WorldWideScience

Sample records for carbon black particles

  1. CCN activation of pure and coated carbon black particles.

    Science.gov (United States)

    Dusek, U; Reischl, G P; Hitzenberger, R

    2006-02-15

    The CCN (cloud condensation nucleus) activation of pure and coated carbon black particles was investigated using the University of Vienna cloud condensation nuclei counter (Giebl, H.; Berner, A.; Reischl, G.; Puxbaum, H.; Kasper-Giebl, A.; Hitzenberger, R. J. Aerosol Sci. 2002, 33, 1623-1634). The particles were produced by nebulizing an aqueous suspension of carbon black in a Collison atomizer. The activation of pure carbon black particles was found to require higher supersaturations than predicted by calculations representing the particles as insoluble, wettable spheres with mobility equivalent diameter. To test whether this effect is an artifact due to heating of the light-absorbing carbon black particles in the laser beam, experiments at different laser powers were conducted. No systematic dependence of the activation of pure carbon black particles on laser power was observed. The observations could be modeled using spherical particles and an effective contact angle of 4-6 degrees of water at their surface. The addition of a small amount of NaCl to the carbon black particles (by adding 5% by mass NaCl to the carbon black suspension) greatly enhanced their CCN efficiency. The measured CCN efficiencies were consistent with Kohler theory for particles consisting of insoluble and hygroscopic material. However, coating the carbon black particles with hexadecanol (a typical film-forming compound with one hydrophobic and one hydrophilic end) efficiently suppressed the CCN activation of the carbon black particles.

  2. Worker exposure to ultrafine particles during carbon black treatment

    Directory of Open Access Journals (Sweden)

    Urszula Mikołajczyk

    2015-07-01

    Full Text Available Background: The aim of the project was to assess the exposure of workers to ultrafine particles released during handling and packing of carbon black. The assessment included the results of the measurements performed in a carbon black handling plant before, during, and after work shift. Material and Methods: The number concentration of particles within the dimension range 10–1000 nm and 10–100 nm was assayed by a condensation particle counter (CPC. The mass concentration of particles was determined by a DustTrak II DRX aerosol concentration monitor. The surface area concentration of the particles potentially deposited in the alveolar (A and tracheo-bronchial (TB regions was estimated by an AeroTrak 9000 nanoparticle monitor. Results: An average mass concentration of particles during the process was 6-fold higher than that before its start, while a 3-fold increase in the average number concentration of particles within the dimension range 10–1000 nm and 10–100 nm was observed during the process. At the same time a 4-fold increase was found in the surface area concentration of the particles potentially deposited in the A and TB regions. Conclusions: During the process of carbon black handling and packing a significantly higher values of each of the analysed parameters, characterizing the exposure to ultrafine particles, were noted. Med Pr 2015;66(3:317–326

  3. Influence of carbon black and indium tin oxide absorber particles on laser transmission welding

    Science.gov (United States)

    Aden, Mirko; Mamuschkin, Viktor; Olowinsky, Alexander

    2015-06-01

    For laser transmission welding of polypropylene carbon black and indium tin oxide (ITO) are used as absorber particles. Additionally, the colorant titanium dioxide is mixed to the absorbing part, while the transparent part is kept in natural state. The absorption coefficients of ITO and carbon black particles are obtained, as well as the scattering properties of polypropylene loaded with titanium dioxide (TiO2). At similar concentrations the absorption coefficient of ITO is an order of magnitude smaller than that of carbon black. Simulations of radiation propagation show that the penetration depth of laser light is smaller for carbon black. Therefore, the density of the released heat is higher. Adding TiO2 changes the distribution of heat in case of ITO, whereas for carbon black the effect is negligible. Thermal simulations reveal the influence of the two absorbers and TiO2 on the heat affected zone. The results of the thermal simulations are compared to tensile test results.

  4. Morphology and Optical Properties of Black-Carbon Particles Relevant to Engine Emissions

    Science.gov (United States)

    Michelsen, H. A.; Bambha, R.; Dansson, M. A.; Schrader, P. E.

    2013-12-01

    Black-carbon particles are believed to have a large influence on climate through direct radiative forcing, reduction of surface albedo of snow and ice in the cryosphere, and interaction with clouds. The optical properties and morphology of atmospheric particles containing black carbon are uncertain, and characterization of black carbon resulting from engines emissions is needed. Refractory black-carbon particles found in the atmosphere are often coated with unburned fuel, sulfuric acid, water, ash, and other combustion by-products and atmospheric constituents. Coatings can alter the optical and physical properties of the particles and therefore change their optical properties and cloud interactions. Details of particle morphology and coating state can also have important effects on the interpretation of optical diagnostics. A more complete understanding of how coatings affect extinction, absorption, and incandescence measurements is needed before these techniques can be applied reliably to a wide range of particles. We have investigated the effects of coatings on the optical and physical properties of combustion-generated black-carbon particles using a range of standard particle diagnostics, extinction, and time-resolved laser-induced incandescence (LII) measurements. Particles were generated in a co-flow diffusion flame, extracted, cooled, and coated with oleic acid. The diffusion flame produces highly dendritic soot aggregates with similar properties to those produced in diesel engines, diffusion flames, and most natural combustion processes. A thermodenuder was used to remove the coating. A scanning mobility particle sizer (SMPS) was used to monitor aggregate sizes; a centrifugal particle mass analyzer (CPMA) was used to measure coating mass fractions, and transmission electron microscopy (TEM) was used to characterize particle morphologies. The results demonstrate important differences in optical measurements between coated and uncoated particles.

  5. Worker exposure to ultrafine particles during carbon black treatment

    OpenAIRE

    Urszula Mikołajczyk; Stella Bujak-Pietrek; Irena Szadkowska-Stańczyk

    2015-01-01

    Wstęp: Celem badania była ocena uwalniania do powietrza stanowisk pracy cząstek ultradrobnych podczas przesypu i pakowania sadzy technicznej. Materiał i metody: Ocena obejmowała wyniki pomiarów przeprowadzonych w zakładzie przesypu sadzy technicznej przed rozpoczęciem procesu przesypu, w czasie wykonywania i po zakończeniu procesu. Określono stężenie liczbowe cząstek o wymiarach z zakresu 10–1000 nm i 10–100 nm z wykorzystaniem kondensacyjnego licznika cząstek (condensation particle cou...

  6. Online single particle measurements of black carbon coatings, structure and optical properties

    Science.gov (United States)

    Allan, James; Liu, Dantong; Taylor, Jonathan; Flynn, Michael; Williams, Paul; Morgan, William; Whitehead, James; Alfarra, Rami; McFiggans, Gordon; Coe, Hugh

    2016-04-01

    The impacts of black carbon on meteorology and climate remain a major source of uncertainty, owing in part to the complex relationship between the bulk composition of the particulates and their optical properties. A particular complication stems from how light interacts with particles in response to the microphysical configuration and any 'coatings', i.e. non-black carbon material that is either co-emitted or subsequently obtained through atmospheric processing. This may cause the particle to more efficiently absorb or scatter light and may even change the sign of its radiative forcing potential. While much insight has been gained through measurements of bulk aerosol properties, either while suspended or after collection on a filter or impactor substrate, this does not provide a complete picture and thus may not adequately constrain the system. Here we present an overview of recent work to better constrain the properties of black carbon using online, in situ measurements of single particles, primarily using a Single Particle Soot Photometer (SP2). We have developed novel methods of inverting the data produced and combining the different metrics derived so as to give the most effective insights into black carbon sources, processes and properties. We have also used this measurement in conjunction with other instruments (sometimes in series) and used the data to challenge many commonly used models of optical properties such as core-shell Mie, Rayleigh-Debeye-Gans and effective medium. This work has been carried out in a variety of atmospheric environments and with laboratory-produced soots, e.g. from a diesel engine rig. Highlights include the finding that with real-world atmospheric aerosols, bulk optical measurements may be insufficient to derive brown carbon parameters without detailed morphological data. We also show that the enhancement of absorption for both ambient and laboratory generated particles only occurs after the coating mass fraction reaches a certain

  7. Numerical modelling of the internal mixing by coagulation of black carbon particles in aircraft exhaust

    Energy Technology Data Exchange (ETDEWEB)

    Ohlsson, S.; Stroem, J. [Stockholm Univ. (Sweden). Dept. of Meteorology

    1997-12-31

    When exhaust gases from an aircraft engine mix with ambient air the humidity may reach water saturation and water droplets will form on the available cloud condensation nuclei (CCN). It is still not resolved if the CCN, on which the cloud droplets form, are mainly particles present in the ambient air or particles emitted by the aircraft. It the exhaust from a jet engine the particles are believed to consist mainly of black carbon (BC) and sulfate. The aim is to study, with the help of a numerical model, how a two-component aerosol (i.e. BC and sulfate) in an exhaust trail may be transformed in terms of hygroscopicity by coagulation mixing and how this may depend on the sulfur content in the fuel. (R.P.) 15 refs.

  8. Ice nucleating particles from biomass combustion: emission rates and the role of refractory black carbon

    Science.gov (United States)

    Levin, E. J.; McMeeking, G. R.; McCluskey, C. S.; Carrico, C. M.; Nakao, S.; Stockwell, C.; Yokelson, R. J.; Sullivan, R. C.; DeMott, P. J.; Kreidenweis, S. M.

    2015-12-01

    Ice nucleating particles (INPs) allow initial ice crystal formation in clouds at temperatures warmer than about -36 °C and are thus important for cloud and precipitation development. One potential source of INPs to the atmosphere is biomass combustion, such as wildfires, prescribed burning and agricultural burning, which emits large quantities of particulate matter into the atmosphere and is a major source of black carbon (BC) aerosol. To better understand and constrain INP emissions from biomass combustion, globally relevant fuels were used in a series of burns during a study called FLAME 4 at the USFS Fire Sciences Laboratory in Missoula, MT. Concentrations of immersion mode INPs were measured using a Colorado State University Continuous Flow Diffusion Chamber (CFDC). During the first part of the study, emissions were measured in real time as fires progressed from ignition to flaming and smoldering phases. INP emissions were observed predominately during periods of intensely flaming combustion. Roughly 75% of measured burns produced detectable INP concentrations and these had, on average, higher combustion efficiencies and higher BC emissions. During the second half of FLAME 4, we directly measured the contribution of refractory black carbon (rBC) to INP concentrations by selectively removing these particles via laser-induced incandescence (LII) using a Single Particle Soot Photometer (SP2; Droplet Measurement Technologies). The SP2 uses a 1064 nm Na:YAG laser to heat rBC aerosol to their vaporization temperatures, thus removing them from the sampled aerosol. By passing combustion aerosol through the SP2 with the laser on and off while measuring the remaining aerosol with the CFDC, we were able to determine the contribution of rBC to the INP population. Reductions in INPs of 0 - 70% were observed when removing rBC from the combustion aerosol, indicating the importance of rBC particles to INP concentrations for some burn scenarios.

  9. Collection efficiency of the soot-particle aerosol mass spectrometer (SP-AMS) for internally mixed particulate black carbon

    Science.gov (United States)

    Willis, M. D.; Lee, A. K. Y.; Onasch, T. B.; Fortner, E. C.; Williams, L. R.; Lambe, A. T.; Worsnop, D. R.; Abbatt, J. P. D.

    2014-12-01

    The soot-particle aerosol mass spectrometer (SP-AMS) uses an intra-cavity infrared laser to vaporize refractory black carbon (rBC) containing particles, making the particle beam-laser beam overlap critical in determining the collection efficiency (CE) for rBC and associated non-refractory particulate matter (NR-PM). This work evaluates the ability of the SP-AMS to quantify rBC and NR-PM mass in internally mixed particles with different thicknesses of organic coating. Using apparent relative ionization efficiencies for uncoated and thickly coated rBC particles, we report measurements of SP-AMS sensitivity to NR-PM and rBC, for Regal Black, the recommended particulate calibration material. Beam width probe (BWP) measurements are used to illustrate an increase in sensitivity for highly coated particles due to narrowing of the particle beam, which enhances the CE of the SP-AMS by increasing the laser beam-particle beam overlap. Assuming complete overlap for thick coatings, we estimate CE for bare Regal Black particles of 0.6 ± 0.1, which suggests that previously measured SP-AMS sensitivities to Regal Black were underestimated by up to a factor of 2. The efficacy of the BWP measurements is highlighted by studies at a busy road in downtown Toronto and at a non-roadside location, which show particle beam widths similar to, but greater than that of bare Regal Black and coated Regal Black, respectively. Further BWP measurements at field locations will help to constrain the range of CE for fresh and aged rBC-containing particles. The ability of the SP-AMS to quantitatively assess the composition of internally mixed particles is validated through measurements of laboratory-generated organic coated particles, which demonstrate that the SP-AMS can quantify rBC and NR-PM over a wide range of particle compositions and rBC core sizes.

  10. Black carbon absorption at the global scale is affected by particle-scale diversity in composition

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    Fierce, Laura; Bond, Tami C.; Bauer, Susanne E.; Mena, Francisco; Riemer, Nicole

    2016-09-01

    Atmospheric black carbon (BC) exerts a strong, but uncertain, warming effect on the climate. BC that is coated with non-absorbing material absorbs more strongly than the same amount of BC in an uncoated particle, but the magnitude of this absorption enhancement (Eabs) is not well constrained. Modelling studies and laboratory measurements have found stronger absorption enhancement than has been observed in the atmosphere. Here, using a particle-resolved aerosol model to simulate diverse BC populations, we show that absorption is overestimated by as much as a factor of two if diversity is neglected and population-averaged composition is assumed across all BC-containing particles. If, instead, composition diversity is resolved, we find Eabs=1-1.5 at low relative humidity, consistent with ambient observations. This study offers not only an explanation for the discrepancy between modelled and observed absorption enhancement, but also demonstrates how particle-scale simulations can be used to develop relationships for global-scale models.

  11. Markedly enhanced direct radiative forcing of black carbon particles under polluted urban environments

    Science.gov (United States)

    Peng, Jianfei; Hu, Min; Guo, Song; Du, Zhuofei; Zheng, Jing; Shang, Dongjie; Zamora, Misti; Zeng, Liming; Shao, Min; Wu, Yusheng; Zheng, Jun; Wang, Yuan; Collins, Don; Zhang, Renyi

    2016-04-01

    Black carbon (BC) particles, produced from incomplete fossil fuel combustion and biomass burning, are ubiquitous in the atmosphere and have profound impacts on air quality, human health, weather, and climate. For example, in areas identified as aerosol hotspots, which include many urban centers and megacities worldwide, solar heating by BC particles has been shown to be comparable to warming due to the greenhouse gases2. Although BC represents a key short-lived climate forcer, its direct radiative forcing remains highly uncertain. In particular, the available results of absorption enhancement of BC particles during atmospheric aging are conflicting from the previous studies, leading to a large uncertainty in global radiative transfer calculation. Here, we quantified the aging and variation in the optical properties of BC particles under ambient conditions in Beijing, China and Houston, US, using a novel chamber approach. BC aging exhibits two distinct stages - initial transformation from a fractal to spherical morphology with little absorption variation and the subsequent growth of fully compact particles with a maximum absorption enhancement factor of 2.4. The variation in BC direct radiative forcing is highly dependent of the rate and timescale of aging, with an estimated increase of 0.45 (0.21 - 0.80) W m-2 from fresh to fully aged particles. Our results reveal a high climatic impact in polluted environments due to rapid aging and a clear distinction between urban cities in developed and developing countries for BC particles, highlighting a larger than recognized co-benefit in air quality improvement and climate protection by BC mediation.

  12. Black Carbon Particle Number Distribution Measurements during the ATHENS-2013 Winter Campaign

    Science.gov (United States)

    Gkatzelis, Georgios; Papanastasiou, Dimitris; Florou, Kalliopi; Kaltsonoudis, Christos; Louvaris, Eyaggelos; Bezentakos, Spiridon; Biskos, Georgios; Pandis, Spuros

    2014-05-01

    Black Carbon (BC) particles emitted by anthropogenic sources play an important role both in climate change and in air quality degradation. Open burning in forests and savannas, combustion of diesel and solid fuels for cooking and heating in homes represent the majority of BC emissions. Earlier work has focused on the BC atmospheric direct radiative forcing that is mostly related to its mass concentration and optical properties of the corresponding particles. A variety of measurement techniques are used to measure the mass concentration of BC by taking advantage of its optical or physical properties. Moreover, the carbonaceous particles containing BC are also important for the indirect forcing of climate. This effect is mostly related to the number concentration of BC particles. The number distribution of BC particles especially below 100 nm is quite uncertain due to limitations of the existing measurement techniques. In this work we employed a thermodenuder-based method as an approach for the measurement of the BC number distribution. More specifically, we combined a thermodenuder (TD) operating at temperatures up to 300 ° C, with a Scanning Mobility Particle Sizer (SMPS) and a High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF AMS). Aerosol size and composition measurements were carried out both at ambient and at elevated TD temperatures in Athens field campaign during January and February of 2013. In parallel, a Multi-Angle Absorption Photometer (MAAP) provided information about the BC mass concentration while a Hygroscopic Tandem Differential Mobility Analyzer (HTDMA) measured the mixing state and the hygroscopicity of the particles as a function of their size. These measurements were then combined to estimate the number concentration of BC particles. Our analysis focused on different periods during the study. During some of them one source dominated the carbonaceous aerosol concentration. Such periods included rush hour traffic, nighttime wood

  13. On-bicycle exposure to particulate air pollution: Particle number, black carbon, PM2.5, and particle size

    Science.gov (United States)

    Hankey, Steve; Marshall, Julian D.

    2015-12-01

    Inhalation of air pollution during transport is an important exposure pathway, especially for certain modes of travel and types of particles. We measured concentrations of particulate air pollution (particle number [PN], black carbon [BC], fine particles [PM2.5], particle size) using a mobile, bicycle-based monitoring platform during morning and afternoon rush-hour to explore patterns of exposure while cycling (34 days between August 14 and October 16, 2012 in Minneapolis, MN). Measurements were geo-located at 1 ​s intervals along 3 prescribed monitoring routes totaling 85 h (1426 km) of monitoring. Mean morning [afternoon] on-road concentrations were 32,500 [16,600] pt cm-3, 2.5 [0.7] μg m-3 BC, 8.7 [8.3] μg m-3 PM2.5, and 42 [39] nm particle diameter. Concentrations were correlated with street functional class and declined within small distances from a major road (e.g., for PN and BC, mean concentration decreased ∼20% by moving 1 block away from major roads to adjacent local roads). We estimate the share of on-bicycle exposure attributable to near-traffic emissions (vs. regional pollution) is ∼50% for PN and BC; ∼25% for PM2.5. Regression models of instantaneous traffic volumes, derived from on-bicycle video recordings of nearby traffic, quantify the increase in particle-concentrations associated with each passing vehicle; for example, trucks were associated with acute, high concentration exposure events (average concentration-increase per truck: 31,000 pt cm-3, 1.0 μg m-3 PM2.5, 1.6 μg m-3 BC). Our findings could be used to inform design of low-exposure bicycle networks in urban areas.

  14. Lack of acute phase response in the livers of mice exposed to diesel exhaust particles or carbon black by inhalation

    OpenAIRE

    Williams Andrew; Møller Peter; Boisen Anne; Bornholdt Jette; Folkmann Janne K; Halappanavar Sabina; Saber Anne T; Yauk Carole; Vogel Ulla; Loft Steffen; Wallin Håkan

    2009-01-01

    Abstract Background Epidemiologic and animal studies have shown that particulate air pollution is associated with increased risk of lung and cardiovascular diseases. Although the exact mechanisms by which particles induce cardiovascular diseases are not known, studies suggest involvement of systemic acute phase responses, including C-reactive protein (CRP) and serum amyloid A (SAA) in humans. In this study we test the hypothesis that diesel exhaust particles (DEP) – or carbon black (CB)-induc...

  15. Surface area of particle administered versus mass in determining the pulmonary toxicity of ultrafine and fine carbon black: comparison to ultrafine titanium dioxide

    Directory of Open Access Journals (Sweden)

    Sager Tina M

    2009-05-01

    Full Text Available Abstract Background Nanoparticles are characterized by having a high surface area per mass. Particulate surface area has been reported to play an important role in determining the biological activity of nanoparticles. However, recent reports have questioned this relationship. This study was conducted to determine whether mass of particles or surface area of particles is the more appropriate dose metric for pulmonary toxicity studies. In this study, rats were exposed by intratracheal instillation to various doses of ultrafine and fine carbon black. At 1, 7, or 42 days post-exposure, inflammatory and cytotoxic potential of each particle type was compared on both a mass dosage (mg/rat as well as an equal surface area dosage (cm2 of particles per cm2 of alveolar epithelium. In an additional study, the pulmonary responses to instillation of ultrafine carbon black were compared to equivalent particle surface area doses of ultrafine titanium dioxide. Results Ultrafine carbon black particles caused a dose dependent but transient inflammatory and cytotoxic response. On a mass basis, these responses were significantly (65 fold greater than those for fine sized carbon black. However, when doses were equalized based on surface area of particles given, the ultrafine carbon black particles were only slightly (non-significantly more inflammogenic and cytotoxic compared to the fine sized carbon black. At one day post-exposure, inflammatory potencies of the ultrafine carbon black and ultrafine titanium dioxide particles were similar. However, while the pulmonary reaction to ultrafine carbon black resolved with time, the inflammatory effects of ultrafine titanium dioxide were more persistent over a 42 day post-exposure period. Conclusion These results indicate that for low toxicity low solubility materials, surface area of particles administered rather than mass burden of particles may be a more appropriate dose metric for pulmonary toxicity studies. In addition

  16. Effect of the particle shape on the optical properties of black carbon aggregates

    Science.gov (United States)

    Skorupski, Krzysztof

    2016-04-01

    Small particles tend to connect to each other and create large geometries, namely aggregates. To simplify the light scattering simulation process, they are usually modelled as assemblies of spheres positioned in point contact. This is a rough approximation because connections between them always exist. In this work we present answers to the three following questions: which optical properties of fractal-like aggregates are strongly dependent on the particle shape, what is the magnitude of the relative extinction error σCext when non-spherical particles are modelled as spheres and whether the relative extinction error σCext is dependent on the aggregate size Np. The paper was aimed at tropospheric black carbon particles and their complex refractive index m was based on the work by Chang and Charalampopoulos. The incident wavelength λ varied from λ = 300nm to λ = 900nm. For the light scattering simulations the ADDA algorithm was used. The polarizability expression was IGT_SO (approximate Integration of Greens Tensor over the dipole) and each particle, regardless of its shape, was composed of ca. Nd ≍ 1000 volume elements (dipoles). In the study, fractal-like aggregates consisted of up to Np = 300 primary particles with the volume equivalent to the volume of a sphere with the radius rp = 15nm. The fractal dimension was Df = 1:8 and the fractal prefactor was kf = 1:3. Geometries were generated with the tunable CC (Cluster-Cluster) algorithm proposed by Filippov et al. The results show that when the extinction cross section σCext is considered, the changes caused by the particle shape, which are especially visible for longer wavelengths λ cannot be neglected. The most significant difference can be observed for the regular tetrahedron. The relative extinction error σCext diminishes slightly along with the number of primary particles Np. However, even when large fractal-like aggregates are studied, it should not be considered as non-existent. On the contrary

  17. Concentrations of fine, ultrafine, and black carbon particles in auto-rickshaws in New Delhi, India

    Science.gov (United States)

    Apte, Joshua, S.; Kirchstetter, Thomas W.; Reich, Alexander, H.; Deshpande, Shyam J.; Kaushik, Geetanjali; Chel, Arvind; Marshall, Julian D.; Nazaroff, William W.

    2011-08-01

    Concentrations of air pollutants from vehicles are elevated along roadways, indicating that human exposure in transportation microenvironments may not be adequately characterized by centrally located monitors. We report results from ˜180 h of real-time measurements of fine particle and black carbon mass concentration (PM 2.5, BC) and ultrafine particle number concentration (PN) inside a common vehicle, the auto-rickshaw, in New Delhi, India. Measured exposure concentrations are much higher in this study (geometric mean for ˜60 trip-averaged concentrations: 190 μg m -3 PM 2.5, 42 μg m -3 BC, 280 × 10 3 particles cm -3; GSD ˜1.3 for all three pollutants) than reported for transportation microenvironments in other megacities. In-vehicle concentrations exceeded simultaneously measured ambient levels by 1.5× for PM 2.5, 3.6× for BC, and 8.4× for PN. Short-duration peak concentrations (averaging time: 10 s), attributable to exhaust plumes of nearby vehicles, were greater than 300 μg m -3 for PM 2.5, 85 μg m -3 for BC, and 650 × 10 3 particles cm -3 for PN. The incremental increase of within-vehicle concentration above ambient levels—which we attribute to in- and near-roadway emission sources—accounted for 30%, 68% and 86% of time-averaged in-vehicle PM 2.5, BC and PN concentrations, respectively. Based on these results, we estimate that one's exposure during a daily commute by auto-rickshaw in Delhi is as least as large as full-day exposures experienced by urban residents of many high-income countries. This study illuminates an environmental health concern that may be common in many populous, low-income cities.

  18. Optimized method for black carbon analysis in ice and snow using the Single Particle Soot Photometer

    Directory of Open Access Journals (Sweden)

    I. A. Wendl

    2014-03-01

    Full Text Available In this study we attempt to optimize the method for measuring black carbon (BC in snow and ice using a single particle soot photometer (SP2. Beside the previously applied ultrasonic (CETAC and Collison-type nebulizers we introduce a jet (APEX-Q nebulizer to aerosolize the aqueous sample for SP2 analysis. Both CETAC and APEX-Q require small sample volumes (few milliliters which makes them suitable for ice core analysis. The APEX-Q shows the least size-dependent nebulizing efficiency in the BC particle diameter range of 100–1000 nm. The CETAC has the advantage that air and liquid flows can be monitored continuously. All nebulizer-types require a calibration with BC standards for the determination of the BC mass concentration in unknown aqueous samples. We found Aquadag to be a suitable material for preparing calibration standards. Further, we studied the influence of different treatments for fresh discrete snow and ice samples as well as the effect of storage. The results show that samples are best kept frozen until analysis. Once melted, they should be sonicated for 25 min, immediately analyzed while being stirred and not be refrozen.

  19. Ambient black carbon particle hygroscopic properties controlled by mixing state and composition

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    D. Liu

    2012-11-01

    Full Text Available The wet removal of black carbon aerosol (BC in the atmosphere is a crucial factor in determining its atmospheric lifetime and thereby the vertical and horizontal distributions, dispersion on local and regional scales, and the direct, semi-direct and indirect radiative forcing effects. The in-cloud scavenging and wet deposition rate of freshly emitted hydrophobic BC will be increased on acquisition of more-hydrophilic components by coagulation or coating processes. The lifetime of BC is still subject to considerable uncertainty for most of the model inputs, which is largely due to the insufficient constraints on the BC hydrophobic-to-hydrophilic conversion process from observational field data. This study was conducted at a site along UK North Norfolk coastline, where the BC particles were transported from different regions within Western Europe. A hygroscopicity tandem differential mobility analyser (HTDMA was coupled with a single particle soot photometer (SP2 to measure the hygroscopic properties of BC particles and associated mixing state in real time. In addition, a Soot Particle AMS (SP-AMS measured the chemical compositions of additional material associated with BC particles. The ensemble of BC particles persistently contained a less-hygroscopic mode at a growth factor (gf of around 1.05 at 90% RH (dry diameter 163 nm. Importantly, a more-hygroscopic mode of BC particles was observed throughout the experiment, the gf of these BC particles extended up to ~1.4–1.6 with the minimum between this and the less hygroscopic mode at a gf ~1.25, or equivalent effective hygroscopicity parameter κ = ~0.1. The gf of BC particles (gfBC was highly influenced by the composition of associated soluble material: increases of gfBC were associated with secondary inorganic components, and these increases were more pronounced when ammonium nitrate was in the BC particles; however the presence of secondary organic matter suppressed the gf

  20. Emissions of Black Carbon Particles in Anthropogenic and Biomass Plumes over California during CARB 2008

    Science.gov (United States)

    Sahu, L. K.; Kondo, Y.; Moteki, N.; Takegawa, N.; Zhao, Y.; Vay, S. A.; Diskin, G. S.; Wisthaler, A.; Huey, L. G.

    2009-12-01

    Measurements of black carbon (BC) and other chemical species were made from the NASA DC-8 aircraft during the CARB campaign conducted over California in June 2008. We operated an SP2 system that measured BC and scattering particles. The vertical profiles of BC and scattering particles show enhancements in the lower troposphere. We have used relations of CO-CH3CN-SO2 to identify the sources of major plumes. The plumes originating from anthropogenic activities, mainly due to the use of fossil fuels (FF), were observed near the surface. However, the influence of smoke plumes from wild fire or biomass-burning (BB) sources was observed up to 3 km. Overall, the 1-minute average BC mass concentrations were in the ranges of about 90-500 ng/m3 and 300-700 ng/m3 in FF and BB plumes, respectively. The shell/core diameter ratios were much lagerer in BB plumes than those in FF plumes. Namely, the median shell/core ratios were 1.2-1.4 for FF plumes, while they were 1.4-1.7 for BB plumes. In both FF and BB plumes, the mass-size distributions of BC were single mode lognormal. However, the mass median diameters FF plumes were considerably smaller. The BC-CO2 regression slopes were 19±9 ng m-3/ppmv and 270±90 ng m-3/ppmv for FF and BB plumes, respectively. On the other hand the regression slopes of BC-CO were about 3.3 ng m-3/ppbv in both the plumes. Conversely, the regression slopes of BC with other co-emitted combustions products can be used to estimate the contributions of emissions from different sources.

  1. Sensitivity of the Single Particle Soot Photometer to different black carbon types

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    M. Laborde

    2012-05-01

    Full Text Available Black carbon (BC is now mainly of anthropogenic origin. It is the dominant light absorbing component of atmospheric aerosols, playing an important role in the earth's radiative balance and therefore relevant to climate change studies. In addition, BC is known to be harmful to human beings making it relevant to policy makers. Nevertheless, the measurement of BC remains biased by the instrument-based definition of BC. The Single Particle Soot Photometer (SP2, allows the measurement of the refractory BC (rBC mass of individual particles using laser-induced incandescence. However, the SP2 needs an empirical calibration to retrieve the rBC mass from the incandescence signal and the sensitivity of the SP2 differs between different BC types. Ideally, for atmospheric studies, the SP2 should be calibrated using ambient particles containing a known mass of ambient rBC. However, such "ambient BC" calibration particles cannot easily be obtained and thus commercially available BC particles are commonly used for SP2 calibration instead. In this study we tested the sensitivity of the SP2 to different BC types in order to characterize the potential error introduced by using non-ambient BC for calibration. The sensitivity of the SP2 was determined, using an aerosol particle mass analyzer, for rBC from thermodenuded diesel exhaust, wood burning exhaust and ambient particles as well as for commercially available products: Aquadag® and fullerene soot.

    Thermodenuded, fresh diesel exhaust has been found to be ideal for SP2 calibration for two reasons. First, the small amount of non-BC matter upon emission reduces the risk of bias due to incomplete removal of non-BC matter and second, it is considered to represent atmospheric rBC in urban locations where diesel exhaust is the main source of BC. The SP2 was found to be up to 16% less sensitive to rBC from thermodenuded ambient particles (≤15 fg than rBC from diesel exhaust, however, at least part

  2. Sensitivity of the Single Particle Soot Photometer to different black carbon types

    Directory of Open Access Journals (Sweden)

    M. Laborde

    2012-01-01

    Full Text Available Black carbon (BC is nowadays mainly of anthropogenic origin. It is the dominant light absorbing component of atmospheric aerosols, playing an important role in the earth's radiative balance and therefore relevant to climate change studies. In addition, BC is known to be harmful to humans making it relevant to policy makers. Nevertheless, the measurement of BC remains biased by the instrument-based definition of BC. The Single Particle Soot Photometer (SP2, allows the measurement of the refractory BC (rBC mass of individual particle using laser-induced incandescence. However the SP2 needs an empirical calibration to retrieve the rBC mass from the incandescence signal and the sensitivity of the SP2 differs between different BC types. Ideally, for atmospheric studies, the SP2 should be calibrated using ambient particles containing a known mass of ambient rBC. However, such "ambient BC" calibration particles cannot easily be obtained and thus commercially available BC particles are commonly used for SP2 calibration instead. In this study we tested the sensitivity of the SP2 to different BC types in order to characterize the potential error introduced by using non-ambient BC for calibration. The sensitivity of the SP2 was determined for rBC from thermodenuded diesel exhaust, wood burning exhaust and ambient particles as well as for commercially available products: Aquadag® and fullerene soot.

    Thermodenuded, fresh diesel exhaust has been found to be ideal for SP2 calibration for two reasons. First, the small amount of non-BC matter upon emission reduces the risk of bias due to incomplete removal of non-BC matter and second, it is considered to represent atmospheric rBC as diesel exhaust is the main source of BC in most locations. The SP2 was found to be up to 16% less sensitive to rBC from thermodenuded ambient particles (≤15 fg than rBC from diesel exhaust, however, at least part of this difference can be explained by

  3. Measurement of Black Carbon and Particle Number Emission Factors from Individual Heavy-Duty Trucks

    Energy Technology Data Exchange (ETDEWEB)

    Ban-Weiss, George A.; Lunden, Melissa M.; Kirchstetter, Thomas W.; Harley, Robert A.

    2009-02-02

    Emission factors for black carbon (BC) and particle number (PN) were measured from 226 individual heavy-duty (HD) diesel-fueled trucks driving through a 1 km-long California highway tunnel in August 2006. Emission factors were based on concurrent increases in BC, PN, and CO{sub 2}B concentrations (measured at 1 Hz) that corresponded to the passage of individual HD trucks. The distributions of BC and PN emission factors from individual HD trucks are skewed, meaning that a large fraction of pollution comes from a small fraction of the in-use vehicle fleet. The highest-emitting 10% of trucks were responsible for {approx} 40% of total BC and PN emissions from all HD trucks. BC emissions were log-normally distributed with a mean emission factor of 1.7 g kg {sup -1} and maximum values of {approx} 10 g kg{sup -1}. Corresponding values for PN emission factors were 4.7 x 10{sup 15} and 4 x 10{sup 16} kg{sup -1}. There was minimal overlap among high-emitters of these two pollutants: only 1 of the 226 HD trucks measured was found to be among the highest 10% for both BC and PN. Monte Carlo resampling of the distribution of BC emission factors observed in this study revealed that uncertainties (1{sigma}) in extrapolating from a random sample of n HD trucks to a population mean emission factor ranged from {+-} 43% for n = 10 to {+-} 8% for n = 300, illustrating the importance of sufficiently large vehicle sample sizes in emissions studies. Studies with low sample sizes are also more easily biased due to misrepresentation of high-emitters. As vehicles become cleaner on average in future years, skewness of the emissions distributions will increase, and thus sample sizes needed to extrapolate reliably from a subset of vehicles to the entire in-use vehicle fleet are expected to become more of a challenge.

  4. Arctic Black Carbon Loading and Profile Using the Single-Particle Soot Photometer (SP2) Field Campaign Report

    Energy Technology Data Exchange (ETDEWEB)

    Sedlacek, Arthur J [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2016-05-01

    One of the major issues confronting aerosol climate simulations of the Arctic and Antarctic cryospheres is the lack of detailed data on the vertical and spatial distribution of aerosols with which to test these models. This is due, in part, to the inherent difficulty of conducting such measurements in extreme environments. However given the pronounced sensitivity of the polar regions to radiative balance perturbations, it is incumbent upon our community to better understand and quantify these perturbations, and their unique feedbacks, so that robust model predictions of this region can be realized. One class of under-measured radiative forcing agents in the polar region is the absorbing aerosol—black carbon and brown carbon. Black carbon (BC; also referred to as light-absorbing carbon [LAC], refractory black carbon [rBC], and soot) is second only to CO2 as a positive forcing agent. Roughly 60% of BC emissions can be attributed to anthropogenic sources (fossil fuel combustion and open-pit cooking), with the remaining fraction being due to biomass burning. Brown carbon (BrC), a major component of biomass burning, collectively refers to non-BC carbonaceous aerosols that typically possess minimal light absorption at visible wavelengths but exhibit pronounced light absorption in the near-ultraviolet (UV) spectrum. Both species can be sourced locally or be remotely transported to the Arctic region and are expected to perturb the radiative balance. The work conducted in this field campaign addresses one of the more glaring deficiencies currently limiting improved quantification of the impact of BC radiative forcing in the cryosphere: the paucity of data on the vertical and spatial distributions of BC. By expanding the Gulfstream aircraft (G-1) payload for the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility-sponsored ACME-V campaign to include the Single-Particle Soot Photometer (SP2)) and leveraging the ACME-V campaign

  5. The Study on the Conductivity Performance and Shielding Effectiveness of Electro-magnetic Radiation of Polyethylene Film with Different Content of Carbon Black Particles

    Institute of Scientific and Technical Information of China (English)

    SUN Run-jun; LAI Kan; ZHANG Jian-chun; HUO Yan

    2004-01-01

    With the help of the testing apparatus made by ourselves for shielding electromagnetic radiation, the electric conductivity and shielding effectiveness of electromagnetic radiation of polyethylene film contained different content of carbon particles was systematically studied in this paper. The results indicate that the electric conductivity and shielding effectiveness of electromagnetic radiation of polyethylene /carbon film have closely relations with content of carbon black particles, which exists a critical content value as 14%~30% and its properties will have a tremendous change.

  6. Lack of acute phase response in the livers of mice exposed to diesel exhaust particles or carbon black by inhalation

    DEFF Research Database (Denmark)

    Saber, Anne T; Halappanavar, Sabina; Folkmann, Janne K;

    2009-01-01

    BACKGROUND: Epidemiologic and animal studies have shown that particulate air pollution is associated with increased risk of lung and cardiovascular diseases. Although the exact mechanisms by which particles induce cardiovascular diseases are not known, studies suggest involvement of systemic acute...... phase responses, including C-reactive protein (CRP) and serum amyloid A (SAA) in humans. In this study we test the hypothesis that diesel exhaust particles (DEP) - or carbon black (CB)-induced lung inflammation initiates an acute phase response in the liver. RESULTS: Mice were exposed to filtered air......, 20 mg/m3 DEP or CB by inhalation for 90 minutes/day for four consecutive days; we have previously shown that these mice exhibit pulmonary inflammation (Saber AT, Bornholdt J, Dybdahl M, Sharma AK, Loft S, Vogel U, Wallin H. Tumor necrosis factor is not required for particle-induced genotoxicity and...

  7. Carbon black recovery

    International Nuclear Information System (INIS)

    A process and apparatus for recovering carbon black from hot smoke which comprises passing the smoke through a cyclone separation zone following cooling, then through aggregate filter beds and regeneration of filter beds with clean off-gas which is recycled to the carbon black reaction zone as quench

  8. A reliable light scattering computing for black carbon-containing particles: Hybrid discrete dipole approximation (h-DDA)

    Science.gov (United States)

    Moteki, N.

    2015-12-01

    Black carbon (BC) is a light-absorbing carbonaceous aerosol emitted from combustions of fossil fuels and biomasses and is estimated as the second most important contributor to positive climate forcing after the carbon dioxide. In the atmosphere, the fractal aggregate of BC-spherules may be mixed with non-absorbing (or weakly absorbing) compounds that forms morphologically complex "BC-containing particle". A reliable scattering code for BC-containing particles is necessary for predicting mass absorption efficiency of BC and designing/evaluating optical techniques for estimating microphysical properties (i.e., size distribution, mixing state, shape, refractive index) of BC-containing particles. The computational methods that derived from the volume-integral form of the Maxwell equation, such as discrete dipole approximation (DDA), are method of choice for morphologically complex object like BC-containing particles. In ordinary DDA, the entire particle volume is approximated as a collection of tiny cubical dipoles (with side length d) placed on a 3D cubic lattice. For several model BC-containing particles, the comparisons with numerically exact T-matrix method reveals that the ordinary DDA suffered from persistent positive systematic error (up to +30%) in absorption even under d DDA error is identified to be the shape error in BC-spherules. To eliminate the shape error in BC-spherules, we propose a new DDA methodology which may be called hybrid DDA (h-DDA): each primary BC sphere is assumed as a spherical dipole, while remaining particle volume of coating material is approximated by a collection of tiny cubical dipoles on a 3D cubic lattice. Positive absorption bias up to +30% in ordinary DDA is suppressed to within 3% in h-DDA. In h-DDA code, an efficient FFT-based algorithm for solving the matrix equation has been implemented, by utilizing the multilevel block-Toeplitz property of the submatrix corresponding to inter-dipole interaction within coating material.

  9. Effect of the secondary organic aerosol coatings on black carbon water uptake, cloud condensation nuclei activity, and particle collapse

    Science.gov (United States)

    The ability of black carbon aerosols to absorb water and act as a cloud condensation nuclei (CCN) directly controls their lifetime in the atmosphere as well as their impact on cloud formation, thus impacting the earth’s climate. Black carbon emitted from most combustion pro...

  10. Source apportionment of wide range particle size spectra and black carbon collected at the airport of Venice (Italy)

    Science.gov (United States)

    Masiol, Mauro; Vu, Tuan V.; Beddows, David C. S.; Harrison, Roy M.

    2016-08-01

    Atmospheric particles are of high concern due to their toxic properties and effects on climate, and large airports are known as significant sources of particles. This study investigates the contribution of the Airport of Venice (Italy) to black carbon (BC), total particle number concentrations (PNC) and particle number size distributions (PNSD) over a large range (14 nm-20 μm). Continuous measurements were conducted between April and June 2014 at a site located 110 m from the main taxiway and 300 m from the runway. Results revealed no significantly elevated levels of BC and PNC, but exhibited characteristic diurnal profiles. PNSD were then analysed using both k-means cluster analysis and positive matrix factorization. Five clusters were extracted and identified as midday nucleation events, road traffic, aircraft, airport and nighttime pollution. Six factors were apportioned and identified as probable sources according to the size profiles, directional association, diurnal variation, road and airport traffic volumes and their relationships to micrometeorology and common air pollutants. Photochemical nucleation accounted for ∼44% of total number, followed by road + shipping traffic (26%). Airport-related emissions accounted for ∼20% of total PNC and showed a main mode at 80 nm and a second mode beyond the lower limit of the SMPS (international airport located in area affected by a complex emission scenario. The results may underpin measures for improving local and regional air quality, and health impact assessment studies.

  11. Admix Compatibility in Carbon Black Loaded Toners

    Institute of Scientific and Technical Information of China (English)

    Paul C. Julien

    2004-01-01

    In a xerographic system where the charge on the toner is controlled by the electrical nature of the carbon black used as a pigment, it is found that the speed with which added toner is charged to the proper level depends on the relative electrical negativity of the carbon black in the original and added toner. This is due to the fact that the incumbent toner typically shares its charge with the new toner through charge exchange among the conductive carbon black particles. If the carbon blacks are electrically dissimilar, this charge sharing may fail.Thus, a toner may work well by itself in a machine, but the same toner may fail when added to a machine already running with a toner from a different vendor or even a different lot of toner from the same vendor. Thus the electrical nature of the carbon black needs to be controlled. This can be done by controlling the oxidation of the carbon black.

  12. Source apportionment of wide range particle size spectra and black carbon collected at the airport of Venice (Italy)

    Science.gov (United States)

    Masiol, Mauro; Vu, Tuan V.; Beddows, David C. S.; Harrison, Roy M.

    2016-08-01

    Atmospheric particles are of high concern due to their toxic properties and effects on climate, and large airports are known as significant sources of particles. This study investigates the contribution of the Airport of Venice (Italy) to black carbon (BC), total particle number concentrations (PNC) and particle number size distributions (PNSD) over a large range (14 nm-20 μm). Continuous measurements were conducted between April and June 2014 at a site located 110 m from the main taxiway and 300 m from the runway. Results revealed no significantly elevated levels of BC and PNC, but exhibited characteristic diurnal profiles. PNSD were then analysed using both k-means cluster analysis and positive matrix factorization. Five clusters were extracted and identified as midday nucleation events, road traffic, aircraft, airport and nighttime pollution. Six factors were apportioned and identified as probable sources according to the size profiles, directional association, diurnal variation, road and airport traffic volumes and their relationships to micrometeorology and common air pollutants. Photochemical nucleation accounted for ∼44% of total number, followed by road + shipping traffic (26%). Airport-related emissions accounted for ∼20% of total PNC and showed a main mode at 80 nm and a second mode beyond the lower limit of the SMPS (factors accounted for less than 10% of number counts, but were relevant for total volume concentrations: nighttime nitrate, regional pollution and local resuspension. An analysis of BC levels over different wind sectors revealed no especially significant contributions from specific directions associated with the main local sources, but a potentially significant role of diurnal dynamics of the mixing layer on BC levels. The approaches adopted in this study have identified and apportioned the main sources of particles and BC at an international airport located in area affected by a complex emission scenario. The results may underpin

  13. Black carbon in marine sediments

    NARCIS (Netherlands)

    Middelburg, J.J.; Nieuwenhuize, J.; Van Breugel, P.

    1999-01-01

    Concentrations of black carbon were determined for a number of marine sediments. A comparison of black carbon based on thermal oxidation and hot concentrated nitric acid pretreatments revealed that the latter significantly overestimates combustion derived carbon phases. Black carbon accounts for abo

  14. Radiocarbon based source apportionment of black carbon in the form of PM10 elemental carbon aerosol particles at the Zeppelin Observatory, Svalbard

    Science.gov (United States)

    Winiger, Patrik; Andersson, August; Espen Yttri, Karl; Tunved, Peter; Gustafsson, Örjan

    2015-04-01

    Black carbon (BC) aerosol particles are formed from incomplete combustion of fossil fuel and biomass. Transported into the Arctic, they potentially contributes to climate warming. However, there are still large uncertainties related to the climate effects of BC, including aspects of radiative properties, mixing state of the particles, transport, atmospheric lifetime and sources. The current study aims to reduce source uncertainties by applying a top-down (observational) source-diagnostic isotope approach and comparing these to bottom-up (modeling) emission inventories to better constrain the source types and source regions. The use of natural abundance radiocarbon (Δ14C) is a powerful tool to distinguish between fossil (void of 14C) and biomass (contemporary 14C) combustion sources. Due to the well-defined end-members, 14C-measurements (alone) provide high precision (

  15. Variability of levels of PM, black carbon and particle number concentration in selected European cities

    Directory of Open Access Journals (Sweden)

    C. Reche

    2011-03-01

    Full Text Available In many large cities of Europe standard air quality limit values of particulate matter (PM are exceeded. Emissions from road traffic and biomass burning are frequently reported to be the major causes. As a consequence of these exceedances a large number of air quality plans, most of them focusing on traffic emissions reductions, have been implemented in the last decade. In spite of this implementation, a number of cities did not record a decrease of PM levels. Thus, is the efficiency of air quality plans overestimated? Or do we need a more specific metric to evaluate the impact of the above emissions on the levels of urban aerosols?

    This study shows the results of the interpretation of the 2009 variability of levels of PM, black carbon (BC, aerosol number concentration (N and a number of gaseous pollutants in seven selected urban areas covering road traffic, urban background, urban-industrial, and urban-shipping environments from southern, central and northern Europe.

    The results showed that variations of PM and N levels do not always reflect the variation of the impact of road traffic emissions on urban aerosols. However, BC levels vary proportionally with those of traffic related gaseous pollutants, such as CO, NO2 and NO. Due to this high correlation, one may suppose that monitoring the levels of these gaseous pollutants would be enough to extrapolate exposure to traffic-derived BC levels. However, the BC/CO, BC/NO2 and BC/NO ratios vary widely among the cities studied, as a function of distance to traffic emissions, vehicle fleet composition and the influence of other emission sources such as biomass burning. Thus, levels of BC should be measured at air quality monitoring sites.

    During traffic rush hours, a narrow variation in the N/BC ratio was evidenced, but a wide variation of this ratio was determined for the noon period. Although in central and northern Europe N and BC levels tend to vary

  16. Measurements of the impact of atmospheric aging on physical and optical properties of ambient black carbon particles in Los Angeles

    Science.gov (United States)

    Krasowsky, Trevor S.; McMeeking, Gavin R.; Wang, Dongbin; Sioutas, Constantinos; Ban-Weiss, George A.

    2016-10-01

    Understanding how physical and optical properties of atmospheric black carbon (BC) particles vary in time and space is critical for reducing uncertainty in climate forcing estimates from ambient BC. In this study, ambient BC was measured in Rubidoux, California, approximately 90 km (55 miles) downwind of downtown Los Angeles. Collocated NOx and NOy measurements were used to estimate the photochemical age of the sampled air. Sampling was conducted throughout entire days between February 3, 2015 and March 12, 2015 to capture diurnal and daily variations in ambient BC. Both ambient and thermally-denuded air was sampled in 15-min cycles to compare the physical and optical properties of coated versus uncoated BC particles. Physical properties of individual BC particles including mass and coating thickness were measured using a Single-Particle Soot Photometer (SP2), and BC optical properties were measured using a Photoacoustic Extinctiometer (PAX) at 870 nm. The mean BC mass concentration (±standard deviation) for the campaign was 0.12 ± 0.08 μg m-3. BC mass concentrations were higher on weekdays than weekends, though only differences between 11:00 and 17:00 h were statistically distinguishable. The fraction of total BC particles that were thickly-coated (f) was found to be relatively low, with a mean of 0.05 ± 0.02 over the campaign. Values for f peaked in the afternoon when photochemical pollutant concentrations are also generally at a maximum. Further, f at 15:00-16:00 h was found to be statistically higher on weekends than weekdays, potentially due to a higher relative amount of ambient SOA to BC on weekends versus weekdays, which would enhance SOA coating of primary BC particles as they age during transport from the western Los Angeles basin to our sampling site on weekends. Differences at other hours during the photochemically active period of the day (10:00-14:00 h) were not statistically different although the weekend values were systematically higher

  17. Ice Nucleation and Droplet Formation by Bare and Coated Black Carbon Particles

    Energy Technology Data Exchange (ETDEWEB)

    Friedman, Beth J.; Kulkarni, Gourihar R.; Beranek, Josef; Zelenyuk, Alla; Thornton, Joel A.; Cziczo, Daniel J.

    2011-10-13

    We have studied the ice formation at heterogeneous and homogeneous temperatures, as well as droplet activation and hygroscopicity of soot particles of variable size and composition. Coatings of adipic, malic, and oleic acid were applied to span a relevant range of solubility, and both uncoated and oleic acid coated soot particles were exposed to ozone to simulate atmospheric oxidation. The results are interpreted in terms of onset ice nucleation with a comparison to a well characterized mineral dust particle that acts as an efficient ice nucleus, as well as particle hygroscopicity. At 253K and 243K, we found no evidence of heterogeneous ice nucleation occurring above the level of detection for our experimental conditions. Above water saturation, droplet formation was observed. At 233K, we observe the occurrence of homogeneous ice nucleation for all particles studied. Coatings also did not significantly alter the ice nucleation behavior of soot particles, but aided in the uptake of water. Hygroscopicity studies confirmed that pure soot particles were hydrophobic, and coated soot particles activated as droplets at high water supersaturations. A small amount of heterogeneous ice nucleation either below the detection limit of our instrument or concurrent with droplet formation and/or homogeneous freezing cannot be precluded, but we are able to set limits for its frequency. We conclude from our studies that both uncoated and coated soot particles are unlikely to contribute to the global budget of heterogeneous ice nuclei at temperatures between 233K and 253K.

  18. Black carbon: The reverse of its dark side

    NARCIS (Netherlands)

    Koelmans, A.A.; Jonker, M.T.O.; Cornelissen, G.; Bucheli, T.D.; Noort, van P.C.M.; Gustafsson, O.

    2006-01-01

    The emission of black carbon is known to cause major environmental problems. Black carbon particles contribute to global warming, carry carcinogenic compounds and cause serious health risks. Here, we show another side of the coin. We review evidence that black carbon may strongly reduce the risk pos

  19. Aerosol-CFD modelling of ultrafine and black carbon particle emission, dilution, and growth near roadways

    Science.gov (United States)

    Huang, L.; Gong, S. L.; Gordon, M.; Liggio, J.; Staebler, R. M.; Stroud, C. A.; Lu, G.; Mihele, C.; Brook, J. R.; Jia, C. Q.

    2014-05-01

    Many studies have shown that on-road vehicle emissions are the dominant source of ultrafine particles (UFP; diameter advance our knowledge on the complex interactions and competition among atmospheric dilution, dispersion and dynamics of UFPs, an aerosol dynamics-CFD coupled model is developed and validated against field measurements. A unique approach of applying periodic boundary conditions is proposed to model pollutant dispersion and dynamics in one unified domain from the tailpipe level to the ambient near-road environment. This approach significantly reduces the size of the computational domain, and therefore, allows fast simulation of multiple scenarios. The model is validated against measured turbulent kinetic energy (TKE) and pollution gradients near a major highway. Through a model sensitivity analysis, the relative importance of individual aerosol dynamical processes on the total particle number concentration (N) and particle number-size distribution (PSD) near a highway is investigated. The results demonstrate that (1) coagulation has a negligible effect on N and particle growth, (2) binary homogeneous nucleation (BHN) of H2SO4-H2O is likely responsible for elevated N closest to the road, (3) N and particle growth are very sensitive to the condensation of semi-volatile organics (SVOCs), particle dry deposition, and the interaction between these processes. The results also indicate that, without the proper treatment of atmospheric boundary layer (i.e. its wind profile and turbulence quantities), the nucleation rate would be underestimated by a factor of 5 in the vehicle wake region due to overestimated mixing. Therefore, introducing ABL conditions to activity-based emission models may potentially improve their performance in estimating UFP traffic emissions.

  20. Influence of Ingredients of Carbon Black Nano-Particle Suspension of Ammonia Solution on Viscosity of Nanofluid

    Institute of Scientific and Technical Information of China (English)

    CHENG Bo; DU Kai; ZHANG Xiao-song; YANG Liu

    2009-01-01

    A series of experiments were performed on the viscosity of a nanofluid,produced by mixing car-bon black and mulsifier OP-10 using ammonia-water with the ultrasonic dispersion.The results show that,when adding surfactant separately in low mass concentrations,at first the viscosity of solution decreases sharply compared with that of ammonia-water.then increases with increasing the concentration of OP-IO.In a certain concentration of surfactant,the viscosity of nanofluids increases with increasing the concentration of nanoparti·des.Based on Einstein model and Langrnuir absorption theory,a new model啪s summed up for nanoflukls.Compared with test values,the calcuhted values on the new model have verified that the model is suitable to predict the viscosity of rmnofluids.beoll.k.the maximum relative error is less than 5%.Nano-particles absorp-tion in the nanofluids is not only single-molecule layer adsorption,but aLso multi-layer molecular adsorption and other complicated adsorption.So the new model,ordy based on single-molecule layer adsorption theory of Lang-muir.is not fully in line with the real circumstances.

  1. Determination of car on-road black carbon and particle number emission factors and comparison between mobile and stationary measurements

    Directory of Open Access Journals (Sweden)

    I. Ježek

    2014-06-01

    Full Text Available We have used two methods for measuring emission factors (EF in real driving conditions on five cars in a controlled environment: the stationary method, where the investigated vehicle drives by the stationary measurement platform and the composition of the plume is measured; and the chasing method, where a mobile measurement platform drives behind the investigated vehicle. We measured EF of black carbon and particle number concentration. The stationary method was tested for repeatability at different speeds and on a slope. The chasing method was tested on a test track and compared to the portable emission measurement system. We further developed the data processing algorithm for both methods, trying to improve consistency, determine the plume duration, limit the background influence and facilitate automatic processing of measurements. The comparison of emission factors determined by the two methods showed good agreement. EFs of a single car measured with either method have a specific distribution with a characteristic value and a long tail of super emissions. Measuring EFs at different speeds or slopes did not significantly influence the EFs of different cars, hence we propose a new description of vehicle emissions that is not related to kinematic or engine parameters, rather we describe the vehicle EF with a characteristic value and a "super emission" tail.

  2. PAH, BTEX, carbonyl compound, black-carbon, NO2 and ultrafine particle dynamometer bench emissions for Euro 4 and Euro 5 diesel and gasoline passenger cars

    Science.gov (United States)

    Louis, Cédric; Liu, Yao; Tassel, Patrick; Perret, Pascal; Chaumond, Agnès; André, Michel

    2016-09-01

    Although implementing Diesel particulate filters (DPF) and other novel aftertreatment technologies makes it possible to achieve significant reductions in particle mass emissions, it may induce the release of ultrafine particles and emissions of many other unregulated compounds. This paper focuses on (i) ultrafine particles, black carbon, BTEX, PAH, carbonyl compounds, and NO2 emissions from Euro 4 and Euro 5 Diesel and gasoline passenger cars, (ii) the influence of driving conditions (e.g., cold start, urban, rural and motorway conditions), and (iii) the impact of additive and catalysed DPF devices on vehicle emissions. Chassis dynamometer tests were conducted on four Euro 5 vehicles and two Euro 4 vehicles: gasoline vehicles with and without direct injection system and Diesel vehicles equipped with additive and catalysed particulate filters. The results showed that compared to hot-start cycles, cold-start urban cycles increased all pollutant emissions by a factor of two. The sole exception was NO2, which was reduced by a factor of 1.3-6. Particulate and black carbon emissions from the gasoline engines were significantly higher than those from the Diesel engines equipped with DPF. Moreover, the catalysed DPF emitted about 3-10 times more carbonyl compounds and particles than additive DPF, respectively, during urban driving cycles, while the additive DPF vehicles emitted 2 and 5 times more BTEX and carbonyl compounds during motorway driving cycles. Regarding particle number distribution, the motorway driving cycle induced the emission of particles smaller in diameter (mode at 15 nm) than the urban cold-start cycle (mode at 80-100 nm). The results showed a clear positive correlation between particle, black carbon, and BTEX emissions, and a negative correlation between particles and NO2.

  3. Black carbon aerosol characterization in a coastal city in South China using a single particle soot photometer

    Science.gov (United States)

    Huang, Xiao-Feng; Sun, Tian-Le; Zeng, Li-Wu; Yu, Guang-He; Luan, Sheng-Ji

    2012-05-01

    Black carbon (BC) is the dominant light-absorbing aerosol component in the atmosphere and plays an important role in atmospheric pollution and climate change. The light-absorbing properties of BC rely on particle size, shape, composition, as well as the BC mixing state with other aerosol components, thus more thorough exploration of BC aerosol characteristics is critical in understanding its atmospheric sources and effects. In this study, a newly-developed Single Particle Soot Photometer (SP2) was deployed in Shenzhen, China, for continuous BC measurements to obtain the important information about size distribution and mixing state of BC under severe air pollution conditions of China. The mean BC mass concentrations were found to be 6.0 and 4.1 μg m-3 at an urban site (UT) in the fall and winter, respectively, while it is much lower (2.6 μg m-3) at a rural site (BG) in the fall. The mass size distributions of BC in volume equivalent diameter (VED) at the three sites showed a similar lognormal pattern, with the peak diameter at BG (222 nm) slightly larger than at the UT (210 nm) site. As to mixing state, the average percentage of internally mixed BC at the UT site was detected to be 40% and 46% in the fall and winter, respectively, while that at the BG site in the fall was only a slightly higher (47%), which implies that fresh local fossil fuel combustions were still significant at this rural site. The analysis of extremely high BC concentrations (>20 μg m-3) at UT indicates that they were a complex of comparable contributions from both local fresh emissions and regional transport under unfavorable meteorology. Other characteristics of BC aerosol and their influencing factors in Shenzhen were also discussed.

  4. Lack of acute phase response in the livers of mice exposed to diesel exhaust particles or carbon black by inhalation

    Directory of Open Access Journals (Sweden)

    Williams Andrew

    2009-04-01

    Full Text Available Abstract Background Epidemiologic and animal studies have shown that particulate air pollution is associated with increased risk of lung and cardiovascular diseases. Although the exact mechanisms by which particles induce cardiovascular diseases are not known, studies suggest involvement of systemic acute phase responses, including C-reactive protein (CRP and serum amyloid A (SAA in humans. In this study we test the hypothesis that diesel exhaust particles (DEP – or carbon black (CB-induced lung inflammation initiates an acute phase response in the liver. Results Mice were exposed to filtered air, 20 mg/m3 DEP or CB by inhalation for 90 minutes/day for four consecutive days; we have previously shown that these mice exhibit pulmonary inflammation (Saber AT, Bornholdt J, Dybdahl M, Sharma AK, Loft S, Vogel U, Wallin H. Tumor necrosis factor is not required for particle-induced genotoxicity and pulmonary inflammation., Arch. Toxicol. 79 (2005 177–182. As a positive control for the induction of an acute phase response, mice were exposed to 12.5 mg/kg of lipopolysaccharide (LPS intraperitoneally. Quantitative real time RT-PCR was used to examine the hepatic mRNA expression of acute phase proteins, serum amyloid P (Sap (the murine homologue of Crp and Saa1 and Saa3. While significant increases in the hepatic expression of Sap, Saa1 and Saa3 were observed in response to LPS, their levels did not change in response to DEP or CB. In a comprehensive search for markers of an acute phase response, we analyzed liver tissue from these mice using high density DNA microarrays. Globally, 28 genes were found to be significantly differentially expressed in response to DEP or CB. The mRNA expression of three of the genes (serine (or cysteine proteinase inhibitor, clade A, member 3C, apolipoprotein E and transmembrane emp24 domain containing 3 responded to both exposures. However, these changes were very subtle and were not confirmed by real time RT

  5. Joint measurements of black carbon and particle mass for heavy-duty diesel vehicles using a portable emission measurement system

    Science.gov (United States)

    Zheng, Xuan; Wu, Ye; Zhang, Shaojun; Baldauf, Richard W.; Zhang, K. Max; Hu, Jingnan; Li, Zhenhua; Fu, Lixin; Hao, Jiming

    2016-09-01

    The black carbon (BC) emitted from heavy-duty diesel vehicles (HDDVs) is an important source of urban atmospheric pollution and creates strong climate-forcing impacts. The emission ratio of BC to total particle mass (PM) (i.e., BC/PM ratio) is an essential variable used to estimate total BC emissions from historical PM data; however, these ratios have not been measured using portable emission measurement systems (PEMS) in order to obtain real-world measurements over a wide range of driving conditions. In this study, we developed a PEMS platform by integrating two Aethalometers and an electric low pressure impactor to realize the joint measurement of real-world BC and PM emissions for ten HDDVs in China. Test results showed that the average BC/PM ratio for five HDDVs equipped with mechanical fuel injection (MI) engines was 0.43 ± 0.06, significantly lower (P five HDDVs equipped with electronically-controlled fuel injection (EI) engines (0.56 ± 0.12). Traffic conditions also affected the BC/PM ratios with higher ratios on freeway routes than on local roads. Furthermore, higher ratios were observed for HDDVs equipped with EI engines than for the MI engines for the highway and local road routes. With an operating mode binning approach, we observed that the instantaneous BC/PM ratios of EI engine vehicles were above those of the MI engine vehicles in all operating modes except for the braking mode (i.e., Bin 0). Therefore, the complex impacts from engine technology and traffic conditions on BC/PM ratios should be carefully considered when estimating real-world BC emissions from HDDVs based on overall PM emissions data.

  6. Joint measurements of black carbon and particle mass for heavy-duty diesel vehicles using a portable emission measurement system

    Science.gov (United States)

    Zheng, Xuan; Wu, Ye; Zhang, Shaojun; Baldauf, Richard W.; Zhang, K. Max; Hu, Jingnan; Li, Zhenhua; Fu, Lixin; Hao, Jiming

    2016-09-01

    The black carbon (BC) emitted from heavy-duty diesel vehicles (HDDVs) is an important source of urban atmospheric pollution and creates strong climate-forcing impacts. The emission ratio of BC to total particle mass (PM) (i.e., BC/PM ratio) is an essential variable used to estimate total BC emissions from historical PM data; however, these ratios have not been measured using portable emission measurement systems (PEMS) in order to obtain real-world measurements over a wide range of driving conditions. In this study, we developed a PEMS platform by integrating two Aethalometers and an electric low pressure impactor to realize the joint measurement of real-world BC and PM emissions for ten HDDVs in China. Test results showed that the average BC/PM ratio for five HDDVs equipped with mechanical fuel injection (MI) engines was 0.43 ± 0.06, significantly lower (P electronically-controlled fuel injection (EI) engines (0.56 ± 0.12). Traffic conditions also affected the BC/PM ratios with higher ratios on freeway routes than on local roads. Furthermore, higher ratios were observed for HDDVs equipped with EI engines than for the MI engines for the highway and local road routes. With an operating mode binning approach, we observed that the instantaneous BC/PM ratios of EI engine vehicles were above those of the MI engine vehicles in all operating modes except for the braking mode (i.e., Bin 0). Therefore, the complex impacts from engine technology and traffic conditions on BC/PM ratios should be carefully considered when estimating real-world BC emissions from HDDVs based on overall PM emissions data.

  7. Effects of Surface-modification of Carbon Black on the Characteristics of Polymerized Toner

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Eun Ho; Kim, Dae Su [Chungbuk National University, Cheongju (Korea, Republic of)

    2013-10-15

    Carbon black was surface-modified to prepare styrene-based suspension polymerized toner with excellent carbon black dispersibility inside toner particles. Carbon black was oxidized first to introduce hydroxyl groups on the surfaces, then esterification between the hydroxyl groups and carboxyl groups of organic acids (oleic acid, palmitic acid, acrylic acid) was followed to obtain organically surface-modified carbon black. The surface-modification of carbon black was confirmed by FTIR. Apparent carbon black dispersibility in the monomer mixture of the binder resin was tested and the particle size of dispersed carbon black was measured by particle size analyzer. Optical micrographs showed that carbon black dispersibility inside toner particles was improved considerably when the carbon black surface-modified with oleic acid was used. The polymerized toner prepared with the carbon black surface-modified with oleic acid showed ideal particle size and size distribution as a toner.

  8. Pyrolytic carbon coated black silicon.

    Science.gov (United States)

    Shah, Ali; Stenberg, Petri; Karvonen, Lasse; Ali, Rizwan; Honkanen, Seppo; Lipsanen, Harri; Peyghambarian, N; Kuittinen, Markku; Svirko, Yuri; Kaplas, Tommi

    2016-01-01

    Carbon is the most well-known black material in the history of man. Throughout the centuries, carbon has been used as a black material for paintings, camouflage, and optics. Although, the techniques to make other black surfaces have evolved and become more sophisticated with time, carbon still remains one of the best black materials. Another well-known black surface is black silicon, reflecting less than 0.5% of incident light in visible spectral range but becomes a highly reflecting surface in wavelengths above 1000 nm. On the other hand, carbon absorbs at those and longer wavelengths. Thus, it is possible to combine black silicon with carbon to create an artificial material with very low reflectivity over a wide spectral range. Here we report our results on coating conformally black silicon substrate with amorphous pyrolytic carbon. We present a superior black surface with reflectance of light less than 0.5% in the spectral range of 350 nm to 2000 nm. PMID:27174890

  9. Black Carbon, The Pyrogenic Clay Mineral?

    Science.gov (United States)

    Most soils contain significant amounts of black carbon, much of which is present as discrete particles admixed with the coarse clay fraction (0.2–2.0 µm e.s.d.) and can be physically separated from the more abundant diffuse biogenic humic materials. Recent evidence has shown that naturally occurring...

  10. 硫化胶中炭黑品种的粒径分布鉴别方法%Determination of Carbon Black Type in Vulcanized Compound by Particle Size Distribution Analysis

    Institute of Scientific and Technical Information of China (English)

    张翠翠; 苍飞飞; 邹滔; 高原; 马姜; 邓平晔

    2015-01-01

    The relationship between particle size distribution and carbon black type was established and the test method to determine the carbon black type in vulcanized compound was obtained by particle size distribution analysis. The carbon black in the vulcanized compound was recovered by pyrolysis and its particle size distribution was measured by laser diffraction nano-particle size analyzer. The results showed that peak value and standard deviation of different type of carbon black were different and the peak value and standard deviation fluctuated within a small range for the same type of carbon black. Thus the unknown carbon black could be identiifed by measuring its particle size distribution. This identiifcation method was suitable for analysis of carbon black in the vulcanized compound iflled with only one type of carbon black and it could not be applied to blended carbon black and carbon black N774.%探索炭黑粒径分布与炭黑品种之间的关系,建立通过炭黑粒径分布鉴别炭黑品种的方法。通过热裂解法回收硫化胶中的炭黑,将回收的炭黑加入分散剂制成悬浊液,利用纳米激光粒度分布仪进行粒径分布测试。结果表明,不同品种炭黑粒径分布的峰值和标准偏差不同,同种炭黑粒径分布的峰值和标准偏差在一个较小的范围内波动,这是硫化胶中未知炭黑品种鉴别的依据。本方法适用于单一炭黑品种硫化胶分析,不适用于并用炭黑及炭黑N774硫化胶分析。

  11. Phase Behavior of Dilute Carbon Black Suspensions and Carbon Black Stabilized Emulsions

    Science.gov (United States)

    Godfrin, Michael; Tiwari, Ayush; Bose, Arijit; Tripathi, Anubhav

    2014-11-01

    We use para-amino benzoic acid terminated carbon black (CB) as a tunable model particulate material to study the effect of inter-particle interactions on phase behavior and steady shear stresses in suspensions and particle-stabilized emulsions. We modulate inter-particle interactions by adding NaCl to the suspension, thus salting surface carboxylate groups. Surprisingly, yield stress behavior emerged at a volume fraction of CB as low as ϕCB = 0.008, and gel behavior was observed at ϕCB >0.05, well below the percolation threshold for non-interacting particles. The yield stress was found to grow rapidly with carbon black concentration suggesting that salt-induced hydrophobicity leads to strong inter-particle interactions and the formation of a network at low particle concentrations. The yield stresses of CB-stabilized emulsions also grows rapidly with carbon black concentrations, implying that inter-droplet interactions can be induced through the tuning of carbon black concentration in emulsion systems. Emulsions stabilized by ionic surfactants show no inter-droplet interactions. In contrast, oil droplets in the CB-stabilized emulsion move collectively or are immobilized because of an interconnected CB network in the aqueous phase.

  12. Ship-borne Observations of Atmospheric Black Carbon Aerosol Particles over the Arctic Ocean, Bering Sea, and North Pacific Ocean during September 2014

    Science.gov (United States)

    Taketani, F.; Miyakawa, T.; Takashima, H.; Komazaki, Y.; Kanaya, Y.; PAN, X.; Inoue, J.

    2015-12-01

    Measurements of refractory black carbon (rBC) aerosol particles using a highly sensitive online single particle soot photometer were performed on-board the R/V Mirai during a cruise across the Arctic Ocean, Bering Sea, and the North Pacific Ocean (31 August-9 October 2014). The measured rBC mass concentrations over the Arctic Ocean in the latitudinal region > 70°N were in the range 0-66 ng/m3 for 1-min averages, with an overall mean value of 1.0 ± 1.2 ng/m3. Single-particle-based observations enabled the measurement of such low rBC mass concentrations. The effects of long-range transport from continents to the Arctic Ocean were limited during the observed period, suggesting that such low rBC concentration levels would prevail over the Arctic Ocean. An analysis of rBC mixing states showed that particles with a non-shell/core structure made a significant contribution to the rBC particles detected over the Arctic Ocean.

  13. The effect of mitigation measures on size distributed mass concentrations of atmospheric particles and black carbon concentrations during the Olympic Summer Games 2008 in Beijing.

    Science.gov (United States)

    Schleicher, Nina; Norra, Stefan; Dietze, Volker; Yu, Yang; Fricker, Mathieu; Kaminski, Uwe; Chen, Yuan; Cen, Kuang

    2011-12-15

    The period of the 2008 Olympic Summer Games in Beijing can be considered as a unique opportunity to study the influences of emission reduction measures on air quality improvement. Within this study atmospheric particles of different size classes (2.5 to 80 μm) were investigated before, during, and after the Olympic Games period in order to observe and assess the success of short-term measures to mitigate extreme urban aerosol pollution and also to investigate, which particle size classes were reduced most effectively. Furthermore, black carbon (BC) concentrations in fine particles (PM(2.5)) during the source control period were compared to those of the previous years in order to investigate the decrease of combustion-derived aerosols. It is shown that besides the implemented mitigation measures precipitation decisively contributed to a considerable decrease of particulate air pollution in Beijing compared to the respective concentrations during the time directly before and after the Olympic Games, and also compared to average August concentrations during the previous years and the following year 2009. Particles of the fine fraction of the coarse mode (2.5 to 5 μm), which have a residence time in the order of several days and which, therefore, are typically transported over long distances from outside of Beijing, were less efficiently reduced than coarser particles. This indicates that long-range transport of atmospheric particles is difficult to control and that presumably the established mitigation area was not large enough to also reduce the fine fraction of the coarse mode more efficiently. Furthermore, the study showed that coarse geogenic particles, which originated to a high percentage from construction sites and resuspension processes due to traffic seemed to be reduced most efficiently during the Olympic Games period. PMID:22035559

  14. Long-term observations of tropospheric particle number size distributions and equivalent black carbon mass concentrations in the German Ultrafine Aerosol Network (GUAN

    Directory of Open Access Journals (Sweden)

    W. Birmili

    2015-11-01

    Full Text Available The German Ultrafine Aerosol Network (GUAN is a cooperative atmospheric observation network, which aims at improving the scientific understanding of aerosol-related effects in the troposphere. The network addresses research questions dedicated to both, climate and health related effects. GUAN's core activity has been the continuous collection of tropospheric particle number size distributions and black carbon mass concentrations at seventeen observation sites in Germany. These sites cover various environmental settings including urban traffic, urban background, rural background, and Alpine mountains. In association with partner projects, GUAN has implemented a high degree of harmonisation of instrumentation, operating procedures, and data evaluation procedures. The quality of the measurement data is assured by laboratory intercomparisons as well as on-site comparisons with reference instruments. This paper describes the measurement sites, instrumentation, quality assurance and data evaluation procedures in the network as well as the EBAS repository, where the data sets can be obtained (doi:10.5072/guan.

  15. Long-term observations of tropospheric particle number size distributions and equivalent black carbon mass concentrations in the German Ultrafine Aerosol Network (GUAN)

    Science.gov (United States)

    Birmili, Wolfram; Weinhold, Kay; Rasch, Fabian; Sonntag, André; Sun, Jia; Merkel, Maik; Wiedensohler, Alfred; Bastian, Susanne; Schladitz, Alexander; Löschau, Gunter; Cyrys, Josef; Pitz, Mike; Gu, Jianwei; Kusch, Thomas; Flentje, Harald; Quass, Ulrich; Kaminski, Heinz; Kuhlbusch, Thomas A. J.; Meinhardt, Frank; Schwerin, Andreas; Bath, Olaf; Ries, Ludwig; Wirtz, Klaus; Fiebig, Markus

    2016-08-01

    The German Ultrafine Aerosol Network (GUAN) is a cooperative atmospheric observation network, which aims at improving the scientific understanding of aerosol-related effects in the troposphere. The network addresses research questions dedicated to both climate- and health-related effects. GUAN's core activity has been the continuous collection of tropospheric particle number size distributions and black carbon mass concentrations at 17 observation sites in Germany. These sites cover various environmental settings including urban traffic, urban background, rural background, and Alpine mountains. In association with partner projects, GUAN has implemented a high degree of harmonisation of instrumentation, operating procedures, and data evaluation procedures. The quality of the measurement data is assured by laboratory intercomparisons as well as on-site comparisons with reference instruments. This paper describes the measurement sites, instrumentation, quality assurance, and data evaluation procedures in the network as well as the EBAS repository, where the data sets can be obtained (doi:10.5072/guan).

  16. Monitoring of black carbon and size-segregated particle number concentrations at 9-m and 65-m distances from a major road in Helsinki

    Energy Technology Data Exchange (ETDEWEB)

    Pakkanen, T.A.; Maekelae, T.; Hillamo, R.E. [Finnish Meteorological Inst., Helsinki (Finland); Virtanen, A.; Roenkkoe, T.; Keskinen, J. [Tampere Univ. of Technology, Inst. of Physics, Aerosol Physics Lab. , Tampere (Finland); Pirjola, L.; Parviainen, H. [Helsinki Polytechnic, Dept. of Technology, Helsinki (Finland); Hussein, T.; Haemeri, K. [Helsinki Univ., Dept. of Physical Sciences, Helsinki (Finland)

    2006-07-01

    In February and August 2003, black carbon (BC) and size-segregated particle number concentrations were monitored simultaneously at 9-m and 65-m distances from a major road in Helsinki, Finland, using aethalometers and electrical low-pressure impactors, respectively. During weekdays in winter, the average total particle number concentrations in the diameter range 0.007-1{mu}m increased during morning rush hours from the nighttime values of 17000 and 12000 cm{sup -3} to 190000 and 130000 cm{sup -3} at the 9-m and 65-m stations, respectively. The corresponding BC concentrations increased from 730 and 430 ng m{sup -3} to 2800 and 1550 ng m{sup -3}. Compared with those in winter, the average rush-hour particle number concentrations were much lower in summer, the likely reason being enhanced nucleation in cold winter conditions. BC concentrations were slightly higher during summer than during winter. Number size distributions measured at the 9-m and 65-m distances and at a background site had similar modal characteristics with the highest peak occurring below 0.03 {mu}m. Despite the different wind conditions in winter and summer, concentrations of total particle number and BC decreased similarly between the 9-m and 65-m stations, the likely principal mechanism being mixing with background air. The strong diurnal variation in concentrations during the weekdays, together with the large concentration difference between the 9-m and 65-m distances, suggests that local traffic was the main source of the measured pollutants, especially during rush hours at the 9-m site. In winter, the decrease in the particle number concentrations from the 9-m site to the 65-m site was most pronounced for the smallest exhaust particles. During an episodic pollution event in winter there were indications of condensational growth of 0.007-0.03 {mu}m particles, which increased the number concentration of 0.03-0.06 {mu}m particles at the 65-m site. (orig.)

  17. Effects of volatile coatings on the morphology and optical detection of combustion-generated black carbon particles.

    Energy Technology Data Exchange (ETDEWEB)

    Bambha, Ray.; Dansson, Mark A; Schrader, Paul E.; Michelsen, Hope A.

    2013-09-01

    We have measured time-resolved laser-induced incandescence (LII) from combustion-generated mature soot extracted from a burner and (1) coated with oleic acid or (2) coated with oleic acid and then thermally denuded using a thermodenuder. The soot samples were size selected using a differential mobility analyser and characterized with a scanning mobility particle sizer, centrifugal particle mass analyser, and transmission electron microscope. The results demonstrate a strong influence of coatings particle morphology and on the magnitude and temporal evolution of the LII signal. For coated particles higher laser fluences are required to reach LII signal levels comparable to those of uncoated particles. This effect is predominantly attributable to the additional energy needed to vaporize the coating while heating the particle. LII signals are higher and signal decay rates are significantly slower for thermally denuded particles relative to coated or uncoated particles, particularly at low and intermediate laser fluences.

  18. The relationship between black carbon concentration and black smoke: A more general approach

    OpenAIRE

    Heal, Mathew R.; Quincey, Paul

    2012-01-01

    The black carbon (BC) component of ambient particulate matter is an important marker for combustion sources and for its impact on human health and radiative forcing. Extensive data archives exist for the black smoke metric, the historic measure of ambient particle darkness. An expression presented in earlier publications (Quincey, 2007; Quincey et al., 2011) for estimating BC concentrations from traditional black smoke measurements is shown to have limitations that can be addressed by using a...

  19. Aerosol-computational fluid dynamics modeling of ultrafine and black carbon particle emission, dilution, and growth near roadways

    Science.gov (United States)

    Huang, L.; Gong, S. L.; Gordon, M.; Liggio, J.; Staebler, R.; Stroud, C. A.; Lu, G.; Mihele, C.; Brook, J. R.; Jia, C. Q.

    2014-12-01

    Many studies have shown that on-road vehicle emissions are the dominant source of ultrafine particles (UFPs; diameter advance our knowledge on the complex interactions and competition among atmospheric dilution, dispersion, and dynamics of UFPs, an aerosol dynamics-computational fluid dynamics (CFD) coupled model is developed and validated against field measurements. A unique approach of applying periodic boundary conditions is proposed to model pollutant dispersion and dynamics in one unified domain from the tailpipe level to the ambient near-road environment. This approach significantly reduces the size of the computational domain, and therefore allows fast simulation of multiple scenarios. The model is validated against measured turbulent kinetic energy (TKE) and horizontal gradient of pollution concentrations perpendicular to a major highway. Through a model sensitivity analysis, the relative importance of individual aerosol dynamical processes on the total particle number concentration (N) and particle number-size distribution (PSD) near a highway is investigated. The results demonstrate that (1) coagulation has a negligible effect on N and particle growth, (2) binary homogeneous nucleation (BHN) of H2SO4-H2O is likely responsible for elevated N closest to the road, and (3) N and particle growth are very sensitive to the condensation of semi-volatile organics (SVOCs), particle dry deposition, and the interaction between these processes. The results also indicate that, without the proper treatment of the atmospheric boundary layer (i.e., its wind profile and turbulence quantities), the nucleation rate would be underestimated by a factor of 5 in the vehicle wake region due to overestimated dilution. Therefore, introducing atmospheric boundary layer (ABL) conditions to activity-based emission models may potentially improve their performance in estimating UFP traffic emissions.

  20. Comparison of Spheroidal Carbonaceous Particle Data with Modelled Atmospheric Black Carbon Concentration and Deposition and Air Mass Sources in Northern Europe, 1850–2010

    Directory of Open Access Journals (Sweden)

    Meri Ruppel

    2013-01-01

    Full Text Available Spheroidal carbonaceous particles (SCP are a well-defined fraction of black carbon (BC, produced only by the incomplete combustion of fossil fuels such as coal and oil. Their past concentrations have been studied using environmental archives, but, additionally, historical trends of BC concentration and deposition can be estimated by modelling. These models are based on BC emission inventories, but actual measurements of BC concentration and deposition play an essential role in their evaluation and validation. We use the chemistry transport model OsloCTM2 to model historical time series of BC concentration and deposition from energy and industrial sources and compare these to sedimentary measurements of SCPs obtained from lake sediments in Northern Europe from 1850 to 2010. To determine the origin of SCPs we generated back trajectories of air masses to the study sites. Generally, trends of SCP deposition and modelled results agree reasonably well, showing rapidly increasing values from 1950, to a peak in 1980, and a decrease towards the present. Empirical SCP data show differences in deposition magnitude between the sites that are not captured by the model but which may be explained by different air mass transport patterns. The results highlight the need for numerous observational records to reliably validate model results.

  1. Prenatal Exposure to Carbon Black (Printex 90)

    DEFF Research Database (Denmark)

    Jackson, Petra; Vogel, Ulla; Wallin, Håkan;

    2011-01-01

    Maternal pulmonary exposure to ultrafine particles during pregnancy may affect the health of the child. Developmental toxicity of carbon black (Printex 90) nanoparticles was evaluated in a mouse model. Time-mated mice were intratracheally instilled with Printex 90 dispersed in Millipore water on ...... on gestation days (GD) 7, 10, 15 and 18, with total doses of 11, 54 and 268 mu g Printex 90/animal. The female offspring prenatally exposed to 268 mu g Printex 90/animal displayed altered habituation pattern during the Open field test....

  2. Vector particles tunneling from BTZ black holes

    CERN Document Server

    Chen, Ge-Rui; Huang, Yong-Chang

    2014-01-01

    In this paper we investigate vector particles' Hawking radiation from a BTZ black hole. By applying the WKB approximation and the Hamilton-Jacobi Ansatz to the Proca equation, we obtain the tunneling spectrum of vector particles. The expected Hawking temperature is recovered.

  3. Vector particles tunneling from BTZ black holes

    Science.gov (United States)

    Chen, Ge-Rui; Zhou, Shiwei; Huang, Yong-Chang

    2015-11-01

    In this paper we investigate vector particles' Hawking radiation from a Banados-Teitelboim-Zanelli (BTZ) black hole. By applying the Wentzel-Kramers-Brillouin (WKB) approximation and the Hamilton-Jacobi ansatz to the Proca equation, we obtain the tunneling spectrum of vector particles. The expected Hawking temperature is recovered.

  4. Characterization of Black Carbon Mixing State Field Campaign Report

    Energy Technology Data Exchange (ETDEWEB)

    Sedlacek, A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Davidovits, P. [Boston College, Chestnut Hill, MA (United States); Lewis, E. R. [Brookhaven National Lab. (BNL), Upton, NY (United States); Onasch, T. B. [Aerodyne Research, Billerica, MA (United States)

    2016-04-01

    Interpreting the temporal relationship between the scattering and incandescence signals recorded by the Single Particle Soot Photometer (SP2), Sedlacek et al. (2012) reported that 60% of the refractory black carbon containing particles in a plume containing biomass burning tracers exhibited non-core-shell structure. Because the relationship between the rBC (refractory black carbon) incandescence and the scattering signals had not been reported in the peer-reviewed literature, and to further evaluate the initial interpretation by Sedlacek et al., a series of experiments was undertaken to investigate black carbon-containing particles of known morphology using Regal black (RB), a proxy for collapsed soot, as the light-absorbing substance to characterize this signal relationship. Particles were formed by coagulation of RB with either a solid substance (sodium chloride or ammonium sulfate) or a liquid substance (dioctyl sebacate), and by condensation with dioctyl sebacate, the latter experiment forming particles in a core-shell configuration. Each particle type experienced fragmentation (observed as negative lagtimes), and each yielded similar lagtime responses in some instances, confounding attempts to differentiate particle morphology using current SP2 lagtime analysis. SP2 operating conditions, specifically laser power and sample flow rate, which in turn affect the particle heating and dissipation rates, play an important role in the behavior of particles in the SP2, including probability of fragmentation. This behavior also depended on the morphology of the particles and on the thermochemical properties of the non-RB substance. Although these influences cannot currently be unambiguously separated, the SP2 analysis may still provide useful information on particle mixing states and black carbon particle sources. This work was communicated in a 2015 publication (Sedlacek et al. 2015)

  5. On the diurnal cycle of urban aerosols, black carbon and the occurrence of new particle formation events in springtime São Paulo, Brazil

    Directory of Open Access Journals (Sweden)

    J. Backman

    2012-12-01

    Full Text Available Large conurbations are a significant source of the anthropogenic pollution and demographic differences between cities that result in a different pollution burden. The metropolitan area of São Paulo (MASP, population 20 million accounts for one fifth of the Brazilian vehicular fleet. A feature of MASP is the amount of ethanol used by the vehicular fleet, known to exacerbate air quality. The study describes the diurnal behaviour of the submicron aerosol and relies on total particle number concentration, particle number size distribution, light scattering and light absorption measurements. Modelled planetary boundary layer (PBL depth and air mass movement data were used to aid the interpretation. During morning rush-hour, stagnant air and a shallow PBL height favour the accumulation of aerosol pollution. During clear-sky conditions, there was a wind shift towards the edge of the city indicating a heat island effect with implications on particulate pollution levels at the site. The median total particle number concentration for the submicron aerosol typically varied in the range 1.6 × 104–3.2 × 104 cm−3 frequently exceeding 4 × 104 cm−3 during the day. During weekdays, nucleation-mode particles are responsible for most of the particles by numbers. The highest concentrations of total particle number concentrations and black carbon (BC were observed on Fridays. Median diurnal values for light absorption and light scattering (at 637 nm wavelength varied in the range 12–33 Mm−1 and 21–64 Mm−1, respectively. The former one is equal to 1.8–5.0 μg m−3 of BC. The growth of the PBL, from the morning rush-hour until noon, is consistent with the diurnal cycle of BC mass concentrations. Weekday hourly median single-scattering albedo (ω0 varied in the range 0.59–0.76. Overall, this suggests a top of atmosphere (TOA warming effect. However

  6. Particle detectors and black holes

    International Nuclear Information System (INIS)

    The author recalls the elevator experiment which ultimately led Einstein to his formulation of General Relativity. In addition to the classical falling weights, flashlights, etc, the author suggests the experimenter also take along a particle detector. This detector will be a particularly simple detector consisting of a Schroedinger particle of mass m in a box with walls impermeable to the detector particle. From the equivalence principle, the detector particle in the accelerated elevator will be in an effective potential maz where z is the coordinate in the direction of the acceleration a, measured from let's say, the center of the detector. The author gives a derivation of the detection process. (Auth.)

  7. MORPHOLOGY OF BLACK CARBON AEROSOLS AND UBIQUITY OF 50-NANOMETER BLACK CARBON AEROSOLS IN THE ATMOSPHERE

    Institute of Scientific and Technical Information of China (English)

    Fengfu Fu; Liangjun Xu; Wei Ye; Yiquan Chen; Mingyu Jiang; Xueqin Xu

    2006-01-01

    Different-sized aerosols were collected by an Andersen air sampler to observe the detailed morphology of the black carbon (BC) aerosols which were separated chemically from the other accompanying aerosols, using a Scanning Electron Microscope equipped with an Energy Dispersive X-ray Spectrometer (SEM-EDX). The results indicate that most BC aerosols are spherical particles of about 50 nm in diameter and with a homogeneous surface. Results also show that these particles aggregate with other aerosols or with themselves to form larger agglomerates in the micrometer range. The shape of these 50-nm BC spherical particles was found to be very similar to that of BC particles released from petroleum-powered vehicular internal combustion engines. These spherical BC particles were shown to be different from the previously reported fullerenes found using Matrix-Assisted Laser Desorption/Ionization Time-Of-Flight Mass Spectrometry (MALDI-TOF-MS).

  8. Applicability of a noise-based model to estimate in-traffic exposure to black carbon and particle number concentrations in different cultures.

    Science.gov (United States)

    Dekoninck, Luc; Botteldooren, Dick; Panis, Luc Int; Hankey, Steve; Jain, Grishma; S, Karthik; Marshall, Julian

    2015-01-01

    Several studies show that a significant portion of daily air pollution exposure, in particular black carbon (BC), occurs during transport. In a previous work, a model for the in-traffic exposure of bicyclists to BC was proposed based on spectral evaluation of mobile noise measurements and validated with BC measurements in Ghent, Belgium. In this paper, applicability of this model in a different cultural context with a totally different traffic and mobility situation is presented. In addition, a similar modeling approach is tested for particle number (PN) concentration. Indirectly assessing BC and PN exposure through a model based on noise measurements is advantageous because of the availability of very affordable noise monitoring devices. Our previous work showed that a model including specific spectral components of the noise that relate to engine and rolling emission and basic meteorological data, could be quite accurate. Moreover, including a background concentration adjustment improved the model considerably. To explore whether this model could also be used in a different context, with or without tuning of the model parameters, a study was conducted in Bangalore, India. Noise measurement equipment, data storage, data processing, continent, country, measurement operators, vehicle fleet, driving behavior, biking facilities, background concentration, and meteorology are all very different from the first measurement campaign in Belgium. More than 24h of combined in-traffic noise, BC, and PN measurements were collected. It was shown that the noise-based BC exposure model gives good predictions in Bangalore and that the same approach is also successful for PN. Cross validation of the model parameters was used to compare factors that impact exposure across study sites. A pooled model (combining the measurements of the two locations) results in a correlation of 0.84 when fitting the total trip exposure in Bangalore. Estimating particulate matter exposure with traffic

  9. Black carbon, particle number concentration and nitrogen oxide emission factors of random in-use vehicles measured with the on-road chasing method

    Directory of Open Access Journals (Sweden)

    I. Ježek

    2015-06-01

    Full Text Available The chasing method was used in an on-road measurement campaign, and emission factors (EF of black carbon (BC, particle number (PN and nitrogen oxides (NOx were determined for 139 individual vehicles of different types encountered on the roads. The aggregated results provide EFs for BC, NOx and PN for three vehicle categories: goods vehicles, gasoline and diesel passenger cars. This is the first on-road measurement study where BC EFs of numerous individual diesel cars were determined in real-world driving conditions. We found good agreement between EFs of goods vehicles determined in this campaign and the results of previous studies that used either chasing or remote sensing measurement techniques. The composition of the sampled car fleet determined from the national vehicle registry information is reflective of Eurostat statistical data on the Slovenian and European vehicle fleet. The median BC EF of diesel and gasoline cars that were in use for less than 5 years, decreased by 60 and 47% from those in use for 5–10 years, respectively, the median NOx and PN EFs, of goods vehicles that were in use for less than five years, decreased from those in use for 5–10 years by 52 and 67%, respectively. The influence of engine maximum power of the measured EFs showed an increase in NOx EF from least to more powerful vehicles with diesel engines. Finally a disproportionate contribution of high emitters to the total emissions of the measured fleet was found; the top 25% of emitting diesel cars contributed 63, 47 and 61% of BC, NOx and PN emissions respectively. With the combination of relatively simple on-road measurements with sophisticated post processing individual vehicles EF can be determined and useful information about the fleet emissions can be obtained by exactly representing vehicles which contribute disproportionally to vehicle fleet emissions; and monitor how the numerous emission reduction approaches are reflected in on-road driving

  10. Electromagnetic properties of carbon black and barium titanate composite materials

    Energy Technology Data Exchange (ETDEWEB)

    Wang Guiqin [School of Material Science and Engineering, Dalian University of Technology, Dalian 116023 (China)], E-mail: c2b2chen@163.com; Chen Xiaodong; Duan Yuping; Liu Shunhua [School of Material Science and Engineering, Dalian University of Technology, Dalian 116023 (China)

    2008-04-24

    Nanocrystalline carbon black/barium titanate compound particle (CP) was synthesized by sol-gel method. The phase structure and morphology of compound particle were investigated by X-ray diffraction (XRD), transmission electron microscope (TEM) and Raman spectrum measurements, the electroconductivity was test by trielectrode arrangement and the precursor powder was followed by differential scanning calorimetric measurements (DSC) and thermal gravimetric analysis (TGA). In addition, the complex relative permittivity and permeability of compound particle were investigated by reflection method. The compound particle/epoxide resin composite (CP/EP) with different contents of CP were measured. The results show barium titanate crystal is tetragonal phase and its grain is oval shape with 80-100 nm which was coated by carbon black film. As electromagnetic (EM) complex permittivity, permeability and reflection loss (RL) shown that the compound particle is mainly a kind of electric and dielectric lossy materials and exhibits excellent microwave absorption performance in the X- and Ku-bands.

  11. Spacetime noncommutative effect on black hole as particle accelerators

    OpenAIRE

    Ding, Chikun; Liu, Changqing; Qian GUO

    2013-01-01

    We study the spacetime noncommutative effect on black hole as particle accelerators and, find that particle falling from infinity with zero velocity cannot collide with unbound energy when the noncommutative Kerr black hole is exactly extremal. Our results also show that the bigger of the spinning black hole's mass is, the higher of center of mass energy that the particles obtain. For small and medium noncommutative Schwarzschild black hole, the collision energy depends on the black holes' mass.

  12. Longitudinal variability of black carbon vertical profiles

    Science.gov (United States)

    Schwarz, J. P.; Weinzierl, B.; Samset, B. H.; Perring, A. E.; Dollner, M.; Heimerl, K.; Markovic, M. Z.; Ziemba, L. D.

    2015-12-01

    Black carbon (BC) aerosol contributes substantially to both climate forcing and climate forcing uncertainty. An important source of this uncertainty derives from the difficulty in predicting BC's global abundance and vertical distribution. Here we present a multi-year record of black carbon (BC) vertical concentration profiles from both sides of the Atlantic, obtained from airborne Single Particle Soot Photometers (SP2s) flown on the NASA DC-8, and the DLR Falcon research aircraft from the CONCERT, ACCESS, DC3, SEAC4RS, and SALTRACE campaigns. The measurements constrain the relative rates of BC transport/removal from, and zonal mixing in, the upper troposphere, as well as the range of BC loadings in these regions. They also constrain the time-rates of change of BC loads in altitudes at which it is a highly efficient (although sparse) climate forcer, and a relatively long-lived aerosol tracer. We find that concentration of BC in the upper troposphere can vary by a factor 10. Over the Northern mid-latitudes concentrations are however consistent to a fraction of this range over wide longitudinal ranges, over month-long timescales. The data show that BC becomes zonally mixed here starting at 500 hPa and extending to near the tropopause. These results imply broader value than previously associated with measured vertical profiles in constraining global scale BC loadings aloft.

  13. Particle creation rate for general black holes

    CERN Document Server

    Firouzjaee, Javad T

    2015-01-01

    We present the particle creation probability rate around a general black hole as an outcome of quantum fluctuations. Using the uncertainty principle for these fluctuation, we derive a new ultraviolet frequency cutoff for the radiation spectrum of a dynamical black hole. Using this frequency cutoff, we define the probability creation rate function for such black holes. We consider a dynamical Vaidya model, and calculate the probability creation rate for this case when its horizon is in a slowly evolving phase. Our results show that one can expect the usual Hawking radiation emission process in the case of a dynamical black hole when it has a slowly evolving horizon. Moreover, calculating the probability rate for a dynamical black hole gives a measure of when Hawking radiation can be killed off by an incoming flux of matter or radiation. Our result strictly suggests that we have to revise the Hawking radiation expectation for primordial black holes that have grown substantially since they were created in the ea...

  14. Black carbon, particle number concentration and nitrogen oxide emission factors of random in-use vehicles measured with the on-road chasing method

    Science.gov (United States)

    Ježek, I.; Katrašnik, T.; Westerdahl, D.; Močnik, G.

    2015-10-01

    The chasing method was used in an on-road measurement campaign, and emission factors (EF) of black carbon (BC), particle number (PN) and nitrogen oxides (NOx) were determined for 139 individual vehicles of different types encountered on the roads. The aggregated results provide EFs for BC, NOx and PN for three vehicle categories: goods vehicles, gasoline and diesel passenger cars. This is the first on-road measurement study where BC EFs of numerous individual diesel cars were determined in real-world driving conditions. We found good agreement between EFs of goods vehicles determined in this campaign and the results of previous studies that used either chasing or remote-sensing measurement techniques. The composition of the sampled car fleet determined from the national vehicle registry information is reflective of Eurostat statistical data on the Slovenian and European vehicle fleet. The median BC EF of diesel and gasoline cars that were in use for less than 5 years decreased by 60 and 47 % from those in use for 5-10 years, respectively; the median NOx and PN EFs of goods vehicles that were in use for less than 5 years decreased from those in use for 5-10 years by 52 and 67 %, respectively. Surprisingly, we found an increase of BC EFs in the newer goods vehicle fleet compared to the 5-10-year old one. The influence of engine maximum power of the measured EFs showed an increase in NOx EF from least to more powerful vehicles with diesel engines. Finally, a disproportionate contribution of high emitters to the total emissions of the measured fleet was found; the top 25 % of emitting diesel cars contributed 63, 47 and 61 % of BC, NOx and PN emissions respectively. With the combination of relatively simple on-road measurements and sophisticated post processing, individual vehicle EF can be determined and useful information about the fleet emissions can be obtained by exactly representing vehicles which contribute disproportionally to vehicle fleet emissions; and

  15. Carbon-Supported Iron Oxide Particles

    DEFF Research Database (Denmark)

    Meaz, T.; Mørup, Steen; Koch, C. Bender

    1996-01-01

    A carbon black ws impregnated with 6 wt% iron using an aqueous solution of iron nitrate. The impregnated carbon was initially dried at 125 C. The effect of heating of the iron oxide phase was investigated at temperatures between 200 and 600 C using Mossbauer spectroscopy. All heat treatments were...... done in an oxygen-containing atmosphere. Ferrihydrite is formed and is stable at and below a temperature of 300 C. At 600 C small particles of maghemite is the dominant iron oxide. A transformation reaction is suggested....

  16. MAP4K4 deficiency in CD4(+) T cells aggravates lung damage induced by ozone-oxidized black carbon particles.

    Science.gov (United States)

    Jin, Ming; Chu, Hongqian; Li, Yuan; Tao, Xi; Cheng, Zhiyuan; Pan, Yao; Meng, Qinghe; Li, Leilei; Hou, Xiaohong; Chen, Yueyue; Huang, Hongpeng; Jia, Guang; Shang, Jing; Zhu, Tong; Shang, Lanqin; Hao, Weidong; Wei, Xuetao

    2016-09-01

    As the main composition of combustion, black carbon (BC) is becoming more and more noticeable at home and abroad. Ozone-oxidized black carbon (oBC) was produced through aging of ozone, one of the near-surface pollutants, to black carbon. And oBC was found to be more oxidation and cell toxicity when compared with BC. Besides, as a key cell of immunity, whether CD4(+) T cell would involve in lung inflammation induced by particular matter is still unclear. This study aims to observe the effect of oBC on lung damage in mice and discuss how the functional MAP4K4 defect CD4(+) T cells (conditional knockout of MAP4K4) presents its role in this process. In our study, MAP4K4 deletion in CD4(+) T cells (MAP4K4 cKO) could increase cell number of macrophages, lymphocytes and neutrophils in bronchoalveolar lavage fluid (BALF) exposed to oBC. MAP4K4 deletion in CD4(+) T cell also affected CD4(+) T cell differentiation in mediastinal lymph nodes after oBC stimulation. The number of CD4(+) IL17(+) T cell increased obviously. The levels of IL-6 mRNA of lung in MAP4K4 cKO mice was higher than that in wild type mice after exposed to oBC, while the level of IL-6 in BALF had the same trend. Histological examination showed that MAP4K4 deletion in CD4(+) T cells affected lung inflammation induced by oBC. Results indicated that MAP4K4 cKO in CD4(+) T cells upgraded the level of inflammation in lung when exposed to oBC, which may be connected to the CD4(+) T cell differentiation and JNK, ERK and P38 pathways. PMID:27504712

  17. Effect of emissions uncertainty and variability on high-resolution concentrations of carbon monoxide, fine particle black carbon, and nitrogen oxides in Fort Collins, Colorado: development of a Bayesian uncertainty modeling and evaluation framework

    Science.gov (United States)

    Mendoza, D. L.; Stuart, A. L.; Dagne, G.; Yu, H.

    2013-12-01

    Uncertainties in emissions estimates are known to be one of the primary sources of uncertainty in calculating concentrations and subsequent exposure estimates. Despite continued improvement in the accuracy of emissions downscaling, the quantification of uncertainties is necessary in order to generate a representative emissions product. Bayesian data assimilation is a promising approach to uncertainty estimation when used to calibrate model results with measurement data. This study discusses an emissions inventory and concentration estimates for carbon monoxide (CO), fine particle (PM2.5) black carbon, and nitrogen oxides (NOx) for the city of Fort Collins, Colorado. The development of a Bayesian framework for updating estimates of emissions and concentrations in multiple stages, using measurement data, is also presented. The emissions inventory was constructed using the 2008 National Emissions Inventory (NEI). The spatial and temporal allocation methods from the Emission Modeling Clearinghouse data set are used to downscale the NEI data from annual and county-level resolution for point, nonpoint, and nonroad sources. Onroad mobile source emissions were estimated by combining a bottom-up emissions calculation approach (using emission factors and activities) for large roadway links within Fort Collins with a top-down spatial allocation approach for other roadways. Vehicle activity data for road links were obtained from local 2009 travel demand model results and automatic traffic recorder (ATR) data. The CALPUFF Gaussian puff dispersion model was used to estimate air pollutant concentrations. Hourly, 1.33 km x 1.33 km MM5 meteorological data was used to capture temporal variability in transport. Distributions of concentrations are obtained for spatial locations and time spans using a Monte Carlo sampling approach. Data for ensemble members are sampled from distributions defined from the emissions inventory and meteorological data. Modeled concentrations of CO, PM2

  18. Are black carbon and soot the same?

    Directory of Open Access Journals (Sweden)

    P. R. Buseck

    2012-09-01

    Full Text Available The climate change and environmental literature, including that on aerosols, is replete with mention of black carbon (BC, but neither reliable samples nor standards exist. Thus, there is uncertainty about its exact nature. That confusion can be avoided if terms are defined and widely understood. Here we discuss an ambiguity between BC and soot and propose a more precise definition for soot as a specific material, which we call ns-soot, where "ns" refers to carbon nanospheres. We define ns-soot as particles that consist of nanospheres, typically with diameters < 100 nm, that possess distinct structures of concentrically wrapped, graphene-like layers of carbon and with grape-like (acinoform morphologies. We additionally propose that, because of their importance for climate modeling and health issues, distinctions are made among bare, coated, and embedded ns-soot. BC, on the other hand, is not a well-defined material. We propose that the term should be restricted to light-absorbing refractory carbonaceous matter of uncertain character and that the uncertainty is stated explicitly.

  19. High energy particle collisions near black holes

    Directory of Open Access Journals (Sweden)

    Zaslavskii O. B.

    2016-01-01

    Full Text Available If two geodesic particles collide near a rotating black hole, their energy in the centre of mass frame Ec.m. can become unbound under certain conditions (the so-called BSW effect. The special role is played here by so-called critical geodesics when one of particles has fine-tuned energy and angular momentum. The nature of geodesics reveals itself also in fate of the debris after collisions. One of particles moving to a remote observer is necessarily near-critical. We discuss, when such a collision can give rise not only unboud Ec.m. but also unbound Killing energy E (so-called super-Penrose process.

  20. A black potential for spin less particles

    Energy Technology Data Exchange (ETDEWEB)

    Ghatak, Ananya, E-mail: gananya04@gmail.com [Department of Physics, Banaras Hindu University, Varanasi 221005 (India); Hasan, Mohammad, E-mail: mohammadhasan786@gmail.com [ISRO Satellite Centre (ISAC), Bangalore 560017 (India); Mandal, Bhabani Prasad, E-mail: bhabani@bhu.ac.in [Department of Physics, Banaras Hindu University, Varanasi 221005 (India)

    2015-07-03

    We consider the most general non-Hermitian Hulthen potential to study the scattering of spin-less relativistic particles. The conditions for CC, SS and CPA are obtained analytically for this potential. We show that almost total absorption occurs for entire range of incidence energy for certain parameter ranges of the potential and hence term this as ‘black potential’. Time reversed of the same potential shows perfect emission for the entire range of particle energy. We also present the classical analog of this potential in terms of waveguide cross section. - Highlights: • Relativistic scattering properties of a spin zero particle due to most general non-Hermitian Hulthen potential are discussed. • Analytical conditions for CC, CPA and SS are obtained. • Broadband CPA is obtained for entire range of incidence energy. • Non-Hermitian Hulthen potential is parametrized in such a way to show broadband CPA and/or CC. • Waveguide analog of such potential is presented.

  1. Determination of black carbon in fine particles using a semi-continuous method at two sites in the city of Guadalajara, Mexico, during 2007.

    Science.gov (United States)

    Hernández-Mena, Leonel; Saldarriaga-Noreña, Hugo; Murillo-Tovar, Mario A; Amador-Muñoz, Omar; López-López, Alberto; Waliszewski, Stefan M

    2011-09-01

    The black carbon is a pollutant species primarily emitted from the combustion of fossil fuels (diesel). Their concentrations associated to PM2.5 were monitoring at two sites in the city of Guadalajara. From January to May (except April), downtown site shown 2.7, 2.6, 4.0 and 2.3 times higher monthly concentrations. The dry season two showed higher concentrations respect to at least one of the others seasons (p < 0.0001) at each site, probably due to atmospheric conditions less favorable for the dispersal of pollutants. During the 24 h period were observed at the year two peaks of concentrations: the highest morning peak and lower night peak, both probably related to anthropogenic activity.

  2. Particles and scalar waves in noncommutative charged black hole spacetime

    OpenAIRE

    Bhar, Piyali; Rahaman, Farook; Biswas, Ritabrata(Indian Institute of Engineering Sceince and Technology Shibpur (Formerly, Bengal Engineering and Science University Shibpur), 711 013, Howrah, West Bengal, India); Mondal, U. F.

    2015-01-01

    In this paper we have discussed geodesics and the motion of test particle in the gravitational field of noncommutative charged black hole spacetime. The motion of massive and massless particle have been discussed seperately. A comparative study of noncommutative charged black hole and usual Reissner-Nordstrom black hole has been done. The study of effective potential has also been included. Finally, we have examined the scattering of scalar waves in noncommutative charged black hole spacetime.

  3. Particles and Scalar Waves in Noncommutative Charged Black Hole Spacetime

    Science.gov (United States)

    Piyali, Bhar; Farook, Rahaman; Ritabrata, Biswas; U. F., Mondal

    2015-07-01

    In this paper we have discussed geodesics and the motion of test particle in the gravitational field of non-commutative charged black hole spacetime. The motion of massive and massless particle have been discussed seperately. A comparative study of noncommutative charged black hole and usual Reissner-Nordström black hole has been done. The study of effective potential has also been included. Finally, we have examined the scattering of scalar waves in noncommutative charged black hole spacetime.

  4. Spacetime Noncommutative Effect on Black Hole as Particle Accelerators

    Science.gov (United States)

    Ding, Chikun; Liu, Changqing; Quo, Qian

    2013-03-01

    We study the spacetime noncommutative effect on black hole as particle accelerators and, find that the particles falling from infinity with zero velocity cannot collide with unbound energy, either near the horizon or on the prograde ISCO when the noncommutative Kerr black hole is exactly extremal. Our results also show that the bigger of the spinning black hole's mass is the higher of center of mass energy that the particles obtain. For small and medium noncommutative Schwarzschild black hole, the collision energy depends on the black hole's mass.

  5. Pyrolytic carbon black composite and method of making the same

    Energy Technology Data Exchange (ETDEWEB)

    Naskar, Amit K.; Paranthaman, Mariappan Parans; Bi, Zhonghe

    2016-09-13

    A method of recovering carbon black includes the step of providing a carbonaceous source material containing carbon black. The carbonaceous source material is contacted with a sulfonation bath to produce a sulfonated material. The sulfonated material is pyrolyzed to produce a carbon black containing product comprising a glassy carbon matrix phase having carbon black dispersed therein. A method of making a battery electrode is also disclosed.

  6. Black carbon, a short lived climate forcer

    International Nuclear Information System (INIS)

    Black carbon, an indicator of urban pollution health effects, is at the heart of adaptation issues as benefits of its control can be felt both at the scale of climate phenomenon and air quality. This element has to do with several notions whose definitions need to be stated again. It sets urban policies at the crossing of climate, air pollution, population health and sustainable development stakes. The CITEPA has made available Mark Tuddenham's literature monitoring concerning black carbon, and, more widely, SLFC (Short lived climate forcers). (authors)

  7. Black carbon and fine particle emissions in Finnish residential wood combustion: Emission projections, reduction measures and the impact of combustion practices

    Science.gov (United States)

    Savolahti, Mikko; Karvosenoja, Niko; Tissari, Jarkko; Kupiainen, Kaarle; Sippula, Olli; Jokiniemi, Jorma

    2016-09-01

    Residential wood combustion (RWC) is a major source of black carbon (BC) and PM2.5 emissions in Finland. Making a robust assessment of emissions on a national level is a challenge due to the varying heater technologies and the effect of users' combustion practices. In this paper we present an update of the emission calculation scheme for Finnish RWC, including technology-specific emission factors based on national measurements. Furthermore, we introduce a transparent method to assess the impact of poor combustion practices on emissions. Using a Finnish emission model, we assessed the emissions in 2000, 2010 and 2030, as well as the cost-efficiency of potential emission reduction measures. The results show that RWC is the biggest source of both PM2.5 and BC emissions in Finland, accounting for 37% and 55% of the total respective emissions. It will also remain the biggest source in the future, and it's role may become even more pronounced if wood consumption continues to increase. Sauna stoves cause the most emissions and also show the biggest potential for emission reductions. Informational campaigns targeted to improve heater users' combustion practices appear as a highly cost-efficient measure, although their impact on country-level emissions was estimated to be relatively limited.

  8. Studies of activated carbon and carbon black for supercapacitor applications

    Energy Technology Data Exchange (ETDEWEB)

    Richner, R.; Mueller, S.; Koetz, R.; Wokaun, A. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    Carbon Black and activated carbon materials providing high surface areas and a distinct pore distribution are prime materials for supercapacitor applications at frequencies < 0.5 Hz. A number of these materials were tested for their specific capacitance, surface and pore size distribution. High capacitance electrodes were manufactured on the laboratory scale with attention to ease of processability. (author) 1 fig., 1 ref.

  9. Hawking Radiation from Elko Particles Tunnelling across Black Strings Horizon

    CERN Document Server

    da Rocha, Roldao

    2014-01-01

    We apply the tunnelling method for the emission and absorption of Elko particles in the event horizon of a black string solution. We show that Elko particles are emitted at the expected Hawking temperature from black strings, but with a quite different signature with respect to the Dirac particles. We employ the Hamilton-Jacobi technique to black hole tunnelling, by applying the WKB approximation to the coupled system of Dirac-like equations governing the Elko particle dynamics. As a typical signature, different Elko particles are shown to produce the same standard Hawking temperature for black strings. However we prove that they present the same probability irrespective of outgoing or ingoing the black hole horizon. It provides a typical signature for mass dimension one fermions, that is different from the mass dimension three halves fermions inherent to Dirac particles, as different Dirac spinor fields have distinct inward and outward probability of tunnelling.

  10. Emission of scalar particles from cylindrical black holes

    OpenAIRE

    Gohar, H.; Saifullah, K.

    2011-01-01

    We study quantum tunneling of scalar particles from black strings. For this purpose we apply WKB approximation and Hamilton-Jacobi method to solve the Klein-Gordon equation for outgoing trajectories. We find the tunneling probability of outgoing charged and uncharged scalars from the event horizon of black strings, and hence the Hawking temperature for these black configurations.

  11. Emission of scalar particles from cylindrical black holes

    Science.gov (United States)

    Gohar, H.; Saifullah, K.

    2013-01-01

    We study quantum tunneling of scalar particles from black strings. For this purpose we apply WKB approximation and Hamilton-Jacobi method to solve the Klein-Gordon equation for outgoing trajectories. We find the tunneling probability of outgoing charged and uncharged scalars from the event horizon of black strings, and hence the Hawking temperature for these black configurations.

  12. Black hole particle emission in higher-dimensional spacetimes.

    Science.gov (United States)

    Cardoso, Vitor; Cavaglià, Marco; Gualtieri, Leonardo

    2006-02-24

    In models with extra dimensions, a black hole evaporates both in the bulk and on the visible brane, where standard model fields live. The exact emissivities of each particle species are needed to determine how the black hole decay proceeds. We compute and discuss the absorption cross sections, the relative emissivities, and the total power output of all known fields in the evaporation phase. Graviton emissivity is highly enhanced as the spacetime dimensionality increases. Therefore, a black hole loses a significant fraction of its mass in the bulk. This result has important consequences for the phenomenology of black holes in models with extra dimensions and black hole detection in particle colliders. PMID:16606074

  13. Comparative analysis of black carbon in soils

    Science.gov (United States)

    Schmidt, Michael W. I.; Skjemstad, Jan O.; Czimczik, Claudia I.; Glaser, Bruno; Prentice, Ken M.; Gelinas, Yves; Kuhlbusch, Thomas A. J.

    2001-03-01

    Black carbon (BC), produced by incomplete combustion of fossil fuels and vegetation, occurs ubiquitously in soils and sediments. BC exists as a continuum from partly charred material to highly graphitized soot particles, with no general agreement on clear-cut boundaries of definition or analysis. In a comparative analysis, we measured BC forms in eight soil samples by six established methods. All methods involved removal of the non-BC components from the sample by thermal or chemical means or a combination of both. The remaining carbon, operationally defined as BC, was quantified via mass balance, elemental composition or by exploiting benzenecarboxylic acids as molecular markers or applying 13C MAS NMR (magic angle spinning nuclear magnetic resonance) spectroscopy. BC concentrations measured for individual samples vary over 2 orders of magnitude (up to a factor of 571). One possible explanation for this wide range of results is that the individual BC methods rely on operational definitions with clear-cut but different boundaries and developed for specific scientific questions, whereas BC represents a continuum of materials with widely contrasting physicochemical properties. Thus the methods are inherently designed to analytically determine different parts of the continuum, and it is crucial to know how measurements made by different techniques relate to each other. It is clear from this preliminary comparative analysis that a collection of BC reference materials should be established as soon as possible 1 ) to ensure long-term intralaboratory and interlaboratory data quality and 2) to facilitate comparative analyses between different analytical techniques and scientific approaches

  14. Modified carbon black materials for lithium-ion batteries

    Energy Technology Data Exchange (ETDEWEB)

    Kostecki, Robert; Richardson, Thomas; Boesenberg, Ulrike; Pollak, Elad; Lux, Simon

    2016-06-14

    A lithium (Li) ion battery comprising a cathode, a separator, an organic electrolyte, an anode, and a carbon black conductive additive, wherein the carbon black has been heated treated in a CO.sub.2 gas environment at a temperature range of between 875-925 degrees Celsius for a time range of between 50 to 70 minutes to oxidize the carbon black and reduce an electrochemical reactivity of the carbon black towards the organic electrolyte.

  15. Black carbon concentrations and mixing state in the Finnish Arctic

    Science.gov (United States)

    Raatikainen, T.; Brus, D.; Hyvärinen, A.-P.; Svensson, J.; Asmi, E.; Lihavainen, H.

    2015-09-01

    Atmospheric aerosol composition was measured using a Single Particle Soot Photometer (SP2) in the Finnish Arctic during winter 2011-2012. The Sammaltunturi measurement site at the Pallas GAW (Global Atmosphere Watch) station receives air masses from different source regions including the Arctic Ocean and continental Europe. The SP2 provides detailed information about mass distributions and mixing state of refractory black carbon (rBC). The measurements showed widely varying rBC mass concentrations (0-120 ng m-3), which were related to varying contributions of different source regions and aerosol removal processes. The rBC mass was log-normally distributed showing a relatively constant rBC core mass mean diameter with an average of 194 nm (75-655 nm sizing range). On average, the number fraction of particles containing rBC was 0.24 (integrated over 350-450 nm particle diameter range) and the average particle diameter to rBC core volume equivalent diameter ratio was 2.0 (averaged over particles with 150-200 nm rBC core volume equivalent diameters). These average numbers mean that the observed rBC core mass mean diameter is similar to those of aged particles, but the observed particles seem to have unusually high particle to rBC core diameter ratios. Comparison of the measured rBC mass concentration with that of the optically detected equivalent black carbon (eBC) using an Aethalometer and a MAAP showed that eBC was larger by a factor of five. The difference could not be fully explained without assuming that only a part of the optically detected light absorbing material is refractory and absorbs light at the wavelength used by the SP2. Finally, climate implications of five different black carbon mixing state representations were compared using the Mie approximation and simple direct radiative forcing efficiency calculations. These calculations showed that the observed mixing state means significantly lower warming effect or even a net cooling effect when compared with

  16. Massive Vector Particles Tunneling From Noncommutative Charged Black Holes

    CERN Document Server

    Övgün, Ali

    2015-01-01

    In this paper, we investigate the tunneling process of charged massive bosons $W^{\\pm}$ (spin-1 particles) from noncommutative charged black holes such as charged RN black holes and charged BTZ black holes. By applying the WKB approximation and by using the Hamilton-Jacobi equation we derive the tunneling rate and the corresponding Hawking temperature for those black holes configuration. The tunneling rate shows that the radiation deviates from pure thermality and is consistent with an underlying unitary theory.

  17. Hawking radiation of Dirac particles from black strings

    Science.gov (United States)

    Ahmed, Jamil; Saifullah, K.

    2011-08-01

    Hawking radiation has been studied as a phenomenon of quantum tunneling in different black holes. In this paper we extend this semi-classical approach to cylindrically symmetric black holes. Using the Hamilton-Jacobi method and WKB approximation we calculate the tunneling probabilities of incoming and outgoing Dirac particles from the event horizon and find the Hawking temperature of these black holes. We obtain results both for uncharged as well as charged particles.

  18. Hawking radiation of Dirac particles from black strings

    CERN Document Server

    Ahmed, Jamil

    2011-01-01

    Hawking radiation has been studied as a phenomenon of quantum tunneling in different black holes. In this paper we extend this semi-classical approach to cylindrically symmetric black holes. Using the Hamilton-Jacobi method and WKB approximation we calculate the tunneling probabilities of incoming and outgoing Dirac particles from the event horizon and find the Hawking temperature of these black holes. We obtain results both for uncharged as well as charged particles.

  19. Massive particle radiation from Gibbons-Maeda black hole

    Institute of Scientific and Technical Information of China (English)

    Fang Heng-Zhong

    2010-01-01

    This paper investigated the massive particle radiation from Gibbous-Maeda black hole by using a semi-classical method. The calculations showed that, if the self-gravitation of the radiated particle is taken into account, the radiation spectrum deviates from exact black body spectrum and the rate of tunneling equals precisely the exponent of the difference of the black hole entropies before and after emission. The conclusion supports the viewpoint of information conservation.

  20. Opportunities and Challenges for Being a Carbon Black Great Power

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    1. The "Uth Five-year Plan" Lay- ing the Foundation for Carbon Black Great Power 1.1 Rapid growth of carbon black output and production capacity During the "llth Five-year Plan" Period, China carbon black output was increased by 1.1 times and realized doubling; and the production capacity of carbon black realized an average annu- al growth of 16.9%. In 2011, the carbon black output was 3.853 million tons, increased by 14.2% compared with that of the last year, and the pro- portion of carbon black output in the world carbon black output was increased from 16% to 36%. The carbon black production capacity was 5.345 mil- lion tons, increased by 6% compared with that of the last year, and the proportion of carbon black production capacity in the world carbon black out- put reached 38%. Chinese carbon black output has been ranking the 1st place throughout the world for 6 years successively, and China has become a great power of carbon black production in the world.

  1. Measuring black carbon spectral extinction in the visible and infrared

    Science.gov (United States)

    Smith, A. J. A.; Peters, D. M.; McPheat, R.; Lukanihins, S.; Grainger, R. G.

    2015-09-01

    This work presents measurements of the spectral extinction of black carbon aerosol from 400 nm to 15 μm. The aerosol was generated using a Miniature Combustion Aerosol Standard soot generator and then allowed to circulate in an aerosol cell where its extinction was measured using a grating spectrometer in the visible and a Fourier transform spectrometer in the infrared. Size distribution, number concentration, and mass extinction cross sections have also been obtained using single-particle aerosol samplers. A mean mass extinction cross section at 550 nm of 8.3 ± 1.6 m2 g-1 is found which, assuming a reasonable single scatter albedo of 0.2, corresponds to a mass absorption cross section of 6.6 ± 1.3 m2 g-1. This compares well with previously reported literature values. Computer analysis of electron microscope images of the particles provides independent confirmation of the size distribution as well as fractal parameters of the black carbon aerosol. The aerosol properties presented in this work are representative of very fresh, uncoated black carbon aerosol. After atmospheric processing of such aerosols (which could include mixing with other constituents and structural changes), different optical properties would be expected.

  2. Charged spinning black holes as accelerators of spinning particles

    CERN Document Server

    Zhang, Yu-Peng; Wei, Shao-Wen; Yang, Jie; Liu, Yu-Xiao

    2016-01-01

    It is well known that some black holes can act as accelerators for particles without spin. Recently, there are some works considering collision of two spinning particles in the background of Schwarzschild and Kerr black holes and it was shown that the spin of the test particles is related to the center-of-mass energy. In this paper we extend the results to some more general cases. We consider Kerr-Newman black holes as accelerators for spinning particles. We derive the center-of-mass energy of the spinning particles and use numerical method to investigate how the center-of-mass energy is affected by the properties of the black holes and spinning particles.

  3. Massive Particle's Tunnelling from Black Hole with Topological Defect

    Institute of Scientific and Technical Information of China (English)

    HAN Yi-Wen

    2007-01-01

    We extend Zhang and Zhao's recent work to black hole with topological defect whose Arnowitt-Deser-Misner mass is no longer identical to its mass parameter. The behaviour of the tunnelling massive particles is investigated,and the emission rate at which massive particles tunnel across the event horizon of the black hole is calculated.The result is consistent with an underlying unitary theory, and takes the same functional form as that of mass-less particles.

  4. Surface modification of inorganic black particles for electrophoretic display

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sang Deuk; Ahn, Woo Jin; Choi, Hyoung Jin [Inha University, Incheon (Korea, Republic of)

    2014-11-15

    Inorganic black particles (Black 444) were modified with poly(methyl methacrylate) as a shell material by using dispersion polymerization to improve their dispersion stability in a medium oil for electrophoretic display applications. They were also positively charged with vinylimidazole to enhance their electrophoretic mobility. The morphology and the shape of the composite particles were characterized by using scanning electron microscopy. The thermal properties and the chemical structure of the samples were examined by using thermogravimetric analysis and Fourier transform infrared spectroscopy, respectively. In addition, the electrophoretic mobility and the zeta-potential of the black444 /PMMA /vinylimidazole particles in a dielectric fluid were measured by using optical microscopy and electrophoretic light scattering. With increasing positive charge, the black444 /PMMA /vinylimidazole particles showed improved electrophoretic characteristics compared to pristine Black 444.

  5. Black carbon characterization in Quebec black spruce forests

    Science.gov (United States)

    Soucemarianadin, Laure; Quideau, Sylvie; Wasylishen, Roderick; MacKenzie, M. Derek

    2014-05-01

    Black carbon (BC), an important component of the global soil carbon pool, is a major by-product of wildfires in Quebec black spruce forests. However, BC characteristics vary depending on the environmental conditions under which it is formed and this may further affect its resistance to degradation. The objective of this study was to characterize the chemical and physical properties of BC formed under variable fire severity to assess its potential for recalcitrance as a passive carbon pool. Samples (n = 267) of BC produced by early season wildfires in 2005-2007 were collected from the surface of black spruce forest floors to cover the range of severity encountered in these fire-affected forests. Representative samples (n = 33) were then analyzed using elemental analysis, solid-state 13C nuclear magnetic resonance (NMR) spectroscopy, scanning electron microscopy and surface area analysis (BET method). Properties of BC sampled in the field were compared with those of samples produced under a range of controlled formation conditions in the laboratory. The NMR spectra of the BC collected on sites affected by low fire severity showed a distribution of total intensity between the different spectral regions very similar to those of unburned fuels, and were dominated by peaks indicative of cellulose, while spectra for BC from higher fire severity sites were dominated by a broad peak assigned to aromatic carbons. Atomic H/C and O/C ratios decreased along the fire severity gradient, confirming that increasing severity was associated with an increase in condensation. By comparing field- to laboratory-produced samples, we concluded that the temperature of formation in the field ranged between 75 and 250 ° C. In all analyzed BC samples, the fraction of aromatic carbon:total carbon was low, suggesting that the freshly produced BC in this boreal forest environment may be susceptible to rapid physical alteration and chemical degradation. Nevertheless, it is important to highlight

  6. Black hole bombs and explosions: from astrophysics to particle physics

    CERN Document Server

    Cardoso, Vitor

    2013-01-01

    Black holes are the elementary particles of gravity, the final state of sufficiently massive stars and of energetic collisions. With a forty-year long history, black hole physics is a fully-blossomed field which promises to embrace several branches of theoretical physics. Here I review the main developments in highly dynamical black holes with an emphasis on high energy black hole collisions and probes of particle physics via superradiance. This write-up, rather than being a collection of well known results, is intended to highlight open issues and the most intriguing results.

  7. Black Hole Atom as a Dark Matter Particle Candidate

    Directory of Open Access Journals (Sweden)

    V. I. Dokuchaev

    2014-01-01

    Full Text Available We propose the new dark matter particle candidate—the “black hole atom,” which is an atom with the charged black hole as an atomic nucleus and electrons in the bound internal quantum states. As a simplified model we consider the the central Reissner-Nordström black hole with the electric charge neutralized by the internal electrons in bound quantum states. For the external observers these objects would look like the electrically neutral Schwarzschild black holes. We suppose the prolific production of black hole atoms under specific conditions in the early universe.

  8. Black Hole Atom as a Dark Matter Particle Candidate

    International Nuclear Information System (INIS)

    We propose the new dark matter particle candidate—the “black hole atom,” which is an atom with the charged black hole as an atomic nucleus and electrons in the bound internal quantum states. As a simplified model we consider the the central Reissner-Nordström black hole with the electric charge neutralized by the internal electrons in bound quantum states. For the external observers these objects would look like the electrically neutral Schwarzschild black holes. We suppose the prolific production of black hole atoms under specific conditions in the early universe

  9. Black carbon measurements using an integrating sphere

    Science.gov (United States)

    Hitzenberger, R.; Dusek, U.; Berner, A.

    1996-08-01

    An integrating sphere was used to determine the black carbon (BC) content of aerosol filter samples dissolved in chloroform (method originally described by Heintzenberg [1982]). The specific absorption coefficient Ba (equal to absorption per mass) of the samples was also measured using the sphere as an integrating detector for transmitted light. Comparing the Ba of ambient samples taken in Vienna, Austria, to the BC concentrations measured on the dissolved filters, a value of approximately 6 m2/g was found to be a reasonable value for the Ba of the black carbon found at the site. The size dependence of Ba of a nebulized suspension of soot was measured using a rotating impactor, and a reasonable agreement between measured and calculated values was found.

  10. Dynamics of Particles Near Black Hole with Higher Dimensions

    CERN Document Server

    Sharif, M

    2016-01-01

    This paper explores the dynamics of particles in higher dimensions. For this purpose, we discuss some interesting features related to the motion of particles near Myers-Perry black hole with arbitrary extra dimensions as well as single non-zero spin parameter. Assuming it as a supermassive black hole at the center of galaxy, we calculate red-blue shifts in the equatorial plane for the far away observer as well as corresponding black hole parameters of the photons. Next, we study the Penrose process and find that the energy gain of particle depends on the variation of black hole dimensions. Finally, we discuss the center of mass energy for eleven dimensions which indicates similar behavior as that of four dimensions but it is higher in four dimensions than five or more dimensions. We conclude that higher dimensions have a great impact on the particle dynamics.

  11. Modified Wave Particle Duality and Black Hole Physics

    Institute of Scientific and Technical Information of China (English)

    LI Xiang

    2007-01-01

    de Broglie relation is revisited, in consideration of a generalization of canonical commuting relation. The possible effects on particle's localization and black hole physics are also discussed, in a heuristic manner.

  12. Evaluation of Methods for the Determination of Black Carbon Emissions from an Aircraft Gas Turbine Engine

    Science.gov (United States)

    The emissions from aircraft gas turbine engines consist of nanometer size black carbon (BC) particles plus gas-phase sulfur and organic compounds which undergo gas-to-particle conversion downstream of the engine as the plume cools and dilutes. In this study, four BC measurement ...

  13. Atmospheric black carbon and warming effects influenced by the source and absorption enhancement in central Europe

    NARCIS (Netherlands)

    Nordmann, S.; Cheng, Y.F.; Carmichael, G.R.; Yu, M.; Denier Van Der Gon, H.A.C.; Zhang, Q.; Saide, P.E.; Pöschl, U.; Su, H.; Birmili, W.; Wiedensohler, A.

    2014-01-01

    Particles containing black carbon (BC), a strong absorbing substance, exert a rather uncertain direct and indirect radiative forcing in the atmosphere. To investigate the mass concentration and absorption properties of BC particles over central Europe, the model WRF-Chem was used at a resolution of

  14. PTCR effect in carbon black/copolymer composites

    Science.gov (United States)

    Costa, L. C.; Chakki, A.; Achour, M. E.; Graça, M. P. F.

    2011-01-01

    Some materials show an abrupt increase in resistivity when the temperature changes only over a few degrees. This phenomenon, known as PTCR effect (positive temperature coefficient of resistivity), has been largely studied in the last few years, due to its potential applications in industry. Particularly, it can be used in auto controlled heaters, temperature sensors, protection circuits and in security systems for power electronic circuits. In this work we present the study of the electrical properties of the percolating system carbon black particles filled with ethylene butylacrylate copolymer composite (EBA), in the temperature range from -100 to 100 °C and in frequencies between 10 Hz and 100 kHz. The PTCR effect was observed at temperatures slightly above the room temperature, for concentrations higher than that of the percolation critical concentration. The mechanism responsible for the change in resistivity, at this stage, is predominantly tunnelling, wherein the conductive filler particles are not in physical contact, and the electrons tunnel through the insulating gap between them. At low temperatures, such as below and close to the glass transition temperature, the DC conductivity obeys the Arrhenius law. The calculated activation energy values are independent of carbon black contents inside the copolymer matrix, suggesting that these particles do not interact significantly with the chain segments of the macromolecules in the EBA copolymer.

  15. Tunneling of massive particles from noncommutative Schwarzschild black hole

    CERN Document Server

    Miao, Yan-Gang; Zhang, Shao-Jun

    2010-01-01

    We apply the generalization of the Parikh-Wilczek method to the tunneling of massive particles from noncommutative Schwarzschild black holes. By deriving the equation of radial motion of the tunneling particle directly, we calculate the emission rate which is shown to be dependent on the noncommutative parameter besides the energy and mass of the tunneling particle. After equating the emission rate to the Boltzmann factor, we obtain the modified Hawking temperature which relates to the noncommutativity and recovers the standard Hawking temperature in the commutative limit. We also discuss the entropy of the noncommutative Schwarzchild black hole and its difference after and before a massive particle's emission.

  16. Tunneling of massive particles from noncommutative inspired Schwarzschild black hole

    Science.gov (United States)

    Miao, Yan-Gang; Xue, Zhao; Zhang, Shao-Jun

    2012-02-01

    We apply the generalization of the Parikh-Wilczek method to the tunneling of massive particles from noncommutative inspired Schwarzschild black holes. By deriving the equation of radial motion of the tunneling particle directly, we calculate the emission rate which is shown to be dependent on the noncommutative parameter besides the energy and mass of the tunneling particle. After equating the emission rate to the Boltzmann factor, we obtain the modified Hawking temperature which relates to the noncommutativity and recovers the standard Hawking temperature in the commutative limit. We also discuss the entropy of the noncommutative inspired Schwarzschild black hole and its difference after and before a massive particle's emission.

  17. Recommendations for the interpretation of "black carbon" measurements

    Directory of Open Access Journals (Sweden)

    A. Petzold

    2013-04-01

    Full Text Available Although black carbon (BC is one of the key atmospheric particulate components driving climate change and air quality, there is no agreement on the terminology that considers all aspects of specific properties, definitions, measurement methods, and related uncertainties. As a result, there is much ambiguity in the scientific literature of measurements and numerical models that refer to BC with different names and based on different properties of the particles, with no clear definition of the terms. The authors present here a recommended terminology to clarify the terms used for BC in atmospheric research, with the goal of establishing unambiguous links between terms, targeted material properties and associated measurement techniques.

  18. Carbon black directed synthesis of ultrahigh mesoporous carbon aerogels

    OpenAIRE

    Macías, Carlos; Haro Remón, Marta; Rasines, Gloria; Parra Soto, José Bernardo; Ovín Ania, María Concepción

    2013-01-01

    [EN] A simple modification of the conventional sol–gel polymerization of resorcinol–formaldehyde mixtures allowed a facile preparation of ultrahigh mesoporous carbon gels. In the conventional synthesis the growth of the cluster polymer particles leading to the development of the porosity is controlled by the R/C ratio. In the presence of a carbon conductive additive, the polymerization of the reactants proceeded through the formation of less-branched polymer clusters resulting in carbon gels ...

  19. Quantum Radiation of Dirac Particles in General Nonstationary Black Holes

    CERN Document Server

    Hua, J C; Hua, Jia-Chen; Huang, Yong-Chang

    2006-01-01

    Quantum radiation of Dirac particles in general nonstationary black holes in the general case is investigated by using the method of generalized tortoise coordinate transformation and considering simultaneously the asymptotic behaviors of the first order and second order forms of Dirac equation near the event horizon. It is generally shown that the temperature and the shape of the event horizon of this kind of black holes depend on both the time and different angles. Further, we give a general expression of the new extra coupling effect in thermal radiation spectrum of Dirac particles which is absent from the thermal radiation spectrum of scalar particles. Also, we reveal a relationship that is ignored before between thermal radiation and non-thermal radiation in the case of scalar particles, which is that the chemical potential in thermal radiation spectrum is equal to the highest energy of the negative energy state of scalar particles in non-thermal radiation for general nonstationary black holes.

  20. Black holes are neither particle accelerators nor dark matter probes.

    Science.gov (United States)

    McWilliams, Sean T

    2013-01-01

    It has been suggested that maximally spinning black holes can serve as particle accelerators, reaching arbitrarily high center-of-mass energies. Despite several objections regarding the practical achievability of such high energies, and demonstrations past and present that such large energies could never reach a distant observer, interest in this problem has remained substantial. We show that, unfortunately, a maximally spinning black hole can never serve as a probe of high energy collisions, even in principle and despite the correctness of the original diverging energy calculation. Black holes can indeed facilitate dark matter annihilation, but the most energetic photons can carry little more than the rest energy of the dark matter particles to a distant observer, and those photons are actually generated relatively far from the black hole where relativistic effects are negligible. Therefore, any strong gravitational potential could probe dark matter equally well, and an appeal to black holes for facilitating such collisions is unnecessary.

  1. Black Holes are neither Particle Accelerators nor Dark Matter Probes

    CERN Document Server

    McWilliams, Sean T

    2012-01-01

    It has been suggested that maximally spinning black holes can serve as particle accelerators, reaching arbitrarily high center-of-mass energies. Despite several objections regarding the practical achievability of such high energies, and demonstrations past and present that such large energies could never reach a distant observer, interest in this problem has remained substantial. We show that, unfortunately, a maximally spinning black hole can never serve as a probe of high energy collisions, even in principle and despite the correctness of the original diverging energy calculation. Black holes can indeed facilitate dark matter annihilation, but the most energetic photons can carry little more than the rest energy of the dark matter particles to a distant observer, and those photons are actually generated relatively far from the black hole where relativistic effects are negligible. Therefore, any strong gravitational potential could probe dark matter equally well, and an appeal to black holes for facilitating...

  2. Reinforcing Effects of Carbon Black on Asphalt Binder for Pavement

    OpenAIRE

    Yamaguchi, Katsuyuki; Sasaki, Iwao; Nishizaki, Itaru; Meiarashi, Seishi; Moriyoshi, Akihiro

    2005-01-01

    Carbon black, used as a reinforcing filler for rubber materials, was evaluated for asphalt binders in pavements. Carbon black added to straight asphalt within 20 wt% caused an increase in the elastic modulus and a decrease in the viscosity of the asphalt, especially at temperatures higher than room temperature. Addition of carbon black raised the maximum service temperature of asphalt in the category of the binder performance grade according to the SHRP (Strategic Highway Research Program) sp...

  3. Characterization of PM2.5 particles originating from a modern waste incineration plant by factor analysis of chemical data, mass and black carbon in ambient aerosol

    DEFF Research Database (Denmark)

    Aboh, Innocent Joy Kwame; Henrikson, Dag; Laursen, Jens;

    In the city of Borås, which is a medium sized city in the south-western part of Sweden, a new modern plant for electricity and heat generation has recently been installed and optimised with respect to internal parameters of efficiency and economy. The direct emissions of gaseous pollutants which...... are subject to restrictions are well below the allowed limits as stated by Swedish and European standards. The aim of the present work is to study the particle pollutants with emphasis on PM2.5 in the ambient air and to identify the specific contribution from the new incineration plant. Many different sources...... contribute to PM2.5 in urban air. Thus, the general problem is to characterise and identify the particle pollution, which can be attributed to gases and/or particles emitted by the waste incineration plant. For this reason aerosol samples, PM2.5, were collected and analyzed for concentrations of twenty...

  4. Is Carbon Black a Suitable Model Colloidal Substrate for Diesel Soot?

    Science.gov (United States)

    Growney, David J; Mykhaylyk, Oleksandr O; Middlemiss, Laurence; Fielding, Lee A; Derry, Matthew J; Aragrag, Najib; Lamb, Gordon D; Armes, Steven P

    2015-09-29

    Soot formation in diesel engines is known to cause premature engine wear. Unfortunately, genuine diesel soot is expensive to generate, so carbon blacks are often used as diesel soot mimics. Herein, the suitability of a commercial carbon black (Regal 250R) as a surrogate for diesel soot dispersed in engine base oil is examined in the presence of two commonly used polymeric lubricant additives. The particle size, morphology, and surface composition of both substrates are assessed using BET surface area analysis, TEM, and XPS. The extent of adsorption of a poly(ethylene-co-propylene) (dOCP) statistical copolymer or a polystyrene-block-poly(ethylene-co-propylene) (PS-PEP) diblock copolymer onto carbon black or diesel soot from n-dodecane is compared indirectly using a supernatant depletion assay technique via UV spectroscopy. Thermogravimetric analysis is also used to directly determine the extent of copolymer adsorption. Degrees of dispersion are examined using optical microscopy, TEM, and analytical centrifugation. SAXS studies reveal some structural differences between carbon black and diesel soot particles. The mean radius of gyration determined for the latter is significantly smaller than that calculated for the former, and in the absence of any copolymer, diesel soot suspended in n-dodecane forms relatively loose mass fractals compared to carbon black. SAXS provides evidence for copolymer adsorption and indicates that addition of either copolymer transforms the initially compact agglomerates into relatively loose aggregates. Addition of dOCP or PS-PEP does not significantly affect the structure of the carbon black primary particles, with similar results being observed for diesel soot. In favorable cases, remarkably similar data can be obtained for carbon black and diesel soot when using dOCP and PS-PEP as copolymer dispersants. However, it is not difficult to identify simple copolymer-particle-solvent combinations for which substantial differences can be observed

  5. Carbon fuel particles used in direct carbon conversion fuel cells

    Science.gov (United States)

    Cooper, John F.; Cherepy, Nerine

    2012-10-09

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  6. 黑土团聚体与颗粒中碳、氮含量及腐殖质组成的比较%Comparison of Carbon, Nitrogen Contents and Humus Compositions in the Aggregates and Particles of Black Soil

    Institute of Scientific and Technical Information of China (English)

    窦森; 郝翔翔

    2013-01-01

    [目的]研究黑土不同粒级团聚体和颗粒中的碳、氮及腐殖质组分含量,并分析、比较土壤团聚体与土壤颗粒中腐殖质相互关系.[方法]以黑土区连续9年的耕作试验为平台,采用湿筛法分离土壤团聚体,超声波方法分离土壤颗粒,分别测定不同粒级团聚体和土壤颗粒中的碳、氮、胡敏酸(HA)、富里酸(FA)、铁结合胡敏素(Hi)、黏粒结合胡敏素(Hc)和不溶性胡敏素(Hr)的含量.[结果]>53μm粒级颗粒中的碳、氮以及HA、FA、Hi和Hc的含量明显低于<53 μm粒级颗粒,而>53 μm和<53 μm粒级团聚体中的碳、氮以及HA、FA、Hi和Hc的含量则基本处于同一水平.因此,形成团聚体的过程,弱化了粒级之间有机质的差异.相同粒级比较,在>53 μm粒级中,团聚体比颗粒含有更多的腐殖质,且PQ值和腐殖质化程度大于颗粒;但在<53 μm粒级中,团聚体和颗粒中腐殖质的含量和PQ值则处于同一水平,说明在较大粒级中,由于同样也包含了小颗粒的作用,强化了团聚体与颗粒中有机质的差异.[结论]土壤团聚体与土壤颗粒中碳、氮以及腐殖质各组分含量随粒级变化的规律存在着明显差异.不同粒级土壤颗粒中有机质的含量差异及其腐殖化程度差异会随着团聚化作用减弱.%[Objective] The objective of this study was to research the contents of carbon,nitrogen and humus composition in different aggregates and particle-size fractions of black soil,to analyze and compare the relationship of humus in the soil aggregate and particle-size fractions.[Method] The research platform was an 9-years field experiment carried out in black soil region,and soil aggregates and particles were separated by wet sieving and ultrasonic method,respectively.The contents of total C,N,the composition of humic substance (HS) in soil aggregates and particle-size fractions,were investigated respectively.[Result] The contents of C,N,humic acid (HA

  7. Vector particles tunneling from four-dimensional Schwarzschild black holes

    Science.gov (United States)

    Chen, Ge-Rui; Zhou, Shiwei; Huang, Yong-Chang

    2015-05-01

    Vector particles' Hawking radiation from a four-dimensional Schwarzschild black hole is investigated. By applying the WKB approximation and the Hamilton-Jacobi ansatz to the Proca equation, we obtain the tunneling spectrum of vector particles and the expected Hawking temperature.

  8. Quantum hoop conjecture: Black hole formation by particle collisions

    International Nuclear Information System (INIS)

    We address the issue of (quantum) black hole formation by particle collision in quantum physics. We start by constructing the horizon wave-function for quantum mechanical states representing two highly boosted non-interacting particles that collide in flat one-dimensional space. From this wave-function, we then derive a probability that the system becomes a black hole as a function of the initial momenta and spatial separation between the particles. This probability allows us to extend the hoop conjecture to quantum mechanics and estimate corrections to its classical counterpart.

  9. Study of Black Sand Particles from Sand Dunes in Badr, Saudi Arabia Using Electron Microscopy

    Directory of Open Access Journals (Sweden)

    Haider Abbas Khwaja

    2015-08-01

    Full Text Available Particulate air pollution is a health concern. This study determines the microscopic make-up of different varieties of sand particles collected at a sand dune site in Badr, Saudi Arabia in 2012. Three categories of sand were studied: black sand, white sand, and volcanic sand. The study used multiple high resolution electron microscopies to study the morphologies, emission source types, size, and elemental composition of the particles, and to evaluate the presence of surface “coatings or contaminants” deposited or transported by the black sand particles. White sand was comprised of natural coarse particles linked to wind-blown releases from crustal surfaces, weathering of igneous/metamorphic rock sources, and volcanic activities. Black sand particles exhibited different morphologies and microstructures (surface roughness compared with the white sand and volcanic sand. Morphological Scanning Electron Microscopy (SEM and Laser Scanning Microscopy (LSM analyses revealed that the black sand contained fine and ultrafine particles (50 to 500 nm ranges and was strongly magnetic, indicating the mineral magnetite or elemental iron. Aqueous extracts of black sands were acidic (pH = 5.0. Fe, C, O, Ti, Si, V, and S dominated the composition of black sand. Results suggest that carbon and other contaminant fine particles were produced by fossil-fuel combustion and industrial emissions in heavily industrialized areas of Haifa and Yanbu, and transported as cloud condensation nuclei to Douf Mountain. The suite of techniques used in this study has yielded an in-depth characterization of sand particles. Such information will be needed in future environmental, toxicological, epidemiological, and source apportionment studies.

  10. Horizon structure of rotating Bardeen black hole and particle acceleration

    International Nuclear Information System (INIS)

    We investigate the horizon structure and ergosphere in a rotating Bardeen regular black hole, which has an additional parameter (g) due to the magnetic charge, apart from the mass (M) and the rotation parameter (a). Interestingly, for each value of the parameter g, there exists a critical rotation parameter (a = aE), which corresponds to an extremal black hole with degenerate horizons, while for a < aE it describes a non-extremal black hole with two horizons, and no black hole for a > aE. We find that the extremal value aE is also influenced by the parameter g, and so is the ergosphere. While the value of aE remarkably decreases when compared with the Kerr black hole, the ergosphere becomes thicker with the increase in g.We also study the collision of two equal mass particles near the horizon of this black hole, and explicitly show the effect of the parameter g. The center-of-mass energy (ECM) not only depend on the rotation parameter a, but also on the parameter g. It is demonstrated that the ECM could be arbitrarily high in the extremal cases when one of the colliding particles has a critical angular momentum, thereby suggesting that the rotating Bardeen regular black hole can act as a particle accelerator. (orig.)

  11. Black hole with a scalar field as a particle accelerator

    CERN Document Server

    Zaslavskii, O B

    2016-01-01

    We consider black holes with the background scalar field and test particles that can interact with this field directly. Then, particle collision near a black hole can lead to unbound energy $E_{c.m.}$ in the centre of mass frame (contrary to some recent claims in literature). This happens if one of particles is neutral whereas another one has nonzero scalar charge. Kinematically, two cases occur here. (i) A neutral particle approaches the horizon with the speed of light while the velocity of the charged one remains separated from it (this is direct analogue of the situation with collision of geodesic particles.). (ii) Both particles approach the horizon with the speed almost equal to that of light but with different rates. As a result, in both cases the relative velocity also approaches the speed of light, so that $E_{c.m.}$ $\\ $becomes unbound.

  12. Intercontinental transport of black carbon to the Arctic free troposphere

    Science.gov (United States)

    Liu, Dantong; Quennehen, Boris; Allan, James; Darbyshire, Eoghan; Williams, Paul; Taylor, Jonathan; Flynn, Michael; Bower, Keith; Coe, Hugh

    2015-04-01

    Black carbon has a large radiative forcing potential in the Arctic, through altering the atmosphere's radiative balance and also initiating ice melt after deposition. Here we present an analysis of aerosol data collected aboard the UK Facility for Airborne Atmospheric Measurements (FAAM) BAe-146 research aircraft during five flights in the free troposphere in the region of Svalbard in March 2013 as part of the Natural Environment Research Council (NERC) Aerosol-Cloud Coupling and Climate Interaction in the Arctic (ACCACIA) project. A number of discrete layers of pollution typical of continental emissions were detected, evidenced by black carbon (measured using a single particle soot photometer), carbon monoxide, organic matter and sulphate (measured using an aerosol mass spectrometer). These were detected at all altitudes within the free troposphere (up to 8 km) and potential source regions were investigated on a plume-by-plume basis using FLEXPART and HYSPLIT. Continental areas were identified as separate potential sources for the different plumes, with transit times of up to 12 days. East Asia showed the strongest influence, being responsible for high concentration plumes at all layers and Europe was found to be responsible for plumes in the lower to mid troposphere. North America had a somewhat weaker influence and no significant influence from Northern Russia was found. Emissions inventory data was used in conjunction with the FLEXPART potential source footprints to try to estimate the relative significance of different sources and it was found that direct emissions from human activities (e.g. transport, industry) were more prevalent than open biomass burning. Significant loadings were detected (of the order of 100 ng sm-3 black carbon relative to CO concentrations of around 50 ppbv) even when instrumental data and model outputs suggest that significant precipitation occurred during uplift, indicating that inefficient scavenging is taking place.

  13. Black hole multiplicity at particle colliders (Do black holes radiate mainly on the brane?)

    OpenAIRE

    Cavaglia, Marco

    2003-01-01

    If gravity becomes strong at the TeV scale, we may have the chance to produce black holes at particle colliders. In this paper we study some experimental signatures of black hole production in TeV-gravity theories. In contrast with the usual lore, we show that the black hole energy loss in the bulk during the Hawking evaporation phase may be of the same order of the energy radiated into the brane. We investigate in detail the multiplicity of the decay products of black hole evaporation. We fi...

  14. Properties of particles in the ergosphere of black holes

    CERN Document Server

    Grib, A A

    2016-01-01

    A new feature of the rotating black holes is the existence in their ergosphere of trajectories of particles with negative and zero energies. Here we analyze general properties of such trajectories comparing them with usual trajectories of particles with positive energy. A comparison with the situation in rotating coordinate frame in Minkowski space-time is made. The possibility of the unbounded growth of the energy of two colliding particles in the centre of mass frame in the ergosphere is analysed.

  15. Tunneling of massive particles from noncommutative inspired Schwarzschild black hole

    OpenAIRE

    Miao, Yan-Gang; Xue, Zhao; Zhang, Shao-Jun

    2010-01-01

    We apply the generalization of the Parikh-Wilczek method to the tunneling of massive particles from noncommutative inspired Schwarzschild black holes. By deriving the equation of radial motion of the tunneling particle directly, we calculate the emission rate which is shown to be dependent on the noncommutative parameter besides the energy and mass of the tunneling particle. After equating the emission rate to the Boltzmann factor, we obtain the modified Hawking temperature which relates to t...

  16. Black hole multiplicity at particle colliders (Do black holes radiate mainly on the brane?)

    International Nuclear Information System (INIS)

    If gravity becomes strong at the TeV scale, we may have the chance to produce black holes at particle colliders. In this Letter we revisit some phenomenological signatures of black hole production in TeV-gravity theories. We show that the bulk-to-brane ratio of black hole energy loss during the Hawking evaporation phase depends crucially on the black hole greybody factors and on the particle degrees of freedom. Since the greybody factors have not yet been calculated in the literature, and the particle content at trans-Planckian energies is not known, it is premature to claim that the black hole emits mainly on the brane. We also revisit the decay time and the multiplicity of the decay products of black hole evaporation. We give general formulae for black hole decay time and multiplicity. We find that the number of particles produced during the evaporation phase may be significantly lower than the average multiplicity which has been used in the past literature

  17. Influence of public transport in black carbon

    Science.gov (United States)

    Vasquez, Y.; Oyola, P.; Gramsch, E. V.; Moreno, F.; Rubio, M.

    2013-05-01

    As a consequence of poor air quality in Santiago de Chile, several measures were taken by the local authorities to improve the environmental conditions and protect the public health. In year 2005 the Chilean government implemented a project called "Transantiago" aimed to introduce major modifications in the public transportation system. The primary objectives of this project were to: provide an economically, socially and environmentally sustainable service and improve the quality of service without increasing fares. In this work we evaluate the impact of the Transantiago system on the black carbon pollution along four roads directly affected by the modification to the transport system. The black carbon has been used to evaluate changes in air quality due to changes in traffic. The assessment was done using measurements of black carbon before Transantiago (June-July 2005) and after its implementation (June-July 2007). Four sites were selected to monitor black carbon at street levels, one site (Alameda) that represents trunk-bus streets, i.e., buses crossing the city through main avenues. Buses using these streets had an important technological update with respect to 2005. Two streets (Usach and Departamental) show a mixed condition, i.e., they combine feeder and trunk buses. These streets combine new EURO III buses with old buses with more than 3 years of service. The last street (Eliodoro Yañez) represent private cars road without public transportation and did not experience change. Hence, the results from the years 2005 and 2007 can be directly compared using an appropriate methodology. To ensure that it was not the meteorological conditions that drive the trends, the comparison between year 2005 and 2007 was done using Wilcoxon test and a regression model. A first assessment at the four sites suggested a non decrease in black carbon concentration from 2005 to 2007, except for Alameda. A first statistical approach confirmed small increases in BC in Usach and E

  18. Black Holes are neither Particle Accelerators nor Dark Matter Probes

    OpenAIRE

    McWilliams, Sean T.

    2012-01-01

    It has been suggested that maximally spinning black holes can serve as particle accelerators, reaching arbitrarily high center-of-mass energies. Despite several objections regarding the practical achievability of such high energies, and demonstrations past and present that such large energies could never reach a distant observer, interest in this problem has remained substantial. We show that, unfortunately, a maximally spinning black hole can never serve as a probe of high energy collisions,...

  19. Charged Particles' Tunneling from Noncommutative Charged Black Hole

    CERN Document Server

    Mehdipour, S Hamid

    2010-01-01

    We apply the tunneling process of charged massive particles through the quantum horizon of a Reissner-Nordstr\\"om black hole in a new noncommutative gravity scenario. In this model, the tunneling amplitude on account of noncommutativity influences in the context of coordinate coherent states is modified. Our calculation points out that the emission rate satisfies the first law of black hole thermodynamics and is consistent with an underlying unitary theory.

  20. Charged particles' tunneling from a noncommutative charged black hole

    OpenAIRE

    Mehdipour, S. Hamid

    2010-01-01

    We apply the tunneling process of charged massive particles through the quantum horizon of a Reissner-Nordstrom black hole in a new noncommutative gravity scenario. In this model, the tunneling amplitude on account of noncommutativity influences in the context of coordinate coherent states is modified. Our calculation points out that the emission rate satisfies the first law of black hole thermodynamics and is consistent with an underlying unitary theory.

  1. A Particle Probing Thermodynamics in Rotating AdS Black Hole

    Science.gov (United States)

    Gwak, Bogeun; Lee, Bum-Hoon

    2016-07-01

    We briefly review the thermodynamics of a probe particle absorption to a black hole in this proceeding. The particle energy has a relation to its momenta at the horizon of the black hole. Following this relation, the particle infinitesimally changes the black hole mass and momenta. Under these changes, the changes of properties of the black hole are consistent with the laws of thermodynamics.

  2. Scattering of particles by deformed non-rotating black holes

    Energy Technology Data Exchange (ETDEWEB)

    Pei, Guancheng [Department of Physics, Center for Field Theory and Particle Physics, Fudan University, 200433, Shanghai (China); Bambi, Cosimo, E-mail: bambi@fudan.edu.cn [Department of Physics, Center for Field Theory and Particle Physics, Fudan University, 200433, Shanghai (China); Theoretical Astrophysics, Eberhard-Karls Universität Tübingen, 72076, Tübingen (Germany)

    2015-11-27

    We study the excitation of axial quasi-normal modes of deformed non-rotating black holes by test particles and we compare the associated gravitational wave signal with that expected in general relativity from a Schwarzschild black hole. Deviations from standard predictions are quantified by an effective deformation parameter, which takes into account deviations from both the Schwarzschild metric and the Einstein equations. We show that, at least in the case of non-rotating black holes, it is possible to test the metric around the compact object, in the sense that the measurement of the gravitational wave spectrum can constrain possible deviations from the Schwarzschild solution.

  3. Scattering of particles by deformed non-rotating black holes

    Energy Technology Data Exchange (ETDEWEB)

    Pei, Guancheng [Fudan University, Department of Physics, Center for Field Theory and Particle Physics, Shanghai (China); Bambi, Cosimo [Fudan University, Department of Physics, Center for Field Theory and Particle Physics, Shanghai (China); Eberhard-Karls Universitaet Tuebingen, Theoretical Astrophysics, Tuebingen (Germany)

    2015-11-15

    We study the excitation of axial quasi-normal modes of deformed non-rotating black holes by test particles and we compare the associated gravitational wave signal with that expected in general relativity from a Schwarzschild black hole. Deviations from standard predictions are quantified by an effective deformation parameter, which takes into account deviations from both the Schwarzschild metric and the Einstein equations. We show that, at least in the case of non-rotating black holes, it is possible to test the metric around the compact object, in the sense that the measurement of the gravitational wave spectrum can constrain possible deviations from the Schwarzschild solution. (orig.)

  4. Effect of sterilization on mineralization of straw and black carbon

    DEFF Research Database (Denmark)

    Bobul'ská, Lenka; Bruun, Sander; Fazekašová, Danica

    2013-01-01

    The study was aimed at investigating the role of microorganisms in the degradation of BC (black carbon). CO evolution was measured under sterilized and non-sterilized soil using BC and straw amendments. Black carbon and straw were produced from homogenously C labelled roots of barley (Hordeum vul...... abiotic source must also be present perhaps abiotic mineralization of labile BC components....

  5. Double-walled carbon nanotubes synthesized using carbon black as the dot carbon source

    Science.gov (United States)

    Chen, Zhi-Gang; Li, Feng; Ren, Wen-Cai; Cong, Hongtao; Liu, Chang; Qing Lu, Gao; Cheng, Hui-Ming

    2006-07-01

    Double-walled carbon nanotubes (DWNTs) were synthesized used carbon black as the dot carbon source by a semi-continuous hydrogen arc discharge process. High-resolution transmission electron microscopy (HRTEM) observations revealed that most of the tubes were DWNTs with outer and inner diameters in the range of 2.67-4 nm and 1.96-3.21 nm, respectively. Most of the DWNTs were in a bundle form of about 10-30 nm in diameter with high purity (about 70%) from thermal gravimetric analysis (TGA), resonant laser Raman spectroscopy, scanning electron microscopy (SEM) and TEM characterizations. It was found that carbon black as the dot carbon source could be easy controlled to synthesize one type of nanotube. A simple process combining oxidation and acid treatment to purify the DWNT bundles was used without damaging the bundles. The structure of carbon black, as the key element for influencing purity, bundle formation and purification of DWNTs, is discussed.

  6. Preparation of Waterborne Nanoscale Carbon Black Dispersion with Sodium Carboxymethyl Cellulose

    Institute of Scientific and Technical Information of China (English)

    YUAN Xia; FANG Kuan-jun

    2006-01-01

    Waterborne nanoscale carbon black dispersion (NCBD) was widely used in inkjet printing, spun-dyeing fibers and coloration fabrics. In this paper, NCBD was prepared using sodium carboxymethyl cellulose (CMC) as dispersant.Effects of CMC viscosity, ultrasonic time and oxidation with hydrogen peroxide on carbon black (CB) particle size were discussed. The results showed that CB particle size decreased by mechanical agitation while it increased by ultrasonic with the increase of CMC viscosity. Ultrasonic is a more effective method to disperse CB particles than that of mechanical agitation. CB particle size obviously decreased with increasing ultrasonic time and arrived at about 160 nm for 60 min. In addition, oxidation with 2 mol/L of H2O2 and 0.2 wt% of CMC300 reduced CB particle size to 160 nm at 90℃ for 2.5 h.

  7. Thermal properties of carbon black aqueous nanofluids for solar absorption

    Directory of Open Access Journals (Sweden)

    Han Dongxiao

    2011-01-01

    Full Text Available Abstract In this article, carbon black nanofluids were prepared by dispersing the pretreated carbon black powder into distilled water. The size and morphology of the nanoparticles were explored. The photothermal properties, optical properties, rheological behaviors, and thermal conductivities of the nanofluids were also investigated. The results showed that the nanofluids of high-volume fraction had better photothermal properties. Both carbon black powder and nanofluids had good absorption in the whole wavelength ranging from 200 to 2,500 nm. The nanofluids exhibited a shear thinning behavior. The shear viscosity increased with the increasing volume fraction and decreased with the increasing temperature at the same shear rate. The thermal conductivity of carbon black nanofluids increased with the increase of volume fraction and temperature. Carbon black nanofluids had good absorption ability of solar energy and can effectively enhance the solar absorption efficiency.

  8. Mesozoic black shales, source mixing and carbon isotopes

    Science.gov (United States)

    Suan, Guillaume

    2016-04-01

    Over the last decades, considerable attention has been devoted to the paleoenvironmental and biogeochemical significance of Mesozoic black shales. Black shale-bearing successions indeed often display marked changes in the organic carbon isotope composition (δ13Corg), which have been commonly interpreted as evidence for dramatic perturbations of global carbon budgets and CO2 levels. Arguably the majority of these studies have discarded some more "local" explanations when interpreting δ13Corg profiles, most often because comparable profiles occur on geographically large and distant areas. Based on newly acquired data and selected examples from the literature, I will show that the changing contribution of organic components with distinct δ13C signatures exerts a major but overlooked influence of Mesozoic δ13Corg profiles. Such a bias occurs across a wide spectrum of sedimentological settings and ages, as shown by the good correlation between δ13Corg values and proxies of kerogen proportions (such as rock-eval, biomarker, palynofacies and palynological data) recorded in Mesozoic marginal to deep marine successions of Triassic, Jurassic and Cretaceous age. In most of these successions, labile, 12C-enriched amorphous organic matter of marine origin dominates strata deposited under anoxic conditions, while oxidation-resistant, 13C-rich terrestrial particles dominate strata deposited under well-oxygenated conditions. This influence is further illustrated by weathering profiles of Toarcian (Lower Jurassic) black shales from France, where weathered areas dominated by refractory organic matter show dramatic 13C-enrichment (and decreased total organic carbon and pyrite contents) compared to non-weathered portions of the same horizon. The implications of these results for chemostratigraphic correlations and pCO2 reconstructions of Mesozoic will be discussed, as well as strategies to overcome this major bias.

  9. Wetting and Non-Wetting Models of Black Carbon Activation

    Science.gov (United States)

    Henson, B. F.; Laura, S.

    2006-12-01

    We present the results of recent modeling studies on the activation of black carbon (BC) aerosol to form cloud condensation nuclei (CCN). We use a model of BC activation based on a general modification of the Koehler equation for insoluble activation in which we introduce a term based on the activity of water adsorbed on the particle surface. We parameterize the model using the free energy of adsorption, a parameter directly comparable to laboratory measurements of water adsorption on carbon. Although the model of the water- surface interaction is general, the form of the activation equation that results depends upon a further model of the distribution of water on the particle. One possible model involves the symmetric growth of a water shell around the isoluble particle core (wetting). This model predicts upper and lower bounding curves for the activation supersaturation given by the range of water interaction energies from hydrophobic to hydrophilic which are in agreement with a large body of recent activation data. The resulting activation diameters are from 3 to 10 times smaller than activation of soluble particles of identical dry diameter. Another possible model involves an exluded liquid droplet growing in contact with the particle (non-wetting). The geometry of this model much more resembles classic assumptions of heterogeneous nucleation theory. This model can yield extremely high activation supersaturation as a function of diameter, as has been observed in some experiments, and enables calculations in agreement with some of these results. We discuss these two geometrical models of water growth, the different behaviors predicted by the resulting activation equation, and the means to determine which model of growth is appropriate for a given BC particle characterized by either water interaction energy or morphology. These simple models enable an efficient and physically reasonable means to calculate the activation of BC aerosol to form CCN based upon a

  10. Cycling of black carbon in the ocean

    Science.gov (United States)

    Coppola, Alysha I.; Druffel, Ellen R. M.

    2016-05-01

    Black carbon (BC) is a by-product of combustion from wildfires and fossil fuels and is a slow-cycling component of the carbon cycle. Whether BC accumulates and ages on millennial time scales in the world oceans has remained unknown. Here we quantified dissolved BC (DBC) in marine dissolved organic carbon isolated by solid phase extraction at several sites in the world ocean. We find that DBC in the Atlantic, Pacific, and Arctic oceans ranges from 1.4 to 2.6 μM in the surface and is 1.2 ± 0.1 μM in the deep Atlantic. The average 14C age of surface DBC is 4800 ± 620 14C years and much older in a deep water sample (23,000 ± 3000 14C years). The range of DBC structures and 14C ages indicates that DBC is not homogeneous in the ocean. We show that there are at least two distinct pools of marine DBC, a younger pool that cycles on centennial time scales and an ancient pool that cycles on >105 year time scales.

  11. Protective effects of pulmonary epithelial lining fluid on oxidative stress and DNA single-strand breaks caused by ultrafine carbon black, ferrous sulphate and organic extract of diesel exhaust particles.

    Science.gov (United States)

    Chuang, Hsiao-Chi; Cheng, Yi-Ling; Lei, Yu-Chen; Chang, Hui-Hsien; Cheng, Tsun-Jen

    2013-02-01

    Pulmonary epithelial lining fluid (ELF) is the first substance to make contact with inhaled particulate matter (PM) and interacts chemically with PM components. The objective of this study was to determine the role of ELF in oxidative stress, DNA damage and the production of proinflammatory cytokines following physicochemical exposure to PM. Ultrafine carbon black (ufCB, 15 nm; a model carbonaceous core), ferrous sulphate (FeSO(4); a model transition metal) and a diesel exhaust particle (DEP) extract (a model organic compound) were used to examine the acellular oxidative potential of synthetic ELF and non-ELF systems. We compared the effects of exposure to ufCB, FeSO(4) and DEP extract on human alveolar epithelial Type II (A549) cells to determine the levels of oxidative stress, DNA single-strand breaks and interleukin-8 (IL-8) production in ELF and non-ELF systems. The effects of ufCB and FeSO(4) on the acellular oxidative potential, cellular oxidative stress and DNA single-strand breakage were mitigated significantly by the addition of ELF, whereas there was no decrease following treatment with the DEP extract. There was no significant effect on IL-8 production following exposure to samples that were suspended in ELF/non-ELF systems. The results of the present study indicate that ELF plays an important role in the initial defence against PM in the pulmonary environment. Experimental components, such as ufCB and FeSO(4), induced the production of oxidative stress and led to DNA single-strand breaks, which were moderately prevented by the addition of ELF. These findings suggest that ELF plays a protective role against PM-driven oxidative stress and DNA damage. PMID:23261976

  12. Selection and Characterization of Carbon Black and Surfactants for Development of Small Scale Uranium Oxicarbide Kernels

    Energy Technology Data Exchange (ETDEWEB)

    Contescu, Cristian I [ORNL

    2006-01-01

    This report supports the effort for development of small scale fabrication of UCO (a mixture of UO{sub 2} and UC{sub 2}) fuel kernels for the generation IV high temperature gas reactor program. In particular, it is focused on optimization of dispersion conditions of carbon black in the broths from which carbon-containing (UO{sub 2} {center_dot} H{sub 2}O + C) gel spheres are prepared by internal gelation. The broth results from mixing a hexamethylenetetramine (HMTA) and urea solution with an acid-deficient uranyl nitrate (ADUN) solution. Carbon black, which is previously added to one or other of the components, must stay dispersed during gelation. The report provides a detailed description of characterization efforts and results, aimed at identification and testing carbon black and surfactant combinations that would produce stable dispersions, with carbon particle sizes below 1 {micro}m, in aqueous HMTA/urea and ADUN solutions. A battery of characterization methods was used to identify the properties affecting the water dispersability of carbon blacks, such as surface area, aggregate morphology, volatile content, and, most importantly, surface chemistry. The report introduces the basic principles for each physical or chemical method of carbon black characterization, lists the results obtained, and underlines cross-correlations between methods. Particular attention is given to a newly developed method for characterization of surface chemical groups on carbons in terms of their acid-base properties (pK{sub a} spectra) based on potentiometric titration. Fourier-transform infrared (FTIR) spectroscopy was used to confirm the identity of surfactants, both ionic and non-ionic. In addition, background information on carbon black properties and the mechanism by which surfactants disperse carbon black in water is also provided. A list of main physical and chemical properties characterized, samples analyzed, and results obtained, as well as information on the desired trend or

  13. Estimation and prediction of black carbon emissions in Beijing City

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Y.; Shao, M. [Peking University, Beijing (China)

    2007-05-15

    Black carbon is a by-product of incomplete combustion of carbon containing fuels. It can alter atmospheric radiation property and make adverse impacts on human health. The energy consumption in Beijing City depends largely on coal burning. Recently, Beijing City has been performing the municipal energy structure adjustment as a tool for air pollution abatement, aiming at the air quality goal for the Beijing 2008 Olympic Games. Based on Beijing energy use data in 2000, combined with emission factors of major sources of black carbon, the emission of black carbon in Beijing City is estimated to be 7.77 Gg. Coke, raw coal and biomass as non-commercial energy are the main contributors to municipal black carbon emissions. Based on Beijing energy planning in the year 2008, the emission of black carbon in 2008 will be 2.97 Gg if the contribution from biomass is not taken into account. Assuming that the black carbon emission from rural biomass in 2008 is the same as that in 2004, the biomass burning will be the largest emitter of black carbon to Beijing City in 2008.

  14. Estimation and prediction of black carbon emissions in Beijing City

    Institute of Scientific and Technical Information of China (English)

    LIU Yuan; SHAO Min

    2007-01-01

    Black carbon is a by-product of incomplete combustion of carbon containing fuels. It can alter atmospheric radiation property and make adverse impacts on human health. The energy consumption in Beijing City depends largely on coal burning. Recently, Beijing City has been performing the municipal energy structure adjustment as a tool for air pollution abatement, aiming at the air quality goal for the Beijing 2008 Olympic Games. Based on Beijing energy use data in 2000, combined with emission factors of major sources of black carbon, the emission of black carbon in Beijing City is estimated to be 7.77 Gg. Coke, raw coal and biomass as non-commercial energy are the main contributors to municipal black carbon emissions. Based on Beijing energy planning in the year 2008, the emission of black carbon in 2008 will be 2.97 Gg if the contribution from biomass is not taken into account. Assuming that the black carbon emission from rural biomass in 2008 is the same as that in 2004, the biomass burning will be the largest emitter of black carbon to Beijing City in 2008.

  15. Addressing inconsistencies in black carbon literature

    Science.gov (United States)

    Shonkoff, S. B.; Chafe, Z.; Smith, K. R.

    2010-12-01

    The literature describing black carbon (BC) emissions, and their effect on Earth’s climate, is growing rapidly. Unfortunately, inconsistencies in definitions; data collection and characterization; system boundaries; and time horizons have led to confusion about the relative importance of BC compared to other climate-active pollutant (CAPs). We discuss three sources of confusion: 1) Currently available BC inventories are not directly comparable to those used by the IPCC to track the greenhouse gases (GHGs) considered in the Kyoto Protocol (CO2, CH4, N2O). In particular, BC inventories often include all emissions: natural and anthropogenic in origin, controllable and non-controllable. IPCC inventories include only anthropogenic emissions. This BC accounting is appropriate for atmospheric science deliberations, but risks being interpreted as an overstatement against official Kyoto GHG inventories in a policy or control context. The IPCC convention of using 1750 as the starting year for emission inventories further complicates matters: significant BC emissions were emitted previous to that date by both human and natural sources. Though none of the pre-1750 BC emissions remain in the atmosphere today, their legacy presents challenges in assigning historical responsibility for associated global warming among sectors and regional populations. 2) Inconsistencies exist in the specific emissions sources considered in atmospheric models used to predict net BC forcing often lead to widely varying climate forcing estimates. For example, while some analyses consider only fossil fuel 1, others include both open biomass burning and fossil fuel combustion 2, and yet others include sources beyond biomass and fossil fuel burning 3. 3) Inconsistencies exist in how analyses incorporate the relationship between BC emissions and the associated cooling aerosols and processes, such as organic carbon (OC), and aerosol indirect effects (AIE). Unlike Kyoto GHGs, BC is rarely emitted in pure

  16. 黑碳颗粒物表面SO2的非均相臭氧氧化%Heterogeneous Oxidation of SO2 by Ozone on the Surface of Black Carbon Particles

    Institute of Scientific and Technical Information of China (English)

    宋寒; 尚静; 朱彤; 赵黎; 叶俊辉

    2012-01-01

    采用漫反射红外傅里叶变换光谱(DRIFTS)结合离子色谱(IC)、X射线光电子能谱(XPS)研究了常温常压下SO2与O3在黑碳颗粒物(以Printex U为代表,简称UBC)表面的非均相反应.研究发现,在O3和水气存在的情况下,体系的反应产物主要是SO2-4,反应在一定时间内持续进行.UBC可提供反应活性位点,促进SO2在其表面的臭氧氧化.O3是关键的氧化剂,能显著提高SO2非均相氧化生成SO2-4的速率.水气的存在有利于表面活性位点再生,使反应持续发生.当SO2和O3的浓度为1014~1015molecule/cm3、相对湿度为40%时,SO2在UBC(1:400,以NaCl为稀释剂稀释400倍)表面非均相反应生成SO2-4的稳态摄取系数(γBET)为1~6×1O-6,SO2-4的生成速率为1014~1015 ion·s-1·g-1.%Black carbon(BC) produced by incomplete combustion processes is an important aerosol species. The heterogeneous reactions of gaseous pollutants (such as S02, 03 and N0x) on the surface of BC particles are of significance because these reactions can change the particles' morphology, chemical composition, hygro-scopicity and optical properties, and thus alter their climate or health effect, as well as these reactions can influence environmental chemical cycling. In this study, the heterogeneous oxidation of SO2 by O3 on the surface of black carbon (using Printex U as the model particles, denoted as UBC) was investigated by the method of Diffuse Reflectance Infrared Fourier Transform Spectroscopy ( DRIFTS) . The surface product was monitored, and confirmed by Ion Chromatographic(IC) and X-ray photoelectron spectroscopy (XPS) techniques. It was found that the main product of SO2 heterogeneous reaction on the surface of UBC or diluted UBC [ with one part of UBC diluted in 399 parts of infrared transparent NaCl powder, denoted as UBC (1 :400) ] was sulfate and the oxidation reaction rate could be greatly enhanced by O3. The simultaneous presence of ozone and water vapor are necessary for the

  17. Discussion on Application of Modified Nano-particle Black Carbon for the Remediation of Soil Heavy Metals Pollution%改性纳米黑碳应用于钝化修复重金属污染土壤中的问题探讨

    Institute of Scientific and Technical Information of China (English)

    成杰民

    2011-01-01

    通过有关文献资料调研,综述纳米黑碳在钝化修复污染土壤中的应用,分析其应用于钝化修复重金属污染土壤时尚待弄清的几个问题.结果表明:(1)由于纳米黑碳是疏水的非极性吸附剂,选择纳米黑碳作为土壤重金属钝化修复剂时,需对其进行氧化改性,以进一步提高其钝化能力.目前常用的氧化剂为氧化性无机酸、酸性高锰酸钾、双氧水、臭氧等,强烈的氧化过程.会破坏纳米黑碳微孔结构.一定程度上降低其吸附量.(2)为了明确其应用的可能性和适用范围.需揭示改性纳米黑碳对土壤中重金属的钝化机理及其影响因素.土壤CEC、pH、重金属离子的性质等可能是影响改性纳米黑碳对土壤中重金属吸附件能的主要因素.(3)充分利用改性纳米黑碳在土壤修复中的有益作用的同时,还需考虑其可能存在的生态环境负面效应,研究其在土壤中的径流迁移、渗漏等,明确其污染地表水和地下水的可能性,研究其生物效应和将吸附钝化后的纳米黑碳从土壤中移除的可能性,明确其潜在的生态环境风险.%In this paper, application of modified nano-particle black carbon for the remediation of soil heavy metals pollution was summarized and several scientific problems needed to be discussed. Firstly, nano-particle black carbon, as a nonpolar and hydrophobic sorbent, needs to be modified with oxidizing agents to improve its absorption characteristic of heavy metals. Oxidizing agents most in use were inorganic oxyacids, KMnO4, H202 or 03. The microporous surface structure of nano-particle black carbon could be damaged in intense oxidation reaction and the adsorption capacity of heavy metals could be decreased. Secondly, absorption mechanism and influence factors should be illuminated to verify the feasibility and scope of application of modified nano-particle black carbon for the remediation of soil heavy metals pollution. The soil pH, CE

  18. Preparation and application of active gangue's carbon black

    Institute of Scientific and Technical Information of China (English)

    ZHANG Xiang-lin; ZHANG Yi-dong

    2007-01-01

    After three-stage pulverization, dry-distillated activation and coupling agent surface modification, the kaolinite-typed gangue of Sichuan Hongni Coal Mine(SHCM) can be manufactured into activated gangue's carbon black. Its surface area is >25 m2/g, and possesses carbon black's carbon framework and structure. It can be used as strengthening agent of high polymer material such as rubber.

  19. Blackbody Radiation and the Carbon Particle

    Directory of Open Access Journals (Sweden)

    Pierre-Marie Robitaille

    2008-07-01

    Full Text Available Since the days of Kirchhoff, blackbody radiation has been considered to be a universal process, independent of the nature and shape of the emitter. Nonetheless, in promoting this concept, Kirchhoff did require, at the minimum, thermal equilibrium with an enclosure. Recently, the author stated (P.-M. Robitaille, IEEE Trans. Plasma Sci., 2003, v.31(6, 1263-1267; P.-M. Robitaille, Progr. in Phys., 2006, v.2, 22-23, that blackbody radiation is not universal and has called for a return to Stewart's law (P.-M. Robitaille, Progr. in Phys., 2008, v.3, 30-35. In this work, a historical analysis of thermal radiation is presented. It is demonstrated that soot, or lampblack, was the standard for blackbody experiments throughout the 1800s. Furthermore, graphite and carbon black continue to play a central role in the construction of blackbody cavities. The advent of universality is reviewed through the writings of Pierre Prevost, Pierre Louis Dulong, Alexis Therese Petit, Jean Baptiste Joseph Fourier, Simeon Denis Poisson, Frederick Herve de la Provostaye, Paul Quentin Desain, Balfour Stewart, Gustav Robert Kirchhoff, and Max Karl Ernst Ludwig Planck. These writings illustrate that blackbody radiation, as experimentally produced in cavities and as discussed theoretically, has remained dependent on thermal equilibrium with at least the smallest carbon particle. Finally, Planck's treatment of Kirchhoff's law is examined in detail and the shortcomings of his derivation are outlined. It is shown once again, that universality does not exist. Only Stewart's law of thermal emission, not Kirchhoff's, is fully valid.

  20. Long-term airborne black carbon measurements on a Lufthansa passenger aircraft

    Science.gov (United States)

    Ditas, Jeannine; Su, Hang; Scharffe, Dieter; Wang, Siwen; Zhang, Yuxuan; Brenninkmeijer, Carl; Pöschl, Ulrich; Cheng, Yafang

    2016-04-01

    Aerosol particles containing black carbon are the most absorbing component of incoming solar radiation and exert a significant positive radiative forcing thus forming next to CO² the strongest component of current global warming (Bond, 2013). Nevertheless, the role of black carbon particles and especially their complex interaction with clouds needs further research which is hampered by the limited experimental data, especially observations in the free and upper troposphere, and in the UTLS (upper troposphere and lower stratosphere). Many models underestimate the global atmospheric absorption attributable to black carbon by a factor of almost 3 (Bond, 2013). In August 2014, a single particle soot photometer was included in the extensive scientific payload of the CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) project. CARIBIC is in operation since 1997 (with an interruption for 2002-2005) and carries out systematic observations at 10-12 km altitude. For this a special air freight container combining different instruments is transported on a monthly basis using a Lufthansa Airbus A340-600 passenger aircraft with destinations from 120°W to 120°E and 10°N to 75°N. The container has equipment for trace gas analyses and sampling and aerosol analyses and sampling and is connected to an inlet system that is part of the aircraft which contains a camera and DOAS remote sensing system. The integration of a single particle soot photometer (SP2) offers the possibility for the first long-term measurement of global distribution of black carbon and so far flights up to November 2015 have been conducted with more than 400 flight hours. So far the SP2 measurements have been analysed for flights over four continents from Munich to San Francisco, Sao Paulo, Tokyo, Beijing, Cape Town, Los Angeles and Hong Kong). The first measurements show promising results of black carbon measurements. Background concentrations in the UTLS

  1. Evaporation of nonzero rest mass particles from a black hole

    International Nuclear Information System (INIS)

    Analytic expressions for the transmission coefficient and the emission and the absorption rates for scalar particles with mass and a chargeless, nonrotating black hole are calculated by using Jacobian elliptic functions and integrals in the Jeffreys--Wentzel--Kramers--Brillouin (JWKB) approximation

  2. Tunneling of Dirac Particles from Kaluza-Klein Black Hole

    Institute of Scientific and Technical Information of China (English)

    ZENG Xiao-Xiong; LI Qiang

    2009-01-01

    Applying the fermions tunneling method, proposed by Kerner and Mann recently, we discuss the tunneling characteristics of Dirac particles from the stationary Kaluza-Klein black hole. To choose Gamma matrix conveniently and avoid the ergosphere dragging effect, we perform it in the dragging coordinate frame. The result shows that Hawking temperature in this case also can be reproduced by the general Dirac equation.

  3. Effects of carbon blacks with various structures on vulcanization and reinforcement of filled ethylene-propylene-diene rubber

    Directory of Open Access Journals (Sweden)

    2008-10-01

    Full Text Available The effects of carbon blacks on vulcanization and mechanical properties of filled ethylene-propylene-diene rubber (EPDM are investigated, by comparing with five types of rubber-grade carbon blacks. Curing kinetics is studied by rheometer and the results indicate that the curing characteristics are influenced by combination of surface area of carbon black and sulphur content on the filler surface, because the former one enhances the physical cross-linking and the latter one introduces the additional chemical cross-linking. Both the degree of cross-linking and cure rate increase with increasing surface area and sulphur content, whereas the optimum cure time and scorch time decrease. The reinforcing nature of the carbon black is assessed from mechanical measurements. It is suggested that the surface area of carbon blacks strongly affects the physical properties of EPDM/carbon black composites. Conductive carbon black (N472 can be used as desirable reinforcing filler due to the higher degree of cross-linking of EPDM with N472 than other EPDM/carbon black composites. The morphology and distribution of particles are studied by using scanning electron microscope. The sound reinforcing ability of N472 is also supported by scanning electron microscope due to the notable dispersibility of N472 within EPDM matrix. N472 ensures the EPDM/N472 composite the most conductive sample among the five composites.

  4. Spinning particles moving around black holes: integrability and chaos

    CERN Document Server

    Lukes-Gerakopoulos, Georgios

    2016-01-01

    The motion of a stellar compact object around a supermassive black hole can be approximated by the motion of a spinning test particle. The equations of motion describing such systems are in general non-integrable, and therefore, chaotic motion should be expected. This article discusses the integrability issue of the spinning particle for the cases of Schwarzschild and Kerr spacetime, and then it focuses on a canonical Hamiltonian formalism where the spin of the particle is included only up to the linear order.

  5. Scattering of scalar particles by a black hole

    CERN Document Server

    Kuchiev, M Yu

    2003-01-01

    The absorption cross section for scalar particle impact on a Schwarzschild black hole is found. The process is dominated by two physical phenomena. One of them is the well-known greybody factor that arises from the energy-dependent potential barrier outside the horizon that filters the incoming and outgoing waves. The other is related to the reflection of particles on the horizon (Kuchiev 2003). This latter effect strongly diminishes the cross section for low energies, forcing it to vanish in the infrared limit. It is argued that this is a general property, the absorption cross section vanishes in the infrared limit for scattering of particles of arbitrary spin.

  6. Universality in Chaos of Particle Motion near Black Hole Horizon

    CERN Document Server

    Hashimoto, Koji

    2016-01-01

    Motion of a particle near a horizon of a spherically symmetric black hole is shown to possess a universal Lyapunov exponent of a chaos provided by its surface gravity. To probe the horizon, we introduce electromagnetic or scalar force to the particle so that it does not fall into the horizon. There appears an unstable maximum of the total potential where the evaluated maximal Lyapunov exponent is found to be independent of the external forces and the particle mass. The Lyapunov exponent is universally given by the surface gravity of the black hole. Unless there are other sources of a chaos, the Lyapunov exponent is subject to an inequality $\\lambda \\leq 2\\pi T_{\\rm BH}/\\hbar$, which is identical to the bound recently discovered by Maldacena, Shenker and Stanford.

  7. Quantification of black carbon mixing state from traffic: implications for aerosol optical properties

    Science.gov (United States)

    Willis, Megan D.; Healy, Robert M.; Riemer, Nicole; West, Matthew; Wang, Jon M.; Jeong, Cheol-Heon; Wenger, John C.; Evans, Greg J.; Abbatt, Jonathan P. D.; Lee, Alex K. Y.

    2016-04-01

    The climatic impacts of black carbon (BC) aerosol, an important absorber of solar radiation in the atmosphere, remain poorly constrained and are intimately related to its particle-scale physical and chemical properties. Using particle-resolved modelling informed by quantitative measurements from a soot-particle aerosol mass spectrometer, we confirm that the mixing state (the distribution of co-emitted aerosol amongst fresh BC-containing particles) at the time of emission significantly affects BC-aerosol optical properties even after a day of atmospheric processing. Both single particle and ensemble aerosol mass spectrometry observations indicate that BC near the point of emission co-exists with hydrocarbon-like organic aerosol (HOA) in two distinct particle types: HOA-rich and BC-rich particles. The average mass fraction of black carbon in HOA-rich and BC-rich particle classes was chemical nature of BC-containing particles and is used to drive a particle-resolved aerosol box model. Significant differences in calculated single scattering albedo (an increase of 0.1) arise from accurate treatment of initial particle mixing state as compared to the assumption of uniform aerosol composition at the point of BC injection into the atmosphere.

  8. Nanohybrid TiO2/carbon black sensor for NO2 gas

    Institute of Scientific and Technical Information of China (English)

    Wei-Jen Liou; Hong-Ming Lin

    2007-01-01

    A nanohybrid sensor of nanosized TiO2-coated carbon black particles, prepared by sol-gel technology for the detection of NO2 gas, has been developed. The response of the electric resistance of the hybrid sensor to NO2 concentration is investigated, showing that the sensitivity of the hybrid sensor is raised as certain ratio of the TiO2 content in the sensor. Easy and cheap to fabricate, the hybrid TiO2/carbon black promises to be a practical sensor for detecting NO2 gas.

  9. Effect of Thermal Aging on the Viscosity of Suspensions of Carbon Black in Polybutadiene

    Science.gov (United States)

    von Meerwall, E.; Hong, M. P.; Kelley, F. N.

    1998-05-01

    We have studied the effects of aging time and temperature on the viscosity of an hydroxyl-terminated polybutadiene (HTPB) containing suspended carbon black. After surface application such HTPB suspensions are crosslinked to form liners in solid rocket motors. The suspension viscosity decreases with aging time, more rapidly at higher temperatures, and approaches a lower asymptote which depends on filler fraction. Heat-drying the carbon black before incorporation lessens the magnitude of this effect and accelerates the approach to equilibrium; moistening the black enlarges it and delays the approach. We conclude that this effect is related to the moisture adsorbed on the black particles. The water is not completely soluble in the polymer, resulting in reversible emulsification, and is driven off during aging. A variety of secondary experiments performed (use of a wetting agent, centrifugation, dc electrical resistivity, NMR spin-spin relaxation and self-diffusion, optical microscopy) eliminate several other likely explanations.

  10. A particle-like description of Planckian black holes

    CERN Document Server

    Spallucci, Euro

    2016-01-01

    In this paper we abandon the idea that even a "quantum" black hole, of Planck size, can still be described as a classical, more or less complicated, geometry. Rather, we consider a genuine quantum mechanical approach where a Planckian black hole is, by all means, just another "particle", even if with a distinguishing property: its linear size increases with the energy. The horizon dynamics is equivalently described in terms of a particle moving in gravitational potential derived from the horizon equation itself in a self-consistent manner. The particle turning-points match the radius of the inner and outer horizons of a charged black hole. This classical model pave the way towards the wave equation for a truly quantum black hole. We compute the exact form of the wave function and determine the energy spectrum. Finally, we describe the classical limit in which the quantum picture correctly approaches the classical geometric formulation. We find that the quantum-to-classical transition occurs far above the Plan...

  11. Estimates of increased black carbon emissions from electrostatic precipitators during powdered activated carbon injection for mercury emissions control.

    Science.gov (United States)

    Clack, Herek L

    2012-07-01

    The behavior of mercury sorbents within electrostatic precipitators (ESPs) is not well-understood, despite a decade or more of full-scale testing. Recent laboratory results suggest that powdered activated carbon exhibits somewhat different collection behavior than fly ash in an ESP and particulate filters located at the outlet of ESPs have shown evidence of powdered activated carbon penetration during full-scale tests of sorbent injection for mercury emissions control. The present analysis considers a range of assumed differential ESP collection efficiencies for powdered activated carbon as compared to fly ash. Estimated emission rates of submicrometer powdered activated carbon are compared to estimated emission rates of particulate carbon on submicrometer fly ash, each corresponding to its respective collection efficiency. To the extent that any emitted powdered activated carbon exhibits size and optical characteristics similar to black carbon, such emissions could effectively constitute an increase in black carbon emissions from coal-based stationary power generation. The results reveal that even for the low injection rates associated with chemically impregnated carbons, submicrometer particulate carbon emissions can easily double if the submicrometer fraction of the native fly ash has a low carbon content. Increasing sorbent injection rates, larger collection efficiency differentials as compared to fly ash, and decreasing sorbent particle size all lead to increases in the estimated submicrometer particulate carbon emissions.

  12. Dirac particles tunneling from black holes with topological defects

    CERN Document Server

    Jusufi, Kimet

    2015-01-01

    We study Hawking radiation of Dirac particles with spin-$1/2$ as a tunneling process from Schwarzschild-de Sitter and Reissner-Nordstr\\"{o}m-de Sitter black holes in background spacetimes with a spinning cosmic string and a global monopole. Solving Dirac's equation by employing the Hamilton-Jacobi method and WKB approximation we find the corresponding tunneling probabilities and the Hawking temperature. Furthermore, we show that the Hawking temperature of black holes remains unchanged in presence of topological defects in both cases.

  13. Dirac particles tunneling from black holes with topological defects

    Science.gov (United States)

    Jusufi, Kimet

    2016-08-01

    We study Hawking radiation of Dirac particles with spin-1 / 2 as a tunneling process from Schwarzschild-de Sitter and Reissner-Nordström-de Sitter black holes in background spacetimes with a spinning cosmic string and a global monopole. Solving Dirac's equation by employing the Hamilton-Jacobi method and WKB approximation we find the corresponding tunneling probabilities and the Hawking temperature. Furthermore, we show that the Hawking temperature of those black holes remains unchanged in presence of topological defects in both cases.

  14. Carbon-rich particles in Comet Halley

    International Nuclear Information System (INIS)

    The majority of particles detected in the coma of Comet Halley contain carbon atoms; many of these grains appear to consist preponderately or only of light elements. These light-element particles may be composed of organic compounds. Of the possible combinations of the elements hydrogen, carbon, nitrogen, and oxygen, numerous examples are found of particles containing the combinations (H,C,O,N), (H,C,N), (H,C,O), and (H,C). These results may bear on the recent detection of polyoxymethylene fragments, the observation of cyanojets (CN patterns consistent with release from solid particles), the possible presence of cyanopolyacetylenes or HCN polymer and the make-up of the CHON particles. If cometary matter could reach the surface of the earth without complete disruption, these diverse organic and mixed particles could create unique microenvironments, possibly with significant or even pivotal prebiotic chemical activity. Here a speculative insight into possible relationships between carbon in comets and carbon in life is given, as well as a brief overview of on-going analysis of data from the highly successful Particle Impact Analyzer (PIA) experiment flown on the Giotto spacecraft for the flyby of Comet Halley (development and implementation of PIA was under the direction of J. Kissel of the Max Planck Institute for Kernphysik, Heidelberg). PIA is a time-of-flight analyzer which obtains mass spectra of ions from individual particles impacting on a Pt-Ag foil target within the instrument

  15. A New Grade Carbon Black Produced by Thermal Plasma Process

    Institute of Scientific and Technical Information of China (English)

    李娟; 何方方; 罗义文; 印永祥; 戴晓雁; 廖旭

    2003-01-01

    This paper presents a new route about producing carbon black, by which the naturalgas cracking is carried out in the absence of oxygen thanks to an electric energy supply externallygiven by a plasma jet. The carbon black produced by this process has a narrow size distributionand a small average diameter of 38 nm as well as a highly branched aggregate. The higher DBPvalue of 1.40 ml/g shows it should be a high structure carbon black. The FTIR spectra shows thatthere are lots of aromatic c-c bonds and a large amount of nitrogen-containing functional groupson the carbon blacks surface, such as -NH, -CN as well as -CH, -OH, -COOH groups.

  16. Thickness effect on electric resistivity on polystyrene and carbon black- based composites

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez-Lopez, S; Vigueras-Santiago, E [Laboratorio de Investigacion y Desarrollo de Materiales Avanzados (LIDMA) Facultad de Quimica, Paseo Colon Esquina con Paseo Tollocan, s/n, CP 50000, Toluca (Mexico); Mayorga-Rojas, M; Reyes-Contreras, D, E-mail: eviguerass@uaemex.m [Facultad de Ciencias, Universidad Autonoma del Estado de Mexico. Av. Instituto Literario 100 Ote. C. P. 50000, Toluca (Mexico)

    2009-05-01

    Changes on electrical resistivity were experimentally studied for polystyrene and carbon black-based composites respect to the temperature. 22% w/w carbon black composite films at 30{mu}m, 2mm y 1cm thick were submitted to thermal heating-cooling cycles from room temperature to 100 deg. C, slightly up to T{sub g} of the composite. For each cycle changes on electrical resistivity constituent a hysteresis loop that depends on the sample thickness. The changes during the heating stage could be explained as a consequence of the thermal expansion and mobility of the polymer chains at T{sub g}, producing a disconnecting of the electrical contacts among carbon black particles and an important increasing (200%) of the electrical resistivity. For each cycle, the hysteresis loop was observed in thicker samples, whereas for 30 mu m thickness sample the hysteresis loop was lost after four cycles.

  17. Electric anisotropy in high density polyethylene + carbon black composites induced by mechanical deformation

    Energy Technology Data Exchange (ETDEWEB)

    Vigueras-Santiago, E; Hernandez-Lopez, S; Camacho-Lopez, M A; Lara-Sanjuan, O, E-mail: eviguerass@uaemex.m [Laboratorio de Investigacion y Desarrollo de Materiales Avanzados (LIDMA), Facultad de Quimica, UAEM. Paseo Colon esq. con Paseo Tollocan, s/n. C.P. 50000, Toluca (Mexico)

    2009-05-01

    High density polyethylene + carbon black composites with electrical anisotropy was studied. Electrical anisotropy was induced by uniaxial mechanical deformation and injection moulding. We show that anisotropy depends on the carbon black concentration and percentage deformation. Resistivity had the highest anisotropy resistivity around the percolation threshold. Perpendicular resistivity showed two magnitude orders higher than parallel resistivity for injected samples, whereas resistivity showed an inverse behaviour for 100% tensile samples. Both directions were set respect to the deformation axe. Anisotropy could be explained in terms of the molecular deformation (alignment) of the polymer chains as a response of the deformation process originating a redistribution of the carbon black particles in both directions. Alignment of the polymer chains was evidenced by polarized Raman spectroscopy.

  18. Carbon black nanoparticles induce type II epithelial cells to release chemotaxins for alveolar macrophages

    Directory of Open Access Journals (Sweden)

    Donaldson Ken

    2005-12-01

    Full Text Available Abstract Background Alveolar macrophages are a key cell in dealing with particles deposited in the lungs and in determining the subsequent response to that particle exposure. Nanoparticles are considered a potential threat to the lungs and the mechanism of pulmonary response to nanoparticles is currently under intense scrutiny. The type II alveolar epithelial cell has previously been shown to release chemoattractants which can recruit alveolar macrophages to sites of particle deposition. The aim of this study was to assess the responses of a type II epithelial cell line (L-2 to both fine and nanoparticle exposure in terms of secretion of chemotactic substances capable of inducing macrophage migration. Results Exposure of type II cells to carbon black nanoparticles resulted in significant release of macrophage chemoattractant compared to the negative control and to other dusts tested (fine carbon black and TiO2 and nanoparticle TiO2 as measured by macrophage migration towards type II cell conditioned medium. SDS-PAGE analysis of the conditioned medium from particle treated type II cells revealed that a higher number of protein bands were present in the conditioned medium obtained from type II cells treated with nanoparticle carbon black compared to other dusts tested. Size-fractionation of the chemotaxin-rich supernatant determined that the chemoattractants released from the epithelial cells were between 5 and 30 kDa in size. Conclusion The highly toxic nature and reactive surface chemistry of the carbon black nanoparticles has very likely induced the type II cell line to release pro-inflammatory mediators that can potentially induce migration of macrophages. This could aid in the rapid recruitment of inflammatory cells to sites of particle deposition and the subsequent removal of the particles by phagocytic cells such as macrophages and neutrophils. Future studies in this area could focus on the exact identity of the substance(s released by the

  19. Protective effects of pulmonary epithelial lining fluid on oxidative stress and DNA single-strand breaks caused by ultrafine carbon black, ferrous sulphate and organic extract of diesel exhaust particles

    International Nuclear Information System (INIS)

    Pulmonary epithelial lining fluid (ELF) is the first substance to make contact with inhaled particulate matter (PM) and interacts chemically with PM components. The objective of this study was to determine the role of ELF in oxidative stress, DNA damage and the production of proinflammatory cytokines following physicochemical exposure to PM. Ultrafine carbon black (ufCB, 15 nm; a model carbonaceous core), ferrous sulphate (FeSO4; a model transition metal) and a diesel exhaust particle (DEP) extract (a model organic compound) were used to examine the acellular oxidative potential of synthetic ELF and non-ELF systems. We compared the effects of exposure to ufCB, FeSO4 and DEP extract on human alveolar epithelial Type II (A549) cells to determine the levels of oxidative stress, DNA single-strand breaks and interleukin-8 (IL-8) production in ELF and non-ELF systems. The effects of ufCB and FeSO4 on the acellular oxidative potential, cellular oxidative stress and DNA single-strand breakage were mitigated significantly by the addition of ELF, whereas there was no decrease following treatment with the DEP extract. There was no significant effect on IL-8 production following exposure to samples that were suspended in ELF/non-ELF systems. The results of the present study indicate that ELF plays an important role in the initial defence against PM in the pulmonary environment. Experimental components, such as ufCB and FeSO4, induced the production of oxidative stress and led to DNA single-strand breaks, which were moderately prevented by the addition of ELF. These findings suggest that ELF plays a protective role against PM-driven oxidative stress and DNA damage. -- Highlights: ► To determine the role of ELF in ROS, DNA damage and IL-8 after exposure to PM. ► ufCB, FeSO4 and DEP extract were used to examine the protective effects of ELF. ► PM-driven oxidative stress and DNA single-strand breakage were mitigated by ELF. ► The findings suggest that ELF has a protective

  20. Protective effects of pulmonary epithelial lining fluid on oxidative stress and DNA single-strand breaks caused by ultrafine carbon black, ferrous sulphate and organic extract of diesel exhaust particles

    Energy Technology Data Exchange (ETDEWEB)

    Chuang, Hsiao-Chi [School of Respiratory Therapy, College of Medicine, Taipei Medical University, Taipei, Taiwan (China); Division of Pulmonary Medicine, Department of Internal Medicine, Shuang Ho Hospital, Taipei Medical University, Taipei, Taiwan (China); Cheng, Yi-Ling; Lei, Yu-Chen [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, Taipei, Taiwan (China); Chang, Hui-Hsien [Institute of Environmental Health, College of Public Health, National Taiwan University, Taipei, Taiwan (China); Cheng, Tsun-Jen, E-mail: tcheng@ntu.edu.tw [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, Taipei, Taiwan (China); Department of Public Health, College of Public Health, National Taiwan University, Taipei, Taiwan (China)

    2013-02-01

    Pulmonary epithelial lining fluid (ELF) is the first substance to make contact with inhaled particulate matter (PM) and interacts chemically with PM components. The objective of this study was to determine the role of ELF in oxidative stress, DNA damage and the production of proinflammatory cytokines following physicochemical exposure to PM. Ultrafine carbon black (ufCB, 15 nm; a model carbonaceous core), ferrous sulphate (FeSO{sub 4}; a model transition metal) and a diesel exhaust particle (DEP) extract (a model organic compound) were used to examine the acellular oxidative potential of synthetic ELF and non-ELF systems. We compared the effects of exposure to ufCB, FeSO{sub 4} and DEP extract on human alveolar epithelial Type II (A549) cells to determine the levels of oxidative stress, DNA single-strand breaks and interleukin-8 (IL-8) production in ELF and non-ELF systems. The effects of ufCB and FeSO{sub 4} on the acellular oxidative potential, cellular oxidative stress and DNA single-strand breakage were mitigated significantly by the addition of ELF, whereas there was no decrease following treatment with the DEP extract. There was no significant effect on IL-8 production following exposure to samples that were suspended in ELF/non-ELF systems. The results of the present study indicate that ELF plays an important role in the initial defence against PM in the pulmonary environment. Experimental components, such as ufCB and FeSO{sub 4}, induced the production of oxidative stress and led to DNA single-strand breaks, which were moderately prevented by the addition of ELF. These findings suggest that ELF plays a protective role against PM-driven oxidative stress and DNA damage. -- Highlights: ► To determine the role of ELF in ROS, DNA damage and IL-8 after exposure to PM. ► ufCB, FeSO{sub 4} and DEP extract were used to examine the protective effects of ELF. ► PM-driven oxidative stress and DNA single-strand breakage were mitigated by ELF. ► The findings

  1. Comparative DEMS study on the electrochemical oxidation of carbon blacks

    DEFF Research Database (Denmark)

    Ashton, Sean James; Arenz, Matthias

    2012-01-01

    heat-treated between 2100 and 3200 °C, such as those typically used as corrosion resistant carbon (CRC) supports for polymer electrolyte membrane fuel cell (PEMFC) catalysts. A methodology combining cyclic voltammetry (CV) and differential electrochemical mass spectrometry (DEMS) is used, which allows...... the characterisation and comparison of the complete electrochemical oxidation rates and behaviours of the various carbon blacks. It is observed that the behaviour of the carbon black towards electrochemical oxidation is highly dynamic, and dependent on the properties of the pristine carbon back, the degree...

  2. Human lung epithelial cell A549 proteome data after treatment with titanium dioxide and carbon black.

    Science.gov (United States)

    Vuong, Ngoc Q; Goegan, Patrick; Mohottalage, Susantha; Breznan, Dalibor; Ariganello, Marianne; Williams, Andrew; Elisma, Fred; Karthikeyan, Subramanian; Vincent, Renaud; Kumarathasan, Premkumari

    2016-09-01

    Here, we have described the dataset relevant to the A549 cellular proteome changes after exposure to either titanium dioxide or carbon black particles as compared to the non-exposed controls, "Proteomic changes in human lung epithelial cells (A549) in response to carbon black and titanium dioxide exposures" (Vuong et al., 2016) [1]. Detailed methodologies on the separation of cellular proteins by 2D-GE and the subsequent mass spectrometry analyses using MALDI-TOF-TOF-MS are documented. Particle exposure-specific protein expression changes were measured via 2D-GE spot volume analysis. Protein identification was done by querying mass spectrometry data against SwissProt and RefSeq protein databases using Mascot search engine. Two-way ANOVA analysis data provided information on statistically significant A549 protein expression changes associated with particle exposures.

  3. Human lung epithelial cell A549 proteome data after treatment with titanium dioxide and carbon black.

    Science.gov (United States)

    Vuong, Ngoc Q; Goegan, Patrick; Mohottalage, Susantha; Breznan, Dalibor; Ariganello, Marianne; Williams, Andrew; Elisma, Fred; Karthikeyan, Subramanian; Vincent, Renaud; Kumarathasan, Premkumari

    2016-09-01

    Here, we have described the dataset relevant to the A549 cellular proteome changes after exposure to either titanium dioxide or carbon black particles as compared to the non-exposed controls, "Proteomic changes in human lung epithelial cells (A549) in response to carbon black and titanium dioxide exposures" (Vuong et al., 2016) [1]. Detailed methodologies on the separation of cellular proteins by 2D-GE and the subsequent mass spectrometry analyses using MALDI-TOF-TOF-MS are documented. Particle exposure-specific protein expression changes were measured via 2D-GE spot volume analysis. Protein identification was done by querying mass spectrometry data against SwissProt and RefSeq protein databases using Mascot search engine. Two-way ANOVA analysis data provided information on statistically significant A549 protein expression changes associated with particle exposures. PMID:27508218

  4. Human lung epithelial cell A549 proteome data after treatment with titanium dioxide and carbon black

    Directory of Open Access Journals (Sweden)

    Ngoc Q. Vuong

    2016-09-01

    Full Text Available Here, we have described the dataset relevant to the A549 cellular proteome changes after exposure to either titanium dioxide or carbon black particles as compared to the non-exposed controls, “Proteomic changes in human lung epithelial cells (A549 in response to carbon black and titanium dioxide exposures” (Vuong et al., 2016 [1]. Detailed methodologies on the separation of cellular proteins by 2D-GE and the subsequent mass spectrometry analyses using MALDI-TOF-TOF-MS are documented. Particle exposure-specific protein expression changes were measured via 2D-GE spot volume analysis. Protein identification was done by querying mass spectrometry data against SwissProt and RefSeq protein databases using Mascot search engine. Two-way ANOVA analysis data provided information on statistically significant A549 protein expression changes associated with particle exposures.

  5. Atmospheric black carbon and sulfate concentrations in Northeast Greenland

    Directory of Open Access Journals (Sweden)

    A. Massling

    2015-04-01

    Full Text Available Measurements of Black Carbon (BC in aerosols at the high Arctic field site Villum Research Station (VRS at Station Nord in North Greenland showed a seasonal variation in BC concentrations with a maximum in winter and spring at ground level. The data was obtained using a Multi Angle Absorption Photometer (MAAP. A similar seasonal pattern was found for sulfate concentrations with a maximum level during winter and spring analyzed by ion chromatography. A correlation between BC and sulfate concentrations was observed over the years 2011 to 2013. This finding gives the hint that most likely transport of primary emitted BC particles to the Arctic was accompanied by aging of the aerosols through condensational processes. This process may have led to the formation of secondary inorganic matter and further transport of BC particles as cloud processing and further washout of particles is less likely based on the typically observed transport patterns of air masses arriving at VRS. Additionally, concentrations of EC (elemental carbon based on a thermo-optical method were determined and compared to BC measurements. Model estimates of the climate forcing due to BC in the Arctic are based on contributions of long-range transported BC during spring and summer. The measured concentrations were here compared with model results obtained by the Danish Hemispheric Model, DEHM. Good agreement between measured and modeled concentrations of both BC and sulfate was observed. The dominant source is found to be combustion of fossil fuel with biomass burning as a minor though significant source. During winter and spring the Arctic atmosphere is known to be impacted by long-range transport of BC and associated with the Arctic haze phenomenon.

  6. New mechanism of acceleration of particles by stellar black holes

    CERN Document Server

    Osmanov, Z

    2016-01-01

    In this paper we study efficiency of particle acceleration in the magnetospheres of stellar mass black holes. For this purpose we consider the linearized set of the Euler equation, continuity equation and Poisson equation respectively. After introducing the varying relativistic centrifugal force, we show that the charge separation undergoes the parametric instability, leading to generation of centrifugally excited Langmuir waves. It is shown that these waves, via the Langmuir collapse damp by means of the Landau damping, as a result energy transfers to particles accelerating them to energies of the order of $10^{16}$eV.

  7. Dirac Particles' Hawking Radiation from a Schwarzschild Black Hole

    Institute of Scientific and Technical Information of China (English)

    HE Xiao-Kai; LIU Wen-Biao

    2007-01-01

    @@ Considering energy conservation and the backreaction of particles to spacetime, we investigate the massless/massive Dirac particles' Hawking radiation from a Schwarzschild black hole. The exact expression of the emission rate near the horizon is obtained and the result indicates that Hawking radiation spectrum is not purely thermal. The result obtained is consistent with the results obtained before. It satisfies the underlying unitary theory and offers a possible mechanism to explain the information loss paradox. Whereas the improved Damour-Ruffini method is more concise and understandable.

  8. Black carbon mixing state impacts on cloud microphysical properties: effects of aerosol plume and environmental conditions

    Energy Technology Data Exchange (ETDEWEB)

    Ching, Ping Pui; Riemer, Nicole; West, Matthew

    2016-05-27

    Black carbon (BC) is usually mixed with other aerosol species within individual aerosol particles. This mixture, along with the particles' size and morphology, determines the particles' optical and cloud condensation nuclei properties, and hence black carbon's climate impacts. In this study the particle-resolved aerosol model PartMC-MOSAIC was used to quantify the importance of black carbon mixing state for predicting cloud microphysical quantities. Based on a set of about 100 cloud parcel simulations a process level analysis framework was developed to attribute the response in cloud microphysical properties to changes in the underlying aerosol population ("plume effect") and the cloud parcel cooling rate ("parcel effect"). It shows that the response of cloud droplet number concentration to changes in BC emissions depends on the BC mixing state. When the aerosol population contains mainly aged BC particles an increase in BC emission results in increasing cloud droplet number concentrations ("additive effect"). In contrast, when the aerosol population contains mainly fresh BC particles they act as sinks for condensable gaseous species, resulting in a decrease in cloud droplet number concentration as BC emissions are increased ("competition effect"). Additionally, we quantified the error in cloud microphysical quantities when neglecting the information on BC mixing state, which is often done in aerosol models. The errors ranged from -12% to +45% for the cloud droplet number fraction, from 0% to +1022% for the nucleation-scavenged black carbon (BC) mass fraction, from -12% to +4% for the effective radius, and from -30% to +60% for the relative dispersion.

  9. An Important Supplement to NAA in Study on Atmosphere Pollution:Determination of Black Carbon

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>Light absorption in the atmosphere is dominated by elemental carbon (EC), sometimes called black carbon (BC). Black carbon is an important indication of man-made pollution in airborne particulate matter

  10. Hygroscopicity of Black-Carbon-Containing Aerosol in Wildfire Plumes

    Science.gov (United States)

    Perring, A. E.; Schwarz, J. P.; Markovic, M. Z.; Fahey, D. W.; Yokelson, R. J.; Jimenez, J. L.; Campuzano Jost, P.; Day, D. A.; Palm, B. B.; Wisthaler, A.; Ziemba, L. D.; Anderson, B. E.; Diskin, G. S.; Huey, L. G.; Gao, R. S.

    2015-12-01

    Water uptake by black carbon (BC) containing aerosol has been quantified in wildfire plumes of varying age (from 1 to ~40 hr old) sampled in North America during the NASA SEAC4RS mission of 2013. Measurements were made in flight using parallel single-particle soot photometers (SP2) that simultaneously detected the BC component of the ambient aerosol ensemble under contrasting humidity conditions. The hygroscopicity parameter, κ, of material internally mixed with BC derived from this data set is consistent with previous estimates of bulk aerosol hygroscopicity from biomass burning sources. We explore the temporal evolution of κ during aging of the Yosemite Rim Fire plume to constrain the rate of conversion of BC-containing aerosol from hydrophobic to hydrophilic modes in these emissions. We also investigate the relationship between κ values for BC-containing particles and the oxidation state and hygroscopicity of the bulk aerosol. These observations have implications for BC transport and removal in biomass burning plumes and provide important constraints on model treatment of BC optical and microphysical properties from wildfire sources in ambient conditions.

  11. Thermal Oxidation of Tail Gases from the Production of Oil-furnace Carbon Black

    OpenAIRE

    Bosak, Z.; Barta, D; Zečević, N.; Šiklušić, S.

    2009-01-01

    This paper describes the production technology of oil-furnace carbon black, as well as the selected solution for preventing the emissions of this process from contaminating the environment.The products of industrial oil-furnace carbon black production are different grades of carbon black and process tail gases. The qualitative composition of these tail gases during the production of oil-furnace carbon black are: carbon(IV) oxide, carbon(II) oxide, hydrogen, methane, hydrogen sulfide, nitrogen...

  12. Are the Hawking particles produced by the black-hole evaporation Higgs particles

    International Nuclear Information System (INIS)

    In the frame-work of the thermo field dynamics approach to the black hole evaporation of W. Israel, utilizing few elementary notions of the Catastrophe theory, it is suggested that the Hawking quanta are Higgs particles of an underlying mechanism of spontaneous symmetry breakdown. (author)

  13. Increased fire frequency optimization of black carbon mixing and storage

    Science.gov (United States)

    Pyle, Lacey; Masiello, Caroline; Clark, Kenneth

    2016-04-01

    Soil carbon makes up a substantial part of the global carbon budget and black carbon (BC - produced from incomplete combustion of biomass) can be significant fraction of soil carbon. Soil BC cycling is still poorly understood - very old BC is observed in soils, suggesting recalcitrance, yet in short term lab and field studies BC sometimes breaks down rapidly. Climate change is predicted to increase the frequency of fires, which will increase global production of BC. As up to 80% of BC produced in wildfires can remain at the fire location, increased fire frequency will cause significant perturbations to soil BC accumulation. This creates a challenge in estimating soil BC storage, in light of a changing climate and an increased likelihood of fire. While the chemical properties of BC are relatively well-studied, its physical properties are much less well understood, and may play crucial roles in its landscape residence time. One important property is density. When BC density is less than 1 g/cm3 (i.e. the density of water), it is highly mobile and can easily leave the landscape. This landscape mobility following rainfall may inflate estimates of its degradability, making it crucial to understand both the short- and long term density of BC particles. As BC pores fill with minerals, making particles denser, or become ingrown with root and hyphal anchors, BC is likely to become protected from erosion. Consequently, how quickly BC is mixed deeper into the soil column is likely a primary controller on BC accumulation. Additionally the post-fire recovery of soil litter layers caps BC belowground, protecting it from erosional forces and re-combustion in subsequent fires, but still allowing bioturbation deeper into the soil column. We have taken advantage of a fire chronosequence in the Pine Barrens of New Jersey to investigate how density of BC particles change over time, and how an increase in fire frequency affects soil BC storage and soil column movement. Our plots have

  14. Black Carbon Measurements of Flame-Generated Soot as Determinedby Optical, Thermal-Optical, Direct Absorption,and Laser Incandescence Methods

    Science.gov (United States)

    Black carbon (BC), light absorbing particles emitted primarily from incomplete combustion, is operationally defined through a variety of instrumental measurements rather than with a universal definition set forth by the research or regulatory communities. To examine the consiste...

  15. Black hole lightning due to particle acceleration at subhorizon scales

    CERN Document Server

    Aleksić, J; Antonelli, L A; Antoranz, P; Babic, A; Bangale, P; Barrio, J A; González, J Becerra; Bednarek, W; Bernardini, E; Biasuzzi, B; Biland, A; Blanch, O; Bonnefoy, S; Bonnoli, G; Borracci, F; Bretz, T; Carmona, E; Carosi, A; Colin, P; Colombo, E; Contreras, J L; Cortina, J; Covino, S; Da Vela, P; Dazzi, F; De Angelis, A; De Caneva, G; De Lotto, B; Wilhelmi, E de Oña; Mendez, C Delgado; Prester, D Dominis; Dorner, D; Doro, M; Einecke, S; Eisenacher, D; Elsaesser, D; Fonseca, M V; Font, L; Frantzen, K; Fruck, C; Galindo, D; López, R J García; Garczarczyk, M; Terrats, D Garrido; Gaug, M; Godinović, N; Muñoz, A González; Gozzini, S R; Hadasch, D; Hanabata, Y; Hayashida, M; Herrera, J; Hildebrand, D; Hose, J; Hrupec, D; Idec, W; Kadenius, V; Kellermann, H; Kodani, K; Konno, Y; Krause, J; Kubo, H; Kushida, J; La Barbera, A; Lelas, D; Lewandowska, N; Lindfors, E; Lombardi, S; Longo, F; López, M; López-Coto, R; López-Oramas, A; Lorenz, E; Lozano, I; Makariev, M; Mallot, K; Maneva, G; Mankuzhiyil, N; Mannheim, K; Maraschi, L; Marcote, B; Mariotti, M; Martínez, M; Mazin, D; Menzel, U; Miranda, J M; Mirzoyan, R; Moralejo, A; Munar-Adrover, P; Nakajima, D; Niedzwiecki, A; Nilsson, K; Nishijima, K; Noda, K; Orito, R; Overkemping, A; Paiano, S; Palatiello, M; Paneque, D; Paoletti, R; Paredes, J M; Paredes-Fortuny, X; Persic, M; Poutanen, J; Moroni, P G Prada; Prandini, E; Puljak, I; Reinthal, R; Rhode, W; Ribó, M; Rico, J; Garcia, J Rodriguez; Rügamer, S; Saito, T; Saito, K; Satalecka, K; Scalzotto, V; Scapin, V; Schultz, C; Schweizer, T; Shore, S N; Sillanpää, A; Sitarek, J; Snidaric, I; Sobczynska, D; Spanier, F; Stamatescu, V; Stamerra, A; Steinbring, T; Storz, J; Strzys, M; Takalo, L; Takami, H; Tavecchio, F; Temnikov, P; Terzić, T; Tescaro, D; Teshima, M; Thaele, J; Tibolla, O; Torres, D F; Toyama, T; Treves, A; Uellenbeck, M; Vogler, P; Zanin, R; Kadler, M; Schulz, R; Ros, E; Bach, U; Krauß, F; Wilms, J

    2014-01-01

    Supermassive black holes with masses of millions to billions of solar masses are commonly found in the centers of galaxies. Astronomers seek to image jet formation using radio interferometry, but still suffer from insufficient angular resolution. An alternative method to resolve small structures is to measure the time variability of their emission. Here, we report on gamma-ray observations of the radio galaxy IC 310 obtained with the MAGIC telescopes revealing variability with doubling time scales faster than 4.8 min. Causality constrains the size of the emission region to be smaller than 20\\% of the gravitational radius of its central black hole. We suggest that the emission is associated with pulsar-like particle acceleration by the electric field across a magnetospheric gap at the base of the radio jet.

  16. Protection of porous carbon fuel particles from boudouard corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Cooper, John F.

    2015-05-26

    A system for producing energy that includes infusing porous carbon particles produced by pyrolysis of carbon-containing materials with an off-eutectic salt composition thus producing pore-free carbon particles, and reacting the carbon particles with oxygen in a fuel cell according to the reaction C+O.sub.2=CO.sub.2 to produce electrical energy.

  17. Particle acceleration in the vacuum gaps in black hole magnetospheres

    CERN Document Server

    Ptitsyna, K

    2015-01-01

    We consider particle acceleration in vacuum gaps in magnetospheres of black holes powered through Blandford-Znajek mechanism and embedded into radiatively-inefficient accretion flow (RIAF) environment. In such situation the gap height is limited by the onset of gamma-gamma pair production on the infrared photons originating from the RIAF. We numerically calculate acceleration and propagation of charged particles taking into account the detailed structure of electric and magnetic field in the gap and in the entire black hole magnetosphere, radiative energy losses and interactions of gamma rays produced by the propagated charged particles with the background radiation field of RIAF. We show that the presence of the vacuum gap has clear observational signatures. The spectra of emission from gaps embedded into a relatively high luminosity RIAF are dominated by the inverse Compton emission with a sharp, super-exponential cut-off in the very-high-energy gamma-ray band. The cut-off energy is determined by the proper...

  18. Particle Collisions in the Lower Dimensional Rotating Black Hole Space-Time with the Cosmological Constant

    International Nuclear Information System (INIS)

    We study the effect of ultrahigh energy collisions of two particles with different energies near the horizon of a 2+1 dimensional BTZ black hole (BSW effect). We find that the particle with the critical angular momentum could exist inside the outer horizon of the BTZ black hole regardless of the particle energy. Therefore, for the nonextremal BTZ black hole, the BSW process is possible on the inner horizon with the fine tuning of parameters which are characterized by the motion of particle, while, for the extremal BTZ black hole, the particle with the critical angular momentum could only exist on the degenerated horizon, and the BSW process could also happen there

  19. Association between Traffic-Related Black Carbon Exposure and Lung Function among Urban Women

    OpenAIRE

    Suglia, Shakira Franco; Gryparis, Alexandros; Schwartz, Joel David; Wright, Rosalind Jo

    2008-01-01

    Background: Although a number of studies have documented the relationship between lung function and traffic-related pollution among children, few have focused on adult lung function or examined community-based populations. Objective: We examined the relationship between black carbon (BC), a surrogate of traffic-related particles, and lung function among women in the Maternal–Infant Smoking Study of East Boston, an urban cohort in Boston, Massachusetts. Methods: We estimated local BC levels us...

  20. Contribution of Black Carbon, Brown Carbon and Lensing Effect to Total Aerosol Absorption in Indo-Gangetic Plain

    Science.gov (United States)

    Shamjad, Pm; Tripathi, Sachchida; Bergin, Mike; Vreeland, Heidi

    2016-04-01

    This study reports the optical and physical properties of atmospheric and denuded (heated at 300°C) aerosols from Indo-Gangetic Plain (IGP) during 20 December 2014 to 28 February 2015. A Single Particle Soot Photometer (SP2) and High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) were used to measure black carbon (BC) and organic carbon (OC) in real time respectively. During experiments large scale carbonaceous aerosol loading is observed in IGP. Multiple biomass burning events are observed with varying intensity and duration. Refractive index of brown carbon (BrC) is derived from filter extracts using Liquid Core Wave Capillary Cell (LWCC). Refractive index of BrC at 405 is 4 times higher in IGP when compared to studies conducted in USA. Through Mie modelling we identified the percentage contribution of black carbon, BrC and lensing effect to total aerosol absorption. On average 75% of absorption is from black carbon alone, while rest is contributed from volatile components. Within the volatile component contribution, at 405 nm BrC contributes around 20% and rest from lensing effect. But at 781 nm lensing contributed more than BrC. Overall results indicate the special characteristics on BrC aerosols in IGP and the importance of considering spectral absorption in global aerosol modelling studies.

  1. Adsorption of Remazol Black B dye on Activated Carbon Felt

    OpenAIRE

    Donnaperna Lucio; Duclaux Laurent; Gadiou Roger

    2008-01-01

    The adsorption of Remazol Black B (anionic dye) on a microporous activated carbon felt is investigated from its aqueous solution. The surface chemistry of activated carbon is studied using X-ray microanalysis, "Boehm" titrations and pH of PZC measurements which indicates that the surface oxygenated groups are mainly acidic in nature. The kinetics of Remazol Black B adsorption is observed to be pH dependent and governed by the diffusion of the dye molecules. The experimental data can be explai...

  2. The dynamics of point particles around black holes

    Science.gov (United States)

    Vega, Michael Francis Ian G., II

    A point particle moving in a curved spacetime gives rise to fields that in turn affect its motion. One conveniently thinks of this interplay as the response of the particle to its self-force. To date, models of point particle motion in the vicinity of black holes have ignored parts of this self-force because it is such a challenge to calculate. This work is part of a larger effort to develop systematic tools for the efficient calculation of such self-forces. This development is made with the aim of accurately simulating the inspiraling motion of compact objects onto supermassive black holes (also known as extreme-mass-ratio binary inspirals, or EMRIs), and of obtaining good predictions of the gravitational waves they emit. EMRIs are the main targets for the proposed space-based gravitational wave detector, the Laser Interferometer Space Antenna (LISA). For the mission to succeed, accurate templates of the gravitational waves it will pick up are necessary. This work is an attempt to address this need. The main contribution of this dissertation is the design and testing of a novel method for simultaneously calculating self-forces and radiation fluxes due point particle sources using (3+1) codes. Concrete calculations of self-forces for particles in strong-field gravity have only previously been done through mode sum approaches, which, while having been critical to the development of the subject, appears inconvenient for the eventual goal of using a calculated self-force to update particle trajectories. The new method avoids a mode decomposition entirely, and instead properly replaces the distributional source of the curved spacetime wave equation by an effective regular source. The resulting regular solution of the wave equation, under appropriate boundary conditions, results in the physical retarded field when evaluated in the wavezone, while its gradient at the location of the particle gives the full self-force. This prescription is founded on the possibility of

  3. Black hole physics. Black hole lightning due to particle acceleration at subhorizon scales.

    Science.gov (United States)

    Aleksić, J; Ansoldi, S; Antonelli, L A; Antoranz, P; Babic, A; Bangale, P; Barrio, J A; Becerra González, J; Bednarek, W; Bernardini, E; Biasuzzi, B; Biland, A; Blanch, O; Bonnefoy, S; Bonnoli, G; Borracci, F; Bretz, T; Carmona, E; Carosi, A; Colin, P; Colombo, E; Contreras, J L; Cortina, J; Covino, S; Da Vela, P; Dazzi, F; De Angelis, A; De Caneva, G; De Lotto, B; de Oña Wilhelmi, E; Delgado Mendez, C; Dominis Prester, D; Dorner, D; Doro, M; Einecke, S; Eisenacher, D; Elsaesser, D; Fonseca, M V; Font, L; Frantzen, K; Fruck, C; Galindo, D; García López, R J; Garczarczyk, M; Garrido Terrats, D; Gaug, M; Godinović, N; González Muñoz, A; Gozzini, S R; Hadasch, D; Hanabata, Y; Hayashida, M; Herrera, J; Hildebrand, D; Hose, J; Hrupec, D; Idec, W; Kadenius, V; Kellermann, H; Kodani, K; Konno, Y; Krause, J; Kubo, H; Kushida, J; La Barbera, A; Lelas, D; Lewandowska, N; Lindfors, E; Lombardi, S; Longo, F; López, M; López-Coto, R; López-Oramas, A; Lorenz, E; Lozano, I; Makariev, M; Mallot, K; Maneva, G; Mankuzhiyil, N; Mannheim, K; Maraschi, L; Marcote, B; Mariotti, M; Martínez, M; Mazin, D; Menzel, U; Miranda, J M; Mirzoyan, R; Moralejo, A; Munar-Adrover, P; Nakajima, D; Niedzwiecki, A; Nilsson, K; Nishijima, K; Noda, K; Orito, R; Overkemping, A; Paiano, S; Palatiello, M; Paneque, D; Paoletti, R; Paredes, J M; Paredes-Fortuny, X; Persic, M; Poutanen, J; Prada Moroni, P G; Prandini, E; Puljak, I; Reinthal, R; Rhode, W; Ribó, M; Rico, J; Rodriguez Garcia, J; Rügamer, S; Saito, T; Saito, K; Satalecka, K; Scalzotto, V; Scapin, V; Schultz, C; Schweizer, T; Shore, S N; Sillanpää, A; Sitarek, J; Snidaric, I; Sobczynska, D; Spanier, F; Stamatescu, V; Stamerra, A; Steinbring, T; Storz, J; Strzys, M; Takalo, L; Takami, H; Tavecchio, F; Temnikov, P; Terzić, T; Tescaro, D; Teshima, M; Thaele, J; Tibolla, O; Torres, D F; Toyama, T; Treves, A; Uellenbeck, M; Vogler, P; Zanin, R; Kadler, M; Schulz, R; Ros, E; Bach, U; Krauß, F; Wilms, J

    2014-11-28

    Supermassive black holes with masses of millions to billions of solar masses are commonly found in the centers of galaxies. Astronomers seek to image jet formation using radio interferometry but still suffer from insufficient angular resolution. An alternative method to resolve small structures is to measure the time variability of their emission. Here we report on gamma-ray observations of the radio galaxy IC 310 obtained with the MAGIC (Major Atmospheric Gamma-ray Imaging Cherenkov) telescopes, revealing variability with doubling time scales faster than 4.8 min. Causality constrains the size of the emission region to be smaller than 20% of the gravitational radius of its central black hole. We suggest that the emission is associated with pulsar-like particle acceleration by the electric field across a magnetospheric gap at the base of the radio jet.

  4. Black hole physics. Black hole lightning due to particle acceleration at subhorizon scales.

    Science.gov (United States)

    Aleksić, J; Ansoldi, S; Antonelli, L A; Antoranz, P; Babic, A; Bangale, P; Barrio, J A; Becerra González, J; Bednarek, W; Bernardini, E; Biasuzzi, B; Biland, A; Blanch, O; Bonnefoy, S; Bonnoli, G; Borracci, F; Bretz, T; Carmona, E; Carosi, A; Colin, P; Colombo, E; Contreras, J L; Cortina, J; Covino, S; Da Vela, P; Dazzi, F; De Angelis, A; De Caneva, G; De Lotto, B; de Oña Wilhelmi, E; Delgado Mendez, C; Dominis Prester, D; Dorner, D; Doro, M; Einecke, S; Eisenacher, D; Elsaesser, D; Fonseca, M V; Font, L; Frantzen, K; Fruck, C; Galindo, D; García López, R J; Garczarczyk, M; Garrido Terrats, D; Gaug, M; Godinović, N; González Muñoz, A; Gozzini, S R; Hadasch, D; Hanabata, Y; Hayashida, M; Herrera, J; Hildebrand, D; Hose, J; Hrupec, D; Idec, W; Kadenius, V; Kellermann, H; Kodani, K; Konno, Y; Krause, J; Kubo, H; Kushida, J; La Barbera, A; Lelas, D; Lewandowska, N; Lindfors, E; Lombardi, S; Longo, F; López, M; López-Coto, R; López-Oramas, A; Lorenz, E; Lozano, I; Makariev, M; Mallot, K; Maneva, G; Mankuzhiyil, N; Mannheim, K; Maraschi, L; Marcote, B; Mariotti, M; Martínez, M; Mazin, D; Menzel, U; Miranda, J M; Mirzoyan, R; Moralejo, A; Munar-Adrover, P; Nakajima, D; Niedzwiecki, A; Nilsson, K; Nishijima, K; Noda, K; Orito, R; Overkemping, A; Paiano, S; Palatiello, M; Paneque, D; Paoletti, R; Paredes, J M; Paredes-Fortuny, X; Persic, M; Poutanen, J; Prada Moroni, P G; Prandini, E; Puljak, I; Reinthal, R; Rhode, W; Ribó, M; Rico, J; Rodriguez Garcia, J; Rügamer, S; Saito, T; Saito, K; Satalecka, K; Scalzotto, V; Scapin, V; Schultz, C; Schweizer, T; Shore, S N; Sillanpää, A; Sitarek, J; Snidaric, I; Sobczynska, D; Spanier, F; Stamatescu, V; Stamerra, A; Steinbring, T; Storz, J; Strzys, M; Takalo, L; Takami, H; Tavecchio, F; Temnikov, P; Terzić, T; Tescaro, D; Teshima, M; Thaele, J; Tibolla, O; Torres, D F; Toyama, T; Treves, A; Uellenbeck, M; Vogler, P; Zanin, R; Kadler, M; Schulz, R; Ros, E; Bach, U; Krauß, F; Wilms, J

    2014-11-28

    Supermassive black holes with masses of millions to billions of solar masses are commonly found in the centers of galaxies. Astronomers seek to image jet formation using radio interferometry but still suffer from insufficient angular resolution. An alternative method to resolve small structures is to measure the time variability of their emission. Here we report on gamma-ray observations of the radio galaxy IC 310 obtained with the MAGIC (Major Atmospheric Gamma-ray Imaging Cherenkov) telescopes, revealing variability with doubling time scales faster than 4.8 min. Causality constrains the size of the emission region to be smaller than 20% of the gravitational radius of its central black hole. We suggest that the emission is associated with pulsar-like particle acceleration by the electric field across a magnetospheric gap at the base of the radio jet. PMID:25378461

  5. Atmospheric black carbon and sulfate concentrations in Northeast Greenland

    Science.gov (United States)

    Massling, A.; Nielsen, I. E.; Kristensen, D.; Christensen, J. H.; Sørensen, L. L.; Jensen, B.; Nguyen, Q. T.; Nøjgaard, J. K.; Glasius, M.; Skov, H.

    2015-08-01

    Measurements of equivalent black carbon (EBC) in aerosols at the high Arctic field site Villum Research Station (VRS) at Station Nord in North Greenland showed a seasonal variation in EBC concentrations with a maximum in winter and spring at ground level. Average measured concentrations were about 0.067 ± 0.071 for the winter and 0.011 ± 0.009 for the summer period. These data were obtained using a multi-angle absorption photometer (MAAP). A similar seasonal pattern was found for sulfate concentrations with a maximum level during winter and spring analyzed by ion chromatography. Here, measured average concentrations were about 0.485 ± 0.397 for the winter and 0.112 ± 0.072 for the summer period. A correlation between EBC and sulfate concentrations was observed over the years 2011 to 2013 stating a correlation coefficient of R2 = 0.72. This finding gives the hint that most likely transport of primary emitted BC particles to the Arctic was accompanied by aging of the aerosols through condensational processes. BC and sulfate are known to have only partly similar sources with respect to their transport pathways when reaching the high Arctic. Aging processes may have led to the formation of secondary inorganic matter and further transport of BC particles as cloud processing and further washout of particles is less likely based on the typically observed transport patterns of air masses arriving at VRS. Additionally, concentrations of EC (elemental carbon) based on a thermo-optical method were determined and compared to EBC measurements. EBC measurements were generally higher, but a correlation between EC and EBC resulted in a correlation coefficient of R2 = 0.64. Model estimates of the climate forcing due to BC in the Arctic are based on contributions of long-range transported BC during spring and summer. The measured concentrations were here compared with model results obtained by the Danish Eulerian Hemispheric Model, DEHM. Good agreement between measured and

  6. Aerosol light absorption, black carbon, and elemental carbon at the Fresno Supersite, California

    Science.gov (United States)

    Chow, Judith C.; Watson, John G.; Doraiswamy, Prakash; Chen, Lung-Wen Antony; Sodeman, David A.; Lowenthal, Douglas H.; Park, Kihong; Arnott, W. Patrick; Motallebi, Nehzat

    2009-08-01

    Particle light absorption ( bap), black carbon (BC), and elemental carbon (EC) measurements at the Fresno Supersite during the summer of 2005 were compared to examine the equivalency of current techniques, evaluate filter-based bap correction methods, and determine the EC mass absorption efficiency (σ ap) and the spectral dependence of bap. The photoacoustic analyzer (PA) was used as a benchmark for in-situ bap. Most bap measurement techniques were well correlated ( r ≥ 0.95). Unadjusted Aethalometer (AE) and Particle Soot Absorption Photometer (PSAP) bap were up to seven times higher than PA bap at similar wavelengths because of absorption enhancement by backscattering and multiple scattering. Applying published algorithms to correct for these effects reduced the differences to 24 and 17% for the AE and PSAP, respectively, at 532 nm. The Multi-Angle Absorption Photometer (MAAP), which accounts for backscattering effects, overestimated bap relative to the PA by 51%. BC concentrations determined by the AE, MAAP, and Sunset Laboratory semi-continuous carbon analyzer were also highly correlated ( r ≥ 0.93) but differed by up to 57%. EC measured with the IMPROVE/STN thermal/optical protocols, and the French two-step thermal protocol agreed to within 29%. Absorption efficiencies determined from PA bap and EC measured with different analytical protocols averaged 7.9 ± 1.5, 5.4 ± 1.1, and 2.8 ± 0.6 m 2/g at 532, 670, and 1047 nm, respectively. The Angström exponent (α) determined from adjusted AE and PA bap ranged from 1.19 to 1.46. The largest values of α occurred during the afternoon hours when the organic fraction of total carbon was highest. Significant biases associated with filter-based measurements of bap, BC, and EC are method-specific. Correcting for these biases must take into account differences in aerosol concentration, composition, and sources.

  7. Synthesis of carbon nanofibers on copper particles

    Science.gov (United States)

    Kol'tsova, T. S.; Larionova, T. V.; Shusharina, N. N.; Tolochko, O. V.

    2015-08-01

    We analyze the synthesis of carbon nanostructures from the gas phase (mixture of acetylene or ethylene with hydrogen) on the surface of copper particles without using other catalysts. The synthesized structures (multilayer graphene and carbon nanofibers) are analyzed by transmission electron microscopy and Raman scattering. It is shown that the fiber structure is determined by the C: H ratio in the gas phase. The kinetics of synthesis is analyzed in terms of the formal kinetics of conversion in accordance with the Johnson—Mehl—Avrami equation.

  8. Costs and global impacts of black carbon abatement strategies

    OpenAIRE

    Rypdal, Kristin; Rive, Nathan; Berntsen, Terje K.; Klimont, Zbigniew; Mideksa, Torben K.; Myhre, Gunnar; Skeie, Ragnhild B.

    2011-01-01

    Abatement of particulate matter has traditionally been driven by health concerns rather than its role in global warming. Here we assess future abatement strategies in terms of how much they reduce the climate impact of black carbon (BC) and organic carbon (OC) from contained combustion. We develop global scenarios which take into account regional differences in climate impact, costs of abatement and ability to pay, as well as both the direct and indirect (snow-albedo) climate impact of BC and...

  9. Carbon dioxide gasification of carbon black: isotope study of carbonate catalysis

    International Nuclear Information System (INIS)

    Temperature-programmed reaction was used with labeled isotopes (13C and 18O) to study interactions between carbon black and potassium carbonate in pure He and 10% CO2/90% He atmospheres. Catalytic gasification precursor complexes were observed. Carbon and oxygen-bearing carbon surface groups interacted with the carbonate above 500 K to form surface complexes. Between 500 and 950 K, and in the presence of gaseous CO2, the complexes participated in C and O exchange with the gas phase while oxygen atoms within the complexes also exchanged with those on the carbon surface. As the temperature rose, the complexes decomposed, with CO2 the initial product. Decomposition started around 500 K in pure He, and around 950 K in CO2/He. Catalytic gasification began only after decomposition of significant portions of the complexes. Elemental potassium formed, and the active catalyst appears to alternate between being potassium metal and a potassium-oxygen-carbon complex. Potassium carbonate is not part of the catalytic cycle. 20 references, 10 figures

  10. Molecular simulation of polycyclic aromatic hydrocarbon sorption to black carbon

    NARCIS (Netherlands)

    J.J.H. Haftka; J.R. Parsons; H.A.J. Govers

    2009-01-01

    Strong sorption of hydrophobic organic contaminants to soot or black carbon (BC) is an important environmental process limiting the bioremediation potential of contaminated soils and sediments. Reliable methods to predict BC sorption coefficients for organic contaminants are therefore required. A co

  11. Evaluation of black carbon estimations in global aerosol models

    NARCIS (Netherlands)

    Koch, D.; Schulz, M.; McNaughton, C.; Spackman, J.R.; Balkanski, Y.; Bauer, S.; Krol, M.C.

    2009-01-01

    We evaluate black carbon (BC) model predictions from the AeroCom model intercomparison project by considering the diversity among year 2000 model simulations and comparing model predictions with available measurements. These model-measurement intercomparisons include BC surface and aircraft concentr

  12. Acute exposure of mice to high-dose ultrafine carbon black decreases susceptibility to pneumococcal pneumonia

    Directory of Open Access Journals (Sweden)

    Gordon Stephen

    2010-10-01

    Full Text Available Abstract Background Epidemiological studies suggest that inhalation of carbonaceous particulate matter from biomass combustion increases susceptibility to bacterial pneumonia. In vitro studies report that phagocytosis of carbon black by alveolar macrophages (AM impairs killing of Streptococcus pneumoniae. We have previously reported high levels of black carbon in AM from biomass smoke-exposed children and adults. We therefore aimed to use a mouse model to test the hypothesis that high levels of carbon loading of AM in vivo increases susceptibility to pneumococcal pneumonia. Methods Female outbred mice were treated with either intranasal phosphate buffered saline (PBS or ultrafine carbon black (UF-CB in PBS; 500 μg on day 1 and day 4, and then infected with S. pneumoniae strain D39 on day 5. Survival was assessed over 72 h. The effect of UF-CB on AM carbon loading, airway inflammation, and a urinary marker of pulmonary oxidative stress was assessed in uninfected animals. Results Instillation of UF-CB in mice resulted a pattern of AM carbon loading similar to that of biomass-smoke exposed humans. In uninfected animals, UF-CB treated animals had increased urinary 8-oxodG (P = 0.055, and an increased airway neutrophil differential count (P . pneumoniae, whereas morbidity and mortality after infection was reduced in UF-CB treated animals (median survival 48 h vs. 30 h, P . pneumoniae colony forming unit counts, and lower airway levels of keratinocyte-derived chemokine/growth-related oncogene (KC/GRO, and interferon gamma. Conclusion Acute high level loading of AM with ultrafine carbon black particles per se does not increase the susceptibility of mice to pneumococcal infection in vivo.

  13. 40 CFR 458.10 - Applicability; description of the carbon black furnace process subcategory.

    Science.gov (United States)

    2010-07-01

    ... carbon black furnace process subcategory. 458.10 Section 458.10 Protection of Environment ENVIRONMENTAL... CATEGORY Carbon Black Furnace Process Subcategory § 458.10 Applicability; description of the carbon black furnace process subcategory. The provisions of this subpart are applicable to discharges resulting...

  14. Hawking radiation from Elko particles tunnelling across black-strings horizon

    Science.gov (United States)

    da Rocha, R.; Hoff da Silva, J. M.

    2014-09-01

    We apply the tunnelling method for the emission and absorption of Elko particles in the event horizon of a black-string solution. We show that Elko particles are emitted at the expected Hawking temperature from black strings, but with a quite different signature with respect to the Dirac particles. We employ the Hamilton-Jacobi technique to black-hole tunnelling, by applying the WKB approximation to the coupled system of Dirac-like equations governing the Elko particle dynamics. As a typical signature, different Elko particles are shown to produce the same standard Hawking temperature for black strings. However, we prove that they present the same probability irrespectively of outgoing or ingoing the black-hole horizon. This provides a typical signature for mass-dimension-one fermions, that is different from the mass-dimension-three halves fermions inherent to Dirac particles, as different Dirac spinor fields have distinct inward and outward probability of tunnelling.

  15. Dynamics of Particles Around a Regular Black Hole with Nonlinear Electrodynamics

    CERN Document Server

    Jawad, Abdul; Jamil, Mubasher; Debnath, Ujjal

    2016-01-01

    We investigate the dynamics of a charged particle being kicked off from its circular orbit around a regular black hole by an incoming massive particle in the presence of magnetic field. The resulting escape velocity, escape energy and the effective potential is analyzed. It is shown that the presence of even a very weak magnetic field helps the charged particles in escaping the gravitational field of the black hole. Moreover the effective force acting on the particle visibly reduces with distance. Thus particle near the black hole will experience higher effective force as compared to when it is far away.

  16. Black Carbon Concentration from Worldwide Aerosol Robotic Network (AERONET)

    Science.gov (United States)

    Schuster, Greg; Dubovik, Oleg; Holben, Brent; Clothiaux, Eugene

    2008-01-01

    Worldwide black carbon concentration measurements are needed to assess the efficacy of the carbon emissions inventory and transport model output. This requires long-term measurements in many regions, as model success in one region or season does not apply to all regions and seasons. AERONET is an automated network of more than 180 surface radiometers located throughout the world. The sky radiance measurements obtained by AERONET are inverted to provide column-averaged aerosol refractive indices and size distributions for the AERONET database, which we use to derive column-averaged black carbon concentrations and specific absorptions that are constrained by the measured radiation field. This provides a link between AERONET sky radiance measurements and the elemental carbon concentration of transport models without the need for an optics module in the transport model. Knowledge of both the black carbon concentration and aerosol absorption optical depth (i.e., input and output of the optics module) will enable improvements to the transport model optics module.

  17. Black silicon maskless templates for carbon nanotube forests

    DEFF Research Database (Denmark)

    Wierzbicki, Rafal; Schmidt, Michael Stenbæk; Boisen, Anja;

    2013-01-01

    We present here a proof of concept for a novel fabrication method of vertically aligned carbon nanotube forests, utilizing black silicon nanograss (a forest of silicon nanometer-sized spikes created with reactive ion etching) coated with titanium tungsten diffusion barrier as a template. The method...... allows maskless definition of carbon nanotube forests with control of their density, nanotube diameter and height. Four nanograss reactive ion etching recipes are investigated and their wafer-to-wafer repeatability, wafer uniformity, and density control is discussed. Evaluation of carbon nanotube forests...

  18. Hawking Radiation of Dirac Particles in an Arbitrarily Accelerating Kinnersley Black Hole

    CERN Document Server

    Wu, S Q

    2002-01-01

    Quantum thermal effect of Dirac particles in an arbitrarily accelerating Kinnersley black hole is investigated by using the method of generalized tortoise coordinate transformation. Both the location and the temperature of the event horizon depend on the advanced time and the angles. The Hawking thermal radiation spectrum of Dirac particles contains a new term which represents the interaction between particles with spin and black holes with acceleration. This spin-acceleration coupling effect is absent from the thermal radiation spectrum of scalar particles.

  19. Hawking radiation of spin-1 particles from a three-dimensional rotating hairy black hole

    Science.gov (United States)

    Sakalli, I.; Ovgun, A.

    2015-09-01

    We study the Hawking radiation of spin-1 particles (so-called vector particles) from a three-dimensional rotating black hole with scalar hair using a Hamilton-Jacobi ansatz. Using the Proca equation in the WKB approximation, we obtain the tunneling spectrum of vector particles. We recover the standard Hawking temperature corresponding to the emission of these particles from a rotating black hole with scalar hair.

  20. Hawking radiation of spin-1 particles from a three-dimensional rotating hairy black hole

    Energy Technology Data Exchange (ETDEWEB)

    Sakalli, I.; Ovgun, A., E-mail: ali.ovgun@emu.edu.tr [Eastern Mediterranean University Famagusta, North Cyprus, Department of Physics (Turkey)

    2015-09-15

    We study the Hawking radiation of spin-1 particles (so-called vector particles) from a three-dimensional rotating black hole with scalar hair using a Hamilton–Jacobi ansatz. Using the Proca equation in the WKB approximation, we obtain the tunneling spectrum of vector particles. We recover the standard Hawking temperature corresponding to the emission of these particles from a rotating black hole with scalar hair.

  1. Synthesis of carbon black/carbon nitride intercalation compound composite for efficient hydrogen production.

    Science.gov (United States)

    Wu, Zhaochun; Gao, Honglin; Yan, Shicheng; Zou, Zhigang

    2014-08-21

    The photoactivity of g-C3N4 is greatly limited by its high recombination rate of photogenerated carriers. Coupling g-C3N4 with other materials has been demonstrated to be an effective way to facilitate the separation and transport of charge carriers. Herein we report a composite of conductive carbon black and carbon nitride intercalation compound synthesized through facile one-step molten salt method. The as-prepared carbon black/carbon nitride intercalation compound composite was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM), UV-vis absorption spectrum and photoluminescence spectroscopy (PL). The carbon black nanoparticles, homogeneously dispersed on the surface of carbon nitride intercalation compound, efficiently enhanced separation and transport of photogenerated carriers, thus improving the visible-light photocatalytic activity. The composite of 0.5 wt% carbon black and carbon nitride intercalation compound exhibited a H2 production rate of 68.9 μmol h(-1), which is about 3.2 times higher than hydrogen production on pristine carbon nitride intercalation compound.

  2. Heat generation of mechanically abused lithium-ion batteries modified by carbon black micro-particulates

    International Nuclear Information System (INIS)

    In the current study, we experimentally investigated the effects of carbon black micro-particulates (CBMP) on the temperature increase of lithium-ion battery coin cells subjected to nail penetration and blunt impact. The major difference between CBMP and regular carbon black additives is in particle size. The testing data showed that addition of 1 wt% of CBMP in the cathode and anode does not influence the cycle life, while can reduce the heat generation rate by nearly 50%, after the peak temperature is reached. Thermal treatment of the modified cells at 100 °C would further reduce the heat generate rate. The initial temperature increase rate, the maximum temperature, as well as the total energy dissipation are not affected. These findings shed light on thermal runaway mitigation of high-energy batteries. (paper)

  3. Hawking radiation of massive vector particles from the linear dilaton black holes

    Science.gov (United States)

    Li, Ran; Zhao, Junkun

    2016-07-01

    By using the tunneling formalism, we calculated the massive vector particles' Hawking radiation from the non-rotating and rotating linear dilaton black holes. By applying the WKB approximation to the Proca field equation that govern the dynamics of massive vector bosons, we derive the tunneling probabilities and radiation spectrums of the emitted vector particles from the linear dilaton black holes. The Hawking temperatures of the linear dilaton black holes have been recovered, which are consistent with the previous results in the literature. This means that the vector particles' tunneling method can also be used in studying the Hawking radiation of asymptotically non-flat and non-AdS black holes.

  4. Assessing the Extent of Black Carbon Absorption Enhancements from Field Observations

    Science.gov (United States)

    Cappa, C. D.; Zhang, X.; Metcalf, A. R.; Kim, H.; Zhang, Q.; Zimmermann, K.; Bertram, T. H.; Corrigan, A. L.; Russell, L. M.

    2013-12-01

    Black carbon (BC) and brown carbon (BrC) play important roles as short-lived climate forcers (SLCFs) as a result of their short atmospheric lifetimes and ability to absorb solar radiation. The direct impacts of BC on climate depend on just how efficiently a given BC particle absorbs solar radiation, while the impacts of BrC depend on the specific properties of the BrC. The addition of 'coatings' to BC particles can theoretically increase the absorption by a given particle, and this theoretical 'lensing' enhancement has been confirmed through laboratory experiments. However, recent field observations (from the CalNex and CARES studies; Cappa et al. 2012), using a novel thermodenuder-absorption method, have suggested that the actual enhancement for ambient particles is substantially less than theoretically expected. Here, we will discuss results from similar measurements made during two recent field studies, the 2013 DISCOVER-AQ Fresno study and the 2013 SOAS Look Rock study. DISCOVER-AQ took place in Jan/Feb 2013 in Fresno, CA. This region is severely impacted by particulate matter from local and regional residential biomass burning, and thus provides a sharp contrast to the previous CalNex and CARES studies. SOAS took place during June/July 2013 at Look Rock National Park, TN, a relatively remote region strongly impacted by biogenic emissions (predominately isoprene) and located approximately 30 miles away from Knoxville, TN. The difference in absorption for dry, ambient particles will be compared with absorption measured for particles that have been passed through a thermodenuder. Additionally, variations in the mass absorption coefficient, determined from comparison of the measured light absorption and refractory black carbon concentrations, will be examined. The relative contributions of BrC and BC to total absorption at 405 nm, 532 nm and 870 nm will be discussed. The overall measurements suggest a relatively small role for lensing-induced absorption

  5. Hawking radiation of scalar particles from accelerating and rotating black holes

    Energy Technology Data Exchange (ETDEWEB)

    Gillani, Usman A.; Rehman, Mudassar; Saifullah, K., E-mail: mani_precious2001@yahoo.com, E-mail: mudassar051@yahoo.com, E-mail: saifullah@qau.edu.pk [Department of Mathematics, Quaid-i-Azam University, Islamabad (Pakistan)

    2011-06-01

    Hawking radiation of uncharged and charged scalar particles from accelerating and rotating black holes is studied. We calculate the tunneling probabilities of these particles from the rotation and acceleration horizons of these black holes. Using this method we recover the correct Hawking temperature as well.

  6. Phase Transformations of Graphite and Carbon Black by Laser with Low Power Density

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The structure phase transformations of graphite and carbon black induced by pulsed laser were studied in this paper. Under irradiation with laser beam of 1.06μm wavelength and power density of 106 W· cm- 2, both graphite structure and carbon black structure were changed obviously. The results of Raman analyses and Transmission Electron Microscopy (TEM) observations show that graphite transforms into nanodiamond about 5 nm and carbon black is graphitized. It is demonstrated that graphite is the intermediate phase in the transformation from carbon black to diamond, and graphite is easier to transform into diamond by laser irradiation than carbon black.

  7. Hawking Radiation of Vector Particles via Tunneling From 4-Dimensional And 5-Dimensional Black Holes

    CERN Document Server

    Feng, Zhongwen; Zu, Xiaotao

    2016-01-01

    Using Proca equation and WKB approximation, we investigate Hawking radiation of vector particles via tunneling from 4-dimensional Kerr-de Sitter black hole and 5-dimensional Schwarzschild-Tangherlini black hole. The results show that the tunneling rates and Hawking temperatures are depended on the properties of spacetime (event horizon, mass and angular momentum). Besides, our results are the same as scalars and fermions tunneling from 4-dimensional Kerr-de Sitter black hole and 5-dimensional Schwarzschild-Tangherlini black hole.

  8. Effective density of Aquadag and fullerene soot black carbon reference materials used for SP2 calibration

    Directory of Open Access Journals (Sweden)

    M. Gysel

    2011-08-01

    Full Text Available The mass and effective density of black carbon (BC particles generated from aqueous suspensions of Aquadag and fullerene soot was measured and parametrized as a function of their mobility diameter. The measurements were made by two independent research groups by operating a differential mobility analyser (DMA in series with an aerosol particle mass analyser (APM or a Couette centrifugal particle mass analyser (CPMA. Consistent and reproducible results were found in this study for different production lots of Aquadag, indicating that the effective density of these particles is a stable quantity and largely unaffected by differences in aerosol generation procedures and suspension treatments. The effective density of fullerene soot particles from one production lot was also found to be stable and independent of suspension treatments. Some difference to previous literature data was observed for both Aquadag and fullerene soot at larger particle diameters. Knowledge of the exact relationship between mobility diameter and particle mass is of great importance, as DMAs are commonly used to size-select particles from BC reference materials for calibration of single particle soot photometers (SP2, which quantitatively detect the BC mass in single particles.

  9. Effective density of Aquadag and fullerene soot black carbon reference materials used for SP2 calibration

    Directory of Open Access Journals (Sweden)

    M. Gysel

    2011-12-01

    Full Text Available The mass and effective density of black carbon (BC particles generated from aqueous suspensions of Aquadag and fullerene soot was measured and parametrized as a function of their mobility diameter. The measurements were made by two independent research groups by operating a differential mobility analyser (DMA in series with an aerosol particle mass analyser (APM or a Couette centrifugal particle mass analyser (CPMA. Consistent and reproducible results were found in this study for different production lots of Aquadag, indicating that the effective density of these particles is a stable quantity and largely unaffected by differences in aerosol generation procedures and suspension treatments. The effective density of fullerene soot particles from one production lot was also found to be stable and independent of suspension treatments. Some differences to previous literature data were observed for both Aquadag and fullerene soot at larger particle diameters. Knowledge of the exact relationship between mobility diameter and particle mass is of great importance, as DMAs are commonly used to size-select particles from BC reference materials for calibration of single particle soot photometers (SP2, which quantitatively detect the BC mass in single particles.

  10. Modified tunneling radiation of the scalar particles and Dirac particles from a five-dimensional black hole

    Science.gov (United States)

    Feng, Zhongwen; Zhu, Xiaodan; Li, Guoping; Fang, Weijing; Zu, Xiaotao

    2016-01-01

    Incorporating the generalized uncertainty principle (GUP) into the tunneling mechanism, we have studied the tunneling radiation of the scalar particles and fermions from the five-dimensional Schwarzschild-Tangherlini black hole. The results showed that the GUP corrected temperatures do not only depend on the mass of ST black hole, but are also affected by the gravity effects correction β. Besides, the β slows down the Hawking temperature increasing and causes the existence of remnants in black hole evaporation.

  11. Particle Acceleration in Kerr-(anti-) de Sitter Black Hole Backgrounds

    CERN Document Server

    Li, Yang; Li, Yun-Liang; Wei, Shao-Wen; Liu, Yu-Xiao

    2010-01-01

    Recently, Ban\\~{a}dos, Silk and West (BSW) found that the center-of-mass energy of two colliding test particles in the neighborhood of an extreme Kerr black hole could be arbitrarily high when one particle has the critical angular momentum. In their paper, they considered the black holes living in a Minkowski space-time with a zero cosmological constant. In this work, we study this process of particles in the backgrounds of the Kerr black holes living in a space-time with a nonzero cosmological constant. We find that for kerr black holes living in a space-time with a negative cosmological constant (Kerr-anti-de Sitter black holes), this process of particles could happen only if the Kerr-anti-de Sitter black hole is extreme and an additional fine tuning is satisfied; while for kerr black holes living in a space-time with a positive cosmological constant (Kerr-de Sitter black holes), this process of particles could happen no matter the Kerr-de Sitter black hole is extreme or not. We also study the particle coll...

  12. Dissolved black carbon in Antarctic lakes: Chemical signatures of past and present sources

    Science.gov (United States)

    Khan, Alia L.; Jaffé, Rudolf; Ding, Yan; McKnight, Diane M.

    2016-06-01

    The perennially ice-covered, closed-basin lakes in the McMurdo Dry Valleys, Antarctica, serve as sentinels for understanding the fate of dissolved black carbon from glacial sources in aquatic ecosystems. Here we show that dissolved black carbon can persist in freshwater and saline surface waters for thousands of years, while preserving the chemical signature of the original source materials. The ancient brines of the lake bottom waters have retained dissolved black carbon with a woody chemical signature, representing long-range transport of black carbon from wildfires. In contrast, the surface waters are enriched in contemporary black carbon from fossil fuel combustion. Comparison of samples collected 25 years apart from the same lake suggests that the enrichment in anthropogenic black carbon is recent. Differences in the chemical composition of dissolved black carbon among the lakes are likely due to biogeochemical processing such as photochemical degradation and sorption on metal oxides.

  13. Particle trapping using dielectrophoretically patterned carbon nanotubes.

    Science.gov (United States)

    Khoshmanesh, Khashayar; Zhang, Chen; Nahavandi, Saeid; Tovar-Lopez, Francisco J; Baratchi, Sara; Hu, Zheng; Mitchell, Arnan; Kalantar-Zadeh, Kourosh

    2010-04-01

    This study presents the dielectrophoretic (DEP) assembly of multi-walled carbon nanotubes (MWCNTs) between curved microelectrodes for the purpose of trapping polystyrene microparticles within a microfluidic system. Under normal conditions, polystyrene particles exhibit negative DEP behaviour and are repelled from microelectrodes. Interestingly, the addition of MWCNTs to the system alters this situation in two ways: first, they coat the surface of particles and change their dielectric properties to exhibit positive DEP behaviour; second, the assembled MWCNTs are highly conductive and after the deposition serve as extensions to the microelectrodes. They establish an array of nanoelectrodes that initiates from the edge of microelectrodes and grow along the electric field lines. These nanoelectrodes can effectively trap the MWCNT-coated particles, since they cover a large portion of the microchannel bottom surface and also create a much stronger electric field than the primary microelectrodes as confirmed by our numerical simulations. We will show that the presence of MWCNT significantly changes performance of the system, which is investigated by trapping sample polystyrene particles with plain, COOH and goat anti-mouse IgG surfaces. PMID:20301125

  14. Academic Training Lectures | Black Holes from a Particle Physics Perspective | 18-19 November

    CERN Multimedia

    2014-01-01

    Black Holes from a Particle Physics Perspective by Georgi Dvali   Tuesday 18 and Wednesday 19 November 2014 from 11 am to 12 noon at CERN ( 40-S2-A01 - Salle Anderson ) Description: We will review the physics of black holes, both large and small, from a particle physicist's perspective, using particle physics tools for describing concepts such as entropy, temperature and quantum information processing. We will also discuss microscopic pictures of black hole formation in high energy particle scattering, potentially relevant for high-energy accelerator experiments, and some differences and similarities with the signatures of other BSM physics. See the Indico page here.

  15. Oxidation behavior of a kind of carbon black

    Institute of Scientific and Technical Information of China (English)

    TANG JunShi; SONG Qiang; HE BaiLei; YAO Qiang

    2009-01-01

    The DTG curves of a kind of carbon black during TPO tests were found to have multiple peaks with an unusual sharp peak after the main peak. TPO tests with different sample loads, oxygen fractions and heating rates were carried out to study the influence of the experimental parameters on the sharp peak. The results show that the sharp peak is not caused by heat and mass transfer limitations, but by the intrinsic oxidation kinetics of the carbon black. The evolution of the specific surface area during the intrinsic kinetic controlled oxidation process was then analyzed using isothermal oxidation at low temperatures which showed that the sharp peak is caused by the increase of the specific surface area. The pore structure changes greatly influence the oxidation process when the reaction is controlled by the intrinsic kinetics. When there were no heat and mass transfer limitations, the different oxidation processes result in the same specific surface area evolution.

  16. Comparison of Toxicity and Deposition of Nano-Sized Carbon Black Aerosol Prepared With or Without Dispersing Sonication

    Science.gov (United States)

    Kang, Mingu; Han, Jeong-Hee

    2013-01-01

    Nanotoxicological research has shown toxicity of nanomaterials to be inversely related to particle size. However, the contribution of agglomeration to the toxicity of nanomaterials has not been sufficiently studied, although it is known that agglomeration is associated with increased nanomaterial size. In this study, we prepared aerosols of nano-sized carbon black by 2 different ways to verify the effects of agglomeration on the toxicity and deposition of nano-sized carbon black. The 2 methods of preparation included the carbon black dispersion method that facilitated clustering without sonication and the carbon black dispersion method involving sonication to achieve scattering and deagglomeration. Male Sprague-Dawley rats were exposed to carbon black aerosols 6 hr a day for 3 days or for 2 weeks. The median mass aerodynamic diameter of carbon black aerosols averaged 2.08 μm (for aerosol prepared without sonication; group N) and 1.79 μm (for aerosol prepared without sonication; group S). The average concentration of carbon black during the exposure period for group N and group S was 13.08 ± 3.18 mg/m3 and 13.67 ± 3.54 mg/ m3, respectively, in the 3-day experiment. The average concentration during the 2-week experiment was 9.83 ± 3.42 mg/m3 and 9.08 ± 4.49 mg/m3 for group N and group S, respectively. The amount of carbon black deposition in the lungs was significantly higher in group S than in group N in both 3-day and 2-week experiments. The number of total cells, macrophages and polymorphonuclear leukocytes in the bronchoalveolar lavage (BAL) fluid, and the number of total white blood cells and neutrophils in the blood in the 2- week experiment were significantly higher in group S than in normal control. However, differences were not found in the inflammatory cytokine levels (IL-1β, TNF-α, IL-6, etc.) and protein indicators of cell damage (albumin and lactate dehydrogenase) in the BAL fluid of both group N and group S as compared to the normal control. In

  17. Dirac and scalar particles tunnelling from topological massive warped-AdS3 black hole

    Science.gov (United States)

    Gecim, G.; Sucu, Y.

    2015-06-01

    We investigate the Dirac and scalar particles tunnelling as a radiation of Warped AdS3 black holes in Topological Massive Gravity. Using Hamilton-Jacobi method, we discuss tunnelling probability and Hawking temperature of the spin-1/2 and spin-0 particles for the black hole. We observe the tunnelling probability and Hawking temperature to be same for the spin-1/2 and spin-0. We show that the tunnelling process may occur, for both Dirac and scalar particles.

  18. Hawking Radiation of Dirac Particles in an Arbitrarily Accelerating Kinnersley Black Hole

    OpenAIRE

    Wu, S Q; Cai, X.

    2002-01-01

    Quantum thermal effect of Dirac particles in an arbitrarily accelerating Kinnersley black hole is investigated by using the method of generalized tortoise coordinate transformation. Both the location and the temperature of the event horizon depend on the advanced time and the angles. The Hawking thermal radiation spectrum of Dirac particles contains a new term which represents the interaction between particles with spin and black holes with acceleration. This spin-acceleration coupling effect...

  19. Massive particles' tunnelling radiation from the black hole with a mass-quadruple moment

    Institute of Scientific and Technical Information of China (English)

    Han Yi-Wen

    2007-01-01

    In this paper, we extend Zhang and Zhao's recent work to the black hole with a mass-quadruple moment. The behaviour of the tunnelling massive particles is investigated, and the emission rate at which massive particles tunnel across the event horizon of the black hole is calculated. The result is consistent with an underlying unitary theory, and takes the same functional form as that of a massless particle.

  20. Single particle studies of black liquor gasification under pressurized conditions

    Energy Technology Data Exchange (ETDEWEB)

    Whitty, K.; Backman, R.; Hupa, M.; Backman, P.; Ek, P.; Hulden, S.T.; Kullberg, M.; Sorvari, V.

    1997-10-01

    The purpose of this project is to provide experimental data relevant to pressurized black liquor gasification concepts. Specifically, the following two goals will be achieved: Data on swelling, char yields and component release during pressurized pyrolysis of small samples of black liquor will be obtained. The reactivity and physical behavior of single black liquor droplets during simultaneous pyrolysis and gasification will be investigated. The structure and composition of black liquor char during formation and conversion will be studied. (orig.)

  1. Personal exposure to Black Carbon in transport microenvironments

    Science.gov (United States)

    Dons, Evi; Int Panis, Luc; Van Poppel, Martine; Theunis, Jan; Wets, Geert

    2012-08-01

    We evaluated personal exposure of 62 individuals to the air pollutant Black Carbon, using 13 portable aethalometers while keeping detailed records of their time-activity pattern and whereabouts. Concentrations encountered in transport are studied in depth and related to trip motives. The evaluation comprises more than 1500 trips with different transport modes. Measurements were spread over two seasons. Results show that 6% of the time is spent in transport, but it accounts for 21% of personal exposure to Black Carbon and approximately 30% of inhaled dose. Concentrations in transport were 2-5 times higher compared to concentrations encountered at home. Exposure was highest for car drivers, and car and bus passengers. Concentrations of Black Carbon were only half as much when traveling by bike or on foot; when incorporating breathing rates, dose was found to be twice as high for active modes. Lowest 'in transport' concentrations were measured in trains, but nevertheless these concentrations are double the concentrations measured at home. Two thirds of the trips are car trips, and those trips showed a large spread in concentrations. In-car concentrations are higher during peak hours compared to off-peak, and are elevated on weekdays compared to Saturdays and even more so on Sundays. These findings result in significantly higher exposure during car commute trips (motive 'Work'), and lower concentrations for trips with motive 'Social and leisure'. Because of the many factors influencing exposure in transport, travel time is not a good predictor of integrated personal exposure or inhaled dose.

  2. Barrow Black Carbon Source and Impact Study Final Campaign Report

    Energy Technology Data Exchange (ETDEWEB)

    Barrett, Tate [Baylor Univ., Waco, TX (United States)

    2014-07-01

    The goal of the Barrow Black Carbon Source and Impact (BBCSI) Study was to characterize the concentration and isotopic composition of carbonaceous atmospheric particulate matter (PM) at the Atmospheric Radiation Measurement site in Barrow, AK. The carbonaceous component was characterized via measurement of the organic and black carbon (OC and BC) components of the total PM. To facilitate complete characterization of the particulate matter, filter-based collections were used, including a medium volume PM2.5 sampler and a high volume PM10 sampler. Thirty-eight fine (PM2.5) and 49 coarse (PM10) particulate matter fractions were collected at weekly and bi-monthly intervals. The PM2.5 sampler operated with minimal maintenance during the 12 month campaign. The PM10 sampler used for the BBCSI used standard Tisch hi-vol motors which have a known lifetime of ~1 month under constant use; this necessitated monthly maintenance and it is suggested that the motors be upgraded to industrial blowers for future deployment in the Arctic. The BBCSI sampling campaign successfully collected and archived 87 ambient atmospheric particulate matter samples from Barrow, AK from July 2012 to June 2013. Preliminary analysis of the organic and black carbon concentrations has been completed. This campaign confirmed known trends of high BC lasting from the winter through to spring haze periods and low BC concentrations in the summer.

  3. Analysis of transpacific transport of black carbon during HIPPO-3: implications for black carbon aging

    Directory of Open Access Journals (Sweden)

    Z. Shen

    2014-01-01

    Full Text Available Long-range transport of black carbon (BC is a growing concern as a result of the efficiency of BC in warming the climate and its adverse impact on human health. We study transpacific transport of BC during HIPPO-3 using a combination of inverse modeling and sensitivity analysis. We use the GEOS-Chem chemical transport model and its adjoint to constrain Asian BC emissions and estimate the source of BC over the North Pacific. We find that different sources of BC dominate the transport to the North Pacific during the southbound (29 March 2010 and northbound (13 April 2010 measurements in HIPPO-3. While biomass burning in Southeast Asia (SE contributes about 60% of BC in March, more than 90% of BC comes from fossil fuel and biofuel combustion in East Asia (EA during the April mission. GEOS-Chem simulations generally resolve the spatial and temporal variation of BC concentrations over the North Pacific, but are unable to reproduce the low and high tails of the observed BC distribution. We find that the optimized BC emissions derived from inverse modeling fail to improve model simulations significantly. This failure indicates that uncertainties in BC transport, rather than in emissions, account for the major biases in GEOS-Chem simulations of BC. The aging process, transforming BC from hydrophobic into hydrophilic form, is one of the key factors controlling wet scavenging and remote concentrations of BC. Sensitivity tests on BC aging suggest that the aging time scale of anthropogenic BC from EA is several hours, faster than assumed in most global models, while the aging process of biomass burning BC from SE may occur much slower, with a time scale of a few days. To evaluate the effects of BC aging and wet deposition on transpacific transport of BC, we develop an idealized model of BC transport. We find that the mid-latitude air masses sampled during HIPPO-3 may have experienced a series of precipitation events, particularly near the EA and SE source

  4. Massive vector particles tunneling from noncommutative charged black holes and their GUP-corrected thermodynamics

    Science.gov (United States)

    Övgün, Ali; Jusufi, Kimet

    2016-05-01

    In this paper, we investigate the tunneling process of charged massive bosons W^{±} (spin-1 particles) from noncommutative charged black holes such as charged RN black holes and charged BTZ black holes. By applying the WKB approximation and by using the Hamilton-Jacobi equation we derive the tunneling rate and the corresponding Hawking temperature for those black holes configuration. Furthermore, we show the quantum gravity effects using the GUP on the Hawking temperature for the noncommutative RN black holes. The tunneling rate shows that the radiation deviates from pure thermality and is consistent with an underlying unitary theory.

  5. Particle Collisions in the Lower Dimensional Rotating Black Hole Space-Time with the Cosmological Constant

    Directory of Open Access Journals (Sweden)

    Jie Yang

    2014-01-01

    Full Text Available We study the effect of ultrahigh energy collisions of two particles with different energies near the horizon of a 2+1 dimensional BTZ black hole (BSW effect. We find that the particle with the critical angular momentum could exist inside the outer horizon of the BTZ black hole regardless of the particle energy. Therefore, for the nonextremal BTZ black hole, the BSW process is possible on the inner horizon with the fine tuning of parameters which are characterized by the motion of particle, while, for the extremal BTZ black hole, the particle with the critical angular momentum could only exist on the degenerated horizon, and the BSW process could also happen there.

  6. Improved dynamic properties of natural rubber filled with irradiation-modified carbon black

    Science.gov (United States)

    Wu, Yongpeng; Wen, Shipeng; Shen, Jing; Jiang, Jian; Hu, Shui; Zhang, Liqun; Liu, Li

    2015-06-01

    In this work, carbon black particles (CBs) were modified by high-energy electron beam (EB) irradiation at different doses. The influence of EB irradiation on the surface and particle size of CBs was investigated. Then, the CBs were compounded with natural rubber (NR), and the mechanical properties and dynamic properties of CBs/NR composite were further researched. The results showed that the irradiated CBs had more oxygen-containing groups and smaller particle sizes than original CBs. After irradiation, the content of bound rubber around the irradiated CBs increased, and the mechanical properties of CBs/NR composite were improved. Most importantly, NR filled with irradiated CBs has lower abrasion, higher wet skid resistance, and lower rolling resistance than NR filled with untreated CBs.

  7. Sulfonated carbon black-based composite membranes for fuel cell applications

    Indian Academy of Sciences (India)

    Hacer Doǧan; Emel Yildiz; Metin Kaya; Tülay Y Inan

    2013-08-01

    Two different commercial grade carbon black samples, Cabot Regal 400R (C1) and Cabot Mogul L (C2), were sulfonated with diazonium salt of sulfanilic acid. The resultant sulfonated carbon black samples (S–C) were characterized by Fourier transform infrared spectroscopy (FTIR) and thermal gravimetric analysis (TGA). Composite membranes were then prepared using S–C as fillers and sulfonated poly(ether ether ketone) (SPEEK) as polymer matrix with three different sulfonation degrees (DS = 60, 70 and 82%). Structure and properties of the composite membranes were characterized by FTIR, TGA, scanning electron microscopy, proton conduction, water uptake, ion exchange capacity and chemical stability. Incorporation of S–C particles above 0.25 wt% caused decrease in chemical stability. Pristine and composite membranes prepared from SPEEK82 decomposed completely in <1 h, which is undesirable for fuel cell applications. SPEEK60 membrane having wt% of 0.25–0.5 with S–C particles led to higher proton conductivity than that of pristine membrane. No positive effect was observed on the properties of the composite membranes with the addition of S–C particles at high concentrations due to the agglomeration problems and decrease in the content of conductive polymer matrix.

  8. Some Interesting Behaviour of Accreting Particles in the Gap Region of Black Hole Accretion Discs

    Institute of Scientific and Technical Information of China (English)

    WANG Ding-Xiong; XIAO Kan; LEI Wei-Hua

    2001-01-01

    Some interesting behaviour of accreting particles in the gap region between the horizon of the Kerr black hole and the inner edge of the surrounding disc is investigated. The following results are obtained. (i) Spacetime coincidence of the maximum of angular velocity of accreting particles and that of the black hole horizon is extended to the more general disc-accretion. (ii) The possibility is discussed of negative energy of accreting particles in prograde orbit inside the ergosphere of the Kerr black hole, which is surrounded by strong enough magnetic field.

  9. Tunneling Radiation of Vector Particles in Four and Five Dimensional Black Holes

    Science.gov (United States)

    Chen, Bingbing

    2016-07-01

    Recent research shows that the WKB approximation and the Hamilton-Jacobi method has been succeed in studying the tunneling radiation of vector particles. In view of this, our main aim in this letter is to study the Proca equation and the vector particles tunneling radiation in the 4-dimensional and 5-dimensional black holes. And finally, the results here show that the temperature of vector particle is the same as Dirac particle's and other particle's.

  10. The onset of chaotic motion of a spinning particle around the Schwarzchild black hole

    Energy Technology Data Exchange (ETDEWEB)

    Kao, J.-K. [Department of Physics, Tamkang University, Tamsui, Taipei, Taiwan (China)]. E-mail: g3180011@tkgis.tku.edu.tw; Cho, H.T. [Department of Physics, Tamkang University, Tamsui, Taipei, Taiwan (China)]. E-mail: htcho@mail.tku.edu.tw

    2005-03-07

    In the Schwarzschild black hole spacetime, we show that chaotic motion can be triggered by the spin of a particle. Taking the spin of the particle as a perturbation and using the Melnikov method, we find that the perturbed stable and unstable orbits are entangled with each other and that illustrates the onset of chaotic behavior in the motion of the particle.

  11. The Onset of Chaotic Motion of a Spinning Particle around the Schwarzchild Black Hole

    CERN Document Server

    Kao, J K

    2005-01-01

    In the Schwarzchild black hole spacetime, we show that chaotic motion can be triggered by the spin of a particle. Taking the spin of the particle as a perturbation and using the Melnikov method, we find that the perturbed stable and unstable orbits are entangled with each other and that illustrates the onset of chaotic behavior in the motion of the particle.

  12. Evaluation of black carbon estimations in global aerosol models

    Directory of Open Access Journals (Sweden)

    D. Koch

    2009-07-01

    Full Text Available We evaluate black carbon (BC model predictions from the AeroCom model intercomparison project by considering the diversity among year 2000 model simulations and comparing model predictions with available measurements. These model-measurement intercomparisons include BC surface and aircraft concentrations, aerosol absorption optical depth (AAOD from AERONET and Ozone Monitoring Instrument (OMI retrievals and BC column estimations based on AERONET. In regions other than Asia, most models are biased high compared to surface concentration measurements. However compared with (column AAOD or BC burden retreivals, the models are generally biased low. The average ratio of model to retrieved AAOD is less than 0.7 in South American and 0.6 in African biomass burning regions; both of these regions lack surface concentration measurements. In Asia the average model to observed ratio is 0.6 for AAOD and 0.5 for BC surface concentrations. Compared with aircraft measurements over the Americas at latitudes between 0 and 50 N, the average model is a factor of 10 larger than observed, and most models exceed the measured BC standard deviation in the mid to upper troposphere. At higher latitudes the average model to aircraft BC is 0.6 and underestimates the observed BC loading in the lower and middle troposphere associated with springtime Arctic haze. Low model bias for AAOD but overestimation of surface and upper atmospheric BC concentrations at lower latitudes suggests that most models are underestimating BC absorption and should improve estimates for refractive index, particle size, and optical effects of BC coating. Retrieval uncertainties and/or differences with model diagnostic treatment may also contribute to the model-measurement disparity. Largest AeroCom model diversity occurred in northern Eurasia and the remote Arctic, regions influenced by anthropogenic sources. Changing emissions, aging, removal, or optical properties within a single model generated a

  13. Evaluation of Black Carbon Estimations in Global Aerosol Models

    Energy Technology Data Exchange (ETDEWEB)

    Koch, D.; Schulz, M.; Kinne, Stefan; McNaughton, C. S.; Spackman, J. R.; Balkanski, Y.; Bauer, S.; Berntsen, T.; Bond, Tami C.; Boucher, Olivier; Chin, M.; Clarke, A. D.; De Luca, N.; Dentener, F.; Diehl, T.; Dubovik, O.; Easter, Richard C.; Fahey, D. W.; Feichter, J.; Fillmore, D.; Freitag, S.; Ghan, Steven J.; Ginoux, P.; Gong, S.; Horowitz, L.; Iversen, T.; Kirkevag, A.; Klimont, Z.; Kondo, Yutaka; Krol, M.; Liu, Xiaohong; Miller, R.; Montanaro, V.; Moteki, N.; Myhre, G.; Penner, J.; Perlwitz, Ja; Pitari, G.; Reddy, S.; Sahu, L.; Sakamoto, H.; Schuster, G.; Schwarz, J. P.; Seland, O.; Stier, P.; Takegawa, Nobuyuki; Takemura, T.; Textor, C.; van Aardenne, John; Zhao, Y.

    2009-11-27

    We evaluate black carbon (BC) model predictions from the AeroCom model intercomparison project by considering the diversity among year 2000 model simulations and comparing model predictions with available measurements. These model-measurement intercomparisons include BC surface and aircraft concentrations, aerosol absorption optical depth (AAOD) from AERONET and OMI retrievals and BC column estimations based on AERONET. In regions other than Asia, most models are biased high compared to surface concentration measurements. However compared with (column) AAOD or BC burden retreivals, the models are generally biased low. The average ratio of model to retrieved AAOD is less than 0.7 in South American and 0.6 in African biomass burning regions; both of these regions lack surface concentration measurements. In Asia the average model to observed ratio is 0.6 for AAOD and 0.5 for BC surface concentrations. Compared with aircraft measurements over the Americas at latitudes between 0 and 50N, the average model is a factor of 10 larger than observed, and most models exceed the measured BC standard deviation in the mid to upper troposphere. At higher latitudes the average model to aircraft BC is 0.6 and underestimate the observed BC loading in the lower and middle troposphere associated with springtime Arctic haze. Low model bias for AAOD but overestimation of surface and upper atmospheric BC concentrations at lower latitudes suggests that most models are underestimating BC absorption and should improve estimates for refractive index, particle size, and optical effects of BC coating. Retrieval uncertainties and/or differences with model diagnostic treatment may also contribute to the model-measurement disparity. Largest AeroCom model diversity occurred in northern Eurasia and the remote Arctic, regions influenced by anthropogenic sources. Changing emissions, aging, removal, or optical properties within a single model generated a smaller change in model predictions than the

  14. Evaluation of black carbon estimations in global aerosol models

    Directory of Open Access Journals (Sweden)

    Y. Zhao

    2009-11-01

    Full Text Available We evaluate black carbon (BC model predictions from the AeroCom model intercomparison project by considering the diversity among year 2000 model simulations and comparing model predictions with available measurements. These model-measurement intercomparisons include BC surface and aircraft concentrations, aerosol absorption optical depth (AAOD retrievals from AERONET and Ozone Monitoring Instrument (OMI and BC column estimations based on AERONET. In regions other than Asia, most models are biased high compared to surface concentration measurements. However compared with (column AAOD or BC burden retreivals, the models are generally biased low. The average ratio of model to retrieved AAOD is less than 0.7 in South American and 0.6 in African biomass burning regions; both of these regions lack surface concentration measurements. In Asia the average model to observed ratio is 0.7 for AAOD and 0.5 for BC surface concentrations. Compared with aircraft measurements over the Americas at latitudes between 0 and 50N, the average model is a factor of 8 larger than observed, and most models exceed the measured BC standard deviation in the mid to upper troposphere. At higher latitudes the average model to aircraft BC ratio is 0.4 and models underestimate the observed BC loading in the lower and middle troposphere associated with springtime Arctic haze. Low model bias for AAOD but overestimation of surface and upper atmospheric BC concentrations at lower latitudes suggests that most models are underestimating BC absorption and should improve estimates for refractive index, particle size, and optical effects of BC coating. Retrieval uncertainties and/or differences with model diagnostic treatment may also contribute to the model-measurement disparity. Largest AeroCom model diversity occurred in northern Eurasia and the remote Arctic, regions influenced by anthropogenic sources. Changing emissions, aging, removal, or optical properties within a single model

  15. Factors Controlling Black Carbon Deposition in Snow in the Arctic

    Science.gov (United States)

    Qi, L.; Li, Q.; He, C.; Li, Y.

    2015-12-01

    This study evaluates the sensitivity of black carbon (BC) concentration in snow in the Arctic to BC emissions, dry deposition and wet scavenging efficiency using a 3D global chemical transport model GEOS-Chem driven by meteorological field GEOS-5. With all improvements, simulated median BC concentration in snow agrees with observation (19.2 ng g-1) within 10%, down from -40% in the default GEOS-Chem. When the previously missed gas flaring emissions (mainly located in Russia) are included, the total BC emission in the Arctic increases by 70%. The simulated BC in snow increases by 1-7 ng g-1, with the largest improvement in Russia. The discrepancy of median BC in snow in the whole Arctic reduces from -40% to -20%. In addition, recent measurements of BC dry deposition velocity suggest that the constant deposition velocity of 0.03 cm s-1 over snow and ice used in the GEOS-Chem is too low. So we apply resistance-in-series method to calculate the dry deposition velocity over snow and ice and the resulted dry deposition velocity ranges from 0.03 to 0.24 cm s-1. However, the simulated total BC deposition flux in the Arctic and BC in snow does not change, because the increased dry deposition flux has been compensated by decreased wet deposition flux. However, the fraction of dry deposition to total deposition increases from 16% to 25%. This may affect the mixing of BC and snow particles and further affect the radative forcing of BC deposited in snow. Finally, we reduced the scavenging efficiency of BC in mixed-phase clouds to account for the effect of Wegener-Bergeron-Findeisen (WBF) process based on recent observations. The simulated BC concentration in snow increases by 10-100%, with the largest increase in Greenland (100%), Tromsø (50%), Alaska (40%), and Canadian Arctic (30%). Annual BC loading in the Arctic increases from 0.25 to 0.43 mg m-2 and the lifetime of BC increases from 9.2 to 16.3 days. This indicates that BC simulation in the Arctic is really sensitive to

  16. Black Carbon in Estuarine (Coastal) High-molecular-weight Dissolved Organic Matter

    Science.gov (United States)

    Mannino, Antonio; Harvey, H. Rodger

    2003-01-01

    Dissolved organic matter (DOM) in the ocean constitutes one of the largest pools of organic carbon in the biosphere, yet much of its composition is uncharacterized. Observations of black carbon (BC) particles (by-products of fossil fuel combustion and biomass burning) in the atmosphere, ice, rivers, soils and marine sediments suggest that this material is ubiquitous, yet the contribution of BC to the ocean s DOM pool remains unknown. Analysis of high-molecular-weight DOM isolated from surface waters of two estuaries in the northwest Atlantic Ocean finds that BC is a significant component of DOM, suggesting that river-estuary systems are important exporters of BC to the ocean through DOM. We show that BC comprises 4-7% of the dissolved organic carbon (DOC) at coastal ocean sites, which supports the hypothesis that the DOC pool is the intermediate reservoir in which BC ages prior to sedimentary deposition. Flux calculations suggest that BC could be as important as vascular plant-derived lignin in terms of carbon inputs to the ocean. Production of BC sequesters fossil fuel- and biomass-derived carbon into a refractory carbon pool. Hence, BC may represent a significant sink for carbon to the ocean.

  17. Black Carbon in Estuarine and Coastal Ocean Dissolved Organic Matter

    Science.gov (United States)

    Mannino, Antonio; Harvey, H. Rodger

    2003-01-01

    Black carbon (BC) in ultrafiltered high-molecular-weight DOM (UDOM) was measured in surface waters of Delaware Bay, Chesapeake Bay and the adjacent Atlantic Ocean (USA) to ascertain the importance of riverine and estuarine DOM as a source of BC to the ocean. BC comprised 5-72% of UDOM-C (27+/-l7%) and on average 8.9+/-6.5% of dissolved organic carbon (DOC) with higher values in the turbid region of the Delaware Estuary and lower yields in the river and coastal ocean. The spatial and seasonal distributions of BC along the salinity gradient of Delaware Bay suggest that the higher levels of BC in surface water UDOM originated from localized sources, possibly from atmospheric deposition or released from resuspended sediments. Black carbon comprised 4 to 7% of the DOC in the coastal Atlantic Ocean, revealing that river-estuary systems are important exporters of colloidal BC to the ocean. The annual flux of BC from Delaware Bay UDOM to the Atlantic Ocean was estimated at 2.4x10(exp 10) g BC yr(exp -1). The global river flux of BC through DOM to the ocean could be on the order of 5.5x1O(exp 12)g BC yr (exp -1). These results support the hypothesis that the DOC pool is the intermediate reservoir in which BC ages prior to sedimentary deposition.

  18. Measuring morphology and density of internally mixed black carbon with SP2 and VTDMA: new insight to absorption enhancement of black carbon in the atmosphere

    Directory of Open Access Journals (Sweden)

    Y. X. Zhang

    2015-11-01

    Full Text Available The morphology and density of black carbon (BC cores in internally mixed BC (In-BC particles affects their mixing state and absorption enhancement. In this work, we developed a new method to measure the morphology and effective density of BC cores of ambient In-BC particles using a single particle soot photometer (SP2 and a volatility tandem differential mobility analyzer (VTDMA, during the CAREBeijing-2013 campaign from 8 to 27 July 2013 at Xianghe Observatory. The new measurement system can select size-resolved ambient In-BC particles and measure the mobility size and mass of In-BC cores. The morphology and effective density of ambient In-BC cores are then calculated. For In-BC cores in the atmosphere, changes in the dynamic shape factor (χ and effective density (ρeff can be characterized as a function of aging process (Dp ⁄ Dc measured by SP2 and VTDMA. During an intensive field study, the ambient In-BC cores had an average χ of ∼ 1.2 and an average density of ∼ 1.2 g cm−3, indicating that ambient In-BC cores have a near-spherical shape with an internal void of ∼ 30 %. With the measured morphology and density, the average shell ⁄ core ratio and absorption enhancement (Eab from ambient black carbon were estimated to be 2.1–2.7 and 1.6–1.9 for different sizes of In-BC particles at 200–350 nm. When assuming the In-BC cores have a void-free BC sphere with a density of 1.8 g cm−3, the shell ⁄ core ratio and Eab could be overestimated by ∼ 13 and ∼ 17 % respectively. The new approach developed in this work will help improve calculations of mixing state and optical properties of ambient In-BC particles by quantification of changes in morphology and density of ambient In-BC cores during aging process.

  19. Gamma rays and energetic particles from primordial black holes

    Science.gov (United States)

    Halzen, F.; Zas, E.; Macgibbon, J. H.; Weekes, T. C.

    1991-01-01

    The standard model of quarks and leptons is used to discuss the signatures of black-hole evaporations. A firm bound on the primordial black hole abundance is obtained from MeV data. It is argued that the MeV bound can be improved by exploiting the new generation of TeV and PeV telescopes.

  20. Massive vector particles tunneling from Kerr and Kerr-Newman black holes

    Science.gov (United States)

    Li, Xiang-Qian; Chen, Ge-Rui

    2015-12-01

    In this paper, we investigate the Hawking radiation of massive spin-1 particles from 4-dimensional Kerr and Kerr-Newman black holes. By applying the Hamilton-Jacobi ansatz and the WKB approximation to the field equations of the massive bosons in Kerr and Kerr-Newman space-time, the quantum tunneling method is successfully implemented. As a result, we obtain the tunneling rate of the emitted vector particles and recover the standard Hawking temperature of both the two black holes.

  1. Massive vector particles tunneling from Kerr and Kerr-Newman black holes

    CERN Document Server

    Li, Xiang-Qian

    2015-01-01

    In this paper, we investigate the Hawking radiation of massive spin-1 particles from 4-dimensional Kerr and Kerr-Newman black holes. By applying the Hamilton-Jacobi ansatz and the WKB approximation to the field equations of the massive bosons in Kerr and Kerr-Newman space-time, the quantum tunneling method is successfully implemented. As a result, we obtain the tunneling rate of the emitted vector particles and recover the standard Hawking temperature of both the two black holes.

  2. Tunneling of massive and charged particles from noncommutative Reissner-Nordstr\\"{o}m black hole

    OpenAIRE

    Nozari, Kourosh; Islamzadeh, Sara

    2012-01-01

    Massive charged and uncharged particles tunneling from commutative Reissner-Nordstrom black hole horizon has been studied with details in literature. Here, by adopting the coherent state picture of spacetime noncommutativity, we study tunneling of massive and charged particles from a noncommutative inspired Reissner-Nordstrom black hole horizon. We show that Hawking radiation in this case is not purely thermal and there are correlations between emitted modes. These correlations may provide a ...

  3. Corrected Hawking Radiation of Dirac Particles from a General Static Riemann Black Hole

    Directory of Open Access Journals (Sweden)

    Ge-Rui Chen

    2013-01-01

    Full Text Available Considering energy conservation and the back reaction of radiating particles to the spacetime, we investigate the massive Dirac particles' Hawking radiation from a general static Riemann black hole using improved Damour-Ruffini method. A direct consequence is that the radiation spectrum is not strictly thermal. The correction to the thermal spectrum is consistent with an underlying unitary quantum theory and this may have profound implications for the black hole information loss paradox.

  4. Centennial black carbon turnover observed in a Russia steppe soil

    Energy Technology Data Exchange (ETDEWEB)

    Hammes, K.; Torn, M.S.; Lapenas, A.G.; Schmidt, M.W.I.

    2008-09-15

    Black carbon (BC), from incomplete combustion of fuels and biomass, has been considered highly recalcitrant and a substantial sink for carbon dioxide. Recent studies have shown that BC can be degraded in soils. We use two soils with very low spatial variability sampled 100 years apart in a Russian steppe preserve to generate the first whole-profile estimate of BC stocks and turnover in the field. Quantities of fire residues in soil changed significantly over a century. Black carbon stock was 2.5 kg m{sup -2}, or about 7-10% of total organic C in 1900. With cessation of biomass burning, BC stocks decreased 25% over a century, which translates into a centennial soil BC turnover (293 years best estimate; range 182-541 years), much faster than so-called inert or passive carbon in ecosystem models. The turnover time presented here is for loss by all processes, namely decomposition, leaching, and erosion, although the latter two were probably insignificant in this case. Notably, at both time points, the peak BC stock was below 30 cm, a depth interval, which is not typically accounted for. Also, the quality of the fire residues changed with time, as indicated by the use benzene poly carboxylic acids (BPCA) as molecular markers. The proportions of less-condensed (and thus more easily degradable) BC structures decreased, whereas the highly condensed (and more recalcitrant) BC structures survived unchanged over the 100-year period. Our results show that BC cannot be assumed chemically recalcitrant in all soils, and other explanations for very old soil carbon are needed.

  5. Barrow Black Carbon Source and Impact Study Final Campaign Report

    Energy Technology Data Exchange (ETDEWEB)

    Barrett, Tate

    2014-07-01

    The goal of the Barrow Black Carbon Source and Impact campaign was to characterize the concentration and isotopic composition of carbonaceous atmospheric particulate matter (PM) at the Atmospheric Radiation Measurement (ARM) Climate Research Facility site in Barrow, Alaska. The carbonaceous component was characterized by measuring the organic and black carbon (OC and BC) components of the total PM. To facilitate complete characterization of the PM, filter-based collections were used, including a medium volume PM2.5 sampler and a high volume PM10 sampler. Thirty-eight fine PM fractions (PM2.5) and 49 coarse (PM10) PM fractions were collected at weekly and bi-monthly intervals. The PM2.5 sampler operated with minimal maintenance during the 12 month campaign. The PM10 sampler used for the Barrow Black Carbon Source and Impact (BBCSI) study used standard Tisch “hi-vol” motors that have a known lifetime of approximately 1 month under constant use; this necessitated monthly maintenance, and it is suggested that, for future deployment in the Arctic, the motors be upgraded to industrial blowers. The BBCSI sampling campaign successfully collected and archived 87 ambient atmospheric PM samples from Barrow, Alaska, from July 2012 to June 2013. Preliminary analysis of the OC and BC concentrations has been completed. This campaign confirmed known trends of high BC lasting from the winter through to spring haze periods and low BC concentrations in the summer. However, the annual OC concentrations had a very different seasonal pattern with the highest concentrations during the summer, lowest concentrations during the fall, and increased concentrations during the winter and spring (Figure 1).

  6. World Carbon Black Output to Reach 12.7 Million Tons in 2015

    Institute of Scientific and Technical Information of China (English)

    Zhu Yongkang

    2012-01-01

    From April 13 to April 17, "Carbon Black China of 2012" (CBC2012) was held in Hangzhou, China. Mr. Paul Ita, the president of US marketing research institution Notch Consulting Group, announced that the prospect of carbon black industry was closely linked with the development of auto industry and tire industry. The demand for carbon black of 2010 increased by 15% compared with that of 2009; the growth rate of demand for carbon black was 5.8% in 2011 and the total output was 10.7 million tons, which increased by about 5.5% compared with that of 2010.

  7. Modal character of atmospheric black carbon size distributions

    Science.gov (United States)

    Berner, A.; Sidla, S.; Galambos, Z.; Kruisz, C.; Hitzenberger, R.; ten Brink, H. M.; Kos, G. P. A.

    1996-08-01

    Samples of atmospheric aerosols, collected with cascade impactors in the urban area of Vienna (Austria) and at a coastal site on the North Sea, were investigated for black carbon (BC) as the main component of absorbing material and for mass. The size distributions are structured. The BC distributions of these samples show a predominant mode, the accumulation aerosol, in the upper submicron size range, a less distinct finer mode attributable to fresh emissions from combustion sources, and a distinct coarse mode of unclear origin. It is important to note that some parameters of the accumulation aerosol are related statistically, indicating the evolution of the atmospheric accumulation aerosol.

  8. Utilization of the Net Heat Process Tail Gases in the Reactor for the Production of Oil-Furnace Carbon Black

    Directory of Open Access Journals (Sweden)

    Bosak, Z.

    2011-02-01

    Full Text Available Tail gases of low calorific value, which are the by-product of oil-furnace carbon black industrial production, can be efficiently used as energy before their final release into the atmosphere. Apart from being used mainly for heating dryers, production of steam, electricity, or flared, they can also be used as a substitute for fuel in the reactor for the production of oil-furnace carbon blacks, thus increasing the efficiency of the hydrocarbon raw feedstock.This technical paper represents the technical-technological solution for applying the waste heat of the low calorific tail gases in the reactor for the production of "hard" grade oil-furnace carbon blacks with savings of the hydrocarbon raw feedstock.The introduction of the preheated low calorific tail gases in the reactor for the production of "hard" grade oil-furnace carbon blacks is achieved by serial cascading of four fans. The system consists of fans designed to pneumatically transport the mixture of process tail gases and oil-furnace carbon black dust particles. This ensures a stable technological process for the introduction of the low calorific process tail gases into the reaction zone where the natural gas and preheated air are combusted.In the production of oil-furnace carbon black N220, it is shown that by using low calorific process tail gases in the amount from 1000 to 2000 m3 h–1 per reactor, savings from 10 to 20 % of natural gas and simultaneously 7 to 9 % of the hydrocarbon raw feedstoks were achieved.

  9. Catalytic Enhancement of Carbon Black and Coal-Fueled Hybrid Direct Carbon Fuel Cells

    DEFF Research Database (Denmark)

    Deleebeeck, Lisa; Ippolito, Davide; Kammer Hansen, Kent

    2015-01-01

    , Ce1-xREExO2-δ (REE = Pr, Sm)) and metal oxides (LiMn2O4, Ag2O). Materials showing the highest activity in carbon black (Mn2O3, CeO2, Ce0.6Pr0.4O2-δ, Ag2O) were subsequently tested for catalytic activity toward bituminous coal, as revealed by both I-V-P curves and electrochemical impedance......Hybrid direct carbon fuel cells (HDCFCs) consisting of a solid carbon (carbon black)-molten carbonate ((62–38 wt% Li-K)2CO3) mixtures in the anode chamber of an anode-supported solid oxide fuel cell type full-cell are tested for their electrochemical performance between 700 and 800°C. Performance...... was investigated using current-voltage-power density curves. In the anode chamber, catalysts are mixed with the carbon-carbonate mixture. These catalysts include various manganese oxides (MnO2, Mn2O3, Mn3O4, MnO), metal carbonates (Ag2CO3, MnCO3, Ce2(CO3)3), metals (Ag, Ce, Ni), doped-ceria (CeO2, Ce1-xGdxO2-x/2...

  10. Asymmetry of Hawking Radiation of Dirac Particles in a Charged Vaidya - de Sitter Black Hole

    CERN Document Server

    Wu, S Q

    2001-01-01

    The Hawking radiation of Dirac particles in a charged Vaidya - de Sitter black hole is investigated by using the method of generalized tortoise coordinate transformation. It is shown that the Hawking radiation of Dirac particles does not exist for $P_1, Q_2$ components, but for $P_2, Q_1$ components it does. Both the location and the temperature of the event horizon change with time. The thermal radiation spectrum of Dirac particles is the same as that of Klein-Gordon particles.

  11. Hawking Radiation of Spin-1 Particles From Three Dimensional Rotating Hairy Black Hole

    CERN Document Server

    Sakalli, I

    2015-01-01

    In the present article, we study the Hawking radiation (HR) of spin-1 particles -- so-called vector particles -- from a three dimensional (3D) rotating black hole with scalar hair (RBHWSH) using Hamilton-Jacobi (HJ) ansatz. Putting the Proca equation amalgamated with the WKB approximation in process, the tunneling spectrum of vector particles is obtained. We recover the standard Hawking temperature corresponding to the emission of these particles from RBHWSH.

  12. An approach to a black carbon emission inventory for Mexico by two methods

    Energy Technology Data Exchange (ETDEWEB)

    Cruz-Núñez, Xochitl, E-mail: xcruz@unam.mx

    2014-05-01

    A black carbon (BC) emission inventory for Mexico is presented. Estimate was performed by using two approaches, based on fuel consumption and emission factors in a top-down scheme, and the second from PM25 emission data and its correlation with black carbon by source category, assuming that black carbon = elemental carbon. Results show that black carbon emissions are in interval 53–473 Gg using the fuel consumption approach and between 62 and 89 using the sector method. Black carbon key sources come from biomass burning in the rural sector, with 47 percent share to the National total. Mobile sources emissions account to 16% to the total. An opportunity to reduce, in the short-term, carbon dioxide equivalent (CO2-eq) emissions by reducing black carbon emissions would be obtained in reducing emissions mainly from biomass burning in rural housing sector and diesel emissions in the transport sector with important co-benefits in direct radiative forcing, public health and air quality. - Highlights: • Black carbon emissions are estimated between 53 and 473 Gg/year on a fuel consumption method. • Black carbon emissions are estimated between 62 and 89 Gg/year on a sector method.

  13. Pseudo-capacitance of ruthenium oxide/carbon black composites for electrochemical capacitors

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Hydrous ruthenium oxide was formed by a new process.The precursor was obtained by mixing the aqueous solutions of RuCl3·xH20 and NaHCO3.The addition of NaHCO3 led to the formation of an oxide with extremely free RuO2 particles forming a porous network structure in the oxide electrode.Polyethylene glycol was added as a controller to partly inhibit the sol-gel reaction.The rate capacitance of 530 F·g-1 was measured for the powder formed at an optimal annealing temperature of 210~C.Several details concerning this new material,including crystal structure,particle size as a function of temperature,and electrochemical properties,were also reported.In addition,the rote capacitance of the composite electrode reached 800 F·g-1 after carbon black was added.By using the modified electrode of a RuO2/carbon black composite electrode,the electrochemical capacitor exhibits high energy density and stable power characteristics.The values of specific energy and maximum specific power of 24 Wh·kg-1 and 4 kW·kg-1,respectively,are demonstrated for a cell voltage between 0 and 1 V.

  14. Synthesis of Cordierite by Decomposition of Metal Nitrates on the Surface of Carbon Black Powder

    Institute of Scientific and Technical Information of China (English)

    XIE Zhi-yong; LIANG Hui; XU Ming-xia; XU Ting-xian

    2004-01-01

    Cordierite precursor was obtained through a process, which involved the decomposition of metal nitrates on the surface of ultrafine carbon black powder between 100-300℃ and the gasification of the carbon black at higher temperature in air. The average size of the particles, which were heat-treated at 700℃ for 10h, is about 1020nm, and the specific surface area is about 129m2/g. The experimental results show that the ultrafine particles of cordierite precursor can be produced by this process. The precursor powder was calcined at different temperatures. X-ray diffraction examination indicates that β-quartz is crystallized from the amorphous matrix around 850℃ firstly and then MgO-Al2O3 spinel and α-cordierite appears. Above 1000℃, MgO-Al2O3 spinel and cristobalite disappear gradually and form an intermediate phase (sapphirine). At around 1300℃, the main phase is α-cordierite, and no other phase is detected.

  15. Absorption Cross Section of Static Einstein-Maxwell Dilation Axion Black Hole for Scalar Particles

    Institute of Scientific and Technical Information of China (English)

    LIU Chang-Qing; JING Ji-Liang

    2007-01-01

    The absorption cross section of the static Einstein-Maxwell dilaton axion (EMDA) black hole for scalar particles is investigated.It is shown that the ratio of the absorption cross section of the EMDA black hole to that of the Schwarzschild black hole decreases as the absolute value of the dilaton increases,and it becomes zero as the dilaton tends to its extremal value.It is also shown that the absorption cross section decreases as both the v and the absolute value of the dilaton increase,and it decreases as the mass of the particle decreases.

  16. Another Mechanism which Can Prevent Infinite Collision Energy via Black Hole as Particle Accelerators

    Science.gov (United States)

    Ding, Chikun; Lin, Siyuan; Li, Junfeng; Wang, Peng; Li, Qian; Zhang, Binqing

    2013-03-01

    It has recently been pointed out that infinite center of mass energies for the colliding particles can be attained when the black hole is exactly extremal and only at infinite time and on the horizon of the black hole. In this letter, we show that it cannot occur when the spacetime noncommutative effect is considered, i.e. the quantum effect of gravity is an other preventing mechanism. Additionally, the bigger of the black hole's mass is, the higher of center of mass energy that the particles obtain.

  17. Non-Commutative Space-Times, Black Hole, and Elementary Particle

    OpenAIRE

    Park, Mu- in

    2001-01-01

    It is shown that elementary black hole can not be distinguished from an elementary particle in the non-commutative space-times (space/space and space/time) at the Planck scale. But, the non-commutative space-times can not be ``directly'' measured in the elementary black hole system. A time-varying non-commutative parameter $\\theta(t)$ is suggested in accordance with the time-varying-G scenario. By identifying the elementary black hole with an elementary particle, the large hierarchy between t...

  18. Effect of the Purple carbon black on the properties of NR/BR blend

    Science.gov (United States)

    Yanfang, Zhao; Dan, Liu; Shengbo, Lin; Binjian; Yinmei, Zhao; Shuangquan, Liao

    2014-08-01

    Purple black is light colored mineral filler mining in recent years in Hainan. The effect of the dosage of the purple carbon black and purple carbon black modificated by Si69 on the vulcanization characteristics, mechanical properties, thermal stability, the damping performance of NR/BR blend rubber were studied, and the blending adhesive tensile sections were analyzed by SEM. Research showed that, with the increasing dosage of the purple carbon black, vulcanization characteristics of NR/BR blend had a little change. Adding the purple carbon black into blending had a reinforcing effect. when the dosage of the purple carbon black was 20, the mechanical properties of blending adhesive was good; Coupling agent Si69 had a modification effect on the purple carbon black. With increasing dosage of Si69, performance of the rubber was improved initially and then decreased; when the mass fraction of Si69 was 8% of the dosage of the purple carbon black, rubber performance was optimal. Purple carbon black had no obvious effect on thermal stability of the rubber, but it improved the damping rubber temperature and damping factor.

  19. Massive Particle Tunnels from the Taub-NUT Black Hole

    Science.gov (United States)

    Chen, D.; Zu, X.; Yang, S.

    2008-06-01

    In this paper, we investigate the Hawking radiation of the Taub-NUT black hole by Hamilton-Jacobi method. When the unfixed background space-time and self-gravitational interaction are considered, the tunnelling rate is related to the change of Bekenstein-Hawking entropy and the radiation spectrum deviates from the purely thermal one. This result is in accordance with Parikh and Wilczek's opinion and gives a correction to the Hawking radiation of the black hole.

  20. The influence of carbon black on curing kinetics and thermal aging of acrylonitrile–butadiene rubber

    Directory of Open Access Journals (Sweden)

    Jaroslava Budinski-Simendić

    2009-10-01

    Full Text Available Elastomers based on a copolymer of butadiene and acrylonitrile (NBR have excellent oil resistance but are very sensitive for degradation at very high temperatures. The aim of this applicative contribution was to determine the effect of high abrasion furnace carbon black with primary particle size 46 nm on aging properties of elastomeric materials based on NBR as network precursor. The curing kinetics was determined using the rheometer with an oscillating disk, in which the network formation process is registered by the torque variation during time. The vulcanizates were obtained in a hydraulic press at 150 °C. The mechanical properties of elastomeric composites were determined before and after thermal aging in an air circulating oven. The reinforcing effect of the filler particles was assessed according to mechanical properties before and after aging.

  1. Black carbon emissions from in-use ships: a California regional assessment

    Directory of Open Access Journals (Sweden)

    G. M. Buffaloe

    2013-09-01

    Full Text Available Black carbon (BC mass emission factors (EFBC; g-BC (kg-fuel−1 from a variety of ocean going vessels have been determined from measurements of BC and carbon dioxide (CO2 concentrations in ship plumes intercepted by the R/V Atlantis during the 2010 California Nexus (CalNex campaign. The ships encountered were all operating within 24 nautical miles of the California coast and were utilizing relatively low sulphur fuels. Black carbon concentrations within the plumes, from which EFBC values are determined, were measured using four independent instruments: a photoacoustic spectrometer and a particle soot absorption photometer, which measure light absorption, and a single particle soot photometer and soot particle aerosol mass spectrometer, which measure the mass concentration of refractory BC directly. The measured EFBC have been divided into vessel type categories and engine type categories, from which averages have been determined. The geometric average EFBC, determined from over 71 vessels and 135 plumes encountered, was 0.31 g-BC (kg-fuel−1. The most frequent engine type encountered was the slow speed diesel (SSD, and the most frequent SSD vessel type was the cargo ship sub-category. Average and median EFBC values from the SSD category are compared with previous observations from the Texas Air Quality Study (TexAQS in 2006, during which the ships encountered were predominately operating on high sulphur fuels. There is a statistically significant difference between the EFBC values from CalNex and TexAQS for SSD vessels and for the cargo and tanker ship types within this engine category. The CalNex EFBC values are lower than those from TexAQS, suggesting that operation on lower sulphur fuels is associated with smaller EFBC values.

  2. Occupational exposure to carbon black in its manufacture.

    Science.gov (United States)

    Gardiner, K; Trethowan, W N; Harrington, J M; Calvert, I A; Glass, D C

    1992-10-01

    Carbon black is manufactured by the vapour phase pyrolysis of heavy aromatic hydrocarbon feedstocks. Its manufacture is worldwide and the majority of its production is for use in the rubber industry especially tyre manufacture. Its carbonaceous nature has led many to investigate the occurrence of exposure-related medical conditions. To quantify any such relationships, it is necessary to assess exposure accurately. As part of such an epidemiological investigation survey involving the measurement both of respirable and of total inhalable carbon black was undertaken in 18 plants in seven European countries between mid-1987 and mid-1989. A total of 1298 respirable samples (SIMPEDS cyclone) and 1317 total inhalable samples (IOM head) were taken and deemed of sufficient quality for inclusion in the study. The distributions of the time-weighted average values were assessed and found to be best described by a log-normal distribution, and so exposure is characterized by geometric means and standard deviations. The data are presented in terms of 13 separate job titles for both dust fractions and shows a wide variation between job titles, with the highest mean exposure experienced by the site cleaners, and 30% of the samples taken from the warehouse packers being in excess of the relevant countries' occupational exposure limits for total inhalable dust. The quality and extent of this data allows both for comparison with exposure standards and for generation of occupational exposure indices, which will be presented in another paper (Gardiner et al., in preparation). PMID:1444068

  3. High Black Carbon (BC) Concentrations along Indian National Highways

    Science.gov (United States)

    Kumar, S.; Singh, A. K.; Singh, R. P.

    2015-12-01

    Abstract:Black carbon (BC), the optically absorbing component of carbonaceous aerosol, has direct influence on radiation budget and global warming. Vehicular pollution is one of the main sources for poor air quality and also atmospheric pollution. The number of diesel vehicles has increased on the Indian National Highways during day and night; these vehicles are used for the transport of goods from one city to another city and also used for public transport. A smoke plume from the vehicles is a common feature on the highways. We have made measurements of BC mass concentrations along the Indian National Highways using a potable Aethalometer installed in a moving car. We have carried out measurements along Varanasi to Kanpur (NH-2), Varanasi to Durgapur (NH-2), Varanasi to Singrauli (SH-5A) and Varanasi to Ghazipur (NH-29). We have found high concentration of BC along highways, the average BC mass concentrations vary in the range 20 - 40 µg/m3 and found high BC mass concentrations up to 600 μg/m3. Along the highways high BC concentrations were characteristics of the presence of industrial area, power plants, brick kilns and slow or standing vehicles. The effect of increasing BC concentrations along the National Highways and its impact on the vegetation and human health will be presented. Key Words: Black Carbon; Aethalometer; mass concentration; Indian National Highways.

  4. Oxidation behavior of a kind of carbon black

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The DTG curves of a kind of carbon black during TPO tests were found to have multiple peaks with an unusual sharp peak after the main peak.TPO tests with different sample loads,oxygen fractions and heating rates were carried out to study the influence of the experimental parameters on the sharp peak.The results show that the sharp peak is not caused by heat and mass transfer limitations,but by the intrinsic oxidation kinetics of the carbon black.The evolution of the specific surface area during the intrinsic kinetic controlled oxidation process was then analyzed using isothermal oxidation at low temperatures which showed that the sharp peak is caused by the increase of the specific surface area.The pore structure changes greatly influence the oxidation process when the reaction is controlled by the intrinsic kinetics.When there were no heat and mass transfer limitations,the different oxidation processes result in the same specific surface area evolution.

  5. Hawking Radiation of Topological Massive Warped-AdS3 Black Holes via Particles Tunnelling

    CERN Document Server

    Gecim, Ganim

    2014-01-01

    We investigate the Dirac and scalar particles tunnelling as a radiation of Warped AdS3 black holes in Topological Massive Gravity. Using Hamilton-Jacobi method, we discuss tunnelling probability and Hawking temperature of the spin-1/2 and spin-0 particles for the black hole. We observe the tunnelling probability and Hawking temperature to be same for the spin-1/2 and spin-0. We also examined the same procedure for the extremal case of the Warped AdS3 black holes, and thus, we show that the tunnelling process may occur, for both Dirac and scalar particles. Furthermore, in the extremal case, we find that the extremal case of the black hole has the Hawking Temperature in the Planck scale and thus it has a surface gravity although it has no surface gravity according to the classical method.

  6. Parikh-Wilczek Tunneling as Massive Particles from Noncommutative Schwarzschild Black Hole

    International Nuclear Information System (INIS)

    In this paper, we apply the tunneling of massive particle through the quantum horizon of a Schwarzschild black hole in noncommutative spacetime. The tunneling effects lead to modified Hawking radiation due to inclusion of back-reaction effects. Our calculations show also that noncommutativity effects cause the further modifications to the thermodynamical relations in black hole. We calculate the emission rate of the massive particles' tunneling from a Schwarzschild black hole which is modified on account of noncommutativity influences. The issues of information loss and possible correlations between emitted particles are discussed. Unfortunately even by considering noncommutativity view point, there is no correlation between different modes of evaporation at least at late-time. Nevertheless, as a result of spacetime noncommutativity, information may be conserved by a stable black hole remnant. (general)

  7. A Black-Hole Primer: Particles, Waves, Critical Phenomena and Superradiant Instabilities

    CERN Document Server

    Berti, Emanuele

    2014-01-01

    These notes were prepared for a lecture on black holes delivered at the DPG Physics School "General Relativity @ 99" (Physikzentrum Bad Honnef, Germany, September 2014). The common thread of the lecture is the relation between geodesic stability and black-hole perturbations in the geometric optics limit. Chapter 1 establishes notation and discusses a common misconception on Michell's "Newtonian black holes". Chapters 2 and 3 deal with particle dynamics and wave dynamics in black-hole spacetimes, respectively. All calculations should be simple enough that they can be done with pen and paper. Chapter 4 builds on this introduction to discuss two exciting topics in current research: critical phenomena in black-hole mergers and the black-hole bomb instability.

  8. Adsorption mechanism of sodium dodecyl benzene sulfonate on carbon blacks by adsorption isotherm and zeta potential determinations.

    Science.gov (United States)

    Zhao, Yapei; Lu, Pei; Li, Caiting; Fan, Xiaopeng; Wen, Qingbo; Zhan, Qi; Shu, Xin; Xu, Tieliang; Zeng, Guangming

    2013-01-01

    Surfactant solutions were propounded to remove fine and hydrophobic carbon black particles from coal-fired flue gas. The adsorption mechanisms between sodium dodecyl benzene sulfonate (SDBS, an anionic surfactant) and carbon black particles in suspension were investigated. The influence of inorganic salt (NaCl) was also considered. As results showed, hydrophobic interactions contributed to the strong adsorption between SDBS and carbon black particles in the absence of NaCl, and adding NaCl affected the adsorption process. The adsorption amount of SDBS significantly increased when NaCl was added into the SDBS solution; however, when SDBS was in low concentration, the amount of adsorbed SDBS, which was responsible for the shift of zeta potentials, varied little under different concentrations of NaCl. This indicated that the adsorption of SDBS was mainly caused by hydrophobic interaction and Na+ could not change the adsorption of SDBS on adsorption site when SDBS was in low concentration. Moreover, the adsorbed SDBS and Na+ were retained in the Stern layer. PMID:23530331

  9. Novel synthesis and electrophoretic response of low density TiO-TiO2-carbon black composite

    International Nuclear Information System (INIS)

    Novel low density TiO-TiO2-carbon black composite was synthesized, which involved the deposition of inorganic coating on the surface of core-shell latex particles and subsequent removal of latex particles by calcination in high-purity nitrogen. The morphology and interior structure were characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The images exhibited the composite had spherical shape and smooth surface, and the interior structure was hollow or porous. X-ray diffraction peaks (XRD) were mostly in agreement with the standard diffraction patterns of rutile TiO2. In addition, the observed peaks at 2θ of 43.5 deg., 50.6 deg. and 74.4 deg. can be indexed to (1 1 1), (2 0 0) and (2 2 0) planes of cubic phase TiO. The X-ray photoelectron spectroscopy (XPS) results indicated that composite consisted of carbon black, TiO and TiO2. The apparent density of the composite was suitable to 1.62 g cm-3, due to density matching with suspending media. Glutin-arabic gum microcapsules containing TiO-TiO2-carbon black composite electrophoretic liquid were prepared via complex coacervation. The particles in the microcapsules showed excellent electrophoretic mobility under a DC field.

  10. Quantum Thermal Effect of Dirac Particles in a Non-Uniformly Rectilinearly Accelerating Kinnersley Black Hole

    Institute of Scientific and Technical Information of China (English)

    吴双清; 蔡勖

    2002-01-01

    We study the Hawking radiation of Dirac particles in an arbitrarily rectilinearly accelerating Kinnersley black hole, using the generalized tortoise coordinate transformation method. Both the location and the temperature of the event horizon depend on the time and polar angle. The Hawking thermal radiation spectrum of Dirac particles is also derived.

  11. Quantum Thermal Effect of Dirac Particles in a Non-uniformly Rectilinearly Accelerating Kinnersley Black Hole

    CERN Document Server

    Shuang-Qing, W; Shuang-Qing, Wu; Xu, Cai

    2002-01-01

    The Hawking radiation of Dirac particles in an arbitrarily rectilinearly accelerating Kinnersley black hole is studied by using a method of the generalized tortoise coordinate transformation. Both the location and the temperature of the event horizon depend on the time and the polar angle. The Hawking thermal radiation spectrum of Dirac particles is also derived.

  12. Tunnelling of scalar and Dirac particles from squashed charged rotating Kaluza-Klein black holes

    CERN Document Server

    Stetsko, M M

    2014-01-01

    Thermal radiation of scalar particles and Dirac fermions from squashed charged rotating five-dimensional black holes is considered. To obtain temperature of the black holes we use the tunnelling method. In case of scalar particles we make use of the Hamilton-Jacobi equation. To consider tunnelling of fermions the Dirac equation was investigated. The examination shows that radial parts of the action for scalar particles and fermions in quasi-classical limit in the vicinity of horizon are almost the same and as a consequence it gives rise to the identical expressions for the temperature in both cases.

  13. On particles tunneling from the Taub-NUT-AdS black hole

    Institute of Scientific and Technical Information of China (English)

    Zeng Xiao-Xiong; Li Qiang

    2009-01-01

    This paper discusses tunneling of scalar particles and Dirac particles from the Taub-NUT-AdS black hole by the Hamilton-Jacobi equation, initially used by Angheben et al, and the Dirac equation, recently proposed by Kerner and Mann. This is performed in the dragging coordinate frame so as to avoid the ergosphere dragging effect. A general form is obtained for the temperature of scalar and Dirac particles tunneling from the Taub-NUT-Ads black hole, which is commensurate with other methods as expected.

  14. GENERAL: On particles tunneling from the Taub-NUT-AdS black hole

    Science.gov (United States)

    Zeng, Xiao-Xiong; Li, Qiang

    2009-11-01

    This paper discusses tunneling of scalar particles and Dirac particles from the Taub-NUT-AdS black hole by the Hamilton-Jacobi equation, initially used by Angheben et al, and the Dirac equation, recently proposed by Kerner and Mann. This is performed in the dragging coordinate frame so as to avoid the ergosphere dragging effect. A general form is obtained for the temperature of scalar and Dirac particles tunneling from the Taub-NUT-Ads black hole, which is commensurate with other methods as expected.

  15. Tunnelling of scalar and Dirac particles from squashed charged rotating Kaluza-Klein black holes

    Energy Technology Data Exchange (ETDEWEB)

    Stetsko, M.M. [Ivan Franko National University of Lviv, Department of Theoretical Physics, Lviv (Ukraine)

    2016-02-15

    The thermal radiation of scalar particles and Dirac fermions from squashed charged rotating five-dimensional black holes is considered. To obtain the temperature of the black holes we use the tunnelling method. In the case of scalar particles we make use of the Hamilton-Jacobi equation. To consider tunnelling of fermions the Dirac equation was investigated. The examination shows that the radial parts of the action for scalar particles and fermions in the quasi-classical limit in the vicinity of horizon are almost the same and as a consequence it gives rise to identical expressions for the temperature in the two cases. (orig.)

  16. Tunnelling of scalar and Dirac particles from squashed charged rotating Kaluza-Klein black holes

    Science.gov (United States)

    Stetsko, M. M.

    2016-02-01

    The thermal radiation of scalar particles and Dirac fermions from squashed charged rotating five-dimensional black holes is considered. To obtain the temperature of the black holes we use the tunnelling method. In the case of scalar particles we make use of the Hamilton-Jacobi equation. To consider tunnelling of fermions the Dirac equation was investigated. The examination shows that the radial parts of the action for scalar particles and fermions in the quasi-classical limit in the vicinity of horizon are almost the same and as a consequence it gives rise to identical expressions for the temperature in the two cases.

  17. Sources of uncertainties in modelling black carbon at the global scale

    NARCIS (Netherlands)

    Vignati, E.; Karl, M.; Krol, M.C.; Wilson, J.; Stier, P.; Cavalli, F.

    2010-01-01

    Our understanding of the global black carbon (BC) cycle is essentially qualitative due to uncertainties in our knowledge of its properties. This work investigates two source of uncertainties in modelling black carbon: those due to the use of different schemes for BC ageing and its removal rate in th

  18. Carbon black nanoparticle instillation induces sustained inflammation and genotoxicity in mouse lung and liver

    DEFF Research Database (Denmark)

    Bourdon, Julie A; Saber, Anne T; Jacobsen, Nicklas R;

    2012-01-01

    Widespread occupational exposure to carbon black nanoparticles (CBNPs) raises concerns over their safety. CBNPs are genotoxic in vitro but less is known about their genotoxicity in various organs in vivo.......Widespread occupational exposure to carbon black nanoparticles (CBNPs) raises concerns over their safety. CBNPs are genotoxic in vitro but less is known about their genotoxicity in various organs in vivo....

  19. Hawking radiation as tunneling of vector particles from Kerr-Newman black hole

    Science.gov (United States)

    Ibungochouba Singh, T.; Ablu Meitei, I.; Yugindro Singh, K.

    2016-03-01

    In this paper, by applying the WKB approximation and Hamilton-Jacobi ansatz to the Proca equation, we investigate the tunneling of vector bosons across the event horizon of Kerr-Newman black hole and also the resulting vector particles' Hawking radiation. Universality of the properties of the emitted spectra of different types of particles is established for Kerr-Newman black hole. The coordinate problem for Hawking radiation of the vector particles is also investigated using three coordinate systems. The thermal spectrum of the radiated vector bosons determined using a direct computation corresponds to a temperature which is twice the Hawking temperature of Kerr-Newman black hole for scalar particles. If the well behaved Eddington coordinate system and Painleve coordinate system are used, the correct result of Hawking temperature is obtained. The reason for the discrepancy in the results of naive coordinate and well behaved coordinates is also discussed.

  20. Isotopic composition of carbon-13 and oxygen-18 from authigenic carbonates, Black Sea region

    Science.gov (United States)

    Logvina, E.; Mazurenko, L.; Prasolov, E.

    2004-05-01

    Several types of authigenic carbonates related to the fluid discharge zones were sampled during the international expeditions onboard R/V "Professor Vodyanitskiy" (56th cruise) and R/V "Professor Logachev" (11th cruise of UNESCO-TTR) in the northwest part of the Black sea. These carbonates are represented as mounds, build-ups and chimney-like structures, cemented sediments, crusts and concretions. The isotope analyses of carbonates were conducted using mass-spectrometer MS-20 in the Laboratory of Isotope Geology (St.Petersburg State University). The obtained values of oxygen-18 varied from +0,6 to -1,9 per mille (up to C0.8 per mille on average). This value is corresponding to normal seawater oxygen-18 value (about 0 per mille); we suspect, that the source of oxygen for carbonate formation is the seawater. The carbonates are characterized by low carbon-13 (from -35,4 to -42,6 per mille) in comparison with normal marine carbonates (about 0 per mille). We have reason to suppose that carbonates associated with fluid venting were formed by light isotopic composition of carbon dioxide (carbon-13 -45 to -52 per mille), which forming under methane microbiologic oxidation with such isotopic composition. This is because of crossing fluid process of carbon dioxide to carbonate with 8~10 degrees temperature carbon became heaver to 10- 11 per mille. The isotopic composition study of carbonate build-ups is of interest because its association with the gas hydrate accumulations is quite often in the gas seeps. This work is financially supported by Russian Foundation for Basic Research, grant 02-05-64346.

  1. Toughening of polypropylene with calcium carbonate particles

    NARCIS (Netherlands)

    Zuiderduin, W.C.J.; Westzaan, C.; Huetink, J.; Gaymans, R.J.

    2003-01-01

    Polypropylene–CaCO3 composites were prepared on a twin screw extruder with a particle content of 0–32 vol%. The influence of particle size (0.07–1.9 μm) and surface treatment of the particles (with and without stearic acid) on the toughening properties were studied. The matrix molecular weight of th

  2. Accelerated ageing of an EAF black slag by carbonation and percolation for long-term behaviour assessment.

    Science.gov (United States)

    Gurtubay, L; Gallastegui, G; Elias, A; Rojo, N; Barona, A

    2014-07-01

    The efficient reuse of industrial by-products, such as the electric arc furnace (EAF) black slag, is still hindered by concern over their long-term behaviour in outdoor environments. The aim of this study was to develop an accelerated ageing method to simulate the long-term natural carbonation of EAF slag exposed to the elements. The degree of carbonation achieved in a freshly produced slag after accelerated ageing and in a slag used on a fifteen-year-old unpaved road was very similar. The influence of particle size on accelerated carbonation was assessed, with it being concluded that the slag sample with a particle size bigger than 5-6 mm underwent slight carbonation over time when it was exposed to CO2. The accelerated ageing procedure based on percolating a previously carbonated water solution through the slag column allowed gradual leaching with simulated acid rain, as well as providing information about the gradual and total chemical release from the slag. Three classification groups were established according to the release rate of the determined elements. The joint use of the accelerated carbonation method and the percolation test is proposed as a useful tool for environmental risk assessment concerning the long-term air exposure of EAF black slag.

  3. Distinguishing black carbon from biogenic humic substances in soil clay fractions

    Science.gov (United States)

    Laird, D.A.; Chappell, M.A.; Martens, D.A.; Wershaw, R. L.; Thompson, M.

    2008-01-01

    Most models of soil humic substances include a substantial component of aromatic C either as the backbone of humic heteropolymers or as a significant component of supramolecular aggregates of degraded biopolymers. We physically separated coarse (0.2-2.0????m e.s.d.), medium (0.02-0.2????m e.s.d.), and fine (> 0.02????m e.s.d.) clay subfractions from three Midwestern soils and characterized the organic material associated with these subfractions using 13C-CPMAS-NMR, DTG, SEM-EDX, incubations, and radiocarbon age. Most of the C in the coarse clay subfraction was present as discrete particles (0.2-5????m as seen in SEM images) of black carbon (BC) and consisted of approximately 60% aromatic C, with the remainder being a mixture of aliphatic, anomeric and carboxylic C. We hypothesize that BC particles were originally charcoal formed during prairie fires. As the BC particles aged in soil their surfaces were oxidized to form carboxylic groups and anomeric and aliphatic C accumulated in the BC particles either by adsorption of dissolved biogenic compounds from the soil solution or by direct deposition of biogenic materials from microbes living within the BC particles. The biogenic soil organic matter was physically separated with the medium and fine clay subfractions and was dominated by aliphatic, anomeric, and carboxylic C. The results indicate that the biogenic humic materials in our soils have little aromatic C, which is inconsistent with the traditional heteropolymer model of humic substances.

  4. Small-angle scattering, contrast variation and the study of complex composite materials: A study of the structure of carbon black

    International Nuclear Information System (INIS)

    Detailed studies are presented on the structure and aggregation of an experimental high surface area carbon black (HSA) using small-angle neutron scattering and the method of contrast variation. We find that the approximately 27 mn HSA particle form small, linear aggregates of average aggregation number 5 when suspended in cyclohexane. There is considerable density fluctuation in the interior of these particles, with the denser regions being toward the outer part of the spherically-averaged structure. This information would not have been obtained from studies of carbon black without solvent. The results will be applied to similar scattering studies on solvent-swollen bound rubber gels made from HSA-polyisoprene. These result show, however, that the strong internal fluctuations of the carbon black will limit the information that can be obtained on the structure and conformation of the elastomer in the gel. There are additional limitation from compositional heterogeneity of the sample

  5. Light Absorption in Arctic Sea Ice - Black Carbon vs Chlorophyll

    Science.gov (United States)

    Ogunro, O. O.; Wingenter, O. W.; Elliott, S.; Hunke, E. C.; Flanner, M.; Wang, H.; Dubey, M. K.; Jeffery, N.

    2015-12-01

    The fingerprint of climate change is more obvious in the Arctic than any other place on Earth. This is not only because the surface temperature there has increased at twice the rate of global mean temperature but also because Arctic sea ice extent has reached a record low of 49% reduction relative to the 1979-2000 climatology. Radiation absorption through black carbon (BC) deposited on Arctic snow and sea ice surface is one of the major hypothesized contributors to the decline. However, we note that chlorophyll-a absorption owing to increasing biology activity in this region could be a major competitor during boreal spring. Modeling of sea-ice physical and biological processes together with experiments and field observations promise rapid progress in the quality of Arctic ice predictions. Here we develop a dynamic ice system module to investigate discrete absorption of both BC and chlorophyll in the Arctic, using BC deposition fields from version 5 of Community Atmosphere Model (CAM5) and vertically distributed layers of chlorophyll concentrations from Sea Ice Model (CICE). To this point, our black carbon mixing ratios compare well with available in situ data. Both results are in the same order of magnitude. Estimates from our calculations show that sea ice and snow around the Canadian Arctic Archipelago and Baffin Bay has the least black carbon absorption while values at the ice-ocean perimeter in the region of the Barents Sea peak significantly. With regard to pigment concentrations, high amounts of chlorophyll are produced in Arctic sea ice by the bottom microbial community, and also within the columnar pack wherever substantial biological activity takes place in the presence of moderate light. We show that the percentage of photons absorbed by chlorophyll in the spring is comparable to the amount attributed to BC, especially in areas where the total deposition rates are decreasing with time on interannual timescale. We expect a continuous increase in

  6. SP2 Deployment at Boston College—Aerodyne-Led Coated Black Carbon Study (BC4) Final Campaign Summary

    Energy Technology Data Exchange (ETDEWEB)

    Onasch, T. B. [Aerodyne Research, Inc., Billerica, MA (United States); Sedlacek, A. J. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2016-03-01

    The main objective of the Boston College-Aerodyne led laboratory study (BC4) was to measure the optical properties of black carbon (BC) particles from a diffusion flame directly and after being coated with secondary organic and inorganic material and to achieve optical closure with model predictions. The measurements of single particle BC mass and population mixing states provided by a single particle soot photometer (SP2) was central to achieving the laboratory-based study’s objective. Specifically, the DOE ARM SP2 instrument participated in the BC4 project to address the following scientific questions: 1. What is the mass-specific absorption coefficient as a function of secondary organic and inorganic material coatings? 2. What is the spread in the population mixing states within our carefully generated laboratory particles? 3. How does the SP2 instrument respond to well-characterized, internally mixed BC-containing particles?

  7. Brief Analysis on the Production & Operation Situation of Chinese Carbon Black Industry in the First Half Year

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    At present, there are about 120 carbon black manufacturing enterprises in China with the production capacity of 3.41 million tons, accounting for 78% of the total production capacity of the country, in which there are 31 carbon black enterprises with the production capacity of over 50,000 tons. Compared with the international carbon black industry, our carbon black industry has a low intensification.

  8. Absorption probabilities associated with spin-3/2 particles near $N$-dimensional Schwarzschild black holes

    CERN Document Server

    Harmsen, G E; Cho, H T; Cornell, A S

    2016-01-01

    In June 2015 the Large Hadron Collider was able to produce collisions with an energy of 13TeV, where collisions at these energy levels may allow for the formation of higher dimensional black holes. In order to detect these higher dimensional black holes we require an understanding of their emission spectra. One way of determining this is by looking at the absorption probabilities associated with the black hole. In this proceedings we will look at the absorption probability for spin-3/2 particles near $N$-dimensional Schwarzschild black holes. We will show how the Unruh method is used to determine these probabilities for low energy particles. We then use the Wentzel-Kramers-Brillouin approximation in order to determine these absorption probabilities for the entire possible energy range.

  9. Electrical properties of foamed polypropylene/carbon black composites

    Science.gov (United States)

    Iliev, M.; Kotzev, G.; Vulchev, V.

    2016-02-01

    Polypropylene composites containing carbon black fillers were produced by vibration assisted extrusion process. Solid (unfoamed) composite samples were molded by conventional injection molding method, while structural foams were molded by a low pressure process. The foamed samples were evidenced to have a solid skin-foamed core structure which main parameters were found to depend on the quantity of material injected in the mold. The average bubbles' sizes and their distribution were investigated by scanning electron microscopy. It is established that the conductivity of the foamed samples gradually decreases when reducing the sample density. Nevertheless, the conductivity is found to be lower than the conductivity of the unfoamed samples both being of the same order. The flexural properties of the composites were studied and the results were discussed in the context of the structure parameters of the foamed samples.

  10. Black Carbon Vertical Profiles Strongly Affect its Radiative Forcing Uncertainty

    Energy Technology Data Exchange (ETDEWEB)

    Samset, B. H.; Myhre, G.; Schulz, M.; Balkanski, Y.; Bauer, Susanne E.; Berntsen, T.; Bian, Huisheng; Bellouin, N.; Diehl, T.; Easter, Richard C.; Ghan, Steven J.; Iversen, T.; Kinne, Stefan; Kirkevag, A.; Lamarque, J.-F.; Lin, G.; Liu, Xiaohong; Penner, Joyce E.; Seland, O.; Skeie, R. B.; Stier, P.; Takemura, T.; Tsigaridis, K.; Zhang, Kai

    2013-03-01

    The impact of black carbon (BC) aerosols on the global radiation balance is not well constrained. Here twelve global aerosol models are used to show that at least 20% of the present uncertainty in modeled BC direct radiative forcing (RF) is due to diversity in the simulated vertical profile of BC mass. Results are from phases 1 and 2 of the global aerosol model intercomparison project (AeroCom). Additionally, a significant fraction of the variability is shown to come from high altitudes, as, globally, more than 40% of the total BC RF is exerted above 5 km. BC emission regions and areas with transported BC are found to have differing characteristics. These insights into the importance of the vertical profile of BC lead us to suggest that observational studies are needed to better characterize the global distribution of BC, including in the upper troposphere.

  11. Massive vector particles tunneling from black holes influenced by the generalized uncertainty principle

    CERN Document Server

    Li, Xiang-Qian

    2016-01-01

    Considering the generalized uncertainty principle which incorporates the central idea of Large eXtra Dimensions, the processes of massive spin-1 particles tunneling from Reissner-Nordstrom and Kerr black holes are investigated. For the black hole, the quantum gravity correction decelerates the increase of the temperature. When the mass of the black hole approaches the order of the higher dimensional Planck mass $M_f$, it stops radiating and leads to a black hole remnant. To $\\mathcal{O}(\\frac{1}{M_f^2})$, the corrected temperatures are affected by the mass and angular momentum of emitted vector bosons. Meanwhile, the temperature of the Kerr black hole becomes uneven due to the rotation.

  12. Particle tunnels across the horizon of Garfinkle-Horowitz-Strominger dilaton black hole

    Institute of Scientific and Technical Information of China (English)

    FANG; HengZhong

    2007-01-01

    We promote the work of Parikh and Wilczek on the black hole radiation to the emission of massive and charged particles from Garfinkle-Horowitz-Strominger black hole. The energy and charge of the space-time are conservational during the course of the evaporation. The calculation shows that the emission spectrum is not precisely thermal, while has a correction, and the conclusion supports the viewpoint of information conservation.

  13. Analytical solutions in rotating linear dilaton black holes: Hawking radiation of charged massive scalar particles

    OpenAIRE

    Sakalli, I.

    2016-01-01

    Hawking radiation of charged massive spin-0 particles are studied in the gravitational, electromagnetic, dilaton, and axion fields of rotating linear dilaton black holes. In this geometry, we separate the covariant Klein--Gordon equation into radial and angular parts and obtain the exact solutions of both the equations in terms of the confluent Heun functions. Using the radial solution, we analyze the behavior of the wave solutions near the event horizon of the rotating linear dilaton black h...

  14. Sources of uncertainties in modelling Black Carbon at the global scale

    Directory of Open Access Journals (Sweden)

    F. Cavalli

    2009-11-01

    Full Text Available Our understanding of the global black carbon cycle is essentially qualitative due to uncertainties in our knowledge of the properties of black carbon. This work investigates uncertainties related to modelling black carbon: due to the use of different schemes for BC ageing and its removal rate in the global Transport-Chemistry model TM5 and due to the uncertainties in the definition and quantification of observed black carbon, which propagate through to both the emission inventories, and the measurements used for the model evaluation.

    The schemes for the atmospheric processing of black carbon that have been tested with the model are (i a simple approach considering black carbon as bulk aerosol and a simple treatment in the removal and (ii a more complete description of microphysical aging within an aerosol dynamics model, where removal is coupled to the microphysical properties of the aerosol. In the first approach a fixed 70% of black carbon is scavenged in clouds and removed when rain is present. The second leads to a global average of 40% black carbon that is scavenged in clouds and subsequently removed by rain, thus resulting in a longer lifetime. This difference is reflected in comparisons between both sets of modelled results and the measurements. Close to the sources, both anthropogenic and vegetation fire source regions, the model results do not differ significantly, showing that the emissions are the prevailing mechanism determining the concentrations and the choice of the aerosol scheme does not influence the levels. In more remote areas such as oceanic and polar regions the differences can be orders of magnitude, due to the differences between the two schemes. The more complete description reproduces the seasonal trend of the black carbon observations in those areas, although not always the magnitude of the signal, while the more simplified approach underestimates black carbon concentrations by orders of magnitude.

  15. Continuous flux of dissolved black carbon from a vanished tropical forest biome

    Science.gov (United States)

    Dittmar, Thorsten; de Rezende, Carlos Eduardo; Manecki, Marcus; Niggemann, Jutta; Coelho Ovalle, Alvaro Ramon; Stubbins, Aron; Bernardes, Marcelo Correa

    2012-09-01

    Humans have used fire extensively as a tool to shape Earth's vegetation. The slash-and-burn destruction of Brazil's Atlantic forest, which once covered over 1.3millionkm2 of present-day Brazil and was one of the largest tropical forest biomes on Earth, is a prime example. Here, we estimate the amount of black carbon generated by the burning of the Atlantic forest, using historical records of land cover, satellite data and black carbon conversion ratios. We estimate that before 1973, destruction of the Atlantic forest generated 200-500 million tons of black carbon. We then estimate the amount of black carbon exported from this relict forest between 1997 and 2008, using measurements of polycyclic aromatic black carbon collected from a large river draining the region, and a continuous record of river discharge. We show that dissolved black carbon (DBC) continues to be mobilized from the watershed each year in the rainy season, despite the fact that widespread forest burning ceased in 1973. We estimate that the river exports 2,700 tons of DBC to the ocean each year. Scaling our findings up, we estimate that 50,000-70,000 tons of DBC are exported from the former forest each year. We suggest that an increase in black carbon production on land could increase the size of the refractory pool of dissolved organic carbon in the deep ocean.

  16. Effect of antioxidant on PTC properties of conductive carbon black/polyethylene composites

    International Nuclear Information System (INIS)

    Complete text of publication follows. Carbon black (CB)-filled high-density polyethylene (HDPE) composites have been used as self resetting fuse for a number of years. The main features of the positive temperature coefficient (PTC) materials are affected by crystallinity of the polymer. The crystallinity of the polymer is changed with thermal treatment. The HDPE/CB composites should be resistant to the severe conditions of high temperature. HDPE with a melt index of 0.35 was selected as the polymer matrix in this work. Carbon black with an average particle size of 86 nm was used. The CB and polymer were mixed in a Brabender Plastograph at 160 deg C for 15 min. The CB/polymer blend thus produced was sandwiched between a pair of copper foils (0.04 mm thick), that served as electrodes. Thermal aging of PTC samples was conducted in an oven at range from 50 deg C to 140 deg C in air. The composites containing 0.5 - 3wt% of Irganox as antioxidant were irradiated under nitrogen at room temperature with different doses of gamma rays from a Co60 source. The conductive composites with thermal aging treatment have the lower resistivity. The reproducibility of the conductive composites depended on the amount of antioxidants

  17. Contribution of regional transport to the black carbon aerosol during winter haze period in Beijing

    Science.gov (United States)

    Wang, Qiyuan; Huang, Ru-Jin; Cao, Junji; Tie, Xuexi; Shen, Zhenxing; Zhao, Shuyu; Han, Yongming; Li, Guohui; Li, Zhengqiang; Ni, Haiyan; Zhou, Yaqing; Wang, Meng; Chen, Yang; Su, Xiaoli

    2016-05-01

    The mass concentrations of atmospheric refractory black carbon (rBC), an important absorber of solar radiation, were continuously measured with a single particle soot photometer (SP2) during wintertime haze period to investigate the transport of pollution to Beijing. The average mass concentration of rBC was 6.1 ± 3.9 μg m-3 during hazy periods, which was 4.7 times higher than it during non-hazy periods. Cluster analysis showed that the air parcels arriving at Beijing mainly originated from the northwest, passed through the south and brought the most polluted air to Beijing. Concentration-weighted trajectory analyses indicated that the central North China Plain were the most likely source region for the rBC that impacted Beijing. Furthermore, the Weather Research and Forecasting-Black Carbon model showed that 71.4-82.0% of the rBC at Beijing was from regional transport during the high rBC episodes and that 47.9-56.8% of the rBC can be attributed to sources in the central North China Plain. These results suggest that regional transport from the central North China Plain, rather than local emissions, was a more important source for rBC pollution in Beijing.

  18. Nature of Microscopic Black Holes and Gravity in Theories with Particle Species

    Science.gov (United States)

    Dvali, Gia

    2010-01-01

    Relying solely on unitarity and the consistency with large-distance black hole physics, we derive model-independent properties of the microscopic black holes and of short-distance gravity in theories with N particle species. In this class of theories black holes can be as light as MPlanck /√ N and be produced in particle collisions above this energy. We show, that the micro black holes must come in the same variety as the species do, although their label is not associated with any conserved charge measurable at large distances. In contrast with big Schwarzschildian ones, the evaporation of the smallest black holes is maximally undemocratic and is biased in favor of particular species. With an increasing mass the democracy characteristic to the usual macro black holes is gradually regained. The lowest possible mass above which black holes become Einsteinian is √ N MPlanck . This fact uncovers the new fundamental scale (below the quantum gravity scale) above which gravity changes classically, and the properties of black holes and gravity are such as if some extra dimensions open up, although no such input exists in the theory. Our observations indicate that geometry of space may be an emergent concept following from large number of species and the consistency with macro black hole physics. We apply our findings to the phenomenological properties of the micro black holes that can be observed at LHC for large N. Extrapolating our findings to small N, one may ask whether the existence of quark and lepton flavors is already an evidence for emergent extra dimensions at short distances.

  19. Black and brown carbon fractal aggregates from combustion of two fuels widely used in Asian rituals

    International Nuclear Information System (INIS)

    Incense sticks and mustard oil are the two most popular combustion fuels during rituals and social ceremonies in Asian countries. Given their widespread use in both closed and open burning activities, it is important to quantify the spectral radiative properties of aerosols emitted from the combustion of both fuels. This information is needed by climate models to assess the impact of these aerosols on radiative forcing. In this study, we used a 3-wavelength integrated photoacoustic-nephelometer – operating simultaneously at 405, 532 and 781 nm – to measure the optical coefficients of aerosols emitted from the laboratory combustion of mustard oil lamp and two types of incense sticks. From the measured optical coefficients at three wavelengths, time-varying single scattering albedo (SSA), absorption Ångström exponent (AAE), and scattering Ångström exponent (SAE) were calculated. For incense smoke particles, the time-averaged mean AAE values were found to be as high as 8.32 (between 405 and 532 nm) and 6.48 (between 532 and 781 nm). This spectrally-varying characteristic of AAE indicates that brown carbon – a class of organic carbon which strongly absorbs solar radiation in the blue and near ultraviolet – is the primary component of incense smoke aerosols. For aerosols emitted from the burning of mustard oil lamp, the time-averaged mean AAE values were ∼1.3 (between 405 and 781 nm) indicating that black carbon (BC) is the primary constituent. Scanning electron microscopy combined with image processing revealed the morphology of incense smoke aerosols to be non-coalescing and weakly-bound aggregates with a mean two-dimensional (2-d) fractal dimension (Df)=1.9±0.07, while the mustard oil smoke aerosols had typical fractal-like BC aggregate morphology with a mean 2-d Df=1.85±0.09. -- Highlights: ► Incense and mustard oil burning aerosols characterized by 3-wavelength photoacoustic spectroscopy and nephelometery, and electron microscopy. ► Brown carbon

  20. Schwarzschild black hole embedded in a dust field: scattering of particles and drag force effects

    Science.gov (United States)

    Bini, Donato; Geralico, Andrea

    2016-06-01

    A ‘temporal analogue’ of the standard Poynting–Robertson effect is analyzed as induced by a dust of particles (instead of a gas of photons) surrounding a Schwarzschild black hole. Test particles inside this cloud undergo acceleration effects due to the presence of a friction force, so that the fate of their evolution can be completely different from the corresponding geodesic motion. Typical situations are discussed of hyperbolic motion of particles scattered by the black hole in the presence of a dust filling the whole spacetime region outside the horizon as well as particles which free fall radially crossing a corona located at a certain distance from the horizon. The existence of equilibrium orbits may prevent particles from either falling into the hole or escaping to infinity.

  1. Nature of Microscopic Black Holes and Gravity in Theories with Particle Species

    CERN Document Server

    Dvali, Gia

    2010-01-01

    Relying solely on unitarity and the consistency with large-distance black hole physics, we derive model-independent properties of the microscopic black holes and of short-distance gravity in theories with N particle species. In this class of theories black holes can be as light as M_{Planck}/\\sqrt{N} and be produced in particle collisions above this energy. We show, that the micro black holes must come in the same variety as the species do, although their label is not associated with any conserved charge measurable at large distances. In contrast with big Schwarzschildian ones, the evaporation of the smallest black holes is maximally undemocratic and is biased in favor of particular species. With an increasing mass the democracy characteristic to the usual macro black holes is gradually regained. The lowest possible mass above which black holes become Einsteinian is \\sqrt{N} M_{Planck}. This fact uncovers the new fundamental scale (below the quantum gravity scale) above which gravity changes classically, and ...

  2. Black carbon as a carbon source for young soils in a glacier forefield?

    Science.gov (United States)

    Eckmeier, E.; Pichler, B.; Krebs, R.; Mavris, C.; Egli, M.

    2012-04-01

    Most evident changes in Alpine soils today occur in proglacial areas where existing young soils are continuously developing. Due to climate change, additional areas will become ice-free and subject to weathering and new soil formation. The glacier forefields of the European Alps are continuously exposed since the glaciers reached their maximum expansion in the 1850s. In these proglacial areas, initial soils have started to develop so that they may offer, under optimal conditions, a continuous chronosequence from 0 to 150 year-old soils. The buildup of organic carbon (Corg) in soil is an important factor controlling weathering and the formation of soils. Not only autochthonous but also distant (allochthonous) sources may contribute to the accumulation of soil organic carbon in young soils and surfaces of glacier forefields. Black carbon could be an important component in Alpine soils. However, only little is known about black carbon in very young soils that develop in glacier forefields. The aim of our study was to examine whether black carbon as an allochthonous source of soil organic matter can be detected in the initial soils, and to estimate its relative contribution (as a function of time) to total organic carbon. We investigated surface soil samples (topsoils, A or AO horizon) from 35 sites distributed over the whole proglacial area of Morteratsch, where ideal conditions for a soil chronosequence from 0 to 150 years can be found. Along this sequence, bare till sediments to weakly developed soils (Leptosols) can be encountered. Black carbon concentrations were determined in fine-earth using the benzene polycarboxylic acid (BPCA) marker method as described by Brodowski et al. (2005). We found that the proportion of BPCA-C to total Corg was related to the time since the surface was exposed. The youngest soils (younger than 40 years) contained the highest proportion of BPCA-C (up to 120 g BPCA-C/kg Corg). In these soils, however, the Corg concentrations were very

  3. Automatic Method for Controlling the Iodine Adsorption Number in Carbon Black Oil Furnaces

    OpenAIRE

    Zečević, N.

    2008-01-01

    There are numerous of different inlet process factors in carbon black oil furnaces which must be continuously and automatically adjusted, due to stable quality of final product. The most important six inlet process factors in carbon black oil-furnaces are:1. volume flow of process air for combustion2. temperature of process air for combustion3. volume flow of natural gas for insurance the necessary heat for thermal reaction of conversionthe hydrocarbon oil feedstock in oil-furnace carbon blac...

  4. Tunneling of Massive Vector Particles From Rotating Charged Black Strings

    OpenAIRE

    Jusufi, Kimet; Övgün, Ali

    2016-01-01

    We study the quantum tunneling of charged massive vector bosons from a charged static and a rotating black string. We apply the standard methods, first we use the WKB approximation and the Hamilton-Jacobi equation, and then we end up with a set of four linear equations. Finally, solving for the radial part by using the determinant of the metric equals zero, the corresponding tunneling rate and the Hawking temperature is recovered in both cases. The tunneling rate deviates from pure thermality...

  5. Charged Particle Tunnels from the Einstein-Maxwell Black Hole

    Science.gov (United States)

    Chen, Deyou; Yang, Shuzheng

    Considering the self-gravitation interaction and the unfixed background space-time, we study the Hawking radiation of the Einstein-Maxwell-Dilaton-Axion (EMDA) black hole by the radial geodesic method and the Hamilton-Jacobi method. Both sets of results agree with Parikh and Wilczek's and show that the actual radiation spectrum deviates from the purely thermal one and the tunneling probability is related to the change of Bekenstein-Hawking entropy, which satisfies an underlying unitary theory.

  6. Carbon black dispersion pre-plating technology for printed wire board manufacturing. Final technology evaluation report

    Energy Technology Data Exchange (ETDEWEB)

    Folsom, D.W.; Gavaskar, A.R.; Jones, J.A.; Olfenbuttel, R.F.

    1993-10-01

    The project compared chemical use, waste generation, cost, and product quality between electroless copper and carbon-black-based preplating technologies at the printed wire board (PWB) manufacturing facility of McCurdy Circuits in Orange, CA. The carbon-black based preplating technology evaluated is used as an alternative process for electroless copper (EC) plating of through-holes before electrolytic copper plating. The specific process used at McCurdy is the BlackHole (BH) technology process, which uses a dispersion of carbon black in an aqueous solution to provide a conductive surface for subsequent electrolytic copper plating. The carbon-black dispersion technology provided effective waste reduction and long-term cost savings. The economic analysis determined that the new process was cost efficient because chemical use was reduced and the process proved more efficient; the payback period was less than 4 yrs.

  7. Markedly enhanced absorption and direct radiative forcing of black carbon under polluted urban environments

    Science.gov (United States)

    Peng, Jianfei; Hu, Min; Guo, Song; Du, Zhuofei; Zheng, Jing; Shang, Dongjie; Levy Zamora, Misti; Zeng, Limin; Shao, Min; Wu, Yu-Sheng; Zheng, Jun; Wang, Yuan; Glen, Crystal R.; Collins, Donald R.; Molina, Mario J.

    2016-04-01

    Black carbon (BC) exerts profound impacts on air quality and climate because of its high absorption cross-section over a broad range of electromagnetic spectra, but the current results on absorption enhancement of BC particles during atmospheric aging remain conflicting. Here, we quantified the aging and variation in the optical properties of BC particles under ambient conditions in Beijing, China, and Houston, United States, using a novel environmental chamber approach. BC aging exhibits two distinct stages, i.e., initial transformation from a fractal to spherical morphology with little absorption variation and subsequent growth of fully compact particles with a large absorption enhancement. The timescales to achieve complete morphology modification and an absorption amplification factor of 2.4 for BC particles are estimated to be 2.3 h and 4.6 h, respectively, in Beijing, compared with 9 h and 18 h, respectively, in Houston. Our findings indicate that BC under polluted urban environments could play an essential role in pollution development and contribute importantly to large positive radiative forcing. The variation in direct radiative forcing is dependent on the rate and timescale of BC aging, with a clear distinction between urban cities in developed and developing countries, i.e., a higher climatic impact in more polluted environments. We suggest that mediation in BC emissions achieves a cobenefit in simultaneously controlling air pollution and protecting climate, especially for developing countries.

  8. Improved dynamic properties of natural rubber filled with irradiation-modified carbon black

    International Nuclear Information System (INIS)

    In this work, carbon black particles (CBs) were modified by high-energy electron beam (EB) irradiation at different doses. The influence of EB irradiation on the surface and particle size of CBs was investigated. Then, the CBs were compounded with natural rubber (NR), and the mechanical properties and dynamic properties of CBs/NR composite were further researched. The results showed that the irradiated CBs had more oxygen-containing groups and smaller particle sizes than original CBs. After irradiation, the content of bound rubber around the irradiated CBs increased, and the mechanical properties of CBs/NR composite were improved. Most importantly, NR filled with irradiated CBs has lower abrasion, higher wet skid resistance, and lower rolling resistance than NR filled with untreated CBs. - Highlights: • Irradiated CBs had more oxygen-containing groups than original CBs. • Irradiated CBs had smaller particle sizes than original CBs. • NR filled with irradiated CBs has lower abrasion than NR filled with untreated CBs. • NR filled with irradiated CBs has lower rolling resistance than NR filled with untreated CBs

  9. Tunneling of massive and charged particles from noncommutative Reissner-Nordstr\\"{o}m black hole

    CERN Document Server

    Nozari, Kourosh

    2012-01-01

    Massive charged and uncharged particles tunneling from commutative Reissner-Nordstrom black hole horizon has been studied with details in literature. Here, by adopting the coherent state picture of spacetime noncommutativity, we study tunneling of massive and charged particles from a noncommutative inspired Reissner-Nordstrom black hole horizon. We show that Hawking radiation in this case is not purely thermal and there are correlations between emitted modes. These correlations may provide a solution to the information loss problem. We also study thermodynamics of noncommutative horizon in this setup.

  10. Tunnelling of relativistic particles from new type black hole in new massive gravity

    Energy Technology Data Exchange (ETDEWEB)

    Gecim, Ganim; Sucu, Yusuf, E-mail: ganimgecim@akdeniz.edu.tr, E-mail: ysucu@akdeniz.edu.tr [Department of Physics, Akdeniz University, Antalya (Turkey)

    2013-02-01

    In the framework of the three dimensional New Massive Gravity theory introduced by Bergshoeff, Hohm and Townsend, we analyze the behavior of relativistic spin-1/2 and spin-0 particles in the New-type Black Hole backgroud, solution of the New Massive Gravity.We solve Dirac equation for spin-1/2 and Klein-Gordon equation for spin-0. Using Hamilton-Jacobi method, we discuss tunnelling probability and Hawking temperature of the spin-1/2 and spin-0 particles for the black hole. We observe that the tunnelling probability and Hawking temperature are same for the spin-1/2 and spin-0.

  11. Massive vector particles tunneling from Kerr and Kerr–Newman black holes

    Directory of Open Access Journals (Sweden)

    Xiang-Qian Li

    2015-12-01

    Full Text Available In this paper, we investigate the Hawking radiation of massive spin-1 particles from 4-dimensional Kerr and Kerr–Newman black holes. By applying the Hamilton–Jacobi ansatz and the WKB approximation to the field equations of the massive bosons in Kerr and Kerr–Newman space-time, the quantum tunneling method is successfully implemented. As a result, we obtain the tunneling rate of the emitted vector particles and recover the standard Hawking temperature of both the two black holes.

  12. Tunneling of massive and charged particles from noncommutative Reissner-Nordström black hole

    Science.gov (United States)

    Nozari, Kourosh; Islamzadeh, Sara

    2013-10-01

    Massive charged and uncharged particles tunneling from commutative Reissner-Nordström black hole horizon has been studied with details in literature. Here, by adopting the coherent state picture of spacetime noncommutativity, we study tunneling of massive and charged particles from a noncommutative inspired Reissner-Nordström black hole horizon. We show that Hawking radiation in this case is not purely thermal and there are correlations between emitted modes. These correlations may provide a solution to the information loss problem. We also study thermodynamics of noncommutative horizon in this setup.

  13. Flowing along the edge: spinning up black holes in AdS spacetimes with test particles

    CERN Document Server

    Rocha, Jorge V

    2014-01-01

    We investigate the consequences of throwing point particles into odd-dimensional Myers-Perry black holes in asymptotically anti-de Sitter (AdS) backgrounds. We restrict our attention to the case in which the angular momenta of the background geometry are all equal. This process allows us to test the generalization of the weak cosmic censorship conjecture to asymptotically AdS spacetimes in higher dimensions. We find no evidence for overspinning in D = 5, 7, 9 and 11 dimensions. Instead, test particles carrying the maximum possible angular momentum that still fall into an extremal rotating black hole generate a flow along the curve of extremal solutions.

  14. Energy extraction and particle acceleration around a rotating black hole in Horava-Lifshitz gravity

    International Nuclear Information System (INIS)

    The Penrose process on rotational energy extraction of the black hole in the original nonprojectable Horava-Lifshitz gravity is studied. The strong dependence of the extracted energy from the special range of parameters of the Horava-Lifshitz gravity, such as parameter ΛW and specific angular momentum a, has been found. Particle acceleration near the rotating black hole in Horava-Lifshitz gravity has been studied. It is shown that the fundamental parameter of the Horava-Lifshitz gravity can impose a limitation on the energy of the accelerating particles preventing them from the infinite value.

  15. A perspective on Black Hole Horizons from the Quantum Charged Particle

    CERN Document Server

    Jaramillo, José Luis

    2016-01-01

    Black hole apparent horizons possess a natural notion of stability, whose spectral characterization can be related to the problem of the stationary quantum charged particle. Such mathematical relation leads to an "analyticity conjecture" on the dependence of the spectral properties on a complex "fine-structure-constant" parameter, that can reduce the study of the spectrum of the (non-selfadjoint) MOTS-stability operator to that of the (selfadjoint) Hamiltonian of the quantum charged particle. Moreover, this perspective might open an avenue to the spinorial treatment of apparent horizon (MOTS-)stability and to the introduction of semiclassical tools to explore some of the qualitative aspects of this black hole spectral problem.

  16. Photo-lability of deep ocean dissolved black carbon

    Directory of Open Access Journals (Sweden)

    A. Stubbins

    2012-05-01

    Full Text Available Dissolved black carbon (DBC, defined here as condensed aromatics isolated from seawater via PPL solid phase extraction and quantified as benzenepolycarboxylic acid (BPCA oxidation products, is a significant component of the oceanic dissolved organic carbon (DOC pool. These condensed aromatics are widely distributed in the open ocean and appear to be tens of thousands of years old. As such DBC is regarded as highly refractory. In the current study, the photo-lability of DBC, DOC and coloured dissolved organic matter (CDOM; ultraviolet-visible absorbance were determined over the course of a 28 day irradiation of North Atlantic Deep Water under a solar simulator. During the irradiation DBC fell from 1044 ± 164 nM-C to 55 ± 15 nM-C, a 20-fold decrease in concentration. Dissolved black carbon photo-degradation was more rapid and more extensive than for bulk CDOM and DOC. The concentration of DBC correlated with CDOM absorbance and the quality of DBC indicated by the ratios of different BPCAs correlated with CDOM absorbance spectral slope, suggesting the optical properties of CDOM may provide a proxy for both DBC concentrations and quality in natural waters. Further, the photo-lability of components of the DBC pool increased with their degree of aromatic condensation. These trends indicate that a continuum of compounds of varying photo-lability exists within the marine DOC pool. In this continuum, photo-lability scales with aromatic character, specifically the degree of condensation. Scaling the rapid photo-degradation of DBC to rates of DOC photo-mineralisation for the global ocean leads to an estimated photo-chemical half-life for oceanic DBC of less than 800 years. This is more than an order of magnitude shorter than the apparent age of DBC in the ocean. Consequently, photo-degradation is posited as the primary sink for oceanic DBC and the apparent survival of DBC molecules in the oceans for millennia appears to be facilitated not by their

  17. Multiple scattering of light by water cloud droplets with external and internal mixing of black carbon aerosols

    Institute of Scientific and Technical Information of China (English)

    Wang Hai-Hua; Sun Xian-Ming

    2012-01-01

    The mixture of water cloud droplets with black carbon impurities is modeled by external and internal mixing models.The internal mixing model is modeled with a two-layered sphere(water cloud droplets containing black carbon(BC)inclusions),and tihe single scattering and absorption characteristics are calculated at the visible wavelength of 0.55 μm by using the Lorenz Mie theory.The external mixing model is developed assuming that the same amount of BC particles are mixed with the water droplets externally.The multiple scattering characteristics we computed by using the Monte Carlo method.The results show that when the size of the BC aerosol is small,the reflection intensity of the internal mixing model is bigger than that of the external mixing model.However,if the size of the BC aerosol is big,the absorption of the internal mixing model will be larger than that of the external mixing model.

  18. Parametric down conversion with a depleted pump as a heuristic model for black hole particle production

    CERN Document Server

    Alsing, Paul M

    2014-01-01

    In this paper, we extend the investigation of Adami and Ver Steeg [Class. Quantum Grav. \\textbf{31}, 075015 (2014)] to treat the process of black hole particle emission as an effective parametric down conversion (PDC) with a depleted (vs. un-depleted) pump. We investigate both the short time (non-depleted pump regime) and long time (depleted pump regime) and its impact on the Holevo channel capacity for communicating information from the far past to the far future in the presence of Hawking radiation. The new feature introduced in this paper is the coupling of the emitted modes through the black hole `source pump' which can be depleted. Within our analogous quantum optical model we examine the entanglement between two emitted particle/anti-particle and anti-particle/particle pairs coupled via the black hole (BH) depleted `pump.' We also investigate the 'Page time' for our model which refers to the conventionally held belief that the information in the BH radiation becomes significant after the black hole has ...

  19. Magnetized particle motion around non-Schwarzschild black hole immersed in an external uniform magnetic field

    Science.gov (United States)

    Rayimbaev, J. R.

    2016-09-01

    The motion of a magnetized particle orbiting around non-Schwarzschild black hole immersed in an external uniform magnetic field is considered. The influence of deformation parameter h to effective potential of the radial motion of the magnetized particle around non-Schwarzschild black hole using Hamilton-Jacobi formalism is studied. We have obtained numerical values of area Δ ρ where magnetized particles can move which is expanding (narrowing) due to the effect of the negative (positive) deformation. Finally, we have studied the collision of two particles (magnetized-neutral, magnetized-magnetized, magnetized-charged) in non-Schwarzschild spacetime and got the center-of-mass energy (E_{c.m}) for the particles. Moreover, we have found the capture radius (r_{cap}) - the distance from the central object to the point where particles collide and fall down to the central compact object. It is shown that non-Schwarzschild black holes could also act as particle accelerators with arbitrarily high center-of-mass energy.

  20. Absorption of a Particle by a Rotating Black Hole: The Potential Barrier

    CERN Document Server

    Heller, Leon

    2016-01-01

    For a test particle approaching a rapidly rotating black hole we find a range of values of the particle's energy and angular momentum, on the order of 1\\% or more of the corresponding values of the hole, such that three conditions are satisfied. 1) The particle can reach the horizon. 2) After absorption the new hole still has a horizon. 3) The area of the new hole is less than the area of the original one, in apparent violation of a theorem of Hawking. We offer support for the claim that the test particle approximation is the cause of the violation.

  1. Hawking Radiation of the Charged Particle via Tunneling from the Kaluza-Klein Black Hole

    Science.gov (United States)

    Pu, Jin; Han, Yan

    2016-08-01

    In this paper, by applying the Lagrangian analysis on the action, we first redefine the geodesic equation of the charged massive particle. Then, basing on the new definition of the geodesic equation, we revisit the Hawking radiation of the charged massive particle via tunneling from the event horizon of the Kaluza-Klein black hole. In our treatment, the geodesic equation of the charged massive particle is defined uniformly with that of the massless particle, which overcomes the shortcomings of its previous definition, and is more suitable for the tunneling mechanism. The highlight of our work is a new and important development for the Parikh-Wilczek's tunneling method.

  2. Tunneling of Massive Vector Particles From Rotating Charged Black Strings

    CERN Document Server

    Jusufi, Kimet

    2015-01-01

    We study the quantum tunneling of charged massive vector bosons from a charged static and a rotating black string. We apply the standard methods, first we use the WKB approximation and the Hamilton-Jacobi equation, and then we end up with a set of four linear equations. Finally, solving for the radial part by using the determinant of the metric equals zero, the corresponding tunneling rate and the Hawking temperature is recovered in both cases. The tunneling rate deviates from pure thermality and is consistent with an underlying unitary theory.

  3. Tunneling of massive vector particles from rotating charged black strings

    Science.gov (United States)

    Jusufi, Kimet; Övgün, Ali

    2016-07-01

    We study the quantum tunneling of charged massive vector bosons from a charged static and a rotating black string. We apply the standard methods, first we use the WKB approximation and the Hamilton-Jacobi equation, and then we end up with a set of four linear equations. Finally, solving for the radial part by using the determinant of the metric equals zero, the corresponding tunneling rate and the Hawking temperature is recovered in both cases. The tunneling rate deviates from pure thermality and is consistent with an underlying unitary theory.

  4. High Voltage Surface Degradation on Carbon Blacks in Lithium Ion Batteries

    DEFF Research Database (Denmark)

    Younesi, Reza

    In order to increase the power density of Li-ion batteries, much research is focused on developing cathode materials that can operate at high voltages above 4.5 V with a high capacity, high cycling stability, and rate capability. However, at high voltages all the components of positive electrodes...... including carbon black (CB) additives have a potential risk of degradation. Though the weight percentage of CB in commercial batteries is generally very small, the volumetric amount and thus the surface area of CB compose a rather large part of a cathode due to its small particle size (≈ 50 nm) and high...... surface area. In this work, the performance of Super P in Li-ion cells at high voltages up to 4.9 V is studied using electrochemical measurements as well as surface characterizations....

  5. Synthesis of SiC Powders by Carbothermal Reduction of Enriched Brown Sepiolite with Carbon Black

    Science.gov (United States)

    Bağci, Cengiz; Arik, Halil

    2013-04-01

    Ultrafine β-silicon carbide (β-SiC) powders were successfully synthesized by carbothermal-reduction reaction (CRR) of sepiolite. Sepiolite of Turkish deposits as a silica (SiO2) precursor and carbon black as a reducing agent were mixed with constant C/SiO2 molar ratio of 4. Mixed powders were subjected to CRR at temperatures of 1450, 1500, and 1550 °C for 1 h in an atmosphere-controlled tube furnace under argon flow of 5 cm3/min. The precursor and resultant powder products were characterized by XRD, SEM, and EDX. Phase transformation was observed in powder products after CRR as a function of the reaction temperature. The results show that the cotton-like nature of sepiolite makes it an effective mineral precursor for synthesis of SiC powders, and that SiC transformation was optimized at 1550 °C with a particle size of approximately 200 nm.

  6. Scattering directionality parameters of fractal black carbon aerosols and comparison with the Henyey-Greenstein approximation.

    Science.gov (United States)

    Pandey, Apoorva; Chakrabarty, Rajan K

    2016-07-15

    Current radiation transfer schemes employ the Henyey-Greenstein (HG) phase function to connect three single parameter representations of aerosol scattering directionality-the hemispherical upscatter fraction (β), the backscatter fraction (b), and the asymmetry parameter (g). The HG phase function does not account for particle morphology, which could lead to significant errors. In this Letter, we compute these single parameters for fractal black carbon (BC) aerosols using the numerically exact superposition T-matrix method. The variations in β, g, and b as a function of aerosol morphology are examined. Corrected empirical relationships connecting these parameters are proposed. We find that the HG phase function could introduce up to a 35% error in β and g estimates. Interestingly, these errors are suppressed by the large mass absorption cross-sections of BC aerosols in radiative transfer calculations and contribute to ≤8% error in direct forcing efficiencies. PMID:27420533

  7. Inflammation and Vascular Effects after Repeated Intratracheal Instillations of Carbon Black and Lipopolysaccharide

    DEFF Research Database (Denmark)

    Christophersen, Daniel Vest; Jacobsen, Nicklas Raun; Jensen, Ditte Marie;

    2016-01-01

    .5% plasma extracted from CB-exposed ApoE-/- mice caused vasoconstriction in aorta rings isolated from naïve mice; this effect was abolished by the treatment with the serotonin receptor antagonist Ketanserin. In conclusion, repeated pulmonary exposure to nanosized CB and LPS caused lung inflammation without......Inflammation and oxidative stress are considered the main drivers of vasomotor dysfunction and progression of atherosclerosis after inhalation of particulate matter. In addition, new studies have shown that particle exposure can induce the level of bioactive mediators in serum, driving vascular......- and systemic toxicity. We aimed to investigate if pulmonary inflammation would accelerate nanoparticle-induced atherosclerotic plaque progression in Apolipoprotein E knockout (ApoE-/-) mice. ApoE -/- mice were exposed to vehicle, 8.53 or 25.6 μg nanosized carbon black (CB) alone or spiked with LPS (0.2 μg...

  8. NONLINEAR CURRENT-VOLTAGE CHARACTERISTICS OF CONDUCTIVE POLYETHYLENE COMPOSITES WITH CARBON BLACK FILLED PET MICROFIBRILS

    Institute of Scientific and Technical Information of China (English)

    Qian-ying Chen; Jing Gao; Kun Dai; Huan Pang; Jia-zhuang Xu; Jian-hua Tang; Zhong-ming Li

    2013-01-01

    Current-voltage electrical behavior of in situ microfibrillar carbon black (CB)/poly(ethylene terephthalate)(PET)/polyethylene (PE) (m-CB/PET/PE) composites with various CB concentrations at ambient temperatures was studied under a direct-current electric field.The current-voltage (Ⅰ-Ⅴ) curves exhibited nonlinearity beyond a critical value of voltage.The dynamic random resistor network (DRRN) model was adopted to semi-qualitatively explain the nonlinear conduction behavior of m-CB/PET/PE composites.Macroscopic nonlinearity originated from the interracial interactions between CB/PET micro fibrils and additional conduction channels.Combined with the special conductive networks,an illustration was proposed to interpret the nonlinear Ⅰ-Ⅴ characteristics by a field emission or tunneling mechanism between CB particles in the CB/PET microfibers intersections.

  9. Impact of brown and clear carbon on light absorption enhancement, single scatter albedo and absorption wavelength dependence of black carbon

    Directory of Open Access Journals (Sweden)

    D. A. Lack

    2010-01-01

    Full Text Available The presence of clear coatings on atmospheric black carbon (BC particles is known to enhance the magnitude of light absorption by the BC cores. Based on calculations using core/shell Mie theory, we demonstrate the enhancement of light absorption (EAbs by atmospheric black carbon (BC when coated in mildly absorbing material (CBrown is reduced, relative to the enhancement by non-absorbing coatings (CClear. This reduction, sensitive to CBrown shell thickness and imaginary refractive index (RI, can be up to 50% for 400 nm radiation and 25% averaged across the visible radiation spectrum for reasonable core/shell diameters. The enhanced direct radiative forcing possible due to the enhancement effect of CClear is therefore reduced if the coating is absorbing. Additionally, the need to explicitly treat BC as an internal, as opposed to external, mixture with CBrown is shown to be important to the calculated single scatter albedo only whensub models treat BC as large spherical cores (>50 nm. For smaller BC cores (or fractal agglomerates consideration of the BC and CBrown as an external mixture leads to relatively small errors in the particle single scatter albedo of <0.03. It is often assumed that observation of an absorption Angstrom exponent (AAE >1 indicates non-BC absorption. Here, it is shown that BC cores coated in CClearcan reasonably have an AAE of up to 1.6, a result that complicates the attribution of observed light absorption to CBrown within ambient particles. However, an AAE<1.6 does not exclude the possibility of CBrown, rather CBrown cannot be confidently assigned unless AAE>1.6. Comparison of these results to some ambient AAE data shows that large-scale attribution of CBrown is a challenging task using current in-situ measurement methods. We suggest that coincident measurements of particle core and

  10. Organic carbon isotopes of the Sinian and Early Cambrian black shales on Yangtze Platform, China

    Institute of Scientific and Technical Information of China (English)

    李任伟; 卢家烂; 张淑坤; 雷加锦

    1999-01-01

    Organic matter of the Sinian and early Cambrian black shales on the Yangtze Platform belongs to the light carbon group of isotopes with the δ13C values from - 27 % to -35 % , which are lower than those of the contemporaneously deposited carbonates and phosphorites. A carbon isotope-stratified paleooceanographic model caused by upwelling is proposed, which can be used not only to interpret the characteristics of organic carbon isotopic compositions of the black shales, but also to interpret the paleogeographic difference in the organic carbon isotope compositions of various types of sedimentary rocks.

  11. The impact of black wattle encroachment of indigenous grasslands on soil carbon, Eastern Cape, South Africa

    DEFF Research Database (Denmark)

    Oelofse, Myles; Birch-Thomsen, Torben; Magid, Jakob;

    2016-01-01

    adverse environmental impacts in South Africa. Little is known about the effects of black wattle encroachment on soil carbon, therefore the aim of this study was to investigate the impact of black wattle encroachment of natural grassland on soil carbon stocks and dynamics. Focussing on two sites...... in the Eastern Cape, South Africa, the study analysed carbon stocks in soil and litter on a chronosequence of black wattle stands of varying ages (up to >50 years) and compared these with adjacent native grassland. The study found that woody encroachment of grassland at one site had an insignificant effect...

  12. Grafted, cross-linked carbon black as a double-layer capacitor electrode material

    Energy Technology Data Exchange (ETDEWEB)

    Richner, R.; Mueller, S.; Wokaun, A.

    2001-03-01

    Isocyanate prepolymers readily react with oxidic functional groups on carbon black. On carbon black grafted with diisocyanates, reactive isocyanate groups are available for cross-linking to a polyurethane system. This cross-linked carbon black was considered as a new active material for electrochemical electrodes. Active material for electric double-layer capacitor electrodes was produced which had values of specific capacitance of up to 200 F/g. Cross-linking efficiencies of up to 58 % of the polymers utilised were achieved. (author)

  13. Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols

    Directory of Open Access Journals (Sweden)

    M. O. Andreae

    2006-01-01

    Full Text Available Although the definition and measurement techniques for atmospheric 'black carbon' ('BC' or 'elemental carbon'' ('EC' have long been subjects of scientific controversy, the recent discovery of light-absorbing carbon that is not black ('brown carbon, Cbrown' makes it imperative to reassess and redefine the components that make up light-absorbing carbonaceous matter (LAC in the atmosphere. Evidence for the atmospheric presence of Cbrown comes from (1 spectral aerosol light absorption measurements near specific combustion sources, (2 observations of spectral properties of water extracts of continental aerosol, (3 laboratory studies indicating the formation of light-absorbing organic matter in the atmosphere, and (4 indirectly from the chemical analogy of aerosol species to colored natural humic substances. We show that brown carbon may severely bias measurements of 'BC' and 'EC' over vast parts of the troposphere, especially those strongly polluted by biomass burning, where the mass concentration of Cbrown is high relative to that of soot carbon. Chemical measurements to determine 'EC' are biased by the refractory nature of Cbrown as well as by complex matrix interferences. Optical measurements of 'BC' suffer from a number of problems: (1 many of the presently used instruments introduce a substantial bias into the determination of aerosol light absorption, (2 there is no unique conversion factor between light absorption and 'EC' or 'BC' concentration in ambient aerosols, and (3 the difference in spectral properties between the different types of LAC, as well as the chemical complexity of Cbrown, lead to several conceptual as well as practical complications. We also suggest that due to the sharply increasing absorption of Cbrown towards the UV, single-wavelength light absorption measurements may not be adequate for the assessment of absorption of solar radiation in the troposphere. We discuss the possible consequences of these effects for our

  14. Tailoring the morphology of raspberry-like carbon black/polystyrene composite microspheres for fabricating superhydrophobic surface

    Energy Technology Data Exchange (ETDEWEB)

    Bao, Yubin [Polymer Alloy Lab., School of Material Science and Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237 (China); Li, Qiuying, E-mail: liqy@ecust.edu.cn [Polymer Alloy Lab., School of Material Science and Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237 (China); Shanghai Key Laboratory Polymeric Materials (China); Key Laboratory of Ultrafine Materials of Ministry of Education (China); Xue, Pengfei; Huang, Jianfeng; Wang, Jibin; Guo, Weihong; Wu, Chifei [Polymer Alloy Lab., School of Material Science and Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237 (China)

    2011-05-15

    In our previous report, raspberry-like carbon black/polystyrene (CB/PS) composite microsphere was prepared through heterocoagulation process. Based on the previous study, in the present work, the morphology of raspberry-like CB/PS particle is tailored through adjusting the polarity and the concentration ratio of CB/PS colloidal suspension with the purpose to prepare particulate film for the fabrication of superhydrophobic surface. Scanning electron microscope (SEM) confirms the morphology of raspberry-like particle and the coverage of CB. Rough surfaces fabricated by raspberry-like particles with proper morphology are observed by SEM and clear evidence of superhydrophobic surface is shown. The structure of raspberry-like particle is analyzed by atom force microscope. The proposed relationship between the hydrophobicity and the structure of CB aggregates on the surface of PS microsphere is discussed in details.

  15. Black carbon estimation in French calcareous soils using chemo-thermal oxidation method

    OpenAIRE

    Caria, G.; Arrouays, D.; Dubromel, E.; Jolivet, C.; Ratié, C.; Bernoux, MARTIAL,; Barthès, Bernard; Brunet, Didier; Grinand, Clovis

    2011-01-01

    We studied the black carbon (BC) content of ca. 405 samples from French topsoil and artificial soil and carbonate mixtures. Our protocol involved three main steps: (i) decarbonation by HCl, (ii) elimination of non-pyrogenic organic carbon in a furnace at 375 degrees C, and (iii) quantification of residual carbon by CHN analysis. BC content increased for calcareous soils according to their carbonates content. Subsequent analyses confirmed the existence of a methodological artefact for BC deter...

  16. Signatures of Energy Flux in Particle Production: A Black Hole Birth Cry and Death Gasp

    CERN Document Server

    Good, Michael R R

    2015-01-01

    It is recently argued that if the Hawking radiation process is unitary, then a black hole's mass cannot be monotonically decreasing. We examine the time dependent particle count and negative energy flux in the non-trivial conformal vacuum via the moving mirror approach. A new, exactly unitary solution is presented which emits a characteristic above-thermal positive energy burst, a thermal plateau, and negative energy flux. It is found that the characteristic positive energy flare and thermal plateau is observed in the particle outflow. However, the results of time dependent particle production show no overt indication of negative energy flux. Therefore, a black hole's birth cry is detectable by asymptotic observers via particle count, whereas its death gasp is not.

  17. Aerosol optical properties and mixing state of black carbon in the Pearl River Delta, China

    Science.gov (United States)

    Tan, Haobo; Liu, Li; Fan, Shaojia; Li, Fei; Yin, Yan; Cai, Mingfu; Chan, P. W.

    2016-04-01

    Aerosols contribute the largest uncertainty to the total radiative forcing estimate, and black carbon (BC) that absorbs solar radiation plays an important role in the Earth's energy budget. This study analysed the aerosol optical properties from 22 February to 18 March 2014 at the China Meteorological Administration Atmospheric Watch Network (CAWNET) station in the Pearl River Delta (PRD), China. The representative values of dry-state particle scattering coefficient (σsp), hemispheric backscattering coefficient (σhbsp), absorption coefficient (σabsp), extinction coefficient (σep), hemispheric backscattering fraction (HBF), single scattering albedo (SSA), as well as scattering Ångström exponent (α) were presented. A comparison between a polluted day and a clean day shows that the aerosol optical properties depend on particle number size distribution, weather conditions and evolution of the mixing layer. To investigate the mixing state of BC at the surface, an optical closure study of HBF between measurements and calculations based on a modified Mie model was employed for dry particles. The result shows that the mixing state of BC might be between the external mixture and the core-shell mixture. The average retrieved ratio of the externally mixed BC to the total BC mass concentration (rext-BC) was 0.58 ± 0.12, and the diurnal pattern of rext-BC can be found. Furthermore, considering that non-light-absorbing particles measured by a Volatility-Tandem Differential Mobility Analyser (V-TDMA) exist independently with core-shell and homogenously internally mixed BC particles, the calculated optical properties were just slightly different from those based on the assumption that BC exist in each particle. This would help understand the influence of the BC mixing state on aerosol optical properties and radiation budget in the PRD.

  18. Synthesis of carbon nanotubes with and without catalyst particles

    Directory of Open Access Journals (Sweden)

    Cuniberti Gianaurelio

    2011-01-01

    Full Text Available Abstract The initial development of carbon nanotube synthesis revolved heavily around the use of 3d valence transition metals such as Fe, Ni, and Co. More recently, noble metals (e.g. Au and poor metals (e.g. In, Pb have been shown to also yield carbon nanotubes. In addition, various ceramics and semiconductors can serve as catalytic particles suitable for tube formation and in some cases hybrid metal/metal oxide systems are possible. All-carbon systems for carbon nanotube growth without any catalytic particles have also been demonstrated. These different growth systems are briefly examined in this article and serve to highlight the breadth of avenues available for carbon nanotube synthesis.

  19. Effect of a biological activated carbon filter on particle counts

    Institute of Scientific and Technical Information of China (English)

    Su-hua WU; Bing-zhi DONG; Tie-jun QIAO; Jin-song ZHANG

    2008-01-01

    Due to the importance of biological safety in drinking water quality and the disadvantages which exist in traditional methods of detecting typical microorganisms such as Cryptosporidium and Giardia,it is necessary to develop an alternative.Particle counts is a qualitative measurement of the amount of dissolved solids in water.The removal rate of particle counts was previously used as an indicator of the effectiveness of a biological activated carbon(BAC)filter in removing Cryptosporidium and Giardia.The particle counts in a BAC filter effluent over one operational period and the effects of BAC filter construction and operational parameters were investigated with a 10 m3/h pilot plant.The results indicated that the maximum particle count in backwash remnant water was as high as 1296 count/ml and it needed about 1.5 h to reduce from the maximum to less than 50 count/ml.During the standard filtration period,particle counts stay constant at less than 50 count/ml for 5 d except when influ-enced by sand filter backwash remnant water.The removal rates of particle counts in the BAC filter are related to characteristics of the carbon.For example,a columned carbon and a sand bed removed 33.3% and 8.5% of particles,respectively,while the particle counts in effluent from a cracked BAC filter was higher than that of the influent.There is no significant difference among particle removal rates with different filtration rates.High post-ozone dosage(>2 mg/L)plays an important role in particle count removal;when the dosage was 3 mg/L,the removal rates by carbon layers and sand beds decreased by 17.5% and increased by 9.5%,respectively,compared with a 2 mg/L dosage.

  20. Measured Wavelength-Dependent Absorption Enhancement of Internally Mixed Black Carbon with Absorbing and Nonabsorbing Materials.

    Science.gov (United States)

    You, Rian; Radney, James G; Zachariah, Michael R; Zangmeister, Christopher D

    2016-08-01

    Optical absorption spectra of laboratory generated aerosols consisting of black carbon (BC) internally mixed with nonabsorbing materials (ammonium sulfate, AS, and sodium chloride, NaCl) and BC with a weakly absorbing brown carbon surrogate derived from humic acid (HA) were measured across the visible to near-IR (550 to 840 nm). Spectra were measured in situ using a photoacoustic spectrometer and step-scanning a supercontinuum laser source with a tunable wavelength and bandwidth filter. BC had a mass-specific absorption cross section (MAC) of 7.89 ± 0.25 m(2) g(-1) at λ = 550 nm and an absorption Ångström exponent (AAE) of 1.03 ± 0.09 (2σ). For internally mixed BC, the ratio of BC mass to the total mass of the mixture was chosen as 0.13 to mimic particles observed in the terrestrial atmosphere. The manner in which BC mixed with each material was determined from transmission electron microscopy (TEM). AS/BC and HA/BC particles were fully internally mixed, and the BC was both internally and externally mixed for NaCl/BC particles. The AS/BC, NaCl/BC, and HA/BC particles had AAEs of 1.43 ± 0.05, 1.34 ± 0.06, and 1.91 ± 0.05, respectively. The observed absorption enhancement of mixed BC relative to the pure BC was wavelength dependent for AS/BC and decreased from 1.5 at λ = 550 nm with increasing wavelength while the NaCl/BC enhancement was essentially wavelength independent. For HA/BC, the enhancement ranged from 2 to 3 and was strongly wavelength dependent. Removal of the HA absorption contribution to enhancement revealed that the enhancement was ≈1.5 and independent of wavelength. PMID:27359341

  1. The Hawking evaporation of dirac particles in general Kerr-Newman black hole background

    International Nuclear Information System (INIS)

    In 1974, a study proposed that there might be some quantum processes, in which the irreducible mass of a black hole is radiated away. Such a quantum vacuum polarization process is named Hawking evaporation. In 1976, a study discussed the Hawking evaporation of Klein-Gordon particles through Klein-Souter-Heisenberg-Euler formalism. Recently, a study found the solution of the Dirac equations just outside the horizon for quasi-extreme Kerr and Kerr-Newman black holes by means of the decoupled Dirac equations with non-zero mass. The corresponding Hawking thermal spectrum formula was also derived. However, it is unnecessary to impose quasi-extreme conditions on the black holes for solving the equations. In this paper, the authors discuss the general Kerr-Newman black hole directly

  2. Integrability of Particle System around a Ring Source as the Newtonian Limit of a Black Ring

    CERN Document Server

    Igata, Takahisa; Yoshino, Hirotaka

    2014-01-01

    The geodesic equation in the five-dimensional singly rotating black ring is non-integrable unlike the case of the Myers-Perry black hole. In the Newtonian limit of the black ring, its geodesic equation agrees with the equation of motion of a particle in the Newtonian potential due to a homogeneous ring gravitational source. In this paper, we show that the Newtonian equation of motion allows the separation of variables in the spheroidal coordinates, providing an non-trivial constant of motion quadratic in momenta. This shows that the Newtonian limit of a black ring recovers the symmetry of its geodesic system, and the geodesic chaos is caused by relativistic effects.

  3. Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols

    Directory of Open Access Journals (Sweden)

    M. O. Andreae

    2006-05-01

    Full Text Available Although the definition and measurement methods of atmospheric ''black carbon'' (''BC'' have long been subjects of scientific controversy, the recent discovery of light-absorbing carbon that is not black (''brown carbon, Cbrown'' makes it imperative to reassess and redefine the components that make up light-absorbing carbonaceous matter (LAC in the atmosphere. Evidence for the atmospheric presence of Cbrown comes directly from aerosol absorption measurements near specific combustion sources, from observations of spectral properties of water extracts of continental aerosol, from laboratory studies indicating the formation of light-absorbing organic matter in the atmosphere, and indirectly from the chemical analogy of aerosol species to colored natural humic substances. We show that these species may severely bias measurements of ''BC'' and ''EC'' over vast parts of the troposphere, where mass concentration of Cbrown is high relative to that of combustion soot. We also imply that due to the strongly skewed absorption of Cbrown towards the UV, single-wavelength light absorption measurements may not be adequate for the assessment of absorption of solar radiation in the troposphere. The possible consequences of these effects on our understanding of tropospheric processes are discussed.

  4. Chemical Bonding and Structural Information of Black CarbonReference Materials and Individual Carbonaceous AtmosphericAerosols

    Energy Technology Data Exchange (ETDEWEB)

    Hopkins, Rebecca J.; Tivanski, Alexei V.; Marten, Bryan D.; Gilles, Mary K.

    2007-04-25

    The carbon-to-oxygen ratios and graphitic nature of a rangeof black carbon standard reference materials (BC SRMs), high molecularmass humic-like substances (HULIS) and atmospheric particles are examinedusing scanning transmission X-ray microscopy (STXM) coupled with nearedge X-ray absorption fine structure (NEXAFS) spectroscopy. UsingSTXM/NEXAFS, individual particles with diameter>100 nm are studied,thus the diversity of atmospheric particles collected during a variety offield missions is assessed. Applying a semi-quantitative peak fittingmethod to the NEXAFS spectra enables a comparison of BC SRMs and HULIS toparticles originating from anthropogenic combustion and biomass burns,thus allowing determination of the suitability of these materials forrepresenting atmospheric particles. Anthropogenic combustion and biomassburn particles can be distinguished from one another using both chemicalbonding and structural ordering information. While anthropogeniccombustion particles are characterized by a high proportion ofaromatic-C, the presence of benzoquinone and are highly structurallyordered, biomass burn particles exhibit lower structural ordering, asmaller proportion of aromatic-C and contain a much higher proportion ofoxygenated functional groups.

  5. Gravitational radiation from the radial infall of highly relativistic point particles into Kerr black holes

    International Nuclear Information System (INIS)

    In this paper, we consider the gravitational radiation generated by the collision of highly relativistic particles with rotating Kerr black holes. We use the Sasaki-Nakamura formalism to compute the waveform, energy spectra, and total energy radiated during this process. We show that the gravitational spectrum for high-energy collisions has definite characteristic universal features, which are independent of the spin of the colliding objects. We also discuss the possible connections between these results and black-hole-black-hole collisions at the speed of light. Our results show that during the high-speed collision of a nonrotating hole with a rotating one, at most 35% of the total energy can get converted into gravitational waves. This 35% efficiency occurs only in the most optimistic situation, that of a zero impact parameter collision, along the equatorial plane, with an almost extreme Kerr black hole. In the general situation, the total gravitational energy radiated is expected to be much less, especially if the impact parameter increases. Thus, if one is able to produce black holes at the CERN Large Hadron Collider, at most 35% of the partons' energy should be emitted during the so-called balding phase. This energy will be missing, since we do not have gravitational wave detectors able to measure such amplitudes. The collision at the speed of light between one rotating black hole and a nonrotating one or two rotating black holes turns out to be the most efficient gravitational wave generator in the Universe

  6. Quantum Tunneling of Massive Particles from a Garfinkle-Horowitz-Strominger Dilatonic Black Hole

    Institute of Scientific and Technical Information of China (English)

    GAO Li; LIU Wen-Biao

    2006-01-01

    Hawking radiation is viewed as a process of quantum tunneling. The massive particles' tunneling from Garfinkle-Horowitz-Strominger black hole is investigated. Using Jingyi Zhang's de Broglie wave method, we get the unthermal spectrum, and the result is consistent with the underlying unitary theory.

  7. Heterogeneous oxidation of SO2 by O3-aged black carbon and its dithiothreitol oxidative potential.

    Science.gov (United States)

    Xu, Weiwei; Li, Qian; Shang, Jing; Liu, Jia; Feng, Xiang; Zhu, Tong

    2015-10-01

    Ozone (O3) is an important atmospheric oxidant. Black carbon (BC) particles released into the atmosphere undergo an aging process via O3 oxidation. O3-aged BC particles may change their uptake ability toward trace reducing gases such as SO2 in the atmosphere, leading to different environmental and health effects. In this paper, the heterogeneous reaction process between O3-aged BC and SO2 was explored via in-situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Combined with ion chromatography (IC), DRIFTS was used to qualitatively and quantitatively analyze the sulfate product. The results showed that O3-aged BC had stronger SO2 oxidation ability than fresh BC, and the reactive species/sites generated on the surface had an important role in the oxidation of SO2. Relative humidity or 254nm UV (ultraviolet) light illumination enhanced the oxidation uptake of SO2 on O3-aged BC. The oxidation potentials of the BC particles were detected via dithiothreitol (DTT) assay. The DTT activity over BC was decreased in the process of SO2 reduction, with the consumption of oxidative active sites. PMID:26456606

  8. Size-dependent wet removal of black carbon in Canadian biomass burning plumes

    Directory of Open Access Journals (Sweden)

    J. W. Taylor

    2014-07-01

    Full Text Available Wet deposition is the dominant mechanism for removing black carbon (BC from the atmosphere, and is key in determining its atmospheric lifetime, vertical gradient and global transport. Despite the importance of BC in the climate system, especially in terms of its ability to modulate the radiative energy budget, there are few quantitative case studies of wet removal in ambient environments. We present a case study of BC wet removal by examining aerosol size distributions and BC coating properties sampled in three Canadian boreal biomass burning plumes, one of which passed through a precipitating cloud. In this plume, the largest and most coated BC particles were found to be preferentially removed, suggesting that nucleation scavenging was the likely dominant mechanism. Calculated mass absorption coefficient (MAC in the plumes showed no significant variation, as the shifts to smaller BC cores and thinner coatings had opposing effects. Similarly, calculated single-scatter albedo (SSA showed little variation, as a large number of non-BC particles were also present in the precipitation-affected plume. The remaining BC cores were smaller than those observed in previous studies of BC in post-precipitation outflow over Asia, possibly due to the thick coatings associated with the biomass burning particles. This study provides important constraints to model parameterisations of BC wet removal in biomass burning regions, which will help to reduce uncertainty in radiative forcing calculations.

  9. On-road black carbon instrument intercomparison and aerosol characteristics by driving environment

    Science.gov (United States)

    Holder, Amara L.; Hagler, Gayle S. W.; Yelverton, Tiffany L. B.; Hays, Michael D.

    2014-05-01

    Large spatial variations of black carbon (BC) concentrations in the on-road and near-road environments necessitate measurements with high spatial resolution to assess exposure accurately. A series of measurements was made comparing the performance of several different BC instruments (Single Particle Soot Photometer, Photo-Acoustic Soot Spectrometer, and Aethalometer) for high time resolution mobile measurements, capable of mapping spatial gradients. All instruments were highly correlated at high time resolution (r2 = 0.80-0.89 at a 2-s resolution), however the slope ranged from 0.52 to 1.03, with the Single Particle Soot Photometer (SP2) consistently reporting the lowest BC concentrations. BC and ultrafine particle (UFP) concentrations were two-fold higher on the highway compared to surrounding roads with lower traffic counts. The BC size distribution had a mass median diameter of approximately 120 nm, which was smaller and less coated than aged urban BC. Mean UFP and BC concentrations were 2 and 1.4 times greater, respectively, during free flowing traffic on the highway compared with times when there was stop-and-go congestion, providing evidence that transit time is not a good predictor of BC or UFP exposure.

  10. Characterizing black carbon in rain and ice cores using coupled tangential flow filtration and transmission electron microscopy

    Directory of Open Access Journals (Sweden)

    A. Ellis

    2015-06-01

    Full Text Available Antarctic ice cores have been used to study the history of black carbon (BC, but little is known with regards to the physical and chemical characteristics of these particles in the remote atmosphere. Characterization remains limited by ultra-trace concentrations in ice core samples and the lack of adequate methods to isolate the particles unaltered from the melt water. To investigate the physical and chemical characteristics of these particles, we have developed a tangential flow filtration (TFF method combined with transmission electron microscopy (TEM. Tests using ultrapure water and polystyrene latex particle standards resulted in excellent blanks and significant particle recovery. This approach has been applied to melt water from Antarctic ice cores as well as tropical rain from Darwin, Australia with successful results: TEM analysis revealed a variety of BC particle morphologies, insoluble coatings, and the attachment of BC to mineral dust particles. The TFF-based concentration of these particles has proven to give excellent results for TEM studies of BC particles in Antarctic ice cores and can be used for future studies of insoluble aerosols in rainwater and ice core samples.

  11. Russia's black carbon emissions: focus on diesel sources

    Science.gov (United States)

    Kholod, Nazar; Evans, Meredydd; Kuklinski, Teresa

    2016-09-01

    Black carbon (BC) is a significant climate forcer with a particularly pronounced forcing effect in polar regions such as the Russian Arctic. Diesel combustion is a major global source of BC emissions, accounting for 25-30 % of all BC emissions. While the demand for diesel is growing in Russia, the country's diesel emissions are poorly understood. This paper presents a detailed inventory of Russian BC emissions from diesel sources. Drawing on a complete Russian vehicle registry with detailed information about vehicle types and emission standards, this paper analyzes BC emissions from diesel on-road vehicles. We use the COPERT emission model (COmputer Programme to calculate Emissions from Road Transport) with Russia-specific emission factors for all types of on-road vehicles. On-road diesel vehicles emitted 21 Gg of BC in 2014: heavy-duty trucks account for 60 % of the on-road BC emissions, while cars represent only 5 % (light commercial vehicles and buses account for the remainder). Using Russian activity data and fuel-based emission factors, the paper also presents BC emissions from diesel locomotives and ships, off-road engines in industry, construction and agriculture, and generators. The study also factors in the role of superemitters in BC emissions from diesel on-road vehicles and off-road sources. The total emissions from diesel sources in Russia are estimated to be 49 Gg of BC and 17 Gg of organic carbon (OC) in 2014. Off-road diesel sources emitted 58 % of all diesel BC in Russia.

  12. Black Carbon Inclusive Multichemical Modeling of PBDE and PCB Biomagnification and -Transformation in Estuarine Food Webs

    NARCIS (Netherlands)

    Paolo, C.; Gandhi, N.; Bhavsar, S.; Heuvel-Greve, van den M.J.; Koelmans, A.A.

    2010-01-01

    Bioavailability and bioaccumulation of polybrominated diphenylethers (PBDEs) are affected by adsorption on black carbon (BC) and metabolism in biota, respectively. Recent studies have addressed these two processes separately, illustrating their importance in assessing contaminant dynamics. In order

  13. Black carbon aerosols and the third polar ice cap

    Energy Technology Data Exchange (ETDEWEB)

    Menon, Surabi; Koch, Dorothy; Beig, Gufran; Sahu, Saroj; Fasullo, John; Orlikowski, Daniel

    2010-04-15

    Recent thinning of glaciers over the Himalayas (sometimes referred to as the third polar region) have raised concern on future water supplies since these glaciers supply water to large river systems that support millions of people inhabiting the surrounding areas. Black carbon (BC) aerosols, released from incomplete combustion, have been increasingly implicated as causing large changes in the hydrology and radiative forcing over Asia and its deposition on snow is thought to increase snow melt. In India BC emissions from biofuel combustion is highly prevalent and compared to other regions, BC aerosol amounts are high. Here, we quantify the impact of BC aerosols on snow cover and precipitation from 1990 to 2010 over the Indian subcontinental region using two different BC emission inventories. New estimates indicate that Indian BC emissions from coal and biofuel are large and transport is expected to expand rapidly in coming years. We show that over the Himalayas, from 1990 to 2000, simulated snow/ice cover decreases by {approx}0.9% due to aerosols. The contribution of the enhanced Indian BC to this decline is {approx}36%, similar to that simulated for 2000 to 2010. Spatial patterns of modeled changes in snow cover and precipitation are similar to observations (from 1990 to 2000), and are mainly obtained with the newer BC estimates.

  14. Characteristics and source of black carbon aerosol over Taklimakan Desert

    Institute of Scientific and Technical Information of China (English)

    FU; S.Joshua

    2010-01-01

    Black carbon(BC) and PM10 in the center of the Taklimakan Desert were online monitored in the whole year of 2007.In addi-tion,TSP samples were also synchronously daily collected by medium-volume samplers with Whatman41 filters in the spring of 2007.BC in the dust aerosol was up to 1.14%of the total mass of PM10.A remarkable seasonal variation of BC in the aerosol was observed in the order of winter>spring>autumn>summer.The peak value of BC appeared at midnight while the lowest one in the evening each day,which was just the reverse of that in the urban area.The contribution of BC to the total mass of PM10 on non-dust storm days was~11 times of that in dust storm.Through back trajectory and principal component analysis,it was found that BC in the dust aerosol over Taklimakan Desert might be attributed to the emission from the anthropogenic activities,including domestic heating,cooking,combustion of oil and natural gas,and the medium-range transport from those oases located in the margins of the desert.The total BC aerosol from the Taklimakan Desert to be transported to the eastward downstream was estimated to be 6.3×104 ton yr-1.

  15. Sources of uncertainties in modelling black carbon at the global scale

    OpenAIRE

    Vignati, E.; Karl, M; M. Krol; Wilson, J.(School of Physics and Astronomy, University of Birmingham, Birmingham, United Kingdom); Stier, P; F. Cavalli

    2010-01-01

    Our understanding of the global black carbon (BC) cycle is essentially qualitative due to uncertainties in our knowledge of its properties. This work investigates two source of uncertainties in modelling black carbon: those due to the use of different schemes for BC ageing and its removal rate in the global Transport-Chemistry model TM5 and those due to the uncertainties in the definition and quantification of the observations, which propagate through to both the emission inventories, and the...

  16. Using Pyrolized Carbon Black (PCB) from Waste Tires in Asphalt Pavement (Part 2, Asphalt Binder)

    OpenAIRE

    Zeng, Yongdong; Lovell, C. W.

    1996-01-01

    Scrap tires derived from automobiles have become a large environmental problem in the United States. In this study, research is carried out to investigate the potential use of tire-derived pyrolyzed carbon black from scrap tires as an asphalt cement modifier. The asphalt cements used in this research were AC10 and AC20. Penetration and softening point tests were performed to obtain the consistency of the asphalt cements. The pyrolyzed carbon black, as provided by Wolf Industries, was comb...

  17. Factorial Based Response Surface Modeling with Confidence Intervals for Optimizing Thermal Optical Transmission Analysis of Atmospheric Black Carbon

    Science.gov (United States)

    We demonstrate how thermal-optical transmission analysis (TOT) for refractory light-absorbing carbon in atmospheric particulate matter was optimized with empirical response surface modeling. TOT employs pyrolysis to distinguish the mass of black carbon (BC) from organic carbon (...

  18. Atmospheric black carbon and warming effects influenced by the source and absorption enhancement in Central Europe

    Directory of Open Access Journals (Sweden)

    S. Nordmann

    2014-06-01

    Full Text Available Particles containing black carbon (BC, a strong absorbing substance, exert a rather uncertain direct and indirect radiative forcing in the atmosphere. To investigate the mass concentration and absorption properties of BC particles over Central Europe, the model WRF-Chem was used at a resolution of 12 km in conjunction with a high resolution BC emission inventory (EUCAARI 42-Pan-European Carbonaceous Aerosol Inventory; 1/8° × 1/16°. The model simulation was evaluated using measurements of equivalent soot carbon, absorption coefficients and particle number concentrations at 7 sites within the German Ultrafine Aerosol Network, PM10 mass concentrations from the dense measurement network of the German Federal Environmental Agency at 392 monitoring stations, and aerosol optical depth from MODIS and AERONET. A distinct time period (25 March to 10 April 2009 was chosen, during which the clean marine air mass prevailed in the first week and afterwards the polluted continental air mass mainly from south-east dominated with elevated daily average BC concentration up to 4 μg m−3. The simulated PM10 mass concentration, aerosol number concentration and optical depth were in a good agreement with the observations, while the modelled BC mass concentrations were found to be a factor of 2 lower than the observations. Together with backtrajectories, detailed model bias analyses suggested that the current BC emission in countries to the east and south of Germany might be underestimated by a factor of 5, at least for the simulation period. Running the model with upscaled BC emissions in these regions led to a smaller model bias and a better correlation between model and measurement. On the contrary, the particle absorption coefficient was positively biased by about 20% even when the BC mass concentration was underestimated by around 50%. This indicates that the internal mixture treatment of BC in the WRF-Chem optical calculation is unrealistic in our case

  19. A Numerical Study on Electrical Percolation of Polymer-Matrix Composites with Hybrid Fillers of Carbon Nanotubes and Carbon Black

    Directory of Open Access Journals (Sweden)

    Yuli Chen

    2014-01-01

    Full Text Available The electrical percolation of polymer-matrix composites (PMCs containing hybrid fillers of carbon nanotubes (CNTs and carbon black (CB is estimated by studying the connection possibility of the fillers using Monte Carlo simulation. The 3D simulation model of CB-CNT hybrid filler is established, in which CNTs are modeled by slender capped cylinders and CB groups are modeled by hypothetical spheres with interspaces because CB particles are always agglomerated. The observation on the effects of CB and CNT volume fractions and dimensions on the electrical percolation threshold of hybrid filled composites is then carried out. It is found that the composite electrical percolation threshold can be reduced by increasing CNT aspect ratio, as well as increasing the diameter ratio of CB groups to CNTs. And adding CB into CNT composites can decrease the CNT volume needed to convert the composite conductivity, especially when the CNT volume fraction is close to the threshold of PMCs with only CNT filler. Different from previous linear assumption, the nonlinear relation between CB and CNT volume fractions at composite percolation threshold is revealed, which is consistent with the synergistic effect observed in experiments. Based on the nonlinear relation, the estimating equation for the electrical percolation threshold of the PMCs containing CB-CNT hybrid fillers is established.

  20. Quantum Radiation Properties of Dirac Particles in General Nonstationary Black Holes

    Directory of Open Access Journals (Sweden)

    Jia-Chen Hua

    2014-01-01

    Full Text Available Quantum radiation properties of Dirac particles in general nonstationary black holes in the general case are investigated by both using the method of generalized tortoise coordinate transformation and considering simultaneously the asymptotic behaviors of the first-order and second-order forms of Dirac equation near the event horizon. It is generally shown that the temperature and the shape of the event horizon of this kind of black holes depend on both the time and different angles. Further, we give a general expression of the new extra coupling effect in thermal radiation spectrum of Dirac particles which is absent from the thermal radiation spectrum of scalar particles. Also, we reveal a relationship that is ignored before between thermal radiation and nonthermal radiation in the case of scalar particles, which is that the chemical potential in thermal radiation spectrum is equal to the highest energy of the negative energy state of scalar particles in nonthermal radiation for general nonstationary black holes.

  1. The Hawking radiation of the charged particle via tunnelling from the axisymmetric Sen black hole

    Institute of Scientific and Technical Information of China (English)

    Jiang Qing-Quan; Yang Shu-Zheng; Chen De-You

    2006-01-01

    Extending Parikh's semi-classical quantum tunnelling model, this paper has studied the Hawking radiation of the charged particle via tunnelling from the horizon of the axisymmetric Sen black hole. Different from the uncharged massless particle, the geodesies of the charged massive particle tunnelling from the horizon is not light-like. The derived result supports Parikh's opinion and provides a correct modification to Hawking strictly thermal spectrum developed by the fixed background space-time and not considering the energy conservation and the self-gravitation interaction.

  2. Numerical investigation on the Ångström exponent of black carbon aerosol

    Science.gov (United States)

    Li, Ji; Liu, Chao; Yin, Yan; Kumar, K. Raghavendra

    2016-04-01

    Black carbon (BC) plays an important role on the global and regional climate, whereas there are significant uncertainties on its optical properties. Among various optical properties, the Ångström exponent (AE) indicates the spectral variation of the particle-optic interaction and is widely used to understand the aerosol properties. We consider the influence of BC geometry on its optical properties and assess the sensitivity of the AE to particle geometry and size distribution. The fractal aggregates with different fractal dimensions are used to represent realistic BC particles, and popular equivalent volume spherical and spheroidal models are also considered for comparison. Even if the fractal aggregates become highly compact and spherical, their optical properties are still significantly different from those of equivalent volume spheres or spheroids. Meanwhile, the Rayleigh-Debye-Gans approximation can hardly provide accurate results for all optical quantities of aggregates with different dimensions. The extinction Ångström exponent (EAE) and absorption Ångström exponent (AAE) are sensitive to both particle geometry and size distribution. With BC becoming more compact (from fractal aggregate to spheroid and to sphere), the AE becomes more sensitive to particle size distribution. The EAE and AAE of aggregates with different size distributions vary between 1.10-1.63 and 0.87-1.50, respectively, whereas those of the spheres or spheroids have wider ranges. Furthermore, the AE at smaller wavelengths (between 0.35 µm and 0.55 µm) is more sensitive to geometry and size distribution than that given by optical properties at larger wavelengths (between 0.55 µm and 0.88 µm).

  3. The influence of different black carbon and sulfate mixing methods on their optical and radiative properties

    Science.gov (United States)

    Zhang, Hua; Zhou, Chen; Wang, Zhili; Zhao, Shuyun; Li, Jiangnan

    2015-08-01

    Three different internal mixing methods (Core-Shell, Maxwell-Garnett, and Bruggeman) and one external mixing method are used to study the impact of mixing methods of black carbon (BC) with sulfate aerosol on their optical properties, radiative flux, and heating rate. The optical properties of a mixture of BC and sulfate aerosol particles are considered for three typical bands. The results show that mixing methods, the volume ratio of BC to sulfate, and relative humidity have a strong influence on the optical properties of mixed aerosols. Compared to internal mixing, external mixing underestimates the particle mass absorption coefficient by 20-70% and the particle mass scattering coefficient by up to 50%, whereas it overestimates the particle single scattering albedo by 20-50% in most cases. However, the asymmetry parameter is strongly sensitive to the equivalent particle radius, but is only weakly sensitive to the different mixing methods. Of the internal methods, there is less than 2% difference in all optical properties between the Maxwell-Garnett and Bruggeman methods in all bands; however, the differences between the Core-Shell and Maxwell-Garnett/Bruggeman methods are usually larger than 15% in the ultraviolet and visible bands. A sensitivity test is conducted with the Beijing Climate Center Radiation transfer model (BCC-RAD) using a simulated BC concentration that is typical of east-central China and a sulfate volume ratio of 75%. The results show that the internal mixing methods could reduce the radiative flux more effectively because they produce a higher absorption. The annual mean instantaneous radiative force due to BC-sulfate aerosol is about -3.18 W/m2 for the external method and -6.91 W/m2 for the internal methods at the surface, and -3.03/-1.56/-1.85 W/m2 for the external/Core-Shell/(Maxwell-Garnett/Bruggeman) methods, respectively, at the tropopause.

  4. Scavenging of biomass burning refractory black carbon and ice nuclei in a Western Pacific extratropical storm

    Directory of Open Access Journals (Sweden)

    J. L. Stith

    2011-01-01

    Full Text Available In situ airborne sampling of refractory black carbon (rBC particles and Ice Nuclei (IN was conducted in and near an extratropical cyclonic storm in the Western Pacific Ocean during the Pacific Dust Experiment, PACDEX, in the spring of 2007. Airmass origins were from Eastern Asia. Cloud hydrometeors were evaporated by a counterflow virtual impactor and the residue was sampled by a single particle soot photometer (SP2 instrument and a continuous flow diffusion chamber ice nucleus detector. Clouds associated primarily with the warm sector of the storm were sampled at various locations and altitudes. In storm midlevels at temperatures where heterogeneous freezing is expected to be significant (here −24 to −29 °C, IN measurements from ice particle residues generally agreed well with simultaneous measurements of total ice concentrations provided that the measurements were made at ambient temperatures similar to those in the CFDC chamber, suggesting heterogeneous freezing as the dominant ice formation process in the mid levels of these warm sector clouds. Lower in the storm, at warmer temperatures (−22 to −6.4 °C, ice particle concentrations were similar to IN concentrations at CFDC chamber temperatures representative of colder temperatures. This is consistent with ice particles forming at storm mid-levels by heterogeneous freezing on IN, followed by sedimentation to lower altitudes. Homogeneous freezing did not appear to contribute significantly to midlevel ice concentrations and rime-splintering was also unlikely due to the absence of significant supercooled liquid water in the warm sector clouds. IN number concentrations were typically about a~factor of five to ten lower than simultaneous measurements of rBC concentrations in cloud.

  5. Particle transport in magnetized media around black holes and associated radiation

    CERN Document Server

    Vieyro, Florencia L

    2012-01-01

    Galactic black hole coronae are composed of a hot, magnetized plasma. The spectral energy distribution produced in this component of X-ray binaries can be strongly affected by different interactions between locally injected relativistic particles and the matter, radiation and magnetic fields in the source. We study the non-thermal processes driven by the injection of relativistic particles into a strongly magnetized corona around an accreting black hole. We compute in a self-consistent way the effects of relativistic bremsstrahlung, inverse Compton scattering, synchrotron radiation, and the pair-production/annihilation of leptons, as well as hadronic interactions. Our goal is to determine the non-thermal broadband radiative output of the corona. The set of coupled kinetic equations for electrons, positrons, protons, and photons are solved and the resulting particle distributions are computed self-consistently. The spectral energy distributions of transient events in X-ray binaries are calculated, as well as t...

  6. Effect Of Black Carbon Radiative Heating On Cloud Microphysics Over Indo-Gangetic Basin

    Science.gov (United States)

    Ghosh, A.; Tripathi, S. N.

    2008-12-01

    Airborne black carbon (BC), the most significant particulate absorber of solar radiation in the atmosphere, is an important contributor to both global and regional-scale climate forcing (Tripathi et al., 2005). In context of cloud microphysics, freshly emitted pure BC particles are hydrophobic (i.e., bad cloud condensation nuclei (CCN)). However, exposure in the atmosphere may transform BC to a hydrophilic state if these particles are coated with additional materials, such as sulfate and organic carbon (OC). In a recent study, Conant et al. (2002) has examined the effect of radiative heating of BC on the critical supersaturation spectrum of internally mixed aerosols. Two main uncertainties introduced in this work are due to lack of knowledge of actual state of mixing and realistic distributions of different aerosol species. Indo-Gangetic Basin (IGB) in the northern India is one of the most polluted regions in the world. The cloud microphysical processes in IGB are very complex and it requires an in depth investigation for understanding of the aerosol-cloud interaction in the region (Tripathi, et al., 2007). In the present work, an attempt has been made to study the effect of radiative heating due to BC particles coated with hydrophilic materials on cloud microphysics over IGB. For this purpose, we have used (a) a two-layer radiative parameter model based on Mie theory (Toon and Ackerman, 1981) to calculate the particle (monodisperse) absorption cross section; (b) a three-dimensional (3D) radiative transfer model, the spherical harmonics discrete ordinate method (SHDOM) (Evans,1998), which assumes a tropical continental atmosphere, to simulate the 3D spectral actinic flux over the study region; and (c) Extended Köhler theory (Conant et al., 2002) to simulate the effect the BC radiative heating on cloud droplet activation. The solar wavelength spectrum used ranges from 0.2 to 5 micrometer. Following the in situ measurements and modeling studies on mixing state (Dey

  7. Ultraviolet Spectroscopy of Matrix-isolated Amorphous Carbon Particles

    Science.gov (United States)

    Schnaiter, M.; Mutschke, H.; Henning, Th.; Lindackers, D.; Strecker, M.; Roth, P.

    1996-06-01

    In view of the interstellar 217.5 nm and the circumstellar 230--250 nm extinction features, the UV extinction behavior of small matrix-isolated amorphous carbon grains is investigated experimentally. The particles were produced in a flame by burning acetylene with oxygen at low pressure. To prevent coagulation, the condensing primary soot grains (average diameter ~6 nm) were extracted by a molecular beam technique into a high-vacuum chamber. There they were deposited into a layer of solid argon, isolated from each other. The particle mass and size were controlled using a particle mass spectrometer. The measured UV extinction of the matrix-isolated particles is compared with measurements on samples produced in the conventional way by collecting carbon smoke on substrate as well as with scattering calculations for small spheres and ellipsoides. The laboratory data give a good representation of the circumstellar extinction feature observed in the spectrum of V348 Sgr.

  8. Evaluating the climate impacts of stratospheric Sulphate, Titania and Black-Carbon injection scenarios using HadGEM2-CCS

    Science.gov (United States)

    Jones, Anthony; Haywood, James; Jones, Andy; Hardimann, Steven

    2015-04-01

    Stratospheric Aerosol Injection (SAI) has emerged as a possible method for ameliorating future global warming. Although most SAI modelling studies have simulated Sulphate injection scenarios (in-line with the natural analogue of volcanic eruptions), various research has identified advantages of using alternative aerosols to sulphate (e.g. Tang et al 2014). In particular, minerals with optimal refractive indices (such as Titania) and sunlight-absorbing aerosols (such as Black-Carbon) have been identified as candidate particles. In this talk, I will present the results of 80-year integrations of HadGEM2-CCS (N96L60) with injection of either sulphate, titania or black-carbon initiated in 2020 and continued until 2100. Aerosol is injected at such a rate as to balance top of the atmosphere (TOA) radiative fluxes in the RCP8.5 scenario, akin to the G3 design of the GeoMIP project. I will compare the climate changes in the baseline scenario (RCP8.5) with the geoengineering scenarios for the 2090s period, and attribute these changes to optical properties of the aerosol species used. Stratospheric dynamical and radiative changes impact the underlying tropical overturning circulation, affecting precipitation, with the magnitude and distribution of impacts dependent on the aerosol species used. Black carbon in particular causes stratospheric heating of >40K, impacting the hydrological cycle and reducing global mean annual precipitation by ~0.25mm/day compared to a historical period. The efficiency of solar-absorption by black carbon means that the injection-rate required to balance TOA fluxes in RCP8.5 is shown to be approximately 1/20th of the mass needed of sulphate and 1/5th of the mass needed of titania. Despite similar global-mean temperature evolution in the geoengineering scenarios (a relative stabilisation), the distribution of high-latitude residual warming and tropical cooling in the sulphate and titania simulations is opposite to the high-latitude cooling and low

  9. Global emission inventory and atmospheric transport of black carbon. Evaluation of the associated exposure

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Rong

    2015-06-01

    This thesis presents research focusing on the improvement of high-resolution global black carbon (BC) emission inventory and application in assessing the population exposure to ambient BC. A particular focus of the thesis is on the construction of a high-resolution (both spatial and sectorial) fuel consumption database, which is used to develop the emission inventory of black carbon. Above all, the author updates the global emission inventory of black carbon, a resource subsequently used to study the atmospheric transport of black carbon over Asia with the help of a high-resolution nested model. The thesis demonstrates that spatial bias in fuel consumption and BC emissions can be reduced by means of the sub-national disaggregation approach. Using the inventory and nested model, ambient BC concentrations can be better validated against observations. Lastly, it provides a complete uncertainty analysis of global black carbon emissions, and this uncertainty is taken into account in the atmospheric modeling, helping to better understand the role of black carbon in regional and global air pollution.

  10. Challenges for Reducing Emissions of Black Carbon from the Transport Sector in Urban Areas

    Science.gov (United States)

    Zavala, M. A.; Molina, L. T.

    2013-05-01

    The transport sector is a large contributor of harmful gaseous and particulate emissions in many urban areas. Black carbon is a component of short-lived particulate matter emitted predominantly by freight, public transport, and heavy- duty trucks. Controlling the emissions of black carbon from the transport sector is important for mitigating its impacts on climate, ecosystems, and human health. However, reducing the emissions of black carbon from mobile sources may be a challenging task in many developing urban areas due to economic, social, and technical constrains. Several emissions control technologies offer a proven approach for reducing emissions of black carbon from diesel-powered mobile sources, but the accurate quantification of associated emissions benefits in developing urban areas is not well documented. We describe recent advances for the estimation of black carbon emissions from the transport sector in real world driving conditions and present examples of the potential benefits of implementing various emission control technologies in Mexico. The results can help in the identification of key factors that hinder the implementation of control emissions for reducing emissions of black carbon elsewhere.

  11. Measurement of Black Carbon and Co-pollutants Emitted from Diesel Vehicles in Mexico

    Science.gov (United States)

    Zavala, M. A.; Molina, L. T.; Fortner, E.; Herndon, S.; Knighton, B.; Yacovitch, T. I.; Floerchinger, C. R.; Roscioli, J. R.; Kolb, C. E.; Paramo, V. H.; Zirath, S.; Mejia, J.; Jazcilevich, A. D.

    2013-12-01

    Freight, public transport, and heavy-duty trucks can contribute to harmful emissions of black carbon and other co-pollutants in many urban areas. Controlling the emissions of black carbon from the transport sector is important for the potential of mitigating its impacts on climate, ecosystems, and human health. However, reducing the emissions of black carbon from mobile sources is be a challenging task in many developing urban areas due to economic, social, and technical constrains, as well as the uncertainties surrounding the accurate quantification of the associated benefits. Several emissions control technologies offer a proven approach for reducing emissions of black carbon from diesel-powered mobile sources, but the accurate quantification of associated emissions benefits in developing urban areas is not well documented. We present the results of the measurement of black carbon and co-emitted pollutants of dozens of diesel powered vehicles, including freight trucks, public transport buses, and intra-city metrobuses sampled during a 4-day experiment in Mexico City in February of 2013 as part of the SLCFs-Mexico project. Measurements were obtained with the Aerodyne Mobile Laboratory, remote sensing, and portable emissions measurements, and encompassed the sampling of several vehicle models and technologies in experimental and real-world driving conditions. The results can help in the identification of key factors that hinder the implementation of control emissions for reducing emissions of black carbon elsewhere and the potential benefits of implementing various emission control technologies.

  12. The nature of carbon material in the black shale rock mass of Kazakhstan

    Energy Technology Data Exchange (ETDEWEB)

    Marchenko, L.G.

    1981-01-01

    Carbon material is closely tied to ores of various origin lying in the carbon (black shale) rock masses of Kazakhastan. The nature of the carbon material in several gold fields is closely examined. Shungite, its paragenesis with ore materials and its role in the carbon and ore material processes, is described. The accumulation of shungite in zones determined to consist of ores, is looked at in terms of prospecting criteria.

  13. Energy extraction and particle acceleration around a rotating black hole in quintessence

    Science.gov (United States)

    Oteev, Tursinbay; Abdujabbarov, Ahmadjon; Stuchlík, Zdeněk; Ahmedov, Bobomurat

    2016-08-01

    We study motion and collision of particles in the gravitational field of rotating black hole immersed in quintessential dark energy characterized with the quintessential parameter ωqin(-1;-1/3) governing the equation of state of the dark energy, and the dimensionless quintessential field parameter tilde{c}. We focus on the acceleration of particles due to collisional processes and show how the center of mass energy depends on the quintessential field parameter tilde{c}. We also make comparison of the obtained results to the collisional energetics of quintessential static black holes demonstrating the crucial role of the rotation parameter a in the particle acceleration. Finally we study the dependence of the maximal value of the efficiency of energy extraction through Penrose process for rotating black hole with quintessential field parameter tilde{c}. It is found that quintessence field decreases the energy extraction efficiency through Penrose process and when the parameter tilde{c} vanishes one can get the standard value of the efficiency coefficient for the Kerr black hole as η˜ 21 %.

  14. Are emissions of black carbon from gasoline vehicles overestimated? Real-time, in situ measurement of black carbon emission factors.

    Science.gov (United States)

    Wang, Yang; Xing, Zhenyu; Zhao, Shuhui; Zheng, Mei; Mu, Chao; Du, Ke

    2016-03-15

    Accurately quantifying black carbon (BC) emission factors (EFs) is a prerequisite for estimation of BC emission inventory. BC EFs determined by measuring BC at the roadside or chasing a vehicle on-road may introduce large uncertainty for low emission vehicles. In this study, BC concentrations were measured inside the tailpipe of gasoline vehicles with different engine sizes under different driving modes to determine the respective EFs. BC EFs ranged from 0.005-7.14 mg/kg-fuel under the speeds of 20-70 km/h, 0.05-28.95 mg/kg-fuel under the accelerations of 0.5-1.5m/s(2). Although the water vapor in the sampling stream could result in an average of 12% negative bias, the BC EFs are significantly lower than the published results obtained with roadside or chasing vehicle measurement. It is suggested to conduct measurement at the tailpipe of gasoline vehicles instead of in the atmosphere behind the vehicles to reduce the uncertainty from fluctuation in ambient BC concentration.

  15. A New Method to Study Hawking Radiation of Charged Particle from Stationary Axisymmetric Sen Black Hole

    Science.gov (United States)

    Yang, Shu-Zheng; Chen, De-You

    2007-01-01

    Taking the self-gravitation interaction and energy conservation, charge conservation and angular momentum conservation into account, we discuss the tunnelling characteristics of the charged particle from Sen black hole by the Hamilton-Jacobi method. The result shows that the tunnelling probability is related to the change of Bekenstein-Hawking entropy, and the actual radiation spectrum deviates from the pure thermal one, which is consistent with the result of Parikh and Wilczek and gives a new method to correct the Hawking pure thermal spectrum of Sen black hole.

  16. Charged Massive Particle's Tunneling From Charged Non-Rotating Micro Black Hole

    CERN Document Server

    Soleimani, M J; Radiman, Shahidan; Abdullah, W A T Wan

    2015-01-01

    In the tunneling framework of Hawking radiation, charged massive particle's tunneling in charged non-rotating TeV-Scale black hole is investigated. To this end, we consider natural cutoffs as a minimal length, a minimal momentum, and a maximal momentum through a generalized uncertainty principle. We focus on the role played by these natural cutoffs on the luminosity of charged non-rotating micro black hole by taking into account the full implications of energy and charge conservation as well as the back- scattered radiation.

  17. Spinor particle creation in near extremal Reissner-Nordström black holes

    Science.gov (United States)

    Chen, Chiang-Mei; Sun, Jia-Rui; Tang, Fu-Yi; Tsai, Ping-Yen

    2015-10-01

    The pair production of spinor particles, which can be captured by the solution of the Dirac equation with an appropriate boundary condition, in charged black holes is investigated. We obtain the closed form of the production rate in the near extremal limit of Reissner-Nordström black holes. The cosmic censorship conjecture is seemingly guaranteed by the pair production process. Moreover, the absorption cross section ratio and retarded Green’s functions of the spinor fields calculated from the gravity side match well with those of spinor operators in the dual conformal field theory (CFT) side.

  18. A New Method to Study Hawking Radiation of Charged Particle from Stationary Axisymmetric Sen Black Hole

    Institute of Scientific and Technical Information of China (English)

    YANG Shu-Zheng; CHEN De-You

    2007-01-01

    @@ Taking the self-gravitation interaction and energy conservation, charge conservation and angular momentum conservation into account, we discuss the tunnelling characteristics of the charged particle from Sen black hole by the Hamilton-Jacobi method. The result shows that the tunnelling probability is related to the change of Bekenstein-Hawking entropy, and the actual radiation spectrum deviates from the pure thermal one, which is consistent with the result of Parikh and Wilczek and gives a new method to correct the Hawking pure thermal spectrum of Sen black hole.

  19. Spinor Particle Creation in Near Extremal Reissner-Nordstrom Black Holes

    CERN Document Server

    Chen, Chiang-Mei; Tang, Fu-Yi; Tsai, Ping-Yen

    2014-01-01

    The pair production of spinor particles, which is captured by the solution of the Dirac equation with an appropriate boundary condition, in charged black holes is investigated. We obtain the closed form of the production rate in the near extremal limit of the Reissner-Nordstrom black holes. The cosmic censorship conjecture is guaranteed by the pair production process. Moreover, the absorption cross section ratio and retarded Green's functions of the spinor fields calculated from the gravity side match well with those of spinor operators in the dual CFT side.

  20. Fermion tunneling of charged particles from a non-static black hole in de Sitter space

    Institute of Scientific and Technical Information of China (English)

    Li Hui-Ling; Yang Shu-Zheng

    2009-01-01

    Introducing a new coordinate system and choosing a set of appropriate matrices γ~μ, this paper attempts to investigate the fermion tunneling of charged particles across the event horizon from the Vaidya-Bonner de Sitter black hole. The result shows that the tunneling rate of the non-static black hole is related not only to the change of Bekenstein-Hawking entropy but also to the integral of the changing horizon, which violates unitary theory and is different from the stationary case.

  1. Quantification and radiocarbon source apportionment of black carbon in atmospheric aerosols using the CTO-375 method

    Science.gov (United States)

    Zencak, Zdenek; Elmquist, Marie; Gustafsson, Örjan

    To make progress towards linking the atmosphere and biogeosphere parts of the black carbon (BC) cycle, a chemothermal oxidation method (CTO-375), commonly applied for isolating BC from complex geomatrices such as soils, sediments and aquatic particles, was applied to investigate the BC also in atmospheric particles. Concentrations and 14C-based source apportionment of CTO-375 based BC was established for a reference aerosol (NIST RM-8785) and for wintertime aerosols collected in Stockholm and in a Swedish background area. The results were compared with thermal-optical (OC/EC) measurements. For NIST RM-8785, a good agreement was found between the BC CTO-375 concentration and the reported elemental carbon (EC) concentration measured by the "Speciation Trends Network—National Institute of Occupational Safety and Health" method (EC NIOSH) with BC CTO-375 of 0.054±0.002 g g -1 and EC NIOSH of 0.067±0.008 g g -1. In contrast, there was an average factor of ca. 20 difference between BC CTO-375 and EC NIOSH for the ambient Scandinavian wintertime aerosols, presumably reflecting a combination of BC CTO-375 isolating only the recalcitrant soot-BC portion of the BC continuum and the EC NIOSH metric inadvertently including some intrinsically non-pyrogenic organic matter. Isolation of BC CTO-375 with subsequent off-line radiocarbon analysis yielded fraction modern values (fM) for total organic carbon (TOC) of 0.93 (aerosols from a Swedish background area), and 0.58 (aerosols collected in Stockholm); whereas the fM for BC CTO-375 isolates were 1.08 (aerosols from a Swedish background area), and 0.87 (aerosols collected in Stockholm). This radiocarbon-based source apportionment suggests that contribution from biomass combustion to cold-season atmospheric BC CTO-375 in Stockholm was 70% and in the background area 88%.

  2. Impacts of black carbon and co-pollutant emissions from transportation sector in Mexico City

    Science.gov (United States)

    Zavala, Miguel; Almanza, Victor; Garcia, Agustin; Jazcilevich, Aron; Lei, Wenfang; Molina, Luisa

    2016-04-01

    Black carbon is one of the most important short-lived climate-forcing agents, which is harmful to human health and also contributes significantly to climate change. Transportation is one of the largest sources of black carbon emissions in many megacities and urban complexes, with diesel vehicles leading the way. Both on-road and off-road vehicles can emit substantial amounts of harmful BC-containing particulate matter (PM) and are also responsible for large emissions of carbon dioxide (CO2), carbon monoxide (CO), nitrogen oxides (NOx), and many other co-emitted volatile organic compounds (VOCs). Regionally, black carbon emissions contributions from mobile sources may vary widely depending on the technical characteristics of the vehicle fleet, the quality and chemical properties of the fuels consumed, and the degree of local development and economic activities that foster wider and more frequent or intensive use of vehicles. This presentation will review and assess the emissions of black carbon from the on-road and off-road transportation sector in the Mexico City Metropolitan Area. Viable mitigation strategies, including innovative technological alternatives to reduce black carbon and co-pollutants in diesel vehicles and their impacts on climate, human health and ecosystems will be described.

  3. 20 years of Black Carbon measurements in Germany

    Science.gov (United States)

    Kutzner, Rebecca; Quedenau, Jörn; Kuik, Friderike; von Schneidemesser, Erika; Schmale, Julia

    2016-04-01

    Black Carbon (BC) is an important short-lived climate-forcing pollutant contributing to global warming through absorption of sunlight. At the same time, BC, as a component of particulate matter (PM) exerts adverse health effects, like decreased lung function and exacerbated asthma. Globally, anthropogenic emission sources of BC include residential heating, transport, and agricultural fires, while the dominant natural emission sources are wildfires. Despite the various adverse effects of BC, legislation that requires mandatory monitoring of BC concentrations does not currently exist in the European Union. Instead, BC is only indirectly monitored as component of PM10 and PM2.5 (particulate matter with a diameter smaller 10 μm and 2.5 μm). Before the introduction of mandatory PM10 and PM2.5 monitoring in the European Union in 2005 and 2015, respectively, 'black smoke', a surrogate for BC, was a required measurement in Germany from the early 1990s. The annual mean limit value was 14 μg m-3 from 1995 and 8 μg m-3 from 1998 onwards. Many 'black smoke' measurements were stopped in 2004, with the repeal of the regulations obtaining at the time. However, in most German federal states a limited number BC monitoring stations continued to operate. Here we present a synthesis of BC data from 213 stations across Germany covering the period between 1994 and 2014. Due to the lack of a standardized method and respective legislation, the data set is very heterogeneous relying on twelve different measurement methods including chemical, optical, and thermal-optical methods. Stations include locations classified as background, urban-background, industrial and traffic among other types. Raw data in many different formats has been modelled and integrated in a relational database, allowing various options for further data analysis. We highlight results from the year 2009, as it is the year with the largest measurement coverage based on the same measurement method, with 30 stations. In

  4. Modeling the impact of black carbon on snowpack properties at an high altitude site in the Himalayas

    Science.gov (United States)

    Jacobi, Hans-Werner; Ménégoz, Martin; Gallée, Hubert; Lim, Saehee; Zanatta, Marco; Jaffrezo, Jean-Luc; Cozic, Julie; Laj, Paolo; Bonasoni, Paolo; Cristofanelli, Paolo; Stocchi, Paolo; Marinoni, Angela; Verza, Gianpietro; Vuillermoz, Elisa

    2013-04-01

    Light absorbing aerosols in the snow can modify the snow albedo. As a result, the seasonal snowpack can melt earlier compared to the unaffected snow leading to a warming effect on the atmosphere. Several global model studies have indicated that the long-range transport of light absorbing aerosols into the Himalayas and the subsequent deposition to the snow have contributed to a temperature rise in these regions. Due to its strong light absorbing properties, black carbon (BC) may play an important role in this process. To evaluate the possible impact of BC on snow albedo we determined BC concentrations in a range of fresh and older snow samples collected between 2009 and 2012 in the vicinity of the Pyramid station, Nepal at an altitude of more than 5000 m. BC concentrations in the snow were obtained after nebulizing the melted samples using a single particle soot photometer. The observed seasonal cycle in BC concentrations in the snow corresponds to observed seasonal cycles in atmospheric BC detected at the Pyramid station. Older snow showed somewhat higher concentrations compared to fresh snow samples indicating the influence of dry deposition of BC. In order to study in detail the impact of black carbon on snow properties, we upgraded the existing one-dimensional physical snowpack model CROCUS to account for the influence of black carbon on the absorption of radiation by the snow. A radiative transfer scheme was implemented into the snowpack model taking into account the solar zenith angle, the snow water equivalent and grain size, the soil albedo, and the concentration of black carbon in the snow. The upgraded model was applied to a high altitude site in the Himalayas using observed BC concentrations and meteorological data recorded at Pyramid station. First results of the simulations will be presented.

  5. Characteristics of Black Carbon Aerosol during the Chinese Lunar Year and Weekdays in Xi’an, China

    Directory of Open Access Journals (Sweden)

    Qiyuan Wang

    2015-02-01

    Full Text Available Black carbon (BC aerosol plays an important role in climate forcing. The net radiative effect is strongly dependent on the physical properties of BC particles. A single particle soot photometer and a carbon monoxide analyser were deployed during the Chinese Lunar Year (CLY and on weekdays at Xi’an, China, to investigate the characteristics of refractory black carbon aerosol (rBC. The rBC mass on weekdays (8.4 μg·m−3 exceeds that during the CLY (1.9 μg·m−3, presumably due to the lower anthropogenic emissions during the latter. The mass size distribution of rBC shows a primary mode peak at ~205 nm and a small secondary mode peak at ~102-nm volume-equivalent diameter assuming 2 g·cm−3 in void-free density in both sets of samples. More than half of the rBC cores are thickly coated during the CLY (fBC = 57.5%; the percentage is slightly lower (fBC = 48.3% on weekdays. Diurnal patterns in rBC mass and mixing state differ for the two sampling periods, which are attributed to the distinct anthropogenic activities. The rBC mass and CO mixing ratios are strongly correlated with slopes of 0.0070 and 0.0016 μg·m−3·ppbv−1 for weekdays and the CLY, respectively.

  6. Sources of uncertainties in modelling black carbon at the global scale

    Directory of Open Access Journals (Sweden)

    E. Vignati

    2010-03-01

    Full Text Available Our understanding of the global black carbon (BC cycle is essentially qualitative due to uncertainties in our knowledge of its properties. This work investigates two source of uncertainties in modelling black carbon: those due to the use of different schemes for BC ageing and its removal rate in the global Transport-Chemistry model TM5 and those due to the uncertainties in the definition and quantification of the observations, which propagate through to both the emission inventories, and the measurements used for the model evaluation.

    The schemes for the atmospheric processing of black carbon that have been tested with the model are (i a simple approach considering BC as bulk aerosol and a simple treatment of the removal with fixed 70% of in-cloud black carbon concentrations scavenged by clouds and removed when rain is present and (ii a more complete description of microphysical ageing within an aerosol dynamics model, where removal is coupled to the microphysical properties of the aerosol, which results in a global average of 40% in-cloud black carbon that is scavenged in clouds and subsequently removed by rain, thus resulting in a longer atmospheric lifetime. This difference is reflected in comparisons between both sets of modelled results and the measurements. Close to the sources, both anthropogenic and vegetation fire source regions, the model results do not differ significantly, indicating that the emissions are the prevailing mechanism determining the concentrations and the choice of the aerosol scheme does not influence the levels. In more remote areas such as oceanic and polar regions the differences can be orders of magnitude, due to the differences between the two schemes. The more complete description reproduces the seasonal trend of the black carbon observations in those areas, although not always the magnitude of the signal, while the more simplified approach underestimates black carbon concentrations by orders of

  7. Carbon in Comet Halley dust particles

    Science.gov (United States)

    Fomenkova, M. N.; Chang, S.

    1994-01-01

    Comets are small bodies of the solar system containing primarily a mixture of frozen gases and carbonaceous and mineral grains. They are likely to preserve volatile mineral from cold regions of the protosolar nebula and remnants of interstellar dust and gas. More than 2500 mass spectra of cometary grains with masses in the range 5 x 10 exp -17 to 5 x 10 exp -12 g were measured in situ by PUMA1 and PUMA2 mass spectrometers on board the VEGA spacecraft during flyby missions to Comet Halley. In this paper, we discuss different organic and inorganic C-containing components discovered so far in Comet Halley dust particles, the nature and abundance of which provide information about possible astrophysical sources of C and constrain models of interstellar grains.

  8. Cellphones as a Distributed Platform for Black Carbon Data Collection

    Science.gov (United States)

    Ramanathan, N.; Ramana, M.; Lukac, M. L.; Siva, P.; Ahmed, T.; Kar, A.; Rehman, I.; Ramanathan, V.

    2010-12-01

    Black carbon (BC), the visible component of soot that gives emissions such as diesel engine exhaust their dark color, has come to be recognized as a major contributor to global warming, and a frontline concern for climate change strategies (Ramanathan 2001, Jacobson 2010). We have developed a new low-cost instrument for gathering and measuring atmospheric BC concentrations that leverages cellphones to transmit data from an air filtration unit to a centralized database for analysis. Our new system relies on image processing techniques, as opposed to other more expensive optical methods, to interpret images of filters captured with a cellphone camera. As a result, the entire system costs less than $500 (and is orders of magnitude cheaper than an Aethalometer, the prevailing method for measuring atmospheric BC). We are working with three community groups in Los Angeles, and will recruit three groups in the San Francisco Bay Area, to enable 40 citizens to be actively engaged in monitoring BC across California. We are working with The Energy Resources Institute, an international NGO based in India, to deploy this instrument with 60 people in conjunction with Project Surya, which aims to deploy clean cookstoves and rigorously evaluate their impact on BC emissions. Field tests of this new instrument performed in California report an average error of 0.28 µg/m3 when compared with an Aethelometer. These excellent results hold the promise of making large-scale data collection of BC feasible and relatively easy to reproduce (Ramanathan et al., forthcoming). The use of cellphones for data collection permits monitoring of BC to occur on a greater, more comprehensive scale not previously possible, and serves as a means of instituting more precise, variation-sensitive evaluations of emissions. By storing the data in a publicly available repository, our system will provide real-time access to mass-scale BC measurements to researchers and the public. Through our pilot

  9. Origin of black carbon concentration peaks in Cairo (Egypt)

    Energy Technology Data Exchange (ETDEWEB)

    Mahmoud, K.F.; Wahab, M.M.A. [Cairo Univ, Fac Sci, Astron and Meteorol Dept, Giza (Egypt); Alfaro, S.C. [Univ Paris 12, LISA, F-94010 Creteil, (France); Alfaro, S.C. [Univ Paris 07, CNRS, F-94010 Creteil (France); Favez, O.; Sciare, J. [CEA Saclay, DSM, LSCE IPSL, Lab mixte CEA-CNRS-UVSQ, F-91191 Gif Sur Yvette (France)

    2008-07-01

    The concentration in black carbon (BC) has been monitored in the mega-city of Cairo (Egypt) during the autumn 2004 and spring 2005 intensive observation periods of the Cairo Aerosol Characterization Experiment (CACHE). As expected for a species released by human activities, hourly mean of this concentration is found to be large at all times. It is also significantly larger in autumn than in spring (9.9 {+-} 6.6 and 6.9 {+-} 4.8 {mu}gC/m{sup 3}, respectively) and quite variable at shorter (diurnal) time scales. Indeed, sharp concentration peaks larger than 25 {mu}gC/m{sup 3} are frequently detected during both observation periods. In order to apportion the roles played by emission intensity and meteorological conditions in the development of these peaks, a simple model is developed that allows derivation of the hourly mean BC emissions by the part of town located upwind of the measurement site. The analysis of the time dependence of these emissions indicates that traffic is by far the major source of BC in Cairo during daytime and this even in autumn when biomass burning takes place in the Nile delta. It is only between 03:00 and 05:00 in the night, at a time when traffic emissions are quite reduced, that the influence of this particular source on BC concentration can become significant. This study also indicates that BC emissions by motorized traffic remain important from the morning rush hour until late in the night. During the day, and particularly in spring, the dilution effect resulting from the development of the planetary boundary layer prevents BC concentrations from becoming very large. This is no longer the case just before sunrise and after sunset, when the combination of dense traffic and low boundary layer is responsible for the observed sharp increase in BC concentration. (authors)

  10. Black carbon concentration trends in Helsinki during 1996–2005

    Directory of Open Access Journals (Sweden)

    T. Pakkanen

    2007-10-01

    Full Text Available The black carbon (BC concentration trends were studied during ten years in Helsinki, Finland. Measurements were made in three campaigns between 1996 and 2005 at an urban area locating two kilometres from the centre of Helsinki. The first campaign was from November 1996 to June 1997, the second from September 2000 to May 2001 and the third from March 2004 to October 2005. In this study, only data from winter and spring months was analysed. The effect of traffic and meteorological variables on the measured BC concentrations was studied by means of a multiple regression analysis, where the meteorological data was obtained from a meteorological pre-processing model (MPP-FMI. During the ten years, the campaign median BC concentrations were found to decrease slightly from 1.11 to 1.00 μg m−3. The lowest campaign median concentration (0.93 μg m−3 was measured during the second campaign in 2000–2001, when also the lowest traffic rates were measured. The strongest decrease between campaigns 1 and 3 was observed during weekday daytimes, when the traffic rates are highest. The variables affecting the measured BC concentrations most were traffic, wind speed and mixing height. On weekdays, traffic had clearly the most important influence and on weekends the effect of wind speed diluted the effect of traffic. The affecting variables and their influence on the BC concentration were similar in winter and spring. The separate examination of the three campaigns showed that the effect of traffic on the BC concentrations had decreased during the studied years. This reduction was caused by cleaner emissions from vehicles, since between years 1996 and 2005 the traffic rates had increased. A rough estimate gave that vehicle number-scaled BC mass concentrations have decreased from 0.0028 to 0.0020 μg m−3 between campaigns 1 and 3.

  11. New Routes to Functionalize Carbon Black for Polypropylene Nanocomposites.

    Science.gov (United States)

    Shepherd, Céline; Hadzifejzovic, Emina; Shkal, Fatma; Jurkschat, Kerstin; Moghal, Jonathan; Parker, Emily M; Sawangphruk, Montree; Slocombe, Daniel R; Foord, John S; Moloney, Mark G

    2016-08-01

    Methods for chemical surface functionalization for carbon black (CB) nanoparticles were studied to produce (CB)/polypropylene (PP) nanocomposites with superior electrical and thermal properties. Nanoparticle dispersion is known to directly control the extent to which nanocomposites maximize the unique attributes of their nanoscale fillers. As a result, tailored nanoparticle surface chemistry is a widely utilized method to enhance the interfacial interactions between nanoparticles and polymer matrices, assisting improved filler dispersion. In this work, a rapid chemical functionalization approach using a number of diarylcarbene derivatives, followed by the azo-coupling of substituted diazonium salts, for the covalent introduction of selected functional groups to the CB surface, is reported. Characterization of the modified CB by XPS, TGA, CHN, and ATR-IR collectively confirmed surface functionalization, estimating surface grafting densities of the order of 10(13) and 10(14) molecules/cm(2). Nanocomposites, synthesized by solvent mixing PP with pristine and modified CB, demonstrated macroscopic property changes as a result of the nanoparticle surface functionalization. Pronounced improvements were observed for PP nanocomposites prepared with a dodecyl-terminated diaryl functionalized CB, in which TEM analysis established improved nanofiller dispersion owing to the enhanced CB-PP interfacial interactions in the nanocomposite. Observed dielectric relaxation responses at 20 wt % loading and a reduced percolation threshold realized conductivities of 1.19 × 10(-4) S cm(-1) at 10 wt %, compared to 2.62 × 10(-15) S cm(-1) for pristine CB/PP nanocomposites at the same filler loading. In addition, thermal properties signify an increase in the number of nucleation sites by the raised degree of crystallinity as well as increased melting and crystallization temperatures. PMID:27417277

  12. Speciation of the ionizable antibiotic sulfamethazine on black carbon (biochar).

    Science.gov (United States)

    Teixidó, Marc; Pignatello, Joseph J; Beltrán, José L; Granados, Mercè; Peccia, Jordan

    2011-12-01

    Adsorption of ionizable compounds by black carbon is poorly characterized. Adsorption of the veterinary antibiotic sulfamethazine (SMT; a.k.a., sulfadimidine; pK(a1) = 2.28, pK(a2) = 7.42) on a charcoal was determined as a function of concentration, pH, inorganic ions, and organic ions and molecules. SMT displayed unconventional adsorption behavior. Despite its hydrophilic nature (log K(ow) = 0.27), the distribution ratio K(d) at pH 5, where SMT(0) prevails, was as high as 10(6) L kg(-1), up to 10(4) times greater than literature reported K(oc). The K(d) decreases at high and low pH but not commensurate with the decline in K(ow) of the ionized forms. At pH 1, where SMT(+) is predominant and the surface is positive, a major driving force is π-π electron donor-acceptor interaction of the protonated aniline ring with the π-electron rich graphene surface, referred to as π(+)-π EDA, rather than ordinary electrostatic cation exchange. In the alkaline region, where SMT(-) prevails and the surface is negative, adsorption is accompanied by near-stoichiometric proton exchange with water, leading to the release of OH(-) and formation of an exceptionally strong H-bond between SMT(0) and a surface carboxylate or phenolate, classified as a negative charge-assisted H-bond, (-)CAHB. At pH 5, SMT(0) adsorption is accompanied by partial proton release and is competitive with trimethylphenylammonium ion, signifying contributions from SMT(+) and/or the zwitterion, SMT(±), which take advantage of π(+)-π EDA interaction and Coulombic attraction to deprotonated surface groups. In essence, both pK(a1) and pK(a2) increase, and SMT(±) is stabilized, in the adsorbed relative to the dissolved state. PMID:22026725

  13. Relationship between Black Carbon and heavy traffic in São Paulo, Brazil

    Science.gov (United States)

    Miranda, R. M.; Perez-Martinez, P.; Ribeiro, F. N. D.; Andrade, M. D. F.

    2015-12-01

    Carbonaceous aerosols play an important role in air quality, human health and global climate change. Black Carbon (BC) can be considered the most efficient light absorber in the visible spectrum and is mainly found in the fine fraction of aerosol. Typically is emitted by incomplete combustion of fossil fuels related to traffic, industrial processes and biomass burning. São Paulo Metropolitan Area (SPMA) with more than 19 million inhabitants, 7 million vehicles, as well as the major industrial and technological park of the country, has high concentrations of air pollutants, especially in the winter and vehicles are considered the principal source of particles emitted to the atmosphere. Since November 2014, Black Carbon and PM2.5 are being monitored using a MAAP (Multi Angle Absorption Photometer) Thermo 5012 and a Dust Trak DRX-8533 TSI in the East Campus of University of São Paulo, close to important highways and also to the largest airport of Brazil (Guarulhos Airport). Average BC concentration was 1.7 μg/m3 with some peaks above 17.0 μg/m3 and for PM2.5 average was 10.2 μg/m3. Particle concentrations reached values greater than the air quality standard (60 μg/m3) in the winter months. Winds coming from the East direction predominate. Traffic restrictions to heavy duty vehicles in the road-rings next to the sampling site during some hours of the day are the responsible for the daily BC and PM2.5 behavior (figure below), where high concentrations occur early in the morning and late at night, when heavy diesel vehicles are released for transit. Seasonal variations are different for BC and PM2.5 due to local sources of BC and meteorological conditions that have more influence on the particles. The weekly variation indicates that concentrations are lower on Sundays and higher from Tuesday to Thursday. Emission factors for BC were calculated based on traffic information.

  14. Engineering a novel material: Nanometric titanium carbide particles in a matrix of carbon nanotubes

    CERN Document Server

    BADIE, Sylvain

    2015-01-01

    New physics studies at ISOLDE are motivated by new beams available, especially beams of exotic nuclei located at the frontier of the nuclear chart. Such beams are often short lived (in the order of milliseconds) and decay before they can be extracted from the target material, where typical diffusion times are in the order of seconds or more. Novel nanostructured and nanocomposite target materials have been developed to increase the release efficiency by reducing the diffusion paths and so the diffusion times, allowing ISOLDE to deliver new and more intense beams of exotic nuclei. 35Ca (25 ms half-life) was attempted by developing a titanium carbide and carbon black nanocomposite, but such isotope could not be extracted. A different production method with different precursors - titanium oxide and multiwall carbon nanotubes - is here proposed and expected to yield a target material which will increase the release rates of such isotope. A novel material, very porous, consisting of titanium carbide particles disp...

  15. Hawking Radiation of Mass Generating Particles From Dyonic Reissner Nordstrom Black Hole

    CERN Document Server

    Sakalli, I

    2016-01-01

    The Hawking radiation is considered as a quantum tunneling process, which can be studied in the framework of the Hamilton-Jacobi method. In this study, we present the wave equation for a mass generating massive and charged scalar particle (boson). In sequel, we analyze the quantum tunneling of these bosons from a generic 4-dimensional spherically symmetric black hole. We apply the Hamilton-Jacobi formalism to derive the radial integral solution for the classically forbidden action which leads to the tunneling probability. To support our arguments, we take the dyonic Reissner-Nordstr\\"{o}m black hole as a test background. Comparing the tunneling probability obtained with the Boltzmann formula, we succeed to read the standard Hawking temperature of the dyonic Reissner-Nordstr\\"{o}m black hole.

  16. Hawking Radiation of Mass Generating Particles from Dyonic Reissner-Nordström Black Hole

    Science.gov (United States)

    Sakalli, I.; Övgün, A.

    2016-09-01

    The Hawking radiation is considered as a quantum tunneling process, which can be studied in the framework of the Hamilton-Jacobi method. In this study, we present the wave equation for a mass generating massive and charged scalar particle (boson). In sequel, we analyse the quantum tunneling of these bosons from a generic 4-dimensional spherically symmetric black hole. We apply the Hamilton-Jacobi formalism to derive the radial integral solution for the classically forbidden action which leads to the tunneling probability. To support our arguments, we take the dyonic Reissner-Nordström black hole as a test background. Comparing the tunneling probability obtained with the Boltzmann formula, we succeed in reading the standard Hawking temperature of the dyonic Reissner-Nordström black hole.

  17. Quasinormal ringing of Kerr black holes. II. Excitation by particles falling radially with arbitrary energy

    CERN Document Server

    Zhang, Zhongyang; Cardoso, Vitor

    2013-01-01

    The analytical understanding of quasinormal mode ringing requires an accurate knowledge of the Green's function describing the response of the black hole to external perturbations. We carry out a comprehensive study of quasinormal mode excitation for Kerr black holes. Relying on the formalism developed by Mano, Suzuki and Takasugi, we improve and extend previous calculations of the quasinormal mode residues in the complex frequency plane ("excitation factors" B_q). Using these results we compute the "excitation coefficients" C_q (essentially the mode amplitudes) in the special case where the source of the perturbations is a particle falling into the black hole along the symmetry axis. We compare this calculation with numerical integrations of the perturbation equations, and we show quantitatively how the addition of higher overtones improves the agreement with the numerical waveforms. Our results should find applications in models of the ringdown stage and in the construction of semianalytical template banks ...

  18. Hawking Radiation of Mass Generating Particles from Dyonic Reissner–Nordström Black Hole

    Indian Academy of Sciences (India)

    I. Sakalli; A Ovgun

    2016-09-01

    The Hawking radiation is considered as a quantum tunneling process, which can be studied in the framework of the Hamilton--Jacobi method. In this study, we present the wave equation for a mass generating massive and charged scalar particle (boson). In sequel, we analyse the quantum tunneling of these bosons from a generic 4-dimensional spherically symmetric black hole. We apply the Hamilton--Jacobi formalism to derive the radial integral solution for the classically forbidden action which leads to the tunneling probability. To support our arguments, we take the dyonic Reissner--Nordström black hole as a test background. Comparing the tunneling probability obtained with the Boltzmann formula, we succeed in reading the standard Hawking temperature of the dyonic Reissner–Nordström black hole.

  19. Comparison of manufactured and black carbon nanoparticle concentrations in aquatic sediments

    NARCIS (Netherlands)

    Koelmans, A.A.; Nowack, B.; Wiesner, M.

    2009-01-01

    In this paper, we show that concentrations of manufactured carbon-based nanoparticles (MCNPs) in aquatic sediments will be negligible compared to levels of black carbon nanoparticles (BCNPs). This is concluded from model calculations accounting for MCNP sedimentation fluxes, removal rates due to agg

  20. Effects of Black Carbon on Climate: Advances in Measurement and Modeling

    Science.gov (United States)

    Kondo, Y.

    2015-04-01

    Black carbon (BC) particles are non-spherical agglomerates consisting of hundreds or thousands of graphitic carbon spherules the diameters of which are about 15-50 nm. The spherules are graphitic in their molecular states and are, thus, strongly light-absorbing. BC particles are emitted by the incomplete combustion of carbon-based fossil fuels and biomass. BC mass in the atmosphere resides in agglomerates typically between 100 and 600 nm in diameter. They influence the global radiation budget by strongly absorbing solar radiation in the visible wavelengths and by changing the albedo of snow through deposition. Radiative forcing (RF) of BC is defined as the change in net radiative flux at the top of the atmosphere in W m-2 due to a change of BC between the pre-industrial time and present-day periods. The instantaneous direct radiative forcing of airborne BC particles (BC DRF), which does not include climate feedbacks, is determined by their absorption cross sections and spatial distributions. The distributions of BC are, in turn, controlled by its emission, dynamical transport, and loss during transport. The absorption cross section of BC is controlled by its optical properties (i.e., refractive index) and microphysical properties (size distribution, morphology, and mixing state). Because it is crucial to characterize these parameters, we first developed techniques to measure them accurately. Newly-developed BC measurement technologies constitute the firm basis of our studies. The techniques were applied to laboratory experiments and field observations of BC particles in air and rainwater. We also developed regional scale three-dimensional (3D) models to quantitatively interpret the observational results. One of the models calculates BC aging and optical/radiative processes explicitly without parameterizations. The reliable field measurements and model calculations of BC has enabled an improved understanding of the physical and chemical processes that control the

  1. Carbon dust particles in a beam-plasma discharge

    Science.gov (United States)

    Koval, O. A.; Vizgalov, V.; Shalpegin, A. V.

    2016-09-01

    This paper focuses on dynamics of micro-sized carbon dust grains in beam-plasma discharge (BPD) plasmas. It was demonstrated that injected dust particles can be captured and transported along the discharge. Longitudinal average velocity of the particles in the central area of the plasma column was 17 m/sec, and 2 m/sec in the periphery. Dust injection caused a decrease of emission intensity of metastable nitrogen molecular ion. This effect is suggested for a spectroscopy method for particles’ potential measurements. Five-micron radius carbon dust grains obtained potential above 500 V in the experiments on PR-2 installation, proving the feasibility of BPDs for the charging of fine dust particles up to high potential values, unattainable in similar plasma conditions.

  2. The role of carbon black/coal-tar pitch interactions in the early stage of carbonization

    Energy Technology Data Exchange (ETDEWEB)

    Menendez, R.; Fernandez, J.J.; Bermejo, J.; Cebolla, V.; Mochida, I.; Korai, Y. [Instituto Nacional del Carbon, Oviedo (Spain)

    1996-09-01

    A study was undertaken of the types of interaction between pitch and carbon black (CB) occurring during thermal treatment in the initial stages of carbonization, and the effects on subsequent coke structures. A commercial coal-tar pitch was blended with CB and thermally treated at temperatures between 400-450{degree}C, for 5 hours - except for 430{degree}C, for 10 hours. The same thermal treatments were applied in the absence of CB to test the effects of temperature alone. Parent and treated pitches were characterized by elemental analysis, optical microscopy, thermomechanical analysis and sequential solvent extraction. Some of the fractions were characterized by FTIR, GC and {sup 1}H-NMR. Cokes obtained at 900{degree}C were characterized by optical microscopy in terms of their porosity and optical texture. Results show that the type of CB/pitch interactions are temperature dependent, the interactions being more significant at lower temperatures. Hydrogenation and polymerization reactions have successively occurred alone the range of temperatures used. CB produced an increase of pitch carbon yield without affecting pitch fluidity at the lower temperatures. The effect on the reduction of coke porosity was pronounced at the initial stages of the treatment. Coke optical texture was affected by the presence of CB showing smaller sizes. 14 refs., 4 figs., 6 tabs.

  3. Angular profile of Particle Emission from a Higher-dimensional Black Hole: Analytic Results

    CERN Document Server

    Kanti, Panagiota

    2012-01-01

    During the spin-down phase of the life of a higher-dimensional black hole, the emission of particles on the brane exhibits a strong angular variation with respect to the rotation axis of the black hole. It has been suggested that this angular variation is the observable that could disentangle the dependence of the radiation spectra on the number of extra dimensions and angular momentum of the black hole. Working in the low-energy regime, we have employed analytical formulae for the greybody factors, angular eigenvalues and eigenfunctions of fermions and gauge bosons, and studied the characteristics of the corresponding angular profiles of emission spectra in terms of only a few dominant partial modes. We have confirmed that, in the low-energy channel, the emitted gauge bosons become aligned to the rotation axis of the produced black hole while fermions form an angle with the rotation axis whose exact value depends on the angular-momentum of the black hole. In the case of scalar fields, we demonstrated the exi...

  4. Central Asian supra-glacier snow melt enhanced by anthropogenic black carbon

    Science.gov (United States)

    Schmale, Julia; Flanner, Mark; Kang, Shichang; Sprenger, Michael; Farinotti, Daniel; Zhang, Qianggong; Guo, Junming; Li, Yang; Lawrence, Mark; Schwikowski, Margit

    2016-04-01

    In Central Asia, more than 60 % of the population depends on water stored in glaciers and mountain snow. Densely populated areas near lower-lying mountain ranges are particularly vulnerable and a recent study showed that the region might lose 50 % of its glacier mass by 2050. While temperature, precipitation and dynamic processes are key drivers of glacial change, deposition of light absorbing impurities such as mineral dust and black carbon can lead to accelerated melting through surface albedo reduction. Here, we discuss the origin of deposited mineral dust and black carbon and their impacts on albedo change and snow melt. 218 snow samples were taken on 4 glaciers, Abramov (Pamir), Suek, Glacier No. 354 and Golubin (Tien Shan), representing deposition between summer 2012 and 2014. They were analyzed for elemental carbon, mineral dust and iron among other parameters. We find the elemental carbon concentration to be at the higher end of the range reported for neighboring mountain ranges between 70 and 502 ng g-1 (interquartile range). To investigate the origin of the snow impurities, we used a Lagrangian particle dispersion model, LAGRANTO. Back trajectory ensembles of 40 members with varied starting points to capture the meteorological spread were released every 6 hours for the covered period at all sites. "Footprints" were calculated and combined with emission inventories to estimate the relative contribution of anthropogenic and natural BC to deposited aerosol on the glaciers. We find that more than 94 % of BC is of anthropogenic origin and the major source region is Central Asia followed by the Middle East. Further exploring the implications of mineral dust and BC deposition, we calculate the snow albedo reduction with the Snow-Ice-Aerosol-Radiative model (SNICAR). Even though mineral dust concentrations were up to a factor of 50 higher than BC concentrations, BC dominates the albedo reduction. Using these results we calculate the snow melt induced by

  5. Gravitational Radiation from the radial infall of highly relativistic point particles into Kerr black holes

    OpenAIRE

    Cardoso, Vitor(CENTRA, Departamento de F´ısica, Instituto Superior Técnico, Universidade de Lisboa — UL, Av. Rovisco Pais 1, 1049, Lisboa, Portugal); Lemos, José P. S.

    2002-01-01

    In this paper, we consider the gravitational radiation generated by the collision of highly relativistic particles with rotating Kerr black holes. We use the Sasaki-Nakamura formalism to compute the waveform, energy spectra and total energy radiated during this process. We show that the gravitational spectrum for high-energy collisions has definite characteristic universal features, which are independent of the spin of the colliding objects. We also discuss possible connections between these ...

  6. Scalar particles emission from black holes with topological defects using Hamilton-Jacobi method

    OpenAIRE

    Jusufi, Kimet

    2015-01-01

    We study quantum tunneling of charged and uncharged scalar particles from the event horizon of Schwarzschild-de Sitter and Reissner-Nordstr\\"{o}m-de Sitter black holes pierced by an infinitely long spinning cosmic string and a global monopole. In order to find the Hawking temperature and the tunneling probability we solve the Klein-Gordon equation by using the Hamilton-Jacobi method and WKB approximation. We show that Hawking temperature is independent of the presence of topological defects i...

  7. Hawking Radiation of Mass Generating Particles From Dyonic Reissner Nordstr\\"{o}m Black Hole

    OpenAIRE

    Sakalli, I.; Övgün, A.

    2016-01-01

    The Hawking radiation is considered as a quantum tunneling process, which can be studied in the framework of the Hamilton-Jacobi method. In this study, we present the wave equation for a mass generating massive and charged scalar particle (boson). In sequel, we analyze the quantum tunneling of these bosons from a generic 4-dimensional spherically symmetric black hole. We apply the Hamilton-Jacobi formalism to derive the radial integral solution for the classically forbidden action which leads...

  8. Hawking Radiation of Massive Vector Particles From Warped AdS$_{\\text{3}}$ Black Hole

    CERN Document Server

    Gursel, H

    2015-01-01

    Hawking radiation (HR) of massive vector particles from a rotating Warped Anti-de Sitter black hole in 2+1 dimensions (WAdS$_{\\text{3}}$BH) is studied in detail. The quantum tunneling approach with the Hamilton-Jacobi method (HJM) is applied in the Proca equation (PE), and we show that the radial function yields the tunneling rate of the outgoing particles. Comparing the result obtained with the Boltzmann factor, we satisfactorly reproduce the Hawking temperature (HT) of the WAdS$_{\\text{3}}$BH.

  9. Hawking Radiation of Scalar and Vector Particles From 5D Myers-Perry Black Holes

    CERN Document Server

    Jusufi, Kimet

    2016-01-01

    In the present paper we explore the Hawking radiation as a quantum tunneling effect from a rotating 5 dimensional Myers-Perry (5D-MPBH) black hole with two independent angular momentum componentes. First, we investigate the Hawking temperature by considering the tunneling of massive scalar particles and spin-1 vector particles from the 5D-MPBH in the Painlev\\'e coordinates and then in the corotating frames. More specifically, we solve the Klein-Gordon and Proca equation by applying the WKB method and Hamilton-Jacobi equation in both cases. Finally, we recover the Hawking temperature and show that coordinates systems do not affect the Hawking temperature.

  10. Scattering and absorption of particles by a black hole involving a global monopole

    Institute of Scientific and Technical Information of China (English)

    Shao Jian Zhou; Wang Yong Jiu

    2012-01-01

    Under the conditions that the wavelength of a particle is much larger than its radius of central mass,and the Schwarzschild field is weak,the scattering of a particle has been studied by many researchers.They obtained that scalar and vector particles abide by Rutherford's angle distribution by using the low level perturbation method and the scattered field's approximation in a weak field.The scattering cross section of a photon coincides with the section in Newton's field of point mass.We can obtain the photon's polarization effect by calculating the second-order perturbation in the linear Schwarzschild field.This article discusses the scattering and absorption of a particle by a black hole involving a global monopole by using the aforesaid method.

  11. Thermal Oxidation of Tail Gases from the Production of Oil-furnace Carbon Black

    Directory of Open Access Journals (Sweden)

    Bosak, Z.

    2009-01-01

    Full Text Available This paper describes the production technology of oil-furnace carbon black, as well as the selected solution for preventing the emissions of this process from contaminating the environment.The products of industrial oil-furnace carbon black production are different grades of carbon black and process tail gases. The qualitative composition of these tail gases during the production of oil-furnace carbon black are: carbon(IV oxide, carbon(II oxide, hydrogen, methane, hydrogen sulfide, nitrogen, oxygen, and water vapor.The quantitative composition and lower caloric value of process tail gases change depending on the type of feedstock used in the production, as well as the type of process. The lower caloric value of process tail gases is relatively small with values ranging between 1500 and 2300 kJ m–3.In the conventional production of oil-furnace carbon black, process tail gases purified from carbon black dust are freely released into the atmosphere untreated. In this manner, the process tail gases pollute the air in the town of Kutina, because their quantitative values are much higher than the prescribed emissions limits for hydrogen sulfide and carbon(II oxide. A logical solution for the prevention of such air pollution is combustion of the process tail gases, i. e. their thermal oxidation. For this purpose, a specially designed flare system has been developed. Consuming minimum amounts of natural gas needed for oxidation, the flare system is designed to combust low caloric process tail gases with 99 % efficiency. Thus, the toxic and flammable components of the tail gases (hydrogen sulfide, hydrogen, carbon(II oxide, methane and other trace hydrocarbons would be transformed into environmentally acceptable components (sulfur(IV oxide, water, carbon(IV oxide and nitrogen(IV oxide, which are in compliance with the emissions limit values prescribed by law.Proper operation of this flare system in the production of oil-furnace carbon black would solve

  12. Gravitational waves from a particle scattered by a Schwarzchild black hole

    Energy Technology Data Exchange (ETDEWEB)

    Oohara, Ken-ichi; Nakamura, Takashi (Kyoto Univ. (Japan). Dept. of Physics)

    1984-01-01

    Using the generalized Regge-Wheeler equation, we have computed the gravitational radiation emitted by a particle of mass ..mu.. with orbital angular momentum ..mu..Lsub(z)(Lsub(z)>4(GM/c/sup 2/)c) and the total energy ..mu..c/sup 2/ scattered by a Schwarzschild black hole of mass M(>>..mu..). It is found that contrary to plunging cases (Lsub(z)<4(GM/c/sup 2/)c), the quasi-normal mode is not excited even when the periastron approaches the limiting value 4(GM/c/sup 2/). The total energy for Lsub(z) = 4.1(GM/c/sup 2/)c is 1.24 x 10/sup -1/ (..mu../M)..mu..c/sup 2/ which is smaller than that for Lsub(z) = 3.9(GM/c/sup 2/)c, 5.49 x 10/sup -1/ (..mu../M)..mu..c/sup 2/. The peak of the energy spectrum is not determined by the quasi-normal mode but by the angular velocity of the particle at the periastron. We have also calculated the energy from a rotating ring scattered by the black hole. In this case, the energy does not diverge in the limit Lsub(z) ..-->.. 4(GM/c/sup 2/)c. However, it has discontinuity at Lsub(z) = 4(GM/c/sup 2/)c, which is due to the frigidity of a black hole to a scattered particle.

  13. Gravitational radiation from a particle with orbital angular momentum plunging into a Kerr black hole

    Energy Technology Data Exchange (ETDEWEB)

    Kojima, Yasufumi; Nakamura, Takashi (Kyoto Univ. (Japan). Dept. of Physics)

    1984-01-01

    Using the Sasaki-Nakamura equation, we have computed the energy, linear and angular momentum of the gravitational radiation induced by a particle of mass ..mu.. and angular momentum ..mu..Lsub(z) plunging in an equatorial plane into a Kerr black hole of mass M(>>..mu..) and angular momentum Ma. It is found that the total energy ..delta..E approximately equal (..mu../M)..mu..c/sup 2/ is emitted by the particle with sufficient large orbital angular momentum. For the same value of /sup +/Lsub(z)/sup +/, a corotating particle emits more energy than a counter-rotating one. We have also calculated the energy from a rotating ring plunging into a Kerr black hole. In this case, we have found that a corotating ring emits less gravitational energy than a counter-rotating one for the same /sup +/Lsub(z)/sup +/. The maximum of the linear momentum is 6 x 10/sup -2/ (..mu../M)..mu..c, which suggests the recoil velocity of the coalesced black hole is 160 km/s for ..mu.. = 0.1 M.

  14. 西安郊区泾河秋、冬季大气黑碳变化及粒径特征%Analysis of Variation and Particle Size Characteristics of Black Carbon at Jinghe, Suburban of Xi'an in Autumn and Winter

    Institute of Scientific and Technical Information of China (English)

    杜川利; 余兴; 李星敏; 陈闯; 王繁强; 彭艳; 董妍; 董自鹏

    2013-01-01

    Black carbon (BC) is one of the most important research fields in aerosol climate effect studies due to its strong absorption effect.Compared to early international efforts,systematic BC observations were started late since 1990s' in several cities of China.The variation and particle size characteristics and their causing factors of BC concentration were analyzed based on data collected at Jinghe station,suburban of Xi' an,during autumn and winter (October 1st,2008-February 28,2009).The station is suitable for BC characteristics study since it is far from downtown area without main BC source nearby.The observational data included BC and particle concentration data collected by atmospheric elements station,meteorological variables collected by automatic meteorological station and sounding station.Results showed that:1) suburban has lower BC concentration than urban area; Contrast to tri-peak diurnal cycle at urban area,suburban showed double-peak characteristic with maximum values of 5.5 μg/m3 (09:00 o'clock) and 6.1 μg/m3 (23:00 o'clock).The two corresponding trough values were 4.9 μg/m3 (06:00 o'clock) and 2.6 μg/m3 (16:00 o'clock),respectively; 2)Relationship between BC concentration and particle size varied with particle sizes.The BC concentration was directly proportional to ultrafine particles and inversely proportional to big particles (e.g.dust).Dust affects measurement of BC concentration; 3) BC concentration was significantly related with temperature inversion near the ground (correlation coefficient).Wind speed had different effects in the processes of transport and diffusion of BC.Continuous precipitation had remarkable removal effects to BC.The increasing BC concentration during autumn could be contributed by the burning of crop stalks during the harvest seasons.In December and January,residential heating through burning coal and firewood by simple equipment caused relative high BC concentration.The reasons for lowest BC concentration in February

  15. 1 Mixing state and absorbing properties of black carbon during Arctic haze

    Science.gov (United States)

    Zanatta, Marco; Gysel, Martin; Eleftheriadis, Kosas; Laj, Paolo; Hans-Werner, Jacobi

    2016-04-01

    The Arctic atmosphere is periodically affected by the Arctic haze occurring in spring. One of its particulate components is the black carbon (BC), which is considered to be an important contributor to climate change in the Arctic region. Beside BC-cloud interaction and albedo reduction of snow, BC may influence Arctic climate interacting directly with the solar radiation, warming the corresponding aerosol layer (Flanner, 2013). Such warming depends on BC atmospheric burden and also on the efficiency of BC to absorb light, in fact the light absorption is enhanced by mixing of BC with other atmospheric non-absorbing materials (lensing effect) (Bond et al., 2013). The BC reaching the Arctic is evilly processed, due to long range transport. Aging promote internal mixing and thus absorption enhancement. Such modification of mixing and is quantification after long range transport have been observed in the Atlantic ocean (China et al., 2015) but never investigated in the Arctic. During field experiments conducted at the Zeppelin research site in Svalbard during the 2012 Arctic spring, we investigated the relative precision of different BC measuring techniques; a single particle soot photometer was then used to assess the coating of Arctic black carbon. This allowed quantifying the absorption enhancement induced by internal mixing via optical modelling; the optical assessment of aged black carbon in the arctic will be of major interest for future radiative forcing assessment.Optical characterization of the total aerosol indicated that in 2012 no extreme smoke events took place and that the aerosol population was dominated by fine and non-absorbing particles. Low mean concentration of rBC was found (30 ng m-3), with a mean mass equivalent diameter above 200 nm. rBC concentration detected with the continuous soot monitoring system and the single particle soot photometer was agreeing within 15%. Combining absorption coefficient observed with an aethalometer and rBC mass

  16. Insights from In-situ Measurements of Black Carbon During the Marine Stratus Experiment

    Science.gov (United States)

    Mazzoleni, C.; Dubey, M.; Chylek, P.; Arnott, P. W.; Seinfeld, J. H.; Varutbangkul, V.; Murphy, S. M.; Sorooshian, A.; Rissman, T. A.; Jonsson, H. H.; Buzorius, G.

    2005-12-01

    regarding the mixing state of the aerosol sampled, while functional relations between SSA and absorption can yield information regarding plume dilution and ambient air entrainment. Some of the instruments carried by the aircraft, such as a Particle Soot Absorption Photometer (PSAP), were run downstream of a Counterflow Virtual Impactor (CVI) in cloud. By combining data from PA and PSAP instruments when the CVI was on, we can deduce the distribution (cloud drop and interstitial fraction) and optical properties of black carbon containing particles inside the cloud. In at least one episode the higher absorption and scattering values appeared to be related to aerosols with high levels of inorganic mass, especially sulfate. An on-going comparison with data from an Aerodyne aerosol mass spectrometer and a particle-into-liquid sampler, also onboard the plane, should help us to understand the chemistry and physics of indirect effects of black carbon containing aerosols on marine stratus.

  17. Hydropyrolysis: implications for radiocarbon pre-treatment and characterization of Black Carbon

    OpenAIRE

    Ascough, P.; M. I. Bird; Meredith, W.; Wood, R. E.; Snape, C.E.; Brock, F.; Higham, T.F.; Large, D.J.; Apperley, D. C.

    2010-01-01

    Charcoal is the result of natural and anthropogenic burning events, when biomass is exposed to elevated temperatures under conditions of restricted oxygen. This process produces a range of materials, collectively known as pyrogenic carbon, the most inert fraction of which is known as Black Carbon (BC). BC degrades extremely slowly, and is resistant to diagenetic alteration involving the addition of exogenous carbon making it a useful target substance for radiocarbon dating particularly of ...

  18. Fine Particulate Matter in São Paulo During the Winter Months: Concentrations and Black Carbon Comparison Between Techniques and Equipments

    Science.gov (United States)

    Miranda, R. M.; Andrade, M. D. F.

    2014-12-01

    During the winter months in São Paulo, Brazil, particulate matter and black carbon were monitored using a Dust Trak (TSI model 8533), a Black Carbon monitor (MAAP-Thermo) and a PM2.5 sampler (Partisol-Thermo). The concentrations were obtained every 5 minutes, from June to August 2014, for the first and second and every 12 hours for the third. The experiment took place in a site at the University of São Paulo which is located in the Southeast part of the Metropolitan Area of São Paulo (MASP). MASP is one of the biggest urban centers of the world, with more than 20 million inhabitants, 10 million vehicles and high values of some regulated pollutants, as particulate matter, especially in winter. Ambient fine particles associated with vehicle emissions have been linked to adverse health effects. Black carbon has a significant share of particulate mass concentrations. Previous studies showed a contribution of more than 30% for São Paulo. This year the climate was atypical in São Paulo. The summer was the driest of the last 30 years. The winter was hot and also dry. Dust trak monitor showed peaks of more than 120 μg/m3 for PM2.5. For a specific period, black carbon concentrations from the MAAP monitor were compared to black carbon measured by optical reflectance on teflon filters collected by the Partisol sampler. Monitor values were around 30% higher, but specific characteristics can influence this value. In the past, optical reflectance and thermal techniques for black carbon were compared. The reflectance technique showed higher results for the fine fraction than the thermal method. Now, reflectance is being compared to instrument measurements and results are also satisfactory.

  19. Sources and mixing state of size-resolved elemental carbon particles in a European megacity: Paris

    Directory of Open Access Journals (Sweden)

    R. M. Healy

    2012-02-01

    Full Text Available An Aerosol Time-Of-Flight Mass Spectrometer (ATOFMS was deployed to investigate the size-resolved chemical composition of single particles at an urban background site in Paris, France, as part of the MEGAPOLI winter campaign in January/February 2010. ATOFMS particle counts were scaled to match coincident Twin Differential Mobility Particle Sizer (TDMPS data in order to generate hourly size-resolved mass concentrations for the single particle classes observed. The total scaled ATOFMS particle mass concentration in the size range 150–1067 nm was found to agree very well with the sum of concurrent High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS and Multi-Angle Absorption Photometer (MAAP mass concentration measurements of organic carbon (OC, inorganic ions and black carbon (BC (R2 = 0.91. Clustering analysis of the ATOFMS single particle mass spectra allowed the separation of elemental carbon (EC particles into four classes: (i EC attributed to biomass burning (ECbiomass, (ii EC attributed to traffic (ECtraffic, (iii EC internally mixed with OC and ammonium sulfate (ECOCSOx, and (iv EC internally mixed with OC and ammonium nitrate (ECOCNOx. Average hourly mass concentrations for EC-containing particles detected by the ATOFMS were found to agree reasonably well with semi-continuous quantitative thermal/optical EC and optical BC measurements (r2 = 0.61 and 0.65–0.68 respectively, n = 552. The EC particle mass assigned to fossil fuel and biomass burning sources also agreed reasonably well with BC mass fractions assigned to the same sources using seven-wavelength aethalometer data (r2 = 0.60 and 0.48, respectively, n = 568. Agreement between the ATOFMS and other instrumentation improved noticeably when a period influenced by significantly aged, internally mixed EC particles was removed from the intercomparison. 88% and 12% of EC particle

  20. Sources and mixing state of size-resolved elemental carbon particles in a European megacity: Paris

    Science.gov (United States)

    Healy, R. M.; Sciare, J.; Poulain, L.; Kamili, K.; Merkel, M.; Müller, T.; Wiedensohler, A.; Eckhardt, S.; Stohl, A.; Sarda-Estève, R.; McGillicuddy, E.; O'Connor, I. P.; Sodeau, J. R.; Wenger, J. C.

    2012-02-01

    An Aerosol Time-Of-Flight Mass Spectrometer (ATOFMS) was deployed to investigate the size-resolved chemical composition of single particles at an urban background site in Paris, France, as part of the MEGAPOLI winter campaign in January/February 2010. ATOFMS particle counts were scaled to match coincident Twin Differential Mobility Particle Sizer (TDMPS) data in order to generate hourly size-resolved mass concentrations for the single particle classes observed. The total scaled ATOFMS particle mass concentration in the size range 150-1067 nm was found to agree very well with the sum of concurrent High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and Multi-Angle Absorption Photometer (MAAP) mass concentration measurements of organic carbon (OC), inorganic ions and black carbon (BC) (R2 = 0.91). Clustering analysis of the ATOFMS single particle mass spectra allowed the separation of elemental carbon (EC) particles into four classes: (i) EC attributed to biomass burning (ECbiomass), (ii) EC attributed to traffic (ECtraffic), (iii) EC internally mixed with OC and ammonium sulfate (ECOCSOx), and (iv) EC internally mixed with OC and ammonium nitrate (ECOCNOx). Average hourly mass concentrations for EC-containing particles detected by the ATOFMS were found to agree reasonably well with semi-continuous quantitative thermal/optical EC and optical BC measurements (r2 = 0.61 and 0.65-0.68 respectively, n = 552). The EC particle mass assigned to fossil fuel and biomass burning sources also agreed reasonably well with BC mass fractions assigned to the same sources using seven-wavelength aethalometer data (r2 = 0.60 and 0.48, respectively, n = 568). Agreement between the ATOFMS and other instrumentation improved noticeably when a period influenced by significantly aged, internally mixed EC particles was removed from the intercomparison. 88% and 12% of EC particle mass was apportioned to fossil fuel and biomass burning respectively using the ATOFMS data

  1. Sources and mixing state of size-resolved elemental carbon particles in a European megacity: Paris

    Directory of Open Access Journals (Sweden)

    R. M. Healy

    2011-11-01

    Full Text Available An Aerosol Time-Of-Flight Mass Spectrometer (ATOFMS was deployed to investigate the size-resolved chemical composition of single particles at an urban background site in Paris, France, as part of the MEGAPOLI winter campaign in January/February 2010. ATOFMS particle counts were scaled to match coincident Twin Differential Mobility Particle Sizer (TDMPS data in order to generate hourly size-resolved mass concentrations for the single particle classes observed. The total scaled ATOFMS particle mass concentration in the size range 150–1067 nm was found to agree very well with the sum of concurrent High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS and Multi-Angle Absorption Photometer (MAAP mass concentration measurements of organic carbon (OC, inorganic ions and black carbon (BC (R2 = 0.91. Clustering analysis of the ATOFMS single particle mass spectra allowed the separation of elemental carbon (EC particles into four classes: (i EC attributed to biomass burning (ECbiomass, (ii EC attributed to traffic (ECtraffic, (iii EC internally mixed with OC and ammonium sulfate (ECOCSOx, and (iv EC internally mixed with OC and ammonium nitrate (ECOCNOx. Average hourly mass concentrations for EC-containing particles detected by the ATOFMS were found to agree reasonably well with semi-continuous quantitative thermal/optical EC and optical BC measurements (r2 = 0.61 and 0.65–0.68, respectively, n = 552. The EC particle mass assigned to fossil fuel and biomass burning sources also agreed reasonably well with BC mass fractions assigned to the same sources using seven-wavelength aethalometer data (r2 = 0.60 and 0.48, respectively, n = 568. Agreement between the ATOFMS and other instrumentation improved noticeably when a period influenced by significantly aged, internally mixed EC particles was removed from the intercomparison. 88 % and 12 % of EC

  2. Estimate the influence of snow grain size and black carbon on albedo

    Institute of Scientific and Technical Information of China (English)

    ZhongMing Guo; NingLian Wang; XiaoBo Wu; HongBo Wu; YuWei Wu

    2015-01-01

    Estimation of the influence of snow grain size and black carbon on albedo is essential in obtaining the accurate albedo. In this paper, field measurement data, including snow grain size, snow depth and density was obtained. Black carbon samples were collected from the snow surface. A simultaneous observation using Analytical Spectral Devices was employed in the Qiyi Glacier located in the Qilian Mountain. Analytical Spectral Devices spectrum data were used to analyze spectral re-flectance of snow for different grain size and black carbon content. The measurements were compared with the results obtained from the Snow, Ice, and Aerosol Radiation model, and the simulation was found to correlate well with the ob-served data. However, the simulated albedo was near to 0.98 times of the measured albedo, so the other factors were as-sumed to be constant using the corrected Snow, Ice, and Aerosol Radiation model to estimate the influence of measured snow grain size and black carbon on albedo. Field measurements were controlled to fit the relationship between the snow grain size and black carbon in order to estimate the influence of these factors on the snow albedo.

  3. Estimation of Black Carbon Emissions from Dry Dipterocarp Forest Fires in Thailand

    Directory of Open Access Journals (Sweden)

    Ubonwan Chaiyo

    2014-12-01

    Full Text Available This study focused on the estimation of black carbon emissions from dry dipterocarp forest fires in Thailand. Field experiments were set up at the natural forest, Mae Nam Phachi wildlife sanctuary, Ratchaburi Province, Thailand. The dead leaves were the main component consumed of the surface biomass with coverage higher than 90% in volume and mass. The dead leaves load was 342 ± 190 g∙m−2 and followed by a little mass load of twig, 100 g∙m−2. The chemical analysis of the dead leaves showed that the carbon content in the experimental biomass fuel was 45.81 ± 0.04%. From the field experiments, it was found that 88.38 ± 2.02% of the carbon input was converted to carbon released to the atmosphere, while less than 10% were left in the form of residues, and returned to soil. The quantity of dead leaves consumed to produce each gram of carbon released was 2.40 ± 0.02 gdry biomass burned. From the study, the emissions factor of carbon dioxide, carbon monoxide, particulate matter (PM2.5 and black carbon amounted 1329, 90, 26.19 and 2.83 g∙kg−1dry biomass burned, respectively. In Thailand, the amount of black carbon emissions from dry dipterocarp forest fires amounted 17.43 tonnes∙y−1.

  4. Erosion of carbon/carbon by solar wind charged particle radiation during a solar probe mission

    Science.gov (United States)

    Sokolowski, Witold; O'Donnell, Tim; Millard, Jerry

    1991-01-01

    The possible erosion of a carbon/carbon thermal shield by solar wind-charged particle radiation is reviewed. The present knowledge of erosion data for carbon and/or graphite is surveyed, and an explanation of erosion mechanisms under different charged particle environments is discussed. The highest erosion is expected at four solar radii. Erosion rates are analytically estimated under several conservative assumptions for a normal quiet and worst case solar wind storm conditions. Mass loss analyses and comparison studies surprisingly indicate that the predicted erosion rate by solar wind could be greater than by nominal free sublimation during solar wind storm conditions at four solar radii. The predicted overall mass loss of a carbon/carbon shield material during the critical four solar radii flyby can still meet the mass loss mission requirement of less than 0.0025 g/sec.

  5. Binder-Free and Carbon-Free Nanoparticle Batteries: A Method for Nanoparticle Electrodes without Polymeric Binders or Carbon Black

    KAUST Repository

    Ha, Don-Hyung

    2012-10-10

    In this work, we have developed a new fabrication method for nanoparticle (NP) assemblies for Li-ion battery electrodes that require no additional support or conductive materials such as polymeric binders or carbon black. By eliminating these additives, we are able to improve the battery capacity/weight ratio. The NP film is formed by using electrophoretic deposition (EPD) of colloidally synthesized, monodisperse cobalt NPs that are transformed through the nanoscale Kirkendall effect into hollow Co 3O 4. EPD forms a network of NPs that are mechanically very robust and electrically connected, enabling them to act as the Li-ion battery anode. The morphology change through cycles indicates stable 5-10 nm NPs form after the first lithiation remained throughout the cycling process. This NP-film battery made without binders and conductive additives shows high gravimetric (>830 mAh/g) and volumetric capacities (>2100 mAh/cm 3) even after 50 cycles. Because similar films made from drop-casting do not perform well under equal conditions, EPD is seen as the critical step to create good contacts between the particles and electrodes resulting in this significant improvement in battery electrode assembly. This is a promising system for colloidal nanoparticles and a template for investigating the mechanism of lithiation and delithiation of NPs. © 2012 American Chemical Society.

  6. Inventory and burial fluxes of Black Carbon in the Swedish continental shelf sediments

    Science.gov (United States)

    Sánchez-García, L.; Cato, I.; Gustafsson, Ö.

    2009-04-01

    Highly condensed black carbon (BC) particles, mainly derived from incomplete combustion of biomass and fossil fuel, are involved in several important processes in the biogeosphere [1], including sedimentary carbon burial, sequestration of organic pollutants in soils and sediments, affecting Earth's radiative heat balance and even human respiratory health. BC is commonly found to constitute several to 20% of total sedimentary carbon, and thus plays an important but poorly constrained role in the global biogeospheric carbon cycle. Sequestration of biogenic carbon as BC is a direct sink of the element from the rapidly cycling atmosphere-biosphere reservoirs, whereas burial of petrogenic/fossil BC is simply a conversion of one form of geological carbon to another [2]. Considerable emphasis has been made on the relevant role this recalcitrant form of organic matter (OM) may play on the global C cycle and yet large uncertainty exists around BC detection and quantification. This work seeks to provide a large-scale estimate of the reservoir and burial sink flux of BC in sediments from the extensive Swedish continental shelf (SCS), as a first approach to global inventories. To this end, a total of 120 sediment samples were collected from the Exclusive Economic Zone (EEZ) along the ?2000 km SCS stretch. The most recalcitrant fraction of the sedimentary OM was isolated and determined by means of a commonly applied method in biogeochemical studies of soils and sediments: chemo-thermal oxidation at 375˚ C in air (CTO-375). The obtained BC concentration was used to estimate the inventory and burial flux of BC in the SCS surface sediments, following [3], which takes into account key geophysical and geochemical properties of the nine distinct sedimentary regimes of the SCS that was separately assessed. Globally representative values of the sediment properties (e.g. density of dried sediments, bioturbated mixing depth, sedimentation rate or porosity over the mixed depth) were

  7. Black carbon in soils and sediments: Analysis, distribution, implications, and current challenges

    Science.gov (United States)

    Schmidt, Michael W. I.; Noack, Angela G.

    2000-09-01

    This review highlights the ubiquity of black carbon (BC) produced by incomplete combustion of plant material and fossil fuels in peats, soils, and lacustrine and marine sediments. We examine various definitions and analytical approaches and seek to provide a common language. BC represents a continuum from partly charred material to graphite and soot particles, with no general agreement on clear-cut boundaries. Formation of BC can occur in two fundamentally different ways. Volatiles recondense to highly graphitized soot-BC, whereas the solid residues form char-BC. Both forms of BC are relatively inert and are distributed globally by water and wind via fluvial and atmospheric transport. We summarize, chronologically, the ubiquity of BC in soils and sediments since Devonian times, differentiating between BC from vegetation fires and from fossil fuel combustion. BC has important implications for various biological, geochemical and environmental processes. As examples, BC may represent a significant sink in the global carbon cycle, affect the Earth's radiative heat balance, be a useful tracer for Earth's fire history, build up a significant fraction of carbon buried in soils and sediments, and carry organic pollutants. On land, BC seems to be abundant in dark-colored soils, affected by frequent vegetation burning and fossil fuel combustion, thus probably contributing to the highly stable aromatic components of soil organic matter. We discuss challenges for future research. Despite the great importance of BC, only limited progress has been made in calibrating analytical techniques. Progress in the quantification of BC is likely to come from systematic intercomparison using BCs from different sources and in different natural matrices. BC identification could benefit from isotopic and spectroscopic techniques applied at the bulk and molecular levels. The key to estimating BC stocks in soils and sediments is an understanding of the processes involved in BC degradation on a

  8. Black and brown carbon fractal aggregates from combustion of two fuels widely used in Asian rituals

    Science.gov (United States)

    Chakrabarty, Rajan K.; Arnold, Ian J.; Francisco, Dianna M.; Hatchett, Benjamin; Hosseinpour, Farnaz; Loria, Marcela; Pokharel, Ashok; Woody, Brian M.

    2013-06-01

    Incense sticks and mustard oil are the two most popular combustion fuels during rituals and social ceremonies in Asian countries. Given their widespread use in both closed and open burning activities, it is important to quantify the spectral radiative properties of aerosols emitted from the combustion of both fuels. This information is needed by climate models to assess the impact of these aerosols on radiative forcing. In this study, we used a 3-wavelength integrated photoacoustic-nephelometer - operating simultaneously at 405, 532 and 781nm - to measure the optical coefficients of aerosols emitted from the laboratory combustion of mustard oil lamp and two types of incense sticks. From the measured optical coefficients at three wavelengths, time-varying single scattering albedo (SSA), absorption Ångström exponent (AAE), and scattering Ångström exponent (SAE) were calculated. For incense smoke particles, the time-averaged mean AAE values were found to be as high as 8.32 (between 405 and 532nm) and 6.48 (between 532 and 781nm). This spectrally-varying characteristic of AAE indicates that brown carbon - a class of organic carbon which strongly absorbs solar radiation in the blue and near ultraviolet - is the primary component of incense smoke aerosols. For aerosols emitted from the burning of mustard oil lamp, the time-averaged mean AAE values were ˜1.3 (between 405 and 781nm) indicating that black carbon (BC) is the primary constituent. Scanning electron microscopy combined with image processing revealed the morphology of incense smoke aerosols to be non-coalescing and weakly-bound aggregates with a mean two-dimensional (2-d) fractal dimension (Df)=1.9±0.07, while the mustard oil smoke aerosols had typical fractal-like BC aggregate morphology with a mean 2-d Df=1.85±0.09.

  9. Hawking Tunneling Radiation of a Particle with Electric and Magnetic Charge from Kerr-Newman-Kasuya Black Hole

    Institute of Scientific and Technical Information of China (English)

    ZHAO Wei-Qin; LEI Jie-Hong; LIU Zhi-Xiang; YANG Shu-Zheng

    2008-01-01

    Extending the Parikh's quantum tunneling method of an uncharged particle, we investigate the quantum radiation characteristics of a particle with electric and magnetic charge via tunneling from the event horizon of theKerr-Newman-Kasuya black hole. The derived result supports the Parikh's opinion and the correction to the thermal spectrum is of precisely the form that satisfies the underlying unitary quantum theory, and finally provides a might explanation to the black hole information puzzle.

  10. Black holes evaporation and big mass particle (maximon, intermediate boson) creation in nonstationary universe

    International Nuclear Information System (INIS)

    This chapter considers the process of creation of particles with maximally big masses (maximons, intermediate bosons) in the nonstationary Universe within the framework of neutral and charged scalar field theory. The conclusions of the matter creation model for real particles (resonances) and hypothetical particles (maximons, friedmons, intermediate bosons) are analyzed. It is determined that if the mechanism of maximon's creation exists, then these particles must be stable. The maximons could be the final states of decaying black holes. A possible mechanism of cosmic ray creation as a result of ''vacuum'' generation of known unstable particles is discussed. The limits upon the mass and the life time of intermediate bosons are calculated. It is demonstrated that the creation of masses greater than 10 GeV, and with life times less than 10-24 sec and quantity of elementary particles greater than 100 are in contradiction with the particle creation mechanism and the experimental mass density in the Universe. The formalism of the examined method and its vacuum properties are discussed in an appendix

  11. Black hole formation from pointlike particles in three-dimensional anti-de Sitter space

    Science.gov (United States)

    Lindgren, E. J.

    2016-07-01

    We study collisions of many point-like particles in three-dimensional anti-de Sitter space, generalizing the known result with two particles. We show how to construct exact solutions corresponding to the formation of either a black hole or a conical singularity from the collision of an arbitrary number of massless particles falling in radially from the boundary. We find that when going away from the case of equal energies and discrete rotational symmetry, this is not a trivial generalization of the two-particle case, but requires that the excised wedges corresponding to the particles must be chosen in a very precise way for a consistent solution. We also explicitly take the limit when the number of particles goes to infinity and obtain thin shell solutions that in general break rotational invariance, corresponding to an instantaneous and inhomogeneous perturbation at the boundary. We also compute the stress–energy tensor of the shell using the junction formalism for null shells and obtain agreement with the point particle picture.

  12. Nano-carbon black and carbon fiber as conductive materials for the diagnosing of the damage of concrete beam

    OpenAIRE

    Yining Ding; Zhipei Chen; Zhibo Han; Yulin Zhang; Torgal, Fernando Pacheco

    2013-01-01

    The nano-carbon black (NCB) and carbon fiber (CF) as electric conductive materials were added into the concrete. The effect of the NCB and CF on the mechanical properties and on the fractional change in resistance (FCR) of concrete was investigated. The relationships among the FCR, the strain of initial geometrical neutral axis (IGNA) and the beam damage degree were developed. The results showed that the relationship between the FCR and IGNA strain can be described by the First Or...

  13. Black carbon measurements during winter 2013-2014 in Athens and intercomparison between different techniques

    Science.gov (United States)

    Liakakou, Eleni; Stravroulas, Jason; Roukounakis, Nikolaos; Paraskevopoulou, Despina; Fourtziou, Luciana; Psiloglou, Vassilis; Gerasopoulos, Evangelos; Sciare, Jean; Mihalopoulos, Nikolaos

    2014-05-01

    Black carbon (BC) is a particulate pollutant species emitted from the combustion of fuels, biomass burning for agricultural purposes and forest fires, with the first two anthropogenic sources being the major contributors to the atmospheric burden of BC. The presence of BC is important due to its direct and indirect physicochemical effects and its use as a tracer of burning and subsequent transport processes. Black carbon measurements took place during winter 2013 -2014 in the frame of a pollution monitoring experiment conducted at the urban site of Thissio, Athens (city center) at the premises of the National Observatory of Athens. The economic crisis in Greece and the resulting turn of Athens inhabitants to wood burning for domestic heating, has led to increased daily concentrations of BC in the range of 2-6 μg m-3, peaking at night time (15-20 μg m-3). Three different optical methods were used for the determination of BC. A Particle Soot Absorption Photometer (PSAP; Radiance Research) commercial instrument was used to monitor the light absorption coefficient (σap) at 565 nm of ambient aerosols, with 1 minute resolution. During parts of the campaign, a portable Aethalometer (AE-42; Magee Scientific) was also used to provide measurement of the aerosol BC content at 7 wavelengths over 5 minutes intervals. Exploiting the measurements at different wavelengths is was feasible to separate wood burning BC from BC related to fossil fuel. Two Multi Angle Absorption Photometers (MAAP; Thermo) were also operated as reference. Finally, aerosol samples were collected on 12-hour basis using a sequential dichotomous sampler for the sampling of PM2.5, PM2.5-10and PM10 fractions of aerosols on quartz filters, and the filters were analyzed for elemental carbon (EC) by a thermal - optical transmission technique. The main objective of the study is the intercomparison of the different BC monitoring techniques under a large range of ambient concentrations achieved due to the special

  14. Aerosol organic carbon to black carbon ratios: Analysis ofpublished data and implications for climate forcing

    Energy Technology Data Exchange (ETDEWEB)

    Novakov, T.; Menon, S.; Kirchstetter, T.W.; Koch, D.; Hansen, J.E.

    2005-07-11

    Measurements of organic carbon (OC) and black carbon (BC)concentrations over a variety of locations worldwide, have been analyzed to infer the spatial distributions of the ratios of OC to BC. Since these ratios determine the relative amounts of scattering and absorption, they are often used to estimate the radiative forcing due to aerosols. An artifact in the protocol for filter measurements of OC has led to widespread overestimates of the ratio of OC to BC in atmospheric aerosols. We developed a criterion to correct for this artifact and analyze corrected OC to BC ratios. The OC to BC ratios, ranging from 1.3to 2.4, appear relatively constant and are generally unaffected by seasonality, sources or technology changes, at the locations considered here. The ratios compare well with emission inventories over Europe and China but are a factor of two lower in other regions. The reduced estimate for OC/BC in aerosols strengthens the argument that reduction of soot emissions maybe a useful approach to slow global warming.

  15. Role of black carbon in the distribution of polychlorinated dibenzo-p-dioxins/dibenzofurans in aged field-contaminated soils

    Energy Technology Data Exchange (ETDEWEB)

    Chai, Y.Z.; Davis, J.W.; Wilken, M.; Martin, G.D.; Mowery, D.M.; Ghosh, U. [Dow Chemical Co USA, Midland, MI (United States). Toxicology & Environmental Research & Consulting

    2011-01-15

    Floodplain soils containing elevated levels of polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDD/Fs) were collected from several locations along the Tittabawassee River (Michigan, USA). The PCDD/F profiles of these soils exhibited distinct congener patterns consistent with byproducts from either chloralkali manufacturing or chlorophenols productions. Black carbon (BC) particles were isolated for the first time from floodplain soil impacted by PCDD/Fs. Petrographic analysis showed that BC particles, including coal, oxidized coal, metallurgical coke, depositional carbon, coal tar/pitch, cenosphere, and charcoal, comprised approximately 30% by volume of the organic fraction with size range of 250 {mu} m-2000 {mu} m from a typical floodplain soil. The BC particles with anthropogenic origin such as pitch and coke associated with the chloralkali production process served as both the source and subsequent transporter for the highly hydrophobic PCDD/Fs. These anthropogenic BC particles were enriched with high levels of PCDFs, containing approximately 1000-fold the concentration found in the bulk soil. The strong association of PCDD/Fs with anthropogenic BC directly impacts the physicochemical and biological availability thus the risk associated with these hydrophobic organochlorines in soils and sediments.

  16. Role of black carbon in the distribution of polychlorinated dibenzo-p-dioxins/dibenzofurans in aged field-contaminated soils.

    Science.gov (United States)

    Chai, Yunzhou; Davis, John W; Wilken, Michael; Martin, Greg D; Mowery, Daniel M; Ghosh, Upal

    2011-01-01

    Floodplain soils containing elevated levels of polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDD/Fs) were collected from several locations along the Tittabawassee River (Michigan, USA). The PCDD/F profiles of these soils exhibited distinct congener patterns consistent with byproducts from either chloralkali manufacturing or chlorophenols productions. Black carbon (BC) particles were isolated for the first time from floodplain soil impacted by PCDD/Fs. Petrographic analysis showed that BC particles, including coal, oxidized coal, metallurgical coke, depositional carbon, coal tar/pitch, cenosphere, and charcoal, comprised approximately 30% by volume of the organic fraction with size range of 250μm-2000μm from a typical floodplain soil. The BC particles with anthropogenic origin such as pitch and coke associated with the chloralkali production process served as both the source and subsequent transporter for the highly hydrophobic PCDD/Fs. These anthropogenic BC particles were enriched with high levels of PCDFs, containing approximately 1000-fold the concentration found in the bulk soil. The strong association of PCDD/Fs with anthropogenic BC directly impacts the physicochemical and biological availability thus the risk associated with these hydrophobic organochlorines in soils and sediments.

  17. A soft photo-mask with embedded carbon black and its application in contact photolithography

    International Nuclear Information System (INIS)

    This paper presents a new type of soft photo-mask which can be used in contact photolithography for achieving small line-width, large area, and high throughput ultraviolet (UV) patterning. It starts from a polydimethylsiloxane (PDMS) mold replicated from a silicon master mold. A carbon black photo-resist (PR) is spin-coated on top of the PDMS mold and then thermally cured. After a contact transfer process, the solidified carbon black PR exists only in the concave region of the PDMS mold, which converts the PDMS mold into a carbon-black/PDMS soft photo-mask. Due to its flexibility, this soft photo-mask can be used in contact photolithography on a slightly curved substrate. Experiments on preparing this new soft photo-mask and its application for fabricating patterned sapphire substrates (PSSs) used in the light-emitting-diode (LED) industry are carried out. Successful results are observed. (paper)

  18. Gravitational Radiation from the radial infall of highly relativistic point particles into Kerr black holes

    CERN Document Server

    Cardoso, V; Cardoso, Vitor; Lemos, Jos\\'e P. S.

    2003-01-01

    In this paper, we consider the gravitational radiation generated by the collision of highly relativistic particles with rotating Kerr black holes. We use the Sasaki-Nakamura formalism to compute the waveform, energy spectra and total energy radiated during this process. We show that the gravitational spectrum for high-energy collisions has definite characteristic universal features, which are independent of the spin of the colliding objects. We also discuss possible connections between these results and the black hole-black hole collision at the speed of light process. With these results at hand, we predict that during the high speed collision of a non-rotating hole with a rotating one, about 35% of the total energy gets converted into gravitational waves. Thus, if one is able to produce black holes at the Large Hadron Collider, 35% of the partons' energy should be emitted during the so called balding phase. This energy will be missing, since we don't have gravitational wave detectors able to measure such amp...

  19. Dynamics of particles around a pseudo-Newtonian Kerr black hole with halos

    Institute of Scientific and Technical Information of China (English)

    Wang Ying; Wu Xin

    2012-01-01

    The regular and chaotic dynamics of test particles in a superposed field between a pseudo-Newtonian Kerr black hole and quadrupolar halos is detailed.In particular,the dependence of dynamics on the quadrupolar parameter of the halos and the spin angular momentum of the rotating black hole is studied.It is found that the small quadrupolar moment,in contrast with the spin angular momentum,does not have a great effect on the stability and radii of the innermost stable circular orbits of these test particles.In addition,chaos mainly occurs for small absolute values of the rotating parameters,and does not exist for the maximum counter-rotating case under some certain initial conditions and parameters.This means that the rotating parameters of the black hole weaken the chaotic properties.It is also found that the counter-rotating system is more unstable than the co-rotating one.Furthermore,chaos is absent for small absolute values of the quadrupoles,and the onset of chaos is easier for the prolate halos than for the oblate ones.

  20. Does the particle creation mechanism favour the formation of a black hole or a naked singularity?

    CERN Document Server

    Bhattacharjee, Sudipto; Chakraborty, Subenoy

    2016-01-01

    The paper deals with collapse dynamics of a spherically symmetric massive star in the framework of non-equilibrium themodynamic prescription through particle creation mechanism. The matter content in the star is in the form of perfect uid with barotropic equation of state and the dissipative phenomena due to non-equilibrium thermodynamics is in the form of bulk viscosity. For simplicity, the thermodynamic system is chosen to be adiabatic (i.e., isentropic) so that the e?ective bulk viscous pressure is linearly related to the particle creation rate. As a result, the evolution of the collapsing star also depends on the particle creation rate. By proper choice of creation rate as a function of the Hubble parameter, it is found that the end state of the collapse may be either a black hole or a naked singularity.

  1. Particle motion and gravitational lensing in the metric of a dilaton black hole in a de Sitter universe

    CERN Document Server

    Mukherjee, N; Mukherjee, Nupur

    2006-01-01

    We consider the metric exterior to a charged dilaton black hole in a de Sitter universe. We study the motion of a test particle in this metric. Conserved quantities are identified and the Hamilton-Jacobi method is employed for the solutions of the equations of motion. We then study the phenomenon of strong field gravitational lensing by these black holes. Expressions for the various lensing quantities are obtained in terms of the metric coefficients. Numerical estimates of several lensing observables are provided for the black hole at the centre of our galaxy and comparisons are made with the values of these observables for other black hole geometries.

  2. Commuter exposure to black carbon, carbon monoxide, and noise in the mass transport khlong boats of Bangkok, Thailand

    Science.gov (United States)

    Ziegler, A. D.; Velasco, E.; Ho, K. J.

    2013-12-01

    Khlong (canal) boats are a unique mass transport alternative in the congested city of Bangkok. Canals and rivers provide exclusive transit-ways for reducing the commuting time of thousands of city residents daily. However, as a consequence of the service characteristics and boats design and state of repair, they can represent a potential public health risk and an important source of black carbon and greenhouse gases. This work quantifies commuter exposure to black carbon, CO and noise when waiting for and travelling in these diesel fueled boats. Exposure to toxic pollutants and acute noise is similar or worse than for other transportation modes. Mean black carbon concentrations observed at one busy pier and along the main canal were much higher than ambient concentrations at sites impacted by vehicular traffic. Concentrations of CO were similar to those reported for roadside areas of Bangkok. The equivalent continuous sound levels registered at the landing pier were similar to those reported for roadsides, but values recorded inside the boats were significantly higher. We believe that the boat service is a viable alternative mode of mass transport, but public safety could be improved to provide a high quality service, comparable to modern rail systems or emerging bus rapid transit systems. These investments would also contribute to reduce the emission of black carbon and other greenhouse and toxic pollutants.

  3. Hawking Radiation of Dirac Particles from a General Dynamical Spherically Symmetrical Black Hole Using a New Tortoise Coordinate Transformation

    Science.gov (United States)

    Liang, Jun; Zhang, Fang-Hui; Zhang, Wei; Zhang, Jing

    2014-01-01

    By utilizing the improved Damour-Ruffini method with a new tortoise transformation, we study the Hawking radiation of Dirac particles from a general dynamical spherically symmetric black hole. In the improved Damour-Ruffini method, the position of the event horizon of the black hole is an undetermined function, and the temperature parameter κ is an undetermined constant. By requiring the Dirac equation to be the standard wave equation near the event horizon of the black hole, κ can be determined automatically. Therefore, the Hawking temperature can be obtained. The result is consistent with that of the Hawking radiation of scalar particles.

  4. Impact of time-activity patterns on personal exposure to black carbon

    OpenAIRE

    Dons, Evi; Int Panis, Luc; Van Poppel, Martine; Theunis, Jan; Willems, Hanny; Torfs, Rudi; Wets, Geert

    2011-01-01

    Time-activity patterns are an important determinant of personal exposure to air pollution. This is demonstrated by measuring personal exposure of 16 participants for 7 consecutive days: 8 couples of which one person was a full-time worker and the other was a homemaker; both had a very different time-activity pattern. We used portable aethalometers to measure black carbon levels with a high temporal resolution and a PDA with GPS-logger and electronic diary. The exposure to black carbon differs...

  5. Bounding the Role of Black Carbon in the Climate System: a Scientific Assessment

    Science.gov (United States)

    Bond, T. C.; Doherty, S. J.; Fahey, D. W.; Forster, P. M.; Bernsten, T.; DeAngelo, B. J.; Flanner, M. G.; Ghan, S.; Karcher, B.; Koch, D.; Kinne, S.; Kondo, Y.; Quinn, P. K.; Sarofim, M. C.; Schultz, M. G.; Schulz, M.; Venkataraman, C.; Zhang, H.; Zhang, S.; Bellouin, N.; Guttikunda, S. K.; Hopke, P. K.; Jacobson, M. Z.; Kaiser, J. W.; Klimont, Z.; Lohmann, U.; Schwarz, J. P.; Shindell, D.; Storelvmo, T.; Warren, S. G.; Zender, C. S.

    2013-01-01

    Black carbon aerosol plays a unique and important role in Earth's climate system. Black carbon is a type of carbonaceous material with a unique combination of physical properties. This assessment provides an evaluation of black-carbon climate forcing that is comprehensive in its inclusion of all known and relevant processes and that is quantitative in providing best estimates and uncertainties of the main forcing terms: direct solar absorption; influence on liquid, mixed phase, and ice clouds; and deposition on snow and ice. These effects are calculated with climate models, but when possible, they are evaluated with both microphysical measurements and field observations. Predominant sources are combustion related, namely, fossil fuels for transportation, solid fuels for industrial and residential uses, and open burning of biomass. Total global emissions of black carbon using bottom-up inventory methods are 7500 Gg/yr in the year 2000 with an uncertainty range of 2000 to 29000. However, global atmospheric absorption attributable to black carbon is too low in many models and should be increased by a factor of almost 3. After this scaling, the best estimate for the industrial-era (1750 to 2005) direct radiative forcing of atmospheric black carbon is +0.71 W/sq m with 90% uncertainty bounds of (+0.08, +1.27)W/sq m. Total direct forcing by all black carbon sources, without subtracting the preindustrial background, is estimated as +0.88 (+0.17, +1.48) W/sq m. Direct radiative forcing alone does not capture important rapid adjustment mechanisms. A framework is described and used for quantifying climate forcings, including rapid adjustments. The best estimate of industrial-era climate forcing of black carbon through all forcing mechanisms, including clouds and cryosphere forcing, is +1.1 W/sq m with 90% uncertainty bounds of +0.17 to +2.1 W/sq m. Thus, there is a very high probability that black carbon emissions, independent of co-emitted species, have a positive forcing

  6. Contributions Of Black Carbon Concentration To Atmospheric Particulate Matter Levels In Navrongo Senior High School. October 2010-March 2011.

    Directory of Open Access Journals (Sweden)

    Abdul-Razak Fuseini

    2015-03-01

    Full Text Available ABSTRACT The objective of this research was to assess the black carbon concentration in air borne particulate matter in ambient air due to the use of biomass for cooking in the Navrongo Senior High School. The Gent air sampler was used to sample airborne particulate matter in the Navrongo Senior High School. These particulates were collected on nuclepore polycarbonate filters for a period of six months. In addition to determination of particulate mass in the two fractions by gravimetric method the aerosol filters were also analyzed for black carbon BC concentration levels using the black smoke reflectometer method. The average fine fraction mass concentration determined was 134.59gm-3 with a minimum of 9.28gm-3 and a maximum of 338.11gm-3 and that of coarse fraction CF was 355.04gm-3 with a minimum of 61.73gm-3 and a maximum of 1117.43gm-3. The black carbon concentration in fine average was 7.62gm-3 with a minimum of 1.68gm-3 and a maximum of 35.35gm-3 and that of the coarse was 6.92gm-3 with a minimum of 1.76gm-3 and a maximum of 22.61gm-3. The results of this research were compared to other works in the country. It was however realized that the values of this research were about twice as much as the other works. This was due to the fact that biomass burning is generally used for cooking in the study area which is usual of Northern Ghana and so produces a lot of black carbon as compared to the other area which are semi-urban areas in the southern part of the country. The values obtained for coarse to fine particulate matter ratio suggest that the particulates were not only largely made up of combustion generated carbonaceous particles but also particulate matter emissions from natural activities.

  7. The influence of different black carbon and sulfate mixing methods on their optical and radiative properties

    International Nuclear Information System (INIS)

    Three different internal mixing methods (Core–Shell, Maxwell-Garnett, and Bruggeman) and one external mixing method are used to study the impact of mixing methods of black carbon (BC) with sulfate aerosol on their optical properties, radiative flux, and heating rate. The optical properties of a mixture of BC and sulfate aerosol particles are considered for three typical bands. The results show that mixing methods, the volume ratio of BC to sulfate, and relative humidity have a strong influence on the optical properties of mixed aerosols. Compared to internal mixing, external mixing underestimates the particle mass absorption coefficient by 20–70% and the particle mass scattering coefficient by up to 50%, whereas it overestimates the particle single scattering albedo by 20–50% in most cases. However, the asymmetry parameter is strongly sensitive to the equivalent particle radius, but is only weakly sensitive to the different mixing methods. Of the internal methods, there is less than 2% difference in all optical properties between the Maxwell-Garnett and Bruggeman methods in all bands; however, the differences between the Core–Shell and Maxwell-Garnett/Bruggeman methods are usually larger than 15% in the ultraviolet and visible bands. A sensitivity test is conducted with the Beijing Climate Center Radiation transfer model (BCC-RAD) using a simulated BC concentration that is typical of east-central China and a sulfate volume ratio of 75%. The results show that the internal mixing methods could reduce the radiative flux more effectively because they produce a higher absorption. The annual mean instantaneous radiative force due to BC–sulfate aerosol is about –3.18 W/m2 for the external method and –6.91 W/m2 for the internal methods at the surface, and –3.03/–1.56/–1.85 W/m2 for the external/Core–Shell/(Maxwell-Garnett/Bruggeman) methods, respectively, at the tropopause. - Highlights: • The aerosol optical properties with different mixing methods

  8. A characterization of Arctic aerosols on the basis of aerosol optical depth and black carbon measurements

    Directory of Open Access Journals (Sweden)

    R. S. Stone

    2014-06-01

    Full Text Available Abstract Aerosols, transported from distant source regions, influence the Arctic surface radiation budget. When deposited on snow and ice, carbonaceous particles can reduce the surface albedo, which accelerates melting, leading to a temperature-albedo feedback that amplifies Arctic warming. Black carbon (BC, in particular, has been implicated as a major warming agent at high latitudes. BC and co-emitted aerosols in the atmosphere, however, attenuate sunlight and radiatively cool the surface. Warming by soot deposition and cooling by atmospheric aerosols are referred to as “darkening” and “dimming” effects, respectively. In this study, climatologies of spectral aerosol optical depth AOD (2001–2011 and Equivalent BC (EBC (1989–2011 from three Arctic observatories and from a number of aircraft campaigns are used to characterize Arctic aerosols. Since the 1980s, concentrations of BC in the Arctic have decreased by more than 50% at ground stations where in situ observations are made. AOD has increased slightly during the past decade, with variations attributed to changing emission inventories and source strengths of natural aerosols, including biomass smoke and volcanic aerosol, further influenced by deposition rates and airflow patterns.

  9. Climatic impacts of stratospheric geoengineering with sulfate, black carbon and titania injection

    Science.gov (United States)

    Jones, Anthony C.; Haywood, James M.; Jones, Andy

    2016-03-01

    In this paper, we examine the potential climatic effects of geoengineering by sulfate, black carbon and titania injection against a baseline RCP8.5 scenario. We use the HadGEM2-CCS model to simulate scenarios in which the top-of-the-atmosphere radiative imbalance due to rising greenhouse gas concentrations is offset by sufficient aerosol injection throughout the 2020-2100 period. We find that the global-mean temperature is effectively maintained at historical levels for the entirety of the period for all three aerosol-injection scenarios, though there is a wide range of side-effects which are discussed in detail. The most prominent conclusion is that although the BC injection rate necessary to produce an equivalent global mean temperature response is much lower, the severity of stratospheric temperature changes (> +70 °C) and precipitation impacts effectively exclude BC from being a viable option for geoengineering. Additionally, while it has been suggested that titania would be an effective particle because of its high scattering efficiency, it also efficiently absorbs solar ultraviolet radiation producing a significant stratospheric warming (> +20 °C). As injection rates and climatic impacts for titania are close to those for sulfate, there appears to be little benefit in terms of climatic influence of using titania when compared to the injection of sulfur dioxide, which has the added benefit of being well-modeled through extensive research that has been carried out on naturally occurring explosive volcanic eruptions.

  10. Characterization of long-term and seasonal variations of black carbon (BC concentrations at Neumayer, Antarctica

    Directory of Open Access Journals (Sweden)

    R. Weller

    2013-02-01

    Full Text Available Continuous black carbon (BC observations were conducted from 1999 through 2009 by an Aethalometer (AE10 and from 2006 through 2011 by a Multi-Angle Absorption Photometer (MAAP at Neumayer Station (NM under stringent contamination control. Considering the respective observation period, BC concentrations measured by the MAAP were somewhat higher (median ± standard deviation: 2.1 ± 2.0 ng m−3 compared to the AE10 results (1.6 ± 2.1 ng m−3. Neither for the AE10 nor for the MAAP data set a significant long-term trend could be detected. Consistently a pronounced seasonality was observed with both instruments showing a primary annual maximum between October and November and a minimum in April with a maximum/minimum ratio of 4.5/1.6 = 3.8 and 2.7/0.64 = 4.2 for the MAAP and AE10 data, respectively. Occasionally a secondary summer maximum in January/February was visible. With the aim to assess the impact of BC on optical properties of the aerosol at NM, we evaluated the BC data along with particle scattering coefficients measured by an integrating nephelometer. We found the mean single scattering albedo of ω550 = 0.992 ± 0.0090 (median: 0.994 at a wavelength of 550 nm with a range of values from 0.95 to 1.0.

  11. Corrosion behavior of modified nano carbon black/epoxy coating in accelerated conditions

    International Nuclear Information System (INIS)

    Graphical abstract: - Highlights: • By using SDS as a surfactant, nano particles of CB were uniformly dispersed. • CB nanoparticle in the epoxy coating improved the corrosion resistance of the coating. • By addition of CB nanoparticles to the epoxy diffusion ions and water became limited. • The dominance of barrier mechanism was proved by calculation of the diffusion coefficients. - Abstract: The electrochemical behavior and anticorrosion properties of modified carbon black (CB) nanoparticles in epoxy coatings were investigated in accelerated conditions. Nanoparticles of CB were modified by sodium dodecyl sulfate (SDS) as surfactant. Dispersion of nanoparticles into epoxy was confirmed by Transmission Electron Microscopy (TEM). The accelerated condition was prepared at 65 °C. CB nanoparticles improved corrosion resistance of the epoxy coating. The optimum concentration of CB in the epoxy coating was 0.75 wt%. Results showed that the CB hinder the corrosion due to its barrier properties. CB can decrease the diffusion coefficient of water in the coating with filling the micropores

  12. Corrosion behavior of modified nano carbon black/epoxy coating in accelerated conditions

    Energy Technology Data Exchange (ETDEWEB)

    Ghasemi-Kahrizsangi, Ahmad; Shariatpanahi, Homeira, E-mail: shariatpanahih@ripi.ir; Neshati, Jaber; Akbarinezhad, Esmaeil

    2015-03-15

    Graphical abstract: - Highlights: • By using SDS as a surfactant, nano particles of CB were uniformly dispersed. • CB nanoparticle in the epoxy coating improved the corrosion resistance of the coating. • By addition of CB nanoparticles to the epoxy diffusion ions and water became limited. • The dominance of barrier mechanism was proved by calculation of the diffusion coefficients. - Abstract: The electrochemical behavior and anticorrosion properties of modified carbon black (CB) nanoparticles in epoxy coatings were investigated in accelerated conditions. Nanoparticles of CB were modified by sodium dodecyl sulfate (SDS) as surfactant. Dispersion of nanoparticles into epoxy was confirmed by Transmission Electron Microscopy (TEM). The accelerated condition was prepared at 65 °C. CB nanoparticles improved corrosion resistance of the epoxy coating. The optimum concentration of CB in the epoxy coating was 0.75 wt%. Results showed that the CB hinder the corrosion due to its barrier properties. CB can decrease the diffusion coefficient of water in the coating with filling the micropores.

  13. Characterization of long-term and seasonal variations of black carbon (BC concentrations at Neumayer, Antarctica

    Directory of Open Access Journals (Sweden)

    R. Weller

    2012-09-01

    Full Text Available Continuous black carbon (BC observations were conducted from 1999 through 2009 by an Aethalometer (AE10 and from 2006 through 2011 by a Multi-Angle Absorption Photometer (MAAP at Neumayer Station (NM under stringent contamination control. Considering the respective observation period, BC concentrations measured by the MAAP were somewhat higher (median ± standard deviation: 2.1 ± 2.0 ng m−3 compared to the AE10 results (1.6 ± 2.1 ng m−3. Neither for the AE10 nor for the MAAP data set a significant long-term trend could be detected. Consistently a pronounced seasonality was observed with both instruments showing a primary annual maximum between October and November and a minimum in April with a maximum/minimum ratio of 4.5/1.6 = 3.8 and 2.7/0.64 = 4.2 for the MAAP and AE10 data, respectively. Occasionally a secondary summer maximum in January/February was visible. With the aim to assess the impact of BC on optical properties of the aerosol at NM, we evaluated the BC data along with particle scattering coefficients measured by an integrating nephelometer. We found the mean single scattering albedo of ω550 = 0.992 ± 0.0090 (median: 0.994 at a wavelength of 550 nm with a range of values from 0.95 to 1.0.

  14. Characterization of long-term and seasonal variations of black carbon (BC) concentrations at Neumayer, Antarctica

    Science.gov (United States)

    Weller, R.; Minikin, A.; Petzold, A.; Wagenbach, D.; König-Langlo, G.

    2013-02-01

    Continuous black carbon (BC) observations were conducted from 1999 through 2009 by an Aethalometer (AE10) and from 2006 through 2011 by a Multi-Angle Absorption Photometer (MAAP) at Neumayer Station (NM) under stringent contamination control. Considering the respective observation period, BC concentrations measured by the MAAP were somewhat higher (median ± standard deviation: 2.1 ± 2.0 ng m-3) compared to the AE10 results (1.6 ± 2.1 ng m-3). Neither for the AE10 nor for the MAAP data set a significant long-term trend could be detected. Consistently a pronounced seasonality was observed with both instruments showing a primary annual maximum between October and November and a minimum in April with a maximum/minimum ratio of 4.5/1.6 = 3.8 and 2.7/0.64 = 4.2 for the MAAP and AE10 data, respectively. Occasionally a secondary summer maximum in January/February was visible. With the aim to assess the impact of BC on optical properties of the aerosol at NM, we evaluated the BC data along with particle scattering coefficients measured by an integrating nephelometer. We found the mean single scattering albedo of ω550 = 0.992 ± 0.0090 (median: 0.994) at a wavelength of 550 nm with a range of values from 0.95 to 1.0.

  15. Low-Wind and Other Microclimatic Factors in Near-road Black Carbon Variability: A Case Study and Assessment Implications

    Science.gov (United States)

    Airborne black carbon from urban traffic is a climate forcing agent and has been associated with health risk to near-road populations. In this paper, we describe a case study of black carbon concentration and compositional variability at and near a traffic-laden multi-lane highw...

  16. Automatic Method for Controlling the Iodine Adsorption Number in Carbon Black Oil Furnaces

    Directory of Open Access Journals (Sweden)

    Zečević, N.

    2008-12-01

    Full Text Available There are numerous of different inlet process factors in carbon black oil furnaces which must be continuously and automatically adjusted, due to stable quality of final product. The most important six inlet process factors in carbon black oil-furnaces are:1. volume flow of process air for combustion2. temperature of process air for combustion3. volume flow of natural gas for insurance the necessary heat for thermal reaction of conversionthe hydrocarbon oil feedstock in oil-furnace carbon black4. mass flow rate of hydrocarbon oil feedstock5. type and quantity of additive for adjustment the structure of oil-furnace carbon black6. quantity and position of the quench water for cooling the reaction of oil-furnace carbon black.The control of oil-furnace carbon black adsorption capacity is made with mass flow rate of hydrocarbon feedstock, which is the most important inlet process factor. Oil-furnace carbon black adsorption capacity in industrial process is determined with laboratory analyze of iodine adsorption number. It is shown continuously and automatically method for controlling iodine adsorption number in carbon black oil-furnaces to get as much as possible efficient control of adsorption capacity. In the proposed method it can be seen the correlation between qualitatively-quantitatively composition of the process tail gasses in the production of oil-furnace carbon black and relationship between air for combustion and hydrocarbon feedstock. It is shown that the ratio between air for combustion and hydrocarbon oil feedstock is depended of adsorption capacity summarized by iodine adsorption number, regarding to BMCI index of hydrocarbon oil feedstock.The mentioned correlation can be seen through the figures from 1. to 4. From the whole composition of the process tail gasses the best correlation for continuously and automatically control of iodine adsorption number is show the volume fraction of methane. The volume fraction of methane in the

  17. Black Ink of Activated Carbon Derived From Palm Kernel Cake (PKC)

    Science.gov (United States)

    Selamat, M. H.; Ahmad, A. H.

    2009-06-01

    Recycling the waste from natural plant to produce useful end products will benefit many industries and help preserve the environment. The research reported in this paper is an investigation on the use of the natural waste of palm kernel cake (PKC) to produce carbon residue as a black carbon for pigment source by using pyrolysis process. The activated carbons (AC) is produced in powder form using ball milling process. Rheological spectra in ink is one of quality control process in determining its performance properties. Findings from this study will help expand the scientific knowledge-base for black ink production and formulation base on PKC. Various inks with different weight percentage compositions of AC will be made and tested against its respective rheological properties in order to determine ideal ink printing system. The items in the formulation used comprised of organic and bio-waste materials with added additive to improve the quality of the black ink. Modified Polyurethane was used as binder. The binder's properties highlighted an ideal vehicle to be applied for good black ink opacity performance. The rheological behaviour is a general foundation for ink characterization where the wt% of AC-PKC resulted in different pseudoplastic behaviors, including the Newtonian behavior. The result found that Newtonian field was located in between 2 wt% and 10 wt% of AC-PKC composition with binder. Mass spectroscopy results shown that the carbon content in PKC is high and very suitable for black performance. In the ageing test, the pigment of PKC perform fairly according to the standard pigment of Black carbon (CB) of ferum oxide pigment. The contact angle for substrate's wettability of the ink system shown a good angle proven to be a water resistive coating on paper subtrates; an advantage of the PKC ink pigment performance.

  18. Bounding the role of black carbon in the climate system: A scientific assessment

    Science.gov (United States)

    Bond, T. C.; Doherty, S. J.; Fahey, D. W.; Forster, P. M.; Berntsen, T.; Deangelo, B. J.; Flanner, M. G.; Ghan, S.; KäRcher, B.; Koch, D.; Kinne, S.; Kondo, Y.; Quinn, P. K.; Sarofim, M. C.; Schultz, M. G.; Schulz, M.; Venkataraman, C.; Zhang, H.; Zhang, S.; Bellouin, N.; Guttikunda, S. K.; Hopke, P. K.; Jacobson, M. Z.; Kaiser, J. W.; Klimont, Z.; Lohmann, U.; Schwarz, J. P.; Shindell, D.; Storelvmo, T.; Warren, S. G.; Zender, C. S.

    2013-06-01

    carbon aerosol plays a unique and important role in Earth's climate system. Black carbon is a type of carbonaceous material with a unique combination of physical properties. This assessment provides an evaluation of black-carbon climate forcing that is comprehensive in its inclusion of all known and relevant processes and that is quantitative in providing best estimates and uncertainties of the main forcing terms: direct solar absorption; influence on liquid, mixed phase, and ice clouds; and deposition on snow and ice. These effects are calculated with climate models, but when possible, they are evaluated with both microphysical measurements and field observations. Predominant sources are combustion related, namely, fossil fuels for transportation, solid fuels for industrial and residential uses, and open burning of biomass. Total global emissions of black carbon using bottom-up inventory methods are 7500 Gg yr-1 in the year 2000 with an uncertainty range of 2000 to 29000. However, global atmospheric absorption attributable to black carbon is too low in many models and should be increased by a factor of almost 3. After this scaling, the best estimate for the industrial-era (1750 to 2005) direct radiative forcing of atmospheric black carbon is +0.71 W m-2 with 90% uncertainty bounds of (+0.08, +1.27) W m-2. Total direct forcing by all black carbon sources, without subtracting the preindustrial background, is estimated as +0.88 (+0.17, +1.48) W m-2. Direct radiative forcing alone does not capture important rapid adjustment mechanisms. A framework is described and used for quantifying climate forcings, including rapid adjustments. The best estimate of industrial-era climate forcing of black carbon through all forcing mechanisms, including clouds and cryosphere forcing, is +1.1 W m-2 with 90% uncertainty bounds of +0.17 to +2.1 W m-2. Thus, there is a very high probability that black carbon emissions, independent of co-emitted species, have a positive forcing and warm

  19. A new algorithm for brown and black carbon identification and organic carbon detection in fine atmospheric aerosols by a multi-wavelength Aethalometer

    Directory of Open Access Journals (Sweden)

    F. Esposito

    2012-02-01

    Full Text Available A novel approach for the analysis of aerosol absorption coefficient measurements is presented. A 7-wavelenghts aethalometer has been employed to identify brown carbon (BrC and black carbon (BC and to detect organic carbon (OC in fine atmospheric aerosols (PM2.5. The Magee Aethalometer estimates the BC content in atmospheric particulate by measuring the light attenuation in the aerosols accumulated on a quartz filter, at the standard wavelength λ = 0.88 μm. The known Magee algorithm is based on the hypothesis of a mass absorption coefficient inversely proportional to the wavelength. The new algorithm has been developed and applied to the whole spectral range; it verifies the spectral absorption behavior and, thus, it distinguishes between black and brown carbon. Moreover, it allows also to correct the absorption estimation at the UV wavelength commonly used to qualitatively detect the presence of mixed hydrocarbons. The algorithm has been applied to data collected in Agri Valley, located in Southern Italy, where torched crude oil undergoes a pre-treatment process.

    The Magee Aethalometer has been set to measure Aerosol absorption coefficients τaer (λ, t every 5 min. Wavelength dependence of τaer (λ, t has been analyzed by a best-fit technique and, excluding UV-wavelengths, both the absorption Angstrom coefficient α and the BC (or BrC concentration have been determined. Finally, daily histograms of α provide information on optical properties of carbonaceous aerosol, while the extrapolation at UV-wavelengths gives information on the presence of semivolatile organic carbon (OC particles.

  20. Circular orbits and related quasiharmonic oscillatory motion of charged particles around weakly magnetized rotating black holes

    Science.gov (United States)

    Tursunov, Arman; Stuchlík, Zdeněk; Kološ, Martin

    2016-04-01

    We study the motion of charged particles in the field of a rotating black hole immersed into an external asymptotically uniform magnetic field, focusing on the epicyclic quasicircular orbits near the equatorial plane. Separating the circular orbits into four qualitatively different classes according to the sign of the canonical angular momentum of the motion and the orientation of the Lorentz force, we analyze the circular orbits using the so-called force formalism. We find the analytical solutions for the radial profiles of velocity, specific angular momentum, and specific energy of the circular orbits in dependence on the black-hole dimensionless spin and the magnetic field strength. The innermost stable circular orbits are determined for all four classes of the circular orbits. The stable circular orbits with an outward-oriented Lorentz force can extend to radii lower than the radius of the corresponding photon circular geodesic. We calculate the frequencies of the harmonic oscillatory motion of the charged particles in the radial and vertical directions related to the equatorial circular orbits and study the radial profiles of the radial, ωr; vertical, ωθ; and orbital, ωϕ, frequencies, finding significant differences in comparison to the epicyclic geodesic circular motion. The most important new phenomenon is the existence of toroidal charged particle epicyclic motion with ωr˜ωθ≫ωϕ that could occur around retrograde circular orbits with an outward-oriented Lorentz force. We demonstrate that for the rapidly rotating black holes the role of the "Wald induced charge" can be relevant.

  1. Improvement of the Rotary Dryers of Wet Pelletized Oil-Furnace Carbon Blacks

    Directory of Open Access Journals (Sweden)

    Zečević, M

    2010-05-01

    Full Text Available Due to the demand for higher production capacity and natural-gas energy savings, improvements were made to the rotary dryers in the drying process of wet pelletized oil-furnace carbon blacks. Since the rotary dryers were originally designed for drying semi-wet pelletized oil-furnace carbon blacks, they did not entirely satisfy optimal conditions for drying wet pelletized oil-furnace carbon blacks. Figure 1 shows the drying principle with key dimensions. The energy for drying the wet pelletized oil-furnace carbon blacks was provided by natural gas combustion in an open-furnace system with an uncontrolled feed of combustion air. Improvements on the rotary dryers were carried out by adjusting the excess oxygen in the gases passing through the butterfly valve on the dryer exhaust stack. By regulating the butterfly valve on the dryer exhaust stack, and applying the prescribed operations for drying wet pelletized oil furnace carbon blacks, the excess oxygen in the tail gases was adjusted in the range of φ = 3.0 % and 5.0 %, depending on the type of oil-furnace carbon blacks. Suggested also is installation of a direct-reverse automatic butterfly valve on the dryer exhaust stack to automatically determine the volume fraction of oxygen in the tail gas, and the volume flow rate of natural gas for combustion. The results the improvements carried out are shown in Tables 3 to 5. Table 2 shows the thermal calculations for the hood of the rotary dryer. Preheating of the process water in the temperature range of 70 °C and 80 °C is also recommended using the net heat from the oil-furnace process for wet pelletization. The results of preheating the process water are shown in Table 1. Depending on the type of oil-furnace carbon black, the aforementioned improvements resulted in natural gas energy savings ranging from 25 % to 35 % in relation to the average natural gas requirement in the drying process, and thus a reduction in carbon emissions of up to 40

  2. Black carbon measurements in the Pearl River Delta region of China

    Science.gov (United States)

    Huang, X.; Gao, R.; Schwarz, J. P.; Ling-Yan, H.; Fahey, D. W.; Laurel A, W.; Zeng, L.

    2009-12-01

    The Pearl River Delta (PRD) region in southeastern China is one of the most polluted industrial/metropolitan areas in the world. The 3C-STAR campaign (Synthesized Prevention Techniques for Air Pollution Complex and Integrated Demonstration in Key City-Cluster Region), carried out in October-November, 2008, was aimed at improving the understanding and quantification of air pollution in the region, while developing technical capacity for regional air quality monitoring and modeling. We report single-particle soot photometer (SP2) measurements and analyses of refractory black carbon (rBC) at Kaiping, a rural site downwind of the major pollution sources in the PRD area. The rBC mass loadings varied between 0.5 and 10 µg-rBC kg-air-1, and averaged 2.8 µg-rBC kg-air-1. These values are roughly an order of magnitude higher than those measured in the Houston, Texas, a major US metropolitan area. The rBC mass distributions show a primary lognormal peak with a median mass diameter of 0.22 µm volume-equivalent diameter (VED), which is similar to those observed in Houston and other regions with the SP2 instrument. A second mode with a mass median diameter of 0.69 µm VED, has not been observed before. Coatings are found on over 50% of rBC particles, suggesting that they are aged and/or of biomass-burning origin. The high rBC loadings cause significant heating of the atmosphere due to direct solar absorption. A diurnal heating rate of over 0.5 K day-1. is estimated for the average of entire dataset with a maximum heating rate near 3 K day-1.

  3. Testing dark energy and light particles via black hole evaporation at colliders

    International Nuclear Information System (INIS)

    We show that collider experiments have the potential to exclude a light scalar field as well as generic models of modified gravity as dark energy candidates. Our mechanism uses the spectrum radiated by black holes and can equally well be applied to determine the number of light degrees of freedom. We obtain the grey body factors for massive scalar particles and calculate the total emissivity. While the Large Hadron Collider (LHC) may not get to the desired accuracy, the measurement is within reach of next generation colliders. (orig.)

  4. Hawking Radiation of Dirac Particles in a Variable-mass Kerr Black Hole

    CERN Document Server

    Shuang-Qing, W; Shuang-Qing, Wu; Xu, Cai

    2001-01-01

    Hawking effect of Dirac particles in a variable-mass Kerr space-time is investigated by using method of the generalized tortoise coordinate transformation. The location and the temperature of event horizon of the non-stationary Kerr black hole are derived. It is shown that the temperature and the shape of event horizon depend not only on the time but also on the polar angle. However, our results demonstrate that the Fermi-Dirac spectrum displays a new spin-rotation effect which is absent from that of Bose-Einstein distribution.

  5. Hawking Radiation of Dirac Particles in a Variable-Mass Kerr Black Hole

    Institute of Scientific and Technical Information of China (English)

    WU Shuang-Qing; CAI Xu

    2001-01-01

    The Hawking effect of Dirac particles in a variable-mass Kerr spacetime is investigated by using the method of the generalized tortoise coordinate transformation. The location and the temperature of the event horizon of the non-stationary Kerr black hole are derived. It is shown that the temperature and the shape of the event horizon depend not only on the time but also on the polar angle. However, our results demonstrate that the Fermi-Diracspectrum displays a residual term whichis absent from that of the Bose-Einstein distribution.

  6. Scalar particles emission from black holes with topological defects using Hamilton-Jacobi method

    CERN Document Server

    Jusufi, Kimet

    2015-01-01

    We study quantum tunneling of charged and uncharged scalar particles from the event horizon of Schwarzschild-de Sitter and Reissner-Nordstr\\"{o}m-de Sitter black holes pierced by an infinitely long spinning cosmic string and a global monopole. In order to find the Hawking temperature and the tunneling probability we solve the Klein-Gordon equation by using the Hamilton-Jacobi method and WKB approximation. We show that Hawking temperature is independent of the presence of topological defects in both cases.

  7. Scalar particles emission from black holes with topological defects using Hamilton-Jacobi method

    Science.gov (United States)

    Jusufi, Kimet

    2015-11-01

    We study quantum tunneling of charged and uncharged scalar particles from the event horizon of Schwarzschild-de Sitter and Reissner-Nordström-de Sitter black holes pierced by an infinitely long spinning cosmic string and a global monopole. In order to find the Hawking temperature and the tunneling probability we solve the Klein-Gordon equation by using the Hamilton-Jacobi method and WKB approximation. We show that Hawking temperature is independent of the presence of topological defects in both cases.

  8. Tunnelling Radiation of Charged and Magnetized Massive Particles from BTZ Black Holes

    Institute of Scientific and Technical Information of China (English)

    HE Tang-Mei; ZHANG Jing-Yi

    2007-01-01

    We investigate the tunnelling radiation of charged and magnetized massive particles from a Ba(n)ados-TeitelboimZanelli (BTZ) black hole by extending the Parikh-Wilczek tunnelling framework. In order to calculate the emission rate,we reconstruct the electromagnetic field tensor and the Lagrangian of the field corresponding to the source with electric and magnetic charges,and treat the charges as an equivalent electric charge for simplicity in the later calculation.The result supports Parikh-Wilczek's conclusion,that is,the Hawking thermal radiation actually deviates from perfect thermality and agrees with an underlying unitary theory.

  9. Scalar field self-force effects on a particle orbiting a Reissner-Nordstrom black hole

    CERN Document Server

    Bini, Donato; Geralico, Andrea

    2016-01-01

    Scalar field self-force effects on a scalar charge orbiting a Reissner-Nordstr\\"om black hole are investigated. The scalar wave equation is solved analytically in a post-Newtonian framework, and the solution is used to compute the self-field as well as the components of the self-force at the particle's location up to 7.5 post-Newtonian order. The energy fluxes radiated to infinity and down the hole are also evaluated. Comparison with previous numerical results in the Schwarzschild case shows a good agreement in both strong-field and weak-field regimes.

  10. Characterization of calcium carbonate sorbent particle in furnace environment

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Kang Soo [Aerosol and Particle Technology Laboratory, Department of Mechanical Engineering, KAIST 291 Daehak-ro, Yuseong-gu, Daejeon, 305-701 (Korea, Republic of); Jung, Jae Hee [Environment Sensor System Research Center, KIST 39-1 Hawolgok-dong, Seongbuk-gu, Seoul, 136-791 (Korea, Republic of); Keel, Sang In; Yun, Jin Han; Min, Tai Jin [Environmental Systems Research Division, KIMM 104 Sinseongno, Yuseong-gu, Daejeon, 305-343 (Korea, Republic of); Kim, Sang Soo, E-mail: sskim@kaist.ac.kr [Aerosol and Particle Technology Laboratory, Department of Mechanical Engineering, KAIST 291 Daehak-ro, Yuseong-gu, Daejeon, 305-701 (Korea, Republic of)

    2012-07-01

    The oxy-fuel combustion system is a promising technology to control CO{sub 2} and NO{sub X} emissions. Furthermore, sulfation reaction mechanism under CO{sub 2}-rich atmospheric condition in a furnace may lead to in-furnace desulfurization. In the present study, we evaluated characteristics of calcium carbonate (CaCO{sub 3}) sorbent particles under different atmospheric conditions. To examine the physical/chemical characteristics of CaCO{sub 3}, which is used as a sorbent particle for in-furnace desulfurization in the oxy-fuel combustion system, they were injected into high temperature drop tube furnace (DTF). Experiments were conducted at varying temperatures, residence times, and atmospheric conditions in a reactor. To evaluate the aerosolizing characteristics of the CaCO{sub 3} sorbent particle, changes in the size distribution and total particle concentration between the DTF inlet and outlet were measured. Structural changes (e.g., porosity, grain size, and morphology) of the calcined sorbent particles were estimated by BET/BJH, XRD, and SEM analyses. It was shown that sorbent particles rapidly calcined and sintered in the air atmosphere, whereas calcination was delayed in the CO{sub 2} atmosphere due to the higher CO{sub 2} partial pressure. Instead, the sintering effect was dominant in the CO{sub 2} atmosphere early in the reaction. Based on the SEM images, it was shown that the reactions of sorbent particles could be explained as a grain-subgrain structure model in both the air and CO{sub 2} atmospheres.

  11. Simulation of Arctic Black Carbon using Hemispheric CMAQ: Role of Russia's BC Emissions, Transport, and Deposition

    Science.gov (United States)

    Huang, K.; Fu, J. S.

    2015-12-01

    Black carbon plays a unique role in the Arctic climate system due to its multiple effects. It causes Arctic warming by directly absorbing sunlight from space and by darkening the surface albedo of snow and ice, which indirectly leads to further warming and melting, thus inducing an Arctic amplification effect. BC depositions over the Arctic are more sensitive to regions in close proximity. In this study, we reconstruct BC emissions for Russian Federation, which is the country that occupies the largest area in the Arctic Circle. Local Russia information such as activity data, emission factors and other emission source data are used. In 2010, total anthropogenic BC emission of Russia is estimated to be around 254 Gg. Gas flaring, a commonly ignored black carbon source, contributes a dominant 43.9% of Russia's total anthropogenic BC emissions. Other sectors, i.e., residential, transportation, industry, and power plants, contribute 22.0%, 17.8%, 11.5%, and 4.8%, respectively. BC simulations were conducted using the hemispheric version of CMAQ with polar projection. Emission inputs are from a global emissions database EDGAR (Emissions Database for Global Atmospheric Research)-HTAPv2 (Hemispheric Transport of Air Pollution) and EDGAR-HTAPv2 with its Russian part replaced by the newly developed Russian BC emissions, respectively. The simulations using the new Russian BC emission inventory could improve 46 - 61% of the Absorption Aerosol Optical Depth (AAOD) measured at the AERONET sites in Russia throughout the whole year as compared to that using the default HTAPv2 emissions. At the four air monitoring sites (Zeppelin, Barrow, Alert, and Tiksi) in the Arctic Circle, surface BC simulations are improved the most during the Arctic haze periods (October - March). Emission perturbation studies show that Russia's BC emissions contribute over 50% of the surface BC concentrations over the Arctic during the cold seasons. This study demonstrates the good capability of H-CMAQ in

  12. Study of the reduction of particle emissions and borate black liquor gasification in bioenergy systems

    Energy Technology Data Exchange (ETDEWEB)

    Leduc, Sylvain

    2004-11-01

    The use of biofuel for district heating and for electricity generation is expected to increase consistently in the coming decades due to the neutral impacts on the greenhouse gases. Domestic wood boilers are first studied in this thesis. The particle emissions from these boilers are high and encounter health problems. This requires better understanding of the combustion process in the boiler. CFD software has been used as a tool for simulating the conditions inside the boiler for design and optimisation of the wood fired boiler. With the CFD model studied in this thesis, it is possible to get a detailed knowledge of the conditions inside the boiler, without excessive computational time and with acceptable accuracy. To decrease the emission of particles from a domestic wood-log boiler, particle traps based on inertial separation could be used. To find out whether the particle tracking option in the commercial CFD-code is reliable, a low-pressure impactor has been studied, and each stage of the impactor has been simulated. By comparing with experiments, it is possible to determine the accuracy of the particle tracking option. It has been shown that the particle tracking procedure in the CFD software Fluent V6.0 offers good accuracy at velocities below 12 m/s with Reynolds numbers 790-2150. Acceptable accuracy was shown for velocities 20-170 m/s at Reynolds numbers 960-2980. The particle tracking with Fluent is then appropriate for the domestic wood-log boiler where the velocities usually do not exceed 30 m/s and the Reynolds numbers are low. 3D simulations with either the RSM turbulence model, for accuracy, or the RNG k-{epsilon} model, to save calculation time, should be used together with the stochastic particle tracking. Knowing that tracking particles with an acceptable accuracy is possible for a domestic wood-log boiler, flow conditions in such a boiler were studied. The three-dimensional velocity and temperature fields were simulated in the secondary combustion

  13. Enhanced Activated Carbon Cathode Performance for Microbial Fuel Cell by Blending Carbon Black

    KAUST Repository

    Zhang, Xiaoyuan

    2014-02-04

    Activated carbon (AC) is a useful and environmentally sustainable catalyst for oxygen reduction in air-cathode microbial fuel cells (MFCs), but there is great interest in improving its performance and longevity. To enhance the performance of AC cathodes, carbon black (CB) was added into AC at CB:AC ratios of 0, 2, 5, 10, and 15 wt % to increase electrical conductivity and facilitate electron transfer. AC cathodes were then evaluated in both MFCs and electrochemical cells and compared to reactors with cathodes made with Pt. Maximum power densities of MFCs were increased by 9-16% with CB compared to the plain AC in the first week. The optimal CB:AC ratio was 10% based on both MFC polarization tests and three electrode electrochemical tests. The maximum power density of the 10% CB cathode was initially 1560 ± 40 mW/m2 and decreased by only 7% after 5 months of operation compared to a 61% decrease for the control (Pt catalyst, 570 ± 30 mW/m2 after 5 months). The catalytic activities of Pt and AC (plain or with 10% CB) were further examined in rotating disk electrode (RDE) tests that minimized mass transfer limitations. The RDE tests showed that the limiting current of the AC with 10% CB was improved by up to 21% primarily due to a decrease in charge transfer resistance (25%). These results show that blending CB in AC is a simple and effective strategy to enhance AC cathode performance in MFCs and that further improvement in performance could be obtained by reducing mass transfer limitations. © 2014 American Chemical Society.

  14. Critical review of black carbon and elemental carbon source apportionment in Europe and the United States

    Science.gov (United States)

    Briggs, Nicole L.; Long, Christopher M.

    2016-11-01

    An increasing number of air pollution source apportionment studies in Europe and the United States have focused on the black carbon (BC) fraction of ambient particulate matter (PM) given its linkage with adverse public health and climate impacts. We conducted a critical review of European and US BC source apportionment studies published since 2003. Since elemental carbon (EC) has been used as a surrogate measure of BC, we also considered source apportionment studies of EC measurements. This review extends the knowledge presented in previous ambient PM source apportionment reviews because we focus on BC and EC and critically examine the differences between source apportionment results for different methods and source categories. We identified about 50 BC and EC source apportionment studies that have been conducted in either Europe or the US since 2003, finding a striking difference in the commonly used source apportionment methods between the two regions and variations in the assigned source categories. Using three dominant methodologies (radiocarbon, aethalometer, and macro-tracer methods) that only allow for BC to be broadly apportioned into either fossil fuel combustion or biomass burning source categories, European studies generally support fossil fuel combustion as the dominant ambient BC source, but also show significant biomass burning contributions, in particular in wintertime at non-urban locations. Among US studies where prevailing methods such as chemical mass balance (CMB) and positive matrix factorization (PMF) models have allowed for estimation of more refined source contributions, there are fewer findings showing the significance of biomass burning and variable findings on the relative proportion of BC attributed to diesel versus gasoline emissions. Overall, the available BC source apportionment studies provide useful information demonstrating the significance of both fossil fuel combustion and biomass burning BC emission sources in Europe and the US

  15. Preparation of calcium carbonate particles coated with titanium dioxide

    Institute of Scientific and Technical Information of China (English)

    Hai Lin; Ying-bo Dong; Le-yong Jiang

    2009-01-01

    The preparation of a new mineral composite material, calcium carbonate particles coated with titanium dioxide, was stud-ied. The mechanism of the preparation process was proposed. The new mineral composite material was made by the mechanochemi-eal method under the optimum condition that the mass ratio of calcium carbonate particles to titanium dioxide was 6.5:3.5. The mass ratios of two different types of titanium dioxide (anatase to rutile) and grinding media to grinded materials were 8:2 and 4:1 respec-tively, and the modified density was 60%. Under this condition, the new material was capable of forming after 120-min modification.The hiding power and oil absorption of this new material were 29.12 g/m~2 and 23.30%, respectively. The results show that the modi-fication is based on surface hydroxylation. After coating with titanium dioxide, the hiding power of calcium carbonate can be im-proved greatly. The new mineral composite materials can be used as the substitute for titanium dioxide.

  16. Black carbon surface oxidation and organic composition of beech-wood soot aerosols

    Science.gov (United States)

    Corbin, J. C.; Lohmann, U.; Sierau, B.; Keller, A.; Burtscher, H.; Mensah, A. A.

    2015-10-01

    Soot particles are the most strongly light-absorbing particles commonly found in the atmosphere. They are major contributors to the radiative budget of the Earth and to the toxicity of atmospheric pollution. Atmospheric aging of soot may change its health- and climate-relevant properties by oxidizing the primary black carbon (BC) or organic particulate matter (OM) which, together with ash, comprise soot. This atmospheric aging, which entails the condensation of secondary particulate matter as well as the oxidation of the primary OM and BC emissions, is currently poorly understood. In this study, atmospheric aging of wood-stove soot aerosols was simulated in a continuous-flow reactor. The composition of fresh and aged soot particles was measured in real time by a dual-vaporizer aerosol-particle mass spectrometer (SP-AMS). The dual-vaporizer SP-AMS provided information on the OM and BC components of the soot as well as on refractory components internally mixed with BC. By switching the SP-AMS laser vaporizer off and using only the AMS thermal vaporizer (at 600 °C), information on the OM component only was obtained. In both modes, OM appeared to be generated largely by cellulose and/or hemicellulose pyrolysis and was only present in large amounts when new wood was added to the stove. In SP-AMS mode, BC signals otherwise dominated the mass spectrum. These signals consisted of ions related to refractory BC (rBC, C1-5+), oxygenated carbonaceous ions (CO1-2+), potassium (K+), and water (H2O+ and related fragments). The C4+ : C3+ ratio, but not the C1+ : C3+ ratio, was consistent with the BC-structure trends of Corbin et al. (2015c). The CO1-2+ signals likely originated from BC surface groups: upon aging, both CO+ and CO2+ increased relative to C1-3+ while CO2+ simultaneously increased relative to CO+. Factor analysis (positive matrix factorization) of SP-AMS and AMS data, using a modified error model to address peak-integration uncertainties, indicated that the surface

  17. Light absorption and scattering by aggregates: Application to black carbon and snow grains

    International Nuclear Information System (INIS)

    under the condition of equal geometrical cross section area for both external and internal mixing states; however, nonspherical snowflakes scatter less light in forward directions than spheres, resulting in a substantial reduction of the asymmetry factor. We further demonstrate that small soot particles on the order of 1 μm internally mixed with snow grains could effectively reduce snow albedo by as much as 5-10%. Indeed, the depositions of black carbon would substantially reduce mountain-snow albedo, which would lead to surface warming and snowmelt, critical to regional climatic surface temperature amplification and feedback.

  18. Black-carbon-surface oxidation and organic composition of beech-wood soot aerosols

    Directory of Open Access Journals (Sweden)

    J. C. Corbin

    2015-03-01

    Full Text Available Soot particles are the most strongly light-absorbing particles commonly found in the atmosphere. They are major contributors to the radiative budget of the Earth and to the toxicity of atmospheric pollution. Atmospheric aging of soot may change its health- and climate-relevant properties by oxidizing the primary black carbon (BC or organic particulate matter (OM which, together with ash, comprise soot. This atmospheric aging, which entails the condensation of secondary particulate matter as well as the oxidation of the primary OM and BC emissions, is currently poorly understood. In this study, atmospheric aging of wood-stove soot aerosols was simulated in a continuous-flow reactor. The composition of fresh and aged soot particles was measured in real time by a dual-vaporizer aerosol-particle mass spectrometer (SP-AMS. The SP-AMS provided information on the OM, BC, and surface composition of the soot. The OM appeared to be generated largely by cellulose and/or hemicellulose pyrolysis, and was only present in large amounts when new wood was added to the stove. BC signals otherwise dominated the mass spectrum. These signals consisted of ions related to refractory BC (rBC, C+1−5, oxygenated surface groups (CO+1−2, potassium (K+ and water (H+2O and related fragments. The C+4 : C+3 ratio, but not the C+1 : C+3 ratio, was consistent with the BC-structure trends of Corbin et al. (2015c. The CO+1−2 signals likely originated from BC surface groups: upon aging, both CO+ and CO+2 increased relative to C+1−3 while CO+2 simultaneously increased relative to CO+. Factor analysis (PMF of SP-AMS and AMS data, using a new error model to account for peak-integration uncertainties, indicated that the surface composition of the BC was approximately constant across all stages of combustion for both fresh and aged samples. These results represent the first time-resolved measurements of in-situ BC-surface aging and suggest that the surface of beech-wood BC may

  19. Enhanced solar energy absorption by internally-mixed black carbon in snow grains

    Directory of Open Access Journals (Sweden)

    M. G. Flanner

    2012-05-01

    Full Text Available Here we explore light absorption by snowpack containing black carbon (BC particles residing within ice grains. Basic considerations of particle volumes and BC/snow mass concentrations show that there are generally 0.05–109 BC particles for each ice grain. This suggests that internal BC is likely distributed as multiple inclusions within ice grains, and thus the dynamic effective medium approximation (DEMA (Chýlek and Srivastava, 1983 is a more appropriate optical representation for BC/ice composites than coated-sphere or standard mixing approximations. DEMA calculations show that the 460 nm absorption cross-section of BC/ice composites, normalized to the mass of BC, is typically enhanced by factors of 1.8–2.1 relative to interstitial BC. BC effective radius is the dominant cause of variation in this enhancement, compared with ice grain size and BC volume fraction. We apply two atmospheric aerosol models that simulate interstitial and within-hydrometeor BC lifecycles. Although only ~2% of the atmospheric BC burden is cloud-borne, 71–83% of the BC deposited to global snow and sea-ice surfaces occurs within hydrometeors. Key processes responsible for within-snow BC deposition are development of hydrophilic coatings on BC, activation of liquid droplets, and subsequent snow formation through riming or ice nucleation by other species and aggregation/accretion of ice particles. Applying deposition fields from these aerosol models in offline snow and sea-ice simulations, we calculate that 32–73% of BC in global surface snow resides within ice grains. This fraction is smaller than the within-hydrometeor deposition fraction because meltwater flux preferentially removes internal BC, while sublimation and freezing within snowpack expose internal BC. Incorporating the DEMA into a global climate model, we simulate increases in BC/snow radiative forcing of 43–86%, relative to scenarios that apply external optical properties to all BC. We

  20. Enhanced solar energy absorption by internally-mixed black carbon in snow grains

    Directory of Open Access Journals (Sweden)

    M. G. Flanner

    2012-01-01

    Full Text Available Here we explore light absorption by snowpack containing black carbon (BC particles residing within ice grains. Basic considerations of particle volumes and BC/snow mass concentrations show that there are generally 0.05–109 BC particles for each ice grain. This suggests that internal BC is likely distributed as multiple inclusions within ice grains, and thus the dynamic effective medium approximation (DEMA (Chýlek and Srivastava, 1983 is a more appropriate optical representation for BC/ice composites than coated-sphere or standard mixing approximations. DEMA calculations show that the 460 nm absorption cross-section of BC/ice composites, normalized to the mass of BC, is typically enhanced by factors of 1.8–2.1 relative to interstitial BC. BC effective radius is the dominant cause of variation in this enhancement, compared with ice grain size and BC volume fraction. We apply two atmospheric aerosol models that simulate interstitial and within-hydrometeor BC lifecycles. Although only ~2% of the atmospheric BC burden is cloud-borne, 71–83% of the BC deposited to global snow and sea-ice surfaces occurs within hydrometeors. Key processes responsible for within-snow BC deposition are development of hydrophilic coatings on BC, activation of liquid droplets, and subsequent snow formation through riming or ice nucleation by other species and aggregation/accretion of ice particles. Applying deposition fields from these aerosol models in offline snow and sea-ice simulations, we calculate that 32–73% of BC in global surface snow resides within ice grains. This fraction is smaller than the within-hydrometeor deposition fraction because meltwater flux preferentially removes internal BC, while sublimation and freezing within snowpack expose internal BC. Incorporating the DEMA into a global climate model, we simulate increases in BC/snow radiative forcing of 43–86%, relative to scenarios that apply external optical properties to all BC. We