ...

    African Journals Online (AJOL)

    ﮫـﻋ ﺔﯾﺮﻈﻧ. -ﻚـﻋ. Résumé. Cet article s'intéresse à l'amélioration des performances du filtre actif parallèle pour s'adapter d'une manière automatique aux variations de la charge. Ce filtre est un onduleur de tension à MLI destiné à éliminer les harmoniques de courant générés par un pont redresseur triphasé non commandé ...

  2. Conseiller les actifs en transition sur le marché du travail

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    Coralie Perez

    2010-02-01

    Full Text Available Le développement des services de conseil, d’orientation et d’accompagnement professionnel ne peut se comprendre indépendamment de la prise en compte des transformations affectant l’emploi et la protection sociale, et notamment de la diffusion de la doxa de l’activation. Ce champ professionnel est dynamique, créateur de nouvelles activités et, de ce fait, de nouveaux postes de conseillers auprès des salariés ou des demandeurs d’emploi ont été créés. L’accent est mis ici sur les conseillers en mobilité professionnelle des Fongecif, d’une part, et sur les « accompagnateurs » des opérateurs privés de placement, d’autre part. Ensemble, ils concourent à l’encadrement des actifs en transition sur le marché du travail.Guidance of people in transition on the labour market: the generalization of differentiated practicesFor the late 80’s, information, advice and guidance (IAG services has been growing in importance, not only for job seekers but for the workforce as a whole. This trend towards the rise of these services can not be understood without taking into account the transformations of employment policies and social welfare, and particularly the spreading of the activation doxa. Nowadays, IAG constitutes a professional field which is quite dynamic; new jobs of advisers/counsellors who support job seekers as well as workers in their career choices have been created. While these services are usually described for job seekers, this article sheds light on the similarities (as well as differences of IAG services for the workforce, assuming that a common rationale underlies their uses. Two types of providers are studied and compared: the ‘advisers of occupational mobility’ of the Fongecif (a mutual fund for demand-led training and counsellors form a private-for-profit providers specializing in job seeking. Together, they contribute to implement techniques of controlling people during their transitions on the labour

  3. Flow and heat transfer thermohydraulic modelisation during the reflooding phase of a P.W.R.'s core

    International Nuclear Information System (INIS)

    Raymond, Patrick

    1978-04-01

    Some generalities about L.O.C.A. are first recalled. The French experimental studies about Emergency Core Cooling System are briefly described. The different heat transfer mechanisms to take into account, according to the flow pattern in the dry zone, and the correlations or methods to calculate them, are defined. Then the Thermohydraulic code computer: FLIRA, which describe the reflooding phase, and a modelisation taking into account the different flow patterns are setted. A first interpretation of ERSEC experiments with a tubular test section shows that it is possible, with this modelisation and some classical heat transfer correlations, to describe the reflooding phase. [fr

  4. 2281-IJBCS-Article-Clement Balogoun

    African Journals Online (AJOL)

    hp

    la production des charbons actifs à partir de résidus ligno-cellulosiques ...... as affected by ozone and alkaline treatment. Chemosphere .... Modeling. Butterworth-Heinemannseries in Chemical Engineering: Boston. Vargas AMM, Cazetta AL, ...

  5. Caractéristiques des souches d'Ustilago nuda, agent du charbon nu de l'orge, résistantes à la carboxine

    OpenAIRE

    Leroux , Pierre

    1986-01-01

    Des souches d’Ustilago nuda, agent du charbon nu de l’orge, résistantes à la carboxine ont été détectées en France et dans d’autres pays européens. Une résistance croisée positive s’observe entre ce fongicide, le fenfuram, la pyracarbolide et divers autres analogues structuraux ; le mépronil se singularise car il est plus toxique pour les isolats résistants à la carboxine que pour les isolats sensibles. Toutes les souches sont affectées de la même manière par l’antimycine A, l’azide de so...

  6. Endocrine control of active sodium transport across frog skin; Le controle endocrinien du transport actif de sodium a travers la peau de grenouille

    Energy Technology Data Exchange (ETDEWEB)

    Maetz, J. [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    I. Action of the neurohypophyseal peptides on sodium transport. 1) On Rana Esculenta, oxytocin alone is active on the sodium transport (not vaso pressin). 2) The post hypophysis of R.e. contains an hormonal factor even more specific on Na transport (12 times more active than oxytocin). 3) This new factor must be closely related to oxytocin. II. Action of the adrenal corticoids. 1) The skin of frogs adapted to a salt-rich external medium, shows a considerable diminution in sodium uptake. 2) This decreased sodium uptake is brought back to normal by the injections of aldosterone. 3) This suggests that salt loading of amphibians (as well as mammals) inhibits the mineralocorticoid activity of the adrenals. (author) [French] I. Action des peptides neurohypophysaires chez Rana esculenta. 1) Le transport actif de Na est sensible a l'action de l'ocytocine mais non a l'hormone antidiuretique. 2) La posthypophyse de ces grenouilles contient un facteur plus specifique encore, puisque 12 fois plus actif que l'ocytocine. 3) Ce facteur est cependant tres voisin de l'ocytocine au point de vue chimique. lI. Action des corticoides surrenaliens chez Rana Esculenta. 1) L'adaptation des grenouilles a un milieu riche en sel a pour effet une diminution considerable du transport actif de sodium, visible in vivo et in vitro. 2) L'injection d'aldosterone a des grenouilles adaptees dans ces conditions restaure le transport actif a un niveau comparable a celui que l'on observe chez les animaux conserves dans de l'eau courante. 3) Ces faits suggerent que la surcharge en NaCI produirait chez les amphibiens, comme chez les mammiferes, une mise au repos de la fonction mineralotrope de la surrenale. (auteur)

  7. Endocrine control of active sodium transport across frog skin; Le controle endocrinien du transport actif de sodium a travers la peau de grenouille

    Energy Technology Data Exchange (ETDEWEB)

    Maetz, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    I. Action of the neurohypophyseal peptides on sodium transport. 1) On Rana Esculenta, oxytocin alone is active on the sodium transport (not vaso pressin). 2) The post hypophysis of R.e. contains an hormonal factor even more specific on Na transport (12 times more active than oxytocin). 3) This new factor must be closely related to oxytocin. II. Action of the adrenal corticoids. 1) The skin of frogs adapted to a salt-rich external medium, shows a considerable diminution in sodium uptake. 2) This decreased sodium uptake is brought back to normal by the injections of aldosterone. 3) This suggests that salt loading of amphibians (as well as mammals) inhibits the mineralocorticoid activity of the adrenals. (author) [French] I. Action des peptides neurohypophysaires chez Rana esculenta. 1) Le transport actif de Na est sensible a l'action de l'ocytocine mais non a l'hormone antidiuretique. 2) La posthypophyse de ces grenouilles contient un facteur plus specifique encore, puisque 12 fois plus actif que l'ocytocine. 3) Ce facteur est cependant tres voisin de l'ocytocine au point de vue chimique. lI. Action des corticoides surrenaliens chez Rana Esculenta. 1) L'adaptation des grenouilles a un milieu riche en sel a pour effet une diminution considerable du transport actif de sodium, visible in vivo et in vitro. 2) L'injection d'aldosterone a des grenouilles adaptees dans ces conditions restaure le transport actif a un niveau comparable a celui que l'on observe chez les animaux conserves dans de l'eau courante. 3) Ces faits suggerent que la surcharge en NaCI produirait chez les amphibiens, comme chez les mammiferes, une mise au repos de la fonction mineralotrope de la surrenale. (auteur)

  8. 2503-IJBCS-Article-Urbain Paul Gnonsoro

    African Journals Online (AJOL)

    hp

    3 Laboratoire Central d'Agrochimie et d'Ecotoxicologie (LCAE), 04 BP 612 Abidjan ... benzo(a)pyrène adsorbée dans l'eau croissait avec la masse de charbon activé .... électrique. (Advantec. KL-280). Les caractéristiques du charbon actif sont.

  9. Study and modeling of the most energetic Active Galactic Nuclei with the Fermi satellite; Etude et modelisation des noyaux actifs de galaxie les plus energetiques avec le satellite Fermi

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez, D.

    2010-06-15

    The Fermi satellite was launched in June 2008. The onboard LAT detector is dedicated to the study of galactic and extra-galactic gamma sources with an energy comprised between 200 MeV and 300 GeV. 1451 sources have been detected in less than 11 months. This document is divided into 6 chapters: 1) gamma astronomy, 2) the Fermi satellite, 3) the active galactic nuclei (NAG), 4) the observation of several blazars (PKS-2155-304 and PG-1553+113) and its simulation, 5) the observation of PKS-2155-304 with both RXTE and Fermi, and 6) conclusion

  10. Etude de pratiques d'enseignement relatives a la modelisation en sciences et technologies avec des enseignants du secondaire

    Science.gov (United States)

    Aurousseau, Emmanuelle

    Les modeles sont des outils amplement utilises en sciences et technologies (S&T) afin de representer et d’expliquer un phenomene difficilement accessible, voire abstrait. La demarche de modelisation est presentee de maniere explicite dans le programme de formation de l’ecole quebecoise (PFEQ), notamment au 2eme cycle du secondaire (Quebec. Ministere de l'Education du Loisir et du Sport, 2007a). Elle fait ainsi partie des sept demarches auxquelles eleves et enseignants sont censes recourir. Cependant, de nombreuses recherches mettent en avant la difficulte des enseignants a structurer leurs pratiques d’enseignement autour des modeles et de la demarche de modelisation qui sont pourtant reconnus comme indispensables. En effet, les modeles favorisent la conciliation des champs concrets et abstraits entre lesquels le scientifique, meme en herbe, effectue des allers-retours afin de concilier le champ experimental de reference qu’il manipule et observe au champ theorique relie qu’il construit. L’objectif de cette recherche est donc de comprendre comment les modeles et la demarche de modelisation contribuent a faciliter l’articulation du concret et de l’abstrait dans l’enseignement des sciences et des technologies (S&T) au 2eme cycle du secondaire. Pour repondre a cette question, nous avons travaille avec les enseignants dans une perspective collaborative lors de groupes focalises et d’observation en classe. Ces dispositifs ont permis d’examiner les pratiques d’enseignement que quatre enseignants mettent en oeuvre en utilisant des modeles et des demarches de modelisation. L’analyse des pratiques d’enseignement et des ajustements que les enseignants envisagent dans leur pratique nous permet de degager des connaissances a la fois pour la recherche et pour la pratique des enseignants, au regard de l’utilisation des modeles et de la demarche de modelisation en S&T au secondaire.

  11. Aspects chimiques de la combustion du charbon pulvérisé. Première partie Chemical Aspects of the Combustion of Pulverized Coal. Part One

    Directory of Open Access Journals (Sweden)

    De Soete G. G.

    2006-11-01

    Full Text Available II n'est pas facile de parvenir à une vue complète des multiples phénomènes chimiques dont la flamme de charbon pulvérisé est le siège. La présente étude bibliographique s'efforce de donner plus qu'une juxtaposition des données de la littérature récente, en risquant une tentative de présentation cohérente des mécanismes chimiques clés qui s'affrontent dans cette combustion. Ces mécanismes font intervenir des réactions en phase gazeuse relativement rapides (combustion des produits gazeux de pyrolyse, formation d'oxydes d'azote à partir de l'azote organique ainsi qu'un certain nombre de réactions hétérogènes très importantes (dévolatilisation pyrolysante rapide, oxydation du coke, réduction hétérogène d'oxydes d'azote qui peuvent se dérouler de façon beaucoup plus lente. En ce qui concerne ces dernières, le régime non isotherme, auquel les soumet l'existence de gradients de température dans la flamme industrielle, entraîne souvent des conséquences non négligeables pour le déroulement de ces mécanismes cinétiques complexes : ainsi la quantité et la composition des produits de pyrolyse est fortement tributaire de ces conditions non isothermes. Carrefour de plusieurs mécanismes chimiques complexes, la flamme de charbon est caractérisée chimiquement par un grand nombre de cas de compétition : a compétition entre différentes voies réactionnelles à l'intérieur d'un mécanisme donné ; à titre d'exemple typique : la pyrolyse du charbon ; b compétition entre phénomènes chimiques et physiques, également à l'intérieur d'un même mécanisme, entraînant la transition éventuellement réversible d'un régime cinétique vers un régime diffusionnel, comme c'est le cas dans l'oxydation du coke, avec des conséquences sensibles pour la vitesse réactionnelle globale et sa dépendance par rapport à la température, pouvant même aller jusqu'à l'extinction de la combustion du coke ; c compétition entre

  12. Coal; Le charbon

    Energy Technology Data Exchange (ETDEWEB)

    Teissie, J.; Bourgogne, D. de; Bautin, F. [TotalFinaElf, La Defense, 92 - Courbevoie (France)

    2001-12-15

    Coal world production represents 3.5 billions of tons, plus 900 millions of tons of lignite. 50% of coal is used for power generation, 16% by steel making industry, 5% by cement plants, and 29% for space heating and by other industries like carbo-chemistry. Coal reserves are enormous, about 1000 billions of tons (i.e. 250 years of consumption with the present day rate) but their exploitation will be in competition with less costly and less polluting energy sources. This documents treats of all aspects of coal: origin, composition, calorific value, classification, resources, reserves, production, international trade, sectoral consumption, cost, retail price, safety aspects of coal mining, environmental impacts (solid and gaseous effluents), different technologies of coal-fired power plants and their relative efficiency, alternative solutions for the recovery of coal energy (fuel cells, liquefaction). (J.S.)

  13. 1 - Aromatization of n-hexane and natural gasoline over ZSM-5 zeolite, 2- Wet catalytic oxidation of phenol on fixed bed of active carbon; 1 - Aromatisation de n-hexane et d'essence sur zeolithe ZSM-5, 2 - Oxydation catalytique en voie humide du phenol sur charbon actif

    Energy Technology Data Exchange (ETDEWEB)

    Suwanprasop, S.

    2005-04-15

    I - The production of aromatic hydrocarbons from n-hexane and natural gasoline over Pd loaded ZSM-5 zeolite in a tubular reactor was achieved under the suitable conditions at 400 deg. C, and 0.4 ml/min reactant feeding rate, employing ZSM-5 (0.5% Pd content) as a catalyst. Under these conditions, n-hexane and natural gasoline conversions were found to be 99.7% and 94.3%, respectively (with respective aromatic selectivity of 92.3% and 92.6%). II - Wet catalytic air oxidation of phenol over a commercial active carbon was studied in a three phase fixed bed reactor under mild temperature and oxygen partial pressure. Exit phenol concentration, COD, and intermediates were analysed. Oxidation of phenol was significantly improved when increasing operating temperature, oxygen partial pressure, and liquid space time, while up or down flow modes had only marginal effect. A complete model involving intrinsic kinetics and all mass transfer limitations gave convenient reactor simulation. (author)

  14. Hydrogen storage by adsorption on activated carbon: investigation of the thermal effects during the charging process; Stockage de l'hydrogene par adsorption sur charbon actif: etude des effets thermiques lors de la charge dynamique d'un reservoir a lit fixe adsorbant

    Energy Technology Data Exchange (ETDEWEB)

    Hermosilla-Lara, G

    2007-02-15

    This work presents an experimental and numerical investigation of the thermal effects occurring during the charge of adsorbent fixed bed tank. The influence of these thermal effects, which result from the exothermal character of the adsorption process and the pressure forces work, on the storage capacity is specially analysed. An experimental setup allowing the dynamic measurements of the temperature and pressure profiles has been used. Then the numerical protocol with the Fluent software, has been validated by comparison of the simulated pressure, flow rate and temperature fields in the tank with the results obtained from an experimental investigation carried out the dynamic storage. Several predictive simulations have been carried out in order to study the effect of the boundary conditions, as the wall temperature or effective thermal conductivity of the porous bed, on the storage capacity of the reservoir. We searched the optimal geometry of an interbed thermal dissipator for a given industrial tank. To do this we made vary the H/L ratio, which represents the ratio of the height of an elementary stage and the total length of the tank. We could determine an optimal geometry which corresponds to the value 1/3 of the ratio H/L. From this optimum we studied the effect of five additional cooling tubes on the tank storage capacity. The stored mass is 15 % higher than that obtained without these tubes. (author)

  15. Devenir des micropolluants prioritaires et émergents dans les filières conventionnelles de traitement des eaux résiduaires urbaines des grosses collectivités (files eau et boues), et au cours du traitement tertiaire au charbon actif

    OpenAIRE

    Mailler , Romain

    2015-01-01

    This PhD was performed within the OPUR (Observatory of URban Pollution) research program, in collaboration with the Research and Development Department of the Parisian public sanitation service (SIAAP). This work deals with the removal of priority and emerging micropollutants by the conventional wastewater treatments, as well as tertiary treatment by activated carbon. A part of this work is also dedicated to the sludge contamination by priority and emerging substances and their fate during sl...

  16. Modelisation of the concentration of macromolecules moving in a Newtonian fluid

    International Nuclear Information System (INIS)

    Hijazi, A.; Zoaeter, M.; Khater, A.; Aussere, D.

    1998-01-01

    Author.This article presents a modelisation of the distribution of a diluted solution of macromolecules submitted to a simple flow in the neighborhood of a non-absorbing solid surface. These macromolecules (length L, negligible diameter) are submitted to two kinds of forces: rotational and translational with brownian and hydrodynamic origins. The evolution of orientation of these molecules in terms of time has been studied, given Einstein equation =D with D coefficient of translation and rotation. By taking as parameters the orientation θ of the macromolecules with respect to an horizontal axis and Z the distance between these macromolecules and the surface, a statistical study has led to determine the distribution. For that reason, the brownian movement considered is supposed to follow a rule of random probability

  17. Modelling Adsorption of Foam-Forming Surfactants Modélisation de l'adsorption des produits tensio-actifs moussants

    Directory of Open Access Journals (Sweden)

    Mannhardt K.

    2006-11-01

    Full Text Available There is considerable interest in the use of foam-forming surfactants for mobility control in gas flooding enhanced oil recovery processes. The success of any such process is strongly affected by the rate of propagation of the surfactant through the reservoir. A sound understanding of surfactant adsorption on rock surfaces at reservoir conditions is therefore essential. This paper describes a model for the evaluation of adsorption during flow of surfactant solutions through porous media. The adsorption term in the flow equation is expressed in terms of the surface excess which proves to be more generally applicable than, for example, the Langmuir adsorption isotherm. Adsorption isotherms of three types of commercially available foam-forming surfactants are determined from core flooding data at different temperatures and brine salinities. L'utilisation de produits tensio-actifs moussants pour le contrôle de mobilité dans les procédés de récupération assistée du pétrole par injection de gaz suscite actuellement un grand intérêt. Mais le succès d'un tel procédé dépend largement de la vitesse de propagation du tensioactif dans le réservoir. Il est donc indispensable d'avoir une bonne connaissance de l'adsorption du tensio-actif sur les surfaces de la roche, dans les conditions de réservoir. Cet article décrit un modèle qui permet d'évaluer l'adsorption pendant l'écoulement de solutions tensio-actives en milieu poreux. Le terme qui représente l'adsorption dans l'équation de l'écoulement est exprimé en fonction de l'excédent de surface, concept qui s'est révélé d'une application plus générale que, par exemple, l'isotherme d'adsorption de Langmuir. Les isothermes d'adsorption de trois types de tensio-actifs moussants disponibles sur le marché sont déterminées à partir de données obtenues lors d'essais de déplacement dans des carottes, à différentes températures et avec des saumures de différentes salinités.

  18. Microparticules composites lipide-silice pour la libération prolongée d'un principe actif dans l'estomac.

    OpenAIRE

    Perge , Laurent; Robitzer , Mike; Quignard , Françoise; Devoisselle , Jean-Marie; Legrand , Philippe

    2010-01-01

    International audience; Ces dernières années, les avancés scientifiques et technologiques ont été menées dans le développement de systèmes par voie orale à libération contrôlée de principe actif indépendants du ntemps de transit dans le tractus digestif et capables de résider plus longtemps dans l'estomac en évitant une vidange gastrique prématurée. Différentes approches ont été développées pour permettre de surpasser ces problèmes, comme des systèmes flottants, des systèmes polymères bioadhé...

  19. New modelling method for fast reactor neutronic behaviours analysis; Nouvelles methodes de modelisation neutronique des reacteurs rapides de quatrieme Generation

    Energy Technology Data Exchange (ETDEWEB)

    Jacquet, P.

    2011-05-23

    Due to safety rules running on fourth generation reactors' core development, neutronics simulation tools have to be as accurate as never before. First part of this report enumerates every step of fast reactor's neutronics simulation implemented in current reference code: ECCO. Considering the field of fast reactors that meet criteria of fourth generation, ability of models to describe self-shielding phenomenon, to simulate neutrons leakage in a lattice of fuel assemblies and to produce representative macroscopic sections is evaluated. The second part of this thesis is dedicated to the simulation of fast reactors' core with steel reflector. These require the development of advanced methods of condensation and homogenization. Several methods are proposed and compared on a typical case: the ZONA2B core of MASURCA reactor. (author) [French] Les criteres de surete qui regissent le developpement de coeurs de reacteurs de quatrieme generation implique l'usage d'outils de calcul neutronique performants. Une premiere partie de la these reprend toutes les etapes de modelisation neutronique des reacteurs rapides actuellement d'usage dans le code de reference ECCO. La capacite des modeles a decrire le phenomene d'autoprotection, a representer les fuites neutroniques au niveau d'un reseau d'assemblages combustibles et a generer des sections macroscopiques representatives est appreciee sur le domaine des reacteurs rapides innovants respectant les criteres de quatrieme generation. La deuxieme partie de ce memoire se consacre a la modelisation des coeurs rapides avec reflecteur acier. Ces derniers necessitent le developpement de methodes avancees de condensation et d'homogenisation. Plusieurs methodes sont proposees et confrontees sur un probleme de modelisation typique: le coeur ZONA2B du reacteur maquette MASURCA

  20. Déphaseur large bande à phase indépendante de la fréquence à base de circuit actif à temps de propagation de groupe négatif

    OpenAIRE

    Ravelo , Blaise ,; Le Roy , Marc; Pérennec , André

    2009-01-01

    National audience; Un nouveau principe de déphaseur actif à phase constante est proposé. Ce déphaseur est obtenu par l'association de dispositifs à Temps de Propagation de Groupe (TPG) positif et négatif de même valeur absolue. Pour le concevoir, nous avons ainsi associé une ligne de transmission classique avec un circuit actif à TPG négatif développé récemment. Après réalisation d'un prototype en technologie planaire hybride, nous avons mesuré une phase constante (indépendante de la fréquenc...

  1. Système énergétique charbon-nucléaire. Méthode d'étude. Exemples de résultats Coal-Nuclear Energy System. Method of Study. Examples of Results

    Directory of Open Access Journals (Sweden)

    Le Penhuizic B.

    2006-11-01

    Full Text Available Dans la perspective d'une raréfaction des hydrocarbures, trois sources d'énergie primaire pourraient permettre de diversifier les approvisionnements : le nucléaire, le charbon et le solaire. Ces énergies primaires sont rarement utilisables directement et doivent être converties en vecteurs énergétiques : électricité, hydrogène, gaz naturel de substitution, hydrocarbures liquides dérivés du charbon, etc. La nature des futurs vecteurs gazeux et leur place dans le bilan énergétique national doivent être examinées dans le cadre d'un système énergétique global. En effet, les nombreux procédés de conversion envisageables sont souvent liés par leurs productions et leurs consommations. D'autre part, les variations saisonnières des consommations imposent de dimensionner pour la pointe les installations de production ou d'équiper des stockages importants. Un premier modèle, rendant compte de ces interactions, a été construit pour représenter la variété des solutions possibles. L'exploitation de ce modèle permet, dans le cadre de diverses hypothèses pour l'avenir, d'apprécier des orientations techniques. Given the outlook for hydrocarbon depletion, three primary energy sources could enable supplies to be diversified, i. e. nuclear energy, coal and solar energy. These primary energy sources can rarely be used directly and must be converted into energy carriers such as electricity, hydrogen, substitute natural gas, liquid hydrocarbons derived from coal, etc. The nature of future gas carriers and their position in the national energy balance must be examined within the framework of an overall energy pattern. Many of the potential conversion processes are often interrelated through their production and consumption. Likewise, seasonal variations in consumption make it necessary to design production plants for peak demand or to create large-scale storage facilities. An initial model taking these interactions into consideration

  2. Les conditions du développement des banques d’actifs naturels en FranceAnalyse du régime institutionnel de la première Réserve d’Actifs Naturels française What conditions to enlarge habitat banks in France ?Institutional regime analysis of the first French habitat bank

    Directory of Open Access Journals (Sweden)

    Fanny Chabran

    2012-05-01

    Full Text Available Les marchés d’actifs naturels sont encore rares en Europe, mais les premières expériences permettent de s’interroger sur le dispositif mis en place au regard de l’objectif de conservation des milieux naturels. Nous avons analysé la première expérience française de banque d’actifs naturels, mise en place dans le cadre des dispositifs de compensation des impacts écologiques des aménagements. Ce projet repose sur d’importants travaux de réhabilitation écologique pour faire retourner un verger intensif vers une végétation herbacée méditerranéenne. Les résultats en écologie de la restauration sont encourageants. En revanche, ils sont encore à évaluer dans les champs politiques ou économiques. Une analyse du régime institutionnel régissant les usages du site montre que l’action mercantile entreprise, tout autant que l’incomplétude du dispositif public de régulation, ne confèrent pas d’assurances définitives quant à la pérennité du dispositif de conservation environnementale du site.Habitat banks are not numerous in Europe but the first experiments allow wondering about the device in relation to the conservation purpose. We analyzed the first French experience of habitat banking introduced in the mitigation regulatory framework. This project is based on important ecological rehabilitation of an intensive orchard to Mediterranean herbaceous vegetation. Results in ecological restoration are good ; however, they are still assessing in the political and economic fields. An analysis of the institutional regime of site uses shows that the mercantile action as well as the public device incompleteness does not provide insurance about the site’s conservation sustainability.

  3. Caractérisation des solutions de tensio-actif utilisées en récupération assistée Characterization of Surfactant Solutions Used in Enhanced Recovery

    Directory of Open Access Journals (Sweden)

    Moulu J. C.

    2006-11-01

    Full Text Available Des solutions de tensio-actif sont étudiées en vue de déterminer celles qui doivent être les plus efficaces pour le déplacement d'huile résiduelle en milieu poreux. Selon les propriétés de ces solutions au moment de leur injection, un banc d'huile se forme rapidement et progresse au niveau du front de tensio-actif, ou au contraire, les globules d'huile sont entraînés avec une vitesse faible dans l'ensemble du bouchon, les échanges entre les phases peuvent alors être importants. On a donc cherché à évaluer les caractéristiques des solutions en tenant compte des échanges qu'elles ont pu avoir avec l'huile et en particulier dans les deux cas extrêmes : solutions aqueuses sans huile et solutions équilibrées avec un grand volume d'huile. Pour ces deux états des solutions aqueuses, on a mis en évidence des comportements rhéologiques et interfaciaux très différents, dus à la migration d'alcool et d'huile entre les phases en présence. Ces propriétés des solutions de tensio-actif ont par ailleurs été reliées à la présence de structures cristallines et à leur transformation au cours des échanges qui se produisent. Research is being done on surfactant solutions to determine the ones that should be the most efficient for driving residual oil in porous media. Depending on the properties of these solutions at the time of their injection, an oil bank is formed quickly and progresses at the level of the surfactant front or, on the contrary, the oil ganglia are displaced slowly in the slug as a whole, and exchanges between the phases may then be great. Therefore, an effort was made to assess the characteristics of solutions while considering the exchanges they may have had with the oil, and particularly in the two extreme cases, i. e. aqueous solutions without oil and equilibrated solutions with a large volume of oil. For these two states of aqueous solutions, very different rheological and interfacial behaviors were found as

  4. A Poromechanical Model for Coal Seams Injected with Carbon Dioxide: From an Isotherm of Adsorption to a Swelling of the Reservoir Un modéle poromécanique pour l’injection de dioxyde de carbone dans des veines de charbon : d’une isotherme d’adsorption à un gonflement du réservoir

    Directory of Open Access Journals (Sweden)

    Nikoosokhan S.

    2012-11-01

    Full Text Available Injecting carbon dioxide into deep unminable coal seams can enhance the amount of methane recovered from the seam. This process is known as CO2-Enhanced Coal Bed Methane production (CO2-ECBM. The seam is a porous medium whose porous system is made of cleats (small natural fractures and of coal pores (whose radius can be as small as a few angström. During the injection process, the molecules of CO2 get adsorbed in the coal pores. Such an adsorption makes the coal swell, which, in the confined conditions that prevail underground, induces a closure of the cleat system of the coal bed reservoir and a loss of injectivity. In this work, we develop a poromechanical model which, starting from the knowledge of an adsorption isotherm and combined with reservoir simulations, enables to estimate the variations of injectivity of the coal bed reservoir over time during the process of injection. The model for the coal bed reservoir is based on poromechanical equations that explicitly take into account the effect of adsorption on the mechanical behavior of a microporous medium. We consider the coal bed reservoir as a dual porosity (cleats and coal porosity medium, for which we derive a set of linear constitutive equations. The model requires as an input the adsorption isotherm on coal of the fluid considered. Reversely, the model provides a way to upscale an adsorption isotherm into a meaningful swelling of the coal bed reservoir at the macroscopic scale. The parameters of the model are calibrated on data on coal samples available in the literature. Reservoir simulations of an injection of carbon dioxide in a coal seam are performed with an in-house finite volume and element code. The variations of injection rate over time during the process of injection are obtained from the simulations. The effect of the compressibility of the coal matrix on those variations is discussed. L’injection de dioxyde de carbone dans des veines de charbon profondes peut augmenter

  5. Modelisation de la diffusion sur les surfaces metalliques: De l'adatome aux processus de croissance

    Science.gov (United States)

    Boisvert, Ghyslain

    Cette these est consacree a l'etude des processus de diffusion en surface dans le but ultime de comprendre, et de modeliser, la croissance d'une couche mince. L'importance de bien mai triser la croissance est primordiale compte tenu de son role dans la miniaturisation des circuits electroniques. Nous etudions ici les surface des metaux nobles et de ceux de la fin de la serie de transition. Dans un premier temps, nous nous interessons a la diffusion d'un simple adatome sur une surface metallique. Nous avons, entre autres, mis en evidence l'apparition d'une correlation entre evenements successifs lorsque la temperature est comparable a la barriere de diffusion, i.e., la diffusion ne peut pas etre associee a une marche aleatoire. Nous proposons un modele phenomenologique simple qui reproduit bien les resultats des simulations. Ces calculs nous ont aussi permis de montrer que la diffusion obeit a la loi de Meyer-Neldel. Cette loi stipule que, pour un processus active, le prefacteur augmente exponentiellement avec la barriere. En plus, ce travail permet de clarifier l'origine physique de cette loi. En comparant les resultats dynamiques aux resultats statiques, on se rend compte que la barriere extraite des calculs dynamiques est essentiellement la meme que celle obtenue par une approche statique, beaucoup plus simple. On peut donc obtenir cette barriere a l'aide de methodes plus precises, i.e., ab initio, comme la theorie de la fonctionnelle de la densite, qui sont aussi malheureusement beaucoup plus lourdes. C'est ce que nous avons fait pour plusieurs systemes metalliques. Nos resultats avec cette derniere approche se comparent tres bien aux resultats experimentaux. Nous nous sommes attardes plus longuement a la surface (111) du platine. Cette surface regorge de particularites interessantes, comme la forme d'equilibre non-hexagonale des i lots et deux sites d'adsorption differents pour l'adatome. De plus, des calculs ab initio precedents n'ont pas reussi a confirmer la

  6. Voies de recherche en matière de récupération assistée du pétrole par tensio-actifs Research Lines in Enhanced Oil Recovery by Surfactants

    OpenAIRE

    Baviere M.; Defives D.; Labrid J.; Minssieux L.

    2006-01-01

    Quelle que soit la conjoncture économique, le procédé de récupération assistée du pétrole par injection d'agents tensio-actifs nécessite une mise en oeuvre très élaborée pour tirer le meilleur parti des produits et donc pour franchir le seuil de rentabilité. Il apparaît par ailleurs que son champ d'application doit être étendu aux conditions de réservoir couramment rencontrées, notamment les fortes salinités, par l'utilisation de structures chimiques adaptées. Pour réduire les pertes de tensi...

  7. Voies de recherche en matière de récupération assistée du pétrole par tensio-actifs Research Lines in Enhanced Oil Recovery by Surfactants

    Directory of Open Access Journals (Sweden)

    Baviere M.

    2006-11-01

    Full Text Available Quelle que soit la conjoncture économique, le procédé de récupération assistée du pétrole par injection d'agents tensio-actifs nécessite une mise en oeuvre très élaborée pour tirer le meilleur parti des produits et donc pour franchir le seuil de rentabilité. Il apparaît par ailleurs que son champ d'application doit être étendu aux conditions de réservoir couramment rencontrées, notamment les fortes salinités, par l'utilisation de structures chimiques adaptées. Pour réduire les pertes de tensio-actifs par adsorption sur la roche, et par suite, préserver l'efficacité du fluide micellaire, deux techniques sont étudiées à l'Institut Français du Pétrole. L'une d'entre elles consiste à réduire l'adsorption en augmentant le pH de la formation à l'aide d'agents alcalins. Dans l'autre méthode, les molécules adsorbées sont remises en solution par un agent désorbant ajouté à l'eau de chasse. L'extension du procédé aux gisements salés est illustrée avec une famille de tensio-actifs qui ont un comportement prometteur dans ces conditions, les sulfonates d'oléfines alpha. Il apparaît que l'efficacité interfaciale de ces produits ne doit pas être seule prise en compte, mais également la solubilité, la stabilité chimique, le comportement rhéologique et l'adsorption sur les surfaces minérales. No matter what the economic situation may be, the process of enhanced oil recovery (EOR by surfactant flooding requires very sophisticated implementation to take maximum advantage of the chemicals and hence to cross the threshold of economic feasibility. It seems, moreover, that the scope of application of this process must be enlarged to meet the reservoir conditions commonly encountered, particularly high salinity, by the use of suitable chemical structures. To reduce surfactant losses by adsorption on the rock and then to preserve the efficiency of the micellar fluid, two techniques are being investigated at the Institut

  8. Modelisation numerique et validation experimentale d'un systeme de protection contre le givre par elements piezoelectriques

    Science.gov (United States)

    Harvey, Derek

    Le degivrage au moyen d'actuateurs piezoelectriques est considere comme une avenue prometteuse pour le developpement de systemes a faible consommation d'energie applicables aux helicopteres legers. Ce type de systeme excite des frequences de resonances d'une structure pour produire des deformations suffisantes pour rompre l'adherence de la glace. Par contre, la conception de tel systeme demeure generalement mal comprise. Ce projet de maitrise etudie l'utilisation de methodes numeriques pour assister la conception des systemes de protection contre le givre a base d'elements piezoelectriques. La methodologie retenue pour ce projet a ete de modeliser differentes structures simples et de simuler l'excitation harmonique des frequences de resonance au moyen d'actuateurs piezoelectriques. Le calcul des frequences de resonances ainsi que la simulation de leur excitation a ensuite ete validee a l'aide de montages experimentaux. La procedure a ete realisee pour une poutre en porte-a-faux et pour une plaque plane a l'aide du logiciel de calcul par elements finis, Abaqus. De plus, le modele de la plaque plane a ete utilise afin de realiser une etude parametrique portant sur le positionnement des actuateurs, l'effet de la rigidite ainsi que de l'epaisseur de la plaque. Finalement, la plaque plane a ete degivree en chambre climatique. Des cas de degivrage ont ete simules numeriquement afin d'etudier la possibilite d'utiliser un critere base sur la deformation pour predire le succes du systeme. La validation experimentale a confirme la capacite du logiciel a calculer precisement a la fois les frequences et les modes de resonance d'une structure et a simuler leur excitation par des actuateurs piezoelectriques. L'etude revele que la definition de l'amortissement dans le modele numerique est essentiel pour l'obtention de resultats precis. Les resultats de l'etude parametrique ont demontre l'importance de minimiser l'epaisseur et la rigidite afin de reduire la valeur des frequences

  9. Entraînement de globules d'huile par un tensio-actif. Etude de la formation du banc Mobilization of Oil Ganglia by a Surfactant Analysis of Bank Formation

    Directory of Open Access Journals (Sweden)

    Moulu J. C.

    2006-11-01

    Full Text Available Lors de l'injection d'une solution de tensio-actif dans un gisement déjà balayé par de l'eau, l'huile résiduelle, piégée sous la forme de globules discontinus, est remise en mouvement et se regroupe éventuellement sous la forme d'un banc d'huile. Le but de la présente étude est d'expliquer la formation de ce banc au cours d'un tel déplacement. Les résultats d'expériences réalisées en micromodèles de billes de verre permettent de constater que : - la récupération globale est corrélable avec le nombre capillaire Nc= uVdf/O, u et Vdf étant la viscosité et la vitesse de Darcy du fluide injecté, O la tension interfaciale avec l'huile en place ; - la vitesse des globules varie différemment avec u, Vdf, O et tend vers la même limite plus grande que la vitesse du fluide injecté pour de grandes valeurs du nombre capillaire Nc ; - le banc d'huile ne se forme que dans le cas où la vitesse des globules atteint celle du fluide injecté. L'huile déplacée reste alors groupée avec une saturation importante au niveau du front de tensio-actif. When a surfactant solution is injected into a reservoir previously waterflooded, the residual oil trapped as discontinuous ganglia is mobilized and eventually bunched together forming an oil bank. The aim of this study is to explain the formation of this bank during such a drive. The results of experiments performed in micromodels of glass beads show that: a Overall recovery can be correlated with the capillary number, Nc = uVfd/O, in which u and Vfd are the viscosity a and Darcy velocity of the injected fluid and O is the interfacial tension with the oil in place. b Ganglia velocity varies differently with u, Vfd and O, and it tends towards the same limit faster than the velocity of the injected fluid for high values of the capillary number Nc. c The oil bank is formed only in the case where globule velocity attaints that of injected fluid. the dispaced oil then remains bunched, with high

  10. Utilisation des courbes de débit fractionnaire pour l'analyse des phénomènes de récupération par tensio-actif Using Fractional Flow Curves to Analyze Surfactant Recovery Phenomena

    Directory of Open Access Journals (Sweden)

    Moulu J. C.

    2006-11-01

    Full Text Available La connaissance des relations débit fractionnaire-saturation obtenues à partir des courbes de perméabilité relative a permis : - d'expliquer les mécanismes de formation et de propagation des différentes phases mobiles (eau et huile en place, phase aqueuse contenant du tensio-actif et/ou de polymère ; - de prévoir l'allure des courbes de récupération (en particulier la composition et le moment d'arrivée du banc d'huile en déplacement secondaire ou tertiaire ; ces courbe concordent sensiblement avec celles que l'on obtient à partir d'expériences de récupération ; - de tenir compte du volume du bouchon du tensio-actif injecté ; - les paramètres des solutions injectées (tension interfaciale, viscosité, adsorption. . . ayant un effet sur la forme des profils de débit fractionnaire, de mettre en relief le points importants pour l'optimisation des déplacements. Ce type d'analyse par lequel on traite ici un nombre limité de cas peut être généralisé et servir à contrôler les résultats d'expériences ou de simulations numériques. Knowing the fractional flow-saturation relations obtained from relative-permeability curves has made it possible: - to explain the formation and propagation mechanisms of different mobile phases (water and oil in place, aqueous phase containing surfactant and/or polymer ; - to predict the shape of recovery curves (in particular the composition and arrival time of the oil bank for secondary or tertiary recovery; these curves more or less agree with the ones obtained from recovery experiments; - to take into consideration the volume of the surfactant slug injected; - to highlight the important points for optimizing displacements using the parameters of injected solutions (interfacial tension, viscosity, adsorption, etc. having an effect on the shape of fractional flow profiles. This type of analysis, in which a limited number of cases are dealt with here, can be generalized and used to check the

  11. Comparison of ensemble post-processing approaches, based on empirical and dynamical error modelisation of rainfall-runoff model forecasts

    Science.gov (United States)

    Chardon, J.; Mathevet, T.; Le Lay, M.; Gailhard, J.

    2012-04-01

    In the context of a national energy company (EDF : Electricité de France), hydro-meteorological forecasts are necessary to ensure safety and security of installations, meet environmental standards and improve water ressources management and decision making. Hydrological ensemble forecasts allow a better representation of meteorological and hydrological forecasts uncertainties and improve human expertise of hydrological forecasts, which is essential to synthesize available informations, coming from different meteorological and hydrological models and human experience. An operational hydrological ensemble forecasting chain has been developed at EDF since 2008 and is being used since 2010 on more than 30 watersheds in France. This ensemble forecasting chain is characterized ensemble pre-processing (rainfall and temperature) and post-processing (streamflow), where a large human expertise is solicited. The aim of this paper is to compare 2 hydrological ensemble post-processing methods developed at EDF in order improve ensemble forecasts reliability (similar to Monatanari &Brath, 2004; Schaefli et al., 2007). The aim of the post-processing methods is to dress hydrological ensemble forecasts with hydrological model uncertainties, based on perfect forecasts. The first method (called empirical approach) is based on a statistical modelisation of empirical error of perfect forecasts, by streamflow sub-samples of quantile class and lead-time. The second method (called dynamical approach) is based on streamflow sub-samples of quantile class and streamflow variation, and lead-time. On a set of 20 watersheds used for operational forecasts, results show that both approaches are necessary to ensure a good post-processing of hydrological ensemble, allowing a good improvement of reliability, skill and sharpness of ensemble forecasts. The comparison of the empirical and dynamical approaches shows the limits of the empirical approach which is not able to take into account hydrological

  12. Ground observations and remote sensing data for integrated modelisation of water budget in the Merguellil catchment, Tunisia

    Science.gov (United States)

    Mougenot, Bernard

    2016-04-01

    The Mediterranean region is affected by water scarcity. Some countries as Tunisia reached the limit of 550 m3/year/capita due overexploitation of low water resources for irrigation, domestic uses and industry. A lot of programs aim to evaluate strategies to improve water consumption at regional level. In central Tunisia, on the Merguellil catchment, we develop integrated water resources modelisations based on social investigations, ground observations and remote sensing data. The main objective is to close the water budget at regional level and to estimate irrigation and water pumping to test scenarios with endusers. Our works benefit from French, bilateral and European projects (ANR, MISTRALS/SICMed, FP6, FP7…), GMES/GEOLAND-ESA) and also network projects as JECAM and AERONET, where the Merguellil site is a reference. This site has specific characteristics associating irrigated and rainfed crops mixing cereals, market gardening and orchards and will be proposed as a new environmental observing system connected to the OMERE, TENSIFT and OSR systems respectively in Tunisia, Morocco and France. We show here an original and large set of ground and remote sensing data mainly acquired from 2008 to present to be used for calibration/validation of water budget processes and integrated models for present and scenarios: - Ground data: meteorological stations, water budget at local scale: fluxes tower, soil fluxes, soil and surface temperature, soil moisture, drainage, flow, water level in lakes, aquifer, vegetation parameters on selected fieds/month (LAI, height, biomass, yield), land cover: 3 times/year, bare soil roughness, irrigation and pumping estimations, soil texture. - Remote sensing data: remote sensing products from multi-platform (MODIS, SPOT, LANDSAT, ASTER, PLEIADES, ASAR, COSMO-SkyMed, TerraSAR X…), multi-wavelength (solar, micro-wave and thermal) and multi-resolution (0.5 meters to 1 km). Ground observations are used (1) to calibrate soil

  13. Etude d'un procédé d'hydroliquéfaction du charbon pour la production simultanée de gaz et de carburant . . . . . Studies of a Coal Hydrogenation Process to Produce CO-Currently Gas and Gasoline

    Directory of Open Access Journals (Sweden)

    Franckowiak S.

    2006-11-01

    Full Text Available Un des principaux moyens de réintroduire le charbon dans le marché énergétique français est de le transformer en produits utiles comme le gaz de réseau ou les carburants. Les procédés d'oxyvapogazéification permettent d'obtenir un gaz de synthèse qui peut être ensuite converti en gaz riche ou en produits liquides. L'hydrogénation en phase liquide (ou hydroliquéfaction se présente pour le long terme comme une seconde voie qui offre des avantages spécifiques - taux de conversion du charbon et rendement élevés, - production directe de gaz de substitution (GNS et de carburant, - possibilité d'utilisation d'hydrogène provenant de l'électricité nucléaire. Un programme d'étude a été lancé avec la participation du Gaz de France (GDF, du Centre d'études et de recherches des Charbonnages de France (Cerchar, de l'institut Français du Pétrole (lFP et du Centre National de la Recherche Scientifique (CNRS dans le cadre du Groupe d'Étude de la Conversion du Charbon par Hydrogénation (GECH. Un banc d'essai d'hydroliquéfaction situé au Cerchar, d'un débit de 10 kg/h de mélange charbon-solvant, permet d'obtenir des hydrogénats dans des conditions variées et en présence de divers catalyseurs. L'étude de la valorisation de ces hydrogénats est effectuée dans les laboratoires de l'lFP. Les essais et les études effectués permettent d'envisager la production à volonté du GNS, de carburants ou des deux ensemble. Un modèle d'optimisation a été réalisé au GDF pour étudier et comparer les différentes filières en prenant en compte l'utilisation d'hydrogène d'électrolyse ou d'hydrogène produit sur place à partir du résidu de liquéfaction. One of the main ways to bring coal in the future french energy market is to transform it into valuable products. The oxygen steam gasification processes give a synthesis gas which can be converted into SNG or gasoline in a catalytic stage. The liquid phase hydrogenation process is a

  14. Physico-Chimie des Atomcules d'Hélium antiprotonique: Modélisation de Processus réactifs en présence d'Antimatière

    Science.gov (United States)

    Sauge, Sébastien

    2000-07-01

    Environ 3%des antiprotons (p) stoppés dans l'hélium survivent plusieurs microsecondes, contre quelques picosecondes dans tout autre matériau. Cette métastabilité inhabituelle résulte d'une capture sur des états liés de l'atome exotique pHe+, dénommé atomcule car il s'apparente à la fois à un atome de Rydberg quasi-circulaire quasi-classique de grand moment angulaire l n-1 37et à une molécule diatomique composée d'un noyau chargé négativement et caractérisée par une forte excitation rotationnelle J=l. En dehors de cette structure duale originale accessible par spectroscopie laser, la physico-chimie de leur interaction avec d'autres atomes ou molécules a fait l'objet d'études microscopiques. Alors que les atomcules résistent à des millions de collisions dans l'hélium pur, des contaminants moléculaires comme H2 les détruisent immédiatement, y compris à basse température. Dans le cadre Born-Oppenheimer, nous interprétons l'interaction moléculaire, calculée par des techniques de chimie quantique {ab initio}, en termes de chemins réactifs classiques, qui présentent des barrières d'activation compatibles avec celles mesurées dans He et H2.Nous montrons par une approche Monte Carlo de trajectoires classiques que la thermalisation détruit fortement les populations initiales, portant la fraction estimée des états de capture à 3%. Nous étudions aussi la recombinaison dissociative pHe+ + e+ e -dans une approche de trajectoires classiques pour les noyaux: nous prédisons la synthèse d'antihydrogène avec un rapport de branchement de 10%, ainsi qu'une nouvelle classe d'atomcules métastables ?={p}, e+, 2e-, qui pourrait être confirmée par spectroscopie. Ce travail illustre la transférabilité des concepts de chimie physique à l'étude de processus exotiques en présence d'antimatière, et apporte un éclairage nouveau sur la physico-chimie des radicaux interstellaires froids.

  15. 1319-IJBCS-Article-Anatole Kifuani

    African Journals Online (AJOL)

    KODJIO NORBERT

    Adsorption de la quinine bichlorhydrate sur un charbon actif peu coûteux à base de la .... partir de l'équation suivante : SBM = Qm ..... Lagergren (Ho et McKay, 1998 ; Srivastava et al., 2006) : ..... pH 5,82. Figure 10: Application du modèle cinétique d'ELOVICH pour l'adsorption de QBC, en ..... Process Safety Environmental.

  16. Research on the structure in solution of optically active synthetic polymers (propylene polysulphide, propylene polyoxide, tertio-butyl polysulphide); Recherche de la structure en solution de polymeres synthetiques, optiquement actifs (polysulfure de propylene, polyoxyde de propylene, polysulfure de tertiobutyle)

    Energy Technology Data Exchange (ETDEWEB)

    Sarrazin, Brigitte

    1971-03-15

    It was proposed to study the structure of sulphur-containing synthetic polymers, stereo-regular, optically active in solution and able to adopt a spiral conformation, with special reference to propylene polysulphide. Two methods were used, the first mathematical (conformational energy calculations) and the second physico-chemical, essentially spectroscopic. By conformational analysis it is possible to choose the most probable structures liable to be adopted by a given polymer in solution while the spectro-polarimetric study should, in principle, invalidate or confirm certain of these hypotheses. The conformational energy calculations showed that in fact there is no energy conformation low enough to be stable in solution. Strictly speaking however we can refer to a region of stability in which steric hindrance is low and many energy minima exist. These minima are indistinguishable both by their energy values and by their spatial localizations and are all enclosed in the region bounded by the barriers due to steric hindrance. This uncertainty does not arise from approximations made in the calculations, but from the multitude of stereochemical structure possible. Investigations into the variation of the optical rotary dispersion and the circular dichroism as a function of temperature indicated the existence of three or more equilibrium states in the dioxane. The spectra appear to be the summation of the optical activities of the numerous simultaneously possible conformations. It appears that polymers, such as propylene polysulphide or propylene polyoxide do not have stable structures in solution. These are molecules of great flexibility possessing a large number of degrees of freedom. These properties distinguish them from the natural polymers, carrying precise information, such as DNA which must consequently have stable conformations. (author) [French] On s'est propose d'etudier la structure de polymeres synthetiques soufres, stereoreguliers, optiquement actifs en

  17. Nuclear geophysics in prospecting for ore and coal deposits; Geophysique nucleaire et prospection des gisements de charbon et autres mineraux; Yadernaya geofizika pri razvedke rudnykh i ugol'nykh mestorozhdenij; Geofisica nuclear u prospeccion de yacimientos de carbon y otros minerales

    Energy Technology Data Exchange (ETDEWEB)

    Bulashevich, Yu P; Voskobojnikov, G M; Muzyukin, L V

    1962-01-15

    eliminated by inverse probes. These neutron methods, and similarly neutron-activation logging, have also been applied at deposits of copper, manganese, aluminium and various other ores. Continuous-activation logging is appropriate where the occurring radioisotope has a suitable half-life. It is then possible to determine the optimum logging conditions (rate, length of probe, etc.) theoretically. Neutron recording during photo-neutron logging makes it possible to distinguish ore bodies containing beryllium, and to estimate the beryllium content from 0.001% upwards. Experience is confirming the effectiveness and economic expediency of nuclear geophysical methods in prospecting for ore and coal deposits. (author) [French] Les methodes de geophysique nucleaire s'emploient surtout pour l'exploration des gisements de charbon et autres mineraux par radiosondage. Dans le cas des gisements de charbon et d'autres mineraux de l'Union sovietique, les types suivants de prospection par sondage radioactif ou nucleaire (SR) trouvent une large application pratique : determination de la densite ou sondage gamma-gamma (S.G.G.) avec le {sup 60}cO comme source de rayonnements, sondage gamma-gamma selectif (S.G.G.S.) avec une source de rayonnements mous du type {sup 75}Se, sondage neutronsneutrons (S.N.N.) et sondage gamma-neutrons (S.G.N.) avec une source de neutrons Po-Be, sondage par activation - surtout par activation continue - avec emploi de la meme source, et sondage photo-neutronique avec l'emetteur gamma {sup 124}Sb. L'objet essentiel du S.R., dans les gisements de minerais, est de reconnaitre les differentes couches de minerais que l'on rencontre dans le trou de sonde, ce qui reduit le temps d'analyse, ainsi que d'evaluer approximativement, sur place, la teneur en elements utiles. Dans les gisements de charbon, le S.R. permet de determiner la profondeur, l'importance et la structure des veines. Les methodes dites S.G.G. et S.G.G.S. sont fondees sur l'enregistrement du rayonnement gamma

  18. Modelisation de l'erosion et des sources de pollution dans le bassin versant Iroquois/Blanchette dans un contexte de changements climatiques

    Science.gov (United States)

    Coulibaly, Issa

    Principale source d'approvisionnement en eau potable de la municipalite d'Edmundston, le bassin versant Iroquois/Blanchette est un enjeu capital pour cette derniere, d'ou les efforts constants deployes pour assurer la preservation de la qualite de son eau. A cet effet, plusieurs etudes y ont ete menees. Les plus recentes ont identifie des menaces de pollution de diverses origines dont celles associees aux changements climatiques (e.g. Maaref 2012). Au regard des impacts des modifications climatiques annonces a l'echelle du Nouveau-Brunswick, le bassin versant Iroquois/Blanchette pourrait etre fortement affecte, et cela de diverses facons. Plusieurs scenarios d'impacts sont envisageables, notamment les risques d'inondation, d'erosion et de pollution a travers une augmentation des precipitations et du ruissellement. Face a toutes ces menaces eventuelles, l'objectif de cette etude est d'evaluer les impacts potentiels des changements climatiques sur les risques d'erosion et de pollution a l'echelle du bassin versant Iroquois/Blanchette. Pour ce faire, la version canadienne de l'equation universelle revisee des pertes en sol RUSLE-CAN et le modele hydrologique SWAT ( Soil and Water Assessment Tool) ont ete utilises pour modeliser les risques d'erosion et de pollution au niveau dans la zone d'etude. Les donnees utilisees pour realiser ce travail proviennent de sources diverses et variees (teledetections, pedologiques, topographiques, meteorologiques, etc.). Les simulations ont ete realisees en deux etapes distinctes, d'abord dans les conditions actuelles ou l'annee 2013 a ete choisie comme annee de reference, ensuite en 2025 et 2050. Les resultats obtenus montrent une tendance a la hausse de la production de sediments dans les prochaines annees. La production maximale annuelle augmente de 8,34 % et 8,08 % respectivement en 2025 et 2050 selon notre scenario le plus optimiste, et de 29,99 % en 2025 et 29,72 % en 2050 selon le scenario le plus pessimiste par rapport a celle

  19. Application des fluides supercritiques à la production d'hydrocarbures. Exploitation des gisements par récupération assistée et applications diverses : pétrole, sables, schistes, charbons Application of Supercritical Fluids to Hydrocarbon Production. Enhanced Oi Recovery and Miscellaneous Applications: Oil, Tar Sands, Shales, Coals

    Directory of Open Access Journals (Sweden)

    Behar E.

    2006-11-01

    Full Text Available Le taux moyen de récupération par drainage naturel des gisements pétroliers atteint à peine 30 %. La récupération assistée désigne l'ensemble des procédés d'exploitation qui permettent d'accroître très sensiblement ce taux. Parmi ces procédés, l'injection de fluides supercritiques joue un rôle prometteur. Les principaux fluides actuellement utilisés sont : le méthane (ou plus généralement les gaz hydrocarbures dits pauvres , l'azote et enfin le gaz carbonique. Les domaines d'application et les mécanismes thermodynamiques mis en jeu sont brièvement exposés, les sources de fluides supercritiques disponibles au voisinage des gisements pétroliers sont rapidement répertoriées et certains problèmes d'exploitation évoqués. Outre leur application en récupération assistée, les fluides supercritiques sont également impliqués dans des procédés de raffinage et d'extraction divers. C'est le procédé de désasphaltage de fractions pétrolières lourdes qui, en 1956, a fait l'objet de la première application industrielle exploitant les fortes variations du pouvoir solvant d'un fluide au voisinage de son point critique. Ce procédé connaît, depuis une dizaine d'années, un regain d'intérêt du fait de l'économie d'énergie qu'il permet de réaliser. D'autre part, les schistes bitumineux, les sables asphaltiques et les charbons, sources d'hydrocarbures considérables pour l'avenir, constituent des domaines d'applications potentielles originales des fluides supercritiques. Les procédés spécifiques, pour la plupart en cours de développement au stade pilote, sont passés en revue. The average recovery by natural drainage from oil fields is barely 30%. Enhanced recovery includes all production processes which appreciably increase this rate. Among such processes, supercritical fluid flooding is quite promising. The main fluids now used are methane (or, more generally, so-called leangaseous hydrocarbons, nitrogen and carbon

  20. PREPARATION DES COMPOSITES BENTONITE-DERIVES DE P4VP APPLICATION A LA RETENTION DES COLORANTS TEXTILE

    OpenAIRE

    GADIRI, ANISSA

    2014-01-01

    Les industries du textile rejettent de grandes quantités d‘eaux usées présentant un risque de toxicité. Il existe déjà des traitements tels que l‘adsorption sur charbon actif qui est un processus efficace mais onéreux et qui produit une boue constituant elle même une menace environnementale. Les argiles, les poly (4-vinylpyridine) et ses dérivées pourraient être des matériaux adsorbants alternatifs à la fois économiques et moins polluants. Beaucoup d‘auteurs ont étudié l‘adsorptio...

  1. Krypton purification (1961); Purification du krypton (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Larher, Y [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Institut Fourier, 38 - Grenoble (France)

    1961-07-01

    The amount of xenon in otherwise very pure krypton can be reduced from 1.5 to 0.0025 per cent approximately by passage through an activated carbon column at dry-ice temperature. The circulation of the krypton is effected by condensing at -196 deg. C and then evaporating. (author) [French] Le taux de xenon dans du krypton par ailleurs tres pur est ramene de 1,5 pour cent a 0,0025 pour cent environ au cours d'un passage a travers une colonne de charbon actif a la temperature de la carboglace. La circulation du krypton se fait par condensation a -196 deg. C, puis evaporation. (auteur)

  2. Progress report 2003 - coal; Rapport d'activite 2003 - charbon

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This report presents the activities of the Group ''Charbonnages de France'' in 2003. The administration council is detailed in the new structure and organization. It concerns also the end of the industrial activities, the social policy, the mine sites remediation, the industrialization of mine regions, the financial results and key data. (A.L.B.)

  3. Coal: the dinosaur wakes up; Charbon: le dinosaure se reveille

    Energy Technology Data Exchange (ETDEWEB)

    Rousseau, Y.; Cosnard, D

    2005-10-01

    In western countries, coal is considered as an industry of the past, but at the Earth's scale the situation is radically the opposite. Since three years, coal is the faster developing energy source, in particular thanks to China expansion and to the oil crisis which makes coal more competitive. This short paper presents the situation of coal mining in China: projects, working conditions and environmental impact. (J.S.)

  4. Modeling of acoustic wave propagation and scattering for telemetry of complex structures; Modelisation de la propagation et de l'interaction d'une onde acoustique pour la telemetrie de structures complexes

    Energy Technology Data Exchange (ETDEWEB)

    LU, B.

    2011-11-07

    ) using a procedure similar to the physical theory of diffraction (PTD). The refined KA provides an improvement of the prediction in the near field of a rigid scatterer. The initial (non refined) KA model is then extended to deal with the scattering from a finite impedance target. The obtained model, the so-called 'general' KA model, is a satisfactory solution for the application to telemetry. Finally, the coupling of the stochastic propagation model and the general KA diffraction model has allowed us to build a complete simulation tool for the telemetry in an inhomogeneous medium. (author) [French] Cette etude s'inscrit dans le cadre du developpement d'outils de simulation de la telemetrie qui est une technique possible pour la surveillance et le controle periodique des reacteurs nucleaires a neutrons rapides refroidis par du sodium liquide (RNR-Na). De maniere generale, la telemetrie consiste a positionner au sein du reacteur un transducteur qui genere un faisceau ultrasonore. Ce faisceau se propage a travers un milieu inhomogene et aleatoire car le sodium liquide est le siege de fluctuations de temperature qui impliquent une variation de la celerite des ondes ultrasonores, ce qui modifie la propagation du faisceau. Ce dernier interagit ensuite avec une structure immergee dans le reacteur. La mesure du temps de vol de l'echo recu par le meme transducteur permet de determiner la position precise de la structure. La simulation complete de la telemetrie necessite donc la modelisation a la fois de la propagation d'une onde acoustique en milieu inhomogene aleatoire et de l'interaction de cette onde avec des cibles de formes variees; c'est l'objectif de ce travail. Un modele stochastique base sur un algorithme de type Monte-Carlo est tout d'abord developpe afin de simuler les perturbations aleatoires du champ de propagation. Le champ acoustique en milieu inhomogene est finalement modelise a partir du champ calcule dans un

  5. Evidence of independent action of neurohypophyseal peptides on osmotic water flow and active sodium transport in the same target organ: studies on RANA esculenta skin and bladder (1961); Arguments en faveur de l'independance des mecanismes d'action de divers peptides neurohypophysaires sur le flux osmotique d'eau et sur le transport actif de sodium au sein d'un meme recepteur: etudes sur la vessie et la peau de RANA esculanta L (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Bourguet, J; Maetz, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    Neurohypophyseal peptides produce on the skin and bladder of certain amphibia simultaneous increases of the passive osmotic permeability to water and active transport of sodium. The present work shows that oxytocin and two of its analogues arginine-8-oxytocin (arginine vasotocin) and lysine-8-oxytocin (lysine vasotocin) may produce the same increase of water permeability, while stimulating in quite different ways the sodium transport. This is the case for both skin and bladder. In other words, there is no correlation between natriferic and hydro-osmotic activities. The results are interpreted as evidence that neurohypophyseal hormones act on not one, as previously assumed, but two targets, inside the same epithelial cell. (author) [French] Les peptides neurohypophysaires produisent simultanement une augmentation de la permeabilite osmotique passive a l'eau, et une stimulation du transport actif de sodium sur la peau et sur la vessie de certains amphibiens. Ce travail montre que l'ocytocine et deux de ses analogues, l'arginine 8-ocytocine (arginine vasotocine) et la lysine-8-ocytocine (lysine vasotocine ) entrainent un accroissement identique de la permeabilite a l'eau, mais stimulent de facon differente le transport de sodium. Ceci est vrai aussi bien pour la peau que pour la vessie. Autrement dit, il n'existe pas de correlation entre les activites natriferique et hydrosmotique. Les resultats suggerent que les hormones neurohypophysaires agissent non sur une seule cible comme on l'avait cru, mais sur deux cibles se trouvant dans la meme cellule. (auteur)

  6. The active thermal solar; Le solaire thermique actif

    Energy Technology Data Exchange (ETDEWEB)

    Bedel, St.; Salomon, Th.

    2000-05-01

    This information paper recalls the different types of solar cells and their operating. It presents the possible utilizations for the buildings heating (air and water systems) and for the water heating in the residential houses (also for the heating of swimming pools) and the collective buildings. The drying of agricultural products and the solar cooling are also discussed. (A.L.B.)

  7. Vinyl Sulfonate/Vinyl Amide Copolymers and Different Surfactants As Suitable Systems in Eorat Higher Temperatures and Salinities Utilisation de mélanges de copolymères vinyl sulfonate/vinyl amide et de différents tensio-actifs en RAP dans des conditions de fortes salinités et de températures élevées

    Directory of Open Access Journals (Sweden)

    Von Halasz S. P.

    2006-11-01

    Full Text Available For enhanced oil recovery flooding processes there will be an increasing demand for polymers having high temperature and electrolyte stability. High molecular weight copolymers based on vinyl sulfonate, vinyl amide, and acryl amide show high performances in matching these demanding requirements. Surfactants are also known that are stable under these conditions, resulting in high deoiling rates. The aim of the present article is to demonstrate the influence of alkylphenol ethoxylates and their corresponding ether sulfonates on VS/VA/AM copolymer solutions. Aqueous solutions of such copolymers were added to varying quantities of nonionic and anionic surfactants at different temperatures using salinity scans. This article discusses the results of experiments with solutions of copolymers and surfactants in terms of compatibility, viscosity yield, flow properties, shear stability, injectability, thermostability, and oil recovery. Solutions of alkylphenol ethoxylates and/or ether sulfonates show nearly the same compatibility within a broad range of temperature and salinity, both with and without polymers. Relatively small amounts of surfactants are able to influence the EOR (Enhanced Oil Recovery properties of the polymer solutions, giving several interesting aspects for improved oil recovery. L'utilisation des polymères en récupération assistée du pétrole a fait apparaître un besoin croissant de polymères stables à haute température et à forte salinité. Les performances des terpolymères vinyl sulfonate/vinyl amide/acrylamide (VS/VA/VM ont montré que ces polymères remplissent de tels critères d'utilisation. On connaît également des tensio-actifs chimiquement stables dans ces mêmes conditions qui pourraient donc permettre d'obtenir des taux de récupération d'huile élevés. L'objectif de ce travail est de mettre en évidence l'influence de la présence d'alkylphénols éthoxyIates et des éthers sulfonates correspondants sur les

  8. Modelling Adsorption of Foam-Forming Surfactants on Heterogeneous Surfaces Using the Surface Excess Formalism Conception de modèle pour l'adsorption des agents tensio-actifs moussants sur des surfaces hétérogènes en faisant appel au formalisme de l'excès de surface

    Directory of Open Access Journals (Sweden)

    Mannhardt K.

    2006-11-01

    Full Text Available Adsorption at the solid/liquid interface is detrimental to most enhanced oil recovery processes that make use of surfactants. This paper describes several extensions to a previously described surface excess model of adsorption in flow through porous media [7, 8]. It is shown that two parameters of the model, the monolayer coverages of surfactant and water, can be determined independently, thus reducing the number of adjustable parameters in the model from six to four. Experimental evidence suggests that the selectivity, previously assumed constant, should be a function of concentration. A functional form of selectivity that is derived from thermodynamic principles is incorporated into the model. Finally, adsorption on heterogeneous surfaces is discussed, and a simple form of surface heterogeneity (a bimodal distribution of selectivities is incorporated into the model and its benefits in determining adsorption isotherms from core flood data are demonstrated. L'adsorption à l'interface solide/liquide nuit aux procédés de RAH qui utilisent des tensio-actifs. Pour la réussite de ces procédés, il est par conséquent impératif de connaître les niveaux d'adsorption et de bien en comprendre les mécanismes. Le modèle qui fait appel au concept d'excès de surface pour décrire l'adsorption dans les écoulements traversant un milieu poreux a été décrit dans des articles précédents et a été utilisé pour évaluer l'adsorption d'un certain nombre d'agents tensioactifs moussants [7,8]. Le présent article étudie trois développements de ce modèle. Le modèle d'adsorption comporte un ensemble de paramètres ajustables qui sont utilisés pour faire correspondre les concentrations d'effluents simulées et expérimentales lors d'une injection en milieu poreux. Ces paramètres peuvent ensuite être utilisés pour calculer les isothermes d'adsorption de certains systèmes. Deux des paramètres du modèle, les revêtements monocouche de

  9. Modelisation of the fission cross section

    International Nuclear Information System (INIS)

    Morariu, Claudia

    2013-03-01

    The neutron cross sections of four nuclear systems (n+ 235 U, n+ 233 U, n+ 241 Am and n+ 237 Np) are studied in the present document. The target nuclei of the first case, like 235 U and 239 Pu, have a large fission cross section after the absorption of thermal neutrons. These nuclei are called 'fissile' nuclei. The other type of nuclei, like 237 Np and 241 Am, fission mostly with fast neutrons, which exceed the fission threshold energy. These types of nuclei are called 'fertile'. The compound nuclei of the fertile nuclei have a binding energy higher than the fission barrier, while for the fissile nuclei the binding energy is lower than the fission barrier. In this work, the neutron induced cross sections for both types of nuclei are evaluated in the fast energy range. The total, reaction and shape-elastic cross sections are calculated by the coupled channel method of the optical model code ECIS, while the compound nucleus mechanism are treated by the statistical models implemented in the codes STATIS, GNASH and TALYS. The STATIS code includes a refined model of the fission process. Results from the theoretical calculations are compared with data retrieved from the experimental data base EXFOR. (author) [fr

  10. Knowledge bases for modelisation of industrial plants

    International Nuclear Information System (INIS)

    Lorre, J.P.; Evrard, J.M.; Dorlet, E.

    1992-01-01

    Our experience in the development of numerous knowledge based control systems for large industrial applications has led us to the expression of a generic problem and to the implementation of the tools to address it. This paper illustrates, with different practical examples that we have encountered, the principal concepts found in the modelling and management of large industrial knowledge bases. We thus arrive at the definition of the formalism to be used. The principles described are now integrated into the tool SPIRAL and are currently being employed in the development of several applications

  11. Turbulence modelling; Modelisation de la turbulence isotherme

    Energy Technology Data Exchange (ETDEWEB)

    Laurence, D. [Electricite de France (EDF), Direction des Etudes et Recherches, 92 - Clamart (France)

    1997-12-31

    This paper is an introduction course in modelling turbulent thermohydraulics, aimed at computational fluid dynamics users. No specific knowledge other than the Navier Stokes equations is required beforehand. Chapter I (which those who are not beginners can skip) provides basic ideas on turbulence physics and is taken up in a textbook prepared by the teaching team of the ENPC (Benque, Viollet). Chapter II describes turbulent viscosity type modelling and the 2k-{epsilon} two equations model. It provides details of the channel flow case and the boundary conditions. Chapter III describes the `standard` (R{sub ij}-{epsilon}) Reynolds tensions transport model and introduces more recent models called `feasible`. A second paper deals with heat transfer and the effects of gravity, and returns to the Reynolds stress transport model. (author). 37 refs.

  12. Modelisation de la conversion electromecanique des machines ...

    African Journals Online (AJOL)

    These implemented models would constitute the module of possible generators that one could couple with a model of wind power engine in order to study, within the framework of a virtual laboratory, the performances of wind-driven systems of electricity generation. Cet article présente les modèles de machines électriques ...

  13. modelisation du comportement hydrologique du bassin versant

    African Journals Online (AJOL)

    LGE

    gestion optimale de l‟eau sur un bassin versant. ..... paramètres sont vérifiés sur la (s) période (s) de contrôle afin de s‟assurer ... critère est très utilisé en hydrologie pour évaluer les performances des modèles pluie-débit. ..... Dans un second temps, il peut d‟agir de la procédure de mesure des débits qui est basée sur la.

  14. Simulation - modeling - experiment; Simulation - modelisation - experience

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    After two workshops held in 2001 on the same topics, and in order to make a status of the advances in the domain of simulation and measurements, the main goals proposed for this workshop are: the presentation of the state-of-the-art of tools, methods and experiments in the domains of interest of the Gedepeon research group, the exchange of information about the possibilities of use of computer codes and facilities, about the understanding of physical and chemical phenomena, and about development and experiment needs. This document gathers 18 presentations (slides) among the 19 given at this workshop and dealing with: the deterministic and stochastic codes in reactor physics (Rimpault G.); MURE: an evolution code coupled with MCNP (Meplan O.); neutronic calculation of future reactors at EdF (Lecarpentier D.); advance status of the MCNP/TRIO-U neutronic/thermal-hydraulics coupling (Nuttin A.); the FLICA4/TRIPOLI4 thermal-hydraulics/neutronics coupling (Aniel S.); methods of disturbances and sensitivity analysis of nuclear data in reactor physics, application to VENUS-2 experimental reactor (Bidaud A.); modeling for the reliability improvement of an ADS accelerator (Biarotte J.L.); residual gas compensation of the space charge of intense beams (Ben Ismail A.); experimental determination and numerical modeling of phase equilibrium diagrams of interest in nuclear applications (Gachon J.C.); modeling of irradiation effects (Barbu A.); elastic limit and irradiation damage in Fe-Cr alloys: simulation and experiment (Pontikis V.); experimental measurements of spallation residues, comparison with Monte-Carlo simulation codes (Fallot M.); the spallation target-reactor coupling (Rimpault G.); tools and data (Grouiller J.P.); models in high energy transport codes: status and perspective (Leray S.); other ways of investigation for spallation (Audoin L.); neutrons and light particles production at intermediate energies (20-200 MeV) with iron, lead and uranium targets (Le Colley F.R.); nuclear data for transmutation (Noguere G.). (J.S.)

  15. The comeback of coal: very risky; Le retour du charbon: un pari a haut risque

    Energy Technology Data Exchange (ETDEWEB)

    Delbecq, D.

    2012-02-15

    Coal is still largely used in developed countries and is the backbone of the energy growth in developing countries. The consumption of coal is expected to grow worldwide in the bracket 25% - 60% between 2009 and 2035 according to different scenarios. The Fukushima accident has aggravated the situation, some countries like Japan and Germany are turning to coal. The main obstacle to carbon sequestration is its cost: carbon capture and sequestration could double the price of electricity. The renaissance of coal is appalling because of its impact on climate warming and on its toll in humane lives. According to the WHO about 24000 people died of silicosis in China each year between 1991 and 1995. (A.C.)

  16. Coal. Fluidized bed, a world record; Charbon. Lit fluidise: record mondial

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    In April 1996, the `Societe Provencale du Lit Fluidise`, a subsidiary of Electricite de France (EDF) has put into service in Gardanne, the most powerful circulating fluidized bed boiler in the world, producing 600 MWt; it was constructed by GEC Alsthom Stein Industrie, and will strongly reduce the SO{sub 2} emissions from the coal power plant of Gardanne, which use a highly sulfurous coal. New regulations concerning the French coal industry are also introduced

  17. Progress report 2003 - coal; Rapport d'activite 2003 - charbon

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This report presents the activities of the Group ''Charbonnages de France'' in 2003. The administration council is detailed in the new structure and organization. It concerns also the end of the industrial activities, the social policy, the mine sites remediation, the industrialization of mine regions, the financial results and key data. (A.L.B.)

  18. Adsorption isotherme de l'acide acétique par des charbons d'origine ...

    African Journals Online (AJOL)

    The adsorption properties of six samples of carbons of which two are obtained from AYOUS (Triplochiton Scléroxylon), two from AKOM (Terminalia Superba) and two obtained commercially were studied from their adsorption isotherms of acetic acid at 30° and 45°C. This study has resulted in the determination of the two ...

  19. Coal. Fluidized bed, a world record; Charbon. Lit fluidise: record mondial

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    In April 1996, the `Societe Provencale du Lit Fluidise`, a subsidiary of Electricite de France (EDF) has put into service in Gardanne, the most powerful circulating fluidized bed boiler in the world, producing 600 MWt; it was constructed by GEC Alsthom Stein Industrie, and will strongly reduce the SO{sub 2} emissions from the coal power plant of Gardanne, which use a highly sulfurous coal. New regulations concerning the French coal industry are also introduced

  20. Problems of underground gasification of coal. Les Problemes que pose une gazeification souterraine des charbons

    Energy Technology Data Exchange (ETDEWEB)

    Doumenc, R A.M.

    1948-11-01

    Underground gasification is examined in collaboration with Socogaz of Brussels. The USSR has been successful and claims to have produced gas of 1,000 cal per cu m at the rate of 30,000 cu m per hr at Gorlovka (Donets). Results of the American, Belgian, and Italian experiments show that the gas produced contains much CO/sub 2/ and only 5 percent CO. The coal has been burned but not gasified. If the main problem to be solved should be production of a rich gas for burning or a sufficiently hot gas for direct heating, many difficulties would need to be overcome, such as remote control of the fire, choice of suitable coal seams, etc. The underground process is attractive because of the great saving in labor. As it is impossible to reproduce conditions on a laboratory scale, the time and expenditure required for these lengthy experiments seem to be amply justified.

  1. Coal: resources, reserves and production - Panorama 2008; Charbon: ressources, reserves et production - Panorama 2008

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    For the French, whose last coal mine closed in 2004, the 'comeback' of coal as a political issue may seem a bit surprising. Even if coal is still used in domestic industry and to produce electricity, it is many years since it was used as the primary energy source for electricity production. This situation, specific to France and certain European countries, is not at all typical of the world situation: in the face of surging energy demand, coal - whose reserves have been estimated by the World Energy Council to cover 145 years of consumption at the current rate - seems to be an energy of the future and an alternative to oil, natural gas and nuclear power for the production of electricity.

  2. Enrobages actifs contenants des peptides antimicrobiens nano-vectorisés

    OpenAIRE

    IMRAN , Muhammad

    2011-01-01

    Food nanotechnology has the potential to improve food safety and bio-security, food processing, food packaging and functional ingredients. Nano-encapsulation of active agents is an innovative concept to protect them against possible denaturation during processing and storage. The overall objective of the present work was to optimize and develop fluorescent labeling and encapsulation of nisin for molecular transfer study in different packaging based on biopolymers and in the food. Nanoencapsul...

  3. APPROCHE POSITIVE DE L'EXTERNALISATION D'ACTIFS : CAS DE LA TITRISATION

    OpenAIRE

    Lejard , Christophe

    2007-01-01

    International audience; les scandales financiers du début des années deux mille ont levé le voile sur un certains nombre de pratiques comptables caractérisées par un manque d'éthique manifeste. Parmi ces pratiques, les montages dits déconsolidants occupèrent une place prépondérante ; ils se matérialisèrent notamment par le recours à diverses opérations financières via un véhicule ad hoc. L'objectif de ce type de montage est l'embellissement de la situation économique de l'entreprise en occult...

  4. Structural Aspects of Flexible Aircraft Control (les Aspects structuraux du controle actif et flexible des aeronefs)

    Science.gov (United States)

    2000-05-01

    est constitude par un .les pressions sur la gouveme et le ensemble de 17 pouts de jauge , de 20 moment de charni~re sont surestimds accildrom~tes, de...avec les corrdlations calcul-essais 130 mm). des rdponses dc jauges de contraintes A 12 Le calcul, comme les essais, permettent chargements statiques...encastrement au mur * 250 capteurs ( pression, jauge , acc~l6romnbtre, fibre optique) gouverne encastrement ~-axe dispositif de s6curit6 ~ guen BLJTEE A JEUl

  5. Contrôle actif acoustique du bruit large bande dans un habitacle automobile

    OpenAIRE

    Loiseau , Paul

    2016-01-01

    Classical methods used for noise reduction in cars are based on adjusting the mechanical properties: mass, stiffness and damping. They are qualified as passive and induce significative addition of weight for reducing low frequency noises. Active noise control is seen as a possible solution to achieve low frequency noise attenuation and weight reduction.The goal of this work is to evaluate achievable performances with such solution.Acoustic enclosures are known to be resonant systems of highor...

  6. Identification de deux phytostérols biologiquement actifs de l'extrait ...

    African Journals Online (AJOL)

    des pics fragments [M-90]+, [M-129]+ et [M-357]+ propres au β-sitostérol triméthylsilyl éther dérivé du β- sitostérol. La présence de ces deux phytostérols ... trimethylsilyl ether derived from β-sitosterol. The presence of these two bioactive .... Technologies, Palo Alto, CA). L'hélium est utilisé comme gaz vecteur au débit de 1.

  7. Novel compact sorption generators for car air conditioning

    Energy Technology Data Exchange (ETDEWEB)

    Tamainot-Telto, Z.; Metcalf, S.J.; Critoph, R.E. [School of Engineering, University of Warwick, Gibet Hill Road, Coventry CV4 7AL (United Kingdom)

    2009-06-15

    A prototype compact generator using the activated carbon-ammonia pair based on the plate heat exchanger concept has been designed and built at Warwick University. The novel generator has low thermal mass and good heat transfer. The heat exchanger uses nickel-brazed shims and spacers to create adsorbent layers only 4 mm thick between pairs of liquid flow channels of very low thermal mass. The prototype sorption generator manufactured was evaluated under EU car air conditioning test conditions. The prototype sorption generator is described and its experimental performance reported. While driven with waste heat from the engine coolant water (at 90 C), a pair of the current prototype generators (loaded with about 1 kg of activated carbon) operating out of phase has produced an average cooling power 1.6 kW with about 2 kW peaks. The typical average COP obtained is 0.22. (author) [French] Un prototype du generateur compact, base sur le concept des echangeurs de chaleur a plaques et utilisant la paire charbon actif-ammoniac, a ete concu et construit a l'Universite de Warwick. Le nouveau generateur a une faible inertie thermique et un excellent transfert de chaleur. L' echangeur utilise des plaques ayant des micro-canaux et des intercalaires brases au Nickel pour creer des couches d'adsorbant de 4 mm d'epaisseur entre les paires de plaques a l'interieur desquelles circule le fluide liquide. Le prototype du generateur a sorption ainsi fabrique a ete teste suivant des conditions prescrites par la Norme Europeenne de la Climatisation Automobile. Le prototype du generateur a sorption est decrit et ses performances experimentales presentees. Une paire dudit prototype (contenant chacun 1 kg the charbon actif), operant avec dephasage et ulisant des pertes thermiques en provenance de l'eau de refroidissement de moteur (a 90 C), a produit une puissance frigorifique moyenne de 1.6 kW avec une valeur maximum de 2 kW. La valeur typique du COP moyen est de

  8. Ameliorer les performances environnementales des centrales a charbon pulverise via la co-combustion de combustible derive de dechets

    Science.gov (United States)

    Vekemans, Odile Geraldine

    Coal supplies around 28% of the world's energy needs and produces some 40% of the world's electricity. In the United States, close to 650 coal power plants currently produce electricity from coal, the majority of witch are equipped with pulverized coal boilers build in the 80's. Due to coal's intrinsic content in nitrogen and sulfur, its combustion is associated with high levels of NOx and SO2 emissions, that are responsible, among other thing, for acid rains. In order to help reduce SO2 emissions of coal power plant, this thesis focuses on the behaviour of a novel feedstock called ReEF(TM) or ReEngineered Feedstock(TM), developed by the company Accordant Energy LLCRTM, that combines non recyclable waste and alkaline sorbent. Since waste have a high calorific value and do not contain sulfur, and since alkaline sorbents (such as limestone) are able to react with SO2 and capture it in solid state, co-combustion of ReEF(TM) and coal could reduce SO2 emissions inside the furnace chamber itself. This technology easy to implement, as it requires a limited initial investment and limited additional space, could help avoid the construction of costly flue gas treatment unit downstream from the furnace. However, careless combustion of this engineered fuel could have disastrous consequences for the coal power plant owners. This thesis, then, deliver one among the first experimental study of co-combustion of coal and ReEF(TM) in conditions characteristic of pulverized coal boilers. As a first step, in order to get familiarize with the feedstock under study, the thermal degradation of a ReEF(TM) without sorbent and of its components is analyzed by thermogravimetry. With the analysis of more than 70 samples at heating rates ranging from 5°C/min to 400°C/min we are able to conclude that ReEF(TM) thermal degradation can be seen as the independent thermal degradation of its components, as long as heat transfer limitations are taken into account. Thus, no substantial chemical interactions between ReEF(TM) components take place during its devolatilization. During the second step of this study, performances of the co-firing of coal and sorbent are compared to that of co-combustion of coal and ReEF(TM) without sorbent. This is carried out in a reactor specially build for this study, capable of reproducing the contact mode between gas and particles, the concentrations, the temperature gradient and the pressure typical of pulverized coal boiler. SO2 emissions reduction around 20% are observed in presence of CaCO3 and of Ca(OH)2 compared to the coal baseline, reduction that generally increased with the increase of sorbent molar ratio compared to sulfur (also called stoic). As for the co-combustion of 20%th of ReEF(TM) and coal, a SO2 emission reduction around 20% is also measured, with no clear effect of ReEF(TM) composition (fiber to plastic ratio). On the other hand, the HCl level that is negligible during coal combustion with and without sorbent, reaches around 20ppm in presence of ReEF(TM), and increases proportionally with the ReEF(TM) plastic content. The first step of this work consists in the study of the co-combustion of coal and ReEF(TM) containing limestone (CaCO3), a mix of sodium bicarbonate (NaHCO3) and limestone, as well as a mix of trona (Na2CO3.NaHCO3.H2O) and limestone. The amount of sorbent in the ReEF(TM) as well as the feeding parameters are adjusted to reach a 20%th feeding of ReEF(TM) compared to coal, to inject sorbents at a stoic of 1, 2 and 2.5 and to obtain Na/Ca molar ratios of 0, 0.1 with trona and NaHCO3, and 0.5 with NaHCO 3 only. Globally, as in the case of sorbent alone, the increase of the total stoic of the feed leads to increased SO2 capture. For a given stoic, to combine waste and limestone in the ReEF(TM), compared to using limestone alone, allows to reach higher levels of SO2 emissions reduction. The combination of sodium-based and calcium-based sorbent even leads to record SO2 emissions reduction of more than 50% with trona, and more than 40% with NaHCO3, at gas residence time in the reactor four time smaller than typical residence time of PCB. Furthermore, the lower fuel-N content of the ReEF(TM), compared to coal, also leads to lower NOx emissions. Combustion of ReEF(TM) with trona is even associated with NOx emissions reduction of more than 50%, possibly due to sodium induced NO reduction. Finally, regarding HCl emissions, chlorine capture by the sorbents leads to HCl levels comparable to that of coal alone. Even if, from the point of view of pollutant emissions, the results are promising, co-feeding ReEF(TM) with sorbent was nonetheless associated with heavy formation of melted ash deposits in the reactor. Deposition probes are used to compare the magnitude of the deposition in function of the ReEF(TM) sorbent composition. With those probes, we are able to figure out that slag formation is quite severe in presence of NaHCO3, and all the more that the Na/Ca ratio is high, but is less severe in presence of limestone alone, and isn't at all problematic in presence of trona. Those results all seem to indicate that co-combustion of coal and 20%th ReEF(TM) containing limestone and trona at a Na/Ca ratio of 0.1 and at a total stoic of 2 is the most adequate composition for application in existing PCB. In all those experiments a single measure of the emissions at the exit of the reactor is conducted, the emissions being associated with a federate of gas and solid and a temperature profile along the reactor. In order to gain insight regarding the behaviour of the gas and the particles inside the reactor, a phenomenological model combining more than 30 reaction kinetics is developed. This model allows us, without any fitting parameter, to predict the CO2, SO2 and NOx emissions measured at the outlet of the reactor. This model is easily adapted to the different ReEF(TM) compositions and was able to take into account the various particle sizes. The model is then used to evaluate potential SO2 emissions reduction that could be obtain with ReEF(TM) co-combustion for a residence time and a temperature profile measured in an existing pulverized coal boiler. Those simulations indicate that SO2 emissions reduction up to 85% could be obtain at the exit of the furnace chamber with a 20%th coal feed substitution by ReEF(TM) containing limestone and trona. Co-combustion of ReEF(TM) in pulverized coal boiler is therefore sensible from the point of view of pulverized coal boiler environmental performances, as long as the ReEF(TM) composition is chosen wisely and is tested beforehand in conditions similar to that of PCB. Furthermore, since ReEF(TM) co-combustion allows electricity production at high efficiency from waste, it is also sensible in terms of waste energetic valorization.

  9. Influence du charbon de bois activé et de la densité de semis sur l ...

    African Journals Online (AJOL)

    activation égal à 0 jour, 15 jours et 30 jours). Le dispositif expérimental utilisé était un split-plot avec trois ... densité D40x40 permet une bonne croissance et un développement maximum du gombo. .... l'activé des microorganismes (Warnock et al.,.

  10. Coal, gas, petroleum, assets and weaknesses: up to when?; Charbon, gaz, petrole, atouts et faiblesses: jusqu'a quand?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-05-01

    The meeting on the perenniality of the coal, the gas and the petroleum, organized the 24 april 2003 at Bordeaux, took place around four topics: what about the fossil fuels reserves, how to conciliate the greenhouse effect, the air pollution and the energy consumption, the future energies as the carbon dioxide catchment and the hydrogen use, the fossil energies future in function of their use. The document presents the whole interventions and the opening allocution. (A.L.B.)

  11. Coal in China: current status and outlook - Panorama 2008; Le charbon en Chine: etat des lieux et perspectives - Panorama 2008

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    Coal is making a much-noticed comeback to the forefront of the energy scene, primarily due to the preponderant role that it plays in supplying energy to the Chinese economy. With demand very high and increasing fast, several challenges have appeared. The first is industrial: domestic production will have to work very hard to keep up with demand. The second is economic: judging by consumption forecasts, the slightest misalignment of supply and demand will have repercussions on world prices. The last, but certainly not least, is the environmental challenge, which is major in that massive investments in modern technology are required to lower the environmental impact of coal.

  12. Coal in India: current status and outlook - Panorama 2008; Le charbon en Inde: etat des lieux et perspectives - Panorama 2008

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    The world cannot do without coal. This energy source covers more than one-quarter (28.4% in 2006) of all primary energy consumption and is used to generate nearly 40% of all electricity consumed worldwide. All scenarios and forecasts agree that coal consumption will be growing substantially, driven mostly by China and India. According to the IEA reference scenario (World Energy Outlook 2007), these two countries are expected to account for 82% of the increase in global coal demand by 2030. The outlook for India gives cause for concern: despite a strong domestic coal industry, it could eventually become a major importer. If so, what will the economic, industrial and environmental consequences be?.

  13. Application of the decree 2910 for coal fired boilers; Application de l`arrete 2910 aux chaudieres a charbon

    Energy Technology Data Exchange (ETDEWEB)

    Hing, K. [CDF Energie, Charbonnages de France, 92 - Rueil-Malmaison (France)

    1997-12-31

    The impacts of the new French decree 2910 concerning the classification of all combustion equipment with regards to their energy sources, energy efficiency and pollution control, on 2 to 20 MW coal-fired boilers, are discussed, with emphasis on their pollutant emissions (SO{sub 2}, NO{sub x} and ashes). The compositions of several coals is presented and the various types of coal-fired boilers adapted to the new decree are presented: automatic boilers, dense fluidized bed boilers, vibrating and chain grids with fume tubes and water tubes

  14. Multiple supply circuits for coal and molybdenite flotation; Circuits a alimentations multiples de flottation de charbon et de molybdenite

    Energy Technology Data Exchange (ETDEWEB)

    Fuertenau, D.W. [Universite de Californie, Berkeley (United States); Williams, M.C. [Universite de Virginie, Morgantown (United States); Hu, W. [Universite de l' Utah, Salt Lake City (United States)

    2001-03-01

    The aim of this experimental study is the design of a new flotation circuit for coal and molybdenite in which the supply is shared into two fractions: the concentrate of one stage is added to the second fraction which supplies the second stage and allows to reduce the reagents consumption. Abstract only. (J.S.)

  15. The coal epic at Freyming-Merlebach; L'epopee du charbon a Freyming-Merlebach

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    This information document has been realized on the closure of the Merlebach site. It is devoted to the coal epic at Freyming-Merlebach. The historical aspects of the exploitation, the working conditions, the economic and environmental aspects of the mine and the today situation are detailed. (A.L.B.)

  16. Modelisation des effets physico-techniques pour la conception des ...

    African Journals Online (AJOL)

    automatisation dans les installations industrielles a besoin d'une régulation automatique des commandes des processus technologiques pour lesquelles certaines contraintes sont à relever compte tenu des exigences des innovations scientifiques de ...

  17. Modelisation of synchrotron radiation losses in realistic tokamak plasmas

    International Nuclear Information System (INIS)

    Albajar, F.; Johner, J.; Granata, G.

    2000-08-01

    Synchrotron radiation losses become significant in the power balance of high-temperature plasmas envisaged for next step tokamaks. Due to the complexity of the exact calculation, these losses are usually roughly estimated with expressions derived from a plasma description using simplifying assumptions on the geometry, radiation absorption, and density and temperature profiles. In the present article, the complete formulation of the transport of synchrotron radiation is performed for realistic conditions of toroidal plasma geometry with elongated cross-section, using an exact method for the calculation of the absorption coefficient, and for arbitrary shapes of density and temperature profiles. The effects of toroidicity and temperature profile on synchrotron radiation losses are analyzed in detail. In particular, when the electron temperature profile is almost flat in the plasma center, as for example in ITB confinement regimes, synchrotron losses are found to be much stronger than in the case where the profile is represented by its best generalized parabolic approximation, though both cases give approximately the same thermal energy contents. Such an effect is not included in present approximate expressions. Finally, we propose a seven-variable fit for the fast calculation of synchrotron radiation losses. This fit is derived from a large database, which has been generated using a code implementing the complete formulation and optimized for massively parallel computing. (author)

  18. Modelisation and numerical simulation for bulk crystal growth processes

    International Nuclear Information System (INIS)

    Duffar, F.; Dusserre, P.; Barat, C.; Nabot, J.P.

    1993-01-01

    The aim of this work is to study the relevance of numerical simulation for improving the process control in the field of crystal growth. This investigation focused on the growth of semiconductor and halide crystals by the Bridgman solidification technique, the principle of which is to cool a seeded feed material contained in a crucible, either by pulling the crucible or by decreasing the temperature in the furnace. Calculations are performed with the finite element method, and for comparison, experiments are carried out on Bridgman pulling machines operating either in a laboratory or in industrial plants. Calculations and experimental data have shown a good agreement and a satisfactory reliability

  19. Contribution to Synchronization and Tracking Modelisation in a CDMA Receiver

    Directory of Open Access Journals (Sweden)

    Aicha Alami Hassani

    2013-01-01

    Full Text Available We propose and analyze a noncoherent receiver with PN code tracking for direct sequence code division multiple access (DS-CDMA communication systems. We employ the delay-lock loop (DLL architectures for the tracking stage. The choice of DLL parameters is studied with special focus on DS-CDMA communication systems and orthogonality conditions. We described the modeling and simulation of the NCO using hardware description language VHDL. Details of the VHDL implementation are shown.

  20. Modelisation mathematique et numerique d'un capteur stockeur d ...

    African Journals Online (AJOL)

    LJ.o ufo. .,.i.(u-a.,...ll c;..c. ~ ..l,!1ji:i. 4.1..it.....!1 I~. ":~ .!.i:.....ill 11\\ . _j •• ~.11. • L)I :i -_,11 • --11 . • • . • 4.IY.l.I ..... ~!/ . __ 11;.,... ·~1 ..:..l.i.i.bl1 Ul:io....l ..l - __ 11. l.s- J-' .

  1. Modeling storm waves; Modeliser les houles de tempete

    Energy Technology Data Exchange (ETDEWEB)

    Benoit, M.; Marcos, F.; Teisson, Ch

    1999-07-01

    Nuclear power stations located on the coast take the water they use to cool their circuits from the sea. The water intake and discharge devices must be able to operate in all weathers, notably during extreme storms, with waves 10 m high and over. To predict the impact of the waves on the equipment, they are modeled digitally from the moment they form in the middle of the ocean right up to the moment they break on the shore. (authors)

  2. Modelisation du stock de biomasse et dynamique de sequestration ...

    African Journals Online (AJOL)

    Mots clés: Jatropha curcas, séquestration, carbone, Bénin, Afrique de l'Ouest. English Title: Biomass stock modeling and dynamics of mineral and carbon sequestration of Jatropha curcas L. under different soil types in Benin. English Abstract. In West Africa, carbon sequestration function of Jatropha curcas shrubs and their ...

  3. Modelisation des emissions de particules microniques et nanometriques en usinage

    Science.gov (United States)

    Khettabi, Riad

    La mise en forme des pieces par usinage emet des particules, de tailles microscopiques et nanometriques, qui peuvent etre dangereuses pour la sante. Le but de ce travail est d'etudier les emissions de ces particules pour fins de prevention et reduction a la source. L'approche retenue est experimentale et theorique, aux deux echelles microscopique et macroscopique. Le travail commence par des essais permettant de determiner les influences du materiau, de l'outil et des parametres d'usinage sur les emissions de particules. E nsuite un nouveau parametre caracterisant les emissions, nomme Dust unit , est developpe et un modele predictif est propose. Ce modele est base sur une nouvelle theorie hybride qui integre les approches energetiques, tribologiques et deformation plastique, et inclut la geometrie de l'outil, les proprietes du materiau, les conditions de coupe et la segmentation des copeaux. Il ete valide au tournage sur quatre materiaux: A16061-T6, AISI1018, AISI4140 et fonte grise.

  4. L’EPURATION TERTIAIRE DES EAUX USEES DE L’INDUSTRIE DE LA CELLULOSE

    Directory of Open Access Journals (Sweden)

    Constantin STANCIU

    2010-05-01

    Full Text Available Les processus de fabrication de la cellulose représentent des sources importantes de pollution tant pour les eaux, que pour l’aire et le sol. La pollution de l’eau est du, essentiellement, aux substances organiques dissous, aux substances en suspension et aux substances colorantes. Les évacuations des substances polluantes résultant de l’industrie de la cellulose se classifient en : substances solides en suspension, composés avec une biodégradabilité rapide ou lente, sels anorganiques, composés toxiques et échangeurs de valeur de pH. On a analysé les substances filtrées résultant du processus de blanchiment de la cellulose pour l’industrie papetière fabriquée du bois des arbres à feuilles caduques (hêtre et l’efficacité de l’épuration par oxydation électrochimique, par oxydation à l’ozone, l’épuration avec des résines échangeuses d’ions et l’épuration par l’ajout de charbon actif.

  5. Oxycombustion avec préchauffage des réactifs pour la valorisation des gaz à bas pouvoir calorifique

    OpenAIRE

    Ba , Abou

    2017-01-01

    The effective utilisation of low calorific value fuel, as gaseous by-products of coal/biomass or industrial residual gases, provides not only excellent opportunities for low cost power generation but also for the reduction of environmental impact of combustion. The present work aims to consider the combination of oxyfuel combustion with fuel and/or oxygen preheating in order to increase thermal efficiency by heat recovery and enhance oxyfuel flame stabilization of blast furnace gas (BFG). Thi...

  6. A 175 Hz / 188 Hz active filter for private power producers; Filtre actif 175 HZ/188 HZ pour producteurs autonomes

    Energy Technology Data Exchange (ETDEWEB)

    Michalak, P.

    1996-12-31

    The connection of certain private electric power producers on the source station bus bars may disturb the 175 Hz or 188 Hz centralized control system signals, which carry tariff messages to the Electricite de France (EDF) grid clients. A new active filter has been developed by EDF and Schlumberger, which raise the tariff signal level at the bus bars by injection of a signal with the same frequency. A prototype has been tested in real conditions

  7. Radiation effects on active pixel sensors (APS); Effets de l'irradiation sur les capteurs a pixels actifs (APS)

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, M.; David, J.P. [ONERA-CERT/, 31 - Toulouse (France)

    1999-07-01

    Active pixel sensor (APS) is a new generation of image sensors which presents several advantages relatively to charge coupled devices (CCDs) particularly for space applications (APS requires only 1 voltage to operate which reduces considerably current consumption). Irradiation was performed using {sup 60}Co gamma radiation at room temperature and at a dose rate of 150 Gy(Si)/h. 2 types of APS have been tested: photodiode-APS and photoMOS-APS. The results show that photoMOS-APS is more sensitive to radiation effects than photodiode-APS. Important parameters of image sensors like dark currents increase sharply with dose levels. Nevertheless photodiode-APS sensitivity is one hundred time lower than photoMOS-APS sensitivity.

  8. Etude de l'auto-adaptivité du filtre actif parallèle aux variations de la ...

    African Journals Online (AJOL)

    The calculated total harmonic distortion (THD) factor is less than 5% and the filter copes with load variations. Key words: shunt active filter; harmonics; PWM inverter; total harmonic distortion; p-q theory. 1. INTRODUCTION. L'utilisation intensive des convertisseurs de l'électronique de puissance devient la cause principale ...

  9. Radiation effects on active pixel sensors (APS); Effets de l'irradiation sur les capteurs a pixels actifs (APS)

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, M; David, J P [ONERA-CERT/, 31 - Toulouse (France)

    1999-07-01

    Active pixel sensor (APS) is a new generation of image sensors which presents several advantages relatively to charge coupled devices (CCDs) particularly for space applications (APS requires only 1 voltage to operate which reduces considerably current consumption). Irradiation was performed using {sup 60}Co gamma radiation at room temperature and at a dose rate of 150 Gy(Si)/h. 2 types of APS have been tested: photodiode-APS and photoMOS-APS. The results show that photoMOS-APS is more sensitive to radiation effects than photodiode-APS. Important parameters of image sensors like dark currents increase sharply with dose levels. Nevertheless photodiode-APS sensitivity is one hundred time lower than photoMOS-APS sensitivity.

  10. Natural rain - induced element leaching from coal ASH; La pluie naturelle - lixiviation d'element de la cendre de charbon

    Energy Technology Data Exchange (ETDEWEB)

    Popovic, A.; Djordjevic, D.; Polic, P. [Belgrade Univ., Dept. of Chemistry, IChTM, Chemistry Center, Belgrade (Yugoslavia)

    2000-07-01

    Six composite samples of coal ash from power plants 'Nikola Tesla' A and B, located in the vicinity of Obrenovac, near Belgrade (Yugoslavia), were subjected to extraction with 1 M acetate solution, pH 5.5, in order to imitate possible leaching of the ash by natural acidic rain. Seven trace and five major elements have been examined, and the obtained amounts were in the range from 0.003 {+-} 0.001 ppm (Cd), to 117 {+-} 27 ppm (Ca), dry ash basis. Though some of the concentrations were higher than allowed by domestic and international regulations it can be concluded that neither of the examined elements represents a serious threat for the environment (at least for the conditions applied in this experiment). Also, both magnesium and iron are carriers of copper, chromium and arsenic, while cadmium is associated with magnesium and manganese. Calcium and manganese are beside magnesium and iron, scavengers of arsenic. (authors)

  11. Nouveaux critères pour juger de l'efficacité d'un fourneau à la combustion du charbon de bois

    Directory of Open Access Journals (Sweden)

    Ndaysenga, M.

    1994-01-01

    Full Text Available New Criteria to Judge Stove Efficiency in the Charcoal Combustion. The water boil test efficiency for choosing the most economic stove in combustion is estimated on the basis of four stoves. In addition to the heating and boiling energy usually considered as selection criterion, other criteria such as the boiling time and the combustion rate have been taken to indicate efficiency. Strangely, it appeared that the stove which maintains water at its boiling point for a long time and has the lowest combustion rate doesn 't valorize fuel energy efficiently if you only keep to the heating and boiling energy. The cooking test made it possible to explain that apparent contradiction : the fuel energy fraction which doesn't enter in the calculation of the heating and boiling energy isn't really lost. A low combustion rate associated with a long boiling time proved to be the best criteria of choosing the most economic stove in fuel. Therefore, the only water boil test doesn't make it possible to identify the most economically efficient stove. Resorting to the cooking test is compelling.

  12. Application of the 2910 by-law to coal-fired heating plants; Application de l`arrete 2910 aux chaudieres a charbon

    Energy Technology Data Exchange (ETDEWEB)

    Hing, K. [CDF Energie (France)

    1997-12-31

    This paper analyzes the impact of the new French regulation about medium power thermal equipments on small coal-fired combustion installations (2 - 20 MW) in particular concerning the limit values of SO{sub 2}, NO{sub x} and dust emissions. (J.S.)

  13. Coal, the metamorphoses of an industry. The new geopolitics of the 21. century; Charbon, les metamorphoses d'une industrie. La nouvelle geopolitique du 21. siecle

    Energy Technology Data Exchange (ETDEWEB)

    Martin-Amouroux, J.M

    2008-07-01

    Coal consumption is growing up so fast and coal reserves are so abundant that coal might overtake petroleum in the future. The worldwide environment will not gain anything in this evolution except if 'clean coal' technologies make a significant jump. What is the driving force of this coal development? The pitfall encountered by nuclear energy and the rise of natural gas prices have been favorable conditions for the development of coal but they cannot hide the worldwide metamorphosis of coal industry. From China, undisputed world leader, to the USA, without omitting India, Russia and the big exporting countries (Australia, Indonesia, South Africa, Colombia), a new map is drawing up. In all these countries, coal companies are concentrating and internationalizing, open new strip mines and new commercial paths. The understanding of this metamorphosis has become one of the keys of the energy prospective and geopolitics of the 21. century. Content: 1 - entering the 21. century with the energy source of the 19. century?; 2 - consumption growth: new trends; 3 - the USA: the Saudi Arabia of coal; 4 - the unexpected rebirth of coal in Russia; 5 - China, world leader of coal industry; 6 - India and south-east Asia are entering the race; 7 - the rise of exporting industries; 8 - international markets and competitive dynamics of industries; 9 - advantage and drawbacks of coal during the coming decades; 10 - will clean coal technologies be ready on time?; 11 - technical appendix. (J.S.)

  14. Réalisation d'éco-ciments par la valorisation de cendres volantes de charbon non conventionnelles issues de centrales thermiques Spreader Stoker

    OpenAIRE

    Sow , Moustapha

    2016-01-01

    The main objective of this project was to evaluate the potential of coal fly ash from Spreader Stoker thermal power plants (Spreader Stoker Coal Fly Ash) in the manufacture of eco-cements in Reunion Island. We first performed a physico-chemical characterization SSCFA and verified its reactivity. Two valorisation paths were chosen, one of which did not present any added value but which permit to value a large quantity of SSCFA by stabilization in cement-based matrices, the other which offers a...

  15. The current status of coal liquefaction technologies - Panorama 2008; La liquefaction du charbon: ou en est-on aujourd'hui? - Panorama 2008

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    In 2008, a first coal liquefaction unit to produce motor fuel (20,000 BPSD) will come on-stream in Shenhua, China (in the Ercos region of Inner Mongolia). Other, more ambitious projects have been announced in China for between now and 2020. Since oil production is expected to peak in the medium term, this technology may develop regionally in the next 20 years to cover ever-increasing demand for motor fuel.

  16. Conceptual Modeling (CM) for Military Modeling and Simulation (M&S) (Modelisation conceptuelle (MC) pour la modelisation et la simulation (M&S) militaires)

    Science.gov (United States)

    2012-07-01

    practitioners to deal with those implications in straight- forward pragmatic ways. The first consideration is the fact of ‘ontological relativism ’ whereby...practitioner in favor of allowing liberal elective of style, an convention commensurate with the challenge of the effort and the cultural , technical...ontological relativism ) mitigation (17) Specification of Conceptual Model Artefact (14) 1,1,1,1,1,1,1,1,2, 10 Specification requirements Expository

  17. Experimental and numerical study of the active control of jets inside combustion chambers; Etude experimentale et numerique du controle actif de jets dans des chambres de combustion

    Energy Technology Data Exchange (ETDEWEB)

    Faivre, V

    2003-12-15

    Combustion instabilities occur when the flame heat release couples with the acoustic waves propagating in the combustion chamber. This phenomenon can lead to strong vibrations and noise but also, sometimes, to the complete combustion device failure. That is the reason why so many studies focus on the control of those instabilities. The method chosen in this study consists in an active control device (or set of actuators) having a strong effect on the mixing of the burner exhaust flow with the ambient fluid. The model configuration studied consists in a non reactive jet of air controlled by four small tangential secondary jets. Experiments have been carried out to optimize the control device geometry. The configuration identified as the most efficient, in terms of mixing enhancement, has been simulated through Large Eddy Simulations (LES). The objective of the numerical part of the present work is double. First, the numerical simulations provide a better understanding of the phenomena occurring when the control is on. Then, it is shown that LES can be considered as a tool to predict the effects of a control device on a flow. (author)

  18. Contribution of the active control to the measurement of fluid-elastic coupling strengths; Apport du controle actif pour la mesure des forces de couplage fluide-elastique

    Energy Technology Data Exchange (ETDEWEB)

    Legendre, S

    1999-06-30

    A precise dimensioning of the tubes inside a steam generator requires a better knowledge of the fluid-elastic coupling phenomena. The direct method for the determination of fluid-elastic coupling coefficients allows to explore only a reduced range of flow velocities and is unsuitable for the low velocities and for velocities close to the critical instability velocity. The active damping control method has been validated both with air and water and offers the possibility to extend the range of flow velocities using an artificial supply of damping: 50% of increase in single-phase flow conditions with measurements performed beyond the critical instability velocity, a doubling of the explored range of velocities in two-phase flow conditions. For a 25% two-phase flow, a stabilization of the damping of the coupled fluid-structure system is observed beyond the critical instability velocity. Finally, the calculation of fluid-elastic dimensionless coefficients has permitted to show the influence of the reduced velocity on the fluid-elastic coupling in two-phase flow conditions. (J.S.)

  19. Accuracy of ECG indices for diagnosis of left ventricular hypertrophy in people >65 years: results from the ActiFE study.

    Science.gov (United States)

    Laszlo, Roman; Kunz, Katia; Dallmeier, Dhayana; Klenk, Jochen; Denkinger, Michael; Koenig, Wolfgang; Rothenbacher, Dietrich; Steinacker, Juergen Michael

    2017-10-01

    The detection of left ventricular hypertrophy (LVH) is still a common objective of electrocardiography (ECG) in clinical practice. The aim of our study was to evaluate the accuracy of LVH ECG indices in people older than 65 recruited from a population-based cohort (ActiFE-Ulm study). In 432 subjects (mean age 76.2 ± 5.5 years, 51% male), left ventricular mass was echocardiographically determined (Devereux formula) and indexed (LVMI) to body surface area. Several LVH ECG indices (Lewis voltage, Gubner-Ungerleider voltage, Sokolow-Lyon voltage/product, Cornell voltage/product) were calculated with the help of resting ECG data and compared with the echocardiographic assessment. Despite echocardiographic signs of LVH [LVMI > 115 (♂) or >95 g/m 2 (♀)] in 47.5% of all subjects, diagnostic performance of all ECG indices was generally low. Magnitude of all LVH-indices was mainly predicted by frontal QRS axis in multivariate linear regression analysis. In comparison with the literature data from younger subjects, average frontal QRS axis turned counterclockwise. Most probably, age-related counterclockwise turn of frontal QRS axis is mainly explanatory for the decreased magnitude of LVH ECG indices and consecutive worse diagnostic performance of these indices in the elderly. ECG indices for detection of LVH have insufficient predictive values in geriatric subjects and should therefore not be used clinically for this purpose. Nevertheless, due to its established relevancy in cardiac risk stratification in this age group, usage of some established ECG indices might keep its significance even in the age of modern cardiac imaging.

  20. The investment funds in carbon actives: state of the art; Les fonds d'investissement dans les actifs carbone: etat des lieux

    Energy Technology Data Exchange (ETDEWEB)

    Dominicis, A. de

    2005-01-15

    Since the beginning in 1999 of the first funds by the World Bank, the purchase mechanisms of carbon actives, developed and reached today more than 1,5 milliards of euros. The landscape is relatively concentrated, in spite of the numerous initiatives. The author presents the situation since 1999, the importance of the european governmental investors, the purchase mechanisms management and an inventory of the carbon actives purchases. (A.L.B.)

  1. Contribution to the dosimetry of tritium in the presence of inactive or active gases; Contribution a la dosimetrie du tritium en presence de gaz inactifs ou actifs

    Energy Technology Data Exchange (ETDEWEB)

    Soudain, G [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-07-01

    Tritium is a dangerous gas for man and the maximum admissible doses in the atmosphere are sufficiently low for the dosage to be fairly difficult. We have developed an apparatus for measuring selectively the contamination of air by this gas when it is alone or when it is associated with other gaseous contaminants. The differential apparatus using two ionization chambers makes it possible to eliminate a parasitic {gamma} radiation field. In a few particular cases, the presence of the radio-active gas has been studied. From the practical point of view, the use of these chambers made of stainless steel makes for easier use since the problems connected with wall adsorption have been satisfactorily resolved. The method can be applied without restriction and very easily to the dosage of traces tritium in air or in the form of tritiated water or tritiated steam in the atmosphere. (author) [French] Le tritium est un gaz dangereux pour l'homme et les concentrations maximales admissibles dans l'atmosphere sont suffisamment basses pour que le dosage soit delicat. Nous avons etudie et realise un appareil qui permet de mesurer selectivement la contamination de l'air par ce gaz lorsqu'il est seul ou lorsqu'il est associe a d'autres agents gazeux contaminants. Le montage differentiel a deux chambres d'ionisation permet d'eliminer un champ de rayonnement {beta} parasite. Dans certains cas particuliers, la presence du gaz radioactif a ete etudiee. Sur le plan pratique, l'utilisation des chambres en acier inoxydable facilite les applications car les problemes d'adsorption aux parois ont ete bien resolus. La methode peut s'appliquer sans restriction et tres pratiquement au dosage des traces de tritium dans l'air ou encore sous forme d'eau tritiee ou de vapeur d'eau tritiee dans l'atmosphere. (auteur)

  2. Personal Hearing Protection including Active Noise Reduction (Les dispositifs de protection de l'ouie, y compris l'attenuation du bruit actif) (CD-ROM)

    National Research Council Canada - National Science Library

    Steeneken, H. J; Dancer, A; McKinley, R; Buck, K; James, S

    2005-01-01

    .... SYSTEMS DETAIL NOTE: Adobe Acrobat Reader is included on disc. ABSTRACT: Personal hearing protection and speech communication facilities are essential for optimal performance in military operations...

  3. Steam-explosion mitigation with polymer and surfactant additives; Mitigation de l`explosion-vapeur par ajout de polymeres et d`agents tensio-actifs

    Energy Technology Data Exchange (ETDEWEB)

    Pineau, D.; Ranval, W.

    1996-02-01

    Vapor explosion (or MFCI for Molten Fuel-Coolant Interaction) is a phenomenon in which a hot liquid rapidly transfers its internal energy into a surrounding colder and more volatile liquid (the coolant) which vaporization is violent. One of the simplest coolant is water. However it was noticed that some particular additives in water could have a mitigative effect on this phenomenon. This paper deals with the description of polymeric and/or surfactant solutions and their ability to suppress vapor explosion. (authors). 24 refs., 5 figs.

  4. Pollution active control: a strategy for a clean and efficient combustion; Le controle actif des polluants: une strategie pour une combustion propre et efficace

    Energy Technology Data Exchange (ETDEWEB)

    Lacas, F. [CNRS Ecole Centrale de Paris, 75 (France). Laboratoire E.M2.C

    1996-12-31

    The active control NOx reduction concept has been applied on two burners (20 kW and 840 kW), using a rotary valve enabling an excitation in the 100 to 1000 Hz band, that can be mounted on existing appliances such as domestic or industrial boilers. NOx level reduction may reach 15 pc for the 20 kW burner, 25 pc for the 840 kW burner with domestic fuel oil and 35 pc for the 840 kW burner using pyridine doped domestic fuel oil. Mechanisms are detailed through flow visualization, and consist mainly in an annular vortex inducing a fuel/air pre-mixing favourable to a large decrease in NOx generation level and establishing a staged process such as in re-burning processes. The pulsed combustion process may be also combined to other pollution control systems

  5. Future Modelling and Simulation Challenges (Defis futurs pour la modelisation et la simulation)

    Science.gov (United States)

    2002-11-01

    work. Typically, simulation is used to generate sensible dynamics of, and information about, how a combat or crisis evolves over time. Drivers for...Escuela de Informática del Ejército C/ Prim, 4 28071 Madrid, Spain Prof. Dr. Fernando de Arriaga Universidad Politécnica de Madrid Ciudad Universitaria s

  6. Physical modelling of interactions between interfaces and turbulence; Modelisation physique des interactions entre interfaces et turbulence

    Energy Technology Data Exchange (ETDEWEB)

    Toutant, A

    2006-12-15

    The complex interactions between interfaces and turbulence strongly impact the flow properties. Unfortunately, Direct Numerical Simulations (DNS) have to entail a number of degrees of freedom proportional to the third power of the Reynolds number to correctly describe the flow behaviour. This extremely hard constraint makes it impossible to use DNS for industrial applications. Our strategy consists in using and improving DNS method in order to develop the Interfaces and Sub-grid Scales concept. ISS is a two-phase equivalent to the single-phase Large Eddy Simulation (LES) concept. The challenge of ISS is to integrate the two-way coupling phenomenon into sub-grid models. Applying a space filter, we have exhibited correlations or sub-grid terms that require closures. We have shown that, in two-phase flows, the presence of a discontinuity leads to specific sub-grid terms. Comparing the maximum of the norm of the sub-grid terms with the maximum of the norm of the advection tensor, we have found that sub-grid terms related to interfacial forces and viscous effect are negligible. Consequently, in the momentum balance, only the sub-grid terms related to inertia have to be closed. Thanks to a priori tests performed on several DNS data, we demonstrate that the scale similarity hypothesis, reinterpreted near discontinuity, provides sub-grid models that take into account the two-way coupling phenomenon. These models correspond to the first step of our work. Indeed, in this step, interfaces are smooth and, interactions between interfaces and turbulence occur in a transition zone where each physical variable varies sharply but continuously. The next challenge has been to determine the jump conditions across the sharp equivalent interface corresponding to the sub-grid models of the transition zone. We have used the matched asymptotic expansion method to obtain the jump conditions. The first tests on the velocity of the sharp equivalent interface are very promising (author)

  7. Thermal modeling. Application to lithium batteries; Modelisation thermique. Application aux accumulateurs lithium

    Energy Technology Data Exchange (ETDEWEB)

    Alexandre, A. [Ecole Nationale Superieure de Mecanique et d`Aerotechnique (ENSMA), 86 - Poitiers (France); Flament, P. [SAFT, 33 - Bordeaux (France); Marolleau, T. [SAFT, Advanced and Industrial Battery Group, 86 - Poitiers (France); Guiot, T.; Lefriec, C. [TSR Futuropolis, 86 - Chasseneuil du Poitou (France)

    1996-12-31

    The thermal modeling of electrochemical batteries is today an integral part of the design and validation operations of new products. The Li-ion pair allows to increase the power density of batteries but leads to higher heat fluxes during charging-output cycles. Thus, the thermal control has become more crucial and requires the use of modeling. SAFT and TSR companies are involved in this approach and use the ESACAP software. This paper presents this software which uses a nodal method for the modeling of the coupled thermal and electrical processes that take place inside elementary cells and batteries. (J.S.)

  8. MODELISATION DE LA CINETIQUE CHIMIQUE DANS LA REDUCTION DES OXYDES D4AZOTE PAR DECHARGE COURONNE.

    OpenAIRE

    MEDJAHDI, Sarah ines

    2015-01-01

    CE TRAVAIL DE recherche rentre dans le cadre général de modélisation de la réduction des oxydes d'azote . l'utilisation des réacteurs a plasma froid non-thermique généré par des décharges couronnes est actuellement l'une des techniques les puis promettre .ses pour la destruction des oxydes d'azote .en effet , le traitement des gaz pollués par les décharges couronnes est notamment rendu possible par la multiplication des décharges Électriques .

  9. Environment modeling and mathematics; Modelisation de l'environnement et mathematiques

    Energy Technology Data Exchange (ETDEWEB)

    Armand, P.; Renard, F. [CEA Bruyeres-le-Chatel, 91 (France)

    2011-01-15

    Environmental modeling is a permanently expanding field of studies and research, relying on numerous mathematical techniques. Some of them are illustrated here, in the framework of the pollutant transport in the atmosphere and hydro-geosphere, two extensively developed subjects at CEA, both for compliance with regulatory requirements, and for impact assessment of gaseous or liquid accidental releases. Our paper deals with meteorological forecast, hydrogeology, fluid mechanics, multiple space and time scales, data assimilation, optimization, geo-statistics and uncertainties. (authors)

  10. Modelisation et simulation de pyrolyse de pneus usages dans des reacteurs de laboratoire et industriel

    Science.gov (United States)

    Lanteigne, Jean-Remi

    The present thesis covers an applied study on tire pyrolysis. The main objective is to develop tools to allow predicting the production and the quality of oil from tire pyrolysis. The first research objective consisted in modelling the kinetics of tires pyrolysis in a reactor, namely an industrial rotary drum operating in batch mode. A literature review performed later demonstrated that almost all kinetics models developed to represent tire pyrolysis could not represent the actual industrial process with enough accuracy. Among the families of kinetics models for pyrolysis, three have been identified: models with one single global reaction, models with multiple combined parallel reactions, and models with multiple parallel and series reactions. It was observed that these models show limitations. In the models with one single global reaction and with multiple parallels reactions, the production of each individual pyrolytic product cannot be predicted, but only for combined volatiles. Morevoer, the mass term in the kinetics refers to the final char weight (Winfinity) that varies with pyrolysis conditions, which yields less robust models. Also, despite the fact that models with multiple parallels and series reactions can predict the rate of production for each pyrolysis product, the selectivities are determined for operating temperatures instead of real mass temperatures, giving models for which parameters tuning is not adequate when used at the industrial scale. A new kinetics model has been developed, allowing predicting the rate of production of noncondensable gas, oil, and char from tire pyrolysis. The novelty of this model is the consideration of intrinsic selectivities for each product as a function of temperature. This hypothesis has been assumed valid considering that in the industrial pyrolysis process, pyrolysis kinetics is limiting. The developed model considers individual kinetics for each of the three pyrolytic products proportional to the global decomposition kinetics of pyrolysables. The simulation with data obtained in industrial operation showed the robustness of the model to predict with accuracy in transient regime, tires pyrolysis, with the help of model parameters obtained at laboratory scale, namely in regards of the trigger of production, the residence time of tires (dynamic production) and the amount of oil produced (cumulative yield). It is a novel way to model pyrolysis that could be extrapolated to new waste materials. The second objective of this doctoral research was to determine the evolution of specific tires specific heat during pyrolysis and the enthalpy of pyrolysis. The origin of this objective comes from a primary contradiction. With few exceptions, it is acknowledged that organic materials pyrolysis is globally an endothermic phenomenon. At the opposite, all experiments led with laboratory apparatuses such as DSC (Differential Scanning Calorimetry) showed exothermic peaks during dynamic experiments (constant heating rate). It has been confirmed by results obtained at the industrial scale, where no sign of exothermicity has been observed. The Hess Law has also confirmed these results, that globally, pyrolysis is indeed a completely endothermic process. An accurate energy balance is required to predict mass temperature during pyrolysis, this parameter being unbindable from kinetics. An advanced investigation of char first allowed demonstrating that specific heat of solids during pyrolysis decreases with increasing temperature until the weight loss peak is reached, around 400°C, and then starts increasing again. This observation, combined with the fact that the sample loses weight during pyrolysis is considered as the major cause of the apparition of an exothermic peak in laboratory scale experiments. That is, the control system of these apparatuses generates a bias and an unavoidable overheat of the samples producing this exothermic behavior. It would thus be an artifact. On the base of new data on the evolution of global specific heat during pyrolysis, a model of the energy balance has been developed at the industrial scale to determine the enthalpy of pyrolysis. The simulation has shown that a major part of the heat transferred to the pyrolized mass would make its temperature increase. Next, an enthalpy of pyrolysis dependent of weight loss was obtained. Finally, two other terms of enthalpy have been found, namely an enthalpy for the breakage of sulfur bridges and an enthalpy for the stabilization of char when conversion approaches completion. This research will have allowed establishing a novel general methodology to determine the enthalpy of pyrolysis. More particularly, new clarifications hasve been obtained in regards to the evolution of specific heat of solids during pyrolysis and new enthalpies of pyrolysis, all endothermic, could be obtained, in agreement with the theoretical expectations. The third research objective concerned the behavior of sulfur during tires pyrolysis. With as a premise that sulfur is an intrinsic contaminant of many types of waste, it is critical to clarify its fate during pyrolysis, in the present case for waste tires. It has been observed in the literature that some quantitative analyses had been presented, but generally, the mechanisms for the distribution of sulfur within the pyrolytic products remain unclear. Thus, it was then not possible to predict the transfer of sulfur to each of the tire pyrolysis products. The results taken form literature have been complemented with a series of TGA experiments followed by complete elemental analyses of the residual solids. Mass balances have been performed in order to characterize the distribution of elements within the three products (noncondensable gas, oil, and char). A novel parameter has been created during this research: the sulfur loss selectivity. This intrinsic selectivity is a prediction of the distribution of sulfur within the pyrolysis products as a function of temperature. Three phenomena has been identified that could affect the sulfur loss selectivity. First, the natural devolatilization of sulfur due to pyrolysis. Next, the sulfur devolatilization due to the desulfurization of the solid matrix by hydrogen and finally, the clustering of sulfur in the solid state due to metal sulfidation (zinc and iron). The results have shown that this selectivity reach a limit value of 1 when pyrolysis is limited by the kinetics and in the absence of metal. When the mass transfer is limiting at low temperature (<500°C) the selectivity will be greater than 1. At a temperature over 350°C with the presence of metals, the selectivity will be lower than 1. It is a useful tool for industrial pyrolysis processes, being a novel indicator for the distribution of contaminants during the pyrolysis of waste. A better comprehension of these mechanisms allows elaborating a better strategy when designing these industrial processes. For example, in light of this research, it could be preferable to pre-treat the tires at lower temperature to eliminate a significant part of sulfur before pyrolyzing them at high temperature. The resulting pyrolytic products would then necessitate a lighter purification post-treatment, being more efficient and more economical.

  11. Numerical modelisation of RF waves in the ion cyclotron range of frequency for Tokamak plasmas

    International Nuclear Information System (INIS)

    Edery, D.; Picq, H.; Samain, A.; Gambier, D.J.

    1987-12-01

    The purpose of this paper is to present the numerical code ALCYON developed to compute the RF field structure in the ion cyclotron range of frequencies. The code handles fundamental and second harmonic heating while the mode conversion onto modes of decreasing wavelength is simulated by a selective power absorption on slow waves when their wavelength reaches the mesh size

  12. The hydro-mechanical modeling of the fractured media; Modelisation hydromecanique des milieux fractures

    Energy Technology Data Exchange (ETDEWEB)

    Kadiri, I

    2002-10-15

    The hydro-mechanical modeling of the fractured media is quite complex. Simplifications are necessary for the modeling of such media, but, not always justified, Only permeable fractures are often considered. The rest of the network is approximated by an equivalent continuous medium. Even if we suppose that this approach is validated, the hydraulic and mechanical properties of the fractures and of the continuous medium are seldom known. Calibrations are necessary for the determination of these properties. Until now, one does not know very well the nature of measurements which must be carried out in order to carry on a modeling in discontinuous medium, nor elements of enough robust validation for this kind of modeling. For a better understanding of the hydro-mechanical phenomena in fractured media, two different sites have been selected for the work. The first is the site of Grimsel in Switzerland in which an underground laboratory is located at approximately 400 m of depth. The FEBEX experiment aims at the in-situ study of the consecutive phenomena due to the installation of a heat source representative of radioactive waste in the last 17 meters of the FEBEX tunnel in the laboratory of Grimsel. Only, the modeling of the hydro-mechanical of the excavation was model. The modeling of the Febex enabled us to establish a methodology of calibration of the hydraulic properties in the discontinuous media. However, this kind of study on such complex sites does not make possible to answer all the questions which arise on the hydro-mechanical behavior of the fractured media. We thus carried out modeling on an other site, smaller than the fist one and more accessible. The experimental site of Coaraze, in the Maritime Alps, is mainly constituted of limestone and fractures. Then the variation of water pressure along fractures is governed by the opening/closure sequence of a water gate. Normal displacement as well as the pore pressure along these fractures are recorded, and then analyzed with the aim to catch the nature of hydro-mechanical coupling. The modeling of Coaraze allowed to reproduce in situ measurements and to give an opinion on the problems of the hydro-mechanical coupling in the fractured mediums. (author)

  13. MODELISATION, SIMULATION ET OPTIMISATION D’UN SYSTEME HYBRIDE EOLIEN-PHOTOVOLTAIQUE

    OpenAIRE

    BELGHITRI, HOUDA

    2010-01-01

    L’exploitation des ressources renouvelables connaît un grand essor dans les pays industrialisés et même dans quelques pays sous-développés. L’Algérie à fournit un grand effort pour l’électrification rurale et saharienne .En effet, le taux d’électrification national pour l’année 2001 est de 96%. Malgré le taux élevé, il existe toujours des foyers épars qui leurs électrifications par l’extension du réseau conventionnel est très coûteuse. Le système hybride de production d’électri...

  14. Modelisation et simulation d'une liaison HVDC de type VSC-MMC

    Science.gov (United States)

    Saad, Hani Aziz

    High-voltage direct current transmission systems (HVDC) are rapidly expanding in the world. Two main factors are responsible for this expansion. The first is related to the difficulty of building new overhead lines to ensure the development of high-voltage AC grids, which makes the usage of underground cables more common. However, the use of such cables is limited in length to a few tens of km because of the capacitive current generated by the cable itself. Beyond this length limit, the solution is usually to transmit in DC. The second factor is related to the development of offshore wind power plants that require connecting powers of several hundred of MW to the mainland grid by cables whose lengths can reach several hundreds of km and consequently require HVDC transmission system. Several HVDC projects are currently planned and developed by the French transmission system operator RTE. One of such projects is the INELFE interconnection project, with a capacity of 2,000 MW, between France and Spain. This thesis has been funded by RTE, in order to model and simulate in off-line and real time modes, modern HVDC interconnections. The delivered simulation means are used to examine targeted HVDC system performances and risks of abnormal interactions with surrounding power systems. The particularity of the INELFE HVDC system is the usage of a dedicated control system that will largely determine the dynamic behaviour of the system for both large disturbances (faults on the network) and small perturbations (power step changes). Various VSC topologies, including the conventional two-level, multi-level diode-clamped and floating capacitor multi-level converters, have been proposed and reported in the literature. However, due to the complexity of controls and practical limitations, the VSC-HVDC system installations have been limited to the two-level and three-level diode-clamped converters. Recently, the development of modular technology called MMC (Modular Multilevel Converter [Siemens] - [Alstom]) or CTL (Cascaded Two Level topology [ABB]) has allowed to overcome existing limitations. This topology consists of several sub-modules connected in series. Each sub-module contains two IGBTs with antiparallel diodes and a capacitor that act as energy storage. The control of these IGBTs allows connecting and disconnecting the capacitor on the network. The grouping of several sub-modules in series forms an arm. From the AC side, each phase consists of two arms. Reactors are included in series with each arm in order to limit the fault current. The large number of IGBTs in MMCs creates complicated computation problems in electromagnetic transient type (EMT-type) simulation tools. Detailed MMC models include the representation of thousands of IGBT (Insulated Gate Bipolar Transistor) switches and must use small numerical integration time steps to accurately represent fast and multiple simultaneous switching events. This becomes particularly more complex for performing real-time simulations. The computational burden introduced by such models highlights the need to develop more efficient models. A current trend is based on simplified models capable of delivering sufficient accuracy for EMT-type simulations, however the validity range of such models must be carefully evaluated. The first objective of this thesis is to model HVDC-MMC transmission systems in EMT-type programs for off-line and real-time simulations. To fulfill this objective, different modelling approaches are presented, then the control system used for HVDC-MMC links is developed and finally the implementations of MMC models using both CPU (Central Processing Unit) and FPGA (Field-Programmable Gate Array) technologies for real-time simulations, are presented. The contributions are useful for researchers and engineers using transient simulation tools for modelling and analysis of power systems including HVDC-MMC. The HVDC links currently planned or constructed in France, are embedded in highly meshed networks and may have significant impact on their operations and performance. Therefore, the second objective of this thesis is to perform modal analysis and parametric studies to assess the risks of abnormal interactions between several HVDC links inserted in meshed AC networks.

  15. Modelling and control of an electric vehicle; Modelisation et controle d`un vehicule electrique

    Energy Technology Data Exchange (ETDEWEB)

    Kwartnik, J

    1995-11-28

    The work described in this report provides to engineers or researchers a tool for electric vehicle simulation. The different components included in the system are described with in particular the choppers, the pedal accelerator and the vehicle dynamic represented by the different constraints applied to the vehicle (efforts of drag, of lift, of rolling and slope resistance). This study has been realized by considering nonlinear phenomenons such as the armature magnetic reaction or the resistance change due to temperature increasing. The complexity of the system leads to use several of control. The theory of linear systems made possible the synthesis of PID controllers after few hypothesis. An on line adaptation technique completed this synthesis by considering nonlinear effects. For the cruise control we have used a control based on fuzzy set theory. We showed through two examples, the cruise control and the motor control using a strategy which minimize the Joule effect looses, the interest and the possibilities of the model evolution. (author) 21 refs.

  16. Studies and modeling of cold neutron sources; Etude et modelisation des sources froides de neutron

    Energy Technology Data Exchange (ETDEWEB)

    Campioni, G

    2004-11-15

    With the purpose of updating knowledge in the fields of cold neutron sources, the work of this thesis has been run according to the 3 following axes. First, the gathering of specific information forming the materials of this work. This set of knowledge covers the following fields: cold neutron, cross-sections for the different cold moderators, flux slowing down, different measurements of the cold flux and finally, issues in the thermal analysis of the problem. Secondly, the study and development of suitable computation tools. After an analysis of the problem, several tools have been planed, implemented and tested in the 3-dimensional radiation transport code Tripoli-4. In particular, a module of uncoupling, integrated in the official version of Tripoli-4, can perform Monte-Carlo parametric studies with a spare factor of Cpu time fetching 50 times. A module of coupling, simulating neutron guides, has also been developed and implemented in the Monte-Carlo code McStas. Thirdly, achieving a complete study for the validation of the installed calculation chain. These studies focus on 3 cold sources currently functioning: SP1 from Orphee reactor and 2 other sources (SFH and SFV) from the HFR at the Laue Langevin Institute. These studies give examples of problems and methods for the design of future cold sources.

  17. Human Modelling for Military Application (Applications militaires de la modelisation humaine)

    Science.gov (United States)

    2010-10-01

    techniques (rooted in the mathematics-centered analytic methods arising from World War I analyses by Lanchester 2 ). Recent requirements for research and...34Dry Shooting for Airplane Gunners - Popular Science Monthly". January 1919. p. 13-14. 2 Lanchester F.W., Mathematics in Warfare in The World of

  18. Human Behaviour Representation in Constructive Modelling (Representation du comportement humain dans des modelisations creatives)

    Science.gov (United States)

    2009-09-01

    Resources and Performance. Action Group 19. Representation of Human Behavior. Lanchester , F. W. (1916). Aircraft in warfare . The dawn of the fourth...Operations and non-kinetic warfare . The second keynote presentation, by Mr. Mike Greenley, CAE Inc. provided an industry perspective, noting the need for...concentrated on tactical-conventional warfare and the emergence of world-wide “irregular warfare ” and “small wars” drive the present and future need

  19. Discrete modelling of rock-fill: Application to dams; Modelisation discrete des enrochements: Application aux barrages

    Energy Technology Data Exchange (ETDEWEB)

    Deluzarche, R

    2004-12-15

    In this study, a discrete numerical model for rock-fill is built up and validated. This model is based upon the definition of bidimensional clusters that can break in different ways. The resistance of the inner bonds of the clusters are calibrated by reproducing the size-dependant resistance of rock blocks submitted to crushing tests. Numerical simulations of laboratory tests are performed on samples made of the different clusters. Tests on crushable clusters emphasize the utmost importance of particle crushing on the behaviour. A dam is modelled. The role of the placed-rock face on the stabilisation is underlined. The deformation of the dam during reservoir filling, as well as its good seismic behaviour is well reproduced by the model. The model makes it possible to show the influence of particle breakage on the settlements. (author)

  20. System reliability analysis and introduction to modelisation by means of Markov chains

    International Nuclear Information System (INIS)

    Doyon, L.R.

    1977-01-01

    A new method to solve simultaneously all models of availability, reliability and maintenaibility for a complex system is described. This analysis is obtained more exactly by using time-intervals between failures and times to repare with probability laws and maintenance policies most adapted to the problem. The expression of this computation, using MARKOV chains corresponds perfectly to computer-language and results very short machine operation times. The procedure necessary for the use of APAFS program operationnal at the CISI (Compagnie Internationale de Services en Informatique) is also described. Thus, a very important tool is now available to designers without any requirement in programming knowledge [fr

  1. European oil product supply modelling; Modelisation de l`offre de produits petroliers en Europe

    Energy Technology Data Exchange (ETDEWEB)

    Saint-Antonin, V

    1998-12-11

    Over the last few years, trends in European oil product consumption (in terms of level as structure and quality) has important implications of the refining industry. In this context, the purpose of this thesis consists in building a mathematical programming model applied to the European refineries in order to determine oil product supply prices, European refining industry investments and oil product exchanges of the European Union. The first part presents the reason for our choice for a long-term aggregate multi-refineries linear programming model, based on European refineries characteristics and the objectives of our model. Its dual properties are studied in detail and we focus particularly on the European exchange modelling. In the second part, an analysis of the European refining trends leads us to identify parameters and variables of the model that are essential to the aggregate representation of the European oil product supply. The third part is devoted to the use of this model, regarding two scenarios of increasingly stringent specifications for gasoline and diesel oil. Our interest for these products is due to their important share of the European oil product consumption and the not insignificant responsibility of the transport sector for atmospheric pollution. Finally, in order to have the use of an overall picture of the European refining industry, we build a regression model summarizing, though a few equations, the main relations between the major endogenous and exogenous variables o the LP model. Based on pseudo-data, this kind of model provides a simple and robust representation of the oil product supply. But a more specialized analysis of the refining industry operations, turning on a technical assessment of processing units, is reliant on the use of an optimization model such as the model we have built. (author) 102 refs.

  2. Modelisation et simulation d'un PON (Passive Optical Network) base ...

    African Journals Online (AJOL)

    English Title: Modeling and simulation of a PON (Passive Optical Network) Based on hybrid technology WDM/TDM. English Abstract. This development is part of dynamism of design for a model combining WDM and TDM multiplexing in the optical network of PON (Passive Optical Network) type, in order to satisfy the high bit ...

  3. Development and modelisation of a hydro-power conversion system based on vortex induced vibration

    Science.gov (United States)

    Lefebure, David; Dellinger, Nicolas; François, Pierre; Mosé, Robert

    2016-11-01

    The Vortex Induced Vibration (VIV) phenomenon leads to mechanical issues concerning bluff bodies immerged in fluid flows and have therefore been studied by numerous authors. Moreover, an increasing demand for energy implies the development of alternative, complementary and renewable energy solutions. The main idea of EauVIV project consists in the use of VIV rather than its deletion. When rounded objects are immerged in a fluid flow, vortices are formed and shed on their downstream side, creating a pressure imbalance resulting in an oscillatory lift. A convertor modulus consists of an elastically mounted, rigid cylinder on end-springs, undergoing flow- induced motion when exposed to transverse fluid-flow. These vortices induce cyclic lift forces in opposite directions on the circular bar and cause the cylinder to vibrate up and down. An experimental prototype was developed and tested in a free-surface water channel and is already able to recover energy from free-stream velocity between 0.5 and 1 m.s -1. However, the large number of parameters (stiffness, damping coefficient, velocity of fluid flow, etc.) associated with its performances requires optimization and we choose to develop a complete tridimensionnal numerical model solution. A 3D numerical model has been developed in order to represent the real system behavior and improve it through, for example, the addition of parallel cylinders. The numerical model build up was carried out in three phases. The first phase consists in establishing a 2D model to choose the turbulence model and quantify the dependence of the oscillations amplitudes on the mesh size. The second corresponds to a 3D simulation with cylinder at rest in first time and with vertical oscillation in a second time. The third and final phase consists in a comparison between the experimental system dynamic behavior and its numerical model.

  4. Modelisation de champs de puits geothermiques en serie pour un stockage thermique saisonnier

    Science.gov (United States)

    Lecomte, Corentin

    This thesis presents a study of the methods for modeling boreholes in series used for seasonal borehole thermal energy storage, along with a description and verification of an analytical model suited for large bore fields (≥ 100 boreholes). A detailed study of existing models for seasonal borehole thermal energy storage using in-series bore fields is performed beforehand, to identify modeling needs. A model entitled NBiS (Network of Borehole in Series) is presented in this thesis. As a first step, the model is studied for a simple configuration involving two boreholes each equipped with a single U-tube, linked in a single network (NBiS(2) model). Then, the model is adapted to a case where the number of boreholes nB is set by the user. Finally, the last version of the model (NBiS(4) model) is suited for nB 4-tubes boreholes piped to form two independent circuits. It also allows the user a mixed configuration with parallel branches of in-series boreholes. Each of the three versions of the NBiS model has been implemented as a Type in the TRNSYS environment. These models have been successfully verified using inter-model comparisons. Lastly, an example of annual simulations for a solar community is presented, where the seasonal borehole thermal energy storage is modeled using a TRNSYS Type of the NBiS suite of models.

  5. Modelisation de materiaux composites adaptatifs munis d'actionneurs en alliage a memoire de forme

    Science.gov (United States)

    Simoneau, Charles

    Technological development of structures having the capabilities to adapt themselves to different operating conditions is increasing in many areas of research such as aerospace. In fact, numerous works are now oriented toward the design of adaptive aircraft wings where the goal is to enhance the aerodynamic properties of the wing. Following this approach, the work realised in the framework of this master thesis presents the steps leading to the creation of a numerical model that can be used to predict the behavior of an adaptive panel, and therefore, eventually of an adaptive aircraft wing. Foremost, the adaptive panel of this project has been designed from a carbon-epoxy composite, acting as host structure, where shape memory alloy (SMA) wires, acting as actuators, have been inserted in it. SMA actuators have also been embedded asymmetrically along the direction of the panel thickness in order to generate a bending moment when the SMA wires are activated. To achieve the modeling of such structure it has been firstly shown that a numerical model composed of only solid finite elements could be used to represent the panel. However, a second numerical model composed of shell, beam and link finite elements showed that identical results can be obtained with much less nodes (the first model was composed of more than 300 000 nodes compared with 1 000 nodes for the second). The combination of shell-beam-link elements has then been chosen. Secondly, a constitutive relation had to be used for modeling the particular behavior of SMA. For the present work, a uniaxial version of the Likhachev's model is used. Due to its fairly straightforward mathematical formulation, this material law is able to model the main functional properties of SMA including the two-way shape memory effect (TWSME) at zero stress obtained after a thermomechanical education treatment. The last step was to compare the results of the numerical simulations with those obtained with a prototype where 19 actuators were embedded in a composite panel of 425 mm x 425 mm. Various load cases were performed. However, during experimental tests, it has been found that the measured actuator temperature was systematically underestimated. Therefore, by comparing the radius of curvature (rho) of the panel as a function of the activation temperature (T) of the actuators, an offset (in temperature) between the curves numerically and experimentally obtained is observable. Aside from this technological difficulty, the experimental and numerical results are very similar and therefore, this numerical model can be used for predicting the behavior of an adaptive panel. In addition, one the main advantages of this numerical model resides in its versatility where it has been shown that a "warping" of the panel could be realized by controlling independently each actuator. Future works should now obviously focus on the temperature measurement while considering the improvement of the numerical model and the possibility to model an initially curved adaptive panel whose form could resemble an aircraft wing.

  6. Modelisation and distribution of neutron flux in radium-beryllium source (226Ra-Be)

    Science.gov (United States)

    Didi, Abdessamad; Dadouch, Ahmed; Jai, Otman

    2017-09-01

    Using the Monte Carlo N-Particle code (MCNP-6), to analyze the thermal, epithermal and fast neutron fluxes, of 3 millicuries of radium-beryllium, for determine the qualitative and quantitative of many materials, using method of neutron activation analysis. Radium-beryllium source of neutron is established to practical work and research in nuclear field. The main objective of this work was to enable us harness the profile flux of radium-beryllium irradiation, this theoretical study permits to discuss the design of the optimal irradiation and performance for increased the facility research and education of nuclear physics.

  7. Modeling of turbulent bubbly flows; Modelisation des ecoulements turbulents a bulles

    Energy Technology Data Exchange (ETDEWEB)

    Bellakhal, Ghazi

    2005-03-15

    The two-phase flows involve interfacial interactions which modify significantly the structure of the mean and fluctuating flow fields. The design of the two-fluid models adapted to industrial flows requires the taking into account of the effect of these interactions in the closure relations adopted. The work developed in this thesis concerns the development of first order two-fluid models deduced by reduction of second order closures. The adopted reasoning, based on the principle of decomposition of the Reynolds stress tensor into two statistically independent contributions turbulent and pseudo-turbulent parts, allows to preserve the physical contents of the second order relations closure. Analysis of the turbulence structure in two basic flows: homogeneous bubbly flows uniform and with a constant shear allows to deduce a formulation of the two-phase turbulent viscosity involving the characteristic scales of bubbly turbulence, as well as an analytical description of modification of the homogeneous turbulence structure induced by the bubbles presence. The Eulerian two-fluid model was then generalized with the case of the inhomogeneous flows with low void fractions. The numerical results obtained by the application of this model integrated in the computer code MELODIF in the case of free sheared turbulent bubbly flow of wake showed a satisfactory agreement with the experimental data and made it possible to analyze the modification of the characteristic scales of such flow by the interfacial interactions. The two-fluid first order model is generalized finally with the case of high void fractions bubbly flows where the hydrodynamic interactions between the bubbles are not negligible any more. (author)

  8. Safety and vulnerability simulation of munitions; Modelisation du comportement de munitions en securite et vulnerabilite

    Energy Technology Data Exchange (ETDEWEB)

    Desailly, D.; Briquet, B.; Brunet, P.; Guegant, Y.; Houdusse, D.; Prost, M. [Groupe SNPE Propulsion/ Centre de Recherches du Boucher, 91 - Vert le Petit (France)

    2002-09-01

    Vulnerability of new weapon systems to accidental and hostile environments is a major concern for military operations and many research programs have been so investigated of SNPE Propulsion. Before they were accepted as being safe and suitable for introduction into military inventories systems underwent a wide range of expensive type qualification trials. There was a need therefore, to develop a greater understanding of the reaction mechanisms that affect the behaviour of confined energetic materials when subjected to external stimuli and computer models to control the resulting hazard. As part of this program SNPE Propulsion has developed a method for modelling Cook-off response in order to master the design of insensitive munitions (IM). The behavior of energetic materials when they are submitted to a thermal threat is complex and follows two different time scales: thermochemical processes, counted in minutes even hours whereas pyrotechnic reaction may require a few microseconds. It was shown that the reaction level is ruled by the competition between pressure generated from the cook-off reaction and stress release resulting from break-up confinement. After self-ignition phenomenon and under some confinement and thermal conditions burning can accelerate to deflagration and lead to a deflagration to detonation transition (DDT) event. The method requires'modular tools describing each physical phenomenon. Works have been first focused on the development of experimental facilities to characterise thermal chemical properties and reactivity of thermally damaged energetic material. Consequently the first part of the model describing self-heating and pyrolysis processes has been implemented in an implicit solver. Simulations have shown quite accurate predictions (ignition temperature, time to event) and proved the effectiveness of this approach. Recent developments are.thus concentrated on the numerical modelling of the reaction violence level prediction hence a thermal damage dependent burning model V.R.E.M.E. has been incorporated in an explicit solver for dynamic problems. First results come from simulations performed on generic vehicles full scale munitions and PBXs explosive warheads- No validation phase has been performed of this time, but results accuracy appears to be encouraging and attractive for future applications. (authors)

  9. MODELISATION DU RISQUE DANS LES METHODOLOGIES D'AUDIT : APPORT DE LA PSYCHOMETRIE

    OpenAIRE

    Mansour, Sadok

    2007-01-01

    Audit decision in risk situations was studied by researchers using normative and descriptive approaches issued from mathematics and economic sciences. We explain the impact of psycholgy resarch conduced by Kahneman and Tversky on the approach of auditors judgment. Key words : Decision, Judgment, Rationality, Heuristics.; Le thème de la décision en situation d'incertitude a été abordé par les recherches en audit en utilisant des approches normatives et descriptives issues des mathématiques et ...

  10. MODELISATION DU RISQUE DANS LES METHODOLOGIES D'AUDIT : APPORT DES DE LA PSYCHOMETRIE

    OpenAIRE

    Sadok Mansour

    2007-01-01

    International audience; Le thème de la décision en situation d'incertitude a été abordé par les recherches en audit en utilisant des approches normatives et descriptives issues des mathématiques et des Sciences économiques. Nous expliquons l'apport en audit des recherches en psychologie de la décision menées par Kahneman et Tversky.

  11. Modelling and control of a tokamak plasma; Modelisation et commande d`un plasma de tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Bremond, S

    1995-10-18

    Vertically elongated tokamak plasmas, while attractive as regards Lawson criteria, are intrinsically instable. It is found that the open-loop instability dynamics is characterised by the relative value of two dimensionless parameters: the coefficient of inductive coupling between the vessel and the coils, and the coil damping efficiency on the plasma displacement relative to that of the vessel. Applications to Tore Supra -where the instability is due to the iron core attraction- and DIII-D are given. A counter-effect of the vessel, which temporarily reverses the effect of coil control on the plasma displacement, is seen when the inductive coupling is higher than the damping ratio. Precise control of the plasma boundary is necessary if plasma-wall interaction and/or coupling to heating antennas are to be monitored. A positional drift, of a few mm/s, which had been observed in the Tore Supra tokamak, is explained and corrected. A linear plasma shape response model is then derived from magnetohydrodynamic equilibrium calculation, and proved to be in good agreement with experimental data. An optimal control law is derived, which minimizes an integral quadratic criteria on tracking errors and energy expenditure. This scheme avoids compensating coil currents, and could render local plasma shaping more precise. (authors). 123 refs., 77 figs., 6 tabs., 4 annexes.

  12. Thermal modeling. Application to lithium batteries; Modelisation thermique. Application aux accumulateurs lithium

    Energy Technology Data Exchange (ETDEWEB)

    Alexandre, A [Ecole Nationale Superieure de Mecanique et d` Aerotechnique (ENSMA), 86 - Poitiers (France); Flament, P [SAFT, 33 - Bordeaux (France); Marolleau, T [SAFT, Advanced and Industrial Battery Group, 86 - Poitiers (France); Guiot, T; Lefriec, C [TSR Futuropolis, 86 - Chasseneuil du Poitou (France)

    1997-12-31

    The thermal modeling of electrochemical batteries is today an integral part of the design and validation operations of new products. The Li-ion pair allows to increase the power density of batteries but leads to higher heat fluxes during charging-output cycles. Thus, the thermal control has become more crucial and requires the use of modeling. SAFT and TSR companies are involved in this approach and use the ESACAP software. This paper presents this software which uses a nodal method for the modeling of the coupled thermal and electrical processes that take place inside elementary cells and batteries. (J.S.)

  13. Le séchage combiné convection-micro-ondes : modelisation-validation-optimisation

    OpenAIRE

    Constant , Thiéry

    1992-01-01

    Not available; Ce travail est consacré à l'étude du séchage combiné convection-micro-ondes, le matériau choisi pour l'étude étant un béton cellulaire. Il comporte une partie théorique et une partie expérimentale. D’un point de vue théorique, deux points sont plus particulièrement discutés: la formulation du terme source volumique d'énergie et la modélisation des transferts de chaleur et de masse avec prise en compte du gradient de pression totale de la phase gazeuse. D’un point de vue expérim...

  14. Modeling of pollutant emissions from road transport; Modelisation des emissions de polluants par le transport routier

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    COPERT III (computer programme to calculate emissions from road transport) is the third version of an MS Windows software programme aiming at the calculation of air pollutant emissions from road transport. COPERT estimates emissions of all regulated air pollutants (CO, NO{sub x}, VOC, PM) produced by different vehicle categories as well as CO{sub 2} emissions on the basis of fuel consumption. This research seminar was organized by the French agency of environment and energy mastery (Ademe) around the following topics: the uncertainties and sensitiveness analysis of the COPERT III model, the presentation of case studies that use COPERT III for the estimation of road transport emissions, and the future of the modeling of road transport emissions: from COPERT III to ARTEMIS (assessment and reliability of transport emission models and inventory systems). This document is a compilation of 8 contributions to this seminar and dealing with: the uncertainty and sensitiveness analysis of the COPERT III model; the road mode emissions of the ESCOMPTE program: sensitivity study; the sensitivity analysis of the spatialized traffic at the time-aggregation level: application in the framework of the INTERREG project (Alsace); the road transport aspect of the regional air quality plan of Bourgogne region: exhaustive consideration of the road network; intercomparison of tools and methods for the inventory of emissions of road transport origin; evolution of the French park of vehicles by 2025: new projections; application of COPERT III to the French context: a new version of IMPACT-ADEME; the European ARTEMIS project: new structural considerations for the modeling of road transport emissions. (J.S.)

  15. Modeling of glass fusion furnaces; Modelisation des fours de fusion de verre

    Energy Technology Data Exchange (ETDEWEB)

    Mechitoua, N. [Electricite de France (EDF), 78 - Chatou (France). Direction des Etudes et Recherches; Plard, C. [Electricite de France, 77 - Moret sur Loing (France). Direction des Etudes et Recherches

    1997-12-31

    The furnaces used for glass melting are industrial installations inside which complex and coupled physical and chemical phenomena occur. Thermal engineering plays a major role and numerical simulation is a precious tool for the analysis of the different coupling, of their interaction and of the influence of the different parameters. In order to optimize the functioning of glass furnaces and to improve the quality of the glass produced, Electricite de France (EdF) has developed a specialized version of the ESTET fluid mechanics code, called `Joule`. This paper describes the functioning principle of glass furnaces, the interactions between heat transfers and flows inside the melted glass, the interactions between heat transfers and the thermal regulation of the furnace, the interactions between heat transfers and glass quality and the heat transfer interactions between the melted glass, the furnace walls and the combustion area. (J.S.)

  16. Mechanical behavior and modelisation of Ti-6Al-4V titanium sheet under hot stamping conditions

    Science.gov (United States)

    Sirvin, Q.; Velay, V.; Bonnaire, R.; Penazzi, L.

    2017-10-01

    The Ti-6Al-4V titanium alloy is widely used for the manufacture of aeronautical and automotive parts (solid parts). In aeronautics, this alloy is employed for its excellent mechanical behavior associated with low density, outstanding corrosion resistance and good mechanical properties up to 600°C. It is especially used for the manufacture of fuselage frames, on the pylon for carrying out the primary structure (machining forged blocks) and the secondary structure in sheet form. In this last case, the sheet metal forming can be done through various methods: at room temperature by drawing operation, at very high temperature (≃900°C) by superplastic forming (SPF) and at intermediate temperature (≥750°C) by hot forming (HF). In order to reduce production costs and environmental troubles, the cycle times reduction associated with a decrease of temperature levels are relevant. This study focuses on the behavior modelling of Ti-6Al-4V alloy at temperatures above room temperature to obtained greater formability and below SPF condition to reduce tools workshop and energy costs. The displacement field measurement obtained by Digital Image Correlation (DIC) is based on innovative surface preparation pattern adapted to high temperature exposures. Different material parameters are identified to define a model able to predict the mechanical behavior of Ti-6Al-4V alloy under hot stamping conditions. The hardening plastic model identified is introduced in FEM to simulate an omega shape forming operation.

  17. 3D Modelling of Urban Terrain (Modelisation 3D de milieu urbain)

    Science.gov (United States)

    2011-09-01

    Biblioteka Wojskowa 1000 Ljubljana NASA Center for AeroSpace Information (CASI) ul. Ostrobramska 109 7115 Standard Drive 04-041 Warszawa TURQUIE Hanover...29, Avenue de la Division Leclerc ul. Ostrobramska 109 Porton Down BP 72, 92322 Châtillon Cedex 04-041 Warszawa Salisbury SP4 0JQ GERMANY

  18. Separation of fission products by the use of recoil; Separation des produits de fission par utilisation du recul

    Energy Technology Data Exchange (ETDEWEB)

    Henry, R; Beydon, J; Bardy, A [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    We have studied fission recoil in U{sub 3}O{sub 8} organic solvent mixtures. The organic phase chosen was first naphtalene then terphenyl. Graphite and activated carbon were also tried out as recoil media. We first verified that the fission fragments are ejected from the uranium oxide particles under our experimental conditions. The retention phenomenon observed is due to an adsorption occurring either during irradiation or during the chemical treatment. Using naphthalene or terphenyl, the individual separation of the fission products has made it possible to show the influence of the chemical nature of the recoil medium on the retention of each fission product. We put forward a hypothesis concerning this phenomenon: experiments carried out using 'scavengers', together with kinetic studies make it possible to explain the retention phenomenon and to choose the most favorable conditions for reducing this retention to a low value. The thermal recombination kinetics demonstrate the influence of the fission ion charge on the final value of the retention for a given temperature. The origins of this thermal recombination are discussed. (author) [French] On a etudie le recul de fission dans les melanges U{sub 3}0{sub 8}, phase organique. La phase organique choisie a ete le naphtalene puis le terphenyle. Le graphite et le charbon actif ont egalement ete essayes comme milieux de recul. On a d'abord determine que les fragments de fission sortent des particules d'oxyde d'uranium avec un rendement de 100 pour cent dans nos conditions experimentales. Le phenomene de retention observe est du a une adsorption ayant lieu pendant l'irradiation ou pendant le traitement chimique. Dans le naphtalene et le terphenyle, la separation individuelle des produits de fission a permis de mettre en evidence l'influence de la nature chimique du milieu de recul sur la retention de chaque produit de fission. On avance une hypothese sur ce phenomene: des experiences effectuees avec des 'scavengers

  19. Formation and destruction mechanisms of nitrogen oxides during coal combustion in circulating fluidized beds; Mecanismes de formation et de destruction des oxydes d`azote lors de la combustion du charbon en lit fluidise circulant

    Energy Technology Data Exchange (ETDEWEB)

    Borrel, G.; Lecuyer, I. [Universite du Haut-Rhin, 68 - Mulhouse (France)

    1997-01-01

    Formation and reduction of nitrogen oxides (NO and N{sub 2}O) during coal combustion in a circulating fluidized bed (CFBC) are very complicated and yet badly known. The aim of the present study was to better characterize these phenomena on a small-sized experimental unit (reactor diameter: 5 cm), with the possibility to re-inject the solids in the bottom of the furnace, as in a real industrial unit. This should allow then to develop a numerical set of chemical reactions involving the nitrogen oxides. The experimental results showed that coal ash plays a great role in reducing nitrogen oxides, the determining parameter being the quantity of unburnt carbon remaining in the ash. The study then detailed the interaction between nitrogen oxides and de-volatilized (char) according to the temperature, NO{sub x} concentration and the mass of solid. In the absence of oxygen small quantities of char can very significantly reduce NO as well as N{sub 2}O. It was possible to establish destruction kinetics on these particles, and orders of reaction could be determined versus the NO{sub x} concentration and the char particle mass (heterogeneous phase chemical reactions). Then, the coal pyrolysis study enabled to identify the products released during coal devolatilization and thermogravimetric analyses displayed several successive weight losses due CO, CO{sub 2} and CH{sub 4} releases, during a linear temperature increase. Lastly coal combustion was studied in the small pilot with variable experimental conditions. Using the previous experimental was studied in the small pilot with variable experimental conditions. Using the previous experimental results, a model was developed to calculate NO{sub x} concentrations during the coal combustion and validated. The NO and N{sub 2}O contents calculated are thoroughly correlated with the experimental data whatever the injection carbon/oxygen ratio is. (author) 96 refs.

  20. Study of the effects of collector-type and collectors mixing in coal flotation; Etude des effets du type de collecteur et de melanges de collecteurs en flottation de charbon

    Energy Technology Data Exchange (ETDEWEB)

    Salch, A.M.; Ramadan, A.M.; Moharam, M.R. [Universite Al-Azhar, Le Caire (Egypt)

    2001-03-01

    This study deals with the effect of different types of collectors in the improvement of coal flotation process for the removal of impurities during the processing of poor quality coals. Abstract only. (J.S.)

  1. The coal. Its place in the world, the specifical problems of the european countries and more particularly the France; Le charbon. Sa place dans le monde, les problemes specifiques des pays d'Europe et tout particulierement de la France

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-12-15

    In a first part, the work group presents the available resources and studies the coal world market evolution. Then in a second time it discusses the european situation, and especially the french and german situation. The last part is devoted to the reconversion of the mines in France, the problems with the example of the coal basin of north of France. (A.L.B.)

  2. Clean coal technologies. The capture and geological storage of CO{sub 2} - Panorama 2008; Les technologies du charbon propre. Captage et stockage geologique du CO{sub 2} - Panorama 2008

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    There is no longer any doubt about the connection between carbon dioxide emissions of human origin and global warming. Nearly 40% of world CO{sub 2} emissions are generated by the electricity production sector, in which the combustion of coal - developing at a roaring pace, especially in China - accounts for a good proportion of the total. At a time when the reduction of greenhouse gases has become an international priority, this growth is a problem. Unless CO{sub 2} capture and storage technologies are implemented, it will be very difficult to contain global warming.

  3. The modelisation of constrained damping layer treatments using the finite element method: spatial model and viscoelastic behaviour

    OpenAIRE

    Rui Moreira; José Dias Rodrigues

    2002-01-01

    Surface and integrated damping treatments with viscoelastic layers play an important position among the passive damping treatments for light and flexible structures under vibration. Application simplicity, low cost, reduced structural modification and reduced additional mass, along with an inherent high efficiency, are the main reasons of it successful usage.However, the design process of these treatments is not simple and requires a reliable tool for adequate designing and analysis.The finit...

  4. SPICE modelling of the transient response of irradiated MOSFETs; Modelisation de la reponse transitoire de MOSFETs irradies avec SPICE

    Energy Technology Data Exchange (ETDEWEB)

    Pouget, V.; Lapuyade, H.; Lewis, D.; Deval, Y.; Fouillat, P. [Bordeaux-1 Univ., IXL, 33 - Talence (France); Sarger, L. [Bordeaux-1 Univ., CPMOH, 33 - Talence (France)

    1999-07-01

    A new SPICE model of irradiated MOSFET taking into account the real response of the 4 electrodes is proposed. The component that has been simulated is an NMOS transistor issued from the AMS BiCMOS 0.8 {mu}m technology. A comparison between SPICE-generated transients and PISCES device simulation demonstrates the accuracy benefits when used in complex electronic architectures. This model could be used when designing electronic circuits able to sustain hardening due to SEE (single event effect), it will be an efficient complement to the physical simulations.

  5. Modelisation of transport in fractured media with a smeared fractures modeling approach: special focus on matrix diffusion process.

    Science.gov (United States)

    Fourno, A.; Grenier, C.; Benabderrahmane, H.

    2003-04-01

    Modeling flow and transport in natural fractured media is a difficult issue due among others to the complexity of the system, the particularities of the geometrical features, the strong parameter value contrasts between the fracture zones (flow zones) and the matrix zones (no flow zones). This lead to the development of dedicated tools like for instance discrete fracture network models (DFN). We follow here another line applicable for classical continuous modeling codes. The fracture network is not meshed here but presence of fractures is taken into account by means of continuous heterogeneous fields (permeability, porosity, head, velocity, concentration ...). This line, followed by different authors, is referred as smeared fracture approach and presents the following advantages: the approach is very versatile because no dedicated spatial discretization effort is required (we use a basic regular mesh, simulations can be done on a rough mesh saving computer time). This makes this kind of approach very promising for taking heterogeneity of properties as well as uncertainties into account within a Monte Carlo framework for instance. Furthermore, the geometry of the matrix blocks where transfers proceed by diffusion is fully taken into account contrary to classical simplified 1D approach for instance. Nevertheless continuous heterogeneous field representation of a fractured medium requires a homogenization process at the scale of the mesh considered. Literature proves that this step of homogenization for transport is still a challenging task. Consequently, the level precision of the results has to be estimated. We precedently proposed a new approach dedicated to Mixed and Hybrid Finite Element approach. This numerical scheme is very interesting for such highly heterogeneous media and in particular guaranties exact conservation of mass flow for each mesh leading to good transport results. We developed a smeared fractures approach to model flow and transport limited to the fractured network. For a long time scale, the diffusion process can't be neglected. It plays an important retention role for the transport of plume. This is why we focus here on the evaluation of the approach for matrix diffusion. In addition, this is, here, a key issue because one of the specificities of the smeared fractures method is that it can deal with the actual rock block volume. Nevertheless we only devote a limited number of meshes to rock matrix blocks so that the limits of the approach in terms of time and space discretization level as well as transport regimes have to be addressed. So, having implemented the developed smeared fracture approach in our code CAST3M, we study the diffusion process for different transport regimes from dominant fracture network transport to dominant matrix diffusion transport and we estimate the validity as well as the precision of the results for different mesh sizes. This is done by comparing the smeared fracture approach results to reference calculations obtained by explicitly meshing the fractured system. Results show that the smeared fracture approach fairly well captures the main features of transport and reduces the simulation costs. For the cases studied, we succeed in having a good precision with different discretization levels. This finally makes this approach an interesting compromise between precision and versatility associated to low computer costs in the perspective of Monte Carlo simulations. A more realistic application is provided based on data from the Äspö underground laboratory (Sweden) and discussed. Future steps include extension of the approach to 3D cases.

  6. Compression-absorption (resorption) refrigerating machinery. Modeling of reactors; Machine frigorifique a compression-absorption (resorption). Modelisation des reacteurs

    Energy Technology Data Exchange (ETDEWEB)

    Lottin, O; Feidt, M; Benelmir, R [LEMTA-UHP Nancy-1, 54 - Vandoeuvre-les-Nancy (France)

    1998-12-31

    This paper is a series of transparencies presenting a comparative study of the thermal performances of different types of refrigerating machineries: di-thermal with vapor compression, tri-thermal with moto-compressor, with ejector, with free piston, adsorption-type, resorption-type, absorption-type, compression-absorption-type. A prototype of ammonia-water compression-absorption heat pump is presented and modeled. (J.S.)

  7. Experimental study and numerical simulation of free pulsed jets; Etude experimentale et modelisation numerique des jets libres pulses

    Energy Technology Data Exchange (ETDEWEB)

    Marzouk, Salwa; Mhiri, Hatem [Ecole Nationale d' Ingenieurs de Monastir, Lab. de Mecanique des Fluides et Thermique, Monastir (Tunisia); Caminat, Ph.; Le Palec, G.; Bournot, Ph. [UNIMECA, 13 - Marseille (France)

    2001-07-01

    A plane pulsed jet flow has been simulated by a finite difference method. Experimental results have also been obtained by laser tomography and particle image velocimetry. The results show that the flow is affected by the pulsation in the vicinity of the nozzle to reach an asymptotic state of a permanent jet. (A.L.B.)

  8. Model of a generator end-winding cage; Modelisation d`une cage de developpantes d`alternateur

    Energy Technology Data Exchange (ETDEWEB)

    Leger, A.C.; Fanton, J.P.; Davies, C.

    1994-09-01

    This document presents some studies concerning the vibratory characterization of particular structures called: generator end-winding cages. These structures are mainly made up of the endings of armature windings. The question of their good mechanical behaviour is of prime importance, since they are submitted to high electromagnetic efforts during the different electrical ratings encountered during operation. The designer (GEC-Alsthom) and the user (EDF) have both undertaken numerical calculations in order to characterize a given machine, in this case a 600 MW bipolar generator; it appeared interesting to compare such calculations. The models realized respectively by GEC-Alsthom and EDF make use of different techniques and hypotheses. GEC-Alsthom represents the sets of rods and spacers by plates, which properties are determined by a pre-processor. The model is simplified to take into account the existing symmetries. It takes profit of previous experience and aims at a fast utilisation. The EDF model tends to allow a further comprehensive calculation, form the electromagnetic efforts to the determination of local stresses. The whole set of the constituting elements of the structure is modelled by beams, which leads to an important size for the model (21 000 degrees of freedom). The validation performed on the two models has been focused on the comparison between respective results and also with experimental results. Each model provides values for the first eigenfrequencies and the associated modes shapes. (authors). 3 refs., 3 figs., 2 tabs.

  9. Modeling of the response under radiation of electronic dosemeters; Modelisations de la reponse sous rayonnements de dosimetres electroniques

    Energy Technology Data Exchange (ETDEWEB)

    Menard, S. [Institut de Radioprotection et de Surete Nucleaire (IRSN), 92 - Fontenay-aux-Roses (France)

    2003-07-01

    The simulation with with calculation codes the interactions and the transport of primary and secondary radiations in the detectors allows to reduce the number of developed prototypes and the number of experiments under radiation. The simulation makes possible the determination of the response of the instrument for exposure configurations more extended that these ones of references radiations produced in laboratories. The M.C.N.P.X. allows to transport, over the photons, electrons and neutrons, the charged particles heavier than the electrons and to simulate the radiation - matter interactions for a certain number of particles. The present paper aims to present the interest of the use of the M.C.N.P.X. code in the study, research and evaluation phases of the instrumentation necessary to the dosimetry monitoring. To do that the presentation gives the results of the modeling of a prototype of a equivalent tissue proportional counter (C.P.E.T.) and of the C.R.A.M.A.L. ( radiation protection apparatus marketed by the Eurisys Mesures society). (N.C.)

  10. Modelling the hydro-mechanical behaviour of swelling unsaturated soils; Modelisation du comportement hydromecanique des sols gonflants non satures

    Energy Technology Data Exchange (ETDEWEB)

    Mrad, M

    2005-10-15

    The use of compacted swelling soils in engineering practice is very widely spread, especially in geotechnical and environmental engineering. After their setup, these materials are likely to be subject to complex suction/stress paths involving significant variations of their hydro-mechanical properties which can affect their initial behaviour. It is important to be able to predict the hydro-mechanical behaviour of these materials taking into account the significant applications for which they are intended. Barcelona team developed a finite-element code (Code-Bright) for the thermo-hydro-mechanical coupling (THM) integrating the BBM elastoplastic model for unsaturated soils based on the independent variables approach. This model is recognized to correctly describe the hydro-mechanical behaviour of unsaturated soils but fails to take into account some particular observed aspects on swelling soils. A second model BExM was then proposed to address these aspects. The objective of this study is: (i) to implement the elastoplastic model BExM for the unsaturated swelling soils in the finite-element code (Code-Bright); (ii) to check the numerical model validity through the numerical simulation of laboratory tests made on swelling soils; and (iii) to apply this model to some practical problems. For this purpose, a new family of numerical procedures adapted to the BExM model was introduced into the code. The equation of the yield surface of this model for a given deviatoric stress states was given in a manner to facilitate calculations of its derivatives. The model was checked by the numerical simulation of suction-controlled odometric tests made on three different swelling soils. The simulation results showed that the numerical model is able to correctly reproduce the experimental data. Lastly, the model was applied to two practical problems: radioactive waste repository in deep geological layers and a shallow footing under the action of a swelling soil. The results obtained showed the ability of the numerical model to modeling hydro-mechanical coupled problems. (author)

  11. MODELISATION ET REALISATION D’UN CAPTEUR-STOCKEUR SOLAIRE A CUVE CYLINDRIQUE AVEC CONCENTRATEUR PARABOLIQUE COMPOSE.

    OpenAIRE

    HADJIAT, Mohammed Moundji

    2014-01-01

    Le but de ce travail est l’étude théorique et expérimentale d’un chauffe-eau solaire de type capteur stockeur. Ce dispositif est composé d’une cuve de stockage cylindrique disposée sur la ligne focale d’un réflecteur solaire en forme de concentrateur parabolique composé « CPC ». Cette cuve peinte en noir mat joue en même temps le rôle d’absorbeur et de stockeur d’eau chaude. Pour cela nous avons d’abord construit un modèle mathématique qui permet de calculer la température moye...

  12. Combustion modelling of a fuel oil flame; Modelisation de la combustion d`une flamme de fuel

    Energy Technology Data Exchange (ETDEWEB)

    Flour, I.; Mechitouan, N.

    1996-10-01

    The combustion modelling of a fuel oil flame has been realised in the scope of the R and D `Combustion Turbines`. This report presents the results of the 2D simulation of a fuel oil flame (n-octane), at atmospherical pressure, without swirl, realised using the Eulerian two-phase flow software Melodif. This calculation has been defined in collaboration with IFP, using experimental data from the IFRP. The hollow cone spray of liquid fuel is injected in the middle of the combustion chamber, with a co-flowing annular air. The furnace diameter is 2 meter and its length is 6,25 meter. A large recirculation zone is induced by the air flow, and leads to take into account the whole furnace, in order to avoid some problems with the limit conditions at the outlet. This calculation deals with droplets evaporation, gaseous phase combustion and radiation heat transfer. Predictions concerning gaseous axial mean velocity and mean temperature gradient in the flame, are in good agreement with measurements. However the temperature is too low in the peripheral zone of the flow. This is probably due to the fact that heat exchanges at the wall furnace are not correctly represented, because of a lack of detailed limit conditions for the walls. The mean radial velocity is not so well predicted, but this measurement is also quite difficult in a strongly longitudinal flow. The results concerning the dispersed phase will not be compared, because no measurements on the liquid fuel were available. As it has been experimentally observed, the simulation shows that the fuel oil spray quickly evaporates as it enters the combustion chamber. This result allows to propose to use an homogeneous approach (hypothesis of no-slipping between the two phases) in an Eulerian one-phase flow code, in case of a 3D simulation of liquid fuel turbine. (authors)

  13. Short term forecasting of petroleum product demand in France; Modelisation a court terme des consommations de produits petroliers en France

    Energy Technology Data Exchange (ETDEWEB)

    Cadren, M

    1998-06-23

    The analysis of petroleum product demand became a privileged thrust of research following the modifications in terms of structure and level of the petroleum markets since eighties. The greatest importance to econometrics models of Energy demand, joint works about nonstationary data, explained the development of error-correction models and the co-integration. In this context, the short term econometrics modelling of petroleum product demand does not only focus on forecasts but also on the measure of the gain acquired from using error-correction techniques and co-integration. It`s filling to take the influence of technical improvement and environment pressures into account in econometrics modelling of petroleum products demand. The first part presents the evolution of Energy Demand in France and more particularly the petroleum product demand since 1986. The objective is to determine the main characteristics of each product, which will help us to analyse and validate the econometrics models. The second part focus on the recent developments in times series modelling. We study the problem of nonstationary data and expose different unit root tests. We examine the main approaches to univariate and multivariate modelling with nonstationary data and distinguish the forecasts of the latter`s. The third part is intended to applications; its objective is to illustrate the theoretic developments of the second part with a comparison between the performances of different approaches (approach Box and Jenkins, Johansen approach`s and structural approach). The models will be applied to the main French petroleum market. The observed asymmetrical demand behaviour is also considered. (author) 153 refs.

  14. Modeling of pollution aerosols in Ile-de-France; Modelisation des aerosols de pollution en Ile-de-France

    Energy Technology Data Exchange (ETDEWEB)

    Hodzic, A

    2005-10-15

    The modeling of aerosols is a major stake in the understanding of the emission processes and evolution of particulates in the atmosphere. However, the parameterizations used in today's aerosol models still comprise many uncertainties. This work has been motivated by the need of better identifying the weaknesses of aerosols modeling tools and by the necessity of having new validation methods for a 3D evaluation of models. The studies have been carried out using the CHIMERE chemistry-transport model, which allows to simulate the concentrations and physico-chemical characteristics of pollution aerosols at the European scale and in Ile-de-France region. The validation approach used is based on the complementarity of the measurements performed on the ground by monitoring networks with those acquired during the ESQUIF campaign (study and simulation of air quality in Ile-de-France), with lidar and photometric measurements and with satellite observations. The comparison between the observations and the simulations has permitted to identify and reduce the modeling errors, and to characterize the aerosol properties in the vicinity of an urban area. (J.S.)

  15. Reserves' potential of sedimentary basin: modeling and estimation; Potentiel de reserves d'un bassin petrolier: modelisation et estimation

    Energy Technology Data Exchange (ETDEWEB)

    Lepez, V

    2002-12-01

    The aim of this thesis is to build a statistical model of oil and gas fields' sizes distribution in a given sedimentary basin, for both the fields that exist in:the subsoil and those which have already been discovered. The estimation of all the parameters of the model via estimation of the density of the observations by model selection of piecewise polynomials by penalized maximum likelihood techniques enables to provide estimates of the total number of fields which are yet to be discovered, by class of size. We assume that the set of underground fields' sizes is an i.i.d. sample of unknown population with Levy-Pareto law with unknown parameter. The set of already discovered fields is a sub-sample without replacement from the previous which is 'size-biased'. The associated inclusion probabilities are to be estimated. We prove that the probability density of the observations is the product of the underlying density and of an unknown weighting function representing the sampling bias. An arbitrary partition of the sizes' interval being set (called a model), the analytical solutions of likelihood maximization enables to estimate both the parameter of the underlying Levy-Pareto law and the weighting function, which is assumed to be piecewise constant and based upon the partition. We shall add a monotonousness constraint over the latter, taking into account the fact that the bigger a field, the higher its probability of being discovered. Horvitz-Thompson-like estimators finally give the conclusion. We then allow our partitions to vary inside several classes of models and prove a model selection theorem which aims at selecting the best partition within a class, in terms of both Kuilback and Hellinger risk of the associated estimator. We conclude by simulations and various applications to real data from sedimentary basins of four continents, in order to illustrate theoretical as well as practical aspects of our model. (author)

  16. Contribution to the modeling of atmospheric pollution in cities; Contribution a la modelisation de la pollution atmospherique dans les villes

    Energy Technology Data Exchange (ETDEWEB)

    Glockmer, St.

    2000-07-01

    Pollution generated by urban traffic and by industry at its periphery is a serious problem of our cities. Once emitted in the atmosphere, pollutants undergo two types of constraints: on one side they react chemically one with another and, on the other side, they are transported by the wind. We have chosen to work on the dynamical, thermal and chemical aspects of the pollution at different scales of the phenomena: local scale (around a group of buildings) and meso-scale (a whole city). Our ambition is not to realize a complete model but to advance step by step on each aspect. We have contributed to the realization of a numerical tool that will be completed and used for concrete pollution episodes. The first chapter is a description of the atmospheric boundary layer. Chapters two and three present models and results of numerical simulations. We stress on k-{epsilon}, RNG and v{sup 2}-f turbulence models, radiative heat transfer models and dynamical and thermal wall laws that allow to take in consideration surface roughness. The last chapter is dedicated to atmospheric chemistry. We have moreover developed a general solver of any number of transport equations coupled by a stiff chemistry and simplified ozone kinetics. (author)

  17. Modelisation agregee de chauffe-eau electriques commandes par champ moyen pour la gestion des charges dans un reseau

    Science.gov (United States)

    Losseau, Romain

    The ongoing energy transition is about to entail important changes in the way we use and manage energy. In this view, smart grids are expected to play a significant part through the use of intelligent storage techniques. Initiated in 2014, the SmartDesc project follows this trend to create an innovative load management program by exploiting the thermal storage associated with electric water heaters existing in residential households. The device control algorithms rely on the recent theory of mean field games to achieve a decentralized control of the water heaters temperatures producing an aggregate optimal trajectory, designed to smooth the electric demand of a neighborhood. Currently, this theory does not include power and temperature constraints due to the tank heating system or necessary for the user's safety and comfort. Therefore, a trajectory violating these constraints would not be feasible and would not induce the forecast load smoothing. This master's thesis presents a method to detect the non-feasability, of a target trajectory based on the Kolmogorov equations associated with the controlled electric water heaters and suggests a way to correct it so as to make it achievable under constraints. First, a partial differential equations based model of the water heaters under temperature constraints is presented. Subsequently, a numerical scheme is developed to simulate it, and applied to the mean field control. The results of the mean field control with and without constraints are compared, and non-feasabilities of the target trajectory are highlighted upon violations. The last part of the thesis is dedicated to developing an accelerated version of the mean field and a method of correcting the target trajectory so as to enlarge as much as possible the set of achievable profiles.

  18. Modelling of fractured reservoirs. Case of multi-scale media; Modelisation des reservoirs fractures. Cas des milieux multi-echelles

    Energy Technology Data Exchange (ETDEWEB)

    Henn, N.

    2000-12-13

    Some of the most productive oil and gas reservoirs are found in formations crossed by multi-scale fractures/faults. Among them, conductive faults may closely control reservoir performance. However, their modelling encounters numerical and physical difficulties linked with (a) the necessity to keep an explicit representation of faults through small-size grid blocks, (b) the modelling of multiphase flow exchanges between the fault and the neighbouring medium. In this thesis, we propose a physically-representative and numerically efficient modelling approach in order to incorporate sub-vertical conductive faults in single and dual-porosity simulators. To validate our approach and demonstrate its efficiency, simulation results of multiphase displacements in representative field sector models are presented. (author)

  19. Thermodynamic analysis and modeling of thermo compressor; Analyse et modelisation thermodynamique du mouvement du piston d'un thermocompresseur

    Energy Technology Data Exchange (ETDEWEB)

    Arques, Ph. [Ecole Centrale de Lyon, 69 - Ecully (France)

    1998-07-01

    A thermo-compressor is a compressor that transforms directly the heat release by a source in an energy of pressure without intermediate mechanical work. It is a conversion of the Stirling engine in driven machine in order that the piston that provides the work has been suppressed. In this article, we present the analytical and numerical analyses of heat and mass transfers modeling in the different volumes of the thermo-compressor. This engine comprises a free piston displacer that separates cold and hot gas. (author)

  20. Modelisation temporelle de la consommation electrique en analyse du cycle de vie appliquee au contexte des TIC

    Science.gov (United States)

    Maurice, Elsa

    Fossil fuels are a scarce energy resource. Since the industrial revolution, mankind uses and abuses of non-renewable energies. They are responsible for many environmental damages. The production of energy is one of the main challenges for a global sustainable development. In our society, we can witness an exponential increase of the usage of the systems of Information and Communication Technologies (ICT) such as Internet, phone calls, etc. The ICT development allows the creation and optimization of many smart systems, the pooling of services, and it also helps damping the climate change. However, because of their electric consumption, the ICT are also responsible for some green house gases (GHG) emissions: 3% in total. This fact gives them the willingness to change in order to limit their GHG emissions. In order to properly evaluate and optimize the ICT services, it is necessary to use some methods of evaluation that comply with the specificity of these systems. Currently, the methods used to evaluate the GHG emissions are not adapted to dynamic systems, which include the ICT systems. The variations of the production of electricity in a day or even a month are not yet taken into account. This problem is far from being restricted to the modelling of GHG emissions, it widens to the global variation in production and consumption of electricity. The Life Cycle Assessment (LCA) method grants useful and complete tools to analyse their environmental impacts, but, as with the GHG computation methods, it should be dynamically adapted. In the ICT framework, the first step to solve this LCA problem is to be able to model the variations in time of the electricity production. This master thesis introduces a new way to include the variation in time of the consumption and production of electricity in LCA methods. First, it generates an historical hourly database of the electricity production and import-export of three Canadian states: Alberta, Ontario and Quebec. Then it develops a model in function of time to predict their electricity consumption. This study is done for a project implementing a " cloud computing " service in between these states. The consumption model then provides information to optimize the best place and time to make use of ICT services such as Internet messaging or server maintenance. This first-ever implementation of time parameter allows more precision and vision in LCA data. The disintegration of electrical inventory flows in LCA refines the effects of the electricity production both historically and in real time. Some short-term predictions for the state of Quebec electrical exportations and importations were also computed in this thesis. The goal is to foresee and optimize in real time the ICT services use. The origin of a kilowatt-hour consumed in Quebec depends on the import-export variable with its surrounding states. This parameter relies mainly on the price of the electricity, the weather and the need for the state of Quebec in energy. This allows to plot a time-varying estimate of the environmental consequences for the consumption of a kilowatt-hour in Quebec. This can then be used to limit the GHG emission of ICT services like " cloud-computing " or " smart-grids ". A smart trade-off between electricity consumption and environmental issues will lead to a more efficient sustainable development.

  1. A Designer’s Guide to Human Performance Modelling (La Modelisation des Performances Humaines: Manuel du Concepteur).

    Science.gov (United States)

    1998-12-01

    into the Systems Engineering Process 17 5.3 Validation of HPMs 18 5.4 Commercialisation of human performance modelling software 18 5.5 Model Tool...budget) so that inappropriate models/tools are not offered. The WG agreed that another form of ’ educating ’ designers in the use of models was by means... Commercialisation of human performance modelling Software 5.2.8 Include human performance in system test. g More and more, customer’s are mandating the provision

  2. Analysis and modelling of the fuels european market; Analyse et modelisation des prix des produits petroliers combustibles en europe

    Energy Technology Data Exchange (ETDEWEB)

    Simon, V

    1999-04-01

    The research focus on the European fuel market prices referring to the Rotterdam and Genoa spot markets as well the German, Italian and French domestic markets. The thesis try to explain the impact of the London IPE future market on spot prices too. The mainstream research has demonstrated that co-integration seems to be the best theoretical approach to investigate the long run equilibrium relations. A particular attention will be devoted to the structural change in the econometric modelling on these equilibriums. A deep analysis of the main European petroleum products markets permit a better model specification concerning each of these markets. Further, we will test if any evidence of relations between spot and domestic prices could be confirmed. Finally, alternative scenarios will be depicted to forecast prices in the petroleum products markets. The objective is to observe the model reaction to changes crude oil prices. (author)

  3. Modeling and numerical study of transfers in fissured environments; Modelisation et etude numerique des transferts en milieux fissures

    Energy Technology Data Exchange (ETDEWEB)

    Granet, S.

    2000-01-28

    Oil recovery from fractured reservoirs plays a very important role in the petroleum industry. Some of the world most productive oil fields are located in naturally fractured reservoirs. Modelling flow in such a fracture network is a very complex problem. This is conventionally done using a specific idealized model. This model is based on the Warren and Root representation and on a dual porosity, dual permeability approach. A simplified formulation of matrix-fracture fluid transfers uses a pseudo-steady-state transfer equation involving a constant exchange coefficient. Such a choice is one of the main difficulties of this approach. To get a better understanding of the simplifications involved in the dual porosity approach a reference model must be available. To obtain such a fine description, we have developed a new methodology. This technique called 'the fissure element methodology' is based on a specific gridding of the fractured medium. The fissure network is gridded with linear elements coupled with an unstructured triangular grid of matrix. An appropriate finite volume scheme has been developed to provide a good description of the flow. The numerical development of is precisely described. A simulator has been developed using this method. Several simulations have been realised. Comparisons have been done with different dual-porosity dual-permeability models. A reflexion concerning the choice of the exchange coefficient used in the dual porosity model is then proposed. This new tool has permit to have a better understanding of the production mechanisms of a complex fractured reservoir. (author)

  4. Towards self-consistent plasma modelisation in presence of neoclassical tearing mode and sawteeth: effects on transport coefficients

    Science.gov (United States)

    Basiuk, V.; Huynh, P.; Merle, A.; Nowak, S.; Sauter, O.; Contributors, JET; the EUROfusion-IM Team

    2017-12-01

    The neoclassical tearing modes (NTM) increase the effective heat and particle radial transport inside the plasma, leading to a flattening of the electron and ion temperature and density profiles at a given location depending on the safety factor q rational surface (Hegna and Callen 1997 Phys. Plasmas 4 2940). In burning plasma such as in ITER, this NTM-induced increased transport could reduce significantly the fusion performance and even lead to a disruption. Validating models describing the NTM-induced transport in present experiment is thus important to help quantifying this effect on future devices. In this work, we apply an NTM model to an integrated simulation of current, heat and particle transport on JET discharges using the European transport simulator. In this model, the heat and particle radial transport coefficients are modified by a Gaussian function locally centered at the NTM position and characterized by a full width proportional to the island size through a constant parameter adapted to obtain the best simulations of experimental profiles. In the simulation, the NTM model is turned on at the same time as the mode is triggered in the experiment. The island evolution is itself determined by the modified Rutherford equation, using self-consistent plasma parameters determined by the transport evolution. The achieved simulation reproduces the experimental measurements within the error bars, before and during the NTM. A small discrepancy is observed on the radial location of the island due to a shift of the position of the computed q = 3/2 surface compared to the experimental one. To explain such small shift (up to about 12% with respect to the position observed from the experimental electron temperature profiles), sensitivity studies of the NTM location as a function of the initialization parameters are presented. First results validate both the transport model and the transport modification calculated by the NTM model.

  5. Modeling of pollution aerosols in Ile-de-France; Modelisation des aerosols de pollution en Ile-de-France

    Energy Technology Data Exchange (ETDEWEB)

    Hodzic, A

    2005-10-15

    The modeling of aerosols is a major stake in the understanding of the emission processes and evolution of particulates in the atmosphere. However, the parameterizations used in today's aerosol models still comprise many uncertainties. This work has been motivated by the need of better identifying the weaknesses of aerosols modeling tools and by the necessity of having new validation methods for a 3D evaluation of models. The studies have been carried out using the CHIMERE chemistry-transport model, which allows to simulate the concentrations and physico-chemical characteristics of pollution aerosols at the European scale and in Ile-de-France region. The validation approach used is based on the complementarity of the measurements performed on the ground by monitoring networks with those acquired during the ESQUIF campaign (study and simulation of air quality in Ile-de-France), with lidar and photometric measurements and with satellite observations. The comparison between the observations and the simulations has permitted to identify and reduce the modeling errors, and to characterize the aerosol properties in the vicinity of an urban area. (J.S.)

  6. Compression-absorption (resorption) refrigerating machinery. Modeling of reactors; Machine frigorifique a compression-absorption (resorption). Modelisation des reacteurs

    Energy Technology Data Exchange (ETDEWEB)

    Lottin, O.; Feidt, M.; Benelmir, R. [LEMTA-UHP Nancy-1, 54 - Vandoeuvre-les-Nancy (France)

    1997-12-31

    This paper is a series of transparencies presenting a comparative study of the thermal performances of different types of refrigerating machineries: di-thermal with vapor compression, tri-thermal with moto-compressor, with ejector, with free piston, adsorption-type, resorption-type, absorption-type, compression-absorption-type. A prototype of ammonia-water compression-absorption heat pump is presented and modeled. (J.S.)

  7. Modelling and numerical simulation of the General Dynamic Equation of aerosols; Modelisation et simulation des aerosols atmospheriques

    Energy Technology Data Exchange (ETDEWEB)

    Debry, E.

    2005-01-15

    Chemical-transport models are now able to describe in a realistic way gaseous pollutants behavior in the atmosphere. Nevertheless atmospheric pollution also exists as fine suspended particles, called aerosols, which interact with gaseous phase, solar radiation, and have their own dynamic behavior. The goal of this thesis is the modelling and numerical simulation of the General Dynamic Equation of aerosols (GDE). Part I deals with some theoretical aspects of aerosol modelling. Part II is dedicated to the building of one size resolved aerosol model (SIREAM). In part III we perform the reduction of this model in order to use it in dispersion models as POLAIR3D. Several modelling issues are still opened: organic aerosol matter, externally mixed aerosols, coupling with turbulent mixing, and nano-particles. (author)

  8. Compositional thermodynamic modelling of crystallization in waxy crudes; Modelisation thermodynamique compositionnelle de la cristallisation des bruts paraffiniques

    Energy Technology Data Exchange (ETDEWEB)

    Calange, S.

    1996-06-26

    During waxy crudes production, the risks of solid deposits formation, mainly in wells and in transport lines, are to be considered. These risks prevention induces high exploitation costs, and sometimes production losses. A better knowledge of the phenomena involved should allow an optimization of production conditions and thus cost reduction. With such objectives, we have developed a compositional thermodynamic model which allows to compute both the Wax Appearance Temperature and the amount of precipitated solid for lower temperatures. We have also implemented an experimental procedure in order to measure the solid deposit curve for a given crude under atmospheric pressure. The model can be used by means of a computer programme called `CRYSPAR`. This model takes into account the non-ideality of the solid phase through the one-parameter Margules equation. Thus it is only necessary to fit this unique parameter on the deposit quantities measured in the laboratory. The value thus determined will further allow the prediction of the deposition curves for crudes when their composition is changed, particularly by solvent addition. The experimental technique used is Differential Scanning Calorimetry (DSC). DSC is fast, easy to use and available in the laboratories of oil companies. (author) 181 refs.

  9. Modelisation of soluble aerosols behaviour in the atmosphere of a PWR nuclear reactor in case of accident

    International Nuclear Information System (INIS)

    Abbas, A.F.

    1984-07-01

    After a short description of soluble aerosols accidental production in a PWR, a calculation model is given for physical properties of a gaz and steam mixture in a given atmosphere. Then the equilibrium of a saline drop with steam is studied. From the MASON equation, a calculation model is given for kinetic of volume variation of a saline drop and also a sensitivity study showing the little influence of the boundary layer on the drop surface, of the drop settling and of the thermodynamic conditions of the containment. As a numerical application, this condensation/evaporation model, and a simplified one with faster numerical resolution, is introduced in the AEROSOLS codes of the CEA-DEMT. The AEROSOLS/A2 suppose a log-normal distribution of the suspended particles in the containment. This application shows the very large sensitivity of the condensation depending on the moisture ratio inside the reactor building, and its primary importance on the behaviour of the aerosols. It is also shown that the simplified model gives a very little difference compared with the detailed model, and that the computation time is much more lower [fr

  10. Modelling of heterogenous neutron leakages in a nuclear reactor; Modelisation des fuites heterogenes de neutrons dans un reacteur nucleaire

    Energy Technology Data Exchange (ETDEWEB)

    Wohleber, X

    1997-11-17

    The TIBERE Model is a neutron leakage method based on B{sub 1} heterogeneous transport equation resolution. In this work, we have studied the influence of the reflection mode at the boundary of the assembly. In particular the White boundary condition has been implemented in the APOLLO2 neutron transport code. We have compared the two TIBERE kinds of boundary conditions (specular and white) with the classical B{sub 1} homogeneous leakage method in the modelling of some reactors. We have remarked the better capability of the TIBERE Model to compute voided assemblies. The white boundary condition is also able to compute a completely voided assembly and, besides, wins a factor 10 in CPU time in comparison with the specular boundary condition. These two heterogenous leakage formalisms have been tested on a partially voided experiment and have shown that the TIBERE Model can compute this kind of situation with a greater precision than the classical B{sub 1} homogeneous leakage method, and with a shorter computational time. (author)

  11. Simulation of the annihilation emission of galactic positrons; Modelisation de l'emission d'annihilation des positrons Galactiques

    Energy Technology Data Exchange (ETDEWEB)

    Gillard, W

    2008-01-15

    Positrons annihilate in the central region of our Galaxy. This has been known since the detection of a strong emission line centered on an energy of 511 keV in the direction of the Galactic center. This gamma-ray line is emitted during the annihilation of positrons with electrons from the interstellar medium. The spectrometer SPI, onboard the INTEGRAL observatory, performed spatial and spectral analyses of the positron annihilation emission. This thesis presents a study of the Galactic positron annihilation emission based on models of the different interactions undergone by positrons in the interstellar medium. The models are relied on our present knowledge of the properties of the interstellar medium in the Galactic bulge, where most of the positrons annihilate, and of the physics of positrons (production, propagation and annihilation processes). In order to obtain constraints on the positrons sources and physical characteristics of the annihilation medium, we compared the results of the models to measurements provided by the SPI spectrometer. (author)

  12. Immiscible displacements in vuggy carbonates: experiments and simulation; Deplacements immiscibles dans des carbonates vacuolaires: experimentation et modelisation

    Energy Technology Data Exchange (ETDEWEB)

    Moctezuma Berthier, A.E.

    2003-07-01

    In the case of the vuggy carbonate rocks, we cannot interpret the experimental results by techniques developed For homogeneous porous media since the data reflect the effect of heterogeneities associated to the structure and to the interconnection of their porosity systems. The objective of this work is to propose new methodologies of characterization of the carbonates with bimodal porosity, as well as improved predictions of the transport properties in multiphase flow. Experimental and modelling work was conducted. A new methodology was proposed for the characterization of the bimodal structure on the pore scale which consists of a combination of centrifugation, nuclear magnetic resonance and mercury porosimetry. It was shown that it is possible to determine the pore sizes as well as the throat sizes which are the input data of the network models. The difference in connectivity of the structure influences the form of the displacement fronts as well as drainage/imbibition hysteresis. When the vugs are not connected, the front is of piston type and in the opposite case, of diffusive type. It was also showed that when the vugs are connected, there is a large hysteresis on the two phases whereas, when the vugs communicate only through the matrix, the hysteresis is less important. On the pore scale, we studied the effect of the vuggy field on the macroscopic properties using reconstructed porous media. We generalized the reconstruction method for vug systems. The numerical conductivity was found to be independent of the porosity distribution of the media; an empirical model was proposed. We showed that permeability is influenced by the vugs connectivity. If the vuggy system is not percolating, the matrix controls the permeability. An empirical model was proposed which considers vug porosity and the ratio of the characteristic scales between the matrix and the vugs. Under biphasic conditions, we showed that the relative permeability of the non-wetting phase is affected for the vuggy field even if it is not connected. On the core scale, we applied the reconstruction method to generate porosity fields by using the experimental charts obtained by X-Ray CT scanner. This method was satisfactory for an isotropic rock. Macroscopic conductivity is only slightly influenced by the porosity distribution; the empirical model on the pore scale is consistent with experimental measurements, and calculations on the reconstructed porosity field also lead to a very good agreement. (author)

  13. Dynamic modeling of an asynchronous squirrel-cage machine; Modelisation dynamique d'une machine asynchrone a cage

    Energy Technology Data Exchange (ETDEWEB)

    Guerette, D.

    2009-07-01

    This document presented a detailed mathematical explanation and validation of the steps leading to the development of an asynchronous squirrel-cage machine. The MatLab/Simulink software was used to model a wind turbine at variable high speeds. The asynchronous squirrel-cage machine is an electromechanical system coupled to a magnetic circuit. The resulting electromagnetic circuit can be represented as a set of resistances, leakage inductances and mutual inductances. Different models were used for a comparison study, including the Munteanu, Boldea, Wind Turbine Blockset, and SimPowerSystem. MatLab/Simulink modeling results were in good agreement with the results from other comparable models. Simulation results were in good agreement with analytical calculations. 6 refs, 2 tabs, 9 figs.

  14. Numerical modeling of transferred arc melting bath heating; Modelisation numerique du chauffage de bains par arc transfere

    Energy Technology Data Exchange (ETDEWEB)

    Bouvier, A. [Electricite de France, 77 - Moret sur Loing (France). Direction des Etudes et Recherches; Trenty, L.; Guillot, J.B. [Ecole Centrale de Paris, Laboratoire EM2C. CNRS, 92 - Chatenay-Malabry (France); Delalondre, C. [Electricite de France (EDF), 78 - Chatou (France). Direction des Etudes et Recherches

    1997-12-31

    This paper presents the modeling of a transferred electric arc inside a bath of melted metal. After a recall of the context of the study, the problem of the modeling, which involves magnetohydrodynamic coupling inside the arc and the bath, is described. The equations that govern the phenomena inside the arc and the bath are recalled and the approach used for the modeling of the anode region of the arc is explained using a 1-D sub-model. The conditions of connection between arc and bath calculations are explained and calculation results obtained with a 200 kW laboratory furnace geometry are presented. (J.S.) 8 refs.

  15. Thermodynamical modeling of nuclear glasses: coexistence of amorphous phases; Modelisation thermodynamique des verres nucleaires: coexistence entre phases amorphes

    Energy Technology Data Exchange (ETDEWEB)

    Adjanor, G

    2007-11-15

    Investigating the stability of borosilicate glasses used in the nuclear industry with respect to phase separation requires to estimate the Gibbs free energies of the various phases appearing in the material. In simulation, using current computational resources, a direct state-sampling of a glassy system with respect to its ensemble statistics is not ergodic and the estimated ensemble averages are not reliable. Our approach consists in generating, at a given cooling rate, a series of quenches, or paths connecting states of the liquid to states of the glass, and then in taking into account the probability to generate the paths leading to the different glassy states in ensembles averages. In this way, we introduce a path ensemble formalism and calculate a Landau free energy associated to a glassy meta-basin. This method was validated by accurately mapping the free energy landscape of a 38-atom glassy cluster. We then applied this approach to the calculation of the Gibbs free energies of binary amorphous Lennard-Jones alloys, and checked the correlation between the observed tendencies to order or to phase separate and the computed Gibbs free energies. We finally computed the driving force to phase separation in a simplified three-oxide nuclear glass modeled by a Born-Mayer-Huggins potential that includes a three-body term, and we compared the estimated quantities to the available experimental data. (author)

  16. Study experimental and modelisation of strain plastic of iron : rats strains, sensibility to strain rate and loading history

    OpenAIRE

    Afane , Mostapha

    1997-01-01

    This work describes the behavior of a cubical system metal centered : the iron 0.02% C with the help many experimental results. The first part of this thesis is devoted to a bibliographical study whose which the sensitivity of the behavior of metals CC to the speed of deformation, to the temperature is put in obviousness, the indication of the possibility of the appearance of the mecanical twining for the great speeds of deformation, the existence for metals CC of them limit inferior elastici...

  17. Geologic modeling constrained by seismic and dynamical data; Modelisation geologique contrainte par les donnees sismiques et dynamiques

    Energy Technology Data Exchange (ETDEWEB)

    Pianelo, L.

    2001-09-01

    Matching procedures are often used in reservoir production to improve geological models. In reservoir engineering, history matching leads to update petrophysical parameters in fluid flow simulators to fit the results of the calculations with observed data. In the same line, seismic parameters are inverted to allow the numerical recovery of seismic acquisitions. However, it is well known that these inverse problems are poorly constrained. The idea of this original work is to simultaneous match both the permeability and the acoustic impedance of the reservoir, for an enhancement of the resulting geological model. To do so, both parameters are linked using either observed relations and/or the classic Wyllie (porosity impedance) and Carman-Kozeny (porosity-permeability) relationships. Hence production data are added to the seismic match, and seismic observations are used for the permeability recovery. The work consists in developing numerical prototypes of a 3-D fluid flow simulator and a 3-D seismic acquisition simulator. Then, in implementing the coupled inversion loop of the permeability and the acoustic impedance of the two models. We can hence test our theory on a 3-D realistic case. Comparison of the coupled matching with the two classical ones demonstrates the efficiency of our method. We reduce significantly the number of possible solutions, and then the number of scenarios. In addition to that, the augmentation of information leads to a natural improvement of the obtained models, especially in the spatial localization of the permeability contrasts. The improvement is significant, at the same time in the distribution of the two inverted parameters, and in the rapidity of the operation. This work is an important step in a way of data integration, and leads to a better reservoir characterization. This original algorithm could also be useful in reservoir monitoring, history matching and in optimization of production. This new and original method is patented and contributes to an improvement in History matching, Seismic interpretation, Reservoir characterization and Matching procedures (inverse problems). (author)

  18. Radioactivity of French coast of the Channel due to the release of technectium 99 and iodine 129: modelisation and measurements

    International Nuclear Information System (INIS)

    Robeau, D.; Patti, F.; Charmasson, S.

    1988-01-01

    Radioactive releases of Iodine 129 are controlled by measurements of the radioactivity in the liquid effluents before it is released in to the sea from the outlet of the reprocessing plant of La Hague. The effects on the marine environment are examined by a radioactive survey of Technecium 99 and Iodine 129 in Fucus (common seaweed). This radioactivity is measured along the north coast of France from Roscoff in the west of Brittany to Wimereux close to the Belgian frontier. The theoretical study of dispersion of radionuclides in the Channel has permitted a simulation model of the transfer of pollutants and particularly Technecium 99 and Iodine 129 to be formulated. (author)

  19. Modelisation numerique d'un actionneur plasma de type decharge a barriere dielectrique par la methode de derive-diffusion

    Science.gov (United States)

    Xing, Jacques

    Dielectric barrier discharge (DBD) plasma actuator is a proposed device for active for control in order to improve the performances of aircraft and turbomachines. Essentially, these actuators are made of two electrodes separated by a layer of dielectric material and convert electricity directly into flow. Because of the high costs associated with experiences in realistic operating conditions, there is a need to develop a robust numerical model that can predict the plasma body force and the effects of various parameters on it. Indeed, this plasma body force can be affected by atmospheric conditions (temperature, pressure, and humidity), velocity of the neutral flow, applied voltage (amplitude, frequency, and waveform), and by the actuator geometry. In that respect, the purpose of this thesis is to implement a plasma model for DBD actuator that has the potential to consider the effects of these various parameters. In DBD actuator modelling, two types of approach are commonly proposed, low-order modelling (or phenomenological) and high-order modelling (or scientific). However a critical analysis, presented in this thesis, showed that phenomenological models are not robust enough to predict the plasma body force without artificial calibration for each specific case. Moreover, there are based on erroneous assumptions. Hence, the selected approach to model the plasma body force is a scientific drift-diffusion model with four chemical species (electrons, positive ions, negative ions, and neutrals). This model was chosen because it gives consistent numerical results comparatively with experimental data. Moreover, this model has great potential to include the effect of temperature, pressure, and humidity on the plasma body force and requires only a reasonable computational time. This model was independently implemented in C++ programming language and validated with several test cases. This model was later used to simulate the effect of the plasma body force on the laminar-turbulent transition on airfoil in order to validate the performance of this model in practical CFD simulation. Numerical results show that this model gives a better prediction of the effect of the plasma on the fluid flow for a practical case in aerospace than a phenomenological model.

  20. Presentation of the CPR ISMIR (Insulators: IRradiation Modelling); Presentation du CPR ISMIR (ISolants: modelisation de l'IRradiation)

    Energy Technology Data Exchange (ETDEWEB)

    Lozes, G. [CEA Saclay, Dir. de l' Energie Nucleaire (DEN/DSOE), 91 - Gif sur Yvette (France)

    2007-07-01

    The CPR ISMIR is a CEA-CNRS program on the behaviour of materials submitted to irradiation; it has been begun to support the applied current research programs on the aging of nuclear fuels, the storage and incineration matrices and the future reactors. Its aim is to contribute to scientifically set up the methods for anticipating the behaviour of ceramic materials under irradiation in using the important development of calculation means. Thus have been developed the basic knowledge and the interactions physics and calculation models at pertinent scales have been elaborated. (O.M.)

  1. Modelisation, conception et simulation des performances d'un collecteur solaire aeraulique a tubes sous vide en milieu nordique

    Science.gov (United States)

    Paradis, Pierre-Luc

    The global energy consumption is still increasing year after year even if different initiatives are set up to decrease fossil fuel dependency. In Canada 80% of the energy is used for space heating and domestic hot water heating in residential sector. This heat could be provided by solar thermal technologies despite few difficulties originating from the cold climate. The aim of this project is to design a solar evacuated tube thermal collector using air as the working fluid. Firstly, needs and specifications of the product are established in a clear way. Then, three concepts of collector are presented. The first one relies on the standard evacuated tube. The second one uses a new technology of tubes; both sides are open. The third one uses heat pipe to extract the heat from the tubes. Based on the needs and specification as criteria, the concept involving tubes with both sides open has been selected as the best idea. In order to simulate the performances of the collector, a model of the heat exchanges in an evacuated tube was developed in 4 steps. The first step is a model in steady state intended to calculate the stagnation temperature of the tube for a fixed solar radiation, outside temperature and wind speed. As a second step, the model is generalised to transient condition in order to validate it with an experimental setup. A root mean square error of 2% is then calculated. The two remainder steps are intended to calculate the temperature of airflow leaving the tube. In the same way, a first model in steady state is developed and then generalised to the transient mode. Then, the validation with an experimental setup gave a difference of 0.2% for the root mean square error. Finally, a preindustrial prototype intended to work in open loop for preheating of fresh air is presented. During the project, explosion of the both sides open evacuated tube in overheating condition blocked the construction of a real prototype for the test. Different path for further work are also identified. One of these is in relation with CFD simulation of the uniformity of the airflow inside of the collector. Another one is the analysis of the design with a design of experiment plan.

  2. Compositional thermodynamic model of asphaltenes flocculation out of crudes; Modelisation thermodynamique compositionnelle de la floculation des bruts asphalteniques

    Energy Technology Data Exchange (ETDEWEB)

    Szewczyk, V

    1997-12-02

    The aim of this work is to propose to the oil industry a compositional thermodynamic model able to predict the operating conditions which induce asphaltenes flocculation out of crudes. In this study, various analytical methods (calorimetry, elemental analysis, {sup 13}C nuclear magnetic resonance, neutron diffusion,...) have been used in order to get a better description of the asphaltene fraction to infer its flocculation mechanism. The proposed model describes this flocculation as a thermodynamic transition inducing the formation of a new liquid phase with a high asphaltene content and formed by all the components initially in the crude: the asphaltene deposit. Asphaltenes are represented as a pseudo-component essentially made of carbon and hydrogen. The analytical modelling of the F11-F20 light fraction is the one proposed by Jaubert (1993). The F20+ heavy fraction is represented by four pseudo-components, their physical properties are calculated using the group contribution methods of Avaullee (1995) and of Rogalski and Neau (1990). The Peng-Robinson equation of state (1976) combined with the Abdoul and Peneloux group contribution mixing rules (1989) is used in order to restitute the gas-liquid-asphaltene deposit phase equilibria. This model not being able to compute flocculation conditions on a predictive manner, the method consists in fitting some physical properties of the pseudo-components introduced in the analytical representation of the asphaltene crudes. he obtained results show results show that the proposed flocculation model is then well adapted to the description of the thermodynamic properties (saturation pressures, relative volumes, flocculation curves) of asphaltene crudes within a relatively large range of temperature (30-150 deg C) and pressure (0.1-50 MPa), covering the majority of conditions met in oil production. (author) 109 refs.

  3. Modeling of columnar and equiaxed solidification of binary mixtures; Modelisation de la solidification colonnaire et equiaxe de melanges binaires

    Energy Technology Data Exchange (ETDEWEB)

    Roux, P

    2005-12-15

    This work deals with the modelling of dendritic solidification in binary mixtures. Large scale phenomena are represented by volume averaging of the local conservation equations. This method allows to rigorously derive the partial differential equations of averaged fields and the closure problems associated to the deviations. Such problems can be resolved numerically on periodic cells, representative of dendritic structures, in order to give a precise evaluation of macroscopic transfer coefficients (Drag coefficients, exchange coefficients, diffusion-dispersion tensors...). The method had already been applied for a model of columnar dendritic mushy zone and it is extended to the case of equiaxed dendritic solidification, where solid grains can move. The two-phase flow is modelled with an Eulerian-Eulerian approach and the novelty is to account for the dispersion of solid velocity through the kinetic agitation of the particles. A coupling of the two models is proposed thanks to an original adaptation of the columnar model, allowing for undercooling calculation: a solid-liquid interfacial area density is introduced and calculated. At last, direct numerical simulations of crystal growth are proposed with a diffuse interface method for a representation of local phenomena. (author)

  4. Mediterranean climate modelling: variability and climate change scenarios; Modelisation climatique du Bassin mediterraneen: variabilite et scenarios de changement climatique

    Energy Technology Data Exchange (ETDEWEB)

    Somot, S

    2005-12-15

    Air-sea fluxes, open-sea deep convection and cyclo-genesis are studied in the Mediterranean with the development of a regional coupled model (AORCM). It accurately simulates these processes and their climate variabilities are quantified and studied. The regional coupling shows a significant impact on the number of winter intense cyclo-genesis as well as on associated air-sea fluxes and precipitation. A lower inter-annual variability than in non-coupled models is simulated for fluxes and deep convection. The feedbacks driving this variability are understood. The climate change response is then analysed for the 21. century with the non-coupled models: cyclo-genesis decreases, associated precipitation increases in spring and autumn and decreases in summer. Moreover, a warming and salting of the Mediterranean as well as a strong weakening of its thermohaline circulation occur. This study also concludes with the necessity of using AORCMs to assess climate change impacts on the Mediterranean. (author)

  5. Research programme 'Active Solar Energy Use - Solar Heating and Heat Storage'. Activities and projects 2003; Programme 'Solaire actif - Chaleur et Stockage de chaleur'. Activites et projets en 2003

    Energy Technology Data Exchange (ETDEWEB)

    Hadorn, J.-C. [Base Consultants, Geneva (Switzerland); Renaud, P. [Planair SA, La Sagne (Switzerland)

    2003-07-01

    In this report by the research, development and demonstration (RD+D) programme coordinators the objectives, activities and main results in the area of solar heating and heat storage in Switzerland are presented for 2003. In a stagnating market environment the strategy of the Swiss Federal Office of Energy mainly consists in improving the quality and durability of solar collectors and materials, optimizing combisystems for space heating and domestic hot water preparation, searching for storage systems with a higher energy storage density than in the case of sensible heat storage in water, developing coloured solar collectors for more architectonic freedom, and finalizing a seasonal heat storage project for 100 dwellings to demonstrate the feasibility of solar fractions larger than 50% in apartment houses. Support was granted to the Swiss Testing Facility SPF in Rapperswil as in previous years; SPF was the first European testing institute to perform solar collector labeling according to the new rules of the 'Solar Keymark', introduced in cooperation with the European Committee for Standardization CEN. Several 2003 projects were conducted within the framework of the Solar Heating and Cooling Programme of the International Energy Agency IEA. Computerized simulation tools were improved. With the aim of jointly producing high-temperature heat and electric power a solar installation including a concentrating collector and a thermodynamic machine based on a Rankine cycle is still being developed. Seasonal underground heat storage was studied in detail by means of a validated computer simulation programme. Design guidelines were obtained for such a storage used in the summer time for cooling and in the winter time for space heating via a heat pump: depending on the ratio 'summer cooling / winter heating', cooling requires a cooling machine, or direct cooling without such a machine is possible. The report ends up with the list of all supported RD+D projects.

  6. Acumulação primitiva:  um processo atuante na sociedade contemporânea Accumulation Primitive: un processus actif dans la societé contemporaine Primitive accumulation: a process active in contemporary society

    Directory of Open Access Journals (Sweden)

    Sandra Lencioni

    2012-03-01

    Full Text Available Com a hegemonia da reprodução social capitalista, a acumulação primitiva é interpretada ora como sendo um fato do passado, ora como um processo que perdura até hoje.  Nosso ponto de vista é de que a acumulação primitiva historicamente não desapareceu, sendo, inclusive, um importante componente da sociedade contemporânea. Nela, os processos capitalistas de acumulação primitiva e de reprodução do capital coexistem e se complementam de forma contraditória e dialética. O primeiro, o processo de acumulação primitiva está relacionado à espoliação e à produção de um capital novo, enquanto que o segundo, o de reprodução do capital está relacionado à exploração e tem como ponto de partida um capital já constituído. A diferença entre os termos espoliação e exploração é apresentada, bem como a posição de Harvey sob essa polêmica, se constituindo nas discussões que constituindo a primeira parte do texto. Na segunda parte se discute que a acumulação primitiva dos dias atuais repete a fraude, o roubo e a violência que estiveram presentes no momento da gênese do capitalismo. Embora o mundo pareça ter mudado, com tanto avanço técnico e tantas leis acerca dos direitos humanos, não mudou muito, pois persistem práticas de fraude, roubo e violência como expedientes de produção de capital.  Vários exemplos de rapinagem dos recursos naturais são dados, incluindo-se aí a biopirataria. Também é destacada a escravidão por dívida, como uma forma violenta de espoliação, uma forma de acumulação primitiva de capital em que o trabalhador livre, pelos mecanismos de sujeição ao qual está submetido, perde sua liberdade. O roubo de terras se constitui num outro exemplo de acumulação primitiva dessa sociedade contemporânea. Afirma-se que todas as formas de espoliação são produtoras de dinheiro e produtoras de capital em potencial e que o capital financeiro é que constrói, em especial, o elo entre acumulação primitiva e reprodução do capital na sociedade contemporânea.Dans le contexte d'hégémonie de la reproduction sociale capitaliste, l'accumulation primitive est interprétée soit comme un processus du passé, soit comme un processus qui se fait présent jusqu’aujourd’hui. Notre point de vue est que l'accumulacion primitive historique n'a pas disparu. Au contraire, elle est encore une importante composante de la société contemporaine. En ce cas, les deux processus capitalistes, d'accumulation primitive et de reproduction du capital, coexistent et s’accomplissent de façon contradictoire et dialectique. Le premier processus est attaché à la spoliation et à la production d'un capital nouveau, alors que le second est attaché à l'exploration d’un capital déjà constitué qui, en même temps, fait partie de celui là. La différence entre les deux termes, spoliation et exploration, est examinée dans la première partie du texte, et en considérant la position de Harvey à propos de cette controverse. Dans la deuxième partie on discute l'accumulation primitive qui se manifeste aujourd’hui, comme la fraude, le vol et la violence, tels qu’ils se présentaient lors de la genèse du capitalisme. Bien que le monde ait changé, à cause du progrès technique, et malgré l’existence de lois de protection des droits de l'homme, il y a encore des actions semblables à celles de cette époque là. Ces actions se manifestent vraiment comme expédientes de la production du capital à la façon primitive, à savoir: le vol de terres; la rapine des ressources naturelles y inclus la biopiraterie; l'esclavage pour dette, une forme violente de spoliation où le travailleur libre, par les mécanismes de domination auxquels il est soumis, perd sa liberté. Par conséquent, on propose la thèse suivante : toutes les formes de spoliation sont productrices d'argent et de capital en potentiel et le capital financier, à son tour,  construit particulièrement le lien entre l’accumulation primitive et la reproduction du capital dans la société contemporaine.With the hegemony of the social accumulation reproduction, the primitive accumulation is interpreted sometimes like a fact of the past and sometimes like a process that continues until today. Our point of view is that the historical primitive accumulation has not disappeared, including being one of the important components of contemporary society. In this society, the capitalists processes of primitive accumulation and the reproduction of capital coexist and complement each other in a contradictory and dialectical way. The first, the process of primitive accumulation is related to spoliation and to the production of new capital, while the second, the reproduction of capital is related to the exploration and it is a part of a capital already existing. The difference between the names 'spoliation' and 'exploitation' is confronted and the Harvey's opinion about accumulation by dispossession is discussed in the first part of the text. The second part discusses about the primitive accumulation of today, repeating the fraud, the theft and the violence, that were presents in the moment of the genesis of capitalism. Although the world seems to have changed, with both technical advancement and a variety of laws about human rights, it has not changed that much. Acts of fraud, theft and violence as expedients to generate capital still continues. Several examples of robbery of the natural resources are given, including the bio-piracy. Also, the debt slavery is emphasized as a violent form of spoliation, a form of primitive accumulation of capital in which the free worker, by mechanisms of subjection which he is subjugated, loses his freedom. The theft of land constitutes another example of primitive accumulation of the contemporary society. It is stated that all forms of dispossession are producing money and producing potential capital. Particularly, the financial capital is the one that especially establishes the link between primitive accumulation and reproduction of capital in contemporary society.

  7. Amorphous silicon cells for the measurement of photosynthetically active radiation; Utilisation des cellules au silicium amorphe pour la mesure du rayonnement photosynthétiquement actif (400-700 nm)

    Energy Technology Data Exchange (ETDEWEB)

    Chartier, M. [Institut National de la Recherche Agronomique, Thiverval-Grignon (France); Bonchretien, P.; Allirand, J. M.; Gosse, G.

    1989-07-01

    Numerical simulation and experimental measurements from amorphous silicon cells in comparison with these now used in ecophysiology illustrate the interest of amorphous silicon cells for the measurement of PAR incident, reflected, and transmitted below the canopy [French] La simulation et la confrontation expérimentale ces réponses des cellules au silicium amorphe par rapport à celles des capteurs existants montrent l’intérêt des cellules au silicium amorphe pour la mesure du rayonnement PAR (exprimé en densité de flux de photons) incident, réfléchi et transmis sous un couvert végétal.

  8. La décision de détention d'actifs liquides : motivations et conséquences : le cas des entreprises cotées au SBF 250

    OpenAIRE

    El Ouazzani, Mohammed Adil

    2014-01-01

    The topic of corporate cash holdings has received relatively little attention from the academicresearchers. Yet, French firms hold significant cash reserves. This research aims to investigate,theoretically and empirically, the motivations and implications of the decision to hold cash.The first part of the thesis aims to provide a state of the art of the theories explaining corporate cashholding behavior. The second part seeks to empirically test these theories on a sample of 202 Frenchcompani...

  9. Développement des marchés financiers et évaluation des actifs bancaires : coût historique versus juste valeur. L'exemple de la titrisation

    OpenAIRE

    Thuelin, Elisabeth

    2002-01-01

    Le recours au coût historique et à des techniques d'allègement des bilans comme la titrisation permettent aux banques de disposer d'une marge de manoeuvre en matière comptable. Le développement des marchés financiers et l'orientation actuelle de l'IASC et du FASB en faveur de la juste valeur sont susceptibles de bouleverser les images des établissements telles qu'elles ressortent des documents comptables.

  10. Research and Development of Monolithic Active Pixel Sensors for the Detection of the Elementary Particles; Recherche et developpement de capteurs actifs monolithiques CMOS pour la detection de particules elementaires

    Energy Technology Data Exchange (ETDEWEB)

    Li, Y

    2007-09-15

    In order to develop high spatial resolution and readout speed vertex detectors for the future International Linear Collider (ILC), fast CMOS Monolithic Active Pixel Sensors (MAPS) are studied on this work. Two prototypes of MAPS, MIMOSA 8 and MIMOSA 16, based on the same micro-electronic architecture were developed in CMOS processes with different thickness of epitaxial layer. The size of pixel matrix is 32 x 128: 8 columns of the pixel array are readout directly with analog outputs and the other 24 columns are connected to the column level auto-zero discriminators. The Correlated Double Sampling (CDS) structures are successfully implemented inside pixel and discriminator. The photo diode type pixels with different diode sizes are used in these prototypes. With a {sup 55}Fe X-ray radioactive source, the important parameters, such as Temporal Noise, Fixed Pattern Noise (FPN), Signal-to-Noise Ratio (SNR), Charge-to-Voltage conversion Factor (CVF) and Charge Collection Efficiency (CCE), are studied as function of readout speed and diode size. For MIMOSA 8, the effect of fast neutrons irradiation is also. Two beam tests campaigns were made: at DESY with a 5 GeV electrons beam and at CERN with a 180 GeV pions beam. Detection Efficiency and Spatial Resolution are studied in function of the discriminator threshold. For these two parameters, the influences of diode size and SNR of the central pixel of a cluster are also discussed. In order to improve the spatial resolution of the digital outputs, a very compact (25 {mu}m x 1 mm) and low consumption (300 {mu}W) column level ADC is designed in AMS 0.35 {mu}m OPTO process. Based on successive approximation architecture, the auto-offset cancellation structure is integrated. A new column level auto-zero discriminator using static latch is also designed. (author)

  11. Experimental study of mechanical behaviour of a clay-stone: application to nuclear waste disposals; Etude experimentale du comportement mecanique d'argiles raides: application au stockage de dechets radio-actifs

    Energy Technology Data Exchange (ETDEWEB)

    Chiarelli, A.S. [Laboratoire de Materiaux et Sciences des Constructions, UPRES JE 2200, IUP Genie Civil et Infrastructures, 95 - Cergy Pontoise (France); Shao, J.F. [Laboratoire de Mecanique de Lille, URA CNRS 1441, EUDIL, 59 - Villeneuve d' Ascq (France); Ledesert, B. [Laboratoire de Sedimentologie et Geodynamique, FRE 2255, 59 - Villeneuve d' Ascq (France); Hoteit, N. [Agence Nationale pour la Gestion des Dechets Nucleaires (ANDRA), 92 - Chatenay Malabry (France)

    2001-02-01

    A study of mechanical behaviour of deep argillaceous rocks from East of France, the 'argilites de l'Est' as a potential host rock for radioactive waste disposal studied by ANDRA, (french national radioactive waste management agency) is presented. Some uniaxial and triaxial compression tests with unloading-reloading cycles were realised on samples from three different depths. Important plastic strains associated to directional degradation of elastic properties show that the two principles strain mechanisms are plasticity and induced anisotropic damage. At microscopic scale, it is related to sliding of clay sheets and oriented microcracks. The influence of mineralogy is that brittle behaviour is more important with calcite while it decreases with clay. (authors)

  12. Conception d'un controleur actif pour le retard de la transition de l'ecoulement laminaire au turbulent sur une aile a geometrie du profil variable dans le tunnel a vent

    Science.gov (United States)

    Popov, Andrei Vladimir

    The aerospace industry is motivated to reduce fuel consumption in large transport aircraft, mainly through drag reduction. The main objective of the global project is the development of an active control system of wing airfoil geometry during flight in order to allow drag reduction. Drag reduction on a wing can be achieved through modifications in the laminar-to-turbulent flow transition point position, which should be situated as close as possible to the trailing edge of the airfoil wing. As the transition point plays a crucial part in this project, this work focuses on the control of its position on the airfoil, as an effect of controlling the deflection of a morphing wing airfoil equipped with a flexible skin. The paper presents the modeling and the experimental testing of the aerodynamic performance of a morphing wing, starting from the design concept phase all the way to the bench and wind tunnel tests phases. Several wind tunnel test runs for various Mach numbers and angles of attack were performed in the 6 x 9 ft2 wind tunnel at the Institute for Aerospace Research at the National Research Council Canada. A rectangular finite aspect ratio wing, having a morphing airfoil cross-section due to a flexible skin installed on the upper surface of the wing, was instrumented with Kulite transducers. The Mach number varied from 0.2 to 0.3 and the angle of attack between -1° and 2°. Unsteady pressure signals were recorded and analyzed and a thorough comparison, in terms of mean pressure coefficients and their standard deviations, was performed against theoretical predictions, using the XFoil computational fluid dynamics code. The acquired pressure data was analyzed through custom-made software created with Matlab/Simulink in order to detect the noise magnitude in the surface airflow and to localize the transition point position on the wing upper surface. This signal processing was necessary in order to detect the Tollmien-Schlichting waves responsible for triggering the transition from laminar to turbulent flow. The flexible skin needed to morph its shape through two actuation points in order to obtain an optimized airfoil shape for several flow conditions in the wind tunnel. The two shape memory alloy actuators, having a non-linear behavior, drove the displacement of the two control points of the flexible skin towards the optimized airfoil shape. This thesis presents the methodology used and the results obtained from designing the controller of the two shape memory actuators as well as the methods used for morphing wing control in the wind tunnel tests designed to prove the concept and validity of the system in real time. Keywords: wing, morphing, laminar, turbulent, transition, control, wind tunnel

  13. [NiFe] hydrogenase structural and functional models: new bio-inspired catalysts for hydrogen evolution; Modeles structuraux et fonctionnels du site actif des hydrogenases [NiFe]: de nouveaux catalyseurs bio-inspires pour la production d'hydrogene

    Energy Technology Data Exchange (ETDEWEB)

    Oudart, Y

    2006-09-15

    Hydrogenase enzymes reversibly catalyze the oxidation and production of hydrogen in a range close to the thermodynamic potential. The [NiFe] hydrogenase active site contains an iron-cyano-carbonyl moiety linked to a nickel atom which is in an all sulphur environment. Both the active site originality and the potential development of an hydrogen economy make the synthesis of functional and structural models worthy. To take up this challenge, we have synthesised mononuclear ruthenium models and more importantly, nickel-ruthenium complexes, mimicking some structural features of the [NiFe] hydrogenase active site. Ruthenium is indeed isoelectronic to iron and some of its complexes are well-known to bear hydrides. The compounds described in this study have been well characterised and their activity in proton reduction has been successfully tested. Most of them are able to catalyze this reaction though their electrocatalytic potentials remain much more negative compared to which of platinum. The studied parameters point out the importance of the complexes electron richness, especially of the nickel environment. Furthermore, the proton reduction activity is stable for several hours at good rates. The ruthenium environment seems important for this stability. Altogether, these compounds represent the very first catalytically active [NiFe] hydrogenase models. Important additional results of this study are the synergetic behaviour of the two metals in protons reduction and the evidence of a protonation step as the limiting step of the catalytic cycle. We have also shown that a basic site close to ruthenium improves the electrocatalytic potential of the complexes. (author)

  14. 2749-IJBCS-Article-Alain Yaoitcha

    African Journals Online (AJOL)

    hp

    Le présent travail a pour objectif d'étudier le potentiel d'émission des rejets des souches des arbres coupés pour la production du charbon de bois. L'inventaire des espèces exploitées a été réalisé dans 24 chantiers de production de charbon répartis dans trois Communes du Département des Collines au Bénin. Au.

  15. The analysis of mixtures of ortho and para-hydrogen and the catalytic conversion o.H{sub 2} {yields} p.H{sub 2}; Analyse des melanges d'ortho et para-hydrogenes et conversion catalytique o.H{sub 2} {yields} p.H{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Botter, F; Dirian, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1956-07-01

    'une part a la temperature ambiante, la difference de quelques pour cent entre Ies conductibilites thermique de l'ortbo-hydrogene et du para-hydrogene s'etant averee tres suffisante, et d'autre part par analyse continue avec enregistrement, le gaz etant a pression atmospherique. Occasionnellement, on a experimente un catharometre de type industriel dont l'utilisation permettrait une grande extension de cette methode analytique, qui s'est montre satisfaisant. On a verifie que la reaction de conversion paramagnetique obeissait a une cinetique du premier ordre. Un certain nombre de substances absorbantes ont ete testees, parmi lesquelles les charbons, souvent utilises en laboratoire pour la production de para-hydrogene, se sont reveles les moins actifs. Un catalyseur oxyde de chrome-alumine a ete prepare d'apres les donnees de la litterature; son activite catalytique est tres grande. Par ailleurs quelques observations quant a l'influence des gaz absorbes sur l'activite catalytique sont rapportees; la comparaison avec les resultats tires de la litterature est malaisee en raison de l'incertitude sur la nature physico-chimique des absorbants utilises dans les deux cas. Enfin le rapport contient des donnees bibliographiques relatives au proprietes des deux varietes d'hydrogene, a leur dosage et aux differents mecanismes d'interconversion. (auteur)

  16. A study of some radioprotection apparatuses used in the case of pool reactors; Etude de quelques dispositifs de radioprotection en service aupres des piles piscines

    Energy Technology Data Exchange (ETDEWEB)

    Robien, E de; Choudens, H de; Delpuech, J [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-07-01

    necessite de mesurer avec une bonne precision des doses {gamma} a l'aide d'un appareil autonome a conduit a la realisation d'un dosiinetre {gamma} a scintillateur plastique; d) l'obligation de condamner l'ouverture des portes de certains locaux ou il risque d'y avoir une intensite de rayonnement forte a conduit a realiser un asservissement de l'ouverture de ces portes a l'intensite de rayonnement a l'interieur des locaux; e) les degagements d'iode radioactif ont ete mesures a l'aide de cartouches de charbon actif entourant un scintillateur relie a un monocanal; f) enfin, la commande de chute des barres des piles, en cas d'accident radioactif, a ete assuree par une chaine dont le detecteur est une chambre immergee dans la piscine, ce qui offre, dans le cas particulier des reacteurs piscines a couche chaude, le double avantage de pouvoir 'piloter' la couche chaude et de s'affranchir des rayonnements transitoires apparaissant dans le hall du reacteur au moment du defournement des dispositifs experimentaux. (auteurs)

  17. Caracterisation, modelisation et validation du transfert radiatif d'atmospheres non standard; impact sur les corrections atmospheriques d'images de teledetection

    Science.gov (United States)

    Zidane, Shems

    This study is based on data acquired with an airborne multi-altitude sensor on July 2004 during a nonstandard atmospheric event in the region of Saint-Jean-sur-Richelieu, Quebec. By non-standard atmospheric event we mean an aerosol atmosphere that does not obey the typical monotonic, scale height variation employed in virtually all atmospheric correction codes. The surfaces imaged during this field campaign included a diverse variety of targets : agricultural land, water bodies, urban areas and forests. The multi-altitude approach employed in this campaign allowed us to better understand the altitude dependent influence of the atmosphere over the array of ground targets and thus to better characterize the perturbation induced by a non-standard (smoke) plume. The transformation of the apparent radiance at 3 different altitudes into apparent reflectance and the insertion of the plume optics into an atmospheric correction model permitted an atmospheric correction of the apparent reflectance at the two higher altitudes. The results showed consistency with the apparent validation reflectances derived from the lowest altitude radiances. This approach effectively confirmed the accuracy of our non-standard atmospheric correction approach. This test was particularly relevant at the highest altitude of 3.17 km : the apparent reflectances at this altitude were above most of the plume and therefore represented a good test of our ability to adequately correct for the influence of the perturbation. Standard atmospheric disturbances are obviously taken into account in most atmospheric correction models, but these are based on monotonically decreasing aerosol variations with increasing altitude. When the atmospheric radiation is affected by a plume or a local, non-standard pollution event, one must adapt the existing models to the radiative transfer constraints of the local perturbation and to the reality of the measurable parameters available for ingestion into the model. The main inputs of this study were those normally used in an atmospheric correction : apparent at-sensor radiance and the aerosol optical depth (AOD) acquired using ground-based sunphotometry. The procedure we employed made use of a standard atmospheric correction code (CAM5S, for Canadian Modified 5S, which comes from the 5S radiative transfer model in the visible and near infrared) : however, we also used other parameters and data to adapt and correctly model the special atmospheric situation which affected the multi-altitude images acquired during the St. Jean field campaign. We then developed a modeling protocol for these atmospheric perturbations where auxiliary data was employed to complement our main data-set. This allowed for the development of a robust and simple methodology adapted to this atmospheric situation. The auxiliary data, i.e. meteorological data, LIDAR profiles, various satellite images and sun photometer retrievals of the scattering phase function, were sufficient to accurately model the observed plume in terms of a unusual, vertical distribution. This distribution was transformed into an aerosol optical depth profile that replaced the standard aerosol optical depth profile employed in the CAM5S atmospheric correction model. Based on this model, a comparison between the apparent ground reflectances obtained after atmospheric corrections and validation values of R*(0) obtained from the lowest altitude data showed that the error between the two was less than 0.01 rms. This correction was shown to be a significantly better estimation of the surface reflectance than that obtained using the atmospheric correction model. Significant differences were nevertheless observed in the non-standard solution : these were mainly caused by the difficulties brought about by the acquisition conditions, significant disparities attributable to inconsistencies in the co-sampling / co-registration of different targets from three different altitudes, and possibly modeling errors and / or calibration. There is accordingly room for improvement in our approach to dealing with such conditions. The modeling and forecasting of such a disturbance is explicitly described in this document: our goal in so doing is to permit the establishment of a better protocol for the acquisition of more suitable supporting data. The originality of this study stems from a new approach for incorporating a plume structure into an operational atmospheric correction model and then demonstrating that the approach was a significant improvement over an approach that ignored the perturbations in the vertical profile while employing the correct overall AOD. The profile model we employed was simple and robust but captured sufficient plume detail to achieve significant improvements in atmospheric correction accuracy. The overall process of addressing all the problems encountered in the analysis of our aerosol perturbation helped us to build an appropriate methodology for characterizing such events based on data availability, distributed freely and accessible to the scientific community. This makes our study adaptable and exportable to other types of non-standard atmospheric events. Keywords : non-standard atmospheric perturbation, multi-altitude apparent radiances, smoke plume, Gaussian plume modelization, radiance fit, AOD, CASI

  18. Proposal of a numerical modeling of reactive flows in combustion chambers of turbojet engines; Proposition d`une modelisation numerique des ecoulements reactifs dans les foyers de turboreacteurs

    Energy Technology Data Exchange (ETDEWEB)

    Ravet, F. [Rouen Univ., 76 - Mont-Saint-Aignan (France)]|[SNECMA, 77 - Moissy-Cramayel (France); Baudoin, Ch.; Schultz, J.L. [SNECMA, 77 - Moissy-Cramayel (France)

    1996-12-31

    Simplifying hypotheses are required when combustion and aerodynamic phenomena are considered simultaneously. In this paper, a turbulent combustion model is proposed, in which the combustion chemistry is reduced to a single reaction. In this way, only two variables are needed to describe the problem and combustion can be characterized by the consumption of one of the two reactive species. In a first step, the instantaneous consumption rate is obtained using the Lagrangian form of the mass fraction equation of the species under consideration, and by considering the equilibrium state only. This state is determined in order to preserve the consistency with results that should be obtained using a complete kinetics scheme. In a second step, the average rate is determined using the instantaneous consumption term and a probabilistic density function. This model was tested on various configurations and in particular on an experimental main chamber and on a reheating chamber. Results indicate that this model could be used to predict temperature levels inside these combustion chambers. Other applications, like the prediction of pollutant species emission can be considered. (J.S.) 12 refs.

  19. Computing broadband accelerograms using kinematic rupture modeling; Generation d'accelerogrammes synthetiques large-bande par modelisation cinematique de la rupture sismique

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz Paredes, J.A

    2007-05-15

    In order to make the broadband kinematic rupture modeling more realistic with respect to dynamic modeling, physical constraints are added to the rupture parameters. To improve the slip velocity function (SVF) modeling, an evolution of the k{sup -2} source model is proposed, which consists to decompose the slip as a sum of sub-events by band of k. This model yields to SVF close to the solution proposed by Kostrov for a crack, while preserving the spectral characteristics of the radiated wave field, i.e. a w{sup 2} model with spectral amplitudes at high frequency scaled to the coefficient of directivity C{sub d}. To better control the directivity effects, a composite source description is combined with a scaling law defining the extent of the nucleation area for each sub-event. The resulting model allows to reduce the apparent coefficient of directivity to a fraction of C{sub d}, as well as to reproduce the standard deviation of the new empirical attenuation relationships proposed for Japan. To make source models more realistic, a variable rupture velocity in agreement with the physics of the rupture must be considered. The followed approach that is based on an analytical relation between the fracture energy, the slip and the rupture velocity, leads to higher values of the peak ground acceleration in the vicinity of the fault. Finally, to better account for the interaction of the wave field with the geological medium, a semi-empirical methodology is developed combining a composite source model with empirical Green functions, and is applied to the Yamaguchi, M{sub w} 5.9 earthquake. The modeled synthetics reproduce satisfactorily well the observed main characteristics of ground motions. (author)

  20. Modelling of nuclear glasses by classical and ab initio molecular dynamics; Modelisation de verres intervenant dans le conditionnement des dechets radioactifs par dynamiques moleculaires classique et ab initio

    Energy Technology Data Exchange (ETDEWEB)

    Ganster, P

    2004-10-15

    A calcium aluminosilicate glass of molar composition 67 % SiO{sub 2} - 12 % Al{sub 2}O{sub 3} - 21 % CaO was modelled by classical and ab initio molecular dynamics. The size effect study in classical MD shows that the systems of 100 atoms are more ordered than the larger ones. These effects are mainly due to the 3-body terms in the empirical potentials. Nevertheless, these effects are small and the structures generated are in agreement with experimental data. In such kind of glass, we denote an aluminium avoidance and an excess of non bridging oxygens which can be compensated by tri coordinated oxygens. When the dynamics of systems of 100 and 200 atoms is followed by ab initio MD, some local arrangements occurs (bond length, angular distributions). Thus, more realistic vibrational properties are obtained in ab initio MD. The modelling of thin films shows that aluminium atoms extend to the most external part of the surface and they are all tri-coordinated. Calcium atoms are set in the sub layer part of the surface and they produce a depolymerization of the network. In classical MD, tri-coordinated aluminium atoms produce an important electric field above the surface. With non bridging oxygens, they constitute attractive sites for single water molecules. (author)

  1. MODELISATION ET OPTIMISATION DU PROCESSUS DE FORMULATION D’UN CHOCOLAT ET DE GRUYERE UTILISANT UN PROGRAMME FACTORIEL DE TYPE 3

    Directory of Open Access Journals (Sweden)

    N.D MIRON

    2005-06-01

    on a utilisé un programme factoriel de type 33 pour l’élaboration des modèles mathématiques et pour l’optimisation de la qualité du produit. Conséquemment, se peut établir les valeurs optimales des paramètres pour l’obtention des caractéristiques organoleptiques satisfaisantes

  2. Creep of uranium dioxide: bending test and mechanical behaviour; Etude du fluage du dioxyde d'uranium: caracterisation par essais de flexion et modelisation mecanique

    Energy Technology Data Exchange (ETDEWEB)

    Colin, Ch

    2003-09-01

    These PhD work in the frame of Pellet-Cladding Interactions studies, in the fuel assemblies of nuclear plants. Electricite de France (EDF) must well demonstrate and insure the integrity of the cladding. For that purpose, the viscoplastic behaviour of the nuclear fuel has to be known and, if possible, controlled. This PhD work aimed to characterize the creep of uranium dioxide, in conditions of transient power regime. First, a literature survey on mechanical behaviour of UO{sub 2} revealed that the ceramic was essentially studied with compressive tests, and that its creep behaviour is characterized by two domains, depending on the stress level. To estimate the loadings in a fuel pellet, EDF and CEA developed specific global codes. A simulation during a power ramp allowed the order of magnitude of the loadings in the pellet to be determined (temperature, thermal gradients, strains, strain rate...). The stress calculation using a finite element simulation requires the identification of behaviour laws, able to describe the behaviour under small strains, low strain rates, and under tensile stresses. Starting from this observation, three point bending method has been chosen to test the uranium dioxide. As, for representativeness reasons, testing specimens cut in actual fuel pads was required in our study; a ten millimeters span has been used. For this study, a specific three-point testing device has been developed, that can tests specimens up to 2 000 C in a controlled atmosphere (Ar + 5% H{sub 2}). A special care has been taken for the measurement of the deflexion of the sample, which is measured using a laser beam, that allow an accuracy of {+-}2{mu}m to be reached at high temperature. Specimens with 0,5 to 1 mm thickness have been tested using this jig. A Norton's law describe, with respective stress exponent and activation energy values of 1.73 and 540 kJ.mole-1, provided a good description of the stationary creep rate. Then, the mechanical behaviour of the fuel has been modeled. The introduction of internal variables in a law describing a kinematic hardening of the material allowed the first two stages of creep and the recovery phenomena observed during partial un-loadings to be described. The identification was realized by inverse method, coupling an optimization of the parameters with a finite element calculation of the deformation of the bending specimen. The application of this model to simulate a transient power ramp demonstrated that the expected stress relaxation in the fuel does not prevent a radial break of pellet at the end of the power increase. During a maintain at high power, the high temperature in the core of the pellet allows a stress relaxation, especially close from the hollows. That results in a flow of the ceramic, mainly axial, that is clearly confirmed by the observation of used pellets. A final application of our experimental device consisted in testing ion-irradiated specimens, with a 50 {mu}m penetration depth. The small thickness of our samples allows the effect of an irradiation on the creep of UO{sub 2} to be revealed. (author)

  3. Control and diagnosis oriented modelling of the compression ignition engine; Modelisation du moteur a allumage par compression dans la perspective du controle et du diagnostic

    Energy Technology Data Exchange (ETDEWEB)

    Grondin, O

    2004-12-15

    This thesis has described an investigation into the modelling of compression ignition engine for control and diagnosis purpose. The Diesel engine is the most efficient and clean internal combustion engine due to modem electromechanical actuators. However, pollutant emission regulations are much more stricter, thus, these complex systems need sophisticated and efficient control algorithms to reach very low emission levels. For this task, engine models are required at each step of the control system development: control laws synthesis, simulation and validation. The system under study is a six cylinder direct injection Diesel engine fitted with a turbocharger. The model of this system is based on physical laws for some parts of the engine such as cylinders, manifolds, turbocharger and crank-slider system. In order to reduce computing time we choose to model heat transfer and heat release during combustion using simple empirical correlations. Resulting model has been implemented in the Matlab-Simulink environment and it can predict variables of interest for control purpose with one degree crank angle resolution. The model has been tested numerically and compared with an industrial engine simulation code with good results. Moreover, model output variables are in good agreement with experimental data recorded on a heavy-duty research engine. The engine model has been embedded on a board providing enough computing performances to perform real-time simulations, this will be helpful for 'hardware-in-the-loop' simulations. Another part of this study is dedicated to the combustion process modelling using a non linear phenomenological model: the NARMAX model. The goal is to predict the in-cylinder pressure evolution using other measurements available on the engine. The NARMAX model parameters have been identified using input-output data carried out from the experimental engine. Such model is well suited for real-time applications compare to numerically cost effective physical models. First results are promising and demonstrate that non linear 'black-box' models can be employed to model the combustion process with the crankshaft speed as main model input. (author)

  4. Radiant heat transfers in turbojet engines. Two applications, three levels of modeling; Transferts radiatifs dans les foyers de turboreacteurs. Deux applications, trois niveaux de modelisation

    Energy Technology Data Exchange (ETDEWEB)

    Schultz, J L; Desaulty, M [SNECMA, Centre de Villaroche, 77 - Moissy-Cramayel (France); Taine, J [Ecole Centrale de Paris, Laboratoire EM2C. CNRS, 92 - Chatenay-Malabry (France)

    1997-12-31

    Several applications linked with the dimensioning of turbojet engines require the use of modeling of radiant heat transfers. Two different applications are presented in this study: the modeling of heat transfers in the main combustion chamber, and modeling of the infrared signature of the post-combustion chamber of a military engine. In the first application, two types of radiant heat transfer modeling are presented: a global modeling based on empirical considerations and used in rapid pre-dimensioning methods, and a modeling based on a grey gases concept and combined to a ray shooting type technique allowing the determination of local radiant heat flux values. In the second application, a specific modeling of the radiant heat flux is used in the framework of a ray shooting method. Each model represents a different level of successive approximations of the radiant heat transfer adapted to flow specificities and to the performance requested. (J.S.) 16 refs.

  5. Finite-elements modeling of radiant heat transfers between mobile surfaces; Modelisation par elements finis de transferts radiatifs entre surfaces mobiles

    Energy Technology Data Exchange (ETDEWEB)

    Daurelle, J V; Cadene, V; Occelli, R [Universite de Provence, 13 - Marseille (France)

    1997-12-31

    In the numerical modeling of thermal industrial problems, radiant heat transfers remain difficult to take into account and require important computer memory and long computing time. These difficulties are enhanced when radiant heat transfers are coupled with finite-elements diffusive heat transfers because finite-elements architecture is complex and requires a lot of memory. In the case of radiant heat transfers along mobile boundaries, the methods must be optimized. The model described in this paper concerns the radiant heat transfers between diffuse grey surfaces. These transfers are coupled with conduction transfers in the limits of the diffusive opaque domain. 2-D and 3-D geometries are analyzed and two configurations of mobile boundaries are considered. In the first configuration, the boundary follows the deformation of the mesh, while in the second, the boundary moves along the fixed mesh. Matter displacement is taken into account in the term of transport of the energy equation, and an appropriate variation of the thermophysical properties of the transition elements between the opaque and transparent media is used. After a description of the introduction of radiative limit conditions in a finite-elements thermal model, the original methods used to optimize calculation time are explained. Two examples of application illustrate the approach used. The first concerns the modeling of radiant heat transfers between fuel rods during a reactor cooling accident, and the second concerns the study of heat transfers inside the air-gap of an electric motor. The method of identification of the mobile surface on the fixed mesh is described. (J.S.) 12 refs.

  6. Modelisation de la dependance de l'espace et du temps dans les etudes d' environnementModelamiento de la dependencia espacial y temporal en estudios ambientales

    Science.gov (United States)

    Stein, Alfred; Sterk, Geert

    This paper analyzes the use of stratification in the modeling of dependence for regionalized variables in space and time. Stratification enables optimal use of available information, and it is used when deterministic, small-scale information is combined with large-scale random variation: on the one hand, the problem of having too few data to reliably estimate statistical parameters may be solved by stratification; on the other hand some variation may be so obvious that it serves as a prerequisite for obtaining any form of stationarity. The paper is illustrated with four case-studies. The first study analyzes optimization of an extant groundwater monitoring network within a catchment of the river Rhine. Stratification in space enabled 5 cm precision of predicted levels at critical locations, something that could not be reached without stratification. The second study analyzed variability in space and time of wind erosion in a field. Erosion by four storms was measured with 21 devices. Use of temporal stratification to overcome lack of spatial data resulted, in one instance, in a decrease of 17 percent in mean absolute error. The third study addressed changes in the soil solution influenced by environmental deposition over a period of six years. Stratification was made in space to enable analysis in the time domain and to obtain spatio-temporal maps. The fourth study used a general space-time model to evaluate the development of root-rot in soybean, caused by naturally occurring pathogens. Predictions were made at unvisited times to estimate the probability of occurrence of root rot. We conclude that use of stratification enhances the utility of space-time statistics for the solution of various environmental and agricultural problems.

  7. A damage model of Zr {alpha} under cyclic loading at 200 degree Celsius; Modelisation de l`endommagement du Zr {alpha} sous chargement cyclique a 200 deg C

    Energy Technology Data Exchange (ETDEWEB)

    Vogel, C.; Drubay, B. [CEA Centre d`Etudes de Saclay, 91 - Gif-sur-Yvette (France). Dept. de Mecanique et de Technologie; Cailletaud, G. [Ecole Nationale Superieure des Mines, 75 - Paris (France); Mottot, M. [CEA Centre d`Etudes de Saclay, 91 - Gif-sur-Yvette (France). Direction des Technologies Avancees

    1994-12-31

    A damage model for anticipating zirconium {alpha} test-piece rupture under cyclic solicitations at 200 degree Celsius is presented. The article is divided into three parts : an experimental approach, the damage model presentation and the application of this model. (O.L.). 10 refs., 7 figs., 4 tabs.

  8. Experimental validation of modelling tools for a PEM fuel cell; Validation experimentale d'outils de modelisation d'une pile a combustible de type PEM

    Energy Technology Data Exchange (ETDEWEB)

    Boillot, M.

    2005-10-15

    In this work, a global view of the phenomena occurring in a PEM fuel cell is given. An original methodology was developed in order to determine the main parameters: thermodynamics, kinetics and transport phenomena. The gas flow in bipolar plates was characterised using experimental determination of residence time distributions and numerical simulations. Kinetics of both electrochemical reactions were analysed feeding the cell by diluted gases. In this part, the diffusion of reactants in the membrane electrodes assembly was taken into account. Finally, the relationship between humidity and electrical performance was investigated and the ohmic resistance of the cell was estimated. (author)

  9. Eulerian numerical simulation of gas-solid flows with several particles species; Modelisation numerique eulerienne des ecoulements gaz-solide avec plusieurs especes de particules

    Energy Technology Data Exchange (ETDEWEB)

    Patino-Palacios, G

    2007-11-15

    The simulation of the multiphase flows is currently an important scientific, industrial and economic challenge. The objective of this work is to improve comprehension via simulations of poly-dispersed flows and contribute the modeling and characterizing of its hydrodynamics. The study of gas-solid systems involves the models that takes account the influence of the particles and the effects of the collisions in the context of the momentum transfer. This kind of study is covered on the framework of this thesis. Simulations achieved with the Saturne-polyphasique-Tlse code, developed by Electricite de France and co-worked with the Institut de Mecanique des Fluides de Toulouse, allowed to confirm the feasibility of approach CFD for the hydrodynamic study of the injectors and dense fluidized beds. The stages of validation concern, on the one hand, the placement of the tool for simulation in its current state to make studies of validation and sensitivity of the models and to compare the numerical results with the experimental data. In addition, the development of new physical models and their establishments in the code Saturne will allow the optimization of the industrial process. To carry out this validation in a satisfactory way, a key simulation is made, in particular a monodisperse injection and the radial force of injection in the case of a poly-disperse flow, as well as the fluidization of a column made up of solid particles. In this last case, one approached three configurations of dense fluidized beds, in order to study the influence of the grid on simulations; then, one simulates the operation of a dense fluidized bed with which one characterizes the segregation between two various species of particles. The study of the injection of the poly-disperse flows presents two configurations; a flow Co-current gas-particle in gas (Case Hishida), and in addition, a poly-phase flow in a configuration of the jet type confined with zones of recirculation and stagnation (case Hercules). Numerical calculations were compared with the experimental data available and showed a satisfactory reproducibility of the hydrodynamic prediction of the multi-phasic flows. (author)

  10. Motor fuel demand analysis - applied modelling in the European union; Modelisation de la demande de carburant appliquee a l`europe

    Energy Technology Data Exchange (ETDEWEB)

    Chorazewiez, S

    1998-01-19

    Motor fuel demand in Europe amounts to almost half of petroleum products consumption and to thirty percent of total final energy consumption. This study considers, Firstly, the energy policies of different European countries and the ways in which the consumption of motor gasoline and automotive gas oil has developed. Secondly it provides an abstract of demand models in the energy sector, illustrating their specific characteristics. Then it proposes an economic model of automotive fuel consumption, showing motor gasoline and automotive gas oil separately over a period of thirty years (1960-1993) for five main countries in the European Union. Finally, forecasts of consumption of gasoline and diesel up to the year 2020 are given for different scenarios. (author) 330 refs.

  11. Modeling of atmospheric pollution at the regional scale: application to the Esquif campaign; Modelisation a l'echelle regionale de la pollution atmospherique: application a la campagne Esquif

    Energy Technology Data Exchange (ETDEWEB)

    Sarrat, C

    2003-06-01

    The Esquif experimental campaign (study and simulation of air quality in Ile-de-France (Paris region, France)) took place between 1998 and 2000 with the aim of better understanding the dynamical and chemical processes leading to atmospheric pollution peaks in Paris. The construction of a rich and diversified database (12 periods of intensive monitoring (PIM)) has been implemented with the aim of improving the existing chemical-transport models in general and air quality forecasting models in particular. In the framework of this study, the data collected during PIM 2 and 6 were used for the validation and analysis of situations of intensive pollution, simulated with the meso-scale numerical meteorological and chemical model Meso-NHC. The validation of both the dynamic fields (temperature and potential temperature, wind, height of the boundary layer) and the chemical fields (mainly O{sub 3}, NO{sub x}, NO{sub y}, PAN, isoprene) of the model allows to discuss some of the parameters of the model such as the initialization, the boundary forcing and the resolution. Then, a study of the dynamical processes allows to analyze the formation and reinforcement of the pollution conditions. Stress is put on the interaction of the regional scale processes with the photochemical pollution events. In this framework, the dynamical-chemical interaction processes are analyzed in detail, in particular when pollution levels are reinforced by the intrusion of residual ozone inside the convective boundary layer, dragged by the turbulence. Also, the impact of the urban hot island and of the urban wind on the redistribution of primary and secondary pollutants are considered. An analysis of the impact of hydrocarbons of biogenic origin on the ozone concentrations with respect to the temperature and to the presence of primary compounds has been performed for the PIM 2 and 6 of the Esquif campaign. (J.S.)

  12. Modelling atmospheric circulations for the study of Alpine valleys pollution; Modelisation des circulations atmospheriques pour l'etude de la pollution des vallees alpines

    Energy Technology Data Exchange (ETDEWEB)

    Brulfert, G

    2004-11-15

    Local weather phenomena observed in alpine valleys frequently lead to the accumulation of emitted anthropogenic airborne species in the low layers of the atmosphere. The development of a numerical model allows reproducing the chemical evolution of air mass during POVA intensive period of observations. In Chamonix and Maurienne valley, computations of photochemical indicators (NO{sub y}, O{sub 3}/NO{sub z}, H{sub 2}O{sub 2}/HNO{sub 3}) prove the ozone regime to be control by volatile organic compounds. Moreover simulation highlighted that the major part of this secondary pollutant is regionally produced. The development of an indicator who localised ozone production sites can help to define abatement scenarios. The chemical mechanism RACM allows describing the evolution of many species. It is possible to conclude that in winter road traffic and heating are the main sources of volatile organic compounds. (author)

  13. Contribution of the ultrasonic simulation to the testing methods qualification process; Contribution de la modelisation ultrasonore au processus de qualification des methodes de controle

    Energy Technology Data Exchange (ETDEWEB)

    Le Ber, L.; Calmon, P. [CEA/Saclay, STA, 91 - Gif-sur-Yvette (France); Abittan, E. [Electricite de France (EDF-GDL), 93 - Saint-Denis (France)

    2001-07-01

    The CEA and EDF have started a study concerning the simulation interest in the qualification of nuclear components control by ultrasonic methods. In this framework, the simulation tools of the CEA, as CIVA, have been tested on real control. The method and the results obtained on some examples are presented. (A.L.B.)

  14. Experimental approach and micro-mechanical modeling of the mechanical behavior of irradiated zirconium alloys; Approche experimentale et modelisation micromecanique du comportement des alliages de zirconium irradies

    Energy Technology Data Exchange (ETDEWEB)

    Onimus, F

    2003-12-01

    Zirconium alloys cladding tubes containing nuclear fuel of the Pressurized Water Reactors constitute the first safety barrier against the dissemination of radioactive elements. Thus, it is essential to predict the mechanical behavior of the material in-reactor conditions. This study aims, on the one hand, to identify and characterize the mechanisms of the plastic deformation of irradiated zirconium alloys and, on the other hand, to propose a micro-mechanical modeling based on these mechanisms. The experimental analysis shows that, for the irradiated material, the plastic deformation occurs by dislocation channeling. For transverse tensile test and internal pressure test this channeling occurs in the basal planes. However, for axial tensile test, the study revealed that the plastic deformation also occurs by channeling but in the prismatic and pyramidal planes. In addition, the study of the macroscopic mechanical behavior, compared to the deformation mechanisms observed by TEM, suggested that the internal stress is higher in the case of irradiated material than in the case of non-irradiated material, because of the very heterogeneous character of the plastic deformation. This analysis led to a coherent interpretation of the mechanical behavior of irradiated materials, in terms of deformation mechanisms. The mechanical behavior of irradiated materials was finally modeled by applying homogenization methods for heterogeneous materials. This model is able to reproduce adequately the mechanical behavior of the irradiated material, in agreement with the TEM observations. (author)

  15. Impacts modeling using the SPH particulate method. Case study; Modelisation d'impacts par la methode particulaire SPH. Etude de cas

    Energy Technology Data Exchange (ETDEWEB)

    Debord, R

    1999-07-01

    The aim of this study is the modeling of the impact of melted metal on the reactor vessel head in the case of a core-meltdown accident. Modeling using the classical finite-element method alone is not sufficient but requires a coupling with particulate methods in order to take into account the behaviour of the corium. After a general introduction about particulate methods, the Nabor and SPH (smoothed particle hydrodynamics) methods are described. Then, the theoretical and numerical reliability of the SPH method is determined using simple cases. In particular, the number of neighbours significantly influences the preciseness of calculations. Also, the mesh of the structure must be adapted to the mesh of the fluid in order to reduce the edge effects. Finally, this study has shown that the values of artificial velocity coefficients used in the simulation of the BERDA test performed by the FZK Karlsruhe (Germany) are not correct. The domain of use of these coefficients was precised during a low speed impact. (J.S.)

  16. Modeling of a tram power network: from the component to the system; Modelisation d'un reseau electrique de tramway: du composant au systeme

    Energy Technology Data Exchange (ETDEWEB)

    Morin, E

    2005-01-15

    The study and the modeling of tram power networks require a system analysis. The use of several power-electronic converters in these networks significantly modifies both their topology and their function. Therefore, modeling methods developed in this thesis differ from traditional approaches, since a global analysis of a system should be linked with the study of its components.To satisfy the demands of the tram domain, this thesis develops modeling methods for transmission lines and transformers. Two levels of analysis are considered. Firstly, the tram power network is evaluated in relation to time. Secondly, an Iterative Harmonic Analysis (IHA) program is developed to compute the spectra of the system accurately. (author)

  17. Characterization and modeling of natural tracers' transfers through the argillites of Tournemire (France); Caracterisation et modelisation des transferts de traceurs naturels dans les argilites de Tournemire

    Energy Technology Data Exchange (ETDEWEB)

    Patriarche, D

    2001-09-13

    The French Institute for Protection and Nuclear Safety (IPSN) is investigating the argillaceous formation of Tournemire (France) as a methodological underground laboratory for conducting research on the feasibility of deep geological repositories for radioactive waste in argilites. Because of the very low water content and hydraulic conductivity of the argilites, the migration through this media should be very low. The fluid flow regime and transport have been studied using natural tracers from the interstitial water. The deuterium and chloride of interstitial water have been chosen for their conservative behavior. After the development of a protocol for the chloride extraction from the water, and tests on the vacuum distillation method for the water extraction from the rock, systematic data acquisition has been performed on the argillaceous sequence of the massif and near the fracture areas. Both chloride and deuterium profiles suggest that transfers are mainly diffusive at the massif scale. But the profiles show an enrichment in delta D and delta {sup 18}O of the interstitial solution in the area of one meter adjacent to a fracture compared to pore water of samples located at further distance. Therefore, these observations are suggesting that a second process could generate specific transfers, at the vicinity of faults. The hypothesis of the molecular diffusion as a dominant process for transport was successfully tested using a transport model, over periods of several tenth of millions years, taking into account geodynamical features of the region (such as tectonic and induced faults), and assuming that some variations of the tracer concentrations at the system boundaries occurred during the major climate-change periods. Even if tracers' transfers are mainly diffusive at the massif scale, they are or should have been affected by a second process causing heterogeneity of concentrations at the vicinity of faults. This process involves either, intrusion of salted solutions or internal transfers due to overpressures. (author)

  18. Kinetics of catalytic reforming with Pt-Sn catalyst; Modelisation cinetique du reformage catalytique sur catalyseur Pt-Sn/Al{sub 2}O{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Cochegrue, H.

    2001-04-01

    Catalytic Reforming is one of the key processes for petrol refining as it produces gasoline with a high octane number and it is a main source of hydrogen. Refiners are asking for more accurate models in order to optimise their plants. An innovative methodology called 'Single Events' is very different from the classical empirical models because it takes into account the various reaction intermediates and reaction pathways. Some hypotheses based on the relative stability of the carbo-cations allow to get a small number of parameters, which are independent of the composition of the feedstock used. The main target of this work was to apply this methodology to the Catalytic Reforming. The single event network had to be first reduced to a late lumped reaction scheme, which incorporates the detailed knowledge of the elementary network while the intermediates and the reaction pathways are reduced: it can be applied now to naphtha feedstock, although the detailed composition is not yet well known. A pilot unit of Catalytic Reforming, which is representative of the industrial processes, was first designed for the kinetic experiments. Experiments with technical heptane were conducted with a fresh catalyst, which was cocked first, and with a used catalyst from a refinery plant. This latter was difficult to use because of its fast deactivation. However, the results obtained allowed to study the influence of the experimental parameters and of the poisoning by iron, and to estimate some of the main kinetic parameters of the model. (author)

  19. Contribution to the modeling and the identification of haptic interfaces; Contribution a la modelisation et a l'identification des interfaces haptiques

    Energy Technology Data Exchange (ETDEWEB)

    Janot, A

    2007-12-15

    This thesis focuses on the modeling and the identification of haptic interfaces using cable drive. An haptic interface is a force feedback device, which enables its user to interact with a virtual world or a remote environment explored by a slave system. It aims at the matching between the forces and displacements given by the user and those applied to virtual world. Usually, haptic interfaces make use of a mechanical actuated structure whose distal link is equipped with a handle. When manipulating this handle to interact with explored world, the user feels the apparent mass, compliance and friction of the interface. This distortion introduced between the operator and the virtual world must be modeled and identified to enhance the design of the interface and develop appropriate control laws. The first approach has been to adapt the modeling and identification methods of rigid and localized flexibilities robots to haptic interfaces. The identification technique makes use of the inverse dynamic model and the linear least squares with the measurements of joint torques and positions. This approach is validated on a single degree of freedom and a three degree of freedom haptic devices. A new identification method needing only torque data is proposed. It is based on a closed loop simulation using the direct dynamic model. The optimal parameters minimize the 2 norms of the error between the actual torque and the simulated torque assuming the same control law and the same tracking trajectory. This non linear least squares problem dramatically is simplified using the inverse model to calculate the simulated torque. This method is validated on the single degree of freedom haptic device and the SCARA robot. (author)

  20. Hybrid meshes and domain decomposition for the modeling of oil reservoirs; Maillages hybrides et decomposition de domaine pour la modelisation des reservoirs petroliers

    Energy Technology Data Exchange (ETDEWEB)

    Gaiffe, St

    2000-03-23

    In this thesis, we are interested in the modeling of fluid flow through porous media with 2-D and 3-D unstructured meshes, and in the use of domain decomposition methods. The behavior of flow through porous media is strongly influenced by heterogeneities: either large-scale lithological discontinuities or quite localized phenomena such as fluid flow in the neighbourhood of wells. In these two typical cases, an accurate consideration of the singularities requires the use of adapted meshes. After having shown the limits of classic meshes we present the future prospects offered by hybrid and flexible meshes. Next, we consider the generalization possibilities of the numerical schemes traditionally used in reservoir simulation and we draw two available approaches: mixed finite elements and U-finite volumes. The investigated phenomena being also characterized by different time-scales, special treatments in terms of time discretization on various parts of the domain are required. We think that the combination of domain decomposition methods with operator splitting techniques may provide a promising approach to obtain high flexibility for a local tune-steps management. Consequently, we develop a new numerical scheme for linear parabolic equations which allows to get a higher flexibility in the local space and time steps management. To conclude, a priori estimates and error estimates on the two variables of interest, namely the pressure and the velocity are proposed. (author)

  1. Quantification of the emissions of the ozone preceding by inverse modelization. Final report; Quantification des emissions des precurseurs de l'ozone par modelisation inverse. Rapport final

    Energy Technology Data Exchange (ETDEWEB)

    Granier, C.; Petron, G. [Institut Pierre Simon Laplace (IPSL), Service d' Aeronomie, 75 - Paris (France); Ciais, Ph.; Bousquet, Ph. [Institut Pierre Simon Laplace (IPSL), Lab. des Sciences du Climat et de l' Environnement, 75 - Paris (France)

    2007-07-01

    In the framework of this work, inverse methods have been developed and applied for two types of applications: climatological observations to optimize the monthly average of the observed compounds; the distribution of the carbon monoxide. The report presents the experimental methodologies, the used simulation and the results. (A.L.B.)

  2. Kinetic modelling of hydro-treatment reactions by study of different chemical groups; Modelisation cinetique des reactions d`hydrotraitement par regroupement en familles chimiques

    Energy Technology Data Exchange (ETDEWEB)

    Bonnardot, J

    1998-11-19

    Hydro-treatment of petroleum shortcuts permits elimination of unwanted components in order to increase combustion in engine and to decrease atmospheric pollution. Hydro-desulfurization (HDS), Hydro-denitrogenation (HDN) and Hydrogenation of aromatics (HDA) of a LCO (Light Cycle Oil)-Type gas oil have been studied using a new pilot at a fixed temperature with a NiMo/Al{sub 2}O{sub 3} catalyst. A hydrodynamic study showed that reactions occurring in the up-flow fixed bed reactor that has been used during the experiments, were governed exclusively by chemical reaction rates and not by diffusion. Through detailed chemical analysis, height chemical groups have been considered: three aromatics groups, one sulfided group, one nitrogenized and NH{sub 3}, H{sub 2}S, H{sub 2}. Two Langmuir-Hinshelwood-type kinetic models with either one or two types of sites have been established. The model with two types of site - one site of hydrogenation and one site of hydrogenolysis - showed a better fit in the modeling of the experimental results. This model enables to forecast the influence of partial pressure of H{sub 2}S and partial pressure of H{sub 2} on hydro-treatment reactions of a LCO-type gas oil. (author) 119 refs.

  3. Modeling of engine hydrodynamics equations on hybrid unstructured meshes; Modelisation des equations de l`hydrodynamique moteur sur maillage non structure hybride

    Energy Technology Data Exchange (ETDEWEB)

    Durand, A

    1996-10-10

    In this thesis, we are interested in the modeling of the compressible Navier-Stokes equations in 2-D moving domains with hybrid meshes. This work, far from being restricted to these equations, could be generalized to any other convection-diffusion system written in conservative vector form. After having described the mathematical equations and elaborated on finite volume (FV) methods, numerical schemes and various meshes, we have selected the Galerkin FV method. This method consists in locating the unknowns at the mesh nodes, then in solving the convective terms by means of VF method - quasi 1-D by edge approximation - and the diffusive terms by means of the finite element (FE) method - P{sub 1} for the triangular and Q{sub 1} for the quadrilateral. The equivalence between the Galerkin FV method and a mass-lumped FE method for temporal terms allows the construction of a new control volume constructed by means of medians. Then, show its interest in comparison to the classical control volume constructed by means of medians. Then first-order in comparison to the classical control volume constructed bu means of medians. Then, the first-order Roe scheme and its extension to second-order by the MUSCL method are detailed Emphasis is laid on two calculations oF the Gradient integral. Numerous numerical tests as well as the comparison with another code validate the approach. In particular, we show that triangular meshes lead to less precise results compared to quadrilateral meshes in certain cases. Afterward, we switch to the dimensionless Navier-Stokes equations and we describe a simplified (Bubnov)-Galerkin FE method in the case of the quadrilaterals. The newly deduced computer code is validated bu the means of a vortex convection-diffusion for different Reynolds numbers. This test shows that only highly viscous flows give rise to equivalent solutions for both meshes. (author)

  4. Modelling porous active layer electrodes of proton exchange membrane fuel cells; Modelisation des couches actives d'electrodes volumiques de piles a combustible a membrane echangeuse de protons

    Energy Technology Data Exchange (ETDEWEB)

    Bultel, Yann

    1997-07-01

    This work focusses on the modeling of mass, charge and heat transfer in the active layers of the volume electrodes of proton exchange membrane fuel cells (PEMFC). A first part describes the structure of fuel cells and the physico-chemical processes taking place at the electrodes. An analysis of the classical models encountered in the literature shows that they all assume that the electro-catalysts is uniformly distributed in a plane or in volume. In a second part, the modeling of mass and charge transport phenomena has been carried out with a numerical calculation software which uses the finite-elements method and which allows to take into consideration the discrete distribution of the catalyst in nano-particulates. The simulations show the limitations of the catalyst use because of the diffusion and ionic ohmic drop both at the electrolyte and particulates scale. In order to improve the modeling of PEMFC fuel cells, the classical models have been modified to consider these local contributions. They require only simple numerical methods, like the finite-differences one. When applied to the oxygen reduction at the cathode or to the hydrogen oxidation at the anode, these models allow to determine the kinetics parameters (exchange current densities and slopes of the Tafel lines) after correction of the active layer diffusion. A modeling of the heat transfers at the active layers scale is proposed. The model takes into account the convective heat transfers between the solid phases and the gas, the electro-osmosis water transfer, and the generation of heat by joule effect and by the electrochemical reactions. Finally, the last chapter presents a study of the reaction mechanisms in the case of porous electrodes using the impedances method. Numerical and analytical models have been developed to calculate the electrode impedances and are applied to the study of oxygen reduction and hydrogen oxidation. (J.S.)

  5. Adsorption of trace elements on a bentonite sample: experimental study and modelling; Retention d'elements trace sur une bentonite: etude experimentale et modelisation

    Energy Technology Data Exchange (ETDEWEB)

    Hurel, Ch

    2002-12-15

    Radioactive waste storage in deep underground is studied in France. The alteration of the radioactive waste can mobilize the elements that can migrate to the geosphere. Clays (bentonite) are investigated as major materials constituting the barriers because of their low permeability and high retention capacity. A thermodynamic surface complexation model, based on the component additivity principle was investigated, in order to predict the adsorption behaviour of pollutants in contact with clay. This principle allows an independent determination of each parameter of the model, limiting the fitting procedure of correlated data, and it allows the use of an adsorption thermodynamic database for a solid. The predictions obtained were in good accordance with experimental data. The model could then be applied successfully in performance assessment. (author)

  6. Thermodynamic modeling of LPG combustion in dual-fuel engines; Modelisation thermodynamique de la combustion du GPL dans les moteurs dual-fuel

    Energy Technology Data Exchange (ETDEWEB)

    Bilcan, A.; Le Corre, O.; Tazerout, M. [Ecole des Mines de Nantes, 44 (France); Ramesh, A. [Indian Institute of Technology Madras (India)

    2002-07-01

    Dual-fuel engines are modified diesel engines burning simultaneously two fuels inside the cylinder: a gaseous one, called the primary fuel and a liquid one, called the pilot fuel. The thermal efficiency of the dual-fuel engine and of the diesel engine are comparable; the level of emissions is lower compared to the diesel one. This article presents a new procedure for the combustion modeling in a LPG-diesel dual-fuel engine. The procedures deals with the ignition delay period and with the rate of heat release inside the cylinder. This procedure is validated using experimental data issued front a collaboration with the Indian Institute of Technology from Madras, India. The used engine is a single-cylinder one, air-cooled. The pilot fuel is direct injected inside the cylinder The engine was run at constant load and with different diesel substitutions, i.e. for different air to fuel ratios of the primary fuel-air mixture. The general error of the procedure is below 10%. (authors)

  7. Thermal stability of the French nuclear waste glass - long term behavior modeling; Etude de la stabilite thermique du verre nucleaire. Modelisation de son evolution a long terme

    Energy Technology Data Exchange (ETDEWEB)

    Orlhac, X

    2000-07-01

    The thermal stability of the French nuclear waste glass was investigated experimentally and by modeling to predict its long-term evolution at low temperature. The crystallization mechanisms were analyzed by studying devitrification in the supercooled liquid. Three main crystalline phases were characterized (CaMoO{sub 4}, CeCO{sub 2}, ZnCr{sub 2}O{sub 4}). Their crystallisation was TO 4.24 wt%, due to the low concentration of the constituent elements. The nucleation and growth curves showed that platinoid elements catalysed nucleation but did not affect growth, which was governed by volume diffusion. The criteria of classic nucleation theory were applied to determine the thermodynamic and diffusional activation energies. Viscosity measurements illustrate the analogy between the activation energy of viscous flow and diffusion, indicating control of crystallization by viscous flow phenomena. The combined action of nucleation and growth was assessed by TTT plots, revealing a crystallization equilibrium line that enables the crystallized fractions to be predicted over the long term. The authors show that hetero-genetics catalyze the transformation without modifying the maximum crystallized fraction. A kinetic model was developed to describe devitrification in the glass based on the nucleation and growth curves alone. The authors show that the low-temperature growth exhibits scale behavior (between time and temperature) similar to thermo-rheological simplicity. The analogy between the resulting activation energy and that of the viscosity was used to model growth on the basis of viscosity. After validation with a simplified (BaO{sub 2}SiO{sub 2}) glass, the model was applied to the containment glass. The result indicated that the glass remained completely vitreous after a cooling scenario with the one measured at the glass core. Under isothermal conditions, several million years would be required to reach the maximum theoretical crystallization fraction. (author)

  8. Modeling of turbulent flows in cooling channels of turbo-machineries; Modelisation des ecoulements turbulents dans des canaux de refroidissement de turbomachines

    Energy Technology Data Exchange (ETDEWEB)

    Bidart, A.; Caltagirone, J.P.; Parneix, S. [Laboratoire MASTER-ENSCPB, 33 - Talence (France)

    1997-12-31

    The MASTER laboratory has been involved since several years in the creation and utilization of modeling tools for the prediction of 3-D turbulent flows and heat transfers in turbine blades in order to optimize the cooling systems of turbo-machineries. This paper describes one of the test-cases that has been used for the validation of the `Aquilon` calculation code developed in this aim. Then, the modeling performed with the `Fluent` industrial code in order to evaluate the possible improvements of the Aquilon code, is presented. (J.S.) 5 refs.

  9. Development of a turbulence model for the modeling of a vortex flow; Developpement d`un modele de turbulence pour modeliser un ecoulement vortex

    Energy Technology Data Exchange (ETDEWEB)

    Reinhardt, B.; Duhamel, Ph.; Cordonnier, A. [FCB Centre de Recherches, 59 - Lille (France); Florent, P. [LAMIH/LMFE, 59 - Valenciennes (France)

    1997-12-31

    The cyclones used in cement industry generally have a diameter of 4 to 6 m. However, tests on cyclones bigger than 4 m can hardly be performed and thus, it is important to study the influence of the size of the apparatus on the development of the generated vortex. A study of the structure and characteristics of the suspension inside a cyclone has been carried out. The results of the characterization of two cyclones (400 and 800 mm diameter) running without load are presented first in order to study the vortex behaviour. In parallel with this experimental study, a numerical study has been carried out and a calculation code called CYCLOP has been developed. The code, the equations of the gas flow inside the cyclone and the modifications given to the turbulent model are presented. (J.S.) 4 refs.

  10. Modeling of a tram power network: from the component to the system; Modelisation d'un reseau electrique de tramway: du composant au systeme

    Energy Technology Data Exchange (ETDEWEB)

    Morin, E.

    2005-01-15

    The study and the modeling of tram power networks require a system analysis. The use of several power-electronic converters in these networks significantly modifies both their topology and their function. Therefore, modeling methods developed in this thesis differ from traditional approaches, since a global analysis of a system should be linked with the study of its components.To satisfy the demands of the tram domain, this thesis develops modeling methods for transmission lines and transformers. Two levels of analysis are considered. Firstly, the tram power network is evaluated in relation to time. Secondly, an Iterative Harmonic Analysis (IHA) program is developed to compute the spectra of the system accurately. (author)

  11. Producción y modelamiento de gliceril-ésteres como plastificantes para PVC / Production et modelisation de glycerol-esters comme plastifiants pour le PVC

    OpenAIRE

    Suárez Palacios, Oscar Yesid

    2011-01-01

    El aumento en la producción mundial de glicerina, debido al crecimiento en el uso de biodiesel, y la tendencia a reemplazar los plastificantes derivados del anhídrido ftálico en la industria del PVC, por la toxicidad de dichas sustancias, motivaron la investigación de la plastificación del PVC con gliceril-ésteres derivados de ácidos carboxílicos de cadena corta (C3 - C8) y aromáticos. En este estudio se aplicó una metodología de diseño de producto para abordar la solución a las problemáticas...

  12. Modeling and numerical analysis of non-equilibrium two-phase flows; Modelisation et analyse numerique des ecoulements diphasiques en desequilibre

    Energy Technology Data Exchange (ETDEWEB)

    Rascle, P.; El Amine, K. [Electricite de France (EDF), Direction des Etudes et Recherches, 92 - Clamart (France)

    1997-12-31

    We are interested in the numerical approximation of two-fluid models of nonequilibrium two-phase flows described by six balance equations. We introduce an original splitting technique of the system of equations. This technique is derived in a way such that single phase Riemann solvers may be used: moreover, it allows a straightforward extension to various and detailed exchange source terms. The properties of the fluids are first approached by state equations of ideal gas type and then extended to real fluids. For the construction of numerical schemes , the hyperbolicity of the full system is not necessary. When based on suitable kinetic unwind schemes, the algorithm can compute flow regimes evolving from mixture to single phase flows and vice versa. The whole scheme preserves the physical features of all the variables which remain in the set of physical states. Several stiff numerical tests, such as phase separation and phase transition are displayed in order to highlight the efficiency of the proposed method. The document is a PhD thesis divided in 6 chapters and two annexes. They are entitled: 1. - Introduction (in French), 2. - Two-phase flow, modelling and hyperbolicity (in French), 3. - A numerical method using upwind schemes for the resolution of two-phase flows without exchange terms (in English), 4. - A numerical scheme for one-phase flow of real fluids (in English), 5. - An upwind numerical for non-equilibrium two-phase flows (in English), 6. - The treatment of boundary conditions (in English), A.1. The Perthame scheme (in English) and A.2. The Roe scheme (in English). 136 refs. This document represents a PhD thesis in the speciality Applied Mathematics presented par Khalid El Amine to the Universite Paris 6.

  13. Aqueous corrosion of borosilicate glasses: experiments, modeling and Monte-Carlo simulations; Alteration par l'eau des verres borosilicates: experiences, modelisation et simulations Monte-Carlo

    Energy Technology Data Exchange (ETDEWEB)

    Ledieu, A

    2004-10-01

    This work is concerned with the corrosion of borosilicate glasses with variable oxide contents. The originality of this study is the complementary use of experiments and numerical simulations. This study is expected to contribute to a better understanding of the corrosion of nuclear waste confinement glasses. First, the corrosion of glasses containing only silicon, boron and sodium oxides has been studied. The kinetics of leaching show that the rate of leaching and the final degree of corrosion sharply depend on the boron content through a percolation mechanism. For some glass contents and some conditions of leaching, the layer which appears at the glass surface stops the release of soluble species (boron and sodium). This altered layer (also called the gel layer) has been characterized with nuclear magnetic resonance (NMR) and small angle X-ray scattering (SAXS) techniques. Second, additional elements have been included in the glass composition. It appears that calcium, zirconium or aluminum oxides strongly modify the final degree of corrosion so that the percolation properties of the boron sub-network is no more a sufficient explanation to account for the behavior of these glasses. Meanwhile, we have developed a theoretical model, based on the dissolution and the reprecipitation of the silicon. Kinetic Monte Carlo simulations have been used in order to test several concepts such as the boron percolation, the local reactivity of weakly soluble elements and the restructuring of the gel layer. This model has been fully validated by comparison with the results on the three oxide glasses. Then, it has been used as a comprehensive tool to investigate the paradoxical behavior of the aluminum and zirconium glasses: although these elements slow down the corrosion kinetics, they lead to a deeper final degree of corrosion. The main contribution of this work is that the final degree of corrosion of borosilicate glasses results from the competition of two opposite mechanisms : the rapid extraction of the soluble species and the reconstruction of the passivating altered layer. (author)

  14. Experimental and theoretical study of phase transitions under ball milling; Etude experimentale et modelisation des changements de phases sous broyage a haute energie

    Energy Technology Data Exchange (ETDEWEB)

    Pochet, P

    1998-12-31

    The aim of this work was to determine how phase transition s under ball-milling depend on the milling conditions and to find out if one can rationalize such transitions with the theory of driven alloys. We have chosen two phase transitions: the order-disorder transition in Fe Al and the precipitation-dissolution NiGe. In the case of Fe Al we have found that the steady-state long range order parameter achieved under ball milling intensity; moreover the same degree of order is achieved starting from an ordered alloy or a disordered solid solution. On the way to fully disordered state the degree of order either decreases monotonically or goes through a short lived transient state. This behaviour is reminiscent of a first order transition while the equilibrium transition is second order. All the above features are well reproduced by a simple model of driven alloys, which was originally build for alloys under irradiation. The stationary degree of order results of two competitive atomic jump mechanisms: the forced displacements induced by the shearing of the grains, and the thermally activated jumps caused by vacancies migrations. Finally we have performed atomistic simulations with a Monte Carlo kinetic algorithm, which revealed the role of the fluctuations in the intensity of the forcing. Moreover we have shown that specific atomistic mechanisms are active in a dilute NiGe solid solution which might lead to ball milling induced precipitation in under-saturated solid solution. (author). 149 refs.

  15. Water leaching of borosilicate glasses: experiments, modeling and Monte Carlo simulations; Alteration par l'eau des verres borosilicates: experiences, modelisation et simulations Monte Carlo

    Energy Technology Data Exchange (ETDEWEB)

    Ledieu, A

    2004-10-15

    This work is concerned with the corrosion of borosilicate glasses with variable oxide contents. The originality of this study is the complementary use of experiments and numerical simulations. This study is expected to contribute to a better understanding of the corrosion of nuclear waste confinement glasses. First, the corrosion of glasses containing only silicon, boron and sodium oxides has been studied. The kinetics of leaching show that the rate of leaching and the final degree of corrosion sharply depend on the boron content through a percolation mechanism. For some glass contents and some conditions of leaching, the layer which appears at the glass surface stops the release of soluble species (boron and sodium). This altered layer (also called the gel layer) has been characterized with nuclear magnetic resonance (NMR) and small angle X-ray scattering (SAXS) techniques. Second, additional elements have been included in the glass composition. It appears that calcium, zirconium or aluminum oxides strongly modify the final degree of corrosion so that the percolation properties of the boron sub-network is no more a sufficient explanation to account for the behavior of these glasses. Meanwhile, we have developed a theoretical model, based on the dissolution and the reprecipitation of the silicon. Kinetic Monte Carlo simulations have been used in order to test several concepts such as the boron percolation, the local reactivity of weakly soluble elements and the restructuring of the gel layer. This model has been fully validated by comparison with the results on the three oxide glasses. Then, it has been used as a comprehensive tool to investigate the paradoxical behavior of the aluminum and zirconium glasses: although these elements slow down the corrosion kinetics, they lead to a deeper final degree of corrosion. The main contribution of this work is that the final degree of corrosion of borosilicate glasses results from the competition of two opposite mechanisms : the rapid extraction of the soluble species and the reconstruction of the passivating altered layer. (author)

  16. Turbulent precipitation of uranium oxalate in a vortex reactor - experimental study and modelling; Precipitation turbulente d'oxalate d'uranium en reacteur vortex - etude experimentale et modelisation

    Energy Technology Data Exchange (ETDEWEB)

    Sommer de Gelicourt, Y

    2004-03-15

    Industrial oxalic precipitation processed in an un-baffled magnetically stirred tank, the Vortex Reactor, has been studied with uranium simulating plutonium. Modelling precipitation requires a mixing model for the continuous liquid phase and the solution of population balance for the dispersed solid phase. Being chemical reaction influenced by the degree of mixing at molecular scale, that commercial CFD code does not resolve, a sub-grid scale model has been introduced: the finite mode probability density functions, and coupled with a model for the liquid energy spectrum. Evolution of the dispersed phase has been resolved by the quadrature method of moments, first used here with experimental nucleation and growth kinetics, and an aggregation kernel based on local shear rate. The promising abilities of this local approach, without any fitting constant, are strengthened by the similarity between experimental results and simulations. (author)

  17. Systemic model for the aid for operating of the reactor Siloe; Modelisation systeme pour l`aide a l`exploitation du reacteur de recherche Siloe

    Energy Technology Data Exchange (ETDEWEB)

    Royer, J.C.; Moulin, V.; Monge, F. [CEA Centre d`Etudes de Grenoble, 38 (France). Direction des Reacteurs Nucleaires; Baradel, C. [ITMI APTOR, 38 - Meylan (France)

    1995-12-31

    The Service of the Reactor Siloe (CEA/DRN/DRE/SRS), fully aware of the abilities and knowledge of his teams in the field of research reactor operating, has undertaken a project of knowledge engineering in this domain. The following aims have been defined: knowledge capitalization for the installation in order to insure its perenniality and valorization, elaboration of a project for the aid of the reactor operators. This article deals with the different actions by the SRS to reach the aims: realization of a technical model for the operation of the Siloe reactor, development of a knowledge-based system for the aid for operating. These actions based on a knowledge engineering methodology, SAGACE, and using industrial tools will lead to an amelioration of the security and the operating of the Siloe reactor. (authors). 13 refs., 7 figs.

  18. Thermal design of horizontal tube boilers. Numerical and experimental investigation; Modelisation thermique de bouilleurs a tubes horizontaux. Etude numerique et validation experimentale

    Energy Technology Data Exchange (ETDEWEB)

    Roser, R.

    1999-11-26

    This work concerns the thermal design of kettle reboilers. Current methods are highly inaccurate, regarded to the correlations for external heat transfer coefficient at one tube scale, as well as to two-phase flow modelling at boiler scale. The aim of this work is to improve these thermal design methods. It contains an experimental investigation with typical operating conditions of such equipment: an hydrocarbon (n-pentane) with low mass flux. This investigation has lead to characterize the local flow pattern through void fraction measurements and, from this, to develop correlations for void fraction, pressure drop and heat transfer coefficient. The approach is original, since the developed correlations are based on the liquid velocity at minimum cross section area between tubes, as variable characterizing the hydrodynamic effects on pressure drop and heat transfer coefficient. These correlations are shown to give much better results than those suggested up to now in the literature, which are empirical transpositions from methods developed for inside tube flows. Furthermore, the numerical code MC3D has been applied using the correlations developed in this work, leading to a modeling of the two-phase flow in the boiler, which is a significant progress compared to current simplified methods. (author)

  19. 3-D modeling of parietal liquid films in internal combustion engines; Modelisation tridimensionnelle des films liquides parietaux dans les moteurs a combustion interne

    Energy Technology Data Exchange (ETDEWEB)

    Foucart, H

    1998-12-11

    To simulate the air-fuel mixing in the intake ports and cylinder of an internal combustion engines, a wall fuel liquid film model has been developed for integration in 3D CFD codes. Phenomena taken into account include wall film formation by an impinging spray without splashing effect, film transport such as governed by mass and momentum equations with hot wall effects, and evaporation considering energy equation with an analytical mass transfer formulation developed here. A continuous-fluid method is used to describe the wall film over a three dimensional complex surface. The basic approximation is that of a laminar incompressible boundary layer; the liquid film equations are written in an integral form and solved by a first-order ALE finite volume scheme; the equation system is closed without coefficient fitting requirements. The model has been implemented in a Multi-Block version of KIVA-II (KMB) and tested against problems having theoretical solutions. Then in a first step, it has been compared to the measurements obtained in a cylindrical pipe reproducing the main characteristics of SI engine intake pipe flow and in a second step, it has been compared to the Xiong experiment concerning the film evaporation on a hot wall. The film behaviour is satisfactory reproduced by the computations for a set of operating conditions. Finally, engine calculations were conducted showing the importance of including a liquid film model for the simulations. (author) 54 refs.

  20. Long term modelling in a second rank world: application to climate policies; Modeliser le long terme dans un monde de second rang: application aux politiques climatiques

    Energy Technology Data Exchange (ETDEWEB)

    Crassous, R

    2008-11-15

    This research aims at the identification of the dissatisfaction reasons with respect to the existing climate models, at the design of an innovating modelling architecture which would respond to these dissatisfactions, and at proposing climate policy assessment pathways. The authors gives a critique assessment of the modelling activity within the field of climate policies, outlines the fact that the large number and the scattering of existing long term scenarios hides a weak control of uncertainties and of the inner consistency of the produced paths, as well as the very low number of modelling paradigms. After a deepened analysis of modelling practices, the author presents the IMACLIM-R modelling architecture which is presented on a world scale and includes 12 areas and 12 sectors, and allows the simulation of evolutions by 2050, and even 2100, with a one-year time step. The author describes a scenario without any climate policy, highlights reassessment possibilities for economical trajectories which would allow greenhouse gas concentration stabilisation on a long term basis through the application of IMACLIM-R innovations. He outlines adjustment and refinement possibilities for climate policies which would robustly limit the transition cost risks.

  1. Modelling of the ultrasonic inspection of steel tubes with longitudinal defects; Modelisation du controle ultrasonore de tubes d`acier presentant des defauts de type ``entaille longitudinale``

    Energy Technology Data Exchange (ETDEWEB)

    Mephane, M

    1998-12-31

    A model has been developed in order to simulate the ultrasonic inspection of steel tubes in the Vallourec control configuration. The model permits to simulate the control of steel tubes showing longitudinal defects located near the internal or external surface of tubes which appear during the rolling process. To detect this kind of defect, the probe is placed in an incident place perpendicular to the tube`s axis. The probe is in front of the external surface of the tube. The main characteristics of the model is to assume that the field radiated in the material does not depend on the probe`s position. This assumption permits to treat separately the field retracted in the material and the interaction between the defect and the ultrasonic beam. The focal plane is located in the material, so the plane waves approximation is applied where the waves front are assumed plane and parallel. The parallel refracted beam becomes divergent after reflection on the internal surface of tube. To treat the beam divergence, an amplitude weighting coefficient is then calculated by mean of the energy conservation of a tube of rays before and after reflection, following the Snell laws. This model can predict the edge diffraction echoes, the echoes issued from the corner effect, and also the mode conversion echoes. It has been validated on artificial notches, and on some natural defects. A comparison between experimental and modelling results shows a good agreement. (author) 39 refs.

  2. Radiant heat transfers in turbojet engines. Two applications, three levels of modeling; Transferts radiatifs dans les foyers de turboreacteurs. Deux applications, trois niveaux de modelisation

    Energy Technology Data Exchange (ETDEWEB)

    Schultz, J.L.; Desaulty, M. [SNECMA, Centre de Villaroche, 77 - Moissy-Cramayel (France); Taine, J. [Ecole Centrale de Paris, Laboratoire EM2C. CNRS, 92 - Chatenay-Malabry (France)

    1996-12-31

    Several applications linked with the dimensioning of turbojet engines require the use of modeling of radiant heat transfers. Two different applications are presented in this study: the modeling of heat transfers in the main combustion chamber, and modeling of the infrared signature of the post-combustion chamber of a military engine. In the first application, two types of radiant heat transfer modeling are presented: a global modeling based on empirical considerations and used in rapid pre-dimensioning methods, and a modeling based on a grey gases concept and combined to a ray shooting type technique allowing the determination of local radiant heat flux values. In the second application, a specific modeling of the radiant heat flux is used in the framework of a ray shooting method. Each model represents a different level of successive approximations of the radiant heat transfer adapted to flow specificities and to the performance requested. (J.S.) 16 refs.

  3. Soil-fluid interaction modeling in cross-well seismic experience; Modelisation du couplage sol-fluide pour la sismique entre puits

    Energy Technology Data Exchange (ETDEWEB)

    Baroni, A.

    1996-11-20

    Simulation of a cross-well experience is difficult, due to the generation of guided waves in the source containing well and in the receiver containing well. A hybrid sub-structural technique is proposed for the experience modelling, where the two holes are independently considered, using analytical and numerical approaches. The unknown quantity of the global problem, describing the global interaction between all the domains, is the stress vector applied on all the interfaces; this problem requires the solution of local problems describing local equilibrium in each domain. The boundary integral equation method in elastic domains, and a variational formulation in fluid domains, are used, assuming the existence of the zeroth guided mode, known as tube wave, at the fluid-solid interface

  4. Finite-elements modeling of radiant heat transfers between mobile surfaces; Modelisation par elements finis de transferts radiatifs entre surfaces mobiles

    Energy Technology Data Exchange (ETDEWEB)

    Daurelle, J.V.; Cadene, V.; Occelli, R. [Universite de Provence, 13 - Marseille (France)

    1996-12-31

    In the numerical modeling of thermal industrial problems, radiant heat transfers remain difficult to take into account and require important computer memory and long computing time. These difficulties are enhanced when radiant heat transfers are coupled with finite-elements diffusive heat transfers because finite-elements architecture is complex and requires a lot of memory. In the case of radiant heat transfers along mobile boundaries, the methods must be optimized. The model described in this paper concerns the radiant heat transfers between diffuse grey surfaces. These transfers are coupled with conduction transfers in the limits of the diffusive opaque domain. 2-D and 3-D geometries are analyzed and two configurations of mobile boundaries are considered. In the first configuration, the boundary follows the deformation of the mesh, while in the second, the boundary moves along the fixed mesh. Matter displacement is taken into account in the term of transport of the energy equation, and an appropriate variation of the thermophysical properties of the transition elements between the opaque and transparent media is used. After a description of the introduction of radiative limit conditions in a finite-elements thermal model, the original methods used to optimize calculation time are explained. Two examples of application illustrate the approach used. The first concerns the modeling of radiant heat transfers between fuel rods during a reactor cooling accident, and the second concerns the study of heat transfers inside the air-gap of an electric motor. The method of identification of the mobile surface on the fixed mesh is described. (J.S.) 12 refs.

  5. Environmental Modeling Packages for the MSTDCL TDP: Review and Recommendations (Trousses de Modelisation Environnementale Pour le PDT DCLTCM: Revue et Recommendations)

    Science.gov (United States)

    2009-09-01

    frequency shallow water scenarios, and DRDC has ready access to a well-established PE model ( PECan ). In those spectral areas below 1 kHz, where the PE...Ocean, LaSpezia, Italy , 2002. 26 DRDC Atlantic CR 2009-004 List of acronyms and initialisms ARP Address Resolution Protocol BLUG Bottom...PCs Personnel Computers PE Parabolic Equation PECan PE Model developed by DRDC SPADES/ICE Sensor Performance and Acoustic Detection Evaluation

  6. Developpement energetique par modelisation et intelligence territoriale: Un outil de prise de decision participative pour le developpement durable des projets eoliens

    Science.gov (United States)

    Vazquez Rascon, Maria de Lourdes

    This thesis focuses on the implementation of a participatory and transparent decision making tool about the wind farm projects. This tool is based on an (argumentative) framework that reflects the stakeholder's values systems involved in these projects and it employs two multicriteria methods: the multicriteria decision aide and the participatory geographical information systems, making it possible to represent this value systems by criteria and indicators to be evaluated. The stakeholder's values systems will allow the inclusion of environmental, economic and social-cultural aspects of wind energy projects and, thus, a sustainable development wind projects vision. This vision will be analyzed using the 16 sustainable principles included in the Quebec's Sustainable Development Act. Four specific objectives have been instrumented to favor a logical completion work, and to ensure the development of a successfultool : designing a methodology to couple the MCDA and participatory GIS, testing the developed methodology by a case study, making a robustness analysis to address strategic issues and analyzing the strengths, weaknesses, opportunities and threads of the developed methodology. Achieving the first goal allowed us to obtain a decision-making tool called Territorial Intelligence Modeling for Energy Development (TIMED approach). The TIMED approach is visually represented by a figure expressing the idea of a co-construction decision and where ail stakeholders are the focus of this methodology. TIMED is composed of four modules: Multi-Criteria decision analysis, participatory geographic Information systems, active involvement of the stakeholders and scientific knowledge/local knowledge. The integration of these four modules allows for the analysis of different implementation scenarios of wind turbines in order to choose the best one based on a participatory and transparent decision-making process that takes into account stakeholders' concerns. The second objective enabled the testing of TIMED in an ex-post experience of a wind farm in operation since 2006. In this test, II people participated representing four stakeholder' categories: the private sector, the public sector, experts and civil society. This test allowed us to analyze the current situation in which wind projects are currently developed in Quebec. The concerns of some stakeholders regarding situations that are not considered in the current context were explored through a third goal. This third objective allowed us to make simulations taking into account the assumptions of strategic levels. Examples of the strategic level are the communication tools used to approach the host community and the park property type. Finally, the fourth objective, a SWOT analysis with the participation of eight experts, allowed us to verify the extent to which TIMED approach succeeded in constructing four fields for participatory decision-making: physical, intellectual, emotional and procedural. From these facts, 116 strengths, 28 weaknesses, 32 constraints and 54 opportunities were identified. Contributions, applications, limitations and extensions of this research are based on giving a participatory decision-making methodology taking into account socio-cultural, environmental and economic variables; making reflection sessions on a wind farm in operation; acquiring MCDA knowledge for participants involved in testing the proposed methodology; taking into account the physical, intellectual, emotional and procedural spaces to al1iculate a participatory decision; using the proposed methodology in renewable energy sources other than wind; the need to an interdisciplinary team for the methodology application; access to quality data; access to information technologies; the right to public participation; the neutrality of experts; the relationships between experts and non-experts; cultural constraints; improvement of designed indicators; the implementation of a Web platform for participatory decision-making and writing a manual on the use of the developed methodology. Keywords: wind farm, multicriteria decision, geographic information systems, TIMED approach, sustainable wind energy projects development, renewable energy, social participation, robustness concern, SWOT analysis.

  7. Characterisation, modelling and control of advanced scenarios in the european tokamak jet; Caracterisation, modelisation et controle des scenarios avances dans le tokamak europeen jet

    Energy Technology Data Exchange (ETDEWEB)

    Tresset, G

    2002-09-26

    The advanced scenarios, developed for less than ten years with the internal transport barriers and the control of current profile, give rise to a 'new deal' for the tokamak as a future thermonuclear controlled fusion reactor. The Joint European Torus (JET) in United Kingdom is presently the most powerful device in terms of fusion power and it has allowed to acquire a great experience in these improved confinement regimes. The reduction of turbulent transport, considered now as closely linked to the shape of current profile optimised for instance by lower hybrid current drive or the self-generated bootstrap current, can be characterised by a dimensionless criterion. Most of useful information related to the transport barriers are thus available. Large database analysis and real time plasma control are envisaged as attractive applications. The so-called 'S'-shaped transport models exhibit some interesting properties in fair agreement with the experiments, while the non-linear multivariate dependencies of thermal diffusivity can be approximated by a neural network, suggesting a new approach for transport investigation and modelling. Finally, the first experimental demonstrations of real time control of internal transport barriers and current profile have been performed on JET. Sophisticated feedback algorithms have been proposed and are being numerically tested to achieve steady-state and efficient plasmas. (author)

  8. Characterisation, modelling and control of advanced scenarios in the european tokamak jet; Caracterisation, modelisation et controle des scenarios avances dans le tokamak europeen jet

    Energy Technology Data Exchange (ETDEWEB)

    Tresset, G

    2002-09-26

    The advanced scenarios, developed for less than ten years with the internal transport barriers and the control of current profile, give rise to a 'new deal' for the tokamak as a future thermonuclear controlled fusion reactor. The Joint European Torus (JET) in United Kingdom is presently the most powerful device in terms of fusion power and it has allowed to acquire a great experience in these improved confinement regimes. The reduction of turbulent transport, considered now as closely linked to the shape of current profile optimised for instance by lower hybrid current drive or the self-generated bootstrap current, can be characterised by a dimensionless criterion. Most of useful information related to the transport barriers are thus available. Large database analysis and real time plasma control are envisaged as attractive applications. The so-called 'S'-shaped transport models exhibit some interesting properties in fair agreement with the experiments, while the non-linear multivariate dependencies of thermal diffusivity can be approximated by a neural network, suggesting a new approach for transport investigation and modelling. Finally, the first experimental demonstrations of real time control of internal transport barriers and current profile have been performed on JET. Sophisticated feedback algorithms have been proposed and are being numerically tested to achieve steady-state and efficient plasmas. (author)

  9. Material characterization and non destructive testing by ultrasounds; modelling, simulation and experimental validation; Caracterisation des materiaux et controle non destructif par ultrasons; modelisation, simulation et validation experimentale

    Energy Technology Data Exchange (ETDEWEB)

    Noroy-Nadal, M H

    2002-06-15

    This memory presents the research concerning the characterization of materials and the Non Destructive Testing (N.D.T) by ultrasonics. The different topics include three steps: modeling, computations and experimental validation. The studied materials concern mainly metals. The memory is divided in four parts. The first one concerns the characterization of materials versus temperature. The determination of the shear modulus G(T) is especially studied for a large temperature range, and around the melting point. The second part is devoted to studies by photothermal devices essentially focused on the modeling of the mechanical displacement and the stress field in coated materials. In this particular field of interest, applications concern either the mechanical characterization of the coating, the defect detection in the structure and finally the evaluation of the coating adhesion. The third section is dedicated to microstructural characterization using acoustic microscopy. The evaluation of crystallographic texture is especially approached, for metallic objects obtained by forming. Before concluding and pointing out some perspectives to this work, the last section concerns the introduction of optimization techniques, applied to the material characterization by acoustic microscopy. (author)

  10. Reduction of thermal models of buildings: improvement of techniques using meteorological influence models; Reduction de modeles thermiques de batiments: amelioration des techniques par modelisation des sollicitations meteorologiques

    Energy Technology Data Exchange (ETDEWEB)

    Dautin, S.

    1997-04-01

    This work concerns the modeling of thermal phenomena inside buildings for the evaluation of energy exploitation costs of thermal installations and for the modeling of thermal and aeraulic transient phenomena. This thesis comprises 7 chapters dealing with: (1) the thermal phenomena inside buildings and the CLIM2000 calculation code, (2) the ETNA and GENEC experimental cells and their modeling, (3) the techniques of model reduction tested (Marshall`s truncature, Michailesco aggregation method and Moore truncature) with their algorithms and their encoding in the MATRED software, (4) the application of model reduction methods to the GENEC and ETNA cells and to a medium size dual-zone building, (5) the modeling of meteorological influences classically applied to buildings (external temperature and solar flux), (6) the analytical expression of these modeled meteorological influences. The last chapter presents the results of these improved methods on the GENEC and ETNA cells and on a lower inertia building. These new methods are compared to classical methods. (J.S.) 69 refs.

  11. Deformable object model and simulation. Application to lung cancer treatment; Modelisation et simulation parametrable d'objets deformables. Application aux traitements des cancers pulmonaires

    Energy Technology Data Exchange (ETDEWEB)

    Baudet, V

    2006-06-15

    Ionising treatment against cancers such as conformal radiotherapy and hadron therapy are set with error margins that take into account statistics of tumour motions, for instance. We are looking for reducing these margins by searching deformable models that would simulate displacements occurring in lungs during a treatment. It must be personalized with the geometry obtained from CT scans of the patient and also it must be parameterized with physiological measures of the patient. In this Ph. D. thesis, we decided to use a mass-spring system to model lungs because of its fast and physically realist deformations obtained in animation. As a starting point, we chose the model proposed by Van Gelder in order to parameterize a mass-spring system with rheological characteristics of an homogeneous, linear elastic isotropic material in two dimensions (2D). However, we tested this model and proved it was false. Hence we did a Lagrangian study in order to obtain a parametric model with rectangular in 2D (cubic in 3D) elements. We also determined the robustness by testing with stretching, inflating, shearing and bending experiments and also by comparing results with other infinite element method. Thus, in this Ph.D. thesis, we explain how to obtain this parametric model, and how it will be linked to physiological data and how accurate it will be. (author)

  12. Models for Aircrew Safety Assessment: Uses, Limitations and Requirements (la Modelisation des conditions de securite des equipages: applications, limitations et cahiers des charges)

    Science.gov (United States)

    1999-08-01

    shipboard monopole an- tenna: effects on near-field, reradiating structures and of whole- body resonance, Eighth Annual Meeting—Abstracts of the Bioe...lectromagnetics Society, 34. 29. Allen, S.J. and Hurt, W.D. (1979) Calorimetric measurement of microwave energy absorption in mice after simultaneous...lethality. A wide range of animal species was studied (from mice to oxen) under free-field explosive and shock tube gener- ated blast waves. The

  13. Reserves' potential of sedimentary basin: modeling and estimation; Potentiel de reserves d'un bassin petrolier: modelisation et estimation

    Energy Technology Data Exchange (ETDEWEB)

    Lepez, V.

    2002-12-01

    The aim of this thesis is to build a statistical model of oil and gas fields' sizes distribution in a given sedimentary basin, for both the fields that exist in:the subsoil and those which have already been discovered. The estimation of all the parameters of the model via estimation of the density of the observations by model selection of piecewise polynomials by penalized maximum likelihood techniques enables to provide estimates of the total number of fields which are yet to be discovered, by class of size. We assume that the set of underground fields' sizes is an i.i.d. sample of unknown population with Levy-Pareto law with unknown parameter. The set of already discovered fields is a sub-sample without replacement from the previous which is 'size-biased'. The associated inclusion probabilities are to be estimated. We prove that the probability density of the observations is the product of the underlying density and of an unknown weighting function representing the sampling bias. An arbitrary partition of the sizes' interval being set (called a model), the analytical solutions of likelihood maximization enables to estimate both the parameter of the underlying Levy-Pareto law and the weighting function, which is assumed to be piecewise constant and based upon the partition. We shall add a monotonousness constraint over the latter, taking into account the fact that the bigger a field, the higher its probability of being discovered. Horvitz-Thompson-like estimators finally give the conclusion. We then allow our partitions to vary inside several classes of models and prove a model selection theorem which aims at selecting the best partition within a class, in terms of both Kuilback and Hellinger risk of the associated estimator. We conclude by simulations and various applications to real data from sedimentary basins of four continents, in order to illustrate theoretical as well as practical aspects of our model. (author)

  14. Modelling, characterization, and development of new photovoltaic devices on thin silicon substrates; Modelisation, caracterisation et realisation de nouvelles structures photovoltaiques sur substrat de silicium mince

    Energy Technology Data Exchange (ETDEWEB)

    Veschetti, Y.

    2005-10-15

    Thermal barrier coatings are used to protect parts from heat. They are generally composed of two layers, one metallic layer providing heat corrosion and oxidation resistance, and one thermally insulating ceramic layer. Two different techniques are industrially used. Plasma spray results in a lamellar structure granting a low thermal conductivity, but with a low thermal expansion compliance. Electron Beam Physical Vapour Deposition generates a columnar structure allowing a better accommodation of the thermal expansion stresses, entailing a improved lifetime of the coating, but with a higher thermal conductivity. The aim of this work is the generation of macro-cracked plasma sprayed coatings made in one thick pass, in order to improve part lifetime. These coatings result from an important through the coating thermal gradient during deposition, entailing such a stress level that macro-cracks are generated. The control of the crack density is possible by adjusting the spray parameters. The coatings exhibit a three-zone structure: lamellae neighbouring the bond coat, a columnar central part resulting from the zirconia liquid bath solidification, and a mixed lamellar columnar zone coming from the piling up of the droplets travelling in the periphery of the particle jet. (author)

  15. Contribution to the modelling of gas-solid reactions and reactors; Contribution a la modelisation des reactions et des reacteurs gaz-solide

    Energy Technology Data Exchange (ETDEWEB)

    Patisson, F

    2005-09-15

    Gas-solid reactions control a great number of major industrial processes involving matter transformation. This dissertation aims at showing that mathematical modelling is a useful tool for both understanding phenomena and optimising processes. First, the physical processes associated with a gas-solid reaction are presented in detail for a single particle, together with the corresponding available kinetic grain models. A second part is devoted to the modelling of multiparticle reactors. Different approaches, notably for coupling grain models and reactor models, are illustrated through various case studies: coal pyrolysis in a rotary kiln, production of uranium tetrafluoride in a moving bed furnace, on-grate incineration of municipal solid wastes, thermogravimetric apparatus, nuclear fuel making, steel-making electric arc furnace. (author)

  16. Simulation of the annihilation emission of galactic positrons; Modelisation de l'emission d'annihilation des positrons Galactiques

    Energy Technology Data Exchange (ETDEWEB)

    Gillard, W

    2008-01-15

    Positrons annihilate in the central region of our Galaxy. This has been known since the detection of a strong emission line centered on an energy of 511 keV in the direction of the Galactic center. This gamma-ray line is emitted during the annihilation of positrons with electrons from the interstellar medium. The spectrometer SPI, onboard the INTEGRAL observatory, performed spatial and spectral analyses of the positron annihilation emission. This thesis presents a study of the Galactic positron annihilation emission based on models of the different interactions undergone by positrons in the interstellar medium. The models are relied on our present knowledge of the properties of the interstellar medium in the Galactic bulge, where most of the positrons annihilate, and of the physics of positrons (production, propagation and annihilation processes). In order to obtain constraints on the positrons sources and physical characteristics of the annihilation medium, we compared the results of the models to measurements provided by the SPI spectrometer. (author)

  17. Experimental study and modelling of iron ore reduction by hydrogen; Etude experimentale et modelisation de la reduction du minerai de fer par l'hydrogene

    Energy Technology Data Exchange (ETDEWEB)

    Wagner, D

    2008-01-15

    In an effort to find new ways to drastically reduce the CO{sub 2} emissions from the steel industry (ULCOS project), the reduction of iron ore by pure hydrogen in a shaft furnace was investigated. The work consisted of literature, experimental, and modelling studies. The chemical reaction and its kinetics were analysed on the basis of thermogravimetric experiments and physicochemical characterizations of partially reduced samples. A specific kinetic model was designed, which simulates the successive reactions, the different steps of mass transport, and possible iron sintering, at the particle scale. Finally, a 2-dimensional numerical model of a shaft furnace was developed. It depicts the variation of the solid and gas temperatures and compositions throughout the reactor. One original feature of the model is using the law of additive characteristic times for calculating the reaction rates. This allowed us to handle both the particle and the reactor scale, while keeping reasonable calculation time. From the simulation results, the influence of the process parameters was assessed. Optimal operating conditions were concluded, which reveal the efficiency of the hydrogen process. (author)

  18. Developpement de techniques numeriques pour l'estimation, la modelisation et la prediction de proprietes thermodynamiques et structurales de systems metalliques a fort ordonnancement chimique

    Science.gov (United States)

    Harvey, Jean-Philippe

    In this work, the possibility to calculate and evaluate with a high degree of precision the Gibbs energy of complex multiphase equilibria for which chemical ordering is explicitly and simultaneously considered in the thermodynamic description of solid (short range order and long range order) and liquid (short range order) metallic phases is studied. The cluster site approximation (CSA) and the cluster variation method (CVM) are implemented in a new minimization technique of the Gibbs energy of multicomponent and multiphase systems to describe the thermodynamic behaviour of metallic solid solutions showing strong chemical ordering. The modified quasichemical model in the pair approximation (MQMPA) is also implemented in the new minimization algorithm presented in this work to describe the thermodynamic behaviour of metallic liquid solutions. The constrained minimization technique implemented in this work consists of a sequential quadratic programming technique based on an exact Newton’s method (i.e. the use of exact second derivatives in the determination of the Hessian of the objective function) combined to a line search method to identify a direction of sufficient decrease of the merit function. The implementation of a new algorithm to perform the constrained minimization of the Gibbs energy is justified by the difficulty to identify, in specific cases, the correct multiphase assemblage of a system where the thermodynamic behaviour of the equilibrium phases is described by one of the previously quoted models using the FactSage software (ex.: solid_CSA+liquid_MQMPA; solid1_CSA+solid2_CSA). After a rigorous validation of the constrained Gibbs energy minimization algorithm using several assessed binary and ternary systems found in the literature, the CVM and the CSA models used to describe the energetic behaviour of metallic solid solutions present in systems with key industrial applications such as the Cu-Zr and the Al-Zr systems are parameterized using fully consistent thermodynamic an structural data generated from a Monte Carlo (MC) simulator also implemented in the framework of this project. In this MC simulator, the modified embedded atom model in the second nearest neighbour formalism (MEAM-2NN) is used to describe the cohesive energy of each studied structure. A new Al-Zr MEAM-2NN interatomic potential needed to evaluate the cohesive energy of the condensed phases of this system is presented in this work. The thermodynamic integration (TI) method implemented in the MC simulator allows the evaluation of the absolute Gibbs energy of the considered solid or liquid structures. The original implementation of the TI method allowed us to evaluate theoretically for the first time all the thermodynamic mixing contributions (i.e., mixing enthalpy and mixing entropy contributions) of a metallic liquid (Cu-Zr and Al-Zr) and of a solid solution (face-centered cubic (FCC) Al-Zr solid solution) described by the MEAM-2NN. Thermodynamic and structural data obtained from MC and molecular dynamic simulations are then used to parameterize the CVM for the Al-Zr FCC solid solution and the MQMPA for the Al-Zr and the Cu-Zr liquid phase respectively. The extended thermodynamic study of these systems allow the introduction of a new type of configuration-dependent excess parameters in the definition of the thermodynamic function of solid solutions described by the CVM or the CSA. These parameters greatly improve the precision of these thermodynamic models based on experimental evidences found in the literature. A new parameterization approach of the MQMPA model of metallic liquid solutions is presented throughout this work. In this new approach, calculated pair fractions obtained from MC/MD simulations are taken into account as well as configuration-independent volumetric relaxation effects (regular like excess parameters) in order to parameterize precisely the Gibbs energy function of metallic melts. The generation of a complete set of fully consistent thermodynamic, physical and structural data for solid, liquid, and stoichiometric compounds and the subsequent parameterization of their respective thermodynamic model lead to the first description of the complete Al-Zr phase diagram in the range of composition [0 ≤ XZr ≤ 5 / 9] based on theoretical and fully consistent thermodynamic properties. MC and MD simulations are performed for the Al-Zr system to define for the first time the precise thermodynamic behaviour of the amorphous phase for its entire range of composition. Finally, all the thermodynamic models for the liquid phase, the FCC solid solution and the amorphous phase are used to define conditions based on thermodynamic and volumetric considerations that favor the amorphization of Al-Zr alloys.

  19. Analysis of structural heterogeneities on drilled cores: a reservoir modeling oriented methodology; Analyse des heterogeneites structurales sur carottes: une methodologie axee vers la modelisation des reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Cortes, P.; Petit, J.P. [Montpellier-2 Univ., Lab. de Geophysique, Tectonique et Sedimentologie, UMR CNRS 5573, 34 (France); Guy, L. [ELF Aquitaine Production, 64 - Pau (France); Thiry-Bastien, Ph. [Lyon-1 Univ., 69 (France)

    1999-07-01

    The characterization of structural heterogeneities of reservoirs is of prime importance for hydrocarbons recovery. A methodology is presented which allows to compare the dynamic behaviour of fractured reservoirs and the observation of microstructures on drilled cores or surface reservoir analogues. (J.S.)

  20. Creep and damage in argillaceous rocks: microstructural change and phenomenological modeling; Fluage et endommagement des roches argileuses: evolution de la microstructure et modelisation phenomenologique

    Energy Technology Data Exchange (ETDEWEB)

    Fabre, G

    2005-06-15

    The underground radioactive waste disposal far exceeds the period of exploitation of common civil engineering works. These specific projects require to predict the irreversible deformations over a large time scale (several centuries) in order to assess the extension and to forecast the evolution of the EDZ (Excavation Damage Zone) around the cavity. In this study, the viscosity of three sedimentary argillaceous rocks has been studied under different conditions of uniaxial compression: static or cyclic creep tests, monotonic and quasistatic tests, performed across various strata orientations. Argillaceous rocks are studied as a possible host layer for radioactive waste disposals. Indeed, they present some of the physical characteristics and mechanical properties, which are essential for being a natural barrier: low permeability, high creep potential and important holding capacity of radioactive elements. The purpose of the experimental study was to shed some light over the mechanisms governing the development of delayed deformations and damage of argillaceous rocks. It relates three rocks: an argillite from East of France, a Tournemire argillite and a marl from Jurassic Mountains. On atomic scale, viscoplastic deformations are due to irreversible displacements of crystalline defects, called dislocations. The experimental study was also supplemented with observations on thin sections extracted from the argillite and marl samples using a SEM. The aim was to identify the mechanisms responsible for the time-dependent behaviour on a microstructural scale. Analytical simulations of the mechanical behaviour of the three rocks gave parameters used in different viscoplastic models. The best modeling was obtained with the viscoplastic model which takes account of the development of volumetric strains and of the damage anisotropy. (author)

  1. Contribution to the modelling of induction machines by fractional order; Contribution a la modelisation dynamique d'ordre non entier de la machine asynchrone a cage

    Energy Technology Data Exchange (ETDEWEB)

    Canat, S.

    2005-07-15

    Induction machine is most widespread in industry. Its traditional modeling does not take into account the eddy current in the rotor bars which however induce strong variations as well of the resistance as of the resistance of the rotor. This diffusive phenomenon, called 'skin effect' could be modeled by a compact transfer function using fractional derivative (non integer order). This report theoretically analyzes the electromagnetic phenomenon on a single rotor bar before approaching the rotor as a whole. This analysis is confirmed by the results of finite elements calculations of the magnetic field, exploited to identify a fractional order model of the induction machine (identification method of Levenberg-Marquardt). Then, the model is confronted with an identification of experimental results. Finally, an automatic method is carried out to approximate the dynamic model by integer order transfer function on a frequency band. (author)

  2. Multi-physic simulations of irradiation experiments in a technological irradiation reactor; Modelisation pluridisciplinaire d'experiences d'irradiation dans un reacteur d'irradiation technologique

    Energy Technology Data Exchange (ETDEWEB)

    Bonaccorsi, Th

    2007-09-15

    A Material Testing Reactor (MTR) makes it possible to irradiate material samples under intense neutron and photonic fluxes. These experiments are carried out in experimental devices localised in the reactor core or in periphery (reflector). Available physics simulation tools only treat, most of the time, one physics field in a very precise way. Multi-physic simulations of irradiation experiments therefore require a sequential use of several calculation codes and data exchanges between these codes: this corresponds to problems coupling. In order to facilitate multi-physic simulations, this thesis sets up a data model based on data-processing objects, called Technological Entities. This data model is common to all of the physics fields. It permits defining the geometry of an irradiation device in a parametric way and to associate information about materials to it. Numerical simulations are encapsulated into interfaces providing the ability to call specific functionalities with the same command (to initialize data, to launch calculations, to post-treat, to get results,... ). Thus, once encapsulated, numerical simulations can be re-used for various studies. This data model is developed in a SALOME platform component. The first application case made it possible to perform neutronic simulations (OSIRIS reactor and RJH) coupled with fuel behavior simulations. In a next step, thermal hydraulics could also be taken into account. In addition to the improvement of the calculation accuracy due to the physical phenomena coupling, the time spent in the development phase of the simulation is largely reduced and the possibilities of uncertainty treatment are under consideration. (author)

  3. Simplified modeling photo-ionisation of uranium in Silva project; Modelisation simplifiee de la photo-ionisation de l'uranium dans le procede Silva

    Energy Technology Data Exchange (ETDEWEB)

    Bodin, B; Pourre-Brichot, P; Valadier, L [CEA Saclay, Dept. des Procedes d' Enrichissement (DCC/DPE/SPTE), 91 - Gif-sur-Yvette (France)

    2000-07-01

    SILVA is a process which targets {sup 235}U by photo-ionization. It is therefore important to compute the proportion of ionized atoms depending on the properties of the lasers. The interaction between atoms and lasers occurs via the link between the Maxwell and Schroedinger equations. This kind of approach is only feasible for a few simple cases: e.g. wave plane or simple laser profiling. Introducing the characteristics of SILVA, computation time increases substantially (several hundred days per kilogram of vapor). To circumvent this problem, we wrote a program (Jackpot) that treats photo-ionization by a simplified model: kinetics equations. However, various optical components were introduced with absorption factor by wavelength, to account for the effects of optics systems on the trajectory. Instead of seeking the complex wavefunction solutions of the Maxwell-Schroedinger equations, we solve a system where the unknown values are a set of populations. The size of the set depends only on the number of hold points in the process. Recent work shows that we can converge towards the same results as the Maxwell-Schroedinger system if we can fit the cross-sections of the kinetic system correctly. As to the optical aspect, Jackpot can handle diffraction. In this case, it solves the propagation equation of an electric field by a double Fourier transform method. For interactions with mirrors, the new direction of a ray is calculated with Descartes law, applying a numerical phase mask to the electric field. We account for diaphragmation mechanisms as well as the absorption law for each mirror, by a real factor by wavelength. Jackpot is simple to use and can be used to predict experimental results. Jackpot is now a library calling by a script written in Python. Changes are being made for a closer approach to reality (real laser, new photo-ionization model)

  4. Reflector modelization in neutronic and optimization methods applied to fuel loading pattern; Modelisation du reflecteur en neutronique et methodes d`optimisation appliquees aux plans de rechargement

    Energy Technology Data Exchange (ETDEWEB)

    Argaud, J P

    1995-12-01

    I Physical description of P.W.R nuclear core can be handled by multigroup neutronic diffusion model. We are interested in two problems, using the same approach for the optimization aspect. To deal with some differences between calculations and measurements, the question of their reduction is then introduced. A reflector parameters identification from core measurements is then purposed, the reflector being at the present time the less known part of core diffusion model. This approach conducts to study the reflector model, in particular by an analysis of its transport origin. It leads finally to a new model of reflector described by boundary operators using an integral formulation on the core/reflector interface. That is on this new model that a parameter identification formulation of calculations-measurements differences reduction is given, using an adjoint state formulation to minimize errors by a gradient method. Furthermore, nuclear fuel reload of P.W.R core needs an optimal distribution of fuel assemblies, namely a loading pattern. This combinatorial optimization problem is then expressed as a cost function minimization, the cost function describing the power spatial distribution. Various methods (linear programming, simulated annealing,...), used to solve this problem, are detailed, given in particular a practical search example. A new approach is then proposed, using the gradient of the cost function to direct the search in the patterns discrete space. Final results of complete patterns search trials are presented, and compared to those obtained by other methods. In particular the results are obtained very quickly. (author). 81 refs., 55 figs., 5 appends.

  5. Studying uranium migration in natural environment: experimental approach and geochemical modeling; Etude de la migration de l'uranium en milieu naturel: approche experimentale et modelisation geochimique

    Energy Technology Data Exchange (ETDEWEB)

    Phrommavanh, V.

    2008-10-15

    The present study deals with characterizing uranium migration in a limited zone of Le Bouchet site, a former uranium ore treatment facility, which is dismantled and the rehabilitation of which is under process. Some wastes are packed in a rehabilitated disposal nearby, called the Itteville site. In the framework of the monitoring of the deposit environment (air, water, sediment) set by prefectorial decrees, a piezometer (PZPK) located downstream to the latter, has shown total dissolved uranium peaks each winter since the 1990's. PZPK collects both the interstitial water of a calcareous peat formation, between the surface and 3 m, and an alluvial aquifer near 6 m of depth. Firstly, a hydrogeochemical characterization of the site has evidenced the uranium source term, which is present in the peat soil near 0.8 m, hence excluding any leaching from the waste disposal. Actually, a few microparticles of uranium oxide and mixed uranium-thorium oxide have been detected, but they do not represent the major part of the source term. Secondly, water chemistry of the peat soil water and PZPK has been monitored every two months from 2004 to 2007 in order to understand the reasons of the seasonal fluctuations of [U]tot.diss.. Completed with geochemical modeling and a bacterial identification by 16S rDNA sequence analysis, water chemistry data showed an important sulfate-reducing bacterial activity in summertime, leading to reducing conditions and therefore, a total dissolved uranium content limited by the low solubility of uraninite U{sup IV}O{sub 2}(s). In wintertime, the latter bacterial activity being minimal and the effective pluviometry more important, conditions are more oxidant, which favors U(VI), more soluble, notably as the Ca{sub 2}UO{sub 2}(CO{sub 3}){sub 3}(aq) complex, evidenced by TRLFS. Finally, bacterial activity has been reproduced in laboratory in order to better characterize its impact on uranium solubility in the peat soil. Various parameters were tested (C sources, temperature, nutrients) to recreate conditions close and also different to those in situ. 16S rDNA sequence bacterial identifications, throughout the incubation time, have confirmed an increase of sulfate-reducing bacteria proportion. At the same time, water chemistry, as well as geochemical calculations and SEM observations and XANES analyses, have evidenced an decrease of [U]tot.diss., owing to its reduction as UO{sub 2}(s) (certainly as nano-particles). Even though the reaction mechanism could not be determined, that is to say biotic (direct uranium reduction by bacteria) or abiotic (indirect reduction), these experiments have showed that sulfate-reducing bacteria can prevail among a varied indigenous population in conditions close to those in situ. Moreover, the studied calcareous peat contains a significant amount of weddellite (CaC{sub 2}O{sub 4}.2H{sub 2}O(s)), accounting for a permanent input of oxalate ions C{sub 2}O{sub 4}{sup 2-} which can be used as C source in the course of sulfate and/or uranium reduction in the summer. (author)

  6. First principles simulation of the electrochemical behaviour of lithium battery materials; Modelisation du comportement electrochimique de materiaux pour batteries au lithium a partir de calculs de premiers principes

    Energy Technology Data Exchange (ETDEWEB)

    Rocquefelte, X.

    2001-10-01

    The functioning of a positive electrode in a lithium battery is based on the reversible intercalation of lithium. In some cases, such a reaction can lead to important structural modifications and therefore to an amorphization of the material. A theoretical approach is presented here that leads to structural predictions and simulations of electrochemical behaviour of positive electrode materials. In the first part, DFT (Density Functional Theory) formalisms and the respective advantages of FLAPW (Full potential Linearized Augmented Plane Waves) and PP/PW (Pseudopotential / Plane Waves) methods are discussed. In the second part are given some fundamental electrochemistry considerations related to the intercalation process, thermodynamics aspects and relationships with electronic structure. Then, an approach combining experimental data and geometry optimisation of structural hypotheses is given. This approach was first applied to a model compound LiMoS{sub 2}, and has been then generalised to systems of industrial interest such as Li{sub x}V{sub 2}O{sub 5} (0 {<=} x {<=} 3). The simulated X-ray diagrams of the optimised structures for LiMoS{sub 2} and {omega} - Li{sub 3}V{sub 2}O{sub 5} are in good agreement with experimental data. In the case of Li{sub x}V{sub 2}O{sub 5}, the first discharge curves starting from {alpha} - V{sub 2}O{sub 5} and {gamma}' - V{sub 2}O{sub 5} were then successfully simulated. A chemical bond analysis was carried out to help understand the origin of the distortion in LiMoS{sub 2} and the voltage variations in the electrochemical curves of Li{sub x}V{sub 2}O{sub 5}. This study clearly demonstrates that an approach combining first-principle calculations and available experimental data is invaluable in the structure determination of poorly crystallized compounds. Such a procedure contributes to the understanding of the phase transitions induced by the lithium intercalation in vanadium oxide compounds and can really be used in the research of new battery materials. (author)

  7. Development of a self-ignition and combustion model for diesel engines; Modelisation de l`auto-inflammation et de la combustion pour les moteurs diesel

    Energy Technology Data Exchange (ETDEWEB)

    Pires Da Cruz, A.

    1997-12-09

    The work concerns self-ignition and combustion modelling in Diesel engines. Special attention is given to turbulence induced effects. Only gas fuel injection is taken into account. Turbulent mixing is identified as one of the main parameters controlling self-ignition in Diesel engines. However, turbulence effects are often neglected by models currently used in engine calculation codes. A new model based on results obtained by direct numerical simulation (DNS) is proposed. It includes turbulence effects by means of the scalar dissipation rate and presumed pdf of the mixture fraction and a chemical reaction progress variable. The model is validated through several steps. First, its results are compared to DNS in simple mixing and self-ignition cases. Then, its averaged version is integrated into the KIVA2-MB calculation code, where its behavior is tested in a one dimensional version and compared to other formulations. Finally, the model is validated with comparisons to experimental results of methane injection into a high pressure combustion chamber filled with hot air. The combustion chamber allows large optical access and therefore, optical diagnostics can be made. (author) 101 refs.

  8. First principles simulation of the electrochemical behaviour of lithium battery materials; Modelisation du comportement electrochimique de materiaux pour batteries au lithium a partir de calculs de premiers principes

    Energy Technology Data Exchange (ETDEWEB)

    Rocquefelte, X

    2001-10-01

    The functioning of a positive electrode in a lithium battery is based on the reversible intercalation of lithium. In some cases, such a reaction can lead to important structural modifications and therefore to an amorphization of the material. A theoretical approach is presented here that leads to structural predictions and simulations of electrochemical behaviour of positive electrode materials. In the first part, DFT (Density Functional Theory) formalisms and the respective advantages of FLAPW (Full potential Linearized Augmented Plane Waves) and PP/PW (Pseudopotential / Plane Waves) methods are discussed. In the second part are given some fundamental electrochemistry considerations related to the intercalation process, thermodynamics aspects and relationships with electronic structure. Then, an approach combining experimental data and geometry optimisation of structural hypotheses is given. This approach was first applied to a model compound LiMoS{sub 2}, and has been then generalised to systems of industrial interest such as Li{sub x}V{sub 2}O{sub 5} (0 {<=} x {<=} 3). The simulated X-ray diagrams of the optimised structures for LiMoS{sub 2} and {omega} - Li{sub 3}V{sub 2}O{sub 5} are in good agreement with experimental data. In the case of Li{sub x}V{sub 2}O{sub 5}, the first discharge curves starting from {alpha} - V{sub 2}O{sub 5} and {gamma}' - V{sub 2}O{sub 5} were then successfully simulated. A chemical bond analysis was carried out to help understand the origin of the distortion in LiMoS{sub 2} and the voltage variations in the electrochemical curves of Li{sub x}V{sub 2}O{sub 5}. This study clearly demonstrates that an approach combining first-principle calculations and available experimental data is invaluable in the structure determination of poorly crystallized compounds. Such a procedure contributes to the understanding of the phase transitions induced by the lithium intercalation in vanadium oxide compounds and can really be used in the research of new battery materials. (author)

  9. Kinetic modeling of the thermal evolution of crude oils in sedimentary basins; Modelisation cinetique de l'evolution thermique des petroles dans les gisements

    Energy Technology Data Exchange (ETDEWEB)

    Bounaceur, R.

    2001-01-15

    The aim of this work is to obtain a better understanding of the reactions involved in the thermal cracking of crude oil in sedimentary basins, and to study its kinetics as a function of temperature and pressure. We study the kinetics of pyrolysis of alkanes at low temperature, high pressure and high conversion and we propose three methods of reduction of the corresponding mechanisms. Several compounds having an inhibiting or accelerating effect on the rate of decomposition of alkanes were also studied. This research led to the construction of a general kinetic model of 5200 elementary steps representing the pyrolysis of a complex mixture of 52 molecules belonging to various chemical families: 30 linear alkanes (from CH{sub 4} to C{sub 30}H{sub 62}), 10 branched-chain alkanes (including pristane and phytane), 2 naphthenes (propyl-cyclo-pentane and propyl-cyclohexane), tetralin, 1-methyl-indan, 4 aromatics (benzene, toluene, butyl-benzene and decyl-benzene), 3 hetero-atomic compounds (a disulfide, a mercaptan and H{sub 2}S). This model is compared to experimental data coming from the pyrolysis of two oils: one from the North Sea and the other from Pematang. The results obtained show a good agreement between the experimental and simulated values. Then, we simulated the cracking of these two oils by using the following burial scenario: initial temperature of 160 degrees, 50 m per million years (ma) in a constant geothermal gradient of 30 degrees C/km, implying a heating rate of 1.5 degrees C/ma. Under these conditions, our model shows that these two oils start to crack only towards 210-220 degrees C and that their time of half-life corresponds to a temperature around 230-240 degrees C. The model also makes it possible to simulate the evolution of geochemical parameters such as the GOR, the API degree... (author)

  10. Thermo-mechanical behaviour modelling of particle fuels using a multi-scale approach; Modelisation du comportement thermomecanique des combustibles a particules par une approche multi-echelle

    Energy Technology Data Exchange (ETDEWEB)

    Blanc, V.

    2009-12-15

    Particle fuels are made of a few thousand spheres, one millimeter diameter large, compound of uranium oxide coated by confinement layers which are embedded in a graphite matrix to form the fuel element. The aim of this study is to develop a new simulation tool for thermo-mechanical behaviour of those fuels under radiations which is able to predict finely local loadings on the particles. We choose to use the square finite element method, in which two different discretization scales are used: a macroscopic homogeneous structure whose properties in each integration point are computed on a second heterogeneous microstructure, the Representative Volume Element (RVE). First part of this works is concerned by the definition of this RVE. A morphological indicator based in the minimal distance between spheres centers permit to select random sets of microstructures. The elastic macroscopic response of RVE, computed by finite element has been compared to an analytical model. Thermal and mechanical representativeness indicators of local loadings has been built from the particle failure modes. A statistical study of those criteria on a hundred of RVE showed the significance of choose a representative microstructure. In this perspective, a empirical model binding morphological indicator to mechanical indicator has been developed. Second part of the work deals with the two transition scale method which are based on the periodic homogenization. Considering a linear thermal problem with heat source in permanent condition, one showed that the heterogeneity of the heat source involve to use a second order method to localized finely the thermal field. The mechanical non-linear problem has been treats by using the iterative Cast3M algorithm, substituting to integration of the behavior law a finite element computation on the RVE. This algorithm has been validated, and coupled with thermal resolution in order to compute a radiation loading. A computation on a complete fuel element reflect a strong interaction between the two scales, that confirm the interest of a such model to compute the behaviour of those fuels. (author)

  11. Modeling of the re-starting of waxy crude oil flows in pipelines; Modelisation du redemarrage des ecoulements de bruts paraffiniques dans les conduites petrolieres

    Energy Technology Data Exchange (ETDEWEB)

    Vinay, G.

    2005-11-15

    Pipelining crude oils that contain large proportions of paraffins can cause many specific difficulties. These oils, known as waxy crude oils, usually exhibit high 'pour point', where this temperature is higher than the external temperature conditions surrounding the pipeline. During the shutdown, since the temperature decreases in the pipeline, the gel-like structure builds up and the main difficulty concerns the issue of restarting. This PhD attempts to improve waxy crude oil behaviour understanding thanks to experiment, modelling and numerical simulation in order to predict more accurately time and pressure required to restart the flow. Using various contributions to the literature, waxy crude oils are described as viscoplastic, thixotropic and compressible fluid. Strong temperature history dependence plays a prevailing role in the whole shutdown and restart process. Thus, waxy crude oils under flowing conditions correspond to the non-isothermal flow of a viscoplastic material with temperature-dependent rheological properties. Besides, the restart of a waxy crude oil is simulated by the isothermal transient flow of a weakly compressible thixotropic fluid in axisymmetric pipe geometry. We retain the Houska model to describe the thixotropic/viscoplastic feature of the fluid and compressibility is introduced in the continuity equation. The viscoplastic constitutive equation is involved using an augmented Lagrangian method and the resulting equivalent saddle-point problem is solved thanks to an Uzawa-like algorithm. Governing equations are discretized using a Finite Volume method and the convection terms are treated thanks to a TVD (Total Variation Diminishing) scheme. The Lagrangian functional technique usually used for incompressible viscoplastic flows, is adapted to compressible situations. Several numerical results attest the good convergence properties of the proposed transient algorithm. The non-isothermal results highlight the strong sensitivity of the flow pattern to the temperature changes in terms of yielded/un-yielded regions. Then, the combined effects of compressibility and thixotropy have beneficial influence on the restart issue. In fact, a thixotropic flow, not able to start up in compressible situations, could be restarted thanks to compressibility. At last, comparison between numerical and experimental results allows to validate the numerical code. (author)

  12. Modeling of the mechanical behaviour of welded structures: behaviour laws and rupture criteria; Modelisation du comportement mecanique de structures soudees: lois de comportement et criteres de rupture

    Energy Technology Data Exchange (ETDEWEB)

    Paris, T.; Delaplanche, D. [CEA Valduc, Laboratoire Calcul et Simulations, 21120 Is-sur-Tille (France); Saanouni, K. [LASMIS-CNRS-FRE 2719, Universite de Technologie de Troyes BP 2060 - 10010 Troyes - (France)

    2006-07-01

    In the framework of the technological developments carried out in the CEA, the analysis of the mechanical behaviour of the heterogeneous welded bonds Ta/TA6V is a main preoccupation. Indeed, the welding of these two materials which cannot be distinguished by their mechanical and thermal properties induces strong microstructural heterogeneities in the melted zone. In order to characterize the behaviour of the welded joints and to develop a model of mechanical behaviour, a four points bending test on a notched specimen has been developed and implemented. This new test has allowed to obtain a macroscopic response of strength-displacement type but to analyze too more finely, with an optical extensometry and images correlation method, the influence of the heterogeneities on the local deformation of the welded joint. The confrontation of these results to a metallurgical study allows to validate the first conclusions deduced of the mechanical characterization tests and to conclude as for the local mechanisms governing the behaviour and the damage of the melted zone. The mechanical behaviour can be restored by an elasto-viscoplastic model with isotropic and non linear kinematic strain hardening coupled to this damage. The proposed model allows to identify the macroscopic behaviour of the weld bead. (O.M.)

  13. Self-shielding phenomenon modelling in multigroup transport code Apollo-2; Modelisation du phenomene d'autoprotection dans le code de transport multigroupe Apollo 2

    Energy Technology Data Exchange (ETDEWEB)

    Coste-Delclaux, M

    2006-03-15

    This document describes the improvements carried out for modelling the self-shielding phenomenon in the multigroup transport code APOLLO2. They concern the space and energy treatment of the slowing-down equation, the setting up of quadrature formulas to calculate reaction rates, the setting-up of a method that treats directly a resonant mixture and the development of a sub-group method. We validate these improvements either in an elementary or in a global way. Now, we obtain, more accurate multigroup reaction rates and we are able to carry out a reference self-shielding calculation on a very fine multigroup mesh. To end, we draw a conclusion and give some prospects on the remaining work. (author)

  14. Impacts modeling using the SPH particulate method. Case study; Modelisation d'impacts par la methode particulaire SPH. Etude de cas

    Energy Technology Data Exchange (ETDEWEB)

    Debord, R

    1999-07-01

    The aim of this study is the modeling of the impact of melted metal on the reactor vessel head in the case of a core-meltdown accident. Modeling using the classical finite-element method alone is not sufficient but requires a coupling with particulate methods in order to take into account the behaviour of the corium. After a general introduction about particulate methods, the Nabor and SPH (smoothed particle hydrodynamics) methods are described. Then, the theoretical and numerical reliability of the SPH method is determined using simple cases. In particular, the number of neighbours significantly influences the preciseness of calculations. Also, the mesh of the structure must be adapted to the mesh of the fluid in order to reduce the edge effects. Finally, this study has shown that the values of artificial velocity coefficients used in the simulation of the BERDA test performed by the FZK Karlsruhe (Germany) are not correct. The domain of use of these coefficients was precised during a low speed impact. (J.S.)

  15. Dynamic-chemistry-aerosol modelling interaction: the ESCOMPTE 2001 experiment; Modelisation de l'interaction dynamique- chimie - aerosol: campagne ESCOMPTE 2001

    Energy Technology Data Exchange (ETDEWEB)

    Cousin, F

    2004-09-01

    After most pollution studies independently devoted to gases and aerosols, there now appears an urgent need to consider their interactions. In this view, an aerosol module has been implemented in the Meso-NH-C model to simulate two IOPs documented during the ESCOMPTE campaign which took place in the Marseille/Fos-Berre region in June-July 2001. First, modelled dynamic parameters (winds, temperatures, boundary layer thickness) and gaseous chemistry have been validated with measurements issued from the exhaustive ESCOMPTE database. Sensitivity analysis have also been performed using different gaseous emission inventories at various resolution. These simulations have illustrated the deep impact of both synoptic and local dynamics on observed ozone concentrations on June 24 (IOP2b) in the ESCOMPTE domain. Afterwards, the ORISAM aerosol module has been introduced into the Meso-NH-C model. Dynamics, gaseous chemistry and aerosol processes have thus been coupled on-line. The particulate pollution episode on June 24 (IOP2b) has been characterised through a satisfactory comparison, specially from sub-micron particles, between modelling and measurements at different representative stations in the domain. This study, with validation of the particulate emission inventory has also highlighted the need for future improvements, such as further characterisation of organic and inorganic aerosol species and consideration of coarse particles. Aerosol impact on gaseous chemistry has been preliminary approached in view of future development and modification to be given to the Meso-NH-C model. (author)

  16. Modelling atmospheric circulations for the study of Alpine valleys pollution; Modelisation des circulations atmospheriques pour l'etude de la pollution des vallees alpines

    Energy Technology Data Exchange (ETDEWEB)

    Brulfert, G.

    2004-11-15

    Local weather phenomena observed in alpine valleys frequently lead to the accumulation of emitted anthropogenic airborne species in the low layers of the atmosphere. The development of a numerical model allows reproducing the chemical evolution of air mass during POVA intensive period of observations. In Chamonix and Maurienne valley, computations of photochemical indicators (NO{sub y}, O{sub 3}/NO{sub z}, H{sub 2}O{sub 2}/HNO{sub 3}) prove the ozone regime to be control by volatile organic compounds. Moreover simulation highlighted that the major part of this secondary pollutant is regionally produced. The development of an indicator who localised ozone production sites can help to define abatement scenarios. The chemical mechanism RACM allows describing the evolution of many species. It is possible to conclude that in winter road traffic and heating are the main sources of volatile organic compounds. (author)

  17. Report of the seminar modeling of pollutants emissions by road transport; Compte-rendu du seminaire modelisation des emissions de polluants par le transport routier

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    This seminar was organised by A.D.E.M.E. around the following themes: uncertainties and sensitivity analysis of the C.O.P.E.R.T. 3 model (computer programme to calculate emissions from road transport), presentation of studies using the C.O.P.E.R.T. 3 model for the estimation of road transport emissions, the future of the modeling of transport emissions from C.O.P.E.R.T.3 to A.R.T.E.M.I.S. (assessment and reliability of transport emission models and inventory systems). The interventions were as follow: uncertainties and sensitivity analysis of the C.O.P.E.R.T. 3 model, emissions from road transport in the E.S.C.O.M.P.T.E. programme (study of sensitivity), analysis of sensitivity at the level of temporal aggregation of the spatialized traffic (to evaluate the sensitivity of an inventory at the level of temporal aggregation of traffic data on an important geographic area) application in the case of the I.N.T.E.R.R.E.G. project (Alsace), the road transport part of the regional plan for air quality in Bourgogne taking into account the road network, intercomparison of tools and inventory methods of road transport emissions, evolution of the French automobile park until 2005 and new projections, application of C.O.P.E.R.T. 3 to the French context a new version of I.M.P.A.C.T.- A.D.E.M.E., the European project A.R.T.E.M.I.S. structures novelties considered for the road transport emissions modeling. (N.C.)

  18. Modeling of the air pollution on various scales; Modelisation de la pollution atmospherique a differentes echelles. confrontations simulations/mesures pour la preparation d'Escompte 2001

    Energy Technology Data Exchange (ETDEWEB)

    Meleux, F.

    2002-11-15

    On June and July 2001, the campaign ESCOMPTE took place in the Marseille area in southern of France, with the aim of generating a detailed 3-D data base for the study of dynamics and chemistry of high pollution events so as to validate and improve air quality models. Previous to this field experiment, a pre-modelling exercise has been performed to document the dynamic interactions between sea and land breezes and orographic flows over this complex topographical area. This study was carried out using a nesting procedure at local and regional scales using the MESO-NH model (jointly developed by Laboratoire d'Aerologie and Meteofrance at Toulouse). Tracers emitted at various locations in the Marseille and Etang de Berre areas were first followed, then in a second step, full chemistry simulations have been run for two selected periods on June and July 1999, quite similar to the meteorological situations met during the IOP2a and the IOP4 in the 2001 campaign. The performance of the model has been assessed by comparing measured data with simulated data for meteorological parameters and ozone. The general ability of the model to correctly simulate these two situations allows to further study ozone plume developments. In particular, these studies bear upon the relative roles of O{sub 3} transport versus O{sub 3} chemical production, as a function of distance within the plume to anthropogenic emissions and biogenic emissions, together with ozone daily variations and peak values observed at rural sites. After that, ozone chemical production sensitivity is analysed in regards to its precursors. (author)

  19. Marine and fluvial facies modelling at petroleum reservoir scale; Modelisation des heterogeneites lithologiques a l'echelle du reservoir petrolier en milieu marin et fluviatile

    Energy Technology Data Exchange (ETDEWEB)

    Leflon, B.

    2005-10-15

    When modelling a petroleum reservoir, well data are very useful to model properties at a sub-seismic scale. Petrophysical properties like porosity or permeability are linked to the rock-type. Two methods based on well data have been developed to model facies. The first one is used to model marine carbonates deposits. The geometry of sedimentary layers is modelled through a special parameterization of the reservoir similar to Wheeler space. The time parameter is defined along the well paths thanks to correlations. The layer thickness is then extrapolated between wells. A given relationship between facies and bathymetry of sedimentation makes it possible to compute bathymetry along the well paths. Bathymetry is then extrapolated from wells and a reference map using the concept of accommodation. The model created this way is stratigraphically consistent. Facies simulation can then be constrained by the computed bathymetry. The second method describes a novel approach to fluvial reservoirs modelling. The core of the method lies in the association of a fairway with the channels to be simulated. Fairways are positioned so that all data are taken in account; they can be stochastic if unknown or explicitly entered if identified on seismic data. A potential field is defined within the fairway. Specifying a transfer function to map this potential field to thickness results in generating a channel inside the fairway. A residual component is stochastically simulated and added to the potential field creating realistic channel geometries. Conditioning to well data is obtained by applying the inverse transfer function at the data location to derive thickness values that will constrain the simulation of residuals. (author)

  20. Calculation system for physical analysis of boiling water reactors; Modelisation des phenomenes physiques specifiques aux reacteurs a eau bouillante, notamment le couplage neutronique-thermohydraulique

    Energy Technology Data Exchange (ETDEWEB)

    Bouveret, F

    2001-07-01

    Although Boiling Water Reactors generate a quarter of worldwide nuclear electricity, they have been only little studied in France. A certain interest now shows up for these reactors. So, the aim of the work presented here is to contribute to determine a core calculation methodology with CEA (Commissariat a l'Energie Atomique) codes. Vapour production in the reactor core involves great differences in technological options from pressurised water reactor. We analyse main physical phenomena for BWR and offer solutions taking them into account. BWR fuel assembly heterogeneity causes steep thermal flux gradients. The two dimensional collision probability method with exact boundary conditions makes possible to calculate accurately the flux in BWR fuel assemblies using the APOLLO-2 lattice code but induces a very long calculation time. So, we determine a new methodology based on a two-level flux calculation. Void fraction variations in assemblies involve big spectrum changes that we have to consider in core calculation. We suggest to use a void history parameter to generate cross-sections libraries for core calculation. The core calculation code has also to calculate the depletion of main isotopes concentrations. A core calculation associating neutronics and thermal-hydraulic codes lays stress on points we still have to study out. The most important of them is to take into account the control blade in the different calculation stages. (author)

  1. Modeling of an electric arc transferred on a melted glass bath; Modelisation d`un arc electrique transfere sur un bain de verre

    Energy Technology Data Exchange (ETDEWEB)

    Mehlman, G.; Langlois, A. [SGN, 78 - Saint Quentin en Yvelines (France)

    1997-12-31

    The aim of this study is to propose a methodology allowing the simulation of melting processes involving electromagnetic phenomena. This methodology is based on the use of scientific calculation tools currently used elsewhere. The case considered in this study has been defined in collaboration with Electricite de France (EdF) and concerns more particularly an electric arc vitrification process for wastes. Basic data have been determined in order to obtain results representative of the tests performed by EdF with pilot installations. (J.S.)

  2. Wall modeling for the simulation of highly non-isothermal unsteady flows; Modelisation de paroi pour la simulation d'ecoulements instationnaires non-isothermes

    Energy Technology Data Exchange (ETDEWEB)

    Devesa, A

    2006-12-15

    Nuclear industry flows are most of the time characterized by their high Reynolds number, density variations (at low Mach numbers) and a highly unsteady behaviour (low to moderate frequencies). High Reynolds numbers are un-affordable by direct simulation (DNS), and simulations must either be performed by solving averaged equations (RANS), or by solving only the large eddies (LES), both using a wall model. A first investigation of this thesis dealt with the derivation and test of two variable density wall models: an algebraic law (CWM) and a zonal approach dedicated to LES (TBLE-{rho}). These models were validated in quasi-isothermal cases, before being used in academic and industrial non-isothermal flows with satisfactory results. Then, a numerical experiment of pulsed passive scalars was performed by DNS, were two forcing conditions were considered: oscillations are imposed in the outer flow; oscillations come from the wall. Several frequencies and amplitudes of oscillations were taken into account in order to gain insights in unsteady effects in the boundary layer, and to create a database for validating wall models in such context. The temporal behaviour of two wall models (algebraic and zonal wall models) were studied and showed that a zonal model produced better results when used in the simulation of unsteady flows. (author)

  3. Present day engines pollutant emissions: proposed model for refinery bases impact; Emissions de polluants des moteurs actuels: modelisation de l'impact des bases de raffinage

    Energy Technology Data Exchange (ETDEWEB)

    Hochart, N.; Jeuland, N.; Montagne, X. [Institut Francais du Petrole (IFP), Div. Techniques d' Applications Energetiques, 92 - Rueil-Malmaison (France); Raux, S. [Institut Francais du Petrole (IFP), Div. Techniques d' Applications Energetiques, Centre d' Etudes et de Developpement Industriel, Rene Navarre, 69 - Vernaison (France); Belot, G.; Cahill, B. [PSA-Peugiot-Citroen, 92 - La Garenne-Colombes (France); Faucon, R.; Petit, A. [Renault, 91 - Lardy (France); Michon, S. [Renault Trucks Powertrain, 69 - Saint Priest (France)

    2003-07-01

    Air quality improvement, especially in urban areas, is one of the major concerns for the coming years. For this reason, car manufacturers, equipment manufacturers and refiners have explored development issues to comply with increasingly severe anti-pollution requirements. In such a context, the identification of the most promising improvement options is essential. A research program, carried out by IFP (Institut francais du petrole), and supported by the French Ministry of Industry, PSA-Peugeot-Citroen, Renault and RVI (Renault Vehicules Industriels), has been built to study this point. It is based on a 4-year program with different steps focused on new engine technologies which will be available in the next 20 years in order to answer to more and more severe pollutant and CO{sub 2} emissions regulations. This program is divided into three main parts: the first one for Diesel car engines, the second for Diesel truck engines and the third for spark ignition engines. The aim of the work reported here is to characterize the effect of fuel formulation on pollutant emissions and engine tuning for different engine technologies. The originality of this study is to use refinery bases as parameters and not conventional physical or chemical parameters. The tested fuels have been chosen in order to represent the major refinery bases expected to be produced in the near future. These results, expressed with linear correlations between fuel composition and pollutant emissions, will help to give a new orientation to refinery tool. The engines presented in this publication are, for spark ignition engines, an EuroII lean-burn engine (Honda VTEC which equips the Honda Civic) and an EuroIII 1.8 l stoichiometric-running Renault engine which equips the Laguna vehicles, and, for diesel engines, an EuroII Renault Laguna 2.2 l indirect injection diesel engine and an EuroII RVI truck engine. For the fuel formulation, an original approach is proposed: while the classical studies are based on the properties of the fuel, this one is built only on a refinery bases approach. For diesel fuels, six refinery bases (a straight-run diesel fuel, an hydro-cracked diesel fuel, a LCO, a diesel fuel obtained by hydro-conversion of vacuum distillation residue, a kerosene and a diesel fuel issued from a Fischer-Tropsch process) have been selected to produce a fuel matrix which was determined according to an experimental blend design. For gasoline fuels, seven bases have been chosen, which are representative of the batch that will be used in the next years: a fuel from isomerization process (mainly constituted of C{sub 5}/C{sub 6} iso-paraffins), an alkylate (constituted of C{sub 7+} iso-paraffins), a fuel from olefins oligomerization process, a fuel from catalytic cracking process (mainly composed of C{sub 7+} olefins and aromatic compounds), a light reformate (C{sub 7}/C{sub 8} aromatic compounds), an heavy reformate (C{sub 9+} aromatic compounds) and an oxygenated compound (ETBE). For each engine, tests have been run on a steady state bench with variations of some tuning parameters. Vehicle tests with the same engines have also been carried out on the European MVEG cycle, where regulated and unregulated pollutant emissions have been recorded. (authors)

  4. Control and diagnosis oriented modelling of the compression ignition engine; Modelisation du moteur a allumage par compression dans la perspective du controle et du diagnostic

    Energy Technology Data Exchange (ETDEWEB)

    Grondin, O.

    2004-12-15

    This thesis has described an investigation into the modelling of compression ignition engine for control and diagnosis purpose. The Diesel engine is the most efficient and clean internal combustion engine due to modem electromechanical actuators. However, pollutant emission regulations are much more stricter, thus, these complex systems need sophisticated and efficient control algorithms to reach very low emission levels. For this task, engine models are required at each step of the control system development: control laws synthesis, simulation and validation. The system under study is a six cylinder direct injection Diesel engine fitted with a turbocharger. The model of this system is based on physical laws for some parts of the engine such as cylinders, manifolds, turbocharger and crank-slider system. In order to reduce computing time we choose to model heat transfer and heat release during combustion using simple empirical correlations. Resulting model has been implemented in the Matlab-Simulink environment and it can predict variables of interest for control purpose with one degree crank angle resolution. The model has been tested numerically and compared with an industrial engine simulation code with good results. Moreover, model output variables are in good agreement with experimental data recorded on a heavy-duty research engine. The engine model has been embedded on a board providing enough computing performances to perform real-time simulations, this will be helpful for 'hardware-in-the-loop' simulations. Another part of this study is dedicated to the combustion process modelling using a non linear phenomenological model: the NARMAX model. The goal is to predict the in-cylinder pressure evolution using other measurements available on the engine. The NARMAX model parameters have been identified using input-output data carried out from the experimental engine. Such model is well suited for real-time applications compare to numerically cost effective physical models. First results are promising and demonstrate that non linear 'black-box' models can be employed to model the combustion process with the crankshaft speed as main model input. (author)

  5. Numerical simulation of the two-phase flow in Diesel injectors; Modelisation de l'ecoulement diphasique dans les injecteurs diesel

    Energy Technology Data Exchange (ETDEWEB)

    Dumont, N.

    2004-12-15

    Combustion quality in Direct Injection Diesel engine depends strongly on the jet atomization in the combustion chamber. Atomization is due to aerodynamic interaction, but it is also influenced by the liquid flow characteristics at the injector exit. As the phenomena are extremely rapid and they take place in very small geometries, experimental investigations are pretty hard to manage. Consequently, our purpose is to develop a simulation code which has two goals: a better comprehension of the flow in the injector in order to optimize the injector geometry, and the prediction of the flow characteristics at the injector exit, in order to provide boundary conditions to combustion simulation codes. At first, we describe phenomena occurring in the injector and their influence on atomization. Their we make a revue of the two-phase models, defining their validity domains. We present the model that we use, based on a homogeneous flow assumption in each mesh cell, and its implementation in KIVA-MB. We show that a particular attention has been focused on exit boundary conditions: we used non-reflective conditions. Simulations results are then described and validated for a one-hole injector and a multi-hole injector, showing the code possibilities to get a better understanding of the liquid flow in an injector during the whole injection. (author)

  6. Water leaching of borosilicate glasses: experiments, modeling and Monte Carlo simulations; Alteration par l'eau des verres borosilicates: experiences, modelisation et simulations Monte Carlo

    Energy Technology Data Exchange (ETDEWEB)

    Ledieu, A

    2004-10-15

    This work is concerned with the corrosion of borosilicate glasses with variable oxide contents. The originality of this study is the complementary use of experiments and numerical simulations. This study is expected to contribute to a better understanding of the corrosion of nuclear waste confinement glasses. First, the corrosion of glasses containing only silicon, boron and sodium oxides has been studied. The kinetics of leaching show that the rate of leaching and the final degree of corrosion sharply depend on the boron content through a percolation mechanism. For some glass contents and some conditions of leaching, the layer which appears at the glass surface stops the release of soluble species (boron and sodium). This altered layer (also called the gel layer) has been characterized with nuclear magnetic resonance (NMR) and small angle X-ray scattering (SAXS) techniques. Second, additional elements have been included in the glass composition. It appears that calcium, zirconium or aluminum oxides strongly modify the final degree of corrosion so that the percolation properties of the boron sub-network is no more a sufficient explanation to account for the behavior of these glasses. Meanwhile, we have developed a theoretical model, based on the dissolution and the reprecipitation of the silicon. Kinetic Monte Carlo simulations have been used in order to test several concepts such as the boron percolation, the local reactivity of weakly soluble elements and the restructuring of the gel layer. This model has been fully validated by comparison with the results on the three oxide glasses. Then, it has been used as a comprehensive tool to investigate the paradoxical behavior of the aluminum and zirconium glasses: although these elements slow down the corrosion kinetics, they lead to a deeper final degree of corrosion. The main contribution of this work is that the final degree of corrosion of borosilicate glasses results from the competition of two opposite mechanisms : the rapid extraction of the soluble species and the reconstruction of the passivating altered layer. (author)

  7. Aqueous corrosion of borosilicate glasses: experiments, modeling and Monte-Carlo simulations; Alteration par l'eau des verres borosilicates: experiences, modelisation et simulations Monte-Carlo

    Energy Technology Data Exchange (ETDEWEB)

    Ledieu, A

    2004-10-01

    This work is concerned with the corrosion of borosilicate glasses with variable oxide contents. The originality of this study is the complementary use of experiments and numerical simulations. This study is expected to contribute to a better understanding of the corrosion of nuclear waste confinement glasses. First, the corrosion of glasses containing only silicon, boron and sodium oxides has been studied. The kinetics of leaching show that the rate of leaching and the final degree of corrosion sharply depend on the boron content through a percolation mechanism. For some glass contents and some conditions of leaching, the layer which appears at the glass surface stops the release of soluble species (boron and sodium). This altered layer (also called the gel layer) has been characterized with nuclear magnetic resonance (NMR) and small angle X-ray scattering (SAXS) techniques. Second, additional elements have been included in the glass composition. It appears that calcium, zirconium or aluminum oxides strongly modify the final degree of corrosion so that the percolation properties of the boron sub-network is no more a sufficient explanation to account for the behavior of these glasses. Meanwhile, we have developed a theoretical model, based on the dissolution and the reprecipitation of the silicon. Kinetic Monte Carlo simulations have been used in order to test several concepts such as the boron percolation, the local reactivity of weakly soluble elements and the restructuring of the gel layer. This model has been fully validated by comparison with the results on the three oxide glasses. Then, it has been used as a comprehensive tool to investigate the paradoxical behavior of the aluminum and zirconium glasses: although these elements slow down the corrosion kinetics, they lead to a deeper final degree of corrosion. The main contribution of this work is that the final degree of corrosion of borosilicate glasses results from the competition of two opposite mechanisms : the rapid extraction of the soluble species and the reconstruction of the passivating altered layer. (author)

  8. Discrete kinematic modeling of the 3-D deformation of sedimentary basins; Modelisation cinematique discrete de la deformation 3D des bassins sedimentaires

    Energy Technology Data Exchange (ETDEWEB)

    Cornu, T.

    2001-01-01

    The present work deals with three-dimensional deformation of sedimentary basins. The main goal of the work was to propose new ways to study tectonic deformation and to insert it into basin-modeling environment for hydrocarbon migration applications. To handle the complexity of the deformation, the model uses kinematic laws, a discrete approach, and the construction of a code that allows the greatest diversity in the deformation mechanisms we can take into account. The 3-D-volume deformation is obtained through the calculation of the behavior of the neutral surface of each basin layer. The main idea is to deform the neutral surface of each layer with the help of geometrical laws and to use the result to rebuild the volume deformation of the basin. The constitutive algorithm includes three characteristic features. The first one deals with the mathematical operator we use to describe the flexural-slip mechanism which is a combination of the translation of the neutral surface nodes and the rotation of the vertical edges attached to these nodes. This performs the reversibility that was required for the basin modeling. The second one is about. the use of a discrete approach, which gives a better description of the global deformation and offers to locally control volume evolutions. The knowledge of volume variations can become a powerful tool in structural geology analysis and the perfect complement for a field study. The last one concerns the modularity of the developed code. Indeed, the proposed model uses three main mechanisms of deformation. But the architecture of the code allows the insertion of new mechanisms or a better interaction between them. The model has been validated first with 2-D cases, then with 3-D natural cases. They give good results from a qualitative point of view. They also show the capacity of the model to provide a deformation path that is geologically acceptable, and its ability to control the volume variations of the basin through the deformation. (author)

  9. Modelling and Simulation as a Service: New Concepts and Service-Oriented Architectures (Modelisation et simulation en tant que service: Nouveaux concepts et architectures orientes service)

    Science.gov (United States)

    2015-05-01

    mobile phones, tablets, laptops, workstations). • Resource Pooling – Computing resources are pooled to serve multiple consumers using a...service provision via a cloud backend , able to scale in and out on demand, accessed over a secure network by the types of devices typically available at

  10. Contribution to the modeling and the identification of haptic interfaces; Contribution a la modelisation et a l'identification des interfaces haptiques

    Energy Technology Data Exchange (ETDEWEB)

    Janot, A

    2007-12-15

    This thesis focuses on the modeling and the identification of haptic interfaces using cable drive. An haptic interface is a force feedback device, which enables its user to interact with a virtual world or a remote environment explored by a slave system. It aims at the matching between the forces and displacements given by the user and those applied to virtual world. Usually, haptic interfaces make use of a mechanical actuated structure whose distal link is equipped with a handle. When manipulating this handle to interact with explored world, the user feels the apparent mass, compliance and friction of the interface. This distortion introduced between the operator and the virtual world must be modeled and identified to enhance the design of the interface and develop appropriate control laws. The first approach has been to adapt the modeling and identification methods of rigid and localized flexibilities robots to haptic interfaces. The identification technique makes use of the inverse dynamic model and the linear least squares with the measurements of joint torques and positions. This approach is validated on a single degree of freedom and a three degree of freedom haptic devices. A new identification method needing only torque data is proposed. It is based on a closed loop simulation using the direct dynamic model. The optimal parameters minimize the 2 norms of the error between the actual torque and the simulated torque assuming the same control law and the same tracking trajectory. This non linear least squares problem dramatically is simplified using the inverse model to calculate the simulated torque. This method is validated on the single degree of freedom haptic device and the SCARA robot. (author)

  11. Experimental and theoretical study of phase transitions under ball milling; Etude experimentale et modelisation des changements de phases sous broyage a haute energie

    Energy Technology Data Exchange (ETDEWEB)

    Pochet, P

    1997-12-31

    The aim of this work was to determine how phase transition s under ball-milling depend on the milling conditions and to find out if one can rationalize such transitions with the theory of driven alloys. We have chosen two phase transitions: the order-disorder transition in Fe Al and the precipitation-dissolution NiGe. In the case of Fe Al we have found that the steady-state long range order parameter achieved under ball milling intensity; moreover the same degree of order is achieved starting from an ordered alloy or a disordered solid solution. On the way to fully disordered state the degree of order either decreases monotonically or goes through a short lived transient state. This behaviour is reminiscent of a first order transition while the equilibrium transition is second order. All the above features are well reproduced by a simple model of driven alloys, which was originally build for alloys under irradiation. The stationary degree of order results of two competitive atomic jump mechanisms: the forced displacements induced by the shearing of the grains, and the thermally activated jumps caused by vacancies migrations. Finally we have performed atomistic simulations with a Monte Carlo kinetic algorithm, which revealed the role of the fluctuations in the intensity of the forcing. Moreover we have shown that specific atomistic mechanisms are active in a dilute NiGe solid solution which might lead to ball milling induced precipitation in under-saturated solid solution. (author). 149 refs.

  12. Kinetic modelling of hydrocracking catalytic reactions by the single events theory; Modelisation cinetique des reactions catalytiques d`hydrocraquage par la theorie des evenements constitutifs

    Energy Technology Data Exchange (ETDEWEB)

    Schweitzer, J.M.

    1998-11-23

    Kinetic modelling of petroleum hydrocracking is particularly difficult given the complexity of the feedstocks. There are two distinct classes of kinetics models: lumped empirical models and detailed molecular models. The productivity of lumped empirical models is generally not very accurate, and the number of kinetic parameters increases rapidly with the number of lumps. A promising new methodology is the use of kinetic modelling based on the single events theory. Due to the molecular approach, a finite and limited number of kinetic parameters can describe the kinetic behaviour of the hydrocracking of heavy feedstock. The parameters are independent of the feedstock. However, the available analytical methods are not able to identify the products on the molecular level. This can be accounted for by means of an posteriori lamping technique, which incorporates the detailed knowledge of the elementary step network. Thus, the lumped kinetic parameters are directly calculated from the fundamental kinetic coefficients and the single event model is reduced to a re-lumped molecular model. Until now, the ability of the method to extrapolate to higher carbon numbers had not been demonstrated. In addition, no study had been published for three phase (gas-liquid-solid) systems and a complex feedstock. The objective of this work is to validate the `single events` method using a paraffinic feedstock. First of all, a series of experiments was conducted on a model compound (hexadecane) in order to estimate the fundamental kinetic parameters for acyclic molecules. To validate the single event approach, these estimated kinetic coefficients were used to simulate hydrocracking of a paraffinic mixture ranging from C11 to C18. The simulation results were then compared to the results obtained from the hydrocracking experiments. The comparison allowed to validate the model for acyclic molecules and to demonstrate that the model is applicable to compounds with higher carbon numbers. (author) 60 refs.

  13. Fuzzy logic and modeling of ventilation networks in the nuclear industry; Logique floue et modelisation des reseaux de ventilation dans l'industrie nucleaire

    Energy Technology Data Exchange (ETDEWEB)

    Floquet, P.; Lhoste, J.C.; Domenech, S.; Pibouleau, L. [Ecole Nationale Superieure des Arts Chimiques et Technologiques, Lab. de Genie Chimique, LGC, UMR CNRS/INP/UPS 5503, 31 - Toulouse (France); Laborde, J.C. [CEA Saclay, Institut de la Protection et de la Surete Nucleaire, IPSN, DPEA/SERAC, 91 - Gif-sur-Yvette (France)

    2001-07-01

    This article presents the implementation of fuzzy logic in the modeling of ducts, filters and pressures of the ventilation networks of the nuclear industry, taking into account the uncertainties of the aeraulic parameters. (J.S.)

  14. Modeling of the dynamical combustion of explosives: influence of mechanical properties; Modelisation de la combustion dynamique des explodifs: influence des proprietes mecaniques

    Energy Technology Data Exchange (ETDEWEB)

    Picart, D.; Pertuis, C. [CEA Le Ripault, 37 - Tours (France)

    1996-12-31

    Experimental observations performed during the combustion of solid explosives under pressure have shown an unexpected desensitization of the samples when damaged. A simplified method of combustion simulation inside a pressure cell is proposed in this study. The model used is based on the description of the mechanical behaviour of the solid phase. It allows to retrieve the overall experimental results, and in particular the occurrence of anomalous combustion modes. (J.S.) 8 refs.

  15. Self-shielding phenomenon modelling in multigroup transport code Apollo-2; Modelisation du phenomene d'autoprotection dans le code de transport multigroupe Apollo 2

    Energy Technology Data Exchange (ETDEWEB)

    Coste-Delclaux, M

    2006-03-15

    This document describes the improvements carried out for modelling the self-shielding phenomenon in the multigroup transport code APOLLO2. They concern the space and energy treatment of the slowing-down equation, the setting up of quadrature formulas to calculate reaction rates, the setting-up of a method that treats directly a resonant mixture and the development of a sub-group method. We validate these improvements either in an elementary or in a global way. Now, we obtain, more accurate multigroup reaction rates and we are able to carry out a reference self-shielding calculation on a very fine multigroup mesh. To end, we draw a conclusion and give some prospects on the remaining work. (author)

  16. Calculation system for physical analysis of boiling water reactors; Modelisation des phenomenes physiques specifiques aux reacteurs a eau bouillante, notamment le couplage neutronique-thermohydraulique

    Energy Technology Data Exchange (ETDEWEB)

    Bouveret, F

    2001-07-01

    Although Boiling Water Reactors generate a quarter of worldwide nuclear electricity, they have been only little studied in France. A certain interest now shows up for these reactors. So, the aim of the work presented here is to contribute to determine a core calculation methodology with CEA (Commissariat a l'Energie Atomique) codes. Vapour production in the reactor core involves great differences in technological options from pressurised water reactor. We analyse main physical phenomena for BWR and offer solutions taking them into account. BWR fuel assembly heterogeneity causes steep thermal flux gradients. The two dimensional collision probability method with exact boundary conditions makes possible to calculate accurately the flux in BWR fuel assemblies using the APOLLO-2 lattice code but induces a very long calculation time. So, we determine a new methodology based on a two-level flux calculation. Void fraction variations in assemblies involve big spectrum changes that we have to consider in core calculation. We suggest to use a void history parameter to generate cross-sections libraries for core calculation. The core calculation code has also to calculate the depletion of main isotopes concentrations. A core calculation associating neutronics and thermal-hydraulic codes lays stress on points we still have to study out. The most important of them is to take into account the control blade in the different calculation stages. (author)

  17. Modelling and numerical simulation of liquid-vapor phase transitions; Modelisation et simulation numerique des transitions de phase liquide-vapeur

    Energy Technology Data Exchange (ETDEWEB)

    Caro, F

    2004-11-15

    This work deals with the modelling and numerical simulation of liquid-vapor phase transition phenomena. The study is divided into two part: first we investigate phase transition phenomena with a Van Der Waals equation of state (non monotonic equation of state), then we adopt an alternative approach with two equations of state. In the first part, we study the classical viscous criteria for selecting weak solutions of the system used when the equation of state is non monotonic. Those criteria do not select physical solutions and therefore we focus a more recent criterion: the visco-capillary criterion. We use this criterion to exactly solve the Riemann problem (which imposes solving an algebraic scalar non linear equation). Unfortunately, this step is quite costly in term of CPU which prevent from using this method as a ground for building Godunov solvers. That is why we propose an alternative approach two equations of state. Using the least action principle, we propose a phase changing two-phase flow model which is based on the second thermodynamic principle. We shall then describe two equilibrium submodels issued from the relaxations processes when instantaneous equilibrium is assumed. Despite the weak hyperbolicity of the last sub-model, we propose stable numerical schemes based on a two-step strategy involving a convective step followed by a relaxation step. We show the ability of the system to simulate vapor bubbles nucleation. (author)

  18. Modeling of the equilibrium of a tokamak plasma; Modelisation de l'equilibre d'un plasma de tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Grandgirard, V

    1999-12-01

    The simulation and the control of a plasma discharge in a tokamak require an efficient and accurate solving of the equilibrium because this equilibrium needs to be calculated again every microsecond to simulate discharges that can last up to 1000 seconds. The purpose of this thesis is to propose numerical methods in order to calculate these equilibrium with acceptable computer time and memory size. Chapter 1 deals with hydrodynamics equation and sets up the problem. Chapter 2 gives a method to take into account the boundary conditions. Chapter 3 is dedicated to the optimization of the inversion of the system matrix. This matrix being quasi-symmetric, the Woodbury method combined with Cholesky method has been used. This direct method has been compared with 2 iterative methods: GMRES (generalized minimal residual) and BCG (bi-conjugate gradient). The 2 last chapters study the control of the plasma equilibrium, this work is presented in the formalism of the optimized control of distributed systems and leads to non-linear equations of state and quadratic functionals that are solved numerically by a quadratic sequential method. This method is based on the replacement of the initial problem with a series of control problems involving linear equations of state. (A.C.)

  19. Workshop on thermal modeling: at the crossroads of several subjects of physics; La modelisation thermique: point de rencontre de plusieurs disciplines de la physique

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    The modeling of thermal phenomena is of prime importance for the dimensioning of industrial facilities. However, the understanding of thermal processes requires to refer to other subjects of physics like electromagnetism, matter transformation, fluid mechanics, chemistry etc.. The aim of this workshop organized by the industrial electro-thermal engineering section of the French society of thermal engineers is to take stock of current or forthcoming advances in the coupling of thermal engineering codes with electromagnetic, fluid mechanics, chemical and mechanical engineering codes. The modeling of phenomena remains the essential link between the laboratory research of new processes and their industrial developments. From the 9 talks given during this workshop, 2 of them deal with thermal processes in nuclear reactors and fall into the INIS scope and the others concern the modeling of industrial heating or electrical processes and were selected for ETDE. (J.S.)

  20. Multivariable fuzzy modelling and command: application to the thermic engine control; Modelisation et commande multivariables floues: application a la commande d`un moteur thermique

    Energy Technology Data Exchange (ETDEWEB)

    Bortolet, P.

    1998-12-11

    During these last two decades, the growing awareness of the contribution of the automobile to the degradation of the environment has forces different figures from the transportation world to put automobiles under more and more severe controls. Fuzzy logic is a technique which allows for the taking into account of experts knowledge; the most recent research work has moreover shown interest in associating fuzzy logic with algorithmic control techniques (adaptive control, robust control...). Our research work can be broken down into three distinct parts: a theoretical approach concerning the methods of fuzzy modeling permitting one to achieve models of the type Takagi-Sugeno and to use them in the synthesis of controls; the work of physical modeling of a four-stroke direct injection gas motor in collaboration with the development teams from Siemens Automotive SA; the simulated application of fuzzy modeling techniques and of fuzzy control developed on a theoretical level to a four-stroke direct injection gas motor. (author) 105 refs.

  1. Radiative modeling and characterization of aerosol plumes hyper-spectral imagery; Modelisation radiative et caracterisation des panaches d'aerosols en imagerie hyperspectrale

    Energy Technology Data Exchange (ETDEWEB)

    Alakian, A

    2008-03-15

    This thesis aims at characterizing aerosols from plumes (biomass burning, industrial discharges, etc.) with hyper-spectral imagery. We want to estimate the optical properties of emitted particles and also their micro-physical properties such as number, size distribution and composition. To reach our goal, we have built a forward semi-analytical model, named APOM (Aerosol Plume Optical Model), which allows to simulate the radiative effects of aerosol plumes in the spectral range [0,4-2,5 {mu}m] for nadir viewing sensors. Mathematical formulation and model coefficients are obtained from simulations performed with the radiative transfer code COMANCHE. APOM is assessed on simulated data and proves to be accurate with modeling errors between 1% and 3%. Three retrieval methods using APOM have been developed: L-APOM, M-APOM and A-APOM. These methods take advantage of spectral and spatial dimensions in hyper-spectral images. L-APOM and M-APOM assume a priori knowledge on particles but can estimate their optical and micro-physical properties. Their performances on simulated data are quite promising. A-APOM method does not require any a priori knowledge on particles but only estimates their optical properties. However, it still needs improvements before being usable. On real images, inversion provides satisfactory results for plumes above water but meets some difficulties for plumes above vegetation, which underlines some possibilities of improvement for the retrieval algorithm. (author)

  2. Modelling and multiparameter control applied to a fast annealing furnace; Modelisation et Commande Multivariable Appliquee a un Four de Recuit Rapide

    Energy Technology Data Exchange (ETDEWEB)

    Bardon, B

    1995-01-31

    Rapid Thermal Processing (RTP) technology is a delicate field to the control engineer. Its compatibility to single-wafer processing is well suited for performing thermal steps in the state-of-the-art integrated circuit (IC) manufacturing. Control of the wafer temperature during the processing is essential. The main problem in the scalar (SISO) approach is due to the steady-state temperature uniformity. A solution to this problem is to vary the spatial energy flux distribution radiating to the wafer. To achieve this requirement, one approach is the use a multivariable (MIMO) control law to manipulate independently the different lamps banks. Thermal process are highly non linear and distributed in nature. Besides, these non-linearities implies process dynamics variations. In this work, after physically describing our process about a reference value of the power and temperature, we present an off-line identification procedure (in the aim of devising a linear multivariable model) using input/output data for different reference values from real experiences and multi-variable least square algorithm. Afterwards, particular attention is devoted to the structure parameter determination of the linear model. Based on the linear model, a multivariable PID controller is designed. The controller coupled with the least mean square identification algorithm is tested under real conditions. The performances of the MIMO adaptive controller is also evaluated in tracking as well as in regulation. (author) refs.

  3. Presentation of the health impact evaluation study of atmospheric emissions of a major coal combustion installation; Mise a jour de l'etude d'evaluation de l'impact sur la sante des rejets atmospheriques des tranches charbon d'une grande installation de combustion

    Energy Technology Data Exchange (ETDEWEB)

    Bonnard, R

    2004-12-15

    In the framework of a working group on the major installations, a study has been realized on a today coal combustion installation. The direct risk by inhalation and the risks bond to indirect exposure of atmospheric releases were analyzed. The calculation method is explained and the uncertainties are discussed to present the results. (A.L.B.)

  4. Development of novel protective high temperature coatings on heat exchanger steels and their corrosion resistance in simulated coal firing environment; Developpement de revetements pour les aciers d'echangeurs thermiques et amelioration de leur resistance a la corrosion en environnement simulant les fumees de combustion et de charbon

    Energy Technology Data Exchange (ETDEWEB)

    Rohr, V.

    2005-10-15

    Improving the efficiencies of thermal power plants requires an increase of the operating temperatures and thus of the corrosion resistance of heat exchanger materials. Therefore, the present study aimed at developing protective coatings using the pack cementation process. Two types of heat exchanger steels were investigated: a 17% Cr-13% Ni austenitic steel and three ferritic-martensitic steels with 9 (P91 and P92) and 12% Cr (HCM12A). The austenitic steel was successfully aluminized at 950 C. For the ferritic-martensitic steels, the pack cementation temperature was decreased down to 650 C, in order to maintain their initial microstructure. Two types of aluminides, made of Fe{sub 2}Al{sub 5} and FeAl, were developed. A mechanism of the coating formation at low temperature is proposed. Furthermore, combining the pack cementation with the conventional heat treatment of P91 allowed to take benefit of higher temperatures for the deposition of a two-step Cr+Al coating. The corrosion resistance of coated and uncoated steels is compared in simulated coal firing environment for durations up to 2000 h between 650 and 700 C. It is shown that the coatings offer a significant corrosion protection and, thus, an increase of the component lifetime. Finally, the performance of coated 9-12% Cr steels is no longer limited by corrosion but by interdiffusion between the coating and the substrate. (author)

  5. Opening of the first CO{sub 2} capture installation on the fumes of a coal power plant - european project Castor, Denmark; Inauguration de la premiere installation de captage du CO{sub 2} sur les fumees d'une centrale electrique au charbon - Projet europeen Castor, Danemark

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-03-15

    The 15 March 2006, was launched the first industrial pilot of CO{sub 2} capture of the Castor project, coordinated by the IFP and financed by the european commission, on the site of the Esbjerg (Denmark) power plant. It is the first world installation allowing the CO{sub 2} capture on the fumes of a coal power plant. This document presents the pilot installation, discusses the european project Castor, the advantages of the CO{sub 2} capture and storage for a better use of the fossil energies, where and how capturing the CO{sub 2} and the Denmark energy context. (A.L.B.)

  6. Atmospheric pollution and heating plants in urban area. What technical solutions for the coal and the heavy oil? For which costs?; Pollution atmospherique et chaufferies en milieu urbain. Quelles solutions techniques pour le charbon et le fioul lourd?. A quel couts?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    In France, furnaces fed with coal and heavy fuel and established in urban area, are bound by many restraints: a reinforcement of the regulations on atmospheric emissions, a strong social demand bound to the urban air quality improvement and a necessary costs mastership. So buildings managers and persons responsible for district heating are confronted with technical and strategical choices. To answer their questions ADEME organized a day of information around four main themes: the urban heating in France, actions on fuels, possible technics for the smokes desulfurization and nitrogen oxides reduction, costs and financing of the solutions. (A.L.B.)

  7. The coal. Its place in the world, the specifical problems of the european countries and more particularly the France; Le charbon. Sa place dans le monde, les problemes specifiques des pays d'Europe et tout particulierement de la France

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-12-15

    In a first part, the work group presents the available resources and studies the coal world market evolution. Then in a second time it discusses the european situation, and especially the french and german situation. The last part is devoted to the reconversion of the mines in France, the problems with the example of the coal basin of north of France. (A.L.B.)

  8. Zoom on India | Gros plan sur l’Inde

    Directory of Open Access Journals (Sweden)

    2012-05-01

    Full Text Available Indian Energy Production and Consumption (in Million Tonnes of Oil EquivalentProduction et consommation d’énergie en Inde (en millions de tonnes d’équivalent pétroleSource: World Bank, World Bank Development Indicators, 2010.Indian Oil, Gas and Coal Imports (in Million Tonnes of Oil Equivalent, 2008*Importations indiennes de pétrole, de gaz et de charbon (en millions de tonnes d’équivalent pétrole, 2008** 2009 for coal data | 2009 pour les données sur le charbon.Sources: British Petroleum...

  9. L'hydrogène Hydrogen

    Directory of Open Access Journals (Sweden)

    Balaceanu J. C.

    2006-11-01

    Full Text Available La crise pétrolière et le bouleversement du classement économique des énergies primaires qu'elle entraîne conjuguent leurs effets avec ceux d'une sensibilisation de l'opinion au respect de l'environnement pour favoriser l'avènement industriel d'innovations scientifiques et techniques dont l'intervention n'était prévisible que dans un avenir de plusieurs décennies. Le développement de l'énergie électrique nucléaire, qui actuellement s'impose économiquement, implique, pour élargir la pénétration de cette forme d'énergie à toutes les utilisations, une énergie chimique relais permettant un stockage et une régulation de la production; l'hydro- gène obtenu par électrolyse de l'eau semble pouvoir constituer ce combustible relais dans un délai raisonnable en tenant compte des contraintes de pollution. La chaleur nucléaire soulève a fortiori des problèmes identiques, elle peut théoriquement par dissociation thermique étagée de l'eau liquide fournir de l'hydrogène avec des rendements très satisfaisants, mais les problèmes de principe et de technologie posés par la mise en opération d'une suite de transformations chimiques et de séparations impliquant des composés particulièrement réactifs sont ardus et leur inventaire même n'est pas achevé. L'hydrogène, nouveau combustible polyvalent d'une industrie gazière perpétuelle, semble pouvoir bénéficier également, au niveau de son utilisation disséminée, de techniques nouvelles : stockages solides, turbines à hauts rendements, piles à combustible, qui ouvrent le marché de la traction et le marché électrique des installations isolées. Agent de réduction réactif et puissant, l'hydrogène peut également se substituer aux réducteurs conventionnels en métallurgie et donner une dimension nouvelle à l'hydrogénométallurgie par voie sèche ou par voie humide. Mais plus encore la mise en valeur économique des combustibles fossiles abondants . charbon, schistes

  10. Flow Behaviour of Alkali, Surfactant, and Xanthan Solutions Used for Enhanced Oil Recovery Fluidité des solutions d'alcali, de tensio-actif et de xanthane utilisées pour la récupération assistée du pétrole

    Directory of Open Access Journals (Sweden)

    Nasr-El-Din H. A.

    2006-11-01

    Full Text Available An experimental study was conducted to examine the effects of various alkalis, surfactants and brines on the viscosity of dilute aqueous solutions of two xanthan materials containing medium and high pyruvate content, over a wide range of parameters. The effect of alkalis on the flow curves of xanthan solutions depended on alkali type and concentration, shear rate and pyruvate content of xanthan. Strong alkalis caused partial degradation of the xanthan molecules. As a result, a fast and significant reduction in apparent viscosity occurred, especially with the high pyruvate xanthan. This drop was only noticeable at low shear rates. Buffered alkalis were less detrimental to the viscosity of xanthan solutions. Triton X-100 up to 10 wt% had no significant effect on the flow curves of both xanthan materials. Neodol 25-3S caused noticeable changes only in the flow curves of the high pyruvate xanthan. Triton X-100 up to 10 wt% in the presence of alkali had no significant effect on the flow curves of either xanthan material. The addition of anionic surfactants at low concentrations slightly decreased the viscosity of alkali/xanthan solutions. A significant viscosity enhancement was observed at higher surfactant concentrations over a narrow range of alkali concentrations. This behaviour was only observed with anionic surfactants and was due to the formation of surfactant aggregates. The effect of sodium chloride on the apparent viscosity of xanthan solutions depended on polymer concentration and the pyruvate content of xanthan. Only the high pyruvate polymer at high polymer concentrations (= 1 wtO/o showed a dramatic increase in the apparent viscosity upon the addition of sodium chloride. At low polymer concentrations, calcium chloride had a more detrimental effect on the viscosity of the high pyruvate xanthan than sodium chloride. Une étude expérimentale a été effectuée pour examiner les effets de divers alcalis, tensioactifs et saumures sur la viscosité de solutions aqueuses diluées de deux produits à base de xanthane, à teneur en pyruvate moyenne (polymère Statoil ou élevée (Flocon 4800, avec une large gamme de paramètres. L'effet des alcalis sur la viscosité des solutions de xanthane dépend du type et de la concentration de l'alcali, du gradient de cisaillement, et de la teneur en pyruvate. L'influence des alcalis sur la courbe de viscosité du xanthane n'est repérable que pour de faibles gradients de cisaillement. Les alcalis forts (hydroxyde de sodium par exemple provoquent une dégradation partielle des molécules de xanthane, d'où une réduction rapide et importante de la viscosité apparente, surtout avec une forte teneur en pyruvate. Les alcalis en solution-tampon (carbonate de sodium par exemple sont moins nocifs pour la viscosité des solutions de xanthane. Par conséquent, dans les procédés à l'alcali/ polymère ou à l'alcali/tensioactif/polymère utilisant la gomme de xanthane, il serait extrêmement avantageux, du point de vue économique, de préférer un alcali tampon plutôt qu'un alcali fort. L'effet des tensioactifs sur les courbes de viscosité des solutions de xanthane dépend du type et de la concentration du produit tensioactif. L'influence du Triton X-100 (tensioactif non ionique sur les courbes des deux produits à base de xanthane n'est pas significative jusqu'à 10 % en poids. Le Néodol 25-3S, tensioactif anionique, ne provoque de modifications de viscosité notables que pour le xanthane à forte teneur en pyruvate. Le Triton X-100, jusqu'à 10 % en poids, en présence d'alcali, n'a pas d'effet marqué sur les courbes de viscosité des deux produits à base de xanthane. L'addition de Néodol 25-3S à faible concentration diminue légèrement la viscosité des solutions alcali/xanthane. On a constaté un renforcement notable de la viscosité des solutions alcali/xanthane pour de plus fortes concentrations en tensioactif, sur une gamme étroite de concentrations en alcali. Ce comportement n'a été observé que pour les tensioactifs anioniques, et il est dû à la formation d'agrégats de tensioactif qui résulte de l'effet électrolytique sur la formation de micelles dans les tensioactifs anioniques. L'effet du chlorure de sodium sur la viscosité apparente des solutions de xanthane dépend de la concentration en polymère et de la teneur en pyruvate. Pour de faibles concentrations en polymère, < ou = 4000 ppm, la viscosité apparente tombe lors de l'addition de sels. Cette chute est due à l'effet d'écran de la charge. Pour de fortes concentrations en polymère (= 1 % en poids, seul le polymère à forte teneur en pyruvate subit une importante augmentation de sa viscosité apparente lors de l'addition de chlorure de sodium. Cette augmentation est due à l'association des molécules de polymère. Pour de faibles concentrations de polymère, le chlorure de calcium nuit plus que le chlorure de sodium à la viscosité du xanthane à forte teneur en pyruvate.

  11. Recovery of Waterflood Residual Oil Using Alkali, Surfactant and Polymer Slugs in Radial Cores Récupération d'huile résiduelle par injection d'eau améliorée de produits alcalins, de tensio-actifs et de polymères dans des carottes radiales

    Directory of Open Access Journals (Sweden)

    Nasr-El-Din H. A.

    2006-11-01

    Full Text Available An experimental study has been conducted to examine mobilization and recovery of waterflood residual oil in radial cores. Alkali, surfactant, and polymer slugs of various compositions, sizes and sequences were tested. Core flood experiments were conducted with unfired radial Berea sandstone disks at a flow rate of 8 cm3/h. David Lloydminster crude oil (total acid number of 0. 45 mg KOH/g oil was used. The results of the present work showed that the composition and sequence of the injected chemical slug play an important role in mobilization and recovery of residual oil. For slugs lacking either mobility control, or low interfacial tension, no oil bank was formed and tertiary oil recovery was less than 20% Sor. A significant oil bank and tertiary oil recovery up to 70 % Sor were obtained with slugs having mobility control and low interfacial tension. However, maximum oil cut, incre-mental oil recovery and surfactant propagation were found to be functions of the alkali content in the slug. The incremental oil recovery, oil cut and slug injectivity greatly improved as the alkali concentration (sodium carbonate in the combined slug was increased. A slight delay in surfactant breakthrough and a significantly slower rate of surfactant propagation were observed at higher sodium carbonate concentrations. Une étude expérimentale ayant pour but d'examiner la mobilisation et la récupération assistée d'huile résiduelle, à la suite d'un déplacement par l'eau en milieu poreux, a été conduite. Des bouchons de produit alcalin, de surfactant et de polymère, ayant des compositions, grosseurs et séquences d'injection variées, furent essayés. Les déplacements en milieu poreux furent conduits en utilisant des carottes de grès berea (non traités à haute température et un débit de 8,0 cm3/h. Pour ce faire, on utilisa de l'huile de David Lloydminster (ayant un nombre acide de 0,45 mg KOH/g d'huile. Les résultats de ce travail ont démontré que la composition et séquence des bouchons chimiques jouent un rôle important dans la mobilisation et la récupération des huiles résiduelles. Les bouchons qui avaient peu de contrôle de mobilité, ou une tension d'interface basse, ne formaient pas de banque d'huile et la récupération tertiaire de l'huile était moins de 20% d'huile résiduelle. Une banque d'huile importante, ainsi qu'une récupération tertiaire allant jusqu'à 70% d'huile résiduelle, furent obtenues avec les bouchons possédant un bon contrôle de mobilité ainsi qu'une tension d'interface basse. Cependant, la fraction maximale d'huile, la récupération accrue d'huile et la propagation des surfactants, se révélèrent reliées à la teneur alkaline du bouchon. La récupération accrue de l'huile, la fraction d'huile et la capacité d'injection du bouchon furent grandement améliorées lorsqu'on augmenta la concentration alkaline (carbonate de sodium des bouchons respectifs. On observa un léger retard de la percée des surfactants et une vitesse de propagation des surfactants beaucoup plus basse lorsque la concentration du carbonate de sodium était plus élevée.

  12. Conformance and Non Conformance of Asset Managers to Environment, Social and Governance Pressures - Sensemaking capacities and the use of externally defined information- / Conformance et Non Conformance des Gestionnaires d'Actifs aux Pressions Environmental, Social et Gouvernance - Capabilités de sensemaking et l'usage d'information externellement définie-

    OpenAIRE

    Sakuma, Kyoko

    2012-01-01

    This thesis focuses on a central behavioral paradox in the asset management community. Recent decades have brought an upsurge in initiatives throughout the investment community to voluntarily integrate sustainability issues into investment decisions. The financial crisis has however revealed behavioral inconsistency and deepening irresponsibility. Today, sustainable investments represent USD 10.7 trillion, or 7% of the entire market, of assets under management and it is growing steadily. O...

  13. Carbon disclosure project 2006. evaluation realized with the SBF 120 enterprises. For 225 investors managing more than 31000 milliards of active dollars; Carbon disclosure project 2006. Enquete menee aupres des entreprises du SBF 120. Pour le compte de 225 investisseurs gerant plus de 31000 milliards de dollars d'actifs

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-10-15

    The Carbon Disclosure Project (CDP) is an independent not-for-profit organisation aiming to create a lasting relationship between shareholders and corporations regarding the implications for shareholder value and commercial operations presented by climate change. Its goal is to facilitate a dialogue, supported by quality information, from which a rational response to climate change will emerge. Over 7 years CDP has become the gold standard for carbon disclosure methodology and process. CDP4 finds that the global investment and corporate communities have made great strides in their understanding of climate change and its competitive and financial implications, and the measurement of these implications. However, awareness and measurement are not translating into sufficient management and activity in the context of the climate change challenge. (A.L.B.)

  14. Télédétection par satellite et SIG pour l'analyse des déplacements des chenaux dans le delta actif de la Rivière Jaune en ChineTeledetección satelitária y SIG para analizar cambios en el desplazamiento de causes en el delta activo del Río Amarillo, China

    Science.gov (United States)

    Yang, Xiaojun; Damen, Michiel C. J.; van Zuidam, Robert A.

    Channel migration in deltaic lowlands tends to be complicated by marine processes and intensified cultural practices. Understanding the ways in which river channels have migrated through time is critical to tackling many geomorphologic and river management problems. Because of large magnitude and rapid rates of change, special surveillance systems are needed to efficiently measure and monitor channel migration. This study presents an application of geographic information technologies for the study of channel migration in the active Yellow River Delta, China. The main source of data was a series of time-sequential Landsat images spanning a period of approximately 19 years. A geographic information system (GIS) was used to support modernized channel position mapping and measurement. The spatio-temporal changes of river banks and channel centerlines were systematically examined, and an attempt was made to relate these computational results with appropriate natural and human processes affecting the delta. This study demonstrates the utility of satellite remote sensing integrated with a GIS in investigating channel migration.

  15. [NiFe] hydrogenase structural and functional models: new bio-inspired catalysts for hydrogen evolution; Modeles structuraux et fonctionnels du site actif des hydrogenases [NiFe]: de nouveaux catalyseurs bio-inspires pour la production d'hydrogene

    Energy Technology Data Exchange (ETDEWEB)

    Oudart, Y

    2006-09-15

    Hydrogenase enzymes reversibly catalyze the oxidation and production of hydrogen in a range close to the thermodynamic potential. The [NiFe] hydrogenase active site contains an iron-cyano-carbonyl moiety linked to a nickel atom which is in an all sulphur environment. Both the active site originality and the potential development of an hydrogen economy make the synthesis of functional and structural models worthy. To take up this challenge, we have synthesised mononuclear ruthenium models and more importantly, nickel-ruthenium complexes, mimicking some structural features of the [NiFe] hydrogenase active site. Ruthenium is indeed isoelectronic to iron and some of its complexes are well-known to bear hydrides. The compounds described in this study have been well characterised and their activity in proton reduction has been successfully tested. Most of them are able to catalyze this reaction though their electrocatalytic potentials remain much more negative compared to which of platinum. The studied parameters point out the importance of the complexes electron richness, especially of the nickel environment. Furthermore, the proton reduction activity is stable for several hours at good rates. The ruthenium environment seems important for this stability. Altogether, these compounds represent the very first catalytically active [NiFe] hydrogenase models. Important additional results of this study are the synergetic behaviour of the two metals in protons reduction and the evidence of a protonation step as the limiting step of the catalytic cycle. We have also shown that a basic site close to ruthenium improves the electrocatalytic potential of the complexes. (author)

  16. Carbon disclosure project 2006. evaluation realized with the SBF 120 enterprises. For 225 investors managing more than 31000 milliards of active dollars; Carbon disclosure project 2006. Enquete menee aupres des entreprises du SBF 120. Pour le compte de 225 investisseurs gerant plus de 31000 milliards de dollars d'actifs

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-10-15

    The Carbon Disclosure Project (CDP) is an independent not-for-profit organisation aiming to create a lasting relationship between shareholders and corporations regarding the implications for shareholder value and commercial operations presented by climate change. Its goal is to facilitate a dialogue, supported by quality information, from which a rational response to climate change will emerge. Over 7 years CDP has become the gold standard for carbon disclosure methodology and process. CDP4 finds that the global investment and corporate communities have made great strides in their understanding of climate change and its competitive and financial implications, and the measurement of these implications. However, awareness and measurement are not translating into sufficient management and activity in the context of the climate change challenge. (A.L.B.)

  17. {sup 238}U-{sup 230}Th-{sup 226}Ra systematics applied to the active oceanic volcanism. Constraints on the duration and processes of magmas formation; Systematique {sup 238}U-{sup 230}Th-{sup 226}Ra appliquee au volcanisme actif oceanique. Contraintes sur la duree et les processus de formation des magmas

    Energy Technology Data Exchange (ETDEWEB)

    Claude-Ivana, Ch

    1997-02-01

    The development of a new precise analytical technique for measuring radioactive disequilibria by TIMS has enabled to put constraints on both the extend and time scale of incompatible element fractionation during magma formation in oceanic islands. Three different settings have been studied: the Grande Comore volcanoes (Comores archipelago), Tenerife and Lanzarote volcanism (Canary islands) and four islands within the Azores: Sao Miguel, Terceira, Pico and Faial islands. The Comores and Canaries archipelagoes are both lying on an old thick oceanic lithosphere. The detailed case in Grande Comore shows evidence for a process of interaction of the Comore plume with the underlying lithosphere. In the Canaries, the lithosphere also contributes to lava formation either during the differentiation (in Tenerife) or during mantle melting (in Lanzarote). Within the Azores, U-series measurements reveal large geochemical and isotopic variations between the different islands that we interpret as reflecting heterogeneities in the Azore plume. In particular, the U-Th fractionation in Sao Miguel volcanics is though to result from melting of an hydrous sediment-bearing mantle. The magma transit times have been found to be very short (1000 yr) in all the basaltic series. This very rapid migration of the melts is an evidence for the absence of large magma chamber and for processes of fracturing during melt transports. However, this model does not apply in the case of the very evolved volcanic series in Tenerife island (Canaries) where transit times of c.a. 100000 yr indicate the presence of a large magmatic reservoir. (author)

  18. 1206-IJBCS-Article-Hounnankpon Yedomonhan

    African Journals Online (AJOL)

    DR GATSING

    villageois des communes de Glazoué et de Dassa-Zoumè au centre-Bénin ..... Figure 3 : Sacs de charbons de bois exposés au bord de la route bitumée à Zounto. Tableau 1 : Taux d'expansion des unités d'occupation (1998 et 2006 ; 2006 et ...

  19. Criblage de variétés commerciales de canne à sucre prometteuses ...

    African Journals Online (AJOL)

    précoces de canne à sucre sur la base du rendement en sucre et de la tolérance au charbon (U. scitaminea) et au .... un broyeur électrique (« Jeffco » food and fodder ..... la canne à sucre en Afrique de l'Ouest et. Centrale. Yamoussoukro. pp.

  20. Comparaison du filtre adaptatif RIF et du filtre a base de reseau de ...

    African Journals Online (AJOL)

    Comparaison du filtre adaptatif RIF et du filtre a base de reseau de neurones pour le filtrage du courant de reference pour la commande du filtre actif parallele. C Benachaiba, A Bassou, B Mazari ...

  1. Geant4 simulation of the Elekta XVI kV CBCT unit for accurate description of potential late toxicity effects of image-guided radiotherapy

    International Nuclear Information System (INIS)

    Brochu, F M; Burnet, N G; Jena, R; Plaistow, R; Thomas, S J; Parker, M A

    2014-01-01

    This paper describes the modelisation of the Elekta XVI Cone Beam Computed Tomography (CBCT) machine components with Geant4 and its validation against calibration data taken for two commonly used machine setups. Preliminary dose maps of simulated CBCTs coming from this modelisation work are presented. This study is the first step of a research project, GHOST, aiming to improve the understanding of late toxicity risk in external beam radiotherapy patients by simulating dose depositions integrated from different sources (imaging, treatment beam) over the entire treatment plan. The second cancer risk will then be derived from different models relating irradiation dose and second cancer risk. (paper)

  2. Heavy Element Staining of Sedimentary Organic Matter Functional Groups for Backscattered Electron Imaging Marquage par éléments lourds de la matière organique sédimentaire pour la microscopie électronique en électrons rétrodiffusés

    Directory of Open Access Journals (Sweden)

    Belin-Geindre S.

    2006-11-01

    , 1992. Son imagerie est basée sur les contrastes de numéro atomique (Z existant entre les divers constituants. La matière organique apparaît noire et les minéraux gris. Cependant il n'est pas possible de distinguer plusieurs types de matière organique avec le MEB/ER. Afin de mettre en évidence des contrastes au MEB/ER entre différentes matières organiques, les échantillons ont été marqués par des éléments lourds qui ont la particularité de se fixer de manière sélective et spécifique sur les groupes fonctionnels. Cette méthode est largement employée par la biologie cellulaire pour révéler divers corps organiques (Soligo et Lambertenghi-Deliliers, 1987; Langsdorff et al. , 1990; Clark, 1991; Namimatsu, 1992 ou bien par la science des matériaux dans le domaine des polymères (Sawyer et Grubb, 1987; Ohlsson et Törnell, 1990; Sue et al. , 1991; Janik et al. , 1992. L'application à la géologie et à la pétrographie est restée jusqu'à présent assez réduite : sédiments argileux (Whitlatch et Johnson, 1974; Green et al. , 1979; Bishop et al. , 1992; Hillier et Clayton, 1992, charbons (Corcoran et Stephens, 1987; Sommerfeld et al. , 1992, sols (Foster, 1981. Les éléments lourds utilisés pour le marquage sont très variés et présentent une spécificité plus ou moins large (Reynolds, 1963; Lewis et Knight, 1976; Takeuchi et Takeuchi, 1990. La matière organique sédimentaire est un mélange complexe de macromolécules dont la composition dépend de la nature de la matière organique originelle et de son degré d'évolution (Tissot et Welte, 1984. La matière organique peu évoluée possède de nombreuses variétés de groupes fonctionnels (Rouxhet et al. , 1980; Béhar et Vandenbroucke, 1987. La faisabilité de la méthode a d'abord été testée sur des polymères contenant des fonctions chimiques susceptibles d'exister dans les kérogènes naturels (tableau 1. Puis elle a été appliquée à des sédiments presque exclusivement formés de

  3. Atmospheric sulfur and climate changes: a modelling study at mid and high-southern latitudes; Soufre atmospherique et changements climatiques: une etude de modelisation pour les moyennes et hautes latitudes Sud

    Energy Technology Data Exchange (ETDEWEB)

    Castebrunet, H

    2007-09-15

    The mid and high-southern latitudes are still marginally affected by anthropogenic sulfur emissions. They are the only regions in the world where the natural cycle of the atmospheric sulfur may still be observed. Sulfur aerosols are well-known for their radiative impact, and thus interact with climate. Climate can in turn affect atmospheric sulfur sources, distribution and chemistry. Antarctic ice cores provide information on the evolution of climate and sulfur deposition at the surface of the ice sheet at glacial-interglacial time scales. The aim of this thesis is to develop and use modeling towards a better understanding of the atmospheric sulfur cycle in antarctic and sub-antarctic regions. Ice core data are used to validate model results under glacial climate conditions. An Atmospheric General Circulation Model (AGCM) coupled to a sulfur chemistry module is used: the LMD-ZTSulfur model, version 4. An update of both the physical and chemical parts of the model. The model was first performed. The impact of there changes on modelled sulfur cycle are evaluated for modern climate. Further, boundary conditions are adapted to simulate the atmospheric circulation and sulfur cycle at the Last Glacial Maximum, approximately 20,000 years ago. In the model, sulfur is found to be highly sensitive to antarctic sea-ice coverage, which is still poorly known during the ice age. An original dataset of ice-age sea-ice coverage was developed. Its impact on the oceanic emissions of dimethyl sulfide, main precursor of sulfur aerosols at high-southern latitudes, is discussed. Using the same oceanic sulfur reservoirs as for present day climate, the model broadly reproduces the glacial deposits of sulfur aerosols on the Antarctic plateau, suggesting little impact of climate on oceanic sulfur production in the Antarctic region. Sensitivity tests were carried out to draw an up-to-date status of major uncertainties and difficulties facing future progress in understanding atmospheric sulfur and climate. (author)

  4. Modelling, development and optimization of integrated power LDMOS transistor. Performance limits in terms of energy; Modelisation, conception et optimisation de composant de puissance lateral DMOS integre. Etude des limites de performance en energie

    Energy Technology Data Exchange (ETDEWEB)

    Farenc, D.

    1997-12-16

    Technologies for Smart Power Integrated Circuits combine into a single chip Bipolar and CMOS transistors, plus power with lateral or vertical DMOS transistors. Complexity which has been increasing dramatically since the mid-80`s has allowed to integrate, into a single monolithic solution, entire systems. This thesis deals with the modelling, conception and test of the power integrated LDMOS transistor. The power LDMOS transistor is used as a switching device. It is characterized by two parameters which are the Specific On-resistance R{sub sp} and the breakdown voltage BV{sub DSS}. The LDMOS transistor developed for the new Smart Power technology exhibits a Specific On-resistance of 200 m{Omega}{sup *}mm{sup 2} and a breakdown voltage of 60 V. This device is dedicated to automotive applications. A reduction of the power device which is achieved with a low Specific On-resistance puts forward new issues such as the maximum Energy capability. When the power device is switched-off on an inductive load, a certain amount of energy is dissipated; if it is beyond a certain limit, the device is destroyed. Our goal is to determine the energy limits which are associated with our new Power integrated LDMOS transistor. (author) 28 refs.

  5. Numerical modelling 2 D and 3 D of circulating fluidized bed: application to the realization of regime diagrams; Modelisation numerique 2D et 3D de lit fluidise circulant: application a la realisation du diagramme des regimes

    Energy Technology Data Exchange (ETDEWEB)

    Begis, J.; Balzer, G.

    1997-02-01

    The numerical modelling of internal CFB boilers flows faced with complex phenomenons due to the flows un-stationariness, the heterogeneousness of the particle size distribution, and interactions between the two phases and the walls. Our study consisted in applying numerical models to the experimental configuration of cold circulating fluidized bed studied at the Cerchar. Special attention was given to the analysis of particles - wall interactions models, stemming from Jenkins (1992) and Louge`s (1994) theories, as well as the influence of the particles on fluid turbulence. In order to realize numerical simulations, we have used Eulerian two-phases flow codes developed at NHL medolif(2D), ESTET-ASTRID(3D). From different tests we have deducted that the most appropriate model for the realization of CFB`s prediction is the model taking in account the influence of particles on fluid turbulence. Then, to evaluate the validity limits of this model, we have built the regime diagram, and we have compared it with the experimental diagram. We have concluded that the simulation allows to describe the different CFB`s working regimes, and especially transitions. We have also noticed the importance of the choice of the mean diameter of the simulated particles. In this way, making a correction of the simulated particles` diameter in comparison with Sauter mean particle diameter, we obtained numerical results in good agreement with experimental data. (authors) 13 refs.

  6. Theoretical study of silicon carbide under irradiation at the nano scale: classical and ab initio modelling; Etude theorique a l'echelle nanometrique du carbure de silicium sous irradiation: modelisation classique et ab initio

    Energy Technology Data Exchange (ETDEWEB)

    Lucas, G

    2006-10-15

    The behaviour of silicon carbide under irradiation has been studied using classical and ab initio simulations, focusing on the nano scale elementary processes. First, we have been interested in the calculation of threshold displacement energies, which are difficult to determine both experimentally and theoretically, and also the associated Frenkel pairs. In the framework of this thesis, we have carried out simulations in classical and ab initio molecular dynamics. For the classical approach, two types of potentials have been used: the Tersoff potential, which led to non satisfactory results, and a new one which has been developed during this thesis. This potential allows a better modelling of SiC under irradiation than most of the empirical potentials available for SiC. It is based on the EDIP potential, initially developed to describe defects in silicon, that we have generalized to SiC. For the ab initio approach, the feasibility of the calculations has been validated and average energies of 19 eV for the C and 38 eV for the Si sublattices have been determined, close to the values empirically used in the fusion community. The results obtained with the new potential EDIP are globally in agreement with those values. Finally, the elementary processes involved in the crystal recovery have been studied by calculating the stability of the created Frenkel pairs and determining possible recombination mechanisms with the nudged elastic band method. (author)

  7. Modeling of an eddy-current ferrite-cored probe response in time harmonic regime; Modelisation de la reponse d'un capteur a courants de Foucault comportant un noyau ferromagnetique en regime harmonique

    Energy Technology Data Exchange (ETDEWEB)

    Buvat, F

    2005-07-01

    In aeronautics, non destructive evaluation by eddy-current is commonly used to detect corrosion area or cracks in structures. Eddy-current testing by using ferrite-cored probes is effective to detect these kind of defects. So, having a model able to predict these probes responses is a major endeavor. Our work consisted in developing a model determining the ferrite-cored probes response to a defect. To model fields inside both the core and the defect, an integral formulation has been used resulting from the application of the Green theorem onto the equations of propagation. Simulation results have been compared to synthetic data obtained by a finite-element method and they have been validated by comparison with measured impedance data. However as this model may be computationally costly, the use of the so-called non-linear approximation has been tested to tackle the case of long defects. The model has been integrated inside the CIVA platform developed by the CEA. (author)

  8. Modelling and experimental study of the behavior of radon and radon decay products in an enclosure. Application to houses; Modelisation et etude experimentale du comportement du radon et de ses descendants dans une enceinte confinee. Application a une habitation

    Energy Technology Data Exchange (ETDEWEB)

    Gouronnec, A M

    1995-02-03

    Since the eighties, more and more studies were performed about radon and its decay products in houses with one of the aim being the estimation of the dose received by their inhabitants. Then, the principal objective of this work is to describe the behaviour of radon and its decay products within a dwelling. In the first part to the report, a few definitions are given and data from literature give an idea of indoor radon and radon decay products activities and/or size distribution. Aspects of dosimetry are presented too. In the second part of the work, a mathematical model, called `PRADDO` of Physic of Radon and radon Decay products in Domestic environment is developed on the basis of the classical model written by Jacobi in 1972. On the one hand, it has to predict radon decay products activities in systems consisting in one or more enclosure(s), from radon activity and from ambient aerosol concentration and size distribution. On the other hand, one part of the model is assigned to study the influence of the entry model parameters variation on the calculated quantities. Then, in the third part of the work, two experimental studies are realised in order to compare measurements to modelization. The first experimentation is a laboratory work, made on the test bench ICARE from IPSN, and the second one consists in describing the basement of an occupied house from Brittany. In the two cases, the comparison between experiments and modelling shows a good agreement if particles are present in the air, but any conclusion is made when is no aerosol in the enclosure. (author). 158 refs., 81 figs., 42 tabs.

  9. Causal reasoning and models of cognitive tasks for naval nuclear power plant operators; Raisonnement causal et modelisation de l`activite cognitive d`operateurs de chaufferie nucleaire navale

    Energy Technology Data Exchange (ETDEWEB)

    Salazar-Ferrer, P

    1995-06-01

    In complex industrial process control, causal reasoning appears as a major component in operators` cognitive tasks. It is tightly linked to diagnosis, prediction of normal and failure states, and explanation. This work provides a detailed review of literature in causal reasoning. A synthesis is proposed as a model of causal reasoning in process control. This model integrates distinct approaches in Cognitive Science: especially qualitative physics, Bayesian networks, knowledge-based systems, and cognitive psychology. Our model defines a framework for the analysis of causal human errors in simulated naval nuclear power plant fault management. Through the methodological framework of critical incident analysis we define a classification of errors and difficulties linked to causal reasoning. This classification is based on shallow characteristics of causal reasoning. As an origin of these errors, more elementary component activities in causal reasoning are identified. The applications cover the field of functional specification for man-machine interfaces, operators support systems design as well as nuclear safety. In addition of this study, we integrate the model of causal reasoning in a model of cognitive task in process control. (authors). 106 refs., 49 figs., 8 tabs.

  10. Direct numerical simulation and modeling of turbulent natural convection in a vertical differentially heated slot; Simulation numerique directe et modelisation de la convection naturelle turbulente dans un canal differentiellement chauffe

    Energy Technology Data Exchange (ETDEWEB)

    Boudjemadi, R.

    1996-03-01

    The main objectives of this thesis are the direct numerical simulation of natural convection in a vertical differentially heated slot and the improvements of second-order turbulence modelling. A three-dimensional direct numerical simulation code has been developed in order to gain a better understanding of turbulence properties in natural convection flows. This code has been validated in several physical configurations: non-stratified natural convection flows (conduction solution), stratified natural convection flows (double boundary layer solution), transitional and turbulent Poiseuille flows. For the conduction solution, the turbulent regime was reached at a Rayleigh number of 1*10{sup 5} and 5.4*10{sup 5}. A detailed analysis of these results has revealed the principal qualities of the available models but has also pointed our their shortcomings. This data base has been used in order to improve the triple correlations transport models and to select the turbulent time scales suitable for such flows. (author). 122 refs., figs., tabs., 4 appends.

  11. Micro-mechanical modeling of the growth/percolation of pressurized pores in a ceramic matrix at high temperatures; Modelisation micromecanique de la croissance et de la percolation de pores sous pression dans une matrice ceramique a haute temperature

    Energy Technology Data Exchange (ETDEWEB)

    Vincent, P.G

    2007-11-15

    The aim of this work is to propose an elasto-plastic model of damage in a porous ceramics containing two populations of saturated cavities: the nuclear fuel uranium dioxide highly irradiated and at high temperature. The followed approach consists in a multi-scale approach based on the hypothesis of separation of the scales between the two populations of cavities (spherical intragranular pores and spheroidal intergranular pores) and of those of the macroscopic isotropy. The proposed elasto-plastic model of damage treats separately of the elasticity, of the surface of plasticity and of the evolution of the internal parameters of the model with load. The taking into account of different pressures in each population of cavity is carried out for elasticity-plasticity-damage. The model developed for the elastic behaviour takes into account the two populations of cavity, their morphology, their distribution and the pore pressures inside them. The proposed plasticity criteria is based on homogenization methods for non linear behaviours. At the grain scale, the first population of cavity is taken into account by a plasticity criteria of Gurson-Tvegaard-Needleman type. At the scale of grains collection, the presence of a second population of cavity inside a compressible matrix leads to the development of new superior boundaries and pertaining estimations for the effective plasticity surface. These models depend on the morphology and of the distribution of cavities. In the case of drained cavities, an analytical estimation, based on the writing of the classical variational principle with a compressible velocity field and an average on the equiprobable orientations is developed. In the case of saturated cavity, another estimation, based on the variational approach of Ponte Castaneda (1991) with a linear N phases comparison composite is proposed. These models are compared to numerical simulations by finite elements and to numerical simulations using the fast Fourier transformation method. The evolution laws of the retained elasto-plastic model (the estimation at N phases) are established on hypotheses of middle conservation of the cavities morphologies. An a posteriori enrichment of the evolution law of the porosity at the second scale is carried out by numerical simulations which are relative to the studied material. These numerical simulations allow to study the coalescence of the voids of the second scale (the percolation term is assimilated to the coalescence phenomenon) and implement a volume/cohesive finite element method on periodical Voronoi cells. (O.M.)

  12. Quantitative characterization of initiation and propagation in stress corrosion cracking. An approach of a phenomenological model; Caracterisation quantitative de l`amorcage et de la propagation en corrosion sous contrainte. Approche d`une modelisation phenomenologique

    Energy Technology Data Exchange (ETDEWEB)

    Raquet, O

    1994-11-25

    A purely phenomenological study of stress corrosion cracking was performed using the couple Z2CN 18.10 (304L) austenitic stainless steel/boiling MgCl{sub 2} aqueous solution. The exploitation of the morphological information (shape of the cracks and size distribution) available after constant elongation rate tests led to the proposal of an analytical expression of the crack initiation and growth rates. This representation allowed to quantitatively characterize the influence of the applied strain rate as well as the effect of corrosion inhibitors on the crack initiation and propagation phases. It can be used in the search for the stress corrosion cracking mechanisms as a `riddle` for the determination of the rate controlling steps. As a matter of fact, no mechanistic hypothesis has been used for its development. (author).

  13. Numerical study and modeling of turbulence modulation in a sheet flow burdened with particulates; Etude numerique et modelisation de la modulation de la turbulence dans un ecoulement de nappe chargee en particules

    Energy Technology Data Exchange (ETDEWEB)

    Vermorel, O

    2003-11-15

    This work is devoted to the numerical and theoretical study of turbulence modulation by particles using direct numerical simulation for the continuous phase coupled with a Lagrangian prediction of trajectories of discrete particles. The configuration corresponds to a slab of particles injected at high velocity into an isotropic decaying turbulence. The motion of a particle is supposed to be governed only by the drag force. The particle mass loading is large so that momentum exchange between particles and fluid results in a significant modulation of the turbulence. Collisions are neglected. The momentum transfer between particles and gas causes a strong acceleration of the gas in the slab. In the periphery of the slab, the turbulence is enhanced due to the production by the mean gas velocity gradients. The analysis of the interphase transfer terms in the gas turbulent kinetic energy equation shows that the direct effect of the particles is to damp the turbulence in the core of the slab but to enhance it in the periphery. This last effect is due to a strong correlation between the particle distribution and the instantaneous gas velocity. Another issue concerns the k-{epsilon} model and the validity of its closure assumptions in two phase flows. A new eddy viscosity expression, function of particle parameters, is used to model the Reynolds stress tensor. The modelling of the gas turbulent dissipation rate is questioned. A two-phase Langevin equation is also tested to model drift velocity and fluid-particles velocity covariance equations. (author)

  14. Rheological study of an hydrate slurry as secondary two-phase refrigerant. Experimental results and modelling; Etude rheologique d'une suspension d'hydrates en tant que fluide frigoporteur diphasique: resultats experimentaux et modelisation

    Energy Technology Data Exchange (ETDEWEB)

    Darbouret, M.

    2005-12-15

    Secondary two-phase fluids are suspensions of solid crystals. Thanks to the melting latent heat, they present a great interest for cold transportation. Moreover, they are a mean of reducing the amount of classical refrigerant. In the refrigeration field, ice slurries are already used. The goal is now to extend this technology to other temperature ranges suitable for other applications like freezing or air-conditioning. For an air-conditioning application, a TBAB (Tetra-Butyl-Ammonium Bromide) aqueous solution is studied. Under atmospheric pressure and for positive temperatures, this solution crystallizes into ice-like compounds named 'hydrates'. First, the physical properties of the aqueous solution and its crystallisation conditions were studied. Two different types of hydrates can appear. The goal of the experimental set-up is to study the rheological behaviour of two-phase fluids. Slurries are made in brushed-surface heat exchanger and pumped into pipes where flow rates and pressure drops are measured. The rheological behaviour of TBAB hydrates slurries can be described using a Bingham fluid model. We highlight that the two rheological parameters, which are the apparent viscosity and the yield shear stress, depend on the volume fraction of crystal of course, but also on the hydrate type, and on the initial concentration of the solution. The yield shear stress is interpreted as the consequence of the Van der Waals inter-particle interaction forces. Finally, possible stratification effects are modelled with a finite difference method. The principle is to calculate particle concentration and velocity profiles following the flow of the slurry. Calculations are validated with experimental velocity profiles published by P. Reghem (2002). This model underlines the influence of the particle distribution in the pipe on pressure drops. (author)

  15. Reduction of Military Vehicle Acquisition Time and Cost through Advanced Modelling and Virtual Simulation (La reduction des couts et des delais d’acquisition des vehicules militaires par la modelisation avancee et la simulation de produit virtuel)

    Science.gov (United States)

    2003-03-01

    aspect of performance and durability than their predecessors. Also, emphasis on reducing radar and infrared signature, and multi-axis thrust vectoring...projectors (Model 9500/P43). Also required are Liquid Crystal Display (LCD) stereoscopic shutter glasses (one set for each user), infrared (IR) emitters...issuing certificate of airworthiness. After the WW2 , it has broadened its scope of activity onto the design of flying apparatus of sorts. The successful

  16. Modeling of creep-fatigue interaction of zirconium {alpha} under cyclic loading at 200 C; Modelisation du comportement et de l`endommagement en fatigue-fluage du zirconium {alpha} a 200C

    Energy Technology Data Exchange (ETDEWEB)

    Vogel, C.

    1996-04-01

    The present work deals with mechanical behaviour of zirconium alpha at 200 deg. C and crack initiation prediction methods, particularly when loading conditions lead to interaction of fatigue and creep phenomena. A classical approach used to study interaction between cyclic effects and constant loading effects does not give easy understanding of experimental results. Therefore, a new approach has been developed, which allow to determine a number of cycles for crack initiation for complex structures under large loading conditions. To study influence of fatigue and creep interaction on crack initiation, a model was chosen, using a scalar variable, giving representation of the material deterioration state. The model uses a non linear cumulating effect between the damage corresponding to cyclic loads and the damage correlated to time influence. The model belongs to uncoupled approaches between damage and behaviour, which is described here by a two inelastic deformations model. This mechanical behaviour model is chosen because it allows distinction between a plastic and a viscous part in inelastic flow. Cyclic damage is function of stress amplitude and mean stress. For the peculiar sensitivity of the material to creep, a special parameter bas been defined to be critical toward creep damage. It is the kinematic term associated to state variables describing this type of hardening in the viscous mechanism. (author).

  17. Modelling of ratchetting with the Chaboche elastoplastic model modified by Burlet and Cailletaud; Modelisation des phenomenes de deformation progressive par le modele elastoplastique de Chaboche modifie par Burlet et Cailletaud

    Energy Technology Data Exchange (ETDEWEB)

    Geyer, P

    1994-01-01

    A fine modelling of the material`s behaviour can be necessary to study the mechanical strength of nuclear power plant`s components under cyclic loads. The modelling of cyclic plasticity made great progress during the past 20 years. Ratchetting is one of the last phenomena for which numerical models have to be improved. We give in this document a state of the art report on research in this field. We notably show the basically different character of ratchetting in uniaxial and biaxial loading tests, usually distinguished as 1D and 2D ratchetting. On the basis of this overview, we selected the kinematic hardening formulation proposed by Burlet and Cailletaud, which we coupled with the Chaboche elastoplastic model with two non linear kinematic hardening variables to improve the modelling of 2D ratchetting. We use the experimental results on the austenitic steel 316L at 20 and 300 deg C under uniaxial loadings (low cycle fatigue) and biaxial loadings (traction-torsion) to study the new model capabilities. We get a good modelling of ratchetting in biaxial loadings. The model has been installed in the ASTER code under the name of UBRLET. It now has to be qualified by component analysis calculations. (author). 25 refs., 30 figs., 11 tabs., 3 annexes.

  18. Analysis and modeling of low voltage electrical network at power line carrier frequencies (3-148.5 kHz); Analyse et modelisation du reseau basse tension aux frequences courants porteurs (3 KHZ-148,5 KHZ)

    Energy Technology Data Exchange (ETDEWEB)

    Duval, G.

    1998-07-01

    Electricite de France (EdF) wishes to establish a physical communication link between his clients and the EdF centres. The final link, i.e. between the high/low voltage transformation substation and the residential clients, being ensured by carrier currents. With this aim, an analysis and a modeling of the low voltage network at the carrier frequencies (3 kHz - 148.5 kHz) has been performed. This work has been carried out in parallel with an experiment involving 3500 apparatuses that use carrier currents. The diversity of the French low voltage networks and the limitations imposed by the EN50065-1 standard about the use of carrier currents in Europe do not favour the development of such carrier current systems. Disturbing voltages and localized impedances represent the main difficulties to get round. Inside accommodations, domotic carrier currents have a reduced range but a higher disturbance amplitude because of the proximity of appliances. A differential mode to common mode conversion phenomenon has been evidenced which generates network couplings and important electromagnetic fields. Energy lines and cables have been analyzed using numerical models. Load peaks have been analyzed using statistical tools in order to take into account the daily fluctuations. The modeling of the network is made in two steps: a double-wire model is considered first. Then a three-phase model is developed which analyzes the inter-phases coupling and the effect of the distribution of clients' loads on each phase. The results of this model are conformable with measurements except for underground networks. As perspectives of future works and beyond todays standard framework, the techniques that allow a sensible increase of communication flow rates have been reviewed. (J.S.)

  19. Study and simulation of irradiated zirconium alloys fracture under type RIA accidental loading conditions; Comprehension et modelisation de la rupture d'alliages de zirconium irradies en conditions accidentelles de type RIA

    Energy Technology Data Exchange (ETDEWEB)

    Le Saux, M. [CEA Saclay, Dept. des Materiaux pour le Nucleaire (DEN/DANS/DMN/SEMI), 91 - Gif-sur-Yvette (France)

    2008-07-01

    The thesis aims to study and simulate the mechanical behavior under Reactivity Initiated Accident loading conditions, of the Zircaloy 4 fuel claddings, irradiated or not. It also aims to characterize and simulate the behavior and the fracture under RIA loading conditions of hydrided Zircaloy 4 non irradiated. This study proposes an experimental approach and a simulation. (A.L.B.)

  20. Modeling by artificial neural networks. Application to the management of fuel in a nuclear power plant; Modelisation par reseaux de neurones. Application a la gestion du combustible dans un reacteur

    Energy Technology Data Exchange (ETDEWEB)

    Gaudier, F

    1999-07-01

    The determination of the family of optimum core loading patterns for Pressurized Water Reactors (PWRs) involves the assessment of the core attributes, such as the power peaking factor for thousands of candidate loading patterns. Despite the rapid advances in computer architecture, the direct calculation of these attributes by a neutronic code needs a lot of of time and memory. With the goal of reducing the calculation time and optimizing the loading pattern, we propose in this thesis a method based on ideas of neural and statistical learning to provide a feed forward neural network capable of calculating the power peaking corresponding to an eighth core PWR. We use statistical methods to deduct judicious inputs (reduction of the input space dimension) and neural methods to train the model (learning capabilities). Indeed, on one hand, a principal component analysis allows us to characterize more efficiently the fuel assemblies (neural model inputs) and the other hand, the introduction of the a priori knowledge allows us to reducing the number of freedom parameters in the neural network. The model was built using a multi layered perceptron trained with the standard back propagation algorithm. We introduced our neural network in the automatic optimization code FORMOSA, and on EDF real problems we showed an important saving in time. Finally, we propose an hybrid method which combining the best characteristics of the linear local approximator GPT (Generalized Perturbation Theory) and the artificial neural network. (author)

  1. On the study of petroleum system operation: contribution of a two-dimensional modeling; Contribution a l`etude du fonctionnement des systemes petroliers: apport d`une modelisation bi-dimensionnelle

    Energy Technology Data Exchange (ETDEWEB)

    Burrus, J.

    1997-07-10

    The third volume of this thesis which main objective is to validate concepts used in hydrocarbon generation and migration models, and more especially the Temispack model developed by IFP, is concerned with the study of over-pressures, sub-compaction and the hydro-mechanical properties of shales. A general conclusion is proposed with the validation of physical and chemico-physical laws, the sedimentary dynamics of basins, and a methodology for the implementation of models in the related basins

  2. Modelling turbulent fluid flows in nuclear and fossil-fired power plants; La modelisation des ecoulements turbulents rencontres dans les reacteurs nucleaires et dans les centrales thermiques a flamme

    Energy Technology Data Exchange (ETDEWEB)

    Viollet, P.L.

    1995-06-01

    The turbulent flows encountered in nuclear reactor thermal hydraulic studies or fossil-fired plant thermo-aerodynamic analyses feature widely varying characteristics, frequently entailing heat transfers and two-phase flows so that modelling these phenomena tends more and more to involve coupling between several branches of engineering. Multi-scale geometries are often encountered, with complex wall shapes, such as a PWR vessel, a reactor coolant pump impeller or a circulating fluidized bed combustion chamber. When it comes to validating physical models of these flows, the analytical process highlights the main descriptive parameters of local flow conditions: tensor characterizing the turbulence anisotropy, characteristic time scales for turbulent flow particle dynamics. Cooperative procedures implemented between national or international working parties can accelerate validation by sharing and exchanging results obtained by the various organizations involved. With this principle accepted, we still have to validate the products themselves, i.e. the software used for the studies. In this context, the ESTET, ASTRID and N3S codes have been subjected to a battery of test cases covering their respective fields of application. These test cases are re-run for each new version, so that the sets of test cases systematically benefit from the gradually upgraded functionalities of the codes. (author). refs., 3 figs., 6 tabs.

  3. Phase equilibria at low temperature for light hydrocarbons-methanol-water-acid gases mixtures: measurements and modelling; Equilibres de phases a basse temperature de systemes complexes CO{sub 2} - hydrocarbures legers - methanol - eau: mesures et modelisation

    Energy Technology Data Exchange (ETDEWEB)

    Ruffine, L.

    2005-10-15

    The need to develop and improve natural gas treatment processes is real. The petroleum industry usually uses separation processes which require phase equilibrium phenomena. Yet, the complexity of the phase equilibria involved results in a lack of data, which in turn limits the development of thermodynamic models. The first part of this work is devoted to experimental investigations for systems containing light hydrocarbons, methanol, water and acid gases. We present a new apparatus that was developed to measure vapor-liquid and vapor-liquid-liquid equilibria. It allowed us to obtain new phase composition data for the methanol-ethane binary system and different mixtures, and also to determine a part of the three phases equilibrium envelope of the same systems. In the second part of this work, we have developed a thermodynamic model based on the CPA equation of state. This choice may be justified by the presence of associating components like methanol, hydrogen sulfide and water in the systems. Such model is necessary for the design of gas treatment plants. Our model provides good results for phase equilibrium calculations for binaries systems without binary interaction parameter in many cases, and describes correctly the vapour-liquid and vapor-liquid-liquid equilibria for complex mixtures. (author)

  4. Characterization and modelling of fluid flows in fissured and fractured media. relation with hydrothermal alterations and paleo-stress quantification; Caracterisation et modelisation des ecoulements fluides en milieu fissure. relation avec les alterations hydrothermales et quantification des paleocontraintes

    Energy Technology Data Exchange (ETDEWEB)

    Sausse, J.

    1998-10-15

    In all materials (rocks, concretes, ceramics,...), the presence of fractures at different scales implies high permeability and often oriented fluid flows. These fluid circulations in fractures induce more or less intense fluid-rock interactions with mineral crystallisation and/or dissolution. These phenomena directly depend on the nature of the fluids and the rocks, the physical and chemical properties of the media and the rate of fluid renewal (permeabilities). Usually, the development of such alterations leads to a massive sealing of the fractures (vein alterations) and of the fissures (fluid inclusion planes and microcracks, pervasive alteration). Therefore, their study brings us precious indications for the understanding of the mechanisms of fluid migrations in fossil systems. A geometrical study of the fracture systems at micro or macroscopic scales, based on the spatial distribution of sealing minerals, is applied to two different granites: the Soultz-sous-Foret granite (Bas-Rhin, France) and the Brezouard granite (Vosges, France). At the macroscopic scale, a new graphical method is proposed in order to study drilling data (Soultz granite). It allows to identify the presence of three independent mineral associations (quartz - illite, calcite-chlorite and hematite) in independent fracture systems characterised by a specific 3D geometry and hydraulic properties. These three types of vein alteration correspond to distinct and non contemporaneous fluid percolations. At the microscopic scale, the reconstitution of crack opening - fluid percolation - crack sealing stages is delicate. However, the study of their geometrical characteristics (orientations, radius, volume densities) and thereby the quantification of their porosities, exchange surfaces and permeabilities, allow to identify their respective roles in the fluid propagation. These microstructures, which are very numerous in granites, imply high but variable matrix permeabilities. This has been confirmed by the modelization of the space-time evolution of the Brezouard granite crack permeability during fluid-rock interactions. The two used permeability models (geometrical or statistical) remain very dependent on the definition of the characteristic opening of fracture or fissure. Real fractures in a rocky mass are characterised by non parallel, flat and thus overlapped walls. The study of these natural fracture surfaces at micro and macroscopic scale is completed by a theoretical modelization of their hydro-mechanical behaviour. This work indicates the influence of the surface roughness on the fluid flow as well as the propagation of the alteration. These fractures were formed and percolated under a particular tectonic regime that controls their orientation. Numerous quartz veins in the Soultz granite are opened and sealed during the Oligocene extension. The characteristic fluid pressure of these opening - sealing stages are quantified thanks to fluid inclusion studies. These inclusions are located in secondary quartz which seal the veins. A new method of paleo-stress quantification is proposed, based on the knowledge of this fluid pressure. It takes i) the geometrical distribution of the vein poles, ii) some empirical considerations of rupture criteria, and iii) the fluid pressures into account. (author)

  5. On the study of petroleum system operation: contribution of a two-dimensional modeling; Contribution a l`etude du fonctionnement des systemes petroliers: apport d`une modelisation bi-dimensionnelle

    Energy Technology Data Exchange (ETDEWEB)

    Burrus, J

    1997-07-10

    The aim of the thesis is to validate concepts used in hydrocarbon generation and migration models; the model considered is the Temispack model developed by IFP, and the validation is based on the investigation of the thermal and hydraulic evolution in various sedimentary basins. It is shown that, in general, the thermal history of sediments is influenced by external processes (sedimentation rates, lithology, climate changes, regional-scale groundwater circulations) which frequently overprint internal processes (variations of crustal/mantle heat flow). It is found that external processes can frequently explain past thermal events that were erroneously attributed to internal causes (tectonic-thermal events). The origin of over-pressures in young basins with high sedimentation rates is shown to be generally related to compaction disequilibrium. Shale permeability values calibrated against overpressure profiles are consistent with experimental constraints. Compaction models predict too-high porosity in over-pressured sediments; this inconsistency is shown to be related to an inadequate definition of the Biot coefficient. In intracratonic basins with low sedimentation rates, diagenesis and fracturing are responsible for the large variability of shale permeability. Hydrocarbon generation models based on Arrhenius kinetics, and kinetic parameters calibrated on Rock Eval pyrolysis experiments are shown to be consistent with observations. Hydrocarbon expulsion and migration can be approximated by a multiphase Darcy equation using pseudo relative permeabilities. Migration pathways are shown to be very sensitive to the stratigraphic organization of basins. The volume 1 presents a bibliographical review, the Temispack model, and the geodynamics of a passive-type margin, the Gulf of Lion

  6. Study of a class of photovoltaic systems using a bond graph approach. Modeling, analysis and control; Etude d'une classe de systemes photovoltaiques par une approche bond graph. Modelisation, analyse et commande

    Energy Technology Data Exchange (ETDEWEB)

    Andoulsi, R.

    2001-12-01

    We present in this thesis a study of a class of photovoltaic system by a bond graph approach. This study concerns the modelling, the analysis and the control of some configurations including PV generator, DC/DC converters and DC motor-pumps. The modelling of the different elements of a photovoltaic system is an indispensable stage that must precede all application of sizing, identification or simulation. However, theses PV systems are of hybrid type and their modelling is complex. It is why we use a unified modelling approach based on the bond graph technique. This methodology is completely systematic and has a sufficient flexibility for allowing the introduction of different components in the system. In the first chapter, we recall the principle of functioning of a photovoltaic generator and we treat mainly the MPPT (Maximum Power Point Tracking) working. In the second chapter, we elaborate bond graph models of various photovoltaic system configurations. For the PV source, we elaborate, in a first stage, a complete model taking into account the various physical phenomena influencing the quality of the PV source. In a second stage, we deduce a reduced bond graph model more easy to use for analysis and control purposes. For the DC/DC converters, we recall the bond graph modelling of switching elements and the average bond graph of the DC/DC converters developed in the literature. Thus, we deduce the bond graphs models of the various DC/DC converters to be used. The third chapter presents a dynamic study of some configurations stability in linear procedure. In the fourth chapter, we study the feasibility of non linear controllers by input/output linearization for some configurations of PV systems. In this study, we use the concept of inverse bond graph to determine, by a bond graph approach, the expression of the control input and the nature of the stability of the internal dynamics (dynamics of zeros). The fifth chapter is dedicated for the presentation of some experimental results. These results are relative to the achieved experimental devices: characterization system for photovoltaic modules and fields; photovoltaic system using a PV generator coupled to a DC motor-pump through a buck converter. This system uses a non linear control for MPPT running. (authors)

  7. Inverse modeling for the optimization of primary sources of atmospheric pollution at a regional scale; Modelisation inverse pour l'optimisation des sources primaires de pollution atmospherique a l'echelle regionale

    Energy Technology Data Exchange (ETDEWEB)

    Pison, I

    2005-12-15

    Atmospheric pollution at a regional scale is the result of various interacting processes: emissions, chemistry, transport, mixing and deposition of gaseous species. The forecast of air quality is then performed by models, in which the emissions are taken into account through inventories. The simulated pollutant concentrations depend highly on the emissions that are used. Now inventories that represent them have large uncertainties. Since it would be difficult today to improve their building methodologies, there remains the possibility of adding information to existing inventories. The optimization of emissions uses the information that is available in measurements to get the inventory that minimizes the difference between simulated and measured concentrations. A method for the inversion of anthropogenic emissions at a regional scale, using network measurements and based on the CHIMERE model and its adjoint, was developed and validated. A kriging technique allows us to optimize the use of the information available in the concentration space. Repeated kriging-optimization cycles increase the quality of the results. A dynamical spatial aggregation technique makes it possible to further reduce the size of the problem. The NO{sub x} emissions from the inventory elaborated by AIRPARIF for the Paris area were inverted during the summers of 1998 and 1999, the events of the ESQUIF campaign being studied in detail. The optimization reduces large differences between simulated and measured concentrations. Generally, however, the confidence level of the results decreases with the density of the measurement network. Therefore, the results with the higher confidence level correspond to the most intense emission fluxes of the Paris area. On the whole domain, the corrections to the average emitted mass and to the matching time profiles are consistent with the estimate of 15% obtained during the ESQUIF campaign. (author)

  8. Modeling of the climate system and of its response to a greenhouse effect increase; Modelisation du systeme climatique et de sa reponse a une augmentation de l'effet de serre

    Energy Technology Data Exchange (ETDEWEB)

    Li, L. [Universite Pierre et Marie Curie, CNRS, Lab. de Meteorologie Dynamique, 75 - Paris (France)

    2005-07-01

    The anthropic disturbance of the Earth's greenhouse effect is already visible and will enhance in the coming years or decades. In front of the rapidity and importance of the global warming effect, the socio-economical management of this change will rise problems and must be studied by the scientific community. At the modeling level, finding a direct strategy for the validation of climate models is not easy: many uncertainties exist because energy transformations take place at a low level and several processes take place at the same time. The variability observed at the seasonal, inter-annual or paleo- scales allows to validate the models at the process level but not the evolution of the whole system. The management of these uncertainties is an integral part of the global warming problem. Thus, several scenarios can be proposed and their risk of occurrence must be estimated. This paper presents first the greenhouse effect, the climatic changes during geologic times, the anthropic disturbance of the greenhouse effect, the modeling of climate and the forecasting of its evolution. (J.S.)

  9. Modeling in fast dynamics of accidents in the primary circuit of PWR type reactors; Modelisation en dynamique rapide d'accidents dans le circuit primaire des reacteurs a eau pressurisee

    Energy Technology Data Exchange (ETDEWEB)

    Robbe, M.F

    2003-12-01

    Two kinds of accidents, liable to occur in the primary circuit of a Pressurized Water Reactor and involving fast dynamic phenomena, are analyzed. The Loss Of Coolant Accident (LOCA) is the accident used to define the current PWR. It consists in a large-size break located in a pipe of the primary circuit. A blowdown wave propagates through the circuit. The pressure differences between the different zones of the reactor induce high stresses in the structures of the lower head and may degrade the reactor core. The primary circuit starts emptying from the break opening. Pressure decreases very quickly, involving a large steaming. Two thermal-hydraulic simulations of the blowdown phase of a LOCA are computed with the Europlexus code. The primary circuit is represented by a pipe-model including the hydraulic peculiarities of the circuit. The main differences between both computations concern the kind of reactor, the break location and model, and the initialization of the accidental operation. Steam explosion is a hypothetical severe accident liable to happen after a core melting. The molten part of the core (called corium) falls in the lower part of the reactor. The interaction between the hot corium and the cold water remaining at the bottom of the vessel induces a massive and violent vaporization of water, similar to an explosive phenomenon. A shock wave propagates in the vessel. what can damage seriously the neighbouring structures or drill the vessel. This work presents a synthesis of in-vessel parametrical studies carried out with the Europlexus code, the linkage of the thermal-hydraulic code Mc3d dedicated to the pre-mixing phase with the Europlexus code dealing with the explosion, and finally a benchmark between the Cigalon and Europlexus codes relative to the Vulcano mock-up. (author)

  10. On the study of petroleum system operation: contribution of a two-dimensional modeling; Contribution a l`etude du fonctionnement des systemes petroliers: apport d`une modelisation bi-dimensionnelle

    Energy Technology Data Exchange (ETDEWEB)

    Burrus, J

    1997-07-10

    The second volume of this thesis which main objective is to validate concepts used in hydrocarbon generation and migration models, and more especially the Temispack model developed by IFP, is concerned with the study of petroleum genesis and migration in the Viking Graben, the Williston basin, the Paris basin, and in deltas such as Gulf Coast and the Mahakam delta

  11. Modelling and development of estimation and control algorithms: application to a bio process; Modelisation et elaboration d`algorithmes d`estimation et de commande: application a un bioprocede

    Energy Technology Data Exchange (ETDEWEB)

    Maher, M

    1995-02-03

    Modelling, estimation and control of an alcoholic fermentation process is the purpose of this thesis. A simple mathematical model of a fermentation process is established by using experimental results obtained on the plant. This nonlinear model is used for numerical simulation, analysis and synthesis of estimation and control algorithms. The problem of state and parameter nonlinear estimation of bio-processes is studied. Two estimation techniques are developed and proposed to bypass the lack of sensors for certain physical variables. Their performances are studied by numerical simulation. One of these estimators is validated on experimental results of batch and continuous fermentations. An adaptive control by law is proposed for the regulation and tracking of the substrate concentration of the plant by acting on the dilution rate. It is a nonlinear control strategy coupled with the previous validated estimator. The performance of this control law is evaluated by a real application to a continuous flow fermentation process. (author) refs.

  12. Long-term analyses of snow dynamics within the french Alps on the 1900-2100 period. Analyses of historical snow water equivalent observations, modelisations and projections of a hundred of snow courses.

    Science.gov (United States)

    Mathevet, T.; Joel, G.; Gottardi, F.; Nemoz, B.

    2017-12-01

    The aim of this communication is to present analyses of climate variability and change on snow water equivalent (SWE) observations, reconstructions (1900-2016) and scenarii (2020-2100) of a hundred of snow courses dissiminated within the french Alps. This issue became particularly important since a decade, in regions where snow variability had a large impact on water resources availability, poor snow conditions in ski resorts and artificial snow production. As a water resources manager in french mountainuous regions, EDF (french hydropower company) has developed and managed a hydrometeorological network since 1950. A recent data rescue research allowed to digitize long term SWE manual measurments of a hundred of snow courses within the french Alps. EDF have been operating an automatic SWE sensors network, complementary to the snow course network. Based on numerous SWE observations time-series and snow accumulation and melt model (Garavaglia et al., 2017), continuous daily historical SWE time-series have been reconstructed within the 1950-2016 period. These reconstructions have been extented to 1900 using 20 CR reanalyses (ANATEM method, Kuentz et al., 2015) and up to 2100 using GIEC Climate Change scenarii. Considering various mountainous areas within the french Alps, this communication focuses on : (1) long term (1900-2016) analyses of variability and trend of total precipitation, air temperature, snow water equivalent, snow line altitude, snow season length , (2) long term variability of hydrological regime of snow dominated watersheds and (3) future trends (2020 -2100) using GIEC Climate Change scenarii. Comparing historical period (1950-1984) to recent period (1984-2016), quantitative results within a region in the north Alps (Maurienne) shows an increase of air temperature by 1.2 °C, an increase of snow line height by 200m, a reduction of SWE by 200 mm/year and a reduction of snow season length by 15 days. These analyses will be extended from north to south of the Alps, on a region spanning 200 km. Caracterisation of the increase of snow line height and SWE reduction are particularly important at a local and watershed scale. This long term change of snow dynamics within moutainuous regions both impacts snow resorts and artificial snow production developments and multi-purposes dam reservoirs managments.

  13. A multi-agent design for a pressurized water reactor (P.W.R.) control system; Modelisation multi-agents pour la conduite d'un reacteur a eau sous pression (REP)

    Energy Technology Data Exchange (ETDEWEB)

    Aimar-Lichtenberger, M. [Paris-11 Univ., 91 - Orsay (France)

    1999-01-01

    This PhD work is in keeping with the complex industrial process control. The starting point is the analysis of control principles in a Pressurized Water Reactor (P.W.R). In order to cope with the limits of the present control procedures, a new control organisation by objectives and means is defined. This functional organisation is based on the state approach and is characterized by the parallel management of control functions to ensure the continuous control of the installation essential variables. With regard to this complex system problematic, we search the most adapted computer modeling. We show that a multi-agent system approach brings an interesting answer to manage the distribution and parallelism of control decisions and tasks. We present a synthetic study of multi-agent systems and their application fields.The choice of a multi-agent approach proceeds with the design of an agent model. This model gains experiences from other applications. This model is implemented in a computer environment which combines the mechanisms of an object language with Prolog. We propose in this frame a multi-agent modeling of the control system where each function is represented by an agent. The agents are structured in a hierarchical organisation and deal with different abstraction levers of the problem. Following a prototype process, the validation is realized by an implementation and by a coupling to a reactor simulator. The essential contributions of an agent approach turn on the mastery of the system complexity, the openness, the robustness and the potentialities of human-machine cooperation. (author)

  14. Thermodynamic modelling of the absorption of acid gas in mixed solvent (water-di-ethanolamine-methanol); Modelisation thermodynamique de l'absorption des gaz acides dans un solvant mixte (eau-diethanolamine-methanol)

    Energy Technology Data Exchange (ETDEWEB)

    Habchi tounsi, K.N.

    2003-10-01

    This work is related to the development of new processes about gas sweetening with mixed solvent coupling a chemical one (aqueous solution of di-ethanolamine) and a physical one (Methanol). These systems are electrolyte solutions constituted by ions and molecular species related each others by chemical reactions. This work is also relevant to the problematic of solvent mixtures (water-methanol). In a first stage we focus our interest over the measurement of original data covering a large experimental interval: five compositions in condition of pressures and temperatures up to 30 and 120 deg C respectively. In a second stage the simultaneous representation of chemical and phase equilibrium was successfully realised. The non stoichiometric method is used for the determination of chemical equilibrium. The heterogeneous method (Peng Robinson + NRTL electrolyte) is used for the representation of vapour liquid equilibrium. (author)

  15. Hygro-thermo-aeraulic modeling of multi-zone buildings. Proposal of a strategy for the resolution of the coupled system; Modelisation hygro-thermo-aeraulique des batiments multizones. Proposition d'une strategie de resolution du systeme couple

    Energy Technology Data Exchange (ETDEWEB)

    Woloszyn-Vallon, M.

    1999-11-01

    The two criteria necessary for the thermal design of buildings - user's comfort and energy efficiency - can lead to contradictory recommendations. In the analyses of both aspects, air moisture content can be an important factor. However, in most existing computer software, moisture is either neglected or represented in a very simplified way. Often only the airborne moisture is represented and the interaction with hygroscopic materials is neglected. We are interested hare in the construction of a comprehensive and reliable tool, able to analyse moisture propagation in a multizone space. All physical phenomena important for correct description of the reality should be integrated. The numerical reliability of the tool should also be ensured in order to enable its industrial use. The results of this work will be applied to CLIM2000, a modular building simulation environment developed by EDF (French Electricity Company). Moisture propagation in a multizone space is a complex phenomenon, especially if the interaction with energy and airflow is represented. However, at the scale of a complete building, four main elements can be distinguished: airborne moisture transport; vapour condensation on cold surface and in the air volume; vapour absorption by hygroscopic materials; sources of vapour (metabolism, housekeeping). In respect to the hypothesis of a multizone model, a consistent set of mathematical models is elaborated. Full interaction among moisture, energy and airflow is represented, enabling simulations of the integrated moisture-energy-airflow behaviour of a multizone building. In order to verify the ability of the proposed model to represent the real situations, its predictions are compared to experimental data. The data were obtained in a fully furnished test house belonging to Building Research Establishment (UK). This experimentation permits analysis of moisture spread in the house and especially the importance of the airborne transport and the influence of hygroscopic materials. Experimental conditions are simulated using the proposed model. A good overall performance of the model can be sent, if the vapour absorbed and released by building materials is represented. We are interested in a dynamic system described by a set of algebro-diffeential equations. To start the time integration of the differential equations, we need to fix a starting point. The best choice is given by the solution of the set of non-linear algebraic equations corresponding to initial stationary date. However, the resolution of this set is often found impossible. To face the numerical resolution of our problems, we called on block methods. The idea is to divide judiciously the system of equations, in such a way as to get an easy solution for each block. The physical interactions between blocks are then numerically ensured by successive global interations. After analysing our system, three principal blocks are identified: airflow block, describing inter-zonal air movements; energy block, describing temperatures in each zone; moisture block, describing air moisture content in each zone. The airflow block has a special role; it determines moisture and energy transport. A strategy to update the values of variables is also adapted to physical interaction among systems and allows rapid convergence. The proposed strategy is validated on a set of benchmark tests designed by CLIM2000 users. (author)

  16. Developpement d'un module microbiologique dÉdiÉ À la modelisation hydrobiogÉochimique et application À la mobilitÉ de l'arsenic

    OpenAIRE

    Parmentier , Marc

    2006-01-01

    The geochemistry of natural system as old mine site is influenced by biological activity. Only informatics tools taking into account geochemistry, hydrodynamics and microbiology will be able to analyse, and then predict, this complex system evolution. For about ten years numerical tools, as CHESS and HYTEC, are able to take into account most of the geochemical and hydrodynamical processes present in soil. The goal of this work is to extend this tools to the microbiologic activity. CHESS calcu...

  17. Mathematical modelling of municipal solid waste incineration and thermodynamic study of the behaviour of heavy metals; Modelisation de l'incineration sur grille d'ordures menageres et approche thermodynamique du comportement des metaux lourds

    Energy Technology Data Exchange (ETDEWEB)

    Menard, Y

    2003-07-15

    The present dissertation describes experimental and theoretical investigations undertaken for the mathematical modelling of municipal solid waste (MSW) incineration in a grate furnace and the thermodynamic study of the speciation of heavy metals (HM), originally contained into MSW, during combustion. Thermogravimetric and gaseous analysis (mass spectrometry and gas chromatography) experiments were performed on MSW samples to get pyrolysis kinetics and to quantify the gaseous species that evolve during the primary reactions of devolatilization. Other experiments were carried out in a fixed bed pilot-scale reactor: the combustion of two types of solids (wood chips and MSW) was studied, and the influence of operating conditions (flow rate, staging and temperature of the primary air) as well as fuel characteristics (moisture content, inert material fraction, lower calorific value) was investigated. A mathematical model was developed for simulating the combustion of a solid fuel, either in a fixed bed reactor or on the grate of an incineration plant. It has been validated by comparison of the calculated results and the experiments carried out on the pilot. Thanks to this model, we have been able to localize the different processes taking place in the fuel bed and to evaluate the influence of the operating conditions on the combustion efficiency. Numerical simulations of the gas flow and combustion in the post-combustion chamber and the heater of an incineration plant were performed using the CFD code FLUENT. The local thermal conditions as well as local gaseous species concentrations obtained from these simulations were eventually used to carry out thermodynamic calculations of the speciation of HM during incineration. (author)

  18. Modelling of air flows in pleated filters and of their clogging by solid particles; Modelisation des ecoulements d'air et du colmatage des filtres plisses par des aerosols solides

    Energy Technology Data Exchange (ETDEWEB)

    Del Fabbro, L

    2002-07-01

    The devices of air cleaning against particles are widely spread in various branches of industry: nuclear, motor, food, electronic,...; among these devices, numerous are constituted by pleated porous media to increase the surface of filtration and thus to reduce the pressure drop, for given air flow. The objective of our work is to compensate a lack evident of knowledge on the evolution of the pressure drop of pleated filter during the clogging and to deduct a modelling from it, on the basis of experiments concerning industrial filters of nuclear and car types. The obtained model is a function of characteristics of the filtering medium and pleats, of the characteristics of solid particles deposited on the filter, of the mass of particles and of the aeraulic conditions of air flow. It also depends on data on the clogging of flat filters of equivalent medium. To elaborate this model of pressure drop, an initial stage was carried out in order to characterize, experimentally and numerically, the pressure drop and the distribution of air flow in clean pleated filters of nuclear (high efficiency particulate air filter, in fiberglasses) and car (mean efficiency filter, in fibers of cellulose) types. The numerical model allowed to understand the fundamental role played by the aeraulic resistance of the filtering medium. From an non-dimensional approach, we established a semi-empirical model of pressure drop for a clean pleated filter valid for both studied types of medium; this model is used of first base for the development of the final model of clogging. The study of the clogging of the filters showed the complexity of the phenomenon dependent mainly on a reduction of the surface of filtration. This observation brings us to propose a clogging of pleated filters in three phases. Both first phases are similar in those observed for flat filters, while last phase corresponds to a reduction of the surface of filtration and leads a strong increase of the filter pressure drop, for a constant air velocity. Our work also deals with the study of the influence of the particles diameters, filtration velocity or still geometrical parameters of the pleating of filters on the values of the pressure drop during the clogging. The obtained results show indeed the interaction of the various parameters and put in evidence the dependence of the pressure drop of a filter with the structure of cake which depends itself on the filtration velocity and of geometrical parameters of pleats. (author)

  19. Modelling the fatigue behaviour of a stratified glass-epoxy composite: theoretical and experimental aspects; Modelisation du comportement en fatigue d`un composite stratifie verre-epoxyde: aspects theoriques et experimentaux

    Energy Technology Data Exchange (ETDEWEB)

    Verdiere, N.; Suri, C. [Laboratoire de mecanique appliquee, 25 - Besancon (France)

    1996-01-01

    Composite materials are used in the manufacture of water transport pipework for use in PWR`s. Estimation of their life expectancy relies on long and costly tests (ASTM D2992B standard). It would be extremely advantageous to have another method relying only on short laboratory tests which could be based on a mechanical behaviour and damage model. For several years, the Laboratoire de Mecanique Appliquee de Besancon has been developing a mechanical behaviour model for composite material tubes for different types of multiaxial stresses. However, this model does not take into account the fatigue behaviour. We therefore needed to find out how this type of stress could be incorporated into the model. To this end, research was undertaken in the form of a thesis (by E. Joseph) both to perfect the multiaxial fatigue stress testing machines and to take into account this type of behaviour in the mechanical model. This study covered glass fibre/epoxy resin composite material tubes and allowed their behaviour to be modelled. An important part of the work concerned the instrumentation and adaptation of test machines which hitherto did not exist so that the research could be carried out. For each of the stress axes (traction, internal pressure without vacuum effect ({Sigma}{sup zz}=0) and internal pressure with vacuum effect ({Sigma}{sup zz}=1/2{Sigma}{sup {theta}{theta}})), instantaneous behaviour was studied. Three stress levels and frequency values were used to define the fatigue behaviour. (authors). 23 refs., 41 figs., 5 tabs.

  20. Simulation of uranium oxides reduction kinetics by hydrogen. Reactivities of germination and growth; Modelisation de la cinetique de reduction d`oxydes d`uranium par l`hydrogene. Reactivites de germination et de croissance

    Energy Technology Data Exchange (ETDEWEB)

    Brun, C

    1997-12-04

    The aim of this work is to simulate the reduction by hydrogen of the tri-uranium octo-oxide U{sub 3}O{sub 8} (obtained by uranium trioxide calcination) into uranium dioxide. The kinetics curves have been obtained by thermal gravimetric analysis, the hydrogen and steam pressures being defined. The geometrical modeling which has allowed to explain the trend of the kinetics curves and of the velocity curves is an anisotropic germination-growth modeling. The powder is supposed to be formed of spherical grains with the same radius. The germs of the new UO{sub 2} phase appear at the surface of the U{sub 3}O{sub 8} grains with a specific germination frequency. The growth reactivity is anisotropic and is very large in the tangential direction to the grains surface. Then, the uranium dioxide growths inside the grain and the limiting step is the grain surface. The variations of the growth reactivity and of the germination specific frequency in terms of the gases partial pressures and of the temperature have been explained by two different mechanisms. The limiting step of the growth mechanism is the desorption of water in the uranium dioxide surface. Concerning the germination mechanism the limiting step is a water desorption too but in the tri-uranium octo-oxide surface. The same geometrical modeling and the same germination and growth mechanisms have been applied to the reduction of a tri-uranium octo-oxide obtained by calcination of hydrated uranium trioxide. The values of the germination specific frequency of this solid are nevertheless weaker than those of the solid obtained by direct calcination of the uranium trioxide. (O.M.) 45 refs.

  1. Modelling of the mechanical behaviour and damage of clay-stones: application to the East argillite; Modelisation du comportement mecanique des argiles raides avec prise en compte de l'endommagement: application aux argilites de l'Est

    Energy Technology Data Exchange (ETDEWEB)

    Aublive-Conil, N

    2003-03-15

    The storage in deep geological formation is one of the solutions retained by France for the management of highly long life radioactive waste. The retained host rock is a clay-stone named East argillite located in the departments of Meuse and Haute-Marne. A thermodynamic formulation is used to propose a rheological model, which reproduces the mechanical behavior of clay-stones. Initially, an anisotropic damage plastic model was formulated in order to describe material degradations. Then, the damage plastic model is reformulated in order to taken into account the damage influence on the hydraulic behavior of porous material. The numerical simulations correctly reproduce the mechanical behavior of East Argillites but also the anisotropy of the hydraulic behavior introduced by the damage effect. (author)

  2. Modelling and characterization of the PEM fuel cell to study interactions with power converters; Modelisation et caracterisation de la pile pem pour l'etude des interactions avec les convertisseurs statiques

    Energy Technology Data Exchange (ETDEWEB)

    Fontes, G

    2005-09-15

    The climatic and energy challenges were now clearly stated. The use of hydrogen is one of the best ways which gives many hopes. Fuel cells are an essential link in the chain of the use of hydrogen. Thus, a lot of studies have been undertaken throughout the world on fuel cells in many fields of physics. Concerning the field of power electronics, a lot of work on distributed generation technologies using fuel cells has been realised too and a great number of power converters dedicated to fuel cells have been studied. However, very few studies have been undertaken on the interactions between fuel cells and power converters. The goals of this work are to study interactions between fuel cells and power converters. Some requirements for the power electronic engineer can follow from this work. This work proposes high signal dynamic models of a H{sub 2}/O{sub 2} PEM fuel cell. These models include the different physical and chemical phenomena. Specific methods based on a limited number of original experiments (low frequency current sweeps) allow to extract the model parameters. These models are used to study the interactions between fuel cells and power converters which are the most used: buck chopper, boost chopper, inverters. The important part of the double layer capacitors has thus been underlined: they can filter the current harmonics created by the power converters. Finally, some choices of filtering elements to be connected to the fuel cell are proposed. (author)

  3. Conception and modelling of photo-detection pixels. PIN photodiodes conceived in amorphous silicon for particles detection; Conception et modelisation de pixels de photodetection: Photodiodes PIN en silicium amorphe en vue de leurs utilisations comme detecteurs de particules

    Energy Technology Data Exchange (ETDEWEB)

    Negru, R

    2008-06-15

    The research done has revealed that the a-Si:H is a material ideally suited for the detection of particles, while being resistant to radiation. It also has a low manufacturing cost, is compatible with existing technology and can be deposited over large areas. Thus, despite the low local mobility of charges (30 cm{sup 2}/V/s), a-Si:H is a material of particular interest for manufacturing high-energy particle detection pixels. As a consequence of this, we have studied the feasibility of an experimental pixel stacked structure based on a-Si:H as a basic sensor element for an electromagnetic calorimeter. The structure of such a pixel consists of different components. First, a silicon PIN diode in a-Si:H is fabricated, followed by a bias resistor and a decoupling capacitor. Before such a structure is made and in order to optimize its design, it is essential to have an efficient behavioural model of the various components. Thus, our primary goal was to develop a two-dimensional physical model of the PIN diode using the SILVACO finite element calculation software. This a-Si:H PIN diode two-dimensional physical model allowed us to study the problem of crosstalk between pixels in a matrix structure of detectors. In particular, we concentrated on the leakage current and the current generated in the volume between neighbouring pixels. The successful implementation of this model in SPICE ensures its usefulness in other professional simulators and especially its integration into a complete electronic structure (PIN diode, bias resistor, decoupling capacity and low noise amplifier). Thanks to these modelling tools, we were able to simulate PIN diode structures in a-Si:H with different thicknesses and different dimensions. These simulations have allowed us to predict that the thicker structures are relevant to the design of the pixel detectors for high energy physics. Applications in astronomy, medical imaging and the analysis of the failure of silicon integrated circuits, can also be envisioned. From a technological point of view, we focused on controlling the entire production chain (the choice of the electrode's material, the deposition sequence, the design of the masks and the clean room lithography). Thus, for example, we propose that the optimum material for the resistors and capacitors electrodes is Titanium, but due to its work function it is not recommended for manufacturing PIN diodes. (author)

  4. Modelization, fabrication and evaluation avalanche photodiodes polarized in Geiger mode for the single photon in astrophysics applications; Modelisation, fabrication et evaluation des photodiodes a avalanche polarisees en mode Geiger pour la detection du photon unique dans les applications Astrophysiques

    Energy Technology Data Exchange (ETDEWEB)

    Pellion, D

    2008-12-15

    The genesis of the work presented in this this is in the field of very high energy astrophysics. One century ago, scientists identified a new type of messenger coming from space: cosmic rays. This radiation consists of particles (photons or other) of very high energy which bombard the Earth permanently. The passage of cosmic radiations in the Earth's atmosphere results in the creation of briefs luminous flashes (5 ns) of very low intensity (1 pW), a Cherenkov flash, and then becomes visible on the ground. In the current state of the art the best detector of light today is the Photomultiplier tube (PMT), thanks to its characteristics of sensitivity and speed. But there are some drawbacks: low quantum efficiency, cost, weight etc. We present in this thesis a new alternative technology: silicon photon counters, made of photodiodes polarized in Geiger mode. This operating mode makes it possible to obtain an effect of multiplication comparable to that of the PMT. A physical and electrical model was developed to reproduce the behaviour of this detector. We then present in this thesis work an original technological process allowing the realization of these devices in the Center of Technology of LAAS-CNRS, with the simulation of each operation of the process. We developed a scheme for the electric characterization of the device, from the static mode to the dynamic mode, in order to check conformity with SILVACO simulations and to the initial model. Results are already excellent, given this is only a first prototype step, and comparable with the results published in the literature. These silicon devices can intervene in all the applications where there is a photomultiplier and replace it. The applications are thus very numerous and the growth of the market of these detectors is very fast. We present a first astrophysical experiment installed at the 'Pic du Midi' site which has detected Cherenkov flashes from cosmic rays with this new semiconductor technology. (author)

  5. 2D compositional modeling of petroleum generation, expulsion and migration in the Southern compartment of the Reconcavo Basin, Brazil; Modelisation compositionnelle 2D de la genese, expulsion et migration du petrole dans le compartiment sud du Bassin de Reconcavo, Bresil

    Energy Technology Data Exchange (ETDEWEB)

    Barroz Penteado, H.L. de

    1999-01-07

    The Reconcavo Basin is part of a rift formed between the Late Jurassic and the Early Cretaceous in northeastern Brazil. The objective of this thesis was the compositional modeling of petroleum generation, expulsion and migration along a cross-section in the Southern Compartment of the basin with the Temispack basin simulation software. A geochemical study of the lacustrine shales of the Gomo Member (Candelas Fm.) has been performed to determine their petroleum potential, the evolution of maturation with depth and changes in petroleum composition. Hydrogen indices of immature kerogens (400-850 mg/g TOC) were shown to be higher than those of whole rocks, thus indicating a retention of Rock-Eval pyrolysis products in the mineral matrix of these type I source rocks. Saturates (30-50% of organic extracts in the immature zone) increase both in absolute and in relative (60-80%) terms in the oil window (2000-2600 m) because of a partial secondary cracking of NSOs and aromatics. After having tested several scenarios of geodynamic evolution between the Aptian and the Oligocene, a variable thickness of post-rift sediments (maximum of 1200 m) has been shown to be necessary to calibrate maturity parameters. Petroleum migration has been modeled to understand migration pathways as well as the role of faults as drains. Thus, two petroleum migration systems have been identified for the Dom Joao and Cexis accumulations. Petroleum compositional variations have been modeled by coupling the processes of retention and secondary cracking. A good calibration of compositions was obtained with secondary cracking parameters for NSOs and aromatics which are close to those of the main primary cracking reaction of a type I kerogen, coupled with a retention of 50% of NSOs within the source rocks. (author)

  6. Analysis of the reactivity of sulphur compounds in petroleum cuts: kinetics and modelling of hydro-treating; Analyse de la reactivite des composes soufres dans les coupes petrolieres: cinetique et modelisation de l'hydrotraitement

    Energy Technology Data Exchange (ETDEWEB)

    Lopez Garcia, C

    2000-12-01

    The study of the hydro-treating of middle distillates comprised the following steps: - Identification and reactivity study of the sulphur compounds present in these petroleum cuts; - Modelling of the process by a chemical kinetic approach. The hydro-treating of middle distillates is a refining process that allows elimination of organic compounds containing sulphur, nitrogen, oxygen and metals. The process also hydrogenates the aromatic compounds providing improved cetane index gas-oils while respecting the regulations that severely limit the content of sulphur compounds. The extension and the improvement of a kinetic model for the hydro-treating of LCO gas-oils (light cycle oil gas-oils) are presented in this work. In order to improve the hydro-desulfurization model predictions, a detailed identification of the sulphur compounds contained in LCO gas-oils was carried out using gas chromatography with a sulphur chemiluminescence detector (GC-SCD). The most refractory sulphur compounds (alkyl-di-benzothiophenes) were identified and lumped into different families. Based on a lumped reaction scheme with a Langmuir-Hinshelwood representation, the model takes into account the influence of temperature, total pressure and hydrogen sulphide partial pressure on the reaction rates for hydro-desulfurization, hydro-denitrogenation and hydro-de-aromatization. The model parameter estimation was based on experiments that were carried out on a micro-pilot unit using an industrial sulfided NiMo/Al{sub 2}O{sub 3} catalyst and LCO feedstocks. The analytical study of the sulphur compounds was also extended to the case of straight run gas-oils (SR). For these feedstocks, a method using high-resolution mass spectrometry coupled with gas chromatography (GC-HRMS) was developed. In this way, the kinetic model can now be extended for the SR gas-oil hydro-treating or for LCO-SR mixtures. (author)

  7. Design, modeling and optimization of poly-air gap actuators with global coils: application to multi-rod linear structures; Conception, modelisation et optimisation des actionneurs polyentrefers a bobinages globaux: application aux structures lineaires multi-tiges

    Energy Technology Data Exchange (ETDEWEB)

    Cavarec, P.E.

    2002-11-15

    The aim of this thesis is the study and the conception of splitted structures of global coil synchronous machines for the maximization of specific torque or thrust. This concept of machine, called multi-air gap, is more precisely applied to the elaboration of a new linear multi-rods actuator. It is clearly connected to the context of direct drive solutions. First, a classification of different electromagnetic actuator families gives the particular place of multi-air gaps actuators. Then, a study, based on geometrical parameters optimizations, underlines the interest of that kind of topology for reaching very high specific forces and mechanical dynamics. A similitude law, governing those actuators, is then extracted. A study of mechanical behaviour, taking into account mechanic (tolerance) and normal forces (guidance), is carried out. Hence, methods for filtering the ripple force, and decreasing the parasitic forces without affecting the useful force are presented. This approach drives to the multi-rods structures. A prototype is then tested and validates the feasibility of that kind of devices, and the accuracy of the magnetic models. This motor, having only eight rods for an active volume of one litre, reaches an electromagnetic force of 1000 N in static conditions. A method for estimate optimal performances of multi-rods actuators under several mechanical stresses is presented. (author)

  8. Modeling of ultrasonic wave propagation in composite materials obtained by the resin transfer molding process; Modelisation de la propagation ultrasonore dans les materiaux composites obtenus par le procede de fabrication RTM (Resin Transfer Molding)

    Energy Technology Data Exchange (ETDEWEB)

    Lonne, S.

    2003-11-01

    The Resin Transfer Molding process for manufacturing composite materials is used to produce parts of complex shape. During the ultrasonic examination of such parts, attenuation is measured to characterize possible porosity content (a potential defect in this material). However, strong variation of attenuation is observed including on sound plates. The present study aims at explaining this by developing a model for ultrasonic propagation and attenuation in such parts which complex microstructure exhibits a multiple-scale aspect. An original model has been developed to predict attenuation at the elementary scale of an unidirectional layer of carbon fibers in an epoxy matrix. It couples multiple scattering by fibers and viscoelastic losses phenomena. It has been experimentally validated and applies to arbitrary two-phase fiber reinforced composites whatever the fiber volume fraction. At the upper scale of a ply made of several elementary layers of various orientations, the anisotropic behavior of ultrasonic waves and their attenuation are obtained by a homogenization procedure. An actual plate is made of several plies separated by pure resin layers. Plies and layers thicknesses are highly variable. A statistical study has been conducted to evaluate the influence of these geometrical variations on the ultrasonic transmission predicted by a model derived from Thomson-Haskell formalism. Ultrasonic attenuation variability practically observed is quantitatively reproduced and explained as resulting from the geometrical irregularity of the microstructure. (author)

  9. Modelling of the meridian flow in nominal and partial flow in axial and helico-centrifugal turbomachinery; Modelisation en regime nominal et partiel de l'ecoulement meridien dans les turbomachines axiales et helicocentrifuges

    Energy Technology Data Exchange (ETDEWEB)

    Ercolino, J.

    2001-01-15

    In this study, a fast analysis code for the meridian flow inside turbo-machineries has been developed. This code is based on the resolution of the averaged dynamical equations controlling the internal stationary and non-viscous flow in the relative reference frame. A linear combination of momentum equations has been used in the axial and radial directions to avoid the source term of the equations to become singular. The model developed is particularly adapted to the general case of compression machines, i.e.the mixed machines. Starting with the hypothesis of a finite number of blading and assuming an axisymmetric flow, the equations allowing to calculate the blading forces and the simplified kinematics of blade-to-blade flow have been developed. This kinematics takes into consideration the geometrical data supplied by manufacturers or by global design softwares. This last approach ensures a very efficient link in the framework of turbomachine design projects where the blades geometry is introduced in a very simple way for a first optimization approach. The results obtained seem to be very consistent in nominal flow but also in partial flow conditions as shown by the qualitative comparisons with test results. (J.S.)

  10. Modeling of effusion in the presence of a turbulent parietal flow. Application to the thermal protection of walls; Modelisation de l`effusion en presence d`un ecoulement parietal turbulent. Application a la protection thermique des parois

    Energy Technology Data Exchange (ETDEWEB)

    Belletre, J.; Bataille, F.; Lallemaned, A. [Institut National des Sciences Appliquees (INSA), 69 - Villeurbanne (France)

    1997-12-31

    The effusion of a cold gas through a porous wall submitted to a hot turbulent parietal flow is studied in order to reduce the convective heat fluxes between the wall and the hot fluid. A modeling of the turbulent dynamical and thermal boundary layer is obtained using a RNG k-{epsilon} model. The cold gas injection through the porous plate and the fluid-wall friction are taken into account using a discrete succession of pores and solid elements. For a 1% injection rate, the modeling results agree with experiments performed in a test-duct. On the other hand, convective heat fluxes on the porous plate are calculated using semi-empirical correlations and different injection rates and temperatures of the hot flow. (J.S.) 23 refs.

  11. Modelling of the hydrogen effects on the morphogenesis of hydrogenated silicon nano-structures in a plasma reactor; Modelisation des effets de l'hydrogene sur la morphogenese des nanostructures de silicium hydrogene dans un reacteur plasma

    Energy Technology Data Exchange (ETDEWEB)

    Brulin, Q

    2006-01-15

    This work pursues the goal of understanding mechanisms related to the morphogenesis of hydrogenated silicon nano-structures in a plasma reactor through modeling techniques. Current technologies are first reviewed with an aim to understand the purpose behind their development. Then follows a summary of the possible studies which are useful in this particular context. The various techniques which make it possible to simulate the trajectories of atoms by molecular dynamics are discussed. The quantum methods of calculation of the interaction potential between chemical species are then developed, reaching the conclusion that only semi-empirical quantum methods are sufficiently fast to be able to implement an algorithm of quantum molecular dynamics on a reasonable timescale. From the tools introduced, a reflection on the nature of molecular metastable energetic states is presented for the theoretical case of the self-organized growth of a linear chain of atoms. This model - which consists of propagating the growth of a chain by the successive addition of the atom which least increases the electronic energy of the chain - shows that the Fermi level is a parameter essential to self organization during growth. This model also shows that the structure formed is not necessarily a total minimum energy structure. From all these numerical tools, the molecular growth of clusters can be simulated by using parameters from magnetohydrodynamic calculation results of plasma reactor modeling (concentrations of the species, interval between chemical reactions, energy of impact of the reagents...). The formation of silicon-hydrogen clusters is thus simulated by the successive capture of silane molecules. The structures formed in simulation at the operating temperatures of the plasma reactor predict the formation of spherical clusters constituting an amorphous silicon core covered by hydrogen. These structures are thus not in a state of minimum energy, contrary to certain experimental results. However, these results were obtained without taking into account the presence of atomic hydrogen in the plasma. A thorough study of the effect of atomic hydrogen on the metastable structures produced in simulation is thus carried out. The study of the interaction of atomic hydrogen on the surface of the cluster gives the possibility of finding the proportion of mechanisms (Eley-Rideal hydrogen desorption, hot atom mechanism or absorption on the surface of the cluster) in agreement with experiments on recombination on silicon surfaces. The interaction of atomic hydrogen with the surface of the clusters also induces a modification of the internal organization of the silicon atoms. The organization of the internal silicon atoms of the clusters as a function of cluster size (magic number) makes it possible to understand why the experimental observations indicate the presence of crystalline structures. Finally this study leads to the prediction of a particularly stable structure which could be used as precursor for the growth of silicon nano-wires. (author)

  12. Modelling of Molecular Structures and Properties in Physical Chemistry and Biophysics, Forty-Fourth International Meeting (Modelisation des Structures et Proprietes Moleculaires en Chimie Physique et en Biophysique, Quarante- Quatrieme Reunion Internationale)

    Science.gov (United States)

    1989-09-01

    apprcc-he novatzice, fondde sur une perception de I’ envixcnnmnt local des atoi-es dolt of frir des resssources inr~rtantes dans le traitement de tous les...Acta, 72, 1-13 (1989). 2586 Etude thdorique de la structure du compiexe Giutathion - Eau oxygdn4e J.Berg~s , JCaillet Dynamique des Interactions Mol...est connu que !a r6action d’oxydati4on du glutathion par 1! eau oxyg~n6e est catalys~e, in vivo, par une enzyme, la glutathion peroxydase. I’l a4t

  13. Modeling of the thermal transfer inside a porous environment: application to nuclear reactors in accident situation; Modelisation du transfert thermique dans un milieu poreux: application aux reacteurs nucleaires en situation accidentelle

    Energy Technology Data Exchange (ETDEWEB)

    Rubiolo, P.R

    2000-03-01

    The purpose of this report is to simulate heat exchanges occurring by conduction, by convection and by radiating in a porous medium made up of opaque particles in a semi-transparent fluid. Usually the determination of the macroscopic equations is based on homogenization techniques, but in the case of a major accident, the complexity of the problem is so overwhelming that semi-empirical methods are used to determine macroscopic coefficients. The author develops a new method to determine these coefficients, this method is based on the calculation of different tensors: the equivalent conductivity tensor, the radiative conductivity tensor, the thermal conductivity tensor and the heat exchange coefficient (h{sub sf}) between the solid phase and the fluid one. The first chapter briefly describes energy, impulse and mass balances. In the case of the energy balance the solid phase is not supposed to be in thermal equilibrium with the liquid phase. The second chapter presents an application of the porous media method to a one-dimensional and stationary problem, this application to a simple problem gives an idea of the performance of the method. The model allowing the calculation of h{sub sf} is developed, it is a wide range model. The second chapter ends with the presentation of the model allowing the computing of the effective conductivity of fuel rods. A comparison between results given by this new method and other numeric calculations or experimental data coming from benchmarks is presented in the third chapter. This chapter ends with the simulation of a reactor core in accidental situation, 2 cases are presented: with and without the presence of water steam. (A.C.)

  14. Contributions to micromechanical model of the non linear behavior of the Callovo-Oxfordian argillite; Contributions a la modelisation micromecanique du comportement non lineaire de l'argilite du callovo-oxfordien

    Energy Technology Data Exchange (ETDEWEB)

    Abou-Chakra Guery, A

    2007-12-15

    This work is performed in the general context of the project of underground disposal of radioactive waste, undertaken by the French National Radioactive Waste Management Agency (ANDRA). Due to its strong density and weak permeability, the formation of Callovo-Oxfordian argillite is chosen as one of possible geological barriers to radionuclides. The objective of the study to develop and validate a non linear homogenization approach of the mechanical behavior of Callovo-Oxfordian argillites. The material is modelled as a composite constituted of an elasto(visco)plastic clay matrix and of linear elastic or elastic damage inclusions. The macroscopic constitutive law is obtained by adapting the incremental method proposed by Hill. The derived model is first compared to Finite Element calculations on unit cell. It is then validated and applied for the prediction of the macroscopic stress-strain responses of the argillite at different geological depths. Finally, the micromechanical model is implemented in a commercial finite element code (Abaqus) for the simulation of a vertical shaft of the underground laboratory. This allows predicting the distribution of damage state and plastic strains and characterizing the excavation damage zone (EDZ). (author)

  15. Assessment, modelization and analysis of {sup 106} Ru experimental transfers through a freshwater trophic system; Evaluation, modelisation et analyse des transferts experimentaux du {sup 106}Ru au sein d`un reseau trophique d`eau douce

    Energy Technology Data Exchange (ETDEWEB)

    Vray, F

    1994-11-24

    Experiments are carried out in order to study {sup 106} RU transfers through a freshwater ecosystem including 2 abiotic compartments (water and sediment) and 3 trophic levels (10 species). Experimental results are expressed mathematically so as they can be included into a global model which is then tested in two different situations. The comparison of the available data concerning the in situ measured concentrations to the corresponding calculated ones validates the whole procedure. Analysis of the so validated results lightens ruthenium distribution process in the environment. The rare detection of this radionuclide in organisms living in areas contaminated by known meaningful releases can be explained by a relativity high detection limit and by a slight role of the sediment as a secondary contamination source. (author). 78 figs., 18 tabs.

  16. A contribution to the physical and chemical model of long-lived radioactive wastes by clayey materials; Contribution a la modelisation physico-chimique de la retention de radioelements a vie longue par des materiaux argileux

    Energy Technology Data Exchange (ETDEWEB)

    Gorgeon, L

    1994-11-25

    This work deals with the high-level and long-lived radioactive wastes confinement which come from the irradiated fuels reprocessing. These wastes are generally coated in a deep geological structure confinement matrix. The radiation protection of a such storage requires that the coating matrix, the technological barriers which separate the storage and the geological medium and the reception rock does not let the radioactive wastes pass. The materials used in this work for the confinement studies are clayey minerals and the retention mechanisms studies are realized on cesium 135, neptunium 237, americium 241 and uranium 233. The first part of this thesis concerns the clayey minerals retention properties towards ions in aqueous solutions. More particularly the relations between these properties and the chemical structure of these solids are investigated. In the second part are presented the experimental works which have allowed to specify the intrinsic characteristics of the studied minerals. Indeed the knowledge of these parameters is essential to quantitatively explain the results of the radionuclides retention. The adsorption mechanisms are described in a third part. (O.L.). 112 refs., 59 figs., 51 tabs.

  17. Modeling the fine fragmentation following the triggering stage of a vapor explosion; Modelisation de la fragmentaton fine lors de la phase de declenchement d`une explosion de vapeur

    Energy Technology Data Exchange (ETDEWEB)

    Darbord, I [CEA Grenoble, 38 (France). Service d` Etudes et de Modelisation Thermohydraulique

    1997-06-11

    In the frame of PWR severe accidents, where the core melt, this thesis studies one of the stages of an FCI (fuel coolant interaction) or vapor explosion. An FCI is a rapid evaporation of a coolant when it comes into contact with a hot liquid. More precisely, the subject of this study is the triggering stage of the FCI, when a fuel drop of diameter around one centimeter breaks up into many fragments, diameter of which is around a hundred micrometers. The model describes the cyclic collapse and growth of a vapor bubble around the fuel droplet and its fragmentation. The main features of the model are: - the destabilization of the film or the vapor bubble due to the growth of Rayleigh-Taylor instabilities (those form coolant jets that contact the fuel surface); - The mechanisms of fragmentation, following the contacts (in the case of entrapment of a certain amount of coolant in the fuel, the entrapped coolant evaporates violently after it has been heated to the homogeneous nucleation temperature); - the transient heat transfer from the fragments to the coolant and the elevated vapor production, which leads to an important expansion of the bubble (about this point, the cooling of the fragments has been described by a transient heat transfer coefficient linked to nucleate boiling). The results of the model show good agreement with experimental data. (Author) 68 refs.

  18. Light ions radiobiological effects on human tumoral cells: measurements modelling and application to hadron-therapy; Mesures et modelisation des effets radiobiologiques des ions legers sur des cellules tumorales humaines: application a l'hadrontherapie

    Energy Technology Data Exchange (ETDEWEB)

    Jalade, P

    2005-11-15

    In classical radiotherapy, the characteristics of photons interactions undergo limits for the treatment of radioresistant and not well located tumours. Pioneering treatments of patients at the Lawrence Laboratory at Berkeley has demonstrated two advantages of hadrons beams: the Relative Biologic Effect (the RBE) and the ballistic of the beams. Since 1994, the clinical centre at Chiba, has demonstrated successfully the applicability of the method. A physics group, managed by G. Kraft, at Darmstadt in Germany, has underlined the advantages of carbon beams. An European pool, called ENGIGHT (European Network for LIGHt ion Therapy) has been created in which the French ETOILE project appeared. The purpose of the thesis concerns measurements and models of 'in vitro' human cells survival. In the first part, the nowadays situation in particles interactions, tracks and cells structures and radiobiology is presented here. The second is devoted to the models based on the beam tracks and localization of the physical dose. Discussion of sensitivity to various parameters of the model has been realized with the help of numerical simulations. Finally the predictions of the improved model has been compared to experimental irradiations of human cells with argon and carbon beams of the GANIL machine. Conclusion of such study shows the performance and limits of a local model for predicting the radiobiological efficiency of light ions in hadron-therapy. (author)

  19. Radiative transfer modelling in combusting systems using discrete ordinates method on three-dimensional unstructured grids; Modelisation des transferts radiatifs en combustion par methode aux ordonnees discretes sur des maillages non structures tridimensionnels

    Energy Technology Data Exchange (ETDEWEB)

    Joseph, D.

    2004-04-01

    The prediction of pollutant species such as soots and NO{sub x} emissions and lifetime of the walls in a combustion chamber is strongly dependant on heat transfer by radiation at high temperatures. This work deals with the development of a code based on the Discrete Ordinates Method (DOM) aiming at providing radiative source terms and wall fluxes with a good compromise between cpu time and accuracy. Radiative heat transfers are calculated using the unstructured grids defined by the Computational Fluid Dynamics (CFD) codes. The spectral properties of the combustion gases are taken into account by a statistical narrow bands correlated-k model (SNB-ck). Various types of angular quadrature are tested and three different spatial differencing schemes were integrated and compared. The validation tests show the limit at strong optical thicknesses of the finite volume approximation used the Discrete Ordinates Method. The first calculations performed on LES solutions are presented, it provides instantaneous radiative source terms and wall heat fluxes. Those results represent a first step towards radiation/combustion coupling. (author)

  20. Coupling between reactions and transport for the modelling and simulation of CO{sub 2} geological storage; Couplage reactions-transport pour la modelisation et la simulation du stockage geologique de CO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Tillier, E

    2007-09-15

    In this work, we present some results about the coupling between transport and geochemistry for the modelling and the simulation of CO{sub 2} geological storage. We present a multiphase flow model and a geochemical model which enables to describe a coupled reactive multiphase flow problem. We then propose two methods of resolution, the first one is a global method, the other one is a splitting method which is used at the IFP in the software COORES. The splitting is based on physical assumptions. The coupling method used is a non iterative method, in which the splitting error is corrected by adding a penalization term. A convergence study shows that this scheme converges to the same solution as the global scheme. A part of this PhD is dedicated to diffusion and dispersion phenomena. We are interested in this term because it cannot be integrated easily in a splitting scheme, if the reactive transport is solved locally (which is necessary to use local time-step). After having highlighted the importance of this term on a representative test case, we show some difficulties encountered to integrate it in a splitting scheme. Finally, we study a miscible multiphase flow problem in 1D from a mathematical point of view. The difficulties arise with the non linearity due to the non zero gas solubility in water. We propose a definition for the weak solution of this problem and its existence is shown thanks to the convergence of a finite volume scheme. (O.M.)

  1. A fifth equation to model the relative velocity the 3-D thermal-hydraulic code THYC; Une cinquieme equation pour modeliser la vitesse relative dans le code de thermohydraulique THYC

    Energy Technology Data Exchange (ETDEWEB)

    Jouhanique, T.; Rascle, P.

    1995-11-01

    E.D.F. has developed, since 1986, a general purpose code named THYC (Thermal HYdraulic Code) designed to study three-dimensional single and two-phase flows in rod tube bundles (pressurised water reactor cores, steam generators, condensers, heat exchangers). In these studies, the relative velocity was calculated by a drift-flux correlation. However, the relative velocity between vapor and liquid is an important parameter for the accuracy of a two-phase flow modelling in a three-dimensional code. The range of application of drift-flux correlations is mainly limited by the characteristic of the flow pattern (counter current flow ...) and by large 3-D effects. The purpose of this paper is to describe a numerical scheme which allows the relative velocity to be computed in a general case. Only the methodology is investigated in this paper which is not a validation work. The interfacial drag force is an important factor of stability and accuracy of the results. This force, closely dependent on the flow pattern, is not entirely established yet, so a range of multiplicator of its expression is used to compare the numerical results with the VATICAN test section measurements. (authors). 13 refs., 6 figs.

  2. Experiment, Modeling and Simulation of Gas-Surface Interactions for Reactive Flows in Hypersonic Flights (L'experimentation, la modelisation et la simulation d'interactions gaz-surface pour ecoulements reactifs en vol hypersonique) (CD-ROM)

    National Research Council Canada - National Science Library

    2007-01-01

    ... of high temperatures gases. Focusing on re-entry situation the presentations dealt with high temperature gas chemistry and also on gas- surface interaction known as catalytic effects for space vehicles...

  3. On the modelling and the analysis of two-phase flow instabilities in pipeline-riser systems; Modelisation et analyse des instabilites d'ecoulements diphasiques dans les conduites petrolieres du type pipeline-riser

    Energy Technology Data Exchange (ETDEWEB)

    Zakarian, E.

    2000-03-10

    Recent estimations predict that over half the remaining offshore oil and gas reserves are located in deep water and marginal fields. For such reserves, economic recovery methods are required. Then, multiphase flows are transported within pipelines and separated on treatment platforms built in shallow water or processed in onshore facilities. Unfortunately, hydrodynamic instabilities may occur whenever gas and liquid flow in a pipeline, generating serious operating problems. This dissertation presents a new way to model two-phase flows in pipelines such as pipeline-riser systems. Equations are algebraic and differential. Their smoothness depends on the closure laws of the problem such as slip or friction laws. Smooth forms of these closure laws are presented for the first time in this dissertation. Therefore, a mathematical analysis of our model fits into a classical frame: a linear analysis leads to an analytical expression of the boundary between stable and unstable flows. A nonlinear analysis provides for the first time, the bifurcation curves of gas-liquid flows in pipe-riser systems, locally round their stability boundary. (author)

  4. Modeling of polarization phenomena due to RF sheaths and electron beams in magnetized plasma; Modelisation de phenomenes de polarisation par des gaines rf et des faisceaux electroniques dans un plasma magnetise

    Energy Technology Data Exchange (ETDEWEB)

    Faudot, E

    2005-07-01

    This work investigates the problematic of hot spots induced by accelerated particle fluxes in tokamaks. It is shown that the polarization due to sheaths in the edge plasma in which an electron beam at a high level of energy is injected, can reach several hundreds volts and thus extend the deposition area. The notion of obstructed sheath is introduced and explains the acceleration of energy deposition by the decreasing of the sheath potential. Then, a 2-dimensional fluid modeling of flux tubes in front of ICRF antennae allows us to calculate the rectified potentials taking into account RF polarization currents transverse to magnetic field lines. The 2-dimensional fluid code designed validates the analytical results which show that the DC rectified potential is 50% greater with polarization currents than without. Finally, the simultaneous application of an electron beam and a RF potential reveals that the potentials due to each phenomenon are additives when RF potential is much greater than beam polarization. The density depletion of polarized flux tubes in 2-dimensional PIC (particles in cells) simulations is characterized but not yet explained. (author)

  5. Synthesis of zirconium by zirconium tetrachloride reduction by magnesio-thermia. Experimental study and modelling; Elaboration de zirconium par reduction de tetrachlorure de zirconium par magnesothermie. Etude experimentale et modelisation

    Energy Technology Data Exchange (ETDEWEB)

    Basin, N

    2001-01-01

    This work deals with the synthesis of zirconium. The ore is carbo-chlorinated to obtain the tetrachloride which is then purified by selective condensation and extractive distillation. Zirconium tetrachloride is then reduced by magnesium and the pseudo-alloy is obtained according to the global following reaction (Kroll process): ZrCl{sub 4} + 2 Mg = 2 MgCl{sub 2}. By thermodynamics, it has been shown that the volatilization of magnesium chloride and the formation of zirconium sub-chlorides are minimized when the combined effects of temperature and of dilution with argon are limited. With these conditions, the products, essentially zirconium and magnesium chloride, are obtained in equivalence ratio in the magnesio-thermia reaction. The global kinetics of the reduction process has been studied by a thermal gravimetric method. A thermo-balance device has been developed specially for this kinetics study. It runs under a controlled atmosphere and is coupled to a vapor tetrachloride feed unit. The transformation is modelled supposing that the zirconium and magnesium chloride formation result: 1)of the evaporation of magnesium from its liquid phase 2)of the transfer of magnesium and zirconium tetrachloride vapors towards the front of the reaction located in the gaseous phase 3)of the chemical reaction. In the studied conditions, the diffusion is supposed to be the limiting process. The influence of the following parameters: geometry of the reactive zone, temperature, scanning rate of the argon-zirconium tetrachloride mixture, composition of the argon-zirconium tetrachloride mixture has been experimentally studied and confronted with success to the model. (O.M.)

  6. A model for the ultrasonic field radiated by an immersed transducer into an anisotropic and heterogeneous medium; Modelisation du champ ultrasonore rayonne dans un solide anisotrope et heterogene par un traducteur immerge

    Energy Technology Data Exchange (ETDEWEB)

    Gengembre, N

    2000-07-01

    A model for the field radiated by an ultrasonic transducer into anisotropic and heterogeneous media is developed in this thesis. This work aims at improving the settings and interpretations of non destructive tests in welded structures. Since the shape of the transducer is assumed arbitrary, its emitting surface is divided into small elementary sources. The overall field at an observation point in the medium is derived by a summation of the elementary contributions of these point sources. An accurate and numerically efficient model is developed using the Geometrical Optics approximation to evaluate these elementary contributions. Two different forms of this approximation are used: The stationary phase method and the pencil method. The first one is based on an exact formulation of the field and is used for fields into anisotropic and homogeneous media. It allows to emphasize specific configurations for which additional developments are required; this need arises for calculation points in the vicinity of caustics (zones of high intensity). This problem is solved for both harmonic and transient fields, for points laying on caustics or in their neighborhood. The pencil method is used for the calculation of fields in heterogeneous media, although it does not permit to overcome the problem of caustics. It is also advantageous for the implementation of the model. A comparison of both above-mentioned methods is drawn, and their equivalence is proved for some cases. The calculation of fields in anisotropic and heterogeneous media is performed using both methods together, and then the problem of caustics is also treated. Calculated fields into welded components are shown and compared with experiments or with a numerical model, in order to validate the developments. (author)

  7. Contribution to modelization and simulation of the ablative-like Rayleigh-Taylor instabilities for ICF; Contribution a la modelisation et a la simulation des instabilites de type Rayleigh-Taylor ablatif pour la FCI

    Energy Technology Data Exchange (ETDEWEB)

    Egly, H

    2007-10-15

    This thesis deals with the dynamics of accelerated ablative front spreading in Inertial Confinement Fusion experiments. ICF is designed for the implosion of a deuterium-tritium spherical target. The outer shell, the ablator, is irradiated providing a high level pressure inside the target. During this first stage, the ablation front propagating inwards is perturbed by hydrodynamics instabilities, which can prevent the fusion reaction in the decelerated stage. We propose here a study on Rayleigh-Taylor instabilities during ablation process, in the two dimensional case. In order to obtain a numerical solution, we perform an asymptotic analysis in the limit of a high temperature ratio, between the remaining cold ablator and the hot ablated plasma. This study is divided in two steps. First, the thermo-diffusive part of the set of equations is approximated by a Hele-Shaw model, which is then perturbed by the hydrodynamics part. Using a vortex method, we have to solve the advection of a vortical sheet moving with the ablation front. We compute the numerical solution on an Eulerian mesh coupled with a marker method. The thermal part is computed by implementing the Fat Boundary Method, recently developed. The hydrodynamic part is obtained from a Finite Volume scheme. (author)

  8. Integration of non linearities in the economic refining model. Case of the hydro-desulfurization unit; Prise en compte de non-linearites dans la modelisation economique du raffinage. Cas de l`unite d`hydrodesulfuration

    Energy Technology Data Exchange (ETDEWEB)

    Baudouin, C.

    1998-12-08

    In recent years, the modifications in oil products demand and the increased quality requirements of European specifications have driven the oil industry towards more and more complex refining schemes. This situation should become even more pronounced in the future. Under these conditions, a technical analysis of the units operation must be carried out and combined with an economic approach. The research undertaken is divided into two parts. The first part is dedicated to the study of the European refining industry and its representation by the classic linear programming model. In these models, the units` operation is represented by typical running. The technical parameters are not explicitly taken into account. Therefore, in order to meet future requirements and to represent this activity in the best way, the current model must be improved. The second part relates to an analysis with forecasts future developments in the European refining sector up to 2010 and how linear programming models themselves will be adapted. Thus, the straight run gas oil hydro-desulfurization unit is completely redefined. The operating conditions and the design parameters of this unit are introduced into the model. Depending on the feed, they determine the performances and the material balance of the unit. Some of these operating conditions are new variables and appear in non linear equations. Therefore, we need non linear programming (the augmented Lagrangians method) to solve this detailed model. The results of the second part confirm those determined by the first part. They also provide us with a better representation of the hydro-desulfurization unit (taking the optimisation of the operating conditions into account). Using these models and the analysis described above, we can develop an outline plan of the future European refining industry. This shows that sizeable investments in both conventional and deep conversion capacity will be required to meet the requirements of changes in demand and more restrictive specification. (author) 27 refs.

  9. Seismic rupture modelling, strong motion prediction and seismic hazard assessment: fundamental and applied approaches; Modelisation de la rupture sismique, prediction du mouvement fort, et evaluation de l'alea sismique: approches fondamentale et appliquee

    Energy Technology Data Exchange (ETDEWEB)

    Berge-Thierry, C

    2007-05-15

    The defence to obtain the 'Habilitation a Diriger des Recherches' is a synthesis of the research work performed since the end of my Ph D. thesis in 1997. This synthesis covers the two years as post doctoral researcher at the Bureau d'Evaluation des Risques Sismiques at the Institut de Protection (BERSSIN), and the seven consecutive years as seismologist and head of the BERSSIN team. This work and the research project are presented in the framework of the seismic risk topic, and particularly with respect to the seismic hazard assessment. Seismic risk combines seismic hazard and vulnerability. Vulnerability combines the strength of building structures and the human and economical consequences in case of structural failure. Seismic hazard is usually defined in terms of plausible seismic motion (soil acceleration or velocity) in a site for a given time period. Either for the regulatory context or the structural specificity (conventional structure or high risk construction), seismic hazard assessment needs: to identify and locate the seismic sources (zones or faults), to characterize their activity, to evaluate the seismic motion to which the structure has to resist (including the site effects). I specialized in the field of numerical strong-motion prediction using high frequency seismic sources modelling and forming part of the IRSN allowed me to rapidly working on the different tasks of seismic hazard assessment. Thanks to the expertise practice and the participation to the regulation evolution (nuclear power plants, conventional and chemical structures), I have been able to work on empirical strong-motion prediction, including site effects. Specific questions related to the interface between seismologists and structural engineers are also presented, especially the quantification of uncertainties. This is part of the research work initiated to improve the selection of the input ground motion in designing or verifying the stability of structures. (author)

  10. Modeling of gas condensates properties using continuous distribution functions for the characterization of the plus fraction; Modelisation des proprietes thermodynamiques des gaz a condensat par representation de la fraction lourde a l`aide de fonctions de distribution

    Energy Technology Data Exchange (ETDEWEB)

    Sportisse, M.

    1996-12-20

    The modeling of thermodynamic behaviour for gas condensates is not yet satisfactory and it involves an adjustment of thermodynamic models. We propose here a fitting based on the characterization of the plus fraction using three continuous distribution functions associated to the following families: n-alkanes, n-alkylbenzenes and poly-aromatics. No continuous thermodynamic model is used and PVT calculations are made with the Peng-Robinson equation of state. For poly-aromatics, a simple correlation of {l_brace} T{sub c}, P{sub c}, {omega} {r_brace} is given. The parameters of the distributions are fitted in order to improve the accuracy of the liquid deposit curve calculation. A continuous minimization by simulated annealing has been used to avoid local minima. Good results on fitting PVT properties have been obtained with more than twenty gas condensates from different areas. Moreover, the prediction of tank liquid and heavy-plus fraction densities are given with an average deviation of 1.2 % and 3.6 %. Tests on temperature extrapolation show that our modeling yields a good representation of pressure and temperature influence on gas condensates behaviour. (author) 89 refs.

  11. Phenomenological modeling of the drying of a thin cloth with a rotating cylinder heated by electromagnetic induction; Modelisation phenomenologique du sechage d'une nappe mince avec un cylindre rotatoire chauffe par induction electromagnetique

    Energy Technology Data Exchange (ETDEWEB)

    Perez, S. [Universidad de Carabobo, Facultad de Ingenieria, Valencia (Venezuela); Therien, N.; Broadbent, A.D. [Sherbrooke Univ., Faculte de Genie, Quebec (Canada)

    2001-07-01

    A phenomenological model of the evolution of the humidity and temperature during the drying of a thin fiber cloth in contact with a metal surface heated by electric induction is presented. The model calculates also the temperature inside the cylinder with respect to its position. Differential mass and energy statuses are established and the concept of substantial derivative is used to bind the state variables with respect to the time and position. The conduction, convection, radiant heat transfer, thermal induction, and energy transfer due to water vaporization are explicitly considered. The model takes into consideration the disturbances due to the variations of the humidity of the cloth at the input of the process. It calculates the response of the process in front of these disturbances and in front of the rotation speed of the cylinder and the electric power supplied to the system. Multiple experiments performed on a bench test have permitted to characterize the response of the drying process (temperature of the cylinder, humidity and temperature of the cloth) under different combinations of conditions. (J.S.)

  12. Phenomenological modeling of the thermal dynamics of a rotating cylinder heated by electromagnetic induction; Modelisation phenomenologique de la dynamique thermique d'un cylindre rotatoire chauffe par induction electromagnetique

    Energy Technology Data Exchange (ETDEWEB)

    Perez, S. [Universidad de Carabobo, Facultad de Ingenieria, Valencia (Venezuela); Therien, N.; Broadbent, A.D. [Sherbrooke Univ., Faculte de Genie, Quebec (Canada)

    2001-07-01

    This work concerns the development of a phenomenological model describing the temperature dynamics of a metal cylinder heated by electric induction. The model used takes into consideration in an explicit way the different mechanisms of energy transfer from the cylinder towards the environment, in particular the convection and radiant heat transfers. The conduction process, which takes place inside the cylinder as a response to the temperature gradient at the periphery of the cylinder, has been characterized too. The process of energy induction inside the cylinder has been characterized in a precise way. The experiments show that the induction is localized in the part of the cylinder facing the inductors and that the induction presents a distributed feature in the induction section. The model proposed is based on the concept of substantial derivative. It calculates the response of the process with respect to these disturbances and with respect to the rotation speed of the cylinder and to the electric power supplied to the system. (J.S.)

  13. Modelling of the mechanical behaviour and damage of clay-stones: application to the East argillite; Modelisation du comportement mecanique des argiles raides avec prise en compte de l'endommagement: application aux argilites de l'Est

    Energy Technology Data Exchange (ETDEWEB)

    Aublive-Conil, N

    2003-03-15

    The storage in deep geological formation is one of the solutions retained by France for the management of highly long life radioactive waste. The retained host rock is a clay-stone named East argillite located in the departments of Meuse and Haute-Marne. A thermodynamic formulation is used to propose a rheological model, which reproduces the mechanical behavior of clay-stones. Initially, an anisotropic damage plastic model was formulated in order to describe material degradations. Then, the damage plastic model is reformulated in order to taken into account the damage influence on the hydraulic behavior of porous material. The numerical simulations correctly reproduce the mechanical behavior of East Argillites but also the anisotropy of the hydraulic behavior introduced by the damage effect. (author)

  14. The Callovo-Oxfordian of the Paris Basin: From its geological context to the modelling of its properties; Le Callovo-Oxfordien du bassin de Paris: du contexte geologique a la modelisation de ses proprietes

    Energy Technology Data Exchange (ETDEWEB)

    Anon

    2006-10-15

    The French law from December 30, 1991 entrusted the French national agency for radioactive wastes (ANDRA) with the mission of assessing the feasibility of a deep geological repository in the clay-rich Callovo-Oxfordian formation of NE France (Meuse and Haute-Marne departements). A research program, coordinated by ANDRA and involving several university laboratories and other French organizations (CNRS, CEA, BRGM, INERIS, INPL, ENSMP) has permitted to gather a huge amount of information about the properties of the Callovo-Oxfordian formation of the eastern part of the Paris basin. These properties are summarized in this introductive paper: paleo-geography, bio-stratigraphy of ammonites, clay mineralogy and other minerals content, anisotropy of argillite beds, permeability and porosity, osmosis and thermal diffusion, chemistry of interstitial waters, fracturing.. (J.S.)

  15. Atomistic modelling study of lanthanide incorporation in the crystal lattice of an apatite; Etude par modelisation atomistique de l'incorporation de lanthanides dans le reseau cristallin d'une apatite phosphocalcique

    Energy Technology Data Exchange (ETDEWEB)

    Louis-Achille, V

    1999-07-01

    Studies of natural and synthetic apatites allow to propose such crystals as matrix for nuclear waste storage. The neodymium substituted britholite, Ca{sub 9}Nd(PO{sub 4}){sub 5}(SiO{sub 4})F{sub 2}. is a model for the trivalent actinide storage Neodymium can be substituted in two types of sites. The aim of this thesis is to compare the chemical nature of this two sites in fluoro-apatite Ca{sub 9}(PO{sub 4}){sub 6}F{sub 2} and then in britholite, using ab initio atomistic modeling. Two approaches are used: one considers the infinite crystals and the second considers clusters. The calculations of the electronic structure for both were performed using Kohn and Sham density functional theory in the local approximation. For solids, pseudopotentials were used, and wave functions are expanded in plane waves. For clusters, a frozen core approximation was used, and the wave functions are expanded in a linear combination of Slater type atomic orbitals. The pseudopotential is semi-relativistic for neodymium, and the Hamiltonian is scalar relativistic for the clusters. The validation of the solid approach is performed using two test cases: YPO{sub 4} and ScPO{sub 4}. Two numerical tools were developed to compute electronic deformation density map, and calculate partial density of stases. A full optimisation of the lattice parameters with a relaxation of the atomic coordinates leads to correct structural and thermodynamic properties for the fluoro-apatite, compared to experience. The electronic deformation density maps do not show any significant differences. between the two calcium sites. but Mulliken analysis on the solid and on the clusters point out the more ionic behavior of the calcium in site 2. A neodymium substituted britholite is then studied. Neodymium location only induces local modifications in; the crystalline structure and few changes in the formation enthalpy. The electronic study points out an increase of the covalent character the bonding involving neodymium compared with the one related to calcium, particularly in the Nd-F bond. (author)

  16. Integrated simulation, evaluation of the climatic risks and safety policies. Synthesis report july 2002; Modelisation integree, evaluation des risques climatiques et des politiques de precaution. Rapport de synthese juillet 2002

    Energy Technology Data Exchange (ETDEWEB)

    Hourcade, J.Ch. [CNRS, Directeur d' etude, EHESS, Directeur, CIRED, 94 - Nogent Sur Marne (France); LeTreut, H. [CNRS, Directeur de recherche, LMD, LMD, 75 - Paris (France)

    2002-07-15

    The aim of this program is the improvement of the natural phenomena representation in the integrated models of the climate policies evaluation and to precise the methodological problems resulting from the damages treatment. It underlines the importance of the retroactions between the CO{sub 2} emissions, the lands affectation and the carbon cycle, as the importance of the uncertainties on the climate sensitivity. (A.L.B.)

  17. Turbulent precipitation of uranium oxalate in a vortex reactor - experimental study and modelling; Precipitation turbulente d'oxalate d'uranium en reacteur vortex - etude experimentale et modelisation

    Energy Technology Data Exchange (ETDEWEB)

    Sommer de Gelicourt, Y

    2004-03-15

    Industrial oxalic precipitation processed in an un-baffled magnetically stirred tank, the Vortex Reactor, has been studied with uranium simulating plutonium. Modelling precipitation requires a mixing model for the continuous liquid phase and the solution of population balance for the dispersed solid phase. Being chemical reaction influenced by the degree of mixing at molecular scale, that commercial CFD code does not resolve, a sub-grid scale model has been introduced: the finite mode probability density functions, and coupled with a model for the liquid energy spectrum. Evolution of the dispersed phase has been resolved by the quadrature method of moments, first used here with experimental nucleation and growth kinetics, and an aggregation kernel based on local shear rate. The promising abilities of this local approach, without any fitting constant, are strengthened by the similarity between experimental results and simulations. (author)

  18. Modeling of the poly-phase flow inside and at the exit of diesel injectors; Modelisation de l'ecoulement polyphasique a l'interieur et en sortie des injecteurs diesel

    Energy Technology Data Exchange (ETDEWEB)

    Moreau, J.B.

    2005-12-15

    Because of pollutant emission requirements for individual vehicles, engine designers are very concerned about high pressure Diesel injection and the related cavitation phenomenon. Computational fluid dynamics is a powerful and cheap tool to investigate such complex systems. A homogeneous multiphase model has been developed: it consists in a mixture of fuel - that may be either liquid or vapor - and gas. It is based on an equation of state that was tabulated between a baro-tropic law for the fuel and the ideal gas equation for the gas. This model is validated on a bubble collapse test and on classical 2D injection cases. 3D computations on realistic injectors highlight the influence of cavitation and secondary flows, inside the injector nozzle, on jet destabilization and liquid core primary atomization. (author)

  19. Study and simulation of the behaviour under irradiation of helium in uranium dioxide; Etude et modelisation du comportement sous irradiation de l'helium dans le dioxyde d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Martin, G

    2007-06-15

    Large quantities of helium are produced from {alpha}-decay of actinides in nuclear fuels during its in-pile operating and its storage. It is important to understand the behaviour of helium in these matrix in order to well simulate the evolution and the resistance of the fuel element. During this thesis, we have used nuclear reaction analyses (NRA) to follow the evolution of the helium implanted in polycrystalline and monocrystalline uranium dioxide (UO{sub 2}). An experimental rig was developed to follow the on-line helium release in UO{sub 2} and the evolution of {sup 3}He profiles as a function of annealing temperature. An automated procedure taking into account the evolution of the depth resolution was developed. Analyses performed with a nuclear microprobe allowed to characterise the spatial distribution of helium at the grain scale and to study the influence of the sample microstructure on the helium migration. This work put into evidence the particular role of grain boundaries and irradiation defects in the helium release process. The analyse of experimental results with a diffusion model corroborates these interpretations. It allowed to determine quantitatively physical properties that characterise the helium behaviour in uranium dioxide (diffusion coefficient, activation energy..). (author)

  20. Numerical modelling of coupled phenomena within molten glass heated by induction and mechanically stirred; Modelisation numerique de phenomenes couples dans des bains de verre brasses mecaniquement et elabores en creuset froid inductif

    Energy Technology Data Exchange (ETDEWEB)

    Jacoutot, L

    2006-11-15

    This study reports on a new vitrification process developed by the French Atomic Energy Commission (CEA, Marcoule). This process is used for the treatment of high activity nuclear waste. It is characterized by the cooling of all the metal walls and by currents directly induced inside the molten glass. In addition, a mechanical stirring device is used to homogenize the molten glass. The goal of this study is to develop numerical tools to understand phenomena which take place within the bath and which involve thermal, hydrodynamic and electromagnetic aspects. The numerical studies are validated using experimental results obtained from pilot vitrification facilities. (author)

  1. Asymptotic analysis, direct numerical simulation and modeling of premixed turbulent flame-wall interaction; Etude asymptotique, simulation numerique directe et modelisation de l`interaction flamme turbulente premelangee-paroi

    Energy Technology Data Exchange (ETDEWEB)

    Bruneaux, G.

    1996-05-20

    Premixed turbulent flame-wall interaction is studied using theoretical and numerical analysis. Laminar interactions are first investigated through a literature review. This gives a characterization of the different configurations of interaction and justifies the use of simplified kinetic schemes to study the interaction. Calculations are then performed using Direct Numerical Simulation with a one-step chemistry model, and are compared with good agreements to asymptotic analysis. Flame-wall distances and wall heat fluxes obtained are compared successfully with those of the literature. Heat losses decrease the consumption rate, leading to extinction at the maximum of wall heat flux. It is followed by a flame retreat, when the fuel diffuses into the reaction zone, resulting in low unburnt hydrocarbon levels. Then, turbulent regime is investigated, using two types of Direct Numerical Simulations: 2D variable density and 3D constant density. Similar results are obtained: the local turbulent flame behavior is identical to a laminar interaction, and tongues of fresh gases are expelled from the wall region, near zones of quenching. In the 2D simulations, minimal flame-wall distances and maximum wall heat fluxes are similar to laminar values. However, the structure of the turbulence in the 3D calculations induces smaller flame-wall distances and higher wall heat fluxes. Finally, a flame-wall interaction model is built and validated. It uses the flamelet approach, where the flame is described in terms of consumption speed and flame surface density. This model is simplified to produce a law of the wall, which is then included in a averaged CFD code (Kiva2-MB). It is validated in an engine calculation. (author) 36 refs.

  2. Modeling of turbulent flows in porous media and at the interface with a free fluid medium; Modelisation des ecoulements turbulents dans les milieux poreux et a l'interface avec un milieu libre

    Energy Technology Data Exchange (ETDEWEB)

    Chandesris, M

    2006-12-15

    This work deals with the numerical simulation of turbulent flows in the whole nuclear reactor core, using multi-scale approaches. First, a macroscopic turbulence model is built, based on a porous media approach, to describe the flow in the fuel assemblies part of the nuclear core. Then, we study the jump conditions that have to be applied at a free fluid/porous interface. A thorough analytical study is carried out for laminar flows. This study allows to answer some fundamental questions about the physical meaning of the jump conditions, the values of the jump parameters and the location of the interface. Using these results, jump conditions for turbulent flows are proposed. The model is then applied to the simulation of a turbulent flow in a simplified model of a reactor core. (author)

  3. Macro-scale turbulence modelling for flows in porous media; Modelisation a l'echelle macroscopique d'un ecoulement turbulent au sein d'un milieu poreux

    Energy Technology Data Exchange (ETDEWEB)

    Pinson, F

    2006-03-15

    - This work deals with the macroscopic modeling of turbulence in porous media. It concerns heat exchangers, nuclear reactors as well as urban flows, etc. The objective of this study is to describe in an homogenized way, by the mean of a spatial average operator, turbulent flows in a solid matrix. In addition to this first operator, the use of a statistical average operator permits to handle the pseudo-aleatory character of turbulence. The successive application of both operators allows us to derive the balance equations of the kind of flows under study. Two major issues are then highlighted, the modeling of dispersion induced by the solid matrix and the turbulence modeling at a macroscopic scale (Reynolds tensor and turbulent dispersion). To this aim, we lean on the local modeling of turbulence and more precisely on the k - {epsilon} RANS models. The methodology of dispersion study, derived thanks to the volume averaging theory, is extended to turbulent flows. Its application includes the simulation, at a microscopic scale, of turbulent flows within a representative elementary volume of the porous media. Applied to channel flows, this analysis shows that even within the turbulent regime, dispersion remains one of the dominating phenomena within the macro-scale modeling framework. A two-scale analysis of the flow allows us to understand the dominating role of the drag force in the kinetic energy transfers between scales. Transfers between the mean part and the turbulent part of the flow are formally derived. This description significantly improves our understanding of the issue of macroscopic modeling of turbulence and leads us to define the sub-filter production and the wake dissipation. A f - <{epsilon}>f - <{epsilon}{sub w}>f model is derived. It is based on three balance equations for the turbulent kinetic energy, the viscous dissipation and the wake dissipation. Furthermore, a dynamical predictor for the friction coefficient is proposed. This model is then successfully applied to the study of turbulent channel flows. (author)

  4. Analysis and modeling of coupled thermo-hydro-mechanical phenomena in 3D fractured media; Analyse et modelisation des phenomenes couples thermo-hydromecaniques en milieux fractures 3D

    Energy Technology Data Exchange (ETDEWEB)

    Canamon Valera, I

    2006-11-15

    This doctoral research was conducted as part of a joint France-Spain co-tutelage PhD thesis in the framework of a bilateral agreement between two universities, the Institut National Polytechnique de Toulouse (INPT) and the Universidad Politecnica de Madrid (UPM). It concerns a problem of common interest at the national and international levels, namely, the disposal of radioactive waste in deep geological repositories. The present work is devoted, more precisely, to near-field hydrogeological aspects involving mass and heat transport phenomena. The first part of the work is devoted to a specific data interpretation problem (pressures, relative humidities, temperatures) in a multi-barrier experimental system at the scale of a few meters - the 'Mock-Up Test' of the FEBEX project, conducted in Spain. Over 500 time series are characterized in terms of spatial, temporal, and/or frequency/scale-based statistical analysis techniques. The time evolution and coupling of physical phenomena during the experiment are analyzed, and conclusions are drawn concerning the behavior and reliability of the sensors. The second part of the thesis develops in more detail the 3-Dimensional (3D) modeling of coupled Thermo-Hydro-Mechanical phenomena in a fractured porous rock, this time at the scale of a hundred meters, based on the data of the 'In-Situ Test' of the FEBEX project conducted at the Grimsel Test Site in the Swiss Alps. As a first step, a reconstruction of the 3D fracture network is obtained by Monte Carlo simulation, taking into account through optimization the geomorphological data collected around the FEBEX gallery. The heterogeneous distribution of traces observed on the cylindrical wall of the tunnel is fairly well reproduced in the simulated network. In a second step, we develop a method to estimate the equivalent permeability of a many-fractured block by extending the superposition method of Ababou et al. [1994] to the case where the permeability of the rock matrix is not negligible (matrix permeability may embody some finer fracturing in addition to pore space). When fracture flow is complemented by significant matrix permeability, it may be possible to avoid empirical connectivity-based corrections, which are used in the literature to account for non-percolation effects. The superposition approach is also applied here to coupled Hydro-Mechanical problems to obtain the equivalent coefficients of the 3D fractured medium, including the permeability tensor, but also elastic stiffness or compliance coefficients, as well as pressure-strain coupling coefficients (Biot). Finally, these results are used to develop a continuum equivalent model for 3D coupled Thermo-Hydro-Mechanics, including: hydro-mechanical coupling via tensorial Biot equations (non-orthotropic), a Darcian flow in an equivalent porous medium (anisotropic permeability), as well as thermal stresses and heat transport by diffusion and convection, taking into account the thermal expansivity of water. Transient simulations of the excavation of the FEBEX gallery, and of the heating due to hypothetical radioactive waste canisters, are conducted using the Comsol Multiphysics software (3D finite elements). The results of numerical simulations are analyzed for different cases and different ways of stressing the system. Finally, preliminary comparisons of simulations with time series data collected during the 'In-Situ Test' of FEBEX yield encouraging results. (author)

  5. Method of modelization assistance with bond graphs and application to qualitative diagnosis of physical systems; Methode d'aide a la modelisation par graphes de liaison et utilisation pour le diagnostic qualitatif de systemes physiques

    Energy Technology Data Exchange (ETDEWEB)

    Lucas, B.

    1994-05-15

    After having recalled the usual diagnosis techniques (failure index, decision tree) and those based on an artificial intelligence approach, the author reports a research aimed at exploring the knowledge and model generation technique. He focuses on the design of an aid to model generation tool and aid-to-diagnosis tool. The bond graph technique is shown to be adapted to the aid to model generation, and is then adapted to the aid to diagnosis. The developed tool is applied to three projects: DIADEME (a diagnosis system based on physical model), the improvement of the SEXTANT diagnosis system (an expert system for transient analysis), and the investigation on an Ariane 5 launcher component. Notably, the author uses the Reiter and Greiner algorithm

  6. Electro-spray ionization - mass spectrometry (ESI/MS) and molecular modelling, two complementary approaches. Application to calixarenes; Electrospray - spectrometrie de masse (ESI/MS) et modelisation moleculaire, deux approches complementaires. Application aux calixarenes

    Energy Technology Data Exchange (ETDEWEB)

    Allain, F.; Virelizier, H.; Moulin, Ch. [CEA Saclay, Dept. des Procedes d' Enrichissement, 91 - Gif-sur-Yvette (France); Lamare, V.; Dozol, J.F. [CEA Cadarache, Dept. d' Entreposage et de Stockage des Dechets, 13 - Saint-Paul-lez-Durance (France)

    2001-07-01

    The molecular dynamics simulation and the experimental results obtained by the ESI/MS technique have shown that the stability of the calixarene - alkaline cation complexes is dependent of the medium. Indeed, in solution, the calixarene presents a strong affinity for cesium whereas in gaseous phase, the strong affinity is for sodium. The stability of the [calixarene+Na]{sup +} complexes depends of the nature of the medium too; these two techniques having shown that the presence of a small quantity of water in the dilution solvent stabilizes the complex. At last, calixarenes with benzo groups on their crown have an affinity for sodium which is weak in solution but strong in gaseous phase. These different results show the excellent complementarity between the two techniques. (O.M.)

  7. Light ions radiobiological effects on human tumoral cells: measurements modelling and application to hadron-therapy; Mesures et modelisation des effets radiobiologiques des ions legers sur des cellules tumorales humaines: application a l'hadrontherapie

    Energy Technology Data Exchange (ETDEWEB)

    Jalade, P

    2005-11-15

    In classical radiotherapy, the characteristics of photons interactions undergo limits for the treatment of radioresistant and not well located tumours. Pioneering treatments of patients at the Lawrence Laboratory at Berkeley has demonstrated two advantages of hadrons beams: the Relative Biologic Effect (the RBE) and the ballistic of the beams. Since 1994, the clinical centre at Chiba, has demonstrated successfully the applicability of the method. A physics group, managed by G. Kraft, at Darmstadt in Germany, has underlined the advantages of carbon beams. An European pool, called ENGIGHT (European Network for LIGHt ion Therapy) has been created in which the French ETOILE project appeared. The purpose of the thesis concerns measurements and models of 'in vitro' human cells survival. In the first part, the nowadays situation in particles interactions, tracks and cells structures and radiobiology is presented here. The second is devoted to the models based on the beam tracks and localization of the physical dose. Discussion of sensitivity to various parameters of the model has been realized with the help of numerical simulations. Finally the predictions of the improved model has been compared to experimental irradiations of human cells with argon and carbon beams of the GANIL machine. Conclusion of such study shows the performance and limits of a local model for predicting the radiobiological efficiency of light ions in hadron-therapy. (author)

  8. Prediction by numerical modeling of the risk zone along a riverside exposed to a dam failure; Prevision par modelisation numerique de la zone de risque bordant un troncon de riviere subissant une rupture de barrage

    Energy Technology Data Exchange (ETDEWEB)

    Mahdi, T.F.

    2004-07-01

    The risk zone associated with the surge wave following dam failure is defined in this study using a newly developed methodology that incorporates the conventionally used maximum water levels, the sediment movement in the river bed and the possibility of bank failure. Although the risk zone is typically defined as the inundated area, extensive lateral erosion that causes landslides could also accompany the inundation. This study demonstrates that the stability of the riverbank (in terms of geotechnical considerations) can influence the delineation of the risk area. The combined disciplines of geotechnics and hydraulics can be used to follow the evolution of the riverbed and riverbanks during a flood event. This study also presents a structured methodology for the St. Venant shallow water wave equations which were used to determine the area likely to be flooded without taking into account sediment transport. It also discusses aspects of the sediment transport theory. Fluvial erosion and lateral bank failure are the basic physical processes responsible for bank retreat. The minimum energy dissipation rate theory is applied for fluvial erosion, while Bishop's modified method is used to analyze slope stability when evaluating lateral bank failures. A numerical modeling of flows over movable beds is presented along with a review of some of the available numerical models. A diagnostic phase that provides information needed to qualify the extent of the damage after a flood is also presented. Some of the numerical models to evaluate risk area were validated on a portion of the HaHa River which was affected in the 1996 Saguenay flood. The new methodology, applied to the Outaouais River at Notre Dame du Nord in Quebec, produces a risk area much greater than that obtained when only the inundated area is considered.

  9. Contribution to the conception, the modelling and the control of automotive power train and of electric converters; Contribution a la conception, la modelisation et la commande du groupe motopropulseur automobile et de convertisseurs d`energie electrique

    Energy Technology Data Exchange (ETDEWEB)

    Bidan, P.

    1998-12-14

    The overall work presented in this thesis globally deals with the conception, the modelling and the control of some applied systems. The first part is devoted to the automotive domain. It concerns the still actualized context of energy savings and reduction of atmospheric pollution, by the improvement of the engine/drive-train control and more particularly of the spark-ignition engine control. In this aim, a first investigation deals with the fuel/air ratio control during the transient phases and suggests the use of an intake manifold pressure control by means of an electric throttle actuator, in order to control the air filling. An original strategy of simultaneous control of fuel and air fillings is then proposed. Another improvement method by an electrical assistance of the engine using a self-controlled synchronous machine drive, is also developed. In the frame of idle-speed control, a prototype allows to show the contribution of this assistance in term of stability and consumption reduction. The second part of the report principally deals with the modelling and the control of electric converters. After a first section describing a methodology of a control-oriented modelling for some classes of static converters, an example of a design of the whole converter-controller is suggested. On the basis of a fourth order voltage switched-mode inverter which should operate as a function generator, the close interaction between filtering quality, structure design and control performances is analyzed and a solution is proposed. For every subject taken up, some prospective features are suggested as well. (author) 37 refs.

  10. Modelling of the flow in the interface of a composite liner at the bottom of a municipal waste landfill; Modelisation des ecoulements dans les interfaces des barrieres d'etancheite composites des installations de stockage de dechets

    Energy Technology Data Exchange (ETDEWEB)

    Cartaud, F

    2004-11-15

    Composite liner at the bottom of waste landfill is based, in France, on a geo-membrane overlapping a compacted clay liner. Defects exist in geo-membranes and leachates, provided by water percolation through the waste, then flow in the interface between the two components of the lining system. The present work consisted in analysis, quantification and modelling of the leakage process in the interface. The experimental study has been carried out on a one-meter scale device in laboratory and allowed to assess the role of normal stress on the flow rate in interface. The case where a geo-textile is present beneath the geo-membrane has been also studied. The modelling allows to take into account more accurately the geometry of the interface and ensures a better quantification of leachate flow rates than using existing methods. (author)

  11. Experimental approach and micro-mechanical modeling of the creep behavior of irradiated zirconium alloys; Approche experimentale et modelisation micromecanique du comportement en fluage des alliages de zircomium irradies

    Energy Technology Data Exchange (ETDEWEB)

    Ribis, J

    2007-12-15

    The fuel rod cladding, strongly affected by microstructural changes due to irradiation such as high density of dislocation loops, is strained by the end-of-life fuel rod internal pressure and the potential release of fission gases and helium during dry storage. Within the temperature range that is expected during dry interim storage, cladding undergoes long term creep under over-pressure. So, in order to have a predictive approach of the behavior of zirconium alloys cladding in dry storage conditions it is essential to take into account: initial dislocation loops, thermal annealing of loops and creep straining due to over pressure. Specific experiments and modelling for irradiated samples have been developed to improve our knowledge in that field. A Zr-1%Nb-O alloy was studied using fine microstructural investigations and mechanical testing. The observations conducted by transmission electron microscopy show that the high density of loops disappears during a heat treatment. The loop size becomes higher and higher while their density falls. The microhardness tests reveal that the fall of loop density leads to the softening of the irradiated material. During a creep test, both temperature and applied stress are responsible of the disappearance of loops. The loops could be swept by the activation of the basal slip system while the prism slip system is inhibited. Once deprived of loops, the creep properties of the irradiated materials are closed to the non irradiated state, a result whose consequence is a sudden acceleration of the creep rate. Finally, a micro-mechanical modeling based on microscopic deformation mechanisms taking into account experimental dislocation loop analyses and creep test, was used for a predictive approach by constructing a deformation mechanism map of the creep behavior of the irradiated material. (author)

  12. Modelling and numerical simulation of two-phase flows using the two-fluid two-pressure approach; Modelisation et simulation numerique des ecoulements diphasiques par une approche bifluide a deux pressions

    Energy Technology Data Exchange (ETDEWEB)

    Guillemaud, V

    2007-03-15

    This thesis is devoted to the modelling and numerical simulation of liquid-vapor flows. In order to describe these phase transition flows, a two-fluid two-pressure approach is considered. This description of the liquid-vapor mixing is associated to the seven-equation model introduced by Baer and Nunziato. This work investigates the properties of this model in order to simulate the phase transition flows occurring in nuclear engineering. First, a theoretical thermodynamic framework is constructed to describe the liquid-vapor mixing. Provided with this framework, various modelling choices are suggested for the interaction terms between the phases. These closure laws comply with an entropy inequality. The mathematical properties of this model are thereafter examined. The convective part is associated to a nonconservative hyperbolic system. First, we focus on the definition of its weak solutions. Several flow regimes for the two-phase mixing derive from this analysis. Such regimes for the two-phase flows are analogous to the torrential and fluvial regimes for the shallow-water equations. Furthermore, we establish the linear and nonlinear stabilities of the liquid-vapor equilibrium. Finally, the implementation of a turbulence model and the introduction of a reconstruction process for the interfacial area are investigated in order to refine the description of the interfacial transfers. Using a fractional step approach, a Finite Volume method is at last constructed to simulate this model. First, various nonconservative adaptations of standard Riemann solvers are developed to approach the convective part. Unlike the classic nonconservative framework, these schemes converge towards the same solution. Furthermore, a new relaxation scheme is proposed to approach the interfacial transfers. Provided with these schemes, the whole numerical method preserves the liquid-vapor equilibria. Using this numerical method, a careful comparison between the one- and two-pressure two-fluid models is presented. The numerical simulation of the strongly unbalanced liquid-vapor flows is at last applied to the safety analysis of the pressurized water nuclear reactors. (author)

  13. Tracer transfer in consolidated porous medium and fractured porous medium: experimentations and modelling; Transferts d'un traceur en milieu poreux consolide et en milieu poreux fissure: experimentations et modelisations

    Energy Technology Data Exchange (ETDEWEB)

    Dalla Costa, C

    2007-07-15

    We try to identify and model physical and chemical mechanisms governing the water flow and the solute transport in fractured consolidated porous medium. An original experimental device was built. The 'cube' consists of an idealized fractured medium reproduced by piling up consolidated porous cubes of 5 cm edge. Meanwhile, columns of the homogeneous consolidated porous medium are studied. The same anionic tracing technique is used in both cases. Using a system analysis approach, we inject concentration pulses in the device to obtain breakthrough curves. After identifying the mass balance and the residence time, we fit the CD and the MIM models to the experimental data. The MIM model is able to reproduce experimental curves of the homogeneous consolidated porous medium better than the CD model. The mobile water fraction is in accordance with the porous medium geometry. The study of the flow rate influence highlights an interference dispersion regime. It was not possible to highlight the observation length influence in this case. On the contrary, we highlight the effect of the observation scale on the fractured and porous medium, comparing the results obtained on a small 'cube' and a big 'cube'. The CD model is not satisfactory in this case. Even if the MIM model can fit the experimental breakthrough curves, it was not possible to obtain unique parameters for the set of experiments. (author)

  14. L'IIASA and the integrated simulation of the trans-border atmospheric pollution assessment and evaluation; L'IIASA et la modelisation integree de la pollution atmospherique transfrontiere. Bilan et evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Soleille, S.; Brignon, J.M.; Farret, R.; Landrieu, G.; Le Gall, A.C.; Rouil, L

    2003-09-15

    The RAINS model is an integrated evaluation model for many pollutants and many effects, developed by he IIASA. This model studies the emissions of 4 atmospheric pollutants (nitrogen oxides, sulfur oxides, ammonium and volatile organic compounds) and the necessary costs to reduce them and the dispersion of these pollutants and their effects (tropospheric ozone formation, acidification and eutrophication). The model can be used in activities scenario mode (energy, agriculture, transports...) to calculate the emissions and their effects or in optimization mode to calculate strategies of emissions control from environmental constraints. (A.L.B.)

  15. Modelling and characterization of the PEM fuel cell to study interactions with power converters; Modelisation et caracterisation de la pile pem pour l'etude des interactions avec les convertisseurs statiques

    Energy Technology Data Exchange (ETDEWEB)

    Fontes, G.

    2005-09-15

    The climatic and energy challenges were now clearly stated. The use of hydrogen is one of the best ways which gives many hopes. Fuel cells are an essential link in the chain of the use of hydrogen. Thus, a lot of studies have been undertaken throughout the world on fuel cells in many fields of physics. Concerning the field of power electronics, a lot of work on distributed generation technologies using fuel cells has been realised too and a great number of power converters dedicated to fuel cells have been studied. However, very few studies have been undertaken on the interactions between fuel cells and power converters. The goals of this work are to study interactions between fuel cells and power converters. Some requirements for the power electronic engineer can follow from this work. This work proposes high signal dynamic models of a H{sub 2}/O{sub 2} PEM fuel cell. These models include the different physical and chemical phenomena. Specific methods based on a limited number of original experiments (low frequency current sweeps) allow to extract the model parameters. These models are used to study the interactions between fuel cells and power converters which are the most used: buck chopper, boost chopper, inverters. The important part of the double layer capacitors has thus been underlined: they can filter the current harmonics created by the power converters. Finally, some choices of filtering elements to be connected to the fuel cell are proposed. (author)

  16. Propagation Modelling and Decision Aids for Communications, Radar and Navigation Systems (La Modelisation de la Propagation et Aides a la Decision Pour les Sysemes de elecommunicaions, de Radar et de Navigation)

    Science.gov (United States)

    1994-09-01

    In these lectures a number of than our knowlede of the underlying ionosphere. equations will be given describing the evaluation of Fortunately, there...and RR disturbances than is HF, and requires no frequency Q = angle between the trail and vector from the trail management in order to maintain viable...for Radio Spectrum Management , tion to the mobile radio channel". IEEE Trans. Veh. Telh. VT- 110 pp., rn, Geneva. 1993a. 34(2%. 86-96, 1985. ITU

  17. Size graded sediment dynamics: from the processes characterization to the transport modelling in the English Channel; Dynamique sedimentaire multiclasse: de l'etude des processus a la modelisation en Manche

    Energy Technology Data Exchange (ETDEWEB)

    Blanpain, O.

    2009-10-15

    The purpose of this work is the implementation of a sediment transport model in the English Channel. The design of such a model requires the identification of the physical processes, their modelling and their in-situ validation. Because of the sedimentary particularities of the study area, modelling of the mechanical behaviour of a non uniform mixture of sediments and particularly of the fine grains within a coarse matrix is required. This study focused on the characterization of the relevant processes by acquisition of experimental and in-situ data. Data acquired in hydro-sedimentary conditions comparable to those found in the English Channel are scarce. A new instrument and image processing technique were specifically conceived and implemented in-situ to observe and measure, with a high temporal resolution, the dynamics of a strongly heterogeneous mixture of particles in a grain-size scale. The data collected compared well with several existing formulations. One of these formulations was chosen to be adapted. The transfer dynamics of fine grains in coarse sediments and their depth of penetration were acquired from stratigraphic samples. The sediment transport model deals with multi-size grains and multi sedimentary layers, it is forced by swell and currents, and accounts for bead load and suspended load transports. It was applied to realistic scenarios for the English Channel. (author)

  18. Modelling coupled to behaviour and damage; rupture criteria in the field of the PVDF transition; Modelisation couplee comportement endommagement et criteres de rupture dans le domaine de la transition du PVDF

    Energy Technology Data Exchange (ETDEWEB)

    Lafarge, M.

    2004-12-15

    Pipeline structures are used for the transport of crude oil in offshore fields. Flexible pipelines are made of an inner metallic layer, which accommodates flexural and tensile strains and of a PVDF layer, which guarantees watertightness. The aim of the study is to determine which conditions can lead to a risk of brittle fracture of the polymer material. The PVDF of interest was extruded without plasticizer and therefore it differs considerably from the standard industrial grade. The lack of plasticizer leads to a difficult extrusion, which creates significant porosity (10%). Several specimens with various geometries were tested in order to analyse the detrimental effect of a defect regarding damage evolution and fracture mechanisms. During the deformation process, the material is characterized by whitening due to void growth and material elongation. Ductile fracture of PVDF is promoted by high temperatures, low strain rates, low stress triaxiality ratios and flexural loading, whereas brittle fracture is favoured by low temperatures (T{<=}Tg = -42 C), high strain rates, high stress triaxiality ratios and tensile loading. The Gurson-Tvergaard-Needleman model, usually used for metallic materials, was employed to model behaviour and damage of PVDF material at various temperatures. Damage is essentially due to void growth and is described by using q1 and q2 parameters. The constitutive model has been successfully applied to account for all aspects of the mechanical behaviour of the material. Crazing is the failure mode and final fracture is assumed to occur when either, the maximum principal plastic strain at low stress triaxiality or the porosity at high stress triaxiality reaches respectively a critical value. Furthermore, the ductile to brittle transition criterion is found to be the maximum principal stress. This latter allows to explain both fracture mechanisms modes in flexural and tensile loading. (author)

  19. Numerical modelling in building thermo-aeraulics: from CFD modelling to an hybrid finite volume / zonal approach; Modelisation numerique de la thermoaeraulique du batiment: des modeles CFD a une approche hybride volumes finis / zonale

    Energy Technology Data Exchange (ETDEWEB)

    Bellivier, A.

    2004-05-15

    For 3D modelling of thermo-aeraulics in building using field codes, it is necessary to reduce the computing time in order to model increasingly larger volumes. The solution suggested in this study is to couple two modelling: a zonal approach and a CFD approach. The first part of the work that was carried out is the setting of a simplified CFD modelling. We propose rules for use of coarse grids, a constant effective viscosity law and adapted coefficients for heat exchange in the framework of building thermo-aeraulics. The second part of this work concerns the creation of fluid Macro-Elements and their coupling with a calculation of CFD finite volume type. Depending on the boundary conditions of the problem, a local description of the driving flow is proposed via the installation and use of semi-empirical evolution laws. The Macro-Elements is then inserted in CFD computation: the values of velocity calculated by the evolution laws are imposed on the CFD cells corresponding to the Macro-Element. We use these two approaches on five cases representative of thermo-aeraulics in buildings. The results are compared with experimental data and with traditional RANS simulations. We highlight the significant gain of time that our approach allows while preserving a good quality of numerical results. (author)

  20. Contributions to micromechanical model of the non linear behavior of the Callovo-Oxfordian argillite; Contributions a la modelisation micromecanique du comportement non lineaire de l'argilite du callovo-oxfordien

    Energy Technology Data Exchange (ETDEWEB)

    Abou-Chakra Guery, A

    2007-12-15

    This work is performed in the general context of the project of underground disposal of radioactive waste, undertaken by the French National Radioactive Waste Management Agency (ANDRA). Due to its strong density and weak permeability, the formation of Callovo-Oxfordian argillite is chosen as one of possible geological barriers to radionuclides. The objective of the study to develop and validate a non linear homogenization approach of the mechanical behavior of Callovo-Oxfordian argillites. The material is modelled as a composite constituted of an elasto(visco)plastic clay matrix and of linear elastic or elastic damage inclusions. The macroscopic constitutive law is obtained by adapting the incremental method proposed by Hill. The derived model is first compared to Finite Element calculations on unit cell. It is then validated and applied for the prediction of the macroscopic stress-strain responses of the argillite at different geological depths. Finally, the micromechanical model is implemented in a commercial finite element code (Abaqus) for the simulation of a vertical shaft of the underground laboratory. This allows predicting the distribution of damage state and plastic strains and characterizing the excavation damage zone (EDZ). (author)

  1. Numerical simulation of compressible multiphase flows with or without phase transition. Application to laser plasma interaction; Modelisation et simulation d'ecoulements multiphasiques compressibles avec ou sans changement de phase. Application a l'interaction laser-plasma

    Energy Technology Data Exchange (ETDEWEB)

    Perrier, V

    2007-07-15

    This work deals with the modelling and simulation of compressible flows. A seven equations model is obtained by homogenizing the Euler system. Fluctuation terms are modeled as relaxation terms. When the relaxation terms tend to infinity, which means that the phases are well mixed, a five equations model is obtained via an asymptotic expansion. This five equations model is strictly hyperbolic, but nonconservative. The discretization of this model is obtained by an asymptotic expansion of a scheme for the seven equations model. The numerical method is implemented, validated on analytic cases, and compared with experiments in the case of multiphase shocks. We are then interested in the modelling of phase transition with two equations of state. Optimization of the mixture entropy leads to the fact that three zones can be separated: one in which the pure liquid is the most stable, one in which the pure gas is the most stable, and one in which a mixture with equality of temperature, pressure and chemical potentials is the most stable. Conditions are given on the coupling of the two equations of state for ensuring that the mixture equation of state is convex, and that the system is strictly hyperbolic. In order to take into account phase transition, a vaporization wave is introduced in the solution of the Riemann problem, that is modeled as a deflagration wave. It is then proved that the usual closure, the Chapman-Jouguet closure, is wrong in general, and a correct closure in the case when both fluids have a perfect gas equation of state. Last, the solution of the Riemann problem is implemented in a multiphase code, and validated on analytic cases. In the same code, models of laser release and thermal conduction are implemented to simulate laser ablation. The results are comparable to the ones obtained with scale laws. The last chapter, fully independent, is concerned with correctors in stochastic homogenization in the case of heavy tails process. (author)

  2. Safety properties test data selection from an algebraic model of Lustre programs; Selection de tests de proprietes de surete a partir d'une modelisation algebrique de programmes lustre

    Energy Technology Data Exchange (ETDEWEB)

    Hsiao, N.Ch

    1995-07-01

    In the context to validate an industrial software, which is a set of reactive programs, we are confronted with the safety properties verification problem. This thesis reports an experience in which our goal is to generate the test data satisfying a safety property. The software to be validated is designed with the SAGA tool, in which a view can be regarded as a program of a programming language called LUSTRE. We adapt a test data generation tool called LOFT to this kind of programs. In this way, we consider the functional testing method on which the LOFT tool is based. Given any LUSTRE program, we try to give it an algebraic model because LOFT treats algebraic specifications. So, our task consists In defining a formal framework in which any LUSTRE program can be translated into a LOFT module: based on an operational semantics of the LUSTRE language, the flow types 'T-flow' are specified with the constructive algebraic formalism, then implemented in a LOFT modules base. Next, in a test selection process assisted by LOFT, a safety property Is expressed by an equation to join other control hypotheses, and to guide the test data selection. Some concrete test data set are generated in this way on some significant examples. This experience confirm the feasibility of formal method on test data selection for the reactive programs. (author)

  3. Study and simulation of the resistance of floccules to shear breakage in a centrifuge; Etude et modelisation de la destruction d`agregats de colloides par les contraintes de cisaillement creees dans un separateur centrifuge

    Energy Technology Data Exchange (ETDEWEB)

    Touron, E

    1995-09-29

    In France, spent fuels are in most cases reprocessed. The aim of the reprocessing is to separate the recyclable fissile materials (uranium, plutonium for instance) of radioactive wastes. The industrial process used until now is the Purex (Plutonium Uranium Refining by EXtraction) process. The two main first steps of this process are nowadays industrially completely controlled. Nevertheless, it exists several secondary operations which can interfere with the good unfolding of this process main steps as for instance, the clarification of the dissolution liquors. The aim of this work is then to improve particularly the separation efficiency between small particles and the associated dissolution liquors. The experimental study of the flow inside the rotor shows complex hydrodynamics arising from turbulence and secondary flows. This turbulent flow is likely to be capable of re-suspending small and flow density particles. The use of flocculants is a way of improving separation efficiencies. In gravity sedimentation, flocculants are frequently used to improve settling of fine particles, by causing them to aggregate behaving as if they were larger. Under slight turbulence, the flocs, which may be fragile, remain intact. In centrifugal sedimentation, shear rates are high and may result in complete floc breakup. Choice of the correct flocculant, proper dosage and right conditioning time result in strong, compact flocs so that flocculants can be used successfully. A diminution of the centrifugal shield from nominal conditions results in a diminution of shear breakage (in the feed zone) so that a total recover of solids may be obtained.(author). 122 refs., 95 figs., 28 tabs.

  4. Modeling and simulation of critical parameters of the first chamber of the dimuon arm spectrometer of the Alice experiment; Modelisation et simulation de parametres critiques de la premiere station du spectrometre dimuons d'ALICE

    Energy Technology Data Exchange (ETDEWEB)

    Guez, D

    2003-10-01

    The Alice experiment that is dedicated to the study of ultra-relativistic heavy ion collisions, will take place in the future large hadron collider (LHC) at CERN. The dimuon arm spectrometer of the Alice experiment is devoted to the search of a new signature of the existence of the quark gluon plasma (QGP). The first chapter is dedicated to the physics notions linked to the study of QGP, a few signatures are proposed for the detection of QGP, particularly the signature concerning the production rate of quarkonium. The second chapter deals with particle detection involved in Alice experiment, the dimuon arm spectrometer is a detector dedicated to the track reconstruction of muons issued from the decay of heavy mesons from J/{psi} and {upsilon} families. The third and the fourth chapters present the studies made to integrate a reliable model of the dimuon arm in the global simulation code of Alice (Aliroot). The fifth chapter presents the software TB{sup 2} that has been developed within the framework of this thesis in order to check and control the output data when the detector is tested with a real particle beam. The sixth chapter presents the results of the tests that have been performed with a 7 GeV/c pion beam. These tests have shown that the electronic noise is coherent with the specifications of Alice experiment. A factor 1,8 between the highest and the weakest values of the gain has been measured in the chamber. The detection efficiency of the chamber has been estimated to 99% in the different cases studied. (A.C.)

  5. Modeling and experimental study of heat transfer in innovate building components for industrial production; Modelisation et etude experimentale des echanges de chaleur dans des composants innovants de batiment industriels

    Energy Technology Data Exchange (ETDEWEB)

    Lacena-Neildez, A.

    2000-05-15

    The main objective of the thesis is the study of a new roof thermal behaviour with the thermal transfer by radiation and convection in order to propose an alternative to the mechanical air-conditioning in the overseas islands, and to determine the way of improving the energy performance. Two fundamental results were obtained. First, the coating has a great importance in relation with the radiative properties. Secondly, air channel geometries can complete insufficient coatings in their cooling purpose. In this thesis, both experimental and modelling analyses were carried out. A solar simulator was used for the experiment to carry out a comparative study of prototypes. A performance indicator was defined; it is the eliminated flux, because the temperature is not sufficient to describe the heat exchange. At the same time, the radiative properties of coatings were measured and a characterisation of paints allows to start a new research of innovative infrared reflective paints. A mono-dimensional model was developed describing thermal exchanges in an air channel component. A sensibility study was carried out which allows to determine the main parameters. The experimental study validated the model in rear flux, more realistic than stagnation. Finally, the feasibility of this new steel component was concluded by a technical-economical study. (author)

  6. Modelling of the source of particles associated with the injection of a pellet in a tokamak; Modelisation de la source de matiere associee a l'injection d'un glacon dans un Tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Waller, V

    2003-03-01

    The most suitable fuel supplying method of present tokamaks is the injection of cryogenic hydrogen pellets. The effectiveness of the system depends on both the poloidal location of the pellet launching point and ablation profile. Since the knowledge of the source of matter is a key parameter for building scenarios and analysing experiments, it is important to have at one's disposal a reliable modelling i) of the ablation process accounting for the fast ion and electron populations resulting from additional heating or current drive and ii) of the matter redistribution inside the discharge. This is the purpose of this thesis, which can be split in three main parts. First and foremost, the physical processes responsible for the extra-ablation due to the supra-thermal electrons and ions are analysed. It is shown that the large Larmor radius of the hot ions yields an increase of the section of the flux tube inside which the ion trajectory intercepts the ablation cloud (of cylindrical shape, along the magnetic field). Moreover, the particle entry into the cloud no longer remains essentially limited to the ends of the cylinder, what decreases the path the ions have to cover before reaching the pellet. These two geometrical effects result in an enhancement of the heat flux at the pellet surface, and thus in an extra-ablation in NBI or ICRH experiments. The second part of the work is devoted to the modelling of the homogenization of the ablated matter in the discharge. On each magnetic surface, the pellet deposits a spatially limited globule of cold and dense material where a charge separation takes place due to the electron and ion drifts in the toroidal magnetic field. Then a vertical electric field builds up, that is cause of the drift of the high density region towards the Low Field Side of the tokamak. This motion lasts as long as the pellet is in a situation of open-circuit and is the cause of the outward (respectively inward) displacement of the density increase with respect to the ablation profile for pellets launched from the LFS of the torus (respectively High Field Side). In addition, for HFS launched pellets, the ablated material that drifts in front of the pellet cools down the plasma, thus decreasing the ablation rate and increasing its penetration. The last part concerns the analysis of the anomalous deflection of the pellet trajectory observed in sawtoothing plasmas. This deflection is due to the rocket effect associated with the Spitzer-Hdrm distortion of the electron distribution. (author)

  7. Modeling of the fatigue intragranular strain hardening of metals at high temperature with keeping up time; Modelisation de l'ecrouissage intragranulaire en fatigue des metaux a haute temperature avec temps de maintien

    Energy Technology Data Exchange (ETDEWEB)

    Sauzay, M.; Mottot, M.; Noblecourt, M.; Allais, L.; Monnet, I.; Perinet, J. [CEA Saclay, Service de Recherche en Metallurgie Appliquee, DMN/SRMA, 91 - Gif-sur-Yvette (France)

    2003-07-01

    This study aims at foreseeing the behaviour of some alloys during high temperature fatigue-relaxation (creep) conditions when the maximum deformation is maintained during long times (about a month for each cycle). Such experiments can hardly be performed with laboratory tests. A simple modeling of the restoration occurring during the keeping of the conditions of deformation can explain the absence of dislocation microstructures. Abstract only. (J.S.)

  8. Simulation of the high temperature intergranular strain hardening in fatigue of materials with hold time; Modelisation de l'ecrouissage intragranulaire en fatigue des metaux a haute temperature avec temps de maintien

    Energy Technology Data Exchange (ETDEWEB)

    Sauzay, M.; Mottot, M.; Noblecourt, M.; Allais, L.; Monnet, I.; Perinet, J

    2003-07-01

    This paper aims to simulate the behavior of some alloys in high temperature fatigue-relaxation (creep), for a long hold time (one month for each cycle) when laboratory experiments are difficult to realize. The first part presents an estimation of the internal intergranular stresses. The second part deals with the recovery occurring during the hold time. (A.L.B.)

  9. Radioactive waste combustion / vitrification under arc plasma: thermal and dynamic modelling; Combustion - vitrification de dechets radioactifs par plasma d'arc: modelisation de la thermique et de la dynamique

    Energy Technology Data Exchange (ETDEWEB)

    Barthelemy, B

    2003-07-01

    This thesis concerns the thermal and dynamic modelling for a combustion/vitrification process of surrogate radioactive waste under transferred arc plasma. The writer presents the confinement processes for radioactive waste using arc plasma and the different software used to model theses processes. This is followed by a description of our experimental equipment including a plasma arc reactor and an inductive system allowing the homogenization of glass temperature. A combustion/vitrification test is described. Thermal and material balances were discussed. The temperature fields of plasma arc and the glass frit conductivity are measured. Finally, the writer describes and clarifies the equations solved for the simulations of the electrically plasma arc and the glass melting including the thin layer of glass frit coating the crucible cold walls. The modelling results are presented in the form of spatial distribution of temperature, velocity and volume power... (author)

  10. Radioactive waste combustion-vitrification under arc plasma: thermal and dynamic modelling; Combustion - vitrification de dechets radioactifs par plasma d'arc: modelisation de la thermique et de la dynamique

    Energy Technology Data Exchange (ETDEWEB)

    Barthelemy, B

    2003-06-01

    This thesis concerns the thermal and dynamic modelling for a combustion/vitrification process of surrogate radioactive waste under transferred arc plasma. The writer presents the confinement processes for radioactive waste using arc plasma and the different software used to model theses processes. This is followed by a description of our experimental equipment including a plasma arc reactor and an inductive system allowing the homogenization of glass temperature. A combustion/vitrification test is described. Thermal and material balances were discussed. The temperature fields of plasma arc and the glass frit conductivity are measured. Finally, the writer describes and clarifies the equations solved for the simulations of the electrically plasma arc and the glass melting including the thin layer of glass frit coating the crucible cold walls. The modelling results are presented in the form of spatial distribution of temperature, velocity and voluminal power... (author)

  11. SIMULATION ET MODELISATION DE LA VARIATION DE LA MOBILITE DE HALL DES PHOTOELECTRONS EN FONCTION DE LA TEMPERATURE DANS LES CRISTAUX DE n-ZnSe :Zn IRRADIES AVEC DES ELECTRONS ENERGETIQUES

    Directory of Open Access Journals (Sweden)

    D DJOUADI

    2007-12-01

    Full Text Available Dans l’intervalle de températures [77..300 K] a été mesurée la mobilité de Hall des électrons d’équilibre et des photoélectrons dans les cristaux de n-ZnSe :Zn irradiés avec un faisceau d’électrons d’énergie E=1,3 MeV et dont la dose d’irradiation varie entre 2,73 1016 et 5.19 1017 électrons/cm2 . Le comportement de la mobilité des photoélectrons s’explique parfaitement dans le cadre d’un modèle à deux-barrières d’un semi-conducteur inhomogène représentant une matrice faiblement ohmique contenant des inclusions fortement ohmiques (clusters. En se basant sur les théories de Shik et de Petrossiyan , une expression approximative de la mobilité de Hall a été obtenue. Il a été montré que ce modèle fonctionne parfaitement pour les petites doses d’irradiation. Lorsque la dose dépasse une certaine valeur critique ( D= 2.98 1017 électrons /cm2 le modèle considéré passe au modèle du potentiel à relief aléatoire.

  12. Modelling the long-range transport. Atmospheric model from the Oslo EMEP-W center; Modelisation du transfert a longue distance modele atmospherique du centre Emep-W- a Oslo

    Energy Technology Data Exchange (ETDEWEB)

    Joffre, S. [Institut Meteorolique de Finlande Geographical Research Vuorikatu, Helsinki (Finland)

    1997-12-31

    In the framework of the European Monitoring and Evaluation Program (EMEP) concerning transfrontier air pollution in Europe, a model has been developed which gives, based on pollution emission and meteorological data, monthly and annual values for the atmospheric content of ten major pollutants, the deposited dry and wet compounds, and the source allocations. Physical principles of the model and its validation are described

  13. The carbon cycle in a land surface model: modelling, validation and implementation at a global scale; Cycle du carbone dans un modele de surface continentale: modelisation, validation et mise en oeuvre a l'echelle globale

    Energy Technology Data Exchange (ETDEWEB)

    Gibelin, A.L

    2007-05-15

    ISBA-A-gs is an option of the CNRM land surface model ISBA which allows for the simulation of carbon exchanges between the terrestrial biosphere and the atmosphere. The model was implemented for the first time at the global scale as a stand-alone model. Several global simulations were performed to assess the sensitivity of the turbulent fluxes and Leaf Area Index to a doubling of the CO{sub 2} atmospheric concentration, and to the climate change simulated by the end of the 21. century. In addition, a new option of ISBA, referred to as ISBA-CC, was developed in order to simulate a more detailed ecosystem respiration by separating the autotrophic respiration and the heterotrophic respiration. The vegetation dynamics and the carbon fluxes were validated at a global scale using satellite datasets, and at a local scale using data from 26 sites of the FLUXNET network. All these results show that the model is sufficiently realistic to be coupled with a general circulation model, in order to account for interactions between the terrestrial biosphere, the atmosphere and the carbon cycle. (author)

  14. Numerical modeling for the electromagnetic non-destructive evaluation: application to the non-destructive evaluation of concrete; Modelisation numerique pour l'evaluation non destructive electromagnetique: application au controle non destructif des structures en beton

    Energy Technology Data Exchange (ETDEWEB)

    Travassos, L

    2007-06-15

    Concrete is the most common building material and accounts for a large part of the systems that are necessary for a country to operate smoothly including buildings, roads, and bridges. Nondestructive testing is one of the techniques that can be used to assess the structural condition. It provides non perceptible information that conventional techniques of evaluation unable to do. The main objective of this work is the numerical simulation of a particular technique of nondestructive testing: the radar. The numerical modeling of the radar assessment of concrete structures make it possible to envisage the behavior of the system and its capacity to detect defects in various configurations. To achieve this objective, it was implemented electromagnetic wave propagation models in concrete structures, by using various numerical techniques to examine different aspects of the radar inspection. First of all, we implemented the finite-difference time-domain method in 3D which allows to take into account concrete characteristics such as porosity, salt content and the degree of saturation of the mixture by using Debye models. In addition, a procedure to improve the radiation pattern of bow-tie antennas is presented. This approach involves the Moment Method in conjunction with the Multi objective Genetic Algorithm. Finally, we implemented imaging algorithms which can perform fast and precise characterization of buried targets in inhomogeneous medium by using three different methods. The performance of the proposed algorithms is confirmed by numerical simulations. (author)

  15. Analysis of the reactivity of sulphur compounds in petroleum cuts: kinetics and modelling of hydro-treating; Analyse de la reactivite des composes soufres dans les coupes petrolieres: cinetique et modelisation de l'hydrotraitement

    Energy Technology Data Exchange (ETDEWEB)

    Lopez Garcia, C.

    2000-12-01

    The study of the hydro-treating of middle distillates comprised the following steps: - Identification and reactivity study of the sulphur compounds present in these petroleum cuts; - Modelling of the process by a chemical kinetic approach. The hydro-treating of middle distillates is a refining process that allows elimination of organic compounds containing sulphur, nitrogen, oxygen and metals. The process also hydrogenates the aromatic compounds providing improved cetane index gas-oils while respecting the regulations that severely limit the content of sulphur compounds. The extension and the improvement of a kinetic model for the hydro-treating of LCO gas-oils (light cycle oil gas-oils) are presented in this work. In order to improve the hydro-desulfurization model predictions, a detailed identification of the sulphur compounds contained in LCO gas-oils was carried out using gas chromatography with a sulphur chemiluminescence detector (GC-SCD). The most refractory sulphur compounds (alkyl-di-benzothiophenes) were identified and lumped into different families. Based on a lumped reaction scheme with a Langmuir-Hinshelwood representation, the model takes into account the influence of temperature, total pressure and hydrogen sulphide partial pressure on the reaction rates for hydro-desulfurization, hydro-denitrogenation and hydro-de-aromatization. The model parameter estimation was based on experiments that were carried out on a micro-pilot unit using an industrial sulfided NiMo/Al{sub 2}O{sub 3} catalyst and LCO feedstocks. The analytical study of the sulphur compounds was also extended to the case of straight run gas-oils (SR). For these feedstocks, a method using high-resolution mass spectrometry coupled with gas chromatography (GC-HRMS) was developed. In this way, the kinetic model can now be extended for the SR gas-oil hydro-treating or for LCO-SR mixtures. (author)

  16. Modelling and simulation of the fuel cell energy source for the Hydro-Gen vehicle; Modelisation et simulation de la source d'energie a pile a combustible du vehicule Hydro-Gen

    Energy Technology Data Exchange (ETDEWEB)

    Schott, P.; Baurens, P. [CEA Grenoble, Dept. d' Etudes des Materiaux, DEM, 38 (France); Poirot, J.Ph. [PSA/DRIA/SEE, 78 - Velizy Villacoublay (France)

    2000-07-01

    A fuel cell generating set is a complex system in which the interactions between the different elements are chemical, hydraulic, thermal, mechanical and electric. The implementation and the optimization of such a system cannot be limited to the study of each element; the system analysis and then the modelling and the dynamical simulation are necessarily required. The bond-graphs theory is particularly well adapted to the multiplicity of the involved phenomena. In this article is presented the modelling used for the generating set of the Hydro-Gen plan. Some representative examples are given as well as the first qualitative results of the simulations. (O.M.)

  17. Multi-scale interaction between magnetic islands and microturbulence in magnetized plasmas; Modelisation et simulation de l'interaction multi-echelle entre ilots magnetiques et la microturbulence dans les plasmas de fusion magnetises

    Energy Technology Data Exchange (ETDEWEB)

    Muraglia, M.

    2009-10-15

    In a tokamak, it exists many kinds of instability at the origin of a damage of the confinement and worst of a lost of a confinement. This work presents a study of the dynamics of a magnetic island in presence of turbulence in magnetized plasmas. More precisely, the goal is to understand the multi-scales interaction between turbulence, generated by a pressure gradient and the magnetic field curvature, and a magnetic island formed thanks to a tearing mode. Thanks to the derivation of a 2-dimensional slab model taking into account both tearing and interchange instabilities, theoretical and numerical linear studies show the pressure effect on the magnetic island linear formation and show interchange modes are stabilized in presence of a strong magnetic field. Then, a numerical nonlinear study is presented in order to understand how the interchange mechanism affects the nonlinear dynamics of a magnetic island. It is shown that the pressure gradient and the magnetic field curvature affect strongly the nonlinear evolution of a magnetic island through dynamics bifurcations. The nature of these bifurcations should be characterized in function of the linear situation. Finally, the last part of this work is devoted to the study of the origin of the nonlinear poloidal rotation of the magnetic island. A model giving the different contributions to the rotation is derived. It is shown, thanks to the model and to the numerical studies, that the nonlinear rotation of the island is mainly governed by the ExB poloidal flow and/or by the nonlinear diamagnetic drift. (author)

  18. Mechanical disequilibria in two-phase flow models: approaches by relaxation and by a reduced model; Modelisation des desequilibres mecaniques dans les ecoulements diphasiques: approches par relaxation et par modele reduit

    Energy Technology Data Exchange (ETDEWEB)

    Labois, M

    2008-10-15

    This thesis deals with hyperbolic models for the simulation of compressible two-phase flows, to find alternatives to the classical bi-fluid model. We first establish a hierarchy of two-phase flow models, obtained according to equilibrium hypothesis between the physical variables of each phase. The use of Chapman-Enskog expansions enables us to link the different existing models to each other. Moreover, models that take into account small physical unbalances are obtained by means of expansion to the order one. The second part of this thesis focuses on the simulation of flows featuring velocity unbalances and pressure balances, in two different ways. First, a two-velocity two-pressure model is used, where non-instantaneous velocity and pressure relaxations are applied so that a balancing of these variables is obtained. A new one-velocity one-pressure dissipative model is then proposed, where the arising of second-order terms enables us to take into account unbalances between the phase velocities. We develop a numerical method based on a fractional step approach for this model. (author)

  19. Modelling the mechanical behaviour of heterogeneous Ta/TA6V welded joints: behaviour and failure criteria; Modelisation du comportement mecanique des liaisons soudees heterogenes Ta/TA6V: comportement et critere de rupture

    Energy Technology Data Exchange (ETDEWEB)

    Paris, Th

    2008-12-15

    As laser welding of two different materials (heterogeneous welding) leads to a joint having a characteristic size close to the millimetre, i.e. much smaller than that of a structure, and as such a junction displays completely different mechanical properties because of the metallurgical transformations induced by intense thermal loading, the aim of this research thesis is to develop a behaviour model, flexible and robust enough, to represent all together the mechanical behaviours of the Ta, the TA6V and the melted zone. This model must be able to take plasticity and visco-plasticity into account, and also to provide a failure criterion through damage mechanics and its coupling with the behaviour. The author first reports the experimental characterization of the base materials (Ta and TA6V) by using tensile tests under different strain rates and different directions, relaxation tests and fatigue shear tests. He also characterizes the melted zone by describing the influence of a thermal treatment (induced by welding) on the formation of the melted zone, and by using different tests: four point bending on notched specimens, nano-indentation test, and longitudinal tensile test. In a second part, the author develops the model within the framework of continuum thermodynamics, and explores the numerical issues. The last part deals with the validation of the model for the concerned materials (Ta and TA6V) and melted zone.

  20. Kinetic modeling of hydrogenation and hydro-denitrogenation mechanisms on sulfurated catalysts; Etude par modelisation cinetique des mecanismes d'hydrogenation et d'hydrodesazotation sur catalyseurs sulfures

    Energy Technology Data Exchange (ETDEWEB)

    Penet, H.

    1998-10-23

    Toluene hydrogenation on a NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst was studied at 350 deg. C as a function of the partial pressures of H{sub 2}, H{sub 2}S and NH{sub 3}. This experimental study shows the following facts: the effect of the H{sub 2}S partial pressure on the hydrogenation rate is complex. The order with respect to H{sub 2}S varies between -0.05 and -0.5 as the pressure varies between 0.125 and 3 bar; in the presence of NH{sub 3}, the H{sub 2}S inhibiting effect is enhanced. Kinetic modeling was performed with the Chemkin II/Surface Chemkin II software package. On the basis of the effect of contact time and H{sub 2}S on toluene hydrogenation, the adsorption by heterolytic dissociation of H{sub 2} and H{sub 2}S was selected. H{sub 2} provides hydride species (H{sup -}) attacking the aromatic ring in a first step. Proton addition during the hydrogenation of the first double bond is the limiting step. In the presence of ammonia. the kinetic modeling shows that the catalyst surface is modified and that the displacement of the H{sub 2}S adsorption equilibrium is expected. The NH{sub 3} adsorption mode could not be clearly discriminated between a simple adsorption through coordination and an adsorption through protonation. This model was applied to the hydro-denitrogenation of 2,6-diethyl-aniline at 350 deg. C on NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst and showed that the limitation step is the hydrogenation of the aromatic ring. (author)

  1. Inverse modeling for the optimization of primary sources of atmospheric pollution at a regional scale; Modelisation inverse pour l'optimisation des sources primaires de pollution atmospherique a l'echelle regionale

    Energy Technology Data Exchange (ETDEWEB)

    Pison, I.

    2005-12-15

    Atmospheric pollution at a regional scale is the result of various interacting processes: emissions, chemistry, transport, mixing and deposition of gaseous species. The forecast of air quality is then performed by models, in which the emissions are taken into account through inventories. The simulated pollutant concentrations depend highly on the emissions that are used. Now inventories that represent them have large uncertainties. Since it would be difficult today to improve their building methodologies, there remains the possibility of adding information to existing inventories. The optimization of emissions uses the information that is available in measurements to get the inventory that minimizes the difference between simulated and measured concentrations. A method for the inversion of anthropogenic emissions at a regional scale, using network measurements and based on the CHIMERE model and its adjoint, was developed and validated. A kriging technique allows us to optimize the use of the information available in the concentration space. Repeated kriging-optimization cycles increase the quality of the results. A dynamical spatial aggregation technique makes it possible to further reduce the size of the problem. The NO{sub x} emissions from the inventory elaborated by AIRPARIF for the Paris area were inverted during the summers of 1998 and 1999, the events of the ESQUIF campaign being studied in detail. The optimization reduces large differences between simulated and measured concentrations. Generally, however, the confidence level of the results decreases with the density of the measurement network. Therefore, the results with the higher confidence level correspond to the most intense emission fluxes of the Paris area. On the whole domain, the corrections to the average emitted mass and to the matching time profiles are consistent with the estimate of 15% obtained during the ESQUIF campaign. (author)

  2. Modeling of atmospheric pollution at the regional scale: application to the Esquif campaign; Modelisation a l'echelle regionale de la pollution atmospherique: application a la campagne Esquif

    Energy Technology Data Exchange (ETDEWEB)

    Sarrat, C.

    2003-06-01

    The Esquif experimental campaign (study and simulation of air quality in Ile-de-France (Paris region, France)) took place between 1998 and 2000 with the aim of better understanding the dynamical and chemical processes leading to atmospheric pollution peaks in Paris. The construction of a rich and diversified database (12 periods of intensive monitoring (PIM)) has been implemented with the aim of improving the existing chemical-transport models in general and air quality forecasting models in particular. In the framework of this study, the data collected during PIM 2 and 6 were used for the validation and analysis of situations of intensive pollution, simulated with the meso-scale numerical meteorological and chemical model Meso-NHC. The validation of both the dynamic fields (temperature and potential temperature, wind, height of the boundary layer) and the chemical fields (mainly O{sub 3}, NO{sub x}, NO{sub y}, PAN, isoprene) of the model allows to discuss some of the parameters of the model such as the initialization, the boundary forcing and the resolution. Then, a study of the dynamical processes allows to analyze the formation and reinforcement of the pollution conditions. Stress is put on the interaction of the regional scale processes with the photochemical pollution events. In this framework, the dynamical-chemical interaction processes are analyzed in detail, in particular when pollution levels are reinforced by the intrusion of residual ozone inside the convective boundary layer, dragged by the turbulence. Also, the impact of the urban hot island and of the urban wind on the redistribution of primary and secondary pollutants are considered. An analysis of the impact of hydrocarbons of biogenic origin on the ozone concentrations with respect to the temperature and to the presence of primary compounds has been performed for the PIM 2 and 6 of the Esquif campaign. (J.S.)

  3. Seismic rupture modelling, strong motion prediction and seismic hazard assessment: fundamental and applied approaches; Modelisation de la rupture sismique, prediction du mouvement fort, et evaluation de l'alea sismique: approches fondamentale et appliquee

    Energy Technology Data Exchange (ETDEWEB)

    Berge-Thierry, C

    2007-05-15

    The defence to obtain the 'Habilitation a Diriger des Recherches' is a synthesis of the research work performed since the end of my Ph D. thesis in 1997. This synthesis covers the two years as post doctoral researcher at the Bureau d'Evaluation des Risques Sismiques at the Institut de Protection (BERSSIN), and the seven consecutive years as seismologist and head of the BERSSIN team. This work and the research project are presented in the framework of the seismic risk topic, and particularly with respect to the seismic hazard assessment. Seismic risk combines seismic hazard and vulnerability. Vulnerability combines the strength of building structures and the human and economical consequences in case of structural failure. Seismic hazard is usually defined in terms of plausible seismic motion (soil acceleration or velocity) in a site for a given time period. Either for the regulatory context or the structural specificity (conventional structure or high risk construction), seismic hazard assessment needs: to identify and locate the seismic sources (zones or faults), to characterize their activity, to evaluate the seismic motion to which the structure has to resist (including the site effects). I specialized in the field of numerical strong-motion prediction using high frequency seismic sources modelling and forming part of the IRSN allowed me to rapidly working on the different tasks of seismic hazard assessment. Thanks to the expertise practice and the participation to the regulation evolution (nuclear power plants, conventional and chemical structures), I have been able to work on empirical strong-motion prediction, including site effects. Specific questions related to the interface between seismologists and structural engineers are also presented, especially the quantification of uncertainties. This is part of the research work initiated to improve the selection of the input ground motion in designing or verifying the stability of structures. (author)

  4. Quantification, modelling and design for signal history dependent effects in mixed-signal SOI/SOS circuits; Quantification, modelisation et conception prenant en compte les etats anterieurs des signaux dans les circuits mixtes SOI/SOS

    Energy Technology Data Exchange (ETDEWEB)

    Edwards, C.F.; Redman-White, W.; Bracey, M.; Tenbroek, B.M.; Lee, M.S. [Southampton Univ., Dept. of Electronics and Computer Sciences (United Kingdom); Uren, M.J.; Brunson, K.M. [DERA Farnborough, GU, Hants (United Kingdom)

    1999-07-01

    This paper deals with how the radiation hardness of mixed signal SOI/SOS CMOS circuits is taken into account at both architectural terms as well as the the transistor level cell designs. The primary issue is to deal with divergent transistor threshold shifts, and to understand the effects of large amplitude non stationary signals on analogue cell behaviour. (authors)

  5. Dolomitization of carbonated reservoirs of platforms. From geologic data to modeling. Example of the great Bahama bank; La dolomitisation des reservoirs carbonates de plate-forme. Des donnees geologiques a la modelisation. Exemple du Grand Banc des Bahamas

    Energy Technology Data Exchange (ETDEWEB)

    Caspard, E.

    2002-09-01

    Dolomitization has long been one of the most studied geological processes because of its economic interest (dolomitic rocks form a significant share of hydrocarbon reservoirs) as well as its academic interest, based on the fact that dolomite scarcely forms in current and recent marine environments whereas seawater is highly over-saturated; and that it is still not possible to synthesize it in laboratory under the same conditions. We used data collected by the University of Miami (Bahamas Drilling Project, ODP Leg 166) to understand the geological context of complete dolomitization of a Messinian 60 m thick reef unit. Classical methods of petrographic analysis of thin sections (optical microscopy, cathodoluminescence, scanning electron microscopy, in situ isotopic analyze using ionic microprobe) showed that the intensity of dolomitization is not controlled by the initial texture of the sediment, that the key parameter for dolomitization is the conservation of the initial mineralogy of magnesian bio-clasts, and that redox conditions, salinity and/or temperature of the precipitation fluid varied significantly during the process. Hydrodynamic modelling showed that during periods of high sea-level, Kohout thermal convection is a viable mechanism for driving marine fluids through the sediments. The key parameter for fluid circulations is the permeability anisotropy on the platform scale. Geochemical modelling showed that seawater is able to induce a complete dolomitization over durations of around one million years. Sensitivity tests showed that the critical parameter (as well as one of the less well-known) to describe diagenetic processes in carbonates is the water/rock reactions kinetics and in particular the precipitation kinetics of carbonate minerals. We finally propose that the dolomitization of the reef unit of the Unda well took place during the high sea-level period which extended over 1,1 My in the early Pliocene, according to the Kohout thermal convection model. (author)

  6. Multi-physic simulations of irradiation experiments in a technological irradiation reactor; Modelisation pluridisciplinaire d'experiences d'irradiation dans un reacteur d'irradiation technologique

    Energy Technology Data Exchange (ETDEWEB)

    Bonaccorsi, Th

    2007-09-15

    A Material Testing Reactor (MTR) makes it possible to irradiate material samples under intense neutron and photonic fluxes. These experiments are carried out in experimental devices localised in the reactor core or in periphery (reflector). Available physics simulation tools only treat, most of the time, one physics field in a very precise way. Multi-physic simulations of irradiation experiments therefore require a sequential use of several calculation codes and data exchanges between these codes: this corresponds to problems coupling. In order to facilitate multi-physic simulations, this thesis sets up a data model based on data-processing objects, called Technological Entities. This data model is common to all of the physics fields. It permits defining the geometry of an irradiation device in a parametric way and to associate information about materials to it. Numerical simulations are encapsulated into interfaces providing the ability to call specific functionalities with the same command (to initialize data, to launch calculations, to post-treat, to get results,... ). Thus, once encapsulated, numerical simulations can be re-used for various studies. This data model is developed in a SALOME platform component. The first application case made it possible to perform neutronic simulations (OSIRIS reactor and RJH) coupled with fuel behavior simulations. In a next step, thermal hydraulics could also be taken into account. In addition to the improvement of the calculation accuracy due to the physical phenomena coupling, the time spent in the development phase of the simulation is largely reduced and the possibilities of uncertainty treatment are under consideration. (author)

  7. Mathematical modelling of municipal solid waste incineration and thermodynamic study of the behaviour of heavy metals; Modelisation de l'incineration sur grille d'ordures menageres et approche thermodynamique du comportement des metaux lourds

    Energy Technology Data Exchange (ETDEWEB)

    Menard, Y.

    2003-07-15

    The present dissertation describes experimental and theoretical investigations undertaken for the mathematical modelling of municipal solid waste (MSW) incineration in a grate furnace and the thermodynamic study of the speciation of heavy metals (HM), originally contained into MSW, during combustion. Thermogravimetric and gaseous analysis (mass spectrometry and gas chromatography) experiments were performed on MSW samples to get pyrolysis kinetics and to quantify the gaseous species that evolve during the primary reactions of devolatilization. Other experiments were carried out in a fixed bed pilot-scale reactor: the combustion of two types of solids (wood chips and MSW) was studied, and the influence of operating conditions (flow rate, staging and temperature of the primary air) as well as fuel characteristics (moisture content, inert material fraction, lower calorific value) was investigated. A mathematical model was developed for simulating the combustion of a solid fuel, either in a fixed bed reactor or on the grate of an incineration plant. It has been validated by comparison of the calculated results and the experiments carried out on the pilot. Thanks to this model, we have been able to localize the different processes taking place in the fuel bed and to evaluate the influence of the operating conditions on the combustion efficiency. Numerical simulations of the gas flow and combustion in the post-combustion chamber and the heater of an incineration plant were performed using the CFD code FLUENT. The local thermal conditions as well as local gaseous species concentrations obtained from these simulations were eventually used to carry out thermodynamic calculations of the speciation of HM during incineration. (author)

  8. Mechanistic study and modeling of radionuclides retention by the hydrated calcium silicates (HCS) of cements; Etude mecanistique et modelisation de la retention de radionucleides par les silicates de calcium hydrates (CSH) des ciments

    Energy Technology Data Exchange (ETDEWEB)

    Pointeau, I

    2000-09-01

    This work attempts to investigate the modelling of radioisotopes (Cs{sup +}, Pb{sup 2+}, Eu{sup 3+}) immobilization in cement matrix, in the frame of the design of engineered barrier of a deep radwaste repository. The model development concept consists of three major steps: - surface chemistry modelling of the calcium silicate hydrate CSH, used to simulate hydrated cement behaviour; - solid analysis of the batch sorption experiments: identification of the uptake mechanism; - both previous steps are used, with isotherm data, in the modelling of the radioisotopes immobilization in the CSH matrix. Final results: (all modelling are available for all the range of studied Ca/Si ratios and have been validated with predictive calculations). - A thermodynamic modelling of the CSH surface chemistry has been developed. The labile calcium and proton sorption constants on silanol sites (>SiOH) have been extracted. - Cs{sup +} is sorbed on two sites. The silanol site (weak site) has a high site density (10 sites.nm{sup -2}), which accounts for the CSH unsaturation in high [CS{sup +}]. A strong site is also identified. - Pb{sup 2+} immobilization in CSH matrix is modelled with surface equilibria and solubility equilibrium. - Eu{sup 3+} fixation has been investigated with solid analysis: Site-Selective anti Time-Resolved Luminescence Spectroscopy, XPS and SEM-EDS. Eu{sup 3+} thus does not precipitate in CSH water but is sorbed on the CSH surface (high hydroxylated environment). Europium is also (minority site) inserted in the CSH framework. (author)

  9. Electromagnetic and thermal modelling of induction motors, by accounting for space harmonics; Modelisation electromagnetique et thermique des moteurs a induction, en tenant compte des harmoniques d'espace

    Energy Technology Data Exchange (ETDEWEB)

    Mezani, S.

    2004-07-15

    This work is interested in the study of the electromagnetic and thermal behaviors of the induction motor. A state of the art is initially drawn up, where we have presented and discussed the current methods dealing with electromagnetic and thermal modeling of induction motors. An electromagnetic model, that uses the 2D complex finite element method to solve the field equations, is developed. The rotor movement is accounted for by coupling the air gap field, for each space harmonic, using the double air gap method. The superposition principle permits the determination of the final solution. To deal with non linear problems, an approach that introduces equivalent reluctivities, is proposed. We have assumed that the saturation is only due to the first space harmonic. A thermal model is elaborated by using the nodal method. The machine is cut up into 11 cylindrical lumped elements, the thermal model represents the juxtaposition of these lumped elements. The electromagnetic and thermal models are, weakly, coupled together for a more precise determination of the temperature distribution inside the motor. In the validation phase of our work, we have designed a test bench that allows specific torque and temperature measurements. The comparison of the calculations and the measurements is satisfactory. (author)

  10. Study, simulation and modelling of a gamma photon detector placed on an integral-type eccentric orbit; Etude, simulation et modelisation d'un detecteur de photons gamma place sur une orbite excentrique de type integral

    Energy Technology Data Exchange (ETDEWEB)

    Diallo, N

    1999-07-01

    Gamma-ray lines are the signature of nuclear reactions and other high-energy processes that take place in the Universe. Their measurement and study provide invaluable information on many important problems in high energy astrophysics, including particle acceleration, physics of compact objects and nucleosynthesis. However the observation of astronomical gamma-ray sources has to be performed above the atmosphere because the Earth's atmosphere is opaque to gamma-rays. Unfortunately at these altitudes, spatial high energy electromagnetic radiation (X and gamma rays) detectors are exposed to intense parasite fluxes of radiation and particles induced by primary galactic cosmic rays. These fluxes as well radiation and secondary particles they generate, constitute a considerable source of background which limits their performances. Our study has been done in the framework of the INTEGRAL mission, a gamma-ray astronomy mission of the European Space Agency. INTEGRAL is devoted to the observation of celestial gamma-ray sources. It consists of two main instruments: an imager IBIS and a high resolution germanium spectrometer SPI ({delta}E/E = 1.6 10{sup -3} at 1.3 MeV). We studied the hadronic component of the SPI background. This component is due to the radioactive decay of unstable nuclides produced by the interactions of cosmic-ray protons with the materials of SPI. It consists of a continuum with gamma ray lines superimposed. To study nuclear processes, Monte Carlo simulations have been performed with the nuclear code TIERCE developed at CEA/DAM. We used the GEANT Monte Carlo code developed at CERN to simulate the germanium detectors response. Background reduction techniques as PSD (Pulse Shape Discrimination) and energetic signatures have been applied in well chosen energy ranges to reduce the background. and improve the SPI sensitivity. With the estimated SPI narrow-line sensitivity level, SPI would be able to detect many gamma ray limes emitted in the active galactic sites. (author)

  11. Numerical modeling of the thermomechanical behavior of networks of underground galleries for the storage of the radioactive waste: approach by homogenization; Modelisation numerique du comportement thermomecanique de reseaux de galeries souterraines pour le stockage des dechets radioactifs: Approche par homogeneisation

    Energy Technology Data Exchange (ETDEWEB)

    Zokimila, P

    2005-10-15

    Deep geological disposal is one of the privileged options for the storage of High Level radioactive waste. A good knowledge of the behavior and properties of the potential geological formations as well as theirs evolution in time under the effect of the stress change induced by a possible installation of storage is required. The geological formation host will be subjected to mechanical and thermal solicitations due respectively to the excavation of the disposal tunnels and the release of heat of the canisters of radioactive waste. These thermomechanical solicitations will generate a stress relief in the host layer and disposal tunnels deformations as well as the extension of the damaged zones (EDZ) could cause local and global instabilities. This work aims to develop calculation methods to optimize numerical modeling of the thermoelastic behavior of the disposal at a large scale and to evaluate thermomechanical disturbance induced by storage on the geological formation host. Accordingly, after a presentation of the state of knowledge on the thermomechanical aspects of the rocks related to deep storage, of numerical modeling 2D and 3D of the thermoelastic behavior of individual disposal tunnel and a network of tunnels were carried out by a discrete approach. However, this classical approach is penalizing to study the global behavior of disposal storage. To mitigate that, an approach of numerical modeling, based on homogenization of periodic structures, was proposed. Formulations as numerical procedures were worked out to calculate the effective thermoelastic behavior of an equivalent heterogeneous structure. The model, obtained by this method, was validated with existing methods of homogenization such as the self-consistent model, as well as the Hashin-Shtrikman bounds. The comparison between the effective thermoelastic behavior and current thermoelastic behavior of reference showed a good coherence of the results. For an application to deep geological storage, the effective thermoelastic properties of a network of circular tunnels could be given in 2D for various dimensions of the distance between galleries. (author)

  12. Microstructural characterization and model of hardening for the irradiated austenitic stainless steels of the internals of pressurized water reactors; Caracterisation microstructurale et modelisation du durcissement des aciers austenitiques irradies des structures internes des reacteurs a eau pressurisee

    Energy Technology Data Exchange (ETDEWEB)

    Pokor, C

    2003-07-01

    The core internals of Pressurized Water Reactors (PWR) are composed of SA 304 stainless steel plates and CW 316 stainless steel bolts. These internals undergo a neutron flux at a temperature between 280 deg C and 380 deg C which modifies their mechanical properties. These modifications are due to the changes in the microstructure of these materials under irradiation which depend on flux, dose and irradiation temperature. We have studied, by Transmission Electron Microscopy, the microstructure of stainless steels SA 304, CW 316 and CW 316Ti irradiated in a mixed flux reactor (OSIRIS at 330 deg C between 0,8 dpa et 3,4 dpa) and in a fast breeder reactor at 330 deg C (BOR-60) up to doses of 40 dpa. Moreover, samples have been irradiated at 375 deg C in a fast breeder reactor (EBR-II) up to doses of 10 dpa. The microstructure of the irradiated stainless steels consists in faulted Frank dislocation loops in the [111] planes of austenitic, with a Burgers vector of [111]. It is possible to find some voids in the solution annealed samples irradiated at 375 deg C. The evolution of the dislocations loops and voids has been simulated with a 'cluster dynamic' model. The fit of the model parameters has allowed us to have a quantitative description of our experimental results. This description of the microstructure after irradiation was coupled together with a hardening model by Frank loops that has permitted us to make a quantitative description of the hardening of SA 304, CW 316 and CW 316Ti stainless steels after irradiation at a certain dose, flux and temperature. The irradiation doses studied grow up to 90 dpa, dose of the end of life of PWR internals. (author)

  13. Contribution to the viscous fluid flow simulation around flexible circular arrays; Contribution a la modelisation de l'ecoulement de fluide visqueux autour de faisceaux de cylindres circulaires

    Energy Technology Data Exchange (ETDEWEB)

    Etienne, St.

    1999-09-01

    To compute the viscous flow around flexible circular cylinders arrays, a numerical model has been set up so solve the Reynolds averaged Navier-Stokes equations (RANSE). A domain decomposition method has been chosen to ensure the great flexibility of structures in the fluid domain. It consists in solving the RANS equations in a Eulerian way near the bodies and in a Lagrangian way in the wake(s). Then, we concentrate calculations in interest areas and we avoid mesh distortions. The resolution in the turbulent regime has been realized with k - {omega} and k - {epsilon} models. Compared with experiments, mix k - {omega} and k - {epsilon} models give the best results. Applications concern with the modeling of shielding and vortex-induced vibrations (VIV) phenomena in arrays of flexible cylinders. Results are validated by comparisons with experimental data. (authors)

  14. Characterization and modeling of multi-dipolar microwave plasmas: application to multi-dipolar plasma assisted sputtering; Caracterisation et modelisation des plasmas micro-onde multi-dipolaires: application a la pulverisation assistee par plasma multi-dipolaire

    Energy Technology Data Exchange (ETDEWEB)

    Tran, T.V

    2006-12-15

    The scaling up of plasma processes in the low pressure range remains a question to be solved for their rise at the industrial level. One solution is the uniform distribution of elementary plasma sources where the plasma is produced via electron cyclotron resonance (ECR) coupling. These elementary plasma sources are made up of a cylindrical permanent magnet (magnetic dipole) set at the end of a coaxial microwave line. Although of simple concept, the optimisation of these dipolar plasma sources is in fact a complex problem. It requires the knowledge, on one hand, of the configurations of static magnetic fields and microwave electric fields, and, on the other hand, of the mechanisms of plasma production in the region of high intensity magnetic field (ECR condition), and of plasma diffusion. Therefore, the experimental characterisation of the operating ranges and plasma parameters has been performed by Langmuir probes and optical emission spectroscopy on different configurations of dipolar sources. At the same time, in a first analytical approach, calculations have been made on simple magnetic field configurations, motion and trajectory of electrons in these magnetic fields, and the acceleration of electrons by ECR coupling. Then, the results have been used for the validation of the numerical modelling of the electron trajectories by using a hybrid PIC (particle-in-cell) / MC (Monte Carlo) method. The experimental study has evidenced large operating domains, between 15 and 200 W of microwave power, and from 0.5 to 15 mtorr argon pressure. The analysis of plasma parameters has shown that the region of ECR coupling is localised near the equatorial plane of the magnet and dependent on magnet geometry. These characterizations, applied to a cylindrical reactor using 48 sources, have shown that densities between 10{sup 11} and 10{sup 12} cm{sup -3} could be achieved in the central part of the volume at a few mtorr argon pressures. The modelling of electron trajectories near the magnet has also shown a better radial confinement with magnets exhibiting high length over diameter ratios. (author)

  15. Characterization and modelling of microwave multi dipole plasmas. Application to multi dipolar plasma assisted sputtering; Caracterization et modelisation des plasmas micro-onde multi-dipolaires. Application a la pulverisation assistee par plasma multi-dipolaire

    Energy Technology Data Exchange (ETDEWEB)

    Tran, Tan Vinh [Universite Joseph Fourier/CNRS-IN2P3, 53 Avenue des Martyrs, F-38026 Grenoble (France)

    2006-07-01

    The scaling up of plasma processes in the low pressure range remains a question to be solved for their rise at the industrial level. One solution is the uniform distribution of elementary plasma sources where the plasma is produced via electron cyclotron resonance (ECR) coupling. These elementary plasma sources are made up of a cylindrical permanent magnet (magnetic dipole) set at the end of a coaxial microwave line. Although of simple concept, the optimisation of these dipolar plasma sources is in fact a complex problem. It requires the knowledge, on one hand, of the configurations of static magnetic fields and microwave electric fields, and, on the other hand, of the mechanisms of plasma production in the region of high intensity magnetic field (ECR condition), and of plasma diffusion. Therefore, the experimental characterisation of the operating ranges and plasma parameters has been performed by Langmuir probes and optical emission spectroscopy on different configurations of dipolar sources. At the same time, in a first analytical approach, calculations have been made on simple magnetic field configurations, motion and trajectory of electrons in these magnetic fields, and the acceleration of electrons by ECR coupling. Then, the results have been used for the validation of the numerical modelling of the electron trajectories by using a hybrid PIC (particle-in-cell) / MC (Monte Carlo) method. The experimental study has evidenced large operating domains, between 15 and 200 W of microwave power, and from 0.5 to 15 mTorr argon pressure. The analysis of plasma parameters has shown that the region of ECR coupling is localised near the equatorial plane of the magnet and dependent on magnet geometry. These characterizations, applied to a cylindrical reactor using 48 sources, have shown that densities between 10{sup 11} and 10{sup 12} cm{sup -3} could be achieved in the central part of the volume at a few mTorr argon pressures. The modelling of electron trajectories near the magnet has also shown a better radial confinement with magnets exhibiting high length over diameter ratios. In addition, the numerical study corroborates the results of the experimental study, i.e. an ECR coupling region close to the equatorial plane of the magnet and not near the end of the coaxial microwave line. Finally, these results have been successfully applied to plasma assisted sputtering of targets allowing, in particular, their uniform erosion. (author)

  16. 3D modeling of stratigraphic units and simulation of seismic facies in the Lion gulf margin; Modelisation 3D des unites stratigraphiques et simulation des facies sismiques dans la marge du golfe du Lion

    Energy Technology Data Exchange (ETDEWEB)

    Chihi, H.

    1997-05-12

    This work aims at providing a contribution to the studies carried out on reservoir characterization by use of seismic data. The study mainly consisted in the use of geostatistical methods in order to model the geometry of stratigraphic units of the Golfe du Lion margin and to simulate the seismic facies from high resolution seismic data. We propose, for the geometric modelling, a methodology based on the estimation of the surfaces and calculation afterwards of the thicknesses, if the modelling of the depth is possible. On the other hand the method consists in estimating the thickness variable directly and in deducing the boundary surfaces afterwards. In order to simulate the distribution of seismic facies within the units of the western domain, we used the truncated Gaussian method. The used approach gave a satisfactory results, when the seismic facies present slightly dipping reflectors with respect to the reference level. Otherwise the method reaches its limits because of the problems of definition of a reference level which allows to follow the clino-forms. In spite of these difficulties, this simulation allows us to estimate the distribution of seismic facies within the units and then to deduce their probable extension. (author) 150 refs.

  17. Modeling of the climate system and of its response to a greenhouse effect increase; Modelisation du systeme climatique et de sa reponse a une augmentation de l'effet de serre

    Energy Technology Data Exchange (ETDEWEB)

    Li, L [Universite Pierre et Marie Curie, CNRS, Lab. de Meteorologie Dynamique, 75 - Paris (France)

    2005-07-01

    The anthropic disturbance of the Earth's greenhouse effect is already visible and will enhance in the coming years or decades. In front of the rapidity and importance of the global warming effect, the socio-economical management of this change will rise problems and must be studied by the scientific community. At the modeling level, finding a direct strategy for the validation of climate models is not easy: many uncertainties exist because energy transformations take place at a low level and several processes take place at the same time. The variability observed at the seasonal, inter-annual or paleo- scales allows to validate the models at the process level but not the evolution of the whole system. The management of these uncertainties is an integral part of the global warming problem. Thus, several scenarios can be proposed and their risk of occurrence must be estimated. This paper presents first the greenhouse effect, the climatic changes during geologic times, the anthropic disturbance of the greenhouse effect, the modeling of climate and the forecasting of its evolution. (J.S.)

  18. Modeling of delayed strains of concrete under biaxial loadings. Application to the reactor containment of nuclear power plants; Modelisation des deformations differees du beton sous sollicitations biaxiales. application aux enceintes de confinement de batiments reacteurs des centrales nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Benboudjema, F

    2002-12-15

    The prediction of delayed strains is of crucial importance for durability and long-term serviceability of concrete structures (bridges, containment vessels of nuclear power plants, etc.). Indeed, creep and shrinkage cause cracking, losses of pre-stress and redistribution of stresses, and also, rarely, the ruin of the structure. The objective of this work is to develop numerical tools, able to predict the long-term behavior of concrete structures. Thus, a new hydro mechanical model is developed, including the description of drying, shrinkage, creep and cracking phenomena for concrete as a non-saturated porous medium. The modeling of drying shrinkage is based on an unified approach of creep and shrinkage. Basic and drying creep models are based on relevant chemo-physical mechanisms, which occur at different scales of the cement paste. The basic creep is explicitly related to the micro-diffusion of the adsorbed water between inter-hydrates and intra-hy