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Sample records for carbonate rocks

  1. Digital carbonate rock physics

    Science.gov (United States)

    Saenger, Erik H.; Vialle, Stephanie; Lebedev, Maxim; Uribe, David; Osorno, Maria; Duda, Mandy; Steeb, Holger

    2016-08-01

    Modern estimation of rock properties combines imaging with advanced numerical simulations, an approach known as digital rock physics (DRP). In this paper we suggest a specific segmentation procedure of X-ray micro-computed tomography data with two different resolutions in the µm range for two sets of carbonate rock samples. These carbonates were already characterized in detail in a previous laboratory study which we complement with nanoindentation experiments (for local elastic properties). In a first step a non-local mean filter is applied to the raw image data. We then apply different thresholds to identify pores and solid phases. Because of a non-neglectable amount of unresolved microporosity (micritic phase) we also define intermediate threshold values for distinct phases. Based on this segmentation we determine porosity-dependent values for effective P- and S-wave velocities as well as for the intrinsic permeability. For effective velocities we confirm an observed two-phase trend reported in another study using a different carbonate data set. As an upscaling approach we use this two-phase trend as an effective medium approach to estimate the porosity-dependent elastic properties of the micritic phase for the low-resolution images. The porosity measured in the laboratory is then used to predict the effective rock properties from the observed trends for a comparison with experimental data. The two-phase trend can be regarded as an upper bound for elastic properties; the use of the two-phase trend for low-resolution images led to a good estimate for a lower bound of effective elastic properties. Anisotropy is observed for some of the considered subvolumes, but seems to be insignificant for the analysed rocks at the DRP scale. Because of the complexity of carbonates we suggest using DRP as a complementary tool for rock characterization in addition to classical experimental methods.

  2. Cataclastic rheology of carbonate rocks

    Institute of Scientific and Technical Information of China (English)

    LU Xiancai; SUN Yan; SHU Liangshu; GU Lianxing; GUO Jichun; ZHU Wenbin

    2005-01-01

    Based on the knowledge of the shallow-level mylonitization of detrital rocks and intrusive rocks, the poorly-known cataclastic rheology of carbonate rocks is discussed comprehensively in this paper. The cases taken from eastern China are analyzed in various aspects including ductile-brittle fault zone, rock texture and structure, clastomylonite layer, leucocratic stress minerals, and frictional dynamometamorphism. It is proposed that the cataclastic flow structure represented by clastomylonite texture is a cooling pattern of flow assemblage characterized by cooling metamorphism, cooling mylonite and cooling stress minerals. Such a pattern is formed generally in mildly reducing physicochemical environments, and is commonly related to regional tectonism and mesothermal and epithermal mineralization.

  3. The thermal evolution indicator of carbonate rocks

    Institute of Scientific and Technical Information of China (English)

    王兆云; 范璞; 程克明

    1995-01-01

    It has been studied by the solid state 13C NMR analysis that the chemical composition and the structure feature of kerogen of carbonate rocks are characteristic of different types and evolution degree. The purpose is to show the evolution degree using the structure parameters of kerogen of carbonate rocks. The detailed analysis of the carbon aromaticity (fa), the hydrogen aromaticity (Ha) and the average aromatic cluster size (Xb) indicates that Xb is the most effective indicator of evolution degree, and it is not influenced by the type and evolution degree of kerogen. The correlation between the average aromatic cluster size and vitrinite reflectance value of kerogen has also been established.

  4. Preliminary Study on weathering and pedogenesis of carbonate rock

    Institute of Scientific and Technical Information of China (English)

    王世杰; 季宏兵; 欧阳自远; 周德全; 郑乐平; 黎廷宇

    1999-01-01

    South China is the largest continuous distribution area of carbonate rock in the world. The origin of the soils over the bedrock carbonate rock has long been a controversial topic. Here further exploration is made by taking five soil profiles as examples, which are developed over the bedrock dolomitite and limestone and morphologically located in upland in karst terrain in the central, west and north Guizhou as well as west Hunan, and proved to be the weathering profiles of carbonate rock by the research results of acid-dissolved extraction experiment of bedrock, mineralogy and trace element geochemistry. Field, mineralogical and trace element geochemical characteristics of weathering and pedogenesis for carbonate rock are discussed in detail. It is pointed out that weathering and pedogenesis of carbonate rock are important pedogenetic mechanisms for soil resources in karst area, providing a basis for further researches on the origin of soils widely overlying bedrock carbonate rocks in South China.

  5. New York and New England carbonate-rock aquifers

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the New York and New England carbonate-rock aquifers in the states of New York, Vermont, Maine, Massachusetts, Connecticut,...

  6. Heterogeneity of Parent Rocks and Its Constraints on Geochemical Criteria in Weathering Crusts of Carbonate Rocks

    Institute of Scientific and Technical Information of China (English)

    WANG Shijie; FENG Zhigang

    2004-01-01

    Owing to the low contents of their acid-insoluble components, carbonate rocks tend to decrease sharply in volume in association with the formation of weathering crust. The formation of a 1 m-thick weathering crust would usually consume more than ten meters to several tens of meters of thickness of parent rocks. The knowledge of how to identify the homogeneity of parent rocks is essential to understand the formation mechanism of weathering crust in karst regions,especially that of thick-layered red weathering crust. In this work the grain-size analyses have demonstrated that the three profiles studied are the residual weathering crust of carbonate rocks and further showed that there objectively exists the heterogeneity of parent rocks in the three studied weathering crusts. The heterogeneity of parent rocks can also be reflected in geochemical parameters of major elements, just as the characteristics of frequency plot of grain-size distribution.Conservative trace element ratios Zr/Hf and Nb/Ta are proven to be unsuitable for tracing the heterogeneity of parent rocks of weathering crust, but its geochemical mechanism is unclear. The authors strongly suggest in this paper that the identification of the homogeneity of parent rocks of weathering crust in karst regions is of prime necessity.

  7. Digital Rock Simulation of Flow in Carbonate Samples

    Science.gov (United States)

    Klemin, D.; Andersen, M.

    2014-12-01

    Reservoir engineering has becomes more complex to deal with current challenges, so core analysts must understand and model pore geometries and fluid behaviors at pores scales more rapidly and realistically. We introduce an industry-unique direct hydrodynamic pore flow simulator that operates on pore geometries from digital rock models obtained using microCT or 3D scanning electron microscope (SEM) images. The PVT and rheological models used in the simulator represent real reservoir fluids. Fluid-solid interactions are introduced using distributed micro-scale wetting properties. The simulator uses density functional approach applied for hydrodynamics of complex systems. This talk covers selected applications of the simulator. We performed microCT scanning of six different carbonate rock samples from homogeneous limestones to vuggy carbonates. From these, we constructed digital rock models representing pore geometries for the simulator. We simulated nonreactive tracer flow in all six digital models using a digital fluid description that included a passive tracer solution. During the simulation, we evaluated the composition of the effluent. Results of tracer flow simulations corresponded well with experimental data of nonreactive tracer floods for the same carbonate rock types. This simulation data of the non-reactive tracer flow can be used to calculate the volume of the rock accessible by the fluid, which can be further used to predict response of a porous medium to a reactive fluid. The described digital core analysis workflow provides a basis for a wide variety of activities, including input to design acidizing jobs and evaluating treatment efficiency and EOR economics. Digital rock multiphase flow simulations of a scanned carbonate rock evaluated the effect of wettability on flow properties. Various wetting properties were tested: slightly oil wet, slightly water wet, and water wet. Steady-state relative permeability simulations yielded curves for all three

  8. Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks

    Science.gov (United States)

    García del Real, Pablo; Maher, Kate; Kluge, Tobias; Bird, Dennis K.; Brown, Gordon E.; John, Cédric M.

    2016-11-01

    Magnesium carbonate minerals produced by reaction of H2O-CO2 with ultramafic rocks occur in a wide range of paragenetic and tectonic settings and can thus provide insights into a variety of geologic processes, including (1) deposition of ore-grade, massive-vein cryptocrystalline magnesite; (2) formation of hydrous magnesium carbonates in weathering environments; and (3) metamorphic carbonate alteration of ultramafic rocks. However, the application of traditional geochemical and isotopic methods to infer temperatures of mineralization, the nature of mineralizing fluids, and the mechanisms controlling the transformation of dissolved CO2 into magnesium carbonates in these settings is difficult because the fluids are usually not preserved. Clumped-isotope compositions of magnesium carbonates provide a means to determine primary mineralization or (re)equilibration temperature, which permits the reconstruction of geologic processes that govern magnesium carbonate formation. We first provide an evaluation of the acid fractionation correction for magnesium carbonates using synthetic magnesite and hydromagnesite, along with natural metamorphic magnesite and low-temperature hydromagnesite precipitated within a mine adit. We show that the acid fractionation correction for magnesium carbonates is virtually indistinguishable from other carbonate acid fractionation corrections given current mass spectrometer resolution and error. In addition, we employ carbonate clumped-isotope thermometry on natural magnesium carbonates from various geologic environments and tectonic settings. Cryptocrystalline magnesite vein deposits from California (Red Mountain magnesite mine), Austria (Kraubath locality), Turkey (Tutluca mine, Eskişehir district) and Iran (Derakht-Senjed deposit) exhibit broadly uniform Δ47 compositions that yield apparent clumped-isotope temperatures that average 23.7 ± 5.0 °C. Based on oxygen isotope thermometry, these clumped-isotope temperatures suggest

  9. Migration and enrichment of trace elements of Lower Palaeozoic carbonate rock strata in Beijing

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Analyses of trace elements of the Lower Palaeozoic carbonate rock strata in Beijing show that the contents of As, Hg, F increase from primary carbonate rocks to weathered carbonate rocks and from primary carbonate rocks to the soil coexisting with carbonate rocks, but the distribution regularity of S is not obvious. In the whole weathered stages, the sorption of As is mainly affected by Fe2O3. In soil Fe2O3 is also the main affecting factor of Hg enrichment. The main existing forms of Hg in primary carbonate rocks should simply be physical adsorption, coprecipitation and false isomorphous form between surface of carbonate rock and Hg. In soil the enrichment of F has little relationship with sul-fides and Fe2O3. In primary carbonate rocks, F is mainly absorbed by sulfides and clay minerals, etc. Weathered samples have closer genetic relationships with primary carbonate rocks. This also implies that weathered carbonate rocks have the close existing forms to that of primary carbonate rocks. In primary carbonate rocks FeS2 and FeS are the main forms of S, and sulfides have fixation effect on some heavy metals, whereas in weathered carbonate rocks and soil the fixation effect is weakened.

  10. Carbonate rocks of Mt. Peca, Slovenia

    Directory of Open Access Journals (Sweden)

    Bernarda Bole

    2002-06-01

    Full Text Available The carbonate massif of Mt. Peca consists of Ladinian-Carnian Wetterstein limestone and dolomite of backreef and reef development. The backreef limestone is bedded and with intrabiomicrite, intrabiopelmicrite and loferite textures. It was deposited in shallow and quiet sedimentation environment with short periodic emergences. The reef facies is characterized by corals, algae, spongians and other reefbuilding organisms. Te larger part of the Peca limestone is slightly dolomitized, and its reef part is in addition strongly recrystallized.With respect to fossil assemblage the reef limestone is attributed to Carnian, mainly to Cordevol.

  11. Comparative study on CO2 sources in soil developed on carbonate rock and non-carbonate rock in Central Guizhou

    Institute of Scientific and Technical Information of China (English)

    黎廷宇; 王世杰; 郑乐平

    2002-01-01

    In this paper, by using concentration and carbon stable isotope the CO2 sources of soil profiles developed on limestone, dolostone and claystone basements in Central Guizhou, China are comparatively studied. The results show that CO2 concentration of soil profiles developed on different basements is different, having the following sequence: limestone>dolostone>claystone. Below the soil depth of 20 cm from the surface the ? 13C value of CO2 in soil profile developed on limestone ranges from -12.811‰ - -13.492‰(PDB), that in soil profile developed on dolostone varys from -13.212‰ - -14.271‰(PDB) and that in soil profile developed on claystone is about -20.234‰ - -21.485‰(PDB). Taking the carbon isotope of soil organic matter and carbonate rock as two isotopic endmembers, the proportion of soil CO2 generated by dissolution of carbonate rock is calculated, about 21%-25% for soil profile developed on limestone basement, 19%-21% for soil profile developed on dolostone basement. There is almost no influx of CO2 generated by the dissolution of carbonate rock in soil profile developed on claystone basement.

  12. Impact breccias in carbonate rocks, Sierra Madera, Texas.

    Science.gov (United States)

    Wilshire, H. G.; Howard, K. A.; Offield, T. W.

    1971-01-01

    Two main types of deformational breccia occur in the Sierra Madera cryptoexplosion structure: monolithologic breccias composed of shattered rock of a single lithology and mixed breccias composed of rocks of several lithologies. Monolithologic breccias generally show no mineralogic signs of shock deformation, but a few samples are shatter-coned in a manner suggesting simultaneous formation of breccias and shatter cones. Mixed breccias, forming irregular, cross-cutting bodies, consistently contain moderately to highly shocked material, with mineralogic evidence of shock pressures of 50 kb to more than 200 kb, which, with evidence from the structural geometry of Sierra Madera and orientation of shatter cones, indicate an impact origin of the breccias. The mode of occurrence of the breccias, petrographic characteristics, and association with shock features are shared by breccias in many other cryptoexplosion structures in both carbonate and crystalline rock terranes, suggesting that such breccias have a common origin.

  13. Correlation between permeability and groundwater flow patterns in carbonate rocks

    Science.gov (United States)

    Park, Y.; Lee, J.; Park, Y.; Keehm, Y.

    2011-12-01

    Groundwater flow in carbonate rocks is controlled by many factors such as degree of fracture and pore development, weathering and diagenesis. Among these factors, fracture is main factor and can form main flow path. Also, flow patterns in carbonate area are decided by these factors. This study was performed to understand factors controlling permeability and flow patterns in carbonate area and to evaluate correlation between permeability and flow patterns. Data used in this study were collected from many literatures and these data were analyzed and evaluated using graphic and statistical analysis. In many carbonate areas, branching conduit patterns were dominant. Of these areas, permeability was relatively high in areas where moving distance of flow was short and hydraulic gradient was steep. This work was supported by the Energy Resources R&D program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government Ministry of Knowledge Economy (No. 2009201030001A).

  14. Rock fracture grouting with microbially induced carbonate precipitation

    Science.gov (United States)

    Minto, James M.; MacLachlan, Erica; El Mountassir, Gráinne; Lunn, Rebecca J.

    2016-11-01

    Microbially induced carbonate precipitation has been proposed for soil stabilization, soil strengthening, and permeability reduction as an alternative to traditional cement and chemical grouts. In this paper, we evaluate the grouting of fine aperture rock fractures with calcium carbonate, precipitated through urea hydrolysis, by the bacteria Sporosarcina pasteurii. Calcium carbonate was precipitated within a small-scale and a near field-scale (3.1 m2) artificial fracture consisting of a rough rock lower surfaces and clear polycarbonate upper surfaces. The spatial distribution of the calcium carbonate precipitation was imaged using time-lapse photography and the influence on flow pathways revealed from tracer transport imaging. In the large-scale experiment, hydraulic aperture was reduced from 276 to 22 μm, corresponding to a transmissivity reduction of 1.71 × 10-5 to 8.75 × 10-9 m2/s, over a period of 12 days under constantly flowing conditions. With a modified injection strategy a similar three orders of magnitude reduction in transmissivity was achieved over a period of 3 days. Calcium carbonate precipitated over the entire artificial fracture with strong adhesion to both upper and lower surfaces and precipitation was controlled to prevent clogging of the injection well by manipulating the injection fluid velocity. These experiments demonstrate that microbially induced carbonate precipitation can successfully be used to grout a fracture under constantly flowing conditions and may be a viable alternative to cement based grouts when a high level of hydraulic sealing is required and chemical grouts when a more durable grout is required.

  15. Comparative study on CO2 sources in soil developed on carbonate rock and non-carbonate rock in Central Guizhou

    Institute of Scientific and Technical Information of China (English)

    黎廷宇; 王世杰; 郑乐平

    2002-01-01

    In this paper, by using concentration and carbon stable isotope the.CO2 sources of soil profiles developed on limestone, dolostone and claystone basements in Central Guizhou, China are comparatively studied. The results show that CO2 concentration of soil profiles developed on different basements is different, having the following sequence: limestone>dolostone>claystone. Below the soil depth of 20 cm from the surface the δ13C value of CO2 in soil profile developed on limestone ranges from -12.811‰ - -13.492‰(PDB), that in soil profile developed on dolostone varys from -13.212‰--14.271‰(PDB) and that in soil profile developed on claystone is about -20.234‰- -21.485‰(PDB). Taking the carbon isotope of soil organic matter and carbonate rock as two isotopic endmembers, the proportion of soil C02 generated by dissolution of carbonate rock is calculated, about 21%-25% for soil profile developed on limestone basement, 19%-21% for soil profile developed on dolostone basement. There is almost no influx of

  16. Carbon Dioxide - rock interaction: from molecular observations to theorised interactions in fluid-rock systems

    Science.gov (United States)

    Calcara, Massimo; Borgia, Andrea

    2013-04-01

    Current global warming theories have produced some benefits: among them, detailed studies on CO2 and its properties, possible applications and perspectives. Starting from its use as a "green solvent" (for instance in decaffeination process), to enhance system in oil recovery, to capture and storage enough amount of CO2 in geological horizon. So, a great debate is centred around this molecule. One More useful research in natural horizon studies is its theorised use in Enhanced Geothermal Systems with CO2 as the only working fluid. In any case, the CO2 characteristics should be deeply understood, before injecting a molecule prone to change easily its aggregation state at relatively shallow depth. CO2 Rock interaction becomes therefore a focal point in approaching research sectors linked in some manner to natural or induced presence of carbon dioxide in geological horizons. Possible chemical interactions between fluids and solids have always been a central topic in defining evolution of the system as a whole in terms of dissolutions, reactions, secondary mineral formation and, in case of whichever plant, scaling. Questions arise in case of presence of CO2 with host rocks. Chemical and molecular properties are strategic. CO2 Rock interactions are based on eventual solubility capability of pure liquid and supercritical CO2 seeking and eventually quantifying its polar and/or ionic solvent capabilities. Single molecule at STP condition is linear, with central carbon atom and oxygen atoms at opposite site on a straight line with a planar angle. It has a quadrupolar moment due to the electronegativity difference between carbon and oxygen. As soon as CO2 forms bond with water, it deforms even at atmospheric pressure, assuming an induced dipole moment with a value around 0.02 Debye. Hydrated CO2 forms a hydrophilic bond; it deforms with an angle of 178 degrees. Pure CO2 forms self aggregates. In the simplest case a dimer, with two molecules of CO2 exerting mutual attraction

  17. Characteristics of hydrocarbon generation and expulsion in matrix and stylolite of carbonate rocks

    Institute of Scientific and Technical Information of China (English)

    高岗; 郝石生; 王晖

    1999-01-01

    Characteristics of organic matter content, hydrocarbon generation and expulsion of carbonate rocks are discussed by analysis of organic carbon and pyrolysis. There is a strong inhomogeneity in distribution of organic matter in carbonate rocks. The organic matter abundance is higher in stylolites, carbonate varves or marls, while it is the lowest in matrixes (purer carbonate rocks around stylolites). Because of stable thickness and broad area, marls and carbonate varves may become good source rocks. At the same depth, stylolites, carbonate varves and matrixes generate and expel hydrocarbons almost at the same time. Expulsion efficiency of carbonate varve is the highest; that of matrixes is the lowest and that of stylolites is between marl’s or carbonate varve’s and matrix’ s.

  18. Molecular and carbon isotopic compositions of gas inclusions of deep carbonate rocks in the Tarim Basin

    Institute of Scientific and Technical Information of China (English)

    ZHOU Shixin; WANG Xianbin; MENG Zifang; LI Yuan; Paul Farrimond; LI Liwu; DUAN Yi

    2004-01-01

    Gaseous components of gas inclusions in deep carbonate rocks (>5700 m) from the Tacan 1 well were analyzed by online mass spectrometry by means of either the stepwise heating technique or vacuum electromagnetism crushing. The carbon isotopic compositions of gases released by vacuum electromagnetism crushing were also measured. Although the molecular compositions of gas inclusions show differences between the two methods, the overall characteristics are that gas inclusions mainly contain CO2, whilst hydrocarbon gases, such as CH4, C2H6 and C3H8, are less abundant. The content of CO is higher in the stepwise heating experiment than that in the method of vacuum electromagnetism crushing, and there are only minor amounts of N2, H2 and O2 in gas inclusions. Methane δ13C values of gas inclusions in Lower Ordovician and Upper Cambrian rocks (from 5713.7 to 6422 m; -52‰-63‰) are similar to those of bacterial methane, but their chemical compositions do not exhibit the dry character in comparison with biogenic gases. These characteristics of deep gas inclusions may be related to the migration fractionation. Some deep natural gases with light carbon isotopic characteristics in the Tazhong Uplift may have a similar origin. The δ13C1 values of gas inclusions in Lower Cambrian rocks (7117-7124 m) are heavier (-39‰), consistent with highly mature natural gases. Carbon isotopic compositions of CO2 in the gas inclusions of deep carbonate rocks are similar (from -4‰ to -13‰) to those of deep natural gases, indicating predominantly an inorganic origin.

  19. Stress path dependent hydromechanical behaviour of heterogeneous carbonate rock

    Directory of Open Access Journals (Sweden)

    Dimanov A.

    2010-06-01

    Full Text Available The influence of stress paths, representative of reservoir conditions, on the hydromechanical behavior of a moderately heterogeneous carbonate has been investigated. Multiscale structural heterogeneities, common for instance in carbonate rocks, can strongly alter the mechanical response and significantly influence the evolution of flow properties with stress. Using a triaxial cell, the permeability evolutions during compression and the effects of brittle (fracture and plastic (pore collapse deformations at yield, were measured. A strong scattering was observed on the mechanical response both in term of compressibility and failure threshold. Using the porosity scaling predicted by an adapted effective medium theory (based on crack growth under Hertzian contact, we have rescaled the critical pressures by the normalized porosity deviation. This procedure reduces efficiently the scattering, revealing in the framework of proportional stress path loading, a linear relation between the critical pressures and the stress path parameter through all the deformation regimes. It leads to a new formulation for the critical state envelope in the 'mean stress, deviatoric stress' diagram. The attractive feature of this new yield envelope formulation relies on the fact that only the two most common different mechanical tests 'Uniaxial Compression' and 'Hydrostatic Compression', are needed to define entirely the yield envelope. Volumic strains and normalized permeabilities are finally mapped in the stresses diagram and correlated.

  20. Comprehensive geochemical identification of highly evolved marine carbonate rocks as hydrocarbon-source rocks as exemplified by the Ordos Basin

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    This study reversed the developing environments of hydrocarbon-source rocks in the Ordos Basin and evaluated carbonate rocks as hydrocarbon-source rocks and their distributions on account of the fact that China's marine carbonate rocks as hydrocarbon-source rocks are characterized by intensive thermal evolution and relatively low abundance of organic matter, by taking the Lower Paleozoic of the Ordos Basin for example and in light of the calculated enrichment coefficients of trace elements, the REE distribution patterns, the mathematical statistics analysis of elements and carbon isotopes and their three-dimensional diagrammatization in combination with the necessary organic parameters. As for the Ordos Basin, TOC=0.2% is an important boundary value. Studies have shown that in the strata where TOC is greater than 0.2%, Ba is highly enriched with positive δ13Ccarb shifts and δ13Corg less than -28‰, reflecting a thigh paleo-productivity, high burial amounts of organic matter, relatively good hydrocarbon-generating potentiality and intensive REE fractionation. All these indicated that the settlement rates are low and the geological conditions are good for the preservation of organic matter, hence favoring the development of hydrocarbon-source rocks. The Klimory and Wulalik formations show certain regularities in those aspects and, therefore, they can be regarded as the potential effective hydrocarbon-source rocks. In the strata where total TOC is less than 0.2%, the contents of Ba are low, δ13Ccarb values are mostly negative, and δ13Corg values range from -24‰--28‰, demonstrating low burial amounts of organic matter, poor potentialities of hydrocarbon generation, weak REE fractionation and rapid settlement rates. These facts showed that most of the hydrocarbon-source rocks were formed in shallow-water, high-energy oxidizing environments, thus unfavoring the development of hydrocarbon-source rocks. It is feasible to make use of the geochemical method to

  1. Study of the Factors Affecting the Abundance of Organic Matter in Jurassic Carbonate Rocks in Qiangtang Basin, Tibet

    Institute of Scientific and Technical Information of China (English)

    文志刚; 胡明毅; 龚文平; 肖传桃

    2004-01-01

    Field and laboratory analyses of carbonate rock samples from the Qiangtang Basin,Tibet, indicate that carbonate source rocks are mainly developed in the Middle Jurassic Xiali Formation and Upper Jurassic Suowa Formation. Comprehensive studies showed that the Suowa Formation carbonate source rocks have a favorable hydrocarbon-generating potential. The abundance of organic matter in the carbonate rocks is controlled mainly by sedimentary environment and inorganic compounds in the rocks, which is higher in the restricted platform facies than in the open platform facies. Organic carbon contents decrease with increasing CaO contents in the source rocks.

  2. The hydrocarbon generation mechanism and the threestage type model of hydrocarbon generation for carbonate source rocks

    Institute of Scientific and Technical Information of China (English)

    王兆云; 程克明

    1997-01-01

    The diagenetic mechanism and process of carbonate rocks, which is different to that of clastic rocks, decides the existence of different existing state organic matters in carbonate rocks. This has been verified by both the microscopic observation of organic petrology and the analysis of organic geochemistry of many samples. Based on the hydrous pyrolysis simulation experiment of the low-mature carbonate rocks, the contrasting study on the yield and their geochemistry characteristics of different existing state soluble organic matters of a series of various maturity samples shows that the different existing state organic matters make different contributions to hydrocarbon generation during every evolution state. So that, the hydrocarbon generation process of carbonate rocks can be summarized as the following three stages; the first is the direct degradation of biogenic bitumen macromolecules during the immature stage, the second is the thermal degradation of a large amount of kerogen at the mature stage,

  3. High=porosity Cenozoic carbonate rocks of South Florida: progressive loss of porosity with depth

    Science.gov (United States)

    Halley, Robert B.; Schmoker, James W.

    1983-01-01

    Porosity measurements by borehole gravity meter in subsurface Cenozoic carbonates of South Florida reveal an extremely porous mass of limestone and dolomite which is transitional in total pore volume between typical porosity values for modern carbonate sediments and ancient carbonate rocks. A persistent decrease of porosity with depth, similar to that of chalks of the Gulf Coast, occurs in these rocks. Carbonate strata with less than 20% porosity are absent from the rocks studied here. Aquifers and aquicludes cannot be distinguished on the basis of porosity. Aquifers are not exceptionally porous when compared to other Tertiary carbonate rocks in South Florida. Permeability in these strata is governed more by the spacial distribution of pore space and matrix than by total volume of porosity present. Dolomite is as porous as, or slightly less porous than, limestones in these rocks. This observation places limits on any model proposed for dolomitization and suggests that dolomitization does not take place by a simple ion-for-ion replacement of magnesium for calcium. Dolomitization may be selective for less porous limestone, or it may involve the incorporation of significant amounts of carbonate as well as magnesium into the rock. The great volume of pore space in these rocks serves to highlight the inefficiency of early diagenesis in reducing carbonate porosity and to emphasize the importance of later porosity reduction which occurs during the burial or late near-surface history of limestones and dolomites.

  4. Second Hydrocarbon—Generation from Organic Matter Trapped in Fluid Inclusions in Carbonate Rocks

    Institute of Scientific and Technical Information of China (English)

    施继锡; 余孝颖

    1999-01-01

    The mechanism and significance of second hydrocarbon-generation from organic matter trapped in fluid inclusions in carbonate rocks are discussed.The types of organic matter and the relationship between them are also reviewed.The organic matter trapped in inclusions and crystals,which account for more than 20%of the total organic matter in carbonate rocks,may be of great significance in the generation of hydrocarbons.High-temperature oil resulting from second hydrocarbon-generation should be an important target,in addition to natural gas,in oilgas prospecting in regions of high-maturity carbonate rocks.

  5. Study on the threshold value of organic enrichment of carbonate as gas source rocks

    Institute of Scientific and Technical Information of China (English)

    XUE Haitao; LU Shuangfang; ZHONG Ningning; WANG Bo

    2004-01-01

    In this paper, calculations have been performed about gas quantity of generation, adsorption, dissolving in oil, dissolving in water, diffusion of unit area carbonate rocks at different geologic conditions in the Tarim basin. According to the material balance principle, the corresponding organic carbon content when gas started expelling from source rocks with separate phases has been worked out. We regard it as the theoretical threshold value (TOCmin) of gas source rocks under the same geologic condition. Based on the simulating calculation, a fact has been discovered that TOCmin decreases with the increasing source rocks thickness, decreases at the beginning and then increases with the increasing maturity and decreases with the better type of organic matter. TOCmin evaluation table of carbonate gas source rocks in the Tarim basin has been established. Investigations indicate that the TOCmin of carbonate gas source rocks varies greatly with the differences of geologic conditions, and gas source rocks cannot be evaluated with a unified TOC threshold value. And we also establish a preliminary evaluation table of TOC industrial threshold value, TOCgy, of carbonate gas source rocks in the Tarim basin.

  6. Carbon and Oxygen Isotope Stratigraphy of the Oxfordian Carbonate Rocks in Amu Darya Basin

    Institute of Scientific and Technical Information of China (English)

    Rongcai Zheng; Yanghui Pan; Can Zhao; Lei Wu; Renjin Chen; Rui Yang

    2013-01-01

    Based on the detailed research on petrologic and geochemical characteristics of deposition and diagenesis of Oxfordian carbonate rocks in Amu Darya Basin,Turkmenistan,carbon and oxygen isotopes were analyzed.The results show that the paleoenvironmental evolution reflected by the samples with well-preserved original carbon isotopes coincides with the carbon-isotope stratigraphic carve and is almost consistent with the global sea-level curve,the Mid-Oxfordian wide transgression,and the positive carbon-isotope excursion event.The Mid-Oxfordian continuing transgression not only laid the foundation for the development of the Oxfordian reef and shoal reservoirs in Amu Darya Basin but also provided an example for the Oxfordian global transgression and the resulting development of reefs and banks and high-speed organic carbon burial events.The response of oxygen isotopes in diagenetic environment showed that micrite limestones and granular limestones underwent weak diagenetic alteration,and the samples largely retained the original seawater features.Dolomitization and the precipitation of hydrothermal calcites tilling solution vugs and fractures before hydrocarbon accumulation occurred in a closed diagenetic environment where the main controlling factor is the temperature,and the diagenetic fluids were from the deep hot brine.The chalkification of the limestones after hydrocarbon accumulation occurred in the oiltield water systems.

  7. In Situ Evaluation of Water-Rock Reactions during Carbon Dioxide Injection in Basaltic and Metasedimentary Rocks

    Science.gov (United States)

    Matter, J. M.; Assayag, N.; Goldberg, D.; Takahashi, T.

    2006-12-01

    Large differences between laboratory and field derived mineral reaction rates underscore the importance of evaluating mineral-fluid reactions under in situ conditions in a natural environment. This study investigates the extent of in situ water-rock reactions in basaltic and metasedimentary rocks (rich in Ca, Mg silicates) after the injection of CO2 enriched water, with the objective of providing information pertinent to permanent storage of anthropogenic CO2 in geologic reservoirs. CO2 injections were conducted using a single-well push-pull testing strategy. CO2 saturated water (pH 3.5) was injected into a hydraulically isolated and permeable aquifer in a 300-m experimental borehole. Water samples were retrieved after the CO2 injection. Mass transfer terms for Ca, Mg, Na, and Si were determined by using the measured ion concentrations. Using the mass balance, the weeks-long incubation time of the injected solution, and geometric estimates of the reactive surface area of the host rocks, in situ bulk rock dissolution rates of aquifer material were estimated. In addition, δ13C data coupled with total CO2 concentration were used as a tracer to quantitatively evaluate processes such as carbonate dissolution and precipitation, oxidation of organic matter and biological activity within the aquifer. Results show that the injected CO2 was neutralized within several days by two processes; mixing with aquifer water, and rock-water reactions. Calculated bulk rock dissolution rates decrease with increasing pH. The pH dependence of the dissolution rate for Ca is twice as large as for Mg, strongly favoring Ca release and possibly suggesting an additional source of Ca besides silicate minerals. Analyses of δ13C on water and rock samples confirm dissolution of calcium carbonates within the aquifer.

  8. Multiscale imaging of carbonate rocks and representative sampling for digital rock physics

    Science.gov (United States)

    Yoon, H.; Dewers, T. A.

    2015-12-01

    Geomaterials containing nano-pores (e.g., shales and carbonate rocks) have become increasingly important for emerging problems such as unconventional gas and oil resources, enhanced oil recovery, and geologic storage of CO2. Accurate prediction of coupled geophysical and chemical processes at the pore scale requires realistic representation of pore structure and topology. This is especially true for chalk materials, where pore networks are small and complex, and require characterization at sub-micron scale. In this work, we apply laser scanning confocal microscopy with various filters to characterize pore structures and microlithofacies at a thin-section scale (micron resolution) and dual focused ion beam-scanning electron microscopy (FIB-SEM) for 3D imaging of nanometer-to-micron scale microcracks and pore distributions. With imaging techniques advanced for nano-pore characterization, it is critical to define representative sampling of FIB-SEM images and apply it to the thin-section or larger scale. In this work, several texture characterization techniques are applied for segmentation clusters represented by a couple of 3-D FIB-SEM image stacks per each cluster. Pore structure evolution is characterized based on geometric and topological properties from a set of FIB-SEM images and lattice-Boltzmann method (LBM) is used to obtain permeability at several different scales. Upscaling of permeability to the Darcy scale (e.g., the thin-section scale) with image dataset will be discussed with emphasis on understanding microfracture-matrix interaction, representative volume for FIB-SEM sampling, and multiphase flow and reactive transport. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  9. Metasomatic Mechanism of Weathering-Pedogenesis of Carbonate Rocks: I. Mineralogical and Micro-Textural Evidence

    Institute of Scientific and Technical Information of China (English)

    朱立军; 李景阳

    2002-01-01

    On the basis of mineralogical, geochemical and micro-textural studies of the typical sections of the red weathering crust of carbonate rocks in the subtropical karst areas of Guizhou Province and Guangxi Autonomous Region, we have found, either on a microscopic or on a macroscopical scale and in different positions of the sections, the most direct and most important mineralogical and micro-textural evidence for the development of metasomatism in the process of weathering-pedogenesis of numerous carbonate rocks. This paper also has expounded for the first time and systematically the mechanism of metasomatism involved in the process of weathering pedogenesis of carbonate rocks and proposed the sequence of mineral metasomatic evolution in the process of weathering-pedogenesis of carbonate rocks.

  10. Sedimentary evolution models of Lower Triassic deep-water carbonate rocks of west Qinling Mts.

    Institute of Scientific and Technical Information of China (English)

    晋慧娟; 李育慈

    1995-01-01

    Based on the study of Lower Triassic deep-water carbonate rock sequence of west Qinling Mts . deep-water carbonate rock sequence is divided into lower fine-grain euxinic deposits of a carbonate gentle slope type and upper bathyal and abyssal sediments of carbonate steep slope type. The upper member is emphatically analysed and synthesized into five fades associations. They comprise four fining- and thinning-upward megacycles, each of them representing a sedimentary column which accumulated after a tensional fault subsidence event, which recorded a whole rifting process of west Qinling ocean trough during Lower Triassic.

  11. The nature of carbon material in the black shale rock mass of Kazakhstan

    Energy Technology Data Exchange (ETDEWEB)

    Marchenko, L.G.

    1981-01-01

    Carbon material is closely tied to ores of various origin lying in the carbon (black shale) rock masses of Kazakhastan. The nature of the carbon material in several gold fields is closely examined. Shungite, its paragenesis with ore materials and its role in the carbon and ore material processes, is described. The accumulation of shungite in zones determined to consist of ores, is looked at in terms of prospecting criteria.

  12. Integrated Experimental and Modeling Studies of Mineral Carbonation as a Mechanism for Permanent Carbon Sequestration in Mafic/Ultramafic Rocks

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zhengrong [Yale Univ., New Haven, CT (United States); Qiu, Lin [Yale Univ., New Haven, CT (United States); Zhang, Shuang [Yale Univ., New Haven, CT (United States); Bolton, Edward [Yale Univ., New Haven, CT (United States); Bercovici, David [Yale Univ., New Haven, CT (United States); Ague, Jay [Yale Univ., New Haven, CT (United States); Karato, Shun-Ichiro [Yale Univ., New Haven, CT (United States); Oristaglio, Michael [Yale Univ., New Haven, CT (United States); Zhu, Wen-Iu [Univ. of Maryland, College Park, MD (United States); Lisabeth, Harry [Univ. of Maryland, College Park, MD (United States); Johnson, Kevin [Univ. of Hawaii, Honolulu, HI (United States)

    2014-09-30

    A program of laboratory experiments, modeling and fieldwork was carried out at Yale University, University of Maryland, and University of Hawai‘i, under a DOE Award (DE-FE0004375) to study mineral carbonation as a practical method of geologic carbon sequestration. Mineral carbonation, also called carbon mineralization, is the conversion of (fluid) carbon dioxide into (solid) carbonate minerals in rocks, by way of naturally occurring chemical reactions. Mafic and ultramafic rocks, such as volcanic basalt, are natural candidates for carbonation, because the magnesium and iron silicate minerals in these rocks react with brines of dissolved carbon dioxide to form carbonate minerals. By trapping carbon dioxide (CO2) underground as a constituent of solid rock, carbonation of natural basalt formations would be a secure method of sequestering CO2 captured at power plants in efforts to mitigate climate change. Geochemical laboratory experiments at Yale, carried out in a batch reactor at 200°C and 150 bar (15 MPa), studied carbonation of the olivine mineral forsterite (Mg2SiO4) reacting with CO2 brines in the form of sodium bicarbonate (NaHCO3) solutions. The main carbonation product in these reactions is the carbonate mineral magnesite (MgCO3). A series of 32 runs varied the reaction time, the reactive surface area of olivine grains and powders, the concentration of the reacting fluid, and the starting ratio of fluid to olivine mass. These experiments were the first to study the rate of olivine carbonation under passive conditions approaching equilibrium. The results show that, in a simple batch reaction, olivine carbonation is fastest during the first 24 hours and then slows significantly and even reverses. A natural measure of the extent of carbonation is a quantity called the carbonation fraction, which compares the amount of carbon removed from solution, during a run, to the maximum amount

  13. Evaluation criteria for gas source rocks of marine carbonate in China

    Institute of Scientific and Technical Information of China (English)

    WANG Zhaoyun; ZHAO Wenzhi; WANG Yunpeng

    2005-01-01

    Hydrocarbon generating and expulsion simulation experiments are carried out using samples artifically matched between the acid-dissolved residue of relatively low-maturity limestone and the original sample. This work makes up for the insufficiency of source rock samples with high abundance of organic matters and low maturity in China. The organic carbon content of the 10 prepared samples varies between 0.15 % and 0.74 %. Pyrolysis data and simulation experiment results of hydrocarbon generating and expulsion, which were obtained by a high-temperature and high-pressure open system, indicate that the lower limit of organic carbon content for marine carbonate rock to generate and expel hydrocarbons is 0.23 %-0.31%. In combination with the numerical analysis of organic carbon in marine carbonate rocks from Tarim Basin, Sichuan Basin, Ordos Basin and North China, as well as the contribution of these gas source rocks to the discovered gas pools, we think that the organic carbon criterion for carbonate gas source rocks should be 0.3%.

  14. Burial stress and elastic strain of carbonate rocks

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke

    2014-01-01

    the product of pore pressure and Biot's coefficient. We can now calculate the elastic strain by dividing “effective stress” with the rock frame modulus. By this procedure, the degree of elastic deformation at a given time and depth can be directly expressed. This facilitates the discussion of the deformation......Burial stress on a sediment or sedimentary rock is relevant for predicting compaction or failure caused by changes in, e.g., pore pressure in the subsurface. For this purpose, the stress is conventionally expressed in terms of its effect: “the effective stress” defined as the consequent elastic...... strain multiplied by the rock frame modulus. We cannot measure the strain directly in the subsurface, but from the data on bulk density and P‐wave velocity, we can estimate the rock frame modulus and Biot's coefficient and then calculate the “effective vertical stress” as the total vertical stress minus...

  15. Metasomatic Origin of Some of the Eclogite—Bearing Carbonate Rocks in the Dabie Mountain Region,China

    Institute of Scientific and Technical Information of China (English)

    顾连兴; 杜建国; 等

    1999-01-01

    Carbonate rocks are one of the major hosts to eclogite in the Mt.Dabie region.Eclogite bodies enclosed in the carbonate rocks occur mostly as knobs,ovoids and lenses measuring centimeters to tens of centimeters in size.The bodies have been intensely carbonatized and usually have transitional contacts with their carbonate hosts.The carbonate rocks have abundant relics of eclogite minerals and their tetrogressive derivatives.The REE patterns of the carbonate rocks are characterized by the absence of negative Ce anomaly.These features suggest that a considerable portion of the eclogite-bearing carbonate rocks in the Mt .Dabie region was produced by carbonatization of eclogites and their retrogressive derivatives.These carbonate rocks suffered deformation and recrystllization after their formation.

  16. Rock Physics of Geologic Carbon Sequestration/Storage

    Energy Technology Data Exchange (ETDEWEB)

    Dvorkin, Jack; Mavko, Gary

    2013-05-31

    This report covers the results of developing the rock physics theory of the effects of CO{sub 2} injection and storage in a host reservoir on the rock's elastic properties and the resulting seismic signatures (reflections) observed during sequestration and storage. Specific topics addressed are: (a) how the elastic properties and attenuation vary versus CO{sub 2} saturation in the reservoir during injection and subsequent distribution of CO{sub 2} in the reservoir; (b) what are the combined effects of saturation and pore pressure on the elastic properties; and (c) what are the combined effects of saturation and rock fabric alteration on the elastic properties. The main new results are (a) development and application of the capillary pressure equilibrium theory to forecasting the elastic properties as a function of CO{sub 2} saturation; (b) a new method of applying this theory to well data; and (c) combining this theory with other effects of CO{sub 2} injection on the rock frame, including the effects of pore pressure and rock fabric alteration. An important result is translating these elastic changes into synthetic seismic responses, specifically, the amplitude-versus-offset (AVO) response depending on saturation as well as reservoir and seal type. As planned, three graduate students participated in this work and, as a result, received scientific and technical training required should they choose to work in the area of monitoring and quantifying CO{sub 2} sequestration.

  17. Research on Diageneses of Cambrian Shoal Facies Carbonate Rocks in the Xiadong Area, Hubei Province

    Institute of Scientific and Technical Information of China (English)

    张秀莲; 蒋凌志

    2001-01-01

    With continuous outcrops, developed shoal facies rocks, complete types of diagenesis and changeable diagenetic environments, Cambrian strata are well developed in the Xiadong area, Yichang, Hubei Province. Under the combined influence of numerous diageneses, secondary pores can be formed, which result in better reservoir properties of the rock strata. The Cambrian rocks in this area consist of mainly carbonate rocks and secondarily detrital rocks. The carbonate rocks are dominated by grainstones including wormkalk, calcirudite-calcarenite, oolitic limestone and oncolitic limestone. Graded bedding and cross bedding are well developed in the strata, which indicates that the formation environment is of a high-energy shoal facies. In this area, there has developed a sequence of stable Cambrian platform carbonate deposition. The evolution trend is as follows: open sea shelf facies? intertidal low-energy restricted sea facies? intertidal high-energy shoal facies? coastal shoal facies? evaporite tidal-flat facies. The diageneses that the strata have experienced mainly include dolomitization, dedolomitization and dissolution, which are constructive diageneses for the formation of secondary pores, such as intercrystal pores, intercrystal solution pores, gypsum mold pores and caverns of dolomite. The diagenetic facies intervals can be divided into the unitary and the compound ones, totalling 22 in the area. In the early atmospheric fresh-water diagenetic environment and the late epidiagenetic environment, Cambrian rocks, especially dolomite of the Middle and Upper Cambrian, experienced extensive and profound fresh water corrosion, forming pore intervals with a porosity ranging from 5% to 15%.

  18. Determination of Carbonate Rock Chemistry Using Laboratory-Based Hyperspectral Imagery

    Directory of Open Access Journals (Sweden)

    Nasrullah Zaini

    2014-05-01

    Full Text Available The development of advanced laboratory-based imaging hyperspectral sensors, such as SisuCHEMA, has created an opportunity to extract compositional information of mineral mixtures from spectral images. Determining proportions of minerals on rock surfaces based on spectral signature is a challenging approach due to naturally-occurring minerals that exist in the form of intimate mixtures, and grain size variations. This study demonstrates the application of SisuCHEMA hyperspectral data to determine mineral components in hand specimens of carbonate rocks. Here, we applied wavelength position, spectral angle mapper (SAM and linear spectral unmixing (LSU approaches to estimate the chemical composition and the relative abundance of carbonate minerals on the rock surfaces. The accuracy of these classification methods and correlation between mineral chemistry and mineral spectral characteristics in determining mineral constituents of rocks are also analyzed. Results showed that chemical composition (Ca-Mg ratio of carbonate minerals at a pixel (e.g., sub-grain level can be extracted from the image pixel spectra using these spectral analysis methods. The results also indicated that the spatial distribution and the proportions of calcite-dolomite mixtures on the rock surfaces vary between the spectral methods. For the image shortwave infrared (SWIR spectra, the wavelength position approach was found to be sensitive to all compositional variations of carbonate mineral mixtures when compared to the SAM and LSU approaches. The correlation between geochemical elements and spectroscopic parameters also revealed the presence of these carbonate mixtures with various chemical compositions in the rock samples. This study concludes that the wavelength position approach is a stable and reproducible technique for estimating carbonate mineral chemistry on the rock surfaces using laboratory-based hyperspectral data.

  19. Acoustic Velocity Data for Clay Bearing Carbonate Rocks

    DEFF Research Database (Denmark)

    Lind, Ida; Shogenova, Alla

    1998-01-01

    Two sets of acoustic data on carbonates were combined to span the porosity interval from below 5% to more than 75%: dolomite and limestone of Paleozoic age from Estonia and mixed sediments from the Caribbean. The carbonate content of the samples ranges from less than 50% to 100%, and it was attem...

  20. Mineral replacements during carbonation of peridotite: implications for carbon dioxide sequestration in ultramafic rocks

    Science.gov (United States)

    Beinlich, Andreas; Hövelmann, Jörn; Plümper, Oliver; Austrheim, Hâkon

    2010-05-01

    In contact with CO2, ultramafic rocks are known to be reactive and eventually form ophicarbonates and listwaenites. Here we present observations from serpentinized peridotite clasts from the Solund Devonian Basin, SW Norway. These clasts show evidence for a stepwise reaction history starting with initial serpentinization and resulting in the formation of carbonates (mainly calcite and dolomite) and quartz. Thus, they represent a natural analogue for CO2 sequestration in ultramafic rocks, which was proposed by the Inter Governmental Panel on Climate Change (IPCC 2005) as one possibility for long-term CO2 storage. In several layers of the basin, the carbonatized ultramafic clasts are important constituents and account for up to 20 vol. % of the basin infill. The investigated clasts show a concentric build-up with green to grey colored cores surrounded by mm to 10 cm thick zones of red to black shades. Textural evidence indicates the following alteration sequence: An early stage is represented by serpentinization of peridotite resulting in a typical mesh texture, with veins of serpentine and Ni-rich hematite surrounding compartments of relict olivine (Fo90). Subsequently, relict olivine breaks down to form an alteration product which is significantly depleted in Mg relative to the precursor olivine. In the more advanced ophicarbonate stage, compartments are filled with calcite, quartz, and talc. In the most advanced stage, quartz, calcite, and hematite dominate and occur together with minor amounts of chromite, talc, and chlorite. The textural evolution is accompanied by a decrease in whole-rock MgO from 40 to 2 wt. % and a CaO increase from 1 to 35 wt. %. All clasts are characterized by high Cr and Ni (1000-4000 and 500-3000 ppm, respectively) revealing their ultramafic origin. Transmission electron microscopy (TEM) observations indicate that the alteration product after olivine is composed of an amorphous material, which is compositionally close to serpentine

  1. Anisotropic rock physics models for interpreting pore structures in carbonate reservoirs

    Institute of Scientific and Technical Information of China (English)

    Li Sheng-Jie; Shao Yu; Chen Xu-Qiang

    2016-01-01

    We developed an anisotropic effective theoretical model for modeling the elastic behavior of anisotropic carbonate reservoirs by combining the anisotropic self-consistent approximation and differential effective medium models. By analyzing the measured data from carbonate samples in the TL area, a carbonate pore-structure model for estimating the elastic parameters of carbonate rocks is proposed, which is a prerequisite in the analysis of carbonate reservoirs. A workfl ow for determining elastic properties of carbonate reservoirs is established in terms of the anisotropic effective theoretical model and the pore-structure model. We performed numerical experiments and compared the theoretical prediction and measured data. The result of the comparison suggests that the proposed anisotropic effective theoretical model can account for the relation between velocity and porosity in carbonate reservoirs. The model forms the basis for developing new tools for predicting and evaluating the properties of carbonate reservoirs.%♦Corresponding author: Li Sheng-Jie (Email: Richard@cup.edu.cn)

  2. Preliminary Rock Physics Characterization of Mississippian Carbonate Reservoir in Canada

    Science.gov (United States)

    Lee, M.; Keehm, Y.; Kim, H.

    2011-12-01

    The Mississippian formations in the Western Canada Sedimentary Basin are known to have large hydrocarbon resources. The Lodgepole formation is the most important reservoir for oil production in Daly and Virden fields. In this study, we performed preliminary reservoir characterization using rock physics modeling. We first delineated the Lodgepole formation by geological information, well-logs and core analysis data. Then, we conducted rock physics analyses such as GR-AI, DEM modeling, porosity-Vp, density-Vp, and porosity-permeability. We identified the Lodgepole formation has different porosity types, volume of shale, and the degree of fractures in difference intervals. In the upper part of the formation, we found that vuggy pores are well developed. Inter-particular porosity and fractures become significant as the depth increases. We found that the lower part can be divided into two groups by acoustic impedance. The prospective reservoir interval, one of the two groups, has higher fracture density, which can be identified by lower acoustic impedance. This result also implies that we could also use AVO analyses to delineate good reservoir intervals. In conclusion, rock physics modeling can be effectively applied to characterize the Lodgepole formation quantitatively with well-log and core analysis data. Acknowledgement: This work was supported by the Energy Resources R&D program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government Ministry of Knowledge Economy (No. 2009201030001A).

  3. Carbon isotopic studies of organic matter in Precambrian rocks.

    Science.gov (United States)

    Oehler, D. Z.; Schopf, J. W.; Kvenvolden, K. A.

    1972-01-01

    A survey has been undertaken of the carbon composition of the total organic fraction of a suite of Precambrian sediments to detect isotopic trends possibly correlative with early evolutionary events. Early Precambrian cherts of the Fig Tree and upper and middle Onverwacht groups of South Africa were examined for this purpose. Reduced carbon in these cherts was found to be isotopically similar to photosynthetically produced organic matter of younger geological age. Reduced carbon in lower Onverwacht cherts was found to be anomalously heavy; it is suggested that this discontinuity may reflect a major event in biological evolution.

  4. Delineation of Magnesium-rich Ultramafic Rocks Available for Mineral Carbon Sequestration in the United States

    Science.gov (United States)

    Krevor, S.C.; Graves, C.R.; Van Gosen, B. S.; McCafferty, A.E.

    2009-01-01

    The 2005 Intergovernmental Panel on Climate Change report on Carbon Dioxide Capture and Storage suggested that a major gap in mineral carbon sequestration is locating the magnesium-silicate bedrock available to sequester CO2. It is generally known that silicate minerals with high concentrations of magnesium are suitable for mineral carbonation. However, no assessment has been made covering the entire United States detailing their geographical distribution and extent, or evaluating their potential for use in mineral carbonation. Researchers at Columbia University and the U.S. Geological Survey have developed a digital geologic database of ultramafic rocks in the continental United States. Data were compiled from varied-scale geologic maps of magnesium-silicate ultramafic rocks. These rock types are potentially suitable as source material for mineral carbon-dioxide sequestration. The focus of the national-scale map is entirely on suitable ultramafic rock types, which typically consist primarily of olivine and serpentine minerals. By combining the map with digital datasets that show non-mineable lands (such as urban areas and National Parks), estimates on potential depth of a surface mine, and the predicted reactivities of the mineral deposits, one can begin to estimate the capacity for CO2 mineral sequestration within the United States. ?? 2009 Elsevier Ltd. All rights reserved.

  5. Integrated Experimental and Modeling Studies of Mineral Carbonation as a Mechanism for Permanent Carbon Sequestration in Mafic/Ultramafic Rocks

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zhengrong [Yale Univ., New Haven, CT (United States); Qiu, Lin [Yale Univ., New Haven, CT (United States); Zhang, Shuang [Yale Univ., New Haven, CT (United States); Bolton, Edward [Yale Univ., New Haven, CT (United States); Bercovici, David [Yale Univ., New Haven, CT (United States); Ague, Jay [Yale Univ., New Haven, CT (United States); Karato, Shun-Ichiro [Yale Univ., New Haven, CT (United States); Oristaglio, Michael [Yale Univ., New Haven, CT (United States); Zhu, Wen-Iu [Univ. of Maryland, College Park, MD (United States); Lisabeth, Harry [Univ. of Maryland, College Park, MD (United States); Johnson, Kevin [Univ. of Hawaii, Honolulu, HI (United States)

    2014-09-30

    A program of laboratory experiments, modeling and fieldwork was carried out at Yale University, University of Maryland, and University of Hawai‘i, under a DOE Award (DE-FE0004375) to study mineral carbonation as a practical method of geologic carbon sequestration. Mineral carbonation, also called carbon mineralization, is the conversion of (fluid) carbon dioxide into (solid) carbonate minerals in rocks, by way of naturally occurring chemical reactions. Mafic and ultramafic rocks, such as volcanic basalt, are natural candidates for carbonation, because the magnesium and iron silicate minerals in these rocks react with brines of dissolved carbon dioxide to form carbonate minerals. By trapping carbon dioxide (CO2) underground as a constituent of solid rock, carbonation of natural basalt formations would be a secure method of sequestering CO2 captured at power plants in efforts to mitigate climate change. Geochemical laboratory experiments at Yale, carried out in a batch reactor at 200°C and 150 bar (15 MPa), studied carbonation of the olivine mineral forsterite (Mg2SiO4) reacting with CO2 brines in the form of sodium bicarbonate (NaHCO3) solutions. The main carbonation product in these reactions is the carbonate mineral magnesite (MgCO3). A series of 32 runs varied the reaction time, the reactive surface area of olivine grains and powders, the concentration of the reacting fluid, and the starting ratio of fluid to olivine mass. These experiments were the first to study the rate of olivine carbonation under passive conditions approaching equilibrium. The results show that, in a simple batch reaction, olivine carbonation is fastest during the first 24 hours and then slows significantly and even reverses. A natural measure of the extent of carbonation is a quantity called the carbonation fraction, which compares the amount of carbon removed from solution, during a run, to the maximum amount

  6. Seismic wave propagation modeling in porous media for various frequencies: A case study in carbonate rock

    Science.gov (United States)

    Nurhandoko, Bagus Endar B.; Wardaya, Pongga Dikdya; Adler, John; Siahaan, Kisko R.

    2012-06-01

    Seismic wave parameter plays very important role to characterize reservoir properties whereas pore parameter is one of the most important parameter of reservoir. Therefore, wave propagation phenomena in pore media is important to be studied. By referring this study, in-direct pore measurement method based on seismic wave propagation can be developed. Porosity play important role in reservoir, because the porosity can be as compartment of fluid. Many type of porosity like primary as well as secondary porosity. Carbonate rock consist many type of porosity, i.e.: inter granular porosity, moldic porosity and also fracture porosity. The complexity of pore type in carbonate rocks make the wave propagation in these rocks is more complex than sand reservoir. We have studied numerically wave propagation in carbonate rock by finite difference modeling in time-space domain. The medium of wave propagation was modeled by base on the result of pattern recognition using artificial neural network. The image of thin slice of carbonate rock is then translated into the velocity matrix. Each mineral contents including pore of thin slice image are translated to velocity since mineral has unique velocity. After matrix velocity model has been developed, the seismic wave is propagated numerically in this model. The phenomena diffraction is clearly shown while wave propagates in this complex carbonate medium. The seismic wave is modeled in various frequencies. The result shows dispersive phenomena where high frequency wave tends to propagate in matrix instead pores. In the other hand, the low frequency waves tend to propagate through pore space even though the velocity of pore is very low. Therefore, this dispersive phenomena of seismic wave propagation can be the future indirect measurement technology for predicting the existence or intensity of pore space in reservoir rock. It will be very useful for the future reservoir characterization.

  7. Multiphase fluid-rock reactions among supercritical carbon dioxide, brine, aquifer, and caprock: relevance to geologic sequestration of carbon

    Energy Technology Data Exchange (ETDEWEB)

    Kaszuba, J. P. (John P.); Janecky, D. R. (David R.); Snow, M. G. (Marjorie G.)

    2004-01-01

    The reactive behavior of a multiphase fluid (supercritical CO{sub 2} and brine) under physical-chemical conditions relevant to geologic storage and sequestration in a carbon repository is largely unknown. Experiments were conducted in a flexible cell hydrothermal apparatus to evaluate multiphase fluid-rock (aquifer plus caprock) reactions that may impact repository integrity.

  8. Weathering-pedogenesis of Carbonate Rocks and Its Environmental Effects in Subtropical Region

    Institute of Scientific and Technical Information of China (English)

    ZHU Lijun; HE Shouyang; LI Jingyang

    2008-01-01

    We investigated the weathering-pedogenesis of carbonate rocks and its environmental effects in subtropical regions of China. The investigation demonstrated that the weathering-pedogenesis of carbonate rocks is the process of a joint action of corrosion and illuviation and metasomatism in subtropical region. It is characterized by multi-stage, multi-path and multi-style.With the persisting development of weathering-pedogenesis of carbonate rocks, metasomatic pedogenesis progressively became the main process of the weathering-pedogenesis and the dominant style of formation of minerals. And it proceeds through the whole process of evolution of theweathering-pedogenesis of carbonate rocks. The stage evolution of wcathering-pedogenesis ofcarbonate rocks and the fractionation evolution of newly produced minerals are characterized byobvious vertically zoning structures and the rules of gradation of elements geochemical characteristics in the carbonate rocks weathering profiles. The geochemical process of weathering-pedogenesis of carbonate rocks can be divided into three geochemical evolution stages, I.e., the Ca, Mg-depletion and Si, AI-enrichment stage; the Fe, Mn enrichment stage and the Si-depletion and Al-enrichment stage in the subtropical regions. Consistent with the three geochemical evolution stages, the sequence of formation and evolution of minerals can be divided into the clay mineral stage; the Fe, Mn oxide and the gibbsite stage. The influence of weathering-pedogenesis of carbonate rocks on the chemical forms of heavy elements is mainly affected via newly produced components and minerals in the process of weathering-pedogenesis, e.g., iron oxide minerals and organic matters. The important mechanism for the mobilization, transport and pollution of F and As is affected the selective adsorption and desorption of F and As on the surface of iron oxide minerals in the subtropical karst zones, I.e., the selective adsorption and desorption on mineral surfaces of

  9. Use of ``rock-typing`` to characterize carbonate reservoir heterogeneity. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Ikwuakor, K.C.

    1994-03-01

    The objective of the project was to apply techniques of ``rock-typing`` and quantitative formation evaluation to borehole measurements in order to identify reservoir and non-reservoir rock-types and their properties within the ``C`` zone of the Ordovician Red River carbonates in the northeast Montana and northwest North Dakota areas of the Williston Basin. Rock-typing discriminates rock units according to their pore-size distribution. Formation evaluation estimates porosities and pore fluid saturation. Rock-types were discriminated using crossplots involving three rock-typing criteria: (1) linear relationship between bulk density and porosity, (2) linear relationship between acoustic interval transit-time and porosity, and (3) linear relationship between acoustic interval transit-time and bulk density. Each rock-type was quantitatively characterized by the slopes and intercepts established for different crossplots involving the above variables, as well as porosities and fluid saturations associated with the rock-types. All the existing production was confirmed through quantitative formation evaluation. Highly porous dolomites and anhydritic dolomites contribute most of the production, and constitute the best reservoir rock-types. The results of this study can be applied in field development and in-fill drilling. Potential targets would be areas of porosity pinchouts and those areas where highly porous zones are downdip from non-porous and tight dolomites. Such areas are abundant. In order to model reservoirs for enhanced oil recovery (EOR) operations, a more localized (e.g. field scale) study, expanded to involve other rock-typing criteria, is necessary.

  10. CaCO3, its reaction and carbonate rocks: terahertz spectroscopy investigation

    Science.gov (United States)

    Zhan, Honglei; Wu, Shixiang; Zhao, Kun; Bao, Rima; Xiao, Lizhi

    2016-10-01

    Carbonate-rich rocks cover a primary part of the earth’s petroleum geology reservoir. The study of carbonate has special significance and more effective study methods are now needed. In order to improve the availability of carbonate rock detection, terahertz (THz) spectroscopy was employed to investigate relevant materials in Na2CO3  +  CaCl2  =  CaCO3  +  2NaCl, which is often used to generate CaCO3. By comparing the materials composited with different ions, it can be revealed that Ca2+, \\text{CO}32- , Na+ and Cl- have respective absorption features at different frequencies. Furthermore, by utilizing a conservation equation it can be observed that the average refractive indices of Na2CO3 as well as CaCl2 equal those of CaCO3 and NaCl in the entire range. Combining the absorption and refractive effect of the materials in the reaction can comprehensively characterize the different substances and reveal the inner interaction during the reaction. THz spectra can deduce the process of molecule rearrangement in the chemical reaction of long-term rock evolution. Besides, the absorption features of the real carbonate rock collected from the nearest town of Sinan county, Guizhou province in Yunnan-Guizhou plateau validate the peaks’ central frequencies of ions and the principal components of carbonates, which can be in agreement with the SEM-EDS analysis. This research will supply a spectral tool to identify the particles in the rock and deduce an evolution of petroleum carbonate reservoir.

  11. Sr isotopic chemostratigraphy of Precambrian carbonate rocks in the Amderma Rise, Pai-Khoi Ridge

    Science.gov (United States)

    Kuznetsov, A. B.; Starikova, E. V.; Maslov, A. V.; Konstantinova, G. V.

    2016-08-01

    The Sr and C isotopic compositions of Precambrian carbonate rocks are determined for Amderma Rise, in the northeastern margin of Pai-Khoi Ridge. Based on the Sr isotopic chemostratigraphy, it is established for the first time that the Amderma Formation is referred to the Early Vendian, while the Morozovsk Formation is Late Riphean in age. This conclusion along with detailed mapping proves that the Precambrian "section" of the Amderma Rise is a series of tectonic plates combined in a nonchronostratigraphic order. Volcanic and sedimentary rocks of the Morozovsk and Sokolninsk formations make up the allochthon proper, while carbonate rocks of the Amderma Formation make up the para-autochthon. The high values of δ13C (up to +9.5‰) identified in limestones of both formations suggest a considerable distance of the Pai-Khoi paleobasin from the passive margin of the Baltic Region upon facies similarity to the Laurentia active margins.

  12. Weathering of Carbonate Rocks by Biological Soil Crusts in Karst Areas

    Institute of Scientific and Technical Information of China (English)

    Ye Chen; Bin Lian; Zuoying Yin; Yuan Tang

    2014-01-01

    The weathering of carbonate rocks by biological soil crusts (BSC) in karst areas is very common. It is helpful to understand the weathering mechanisms and processes for avoiding karst rock-desertification. The weathering of carbonate rocks by BSC in karst areas, namely the expansion, contraction and curl resulting from environmental wetting-drying cycles, was investigated and ana-lyzed in this paper. The bulk density, area and thickness of BSC were determined and the weathering amount of limestone and dolomite per unit area of BSC was calculated as 3 700 and 3 400 g·m-2; the amount of biomass on the surface of limestone and dolomite was calculated as 1 146 and 1 301 g·m-2, respectively. Such an increased weathering amount was not only the result of chemical and physical weathering of BSC on carbonate rocks, but also the attachment and cementation of BSC to clay parti-cles, dust-fall, sand particles, solid particles brought by strong air currents, wind and other factors in the surrounding environment, which may also be related to the special environment and the special time period. Based on the results obtained, a weathering mode of BSC is studied, and the mechanisms of weathering by BSC are discussed. In conclusion, we suggest that the mechanical force exerted by the expansion and constriction of gelatinous and mucilaginous substances through wetting and drying of BSC play a significant role in the physical weathering process of the carbonate substrates.

  13. Quantification methods of Black Carbon: Comparison of Rock-Eval analysis with traditional methods

    NARCIS (Netherlands)

    Poot, A.; Quik, J.T.K.; Veld, H.; Koelmans, A.A.

    2009-01-01

    Black Carbon (BC) quantification methods are reviewed, including new Rock-Eval 6 data on BC reference materials. BC has been reported to have major impacts on climate, human health and environmental quality. Especially for risk assessment of persistent organic pollutants (POPs) it is important to ac

  14. Isotopic studies of beach rock carbonates from Konkan, central west coast of India

    Digital Repository Service at National Institute of Oceanography (India)

    Kumar, B.; Rajamanickam, G.V.; Gujar, A.R.

    The beach rock carbonates from the 200 km long stretch from Guhagar in the north to Deogad in the south along the Konkan coast (Maharashtra, India) are studied for sup(14)C dating and sup(13)C : sup(12)C and sup(18)O : sup(16)O ratio determination...

  15. Driving mechanism of low salinity flooding in carbonate rocks (SPE-174300-MS)

    NARCIS (Netherlands)

    Mahani, Hassan; Berg, Steffen; Keya, Arsene; Bartels, W.; Nasralla, Ramez; Rossen, William

    2015-01-01

    Several studies conducted mainly on the laboratory scale indicate that in carbonate rocks oil displacement can be influenced by the ionic composition of the brine, providing an opportunity to improve recovery by optimizing the brine mixture used in secondary or tertiary recovery. In industry this to

  16. Sylolites in carbonate rock: barriers to fluid flow?

    Science.gov (United States)

    Heap, M. J.; Baud, P.; Meredith, P. G.; Reuschlé, T.

    2012-04-01

    Stylolites, products of intergranular pressure-solution, form laterally-extensive, clay-enriched, planar features in porous sedimentary rocks. While mechanical strain localisation has been shown to dramatically decrease permeability in sedimentary rock (Baud et al., 2012), little attention has focused on the impact of chemical strain localisation. Potentially, stylolites could significantly influence regional fluid flow, an important consideration in, for example, geotechnical engineering and petroleum geoscience. To this end, we have performed a systematic study of the influence of stylolites (both parallel and perpendicular to the imposed flow direction) on the water and gas permeability of three oolitic limestones with porosities ranging from 6 to 16 %. Our experimental data show that the presence of stylolites increased the permeability of our limestone samples by about a factor of two (when compared to the adjacent stylolite-free material). However, the magnitude of the permeability increase was found to be independent of stylolite orientation and number. Porosity measurements demonstrated that core samples containing stylolites were consistently more porous than the adjacent stylolite-free material. We therefore suggest that it is the increase in porosity (or "stylolitic porosity", as a result of the presence of a stylolite) that is responsible for the observed modest increase in permeability. This conclusion is supported by x-ray computed tomographic images of the samples that show that sample density is unperturbed by the presence of a stylolite. We can further conclude that the impact of mechanical strain localisation (e.g., compaction bands, see Baud et al., 2012) has a much greater impact on fluid flow than chemical strain localisation (e.g., stylolites, this study).

  17. Laboratory Experiments to Evaluate Matrix Diffusion of Dissolved Organic Carbon Carbon-14 in Southern Nevada Fractured-rock Aquifers

    Energy Technology Data Exchange (ETDEWEB)

    Hershey, Ronald L. [Nevada University, Reno, NV (United States). Desert Research Institute; Fereday, Wyatt [Nevada University, Reno, NV (United States). Desert Research Institute

    2016-05-01

    Dissolved inorganic carbon (DIC) carbon-14 (14C) is used to estimate groundwater ages by comparing the DIC 14C content in groundwater in the recharge area to the DIC 14C content in the downgradient sampling point. However, because of chemical reactions and physical processes between groundwater and aquifer rocks, the amount of DIC 14C in groundwater can change and result in 14C loss that is not because of radioactive decay. This loss of DIC 14C results in groundwater ages that are older than the actual groundwater ages. Alternatively, dissolved organic carbon (DOC) 14C in groundwater does not react chemically with aquifer rocks, so DOC 14C ages are generally younger than DIC 14C ages. In addition to chemical reactions, 14C ages may also be altered by the physical process of matrix diffusion. The net effect of a continuous loss of 14C to the aquifer matrix by matrix diffusion and then radioactive decay is that groundwater appears to be older than it actually is. Laboratory experiments were conducted to measure matrix diffusion coefficients for DOC 14C in volcanic and carbonate aquifer rocks from southern Nevada. Experiments were conducted using bromide (Br-) as a conservative tracer and 14C-labeled trimesic acid (TMA) as a surrogate for groundwater DOC. Outcrop samples from six volcanic aquifers and five carbonate aquifers in southern Nevada were used. The average DOC 14C matrix diffusion coefficient for volcanic rocks was 2.9 x 10-7 cm2/s, whereas the average for carbonate rocks was approximately the same at 1.7 x 10-7 cm2/s. The average Br- matrix diffusion coefficient for volcanic rocks was 10.4 x 10-7 cm2/s, whereas the average for carbonate rocks was less at 6.5 x 10-7 cm2/s. Carbonate rocks exhibited greater variability in

  18. Probe imaging studies of magnetic susceptibility and permeability for sensitive characterisation of carbonate reservoir rocks

    Science.gov (United States)

    Ivakhnenko, Aleksandr; Bigaliyeva, Akmaral; Dubinin, Vladislav

    2016-04-01

    In this study were disclosed the main principals of identifying petrophysical properties of carbonate reservoirs such as porosity, permeability and magnetic susceptibility. While exploring and developing reservoir there are significant diversity of tasks that can be solved by appropriate knowledge of properties which are listed above. Behavior of fluid flow, distribution of hydrocarbons and other various industrial applications can be solved by measuring areal distribution of these petrophysical parameters. The results demonstrate how magnetic probe and hysteresis measurements correlate with petrophysical parameters in carbonate reservoirs. We made experimental measurements and theoretical calculations of how much magnetic susceptibility depends on the porosity of the rocks and analyzed data with graphics. In theoretical model of the carbonate rocks we considered calcite, dolomite, quartz and combinations of calcite and dolomite, calcite and Fe-dolomite, calcite and quartz, calcite and aragonite with increasing concentrations of the dolomite, Fe-dolomite, quartz and aragonite up to 50% with step of 5%. Here we defined dependence of magnetic susceptibility from the porosity: the higher porosity measurements, the less slope of magnetic susceptibility, consequently mass magnetization is higher for diamagnetic and lower for paramagnetic carbonate rocks, but in the both cases magnetic susceptibility tries to reach zero with increasing of the total porosity. Rock measurements demonstrate that reservoir zones of the low diamagnetic magnetic susceptibility are generally correlated with higher permeability and also porosity distribution. However for different carbonate reservoirs we establish different relationships depending on the complexity of their mineralogy and texture. Application of integral understanding in distribution of permeability, porosity and mineral content in heterogeneous carbonates represented by this approach can be useful tool for carbonate reservoir

  19. Hydrocarbon accumulation in deep fluid modified carbonate rock in the Tarim Basin

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The activities of deep fluid are regionalized in the Tarim Basin. By analyzing the REE in core samples and crude oil, carbon isotope of carbon dioxide and inclusion temperature measurement in the west of the Tazhong Uplift in the western Tarim Basin, all the evidence confirms the existence of deep fluid. The deep fluid below the basin floor moved up into the basin through discordogenic fauit and volcanicity to cause corrosion and metaaomatosis of carbonate rock by exchange of matter and energy. The pore structure and permeability of the carbonate reservoirs were improved, making the carbonate reservoirs an excellent type of deeply buried modification. The fluorite ore belts discovered along the large fault and the volcanic area in the west of the Tazhong Uplift are the outcome of deep fluid action. Such carbonate reservoirs are the main type of reservoirs in the Tazhong 45 oilfield. The carbonate reservoirs in well YM 7 are improved obviously by thermal fluid dolomitization. The origin and territory of deep fluid are associated with the discordogenic fault and volcanicity in the basin. The discordogenic fault and volcanic area may be the pointer of looking for the deep fluid modified reservoirs. The primary characteristics of hydrocarbon accumulation in deep fluid reconstructed carbonate rock are summarized as accumulation near the large fault and volcano passage, late-period hydrocarbon accumulation after volcanic activity, and subtle trap reservoirs controlled by lithology.

  20. The role of forest trees and their mycorrhizal fungi in carbonate rock weathering and its significance for global carbon cycling.

    Science.gov (United States)

    Thorley, Rachel M S; Taylor, Lyla L; Banwart, Steve A; Leake, Jonathan R; Beerling, David J

    2015-09-01

    On million-year timescales, carbonate rock weathering exerts no net effect on atmospheric CO2 concentration. However, on timescales of decades-to-centuries, it can contribute to sequestration of anthropogenic CO2 and increase land-ocean alkalinity flux, counteracting ocean acidification. Historical evidence indicates this flux is sensitive to land use change, and recent experimental evidence suggests that trees and their associated soil microbial communities are major drivers of continental mineral weathering. Here, we review key physical and chemical mechanisms by which the symbiotic mycorrhizal fungi of forest tree roots potentially enhance carbonate rock weathering. Evidence from our ongoing field study at the UK's national pinetum confirms increased weathering of carbonate rocks by a wide range of gymnosperm and angiosperm tree species that form arbuscular (AM) or ectomycorrhizal (EM) fungal partnerships. We demonstrate that calcite-containing rock grains under EM tree species weather significantly faster than those under AM trees, an effect linked to greater soil acidification by EM trees. Weathering and corresponding alkalinity export are likely to increase with rising atmospheric CO2 and associated climate change. Our analyses suggest that strategic planting of fast-growing EM angiosperm taxa on calcite- and dolomite-rich terrain might accelerate the transient sink for atmospheric CO2 and slow rates of ocean acidification.

  1. Diagenetic Pattern in the Citarate Carbonate Rocks, Cilograng Area, Lebak Regency, Banten Province

    Directory of Open Access Journals (Sweden)

    N. I. Basuki

    2014-06-01

    Full Text Available DOI: 10.17014/ijog.v7i3.142The carbonate sequence overlies conformably the tuffaceous sandstone unit, and in turn is conformably underlain by the tuff-sandstone unit, both of which are members of the Citarate Formation. The Citarate carbonate rocks were deposited in an open platform back reef environment, which was temporarily drowned by local sea level rise. Regional Middle Miocene deformation formed NNE-WSW trend faults and E-W trend folds in the researched area. This paper discusses the nature of diagenetic alteration of the Citarate carbonate rocks based on petrographic analyses of twenty surface samples. Carbonate rocks from bottom to top comprise algae packstone, packstone-grainstone, coral-algae packstone, and foraminifer wackestone-packstone. Fragments of coral, coralline red algae, and large foraminifera are the dominant bioclasts in most of the observed samples, whereas echinoids and bivalves are less abundant; they are set in a recrystallized micrite matrix. Planktonic foraminifera are abundant only in few samples. Fragments of plagioclase, igneous volcanic rocks, pyroclastic rocks (tuff, and much less abundant quartz are commonly present in all the studied samples. A generalized diagenesis includes early marine cementation by fibrous aragonite, compaction, aragonite dissolution and/or neomorphism, precipitation of equant-grained calcite cement in a phreatic environment, dissolution to form moldic porosities, dolomitization, the formation of stylolites and fractures, and precipitation of late ferroan calcite during burial. Multiple carbonate cements occur as pore-filling phases, with ferroan calcite cementation taking place during later-stage burial. Secondary porosities were formed during different stages in diagenetic processes, such as dissolution, dolomitization, and stylolite and fracture formations. Although precipitation of nonferroan and ferroan calcite cement occluded porosities, porosity enhancement during early selective

  2. Geological and geomechanical properties of the carbonate rocks at the eastern Black Sea Region (NE Turkey)

    Science.gov (United States)

    Ersoy, Hakan; Yalçinalp, Bülent; Arslan, Mehmet; Babacan, Ali Erden; Çetiner, Gözde

    2016-11-01

    Turkey located in the Alpine-Himalayan Mountain Belt has 35% of the natural stone reserves of the world and has good quality marble, limestone, travertine and onyx reserves especially in the western regions of the country. The eastern Black Sea Region with a 1.4 million meters cubes reserve has a little role on the natural stone production in the country. For this reason, this paper deals with investigation on the potential of carbonate stone in the region and determination of the geological and geo-mechanical properties of these rocks in order to provide economic contribution to the national economy. While the study sites are selected among the all carbonate rock sites, the importance as well as the representative of the sites were carefully considered for the region. After representative samples were analyzed for major oxide and trace element compositions to find out petrochemical variations, the experimental program conducted on rock samples for determination of both physical and strength properties of the carbonate rocks. The results of the tests showed that there are significant variations in the geo-mechanical properties of the studied rock groups. The density values vary from 2.48 to 2.70 gr/cm3, water absorption by weight values range from 0.07 to 1.15% and the apparent porosity of the carbonate rocks are between 0.19 and 3.29%. However, the values of the UCS shows variation from 36 to 80 MPa. Tensile and bending strength values range from 3.2 to 7.5 MPa and 6.0-9.2 MPa respectively. Although the onyx samples have the lowest values of apparent porosity and water absorption by weight, these samples do not have the highest values of UCS values owing to occurrence of the micro-cracks. The UCS values of the rock samples were also found after cycling tests However, the limestone samples have less than 5% deterioration after freezing-thawing and wetting-drying tests, but travertine and onyx samples have more than 15% deterioration. Exception of the apparent

  3. DETERMINATION OF ROCK-BREAKING PERFORMANCE OF HIGH-PRESSURE SUPERCRITICAL CARBON DIOXIDE JET

    Institute of Scientific and Technical Information of China (English)

    DU Yu-kun; WANG Rui-he; NI Hong-jian; LI Mu-kun; SONG Wei-qiang; SONG Hui-fang

    2012-01-01

    In this study,a well-designcd cxperimental setup is used to determine the rock-breaking performance of a high-pressure supercritical carbon dioxide (SC-CO2) jet.Its rock-breaking performance is first compared with that of a high-pressure water jet under the same operation conditions.The effects of five major factors that affect the rock-breaking performance of the high-pressure SC-CO2 jet,i.e.,the nozzle diameter,the standoff distance,the jet pressure,the rock compressive strength and the jet temperature are experimentally determined.The experimental results indicate that the rock-breaking performance of the SC-CO2 jet is significantly improved over the high-pressure water jet.It is also found that the rock-breaking performance of the SC-CO2 jet is improved with the increase of the nozzle diameter or the standoff distance,until the nozzle diameter or the standoff distance reaches a certain critical value and after that it begins to deteriorate.The rock-breaking performance of the SC-CO2 jet improves monotonically with the increase of the jet pressure,while it shows a monotonic deterioration with the increase of the rock compressive strength.In addition,it is found that,under the same working conditions,the SC-CO2 jet can always provide a better rock-breaking performance than the subcritical liquid CO2 jet.

  4. Carbon sequestration via reaction with basaltic rocks: geochemical modeling and experimental results

    Science.gov (United States)

    Rosenbauer, Robert J.; Thomas, Burt; Bischoff, James L.; Palandri, James

    2012-01-01

    Basaltic rocks are potential repositories for sequestering carbon dioxide (CO2) because of their capacity for trapping CO2 in carbonate minerals. We carried out a series of thermodynamic equilibrium models and high pressure experiments, reacting basalt with CO2-charged fluids over a range of conditions from 50 to 200 °C at 300 bar. Results indicate basalt has a high reactivity to CO2 acidified brine. Carbon dioxide is taken up from solution at all temperatures from 50 to 200 °C, 300 bar, but the maximum extent and rate of reaction occurs at 100 °C, 300 bar. Reaction path simulations utilizing the geochemical modeling program CHILLER predicted an equilibrium carbonate alteration assemblage of calcite, magnesite, and siderite, but the only secondary carbonate identified in the experiments was a ferroan magnesite. The amount of uptake at 100 °C, 300 bar ranged from 8% by weight for a typical tholeite to 26% for a picrite. The actual amount of CO2 uptake and extent of rock alteration coincides directly with the magnesium content of the rock suggesting that overall reaction extent is controlled by bulk basalt Mg content. In terms of sequestering CO2, an average basaltic MgO content of 8% is equivalent to 2.6 × 108 metric ton CO2/km3 basalt.

  5. Water-rock interaction during mineral carbonation and volcanic ash weathering

    OpenAIRE

    Helgi Arnar Alfreðsson 1984

    2015-01-01

    The reduction of atmospheric carbon dioxide (CO2) is considered one of the greatest challenges of this century. Carbon capture and storage (CCS) is one of the means proposed to lower the atmospheric CO2 content. The aim of the CarbFix project in Iceland was to design and test a CO2 re-injection system, in which CO2 from the Hellisheidi geothermal power plant was injected, fully dissolved in water, into basaltic rocks. In this way the carbon is mineralized upon basalt dissolution by the precip...

  6. Mass transfer controlled by fracturing in micritic carbonate rocks

    Science.gov (United States)

    Richard, James; Coulon, Michel; Gaviglio, Patrick

    2002-05-01

    The fractured Coniacian chalk from the Omey area (Paris Basin, France) displays strong evidence of modifications controlled by brittle deformation. Fracturing is associated with important changes in pore space (decrease in total porosity and pore interconnection, change in distribution of pore access diameters and capillary characteristics), nannofacies (gradual evolution from a point-contact fabric to a welded, interlocked or coalescent fabric) and chemical composition (Sr concentration decrease). These modifications result from fluid-rock interaction that control significant mass transfer (percentage of secondary calcite >50%). Sr is a remarkable indicator of these mass transfers. Sr analyses allowed us to prove that the deformed zone (26.7 m) is wider than the fractured zone (11.3 m). They also indicate that the footwall block is less affected than the hanging wall block. A physicochemical model of the deformation mechanism is proposed. It shows that a cyclic process of fracturing controls the temporal evolution of the fluid saturation and fluid pressure and, consequently, the mass transfer.

  7. "Frictional processes" in carbonate-bearing rocks at seismic deformation conditions

    Science.gov (United States)

    Di Toro, G.; Spagnuolo, E.; Violay, M.; Rempe, M.; Smith, S. A. F.; Nielsen, S. B.; Fondriest, M.; Plumper, O.

    2015-12-01

    Moderate to large earthquakes often rupture and propagate along faults in carbonate-bearing rocks (dolostones, limestones, marbles, etc.). Compared to silicate-bearing rocks, which melt, weaken and wear when sheared at seismic slip rates (ca. 1 m/s), carbonate-bearing rocks do not melt, the minimum friction coefficient can be much lower (down to 5% of static friction) and the wear rate is negligible at seismic slip rates. In cohesive carbonate-bearing rocks, experiments simulating seismic deformation conditions and stopped at slip initiation (solid lubricant) at asperity contacts. With progressive slip and bulk temperature increase, nanograins accommodate large strain rates (ca. 104 s-1) by grain boundary sliding as suggested by several authors. The presence of a microporous fabric boosts pore-controlled diffusive process propelled by CO2 gas exhaust due to decarbonation. Enhanced pore-controlled diffusive processes allow (1) efficient mass transfer during grain boundary sliding and (2) sintering of the nanograins into a foam-like slip surface at the end of the experiment.

  8. Sinkhole susceptibility in carbonate rocks of the Apulian karst (southern Italy)

    Science.gov (United States)

    Di Santo, Antonio; Fazio, Nunzio L.; Fiore, Antonio; Lollino, Piernicola; Luisi, Michele; Miccoli, Maria N.; Pagliarulo, Rosa; Parise, Mario; Perrotti, Michele; Pisano, Luca; Spalluto, Luigi; Vennari, Carmela; Vessia, Giovanna

    2016-04-01

    modelling the instability processes, and the development of charts for a preliminary evaluation of the stability of underground caves. Two distinct approaches were established to take into account the different petrographic, structural and geotechnical features of both the hard and soft carbonate rocks. The approach dealing with hard carbonate rocks (where natural karst caves develop) is based on speleological and geometrical surveys of the caves and on an integrated geological and geomechanical characterization of the carbonate rock mass, aimed at individuating the main critical aspects of the karst caves in terms of likely effects on the society. On the other hand, the approach to verify the stability of soft rocks where artificial cavities have been excavated is mostly dependent upon the peculiar petrographic and geomechanical characteristics of the calcarenite rock mass, typically massive and unaffected by tectonic discontinuities. As a consequence, the traditional analytical methods of rock mass classification fail in these materials, since the rock strength of soft calcarenites is mostly dependent upon sediment texture, porosity type and distribution and degree of cementation. The fluid circulation into the rock mass is also important because the removal of the rock matrix may induce a rapid deterioration of the mechanical behaviour of the rock mass. The approach to the calcarenite is mostly based on the characterization of petrographic and geotechnical parameters by means of direct sampling from the rock walls and in situ surveys (wells, trenches, etc.). Through implementation of the two approaches, our goal is to reconstruct accurate geometrical, geological and geotechnical models for both natural caves and artificial cavities. These models will be useful also to plan specific monitoring activities in order to understand the development of underground instability, and the related evolution through the rock mass, possibly threatening the urban areas and

  9. Experimental determination of natural carbonate rock dissolution rates with a focus on temperature dependency

    Science.gov (United States)

    Kirstein, Jens; Hellevang, Helge; Haile, Beyene G.; Gleixner, Gerd; Gaupp, Reinhard

    2016-05-01

    The denudation of carbonate rocks at landscape scale is controlled by factors like mineral composition, temperature, precipitation, runoff, fracture spacing and vegetation cover. Knowledge on carbonate denudation is important in order to understand landscape development and long-term terrestrial/marine carbon transport, but there are few laboratory studies done on weathering rates of natural carbonate rocks under the low temperatures relevant for glacial-interglacial periods. To enhance the understanding of carbonate dissolution kinetics we studied low-temperature dissolution reactions of various natural Triassic carbonate rocks belonging to the Lower Muschelkalk in Germany. We conducted batch and flow-through experiments investigating the direct correlation of dissolution rates with temperature, and to establish whether the fine-grained carbonate rocks (micrite) are more reactive than the coarser-grained sparitic limestones. By increasing the temperature from 5 to 26 °C far-from-equilibrium dissolution rates of micritic and sparitic limestone samples increased from 2.42 × 10- 07 to 10.88 × 10- 07 and 4.19 × 10- 07 to 7.74 × 10- 07 mol m- 2 s- 1, respectively (Specific Surface Areas (SSA) of about 0.006-0.01 m2/g). The dissolution rates of dolomite rock samples varied only slightly from 1.06 × 10- 07 to 2.02 × 10- 07 mol m- 2 s- 1 (SSA approximately 0.002 m2/g) in the temperature range 5-25 °C at circum-neutral pH. The obtained apparent activation energies are in the range of earlier experiments done at higher temperatures, but there is a distinct difference between the calcite in the micrite (~ 51 kJ/mol) and sparitic (~ 20-22 kJ/mol) lithologies, indicating that the dissolution mechanisms are not the same. Using these activation energies in modelling of natural carbonate denudation we see that there is a clear effect of changing temperature, but this is mostly through the increased solubility at lower temperatures and not through the increasing far

  10. Decrypting the Formation Conditions of the Basement Carbonate-Bearing Rocks at Nili Fossae

    Science.gov (United States)

    Brown, A. J.

    2015-12-01

    The Nili Fossae region is the site of a number of proposed Landing Sites for the Mars 2020 Rover. A distinguishing feature of many of these sites is the access to large exposures of carbonate (Ehlmann et al. 2008). Serpentinization has been proposed as a formation mechanism of these carbonates, including carbonated (Brown et al. 2010, Viviano, et al. 2013) and low temperature, near surface serpentinization. The potential for carbonated serpentization at Nili Fossae links the region to Earth analogs in terrestrial greenstone belts such as the Pilbara in Western Australia, where talc-carbonate bearing komatiite cumulate units of the Dresser Formation overlie the siliceous, stromatolite-bearing Strelley Pool Chert unit (Van Kranendonk and Pirajno, 2004). If a similar relationship exists on Mars, investigations of rocks stratigraphically beneath the carbonate-bearing units at Nili Fossae ("the basement rocks") may provide the best chance to examine well preserved organic material from the Noachian. This hypothesis is testable by Mars 2020. In preparation for the the Mars 2020 landing site, we are examining the thermodynamic relationships that favor formation of serpentine and talc-carbonate and different pressures and temperatures in the crust (Barnes 2007). This will allow us to constrain the low grade metamorphism required to replicate the proposed models of serpentinisation and help us understand the regional metamophic gradient that is critical to furthering our knowledge of the ancient rocks of Nili Fossae. Refs:Barnes, S. J. "Komatiites: Petrology, Volcanology, Metamorphism, and Geochemistry." S.E.G. 13 (2007): 13. Brown, A. J., et al.. "Hydrothermal Formation of Clay-Carbonate Alteration Assemblages in the Nili Fossae Region of Mars." EPSL 297 (2010): 174-82. Ehlmann, B. L. et al. "Orbital Identification of Carbonate-Bearing Rocks on Mars." Science 322, no. 5909 1828-32. Van Kranendonk, M.J., and F. Pirajno. "Geochemistry of Metabasalts and Hydrothermal

  11. In search of early life: Carbonate veins in Archean metamorphic rocks as potential hosts of biomarkers

    Science.gov (United States)

    Peters, Carl A.; Piazolo, Sandra; Webb, Gregory E.; Dutkiewicz, Adriana; George, Simon C.

    2016-11-01

    The detection of early life signatures using hydrocarbon biomarkers in Precambrian rocks struggles with contamination issues, unspecific biomarkers and the lack of suitable sedimentary rocks due to extensive thermal overprints. Importantly, host rocks must not have been exposed to temperatures above 250 °C as at these temperatures biomarkers are destroyed. Here we show that Archean sedimentary rocks from the Jeerinah Formation (2.63 billion yrs) and Carawine Dolomite (2.55 billion yrs) of the Pilbara Craton (Western Australia) drilled by the Agouron Institute in 2012, which previously were suggested to be suitable for biomarker studies, were metamorphosed to the greenschist facies. This is higher than previously reported. Both the mineral assemblages (carbonate, quartz, Fe-chlorite, muscovite, microcline, rutile, and pyrite with absence of illite) and chlorite geothermometry suggest that the rocks were exposed to temperatures higher than 300 °C and probably ∼400 °C, consistent with greenschist-facies metamorphism. This facies leads to the destruction of any biomarkers and explains why the extraction of hydrocarbon biomarkers from pristine drill cores has not been successful. However, we show that the rocks are cut by younger formation-specific carbonate veins containing primary oil-bearing fluid inclusions and solid bitumens. Type 1 veins in the Carawine Dolomite consist of dolomite, quartz and solid bitumen, whereas type 2 veins in the Jeerinah Formation consist of calcite. Within the veins fluid inclusion homogenisation temperatures and calcite twinning geothermometry indicate maximum temperatures of ∼200 °C for type 1 veins and ∼180 °C for type 2 veins. Type 1 veins have typical isotopic values for reprecipitated Archean sea-water carbonates, with δ13CVPDB ranging from - 3 ‰ to 0‰ and δ18OVPDB ranging from - 13 ‰ to - 7 ‰, while type 2 veins have isotopic values that are similar to hydrothermal carbonates, with δ13CVPDB ranging from - 18

  12. Fault zone properties in carbonate rocks: insights for well logs, core and field data

    Science.gov (United States)

    Giorgioni, Maurizio; Cilona, Antonino; Tondi, Emanuele; Agosta, Fabrizio

    2010-05-01

    In the last few years, numerous works addressed the deformation processes in carbonate rocks. These studies, generally sponsored by the oil industry, aimed to a better understanding of the structural and hydraulic properties of fault zones as well as of the subsurface fluid pathways in deformed carbonate rocks. This effort was mainly driven by the economic significance that carbonate rocks have for the oil industry, since they represent important natural reservoirs of hydrocarbons. According to the many field-based research scientific articles published in the recent past, both structural and hydraulic properties of fault zones, and their evolution trough time, exert a first order control on subsurface fluid flow and accumulation in fractured carbonate reservoirs. In order to convert this knowledge into predictive modeling tools that would help to optimize their exploitation, it should be useful to integrate the field-based data together with the subsurface data, which generally consist of core and well log (resistivity, acoustic, gamma ray etc.) analyses usually gathered to assess the formation evaluation of carbonate reservoir. The presented work aims at filling this cognitive gap by the acquisition and elaboration of subsurface geophysical properties of a hydrocarbon-bearing oblique normal fault zone characterized by 10's of m offset, and cropping out in an exposed analogue of fractured carbonate reservoir (Maiella Mountain, Italy). The deformation mechanisms associated to the processes of fault nucleation and development within the Oligo-Miocene shallow-water carbonate rocks were documented in the recent past by our research group. In this present contribution, we present the results of our elaboration of the geophysical data, obtained from well logs oriented perpendicular to the study fault zone. These results are consistent with the following statements: a) there is a meaningful correlations between cores and digital images; b) a detailed structural analysis

  13. Performance improvement of ionic surfactant flooding in carbonate rock samples by use of nanoparticles

    Directory of Open Access Journals (Sweden)

    Mohammad Ali Ahmadi

    2016-07-01

    Full Text Available Abstract Various surfactants have been used in upstream petroleum processes like chemical flooding. Ultimately, the performance of these surfactants depends on their ability to reduce the interfacial tension between oil and water. The surfactant concentration in the aqueous solution decreases owing to the loss of the surfactant on the rock surface in the injection process. The main objective of this paper is to inhibit the surfactant loss by means of adding nanoparticles. Sodium dodecyl sulfate and silica nanoparticles were used as ionic surfactant and nanoparticles in our experiments, respectively. AEROSIL® 816 and AEROSIL® 200 are hydrophobic and hydrophilic nanoparticles. To determine the adsorption loss of the surfactant onto rock samples, a conductivity approach was used. Real carbonate rock samples were used as the solid phase in adsorption experiments. It should be noted that the rock samples were water wet. This paper describes how equilibrium adsorption was investigated by examining adsorption behavior in a system of carbonate sample (solid phase and surfactant solution (aqueous phase. The initial surfactant and nanoparticle concentrations were 500–5000 and 500–2000 ppm, respectively. The rate of surfactant losses was extremely dependent on the concentration of the surfactant in the system, and the adsorption of the surfactant decreased with an increase in the nanoparticle concentration. Also, the hydrophilic nanoparticles are more effective than the hydrophobic nanoparticles.

  14. Radiocarbon dating of prehistoric rock paintings by selective oxidation of organic carbon

    Energy Technology Data Exchange (ETDEWEB)

    Russ, J.; Hyman, M.; Shafer, H.J.; Rowe, M.W. (Texas A and M Univ., College Station, TX (USA))

    1990-12-27

    Dating of prehistoric rock paintings (pictographs) has traditionally relied on indirect evidence. This includes inferences based on the archaeological context, such as superpositions of pictorial styles and the depiction of images that constrain their ages, as well as dating of deposits that either cover the art in situ or contain separated fragments of the painted surface. Migration of ions between the bulk rock and the natural coatings that form on a newly exposed surface has also been exploited to date petroglyphs (rock carvings) in desert regions. Until recently, however, direct dating (by radiocarbon techniques) of pictographs has not been possible, mainly because of the problem of separating inorganic carbon from the organic material in the pigments. Here we report on a new technique which allows this separation to be effected by using a low-temperature, low-pressure oxygen plasma to oxidize selectively the organic component; this may then be analysed using standard {sup 14}C methods. We have applied this technique to a portion of a pictograph from the Lower Pecos region of southwest Texas. The date obtained, 3,865{plus minus}100 yr BP (before present) is consistent with that expected on the basis of archaeological inference. As organic carbon is a ubiquitous component of pictograph paints, this technique should be applicable to rock paintings throughout the world. (author).

  15. Bonding preference of carbon, nitrogen, and oxygen in niobium-based rock-salt structures.

    Science.gov (United States)

    Miura, Akira; Takei, Takahiro; Kumada, Nobuhiro; Wada, Satoshi; Magome, Eisuke; Moriyoshi, Chikako; Kuroiwa, Yoshihiro

    2013-09-03

    Carbon, nitrogen, and oxygen are essential components in solid-state materials. However, understanding their preference on the bonding to metals has not been straightforward. Here, niobium carbide, nitride, and oxide with simple rock-salt-based structures were analyzed by first-principles calculations and synchrotron X-ray diffraction. We found that an increase in the atomic number from carbon to oxygen formed fewer and shorter bonds to metals with better hybridization of atomic orbitals. This can provide a simple guiding principle for understanding the bonding and designing carbides, nitrides, oxides, and mixed-anion compounds.

  16. The fate of carbon and CO2 - fluid-rock interaction during subduction metamorphism of serpentinites

    Science.gov (United States)

    Menzel, Manuel D.; Garrido, Carlos J.; López Sánchez-Vizcaíno, Vicente; Marchesi, Claudio; Hidas, Károly

    2016-04-01

    Given to its large relevance for present and past climate studies, the deep carbon cycle received increasing attention recently. However, there are still many open questions concerning total mass fluxes and transport processes between the different carbon reservoirs in the Earth's interior. One key issue is the carbon transfer from the subducting slab into fluids and rocks in the slab and mantle wedge. This transfer is controlled by the amount and speciation of stable carbon-bearing phases, which have a strong impact on the pH, redox conditions and trace-element budget of slab fluids. As recent experiments and thermodynamic modeling have shown, water released from dehydrating serpentinites has a great potential to produce CO2-enriched slab fluids by dissolution of carbonate minerals. To constrain the fate of carbon and CO2-fluid-rock interactions during subduction metamorphism of serpentinites, we have studied carbonate-bearing serpentinites recording different prograde evolutions from antigorite schists to Chl-harzburgites in high-P massifs of the Nevado-Filabride Complex (Betic Cordillera, S. Spain). Our results indicate that dissolution of dolomite in marbles in contact with dehydrating serpentinites is spatially limited during prograde metamorphism of carbonate-bearing serpentinites, but it can lead to the formation of silicate-rich zones in marbles close to the contacts. In lower grade serpentinite massifs (1.0-1.5 GPa / 550 °C), the presence of marble lenses in contact with antigorite schists appears to promote local dehydration of serpentinite coupled with carbonation of antigorite, forming Cpx-Tr-Chl-bearing high grade ophicarbonate zones. At the Cerro del Almirez ultramafic massif, where a dehydration front from antigorite-serpentinite to prograde Chl-harzburgite is preserved (1.9 GPa / 680 °C), a significant amount of carbon is retained in prograde Chl-harzburgites and Tr-Dol-marble lenses. This observation is at odds with thermodynamic models that

  17. Digital Rock Physics: Mechanical Properties of Carbonate Core Plug at Different Resolutions

    Science.gov (United States)

    Faisal, T. F.; Jouini, M. S.; Islam, A.; Chevalier, S.; Jouiad, M.; Sassi, M.

    2014-12-01

    Digital Rock Physics (DRP) is a novel technology that could be used to generate accurate, fast and cost effective special core analysis (SCAL) properties to support reservoir characterization and simulation tools. For this work, Micro-CT images at different resolutions have been used to run simulations to determine elastic properties like bulk, shear, Young's Modulus and Poisson's ratio of a dry carbonate core plug from Abu Dhabi reservoirs. Pre processing and segmentation of raw images is performed in FEI 3D visualization and analysis tool Avizo. Carbonates are characterized by a very complex pore-space structure and so a high degree of heterogeneity. Abaqus that is based on Finite Element Method is used to run 2D and 3D elastic simulations. Results will be compared by simulating the same core-plug in an alternative segmentation and FEM modeling environment used previously by Jouini & Vega et al. 2012 [1]. Acoustic wave propagation experiments at different confining pressures are performed in the laboratory Triaxial machine to determine the dynamic Young's modulus and Poisson's ratio for the same core plug. Expeirmental results are compared with numerical results. [1] Jouini, M.S. and Vega, S. 2012. Simulation of carbonate rocks elastic properties using 3D X-Ray computed tomography images based on Discrete Element Method and Finite Element Method. 46th US Rock Mechanics / Geomechanics Symposium, Chicago, Il, USA, 24-27 June 2012.

  18. Effect of pore structure on seismic rock-physics characteristics of dense carbonates

    Institute of Scientific and Technical Information of China (English)

    Pan Jian-Guo; Wang Hong-Bin; Li Chuang; Zhao Jian-Guo

    2015-01-01

    The Ordovician carbonate rocks of the Yingshan formation in the Tarim Basin have a complex pore structure owing to diagenetic and secondary structures. Seismic elastic parameters (e.g., wave velocity) depend on porosity and pore structure. We estimated the average specific surface, average pore-throat radius, pore roundness, and average aspect ratio of carbonate rocks from the Tazhong area. High P-wave velocity samples have small average specific surface, small average pore-throat radius, and large average aspect ratio. Differences in the pore structure of dense carbonate samples lead to fluid-related velocity variability. However, the relation between velocity dispersion and average specifi c surface, or the average aspect ratio, is not linear. For large or small average specifi c surface, the pore structure of the rock samples becomes uniform, which weakens squirtfl ow and minimizes the residuals of ultrasonic data and predictions with the Gassmann equation. When rigid dissolved (casting mold) pores coexist with less rigid microcracks, there are significant P-wave velocity differences between measurements and predictions.

  19. Retention of Metasedimentary Carbon during Subduction through Forearcs: Evidence from HP/UHP Rocks

    Science.gov (United States)

    Bebout, G. E.; Anderson, L. D.; Agard, P.; Bastoni, C.; Sills, G.; McCall, A. M.

    2010-12-01

    Knowledge of the degrees of retention or loss of C during trench-to-subarc metamorphism of subducting sediments (and altered oceanic crust) is critical in any model of deep-Earth C cycling. Existing theoretical analyses of subduction-zone decarbonation indicate little decarbonation of more pure metacarbonates to great depths in relatively cool margins unless subducting sediments are fluxed by H2O-rich fluids introduced from an external source. Western Alps metasedimentary rocks in the Schistes Lustres (SL) and at Lago di Cignana (CIG) allow assessment of extents of prograde devolatilization along prograde P-T paths similar to those experienced in most modern convergent margins. These suites represent a wide range of peak P-T (350-625°C; 1.5-2.9 GPa), in the same structural nappe, and contain pelitic and impure carbonate lithologies interlayered at cm to km scales. Integrated petrologic-geochemical study of the metapelites has documented minimal dehydration and surprising retention of particularly fluid-mobile trace elements such as B, Cs, and N in even the CIG rocks representing subduction to ~90 km depths [1, this study]. Schistes Lustres metacarbonates (20-90 wt% carbonate) are remarkably devoid of calc-silicate phases, indicating little decarbonation, and carbonate δ13CVPDB in these rocks is accordingly uniform across grade (mostly between -1.5 and +1‰, values typical of oceanic carbonates). CIG marble layers containing minor amounts of garnet, clinozoisite, and titanite have similar carbonate δ13C. In metapelitic rocks, carbonaceous matter (full range 0.04-0.3 wt%; 0.04-0.1 wt% for CIG) shows subtle increase in δ13C from values typical of marine organic matter (-26 to -22‰) in low-grade SL to higher values approaching -16‰ in the highest-grade SL and at CIG. Metapelite C/N shows no significant change across grade, with values typical of seafloor sediments (2-10). δ15Nair is relatively uniform across grade (+2.5 to +5‰), but values for CIG at the

  20. Inorganic carbon cycle in soil-rock-groundwater system in karst and fissured aquifers

    Directory of Open Access Journals (Sweden)

    Ajda Koceli

    2013-12-01

    Full Text Available The paper presents a systematic analysis of the isotopic composition of carbon (δ13CCaCO3 in carbonate rocks in central Slovenia, representing karst and fissured aquifers, and share of carbon contributions from carbonate dissolution and degradation of organic matter in aquifers, calculated from the mass balance equation. 59 samples of rocks (mainly dolomites from Upper Permian to Upper Triassic age were analyzed. Samples of carbonate rocks were pulverized and ground to fraction of 45 μm and for determination of δ13CCaCO3 analyzed with mass spectrometer for analyses of stable isotopes of light elements-IRMS. The same method was used for determination of isotopic composition of dissolved inorganic carbon (δ13CDIC in groundwater for 54 of 59 locations. Values of δ13CCaCO3 are in the range from -2.0 ‰ to +4.1 ‰, with an average δ13CCaCO3 value of +2.2 ‰. These values are typical for marine carbonates with δ13CCaCO3 around 0 ‰, although δ13CCaCO3 values differ between groups depending on the origin and age. Early diagenetic dolomites have relatively higher values of δ13CCaCO3 compared to other analyzed samples. The lowest values of δ13CCaCO3 were observed in Cordevolian and Bača dolomite, probably due to late diagenesis, during which meteoric water with lower isotopic carbon composition circulated in the process of sedimentation. Values of δ13CDIC range from -14.6 ‰ to -8.2 ‰. Higher δ13CDIC values (-8.2 ‰ indicate a low proportion of soil CO2 in the aquifer and rapid infiltration, while lower values (-14.6 ‰ indicate higher proportion of soil CO2 in the aquifer and slower infiltration. Calculated contributions of carbon from organic matter / dissolution of carbonates in the karstic and fissured aquifers s how a similar proportion (50 % : 50 %.

  1. Role of Carbonic Anhydrase as an Activator in Carbonate Rock Dissolution and Its Implication for Atmospheric CO2 Sink

    Institute of Scientific and Technical Information of China (English)

    刘再华

    2001-01-01

    The conversion of CO2 into H+ and is a relatively slow reaction. Hence, its kinetics may be rate determining in carbonate rock dissolution. Carbonic anhydrase (CA), which is widespread in nature, was used to catalyze the CO2 conversion process in dissolution experiments of limestone and dolomite. It was found that the rate of dissolution increases by a factor of about 10 after the addition of CA at a high CO2 partial pressure (Pco2) for limestone and about 3 at low Pco2 for dolomite. This shows that reappraisal is necessary for the importance of chemical weathering (including carbonate rock dissolution and silicate weathering) in the atmospheric CO2 sink and the mysterious missing sink in carbon cycling. It is doubtless that previous studies of weathering underestimated weathering rates due to the ignorance of CA as an activator in weathering, thus the contribution of weathering to the atmospheric CO2 sink is also underestimated. This finding also shows the need to examine the situ distribution and activity of CA in different waters and to investigate the role of CA in weathering.``

  2. Estimation of compressional seismic wave attenuation of carbonate rocks in Abu Dhabi, United Arab Emirates

    Science.gov (United States)

    Bouchaala, Fateh; Ali, Mohammed Y.; Farid, Asam

    2014-07-01

    The subsurface geology of Abu Dhabi in the United Arab Emirates is primarily composed of carbonate rocks. Such media are known to be highly heterogeneous. Very few studies have attempted to estimate attenuation in carbonate rocks. In Abu Dhabi no attenuation profile has been published. This study provides the first seismic wave attenuation profiles in Abu Dhabi using dense array of VSP data. We estimated three attenuation profiles: the apparent, the scattering, and the intrinsic attenuations. The apparent attenuation profile was computed using amplitude decay and spectral-ratio methods. The scattering attenuation profile was estimated using a generalized reflection-transmission matrix forward model. It is usually estimated from the sonic log, but to be more consistent with the apparent attenuation, we succeeded in this paper to estimate it from the VSP data. We subtracted the scattering attenuation from the apparent attenuation to deduce the intrinsic attenuation. The results of the study indicate that the scattering attenuation is significant compared to the published studies that are mainly based on clastic rocks. The high scattering attenuation can reach up to 0.02. It can be explained by the strong heterogeneity of the carbonate rocks. This study demonstrates that the Simsima and Rus Formations have considerable scattering and intrinsic attenuations. These formations are considered aquifers in Abu Dhabi; we therefore interpreted this high intrinsic attenuation zones to be due to the heterogeneity and to the fluids contained in these formations. The Umm-Er-Radhuma Formation is a more homogenous formation with limited aquifer potential. Hence, scattering and intrinsic attenuations of the Umm-Er-Radhuma Formation are low.

  3. Fracture Dissolution of Carbonate Rock: An Innovative Process for Gas Storage

    Energy Technology Data Exchange (ETDEWEB)

    James W. Castle; Ronald W. Falta; David Bruce; Larry Murdoch; Scott E. Brame; Donald Brooks

    2006-10-31

    The goal of the project is to develop and assess the feasibility and economic viability of an innovative concept that may lead to commercialization of new gas-storage capacity near major markets. The investigation involves a new approach to developing underground gas storage in carbonate rock, which is present near major markets in many areas of the United States. Because of the lack of conventional gas storage and the projected growth in demand for storage capacity, many of these areas are likely to experience shortfalls in gas deliverability. Since depleted gas reservoirs and salt formations are nearly non-existent in many areas, alternatives to conventional methods of gas storage are required. The need for improved methods of gas storage, particularly for ways to meet peak demand, is increasing. Gas-market conditions are driving the need for higher deliverability and more flexibility in injection/withdrawal cycling. In order to meet these needs, the project involves an innovative approach to developing underground storage capacity by creating caverns in carbonate rock formations by acid dissolution. The basic concept of the acid-dissolution method is to drill to depth, fracture the carbonate rock layer as needed, and then create a cavern using an aqueous acid to dissolve the carbonate rock. Assessing feasibility of the acid-dissolution method included a regional geologic investigation. Data were compiled and analyzed from carbonate formations in six states: Indiana, Ohio, Kentucky, West Virginia, Pennsylvania, and New York. To analyze the requirements for creating storage volume, the following aspects of the dissolution process were examined: weight and volume of rock to be dissolved; gas storage pressure, temperature, and volume at depth; rock solubility; and acid costs. Hydrochloric acid was determined to be the best acid to use because of low cost, high acid solubility, fast reaction rates with carbonate rock, and highly soluble products (calcium chloride

  4. Rock physics modeling of heterogeneous carbonate reservoirs:porosity estimation and hydrocarbon detection

    Institute of Scientific and Technical Information of China (English)

    Yu Hao; Ba Jing; Carcione Jose; Li Jin-Song; Tang Gang; Zhang Xing-Yang; He Xin-Zhen; Ouyang Hua

    2014-01-01

    In heterogeneous natural gas reservoirs, gas is generally present as small patch-like pockets embedded in the water-saturated host matrix. This type of heterogeneity, also called“patchy saturation”, causes significant seismic velocity dispersion and attenuation. To establish the relation between seismic response and type of fluids, we designed a rock physics model for carbonates. First, we performed CT scanning and analysis of the fluid distribution in the partially saturated rocks. Then, we predicted the quantitative relation between the wave response at different frequency ranges and the basic lithological properties and pore fluids. A rock physics template was constructed based on thin section analysis of pore structures and seismic inversion. This approach was applied to the limestone gas reservoirs of the right bank block of the Amu Darya River. Based on poststack wave impedance and prestack elastic parameter inversions, the seismic data were used to estimate rock porosity and gas saturation. The model results were in good agreement with the production regime of the wells.

  5. Source rock potential of the organic rich Turonian - Upper Campanian carbonates of northern Lebanon

    Energy Technology Data Exchange (ETDEWEB)

    Daher, S. Bou; Littke, R. [RWTH Aachen Univ. (Germany). Energy and Mineral Resources Group (EMR); Nader, F.H. [IFP Energies nouvelles, Paris (France). Dept. of Sedimentology-Stratigraphy

    2013-08-01

    Upper Cretaceous chalks, marls, and shales are arguably the most prolific petroleum source rocks in the eastern Mediterranean region. 209 core samples from the Turonian - Upper Campanian rock succession in north Lebanon were collected and analyzed for their organic matter (OM) content, quality, and maturity. The total organic carbon (TOC) measurements revealed a very good source rock potential for a 150 m interval within the Upper Santonian - Upper Campanian, with an average of 2% TOC. High HI values (average 707 mg/g TOC) characterize these source rocks as type I kerogen and reflect a very good preservation of the organic matter. T{sub max} values (average 421 C) match the other maturity parameters such as vitrinite reflectance (average 0.35%), and all point towards immature organic matter. The equivalent Upper Cretaceous in the offshore Levant basin has enough overburden to have reached maturity. However, the accurate extrapolation of the organic matter quality and quantity to the offshore is yet a challenge with the data at hand. (orig.)

  6. Petrophysical Clasification of Different Rocks in Carbonate Reservoirs of the Northern Cuban Heavy Oil Belt

    Directory of Open Access Journals (Sweden)

    Odalys Reyes Paredes

    2014-09-01

    Full Text Available The permeability is one of the main parameters to classify the porosity environment, this parametercan't be measured by log's tools, and it has no direct relation with the total porosity. It is closely relatedto the kind of rock (size and distribution of particles. In the Northern Cuban Heavy Oil Belt (FNCPC,the reservoirs are made up of carbonate rocks (mudstone / wackestone, with fracture porosity andother types of porosity such as: joins of dissolution and estilolitos formed from diagenetic processes.The different formations frequently show heterogeneities that can be noticeable hindering their owncharacterization. The cores present a very poor recuperation and on numerous occasions recoveringonly intervals that don't contribute anything to the flow of fluids. The analysis about different kinds ofrocks is done in this article; it is conceived throughout data of cores and thin sections. The petrophysicalclassification of different kinds of rocks for carbonate reservoirs are established from the porosity andpermeability relationships and porosity environment structure.

  7. Petrophysical studies of north American carbonate rock samples and evaluation of pore-volume compressibility models

    Science.gov (United States)

    da Silva, Gilberto Peixoto; Franco, Daniel R.; Stael, Giovanni C.; da Costa de Oliveira Lima, Maira; Sant'Anna Martins, Ricardo; de Moraes França, Olívia; Azeredo, Rodrigo B. V.

    2015-12-01

    In this work, we evaluate two pore volume compressibility models that are currently discussed in the literature (Horne, 1990; Jalalh, 2006b). Five groups of carbonate rock samples from the three following sedimentary basins in North America that are known for their association with hydrocarbon deposits were selected for this study: (i) the Guelph Formation of the Michigan Basin (Middle Silurian); (ii) the Edwards Formation of the Central Texas Platform (Middle Cretaceous); and (iii) the Burlington-Keokuk Formation of the Mississippian System (Lower Mississippian). In addition to the evaluation of the compressibility model, a petrophysical evaluation of these rock samples was conducted. Additional characterizations, such as grain density, the effective porosity, absolute grain permeability, thin section petrography, MICP and NMR, were performed to complement constant pore-pressure compressibility tests. Although both models presented an overall good representation of the compressibility behavior of the studied carbonate rocks, even when considering their broad porosity range (~ 2-38%), the model proposed by Jalalh (2006b) performed better with a confidence level of 95% and a prediction interval of 68%.

  8. Estimating permeability of carbonate rocks from porosity and v(p)/v(s)

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Baechle, G.; Eberli, G.P.

    2007-01-01

    We present a method for predicting permeability from sonic and density data. The method removes the porosity effect on the ratio upsilon(p)/upsilon(s), of dry rock, and it addresses the specific surface as an indirect measure of permeability. We look at ultrasonic data, porosity......, and the permeability of 114 carbonate core plugs. In doing so, we establish an empirical relationship between the specific surface of the solid phase (as calculated by Kozeny's equation) and upsilon(p)/upsilon(s) (linearly transformed to remove the porosity effect). One must view the specific surface derived by using...... settings. We find a reasonable match between predicted and measured permeability. The match is better for samples with carbonate mud-filled depositional textures than for carbonate mud-poor depositional textures. Diagenetic factors such as vuggy porosity decrease the predictability of permeability....

  9. Syn- and postkinematic cement textures in fractured carbonate rocks: Insights from advanced cathodoluminescence imaging

    Science.gov (United States)

    Ukar, Estibalitz; Laubach, Stephen E.

    2016-10-01

    In calcite and dolomite deposits in fractures, transmitted light and optical cathodoluminescence methods detect crack-seal texture in some fractures, but scanning electron microscope-based cathodoluminescence (SEM-CL) combined with secondary-electron images and element maps, reveals crack-seal and cement growth textures where previous SEM-CL imaging methods found massive or featureless deposits. In a range of fractured carbonate rocks, patterns and textures of calcite and dolomite cements precipitated during and after fracture growth resemble complex accumulation patterns found in quartz in sandstone fractures, suggesting that some apparent differences between carbonate mineral and quartz deposits in fractures reflect the limits of previous imaging methods. Advances in delineating textures in widespread carbonate mineral deposits in fractures provide evidence for growth and occlusion of fracture porosity.

  10. Alteration of the Carbon and Nitrogen Isotopic Composition in the Martian Surface Rocks Due to Cosmic Ray Exposure

    Science.gov (United States)

    Pavlov, A. A.; Pavlov, A. K.; Ostryakov, V. M.; Vasilyev, G. I.; Mahaffy, P.; Steele, A.

    2014-01-01

    C-13/C-12 and N-15/N-14 isotopic ratios are pivotal for our understanding of the Martian carbon cycle, history of the Martian atmospheric escape, and origin of the organic compounds on Mars. Here we demonstrate that the carbon and nitrogen isotopic composition of the surface rocks on Mars can be significantly altered by the continuous exposure of Martian surface to cosmic rays. Cosmic rays can effectively produce C-13 and N-15 isotopes via spallation nuclear reactions on oxygen atoms in various Martian rocks. We calculate that in the top meter of the Martian rocks, the rates of production of both C-13 and N-15 due to galactic cosmic rays (GCRs) exposure can vary within 1.5-6 atoms/cm3/s depending on rocks' depth and chemical composition. We also find that the average solar cosmic rays can produce carbon and nitrogen isotopes at a rate comparable to GCRs in the top 5-10 cm of the Martian rocks. We demonstrate that if the total carbon content in a surface Martian rock is rocks with relatively short exposure ages (e.g., 100 million years), cosmogenic changes in N-15/N-14 ratio are still very significant. We also show that a short exposure to cosmic rays of Allan Hills 84001 while on Mars can explain its high-temperature heavy nitrogen isotopic composition (N-15/N-14). Applications to Martian meteorites and the current Mars Science Laboratory mission are discussed.

  11. Carbon isotopic characteristics of hydrocarbon gases from coal-measure source rocks--A thermal simulation experiment

    Institute of Scientific and Technical Information of China (English)

    ZHENG Jianjing; HU Huifang; SUN Guoqiang; JI Limin

    2006-01-01

    Gaseous hydrocarbon geochemistry research through a thermal simulation experiment in combination with the natural evolution process in which natural gases were formed from coal-measure source rocks revealed that the δ13C1 values of methane vary from light to heavy along with the increase of thermal evolution degree of coal-measure source rocks, and the δ13C2 values of ethane range from -28.3‰ to -20‰ (PDB). δ13C2 value was -28‰± ( Ro= 0.45% - 0.65%) at the lower thermal evolution stage of coal-measure source rocks. After the rocks entered the main hydrocarbon-generating stage (Ro=0.65% - 1.50%), δ13C2 values generally varied within the range of -26‰ - -23‰±; with further thermal evolution of the rocks the carbon isotopes of ethane became heavier and heavier, but generally less than - 20‰.The partial carbon isotope sequence inversion of hydrogen gases is a characteristic feature of mixing of natural gases of different origins. Under the condition of specially designated type of organic matter, hydrogen source rocks may show this phenomenon via their own evolution.In the lower evolution stages of the rocks, it is mainly determined by organic precursors that gaseous hydrocarbons display partial inversion of the carbon isotope sequence and the carbon isotopic values of ethane are relatively low. These characteristic features also are related to the geochemical composition of primary soluble organic matter.

  12. Coesite-Diamond Assemblage in Ultrahigh Pressure Crustal and Mantle rocks: Evidence for Carbon Recycling

    Science.gov (United States)

    Sobolev, N. V.

    2010-12-01

    press, Contr. Min. Petr.). This extensive wide range in δ13C (PDB) for coesite-bearing diamonds, from -28 to +1.5 ‰, along with common crustal δ18O (SMOW) values from the principal rock-forming minerals (garnet and clinopyroxene) and accessory mineral (coesite), is typical for diamondiferous mantle eclogites, crustal UHPM rocks, and DIs. The petrogenetic evidences from all these rocks and minerals are indicative of major subduction of crustal protoliths (Ringwood, 1972, EPSL, 14:233), including the recycling of crustal carbon into diamonds in mantle eclogites, first speculated on by V.S. Sobolev and N.V. Sobolev (1980, Dokl. Akad. Nauk SSSR, 249: 1217).

  13. Fission Track Dating of Authigenic Quartz in Red Weathering Crusts of Carbonate Rocks in Guizhou Province

    Institute of Scientific and Technical Information of China (English)

    LIU Xiuming; WANG Shijie; ZHANG Feng

    2004-01-01

    The Cenozoic evolution history of Guizhou Province, which is located on the southeastem flank of the Qinghai-Tibet Plateau, is unclear because of the lack of sedimentation records. The red weathering crusts widespread on the Yunnan-Guizhou Plateau may bear critical information about their evolution history. This work firstly determined the ages of four red weathering crusts in eastern, central and northern Guizhou. The material used in fission track dating is well-crystallized quartz occurring in many in-situ weathering crusts of carbonate rocks. The results showed that the fission track ages of quartz vary over a wide range from 1 to 25 Ma in the four profiles, significantly younger than the ages of the Triassic and Cambrian parent rocks. In combination with the evolution history of the regional geology during the period from 25 to 1 Ma, the ages of quartz can exclude the possibility that the origin of quartz has nothing to do with primary clastic minerals in parent rocks, authigenesis during diagenesis and hydrothermal precipitation or replacement by volcanic activities. It is deduced that the well-crystallized quartz was precipitated from Si-rich weathering fluids during the weathering process of carbonate rocks. The recorded ages of quartz from the four profiles are consistent with the episodes of the planation surfaces on the Qinghai-Tibet Plateau, the forming stages of red soil in the tropics of South China, the tectonically stable periods in Guizhou, and the ages of weathering in other parts of the world during the Cenozoic era. That is to say, the ages of authigenic quartz dated by the fission track method are well feasible and credible.

  14. Enhanced Oil Recovery from Oil-wet Carbonate Rock by Spontaneous Imbibition of Aqueous Surfactant Solutions

    Energy Technology Data Exchange (ETDEWEB)

    Standnes, Dag Chun

    2001-09-01

    The main theme of this thesis is an experimental investigation of spontaneous imbibition (SI) of aqueous cationic surfactant solution into oil-wet carbonate (chalk- and dolomite cores). The static imbibition process is believed to represent the matrix flow of oil and water in a fractured reservoir. It was known that aqueous solution of C{sub 12}-N(CH{sub 3}){sub 3}Br (C12TAB) was able to imbibe spontaneously into nearly oil-wet chalk material, but the underlying mechanism was not understood. The present work was therefore initiated, with the following objectives: (1) Put forward a hypothesis for the chemical mechanism underlying the SI of C12TAB solutions into oil-wet chalk material based on experimental data and (2) Perform screening tests of low-cost commercially available surfactants for their ability to displace oil by SI of water into oil-wet carbonate rock material. It is essential for optimal use of the surfactant in field application to have detailed knowledge about the mechanism underlying the SI process. The thesis also discusses some preliminary experimental results and suggests mechanisms for enhanced oil recovery from oil-wet carbonate rock induced by supply of thermal energy.

  15. Study on the restitution coefficient of original total organic carbon for high mature marine source rocks

    Institute of Scientific and Technical Information of China (English)

    QIN Jianzhong; ZHENG Longju; Tenger

    2007-01-01

    On the basis of the results of hydropyrolysis simulations for about 90 different types of immature to mature source rocks selected from about 5 000 marine source rocks in China,along with the natural thermal evolution profiles,the following conclusions were obtained.(1) Total organic carbon (TOC) content of excellent marine source rocks does not change obviously when Ro<0.8% or Ro > 1.3%,and the residual TOC content is decreasing gradually with the maturity increase at 0.8% <Ro< 1.3%.(2) At the high-post mature stage (Ro > 1.3%),the decreased maximums of residual TOC content for the kerogen of sapropel (Ⅰ),Ⅱ1,and Ⅱ are usually 40%,32% and 24%,respectively,and their TOC restitution coefficient is,respectively,1.68,1.48 and 1.32.(3)Both the TOC decreasing amplitude and the restitution coefficient decrease gradually with the decrease of TOC content for the source rocks with low organic matter abundance (usually 0.3% < TOC < 1.0%).The TOC restitution coefficients are,respectively,1.20 and 1.0,when 0.3%<TOC<0.5% and TOC < 0.3%.(4) TOCres.of solid bitumen and shale with high organic matter abundance (TOC > 30%) also require no restitution at the high mature stage.Such kind of TOC restitution is further supported by the coincidence of the decrease of residual TOC with the decreasing of S1 + S2 and the increasing of hydrocarbon quantity during the experimental simulation of hydrocarbon generation and expulsion for marine source rocks (0.3%<TOC&<30%) in natural thermal evolution profiles.

  16. In-situ analysis of strain localization related to structural heterogeneities of carbonate rocks

    Directory of Open Access Journals (Sweden)

    Dimanov A.

    2010-06-01

    Full Text Available The technique of Digital Image Correlation (DIC has been applied to study the deformation of porous carbonate rocks subjected to uniaxial compression tests. The tests have been performed at two different scales: on cylinders of 10 cm high compressed with a standard press with digital images recorded by optical microscopy at a global and local scale and on smaller parallelepiped samples deformed inside a scanning electron microscope (SEM. The development of localization at different scales is thus recorded as well as the damage and compaction mechanisms in relation with the microstructural heterogeneities.

  17. Rock Outcrops Redistribute Organic Carbon and Nutrients to Nearby Soil Patches in Three Karst Ecosystems in SW China.

    Science.gov (United States)

    Wang, Dianjie; Shen, Youxin; Li, Yuhui; Huang, Jin

    2016-01-01

    Emergent rock outcrops are common in terrestrial ecosystems. However, little research has been conducted regarding their surface function in redistributing organic carbon and nutrient fluxes to soils nearby. Water that fell on and ran off 10 individual rock outcrops was collected in three 100 × 100 m plots within a rock desertification ecosystem, an anthropogenic forest ecosystem, and a secondary forest ecosystem between June 2013 and June 2014 in Shilin, SW China. The concentrations of total organic carbon (TOC), total nitrogen (N), total phosphorus (P), and potassium (K) in the water samples were determined during three seasons, and the total amounts received by and flowing out from the outcrops were calculated. In all three ecosystems, TOC and N, P, and K were found throughout the year in both the water received by and delivered to nearby soil patches. Their concentrations and amounts were generally greater in forested ecosystems than in the rock desertification ecosystem. When rock outcrops constituted a high percentage (≥ 30%) of the ground surface, the annual export of rock outcrop runoff contributed a large amount of organic carbon and N, P, and K nutrients to soil patches nearby by comparison to the amount soil patches received via atmospheric deposition. These contributions may increase the spatial heterogeneity of soil fertility within patches, as rock outcrops of different sizes, morphologies, and emergence ratios may surround each soil patch.

  18. Textural identification of carbonate rocks by image processing and neural network: Methodology proposal and examples

    Science.gov (United States)

    Marmo, Roberto; Amodio, Sabrina; Tagliaferri, Roberto; Ferreri, Vittoria; Longo, Giuseppe

    2005-06-01

    Using more than 1000 thin section photos of ancient (Phanerozoic) carbonates from different marine environments (pelagic to shallow-water) a new numerical methodology, based on digitized images of thin sections, is proposed here. In accordance with the Dunham classification, it allows the user to automatically identify carbonate textures unaffected by post-depositional modifications (recrystallization, dolomitization, meteoric dissolution and so on). The methodology uses, as input, 256 grey-tone digital image and by image processing gives, as output, a set of 23 values of numerical features measured on the whole image including the "white areas" (calcite cement). A multi-layer perceptron neural network takes as input this features and gives, as output, the estimated class. We used 532 images of thin sections to train the neural network, whereas to test the methodology we used 268 images taken from the same photo collection and 215 images from San Lorenzello carbonate sequence (Matese Mountains, southern Italy), Early Cretaceous in age. This technique has shown 93.3% and 93.5% of accuracy to classify automatically textures of carbonate rocks using digitized images on the 268 and 215 test sets, respectively. Therefore, the proposed methodology is a further promising application to the geosciences allowing carbonate textures of many thin sections to be identified in a rapid and accurate way. A MATLAB-based computer code has been developed for the processing and display of images.

  19. Alteration of the carbon and nitrogen isotopic composition in the Martian surface rocks due to cosmic ray exposure

    Science.gov (United States)

    Pavlov, A. A.; Pavlov, A. K.; Ostryakov, V. M.; Vasilyev, G. I.; Mahaffy, P.; Steele, A.

    2014-06-01

    13C/12C and 15N/14N isotopic ratios are pivotal for our understanding of the Martian carbon cycle, history of the Martian atmospheric escape, and origin of the organic compounds on Mars. Here we demonstrate that the carbon and nitrogen isotopic composition of the surface rocks on Mars can be significantly altered by the continuous exposure of Martian surface to cosmic rays. Cosmic rays can effectively produce 13C and 15N isotopes via spallation nuclear reactions on oxygen atoms in various Martian rocks. We calculate that in the top meter of the Martian rocks, the rates of production of both 13C and 15N due to galactic cosmic rays (GCRs) exposure can vary within 1.5-6 atoms/cm3/s depending on rocks' depth and chemical composition. We also find that the average solar cosmic rays can produce carbon and nitrogen isotopes at a rate comparable to GCRs in the top 5-10 cm of the Martian rocks. We demonstrate that if the total carbon content in a surface Martian rock is Mars can explain its high-temperature heavy nitrogen isotopic composition (15N/14N). Applications to Martian meteorites and the current Mars Science Laboratory mission are discussed.

  20. Geochemistry of arsenic in low sulfide-high carbonate coal waste rock, Elk Valley, British Columbia, Canada.

    Science.gov (United States)

    Biswas, Ashis; Hendry, M Jim; Essilfie-Dughan, Joseph

    2017-02-01

    This study investigated the geochemistry of arsenic (As) in low sulfide-high carbonate coal waste rock of the Elk Valley, British Columbia, Canada. Its abundance and mineralogical associations in waste rock of different placement periods were determined in addition to its mobilization into porewater and rock-drain effluent. The mean (5.34mg/kg; 95% confidence interval: 4.95-5.73mg/kg) As concentration in the waste rock was typical of sedimentary rock. Electron microprobe and As K-edge X-ray absorption near-edge spectroscopic analyses showed the As is predominantly associated with primary pyrites in both source and freshly blasted waste rock. However, in aged waste rock the As is associated with both primary pyrites and secondary Fe oxyhydroxides. Oxidation of pyrite in waste rock dumps was reflected by the presence of high concentrations of SO4(2-) in porewater and oxidation rims of Fe oxyhydroxides around pyrite grains. Acid released from pyrite oxidation to Fe oxyhydroxides is neutralized by carbonate mineral dissolution that buffers the pH in the waste rock to circumneutral values. Adsorption of As onto secondary Fe oxyhydroxides provides an internal geochemical control on As release during pyrite oxidation and porewater flushing from the dump, resulting in the low As concentrations observed in porewater (median: 9.91μg/L) and rock-drain effluent (median: 0.31μg/L). Secondary Fe oxyhydroxides act as a long-term sink for As under present day hydrologic settings in waste rock dumps in the Elk Valley.

  1. Wettability evaluation of a carbonate reservoir rock from core to pore level

    Energy Technology Data Exchange (ETDEWEB)

    Al-Yousef, H.Y.; Lichaa, P.M.; Al-Kaabi, A.U.; Alpustun, H.

    1995-10-01

    Wettability evaluation was performed during stags of as received, cleaned, and restored states on core samples form a Saudi Arabian carbonate reservoir. The wettability behavior from the chemistry of brine-oil-carbonate rock interaction was found to be neutral to slightly oil-wet. The pore-size distribution obtained from mercury injection data indicated that about 15--20 percent of the pore volume is not accessible to asphaltene particles in the crude oil. Therefore a mixed-wettability state can exist. These results were confirmed by the evaluation of the wettability of the cores using USBM and Amott techniques. The wettability at the pore level was studied using Cryo-Scanning Electron Microscopy. Rock samples were examined at irreducible water and residual oil saturations during cleaned and restored states. At irreducible water saturation, both oil and brine were present in the intergranular macroporosity and intragranular macropores and micropores. At residual oil saturation,oil was found in the form of isolated globules in the cleaned case. After aging, the oil is more loosely distributed in the porosity and generally contacts the pore walls. This indicates an evolution toward oil wetness with aging. These results are in agreement with the changes of wettability indices obtained using USBM technique.

  2. Effect of carbon substrates on rock phosphate solubilization by bacteria from composts and macrofauna.

    Science.gov (United States)

    Hameeda, B; Reddy, Y Harish Kumar; Rupela, O P; Kumar, G N; Reddy, Gopal

    2006-10-01

    Five of the 207 isolates from different composts, farm waste compost (FWC), rice straw compost (RSC), Gliricidia vermicompost (GVC), and macrofauna, showed rock phosphate (RP) solubilization in buffered medium in plate culture. When tested in RP broth medium, all five strains, Enterobacter cloacae EB 27, Serratia marcescens EB 67, Serratia sp. EB 75, Pseudomonas sp. CDB 35, and Pseudomonas sp. BWB 21, showed gluconic acid production and solubilized RP. Based on cellulose-degrading and P-solubilizing ability, two strains were selected for further studies. In the presence of different carbon sources, both strains showed a drop in pH and solubilized RP. P released was maximum with glucose (1212 and 522 micromol) and minimum with cellobiose (455 and 306 micromol) by S. marcescens EB 67 and Pseudomonas sp. CDB 35, respectively. Glucose dehydrogenase (GDH) activity was 63 and 77% with galactose and 35 and 46% with cellobiose when compared to glucose (100%) by EB 67 and CDB 35, respectively. Both strains solubilized RP in the presence of different crop residues. EB 67 and CDB 35 showed maximum cellulase activity (0.027 units) in the presence of rice straw and a mixture of rice straw and root. P solubilized from RP in the presence of pigeonpea root was 134 and 140 micromol with EB 67 and CDB 35. Significantly, these bacteria isolated from composts and macrofauna solubilized rock phosphate in the presence of various pure carbon substrates and crop residues and their importance in soil/rhizosphere conditions is discussed.

  3. Thermal simulation experiment on the hydrocarbon regeneration of marine carbonate source rock

    Institute of Scientific and Technical Information of China (English)

    LI HuiLi; JIN ZhiJun; HE ZhiLiang; QIN JianZhong; SHAO ZhiBing

    2007-01-01

    Hydrocarbon regeneration of marine carbonate source rock was simulated with thermal experiments in a laboratory. The results reveal that hydrocarbon regeneration does not simply continue the primary hydrocarbon generation process, and that, for marine carbonate source rock, discontinuous hydrocarbon generation differs greatly from the continuous generation. Several different features of hydrocarbon regeneration were observed in the experiments. First, the liquid hydrocarbon generation peak was always observed no matter what the initial maturity of the sample was. Moreover, the maturity and the liquid hydrocarbon yield corresponding to the peak varied with the sample's initial maturity. Second, the hydrocarbon regeneration started earlier than the continuous one. In the experiments, the hydrocarbon could be re-generated when the sample maturity did not rise to any great extent. Third, the accumulative hydrocarbon-generating quantity during discontinuous generation was always more than that during continuous generation. And the hydrocarbon-generating quantity varied with the discontinuous generation history. Chemical kinetic analysis suggests that discontinuous hydrocarbon generation should not only be explained by the parallel reaction mechanism but also by the consecutive reaction mechanism which has been ignored in the traditional chemical kinetic model for continuous hydrocarbon generation.

  4. Origin and role of fluids involved in the seismic cycle of extensional faults in carbonate rocks

    Science.gov (United States)

    Smeraglia, Luca; Berra, Fabrizio; Billi, Andrea; Boschi, Chiara; Carminati, Eugenio; Doglioni, Carlo

    2016-09-01

    We examine the potentially-seismic right-lateral transtensional-extensional Tre Monti Fault (central Apennines, Italy) with structural and geochemical methods and develop a conceptual evolutionary model of extensional faulting with fluid involvement in shallow (≤3 km depth) faults in carbonate rocks. In the analysed fault zone, multiscale fault rock structures include injection veins, fluidized ultracataclasite layers, and crackle breccias, suggesting that the fault slipped seismically. We reconstructed the relative chronology of these structures through cross-cutting relationship and cathodoluminescence analyses. We then used C- and O-isotope data from different generations of fault-related mineralizations to show a shift from connate (marine-derived) to meteoric fluid circulation during exhumation from 3 to ≤1 km depths and concurrent fluid cooling from ∼68 to hydrological system, where prevalently connate fluids circulated within the fault zone at temperatures between 60° and 75 °C. During fault zone exhumation, at depths ≤1 km and temperatures hydrological circulation became open and meteoric-derived fluids progressively infiltrated and circulated within the fault zone. The role of these fluids during syn-exhumation seismic cycles of the Tre Monti Fault has been substantially passive along the whole fault zone, the fluids being passively redistributed at hydrostatic pressure following co-seismic dilatancy. Only the principal fault has been characterized, locally and transiently, by fluid overpressures. The presence of low-permeability clayey layers in the sedimentary sequence contributed to control the type of fluids infiltrating into the fault zone and possibly their transient overpressures. These results can foster the comprehension of seismic faulting at shallow depths in carbonate rocks of other fold-thrust belts involved in post-collisional seismogenic extensional tectonics.

  5. Kinetic study of the hydrocarbon generation from marine carbonate source rocks characterization of products of gas and liquid hydrocarbon

    Institute of Scientific and Technical Information of China (English)

    GENG Xinhua; GENG Ansong; XIONG Yongqiang; LIU Jinzhong; ZHANG Haizu; ZHAO Qingfang

    2006-01-01

    The kinetic parameters of hydrocarbon generation from the marine carbonate source rocks were determined and calibrated through kinetic simulating experiment. The kinetic parameters of hydrocarbon generation then were extrapolated to geological condition by using the relative software.The result shows that gaseous hydrocarbons (C1, C2,C3, C4-5) were generated in condition of 150℃<T<220℃(1.0%<Ro <3.0% ). Light hydrocarbons (C6-13)and heavy hydrocarbons ( C13+) were generated in condition of 100 ℃<T<170 ℃ (0.5%<Ro<1.5%). A quantitative reference to examine the natural evolution of hydrocarbon of marine carbonate source rocks can be established through the results. It also provides a new method for evaluating the highly mature marine carbonate source rock more reasonably.

  6. Chromium Isotopes in Carbonate Rocks: New Insights into Proterozoic Atmospheric Oxygenation

    Science.gov (United States)

    Kah, L. C.; Gilleaudeau, G. J.; Frei, R.; Kaufman, A. J.; Azmy, K.; Bartley, J. K.; Chernyavskiy, P.; Knoll, A. H.

    2015-12-01

    There has been a long-standing debate in geobiology about the role that Earth's oxygenation played in the evolution of complex life. Temporal linkages exist between the Great Oxidation Event (GOE) and the evolution of eukaryotes, as well as Neoproterozoic rise in oxygen and the diversification of metazoans. Further advances have been hampered, however, by the lack of direct proxies that mark specific levels of atmospheric pO2 in the geologic past. Chromium (Cr) isotopes show promise in this regard because the oxidation of Cr during terrestrial weathering—which results in isotopic fractionation—is dependent on a specific threshold of atmospheric pO2 (0.1-1% of the present atmospheric level [PAL]). This threshold value broadly coincides with recent estimates of the oxygen requirements of early animals. Here we report new Cr-isotope data from four late Mesoproterozoic carbonate-dominated successions. Samples were collected from the Turukhansk Uplift (Siberia), the El Mreiti Group (Mauritania), the Vazante Group (Brazil), and the Angmaat Formation (Canada). We emphasize the application of Cr-isotopes to carbonate rocks because the broad temporal range of this lithology in the geologic record provides an opportunity to significantly expand our understanding of Proterozoic oxygenation on shorter time scales. Our data indicate that pO2 levels required to support early animals were attained long before Neoproterozoic metazoan diversification, although the large degree of isotopic heterogeneity in our dataset may indicate that pO2 > 0.1-1% PAL was only a transient phenomenon in the Mesoproterozoic. This study demonstrates the utility of Cr-isotopes as an atmospheric redox proxy in carbonate rocks and helps inform future avenues of research on Proterozoic pO2 thresholds.

  7. Planetary rover robotics experiment in education: carbonate rock collecting experiment of the Husar-5 rover

    Science.gov (United States)

    Szalay, Kristóf; Lang, Ágota; Horváth, Tamás; Prajczer, Péter; Bérczi, Szaniszló

    2013-04-01

    Introduction: The new experiment for the Husar-5 educational space probe rover consists of steps of the technology of procedure of finding carbonate speci-mens among the rocks on the field. 3 main steps were robotized: 1) identification of carbonate by acid test, 2) measuring the gases liberated by acid, and 3) magnetic test. Construction of the experiment: The basis of the robotic realization of the experiment is a romote-controlled rover which can move on the field. Onto this rover the mechanism of the experiments were built from Technics LEGO elements and we used LEGO-motors for making move these experiments. The operation was coordinated by an NXT-brick which was suitable to programming. Fort he acetic-test the drops should be passed to the selected area. Passing a drop to a locality: From the small holder of the acid using densified gas we pump some drop onto the selected rock. We promote this process by pumpig the atmospheric gas into another small gas-container, so we have another higher pressure gas there. This is pumped into the acid-holder. The effect of the reaction is observed by a wireless onboard camera In the next step we can identify the the liberated gas by the gas sensor. Using it we can confirm the liberation of the CO2 gas without outer observer. The third step is the controll of the paramagnetic properties.. In measuring this feature a LEGO-compass is our instrumentation. We use a electric current gener-ated magnet. During the measurements both the coil and the gas-sensor should be positioned to be near to the surface. This means, that a lowering and an uplifting machinery should be constructed. Summary: The sequence of the measurement is the following. 1) the camera - after giving panorama images - turns toward the soil surface, 2) the dropping onto the rock surface 3) at the same time the gas-sensor starts to move down above the rock 4) the compass sensor also moves down on the arm which holds both the gas-sensor and the compass-sensor 5

  8. Detailed Study of Seismic Wave Attenuation in Carbonate Rocks: Application on Abu Dhabi Oil Fields

    Science.gov (United States)

    Bouchaala, F.; Ali, M. Y.; Matsushima, J.

    2015-12-01

    Seismic wave attenuation is a promising attribute for the petroleum exploration, thanks to its high sensitivity to physical properties of subsurface. It can be used to enhance the seismic imaging and improve the geophysical interpretation which is crucial for reservoir characterization. However getting an accurate attenuation profile is not an easy task, this is due to complex mechanism of this parameter, although that many studies were carried out to understand it. The degree of difficulty increases for the media composed of carbonate rocks, known to be highly heterogeneous and with complex lithology. That is why few attenuation studies were done successfully in carbonate rocks. The main objectives of this study are, Getting an accurate and high resolution attenuation profiles from several oil fields. The resolution is very important target for us, because many reservoirs in Abu Dhabi oil fields are tight.Separation between different modes of wave attenuation (scattering and intrinsic attenuations).Correlation between the attenuation profiles and other logs (Porosity, resistivity, oil saturation…), in order to establish a relationship which can be used to detect the reservoir properties from the attenuation profiles.Comparison of attenuation estimated from VSP and sonic waveforms. Provide spatial distribution of attenuation in Abu Dhabi oil fields.To reach these objectives we implemented a robust processing flow and new methodology to estimate the attenuation from the downgoing waves of the compressional VSP data and waveforms acquired from several wells drilled in Abu Dhabi. The subsurface geology of this area is primarily composed of carbonate rocks and it is known to be highly fractured which complicates more the situation, then we separated successfully the intrinsic attenuation from the scattering. The results show that the scattering is significant and cannot be ignored. We found also a very interesting correlation between the attenuation profiles and the

  9. On the neutralization of acid rock drainage by carbonate and silicate minerals

    Science.gov (United States)

    Sherlock, E. J.; Lawrence, R. W.; Poulin, R.

    1995-02-01

    The net result of acid-generating and-neutralizing reactions within mining wastes is termed acid rock drainage (ARD). The oxidation of sulfide minerals is the major contributor to acid generation. Dissolution and alteration of various minerals can contribute to the neutralization of acid. Definitions of alkalinity, acidity, and buffer capacity are reviewed, and a detailed discussion of the dissolution and neutralizing capacity of carbonate and silicate minerals related to equilibium conditions, dissolution mechanism, and kinetics is provided. Factors that determine neutralization rate by carbonate and silicate minerals include: pH, PCO 2, equilibrium conditions, temperature, mineral composition and structure, redox conditions, and the presence of “foreign” ions. Similar factors affect sulfide oxidation. Comparison of rates shows sulfides react fastest, followed by carbonates and silicates. The differences in the reaction mechanisms and kinetics of neutralization have important implications in the prediction, control, and regulation of ARD. Current static and kinetic prediction methods upon which mine permitting, ARD control, and mine closure plans are based do not consider sample mineralogy or the kinetics of the acid-generating and-neutralizing reactions. Erroneous test interpretations and predictions can result. The importance of considering mineralogy for site-specific interpretation is highlighted. Uncertainty in prediction leads to difficulties for the mine operator in developing satisfactory and cost-effective control and remediation measures. Thus, the application of regulations and guidelines for waste management planning need to beflexible.

  10. Biological marker characteristics of oils and asphalts from carbonate source rocks in a rapidly subsiding graben, Dead Sea, Israel

    Science.gov (United States)

    Rullkötter, Jürgen; Spiro, Baruch; Nissenbaum, Arie

    1985-06-01

    A detailed GC/MS study of biological marker compounds in the saturated and aromatic hydrocarbon fractions of oils and asphalts from the Dead Sea area, Israel, provided decisive information to the solution of a long-lasting controversy by showing that the asphalts are products of early generation in an immature stage from the same type of carbonate source rock which generated more mature oils. The asphalts are not biodegraded residues of the oils. Oils from six different wells, and asphalts from wells, outcrops, and a floating block from the Dead Sea all have very similar sterane and triterpane patterns. They all lack rearranged steranes (diasteranes) indicating a carbonate source matrix and compare reasonably well with a sample of Upper Cretaceous bituminous chalk from Nebi Musa. The main difference between the oils and the asphalts is a significantly higher triaromatic to mono- plus triaromatic steroid hydrocarbon ratio in the former. This is explained as a result of rapid subsidence and heating of their source rock close to the deep parts of the Dead Sea graben. The oils thus were generated in the more deeply buried source rock blocks under the graben fill, whereas the asphalts either originate from an immature source rock section closer to the graben rims or represent an earlier phase of generation and expulsion. This study also provides general information on the evolution of biological markers in carbonate source rocks. Low-activation-energy processes, like isomerisation of steranes, appear to occur much faster at low temperatures than in shales. The high sulfur content and less cross-linking of the biogenic organic matter into a complex kerogen structure are suggested to be responsible for this. Care should be taken when using only sterane isomerisation to assess the maturity of hydrocarbons from carbonate rocks and of carbonate-derived oils.

  11. Chemical kinetics study of hydrocarbon regeneration from organic matter in carbonate source rocks and its significance

    Institute of Scientific and Technical Information of China (English)

    LU ShuangFang; ZHONG NingNing; XUE HaiTao; PAN ChangChun; LI JiJun; LI HongTao

    2007-01-01

    In the comparison research of hydrocarbon regeneration, a low maturity carbonate source rock is heated to different temperatures in a gold tube to obtain a series of samples with different maturities. Then, the heated samples, before and after extraction, are subjected to Rock-Eval pyrolysis through a thermal simulation of hydrocarbon regeneration in order to inspect pyrolysis characteristics and probe into the characteristics of the chemical kinetics of each sample. The results indicate that, whether hydrocarbon regeneration peak is delayed or advanced, the potential of hydrocarbon regeneration is closely related to the expulsion amount and breakdown maturity of primary hydrocarbon generation. After extraction, the average activation energy of artificially maturated samples increases with the in creasing maturity, but the chemical kinetic properties of un-extracted samples decrease. The calibrated chemical kinetic models that describe extracted and un-extracted samples are applied to the Bohai Bay and the Songliao Basin, and the results indicate that the combination of the two models can explain some contradictory conclusions previously reported. These results also facilitate the quantitative evaluation of the amount of hydrocarbon regeneration by the chemical kinetic method.

  12. Chemical kinetics study of hydrocarbon regeneration from organic matter in carbonate source rocks and its significance

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    In the comparison research of hydrocarbon regeneration, a low maturity carbonate source rock is heated to different temperatures in a gold tube to obtain a series of samples with different maturities. Then, the heated samples, before and after extraction, are subjected to Rock-Eval pyrolysis through a thermal simulation of hydrocarbon regeneration in order to inspect pyrolysis characteristics and probe into the characteristics of the chemical kinetics of each sample. The results indicate that, whether hy- drocarbon regeneration peak is delayed or advanced, the potential of hydrocarbon regeneration is closely related to the expulsion amount and breakdown maturity of primary hydrocarbon generation. After extraction, the average activation energy of artificially maturated samples increases with the in- creasing maturity, but the chemical kinetic properties of un-extracted samples decrease. The calibrated chemical kinetic models that describe extracted and un-extracted samples are applied to the Bohai Bay and the Songliao Basin, and the results indicate that the combination of the two models can explain some contradictory conclusions previously reported. These results also facilitate the quantitative evaluation of the amount of hydrocarbon regeneration by the chemical kinetic method.

  13. The determination of calcium in phosphate, carbonate, and silicate rocks by flame photometer

    Science.gov (United States)

    Kramer, Henry

    1956-01-01

    A method has been developed for the determination of calcium in phosphate, carbonate, and silicate rocks using the Beckman flame photometer, with photomultiplier attachement. The sample is dissolved in hydrofluoric, nitric, and perchloric acids, the hydrofluoric and nitric acids are expelled, a radiation buffer consisting of aluminum, magnesium, iron, sodium, potassium, phosphoric acid, and nitric acid is added, and the solution is atomized in an oxy-hydrogen flame with an instrument setting of 554 mµ. Measurements are made by comparison against calcium standards, prepared in the same manner, in the 0 to 50 ppm range. The suppression of calcium emission by aluminum and phosphate was overcome by the addition of a large excess of magnesium. This addition almost completely restores the standard curve obtained from a solution of calcium nitrate. Interference was noted when the iron concentration in the aspirated solution (including the iron from the buffer) exceeded 100 ppm iron. Other common rock-forming elements did not interfere. The results obtained by this procedure are within ± 2 percent of the calcium oxide values obtained by other methods in the range 1 to 95 percent calcium oxide. In the 0 to 1 percent calcium oxide range the method compares favorably with standard methods.

  14. Estimation of Physical Property Changes by Oil Saturation in Carbonates and Sandstone Using Computational Rock Physics Methods

    Science.gov (United States)

    Lee, M.; Keehm, Y.

    2010-12-01

    Carbonate Reservoirs are drawing a great attention as global energy demands and consumption increase rapidly, since more than 60% of oil and 40% of gas of world reserves are in carbonate rocks. However, most of them are hard to develop mainly due to their complexity and heterogeneity, especially at the pore scale. In this study, we perform computational rock physics modeling (numerical simulations on pore microstructures of carbonate rocks) and compare the results with those from sandstone. The brief procedure of the method is (1) to obtain high-resolution pore microstructure with a spatial resolution of 1-2 micron by X-ray microtomography technique, (2) to perform two-phase lattice-Boltzmann (LB) flow simulation to obtain various oil and water saturations, then (3) to calculate physical properties, such as P-wave velocity and electrical conductivity through pore-scale property simulation techniques. For the carbonate rock, we identified much more isolated pores than sandstone by investigating pore microstructures. Thus permeability and electrical conductivity were much smaller than those of sandstone. The electrical conductivity versus oil saturation curve of the carbonate rock showed sharper decrease at low oil saturation, but similar slope at higher oil saturation. We think that higher complexity of pore connectivity is responsible for this effect. The P-wave velocity of the carbonate rock was much higher than sandstone and the it did not show any significant changes during the change of oil saturation. Therefore, we think that fluid discrimination by seismic data with P-wave velocity alone would pose a greate challenge in most carbonate reservoirs. In addition, the S-wave velocity seems not to be sensitive either, which suggest that the AVO-type analysis would also be difficult, though requires more researches. On the other hand, our computational rock physics approach can be useful in preliminary analysis of carbonate reservoirs since it can determine the

  15. Interaction between Fingering and Heterogeneity during Viscous Oil Recovery in Carbonate Rocks (Invited)

    Science.gov (United States)

    Mohanty, K. K.; Doorwar, S.

    2013-12-01

    Due to the fast depleting conventional oil reserves, research in the field of petroleum engineering has shifted focus towards unconventional (viscous and heavy) oils. Many of the viscous oil reserves are in carbonate rocks. Thermal methods in carbonate formations are complicated by mineral dissolution and precipitation. Non-thermal methods should be developed for viscous oils in carbonates. In viscous oil reservoirs, oil recovery due to water flood is low due to viscous fingering. Polymer flood is an attractive process, but the timing of the polymer flood start is an important parameter in the optimization of polymer floods. Vuggy Silurian dolomite cores were saturated with formation brine and reservoir oil (150-200 cp). They were then displaced by either a polymeric solution (secondary polymer flood) or brine followed the polymeric solution (tertiary polymer flood). The amount of brine injection was varied as a parameter. Oil recovery and pressure drop was monitored as a function of the starting point of the polymer flood. To visualize the displacement at the pore-scale, two types of micromodels were prepared: one with isolated heterogeneity and the other with connected heterogeneity. The wettability of the micromodels was either water-wet or oil-wet. The micromodels were saturated with formation brine and oil. A series of water flood and polymer flood was conducted to identify the mechanism of fluid flow. Dolomite corefloods show that a tertiary polymer flood following a secondary water flood recovers a substantial amount of oil unlike what is observed in typical sandstone cores with light oil. The tertiary oil recovery plus the secondary waterflood recovery can exceed the oil recovery in a secondary polymer flood in dolomite-viscous oil-brine system. These experiments were repeated in a Berea-oil-brine system which showed that the oil recovered in the secondary polymer flood was similar to the cumulative oil recovery in the tertiary polymer flood. The high

  16. Unusual N—Alkane Distributions in Extracts from Marine Carbonate Rocks at High Levels of Maturity and Overmaturity

    Institute of Scientific and Technical Information of China (English)

    李景贵; R.PAULPHILP; 等

    2002-01-01

    N-alkanes in extracts from possible carbonate source rocks of the Lower Ordovician Majiagou Formation in the central gas field of the Shanganning Basin and the Upper Sinian Dengying Formation in the Weiyuan gas field of the Sichuan Basin,are characterized by bimodal distributions with the dominant carbon numbers in the range C17-C21 and C25-C29.In most sam-ples,the lower carbon number components are present in greater abundance than the higher car-bon number ones.Most samples contain significant concentrations of waxy hydrocarbons(C22+)with C21-/C22+ ratios between 0.50 to 3.16 ,and an average value of 1.34.The n-alkanes in extracts of outcrops and shallow core samples of Upper Proterozoic and Lower Palaeozoic carbon-ate rocks in the western and southern parts of the North China Basin are of unimodal distribu-tions dominated by n-alkanes maximizing in the C25-C29 range.These extracts have very high concentrations of waxy hydrocarbons with C21-/C22+ ratios all<1.0,ranging from 0.14 to 0.90 and averaging 0.36.All of the extracts have a marked odd/even predominance in the high mo-lecular weight n-alkane range regardless of whether they are from shallow or deep cores or out-crop samples.Simulation experiments were performed using typical sapropelic-type kerogens from the immature Sinian Lower Xiamalin Formation carbonate-rich shales collected at Jixian ,Hebei Province,North China Basin ,and the contemporary microplanktonic blue-green algae Spirulina subsala.Results indicate that the unusual distribution of n-alkanes in the extracts of Upper Proterozoic and Lower Palaeozoic carbonate rocks possibly originated from algae in the source rocks at high levels fo maturity and overmaturity.

  17. Mechanical Behavior of Low Porosity Carbonate Rock: From Brittle Creep to Ductile Creep.

    Science.gov (United States)

    Nicolas, A.; Fortin, J.; Gueguen, Y.

    2014-12-01

    Mechanical compaction and associated porosity reduction play an important role in the diagenesis of porous rocks. They may also affect reservoir rocks during hydrocarbon production, as the pore pressure field is modified. This inelastic compaction can lead to subsidence, cause casing failure, trigger earthquake, or change the fluid transport properties. In addition, inelastic deformation can be time - dependent. In particular, brittle creep phenomena have been deeply investigated since the 90s, especially in sandstones. However knowledge of carbonates behavior is still insufficient. In this study, we focus on the mechanical behavior of a 14.7% porosity white Tavel (France) carbonate rock (>98% calcite). The samples were deformed in a triaxial cell at effective confining pressures ranging from 0 MPa to 85 MPa at room temperature and 70°C. Experiments were carried under dry and water saturated conditions in order to explore the role played by the pore fluids. Two types of experiments have been carried out: (1) a first series in order to investigate the rupture envelopes, and (2) a second series with creep experiments. During the experiments, elastic wave velocities (P and S) were measured to infer crack density evolution. Permeability was also measured during creep experiments. Our results show two different mechanical behaviors: (1) brittle behavior is observed at low confining pressures, whereas (2) ductile behavior is observed at higher confining pressures. During creep experiments, these two behaviors have a different signature in term of elastic wave velocities and permeability changes, due to two different mechanisms: development of micro-cracks at low confining pressures and competition between cracks and microplasticity at high confining pressure. The attached figure is a summary of 20 triaxial experiments performed on Tavel limestone under different conditions. Stress states C',C* and C*' and brittle strength are shown in the P-Q space: (a) 20°C and dry

  18. An Experimental Study of Mixture Corrosion Effects of Carbonate Rocks in the Transitional Zone of Littoral Karst Areas

    Institute of Scientific and Technical Information of China (English)

    陈鸿汉; 邹胜章; 朱远峰; 陈从喜

    2001-01-01

    The mechanism for development of littoral karst differs from that of inland karst, and the mixture corrosion effects are one of the most important factors that control the development of littoral karst. Through seven groups of static experiments carried out in a closed CO2-H2O system, basic conclusions can be drawn as follows: (1) the basic law of corrosion process in a transitional zone of seawater-freshwater in littoral karst areas is identical with that in the fresh water,i.e., the lithologic characteristics and rock structure are the main factors which control the development of littoral karst; (2)the mixture corrosion rate of the carbonate rock in the above transitional zone is faster than that in fresh water or seawater;(3) the mechanism for development of carbonate rocks differs at various pressures of CO2 in a transitional zone in littoral karst areas.``

  19. Silurian and Devonian source rocks and crude oils from the western part of Libya: Organic geochemistry, palynology and carbon stratigraphy

    NARCIS (Netherlands)

    Elkelani, Mohamed M.A.

    2015-01-01

    The Early Silurian “hot” shales and Late Devonian black shales are major regional oil and gas source rocks in North Africa. Their deposition probably played a major role in global carbon cycling in general because of the large areas of the ocean affected. Comparing the Libyan δ13C record with record

  20. The thin section rock physics: Modeling and measurement of seismic wave velocity on the slice of carbonates

    Energy Technology Data Exchange (ETDEWEB)

    Wardaya, P. D., E-mail: pongga.wardaya@utp.edu.my; Noh, K. A. B. M., E-mail: pongga.wardaya@utp.edu.my; Yusoff, W. I. B. W., E-mail: pongga.wardaya@utp.edu.my [Petroleum Geosciences Department, Universiti Teknologi PETRONAS, Tronoh, Perak, 31750 (Malaysia); Ridha, S. [Petroleum Engineering Department, Universiti Teknologi PETRONAS, Tronoh, Perak, 31750 (Malaysia); Nurhandoko, B. E. B. [Wave Inversion and Subsurface Fluid Imaging Research Laboratory (WISFIR), Dept. of Physics, Institute of Technology Bandung, Bandung, Indonesia and Rock Fluid Imaging Lab, Bandung (Indonesia)

    2014-09-25

    This paper discusses a new approach for investigating the seismic wave velocity of rock, specifically carbonates, as affected by their pore structures. While the conventional routine of seismic velocity measurement highly depends on the extensive laboratory experiment, the proposed approach utilizes the digital rock physics view which lies on the numerical experiment. Thus, instead of using core sample, we use the thin section image of carbonate rock to measure the effective seismic wave velocity when travelling on it. In the numerical experiment, thin section images act as the medium on which wave propagation will be simulated. For the modeling, an advanced technique based on artificial neural network was employed for building the velocity and density profile, replacing image's RGB pixel value with the seismic velocity and density of each rock constituent. Then, ultrasonic wave was simulated to propagate in the thin section image by using finite difference time domain method, based on assumption of an acoustic-isotropic medium. Effective velocities were drawn from the recorded signal and being compared to the velocity modeling from Wyllie time average model and Kuster-Toksoz rock physics model. To perform the modeling, image analysis routines were undertaken for quantifying the pore aspect ratio that is assumed to represent the rocks pore structure. In addition, porosity and mineral fraction required for velocity modeling were also quantified by using integrated neural network and image analysis technique. It was found that the Kuster-Toksoz gives the closer prediction to the measured velocity as compared to the Wyllie time average model. We also conclude that Wyllie time average that does not incorporate the pore structure parameter deviates significantly for samples having more than 40% porosity. Utilizing this approach we found a good agreement between numerical experiment and theoretically derived rock physics model for estimating the effective seismic

  1. Unusual N-Alkane Distributions in Extracts from Marine Carbonate Rocks at High Levels of Maturity and Overmaturity

    Institute of Scientific and Technical Information of China (English)

    LI JINGGUI(李景贵); R. PAUL PHILP; CUI MINGZHONG(崔明中)

    2002-01-01

    N-alkanes in extracts from possible carbonate source rocks of the Lower Ordovician Majiagou Formation in the central gas field of the Shanganning Basin and the Upper Sinian Dengying Formation in the Weiyuan gas field of the Sichuan Basin, are characterized by bimodal distributions with the dominant carbon numbers in the range C17-C21 and C25-C29. In most samples, the lower carbon number components are present in greater abundance than the higher carbon number ones. Most samples contain significant concentrations of waxy hydrocarbons ( C22 + )with C21-/C22+ ratios between 0.50 to 3.16, and an average value of 1.34. The n-alkanes in extracts of outcrops and shallow core samples of Upper Proterozoic and Lower Palaeozoic carbonate rocks in the western and southern parts of the North China Basin are of unimodal distributions dominated by n-alkanes maximizing in the C25-C29 range. These extracts have very high concentrations of waxy hydrocarbons with C21 -/C22 + ratios all <1.0, ranging from 0. 14 to 0. 90 and averaging 0.36. AⅡ of the extracts have a marked odd/even predominance in the high molecular weight n-alkane range regardless of whether they are from shallow or deep cores or outcrop samples. Simulation experiments were performed using typical sapropelic-type kerogens from the immature Sinian Lower Xiamalin Formation carbonate-rich shales collected at Jixian,Hebei Province, North China Basin, and the contemporary microplanktonic blue-green algae Spirulina subsala. Results indicate that the unusual distribution of n-alkanes in the extracts of Upper Proterozoic and Lower Palaeozoic carbonate rocks possibly originated from algae in the source rocks at high levels of maturity and overmaturity.

  2. Methods for estimation of long-term non-carbonate neutralisation of acid rock drainage.

    Science.gov (United States)

    Miller, Stuart D; Stewart, Warwick S; Rusdinar, Yuni; Schumann, Russell E; Ciccarelli, Joseph M; Li, Jun; Smart, Roger St C

    2010-04-01

    In the long-term phase of an acid rock drainage (ARD) evolution profile, after any short-term neutralisation capacity provided by carbonate minerals is exhausted, the net acid release is a product of a declining acid generation rate (AGR) and a slower, long-term acid neutralisation rate mainly provided by gangue silicate minerals. At some point, the AGR and the non-carbonate acid neutralisation rate (ANRnc) will be similar. Matching of the AGR and ANRnc near 10mg H(2)SO(4)/kg/week is demonstrated in data from 10-year columns. This long-term neutralisation is not measured at present in any accepted assessment tests. Methods to estimate ANRnc, based on silicate mineralogy and solution assays from long-term column leach tests, are compared. Good agreement is demonstrated between rates measured from the solution assay data and those calculated from mineralogy using kinetic databases. More rigorous analysis of the leachate chemistry of selected long-term leach tests also suggests possible cover design criteria based on the maximum AGR that will maintain a pH>4 in leachate from ARD materials. The data show a distinct break at an AGR of 3mg H(2)SO(4)/kg/week, below which no leachate pH is less than 4. The results indicate that an AGR of 10t H(2)SO(4)/ha/year is conservative and a suitable cover design target for ARD control that would be matched by ANRnc.

  3. Strain localization in carbonate rocks experimentally deformed in the ductile field

    Science.gov (United States)

    Rybacki, E.; Morales, L. F. G.; Dresen, G.

    2012-04-01

    The deformation of rocks in the Earth's crust is often localized, varying from brittle fault gauges in shallow environments to mylonites in ductile shear zones at greater depth. A number of theoretical, experimental, and field studies focused on the evolution and extend of brittle fault zones, but little is known so far about initiation of ductile shear zones. Strain localization in rocks deforming at high temperature and pressure may be induced by several physical, chemical, or structurally-related mechanisms. We performed simple and pure shear deformation experiments on carbonate rocks containing structural inhomogenities in the ductile deformation regime. The results may help to gain insight into the evolution of high temperature shear zones. As starting material we used cylindrical samples of coarse-grained Carrara marble containing one or two 1 mm thin artificially prepared sheets of fine-grained Solnhofen limestone, which act as soft inclusions under the applied experimental conditions. Length and diameter of the investigated solid and hollow cylinders were 10-20 mm and 10-15 mm, respectively. Samples were deformed in a Paterson-type gas deformation apparatus at 900° C temperature and confining pressures of 300 and 400 MPa. Three samples were deformed in axial compression at a bulk strain rate of 8x10-5 s-1to axial strains between 0.02 and 0.21 and 15 samples were twisted in torsion at a bulk shear strain rate of 2x10-4 s-1 to shear strains between 0.01 and 3.74. At low strain, specimens deformed axially and in torsion show minor strain hardening that is replaced by strain weakening at shear strains in excess of about 0.2. Peak shear stress at the imposed condition is about 20 MPa. Strain localized strongly within the weak inclusions as indicated by inhomogeneous bending of initially straight strain markers on sample jackets. Maximum strain concentration within inclusions with respect to the adjacent matrix was between 4 and 40, depending on total strain and

  4. Mg Isotope Evolution During Water-Rock Interaction in a Carbonate Aquifer

    Science.gov (United States)

    Zhang, Z.; Jacobson, A. D.; Lundstrom, C. C.; Huang, F.

    2008-12-01

    To better understand how Mg isotopes behave during weathering and aqueous transport, we used a Nu Plasma MC-ICP-MS to measure δ26Mg values (relative to DSM-3) in water samples along a 236 km flow path in the Madison aquifer of South Dakota, a confined carbonate aquifer recharging in the igneous Black Hills. We also analyzed local granite and dolomite samples to characterize the Mg isotope composition of source rocks constituting the recharge zone and aquifer, respectively. Repeated analyses of Mg standard solutions yielded external precisions (2σ) better than 0.1 permil for δ26Mg(CAM-1, - 2.584±0.071, n=13; UIMg-1, -2.217±0.087, n=9.). The Madison aquifer provides a unique opportunity to quantify Mg isotope effects during water-rock interaction because (1) fluids and rock have chemically equilibrated over a much longer timescale (up to ~15 kyr) than can be simulated in laboratory experiments and (2) previous studies have determined the rates and mass-balances of de- dolomitization and other geochemical reactions controlling solute evolution along the flow path. Reactions important for changing the concentration and isotope composition of Mg include dolomite dissolution, Mg-for- Na ion exchange, calcite precipitation, and isotope exchange. δ26Mg values within the recharge region (0-17 km along flow path) vary between -1.08 and -1.63 permil, and then remain essentially constant at -1.408±0.010 permil(1σ, 5 samples) from 17 to 189 km. A final sample at 236 km shows an increase to -1.09 permil. Either mixing between different recharge waters or rapid isotope exchange between infiltrating waters and dolomite could control δ26Mg variability between 0 and 17 km. Likewise, reactive transport modeling suggests that preferential uptake of 24Mg during Mg-for-Na ion exchange might cause an increase in δ26Mg between 189 and 236 km. However, unchanging δ26Mg values observed throughout most of the aquifer clearly demonstrate that Mg isotopes are not fractionated during

  5. Petroleum geological features and exploration prospect of deep marine carbonate rocks in China onshore: A further discussion

    Directory of Open Access Journals (Sweden)

    Zhao Wenzhi

    2014-10-01

    Full Text Available Deep marine carbonate rocks have become one of the key targets of onshore oil and gas exploration and development for reserves replacement in China. Further geological researches of such rocks may practically facilitate the sustainable, steady and smooth development of the petroleum industry in the country. Therefore, through a deep investigation into the fundamental geological conditions of deep marine carbonate reservoirs, we found higher-than-expected resource potential therein, which may uncover large oil or gas fields. The findings were reflected in four aspects. Firstly, there are two kinds of hydrocarbon kitchens which were respectively formed by conventional source rocks and liquid hydrocarbons cracking that were detained in source rocks, and both of them can provide large-scale hydrocarbons. Secondly, as controlled by the bedding and interstratal karstification, as well as the burial and hydrothermal dolomitization, effective carbonate reservoirs may be extensively developed in the deep and ultra-deep strata. Thirdly, under the coupling action of progressive burial and annealing heating, some marine source rocks could form hydrocarbon accumulations spanning important tectonic phases, and large quantity of liquid hydrocarbons could be kept in late stage, contributing to rich oil and gas in such deep marine strata. Fourthly, large-scale uplifts were formed by the stacking of multi-episodic tectonism and oil and gas could be accumulated in three modes (i.e., stratoid large-area reservoir-forming mode of karst reservoirs in the slope area of uplift, back-flow type large-area reservoir-forming mode of buried hill weathered crust karst reservoirs, and wide-range reservoir-forming mode of reef-shoal reservoirs; groups of stratigraphic and lithologic traps were widely developed in the areas of periclinal structures of paleohighs and continental margins. In conclusion, deep marine carbonate strata in China onshore contain the conditions for

  6. Pore space characterization in carbonate rocks - Approach to combine nuclear magnetic resonance and elastic wave velocity measurements

    Science.gov (United States)

    Müller-Huber, Edith; Schön, Jürgen; Börner, Frank

    2016-04-01

    Pore space features influence petrophysical parameters such as porosity, permeability, elastic wave velocity or nuclear magnetic resonance (NMR). Therefore they are essential to describe the spatial distribution of petrophysical parameters in the subsurface, which is crucial for efficient reservoir characterization especially in carbonate rocks. While elastic wave velocity measurements respond to the properties of the solid rock matrix including pores or fractures, NMR measurements are sensitive to the distribution of pore-filling fluids controlled by rock properties such as the pore-surface-to-pore-volume ratio. Therefore a combination of both measurement principles helps to investigate carbonate pore space using complementary information. In this study, a workflow is presented that delivers a representative average semi-axis length of ellipsoidal pores in carbonate rocks based on the pore aspect ratio received from velocity interpretation and the pore-surface-to-pore-volume ratio Spor as input parameters combined with theoretical calculations for ellipsoidal inclusions. A novel method to calculate Spor from NMR data based on the ratio of capillary-bound to movable fluids and the thickness of the capillary-bound water film is used. To test the workflow, a comprehensive petrophysical database was compiled using micritic and oomoldic Lower Muschelkalk carbonates from Germany. The experimental data indicate that both mud-dominated and grain-dominated carbonates possess distinct ranges of petrophysical parameters. The agreement between the predicted and measured surface-to-volume ratio is satisfying for oomoldic and most micritic samples, while pyrite or significant sample heterogeneity may lead to deviations. Selected photo-micrographs and scanning electron microscope images support the validity of the estimated representative pore dimensions.

  7. Assessing and calibrating the ATR-FTIR approach as a carbonate rock characterization tool

    Science.gov (United States)

    Henry, Delano G.; Watson, Jonathan S.; John, Cédric M.

    2017-01-01

    ATR-FTIR (attenuated total reflectance Fourier transform infrared) spectroscopy can be used as a rapid and economical tool for qualitative identification of carbonates, calcium sulphates, oxides and silicates, as well as quantitatively estimating the concentration of minerals. Over 200 powdered samples with known concentrations of two, three, four and five phase mixtures were made, then a suite of calibration curves were derived that can be used to quantify the minerals. The calibration curves in this study have an R2 that range from 0.93-0.99, a RMSE (root mean square error) of 1-5 wt.% and a maximum error of 3-10 wt.%. The calibration curves were used on 35 geological samples that have previously been studied using XRD (X-ray diffraction). The identification of the minerals using ATR-FTIR is comparable with XRD and the quantitative results have a RMSD (root mean square deviation) of 14% and 12% for calcite and dolomite respectively when compared to XRD results. ATR-FTIR is a rapid technique (identification and quantification takes < 5 min) that involves virtually no cost if the machine is available. It is a common tool in most analytical laboratories, but it also has the potential to be deployed on a rig for real-time data acquisition of the mineralogy of cores and rock chips at the surface as there is no need for special sample preparation, rapid data collection and easy analysis.

  8. Sulfur and carbon isotopic variations in Neoproterozoic sedimentary rocks from southern China

    Institute of Scientific and Technical Information of China (English)

    CHU Xuelei; ZHANG Qirui; ZHANG Tonggang; FENG Lianjun

    2003-01-01

    A new set of δ34Ssulfide, δ34Ssulfate and δ13Ccarbonate values has been reported from Neoproterozoic sedimentary rocks in southern China. The interglacial black shales of the Datangpo Fm. display higher δ34Ssulfide values with >+20‰ average, but the postglacial black shales from the Doushantuo Fm. show negative δ34Ssulfide values. However, the Jinjiadong Fm., the same post-glaciation as the Doushantuo Fm., has positive δ34Ssulfide values, implying that the δ34S value of sedimentary sulfides would be controlled by lithofacies and paleogeographic environments. The δ34Ssulfate values relative to δ13Ccarbonate were obtained by extraction of trace sulfate from the successive carbonate sequences in the Yangtze Gorges sections. A preliminary interpretation suggests that the oceanic environment may fluctuate dramatically at the post-glacial Doushantuo stage and, then, recover its stability at the Dengying stage on the basis of the high resolution δ34S and δ13C curves of seawater.

  9. Petrographical Study of Ewekoro Carbonate Rocks, in Ibese, South Western Nigeria

    Directory of Open Access Journals (Sweden)

    Osinowo O.O.

    2010-12-01

    Full Text Available

    Limestone deposits can be found in every system of the geologic column since the Precambrian. In classifying this rock, various attempts have been made and notable among them is the classification scheme based on three components: allochems, cements and matrix. Another classification divided limestoneonthe basis of texture into grainstone, packstone, mudstone, wackestone and boundstone. Texturally, limestone ranges from fine to coarse grained with aragonite and calcite as the most common minerals. This work was aimed at identifying and describing both the allochemical and orthochemical components of the limestone deposits in order to classify and deduce their depositional environment.

    Eight core samples of limestone deposits representing the Ewekoro Formation of the Dahomey Basin were studied petrographically.

    The result of the analysis carried out on the samples showed that the Ibese limestone is composed of the following allochems: sponges, echinoids, bivalves, coralline algae, and pelecypod which represent the skeletal content and intraclasts, pellets and ooids which represent the non skeletal grains. The orthochemical constituents include the carbonate mud matrix and the sparry calcite cement.

    These constituents observed from the slides indicate that the Ibese limestone belongs to the class of wackestone and could have been deposited in a quiet and low energy environment.

  10. Quantitative Estimation of Carbonate Rock Fraction in Karst Regions Using Field Spectra in 2.0–2.5 μm

    Directory of Open Access Journals (Sweden)

    Xiangjian Xie

    2016-01-01

    Full Text Available Considering the important roles of carbonate rock fraction in karst rocky desertification areas and their potential for indicating damage to vegetation, improved knowledge is desired to assess the application of spectroscopy and remote sensing to characterizing and quantifying the biophysical constituents of karst landscapes. In this study, we examined the spectra of major surface constituents in karst areas for direct evidence of absorption features attributable to carbonate rock fraction. Using spectral feature analysis with continuum removal, we observed that there are overlapping spectral absorption in 2.149–2.398 μm by soils and non-photosynthetic vegetation. These overlapping features complicated the carbonate absorption feature near 2.340 μm in synthetic mixed spectra. To remove the overprint signal, two hyperspectral carbonate rock indices (HCRIs were developed. Compared to the absorption features including depths, areas, and KRDSIs (karst rocky desertification synthesis indices, linear regression of HCRIs with carbonate rock fraction in linear synthetic mixtures resulted in higher correlations and lower errors. This study demonstrates that spectral variation of the surface constituents spectra in 2.270–2.398 μm region can indicate carbonate rock fraction and be used to quantify them. Still, additional research is needed to advance our understanding of the spectral influences from carbonate petrography relative to carbonate mineralogy, components and physical state of rock surface.

  11. Determination of carbon isotopic composition of individual light hydrocarbons evolved from pyrolysis of source rocks by using GC-IRMS

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The carbon isotopic composition of individual light hydrocarbons generated from source rocks that had been pyrolysed in vacuum glass tube were determined by using the GC-IRMS techniques. The results indicate that abundant CO2 in the pyrolysates has a remarkable effect on the determination of CH4δ13C. Running cryogenically with an initial temperature of -40℃can effectively eliminate the effect. In addition, it conduces to measuring the δ13C of C2+ hydrocarbons by increasing the injection volume and/or absorbing CO2 with the solution of sodium hydroxide.The above measures will help to get the carbon isotopic composition of C1-C7 components, which is of great significance for gas/source rock correlation and for study on the genesis of natural gas.

  12. Carbonate rock classification applied to brazilian sedimentary basins; Classificacao de rochas carbonaticas aplicavel as bacias sedimentares brasileiras

    Energy Technology Data Exchange (ETDEWEB)

    Terra, Gerson Jose Salamoni [Universidade Petrobras, Rio de Janeiro, RJ (Brazil). Escola de Ciencias e Tecnologias de Exploracao e Producao], E-mail: gersonterra@petrobras.com.br; Spadini, Adali Ricardo [Petrobras E e P, Rio de Janeiro, RJ (Brazil). Exploracao], E-mail: spadini@petrobras.com.br; Franca, Almerio Barros [Centro de Pesquisa e Desenvolvimento Leopoldo A. Miguez de Mello (CENPES), Rio de Janeiro, RJ (Brazil). Sedimentologia e Petrologia] (and others)

    2009-11-15

    A new classification of carbonate rocks is proposed seeking to cover the entire spectrum of their occurrence in Brazilian basins. Emphasis is given to those in oil exploration and production locations, especially since the discovery of giant oil fields in the so called Pre-Salt section. This classification is a synergy between the various existing classifications adapting or modifying some terms and introducing new names. The carbonate rocks were divided into four groups according to their depositional texture: 1) elements not bound during deposition (mudstone, wackestone, packstone, grainstone, floatstone, rudstone, bioaccumulated, breccia), 2) elements bound during deposition, or in situ (boundstone, stromatolite, arborescent stromatolite, arbustiform stromatolite, dendriform stromatolite, thrombolite, dendrolite, leiolite, spherulitite, travertine and tufa), 3) elements bound or not bound during deposition (laminite, smooth laminite, crenulated laminite); 4) unrecognized depositional texture (crystalline limestone, dolomite). (author)

  13. Biological marker characteristics of oils and asphalts from carbonate source rocks in a rapidly subsiding graben, Dead Sea, Israel

    Energy Technology Data Exchange (ETDEWEB)

    Rullkoetter, J.; Spiro, B.; Nissenbaum, A.

    1985-06-01

    A detailed GC/MS study of biological marker compounds in the saturated and aromatic hydrocarbon fractions of oils and asphalts from the Dead Sea area, Israel, provided decisive information to the solution of a long-lasting controversy by showing that the asphalts are products of early generation in an immature stage from the same type of carbonate source rock which generated more mature oils. The asphalts are not biodegraded residues of the oils. This study also provides general information on the evolution of biological markers in carbonate source rocks. Low-activation-energy processes, like isomerization of steranes, appear to occur much faster at low temperatures than in shales. The high sulfur content and less cross-linking of the biogenic organic matter into a complex kerogen structure are suggested to be responsible for this. 41 references, 8 figures, 2 tables.

  14. Investigation of Chromium and Nickel mobility in serpentinite soils and rocks: Impact into groundwaters and influences of carbonation.

    Science.gov (United States)

    Baneschi, Ilaria; Natali, Claudio; Boschi, Chiara; Chiarantini, Laura; Guidi, Massimo

    2013-04-01

    Potentially harmful elements such as Cr and Ni in soils are increasingly drawing the attention of scientists and authorities due to their potential toxicity to humans and ecosystems. In the Tuscany region high levels of Cr in Ni have been reported in ultramafic rocks and soils. Furthermore, concentrations of Cr in groundwater of several aquifer systems of this area can approach the maximum contamination level of 50 µg/l, mainly in the form of Cr (VI). The main mechanism for mobilization Cr (VI) at these sites is the weathering of Cr (III) from ultramafic rock with subsequent oxidation. To characterize the effects of weathering and the accessibility of geologically sourced and potentially toxic Cr and Ni in coastal Tuscany EU and Regione Toscana financed a multidisciplinary project, named RESPIRA. The study of waters, rocks and soils was conducted in the some sites of the coastal area of Tuscany, where concentrations of Cr (VI) in springwaters are around 50 µg/l (like in Querceto and Montecastelli) or below the detection limit, such as in Santa Luce. It has to be noted that at the site of Montecastelli and Querceto carbonation of serpentinite outcrops has been revealed (Boschi, 2011), together with iron rich brucite. Chemical and mineralogical analyses were conducted on rock and soil samples by scanning electron microscopy (SEM), electron microprobe (EMP), X-Ray Fluorescence (XRF) and seven-steps sequential extraction. Extraction analyses were performed to obtain quantitative information on the distribution of trace metals in different mineralogical phases (clay minerals, carbonates, amorphous Fe, Mn oxides, organic matter and other silicates and oxides). The results show that the residual fraction was the predominant form of Cr and Ni in soil and rock samples. However, the concentrations of Ni associated to exchangeable, carbonates, Mn oxides and non cristalline fractions were higher than those of Cr, indicating that Ni was more available than Cr in all samples

  15. Evapotranspiration units in the Basin and Range carbonate-rock aquifer system, White Pine County, Nevada, and adjacent parts of Nevada and Utah

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Accurate estimates of ground-water discharge are crucial in the development of a water budget for the Basin and Range Carbonate-rock Aquifer System (BARCAS) study...

  16. Multicriteria decision-making analysis based methodology for predicting carbonate rocks' uniaxial compressive strength

    Directory of Open Access Journals (Sweden)

    Ersoy Hakan

    2012-10-01

    Full Text Available

    ABSTRACT

    Uniaxial compressive strength (UCS deals with materials' to ability to withstand axially-directed pushing forces and especially considered to be rock materials' most important mechanical properties. However, the UCS test is an expensive, very time-consuming test to perform in the laboratory and requires high-quality core samples having regular geometry. Empirical equations were thus proposed for predicting UCS as a function of rocks' index properties. Analytical hierarchy process and multiple regression analysis based methodology were used (as opposed to traditional linear regression methods on data-sets obtained from carbonate rocks in NE Turkey. Limestone samples ranging from Devonian to late Cretaceous ages were chosen; travertine-onyx samples were selected from morphological environments considering their surface environmental conditions Test results from experiments carried out on about 250 carbonate rock samples were used in deriving the model. While the hierarchy model focused on determining the most important index properties affecting on UCS, regression analysis established meaningful relationships between UCS and index properties; 0. 85 and 0. 83 positive coefficient correlations between the variables were determined by regression analysis. The methodology provided an appropriate alternative to quantitative estimation of UCS and avoided the need for tedious and time consuming laboratory testing


    RESUMEN

    La resistencia a la compresión uniaxial (RCU trata con la capacidad de los materiales para soportar fuerzas empujantes dirigidas axialmente y, especialmente, es considerada ser uno de las más importantes propiedades mecánicas de

  17. Pseudo-random renormalization group forward and inverse modeling of the electrical properties of some carbonate rocks

    Science.gov (United States)

    Gomaa, Mohamed M.; Kassab, Mohamed A.

    2016-12-01

    Electrical properties of carbonate rocks from North Sinai, Egypt, were investigated experimentally in the frequency domain (100 Hz to 100 kHz). Changes between electrical properties were attributed to changes in mineral composition and texture of samples. Asymmetric mixture laws cannot describe electrical behavior of heterogeneous rocks in the mentioned frequency range. A theoretical pseudo-random renormalization group (PRNG) method was developed to model electrical behavior of rock mixtures. The main goal of this paper is to make forward and inverse modeling using PRNG method for the electrical properties as a function of frequency for carbonate rocks with texture. In PRNG method four phases were used to take into account the texture in the samples. Four phases are the best that we could use in the model. We are trying to increase the competence of the model in the near future. In these four phases mainly conducting constituents (silt and clay) and mainly insulating constituents (sand, air and carbonate) may coat each other. With appropriately chosen coatings for the four phases, the PRNG method can reasonably model the electrical properties of the samples in the measured frequency range. Thus, an inverse problem is used to find the detailed structure of the four phases, which leads to the measured electrical properties of the samples, taking into account the measured concentrations of the different constituents of the samples. The inverse problem is based on minimizing the misfit between the measured frequency response for the conductivity and the dielectric constant and those obtained theoretically from the PRNG method. It was shown that the texture plays an important role in determining the A.C. electrical properties of heterogeneous samples.

  18. Adsorption of Anionic, Cationic and Nonionic Surfactants on Carbonate Rock in Presence of ZrO 2 Nanoparticles

    Science.gov (United States)

    Esmaeilzadeh, Pouriya; Bahramian, Alireza; Fakhroueian, Zahra

    The adsorption of surfactants at the solid-water interface is important for the control of wetting, lubrication, detergency and in mineral flotation.We have studied the adsorptions of different types of surfactants, cationic (Dodecyl trimethylammonium bromide, DTAB), anionic (sodium dodecyl sulfate, SDS) and non-anionic (lauryl alcohol-7 mole ethoxylate, LA7) on carbonate rock in presence of zirconium oxide spherical nanoparticles (17-19 nm). ZrO2 nanoparticles with tetrahedral structure have significant effect on adsorption of surfactants on the carbonate rock. We have used the measured conductivities to determine the rate of adsorption of surfactants at rock-water interfaces. The conductivity of DTAB in aqueous solutions containing calcite powder decreases more than the other surfactants in contact with ZrO2 nanoparticles. We have also investigated the adsorption of surfactants at the air-water interface. The presence of nanoparticles, as demonstrated by our experiments, enhances the surface activity and surface adsorption of the surfactants through electrostatic forces or formation of nanostructures. Dynamic light structuring data shows similar aggregation number of nanoparticles in presence of nanoparticles.

  19. Ultra-fine grinding and mechanical activation of mine waste rock using a high-speed stirred mill for mineral carbonation

    Institute of Scientific and Technical Information of China (English)

    Jia-jie Li; Michael Hitch

    2015-01-01

    CO2 sequestration by mineral carbonation can permanently store CO2 and mitigate climate change. However, the cost and reaction rate of mineral carbonation must be balanced to be viable for industrial applications. In this study, it was attempted to reduce the carbonation costs by using mine waste rock as a feed stock and to enhance the reaction rate using wet mechanical activation as a pre-treatment method. Slurry rheological properties, particle size distribution, specific surface area, crystallinity, and CO2 sequestration reaction efficiency of the initial and mechanically activated mine waste rock and olivine were characterized. The results show that serpentine acts as a catalyst, in-creasing the slurry yield stress, assisting new surface formation, and hindering the size reduction and structure amorphization. Mechanically activated mine waste rock exhibits a higher carbonation conversion than olivine with equal specific milling energy input. The use of a high-speed stirred mill may render the mineral carbonation suitable for mining industrial practice.

  20. Carbonate- and silicate-rich globules in the kimberlitic rocks of northwestern Tarim large igneous province, NW China: Evidence for carbonated mantle source

    Science.gov (United States)

    Cheng, Zhiguo; Zhang, Zhaochong; Santosh, M.; Hou, Tong; Zhang, Dongyang

    2014-12-01

    We report carbonate- and silicate-rich globules and andradite from the Wajilitage kimberlitic rocks in the northwestern Tarim large igneous province, NW China. The carbonate-rich globules vary in size from 1 to 3 mm, and most have ellipsoidal or round shape, and are composed of nearly pure calcite. The silicate-rich globules are elliptical to round in shape and are typically larger than the carbonate-rich globules ranging from 2 to several centimeters in diameter. They are characterized by clear reaction rims and contain several silicate minerals such as garnet, diopside and phlogopite. The silicate-rich globules, reported here for the first time, are suggested to be related to the origin of andradite within the kimberlitic rocks. Our results show that calcite in the carbonate-rich globules has a high XCa (>0.97) and is characterized by extremely high concentrations of the total rare earth elements (up to 1500 ppm), enrichment in Sr (8521-10,645 ppm) and LREE, and remarkable depletion in Nd, Ta, Zr, Hf and Ti. The calcite in the silicate-rich globules is geochemically similar to those in the carbonate-rich globules except the lower trace element contents. Garnet is dominantly andradite (And59.56-92.32Grs5.67-36.03Pyr0.36-4.61Spe0-0.33) and is enriched in light rare earth elements (LREEs) and relatively depleted in Rb, Ba, Th, Pb, Sr, Zr and Hf. Phlogopite in the silicate-rich globules has a high Mg# ranging from 0.93 to 0.97. The composition of the diopside is Wo45.82-51.39En39.81-49.09Fs0.88-0.95 with a high Mg# ranging from 0.88 to 0.95. Diopside in the silicate-rich globules has low total rare earth element (REE) contents (14-31 ppm) and shows middle REE- (Eu to Gd), slight light REE- and heavy REE-enrichment with elevated Zr, Hf and Sr contents and a negative Nb anomaly in the normalized diagram. The matrix of the kimberlitic rocks are silica undersaturated (27.92-29.31 wt.% SiO2) with low Al2O3 (4.51-5.15 wt.%) and high CaO (17.29-17.77 wt.%) contents. The

  1. Authigenic potassium feldspar: a tracer for the timing of palaeofluid flow in carbonate rocks, Northern Calcareous Alps, Austria

    Science.gov (United States)

    Spotl, C.; Kunk, M.J.; Ramseyer, K.; Longstaffe, F.J.

    1998-01-01

    This paper is included in the Special Publication entitled 'Dating and duration of fluid flow and fluid-rock interaction', edited by J. Parnell. Feldspar is a common authigenic constituent in Permian carbonate rocks which occur as tectonically isolated blocks within the evaporitic Haselgebirge melange in the Northern Calcareous Alps (NCA). Coexisting with pyrite, anhydrite, (saddle) dolomite, magnesite, fluorite and calcite, K-feldspar and minor albite record an event of regionally extensive interaction of hot brines with carbonate rocks. Detailed petrographic, crystallographic and geochemical studies reveal a variability in crystal size and shape, Al-Si ordering, elemental and stable isotopic compositions of the K-feldspar, which is only partially consistent with the traditional view of authigenic feldspar as a well-ordered, compositionally pure mineral. 40Ar-39Ar step- heating measurements of authigenic potassium feldspar from several localities yield two age populations, an older one of 145-154 Ma, and a younger one of c.90-97 Ma. Most age spectra reflect cooling through the argon retention temperature interval, which was rapid in some localities (as indicated by plateau ages) and slower in others. Rb-Sr isotope data are more difficult to interpret, because in many K-feldspar samples they are controlled largely by Sr-bearing inclusions. The Jurassic 40Ar-39Ar dates are interpreted as minimum ages of feldspar growth and hence imply that fluid-rock interaction is likely to be simultaneous with or to slightly predate melange formation. Deformation associated with the closure and subduction of the Meliata-Hallstatt ocean south of the NCA during the Upper Jurassic is regarded as the principal geodynamic driving force for both enhanced fluid circulation and melange formation. Some localities were reheated beyond the argon retention temperature for microcline during mid-Cretaceous nappe stacking of the NCA, thus obliterating the older signal.

  2. Carbon deposition during brittle rock deformation: Changes in electrical properties of fault zones and potential geoelectric phenomena during earthquakes

    Energy Technology Data Exchange (ETDEWEB)

    Mathez, E A; Roberts, J J; Duba, A G; Kronenberg, A K; Karner, S L

    2008-05-16

    To investigate potential mechanisms for geoelectric phenomena accompanying earthquakes, we have deformed hollow cylinders of Sioux quartzite to failure in the presence of carbonaceous pore fluids and investigated the resulting changes in electrical conductivity and carbon distribution. Samples were loaded at room temperature or 400 C by a hydrostatic pressure at their outer diameter, increasing pressure at a constant rate to {approx}290 MPa. Pore fluids consisted of pure CO, CO{sub 2}, CH{sub 4} and a 1:1 mixture of CO{sub 2} and CH{sub 4}, each with pore pressures of 2.0 to 4.1 MPa. Failure occurred by the formation of mode II shear fractures transecting the hollow cylinder walls. Radial resistivities of the cylinders fell to 2.9 to 3.1 M{Omega}-m for CO tests and 15.2 to 16.5 M{Omega}-m for CO{sub 2}:CH{sub 4} tests, compared with >23 M{Omega}-m for dry, undeformed cylinders. Carbonaceous fluids had no discernable influence on rock strength. Based on mapping using electron microprobe techniques, carbon occurs preferentially as quasi-continuous films on newly-formed fracture surfaces, but these films are absent from pre-existing surfaces in those same experiments. The observations support the hypothesis that electrical conductivity of rocks is enhanced by the deposition of carbon on fracture surfaces and imply that electrical properties may change in direct response to brittle deformation. They also suggest that the carbon films formed nearly instantaneously as the cracks formed. Carbon film deposition may accompany the development of microfracture arrays prior to and during fault rupture and thus may be capable of explaining precursory and coseismic geoelectric phenomena.

  3. Estimating Hydrogeological Parameters in Covered Carbonate Rocks Using a Discrete-State Compartment Model and Environmental Tritium

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Nowadays, isotope environmental technique tends to be used as a reconnaissance tool , both qualitative and quantitative, to calculate the aquifer parameters particularly in carbonate rock aquifers. But, the heterogeneous flow is still problematic when Lumped-parameter Models are usually used to calculate the residence times and hydraulic parameters. However, Discrete-State Compartment Model can provide a powerful model to heterogeneous medium. One such study was carried on in Dazha valley, where the environmental tritium was used as a tracer for determining hydrogeological parameters based on a discrete-state compartment model.

  4. Supercritical Carbon Dioxide Extraction of Organic Matter from Petroleum Source Rocks and Its Implications

    Institute of Scientific and Technical Information of China (English)

    沈忠民; 周光甲; 等

    1996-01-01

    Organic matter was experimentally extracted by supercritical fluids(CO2+1% isopropanol)from petroleum source rocks of different thermo-maturities at different buried depths in the same stratigraphic unit in the Dongying Basin.The results show that supercritical fluid extraction(SFE)is more effective than Soxhlet extraction(SE),with higher amounts and greater varieties of hydrocarbons and soluble organic matter becoming extractive.The supercritical CO2 extraction is therefore considered more valuable in evaluation of petroleum source rocks and oil resources,particularly those of immature types.

  5. Deteriorating effects of lichen and microbial colonization of carbonate building rocks in the Romanesque churches of Segovia (Spain)

    Energy Technology Data Exchange (ETDEWEB)

    Rios, Asuncion de los [Instituto de Recursos Naturales, Centro de Ciencias Medioambientales (CSIC), Serrano 115 dpdo., 28006 Madrid (Spain)], E-mail: arios@ccma.csic.es; Camara, Beatriz [Instituto de Recursos Naturales, Centro de Ciencias Medioambientales (CSIC), Serrano 115 dpdo., 28006 Madrid (Spain); Garcia del Cura, Ma Angeles [Instituto de Geologia Economica CSIC-UCM, Laboratorio de Petrologia Aplicada, Unidad Asociada CSIC-UA, Alicante (Spain); Rico, Victor J. [Departamento de Biologia Vegetal II, Facultad de Farmacia, Universidad Complutense, 28040 Madrid (Spain); Galvan, Virginia [Facultad Patrimonio Cultural, Universidad SEK, Convento de Santa Cruz la Real, 40003 Segovia (Spain); Ascaso, Carmen [Instituto de Recursos Naturales, Centro de Ciencias Medioambientales (CSIC), Serrano 115 dpdo., 28006 Madrid (Spain)

    2009-01-15

    In this study, the deterioration effects of lichens and other lithobionts in a temperate mesothermal climate were explored. We examined samples of dolostone and limestone rocks with visible signs of biodeterioration taken from the exterior wall surfaces of four Romanesque churches in Segovia (Spain): San Lorenzo, San Martin, San Millan and La Vera Cruz. Biofilms developing on the lithic substrate were analyzed by scanning electron microscopy. The most common lichen species found in the samples were recorded. Fungal cultures were then obtained from these carbonate rocks and characterized by sequencing Internal Transcribed Spacers (ITS). Through scanning electron microscopy in back-scattered electron mode, fungi (lichenized and non-lichenized) were observed as the most frequent microorganisms occurring at sites showing signs of biodeterioration. The colonization process was especially conditioned by the porosity characteristics of the stone used in these buildings. While in dolostones, microorganisms mainly occupied spaces comprising the rock's intercrystalline porosity, in bioclastic dolomitized limestones, fungal colonization seemed to be more associated with moldic porosity. Microbial biofilms make close contact with the substrate, and thus probably cause significant deterioration of the underlying materials. We describe the different processes of stone alteration induced by fungal colonization and discuss the implications of these processes for the design of treatments to prevent biodeterioration.

  6. Imaging of oil layers, curvature and contact angle in a mixed-wet and a water-wet carbonate rock

    Science.gov (United States)

    Singh, Kamaljit; Bijeljic, Branko; Blunt, Martin J.

    2016-03-01

    We have investigated the effect of wettability of carbonate rocks on the morphologies of remaining oil after sequential oil and brine injection in a capillary-dominated flow regime at elevated pressure. The wettability of Ketton limestone was altered in situ using an oil phase doped with fatty acid which produced mixed-wet conditions (the contact angle where oil contacted the solid surface, measured directly from the images, θ=180°, while brine-filled regions remained water-wet), whereas the untreated rock (without doped oil) was weakly water-wet (θ=47 ± 9°). Using X-ray micro-tomography, we show that the brine displaces oil in larger pores during brine injection in the mixed-wet system, leaving oil layers in the pore corners or sandwiched between two brine interfaces. These oil layers, with an average thickness of 47 ± 17 µm, may provide a conductive flow path for slow oil drainage. In contrast, the oil fragments into isolated oil clusters/ganglia during brine injection under water-wet conditions. Although the remaining oil saturation in a water-wet system is about a factor of two larger than that obtained in the mixed-wet rock, the measured brine-oil interfacial area of the disconnected ganglia is a factor of three smaller than that of oil layers.

  7. An assessment of geochemical preparation methods prior to organic carbon concentration and carbon isotope ratio analyses of fine-grained sedimentary rocks

    Science.gov (United States)

    KöNitzer, Sven F.; Leng, Melanie J.; Davies, Sarah J.; Stephenson, Michael H.

    2012-09-01

    This study summarizes organic carbon isotope (δ13C) and total organic carbon (TOC) data from a series of tests undertaken to provide an appropriate methodology for pre-analysis treatment of mudstones from an Upper Carboniferous sedimentary succession, in order to develop a consistent preparation procedure. The main treatments involved removing both inorganic carbonate and hydrocarbons (which might be extraneous) before δ13C and TOC analysis. The results show that decarbonating using hydrochloric acid causes significant reduction in δ13C and total carbon (TC) of the bulk material due to the removal of inorganic carbonate. These changes are most pronounced where soluble calcium carbonate (rather than Ca-Mg-Fe carbonate) is present. Deoiled samples show only slightly higher mean δ13C where visible bitumen was extracted from the bulk sample. Moreover, the isotopic signatures of the extracts are closely correlated to those of their respective bulk samples, suggesting that small yields of hydrocarbons were generated in situ with no isotopic fractionation. In addition, further δ13C and TC analyses were performed on samples where mixing of oil-based drilling mud with brecciated core material had been undertaken. Brecciated mudstone material did not display distinct isotopic signals compared to the surrounding fine-grained material. Overall we show that the most accurate assessment of bulk organic carbon isotopes and concentration in these samples can be achieved through decarbonating the material prior to measurement via the `rinse method'. However, our results support recent findings that pre-analysis acid treatments can cause variable and unpredictable errors in δ13C and TOC values. We believe that, despite these uncertainties, the findings presented here can be applied to paleoenvironmental studies on organic matter contained within sedimentary rocks over a range of geological ages and compositions.

  8. The Effect of Magnesium Carbonate (Chalk) on Geometric Entropy, Force, and Electromyography During Rock Climbing.

    Science.gov (United States)

    Kilgas, Matthew A; Drum, Scott N; Jensen, Randall L; Phillips, Kevin C; Watts, Phillip B

    2016-12-01

    Rock climbers believe chalk dries the hands of sweat and improves the static coefficient of friction between the hands and the surface of the rock. The purpose of this study was to assess whether chalk affects geometric entropy or muscular activity during rock climbing. Nineteen experienced recreational rock climbers (13 males, 6 females; 173.5 ± 7.0 cm; 67.5 ± 3.4 kg) completed 2 climbing trails with and without chalk. The body position of the climber and muscular activity of the finger flexors was recorded throughout the trial. Following the movement sequence participants hung from a standard climbing hold until they slipped from the climbing structure, while the coefficient of friction and the ratio of the vertical forces on the hands and feet were determined. Although there were no differences in the coefficient of friction (P = .748), geometric entropy (P = .359), the ratio of the vertical forces between the hands and feet (P = .570), or muscular activity (P = .968), participants were able to hang longer after the use of chalk 62.9 ± 36.7 s and 49.3 ± 25.2 s (P = .046). This is advantageous because it may allow for prolonged rests, and more time to plan the next series of climbing moves.

  9. Variations in hydraulic conductivity with scale of measurement during aquifer tests in heterogeneous, porous carbonate rocks

    Science.gov (United States)

    Schulze-Makuch, Dirk; Cherkauer, Douglas S.

    Previous studies have shown that hydraulic conductivity of an aquifer seems to increase as the portion of the aquifer tested increases. To date, such studies have all relied on different methods to determine hydraulic conductivity at each scale of interest, which raises the possibility that the observed increase in hydraulic conductivity is due to the measurement method, not to the scale. This study analyzes hydraulic conductivity with respect to scale during individual aquifer tests in porous, heterogeneous carbonate rocks in southeastern Wisconsin, USA. Results from this study indicate that hydraulic conductivity generally increases during an individual test as the volume of aquifer impacted increases, and the rate of this increase is the same as the rate of increase determined by using different measurement methods. Thus, scale dependence of hydraulic conductivity during single tests does not depend on the method of measurement. This conclusion is supported by 22 of 26 aquifer tests conducted in porous-flow-dominated carbonate units within the aquifer. Instead, scale dependency is probably caused by heterogeneities within the aquifer, a conclusion supported by digital simulation. All of the observed types of hydraulic-conductivity variations with scale during individual aquifer tests can be explained by a conceptual model of a simple heterogeneous aquifer composed of high-conductivity zones within a low-conductivity matrix. Résumé Certaines études ont montré que la conductivité hydraulique d'un aquifère semble augmenter en même temps que la partie testée de l'aquifère s'étend. Jusqu'à présent, ces études ont toutes reposé sur des méthodes de détermination de la conductivité hydraulique différentes pour chaque niveau d'échelle, ce qui a conduit à penser que l'augmentation observée de la conductivité hydraulique pouvait être due aux méthodes de mesure et non à l'effet d'échelle. Cette étude analyse la conductivité hydraulique par

  10. Geochemical evolution of a fractured zone in the cap rock of an underground carbon storage site

    Science.gov (United States)

    Vialle, S.; Druhan, J. L.; Maher, K.

    2013-12-01

    Assessment and management of environmental risks associated with underground storage of CO2 in geological systems is essential for the commercial deployment of this technology. A major risk is leakage of the CO2 from its storage reservoir, through wellbores, and along faults and fractures in the cap rock. The geochemical reactions likely to take place as CO2 leaks through a damage zone and their impact on cap rock integrity still need to be better understood and quantified. Should CO2 leakage occur, geochemical reactions would govern the environmental impact on shallow groundwater aquifers and could provide an indication of the leak prior to surface-based monitoring techniques. We used the reactive transport code TOUGH2/TOUGHREACT to model a leakage scenario through a fractured cap rock. Since geochemical reactions will strongly depend upon the local hydrodynamics of the CO2 leak, the first step of the study is to provide an appropriate physical representation of fluid flow through the system. Typically, for a low porosity rock formation, a fault/damaged zone system is composed of a core of low permeability and a damage zone with second-order fractures whose density decreases with distance from the fault core. Permeability is thus increased along the fault plane and laterally decreases down to the permeability value of the undamaged cap rock. Appropriate scaling relationships (e.g., and analytical expression of for permeability as a function of fracture aperture and fracture density), effective physical parameters as well as constitutive relationships are carefully chosen to model the fractured system, treated as an equivalent porous medium. The cap rock is initially saturated with brine (salinity of 0.15 in mass fraction) and due to overpressure in the lower storage reservoir, CO2 migrates through the damage zone. Geochemical reactions involve both salt precipitation due to the partitioning of H2O and CO2 between liquid and gas phases as well as well reactions

  11. Lipid biomarkers preserved in hydrate-associated authigenic carbonate rocks of the Gulf of Mexico

    NARCIS (Netherlands)

    Pancost, R.D.; Zhang, C.L.; Tavacoli, J.; Talbot, H.M.; Farrimond, P.; Schouten, S.; Sinninghe Damsté, J.S.; Sassen, R.

    2005-01-01

    Anaerobic oxidation of methane (AOM) is common in ocean-margin sediments, where it is mediated by consortia of Archaea and Bacteria and can result in the formation of authigenic carbonate, including extensive carbonate crusts. Previous work indicates that AOM is associated with Gulf of Mexico hydroc

  12. Molecular marker and stable carbon isotope analyses of carbonaceous Ambassador uranium ores of Mulga Rock in Western Australia

    Science.gov (United States)

    Jaraula, C.; Schwark, L.; Moreau, X.; Grice, K.; Bagas, L.

    2013-12-01

    Mulga Rock is a multi-element deposit containing uranium hosted by Eocene peats and lignites deposited in inset valleys incised into Permian rocks of the Gunbarrel Basin and Precambrian rocks of the Yilgarn Craton and Albany-Fraser Orogen. Uranium readily adsorbs onto minerals or phytoclasts to form organo-uranyl complexes. This is important in pre-concentrating uranium in this relatively young ore deposit with rare uraninite [UO2] and coffinite [U(SiO4)1-x(OH)4x], more commonly amorphous and sub-micron uranium-bearing particulates. Organic geochemical and compound-specific stable carbon isotope analyses were conducted to identify possible associations of molecular markers with uranium accumulation and to recognize effect(s) of ionizing radiation on molecular markers. Samples were collected from the Ambassador deposit containing low (2000 ppm) uranium concentrations. The bulk rock C/N ratios of 82 to 153, Rock-Eval pyrolysis yields of 316 to 577 mg hydrocarbon/g TOC (Hydrogen Index, HI) and 70 to 102 mg CO2/g TOC (Oxygen Index, OI) are consistent with a terrigenous and predominantly vascular plant OM source deposited in a complex shallow water system, ranging from lacustrine to deltaic, swampy wetland and even shallow lake settings as proposed by previous workers. Organic solvent extracts were separated into saturated hydrocarbon, aromatic hydrocarbon, ketone, and a combined free fatty acid and alcohol fraction. The molecular profiles appear to vary with uranium concentration. In samples with relatively low uranium concentrations, long-chain n-alkanes, alcohols and fatty acids derived from epicuticular plant waxes dominate. The n-alkane distributions (C27 to C31) reveal an odd/even preference (Carbon Preference Index, CPI=1.5) indicative of extant lipids. Average δ13C of -27 to -29 ‰ for long-chain n-alkanes is consistent with a predominant C3 plant source. Samples with relatively higher uranium concentrations contain mostly intermediate-length n

  13. C-, Sr-isotope stratigraphy of carbonate rocks from the Southern Espinhaço Ridge, Minas Gerais, southeastern Brazil

    Directory of Open Access Journals (Sweden)

    LUCIO M.S. FRAGA

    2014-06-01

    Full Text Available Neoproterozoic carbonate rocks comprise different stratigraphic units in the southern part of the Espinhaço Ridge, Minas Gerais, Brazil. C, O- and Sr-isotope analyses were carried out along four selected stratigraphic sections across these formations. These are: (i the Rio Pardo Grande Formation in the upper portion of the Espinhaço Supergroup, sampled in section 3; (ii Macaúbas Group laminated limestones (Tijucuçu Farm and dolostone layers (Domingas Formation have been respectively sampled along the so-called sections 1 and 2, and (iii the lower stratigraphic units of the Bambuí Group, sampled in section 4. Laminated limestone samples from the Macaúbas Group have δ13C values as high as 10.9‰ decreasing up section to -1.1‰ and 87Sr/86Sr values vary from 0.7072 to 0.7076, a range commonly observed in Cryogenian rocks. In section 2, dolomitic samples exhibit 87Sr/86Sr from 0.7076 to 0.7077 while in section 3, 87Sr/86Sr from 0.7074 to 0.7079. In section 4, 87Sr/86Sr values are around 0.7080. The values of 87Sr/86Sr observed in carbonate samples from the Macaúbas Group are similar to those observed in the Sr-isotope secular curve for the Neoproterozoic. Carbonate samples from the base of the Bambuí Group correlate with Ediacaran fingerprints, after the Marinoan (ca. 635 Ma glaciation.

  14. Integrated petrographical and petrophysical studies of some Eocene carbonate rocks, Southwest Sinai, Egypt

    Directory of Open Access Journals (Sweden)

    Hesham Abuseda

    2015-06-01

    The petrophysical behavior of the studied facies has been outlined by measuring rock porosity, density, permeability, and electrical resistivity. The reservoir quality index (RQI reveals that, the petrophysical features of the studied facies are consistent with the petrographical characteristics indicating bad reservoir properties for Thebes, Samalut, Darat and Tanka formations in the nearby subsurface extensions. Studying the petrophysical behavior indicates that, both permeability and formation resistivity factor are mostly dependent on the effective porosity and to some extent on the electric tortuosity.

  15. Fracture system influence on the reservoirs rock formation of Ordovician-Devonian carbonates in West Siberia tectonic depression

    Science.gov (United States)

    Koveshnikov, A. E.; Nesterova, A. C.; Dolgaya, T. F.

    2016-09-01

    During the Paleozoic period from the beginning of the Cambrian to the end of the Carboniferous in the boundaries of the West Siberia tectonic depression there occurred the sea, where the carbonate platforms were formed by the limestones accumulation. All the area at the end of the Carboniferous period was turned to land. Resulting from Gertsynskaya folding in the times of Permian - Triassic the formed deposits were folded and denudated to a considerable extent. Besides, the reservoir rocks of the crust of weathering including redeposited one, were formed as a result of hypergenesis, during the continental stand of the area in the near-surface zone. A new geological prospecting unit has been suggested which underlies these crusts of weathering and formed during fracture tectonic processes with hydrothermal-metasomatic limestones reworking and the processes of hydrothermal leaching and dolomitization. So, in the carbonate platforms the system of fissure zones related to tectonic disturbance was formed. This has a dendrite profile where the series of tangential, more thinned fractures deviate from the stem and finish in pores and caverns. The carbonate platforms formation in the West Siberia tectonic depression has been analyzed, their dynamics and gradual increasing from the minimal in Ordovician and Silurian to maximal at the end of the Late Devonian has been shown.

  16. Early diagenetic growth of carbonate concretions in the upper Doushantuo Formation in South China and their significance for the assessment of hydrocarbon source rock

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Mineralogical and textural characteristics and organic carbon composition of the carbonate concretions from the upper Doushantuo Formation (ca. 551 Ma) in the eastern Yangtze Gorge area reveal their early diagenetic (shallow) growth in organic-rich shale. High organic carbon content (up to 10%) and abundance of framboidal pyrites in the hosting shale suggest an anoxic or euxinic depositional environment. Well-preserved cardhouse clay fabrics in the concretions suggest their formation at 0-3 m burial depth, likely associated with microbial decomposition of organic matter and anaerobic oxidation of methane. Gases through decomposition of organic matter and/or from methanogenesis created bubbles and cavities, and anaerobic methane oxidation at the sulfate reduction zone resulted in carbonate precipitation, filling in bubbles and cavities to form spherical structures of the concretions. Rock pyrolysis analyses show that the carbonate concretions have lower total organic carbon (TOC) content but higher effective carbon than those in the host rocks. This may be caused by enclosed organic matter in pores of the concretions so that organic matter was protected from further modification during deep burial and maintained high hydrocarbon generating potential even in over-matured source rock. As a microbialite sensu latu, concretions have special growth conditions and may provide important information on the microbial activities in depositional and early burial environments.

  17. Assessing potential diagenetic alteration of primary iodine-to-calcium ratios in carbonate rocks

    Science.gov (United States)

    Hardisty, D. S.; Lu, Z.; Swart, P. K.; Planavsky, N.; Gill, B. C.; Loyd, S. J.; Lyons, T. W.

    2015-12-01

    We have evaluated iodine-to-calcium (I/Ca) ratios from a series of carbonate samples with well-constrained histories of diagenetic alteration to assess the likelihood of overprints on primary water column-derived signals. Because only the oxidized iodine species, iodate, is incorporated during carbonate precipitation, I/Ca ratios have strong potential as proxies for both marine redox and carbon cycling. This utility lies with the combination of iodate's redox sensitivity as well as the close association between iodine and marine organic matter. However, despite the possibility of large pore water iodine enrichments relative to overlying seawater, carbonate alteration under reducing diagenetic conditions, and iodate-to-iodide reduction, no study has assessed the prospect of diagenetic alteration of primary I/Ca ratios. Here, we evaluated aragonite-to-calcite transformations and dolomitization within the Key Largo Limestone of South Florida and the Clino and Unda drill cores of the Bahamas Bank. Also, early burial diagenesis was studied through analysis of I/Ca ratios in short cores from a variety of shallow settings within the Exuma Bay, Bahamas. Further, we evaluated authigenic carbonates through analysis of iodine in concretions constrained to have formed during varying stages of evolving pore fluid chemistry. In all cases, I/Ca ratios show the potential for diagenetic iodine loss relative to water-column derived values, consistent with observations of quantitative reduction of dissolved iodate to iodide in pore waters before or synchronous with carbonate alteration. In no case, however, did we observe an increase in I/Ca during diagenetic transformation. Our results suggest both that primary I/Ca values and trends can be preserved but that maximum I/Ca ratios should be considered a minimum estimate of seawater iodate. We recommend that ancient carbonates with distinct I/Ca trends not indicative of diagenetic iodine loss reflect preservation of or very early

  18. Reactivity of Hontomín carbonate rocks to acidic solution injection: reactive "push-pull" tracer tests results

    Science.gov (United States)

    De Gaspari, Francesca; Cabeza, Yoar; Luquot, Linda; Rötting, Tobias; Saaltink, Maarten W.; Carrera, Jesus

    2014-05-01

    Several field tests will be carried out in order to characterize the reservoir for CO2 injection in Hontomín (Burgos, Spain) as part of the Compostilla project of "Fundación Ciudad de la Energía" (CIUDEN). Once injected, the dissolution of the CO2 in the resident brine will increase the acidity of the water and lead to the dissolution of the rocks, constituted mainly by carbonates. This mechanism will cause changes in the aquifer properties such as porosity and permeability. To reproduce the effect of the CO2 injection, a reactive solution with 2% of acetic acid is going to be injected in the reservoir and extracted from the same well (reactive "push-pull" tracer tests) to identify and quantify the geochemical reactions occurring into the aquifer. The reactivity of the rock will allow us also to evaluate the changes of its properties. Previously, theoretical calculations of Damkhöler numbers were done to determine the acid concentrations and injection flow rates needed to generate ramified-wormholes patterns, during theses "push-pull" experiments. The aim of this work is to present the results and a preliminary interpretation of the field tests.

  19. Groundwater quality in the Valley and Ridge and Piedmont and Blue Ridge carbonate-rock aquifers, eastern United States

    Science.gov (United States)

    Lindsey, Bruce; Belitz, Kenneth

    2017-01-19

    Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water. The Valley and Ridge and Piedmont and Blue Ridge carbonate-rock aquifers constitute two of the important areas being evaluated. One or more inorganic constituents with human-health benchmarks were detected at high concentrations in about 15 percent of the study area and at moderate concentrations in about 17 percent. Organic constituents were not detected at high concentrations in the study area. One or more organic constituents with human-health benchmarks were detected at moderate concentrations in about 2 percent of the study area.

  20. How the rock fabrics can control the physical properties - A contribution to the understanding of carbonate reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Duerrast, H.; Siegesmund, S. [Goettingen Univ. (Germany)

    1998-12-31

    The correlation between microfabrics and physical properties will be illustrated in detail on three dolomitic carbonate reservoir rocks with different porosity. For this study core segments from the Zechstein Ca2-layer (Permian) of the Northwest German Basin were kindly provided by the Preussag Energie GmbH, Lingen. The mineral composition was determined by using the X-ray diffraction method. Petrographic and detailed investigation of the microfabrics, including the distribution and orientation of the cracks were done macroscopally (core segments) and microscopally with the optical microscope and the Scanning Electron Microscope (thin sections in three orthogonally to each other oriented directions). Different kinds of petrophysical measurements were carried out, e.g. porosity, permeability, electrical conductivity, seismic velocities. (orig.)

  1. The relationship between carbonate facies, volcanic rocks and plant remains in a late Palaeozoic lacustrine system (San Ignacio Fm, Frontal Cordillera, San Juan province, Argentina)

    Science.gov (United States)

    Busquets, P.; Méndez-Bedia, I.; Gallastegui, G.; Colombo, F.; Cardó, R.; Limarino, O.; Heredia, N.; Césari, S. N.

    2013-07-01

    The San Ignacio Fm, a late Palaeozoic foreland basin succession that crops out in the Frontal Cordillera (Argentinean Andes), contains lacustrine microbial carbonates and volcanic rocks. Modification by extensive pedogenic processes contributed to the massive aspect of the calcareous beds. Most of the volcanic deposits in the San Ignacio Fm consist of pyroclastic rocks and resedimented volcaniclastic deposits. Less frequent lava flows produced during effusive eruptions led to the generation of tabular layers of fine-grained, greenish or grey andesites, trachytes and dacites. Pyroclastic flow deposits correspond mainly to welded ignimbrites made up of former glassy pyroclasts devitrified to microcrystalline groundmass, scarce crystals of euhedral plagioclase, quartz and K-feldspar, opaque minerals, aggregates of fine-grained phyllosilicates and fiammes defining a bedding-parallel foliation generated by welding or diagenetic compaction. Widespread silicified and silica-permineralized plant remains and carbonate mud clasts are found, usually embedded within the ignimbrites. The carbonate sequences are underlain and overlain by volcanic rocks. The carbonate sequence bottoms are mostly gradational, while their tops are usually sharp. The lower part of the carbonate sequences is made up of mud which appear progressively, filling interstices in the top of the underlying volcanic rocks. They gradually become more abundant until they form the whole of the rock fabric. Carbonate on volcanic sandstones and pyroclastic deposits occur, with the nucleation of micritic carbonate and associated production of pyrite. Cyanobacteria, which formed the locus of mineral precipitation, were related with this nucleation. The growth of some of the algal mounds was halted by the progressive accumulation of volcanic ash particles, but in most cases the upper boundary is sharp and suddenly truncated by pyroclastic flows or volcanic avalanches. These pyroclastic flows partially destroyed the

  2. Genesis of Pb-Zn-Cu-Ag Deposits within Permian Carboniferous-Carbonate Rocks in Madina Regency, North Sumatra

    Directory of Open Access Journals (Sweden)

    Bhakti Hamonangan Harahap

    2015-11-01

    Full Text Available Strong mineralized carbonate rock-bearing Pb-Zn-Cu-Ag-(Au ores are well exposed on the Latong River area, Madina Regency, North Sumatra Province. The ore deposit is hosted within the carbonate rocks of the Permian to Carboniferous Tapanuli Group. It is mainly accumulated in hollows replacing limestone in the forms of lensoidal, colloform, veins, veinlets, cavity filling, breccia, and dissemination. The ores dominantly consist of galena (126 000 ppm Pb and sphalerite (2347 ppm Zn. The other minerals are silver, azurite, covellite, pyrite, marcasite, and chalcopyrite. This deposit was formed by at least three phases of mineralization, i.e. pyrite and then galena replaced pyrite, sphalerite replaced galena, and pyrite. The last phase is the deposition of chalcopyrite that replaced sphalerite. The Latong sulfide ore deposits posses Pb isotope ratio of 206Pb/204Pb = 19.16 - 20.72, 207Pb/204Pb = 16.16 - 17.29, and 208Pb/204Pb = 42.92 - 40.78. The characteristic feature of the deposit indicates that it is formed by a sedimentary process rather than an igneous activity in origin. This leads to an interpretation that the Latong deposit belongs to the Sedimentary Hosted Massive Sulfide (SHMS of Mississippi Valley-Type (MVT. The presence of SHMS in the island arc such as Sumatra has become controversial. For a long time, ore deposits in the Indonesian Island Arc are always identical with the porphyry and hydrothermal processes related to arc magmatism. This paper is dealing with the geology of Latong and its base metal deposits. This work is also to interpret their genesis as well as general relationship to the regional geology and tectonic setting of Sumatra.

  3. MULTIDISCIPLINARY IMAGING OF ROCK PROPERTIES IN CARBONATE RESERVOIRS FOR FLOW-UNIT TARGETING

    Energy Technology Data Exchange (ETDEWEB)

    Stephen C. Ruppel

    2005-02-01

    Despite declining production rates, existing reservoirs in the US contain large quantities of remaining oil and gas that constitute a huge target for improved diagnosis and imaging of reservoir properties. The resource target is especially large in carbonate reservoirs, where conventional data and methodologies are normally insufficient to resolve critical scales of reservoir heterogeneity. The objectives of the research described in this report were to develop and test such methodologies for improved imaging, measurement, modeling, and prediction of reservoir properties in carbonate hydrocarbon reservoirs. The focus of the study is the Permian-age Fullerton Clear Fork reservoir of the Permian Basin of West Texas. This reservoir is an especially appropriate choice considering (a) the Permian Basin is the largest oil-bearing basin in the US, and (b) as a play, Clear Fork reservoirs have exhibited the lowest recovery efficiencies of all carbonate reservoirs in the Permian Basin.

  4. Modeling and interpretation of Q logs in carbonate rock using a double porosity model and well logs

    Science.gov (United States)

    Parra, Jorge O.; Hackert, Chris L.

    2006-03-01

    Attenuation data extracted from full waveform sonic logs is sensitive to vuggy and matrix porosities in a carbonate aquifer. This is consistent with the synthetic attenuation (1 / Q) as a function of depth at the borehole-sonic source-peak frequency of 10 kHz. We use velocity and densities versus porosity relationships based on core and well log data to determine the matrix, secondary, and effective bulk moduli. The attenuation model requires the bulk modulus of the primary and secondary porosities. We use a double porosity model that allows us to investigate attenuation at the mesoscopic scale. Thus, the secondary and primary porosities in the aquifer should respond with different changes in fluid pressure. The results show a high permeability region with a Q that varies from 25 to 50 and correlates with the stiffer part of the carbonate formation. This pore structure permits water to flow between the interconnected vugs and the matrix. In this region the double porosity model predicts a decrease in the attenuation at lower frequencies that is associated with fluid flowing from the more compliant high-pressure regions (interconnected vug space) to the relatively stiff, low-pressure regions (matrix). The chalky limestone with a low Q of 17 is formed by a muddy porous matrix with soft pores. This low permeability region correlates with the low matrix bulk modulus. A low Q of 18 characterizes the soft sandy carbonate rock above the vuggy carbonate. This paper demonstrates the use of attenuation logs for discriminating between lithology and provides information on the pore structure when integrated with cores and other well logs. In addition, the paper demonstrates the practical application of a new double porosity model to interpret the attenuation at sonic frequencies by achieving a good match between measured and modeled attenuation.

  5. Low Ni olivine in silica-undersaturated ultrapotassic igneous rocks as evidence for carbonate metasomatism in the mantle

    Science.gov (United States)

    Ammannati, Edoardo; Jacob, Dorrit E.; Avanzinelli, Riccardo; Foley, Stephen F.; Conticelli, Sandro

    2016-06-01

    Subduction drags a large amount of CO2 into the Earth's interior, which is partly returned to the atmosphere by arc volcanism. Processes involved in the recycling of subducted carbon within the upper mantle are mainly related to mineralogical transformation. Subducted CO2 may dramatically affect the equilibria among peridotitic minerals (olivine vs. pyroxenes) changing their stability fields and hence their modal abundances. This process is accompanied by a subduction-induced change in the budget of some incompatible trace and major elements (e.g., K, Ca, HFSE), whereas it has a minimal effect on the mass balance of compatible elements (e.g., Ni). We report trace elements in olivine in subduction-related mafic alkaline ultrapotassic rocks from Italy, which are used as a proxy to define mantle wedge mineralogy and metasomatic processes. Minor element concentrations, and in particular the high Li and low Ti of all the olivines, confirm a major role for recycled sediment in the generation of Italian ultrapotassic magmas. The distinct contents of Ni, Mn, and Ca in olivine reflect the bimodal character of silica-rich and silica-poor ultrapotassic Italian rocks and constrain two distinct mineralogical reactions between metasomatic agents and peridotite. Olivine chemistry from silica-saturated rocks reflects the reaction of silicate melts with the ambient mantle, with consequent consumption of olivine in favour of orthopyroxene. In contrast, the low-Ni, high-Mn/Fe of olivine crystallised from silica-undersaturated leucitites require a mantle source enriched in olivine (and clinopyroxene) compared to orthopyroxene, as a result of the interaction between the ambient peridotitic mantle and CaCO3-rich metasomatic agents. The change from silica-oversaturated lamproites to silica-undersaturated leucitites and thus the difference in the olivine composition is due to a change in composition of the subducting sediment from pelitic to carbonate-rich. The results of this study

  6. Geochemical features of the geothermal CO2-water-carbonate rock system and analysis on its CO2 sources--Examples from Huanglong Ravine and Kangding, Sichuan, and Xiage, Zhongdian, Yunnan

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Taking Huanglong Ravine and Kangding, Sichuan, and Xiage, Zhongdian, Yunnan, as examples, the authors summarize the hydrogeochemical and carbon stable isotopic features of the geothermal CO2-water-carbonate rock system and analyze the CO2 sources of the system. It was found that the hydrogeochemical and carbon stable isotopic features of such a system are different from those of shallow CO2-water-carbonate rock system, which is strongly influenced by biosphere. The former has higher CO2 partial pressure, and is rich in heavy carbon stable isotope. In addition, such a geothermal system is also different from that developed in igneous rock. The water in the latter system lacks Ca2+, and thus, there are few tufa deposits on ground surface, but it is rich in light carbon stable isotope. Further analysis shows that CO2 of the geothermal CO2-water-carbonate rock system is a mixture of metamorphic CO2 and magmatic CO2.

  7. delta 15N and non-carbonate delta 13C values for two petroleum source rock reference materials and a marine sediment reference material

    Science.gov (United States)

    Dennen, Kristin O.; Johnson, Craig A.; Otter, Marshall L.; Silva, Steven R.; Wandless, Gregory A.

    2006-01-01

    Samples of United States Geological Survey (USGS) Certified Reference Materials USGS Devonian Ohio Shale (SDO-1), and USGS Eocene Green River Shale (SGR-1), and National Research Council Canada (NRCC) Certified Marine Sediment Reference Material (PACS-2), were sent for analysis to four separate analytical laboratories as blind controls for organic rich sedimentary rock samples being analyzed from the Red Dog mine area in Alaska. The samples were analyzed for stable isotopes of carbon (delta13Cncc) and nitrogen (delta15N), percent non-carbonate carbon (Wt % Cncc) and percent nitrogen (Wt % N). SDO-1, collected from the Huron Member of the Ohio Shale, near Morehead, Kentucky, and SGR-1, collected from the Mahogany zone of the Green River Formation are petroleum source rocks used as reference materials for chemical analyses of sedimentary rocks. PACS-2 is modern marine sediment collected from the Esquimalt, British Columbia harbor. The results presented in this study are, with the exceptions noted below, the first published for these reference materials. There are published information values for the elemental concentrations of 'organic' carbon (Wt % Corg measured range is 8.98 - 10.4) and nitrogen (Wt % Ntot 0.347 with SD 0.043) only for SDO-1. The suggested values presented here should be considered 'information values' as defined by the NRCC Institute for National Measurement Reference Materials and should be useful for the analysis of 13C, 15N, C and N in organic material in sedimentary rocks.

  8. A Discussion of Concavo-Convex Contacts between Oolites and Quartz Grains in Mixed Siliciclastic-Carbonate Rocks in Huanghua Basin, China

    Institute of Scientific and Technical Information of China (English)

    Ma Yanping; Liu Li

    2002-01-01

    Concavo-convex contacrs between oolites and quartz grains are observed in mixed siliciclastic-carbonate rocks of the lower part of number 1 of Shahejie Formation, beach area, Dagang. Thin sections observation shows that oolite is convex in quartz grain, and oolite is complete. A possible explanation for it is pressure dissolution under alkaline fluid.

  9. Acid neutralizing capacity and leachate results for igneous rocks, with associated carbon contents of derived soils, Animas River AML site, Silverton, Colorado

    Science.gov (United States)

    Yager, Douglas B.; Stanton, Mark R.; Choate, LaDonna M.; Burchell,

    2009-01-01

    Mine planning efforts have historically overlooked the possible acid neutralizing capacity (ANC) that local igneous rocks can provide to help neutralize acidmine drainage. As a result, limestone has been traditionally hauled to mine sites for use in neutralizing acid drainage. Local igneous rocks, when used as part of mine life-cycle planning and acid mitigation strategy, may reduce the need to transport limestone to mine sites because these rocks can contain acid neutralizing minerals. Igneous hydrothermal events often introduce moderately altered mineral assemblages peripheral to more intensely altered rocks that host metal-bearing veins and ore bodies. These less altered rocks can contain ANC minerals (calcite-chlorite-epidote) and are referred to as a propylitic assemblage. In addition, the carbon contents of soils in areas of new mining or those areas undergoing restoration have been historically unknown. Soil organic carbon is an important constituent to characterize as a soil recovery benchmark that can be referred to during mine cycle planning and restoration. This study addresses the mineralogy, ANC, and leachate chemistry of propylitic volcanic rocks that host polymetallic mineralization in the Animas River watershed near the historical Silverton, Colorado, mining area. Acid titration tests on volcanic rocks containing calcite (2 – 20 wt %) and chlorite (6 – 25 wt %), have ANC ranging from 4 – 146 kg/ton CaCO3 equivalence. Results from a 6-month duration, kinetic reaction vessel test containing layered pyritic mine waste and underlying ANC volcanic rock (saturated with deionized water) indicate that acid generating mine waste (pH 2.4) has not overwhelmed the ANC of propylitic volcanic rocks (pH 5.8). Sequential leachate laboratory experiments evaluated the concentration of metals liberated during leaching. Leachate concentrations of Cu-Zn-As-Pb for ANC volcanic rock are one-to-three orders of magnitude lower when compared to leached solution from

  10. Reservoir Modeling of Carbonate on Fika Field: The Challenge to Capture the Complexity of Rock and Oil Types

    Directory of Open Access Journals (Sweden)

    Erawati Fitriyani Adji

    2014-09-01

    Full Text Available DOI: 10.17014/ijog.v1i2.181The carbonate on Fika Field has a special character, because it grew above a basement high with the thickness and internal character variation. To develop the field, a proper geological model which can be used in reservoir simulation was needed. This model has to represent the complexity of the rock type and the variety of oil types among the clusters. Creating this model was challenging due to the heterogeneity of the Baturaja Formation (BRF: Early Miocene reef, carbonate platform, and breccia conglomerate grew up above the basement with a variety of thickness and quality distributions. The reservoir thickness varies between 23 - 600 ft and 3D seismic frequency ranges from 1 - 80 Hz with 25 Hz dominant frequency. Structurally, the Fika Field has a high basement slope, which has an impact on the flow unit layering slope. Based on production data, each area shows different characteristics and performance: some areas have high water cut and low cumulative production. Oil properties from several clusters also vary in wax content. The wax content can potentially build up a deposit inside tubing and flow-line, resulted in a possible disturbance to the operation. Five well cores were analyzed, including thin section and XRD. Seven check-shot data and 3D seismic Pre-Stack Time Migration (PSTM were available with limited seismic resolution. A seismic analysis was done after well seismic tie was completed. This analysis included paleogeography, depth structure map, and distribution of reservoir and basement. Core and log data generated facies carbonate distribution and rock typing, defining properties for log analysis and permeability prediction for each zone. An Sw prediction for each well was created by J-function analysis. This elaborates capillary pressure from core data, so it is very similar to the real conditions. Different stages of the initial model were done i.e. scale-up properties, data analysis, variogram modeling

  11. Rock Magnetic Cyclostratigraphy of the Edicaran Doushantuo Formation, South China: Determining the Duration of the Shuram Carbon Isotope Excursion

    Science.gov (United States)

    Gong, Z.; Kodama, K. P.; Li, Y. X.

    2015-12-01

    To determine the duration of the Shuram carbon-isotope excursion (SE), we conducted paleomagnetic, rock magnetic, and carbon isotopic studies of the Ediacaran Doushantuo Formation at the Dongdahe-Feidatian section near Chengjiang in South China. Zhu et al. (2007)1 indicate that the SE is 97.4 ± 9.5 m thick at this locality. The SE may record the oxidation of the ocean just before the Cambrian explosion. We collected unoriented samples for rock magnetic cyclostratigraphy at 10 cm intervals for 68 m of the Dongdahe section and 101 oriented cores at 2-3 m intervals for paleomagnetism. Comparing our carbon isotope measurements, made on chips from the cores, to Zhu et al.'s previous work shows that the Dongdahe section records 70% of the excursion. The paleomagnetic samples were alternating field and thermally demagnetized, but were totally remagnetized in the present day geomagnetic field (D=358˚, I=38˚). Multi-taper method spectral analysis of the mass-normalized susceptibility of the 600 unoriented samples revealed six strong spectral peaks that rose above the 95% confidence limits of the robust red noise. The stratigraphic thickness of these cycles is 410, 89.3, 32.5, 27.6, 22.1 and 20.9 cm. A smaller peak with a wavelength of 110 cm was also observed. Based on the ratios of these wavelengths we interpret them to be astronomically-forced. If the 410 cm peak is set to long eccentricity (405 kyr), then the other peaks yield near-Milankovitch periods of short eccentricity (109 and 88 kyr), obliquity (32 and 27 kyr), and precession (22 and 21 kyr). A strong peak with a wavelength of 1710 cm was also observed, but is not interpreted to be orbitally-forced. The sediment accumulation rate for the Dongdahe section is 1 cm/kyr making the duration of the SE in South China 9.74 ± 0.95 Myr, in excellent agreement with estimates from Australia and California, thus supporting a primary origin for the SE and possibly the cause of the Cambrian explosion. 1PPP 254 7-61

  12. Reactive Flow Experiments to Characterize Porosity and Permeability Evolution during CO2 Transport in Weyburn-Midale Carbonate Rocks

    Science.gov (United States)

    Smith, M. M.; Sholokhova, Y.; Hao, Y.; Carroll, S.

    2011-12-01

    We investigated the relative effects of CO2-induced disequilibrium and pre-existing mineralogy and void space heterogeneity on permeability development in carbonate core samples from the Weyburn-Midale hydrocarbon reservoir (Canada). The aim of our work was to use detailed pre- and post-experimental x-ray computed tomography (XCMT) imaging, as well as geochemical data, to constrain reactive transport models that predict the evolution of pore space and permeability for geologic storage of CO2 in enhanced oil recovery (EOR) fields. A total of nine core-flooding experiments were completed, using three distinct rock types (tight limestone, porous dolostone, and evaporite caprock) to represent the range of natural reservoir physical and chemical heterogeneity. Experiments were conducted under 25 MPa confining pressure, 60C temperature, and elevated salinity conditions, with pCO2 levels from 0.5-3 MPa. The coupling of intensive characterization with pressure/permeability and solution chemistry measurements provided powerful tools for interpreting and correlating mineral reactions and stability with pre-existing features and heterogeneities. We observed increased carbonate mass transfer rates, stable dissolution fronts, and greater volumes of dissolved minerals for cores with relatively homogeneous pore networks. Samples with more heterogeneous pore size distributions responded with variable mass transfer rates and development of fast transport pathways in regions with preexisting fractures. We infer that the breakthrough of these preferential fluid pathways leads to reductions in available reactive surface area, allowing undersaturated fluids to be transported through the cores despite relatively fast carbonate dissolution kinetics.

  13. Summary of Radionuclide Reactive Transport Experiments in Fractured Tuff and Carbonate Rocks from Yucca Flat, Nevada Test Site

    Energy Technology Data Exchange (ETDEWEB)

    Zavarin, M; Roberts, S; Reimus, P; Johnson, M

    2006-10-11

    , Mercury, Nevada. Readers are referred to the original reports ''Radionuclide Transport in Tuff and Carbonate Fractures from Yucca Flat, Nevada Test Site'' (Zavarin et al., 2005) and ''Radionuclide Sorption and Transport in Fractured Rocks of Yucca Flat, Nevada Test Site'' (Ware et al., 2005) for specific details not covered in this summary report.

  14. Preliminary investigations on the carbon dioxide sequestering potential of the ultramafic rock

    Energy Technology Data Exchange (ETDEWEB)

    Goff, F.; Guthrie, G.; Counce, D.; Kluk, E.; Bergfeld, D.; Snow, M.

    1997-08-01

    Fossil fuels continue to provide major sources of energy to the modern world even though global emissions of CO{sub 2} are presently at levels of 19 Gt/yr. Future antipollution measures may include sequestering of waste CO{sub 2} as magnesite (MgCO{sub 3}) by processing ultramafic rocks to obtain reactable Mg. Huge ultramafic deposits consisting of relatively pure Mg-rich silicates exist throughout much of the world in ophiolites and layered intrusions. Peridotites (especially dunites) and serpentinites comprise the best ores because they contain the most Mg by weight and are relatively reactive to hot acids such as HCl. Although mining such deposits on a large scale would have environmental impacts, the sequestering process could provide Cr, Ni, and other metals as byproducts and could dispose of existing waste (white) asbestos. Small ultramafic bodies ({approximately} 1 km{sup 3}) can potentially sequester about 1 Gt of CO{sub 2} or about 20% of annual US emissions. A single large deposit of dunite ({approximately} 30 km{sup 3}) could dispose of about 20 yr of current US CO{sub 2} emissions. The cost and environmental impact of mining these deposits must be weighed against the increased costs of energy and benefits to the atmosphere and climate.

  15. Strontium Isotopic Composition of Paleozoic Carbonate Rocks in the Nevada Test Site Vicinity, Clark, Lincoln, and Nye Counties, Nevada, and Inyo County, California

    Science.gov (United States)

    Paces, James B.; Peterman, Zell E.; Futo, Kiyoto; Oliver, Thomas A.; Marshall, Brian D.

    2007-01-01

    Ground water moving through permeable Paleozoic carbonate rocks represents the most likely pathway for migration of radioactive contaminants from nuclear weapons testing at the Nevada Test Site, Nye County, Nevada. The strontium isotopic composition (87Sr/86Sr) of ground water offers a useful means of testing hydrochemical models of regional flow involving advection and reaction. However, reaction models require knowledge of 87Sr/86Sr data for carbonate rock in the Nevada Test Site vicinity, which is scarce. To fill this data gap, samples of core or cuttings were selected from 22 boreholes at depth intervals from which water samples had been obtained previously around the Nevada Test Site at Yucca Flat, Frenchman Flat, Rainier Mesa, and Mercury Valley. Dilute acid leachates of these samples were analyzed for a suite of major- and trace-element concentrations (MgO, CaO, SiO2, Al2O3, MnO, Rb, Sr, Th, and U) as well as for 87Sr/86Sr. Also presented are unpublished analyses of 114 Paleozoic carbonate samples from outcrops, road cuts, or underground sites in the Funeral Mountains, Bare Mountain, Striped Hills, Specter Range, Spring Mountains, and ranges east of the Nevada Test Site measured in the early 1990's. These data originally were collected to evaluate the potential for economic mineral deposition at the potential high-level radioactive waste repository site at Yucca Mountain and adjacent areas (Peterman and others, 1994). Samples were analyzed for a suite of trace elements (Rb, Sr, Zr, Ba, La, and Ce) in bulk-rock powders, and 87Sr/86Sr in partial digestions of carbonate rock using dilute acid or total digestions of silicate-rich rocks. Pre-Tertiary core samples from two boreholes in the central or western part of the Nevada Test Site also were analyzed. Data are presented in tables and summarized in graphs; however, no attempt is made to interpret results with respect to ground-water flow paths in this report. Present-day 87Sr/86Sr values are compared to values

  16. Strontium Isotopic Composition of Paleozoic Carbonate Rocks in the Nevada Test Site Vicinity, Clark, Lincoln, and Nye Counties, Nevada and Inyo County, California.

    Energy Technology Data Exchange (ETDEWEB)

    James B. Paces; Zell E. Peterman; Kiyoto Futa; Thomas A. Oliver; and Brian D. Marshall.

    2007-08-07

    Ground water moving through permeable Paleozoic carbonate rocks represents the most likely pathway for migration of radioactive contaminants from nuclear weapons testing at the Nevada Test Site, Nye County, Nevada. The strontium isotopic composition (87Sr/86Sr) of ground water offers a useful means of testing hydrochemical models of regional flow involving advection and reaction. However, reaction models require knowledge of 87Sr/86Sr data for carbonate rock in the Nevada Test Site vicinity, which is scarce. To fill this data gap, samples of core or cuttings were selected from 22 boreholes at depth intervals from which water samples had been obtained previously around the Nevada Test Site at Yucca Flat, Frenchman Flat, Rainier Mesa, and Mercury Valley. Dilute acid leachates of these samples were analyzed for a suite of major- and trace-element concentrations (MgO, CaO, SiO2, Al2O3, MnO, Rb, Sr, Th, and U) as well as for 87Sr/86Sr. Also presented are unpublished analyses of 114 Paleozoic carbonate samples from outcrops, road cuts, or underground sites in the Funeral Mountains, Bare Mountain, Striped Hills, Specter Range, Spring Mountains, and ranges east of the Nevada Test Site measured in the early 1990's. These data originally were collected to evaluate the potential for economic mineral deposition at the potential high-level radioactive waste repository site at Yucca Mountain and adjacent areas (Peterman and others, 1994). Samples were analyzed for a suite of trace elements (Rb, Sr, Zr, Ba, La, and Ce) in bulk-rock powders, and 87Sr/86Sr in partial digestions of carbonate rock using dilute acid or total digestions of silicate-rich rocks. Pre-Tertiary core samples from two boreholes in the central or western part of the Nevada Test Site also were analyzed. Data are presented in tables and summarized in graphs; however, no attempt is made to interpret results with respect to ground-water flow paths in this report. Present-day 87Sr/86Sr values are compared to

  17. Isotope studies of carbonate rocks of La Luna Formation (Venezuela) to constrain the oceanic anoxic event 3 (OAE3)

    Science.gov (United States)

    Machado, M. C.; Chemale, F., Jr.; Kawashita, K.; Rey, O.; Moura, C. A. V.

    2016-12-01

    87Sr/86Sr ratios, δ13C, and δ18O determinations performed on 30 bulk carbonate rocks are presented to constrain the isotope characteristics regarding Oceanic Anoxic Event 3 in the La Luna Formation, Maracaibo Basin. The samples were collected along a 22 m profile in San Miguel region (Merida State, Venezuela). The exhibited 87Sr/86Sr ratios are between 0.707659, at the base, and 0.707733 at the top of studied section, corresponding estimated younger numerical ages than the inferred ages dated as Santonian (85.8-83.5 Ma) based on occurrence of Dicarinella asymetrica. The obtained 87Sr/86Sr ratios are certainly higher than expected for Santonian sea Sr and they are attributed to regular riverine strontium fluxes in the restricted (gulf-like) Maracaibo Basin. The values of δ18O data between -3.76‰ and -11.76‰ are distributed in two distinct clusters in a same way and coherent as for δ13C data which are in a range between -1.75‰ and -13.87‰. One of the clusters δ13C = -2.5 ± 1.0‰ and δ18O = -10.0 ± 1.5‰), illustrate the homogeneous marine deposition under tropical conditions, while the other, more variable, probably could reflect the cyclicity of temporally changes in Pacific versus Atlantic Ocean circulation with cooling water or cooling trend climate. These δ13C values around -2.5 ± 1.0‰ do not fit with the significant carbon isotope excursion as expected for the oceanic anoxic event (OAE) and support the work hypothesis that Coniacian-Santonian anoxic event (denominate as OAE3) is not a global one.

  18. Influence of Intrinsic Colloid Formation on Migration of Cerium through Fractured Carbonate Rock.

    Science.gov (United States)

    Tran, Emily L; Klein-BenDavid, Ofra; Teutsch, Nadya; Weisbrod, Noam

    2015-11-17

    Migration of colloids may facilitate the transport of radionuclides leaked from near surface waste sites and geological repositories. Intrinsic colloids are favorably formed by precipitation with carbonates in bicarbonate-rich environments, and their migration may be enhanced through fractured bedrock. The mobility of Ce(III) as an intrinsic colloid was studied in an artificial rainwater solution through a natural discrete chalk fracture. The results indicate that at variable injection concentrations (between 1 and 30 mg/L), nearly all of the recovered Ce takes the form of an intrinsic colloid of >0.45 μm diameter, including in those experiments in which the inlet solution was first filtered via 0.45 μm. In all experiments, these intrinsic colloids reached their maximum relative concentrations prior to that of the Br conservative tracer. Total Ce recovery from experiments using 0.45 μm filtered inlet solutions was only about 0.1%, and colloids of >0.45 μm constituted the majority of recovered Ce. About 1% of Ce was recovered when colloids of >0.45 μm were injected, indicating the enhanced mobility and recovery of Ce in the presence of bicarbonate.

  19. Variation in stable carbon isotopes in organic matter from the Gunflint Iron Formation. [Precambrian rock analysis

    Science.gov (United States)

    Barghoorn, E. S.; Knoll, A. H.; Dembicki, H., Jr.; Meinschein, W. G.

    1977-01-01

    Results are presented for an isotopic analysis of the kerogen separated from 15 samples of the Gunflint Iron Formation, Ontario, and the conformably overlying Rove Formation. Reasons for which the Gunflint Iron Formation is suitable for such a study of a single Precambrian formation are identified. The general geology of the formation is outlined along with sample selection, description, and preparation. Major conclusions are that the basal Gunflint algal chert and shale facies are depleted in C-13 relative to the chert-carbonate and taconite facies, that differences in the delta C-13 values between Gunflint facies correlate with marked differences in their biological source materials as evidenced by their respective microbiotas, that the anthraxolites are anomalously depleted in C-13 relative to the kerogen of their encompassing cherts and shales, and that the effects of igneous intrusion and concomitant thermal alteration are shown by a marked loss of C-12 at the contact. The demonstration that not all kerogens are isotopically alike stresses the importance of facies data to the interpretation of C-13/C-12 ratios of ancient organic matter.

  20. Alkali-aggregate reactivity of typical siliceious glass and carbonate rocks in alkali-activated fly ash based geopolymers

    Science.gov (United States)

    Lu, Duyou; Liu, Yongdao; Zheng, Yanzeng; Xu, Zhongzi; Shen, Xiaodong

    2013-08-01

    For exploring the behaviour of alkali-aggregate reactivity (AAR) in alkali-activated geopolymeric materials and assessing the procedures for testing AAR in geopolymers, the expansion behaviour of fly ash based geopolymer mortars with pure silica glass and typical carbonate rocks were studied respectively by curing at various conditions, i.e. 23°C and 38°C with relative humidity over 95%, immersed in 1M NaOH solution at 80°C. Results show that, at various curing conditions, neither harmful ASR nor harmful ACR was observed in geopolymers with the criteria specified for OPC system. However, with the change of curing conditions, the geopolymer binder and reactive aggregates may experience different reaction processes leading to quite different dimensional changes, especially with additional alkalis and elevated temperatures. It suggests that high temperature with additional alkali for accelerating AAR in traditional OPC system may not appropriate for assessing the alkali-aggregate reactivity behaviour in geopolymers designed for normal conditions. On the other hand, it is hopeful to control the dimensional change of geopolymer mortar or concrete by selecting the type of aggregates and the appropriate curing conditions, thus changing the harmful AAR in OPC into beneficial AAR in geopolymers and other alkali-activated cementitious systems.

  1. ADVANCED CHARACTERIZATION OF FRACTURED RESERVOIRS IN CARBONATE ROCKS: THE MICHIGAN BASIN

    Energy Technology Data Exchange (ETDEWEB)

    James R. Wood; William B. Harrison

    2002-12-01

    Michigan Basin, and it is crucial in developing reservoir quality rocks in some fields. Data on the occurrence of dolomite was extracted from driller's reports for all reported occurrences in Michigan, nearly 50 fields and over 500 wells. A digital database was developed containing the geographic location of all these wells (latitude-longitude) as well as the elevation of the first encounter of dolomite in the field/reservoir. Analysis shows that these dolomite occurrences are largely confined to the center of the basin, but with some exceptions, such as N. Adams Field. Further, some of the dolomite occurrences show a definite relationship to the fracture pattern described above, suggesting a genetic relationship that needs further work. Other accomplishments of this past reporting period include obtaining a complete land grid for the State of Michigan and further processing of the high and medium resolution DEM files. We also have measured new fluid inclusion data on dolomites from several fields that suggest that the dolomitization occurred at temperatures between 100 and 150 C. Finally, we have extracted the lithologic data for about 5000 wells and are in the process of integrating this data into the overall model for the Michigan Basin.

  2. Quantifying the pluri-centennial soil organic carbon pool using Rock-Eval pyrolysis

    Science.gov (United States)

    Cécillon, Lauric; Baudin, François; Chenu, Claire; Christensen, Bent T.; Houot, Sabine; Kätterer, Thomas; Lutfalla, Suzanne; Macdonald, Andy; van Oort, Folkert; Plante, Alain F.; Savignac, Florence; Soucémarianadin, Laure; Barré, Pierre

    2016-04-01

    Soil C is a key component of climate change. Any alteration of the soil organic C (SOC) reservoir yields a rapid modification of the atmospheric CO2 concentration. However, a part of the SOC reservoir will not contribute significantly to next century's land CO2 emissions as its residence time exceeds this timescale. The size of the pluri-centennial SOC pool is supposed to be large (ca. one third of total SOC), but is in fact highly uncertain as it cannot be estimated accurately by any analytical method. This methodological gap hampers the proper initialization of SOC dynamics models, questioning their predictions on the evolution of the global SOC reservoir. Here, using an exceptional soil sample set coming from long-term agronomic experiments in Western and Northern Europe, we show that a multivariate regression model based on Rock-Eval 6 (RE6) pyrolysis data can accurately predict the proportion of the pluri-centennial SOC pool in a soil sample with a prediction error lower than 6% for a wide range of soil types and land-uses. One hundred and six soil samples coming from four sites (Grignon, FR; Rothamsted, UK; Ultuna, SW; Versailles, FR) with long-term bare fallow (LTBF) and associated non bare fallow treatments (organic amendments, cropping systems, grasslands) were used to calibrate and validate the model. In a previous study, the modelling of SOC decay in LTBF experiments allowed estimating the size of the pluri-centennial persistant SOC pool at each of these sites (Barré et al., 2010, Biogeosciences 7:3839-3850). Based on these estimates, we calculated the proportion of pluri-centennial persistant SOC (% of total SOC) in each of the 106 soil samples. They showed very diverse proportions of pluri-centennial persistant SOC pool (from 6 to 100% of total SOC, with total SOC concentrations ranging from 5 to 46 gC.kg-1soil). All samples were analysed using RE6 pyrolysis. Five RE6 pyrograms per sample were used to compute the temperatures at which a specific

  3. Vertical Microbial Community Variability of Carbonate-based Cones may Provide Insight into Formation in the Rock Record

    Science.gov (United States)

    Trivedi, C.; Bojanowski, C.; Daille, L. K.; Bradley, J.; Johnson, H.; Stamps, B. W.; Stevenson, B. S.; Berelson, W.; Corsetti, F. A.; Spear, J. R.

    2015-12-01

    Stromatolite morphogenesis is poorly understood, and the process by which microbial mats become mineralized is a primary question in microbialite formation. Ancient conical stromatolites are primarily carbonate-based whereas the few modern analogues in hot springs are either non-mineralized or mineralized by silica. A team from the 2015 International GeoBiology Course investigated carbonate-rich microbial cones from near Little Hot Creek (LHC), Long Valley Caldera, California, to investigate how conical stromatolites might form in a hot spring carbonate system. The cones are up to 3 cm tall and are found in a calm, ~45° C pool near LHC that is 4 times super-saturated with respect to CaCO3. The cones rise from a flat, layered microbial mat at the edge of the pool. Scanning electron microscopy revealed filamentous bacteria associated with calcite crystals within the cone tips. Preliminary 16S rRNA gene analysis indicated variability of community composition between different vertical levels of the cone. The cone tip had comparatively greater abundance of filamentous cyanobacteria (Leptolyngbya and Phormidium) and fewer heterotrophs (e.g. Chloroflexi) compared to the cone bottom. This supports the hypothesis that cone formation may depend on the differential abundance of the microbial community and their potential functional roles. Metagenomic analyses of the cones revealed potential genes related to chemotaxis and motility. Specifically, a genomic bin identified as a member of the genus Isosphaera contained an hmp chemotaxis operon implicated in gliding motility in the cyanobacterium Nostoc punctiforme [1]. Isosphaera is a Planctomycete shown to have phototactic capabilities [2], and may play a role in conjunction with cyanobacteria in the vertical formation of the cones. This analysis of actively growing cones indicates a complex interplay of geochemistry and microbiology that form structures which can serve as models for processes that occurred in the past and are

  4. Investigation of carbonate rocks appropriate for the production of natural hydraulic lime binders

    Science.gov (United States)

    Triantafyllou, George; Panagopoulos, George; Manoutsoglou, Emmanouil; Christidis, George; Přikryl, Richard

    2014-05-01

    Cement industry is facing growing challenges in conserving materials and conforming to the demanding environmental standards. Therefore, there is great interest in the development, investigation and use of binders alternatives to Portland cement. Natural hydraulic lime (NHL) binders have become nowadays materials with high added value, due to their advantages in various construction applications. Some of them include compatibility, suitability, workability and the versatility in applications. NHL binders are made from limestones which contain sufficient argillaceous or siliceous components fired at relatively low temperatures, with reduction to powder by slaking with or without grinding. This study is focused in developing technology for small-scale production of cementitious binders, combining the knowledge and experience of geologists and mineral resources engineers. The first step of investigation includes field techniques to the study the lithology, texture and sedimentary structure of Neogene carbonate sediments, from various basins of Crete Island, Greece and the construction of 3D geological models, in order to determine the deposits of each different geological formation. Sampling of appropriate quantity of raw materials is crucial for the investigation. Petrographic studies on the basis of the study of grain type, grain size, types of porosity and depositional texture, are necessary to classify effectively industrial mineral raw materials for this kind of application. Laboratory tests should also include the study of mineralogical and chemical composition of the bulk raw materials, as well as the content of insoluble limestone impurities, thus determining the amount of active clay and silica components required to produce binders of different degree of hydraulicity. Firing of the samples in various temperatures and time conditions, followed by X-ray diffraction analysis and slaking rate tests of the produced binders, is essential to insure the

  5. Petrogenesis of tourmaline rocks associated with Fe-carbonate graphite metapelite, metabasite and strata-bound polymetallic sulphide mineralisation, Peloritani Mountains, Sicily, Southern Italy

    Science.gov (United States)

    Ferla, Paolo; Meli, Carmelina

    2007-12-01

    Tourmalinite and tourmaline-rich rocks associated with Fe-carbonate-graphite phyllite, strata-bound polymetallic sulphide deposits, metabasite and marble were studied, for information on the mechanism of tourmaline formation in the pre-Hercynian low-grade metamorphic sequence of the Mandanici Unit in the Peloritani Mountains of Sicily, southern Italy. The major and trace element compositions of the tourmaline rocks suggest the existence of a sedimentary protolith with pre-metamorphic black shale and bedded chert. Boron was interpreted to be accumulated in a restricted sedimentary basin, between platform carbonate formations, with abundant organic matter and Fe-Al-Ti-rich laterite-bauxite soil-derived clastic supply, under a continental volcano-tectonic extensional regime accompanied by a local convective hydrothermal system along faults. Petrographic, crystal-chemical and δ11B isotopic data are compatible with a model of marine sediment dewatering at temperatures below 200 °C, which caused the removal of boron from clay. Metamorphism led to the development of tourmaline in an Al-Ti-rich environment, in equilibrium with other minerals such as ilmenite, albite and muscovite. The upper temperature of metamorphism (almost 375 °C), estimated on the basis of δ11B, fits geothermometric results from Δ 13C carbonate-graphite on associated rocks. The estimated value of δ11B in the tourmalinite protolith, - 7.5‰ , is also compatible with continental-derived Al-rich sediments.

  6. Hydrogeologic and geospatial data for the assesment of focused recharge to the Carbonate-Rock Aquifer in Genesee County, New York

    Science.gov (United States)

    Reddy, James E.; Kappel, William M.

    2010-01-01

    Existing hydrogeologic and geospatial data useful for the assessment of focused recharge to the carbonate-rock aquifer in the central part of Genesee County, NY, were compiled from numerous local, State, and Federal agency sources. Data sources utilized in this pilot study include available geospatial datasets from Federal and State agencies, interviews with local highway departments and the Genesee County Soil and Water Conservation District, and an initial assessment of karst features through the analysis of ortho-photographs, with minimal field verification. The compiled information is presented in a series of county-wide and quadrangle maps. The county-wide maps present generalized hydrogeologic conditions including distribution of geologic units, major faults, and karst features, and bedrock-surface and water-table configurations. Ten sets of quadrangle maps of the area that overlies the carbonate-rock aquifer present more detailed and additional information including distribution of bedrock outcrops, thin and (or) permeable soils, and karst features such as sinkholes and swallets. Water-resource managers can utilize the information summarized in this report as a guide to their assessment of focused recharge to, and the potential for surface contaminants to reach the carbonate-rock aquifer.

  7. Soils on the Late Triassic carbonate rocks in the West Karavanke Mountains and the high plateaus of the Julian Alps (Slovenia

    Directory of Open Access Journals (Sweden)

    Tomaž Budkovič

    2009-06-01

    Full Text Available Grain-size analysis, mineral composition of heavy and light fraction, and surface texture of quartz grains in soilsdeveloped on different parent carbonate rocks in the region of the West Karavanke Mountains and the high plateausof the Julian Alps (Mežakla, Pokljuka, Jelovica revealed their polygenetic origin. Homogeneity of the heavymineral assemblage in the soils developed on different parent carbonate rocks indicates – besides autochthonousmaterial (insoluble residue of carbonate rocks, the presence of allochthonous (external material in the compositionof mineral component of soils, too. Heavy mineral assemblage indicates a metamorphic-igneous source area, whichis most probably in the Central Alps. The Drava glacier transported material from there, and deposited it in tillesalong the Drava valley. They were exposed to the fluvial and eolian erosion after the Würm deglaciation. Mostly siltymaterial was transported over the ridges of the Karavanke Mountains by the northeren winds. Their deposition beganon the southern calm and protected slopes and saddles, and continued southward on high plateaus of the JulianAlps, and very possibly even farther.

  8. Vulnerability of shallow ground water and drinking-water wells to nitrate in the United States: Model of predicted nitrate concentration in shallow, recently recharged ground water -- Input data set for carbonate rocks (gwava-s_crox)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the presence or absence of Valley and Ridge carbonate rocks in the conterminous United States. The data set was used as an input data layer...

  9. Micro-scale experimental investigation of the effect of flow rate on trapping in sandstone and carbonate rock samples

    Science.gov (United States)

    Khishvand, Mahdi; Akbarabadi, Morteza; Piri, Mohammad

    2016-08-01

    We present the results of a pore-scale experimental study of residual trapping in consolidated sandstone and carbonate rock samples under confining stress. We investigate how the changes in wetting phase flow rate impacts pore-scale distribution of fluids during imbibition in natural, water-wet porous media. We systematically study pore-scale trapping of the nonwetting phase as well as size and distribution of its disconnected globules. Seven sets of drainage-imbibition experiments were performed with brine and oil as the wetting and nonwetting phases, respectively. We utilized a two-phase miniature core-flooding apparatus integrated with an X-ray microtomography system to examine pore-scale fluid distributions in small Bentheimer sandstone (D = 4.9 mm and L = 13 mm) and Gambier limestone (D = 4.4 mm and L = 75 mm) core samples. The results show that with increase in capillary number, the residual oil saturation at the end of the imbibition reduces from 0.46 to 0.20 in Bemtheimer sandstone and from 0.46 to 0.28 in Gambier limestone. We use pore-scale displacement mechanisms, in-situ wettability characteristics, and pore size distribution information to explain the observed capillary desaturation trends. The reduction was believed to be caused by alteration of the order in which pore-scale displacements took place during imbibition. Furthermore, increase in capillary number produced significantly different pore-scale fluid distributions during imbibition. We explored the pore fluid occupancies and studied size and distribution of the trapped oil clusters during different imbibition experiments. The results clearly show that as the capillary number increases, imbibition produces smaller trapped oil globules. In other words, the volume of individual trapped oil globules decreased at higher brine flow rates. Finally, we observed that the pore space in the limestone sample was considerably altered through matrix dissolution at extremely high brine flow rates. This

  10. Reactive Transport at the Pore Scale with Applications to the Dissolution of Carbonate Rocks for CO2 Sequestration Operations

    Science.gov (United States)

    Boek, E.; Gray, F.; Welch, N.; Shah, S.; Crawshaw, J.

    2014-12-01

    In CO2 sequestration operations, CO2 injected into a brine aquifer dissolves in the liquid to create an acidic solution. This may result in dissolution of the mineral grains in the porous medium. Experimentally, it is hard to investigate this process at the pore scale. Therefore we develop a new hybrid particle simulation algorithm to study the dissolution of solid objects in a laminar flow field, as encountered in porous media flow situations. First, we calculate the flow field using a multi-relaxation-time lattice Boltzmann (LB) algorithm implemented on GPUs, which demonstrates a very efficient use of the GPU device and a considerable performance increase over CPU calculations. Second, using a stochastic particle approach, we solve the advection-diffusion equation for a single reactive species and dissolve solid voxels according to our reaction model. To validate our simulation, we first calculate the dissolution of a solid sphere as a function of time under quiescent conditions. We compare with the analytical solution for this problem [1] and find good agreement. Then we consider the dissolution of a solid sphere in a laminar flow field and observe a significant change in the sphericity with time due to the coupled dissolution - flow process. Second, we calculate the dissolution of a cylinder in channel flow in direct comparison with corresponding dissolution experiments. We discuss the evolution of the shape and dissolution rate. Finally, we calculate the dissolution of carbonate rock samples at the pore scale in direct comparison with micro-CT experiments. This work builds on our recent research on calculation of multi-phase flow [2], [3] and hydrodynamic dispersion and molecular propagator distributions for solute transport in homogeneous and heterogeneous porous media using LB simulations [4]. It turns out that the hybrid simulation model is a suitable tool to study reactive flow processes at the pore scale. This is of great importance for CO2 storage and

  11. Quantification of sub-resolution porosity in carbonate rocks by applying high-salinity contrast brine using X-ray microtomography differential imaging

    Science.gov (United States)

    Lin, Qingyang; Al-Khulaifi, Yousef; Blunt, Martin J.; Bijeljic, Branko

    2016-10-01

    Characterisation of the pore space in carbonate reservoirs and aquifers is of utmost importance in a number of applications such as enhanced oil recovery, geological carbon storage and contaminant transport. We present a new experimental methodology that uses high-salinity contrast brine and differential imaging acquired by X-ray tomography to non-invasively obtain three-dimensional spatially resolved information on porosity and connectivity of two rock samples, Portland and Estaillades limestones, including sub-resolution micro-porosity. We demonstrate that by injecting 30 wt% KI brine solution, a sufficiently high phase contrast can be achieved allowing accurate three-phase segmentation based on differential imaging. This results in spatially resolved maps of the solid grain phase, sub-resolution micro-pores within the grains, and macro-pores. The total porosity values from the three-phase segmentation for two carbonate rock samples are shown to be in good agreement with Helium porosity measurements. Furthermore, our flow-based method allows for an accurate estimate of pore connectivity and a distribution of porosity within the sub-resolution pores.

  12. Heterogeneous carbonaceous matter in sedimentary rock lithocomponents causes significant trichloroethylene (TCE) sorption in a low organic carbon content aquifer/aquitard system.

    Science.gov (United States)

    Choung, Sungwook; Zimmerman, Lisa R; Allen-King, Richelle M; Ligouis, Bertrand; Feenstra, Stanley

    2014-10-15

    This study evaluated the effects of heterogeneous thermally altered carbonaceous matter (CM) on trichloroethylene (TCE) sorption for a low fraction organic carbon content (foc) alluvial sedimentary aquifer and aquitard system (foc=0.046-0.105%). The equilibrium TCE sorption isotherms were highly nonlinear with Freundlich exponents of 0.46-0.58. Kerogen+black carbon was the dominant CM fraction extracted from the sediments and accounted for >60% and 99% of the total in the sands and silt, respectively. Organic petrological examination determined that the kerogen included abundant amorphous organic matter (bituminite), likely of marine origin. The dark calcareous siltstone exhibited the greatest TCE sorption among aquifer lithocomponents and accounted for most sorption in the aquifer. The results suggest that the source of the thermally altered CM, which causes nonlinear sorption, was derived from parent Paleozoic marine carbonate rocks that outcrop throughout much of New York State. A synthetic aquifer-aquitard unit system (10% aquitard) was used to illustrate the effect of the observed nonlinear sorption on mass storage potential at equilibrium. The calculation showed that >80% of TCE mass contained in the aquifer was sorbed on the aquifer sediment at aqueous concentration TCE groundwater plume in the aquifer studied. It is implied that sorption may similarly contribute to TCE persistence in other glacial alluvial aquifers with similar geologic characteristics, i.e., comprised of sedimentary rock lithocomponents that contain thermally altered CM.

  13. Heterogeneous carbonaceous matter in sedimentary rock lithocomponents causes significant trichloroethylene (TCE) sorption in a low organic carbon content aquifer/aquitard system

    Science.gov (United States)

    Choung, Sungwook; Zimmerman, Lisa R.; Allen-King, Richelle M.; Ligouis, Bertrand; Feenstra, Stanley

    2014-10-01

    This study evaluated the effects of heterogeneous thermally altered carbonaceous matter (CM) on trichloroethylene (TCE) sorption for a low fraction organic carbon content (foc) alluvial sedimentary aquifer and aquitard system (foc = 0.046-0.105%). The equilibrium TCE sorption isotherms were highly nonlinear with Freundlich exponents of 0.46-0.58. Kerogen + black carbon was the dominant CM fraction extracted from the sediments and accounted for > 60% and 99% of the total in the sands and silt, respectively. Organic petrological examination determined that the kerogen included abundant amorphous organic matter (bituminite), likely of marine origin. The dark calcareous siltstone exhibited the greatest TCE sorption among aquifer lithocomponents and accounted for most sorption in the aquifer. The results suggest that the source of the thermally altered CM, which causes nonlinear sorption, was derived from parent Paleozoic marine carbonate rocks that outcrop throughout much of New York State. A synthetic aquifer-aquitard unit system (10% aquitard) was used to illustrate the effect of the observed nonlinear sorption on mass storage potential at equilibrium. The calculation showed that > 80% of TCE mass contained in the aquifer was sorbed on the aquifer sediment at aqueous concentration < 1000 μg L- 1. These results show that sorption is likely a significant contributor to the persistence of a TCE groundwater plume in the aquifer studied. It is implied that sorption may similarly contribute to TCE persistence in other glacial alluvial aquifers with similar geologic characteristics, i.e., comprised of sedimentary rock lithocomponents that contain thermally altered CM.

  14. Assimilation of carbonate country rock by the parent magma of the Panzhihua Fe-Ti-V deposit (SW China: Evidence from stable isotopes

    Directory of Open Access Journals (Sweden)

    Clément Ganino

    2013-09-01

    Full Text Available The Panzhihua intrusion in southwest China is part of the Emeishan Large Igneous Province and host of a large Fe-Ti-V ore deposit. During emplacement of the main intrusion, multiple generations of mafic dykes invaded carbonate wall rocks, producing a large contact aureole. We measured the oxygen-isotope composition of the intrusions, their constituent minerals, and samples of the country rock. Magnetite and plagioclase from Panzhihua intrusion have δ18O values that are consistent with magmatic equilibrium, and formed from magmas with δ18O values that were 1–2‰ higher than expected in a mantle-derived magma. The unmetamorphosed country rock has high δ18O values, ranging from 13.2‰ (sandstone to 24.6–28.6‰ (dolomite. The skarns and marbles from the aureole have lower δ18O and δ13C values than their protolith suggesting interaction with fluids that were in exchange equilibrium with the adjacent mafic magmas and especially the numerous mafic dykes that intruded the aureole. This would explain the alteration of δ18O of the dykes which have significantly higher values than expected for a mantle-derived magma. Depending on the exact δ18O values assumed for the magma and contaminant, the amount of assimilation required to produce the elevated δ18O value of the Panzhihua intrusion was between 8 and 13.7 wt.%, assuming simple mixing. The exact mechanism of contamination is unclear but may involve a combination of assimilation of bulk country rock, mixing with a melt of the country rock and exchange with CO2-rich fluid derived from decarbonation of the marls and dolomites. These mechanisms, particularly the latter, were probably involved in the formation of the Fe-Ti-V ores.

  15. Characterization of reactive flow-induced evolution of carbonate rocks using digital core analysis- part 1: Assessment of pore-scale mineral dissolution and deposition

    Science.gov (United States)

    Qajar, Jafar; Arns, Christoph H.

    2016-09-01

    The application of X-ray micro-computed tomography (μ-CT) for quantitatively characterizing reactive-flow induced pore structure evolution including local particle detachment, displacement and deposition in carbonate rocks is investigated. In the studies conducted in this field of research, the experimental procedure has involved alternating steps of imaging and ex-situ core sample alteration. Practically, it is impossible to return the sample, with micron precision, to the same position and orientation. Furthermore, successive images of a sample in pre- and post-alteration states are usually taken at different conditions such as different scales, resolutions and signal-to-noise ratios. These conditions accompanying with subresolution features in the images make voxel-by-voxel comparisons of successive images problematic. In this paper, we first address the respective challenges in voxel-wise interpretation of successive images of carbonate rocks subject to reactive flow. Reactive coreflood in two carbonate cores with different rock types are considered. For the first rock, we used the experimental and imaging results published by Qajar et al. (2013) which showed a quasi-uniform dissolution regime. A similar reactive core flood was conducted in the second rock which resulted in wormhole-like dissolution regime. We particularly examine the major image processing operations such as transformation of images to the same grey-scale, noise filtering and segmentation thresholding and propose quantitative methods to evaluate the effectiveness of these operations in voxel-wise analysis of successive images of a sample. In the second part, we generalize the methodology based on the three-phase segmentation of normalized images, microporosity assignment and 2D histogram of image intensities to estimate grey-scale changes of individual image voxels for a general case where the greyscale images are segmented into arbitrary number of phases. The results show that local (voxel

  16. Stages of weathering mantle formation from carbonate rocks in the light of rare earth elements (REE) and Sr-Nd-Pb isotopes

    Science.gov (United States)

    Hissler, Christophe; Stille, Peter

    2015-04-01

    Weathering mantles are widespread and include lateritic, sandy and kaolinite-rich saprolites and residuals of partially dissolved rocks. These old regolith systems have a complex history of formation and may present a polycyclic evolution due to successive geological and pedogenetic processes that affected the profile. Until now, only few studies highlighted the unusual high content of associated trace elements in weathering mantles originating from carbonate rocks, which have been poorly studied, compared to those developing on magmatic bedrocks. For instance, these enrichments can be up to five times the content of the underlying carbonate rocks. However, these studies also showed that the carbonate bedrock content only partially explains the soil enrichment for all the considered major and trace elements. Up to now, neither soil, nor saprolite formation has to our knowledge been geochemically elucidated. Therefore, the aim of this study was to examine more closely the soil forming dynamics and the relationship of the chemical soil composition to potential sources. REE distribution patterns and Sr-Nd-Pb isotope ratios have been used because they are particularly well suited to identify trace element migration, to recognize origin and mixing processes and, in addition, to decipher possible anthropogenic and/or "natural" atmosphere-derived contributions to the soil. Moreover, leaching experiments have been applied to identify mobile phases in the soil system and to yield information on the stability of trace elements and especially on their behaviour in these Fe-enriched carbonate systems. All these geochemical informations indicate that the cambisol developing on such a typical weathering mantle ("terra fusca") has been formed through weathering of a condensed Bajocian limestone-marl facies. This facies shows compared to average world carbonates important trace element enrichments. Their trace element distribution patterns are similar to those of the soil

  17. Equilibrium of Groundwater with Carbonate Minerals of the Water-Bearing Rocks under Anthropogenic Impact (by the example of Kishinev, Moldova)

    Science.gov (United States)

    Timoshenkova, A. N.; Pasechnik, E. Yu; Tokarenko, O. G.

    2014-08-01

    The paper presents calculation results of equilibrium of groundwater in Kishenev with a variety of secondary carbonate minerals. It is shown that the groundwater-rock system is in equilibrium with some minerals, such as calcite, magnesite, dolomite, siderite, but at the same time is not in equilibrium with strontianite. It indicates that secondary mineral precipitation is possible. Specific nitrate chemical water type, which is rarely observed in nature and characterized by the presence of anthropogenic impact in this territory, in some cases is of higher saturation as compared to calcite, dolomite and magnesite due to the fact that nitrate ion content increases with the increase of calcium content.

  18. A High-Resolution Multitechniques Approach to Characterize Bio-Organo-Mineral Associations Within Rock Samples: Tracking Biological vs Abiotic Processes? Towards a Better Understanding of the Deep Carbon Cycle.

    Science.gov (United States)

    Pisapia, C.

    2015-12-01

    Among all elements, carbon plays one of the major roles for the sustainability of life on Earth. Past considerations of the carbon cycle have mainly focused on surface processes occurring at the atmosphere, oceans and shallow crustal environments. By contrast, little is known about the Deep Carbon cycle whereas both geochemical and biological processes may induce organic carbon production and/or consumption at depth. Indeed, the nowadays-recognized capability of geochemical processes such as serpentinization to generate abiotic organic compounds as well as the existence of a potentially important intraterrestrial life raises questions about the limit of biotic/abiotic carbon on Earth's deep interior and how it impacts global biogeochemical cycles. It is then mandatory to increase our knowledge on the nature and extent of carbon reservoirs along with their sources, sinks and fluxes in the subsurface. This implies to be able to finely characterize organomineral associations within crustal rocks although it might be hampered by the scarceness and heterogeneous micrometric spatial distribution of organic molecules in natural rocks. We then developed an in situ analytical strategy based on the combination of high-resolution techniques to track organic molecules at the pore level in natural rocks and to determine their biological or abiotic origin. We associated classical high-resolution techniques and synchrotron-based imaging techniques in order to characterize their nature and localization (SEM/TEM, coupled CLSM/Raman spectroscopy, Tof-SIMS) along with their 3D-distribution relatively to mineral phases (S-FTIR, S-DeepUV, XANES, Biphoton microscopy). The effectiveness of this approach to shed light on the speciation and nature of carbon in subsurface environments will be illustrated through the study of (i) subsurface ecosystems and abiotic organic carbon within ultramafic rocks of the oceanic lithosphere as putative analogs for the nature and functioning of primitive

  19. Microbiology of shallow subsurface aquifer and carbonate rocks studied by culture-dependent and culture-independent methods. Preliminary results on an underground laboratory, the LSBB, Rustrel, France

    Directory of Open Access Journals (Sweden)

    Galès Grégoire

    2016-01-01

    Full Text Available We investigated the microbiology of a shallow subsurface site, the LSBB, located near Avignon. This site lies in carbonate rocks, belonging to the Urgonian facies. Rock, concrete and water samples were collected and directly transferred to the laboratory. Studies of microorganisms as pure cultures are the only way to get their real physiological properties. Nevertheless, microbiologists cannot cultivate and isolate the majority of microorganisms for several reasons, one being our lack of understanding of their minimal needs. Molecular studies, e.g. extraction and sequencing of the total nucleic acids present in an environment provide phylogenetic and metabolic information on uncultivated microorganisms. We performed aerobic and anaerobic culture with various electron acceptors and donors, searching for heterotrophic, methanogenic, sulphate- nitrate- and FeIII- reducing Prokaryotes. We also performed DNA extractions and PCR amplification of ribosomal RNA genes, to test if our protocols were adapted to this environment. Our results show that the LSBB galleries are colonized by a low diversity microbiote, with a strong influence of anthropogenic activities. Further studies will link the microorganisms biodiversity and the petrophysic properties of rocks.

  20. Rock formation characterization for carbon dioxide geosequestration: 3D seismic amplitude and coherency anomalies, and seismic petrophysical facies classification, Wellington and Anson-Bates Fields, Kansas, USA

    Science.gov (United States)

    Ohl, Derek; Raef, Abdelmoneam

    2014-04-01

    Higher resolution rock formation characterization is of paramount priority, amid growing interest in injecting carbon dioxide, CO2, into subsurface rock formations of depeleting/depleted hydrocarbon reservoirs or saline aquifers in order to reduce emissions of greenhouse gases. In this paper, we present a case study for a Mississippian carbonate characterization integrating post-stack seismic attributes, well log porosities, and seismic petrophysical facies classification. We evaluated changes in petrophysical lithofacies and reveal structural facies-controls in the study area. Three cross-plot clusters in a plot of well log porosity and acoustic impedance corroborated a Neural Network petrophysical facies classification, which was based on training and validation utilizing three petrophysically-different wells and three volume seismic attributes, extracted from a time window including the wavelet of the reservoir-top reflection. Reworked lithofacies along small-throw faults has been revealed based on comparing coherency and seismic petrophysical facies. The main objective of this study is to put an emphasis on reservoir characterization that is both optimized for and subsequently benefiting from pilot tertiary CO2 carbon geosequestration in a depleting reservoir and also in the deeper saline aquifer of the Arbuckle Group, south central Kansas. The 3D seismic coherency attribute, we calculated from a window embracing the Mississippian top reflection event, indicated anomalous features that can be interpreted as a change in lithofacies or faulting effect. An Artificial Neural Network (ANN) lithofacies modeling has been used to better understand these subtle features, and also provide petrophysical classes, which will benefit flow-simulation modeling and/or time-lapse seismic monitoring feasibility analysis. This paper emphasizes the need of paying greater attention to small-scale features when embarking upon characterization of a reservoir or saline-aquifer for CO2

  1. Impact of SO{sub 2} and NO on carbonated rocks submitted to a geological storage of CO{sub 2} : an experimental study

    Energy Technology Data Exchange (ETDEWEB)

    Renard, S.; Sterpenich, J.; Pironon, J.; Randi, A.; Chiquet, P.; Lescanne, M. [Nancy Univ. (France); Total (France)

    2010-07-01

    This study presented the preliminary results regarding the mineralogical transformation of rocks and well materials that have undergone carbon dioxide (CO{sub 2}) and co-injected annex gases. In particular, the study investigated the capture and geological storage of CO{sub 2} from high emitting sources such as coal and gas power plants. It focused on the following 3 capture processes: (1) precombustion of hydrogen sulphide (H{sub 2}S), hydrogen (H{sub 2}), carbon monoxide (CO) and methane (CH{sub 4}), (2) post-combustion of sulphur dioxide (SO{sub 2}), nitric oxide (NO), nitrogen (N{sub 2}), argon (Ar), and oxygen (O{sub 2}), and (3) oxy-combustion of oxygen SO{sub 2}, N{sub 2}, NO and Ar. An overview of the composition of flue gases from coal and gas power plants was included. Since the complete purification of CO{sub 2} is unachievable for cost reasons as well as for CO{sub 2} surplus of emissions due to the separation processes, many of these gases could be co-injected with the CO{sub 2}. The study focused on the experimental reactivity of rocks submitted to gas injection. The impact of these gases on the chemical stability of reservoir rocks, caprocks and wells must be evaluated before any large scale injection procedure can take place, particularly since physico-chemical transformations could modify the mechanical and injectivity properties of the site, potentially affecting storage safety. Laboratory simulations were conducted of the geochemical interactions between carbonate rocks, SO{sub 2} and NO which could be co-injected with CO{sub 2}. The results were interpreted in terms of petrophysical and chemical impacts of the injected gases on the mineral assemblages of a storage site. Scanning electron microscopy, transmission electron microscopy, Raman spectroscopy and X-ray diffraction techniques were used to observe and analyze the solid samples following the experiments. Aqueous solutions were analysed with inductively coupled plasma (ICP) mass

  2. Using synchrotron X-ray microtomography to characterize the pore network of reservoir rocks: A case study on carbonates

    Science.gov (United States)

    Arzilli, F.; Cilona, A.; Mancini, L.; Tondi, E.

    2016-09-01

    In this work we propose a new methodology to calculate pore connectivity in granular rocks. This method is useful to characterize the pore networks of natural and laboratory compaction bands (CBs), and compare them with the host rock pore network. Data were collected using the synchrotron X-ray microtomography technique and quantitative analyses were carried out using the Pore3D software library. The porosity was calculated from segmented tridimensional images of deformed and pristine rocks. A process of skeletonization of the pore space was used to obtain the number of connected pores within the rock volume. By analyzing the skeletons the differences between natural and laboratory CBs were highlighted. The natural CB has a lower porosity than to the laboratory one. In natural CBs, the grain contacts appear welded, whereas laboratory CBs show irregular pore shape. Moreover, we assessed for the first time how pore connectivity evolves as a function of deformation, documenting the mechanism responsible for pore connectivity drop within the CBs.

  3. Collecting Rocks

    Institute of Scientific and Technical Information of China (English)

    孙铮

    2007-01-01

    My hobby is collecting rocks.It is very special,isn’t it?I began to collect rocks about four years ago.I usually go hiking in the mountains,or near the river to look for rocks.When I find a rock,I pick it up and clean it with the brush and water.Then I put it into my bag.Most of the rocks I have collected are quartzite~*.They are really

  4. CAUSE STUDY OF LATERITE OVERLYING CARBONATE ROCKS%碳酸盐岩上覆红土的成因研究

    Institute of Scientific and Technical Information of China (English)

    符必昌; 黄英; 方丽萍; 王昆; 金克盛; 刘鹏

    2013-01-01

    The cause of laterite overlying carbonate rocks has not been resolved and became the key problem for the restriction to further study of laterite,karst etc subject area. It is an important problem to be solved for the not objective scientific research results. Related academic circles in carbonate rocks on the overlaying laterite causes appeared in the process of cognition is discussed,the main problems is reviewed,a new perspective and established carbonate on the overlaying the formation of the laterite model is proposed. The model can not only system science to explain China science for a long time not solved many of the red clay and carbonate complex relations between and objective reasonably explain nature carbonate on the overlaying laterite forming the real reason. The research result has important guiding significance to laterite and karst.%  碳酸盐岩上覆红土的成因一直悬而未决,致使它成了制约我国红土、岩溶等学科领域进行系统深入研究的关键问题,越来越多欠客观科学的红土、岩溶研究结果又使它成为亟待解决的重要问题。通过对我国学术界在碳酸盐岩上覆红土成因认识、研究过程中出现的主要问题进行评述,在此基础上提出一种全新的研究思路,由此建立的碳酸盐岩上覆红土的形成模式既能系统科学地解释长期以来没有解决的诸多红黏土与碳酸盐岩之间的复杂关系,又能客观合理地解释自然界碳酸盐岩上覆红土形成的真实原因,该研究成果对红土、岩溶研究具有重要的指导意义。

  5. Quantifying Fracture Heterogeneity in Different Domains of Folded Carbonate Rocks to Improve Fractured Reservoir Analog Fluid Flow Models

    NARCIS (Netherlands)

    Bisdom, K.; Bertotti, G.; Gauthier, B.D.M.; Hardebol, N.J.

    2013-01-01

    Fluid flow in carbonate reservoirs is largely controlled by multiscale fracture networks. Significant variations of fracture network porosity and permeability are caused by the 3D heterogeneity of the fracture network characteristics, such as intensity, orientation and size. Characterizing fracture

  6. KREEP Rocks

    Institute of Scientific and Technical Information of China (English)

    邹永廖; 徐琳; 欧阳自远

    2004-01-01

    KREEP rocks with high contents of K, REE and P were first recognized in Apollo-12 samples, and it was confirmed later that there were KREEP rock fragments in all of the Apollo samples, particularly in Apollo-12 and-14 samples. The KREEP rocks distributed on the lunar surface are the very important objects of study on the evolution of the moon, as well as to evaluate the utilization prospect of REE in KREEP rocks. Based on previous studies and lunar exploration data, the authors analyzed the chemical and mineral characteristics of KREEP rocks, the abundance of Th on the lunar surface materials, the correlation between Th and REE of KREEP rocks in abundance, studied the distribution regions of KREEP rocks on the lunar surface, and further evaluated the utilization prospect of REE in KREEP rocks.

  7. Rock Stars

    Institute of Scientific and Technical Information of China (English)

    张国平

    2000-01-01

    Around the world young people are spending unbelievable sums of money to listen to rock music. Forbes Magazine reports that at least fifty rock stars have incomes between two million and six million dollars per year.

  8. Numerical modelling of fault reactivation in carbonate rocks under fluid depletion conditions - 2D generic models with a small isolated fault

    Science.gov (United States)

    Zhang, Yanhua; Clennell, Michael B.; Delle Piane, Claudio; Ahmed, Shakil; Sarout, Joel

    2016-12-01

    This generic 2D elastic-plastic modelling investigated the reactivation of a small isolated and critically-stressed fault in carbonate rocks at a reservoir depth level for fluid depletion and normal-faulting stress conditions. The model properties and boundary conditions are based on field and laboratory experimental data from a carbonate reservoir. The results show that a pore pressure perturbation of -25 MPa by depletion can lead to the reactivation of the fault and parts of the surrounding damage zones, producing normal-faulting downthrows and strain localization. The mechanism triggering fault reactivation in a carbonate field is the increase of shear stresses with pore-pressure reduction, due to the decrease of the absolute horizontal stress, which leads to an expanded Mohr's circle and mechanical failure, consistent with the predictions of previous poroelastic models. Two scenarios for fault and damage-zone permeability development are explored: (1) large permeability enhancement of a sealing fault upon reactivation, and (2) fault and damage zone permeability development governed by effective mean stress. In the first scenario, the fault becomes highly permeable to across- and along-fault fluid transport, removing local pore pressure highs/lows arising from the presence of the initially sealing fault. In the second scenario, reactivation induces small permeability enhancement in the fault and parts of damage zones, followed by small post-reactivation permeability reduction. Such permeability changes do not appear to change the original flow capacity of the fault or modify the fluid flow velocity fields dramatically.

  9. Rock Finding

    Science.gov (United States)

    Rommel-Esham, Katie; Constable, Susan D.

    2006-01-01

    In this article, the authors discuss a literature-based activity that helps students discover the importance of making detailed observations. In an inspiring children's classic book, "Everybody Needs a Rock" by Byrd Baylor (1974), the author invites readers to go "rock finding," laying out 10 rules for finding a "perfect" rock. In this way, the…

  10. Rock Art

    Science.gov (United States)

    Henn, Cynthia A.

    2004-01-01

    There are many interpretations for the symbols that are seen in rock art, but no decoding key has ever been discovered. This article describes one classroom's experiences with a lesson on rock art--making their rock art and developing their own personal symbols. This lesson allowed for creativity, while giving an opportunity for integration…

  11. Microbiotic crusts on soil, rock and plants: neglected major players in the global cycles of carbon and nitrogen?

    Science.gov (United States)

    Elbert, W.; Weber, B.; Büdel, B.; Andreae, M. O.; Pöschl, U.

    2009-07-01

    Microbiotic crusts consisting of bacteria, fungi, algae, lichens, and bryophytes colonize most terrestrial surfaces, and they are able to fix carbon and nitrogen from the atmosphere. Here we show that microbiotic crusts are likely to play major roles in the global biogeochemical cycles of carbon and nitrogen, and we suggest that they should be further characterized and taken into account in studies and models of the Earth system and climate. For the global annual net uptake of carbon by microbiotic crusts we present a first estimate of ~3.6 Pg a-1. This uptake corresponds to ~6% of the estimated global net carbon uptake by terrestrial vegetation (net primary production, NPP: ~60 Pg a-1), and it is of the same magnitude as the global annual carbon turnover due to biomass burning. The estimated rate of nitrogen fixation by microbiotic crusts (~45 Tg a-1) amounts to ~40% of the global estimate of biological nitrogen fixation (107 Tg a-1). With regard to Earth system dynamics and global change, the large contribution of microbiotic crusts to nitrogen fixation is likely to be important also for the sequestration of CO2 by terrestrial plants (CO2 fertilization), because the latter is constrained by the availability of fixed nitrogen.

  12. Microbiotic crusts on soil, rock and plants: neglected major players in the global cycles of carbon and nitrogen?

    Directory of Open Access Journals (Sweden)

    W. Elbert

    2009-07-01

    Full Text Available Microbiotic crusts consisting of bacteria, fungi, algae, lichens, and bryophytes colonize most terrestrial surfaces, and they are able to fix carbon and nitrogen from the atmosphere. Here we show that microbiotic crusts are likely to play major roles in the global biogeochemical cycles of carbon and nitrogen, and we suggest that they should be further characterized and taken into account in studies and models of the Earth system and climate.

    For the global annual net uptake of carbon by microbiotic crusts we present a first estimate of ~3.6 Pg a−1. This uptake corresponds to ~6% of the estimated global net carbon uptake by terrestrial vegetation (net primary production, NPP: ~60 Pg a−1, and it is of the same magnitude as the global annual carbon turnover due to biomass burning. The estimated rate of nitrogen fixation by microbiotic crusts (~45 Tg a−1 amounts to ~40% of the global estimate of biological nitrogen fixation (107 Tg a−1. With regard to Earth system dynamics and global change, the large contribution of microbiotic crusts to nitrogen fixation is likely to be important also for the sequestration of CO2 by terrestrial plants (CO2 fertilization, because the latter is constrained by the availability of fixed nitrogen.

  13. A Study of the Connection Among Basin-Fill Aquifers, Carbonate-Rock Aquifers, and Surface-Water Resources in Southern Snake Valley, Nevada

    Science.gov (United States)

    ,

    2008-01-01

    The Secretary of the Interior through the Southern Nevada Public Lands Management Act approved funding for research to improve understanding of hydrologic systems that sustain numerous water-dependent ecosystems on Federal lands in Snake Valley, Nevada. Some of the streams and spring-discharge areas in and adjacent to Great Basin National Park have been identified as susceptible to ground-water withdrawals (Elliott and others, 2006) and research has shown a high potential for ground-water flow from southern Spring Valley into southern Snake Valley through carbonate rocks that outcrop along a low topographic divide known as the Limestone Hills (Welch and others, 2007). Comprehensive geologic, hydrologic, and chemical information will be collected and analyzed to assess the hydraulic connection between basin-fill aquifers and surface-water resources, water-dependent ecological features, and the regional carbonate-rock aquifer, the known source of many high-discharge springs. Understanding these connections is important because proposed projects to pump and export ground water from Spring and Snake Valleys in Nevada may result in unintended capture of water currently supplying springs, streams, wetlands, limestone caves, and other biologically sensitive areas (fig. 1). The methods that will be used in this study may be transferable to other areas in the Great Basin. The National Park Service, Bureau of Land Management, U.S. Fish and Wildlife Service, and U.S. Forest Service submitted the proposal for funding this research to facilitate science-based land management. Scientists from the U.S. Geological Survey (USGS) Water Resources and Geologic Disciplines, and the University of Nevada, Reno, will accomplish four research elements through comprehensive data collection and analysis that are concentrated in two distinct areas on the eastern and southern flanks of the Snake Range (fig. 2). The projected time line for this research is from July 2008 through September 2011.

  14. The human impact on natural rock reserves using basalt, anorthosite, and carbonates as raw materials in insulation products

    DEFF Research Database (Denmark)

    Dahl, Tais Wittchen; Clausen, Anders U.; Hansen, Peter B.

    2011-01-01

    Typical crustal rocks such as basalt, limestone, and anorthosite are used in stone wool insulation products. The raw materials for stone wool production are not specific to any rare mineral source but depend upon the mixture of materials having the correct chemical composition, exemplified by 40 ...... materials serve as excellent source materials for new products. Moreover, current production lines exploit more than 30 natural and 20-30 synthetic source materials that circumvent regional depletion and contribute to the recycling of other industrial materials.......Typical crustal rocks such as basalt, limestone, and anorthosite are used in stone wool insulation products. The raw materials for stone wool production are not specific to any rare mineral source but depend upon the mixture of materials having the correct chemical composition, exemplified by 40 wt...... exploration. Globally, anorthositic provinces comprise smaller volumes than do limestone or basalt, but still occur in sufficient amounts to supply for the production of insulation materials indefinitely. An evaluation of the modern consumption rates and reserves shows that the crustal inventories...

  15. Dawsonite and other carbonate veins in the Cretaceous Izumi Group, SW Japan: a natural support for fracture self-sealing in mud-stone cap-rock in CGS?

    Energy Technology Data Exchange (ETDEWEB)

    Okuyama, Yasuko; Funatsu, Takahiro; Fujii, Takashi [Institute for Geo-Resources and environment, GSJ, AISI, 1-1-1 Higashi, Central 7, Tsukuba, ibaraki 305-8567 (Japan); Take, Shuji [Kishiwada Nature Club, c/o Kishiwada City Natural History Museum, Sakai-Machi 5-6, Kishiwada, Osaka 596-0072 (Japan)

    2013-07-01

    Dawsonite-bearing carbonate veins are abundant in a compact mud-stone layer of the lower part of the Izumi Group, SW Japan. The mode of occurrence of the veins probably indicates fracturing and mineral sealing associated with upwelling of CO{sub 2}-rich fluid evolved in the reservoir beneath. The carbonate veins studied here can be a natural support to fracturing and healing of mud-stone cap-rock in the CO{sub 2} geological storage. (authors)

  16. The Formation of Carbonate Minerals and the Mobility of Heavy Metals during Water-CO2-Mafic Rock Interactions

    DEFF Research Database (Denmark)

    Olsson, Jonas

    are consistent with values of controlled laboratory experiments from the literature for Ba, Cd, Co, Cu, Mg, Mn, Na, Ni, Sr and Zn. The calcium carbonates also scavenge other elements, including rare earth elements (REE) and the toxic metals As and Pb. This and the next study can be considered natural analogues...... minerals, the reaction products are known to be manifold and reflect the complex composition of the basaltic material. Formation of secondary products, such aluminium and iron (hydr)oxides, are considered undesirable, because (1) they consume the cations that could be used to sequester CO2, thus compete...... with the process of carbonation, and (2) they can form a passivating layer, which inhibit dissolution of the basaltic material and slow down the carbonation process. The purpose of this thesis was to identify formation products, relevant to CarbFix, and assess their ability to immobilize toxic metals released from...

  17. Integration of stable carbon isotope, microbial community, dissolved hydrogen gas, and 2HH2O tracer data to assess bioaugmentation for chlorinated ethene degradation in fractured rocks

    Science.gov (United States)

    Révész, Kinga M.; Lollar, Barbara Sherwood; Kirshtein, Julie D.; Tiedeman, Claire R.; Imbrigiotta, Thomas E.; Goode, Daniel J.; Shapiro, Allen M.; Voytek, Mary A.; Lacombe, Pierre J.; Busenberg, Eurybiades

    2014-01-01

    An in situ bioaugmentation (BA) experiment was conducted to understand processes controlling microbial dechlorination of trichloroethene (TCE) in groundwater at the Naval Air Warfare Center (NAWC), West Trenton, NJ. In the BA experiment, an electron donor (emulsified vegetable oil and sodium lactate) and a chloro-respiring microbial consortium were injected into a well in fractured mudstone of Triassic age. Water enriched in 2H was also injected as a tracer of the BA solution, to monitor advective transport processes. The changes in concentration and the δ13C of TCE, cis-dichloroethene (cis-DCE), and vinyl chloride (VC); the δ2H of water; changes in the abundance of the microbial communities; and the concentration of dissolved H2 gas compared to pre- test conditions, provided multiple lines of evidence that enhanced biodegradation occurred in the injection well and in two downgradient wells. For those wells where the biodegradation was stimulated intensively, the sum of the molar chlorinated ethene (CE) concentrations in post-BA water was higher than that of the sum of the pre-BA background molar CE concentrations. The concentration ratios of TCE/(cis-DCE + VC) indicated that the increase in molar CE concentration may result from additional TCE mobilized from the rock matrix in response to the oil injection or due to desorption/diffusion. The stable carbon isotope mass-balance calculations show that the weighted average 13C isotope of the CEs was enriched for around a year compared to the background value in a two year monitoring period, an effective indication that dechlorination of VC was occurring. Insights gained from this study can be applied to efforts to use BA in other fractured rock systems. The study demonstrates that a BA approach can substantially enhance in situ bioremediation not only in fractures connected to the injection well, but also in the rock matrix around the well due to processes such as diffusion and desorption. Because the effect of the

  18. Residual effect of storage in an elevated carbon dioxide atmosphere on the microbial flora of rock cod (Sebastes spp. )

    Energy Technology Data Exchange (ETDEWEB)

    Wang, M.Y.; Ogrydziak, D.M.

    1986-10-01

    A residual inhibitory effect on microbial growth due to modified-atmosphere (MA) storage (MA, 80% CO/sub 2/-20% air) was demonstrated for rock cod fillets stored in MA and transferred to air at 4/sup 0/C. Results of measurements of CO/sub 2/ concentrations of the fillets suggested that the residual effect after transfer from MA to air was not due to retention of CO/sup 2/ at the surface of the fillets but was probably due to the microbial ecology of the system. Lactobacillus spp. and tan Alteromonas spp. (TAN) predominated after 7 and 14 days of storage in MA. During storage in MA, Pseudomonas spp. were inhibited or killed. Following transfer from MA to air, the percentage of the total flora represented by Lactobacillus spp. and TAN bacteria decreased, and 6 days after transfer Pseudomonas spp. were again dominant.

  19. Methyl diamantane index (MDI) as a maturity parameter for Lower Palaeozoic carbonate rocks at high maturity and overmaturity

    Energy Technology Data Exchange (ETDEWEB)

    Jinggui, Li; Mingzhong, Cui [Academia Sinica, Lanzhou (China). Inst. of Geology; Philp, Paul [Oklahoma Univ., Norman, OK (United States). School of Geology and Geophysics

    2000-07-01

    Diamantanes were identified in extracts from the Lower Ordovician Majiagou Formations (O{sub 1}m{sub 5}) of the central gas field, Shanganning Basin, China. At 3100-3800 m, corresponding to R{sub o} 1.9-3.9%, the MDI [methyl diamantine index = 4 - MD/(1-MD+3-MD+4-MD)] ranges from 40 to 65% for the source rock extracts. Changes in the MDI index in the very mature sections (R{sub o} > 2.0%) are relatively small and no linear correlation between MDI and R{sub o}, or MDI and depth, is noted, as previously reported, suggesting the possibility that the MDI may have limited applicability in maturity determinations. (Author)

  20. Tracing groundwater with low-level detections of halogenated VOCs in a fractured carbonate-rock aquifer, Leetown Science Center, West Virginia, USA

    Science.gov (United States)

    Plummer, L. Niel; Sibrell, Philip L.; Casile, Gerolamo C.; Busenberg, Eurybiades; Hunt, Andrew G.; Schlosser, Peter

    2013-01-01

    Measurements of low-level concentrations of halogenated volatile organic compounds (VOCs) and estimates of groundwater age interpreted from 3H/3He and SF6 data have led to an improved understanding of groundwater flow, water sources, and transit times in a karstic, fractured, carbonate-rock aquifer at the Leetown Science Center (LSC), West Virginia. The sum of the concentrations of a set of 16 predominant halogenated VOCs (TDVOC) determined by gas chromatography with electron-capture detector (GC–ECD) exceeded that possible for air–water equilibrium in 34 of the 47 samples (median TDVOC of 24,800 pg kg−1), indicating that nearly all the water sampled in the vicinity of the LSC has been affected by addition of halogenated VOCs from non-atmospheric source(s). Leakage from a landfill that was closed and sealed nearly 20 a prior to sampling was recognized and traced to areas east of the LSC using low-level detection of tetrachloroethene (PCE), methyl chloride (MeCl), methyl chloroform (MC), dichlorodifluoromethane (CFC-12), and cis-1,2-dichloroethene (cis-1,2-DCE). Chloroform (CHLF) was the predominant VOC in water from domestic wells surrounding the LSC, and was elevated in groundwater in and near the Fish Health Laboratory at the LSC, where a leak of chlorinated water occurred prior to 2006. The low-level concentrations of halogenated VOCs did not exceed human or aquatic-life health criteria, and were useful in providing an awareness of the intrinsic susceptibility of the fractured karstic groundwater system at the LSC to non-atmospheric anthropogenic inputs. The 3H/3He groundwater ages of spring discharge from the carbonate rocks showed transient behavior, with ages averaging about 2 a in 2004 following a wet climatic period (2003–2004), and ages in the range of 4–7 a in periods of more average precipitation (2008–2009). The SF6 and CFC-12 data indicate older water (model ages of 10s of years or more) in the low-permeability shale of the Martinsburg

  1. 'Escher' Rock

    Science.gov (United States)

    2004-01-01

    [figure removed for brevity, see original site] Chemical Changes in 'Endurance' Rocks [figure removed for brevity, see original site] Figure 1 This false-color image taken by NASA's Mars Exploration Rover Opportunity shows a rock dubbed 'Escher' on the southwestern slopes of 'Endurance Crater.' Scientists believe the rock's fractures, which divide the surface into polygons, may have been formed by one of several processes. They may have been caused by the impact that created Endurance Crater, or they might have arisen when water leftover from the rock's formation dried up. A third possibility is that much later, after the rock was formed, and after the crater was created, the rock became wet once again, then dried up and developed cracks. Opportunity has spent the last 14 sols investigating Escher, specifically the target dubbed 'Kirchner,' and other similar rocks with its scientific instruments. This image was taken on sol 208 (Aug. 24, 2004) by the rover's panoramic camera, using the 750-, 530- and 430-nanometer filters. The graph above shows that rocks located deeper into 'Endurance Crater' are chemically altered to a greater degree than rocks located higher up. This chemical alteration is believed to result from exposure to water. Specifically, the graph compares ratios of chemicals between the deep rock dubbed 'Escher,' and the more shallow rock called 'Virginia,' before (red and blue lines) and after (green line) the Mars Exploration Rover Opportunity drilled into the rocks. As the red and blue lines indicate, Escher's levels of chlorine relative to Virginia's went up, and sulfur down, before the rover dug a hole into the rocks. This implies that the surface of Escher has been chemically altered to a greater extent than the surface of Virginia. Scientists are still investigating the role water played in influencing this trend. These data were taken by the rover's alpha particle X-ray spectrometer.

  2. Optimization of the Acetic Acid method for microfossil extraction from lithified carbonate rocks: Examples from the Jurassic and Miocene of Saudi Arabia

    Science.gov (United States)

    Chan, Septriandi; Malik, Muhammad; Kaminski, Michael; Babalola, Lamidi

    2016-04-01

    We report the first ever use of the acetic acid processing method for the extraction of microfossils from indurated limestones in Saudi Arabia. Two different limestone samples from Middle Jurassic and Middle Miocene formation in Saudi Arabia were tested under different concentrations of acid from 50% to 100% and with processing times from 2 hours to 10 hours, in an attempt to optimize the processing methodology. The recovery of acid residues shows a similar trend for both Jurassic and Miocene samples. The weight percentage of residue particle size > 1 mm decreases as acid concentration increases, especially in the 50 to 80% acid concentration range, and the weight percentage of the smallest size particles >0.063 mm increases as acid concentration increases. The small fraction of residue between 0.50 - 0.063 mm was split into 3 g subsamples and picked for microfossils in order to assess their preservation. All concentrations of acetic acid tested show promising results for both the Jurassic Dhruma and Miocene Dam formation carbonates. Higher acid concentrations with longer reaction times yield better recovery than higher concentrations with less reaction time. Based on our experiment, we recommended a 60% concentration of acetic acid to be the optimal concentration for use on routine micropaleontological samples of Saudi Arabian carbonate rocks. By lowering the concentration of acetic acid from 80% to 60%, the consumption of acid is reduced without compromising the recovery of microfossils, and the sample can be processed in a more environmentally friendly manner.

  3. Cyclic Sequences, Events and Evolution of the Sino-Korean Plate,with a Discussion on the Evolution of Molar-tooth Carbonates,Phosphorites and Source Rocks

    Institute of Scientific and Technical Information of China (English)

    MENG Xianghua; GE Ming

    2003-01-01

    This paper gives an account of the research that the authors conducted on the cyclic sequences, events and evolutionary history from Proterozoic to Meso-Cenozoic in the Sino-Korean plate based on the principle of the Cosmos-Earth System. The authors divided this plate into 20 super-cyclic or super-mega-cyclic periods and more than 100 Oort periods. The research focused on important sea flooding events, uplift interruption events, tilting movement events, molar-tooth carbonate events, thermal events, polarity reversal events, karst events, volcanic explosion events and storm events, as well as types of resource areas and paleotectonic evolution. By means of the isochronous theory of the Cosmos-Earth System periodicity and based on long-excentricity and periodicity, the authors elaborately studied the paleogeographic evolution of the aulacogen of the Sino-Korean plate, the oolitic beach platform formation, the development of foreland basin and continental rift valley basin, and reconstructed the evolution of tectonic paleogeography and stratigraphic framework in the Sino-Korean plate in terms of evolutionary maps. Finally, the authors gave a profound discussion on the formation and development of molar-tooth carbonates, phosphorites and source rocks.

  4. From Basin Black Shales to Platform Carbonate Rocks: A Study on Sequence Stratigraphy for the Lower Cambrian of the Upper-Yangtze Region in South China

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    In the Upper-Yangtze region, especially in Guizhou Province and its adjacent areas, the Lower Cambrian is well developed and is marked by a succession from black shales of the basin facies to carbonate rocks of the platform facies. The drowning event of the platform occurring at the turn from Sinian to Cambrian resulted in a set of black shales, i.e. the Niutitang Formation, which makes up the bottom part of the Lower Cambrian. With the shoaling of the sedimentary environment, a set of carbonate rocks, i.e. the Qingxudong Formation, was formed in the top part of the Lower Cambrian. Thus, the Lower Cambrian in the study area makes up one second-order sequence that can be further subdivided into five third-order sequences, and forms a regularly cyclic succession of transgression-regression. There is a regularly vertical stacking pattern for the third-order sequences in the second-order sequence. From bottom to top, the succession of the "CS (condensed section)+HST (high-stand system tract)" of the third-order sequences is changed into the succession of the "TST (transgressive system tract)+CS+HST". Correspondingly, the drowning-type sequence boundary is changed into the exposure-type one. Therefore, both the second-order and the third-order sequences have similar sedimentary-facies architectures. A concomitant with these temporal changes,the Lower Cambrian with a thickness of 1000 m that contains five third-order sequences is changed into a condensed succession that cannot identify third-order sequences toward the southeast with the deepening of the sedimentary environment. According to the elementary features of the third-order sequences, i.e. the regularity o sedimentary-facies successions in space and the synchronism of sedimentary-environment changes in time, the detailed division of the third-order sequences at main logged sections in different paleogeographical background becomes the basis to establish the sequence-stratigraphic framework that can demonstrate

  5. 'Earhart' Rock

    Science.gov (United States)

    2004-01-01

    This false-color image taken by NASA's Mars Exploration Rover Opportunity shows a rock informally named 'Earhart' on the lower slopes of 'Endurance Crater.' The rock was named after the pilot Amelia Earhart. Like 'Escher' and other rocks dotting the bottom of Endurance, scientists believe fractures in Earhart could have been formed by one of several processes. They may have been caused by the impact that created Endurance Crater, or they might have arisen when water leftover from the rock's formation dried up. A third possibility is that much later, after the rock was formed, and after the crater was created, the rock became wet once again, then dried up and developed cracks. Rover team members do not have plans to investigate Earhart in detail because it is located across potentially hazardous sandy terrain. This image was taken on sol 219 (Sept. 4) by the rover's panoramic camera, using its 750-, 530- and 430-nanometer filters.

  6. Rock Art

    OpenAIRE

    Huyge, Dirk

    2009-01-01

    Rock art, basically being non-utilitarian, non-textual anthropic markings on natural rock surfaces, was an extremely widespread graphical practice in ancient Egypt. While the apogee of the tradition was definitely the Predynastic Period (mainly fourth millennium BCE), examples date from the late Palaeolithic (c. 15,000 BCE) until the Islamic era. Geographically speaking, “Egyptian” rock art is known from many hundreds of sites along the margins of the Upper Egyptian and Nubian Nile Valley and...

  7. Rock blocks

    OpenAIRE

    Turner, W.

    2007-01-01

    Consider representation theory associated to symmetric groups, or to Hecke algebras in type A, or to q-Schur algebras, or to finite general linear groups in non-describing characteristic. Rock blocks are certain combinatorially defined blocks appearing in such a representation theory, first observed by R. Rouquier. Rock blocks are much more symmetric than general blocks, and every block is derived equivalent to a Rock block. Motivated by a theorem of J. Chuang and R. Kessar in the case of sym...

  8. Training and Research on Probabilistic Hydro-Thermo-Mechanical Modeling of Carbon Dioxide Geological Sequestration in Fractured Porous Rocks

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez, Marte

    2013-05-31

    Colorado School of Mines conducted research and training in the development and validation of an advanced CO{sub 2} GS (Geological Sequestration) probabilistic simulation and risk assessment model. CO{sub 2} GS simulation and risk assessment is used to develop advanced numerical simulation models of the subsurface to forecast CO2 behavior and transport; optimize site operational practices; ensure site safety; and refine site monitoring, verification, and accounting efforts. As simulation models are refined with new data, the uncertainty surrounding the identified risks decrease, thereby providing more accurate risk assessment. The models considered the full coupling of multiple physical processes (geomechanical and fluid flow) and describe the effects of stochastic hydro-mechanical (H-M) parameters on the modeling of CO{sub 2} flow and transport in fractured porous rocks. Graduate students were involved in the development and validation of the model that can be used to predict the fate, movement, and storage of CO{sub 2} in subsurface formations, and to evaluate the risk of potential leakage to the atmosphere and underground aquifers. The main major contributions from the project include the development of: 1) an improved procedure to rigorously couple the simulations of hydro-thermomechanical (H-M) processes involved in CO{sub 2} GS; 2) models for the hydro-mechanical behavior of fractured porous rocks with random fracture patterns; and 3) probabilistic methods to account for the effects of stochastic fluid flow and geomechanical properties on flow, transport, storage and leakage associated with CO{sub 2} GS. The research project provided the means to educate and train graduate students in the science and technology of CO{sub 2} GS, with a focus on geologic storage. Specifically, the training included the investigation of an advanced CO{sub 2} GS simulation and risk assessment model that can be used to predict the fate, movement, and storage of CO{sub 2} in

  9. Carbon transformations by attached bacterial populations in granitic groundwater from deep crystalline bed-rock of the Stripa research mine.

    Science.gov (United States)

    Ekendahl, S; Pedersen, K

    1994-07-01

    This paper presents and compares the assimilation rates of CO2 and lactate, and the lactate respiration rates, of attached bacterial populations growing in slowly flowing groundwater (1-3 mm s-1) from deep crystalline bed-rock of the Stripa research mine, Sweden. The bacteria studied grew in anoxic, high-pH (9-10) and low-redox artesian groundwater flowing up through tubing from two levels of a borehole designated V2, 812-820 m and 970-1240 m below ground. Bacteria were allowed to attach to and grow on sterile glass microscope slides in laminar-flow reactors connected to the flowing groundwater. Total numbers of bacteria were counted by acridine orange direct counts. The bacteria grew slowly, with doubling times of 34 d at 10 degrees C for the 812-820 m population, 23 d for the 970-1240 m population at 10 degrees C and 16 d for this population at 20 degrees C. Numbers of attached bacteria reached between 10(6) and 10(7) bacteria cm-2. The populations at the two levels of the borehole were different in physiology as well as in phylogeny and reflected the heterogeneity between the sampling levels. The earlier proposed presence of sulphate-reducing bacteria could not be confirmed. This is discussed in relation to results from 16S rRNA gene sequencing studies. The CO2 assimilation rates (as mol CO2 cm-2 h-1, using liquid scintillation techniques) increased with depth and temperature.(ABSTRACT TRUNCATED AT 250 WORDS)

  10. ASSESSMENT OF CARBON DIOXIDE SEQUESTRATION POTENTIAL OF ULTRAMAFIC ROCKS IN CHINA%中国超基性岩封存CO2的潜力研究

    Institute of Scientific and Technical Information of China (English)

    盛雪芬; 季峻峰; 陈骏

    2011-01-01

    大气CO浓度上升引起的气候效应正受到国际社会的高度关注.超基性岩石与CO反应可生成稳定的碳酸盐矿物而永久性地固定CO,有效地降低人类活动排放到大气中CO浓度,从而缓解日趋严重的温室效应带来的全球气候恶化.根据各省记载的超基性岩体的岩石学、地球化学资料,按照公式:T=1/3·a·t·r·d·(1-φ)计算,对各省市自治区的CO封存量进行了详细统计和评估.计算表明,中国超基性岩封存CO的潜力巨大,总封存量可达13.02×10CO,约为2008年全国CO总排放量的1887倍.其中超过11.55×10t CO的封存量(占全国总量的89%)在西藏和新疆地区,其他地区占全国的11%,总量达到1.46x10tCO,相当于2008年全国总排放量的212倍,因此具有较高的碳封存潜力.由于各省工业产业结构分布的不均匀导致CO排放量有着很大的差异,因此利用超基性岩封存CO的潜力相差悬殊.东南沿海和华南地区等经济发达地区相对封存储量较少,应考虑其他方式来封存.%The global is facing a major challenge due to anthropogenic CO2 emission from the utilization of fossil fuels.Ultra-mafic rock storage is potential to reduce the atmospheric CO2 ,with high reactivity to form carbonates leading to a very stable sequestration, eventually to relief the increasingly dangerous global warming originating from the greenhouse effect.After the statistics on the data of petrology and geochemistry of the ultra-mafic rocks recorded in the regional geology of 27 provinces in China,we used the equation: T= 1/3 · a · t · r · d · (1-φ)( T is the potential CO2 storage capacity sequestrating in the ultra-mafic rocks; a is the area of the ultra-mafic rock outcrops; t is the estimated depth of the ultra-mafic rocks; r is how much CO2 can be consumed by 1 t peridotite or 1 t serpentine,which is 0. 63 t and 0. 46 t respectively; d is the densities of the ultra-mafic rocks, peridotite is 3.4g/mi3 and serpentine is

  11. Water-rock interaction under peri-glacial conditions: example of the secondary carbonates of the Broegger Peninsula (Spitzbergen); Interactions eaux-roches en milieu periglaciaire: exemple des carbonates secondaires de la presqu`ile de Broegger (Spitzberg)

    Energy Technology Data Exchange (ETDEWEB)

    Marlin, C.; Dever, L. [Paris-11 Univ., 91 - Orsay (France). Laboratoire d`Hydrologie et de Geochimie Isotopique

    1998-12-31

    Measurements of the isotopic and chemical contents of soil water and carbonates at different field sites in Spitzbergen were undertaken to study the precipitation conditions of soil secondary calcites under the current peri-glacial climate. A main experimental site (`cote 80`) has been established located on a fluvio-glacial terrasse at 80 m.a.s.l. near Ny Alesund (79 deg N, 12 deg. E). The active layer is at around 1.2 m depth on a continuous permafrost. The soil temperatures measured every 5 cm from the surface to the permafrost show that the freezing fronts move both the surface and permafrost, converging at around 0.6 m depth where the system is closed. During the beginning of the freezing period, the solute content increases in the residual water according to the distribution coefficient between water and ice. Calcite precipitation occurs in a second stage as indicated by the simultaneous decrease of the calcite saturation index and increase of the concentration of non-interactive elements. Chemical and isotopic ({sup 18}O, {sup 2}H, {sup 13}C et {sup 14}C) analyses have been made on the different samples with a mineralogical description of the carbonate coatings obtained by SEM and microprobe analyses. The isotopic values result from a mixing between recent calcites and `old` calcites. The recent calcites are probably in isotopic equilibrium with the present day solutions. The `old calcites` have precipitated under colder conditions than today. The low radiocarbon activities (10.2 to 24.8 pcm) of the `cote 80` site indicate that the `old calcites` have precipitated during the last interglacial period or an inter-stadial period of the Pleistocene. The good relationship between the carbon- 14 activity and the carbon- 13 content indicates that the beginning of the pedogenesis is not identical at all sites and is dependent on the timing of deglaciation and vulnerability of rocks to frost-weathering. (authors) 18 refs.

  12. Art Rocks with Rock Art!

    Science.gov (United States)

    Bickett, Marianne

    2011-01-01

    This article discusses rock art which was the very first "art." Rock art, such as the images created on the stone surfaces of the caves of Lascaux and Altimira, is the true origin of the canvas, paintbrush, and painting media. For there, within caverns deep in the earth, the first artists mixed animal fat, urine, and saliva with powdered minerals…

  13. Type division and controlling factor analysis of 3rd-order sequences in marine carbonate rocks

    Directory of Open Access Journals (Sweden)

    Yunbo Zhang

    2014-03-01

    Full Text Available Type division and controlling factor analysis of 3rd-order sequence are of practical significance to tectonic analysis, sedimentary environment identification, and other geological researches. Based on the comprehensive analysis of carbon and oxygen isotope trends, paleobathymetry and spectral-frequency of representative well logs, 3rd-order sequences can be divided into 3 types: (a global sea level (GSL sequence mainly controlled by GSL change; (b tectonic sequence mainly controlled by regional tectonic activity; and (c composite sequence jointly controlled by GSL change and regional tectonic activity. This study aims to identify the controlling factors of 3rd-order sequences and to illustrate a new method for classification of 3rd-order sequences of the middle Permian strata in the Sichuan Basin, China. The middle Permian strata in the Sichuan Basin consist of 3 basin-contrastive 3rd-order sequences, i.e., PSQ1, PSQ2 and PSQ3. Of these, PSQ1 is a GSL sequence while PSQ2 and PSQ3 are composite sequences. The results suggest that the depositional environment was stable during the deposition of PSQ1, but was activated by tectonic activity during the deposition of the middle Permian Maokou Formation.

  14. Water Resources of the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah - Draft Report

    Science.gov (United States)

    Welch, Alan H.; Bright, Daniel J.

    2007-01-01

    Summary of Major Findings This report summarizes results of a water-resources study for White Pine County, Nevada, and adjacent areas in east-central Nevada and western Utah. The Basin and Range carbonate-rock aquifer system (BARCAS) study was initiated in December 2004 through Federal legislation (Section 131 of the Lincoln County Conservation, Recreation, and Development Act of 2004) directing the Secretary of the Interior to complete a water-resources study through the U.S. Geological Survey, Desert Research Institute, and State of Utah. The study was designed as a regional water-resource assessment, with particular emphasis on summarizing the hydrogeologic framework and hydrologic processes that influence ground-water resources. The study area includes 13 hydrographic areas that cover most of White Pine County; in this report however, results for the northern and central parts of Little Smoky Valley were combined and presented as one hydrographic area. Hydrographic areas are the basic geographic units used by the State of Nevada and Utah and local agencies for water-resource planning and management, and are commonly defined on the basis of surface-water drainage areas. Hydrographic areas were further divided into subbasins that are separated by areas where bedrock is at or near the land surface. Subbasins represent subdivisions used in this study for estimating recharge, discharge, and water budget. Hydrographic areas represent the subdivision used for reporting summed and tabulated subbasin estimates.

  15. Water Resources of the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah

    Science.gov (United States)

    Welch, Alan H.; Bright, Daniel J.; Knochenmus, Lari A.

    2008-01-01

    INTRODUCTION This report summarizes results of a water-resources study for White Pine County, Nevada, and adjacent areas in east-central Nevada and western Utah. The Basin and Range carbonate-rock aquifer system (BARCAS) study was initiated in December 2004 through Federal legislation (Section 301(e) of the Lincoln County Conservation, Recreation, and Development Act of 2004; PL108-424) directing the Secretary of the Interior to complete a water-resources study through the U.S. Geological Survey, Desert Research Institute, and State of Utah. The study was designed as a regional water-resource assessment, with particular emphasis on summarizing the hydrogeologic framework and hydrologic processes that influence ground-water resources. The study area includes 13 hydrographic areas that cover most of White Pine County; in this report however, results for the northern and central parts of Little Smoky Valley were combined and presented as one hydrographic area. Hydrographic areas are the basic geographic units used by the State of Nevada and Utah and local agencies for water-resource planning and management, and are commonly defined on the basis of surface-water drainage areas. Hydrographic areas were further divided into subbasins that are separated by areas where bedrock is at or near the land surface. Subbasins are the subdivisions used in this study for estimating recharge, discharge, and water budget. Hydrographic areas are the subdivision used for reporting summed and tabulated subbasin estimates.

  16. Critical elements in sediment-hosted deposits (clastic-dominated Zn-Pb-Ag, Mississippi Valley-type Zn-Pb, sedimentary rock-hosted Stratiform Cu, and carbonate-hosted Polymetallic Deposits): A review: Chapter 12

    Science.gov (United States)

    Marsh, Erin; Hitzman, Murray W.; Leach, David L.

    2016-01-01

    Some sediment-hosted base metal deposits, specifically the clastic-dominated (CD) Zn-Pb deposits, carbonate-hosted Mississippi Valley-type (MVT) deposits, sedimentary-rock hosted stratiform copper deposits, and carbonate-hosted polymetallic (“Kipushi type”) deposits, are or have been important sources of critical elements including Co, Ga, Ge, and Re. The generally poor data concerning trace element concentrations in these types of sediment-hosted ores suggest that there may be economically important concentrations of critical elements yet to be recognized.

  17. Vulnerability of shallow ground water and drinking-water wells to nitrate in the United States: Model of predicted nitrate concentration in U.S. ground water used for drinking (simulation depth 50 meters) -- Input data set for sandstone and carbonate rocks (gwava-dw_sscb)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the presence or absence of sandstone and carbonate rock aquifers in the conterminous United States. The data set was used as an input data...

  18. Hydrogeology of, and ground-water flow in, a valley-fill and carbonate-rock aquifer system near Long Valley in the New Jersey Highlands

    Science.gov (United States)

    Nicholson, R.S.; McAuley, S.D.; Barringer, J.L.; Gordon, A.D.

    1996-01-01

    The hydrogeology of and ground-water flow in a valley-fill and carbonate-rock aquifer system were evaluated by using numerical-modeling techniques and geochemical interpretations to address concerns about the adequacy of the aquifer system to meet increasing demand for water. The study was conducted during 1987-90 by the U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection and Energy. The effects of recent and anticipated ground-water withdrawals on water levels, stream base flows, and water budgets were estimated. Simulation results indicate that recent withdrawals of 4.7 million gallons per day have resulted in water-level declines of up to 35 feet. Under conditions of increases in withdrawals of 121 percent, water levels would decline up to an additional 28 feet. The magnitude of predicted average base-flow depletion, when compared with historic low flows, indicates that projected increases in withdrawals may substantially deplete seasonal low flow of Drakes Brook and South Branch Raritan River. Results of a water-budget analysis indicate that the sources of water to additional supply wells would include leakage from the overlying valley-fill aquifer and induced leakage of surface water into the aquifer system. Results of water-quality analyses indicate that human activities are affecting the quality of the ground water. With the exception of an elevated iron concentration in water from one well, concentrations of inorganic constituents in water from 75 wells did not exceed New Jersey primary or secondary drinking-water regulations. Volatile organic compounds were detected in water from several wells; in two samples, concentrations of specific compounds exceeded drinking-water regulations.

  19. 'Wopmay' Rock

    Science.gov (United States)

    2004-01-01

    This approximate true-color image taken by NASA's Mars Exploration Rover Opportunity shows an unusual, lumpy rock informally named 'Wopmay' on the lower slopes of 'Endurance Crater.' The rock was named after the Canadian bush pilot Wilfrid Reid 'Wop' May. Like 'Escher' and other rocks dotting the bottom of Endurance, scientists believe the lumps in Wopmay may be related to cracking and alteration processes, possibly caused by exposure to water. The area between intersecting sets of cracks eroded in a way that created the lumpy appearance. Rover team members plan to drive Opportunity over to Wopmay for a closer look in coming sols. This image was taken by the rover's panoramic camera on sol 248 (Oct. 4, 2004), using its 750-, 530- and 480-nanometer filters.

  20. 鄂尔多斯奥陶系碳酸盐岩碳氧同位素特征及其意义%Characteristics of carbon and oxygen isotopes of the Ordovician carbonate rocks in Ordos and their implication

    Institute of Scientific and Technical Information of China (English)

    陈强; 张慧元; 李文厚; 郝松立; 刘卓

    2012-01-01

    鄂尔多斯古生代海相地层沉积厚度巨大.鄂尔多斯奥陶系碳酸盐岩的碳氧同位素组成受后期成岩作用影响较小,基本保留了原始海洋的同位素组成:δ13C值分布于-7.30‰~2.26‰之间,均值-0.30‰;δ18O值分布于-13.14‰~-1.94‰之间,均值-6.38‰,碳氧同位素组成与全球基本一致.区域上,鄂尔多斯西缘具有相对较高的δ13C值,南缘次之,而东缘最低.纵向上,碳同位素组成逐渐增重,并在中晚奥陶世发生明显的正向偏移,δ13C均值由马家沟组的-0.36‰增加到平凉组的0.15‰,至背锅山组增加至0.68‰.碳同位素的区域分布差异表明鄂尔多斯西缘水体相对较深,南缘次之,东缘相对较浅,由早奥陶世至晚奥陶世水体逐渐加深,碳同位素组成反映的海平面变化趋势与沉积相演化一致.鄂尔多斯西南缘中晚奥陶世碳同位素组成的正向偏移,标志着较高的生产力和有机碳埋藏率,具有重要的石油地质学意义,西南缘的平凉组/乌拉力克组和背锅山组是下古生界最重要和有效的烃源岩层.%The Ordos has gigantically thick Paleozoic marine strata. The carbon and oxygen isotopes of the Ordovician carbonate rocks in the Ordos are less modified by post-depositional diagenesis, and thus provide helpful insights into the original ocean. The δ13C values of the Ordovician carbonate rocks in the Ordos range from - 7. 30‰ to 2. 26‰ with a mean value of - 0. 30‰ and the δ18O varies between -13. 14‰ and -1.94‰, averaging at -6. 38‰, which indicate the carbon and oxygen isotopes of the Ordovician in the Ordos are comparable to those of the global Ordovician. Spatially, the δ13C shows a decreasing trend, indicating shoaling in water-depth from the western margin of the Ordos, to the southern margin and then to the eastern margin. Temporally, the S C gradually increases, showing that sea level rose from the Early to the Late Ordovician, with a significant

  1. Source rock

    OpenAIRE

    Abubakr F. Makky; Mohamed I. El Sayed; Ahmed S. Abu El-Ata; Ibrahim M. Abd El-Gaied; Mohamed I. Abdel-Fattah; Zakaria M. Abd-Allah

    2014-01-01

    West Beni Suef Concession is located at the western part of Beni Suef Basin which is a relatively under-explored basin and lies about 150 km south of Cairo. The major goal of this study is to evaluate the source rock by using different techniques as Rock-Eval pyrolysis, Vitrinite reflectance (%Ro), and well log data of some Cretaceous sequences including Abu Roash (E, F and G members), Kharita and Betty formations. The BasinMod 1D program is used in this study to construct the burial history ...

  2. Ayers Rock

    Institute of Scientific and Technical Information of China (English)

    王慧茹

    2002-01-01

    Ayers Rock is right in the centre of Australia.It's nearly two thousand kilometres______Sydney.So we flew most of the way.h was rather cloudy______But after we left the mountains behind us, there was hardly a cloud in thesky.

  3. Intellektuaalne rock

    Index Scriptorium Estoniae

    2007-01-01

    Briti laulja-helilooja ja näitleja Toyah Willcox ning Bill Rieflin ansamblist R.E.M. ja Pat Mastelotto King Krimsonist esinevad koos ansamblitega The Humans ja Tuner 25. okt. Tallinnas Rock Cafés ja 27. okt Tartu Jaani kirikus

  4. Rock Paintings.

    Science.gov (United States)

    Jones, Julienne Edwards

    1998-01-01

    Discusses the integration of art and academics in a fifth-grade instructional unit on Native American culture. Describes how students studied Native American pictographs, designed their own pictographs, made their own tools, and created rock paintings of their pictographs using these tools. Provides a list of references on Native American…

  5. A Cenozoic record of the equatorial Pacific carbonate compensation depth

    Digital Repository Service at National Institute of Oceanography (India)

    Palike, H.; Lyle, M.W.; Nishi, H.; Raffi, I.; Ridgwell, A; Gamage, K.; Klaus, A; Acton, G.; Anderson, L.; Backman, J.; Baldauf, J.; Beltran, C.; Bohaty, S.M.; Bown, P.; Busch, W.; Channell, J.E.T.; Chun, C.O.J.; Delaney, M.; Dewangan, P.; et al.

    of silicate rocks and organic-carbon-bearing rocks. The integrated effect of these processes is reflected in the calcium carbonate compensation depth, which is the oceanic depth at which calcium carbonate is dissolved. Here we present a carbonate accumulation...

  6. High-temperature carbidization of carboniferous rocks

    Science.gov (United States)

    Goldin, B. A.; Grass, V. E.; Nadutkin, A. V.; Nazarova, L. Yu.

    2009-08-01

    Processes of thermal metamorphism of carboniferous rocks have been studied experimentally. The conditions of high-temperature interaction of shungite carbon with components of the contained rocks, leading to formation of carbide compounds, have been determined. The results of this investigation contribute to the works on searching for new raw material for prospective material production.

  7. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2016-01-01

    20160255 Wang Na(Tianjin Center of Geological Survey,China Geological Survey,Tianjin 300170,China);Teng Xinhua Determination of Low-Content Iron Carbonate in Stream Sediments by Flame Atomic Absorption Spectrometry with Aluminum Chloride Extraction(Rock and Mineral Analysis,ISSN0254-5357,CN11-2131/TD,34(2),2015,p.229

  8. 北京西山昌平组下部角砾碳酸盐岩类型及成因%THE CLASSIFICATION AND GENESIS OF BRECCIA CARBONATE ROCK IN LOWER PART OF CHANGPING FORMATION OF XISHAN, BEIJING

    Institute of Scientific and Technical Information of China (English)

    杨舒然; 廖志坚

    2011-01-01

    The genesis of breccia carbonate rocks in lower part of Changping Formation can be divided into 2 types, which are separately 1. the weathering sedentary breccia; 2. the gravity flow breccia. The genetic mecha- nism is the gentle slope gravity flow in transition from platform to slope.%昌平组下部角砾状碳酸盐岩有两类成因,分别为风化残积角砾岩和重力流角砾岩,其成因机制为由台地向斜坡过渡的缓坡重力流形成。

  9. Geologic assessment of undiscovered oil and gas resources—Lower Cretaceous Albian to Upper Cretaceous Cenomanian carbonate rocks of the Fredericksburg and Washita Groups, United States Gulf of Mexico Coastal Plain and State Waters

    Science.gov (United States)

    Swanson, Sharon M.; Enomoto, Catherine B.; Dennen, Kristin O.; Valentine, Brett J.; Cahan, Steven M.

    2017-02-10

    In 2010, the U.S. Geological Survey (USGS) assessed Lower Cretaceous Albian to Upper Cretaceous Cenomanian carbonate rocks of the Fredericksburg and Washita Groups and their equivalent units for technically recoverable, undiscovered hydrocarbon resources underlying onshore lands and State Waters of the Gulf Coast region of the United States. This assessment was based on a geologic model that incorporates the Upper Jurassic-Cretaceous-Tertiary Composite Total Petroleum System (TPS) of the Gulf of Mexico basin; the TPS was defined previously by the USGS assessment team in the assessment of undiscovered hydrocarbon resources in Tertiary strata of the Gulf Coast region in 2007. One conventional assessment unit (AU), which extends from south Texas to the Florida panhandle, was defined: the Fredericksburg-Buda Carbonate Platform-Reef Gas and Oil AU. The assessed stratigraphic interval includes the Edwards Limestone of the Fredericksburg Group and the Georgetown and Buda Limestones of the Washita Group. The following factors were evaluated to define the AU and estimate oil and gas resources: potential source rocks, hydrocarbon migration, reservoir porosity and permeability, traps and seals, structural features, paleoenvironments (back-reef lagoon, reef, and fore-reef environments), and the potential for water washing of hydrocarbons near outcrop areas.In Texas and Louisiana, the downdip boundary of the AU was defined as a line that extends 10 miles downdip of the Lower Cretaceous shelf margin to include potential reef-talus hydrocarbon reservoirs. In Mississippi, Alabama, and the panhandle area of Florida, where the Lower Cretaceous shelf margin extends offshore, the downdip boundary was defined by the offshore boundary of State Waters. Updip boundaries of the AU were drawn based on the updip extent of carbonate rocks within the assessed interval, the presence of basin-margin fault zones, and the presence of producing wells. Other factors evaluated were the middle

  10. 岩石风化碳汇研究的最新进展和展望%New progress and prospects in the study of rock-weathering-related carbon sinks

    Institute of Scientific and Technical Information of China (English)

    刘再华

    2012-01-01

    , the contribution of silicate weathering to the atmospheric CO2 sink may be only 6%, while the other 94% is accounted for by carbonate weathering. On the other hand, owing to the aquatic photosynthetic uptake of the weathering-related DIC and burial of some of the resulting (autochthonous) organic C, the atmospheric CO2 sink relating tocarbonate weathering might be important in controlling both short-term and long-term climate change. Another new finding is that rock-weathering-related carbon sinks have increased with global warming and land-use change, acting as a negative mechanism for global warming. Future investigation should focus on the in-depth study of rock weathering processes and mechanisms in carbon capture and storage, so as to reveal the regulating potential of the carbon sink according to the climate and land use, which will serve countries in their decision making with respect to climate change. Important study topics include (1) rock weathering processes and controlling mechanisms of climate and land use in carbon sinks, (2) the importance of small amounts of carbonate minerals in controlling the DIC and carbon sink of silicate watersheds, (3) the ratio of autochthonous carbon in total organic carbon, and (4) the regulating potential of rock-weathering-related carbon sinks according to climate and land use.

  11. 上扬子地区早三叠世异常碳酸盐岩的分类与特征%Classification and characters of the Early Triassic anomalous carbonate rocks in Upper Yangtze Area

    Institute of Scientific and Technical Information of China (English)

    时志强; 安红艳; 伊海生; 张华; 曾德勇

    2011-01-01

    The anomalous carbonates of the late period of Late Permian and Early Triassic in the Upper Yangtze Area can be divided into three main types by genesis: A—biogenic anomalous carbonate rocks, B—abiogenetic (chemical and hydrodynamic ) anomalous carbonate rocks, C—multi-genetic anomalous carbonate rocks. Eight specific sorts of the anomalous carbonate rocks can be further distinguished, including microbiolite, brecciform limestone, flat-pebble limestone, ribbon limestone, thinbedded or laminated argillaceous limestone, oolitic limestone and 2 kinds of vermiculate limestone ( Type a and Type b). The extreme palaeoceanic environment and paleoclimatic conditions are the basis of the development of the anomalous carbonate rocks (mainly anachronistic facies) around P/T boundary. After the P/T mass extinction, the destruction of benthonic animals living on the surface of marine sediments was nearly stopped and the ocean currents were almost stagnated, meanwhile the surface layer of the sea water suffered the disturbing of megamonsoon and cyclonic storms, the algo-fungus ecosystem of euphoriczone grew and formed the wave-resistance microbiolites on the biohermal facies or on the shallow water carbonate platform. Seafloor was often affected by frequent storms which tear up the unconsolidated syngenetic carbonate ooze and thus the syngenetic pebble formed. At the same time, the particular gradient of the paleotopography intensified the development of carbonate gravity flows which might also be triggered by the storms; moreover the calcium carbonate-supersaturated sea water allowed the carbonate directly precipitating in the forms of chemical precipitation on the seafloor and the clays brought by the megamonsoon deposited together with the carbonate chemical precipitation. All the mentioned process happened at the earliest Early Triassic specific palaeoenvironment, which resulted in the appearance of the diverse anomalous carbonate deposition in the Upper Yangzte Area

  12. CERN Rocks

    CERN Multimedia

    2004-01-01

    The 15th CERN Hardronic Festival took place on 17 July on the terrace of Rest 3 (Prévessin). Over 1000 people, from CERN and other International Organizations, came to enjoy the warm summer night, and to watch the best of the World's High Energy music. Jazz, rock, pop, country, metal, blues, funk and punk blasted out from 9 bands from the CERN Musiclub and Jazz club, alternating on two stages in a non-stop show.  The night reached its hottest point when The Canettes Blues Band got everybody dancing to sixties R&B tunes (pictured). Meanwhile, the bars and food vans were working at full capacity, under the expert management of the CERN Softball club, who were at the same time running a Softball tournament in the adjacent "Higgs Field". The Hardronic Festival is the main yearly CERN music event, and it is organized with the support of the Staff Association and the CERN Administration.

  13. Evolution of Sedimentary Rocks

    Science.gov (United States)

    Veizer, J.; MacKenzie, F. T.

    2003-12-01

    For almost a century, it has been recognized that the present-day thickness and areal extent of Phanerozoic sedimentary strata increase progressively with decreasing geologic age. This pattern has been interpreted either as reflecting an increase in the rate of sedimentation toward the present (Barrell, 1917; Schuchert, 1931; Ronov, 1976) or as resulting from better preservation of the younger part of the geologic record ( Gilluly, 1949; Gregor, 1968; Garrels and Mackenzie, 1971a; Veizer and Jansen, 1979, 1985).Study of the rocks themselves led to similarly opposing conclusions. The observed secular (=age) variations in relative proportions of lithological types and in chemistry of sedimentary rocks (Daly, 1909; Vinogradov et al., 1952; Nanz, 1953; Engel, 1963; Strakhov, 1964, 1969; Ronov, 1964, 1982) were mostly given an evolutionary interpretation. An opposing, uniformitarian, approach was proposed by Garrels and Mackenzie (1971a). For most isotopes, the consensus favors deviations from the present-day steady state as the likely cause of secular trends.This chapter attempts to show that recycling and evolution are not opposing, but complementary, concepts. It will concentrate on the lithological and chemical attributes of sediments, but not deal with the evolution of sedimentary mineral deposits (Veizer et al., 1989) and of life ( Sepkoski, 1989), both well amenable to the outlined conceptual treatment. The chapter relies heavily on Veizer (1988a) for the sections dealing with general recycling concepts, on Veizer (2003) for the discussion of isotopic evolution of seawater, and on Morse and Mackenzie (1990) and Mackenzie and Morse (1992) for discussion of carbonate rock recycling and environmental attributes.

  14. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20101621 Chen Heping (Nanyang Geology Testing & Research Center of Henan Province, Nanyang 473000, China); Sha Yanmei Simultaneous Determination of Major and Minor Elements in Carbonates by Inductively Coupled Plasma-Atomic Emission Spectrometry with Multi-direction Viewing Mode (Rock and Mineral Analysis, ISSN0254-5357, CN11-2131/TD, 28(4), 2009, p.367-369, 5 tables, 10 refs.)

  15. 87Sr/86Sr Ratios in Carbonate From the Red Lake and Steep Rock Groups in Canada Suggest Rb-enriched Continental Crust was Influencing Seawater Chemistry Prior to 3.0 Ga

    Science.gov (United States)

    Satkoski, A.; Fralick, P. W.; Beard, B. L.; Johnson, C.

    2015-12-01

    Previous work has suggested that prior to 2.5 Ga, Sr isotope compositions of seawater were essentially mantle buffered and the effects of continental weathering on seawater chemistry were negligible. To test this, we collected Sr isotope data from 2.93 and 2.80 Ga carbonates that are part of the Red Lake and Steep Rock groups (Canada), respectively. To better understand carbonate formation and any post-depositional alteration, Sr isotopes are considered with O isotopes and REEs, as well as Rb and Sr contents, including correction for decay of 87Rb. All samples have Y/Ho ratios higher than chondrite and have positive La anomalies, which, combined with low Rb contents suggests that clastic contamination is negligible. Samples we consider near pristine have δ18O (VSMOW) values >20‰. Samples with the highest Y/Ho ratios and largest La anomalies from Red Lake and Steep Rock have initial 87Sr/86Sr ratios of 0.7018-0.7020. This Sr isotope composition is significantly more radiogenic than contemporaneous mantle (0.7011-0.7012), especially at a time when the isotopic difference between the crust and mantle was much less than today. This implies that radiogenic continental crust was emergent and shed detritus into the world's oceans prior to 3.0 Ga, in contrast with proposals for submerged continental crust, but in line with new estimates that continental crust at 3.0 Ga was 60-70% of current volume. We contend that this large amount of crust combined with enhanced Archean weathering could account for the radiogenic Sr isotope compositions we report here, and suggests a significant impact from continental weathering on ocean chemistry during the Archean.

  16. Fractures network analysis and interpretation in carbonate rocks using a multi-criteria statistical approach. Case study of Jebal Chamsi and Jebal Belkhir, South-western part of Tunisia

    Science.gov (United States)

    Msaddek, Mohamed Haythem; Moumni, Yahya; Chenini, Ismail; Mercier, Eric; Dlala, Mahmoud

    2016-11-01

    The quantitative analysis of fractures in carbonate rocks across termination folds is important for the understanding of the fractures network distribution and arrangement. In this study, we performed a quantitative analysis and interpretation of fracture network to identify the fracture networks type. For this reason, we used a multi-criteria statistical analysis. The distribution of directional families in all measured stations and their elemental distribution are firstly examined. Then we performed the analysis of directional criteria for each of the two and three neighbouring stations. Finally, the elemental analyses of fracture families crossing others were carried out. This methodology was applied to the folds of Jebal Chamsi and Jebal Belkhir areas located in south western Tunisia characterized by simple folds of carbonate geological formations. The application of the global and the elemental statistical analysis criteria of directional families show a random arrangement of fractures. However, elemental analysis of two and three neighbouring stations for families crossing one another shows a pseudo-organization of fracture arrangements.

  17. Rock formation characterization for CO2-EOR and carbon geosequestration; 3D seismic amplitude and coherency anomalies, Wellington Field, Kansas, USA

    Science.gov (United States)

    Ohl, D.; Raef, A.; Watnef, L.; Bhattacharya, S.

    2011-01-01

    In this paper, we present a workflow for a Mississipian carbonates characterization case-study integrating post-stack seismic attributes, well-logs porosities, and seismic modeling to explore relating changes in small-scale "lithofacies" properties and/or sub-seismic resolution faulting to key amplitude and coherency 3D seismic attributes. The main objective of this study is to put emphasis on reservoir characterization that is both optimized for and subsequently benefiting from pilot tertiary CO2-EOR in preparation for future carbon geosequestration in a depleting reservoir and a deep saline aquifer. The extracted 3D seismic coherency attribute indicated anomalous features that can be interpreted as a lithofacies change or a sub-seismic resolution faulting. A 2D finite difference modeling has been undertaken to understand and potentially build discriminant attributes to map structural and/or lithofacies anomalies of interest especially when embarking upon CO2-EOR and/or carbon sequestration monitoring and management projects. ?? 2011 Society of Exploration Geophysicists.

  18. Evaluation of Five Sedimentary Rocks Other Than Salt for Geologic Repository Siting Purposes

    Energy Technology Data Exchange (ETDEWEB)

    Croff, A.G.; Lomenick, T.F.; Lowrie, R.S.; Stow, S.H.

    2003-11-15

    The US Department of Energy (DOE), in order to increase the diversity of rock types under consideration by the geologic disposal program, initiated the Sedimary ROck Program (SERP), whose immediate objectiv eis to evaluate five types of secimdnary rock - sandstone, chalk, carbonate rocks (limestone and dolostone), anhydrock, and shale - to determine the potential for siting a geologic repository. The evaluation of these five rock types, together with the ongoing salt studies, effectively results in the consideration of all types of relatively impermeable sedimentary rock for repository purposes. The results of this evaluation are expressed in terms of a ranking of the five rock types with respect to their potential to serve as a geologic repository host rock. This comparative evaluation was conducted on a non-site-specific basis, by use of generic information together with rock evaluation criteria (RECs) derived from the DOE siting guidelines for geologic repositories (CFR 1984). An information base relevant to rock evaluation using these RECs was developed in hydrology, geochemistry, rock characteristics (rock occurrences, thermal response, rock mechanics), natural resources, and rock dissolution. Evaluation against postclosure and preclosure RECs yielded a ranking of the five subject rocks with respect to their potential as repository host rocks. Shale was determined to be the most preferred of the five rock types, with sandstone a distant second, the carbonate rocks and anhydrock a more distant third, and chalk a relatively close fourth.

  19. Determination of chlorine in silicate rocks

    Science.gov (United States)

    Peck, L.C.

    1959-01-01

    In a rapid accurate method for the determination of chlorine in silicate rocks, the rock powder is sintered with a sodium carbonate flux containing zinc oxide and magnesium carbonate. The sinter cake is leached with water, the resulting solution is filtered, and the filtrate is acidified with nitric acid. Chlorine is determined by titrating this solution with mercuric nitrate solution using sodium nitroprusside as the indicator. The titration is made in the dark with a beam of light shining through the solution. The end point of the titration is found by visually comparing the intensity of this beam of light with that of a similar beam of light in a reference solution.

  20. Rock Plasticity from Microtomography and Upscaling

    Institute of Scientific and Technical Information of China (English)

    Jie Liu; Reem Freij-Ayoub; Klaus Regenauer-Lieb

    2015-01-01

    We present a workflow for upscaling of rock properties using microtomography and percolation theory. In this paper we focus on a pilot study for assessing the plastic strength of rocks from a digital rock image. Firstly, we determine the size of mechanical representative volume ele-ment (RVE) by using upper/lower bound dissipation computations in accordance with thermody-namics. Then the mechanical RVE is used to simulate the rock failure at micro-scale using FEM. Two cases of different pressures of linear Drucker-Prager plasticity of rocks are computed to com-pute the macroscopic cohesion and the angle of internal friction of the rock. We also detect the criti-cal exponents of yield stress for scaling laws from a series of derivative models that are created by a shrinking/expanding algorithm. We use microtomographic data sets of two carbonate samples and compare the results with previous results. The results show that natural rock samples with irregular structures may have the critical exponent of yield stress different from random models. This unex-pected result could have significant ramifications for assessing the stability of solid materials with internal structure. Therefore our pilot study needs to be extended to investigate the scaling laws of strength of many more natural rocks with irregular microstructure.

  1. Geotechnical Descriptions of Rock and Rock Masses.

    Science.gov (United States)

    1985-04-01

    weathering is presented by Dornbusch (1982). 39. Mechanical, or physical, weathering of rock occurs primarily by (a) freeze expansion (or frost wedging...34Engineering Classifica- tion of In-Situ Rock," Technical Report No. AFWL-TR-67-144, Air Force Weapons Laboratory, Kirtland Air Force Base, N. Mex. Dornbusch , W

  2. STUDY ON THE PERMEABILITY OF CARBONATE ROCK GEOTHERMAL RESERVOIR IN BEIJING%北京地区碳酸盐岩热储渗透性研究

    Institute of Scientific and Technical Information of China (English)

    王树芳; 庞忠和; 何铁柱; 林沛; 刘凯; 刘久荣

    2014-01-01

    Beijing as capital of China is located in North China.The geothermal field in Beijing is mainly medium-low temperature conductive type,in which the Wumishan Formation with a thickness of more than 2000m of the Jixian System is the main reservoir and the rock of the Wumishan Formation is dolomite.Conductivity of the reservoir was usually calculated to understand reservoir characteristics, which could not accurately reflect permeability of the reservoir due to density variation of geothermal water.In order to understand permeability of the reservoir to direct geothermal resources development,porosity and permeability data of 34 dolomite rock cores collected from field outcrop and down-hole were compared and analyzed.The results indicated that permeability of outcrop and down-hole ranges are (10.0001 158 ~0.33333 )×10-3 μm2 and (0.0088 ~0.334 )×10-3 μm2 respectively,and the average value are 0.0622321×10-3μm2 and 0.385316×10-3μm2.The porosity ranges from 0.25%to 3.00%.The permeability of the rock cores are so low that geothermal energy could not be exacted without factures and fissures generated from tectonic movement and karstification.Therefore,permeability calculated from pump test could reflect total permeability of rock matrix,fractures and fissures.The calculated permeability of reservoir from 110 pump tests ranges from 13.74×10-3μm2 to 104474.00×10-3μm2,and the average is 4797.58× 10-3μm2.The cumulated percentage of permeability values between 100×10-3μm2 and 1000×10-3μm2 are more than 75%,the values less than 100×10-3μm2 are only 13.64%,and the permeability values greater than 100000× 10-3μm2 are 0.91 percent.In order to demonstrate relationship between reservoir buried depth and permeability, the buried depth were divided into 500m,500~1000m,1000~1500m,1500~2000m,2000~2500m,2500~3000m and 3000~3500m.The average permeability and average buried depth were plotted together in x,y coordi-nates.The results indicated that the average

  3. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110887 Chen Yong(College of Geo-Resources and Information,China University of Petroleum,Qingdao 266555,China);Ge Yunjin Experimental Study on the Modes of Hydrocarbon-Bearing Inclusion Trapped in Carbonate Rock Reservoirs(Rock and Mineral Analysis,ISSN0254-5357,CN11-2131/TD,29(3),2010,p.217-220,1 illus.,16 refs.,with English abstract)Key words:petroleum products,organic inclusion,carbonates20110888 Cheng Zhizhong(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang 065000,China);Gu Tiexin Preparation of Nine Iron Ore Reference Materials of GFe-1~GFe-9(Rock and Mineral Analysis,ISSN0254-5357,CN11-2131/TD,29(3),2010,p.305-308,5 tables,13 refs.)Key words:iron ores,type specimens Nine standard reference iron ore samples of GFe-1~GFe-9 were developed.The concentrations of TFe of the samples ranged from 20.17% to 66.87%,which covered a wide iron concentration range from concentrated iron ore powder to poor iron ores and can meet the needs for iron ore exploration and ore-dressing.Powder XRF technique was used for homogeneity test and the analytical results indicated that all elements tested were in good homogeneity.

  4. Logging identification methods of clastic and carbonate rocks and their differences%应用测井技术识别碎屑岩与碳酸盐岩地质事件及其差异

    Institute of Scientific and Technical Information of China (English)

    李浩; 游瑜春; 郑亚斌; 张渝丽; 魏修平; 王丹丹

    2011-01-01

    应用测井技术识别地质事件时,对具有隐蔽测井信息结构变化的识别涉及较少,限制了认知地质事件的精度和可靠性.而根据测井记录的地质响应及其相关测井信息组合特征,研究重要地质事件的多样性与测井曲线之间的成因关系,以及测井曲线纵、横向变化与地质演变的成因关系,可以探索性地解决上述问题.运用该方法可识别出碎屑岩和碳酸盐岩地质事件并推断其成因机理.通过对地质事件表现形式多样性的分析,提出了碎屑岩地质事件的识别和论证方法;通过同成因地质界面的识别与追踪,提出了碳酸盐岩"同期异相"地层对比问题的识别方法和依据.地层的岩性成因机制不同,碎屑岩和碳酸盐岩地层的地质事件研究方法也有所不同,二者的识别差别在于地质界面的追踪依据不同、地质界面的测井响应特征不同以及测井信息与地质界面识别的对应关系不同.应用该方法,成功解决了大港油田、普光气田以及澳大利亚等国内外油气探区地质研究中地质界面识别的关键问题.%Log technique have been employed in the recognition of many meaningful geological events. However, the subtle changes of logs are seldom recognized and used, thus limiting the accuracy and reliability of interpretation. The issue could be tackled be establishing genetic relationships between the variety of important geological events and logs, and that between geological evolution and the vertical and horizontal changes of the logs based on a comprehensive study on geological responses and the combined features of associated logs. The method is used to identify geological events of clastic and carbonate rocks as well as their formation mechanism.Based on an analysis of the variety of geological events, an approach for identifying geological events of clastic rocks is proposed. Through identification and tracing of isogenesis geologic boundaries, an

  5. Characterisation of carbonate rocks from near-surface cross-hole and reflection GPR investigations - A case study from southeast Zealand, Denmark

    DEFF Research Database (Denmark)

    Nielsen, Lars; Looms, Majken Caroline; Hansen, Thomas Mejer

    the boreholes for lithological control and to facilitate laboratory measurements of porosity and permeability. Cross-hole GPR data were collected between boreholes with 100 MHz Sensors&Software antennae. The distance between source and receiver antenna positions in the boreholes was set to 0.25 m. Mounded...... to facilitate deeper imaging of the carbonates. The section studied with the cross-hole data is water-saturated. Simple 1D modelling of the cross-hole data indicates a strong drop in GPR velocity at 7 to 8 m depth. Different 2D inversion strategies are tested for fine scale resolution of the inter...

  6. Organic matter in deep carbonate rocks of the Tarim Basin, NW China%塔里木盆地深层碳酸盐岩中有机质特征

    Institute of Scientific and Technical Information of China (English)

    周世新; 宋振响; 王保忠; 贾星亮; 李靖

    2011-01-01

    Compositions of free and inclusion organic matter and the individual hydrocarbon isotopic compositions of n-alkanes and isoalkanes were investigated in deep carbonate rocks from the Tacan 1 well of the Tarim Basin.The comparison reveals that there are different evolutional trends for biomarker maturity parameters in different occurrences of organic matter at the high- and over-mature stage.The biomarker thermal maturity parameters of Ts/Tm for C27 hopanes and tricyclics/hopanes ratio can still be used to estimate the maturity of source-rock extracts when Ro is in the range of 1.0%-1.3%.Wherces, these biomarker parameters showed reverse trends and are not useful for maturity assessment when Ro is over 1.3%.The two ratios of C29 sterane isomerization, 205/(205+20R) and ββ/ββ+αα),also showed reverse change trends and can not be used to indicate the level of maturity when Ro is more than 1.1%.Although there are obvious different molecular compositions between free organic matter (chloroform bitumen A) and inclusion organic matter (chloroform bitumen C) in the deep carbonate rocks, the carbon isotopic values of n-alkanes and isoalkanes have similar values for the same samples with two different existence states, which indicates that the organic matters in the two existence states are derived from the same precursor, and their differences in molecular composition characteristics are due to the difference in thermal maturity.%通过对塔里木盆地塔参1井深层碳酸盐岩中游离有机质和包裹有机质组成及正、异构烷烃单体烃碳同位素组成特征的对比研究发现,在高-过成熟演化阶段,不同赋存形式有机质中常用生物标志化合物成熟度参数存在明显不同的响应.R值为1.0%~1.3%时,Ts/Tm和Σ三环萜/Σ藿烷参数仍可用作成熟度指标;当R值大于1.3%时,这两项参数变化趋势发生反转,不能用以表征有机质的热演化程度.C甾烷两项成熟度参数20S/(20S+20R)和

  7. The Formation and Distribution of the Marine Hydrocarbon Source Rock in the Tarim Basin, NW China

    Institute of Scientific and Technical Information of China (English)

    CAI Xiyuan; WANG Yi

    2008-01-01

    There are significant differences in type and distribution between marine source rock and continental source rock. According to the lithology, the Cambrian-Ordovician source rock in the Tarim basin is divided into two types: the carbonate source rock and the mud source rock. The two sets of source rocks are developed mainly in three sets of formations, Lower-Middle Cambrian carbonate source rock and mud source rock, Lower-Middle Ordovician mud source rock and Upper Ordovician lime mud source rock. The stratigraphic and areal distributions of the source rocks are controlled by the altitude and the sedimentary facies respectively. The mud source rock is developed in slope-semi deep sea environment. The source rock developed in the slope sedimentary environment is related with the anoxic environment and the one developed in semi deep sea has a close relationship with the up-flowing sea water. The carbonate source rock is developed mainly in platform slope of highstand systems tract and it is usually intimately associated with the salt rock. The Lower-Middle Cambrian carbonate source rock is developed mainly in the Bachu, Tazhong, Taugguzibasi and Yingmaili areas. The Lower-Middle Cambrian mud source rock is mainly developed in the areas east of the line of Kunan 1-Tadong 1. The Lower-Middle Ordovician mud source rock is developed mainly in the east slope of the Manjiaer depression. The carbonate source rock of Early Ordovician is developed mainly in the platform slope of highstand systems tract, such as the south margin of Tabei, the north slope of Tazhong, the Bachu area and Keping area.

  8. Graphitic Carbons and Biosignatures

    OpenAIRE

    Bernard, S.; Papineau, D

    2014-01-01

    The unambiguous identification of graphitic carbons as remains of life in ancient rocks is challenging because fossilized biogenic molecules are inevitably altered and degraded during diagenesis and metamorphism of the host rocks. Yet, recent studies have highlighted the possible preservation of biosignatures carried by some of the oldest graphitic carbons. Laboratory simulations are increasingly being used to better constrain the transformations of organic molecules into graphitic carbons in...

  9. My Pet Rock

    Science.gov (United States)

    Lark, Adam; Kramp, Robyne; Nurnberger-Haag, Julie

    2008-01-01

    Many teachers and students have experienced the classic pet rock experiment in conjunction with a geology unit. A teacher has students bring in a "pet" rock found outside of school, and the students run geologic tests on the rock. The tests include determining relative hardness using Mohs scale, checking for magnetization, and assessing luster.…

  10. Diagenetic environments of calcite veins hosted in marine carbonate rocks in middle Yangtze region of South China%中扬子海相碳酸盐岩中方解石脉成岩环境研究

    Institute of Scientific and Technical Information of China (English)

    王芙蓉; 何生; 杨兴业

    2011-01-01

    Analyses of thin slices, cathodoluminescence and carbon-oxygen isotope of calcite veins hosted in marine carbonate rocks distributed around Jingshan County in the middle Yangtze region of South China indicated that, two crystal forms including radial calcite and isometric texture calcite could be identified in calcite veins in the Triassic and the cathodoluminescence intensity was different. The Permian and Ordovician fractures were mainly filled with isometric texture calcite veins and the cathodoluminescence intensity was similar with that of the surrounding rocks. The δl3 CPDB value of calcite veins ranged from -6. 76‰ to 4. Ol‰and the δ18 OPDB value ranged from -17. 95‰to -5. 67‰, indicating the marine phreatic environment and the mixing phreatic environment for calcite veins deposition. Calcite veins in the Triassic were sedimentary origin, and part of calcite veins in the Permian and the Ordovician suffered latter diagenetic fluid dissolution. Fluid generated from organic-matter maturation effected the formation of calcite veins in the Permian to some degree.%通过对中扬子京山县城周边露头碳酸盐岩中方解石脉的普通薄片、阴极发光以及碳氧同位索等资料分析,认为该区露头三叠系裂隙中充填放射状和等轴粒状的方解石且阴极发光强度有差异,二叠系和奥陶系裂隙中主要为等轴粒状方解石,阴极发光与围岩相似.方解石脉的δ13CPDB位于-6.76‰~4.01‰之间,δ18OPDB在-17.95‰~-5.67‰之间,基本为海水潜流带一混合水潜流带沉积环境.三叠系方解石脉基本上为沉积碳酸盐岩,二叠系和奥陶系部分方解石脉受后期成岩流体的影响,其中二叠系有饥质成熟产生的流体对该层系方解石脉的形成有一定影响.

  11. 湖相碳酸盐岩烃源岩有机显微组分分类及其岩石学特征——以酒西盆地为例%A petrographic classification of macerals in lacustrine carbonate source rocks and their organic petrological characteristics: A case study on Jiuxi basin, NW China

    Institute of Scientific and Technical Information of China (English)

    涂建琪; 陈建平; 张大江; 程克明; 陈建军; 杨智明

    2012-01-01

    酒西盆地主力烃源岩为下白垩统下沟组和赤金堡组暗色半深湖相-深湖相的白云质泥岩和泥质白云岩,是典型的湖相碳酸盐岩烃源岩.通过对酒西盆地下白垩统二百多块湖相碳酸盐岩烃源岩详细的有机岩石学研究,解剖了湖相碳酸盐岩烃源岩中有机质的赋存形式,揭示了藻纹层为有机质纹层的主要发育形式,其与富泥晶白云石纹层和富粘土纹层构成湖相碳酸盐岩烃源岩特有的“三元式纹层”沉积结构,系统总结了各显微组分的光性、成因、生烃性及分布规律,提出了以全岩和干酪根为基础的湖相碳酸盐岩有机显微组分分类方案,首次鉴定出对酒西盆地油气有贡献的主要生烃组分为腐泥无定形体、腐殖无定形体以及浮游藻类体、孢粉体、壳屑体五种有机显微组分.%The typical lacustrine carbonate source rocks include dark dolomitic mudstone and argillaceous dolomite of Chijinpu ami Xiagou formations of Lower Cretaceous, which represent major petroleum source rocks in Jiuxi basin, NW China. Over 200 samples were selected from Lower Cretaceous lacustrine carbonate source rocks in Jiuxi basin for a detailed organic petrology analysis. Organic laminae has been recognized which is mainly algal laminae and "three-layer" structure is unique for lacustrine carbonate source rocks, which consists of algal laminae, micrite dolomite laminae and clay laminae. A petrographic classification of macerals in lacustrine carbonate source rocks has been suggested on the basis of whole rock and kerogen analysis. The discussion has also been carried out on the origins, the optical properities, hydrocarbon generation potential and geological distribution of macerals in these lacustrine carbonate source rocks. Five major hydrocarbon-generating macerals contributed to petroleum resources are firstly identified which are sapropelic amorphogen, humic amorphogen, alginite, sporopollenite and

  12. Micrometer scale carbon isotopic study of bitumen associated with Athabasca uranium deposits: Constraints on the genetic relationship with petroleum source-rocks and the abiogenic origin hypothesis

    Science.gov (United States)

    Sangély, L.; Chaussidon, M.; Michels, R.; Brouand, M.; Cuney, M.; Huault, V.; Landais, P.

    2007-06-01

    In situ analytical techniques - Fourier transform infrared microspectroscopy (μFTIR) and ion microprobe - have been used to unravel the origin of solid bitumen associated with the uranium deposits of Athabasca (Saskatchewan, Canada). Both aliphaticity and carbon isotopic compositions within the samples are heterogeneous but spatially organized in concentric zonations at the micrometer scale. Finally, the δ13C values are positively correlated to the aliphatic contents over an extremely large isotopic range from ˜ - 49‰ to ˜ - 31‰. We infer that this positive correlation may be related to the carbon isotopic fractionations associated with the synthesis of bitumen through the catalytic hydrogenation of CO 2, rather than the result of pre-existing petroleum product precipitation and/or alteration (such as radiolysis). This explanation is consistent with (i) published results of abiogenic synthesis experiments, in which the differences in δ13C values between saturated and unsaturated hydrocarbons range from + 2 and + 19‰, in contrast to the differences systematically observed in conventional bitumen and petroleum ranging from 0‰ to - 4‰; (ii) the absence of a similar positive correlation between aliphatic contents and δ13C values in the other bitumen analyzed in the present study, for which a biogenic origin has been unequivocally established (samples from Oklo, Gabon, and Lodève, France, uranium deposits); (iii) the presence of CO 2 and H 2 in the gas-phase of fluid inclusions in the Athabasca uranium deposits, H 2 resulting from water radiolysis. The present results suggest that the δ13C vs. aliphaticity correlation could be used as a criterion to discriminate between abiogenic vs. biogenic origin of macromolecular organic matter.

  13. Spectrophotometric determination of fluorine in silicate rocks

    Science.gov (United States)

    Peck, L.C.; Smith, V.C.

    1964-01-01

    The rock powder is sintered with a sodium carbonate flux containing zinc oxide and magnesium carbonate, the sinter-cake leached with water and the resulting solution filtered. Fluorine is separated from the acidified filtrate by steam distillation and determined spectrophotometrically by means of a zirconium-SPADNS reagent. If a multiple-unit distillation apparatus is used, 12 determinations can be completed per man-day. ?? 1964.

  14. Rock History and Culture

    OpenAIRE

    Gonzalez, Éric

    2013-01-01

    Two ambitious works written by French-speaking scholars tackle rock music as a research object, from different but complementary perspectives. Both are a definite must-read for anyone interested in the contextualisation of rock music in western popular culture. In Une histoire musicale du rock (i.e. A Musical History of Rock), rock music is approached from the point of view of the people – musicians and industry – behind the music. Christophe Pirenne endeavours to examine that field from a m...

  15. Research on Water-resisting Characteristics of Carbonate Rock on Top of Ordovician System in Longgu Coal Mine%龙固煤矿奥陶系顶部碳酸盐岩隔水特性分析研究

    Institute of Scientific and Technical Information of China (English)

    戎虎仁; 白海波

    2015-01-01

    To counter to the threat of the Ordovician karst aquifer during the mining of 21st coal seam in Longgu Mine, systematic analysis and research were made in this paper on the lithological property, the development degree of fissures, the filling degree, the structural characteristics of pores, the water inflow from boreholes and so on of the carbonate rock on the top of the Ordovician system. Research results showed that:①There is a relative water-resisting layer with the thickness about 60 m on the top of the Ordovician system, which was composed of Badou limestone stratum with developed fissures and high filling rate and Gezhuang dolomite stratum with nondevelopment of partial fissures;②The fissure percentage of the relative water-resisting layer of BADOU stratum and GEZHUANG on the top of Ordovician system is 2% ~9% and 2% ~3% respectively, with less residual fissures in the relative water-resisting layer and abvious pressure eliminating and water blocking effect;③ The diameter of most pores of the carbonate rock on the top of Ordovician system is less than 30μm, with poor connectivity among them, small effective pore-throat ratio and bad seepage capacity under natural condition;④Drain holes are all located in faults or fractured zones, the water flowing channels such as faults and broken rock are the main zones where the relative water-resisting layer is fractured, and they are also the places need to be detected and controlled during the mining of 21 st coal seam;and⑤There is a relative water-resisting layer in 60 m thick on the top of Ordovician system in Longgu Mine, which can provide a certain protection for the safe mining of 21st coal seam.%针对龙固煤矿21煤开采受奥陶系岩溶含水层威胁的问题,系统分析研究了奥陶系顶部碳酸盐岩的岩性、裂隙发育程度、充填程度、孔隙结构、钻孔涌水量等特性。研究结果表明:①矿区奥陶系顶部存在约60 m厚的相对隔水层,由裂隙发育且

  16. 龙门石窟碳酸盐岩体文物风化作用模拟试验研究%Simulation experiment for weathering of culture relic on carbonate rock palisades in Longmen grottoes

    Institute of Scientific and Technical Information of China (English)

    张傲; 方云; 徐敏; 陈建平; 范子龙

    2012-01-01

    为了研究凝结水对龙门石窟碳酸盐岩表面的风化作用机理,在现场进行凝结水观测、CO2浓度监测的基础上,利用自行研制、能模拟现场温湿度环境、能提供CO2外部来源,并能对反应过程进行监控的室内模拟试验装置系统对石窟碳酸盐岩风化作用进行模拟实验.实验结果表明,凝结水会造成碳酸盐岩表面的溶解,在CO2加入的条件下风化效果加剧,岩石的质量损失和孔隙率同时增大.经过78次的模拟试验后,灰岩岩样质量损失率为0.077%~0.088%,孔隙率由实验前的0.39 %~0.40%增长到0.71%~0.74%;白云岩岩样的质量损失率为0.032%~0.038%,孔隙率由实验前的0.61%~0.68%增长为0.77%~0.85 %;灰岩和白云岩的平均溶蚀深度分别为89.475 μm和36.865 μm,溶蚀速度分别为0.0956 μm/h和0.0575μm/h,风化溶蚀作用对龙门石窟文物的影响破坏较大.%In order to research the weathering mechanism on the surface of carbonate rock by condensation water in Longmen grottoes, in light of monitoring for condensation water and CO2 concentration on the spot, the weathering process is stimulated with a self-made indoor experimental tester that enabling stimulating temperature and humidity conditions, providing external source of CO2, and monitoring the reaction process. It shows that condensation water can dissolve the surface of carbonate rock, and that the mass loss and porosity of the rocks will increase when CO2 is added. Based on 78 tests, it proves that the mass loss of limestone sample is 0. 077 %~0. 088 % and the porosity increased from 0. 39 %~0. 40 % to 0. 71 %~0. 74 %; mass loss of dolomite sample is 0. 032 %~0. 038 % and the porosity increased from 0. 61 %~0. 68 % to 0. 77 %~0. 85 %; the average corrosion depth and velocity of limestone is 89. 475 μm and 0. 0956 μm/h, those of dolomite is 36. 865 μm and 0. 0575 μm/h. It is concluded that the corrosive weathering is of great

  17. Life Found Lurking under Arctic Rocks

    Institute of Scientific and Technical Information of China (English)

    Sarah Graham; 刘晓

    2004-01-01

    @@ The Arctic tundra② would not appear a welcoming environment for life. But a paper published today in the journal Nature suggests that polar deserts may house photosynthetic③ organisms in a very unlikely place--under rocks. The discovery of the photosynthetic cyanobacteria④ could potentially double estimates of the carbon sequestration⑤ potential in these extreme environments.

  18. Radiocarbon dating of ancient rock paintings

    Energy Technology Data Exchange (ETDEWEB)

    Ilger, W.A.; Hyman, M.; Rowe, M.W. [Texas A and M Univ., College Station, TX (United States). Dept. of Chemistry; Southon, J. [Lawrence Livermore National Lab., CA (United States)

    1995-06-20

    This report presents progress made on a technique for {sup 14}C dating pictographs. A low-temperature oxygen plasma is used coupled with high-vacuum technologies to selectively remove C-containing material in the paints without contamination from inorganic carbon from rock substrates or accretions.

  19. Principles of rock mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Turchaninov, I.A.; Iofis, M.A.; Kasparyan, E.V.

    1979-01-01

    This book presents the principles of rock mechanics in a systematic way, reflecting both the historic development and the contemporary status of theoretical and experimental techniques used for the determination of the properties and stress state of rock masses, calculation of elements of systems for exploitation of useful mineral deposits and the design of mine openings. The subject of rock mechanics is discussed and methods and basic approaches are analyzed. The most widely used methods for determining the properties of rock in specimens and in situ are described. Problems of determining the stress strain state of the rock around mine openings by both experimental and analytic methods are discussed. The primary results of the study of the stress state of rock around main, development and production openings are presented. Problems of the movement of rock due to extraction of minerals are analyzed in detail, as are the conditions and causes of the development of rock bursts and sudden release of rock and gas in both surface and underground mines. Procedures for preventing or localizing rock bursts or sudden outbursts are described. (313 refs.)

  20. Carbonate aquifers

    Science.gov (United States)

    Cunningham, Kevin J.; Sukop, Michael; Curran, H. Allen

    2012-01-01

    Only limited hydrogeological research has been conducted using ichnology in carbonate aquifer characterization. Regardless, important applications of ichnology to carbonate aquifer characterization include its use to distinguish and delineate depositional cycles, correlate mappable biogenically altered surfaces, identify zones of preferential groundwater flow and paleogroundwater flow, and better understand the origin of ichnofabric-related karst features. Three case studies, which include Pleistocene carbonate rocks of the Biscayne aquifer in southern Florida and Cretaceous carbonate strata of the Edwards–Trinity aquifer system in central Texas, demonstrate that (1) there can be a strong relation between ichnofabrics and groundwater flow in carbonate aquifers and (2) ichnology can offer a useful methodology for carbonate aquifer characterization. In these examples, zones of extremely permeable, ichnofabric-related macroporosity are mappable stratiform geobodies and as such can be represented in groundwater flow and transport simulations.

  1. 塔里木盆地下古生界海相碳酸盐岩油气的特殊性%Particularities of Hydrocarbon in Lower Paleozoic Marine Carbonate Rocks in Tarim Basin

    Institute of Scientific and Technical Information of China (English)

    邬光辉; 刘虎; 石晓龙

    2014-01-01

    勘探开发资料的综合分析表明,塔里木盆地寒武系-奥陶系以石灰岩储层为主的碳酸盐岩油气藏复杂多样,不同于世界典型的中新生界海相碳酸盐岩。塔里木盆地下古生界碳酸盐岩在地质条件方面存在四大特性:(1)小克拉通多旋回构造运动,构造改造强烈;(2)烃源岩古老,海西晚期石油资源与喜马拉雅晚期天然气资源造成盆地富油也富气;(3)石灰岩为主的次生改造型储层非均质性极强;(4)埋深大,储盖组合较差。塔里木盆地海相碳酸盐岩油气藏具有四大特性:(1)以非构造油气藏为主;(2)经历多期油气充注与调整改造,流体性质复杂多变;(3)大面积、中低储量丰度的小型油气藏叠置连片;(4)油气水产出复杂,油气产量主要来自少量高效井。%Based on the comprehensive analysis of a great number of exploration and development data, it is shown that the Cambrian-Ordovician limestone-predominated carbonate hydrocarbon reservoirs in Tarim Basin are quite multifarious and complicated and they are different from the typical Meso-Cenozoic carbonate reservoirs in the world. The Lower Paleozoic carbonate hydrocarbon reservoirs present four particular features in geological conditions in this basin: 1) Multi-period tectonic movements in the small craton have brought about intensive structural reformations on hydrocarbon accumulation. 2) Contributing to the late Hercynian hydrocarbon charge and the late Himalayan gas enrichment, the basin is rich in both oil and gas resources on the basis of ancient Cambrian-Ordovician source rocks. 3) Most of limestone-predominated reservoirs with reformed secondary pores are of low matrix porosity and permeability and excessive heterogeneity. 4) Carbonate reservoirs are deep buried more than 5000m with poor reservoir-cap assemblages in the basin. The Lower Paleozoic reformed marine carbonate reservoirs in the

  2. Catalytic decarboxylations of fatty acids in immature oil source rocks

    Institute of Scientific and Technical Information of China (English)

    李哲; 张再龙; 孙燕华; 劳永新; 蔺五正; 吴卫芳

    2003-01-01

    Catalytic decarboxylations of fatty acids in immature oil source rock samples were examined in this study. The rock samples were obtained from seven oil fields in China. In order to clarify the effect of each mineral matter in the rock samples, both the Fe M?ssbauer effect and the X-ray diffraction (XRD) were used to determine the relative content of each mineral in the rock samples, and the catalytic activities of several minerals like clays, carbonates and pyrite were determined. The Fe M?ssbauer effect and the XRD studies show that clays are the main mineral components in the rock samples except for the samples from Biyang and Jianghan in which the main mineral component is ankerite. The other mineral components include calcite, plagioclase, quartz, feldspar, siderite, aragonite, pyrite, analcime, pyroxene and anhydrite. The studies of the catalytic decarboxylations of fatty acids suggest that carbonates and pyrite can make much greater contributions to the catalytic activities of the rock samples than clays. It is found that the overall catalytic activities of the rock samples are well related to the relative contents and the catalytic activities of clays, carbonates and pyrite in the rock samples.

  3. Soft rocks in Argentina

    Institute of Scientific and Technical Information of China (English)

    Giambastiani; Mauricio

    2014-01-01

    Soft rocks are a still fairly unexplored chapter in rock mechanics. Within this category are the clastic sedimentary rocks and pyroclastic volcanic rocks, of low to moderate lithification (consolidation, cemen-tation, new formed minerals), chemical sedimentary rocks and metamorphic rocks formed by minerals with Mohs hardness less than 3.5, such as limestone, gypsum, halite, sylvite, between the first and phyllites, graphitic schist, chloritic shale, talc, etc., among the latter. They also include any type of rock that suffered alteration processes (hydrothermal or weathering). In Argentina the study of low-strength rocks has not received much attention despite having extensive outcrops in the Andes and great impact in the design criteria. Correlation between geomechanical properties (UCS, deformability) to physical index (porosity, density, etc.) has shown promising results to be better studied. There are many studies and engineering projects in Argentina in soft rock geological environments, some cited in the text (Chihuído dam, N. Kirchner dam, J. Cepernic Dam, etc.) and others such as International Tunnel in the Province of Mendoza (Corredor Bioceánico), which will require the valuable contribution from rock mechanics. The lack of consistency between some of the physical and mechanical parameters explored from studies in the country may be due to an insufficient amount of information and/or non-standardization of criteria for testing materials. It is understood that more and better academic and professional efforts in improv-ing techniques will result in benefits to the better understanding of the geomechanics of weak rocks.

  4. Depositional Characteristics and Their Geological Implications of the Permo-Carboniferous Carbonate Rocks from Yingen-Ejinaqi and Their Surrounding Areas, Inner Mongolia, China%银根-额济纳旗及邻区石炭-二叠纪碳酸盐岩的沉积特征及其地质意义

    Institute of Scientific and Technical Information of China (English)

    赵省民; 陈登超; 邓坚; 李锦平

    2011-01-01

    火山岩或火山碎屑岩、辫状三角洲或扇三角洲砂砾岩,以及碳酸盐岩建造中的火山岩、火山碎屑岩和砂砾岩夹层,成为本区域石炭一二叠纪的潜在油气储层.%A study of depositional characteristics on carbonate rocks of Permo-Carboniferous was carried out by analyzing of petrology and their formation characteristics of carbonate rocks. A lot of fieldworks of the Permo-Carboniferous system in the study area indicate that, the carbonate rocks of Permo-Carboniferouus are dominated by calcirudite, crinoidal limestone and micrite with massive structure and graded bedding, volcanic or pyroclastic rocks acting as pedestals and interteds of the carbonate formations prevail in the area, which show the neritic paleoenvironmental settings of frequent tension-faulting, strong volcanisn, steep topography and deeper water during the period of Permo-Carboniferous. The Permo-Carboniferous carbonate rock formations respeetively on the pedestals of volcanic or pyroclastic rocks, granulites from braided river or fan deltas, mudstones originated from littoral zone and shelf comprise volcano-elevated carbonate rock formation (VEF). delta-elevated carbonate rock formation (DEF), coast-subsiding carbonate rock formation (CSF) and shelf-sboaling carbonate rock formation (SSF). The formations, all of which were formed by working together of region tectonics andchange in sea level, show the distinct mechanism of construction. Among of them, the voleano-elevated formation, with volcanic or py-roclastic interbeds and prevailling in the area, originated from the relative sea level fall driven by volcano eruption r~ulting from tectonicextension, in the setting of long-term ri~ in sea level The delta-elevated formation inferior to the volcano-elevated in development,with granulite interbeds, arose from the relative swa level fall driven by braided river or fan deltas progradation r~ulting from tectonicuplifting, in the context of long-term ri~ in sea

  5. Suitability of static tests for acid rock drainage assessment of mine waste rock

    Directory of Open Access Journals (Sweden)

    Päivi M. Kauppila

    2010-12-01

    Full Text Available In the present study, eight rock samples were analysed with a modified acid-base accounting (ABA test and the corresponding net acid generation (NAG test. In addition, the main and trace elements solubilised during the tests were determined with ICPOES/MS. Both the modified ABA and NAG tests classified the rock samples with a lowsulphide-S content (0.1–0.4 % and low carbonate mineral content (≤0.2 % into the category of ‘potentially acid generating’. The low neutralization potentials of these rocks were partly due to additional acid produced in silicate weathering, upon the hydrolyzation of Fe and Al during the tests. In contrast to the modified ABA, the contribution of slowly reactive carbonate minerals to the neutralisation potential was seen in the NAG test and in the carbonate NP calculation, as they classified the rock samples containing these minerals into the category of ‘non-acid generating’. This supports the use of the carbonate neutralizing potential (NP and/or the NAG test in mine waste screening. In the NAG test, acid generation and neutralization reactions either raising or decreasing the pH significantly influenced the solubility of trace metals and Al. This suggests that the extract contents could be useful in assessing contaminant mobility during long-term acid generating reactions.

  6. Relating rock avalanche morphology to emplacement processes

    Science.gov (United States)

    Dufresne, Anja; Prager, Christoph; Bösmeier, Annette

    2015-04-01

    The morphology, structure and sedimentological characteristics of rock avalanche deposits reflect both internal emplacement processes and external influences, such as runout path characteristics. The latter is mainly predisposed by topography, substrate types, and hydrogeological conditions. Additionally, the geological setting at the source slope controls, e.g. the spatial distribution of accumulated lithologies and hence material property-related changes in morphology, or the maximum clast size and amount of fines of different lithological units. The Holocene Tschirgant rock avalanche (Tyrol, Austria) resulted from failure of an intensely deformed carbonate rock mass on the southeast face of a 2,370-m-high mountain ridge. The initially sliding rock mass rapidly fragmented as it moved towards the floor of the Inn River valley. Part of the 200-250 x 106 m3 (Patzelt 2012) rock avalanche debris collided with and moved around an opposing bedrock ridge and flowed into the Ötz valley, reaching up to 6.3 km from source. Where the Tschirgant rock avalanche spread freely it formed longitudinal ridges aligned along motion direction as well as smaller hummocks. Encountering high topography, it left runup ridges, fallback patterns (i.e. secondary collapse), and compressional morphology (successively elevated, transverse ridges). Further evidence for the mechanical landslide behaviour is given by large volumes of mobilized valley-fill sediments (polymict gravels and sands). These sediments indicate both shearing and compressional faulting within the rock avalanche mass (forming their own morphological units through, e.g. in situ bulldozing or as distinctly different hummocky terrain), but also indicate extension of the spreading landslide mass (i.e. intercalated/injected gravels encountered mainly in morphological depressions between hummocks). Further influences on its morphology are given by the different lithological units. E.g. the transition from massive dolomite

  7. CRITERIA FOR ROCK ENGINEERING FAILURE

    Institute of Scientific and Technical Information of China (English)

    ZHUDeren; ZHANGYuzhuo

    1995-01-01

    A great number of underground rock projects are maintained in the rock mass which is subject to rock damage and failure development. In many cases, the rock. engineering is still under normal working conditions even though rock is already fails to some extent. This paper introduces two different concepts: rock failure and rock engineering failure. Rock failure is defined as a mechanical state under which an applicable characteristic is changed or lost.However, the rock engineering failure is an engineering state under which an applicable function is changed or lost. The failure of surrounding rocks is the major reason of rock engineering failure. The criterion of rock engineering failure depends on the limit of applicable functions. The rock engineering failure state possesses a corresponding point in rock failure state. In this paper, a description of rock engineering failure criterion is given by simply using a mechanical equation or expression. It is expected that the study of rock engineering failure criterion will be an optimal approach that combines research of rock mechanics with rock engineering problems.

  8. Pop & rock / Berk Vaher

    Index Scriptorium Estoniae

    Vaher, Berk, 1975-

    2001-01-01

    Uute heliplaatide Redman "Malpractice", Brian Eno & Peter Schwalm "Popstars", Clawfinger "A Whole Lot of Nothing", Dario G "In Full Color", MLTR e. Michael Learns To Rock "Blue Night" lühitutvustused

  9. Art on Rock

    Institute of Scientific and Technical Information of China (English)

    HU YUE

    2010-01-01

    @@ With sprawling deserts and serene lakes, the natural wonders of Ningxia Hui Autonomous Region have never failed to take the breath away from visitors. The area has another major attraction, though: the Helan Mountain rock engravings.

  10. Art on Rock

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    With sprawling deserts and serene lakes, the natural wonders of Ningxia Hui Autonomous Region have never failed totake the breath away from visitors. The areahas another major attraction, though: the Helan Mountain rock engravings.

  11. Rock kinoekraanil / Katrin Rajasaare

    Index Scriptorium Estoniae

    Rajasaare, Katrin

    2008-01-01

    7.-11. juulini kinos Sõprus toimuval filminädalal "Rock On Screen" ekraanile jõudvatest rockmuusikuid portreteerivatest filmidest "Lou Reed's Berlin", "The Future Is Unwritten: Joe Strummer", "Control: Joy Division", "Hurriganes", "Shlaager"

  12. Days of Rock

    Institute of Scientific and Technical Information of China (English)

    YUAN

    2004-01-01

    FROM last October 1 st to 3rd, at the foot of Fragrant Hill, a suburban Beijing resort famous for its flaming maple leaves in autumn, more than 20,000 rock fans indulged themselves in music for three days.

  13. Writing Rock Music Reviews.

    Science.gov (United States)

    Brown, Donal

    1980-01-01

    Suggests ways student reviewers of rock music groups can write better reviews. Among the suggestions made are that reviewers occasionally discuss the audience or what makes a particular group unique, support general comment with detail, and avoid ecstatic adjectives. (TJ)

  14. Rock avalanches on glaciers

    OpenAIRE

    Shugar, Daniel

    2011-01-01

    This thesis examines relations between rock avalanches and the glaciers on which they are deposited. I have attempted to understand a geophysical phenomenon from two viewpoints: sedimentology and glaciology. The contributions are both methodological, and practical. I have used a GIS to quantify debris sheet geomorphology. A thorough characterization of rock avalanche debris is a necessary step in understanding the flow mechanics of large landslide. I have also developed a technique for solvin...

  15. Weathering of rock 'Ginger'

    Science.gov (United States)

    1997-01-01

    One of the more unusual rocks at the site is Ginger, located southeast of the lander. Parts of it have the reddest color of any material in view, whereas its rounded lobes are gray and relatively unweathered. These color differences are brought out in the inset, enhanced at the upper right. In the false color image at the lower right, the shape of the visible-wavelength spectrum (related to the abundance of weathered ferric iron minerals) is indicated by the hue of the rocks. Blue indicates relatively unweathered rocks. Typical soils and drift, which are heavily weathered, are shown in green and flesh tones. The very red color in the creases in the rock surface correspond to a crust of ferric minerals. The origin of the rock is uncertain; the ferric crust may have grown underneath the rock, or it may cement pebbles together into a conglomerate. Ginger will be a target of future super-resolution studies to better constrain its origin.Mars Pathfinder is the second in NASA's Discovery program of low-cost spacecraft with highly focused science goals. The Jet Propulsion Laboratory, Pasadena, CA, developed and manages the Mars Pathfinder mission for NASA's Office of Space Science, Washington, D.C. The Imager for Mars Pathfinder (IMP) was developed by the University of Arizona Lunar and Planetary Laboratory under contract to JPL. Peter Smith is the Principal Investigator. JPL is an operating division of the California Institute of Technology (Caltech).

  16. Elastic Properties of Sedimentary Rocks

    Science.gov (United States)

    Melendez Martinez, Jaime

    Sedimentary rocks are an important research topic since such rocks are associated to sources of ground water as well as oil, gas, and mineral reservoirs. In this work, elastic and physical properties of a variety of sedimentary samples that include glacial sediments, carbonates, shales, one evaporite, and one argillite from a variety of locations are investigated. Assuming vertical transverse isotropy, ultrasonic compressional- and shear-waves (at 1 MHz central frequency) were measured as a function of confining pressure on all samples with the exception of glacial samples which were tested assuming isotropy. Tensile strength tests (Brazilian test) were also carried out on selected glacial samples and, in addition, static-train measurements were conducted on shales and argillite samples. Lithological and textural features of samples were obtained through thin section techniques, scanning electron microscopy images and micro-tomography images. X-ray diffraction and X-Ray fluorescence provided the mineralogical oxides content information. Porosity, density, and pore structure were studied by using a mercury intrusion porosimeter and a helium pycnometer. The wide range of porosities of the studied samples (ranging from a minimum of 1% for shales to a maximum 45% for some glacial sediments) influence the measured velocities since high porosity sample shows an noticeable velocity increment as confining pressure increases as a consequence of closure of microcracks and pores, unlike low porosity samples where increment is quasi-lineal. Implementation of Gassmann's relation to ultrasonic velocities obtained from glacial samples has negligible impact on them when assuming water saturated samples, which suggests that state of saturation it is no so important in defining such velocities and instead they are mainly frame-controlled. On the other hand, velocities measured on carbonate and evaporite samples show that samples are at best weak anisotropic, thus the intrinsic

  17. Suitability of static tests for acid rock drainage assessment of mine waste rock

    OpenAIRE

    Päivi M. Kauppila; Timo Myöhänen; Marja Liisa Räisänen

    2010-01-01

    In the present study, eight rock samples were analysed with a modified acid-base accounting (ABA) test and the corresponding net acid generation (NAG) test. In addition, the main and trace elements solubilised during the tests were determined with ICPOES/MS. Both the modified ABA and NAG tests classified the rock samples with a lowsulphide-S content (0.1–0.4 %) and low carbonate mineral content (≤0.2 %) into the category of ‘potentially acid generating’. The low neutralization potentials of t...

  18. Session: Hard Rock Penetration

    Energy Technology Data Exchange (ETDEWEB)

    Tennyson, George P. Jr.; Dunn, James C.; Drumheller, Douglas S.; Glowka, David A.; Lysne, Peter

    1992-01-01

    This session at the Geothermal Energy Program Review X: Geothermal Energy and the Utility Market consisted of five presentations: ''Hard Rock Penetration - Summary'' by George P. Tennyson, Jr.; ''Overview - Hard Rock Penetration'' by James C. Dunn; ''An Overview of Acoustic Telemetry'' by Douglas S. Drumheller; ''Lost Circulation Technology Development Status'' by David A. Glowka; ''Downhole Memory-Logging Tools'' by Peter Lysne.

  19. 塔里木盆地海相碳酸盐岩沥青“A”的地球化学特征%Geochemical Characteristics of Bitumen "A" in Marine Carbonate Rock from the Tarim Basin

    Institute of Scientific and Technical Information of China (English)

    孙敏卓; 龙国徽; 孟仟祥; 郑建京; 王国仓; 房嬛; 王作栋

    2011-01-01

    The marine carbonate rocks were crushed in to powder before taking chloroform solvent extraction by the Soxhlet apparatus. The soluble organic components were separated by column chromatography to yield saturated hydrocarbon, aromatic hydrocarbon and non-hydrocarbon after the asphaltene was precipitated by hexane. The saturated hydrocarbon and aromatic hydrocarbon were directly measured by Gas Chromatography-Mass Spectrometry (GC-MS). The non-hydrocarbon was esterified by BC13-CH3OH mixed solution before taking measurement by GC-MS. The analysis result showed that the organic matters have undergone a high degree of evolution and the kerogen type is dominated by the aquatic organisms. The platform facies hydrocarbon-generating paleoenvironment was sulphur microorganism enriched saline deep water reducing environment. The organic matters of samples have experienced the strong process of cyclization-aromatization and demethylation, which were helpful to the generation of natural gas mainly with methane. The detectable long mid-chain ketones (C31-16-one, C33-16-one and C35-18-one) in the aromatic hydrocarbon might be the particular biomarkers about the presence of the organic acid salts.%塔里木盆地采集的海相碳酸盐岩样品经粉碎后在索氏抽提器中用氯仿溶液抽提,正己烷沉淀沥青质后,可溶有机质进行柱色层族组成分离,获得饱和烃、芳烃、非烃,饱和烃和芳烃直接进行气相色谱-质谱分析,非烃经三氟化硼-甲醇混合液酯化后进行气相色谱-质谱分析.结果显示,样品有机质的演化程度高,母质类型以水生生物为主,台地相成烃古环境为富含单质硫的微生物发育的成化深水还原环境.样品有机质经历过强烈的环化-芳构化过程和去甲基化过程有利于以甲烷为主的天然气的生成.样品的芳烃馏分中检测到C31 - 16 - one、C33 -16 -one和C35-18 -one长链中位酮化合物,推断这些长链中位酮可能是有机酸盐存在的特征生物标识化合物.

  20. 塔里木盆地塔中地区奥陶系碳酸盐岩封盖性能%Sealing capacity of the Ordovician carbonate rocks in Tazhong area,the Tarim Basin

    Institute of Scientific and Technical Information of China (English)

    钱一雄; 何治亮; 陈强路; 李慧莉; 路清华; 蔡习尧; 尤东华

    2012-01-01

    利用5口区探井碳酸盐岩的矿物组成、微孔特征和测井资料等对塔里木盆地塔中地区奥陶系碳酸盐岩封盖性能进行了研究.结果表明,塔中奥陶系良里塔格组和鹰山组位于中成岩A-B亚段和晚成岩A亚段.良里塔格组中颗粒灰岩的突破压力为1.81 ~ 29.76 MPa,突破半径为13.89~77.35 nm,变化较大;泥灰岩的突破压力为14.33 MPa,突破半径为9.77 nm;含泥质条带泥晶灰岩的突破压力为3.15 ~5.41 MPa,突破半径为25.90~44.51 nm.鹰山组灰云岩的突破压力为0.98 ~ 10.35 MPa,突破半径为13.52~142.60 nm.因此,良里塔格组泥灰岩、部分颗粒灰岩及鹰山组云灰岩均有一定的封盖能力,其连续厚度大于5 m,突破压力大于5 MPa,突破半径介于10 ~ 20 nm,孔喉半径小于0.1 μm.塔中鹰山组内分布稳定、厚4~10m的高电阻含云灰岩构成的致密层段可作为局部封盖层,是中1井奥陶系鹰山组上油、下气油气分布的主要原因之一.%Mineral composition, micro-pore characteristics and well-logs from five wells were used to study the sealing capacity of the Ordovician carbonate rocks in Tazhong area,Tarim Basin. The Ordovician Lianglitage and Yingshan formations are at substage A-B of the middle diagenetic stage and substage A of the late diagenetic stage. For the Lianglitage Formation grainstone,the breakthrough pressure (BP) is 1. 81 -29. 76 Mpa,and the threshold radius (TR) is 13. 89 -77. 35 nm,. For the marlstones,the BP is 14. 33MPa and TR is 25. 9 -44. 51 nm. For the micritic limestone with band of argillite, the BP is 0. 98 - 10. 35 Mpa and the TR is 13. 52 - 142. 60 nm. The BP and the TR of the Yingshan Formation limy dolomites are 0. 98 - 10. 35 Mpa and 13. 52 - 142. 60 nm. Thus, the marlstone and partial grainstone of the Lianglitage Formation and the Yingshan Formation dolomite limestone have certain sealing capacity,with thickness over 5 m,BP over 5 Mpa,TR between 10-20 nm,pore throat radium

  1. Slippery Rock University

    Science.gov (United States)

    Arnhold, Robert W.

    2008-01-01

    Slippery Rock University (SRU), located in western Pennsylvania, is one of 14 state-owned institutions of higher education in Pennsylvania. The university has a rich tradition of providing professional preparation programs in special education, therapeutic recreation, physical education, and physical therapy for individuals with disabilities.…

  2. Rock-hard coatings

    NARCIS (Netherlands)

    Muller, M.

    2007-01-01

    Aircraft jet engines have to be able to withstand infernal conditions. Extreme heat and bitter cold tax coatings to the limit. Materials expert Dr Ir. Wim Sloof fits atoms together to develop rock-hard coatings. The latest invention in this field is known as ceramic matrix composites. Sloof has sign

  3. Umhlanga Rocks coastal defense

    NARCIS (Netherlands)

    De Jong, L.; De Jong, B.; Ivanova, M.; Gerritse, A.; Rietberg, D.; Dorrepaal, S.

    2014-01-01

    The eThekwini coastline is a vulnerable coastline subject to chronic erosion and damage due to sea level rise. In 2007 a severe storm caused major physical and economic damage along the coastline, proving the need for action. Umhlanga Rocks is a densely populated premium holiday destination on the e

  4. Microcraters on lunar rocks.

    Science.gov (United States)

    Morrison, D. A.; Mckay, D. S.; Heiken, G. H.; Moore, H. J.

    1972-01-01

    Microcrater frequency distributions have been obtained for nine Apollo rocks and an exterior chip of an Apollo 12 rock. The frequency distributions indicate that five of the Apollo 14 rocks were tumbled more than once exposing different rock faces whereas four were not tumbled and represent a single exposure interval. The cumulative frequency of craters per square centimeter was extended below optical resolution limits using a SEM scan of an exterior chip of breccia 12073. No craters with central pit diameters less than 15 microns were seen in a total area of 0.44 sq cm. A detailed SEM scan of crystal faces and glassy crater liners revealed no microcraters equal to or larger than the resolution limit of 5 microns. An upper limit of 170 craters per sq cm with central pit diameters larger than 5 microns was set. The slope of the cumulative frequency curve for craters with central pit diameters less than about 75 microns is less than that obtained by other workers.

  5. The instantaneous rate dependence in low temperature laboratory rock friction and rock deformation experiments

    Science.gov (United States)

    Beeler, N.M.; Tullis, T.E.; Kronenberg, A.K.; Reinen, L.A.

    2007-01-01

    Earthquake occurrence probabilities that account for stress transfer and time-dependent failure depend on the product of the effective normal stress and a lab-derived dimensionless coefficient a. This coefficient describes the instantaneous dependence of fault strength on deformation rate, and determines the duration of precursory slip. Although an instantaneous rate dependence is observed for fracture, friction, crack growth, and low temperature plasticity in laboratory experiments, the physical origin of this effect during earthquake faulting is obscure. We examine this rate dependence in laboratory experiments on different rock types using a normalization scheme modified from one proposed by Tullis and Weeks [1987]. We compare the instantaneous rate dependence in rock friction with rate dependence measurements from higher temperature dislocation glide experiments. The same normalization scheme is used to compare rate dependence in friction to rock fracture and to low-temperature crack growth tests. For particular weak phyllosilicate minerals, the instantaneous friction rate dependence is consistent with dislocation glide. In intact rock failure tests, for each rock type considered, the instantaneous rate dependence is the same size as for friction, suggesting a common physical origin. During subcritical crack growth in strong quartzofeldspathic and carbonate rock where glide is not possible, the instantaneous rate dependence measured during failure or creep tests at high stress has long been thought to be due to crack growth; however, direct comparison between crack growth and friction tests shows poor agreement. The crack growth rate dependence appears to be higher than the rate dependence of friction and fracture by a factor of two to three for all rock types considered. Copyright 2007 by the American Geophysical Union.

  6. Comprehensive geochemical identification of highly evolved marine hydrocarbon source rocks: Organic matter, paleoenvironment and development of effective hydrocarbon source rocks

    Institute of Scientific and Technical Information of China (English)

    TENGER; LIU Wenhui; XU Yongchang; CHEN Jianfa; HU Kai; GAO Changlin

    2006-01-01

    This study analyzed the developing environments of hydrocarbon source rocks in the Ordos Basin and evaluated carbonate rocks as hydrocarbon source rocks and their distributions on account of the fact that China's marine carbonate rocks as hydrocarbon source rocks are characterized by the intensive thermal evolution and relatively low abundance of organic matter, by taking the Lower Paleozoic of the Ordos Basin for example and in light of the calculated enrichment coefficients of trace elements, the profile analysis of trace element contents, ratios of relevant elements, and stable isotopic compositions and their three-dimensional diagrammatization in combination with the necessary organic parameters. As for the Ordos Basin, TOC=0.2% is an important boundary value. Studies have shown that in the strata TOC>0.2%, V/(V+Ni)>0.50, Zr/Rb<2, Rb/K(×104)>30, Z>122, Th/U>0.80, Zn and Mo are enriched with a positive δ13Ccarb excursion. All these indicated a stagnant and stratified sedimentary environment that has low energy, anoxia and high salinity in bottom water. In these strata the geological conditions are good for the preservation of organic matter, hence favoring the development of hydrocarbon source rocks. These strata have δ13Corg<-28‰ (Ⅰ-Ⅱtype) and high hydrocarbon-generated potential. The Klimory and Wulalik formations show certain regularities in those aspects, therefore, they can be regarded as the potential effective hydrocarbon source rocks. In the strata TOC≤0.2%, Zr/Rb>1, V/(V+Ni)<0.50, Rb/K<30, Th/U<0.80, Cu, Zn, etc are depleted, and δ13Corg values range from -24‰ to -28‰. All these facts showed that most of the carbonate rocks or mudstones were formed in high-energy oxidizing environments, thus unfavorable to the development of hydrocarbon source rocks. It is feasible to make use of the geochemical method to comprehensively assess the highly evolved marine carbonates rocks as potential hydrocarbon source rocks and

  7. Authigenic Carbonate and the History of the Global Carbon Cycle

    Science.gov (United States)

    Schrag, Daniel P.; Higgins, John. A.; Macdonald, Francis A.; Johnston, David T.

    2013-02-01

    We present a framework for interpreting the carbon isotopic composition of sedimentary rocks, which in turn requires a fundamental reinterpretation of the carbon cycle and redox budgets over Earth's history. We propose that authigenic carbonate, produced in sediment pore fluids during early diagenesis, has played a major role in the carbon cycle in the past. This sink constitutes a minor component of the carbon isotope mass balance under the modern, high levels of atmospheric oxygen but was much larger in times of low atmospheric O2 or widespread marine anoxia. Waxing and waning of a global authigenic carbonate sink helps to explain extreme carbon isotope variations in the Proterozoic, Paleozoic, and Triassic.

  8. Pitted Rock Named Ender

    Science.gov (United States)

    1997-01-01

    This image was taken by the Sojourner rover's right front camera on Sol 33. The rock in the foreground, nicknamed 'Ender', is pitted and marked by a subtle horizontal texture. The bright material on the top of the rock is probably wind-deposited dust. The Pathfinder Lander is seen in the distance at right. The lander camera is the cylindrical object on top of the deployed mast.Mars Pathfinder is the second in NASA's Discovery program of low-cost spacecraft with highly focused science goals. The Jet Propulsion Laboratory, Pasadena, CA, developed and managed the Mars Pathfinder mission for NASA's Office of Space Science, Washington, D.C. JPL is a division of the California Institute of Technology (Caltech).

  9. Rock and mineral magnetism

    CERN Document Server

    O’Reilly, W

    1984-01-01

    The past two decades have witnessed a revolution in the earth sciences. The quantitative, instrument-based measurements and physical models of. geophysics, together with advances in technology, have radically transformed the way in which the Earth, and especially its crust, is described. The study of the magnetism of the rocks of the Earth's crust has played a major part in this transformation. Rocks, or more specifically their constituent magnetic minerals, can be regarded as a measuring instrument provided by nature, which can be employed in the service of the earth sciences. Thus magnetic minerals are a recording magnetometer; a goniometer or protractor, recording the directions of flows, fields and forces; a clock; a recording thermometer; a position recorder; astrain gauge; an instrument for geo­ logical surveying; a tracer in climatology and hydrology; a tool in petrology. No instrument is linear, or free from noise and systematic errors, and the performance of nature's instrument must be assessed and ...

  10. Uranium in alkaline rocks

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, M.; Wollenberg, H.; Strisower, B.; Bowman, H.; Flexser, S.; Carmichael, I.

    1978-04-01

    Geologic and geochemical criteria were developed for the occurrence of economic uranium deposits in alkaline igneous rocks. A literature search, a limited chemical analytical program, and visits to three prominent alkaline-rock localities (Ilimaussaq, Greenland; Pocos de Caldas, Brazil; and Powderhorn, Colorado) were made to establish criteria to determine if a site had some uranium resource potential. From the literature, four alkaline-intrusive occurrences of differing character were identified as type-localities for uranium mineralization, and the important aspects of these localities were described. These characteristics were used to categorize and evaluate U.S. occurrences. The literature search disclosed 69 U.S. sites, encompassing nepheline syenite, alkaline granite, and carbonatite. It was possible to compare two-thirds of these sites to the type localities. A ranking system identified ten of the sites as most likely to have uranium resource potential.

  11. Palaeozoic source rocks in the Dniepr-Donets Basin, Ukraine

    Energy Technology Data Exchange (ETDEWEB)

    Sachsenhofer, R.F.; Shymanovskyy, V.A.; Bechtel, A.; Gratzer, R.; Horsfield, B.; Reischenbacher, D. [University of Leoben, Leoben (Austria). Dept. of Applied Geoscience & Geophysics

    2010-11-15

    The Dniepr-Donets Basin (DDB) is a major petroleum province in Eastern Europe. In order to understand the regional and stratigraphic distribution of source rocks for the dominantly gas-prone petroleum system, 676 fine-grained rocks from 30 wells were analysed for bulk parameters (total organic carbon (TOC), carbonate, sulphur, RockEval). A subset of samples was selected for maceral and biomarker analysis, pyrolysis-gas chromatography and kinetic investigations. Organic-rich sediments occur in different intervals within the basin fill. Maximum TOC contents (5.0 +/- 1.9%) occur in the Rudov Beds, several tens of metres thick. The oil-prone rocks (Type III-II kerogen) were deposited in basinal settings above an unconformity separating Lower and Upper Visean sections. While maximum TOC contents occur in the Rudov Beds, high TOC contents are observed in the entire Tournaisian and Visean section. However, these rocks are mainly gas condensate-prone. Highly oil-prone black shales with up to 16% TOC and hydrogen index values up to 550 mgHC g{sup -1} TOC occur in Serpukhovian intervals in the northwestern part of the DDB. Oil-prone Lower Serpukhovian and gas condensate-prone Middle Carboniferous coal is widespread in the southern and southeastern part of the basin. Although no source rocks with a Devonian age were detected, their presence cannot be excluded.

  12. Genesis and organic geochemical characteristics of the carbonaceous rock stratabound gold deposits, South China

    Institute of Scientific and Technical Information of China (English)

    胡凯; 翟建平; 刘英俊; 王鹤年; 张景荣; 贾蓉芬

    2000-01-01

    The organic matter of three different chronological major carbonaceous rock gold-bearing formations of South China (Middle Proterozoic Shangqiaoshan group of northeastern Jiangxi, Lower Cambrian Shuikou group of northern Guangxi and Devonian Shetianqiao group of eastern Hunan) and related carbonaceous stratabound gold deposits such as Jinshan, Longshui and Shixia deposits, respectively, has been characterized by organic geochemical techniques. These organic geochemical results show that the average total organic carbon (TOC) content of the three chronological carbonaceous rock gold-bearing formations of South China ranges from 0.15% to 1.56%. The thermal maturity of the organic matter of host rocks in the three gold-bearing formations is high. The micro-component of the organic matter of the host rocks consists primarily of solid bitumen and graphite. The organic carbon and gold of the host rocks appear to syndeposit in situ during the formation of the gold-bearing formations. The organic carbon played

  13. Rock in Rio: eternamente jovem

    OpenAIRE

    Ricardo Ferreira Freitas; Flávio Lins Rodrigues

    2014-01-01

    The purpose of this article is to discuss the role of Rock in Rio: The Musical, as herald of megafestival Rock in Rio. Driven by the success that musicals have reached in Brazil, we believe that the design of this spectacle of music, dance and staging renews the brand of the rock festival, once it adds the force of young and healthy bodies to its concept. Moreover, the musical provides Rock in Rio with some distance from the controversal trilogy of sex, drugs and rock and roll, a strong mark ...

  14. Rock in Rio: forever young

    Directory of Open Access Journals (Sweden)

    Ricardo Ferreira Freitas

    2014-12-01

    Full Text Available The purpose of this article is to discuss the role of Rock in Rio: The Musical, as herald of megafestival Rock in Rio. Driven by the success that musicals have reached in Brazil, we believe that the design of this spectacle of music, dance and staging renews the brand of the rock festival, once it adds the force of young and healthy bodies to its concept. Moreover, the musical provides Rock in Rio with some distance from the controversal trilogy of sex, drugs and rock and roll, a strong mark of past festivals around the world. Thus, the musical expands the possibilities of growth for the brand.

  15. Rock blasting and explosives engineering

    Energy Technology Data Exchange (ETDEWEB)

    Persson, P.-A.; Holmberg, R.; Lee, J. (New Mexico Institute of Mining and Technology, Socorro, NM (United States). Research Center for Energetic Materials)

    1994-01-01

    The book covers the practical engineering aspects of different kinds of rock blasting. It includes a thorough analysis of the cost of the entire process of tunneling by drilling and blasting compared with full-face boring. It covers the economics of the entire rock blasting operation and its dependence on the size of excavation. The book highlights the fundamentals of rock mechanics, shock waves and detonation, initiation and mechanics of rock motion. It describes the engineering design principles and computational techniques for many separate mining methods and rock blasting operations. 274 refs.

  16. Physical and chemical weathering. [of Martian surface and rocks

    Science.gov (United States)

    Gooding, James L.; Arvidson, Raymond E.; Zolotov, Mikhail IU.

    1992-01-01

    Physical and chemical weathering processes that might be important on Mars are reviewed, and the limited observations, including relevant Viking results and laboratory simulations, are summarized. Physical weathering may have included rock splitting through growth of ice, salt or secondary silicate crystals in voids. Chemical weathering probably involved reactions of minerals with water, oxygen, and carbon dioxide, although predicted products vary sensitively with the abundance and physical form postulated for the water. On the basis of kinetics data for hydration of rock glass on earth, the fate of weathering-rind formation on glass-bearing Martian volcanic rocks is tentatively estimated to have been on the order of 0.1 to 4.5 cm/Gyr; lower rates would be expected for crystalline rocks.

  17. A revision of the Haiming rock avalanche (Eastern Alps)

    Science.gov (United States)

    Dufresne, Anja; Ostermann, Marc; Kelfoun, Karim; Ring, Max; Asam, Dario; Prager, Christoph

    2016-04-01

    The carbonate Haiming rock avalanche is directly neighbouring the larger Tschirgant rock avalanche deposit, both located in the upper Inn valley (Tyrol, Austria). Based on detailed morpho-lithologic mapping of the deposit, which has not been done at Haiming before, the sedimentology of the Holocene landslide debris is characterised. Structural-tectonic elements of the bedrock units at the scarp area are supplemented with borehole data from drillings at the source area giving valuable insights into the complex geological bedrock composition and structure. New source and runout reconstructions allow updated volumetric calculations, which are subsequently integrated into numerical runout modelling. Haiming is one of few topographically unobstructed rock avalanches, yet its morphology was greatly influenced by fluvial terraces, which are still discernible through the deposit on LiDAR hillshade images. We also address the influence of the rock avalanche on the valley floor and local river system as a short-lived dam and its interaction with fluvial incision. Finally, we discuss the Haiming rock avalanche in view of the other massive rock slope failures in the area ("Fernpass cluster"), their spatio-temporal distribution, and point out further highlights of this simple(?) rock avalanche deposit.

  18. Process and Energy Optimization Assessment, Rock Island Arsenal, IL

    Science.gov (United States)

    2004-09-01

    applications and process equipment. Process equipment includes two absorption chillers , two steam- operated forge presses, immersion heaters for the...evaluate the boiler strategy at this facility. The facility is currently in the process of replacing the absorption chillers with electric chillers ...Carbonate Fuel Cells for DoD Applications: Rock Island Arsenal MCFC Engi- neer Research and Development Center, Construction Engineering Research

  19. 安徽霍邱安阳山晚石炭世碳酸盐岩地层中奥陶纪牙形石和虫颚化石的发现%DiSCovery of orDoviC iAn ConoDont AnD SColeCoDont foSSilS in lAter CArbonACeouS CArbonAte roCk StrAtA in AnyAnG Mt, huoQiu, Anhui

    Institute of Scientific and Technical Information of China (English)

    程成; 李双应; 稽在飞; 王松; 杨栋栋; 张强

    2014-01-01

    A latest research indicated that carbonate rock member in the lower part of the Anyang Mt (Baida Mt) section, Huoqiu, Anhui belongs to late Carbonaceous epoch, clastic rock member in the upper part to Qingbaikouan period. Further micropaleonlogical analysis found abundant such fossils in the late carbonaceous carbonate rock, of which conodont and scolecodont fossils dominate in quantity. Identified conodont is Belodina, scolecodonts include Marlenites marginatus,Chairidogenys borealis,Cornugenys sp.,Porrhogrnys sp.,Channahania sp.,Paradrilonersgenys cherylae, etc. Belodina dated back to late Ordovician epoch and scolecodonts Ordovician period. Ordovician fossils occurring in later Carbonaceous epoch suggested that there may have been an Ordovician source of micro fossils, which were eroded, transported, re-deposited and preserved in late Carbonaceous carbonate rock. Obviously, this discovery may not be significant stratigraphically, but paleogeographically and paleotectonically.%最近的研究表明,安徽霍邱地区安阳山(白大山)剖面下部碳酸盐岩段属于晚石炭世,上部碎屑岩段属于青白口纪。我们进一步对剖面进行了微体古生物分析,在晚石炭世碳酸盐岩中发现了丰富的微体古生物化石,其中以牙形石和虫颚化石数量最多。经鉴定,有牙形石Belodina和虫颚化石Marlenites marginatus,Chairidogenys borealis,Cornugenys sp.,Porrhogrnys sp.,Channahania sp.,Paradrilonersgenys cherylae等,Belodina时代为晚奥陶世,虫颚化石的时代为奥陶纪。晚石炭世地层中存在奥陶纪化石,表明可能存在奥陶系的物源区,微体化石是通过剥蚀、搬运再沉积保存到晚石炭世碳酸盐岩中。显然,新发现的微体化石可能并不具有地层意义,但是具有古地理和古构造意义。

  20. Estimating elastic moduli of rocks from thin sections: Digital rock study of 3D properties from 2D images

    Science.gov (United States)

    Saxena, Nishank; Mavko, Gary

    2016-03-01

    Estimation of elastic rock moduli using 2D plane strain computations from thin sections has several numerical and analytical advantages over using 3D rock images, including faster computation, smaller memory requirements, and the availability of cheap thin sections. These advantages, however, must be weighed against the estimation accuracy of 3D rock properties from thin sections. We present a new method for predicting elastic properties of natural rocks using thin sections. Our method is based on a simple power-law transform that correlates computed 2D thin section moduli and the corresponding 3D rock moduli. The validity of this transform is established using a dataset comprised of FEM-computed elastic moduli of rock samples from various geologic formations, including Fontainebleau sandstone, Berea sandstone, Bituminous sand, and Grossmont carbonate. We note that using the power-law transform with a power-law coefficient between 0.4-0.6 contains 2D moduli to 3D moduli transformations for all rocks that are considered in this study. We also find that reliable estimates of P-wave (Vp) and S-wave velocity (Vs) trends can be obtained using 2D thin sections.

  1. Rock composition and origin of the Duwi Formation calcareous rocks, Upper Egypt

    Institute of Scientific and Technical Information of China (English)

    Baioumy H.M.; Attia A.M.; Boulis S.N.; Hassan M.S.; Helmy M.E.

    2005-01-01

    Upper Cretaceous phosphorite beds of the Duwi Formation, Upper Egypt, are intercalated with limestone, sandy limestone, marl, calcareous shales, and calcareous sandstone. Calcareous intercalations were subjected to field and detailed petrographic, mineralogical and geochemical investigations in order to constrain their rock composition and origin.Mineralogically, dolomite, calcite, quartz, francolite and feldspars are the non-clay minerals. Smectite, kaolinite and illite represent the clay minerals. Major and trace elements can be classified as the detrital and carbonate fractions based on their sources. The detrital fraction includes the elements that are derived from detrital sources, mainly clay minerals and quartz, such as Si, Al, Fe, Ti, K, Ba, V, Ni, Co, Cr, Zn, Cu, Zr, and Mo. The carbonate fraction includes the elements that are derived from carbonates, maily calcite and dolomite, such as Ca, Mg and Sr. Dolomite occurs as being dense, uniform, mosaic, very fine-to-fine, non-ferroan, and non-stoichiometrical suggesting its early diagenetic formation in a near-shore oxidizing shallow marine environment. The close association and positive correlation between dolomite and smectite indicates the role of clay minerals in the formation of dolomite as a source of Mg 2+-rich solutions.Calcareous rocks were deposited in marine, oxidizing and weakly alkaline conditions, marking a semi-arid climatic period. The calcareous/argillaceous alternations are due to oscillations in clay/carbonate ratio.

  2. Depositional environment and source rock potential of Cenomanian and Turonian sedimentary rocks of the Tarfaya Basin, Southwest Morocco

    Energy Technology Data Exchange (ETDEWEB)

    Ghassal, B.I.; Littke, R.; Sachse, V.; Sindern, S.; Schwarzbauer, J.

    2016-07-01

    Detailed organic and inorganic geochemical analyses were used to assess the depositional environment and source rock potential of the Cenomanian and Turonian oil shale deposits in the Tarfaya Basin. This study is based on core samples from the Tarfaya Sondage-4 well that penetrated over 300m of Mid Cretaceous organic matter-rich deposits. A total of 242 samples were analyzed for total organic and inorganic carbon and selected samples for total sulfur and major elements as well as for organic petrology, Rock-Eval pyrolysis, Curie-Point-pyrolysis-gaschromatography-Mass-Spectrometry and molecular geochemistry of solvent extracts. Based on major elements the lower Cenomanian differs from the other intervals by higher silicate and lower carbonate contents. Moreover, the molecular geochemistry suggests anoxic bottom marine water conditions during the Cenomanian-Turonian Boundary Event (CTBE; Oceanic Anoxic Event 2: OAE2). As a proxy for the Sorg/Corg ratio, the ratio total thiophenes/total benzenes compounds was calculated from pyrolysate compositions. The results suggest that Sorg/ Corg is low in the lower Cenomanian, moderate in the upper Cenomanian, very high in the CTBE (CenomanianTuronian Boundary Event) and high in the Turonian samples. Rock-Eval data reveal that the lower Cenomanian is a moderately organic carbon-rich source rock with good potential to generate oil and gas upon thermal maturation. On the other hand, the samples from the upper Cenomanian to Turonian exhibit higher organic carbon content and can be classified as oil-prone source rocks. Based on Tmax data, all rocks are thermally immature. The microscopic investigations suggest dominance of submicroscopic organic matter in all samples and different contents of bituminite and alginite. The lower Cenomanian samples have little visible organic matter and no bituminite. The upper Cenomanian and CTBE samples are poor in bituminite and have rare visible organic matter, whereas the Turonian samples change

  3. From stones to rocks

    Science.gov (United States)

    Mortier, Marie-Astrid; Jean-Leroux, Kathleen; Cirio, Raymond

    2013-04-01

    With the Aquila earthquake in 2009, earthquake prediction is more and more necessary nowadays, and people are waiting for even more accurate data. Earthquake accuracy has increased in recent times mainly thanks to the understanding of how oceanic expansion works and significant development of numerical seismic prediction models. Despite the improvements, the location and the magnitude can't be as accurate as citizen and authorities would like. The basis of anticipating earthquakes requires the understanding of: - The composition of the earth, - The structure of the earth, - The relations and movements between the different parts of the surface of the earth. In order to answer these questions, the Alps are an interesting field for students. This study combines natural curiosity about understanding the predictable part of natural hazard in geology and scientific skills on site: observing and drawing landscape, choosing and reading a representative core drilling, replacing the facts chronologically and considering the age, the length of time and the strength needed. This experience requires students to have an approach of time and space radically different than the one they can consider in a classroom. It also limits their imagination, in a positive way, because they realize that prediction is based on real data and some of former theories have become present paradigms thanks to geologists. On each location the analyzed data include landscape, core drilling and the relation established between them by students. The data is used by the students to understand the meaning, so that the history of the formation of the rocks tells by the rocks can be explained. Until this year, the CBGA's perspective regarding the study of the Alps ground allowed students to build the story of the creation and disappearance of the ocean, which was a concept required by French educational authorities. But not long ago, the authorities changed their scientific expectations. To meet the

  4. Michael Learns to Rock

    Institute of Scientific and Technical Information of China (English)

    汪海涛

    2004-01-01

    夜幕降临.空气中传来北欧的声音,来自丹麦的四人流行乐队Michael Learns to Rock(迈克学摇滚)正把探情款款的歌声带到上海的咖啡厅和酒吧。北欧一直活跃着一批世界顶级的乐队.从丹麦的A-Ha到Aqua,从瑞典的ABBA到Roxette和Ace of Base,从挪威的Se

  5. Rock Properties Model

    Energy Technology Data Exchange (ETDEWEB)

    C. Lum

    2004-09-16

    The purpose of this model report is to document the Rock Properties Model version 3.1 with regard to input data, model methods, assumptions, uncertainties and limitations of model results, and qualification status of the model. The report also documents the differences between the current and previous versions and validation of the model. The rock properties model provides mean matrix and lithophysae porosity, and the cross-correlated mean bulk density as direct input to the ''Saturated Zone Flow and Transport Model Abstraction'', MDL-NBS-HS-000021, REV 02 (BSC 2004 [DIRS 170042]). The constraints, caveats, and limitations associated with this model are discussed in Section 6.6 and 8.2. Model validation accomplished by corroboration with data not cited as direct input is discussed in Section 7. The revision of this model report was performed as part of activities being conducted under the ''Technical Work Plan for: The Integrated Site Model, Revision 05'' (BSC 2004 [DIRS 169635]). The purpose of this revision is to bring the report up to current procedural requirements and address the Regulatory Integration Team evaluation comments. The work plan describes the scope, objectives, tasks, methodology, and procedures for this process.

  6. Fossils, rocks, and time

    Science.gov (United States)

    Edwards, Lucy E.; Pojeta, John

    1999-01-01

    We study our Earth for many reasons: to find water to drink or oil to run our cars or coal to heat our homes, to know where to expect earthquakes or landslides or floods, and to try to understand our natural surroundings. Earth is constantly changing--nothing on its surface is truly permanent. Rocks that are now on top of a mountain may once have been at the bottom of the sea. Thus, to understand the world we live on, we must add the dimension of time. We must study Earth's history. When we talk about recorded history, time is measured in years, centuries, and tens of centuries. When we talk about Earth history, time is measured in millions and billions of years. Time is an everyday part of our lives. We keep track of time with a marvelous invention, the calendar, which is based on the movements of Earth in space. One spin of Earth on its axis is a day, and one trip around the Sun is a year. The modern calendar is a great achievement, developed over many thousands of years as theory and technology improved. People who study Earth's history also use a type of calendar, called the geologic time scale. It looks very different from the familiar calendar. In some ways, it is more like a book, and the rocks are its pages. Some of the pages are torn or missing, and the pages are not numbered, but geology gives us the tools to help us read this book.

  7. A smart rock

    Science.gov (United States)

    Pressel, Phil

    2014-12-01

    This project was to design and build a protective weapon for a group of associations that believed in aliens and UFO's. They collected enough contributions from societies and individuals to be able to sponsor and totally fund the design, fabrication and testing of this equipment. The location of this facility is classified. It also eventually was redesigned by the Quartus Engineering Company for use at a major amusement park as a "shoot at targets facility." The challenge of this project was to design a "smart rock," namely an infrared bullet (the size of a gallon can of paint) that could be shot from the ground to intercept a UFO or any incoming suspicious item heading towards the earth. Some of the challenges to design this weapon were to feed cryogenic helium at 5 degrees Kelvin from an inair environment through a unique rotary coupling and air-vacuum seal while spinning the bullet at 1500 rpm and maintain its dynamic stability (wobble) about its spin axis to less than 10 micro-radians (2 arc seconds) while it operated in a vacuum. Precision optics monitored the dynamic motion of the "smart rock."

  8. Rock critics as 'Mouldy Modernists'

    Directory of Open Access Journals (Sweden)

    Becky Shepherd

    2011-09-01

    Full Text Available Contemporary rock criticism appears to be firmly tied to the past. The specialist music press valorise rock music of the 1960s and 1970s, and new emerging artists are championed for their ‘retro’ sounding music by journalists who compare the sound of these new artists with those included in the established ‘canon’ of rock music. This article examines the narrative tropes of authenticity and nostalgia that frame the retrospective focus of this contemporary rock writing, and most significantly, the maintenance of the rock canon within contemporary popular culture. The article concludes by suggesting that while contemporary rock criticism is predominately characterised by nostalgia, this nostalgia is not simply a passive romanticism of the past. Rather, this nostalgia fuels a process of active recontextualisation within contemporary popular culture.

  9. 碳酸盐岩中不同赋存状态有机质地球化学特征对比及对成烃的贡献%The Organic Geochemical Characteristcs Comparison and Contributors of Different Existing State Organic Matter in Carbonate Rocks

    Institute of Scientific and Technical Information of China (English)

    王兆云; 程克明

    2000-01-01

    The existing state of organic matter in carbonate rocks not onlyhas dissemination state, but also has inclusion state. The acid liquid soluble organic matter I is also divided while extracting the inclusion organic matter. The analysis of the quantity, IR spectrocopy, GC and GC-MS among the bitumen A, Bitumen C and acid liquid soluble organic matter show that their characteristics are not the same. The results play an important role for evaluating the hydrocarbon producion potential and discussing the hydrocarbon generating mechanism and process of carbonate rocks%碳酸盐沉积物特殊的成岩机理和过程决定了有机质的复杂赋存状态,在碳酸盐岩中,除分散有机质外,还存在包裹体有机质。在包裹体有机质的提取过程中,当用6%(质量分数)的盐酸酸解碳酸盐矿物时,又将包裹体中的一部分有机质分离出(部分呈悬浮状态),本文定义为酸溶有机质I。对这三部分可溶有机质的含量、红外光谱、GC、GC-MS等分析表明它们的特征是不同的,并且分散有机质和包裹有机质在不同演化阶段对成烃的贡献不同。这为评价碳酸盐岩生烃潜力以及研究碳酸盐岩生烃机制和过程奠定了基础。

  10. Research on The Surrounding Rock Deformation Law of Carbon Shale Small Interval Tunnel%炭质页岩小净距隧道围岩变形规律研究

    Institute of Scientific and Technical Information of China (English)

    段宝福; 翁现合

    2012-01-01

    以湖北宴家隧道工程为例,结合现场施工监测,采用有限元程序对节理围岩隧道施工进行模拟,对节理围岩隧道的开挖对地层扰动的范围进行定量确定.对小间距双线隧道在炭质页岩条件下节理面上游隧道先行施工进行数值模拟,将实测数据与数值模拟进行对比,总结出炭质页岩小间距隧道左右洞有施工差别时围岩变形规律.%Taking the Hubei Yanjia tunnel project as an example, the construction of jointed surrounding rock tunnels was simulated using finite element software and the range of disturbance caused by the excavation was quantatively determined. Numerical simulations were also performed for the upper tunnel under carbonaceous shale in small interval tunnel and simulation results were compared against site measurement.Conclusions were drawn regarding the principles of tunnel surrounding rock deformation when the two holes are constructed differently.

  11. Managing Rock Squirrels in Utah

    OpenAIRE

    Frey, Nicki

    2015-01-01

    Although they do not exist in large colonies like other ground squirrels, rock squirrels can still sometimes generate conflicts with homeowners and farmers alike. Most damage occurs when a few rock squirrels take residence in a homeowner’s back yard, and begin to forage on garden vegetables and fruit trees. There are several direct and indirect ways that private landowners can manage and reduce rock squirrels on their property. This fact sheet give management tips.

  12. [Hearing disorders and rock music].

    Science.gov (United States)

    Lindhardt, Bjarne Orskov

    2008-12-15

    Only few studies have investigated the frequency of hearing disorders in rock musicians. Performing rock music is apparently associated with a hearing loss in a fraction of musicians. Tinnitus and hyperacusis are more common among rock musicians than among the background population. It seems as if some sort of resistance against further hearing loss is developed over time. The use of ear protection devices have not been studied systematically but appears to be associated with diminished hearing loss.

  13. Critical issues in soft rocks

    Institute of Scientific and Technical Information of China (English)

    Milton Assis Kanji

    2014-01-01

    This paper discusses several efforts made to study and investigate soft rocks, as well as their physico-mechanical characteristics recognized up to now, the problems in their sampling and testing, and the possibility of its reproduction through artificially made soft rocks. The problems in utilizing current and widespread classification systems to some types of weak rocks are also discussed, as well as other problems related to them. Some examples of engineering works in soft rock or in soft ground are added, with emphasis on their types of problems and solutions.

  14. Rock.XML - Towards a library of rock physics models

    Science.gov (United States)

    Jensen, Erling Hugo; Hauge, Ragnar; Ulvmoen, Marit; Johansen, Tor Arne; Drottning, Åsmund

    2016-08-01

    Rock physics modelling provides tools for correlating physical properties of rocks and their constituents to the geophysical observations we measure on a larger scale. Many different theoretical and empirical models exist, to cover the range of different types of rocks. However, upon reviewing these, we see that they are all built around a few main concepts. Based on this observation, we propose a format for digitally storing the specifications for rock physics models which we have named Rock.XML. It does not only contain data about the various constituents, but also the theories and how they are used to combine these building blocks to make a representative model for a particular rock. The format is based on the Extensible Markup Language XML, making it flexible enough to handle complex models as well as scalable towards extending it with new theories and models. This technology has great advantages as far as documenting and exchanging models in an unambiguous way between people and between software. Rock.XML can become a platform for creating a library of rock physics models; making them more accessible to everyone.

  15. Rock the Globe

    CERN Multimedia

    Laëtitia Pedroso

    2010-01-01

    Created in 2005, the Swiss rock band "Wind of Change" is now candidate for the Eurovision Song Contest 2011 with a new song " Night & Light " with the music video filmed at CERN.   With over 20 gigs under their belt and two albums already released, the five members of the band (Alex Büchi, vocals; Arthur Spierer, drums; David Gantner, bass; Romain Mage and Yannick Gaudy, guitar) continue to excite audiences. For their latest composition "Night & Light", the group filmed their music video in the Globe of Science and Innovation. Winning the Eurovision contest would be a springboard in their artistic career for these young musicians. The selection results will be available December 11, 2010.      

  16. New approaches in the indirect quantification of thermal rock properties in sedimentary basins: the well-log perspective

    DEFF Research Database (Denmark)

    Fuchs, Sven; Balling, Niels; Förster, Andrea

    capacity in sedimentary rocks derived from data provided by standard geophysical well logs. The approach is based on a data set of synthetic sedimentary rocks (clastic rocks, carbonates and evaporates) composed of mineral assemblages with variable contents of 15 major rock-forming minerals and porosities......: Fuchs, Sven; Balling, Niels; Förster, Andrea (2015): Calculation of thermal conductivity, thermal diffusivity and specific heat capacity of sedimentary rocks using petrophysical well logs. Geophysical Journal International 203, 1977-2000, doi: 10.1093/gji/ggv403...

  17. Rock Art in Kurdistan Iran

    Directory of Open Access Journals (Sweden)

    Jamal Lahafian

    2013-12-01

    Full Text Available Kurdistan, with great potential and prehistoric resources, has numerous petroglyphs in different areas of the province. During the last 14 years of extensive field study, more than 30 sites of rock art have been identified and introduced by the author. In this article, we summarize these rock art areas in Iranian Kurdistan.

  18. Rock Art in Kurdistan Iran

    OpenAIRE

    Jamal Lahafian

    2013-01-01

    Kurdistan, with great potential and prehistoric resources, has numerous petroglyphs in different areas of the province. During the last 14 years of extensive field study, more than 30 sites of rock art have been identified and introduced by the author. In this article, we summarize these rock art areas in Iranian Kurdistan.

  19. Workshop on hydrology of crystalline basement rocks

    Energy Technology Data Exchange (ETDEWEB)

    Davis, S.N. (comp.)

    1981-08-01

    This workshop covered the following subjects: measurements in relatively shallow boreholes; measurement and interpretation of data from deep boreholes; hydrologic properties of crystalline rocks as interpreted by geophysics and field geology; rock mechanics related to hydrology of crystalline rocks; the possible contributions of modeling to the understanding of the hydrology of crystalline rocks; and geochemical interpretations of the hydrology of crystalline rocks. (MHR)

  20. Spectral-induced polarization characteristics of rocks from Shinyemi deposit in Northeastern South Korea

    Science.gov (United States)

    Park, Samgyu; Shin, Seung Wook; Son, Jeong-Sul; Kim, Changryol

    2016-04-01

    Contact metasomatism between carbonate and igneous rocks leads to the formation of skarn deposits, and ore minerals are abundant. Geophysical methods that visualize the distributions of physical properties have been utilized to determine lithological boundaries in ore deposits. In particular, spectral-induced polarization (SIP) is the most effective of those methods for mineral exploration because it can obtain not only the boundaries but also the abundance and grain size of ore minerals. It is crucial to characterize the SIP responses of in situ rocks for a more realistic interpretation. Thus, typical rocks composed of igneous rock, skarn rock, skarn ore, and carbonate rock were sampled from drilling cores in the Shinyemi deposit, which is one of the well-known skarn deposits in Northeastern South Korea. The purpose of this study was to characterize the SIP responses of rocks by laboratory measurements. The characterization was performed by evaluating spectra and IP parameters. The IP properties were acquired from equivalent circuit analysis using a circuit model based on the electrochemical theory, and the analysis results of this circuit model were relatively well fit compared with those of the traditional Dias and Cole-Cole models. The frequency responses below 100 Hz in the spectra and the chargeability values of the skarn rocks and ores containing magnetite were relatively strong and high, respectively, compared with those of non-mineralized igneous and carbonate rocks. Therefore, it is considered that these characteristics are dependent on the abundance of magnetite. In case of the skarn ores with high magnetite content, the resistivity values were significantly low and the relaxation time values were influenced by the grain size of magnetite. On the other hand, it is considered that the DC resistivity and the relaxation time values of the igneous and carbonate rocks are slightly related to the porosity and the grade of hydrothermal alteration, respectively.

  1. Rock suitability classification RSC 2012

    Energy Technology Data Exchange (ETDEWEB)

    McEwen, T. (ed.) [McEwen Consulting, Leicester (United Kingdom); Kapyaho, A. [Geological Survey of Finland, Espoo (Finland); Hella, P. [Saanio and Riekkola, Helsinki (Finland); Aro, S.; Kosunen, P.; Mattila, J.; Pere, T.

    2012-12-15

    This report presents Posiva's Rock Suitability Classification (RSC) system, developed for locating suitable rock volumes for repository design and construction. The RSC system comprises both the revised rock suitability criteria and the procedure for the suitability classification during the construction of the repository. The aim of the classification is to avoid such features of the host rock that may be detrimental to the favourable conditions within the repository, either initially or in the long term. This report also discusses the implications of applying the RSC system for the fulfilment of the regulatory requirements concerning the host rock as a natural barrier and the site's overall suitability for hosting a final repository of spent nuclear fuel.

  2. Seismic properties of polyphase rocks

    Science.gov (United States)

    Wang, Qin

    2005-11-01

    Knowledge about the seismic properties of polyphase rocks is fundamental for interpreting seismic refraction and reflection data and for establishing lithospheric structure and composition models. This study aims to obtain more precise relationships between seismic properties of rocks and controlling factors (e.g., pressure, temperature, mineralogical and chemical compositions, microstructure of rocks), particularly for those rocks imprinted by ultrahigh-pressure (UHP) metamorphism. These relationships will be very helpful to extrapolate calculated and measured seismic properties of rocks to depths of interest and to engender interpretations relevant to petrological composition and tectonic process. An Internet Database of Rock Seismic Properties (DRSP) was set up and a Handbook of Seismic Properties of Minerals, Rocks and Ores was published. They comprise almost all data available in the literature during the past 4 decades and can serve as a convenient, comprehensive and concise information source on physical properties of rocks to the earth sciences and geotechnical communities. Statistical results of the DRSP reveal the dependence of seismic properties on density, porosity, humidity, and mineralogical and chemical compositions. Using 16 different averaging methods, we calculated P-wave velocities of 696 dry samples according to the volume fraction and elastic constants of each constituent mineral. Although only 22 common minerals were taken into account in the computation, the calculated P-wave velocities agree well with laboratory values measured at about 300 MPa, where most microcracks are closed and the mean Vp of a polymineralic rock is exclusively controlled by its modal composition. However, none of these mixture rules can simultaneously fit measured P-wave velocities for all lithologies or at all pressures. Therefore, more prudence is required in selecting an appropriate mixture rule for calculation of seismic velocities of different rock types.

  3. Research on Mechanism of Rock Burst Generation and Development for High Stress Rock Tunnels

    Institute of Scientific and Technical Information of China (English)

    高全臣; 赫建明; 王代华

    2001-01-01

    Through the investigation and analysis of high stress distribution in surrounding rock during the excavation of rock tunnels,the key factors to cause rock burst and the mechanism of rock burst generation and development are researched. The result shows that the scale and range of rock burst are related with elastic deformation energy storied in rock mass and the characteristics of unloading stress waves. The measures of preventing from rock burst for high stress rock tunnels are put forward.

  4. Tracer tomography (in) rocks!

    Science.gov (United States)

    Somogyvári, Márk; Jalali, Mohammadreza; Jimenez Parras, Santos; Bayer, Peter

    2016-04-01

    Physical behavior of fractured aquifers is rigorously controlled by the presence of interconnected conductive fractures, as they represent the main pathways for flow and transport. Ideally, they are simulated as a discrete fracture network (DFN) in a model to capture the role of fracture system geometry, i.e. fracture length, height, and width (aperture/transmissivity). Such network may be constrained by prior geological information or direct data resources such as field mapping, borehole logging and geophysics. With the many geometric features, however, calibration of a DFN to measured data is challenging. This is especially the case when spatial properties of a fracture network need to be calibrated to flow and transport data. One way to increase the insight in a fractured rock is by combining the information from multiple field tests. In this study, a tomographic configuration that combines multiple tracer tests is suggested. These tests are conducted from a borehole with different injection levels that act as sources. In a downgradient borehole, the tracer is recorded at different levels or receivers, in order to maximize insight in the spatial heterogeneity of the rock. As tracer here we chose heat, and temperature breakthrough curves are recorded. The recorded tracer data is inverted using a novel stochastic trans-dimensional Markov Chain Monte Carlo procedure. An initial DFN solution is generated and sequentially modified given available geological information, such as expected fracture density, orientation, length distribution, spacing and persistency. During this sequential modification, the DFN evolves in a trans-dimensional inversion space through adding and/or deleting fracture segments. This stochastic inversion algorithm requires a large number of thousands of model runs to converge, and thus using a fast and robust forward model is essential to keep the calculation efficient. To reach this goal, an upwind coupled finite difference method is employed

  5. A review of some recently proposed modeling paradigms for the sorption of hydrophobic organic chemicals to heterogeneous carbonaceous matter in soils, sediments, and rocks -- the role of thermally altered carbon

    Science.gov (United States)

    Ball, W. P.; Allen-King, R. M.; Grathwohl, P.; Nguyen, T. H.; Brown, R. A.

    2003-04-01

    Heterogeneity of naturally occurring carbonaceous materials (CMs) in soils, sediments, and rocks causes the sorption of hydrophobic organic chemicals (HOCs) to occur as a combination of surface adsorption and phase partitioning, with the latter typically more linearly dependent on aqueous concentration. In particular, thermally altered CMs (such as wood char, soots, coals, and kerogen) are widespread in the environment and can serve as an important sorbents even when present in small quantities (especially at low concentrations of adsorbates). In this context, recent literature has presented models to simulate HOC sorption as the combined effect of adsorption to thermally altered CM and a more linear solvation-driven absorption into gel-like organic matter. We describe different forms of thermally altered CM, the manner in which these materials can serve as especially strong adsorbents, and the conditions under which they can control solid-aqueous distribution. Individual study with some well-characterized chars, coals, and soots have been conducted in our laboratories and provide some clear indications of the potential role of these materials in affecting overall contaminant uptake. Additionally, some specific examples of model fits to soil, sediment and rock samples with identified thermally altered CM components provide a linkage between such sorption components and sorbent material properties. Because both the adsorption and partition components are scalable by compound solubility, it may often be possible to provide estimates of nonlinear isotherms for a wide range of chemicals based on comparatively few experimental measurements using probe chemical sorbates. Although such a limited experimental study is not expected to provide a precise accounting of all aspects of adsorption and partitioning, we maintain that it will be clearly preferable to an a priori assumption of linear phase partitioning, and particularly so if enough information can be generated to

  6. Sedimentology and facies analysis of Devonian Rocks, southern district of Mackenzie, North West Territories, Canada

    NARCIS (Netherlands)

    Meijer Drees, N.C.

    1989-01-01

    The Devonian rock succession in the southern part of the District of Mackenzie consists of interbedded evaporites and carbonates, fossiliferous carbonates and shales. Inthe study areathe Devonian succession unconformably overlies LowerPaleozoic orPrecambrian strata and thins in a northeastward direc

  7. Uranium series, volcanic rocks

    Science.gov (United States)

    Vazquez, Jorge A.

    2014-01-01

    Application of U-series dating to volcanic rocks provides unique and valuable information about the absolute timing of crystallization and differentiation of magmas prior to eruption. The 238U–230Th and 230Th-226Ra methods are the most commonly employed for dating the crystallization of mafic to silicic magmas that erupt at volcanoes. Dates derived from the U–Th and Ra–Th methods reflect crystallization because diffusion of these elements at magmatic temperatures is sluggish (Cherniak 2010) and diffusive re-equilibration is insignificant over the timescales (less than or equal to 10^5 years) typically associated with pre-eruptive storage of nearly all magma compositions (Cooper and Reid 2008). Other dating methods based on elements that diffuse rapidly at magmatic temperatures, such as the 40Ar/39Ar and (U–Th)/He methods, yield dates for the cooling of magma at the time of eruption. Disequilibrium of some short-lived daughters of the uranium series such as 210Po may be fractionated by saturation of a volatile phase and can be employed to date magmatic gas loss that is synchronous with volcanic eruption (e.g., Rubin et al. 1994).

  8. Rock salt constitutive modeling

    Energy Technology Data Exchange (ETDEWEB)

    Nickell, R.E.

    1980-03-18

    The Serata model is the best operational model available today because it incorporates: (1) a yield function to demarcate between viscoelastic and viscoplastic behavior of rock salt; (2) a pressure and temperature dependence for yield stresses; and (3) a standard linear solid, which can be readily extended into the non-linear regime, to represent creep behavior. Its only deficiencies appear to be the lack of secondary creep behavior (a free dashpot) and some unsettling arbitrariness about the Poisson's ratio (..nu.. ..-->.. 0.5) argument for viscoplasticity. The Sandia/WIPP model will have good primary and secondary creep capability, but lacks the viscoplastic behavior. In some cases, estimated inelastic strains may be underpredicted. If a creep acceleration mechanism associated with brine inclusions is observed, this model may require extensive revision. Most of the other models available (SAI, RE-SPEC, etc.) are only useful for short-term calculations, because they employ temporal power law (t/sup n/) primary creep representations. These models are unsatisfactory because they cannot represent dual mechanisms with differing characteristic times. An approach based upon combined creep and plasticity is recommended in order to remove the remaining deficiency in the Serata model. DOE/Sandia/WIPP should be encouraged to move aggressively in this regard.

  9. They will rock you!

    CERN Multimedia

    Anaïs Schaeffer

    2013-01-01

    On 30 September, CERN will be the venue for one of the most prestigious events of the year: the concert for the Bosons&More event, the Organization’s celebration of the remarkable performance of the LHC and all its technical systems, as well as the recent fundamental discoveries. Topping the bill will be the Orchestre de la Suisse Romande, the CERN Choir, the Zürcher Sing-Akademie and the Alan Parsons Live Project rock group, who have joined forces to create an unforgettable evening’s entertainment.   The Orchestre de la Suisse Romande, directed by Maestro Neeme Järvi, artistic and musical director of the OSR. (Image: Grégory Maillot). >>> From the Orchestre de la Suisse Romande… Henk Swinnen, General Manager of the Orchestre de la Suisse Romande (OSR), answers some questions for the CERN Bulletin, just a few days before the event. How did this project come about? When CERN invited us to take part in the B...

  10. Source rock potential in Pakistan

    Energy Technology Data Exchange (ETDEWEB)

    Raza, H.A. (Hydrocarbon Development Institute of Pakistan, Islamabad (Pakistan))

    1991-03-01

    Pakistan contains two sedimentary basins: Indus in the east and Balochistan in the west. The Indus basin has received sediments from precambrian until Recent, albeit with breaks. It has been producing hydrocarbons since 1914 from three main producing regions, namely, the Potwar, Sulaisman, and Kirthar. In the Potwar, oil has been discovered in Cambrian, Permian, Jurassic, and Tertiary rocks. Potential source rocks are identified in Infra-Cambrian, Permian, Paleocene, and Eocene successions, but Paleocene/Eocene Patala Formation seems to be the main source of most of the oil. In the Sulaiman, gas has been found in Cretaceous and Tertiary; condensate in Cretaceous rocks. Potential source rocks are indicated in Cretaceous, Paleocene, and Eocene successions. The Sembar Formation of Early Cretaceous age appears to be the source of gas. In the Kirthar, oil and gas have been discovered in Cretaceous and gas has been discovered in paleocene and Eocene rocks. Potential source rocks are identified in Kirthar and Ghazij formations of Eocene age in the western part. However, in the easter oil- and gas-producing Badin platform area, Union Texas has recognized the Sembar Formation of Early Cretaceous age as the only source of Cretaceous oil and gas. The Balochistan basin is part of an Early Tertiary arc-trench system. The basin is inadequately explored, and there is no oil or gas discovery so far. However, potential source rocks have been identified in Eocene, Oligocene, Miocene, and Pliocene successions based on geochemical analysis of surface samples. Mud volcanoes are present.

  11. Towards a geomechanics classification of folded layered rock masses

    Science.gov (United States)

    Agliardi, Federico; Zanchi, Andrea; Bianchi, Federico; Crosta, Giovanni B.

    2016-04-01

    Several schemes have been proposed in the last decades to account for the effects of structure and alteration of rock masses on their geo-mechanical properties. Among these, the Geological Strength Index (GSI) turned out as the most effective to account for complex geological conditions, including heavily fractured, heterogeneous (e.g. flysch-like) or tectonically disturbed rock masses. It is well known that folding has a direct impact on the type and degree of fracturing. Nevertheless, no classification scheme has been developed to introduce explicitly the effects of folding and associated fracturing on rock mass strength and deformability. In this perspective, we carried out an exploratory study aimed at establishing relationships between outcrop-scale folding and GSI in layered carbonate rock masses, exceptionally well exposed in a quarry near Bergamo (Lombardia, Southern Alps). A N-S trending, 350m long and 115m high benched rock face exposes a complete cross section of a sub-horizontal inclined fold involving Lower Jurassic cherty mudstones (Moltrasio Lms.) and marly limestones successions (Domaro Lms.). The main fold has an axial surface moderately dipping to the north and is characterised by polyharmonic folds at scales of metres to tens of metres. The site was documented by producing a digital outcrop through a high-resolution terrestrial photogrammetric survey from distances ranging from 70 to 130 m (18 camera stations, 395 pictures), using RTK GNSS measurements for camera station geo-referencing. Data processing by Structure-from-Motion (SfM) techniques resulted in detailed point clouds covering the entire slope with a cm-scale accuracy. In order to establish relationships between lithology, folding styles, and geomechanical properties of folded rock masses we performed a detailed structural analysis at 25 survey stations spread over all the different fold sectors. These surveys include: lithology, bedding attitude and thickness, brittle structures (e

  12. Sulphate rocks as an arena for karst development

    Directory of Open Access Journals (Sweden)

    Andrejchuk V.

    1996-01-01

    Full Text Available The rocks in which karst systems develop are most commonly composed of carbonate sulphate and chloride minerals. The sulphate minerals are quite numerous, but only gypsum and anhydrite form extensive masses in sedimentary sequences. Other minerals, which represent sulphates of K, Mg and Na, normally occur as minor beds (0.1-5.0 m, or as inclusions associated with chloride rocks. However some minerals precipitated in salt-generating basins, such as mirabilite and glauberite (typically formed in the Kara-Bogaz-Gol Gulf, salt lakes of Siberia and in China, form sequences up to 5-10 m thick where karst may develop. Due to the very high solubility of Na -sulphates, karst processes and features occurring in these rocks resemble salt karst. Thus, the term sulphate karst, although not strictly correct, is used mainly to indicate karst developed in gypsum and anhydrite.

  13. Geoelectrical Characterization of Sulphate Rocks

    OpenAIRE

    Guinea Maysounave, Ander

    2012-01-01

    [eng] Gypsum rocks are widely exploited in the world as industrial minerals. The purity of the gypsum rocks (percentage in gypsum mineral –CaSO4•2H2O- in the whole rock) is a critical factor to evaluate the potential exploitability of a gypsum deposit. It is considered than purities higher than 80% in gypsum are required to be economically profitable. Gypsum deposits have been studied with geoelectrical methods; a direct relationship between the electrical resistivity values of the gypsum roc...

  14. Multiverso: Rock'n'Astronomy

    Science.gov (United States)

    Caballero, J. A.

    2012-05-01

    In the last few years, there have been several projects involving astronomy and classical music. But have a rock band ever appeared at a science conference or an astronomer at a rock concert? We present a project, Multiverso, in which we mix rock and astronomy, together with poetry and video art (Caballero, 2010). The project started in late 2009 and has already reached tens of thousands people in Spain through the release of an album, several concert-talks, television, radio, newspapers and the internet.

  15. High-resolution rock structure image processing method and its applications in carbonate reservoir evaluation%高清晰岩石结构图像处理方法及其在碳酸盐岩储层评价中的应用

    Institute of Scientific and Technical Information of China (English)

    柴华; 李宁; 夏守姬; 武宏亮; 郭宏伟; 王克文; 冯周; 梁明星

    2012-01-01

    电阻率成像测井已经成为解决非均质复杂碎屑岩储层、缝洞型碳酸盐岩储层、火山岩储层问题不可或缺的关键手段之一,而且正在逐渐从高端测井技术走进常规系列.目前主流的成像处理方法中,普遍采用了基于像素分布特征统计的图像增强方法.该方法相对于最初的线性图像增强方法,效果明显改善,然而在处理中未能考虑岩石结构特征的分布规律,经常导致重要的地质特征被湮没在次要特征和噪声中.笔者在传统图像增强方法的基础上,进一步以结构信息为核心要素,提出了基于岩石结构的图像增强方法.该方法以岩石结构特征判别为基础,有针对性地提高图像中关键信息的权重,弱化背景和噪声,并针对结构特征分布规律进行成像色标动态优化,从而显著提高了图像的有效信息量和清晰度,为进一步的精细解释工作提供了先决条件.%The resistivity imaging logging is known as one of the indispensable means for solving problems of heterogeneous complex clastic reservoirs fractured-vuggy carbonate reservoirs, and volcanic reservoirs. The previous high-end logging technology is gradually considered to be a routine method. At present, the mainstream image processing approaches commonly employ the image enhancement methods based on the pixel distribution characteristics. Despite substantial improvement compared to the original linear image enhancement method, the distribution-based image enhancement methods do not take into account the distributions of rock structural features, commonly leading to the submergence of major geological features in minor features and noises. On the basis of conventional image enhancement methods, this study focused on rock structure information and proposed a new rock structure-based image enhancement method. Based on the identification of rock structural features, the proposed method was shown to increase the weight of targeted

  16. Genesis and organic geochemical characteristics of the carbonaceous rock stratabound gold deposits, South China

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The organic matter of three different chronological major carbonaceous rock gold-bearing formations of South China (Middle Proterozoic Shangqiaoshan group of northeastern Jiangxi, Lower Cambrian Shuikou group of northern Guangxi and Devonian Shetianqiao group of eastern Hunan) and related carbonaceous stratabound gold deposits such as Jinshan, Longshui and Shixia deposits, respectively, has been characterized by organic geochemical techniques. These organic geochemical results show that the average total organic carbon (TOC) content of the three chronological carbonaceous rock gold-bearing formations of South China ranges from 0.15% to 1.56%. The thermal maturity of the organic matter of host rocks in the three gold-bearing formations is high. The micro-component of the organic matter of the host rocks consists primarily of solid bitumen and graphite. The organic carbon and gold of the host rocks appear to syndeposit in situ during the formation of the gold-bearing formations. The organic carbon played a certain role in controlling the geochemical environment of the gold-bearing formations. The metallogenetic mechanism of the carbonaceous rock stratabound gold deposits of South China is closely associated in genesis with the sedimentation, diagenesis and thermal evolution history of the organic matter of host rocks in the gold-bearing formations.

  17. Hydrogeologic framework of fractured sedimentary rock, Newark Basin, New Jersey

    Science.gov (United States)

    Lacombe, Pierre J.; Burton, William C.

    2010-01-01

    The hydrogeologic framework of fractured sedimentary bedrock at the former Naval Air Warfare Center (NAWC), Trenton, New Jersey, a trichloroethylene (TCE)-contaminated site in the Newark Basin, is developed using an understanding of the geologic history of the strata, gamma-ray logs, and rock cores. NAWC is the newest field research site established as part of the U.S. Geological Survey Toxic Substances Hydrology Program, Department of Defense (DoD) Strategic Environmental Research and Development Program, and DoD Environmental Security Technology Certification Program to investigate contaminant remediation in fractured rock. Sedimentary bedrock at the NAWC research site comprises the Skunk Hollow, Byram, and Ewing Creek Members of the Lockatong Formation and Raven Rock Member of the Stockton Formation. Muds of the Lockatong Formation that were deposited in Van Houten cycles during the Triassic have lithified to form the bedrock that is typical of much of the Newark Basin. Four lithotypes formed from the sediments include black, carbon-rich laminated mudstone, dark-gray laminated mudstone, light-gray massive mudstone, and red massive mudstone. Diagenesis, tectonic compression, off-loading, and weathering have altered the rocks to give some strata greater hydraulic conductivity than other strata. Each stratum in the Lockatong Formation is 0.3 to 8 m thick, strikes N65 degrees E, and dips 25 degrees to 70 degrees NW. The black, carbon-rich laminated mudstone tends to fracture easily, has a relatively high hydraulic conductivity and is associated with high natural gamma-ray count rates. The dark-gray laminated mudstone is less fractured and has a lower hydraulic conductivity than the black carbon-rich laminated mudstone. The light-gray and the red massive mudstones are highly indurated and tend to have the least fractures and a low hydraulic conductivity. The differences in gamma-ray count rates for different mudstones allow gamma-ray logs to be used to correlate and

  18. ROCK DEFORMATION. Final Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    None

    2002-05-24

    The Gordon Research Conference (GRC) on ROCK DEFORMATION was held at II Ciocco from 5/19/02 thru 5/24/02. Emphasis was placed on current unpublished research and discussion of the future target areas in this field.

  19. Anthropic Rock: a brief history

    Directory of Open Access Journals (Sweden)

    R. B. Cathcart

    2011-03-01

    Full Text Available Stone tool-making is a reductive process. Synthetic rock manufacturing, preeminently an additive process, will not for-ever be confined to only the Earth-biosphere. This brief focuses on humanity's ancient past, hodiernal and possible future even more massive than present-day creation of artificial rocks within our exploitable Solar System. It is mostly Earth-centric account that expands the factual generalities underlying the unique non-copyrighted systemic technogenic rock classification first publicly presented (to the American Geological Society during 2001, by its sole intellectual innovator, James Ross Underwood, Jr. His pioneering, unique exposition of an organization of this ever-increasingly important aspect of the Anthropic Rock story, spatially expansive material lithification, here is given an amplified discussion for the broader geo and space science social group-purpose of encouragement of a completer 21st Century treatment of Underwood's explicative subject-chart (Fig. 2.

  20. TOC changes in the process of thermal evolution of source rock and its controls

    Institute of Scientific and Technical Information of China (English)

    ZHONG; Ningning; LU; Shuangfang; HUANG; Zhilong; ZHANG; Y

    2004-01-01

    Through geological observation, simulation in laboratory and numerical modeling, the factors that control the changes in total organic content (TOC) of source rock have been studied. When the formula DTOC=(TOC0-TOC)/TOC0 (original organic carbon content in the rock) is used to measure the TOC (total organic carbon content) changes in the source rock through geological time, the degrees and directions of such changes are determined by losses and relative amounts both of organic and inorganic matter in the source rock. The DTOC equation, which is used to calculate the loss rate in the process of maturation for the source rock, is therefore obtained by analyzing the mass balance relations. For a certain type of source rock with a certain maturation history, the changes of its TOC respond only to the rates of hydrocarbon generation and expulsion. In actual cases of geological entities, DTOC generally ranges from -0.05 to 0.2, while the calculated reconversion coefficient (k) for organic carbon content remains between 0.90 and 1.25. Only in an ideal situation where there are extremely high rates of hydrocarbon generation and expulsion can the DTOC value experience significant changes, with k reaching up to 2.5. It is concluded, therefore, that the criterion for carbonates source rock assessment, based on reconverting the TOC to the value of its original state, may have overestimated the course of the "carbon-reduction", which is likely in many cases to make a poor source rock sound better.

  1. Thermally induced rock stress increment and rock reinforcement response

    Energy Technology Data Exchange (ETDEWEB)

    Hakala, M. [KMS Hakala Oy, Nokia (Finland); Stroem, J.; Nujiten, G.; Uotinen, L. [Rockplan, Helsinki (Finland); Siren, T.; Suikkanen, J.

    2014-07-15

    This report describes a detailed study of the effect of thermal heating by the spent nuclear fuel containers on the in situ rock stress, any potential rock failure, and associated rock reinforcement strategies for the Olkiluoto underground repository. The modelling approach and input data are presented together repository layout diagrams. The numerical codes used to establish the effects of heating on the in situ stress field are outlined, together with the rock mass parameters, in situ stress values, radiogenic temperatures and reinforcement structures. This is followed by a study of the temperature and stress evolution during the repository's operational period and the effect of the heating on the reinforcement structures. It is found that, during excavation, the maximum principal stress is concentrated at the transition areas where the profile changes and that, due to the heating from the deposition of spent nuclear fuel, the maximum principal stress rises significantly in the tunnel arch area of NW/SW oriented central tunnels. However, it is predicted that the rock's crack damage (CD, short term strength) value of 99 MPa will not be exceeded anywhere within the model. Loads onto the reinforcement structures will come from damaged and loosened rock which is assumed in the modelling as a free rock wedge - but this is very much a worst case scenario because there is no guarantee that rock cracking would form a free rock block. The structural capacity of the reinforcement structures is described and it is predicted that the current quantity of the rock reinforcement is strong enough to provide a stable tunnel opening during the peak of the long term stress state, with damage predicted on the sprayed concrete liner. However, the long term stability and safety can be improved through the implementation of the principles of the Observational Method. The effect of ventilation is also considered and an additional study of the radiogenic heating effect on the

  2. Institute for Rock Magnetism established

    Science.gov (United States)

    Banerjee, Subir K.

    There is a new focal point for cooperative research in advanced rock magnetism. The University of Minnesota in Minneapolis has established an Institute for Rock Magnetism (IRM) that will provide free access to modern equipment and encourage visiting fellows to focus on important topics in rock magnetism and related interdisciplinary research. Funding for the first three years has been secured from the National Science Foundation, the W.M. Keck Foundation, and the University of Minnesota.In the fall of 1986, the Geomagnetism and Paleomagnetism (GP) section of the AGU held a workshop at Asilomar, Calif., to pinpoint important and emerging research areas in paleomagnetism and rock magnetism, and the means by which to achieve them. In a report of this workshop published by the AGU in September 1987, two urgent needs were set forth. The first was for interdisciplinary research involving rock magnetism, and mineralogy, petrology, sedimentology, and the like. The second need was to ease the access of rock magnetists and paleomagnetists around the country to the latest equipment in modern magnetics technology, such as magneto-optics or electronoptics. Three years after the publication of the report, we announced the opening of these facilities at the GP section of the AGU Fall 1990 Meeting. A classified advertisement inviting applications for visiting fellowships was published in the January 22, 1991, issue of Eos.

  3. Mesozoic and Cenozoic rocks from Malta Escarpment (central Mediterranean)

    Energy Technology Data Exchange (ETDEWEB)

    Scandone, P. (Istituto di Geologia e Paleontologia, Pisa, Italy); Patacca, E.; Radoicic, R.; Ryan, W.B.F.; Cita, M.B.; Rawson, M.; Chezar, H.; Miller, E.; McKenzie, J.; Rossi, S.

    1981-07-01

    Sedimentary rocks of Triassic-Neogene age are present on the Malta Escarpment of the eastern Mediterranean. Upper Triassic dolomitic limestones of shallow-water origin, at depths between 2.5 and 3.5 km, are similar in lithofacies to coeval platform carbonates of the Siracusa (Syracuse) belt of southern Sicily. Jurassic rocks include lower-middle Liassic shallow-water limestones followed by condensed hemipelagic lime deposits indicative of sinking and starving of the former platform. Cretaceous materials are represented by both red marls rich in planktonic faunas and reworkd volcaniclastic breccias including shallow-water skeletal material. Paleogene rocks are both shallow-water limestones with corals, algae, and bivalves, and redeposited calcarenites of lithofacies similar to those from surface and subsurface of the Ragusa zone. Oligocene-lower Miocene rocks from the escarpment are also similar in lithology to the coeval Ragusa deposits. Tortonian is represented by hemipelagic marls indicating open-marine environment. Pervasive dolomitization on lime crusts and on initial-stage fissure fillings with strongly positive isotopic oxygen ratio is thought to be a product of Messinian evaporitic drawdown. Pliocene sediments belong to the Trubi facies and consist of pelagic foraminiferal chalk. An impressive vertical relief existed by Miocene times, as attested by Messinian crusts and veins on or in rocks as old as Late Triassic. Our data do not provide evidence that this morphologic feature necessarily coincides with a continent-ocean transition. The present escarpment was produced by faulting, erosion, and defacement. 14 figures, 1 table.

  4. Treated and untreated rock dust: Quartz content and physical characterization.

    Science.gov (United States)

    Soo, Jhy-Charm; Lee, Taekhee; Chisholm, William P; Farcas, Daniel; Schwegler-Berry, Diane; Harper, Martin

    2016-11-01

    Rock dusting is used to prevent secondary explosions in coal mines, but inhalation of rock dusts can be hazardous if the crystalline silica (e.g., quartz) content in the respirable fraction is high. The objective of this study is to assess the quartz content and physical characteristics of four selected rock dusts, consisting of limestone or marble in both treated (such as treatment with stearic acid or stearates) and untreated forms. Four selected rock dusts (an untreated and treated limestone and an untreated and treated marble) were aerosolized in an aerosol chamber. Respirable size-selective sampling was conducted along with particle size-segregated sampling using a Micro-Orifice Uniform Deposit Impactor. Fourier Transform Infrared spectroscopy and scanning electron microscopy with energy-dispersive X-ray (SEM-EDX) analyses were used to determine quartz mass and particle morphology, respectively. Quartz percentage in the respirable dust fraction of untreated and treated forms of the limestone dust was significantly higher than in bulk samples, but since the bulk percentage was low the enrichment factor would not have resulted in any major change to conclusions regarding the contribution of respirable rock dust to the overall airborne quartz concentration. The quartz percentage in the marble dust (untreated and treated) was very low and the respirable fractions showed no enrichment. The spectra from SEM-EDX analysis for all materials were predominantly from calcium carbonate, clay, and gypsum particles. No free quartz particles were observed. The four rock dusts used in this study are representative of those presented for use in rock dusting, but the conclusions may not be applicable to all available materials.

  5. Substantial global carbon uptake by cement carbonation

    Science.gov (United States)

    Xi, Fengming; Davis, Steven J.; Ciais, Philippe; Crawford-Brown, Douglas; Guan, Dabo; Pade, Claus; Shi, Tiemao; Syddall, Mark; Lv, Jie; Ji, Lanzhu; Bing, Longfei; Wang, Jiaoyue; Wei, Wei; Yang, Keun-Hyeok; Lagerblad, Björn; Galan, Isabel; Andrade, Carmen; Zhang, Ying; Liu, Zhu

    2016-12-01

    Calcination of carbonate rocks during the manufacture of cement produced 5% of global CO2 emissions from all industrial process and fossil-fuel combustion in 2013. Considerable attention has been paid to quantifying these industrial process emissions from cement production, but the natural reversal of the process--carbonation--has received little attention in carbon cycle studies. Here, we use new and existing data on cement materials during cement service life, demolition, and secondary use of concrete waste to estimate regional and global CO2 uptake between 1930 and 2013 using an analytical model describing carbonation chemistry. We find that carbonation of cement materials over their life cycle represents a large and growing net sink of CO2, increasing from 0.10 GtC yr-1 in 1998 to 0.25 GtC yr-1 in 2013. In total, we estimate that a cumulative amount of 4.5 GtC has been sequestered in carbonating cement materials from 1930 to 2013, offsetting 43% of the CO2 emissions from production of cement over the same period, not including emissions associated with fossil use during cement production. We conclude that carbonation of cement products represents a substantial carbon sink that is not currently considered in emissions inventories.

  6. Diversity of endolithic fungal communities in dolomite and limestone rocks from Nanjiang Canyon in Guizhou karst area, China.

    Science.gov (United States)

    Tang, Yuan; Lian, Bin

    2012-06-01

    The endolithic environment, the tiny pores and cracks in rocks, buffer microbial communities from a number of physical stresses, such as desiccation, rapid temperature variations, and UV radiation. Considerable knowledge has been acquired about the diversity of microorganisms in these ecosystems, but few culture-independent studies have been carried out on the diversity of fungi to date. Scanning electron microscopy of carbonate rock fragments has revealed that the rock samples contain certain kinds of filamentous fungi. We evaluated endolithic fungal communities from bare dolomite and limestone rocks collected from Nanjiang Canyon (a typical karst canyon in China) using culture-independent methods. Results showed that Ascomycota was absolutely dominant both in the dolomite and limestone fungal clone libraries. Basidiomycota and other eukaryotic groups (Bryophyta and Chlorophyta) were only detected occasionally or at low frequencies. The most common genus in the investigated carbonate rocks was Verrucaria. Some other lichen-forming fungi (e.g., Caloplaca, Exophiala, and Botryolepraria), Aspergillus, and Penicillium were also identified from the rock samples. The results provide a cross-section of the endolithic fungal communities in carbonate rocks and help us understand more about the role of microbes (fungi and other rock-inhabiting microorganisms) in rock weathering and pedogenesis.

  7. Effect of diagenesis on compaction of reservoir rocks

    OpenAIRE

    Olgaard, D.; Cameron, S.; Dunsmuir, J.; Herhold, A.; King, H; Gooch, M. J.

    2007-01-01

    Predicting sediment porosity-depth trends and ultimately the quality of reservoir rocks requires an understanding of mechanical and chemical compaction mechanisms during diagenesis. In many siliciclastic sediments porosity versus depth profiles can be predicted from the sediment’s stress history. In carbonates such predictions are more difficult because chemical diagenesis is prevalent even within a few meters of the seafloor. We used a systematic laboratory approach to investigate th...

  8. 30 CFR 57.3461 - Rock bursts.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Rock bursts. 57.3461 Section 57.3461 Mineral...-Underground Only § 57.3461 Rock bursts. (a) Operators of mines which have experienced a rock burst shall— (1) Within twenty four hours report to the nearest MSHA office each rock burst which: (i) Causes persons...

  9. Use of total organic carbon, spectral gamma ray and bioturbation as tools in the identification of source rock; Carbono organico total, gamaespectrometria e bioturbacao como ferramentas na busca de possiveis horizontes geradores de hidrocarbonetos

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Anderson S.; Pereira, Egberto [Universidade do Estado do Rio de Janeiro (UERJ), RJ (Brazil). Faculdade de Geologia. Dept. de Estratigrafia e Paleontologia

    2008-07-01

    This work presents the result obtained for the gamaespectrometric study of a borehole situated in north of Parana Basin, concerning sediments of the Ponta Grossa Formation. The Total Radioactivity data and the concentrations of Potassium (K), Uranium (U), Thorium (Th) have been compared to the Total Organic Carbon (TOC) and to the degree of bioturbation intensity. The mentioned formation is composed of basal sandstones deposited in shoreface conditions, which pass to siltstones and black shales deposited in offshore conditions. Nine sedimentary facies were identified based on sedimentological characteristics and sedimentary structures. The bioturbation intensity indicates the modification degree of the initial arrangement of sedimentary beds by the action of organisms. High TOC values in the intervals in addition to the increase of the radioactivity values indicate anoxic conditions. These conditions are ideal for the organic matter concentration and preservation, reflecting favorable intervals to the hydrocarbons (HC) generation. Thus, with the integrated use of diverse tools it was possible to confirm that the Givetian-Frasnian interval of the Ponta Grossa Formation presents the best potential of HC generation of the section analyzed. (author)

  10. Tracing Life in the Earliest Terrestrial Rock Record

    Science.gov (United States)

    Lepland, A.; van Zuilen, M.; Arrhenius, G.

    2001-12-01

    The principal method for studying the earliest traces of life in the metamorphosed, oldest (> 3.5 Ga) terrestrial rocks involves determination of isotopic composition of carbon, mainly prevailing as graphite. It is generally believed that this measure can distinguish biogenic graphite from abiogenic varieties. However, the interpretation of life from carbon isotope ratios has to be assessed within the context of specific geologic circumstances requiring (i) reliable protolith interpretation (ii) control of secondary, metasomatic processes, and (iii) understanding of different graphite producing mechanisms and related carbon isotopic systematics. We have carried out a systematic study of abundance, isotopic composition and petrographic associations of graphite in rocks from the ca. 3.8 Ga Isua Supracrustal Belt (ISB) in southern West Greenland. Our study indicates that most of the graphite in ISB occurs in carbonate-rich metasomatic rocks (metacarbonates) while sedimentary units, including banded iron formations (BIFs) and metacherts, have exceedingly low graphite concentrations. Regardless of isotopic composition of graphite in metacarbonate rocks, their secondary origin disqualifies them from providing evidence for traces of life stemming from 3.8 Ga. Recognition of the secondary origin of Isua metacarbonates thus calls for reevaluation of biologic interpretations by Schidlowski et al. (1979) and Mojzsis et al. (1996) that suggested the occurrence of 3.8 Ga biogenic graphite in these rocks. The origin of minute quantities of reduced carbon, released from sedimentary BIFs and metacherts at combustion steps > 700 C remains to be clarified. Its isotopic composition (d13C from -18 to -25%) may hint at a biogenic origin. However, such isotopically light carbon was also found in Proterozoic mafic dykes cross-cutting the metasedimentary units in the ISB. The occurrence of isotopically light, reduced carbon in biologically irrelevant dykes may indicate secondary graphite

  11. Determining the stress of rock massif

    OpenAIRE

    2014-01-01

    Defining the stress rock massif is essential for design of underground facilities and methods of mining in the mines. Assessment the value of stress state of rock massif and rock strength in the various loads allows rational design. This is of particular importance when sizing columns, determining the extent of excavation, the cross-sections of underground rooms in problems with rock bursts and others. This paper briefly gives the basic methods of determining the rock massif stress as part of...

  12. Carbon isotope anomalies in carbonates of the Karelian series

    Science.gov (United States)

    Iudovich, Ia. E.; Makarikhin, V. V.; Medvedev, P. V.; Sukhanov, N. V.

    1990-07-01

    Results are presented on carbon isotope distributions in carbonates of the Karelian complex. A highly anomalous isotopic composition was found in carbonate rocks aged from 2.6 to 1.9 b.y. In the stromatolitic carbonates of the Onega water table, delta-(C-13) reaches a value of +18 percent, while the shungite layer of the Zaonega horizon is characterized by a wide dispersion (from +7.9 to -11.8 percent). These data are in good agreement with the known geochemical boundary (about 2.2 b.y. ago) in the history of the earth.

  13. Ellipsoidal anisotropy in elasticity for rocks and rock masses

    CERN Document Server

    Pouya, Ahmad

    2011-01-01

    One of the interesting features with the ellipsoidal models of anisotropy presented in this paper is their acceptance of analytical solutions for some of the basic elasticity problems. It was shown by Pouya (2000) and Pouya and Zaoui (2006) that many closed-form solutions for basic problems involving linear isotropic materials could be extended by linear transformation to cover a variety of "ellipsoidal" materials. This paper will describe two main varieties of ellipsoidal elastic models and show how well they fit the in situ data for sedimentary rocks; numerical homogenization results for several varieties of fractured rock masses will also be provided.

  14. Sedimentary environments of organic matter from Middle Permian source rocks in northern Xinjiang,China

    Institute of Scientific and Technical Information of China (English)

    MIAO Jianyu; KOU Hansheng; ZHOU Lifa; HAN Zhongyuan

    2006-01-01

    A systematic analysis of the inorganic and organic geochemistry of Middle Permian source rocks comprising carbonate rocks and mudstones was carried out, with samples collected from the outcrop and bore of the Junggar, Turpan and Ili basins in northern Xinjiang. This study confirmed that sedimentary parameters for an ancient water body, such as inorganic geochemistry and paleosalinity, have a close relation to the organic matter of source rocks. It is also disclosed that phytane predominance in the source rocks is mainly due to a reducing environment. Biomarkers, such as gammacerane and β-carotene, in the samples reflect a specific salinity in the sedimentary environments. Sedimentary zones with a strong reducing environment are more likely to produce deposits of primary organic matter, which will be buried and preserved contemporarily. Consequently, the source rocks are generally high in organic content and better in organic type than ordinary ones, and vice versa.

  15. Effects of changes in rock microstructures on permeability: 3-D printing investigation

    Science.gov (United States)

    Head, D.; Vanorio, T.

    2016-07-01

    Rocks are naturally heterogeneous; two rock samples with identical bulk properties can vary widely in microstructure. Understanding how the microstructure and bulk properties of rocks then evolve during experiments and computations simulating diagenesis is inherently a multiscale problem. The advent of modern 3-D printing has provided an unprecedented opportunity to link those scales by combining the strengths of digital and experimental rock physics. In this study, we take a computerized tomography-scanned model of a natural carbonate pore space then iteratively digitally manipulate, 3-D print, and measure the flow properties in the laboratory. This approach allows us to access multiple scales digitally and experimentally and test hypotheses about how changes in rock microstructure due to compaction and dissolution affect bulk transport properties in a repeatable manner.

  16. Geochemical characteristics of the oceanic island- type volcanic rocks in the Chiang Mai zone, northern Thailand

    Institute of Scientific and Technical Information of China (English)

    SHEN Shangyue; FENG Qinglai; ZHANG Zhibin; CHONGPAN Chonglakmani

    2009-01-01

    The oceanic island volcanic rocks in the Chiang Mai zone, northern Thailand, are usually covered by Lower Carboniferous and Upper Permian shallow-water carbonate rocks, with the Hawaii rocks and potash trachybasalt being the main rock types. The alkaline series is dominant with sub-alkaline series occurring in few cases. The geochemical characteristics are described as follows: the major chemical compositions are characterized by high TiO2, high P2O5 and medium K2O; the rare-earth elements are characterized by right-inclined strong LREE-enrichment patterns; the trace element patterns are of the upward-bulging K-Ti enrichment type; multi-component plots falling within the fields of oceanic island basalts and alkali basalts, belonging to the oceanic island-type volcanic rocks, which are similar to the equivalents in Deqin and Gengma (the Changning-Menglian zone) of Yunnan Province, China.

  17. Thermal recovery of bitumen from carbonate reservoirs: formation damage aspects

    Energy Technology Data Exchange (ETDEWEB)

    Thimm, H.F. [Thimm Petroleum Technologies Inc. (Canada)

    2011-07-01

    In Alberta, about a third of bitumen resources are located in carbonate reservoirs but none of it is considered as a reserve by the Alberta Energy Resources Conservation Board (ERCB). In fact no pilot has been successful in recovering bitumen from carbonate reservoirs due to formation damage problems. Carbonate rock is chemically active at the high temperatures reached in thermal recovery processes, carbon dioxide is generated and carbonate minerals are precipitated. The aim of this paper is to find methods to control the phenomenon. Kinetic and thermodynamic controls were used. Results showed that formation damage is due to aqueous carbon dioxide attacking the reservoir rock. They found that a reduction of the partial pressure of carbon dioxide could inhibit the initial dissolution of rock material by reducing the concentration of aqueous carbon dioxide. A method to overcome the formation damage problem was found and a co-injection of gas and steam process was developed to apply it.

  18. Hot dry rock geothermal energy

    Science.gov (United States)

    Heiken, G.; Murphy, H.; Nunz, G.; Potter, R.

    1981-08-01

    Man-made geothermal systems are discussed which make it possible to extract heat from hot rocks in areas where natural fluids are insufficient for the development of hydrothermal energy. The location and magnitude of high- and low-temperature geothermal resources in the USA for such hot dry rock (HDR) systems are examined. An HDR concept is described in which water is injected into one of two nearly parallel wells connected at depth by man-made fractures; the injected water circulates through the fracture system, where it is heated by conduction from the hot rock, and hot fluid, which can be used for heating or for electric power generation, rises through the second well. Some heat-extraction experiments using the described concept are reviewed which are being conducted in a complex volcanic field in New Mexico. The economics of HDR energy is evaluated.

  19. Attachable rock bolters for roadheaders

    Energy Technology Data Exchange (ETDEWEB)

    Weibezahn, K. [Wirth Maschinen- und Bohrgeraete-Fabrik GmbH, Erkelenz (Germany); West, M. [Deilmann-Haniel Mining Systems GmbH (Germany)

    2004-07-01

    Roadheaders are used in mining and tunnelling in medium hard rock formations. The excavated space is made safe either by NATM-technology or a steel support system. The application of a rock bolting system up to now was restricted to formations that can cope with at least some support lag. A new system was developed in close cooperation between WIRTH Maschinen- und Bohrgeraetefabrik GmbH and deilmann-haniel mining systems gmbh that allows to carry out rock bolting with two drill rigs whicht are attached to the cutting boom of the roadheader even in front of the cutter head directly after cutting. Alternatively a robot may be attached to above named system that enables remotely controlled shot-creting close to the face.

  20. Dovyrenite Ca6Zr[Si2O7]2(OH)4 - A New Mineral from Skarned Carbonate Xenoliths in Basic-Ultrabasic Rocks of the Ioko-Dovyren Massif, Northern Baikal Region, Russia

    Science.gov (United States)

    Galuskin, Evgeny V.; Pertsev, Nikolai N.; Armbruster, Thomas; Kadiyski, Milen; Zadov, Aleksander E.; Galuskina, Irina O.; Dzierżanowski, Piotr; Wrzalik, Roman; Kislov, Evgeny V.

    2007-01-01

    Dovyrenite, simplified formula Ca6Zr[Si2O7]2(OH)4, occurs as an accessory mineral in vein skarns developed in carbonate xenoliths in subvolcanic layered plagiodunite-troctolite series in the Ioko-Dovyren Massif of Proterozoic age, Northern Baikal Region, Buryatia, Russia. Dovyrenite is a late mineral of altered pyroxene and melilite-monticellite skarns. Associated minerals are Zr-bearing phases: fassaitic pyroxene, perovskite and hydrogarnets; and also monticellite, vesuvianite, diopside, foshagite, brucite, calzirtite, tazheranite, baghdadite, apatite, calcite, native bismuth, sphalerite, selenian galena, clausthalite, safflorite, rammelsbergite, pyrrhotite, pentlandite, valleriite, laitakarite, nickeline, nickel-skutterudite. The average structure of dovyrenite is orthorhombic, space group Pnnm, with subcell parameters A = 5.666(16) Å, B = 18.844(5) Å, C = 3.728(11) Å, V = 398.0(2) Å3 and Z = 1. Dovyrenite shows a new type of modular structure with stacking of the tobermorite-like and the rosenbuschite-like layers parallel to (010). Single-crystal structural data point to an incompletely occupied Ca(2) site from the rosenbuschite module which is confirmed by microprobe analyses: ZrO2 16.47, SiO2 32.83, TiO2 0.14, HfO2 0.16, Cr2O3 0.01, CaO 43.87, FeO 0.25, MgO 0.13, MnO 0.02, Nb2O3 0.03; total 99.38 wt% with calculated H2O. The empirical formula is (Ca5.73Fe0.03Mg0.02)σ5.78(Zr0.98Hf0.01Ti0.01)σ1Si4(O13.56OH0.44)σ14(OH)4. The presence of two types of OH group in the dovyrenite structure is corroborated by FTIR and Raman spectroscopy. Dovyrenite is an optically positive biaxial mineral: α 1.659(2), β 1.660(2); γ 1.676(2); 2Vz 30(5)° (measured), 28° (calculated). The coexistence of monticellite, foshagite and dovyrenite points to a narrow interval of crystallization 560-630°C under subvolcanic conditions (P < 108 Pa).

  1. 不同水流速度下温度对奥陶系碳酸盐岩溶蚀速度的影响%Influence of temperature on dissolution rate in Ordovician carbonate rock in different water flow rate

    Institute of Scientific and Technical Information of China (English)

    邵东梅

    2012-01-01

    In order to understand the influence of temperature on dissolution rate in Ordovician carbonate brock in different water flow rate, dissolution experiment was conducted at different temperature, different water flow rate and different CO2 pressure with self-designed and manufactured dissolution device which can simulates water flow conditions and contains 24 samples as platform, samples collected from Zhangji mine in Huainan, Zhangcun mine in Luan and Dongtan mine in Yanzhou were used as representative samples. The experiment results show that when water flow rate is relatively low(16.67 mL/min), the influence of environmental temperature change on dissolution rate is insignificant(the average dissolution volume is 0.0006g/cm2), when the water flow rate is high (60mL/min), the influence of temperature change on dissolution rate is significant (the average dissolution volume is 0.003 8g/cm2). That is to say, in strong run-off zone of ground water, the influence of temperature on dissolution rate is bigger and the dissolution rate is higher, so fcarst is developed.%为了解不同水流速度下温度对碳酸盐岩溶蚀速度的影响,以自行设计、制造的能够模拟水流条件,并且可同时容纳24个样品的溶蚀试验装置为平台,以淮南张集矿、潞安漳村矿和兖州东滩矿奥陶系灰岩为代表性岩石试样,选取不同温度、水流速度及CO2压力,进行了溶蚀试验.试验结果显示,在水流速度较低时(16.67 mL/min),环境温度的变化对溶蚀速度的影响比较微小(平均溶蚀变化量为0.0006 g/cm2).在水流速度较大时(60 mL/min),温度的改变对溶蚀速度影响较大(平均溶蚀变化量为0.0038g/cm2).也就是说在地下水的强径流带,温度对溶蚀速度的影响相对较大,溶蚀速度较快,所以岩溶较发育.

  2. 羌塘盆地双湖地区曲色组冷泉碳酸盐岩及其地质意义%Characteristics and significance of the cold-vent carbonate rocks from the Quse Formation in the Shuanghu area, Qiangtang Basin, northern Xizang

    Institute of Scientific and Technical Information of China (English)

    夏国清; 伊海生

    2015-01-01

    The carbonate concretions occur in large numbers in the Quse Formation, Shuanghu area, Qiangtang Basin, northern Xizang, and display hummocky, ellipsoidal, lenticular, stratoid, vein, dendritic, clotted, vesicular and seepage textures and structures. These nodules consist dominantly of micritic carbonate minerals with minor amount of clay minerals, quartz, framboidal and subhedral pyrite with an average grain size of about 5. 0μm,in which the sun-flower structures may be observed. The organic fossils such as bivalves, ammonites, worm-like or dendritic fossils and ultra-microbial fossils are found to be arranged with a higher density. The carbon isotopes in the analyzed samples are noticeably negative excursion while the sulfur isotopes in the analyzed samples exhibit a markedly distinct positive excursion. The results of research outlined above are in good agreement with the mechanisms for the formation of the cold-vent carbonate rocks produced by the seepage and release of the modern submarine natural gas. It is inferred from this reason that the carbonate concretions in the study area may be originated from the seepage and eruption of ancient natural gas. The presence of numerous submarine natural gas vents implies that there is a direct correlation between the oceanic anoxic events and the eruption of the submarine natural gas hydrates in the Shuanghu area, Qiangtang Basin during the Early Jurassic.%羌塘盆地南部双湖地区曲色组地层发育大量碳酸盐岩结核,这些结核多呈丘状、椭球状、透镜状、似层状、脉状、树枝状产出。其物质组分主要为泥微晶碳酸盐矿物,少量粘土矿物、石英及草莓状、半自形黄铁矿等。草莓状黄铁矿平均粒径在5.0μm左右,内部可见葵花状构造。发育凝块状、气孔状和渗漏孔等特殊构造。产双壳类、菊石类、蠕虫状或树枝状生物及超微生物化石,生物密度极高。碳同位素明显负偏,硫同位素则明显正

  3. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140786Deng Zhenping(Institute of Karst Geology,Chinese Academy of Geological Sciences,Guilin 541004,China);Yang Wen-qiong Application of Stripping Voltammetry with a Solid Amalgam Electrode for Determination of Copper in a Tracer and Groundwater Tracing Experiment(Rock and Mineral Analy-

  4. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20041935 Chen Bailin (China University of Geosciences, Beijing);Shu Bin X-Ray Analysis of Deformed Rocks from Beishan Area, Gansu Province, China (Journal of Jilin University (Earth Science Edition ), ISSN 1671-5888 CN22-1343/P, 33(4), 2003, p. 424-429, 442, 2 illus. , 3 tables, 13 refs. )

  5. Los abuelos de nuestro rock

    Directory of Open Access Journals (Sweden)

    Jacobo Celnik

    2016-12-01

    Full Text Available Los Yetis. Una bomba atómica a go go. La historia de los abuelos de nuestro rock. Diego Londoño; Pulso & Letra Editores, Instituto para el Desarrollo de Antioquia, Instituto de Cultura y Patrimonio de Antioquia, 2014, 98 págs., fotografías.

  6. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131550 Bai Jinfeng(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang 065000,China);Bo Wei Determination of 36Elements in Geochemical Samples by High Resolution Inductively Coupled Plasma-Mass Spectrometry(Rock and Mineral Analysis,ISSN0254-5357,CN11-2131/TD,31(5),2012,p.814

  7. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    <正>20050704 Cheng Lin (Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039, China); Feng Songlin Analysis of Colored Elements in Ancient Colored Glaze by SRXRF (Rock and Mineral Analysis, ISSN0254-5357, CN11 -2131/TD, 23 (2), 2004, p. 113-116, 120, 3 illus. , 3 tables, 6 refs. )

  8. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20142093Chen Daohua(Guangzhou Marine Geological Survey,Guangzhou 510075,China);Diao Shaobo The Latest Progress of Geological Marine Testing Technology in China(Rock and Mineral Analysis,ISSN0254-5357,CN11-2131/TD,32(6),2013,p.850-859,105refs.)Key words:chemical analysis,China

  9. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20070252 Chen Meilan (Biological and Environmental College, Zhejiang Shuren University, Hangzhou 310015, China); Li Li Study on Adsorption of Phenol by Modified Organobentonite (Rock and Mineral Analysis, ISSN0254-5357, CN11-2131/TD, 24(4), 2005, p.259-261, 267, 6 illus., 1 table, 11 refs.) Key words: bentonite, benzene, adsorption

  10. Inelastic deformation in crystalline rocks

    Science.gov (United States)

    Rahmani, H.; Borja, R. I.

    2011-12-01

    The elasto-plastic behavior of crystalline rocks, such as evaporites, igneous rocks, or metamorphic rocks, is highly dependent on the behavior of their individual crystals. Previous studies indicate that crystal plasticity can be one of the dominant micro mechanisms in the plastic deformation of crystal aggregates. Deformation bands and pore collapse are examples of plastic deformation in crystalline rocks. In these cases twinning within the grains illustrate plastic deformation of crystal lattice. Crystal plasticity is governed by the plastic deformation along potential slip systems of crystals. Linear dependency of the crystal slip systems causes singularity in the system of equations solving for the plastic slip of each slip system. As a result, taking the micro-structure properties into account, while studying the overall behavior of crystalline materials, is quite challenging. To model the plastic deformation of single crystals we use the so called `ultimate algorithm' by Borja and Wren (1993) implemented in a 3D finite element framework to solve boundary value problems. The major advantage of this model is that it avoids the singularity problem by solving for the plastic slip explicitly in sub steps over which the stress strain relationship is linear. Comparing the results of the examples to available models such as Von Mises we show the significance of considering the micro-structure of crystals in modeling the overall elasto-plastic deformation of crystal aggregates.

  11. Comparative analysis of cyanobacteria inhabiting rocks with different light transmittance in the Mojave Desert: a Mars terrestrial analogue

    Science.gov (United States)

    Smith, Heather D.; Baqué, Mickael; Duncan, Andrew G.; Lloyd, Christopher R.; McKay, Christopher P.; Billi, Daniela

    2014-05-01

    The Mojave Desert has been long considered a suitable terrestrial analogue to Mars in many geological and astrobiological aspects. The Silver Lake region in the Mojave Desert hosts several different rock types (talc, marble, quartz, white carbonate and red-coated carbonate) colonized by hypoliths within a few kilometres. This provides an opportunity to investigate the effect of rock type on hypolithic colonization in a given environment. Transmission measurements from 300 to 800 nm showed that the transmission of blue and UVA varied between rock types. The wavelength at which the transmission fell to 1% of the transmission at 600 nm was 475 nm for white carbonate and quartz, 425 nm for red-coated carbonate and talc and 380 nm for marble. The comparative analysis of the cyanobacterial component of hypoliths under different rocks, as revealed by sequencing 16S rRNA gene clone libraries, showed no significant variation with rock type; hypoliths were dominated by phylotypes of the genus Chroococcidiopsis, although less abundant phylotypes of the genus Loriellopsis, Leptolyngbya and Scytonema occurred. The comparison of the confocal laser scanning microscopy-λ (CLSM-λ) scan analysis of the spectral emission of the photosynthetic pigments of Chroococcidiopsis in different rocks with the spectrum of isolated Chroococcidiopsis sp. 029, revealed a 10 nm red shift in the emission fingerprinting for quartz and carbonate and a 5 nm red shift for talc samples. This result reflects the versatility of Chroococcidiopsis in inhabiting dry niches with different light availability for photosynthesis.

  12. Acritarchs in carbonaceous meteorites and terrestrial rocks

    Science.gov (United States)

    Rozanov, Alexei Y.; Hoover, Richard B.

    2013-10-01

    Acritarchs are a group of organic-walled, acid-resistant microfossils of uncertain or unknown origin. Some are thought to represent the cysts or resting stages of unicellular protists (possibly dinoflagellates), chrysophytes (green algae) or other planktonic eukaryotic algae. Acritarchs are found throughout the geologic column extending back as far at 3.2 Ga. The presence of large sphaeromorphs in the Archaean provides evidence that the eukaryotic lineage extends much farther back in time than previously thought possible. Acritarchs are abundant in the Paleoproterozoic shales (1.9-1.6 Ga) of the former Soviet Union and they have been extensively used for the investigation of Proterozoic and Paleozoic biostratigraphy and paleoenvironmental parameters. Scanning Electron Microscope studies have revealed the fossilized remains of organic-walled microfossils of unknown origin and exhibiting characteristics of acritarchs in a variety of carbonaceous meteorites. In many cases, these remains are black or brown in color and have Carbon/Oxygen ratios suggesting they have been diagenetically converted into kerogen. It is not feasible that the fossilized remains of organicwalled microfossils such as acritarchs represent biological contaminant that invaded and became embedded in the rock matrix of carbonaceous meteorites within the short time periods of their residence on Earth. Consequently, these groups of microfossils are considered to provide an additional line for the existence of indigenous extraterrestrial microbial remains in meteorites. This paper presents a brief review of acritarchs in terrestrial rocks and provides images of a number of similar morphotypes of uncertain origin found in freshly fractured samples of carbonaceous meteorites.

  13. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20080934 Cai Yuman(Geological Survey of Jiangsu Province,Nanjing 210018,China);Lu Lijuan Determination of Carbonate(Anhydride Carbonate)in Natural Gypsum by Acid-Base Titration(Jiangsu Geology,ISSN1003-6474,CN32-1258/P,31(2),2007,p.127-129,3 illus.,8 refs.)Key words:titration,carbonatesThe authors establish a method of acid-base ti

  14. Determination of ejection velocity of rock fragments during rock burst in consideration of damage

    Institute of Scientific and Technical Information of China (English)

    ZUO Yu-jun; LI Xi-bing; ZHOU Zi-long

    2005-01-01

    The ejection velocity of rock fragments during rock burst, one of the important indexes representing the rock burst strength, is used most conveniently in the supporting design of tunnel with rock burst tendency and is often determined by means of observation devices. In order to calculate the average ejection velocity of rock fragments theoretically, the energy of rock burst was divided into damage consuming energy and kinetic energy gained by unit volume of rock firstly, and then the rock burst kinetic proportional coefficient η was brought up which could be determined according to the rock-burst damage energy index WD , at last the expression of the average ejection velocity of rock fragments during rock burst was obtained and one deep level underground tunnel was researched using the mentioned method. The results show that the calculation method is valid with or without considering the tectonic stress of tunnels, and that the method can be a reference for supporting design of deep mining.

  15. 熔融制样-X射线荧光光谱法测定碳酸盐岩石中主次量元素及烧失量%Determination of primary and secondary elements in carbonate rocks by fusion sample preparation-XRF and the loss on ignition

    Institute of Scientific and Technical Information of China (English)

    苏丹

    2016-01-01

    碳酸盐岩石的主要成分为碳酸钙、碳酸镁,采用熔融制样—X射线荧光光谱法对其主次量元素进行测定时,最难解决的是烧失量大导致测定结果偏低问题。如果以灼烧后的试样制备试料片,灼烧后的试料极易吸收空气中的水分和二氧化碳,同样会使测定结果偏低,且检测流程繁琐。该文采用试样经烘干后直接熔融制样,采用基本参数法 NBSGSC 得到理论 Alphas 系数,结合烧失量( LOI)计算理论的元素间校正因子,基于浓度的乘法模式对标准曲线进行校正,消除了烧失量对各组分测定的影响;各组分标准曲线的相关系数0.9980~0.9999;测定结果的相对标准偏差RSD(n=11)为0.28%~5.01%;通过仪器设定,自动计算出试样的烧失量,无需再通过化学法进行测定。该检测方法可实现一次熔样,完成10种元素及烧失量同时测定,且分析结果精密度好、准确度高、方法快速简便、大大降低了分析成本,适用于碳酸盐岩石的批量检测。%Carbonate rocks mainly consist of CaCO3 and MgCO3 . When fusion sample preparation-XRF deter-mines main and secondary elements,it is difficult to deal with large loss on ignition that results in lower determination value. If prepared by ignited samples,the specimen is likely to absorb H2 O and CO2 in the air,which will also result in lower determination value besides being a lengthy detection flowsheet. The paper immediately prepared the sample by fusing after the sample was dried,employed NBSGSC to obtain Alphas coefficient,calculated correction factors between elements based on LOI,corrected standard curves based on multiplication patterns of concentration,and finally eradi-cated the influence of LOI on the determination of each element; the correlation coefficient of the standard curve of each composition was 0. 998 0-0. 999 9;the RSD(n=11) of the determination result was 0. 28 % -5. 01 %;LOI was automatically

  16. Greenhouse Gases and Energy Intensity of Granite Rock Mining Operations in Thailand: A Case of Industrial Rock-Construction

    Science.gov (United States)

    Kittipongvises, Suthirat; Chavalparit, Orathai; Sutthirat, Chakkaphan

    2016-12-01

    This paper is aimed to systematically assess greenhouse gases (GHGs) and energy intensity of the granite rock mining operations in Thailand and also identify a range of feasible options to minimize their GHG emissions. Mining factories A, B and C, located in the Eastern region of Thailand, were selected as research case studies. The results indicated that the 3-year average of GHGs emissions from factories A to C was 3387 718 kgCO2e per year with approximately 2.92 kgCO2e per ton of granite rock produced over 2012 to 2014. Of this, the carbon intensity of grid-electricity consumption for the crushed rock production was 1.84 kgCO2/kWh. Diesel fuel combustion for transport activities in the mining factories was the greatest contributor to GHGs emissions (68 %) compared to the purchased electricity and explosion process, with 31 % and 1 %, respectively. In-Pit Crushing and Conveying (IPCC) installation, haul truck payload optimization and management, and reduction in tire rolling resistance have shown potential to reduce carbon emissions accounted for 20 % to 70 %.

  17. Greenhouse Gases and Energy Intensity of Granite Rock Mining Operations in Thailand: A Case of Industrial Rock-Construction

    Directory of Open Access Journals (Sweden)

    Kittipongvises Suthirat

    2016-12-01

    Full Text Available This paper is aimed to systematically assess greenhouse gases (GHGs and energy intensity of the granite rock mining operations in Thailand and also identify a range of feasible options to minimize their GHG emissions. Mining factories A, B and C, located in the Eastern region of Thailand, were selected as research case studies. The results indicated that the 3-year average of GHGs emissions from factories A to C was 3387 718 kgCO2e per year with approximately 2.92 kgCO2e per ton of granite rock produced over 2012 to 2014. Of this, the carbon intensity of grid-electricity consumption for the crushed rock production was 1.84 kgCO2/kWh. Diesel fuel combustion for transport activities in the mining factories was the greatest contributor to GHGs emissions (68 % compared to the purchased electricity and explosion process, with 31 % and 1 %, respectively. In-Pit Crushing and Conveying (IPCC installation, haul truck payload optimization and management, and reduction in tire rolling resistance have shown potential to reduce carbon emissions accounted for 20 % to 70 %.

  18. Are there rocks from the Brezovské Karpaty Mts. suitable for construction and decoration purposes?

    Directory of Open Access Journals (Sweden)

    Rudolf Holzer

    2014-06-01

    Full Text Available This research has focused on assessing the most important physical and mechanical properties of rocks quarried in the Brezovské Karpaty Mts. Carbonate sandstones and conglomerates of Upper Cretaceous and carbonate sandstone of Neogene sedimentary strata were considered. The sites Chtelnica – Trianova and Chtelnica – Malé Skalky were chosen as appropriate material for monuments and for restoration work. Samples for the assessment of rock properties were taken from abandoned and operated quarries. The tested specimens for laboratory tests in a form of cubes and cylinders were prepared from monoliths and drilled cores were taken from the depth up to 1 m within the rock mass. To broaden the scope of the investigations previous research results from quarries at St. Margarethen (Burgenland, Austria in similar lithological type were also included. Thin sections were made from one of the drill cores from each quarry. The rock quality and durability were assessed through laboratory testing of physical and mechanical properties, including measurements of real and apparent density, porosity, water absorption capacity, uniaxial compressive strength (UCS for both dry and water-saturated rock samples and for samples following repeated freeze-thaw cycles, the coefficient of softening and the coefficient of freezing. All investigated rock samples had different porosities and absorption capacities. They also differed in their UCS values, which varied greatly but mostly belonged to the weak rock category (UCS below 50 MPa. Based on physical and mechanical properties of rocks assessed on a number of tested samples from two investigated sites in Slovakia and one comparable site in Austria, quality assurance of the rock utilization as a decoration/restoration material is presented.

  19. Exercise Desert Rock Letter Orders. Army, Camp Desert Rock, Nevada.

    Science.gov (United States)

    1957-08-01

    WILF.iED J MSGT A19032i3 HJ;,ŕWAY, ELLafGzJN 8FC Xf,37791267 INOZ W, P. 1. PVT2 US52401808 KELLEY, JESSIE J SFC R1� EVaS, LOUIS PFC .,53073109...Ord Co (HAM) Camo Desert Rock, Nevada You will preeeed to Reynolds Funeral Vome, Sigourney, Iowa 0/a 24 AU ist 1957 for apprx fourteen (14) days to

  20. Experimental evaluation of in situ CO2-water-rock reactions during CO2 injection in basaltic rocks: Implications for geological CO2 sequestration

    Science.gov (United States)

    Matter, Juerg M.; Takahashi, Taro; Goldberg, David

    2007-02-01

    Deep aquifers are potential long-term storage sites for anthropogenic CO2 emissions. The retention time and environmental safety of the injected CO2 depend on geologic and physical factors and on the chemical reactions between the CO2, the aquifer water, and the host rocks. The pH buffer capacity of the aquifer water and the acid neutralization potential of the host rocks are important factors for the permanent stabilization of the injected CO2. Mafic rocks, such as basalt, which primarily consists of Ca, Mg silicate minerals, have a high acid neutralization capacity by providing alkaline earth elements that form stable carbonate minerals. The carbonate minerals formed thus sequester CO2 in a chemically stable and environmentally benign form. In this study, we present results from a small-scale CO2 injection test in mafic and metasedimentary rocks. The injection test was conducted using a single-well push-pull test strategy. CO2 saturated water (pH = 3.5) was injected into a hydraulically isolated and permeable aquifer interval to study the acid neutralization capacity of Ca, Mg silicate rocks and to estimate in situ cation release rates. Release rates for Ca, Mg, and Na were calculated by use of solute compositions of water samples retrieved after the CO2 injection, the incubation time of the injected solution within the aquifer, and geometric estimates of the reactive surface area of the host rocks. Our results confirm rapid acid neutralization rates and water-rock reactions sufficient for safe and permanent storage of CO2. Carbonic acid was neutralized within hours of injection into a permeable mafic aquifer by two processes: mixing between the injected solution and the aquifer water, and water-rock reactions. Calculated cation release rates decrease with increasing pH that is confirmed by laboratory-based experiments. Large differences between release rates obtained from the field and laboratory experiments may be mainly due to uncertainties in the estimation

  1. Isotopic and multi-proxy continental records in the Precambrian rocks, Aldan Shield, Russian Federation

    Science.gov (United States)

    Guliy, Vasyl

    2015-04-01

    Clay minerals and hematite from paleo-weathering profiles, observed on and within Precambrian rocks of the apatite deposits, have been investigated from the view-points of geology, mineralogy, pedology. Weathering phenomena have been recognized in the Fedorovskaya and Gorbyliakhskaya Formations of the Precambrian Aldan Shield. Two complexes that differ in rock composition and structure are involved in the geological sections of the deposits. The lower complex (basement) is a stratum (up to 500m) of interlayered gneisses, schists and apatite-bearing carbonate and calc-silicate rocks. The upper complex (up to 200m) is a blanket-like residual deposit intensely crushed and strongly altered formations of the basement. Clay minerals (hydromica, vermiculite, chlorite, illite, and kaolinite) are predominantly developed in the upper complex of the deposits, whereas in the lower complex they occur dissipated as separate crystals and grains or concentrated in layers and nests mainly in the apatite-carbonate rocks. The carbonate rocks are typically medium-grained, massive, mottled or banded, and red-brown in color. Their oxidized character is expressed by high Fe3+/Fe2+ ratio. The banded structure is due to throughgoing bands a few millimeters to several decimeters in thickness. Some of the mottled rocks contain pocket-like isolation and thin beds rich in clay, hematite (after magnetite), and rounded apatite and seem to be of paleo-carstic origin. The isotopic data for the carbonates from coexisting poor and rich in clay minerals bands are similar to those under- and overlaying massive carbonates. It is consistent with the proposed model of simultaneous chemogenic and detrital deposition and intra-formational erosion during weathering processes.

  2. The origin and evolution of terrestrial and Martian rock labyrinths

    Science.gov (United States)

    Brook, G. A.

    1984-01-01

    The morphological characteristics and evolutionary development of rock labyrinths on Earth (in sandstone, volcanics, and carbonates) are compared with those on Mars. On Earth rock labyrinths originate as parallel, an echelon, or intersecting narrow grabens, or develop where fault and joint networks are selectively eroded. Labyrinths frequently contain both downfaulted and erosional elements. Closed labyrinths contain depressions; open labyrinths do not, they are simple part of a fluvial network generally of low order. As closed labyrinths made up of intersecting grabens or made up of connected erosional depressions are extremely common on Mars, the research focussed on an understanding of these labyrinth types. Field investigations were carried out in Canyonlands National Park, Utah, and in the Chirachahua Mountains of Arizona. Martian labyrinths were investigated using Viking orbiter images. In addition, research was undertaken on apparent thermokarst features in Lunae Planum and Chryse Planitia where closed depressions are numerous and resemble atlas topography.

  3. 21 CFR 868.5180 - Rocking bed.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Rocking bed. 868.5180 Section 868.5180 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES ANESTHESIOLOGY DEVICES Therapeutic Devices § 868.5180 Rocking bed. (a) Identification. A rocking bed is a...

  4. Rock Music's Place in the Library.

    Science.gov (United States)

    Politis, John

    1983-01-01

    Discussion of the importance of rock music as an expression of aural culture includes its history, rock music today, and the development of a rock music collection in the library (placement of collection and books which aid in developing a collection of permanent value). Three references are included. (EJS)

  5. Rock Art: Connecting to the Past.

    Science.gov (United States)

    Knipe, Marianne

    2001-01-01

    Presents an activity for fourth-grade students in which they learn about ancient art and create their own authentic-looking rock sculptures with pictograms, or painted images. Explains how the students create their own rocks and then paint a pictograph on the rocks with brown paint. (CMK)

  6. Differentiation and analysis on rock breaking characteristics of TBM disc cutter at different rock temperatures

    Institute of Scientific and Technical Information of China (English)

    谭青; 张桂菊; 夏毅敏; 李建芳

    2015-01-01

    In order to study rock breaking characteristics of tunnel boring machine (TBM) disc cutter at different rock temperatures, thermodynamic rock breaking mathematical model of TBM disc cutter was established on the basis of rock temperature change by using particle flow code theory and the influence law of interaction mechanism between disc cutter and rock was also numerically simulated. Furthermore, by using the linear cutting experiment platform, rock breaking process of TBM disc cutter at different rock temperatures was well verified by the experiments. Finally, rock breaking characteristics of TBM disc cutter were differentiated and analyzed from microscale perspective. The results indicate the follows. 1) When rock temperature increases, the mechanical properties of rock such as hardness, and strength, were greatly reduced, simultaneously the microcracks rapidly grow with the cracks number increasing, which leads to rock breaking load decreasing and improves rock breaking efficiency for TBM disc cutter. 2) The higher the rock temperature, the lower the rock internal stress. The stress distribution rules coincide with the Buzin Neske stress circle rules: the maximum stress value is below the cutting edge region and then gradually decreases radiant around; stress distribution is symmetrical and the total stress of rock becomes smaller. 3) The higher the rock temperature is, the more the numbers of micro, tensile and shear cracks produced are by rock as well as the easier the rock intrusion, along with shear failure mode mainly showing. 4) With rock temperature increasing, the resistance intrusive coefficients of rock and intrusion power decrease obviously, so the specific energy consumption that TBM disc cutter achieves leaping broken also decreases subsequently. 5) The acoustic emission frequency remarkably increases along with the temperature increasing, which improves the rock breaking efficiency.

  7. Mechanism of Rock Burst Occurrence in Specially Thick Coal Seam with Rock Parting

    Science.gov (United States)

    Wang, Jian-chao; Jiang, Fu-xing; Meng, Xiang-jun; Wang, Xu-you; Zhu, Si-tao; Feng, Yu

    2016-05-01

    Specially thick coal seam with complex construction, such as rock parting and alternative soft and hard coal, is called specially thick coal seam with rock parting (STCSRP), which easily leads to rock burst during mining. Based on the stress distribution of rock parting zone, this study investigated the mechanism, engineering discriminant conditions, prevention methods, and risk evaluation method of rock burst occurrence in STCSRP through setting up a mechanical model. The main conclusions of this study are as follows. (1) When the mining face moves closer to the rock parting zone, the original non-uniform stress of the rock parting zone and the advancing stress of the mining face are combined to intensify gradually the shearing action of coal near the mining face. When the shearing action reaches a certain degree, rock burst easily occurs near the mining face. (2) Rock burst occurrence in STCSRP is positively associated with mining depth, advancing stress concentration factor of the mining face, thickness of rock parting, bursting liability of coal, thickness ratio of rock parting to coal seam, and difference of elastic modulus between rock parting and coal, whereas negatively associated with shear strength. (3) Technologies of large-diameter drilling, coal seam water injection, and deep hole blasting can reduce advancing stress concentration factor, thickness of rock parting, and difference of elastic modulus between rock parting and coal to lower the risk of rock burst in STCSRP. (4) The research result was applied to evaluate and control the risk of rock burst occurrence in STCSRP.

  8. Process-response theory and its application to the Lacustrine carbonate rocks:A case study of the Es4 in the mid-northern part of the western sag of Liaohe depression%过程响应理论及其在湖相碳酸盐岩中的应用--以辽河西部凹陷中北部地区Es4为例

    Institute of Scientific and Technical Information of China (English)

    王青春; 贺萍; 王对兴; 危宇宁; 武新民

    2016-01-01

    As a new method of basin sedimentological research, the process-response theory is based on the earth system science. This kind of method is composed of process research and response research. The controlling role of the basin evolution in the sedimentary process is emphasized in this theory. The process-response theory was successfully applied to the study of lacustrine carbonate rocks in the 4th member of Shahejie Formation (Es4) within the mid-northern part of the western sag of Liaohe depression. The results show that the formation and distribution of lacustrine carbonate rocks are obviously controlled by basin evolution process in time and space. Based on the study of the Es4 in the mid-northern part of the western sag of Liaohe depression, the authors hold that the sedimentary environment of lacustrine carbonate rocks has three key points. The first one is the suitable topography and hydrodynamic conditions. The second one is the favorable climate and water media, and the last one is the rich provenance supply and the dolomitic conditions. The application of the process-response theory, together with the research on the three key points and the comprehensive sedimentary model of lacustrine carbonate rocks, constitutes the basis for establishing the composite sedimentary model with more reference and guidance value.%提过程响应理论是在地球系统科学基础上提出的一种盆地沉积学研究方法,主要包括过程研究和响应研究两个方面,强调盆地演化过程对其沉积过程的控制意义。论文运用过程响应理论对辽河坳陷西部凹陷中北部地区Es4碳酸盐岩进行了研究,取得了很好的效果。研究表明,湖相碳酸盐岩的形成和分布在时间和空间上受湖盆演化过程控制明显,有利的地形和水动力条件、有利的气候和水介质条件、有利的物源和白云岩化条件,这三个关键要素,共同铸就了辽河坳陷西部凹陷中北部地区Es4湖相碳

  9. ESR dating of fault rocks

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Hee Kwon [Kangwon National Univ., Chuncheon (Korea, Republic of)

    2002-03-15

    Past movement on faults can be dated by measurement of the intensity of ESR signals in quartz. These signals are reset by local lattice deformation and local frictional heating on grain contacts at the time of fault movement. The ESR signals then trow back as a result of bombardment by ionizing radiation from surrounding rocks. The age is obtained from the ratio of the equivalent dose, needed to produce the observed signal, to the dose rate. Fine grains are more completely reset during faulting, and a plot of age vs grain size shows a plateau for grains below critical size : these grains are presumed to have been completely zeroed by the last fault activity. We carried out ESR dating of fault rocks collected from the Yangsan fault system. ESR dates from the this fault system range from 870 to 240 ka. Results of this research suggest that long-term cyclic fault activity continued into the pleistocene.

  10. Methods of rock burst prediction

    Energy Technology Data Exchange (ETDEWEB)

    Genkin, V.A.; Minin, Yu.Ya.; Morozov, G.D.; Proskuryakov, V.M.; Cmirnov, V.A.

    1979-07-01

    Some methods of predicting rock bursts in underground coal and iron ore mines are evaluated: using BP-18 indenters and the MGD indenter with automatic recording; seismic method consisting in measuring the speed of shock waves travelling through various layers (apparatus SB-20 is designed for use in coal mines); electrometric method (measuring resistance between two electrodes when electric currents flow through coal and rocks). The design of the AEhSSh-1 measuring instrument, used in the electrometric method in coal mines is also described. Each of the methods is described and mathematical fomulae used as their theoretical basis are presented. The calculating process is explained and brief information on the design and use of the measuring instrument is given. The methods are evaluated from the viewpoint of precision. (In Russian)

  11. Kimberley rock art dating project

    Energy Technology Data Exchange (ETDEWEB)

    Walsh, G.L. [Takarakka Rock Art Research Centre, NT, (Australia); Morwood, M. [New England University, Armidale, NSW, (Australia). Dept of Archaeology and Palaeoanthropology

    1997-12-31

    The art`s additional value, unequalled by traditionally recognised artefacts, is its permanent pictorial documentation presenting a `window` into the otherwise intangible elements of perceptions, vision and mind of pre-historic cultures. Unfortunately it`s potential in establishing Kimberley archaeological `big picture` still remains largely unrecognised. Some of findings of the Kimberley Rock Art Dating Project, using AMS and optical stimulated luminescence (OSL) dating techniques, are outlined. It is estimated that these findings will encourage involvement by a greater diversity of specialist disciplines to tie findings into levels of this art sequence as a primary reference point. The sequence represents a sound basis for selecting specific defined images for targeting detailed studies by a range of dating technique. This effectively removes the undesirable ad hoc sampling of `apparently old paintings`; a process which must unavoidably remain the case with researchers working on most global bodies of rock art.

  12. Origin of lunar feldspathic rocks

    Science.gov (United States)

    Walker, D.; Grove, T. L.; Longhi, J.; Stolper, E. M.; Hays, J. F.

    1973-01-01

    Melting experiments and petrographic studies of lunar feldspathic rocks reveal possible genetic relationships among several compositionally and mineralogically distinct groups of lunar rocks and soil fragments. Dry, low PO2 partial melting of crustal anorthositic norites of the anorthositic-noritic-troctolitic (ANT) suite produces liquids of the KREEP-Fra Mauro basalt type; dry, low PO2 partial melting of pink spinel troctolite (PST) produces liquids of the 'very high alumina basalt' or microtroctolite type. Both ANT and PST are probable components of the primitive terra crust. If crystal fractionation in a cooling basaltic liquid could have produced such a crust, it would also produce a mafic interior capable of yielding mare basalts by later remelting at depth.

  13. Damage Model of Brittle Coal-Rock and Damage Energy Index of Rock Burst

    Institute of Scientific and Technical Information of China (English)

    尹光志; 张东明; 魏作安; 李东伟

    2003-01-01

    Based on the mechanical experiment of brittle coal-rock and the damage mechanical theory, a damage model was established. Coal-Rock damage mechanical characteristic was researched. Furthermore, interior energy transformation mechanism of rock was analyzed from the point of view of damage mechanics and damage energy release rate of brittle coal rock was derived. By analyzing the energy transformation of rock burst, a new conception, damage energy index of rock burst, was put forward. The condition of rock burst was also established.

  14. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20111673 Cao Ban(Zhejiang Institute of Geological & Mineral Resources,Hangzhou 310007,China);Ma Jun Determination of 16 Polycyclic Aromatic Hydrocarbons in Groundwater by High Performance Liquid Chromatography with Fluorescence-Ultraviolet Detector(Rock and Mineral Analysis,ISSN0254-5357,CN11-2131/TD,29(5),2010,p.539-542,2 illus.,4 tables,15 refs.)Key words:liquid chromatography,polycyclic aromatic hydrocarbons,fluorescence analysis

  15. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20070970 Cheng Jian(Center of Analysis and Testing,Hunan Zhuye Torch Metals Co., Ltd.,Zhuzhou 412004,China)Direct Deter- mination of Lead in Refined Indium by Flume Atomic Absorption Spectrometry (Rock and Mineral Analysis,ISSN 0254- 5357,CN11-2131/TD,25(1),2006,p.91 -92,94,1 illus.,7 tables,5 refs.) Key words:lead,atomic absorption

  16. The structures of noncrystalline rocks

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The structural studies of noncrystalline rocks by total radial distribution function (RDF) which was derived from the wide angular X-ray scattering (WAXS) have been reported. In order to make a further study of the structural features shown by RDF, the unsymmetric peaks in total RDF were separated into the approximately symmetric peaks by the multi-peaks separation processing. By analyzing the relationship of the peak parameters with the compositions, the information of further structures has been discussed.

  17. 20020118: Rock (2), panel (14)

    OpenAIRE

    None

    2002-01-01

    Rock Art photograph, unknown [cam element='coordinate' qualifier='longitude']W 70deg34'55.9"[/cam][cam element='coordinate' qualifier='latitude']S 32deg49'49.0"[/cam][cam element='coordinate' qualifier='altitude']924[/cam][cam element='coordinate' qualifier='bearing']60[/cam][cam element='coordinate' qualifier='inclination']75[/cam][cam element='coordinate' qualifier='cartesian'](1.950,1.640,2.190)[/cam

  18. Shock Propagation In Crustal Rock

    Science.gov (United States)

    1991-04-29

    Muscovite dehydroxylation: High-temperature studies, Am. Mineral., 72, 537-550, 1986. Halbach, H., and N. D. Chatterjee, An empirical Redlich - Kwong ...earth and other planetary surfaces as well having application in the study of the Earth’s interior. Granitic rocks are the most common component of...their applicability to muscovite above 1000 K. Thermodynamic functions for H20 were taken from Halbach and Chatterjee [1982]. Gibbs’ free energy

  19. The impact of mechanical properties of rock to the collision of rock piece

    Directory of Open Access Journals (Sweden)

    Borut Macuh

    2007-06-01

    Full Text Available The paper presents the analytical solution of the rock piece motion considering influences of geometrical and mechanical characteristics of rock mass on the arbitrary slope. The main objective of the paper is to determine the motion of the rock piece considering possibility of rock piece failure due to collision. Brief description of the analytical solution of the rock piece motion on a steep slope is given. The laboratory tests were performed to determine uniaxial compressive strength and elastic properties of the considered rock mass. Further, velocities that cause rock piece failure were determined. These maximum velocities indirectly belong to certain mass of rock piece and can be lower than velocities calculated in rock-fall analysis for certain slope geometry. Consequently, the energy magnitude is limited, because at certain velocity and mass of rock piece bigger pieces crash at collision.

  20. ESR dating of fault rocks

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Hee Kwon [Kangwon National Univ., Chuncheon (Korea, Republic of)

    2003-02-15

    Past movement on faults can be dated by measurement of the intensity of ESR signals in quartz. These signals are reset by local lattice deformation and local frictional heating on grain contacts at the time of fault movement. The ESR signals then grow back as a result of bombardment by ionizing radiation from surrounding rocks. The age is obtained from the ratio of the equivalent dose, needed to produce the observed signal, to the dose rate. Fine grains are more completely reset during faulting, and a plot of age vs. grain size shows a plateau for grains below critical size; these grains are presumed to have been completely zeroed by the last fault activity. We carried out ESR dating of fault rocks collected near the Gori nuclear reactor. Most of the ESR signals of fault rocks collected from the basement are saturated. This indicates that the last movement of the faults had occurred before the Quaternary period. However, ESR dates from the Oyong fault zone range from 370 to 310 ka. Results of this research suggest that long-term cyclic fault activity of the Oyong fault zone continued into the Pleistocene.

  1. Committee neural network model for rock permeability prediction

    Science.gov (United States)

    Bagheripour, Parisa

    2014-05-01

    Quantitative formulation between conventional well log data and rock permeability, undoubtedly the most critical parameter of hydrocarbon reservoir, could be a potent tool for solving problems associated with almost all tasks involved in petroleum engineering. The present study proposes a novel approach in charge of the quest for high-accuracy method of permeability prediction. At the first stage, overlapping of conventional well log data (inputs) was eliminated by means of principal component analysis (PCA). Subsequently, rock permeability was predicted from extracted PCs using multi-layer perceptron (MLP), radial basis function (RBF), and generalized regression neural network (GRNN). Eventually, a committee neural network (CNN) was constructed by virtue of genetic algorithm (GA) to enhance the precision of ultimate permeability prediction. The values of rock permeability, derived from the MPL, RBF, and GRNN models, were used as inputs of CNN. The proposed CNN combines results of different ANNs to reap beneficial advantages of all models and consequently producing more accurate estimations. The GA, embedded in the structure of the CNN assigns a weight factor to each ANN which shows relative involvement of each ANN in overall prediction of rock permeability from PCs of conventional well logs. The proposed methodology was applied in Kangan and Dalan Formations, which are the major carbonate reservoir rocks of South Pars Gas Field-Iran. A group of 350 data points was used to establish the CNN model, and a group of 245 data points was employed to assess the reliability of constructed CNN model. Results showed that the CNN method performed better than individual intelligent systems performing alone.

  2. The physical principles of rock magnetism

    CERN Document Server

    Stacey, Frank

    1974-01-01

    Developments in Solid Earth Geophysics 5: The Physical Principles of Rock Magnetism explores the physical principles of rock magnetism, with emphasis on the properties of finely divided magnetic materials. It discusses the origin and stability of rock magnetizations, the role of remanent magnetism in interpreting magnetic surveys, magnetic anisotropy as an indicator of rock fabric, and the relationship between piezomagnetic changes and seismic activity. Organized into 13 chapters, this volume discusses the properties of solids, magnetite and hematite grains, and rocks with magnetite grains

  3. A Review on the British Rock Music

    OpenAIRE

    Hutapea, Alfian Hadi Pranata

    2011-01-01

    Music has an important role in people’s life. In people’s daily, music is often hearing of course and in people’s customs and traditions music is also be used. Music has many genres, one of them is rock music. Many people like rock music especially youngman because rock music has given a message in a song through enthusiasm expression. Rock music has many subgenres and each of subgenres have a distinctive feature. The developing of rock music is very wide in the world, especially in Great Bri...

  4. Depositional environment and organic geochemistry of the Upper Permian Ravenfjeld Formation source rock in East Greenland

    Energy Technology Data Exchange (ETDEWEB)

    Christiansen, F.G.; Piasecki, S.; Stemmerik, L. (Geologoical Survey of Greenland, Copenhagen (Denmark)); Telnaes, N. (Norsk Hydro Research Center, Bergen (Norway))

    1993-09-01

    The Upper Permian Ravnefjeld Formation in East Greenland is composed of shales that laterally pass into carbonate buildups and platforms of the Wegener Halvo Formation. The Ravnefjeld Formation is subdivided into five units that can be traced throughout the Upper Permian depositional basin. Two of the units are laminated and organic rich and were deposited under anoxic conditions. They are considered good to excellent source rocks for liquid hydrocarbons with initial average TOC (total organic carbon) values between 4 and 5% and HI (hydrogen index) between 300 and 400. The cumulative source rocks are separated and enclosed by three units of bioturbated siltstone with a TOC of less than 0.5% and an HI of less than 100. These siltstones were deposited under relatively oxic conditions. The organic geochemistry of the source rocks is typical for marine source rocks with some features normally associated with carbonate/evaporite environments [low Pr/Ph (pristane/phytane), low CPI (carbon preference index), distribution of tricyclic and pentacyclic terpanes]. The establishment of anoxic conditions and subsequent source rock deposition was controlled by eustatic sea level changes. The subenvironment (paleogeographic setting, influx of carbonate material, water depth, salinity) has some influence on a number of bulk parameters [TOC-HI relations, TOC-TS (total sulfur) relations] and, in particular, biomarker parameters such as Pr/Ph and terpane ratios. All the basal shales or shales in the vicinity of carbonate buildups of platforms are characterized by low Pr/Ph, high C[sub 23] tricyclic terpanes, and high C[sub 35] and C[sub 33] hopanes. 52 refs., 20 figs., 3 tabs.

  5. Petrology of unshocked crystalline rocks and shock effects in lunar rocks and minerals

    Science.gov (United States)

    Chao, E.C.T.; James, O.B.; Minkin, J.A.; Boreman, J.A.; Jackson, E.D.; Raleigh, C.B.

    1970-01-01

    On the basis of rock modes, textures, and mineralogy, unshocked crystalline rocks are classified into a dominant ilmenite-rich suite (subdivided into intersertal, ophitic, and hornfels types) and a subordinate feldspar-rich suite (subdivided into poikilitic and granular types). Weakly to moderately shocked rocks show high strain-rate deformation and solid-state transformation of minerals to glasses; intensely shocked rocks are converted to rock glasses. Data on an unknown calcium-bearing iron metasilicate are presented.

  6. Rock bending creep and disturbance effects

    Institute of Scientific and Technical Information of China (English)

    付志亮; 郑颖人; 刘元雪

    2008-01-01

    The bending creep and its disturbance effects of red sandstone rock beam and oil shale rock beam were studied by adopting the self-developed gravitation level style rock creep test machine and bending creep test system,and the constitutive equations were established.It is found that fracture morphology of rock beams under no disturbance load is regular,cracking position of fractures is on part of loading concentration,the crack starts from a neutral plane.However,fracture morphology of rock beams under disturbance load is irregular,cracking position of fractures deviates from a neutral plane.Delayed instability of rock beam occurs for some time under constant disturbance load.When disturbance load is beyond a certain range,suddenly instability of occurs rock beam in a certain time.The results show that there is a guiding significance for creep stability in the geotechnical engineering fields.

  7. Earthquake resistant design of rock oil tanks

    Energy Technology Data Exchange (ETDEWEB)

    Hamada, M.; Iwano, M.; Izumi, H.; Shiba, Y.; Sugihara, Y.

    1983-01-01

    In order to establish a rational procedure of the earthquake resistant design of large rock caverns, such as oil storage tanks on nuclear power plants, experimental and numerical studies were conducted. Dynamic strains during earthquakes were observed on the lining of a railway tunnel constructed in a hard rock mountain, while the seismic motion in the surrounding rock was examined precisely. The observation clarified that the lining strain of the tunnel was linearly and statically related to the rock strain and the ratio of the lining strain to the rock strain was dominated by the relative stiffness of the lining and rock. Based on the results of the earthquake observation, numerical models were proposed for the estimation of the dynamic strains of rock caverns. A good agreement between the calculated strains and the observed ones assured the adequacy of the numerical models.

  8. Core-flood experiment for transport of reactive fluids in rocks.

    Science.gov (United States)

    Ott, H; de Kloe, K; van Bakel, M; Vos, F; van Pelt, A; Legerstee, P; Bauer, A; Eide, K; van der Linden, A; Berg, S; Makurat, A

    2012-08-01

    Investigation of the transport of reactive fluids in porous rocks is an intriguing but challenging task and relevant in several areas of science and engineering such as geology, hydrogeology, and petroleum engineering. We designed and constructed an experimental setup to investigate physical and chemical processes caused by the flow of reactive and volatile fluids such as supercritical CO(2) and/or H(2)S in geological formations. Potential applications are geological sequestration of CO(2) in the frame of carbon capture and storage and acid-gas injection for sulfur disposal and/or enhanced oil recovery. The present paper outlines the design criteria and the realization of reactive transport experiments on the laboratory scale. We focus on the spatial and time evolution of rock and fluid composition as a result of chemical rock fluid interaction and the coupling of chemistry and fluid flow in porous rocks.

  9. Metasomatic origin of quartz-pyroxene rock, Akilia, Greenland, and implications for Earth's earliest life.

    Science.gov (United States)

    Fedo, Christopher M; Whitehouse, Martin J

    2002-05-24

    A quartz-pyroxene rock interpreted as a banded iron formation (BIF) from the island of Akilia, southwest Greenland, contains (13)C-depleted graphite that has been claimed as evidence for the oldest (>3850 million years ago) life on Earth. Field relationships on Akilia document multiple intense deformation events that have resulted in parallel transposition of Early Archean rocks and significant boudinage, the tails of which commonly form the banding in the quartz-pyroxene rock. Geochemical data possess distinct characteristics consistent with an ultramafic igneous, not BIF, protolith for this lithology and the adjacent schists. Later metasomatic silica and iron introduction have merely resulted in a rock that superficially resembles a BIF. An ultramafic igneous origin invalidates claims that the carbon isotopic composition of graphite inclusions represents evidence for life at the time of crystallization.

  10. A Simple Hydromechanical Modeling of Carbon Sequestration in Sedimentary Rocks

    CERN Document Server

    Ghaffari, Hamed O

    2009-01-01

    In this study, over different scenarios we will simulate a week coupling of hydromechanical loads in a long term CO2 injection with a hypothetical reservoir while the effect of pore water pressure and then multi-phase flow procedure has been ignored. In the first basic case the homogenous case has been considered when the theory of poroelasticity was employed. Second case covers the effects of directional heterogeneity, constructed by random faults, on the flow paths of gas and other attributes of the system. Also, in the latter case the impact of stress state as an active loads (body loads) has been regarded. Thanks to multiple directional heterogeneity, which induces only one heterogenic parameter (intrinsic permeability), distinguishable flow paths can be recognized. In another process, the failure ability of system regard to Mohr-Columb criterion is measured as well as options that, presumably, the system has continuum faults (zero cohesion). The results over different cases shows absedince of ground surf...

  11. Brittle and semibrittle creep in a low porosity carbonate rock

    Science.gov (United States)

    Nicolas, Aurélien; Fortin, Jérôme; Regnet, Jean-Baptiste; Dimanov, Alexandre; Guéguen, Yves

    2016-04-01

    The mechanical behavior of limestones at room temperature is brittle at low confining pressure and becomes semi-brittle with the increase of the confining pressure. The brittle behavior is characterized by a macroscopic dilatancy due to crack propagation, leading to a stress drop when cracks coalesce at failure. The semi-brittle behavior is characterized by diffuse deformation due to intra-crystalline plasticity (dislocation movements and twinning) and microcracking. The aim of this work is to examine the influence of pore fluid and time on the mechanical behavior. Constant strain rate triaxial deformation experiments and stress-stepping creep experiments were performed on white Tavel limestone (porosity 14.7%). Elastic wave velocity evolutions were recorded during each experiment and inverted to crack densities. Constant strain rate triaxial experiments were performed for confining pressure in the range of 5-90 MPa. For Pc≤55 MPa our results show that the behavior is brittle. In this regime, water-saturation decreases the differential stress at the onset of crack propagation and enhances macroscopic dilatancy. For Pc≥70 MPa, the behavior is semi-brittle. Inelastic compaction is due to intra-crystalline plasticity and micro-cracking. However, in this regime, our results show that water-saturation has no clear effect at the onset of inelastic compaction. Stress stepping creep experiments were performed in a range of confining pressures crossing the brittle-ductile transition. In the brittle regime, the time-dependent axial deformation is coupled with dilatancy and a decrease of elastic wave velocities, which is characteristic of crack propagation and/or nucleation. In the semi-brittle regime, the first steps are inelastic compactant because of plastic pore collapse. But, following stress steps are dilatant because of crack nucleation and/or propagation. However, our results show that the axial strain rate is always controlled by plastic phenomena, until the last step, during which the axial strain rate increases significantly because of crack interactions leading to the macroscopic failure Our results show the complex interplay between confining pressure, pore fluid and strain rate (i.e. time), which has an influence on the micromechanisms of deformation and thus on the macroscopic behavior.

  12. Geochemistry of crude oils, seepage oils and source rocks from Belize and Guatemala

    DEFF Research Database (Denmark)

    Petersen, H.I.; Holland, B.; Nytoft, H.P.;

    2012-01-01

    Mountains fault block in central Belize which separates the Corozal Basin in northern Belize from the Belize Basin to the south. Numerous petroleum seeps have been reported in both of these basins. Small-scale oil production takes place in the Corozal Basin and the North and South Petén Basins....... For this study, samples of crude oil, seepage oil and potential source rocks were collected from both countries and were investigated by organic geochemical analyses and microscopy. The oil samples consisted of non-biodegraded crude oils and slightly to severely biodegraded seepage oils, both of which were...... generated from source rocks with similar thermal maturities. The crude oils were generated from marine carbonate source rocks and could be divided into three groups: Group 1 oils come from the North Petén Basin (Guatemala) and the western part of the Corozal Basin (Belize), and have a typical carbonate...

  13. Distribution, richness, quality, and thermal maturity of source rock units on the North Slope of Alaska

    Science.gov (United States)

    Peters, K.E.; Bird, K.J.; Keller, M.A.; Lillis, P.G.; Magoon, L.B.

    2003-01-01

    Four source rock units on the North Slope were identified, characterized, and mapped to better understand the origin of petroleum in the area: Hue-gamma ray zone (Hue-GRZ), pebble shale unit, Kingak Shale, and Shublik Formation. Rock-Eval pyrolysis, total organic carbon analysis, and well logs were used to map the present-day thickness, organic quantity (TOC), quality (hydrogen index, HI), and thermal maturity (Tmax) of each unit. To map these units, we screened all available geochemical data for wells in the study area and assumed that the top and bottom of the oil window occur at Tmax of ~440° and 470°C, respectively. Based on several assumptions related to carbon mass balance and regional distributions of TOC, the present-day source rock quantity and quality maps were used to determine the extent of fractional conversion of the kerogen to petroleum and to map the original organic richness prior to thermal maturation.

  14. Does carbon dioxide pool or stream in the subsurface?

    CERN Document Server

    Cardoso, Silvana S S

    2014-01-01

    Pools of carbon dioxide are found in natural geological accumulations and in engineered storage in saline aquifers. It has been thought that once this CO2 dissolves in the formation water, making it denser, convection streams would transport it efficiently to depth, but this may not be so. Here, we assess the impact of natural chemical reactions between the dissolved CO2 and the rock formation on the convection streams in the subsurface. We show that, while in carbonate rocks the streaming of dissolved carbon dioxide persists, the chemical interactions in silicate-rich rocks may curb this transport drastically and even inhibit it altogether. New laboratory experiments confirm the curtailing of convection by reaction. Wide and narrow streams of dense carbon-rich water are shut-off gradually as reaction strength increases until all transport of the pooled carbon dioxide occurs by slow molecular diffusion. These results show that the complex fluid dynamic and kinetic interactions between pooled carbon dioxide an...

  15. Thermal Waters in Maguarichi, Chihuahua, Mexico: Influence on Volcanic Rocks Alteration

    Science.gov (United States)

    Mascote, C. R.; Espejel-Garcia, V. V.; Villalobos-Aragon, A.

    2013-05-01

    Piedras de Lumbre, Maguarichi, is located 294 km. to the SW of Chihuahua city, in northern Mexico, in the Sierra Madre Occidental (SMO). The study area is composed of a set of igneous volcanic rocks affected by hydrothermal flows, which apparently run along a fault. Outcrops of hot springs, going out with high pressure, are active all over the year and have no seasonal flow changes. The hydrothermal flows, approximately 20, that reach the surface area at Piedras de Lumbre, are altering the volcanic rocks that surround the hot springs. The study area is highly altered, and evidenced by a variety range of colors in the rock surfaces. The rock samples collected at the region show a crystal growth due to the influence of the salts from the thermal water. The rocks closest to the water openings have a change in its mineralogy, with the mafic minerals, present in andesites, been replaced by carbonates and sulfates, leaving only the clear mineral pseudomorphs. On the crust of the rocks a white layer of material (salts), product of the thermal waters has precipitated. The alteration is perceived only about 5 m. or less around the hot springs. The water, which has high contents of arsenic and sulfates has exerted a strong alteration in rhyolitic and andesitic rocks.

  16. Thermogravimetry-differential thermal analysis coupled with chromatography as a thermal simulation experimental method and its application to gaseous hydrocarbons from different source rocks

    Institute of Scientific and Technical Information of China (English)

    SHI Ji'an; ZHAO Xin; WANG Qi; LIU Quanyou

    2005-01-01

    In this paper a thermogravimetry-differential thermal analysis method coupled with chromatography (TG-DTA-GC) has been adopted to simulate the generation of gaseous hydrocarbons from different hydrocarbon source rocks such as coals, mudstones, and carbonate rocks with different maturities. The temperature programming for thermal simulation experiment is 20℃/min from ambient temperature to 700℃. As viewed from the quantities and composition of generated gaseous hydrocarbons at different temperatures, it is shown that low-mature coal has experienced the strongest exothermic reaction and the highest loss of weight in which the first exothermic peak is relatively low. Low-mature coal samples have stronger capability of generating gaseous hydrocarbons than high-mature samples. The amounts and composition of gaseous hydrocarbons generated are closely related not only to the abundance of organic carbon in source rocks, but also to the type of kerogen in the source rocks, and their thermal maturity. In the present highly mature and over-mature rock samples organic carbon, probably, has already been exhausted, so the production of gaseous hydrocarbons in large amounts is impossible. The contents of heavy components in gaseous hydrocarbons from the source rocks containing type-Ⅰand -Ⅱ kerogens are generally high; those of light components such as methane and ethane in gaseous hydrocarbons from the source rocks with Ⅲ-type kerogens are high as well. In the course of thermal simulation of carbonate rock samples, large amounts of gaseous hydrocarbons were produced in a high temperature range.

  17. Laboratory investigation of novel oil recovery method for carbonate reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Yousef, A.A.; Al-Saleh, S.; Al-Kaabi, A.; Al-Jawfi, M. [Saudi Aramco, Riyadh (Saudi Arabia)

    2010-07-01

    This paper described a core flooding laboratory study conducted using composite rock samples from a carbonate reservoir. The aim of the study was to investigate the impact of salinity and ionic composition on oil, brine and rock interactions. Experimental parameters and procedures were designed to replicate reservoir conditions and current field injection practices. Results of the study demonstrated that alterations in the salinity and ionic composition of injected water can have a significant impact on the wettability of the rock surface. Nuclear magnetic resonance (NMR) studies confirmed that injecting different salinity slugs of seawater in carbonate core samples can cause a significant alteration in the surface charges of the rock, and lead to increased interactions with water molecules. The constant reduction of pressure drop across the composite cores with the injection of different diluted versions of water also provided proof of brine, oil and rock alterations. Results of the study indicated that the driving mechanism for waterflooding recovery processes is wettability alteration, which can be triggered by alterations in carbonate rock surface charges, and improvements in the connectivity between rock pore systems that coexist in carbonate rock samples. 41 refs., 8 tabs., 16 figs.

  18. Investigation of the plasma processability of natural carbon bearing formations

    Science.gov (United States)

    Molchanov, V. P.

    2017-01-01

    In the south of the Russian Far East, a new perspective source of minerals was pioneered, which is the metal-bearing high carbon rocks of the Ruzhinskaya square. The rocks are rich in crystalline graphite, gold, platinum and carbon nanostructures (fullerene, nanotubes and diamond-like carbon). The technique of extraction of ultrapure (99.98%) crystalline graphite from these rocks has been developed using hydrometallugical methods. The obtained graphite was used as a raw material for plasma-chemical tests succeeded in the separation of nanodimensional carbon structures, part of which could be inherited from the natural graphite-bearing rocks. The results of investigation will be used in the development of resource-saving technology of minerals extraction.

  19. Impact of Diagenetic Alterations on the Petrophysical and Multiphase Flow Properties of Carbonate Rocks Using a Reactive Pore Network Modeling Approach Impact des altérations diagénétiques sur les propriétés pétrophysiques et d’écoulement polyphasique de roches carbonates en utilisant une modélisation par l’approche réseau de pores

    Directory of Open Access Journals (Sweden)

    Algive L.

    2012-02-01

    Full Text Available Sedimentary reservoir rocks generally have complex and heterogeneous pore networks that are related to the original depositional rock texture and subsequent diagenetic alterations. Such alterations are in part controlled by the original mineralogy and sedimentological facies, the compaction history, the involved fluids (and rock/fluid interactions, the flow history and the related physico-chemical conditions. During the diagenetic evolution (paragenesis, cycles of alternating dissolution (porosity enhancement and precipitation (porosity destruction caused by changes in chemical and thermodynamic conditions may lead to heterogeneous rock structure at both local and reservoir scale. In the absence of cored plugs to measure the petrophysical properties (i.e. porosity, permeability and formation factor and multiphase flow properties (i.e. capillary pressure, relative permeability and resistivity index, a numerical tool that calculates these properties from pore structure data by predicting its evolution during the diagenetic cycle is of great interest for the petroleum industry and reservoir characterization studies. A Pore Network Model (PNM provides opportunities to study transport phenomena in fundamental ways because detailed information is available at the pore scale. It has been used over the last decades to understand basic phenomena such as capillarity, multiphase flow or coupled phenomena. In particular, this modeling approach is appropriate to study the rock/fluid interactions since the mass exchange at surfaces can be modeled explicitly. It can provide quantitative information both on the effective transport property modifications due to the reactions and on the structure evolution resulting from dissolution/precipitation mechanisms. In the present paper, this approach is used to study the effect of the diagenetic cycle on the petrophysical properties of carbonate rocks. It involves three discrete steps. The first step consists of

  20. Rock burst proneness prediction by acoustic emission test during rock deformation

    Institute of Scientific and Technical Information of China (English)

    张志镇; 高峰; 尚晓吉

    2014-01-01

    Rock burst is a severe disaster in mining and underground engineering, and it is important to predict the rock burst risk for minimizing the loss during the constructing process. The rock burst proneness was connected with the acoustic emission (AE) parameter in this work, which contributes to predicting the rock burst risk using AE technique. Primarily, a rock burst proneness index is proposed, and it just depends on the heterogeneous degree of rock material. Then, the quantificational formula between the value of rock burst proneness index and the accumulative AE counts in rock sample under uniaxial compression with axial strain increases is developed. Finally, three kinds of rock samples, i.e., granite, limestone and sandstone are tested about variation of the accumulative AE counts under uniaxial compression, and the test data are fitted well with the theoretic formula.

  1. Carbon dioxide released from subduction zones by fluid-mediated reactions

    Science.gov (United States)

    Ague, Jay J.; Nicolescu, Stefan

    2014-05-01

    The balance between the subduction of carbonate mineral-bearing rocks into Earth's mantle and the return of CO2 to the atmosphere by volcanic and metamorphic degassing is critical to the carbon cycle. Carbon is thought to be released from subducted rocks mostly by simple devolatilization reactions. However, these reactions will also retain large amounts of carbon within the subducting slab and have difficulty in accounting for the mass of CO2 emitted from volcanic arcs. Carbon release may therefore occur via fluid-induced dissolution of calcium carbonate. Here we use carbonate δ18O and δ13C systematics, combined with analyses of rock and fluid inclusion mineralogy and geochemistry, to investigate the alteration of the exhumed Eocene Cycladic subduction complex on the Syros and Tinos islands, Greece. We find that in marble rocks adjacent to two fluid conduits that were active during subduction, the abundance of calcium carbonate drastically decreases approaching the conduits, whereas silicate minerals increase. Up to 60-90% of the CO2 was released from the rocks--far greater than expected via simple devolatilization reactions. The δ18O of the carbonate minerals is 5-10 lighter than is typical for metamorphosed carbonate rocks, implying that isotopically light oxygen was transported by fluid infiltration from the surroundings. We suggest that fluid-mediated carbonate mineral removal, accompanied by silicate mineral precipitation, provides a mechanism for the release of enormous amounts of CO2 from subduction zones.

  2. Overexpression of ROCK1 and ROCK2 inhibits human laryngeal squamous cell carcinoma.

    Science.gov (United States)

    Zhang, Junbo; He, Xue; Ma, Yueying; Liu, Yanli; Shi, Huaiyin; Guo, Weiwei; Liu, Liangfa

    2015-01-01

    Rho-associated coiled-coil containing protein kinase (ROCK) over-expression has been implicated in the progression of many tumor types. The aim of this study was to explore the roles of ROCK1 and ROCK2 in human laryngeal squamous cell carcinoma (LSCC). ROCK1 and ROCK2 expression levels were examined in 50 cases of human LSCC samples by immunohistochemistry. Effects of ROCK1 and ROCK2 on LSCC cell proliferation and motility were investigated in the presence of the ROCK inhibitor Y-27632. The results showed that ROCK1 expression was positively correlated with tumor size and lymph node metastasis (P ROCK2 positively correlated with tumor size (P ROCK2 by Y-27632 significantly inhibits proliferation, migration, and invasion of LSCC cells. Our data indicate that expression of ROCK1 and ROCK2 are closely associated with tumor growth and lymph node metastasis of LSCC. Thus, these two ROCK isoforms may be useful as molecular makers for LSCC diagnosis and may be useful therapeutic targets as well.

  3. Hot Dry Rock; Geothermal Energy

    Energy Technology Data Exchange (ETDEWEB)

    None

    1990-01-01

    The commercial utilization of geothermal energy forms the basis of the largest renewable energy industry in the world. More than 5000 Mw of electrical power are currently in production from approximately 210 plants and 10 000 Mw thermal are used in direct use processes. The majority of these systems are located in the well defined geothermal generally associated with crustal plate boundaries or hot spots. The essential requirements of high subsurface temperature with huge volumes of exploitable fluids, coupled to environmental and market factors, limit the choice of suitable sites significantly. The Hot Dry Rock (HDR) concept at any depth originally offered a dream of unlimited expansion for the geothermal industry by relaxing the location constraints by drilling deep enough to reach adequate temperatures. Now, after 20 years intensive work by international teams and expenditures of more than $250 million, it is vital to review the position of HDR in relation to the established geothermal industry. The HDR resource is merely a body of rock at elevated temperatures with insufficient fluids in place to enable the heat to be extracted without the need for injection wells. All of the major field experiments in HDR have shown that the natural fracture systems form the heat transfer surfaces and that it is these fractures that must be for geothermal systems producing from naturally fractured formations provide a basis for directing the forthcoming but, equally, they require accepting significant location constraints on HDR for the time being. This paper presents a model HDR system designed for commercial operations in the UK and uses production data from hydrothermal systems in Japan and the USA to demonstrate the reservoir performance requirements for viable operations. It is shown that these characteristics are not likely to be achieved in host rocks without stimulation processes. However, the long term goal of artificial geothermal systems developed by systematic

  4. Carbon Carbon Composites: An Overview .

    Directory of Open Access Journals (Sweden)

    G. Rohini Devi

    1993-10-01

    Full Text Available Carbon carbon composites are a new class of engineering materials that are ceramic in nature but exhibit brittle to pseudoplastic behaviour. Carbon-carbon is a unique all-carbon composite with carbon fibre embeded in carbon matrix and is known as an inverse composite. Due to their excellent thermo-structural properties, carbon-carbon composites are used in specialised application like re-entry nose-tips, leading edges, rocket nozzles, and aircraft brake discs apart from several industrial and biomedical applications. The multidirectional carbon-carbon product technology is versatile and offers design flexibility. This paper describes the multidirectional preform and carbon-carbon process technology and research and development activities within the country. Carbon-carbon product experience at DRDL has also been discussed. Development of carbon-carbon brake discs process technology using the liquid impregnation process is described. Further the test results on material characterisation, thermal, mechanical and tribological properties are presented.

  5. Black ★Rock Shooter

    Institute of Scientific and Technical Information of China (English)

    Yuko

    2012-01-01

    《黑岩射手(Black RockShooter)》无疑是2月番中最吸引眼球的新番了。本作的人气高到几乎全国各地的漫展都可以看到黑岩射手MATO(麻陶)的Cosplay——一位身穿黑衣短裤.手持巨型枪械,左眼发出蓝色火焰般的光芒的少女。

  6. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110144 Hu Lan(Anhui Institute of Geological Experiment,Hefei 230001,China);Liu Yueyou Determination of Micro-amount of Bismuth in Polymetallic Ores by Hydride Generation-Atomic Fluorescence Spectrometry with Alkaline Mode(Rock and Mineral Analysis,ISSN0254-5357,CN11-2131/TD,29(1),2010,p.87-88,2 tables,10 refs.)Key words:atomic fluorescence spectrometry,bismuthA method for the determination of micro-amount of bismuth in polymetallic ores by hydride gen

  7. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20150204 Abaydulla Alimjan(Department of Chemistry and Environmental Sciences,Kashgar Teachers College,Kashgar 844006,China);Cheng Chunying Non-Metallic Element Composition Analysis of Non-Ferrous Metal Ores from Oytagh Town,Xinjiang(Rock and Mineral Analysis,ISSN0254-5357,CN11-2131/TD,33(1),2014,p.44-50,5illus.,4tables,28refs.)Key words:nonferrous metals ore,nonmetals,chemical analysis,thermogravimetric analysis Anions in non-ferrous ore materials

  8. Big Bang Day : Physics Rocks

    CERN Multimedia

    Brian Cox; John Barrowman; Eddie Izzard

    2008-01-01

    Is particle physics the new rock 'n' roll? The fundamental questions about the nature of the universe that particle physics hopes to answer have attracted the attention of some very high profile and unusual fans. Alan Alda, Ben Miller, Eddie Izzard, Dara O'Briain and John Barrowman all have interests in this branch of physics. Brian Cox - CERN physicist, and former member of 90's band D:Ream, tracks down some very well known celebrity enthusiasts and takes a light-hearted look at why this subject can appeal to all of us.

  9. New approaches in the indirect quantification of thermal rock properties in sedimentary basins: the well-log perspective

    Science.gov (United States)

    Fuchs, Sven; Balling, Niels; Förster, Andrea

    2016-04-01

    Numerical temperature models generated for geodynamic studies as well as for geothermal energy solutions heavily depend on rock thermal properties. Best practice for the determination of those parameters is the measurement of rock samples in the laboratory. Given the necessity to enlarge databases of subsurface rock parameters beyond drill core measurements an approach for the indirect determination of these parameters is developed, for rocks as well a for geological formations. We present new and universally applicable prediction equations for thermal conductivity, thermal diffusivity and specific heat capacity in sedimentary rocks derived from data provided by standard geophysical well logs. The approach is based on a data set of synthetic sedimentary rocks (clastic rocks, carbonates and evaporates) composed of mineral assemblages with variable contents of 15 major rock-forming minerals and porosities varying between 0 and 30%. Petrophysical properties are assigned to both the rock-forming minerals and the pore-filling fluids. Using multivariate statistics, relationships then were explored between each thermal property and well-logged petrophysical parameters (density, sonic interval transit time, hydrogen index, volume fraction of shale and photoelectric absorption index) on a regression sub set of data (70% of data) (Fuchs et al., 2015). Prediction quality was quantified on the remaining test sub set (30% of data). The combination of three to five well-log parameters results in predictions on the order of Journal International 203, 1977-2000, doi: 10.1093/gji/ggv403

  10. The kinetics of binding carbon dioxide in magnesium carbonate

    Energy Technology Data Exchange (ETDEWEB)

    Butt, D.P.; Lackner, K.S.; Wendt, C.H.; Vaidya, R.; Pile, D.L.; Park, Y.; Holesinger, T.; Harradine, D.M. [Los Alamos National Lab., NM (United States); Nomura, Koji [Los Alamos National Lab., NM (United States). Materials Science and Technology Div.]|[Chichibu Onada Cement Co., Tokyo (Japan)

    1998-08-01

    Humans currently consume about 6 Gigatons of carbon annually as fossil fuel. In some sense, the coal industry has a unique advantage over many other anthropogenic and natural emitters of CO{sub 2} in that it owns large point sources of CO{sub 2} from which this gas could be isolated and disposed of. If the increased energy demands of a growing world population are to be satisfied from coal, the implementation of sequestration technologies will likely be unavoidable. The authors` method of sequestration involves binding carbon dioxide as magnesium carbonate, a thermodynamically stable solid, for safe and permanent disposal, with minimal environmental impact. The technology is based on extracting magnesium hydroxide from common ultramafic rock for thermal carbonation and subsequent disposition. The economics of the method appear to be promising, however, many details of the proposed process have yet to be optimized. Realization of a cost effective method requires development of optimal technologies for efficient extraction and thermal carbonation.

  11. Rock Goes to School on Screen: A Model for Teaching Non-"Learned" Musics Derived from the Films "School of Rock" (2003) and "Rock School" (2005)

    Science.gov (United States)

    Webb, Michael

    2007-01-01

    What can be learned from two films with "rock" and "school" in their titles, about rock in school and about music and schooling more broadly? "School of Rock" (2003), a "family comedy," and "Rock School" (2005), a documentary, provoke a range of questions, ideological and otherwise, surrounding the inclusion of rock in formal instructional…

  12. Global Carbon Cycle of the Precambrian Earth

    DEFF Research Database (Denmark)

    Wiewióra, Justyna

    to investigate carbon fluxes between Precambrian Earth’s mantle and crust and to trace the evolution of life in the Eoarchaean oceans. The world’s desire for diamonds gives us a unique opportunity to obtain insight into the nature of metasomatic fluids affecting the subcratonic lithospheric mantle (SCLM) beneath...... derived from surface water. Partitioning of carbon between 13C-rich oxidized and 13C-poor reduced species indicates that life in the early ocean had to be well evolved before 3.8 Ga. Therefore, the Isua ultramafic rocks may be considered as an indirect biomarker for ancient life.......The carbon isotopic composition of distinct Archaean geological records provides information about the global carbon cycle and emergence of life on early Earth. We utilized carbon isotopic records of Greenlandic carbonatites, diamonds, graphites, marbles, metacarbonates and ultramafic rocks...

  13. Differential Regulation of Adhesion Complex Turnover by ROCK1 and ROCK2

    OpenAIRE

    Lock, Frances E.; Katie R Ryan; Poulter, Natalie S.; Maddy Parsons; Hotchin, Neil A

    2012-01-01

    BACKGROUND: ROCK1 and ROCK2 are serine/threonine kinases that function downstream of the small GTP-binding protein RhoA. Rho signalling via ROCK regulates a number of cellular functions including organisation of the actin cytoskeleton, cell adhesion and cell migration. METHODOLOGY/PRINCIPAL FINDINGS: In this study we use RNAi to specifically knockdown ROCK1 and ROCK2 and analyse their role in assembly of adhesion complexes in human epidermal keratinocytes. We observe that loss of ROCK1 inhibi...

  14. Preliminary Rock Physics Analysis on Lodgepole Formation in Manitoba, Canada

    Science.gov (United States)

    Kim, N.; Keehm, Y.

    2012-12-01

    We present rock physics analysis results of Lodgepole Formation, a carbonate reservoir in Daly Field, Manitoba, Canada. We confirmed that the Lodgepole Formation can be divided into six units in the study area: Basal Limestone, Cromer Shale, Cruickshank Crinoidal, Cruickshank Shale, Daly member and Flossie Lake member from the bottom, using eight well log data and previous works. We then performed rock physics analyses on four carbonate units (Basal Limestone, Cruickshank Crinoidal, Daly and Flossie Lake), such as Vp-porosity, AI-porosity, DEM (differential effective medium) modeling, and fluid substitution analysis. In Vp-porosity domain, the top unit, Flossie Lake member has lower porosity and higher velocity, while the other units show similar porosity and velocity. We think that this results from the diagenesis of Flossie Lake member since it bounds with unconformity. However, the four units show very similar trend in Vp-porosity domain, and we can report one Vp-porosity relation for all carbonate units of the Lodgepole formation. We also found that the acoustic impedance varies more than 10% from low porosity zone (3-6%) to high porosity zone (9-12%) from AI-porosity analysis. Thus one can delineate high porosity zone from seismic impedance data. DEM modeling showed that Flossie Lake would have relatively low aspect ratio of pores than the others, which implies that the top unit has been influenced by diagenesis. To determine fluid sensitivity of carbonate units, we conducted fluid substitution on four units from 100% water to 100% oil. The top unit, Flossie Lake, showed slight increase of Vp, which seems to be density effect. The others showed small decrease of Vp, but not significant. If we observe Vp/Vs rather than Vp, the sensitivity increases. However, fluid discrimination would be difficult because of high stiffness of rock frame. In summary, three lower carbonate units of Lodgepole Formation would be prospective and high porosity zone can be delineated

  15. Multiversos: Rock'n'Astronomy

    Science.gov (United States)

    Caballero, J. A.; Arias, A.; García, N.

    2011-11-01

    Imagine that you can use your fingers only for typing target coordinates at thetelescope, reduce images and spectra with IRAF, or write papers for Astronomy &Astrophysics, but you would never be able to play an electric guitar.Imagine that you love music, work in front of the computer always withheadphones, and dream of playing with your favourite rock band in a tumultuousconcert.Imagine that you are an astronomer who, after a "cosmic fluke", share stagewith the band which themes you have always hummed since you were a teenager.Imagine that you were born for rock, played a main role in the best Spanishalbum of the 90s (Omega, with Enrique Morente), and your songs arerutinary played by Radio 3, but you would never be able to detect an exoplanetor a galaxy at a high redshift.Imagine that you love Astronomy, try to see the Moon craters and Andromeda withyour small telescope through the light pollution of your city, and explain yourdaughter that Pluto is not a planet any longer. Imagine that you are a musician who, after a "cosmic fluke", give a talk justafter a Nobel laureate that discovered the cosmic microwave backgroundradiation.Such "cosmic flukes" sometimes happen. If you were not at the dinner of the SEA meeting and do not believe us, visithttp://www.myspace.com/antonioariasmultiverso or open the proceedings DVD andlisten "El ordenador simula el nacimiento de las estrella...".

  16. Laboratory characterization of rock joints

    Energy Technology Data Exchange (ETDEWEB)

    Hsiung, S.M.; Kana, D.D.; Ahola, M.P.; Chowdhury, A.H.; Ghosh, A. [Southwest Research Inst., San Antonio, TX (United States). Center for Nuclear Waste Regulatory Analyses

    1994-05-01

    A laboratory characterization of the Apache Leap tuff joints under cyclic pseudostatic and dynamic loads has been undertaken to obtain a better understanding of dynamic joint shear behavior and to generate a complete data set that can be used for validation of existing rock-joint models. Study has indicated that available methods for determining joint roughness coefficient (JRC) significantly underestimate the roughness coefficient of the Apache Leap tuff joints, that will lead to an underestimation of the joint shear strength. The results of the direct shear tests have indicated that both under cyclic pseudostatic and dynamic loadings the joint resistance upon reverse shearing is smaller than that of forward shearing and the joint dilation resulting from forward shearing recovers during reverse shearing. Within the range of variation of shearing velocity used in these tests, the shearing velocity effect on rock-joint behavior seems to be minor, and no noticeable effect on the peak joint shear strength and the joint shear strength for the reverse shearing is observed.

  17. Rock-property changes during reservoir compaction

    Energy Technology Data Exchange (ETDEWEB)

    Morita, N. (Conoco, Inc., Ponca City, OK (United States)); Gray, K.E. (Texas Univ., Austin, TX (United States)); Srouji, F.A.A.; Jogi, P.N. (Teleco Oilfield Services Inc., Meviden, CT (US))

    1992-09-01

    Deformations, absolute permeability, electrical resistivity, PV change, and compressional- and shear-wave velocities were measured for Berea sandstone under various loading paths at temperatures from 70 to 380{degrees} F. The experimental behavior was subdivided into five categories. The experimental results were analyzed for each category, and the analysis was used to construct semianalytical rock-property equations, are expressed in terms of strain components. This formalism is practical because strains are more directly related to rock properties that are stress components. This paper presents unique rock-property data, including axial and radial measurements with various loading paths and temperatures; semianalytical equations that accurately simulate rock properties under various loading paths up to rock failure; and realistic predictions of rock-property changes during reservoir compaction.

  18. Grain-rimming kaolinite in Permian Rotliegend reservoir rocks

    Science.gov (United States)

    Waldmann, Svenja; Gaupp, Reinhard

    2016-04-01

    precipitation. Under the presence of sulfate (SO42 -), partial hematite dissolution and the reduction of Fe3 + to Fe2 + occur, where the latter is further incorporated in Fe-Mg-rich carbonates. The sulfate is bonded in anhydrite. The results of this study are relevant for reservoir quality predictions in kaolinite-dominated systems, as well as for CO2 storage projects and the prediction of long-term fluid-rock interactions under the participation of carbon dioxide and/or other gases.

  19. Mass Dependent Fractionation of Hg Isotopes in Source Rocks, Mineral Deposits and Spring Waters of the California Coast Ranges, USA

    Science.gov (United States)

    Smith, C. N.; Kesler, S. E.; Blum, J. D.; Rytuba, J. J.

    2007-12-01

    We present here the first study of the isotopic composition of Hg in rocks, ore deposits, and active hydrothermal systems from the California Coast Ranges, one of Earth's largest Hg-depositing systems. The Franciscan Complex and Great Valley Sequence, which form the bedrock in the California Coast Ranges, are intruded and overlain by Tertiary volcanic rocks including the Clear Lake Volcanic Sequence. These rocks contain two types of Hg deposits, hot-spring deposits that form at shallow depths (geothermal systems that release Hg to the present surface. The Franciscan Complex and Great Valley Sequence contain clastic sedimentary rocks with higher concentrations of Hg than volcanic rocks of the Clear Lake Volcanic Field. Mean Hg isotope compositions for all three rock units are similar, although the range of values in Franciscan Complex rocks is greater than in either Great Valley or Clear Lake rocks. Hot spring and silica-carbonate Hg deposits have similar average isotopic compositions that are indistinguishable from averages for the three rock units, although δ202Hg values for the Hg deposits have a greater variance than the country rocks. Precipitates from dilute spring and saline thermal waters in the area have similarly large variance and a mean δ202Hg value that is significantly lower than the ore deposits and rocks. These observations indicate there is little or no isotopic fractionation during release of Hg from its source rocks into hydrothermal solutions. Isotopic fractionation does appear to take place during transport and concentration of Hg in deposits, especially in their uppermost parts. Boiling of hydrothermal fluids is likely the most important process causing of the observed Hg isotope fractionation. This should result in the release of Hg with low δ202Hg values into the atmosphere from the top of these hydrothermal systems and a consequent enrichment in heavy Hg isotopes in the upper crust through time.

  20. Geochemical Characteristics and Metallogenesis of Volcanic Rocks as Exemplified by Volcanic Rocks in Ertix,Xinjiang

    Institute of Scientific and Technical Information of China (English)

    刘铁庚; 叶霖

    1997-01-01

    Volcanic rocks in Ertix,Xinjiang,occurring in the collision zone between the Siberia Plate and the Junggar Plate,are distributed along the Eritix River Valley in northern Xinjiang.The volcanic rocks were dated at Late Paleozoic and can be divided into the spilite-keratophyre series and the basalt-andesite series.The spilite-keratophyre series volcanic rocks occur in the Altay orogenic belt at the southwest margin of the Siberia Plate.In addition to sodic volcanic rocks.There are also associated potassic-sodic volcanic rocks and potassic volcanic rocks.The potassic-sodic volcanic rocks occur at the bottom of the eruption cycle and control the distribution of Pb and Zn deposits.The potassic volcanic rocks occur at the top of the eruption cycle and are associated with Au and Cu mineralizations.The sodic volcanic rocks occur in the middle stage of eruption cycle and control the occurrence of Cu(Zn) deposits.The basalt-andesite series volcanic rocks distributed in the North Junggar orogenic belt at the north margin of the Junggar-Kazakstan Plate belong to the potassic sodic volcain rocks.The volcanic rocks distributed along the Ulungur fault are relatively rich in sodium and poor in potassium and are predominated by Cu mineralization and associated with Au mineralization.Those volcanic rocks distributed along the Ertix fault are relatively rich in K and poor in Na,with Au mineralization being dominant.

  1. The rock resources of the Northern Emirates

    OpenAIRE

    Mitchell, Clive; Styles, Michael

    2011-01-01

    The Rock Resources of the Northern Emirates The United Arab Emirates (UAE) has vast resources of limestone and hard rock in the northern Emirates. These are currently exploited by quarrying companies to produce construction aggregate and raw material for the manufacture of cement, with a small amount being used to produce rock wool, dimension stone and mineral filler. The demand by industry for higher value mineral products that could be produced from these resources is mostly met by impor...

  2. Huashan rock paintings and other simitar paintings

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    China is one of the countries with the rechest rock paintings in the world. The Huashan rock paintings features color paintings, quite different from those in the North China areas where petroglyphs were created by engraving, chiseling,incising,or grinding,such as those in Inner Mongolia and Helan Mountains in Gansu.The rock paintings at Ulanchabu of Inner Mongolia are regarded as works of the Neolithic age,bronze age and iron age ,featuring mainly such grassland animals as

  3. Motion of rock masses on slope

    Directory of Open Access Journals (Sweden)

    Urška Petje

    2006-12-01

    Full Text Available This paper shows the different ways of how rock masses (stones, rocks, and blocks move along slopes and for each different way of motion (free fall, bouncing, rolling, sliding, slowing down, lubrication, fluidizationadequatedynamicequationsaregiven.Knowingthe kinematics and dynamics of travelling rock masses is necessary for mathematical modeling of motion and by this an assessment of maximal possible rockfall runout distances as an example of a sudden and hazardeous natural phenomenon, threatening man and his property, especially in the natural environment.

  4. Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania; effects of pipe-outlet terracing on quantity and quality of surface runoff and ground water in a small carbonate-rock basin near Churchtown, Pennsylvania, 1983-89

    Science.gov (United States)

    Lietman, P.L.; Gustafson-Minnich, L. C.; Hall, D.W.

    1997-01-01

    Terracing effects on surface-runoff and ground- water quantity and quality were investigated by the U.S. Geological Survey, in cooperation with Pennsylvania Department of Environmental Resources, during 1983-89 at a 23.1-acre agricultural site in Lancaster County, Pa., as part of the 1982 Rural Clean Water Program. The site, underlain by carbonate rock, was primarily corn and alfalfa fields; the median slope was 6 percent.Normal precipitation is about 42 inches per year. Average annual runoff was 11 percent and ground- water recharge was 37 percent of precipitation.Runoff quantity, suspended-sediment, and nutrient data, ground-water level and nutrient data, and precipitation-quantity data were collected for 21 months prior to, and 58 months after, pipe-outlet terrace construction. Data were analyzed by use of graphical, regression, covariate, cluster, Mann- Whitney Rank Sum test, and double-mass curvetechniques. Terracing changed runoff characteristics. Storm characteristics were similar throughout the study period. However, after terracing, storms producing less than 0.4 inch of precipitation rarely produced runoff. Total-storm discharge as a function of precipitation did not change significantly throughout the range of runoff-producing storms after terracing. Multiple-discharge peaks on hydrographs before terracing did not occur after terracing when hydrographs reflected the stepwisedraining of each terrace through the pipe outlet. After an initial 2-year period of terrace stabilization, suspended-sediment yield in runoff decreased significantly as a function of runoff. This result was expected because terracing decreased runoff energy, and because terrace ponding allowed time for sediment redeposition. Nitrate plus nitrite yields increased proportionally throughout the range of runoff during the post-terracing period relative to the pre- terracing period. After terracing, a combination of increased soil contact time and increased nitrification caused by wetter

  5. The long-term carbon cycle, fossil fuels and atmospheric composition.

    Science.gov (United States)

    Berner, Robert A

    2003-11-20

    The long-term carbon cycle operates over millions of years and involves the exchange of carbon between rocks and the Earth's surface. There are many complex feedback pathways between carbon burial, nutrient cycling, atmospheric carbon dioxide and oxygen, and climate. New calculations of carbon fluxes during the Phanerozoic eon (the past 550 million years) illustrate how the long-term carbon cycle has affected the burial of organic matter and fossil-fuel formation, as well as the evolution of atmospheric composition.

  6. Meteorite Linked to Rock at Meridiani

    Science.gov (United States)

    2004-01-01

    This meteorite, a basalt lava rock nearly indistinguishable from many Earth rocks, provided the first strong proof that meteorites could come from Mars. Originally weighing nearly 8 kilograms (17.6 pounds), it was collected in 1979 in the Elephant Moraine area of Antarctica. The side of the cube at the lower left in this image measures 1 centimeter (0.4 inches). This picture shows a sawn face of this fine-grained gray rock. (The vertical stripes are saw marks.) The black patches in the rock are melted rock, or glass, formed when a large meteorite hit Mars near the rock. The meteorite impact probably threw this rock, dubbed 'EETA79001,' off Mars and toward Antarctica on Earth. The black glass contains traces of martian atmosphere gases. The Mars Exploration Rover Opportunity has discovered that a rock dubbed 'Bounce' at Meridiani Planum has a very similar mineral composition to this meteorite and likely shares common origins. Bounce itself is thought to have originated outside the area surrounding Opportunity's landing site; an impact or collision likely threw the rock away from its primary home.

  7. Characteristics of the Triassic Source Rocks of the Aitutu Formation in the (West Timor Basin

    Directory of Open Access Journals (Sweden)

    Asep Kurnia Permana

    2014-12-01

    Full Text Available DOI:10.17014/ijog.v1i3.192The Triassic rocks of the (West Timor Basin have been identified that was mainly deposited in the  marine environment. The fine grained clastics and carbonate  rocks of this Triassic marine  facies are considered to be the most promising source rocks potential in this basin. In this paper we present geochemical and petrographic data from outcrop samples of the Triassic carbonate Aitutu Formation, due to emphasized the organic maturation, kerogen type of the organic matter and the origin of the organic matter.  A representative of selected sample were subjected to the Rock-Eval Pyrolisis, vitrinite reflectance and thermal alteration index, bitumen extraction, were analyzed on the GC-MS. The samples were collected from marine deposit of the Triassic Sequence. The TOC values of the analyzed sample range between rich and rich organic richness (0.51% - 9.16%, wt.%, TOC, which consists mainly of type II and III kerogen and the organic matter consider to be predominantly oil/gas prone and gas prone potential. The thermal maturity assessed from Tmax, TAI, and vitrinite reflectance shows an immature to early peak mature stage of the organic matter. The GC-MS analyses of the biomarkers indicate mainly the organic matter derived from mixed source rocks facies containing alga debris and higher plant terrestrial origin.

  8. Prediction of rock brittleness using nondestructive methods for hard rock tunneling

    Directory of Open Access Journals (Sweden)

    Rennie B. Kaunda

    2016-08-01

    Full Text Available The material and elastic properties of rocks are utilized for predicting and evaluating hard rock brittleness using artificial neural networks (ANN. Herein hard rock brittleness is defined using Yagiz' method. A predictive model is developed using a comprehensive database compiled from 30 years' worth of rock tests at the Earth Mechanics Institute (EMI, Colorado School of Mines. The model is sensitive to density, elastic properties, and P- and S-wave velocities. The results show that the model is a better predictor of rock brittleness than conventional destructive strength-test based models and multiple regression techniques. While the findings have direct implications on intact rock, the methodology can be extrapolated to rock mass problems in both tunneling and underground mining where rock brittleness is an important control.

  9. Prediction of rock brittleness using nondestructive methods for hard rock tunneling

    Institute of Scientific and Technical Information of China (English)

    Rennie B. Kaunda; Brian Asbury

    2016-01-01

    The material and elastic properties of rocks are utilized for predicting and evaluating hard rock brit-tleness using artificial neural networks (ANN). Herein hard rock brittleness is defined using Yagiz’ method. A predictive model is developed using a comprehensive database compiled from 30 years’ worth of rock tests at the Earth Mechanics Institute (EMI), Colorado School of Mines. The model is sensitive to density, elastic properties, and P-and S-wave velocities. The results show that the model is a better predictor of rock brittleness than conventional destructive strength-test based models and mul-tiple regression techniques. While the findings have direct implications on intact rock, the methodology can be extrapolated to rock mass problems in both tunneling and underground mining where rock brittleness is an important control.

  10. Matrix rigidity differentially regulates invadopodia activity through ROCK1 and ROCK2.

    Science.gov (United States)

    Jerrell, Rachel J; Parekh, Aron

    2016-04-01

    ROCK activity increases due to ECM rigidity in the tumor microenvironment and promotes a malignant phenotype via actomyosin contractility. Invasive migration is facilitated by actin-rich adhesive protrusions known as invadopodia that degrade the ECM. Invadopodia activity is dependent on matrix rigidity and contractile forces suggesting that mechanical factors may regulate these subcellular structures through ROCK-dependent actomyosin contractility. However, emerging evidence indicates that the ROCK1 and ROCK2 isoforms perform different functions in cells suggesting that alternative mechanisms may potentially regulate rigidity-dependent invadopodia activity. In this study, we found that matrix rigidity drives ROCK signaling in cancer cells but that ROCK1 and ROCK2 differentially regulate invadopodia activity through separate signaling pathways via contractile (NM II) and non-contractile (LIMK) mechanisms. These data suggest that the mechanical rigidity of the tumor microenvironment may drive ROCK signaling through distinct pathways to enhance the invasive migration required for cancer progression and metastasis.

  11. Some influences of rock strength and strain rate on propagation of rock avalanches

    Science.gov (United States)

    Bowman, Elisabeth; Rait, Kim

    2016-04-01

    Rock avalanches are extreme and destructive mass movements in which large volumes of rock (typically >1 million cubic metres) travel at high speeds, covering large distances, and the occurrence of which is highly unpredictable. The "size effect" in rock avalanches, whereby those with larger volumes produce greater spreading efficiency (as defined by an increase in normalised runout) or lower farboschung angle (defined as the tangent of the ratio of fall height to runout length), is well known. Studies have shown that rock strength is a controlling factor in the mobility of rock avalanches - that is, mass movements involving lower strength rock are generally found to produce greater mobility as evidenced by the spread of deposits or low farboschung angle. However, there are conflicting ideas as to how and why this influence is manifested. This paper discusses different theories of rock comminution in light of numerical simulations of rock clasts undergoing normal and shear induced loading, experimental work on rock avalanche behaviour, and dynamic fracture mechanics. In doing so, we introduce the idea of thresholds of strain rate for the production of dynamic fragmentation (as opposed to pseudo-static clast crushing) that are based, inter alia, on static rock strength. To do this, we refer to data from physical models using rock analogue materials, field data on chalk cliff collapses, and field statistics from documented rock avalanches. The roles of normal and shear loading and loading rate within a rock avalanche are examined numerically using 3D Discrete Element Method models of rock clasts loaded to failure. Results may help to reconcile the observations that large rock avalanches in stronger materials tend not to fragment as much as those in weaker materials and also possess lower mobility, while small cliff collapses (typically > 1000 cubic metres) in weak chalk can exhibit rock avalanche-like behaviour at much smaller volumes.

  12. Origin of beach-stranded tars from source rocks indigeneous to Seychelles

    Energy Technology Data Exchange (ETDEWEB)

    Plummer, P.S. [Seychelles National Oil Co., Mahe (South Africa)

    1996-03-01

    Tarballs have been found stranded as traction deposits on a beach on northwest Mahe Island, Seychelles, with every ebbing tide. Weekly collections from mid-1993 to mid-1994 gathered nearly 4750 samples of two types of tar: a dominant black malleable tar and a less common brownish-black hard tar. Both tars represent moderately degraded extracts of crude oils seemingly derived from mature source rocks dominated by a combination of oil-prone phytoplanktonic and algal organic matter over gas-prone land-plant organic matter. Source rock deposition occurred principally in paralic to open-marine environments. The presence of minor oleanane and bicadinane, and a general preponderance of diasteranes and tricyclic terpanes in the hard tar suggest derivation from a Late Cretaceous clastic source rock with possible carbonate interbeds. By contrast, no samples of the malleable tar contain oleanane or bicadinane, but all contain significant norhopane and tetracyclic terpanes, which, along with significant sulfur and low diasterane contents, indicate derivation from a carbonate source rock of perhaps pre-Late Cretaceous age. Additionally, maturity and limited geochemical data from proven and potential source rocks present in the offshore wells enable the malleable and hard tars to be equated with specific units in the Seychelles stratigraphy; the malleable tar is seemingly derived from a Middle Jurassic carbonate of Tethyan affinity and the hard tar possibly originated from either Campanian or Maastrichtian-Paleocene shales. These tars are thus concluded to be natural seepage products derived from source rocks indigenous to Seychelles, and their persistent beach stranding significantly reduces the risk of hydrocarbon exploration in this frontier province.

  13. Carbon cycle makeover

    DEFF Research Database (Denmark)

    Canfield, Donald Eugene; Kump, Lee R.

    2013-01-01

    remaining in sediments after respiration leave a residual of oxygen in the atmosphere. The source of oxygen to the atmosphere represented by organic matter burial is balanced by oxygen sinks associated with rock weathering and chemical reaction with volcanic gases. This is the long-term carbon and oxygen......In 1845, the French chemist and mining engineer Jacques-Joseph Ebelman figured out why Earth's atmosphere contains oxygen (1). Oxygen is produced by plants during photosynthesis, but almost all of this oxygen is used again in respiration. Ebelman reasoned that small amounts of organic matter...

  14. Source rock contributions to the Lower Cretaceous heavy oil accumulations in Alberta: a basin modeling study

    Science.gov (United States)

    Berbesi, Luiyin Alejandro; di Primio, Rolando; Anka, Zahie; Horsfield, Brian; Higley, Debra K.

    2012-01-01

    The origin of the immense oil sand deposits in Lower Cretaceous reservoirs of the Western Canada sedimentary basin is still a matter of debate, specifically with respect to the original in-place volumes and contributing source rocks. In this study, the contributions from the main source rocks were addressed using a three-dimensional petroleum system model calibrated to well data. A sensitivity analysis of source rock definition was performed in the case of the two main contributors, which are the Lower Jurassic Gordondale Member of the Fernie Group and the Upper Devonian–Lower Mississippian Exshaw Formation. This sensitivity analysis included variations of assigned total organic carbon and hydrogen index for both source intervals, and in the case of the Exshaw Formation, variations of thickness in areas beneath the Rocky Mountains were also considered. All of the modeled source rocks reached the early or main oil generation stages by 60 Ma, before the onset of the Laramide orogeny. Reconstructed oil accumulations were initially modest because of limited trapping efficiency. This was improved by defining lateral stratigraphic seals within the carrier system. An additional sealing effect by biodegraded oil may have hindered the migration of petroleum in the northern areas, but not to the east of Athabasca. In the latter case, the main trapping controls are dominantly stratigraphic and structural. Our model, based on available data, identifies the Gordondale source rock as the contributor of more than 54% of the oil in the Athabasca and Peace River accumulations, followed by minor amounts from Exshaw (15%) and other Devonian to Lower Jurassic source rocks. The proposed strong contribution of petroleum from the Exshaw Formation source rock to the Athabasca oil sands is only reproduced by assuming 25 m (82 ft) of mature Exshaw in the kitchen areas, with original total organic carbon of 9% or more.

  15. Hard rock, heavy metal, metal

    OpenAIRE

    Hein, Fabien

    2011-01-01

    Le terme générique metal désigne une multitude de genres et de sous-genres musicaux issus de l’appariement du hard rock et du heavy metal. Il résulte d’une agrégation sémantique consécutive de l’érosion et de l’interpénétration de ces termes au cours des années 1980. Leurs modèles canoniques, respectivement représentés par les groupes Led Zeppelin et Black Sabbath, se sont progressivement dilués sous l’effet d’une filiation particulièrement effervescente et féconde : black, thrash, doom, prog...

  16. ROCKS & MINERALS DETERMINATION AND ANALYSIS

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091570 Ge Yunjin(College of Geo-Resource and Information,China University of Petroleum,Dongying 257061,China);Chen Yong Advance in Low Temperature Phase Transition and Raman Spectrum Technique in Composition Determination of Fluid Inclusions(Rock and Mineral Analysis,ISSN0254-5357,CN11-2131/TD,27(3),2008,p.207-210,22 refs.)Key words:fluid inclusions,Raman spectraThe principle and development of low-temperature analytical techniques for fluid inclusions were expounded.The traditional low-temperature analytical technology mainly focused on the measurement of inorganic salt using congealed microthermometry,but now it is developed to semi-quantitative and quantitative analysis of fluid inclusions using in-situ cryogenic Raman spectrometry.

  17. Differential regulation of adhesion complex turnover by ROCK1 and ROCK2.

    Directory of Open Access Journals (Sweden)

    Frances E Lock

    Full Text Available BACKGROUND: ROCK1 and ROCK2 are serine/threonine kinases that function downstream of the small GTP-binding protein RhoA. Rho signalling via ROCK regulates a number of cellular functions including organisation of the actin cytoskeleton, cell adhesion and cell migration. METHODOLOGY/PRINCIPAL FINDINGS: In this study we use RNAi to specifically knockdown ROCK1 and ROCK2 and analyse their role in assembly of adhesion complexes in human epidermal keratinocytes. We observe that loss of ROCK1 inhibits signalling via focal adhesion kinase resulting in a failure of immature adhesion complexes to form mature stable focal adhesions. In contrast, loss of ROCK2 expression results in a significant reduction in adhesion complex turnover leading to formation of large, stable focal adhesions. Interestingly, loss of either ROCK1 or ROCK2 expression significantly impairs cell migration indicating both ROCK isoforms are required for normal keratinocyte migration. CONCLUSIONS: ROCK1 and ROCK2 have distinct and separate roles in adhesion complex assembly and turnover in human epidermal keratinocytes.

  18. Mixing-controlled uncertainty in long-term predictions of acid rock drainage from heterogeneous waste-rock piles

    Science.gov (United States)

    Pedretti, D.; Beckie, R. D.; Mayer, K. U.

    2015-12-01

    The chemistry of drainage from waste-rock piles at mine sites is difficult to predict because of a number of uncertainties including heterogeneous reactive mineral content, distribution of minerals, weathering rates and physical flow properties. In this presentation, we examine the effects of mixing on drainage chemistry over timescales of 100s of years. We use a 1-D streamtube conceptualization of flow in waste rocks and multicomponent reactive transport modeling. We simplify the reactive system to consist of acid-producing sulfide minerals and acid-neutralizing carbonate minerals and secondary sulfate and iron oxide minerals. We create multiple realizations of waste-rock piles with distinct distributions of reactive minerals along each flow path and examine the uncertainty of drainage geochemistry through time. The limited mixing of streamtubes that is characteristic of the vertical unsaturated flow in many waste-rock piles, allows individual flowpaths to sustain acid or neutral conditions to the base of the pile, where the streamtubes mix. Consequently, mixing and the acidity/alkalinity balance of the streamtube waters, and not the overall acid- and base-producing mineral contents, control the instantaneous discharge chemistry. Our results show that the limited mixing implied by preferential flow and the heterogeneous distribution of mineral contents lead to large uncertainty in drainage chemistry over short and medium time scales. However, over longer timescales when one of either the acid-producing or neutralizing primary phases is depleted, the drainage chemistry becomes less controlled by mixing and in turn less uncertain. A correct understanding of the temporal variability of uncertainty is key to make informed long-term decisions in mining settings regarding the management of waste material.

  19. Amino acids and hydrocarbons approximately 3,800-Myr old in the Isua rocks, southwestern Greenland

    Science.gov (United States)

    Nagy, B.; Engel, M. H.; Zumberge, J. E.; Ogino, H.; Chang, S. Y.

    1981-01-01

    Results of an analysis of amino acids and hydrocarbons found in the Isua banded iron formation, which contains the oldest known rocks on earth, are discussed. Similarities are pointed out between the relative amino acid abundances of the Isua rocks and those of lichens found on their surfaces, and a lack of substantial racemization indicated by the low D/L ratios in the 3800-million year old rock samples is noted. Experimental results showing the possibility of amino acid diffusion from lichens into the rocks are presented. Comparisons of the Isua rock amino acid D/L ratios with those reported for samples from other regions indicates that none of the Isua amino acids are older than a few tens of thousands to a few hundred thousand years. Analyses of the saturated hydrocarbons of the Isua samples reveals no odd carbon number preference, which may indicate antiquity, however laboratory experiments have shown that amino acids and aromatic and saturated aliphatic hydrocarbons could not have survived the metamorphic history of the Isua rocks. The evidence presented thus suggests that the amino acids and hydrocarbons found are not of the age of the sediments.

  20. Geochemistry of Eagle Ford group source rocks and oils from the first shot field area, Texas

    Science.gov (United States)

    Edman, Janell D.; Pitman, Janet K.; Hammes, Ursula

    2010-01-01

    Total organic carbon, Rock-Eval pyrolysis, and vitrinite reflectance analyses performed on Eagle Ford Group core and cuttings samples from the First Shot field area, Texas demonstrate these samples have sufficient quantity, quality, and maturity of organic matter to have generated oil. Furthermore, gas chromatography and biomarker analyses performed on Eagle Ford Group oils and source rock extracts as well as weight percent sulfur analyses on the oils indicate the source rock facies for most of the oils are fairly similar. Specifically, these source rock facies vary in lithology from shales to marls, contain elevated levels of sulfur, and were deposited in a marine environment under anoxic conditions. It is these First Shot Eagle Ford source facies that have generated the oils in the First Shot Field. However, in contrast to the generally similar source rock facies and organic matter, maturity varies from early oil window to late oil window in the study area, and these maturity variations have a pronounced effect on both the source rock and oil characteristics. Finally, most of the oils appear to have been generated locally and have not experienced long distance migration. 

  1. Inference of coastal submergence from the study of beach rock off Visakhapatnam

    Digital Repository Service at National Institute of Oceanography (India)

    Rajamanickam, G.V.; Rao, K.M.; Rao, T.C.S.

    along Mand'apam - Kilakarai - Tutkorin section (Foote; 1889). Occurrence of beach sandstones along Vis3.khapatnam coast is so far recorded by Blanford (1872) but the extension of such beach rocks is too light. The authors had an opportunity to obtain...) Petrology of Sedimentary Rocks, Hem