WorldWideScience

Sample records for carbon offsets reversal

  1. Carbon offsets, reversal risk and US climate policy

    Directory of Open Access Journals (Sweden)

    Chen Yihsu

    2009-06-01

    Full Text Available Abstract Background One controversial issue in the larger cap-and-trade debate is the proper use and certification of carbon offsets related to changes in land management. Advocates of an expanded offset supply claim that inclusion of such activities would expand the scope of the program and lower overall compliance costs, while opponents claim that it would weaken the environmental integrity of the program by crediting activities that yield either nonexistent or merely temporary carbon sequestration benefits. Our study starts from the premise that offsets are neither perfect mitigation instruments nor useless "hot air." Results We show that offsets provide a useful cost containment function, even when there is some threat of reversal, by injecting additional "when-flexibility" into the system. This allows market participants to shift their reduction requirements to periods of lower cost, thereby facilitating attainment of the least-cost time path without jeopardizing the cumulative environmental integrity of the system. By accounting for market conditions in conjunction with reversal risk, we develop a simple offset valuation methodology, taking into account the two most important factors that typically lead offsets to be overvalued or undervalued. Conclusion The result of this paper is a quantitative "model rule" that could be included in future legislation or used as a basis for active management by a future "carbon fed" or other regulatory authority with jurisdiction over the US carbon market to actively manage allowance prices.

  2. Carbon offsetting: sustaining consumption?

    OpenAIRE

    Heather Lovell; Harriet Bulkeley; Diana Liverman

    2009-01-01

    In this paper we examine how theories of sustainable and ethical consumption help us to understand a new, rapidly expanding type of consumer product designed to mitigate climate change: carbon offsets. The voluntary carbon offset market grew by 200% between 2005 and 2006, and there are now over 150 retailers of voluntary carbon offsets worldwide. Our analysis concentrates on the production and consumption of carbon offsets, drawing on ideas from governmentality and political ecology about how...

  3. Governing the carbon offset market

    OpenAIRE

    Lovell, Heather C.

    2010-01-01

    Carbon offsets are produced and sold under the international climate change regime (the United Nations Kyoto Protocol) and also within an expanding voluntary offset market in which companies and individuals can voluntarily opt to compensate for their greenhouse gas emissions. The volume of carbon produced and consumed within compliance and voluntary markets has grown dramatically in the last 5 years, raising a number of governance challenges. This Focus Article gives an overview of the govern...

  4. Managing dependencies in forest offset projects: toward a more complete evaluation of reversal risk

    Science.gov (United States)

    David M Cooley; Chrsitopher S Galik; Thomas P Holmes; Carolyn Kousky; Roger M Cooke

    2011-01-01

    Although forest carbon offsets can play an important role in the implementation of comprehensive climate policy, they also face an inherent risk of reversal. If such risks are positively correlated across projects, it can affect the integrity of larger project portfolios and potentially the entire offsets program. Here, we discuss three types of risks that could affect...

  5. Common-image gathers in the offset domain from reverse-time migration

    KAUST Repository

    Zhan, Ge

    2014-04-01

    Kirchhoff migration is flexible to output common-image gathers (CIGs) in the offset domain by imaging data with different offsets separately. These CIGs supply important information for velocity model updates and amplitude-variation-with-offset (AVO) analysis. Reverse-time migration (RTM) offers more insights into complex geology than Kirchhoff migration by accurately describing wave propagation using the two-way wave equation. But, it has difficulty to produce offset domain CIGs like Kirchhoff migration. In this paper, we develop a method for obtaining offset domain CIGs from RTM. The method first computes the RTM operator of an offset gather, followed by a dot product of the operator and the offset data to form a common-offset RTM image. The offset domain CIGs are then achieved after separately migrating data with different offsets. We generate offset domain CIGs on both the Marmousi synthetic data and 2D Gulf of Mexico real data using this approach. © 2014.

  6. Carbon offset potentials and design: Anticipating future public policy

    International Nuclear Information System (INIS)

    Trexler, M.C.; Kosloff, L.H.; Gowen, M.

    1994-01-01

    Carbon offsets offer CO 2 emitters the opportunity to compensate for some proportion of their CO 2 emissions through the pursuit of emissions reduction or carbon sequestration projects beyond their own operational boundaries. The flexibility to pursue carbon offsets ''off-site'' can dramatically reduce the costs of achieving a given net emissions reduction. The future role of carbon offsets, however, continues to be a topic of considerable debate. Several processes are currently under way nationally and internationally that will help shape this role. This paper discusses how alternative policy outcomes could encourage or restrict the viability of carbon offsets as a component of corporate climate change mitigation portfolios and proposes criteria by which projects should be evaluated prior to the finalization of national or international policy frameworks. Based on these outcomes, the potential for offsets could be very large or very modest. It is vital that policy development in the offset arena account for the still voluntary nature of mitigation efforts and that the objective of climate change mitigation not be forgotten in the push for offset rules and regulations. At the same time, carbon offsets are far from a panacea for climate change mitigation and should be evaluated in the context of a larger global mitigation portfolio

  7. Design rules for vertical interconnections by reverse offset printing

    Science.gov (United States)

    Kusaka, Yasuyuki; Kanazawa, Shusuke; Ushijima, Hirobumi

    2018-03-01

    Formation of vertical interconnections by reverse offset printing was investigated, particularly focusing on the transfer step, in which an ink pattern is transferred from a polydimethylsiloxane (PDMS) sheet for the step coverage of contact holes. We systematically examined the coverage of contact holes made of a tapered photoresist layer by varying the hole size, the hole depth, PDMS elasticity, PDMS thickness, printing speed, and printing indentation depth. Successful ink filling was achieved when the PDMS was softer, and the optimal PDMS thickness varied depending on the size of the contact holes. This behaviour is related to the bell-type uplift deformation of incompressible PDMS, which can be described by contact mechanics numerical simulations. Based on direct observation of PDMS/resist-hole contact behaviour, the step coverage of contact holes typically involves two steps of contact area growth: (i) the PDMS first touches the bottom of the holes and then (ii) the contact area gradually and radially widens toward the tapered sidewall. From an engineering perspective, it is pointed out that mechanical synchronisation mismatch in the roll-to-sheet type printing invokes the cracking of ink layers at the edges of contact holes. According to the above design rule, ink filling into a contact hole with thickness of 2.5 µm and radius of 10 µm was achieved. Contact chain patterns with 1386 points of vertical interconnections with the square hole size of up to 10 µm successfully demonstrated the validity of the technique presented herein.

  8. Expanding the development benefits from carbon offsets

    Energy Technology Data Exchange (ETDEWEB)

    Ayres, Jessica; Grieg-Gran, Maryanne; Harris, Lizzie; Huq, Saleemul

    2006-10-15

    The Clean Development Mechanism (CDM) of the Kyoto Protocol which allows for trade in emission reductions between developing and developed countries has a specific aim of ensuring that carbon emission reduction projects contribute to sustainable development of the host country according to standards set by that country. However, the development potential of transactions under the CDM is constrained by a number of factors. Governments face the dilemma of setting demanding sustainable development criteria and running the risk of losing investments to other developing countries with less demanding standards, or setting less stringent standards and thus generating little benefit at the local level. This is compounded by the fact that concluding deals under the CDM in developing countries is more expensive, time-consuming and risky than buying carbon credits elsewhere.

  9. Forest Carbon Offsets Revisited: Shedding Light on Darkwoods

    NARCIS (Netherlands)

    Kooten, van G.C.; Bogle, T.; Vries, de F.P.

    2015-01-01

    This paper investigates the viability of carbon offset credits created through forest conservation and preservation. A detailed forest management model based on a case study of a forest estate in southeastern British Columbia, owned by The Nature Conservancy of Canada (NCC) is used to demonstrate

  10. Improved stove programs need robust methods to estimate carbon offsets

    OpenAIRE

    Johnson, Michael; Edwards, Rufus; Masera, Omar

    2010-01-01

    Current standard methods result in significant discrepancies in carbon offset accounting compared to approaches based on representative community based subsamples, which provide more realistic assessments at reasonable cost. Perhaps more critically, neither of the currently approved methods incorporates uncertainties inherent in estimates of emission factors or non-renewable fuel usage (fNRB). Since emission factors and fNRB contribute 25% and 47%, respectively, to the overall uncertainty in ...

  11. How sensitive is the deltoid moment arm to humeral offset changes with reverse total shoulder arthroplasty?

    Science.gov (United States)

    Walker, David R; Kinney, Allison L; Wright, Thomas W; Banks, Scott A

    2016-06-01

    Reverse total shoulder arthroplasty commonly treats cuff-deficient or osteoarthritic shoulders not amenable to rotator cuff repair. This study investigates deltoid moment arm sensitivity to variations in the joint center and humeral offset of 3 representative reverse total shoulder arthroplasty subjects. We hypothesized that a superior joint implant placement may exist, indicated by muscle moment arms, compared with the current actual surgical implant configuration. Moment arms for the anterior, lateral, and posterior aspects of the deltoid muscle were determined for 1521 perturbations of the humeral offset location away from the surgical placement in a subject-specific musculoskeletal model with motion defined by subject-specific in vivo abduction kinematics. The humeral offset was varied from its surgical position ±4 mm in the anterior/posterior direction, ±12 mm in the medial/lateral direction, and -10 to 14 mm in the superior/inferior direction. The anterior deltoid moment arm varied in humeral offset and center of rotation up to 20 mm, primarily in the medial/lateral and superior/inferior directions. The lateral deltoid moment arm varied in humeral offset up to 20 mm, primarily in the medial/lateral and anterior/posterior directions. The posterior deltoid moment arm varied up to 15 mm, primarily in early abduction, and was most sensitive to humeral offset changes in the superior/inferior direction. High variations in muscle moment arms were found for all 3 deltoid components, presenting an opportunity to dramatically change the deltoid moment arms through surgical placement of the reverse shoulder components and by varying the overall offset of the humerus. Basic Science Study; Computer Modeling. Copyright © 2016 Journal of Shoulder and Elbow Surgery Board of Trustees. Published by Elsevier Inc. All rights reserved.

  12. Bird community conservation and carbon offsets in western North America.

    Science.gov (United States)

    Schuster, Richard; Martin, Tara G; Arcese, Peter

    2014-01-01

    Conservation initiatives to protect and restore valued species and communities in human-dominated landscapes face huge challenges linked to the cost of acquiring habitat. We ask how the sale of forest carbon offsets could reduce land acquisition costs, and how the alternate goals of maximizing α or β-diversity in focal communities could affect the prioritization land parcels over a range of conservation targets. Maximizing total carbon storage and carbon sequestration potential reduced land acquisition costs by up to 48%. Maximizing β rather than α-diversity within forest and savannah bird communities reduced acquisition costs by up to 15%, and when these solutions included potential carbon credit revenues, acquisition cost reductions up to 32% were achieved. However, the total cost of conservation networks increased exponentially as area targets increased in all scenarios. Our results indicate that carbon credit sales have the potential to enhance conservation outcomes in human-dominated landscapes by reducing the net acquisition costs of land conservation in old and maturing forests essential for the persistence of old forest plant and animal communities. Maximizing β versus α-diversity may further reduce costs by reducing the total area required to meet conservation targets and enhancing landscape heterogeneity. Although the potential value of carbon credit sales declined as a fraction of total acquisition costs, even conservative scenarios using a carbon credit value of $12.5/T suggest reductions in acquisition cost of up to $235 M, indicating that carbon credit sales could substantially reduce the costs of conservation.

  13. Japanese citizens’ preferences regarding voluntary carbon offsets: an experimental social survey of Yokohama and Kitakyushu

    International Nuclear Information System (INIS)

    Nakamura, Hidenori; Kato, Takaaki

    2013-01-01

    This study uses an experimental social survey in two large Japanese cities to explore citizens’ attitudes toward international voluntary carbon offsetting that encourages low carbon development in developing countries. In particular, the study focuses on whether the offsetting is a contribution to meet national target of greenhouse gas (GHG) emissions reduction under the Kyoto Protocol or reduction beyond the national target, using Kyoto credits generated from climate change mitigation projects in developing countries. The study finds that around 40% of the survey respondents chose real carbon offsetting over a gift certificate as compensation for their participation in the survey, around half of whom chose carbon offsetting contribution to the world. However, most of the current Japanese carbon offsetting providers utilise only the carbon offsetting contribution to the Japanese government. Thus, Japanese citizens have significant untapped potential for undertaking more carbon offsetting to meet targets other than national targets. However, the results also show that there is a general lack of understanding regarding the mechanism of carbon offsetting. Carbon offsetting providers in Japan and other countries that may have national self-imposed targets and allowing the usage of international carbon offsetting should therefore be considered, so as to provide individuals with the options of either contributing to their government to help it meet its national target or contributing to the world to help reduce GHG emissions beyond the national targets.

  14. How costly are carbon offsets? A meta-analysis of carbon forest sinks

    NARCIS (Netherlands)

    Kooten, van G.C.; Eagle, A.J.; Manley, J.; Smolak, T.

    2004-01-01

    Carbon terrestrial sinks are seen as a low-cost alternative to fuel switching and reduced fossil fuel use for lowering atmospheric CO2. As a result of agreements reached at Bonn and Marrakech, carbon offsets have taken on much greater importance in meeting Kyoto targets for the first commitment

  15. Willingness to Pay of Air Passengers for Carbon-Offset

    Directory of Open Access Journals (Sweden)

    Rong-Chang Jou

    2015-03-01

    Full Text Available An important source of anthropogenic greenhouse gas (GHG emissions is the air transport sector, which accounts for approximately 2% of global GHG emissions. Therefore, reducing GHG emissions from aircrafts has become a major challenge for transportation authorities worldwide. In recent years, much research has focused on tax ideas related to the CO2 emissions produced by air transport, such as the voluntary carbon offset (VCO. This study investigates the willingness of economy class air passengers to pay to compensate for the CO2 emissions produced during their journeys from Taiwan to Hong Kong. Together with the Spike model, a framework known as the contingent valuation (CV method offers a way to investigate how much the air passenger would be willing to pay to offset a journey’s airplane-generated CO2 emissions. The Spike model was applied to address the problem of zero willingness to pay (WTP. The results obtained in this study are consistent with the results found in previous studies and therefore can provide valuable insights into pricing strategies for airlines.

  16. Using forest carbon credits to offset emissions in the downstream business

    NARCIS (Netherlands)

    Hein, Lars

    2017-01-01

    A forthcoming report by Concawe, entitled Using Forest Carbon Credits to Offset Emissions in the Downstream Business, investigated whether, and how, forest carbon credits can be used to offset emissions from the European refining and road transport sectors. Forest carbon plays a major role in the

  17. Offsetting China's CO2 Emissions by Soil Carbon Sequestration

    International Nuclear Information System (INIS)

    Lal, R.

    2004-01-01

    Fossil fuel emissions of carbon (C) in China in 2000 was about 1 Pg/yr, which may surpass that of the U.S. (1.84 Pg C) by 2020. Terrestrial C pool of China comprises about 35 to 60 Pg in the forest and 120 to 186 Pg in soils. Soil degradation is a major issue affecting 145 Mha by different degradative processes, of which 126 Mha are prone to accelerated soil erosion. Similar to world soils, agricultural soils of China have also lost 30 to 50% or more of the antecedent soil organic carbon (SOC) pool. Some of the depleted SOC pool can be re-sequestered through restoration of degraded soils, and adoption of recommended management practices. The latter include conversion of upland crops to multiple cropping and rice paddies, adoption of integrated nutrient management (INM) strategies, incorporation of cover crops in the rotations cycle and adoption of conservation-effective systems including conservation tillage. A crude estimated potential of soil C sequestration in China is 119 to 226 Tg C/y of SOC and 7 to 138 Tg C/y for soil inorganic carbon (SIC) up to 50 years. The total potential of soil C sequestration is about 12 Pg, and this potential can offset about 25% of the annual fossil fuel emissions in China

  18. Common-image gathers in the offset domain from reverse-time migration

    KAUST Repository

    Zhan, Ge; Zhang, Minyu

    2014-01-01

    Kirchhoff migration is flexible to output common-image gathers (CIGs) in the offset domain by imaging data with different offsets separately. These CIGs supply important information for velocity model updates and amplitude-variation-with-offset (AVO

  19. Handbook of Carbon Offset Programs. Trading Systems, Funds, Protocols and Standards

    Energy Technology Data Exchange (ETDEWEB)

    Kollmuss, Anja; Lazarus, Michael; Lee, Carrie; Polycarp, Clifford (SEI-US (United States)); LeFranc, Maurice (US EPA (United States))

    2010-03-15

    Greenhouse gas (GHG) offsets have long been promoted as an important element of a comprehensive climate policy approach. Offset programs can reduce the overall cost of achieving a given emission goal by enabling emission reductions to occur where costs are lower. Offsets have the potential to deliver sustainability co-benefits, through technology development and transfer. They can also develop human and institutional capacity for reducing emissions in sectors and locations not included in a cap and trade or a mandatory government policy. However, offsets can pose a risk to the environmental integrity of climate actions, especially if issues surrounding additionality, permanence, leakage, quantification and verification are not adequately addressed. The challenge is to design offset programs and policies that can maximize their potential benefits while minimizing their potential risks. This handbook provides a systematic and comprehensive review of existing offset programs. It looks are what offsets are, how offset mechanisms function, and the successes and pitfalls they have encountered. Coverage includes offset programs across the full swath of applications including mandatory and voluntary systems, government regulated and private markets, carbon offset funds, and accounting and reporting protocols such as the WBCSD/WRI GHG Protocol and ISO 14064. Learning from the successes and failures of these programs will be essential to crafting effective climate policy. A reference for regulators, policy makers, business leaders and NGOs concerned with the design and operation of GHG offset programs world-wide

  20. Regional impacts of a program for private forest carbon offset sales

    Science.gov (United States)

    Darius M. Adams; Ralph Alig; Greg Latta; Eric M. White

    2011-01-01

    Policymakers are examining wide range of alternatives for climate change mitigation, including carbon offset sales programs, to enhance sequestration in the forest sector. Under an offset sales program, on-the-ground forestry could change as result of both afforestation and modifications in the management of existing forests. These effects could vary markedly by region...

  1. Analyzing the efficacy of subtropical urban forests in offsetting carbon emissions from cities

    Science.gov (United States)

    Francisco Escobedo; Sebastian Varela; Min Zhao; John E. Wagner; Wayne Zipperer

    2010-01-01

    Urban forest management and policies have been promoted as a tool to mitigate carbon dioxide (CO2) emissions. This study used existing CO2 reduction measures from subtropical Miami-Dade and Gainesville, USA and modeled carbon storage and sequestration by trees to analyze policies that use urban forests to offset carbon emissions. Field data were analyzed, modeled, and...

  2. How costly are carbon offsets : a meta-analysis of forest carbon sinks

    International Nuclear Information System (INIS)

    Van Kooten, G.C.; Eagle, A.J.; Manley, J.; Smolak, T.M.

    2004-01-01

    Carbon terrestrial sinks are one of the many proposed mitigation responses to climate change. Carbon sinks are considered to be a low-cost alternative to fuel switching and reduced fossil fuel consumption for reducing atmospheric carbon dioxide emissions. This study examined the costs of sequestering carbon in terrestrial ecosystems via forestry activities. A meta-regression analysis was used to determine which factors influence the costs of carbon sequestration via forest activities. Important concerns about how the Kyoto Protocol may be implemented were also addressed. The meta-regression analysis was used to examine 981 estimates from 55 studies on the cost of creating carbon offsets using forestry. Baseline cost estimates are US$46.62 to 260.29 per tC. Tree planting and agroforestry increases costs by more than 200 per cent. Costs are lowest when post-harvest storage of carbon in wood products is considered, or when biomass is substituted for fossil fuels in energy production. The meta-analysis also considered land use, land-use change and forestry (LULUCF) policies that increase the carbon sink functions of terrestrial ecosystems. The main motive for using sinks in the accounting process is that they avoid the use of expensive controls for the emission of carbon dioxide and other greenhouse gases. refs., tabs

  3. Barriers to the development of forest carbon offsetting: Insights from British Columbia, Canada.

    Science.gov (United States)

    Peterson St-Laurent, Guillaume; Hagerman, Shannon; Hoberg, George

    2017-12-01

    In recent years, the provision of economic incentives through carbon financing and carbon offsetting has been central to efforts at forest carbon mitigation. However, notwithstanding their potentially important roles in climate policy, forest carbon offsets face numerous barriers which have limited widespread implementation worldwide. This paper uses the case study of the Canadian province of British Columbia to explore the barriers associated with achieving widespread implementation of forest carbon offsets in the next several decades. Drawing on interviews with experts from government, non-governmental organizations, the private sector and First Nations, six main barriers are identified and discussed: (1) deficiencies of carbon markets, (2) limited economic benefits, (3) uncertain climate effectiveness, (4) negative public opinion, (5) limited and uncertain property rights, and (6) governance issues. While respondents from different sectors agreed on various points, divergence was also observed, notably on the trade-off between generating environmentally sound offsets and promoting cost-effective ways to achieve mitigation. We discuss these differences in the context of the goals and objectives of different actors, and offer insights for understanding the uptake (or not) of carbon offset policies. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Factors influencing current interests and motivations of local governments to supply carbon offset credits from urban forestry

    Science.gov (United States)

    N. Poudyal; J. Siry; M. Bowker

    2009-01-01

    This study conducted a nationwide survey of municipal governments in the United States to assess their motivations, willingness, and technical as well as managerial capacities of cities to store carbon and sell carbon offsets. The analysis reveals that cities are fairly interested in selling carbon offsets and their interest in carbon trading is driven by the degree of...

  5. Flexible ambipolar organic field-effect transistors with reverse-offset-printed silver electrodes for a complementary inverter.

    Science.gov (United States)

    Park, Junsu; Kim, Minseok; Yeom, Seung-Won; Ha, Hyeon Jun; Song, Hyenggun; Min Jhon, Young; Kim, Yun-Hi; Ju, Byeong-Kwon

    2016-06-03

    We report ambipolar organic field-effect transistors and complementary inverter circuits with reverse-offset-printed (ROP) Ag electrodes fabricated on a flexible substrate. A diketopyrrolopyrrole-based co-polymer (PDPP-TAT) was used as the semiconductor and poly(methyl methacrylate) was used as the gate insulator. Considerable improvement is observed in the n-channel electrical characteristics by inserting a cesium carbonate (Cs2CO3) as the electron-injection/hole-blocking layer at the interface between the semiconductors and the electrodes. The saturation mobility values are 0.35 cm(2) V(-1) s(-1) for the p-channel and 0.027 cm(2) V(-1) s(-1) for the n-channel. A complementary inverter is demonstrated based on the ROP process, and it is selectively controlled by the insertion of Cs2CO3 onto the n-channel region via thermal evaporation. Moreover, the devices show stable operation during the mechanical bending test using tensile strains ranging from 0.05% to 0.5%. The results confirm that these devices have great potential for use in flexible and inexpensive integrated circuits over a large area.

  6. Analysis of the production and transaction costs of forest carbon offset projects in the USA.

    Science.gov (United States)

    Galik, Christopher S; Cooley, David M; Baker, Justin S

    2012-12-15

    Forest carbon offset project implementation costs, comprised of both production and transaction costs, could present an important barrier to private landowner participation in carbon offset markets. These costs likewise represent a largely undocumented component of forest carbon offset potential. Using a custom spreadsheet model and accounting tool, this study examines the implementation costs of different forest offset project types operating in different forest types under different accounting and sampling methodologies. Sensitivity results are summarized concisely through response surface regression analysis to illustrate the relative effect of project-specific variables on total implementation costs. Results suggest that transaction costs may represent a relatively small percentage of total project implementation costs - generally less than 25% of the total. Results also show that carbon accounting methods, specifically the method used to establish project baseline, may be among the most important factors in driving implementation costs on a per-ton-of-carbon-sequestered basis, dramatically increasing variability in both transaction and production costs. This suggests that accounting could be a large driver in the financial viability of forest offset projects, with transaction costs likely being of largest concern to those projects at the margin. Copyright © 2012 Elsevier Ltd. All rights reserved.

  7. Stakeholders of Voluntary Forest Carbon Offset Projects in China: An Empirical Analysis

    Directory of Open Access Journals (Sweden)

    Derong Lin

    2015-01-01

    Full Text Available Climate change is one of the defining challenges facing the planet. Voluntary forest carbon offset project which has the potential to boost forest carbon storage and mitigate global warming has aroused the global concern. The objective of this paper is to model the game situation and analyze the game behaviors of stakeholders of voluntary forest carbon offset projects in China. A stakeholder model and a Power-Benefit Matrix are constructed to analyze the roles, behaviors, and conflicts of stakeholders including farmers, planting entities, communities, government, and China Green Carbon Foundation. The empirical analysis results show that although the stakeholders have diverse interests and different goals, a win-win solution is still possible through their joint participation and compromise in the voluntary forest carbon offset project. A wide governance structure laying emphasis on benefit balance, equality, and information exchanges and being regulated by all stakeholders has been constructed. It facilitates the agreement among the stakeholders with conflicting or different interests. The joint participation of stakeholders in voluntary forest carbon offset projects might change the government-dominated afforestation/reforestation into a market, where all participators including government are encouraged to cooperate with each other to improve the condition of fund shortage and low efficiency.

  8. The Purchase of Voluntary Carbon Offsets by Australian Consumers: Exploring the Attitude-Behaviour Gap

    DEFF Research Database (Denmark)

    Adamsen, Jannie Mia; Sloan, Sarah

    This research examines the level of environmental awareness among Australian consumers and identifies the factors that affect attitudes and behaviour towards purchasing carbon offset products. Data was obtained from 83 consumers through an online survey to measure knowledge and purchase behaviour...... of carbon offsets, intention for future purchases and attitudes towards the environment. The results demonstrate that an attitude-behaviour gap exists among Australian consumers; while consumers possess strong positive attitudes towards the environment and climate change, this does not translate into actual...

  9. Climate change : observations on the potential role of carbon offsets in climate change legislation

    Science.gov (United States)

    2009-03-05

    Currently, carbon offsets are generated, bought, and sold in two types of markets. In markets such as the United States, which does not have binding limits on emissions, the market is referred to as a voluntary market. Conversely, in the European Uni...

  10. Carbon offsets as an economic alternative to large-scale logging: a case study in Guyana

    Energy Technology Data Exchange (ETDEWEB)

    Osborne, T. [Energy and Resources Group, University of California Berkeley, 310 Barrows Hall, Berkeley CA 94720 (United States); Kiker, C. [Food and Resource Economics Department, University of Florida, PO Box 110240, Gainesville, FL 32611 (United States)

    2005-03-01

    The objective of this study is to analyze the economic viability of carbon-offset projects that avoid logging in Guyana's forests. The results of this case study illustrate the cost effectiveness of alternative land-use options that reduce deforestation and associated greenhouse gas (GHG) emissions. This analysis demonstrates that using Guyana's rainforests for climate change mitigation can generate equivalent revenue to that of conventional large-scale logging without detrimental environmental impacts. At a 12% discount rate, the break-even price for carbon is estimated to be about US$ 0.20/tC. This estimate falls toward the low range of carbon prices for existing carbon offset projects that avoid deforestation.

  11. Family forest landowners' interest in forest carbon offset programs: Focus group findings from the Lake States, USA

    Science.gov (United States)

    Kristell A. Miller; Stephanie A. Snyder; Mike A. Kilgore; Mae A. Davenport

    2014-01-01

    In 2012, focus groups were organized with individuals owning 20+ acres in the Lake States region of the United States (Michigan, Minnesota, and Wisconsin) to discuss various issues related to forest carbon offsetting. Focus group participants consisted of landowners who had responded to an earlier mail-back survey (2010) on forest carbon offsets. Two focus groups were...

  12. How much carbon offsetting and where? Implications of efficiency, effectiveness, and ethicality considerations for public opinion formation

    International Nuclear Information System (INIS)

    Anderson, Brilé; Bernauer, Thomas

    2016-01-01

    A fundamental policy design choice in government-led climate change mitigation is: what role should flexibility mechanisms like carbon offsetting play in reducing greenhouse gas (GHG) emissions. Since public opinion affects the policy choices of government, we investigate how arguments regarding carbon offsetting's economic efficiency, effectiveness, and ethicality, which have been key points in the public debate, impact the public's preferences. We fielded an online framing experiment in the United States (N=995) to empirically identify how arguments for and against carbon offsetting influence public preferences for the inclusion of offsetting in national GHG mitigation policy. We find that the public's support for international offsetting increases and support for reductions at their source (i.e. within firms' own operations) diminishes when considerations of economic efficiency gains are at the forefront. Support for offsetting declines when individuals are confronted with arguments concerning its effectiveness and ethicality, which suggests that future policies will require clear standards of additionality in order to address these concerns. Moreover, we find that how carbon offsetting is framed matters even amongst climate skeptics and support could potentially be enhanced via improved communication on efficiency gains. - Highlights: •We use a framing survey experiment to study public opinion on carbon offsetting. •Efficiency gains increase public support for international carbon offsetting. •Concerns about effectiveness/additionality and ethicality reduce support. •More information on efficiency gains and strengthening additionality could help increase support.

  13. Carbon Offsets in California: What Role for Earth Scientists in the Policy Process? (Invited)

    Science.gov (United States)

    Cullenward, D.; Strong, A. L.

    2013-12-01

    This talk addresses the policy structure in California for developing and approving carbon offset protocols, which rely on findings from the environmental and earth sciences communities. In addition to providing an overview of the legal requirements of carbon offsets, we describe a series of case studies of how scientists can engage with policymakers. Based on those experiences, we suggest ways for the earth sciences community to become more involved in climate policy development. California's climate law, known as AB 32, requires that major sectors of the state's economy reduce their emissions to 1990 levels by 2020. As part of AB 32, the California Air Resources Board created a cap-and-trade market to ensure compliance with the statutory target. Under this system, regulated companies have to acquire tradable emissions permits (called 'compliance instruments') for the greenhouse gas emissions they release. The State allocates a certain number of allowances to regulated entities through a mixture of auctions and free transfers, with the total number equal to the overall emissions target; these allowances, along with approved offsets credits, are the compliance instruments that regulated entities are required to obtain by law. One of the key policy design issues in California's cap-and-trade market concerns the use of carbon offsets. Under AB 32, the Air Resources Board can issue offset credits to project developers who reduce emissions outside of the capped sectors (electricity, industry, and transportation)--or even outside of California--pursuant to approved offset protocols. Project developers then sell the credits to regulated companies in California. Essentially, offsets allow regulated entities in California to earn credit for emissions reductions that take place outside the scope of AB 32. Many regulated entities and economists are in favor of offsets because they view them as a source of low-cost compliance instruments. On the other hand, critics argue that

  14. Inter-trading permanent emissions credits and rented temporary carbon emissions offsets. Some issues and alternatives

    International Nuclear Information System (INIS)

    Sedjo, Roger A.; Marland, Gregg

    2003-01-01

    Permit trading among polluting parties is now firmly established as a policy tool in a range of environmental policy areas. The Kyoto Protocol accepts the principle that sequestration of carbon in the terrestrial biosphere can be used to offset emissions of carbon from fossil fuel combustion and outlines mechanisms. Although the lack of guaranteed permanence of biological offsets is often viewed as a defect, this paper argues that the absence of guaranteed permanence need not be a fundamental problem. We view carbon emissions as a liability issue. One purpose of an emissions credit system is to provide the emitter with a means to satisfy the carbon liability associated with her firm's (or country's) release of carbon into the atmosphere. We have developed and here expand on a rental approach, in which sequestered carbon is explicitly treated as temporary: the emitter temporarily satisfies his liability by temporarily 'parking' his liability, for a fee, in a terrestrial carbon reservoir, or 'sink,' such as a forest or agricultural soil. Finally, the paper relates the value of permanent and temporary sequestration and argues that both instruments are tradable and have a high degree of substitutability that allows them to interact in markets

  15. High resolution remote sensing for reducing uncertainties in urban forest carbon offset life cycle assessments.

    Science.gov (United States)

    Tigges, Jan; Lakes, Tobia

    2017-10-04

    Urban forests reduce greenhouse gas emissions by storing and sequestering considerable amounts of carbon. However, few studies have considered the local scale of urban forests to effectively evaluate their potential long-term carbon offset. The lack of precise, consistent and up-to-date forest details is challenging for long-term prognoses. Therefore, this review aims to identify uncertainties in urban forest carbon offset assessment and discuss the extent to which such uncertainties can be reduced by recent progress in high resolution remote sensing. We do this by performing an extensive literature review and a case study combining remote sensing and life cycle assessment of urban forest carbon offset in Berlin, Germany. Recent progress in high resolution remote sensing and methods is adequate for delivering more precise details on the urban tree canopy, individual tree metrics, species, and age structures compared to conventional land use/cover class approaches. These area-wide consistent details can update life cycle inventories for more precise future prognoses. Additional improvements in classification accuracy can be achieved by a higher number of features derived from remote sensing data of increasing resolution, but first studies on this subject indicated that a smart selection of features already provides sufficient data that avoids redundancies and enables more efficient data processing. Our case study from Berlin could use remotely sensed individual tree species as consistent inventory of a life cycle assessment. However, a lack of growth, mortality and planting data forced us to make assumptions, therefore creating uncertainty in the long-term prognoses. Regarding temporal changes and reliable long-term estimates, more attention is required to detect changes of gradual growth, pruning and abrupt changes in tree planting and mortality. As such, precise long-term urban ecological monitoring using high resolution remote sensing should be intensified

  16. Offset of the potential carbon sink from boreal forestation by decreases in surface albedo

    International Nuclear Information System (INIS)

    Betts, R.A.

    2000-01-01

    Carbon uptake by forestation is one method proposed to reduce net carbon dioxide emissions to the atmosphere and so limit the radiative forcing of climate change. But the overall impact of forestation on climate will also depend on other effects associated with the creation of new forests. In particular the albedo of a forested landscape is generally lower than that of cultivated land, especially when snow is lying, and decreasing albedo exerts a positive radiative forcing on climate. Here I simulate the radiative forcings associated with changes in surface albedo as a result of forestation in temperate and boreal forest areas, and translate these forcings into equivalent changes in local carbon stock for comparison with estimated carbon sequestration potentials. I suggest that in many boreal forest areas, the positive forcing induced by decreases in albedo can offset the negative forcing that is expected from carbon sequestration. Some high-latitude forestation activities may therefore increase climate change, rather that mitigating it as intended

  17. Willingness to pay for carbon offset certification and co-benefits among (high-)flying young adults in the UK

    International Nuclear Information System (INIS)

    MacKerron, George J.; Mourato, Susana; Egerton, Catrin; Gaskell, Christopher; Parpia, Aimie

    2009-01-01

    Voluntary carbon offsets represent a growing share of the carbon market as a whole, and have the potential to contribute to meeting greenhouse gas emissions targets and reducing anthropogenic climate change. Certain offset project types may also deliver co-benefits including safeguarding or promoting biodiversity, supporting human development and poverty reduction, and enabling market and technology development in low-carbon sectors. These co-benefits might encourage consumers to participate in the voluntary offset market, depending on their effects both on consumers' willingness to pay (WTP) for offsets and on implementation costs. However, the offset market is not yet sufficiently developed to give a clear indication of consumer WTP for offsets with varying attributes. This exploratory stated preference study therefore uses a choice experiment to estimate WTP for certified and uncertified offsets, with or without these specific co-benefits, in an aviation context. It is, to the best of our knowledge, the first to do so. Our results suggest that uptake of voluntary offsets may be encouraged by investing in projects with co-benefits and by emphasising those co-benefits to consumers. They also suggest that certification regimes will add value to offsets, helping compensate for increased costs, provided that consumers are made fully aware of them. (author)

  18. Site productivity and forest carbon stocks in the United States: Analysis and implications for forest offset project planning

    Science.gov (United States)

    Coeli M. Hoover; James E. Smith

    2012-01-01

    The documented role of United States forests in sequestering carbon, the relatively low cost of forest-based mitigation, and the many co-benefits of increasing forest carbon stocks all contribute to the ongoing trend in the establishment of forest-based carbon offset projects. We present a broad analysis of forest inventory data using site quality indicators to provide...

  19. Etude Climat no. 31 'Carbon offset projects in the agricultural sector'

    International Nuclear Information System (INIS)

    Foucherot, Claudine; Bellassen, Valentin

    2012-01-01

    Among the publications of CDC Climat Research, 'Climate Reports' offer in-depth analyses on a given subject. This issue addresses the following points: The agricultural sector accounts for 14% of global anthropogenic greenhouse gas emissions. If we also take into account carbon emissions and sequestration from upstream - production of fertilisers, deforestation, etc. - and downstream - bio-energies, etc. - the share rises to 30%. Many practices and technologies enable agriculture's impact on climate change to be reduced. According to a number of estimates that are summarised in this research, the agricultural sector's mitigation potential is of the same order of magnitude as its emissions over a period of 30 years. However, changing agricultural practices comes at a cost, and in most cases such changes are not made without economic incentives. Carbon offsetting projects are one of the economic tools available to reduce agricultural emissions by paying for metric tons of avoided CO 2 e emissions. A summary of the emission reductions enabled by agricultural projects to date is provided in this report. It covers most projects certified by quality assurance standards, including those set up by the Kyoto Protocol (Clean Development Mechanism and Joint Implementation) and those in the voluntary market (Verified Carbon Standard, Climate Action Reserve, Gold Standard, Chicago Climate Exchange, and American Carbon Registry). The assessment drawn up on this basis shows that emission reductions enabled through carbon offsetting are thousand times lower than actual emissions and their potential mitigation. Agricultural projects have reduced emissions by 14 MtCO 2 e in 2010, i.e. 7% of the reductions generated by all carbon offset projects across all sectors for this year. Initiatives focus on three technologies: - bio-energies (crop residues), - methanation of livestock waste, - and soil carbon sequestration using no-till practices. This is very little compared with the large

  20. Rewetting of semi-dried ink patterns by vapour annealing for developing a reflow process in reverse offset printing

    International Nuclear Information System (INIS)

    Kusaka, Yasuyuki; Ushijima, Hirobumi; Sugihara, Kazuyoshi; Koutake, Masayoshi

    2017-01-01

    A process for reflowing patterned materials for reverse offset printing was developed, with the aim of mitigating the step-coverage problem in multilayered devices. The proposed reflow process involves a single step of vapour annealing at moderate temperatures ranging from 60 to 70 °C. This step successfully changes the height profile of semi-dried ink patterns formed on a silicone blanket, from an initially rectangular shape to a rounded shape. A systematic investigation on the effects of various vapour species and vapour temperatures on the reflow process revealed that the miscibility between the vapour and the ink, and a low boiling point of the respective solvent (high vapour pressure) are the prerequisites for successful reflows of semi-dried ink layers patterned on a silicone blanket. The results suggested that the rewetting of previously semi-dried patterns is the main mechanism in the reflow process, which led to a change in the height profile. Furthermore, the reflowed patterns demonstrated almost identical peak-height thicknesses, irrespective of the width of the patterns. This is a unique property that is unattainable by other printing methods, including gravure offset printing and microcontact printing, wherein printed patterns have rounded shapes without a reflow process, but their thickness inevitably depends on the pattern sizes. (technical note)

  1. Prospects for international trade in environmental services: An analysis of international carbon emission off-sets

    International Nuclear Information System (INIS)

    Swisher, J.N.

    1991-01-01

    This dissertation presents a case study analysis in which the costs to a US electric utility of reducing its carbon dioxide (CO 2 ) emissions are compared with the costs of carbon-saving forestry projects in Costa Rica and Guatemala. The results show that a large electric utility in the south-central US would find it relatively inexpensive, even profitable given a conducive regulatory treatment, to reduce its CO 2 emissions by a few percent over the next ten years, through direct investment in energy end-use efficiency improvements. In comparison, the costs of the forestry projects studied in Central America range from $1/TC to a worst-case value of about $55/TC, with most project costs between $5 and $13/TC, depending on the type of project, the climate, and the opportunity cost of land. The total amount of CO 2 storage potential is significant, about 100 million tons per country, but not enough to suggest that forestry can offset more than a few percent of global CO 2 emissions from fossil fuel use. These case studies suggest that international trade in the environmental service of reducing global CO 2 accumulation could have significant economic and ecological benefits. A transaction in which a utility pays for forestry projects in exchange for credit against an emission reduction policy is an example of an international carbon emission offset (ICEO). ICEO's could provide a currency for funding carbon-saving services as a way to comply with national policies to reduce CO 2 emissions, as long as compliance is allowed through investments in other countries. This type of North-South transfer is necessary to reconcile economic efficiency and international equity, because of the disparity between the national allocations of responsibility for greenhouse gas emissions and opportunities for emission reductions

  2. Creating Carbon Offsets in Agriculture through No-Till Cultivation. A Meta-Analysis of Costs and Carbon Benefits

    International Nuclear Information System (INIS)

    Manley, J.; Van Kooten, G.C.; Moeltner, K.; Johnson, D.W.

    2005-01-01

    Carbon terrestrial sinks are often seen as a low-cost alternative to fuel switching and reduced fossil fuel use for lowering atmospheric CO2. To determine whether this is true for agriculture, one meta-regression analysis (52 studies, 536 observations) examines the costs of switching from conventional tillage to no-till, while another (51 studies, 374 observations) compares carbon accumulation under the two practices. Costs per ton of carbon uptake are determined by combining the two results. The viability of agricultural carbon sinks is found to vary by region and crop, with no-till representing a low-cost option in some regions (costs of less than $10 per tC), but a high-cost option in others (costs of 100-$400 per tC). A particularly important finding is that no-till cultivation may store no carbon at all if measurements are taken at sufficient depth. In some circumstances no-till cultivation may yield a triple dividend of carbon storage, increased returns and reduced soil erosion, but in many others creating carbon offset credits in agricultural soils is not cost effective because reduced tillage practices store little or no carbon

  3. Urban forests' potential to supply marketable carbon emission offsets: a survey of municipal governments in the United States

    Science.gov (United States)

    Neelam C. Poudyal; Jacek P. Siry; J. M. Bowker

    2010-01-01

    This study assesses the motivation, willingness, and technical as well as managerial capacities of U.S. cities to store carbon and sell carbon offsets. Based on a national survey of urban foresters, arborists, and other officials responsible for urban forest management within U.S. municipal governments, results indicate that local governments are interested in selling...

  4. Biomass offsets little or none of permafrost carbon release from soils, streams, and wildfire: an expert assessment

    Science.gov (United States)

    Benjamin W Abbott; Jeremy B Jones; Edward A G Schuur; F Stuart Chapin III; William B Bowden; M Syndonia Bret-Harte; Howard E Epstein; Michael D Flannigan; Tamara K Harms; Teresa N Hollingsworth; Michelle C Mack; A David McGuire; Susan M Natali; Adrian V Rocha; Suzanne E Tank; Merritt R Turetsky; Jorien E Vonk; Kimberly P Wickland; George R Aiken; Heather D Alexander; Rainer M W Amon; Brian W Benscoter; Yves Bergeron; Kevin Bishop; Olivier Blarquez; Amy L Breen; Ishi Buffam; Yihua Cai; Christopher Carcaillet; Sean K Carey; Jing M Chen; Han Y H Chen; Torben R Christensen; Lee W Cooper; J Hans C Cornelissen; William J de Groot; Thomas H DeLuca; Ellen Dorrepaal; Ned Fetcher; Jacques C Finlay; Bruce C Forbes; Nancy H F French; Sylvie Gauthier; Martin P Girardin; Scott J Goetz; Johann G Goldammer; Laura Gough; Paul Grogan; Laodong Guo; Philip E Higuera; Larry Hinzman; Feng Sheng Hu; Gustaf Hugelius; Elchin E Jafarov; Randi Jandt; Jill F Johnstone; Eric S Kasischke; Gerhard Kattner; Ryan Kelly; Frida Keuper; George W Kling; Pirkko Kortelainen; Jari Kouki; Peter Kuhry; Hjalmar Laudon; Isabelle Laurion; Robie W Macdonald; Paul J Mann; Pertti J Martikainen; James W McClelland; Ulf Molau; Steven F Oberbauer; David Olefeldt; David Par??; Marc-Andr?? Parisien; Serge Payette; Changhui Peng; Oleg S Pokrovsky; Edward B Rastetter; Peter A Raymond; Martha K Raynolds; Guillermo Rein; James F Reynolds; Martin Robards; Brendan M Rogers; Christina Sch??del; Kevin Schaefer; Inger K Schmidt; Anatoly Shvidenko; Jasper Sky; Robert G M Spencer; Gregory Starr; Robert G Striegl; Roman Teisserenc; Lars J Tranvik; Tarmo Virtanen; Jeffrey M Welker; Sergei Zimov

    2016-01-01

    As the permafrost region warms, its large organic carbon pool will be increasingly vulnerable to decomposition, combustion, and hydrologic export. Models predict that some portion of this release will be offset by increased production of Arctic and boreal biomass; however, the lack of robust estimates of net carbon balance increases the risk of further overshooting...

  5. Analysis of the German market for voluntary carbon offsetting; Analyse des deutschen Marktes zur freiwilligen Kompensation von Treibhausgasemissionen

    Energy Technology Data Exchange (ETDEWEB)

    Kind, Christian; Duwe, Sebastian; Taenzler, Dennis; Reuster, Lena [adelphi research gGmbH, Berlin (Germany); Kleemann, Max; Krebs, Jan-Marten [sustainable AG, Muenchen (Germany)

    2010-12-15

    In the past years the market for voluntary carbon offsetting has developed rapidly. Certificates sold on this market originate partly from the compliance market, i.e. from projects of the Clean Development Mechanism and the Joint Implementation. Mostly, however, certificates stem from projects of the voluntary carbon market. Voluntary carbon offsetting can serve as another mechanism to efficiently prevent emissions, while at the same time achieving co-benefits. Very little is known however of the exact state of the voluntary carbon market, e.g. factors like business volume, market actors, origin of certificates or the efficacy of the voluntary market. Analyses of the market on the global market for voluntary offsetting do exist (ENDS, Hamilton et al. 2007, 2008, 2009); however they do not allow any conclusions for the market situation in Germany. This study aims at closing this gap. From the end of 2009 until the beginning of 2010 adelphi and sustainable interviewed providers of offset services, intermediaries, certifiers and consumers like businesses and public institutions on their activities in the voluntary carbon offset market in Germany. (orig.)

  6. The Willingness of Non-Industrial Private Forest Owners to Enter California's Carbon Offset Market.

    Science.gov (United States)

    Kelly, Erin Clover; Gold, Gregg J; Di Tommaso, Joanna

    2017-11-01

    While non-industrial private forest landowners have a significant amount of forest landholdings in the US, they are underrepresented in the California cap-and-trade market forest offset program. Additional participation could benefit both the market and non-industrial private forest landowners. We developed a mail questionnaire which served as both a survey instrument and outreach tool about the market. Questions covered forest ownership objectives, landowners' future plans for forests, views of climate change, and attitudes and intentions regarding forest carbon offset project development. We sampled from five Northern California counties for a total of 143 usable surveys. Three different groups of landowners were identified based on their management objectives: amenity (including protecting nature and recreation); legacy (passing land to children and/or maintaining a farm or ranch); and income. Landowner objective groups differed on several key variables, particularly related to potential motivations for joining the market, while all landowners expressed concerns about protocol requirements. Regardless of ownership objectives, over half expressed that receiving revenue from their forests would be an important motivator to join, though most were unwilling to satisfy protocol requirements, even after learning of the potential benefits of program participation. Thus, participation appears to be limited by the costly and complex project development process, as well as a lack of landowner awareness. Extending these lessons, we assert that different landowners may approach payment for ecosystem services programs with different needs, awareness, and motivations, which provide important lessons for those who conduct landowner outreach and for PES program designers.

  7. The Willingness of Non-Industrial Private Forest Owners to Enter California's Carbon Offset Market

    Science.gov (United States)

    Kelly, Erin Clover; Gold, Gregg J.; Di Tommaso, Joanna

    2017-11-01

    While non-industrial private forest landowners have a significant amount of forest landholdings in the US, they are underrepresented in the California cap-and-trade market forest offset program. Additional participation could benefit both the market and non-industrial private forest landowners. We developed a mail questionnaire which served as both a survey instrument and outreach tool about the market. Questions covered forest ownership objectives, landowners' future plans for forests, views of climate change, and attitudes and intentions regarding forest carbon offset project development. We sampled from five Northern California counties for a total of 143 usable surveys. Three different groups of landowners were identified based on their management objectives: amenity (including protecting nature and recreation); legacy (passing land to children and/or maintaining a farm or ranch); and income. Landowner objective groups differed on several key variables, particularly related to potential motivations for joining the market, while all landowners expressed concerns about protocol requirements. Regardless of ownership objectives, over half expressed that receiving revenue from their forests would be an important motivator to join, though most were unwilling to satisfy protocol requirements, even after learning of the potential benefits of program participation. Thus, participation appears to be limited by the costly and complex project development process, as well as a lack of landowner awareness. Extending these lessons, we assert that different landowners may approach payment for ecosystem services programs with different needs, awareness, and motivations, which provide important lessons for those who conduct landowner outreach and for PES program designers.

  8. The Role of Public-Private Partnerships in Local Infrastructure: the Case of Carbon Offset Projects

    International Nuclear Information System (INIS)

    Teichmann, Dorothee

    2011-01-01

    Investment in low carbon infrastructure is considered as an important component of the fight against climate change. The mechanisms of climate regulation (such as carbon offsets) transfer to project developers the risks associated with reducing emissions of greenhouse gas (GHG) emissions, i.e. operational and technological risk, or risks associated with the environmental monitoring and the regulatory mechanism itself. The success of projects - and thus their ability to attract private capital - depends importantly on the risk sharing arrangements between the private and public partners involved in the project. We show that the delegation of tasks between the partners can create risks that affect the environmental effectiveness and economic efficiency of the project. Contracts need to be well designed to mitigate those risks. For a sample of landfill gas flaring projects financed under the Clean Development Mechanism, it is shown that the out-sourcing of the provision of technology creates additional risks. The out-sourcing of the development of the Project Design Documents as required by UNFCCC and the separation of the operation of the landfill and the CDM project appear to be manageable by risk sharing arrangements between partners. In the latter case, each partner should bear the risk associated with his own responsibility. In fact, if carbon revenues are the only income stream for the CDM project developer, the incentive to reduce GHG emissions is maintained. (author)

  9. Opportunities and Challenges for Terrestrial Carbon Offsetting and Marketing, with Some Implications for Forestry in the UK

    Directory of Open Access Journals (Sweden)

    Maria Nijnik

    2010-12-01

    Full Text Available Background and Purpose: Climate change and its mitigation have become increasingly high profile issues since the late 1990s, with the potential of forestry in carbon sequestration a particular focus. The purpose of this paper is to outline the importance of socio-economic considerations in this area. Opportunities for forestry to sequester carbon and the role of terrestrial carbon uptake credits in climate change negotiations are addressed, together with the feasibility of bringing terrestrial carbon offsets into the regulatory emission trading scheme. The paper discusses whether or not significant carbon offsetting and trading will occur on a large scale in the UK or internationally. Material and Methods: The paper reviews the literature on the socio-economic aspects of climate change mitigation via forestry (including the authors’ research on this topic to assess the potential for carbon offsetting and trading, and the likely scale of action. Results and Conclusion: We conclude that the development of appropriate socio-economic framework conditions (e.g. policies, tenure rights, including forest carbon ownership, and markets and incentives for creating and trading terrestrial carbon credits are important in mitigating climate change through forestry projects, and we make suggestions for future research that would be required to support such developments.

  10. Investing carbon offsets in woody forests - the best solution for California?

    Science.gov (United States)

    Dass, P.; Houlton, B. Z.; Warlind, D.

    2016-12-01

    Increasing atmospheric carbon dioxide (CO2) concentrations from fossil fuel combustion, land conversion and biomass burning are principal to climate change and its manifolds risks on human health, the environment and the global economy. Effective mitigation of climate change thereby involves cutting fossil-fuel emissions at the source or capturing CO2 in engineered or natural ecosystem stocks, or both. The lifetime of CO2 in the atmosphere exceeds 100 years; thus, in the case of CO2 sequestration by natural ecosystems, the residence time of soil and vegetation carbon(C) is a critical component of the efficacy of C offsets in the marketplace, particularly in local to global Cap and Trade frameworks. Here we use a land-surface model to analyze trade-offs in C investment into natural forest vs. grassland sinks and the role of fire in driving the most sustained pathways of CO2 sequestration under Cap and Trade policies. We focus on the California Climate Exchange and AB32 as the model system for examining risks of CO2 offset investments by considering model-based scenarios of (a.) natural woody forests (mixture of trees, shrubs and grasslands) or (b.) pure grasslands (no woody vegetation allowed) under conditions of drought and changes in fire frequency. While forests capture more carbon than grasslands, the latter stores a greater fraction of C in below ground stocks, making it less vulnerable to climate-driven disturbances. Preliminary results for simulations carried out for the last century for the state of California corroborate this hypothesis: while trees capture 100 GgCyr-1 more than grasses, CO2 emissions due to fire is less by 20 GgCyr-1 from grasslands when compared to forest environments. Since policies need to regard potential future scenarios, we present results that investigate how the alternate systems of trees and grasses respond to (i.) the environmental conditions of the no-mitigation scenario (RCP 8.5) through the year 2100, (ii.) periods of extended

  11. Beyond pure offsetting: Assessing options to generate Net-Mitigation-Effects in carbon market mechanisms

    International Nuclear Information System (INIS)

    Warnecke, Carsten; Wartmann, Sina; Höhne, Niklas; Blok, Kornelis

    2014-01-01

    The current project-based carbon market mechanisms such as the Clean Development Mechanism (CDM) and the Joint Implementation (JI) do not have a direct impact on global greenhouse gas emission levels, because they only replace or offset emissions. Nor do they contribute to host country's national greenhouse gas emission reduction targets. Contributions to net emission reductions in host countries is likely to become mandatory in new mechanisms under development such as in the framework for various approaches, a new market-based mechanism and even in a reformed JI. This research analysed the question if approaches for carbon market-based mechanisms exist that allow the generation of net emission reductions in host countries while keeping project initiation attractive. We present a criteria-based assessment method and apply it for four generic options in existing mechanisms and derive implications for future mechanism frameworks. We identified the application of “discounts” on the amount of avoided emissions for the issuance of carbon credits and “standardisation below business as usual” as most promising options over “limiting the crediting period” and “over-conservativeness”. We propose to apply these options differentiated over project types based on internal rate of return to ensure cost-efficiency and attractiveness. - Highlights: • Options for net emission reductions of market-based mechanisms are assessed. • Research combines past and current views for project and sector-based mechanisms. • Implementation ensures initiation of mitigation activities is not discouraged. • Important insights for methodological design of new market-based mechanisms. • Profitability-based approach for project-based mechanisms suggested

  12. Radiocarbon age-offsets in an arctic lake reveal the long-term response of permafrost carbon to climate change

    Science.gov (United States)

    Gaglioti, Benjamin V.; Mann, Daniel H.; Jones, Benjamin M.; Pohlman, John W.; Kunz, Michael L.; Wooller, Matthew J.

    2014-01-01

    Continued warming of the Arctic may cause permafrost to thaw and speed the decomposition of large stores of soil organic carbon (OC), thereby accentuating global warming. However, it is unclear if recent warming has raised the current rates of permafrost OC release to anomalous levels or to what extent soil carbon release is sensitive to climate forcing. Here we use a time series of radiocarbon age-offsets (14C) between the bulk lake sediment and plant macrofossils deposited in an arctic lake as an archive for soil and permafrost OC release over the last 14,500 years. The lake traps and archives OC imported from the watershed and allows us to test whether prior warming events stimulated old carbon release and heightened age-offsets. Today, the age-offset (2 ka; thousand of calibrated years before A.D. 1950) and the depositional rate of ancient OC from the watershed into the lake are relatively low and similar to those during the Younger Dryas cold interval (occurring 12.9–11.7 ka). In contrast, age-offsets were higher (3.0–5.0 ka) when summer air temperatures were warmer than present during the Holocene Thermal Maximum (11.7–9.0 ka) and Bølling-Allerød periods (14.5–12.9 ka). During these warm times, permafrost thaw contributed to ancient OC depositional rates that were ~10 times greater than today. Although permafrost OC was vulnerable to climate warming in the past, we suggest surface soil organic horizons and peat are presently limiting summer thaw and carbon release. As a result, the temperature threshold to trigger widespread permafrost OC release is higher than during previous warming events.

  13. Biomass offsets little or none of permafrost carbon release from soils, streams, and wildfire: an expert assessment

    Science.gov (United States)

    Benjamin W. Abbott,; Jeremy B. Jones,; Edward A.G. Schuur,; F.S. Chapin, III; Bowden, William B.; M. Syndonia Bret-Harte,; Howard E. Epstein,; Michael D. Flannigan,; Tamara K. Harms,; Teresa N. Hollingsworth,; Mack, Michelle C.; McGuire, A. David; Susan M. Natali,; Adrian V. Rocha,; Tank, Suzanne E.; Merrit R. Turetsky,; Jorien E. Vonk,; Wickland, Kimberly P.; Aiken, George R.

    2016-01-01

    As the permafrost region warms, its large organic carbon pool will be increasingly vulnerable to decomposition, combustion, and hydrologic export. Models predict that some portion of this release will be offset by increased production of Arctic and boreal biomass; however, the lack of robust estimates of net carbon balance increases the risk of further overshooting international emissions targets. Precise empirical or model-based assessments of the critical factors driving carbon balance are unlikely in the near future, so to address this gap, we present estimates from 98 permafrost-region experts of the response of biomass, wildfire, and hydrologic carbon flux to climate change. Results suggest that contrary to model projections, total permafrost-region biomass could decrease due to water stress and disturbance, factors that are not adequately incorporated in current models. Assessments indicate that end-of-the-century organic carbon release from Arctic rivers and collapsing coastlines could increase by 75% while carbon loss via burning could increase four-fold. Experts identified water balance, shifts in vegetation community, and permafrost degradation as the key sources of uncertainty in predicting future system response. In combination with previous findings, results suggest the permafrost region will become a carbon source to the atmosphere by 2100 regardless of warming scenario but that 65%–85% of permafrost carbon release can still be avoided if human emissions are actively reduced.

  14. Carbon emission offsets for aviation-generated emissions due to international travel to and from New Zealand

    International Nuclear Information System (INIS)

    Smith, Inga J.; Rodger, Craig J.

    2009-01-01

    International air transport emissions are not subject to liability under the Kyoto Protocol. However, pressure is mounting globally for international aviation to be included in post-Kyoto arrangements. In the absence of international collective action, a number of so-called carbon offsetting schemes have emerged that allow individual travellers and companies to compensate for their international air travel emissions. These schemes offer technological solutions, such as planting sink forests to sequester emissions. To consider the implications of future collective action, this paper presents a case study assessment of the physical feasibility of five schemes for all short duration journeys to and from New Zealand. This is the first comprehensive national-level case study assessment of competing offsetting options for international aviation emissions in the peer-reviewed literature. The CO 2 -e emissions produced by the air travel of international visitors to New Zealand, and for New Zealand residents travelling overseas, is calculated in this paper to be 7893 and 3948 Gg, respectively, in 2005. It is then shown that no single offsetting scheme targeted inside the country appears physically and/or politically realistic. This indicates the sheer size of these emissions, and the challenge that the international community faces for collective action on this matter. (author)

  15. Potential increases in natural disturbance rates could offset forest management impacts on ecosystem carbon stocks.

    Science.gov (United States)

    John B. Bradford; Nicholas R. Jensen; Grant M. Domke; Anthony W. D' Amato

    2013-01-01

    Forested ecosystems contain the majority of the world’s terrestrial carbon, and forest management has implications for regional and global carbon cycling. Carbon stored in forests changes with stand age and is affected by natural disturbance and timber harvesting. We examined how harvesting and disturbance interact to influence forest carbon stocks over the Superior...

  16. Carbon storage and emissions offset potential in an African dry forest, the Arabuko-Sokoke Forest, Kenya.

    Science.gov (United States)

    Glenday, Julia

    2008-07-01

    Concerns about rapid tropical deforestation, and its contribution to rising atmospheric concentrations of greenhouse gases, increase the importance of monitoring terrestrial carbon storage in changing landscapes. Emerging markets for carbon emission offsets may offer developing nations needed incentives for reforestation, rehabilitation, and avoided deforestation. However, relatively little empirical data exists regarding carbon storage in African tropical forests, particularly for those in arid or semi-arid regions. Kenya's 416 km(2) Arabuko-Sokoke Forest (ASF) is the largest remaining fragment of East African coastal dry forest and is considered a global biodiversity hotspot (Myers et al. 2000), but has been significantly altered by past commercial logging and ongoing extraction. Forest carbon storage for ASF was estimated using allometric equations for tree biomass, destructive techniques for litter and herbaceous vegetation biomass, and spectroscopy for soils. Satellite imagery was used to assess land cover changes from 1992 to 2004. Forest and thicket types (Cynometra webberi dominated, Brachystegia spiciformis dominated, and mixed species forest) had carbon densities ranging from 58 to 94 Mg C/ha. The ASF area supported a 2.8-3.0 Tg C carbon stock. Although total forested area in ASF did not change over the analyzed time period, ongoing disturbances, quantified by the basal area of cut tree stumps per sample plot, correlated with decreased carbon densities. Madunguni Forest, an adjoining forest patch, lost 86% of its forest cover and at least 76% of its terrestrial carbon stock in the time period. Improved management of wood harvesting in ASF and rehabilitation of Madunguni Forest could substantially increase terrestrial carbon sequestration in the region.

  17. Assessment of the potential of urban organic carbon dynamics to off-set urban anthropogenic emissions

    Science.gov (United States)

    Gottschalk, P.; Churkina, G.; Wattenbach, M.; Cubasch, U.

    2010-12-01

    The impact of urban systems on current and future global carbon emissions has been a focus of several studies. Many mitigation options in terms of increasing energy efficiency are discussed. However, apart from technical mitigation potential urban systems also have a considerable biogenic potential to mitigate carbon through an optimized management of organic carbon pools of vegetation and soil. Berlin city area comprises almost 50% of areas covered with vegetation or largely covered with vegetation. This potentially offers various areas for carbon mitigation actions. To assess the mitigation potentials our first objective is to estimate how large current vegetation and soil carbon stocks of Berlin are. We use publicly available forest and soil inventories to calculate soil organic carbon of non-pervious areas and forest standing biomass carbon. This research highlights data-gaps and assigns uncertainty ranges to estimated carbon resources. The second objective is to assess the carbon mitigation potential of Berlin’s vegetation and soils using a biogeochemical simulation model. BIOME-BGC simulates carbon-, nitrogen- and water-fluxes of ecosystems mechanistically. First, its applicability for Berlin forests is tested at selected sites. A spatial application gives an estimate of current net carbon fluxes. The application of such a model allows determining the sensitivity of key ecosystem processes (e.g. carbon gains through photosynthesis, carbon losses through decomposition) towards external drivers. This information can then be used to optimise forest management in terms of carbon mitigation. Initial results of Berlin’s current carbon stocks and its spatial distribution and preliminary simulations results will be presented.

  18. Uses of Single Photon Lidar (SPL) in the Monitoring Reporting and Verification of afforestation and carbon offset projects

    Science.gov (United States)

    Dolan, K. A.; DeCola, P.; Dubayah, R.; Huang, W.; Hurtt, G. C.; Tang, H.; Whitehurst, A.

    2017-12-01

    As societies move towards increased valuation of carbon through markets, regulations, and voluntary agreements the need to develop comprehensive, traceable and continuous, carbon monitoring, reporting and verification (MRV) systems has risen in priority locally to globally. Future landuse decisions, to conserve, develop or reforest, rests on the perceived valuation of anthropogenic and ecological benefits, as well as our ability to measure, report, verify, and "project" those benefits. Two carbon markets in the US, the Regional Green House Gas Initiative (RGGI) and the California Cap and Trade, accept carbon credits or offsets from the forestry sector from avoided emissions through forest conservation, by the enhancement land carbon sequestration through improved forest management and through reforestation projects. These investments often go beyond state, and national boundaries. For example, Blue Source a leading investment firm in forest carbon credits invested in over 20,000 acres of Pennsylvania forests in collaboration with The Nature Conservatory (TNC) Forest Conservation Program. Further local to national governments are writing their own climate policies and regulations and are setting targets for forest carbon storage and sequestration as part of their climate action portfolios. Yet, often little resources or effort is left for monitoring the success of projects such as afforestation initiatives once they have been completed. While field data is critical to monitoring efforts, covering the vast areas needed and getting accurate structural information from field campaigns alone can be difficult and costly. The use of Lidar as a supplement to other developed forest monitoring techniques has advanced significantly over the last decade. Here we evaluate the use of single photon lidar (SPL) collected in the summer of 2015, developed for rapidly collecting high-density, three-dimensional data over a variety of terrain targets, to aid in carbon offset MRV on an

  19. A ton is not always a ton: A road-test of landfill, manure, and afforestation/reforestation offset protocols in the U.S. carbon market

    International Nuclear Information System (INIS)

    Lee, Carrie M.; Lazarus, Michael; Smith, Gordon R.; Todd, Kimberly; Weitz, Melissa

    2013-01-01

    Highlights: • Protocols are the foundation of an offset program. • Using sample projects, we “road test” landfill, manure and afforestation protocols from 5 programs. • For a given project, we find large variation in the volume of offsets generated. • Harmonization of protocols can increase the likelihood that “a ton is a ton”. • Harmonization can enhance prospects for linking emission trading systems. -- Abstract: The outcome of recent international climate negotiations suggests we are headed toward a more fragmented carbon market, with multiple emission trading and offset programs operating in parallel. To effectively harmonize and link across programs, it will be important to ensure that across offset programs and protocols that a “ton is a ton”. In this article, we consider how sample offsets projects in the U.S. carbon market are treated across protocols from five programs: the Clean Development Mechanism, Climate Action Reserve, Chicago Climate Exchange, Regional Greenhouse Gas Initiative, and the U.S. EPA's former program, Climate Leaders. We find that differences among protocols for landfill methane, manure management, and afforestation/reforestation project types in accounting boundary definitions, baseline setting methods, measurement rules, emission factors, and discounts lead to differences in offsets credited that are often significant (e.g. greater than 50%). We suggest opportunities for modification and harmonization of protocols that can improve offset quality and credibility and enhance prospects for future linking of trading units and systems

  20. Potential increases in natural disturbance rates could offset forest management impacts on ecosystem carbon stocks

    Science.gov (United States)

    Bradford, John B.; Jensen, Nicholas R.; Domke, Grant M.; D’Amato, Anthony W.

    2013-01-01

    Forested ecosystems contain the majority of the world’s terrestrial carbon, and forest management has implications for regional and global carbon cycling. Carbon stored in forests changes with stand age and is affected by natural disturbance and timber harvesting. We examined how harvesting and disturbance interact to influence forest carbon stocks over the Superior National Forest, in northern Minnesota. Forest inventory data from the USDA Forest Service, Forest Inventory and Analysis program were used to characterize current forest age structure and quantify the relationship between age and carbon stocks for eight forest types. Using these findings, we simulated the impact of alternative management scenarios and natural disturbance rates on forest-wide terrestrial carbon stocks over a 100-year horizon. Under low natural mortality, forest-wide total ecosystem carbon stocks increased when 0% or 40% of planned harvests were implemented; however, the majority of forest-wide carbon stocks decreased with greater harvest levels and elevated disturbance rates. Our results suggest that natural disturbance has the potential to exert stronger influence on forest carbon stocks than timber harvesting activities and that maintaining carbon stocks over the long-term may prove difficult if disturbance frequency increases in response to climate change.

  1. Profiting from the sale of carbon offsets: a case study of the Trigg Ranch

    Science.gov (United States)

    Hannah Gosnell; Nicole Robinson-Maness; Susan. Charnley

    2011-01-01

    One result of growing concerns about climate change has been the development of a variety of market-based mechanisms aimed at incentivizing agricultural landowners to manage their lands in ways that mitigate climate change through carbon sequestration. Most of this attention has been aimed at engaging forest and farm owners in the voluntary carbon market, but in recent...

  2. Biomass offsets little or none of permafrost carbon release from soils, streams, and wildfire

    DEFF Research Database (Denmark)

    Abbott, Benjamin W.; Jones, Jeremy B.; Schuur, Edward A. G.

    2016-01-01

    estimates of net carbon balance increases the risk of further overshooting international emissions targets. Precise empirical or model-based assessments of the critical factors driving carbon balance are unlikely in the near future, so to address this gap, we present estimates from 98 permafrost......-region experts of the response of biomass, wildfire, and hydrologic carbon flux to climate change. Results suggest that contrary to model projections, total permafrost-region biomass could decrease due to water stress and disturbance, factors that are not adequately incorporated in current models. Assessments...... indicate that end-of-the-century organic carbon release from Arctic rivers and collapsing coastlines could increase by 75% while carbon loss via burning could increase four-fold. Experts identified water balance, shifts in vegetation community, and permafrost degradation as the key sources of uncertainty...

  3. Carbon Sequestration in Arable Soils is Likely to Increase Nitrous Oxide Emissions, Offsetting Reductions in Climate Radiative Forcing

    International Nuclear Information System (INIS)

    Li, Changsheng Li; Frolking, S.; Butterbach-Bahl, K.

    2005-01-01

    Strategies for mitigating the increasing concentration of carbon dioxide (CO2) in the atmosphere include sequestering carbon (C) in soils and vegetation of terrestrial ecosystems. Carbon and nitrogen (N) move through terrestrial ecosystems in coupled biogeochemical cycles, and increasing C stocks in soils and vegetation will have an impact on the N cycle. We conducted simulations with a biogeochemical model to evaluate the impact of different cropland management strategies on the coupled cycles of C and N, with special emphasis on C-sequestration and emission of the greenhouse gases methane (CH4) and nitrous oxide (N2O). Reduced tillage, enhanced crop residue incorporation, and farmyard manure application each increased soil C-sequestration, increased N2O emissions, and had little effect on CH4 uptake. Over 20 years, increases in N2O emissions, which were converted into CO2-equivalent emissions with 100-year global warming potential multipliers, offset 75-310% of the carbon sequestered, depending on the scenario. Quantification of these types of biogeochemical interactions must be incorporated into assessment frameworks and trading mechanisms to accurately evaluate the value of agricultural systems in strategies for climate protection

  4. Microbe-driven turnover offsets mineral-mediated storage of soil carbon under elevated CO2

    Science.gov (United States)

    Benjamin N. Sulman; Richard P. Phillips; A. Christopher Oishi; Elena Shevliakova; Stephen W. Pacala

    2014-01-01

    The sensitivity of soil organic carbon (SOC) to changing environmental conditions represents a critical uncertainty in coupled carbon cycle–climate models1.Much of this uncertainty arises from our limited understanding of the extent to which root–microbe interactions induce SOC losses (through accelerated decomposition or ‘priming’2) or indirectly promote SOC gains (...

  5. Microbe-driven turnover offsets mineral-mediated storage of soil carbon under elevated CO2

    Science.gov (United States)

    Sulman, Benjamin N.; Phillips, Richard P.; Oishi, A. Christopher; Shevliakova, Elena; Pacala, Stephen W.

    2014-12-01

    The sensitivity of soil organic carbon (SOC) to changing environmental conditions represents a critical uncertainty in coupled carbon cycle-climate models. Much of this uncertainty arises from our limited understanding of the extent to which root-microbe interactions induce SOC losses (through accelerated decomposition or `priming') or indirectly promote SOC gains (via `protection' through interactions with mineral particles). We developed a new SOC model to examine priming and protection responses to rising atmospheric CO2. The model captured disparate SOC responses at two temperate free-air CO2 enrichment (FACE) experiments. We show that stabilization of `new' carbon in protected SOC pools may equal or exceed microbial priming of `old' SOC in ecosystems with readily decomposable litter and high clay content (for example, Oak Ridge). In contrast, carbon losses induced through priming dominate the net SOC response in ecosystems with more resistant litters and lower clay content (for example, Duke). The SOC model was fully integrated into a global terrestrial carbon cycle model to run global simulations of elevated CO2 effects. Although protected carbon provides an important constraint on priming effects, priming nonetheless reduced SOC storage in the majority of terrestrial areas, partially counterbalancing SOC gains from enhanced ecosystem productivity.

  6. Highly reversible lead-carbon battery anode with lead grafting on the carbon surface

    KAUST Repository

    Yin, Jian; Lin, Nan; Zhang, Wenli; Lin, Zheqi; Zhang, Ziqing; Wang, Yue; Shi, Jun; Bao, Jinpeng; Lin, Haibo

    2018-01-01

    A novel C/Pb composite has been successfully prepared by electroless plating to reduce the hydrogen evolution and achieve the high reversibility of the anode of lead-carbon battery (LCB). The deposited lead on the surface of C/Pb composite was found to be uniform and adherent to carbon surface. Because lead has been stuck on the surface of C/Pb composite, the embedded structure suppresses the hydrogen evolution of lead-carbon anode and strengthens the connection between carbon additive and sponge lead. Compared with the blank anode, the lead-carbon anode with C/Pb composite displays excellent charge–discharge reversibility, which is attributed to the good connection between carbon additives and lead that has been stuck on the surface of C/Pb composite during the preparation process. The addition of C/Pb composite maintains a solid anode structure with high specific surface area and power volume, and thereby, it plays a significant role in the highly reversible lead-carbon anode.

  7. Highly reversible lead-carbon battery anode with lead grafting on the carbon surface

    KAUST Repository

    Yin, Jian

    2018-03-27

    A novel C/Pb composite has been successfully prepared by electroless plating to reduce the hydrogen evolution and achieve the high reversibility of the anode of lead-carbon battery (LCB). The deposited lead on the surface of C/Pb composite was found to be uniform and adherent to carbon surface. Because lead has been stuck on the surface of C/Pb composite, the embedded structure suppresses the hydrogen evolution of lead-carbon anode and strengthens the connection between carbon additive and sponge lead. Compared with the blank anode, the lead-carbon anode with C/Pb composite displays excellent charge–discharge reversibility, which is attributed to the good connection between carbon additives and lead that has been stuck on the surface of C/Pb composite during the preparation process. The addition of C/Pb composite maintains a solid anode structure with high specific surface area and power volume, and thereby, it plays a significant role in the highly reversible lead-carbon anode.

  8. Integrating biorefinery and farm biogeochemical cycles offsets fossil energy and mitigates soil carbon losses

    Science.gov (United States)

    Crop residues are potentially significant sources of feedstock for biofuel production in the US. However there are concerns with maintaining the environmental functions of these residues while also serving as a feedstock for biofuel production. Maintaining soil organic carbon (SOC) along with its fu...

  9. Research on the influencing factors of reverse logistics carbon footprint under sustainable development.

    Science.gov (United States)

    Sun, Qiang

    2017-10-01

    With the concerns of ecological and circular economy along with sustainable development, reverse logistics has attracted the attention of enterprise. How to achieve sustainable development of reverse logistics has important practical significance of enhancing low carbon competitiveness. In this paper, the system boundary of reverse logistics carbon footprint is presented. Following the measurement of reverse logistics carbon footprint and reverse logistics carbon capacity is provided. The influencing factors of reverse logistics carbon footprint are classified into five parts such as intensity of reverse logistics, energy structure, energy efficiency, reverse logistics output, and product remanufacturing rate. The quantitative research methodology using ADF test, Johansen co-integration test, and impulse response is utilized to interpret the relationship between reverse logistics carbon footprint and the influencing factors more accurately. This research finds that energy efficiency, energy structure, and product remanufacturing rate are more capable of inhibiting reverse logistics carbon footprint. The statistical approaches will help practitioners in this field to structure their reverse logistics activities and also help academics in developing better decision models to reduce reverse logistics carbon footprint.

  10. An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Son, Seoung-Bum; Gao, Tao; Harvey, Steve P.; Steirer, K. Xerxes; Stokes, Adam; Norman, Andrew; Wang, Chunsheng; Cresce, Arthur; Xu, Kang; Ban, Chunmei

    2018-04-02

    Magnesium-based batteries possess potential advantages over their lithium counterparts. However, reversible Mg chemistry requires a thermodynamically stable electrolyte at low potential, which is usually achieved with corrosive components and at the expense of stability against oxidation. In lithium-ion batteries the conflict between the cathodic and anodic stabilities of the electrolytes is resolved by forming an anode interphase that shields the electrolyte from being reduced. This strategy cannot be applied to Mg batteries because divalent Mg2+ cannot penetrate such interphases. Here, we engineer an artificial Mg2+-conductive interphase on the Mg anode surface, which successfully decouples the anodic and cathodic requirements for electrolytes and demonstrate highly reversible Mg chemistry in oxidation-resistant electrolytes. The artificial interphase enables the reversible cycling of a Mg/V2O5 full-cell in the water-containing, carbonate-based electrolyte. This approach provides a new avenue not only for Mg but also for other multivalent-cation batteries facing the same problems, taking a step towards their use in energy-storage applications.

  11. An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes

    Science.gov (United States)

    Son, Seoung-Bum; Gao, Tao; Harvey, Steve P.; Steirer, K. Xerxes; Stokes, Adam; Norman, Andrew; Wang, Chunsheng; Cresce, Arthur; Xu, Kang; Ban, Chunmei

    2018-05-01

    Magnesium-based batteries possess potential advantages over their lithium counterparts. However, reversible Mg chemistry requires a thermodynamically stable electrolyte at low potential, which is usually achieved with corrosive components and at the expense of stability against oxidation. In lithium-ion batteries the conflict between the cathodic and anodic stabilities of the electrolytes is resolved by forming an anode interphase that shields the electrolyte from being reduced. This strategy cannot be applied to Mg batteries because divalent Mg2+ cannot penetrate such interphases. Here, we engineer an artificial Mg2+-conductive interphase on the Mg anode surface, which successfully decouples the anodic and cathodic requirements for electrolytes and demonstrate highly reversible Mg chemistry in oxidation-resistant electrolytes. The artificial interphase enables the reversible cycling of a Mg/V2O5 full-cell in the water-containing, carbonate-based electrolyte. This approach provides a new avenue not only for Mg but also for other multivalent-cation batteries facing the same problems, taking a step towards their use in energy-storage applications.

  12. Terrestrial carbon losses from mountaintop coal mining offset regional forest carbon sequestration in the 21st century

    International Nuclear Information System (INIS)

    Elliott Campbell, J; Fox, James F; Acton, Peter M

    2012-01-01

    Studies that quantify the spatial and temporal variability of carbon sources and sinks provide process-level information for the prediction of future levels of atmospheric carbon dioxide as well as verification of current emission agreements. Assessments of carbon sources and sinks for North America that compare top-down atmospheric constraints with bottom-up inventories find particularly large carbon sinks in the southeastern US. However, this southeastern US sink may be impacted by extreme land-use disturbance events due to mountaintop coal mining (MCM). Here we apply ecosystem modeling and field experiment data to quantify the potential impact of future mountaintop coal mining on the carbon budget of the southern Appalachian forest region. For projections based on historical mining rates, grassland reclamation, and the continued regrowth of un-mined forests, we find that the southern Appalachian forests switch from a net carbon sink to a net carbon source by year 2025–33 with a 30%–35% loss in terrestrial carbon stocks relative to a scenario with no future mining by the year 2100. Alternatively, scenarios of forest sequestration due to the effect of CO 2 fertilization result in a 15%–24% loss in terrestrial carbon stocks by the year 2100 for mining scenarios relative to scenarios with no future mining. These results suggest that while power plant stack emissions are the dominant life-cycle stage in coal-fired electricity, accounting for mountaintop coal mining in bottom-up inventories may be a critical component of regional carbon budgets. (letter)

  13. Evaluating land-use and private forest management responses to a potential forest carbon offset sales program in western Oregon (USA)

    Science.gov (United States)

    Gregory S. Latta; Darius M. Adams; Kathleen P. Bell; Jeff Kline

    2016-01-01

    We describe the use of linked land-use and forest sector models to simulate the effects of carbon offset sales on private forest owners' land-use and forest management decisions inwestern Oregon (USA). Our work focuses on forest management decisions rather than afforestation, allows full forest sector price adjustment to land-use changes, and incorporates time-...

  14. In-Lake Processes Offset Increased Terrestrial Inputs of Dissolved Organic Carbon and Color to Lakes

    Science.gov (United States)

    Köhler, Stephan J.; Kothawala, Dolly; Futter, Martyn N.; Liungman, Olof; Tranvik, Lars

    2013-01-01

    Increased color in surface waters, or browning, can alter lake ecological function, lake thermal stratification and pose difficulties for drinking water treatment. Mechanisms suggested to cause browning include increased dissolved organic carbon (DOC) and iron concentrations, as well as a shift to more colored DOC. While browning of surface waters is widespread and well documented, little is known about why some lakes resist it. Here, we present a comprehensive study of Mälaren, the third largest lake in Sweden. In Mälaren, the vast majority of water and DOC enters a western lake basin, and after approximately 2.8 years, drains from an eastern basin. Despite 40 years of increased terrestrial inputs of colored substances to western lake basins, the eastern basin has resisted browning over this time period. Here we find the half-life of iron was far shorter (0.6 years) than colored organic matter (A420 ; 1.7 years) and DOC as a whole (6.1 years). We found changes in filtered iron concentrations relate strongly to the observed loss of color in the western basins. In addition, we observed a substantial shift from colored DOC of terrestrial origin, to less colored autochthonous sources, with a substantial decrease in aromaticity (-17%) across the lake. We suggest that rapid losses of iron and colored DOC caused the limited browning observed in eastern lake basins. Across a wider dataset of 69 Swedish lakes, we observed greatest browning in acidic lakes with shorter retention times (< 1.5 years). These findings suggest that water residence time, along with iron, pH and colored DOC may be of central importance when modeling and projecting changes in brownification on broader spatial scales. PMID:23976946

  15. Non-covalent and reversible functionalization of carbon nanotubes

    Directory of Open Access Journals (Sweden)

    Antonello Di Crescenzo

    2014-09-01

    Full Text Available Carbon nanotubes (CNTs have been proposed and actively explored as multipurpose innovative nanoscaffolds for applications in fields such as material science, drug delivery and diagnostic applications. Their versatile physicochemical features are nonetheless limited by their scarce solubilization in both aqueous and organic solvents. In order to overcome this drawback CNTs can be easily non-covalently functionalized with different dispersants. In the present review we focus on the peculiar hydrophobic character of pristine CNTs that prevent them to easily disperse in organic solvents. We report some interesting examples of CNTs dispersants with the aim to highlight the essential features a molecule should possess in order to act as a good carbon nanotube dispersant both in water and in organic solvents. The review pinpoints also a few examples of dispersant design. The last section is devoted to the exploitation of the major quality of non-covalent functionalization that is its reversibility and the possibility to obtain stimuli-responsive precipitation or dispersion of CNTs.

  16. The Impact of Carbon Emissions Policies on Reverse Supply Chain Network Design

    Directory of Open Access Journals (Sweden)

    Bandar A. ALKHAYYAL

    2018-01-01

    Full Text Available Reverse Supply Chain is described as an initiative that plays an important role in the global supply chain for those who seek environmentally responsible solutions for their end-of-life products. The relative economic and environmental benefits of reverse supply chain are influenced by costs and emissions during collection, transportation, recovery facilities, disassembly, recycling, remanufacturing, and disposal of unrecoverable components. The design of reverse supply chain network takes into account social, economic and environmental objectives. This paper addresses the design of reverse supply chain under the three common regulatory policies, strict carbon caps, carbon tax, and carbon cap-and-trade.

  17. Carbon Tolerant Fuel Electrodes for Reversible Sofc Operating on Carbon Dioxide

    Directory of Open Access Journals (Sweden)

    Papazisi Kalliopi Maria

    2017-01-01

    Full Text Available A challenging barrier for the broad, successful implementation of Reversible Solid Oxide Fuel Cell (RSOFC technology for Mars application utilizing CO2 from the Martian atmosphere as primary reactant, remains the long term stability by the effective control and minimization of degradation resulting from carbon built up. The perovskitic type oxide material La0.75Sr0.25Cr0.9Fe0.1O3-δ (LSCF has been developed and studied for its performance and tolerance to carbon deposition, employed as bi-functional fuel electrode in a Reversible SOFC operating on the CO2 cycle (Solid Oxide Electrolysis Cell/SOEC: CO2 electrolysis, Solid Oxide Fuel Cell/SOFC: power generation through the electrochemical reaction of CO and oxygen. A commercial state-of-the-art NiO-YSZ (8% mol Y2O3 stabilized ZrO2 cermet was used as reference material. CO2 electrolysis and fuel cell operation in 70% CO/CO2 were studied in the temperature range of 900-1000°C. YSZ was used as electrolyte while LSM-YSZ/LSM (La0.2Sr0.8MnO3 as oxygen electrode. Results showed that LSCF had high and stable performance under RSOFC operation.

  18. Black carbon: The reverse of its dark side

    NARCIS (Netherlands)

    Koelmans, A.A.; Jonker, M.T.O.; Cornelissen, G.; Bucheli, T.D.; Noort, van P.C.M.; Gustafsson, O.

    2006-01-01

    The emission of black carbon is known to cause major environmental problems. Black carbon particles contribute to global warming, carry carcinogenic compounds and cause serious health risks. Here, we show another side of the coin. We review evidence that black carbon may strongly reduce the risk

  19. Electrochemical reversibility of reticulated vitreous carbon electrodes heat treated at different carbonization temperatures

    Directory of Open Access Journals (Sweden)

    Emerson Sarmento Gonçalves

    2006-06-01

    Full Text Available Electrochemical response of ferri/ferrocyanide redox couple is discussed for a system that uses reticulated vitreous carbon (RVC three dimensional electrodes prepared at five different Heat Treatment Temperatures (HTT in the range of 700 °C to 1100 °C. Electrical resistivity, scanning electron microscopy and X ray Diffraction analyses were performed for all prepared samples. It was observed that the HTT increasing promotes an electrical conductivity increasing while the Bragg distance d002 decreases. The correlation between reversibility behavior of ferri/ferrocyanide redox couple and both surface morphology and chemical properties of the RVC electrodes demonstrated a strong dependence on the HTT used to prepare the RVC.

  20. Tendances Carbone no. 89. European Offset Projects: A tool to rally Poland towards the 2030 Energy Climate Package

    International Nuclear Information System (INIS)

    Bellassen, Valentin; Alberola, Emilie

    2014-03-01

    Among the publications of CDC Climat Research, 'Tendances Carbone' bulletin specifically studies the developments of the European market for CO 2 allowances. Beside some statistical figures about energy production/consumption and carbon markets, this issue specifically addresses the following points: - EUA supply: after the approbation of the back-loading regulation, the number of auctioned allowances for 2014 will be reduced by 400 million. National allocations plans of all 28 member states for the free allocation of allowances for 2013 have been approved. - 2030 climate and energy package: the EU Parliament adopted a non-binding resolution on the 2030 Climate and Energy Framework. On 20-21 March the European Council will meet to discuss this framework. - Carbon leakage list for 2015-2019: industrial stakeholders will be informed at the latest by the end of March 2014 if their sectors are included on the first draft of the new carbon leakage list

  1. Preparation of ultrasmall porous carbon nanospheres by reverse microemulsion-hydrothermal method

    Science.gov (United States)

    Wang, Jiasheng; Zhao, Yahong; Wang, Wan-Hui; Bao, Ming

    Porous carbon nanospheres (CNSs) have wide applications. A big challenge in materials science is synthesis of discrete ultrasmall porous carbon nanospheres. Herein, we report a facile reverse microemulsion-hydrothermal method to prepare discrete porous CNSs. The obtained CNSs possess an average diameter of 20nm and pores of 0.7nm and 3.4nm. Our work has provided a convenient method for the controllable synthesis of ultrasmall porous CNSs with potential applications.

  2. Synthesis of CaCO3 nanoparticles by carbonation of lime solutions in reverse micellar systems

    NARCIS (Netherlands)

    Heeres, H.J.; Jain, R.; Mehra, A.; Dagaonkar, M.V.

    2004-01-01

    Application of reverse micelles for the synthesis of nano-sized calcium carbonate particles in different solvents (cyclohexane, decane and heptane) has been investigated. The effect of the mole ratio of water-to-surfactant (R) and type of solvent has been studied on the size and nature of the

  3. Reversible storage of lithium in a rambutan-like tin-carbon electrode.

    Science.gov (United States)

    Deng, Da; Lee, Jim Yang

    2009-01-01

    Fruity electrodes: A simple bottom-up self-assembly method was used to fabricate rambutan-like tin-carbon (Sn@C) nanoarchitecture (see scheme, green Sn) to improve the reversible storage of lithium in tin. The mechanism of the growth of the pear-like hairs is explored.

  4. How Much Carbon Is in the Forest? A Project-Based Science Investigation of Trees' Role in Offsetting Global Warming

    Science.gov (United States)

    Penniman, Leah

    2011-01-01

    At the start of an integrated Algebra I and Environmental Science class, students were presented with the following challenge: "How much carbon is stored in the Normanskill Preserve?" They were told they had one month to investigate and present their results, and asked, "What do you need to begin?" This hook served to introduce…

  5. Assessing offsets between the δ13C of sedimentary components and the global exogenic carbon pool across early Paleogene carbon cycle perturbations

    NARCIS (Netherlands)

    Sluijs, A.; Dickens, G.R.

    2012-01-01

    Negative stable carbon isotope excursions (CIEs) across the Paleocene–Eocene thermal maximum (PETM; ∼56 Ma) range between 2‰ and 7‰, even after discounting sections with truncated records. Individual carbon isotope records differ in shape and magnitude from variations in the global exogenic carbon

  6. Carbon recovery rates following different wildfire risk mitigation treatments

    Science.gov (United States)

    M. Hurteau; M. North

    2010-01-01

    Sequestered forest carbon can provide a climate change mitigation benefit, but in dry temperate forests, wildfire poses a reversal risk to carbon offset projects. Reducing wildfire risk requires a reduction in and redistribution of carbon stocks, the benefit of which is only realized when wildfire occurs. To estimate the time needed to recover carbon removed and...

  7. Reduced Reactivity of Amines against Nucleophilic Substitution via Reversible Reaction with Carbon Dioxide

    Directory of Open Access Journals (Sweden)

    Fiaz S. Mohammed

    2015-12-01

    Full Text Available The reversible reaction of carbon dioxide (CO2 with primary amines to form alkyl-ammonium carbamates is demonstrated in this work to reduce amine reactivity against nucleophilic substitution reactions with benzophenone and phenyl isocyanate. The reversible formation of carbamates has been recently exploited for a number of unique applications including the formation of reversible ionic liquids and surfactants. For these applications, reduced reactivity of the carbamate is imperative, particularly for applications in reactions and separations. In this work, carbamate formation resulted in a 67% reduction in yield for urea synthesis and 55% reduction for imine synthesis. Furthermore, the amine reactivity can be recovered upon reversal of the carbamate reaction, demonstrating reversibility. The strong nucleophilic properties of amines often require protection/de-protection schemes during bi-functional coupling reactions. This typically requires three separate reaction steps to achieve a single transformation, which is the motivation behind Green Chemistry Principle #8: Reduce Derivatives. Based upon the reduced reactivity, there is potential to employ the reversible carbamate reaction as an alternative method for amine protection in the presence of competing reactions. For the context of this work, CO2 is envisioned as a green protecting agent to suppress formation of n-phenyl benzophenoneimine and various n-phenyl–n-alky ureas.

  8. Potential for large-scale solar collector system to offset carbon-based heating in the Ontario greenhouse sector

    Science.gov (United States)

    Semple, Lucas M.; Carriveau, Rupp; Ting, David S.-K.

    2018-04-01

    In the Ontario greenhouse sector the misalignment of available solar radiation during the summer months and large heating demand during the winter months makes solar thermal collector systems an unviable option without some form of seasonal energy storage. Information obtained from Ontario greenhouse operators has shown that over 20% of annual natural gas usage occurs during the summer months for greenhouse pre-heating prior to sunrise. A transient model of the greenhouse microclimate and indoor conditioning systems is carried out using TRNSYS software and validated with actual natural gas usage data. A large-scale solar thermal collector system is then incorporated and found to reduce the annual heating energy demand by approximately 35%. The inclusion of the collector system correlates to a reduction of about 120 tonnes of CO2 equivalent emissions per acre of greenhouse per year. System payback period is discussed considering the benefits of a future Ontario carbon tax.

  9. Nanoconfinement in activated mesoporous carbon of calcium borohydride for improved reversible hydrogen storage.

    Science.gov (United States)

    Comănescu, Cezar; Capurso, Giovanni; Maddalena, Amedeo

    2012-09-28

    Mesoporous carbon frameworks were synthesized using the soft-template method. Ca(BH(4))(2) was incorporated into activated mesoporous carbon by the incipient wetness method. The activation of mesoporous carbon was necessary to optimize the surface area and pore size. Thermal programmed absorption measurements showed that the confinement of this borohydride into carbon nanoscaffolds improved its reversible capacity (relative to the reactive portion) and performance of hydrogen storage compared to unsupported borohydride. Hydrogen release from the supported hydride started at a temperature as low as 100 °C and the dehydrogenation rate was fast compared to the bulk borohydride. In addition, the hydrogen pressure necessary to regenerate the borohydride from the dehydrogenation products was reduced.

  10. Angled BIO-RSA (bony-increased offset-reverse shoulder arthroplasty): a solution for the management of glenoid bone loss and erosion.

    Science.gov (United States)

    Boileau, Pascal; Morin-Salvo, Nicolas; Gauci, Marc-Olivier; Seeto, Brian L; Chalmers, Peter N; Holzer, Nicolas; Walch, Gilles

    2017-12-01

    Glenoid deficiency and erosion (excessive retroversion/inclination) must be corrected in reverse shoulder arthroplasty (RSA) to avoid prosthetic notching or instability and to maximize function, range of motion, and prosthesis longevity. This study reports the results of RSA with an angled, autologous glenoid graft harvested from the humerus (angled BIO-RSA). A trapezoidal bone graft, harvested from the humeral head and fixed with a long-post baseplate and screws, was used to compensate for residual glenoid bone loss/erosion. For simple to moderate (25°) and complex (multiplanar) glenoid bone defects, patient-specific grafts and guides were used after 3-dimensional planning. Patients were reviewed with minimum 2 years of follow-up. Mean follow-up was 36 months (range, 24-81 months). Preoperative and postoperative measurements of inclination and version were performed in the plane of the scapula on computed tomography images. The study included 54 patients (41 women, 13 men; mean 73 years old). Fifteen patients had combined vertical and horizontal glenoid bone deficiency. Among E2/E3 glenoids, inclination improved from 37° (range, 14° to 84°) to 10.2° (range -28° to 36°, P RSA predictably corrects glenoid deficiency, including severe (>25°) multiplanar deformity. Graft incorporation is predictable. Advantages of using an autograftharvested in situ include bone stock augmentation, lateralization, low donor-site morbidity, low relative cost, and flexibility needed to simultaneously correct posterior and superior glenoid defects. Copyright © 2017 The Authors. Published by Elsevier Inc. All rights reserved.

  11. Reversible insertion of carbon dioxide into Pt(II)-hydroxo bonds.

    Science.gov (United States)

    Lohr, Tracy L; Piers, Warren E; Parvez, Masood

    2013-10-01

    The reactivity of three monomeric diimine Pt(II) hydroxo complexes, (NN)Pt(OH)R (NN = bulky diimine ligand; R = OH, ; R = C6H5, ; R = CH3, ) towards carbon dioxide has been investigated. Insertion into the Pt-OH bonds was found to be facile and reversible at low temperature for all compounds; the reaction with bis-hydroxide gives an isolable κ(2)-carbonato compound , with elimination of water.

  12. Solar cells from 120 PPMA carbon-contaminated feedstock without significantly higher reverse current or shunt

    Energy Technology Data Exchange (ETDEWEB)

    Manshanden, P.; Coletti, G. [ECN Solar Energy, Petten (Netherlands)

    2012-09-15

    In a bid to drive down the cost of silicon wafers, several options for solar grade silicon feedstock have been investigated over the years. All methods have in common that the resulting silicon contains higher levels of impurities like dopants, oxygen, carbon or transition metals, the type and level of impurities depending on the raw materials and refining processes. In this work wafers from a p-type mc-Si ingot made with feedstock contaminated with 120 ppma of carbon have been processed into solar cells together with reference uncontaminated feedstock from semiconductor grade polysilicon with <0.4 ppma carbon. The results show that comparable reverse current, shunts, and efficiencies can be reached for both types of wafers. Gettering and defect hydrogenation effectiveness also did not deviate from the reference. Electroluminescence pictures do not show increased hotspot formation, even at -16V.

  13. Repeated administrations of carbon nanotubes in male mice cause reversible testis damage without affecting fertility

    Science.gov (United States)

    Bai, Yuhong; Zhang, Yi; Zhang, Jingping; Mu, Qingxin; Zhang, Weidong; Butch, Elizabeth R.; Snyder, Scott E.; Yan, Bing

    2010-09-01

    Soluble carbon nanotubes show promise as materials for in vivo delivery and imaging applications. Several reports have described the in vivo toxicity of carbon nanotubes, but their effects on male reproduction have not been examined. Here, we show that repeated intravenous injections of water-soluble multiwalled carbon nanotubes into male mice can cause reversible testis damage without affecting fertility. Nanotubes accumulated in the testes, generated oxidative stress and decreased the thickness of the seminiferous epithelium in the testis at day 15, but the damage was repaired at 60 and 90 days. The quantity, quality and integrity of the sperm and the levels of three major sex hormones were not significantly affected throughout the 90-day period. The fertility of treated male mice was unaffected; the pregnancy rate and delivery success of female mice that mated with the treated male mice did not differ from those that mated with untreated male mice.

  14. Reverse capillary flow of condensed water through aligned multiwalled carbon nanotubes

    International Nuclear Information System (INIS)

    Yun, Jongju; Jeon, Wonjae; Alam Khan, Fakhre; Lee, Jinkee; Baik, Seunghyun

    2015-01-01

    Molecular transport through nanopores has recently received considerable attention as a result of advances in nanofabrication and nanomaterial synthesis technologies. Surprisingly, water transport investigations through carbon nanochannels resulted in two contradicting observations: extremely fast transport or rejection of water molecules. In this paper, we elucidate the mechanism of impeded water vapor transport through the interstitial space of aligned multiwalled carbon nanotubes (aligned-MWCNTs)—capillary condensation, agglomeration, reverse capillary flow, and removal by superhydrophobicity at the tip of the nanotubes. The origin of separation comes from the water’s phase change from gas to liquid, followed by reverse capillary flow. First, the saturation water vapor pressure is decreased in a confined space, which is favorable for the phase change of incoming water vapor into liquid drops. Once continuous water meniscus is formed between the nanotubes by the adsoprtion and agglomeration of water molecules, a high reverse Laplace pressure is induced in the mushroom-shaped liquid meniscus at the entry region of the aligned-MWCNTs. The reverse Laplace pressure can be significantly enhanced by decreasing the pore size. Finally, the droplets pushed backward by the reverse Laplace pressure can be removed by superhydrophobicity at the tip of the aligned-MWCNTs. The analytical analysis was also supported by experiments carried out using 4 mm-long aligned-MWCNTs with different intertube distances. The water rejection rate and the separation factor increased as the intertube distance decreased, resulting in 90% and 10, respectively, at an intertube distance of 4 nm. This mechanism and nanotube membrane may be useful for energy-efficient water vapor separation and dehumidification. (paper)

  15. Synthesis of carbon nanotube-TiO(2) nanotubular material for reversible hydrogen storage.

    Science.gov (United States)

    Mishra, Amrita; Banerjee, Subarna; Mohapatra, Susanta K; Graeve, Olivia A; Misra, Mano

    2008-11-05

    A material consisting of multi-walled carbon nanotubes (MWCNTs) and larger titania (TiO(2)) nanotube arrays has been produced and found to be efficient for reversible hydrogen (H(2)) storage. The TiO(2) nanotube arrays (diameter ∼60 nm and length ∼2-3 µm) are grown on a Ti substrate, and MWCNTs a few µm in length and ∼30-60 nm in diameter are grown inside these TiO(2) nanotubes using chemical vapor deposition with cobalt as a catalyst. The resulting material has been used in H(2) storage experiments based on a volumetric method using the pressure, composition, and temperature relationship of the storage media. This material can store up to 2.5 wt% of H(2) at 77 K under 25 bar with more than 90% reversibility.

  16. Synthesis of carbon nanotube-TiO2 nanotubular material for reversible hydrogen storage

    International Nuclear Information System (INIS)

    Mishra, Amrita; Banerjee, Subarna; Mohapatra, Susanta K; Graeve, Olivia A; Misra, Mano

    2008-01-01

    A material consisting of multi-walled carbon nanotubes (MWCNTs) and larger titania (TiO 2 ) nanotube arrays has been produced and found to be efficient for reversible hydrogen (H 2 ) storage. The TiO 2 nanotube arrays (diameter ∼60 nm and length ∼2-3 μm) are grown on a Ti substrate, and MWCNTs a few μm in length and ∼30-60 nm in diameter are grown inside these TiO 2 nanotubes using chemical vapor deposition with cobalt as a catalyst. The resulting material has been used in H 2 storage experiments based on a volumetric method using the pressure, composition, and temperature relationship of the storage media. This material can store up to 2.5 wt% of H 2 at 77 K under 25 bar with more than 90% reversibility.

  17. Offset drilling obligations

    International Nuclear Information System (INIS)

    Boyd, K.D.; Kalmakoff, J.J.

    1998-01-01

    A review of the 'offset well' clause found in freehold and Crown natural gas and petroleum leases was presented. The objective was to provide lessors and lessees with a clear understanding of the rights and obligations associated with offset wells. It was noted that offset well obligations vary according to the form of lease used, the type of offsetting well, the regulatory regime and the geophysical characteristics of the producing formation. Some suggestions were made as to how current versions of the offset well clause can be amended to overcome some of the problems encountered in applying the clause to an offset horizontal well that has been drilled on adjoining lands. Failure to resolve the new issues presented by horizontal drilling technology in terms of documentation, which records respective rights and obligations on the basis of generally accepted principles, will result in large numbers of conflicts and unnecessary litigation. 144 refs., 1 fig

  18. Reversible Assembly of Graphitic Carbon Nitride 3D Network for Highly Selective Dyes Absorption and Regeneration.

    Science.gov (United States)

    Zhang, Yuye; Zhou, Zhixin; Shen, Yanfei; Zhou, Qing; Wang, Jianhai; Liu, Anran; Liu, Songqin; Zhang, Yuanjian

    2016-09-27

    Responsive assembly of 2D materials is of great interest for a range of applications. In this work, interfacial functionalized carbon nitride (CN) nanofibers were synthesized by hydrolyzing bulk CN in sodium hydroxide solution. The reversible assemble and disassemble behavior of the as-prepared CN nanofibers was investigated by using CO2 as a trigger to form a hydrogel network at first. Compared to the most widespread absorbent materials such as active carbon, graphene and previously reported supramolecular gel, the proposed CN hydrogel not only exhibited a competitive absorbing capacity (maximum absorbing capacity of methylene blue up to 402 mg/g) but also overcame the typical deficiencies such as poor selectivity and high energy-consuming regeneration. This work would provide a strategy to construct a 3D CN network and open an avenue for developing smart assembly for potential applications ranging from environment to selective extraction.

  19. New Pathways and Metrics for Enhanced, Reversible Hydrogen Storage in Boron-Doped Carbon Nanospaces

    Energy Technology Data Exchange (ETDEWEB)

    Pfeifer, Peter [University of Missouri; Wexler, Carlos [University of Missouri; Hawthorne, M. Frederick [University of Missouri; Lee, Mark W. [University of Missouri; Jalistegi, Satish S. [University of Missouri

    2014-08-14

    This project, since its start in 2007—entitled “Networks of boron-doped carbon nanopores for low-pressure reversible hydrogen storage” (2007-10) and “New pathways and metrics for enhanced, reversible hydrogen storage in boron-doped carbon nanospaces” (2010-13)—is in support of the DOE's National Hydrogen Storage Project, as part of the DOE Hydrogen and Fuel Cells Program’s comprehensive efforts to enable the widespread commercialization of hydrogen and fuel cell technologies in diverse sectors of the economy. Hydrogen storage is widely recognized as a critical enabling technology for the successful commercialization and market acceptance of hydrogen powered vehicles. Storing sufficient hydrogen on board a wide range of vehicle platforms, at energy densities comparable to gasoline, without compromising passenger or cargo space, remains an outstanding technical challenge. Of the main three thrust areas in 2007—metal hydrides, chemical hydrogen storage, and sorption-based hydrogen storage—sorption-based storage, i.e., storage of molecular hydrogen by adsorption on high-surface-area materials (carbons, metal-organic frameworks, and other porous organic networks), has emerged as the most promising path toward achieving the 2017 DOE storage targets of 0.055 kg H2/kg system (“5.5 wt%”) and 0.040 kg H2/liter system. The objective of the project is to develop high-surface-area carbon materials that are boron-doped by incorporation of boron into the carbon lattice at the outset, i.e., during the synthesis of the material. The rationale for boron-doping is the prediction that boron atoms in carbon will raise the binding energy of hydro- gen from 4-5 kJ/mol on the undoped surface to 10-14 kJ/mol on a doped surface, and accordingly the hydro- gen storage capacity of the material. The mechanism for the increase in binding energy is electron donation from H2 to electron-deficient B atoms, in the form of sp2 boron-carbon bonds. Our team is proud to have

  20. Global reverse supply chain design for solid waste recycling under uncertainties and carbon emission constraint.

    Science.gov (United States)

    Xu, Zhitao; Elomri, Adel; Pokharel, Shaligram; Zhang, Qin; Ming, X G; Liu, Wenjie

    2017-06-01

    The emergence of concerns over environmental protection, resource conservation as well as the development of logistics operations and manufacturing technology has led several countries to implement formal collection and recycling systems of solid waste. Such recycling system has the benefits of reducing environmental pollution, boosting the economy by creating new jobs, and generating income from trading the recyclable materials. This leads to the formation of a global reverse supply chain (GRSC) of solid waste. In this paper, we investigate the design of such a GRSC with a special emphasis on three aspects; (1) uncertainty of waste collection levels, (2) associated carbon emissions, and (3) challenges posed by the supply chain's global aspect, particularly the maritime transportation costs and currency exchange rates. To the best of our knowledge, this paper is the first attempt to integrate the three above-mentioned important aspects in the design of a GRSC. We have used mixed integer-linear programming method along with robust optimization to develop the model which is validated using a sample case study of e-waste management. Our results show that using a robust model by taking the complex interactions characterizing global reverse supply chain networks into account, we can create a better GRSC. The effect of uncertainties and carbon constraints on decisions to reduce costs and emissions are also shown. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. Low Offset AC Correlator.

    Science.gov (United States)

    This patent describes a low offset AC correlator avoids DC offset and low frequency noise by frequency operating the correlation signal so that low...noise, low level AC amplification can be substituted for DC amplification. Subsequently, the high level AC signal is demodulated to a DC level. (Author)

  2. Effectiveness of carbon dioxide removal in lowering atmospheric CO2 and reversing global warming in the context of 1.5 degrees

    Science.gov (United States)

    Zickfeld, K.; Azevedo, D.

    2017-12-01

    The majority of emissions scenarios that limit warming to 2°C, and nearly all emission scenarios that do not exceed 1.5°C warming by the year 2100 require artificial removal of CO2 from the atmosphere. Carbon dioxide removal (CDR) technologies in these scenarios are required to offset emissions from sectors that are difficult or costly to decarbonize and to generate global `net negative' emissions, allowing to compensate for earlier emissions and to meet long-term climate stabilization targets after overshoot. Only a few studies have explored the Earth system response to CDR and large uncertainties exist regarding the effect of CDR on the carbon cycle and its effectiveness in reversing climate impacts after overshoot. Here we explore the effectiveness of CDR in lowering atmospheric CO2 ("carbon cycle effectiveness") and cool global climate ("cooling effectiveness"). We force the University of Victoria Earth System Climate Model, a model of intermediate complexity, with a set of negative CO2 emissions pulses of different magnitude and applied from different background atmospheric CO2 concentrations. We find the carbon cycle effectiveness of CDR - defined as the change in atmospheric CO2 per unit CO2 removed - decreases with the amount of CO2 removed from the atmosphere and increases at higher background CO2 concentrations from which CDR is applied due to nonlinear responses of carbon sinks to CO2 and climate. The cooling effectiveness - defined as the change in global mean surface air temperature per unit CO2 removed - on the other hand, is largely insensitive to the amount of CO2 removed, but decreases if CDR is applied at higher atmospheric CO2 concentrations, due to the logarithmic relationship between atmospheric CO2 and radiative forcing. Based on our results we conclude that CDR is more effective in restoring a lower atmospheric CO2 concentration and reversing impacts directly linked to CO2 at lower levels of overshoot. CDR's effectiveness in restoring a

  3. Corrosion Inhibition of the Galvanic Couple Copper-Carbon Steel in Reverse Osmosis Water

    Directory of Open Access Journals (Sweden)

    Irene Carrillo

    2011-01-01

    Full Text Available The purpose of this paper is to evaluate the electrochemical behaviour of corrosion inhibition of the copper-carbon steel galvanic couple (Cu-CS, exposed to reverse osmosis water (RO used for rinsing of heat exchangers for heavy duty machinery, during manufacture. Molybdate and nitrite salts were utilized to evaluate the inhibition behaviour under galvanic couple conditions. Cu-CS couple was used as working electrodes to measure open circuit potential (OCP, potentiodynamic polarization (PP, and electrochemical impedance spectroscopy (EIS. The surface conditions were characterized by scanning electron microscopy (SEM and electron dispersive X-ray spectroscopy (EDS. The most effective concentration ratio between molybdate and nitrite corrosion inhibitors was determined. The morphological study indicated molybdate deposition on the anodic sites of the galvanic couple. The design of molybdate-based corrosion inhibitor developed in the present work should be applied to control galvanic corrosion of the Cu-CS couple during cleaning in the manufacture of heat exchangers.

  4. Reversible thermal fusing model of carbon black current-limiting thermistors

    International Nuclear Information System (INIS)

    Martin, James E.; Heaney, Michael B.

    2000-01-01

    Composites of carbon black particles in polyethylene exhibit an unusually rapid increase in resistivity as the applied electric field is increased, making this material commercially useful as current-limiting thermistors, also known as automatically resettable fuses. In this application the composite is in series with the circuit it is protecting: at low applied voltages the circuit is the load, but at high applied voltages the composite becomes the load, limiting the current to the circuit. We present a simple model of this behavior in terms of a network of nonlinear resistors. Each resistor has a resistance that depends explicitly and reversibly on its instantaneous power dissipation. This model predicts that in the soft fusing, or current-limiting, regime, where the current through the composite decreases with increasing voltage, a platelike dissipation instability develops normal to the applied field, in agreement with experimental observations, which is solely due to fluctuations in the microstructure

  5. Self-sensing of carbon nanofiber concrete columns subjected to reversed cyclic loading

    Science.gov (United States)

    Howser, R. N.; Dhonde, H. B.; Mo, Y. L.

    2011-08-01

    Civil infrastructures are generally a country's most expensive investment, and concrete is the most widely used material in the construction of civil infrastructures. During a structure's service life, concrete ages and deteriorates, leading to substantial loss of structural integrity and potentially resulting in catastrophic disasters such as highway bridge collapses. A solution for preventing such occurrences is the use of structural health monitoring (SHM) technology for concrete structures containing carbon nanofibers (CNF). CNF concrete has many structural benefits. CNF restricts the growth of nanocracks in addition to yielding higher strength and ductility. Additionally, test results indicate a relationship between electrical resistance and concrete strain, which can be well utilized for SHM. A series of reinforced concrete (RC) columns were built and tested under a reversed cyclic loading using CNF as a SHM device. The SHM device detected and assessed the level of damage in the RC columns, providing a real-time health monitoring system for the structure's overall integrity.

  6. Self-sensing of carbon nanofiber concrete columns subjected to reversed cyclic loading

    International Nuclear Information System (INIS)

    Howser, R N; Dhonde, H B; Mo, Y L

    2011-01-01

    Civil infrastructures are generally a country's most expensive investment, and concrete is the most widely used material in the construction of civil infrastructures. During a structure's service life, concrete ages and deteriorates, leading to substantial loss of structural integrity and potentially resulting in catastrophic disasters such as highway bridge collapses. A solution for preventing such occurrences is the use of structural health monitoring (SHM) technology for concrete structures containing carbon nanofibers (CNF). CNF concrete has many structural benefits. CNF restricts the growth of nanocracks in addition to yielding higher strength and ductility. Additionally, test results indicate a relationship between electrical resistance and concrete strain, which can be well utilized for SHM. A series of reinforced concrete (RC) columns were built and tested under a reversed cyclic loading using CNF as a SHM device. The SHM device detected and assessed the level of damage in the RC columns, providing a real-time health monitoring system for the structure's overall integrity

  7. Persistent cyclestability of carbon coated Zn–Sn metal oxide/carbon microspheres as highly reversible anode material for lithium-ion batteries

    International Nuclear Information System (INIS)

    Fang, Guoqing; Kaneko, Shingo; Liu, Weiwei; Xia, Bingbo; Sun, Hongdan; Zhang, Ruixue; Zheng, Junwei; Li, Decheng

    2013-01-01

    Development of high-capacity anode materials equipped with strong cyclestability is a great challenge for use as practical electrode for high-performance lithium-ion rechargeable battery. In this study, we synthesized a carbon coated Zn–Sn metal nanocomposite oxide and carbon spheres (ZTO@C/CSs) via a simple glucose hydrothermal reaction and subsequent carbonization approach. The carbon coated ZTO/carbon microspheres composite maintained a reversible capacity of 680 mAh g −1 after 345 cycles at a current density of 100 mA g −1 , and furthermore the cell based on the composite exhibited an excellent rate capability of 470 mAh g −1 even when the cell was cycled at 2000 mA g –1 . The thick carbon layer formed on the ZTO nanoparticles and carbon spheres effectively buffered the volumetric change of the particles, which thus prolonged the cycling performance of the electrodes

  8. Policy development for biodiversity offsets: a review of offset frameworks.

    Science.gov (United States)

    McKenney, Bruce A; Kiesecker, Joseph M

    2010-01-01

    Biodiversity offsets seek to compensate for residual environmental impacts of planned developments after appropriate steps have been taken to avoid, minimize or restore impacts on site. Offsets are emerging as an increasingly employed mechanism for achieving net environmental benefits, with offset policies being advanced in a wide range of countries (i.e., United States, Australia, Brazil, Colombia, and South Africa). To support policy development for biodiversity offsets, we review a set of major offset policy frameworks-US wetlands mitigation, US conservation banking, EU Natura 2000, Australian offset policies in New South Wales, Victoria, and Western Australia, and Brazilian industrial and forest offsets. We compare how the frameworks define offset policy goals, approach the mitigation process, and address six key issues for implementing offsets: (1) equivalence of project impacts with offset gains; (2) location of the offset relative to the impact site; (3) "additionality" (a new contribution to conservation) and acceptable types of offsets; (4) timing of project impacts versus offset benefits; (5) offset duration and compliance; and (6) "currency" and mitigation replacement ratios. We find substantial policy commonalities that may serve as a sound basis for future development of biodiversity offsets policy. We also identify issues requiring further policy guidance, including how best to: (1) ensure conformance with the mitigation hierarchy; (2) identify the most environmentally preferable offsets within a landscape context; and (3) determine appropriate mitigation replacement ratios.

  9. Bioluminescence-Based Method for Measuring Assimilable Organic Carbon in Pretreatment Water for Reverse Osmosis Membrane Desalination ▿

    Science.gov (United States)

    Weinrich, Lauren A.; Schneider, Orren D.; LeChevallier, Mark W.

    2011-01-01

    A bioluminescence-based assimilable organic carbon (AOC) test was developed for determining the biological growth potential of seawater within the reverse osmosis desalination pretreatment process. The test uses Vibrio harveyi, a marine organism that exhibits constitutive luminescence and is nutritionally robust. AOC was measured in both a pilot plant and a full-scale desalination plant pretreatment. PMID:21148685

  10. [Carbon sequestration in soil particle-sized fractions during reversion of desertification at Mu Us Sand land.

    Science.gov (United States)

    Ma, Jian Ye; Tong, Xiao Gang; Li, Zhan Bin; Fu, Guang Jun; Li, Jiao; Hasier

    2016-11-18

    The aim of this study was to investigate the effects of carbon sequestration in soil particle-sized fractions during reversion of desertification at Mu Us Sand Land, soil samples were collected from quicksand land, semifixed sand and fixed sand lands that were established by the shrub for 20-55 year-old and the arbor for 20-50 year-old at sand control region of Yulin in Northern Shaanxi Province. The dynamics and sequestration rate of soil organic carbon (SOC) associated with sand, silt and clay were measured by physical fractionation method. The results indicated that, compared with quicksand area, the carbon content in total SOC and all soil particle-sized fractions at bothsand-fixing sand forest lands showed a significant increasing trend, and the maximum carbon content was observed in the top layer of soils. From quicksand to fixed sand land with 55-year-old shrub and 50-year-old arbor, the annual sequestration rate of carbon stock in 0-5 cm soil depth was same in silt by 0.05 Mg·hm -2 ·a -1 . The increase rate of carbon sequestration in sand was 0.05 and 0.08 Mg·hm -2 ·a -1 , and in clay was 0.02 and 0.03 Mg·hm -2 ·a -1 at shrubs and arbors land, respectively. The increase rate of carbon sequestration in 0-20 cm soil layer for all the soil particles was averagely 2.1 times as that of 0-5 cm. At the annual increase rate of carbon, the stock of carbon in sand, silt and clay at the two fixed sand lands were increased by 6.7, 18.1 and 4.4 times after 50-55 year-old reversion of quicksand land to fixed sand. In addition, the average percentages that contributed to accumulation of total SOC by different particles in 0-20 cm soil were in the order of silt carbon (39.7%)≈sand carbon (34.6%) > clay carbon (25.6%). Generally, the soil particle-sized fractions had great carbon sequestration potential during reversion of desertification in Mu Us Sand Land, and the slit and sand were the main fractions for carbon sequestration at both fixed sand lands.

  11. Exploring residential energy consumers' willingness to accept and pay to offset their CO2-emission

    DEFF Research Database (Denmark)

    Yang, Yingkui; Solgaard, Hans Stubbe

    2015-01-01

    to pay for carbon offset. Finally, the ordered logit model is used in modelling willing to pay for carbon offset. Findings The results show that there is significant support from residential energy consumer to offset their CO2 emission from electricity consumption. The WTP is motivated by consumers...

  12. Programmable self-assembly of carbon nanotubes assisted by reversible denaturation of a protein

    International Nuclear Information System (INIS)

    Nithiyasri, P; Parthasarathy, M; Balaji, K; Brindha, P

    2012-01-01

    Self-assembly of pristine multi-walled carbon nanotubes (CNTs) in aqueous dispersion using a protein, bovine serum albumin (BSA), has been demonstrated. Step-wise conformational changes in BSA as a function of temperature have been deployed to direct the assembly of nanotubes. More specifically, CNTs distributed randomly in native BSA at 35 °C as well as completely denatured BSA solution at 80 °C self-assemble in the intermediate temperature range of 45–65 °C, as evident from scanning and transmission electron microscopy. Fourier transform infrared (FTIR) and fluorescence studies indicate significant changes in the α-helical content of the protein with respect to the amide I and II bands and tryptophan emission intensity, respectively. The stability of CNT dispersion in BSA solution has been attributed to the hydrophobic interaction between nanotubes and the protein molecule by adding sodium cholate to the dispersion. Moreover, a mechanism based on electrostatic repulsion between BSA-bound CNTs has been proposed for the thermally reversible assembly of CNTs in BSA solution based on evidence from zeta potential measurements and FTIR spectroscopy. Thus the present report demonstrates bio-mimetic self-assembly of as-synthesized CNTs using changes in surface charge and conformation of an unfolding protein for biomedical applications and nanobiotechnology. (paper)

  13. Liver fibrosis in mice induced by carbon tetrachloride and its reversion by luteolin

    International Nuclear Information System (INIS)

    Domitrovic, Robert; Jakovac, Hrvoje; Tomac, Jelena; Sain, Ivana

    2009-01-01

    Hepatic fibrosis is effusive wound healing process in which excessive connective tissue builds up in the liver. Because specific treatments to stop progressive fibrosis of the liver are not available, we have investigated the effects of luteolin on carbon tetrachloride (CCl 4 )-induced hepatic fibrosis. Male Balb/C mice were treated with CCl 4 (0.4 ml/kg) intraperitoneally (i.p.), twice a week for 6 weeks. Luteolin was administered i.p. once daily for next 2 weeks, in doses of 10, 25, and 50 mg/kg of body weight. The CCl 4 control group has been observed for spontaneous reversion of fibrosis. CCl 4 -intoxication increased serum aminotransferase and alkaline phosphatase levels and disturbed hepatic antioxidative status. Most of these parameters were spontaneously normalized in the CCl 4 control group, although the progression of liver fibrosis was observed histologically. Luteolin treatment has increased hepatic matrix metalloproteinase-9 levels and metallothionein (MT) I/II expression, eliminated fibrinous deposits and restored architecture of the liver in a dose-dependent manner. Concomitantly, the expression of glial fibrillary acidic protein and α-smooth muscle actin indicated deactivation of hepatic stellate cells. Our results suggest the therapeutic effects of luteolin on CCl 4 -induced liver fibrosis by promoting extracellular matrix degradation in the fibrotic liver tissue and the strong enhancement of hepatic regenerative capability, with MTs as a critical mediator of liver regeneration.

  14. Innovative nanoporous carbons with ultrahigh uptakes for capture and reversible storage of CO{sub 2} and volatile iodine

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Hanxue; La, Peiqing [College of Petrochemical Technology, Lanzhou University of Technology, Langongping Road 287, Lanzhou 730050, PR China (China); Yang, Ruixia [State Key Laboratory of Molecular Reaction Dynamics, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China); Zhu, Zhaoqi; Liang, Weidong; Yang, Baoping [College of Petrochemical Technology, Lanzhou University of Technology, Langongping Road 287, Lanzhou 730050, PR China (China); Li, An, E-mail: lian2010@lut.cn [College of Petrochemical Technology, Lanzhou University of Technology, Langongping Road 287, Lanzhou 730050, PR China (China); Deng, Weiqiao, E-mail: dengwq@dicp.ac.cn [State Key Laboratory of Molecular Reaction Dynamics, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China)

    2017-01-05

    Highlights: • Cigarette filter was utilized to prepare highly porous carbons as super absorbents. • The porous carbons exhibit excellent iodine uptake. • The porous carbons show high CO{sub 2} adsorption capacity of 6.0 mmol g{sup −1} at 273 K. - Abstract: Porous carbons as solid-state adsorbents have recently attracted considerable interest in the areas of storage and capture of CO{sub 2} as well as the adsorption of radioactive matters. In this work, cigarette butts, one kind of common wastes referring to the filters, were utilized to prepare highly porous carbons by KOH activation in argon atmosphere. The resulting porous carbon shows a high specific surface area of up to 2751 m{sup 2} g{sup −1} with abundant micropores. The resulting porous carbon exhibits excellent iodine uptake of 262 wt% and high CO{sub 2} adsorption capacity of 6.0 mmol g{sup −1} at ambient pressure and 273 K, which both are among the highest values reported to date. Given these excellent iodine uptake, CO{sub 2} adsorption capacity, ease of preparation as well as good physiochemical stability, the porous carbons derived from cigarette butts show great potential in the reversible adsorption of radioactive iodine and CO{sub 2}.

  15. Offset Compound Gear Drive

    Science.gov (United States)

    Stevens, Mark A.; Handschuh, Robert F.; Lewicki, David G.

    2010-01-01

    The Offset Compound Gear Drive is an in-line, discrete, two-speed device utilizing a special offset compound gear that has both an internal tooth configuration on the input end and external tooth configuration on the output end, thus allowing it to mesh in series, simultaneously, with both a smaller external tooth input gear and a larger internal tooth output gear. This unique geometry and offset axis permits the compound gear to mesh with the smaller diameter input gear and the larger diameter output gear, both of which are on the same central, or primary, centerline. This configuration results in a compact in-line reduction gear set consisting of fewer gears and bearings than a conventional planetary gear train. Switching between the two output ratios is accomplished through a main control clutch and sprag. Power flow to the above is transmitted through concentric power paths. Low-speed operation is accomplished in two meshes. For the purpose of illustrating the low-speed output operation, the following example pitch diameters are given. A 5.0 pitch diameter (PD) input gear to 7.50 PD (internal tooth) intermediate gear (0.667 reduction mesh), and a 7.50 PD (external tooth) intermediate gear to a 10.00 PD output gear (0.750 reduction mesh). Note that it is not required that the intermediate gears on the offset axis be of the same diameter. For this example, the resultant low-speed ratio is 2:1 (output speed = 0.500; product of stage one 0.667 reduction and stage two 0.750 stage reduction). The design is not restricted to the example pitch diameters, or output ratio. From the output gear, power is transmitted through a hollow drive shaft, which, in turn, drives a sprag during which time the main clutch is disengaged.

  16. Alkyne- and 1,6-elimination- succinimidyl carbonate – terminated heterobifunctional poly(ethylene glycol) for reversible "Click" PEGylation

    OpenAIRE

    Xie, Yumei; Duan, Shaofeng; Forrest, M. Laird

    2010-01-01

    A new heterobifunctional (succinimidyl carbonate, SC)-activated poly(ethylene glycol) (PEG) with a reversible 1,6-elimination linker and a terminal alkyne for "click" chemistry was synthesized with high efficiency and low polydispersity. The α-alkyne-ω-hydroxyl PEG was first prepared using trimethylsilyl-2-propargyl alcohol as an initiator for ring-opening polymerization of ethylene oxide followed by mild deprotection with tetrabutylammonium fluoride. The hydroxy end was then modified with di...

  17. Alkyne- and 1,6-elimination- succinimidyl carbonate - terminated heterobifunctional poly(ethylene glycol) for reversible "Click" PEGylation.

    Science.gov (United States)

    Xie, Yumei; Duan, Shaofeng; Forrest, M Laird

    2010-01-01

    A new heterobifunctional (succinimidyl carbonate, SC)-activated poly(ethylene glycol) (PEG) with a reversible 1,6-elimination linker and a terminal alkyne for "click" chemistry was synthesized with high efficiency and low polydispersity. The α-alkyne-ω-hydroxyl PEG was first prepared using trimethylsilyl-2-propargyl alcohol as an initiator for ring-opening polymerization of ethylene oxide followed by mild deprotection with tetrabutylammonium fluoride. The hydroxy end was then modified with diglycolic anhydride to generate α-alkyne-ω-carboxylic acid PEG. The reversible 1, 6-elimination linker was introduced by conjugation of a hydroxymethyl phenol followed by activation with N,N'-disuccinimidyl carbonate to generate the heterobifunctional α-alkyne-ω-SC PEG. The terminal alkyne is available for "click" conjugation to azido ligands via 1,3-dipolar cycloaddition, and the succinimidyl carbonate will form a reversible conjugate to amines (e.g. in proteins) that can release the unaltered amine after base or enzyme catalyzed cleavage of the 1,6-linker.

  18. The Impact of Carbon Emissions Policies on Reverse Supply Chain Network Design

    OpenAIRE

    Bandar A. ALKHAYYAL; Surendra M. GUPTA

    2018-01-01

    Reverse Supply Chain is described as an initiative that plays an important role in the global supply chain for those who seek environmentally responsible solutions for their end-of-life products. The relative economic and environmental benefits of reverse supply chain are influenced by costs and emissions during collection, transportation, recovery facilities, disassembly, recycling, remanufacturing, and disposal of unrecoverable components. The design of reverse supply chain network takes in...

  19. Visual and reversible carbon dioxide sensing enabled by doctor blade coated macroporous photonic crystals.

    Science.gov (United States)

    Lin, Yi-Han; Suen, Shing-Yi; Yang, Hongta

    2017-11-15

    With significant impacts of carbon dioxide on global climate change, carbon dioxide sensing is of great importance. However, most of the existing sensing technologies are prone to interferences from carbon monoxide, or suffer from the use of sophisticated instruments. This research reports the development of reproducible carbon dioxide sensor using roll-to-roll compatible doctor blade coated three-dimensional macroporous photonic crystals. The pores are functionalized with amine groups to allow the reaction with carbon dioxide in the presence of humidity. The adsorption of carbon dioxide leads to red-shift and amplitude reduction of the optical stop bands, resulting in carbon dioxide detection with visible readout. The dependences of the diffraction wavelength on carbon dioxide partial pressure for various amine-functionalized photonic crystals and different humidities in the environment are systematically investigated. In addition, the reproducibility of carbon dioxide sensing has also been demonstrated in this research. Copyright © 2017 Elsevier Inc. All rights reserved.

  20. Full color emitting fluorescent carbon material as reversible pH sensor with multicolor live cell imaging.

    Science.gov (United States)

    Sharma, Vinay; Kaur, Navpreet; Tiwari, Pranav; Mobin, Shaikh M

    2018-05-01

    Carbon-based nano materials are developed as a cytocompatible alternative to semiconducting quantum dots for bioimaging and fluorescence-based sensing. The green alternatives for the synthesis of carbon materials are imminent. The present study demonstrates microwave based one step quick synthesis of fluorescent carbon material (FCM) having three variants: (i) un-doped fluorescent carbon material (UFCM) (ii) nitrogen doped FCM (N@FCM), and (iii) nitrogen & phosphorus co-doped FCM (N-P@FCM) using sugarcane extract as a carbon source. The N doping was performed using ethylenediamine and phosphoric acid was used for P doping. The heteroatom doped FCM were synthesized due to insolubility of UFCM in water. Unlike, UFCM, the N@FCM and N-P@FCM were found to be highly soluble in water. The N-P@FCM shows highest quantum yield among the three. The N-P@FCM was explored for alkaline pH sensing and it shows a quenching of fluorescence in the pH range 09-14. The sensing behaviour shows reversibility and high selectivity. Further, the sensor was also investigated for their biocompatibility and hence employed as a promising multicolour probe for cancer cell imaging. The generality in cell imaging was investigated by flow cytometry. The hetero-atom doped green carbon-dots may open new avenues for sensing and selective cellular targeting. Copyright © 2018 Elsevier B.V. All rights reserved.

  1. Organic Carbon Reduction in Seawater Reverse Osmosis (SWRO) Plants, Jeddah, Saudi Arabia

    KAUST Repository

    Alshahri, Abdullah

    2015-12-01

    Desalination is considered to be a major source of usable water in the Middle East, especially the Gulf countries which lack fresh water resources. A key and sometimes the only solution to produce high quality water in these countries is through the use of seawater reverse osmosis (SWRO) desalination technology. Membrane fouling is an economic and operational defect that impacts the performance of SWRO desalination technology. To limit this fouling phenomenon, it is important to implement the appropriate type of intake and pre-treatment system design. In this study, two types of systems were investigated, a vertical well system and a surface-water intake at a 9m depth. The purpose of this investigation is to study the impact of the different intake systems and pre-treatment stages in minimizing the concentrations of algae, bacteria, natural organic matter (NOM) and transparent exopolymer particles (TEP), in the feed water prior to pre-treatment, through the pre-treatment stages, and in the product water and concentrate. Water samples were collected from the surface seawater, the intakes (wells for site A, 9 m depth open ocean intake at site B), after the media filter, after the cartridge filter, and from the permeate and reject streams. The measured parameters included physical parameters, algae, bacteria, total organic carbon (TOC), fractions of dissolved NOM, particulate and colloidal TEP. The results of this study prove that the natural filtration and biological treatment of the seawater which occur in the aquifer matrix are very effective in improving the raw water quality to a significant degree. The results demonstrated that algae and biopolymers were 100% removed, the bacterial concentrations were significantly removed and roughly 50% or greater of TOC concentrations was eliminated by the aquifer matrix at site A. The aquifer feeding the vertical wells reduced TEP concentrations, but to differing degree. There is a slight decrease in the concentrations of

  2. Analysis and evaluation of forest carbon projects and respective certification standards for the voluntary offset of greenhouse gas emissions; Analyse und Bewertung von Waldprojekten und entsprechender Standards zur freiwilligen Kompensation von Treibhausgasemissionen

    Energy Technology Data Exchange (ETDEWEB)

    Held, Christian; Tennigkeit, Timm; Techel, Grit; Seebauer, Matthias [UNIQUE forestry consultants GmbH, Freiburg (Germany)

    2010-12-15

    Forest based CO{sub 2} sequestration projects, regardless of their methodological approach, are always defined by the interaction of two carbon pools: (a) the CO{sub 2} stored in the forest ecosys-tem and (b) the CO{sub 2} present in the atmosphere. Forests are sinks for atmospheric carbon. This holds especially true for young or immature forests, if they are not disturbed and are not yet at equilibrium of increment, harvest and/or decay and harvest. This positive net sequestration of CO{sub 2} can be traded via emission reduction certificates, e.g. to offset emissions from industrial production, travelling and energy consumption. In contrast, the atmospheric pool increases if forests are destroyed leading to the release of the stored CO{sub 2}. This occurs if forest lands are converted into other land uses such as agricul-ture, or through forest management activities like harvesting or natural disturbances like for-est fires or pests. In all these cases forests become sources of CO{sub 2}. (orig.)

  3. Online combination of reversed-phase/reversed-phase and porous graphitic carbon liquid chromatography for multicomponent separation of proteomics and glycoproteomics samples.

    Science.gov (United States)

    Lam, Maggie P Y; Lau, Edward; Siu, S O; Ng, Dominic C M; Kong, Ricky P W; Chiu, Philip C N; Yeung, William S B; Lo, Clive; Chu, Ivan K

    2011-11-01

    In this paper, we describe an online combination of reversed-phase/reversed-phase (RP-RP) and porous graphitic carbon (PGC) liquid chromatography (LC) for multicomponent analysis of proteomics and glycoproteomics samples. The online RP-RP portion of this system provides comprehensive 2-D peptide separation based on sequence hydrophobicity at pH 2 and 10. Hydrophilic components (e.g. glycans, glycopeptides) that are not retained by RP are automatically diverted downstream to a PGC column for further trapping and separation. Furthermore, the RP-RP/PGC system can provide simultaneous extension of the hydropathy range and peak capacity for analysis. Using an 11-protein mixture, we found that the system could efficiently separate native peptides and released N-glycans from a single sample. We evaluated the applicability of the system to the analysis of complex biological samples using 25 μg of the lysate of a human choriocarcinoma cell line (BeWo), confidently identifying a total of 1449 proteins from a single experiment and up to 1909 distinct proteins from technical triplicates. The PGC fraction increased the sequence coverage through the inclusion of additional hydrophilic sequences that accounted for up to 6.9% of the total identified peptides from the BeWo lysate, with apparent preference for the detection of hydrophilic motifs and proteins. In addition, RP-RP/PGC is applicable to the analysis of complex glycomics samples, as demonstrated by our analysis of a concanavalin A-extracted glycoproteome from human serum; in total, 134 potentially N-glycosylated serum proteins, 151 possible N-glycosylation sites, and more than 40 possible N-glycan structures recognized by concanavalin A were simultaneously detected. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Reversible interconversion of carbon dioxide and formate by an electroactive enzyme

    NARCIS (Netherlands)

    Reda, T.; Plugge, C.M.; Abram, N.J.; Hirst, J.

    2008-01-01

    Carbon dioxide (CO2) is a kinetically and thermodynamically stable molecule. It is easily formed by the oxidation of organic molecules, during combustion or respiration, but is difficult to reduce. The production of reduced carbon compounds from CO2 is an attractive proposition, because

  5. Update on markets for forestry offsets

    International Nuclear Information System (INIS)

    Neeff, T.; Eichler, L.; Deecke, I.; Fehse, J.

    2007-01-01

    This guide is an update of the book 'Guidebook to Markets and Commercialization of CDM forestry projects'. The document provides information on the development of CMD methodologies, projects registered and markets since the publication of the first version. In addition it introduces the emerging non-Kyoto markets, it presents a classification of the existing developments, it describes each market including the buyer's preferences and it discusses the use of standards and quality criteria and transaction costs. We focus on markets for offsets from developing countries, rather than domestic offsets in developed countries. Section 1 is an introduction to the topic and an overview of the most recent developments. Sections 2 and 3 look at recent experiences and market developments for CDM reforestation projects. These sections are meant to be an update of the above mentioned guidebook and thus refrain from an exhaustive description. Section 4 assesses non-Kyoto markets for carbon offsets from forestry projects. It includes a description of the various market schemes and types of buyers. The section attempts to provide the project developer with useful information for developing a project following buyer' requirements. Finally, section 5 puts the assessment of opportunities for forestry in the broader context of the larger carbon markets. The report then concludes with a comparison of advantages and disadvantages of the CDM and non-Kyoto schemes from the project developer's point of view

  6. Indirect human impacts reverse centuries of carbon sequestration and salt marsh accretion.

    Science.gov (United States)

    Coverdale, Tyler C; Brisson, Caitlin P; Young, Eric W; Yin, Stephanie F; Donnelly, Jeffrey P; Bertness, Mark D

    2014-01-01

    Direct and indirect human impacts on coastal ecosystems have increased over the last several centuries, leading to unprecedented degradation of coastal habitats and loss of ecological services. Here we document a two-century temporal disparity between salt marsh accretion and subsequent loss to indirect human impacts. Field surveys, manipulative experiments and GIS analyses reveal that crab burrowing weakens the marsh peat base and facilitates further burrowing, leading to bank calving, disruption of marsh accretion, and a loss of over two centuries of sequestered carbon from the marsh edge in only three decades. Analogous temporal disparities exist in other systems and are a largely unrecognized obstacle in attaining sustainable ecosystem services in an increasingly human impacted world. In light of the growing threat of indirect impacts worldwide and despite uncertainties in the fate of lost carbon, we suggest that estimates of carbon emissions based only on direct human impacts may significantly underestimate total anthropogenic carbon emissions.

  7. Self-assembled air-stable magnesium hydride embedded in 3-D activated carbon for reversible hydrogen storage.

    Science.gov (United States)

    Shinde, S S; Kim, Dong-Hyung; Yu, Jin-Young; Lee, Jung-Ho

    2017-06-01

    The rational design of stable, inexpensive catalysts with excellent hydrogen dynamics and sorption characteristics under realistic environments for reversible hydrogen storage remains a great challenge. Here, we present a simple and scalable strategy to fabricate a monodispersed, air-stable, magnesium hydride embedded in three-dimensional activated carbon with periodic synchronization of transition metals (MHCH). The high surface area, homogeneous distribution of MgH 2 nanoparticles, excellent thermal stability, high energy density, steric confinement by carbon, and robust architecture of the catalyst resulted in a noticeable enhancement of the hydrogen storage performance. The resulting MHCH-5 exhibited outstanding hydrogen storage performance, better than that of most reported Mg-based hydrides, with a high storage density of 6.63 wt% H 2 , a rapid kinetics loading in hydrogenation compared to that of commercial MgH 2 . The origin of the intrinsic hydrogen thermodynamics was elucidated via solid state 1 H NMR. This work presents a readily scaled-up strategy towards the design of realistic catalysts with superior functionality and stability for applications in reversible hydrogen storage, lithium ion batteries, and fuel cells.

  8. Effects of Cover Crops to Offset Soil Carbon Changes Under No-till on an Ohio farm when Biomass is Harvested

    Science.gov (United States)

    Kimble, J. M.; Everett, L. R.; Richards, W.

    2003-12-01

    The results of a long term experiment to look at the use of cover crops and there effect on soil organic carbon. No-till has been shown to increase SOC and improve the overall soil quality under conditions where the biomass has been returned to the field. However, biomass may be removed as silage or for use in biofuels. The removal will reduce the inputs to the field so to overcome the amount of biomass not returned to the soil different cover crops were used. This experiment was done on a working farm where the corn biomass was being removed as silage. Four cover crops were planted in early September of 2002: rye, oats, clover, and canola with two controls, one with no cover crop and one where corn stubble was left on the field. The soils were sampled soon after the crops were planted and again in the spring of 2003 before the cover crops were killed just prior to planting. The first results indicate that the most root biomass was produced by the rye followed by oats then canola and then clover.

  9. Solid-phase reversible trap for [ sup 1 sup 1 C]carbon dioxide using carbon molecular sieves

    CERN Document Server

    Mock, B H; Mulholland, G T

    1995-01-01

    A simple, maintenance-free trapping technique which concentrates and purifies no-carrier-added sup 1 sup 1 CO sub 2 from gas targets is described. The trap requires no liquid nitrogen cooling and has no moving parts besides solenoid valves. It employs carbon molecular sieves to adsorb sup 1 sup 1 CO sub 2 selectively from gas targets at room temperature. Nitrogen, O sub 2 , CO, NO and moisture in the target gas which could interfere with subsequent radiochemical steps are not retained. Trapping efficiency of 1 g of sieve for sup 1 sup 1 CO sub 2 from a 240 cm sup 3 target gas dump and helium flush cycle is <99%, and the adsorbed sup 1 sup 1 CO sub 2 is recovered quantitatively as a small concentrated bolus from the carbon sieve trap by thermal desorption. This durable trap has performed reliably for more than 1 y with a single charge of carbon sieve. It has simplified the production, and improved the yields of several sup 1 sup 1 C-radiochemicals at this laboratory.

  10. Persulfate Oxidation Regeneration of Granular Activated Carbon: Reversible Impacts on Sorption Behavior

    Science.gov (United States)

    Chemical oxidation regeneration of granular activated carbon (GAC) is a developing technology that can be carried out utilizing thermally-activated persulfate. During chemical regeneration of GAC, aggressive oxidative conditions lead to high acidity (pH < 2) and the accumulation ...

  11. Reversing climate change how carbon removals can resolve climate change and fix the economy

    CERN Document Server

    Chichilnisky, Graciela

    2018-01-01

    The Kyoto Protocol capped the emissions of the main emitters, the industrialized countries, one by one. It also created an innovative financial mechanism, the Carbon Market and its Clean Development Mechanism (CDM), which allows developing nations to receive carbon credits when they reduce their emissions below their baselines. The carbon market, an economic system that created a price for carbon for the first time, is now used in four continents, is promoted by the World Bank, and is recommended even by leading oil and gas companies. However, one critical problem for the future of the Kyoto Protocol is the continuing impasse between the rich and the poor nations. Who should reduce emissions — the rich or the poor countries? This book is about the 21st session of the Conference of the Parties to the United Nations Framework Convention on Climate Change (UNFCCC), or COP21, held from 30 November to 11 December 2015 in Paris, which brought together around 40,000 participants in total — with delegates repre...

  12. Effect of reverse Boudouard reaction catalyst on the performance of solid oxide carbon fuel cells integrated with a dry gasifier

    International Nuclear Information System (INIS)

    Kim, Sun-Kyung; Mehran, Muhammad Taqi; Mushtaq, Usman; Lim, Tak-Hyoung; Lee, Jong-Won; Lee, Seung-Bok; Park, Seok-Joo; Song, Rak-Hyun

    2016-01-01

    Highlights: • The addition of K_2CO_3 catalyst in carbon fuel improves the performance of SO-CFC. • Thermal and electrochemical analyses done to elucidate the catalytic enhancement. • Material characterization of SO-CFC performed after long-term degradation test. - Abstract: A solid oxide carbon fuel cell (SO-CFC) integrated with a dry gasifier was operated on activated carbon fuel and the effect of adding a reverse Boudouard gasification catalyst on the performance and long-term operation characteristics of the SO-CFC was investigated. The reactivity of the carbon fuels for the Boudouard gasification reaction was analyzed by a thermal analysis at various operating conditions. The SO-CFC was then operated on gasified fuel gas consisting of CO_2 and CO obtained from the integrated dry gasifier. The SO-CFC operated on activated carbon fuel with 5 wt.% K_2CO_3 achieved a maximum power density of 202, 262, and 271 mW/cm"2 at 750, 800, and 850 °C, respectively; the SO-CFC fueled with activated carbon fuel without a catalyst meanwhile yielded maximum power density of 168 mW/cm"2 at 850 °C. By using electrochemical impedance spectroscopy, the effect of adding the catalyst on the gasification products and subsequently on the performance of the SO-CFC was studied. A long-term degradation test was conducted by continuously operating the SO-CFC at 50 mA/cm"2 for 518 h at 750 °C. During the long-term degradation test, the average degradation rate of the SO-CFC was found to be 183 mV/kh. The post-mortem SEM and XRD analyses of the SO-CFC after the long-term test revealed the presence of carbon deposits and oxidation of Ni at the anode, causing a relatively higher degree of degradation in the SO-CFC integrated with the dry gasifier during the long-term operation. The addition of the K_2CO_3 based dry gasification catalyst significantly enhances the performance of the SO-CFC integrated with dry gasification, but during long-term operation, the degradation rate is found

  13. High-performance multi-functional reverse osmosis membranes obtained by carbon nanotube·polyamide nanocomposite

    Science.gov (United States)

    Inukai, Shigeki; Cruz-Silva, Rodolfo; Ortiz-Medina, Josue; Morelos-Gomez, Aaron; Takeuchi, Kenji; Hayashi, Takuya; Tanioka, Akihiko; Araki, Takumi; Tejima, Syogo; Noguchi, Toru; Terrones, Mauricio; Endo, Morinobu

    2015-01-01

    Clean water obtained by desalinating sea water or by purifying wastewater, constitutes a major technological objective in the so-called water century. In this work, a high-performance reverse osmosis (RO) composite thin membrane using multi-walled carbon nanotubes (MWCNT) and aromatic polyamide (PA), was successfully prepared by interfacial polymerization. The effect of MWCNT on the chlorine resistance, antifouling and desalination performances of the nanocomposite membranes were studied. We found that a suitable amount of MWCNT in PA, 15.5 wt.%, not only improves the membrane performance in terms of flow and antifouling, but also inhibits the chlorine degradation on these membranes. Therefore, the present results clearly establish a solid foundation towards more efficient large-scale water desalination and other water treatment processes. PMID:26333385

  14. Functionalization of vertically aligned carbon nanotubes with polystyrene via surface initiated reversible addition fragmentation chain transfer polymerization

    Energy Technology Data Exchange (ETDEWEB)

    Macdonald, Thomas; Gibson, Christopher T.; Constantopoulos, Kristina; Shapter, Joseph G. [Flinders Centre for Nanoscale Science and Technology, School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide, SA, 5001 (Australia); Ellis, Amanda V., E-mail: amanda.ellis@flinders.edu.au [Flinders Centre for Nanoscale Science and Technology, School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide, SA, 5001 (Australia)

    2012-01-15

    Here we demonstrate the covalent attachment of vertically aligned (VA) acid treated single-walled carbon nanotubes (SWCNTs) onto a silicon substrate via dicyclohexylcarbodiimide (DCC) coupling chemistry. Subsequently, the pendant carboxyl moieties on the sidewalls of the VA-SWCNTs were derivatized to acyl chlorides, and then finally to bis(dithioester) moieties using a magnesium chloride dithiobenzoate salt. The bis(dithioester) moieties were then successfully shown to act as a chain transfer agent (CTA) in the reversible addition fragmentation chain transfer (RAFT) polymerization of styrene in a surface initiated 'grafting-from' process from the VA-SWCNT surface. Atomic force microscopy (AFM) verified vertical alignment of the SWCNTs and the maintenance thereof throughout the synthesis process. Finally, Raman scattering spectroscopy and AFM confirmed polystyrene functionalization.

  15. Functionalization of vertically aligned carbon nanotubes with polystyrene via surface initiated reversible addition fragmentation chain transfer polymerization

    International Nuclear Information System (INIS)

    Macdonald, Thomas; Gibson, Christopher T.; Constantopoulos, Kristina; Shapter, Joseph G.; Ellis, Amanda V.

    2012-01-01

    Here we demonstrate the covalent attachment of vertically aligned (VA) acid treated single-walled carbon nanotubes (SWCNTs) onto a silicon substrate via dicyclohexylcarbodiimide (DCC) coupling chemistry. Subsequently, the pendant carboxyl moieties on the sidewalls of the VA-SWCNTs were derivatized to acyl chlorides, and then finally to bis(dithioester) moieties using a magnesium chloride dithiobenzoate salt. The bis(dithioester) moieties were then successfully shown to act as a chain transfer agent (CTA) in the reversible addition fragmentation chain transfer (RAFT) polymerization of styrene in a surface initiated “grafting-from” process from the VA-SWCNT surface. Atomic force microscopy (AFM) verified vertical alignment of the SWCNTs and the maintenance thereof throughout the synthesis process. Finally, Raman scattering spectroscopy and AFM confirmed polystyrene functionalization.

  16. Water Diffusion Mechanism in Carbon Nanotube and Polyamide Nanocomposite Reverse Osmosis Membranes: A Possible Percolation-Hopping Mechanism

    Science.gov (United States)

    Araki, Takumi; Cruz-Silva, Rodolfo; Tejima, Syogo; Ortiz-Medina, Josue; Morelos-Gomez, Aaron; Takeuchi, Kenji; Hayashi, Takuya; Terrones, Mauricio; Endo, Morinobu

    2018-02-01

    This paper is a contribution to the Physical Review Applied collection in memory of Mildred S. Dresselhaus. The mechanism of water diffusion across reverse osmosis nanocomposite membranes made of carbon nanotubes (CNTs) and aromatic polyamide is not completely understood despite its high potential for desalination applications. While most of the groups have proposed that superflow inside the CNT might positively impact the water flow across membranes, here we show theoretical evidence that this is not likely the case in composite membranes because CNTs are usually oriented parallel to the membrane surface, not to mention that sometimes the nanotube cores are occluded. Instead, we propose an oriented diffusion mechanism that explains the high water permeation by decreasing the diffusion path of water molecules across the membranes, even in the presence of CNTs that behave as impermeable objects. Finally, we provide a comprehensive description of the molecular dynamics occurring in water desalination membranes by considering the bond polarizability caused by dynamic charge transfer and explore the use of molecular-dynamics-derived stochastic diffusion simulations. The proposed water diffusion mechanism offers an alternative and most likely explanation for the high permeation phenomena observed in CNTs and PA nanocomposite membranes, and its understanding can be helpful to design the next generation of reverse osmosis desalination membranes.

  17. Pulse-reversal electropolymerization of polypyrrole on functionalized carbon nanotubes as composite counter electrodes in dye-sensitized solar cells

    International Nuclear Information System (INIS)

    Wang, Wei-Yan; Ting, Pan-Ning; Luo, Shu-Hui; Lin, Jeng-Yu

    2014-01-01

    Highlights: • MWCNT/PPy composite was incorporated in Pt-free DSCs. • Evenly coating of PPy on MWCNT was achieved by using pulse-reversal technique. • The DSC with theMWCNT/PPy composite reached an efficiency of 6.21%. - Abstract: In this current work, we proposed a modified two-step method to prepare multiwalled carbon nanotube/polypyrrol (MWCNT/PPy) composite counter electrodes (CEs) toward triiodide reduction in dye-sensitized solar cells (DSCs). MWCNTs were deposited onto the surface of fluorinated tin oxide (FTO) glass substrates by electrophoretic deposition, and then subjected to the PPy electropolymerization by using a pulse-reversal technique. With regard to the electropolymerization of PPy on the MWCNTs-coated FTO substrate by conventional cyclic voltammetry (CV) method (designated as MWCNT/PPy-CV CE), the MWCNT/PPy-PR CE still retrained the mesoporous morphology originating from the MWCNT conductive framework and the PPy thin film was found to be evenly coated on the MWCNT surface. According to the extensive electrochemical analyses, the mesoporous nanostructure of the MWCNT/PPy-PR CE provided increased active surface area for I 3 - reduction and facilitated the electron transport at the interface of CE/electrolyte and the redox electrolyte penetration within the CE. As a result, the DSC assembled with the MWCNT/PPy-PR CE reaches a comparable photovoltaic efficiency of 6.21% to that of the DSC based on the Pt CE (6.66%)

  18. Evaluation of the treatment of reverse osmosis concentrates from municipal wastewater reclamation by coagulation and granular activated carbon adsorption.

    Science.gov (United States)

    Sun, Ying-Xue; Yang, Zhe; Ye, Tao; Shi, Na; Tian, Yuan

    2016-07-01

    Reverse osmosis concentrate (ROC) from municipal wastewater reclamation reverse osmosis (mWRRO) contains elevated concentrations of contaminants which pose potential risks to aquatic environment. The treatment of ROC from an mWRRO using granular activated carbon (GAC) combined pretreatment of coagulation was optimized and evaluated. Among the three coagulants tested, ferric chloride (FeCl3) presented relatively higher DOC removal efficiency than polyaluminium chloride and lime at the same dosage and coagulation conditions. The removal efficiency of DOC, genotoxicity, and antiestrogenic activity concentration of the ROC could achieve 16.9, 18.9, and 39.7 %, respectively, by FeCl3 coagulation (with FeCl3 dosage of 180.22 mg/L), which can hardly reduce UV254 and genotoxicity normalized by DOC of the DOM with MW activity were completely eliminated by the GAC adsorption. The results suggest that GAC adsorption combined pretreatment of FeCl3 coagulation as an efficient method to control organics, genotoxicity, and antiestrogenic activity in the ROC from mWRRO system.

  19. Light emission in forward and reverse bias operation in OLED with amorphous silicon carbon nitride thin films

    Science.gov (United States)

    Reyes, R.; Cremona, M.; Achete, C. A.

    2011-01-01

    Amorphous silicon carbon nitride (a-SiC:N) thin films deposited by magnetron sputtering were used in the structure of an organic light emitting diode (OLED), obtaining an OLED operating in forward and reverse bias mode. The device consist of the heterojunction structure ITO/a-SiC:N/Hole Transport Layer (HTL)/ Electron Transport Layer (ETL)/a-SiC:N/Al. As hole transporting layer was used a thin film of 1-(3-methylphenyl)-1,2,3,4 tetrahydroquinoline - 6 - carboxyaldehyde - 1,1'- diphenylhydrazone (MTCD), while the tris(8-hydroxyquinoline aluminum) (Alq3) is used as electron transport and emitting layer. A significant increase in the voltage operation compared to the conventional ITO/MTCD/Alq3/Al structure was observed, so the onset of electroluminescence occurs at about 22 V in the forward and reverse bias mode of operation. The electroluminescence spectra is similar in both cases, only slightly shifted 0.14 eV to lower energies in relation to the conventional device.

  20. Light emission in forward and reverse bias operation in OLED with amorphous silicon carbon nitride thin films

    Energy Technology Data Exchange (ETDEWEB)

    Reyes, R [Facultad de Ingenieria Quimica y Textil, Universidad Nacional de Ingenieria, Av. Tupac Amaru SN, Lima (Peru); Cremona, M [Departamento de Fisica, PontifIcia Universidade Catolica de Rio de Janeiro, PUC-Rio, Cx. Postal 38071, Rio de Janeiro, RJ, CEP 22453-970 (Brazil); Achete, C A, E-mail: rreyes@uni.edu.pe [Departamento de Engenheria Metalurgica e de Materiais, Universidade Federal do Rio de Janeiro, Cx. Postal 68505, Rio de Janeiro, RJ, CEP 21945-970 (Brazil)

    2011-01-01

    Amorphous silicon carbon nitride (a-SiC:N) thin films deposited by magnetron sputtering were used in the structure of an organic light emitting diode (OLED), obtaining an OLED operating in forward and reverse bias mode. The device consist of the heterojunction structure ITO/a-SiC:N/Hole Transport Layer (HTL)/ Electron Transport Layer (ETL)/a-SiC:N/Al. As hole transporting layer was used a thin film of 1-(3-methylphenyl)-1,2,3,4 tetrahydroquinoline - 6 - carboxyaldehyde - 1,1'- diphenylhydrazone (MTCD), while the tris(8-hydroxyquinoline aluminum) (Alq{sub 3}) is used as electron transport and emitting layer. A significant increase in the voltage operation compared to the conventional ITO/MTCD/Alq{sub 3}/Al structure was observed, so the onset of electroluminescence occurs at about 22 V in the forward and reverse bias mode of operation. The electroluminescence spectra is similar in both cases, only slightly shifted 0.14 eV to lower energies in relation to the conventional device.

  1. Light emission in forward and reverse bias operation in OLED with amorphous silicon carbon nitride thin films

    International Nuclear Information System (INIS)

    Reyes, R; Cremona, M; Achete, C A

    2011-01-01

    Amorphous silicon carbon nitride (a-SiC:N) thin films deposited by magnetron sputtering were used in the structure of an organic light emitting diode (OLED), obtaining an OLED operating in forward and reverse bias mode. The device consist of the heterojunction structure ITO/a-SiC:N/Hole Transport Layer (HTL)/ Electron Transport Layer (ETL)/a-SiC:N/Al. As hole transporting layer was used a thin film of 1-(3-methylphenyl)-1,2,3,4 tetrahydroquinoline - 6 - carboxyaldehyde - 1,1'- diphenylhydrazone (MTCD), while the tris(8-hydroxyquinoline aluminum) (Alq 3 ) is used as electron transport and emitting layer. A significant increase in the voltage operation compared to the conventional ITO/MTCD/Alq 3 /Al structure was observed, so the onset of electroluminescence occurs at about 22 V in the forward and reverse bias mode of operation. The electroluminescence spectra is similar in both cases, only slightly shifted 0.14 eV to lower energies in relation to the conventional device.

  2. Carbon Neutrality and the Use of Offsets

    Science.gov (United States)

    Ney, Richard A.; Purman, Judith R.

    2009-01-01

    Many organizations, including colleges and universities, are moving to address the threat of climate change by reducing greenhouse gas (GHG) emissions from their operations. For example, the rapid growth of participation in the Presidents Climate Commitment (PCC) now means that more than 600 colleges and universities have pledged to develop plans…

  3. Austenite reversion in low-carbon martensitic stainless steels – a CALPHAD-assisted review

    DEFF Research Database (Denmark)

    Niessen, Frank

    2018-01-01

    Low-carbon martensitic stainless steels with 11.5–16 wt-% Cr and martensite upon inter-critical annealing. The review treats...... the mechanisms governing the formation and stabilisation of reverted austenite and is assisted by the computation of phase equilibria. Literature data on Cr and Ni concentrations of the reverted austenite/martensite dual-phase microstructure are assessed with respect to predicted concentrations. Reasonable...... agreement was found for concentrations in martensite. Systematic excess of Cr in austenite of approx. 2 wt-% relative to calculations was suspected to originate from the growth of M23C6 with a coherent interface to austenite. Within large scatter, measured values of Ni in austenite were on average 2 wt...

  4. BC Hydro shops for GHG offsets

    International Nuclear Information System (INIS)

    Anon.

    2000-01-01

    BC Hydro is reported to have offered to purchase one million tonnes of carbon dioxide reductions in Canada's Greenhouse Gas Emissions Reduction Trading program (GERT). The program uses a baseline and credit system, where emitters purchase measurable quantities of site-specific GHG reductions. Since mid-1998, the program registered five bilateral trades and seven offers to sell. BC Hydro's recent offer is the first offer to buy. BC Hydro has made the offer to buy in expectation of the introduction of the start of the Kyoto Protocol reductions, and expects to be in the game for some time to come if it is to meet its obligations under the Kyoto Protocol. Preference will be given to projects located in Canada, but BC Hydro will consider reductions created anywhere in the world. The financial range of a single trade is between $50,000 and $1 million. (GHG offsets are currently trading in North America for between $.50 and $3.00 Cdn per metric tonne of carbon dioxide equivalent.) At present, offsets are selling at a heavily discounted price because of the uncertainty that investments made now will be credited against future regulations curbing emitters. Consequently, buying now while prices are low, may lead to sizable benefits later, depending on the actual regulations when they are promulgated. Trading now will also give BC Hydro greater credibility and assurance to have its voice heard when discussions about emissions trading and the implementation of emission trading rules reaches the serious stage

  5. Offsets - An opportunity of Financing

    International Nuclear Information System (INIS)

    PRIN, Coralie

    2008-01-01

    Nuclear Research Reactors sometimes need to implement projects to upgrade, revamp or convert their reactor, acquire new fuel elements, etc. However, as their activities are mainly of noncommercial nature, they sometimes lack of financial resources to implement these projects by themselves. Several solutions exist: loans, governmental budget, subsidies from international organizations (IAEA). Offsets are another source of financing. They also are free of charge for the reactor. The objective of offsets is to Identify, implement and finance projects that: directly create or sustain a local economic activity of high-added value, would not have happened without the Obligor's intervention, and are of crucial importance given the country's political background (favor employment, technology transfers, training and education, research and development, etc.). Companies worldwide are willing to finance local projects to fulfill their Offset Obligation. Local organizations or institutions are willing to invest to increase their activities but lack of financial resources. Offset regulations are an opportunity on both sides and are free for the local organization. The monetary value of an Offset obligation is calculated as a percentage of the main contract price (or as a percentage of the imported part value). That percentage depends on the Country's legislation and on the nature of the main contract (defense or civilian). This value has to be compensated by an equivalent economic value (a Project's cost is different from its value). There is two ways of assessing a value: - Political aspects: The Project is of political importance for the country (development of an export capability, technology and/or know-how transfers) and the project in line with the country's political priorities (employment, research, international presence, etc.). - Economic benefits: the project directly sustains or creates additional activities, turnover, R and D, employment, etc. It benefits directly

  6. Bottom-up linking of carbon markets under far-sighted cap coordination and reversibility

    Science.gov (United States)

    Heitzig, Jobst; Kornek, Ulrike

    2018-03-01

    The Paris Agreement relies on nationally determined contributions to reach its targets and asks countries to increase ambitions over time, leaving open the details of this process. Although overcoming countries' myopic `free-riding' incentives requires cooperation, the global public good character of mitigation makes forming coalitions difficult. To cooperate, countries may link their carbon markets1, but is this option beneficial2? Some countries might not participate, not agree to lower caps, or not comply to agreements. While non-compliance might be deterred3, countries can hope that if they don't participate, others might still form a coalition. When considering only one coalition whose members can leave freely, the literature following the publication of refs 4,5 finds meagre prospects for effective collaboration6. Countries also face incentives to increase emissions when linking their markets without a cap agreement7,8. Here, we analyse the dynamics of market linkage using a game-theoretic model of far-sighted coalition formation. In contrast to non-dynamic models and dynamic models without far-sightedness9,10, in our model an efficient global coalition always forms eventually if players are sufficiently far-sighted or caps are coordinated immediately when markets are linked.

  7. Forest gardening on abandoned terraces links local biomass carbon accumulation to international carbon markets, reverses land degradation, improves food diversity, and increases farmer income

    Science.gov (United States)

    Schmidt, Hans-Peter; Pandit, Bishnu Hari; Kammann, Claudia

    2017-04-01

    project to a carbon capture financing system. All planted trees are GIS inventoried and their yearly biomass carbon up-take is calculated on the base of the average ten-year carbon accumulation. The 25,000 mixed trees accumulate the equivalent of 350 t CO2 per year. At 35 US per t of CO2eq paid in advance by the international community in form of private carbon compensation subscriptions, all costs for the set-up of the forest gardens, their maintenance for three years plus a yearly prime could be paid. After this initial period of three years, the income from tree crops (fruits, nuts, medicine, essential oil, silk, perfume, honey, timber, animal fodder) exceeds by far the (catalyzer) carbon credits providing average crop incomes for the 25,000 trees including secondary mixed cropping of more than 150,000 USD per year. With new processed tree crop products, better-paid jobs are created, the local economy is fostered and the "lost generation" can start to return to their home villages. The objective of this pilot forest garden project was to establish a robust socio-agronomic system that can be multiplied from village to village, increasing soil fertility, protecting abandoned terraces from erosion, replenishing water resources, and generating stable incomes with climate-smart agriculture. The essential catalyst of the project was to link the global need to capture atmospheric carbon and to create negative emissions to slow down climate change with the local capacity to increase biomass growth and to sequester biomass carbon with new low-tech technology (biochar). The financial exchange between global CO2-emmitting communities with local CO2 capturing farmer communities could become a new motor to reverse land degradation, to reestablish ecosystem services, and to develop the rural socio-economy.

  8. 7 CFR 400.129 - Salary offset.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 6 2010-01-01 2010-01-01 false Salary offset. 400.129 Section 400.129 Agriculture... Years § 400.129 Salary offset. (a) Debt collection by salary offset is feasible if: the cost to the Government of collection by salary offset does not exceed the amount of the debt; there are no legal...

  9. Surface modification of commercial seawater reverse osmosis membranes by grafting of hydrophilic monomer blended with carboxylated multiwalled carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Vatanpour, Vahid, E-mail: vahidvatanpour@khu.ac.ir; Zoqi, Naser

    2017-02-28

    Highlights: • A commercial PA RO membrane was modified by grafting of hydrophilic acrylic acid. • COOH-MWCNTs were mixed in grafting layer to increase permeability and antifouling. • However, more increase of CNTs caused in reduction of flux of the membranes. • Effect of acrylic acid amount, contact time and curing time was optimized. - Abstract: In this study, modification of commercial seawater reverse osmosis membranes was carried out with simultaneous use of surface grafting and nanoparticle incorporation. Membrane grafting with a hydrophilic acrylic acid monomer and thermal initiator was used to increase membrane surface hydrophilicity. The used nanomaterial was carboxylated multiwalled carbon nanotubes (MWCNTs), which were dispersed in the grafting solution and deposited on membrane surface to reduce fouling by creating polymer brushes and hydrodynamic resistance. Effectiveness of the grafting process (formation of graft layer on membrane surface) was proved by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analyses. Increase of membrane surface hydrophilicity was approved with contact angle test. First, the grafting was performed on the membrane surfaces with different monomer concentrations, various contact times and several membrane curing times (three variables for optimization). The modified membranes were tested by a cross-flow setup using saline solution for permeability and rejection tests, and bovine serum albumin (BSA) solution for fouling test. The results showed that the modified membranes with 0.75 M of monomer, 3 min contact time and 80 min curing time in an oven at 50 °C presented the highest flux and lowest rejection decline related to the commercial reverse osmosis membrane. In the next step, the optimum grafting condition was selected and the nanotubes with different weight percentages were dispersed in the acrylic acid monomer solution. The membrane containing 0.25 wt% COOH-MWCNTs showed the

  10. Surface modification of commercial seawater reverse osmosis membranes by grafting of hydrophilic monomer blended with carboxylated multiwalled carbon nanotubes

    International Nuclear Information System (INIS)

    Vatanpour, Vahid; Zoqi, Naser

    2017-01-01

    Highlights: • A commercial PA RO membrane was modified by grafting of hydrophilic acrylic acid. • COOH-MWCNTs were mixed in grafting layer to increase permeability and antifouling. • However, more increase of CNTs caused in reduction of flux of the membranes. • Effect of acrylic acid amount, contact time and curing time was optimized. - Abstract: In this study, modification of commercial seawater reverse osmosis membranes was carried out with simultaneous use of surface grafting and nanoparticle incorporation. Membrane grafting with a hydrophilic acrylic acid monomer and thermal initiator was used to increase membrane surface hydrophilicity. The used nanomaterial was carboxylated multiwalled carbon nanotubes (MWCNTs), which were dispersed in the grafting solution and deposited on membrane surface to reduce fouling by creating polymer brushes and hydrodynamic resistance. Effectiveness of the grafting process (formation of graft layer on membrane surface) was proved by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analyses. Increase of membrane surface hydrophilicity was approved with contact angle test. First, the grafting was performed on the membrane surfaces with different monomer concentrations, various contact times and several membrane curing times (three variables for optimization). The modified membranes were tested by a cross-flow setup using saline solution for permeability and rejection tests, and bovine serum albumin (BSA) solution for fouling test. The results showed that the modified membranes with 0.75 M of monomer, 3 min contact time and 80 min curing time in an oven at 50 °C presented the highest flux and lowest rejection decline related to the commercial reverse osmosis membrane. In the next step, the optimum grafting condition was selected and the nanotubes with different weight percentages were dispersed in the acrylic acid monomer solution. The membrane containing 0.25 wt% COOH-MWCNTs showed the

  11. Contribution of assimilable organic carbon to biological fouling in seawater reverse osmosis membrane treatment.

    Science.gov (United States)

    Weinrich, Lauren; LeChevallier, Mark; Haas, Charles N

    2016-09-15

    Biological fouling occurs on RO membranes when bacteria and nutrients are present in conditions that are conducive to growth and proliferation of the bacteria. Controlling microbial growth on the membranes is typically limited to biocide application (i.e., disinfectants) in seawater RO plants. However, biological growth and subsequent fouling has not been well-managed. Pretreatment has not been focused on nutrient limitation. This project used a biological assay, the assimilable organic carbon (AOC) test to evaluate pretreatment effects on the nutrient supply. The AOC test provided a useful surrogate measurement for the biodegradability or biofouling potential of RO feed water. Biofouling observed in controlled conditions at the bench- and pilot-scale resulted in statistically significant correlations between AOC and the operational effects caused by biofouling. Membrane fouling rates are observed through operational changes over time such as increased differential pressure between the membrane feed and concentrate locations and decreased permeate flux through the membrane. In full scale plants there were strong correlations when AOC was used as a predictor variable for increased differential pressure (0.28-0.55 bar from September-December 2012) and decreased specific flux (1.40 L per hour/(m(2) · bar)). Increased differential pressure was associated with RO membrane biological fouling when the median AOC was 50 μg/L during pilot testing. Conditions were also evaluated at the bench-scale using a flat sheet RO membrane. In a comparison test using 30 and 1000 μg/L AOC, fouling was detected on more portions of the membrane when AOC was higher. Biofilm and bacterial deposits were apparent from scanning electron microscope imaging and biomass measurements using ATP. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Offsets and conservation of the species of the EU habitats and birds directives.

    Science.gov (United States)

    Regnery, Baptiste; Couvet, Denis; Kerbiriou, Christian

    2013-12-01

    Biodiversity offsets are intended to achieve no net loss of biodiversity due to economic and human development. A variety of biodiversity components are addressed by offset policies. It is required that loss of protected species due to development be offset under the EU Habitats and Birds Directives in Europe. We call this type of offset a species-equality offset because the offset pertains to the same species affected by the development project. Whether species equality can be achieved by offset design is unknown. We addressed this gap by reviewing derogation files (i.e., specific files that describe mitigation measures to ensure no net loss under the EU Habitats and Birds Directives) from 85 development projects in France (2009-2010). We collected information on type of effect (reversible vs. irreversible) and characteristics of affected and offset sites (i.e., types of species, total area). We analyzed how the type of effect and the affected-site characteristics influenced the occurrence of offset measures. The proportion of species targeted by offset measures (i.e., offset species) increased with the irreversibility of the effect of development and the conservation status of the species affected by development (i.e., affected species). Not all effects on endangered species (International Union for Conservation of Nature Red List) were offset; on average, 82% of affected species would be offset. Twenty-six percent of species of least concern were offset species. Thirty-five percent of development projects considered all affected species in their offset measures. Species richness was much lower in offset sites than in developed sites even after offset proposals. For developed areas where species richness was relatively high before development, species richness at offset sites was 5-10 times lower. The species-equality principle appears to have been applied only partially in offset policies, as in the EU directives. We suggest the application of this principle

  13. The spammed code offset method

    NARCIS (Netherlands)

    Skoric, B.; Vreede, de N.

    2013-01-01

    Helper data schemes are a security primitive used for privacy-preserving biometric databases and Physical Unclonable Functions. One of the oldest known helper data schemes is the Code Offset Method (COM). We propose an extension of the COM: the helper data is accompanied by many instances of fake

  14. The spammed code offset method

    NARCIS (Netherlands)

    Skoric, B.; Vreede, de N.

    2014-01-01

    Helper data schemes are a security primitive used for privacy-preserving biometric databases and physical unclonable functions. One of the oldest known helper data schemes is the code offset method (COM). We propose an extension of the COM: the helper data are accompanied by many instances of fake

  15. Strong and reversible modulation of carbon nanotube-silicon heterojunction solar cells by an interfacial oxide layer.

    Science.gov (United States)

    Jia, Yi; Cao, Anyuan; Kang, Feiyu; Li, Peixu; Gui, Xuchun; Zhang, Luhui; Shi, Enzheng; Wei, Jinquan; Wang, Kunlin; Zhu, Hongwei; Wu, Dehai

    2012-06-21

    Deposition of nanostructures such as carbon nanotubes on Si wafers to make heterojunction structures is a promising route toward high efficiency solar cells with reduced cost. Here, we show a significant enhancement in the cell characteristics and power conversion efficiency by growing a silicon oxide layer at the interface between the nanotube film and Si substrate. The cell efficiency increases steadily from 0.5% without interfacial oxide to 8.8% with an optimal oxide thickness of about 1 nm. This systematic study reveals that formation of an oxide layer switches charge transport from thermionic emission to a mixture of thermionic emission and tunneling and improves overall diode properties, which are critical factors for tailoring the cell behavior. By controlled formation and removal of interfacial oxide, we demonstrate oscillation of the cell parameters between two extreme states, where the cell efficiency can be reversibly altered by a factor of 500. Our results suggest that the oxide layer plays an important role in Si-based photovoltaics, and it might be utilized to tune the cell performance in various nanostructure-Si heterojunction structures.

  16. Diazonium modification of porous graphitic carbon with catechol and amide groups for hydrophilic interaction and attenuated reversed phase liquid chromatography.

    Science.gov (United States)

    Iverson, Chad D; Zhang, Ya; Lucy, Charles A

    2015-11-27

    Porous graphitic carbon (PGC) is an increasingly popular and attractive phase for HPLC on account of its chemical and thermal stability, and its unique separation mechanism. However, native PGC is strongly hydrophobic and in some instances excessively retentive. As part of our effort to build a library of hydrophilic covalently modified PGC phases, we functionalized PGC with catechol and amide groups by means of aryl diazonium chemistry to produce two new phases. Successful grafting was confirmed by X-ray photoelectron spectroscopy (XPS). Under HILIC conditions, the Catechol-PGC showed up to 5-fold increased retention relative to unmodified PGC and selectivity that differed from four other HILIC phases. Under reversed phase conditions, the Amide-PGC reduced the retentivity of PGC by almost 90%. The chromatographic performance of Catechol-PGC and Amide-PGC is demonstrated by separations of nucleobases, nucleosides, phenols, alkaline pharmaceuticals, and performance enhancing stimulants. These compounds had retention factors (k) ranging from 0.5 to 13. Copyright © 2015 Elsevier B.V. All rights reserved.

  17. The voluntary offset - approaches and limitations

    International Nuclear Information System (INIS)

    2012-06-01

    After having briefly presented the voluntary offset mechanism which aims at funding a project of reduction or capture of greenhouse gas emissions, this document describes the approach to be followed to adopt this voluntary offset, for individuals as well as for companies, communities or event organisations. It describes other important context issues (projects developed under the voluntary offset, actors of the voluntary offsetting market, market status, offset labels), and how to proceed in practice (definition of objectives and expectations, search for needed requirements, to ensure the meeting of requirements with respect to expectations). It addresses the case of voluntary offset in France (difficult implantation, possible solutions)

  18. Dual Carbon-Confined SnO2 Hollow Nanospheres Enabling High Performance for the Reversible Storage of Alkali Metal Ions.

    Science.gov (United States)

    Wu, Qiong; Shao, Qi; Li, Qiang; Duan, Qian; Li, Yanhui; Wang, Heng-Guo

    2018-04-25

    To explore a universal electrode material for the high-performance electrochemical storage of Li + , Na + , and K + ions remains a big challenge. Herein, we propose a "trinity" strategy to coat the SnO 2 hollow nanospheres using the dual carbon layer from the polydopamine-derived nitrogen-doped carbon and graphene. Thereinto, hollow structures with sufficient void space could buffer the volume expansion, whereas dual carbon-confined strategy could not only elastically prevent the aggregation of nanoparticle and ensure the structural integrity but also immensely improve the conductivity and endow high rate properties. Benefiting from the effective strategy and specific structure, the dual carbon-confined SnO 2 hollow nanosphere (denoted as G@C@SnO 2 ) can serve as the universal host material for alkali metal ions and enable their rapid and reversible storage. As expected, the resulting G@C@SnO 2 as a universal anode material shows reversible alkali-metal-ion storage with high performance. We believe this that strategy could pave the way for constructing other metal-oxide-based dual carbon-confined high-performance materials for the future energy storage applications.

  19. Pellicular particles with spherical carbon cores and porous nanodiamond/polymer shells for reversed-phase HPLC.

    Science.gov (United States)

    Wiest, Landon A; Jensen, David S; Hung, Chuan-Hsi; Olsen, Rebecca E; Davis, Robert C; Vail, Michael A; Dadson, Andrew E; Nesterenko, Pavel N; Linford, Matthew R

    2011-07-15

    A new stationary phase for reversed-phase high performance liquid chromatography (RP HPLC) was created by coating spherical 3 μm carbon core particles in a layer-by-layer (LbL) fashion with poly(allylamine) (PAAm) and nanodiamond. Unfunctionalized core carbon particles were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), time-of-flight secondary ion mass spectrometry (ToF-SIMS), and Raman spectroscopy. After LbL of PAAm and nanodiamond, which yields ca. 4 μm core-shell particles, the particles were simultaneously functionalized and cross-linked using a mixture of 1,2-epoxyoctadecane and 1,2,7,8-diepoxyoctane to obtain a mechanically stable C(18)/C(8) bonded outer layer. Core-shell particles were characterized by SEM, and their surface area, pore diameter, and volume were determined using the Brunauer-Emmett-Teller (BET) method. Short stainless steel columns (30 × 4.6 mm i.d.) were packed and the corresponding van Deemter plots obtained. The Supporting Information contains a MATLAB program used to fit the van Deemter data. The retentions of a suite of analytes were investigated on a conventional HPLC at various organic solvent compositions, pH values of mobile phases, including extreme pH values, and column temperatures. At 60 °C, a chromatogram of 2,6-diisopropylphenol showed 71,500 plates/m (N/m). Chromatograms obtained under acidic conditions (pH 2.7) of a mixture of acetaminophen, diazepam, and 2,6-diisopropylphenol and a mixture of phenol, 4-methylphenol, 2-chlorophenol, 4-chlorophenol, 4-bromophenol, and 1-tert-butyl-4-methylphenol are presented. Retention of amitriptyline, cholesterol, and diazinon at temperatures ranging from 35 to 80 °C and at pH 11.3 is reported. A series of five basic drugs was also separated at this pH. The stationary phase exhibits considerable hydrolytic stability at high pH (11.3) and even pH 13 over extended periods of time. An analysis run on a UHPLC with a "sandwich" injection

  20. One-Pot Synthesis of Carbon-Coated SnO 2 Nanocolloids with Improved Reversible Lithium Storage Properties

    KAUST Repository

    Lou, Xiong Wen; Chen, Jun Song; Chen, Peng; Archer, Lynden A.

    2009-01-01

    of 300 mA/g in hybrid SnO 2-carbon electrodes containing as much as 1/3 of their mass in the low-activity carbon shell. By reducing the SnO 2-carbon particles with H 2, we demonstrate a simple route to carbon-coated Sn nanospheres. Lithium storage

  1. Reversible and irreversible impacts of greenhouse gas emissions in multi-century projections with the NCAR global coupled carbon cycle-climate model

    Energy Technology Data Exchange (ETDEWEB)

    Froelicher, Thomas L.; Joos, Fortunat [University of Bern, Climate and Environmental Physics, Physics Institute, Bern (Switzerland); University of Bern, Oeschger Centre for Climate Change Research, Bern (Switzerland)

    2010-12-15

    The legacy of historical and the long-term impacts of 21st century greenhouse gas emissions on climate, ocean acidification, and carbon-climate feedbacks are investigated with a coupled carbon cycle-climate model. Emission commitment scenarios with zero emissions after year 2100 and 21st century emissions of 1,800, 900, and 0 gigatons of carbon are run up to year 2500. The reversibility and irreversibility of impacts is quantified by comparing anthropogenically-forced regional changes with internal, unforced climate variability. We show that the influence of historical emissions and of non-CO{sub 2} agents is largely reversible on the regional scale. Forced changes in surface temperature and precipitation become smaller than internal variability for most land and ocean grid cells in the absence of future carbon emissions. In contrast, continued carbon emissions over the 21st century cause irreversible climate change on centennial to millennial timescales in most regions and impacts related to ocean acidification and sea level rise continue to aggravate for centuries even if emissions are stopped in year 2100. Undersaturation of the Arctic surface ocean with respect to aragonite, a mineral form of calcium carbonate secreted by marine organisms, is imminent and remains widespread. The volume of supersaturated water providing habitat to calcifying organisms is reduced from preindustrial 40 to 25% in 2100 and to 10% in 2300 for the high emission case. We conclude that emission trading schemes, related to the Kyoto Process, should not permit trading between emissions of relatively short-lived agents and CO{sub 2} given the irreversible impacts of anthropogenic carbon emissions. (orig.)

  2. 34 CFR 31.11 - Offset process.

    Science.gov (United States)

    2010-07-01

    ... 34 Education 1 2010-07-01 2010-07-01 false Offset process. 31.11 Section 31.11 Education Office of the Secretary, Department of Education SALARY OFFSET FOR FEDERAL EMPLOYEES WHO ARE INDEBTED TO THE UNITED STATES UNDER PROGRAMS ADMINISTERED BY THE SECRETARY OF EDUCATION § 31.11 Offset process. (a) The...

  3. 5 CFR 179.307 - Administrative offset.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Administrative offset. 179.307 Section 179.307 Administrative Personnel OFFICE OF PERSONNEL MANAGEMENT CIVIL SERVICE REGULATIONS CLAIMS COLLECTION STANDARDS Administrative Offset § 179.307 Administrative offset. (a) If the debtor does not...

  4. Workshop Papers: CERI's Alberta Offset Development Workshop

    International Nuclear Information System (INIS)

    1998-01-01

    New and innovative policy approaches are necessary to help Canada achieve its target for greenhouse gas (GHG) emission reductions, since it is becoming clear that the voluntary action plans that are currently in place are not adequate to address climate change. The use of economic instruments to reduce greenhouse gas emissions was the focus of this conference. Topics included various forms of greenhouse gas emissions trading, taxation instruments, and hybrid instruments which make use of both emissions trading and emissions charges. The three forms of emission trading - carbon content trading, allowance trading, and credit trading - which have the potential to beneficially influence climate change were explored by several participants. Technical and policy related issues were explored in detail and the manner in which offsets fit into global, regional and local scenarios were reviewed. It was emphasized that clear and consistent policy signals and a flexible attitude from government is necessary to interest greenhouse gas emitters in taking action to reduce emissions without sacrificing the economy. Under a joint implementation framework recently agreed to at Kyoto, developed countries could earn credits for limiting emissions or enhancing carbon sinks in other countries by taking advantage of the low costs of emission reductions in developing countries. To date, this is the most fertile area for innovative action for effecting a global reduction in greenhouse gas emissions. refs., tabs., figs

  5. Guidance document to the BC emission offsets regulation

    International Nuclear Information System (INIS)

    2010-11-01

    British Columbia's (BC) emission offset regulations were established under the Greenhouse Gas Reduction Targets Act passed in 2007. Targets for greenhouse gas (GHG) emission reductions included a 6 percent reduction by 2012; an 18 percent reduction by 2016; a 33 percent reduction by 2020; and an 80 percent reduction by 2050. Carbon neutral agreements began in 2008, and covered emissions produced from government business travel and by provincial government ministries and agencies. This report presented a list of key recommendations developed by the Pacific Carbon Trust for use in future carbon offset projects. Recommendations included the use of correct emission factors when quantifying projected emission reductions from an offset project; the use of a robust data management system; and the use of evidence in supporting additionality arguments. The document outlined planning procedures for project baseline selection processes, protocol selections, and the identification of sources sinks and reservoirs. Issues related to quantification and measurements, emissions factors, and accuracy and uncertainty were also addressed. Validation, verification, and contracting options were also presented. 6 tabs., 3 figs.

  6. One-Pot Synthesis of Carbon-Coated SnO 2 Nanocolloids with Improved Reversible Lithium Storage Properties

    KAUST Repository

    Lou, Xiong Wen

    2009-07-14

    We report a simple glucose-mediated hydrothermal method for gram-scale synthesis of nearly monodisperse hybrid SnO 2 nanoparticles. Glucose is found to play the dual role of facilitating rapid precipitation of polycrystalline SnO 2 nanocolloids and in creating a uniform, glucose-derived, carbon-rich polysaccharide (GCP) coating on the SnO 2 nanocores. The thickness of the GCP coating can be facilely manipulated by varying glucose concentration in the synthesis medium. Carbon-coated SnO 2 nanocolloids obtained after carbonization of the GCP coating exhibit significantly enhanced cycling performance for lithium storage. Specifically, we find that a capacity of ca. 440 mA h/g can be obtained after more than 100 charge/discharge cycles at a current density of 300 mA/g in hybrid SnO 2-carbon electrodes containing as much as 1/3 of their mass in the low-activity carbon shell. By reducing the SnO 2-carbon particles with H 2, we demonstrate a simple route to carbon-coated Sn nanospheres. Lithium storage properties of the latter materials are also reported. Our results suggest that large initial irreversible losses in these materials are caused not only by the initial, presumably irreversible, reduction of SnO 2 as generally perceived in the field, but also by the formation of the solid electrolyte interface (SEI). © 2009 American Chemical Society.

  7. Synergetic interface between NiO/Ni3S2 nanosheets and carbon nanofiber as binder-free anode for highly reversible lithium storage

    Science.gov (United States)

    Jiang, Jialin; Ma, Chao; Yang, Yinbo; Ding, Jingjing; Ji, Hongmei; Shi, Shaojun; Yang, Gang

    2018-05-01

    A novel heterostructure of NiO/Ni3S2 nanoflake is synthesized and composited with carbon nanofibers (CNF) membrane. NiO/Ni3S2 nanoflakes are homogeneously dispersed in CNF network, herein, NiO/Ni3S2 like leaf and CNF like branch. Carbon nanofibers network efficiently prevents the pulverization and buffers the volume changes of NiO/Ni3S2, meanwhile, NiO/Ni3S2 nanoflakes through the conductive channels of carbon nanofibers own improved Li+ diffusion ability and structural stability. The capacity of NiO/Ni3S2/CNF reaches to 519.2 mA g-1 after 200 cycles at the current density of 0.5 A g-1 while NiO/Ni3S2 fades to 71 mAh g-1 after 40 cycles. Owing to the synergetic structure, the resultant binder-free electrode NiO/Ni3S2/carbon nanofibers shows an excellent reversible lithium storage capability.

  8. Forest biomass and tree planting for fossil fuel offsets in the Colorado Front Range

    Science.gov (United States)

    Mike A. Battaglia; Kellen Nelson; Dan Kashian; Michael G. Ryan

    2010-01-01

    This study estimates the amount of carbon available for removal in fuel reduction and reforestation treatments in montane forests of the Colorado Front Range based on site productivity, pre-treatment basal area, and planting density. Thinning dense stands will yield the greatest offsets for biomass fuel. However, this will also yield the greatest carbon losses, if the...

  9. Si-Carbon Composite Nanofibers with Good scalability and Favorable Architecture for Highly Reversible Lithium Storage and Superb Kinetics

    International Nuclear Information System (INIS)

    Lee, Youngmin; Heo, Yoon-Uk; Song, Dahye; Shin, Dong Wook; Kang, Yong-Mook

    2014-01-01

    We demonstrate a simple electrospinning for preparing Si-carbon composite Nanofiber (NF) in which aciniform aggregates of Si particles are well encased by amorphous carbon. The Si-carbon composite NF exhibit a significantly improved electrochemical performance with a high specific capacity of 1250 mAh·g −1 and a superior cycling performance during 50 cycles at a rate of 0.2 C. More importantly, Si-carbon composite NF maintain about 70% of initial capacity at 0.2 C and an excellent cycling stability even at 25 times higher current density compared to the initial condition, proving that it has superb kinetics compared to ever reported Si or SiO x materials. The electrochemical superiority of Si-carbon composite NF can be attributed to amorphous carbon framework accommodating the inherent volume expansion of Si during lithiation as well as the enlarged contact area between active materials and conducting agent attributed to the morphological characteristics of its one dimensional (1D) nanostructure

  10. Utilization of curve offsets in additive manufacturing

    Science.gov (United States)

    Haseltalab, Vahid; Yaman, Ulas; Dolen, Melik

    2018-05-01

    Curve offsets are utilized in different fields of engineering and science. Additive manufacturing, which lately becomes an explicit requirement in manufacturing industry, utilizes curve offsets widely. One of the necessities of offsetting is for scaling which is required if there is shrinkage after the fabrication or if the surface quality of the resulting part is unacceptable. Therefore, some post-processing is indispensable. But the major application of curve offsets in additive manufacturing processes is for generating head trajectories. In a point-wise AM process, a correct tool-path in each layer can reduce lots of costs and increase the surface quality of the fabricated parts. In this study, different curve offset generation algorithms are analyzed to show their capabilities and disadvantages through some test cases and improvements on their drawbacks are suggested.

  11. HST-COS Observations on Hydrogen, Helium, Carbon, and Nitrogen Emission from the SN 1987A Reverse Shock

    Science.gov (United States)

    France, Kevin; McCray, Richard; Penton, Steven V.; Kirshner, Robert P.; Challis, Peter; Laming, J. Martin; Bouchet, Patrice; Chevalier, Roger; Garnavich, Peter M.; Fransson, Claes; hide

    2011-01-01

    We present the most sensitive ultraviolet observations of Supernova 1987 A to date. Imaging spectroscopy from the Hubble Space Telescope-Cosmic Origins Spectrograph shows many narrow (Delta v approximates 300 km/s) emission lines from the circumstellar ring, broad Delta v approximates 10-20 x 10(exp 3) km/s) emission lines from the reverse shock, and ultraviolet continuum emission. The high signal-to-noise ratio (>40 per resolution element) broad Ly-alpha emission is excited by soft X-ray and EUV heating of mostly neutral gas in the circumstellar ring and outer supernova debris. The ultraviolet continuum at lambda > 1350 A can be explained by H-I two-photon (2s(exp 2)S(sub 1/2)-l(exp 2)S(sub 1/2)) emission from the same region. We confirm our earlier, tentative detection of N V lambda 1240 emission from the reverse shock and present the first detections of broad He II lambda1640, C IV lambda 1550, and N IV ] lambda1486 emission lines from the reverse shock. The helium abundance in the high-velocity material is He/H = 0.14 +/- 0.06. The N V /H alpha line ratio requires partial ion-electron equilibration (T(sub e)/T(sub p) approximately equal to 0.14-0.35). We find that the N/C abundance ratio in the gas crossing the reverse shock is significantly higher than that in the circumstellar ring, a result that may be attributed to chemical stratification in the outer envelope of the supernova progenitor. The N/C abundance may have been stratified prior to the ring expUlsion, or this result may indicate continued CNO processing in the progenitor subsequent to the expUlsion of the circumstellar ring.

  12. HPLC in Reversed Phase Mode: Tool for Investigation of Kinetics of Blackcurrant Seed Oil Lipolysis in Supercritical Carbon Dioxide

    Czech Academy of Sciences Publication Activity Database

    Bártlová, Milena; Bernášek, Prokop; Sýkora, Jan; Sovová, Helena

    2006-01-01

    Roč. 839, 1-2 (2006), s. 80-84 ISSN 1570-0232. [International Symposium on Separations in the Biosciences /4./. Utrecht, 18.09.2005-21.09.2005] R&D Projects: GA ČR(CZ) GA203/04/0120 Institutional research plan: CEZ:AV0Z40720504 Keywords : enzyme * supercritical carbon dioxide * oil hydrolysis Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 2.647, year: 2006

  13. Reverse Algols

    Science.gov (United States)

    Leung, K. C.

    1989-01-01

    Reverse Algols, binary systems with a semidetached configuration in which the more massive component is in contact with the critical equipotential surface, are examined. Observational evidence for reverse Algols is presented and the parameters of seven reverse Algols are listed. The evolution of Algols and reverse Algols is discussed. It is suggested that, because reverse Algols represent the premass-reversal semidetached phase of close binary evolution, the evolutionary time scale between regular and reverse Algols is the ratio of the number of confirmed systems of these two Algol types.

  14. A Review of Offset Programs: Trading Systems, Funds, Protocols, Standards and Retailers

    Energy Technology Data Exchange (ETDEWEB)

    Kollmuss, Anja; Lazarus, Michael; Lee, Carrie; Polycarp, Clifford

    2008-11-15

    Carbon or greenhouse gas (GHG) offsets have long been promoted as an important element of a comprehensive climate policy approach. Offset programs can reduce the overall cost of achieving a given emission goal by enabling emission reductions to occur where costs are lower. Furthermore, offsets have the potential to deliver sustainability co-benefits, spurred through technology development and transfer, and to develop human and institutional capacity for reducing emissions in sectors and locations not included in a cap and trade or a mandatory government policy. However, offsets can pose a risk to the environmental integrity of climate actions, especially if issues surrounding additionality, permanence, leakage, quantification and verification are not adequately addressed. The challenge for policymakers is clear: to design offset programs and policies that can maximize their potential benefits while minimizing their potential risks. The goal of this review is to provide an up-to-date analysis and synthesis of the most influential offset programs and activities, to reflect on lessons learned, and thus to inform participants and designers of current and future offset programs. Our intention is to periodically update this review to stay abreast of ongoing developments, and to develop a website portal to make this information more accessible. This version targets programs that meet one or more of the following criteria: - a significant volume of credit transactions occurring or anticipated; - an established set of rules or protocols - path-breaking, novel or otherwise notable initiatives or important lessons learned

  15. Electrodeposition of mesoscopic Pt-Ru on reticulated vitreous carbon from reverse emulsions and microemulsions: Application to methanol electro-oxidation

    International Nuclear Information System (INIS)

    Cheng, Tommy T.; Gyenge, Elod L.

    2006-01-01

    High surface area Pt-Ru (between 120 and 400 cm 2 mg -1 ) meso-sized particles and mesoporous coatings were electrodeposited on reticulated vitreous carbon (RVC) three-dimensional electrodes using reverse emulsions and microemulsions. The organic phase of the colloidal media was composed of cyclohexane, Triton X-100 non-ionic surfactant and tetrabutylammonium perchlorate (for ionic conductivity) while the aqueous phase contained H 2 PtCl 6 and RuCl 3 (or (NH 4 ) 2 RuCl 6 ). For microemulsification to occur isopropanol was also added as co-surfactant. The catalytic activity for the electro-oxidation of methanol was assessed by cyclic voltammetry and chronopotentiometry in conjunction with surface area measurement by Cu underpotential deposition. The composition and morphology of the Pt-Ru deposit was analyzed by inductively coupled plasma atomic emission spectroscopy and scanning electron microscopy, respectively. The effects on the catalytic activity of the deposition current density, temperature, RVC pretreatment and plating bath composition are presented. It was found that the electrodeposition of Pt-Ru in reverse microemulsion yielded the highest specific surface area (400 cm 2 mg -1 ) and catalytic activity toward CH 3 OH electro-oxidation as shown, for example, by a 50-200 mV more negative anode potential determined by chronopotentiometry compared to a catalyst obtained by pure aqueous and emulsion electroplating

  16. Electrodeposition of mesoscopic Pt-Ru on reticulated vitreous carbon from reverse emulsions and microemulsions: Application to methanol electro-oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Tommy T. [2360 East Mall, Department of Chemical and Biological Engineering, University of British Columbia, Vancouver, BC, V6T 1Z3 (Canada); Gyenge, Elod L. [2360 East Mall, Department of Chemical and Biological Engineering, University of British Columbia, Vancouver, BC, V6T 1Z3 (Canada)]. E-mail: egyenge@chml.ubc.ca

    2006-05-20

    High surface area Pt-Ru (between 120 and 400 cm{sup 2} mg{sup -1}) meso-sized particles and mesoporous coatings were electrodeposited on reticulated vitreous carbon (RVC) three-dimensional electrodes using reverse emulsions and microemulsions. The organic phase of the colloidal media was composed of cyclohexane, Triton X-100 non-ionic surfactant and tetrabutylammonium perchlorate (for ionic conductivity) while the aqueous phase contained H{sub 2}PtCl{sub 6} and RuCl{sub 3} (or (NH{sub 4}){sub 2}RuCl{sub 6}). For microemulsification to occur isopropanol was also added as co-surfactant. The catalytic activity for the electro-oxidation of methanol was assessed by cyclic voltammetry and chronopotentiometry in conjunction with surface area measurement by Cu underpotential deposition. The composition and morphology of the Pt-Ru deposit was analyzed by inductively coupled plasma atomic emission spectroscopy and scanning electron microscopy, respectively. The effects on the catalytic activity of the deposition current density, temperature, RVC pretreatment and plating bath composition are presented. It was found that the electrodeposition of Pt-Ru in reverse microemulsion yielded the highest specific surface area (400 cm{sup 2} mg{sup -1}) and catalytic activity toward CH{sub 3}OH electro-oxidation as shown, for example, by a 50-200 mV more negative anode potential determined by chronopotentiometry compared to a catalyst obtained by pure aqueous and emulsion electroplating.

  17. Reverse Logistics

    OpenAIRE

    Kulikova, Olga

    2016-01-01

    This thesis was focused on the analysis of the concept of reverse logistics and actual reverse processes which are implemented in mining industry and finding solutions for the optimization of reverse logistics in this sphere. The objective of this paper was the assessment of the development of reverse logistics in mining industry on the example of potash production. The theoretical part was based on reverse logistics and mining waste related literature and provided foundations for further...

  18. 41 CFR 105-56.019 - Offset amount.

    Science.gov (United States)

    2010-07-01

    ... Administration 56-SALARY OFFSET FOR INDEBTEDNESS OF FEDERAL EMPLOYEES TO THE UNITED STATES Centralized Salary... referred for offset under this subpart is $100. (b) The amount offset from a salary payment under this... resolved to the satisfaction of GSA. ...

  19. Red Phosphorus-Embedded Cross-Link-Structural Carbon Films as Flexible Anodes for Highly Reversible Li-Ion Storage

    Energy Technology Data Exchange (ETDEWEB)

    Ruan, Jiafeng [School of Materials; Yuan, Tao [School of Materials; Pang, Yuepeng [School of Materials; Xu, Xinbo [School of Materials; Yang, Junhe [School of Materials; Hu, Wenbin; Zhong, Cheng; Ma, Zi-Feng [Shanghai Electrochemical Energy Devices Research Center,; Bi, Xuanxuan [Chemical; Zheng, Shiyou [School of Materials

    2017-10-06

    Red phosphorus (P) is considered to be one of the most attractive anodic materials for lithium-ion batteries (LIBs) due to its high theoretical capacity of 2596 mAh g–1. However, intrinsic characteristics such as the poor electronic conductivity and large volume expansion at lithiation impede the development of red P. Here, we design a new strategy to embed red P particles into a cross-link-structural carbon film (P–C film), in order to improve the electronic conductivity and accommodate the volume expansion. The red P/carbon film is synthesized via vapor phase polymerization (VPP) followed by the pyrolysis process, working as a flexible binder-free anode for LIBs. High cycle stability and good rate capability are achieved by the P–C film anode. With 21% P content in the film, it displays a capacity of 903 mAh g–1 after 640 cycles at a current density of 100 mA g–1 and a capacity of 460 mAh g–1 after 1000 cycles at 2.0 A g–1. Additionally, the Coulombic efficiency reaches almost 100% for each cycle. The superior properties of the P–C films together with their facile fabrication make this material attractive for further flexible and high energy density LIB applications.

  20. Great Apes and Biodiversity Offset Projects in Africa: The Case for National Offset Strategies

    Science.gov (United States)

    Kormos, Rebecca; Kormos, Cyril F.; Humle, Tatyana; Lanjouw, Annette; Rainer, Helga; Victurine, Ray; Mittermeier, Russell A.; Diallo, Mamadou S.; Rylands, Anthony B.; Williamson, Elizabeth A.

    2014-01-01

    The development and private sectors are increasingly considering “biodiversity offsets” as a strategy to compensate for their negative impacts on biodiversity, including impacts on great apes and their habitats in Africa. In the absence of national offset policies in sub-Saharan Africa, offset design and implementation are guided by company internal standards, lending bank standards or international best practice principles. We examine four projects in Africa that are seeking to compensate for their negative impacts on great ape populations. Our assessment of these projects reveals that not all apply or implement best practices, and that there is little standardization in the methods used to measure losses and gains in species numbers. Even if they were to follow currently accepted best-practice principles, we find that these actions may still fail to contribute to conservation objectives over the long term. We advocate for an alternative approach in which biodiversity offset and compensation projects are designed and implemented as part of a National Offset Strategy that (1) takes into account the cumulative impacts of development in individual countries, (2) identifies priority offset sites, (3) promotes aggregated offsets, and (4) integrates biodiversity offset and compensation projects with national biodiversity conservation objectives. We also propose supplementary principles necessary for biodiversity offsets to contribute to great ape conservation in Africa. Caution should still be exercised, however, with regard to offsets until further field-based evidence of their effectiveness is available. PMID:25372894

  1. Monodispersed Carbon-Coated Cubic NiP2 Nanoparticles Anchored on Carbon Nanotubes as Ultra-Long-Life Anodes for Reversible Lithium Storage.

    Science.gov (United States)

    Lou, Peili; Cui, Zhonghui; Jia, Zhiqing; Sun, Jiyang; Tan, Yingbin; Guo, Xiangxin

    2017-04-25

    In search of new electrode materials for lithium-ion batteries, metal phosphides that exhibit desirable properties such as high theoretical capacity, moderate discharge plateau, and relatively low polarization recently have attracted a great deal of attention as anode materials. However, the large volume changes and thus resulting collapse of electrode structure during long-term cycling are still challenges for metal-phosphide-based anodes. Here we report an electrode design strategy to solve these problems. The key to this strategy is to confine the electroactive nanoparticles into flexible conductive hosts (like carbon materials) and meanwhile maintain a monodispersed nature of the electroactive particles within the hosts. Monodispersed carbon-coated cubic NiP 2 nanoparticles anchored on carbon nanotubes (NiP 2 @C-CNTs) as a proof-of-concept were designed and synthesized. Excellent cyclability (more than 1000 cycles) and capacity retention (high capacities of 816 mAh g -1 after 1200 cycles at 1300 mA g -1 and 654.5 mAh g -1 after 1500 cycles at 5000 mA g -1 ) are characterized, which is among the best performance of the NiP 2 anodes and even most of the phosphide-based anodes reported so far. The impressive performance is attributed to the superior structure stability and the enhanced reaction kinetics incurred by our design. Furthermore, a full cell consisting of a NiP 2 @C-CNTs anode and a LiFePO 4 cathode is investigated. It delivers an average discharge capacity of 827 mAh g -1 based on the mass of the NiP 2 anode and exhibits a capacity retention of 80.7% over 200 cycles, with an average output of ∼2.32 V. As a proof-of-concept, these results demonstrate the effectiveness of our strategy on improving the electrode performance. We believe that this strategy for construction of high-performance anodes can be extended to other phase-transformation-type materials, which suffer a large volume change upon lithium insertion/extraction.

  2. Reverse Osmosis

    Indian Academy of Sciences (India)

    many applications, one of which is desalination of seawater. The inaugural Nobel Prize in Chemistry was awarded in 1901 to van 't Hoff for his seminal work in this area. The present article explains the principle of osmosis and reverse osmosis. Osmosis and Reverse Osmosis. As the name suggests, reverse osmosis is the ...

  3. Seasonal reversal of temperature-moisture response of net carbon exchange of biocrusted soils in a cool desert ecosystem.

    Science.gov (United States)

    Tucker, C.; Reed, S.; Howell, A.

    2017-12-01

    Carbon cycling associated with biological soil crusts, which occur in interspaces between vascular plants in drylands globally, may be an important part of the coupled climate-carbon cycle of the Earth system. A major challenge to understanding CO2 fluxes in these systems is that much of the biotic and biogeochemical activity occurs in the upper few mm of the soil surface layer (i.e., the `mantle of fertility'), which exhibits highly dynamic and difficult to measure temperature and moisture fluctuations. Here, we report data collected in a cool desert ecosystem over one year using a multi-sensor approach to simultaneously measuring temperature and moisture of the biocrust surface layer (0-2 mm), and the deeper soil profile (5-20 cm), concurrent with automated measurement of surface soil CO2 effluxes. Our results illuminate robust relationships between microclimate and field CO2 pulses that have previously been difficult to detect and explain. The temperature of the biocrust surface layer was highly variable, ranging from minimum of -9 °C in winter to maximum of 77 °C in summer with a maximum diurnal range of 61 °C. Temperature cycles were muted deeper in the soil profile. During summer, biocrust and soils were usually hot and dry and CO2 fluxes were tightly coupled to pulse wetting events experienced at the biocrust surface, which consistently resulted in net CO2 efflux (i.e., respiration). In contrast, during the winter, biocrust and soils were usually cold and moist, and there was sustained net CO2 uptake via photosynthesis by biocrust organisms, although during cold dry periods CO2 fluxes were minimal. During the milder spring and fall seasons, short wetting events drove CO2 loss, while sustained wetting events resulted in net CO2 uptake. Thus, the upper and lower bounds of net CO2 exchange at a point in time were functions of the seasonal temperature regime, while the actual flux within those bounds was determined by the magnitude and duration of biocrust

  4. Carbon Dioxide Nucleation as a Novel Cleaning Method for Sodium Alginate Fouling Removal from Reverse Osmosis Membranes desalination

    KAUST Repository

    Alnajjar, Heba

    2017-05-01

    The use of Reverse osmosis (RO) membranes have been significantly increasing in water desalination, and the main operational obstacle in RO desalination plants is membrane fouling. Among other solutes, dissolved biopolymers, such as polysaccharides can lead to severe membrane fouling especially with the addition of calcium ions because of the complexation formation between the surface of membrane and foulants materials. However, this complexation can also take place in the feed bulk, resulting in foulants aggregates formation. Although there are some physical techniques that can maintain the membrane performance without reducing its lifetime, only chemical cleanings are still commonly used in RO plants. In this study, a novel cleaning method is proposed to restore the membrane performance by removing the deposited foulants without reducing the membrane lifetime. The cleaning method is based on using water saturated with dissolved CO2 gas, and its principle is based on producing spontaneous CO2 bubbles due to local pressure difference leading to nucleation of bubbles throughout the membrane surface, especially at nucleation sites, which improve the cleaning efficiency. Alginic acid sodium salt was used as a model of polysaccharides foulants in presence of different concentrations of NaCl and calcium ions aiming to enhance membrane fouling, and then CO2 cleaning solution efficiency, in terms flux recovery (FR), was tested under different operating conditions and compared to other cleaning methods. Average FR of 20%±3, 25%±3 and 80%±3 for MilliQ water, a cleaning solution at pH4, and CO2 solution at 6 bar, 0.17 m/s, and 23 ̊C ±0.2 for 6 minutes were obtained, respectively. The efficiency of this novel cleaning method was also compared to direct osmosis overnight, and the average flux was comparable (about 60%±3), though that the cleaning time was significantly different. Various calcium concentrations (0-10 mM) were added in the alginate solution to study the

  5. 12 CFR 1408.39 - Procedures for salary offset.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 7 2010-01-01 2010-01-01 false Procedures for salary offset. 1408.39 Section... STATES Offset Against Salary § 1408.39 Procedures for salary offset. (a) The Chairman, or designee of the... periods following the date of mailing or delivery of the Notice of Intent to Collect by Salary Offset. (c...

  6. 22 CFR 309.17 - Procedures for salary offset.

    Science.gov (United States)

    2010-04-01

    ... 22 Foreign Relations 2 2010-04-01 2010-04-01 true Procedures for salary offset. 309.17 Section 309.17 Foreign Relations PEACE CORPS DEBT COLLECTION Salary Offset § 309.17 Procedures for salary offset. Unless otherwise provided by statute or contract, the following procedures apply to salary offset: (a...

  7. 41 CFR 105-56.018 - Salary offset.

    Science.gov (United States)

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Salary offset. 105-56... Administration 56-SALARY OFFSET FOR INDEBTEDNESS OF FEDERAL EMPLOYEES TO THE UNITED STATES Centralized Salary Offset (CSO) Procedures-GSA as Creditor Agency § 105-56.018 Salary offset. When a match occurs and all...

  8. 5 CFR 1639.27 - Procedures for salary offset.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Procedures for salary offset. 1639.27... Salary Offset § 1639.27 Procedures for salary offset. (a) The Board will coordinate salary deductions... pay and will implement the salary offset. (c) Deductions will begin within three official pay periods...

  9. 41 CFR 105-56.028 - Salary offset.

    Science.gov (United States)

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Salary offset. 105-56... Administration 56-SALARY OFFSET FOR INDEBTEDNESS OF FEDERAL EMPLOYEES TO THE UNITED STATES Centralized Salary Offset (CSO) Procedures-GSA as Paying Agency § 105-56.028 Salary offset. When a match occurs and all...

  10. 12 CFR 608.839 - Procedures for salary offset.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 6 2010-01-01 2010-01-01 false Procedures for salary offset. 608.839 Section... OWED THE UNITED STATES Offset Against Salary § 608.839 Procedures for salary offset. (a) The Chairman... Intent to Collect by Salary Offset. (c)(1) If the amount of the debt is equal to or is less than 15...

  11. 5 CFR 179.211 - Notice of salary offset.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Notice of salary offset. 179.211 Section... COLLECTION STANDARDS Salary Offset § 179.211 Notice of salary offset. (a) Upon receipt of proper... certification as the debtor, a written notice of salary offset. Such notice shall, at a minimum: (1) State that...

  12. 7 CFR 3.46 - Offset against tax refunds.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 1 2010-01-01 2010-01-01 false Offset against tax refunds. 3.46 Section 3.46 Agriculture Office of the Secretary of Agriculture DEBT MANAGEMENT Administrative Offset § 3.46 Offset against tax refunds. USDA will take action to effect administrative offset against tax refunds due to debtors...

  13. Phase ambiguity resolution for offset QPSK modulation systems

    Science.gov (United States)

    Nguyen, Tien M. (Inventor)

    1991-01-01

    A demodulator for Offset Quaternary Phase Shift Keyed (OQPSK) signals modulated with two words resolves eight possible combinations of phase ambiguity which may produce data error by first processing received I(sub R) and Q(sub R) data in an integrated carrier loop/symbol synchronizer using a digital Costas loop with matched filters for correcting four of eight possible phase lock errors, and then the remaining four using a phase ambiguity resolver which detects the words to not only reverse the received I(sub R) and Q(sub R) data channels, but to also invert (complement) the I(sub R) and/or Q(sub R) data, or to at least complement the I(sub R) and Q(sub R) data for systems using nontransparent codes that do not have rotation direction ambiguity.

  14. Vegetation shift from deciduous to evergreen dwarf shrubs in response to selective herbivory offsets carbon losses: evidence from 19 years of warming and simulated herbivory in the subarctic tundra.

    Science.gov (United States)

    Ylänne, Henni; Stark, Sari; Tolvanen, Anne

    2015-10-01

    Selective herbivory of palatable plant species provides a competitive advantage for unpalatable plant species, which often have slow growth rates and produce slowly decomposable litter. We hypothesized that through a shift in the vegetation community from palatable, deciduous dwarf shrubs to unpalatable, evergreen dwarf shrubs, selective herbivory may counteract the increased shrub abundance that is otherwise found in tundra ecosystems, in turn interacting with the responses of ecosystem carbon (C) stocks and CO2 balance to climatic warming. We tested this hypothesis in a 19-year field experiment with factorial treatments of warming and simulated herbivory on the dominant deciduous dwarf shrub Vaccinium myrtillus. Warming was associated with a significantly increased vegetation abundance, with the strongest effect on deciduous dwarf shrubs, resulting in greater rates of both gross ecosystem production (GEP) and ecosystem respiration (ER) as well as increased C stocks. Simulated herbivory increased the abundance of evergreen dwarf shrubs, most importantly Empetrum nigrum ssp. hermaphroditum, which led to a recent shift in the dominant vegetation from deciduous to evergreen dwarf shrubs. Simulated herbivory caused no effect on GEP and ER or the total ecosystem C stocks, indicating that the vegetation shift counteracted the herbivore-induced C loss from the system. A larger proportion of the total ecosystem C stock was found aboveground, rather than belowground, in plots treated with simulated herbivory. We conclude that by providing a competitive advantage to unpalatable plant species with slow growth rates and long life spans, selective herbivory may promote aboveground C stocks in a warming tundra ecosystem and, through this mechanism, counteract C losses that result from plant biomass consumption. © 2015 John Wiley & Sons Ltd.

  15. The Climate-Energy package: Usage and impact of offsets in the European Union

    International Nuclear Information System (INIS)

    Galharret, S.

    2009-09-01

    This paper aims at clarifying the current European dispositions on the quantity of allowable carbon emission 'offsets' over the 2008-2012 and 2012-2020 periods, as well as the implications on the level of the European reduction effort with respect to a unilateral path of de-carbonation of economy by 2020. The author makes a distinction between sectors submitted or not to the Emission Trading Scheme (ETS)

  16. 20 CFR 627.708 - Offset process.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 3 2010-04-01 2010-04-01 false Offset process. 627.708 Section 627.708 Employees' Benefits EMPLOYMENT AND TRAINING ADMINISTRATION, DEPARTMENT OF LABOR GENERAL PROVISIONS GOVERNING... process. (a) In accordance with section 164(d) of the Act, the primary sanction for misexpenditure of JTPA...

  17. Sample Adaptive Offset Optimization in HEVC

    Directory of Open Access Journals (Sweden)

    Yang Zhang

    2014-11-01

    Full Text Available As the next generation of video coding standard, High Efficiency Video Coding (HEVC adopted many useful tools to improve coding efficiency. Sample Adaptive Offset (SAO, is a technique to reduce sample distortion by providing offsets to pixels in in-loop filter. In SAO, pixels in LCU are classified into several categories, then categories and offsets are given based on Rate-Distortion Optimization (RDO of reconstructed pixels in a Largest Coding Unit (LCU. Pixels in a LCU are operated by the same SAO process, however, transform and inverse transform makes the distortion of pixels in Transform Unit (TU edge larger than the distortion inside TU even after deblocking filtering (DF and SAO. And the categories of SAO can also be refined, since it is not proper for many cases. This paper proposed a TU edge offset mode and a category refinement for SAO in HEVC. Experimental results shows that those two kinds of optimization gets -0.13 and -0.2 gain respectively compared with the SAO in HEVC. The proposed algorithm which using the two kinds of optimization gets -0.23 gain on BD-rate compared with the SAO in HEVC which is a 47 % increase with nearly no increase on coding time.

  18. Reversible Second Order Kinetics of Sorption-Desorption of Cr(VI Ion on Activated Carbon from Palm Empty Fruit Bunches

    Directory of Open Access Journals (Sweden)

    Iip Izul Falah

    2015-11-01

    Full Text Available Activated carbon (AC from palm empty fruit bunches has been prepared, and this material was then used to adsorb Cr(VI from a solution. Characterization of the AC was conducted by detection of its functional groups, determination of total volatile compounds (VC content and its iodine number. Study on sorption-desorption kinetics was conducted by comparing results of evaluations of several models with proposed reversible second order model using the data produced in this work. Results of the works showed that the AC had similar characters compared with the AC produced by previous researchers. Application of the kinetics models on sorption Cr(VI onto the AC showed that nearly all of the models gave a good linearity. However, only the proposed model had a good relation with Langmuir isotherm, with respectively sorption (ks and desorption (kd constants were 5.75 x 10-4 L.mg‑1.min-1 and 2.20 x 10-3 min-1; maximum sorption capacity, qm = 20.00 mg.g-1; and equilibrium constant, K from kinetics experiment (0.261 L.mg-1 was comparable with the result from the isotherm experiment (0.269 L.mg-1. Hence, using this model, kinetics and Langmuir parameters can probably be determined from a single kinetics data experiment.

  19. Point Climat no. 11 'Japan's Bilateral Offset Crediting Mechanism: A Bilateral Solution to a Global Issue?'

    International Nuclear Information System (INIS)

    Le, Hanh; Delbosc, Anais

    2012-01-01

    Among the publications of CDC Climat Research, 'Climate Briefs' presents, in a few pages, hot topics in climate change policy. This issue addresses the following points: In order to achieve its long-term emission reduction target following the Fukushima incident, Japan would rely more heavily on international offsetting activities. Concurrent to vigorous proposals to reform the CDM, Japan is also promoting an offset crediting scheme through bilateral agreements with developing countries as a post-2012 market mechanism. Despite potential benefits, issues relating to the accounting rules, environmental integrity and implications to carbon markets warrant further consideration prior to international recognition

  20. A GPS Satellite Clock Offset Prediction Method Based on Fitting Clock Offset Rates Data

    Directory of Open Access Journals (Sweden)

    WANG Fuhong

    2016-12-01

    Full Text Available It is proposed that a satellite atomic clock offset prediction method based on fitting and modeling clock offset rates data. This method builds quadratic model or linear model combined with periodic terms to fit the time series of clock offset rates, and computes the model coefficients of trend with the best estimation. The clock offset precisely estimated at the initial prediction epoch is directly adopted to calculate the model coefficient of constant. The clock offsets in the rapid ephemeris (IGR provided by IGS are used as modeling data sets to perform certain experiments for different types of GPS satellite clocks. The results show that the clock prediction accuracies of the proposed method for 3, 6, 12 and 24 h achieve 0.43, 0.58, 0.90 and 1.47 ns respectively, which outperform the traditional prediction method based on fitting original clock offsets by 69.3%, 61.8%, 50.5% and 37.2%. Compared with the IGU real-time clock products provided by IGS, the prediction accuracies of the new method have improved about 15.7%, 23.7%, 27.4% and 34.4% respectively.

  1. An improved in situ measurement of offset phase shift towards quantitative damping-measurement with AFM

    International Nuclear Information System (INIS)

    Minary-Jolandan, Majid; Yu Minfeng

    2008-01-01

    An improved approach is introduced in damping measurement with atomic force microscope (AFM) for the in situ measurement of the offset phase shift needed for determining the intrinsic mechanical damping in nanoscale materials. The offset phase shift is defined and measured at a point of zero contact force according to the deflection part of the AFM force plot. It is shown that such defined offset phase shift is independent of the type of sample material, varied from hard to relatively soft materials in this study. This improved approach allows the self-calibrated and quantitative damping measurement with AFM. The ability of dynamic mechanical analysis for the measurement of damping in isolated one-dimensional nanostructures, e.g. individual multiwalled carbon nanotubes, was demonstrated

  2. Cap and trade offsets regulation - consultation paper

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-07-01

    Due to increasing concerns about the environment, British Columbia has committed to reducing its 2007 greenhouse gas emissions levels by 33% in 2020 and 80% in 2050. To reach those objectives, emissions trading and offset regulations are being developed by the Climate Action Secretariat. The aim of this document is to present a first draft of the regulations to the various stakeholders, including First Nations and the general public, together with the proposed offset eligibility criteria and related process, and to get their feedback. This document is itself part of the 5-phase process of developing the regulations. Following the 45 days during which comments on the proposed regulation were sought, the climate action secretariat will complete legal drafting of the regulations, drawing on help from this stakeholder input, and the regulation will subsequently be implemented. An accompanying response form was attached to this consultation paper.

  3. Forest carbon calculators: a review for managers, policymakers, and educators

    Science.gov (United States)

    Harold S.J. Zald; Thomas A. Spies; Mark E. Harmon; Mark J. Twery

    2016-01-01

    Forests play a critical role sequestering atmospheric carbon dioxide, partially offsetting greenhouse gas emissions, and thereby mitigating climate change. Forest management, natural disturbances, and the fate of carbon in wood products strongly influence carbon sequestration and emissions in the forest sector. Government policies, carbon offset and trading programs,...

  4. Rapid determination of hydrophilic phenols in olive oil by vortex-assisted reversed-phase dispersive liquid-liquid microextraction and screen-printed carbon electrodes.

    Science.gov (United States)

    Fernández, Elena; Vidal, Lorena; Canals, Antonio

    2018-05-01

    A novel approach is presented to determine hydrophilic phenols in olive oil samples, employing vortex-assisted reversed-phase dispersive liquid-liquid microextraction (RP-DLLME) for sample preparation and screen-printed carbon electrodes for voltammetric analysis. The oxidation of oleuropein, hydroxytyrosol, caffeic acid, ferulic acid and tyrosol was investigated, being caffeic acid and tyrosol selected for quantification. A matrix-matching calibration using sunflower oil as analyte-free sample diluted with hexane was employed to compensate matrix effects. Samples were analyzed under optimized RP-DLLME conditions, i.e., extractant phase, 1M HCl; extractant volume, 100µL; extraction time, 2min; centrifugation time, 10min; centrifugation speed, 4000rpm. The working range showed a good linearity between 0.075 and 2.5mgL -1 (r = 0.998, N = 7) for caffeic acid, and between 0.075 and 3mgL -1 (r = 0.999, N = 8) for tyrosol. The methodological limit of detection was empirically established at 0.022mgL -1 for both analytes, which is significantly lower than average contents found in olive oil samples. The repeatability was evaluated at two different spiking levels (i.e., 0.5mgL -1 and 2mgL -1 ) and coefficients of variation ranged from 8% to 11% (n = 5). The applicability of the proposed method was tested in olive oil samples of different quality (i.e., refined olive oil, virgin olive oil and extra virgin olive oil). Relative recoveries varied between 83% and 108% showing negligible matrix effects. Finally, fifteen samples were analyzed by the proposed method and a high correlation with the traditional Folin-Ciocalteu spectrophotometric method was obtained. Thereafter, the concentrations of the fifteen oil samples were employed as input variables in linear discriminant analysis in order to distinguish between olive oils of different quality. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. Novel climates reverse carbon uptake of atmospherically dependent epiphytes: Climatic constraints on the iconic boreal forest lichen Evernia mesomorpha

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Robert J. [Oregon State Univ., Corvallis, OR (United States); Nelson, Peter R. [Univ. of Maine, Fort Kent, ME (United States); Jovan, Sarah [USDA Forest Service, Portland, OR (United States). Pacific Northwest Research Station; Hanson, Paul J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); McCune, Bruce [Oregon State Univ., Corvallis, OR (United States)

    2018-02-26

    Premise of the Study: Changing climates are expected to affect the abundance and distribution of global vegetation, especially plants and lichens with an epiphytic lifestyle and direct exposure to atmospheric variation. The study of epiphytes could improve understanding of biological responses to climatic changes, but only if the conditions that elicit physiological performance changes are clearly defined.Methods: We evaluated individual growth performance of the epiphytic lichen Evernia mesomorpha, an iconic boreal forest indicator species, in the first year of a decade-long experiment featuring whole-ecosystem warming and drying. Field experimental enclosures were located near the southern edge of the species’ range.Key Results: Mean annual biomass growth of Evernia significantly declined 6 percentage points for every +1°C of experimental warming after accounting for interactions with atmospheric drying. Mean annual biomass growth was 14% in ambient treatments, 2% in unheated control treatments, and -9% to -19% (decreases) in energy-added treatments ranging from +2.25 to +9.00°C above ambient temperatures. Warming-induced biomass losses among persistent individuals were suggestive evidence of an extinction debt that could precede further local mortality events.Conclusions: Changing patterns of warming and drying would decrease or reverse Evernia growth at its southern range margins, with potential consequences for the maintenance of local and regional populations. Negative carbon balances among persisting individuals could physiologically commit these epiphytes to local extinction. Our findings illuminate the processes underlying local extinctions of epiphytes and suggest broader consequences for range shrinkage if dispersal and recruitment rates cannot keep pace.

  6. Constructing carbon offsets: The obstacles to quantifying emission reductions

    International Nuclear Information System (INIS)

    Millard-Ball, Adam; Ortolano, Leonard

    2010-01-01

    The existing literature generally ascribes the virtual absence of the transport sector from the Clean Development Mechanism (CDM) to the inherent complexity of quantifying emission reductions from mobile sources. We use archival analysis and interviews with CDM decision-makers and experts to identify two additional groups of explanations. First, we show the significance of aspects of the CDM's historical evolution, such as the order in which methodologies were considered and the assignment of expert desk reviewers. Second, we highlight inconsistencies in the treatment of uncertainty across sectors. In contrast to transport methodologies, other sectors are characterized by a narrow focus on sources of measurement uncertainty and a neglect of economic effects ('market leakages'). We do not argue that the rejection of transport methodologies was unjustified, but rather than many of the same problems are inherent in other sectors. Thus, the case of transport sheds light on fundamental problems in quantifying emission reductions under the CDM. We argue that a key theoretical attraction of the CDM-equalization of marginal abatement costs across all sectors-has been difficult to achieve in practice.

  7. The Effect of Allowing Pollution Offsets with Imperfect Enforcement

    OpenAIRE

    Hilary Sigman; Howard F. Chang

    2011-01-01

    Public policies for pollution control, including climate change policies, sometimes allow polluters in one sector subject to an emissions cap to offset excessive emissions in that sector with pollution abatement in another sector. The government may often find it more costly to verify offset claims than to verify compliance with emissions caps. Concerns about such difficulties in enforcement may lead regulators to restrict the use of offsets. In this paper, we demonstrate that allowing offset...

  8. 22 CFR 1007.8 - Procedures for salary offset.

    Science.gov (United States)

    2010-04-01

    ... 22 Foreign Relations 2 2010-04-01 2010-04-01 true Procedures for salary offset. 1007.8 Section 1007.8 Foreign Relations INTER-AMERICAN FOUNDATION SALARY OFFSET § 1007.8 Procedures for salary offset... final salary or leave payments in accordance with 31 U.S.C. 3716. ...

  9. 29 CFR 1650.110 - Implementation of salary offset.

    Science.gov (United States)

    2010-07-01

    ... 29 Labor 4 2010-07-01 2010-07-01 false Implementation of salary offset. 1650.110 Section 1650.110... Procedures for the Collection of Debts by Salary Offset § 1650.110 Implementation of salary offset. (a... proposed voluntary repayment agreement, deductions will begin in the next bi-weekly salary payment after a...

  10. 16 CFR 1027.8 - Procedures for salary offset.

    Science.gov (United States)

    2010-01-01

    ... 16 Commercial Practices 2 2010-01-01 2010-01-01 false Procedures for salary offset. 1027.8 Section 1027.8 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION GENERAL SALARY OFFSET § 1027.8 Procedures for salary offset. (a) Deductions to liquidate an employee's debt will be by the method and in the...

  11. 10 CFR 16.15 - Procedures for internal salary offset.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 1 2010-01-01 2010-01-01 false Procedures for internal salary offset. 16.15 Section 16.15 Energy NUCLEAR REGULATORY COMMISSION SALARY OFFSET PROCEDURES FOR COLLECTING DEBTS OWED BY FEDERAL EMPLOYEES TO THE FEDERAL GOVERNMENT § 16.15 Procedures for internal salary offset. (a) Deductions to...

  12. 17 CFR 141.8 - Procedures for salary offset.

    Science.gov (United States)

    2010-04-01

    ... 17 Commodity and Securities Exchanges 1 2010-04-01 2010-04-01 false Procedures for salary offset. 141.8 Section 141.8 Commodity and Securities Exchanges COMMODITY FUTURES TRADING COMMISSION SALARY OFFSET § 141.8 Procedures for salary offset. (a) Deductions to liquidate an employee's debt will be by...

  13. 10 CFR 1015.215 - Federal salary offset.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 4 2010-01-01 2010-01-01 false Federal salary offset. 1015.215 Section 1015.215 Energy... Administrative Collection of Claims § 1015.215 Federal salary offset. (a) DOE may authorize Treasury to offset a Federal salary to satisfy delinquent debt in accordance with 5 U.S.C. 5514, Installment Deduction for...

  14. 40 CFR 13.21 - Employee salary offset-general.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 1 2010-07-01 2010-07-01 false Employee salary offset-general. 13.21... STANDARDS Administrative Offset § 13.21 Employee salary offset—general. (a) Purpose. This section... collection by salary offset under 5 U.S.C. 5514 of debts owed EPA and debts owed to other Federal agencies by...

  15. 45 CFR 33.10 - Procedures for salary offset.

    Science.gov (United States)

    2010-10-01

    ... 45 Public Welfare 1 2010-10-01 2010-10-01 false Procedures for salary offset. 33.10 Section 33.10 Public Welfare DEPARTMENT OF HEALTH AND HUMAN SERVICES GENERAL ADMINISTRATION SALARY OFFSET § 33.10 Procedures for salary offset. (a) Method and source of deductions. Unless the employee and the Secretary have...

  16. 38 CFR 1.992 - Procedures for salary offset.

    Science.gov (United States)

    2010-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 1 2010-07-01 2010-07-01 false Procedures for salary offset. 1.992 Section 1.992 Pensions, Bonuses, and Veterans' Relief DEPARTMENT OF VETERANS AFFAIRS GENERAL PROVISIONS Salary Offset Provisions § 1.992 Procedures for salary offset. (a) Types of collection...

  17. 5 CFR 1215.8 - Procedures for salary offset.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Procedures for salary offset. 1215.8... MANAGEMENT Salary Offset § 1215.8 Procedures for salary offset. (a) Deductions to liquidate an employee's... payment due to a separated employee including but not limited to final salary payment or leave in...

  18. 45 CFR 607.8 - Procedures for salary offset.

    Science.gov (United States)

    2010-10-01

    ... 45 Public Welfare 3 2010-10-01 2010-10-01 false Procedures for salary offset. 607.8 Section 607.8 Public Welfare Regulations Relating to Public Welfare (Continued) NATIONAL SCIENCE FOUNDATION SALARY OFFSET § 607.8 Procedures for salary offset. (a) Deductions to liquidate an employee's debt will be by...

  19. 32 CFR 1697.8 - Procedures for salary offset.

    Science.gov (United States)

    2010-07-01

    ... 32 National Defense 6 2010-07-01 2010-07-01 false Procedures for salary offset. 1697.8 Section 1697.8 National Defense Other Regulations Relating to National Defense SELECTIVE SERVICE SYSTEM SALARY OFFSET § 1697.8 Procedures for salary offset. (a) Deductions to liquidate an employee's debt will be by...

  20. 14 CFR 1261.603 - Procedures for salary offset.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 5 2010-01-01 2010-01-01 false Procedures for salary offset. 1261.603... salary offset. If NASA is both the paying and creditor agency, the following requirements must be met... of the debt through salary offset by deductions from the employee's current disposable pay, stating...

  1. 22 CFR 34.16 - Procedures for salary offset.

    Science.gov (United States)

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Procedures for salary offset. 34.16 Section 34.16 Foreign Relations DEPARTMENT OF STATE CLAIMS AND STOLEN PROPERTY DEBT COLLECTION Salary Offset § 34.16 Procedures for salary offset. Unless otherwise provided by statute or contract, the following...

  2. 5 CFR 179.212 - Procedures for salary offset.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Procedures for salary offset. 179.212... COLLECTION STANDARDS Salary Offset § 179.212 Procedures for salary offset. (a) The Director or his or her designee shall coordinate salary deductions under this subpart. (b) OPM payroll office shall determine the...

  3. 45 CFR 708.10 - Procedures for salary offset.

    Science.gov (United States)

    2010-10-01

    ... 45 Public Welfare 3 2010-10-01 2010-10-01 false Procedures for salary offset. 708.10 Section 708... COLLECTION BY SALARY OFFSET FROM INDEBTED CURRENT AND FORMER EMPLOYEES § 708.10 Procedures for salary offset... to final salary payment, retired pay, or lump sum leave, etc. as of the date of separation to the...

  4. 47 CFR 1.1951 - Offset against tax refunds.

    Science.gov (United States)

    2010-10-01

    ... 47 Telecommunication 1 2010-10-01 2010-10-01 false Offset against tax refunds. 1.1951 Section 1... Claims Owed the United States Cooperation with the Internal Revenue Service § 1.1951 Offset against tax refunds. The Commission will take action to effect administrative offset against tax refunds due to...

  5. 13 CFR 120.1722 - SBA's offset rights.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false SBA's offset rights. 120.1722... of SBA Secondary Market Guarantee Program for First Lien Position 504 Loan Pools § 120.1722 SBA's offset rights. SBA shall have the right to offset any amount owed by Lender to SBA, including, without...

  6. 41 CFR 105-56.029 - Offset amount.

    Science.gov (United States)

    2010-07-01

    ... Administration 56-SALARY OFFSET FOR INDEBTEDNESS OF FEDERAL EMPLOYEES TO THE UNITED STATES Centralized Salary... salary offset under this subpart is $100. (b) The amount offset from a salary payment under this subpart... otherwise resolved to the satisfaction of the creditor agency. ...

  7. Alternative method for determining the constant offset in lidar signal

    Science.gov (United States)

    Vladimir A. Kovalev; Cyle Wold; Alexander Petkov; Wei Min Hao

    2009-01-01

    We present an alternative method for determining the total offset in lidar signal created by a daytime background-illumination component and electrical or digital offset. Unlike existing techniques, here the signal square-range-correction procedure is initially performed using the total signal recorded by lidar, without subtraction of the offset component. While...

  8. Research on Stress Neutral Layer Offset in the Straightening Process

    Directory of Open Access Journals (Sweden)

    Hailian Gui

    2015-01-01

    Full Text Available The stress neutral layer offset is analyzed by theoretical and numerical calculation methods. In traditional straightening theory, the stress neutral layer was consistent with the geometric central layer. However, there is a phenomenon that the stress neutral layer has some offset with the geometric neutral layer. This offset is a very important factor for improving the precision of the straightening force. The formula of the stress neutral layer offset is obtained by a theoretical method and the change law is given by numerical calculation method. The neutral layer offset theory provides the theoretical basis for establishing the model of straightening force precisely.

  9. Reagan Defense Forum: The Third Offset Strategy

    Science.gov (United States)

    2015-11-07

    guided weapons as you do, and have a homefield advantage. How would you do that? And the LRRDPP really, really did a great job in looking at that...The second thing was the Defense Science Board summer study on autonomy . To a person, every single person on the summer study said, we can’t prove...it, but we believe we are at an inflection point at an artificial intelligence and autonomy . How might we use that as an advantage in an offset

  10. Efficient Fixed-Offset GPR Scattering Analysis

    DEFF Research Database (Denmark)

    Meincke, Peter; Chen, Xianyao

    2004-01-01

    The electromagnetic scattering by buried three-dimensional penetrable objects, as involved in the analysis of ground penetrating radar systems, is calculated using the extended Born approximation. The involved scattering tensor is calculated using fast Fourier transforms (FFT's). We incorporate...... in the scattering calculation the correct radiation patterns of the ground penetrating radar antennas by using their plane-wave transmitting and receiving spectra. Finally, we derive an efficient FFT-based method to analyze a fixed-offset configuration in which the location of the transmitting antenna is different...

  11. Emissions trading with offset markets and free quota allocations

    Energy Technology Data Exchange (ETDEWEB)

    Rosendahl, Knut Einar; Strand, Jon

    2012-07-01

    We study interactions between a 'policy bloc's' emissions quota market and an offset market where emissions offsets can be purchased from a non-policy 'fringe' of countries (such as for the CDM under the Kyoto Protocol). Policy-bloc firms are assumed to benefit from free quota allocations that are updated according to either past emissions or past outputs. We show that both overall abatement, and the allocation of given abatement between the policy bloc and the fringe, tend to be inefficient. When the policy-bloc quota market and offset markets are fully integrated (and firms buy offsets directly from the fringe), and all quotas and offsets must be traded at a single price, it is optimal for the policy bloc to either not constrain the offset market whatsoever, or to ban offsets completely. The former (latter) case occurs when free allocation of quotas is not too generous (very generous), and the offset market can profitably deliver large (only a small) quota amounts. Governments of policy countries would however instead prefer to buy offsets directly from the fringe at a price below the policy-bloc quota price. The offset price will then be below the marginal damage cost of emissions, and the quota price in the policy bloc above marginal damage cost. This solution is also inefficient as the policy bloc (acting as a monopsonist) purchases too few offsets from the fringe.(Author)

  12. Biodiversity offsets and the challenge of achieving no net loss.

    Science.gov (United States)

    Gardner, Toby A; VON Hase, Amrei; Brownlie, Susie; Ekstrom, Jonathan M M; Pilgrim, John D; Savy, Conrad E; Stephens, R T Theo; Treweek, Jo; Ussher, Graham T; Ward, Gerri; Ten Kate, Kerry

    2013-12-01

    Businesses, governments, and financial institutions are increasingly adopting a policy of no net loss of biodiversity for development activities. The goal of no net loss is intended to help relieve tension between conservation and development by enabling economic gains to be achieved without concomitant biodiversity losses. biodiversity offsets represent a necessary component of a much broader mitigation strategy for achieving no net loss following prior application of avoidance, minimization, and remediation measures. However, doubts have been raised about the appropriate use of biodiversity offsets. We examined what no net loss means as a desirable conservation outcome and reviewed the conditions that determine whether, and under what circumstances, biodiversity offsets can help achieve such a goal. We propose a conceptual framework to substitute the often ad hoc approaches evident in many biodiversity offset initiatives. The relevance of biodiversity offsets to no net loss rests on 2 fundamental premises. First, offsets are rarely adequate for achieving no net loss of biodiversity alone. Second, some development effects may be too difficult or risky, or even impossible, to offset. To help to deliver no net loss through biodiversity offsets, biodiversity gains must be comparable to losses, be in addition to conservation gains that may have occurred in absence of the offset, and be lasting and protected from risk of failure. Adherence to these conditions requires consideration of the wider landscape context of development and offset activities, timing of offset delivery, measurement of biodiversity, accounting procedures and rule sets used to calculate biodiversity losses and gains and guide offset design, and approaches to managing risk. Adoption of this framework will strengthen the potential for offsets to provide an ecologically defensible mechanism that can help reconcile conservation and development. Balances de Biodiversidad y el Reto de No Obtener P

  13. How economic contexts shape calculations of yield in biodiversity offsetting.

    Science.gov (United States)

    Carver, L; Sullivan, S

    2017-10-01

    We examined and analyzed methods used to create numerical equivalence between sites affected by development and proposed conservation offset sites. Application of biodiversity offsetting metrics in development impact and mitigation assessments is thought to standardize biodiversity conservation outcomes, sometimes termed yield by those conducting these calculations. The youth of biodiversity offsetting in application, however, means little is known about how biodiversity valuations and offset contracts between development and offset sites are agreed on in practice or about long-term conservation outcomes. We examined how sites were made commensurable and how biodiversity gains or yields were calculated and negotiated for a specific offset contract in a government-led pilot study of biodiversity offsets in England. Over 24 months, we conducted participant observations of various stages in the negotiation of offset contracts through repeated visits to 3 (anonymized) biodiversity offset contract sites. We conducted 50 semistructured interviews of stakeholders in regional and local government, the private sector, and civil society. We used a qualitative data analysis software program (DEDOOSE) to textually analyze interview transcriptions. We also compared successive iterations of biodiversity-offsetting calculation spreadsheets and planning documents. A particular focus was the different iterations of a specific biodiversity impact assessment in which the biodiversity offsetting metric developed by the U.K.'s Department for Environment, Food and Rural Affairs was used. We highlight 3 main findings. First, biodiversity offsetting metrics were amended in creative ways as users adapted inputs to metric calculations to balance and negotiate conflicting requirements. Second, the practice of making different habitats equivalent to each other through the application of biodiversity offsetting metrics resulted in commensuration outcomes that may not provide projected

  14. Domestic offset projects in the built environment

    Energy Technology Data Exchange (ETDEWEB)

    Oikonomou, V.; Spijker, E.; Van der Gaast, W. [Joint Implementation Network, Laan Corpus den Hoorn 300, 9728JT Groningen (Netherlands); Flamos, A.; Spyridaki, N.A. [Department of Industrial Management, University of Piraeus, Karaoli and Dimitriou 80 Str, 185 34 Piraeus (Greece)

    2012-08-15

    Emission reduction activities in the European Union (EU) in- and outside the European Trading System (ETS) thus far have largely taken place separately. One possibility to combine the two is through linking Non-ETS offset project-based crediting schemes in the form of Joint Implementation or domestic offset (DO) projects with the EU ETS. Linking would allow non-ETS offset project-based CO2 credits to be traded within the ETS market. This paper discusses the merits and drawbacks of the implementation of a DO scheme in the built environment in the Netherlands. The built environment can be characterised as a sector with a great diversity and significant energy savings potential. Emphasis is paid on the modalities for estimating energy savings under DO projects. The authors discuss if next to existing EU, national or regional policies in the Netherlands, DO could spur initiatives in sub-sectors or market areas that are difficult to reach with conventional policy instruments. Thus, despite the existing policy framework in this sector, there could be still space for DO to reach the untapped energy savings potential. DO can support activities and technologies that are not covered by other policy instruments, either because they are not part of the instruments focus or are above the minimum requirements of the incumbent policy targets. It is expected that some lessons from this study in the Netherlands can be taken into account also by other countries facing similar market circumstances, which have implemented several policy instruments and are considering DO schemes as an alternative for capturing part of the untapped energy saving potential in their end use sectors. Another possible advantage of DO is that it has the potential to reduce public spending on existing policy goals, when it is considered in conjunction with existing public financing instruments. In order to tap into this potential, there are a series of hurdles in place, like additionality and the current CO2

  15. Enabling food security by verifying agricultural carbon

    DEFF Research Database (Denmark)

    Kahiluoto, H; Smith, P; Moran, D

    2014-01-01

    Rewarding smallholders for sequestering carbon in agricultural land can improve food security while mitigating climate change. Verification of carbon offsets in food-insecure regions is possible and achievable through rigorously controlled monitoring......Rewarding smallholders for sequestering carbon in agricultural land can improve food security while mitigating climate change. Verification of carbon offsets in food-insecure regions is possible and achievable through rigorously controlled monitoring...

  16. Noise Prediction Module for Offset Stream Nozzles

    Science.gov (United States)

    Henderson, Brenda S.

    2011-01-01

    A Modern Design of Experiments (MDOE) analysis of data acquired for an offset stream technology was presented. The data acquisition and concept development were funded under a Supersonics NRA NNX07AC62A awarded to Dimitri Papamoschou at University of California, Irvine. The technology involved the introduction of airfoils in the fan stream of a bypass ratio (BPR) two nozzle system operated at transonic exhaust speeds. The vanes deflected the fan stream relative to the core stream and resulted in reduced sideline noise for polar angles in the peak jet noise direction. Noise prediction models were developed for a range of vane configurations. The models interface with an existing ANOPP module and can be used or future system level studies.

  17. Net present biodiversity value and the design of biodiversity offsets.

    Science.gov (United States)

    Overton, Jacob McC; Stephens, R T Theo; Ferrier, Simon

    2013-02-01

    There is an urgent need to develop sound theory and practice for biodiversity offsets to provide a better basis for offset multipliers, to improve accounting for time delays in offset repayments, and to develop a common framework for evaluating in-kind and out-of-kind offsets. Here, we apply concepts and measures from systematic conservation planning and financial accounting to provide a basis for determining equity across type (of biodiversity), space, and time. We introduce net present biodiversity value (NPBV) as a theoretical and practical measure for defining the offset required to achieve no-net-loss. For evaluating equity in type and space we use measures of biodiversity value from systematic conservation planning. Time discount rates are used to address risk of non-repayment, and loss of utility. We illustrate these concepts and measures with two examples of biodiversity impact-offset transactions. Considerable further work is required to understand the characteristics of these approaches.

  18. Collisional-radiative models for hydrogen-like and helium-like carbon and oxygen ions and applications to experimental data from the TS Tokamak and the reversed field pinch RFX

    Energy Technology Data Exchange (ETDEWEB)

    Carraro, L.; Sattin, F.; Puiatty, M.E.; Scarin, P.; Valisa, M. [Associazione EURATOM-ENEA sulla Fusione, Frascati (Italy); Mattioli, M.; Demichelis, C.; Mandl, W. [Association Euratom-CEA, Centre d`Etudes de Cadarache, 13 - Saint-Paul-lez-Durance (France). Dept. de Recherches sur la Fusion Controlee; Hogan, J.T. [Oak Ridge National Lab., TN (United States)

    1996-07-01

    Collisional radiative models (CRM) are needed to simulate experimental line brightnesses and emissivities from fusion devices. CRM are built for H-like and He-like carbon and oxygen ions. The impurity ion radial distribution is obtained using a transport code with two radius dependent transport parameters: a diffusion coefficient D and an inward convection velocity V. Examples are given of the quantitative interpretation of experimental spectroscopic data from two fusion devices: the Tore Supra Tokamak and the Reversed Field Pinch RFX. (K.A.). 60 refs.

  19. Collisional-radiative models for hydrogen-like and helium-like carbon and oxygen ions and applications to experimental data from the TS Tokamak and the reversed field pinch RFX

    International Nuclear Information System (INIS)

    Carraro, L.; Sattin, F.; Puiatty, M.E.; Scarin, P.; Valisa, M.; Mattioli, M.; Demichelis, C.; Mandl, W.

    1996-07-01

    Collisional radiative models (CRM) are needed to simulate experimental line brightnesses and emissivities from fusion devices. CRM are built for H-like and He-like carbon and oxygen ions. The impurity ion radial distribution is obtained using a transport code with two radius dependent transport parameters: a diffusion coefficient D and an inward convection velocity V. Examples are given of the quantitative interpretation of experimental spectroscopic data from two fusion devices: the Tore Supra Tokamak and the Reversed Field Pinch RFX. (K.A.)

  20. Phase-ambiguity resolution for QPSK modulation systems. Part 2: A method to resolve offset QPSK

    Science.gov (United States)

    Nguyen, Tien Manh

    1989-01-01

    Part 2 presents a new method to resolve the phase-ambiguity for Offset QPSK modulation systems. When an Offset Quaternary Phase-Shift-Keyed (OQPSK) communications link is utilized, the phase ambiguity of the reference carrier must be resolved. At the transmitter, two different unique words are separately modulated onto the quadrature carriers. At the receiver, the recovered carrier may have one of four possible phases, 0, 90, 180, or 270 degrees, referenced to the nominally correct phase. The IF portion of the channel may cause a phase-sense reversal, i.e., a reversal in the direction of phase rotation for a specified bit pattern. Hence, eight possible phase relationships (the so-called eight ambiguous phase conditions) between input and output of the demodulator must be resolved. Using the In-phase (I)/Quadrature (Q) channel reversal correcting property of an OQPSK Costas loop with integrated symbol synchronization, four ambiguous phase conditions are eliminated. Thus, only four possible ambiguous phase conditions remain. The errors caused by the remaining ambiguous phase conditions can be corrected by monitoring and detecting the polarity of the two unique words. The correction of the unique word polarities results in the complete phase-ambiguity resolution for the OQPSK system.

  1. Offset Implementations for Turkey’s International Defense Acquisitions

    Science.gov (United States)

    2008-12-01

    has been a source of confusion in the field of offsets and countertrade (Schmidt, 1989, p. 4) Compensatory trade agreements — or reciprocal trade...complementary policy instruments. Countertrade and offset terms have usually been overall terms to define and classify reciprocal trade agreements...motives and characteristics in nature. Author Grant T. Hammond classifies reciprocal trade as countertrade , offsets and barter — which involve all

  2. Success Factors in Offset Deals: A Case Study Based Examination

    OpenAIRE

    Heinz Kirchwehm

    2014-01-01

    The requests for offset obligations occurs primarily in the area of arms imports and covers the full range of industrial and commercial benefits that companies provide to foreign governments as inducements or conditions for the purchase of military goods and services. Increasingly, all major contracts ask for offset obligations. They are now key differentiators in major contracts and it is a fast growing market. For the suppliers, offsets are a key differentiator in earning new business and t...

  3. Enhanced marine sulphur emissions offset global warming and impact rainfall.

    Science.gov (United States)

    Grandey, B S; Wang, C

    2015-08-21

    Artificial fertilisation of the ocean has been proposed as a possible geoengineering method for removing carbon dioxide from the atmosphere. The associated increase in marine primary productivity may lead to an increase in emissions of dimethyl sulphide (DMS), the primary source of sulphate aerosol over remote ocean regions, potentially causing direct and cloud-related indirect aerosol effects on climate. This pathway from ocean fertilisation to aerosol induced cooling of the climate may provide a basis for solar radiation management (SRM) geoengineering. In this study, we investigate the transient climate impacts of two emissions scenarios: an RCP4.5 (Representative Concentration Pathway 4.5) control; and an idealised scenario, based on RCP4.5, in which DMS emissions are substantially enhanced over ocean areas. We use mini-ensembles of a coupled atmosphere-ocean configuration of CESM1(CAM5) (Community Earth System Model version 1, with the Community Atmosphere Model version 5). We find that the cooling effect associated with enhanced DMS emissions beneficially offsets greenhouse gas induced warming across most of the world. However, the rainfall response may adversely affect water resources, potentially impacting human livelihoods. These results demonstrate that changes in marine phytoplankton activity may lead to a mixture of positive and negative impacts on the climate.

  4. Economic and ecological outcomes of flexible biodiversity offset systems.

    Science.gov (United States)

    Habib, Thomas J; Farr, Daniel R; Schneider, Richard R; Boutin, Stan

    2013-12-01

    The commonly expressed goal of biodiversity offsets is to achieve no net loss of specific biological features affected by development. However, strict equivalency requirements may complicate trading of offset credits, increase costs due to restricted offset placement options, and force offset activities to focus on features that may not represent regional conservation priorities. Using the oil sands industry of Alberta, Canada, as a case study, we evaluated the economic and ecological performance of alternative offset systems targeting either ecologically equivalent areas (vegetation types) or regional conservation priorities (caribou and the Dry Mixedwood natural subregion). Exchanging dissimilar biodiversity elements requires assessment via a generalized metric; we used an empirically derived index of biodiversity intactness to link offsets with losses incurred by development. We considered 2 offset activities: land protection, with costs estimated as the net present value of profits of petroleum and timber resources to be paid as compensation to resource tenure holders, and restoration of anthropogenic footprint, with costs estimated from existing restoration projects. We used the spatial optimization tool MARXAN to develop hypothetical offset networks that met either the equivalent-vegetation or conservation-priority targets. Networks that required offsetting equivalent vegetation cost 2-17 times more than priority-focused networks. This finding calls into question the prudence of equivalency-based systems, particularly in relatively undeveloped jurisdictions, where conservation focuses on limiting and directing future losses. Priority-focused offsets may offer benefits to industry and environmental stakeholders by allowing for lower-cost conservation of valued ecological features and may invite discussion on what land-use trade-offs are acceptable when trading biodiversity via offsets. Resultados Económicos y Ecológicos de Sistemas de Compensación de

  5. Attention-dependent sound offset-related brain potentials.

    Science.gov (United States)

    Horváth, János

    2016-05-01

    When performing sensory tasks, knowing the potentially occurring goal-relevant and irrelevant stimulus events allows the establishment of selective attention sets, which result in enhanced sensory processing of goal-relevant events. In the auditory modality, such enhancements are reflected in the increased amplitude of the N1 ERP elicited by the onsets of task-relevant sounds. It has been recently suggested that ERPs to task-relevant sound offsets are similarly enhanced in a tone-focused state in comparison to a distracted one. The goal of the present study was to explore the influence of attention on ERPs elicited by sound offsets. ERPs elicited by tones in a duration-discrimination task were compared to ERPs elicited by the same tones in not-tone-focused attentional setting. Tone offsets elicited a consistent, attention-dependent biphasic (positive-negative--P1-N1) ERP waveform for tone durations ranging from 150 to 450 ms. The evidence, however, did not support the notion that the offset-related ERPs reflected an offset-specific attention set: The offset-related ERPs elicited in a duration-discrimination condition (in which offsets were task relevant) did not significantly differ from those elicited in a pitch-discrimination condition (in which the offsets were task irrelevant). Although an N2 reflecting the processing of offsets in task-related terms contributed to the observed waveform, this contribution was separable from the offset-related P1 and N1. The results demonstrate that when tones are attended, offset-related ERPs may substantially overlap endogenous ERP activity in the postoffset interval irrespective of tone duration, and attention differences may cause ERP differences in such postoffset intervals. © 2016 Society for Psychophysiological Research.

  6. 22 CFR 213.21 - Employee salary offset-general.

    Science.gov (United States)

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Employee salary offset-general. 213.21 Section... § 213.21 Employee salary offset—general. (a) Purpose. This section establishes USAID's policies and... account of an employee. (b) Scope. The provisions of this section apply to collection by salary offset...

  7. 45 CFR 1179.8 - Procedures for salary offset.

    Science.gov (United States)

    2010-10-01

    ... 45 Public Welfare 3 2010-10-01 2010-10-01 false Procedures for salary offset. 1179.8 Section 1179... AND THE HUMANITIES NATIONAL ENDOWMENT FOR THE HUMANITIES SALARY OFFSET § 1179.8 Procedures for salary... to final salary payment or leave in accordance with 31 U.S.C. 3716. ...

  8. 6 CFR 13.44 - Right to administrative offset.

    Science.gov (United States)

    2010-01-01

    ... 6 Domestic Security 1 2010-01-01 2010-01-01 false Right to administrative offset. 13.44 Section 13.44 Domestic Security DEPARTMENT OF HOMELAND SECURITY, OFFICE OF THE SECRETARY PROGRAM FRAUD CIVIL REMEDIES § 13.44 Right to administrative offset. The amount of any penalty or assessment that has become...

  9. 38 CFR 3.658 - Offsets; dependency and indemnity compensation.

    Science.gov (United States)

    2010-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 1 2010-07-01 2010-07-01 false Offsets; dependency and... AFFAIRS ADJUDICATION Pension, Compensation, and Dependency and Indemnity Compensation Adjustments and Resumptions § 3.658 Offsets; dependency and indemnity compensation. (a) When an award of dependency and...

  10. BPM Offset Determination by Sinusoidal Quadrupole K-modulation

    CERN Document Server

    Baer, T; Wenninger, J

    2011-01-01

    To ensure an adequate orbit steering that maximizes the machine aperture, a good knowledge of the BPM measurement offsets is crucial. During this MD, a sinusoidal k-modulation of individually powered quadrupoles was performed to determine the offsets of the nearby BPMs. An accuracy of 10µm for the determination of the absolute beam position is reached.

  11. Measuring coseismic displacements with point-like targets offset tracking

    KAUST Repository

    Hu, Xie; Wang, Teng; Liao, Mingsheng

    2014-01-01

    Offset tracking is an important complement to measure large ground displacements in both azimuth and range dimensions where synthetic aperture radar (SAR) interferometry is unfeasible. Subpixel offsets can be obtained by searching for the cross-correlation peak calculated from the match patches uniformly distributed on two SAR images. However, it has its limitations, including redundant computation and incorrect estimations on decorrelated patches. In this letter, we propose a simple strategy that performs offset tracking on detected point-like targets (PT). We first detect image patches within bright PT by using a sinc-like template from a single SAR image and then perform offset tracking on them to obtain the pixel shifts. Compared with the standard method, the application on the 2010 M 7.2 El Mayor-Cucapah earthquake shows that the proposed PT offset tracking can significantly increase the cross-correlation and thus result in both efficiency and reliability improvements. © 2013 IEEE.

  12. Quadrupole to BPM offset determination in Indus-2

    International Nuclear Information System (INIS)

    Jena, Saroj; Ghodke, A.D.; Singh, G.

    2009-01-01

    A feasibility of finding the quadrupole to BPM offset using beam based alignment (BBA) technique in Indus-2 has been studied. The measurements of the offsets between BPM and quadrupoles could be performed by using quadratic fitting for the minima of the orbit response w. r. t. changes in the quadrupole strengths. These offsets will be integrated to the orbit data during closed orbit correction. There are 72 quadrupoles and 56 BPMs in Indus-2. However the assessment of Quad-BPM offsets is not feasible in some cases due to non-availability of BPM adjacent to quadrupole and also in some cases because of a large phase advance between quadrupole and nearby BPM. Here single corrector method is used to obtain these offsets and assumed the current of each quadrupole can be varied independently. A graphical user interface (GUI) is developed in MATLAB for the use of BBA in Indus-2. (author)

  13. Cerebral proton magnetic resonance spectroscopy demonstrates reversibility of N-acetylaspartate/creatine in gray matter after delayed encephalopathy due to carbon monoxide intoxication

    DEFF Research Database (Denmark)

    Hansen, Marco Bo; Kondziella, Daniel; Danielsen, Else Rubæk

    2014-01-01

    with cerebral proton magnetic resonance spectroscopy showed a dramatically decrease in N-acetylaspartate to total creatine ratios and elevated lactate levels in the gray matter. Subsequently, our patient received six additional sessions of hyperbaric oxygen therapy with only minimal recovery. At six...... reversal of N-acetylaspartate to total creatine ratios in gray matter has, to our knowledge, never been described before and shows that severe, initial measurements may not predict poor long-term patient outcome....

  14. Reversible Statistics

    DEFF Research Database (Denmark)

    Tryggestad, Kjell

    2004-01-01

    The study aims is to describe how the inclusion and exclusion of materials and calculative devices construct the boundaries and distinctions between statistical facts and artifacts in economics. My methodological approach is inspired by John Graunt's (1667) Political arithmetic and more recent work...... within constructivism and the field of Science and Technology Studies (STS). The result of this approach is here termed reversible statistics, reconstructing the findings of a statistical study within economics in three different ways. It is argued that all three accounts are quite normal, albeit...... in different ways. The presence and absence of diverse materials, both natural and political, is what distinguishes them from each other. Arguments are presented for a more symmetric relation between the scientific statistical text and the reader. I will argue that a more symmetric relation can be achieved...

  15. 15 CFR 19.10 - How will Commerce entities use administrative offset (offset of non-tax Federal payments) to...

    Science.gov (United States)

    2010-01-01

    ... 15 Commerce and Foreign Trade 1 2010-01-01 2010-01-01 false How will Commerce entities use administrative offset (offset of non-tax Federal payments) to collect a Commerce debt? 19.10 Section 19.10 Commerce and Foreign Trade Office of the Secretary of Commerce COMMERCE DEBT COLLECTION Procedures To...

  16. Forests and carbon storage

    Science.gov (United States)

    Michael G. Ryan

    2008-01-01

    Forests store much carbon and their growth can be a carbon sink if disturbance or harvesting has killed or removed trees or if trees that can now regrow are planted where they did not historically occur. Forests and long-lived wood products currently offset 310 million metric tons of U.S. fossil fuel emissions of carbon--20 percent of the total (Pacala et al. 2007)....

  17. Mining and biodiversity offsets: a transparent and science-based approach to measure "no-net-loss".

    Science.gov (United States)

    Virah-Sawmy, Malika; Ebeling, Johannes; Taplin, Roslyn

    2014-10-01

    Mining and associated infrastructure developments can present themselves as economic opportunities that are difficult to forego for developing and industrialised countries alike. Almost inevitably, however, they lead to biodiversity loss. This trade-off can be greatest in economically poor but highly biodiverse regions. Biodiversity offsets have, therefore, increasingly been promoted as a mechanism to help achieve both the aims of development and biodiversity conservation. Accordingly, this mechanism is emerging as a key tool for multinational mining companies to demonstrate good environmental stewardship. Relying on offsets to achieve "no-net-loss" of biodiversity, however, requires certainty in their ecological integrity where they are used to sanction habitat destruction. Here, we discuss real-world practices in biodiversity offsetting by assessing how well some leading initiatives internationally integrate critical aspects of biodiversity attributes, net loss accounting and project management. With the aim of improving, rather than merely critiquing the approach, we analyse different aspects of biodiversity offsetting. Further, we analyse the potential pitfalls of developing counterfactual scenarios of biodiversity loss or gains in a project's absence. In this, we draw on insights from experience with carbon offsetting. This informs our discussion of realistic projections of project effectiveness and permanence of benefits to ensure no net losses, and the risk of displacing, rather than avoiding biodiversity losses ("leakage"). We show that the most prominent existing biodiversity offset initiatives employ broad and somewhat arbitrary parameters to measure habitat value and do not sufficiently consider real-world challenges in compensating losses in an effective and lasting manner. We propose a more transparent and science-based approach, supported with a new formula, to help design biodiversity offsets to realise their potential in enabling more responsible

  18. Achieving biodiversity benefits with offsets: Research gaps, challenges, and needs.

    Science.gov (United States)

    Gelcich, Stefan; Vargas, Camila; Carreras, Maria Jose; Castilla, Juan Carlos; Donlan, C Josh

    2017-03-01

    Biodiversity offsets are becoming increasingly common across a portfolio of settings: national policy, voluntary programs, international lending, and corporate business structures. Given the diversity of ecological, political, and socio-economic systems where offsets may be applied, place-based information is likely to be most useful in designing and implementing offset programs, along with guiding principles that assure best practice. We reviewed the research on biodiversity offsets to explore gaps and needs. While the peer-reviewed literature on offsets is growing rapidly, it is heavily dominated by ecological theory, wetland ecosystems, and U.S.-based research. Given that majority of offset policies and programs are occurring in middle- and low-income countries, the research gaps we identified present a number of risks. They also present an opportunity to create regionally based learning platforms focused on pilot projects and institutional capacity building. Scientific research should diversify, both topically and geographically, in order to support the successful design, implementation, and monitoring of biodiversity offset programs.

  19. An intercomparison of the thermal offset for different pyranometers

    Science.gov (United States)

    Sanchez, G.; Cancillo, M. L.; Serrano, A.

    2016-07-01

    An unprecedented intensive intercomparison campaign focused on the experimental measurement of the thermal offset of pyranometers has been conducted at Badajoz (Spain) with the participation of three main manufacturers. The purpose of this study is to compare the thermal offset of six commercially available pyranometers, being some of them widely used and others recently commercialized. In this campaign, the capping methodology has been used to experimentally measure the daytime thermal offset of the pyranometers. Thus, a short but intense campaign has been conducted in two selected summer days under clear-sky conditions, covering a large range of solar zenith angle, irradiance, and temperature. Along the campaign, a total of 305 capping events have been performed, 61 for each pyranometer. The daytime thermal offset obtained for different pyranometers ranges between 0 and -16.8 W/m2 depending on the environmental conditions, being sometimes notably higher than values estimated indoors by manufacturers. The thermal offset absolute value of all instruments shows a diurnal cycle, increasing from sunrise to central hours of the day and decreasing from midafternoon to sunset. The analysis demonstrates that thermal offset is notably higher and more variable during daytime than during nighttime, requiring specific daytime measurements. Main results emphasize the key role played by wind speed in modulating the thermal offset.

  20. DFT-based offset-QAM OFDM for optical communications.

    Science.gov (United States)

    Zhao, Jian

    2014-01-13

    We experimentally demonstrate and numerically investigate a discrete-Fourier-transform (DFT) based offset quadrature-amplitude-modulation (offset-QAM) orthogonal frequency division multiplexing (OFDM) system. We investigate the scheme using a set of square-root-raised-cosine functions and a set of super-Gaussian functions as signal spectra. It is shown that offset-QAM OFDM exhibits negligible penalty for all investigated spectra, in contrast to rectangular-function based Nyquist FDM (N-FDM) and sinc-function based conventional OFDM (C-OFDM). The required guard interval (GI) length for dispersion compensation in offset-QAM OFDM is analyzed and shown to scale with twice the subcarrier spacing rather than the full OFDM bandwidth. Experimental results show that 38-Gb/s offset-16QAM OFDM supports 600-km fiber transmission with negligible penalty in the absence of GI while a GI length of eight is required in C-OFDM. Further numerical simulations show that by avoiding the GI, 112-Gb/s polarization multiplexed offset-4QAM OFDM can achieve 23% increase in net data rate over C-OFDM under the same transmission reach. We also discuss the design of the pulse-shaping filter in the DFT-based implementation and show that when compared to N-FDM, the required memory length of the filter for pulse shaping can be reduced from 60 to 2 in offset-QAM OFDM regardless of the fiber length.

  1. Carbon Valuation: Alternatives, Alternations and Lateral Measures?

    DEFF Research Database (Denmark)

    Dalsgaard, Steffen

    2016-01-01

    This article refers to carbon valuation as the practice of ascribing value to, and assessing the value of, actions and objects in terms of carbon emissions. Due to the pervasiveness of carbon emissions in the actions and objects of everyday lives of human beings, the making of carbon offsets and ...

  2. Carbonization

    Energy Technology Data Exchange (ETDEWEB)

    Hennebutte, H G; Goutal, E

    1921-07-04

    Materials such as coal, peat, or schist are subjected to a rising temperature in successive stages in apparatus in which the distillation products are withdrawn at each stage. For example in a three-stage process, the acid products of the first or low-temperature stage are fixed in a suitable reagent, the basic products from a second or higher-temperature stage are absorbed in an acid reagent, hydrocarbons being retained by solvents, while the third are subjected to a pyrogenation process carried out in a closed vessel. Wherein the material is subjected in stages to a rising temperature, the gasified products being withdrawn at each stage, and are prevented as far as possible from mixing with the carbonized products.

  3. Temperature Induced Voltage Offset Drifts in Silicon Carbide Pressure Sensors

    Science.gov (United States)

    Okojie, Robert S.; Lukco, Dorothy; Nguyen, Vu; Savrun, Ender

    2012-01-01

    We report the reduction of transient drifts in the zero pressure offset voltage in silicon carbide (SiC) pressure sensors when operating at 600 C. The previously observed maximum drift of +/- 10 mV of the reference offset voltage at 600 C was reduced to within +/- 5 mV. The offset voltage drifts and bridge resistance changes over time at test temperature are explained in terms of the microstructure and phase changes occurring within the contact metallization, as analyzed by Auger electron spectroscopy and field emission scanning electron microscopy. The results have helped to identify the upper temperature reliable operational limit of this particular metallization scheme to be 605 C.

  4. Public Budget Database - Budget Authority and offsetting receipts 1976-Current

    Data.gov (United States)

    Executive Office of the President — This file contains historical budget authority and offsetting receipts for 1976 through the current budget year, as well as four years of projections. It can be used...

  5. Public Budget Database - Outlays and offsetting receipts 1962-Current

    Data.gov (United States)

    Executive Office of the President — This file contains historical outlays and offsetting receipts for 1962 through the current budget year, as well as four years of projections. It can be used to...

  6. Defense Trade: Data Collection and Coordination on Offsets

    National Research Council Canada - National Science Library

    2000-01-01

    ... on the U.S. economy and national security. Defense offsets are the full range of industrial and commercial benefits that firms provide to foreign governments as inducements or conditions for the purchase of military goods and services...

  7. Offset Trace-Based Video Quality Evaluation Network Transport

    DEFF Research Database (Denmark)

    Seeling, P.; Reisslein, M.; Fitzek, Frank

    2006-01-01

    Video traces contain information about encoded video frames, such as frame sizes and qualities, and provide a convenient method to conduct multimedia networking research. Although wiedely used in networking research, these traces do not allow to determine the video qaulityin an accurate manner...... after networking transport that includes losses and delays. In this work, we provide (i) an overview of frame dependencies that have to be taken into consideration when working with video traces, (ii) an algorithmic approach to combine traditional video traces and offset distortion traces to determine...... the video quality or distortion after lossy network transport, (iii) offset distortion and quality characteristics and (iv) the offset distortion trace format and tools to create offset distortion traces....

  8. Simple UHV offset manipulator with independent theta and phi rotations

    International Nuclear Information System (INIS)

    Jamison, K.D.; Dunning, F.B.

    1984-01-01

    A simple UHV offset manipulator is described that not only allows a target crystal to be moved to any point on a circle centered on the manipulator axis but also provides indepedent theta and phi rotations at each position

  9. Joint implementation: Biodiversity and greenhouse gas offsets

    Science.gov (United States)

    Cutright, Noel J.

    1996-11-01

    One of the most pressing environmental issues today is the possibility that projected increases in global emissions of greenhouse gases from increased deforestation, development, and fossil-fuel combustion could significantly alter global climate patterns. Under the terms of the United Nations Framework Convention on Climate Change, signed in Rio de Janeiro during the June 1992 Earth Summit, the United States and other industrialized countries committed to balancing greenhouse gas emissions at 1990 levels in the year 2000. Included in the treaty is a provision titled “Joint Implementation,” whereby industrialized countries assist developing countries in jointly modifying long-term emission trends, either through emission reductions or by protecting and enhancing greenhouse gas sinks (carbon sequestration). The US Climate Action Plan, signed by President Clinton in 1993, calls for voluntary climate change mitigation measures by various sectors, and the action plan included a new program, the US Initiative on Joint Implementation. Wisconsin Electric decided to invest in a Jl project because its concept encourages creative, cost-effective solutions to environmental problems through partnering, international cooperation, and innovation. The project chosen, a forest preservation and management effort in Belize, will sequester more than five million tons of carbon dioxide over a 40-year period, will become economically selfsustaining after ten years, and will have substantial biodiversity benefits.

  10. The Determinants Of United States Government Policy And Practice Towards Offsets In International Trade

    National Research Council Canada - National Science Library

    Milligan, Joseph

    2003-01-01

    .... Offsets are increasing as a percentage of defense exports. Because US industry leads worldwide defense exports, US offsets policy and the potential impact of offsets on US national security are highly significant...

  11. Offsets in International Weapons Acquisitions: The Turkish Experience

    Science.gov (United States)

    2002-03-01

    Countertrade : In addition to the types of offsets defined above, various types of commercial countertrade arrangements may be required. A contract may...Offsets, Industrial Participation and Countertrade ,” A Compendium of Developments in the Military and Civil Sectors 1995-2000, Presidential Commission...www.ssm.gov.tr/english/projekriterlering.htm ) Internet accessed 14 January 2002b. Schaffer, Lindsey. Winning The Countertrade War, (New York, John Wiley

  12. Impacts of GNSS position offsets on global frame stability

    Science.gov (United States)

    Griffiths, Jake; Ray, Jim

    2014-05-01

    Positional offsets appear in Global Navigation Satellite System (GNSS) time series for a variety of reasons. Antenna or radome changes are the most common cause for these discontinuities. Many others are from earthquakes, receiver changes, and different anthropogenic modifications at or near the stations. Some jumps appear for unknown or undocumented reasons. The accurate determination of station velocities, and therefore geophysical parameters and terrestrial reference frames, requires that positional offsets be correctly found and compensated. Williams (2003) found that undetected offsets introduce a random walk error component in individual station time series. The topic of detecting positional offsets has received considerable attention in recent years (e.g., Detection of Offsets in GPS Experiment; DOGEx), and most research groups using GNSS have adopted a combination of manual and automated methods for finding them. The removal of a positional offset is usually handled by estimating the average station position on both sides of the discontinuity, assuming a constant, continuous velocity. This is sufficient in the absence of time-correlated errors. However, GNSS time series contain systematic and power-law errors (white to random walk noise). In this paper, we aim to evaluate the impact to both individual station results and the overall stability of the global reference frame from adding increasing numbers of positional discontinuities. We use the International GNSS Service (IGS) weekly SINEX files, and iteratively insert positional offset parameters at the midpoint of each data segment. Each iteration includes a restacking of the modified SINEX files using the CATREF software from Institut National de l'Information Géographique et Forestière (IGN) to estimate: regularized station positions, secular velocities, Earth orientation parameters, Helmert frame alignment parameters, and the empirical shifts across all positional discontinuities. A comparison of the

  13. Characteristics and structure of turbulent 3D offset jets

    International Nuclear Information System (INIS)

    Agelin-Chaab, M.; Tachie, M.F.

    2011-01-01

    Highlights: → We investigated three-dimensional turbulent offset jets using particle image velocimetry. → We examined the effects of offset height and Reynolds number on the structure of 3D offset jets. → Effects of Reynolds number and offset height on the decay and growth rates exist close to the exit. → This study provides additional insight and comprehensive data for validating numerical models. - Abstract: Three-dimensional turbulent offset jets were investigated using a particle image velocimetry technique. The measurements were performed at three different exit Reynolds numbers and for four offset heights. The results in the early region of flow development clearly show significant effects of Reynolds number and offset height on the decay of maximum mean velocity and growth of the shear layer. On the contrary, the decay and spread rates were found to be nearly independent of offset height at larger downstream distances. The decay rates of 1.18 ± 0.03 as well as the spread rates of 0.055 ± 0.001 and 0.250 ± 0.005 obtained, respectively, in the wall-normal and lateral directions fall in the range of values reported in previous studies. The locations of the maximum mean velocities increased nearly linearly with streamwise distance in the self-similar region. Analysis from two-point velocity correlations revealed substantially larger structures in the outer layer and self-similar region than in the inner layer and developing region. It was also observed that the hairpin vortices in the inner regions of the wall jets are inclined at angles of 11.2 o ± 0.6 o , which are in good agreement with reported values in boundary layer studies.

  14. Chemical recycling of carbon dioxide emissions from a cement plant into dimethyl ether, a case study of an integrated process in France using a Reverse Water Gas Shift (RWGS) step

    International Nuclear Information System (INIS)

    Vibhatavata, Phuangphet; Borgard, Jean-Marc; Tabarant, Michel; Bianchi, Daniel; Mansilla, Christine

    2013-01-01

    Recycling of carbon dioxide (CO 2 ) and hydrogen (H 2 ) into liquid fuel technology has recently gained wide public interest since it is a potential pathway to increase the liquid fuel supply and to mitigate CO 2 emissions simultaneously. In France, the majority of the electricity production is derived from nuclear and renewable energy which have a low CO 2 footprint. This electricity power enables a potential for massive hydrogen production with low carbon emissions. We studied the possibility to develop this technology at an industrial scale in the French context on a typical industrial example of a cement manufacture in the south of France. An integrated process is proposed, which enables the use of the heat released by the CO 2 to fuel process to help to capture the CO 2 released by the cement manufacture. Some technological issues are discussed, and a potential solution is proposed for the catalyst used in the critical step of the Reverse Water Gas-Shift reaction (RWGS) of the process. (authors)

  15. Comparison of Greenhouse Gas Offset Quantification Protocols for Nitrogen Management in Dryland Wheat Cropping Systems of the Pacific Northwest

    Directory of Open Access Journals (Sweden)

    Tabitha T. Brown

    2017-11-01

    Full Text Available In the carbon market, greenhouse gas (GHG offset protocols need to ensure that emission reductions are of high quality, quantifiable, and real. Lack of consistency across protocols for quantifying emission reductions compromise the credibility of offsets generated. Thus, protocol quantification methodologies need to be periodically reviewed to ensure emission offsets are credited accurately and updated to support practical climate policy solutions. Current GHG emission offset credits generated by agricultural nitrogen (N management activities are based on reducing the annual N fertilizer application rate for a given crop without reducing yield. We performed a “road test” of agricultural N management protocols to evaluate differences among protocol components and quantify nitrous oxide (N2O emission reductions under sample projects relevant to N management in dryland, wheat-based cropping systems of the inland Pacific Northwest (iPNW. We evaluated five agricultural N management offset protocols applicable to North America: two methodologies of American Carbon Registry (ACR1 and ACR2, Verified Carbon Standard (VCS, Climate Action Reserve (CAR, and Alberta Offset Credit System (Alberta. We found that only two protocols, ACR2 and VCS, were suitable for this study, in which four sample projects were developed representing feasible N fertilizer rate reduction activities. The ACR2 and VCS protocols had identical baseline and project emission quantification methodologies resulting in identical emission reduction values. Reducing N fertilizer application rate by switching to variable rate N (sample projects 1–3 or split N application (sample project 4 management resulted in a N2O emission reduction ranging from 0.07 to 0.16, and 0.26 Mg CO2e ha−1, respectively. Across the range of C prices considered ($5, $10, and $50 per metric ton of CO2 equivalent, we concluded that the N2O emission offset payment alone ($0.35–$13.0 ha−1 was unlikely to

  16. Heritable IUGR and adult metabolic syndrome are reversible and associated with alterations in the metabolome following dietary supplementation of 1-carbon intermediates.

    Science.gov (United States)

    Seferovic, Maxim D; Goodspeed, Danielle M; Chu, Derrick M; Krannich, Laura A; Gonzalez-Rodriguez, Pablo J; Cox, James E; Aagaard, Kjersti M

    2015-06-01

    Metabolic syndrome (MetS), following intrauterine growth restriction (IUGR), is epigenetically heritable. Recently, we abrogated the F2 adult phenotype with essential nutrient supplementation (ENS) of intermediates along the 1-carbon pathway. With the use of the same grandparental uterine artery ligation model, we profiled the F2 serum metabolome at weaning [postnatal day (d)21; n = 76] and adulthood (d160; n = 12) to test if MetS is preceded by alterations in the metabolome. Indicative of developmentally programmed MetS, adult F2, formerly IUGR rats, were obese (621 vs. 461 g; P metabolome at weaning (randomForest analysis; class error metabolome accompany heritable IUGR, precede adult-onset MetS, and are partially amenable to dietary intervention. © FASEB.

  17. Compaction of LiBH4-LiAlH4 nanoconfined in activated carbon nanofibers: Dehydrogenation kinetics, reversibility, and mechanical stability during cycling

    DEFF Research Database (Denmark)

    Plerdsranoy, Praohatsorn; Javadian-Deylami, Seyd Payam; Jensen, Nicholai Daugaard

    2017-01-01

    To enhance volumetric hydrogen capacity for on-board fuel cells, compaction of LiAlH4-LiBH4 nanoconfined in activated carbon nanofibers (ACNF) is for the first time proposed. Loose powders of milled and nanoconfined LiAlH4-LiBH4 samples are compacted under 976 MPa to obtain the pellet samples...... with thickness and diameter of ∼1.20–1.30 and 8.0 mm, respectively. Dehydrogenation temperature of milled LiAlH4-LiBH4 increases from 415 to 434 °C due to compaction, while those of both compacted and loose powder samples of nanoconfined LiAlH4-LiBH4 are lower at comparable temperature of 330–335 °C. Hydrogen...

  18. Formation of Offset and Dual Active Galactic Nuclei

    Science.gov (United States)

    Barrows, Scott; Comerford, Julia M.; Greene, Jenny E.

    2018-06-01

    Galaxy mergers are effective mechanisms for triggering accretion onto supermassive black holes (SMBHs) and thereby powering active galactic nuclei (AGN). In the merger scenario, when the SMBH from only one galaxy is accreting we observe a spatially offset AGN, and when the SMBHs from both galaxies are accreting we observe a dual AGN. Understanding the merger conditions that lead to the formation of offset AGN versus dual AGN is fundamental to informing models of hierarchical SMBH growth and the physics leading to the accretion of matter onto SMBHs. However, while the role of galaxy mergers for AGN triggering has been well-studied, the efficiency with which these events trigger offset AGN versus dual AGN is currently unclear. One reason for this gap in knowledge can be attributed to the observational difficulties in distinguishing between offset and dual AGN since doing so requires high spatial resolution, especially in the small separation regime where merger-driven AGN triggering is most likely to occur. To overcome this hurdle, we have utilized the spatial resolution of the Chandra X-ray Observatory to develop a unique sample of AGN hosted by late-stage galaxy mergers. Moreover, we have recently acquired Hubble Space Telescope imaging for a subset of these systems to examine the role that their merger morphologies play in SMBH growth and the formation of offset and dual AGN. We find that offset AGN are predominately found in minor mergers, whereas dual AGN are usually hosted by major mergers and galaxies with large morphological asymmetries. Furthermore, in both offset and dual AGN, the rate of SMBH growth increases toward more major mergers and larger morphological asymmetries. These results are in agreement with numerical simulations predicting that merger morphology is a relevant parameter governing SMBH merger-driven growth, and these results are the first to observationally confirm these trends at small pair separations.

  19. Fundamentally Addressing Bromine Storage through Reversible Solid-State Confinement in Porous Carbon Electrodes: Design of a High-Performance Dual-Redox Electrochemical Capacitor.

    Science.gov (United States)

    Yoo, Seung Joon; Evanko, Brian; Wang, Xingfeng; Romelczyk, Monica; Taylor, Aidan; Ji, Xiulei; Boettcher, Shannon W; Stucky, Galen D

    2017-07-26

    Research in electric double-layer capacitors (EDLCs) and rechargeable batteries is converging to target systems that have battery-level energy density and capacitor-level cycling stability and power density. This research direction has been facilitated by the use of redox-active electrolytes that add faradaic charge storage to increase energy density of the EDLCs. Aqueous redox-enhanced electrochemical capacitors (redox ECs) have, however, performed poorly due to cross-diffusion of soluble redox couples, reduced cycle life, and low operating voltages. In this manuscript, we propose that these challenges can be simultaneously met by mechanistically designing a liquid-to-solid phase transition of oxidized catholyte (or reduced anolyte) with confinement in the pores of electrodes. Here we demonstrate the realization of this approach with the use of bromide catholyte and tetrabutylammonium cation that induces reversible solid-state complexation of Br 2 /Br 3 - . This mechanism solves the inherent cross-diffusion issue of redox ECs and has the added benefit of greatly stabilizing the reactive bromine generated during charging. Based on this new mechanistic insight on the utilization of solid-state bromine storage in redox ECs, we developed a dual-redox EC consisting of a bromide catholyte and an ethyl viologen anolyte with the addition of tetrabutylammonium bromide. In comparison to aqueous and organic electric double-layer capacitors, this system enhances energy by factors of ca. 11 and 3.5, respectively, with a specific energy of ∼64 W·h/kg at 1 A/g, a maximum power density >3 kW/kg, and cycling stability over 7000 cycles.

  20. Offset-electrode profile acquisition strategy for electrical resistivity tomography

    Science.gov (United States)

    Robbins, Austin R.; Plattner, Alain

    2018-04-01

    We present an electrode layout strategy that allows electrical resistivity profiles to image the third dimension close to the profile plane. This "offset-electrode profile" approach involves laterally displacing electrodes away from the profile line in an alternating fashion and then inverting the resulting data using three-dimensional electrical resistivity tomography software. In our synthetic and field surveys, the offset-electrode method succeeds in revealing three-dimensional structures in the vicinity of the profile plane, which we could not achieve using three-dimensional inversions of linear profiles. We confirm and explain the limits of linear electrode profiles through a discussion of the three-dimensional sensitivity patterns: For a homogeneous starting model together with a linear electrode layout, all sensitivities remain symmetric with respect to the profile plane through each inversion step. This limitation can be overcome with offset-electrode layouts by breaking the symmetry pattern among the sensitivities. Thanks to freely available powerful three-dimensional resistivity tomography software and cheap modern computing power, the requirement for full three-dimensional calculations does not create a significant burden and renders the offset-electrode approach a cost-effective method. By offsetting the electrodes in an alternating pattern, as opposed to laying the profile out in a U-shape, we minimize shortening the profile length.

  1. Offsets : An innovative approach to reducing greenhouse gases

    International Nuclear Information System (INIS)

    Steward, B.

    1998-01-01

    One of the most innovative ways to address climate change is the use of offsets, which refers to actions taken outside of a company's operations, domestically and internationally, to reduce greenhouse gas emissions. This paper is devoted to a discussion of Suncor Energy's action plan for greenhouse gases which include offsets, and to an explanation of the reasons why offsets are fundamental to successful greenhouse gas management. Suncor Energy Inc., has developed a plan with seven elements to meet their target of stabilizing their greenhouse gas emissions at 1990 levels by year 2000. The seven elements include: (1) energy efficiency and process improvements at their oil sands facility, (2) the development of alternative and renewable sources of energy, such as ethanol blended gasolines and the use of wind turbines to generate electricity, (3) promoting environmental and economic research to develop more advanced oil and gas technology to reduce greenhouse gas emissions, (4) implementing a constructive public policy input in support of sustainable development, (5) educating employees, customers and communities on global climate change, (6) measuring and reporting the company's environmental progress, and (7) pursuing domestic and international offset opportunities such as transfer of technology to developing countries, cogeneration of energy using natural gas, energy efficiency, renewable energy sources, emission reduction purchases and forest conservation. Of these proposed measures, offsets are the critical element which could spell the difference between success and failure in managing greenhouse gas emissions and the difference between economic hardship and economic opportunity

  2. Efficacy of Novel Carbon Nanoparticle Antioxidant Therapy in a Severe Model of Reversible Middle Cerebral Artery Stroke in Acutely Hyperglycemic Rats

    Directory of Open Access Journals (Sweden)

    Roderic H. Fabian

    2018-04-01

    Full Text Available IntroductionWhile oxidative stress can be measured during transient cerebral ischemia, antioxidant therapies for ischemic stroke have been clinically unsuccessful. Many antioxidants are limited in their range and/or capacity for quenching radicals and can generate toxic intermediates overwhelming depleted endogenous protection. We developed a new antioxidant class, 40 nm × 2 nm carbon nanoparticles, hydrophilic carbon clusters, conjugated to poly(ethylene glycol termed PEG-HCCs. These particles are high-capacity superoxide dismutase mimics, are effective against hydroxyl radical, and restore the balance between nitric oxide and superoxide in the vasculature. Here, we report the effects of PEG-HCCs administered during reperfusion after transient middle cerebral artery occlusion (tMCAO by suture in the rat under hyperglycemic conditions. Hyperglycemia occurs in one-third of stroke patients and worsens clinical outcome. In animal models, this worsening occurs largely by accelerating elaboration of reactive oxygen species (ROS during reperfusion.MethodsPEG-HCCs were studied for their protective ability against hydrogen peroxide in b.End3 brain endothelial cell line and E17 primary cortical neuron cultures. In vivo, hyperglycemia was induced by streptozotocin injection 2 days before tMCAO. 58 Male Sprague-Dawley rats were analyzed. They were injected IV with PBS or PEG-HCCs (4 mg/kg 2× at the time of recanalization after either 90- or 120-min occlusion. Rats were survived for up to 3 days, and infarct volume characteristics and neurological functional outcome (modified Bederson Score were assessed.ResultsPEG-HCCs were protective against hydrogen peroxide in both culture models. In vivo improvement was found after PEG-HCCs with 90-min ischemia with reduction in infarct size (42%, hemisphere swelling (46%, hemorrhage score (53%, and improvement in Bederson score (70% (p = 0.068–0.001. Early high mortality in the 2-h in the PBS

  3. Skallerup Klit's carbon footprint

    DEFF Research Database (Denmark)

    Zacho, Kristina Overgaard; Ørnstrup, Niels Holm; Zimmermann, Tine Marquard

    by offsetting and without making actual emission reductions. Therefore the purpose of this study is to present recommendations on how Skallerup Klit can build up their business strategy using Carbon Footprint (CFP) as a tool. The CPF is calculated and assessed by using financial data in an Input-output LCA...

  4. Biodiversity offsetting and restoration under the European Union Habitats Directive: balancing between no net loss and deathbed conservation?

    Directory of Open Access Journals (Sweden)

    Hendrik Schoukens

    2016-12-01

    Full Text Available Biodiversity offsets have emerged as one of the most prominent policy approaches to align economic development with nature protection across many jurisdictions, including the European Union. Given the increased level of scrutiny that needs to be applied when authorizing economic developments near protected Natura 2000 sites, the incorporation of onsite biodiversity offsets in project design has grown increasingly popular in some member states, such as the Netherlands and Belgium. Under this approach, the negative effects of developments are outbalanced by restoration programs that are functionally linked to the infrastructure projects. However, although taking into consideration that the positive effects of onsite restoration measures leads to more leeway for harmful project development, the EU Court of Justice has recently dismissed the latter approaches for going against the preventative underpinnings of the EU Habitats Directive. Also, the expected beneficial outcomes of the restoration efforts are uncertain and thus cannot be relied upon in an ecological assessment under Article 6(3 of the Habitats Directive. Although biodiversity offsets can still be relied upon whenever application is being made of the derogation clause under Article 6(4 of the Habitats Directive, they cannot be used as mitigation under the generic decision-making process for plans and programs liable to adversely affect Natura 2000 sites. We outline the main arguments pro and contra the stance of the EU Court of Justice with regards to the exact delineation between mitigation and compensation. The analysis is also framed in the ongoing debate on the effectiveness of the EU nature directives. Although ostensibly rigid, it is argued that the recent case-law developments are in line with the main principles underpinning biodiversity offsetting. Opening the door for biodiversity offsetting under the Habitats Directive will certainly not reverse the predicament of the EU

  5. Long-term simulations of forest management impacts on carbon storage from loblolly pine plantations in the Southern U.S.

    Science.gov (United States)

    Huei-Jin Wang; Philip J. Radtke; Stephen P. Prisley

    2012-01-01

    Accounting for forest components in carbon accounting systems may be insufficient when substantial amounts of sequestered carbon are harvested and converted to wood products in use and in landfill. The potential of forest offset – in-woods aboveground carbon storage, carbon stored in harvested wood, and energy offset by burning harvested wood – from loblolly pine...

  6. Tracing Supermassive Black Hole Growth with Offset and Dual AGN

    Science.gov (United States)

    Comerford, Julia

    The growth of supermassive black holes is tied to the evolution of their host galaxies, but we are still missing a fundamental understanding of how and when supermassive black holes build up their mass. Black hole mass growth can be traced when the black holes are powered as active galactic nuclei (AGN), and AGN activity can be triggered by the stochastic accretion of gas or by gas inflows driven by galaxy mergers. Galaxy merger simulations make a series of predictions about the AGN that are triggered by mergers: (1) major mergers preferentially trigger higher-luminosity AGN, (2) minor mergers more often trigger AGN activity in one supermassive black hole while major mergers more often trigger AGN activity in both black holes in a merger, and (3) black hole mass growth peaks when the black holes approach the center (theory have been limited by the difficulty in defining a clean observational sample of AGN in galaxy mergers and the observational challenge of spatially resolving two AGN with small (dual AGN as a new observational tool that can be used to address how and when supermassive black hole mass growth occurs. A merger of two galaxies brings two supermassive black holes together, and the two black holes exist at kpc-scale separations for 100 Myr before ultimately merging. While the black holes are at kpc-scale separations, they are known as dual AGN when both of them are fueled as AGN and offset AGN when only one is fueled as an AGN. Since offset and dual AGN only occur in galaxy mergers, by their very definition, they provide a clean observational sample of black hole mass growth in galaxy mergers. The small, kpc-scale separations of offset and dual AGN also enable an observational test of black hole fueling near the centers of merger-remnant galaxies. The full potential of offset and dual AGN for such studies of black hole mass growth has not yet been realized, due to the small number of such systems known. To date, only 13 confirmed offset and dual AGN are

  7. Localisation of beam offset jitter sources at ATF2

    CERN Document Server

    Pfingstner, J; Patecki, M; Schulte, D; Tomás, R

    2014-01-01

    For the commissioning and operation of modern particle accelerators, automated error detection and diagnostics methods are becoming increasingly important. In this paper, we present two such methods, which are capable of localising sources of beam offset jitter with a combination of correlation studies and so called degree of freedom plots. The methods were applied to the ATF2 beam line at KEK, where one of the major goals is the reduction of the beam offset jitter. Results of this localisation are shown in this paper. A big advantage of the presented method is its high robustness especially to varying optics parameters. Therefore, we believe that the developed beam offset jitter localisation methods can be easily applied to other accelerators.

  8. 12 CFR 313.49 - Coordinating salary offset with other agencies.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 4 2010-01-01 2010-01-01 false Coordinating salary offset with other agencies... PRACTICE PROCEDURES FOR CORPORATE DEBT COLLECTION Salary Offset § 313.49 Coordinating salary offset with... employee has consented to the salary offset in writing or has signed a statement acknowledging receipt of...

  9. 22 CFR 213.22 - Salary offset when USAID is the creditor agency.

    Science.gov (United States)

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Salary offset when USAID is the creditor agency... Administrative Offset § 213.22 Salary offset when USAID is the creditor agency. (a) Due process requirements... through salary offset, USAID will first provide the employee with the opportunity to pay in full the...

  10. 45 CFR 33.8 - Voluntary repayment agreement in lieu of salary offset.

    Science.gov (United States)

    2010-10-01

    ... 45 Public Welfare 1 2010-10-01 2010-10-01 false Voluntary repayment agreement in lieu of salary... SALARY OFFSET § 33.8 Voluntary repayment agreement in lieu of salary offset. (a)(1) In response to the... notice of intent to offset. An employee who wishes to repay the debt without salary offset shall also...

  11. 7 CFR 3.80 - Written agreement to repay debts as alternative to salary offset.

    Science.gov (United States)

    2010-01-01

    ... salary offset. 3.80 Section 3.80 Agriculture Office of the Secretary of Agriculture DEBT MANAGEMENT Federal Salary Offset § 3.80 Written agreement to repay debts as alternative to salary offset. (a) Notification by employee. The employee may propose, in response to a Notice of Intent to Offset Salary, a...

  12. 7 CFR 3.81 - Procedures for salary offset: when deductions may begin.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 1 2010-01-01 2010-01-01 false Procedures for salary offset: when deductions may... Salary Offset § 3.81 Procedures for salary offset: when deductions may begin. (a) Deductions to liquidate... Offset Salary to collect from the employee's current pay. (b) If the employee filed a petition for a...

  13. 40 CFR 13.22 - Salary offset when EPA is the creditor agency.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 1 2010-07-01 2010-07-01 false Salary offset when EPA is the creditor... COLLECTION STANDARDS Administrative Offset § 13.22 Salary offset when EPA is the creditor agency. (a... through salary offset, EPA will first provide the employee with the opportunity to pay in full the amount...

  14. 22 CFR 213.23 - Salary offset when USAID is not the creditor agency.

    Science.gov (United States)

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Salary offset when USAID is not the creditor... Administrative Offset § 213.23 Salary offset when USAID is not the creditor agency. (a) USAID will use salary... installment, if a date other than the next established pay period. (b) Requests for salary offset must be sent...

  15. 5 CFR 179.213 - Coordinating salary offset with other agencies.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Coordinating salary offset with other... REGULATIONS CLAIMS COLLECTION STANDARDS Salary Offset § 179.213 Coordinating salary offset with other agencies... intent of this regulation. (2) The designated salary offset coordinator will be responsible for: (i...

  16. Quality of urban forest carbon credits

    Science.gov (United States)

    Neelam C. Poudyala; Jacek P. Siry; J.M. Bowker

    2011-01-01

    While the urban forest is considered an eligible source of carbon offset credits, little is known about its market potential and the quality aspects of the credits. As credit suppliers increase in number and credit buyers become more interested in purchasing carbon credits, it is unclear whether and how urban forest carbon credits can perform relative to the other...

  17. In the market for carbon: conventions, coordination and narratives of voluntary carbon offsetting in Chiapas, Mexico

    OpenAIRE

    Hendrickson, Cary Yungmee

    2017-01-01

    Bibliografia. Esta tesis tiene el objetivo de investigar cómo las narrativas globales alrededor de los bonos de carbono en el sector forestal crean valor e influencian lo que los mercados de carbono otorgan, cómo y a quién. Se relaciona con el marco teórico de las convenciones y con el enfoque del análisis del discurso para analizar las diferentes convenciones movilizadas en las narrativas utilizadas por los actores involucrados en la cadena de valor del carbono. Se examina un estudio de c...

  18. Spatially Offset Active Galactic Nuclei. II. Triggering in Galaxy Mergers

    Energy Technology Data Exchange (ETDEWEB)

    Barrows, R. Scott; Comerford, Julia M. [Department of Astrophysical and Planetary Sciences, University of Colorado Boulder, Boulder, CO 80309 (United States); Greene, Jenny E. [Department of Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States); Pooley, David, E-mail: Robert.Barrows@Colorado.edu [Department of Physics and Astronomy, Trinity University, San Antonio, TX 78212 (United States)

    2017-04-01

    Galaxy mergers are likely to play a role in triggering active galactic nuclei (AGNs), but the conditions under which this process occurs are poorly understood. In Paper I, we constructed a sample of spatially offset X-ray AGNs that represent galaxy mergers hosting a single AGN. In this paper, we use our offset AGN sample to constrain the parameters that affect AGN observability in galaxy mergers. We also construct dual-AGN samples with similar selection properties for comparison. We find that the offset AGN fraction shows no evidence for a dependence on AGN luminosity, while the dual-AGN fractions show stronger evidence for a positive dependence, suggesting that the merger events forming dual AGNs are more efficient at instigating accretion onto supermassive black holes than those forming offset AGNs. We also find that the offset and dual-AGN fractions both have a negative dependence on nuclear separation and are similar in value at small physical scales. This dependence may become stronger when restricted to high AGN luminosities, although a larger sample is needed for confirmation. These results indicate that the probability of AGN triggering increases at later merger stages. This study is the first to systematically probe down to nuclear separations of <1 kpc (∼0.8 kpc) and is consistent with predictions from simulations that AGN observability peaks in this regime. We also find that the offset AGNs are not preferentially obscured compared to the parent AGN sample, suggesting that our selection may be targeting galaxy mergers with relatively dust-free nuclear regions.

  19. Pulsar Pair Cascades in Magnetic Fields with Offset Polar Caps

    Science.gov (United States)

    Harding, Alice K.; Muslimov, Alex G.

    2012-01-01

    Neutron star magnetic fields may have polar caps (PC) that are offset from the dipole axis, through field-line sweepback near the light cylinder or non-symmetric currents within the star. The effects of such offsets on electron-positron pair cascades are investigated, using simple models of dipole magnetic fields with small distortions that shift the PCs by different amounts or directions. Using a Monte Carlo pair cascade simulation, we explore the changes in the pair spectrum, multiplicity and energy flux across the PC, as well as the trends in pair flux and pair energy flux with spin-down luminosity, L(sub sd). We also give an estimate of the distribution of heating flux from returning positrons on the PC for different offsets. We find that even modest offsets can produce significant increases in pair multiplicity, especially for pulsars that are near or beyond the pair death lines for centered PCs, primarily because of higher accelerating fields. Pair spectra cover several decades in energy, with the spectral range of millisecond pulsars (MSPs) two orders of magnitude higher than for normal pulsars, and PC offsets allow significant extension of all spectra to lower pair energies. We find that the total PC pair luminosity L(sub pair) is proportional to L(sub sd), with L(sub pair) approximates 10(exp -3) L(sub sd) for normal pulsars and L(sub pair) approximates 10(exp -2) L(sub sd) for MSPs. Remarkably, the total PC heating luminosity for even large offsets increases by less than a factor of two, even though the PC area increases by much larger factors, because most of the heating occurs near the magnetic axis.

  20. Spatially Offset Active Galactic Nuclei. II. Triggering in Galaxy Mergers

    Science.gov (United States)

    Barrows, R. Scott; Comerford, Julia M.; Greene, Jenny E.; Pooley, David

    2017-04-01

    Galaxy mergers are likely to play a role in triggering active galactic nuclei (AGNs), but the conditions under which this process occurs are poorly understood. In Paper I, we constructed a sample of spatially offset X-ray AGNs that represent galaxy mergers hosting a single AGN. In this paper, we use our offset AGN sample to constrain the parameters that affect AGN observability in galaxy mergers. We also construct dual-AGN samples with similar selection properties for comparison. We find that the offset AGN fraction shows no evidence for a dependence on AGN luminosity, while the dual-AGN fractions show stronger evidence for a positive dependence, suggesting that the merger events forming dual AGNs are more efficient at instigating accretion onto supermassive black holes than those forming offset AGNs. We also find that the offset and dual-AGN fractions both have a negative dependence on nuclear separation and are similar in value at small physical scales. This dependence may become stronger when restricted to high AGN luminosities, although a larger sample is needed for confirmation. These results indicate that the probability of AGN triggering increases at later merger stages. This study is the first to systematically probe down to nuclear separations of <1 kpc (˜0.8 kpc) and is consistent with predictions from simulations that AGN observability peaks in this regime. We also find that the offset AGNs are not preferentially obscured compared to the parent AGN sample, suggesting that our selection may be targeting galaxy mergers with relatively dust-free nuclear regions.

  1. Managing Reverse Logistics or Reversing Logistics Management?

    OpenAIRE

    Brito, Marisa

    2004-01-01

    textabstractIn the past, supply chains were busy fine-tuning the logistics from raw material to the end customer. Today an increasing flow of products is going back in the chain. Thus, companies have to manage reverse logistics as well.This thesis contributes to a better understanding of reverse logistics. The thesis brings insights on reverse logistics decision-making and it lays down theoretical principles for reverse logistics as a research field.In particular it puts together a framework ...

  2. Investigation on synchronization of the offset printing process for fine patterning and precision overlay

    International Nuclear Information System (INIS)

    Kang, Dongwoo; Lee, Eonseok; Kim, Hyunchang; Choi, Young-Man; Lee, Seunghyun; Kim, Inyoung; Yoon, Dukkyun; Jo, Jeongdai; Kim, Bongmin; Lee, Taik-Min

    2014-01-01

    Offset printing processes are promising candidates for producing printed electronics due to their capacity for fine patterning and suitability for mass production. To print high-resolution patterns with good overlay using offset printing, the velocities of two contact surfaces, which ink is transferred between, should be synchronized perfectly. However, an exact velocity of the contact surfaces is unknown due to several imperfections, including tolerances, blanket swelling, and velocity ripple, which prevents the system from being operated in the synchronized condition. In this paper, a novel method of measurement based on the sticking model of friction force was proposed to determine the best synchronized condition, i.e., the condition in which the rate of synchronization error is minimized. It was verified by experiment that the friction force can accurately represent the rate of synchronization error. Based on the measurement results of the synchronization error, the allowable margin of synchronization error when printing high-resolution patterns was investigated experimentally using reverse offset printing. There is a region where the patterning performance is unchanged even though the synchronization error is varied, and this may be viewed as indirect evidence that printability performance is secured when there is no slip at the contact interface. To understand what happens at the contact surfaces during ink transfer, the deformation model of the blanket's surface was developed. The model estimates how much deformation on the blanket's surface can be borne by the synchronization error when there is no slip at the contact interface. In addition, the model shows that the synchronization error results in scale variation in the machine direction (MD), which means that the printing registration in the MD can be adjusted actively by controlling the synchronization if there is a sufficient margin of synchronization error to guarantee printability. The effect of

  3. Multi-residue determination of 171 pesticides in cowpea using modified QuEChERS method with multi-walled carbon nanotubes as reversed-dispersive solid-phase extraction materials.

    Science.gov (United States)

    Han, Yongtao; Song, Le; Zou, Nan; Chen, Ronghua; Qin, Yuhong; Pan, Canping

    2016-09-15

    A rapid and sensitive method for the determination of 171 pesticides in cowpea was developed using multi-walled carbon nanotubes (MWCNTs) as reversed-dispersive solid-phase (r-DSPE) extraction materials. The clean-up performance of MWCNTs was proved to be obviously superior to PSA and GCB. This method was validated on cowpea spiked at 0.01 and 0.1mgkg(-1) with five replicates. The mean recoveries for 169 pesticides ranged from 74% to 129% with relative standard deviations (RSDs) (n=5) lower than 16.4%, except diflufenican and quizalofop-ethyl. Good linearity for all pesticides was obtained with the calibration curve coefficients (R(2)) larger than 0.9970. The limit of detection (LODs) and limit of quantification (LOQs) for the 171 pesticides ranged from 0.001 to 0.003mgkg(-1) and from 0.002 to 0.009mgkg(-1), respectively. The method was demonstrated to be reliable and sensitive for the routine monitoring of the 171 pesticides in cowpea samples. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. 20 CFR 404.525 - Suspension of offset.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 2 2010-04-01 2010-04-01 false Suspension of offset. 404.525 Section 404.525 Employees' Benefits SOCIAL SECURITY ADMINISTRATION FEDERAL OLD-AGE, SURVIVORS AND DISABILITY INSURANCE (1950....521, the overpaid individual notifies us that he or she is exercising a right described in § 404.522(a...

  5. Imagining Another Context during Encoding Offsets Context-Dependent Forgetting

    Science.gov (United States)

    Masicampo, E. J.; Sahakyan, Lili

    2014-01-01

    We tested whether imagining another context during encoding would offset context-dependent forgetting. All participants studied a list of words in Context A. Participants who remained in Context A during the test recalled more than participants who were tested in another context (Context B), demonstrating the standard context-dependent forgetting…

  6. 76 FR 24406 - Collection by Offset From Indebted Government Employees

    Science.gov (United States)

    2011-05-02

    ... alternative dispute resolution methods if they are not inconsistent with agency-specific laws and regulations... by offset and allows the debtor additional opportunities to dispute the debt, enter into a repayment... is proposing to revise the definition of FCCS to include a reference to 31 CFR parts 900 through 904...

  7. Subsurface offset behaviour in velocity analysis with extended reflectivity images

    NARCIS (Netherlands)

    Mulder, W.A.

    2012-01-01

    Migration velocity analysis with the wave equation can be accomplished by focusing of extended migration images, obtained by introducing a subsurface offset or shift. A reflector in the wrong velocity model will show up as a curve in the extended image. In the correct model, it should collapse to a

  8. 75 FR 62348 - Reimbursement Offsets for Medical Care or Services

    Science.gov (United States)

    2010-10-08

    ... DEPARTMENT OF VETERANS AFFAIRS 38 CFR Part 17 RIN 2900-AN55 Reimbursement Offsets for Medical Care... Veterans Affairs (VA) proposes to amend its regulations concerning the reimbursement of medical care and... situations where third-party payers are required to reimburse VA for costs related to care provided by VA to...

  9. Performance and Vibration Analyses of Lift-Offset Helicopters

    Directory of Open Access Journals (Sweden)

    Jeong-In Go

    2017-01-01

    Full Text Available A validation study on the performance and vibration analyses of the XH-59A compound helicopter is conducted to establish techniques for the comprehensive analysis of lift-offset compound helicopters. This study considers the XH-59A lift-offset compound helicopter using a rigid coaxial rotor system as a verification model. CAMRAD II (Comprehensive Analytical Method of Rotorcraft Aerodynamics and Dynamics II, a comprehensive analysis code, is used as a tool for the performance, vibration, and loads analyses. A general free wake model, which is a more sophisticated wake model than other wake models, is used to obtain good results for the comprehensive analysis. Performance analyses of the XH-59A helicopter with and without auxiliary propulsion are conducted in various flight conditions. In addition, vibration analyses of the XH-59A compound helicopter configuration are conducted in the forward flight condition. The present comprehensive analysis results are in good agreement with the flight test and previous analyses. Therefore, techniques for the comprehensive analysis of lift-offset compound helicopters are appropriately established. Furthermore, the rotor lifts are calculated for the XH-59A lift-offset compound helicopter in the forward flight condition to investigate the airloads characteristics of the ABC™ (Advancing Blade Concept rotor.

  10. Positron annihilation imaging device using multiple offset rings of detectors

    International Nuclear Information System (INIS)

    Thompson, C.J.

    1981-01-01

    This patent application relates to a positron annihilation imaging device comprising two or more coaxial circular arrays of detectors (2,2'), with the detectors in one array angularly offset with respect to the detectors in the adjacent array to detect more than one tomographic image simultaneously through different cross-sections of a patient. (author)

  11. Model Predictive Control for Offset-Free Reference Tracking

    Czech Academy of Sciences Publication Activity Database

    Belda, Květoslav

    2016-01-01

    Roč. 5, č. 1 (2016), s. 8-13 ISSN 1805-3386 Institutional support: RVO:67985556 Keywords : offset-free reference tracking * predictive control * ARX model * state-space model * multi-input multi-output system * robotic system * mechatronic system Subject RIV: BC - Control Systems Theory http://library.utia.cas.cz/separaty/2016/AS/belda-0458355.pdf

  12. Managing Reverse Logistics or Reversing Logistics Management?

    NARCIS (Netherlands)

    M.P. de Brito (Marisa)

    2004-01-01

    textabstractIn the past, supply chains were busy fine-tuning the logistics from raw material to the end customer. Today an increasing flow of products is going back in the chain. Thus, companies have to manage reverse logistics as well.This thesis contributes to a better understanding of reverse

  13. Competitiveness of terrestrial greenhouse gas offsets. Are they a bridge to the future?

    International Nuclear Information System (INIS)

    McCarl, B.A.; Sands, R.D.

    2007-01-01

    Activities to reduce net greenhouse gas emissions by biological soil or forest carbon sequestration predominantly utilize currently known, readily implementable technologies. Many other greenhouse gas emission reduction options require future technological development or must wait for turnover of capital stock. Carbon sequestration options in soils and forests, while ready to go now, generally have a finite life, allowing use until other strategies are developed. This paper reports on an investigation of the competitiveness of biological carbon sequestration from a dynamic and multiple strategy viewpoint. Key factors affecting the competitiveness of terrestrial mitigation options are land availability and cost effectiveness relative to other options including CO2 capture and storage, energy efficiency improvements, fuel switching, and non-CO2 greenhouse gas emission reductions. The analysis results show that, at lower CO2 prices and in the near term, soil carbon and other agricultural/forestry options can be important bridges to the future, initially providing a substantial portion of attainable reductions in net greenhouse gas emissions, but with a limited role in later years. At higher CO2 prices, afforestation and biofuels are more dominant among terrestrial options to offset greenhouse gas emissions. But in the longer run, allowing for capital stock turnover, options to reduce greenhouse gas emissions from the energy system and biofuels provide an increasing share of potential reductions in total US greenhouse gas emissions

  14. Reversible Thermoset Adhesives

    Science.gov (United States)

    Mac Murray, Benjamin C. (Inventor); Tong, Tat H. (Inventor); Hreha, Richard D. (Inventor)

    2016-01-01

    Embodiments of a reversible thermoset adhesive formed by incorporating thermally-reversible cross-linking units and a method for making the reversible thermoset adhesive are provided. One approach to formulating reversible thermoset adhesives includes incorporating dienes, such as furans, and dienophiles, such as maleimides, into a polymer network as reversible covalent cross-links using Diels Alder cross-link formation between the diene and dienophile. The chemical components may be selected based on their compatibility with adhesive chemistry as well as their ability to undergo controlled, reversible cross-linking chemistry.

  15. Amazon River carbon dioxide outgassing fuelled by wetlands

    NARCIS (Netherlands)

    Abril, G.; Martinez, J.M.; Artigas, L.F.; Moreira-Turcq, P.; Benedetti, M.F.; Vidal, L.; Meziane, T.; Kim, J.-H.; Bernardes, M.C.; Savoye, N.; Deborde, J.; Souza, E.L.; Alberic, P.; de Souza, M.F.L.; Roland, F.

    2014-01-01

    River systems connect the terrestrial biosphere, the atmosphere and the ocean in the global carbon cycle(1). A recent estimate suggests that up to 3 petagrams of carbon per year could be emitted as carbon dioxide (CO2) from global inland waters, offsetting the carbon uptake by terrestrial

  16. How to estimate carbon sequestration on small forest tracts estimate carbon sequestration on small forest tracts

    Science.gov (United States)

    Coeli M. Hoover; Richard A. Birdsey; Linda S. Heath; Susan L. Stout

    2000-01-01

    International climate change agreements may allow carbon stored as a result of afforestation and reforestation to be used to offset CO2 emissions. Monitoring the carbon sequestered or released through forest management activities thus becomes important. Estimating forest carbon storage is feasible even for nonindustrial private forestland (NIPF)...

  17. Tubal Ligation Reversal

    Science.gov (United States)

    ... seal off the fallopian tubes, such as the Essure or Adiana systems, generally aren't reversible. Why ... electrocautery). Some types of sterilization, such as the Essure or Adiana systems, aren't considered reversible. Risks ...

  18. Environmental change and the carbon balance of Amazonian forests

    International Nuclear Information System (INIS)

    Aragao, Luiz E.O.C.; Poulter, Benjamin

    2014-01-01

    Extreme climatic events and land-use change are known to influence strongly the current carbon cycle of Amazonia, and have the potential to cause significant global climate impacts. This review intends to evaluate the effects of both climate and anthropogenic perturbations on the carbon balance of the Brazilian Amazon and to understand how they interact with each other. By analysing the outputs of the Intergovernmental Panel for Climate Change (IPCC) Assessment Report 4 (AR4) model ensemble, we demonstrate that Amazonian temperatures and water stress are both likely to increase over the 21. Century. Curbing deforestation in the Brazilian Amazon by 62% in 2010 relative to the 1990's mean decreased the Brazilian Amazon's deforestation contribution to global land use carbon emissions from 17% in the 1990's and early 2000's to 9% by 2010. Carbon sources in Amazonia are likely to be dominated by climatic impacts allied with forest fires (48.3% relative contribution) during extreme droughts. The current net carbon sink (net biome productivity, NBP) of +0.16 (ranging from +0.11 to +0.21) PgCyear-1 in the Brazilian Amazon, equivalent to 13.3% of global carbon emissions from land-use change for 2008, can be negated or reversed during drought years [NBP=-0.06 (-0.31 to +0.01) PgCyear -1 ]. Therefore, reducing forest fires, in addition to reducing deforestation, would be an important measure for minimizing future emissions. Conversely, doubling the current area of secondary forests and avoiding additional removal of primary forests would help the Amazonian gross forest sink to offset approximately 42% of global land-use change emissions. We conclude that a few strategic environmental policy measures are likely to strengthen the Amazonian net carbon sink with global implications. Moreover, these actions could increase the resilience of the net carbon sink to future increases in drought frequency. (authors)

  19. Environmental change and the carbon balance of Amazonian forests.

    Science.gov (United States)

    Aragão, Luiz E O C; Poulter, Benjamin; Barlow, Jos B; Anderson, Liana O; Malhi, Yadvinder; Saatchi, Sassan; Phillips, Oliver L; Gloor, Emanuel

    2014-11-01

    Extreme climatic events and land-use change are known to influence strongly the current carbon cycle of Amazonia, and have the potential to cause significant global climate impacts. This review intends to evaluate the effects of both climate and anthropogenic perturbations on the carbon balance of the Brazilian Amazon and to understand how they interact with each other. By analysing the outputs of the Intergovernmental Panel for Climate Change (IPCC) Assessment Report 4 (AR4) model ensemble, we demonstrate that Amazonian temperatures and water stress are both likely to increase over the 21st Century. Curbing deforestation in the Brazilian Amazon by 62% in 2010 relative to the 1990s mean decreased the Brazilian Amazon's deforestation contribution to global land use carbon emissions from 17% in the 1990s and early 2000s to 9% by 2010. Carbon sources in Amazonia are likely to be dominated by climatic impacts allied with forest fires (48.3% relative contribution) during extreme droughts. The current net carbon sink (net biome productivity, NBP) of +0.16 (ranging from +0.11 to +0.21) Pg C year(-1) in the Brazilian Amazon, equivalent to 13.3% of global carbon emissions from land-use change for 2008, can be negated or reversed during drought years [NBP = -0.06 (-0.31 to +0.01) Pg C year(-1) ]. Therefore, reducing forest fires, in addition to reducing deforestation, would be an important measure for minimizing future emissions. Conversely, doubling the current area of secondary forests and avoiding additional removal of primary forests would help the Amazonian gross forest sink to offset approximately 42% of global land-use change emissions. We conclude that a few strategic environmental policy measures are likely to strengthen the Amazonian net carbon sink with global implications. Moreover, these actions could increase the resilience of the net carbon sink to future increases in drought frequency. © 2014 The Authors. Biological Reviews © 2014 Cambridge Philosophical

  20. Reverse logistics - a framework

    NARCIS (Netherlands)

    M.P. de Brito (Marisa); R. Dekker (Rommert)

    2002-01-01

    textabstractIn this paper we define and compare Reverse Logistics definitions. We start by giving an understanding framework of Reverse Logistics: the why-what-how. By this means, we put in context the driving forces for Reverse Logistics, a typology of return reasons, a classification of

  1. Designing carbon markets, Part II: Carbon markets in space

    International Nuclear Information System (INIS)

    Fankhauser, Samuel; Hepburn, Cameron

    2010-01-01

    This paper analyses the design of carbon markets in space (i.e., geographically). It is part of a twin set of papers that, starting from first principles, ask what an optimal global carbon market would look like by around 2030. Our focus is on firm-level cap-and-trade systems, although much of what we say would also apply to government-level trading and carbon offset schemes. We examine the 'first principles' of spatial design to maximise flexibility and to minimise costs, including key design issues in linking national and regional carbon markets together to create a global carbon market.

  2. Life cycle assessment of offset printed matter with EDIP97

    DEFF Research Database (Denmark)

    Larsen, Henrik Fred; Hansen, Morten Søes; Hauschild, Michael Zwicky

    2009-01-01

    warming, acidification and nutrient enrichment. Ecotoxicity and human toxicity, which are related to emissions of chemicals etc., are only included to a limited degree or not at all. In this paper we include the impacts from chemicals emitted during the life cycle of sheet fed offset printed matter....... This is done by making use of some of the newest knowledge about emissions from the production at the printing industry combined with knowledge about the composition of the printing materials used. In cases with available data also upstream emissions from the production of printing materials are included....... The results show that inclusion of the chemical emission-related impacts makes the EDIP97 impact profile of sheet fed offset products much more varied, as well for the normalised profiles as for the profiles weighted by distance to political environmental targets. Especially the ecotoxicity impact potential...

  3. REAL TIME QUALITY CONTROL OF THE HEATSET OFFSET PRINTING PROCESS

    Directory of Open Access Journals (Sweden)

    Răzvan-George RĂCHERU

    2016-05-01

    Full Text Available Offset lithography is one of the most common ways of creating printed materials. Compared to other printing methods, offset printing is best suited for economically producing large volumes of high quality prints in a manner that requires little maintenance. Because of the high speed and the high volume of the printing press, we have to rely on automation for press control and not just to the printer’s eye. When printing an image that has more than one color, it is necessary to print each color separately and ensure each color overlaps the others precisely. If this is not done, the finished image will look fuzzy, blurred or "out of register". To help line the colors up correctly, a system of registration is necessary. Therefore, the use of an automated real time quality control system will result in a more consistent color for the customer and less waste for the printer.

  4. Axial offset anomalies and local pH

    International Nuclear Information System (INIS)

    Tarin, F.; Montes, M.; Izquierdo, J.; Garcia-Sanchez, J.

    2001-01-01

    Small radial and axial offset anomalies (AOA) in some Spanish PWR-type NPP's, in addition to the knowledge of the existence of similar anomalies in U.S. PWR's, led us in 1993 to study this problem. Important parameters were correlated for a database of plant operating data consisting of six cycles of five different PWR plants (all of them of the Westinghouse 3-loop, 12 ft., 17 x 17 fuel design). One of these cycles (the oldest one) followed the standard constant pH 308 = 7.0, and the remaining ones followed a modified elevated pH control strategy (the pH at EOC is typically 7.4). Only for the oldest cycle that used the standard pH control was the in-core and ex-core axial offset values found to be in good agreement with the predictions, and an anomalous soluble boron curve behavior not observed. (author)

  5. Force-deflection analysis of offset indentations on pressurised pipes

    International Nuclear Information System (INIS)

    Hyde, T.H.; Luo, R.; Becker, A.A.

    2007-01-01

    The indenter force vs. deflection characteristics of pressurised pipes with long offset indentations under plane strain conditions have been investigated using finite element (FE) and analytical methods with four experimental tests performed on aluminium rings. Two different materials and five different geometries were used to investigate their effects on the elastic-plastic behaviour. A comparison of the experimental, FE and the analytical results indicates that the analytical formulation developed in this paper, for predicting the force-deflection curves for pressurised pipes with offset indenters, is reasonably accurate. Also, all of the analyses presented in this paper indicate that by using a representative flow stress, which is defined as the average of the yield and ultimate tensile stresses, the analytical method can accurately predict the force-deflection curves

  6. Offset Free Tracking Predictive Control Based on Dynamic PLS Framework

    Directory of Open Access Journals (Sweden)

    Jin Xin

    2017-10-01

    Full Text Available This paper develops an offset free tracking model predictive control based on a dynamic partial least square (PLS framework. First, state space model is used as the inner model of PLS to describe the dynamic system, where subspace identification method is used to identify the inner model. Based on the obtained model, multiple independent model predictive control (MPC controllers are designed. Due to the decoupling character of PLS, these controllers are running separately, which is suitable for distributed control framework. In addition, the increment of inner model output is considered in the cost function of MPC, which involves integral action in the controller. Hence, the offset free tracking performance is guaranteed. The results of an industry background simulation demonstrate the effectiveness of proposed method.

  7. Optimization based tuning approach for offset free MPC

    DEFF Research Database (Denmark)

    Olesen, Daniel Haugård; Huusom, Jakob Kjøbsted; Jørgensen, John Bagterp

    2012-01-01

    We present an optimization based tuning procedure with certain robustness properties for an offset free Model Predictive Controller (MPC). The MPC is designed for multivariate processes that can be represented by an ARX model. The advantage of ARX model representations is that standard system...... identifiation techniques using convex optimization can be used for identification of such models from input-output data. The stochastic model of the ARX model identified from input-output data is modified with an ARMA model designed as part of the MPC-design procedure to ensure offset-free control. The ARMAX...... model description resulting from the extension can be realized as a state space model in innovation form. The MPC is designed and implemented based on this state space model in innovation form. Expressions for the closed-loop dynamics of the unconstrained system is used to derive the sensitivity...

  8. Automatic WEMVA by Focusing Subsurface Offset Virtual Sources

    KAUST Repository

    Sun, Bingbing

    2017-05-26

    Macro velocity building is important for subsequent prestack depth migration and full waveform inversion. Wave equation migration velocity analysis (WEMVA) utilizes band-limited waveform to invert the velocity in an automatic manner. Normally, inversion would be implemented by focusing the subsurface offset common image gathers(SOCIGs). We re-examine it with a different perspective and propose to view the SOCIGs and the background wavefield together as subsurface offset virtual sources(SOVS). A linear system connecting the perturbation of the position of those SOVS and velocity is derived and solved subsequently using a conjugate gradient method. Both synthetic and real dataset examples verify the correctness and effectiveness of the proposed method.

  9. Coherence between geophysical excitations and celestial pole offsets

    Czech Academy of Sciences Publication Activity Database

    Ron, Cyril; Vondrák, Jan

    2011-01-01

    Roč. 8, č. 3 (2011), s. 243-247 ISSN 1214-9705. [Czech-Polish Workshop on Recent Geodynamics of the Sudeten and Adjacent Areas. Třešť, 04.11.2010-06.11. 2010] R&D Projects: GA ČR GA205/08/0908 Institutional research plan: CEZ:AV0Z10030501 Keywords : geophysical excitations * celestial pole offsets * coherence Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics Impact factor: 0.530, year: 2011

  10. Improved SAR Image Coregistration Using Pixel-Offset Series

    KAUST Repository

    Wang, Teng

    2014-03-14

    Synthetic aperture radar (SAR) image coregistration is a key procedure before interferometric SAR (InSAR) time-series analysis can be started. However, many geophysical data sets suffer from severe decorrelation problems due to a variety of reasons, making precise coregistration a nontrivial task. Here, we present a new strategy that uses a pixel-offset series of detected subimage patches dominated by point-like targets (PTs) to improve SAR image coregistrations. First, all potentially coherent image pairs are coregistered in a conventional way. In this step, we propose a coregistration quality index for each image to rank its relative “significance” within the data set and to select a reference image for the SAR data set. Then, a pixel-offset series of detected PTs is made from amplitude maps to improve the geometrical mapping functions. Finally, all images are resampled depending on the pixel offsets calculated from the updated geometrical mapping functions. We used images from a rural region near the North Anatolian Fault in eastern Turkey to test the proposed method, and clear coregistration improvements were found based on amplitude stability. This enhanced the fact that the coregistration strategy should therefore lead to improved InSAR time-series analysis results.

  11. Improved SAR Image Coregistration Using Pixel-Offset Series

    KAUST Repository

    Wang, Teng; Jonsson, Sigurjon; Hanssen, Ramon F.

    2014-01-01

    Synthetic aperture radar (SAR) image coregistration is a key procedure before interferometric SAR (InSAR) time-series analysis can be started. However, many geophysical data sets suffer from severe decorrelation problems due to a variety of reasons, making precise coregistration a nontrivial task. Here, we present a new strategy that uses a pixel-offset series of detected subimage patches dominated by point-like targets (PTs) to improve SAR image coregistrations. First, all potentially coherent image pairs are coregistered in a conventional way. In this step, we propose a coregistration quality index for each image to rank its relative “significance” within the data set and to select a reference image for the SAR data set. Then, a pixel-offset series of detected PTs is made from amplitude maps to improve the geometrical mapping functions. Finally, all images are resampled depending on the pixel offsets calculated from the updated geometrical mapping functions. We used images from a rural region near the North Anatolian Fault in eastern Turkey to test the proposed method, and clear coregistration improvements were found based on amplitude stability. This enhanced the fact that the coregistration strategy should therefore lead to improved InSAR time-series analysis results.

  12. Multi-offset GPR methods for hyporheic zone investigations

    Science.gov (United States)

    Brosten, T.R.; Bradford, J.H.; McNamara, J.P.; Gooseff, M.N.; Zarnetske, J.P.; Bowden, W.B.; Johnston, M.E.

    2009-01-01

    Porosity of stream sediments has a direct effect on hyporheic exchange patterns and rates. Improved estimates of porosity heterogeneity will yield enhanced simulation of hyporheic exchange processes. Ground-penetrating radar (GPR) velocity measurements are strongly controlled by water content thus accurate measures of GPR velocity in saturated sediments provides estimates of porosity beneath stream channels using petrophysical relationships. Imaging the substream system using surface based reflection measurements is particularly challenging due to large velocity gradients that occur at the transition from open water to saturated sediments. The continuous multi-offset method improves the quality of subsurface images through stacking and provides measurements of vertical and lateral velocity distributions. We applied the continuous multi-offset method to stream sites on the North Slope, Alaska and the Sawtooth Mountains near Boise, Idaho, USA. From the continuous multi-offset data, we measure velocity using reflection tomography then estimate water content and porosity using the Topp equation. These values provide detailed measurements for improved stream channel hydraulic and thermal modelling. ?? 2009 European Association of Geoscientists & Engineers.

  13. Temperature and Voltage Offsets in High-ZT Thermoelectrics

    Science.gov (United States)

    Levy, George S.

    2017-10-01

    Thermodynamic temperature can take on different meanings. Kinetic temperature is an expectation value and a function of the kinetic energy distribution. Statistical temperature is a parameter of the distribution. Kinetic temperature and statistical temperature, identical in Maxwell-Boltzmann statistics, can differ in other statistics such as those of Fermi-Dirac or Bose-Einstein when a field is present. Thermal equilibrium corresponds to zero statistical temperature gradient, not zero kinetic temperature gradient. Since heat carriers in thermoelectrics are fermions, the difference between these two temperatures may explain voltage and temperature offsets observed during meticulous Seebeck measurements in which the temperature-voltage curve does not go through the origin. In conventional semiconductors, temperature offsets produced by fermionic electrical carriers are not observable because they are shorted by heat phonons in the lattice. In high-ZT materials, however, these offsets have been detected but attributed to faulty laboratory procedures. Additional supporting evidence for spontaneous voltages and temperature gradients includes data collected in epistatic experiments and in the plasma Q-machine. Device fabrication guidelines for testing the hypothesis are suggested including using unipolar junctions stacked in a superlattice, alternating n/n + and p/p + junctions, selecting appropriate dimensions, doping, and loading.

  14. Shielding analysis of the IEM cell offset adapter plate

    International Nuclear Information System (INIS)

    Simons, R.L.

    1995-01-01

    The adapter plate for the Interim Examination and Maintenance (IEM) cell ten foot ceiling valve was modified so that the penetration through the valve is offset to the north side of the steel plate. The modifications required that the shielding effectiveness be evaluated for several operating conditions. The highest gamma ray dose rate (51 mrem/hr) occurs when a Core Component Container (CCC) with six high burn-up driver fuel assemblies is transferred into or out of Solid Waste Cask (SWC). The neutron dose rate at the same source location is 2.5 mrem/hr. The total dose rate during the transfer is less than the 200 mrem/hr limit. If the ten foot ceiling valve is closed, the dose rate with twelve DFA in the cell will be less than 0.1 mrem/hr. However, with the ceiling valve open the dose rate will be as high as 12 mrem/hr. The latter condition will require controlled access to the area around the offset adapter plate when the ceiling valve is open. It was found that gaps in the shield block around the SWC floor valve will allow contact dose rates as high as 350 mrem/hr during the transfer of a fully loaded CCC. Although this situation does not pertain to the offset adapter plate, it will require controlled access around the SWC valve during the transfer of a fully loaded CCC

  15. Band offsets in ITO/Ga2O3 heterostructures

    Science.gov (United States)

    Carey, Patrick H.; Ren, F.; Hays, David C.; Gila, B. P.; Pearton, S. J.; Jang, Soohwan; Kuramata, Akito

    2017-11-01

    The valence band offsets in rf-sputtered Indium Tin Oxide (ITO)/single crystal β-Ga2O3 (ITO/Ga2O3) heterostructures were measured with X-Ray Photoelectron Spectroscopy using the Kraut method. The bandgaps of the component materials in the heterostructure were determined by Reflection Electron Energy Loss Spectroscopy as 4.6 eV for Ga2O3 and 3.5 eV for ITO. The valence band offset was determined to be -0.78 ± 0.30 eV, while the conduction band offset was determined to be -0.32 ± 0.13 eV. The ITO/Ga2O3 system has a nested gap (type I) alignment. The use of a thin layer of ITO between a metal and the Ga2O3 is an attractive approach for reducing contact resistance on Ga2O3-based power electronic devices and solar-blind photodetectors.

  16. Temperature and Voltage Offsets in High- ZT Thermoelectrics

    Science.gov (United States)

    Levy, George S.

    2018-06-01

    Thermodynamic temperature can take on different meanings. Kinetic temperature is an expectation value and a function of the kinetic energy distribution. Statistical temperature is a parameter of the distribution. Kinetic temperature and statistical temperature, identical in Maxwell-Boltzmann statistics, can differ in other statistics such as those of Fermi-Dirac or Bose-Einstein when a field is present. Thermal equilibrium corresponds to zero statistical temperature gradient, not zero kinetic temperature gradient. Since heat carriers in thermoelectrics are fermions, the difference between these two temperatures may explain voltage and temperature offsets observed during meticulous Seebeck measurements in which the temperature-voltage curve does not go through the origin. In conventional semiconductors, temperature offsets produced by fermionic electrical carriers are not observable because they are shorted by heat phonons in the lattice. In high- ZT materials, however, these offsets have been detected but attributed to faulty laboratory procedures. Additional supporting evidence for spontaneous voltages and temperature gradients includes data collected in epistatic experiments and in the plasma Q-machine. Device fabrication guidelines for testing the hypothesis are suggested including using unipolar junctions stacked in a superlattice, alternating n/ n + and p/ p + junctions, selecting appropriate dimensions, doping, and loading.

  17. Simulation on Vehicle Vibration Offset of NX70 Flatcar

    Directory of Open Access Journals (Sweden)

    Han Yanhui

    2014-11-01

    Full Text Available The current rolling stock gauge for standard gauge railway is a static gauge to check the vehicle frame. The contradiction of large construction gauge and small rolling stock gauge has always existed. It is important to set down the clearance requirements in respect of physical size for the safe passage of rail vehicles. Reasonably determining the maximum vibration offset can improve the efficiency of clearance. As an example, analyze the complex vibration of NX70 flat car by simulation test on the running track. Comprehensive considering the track model, loading plan, line conditions and running speed, then SIMPACK is used to present the vehicle system dynamics simulation model. After researching simulation result, respectively determine the maximum vehicle vibration offset for railroads of Class I, Class II and Class III on the height of the center of gravity 2000 mm and 2400 mm. According to the clearance between the structure gauge and the position of maximum vibration offset, analyze the safety of vehicle operation since the center of gravity is higher than before.

  18. Tax-Optimal Step-Up and Imperfect Loss Offset

    Directory of Open Access Journals (Sweden)

    Markus Diller

    2012-05-01

    Full Text Available In the field of mergers and acquisitions, German and international tax law allow for several opportunities to step up a firm's assets, i.e., to revaluate the assets at fair market values. When a step-up is performed the taxpayer recognizes a taxable gain, but also obtains tax benefits in the form of higher future depreciation allowances associated with stepping up the tax base of the assets. This tax-planning problem is well known in taxation literature and can also be applied to firm valuation in the presence of taxation. However, the known models usually assume a perfect loss offset. If this assumption is abandoned, the depreciation allowances may lose value as they become tax effective at a later point in time, or even never if there are not enough cash flows to be offset against. This aspect is especiallyrelevant if future cash flows are assumed to be uncertain. This paper shows that a step-up may be disadvantageous or a firm overvalued if these aspects are not integrated into the basic calculus. Compared to the standard approach, assets should be stepped up only in a few cases and - under specific conditions - at a later point in time. Firm values may be considerably lower under imperfect loss offset.

  19. Black-body anomaly: analysis of temperature offsets

    International Nuclear Information System (INIS)

    Szopa, M.; Hofmann, R.; Schwarz, M.; Giacosa, F.

    2008-01-01

    Based on the postulate that photon propagation is governed by a dynamically broken SU(2) gauge symmetry (scale ∝10 -4 eV) we make predictions for temperature offsets due to a low-temperature (a few times the present CMB temperature) spectral anomaly at low frequencies. Temperature offsets are extracted from least-square fits of the anomalous black-body spectra to their conventional counterparts. We discuss statistical errors, compare our results with those obtained from calibration data of the FIRAS instrument, and point out that our predicted offsets are screened by experimental errors given the frequency range used by FIRAS to perform their spectral fits. We also make contact with the WMAP observation by blueshifting their frequency bands. Although our results hint towards a strong dynamical component in the CMB dipole and an explanation of low-l suppression, it is important in view of its particle-physics implications that the above postulate be verified/falsified by an independent low-temperature black-body precision experiment. (orig.)

  20. Estimates of Future Supply of International Greenhouse Gas Offsets: A Critical Review

    Energy Technology Data Exchange (ETDEWEB)

    Erickson, Peter; Lazarus, Michael (Stockholm Environment Inst. (United States)), e-mail: mlaz@sei-us.org; Kelly, Alexia (World Resources Inst., (United States))

    2010-07-01

    This report reviews estimates of the projected availability (i.e., supply) of international offsets, evaluates the various methods used and outlines factors that should be incorporated into future analyses of international offset supply and quality. U.S. policymakers have relied on offsets from developing countries as a primary form of cost containment in proposed cap-and-trade legislation. These legislative proposals allow for emitters to use up to 1.5 billion tons CO{sub 2}e of offsets from developing countries to meet their annual compliance obligations. In this paper, we review estimates of the projected availability (i.e., supply) of international offsets, and evaluate the various methods used. We find that: (1) Estimates of supply of international offsets to global markets vary widely, with estimates differing by billions of tons CO{sub 2}e annually in 2020; (2) Despite the variation, existing studies suggest that by 2020 gross international offset supply will likely exceed U.S. demand for international offsets under current Congressional cap-and-trade designs; (3) Competition with governments and entities with emission reduction obligations (e.g. the EU), as well as with policies and measures undertaken by developing countries as part of their own mitigation contributions, could reduce the net offset supply available to U.S. entities; and (4) Several important offset program design and market factors that are central to future offset markets and credit issuance (e.g., sources of offset supply, program stringency and crediting methods, establishment of international governance and market structures) have yet to be systematically considered in offset supply assessments. This paper outlines factors that should be incorporated into future analyses of international offset supply and quality. 7 Such analyses could prove particularly germane as policy makers continue to deliberate on the role of international offsets, including whether and how to recognize credits

  1. 25 CFR 513.30 - When may the Commission use salary offset to collect debts?

    Science.gov (United States)

    2010-04-01

    ... 25 Indians 2 2010-04-01 2010-04-01 false When may the Commission use salary offset to collect... GENERAL PROVISIONS DEBT COLLECTION Salary Offset § 513.30 When may the Commission use salary offset to... salary offset under the authority of: 5 U.S.C. 5514; 31 U.S.C. 3716; 5 CFR part 550, subpart K; 31 CFR...

  2. Reversible flowchart languages and the structured reversible program theorem

    DEFF Research Database (Denmark)

    Yokoyama, Tetsuo; Axelsen, Holger Bock; Glück, Robert

    2008-01-01

    Many irreversible computation models have reversible counterparts, but these are poorly understood at present. We introduce reversible flowcharts with an assertion operator and show that any reversible flowchart can be simulated by a structured reversible flowchart using only three control flow...... operators. Reversible flowcharts are r- Turing-complete, meaning that they can simuluate reversible Turing machines without garbage data. We also demonstrate the injectivization of classical flowcharts into reversible flowcharts. The reversible flowchart computation model provides a theoretical...

  3. Docking Offset Between the Space Shuttle and the International Space Station and Resulting Impacts to the Transfer of Attitude Reference and Control

    Science.gov (United States)

    Helms, W. Jason; Pohlkamp, Kara M.

    2011-01-01

    The Space Shuttle does not dock at an exact 90 degrees to the International Space Station (ISS) x-body axis. This offset from 90 degrees, along with error sources within their respective attitude knowledge, causes the two vehicles to never completely agree on their attitude, even though they operate as a single, mated stack while docked. The docking offset can be measured in flight when both vehicles have good attitude reference and is a critical component in calculations to transfer attitude reference from one vehicle to another. This paper will describe how the docking offset and attitude reference errors between both vehicles are measured and how this information would be used to recover Shuttle attitude reference from ISS in the event of multiple failures. During STS-117, ISS on-board Guidance, Navigation and Control (GNC) computers began having problems and after several continuous restarts, the systems failed. The failure took the ability for ISS to maintain attitude knowledge. This paper will also demonstrate how with knowledge of the docking offset, the contingency procedure to recover Shuttle attitude reference from ISS was reversed in order to provide ISS an attitude reference from Shuttle. Finally, this paper will show how knowledge of the docking offset can be used to speed up attitude control handovers from Shuttle to ISS momentum management. By taking into account the docking offset, Shuttle can be commanded to hold a more precise attitude which better agrees with the ISS commanded attitude such that start up transients with the ISS momentum management controllers are reduced. By reducing start-up transients, attitude control can be transferred from Shuttle to ISS without the use of ISS thrusters saving precious on-board propellant, crew time and minimizing loads placed upon the mated stack.

  4. 38 CFR 1.990 - Written agreement to repay debt as alternative to salary offset.

    Science.gov (United States)

    2010-07-01

    ... repay debt as alternative to salary offset. 1.990 Section 1.990 Pensions, Bonuses, and Veterans' Relief DEPARTMENT OF VETERANS AFFAIRS GENERAL PROVISIONS Salary Offset Provisions § 1.990 Written agreement to repay debt as alternative to salary offset. (a) Notification by employee. The employee may propose, in...

  5. 41 CFR 105-56.027 - Centralized salary offset computer match.

    Science.gov (United States)

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Centralized salary... Services Administration 56-SALARY OFFSET FOR INDEBTEDNESS OF FEDERAL EMPLOYEES TO THE UNITED STATES Centralized Salary Offset (CSO) Procedures-GSA as Paying Agency § 105-56.027 Centralized salary offset...

  6. 22 CFR 309.18 - Voluntary repayment agreements as an alternative to salary offset.

    Science.gov (United States)

    2010-04-01

    ... to salary offset. 309.18 Section 309.18 Foreign Relations PEACE CORPS DEBT COLLECTION Salary Offset § 309.18 Voluntary repayment agreements as an alternative to salary offset. (a) In response to a notice of intent, an employee may propose a written agreement to repay the debt as an alternative to salary...

  7. 36 CFR 1201.32 - What are NARA's procedures for salary offset?

    Science.gov (United States)

    2010-07-01

    ... for salary offset? 1201.32 Section 1201.32 Parks, Forests, and Public Property NATIONAL ARCHIVES AND RECORDS ADMINISTRATION GENERAL RULES COLLECTION OF CLAIMS Salary Offset § 1201.32 What are NARA's procedures for salary offset? (a) NARA will coordinate salary deductions under this subpart as appropriate...

  8. 40 CFR 13.23 - Salary offset when EPA is not the creditor agency.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 1 2010-07-01 2010-07-01 false Salary offset when EPA is not the... CLAIMS COLLECTION STANDARDS Administrative Offset § 13.23 Salary offset when EPA is not the creditor... period. (4) Unless the employee has consented in writing to the salary deductions or signed a statement...

  9. 24 CFR 17.134 - Procedures for salary offset: when deductions may begin.

    Science.gov (United States)

    2010-04-01

    ... 24 Housing and Urban Development 1 2010-04-01 2010-04-01 false Procedures for salary offset: when deductions may begin. 17.134 Section 17.134 Housing and Urban Development Office of the Secretary, Department... Government Salary Offset Provisions § 17.134 Procedures for salary offset: when deductions may begin. (a...

  10. 5 CFR 1639.28 - Coordinating salary offset with other agencies.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Coordinating salary offset with other... CLAIMS COLLECTION Salary Offset § 1639.28 Coordinating salary offset with other agencies. (a... employee is in the process of separating and has not received a final salary check or other final payment(s...

  11. 20 CFR 361.11 - Procedures for salary offset: When deductions may begin.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 1 2010-04-01 2010-04-01 false Procedures for salary offset: When deductions... § 361.11 Procedures for salary offset: When deductions may begin. (a) Deductions to liquidate an... a debt is completed, offset shall be made from subsequent payments of any nature (e.g., final salary...

  12. 24 CFR 17.133 - Written agreement to repay debt as alternative to salary offset.

    Science.gov (United States)

    2010-04-01

    ... alternative to salary offset. 17.133 Section 17.133 Housing and Urban Development Office of the Secretary... the Government Salary Offset Provisions § 17.133 Written agreement to repay debt as alternative to salary offset. (a) Notification by employee. The employee may propose, in response to a Notice of Intent...

  13. 5 CFR 179.209 - Voluntary repayment agreement as alternative to salary offset.

    Science.gov (United States)

    2010-01-01

    ... alternative to salary offset. 179.209 Section 179.209 Administrative Personnel OFFICE OF PERSONNEL MANAGEMENT CIVIL SERVICE REGULATIONS CLAIMS COLLECTION STANDARDS Salary Offset § 179.209 Voluntary repayment agreement as alternative to salary offset. (a)(1) In response to a notice of intent, an employee may propose...

  14. 12 CFR 1408.41 - Requesting current paying agency to offset salary.

    Science.gov (United States)

    2010-01-01

    ... salary. 1408.41 Section 1408.41 Banks and Banking FARM CREDIT SYSTEM INSURANCE CORPORATION COLLECTION OF CLAIMS OWED THE UNITED STATES Offset Against Salary § 1408.41 Requesting current paying agency to offset salary. (a) To request a paying agency to impose a salary offset against amounts owed to the debtor, the...

  15. 7 CFR 3.83 - Procedures for salary offset: methods of collection.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 1 2010-01-01 2010-01-01 false Procedures for salary offset: methods of collection. 3.83 Section 3.83 Agriculture Office of the Secretary of Agriculture DEBT MANAGEMENT Federal Salary Offset § 3.83 Procedures for salary offset: methods of collection. (a) General. A debt will be collected...

  16. 45 CFR 2506.33 - How will the Corporation coordinate salary offsets with other agencies?

    Science.gov (United States)

    2010-10-01

    ... 45 Public Welfare 4 2010-10-01 2010-10-01 false How will the Corporation coordinate salary offsets... (Continued) CORPORATION FOR NATIONAL AND COMMUNITY SERVICE COLLECTION OF DEBTS Salary Offset § 2506.33 How will the Corporation coordinate salary offsets with other agencies? (a) Responsibilities of the...

  17. 24 CFR 17.137 - Procedures for salary offset: imposition of interest.

    Science.gov (United States)

    2010-04-01

    ... 24 Housing and Urban Development 1 2010-04-01 2010-04-01 false Procedures for salary offset: imposition of interest. 17.137 Section 17.137 Housing and Urban Development Office of the Secretary... the Government Salary Offset Provisions § 17.137 Procedures for salary offset: imposition of interest...

  18. 7 CFR 3.82 - Procedures for salary offset: types of collection.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 1 2010-01-01 2010-01-01 false Procedures for salary offset: types of collection. 3.82 Section 3.82 Agriculture Office of the Secretary of Agriculture DEBT MANAGEMENT Federal Salary Offset § 3.82 Procedures for salary offset: types of collection. A debt will be collected in a lump-sum...

  19. 41 CFR 105-56.017 - Centralized salary offset computer match.

    Science.gov (United States)

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Centralized salary... Services Administration 56-SALARY OFFSET FOR INDEBTEDNESS OF FEDERAL EMPLOYEES TO THE UNITED STATES Centralized Salary Offset (CSO) Procedures-GSA as Creditor Agency § 105-56.017 Centralized salary offset...

  20. 24 CFR 17.136 - Procedures for salary offset: methods of collection.

    Science.gov (United States)

    2010-04-01

    ... 24 Housing and Urban Development 1 2010-04-01 2010-04-01 false Procedures for salary offset: methods of collection. 17.136 Section 17.136 Housing and Urban Development Office of the Secretary... the Government Salary Offset Provisions § 17.136 Procedures for salary offset: methods of collection...

  1. 24 CFR 17.135 - Procedures for salary offset: types of collection.

    Science.gov (United States)

    2010-04-01

    ... 24 Housing and Urban Development 1 2010-04-01 2010-04-01 false Procedures for salary offset: types of collection. 17.135 Section 17.135 Housing and Urban Development Office of the Secretary... the Government Salary Offset Provisions § 17.135 Procedures for salary offset: types of collection. A...

  2. 12 CFR 1704.29 - Coordinating salary offset with other agencies.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 7 2010-01-01 2010-01-01 false Coordinating salary offset with other agencies... HOUSING AND URBAN DEVELOPMENT OFHEO ORGANIZATION AND FUNCTIONS DEBT COLLECTION Salary Offset § 1704.29 Coordinating salary offset with other agencies. (a) Responsibility of OFHEO as the creditor agency. (1) OFHEO...

  3. 38 CFR 1.991 - Procedures for salary offset: when deductions may begin.

    Science.gov (United States)

    2010-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 1 2010-07-01 2010-07-01 false Procedures for salary offset: when deductions may begin. 1.991 Section 1.991 Pensions, Bonuses, and Veterans' Relief DEPARTMENT OF VETERANS AFFAIRS GENERAL PROVISIONS Salary Offset Provisions § 1.991 Procedures for salary offset...

  4. 20 CFR 361.10 - Written agreement to repay debt as alternative to salary offset.

    Science.gov (United States)

    2010-04-01

    ... alternative to salary offset. 361.10 Section 361.10 Employees' Benefits RAILROAD RETIREMENT BOARD INTERNAL... EMPLOYEES § 361.10 Written agreement to repay debt as alternative to salary offset. (a) Notification by... debt as an alternative to salary offset. Any employee who wishes to do this must submit a proposed...

  5. 12 CFR 608.841 - Requesting current paying agency to offset salary.

    Science.gov (United States)

    2010-01-01

    ... salary. 608.841 Section 608.841 Banks and Banking FARM CREDIT ADMINISTRATION ADMINISTRATIVE PROVISIONS COLLECTION OF CLAIMS OWED THE UNITED STATES Offset Against Salary § 608.841 Requesting current paying agency to offset salary. (a) To request a paying agency to impose a salary offset against amounts owed to...

  6. 36 CFR 1201.33 - How will NARA coordinate salary offsets with other agencies?

    Science.gov (United States)

    2010-07-01

    ... salary offsets with other agencies? 1201.33 Section 1201.33 Parks, Forests, and Public Property NATIONAL ARCHIVES AND RECORDS ADMINISTRATION GENERAL RULES COLLECTION OF CLAIMS Salary Offset § 1201.33 How will NARA coordinate salary offsets with other agencies? (a) Responsibilities of NARA as the creditor agency...

  7. 12 CFR 313.46 - Notice of salary offset where FDIC is the paying agency.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 4 2010-01-01 2010-01-01 false Notice of salary offset where FDIC is the... AND RULES OF PRACTICE PROCEDURES FOR CORPORATE DEBT COLLECTION Salary Offset § 313.46 Notice of salary... shall send the employee a written notice of salary offset. Such notice shall advise the employee: (1...

  8. 12 CFR 1704.27 - Notice of salary offset where OFHEO is the paying agency.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 7 2010-01-01 2010-01-01 false Notice of salary offset where OFHEO is the..., DEPARTMENT OF HOUSING AND URBAN DEVELOPMENT OFHEO ORGANIZATION AND FUNCTIONS DEBT COLLECTION Salary Offset § 1704.27 Notice of salary offset where OFHEO is the paying agency. (a) Notice. Upon issuance of a proper...

  9. 7 CFR 400.141 - Internal Revenue Service (IRS) Tax Refund Offset.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 6 2010-01-01 2010-01-01 false Internal Revenue Service (IRS) Tax Refund Offset. 400...-Regulations for the 1986 and Succeeding Crop Years § 400.141 Internal Revenue Service (IRS) Tax Refund Offset... debt owing to any Federal agency by offset against a taxpayer's Federal income tax refund. This section...

  10. Forest disturbance and North American carbon flux

    Science.gov (United States)

    S. N. Goward; J. G. Masek; W. Cohen; G. Moisen; G. J. Collatz; S. Healey; R. A. Houghton; C. Huang; R. Kennedy; B. Law; S. Powell; D. Turner; M. A. Wulder

    2008-01-01

    North America's forests are thought to be a significant sink for atmospheric carbon. Currently, the rate of sequestration by forests on the continent has been estimated at 0.23 petagrams of carbon per year, though the uncertainty about this estimate is nearly 50%. This offsets about 13% of the fossil fuel emissions from the continent [Pacala et al., 2007]. However...

  11. Introduction to reversible computing

    CERN Document Server

    Perumalla, Kalyan S

    2013-01-01

    Few books comprehensively cover the software and programming aspects of reversible computing. Filling this gap, Introduction to Reversible Computing offers an expanded view of the field that includes the traditional energy-motivated hardware viewpoint as well as the emerging application-motivated software approach. Collecting scattered knowledge into one coherent account, the book provides a compendium of both classical and recently developed results on reversible computing. It explores up-and-coming theories, techniques, and tools for the application of rever

  12. Digital Colour Printing on the Way to Offset Quality

    Directory of Open Access Journals (Sweden)

    Andrew Tribute

    2004-12-01

    Full Text Available Digital production colour printing is now more than ten years old. The first implementations of this technology from Indigo and Xeikon started the market but they suffered problems with reliability,quality and overall running costs. They produced a very good-looking printed image but it was notcomparable to offset. Quality problems were that tints often were streaky or banded, flat tints did notreproduce well, and the overall image had a somewhat harsh reflective look.Ongoing developments of digital colour printing mainly from Xerox and Canon developed the marketand improved the economics of the process. Certain elements of the quality also improved. Indigoand Xeikon also showed significant quality improvements and better economics. The improvedquality came closer to the look of offset, but in most cases was still obviously printed digitally.New developments are happening in what is termed "Digital Colour Lite." This is a range of new slower presses coming from Japan which run at around 30 pages/minute and cost well under 50.000 Euro. A few of these are getting almost offset quality through the use of new chemical toners that significantly improve printing quality.At the same time as the quality of digital colour printing has improved, so have the cost economics of running the presses. Potential buyers of presses will have to understand the different business models for running these presses. These are the "click" models from most suppliers, or the pay by usage model as offered by Heidelberg with the NexPress.

  13. Digital Offset Calibration of an OPAMP Towards Improving Static Parameters of 90 nm CMOS DAC

    Directory of Open Access Journals (Sweden)

    D. Arbet

    2014-09-01

    Full Text Available In this paper, an on-chip self-calibrated 8-bit R-2R digital-to-analog converter (DAC based on digitally compensated input offset of the operational amplifier (OPAMP is presented. To improve the overall DAC performance, a digital offset cancellation method was used to compensate deviations in the input offset voltage of the OPAMP caused by process variations. The whole DAC as well as offset compensation circuitry were designed in a standard 90 nm CMOS process. The achieved results show that after the self-calibration process, the improvement of 48% in the value of DAC offset error is achieved.

  14. Evolution of bias field and offset piezoelectric coefficient in bulk lead zirconate titanate with fatigue

    International Nuclear Information System (INIS)

    Zhang Yong; Baturin, Ivan S.; Aulbach, Emil; Lupascu, Doru C.; Kholkin, Andrei L.; Shur, Vladimir Ya.; Roedel, Juergen

    2005-01-01

    Hysteresis loops of the piezoelectric coefficient, d 33 =f(E 3 ), are measured on virgin and fatigued lead zirconate titanate ceramics. Four parameters are directly extracted from the measurements: internal bias field E b , offset piezoelectric coefficient d offset , coercive field E c , and remnant piezoelectric coefficient d r . The reduction in d r displays the decreasing switchable polarization with fatigue cycling. E b and d offset are found to be linearly related. After thermal annealing, both offsets disappear, while the increase in E c and the reduction in d r withstand annealing. The microscopic entities responsible for the offsets are less stable than those for reduced switching

  15. Luminosity Optimization With Offset, Crossing Angle, and Distortion

    CERN Document Server

    Wu, Juhao

    2005-01-01

    In a linear collider, sources of beam jitter due to kicker noise, quadrupole vibration and long-range transverse wakefields will lead to beam offsets and tilts at the Intersection Point (IP). In addition, sources of emittance dilution such as short-range transverse wakefields or dispersive errors will lead to internal beam distortions. When the IP disruption parameter is large, these beam imperfections will be amplified by a single bunch kink instability which will lead to luminosity loss. In this paper, we study the luminosity loss and then the optimization required to cancel the luminosity loss first analytically and then with simulation.

  16. Positron annihilation imaging device using multiple offset rings of detectors

    International Nuclear Information System (INIS)

    Thompson, C.J.

    1982-01-01

    A means is provided for recording more than one tomographic image simultaneously through different cross-sections of a patient, using positron emission tomography. Separate rings of detectors are used to construct every odd-numbered slice, and coincident events that occur between adjacent rings of detectors provide a center or even-numbered slice. Detector rings are offset with respect to one another by half the angular separation of the detectors, allowing an image to be reconstructed from the central slice without the necessity of physically rotating the detector array while accumulating data

  17. Beam-based calibration system of BPM offset on BEPC

    International Nuclear Information System (INIS)

    Hu Chunliang

    2004-01-01

    The ever-increasing demand for better performance from circular accelerators requires improved methods to calibrate beam position monitors (BPM). A beam based calibration system has been established to locate the centers of the BPM with respect to the magnetic center of quadrupole magnets. Additional windings are applied to the quadrupole magnets to make the quadrupole magnetic strength individually adjustable and the number of the power supply of all 32 additional windings is only one. Software system has been finished to automatically measure the offsets of BPMs. The effect of the beam-based calibration system shows that the calibration of BPM has been more quickly and accurately

  18. Using Audio-Derived Affective Offset to Enhance TV Recommendation

    DEFF Research Database (Denmark)

    Shepstone, Sven Ewan; Tan, Zheng-Hua; Jensen, Søren Holdt

    2014-01-01

    . First a user's mood profile is determined using 12-class audio-based emotion classifications . An initial TV content item is then displayed to the user based on the extracted mood profile. The user has the option to either accept the recommendation, or to critique the item once or several times......, by navigating the emotion space to request an alternative match. The final match is then compared to the initial match, in terms of the difference in the items' affective parameterization . This offset is then utilized in future recommendation sessions. The system was evaluated by eliciting three different...

  19. Reversibility of female sterilization.

    Science.gov (United States)

    Siegler, A M; Hulka, J; Peretz, A

    1985-04-01

    The discussion considers the current status of reversibility of sterilization in the US and describes clinical and experimental efforts for developing techniques designed for reversibility. It focuses on regret following sterilization, reversal potential of current sterilization techniques, patient selection, current reversal techniques, results of sterilization procedures, experimental approaches to reversal of current techniques of sterilization, and sterilization procedures devised for reversibility, in humans and in animals. Request is the 1st stage of reversal, but a request for sterilization reversal (SR) does not always mean regret for a decision made at the time. Frequently it is a wish to restore fertility because life circumstances have changed after a sterilization that was ppropriate at the time it was performed. Schwyhart and Kutner reviewed 22 studies published between 1949-69 in which they found that the percentage of patients regretting the procedure ranged from 1.3-15%. Requests for reversal remain low in most countries, but if sterilization becomes a more popular method of contraception, requests will also increase. The ideal operation considered as a reversaible method of sterilization should include an easy, reliable outpatient method of tubal occlusion with miniml risk or patient discomfort that subsequently could be reversed without the need for a major surgical intervention. Endoscopic methods have progressed toward the 1st objective. A recent search of the literature uncovered few series of SR of more than 50 cases. The 767 operations found were analyzed with regard to pregnancy outcome. The precent of live births varied from 74-78.8%, and the occurance of tubal pregnancies ranged from 1.7-6.5%. All of the confounding variables in patient selection and small numbers of reported procedures preclude any conclusion about the different techniques or the number of operations that give a surgeon a level of expertise. Few authors classify their

  20. Designing carbon markets. Part I: Carbon markets in time

    International Nuclear Information System (INIS)

    Fankhauser, Samuel; Hepburn, Cameron

    2010-01-01

    This paper analyses the design of carbon markets in time (i.e., intertemporally). It is part of a twin set of papers that ask, starting from first principles, what an optimal global carbon market would look like by around 2030. Our focus is on firm-level cap-and-trade systems, although much of what we say would also apply to government-level trading and carbon offset schemes. We examine the 'first principles' of temporal design that would help to maximise flexibility and to minimise costs, including banking and borrowing and other mechanisms to provide greater carbon price predictability and credibility over time.

  1. A Computer Simulation of the System-Wide Effects of Parallel-Offset Route Maneuvers

    Science.gov (United States)

    Lauderdale, Todd A.; Santiago, Confesor; Pankok, Carl

    2010-01-01

    Most aircraft managed by air-traffic controllers in the National Airspace System are capable of flying parallel-offset routes. This paper presents the results of two related studies on the effects of increased use of offset routes as a conflict resolution maneuver. The first study analyzes offset routes in the context of all standard resolution types which air-traffic controllers currently use. This study shows that by utilizing parallel-offset route maneuvers, significant system-wide savings in delay due to conflict resolution of up to 30% are possible. It also shows that most offset resolutions replace horizontal-vectoring resolutions. The second study builds on the results of the first and directly compares offset resolutions and standard horizontal-vectoring maneuvers to determine that in-trail conflicts are often more efficiently resolved by offset maneuvers.

  2. Quantum reverse hypercontractivity

    Energy Technology Data Exchange (ETDEWEB)

    Cubitt, Toby [Department of Computer Science, University College London, London, United Kingdom and Centre for Quantum Information and Foundations, DAMTP, University of Cambridge, Cambridge (United Kingdom); Kastoryano, Michael [NBIA, Niels Bohr Institute, University of Copenhagen, 2100 Copenhagen (Denmark); Montanaro, Ashley [School of Mathematics, University of Bristol, Bristol (United Kingdom); Temme, Kristan [Institute for Quantum Information and Matter, California Institute of Technology, Pasadena, California 91125 (United States)

    2015-10-15

    We develop reverse versions of hypercontractive inequalities for quantum channels. By generalizing classical techniques, we prove a reverse hypercontractive inequality for tensor products of qubit depolarizing channels. We apply this to obtain a rapid mixing result for depolarizing noise applied to large subspaces and to prove bounds on a quantum generalization of non-interactive correlation distillation.

  3. Atrioventricular Pacemaker Lead Reversal

    Directory of Open Access Journals (Sweden)

    Mehmet K Aktas, MD

    2007-01-01

    Full Text Available During cardiac surgery temporary epicardial atrial and ventricular leads are placed in case cardiac pacing is required postoperatively. We present the first reported series of patients with reversal of atrioventricular electrodes in the temporary pacemaker without any consequent deleterious hemodynamic effect. We review the electrocardiographic findings and discuss the findings that lead to the discovery of atrioventricular lead reversal.

  4. 36 CFR 1011.10 - How will the Presidio Trust use administrative offset (offset of non-tax federal payments) to...

    Science.gov (United States)

    2010-07-01

    ... 36 Parks, Forests, and Public Property 3 2010-07-01 2010-07-01 false How will the Presidio Trust... Trust Debts § 1011.10 How will the Presidio Trust use administrative offset (offset of non-tax federal...) If not already transferred to the FMS under § 1011.9 of this part, the Presidio Trust will refer any...

  5. Offsetting the impacts of mining to achieve no net loss of native vegetation.

    Science.gov (United States)

    Sonter, L J; Barrett, D J; Soares-Filho, B S

    2014-08-01

    Offsets are a novel conservation tool, yet using them to achieve no net loss of biodiversity is challenging. This is especially true when using conservation offsets (i.e., protected areas) because achieving no net loss requires avoiding equivalent loss. Our objective was to determine if offsetting the impacts of mining achieves no net loss of native vegetation in Brazil's largest iron mining region. We used a land-use change model to simulate deforestation by mining to 2020; developed a model to allocate conservation offsets to the landscape under 3 scenarios (baseline, no new offsets; current practice, like-for-like [by vegetation type] conservation offsetting near the impact site; and threat scenario, like-for-like conservation offsetting of highly threatened vegetation); and simulated nonmining deforestation to 2020 for each scenario to quantify avoided deforestation achieved with offsets. Mines cleared 3570 ha of native vegetation by 2020. Under a 1:4 offset ratio, mining companies would be required to conserve >14,200 ha of native vegetation, doubling the current extent of protected areas in the region. Allocating offsets under current practice avoided deforestation equivalent to 3% of that caused by mining, whereas allocating under the threat scenario avoided 9%. Current practice failed to achieve no net loss because offsets did not conserve threatened vegetation. Explicit allocation of offsets to threatened vegetation also failed because the most threatened vegetation was widely dispersed across the landscape, making conservation logistically difficult. To achieve no net loss with conservation offsets requires information on regional deforestation trajectories and the distribution of threatened vegetation. However, in some regions achieving no net loss through conservation may be impossible. In these cases, other offsetting activities, such as revegetation, will be required. © 2014 Society for Conservation Biology.

  6. Reversible airfoils for stopped rotors in high speed flight

    International Nuclear Information System (INIS)

    Niemiec, Robert; Jacobellis, George; Gandhi, Farhan

    2014-01-01

    This study starts with the design of a reversible airfoil rib for stopped-rotor applications, where the sharp trailing-edge morphs into the rounded leading-edge, and vice-versa. A NACA0012 airfoil is approximated in a piecewise linear manner and straight, rigid outer profile links used to define the airfoil contour. The end points of the profile links connect to control links, each set on a central actuation rod via an offset. Chordwise motion of the actuation rod moves the control and the profile links and reverses the airfoil. The paper describes the design methodology and evolution of the final design, based on which two reversible airfoil ribs were fabricated and used to assemble a finite span reversible rotor/wing demonstrator. The profile links were connected by Aluminum strips running in the spanwise direction which provided stiffness as well as support for a pre-tensioned elastomeric skin. An inter-rib connector with a curved-front nose piece supports the leading-edge. The model functioned well and was able to reverse smoothly back-and-forth, on application and reversal of a voltage to the motor. Navier–Stokes CFD simulations (using the TURNS code) show that the drag coefficient of the reversible airfoil (which had a 13% maximum thickness due to the thickness of the profile links) was comparable to that of the NACA0013 airfoil. The drag of a 16% thick elliptical airfoil was, on average, about twice as large, while that of a NACA0012 in reverse flow was 4–5 times as large, even prior to stall. The maximum lift coefficient of the reversible airfoil was lower than the elliptical airfoil, but higher than the NACA0012 in reverse flow operation. (paper)

  7. Redefining RECs-Part 1: Untangling attributes and offsets

    International Nuclear Information System (INIS)

    Gillenwater, Michael

    2008-01-01

    Renewable energy and greenhouse gas emissions markets are currently in a state of confusion regarding the treatment of Renewable Energy Certificates (RECs). Should consumers buy RECs or emission offsets? After examining this question, the author concludes that RECs are not equivalent to emission offset credits, and as currently defined, the retiring of a REC may have no impact on emissions from electric power generation. Consumers who purchase RECs in voluntary green power markets are providing financial assistance to renewable generators in the form of a production subsidy. Generators that sell RECs are not transferring emission reductions, since they are unlikely to have ownership or the ability to quantify reductions using a commonly accepted standard. More importantly, RECs currently sold in voluntary markets do not pass credible additionality tests and can, at best, be expected to have a market demand effect, which will be less than the supply of RECs on the market. REC definitions that use the term 'environmental attributes' or 'environmental benefits' are almost universally ambiguous, providing the mistaken impression that consumers are purchasing a good instead of subsidizing a public good

  8. Neoclassical offset toroidal velocity and auxiliary ion heating in tokamaks

    Energy Technology Data Exchange (ETDEWEB)

    Lazzaro, E., E-mail: lazzaro@ifp.cnr.it [Istituto di Fisica del Plasma CNR (Italy)

    2016-05-15

    In conditions of ideal axisymmetry, for a magnetized plasma in a generic bounded domain, necessarily toroidal, the uniform absorption of external energy (e.g., RF or any isotropic auxiliary heating) cannot give rise to net forces or torques. Experimental evidence on contemporary tokamaks shows that the near central absorption of RF heating power (ICH and ECH) and current drive in presence of MHD activity drives a bulk plasma rotation in the co-I{sub p} direction, opposite to the initial one. Also the appearance of classical or neoclassical tearing modes provides a nonlinear magnetic braking that tends to clamp the rotation profile at the q-rational surfaces. The physical origin of the torque associated with P{sub RF} absorption could be due the effects of asymmetry in the equilibrium configuration or in power deposition, but here we point out also an effect of the response of the so-called neoclassical offset velocity to the power dependent heat flow increment. The neoclassical toroidal viscosity due to internal magnetic kink or tearing modes tends to relax the plasma rotation to this asymptotic speed, which in absence of auxiliary heating is of the order of the ion diamagnetic velocity. It can be shown by kinetic and fluid calculations, that the absorption of auxiliary power by ions modifies this offset proportionally to the injected power thereby forcing the plasma rotation in a direction opposite to the initial, to large values. The problem is discussed in the frame of the theoretical models of neoclassical toroidal viscosity.

  9. Offset coil designs for superconducting magnets, a logical development

    International Nuclear Information System (INIS)

    Collins, T.

    1986-03-01

    Dipoles and quadrupoles for any new, large proton ring must be stronger, smaller and have better field shape (systematic error) than those used in the Doubler. The present two-shell designs are rigid in that the coils are too thin but cannot be relatively fatter without destroying the field quality. An examination of the coil shapes for dipoles and quadrupoles which produce perfect fields from a uniform current density shows clearly that our persistent use of a circular form for the inner surface of the coils is a poor approximation. When this is corrected by ''offsets'' there is a striking improvement both in the strength of fields and in the field quality. The same analysis makes clear that the efficient use of superconductor and the overall magnet size is determined by the perfect coil shapes. Any reasonable magnet will not differ significantly from the ideal for these parameters. This will be particularly helpful in setting design goals for very large quadrupoles. The offset two-shell dipole design preserves the mechanical features of the highly successful, resilient doubler magnets while greatly extending the performance

  10. Irrigation offsets wheat yield reductions from warming temperatures

    Science.gov (United States)

    Tack, Jesse; Barkley, Andrew; Hendricks, Nathan

    2017-11-01

    Temperature increases due to climate change are expected to cause substantial reductions in global wheat yields. However, uncertainty remains regarding the potential role for irrigation as an adaptation strategy to offset heat impacts. Here we utilize over 7000 observations spanning eleven Kansas field-trial locations, 180 varieties, and 29 years to show that irrigation significantly reduces the negative impact of warming temperatures on winter wheat yields. Dryland wheat yields are estimated to decrease about eight percent for every one-degree Celsius increase in temperature, yet irrigation completely offsets this negative impact in our sample. As in previous studies, we find that important interactions exist between heat stress and precipitation for dryland production. Here, uniquely, we observe both dryland and irrigated trials side-by-side at the same locations and find that precipitation does not provide the same reduction in heat stress as irrigation. This is likely to be because the timing, intensity, and volume of water applications influence wheat yields, so the ability to irrigate—rather than relying on rainfall alone—has a stronger influence on heat stress. We find evidence of extensive differences of water-deficit stress impacts across varieties. This provides some evidence of the potential for adapting to hotter and drier climate conditions using optimal variety selection. Overall, our results highlight the critical role of water management for future global food security. Water scarcity not only reduces crop yields through water-deficit stress, but also amplifies the negative effects of warming temperatures.

  11. Non-Newtonian ink transfer in gravure-offset printing

    International Nuclear Information System (INIS)

    Ghadiri, Fatemeh; Ahmed, Dewan Hasan; Sung, Hyung Jin; Shirani, Ebrahim

    2011-01-01

    The inks used in gravure-offset printing are non-Newtonian fluids with higher viscosities and lower surface tensions than Newtonian fluids. This paper examines the transfer of a non-Newtonian ink between a flat plate and a groove when the plate is moved upward with a constant velocity while the groove is held fixed. Numerical simulations were carried out with the Carreau model to explore the behavior of this non-Newtonian ink in gravure-offset printing. The volume of fluid (VOF) method was implemented to capture the interface during the ink transfer process. The effects of varying the contact angle of the ink on the flat plate and groove walls and geometrical parameters such as the groove angle and the groove depth on the breakup time of the liquid filament that forms between the plate and the groove and the ink transfer ratio were determined. Our results indicate that increasing the groove contact angle and decreasing the flat plate contact angle enhance the ink transfer ratio and the breakup time. However, increasing the groove depth and the groove angle decreases the transfer ratio and the breakup time. By optimizing these parameters, it is possible to achieve an ink transfer from the groove to the flat plate of approximately 92%. Moreover, the initial width and the vertical velocity of the neck of the ink filament have significant influences on the ink transfer ratio and the breakup time.

  12. From coseismic offsets to fault-block mountains

    Science.gov (United States)

    Thompson, George A.; Parsons, Tom

    2017-09-01

    In the Basin and Range extensional province of the western United States, coseismic offsets, under the influence of gravity, display predominantly subsidence of the basin side (fault hanging wall), with comparatively little or no uplift of the mountainside (fault footwall). A few decades later, geodetic measurements [GPS and interferometric synthetic aperture radar (InSAR)] show broad (˜100 km) aseismic uplift symmetrically spanning the fault zone. Finally, after millions of years and hundreds of fault offsets, the mountain blocks display large uplift and tilting over a breadth of only about 10 km. These sparse but robust observations pose a problem in that the coesismic uplifts of the footwall are small and inadequate to raise the mountain blocks. To address this paradox we develop finite-element models subjected to extensional and gravitational forces to study time-varying deformation associated with normal faulting. Stretching the model under gravity demonstrates that asymmetric slip via collapse of the hanging wall is a natural consequence of coseismic deformation. Focused flow in the upper mantle imposed by deformation of the lower crust localizes uplift, which is predicted to take place within one to two decades after each large earthquake. Thus, the best-preserved topographic signature of earthquakes is expected to occur early in the postseismic period.

  13. "3D_Fault_Offsets," a Matlab Code to Automatically Measure Lateral and Vertical Fault Offsets in Topographic Data: Application to San Andreas, Owens Valley, and Hope Faults

    Science.gov (United States)

    Stewart, N.; Gaudemer, Y.; Manighetti, I.; Serreau, L.; Vincendeau, A.; Dominguez, S.; Mattéo, L.; Malavieille, J.

    2018-01-01

    Measuring fault offsets preserved at the ground surface is of primary importance to recover earthquake and long-term slip distributions and understand fault mechanics. The recent explosion of high-resolution topographic data, such as Lidar and photogrammetric digital elevation models, offers an unprecedented opportunity to measure dense collections of fault offsets. We have developed a new Matlab code, 3D_Fault_Offsets, to automate these measurements. In topographic data, 3D_Fault_Offsets mathematically identifies and represents nine of the most prominent geometric characteristics of common sublinear markers along faults (especially strike slip) in 3-D, such as the streambed (minimum elevation), top, free face and base of channel banks or scarps (minimum Laplacian, maximum gradient, and maximum Laplacian), and ridges (maximum elevation). By calculating best fit lines through the nine point clouds on either side of the fault, the code computes the lateral and vertical offsets between the piercing points of these lines onto the fault plane, providing nine lateral and nine vertical offset measures per marker. Through a Monte Carlo approach, the code calculates the total uncertainty on each offset. It then provides tools to statistically analyze the dense collection of measures and to reconstruct the prefaulted marker geometry in the horizontal and vertical planes. We applied 3D_Fault_Offsets to remeasure previously published offsets across 88 markers on the San Andreas, Owens Valley, and Hope faults. We obtained 5,454 lateral and vertical offset measures. These automatic measures compare well to prior ones, field and remote, while their rich record provides new insights on the preservation of fault displacements in the morphology.

  14. Effects of Carrier Frequency Offset, Timing Offset, and Channel Spread Factor on the Performance of Hexagonal Multicarrier Modulation Systems

    Directory of Open Access Journals (Sweden)

    Kui Xu

    2009-01-01

    Full Text Available Hexagonal multicarrier modulation (HMM system is the technique of choice to overcome the impact of time-frequency dispersive transmission channel. This paper examines the effects of insufficient synchronization (carrier frequency offset, timing offset on the amplitude and phase of the demodulated symbol by using a projection receiver in hexagonal multicarrier modulation systems. Furthermore, effects of CFO, TO, and channel spread factor on the performance of signal-to-interference-plus-noise ratio (SINR in hexagonal multicarrier modulation systems are further discussed. The exact SINR expression versus insufficient synchronization and channel spread factor is derived. Theoretical analysis shows that similar degradation on symbol amplitude and phase caused by insufficient synchronization is incurred as in traditional cyclic prefix orthogonal frequency-division multiplexing (CP-OFDM transmission. Our theoretical analysis is confirmed by numerical simulations in a doubly dispersive (DD channel with exponential delay power profile and U-shape Doppler power spectrum, showing that HMM systems outperform traditional CP-OFDM systems with respect to SINR against ISI/ICI caused by insufficient synchronization and doubly dispersive channel.

  15. Multi-analysis and modeling of asymmetry offset for Hall effect structures

    Energy Technology Data Exchange (ETDEWEB)

    Paun, Maria-Alexandra, E-mail: maria_paun2003@yahoo.com

    2017-03-15

    The topological (asymmetry) offset voltage of CMOS cross-like Hall cells is analyzed in this paper. In order to attain the stated objective, different approaches have been considered. Both circuit and three-dimensional models have been developed. Variation of the misalignment offset with the biasing current has been studied through physical and circuit models. The latter is a non-homogenous finite elements model, which relies on using parameterized resistances and current-controlled current sources, of CMOS Hall cells. The displacement offset for various asymmetries and the offset variation with the temperature were investigated through the circuit model developed. Various experimental results for the single and magnetic equivalent offset have also been provided. - Highlights: • In this paper both physical and circuit models have been proposed for the evaluation of Hall cells offset. • Variation of the misalignment offset with the biasing current has been studied. • The displacement offset for various asymmetries and the offset variation with the temperature were investigated. • Various experimental results for single and magnetic equivalent offset were provided. • The obtained simulation results are in accordance with the experimental data.

  16. Utilizing Forest Inventory and Analysis Data, Remote Sensing, and Ecosystem Models for National Forest System Carbon Assessments

    Science.gov (United States)

    Alexa J. Dugan; Richard A. Birdsey; Sean P. Healey; Christopher Woodall; Fangmin Zhang; Jing M. Chen; Alexander Hernandez; James B. McCarter

    2015-01-01

    Forested lands, representing the largest terrestrial carbon sink in the United States, offset 16% of total U.S. carbon dioxide emissions through carbon sequestration. Meanwhile, this carbon sink is threatened by deforestation, climate change and natural disturbances. As a result, U.S. Forest Service policies require that National Forests assess baseline carbon stocks...

  17. Methodology to include a correction for offset in the calibration of a Diode-based 2D verification device; Metodologia para incluir una correccion por offset en la calibracion de un dispositivo de verificacion 2D basado en diodos

    Energy Technology Data Exchange (ETDEWEB)

    Ramirez Ros, J. C.; Pamos Urena, M.; Jerez Sainz, M.; Lobato Munoz, M.; Jodar Lopez, C. A.; Ruiz Lopez, M. a.; Carrasco Rodriguez, J. L.

    2013-07-01

    We propose a methodology to correct doses of device verification 2D MapChek2 planes by offset. This methodology provides an array of correction by Offset applied to the calibration per dose due to the Offset of the diode Central as well as the correction of the Offset of each diode on each acquisition. (Author)

  18. An algebra of reversible computation.

    Science.gov (United States)

    Wang, Yong

    2016-01-01

    We design an axiomatization for reversible computation called reversible ACP (RACP). It has four extendible modules: basic reversible processes algebra, algebra of reversible communicating processes, recursion and abstraction. Just like process algebra ACP in classical computing, RACP can be treated as an axiomatization foundation for reversible computation.

  19. Improved perfusion quantification in FAIR imaging by offset correction

    DEFF Research Database (Denmark)

    Sidaros, Karam; Andersen, Irene Klærke; Gesmar, Henrik

    2001-01-01

    Perfusion quantification using pulsed arterial spin labeling has been shown to be sensitive to the RF pulse slice profiles. Therefore, in Flow-sensitive Alternating-Inversion Recovery (FAIR) imaging the slice selective (ss) inversion slab is usually three to four times thicker than the imaging...... slice. However, this reduces perfusion sensitivity due to the increased transit delay of the incoming blood with unperturbed spins. In the present article, the dependence of the magnetization on the RF pulse slice profiles is inspected both theoretically and experimentally. A perfusion quantification...... model is presented that allows the use of thinner ss inversion slabs by taking into account the offset of RF slice profiles between ss and nonselective inversion slabs. This model was tested in both phantom and human studies. Magn Reson Med 46:193-197, 2001...

  20. Frequency offset estimation in OFDM systems using Bayesian filtering

    Science.gov (United States)

    Yu, Yihua

    2011-10-01

    Orthogonal frequency division multiplexing (OFDM) is sensitive to carrier frequency offset (CFO) that causes inter-carrier interference (ICI). In this paper, we present two schemes for the CFO estimation, which are based on rejection sampling (RS) and a form of particle filtering (PF) called kernel smoothing technique, respectively. The first scheme is offline estimation, where the observations contained in the OFDM training symbol are treated in the batch mode. The second scheme is online estimation, where the observations in the OFDM training symbol are treated in the sequential manner. Simulations are provided to illustrate the performances of the schemes. Performance comparisons of the two schemes and with other Bayesian methods are provided. Simulation results show that the two schemes are effective when estimating the CFO and can effectively combat the effect of ICI in OFDM systems.

  1. Space and the Third Offset Symposium - Summary Report

    Energy Technology Data Exchange (ETDEWEB)

    Bahney, B. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2017-01-05

    The Third Offset Workshop explored the nature of the challenges and opportunities facing the United States as it is increasingly forced to integrate space into defense strategy as well as deterrence and strategic stability frameworks. Participants broadly agreed that Washington’s deep ties to allies and partners, as well as its history of leveraging an innovative U.S private sector, will be enduring competitive advantages against potential rivals into the foreseeable future. Yet panelists also highlighted key challenges from Russia and China’s rapid integration of space capabilities into conventional and nuclear warfighting, the pronounced growth in Chinese and Russian counterspace capabilities, and tensions in the U.S.-Russia relationship.

  2. Application of electron beam curing in web-offset printing

    International Nuclear Information System (INIS)

    Rodrigues, A.M.; Newcomb, W.T.

    1984-01-01

    Four years ago, the first commercial installation of an electron beam processor, coupled with a high speed web offset printing press was described. This line has been in operation since and its success demonstrates the advantages and feasibility of such an application. Just recently, another company has announced that it is using electron beam curing in its printing lines. Judging from the amount of inquiries and opportunities being actively pursued one can state that the use of electron beam systems in printing applications has come of age. This paper describes the advantages of this process, the characteristics of the equipment that are important for industrial use in a multishift environment, and addresses its economics through analysis of some major cost elements

  3. Direct benefits of choosing a high-fitness mate can offset the indirect costs associated with intralocus sexual conflict.

    Science.gov (United States)

    Pischedda, Alison; Chippindale, Adam K

    2017-06-01

    Intralocus sexual conflict generates a cost to mate choice: high-fitness partners transmit genetic variation that confers lower fitness to offspring of the opposite sex. Our earlier work in the fruit fly, Drosophila melanogaster, revealed that these indirect genetic costs were sufficient to reverse potential "good genes" benefits of sexual selection. However, mate choice can also confer direct fitness benefits by inducing larger numbers of progeny. Here, we consider whether direct benefits through enhanced fertility could offset the costs associated with intralocus sexual conflict in D. melanogaster. Using hemiclonal analysis, we found that females mated to high-fitness males produced 11% more offspring compared to those mated to low-fitness males, and high-fitness females produced 34% more offspring than low-fitness females. These direct benefits more than offset the reduction in offspring fitness caused by intralocus sexual conflict, creating a net fitness benefit for each sex to pairing with a high-fitness partner. Our findings highlight the need to consider both direct and indirect effects when investigating the fitness impacts of mate choice. Direct fitness benefits may shelter sexually antagonistic alleles from selection, suggesting a novel mechanism for the maintenance of fitness variation. © 2017 The Author(s). Evolution © 2017 The Society for the Study of Evolution.

  4. Phase Offsets and the Energy Budgets of Hot Jupiters

    Science.gov (United States)

    Schwartz, Joel C.; Kashner, Zane; Jovmir, Diana; Cowan, Nicolas B.

    2017-12-01

    Thermal phase curves of short-period planets on circular orbits provide joint constraints on the fraction of incoming energy that is reflected (Bond albedo) and the fraction of absorbed energy radiated by the night hemisphere (heat recirculation efficiency). Many empirical studies of hot Jupiters have implicitly assumed that the dayside is the hottest hemisphere and the nightside is the coldest hemisphere. For a given eclipse depth and phase amplitude, an orbital lag between a planet’s peak brightness and its eclipse—a phase offset—implies that planet’s nightside emits greater flux. To quantify how phase offsets impact the energy budgets of short-period planets, we compile all infrared observations of the nine planets with multi-band eclipse depths and phase curves. Accounting for phase offsets shifts planets to lower Bond albedo and greater day-night heat transport, usually by ≲1σ. For WASP-12b, the published phase variations have been analyzed in two different ways, and the inferred energy budget depends sensitively on which analysis one adopts. Our fiducial scenario supports a Bond albedo of {0.27}-0.13+0.12, significantly higher than the published optical geometric albedo, and a recirculation efficiency of {0.03}-0.02+0.07, following the trend of larger day-night temperature contrast with greater stellar irradiation. If instead we adopt the alternative analysis, then WASP-12b has a Bond albedo consistent with zero and a much higher recirculation efficiency. To definitively determine the energy budget of WASP-12b, new observational analyses will be necessary.

  5. Sex reversal in vertebrates

    OpenAIRE

    2016-01-01

    This special topic issue of Sexual Development gives an overview of sex reversal in vertebrates, from fishes naturally changing their sex, to rodents escaping the mammalian SRY-determining system. It offers eight up-to-date reviews on specific subjects in sex reversal, considering fishes, amphibians, reptiles, birds, marsupials, and placental mammals, including humans. The broad scope of represented animals makes this ideal for students and researchers, especially those interested in the...

  6. Family forest owners in the redwood region: management priorities and opportunities in a carbon market

    Science.gov (United States)

    Erin Clover Kelly; Joanna Di Tommaso; Arielle Weisgrau

    2017-01-01

    California’s cap-and-trade carbon market has included forest offset projects, available to all private landowners across the United States. The redwood region has been at the forefront of the market, creating the earliest forest carbon projects. From carbon registries, we compiled a database of all forest carbon projects in the market, in order to determine...

  7. What Issues Does the Czech Republic Face Concerning Offsets in the Context of Military Purchases?

    Science.gov (United States)

    2006-09-01

    of CZK 19.650 billion; approximately USD 0.9 billion)1. Countertrade is an immense, pervasive business practice, involving huge numbers of people...overwhelmed with various terms: direct and indirect offsets, countertrade , bilateral government trade, compensatory arrangements, clearing arrangements...34Coproduction, Barter, and Countertrade : Offsets in the International Arms Market," (Orbis, 1985), 29. 8 1. The Meaning of Offsets, Definitions and

  8. Echoic Memory: Investigation of Its Temporal Resolution by Auditory Offset Cortical Responses

    OpenAIRE

    Nishihara, Makoto; Inui, Koji; Morita, Tomoyo; Kodaira, Minori; Mochizuki, Hideki; Otsuru, Naofumi; Motomura, Eishi; Ushida, Takahiro; Kakigi, Ryusuke

    2014-01-01

    Previous studies showed that the amplitude and latency of the auditory offset cortical response depended on the history of the sound, which implicated the involvement of echoic memory in shaping a response. When a brief sound was repeated, the latency of the offset response depended precisely on the frequency of the repeat, indicating that the brain recognized the timing of the offset by using information on the repeat frequency stored in memory. In the present study, we investigated the temp...

  9. Demonstrating biodiversity offset policy outcomes using the classic "trading in a pit market" classroom game

    DEFF Research Database (Denmark)

    Bull, Joseph William; Strange, Niels

    2017-01-01

    , and subsequently, the provision of full ecological compensation measures elsewhere by the associated developer, e. g., habitat restoration. The objective is no net loss of biodiversity overall. Here, we develop an offset experiment in the style of a classic economic game (‘trading in a pit market’), which can...... the experiment, with and without a hypothetical biodiversity offset policy in place, revealed some key principles around offsetting which have been noted in real world policy outcomes....

  10. A SURVEY OF AUTOMATION TECHNIQUES COMING FORTH IN SHEET-FED OFFSET PRINTING ORGANIZATIONS

    OpenAIRE

    Mr. Ramesh Kumar*, Mr. Bijender & Mr. Sandeep Boora

    2017-01-01

    Sheet-Fed offset is one of the premier processes in India as well as abroad. To cope up with customers large quantity demands automation has become mandatory. From prepress to post press a wide range of automation techniques exist and coming forth for sheet fed offset presses. Objective of this paper is to throw light on various sheet-fed offset automation techniques existing today and their futuristic implications. The data related to automation was collected with the help of survey conducte...

  11. On thermodynamic and microscopic reversibility

    International Nuclear Information System (INIS)

    Crooks, Gavin E

    2011-01-01

    The word 'reversible' has two (apparently) distinct applications in statistical thermodynamics. A thermodynamically reversible process indicates an experimental protocol for which the entropy change is zero, whereas the principle of microscopic reversibility asserts that the probability of any trajectory of a system through phase space equals that of the time reversed trajectory. However, these two terms are actually synonymous: a thermodynamically reversible process is microscopically reversible, and vice versa

  12. Accounting for Uncertainty and Time Lags in Equivalency Calculations for Offsetting in Aquatic Resources Management Programs

    Science.gov (United States)

    Bradford, Michael J.

    2017-10-01

    Biodiversity offset programs attempt to minimize unavoidable environmental impacts of anthropogenic activities by requiring offsetting measures in sufficient quantity to counterbalance losses due to the activity. Multipliers, or offsetting ratios, have been used to increase the amount of offsets to account for uncertainty but those ratios have generally been derived from theoretical or ad-hoc considerations. I analyzed uncertainty in the offsetting process in the context of offsetting for impacts to freshwater fisheries productivity. For aquatic habitats I demonstrate that an empirical risk-based approach for evaluating prediction uncertainty is feasible, and if data are available appropriate adjustments to offset requirements can be estimated. For two data-rich examples I estimate multipliers in the range of 1.5:1 - 2.5:1 are sufficient to account for the uncertainty in the prediction of gains and losses. For aquatic habitats adjustments for time delays in the delivery of offset benefits can also be calculated and are likely smaller than those for prediction uncertainty. However, the success of a biodiversity offsetting program will also depend on the management of the other components of risk not addressed by these adjustments.

  13. Correlation between centre offsets and gas velocity dispersion of galaxy clusters in cosmological simulations

    Science.gov (United States)

    Li, Ming-Hua; Zhu, Weishan; Zhao, Dong

    2018-05-01

    The gas is the dominant component of baryonic matter in most galaxy groups and clusters. The spatial offsets of gas centre from the halo centre could be an indicator of the dynamical state of cluster. Knowledge of such offsets is important for estimate the uncertainties when using clusters as cosmological probes. In this paper, we study the centre offsets roff between the gas and that of all the matter within halo systems in ΛCDM cosmological hydrodynamic simulations. We focus on two kinds of centre offsets: one is the three-dimensional PB offsets between the gravitational potential minimum of the entire halo and the barycentre of the ICM, and the other is the two-dimensional PX offsets between the potential minimum of the halo and the iterative centroid of the projected synthetic X-ray emission of the halo. Haloes at higher redshifts tend to have larger values of rescaled offsets roff/r200 and larger gas velocity dispersion σ v^gas/σ _{200}. For both types of offsets, we find that the correlation between the rescaled centre offsets roff/r200 and the rescaled 3D gas velocity dispersion, σ _v^gas/σ _{200} can be approximately described by a quadratic function as r_{off}/r_{200} ∝ (σ v^gas/σ _{200} - k_2)2. A Bayesian analysis with MCMC method is employed to estimate the model parameters. Dependence of the correlation relation on redshifts and the gas mass fraction are also investigated.

  14. Possible Correlations between the Emission Properties of SGRBs and Their Offsets from the Host Galaxies

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Shuai; Jin, Zhi-Ping; Li, Xiang; Fan, Yi-Zhong; Wei, Da-Ming [Key Laboratory of Dark Matter and Space Astronomy, Purple Mountain Observatory, Chinese Academy of Sciences, Nanjing, 210008 (China); Zhang, Fu-Wen, E-mail: jin@pmo.ac.cn, E-mail: yzfan@pmo.ac.cn, E-mail: dmwei@pmo.ac.cn [College of Science, Guilin University of Technology, Guilin 541004 (China)

    2017-07-20

    Short gamma-ray bursts (SGRBs) are widely believed to be from mergers of binary compact objects involving at least one neutron star and hence have a broad range of spatial offsets from their host galaxies. In this work, we search for possible correlations between the emission properties of 18 SGRBs and their offsets from the host galaxies. The SGRBs with and without extended emission do not show significant differences between their offset distributions, in agreement with some previous works. There are, however, possible correlations between the optical and X-ray afterglow emission and the offsets. The underlying physical origins are examined.

  15. Accounting for Uncertainty and Time Lags in Equivalency Calculations for Offsetting in Aquatic Resources Management Programs.

    Science.gov (United States)

    Bradford, Michael J

    2017-10-01

    Biodiversity offset programs attempt to minimize unavoidable environmental impacts of anthropogenic activities by requiring offsetting measures in sufficient quantity to counterbalance losses due to the activity. Multipliers, or offsetting ratios, have been used to increase the amount of offsets to account for uncertainty but those ratios have generally been derived from theoretical or ad-hoc considerations. I analyzed uncertainty in the offsetting process in the context of offsetting for impacts to freshwater fisheries productivity. For aquatic habitats I demonstrate that an empirical risk-based approach for evaluating prediction uncertainty is feasible, and if data are available appropriate adjustments to offset requirements can be estimated. For two data-rich examples I estimate multipliers in the range of 1.5:1 - 2.5:1 are sufficient to account for the uncertainty in the prediction of gains and losses. For aquatic habitats adjustments for time delays in the delivery of offset benefits can also be calculated and are likely smaller than those for prediction uncertainty. However, the success of a biodiversity offsetting program will also depend on the management of the other components of risk not addressed by these adjustments.

  16. [Review of lime carbon sink.

    Science.gov (United States)

    Liu, Li Li; Ling, Jiang Hua; Tie, Li; Wang, Jiao Yue; Bing, Long Fei; Xi, Feng Ming

    2018-01-01

    Under the background of "missing carbon sink" mystery and carbon capture and storage (CCS) technology development, this paper summarized the lime material flow process carbon sink from the lime carbonation principles, impact factors, and lime utilization categories in chemical industry, metallurgy industry, construction industry, and lime kiln ash treatment. The results showed that the lime carbonation rate coefficients were mainly impacted by materials and ambient conditions; the lime carbon sink was mainly in chemical, metallurgy, and construction industries; and current researches focused on the mechanisms and impact factors for carbonation, but their carbon sequestration calculation methods had not been proposed. Therefore, future research should focus on following aspects: to establish a complete system of lime carbon sequestration accounting method in view of material flow; to calculate lime carbon sequestration in both China and the world and explain their offset proportion of CO 2 emission from lime industrial process; to analyze the contribution of lime carbon sequestration to missing carbon sink for clarifying part of missing carbon sinks; to promote the development of carbon capture and storage technology and provide some scientific bases for China's international negotiations on climate change.

  17. Reversible Communicating Processes

    Directory of Open Access Journals (Sweden)

    Geoffrey Brown

    2016-02-01

    Full Text Available Reversible distributed programs have the ability to abort unproductive computation paths and backtrack, while unwinding communication that occurred in the aborted paths. While it is natural to assume that reversibility implies full state recovery (as with traditional roll-back recovery protocols, an interesting alternative is to separate backtracking from local state recovery. For example, such a model could be used to create complex transactions out of nested compensable transactions where a programmer-supplied compensation defines the work required to "unwind" a transaction. Reversible distributed computing has received considerable theoretical attention, but little reduction to practice; the few published implementations of languages supporting reversibility depend upon a high degree of central control. The objective of this paper is to demonstrate that a practical reversible distributed language can be efficiently implemented in a fully distributed manner. We discuss such a language, supporting CSP-style synchronous communication, embedded in Scala. While this language provided the motivation for the work described in this paper, our focus is upon the distributed implementation. In particular, we demonstrate that a "high-level" semantic model can be implemented using a simple point-to-point protocol.

  18. Substantial global carbon uptake by cement carbonation

    OpenAIRE

    Xi, Fengming; Davis, Steven J.; Ciais, Philippe; Crawford-Brown, Douglas; Guan, Dabo; Pade, Claus; Shi, Tiemao; Syddall, Mark; Lv, Jie; Ji, Lanzhu; Bing, Longfei; Wang, Jiaoyue; Wei, Wei; Yang, Keun-Hyeok; Lagerblad, Björn

    2016-01-01

    Calcination of carbonate rocks during the manufacture of cement produced 5% of global CO2 emissions from all industrial process and fossil-fuel combustion in 20131, 2. Considerable attention has been paid to quantifying these industrial process emissions from cement production2, 3, but the natural reversal of the process—carbonation—has received little attention in carbon cycle studies. Here, we use new and existing data on cement materials during cement service life, demolition, and secondar...

  19. Global Cr-isotope distributions in surface seawater and incorporation of Cr isotopes into carbonate shells

    DEFF Research Database (Denmark)

    Paulukat, Cora Stefanie; Frei, Robert; Vögelin, Andrea Regula

    produced carbonate shells (bivalves, gastropods) and corals. Our preliminary data set ranges approximately from d53Cr = -0.2 to +0.7‰. They are isotopically lighter than local seawater. This is in good agreement with [6], who measured a negative offset from seawater in corals. These offsets indicate some...

  20. Freshwater reservoir offsets and food crusts: Isotope, AMS, and lipid analyses of experimental cooking residues

    Science.gov (United States)

    Taché, Karine; Lovis, William A.

    2018-01-01

    Freshwater reservoir offsets (FROs) occur when AMS dates on charred, encrusted food residues on pottery predate a pot’s chronological context because of the presence of ancient carbon from aquatic resources such as fish. Research over the past two decades has demonstrated that FROs vary widely within and between water bodies and between fish in those water bodies. Lipid analyses have identified aquatic biomarkers that can be extracted from cooking residues as potential evidence for FROs. However, lacking has been efforts to determine empirically how much fish with FROs needs to be cooked in a pot with other resources to result in significant FRO on encrusted cooking residue and what percentage of fish C in a residue is needed to result in the recovery of aquatic biomarkers. Here we provide preliminary assessments of both issues. Our results indicate that in historically-contingent, high alkalinity environments fish may result in a statistically significant FRO, but that biomarkers for aquatic resources may be present in the absence of a significant FRO. PMID:29694436

  1. Attention capture by contour onsets and offsets: no special role for onsets.

    Science.gov (United States)

    Watson, D G; Humphreys, G W

    1995-07-01

    In five experiments, we investigated the power of targets defined by the onset or offset of one of an object's parts (contour onsets and offsets) either to guide or to capture visual attention. In Experiment 1, search for a single contour onset target was compared with search for a single contour offset target against a static background of distractors; no difference was found between the efficiency with which each could be detected. In Experiment 2, onsets and offsets were compared for automatic attention capture, when both occurred simultaneously. Unlike in previous studies, the effects of overall luminance change, new-object creation, and number of onset and offset items were controlled. It was found that contour onset and offset items captured attention equally well. However, display size effects on both target types were also apparent. Such effects may have been due to competition for selection between multiple onset and offset stimuli. In Experiments 3 and 4, single onset and offset stimuli were presented simultaneously and pitted directly against one another among a background of static distractors. In Experiment 3, we examined "guided search," for a target that was formed either from an onset or from an offset among static items. In Experiment 4, the onsets and offsets were uncorrelated with the target location. Similar results occurred in both experiments: target onsets and offsets were detected more efficiently than static stimuli which needed serial search; there remained effects of display size on performance; but there was still no advantage for onsets. In Experiment 5, we examined automatic attention capture by single onset and offset stimuli presented individually among static distractors. Again, there was no advantage for onset over offset targets and a display size effect was also present. These results suggest that, both in isolation and in competition, onsets that do not form new objects neither guide nor gain automatic attention more efficiently

  2. The Binary Offset Effect in CCDs: an Anomalous Readout Artifact Affecting Most Astronomical CCDs in Use

    Science.gov (United States)

    Boone, Kyle Robert; Aldering, Gregory; Copin, Yannick; Dixon, Samantha; Domagalski, Rachel; Gangler, Emmanuel; Pecontal, Emmanuel; Perlmutter, Saul; Nearby Supernova Factory Collaboration

    2018-01-01

    We discovered an anomalous behavior of CCD readout electronics that affects their use in many astronomical applications, which we call the “binary offset effect”. Due to feedback in the readout electronics, an offset is introduced in the values read out for each pixel that depends on the binary encoding of the previously read-out pixel values. One consequence of this effect is that a pathological local background offset can be introduced in images that only appears where science data are present on the CCD. The amplitude of this introduced offset does not scale monotonically with the amplitude of the objects in the image, and can be up to 4.5 ADU per pixel for certain instruments. Additionally, this background offset will be shifted by several pixels from the science data, potentially distorting the shape of objects in the image. We tested 22 instruments for signs of the binary offset effect and found evidence of it in 16 of them, including LRIS and DEIMOS on the Keck telescopes, WFC3-UVIS and STIS on HST, MegaCam on CFHT, SNIFS on the UH88 telescope, GMOS on the Gemini telescopes, HSC on Subaru, and FORS on VLT. A large amount of archival data is therefore affected by the binary offset effect, and conventional methods of reducing CCD images do not measure or remove the introduced offsets. As a demonstration of how to correct for the binary offset effect, we have developed a model that can accurately predict and remove the introduced offsets for the SNIFS instrument on the UH88 telescope. Accounting for the binary offset effect is essential for precision low-count astronomical observations with CCDs.

  3. Economic impact of reversion

    International Nuclear Information System (INIS)

    2005-01-01

    Estimations of the Norwegian hydropower production and various reversion models' market value have been made. The value of the Norwegian hydropower production until 01.01.2007 is estimated to about Nok 289 billion after taxes, or about 2,42 Nok/kWh medium production, given an expected future electricity price of around 0,25 Nok/kWh and a discount rate at 6,5 percent in nominal terms after taxes. The estimate is slightly above the level of prices for Norwegian hydropower plants in the last 8-10 years. The value of reversion in private plants which today have a limited licence time is estimated to Nok 5,5 billion. The value of reversion in public-owned Norwegian hydropower plants are about Nok 21 billion with a 60 year licence period from 01.01.2007, and about 12 billion for 75 years (ml)

  4. Reversible deep disposal

    International Nuclear Information System (INIS)

    2009-10-01

    This presentation, given by the national agency of radioactive waste management (ANDRA) at the meeting of October 8, 2009 of the high committee for the nuclear safety transparency and information (HCTISN), describes the concept of deep reversible disposal for high level/long living radioactive wastes, as considered by the ANDRA in the framework of the program law of June 28, 2006 about the sustainable management of radioactive materials and wastes. The document presents the social and political reasons of reversibility, the technical means considered (containers, disposal cavities, monitoring system, test facilities and industrial prototypes), the decisional process (progressive development and blocked off of the facility, public information and debate). (J.S.)

  5. Spatial Offsets in Flare-CME Current Sheets

    Energy Technology Data Exchange (ETDEWEB)

    Raymond, John C. [Harvard-Smithsonian Center for Astrophysics, 60 Garden St., Cambridge, MA 02138 (United States); Giordano, Silvio [INAF-Osservatorio Astrofisico di Torino, via Osservatorio 20, I-10025 Pino Torinese (Italy); Ciaravella, Angela, E-mail: jraymond@cfa.harvard.edu [INAF-Osservatorio Astronomico di Palermo, P.za Parlamento 1, I-90134 Palermo (Italy)

    2017-07-10

    Magnetic reconnection plays an integral part in nearly all models of solar flares and coronal mass ejections (CMEs). The reconnection heats and accelerates the plasma, produces energetic electrons and ions, and changes the magnetic topology to form magnetic flux ropes and to allow CMEs to escape. Structures that appear between flare loops and CME cores in optical, UV, EUV, and X-ray observations have been identified as current sheets and have been interpreted in terms of the nature of the reconnection process and the energetics of the events. Many of these studies have used UV spectral observations of high temperature emission features in the [Fe xviii] and Si xii lines. In this paper, we discuss several surprising cases in which the [Fe xviii] and Si xii emission peaks are spatially offset from each other. We discuss interpretations based on asymmetric reconnection, on a thin reconnection region within a broader streamer-like structure, and on projection effects. Some events seem to be easily interpreted as the projection of a sheet that is extended along the line of sight that is viewed an angle, but a physical interpretation in terms of asymmetric reconnection is also plausible. Other events favor an interpretation as a thin current sheet embedded in a streamer-like structure.

  6. MSK and offset QPSK modulation with bandlimiting filters

    Science.gov (United States)

    Prabhu, V. K.

    1981-01-01

    It is considered by some that minimum shift keying (MSK) is spectrally more efficient than quaternary phase-shift keying/offset quadrature phase-shift keying (QPSK/OQPSK). An analytical method is presented here for determining the detection efficiencies of MSK and QPSK/OQPSK when the constant-envelope signal is passed through a set of filters and when the resulting signal is corrupted by Gaussian noise. The detection efficiency of MSK is compared with that of QPSK/OQPSK when a four-pole Butterworth filter is used as a transmit filter and for two different receive filter functions. When the two-sided 3-dB bandwidth of the transmit filter is between approximately 1.00/T and 1.50/T, it is shown that the detection efficiency of MSK is not substantially different from that of QPSK/OQPSK. For more severe bandlimiting of the signal, the performance of MSK is shown to be inferior to that of QPSK/OQPSK. It is, therefore, concluded that MSK does not have significantly better detection efficiency when the effect of bandlimiting filters is taken into account.

  7. Offsetting deficit conceptualisations: methodological considerations for higher education research

    Directory of Open Access Journals (Sweden)

    Lynn Coleman

    2016-06-01

    Full Text Available This paper contributes to the current introspection in the academic development community that critiques the persistent conceptualisations of students as deficient. Deficit discourses are also implicated in many of the student support, curriculum and pedagogic initiatives employed across the higher education sector. The argument developed here, unlike most of the existing debates which focus on pedagogic or institutional initiatives, explores how the research interests and methodological choices of academic developers and researchers could incorporate sensitivity against deficit conceptions and foster more contextualised accounts of students and their learning. This article uses an ethnographic study into the assignment practices of vocational higher education students to show how certain methodological and theoretical choices engender anti-deficit conceptualisations. The study’s analytic framework uses the concepts of literacy practices and knowledge recontextualisation to place analytic attention on both the students’ assignment practices and the influence of curriculum decision making on such practices. The significance of this dual focus is its ability to capture the complexity of students’ meaning-making during assignment production, without remaining silent about the structuring influence of the curriculum. I argue in this paper that the focus on both students and curriculum is able to offer contextualised accounts of students’ interpretations and enacted experiences of their assessment and curriculum environment. Exploring the multidimensional nature of student learning experiences in ways that accommodate the influence of various contextual realities brings researchers and their research agendas closer to offsetting deficit conceptualisation.

  8. Offset linear scaling for H-mode confinement

    International Nuclear Information System (INIS)

    Miura, Yukitoshi; Tamai, Hiroshi; Suzuki, Norio; Mori, Masahiro; Matsuda, Toshiaki; Maeda, Hikosuke; Takizuka, Tomonori; Itoh, Sanae; Itoh, Kimitaka.

    1992-01-01

    An offset linear scaling for the H-mode confinement time is examined based on single parameter scans on the JFT-2M experiment. Regression study is done for various devices with open divertor configuration such as JET, DIII-D, JFT-2M. The scaling law of the thermal energy is given in the MKSA unit as W th =0.0046R 1.9 I P 1.1 B T 0.91 √A+2.9x10 -8 I P 1.0 R 0.87 P√AP, where R is the major radius, I P is the plasma current, B T is the toroidal magnetic field, A is the average mass number of plasma and neutral beam particles, and P is the heating power. This fitting has a similar root mean square error (RMSE) compared to the power law scaling. The result is also compared with the H-mode in other configurations. The W th of closed divertor H-mode on ASDEX shows a little better values than that of open divertor H-mode. (author)

  9. Offset project report : Cleanit Greenit aerobic composting project

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-02-15

    The Cleanit Greenit site is owned and operated by Cleanit Greenit Composting System Inc. and is a composting facility located in Edmonton, Alberta. The facility has an annual processing capacity of 20,000 tonnes of organic waste and was the first in Canada to compost a large variety of industrial by-products containing hydrocarbons, through controlled blending with other wastes and monitoring of moisture, temperature and pH. The composting process turns organic waste material from industrial, commercial and domestic sources into finished projects, thus removing these materials from conditions where treatment and disposal is often difficult, expensive and environmentally harmful. This protocol document covered the diversion of organic residues from landfill for biological decomposition to a condition sufficiently stable for nuisance-free storage and for safe use in land application. A wide variety of organic residues were considered, including agricultural and agri-food residues; the organic portion of municipal solid waste; food wastes; and forestry and landscaping wastes. The document presented information on the Cleanit Greenit project and discussed the calculation of greenhouse gas emission reductions. An appendix that contained the Cleanit Greenit aerobic composting offset project plan was also provided. tabs., figs.

  10. 20 CFR 361.13 - Procedures for salary offset: Methods of collection.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 1 2010-04-01 2010-04-01 false Procedures for salary offset: Methods of collection. 361.13 Section 361.13 Employees' Benefits RAILROAD RETIREMENT BOARD INTERNAL ADMINISTRATION... § 361.13 Procedures for salary offset: Methods of collection. (a) General. A debt will be collected by...

  11. 20 CFR 361.12 - Procedures for salary offset: Types of collection.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 1 2010-04-01 2010-04-01 false Procedures for salary offset: Types of collection. 361.12 Section 361.12 Employees' Benefits RAILROAD RETIREMENT BOARD INTERNAL ADMINISTRATION... § 361.12 Procedures for salary offset: Types of collection. A debt will be collected in a lump sum or in...

  12. 7 CFR 400.136 - Procedures for salary offset; when deductions may begin.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 6 2010-01-01 2010-01-01 false Procedures for salary offset; when deductions may... Management-Regulations for the 1986 and Succeeding Crop Years § 400.136 Procedures for salary offset; when... amount outlined in the Notice of Intent to collect from the employee's salary, as provided for in § 400...

  13. 7 CFR 400.138 - Procedures for salary offset; methods of collection.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 6 2010-01-01 2010-01-01 false Procedures for salary offset; methods of collection. 400.138 Section 400.138 Agriculture Regulations of the Department of Agriculture (Continued) FEDERAL... Management-Regulations for the 1986 and Succeeding Crop Years § 400.138 Procedures for salary offset; methods...

  14. 45 CFR 2506.32 - What are the Corporation's procedures for salary offset?

    Science.gov (United States)

    2010-10-01

    ... 45 Public Welfare 4 2010-10-01 2010-10-01 false What are the Corporation's procedures for salary...) CORPORATION FOR NATIONAL AND COMMUNITY SERVICE COLLECTION OF DEBTS Salary Offset § 2506.32 What are the Corporation's procedures for salary offset? (a) The Corporation will coordinate salary deductions under this...

  15. 7 CFR 400.137 - Procedures for salary offset; types of collection.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 6 2010-01-01 2010-01-01 false Procedures for salary offset; types of collection. 400.137 Section 400.137 Agriculture Regulations of the Department of Agriculture (Continued) FEDERAL CROP...-Regulations for the 1986 and Succeeding Crop Years § 400.137 Procedures for salary offset; types of collection...

  16. An Examination of Tailored Training Offsets on Core Mortarman Skills Acquisition

    Science.gov (United States)

    2016-02-01

    Training, Mortar, Mortar Gunner’s Exam , Tests SECURITY CLASSIFICATION OF 19. LIMITATION OF ABSTRACT 20...training offsets in 11C OSUT, and ( c ) provide guidance and tools for developing effective training offsets to enhance Soldiers’ core skills proficiencies...Two-Week Mortar Training Including Gunner’s Exam ............................... 13 Knowledge and Application Tests

  17. Determination of the aging offset voltage of AMR sensors based on accelerated degradation test

    NARCIS (Netherlands)

    Zambrano Constantini, A.C.; Kerkhoff, Hans G.

    Usually Anisotropic Magnetoresistance angle sensors are configured with two Wheatstone bridges, but an undesirable offset voltage included in the sensor output affects its accuracy. The total offset voltage combines a voltage due to resistance mismatches during manufacturing and a voltage from

  18. 41 CFR 105-56.008 - Pre-offset paper hearing.

    Science.gov (United States)

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Pre-offset paper hearing. 105-56.008 Section 105-56.008 Public Contracts and Property Management Federal Property Management... General Services Administration Employees § 105-56.008 Pre-offset paper hearing. If a hearing is to be...

  19. 7 CFR 1951.106 - Offset of payments to entities related to debtors.

    Science.gov (United States)

    2010-01-01

    ...) General. Collections of delinquent debts through administrative offset will be in accordance with 7 CFR... delinquent debts through administrative offset may be taken against a debtor's pro rata share of payments due..., or after receiving a loan, established an entity, or has reorganized, transferred ownership of, or...

  20. Spatial optimization of carbon-stocking projects across Africa integrating stocking potential with co-benefits and feasibility.

    Science.gov (United States)

    Greve, Michelle; Reyers, Belinda; Mette Lykke, Anne; Svenning, Jens-Christian

    2013-01-01

    Carbon offset projects through forestation are employed within the emissions trading framework to store carbon. Yet, information about the potential of landscapes to stock carbon, essential to the design of offset projects, is often lacking. Here, based on data on vegetation carbon, climate and soil, we quantify the potential for carbon storage in woody vegetation across tropical Africa. The ability of offset projects to produce co-benefits for ecosystems and people is then quantified. When co-benefits such as biodiversity conservation are considered, the top-ranked sites are sometimes different to sites selected purely for their carbon-stocking potential, although they still possess up to 92% of the latter carbon-stocking potential. This work provides the first continental-scale assessment of which areas may provide the greatest direct and indirect benefits from carbon storage reforestation projects at the smallest costs and risks, providing crucial information for prioritization of investments in carbon storage projects.

  1. Thermosensory reversal effect quantified

    NARCIS (Netherlands)

    Bergmann Tiest, W.M.; Kappers, A.M.L.

    2008-01-01

    At room temperature, some materials feel colder than others due to differences in thermal conductivity, heat capacity and geometry. When the ambient temperature is well above skin temperature, the roles of 'cold' and 'warm' materials are reversed. In this paper, this effect is quantified by

  2. Thermosensory reversal effect quantified

    NARCIS (Netherlands)

    Bergmann Tiest, W.M.; Kappers, A.M.L.

    2008-01-01

    At room temperature, some materials feel colder than others due to differences in thermal conductivity, heat capacity and geometry. When the ambient temperature is well above skin temperature, the roles of ‘cold’ and ‘warm’ materials are reversed. In this paper, this effect is quantified by

  3. Time reversal communication system

    Science.gov (United States)

    Candy, James V.; Meyer, Alan W.

    2008-12-02

    A system of transmitting a signal through a channel medium comprises digitizing the signal, time-reversing the digitized signal, and transmitting the signal through the channel medium. The channel medium may be air, earth, water, tissue, metal, and/or non-metal.

  4. Engineering Encounters: Reverse Engineering

    Science.gov (United States)

    McGowan, Veronica Cassone; Ventura, Marcia; Bell, Philip

    2017-01-01

    This column presents ideas and techniques to enhance your science teaching. This month's issue shares information on how students' everyday experiences can support science learning through engineering design. In this article, the authors outline a reverse-engineering model of instruction and describe one example of how it looked in our fifth-grade…

  5. Sex Reversal in Birds.

    Science.gov (United States)

    Major, Andrew T; Smith, Craig A

    2016-01-01

    Sexual differentiation in birds is controlled genetically as in mammals, although the sex chromosomes are different. Males have a ZZ sex chromosome constitution, while females are ZW. Gene(s) on the sex chromosomes must initiate gonadal sex differentiation during embryonic life, inducing paired testes in ZZ individuals and unilateral ovaries in ZW individuals. The traditional view of avian sexual differentiation aligns with that expounded for other vertebrates; upon sexual differentiation, the gonads secrete sex steroid hormones that masculinise or feminise the rest of the body. However, recent studies on naturally occurring or experimentally induced avian sex reversal suggest a significant role for direct genetic factors, in addition to sex hormones, in regulating sexual differentiation of the soma in birds. This review will provide an overview of sex determination in birds and both naturally and experimentally induced sex reversal, with emphasis on the key role of oestrogen. We then consider how recent studies on sex reversal and gynandromorphic birds (half male:half female) are shaping our understanding of sexual differentiation in avians and in vertebrates more broadly. Current evidence shows that sexual differentiation in birds is a mix of direct genetic and hormonal mechanisms. Perturbation of either of these components may lead to sex reversal. © 2016 S. Karger AG, Basel.

  6. Elastomers with Reversible Nanoporosity

    DEFF Research Database (Denmark)

    Szewczykowski, Piotr Przemyslaw; Andersen, K.; Schulte, Lars

    2009-01-01

    nanostructure and displays liquid-filled cavities. Upon several cycles of swelling and drying the cavities open and close in a reversible fashion. When exposed to a nonsolvent, the material remains collapsed. This discriminating behavior of liquid-material interaction holds potential for the use...

  7. Improved SAR Amplitude Image Offset Measurements for Deriving Three-Dimensional Coseismic Displacements

    KAUST Repository

    Wang, Teng; Jonsson, Sigurjon

    2015-01-01

    Offsets of synthetic aperture radar (SAR) images have played an important role in deriving complete three-dimensional (3-D) surface displacement fields in geoscientific applications. However, offset maps often suffer from multiple outliers and patch-like artifacts, because the standard offset-measurement method is a regular moving-window operation that does not consider the scattering characteristics of the ground. Here, we show that by focusing the offset measurements on predetected strong reflectors, the reliability and accuracy of SAR offsets can be significantly improved. Application to the 2011 Van (Turkey) earthquake reveals a clear deformation signal from an otherwise decorrelated interferogram, making derivation of the 3-D coseismic displacement field possible. Our proposed method can improve mapping of coseismic deformation and other ground displacements, such as glacier flow and landslide movement when strong reflectors exist.

  8. Tuning SISO offset-free Model Predictive Control based on ARX models

    DEFF Research Database (Denmark)

    Huusom, Jakob Kjøbsted; Poulsen, Niels Kjølstad; Jørgensen, Sten Bay

    2012-01-01

    , the proposed controller is simple to tune as it has only one free tuning parameter. These two features are advantageous in predictive process control as they simplify industrial commissioning of MPC. Disturbance rejection and offset-free control is important in industrial process control. To achieve offset......In this paper, we present a tuning methodology for a simple offset-free SISO Model Predictive Controller (MPC) based on autoregressive models with exogenous inputs (ARX models). ARX models simplify system identification as they can be identified from data using convex optimization. Furthermore......-free control in face of unknown disturbances or model-plant mismatch, integrators must be introduced in either the estimator or the regulator. Traditionally, offset-free control is achieved using Brownian disturbance models in the estimator. In this paper we achieve offset-free control by extending the noise...

  9. Improved SAR Amplitude Image Offset Measurements for Deriving Three-Dimensional Coseismic Displacements

    KAUST Repository

    Wang, Teng

    2015-02-03

    Offsets of synthetic aperture radar (SAR) images have played an important role in deriving complete three-dimensional (3-D) surface displacement fields in geoscientific applications. However, offset maps often suffer from multiple outliers and patch-like artifacts, because the standard offset-measurement method is a regular moving-window operation that does not consider the scattering characteristics of the ground. Here, we show that by focusing the offset measurements on predetected strong reflectors, the reliability and accuracy of SAR offsets can be significantly improved. Application to the 2011 Van (Turkey) earthquake reveals a clear deformation signal from an otherwise decorrelated interferogram, making derivation of the 3-D coseismic displacement field possible. Our proposed method can improve mapping of coseismic deformation and other ground displacements, such as glacier flow and landslide movement when strong reflectors exist.

  10. Research developments in methods to reduce the carbon footprint of the food system: a review.

    Science.gov (United States)

    Xu, Zhongyue; Sun, Da-Wen; Zeng, Xin-An; Liu, Dan; Pu, Hongbin

    2015-01-01

    Global warming is a worldwide issue with its evident impact across a wide range of systems and sectors. It is caused by a number of greenhouse gases (GHGs) emissions, in which food system has made up of a large part. Recently, reduction of GHG emissions has become an urgent issue to be resolved in the food system. Many governments and organizations are making great endeavors to alleviate the adverse effect of this phenomenon. In this review, methods to reduce the carbon footprint within the life cycle of a food system are presented from the technical, consumption behavior and environmental policies perspectives. The whole food system including raw material acquisition, processing, packaging, preservation, transportation, consumption, and disposal are covered. Improving management techniques, and adopting advanced technology and equipment are critical for every stage of a food system. Rational site selection is important to alleviate the influence of land use change. In addition, environmental choices of packaging stage, reduction in refrigeration dependence, and correct waste treatment are essential to reduce the total carbon footprint of the production. However, only technical methods cannot radically reverse the trend of climate change, as consumption behaviors present a great deal of influence over climate change. Appropriate purchase patterns and substitution within food product categories by low carbon products can reduce GHG emissions. Development of methods to calculate the carbon footprint of every kind of food and its processing technology enable people to make environmental choice. Policy can shape and cultivate the new code of consumption and influence the direction of emerging technology and science. From political perspectives, government intervention and carbon offset are common tools, especially for carbon tax and a real or implicit price of carbon. Finally, by mitigating the methodologies described above, the rate and magnitude of climate changes

  11. Possible correlations between gamma-ray burst and its host galaxy offset

    Science.gov (United States)

    Wang, Fei-Fei; Zou, Yuan-Chuan; Liu, Yu; Liao, Bin; Moharana, Reetanjali

    2018-06-01

    We collected the information of 304 gamma-ray bursts (GRBs) from the literature, and analyzed the correlations among the host galaxy offsets (the distance from the site of the GRB to the center of its host galaxy), T90,i (the duration T90 in rest-frame), TR45,i (the duration TR45 in rest-frame), Eγ,iso (the isotropic equivalent energy), Lγ,iso (=Eγ,iso /T90,i, the isotropic equivalent luminosity) and Lpk (peak luminosity). We found that T90,i, TR45,i, Eγ,iso, Lpk have negative correlation with offset, which is consistent with origin of short GRBs (SGRBs) and long GRBs (LGRBs). On separate analysis, we found similar results for log ⁡Eγ,iso - log ⁡ (offset) and log ⁡Lpk - log ⁡ (offset) relations in case of SGRBs only, while no obvious relation for LGRBs. There is no correlations between offset and Lγ,iso. We also put the special GRB 170817A and GRB 060218A on the plots. The two GRBs both have low luminosity and small offset. In the log ⁡ (offset) - log ⁡T90,i plot, we found GRB 170817A locates in between the two regions of SGRBs and LGRBs and it is the outlier in the offset -Eγ,iso, offset -Lγ,iso and offset -Lpk plots. Together with GRB 060218A being an outlier in all plots, it indicates the speciality of GRBs 170817A and 060218A, and might imply more subgroups of the GRB samples.

  12. Relationship between acoustic voice onset and offset and selected instances of oscillatory onset and offset in young healthy males and females

    Science.gov (United States)

    Patel, Rita; Forrest, Karen; Hedges, Drew

    2016-01-01

    Objective To investigate the relationship between (1) onset of the acoustic signal and pre-phonatory phases associated with oscillatory onset and (2) offset of the acoustic signal with the post-phonatory events associated with oscillatory offset across vocally healthy adults. Subjects and Methods High-speed videoendoscopy was captured simultaneously with the acoustic signal during repeated production of /hi.hi.hi/ at typical pitch and loudness from 56 vocally healthy adults (age 20–42 years; 21 male, 35 female). The relationship between the acoustic sound pressure signal and oscillatory onset /offset events from the glottal area waveforms (GAW), were statistically investigated using a multivariate linear regression analysis. Results The onset of the acoustic signal (X1a) is a significant predictor of the onset of first oscillations (X1g) and onset of sustained oscillations (X2g). X1a as well as gender are significant predictors of the first instance of medial contact (X1.5g). The offset of the acoustic signal (X2a) is a significant predictor of the first instance of oscillatory offset (X3g), first instance of incomplete glottal closure (X3.5g), and cessation of vocal fold motion (X4g). Conclusions The acoustic signal onset is closely related to the first medial contact of the vocal folds but the latency between these events is longer for females compared to males. The offset of the acoustic signal occurs immediately after incomplete glottal adduction. The emerging normative group latencies between the onset/offset of the acoustic and the GAW from this study appear promising for future investigations. PMID:27769696

  13. Observation of neoclassical transport in reverse shear plasmas on TFTR

    International Nuclear Information System (INIS)

    Efthimion, P.C.; Goeler, S. von; Houlberg, W.A.

    1999-01-01

    Perturbative experiments on TFTR have investigated the transport of multiple ion species in reverse shear (RS) plasmas. The profile evolutions of trace tritium and helium and intrinsic carbon indicate the formation of core particle transport barriers in enhanced reverse shear (ERS) plasmas. There is an order of magnitude reduction in the particle diffusivity inside the RS region. The diffusivities for these species in ERS plasmas agree with neoclassical theory. (author)

  14. Highly stretchable carbon aerogels.

    Science.gov (United States)

    Guo, Fan; Jiang, Yanqiu; Xu, Zhen; Xiao, Youhua; Fang, Bo; Liu, Yingjun; Gao, Weiwei; Zhao, Pei; Wang, Hongtao; Gao, Chao

    2018-02-28

    Carbon aerogels demonstrate wide applications for their ultralow density, rich porosity, and multifunctionalities. Their compressive elasticity has been achieved by different carbons. However, reversibly high stretchability of neat carbon aerogels is still a great challenge owing to their extremely dilute brittle interconnections and poorly ductile cells. Here we report highly stretchable neat carbon aerogels with a retractable 200% elongation through hierarchical synergistic assembly. The hierarchical buckled structures and synergistic reinforcement between graphene and carbon nanotubes enable a temperature-invariable, recoverable stretching elasticity with small energy dissipation (~0.1, 100% strain) and high fatigue resistance more than 10 6 cycles. The ultralight carbon aerogels with both stretchability and compressibility were designed as strain sensors for logic identification of sophisticated shape conversions. Our methodology paves the way to highly stretchable carbon and neat inorganic materials with extensive applications in aerospace, smart robots, and wearable devices.

  15. Transpressive mantle uplift at large offset oceanic transform faults

    Science.gov (United States)

    Maia, M.; Briais, A.; Brunelli, D.; Ligi, M.; Sichel, S. E.; Campos, T.

    2017-12-01

    Large-offset transform faults deform due to changes in plate motions and local processes. At the St. Paul transform, in the Equatorial Atlantic, a large body of ultramafic rocks composed of variably serpentinized and mylonitized peridotites is presently being tectonically uplifted. We recently discovered that the origin of the regional mantle uplift is linked to long-standing compressive stresses along the transform fault (1). A positive flower structure, mainly made of mylonitized mantle rocks, can be recognized on the 200 km large push-up ridge. Compressive earthquakes mechanisms reveal seismically active thrust faults on the southern flank of the ridge . The regional transpressive stress field affects a large portion of the ridge segment south of the transform, as revealed by the presence of faults and dykes striking obliquely to the direction of the central ridge axis. A smaller thrust, affecting recent sediments, was mapped south of this segment, suggesting a regional active compressive stress field. The transpressive stress field is interpreted to derive from the propagation of the Mid-Atlantic Ridge (MAR) segment into the transform domain as a response to the enhanced melt supply at the ridge axis. The propagation forced the migration and segmentation of the transform fault southward and the formation of restraining step-overs. The process started after a counterclockwise change in plate motion at 11 Ma initially resulting in extensive stress of the transform domain. A flexural transverse ridge formed in response. Shortly after plate reorganization, the MAR segment started to propagate southwards due to the interaction of the ridge and the Sierra Leone thermal anomaly. 1- Maia et al., 2016. Extreme mantle uplift and exhumation along a transpressive transform fault Nat. Geo. doi:10.1038/ngeo2759

  16. The beam based alignment technique for the measurements of beam position monitors offsets and beam offsets from quadrupoles in the Pohang Light Source

    International Nuclear Information System (INIS)

    Kim, K.H.; Huang, J.Y.; Ko, I.S.

    1999-01-01

    The beam based alignment (BBA) technique is applied to the 2-GeV storage ring of the Pohang Light Source to measure the offsets of beam position monitors. This measurement is particularly necessary for beam position monitors (BPMs) plugged into a long (∼10 m) aluminum chamber, since the mechanical deformation of the vacuum chamber is experienced after repeated heating for the outgassing process, and the BPM positions are changed accordingly. A part of the excitation current of each quadrupole magnet is shunted through an electronic shunt circuit. Then, the closed orbit receives a perturbation due to the current reduction. Using two quadrupole magnets, we can measure the offset of each BPM. Also, the BBA technique is applied to measure the beam offsets from the center of quadrupole magnets, and gives information to the survey team about which quadrupole magnets should be aligned mostly. In this process, we introduce the merit function to reduce various errors such as BPM characteristic changes and the lattice imperfection. By minimizing the merit function, we can get the beam offset as the maximized expectation value. This paper presents the BBA technique used and experimental results taken from the 2-GeV Pohang Light Source (PLS) storage ring. When the BPM offset is measured, it is observed that a 3% of the shunt current is suitable. (author)

  17. Should we plant trees to offset greenhouse gas emissions in semi-arid environments?

    Science.gov (United States)

    Pataki, D. E.; Pincetl, S.; Gillespie, T. W.; Li, W.; McCarthy, H. R.; Saatchi, S.; Saphores, J.

    2008-12-01

    small proportion of the total greenhouse gases emitted from fossil fuel combustion in the urban area. In general, there is a tradeoff between water costs and carbon offset benefits of urban forests that must be taken into account in environmental tree planting programs in semi-arid cities.

  18. New Dynamic Library of Reverse Osmosis Plants with Fault Simulation

    International Nuclear Information System (INIS)

    Luis, Palacin; Fernando, Tadeo; Cesar, de Prada; Elfil, Hamza

    2009-01-01

    This paper presents an update of a dynamic library of reverse osmosis plants (ROSIM). This library has been developed in order to be used for optimization, simulation, controller testing or fault detection strategies and a simple fault tolerant control is tested. ROSIM is based in a set of components representing the different units of a typical reverse osmosis plant (as sand filters, cartridge filters, exchanger energy recoveries, pumps, membranes, storage tanks, control systems, valves, etc.). Different types of fouling (calcium carbonate, iron hydroxide, biofouling) have been added and the mathematical model of the reverse osmosis membranes, proposed in the original library, has been improved.

  19. The extended wedge method: atomic force microscope friction calibration for improved tolerance to instrument misalignments, tip offset, and blunt probes.

    Science.gov (United States)

    Khare, H S; Burris, D L

    2013-05-01

    One of the major challenges in understanding and controlling friction is the difficulty in bridging the length and time scales of macroscale contacts and those of the single asperity interactions they comprise. While the atomic force microscope (AFM) offers a unique ability to probe tribological surfaces in a wear-free single-asperity contact, instrument calibration challenges have limited the usefulness of this technique for quantitative nanotribological studies. A number of lateral force calibration techniques have been proposed and used, but none has gained universal acceptance due to practical considerations, configuration limitations, or sensitivities to unknowable error sources. This paper describes a simple extension of the classic wedge method of AFM lateral force calibration which: (1) allows simultaneous calibration and measurement on any substrate, thus eliminating prior tip damage and confounding effects of instrument setup adjustments; (2) is insensitive to adhesion, PSD cross-talk, transducer/piezo-tube axis misalignment, and shear-center offset; (3) is applicable to integrated tips and colloidal probes; and (4) is generally applicable to any reciprocating friction coefficient measurement. The method was applied to AFM measurements of polished carbon (99.999% graphite) and single crystal MoS2 to demonstrate the technique. Carbon and single crystal MoS2 had friction coefficients of μ = 0.20 ± 0.04 and μ = 0.006 ± 0.001, respectively, against an integrated Si probe. Against a glass colloidal sphere, MoS2 had a friction coefficient of μ = 0.005 ± 0.001. Generally, the measurement uncertainties ranged from 10%-20% and were driven by the effect of actual frictional variation on the calibration rather than calibration error itself (i.e., due to misalignment, tip-offset, or probe radius).

  20. Reversed field pinch diagnostics

    International Nuclear Information System (INIS)

    Weber, P.G.

    1986-01-01

    The Reversed Field Pinch (RFP) is a toroidal, axisymmetric magnetic confinement configuration characterized by a magnetic field configuration in which the toroidal magnetic field is of similar strength to the poloidal field, and is reversed at the edge compared to the center. The RFP routinely operates at high beta, and is a strong candidate for a compact fusion device. Relevant attributes of the configuration will be presented, together with an overview of present and planned experiments and their diagnostics. RFP diagnostics are in many ways similar to those of other magnetic confinement devices (such as tokamaks); these lectures will point out pertinent differences, and will present some diagnostics which provide special insights into unique attributes of the RFP

  1. Posterior Reversible Encephalopathy (PRES)

    International Nuclear Information System (INIS)

    Moron E, Fanny E; Diaz Marchan, Pedro

    2005-01-01

    The Posterior Reversible Encephalopathy Syndrome (PRES) is a clinical Syndrome composed of cephalea, alteration in vision and convulsions, usually observed in patients with sudden elevation of arterial pressure. The imagenologic evidence shows reversible vasogenic brain edema without stroke. Its location is predominantly posterior; it affects the cortex and the subcortical white matter of the occipital, parietal and temporal lobes. The treatment with antihypertensive drugs and the removing of immunosupressor medication are generally associated with complete neurological recovery; this is reflected also in the images which return to their basal condition. The untreated hypertension, on the other side, can result in a progressive defect of the autoregulation system of the central nervous system with cerebral hemorrhage, irreversible brain stroke, coma and death

  2. In-Flight Calibration Methods for Temperature-Dependent Offsets in the MMS Fluxgate Magnetometers

    Science.gov (United States)

    Bromund, K. R.; Plaschke, F.; Strangeway, R. J.; Anderson, B. J.; Huang, B. G.; Magnes, W.; Fischer, D.; Nakamura, R.; Leinweber, H. K.; Russell, C. T.; hide

    2016-01-01

    During the first dayside season of the Magnetospheric Multiscale (MMS) mission, the in-flight calibration process for the Fluxgate magnetometers (FGM) implemented an algorithm that selected a constant offset (zero-level) for each sensor on each orbit. This method was generally able to reduce the amplitude of residual spin tone to less than 0.2 nT within the region of interest. However, there are times when the offsets do show significant short-term variations. These variations are most prominent in the nighttime season (phase 1X), when eclipses are accompanied by offset changes as large as 1 nT. Eclipses are followed by a recovery period as long as 12 hours where the offsets continue to change as temperatures stabilize. Understanding and compensating for these changes will become critical during Phase 2 of the mission in 2017, when the nightside will become the focus of MMS science. Although there is no direct correlation between offset and temperature, the offsets are seen for the period of any given week to be well-characterized as function of instrument temperature. Using this property, a new calibration method has been developed that has proven effective in compensating for temperature-dependent offsets during phase 1X of the MMS mission and also promises to further refine calibration quality during the dayside season.

  3. In-Flight Calibration Methods for Temperature-Dependendent Offsets in the MMS Fluxgate Magnetometers

    Science.gov (United States)

    Bromund, K. R.; Plaschke, F.; Strangeway, R. J.; Anderson, B. J.; Huang, B. G.; Magnes, W.; Fischer, D.; Nakamura, R.; Leinweber, H. K.; Russell, C. T.; Baumjohann, W.; Chutter, M.; Torbert, R. B.; Le, G.; Slavin, J. A.; Kepko, L.

    2016-12-01

    During the first dayside season of the Magnetospheric Multiscale (MMS) mission, the in-flight calibration process for the Fluxgate magnetometers (FGM) implemented an algorithm that selected a constant offset (zero-level) for each sensor on each orbit. This method was generally able to reduce the amplitude of residual spin tone to less than 0.2 nT within the region of interest. However, there are times when the offsets do show significant short-term variations. These variations are most prominent in the nighttime season (phase 1X), when eclipses are accompanied by offset changes as large as 1 nT. Eclipses are followed by a recovery period as long as 12 hours where the offsets continue to change as temperatures stabilize. Understanding and compensating for these changes will become critical during Phase 2 of the mission in 2017, when the nightside will become the focus of MMS science. Although there is no direct correlation between offset and temperature, the offsets are seen — for the period of any given week — to be well-characterized as function of instrument temperature. Using this property, a new calibration method has been developed that has proven effective in compensating for temperature-dependent offsets during phase 1X of the MMS mission and also promises to further refine calibration quality during the dayside season.

  4. A Framework for Implementing and Valuing Biodiversity Offsets in Colombia: A Landscape Scale Perspective

    Directory of Open Access Journals (Sweden)

    Shirley Saenz

    2013-11-01

    Full Text Available Biodiversity offsets provide a mechanism for maintaining or enhancing environmental values in situations where development is sought, despite negative environmental impacts. They seek to ensure that unavoidable deleterious environmental impacts of development are balanced by environmental gains. When onsite impacts warrant the use of offsets there is often little attention paid to make sure that the location of offset sites provides the greatest conservation benefit, ensuring they are consistent with landscape level conservation goals. In most offset frameworks it is difficult for developers to proactively know the offset requirements they will need to implement. Here we propose a framework to address these needs. We propose a series of rules for selecting offset sites that meet the conservation needs of potentially impacted biological targets. We then discuss an accounting approach that seeks to support offset ratio determinations based on a structured and transparent approach. To demonstrate the approach, we present a framework developed in partnership with the Colombian Ministry of Environment and Sustainable Development to reform existing mitigation regulatory processes.

  5. Reversible infantile mitochondrial diseases.

    Science.gov (United States)

    Boczonadi, Veronika; Bansagi, Boglarka; Horvath, Rita

    2015-05-01

    Mitochondrial diseases are usually severe and progressive conditions; however, there are rare forms that show remarkable spontaneous recoveries. Two homoplasmic mitochondrial tRNA mutations (m.14674T>C/G in mt-tRNA(Glu)) have been reported to cause severe infantile mitochondrial myopathy in the first months of life. If these patients survive the first year of life by extensive life-sustaining measures they usually recover and develop normally. Another mitochondrial disease due to deficiency of the 5-methylaminomethyl-2-thiouridylate methyltransferase (TRMU) causes severe liver failure in infancy, but similar to the reversible mitochondrial myopathy, within the first year of life these infants may also recover completely. Partial recovery has been noted in some other rare forms of mitochondrial disease due to deficiency of mitochondrial tRNA synthetases and mitochondrial tRNA modifying enzymes. Here we summarize the clinical presentation of these unique reversible mitochondrial diseases and discuss potential molecular mechanisms behind the reversibility. Understanding these mechanisms may provide the key to treatments of potential broader relevance in mitochondrial disease, where for the majority of the patients no effective treatment is currently available.

  6. Positioning paper on reversibility

    International Nuclear Information System (INIS)

    2016-01-01

    After having recalled the legal framework adopted in 2006 for the deep geological storage of radioactive wastes, and briefly introduced the concept of reversibility, this publication presents the principle of geological storage, presents high and medium level and long life wastes, highlights the ethical necessity to deal with these radioactive wastes, outlines that geological storage is the generally admitted and adopted solution at the international level, and presents additional means implemented for radioactive waste management. It presents the Cigeo project as the technical answer to the issue of radioactive waste storage, describes the Cigeo development process, its current status and its development planning, and justifies the choice of this technical solution, notably from an ethical point of view. It addresses the issue of reversibility and proposes an overview of the various tools and means which aim at guaranteeing this reversibility. Appendices propose figures illustrating the Cigeo project and its development process, and a rather detailed Power Point presentation of the project by the ANDRA (history, object, planning, installations, and so on)

  7. An Analysis of Second-Tier Arms Producing Countries' Offset Policies: Technology Transfer and Defense Industrial Base Establishment

    National Research Council Canada - National Science Library

    Confer, Brian S

    2008-01-01

    The purpose of this thesis is to determine if offsets are an effective means of second-tier countries acquiring technology and if offsets enhance their ability to establish and maintain an industrial...

  8. The offset-midpoint traveltime pyramid of P-waves in homogeneous orthorhombic media

    KAUST Repository

    Hao, Qi; Stovas, Alexey; Alkhalifah, Tariq Ali

    2016-01-01

    The offset-midpoint traveltime pyramid describes the diffraction traveltime of a point diffractor in homogeneous media. We have developed an analytic approximation for the P-wave offset-midpoint traveltime pyramid for homogeneous orthorhombic media. In this approximation, a perturbation method and the Shanks transform were implemented to derive the analytic expressions for the horizontal slowness components of P-waves in orthorhombic media. Numerical examples were shown to analyze the proposed traveltime pyramid formula and determined its accuracy and the application in calculating migration isochrones and reflection traveltime. The proposed offset-midpoint traveltime formula is useful for Kirchhoff prestack time migration and migration velocity analysis for orthorhombic media.

  9. The offset-midpoint traveltime pyramid of P-waves in homogeneous orthorhombic media

    KAUST Repository

    Hao, Qi

    2016-07-18

    The offset-midpoint traveltime pyramid describes the diffraction traveltime of a point diffractor in homogeneous media. We have developed an analytic approximation for the P-wave offset-midpoint traveltime pyramid for homogeneous orthorhombic media. In this approximation, a perturbation method and the Shanks transform were implemented to derive the analytic expressions for the horizontal slowness components of P-waves in orthorhombic media. Numerical examples were shown to analyze the proposed traveltime pyramid formula and determined its accuracy and the application in calculating migration isochrones and reflection traveltime. The proposed offset-midpoint traveltime formula is useful for Kirchhoff prestack time migration and migration velocity analysis for orthorhombic media.

  10. Status of time reversal invariance

    International Nuclear Information System (INIS)

    Henley, E.M.

    1989-01-01

    Time Reversal Invariance is introduced, and theories for its violation are reviewed. The present experimental and theoretical status of Time Reversal Invariance and tests thereof will be presented. Possible future tests will be discussed. 30 refs., 2 figs., 1 tab

  11. Introduction to time reversal theory

    International Nuclear Information System (INIS)

    Henley, E.M.

    1987-01-01

    Theory and reaction mechanisms relevant to time reversal invariance are reviewed. Consequences of time reversal invariance are presented under the headings of CP tests, electromagnetic moments, weak emissions or absorptions, and scattering reactions. 8 refs., 4 figs

  12. Simulation of Far-Field Superresolution Fluorescence Imaging with Two-Color One-Photon Excitation of Reversible Photoactivatable Protein

    International Nuclear Information System (INIS)

    Wang Chen; Qiao Ling-Ling; Mao Zheng-Le

    2011-01-01

    We propose to achieve far-field super-resolution imaging by using offset two-color one-photon (2C1P) excitation of reversible photoactivatable fluorescence proteins. Due to the distinctive photoswitching performance of the proteins, such as dronpa, the fluorescence emission will only come from the overlapped region of activation beam and excitation beam. The analysis solution of rate equation shows that the resolution of offset 2C1P microscope is 'engineered' by laser power of excitation and activation beams and the power ratio between them. Superior lateral and transverse resolution is theoretically demonstrated compared with conventional fluorescence scanning microscopy. (fundamental areas of phenomenology(including applications))

  13. The Causes of Preference Reversal.

    OpenAIRE

    Tversky, Amos; Slovic, Paul; Kahneman, Daniel

    1990-01-01

    Observed preference reversal cannot be adequately explained by violations of independence, the reduction axiom, or transitivity. The primary cause of preference reversal is the failure of procedure invariance, especially the overpricing of low-probability, high-payoff bets. This result violates regret theory and generalized (nonindependent) utility models. Preference reversal and a new reversal involving time preferences are explained by scale compatibility, which implies that payoffs are wei...

  14. Geomagnetic Field During a Reversal

    Science.gov (United States)

    Heirtzler, J. R.

    2003-01-01

    It has frequently been suggested that only the geomagnetic dipole, rather than higher order poles, reverse during a geomagnetic field reversal. Under this assumption the geomagnetic field strength has been calculated for the surface of the Earth for various steps of the reversal process. Even without an eminent a reversal of the field, extrapolation of the present secular change (although problematic) shows that the field strength may become zero in some geographic areas within a few hundred years.

  15. A Study on Reverse Logistics

    OpenAIRE

    Reddy, Dhananjaya

    2011-01-01

    In the competitive world of manufacturing, companies are often searching for new ways to improve their process, customer satisfaction and stay ahead in the game with their competitors. Reverse logistics has been considered a strategy to bring these things to life for the past decade or so. This thesis work tries to shed some light on the basics of reverse logistics and how reverse logistics can be used as a management strategy. This paper points out the fundamentals of reverse logistics and l...

  16. Biodiverse planting for carbon and biodiversity on indigenous land.

    Science.gov (United States)

    Renwick, Anna R; Robinson, Catherine J; Martin, Tara G; May, Tracey; Polglase, Phil; Possingham, Hugh P; Carwardine, Josie

    2014-01-01

    Carbon offset mechanisms have been established to mitigate climate change through changes in land management. Regulatory frameworks enable landowners and managers to generate saleable carbon credits on domestic and international markets. Identifying and managing the associated co-benefits and dis-benefits involved in the adoption of carbon offset projects is important for the projects to contribute to the broader goal of sustainable development and the provision of benefits to the local communities. So far it has been unclear how Indigenous communities can benefit from such initiatives. We provide a spatial analysis of the carbon and biodiversity potential of one offset method, planting biodiverse native vegetation, on Indigenous land across Australia. We discover significant potential for opportunities for Indigenous communities to achieve carbon sequestration and biodiversity goals through biodiverse plantings, largely in southern and eastern Australia, but the economic feasibility of these projects depend on carbon market assumptions. Our national scale cost-effectiveness analysis is critical to enable Indigenous communities to maximise the benefits available to them through participation in carbon offset schemes.

  17. Offsetting global warming-induced elevated greenhouse gas emissions from an arable soil by biochar application.

    Science.gov (United States)

    Bamminger, Chris; Poll, Christian; Marhan, Sven

    2018-01-01

    Global warming will likely enhance greenhouse gas (GHG) emissions from soils. Due to its slow decomposability, biochar is widely recognized as effective in long-term soil carbon (C) sequestration and in mitigation of soil GHG emissions. In a long-term soil warming experiment (+2.5 °C, since July 2008) we studied the effect of applying high-temperature Miscanthus biochar (0, 30 t/ha, since August 2013) on GHG emissions and their global warming potential (GWP) during 2 years in a temperate agroecosystem. Crop growth, physical and chemical soil properties, temperature sensitivity of soil respiration (R s ), and metabolic quotient (qCO 2 ) were investigated to yield further information about single effects of soil warming and biochar as well as on their interactions. Soil warming increased total CO 2 emissions by 28% over 2 years. The effect of warming on soil respiration did not level off as has often been observed in less intensively managed ecosystems. However, the temperature sensitivity of soil respiration was not affected by warming. Overall, biochar had no effect on most of the measured parameters, suggesting its high degradation stability and its low influence on microbial C cycling even under elevated soil temperatures. In contrast, biochar × warming interactions led to higher total N 2 O emissions, possibly due to accelerated N-cycling at elevated soil temperature and to biochar-induced changes in soil properties and environmental conditions. Methane uptake was not affected by soil warming or biochar. The incorporation of biochar-C into soil was estimated to offset warming-induced elevated GHG emissions for 25 years. Our results highlight the suitability of biochar for C sequestration in cultivated temperate agricultural soil under a future elevated temperature. However, the increased N 2 O emissions under warming limit the GHG mitigation potential of biochar. © 2017 John Wiley & Sons Ltd.

  18. Geomagnetic Reversals during the Phanerozoic.

    Science.gov (United States)

    McElhinny, M W

    1971-04-09

    An antalysis of worldwide paleomagnetic measurements suggests a periodicity of 350 x 10(6) years in the polarity of the geomagnetic field. During the Mesozoic it is predominantly normal, whereas during the Upper Paleozoic it is predominantly reversed. Although geomagnetic reversals occur at different rates throughout the Phanerozoic, there appeaars to be no clear correlation between biological evolutionary rates and reversal frequency.

  19. Reversal Strategies for NOACs

    DEFF Research Database (Denmark)

    Husted, Steen; Verheugt, Freek; Comuth, Willemijn

    2015-01-01

    , coagulation factor concentrates or NOAC-specific antidotes could be used. Coagulation factor concentrates can be used in patients with haemophilia and to reverse the effect of VKAs but, in NOAC-treated patients, results are inconsistent and these agents could potentially have pro-thrombotic effects. Specific...... antidotes for NOACs are expected to be on the market soon. Phase III clinical trials with a humanized antibody fragment directed against dabigatran (idarucizumab) and recombinant, modified factor Xa (andexanet alfa) are ongoing. A molecule (aripazine) with broad activity against various anticoagulants...

  20. Reversible brazing process

    Science.gov (United States)

    Pierce, Jim D.; Stephens, John J.; Walker, Charles A.

    1999-01-01

    A method of reversibly brazing surfaces together. An interface is affixed to each surface. The interfaces can be affixed by processes such as mechanical joining, welding, or brazing. The two interfaces are then brazed together using a brazing process that does not defeat the surface to interface joint. Interfaces of materials such as Ni-200 can be affixed to metallic surfaces by welding or by brazing with a first braze alloy. The Ni-200 interfaces can then be brazed together using a second braze alloy. The second braze alloy can be chosen so that it minimally alters the properties of the interfaces to allow multiple braze, heat and disassemble, rebraze cycles.

  1. 76 FR 5070 - Offset of Tax Refund Payments To Collect Delinquent State Unemployment Compensation Debts

    Science.gov (United States)

    2011-01-28

    ... Payments To Collect Delinquent State Unemployment Compensation Debts AGENCY: Financial Management Service... (referred to as ``tax refund offset'') to collect delinquent State unemployment compensation debts. The Department of the Treasury (Treasury) will incorporate the procedures necessary to collect State unemployment...

  2. An offset cancellation technique in a switched-capacitor comparator for SAR ADCs

    International Nuclear Information System (INIS)

    Tong Xingyuan; Zhu Zhangming; Yang Yintang

    2012-01-01

    An offset cancellation technique for a SAR (successive approximation register) ADC switched-capacitor comparator is described. The comparator is designed with a pre-amplifying and regenerative latching structure and realized in 0.18 μm CMOS. With the first stage preamplifier offset cancellation and low offset regenerative latching approach, the equivalent offset of the comparator is reduced to < 0.55 mV. By using the pre-amplifying and regenerative latching comparison mode the comparator exhibits low power dissipation. Under a 1.8 V power supply, with a 200 kS/s ADC sampling rate and 3 MHz clock frequency, a 13-bit comparison resolution is reached and less than 0.09 mW power dissipation is consumed. The superiority of this comparator is discussed and proved by the post-simulation and application to a 10 bit 200 kS/s touch screen SAR A/D converter. (semiconductor integrated circuits)

  3. Pair Cascades and Deathlines in Magnetic Fields with Offset Polar Caps

    Science.gov (United States)

    Harding, Alice K.; Muslimov, Alex G.

    2012-01-01

    We present results of electron-positron pair cascade simulations in a dipole magnetic field whose polar cap is offset from the dipole axis. In such a field geometry, the polar cap is displaced a small fraction of the neutron star radius from the star symmetry axis and the field line radius of curvature is modified. Using the modified parallel electric field near the offset polar cap, we simulate pair cascades to determine the pair deathlines and pair multiplicities as a function of the offset. We find that the pair multiplicity can change dr;unatically with a modest offset, with a significant increase on one side of the polar cap. Lower pair deathlines allow a larger fraction of the pulsar population, that include old and millisecond pulsars, to produce cascades with high multiplicity. The results have some important implications for pulsar particle production, high-energy emission and cosmic-ray contribution.

  4. Dynamics analysis of microsphere in a dual-beam fiber-optic trap with transverse offset.

    Science.gov (United States)

    Chen, Xinlin; Xiao, Guangzong; Luo, Hui; Xiong, Wei; Yang, Kaiyong

    2016-04-04

    A comprehensive dynamics analysis of microsphere has been presented in a dual-beam fiber-optic trap with transverse offset. As the offset distance between two counterpropagating beams increases, the motion type of the microsphere starts with capture, then spiral motion, then orbital rotation, and ends with escape. We analyze the transformation process and mechanism of the four motion types based on ray optics approximation. Dynamic simulations show that the existence of critical offset distances at which different motion types transform. The result is an important step toward explaining physical phenomena in a dual-beam fiber-optic trap with transverse offset, and is generally applicable to achieving controllable motions of microspheres in integrated systems, such as microfluidic systems and lab-on-a-chip systems.

  5. Combining landscape-level conservation planning and biodiversity offset programs: a case study.

    Science.gov (United States)

    Underwood, Jared G

    2011-01-01

    Habitat loss is a major factor in the endangerment and extinction of species around the world. One promising strategy to balance continued habitat loss and biodiversity conservation is that of biodiversity offsets. However, a major concern with offset programs is their consistency with landscape-level conservation goals. While merging offset policies and landscape-level conservation planning is thought to provide advantages over a traditional disconnected approach, few such landscape-level conservation-offset plans have been designed and implemented, so the effectiveness of such a strategy remains uncertain. In this study, we quantitatively assess the conservation impact of combining landscape-level conservation planning and biodiversity offset programs by comparing regions of San Diego County, USA with the combined approach to regions with only an offset program. This comparison is generally very difficult due to a variety of complicating factors. We overcome these complications and quantify the benefits to rare and threatened species of implementing a combined approach by assessing the amount of each species' predicted distribution, and the number of documented locations, conserved in comparison to the same metric for areas with an offset policy alone. We found that adoption of the combined approach has increased conservation for many rare species, often 5-10 times more than in the comparison area, and that conservation has been focused in the areas most important for these species. The level of conservation achieved reduces uncertainty that these species will persist in the region into the future. This San Diego County example demonstrates the potential benefits of combining landscape-level conservation planning and biodiversity offset programs.

  6. Mono-Exponential Fitting in T2-Relaxometry: Relevance of Offset and First Echo.

    Directory of Open Access Journals (Sweden)

    David Milford

    Full Text Available T2 relaxometry has become an important tool in quantitative MRI. Little focus has been put on the effect of the refocusing flip angle upon the offset parameter, which was introduced to account for a signal floor due to noise or to long T2 components. The aim of this study was to show that B1 imperfections contribute significantly to the offset. We further introduce a simple method to reduce the systematic error in T2 by discarding the first echo and using the offset fitting approach.Signal curves of T2 relaxometry were simulated based on extended phase graph theory and evaluated for 4 different methods (inclusion and exclusion of the first echo, while fitting with and without the offset. We further performed T2 relaxometry in a phantom at 9.4T magnetic resonance imaging scanner and used the same methods for post-processing as in the extended phase graph simulated data. Single spin echo sequences were used to determine the correct T2 time.The simulation data showed that the systematic error in T2 and the offset depends on the refocusing pulse, the echo spacing and the echo train length. The systematic error could be reduced by discarding the first echo. Further reduction of the systematic T2 error was reached by using the offset as fitting parameter. The phantom experiments confirmed these findings.The fitted offset parameter in T2 relaxometry is influenced by imperfect refocusing pulses. Using the offset as a fitting parameter and discarding the first echo is a fast and easy method to minimize the error in T2, particularly for low to intermediate echo train length.

  7. Forest and wood products role in carbon sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Sampson, R.N.

    1997-12-31

    An evaluation of the use of U.S. forests and forest products for carbon emission mitigation is presented. The current role of forests in carbon sequestration is described in terms of regional differences and forest management techniques. The potential for increasing carbon storage by converting marginal crop and pasture land, increasing timberland growth, reducing wildfire losses, and changing timber harvest methods is examined. Post-harvest carbon flows, environmental impacts of wood products, biomass energy crops, and increased use of energy-conserving trees are reviewed for their potential in reducing or offsetting carbon emissions. It is estimated that these techniques could offset 20 to 40 percent of the carbon emitted annually in the U.S. 39 refs., 5 tabs.

  8. Reversibly Bistable Flexible Electronics

    KAUST Repository

    Alfaraj, Nasir

    2015-05-01

    Introducing the notion of transformational silicon electronics has paved the way for integrating various applications with silicon-based, modern, high-performance electronic circuits that are mechanically flexible and optically semitransparent. While maintaining large-scale production and prototyping rapidity, this flexible and translucent scheme demonstrates the potential to transform conventionally stiff electronic devices into thin and foldable ones without compromising long-term performance and reliability. In this work, we report on the fabrication and characterization of reversibly bistable flexible electronic switches that utilize flexible n-channel metal-oxide-semiconductor field-effect transistors. The transistors are fabricated initially on rigid (100) silicon substrates before they are peeled off. They can be used to control flexible batches of light-emitting diodes, demonstrating both the relative ease of scaling at minimum cost and maximum reliability and the feasibility of integration. The peeled-off silicon fabric is about 25 µm thick. The fabricated devices are transferred to a reversibly bistable flexible platform through which, for example, a flexible smartphone can be wrapped around a user’s wrist and can also be set back to its original mechanical position. Buckling and cyclic bending of such host platforms brings a completely new dimension to the development of flexible electronics, especially rollable displays.

  9. On determining fluxgate magnetometer spin axis offsets from mirror mode observations

    Science.gov (United States)

    Plaschke, Ferdinand; Narita, Yasuhito

    2016-09-01

    In-flight calibration of fluxgate magnetometers that are mounted on spacecraft involves finding their outputs in vanishing ambient fields, the so-called magnetometer offsets. If the spacecraft is spin-stabilized, then the spin plane components of these offsets can be relatively easily determined, as they modify the spin tone content in the de-spun magnetic field data. The spin axis offset, however, is more difficult to determine. Therefore, usually Alfvénic fluctuations in the solar wind are used. We propose a novel method to determine the spin axis offset: the mirror mode method. The method is based on the assumption that mirror mode fluctuations are nearly compressible such that the maximum variance direction is aligned to the mean magnetic field. Mirror mode fluctuations are typically found in the Earth's magnetosheath region. We introduce the method and provide a first estimate of its accuracy based on magnetosheath observations by the THEMIS-C spacecraft. We find that 20 h of magnetosheath measurements may already be sufficient to obtain high-accuracy spin axis offsets with uncertainties on the order of a few tenths of a nanotesla, if offset stability can be assumed.

  10. On determining fluxgate magnetometer spin axis offsets from mirror mode observations

    Directory of Open Access Journals (Sweden)

    F. Plaschke

    2016-09-01

    Full Text Available In-flight calibration of fluxgate magnetometers that are mounted on spacecraft involves finding their outputs in vanishing ambient fields, the so-called magnetometer offsets. If the spacecraft is spin-stabilized, then the spin plane components of these offsets can be relatively easily determined, as they modify the spin tone content in the de-spun magnetic field data. The spin axis offset, however, is more difficult to determine. Therefore, usually Alfvénic fluctuations in the solar wind are used. We propose a novel method to determine the spin axis offset: the mirror mode method. The method is based on the assumption that mirror mode fluctuations are nearly compressible such that the maximum variance direction is aligned to the mean magnetic field. Mirror mode fluctuations are typically found in the Earth's magnetosheath region. We introduce the method and provide a first estimate of its accuracy based on magnetosheath observations by the THEMIS-C spacecraft. We find that 20 h of magnetosheath measurements may already be sufficient to obtain high-accuracy spin axis offsets with uncertainties on the order of a few tenths of a nanotesla, if offset stability can be assumed.

  11. Coupling between core and cladding modes in a helical core fiber with large core offset

    International Nuclear Information System (INIS)

    Napiorkowski, Maciej; Urbanczyk, Waclaw

    2016-01-01

    We analyzed the effect of resonant coupling between core and cladding modes in a helical core fiber with large core offset using the fully vectorial method based on the transformation optics formalism. Our study revealed that the resonant couplings to lower order cladding modes predicted by perturbative methods and observed experimentally in fibers with small core offsets are in fact prohibited for larger core offsets. This effect is related to the lack of phase matching caused by elongation of the optical path of the fundamental modes in the helical core. Moreover, strong couplings to the cladding modes of the azimuthal modal number much higher than predicted by perturbative methods may be observed for large core offsets, as the core offset introduces higher order angular harmonics in the field distribution of the fundamental modes. Finally, in contrast to previous studies, we demonstrate the existence of spectrally broad polarization sensitive couplings to the cladding modes suggesting that helical core fibers with large core offsets may be used as broadband circular polarizers. (paper)

  12. Channel estimation in DFT-based offset-QAM OFDM systems.

    Science.gov (United States)

    Zhao, Jian

    2014-10-20

    Offset quadrature amplitude modulation (offset-QAM) orthogonal frequency division multiplexing (OFDM) exhibits enhanced net data rates compared to conventional OFDM, and reduced complexity compared to Nyquist FDM (N-FDM). However, channel estimation in discrete-Fourier-transform (DFT) based offset-QAM OFDM is different from that in conventional OFDM and requires particular study. In this paper, we derive a closed-form expression for the demultiplexed signal in DFT-based offset-QAM systems and show that although the residual crosstalk is orthogonal to the decoded signal, its existence degrades the channel estimation performance when the conventional least-square method is applied. We propose and investigate four channel estimation algorithms for offset-QAM OFDM that vary in terms of performance, complexity, and tolerance to system parameters. It is theoretically and experimentally shown that simple channel estimation can be realized in offset-QAM OFDM with the achieved performance close to the theoretical limit. This, together with the existing advantages over conventional OFDM and N-FDM, makes this technology very promising for optical communication systems.

  13. Consultations on the design of a greenhouse gas offset system for Canada 2003 : Summary report

    International Nuclear Information System (INIS)

    2003-10-01

    A series of one-day consultation sessions were held from June 16 to 26, 2003 in 6 cities throughout Canada, hosted by the federal government's interdepartmental Working Group on Offsets (WGO). The consultations were held in an effort to: (1) disseminate information to the provinces, territories and stakeholders concerning options and process for the development of an offset system for greenhouse gases, (2) promote the exchange of ideas and discussion on the feasibility of an offset system, (3) gather initial feedback on design considerations, elements and options, and (4) provide advice to provinces and territories on ways to provide further input on the offset system design. The 295 people who attended the sessions represented industries considered to be potential buyers of offset credits, industries considered to be potential sellers of such credits, and other sectors such as consultants, traders, insurance and finance. In addition, academia and other stakeholders were present. This document provides a summary of the main messages that emerged from the discussions. The comments reflected the following notions: support for the concept was expressed; principles should be as open as possible; surplus eligibility criteria should be less restrictive; administrative issues should consider a third party for active government involvement; design issues; forestry issues; agriculture issues; landfill gas issues; regional issues; and, next steps. These comments will be considered during the development phase of a greenhouse gas offset system in Canada. tabs

  14. Band Offsets at the Interface between Crystalline and Amorphous Silicon from First Principles

    Science.gov (United States)

    Jarolimek, K.; Hazrati, E.; de Groot, R. A.; de Wijs, G. A.

    2017-07-01

    The band offsets between crystalline and hydrogenated amorphous silicon (a -Si ∶H ) are key parameters governing the charge transport in modern silicon heterojunction solar cells. They are an important input for macroscopic simulators that are used to further optimize the solar cell. Past experimental studies, using x-ray photoelectron spectroscopy (XPS) and capacitance-voltage measurements, have yielded conflicting results on the band offset. Here, we present a computational study on the band offsets. It is based on atomistic models and density-functional theory (DFT). The amorphous part of the interface is obtained by relatively long DFT first-principles molecular-dynamics runs at an elevated temperature on 30 statistically independent samples. In order to obtain a realistic conduction-band position the electronic structure of the interface is calculated with a hybrid functional. We find a slight asymmetry in the band offsets, where the offset in the valence band (0.29 eV) is larger than in the conduction band (0.17 eV). Our results are in agreement with the latest XPS measurements that report a valence-band offset of 0.3 eV [M. Liebhaber et al., Appl. Phys. Lett. 106, 031601 (2015), 10.1063/1.4906195].

  15. Optimum energy levels and offsets for organic donor/acceptor binary photovoltaic materials and solar cells

    International Nuclear Information System (INIS)

    Sun, S.-S.

    2005-01-01

    Optimum frontier orbital energy levels and offsets of an organic donor/acceptor binary type photovoltaic material have been analyzed using classic Marcus electron transfer theory in order to achieve the most efficient photo induced charge separation. This study reveals that, an exciton quenching parameter (EQP) yields one optimum donor/acceptor frontier orbital energy offset that equals the sum of the exciton binding energy and the charge separation reorganization energy, where the photo generated excitons are converted into charges most efficiently. A recombination quenching parameter (RQP) yields a second optimum donor/acceptor energy offset where the ratio of charge separation rate constant over charge recombination rate constant becomes largest. It is desirable that the maximum RQP is coincidence or close to the maximum EQP. A third energy offset is also identified where charge recombination becomes most severe. It is desirable that the most severe charge recombination offset is far away from maximum EQP offset. These findings are very critical for evaluating and fine tuning frontier orbital energy levels of a donor/acceptor pair in order to realize high efficiency organic photovoltaic materials

  16. Policy development for environmental licensing and biodiversity offsets in Latin America.

    Directory of Open Access Journals (Sweden)

    Ana Villarroya

    Full Text Available Attempts to meet biodiversity goals through application of the mitigation hierarchy have gained wide traction globally with increased development of public policy, lending standards, and corporate practices. With interest in biodiversity offsets increasing in Latin America, we seek to strengthen the basis for policy development through a review of major environmental licensing policy frameworks in Argentina, Brazil, Chile, Colombia, Mexico, Peru and Venezuela. Here we focused our review on an examination of national level policies to evaluate to which degree current provisions promote positive environmental outcomes. All the surveyed countries have national-level Environmental Impact Assessment laws or regulations that cover the habitats present in their territories. Although most countries enable the use of offsets only Brazil, Colombia, Mexico and Peru explicitly require their implementation. Our review has shown that while advancing quite detailed offset policies, most countries do not seem to have strong requirements regarding impact avoidance. Despite this deficiency most countries have a strong foundation from which to develop policy for biodiversity offsets, but several issues require further guidance, including how best to: (1 ensure conformance with the mitigation hierarchy; (2 identify the most environmentally preferable offsets within a landscape context; (3 determine appropriate mitigation replacement ratios; and (4 ensure appropriate time and effort is given to monitor offset performance.

  17. Policy development for environmental licensing and biodiversity offsets in Latin America.

    Science.gov (United States)

    Villarroya, Ana; Barros, Ana Cristina; Kiesecker, Joseph

    2014-01-01

    Attempts to meet biodiversity goals through application of the mitigation hierarchy have gained wide traction globally with increased development of public policy, lending standards, and corporate practices. With interest in biodiversity offsets increasing in Latin America, we seek to strengthen the basis for policy development through a review of major environmental licensing policy frameworks in Argentina, Brazil, Chile, Colombia, Mexico, Peru and Venezuela. Here we focused our review on an examination of national level policies to evaluate to which degree current provisions promote positive environmental outcomes. All the surveyed countries have national-level Environmental Impact Assessment laws or regulations that cover the habitats present in their territories. Although most countries enable the use of offsets only Brazil, Colombia, Mexico and Peru explicitly require their implementation. Our review has shown that while advancing quite detailed offset policies, most countries do not seem to have strong requirements regarding impact avoidance. Despite this deficiency most countries have a strong foundation from which to develop policy for biodiversity offsets, but several issues require further guidance, including how best to: (1) ensure conformance with the mitigation hierarchy; (2) identify the most environmentally preferable offsets within a landscape context; (3) determine appropriate mitigation replacement ratios; and (4) ensure appropriate time and effort is given to monitor offset performance.

  18. Reversed austenite in 0Cr13Ni4Mo martensitic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Song, Y.Y., E-mail: songyuanyuan@imr.ac.cn [Institute of Metal Research, Chinese Academy of Science, Shenyang 110016 (China); Li, X.Y.; Rong, L.J.; Li, Y.Y. [Institute of Metal Research, Chinese Academy of Science, Shenyang 110016 (China); Nagai, T. [National Institute for Materials Science, Sengen 1-2-1, Tsukuba 305-0047 (Japan)

    2014-01-15

    The austenite reversion process and the distribution of carbon and other alloying elements during tempering in 0Cr13Ni4Mo martensitic stainless steel have been investigated by in-situ high temperature X-ray diffraction (XRD) and scanning transmission electron microscopy (STEM). The microstructure of the reversed austenite was characterized using transmission electron microscopy (TEM). The results revealed that the amount of the reversed austenite formed at high temperature increased with the holding time. Direct experimental evidence supported carbon partitioning to carbides and Ni to the reversed austenite. The reversed austenite almost always nucleated in contact with lath boundary M{sub 23}C{sub 6} carbides during tempering and the diffusion of Ni promoted its growth. The Ni enrichment and the ultrafine size of the reversed austenite were considered to be the main factors that accounted for the stability of the reversed austenite. - Highlights: • The amount of the reversed austenite formed at high temperature increases with the holding time. • STEM results directly show that carbon is mainly partitioned into the carbides and Ni into the reversed austenite. • The Ni enrichment and the ultrafine size are the main factors leading to the stabilization of the reversed austenite.

  19. Single component, reversible ionic liquids for energy applications

    Energy Technology Data Exchange (ETDEWEB)

    Vittoria Blasucci; Ryan Hart; Veronica Llopis Mestre; Dominique Julia Hahne; Melissa Burlager; Hillary Huttenhower; Beng Joo Reginald Thio; Pamela Pollet; Charles L. Liotta; Charles A. Eckert [Georgia Institute of Technology, Atlanta, GA (United States). Chemical & Biomolecular Engineering

    2010-06-15

    Single component, reversible ionic liquids have excellent potential as novel solvents for a variety of energy applications. Our energy industry is faced with many new challenges including increased energy consumption, depleting oil reserves, and increased environmental awareness. We report the use of reversible ionic liquids to solve two energy challenges: extraction of hydrocarbons from contaminated crude oil and carbon capture from power plant flue gas streams. Our reversible solvents are derived from silylated amine molecular liquids which react with carbon dioxide reversibly to form ionic liquids. Here we compare the properties of various silylated amine precursors and their corresponding ionic liquids. We show how the property changes are advantageous in the two aforementioned energy applications. In the case of hydrocarbon purification, we take advantage of the polarity switch between precursor and ionic liquid to enable separations. In carbon capture, our solvents act as dual physical and chemical capture agents for carbon dioxide. Finally, we show the potential economics of scale-up for both processes. 20 refs., 1 fig., 3 tabs.

  20. Reversible posterior leukoencephalopathy syndrome

    International Nuclear Information System (INIS)

    Lee, Eun Ja; Yu, Won Jong; Ahn, Kook Jin; Jung, So Lyung; Lee, Yeon Soo; Kim, Ji Chang; Kang, Si Won; Song, Chang Joon; Song, Soon-Young; Koo, Ja Hong; Kim, Man Deuk

    2001-01-01

    To review reversible posterior leukoencephalopathy syndrome. We reviewed 22 patients (M:F=3:19; age, 17-46 years) with the characteristic clinical and imaging features of reversible posterior leukoencephalopathy syndrome. All underwent brain MRI, and in three cases both CT and MRI were performed. In one, MRA was obtained, and in eleven, follow-up MR images were obtained. We evaluated the causes of this syndrome, its clinical manifestations, and MR findings including the locations of lesions, the presence or absence of contrast enhancement, and the changes seen at follow-up MRI. Of the 22 patients, 13 had eclampsia (six during pregnancy and seven during puerperium). Four were receiving immunosuppressive therapy (three, cyclosporine ; one, FK 506). Four suffered renal failure and one had complicated migraine. The clinical manifestations included headache (n=12), visual disturbance (n=13), seizure (n=15), focal neurologic sign (n=3), and altered mental status (n=2). Fifteen patients had hypertension and the others normotension. MRI revealed that lesions were bilateral (n=20) or unilateral (n=2). In all patients the lesion was found in the cortical and subcortical areas of the parieto-occipital lobes ; other locations were the basal ganglia (n=9), posterior temporal lobe (n=8), frontal lobe (n=5), cerebellum (n=5), pons (n=2), and thalamus (n=1). All lesions were of high signal intensity on T2-weighted images, and of iso to low intensity on T1-weighted images. One was combined with acute hematoma in the left basal ganglia. In eight of 11 patients who underwent postcontrast T1-weighted MRI, there was no definite enhancement ; in one, enhancement was mild, and in tow, patchy. CT studies showed low attenuation, and MRA revealed mild vasospasm. The symptoms of all patients improved. Follow-up MRI in nine of 11 patients depicted complete resolution of the lesions ; in two, small infarctions remained but the extent of the lesions had decreased. Reversible posterior