WorldWideScience

Sample records for bronze

  1. Bronze Saddlery

    Institute of Scientific and Technical Information of China (English)

    1996-01-01

    A number of relics were unearthed when Chinese archaeologists discovered a group of graves in Liaoning Province in April, 1976. Dating back to the Spring and Autumn Period and the Warring States Period, the tombs contained many bronze ornaments for saddles that featured such animals as frogs, snakes, tigers and rabbits.

  2. Bronze rainbow hologram mirrors

    Science.gov (United States)

    Dawson, P.

    2006-02-01

    This project draws on holographic embossing techniques, ancient artistic conventions of bronze mirror design and modelling and casting processes to accomplish portraiture of reflection. Laser scanning, 3D computer graphics and holographic imaging are employed to enable a permanent 3D static holographic image to appear integrated with the real-time moving reflection of a viewer's face in a polished bronze disc. The disc and the figure which holds it (caryatid) are cast in bronze from a lost wax model, a technique which has been used for millennia to make personal mirrors. The Caryatid form of bronze mirror which went through many permutations in ancient Egyptian, Greece and Rome shows a plethora of expressive figure poses ranging from sleek nudes to highly embellished multifigure arrangements. The prototype of this series was made for Australian choreographer Graeme Murphy, Artistic Director of the Sydney Dance Company. Each subsequent mirror will be unique in figure and holographic imagery as arranged between artist and subject. Conceptually this project references both the modern experience of viewing mirrors retrieved from ancient tombs, which due to deterioration of the surface no longer reflect, and the functioning of Chinese Magic mirrors, which have the ability to project a predetermined image. Inspired by the metaphorical potential of these mirrors, which do not reflect the immediate reality of the viewer, this bronze hologram mirror series enables each viewer to reflect upon himself or herself observing simultaneously the holographic image and their own partially obliterated reflection.

  3. Bronze Age Acrobats

    DEFF Research Database (Denmark)

    Iversen, Rune

    2014-01-01

    immaterial, ritual and cosmological exchange that characterized the second and early firstmillennium BC.Beliefs and ritual practices went hand in hand with the adoption of a series of elite items and an aristocratic lifestyle, thereby creating a unique and fascinating European Bronze Age....

  4. Ancient Chinese Bronzes: Teacher's Packet.

    Science.gov (United States)

    Smithsonian Institution, Washington, DC. Arthur M. Sackler Gallery.

    The focus of this teacher's packet is the bronze vessels made for the kings and great families of the early Chinese dynasties between 1700 B.C. and 200 A.D. The materials in the guide are intended for use by teachers and students visiting the exhibition, "The Arts of China," at the Arthur M. Sackler Gallery of the Smithsonian Institution in…

  5. Bronze Statuettes in Roman Graves

    Directory of Open Access Journals (Sweden)

    Margherita Bolla

    2014-02-01

    Full Text Available This research follows the investigations about the relationship between bronze statuettes and contexts in Roman times, particularly explored by Annemarie Kaufmann-Heinimann. The rarity of bronze figures (human, divine and animals in Roman tombs of Imperial age has been repeatedly emphasized. The aim of the paper is the collection, not exhaustive, of evidences in funerary contexts, to determine their meaning. From a methodological point of view, it was necessary to exclude figurines placed in graves but with other originary functions and several bronzes whose finding in tombs is unreliable. This preliminary survey has given about eighty all-round bronzes from burials, distributed in different areas, both in the Empire and marginal. Considering the huge amount of Roman burials known today, the overall evidence is scarce but allows some observations; it is evident the pre-eminence of Venus and Mercury, gods which had a funerary role. There is also an attempt to find the reasons of the rarity of metal statuettes in the tombs of roman period.

  6. Decorative layers on tin bronzes

    Directory of Open Access Journals (Sweden)

    Z. Konopka

    2010-10-01

    Full Text Available Decorative layers are decisive for aesthetic value of castings, therefore significant demands are raised towards such layers, e.g. pleasant durable colour, gloss, and smoothness. The work discusses the influence of the type of mechanical working applied to the surfaces of CuSn10 tin bronze castings on the quality and durability of a decorative coating. The scope of the work has included designing and manufacturing of cast samples of tin bronze, mechanical working of the surfaces in order to prepare them for applying coating layers,generating decorative layers as a result of chemical reactions, and the quality assessment and comparison of the obtained coating. Theassessment of thickness and continuity of the obtained decorative layers based on metallographic examinations has been presented.

  7. The Bronze Age Smith as Individual

    DEFF Research Database (Denmark)

    Nørgaard, Heide Wrobel

    During 1550-1100 BC magnificent decorated bronze objects appear in grave and hoard finds in Northwest Europe. While investigating similarities in the decorative elements of bronze objects belonging to the female gender, it is possible to find traces of the production process. These distinctive fe...

  8. New Research on Bronze Age Textile Production

    DEFF Research Database (Denmark)

    Andersson, Eva Birgitta; Mårtensson, Linda; Nosch, Marie-Louise Bech;

    2008-01-01

    presentation of the results from the systematic tests with Bronze Age textile tools. results concerning mesurements of lenght and time consumed.......presentation of the results from the systematic tests with Bronze Age textile tools. results concerning mesurements of lenght and time consumed....

  9. Population genomics of Bronze Age Eurasia.

    Science.gov (United States)

    Allentoft, Morten E; Sikora, Martin; Sjögren, Karl-Göran; Rasmussen, Simon; Rasmussen, Morten; Stenderup, Jesper; Damgaard, Peter B; Schroeder, Hannes; Ahlström, Torbjörn; Vinner, Lasse; Malaspinas, Anna-Sapfo; Margaryan, Ashot; Higham, Tom; Chivall, David; Lynnerup, Niels; Harvig, Lise; Baron, Justyna; Della Casa, Philippe; Dąbrowski, Paweł; Duffy, Paul R; Ebel, Alexander V; Epimakhov, Andrey; Frei, Karin; Furmanek, Mirosław; Gralak, Tomasz; Gromov, Andrey; Gronkiewicz, Stanisław; Grupe, Gisela; Hajdu, Tamás; Jarysz, Radosław; Khartanovich, Valeri; Khokhlov, Alexandr; Kiss, Viktória; Kolář, Jan; Kriiska, Aivar; Lasak, Irena; Longhi, Cristina; McGlynn, George; Merkevicius, Algimantas; Merkyte, Inga; Metspalu, Mait; Mkrtchyan, Ruzan; Moiseyev, Vyacheslav; Paja, László; Pálfi, György; Pokutta, Dalia; Pospieszny, Łukasz; Price, T Douglas; Saag, Lehti; Sablin, Mikhail; Shishlina, Natalia; Smrčka, Václav; Soenov, Vasilii I; Szeverényi, Vajk; Tóth, Gusztáv; Trifanova, Synaru V; Varul, Liivi; Vicze, Magdolna; Yepiskoposyan, Levon; Zhitenev, Vladislav; Orlando, Ludovic; Sicheritz-Pontén, Thomas; Brunak, Søren; Nielsen, Rasmus; Kristiansen, Kristian; Willerslev, Eske

    2015-06-11

    The Bronze Age of Eurasia (around 3000-1000 BC) was a period of major cultural changes. However, there is debate about whether these changes resulted from the circulation of ideas or from human migrations, potentially also facilitating the spread of languages and certain phenotypic traits. We investigated this by using new, improved methods to sequence low-coverage genomes from 101 ancient humans from across Eurasia. We show that the Bronze Age was a highly dynamic period involving large-scale population migrations and replacements, responsible for shaping major parts of present-day demographic structure in both Europe and Asia. Our findings are consistent with the hypothesized spread of Indo-European languages during the Early Bronze Age. We also demonstrate that light skin pigmentation in Europeans was already present at high frequency in the Bronze Age, but not lactose tolerance, indicating a more recent onset of positive selection on lactose tolerance than previously thought. PMID:26062507

  10. The Bronze Age Smith as Individual

    OpenAIRE

    Nørgaard, Heide Wrobel

    2011-01-01

    During 1550-1100 BC magnificent decorated bronze objects appear in grave and hoard finds in Northwest Europe. While investigating similarities in the decorative elements of bronze objects belonging to the female gender, it is possible to find traces of the production process. These distinctive features can help to identify workshops and their sphere of influence. Sometimes these traces have the ability to give much more information than just indicate the crafting process of the object. Errors...

  11. Research on the Orientation of Decoration on Bronzes from Yinxu

    Institute of Scientific and Technical Information of China (English)

    岳洪彬

    2003-01-01

    The study of surface decoration is one important aspect of research on Yinxu 殷墟 bronzes and has been a particular focus of investigations of bronzes from the Three Dynasties. Previous scholars have already made great strides in this line of research and they have provided not only an important precedent for making chronological distinctions among the late Shang bronzes.

  12. “Neutron metallography” of archaeological bronzes

    Science.gov (United States)

    Siano, S.; Bartoli, L.; Kockelmann, W.; Zoppi, M.; Miccio, M.

    2004-07-01

    Following a first demonstration on the potentials of time-of-flight neutron diffraction in the microstructural characterisation of archaeological bronzes, we present here the results of a further systematic study on the topic. The experiments were performed on standardised specimens and original archaeological bronze findings at the powder diffractometer ROTAX. The possibility to achieve various metallographic data concerning alloy composition, homogeneity, dendritic structure, metal and mineral phases, as well as the effects of hardening, annealing, and re-crystallisation processes was successfully demonstrated. Furthermore, we also report a texture analysis on a Roman coin, which provided a clear striking fingerprint thus demonstrating a powerful authentication method.

  13. 75 FR 14257 - Pricing for Bronze Medals

    Science.gov (United States)

    2010-03-24

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF THE TREASURY United States Mint Pricing for Bronze Medals AGENCY: United States Mint, Department of the Treasury. ACTION: Notice. SUMMARY: The United States Mint is announcing the price of the 1\\5/16\\- inch...

  14. Copper and bronze coating with molybdenite

    International Nuclear Information System (INIS)

    The conditions were studied for producing qualitative bronze self-lubricating composite electrochemical coatings (SCEC). The copper composite coatings have been produced from sulfate electrolyte used for copper plating. The bronze SCEC have been obtained from a bath of the composition: tin dichloride-35, copper chloride-40, pyrophosphoric potassium-490. The problem of the optimal planning of Cu-MoS2 composite coatings characteristics has been considered. The matrix of the experiments planning is given, as well as the test results and numerical solution of coefficients of regression equations. The hardness of the bronze SCEC is affected most of all by the concentration and acidity of the suspension, and least of all - by the bath temperature. The friction coefficient of the self-lubricating coatings coupled with brass depends to a greater extent on the temperature and concentration of the suspension. The highest decrease of the friction coefficient can be expected at the minimum value of the abovesaid technological factors. The transient electric conductivity of the couple undergoing friction in air depends mainly on the cathode current density and concentration of dispersion phase in the electrolyte used for bronze plating. With the increase in the suspension concentration (and, therefore, in the amount of MoS2 inclusions into the coatings) the antifriction properties of the SCEC enhance. The dispersion addition increases the transient electric conductivity of the contact, however this does not prevent SCEC from being used in electrocommutation devices

  15. Population genomics of Bronze Age Eurasia

    DEFF Research Database (Denmark)

    Allentoft, Morten E.; Sikora, Martin; Sjögren, Karl-Göran;

    2015-01-01

    The Bronze Age of Eurasia (around 3000-1000 BC) was a period of major cultural changes. However, there is debate about whether these changes resulted from the circulation of ideas or from human migrations, potentially also facilitating the spread of languages and certain phenotypic traits. We inv...... a more recent onset of positive selection on lactose tolerance than previously thought....

  16. Thermal and Electrical Conductivity Measurements of CDA 510 Phosphor Bronze

    Science.gov (United States)

    Tuttle, James E.; Canavan, Edgar; DiPirro, Michael

    2009-01-01

    Many cryogenic systems use electrical cables containing phosphor bronze wire. While phosphor bronze's electrical and thermal conductivity values have been published, there is significant variation among different phosphor bronze formulations. The James Webb Space Telescope (JWST) will use several phosphor bronze wire harnesses containing a specific formulation (CDA 510, annealed temper). The heat conducted into the JWST instrument stage is dominated by these harnesses, and approximately half of the harness conductance is due to the phosphor bronze wires. Since the JWST radiators are expected to just keep the instruments at their operating temperature with limited cooling margin, it is important to know the thermal conductivity of the actual alloy being used. We describe an experiment which measured the electrical and thermal conductivity of this material between 4 and 295 Kelvin.

  17. 77 FR 14600 - Pricing for 2012 Kennedy Half-Dollar Bags and Rolls, Bronze Medals, the First Spouse Bronze Medal...

    Science.gov (United States)

    2012-03-12

    ... United States Mint Pricing for 2012 Kennedy Half-Dollar Bags and Rolls, Bronze Medals, the First Spouse.... SUMMARY: The United States Mint is announcing 2012 pricing for Kennedy Half-Dollar bags and rolls, bronze..., Associate Director for Sales and Marketing; United States Mint; 801 9th Street NW., Washington, DC 20220;...

  18. Gold and Silver Inlaid Bronze Sheep

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Gold and silver inlaying is a metal processing technique popular during the Spring and Autumn Period (770-476 B. C.) and the Warring States Period (475-221 B. C.). Patterns on the surface of the bronze figure are chiselled out and gold and silver threads (which can be as thin as hair) are inlaid. Finally the whole figure is filed and polished resulting in a splendid artistic work highlighting the different colours of the three different kinds of metal. The artifact shown here was unearthed from Ningxia'...

  19. Atomically resolved images of lithium purple bronze

    Energy Technology Data Exchange (ETDEWEB)

    Klinke, Melanie; Bienert, Robert; Waelsch, Michael; Podlich, Tatjana; Matzdorf, Rene [Experimentalphysik II, Universitaet Kassel (Germany); Jin, Rongying [Department of Physics and Astronomy, Lousiana State University (United States)

    2012-07-01

    The lithium molybdenum purple bronze Li{sub 0.9}Mo{sub 6}O{sub 17} is a quasi 1D metal at room temperature showing Luttinger liquid physics. The highly anisotropic conductivity runs along the crystallographic b axis where Mo-O chains, formed by the shared edges of the MoO{sub 6} octahedra, provide the electrical transport. Li{sub 0.9}Mo{sub 6}O{sub 17} samples were investigated with low-temperature scanning tunneling microscopy and spectroscopy. By cleaving the samples at low temperatures (60 K) we obtained atomically resolved images of the surface. In these images the Mo-O chains are visible, which are covered by layers of MoO{sub 6} octahedra and MoO{sub 4} tetrahedra.

  20. Russian meteorite Bronze Age (rock record)

    CERN Document Server

    Vodolazhskaya, Larisa

    2013-01-01

    This paper presents the results of a study of petroglyphs found in the quartzite grotto near the Skelnovsky small village in the Northern Black Sea in the South of Russia. The aim of the study was the analysis and interpretation of the Early Bronze Age petroglyphs using archaeoastronomical methods. The article presents a comparative analysis of Skelnovsky grotto ancient images and contemporary eyewitness accounts of the Sikhote-Alin meteorite fall and meteorite shower. Some petroglyphs were interpreted by us using ethnographic and folklore material. In this study, the magnetic declination for the geographical coordinates Skelnovsky farm was calculated, and the projection of the whole picture Skelnovskih petroglyphs on the topographical map of the area was built. The proposed location of the meteorite fall was determined with this projection. It is confirmed by satellite pictures, on which are the distinguishable terrain features, typical for the meteorite fall, are visible including the possible impact crater...

  1. Stamps of New China Eastern Zhou Dynasty Bronzes

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    The State Postal Bureau’s latest set of special stamps for 2003 features Eastern Zhou Dynasty (770-256 B,C.) bronzes. This eight-stamp set is the third to feature this type of relic; a set issued in 1964 depicted bronzes from the Yin Dynasty (14th-11th century}, and one featuring Western Zhou Dynasty (11th century-771 B.C.) bronzes was released in 1982.The Eastern Zhou Dynasty followed the Western, and during this period, bronze vessel casting developed remarkably. Artifacts from this period include sacrificial vessels, musical instruments, utensils, weapons and tools.One of these pieces, a rectangular tray decorated with tortoise and fish patterns, dates back to the late Spring and Autumn Period

  2. Reversibility of the lithium-vanadium bronze structure when cycled

    International Nuclear Information System (INIS)

    The positive electrodes of the lithium secondary current sources, manufactured on the basis of the Li1+x V3O8 lithium-vanadium bronze, obtained through the alcoxotechnology, are studied. It is established, that in proportion to the lithium introduction the initial crystalline bronze renders amorphous, remaining a single-phase one. Increase in the x-lithifying rate leads practically to decrease in the α-parameters and increase in the b- and c-parameters of the bronze crystal lattice, whereby these changes are quite reversible by cycling. The obvious degradation of the electrode electrical parameters is not connected with irreversible structural changes and may be explained by formation of passive films on the surface of the particles of the lithium-vanadium bronze

  3. 75 FR 57825 - Culturally Significant Objects Imported for Exhibition Determinations: “Ancient Chinese Bronzes...

    Science.gov (United States)

    2010-09-22

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF STATE Culturally Significant Objects Imported for Exhibition Determinations: ``Ancient Chinese Bronzes From the... objects to be included in the exhibition ``Ancient Chinese Bronzes from the Shouyang Studio: The...

  4. Electrochemical testing of laser treated bronze surface

    Energy Technology Data Exchange (ETDEWEB)

    Yilbas, B.S., E-mail: bsyilbas@kfupm.edu.sa [Dept. of Mechanical Engineering, King Fahd University of Petroleum and Minerals (KFUPM), Dhahran 31261 (Saudi Arabia); Toor, Ihsan-ul-Haq; Malik, Jahanzaib; Patel, F. [Dept. of Mechanical Engineering, King Fahd University of Petroleum and Minerals (KFUPM), Dhahran 31261 (Saudi Arabia); Karatas, C. [Engineering Faculty, Hacettepe University, Ankara (Turkey)

    2013-06-25

    Highlights: ► Laser treated surface is free from asperities. ► Laser treated layer extends uniformly below the surface with a thickness in the order of 40 μm. ► Presence of Cu{sub 3}N nitrides is evident from X-ray diffractogram. ► Dendritic structure is formed below the surface due to relatively slower cooling rates as compared to that at the surface. ► The corrosion current density for the laser treated surface is much less than that of the as-received surface. -- Abstract: Electrochemical testing of laser treated bronze surface is carried out and corrosion resistance of the surface is assessed. Morphological and metallurgical changes in the laser treated layer are examined using scanning electron microscope, energy dispersive spectroscopy, and X-ray diffraction. The pit sites formed at the surface are analyzed using scanning electron microscope. It is found that laser treatment improves the corrosion resistance of the treated surface. Fine grains are formed in the surface region of the laser treated layer, which are attributed to the large cooling rates from the surface.

  5. Study of patina formation on bronze specimens

    International Nuclear Information System (INIS)

    In this study, bronze samples (94.059% Cu; 0.023% Zn; 0.077% Pb and 5.801% Sn, w/w) were exposed for 8 months to a marine atmosphere (splash zone) at Barra of Tijuca Beach, Rio de Janeiro. X-ray diffraction analysis (XRD) was used to identify the composition of the corrosion products formed on the samples. The electrochemical properties were analyzed using potential and electrochemical impedance measurements. These analyses and measurements were obtained from periodically removed samples, and compared to those exposed to laboratory tests (total and alternating immersion) in 10-2 mol L-1 NaCl solution. The corrosion potential results, allied to XRD analysis, showed that the chemical nature of the films obtained on the surface of the field test samples was very similar to that obtained in the alternating immersion test. The main products identified were cuprite and atacamite. However, the film formed during the total immersion (TI) test was primarily composed of cuprite with nantokite traces, which was not observed in either the field or in alternating tests. The electrochemical impedance measurements obtained in laboratory and field test samples showed the formation of films with a porous structure. The thermodynamic evaluation was also consistent with the corrosion products formed.

  6. Evaluation of Bio-field Treatment on Physical and Structural Properties of Bronze Powder

    OpenAIRE

    Mahendra Kumar Trivedi; Gopal Nayak; Rama Mohan Tallapragada

    2015-01-01

    Bronze, a copper-tin alloy, widely utilizing in manufacturing of gears, bearing, and packing technologies due to its versatile physical, mechanical, and chemical properties. The aim of the present work was to evaluate the effect of bio-field treatment on physical and structural properties of bronze powder. Bronze powder was divided into two samples, one served as control and the other sample was received bio-field treatment. Control and treated bronze samples were characterized using x-ray di...

  7. Evaluation of Biofield Treatment on Physical and Structural Properties of Bronze Powder

    OpenAIRE

    Trivedi, Mahendra; Nayak, Gopal

    2015-01-01

    Bronze, a copper-tin alloy, widely utilizing in manufacturing of gears, bearing, and packing technologies due to its versatile physical, mechanical, and chemical properties. The aim of the present work was to evaluate the effect of biofield treatment on physical and structural properties of bronze powder. Bronze powder was divided into two samples, one served as control and the other sample was received biofield treatment. Control and treated bronze samples were characterized using x-ray diff...

  8. Prompt gamma-ray analysis of archaeological bronze

    International Nuclear Information System (INIS)

    Prompt γ-ray analysis using the internal monostandard method was applied to voluminous archaeological bronze mirrors produced in ancient China. Sn/Cu content ratios were determined nondestructively by this method. Furthermore, Au/Cu, As/Cu, and Sb/Cu content ratios were determined by means of measuring decay γ-rays emitted from radioactive nuclides produced within samples via (n,γ) reactions. It is clear that the Sn/Cu content ratios in bronze mirrors produced in the Sung era is smaller than in ones produced in between the Han and the Tung era. (author)

  9. The Early Bronze Age Dwellings in the Southern Levant

    Directory of Open Access Journals (Sweden)

    Deborah Sebag

    2007-10-01

    Full Text Available The house is a strategic base for the study of any given civilization. By studying the habitations, it is possible to find indications of not only the way of life of its occupants, their social organization, their world view, their needs, their resources but also of the available technologies. In this study, we will give a chronological presentation of the various types of dwellings through the Early Bronze age, in the Southern Levant. It is during the Early Bronze Age (3 100-2 000 B.C., t...

  10. Archaeological investigations of the Bronze Age village of Bagnara di Romagna (RA

    Directory of Open Access Journals (Sweden)

    Maurizio Cattani

    2014-12-01

    Full Text Available This paper summarizes the results of researches carried out in the area next to the modern village of Bagnara di Romagna (RA, where several evidences related to a Bronze Age settlement have been collected. Recently test trenches and surface collections allowed to retrieve bronze and ceramics dating from the Middle Bronze Age (phase BM2 to the Recent Bronze Age (phase BR2. The analysis of landscape and the palaeoenvironmental reconstruction complete the outline of the region of Imola, Faenza and Lugo during the Bronze Age where are well known the ancient settlements of Solarolo, via Ordiere, Monte Castellaccio end S. Giuliano di Toscanella.

  11. Origin of the mysterious Yin-Shang bronzes in China indicated by lead isotopes

    Science.gov (United States)

    Sun, Wei-dong; Zhang, Li-peng; Guo, Jia; Li, Cong-ying; Jiang, Yu-hang; Zartman, Robert E.; Zhang, Zhao-feng

    2016-01-01

    Fine Yin-Shang bronzes containing lead with puzzlingly highly radiogenic isotopic compositions appeared suddenly in the alluvial plain of the Yellow River around 1400 BC. The Tongkuangyu copper deposit in central China is known to have lead isotopic compositions even more radiogenic and scattered than those of the Yin-Shang bronzes. Most of the Yin-Shang bronzes are tin-copper alloys with high lead contents. The low lead and tin concentrations, together with the less radiogenic lead isotopes of bronzes in an ancient smelting site nearby, however, exclude Tongkuangyu as the sole supplier of the Yin-Shang bronzes. Interestingly, tin ingots/prills and bronzes found in Africa also have highly radiogenic lead isotopes, but it remains mysterious as to how such African bronzes may have been transported to China. Nevertheless, these African bronzes are the only bronzes outside China so far reported that have lead isotopes similar to those of the Yin-Shang bronzes. All these radiogenic lead isotopes plot along ~2.0–2.5 Ga isochron lines, implying that deposits around Archean cratons are the most likely candidates for the sources. African cratons along the Nile and even micro-cratons in the Sahara desert may have similar lead signatures. These places were probably accessible by ancient civilizations, and thus are the most favorable suppliers of the bronzes. PMID:26988425

  12. Origin of the mysterious Yin-Shang bronzes in China indicated by lead isotopes

    Science.gov (United States)

    Sun, Wei-Dong; Zhang, Li-Peng; Guo, Jia; Li, Cong-Ying; Jiang, Yu-Hang; Zartman, Robert E.; Zhang, Zhao-Feng

    2016-03-01

    Fine Yin-Shang bronzes containing lead with puzzlingly highly radiogenic isotopic compositions appeared suddenly in the alluvial plain of the Yellow River around 1400 BC. The Tongkuangyu copper deposit in central China is known to have lead isotopic compositions even more radiogenic and scattered than those of the Yin-Shang bronzes. Most of the Yin-Shang bronzes are tin-copper alloys with high lead contents. The low lead and tin concentrations, together with the less radiogenic lead isotopes of bronzes in an ancient smelting site nearby, however, exclude Tongkuangyu as the sole supplier of the Yin-Shang bronzes. Interestingly, tin ingots/prills and bronzes found in Africa also have highly radiogenic lead isotopes, but it remains mysterious as to how such African bronzes may have been transported to China. Nevertheless, these African bronzes are the only bronzes outside China so far reported that have lead isotopes similar to those of the Yin-Shang bronzes. All these radiogenic lead isotopes plot along ~2.0–2.5 Ga isochron lines, implying that deposits around Archean cratons are the most likely candidates for the sources. African cratons along the Nile and even micro-cratons in the Sahara desert may have similar lead signatures. These places were probably accessible by ancient civilizations, and thus are the most favorable suppliers of the bronzes.

  13. Reporting Casting Bronze Plaque Becomes Advisers Class Project

    Science.gov (United States)

    Ross, Charlie

    1977-01-01

    Describes an advisers' class project (at the University of Oklahoma) which consisted of reporting on the casting of a bronze plaque bearing the names of the first school newspaper, "The Students Gazette," and its editor, Samuel M. Fox, for presentation in Philadelphia to commemorate scholastic journalism's Bicentennial. (MB)

  14. Panetta Awarded Bronze Star for Afghanistan Intel Mission

    OpenAIRE

    Naval Postgraduate School Public Affairs Office

    2008-01-01

    Fellow officers in full dress uniform, family and friends ringed the room in rapt attention as Naval Reserve Lt. James Panetta was awarded the Bronze Star Medal by Naval Postgraduate School President Daniel Oliver in a special ceremony in the President's Conference Room, Dec. 9.

  15. Corrosion behavior of leaded-bronze alloys in sea water

    Energy Technology Data Exchange (ETDEWEB)

    Zohdy, K.M., E-mail: khalzohdy@yahoo.com [Higher Technological Institute, 10" t" h of Ramadan City (Egypt); Sadawy, M.M. [Mining and Petroleum Engineering Department, Al-Azhar University, Nasr City, Cairo 11371 (Egypt); Ghanem, M. [Industrial Education, Suez University (Egypt)

    2014-10-15

    The corrosion behavior of leaded-bronze alloys (Cu–5Sn–5Zn–5Pb, Cu–8Sn–8Zn–8Pb and Cu–10Sn–10Zn–10Pb) in sea water was investigated using weight loss method, open-circuit potential measurements (OCP), polarization techniques and electrochemical impedance spectroscopy (EIS). The nature and morphology of the corrosion products were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results showed that the corrosion resistance decreases with decreasing copper content. The XRD indicated that the composition of patina depends on the concentration of Cu, Sn, Zn and Pb in each alloy. - Highlights: • The corrosion potential of leaded bronze shifts to more noble potential. • The corrosion resistance increases with increasing amount of copper content in leaded bronze alloys. • The patina formed on Cu–5Sn–5Zn–5Pb is more uniform and protective than other alloys. • The composition of patina formed on leaded bronze depends on the concentration of Cu, Sn, Zn and Pb in the alloy.

  16. Electrodeposited nanocrystalline bronze alloys as replacement for Ni

    NARCIS (Netherlands)

    Hovestad, A.; Tacken, R.A.; Mannetje, H.H.'t

    2008-01-01

    Nanocrystalline white-bronze, CuSn, electroplating was investigated as alternative to Ni plating as undercoat for noble metals in jewellery applications. A strongly acidic plating bath was developed with an organic additive to suppress hydrogen evolution and obtain bright coatings. Polarization curv

  17. The study of bronze statuettes with the help of neutron-imaging techniques

    OpenAIRE

    Van Langh, R.; Lehmann, E; Hartmann, S.; Kaestner, A.; Scholten, F.

    2009-01-01

    Until recently fabrication techniques of Renaissance bronzes have been studied only with the naked eye, microscopically, videoscopically and with X-radiography. These techniques provide information on production techniques, yet much important detail remains unclear. As part of an interdisciplinary study of Renaissance bronzes undertaken by the Rijksmuseum Amsterdam, neutron-imaging techniques have been applied with the aim of obtaining a better understanding of bronze workmanship during the R...

  18. Characterization of bronzes by abrasive stripping voltammetry and thin layer chromatography

    OpenAIRE

    Komorsky-Lovrić, Šebojka; Horvat, Alka J.M.; Ivanković, Danijela

    2006-01-01

    Corrosion potentials of five samples of bronzes having different compositions and the stripping peak potentials of their main components were determined by abrasive stripping voltammetry. Using thin-layer chromatography in combination with electrochemical dissolution of bronzes in the two electrode sampler, the ions of tin, copper, lead and nickel were detected as the products of electro-oxidation of bronzes. It is shown that the dissolution of tin is preferential at low potential differences...

  19. Rewriting the Central European Early Bronze Age Chronology: Evidence from Large-Scale Radiocarbon Dating.

    Directory of Open Access Journals (Sweden)

    Philipp W Stockhammer

    Full Text Available The transition from the Neolithic to the Early Bronze Age in Central Europe has often been considered as a supra-regional uniform process, which led to the growing mastery of the new bronze technology. Since the 1920s, archaeologists have divided the Early Bronze Age into two chronological phases (Bronze A1 and A2, which were also seen as stages of technical progress. On the basis of the early radiocarbon dates from the cemetery of Singen, southern Germany, the beginning of the Early Bronze Age in Central Europe was originally dated around 2300/2200 BC and the transition to more complex casting techniques (i.e., Bronze A2 around 2000 BC. On the basis of 140 newly radiocarbon dated human remains from Final Neolithic, Early and Middle Bronze Age cemeteries south of Augsburg (Bavaria and a re-dating of ten graves from the cemetery of Singen, we propose a significantly different dating range, which forces us to re-think the traditional relative and absolute chronologies as well as the narrative of technical development. We are now able to date the beginning of the Early Bronze Age to around 2150 BC and its end to around 1700 BC. Moreover, there is no transition between Bronze (Bz A1 and Bronze (Bz A2, but a complete overlap between the type objects of the two phases from 1900-1700 BC. We thus present a revised chronology of the assumed diagnostic type objects of the Early Bronze Age and recommend a radiocarbon-based view on the development of the material culture. Finally, we propose that the traditional phases Bz A1 and Bz A2 do not represent a chronological sequence, but regionally different social phenomena connected to the willingness of local actors to appropriate the new bronze technology.

  20. Quantitative multiphase analysis of archaeological bronzes by neutron diffraction

    CERN Document Server

    Siano, S; Celli, M; Pini, R; Salimbeni, R; Zoppi, M; Kockelmann, W A; Iozzo, M; Miccio, M; Moze, O

    2002-01-01

    In this paper, we report the first investigation on the potentials of neutron diffraction to characterize archaeological bronze artifacts. The preliminary feasibility of phase and structural analysis was demonstrated on standardised specimens with a typical bronze alloy composition. These were realised through different hardening and annealing cycles, simulating possible ancient working techniques. The Bragg peak widths that resulted were strictly dependent on the working treatment, thus providing an important analytical element to investigate ancient making techniques. The diagnostic criteria developed on the standardised specimens were then applied to study two Etruscan museum pieces. Quantitative multiphase analysis by Rietveld refinement of the diffraction patterns was successfully demonstrated. Furthermore, the analysis of patterns associated with different artifact elements also yielded evidence for some peculiar perspective of the neutron diffraction diagnostics in archeometric applications. (orig.)

  1. Friction stir processing / welding of NiAl bronzes

    OpenAIRE

    McNelley, Terry; Menon, Sarath

    2016-01-01

    Research Project Friction stir processing (FSP) of as-cast NiAl bronzes converts the as-cast microstructure to a wrought condition in the volume of materials subjected to the process. This results in improved properties in the absence of component shape change. With the development of portable systems, friction stir processing may enable in situ repair of defective components such as propellers and thus avoid expensive procedures such as dry docking for such repairs.

  2. NUMERICAL MODELING OF HARDENING OF UNINTERRUPTEDLY-CASTED BRONZE CASTING

    Directory of Open Access Journals (Sweden)

    E. I. Marukovich

    2009-01-01

    Full Text Available The three-dimensional numerical model for calculation of thermal fields during solidification of continuously casted bronze casting is developed. Coefficients of heat transfer on borders of calculation areas on the basis of the solution of inverse heat transfer conduction problem are determined. The analysis of thermal fields, depending on loop variables of drawing and the sizes of not cooled zone of crystallizer is curried out.

  3. Prevention of Dealloying in Manganese Aluminium Bronze Propeller: Part II

    OpenAIRE

    Napachat Tareelap; Kaysinee Sriraksasin; Nakorn Srisukhumbowornchai; Swieng Thuanboon; Choochat Nitipanyawong

    2014-01-01

    Due to the failure of manganese aluminium bronze (MAB) propeller caused by dealloying corrosion as described in Part I [1], this work aims to study the prevention of dealloying corrosion using aluminium and zinc sacrificial anodes. The results indicated that both of the sacrificial anodes could prevent the propeller from dealloying. Moreover, the dealloying in seawater was less than that found in brackish water. It was possible that hydroxide ions, from cathodic reaction, reacted with calcium...

  4. The Development of Iron Technology in the Mediterranean Bronze Age

    OpenAIRE

    Leek, Rodney Thomas

    2014-01-01

    In the eastern Mediterranean region in the Bronze Age there were a number of elite controlled, complex societies that through cultural activities and trade and international agreements, participated in a regional exchange economy. In the transition to Iron Age there was a confusing period with wars, migrations and the collapse of most of the elite societies,. At this time, iron technology had already spread to some parts of the region. When the regional economy collapsed in c. 1200 BC it crea...

  5. Tamil Chola Bronzes and Swamimalai Legacy: Metal Sources and Archaeotechnology

    Science.gov (United States)

    Srinivasan, Sharada

    2016-05-01

    This review explores the great copper alloy image casting traditions of southern India from archaeometallurgical and ethnometallurgical perspectives. The usefulness of lead isotope ratio and compositional analysis in the finger-printing and art historical study of more than 130 early historic, Pallava, Chola, later Chola, and Vijayanagara sculptures (fifth-eighteenth centuries) is highlighted, including Nataraja, Buddha, Parvati, and Rama images made of copper, leaded bronze, brass, and gilt copper. Image casting traditions at Swamimalai in Tamil Nadu are compared with artistic treatises and with the technical examination of medieval bronzes, throwing light on continuities and changes in foundry practices. Western Indian sources could be pinpointed for a couple of medieval images from lead isotope analysis. Slag and archaeometallurgical investigations suggest the exploitation of some copper and lead-silver sources in the Andhra and Karnataka regions in the early historic Satavahana period and point to probable copper sources for the medieval images in Karnataka, Tamil Nadu, and Andhra Pradesh. The general lower iron content in southern Indian bronzes perhaps renders the proximal copper-magnetite reserves of Seruvila in Sri Lanka as a less likely source. Given the lack of lead deposits in Sri Lanka, however, the match of the lead isotope signatures of a well-known Ceylonese Buddhist Tara in British Museum with a Buddha image from Nagapattinam in Tamil Nadu may underscore ties between the island nation and the southern Indian Tamil regions.

  6. Matisse to Picasso: a compositional study of modern bronze sculptures.

    Science.gov (United States)

    Young, Marcus L; Schnepp, Suzanne; Casadio, Francesca; Lins, Andrew; Meighan, Melissa; Lambert, Joseph B; Dunand, David C

    2009-09-01

    Inductively coupled plasma-optical emission spectroscopy (ICP-OES) was used to determine the bulk metal elemental composition of 62 modern bronze sculptures cast in Paris in the first half of the twentieth century from the collections of The Art Institute of Chicago and the Philadelphia Museum of Art. As a result, a comprehensive survey of the alloy composition of the sculptures of many prominent European artists of the early twentieth century is presented here for the first time. The sculptures in this study consist of predominantly copper with two main alloying elements (zinc and tin). By plotting the concentrations of these two elements (zinc and tin) against each other for all the sculptures studied, three clusters of data become apparent: (A) high-zinc brass; (B) low-zinc brass; (C) tin bronze. These clusters correlate to specific foundries, which used specific casting methods (sand or lost wax) that were influenced by individual preferences and technical skills of the foundry masters. For instance, the high-zinc brass alloys (with the highest levels of tin and zinc and the lowest melting temperature) correspond to most of the Picasso sculptures, correlate with the Valsuani foundry, and are associated with the most recent sculptures (post-WWII) and with the lost-wax casting method. By expanding the ICP-OES database of objects studied, these material correlations may become useful for identifying, dating, or possibly even authenticating other bronzes that do not bear foundry marks. Figure. PMID:19629458

  7. Tamil Chola Bronzes and Swamimalai Legacy: Metal Sources and Archaeotechnology

    Science.gov (United States)

    Srinivasan, Sharada

    2016-08-01

    This review explores the great copper alloy image casting traditions of southern India from archaeometallurgical and ethnometallurgical perspectives. The usefulness of lead isotope ratio and compositional analysis in the finger-printing and art historical study of more than 130 early historic, Pallava, Chola, later Chola, and Vijayanagara sculptures (fifth-eighteenth centuries) is highlighted, including Nataraja, Buddha, Parvati, and Rama images made of copper, leaded bronze, brass, and gilt copper. Image casting traditions at Swamimalai in Tamil Nadu are compared with artistic treatises and with the technical examination of medieval bronzes, throwing light on continuities and changes in foundry practices. Western Indian sources could be pinpointed for a couple of medieval images from lead isotope analysis. Slag and archaeometallurgical investigations suggest the exploitation of some copper and lead-silver sources in the Andhra and Karnataka regions in the early historic Satavahana period and point to probable copper sources for the medieval images in Karnataka, Tamil Nadu, and Andhra Pradesh. The general lower iron content in southern Indian bronzes perhaps renders the proximal copper-magnetite reserves of Seruvila in Sri Lanka as a less likely source. Given the lack of lead deposits in Sri Lanka, however, the match of the lead isotope signatures of a well-known Ceylonese Buddhist Tara in British Museum with a Buddha image from Nagapattinam in Tamil Nadu may underscore ties between the island nation and the southern Indian Tamil regions.

  8. Chemical and Electrochemical Characterization of Artificial Sulphate Patina on Bronze

    Institute of Scientific and Technical Information of China (English)

    MAO Yangwu; NIE Dunwei; MOMBELLO Domenico

    2014-01-01

    Copper patinas are generally regarded as aesthetically pleasing and are supposed to protect copper against further corrosion. The preparation of artificial sulphate patina on bronzes has been realized by immersing the bronze into CuSO4 solution. The effect of immersion time on the formation of the patina has been investigated. The sulphate patina obtained with immersion time of 500 h in CuSO4 solution consists of flat area and crystals. The flat area in the patina is mainly made of cuprite, whereas the crystals are mainly composed of brochantite. The electrochemical measurement of sulphate patina in simulated acid rain with pH 3.1 shows that the protective effectiveness of patina decreases with time and the dissolution of patina is the key factor leading to the degradation of patina. The investigation of the formation mechanism of sulphate patina shows that the cuprite layer forms on the surface of bronze in the initial patination. Then, crystal brochantite grows on the surface of cuprite by the oxidation of cuprite and the incorporation of CuSO4 solution.

  9. HANDICRAFT IN LATE BRONZE-EARLY IRON AGE IN NAKHCHIVAN

    Directory of Open Access Journals (Sweden)

    Toğrul HALİLOV

    2012-04-01

    Full Text Available The article handicraft have been learnt in the Nakhchivan late bronze-early iron age. It was defined that pottery wasone of the ancient craftsmanship areas in Nakhichivan. At that time Nakhichivan, as well as the other regions of Azerbaijan, was an important centre of craftsmanship. The pottery products differed from one another in their size, shape, ornaments on them, the material the were made of and the technology. The pottery products made by Nakhichivan potters were divided into two groups-welfare and kitchen ceramics. Their similar monuments in the South Caucasus and the Middle East in the same period, the archaeological materials found in the Urmia basin and Eastern Anatolia. As a result of comparative investigation it is defined that oldest labour tools producted from bone and stone in Nakchivan. New type of labour tools are producted connecting to treatmen of metal in following period. Stone and bone tools are used little in iron and bronz period. It is defined that daggers, arrow and spear heads, jewelry founded in archaeological monument belong to epoch late bronze-early iron age in the Nakhchivan have got peculiarity of culture of Khojalı-Gadabay in Azerbaijan. Some of daggers belong to culture Near East.

  10. The moessbauer spectroscopy study of an ancient bronze mirror without sampling

    International Nuclear Information System (INIS)

    The Moessbauer spectra of 119Sn for a bronze mirror of the Han Dynasty are described. A method of measuring Moessbauer spectrum without sampling is established. For the sake of contrast, both the spectra of transmission and of γ-ray scattering were measured. The results show that on the surface of the bronze mirror tin is in the state of Sn4+ oxide

  11. Abrasive wear of BA1055 bronze with additives of Si, Cr, Mo and/or W

    Directory of Open Access Journals (Sweden)

    B. P. Pisarek

    2008-10-01

    Full Text Available Aluminium bronzes belong to the high-grade constructional materials applied on the put under strongly load pieces of machines, aboutgood sliding, resistant properties on corrosion both in the cast state how and after the thermal processing. It moves to them Cr and Si in the aim of the improvement of their usable proprieties. The additions Mo and/or W were not applied so far. It was worked out therefore the new kind of bronzes casting including these elements. Make additions to the Cu-Al-Fe-Ni bronze of Si, Cr, Mo and/or W in the rise of these properties makes possible. The investigations of the surface distribution of the concentration of elements in the microstructure of the studied bronze on X-ray microanalyzer were conducted. It results from conducted investigations, that in the aluminium bronze BA1055 after makes additions Si, Cr, Mo and/or W the phases of the type κFe, κNi crystallize, probably as complex silicides. Elements such as: Fe and Si dissolve first of all in phases κ, in smaller stage in the matrix of the bronze; Mn, Ni and W they dissolve in matrix and phases κ. It dissolves Cr and Mo in the larger stage in phases κ than in the matrix. The sizes of the abrasive wear were compared in the state cast multicomponentnew casting Cu-Al-Fe-Ni bronzes with the additives Cr, Mo or W with the wear of the bronze CuAl10Fe5Ni5Si. The investigations of thewear were conducted on the standard device. It results from conducted investigations, that make additions to bronze BA1055 of the additives of Si, Cr, Mo, and/or W it influences the rise of the hardness (HB of the bronze in the cast state, in the result of the enlarged quantity separates of hard phases κ, and in the consequence the decrease of the abrasive wear. The addition of molybdenum made possible obtainment of the microhardness of the phase α and γ 2 on the comparable level. From the microstructure of the bronze CuAl10Fe5Ni5MoSi is characterizes the smallest abrasive wear among

  12. Determining Foundry Area of Bronze Vessel Using REE in Clay Mould Residues

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The composition of casting clay core might provide clue to the foundry area of the bronze vessels. REE analysis of the residual clay mould was conducted by inductively coupled plasma atomic emission spectrometer (ICP-AES). Results reveal that characteristic of REE of clay mould from different region is dissimilar. It is feasible to restrict the possible foundry area of the bronze vessels on the basis of analysis of REE of clay mould residues on the bronzes. Meanwhile, this paper attempts to determine the foundry area of the bronze vessels unearthed at Jiuliandun tombs of Chu State, dated back to Warring States Period, in Zaoyang City, Hubei Province, and at Zuozhong cemetery, Spring and Autumn Period, in Jingmen City, Hubei Province. REE of clay core provides information on the foundry area of bronze vessels.

  13. Metallurgical and Chemical Characterization of Bronze Remains Found at the Houhe Site in Shanxi Province, China

    Science.gov (United States)

    Mu, D.; Nan, P. H.; Wang, J. Y.; Song, G. D.; Luo, W. G.

    2015-07-01

    This study attempts to determine the metallurgical and chemical characteristics of Chinese bronze artifacts from the early Iron Age by taking the bronze artifacts from the Houhe site as an example. The bronze artifacts included vessels, buckles, mirrors, and bells. Elemental compositions of 10 Chinese bronze artifacts from the Houhe site were determined by an x-ray fluorescence system. Microstructures were observed by a polarizing microscope. Most of the artifacts were cast and lacked external evidence of secondary processing. The copper content of the vessels is higher than the other samples, and the copper content of buckles is the lowest. High tin content is a distinctive characteristic of the mirrors. Through comparisons, bells show a decline in the content of copper from the Western Zhou dynasty to the early Han dynasty, and the content of lead increased over time. Combined with historical studies, the findings show that there may have been industrial standards for bronze production during the Han dynasty.

  14. Preliminary result on the analysis of Late Bronze Age metals

    International Nuclear Information System (INIS)

    Complete text of publication follows. The main event of the complex cultural changes during the transition from Middle to Late Bronze Age was the appearance of Tumulus culture in the Danube-Tisza region. In this period people rose mounds (tumuli) above their graves made from stone and soil. According to our present knowledge we believe that the ethnically inhomogeneous Tumulus culture was made homogenous by commerce (especially bronze commerce). Depots were typical of the final period of Middle Bronze Age called Koszider-phase. During the tumulus period the practice of hiding depots came to its end, bronze objects were put into graves. Therefore, it would be important to analyze the relation between the Koszider and Tumulus metallurgy. The main question to be answered is the following: were the trade connections and exchange of goods discontinued during the time of cultural changes? Examination of archaeological finds is carried out usually by typological methods which provide information on the attire fashion and funeral rite of cultures. The inherent capability of analytical techniques makes it possible to draw conclusions on the provenance of metals, thus facilitating to establish the contemporary trade routes. The metal finds from the southern part of the Great Hungarian Plain has not been investigated yet, though it would be important from the point of view of Tumulus culture. The main question is whether there is any noticeable change between the metallurgical craftsmanship of the consecutive eras. Therefore, it is important to determine the composition of the used raw materials, their sources, as well as the applied manufacturing technologies. For the characterization of archaeological bronze finds both conventional X-ray fluorescence (XRF) method and micro proton induced X-ray fluorescence (micro-PIXE) techniques are applied. The first one serves for the determination of the bulk composition of samples while the second one for the characterization of

  15. Novel polar dielectrics with the tetragonal tungsten bronze structure

    OpenAIRE

    Andrei ROTARU

    2013-01-01

    There is great interest in the development of new polar dielectric ceramics and multiferroic materials with new and improved properties. A family of tetragonal tungsten bronze (TTB) relaxors of composition Ba₆M³⁺Nb₉O₃₀ (M³⁺ = Ga³⁺, Sc³⁺ and In³⁺, and also their solid solutions) were studied in an attempt to understand their dielectric properties to enable design of novel polar TTB materials. A combination of electrical measurements (dielectric and impedance spectroscopy) and powder diffr...

  16. Investigation of laser cleaning on bronze cultural relics

    Science.gov (United States)

    Ling, Xiulan; Wang, Gao; Zhang, Chen

    2016-05-01

    The effects of laser cleaning on the corrosion layers of bronze cultural relics were studied using a pulsed fiber laser. The laser cleaning threshold value of the corrosion layers was obtained. It was found that the corrosion layer was removed successfully by employing a laser fluence value of 0.32 J cm-2 and scanning for three times. To obtain experimental evidence, laser con-focal scanning microscopy, scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDS), laser induced breakdown spectroscopy (LIBS) and laser Raman spectroscopy were employed to investigate the cleaning efficiency of corrosion layers on specimens.

  17. Diffusion bonding of titanium alloy to tin-bronze

    Institute of Scientific and Technical Information of China (English)

    李卓然; 冯吉才; 刘会杰

    2002-01-01

    The vacuum diffusion bonding of titanium alloy to tin-bronze has been studied and the feasibility and appropriate processing parameters have been investigated. The maximum tensile strength of the joints is bonded joint has been observed by SEM, X-ray and EPMA, and the main factors affecting diffusion bonding have been analyzed. The intermetallic compounds Ti2Cu and TiCu were formed near the interface. The width and quantity of the intermetallic compound increases with the increase of the bonding time. The formation of the intermetallic compounds results in embrittlement of the joint and the poor joint properties.

  18. Prevention of Dealloying in Manganese Aluminium Bronze Propeller: Part II

    Directory of Open Access Journals (Sweden)

    Napachat Tareelap

    2014-03-01

    Full Text Available Due to the failure of manganese aluminium bronze (MAB propeller caused by dealloying corrosion as described in Part I [1], this work aims to study the prevention of dealloying corrosion using aluminium and zinc sacrificial anodes. The results indicated that both of the sacrificial anodes could prevent the propeller from dealloying. Moreover, the dealloying in seawater was less than that found in brackish water. It was possible that hydroxide ions, from cathodic reaction, reacted with calcium in seawater to form calcium carbonate film protecting the propeller from corrosion.

  19. Environmental roots of the late bronze age crisis.

    Science.gov (United States)

    Kaniewski, David; Van Campo, Elise; Guiot, Joël; Le Burel, Sabine; Otto, Thierry; Baeteman, Cecile

    2013-01-01

    The Late Bronze Age world of the Eastern Mediterranean, a rich linkage of Aegean, Egyptian, Syro-Palestinian, and Hittite civilizations, collapsed famously 3200 years ago and has remained one of the mysteries of the ancient world since the event's retrieval began in the late 19(th) century AD/CE. Iconic Egyptian bas-reliefs and graphic hieroglyphic and cuneiform texts portray the proximate cause of the collapse as the invasions of the "Peoples-of-the-Sea" at the Nile Delta, the Turkish coast, and down into the heartlands of Syria and Palestine where armies clashed, famine-ravaged cities abandoned, and countrysides depopulated. Here we report palaeoclimate data from Cyprus for the Late Bronze Age crisis, alongside a radiocarbon-based chronology integrating both archaeological and palaeoclimate proxies, which reveal the effects of abrupt climate change-driven famine and causal linkage with the Sea People invasions in Cyprus and Syria. The statistical analysis of proximate and ultimate features of the sequential collapse reveals the relationships of climate-driven famine, sea-borne-invasion, region-wide warfare, and politico-economic collapse, in whose wake new societies and new ideologies were created. PMID:23967146

  20. Environmental roots of the late bronze age crisis.

    Directory of Open Access Journals (Sweden)

    David Kaniewski

    Full Text Available The Late Bronze Age world of the Eastern Mediterranean, a rich linkage of Aegean, Egyptian, Syro-Palestinian, and Hittite civilizations, collapsed famously 3200 years ago and has remained one of the mysteries of the ancient world since the event's retrieval began in the late 19(th century AD/CE. Iconic Egyptian bas-reliefs and graphic hieroglyphic and cuneiform texts portray the proximate cause of the collapse as the invasions of the "Peoples-of-the-Sea" at the Nile Delta, the Turkish coast, and down into the heartlands of Syria and Palestine where armies clashed, famine-ravaged cities abandoned, and countrysides depopulated. Here we report palaeoclimate data from Cyprus for the Late Bronze Age crisis, alongside a radiocarbon-based chronology integrating both archaeological and palaeoclimate proxies, which reveal the effects of abrupt climate change-driven famine and causal linkage with the Sea People invasions in Cyprus and Syria. The statistical analysis of proximate and ultimate features of the sequential collapse reveals the relationships of climate-driven famine, sea-borne-invasion, region-wide warfare, and politico-economic collapse, in whose wake new societies and new ideologies were created.

  1. Corrosion characteristics of copper and leaded bronze in palm biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Haseeb, A.S.M.A.; Masjuki, H.H.; Ann, L.J.; Fazal, M.A. [Department of Mechanical Engineering, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2010-03-15

    Biodiesel has become more attractive as alternative fuel for automobiles because of its environmental benefits and the fact that it is made from renewable sources. However, corrosion of metals in biodiesel is one of the concerns related to biodiesel compatibility issues. This study aims to characterize the corrosion behavior of commercial pure copper and leaded bronze commonly encountered in the automotive fuel system in diesel engine. Static immersion tests in B0, B50 and B100 fuels were carried out at room temperature for 2640 h. Similar immersion tests in B0, B100 and B100 (oxidized) fuels were also conducted at 60 C for 840 h. At the end of the test, corrosion behavior was investigated by weight loss measurements and changes in surface morphology. Fuels were analyzed by using TAN analyzer, FTIR, MOA (multi-element oil analyzer) to investigate acid concentration, oxidation level with water content and corrosive impurities respectively. Results showed that under the experimental conditions, pure copper was more susceptible to corrosion in biodiesel as compared to leaded bronze. (author)

  2. Palaeoethnobotanical Data from the High Mountainous Early Bronze Age Settlement of Tsaghkasar-1 (Mt. Aragats, Armenia

    Directory of Open Access Journals (Sweden)

    Roman Hovsepyan

    2011-09-01

    Full Text Available Palaeoethnobotanical investigations suggest that at least part of the Early Bronze Age population of Tsaghkasar was settled and practiced agriculture in the high mountainous zone. People there appear to have cultivated hexa‐ and tetraploid wheats (probably bread wheat and emmer and barley (possibly hulled. Bronze Age agriculture in the Southern Caucasus differs from earlier and later period when cultivation of pulses, oil‐producing plants, and other plants was common. This emphasis on the cultivation and use of certain cereal grains at Early Bronze sites such as Tsaghkasar can tentatively be added to a constellation of practices associated with the Kura‐Araxes culture in the South Caucasus.

  3. History of a Bronze Age tell and its environment

    Science.gov (United States)

    Kovács, Gabriella; Füleky, György; Vicze, Magdolna

    2016-04-01

    Százhalombatta-Földvár is the most excessively researched Bronze Age tell site in Hungary. Parallel to the investigation of the settlement structure and activity patterns the changes of the landscape and the effect of human alteration is also studied. Significant changes of the landscape can be detected from the Bronze Age until the recent natural and cultural heritage protection of the area. Archaeological, soil analytical and thin section soil micromorphological methods are used to reconstruct the past 4000 years of the tell and its immediate surroundings. Prior to the Bronze Age the area was covered by forest vegetation, so the initial settling could only be realised after deforestation (2000 BC). The result of the soil corings and the prepared soil thin sections are solid proves of this action. It also became evident that at some areas - so far it seems that at locales where house floors were laid for the very first time - even the topsoil was removed so intensively that only the B horizon of the relict forest soil can be found. This observation needs to be further tested outside the habitation area to define the horizontal extension of the forest clearance and the topsoil removal. The northern side of the settlement is bordered by a natural erosion gully. At 2000 BC it was just a natural depression, but by 1500 BC it was deepened to serve as a fortification ditch. Around 1200 BC the ditch started to be filled in and by 1000 BC it was refilled to such an extent that its surface was utilised again. At about 600 BC (Late Iron Age) a smaller inner rampart was erected on the southern side of the ditch for inner separation. Not much is known about the Roman period of this area (200 AD) but the remnants of a watchtower indicate their presence. During the 18th century AD the area was used for grape cultivation and later for hobby gardens up until the protection of the area in the late 20th century. Since then species of the original vegetation started to grow back

  4. Cavitation erosion behavior of nickel-aluminum bronze weldment

    Institute of Scientific and Technical Information of China (English)

    李小亚; 闫永贵; 许振明; 李建国

    2003-01-01

    Cavitation erosion behavior of nickel-aluminum bronze(NAB)weldment in 3.5% NaCl aqueous solution was studied by magnetostrictive vibratory device for cavitation erosion.The results show that cavitation erosion resistance of the weld zone(WZ)of the weldment is superior to that of the base metal.SEM observation of eroded specimens reveals that the phases undergoing selective attack by the stress of cavitation erosion at the early stage of cavitation erosion are:martensite in the WZ,α phase in the heat-affected zone(HAZ)and eutectoidal phase in the base metal; the microcracks causing cavitation damage initiate at the phase boundaries.

  5. LAMQS analysis applied to ancient Egyptian bronze coins

    International Nuclear Information System (INIS)

    Some Egyptian bronze coins, dated VI-VII sec A.D. are analyzed through different physical techniques in order to compare their composition and morphology and to identify their origin and the type of manufacture. The investigations have been performed by using micro-invasive analysis, such as Laser Ablation and Mass Quadrupole Spectrometry (LAMQS), X-ray Fluorescence (XRF), Laser Induced Breakdown Spectroscopy (LIBS), Electronic (SEM) and Optical Microscopy, Surface Profile Analysis (SPA) and density measurements. Results indicate that the coins have a similar bulk composition but significant differences have been evidenced due to different constituents of the patina, bulk alloy composition, isotopic ratios, density and surface morphology. The results are in agreement with the archaeological expectations, indicating that the coins have been produced in two different Egypt sites: Alexandria and Antinoupolis. A group of fake coins produced in Alexandria in the same historical period is also identified.

  6. LAMQS analysis applied to ancient Egyptian bronze coins

    Energy Technology Data Exchange (ETDEWEB)

    Torrisi, L., E-mail: lorenzo.torrisi@unime.i [Dipartimento di Fisica dell' Universita di Messina, Salita Sperone, 31, 98166 Messina (Italy); Caridi, F.; Giuffrida, L.; Torrisi, A. [Dipartimento di Fisica dell' Universita di Messina, Salita Sperone, 31, 98166 Messina (Italy); Mondio, G.; Serafino, T. [Dipartimento di Fisica della Materia ed Ingegneria Elettronica dell' Universita di Messina, Salita Sperone, 31, 98166 Messina (Italy); Caltabiano, M.; Castrizio, E.D. [Dipartimento di Lettere e Filosofia dell' Universita di Messina, Polo Universitario dell' Annunziata, 98168 Messina (Italy); Paniz, E.; Salici, A. [Carabinieri, Reparto Investigazioni Scientifiche, S.S. 114, Km. 6, 400 Tremestieri, Messina (Italy)

    2010-05-15

    Some Egyptian bronze coins, dated VI-VII sec A.D. are analyzed through different physical techniques in order to compare their composition and morphology and to identify their origin and the type of manufacture. The investigations have been performed by using micro-invasive analysis, such as Laser Ablation and Mass Quadrupole Spectrometry (LAMQS), X-ray Fluorescence (XRF), Laser Induced Breakdown Spectroscopy (LIBS), Electronic (SEM) and Optical Microscopy, Surface Profile Analysis (SPA) and density measurements. Results indicate that the coins have a similar bulk composition but significant differences have been evidenced due to different constituents of the patina, bulk alloy composition, isotopic ratios, density and surface morphology. The results are in agreement with the archaeological expectations, indicating that the coins have been produced in two different Egypt sites: Alexandria and Antinoupolis. A group of fake coins produced in Alexandria in the same historical period is also identified.

  7. Elements inter-diffusion in the turning of wear-resistance aluminum bronze

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Inter-diffusion of elements between the tool and the workpiece during the turning of aluminum bronze using high-speed steel and cemented carbide tools have been studied. The tool wear samples were prepared by using M2 high-speed steel and YW1 cemented carbide tools to turn a novel high strength, wear-resistance aluminum bronze without coolant and lubricant. Adhesion of workpiece materials was found on all tools' surface. The diffusion couples made of tool materials and aluminum bronze were prepared to simulate the inter-diffusion during the machining. The results obtained from tool wear samples were compared with those obtained from diffusion couples. Strong inter-diffusion between the tool materials and the aluminum bronze was observed in all samples. It is concluded that diffusion plays a significant role in the tool wear mechanism.

  8. University receives 2009 Governor's Environmental Excellence Bronze Medal for Campus Tree Tour 2008 Event

    OpenAIRE

    West, Hilary

    2009-01-01

    Virginia Tech received the 2009 Governor's Environmental Excellence Bronze Medal in the Environmental Project (Government) category for hosting the Campus Tree Tour 2008 tree planting event in Blacksburg on Oct. 21, 2008.

  9. The Bronze "Ding of Flourishing Olympic "for the Main Stadium of the 2008 Olympic Games

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ The bronze "Ding of Flourishing Olympic" for the main stadium of the 2008Olympic Games has been completed by Yuda Group Company. The "Ding of Flourishing Olympic" was designed by Lanzhou Ludu Chunqiu Cultural Disseminating Co. Ltd.

  10. Influence Cr on Crystallization and the Phase Transformations of the Bronze BA1044

    Directory of Open Access Journals (Sweden)

    B. P. Pisarek

    2007-07-01

    Full Text Available The investigations were introduced in the paper, method of thermal and derivative analysis (TDA, the process of crystallization and phase transformation in the solid state of the aluminium bronze CuA110Fe4Ni4 (BA1044 and with the addition 0.3% Cr. Two intermetallic phase were identified in the microstructure of the bronze BA1044: κFel - rich in Fe and Cu and κFe2 - rich in Fe, and in the microstructure of the bronze BA1044+0.3 % Cr only one phase κFel - rich in Fe, Cu and Cr. The presence of chrome in the bronze BA1044 reduce size the primary crystals of the phase β, reduces the dynamics of the processes of thermal phase transformation in the solid state and lengthens the time their of duration.

  11. Facile Preparation of Molybdenum Bronzes as an Efficient Hole Extraction Layer in Organic Photovoltaics.

    Science.gov (United States)

    Wang, Jiantai; Zhang, Jun; Meng, Bin; Zhang, Baohua; Xie, Zhiyuan; Wang, Lixiang

    2015-06-24

    We proposed a facile and green one-pot strategy to synthesize Mo bronzes nanoparticles to serve as an efficient hole extraction layer in polymer solar cells. Mo bronzes were obtained through reducing the fractional self-aggregated ammonium heptamolybdate with appropriate reducing agent ascorbic acid, and its optoelectronic properties were fully characterized. The synthesized Mo bronzes displayed strong n-type semiconductor characteristics with a work function of 5.2-5.4 eV, matched well with the energy levels of current donor polymers. The presented gap states of the Mo bronzes near the Fermi level were beneficial for facilitating charge extraction. The as-synthesized Mo bronzes were used as hole extraction layer in polymer solar cells and significantly enhanced the photovoltaic performance and stability. The power conversion efficiency was increased by more than 18% compared with the polyethylene dioxythiophene:polystyrenesulfonate-based reference cell. The excellent performance and facile preparation render the as-synthesized solution-processed Mo bronzes nanoparticles a promising candidate for hole extraction layer in low-cost and efficient polymer solar cells.

  12. Investigating Early/Middle Bronze Age copper and bronze axes by micro X-ray fluorescence spectrometry and neutron imaging techniques

    Science.gov (United States)

    Figueiredo, Elin; Pereira, Marco A. Stanojev; Lopes, Filipa; Marques, José G.; Santos, Joana P.; Araújo, M. Fátima; Silva, Rui J. C.; Senna-Martinez, João C.

    2016-08-01

    Micro X-ray fluorescence (micro-XRF) analysis and neutron imaging techniques, namely 2D radiography and 3D tomography, have been applied for the study of four metal axes from the Early/Middle Bronze Age in Western Iberia, a period characterized by a metallurgical change in the use of copper to bronze. Micro-XRF analysis has shown that one of the axes was produced in copper with some arsenic while the other three were produced in a copper-tin alloy (bronze) with variable tin contents and some arsenic and lead. Neutron radiography and tomography were applied to study internal heterogeneities of the axes in a non-invasive way since the specificities of neutron interaction with matter allow a suitable penetration of these relatively thick copper-based objects when compared to the use of a conventional X-ray radiography. Neutron imaging allowed the visualization of internal fissures and pores and the evaluation of their distribution, size and shape. Relevant information for the reconstruction of ancient manufacturing techniques was gathered, revealing that one ax was produced with the mold in an angle of ≈ 25°, probably to facilitate gas escape during metal pouring. Also, information regarding physical weaknesses of the axes was collected, providing relevant data for their conservation. The combination of these non-destructive techniques allowed the evaluation of the metal composition and the internal structure of the axes. Micro-XRF allowed the distinction among copper and bronze axes, and provided data about the composition of early bronzes for which data is scarce. The neutron imaging study allowed for the first time the visualization of internal heterogeneities in early bronze axes, namely pores and large voids, providing relevant information for the reconstruction of ancient manufacturing techniques and raising pertinent information regarding physical weaknesses of these types of objects.

  13. Flux pinning in bronze-processed Nb3Sn wires

    International Nuclear Information System (INIS)

    The scaling law derived by Kramer for magnetic flux pinning in high magnetic fields was examined for its applicability to the magnetic field dependence of critical-current densities in the bronze processed monofilamentary Nb3Sn wires. From this it was concluded that: (1) its prediction for the form of the dependence of critical current on magnetic field and grain size [/J vector /sub c/ x H vector/ approx. h/sup 1/2/(1-h)2(1-a0√rho)-2] was found to be very good in most cases including wires with very small Nb3Sn grains (approx. 400 A). It was found very useful in comparison of J/sub c/ for different wires and in extrapolating to obtain H/sub c2/ for these wires. (2) However, it could not account consistently for the anisotropy in critical current of a tape which was measured with H applied perpendicular and parallel to the tape face. (3) The values of kappa1 which were determined with the scaling law were too small by a factor of 2 to 3, and the trend in the variation with heat-treating time was opposite to that which is reasonably to be expected. That the behavior of kappa1 is thus seriously in contradiction with the expected behavior for Nb3Sn suggests basic faults in the derivation of the scaling equation for critical currents at high magnetic fields

  14. Understanding metal–insulator transition in sodium tungsten bronze

    Indian Academy of Sciences (India)

    Sanhita Paul; Satyabrata Raj

    2015-06-01

    We have carried out angle-resolved photoemission spectroscopy (ARPES) and spectromicroscopy studies to understand the metal–insulator transition (MIT) observed in sodium tungsten bronzes, NaWO3. The experimentally determined band structure is compared with the theoretical calculation based on full-potential linear augmented plane-wave method. It has been found that there is a good gross agreement between experiment and theory. ARPES spectra on the insulating sample show that the states near F are localized due to the random distribution of Na in WO3 lattice which causes strong disorder in the system. Our spectromicroscopy measurements on both insulating and metallic samples do not approve percolation model to explain MIT in NaWO3. Photoemission spectroscopy on metallic samples does not show any Na-induced impurity band (level), which was one of the models to explain MIT. Electron-like Fermi surface(s) has been found from our experiment for metallic samples at the (X) point which shows good agreement with band calculation.

  15. Exploring the bronzing effect at the surface of ink layers

    Science.gov (United States)

    Hébert, Mathieu; Mallet, Maxime; Deboos, Alexis; Chavel, Pierre; Kuang, Deng-Feng; Hugonin, Jean-Paul; Besbes, Mondher; Cazier, Anthony

    2015-03-01

    We investigate the optical phenomenon responsible for the colored shine that sometimes appears at the surface of ink layers in the specular direction, often called bronzing or gloss differential. It seems to come from the wavelength-dependent refractive index of the ink, which induces a wavelength-dependent reflectance of the ink-air interface. Our experiments on cyan and magenta inkjet inks confirm this theory. Complex refractive indices can be obtained from measurements of the spectral reflectance and transmittance of a transparency film coated with the ink. We propose a correction of the classical Clapper-Yule model in order to include the colored gloss in the prediction of the spectral reflectance of an inked paper. We also explored effects of scattering by the micrometric or nanometric roughness of the ink surface. The micrometric roughness, easy to model with a geometrical optics model, can predict the spreading of the colored gloss over a large cone. Electromagnetic models accounting for the effect of the nanometric roughness of the surface also predict the attenuation of short wavelengths observed under collimated illumination.

  16. Corrosion of Bronzes by Extended Wetting with Single versus Mixed Acidic Pollutants

    Directory of Open Access Journals (Sweden)

    Liliana Gianni

    2014-04-01

    Full Text Available The corrosion of bronzes was examined in the context of single-acid versus mixed-acid (as in urban acid rain solutions. Two bi-component bronzes (copper with either 3% Sn or 7% Sn that closely represent those of historic artifacts were immersed for five weeks in conditions designed to replicate those experienced by statues and ornaments in cities where rainfall and humidity constantly produce an electrolyte layer on the surfaces of bronzes. Ions, acids, and particles of pollutants can dissolve in this layer, resulting in a variety of harsh corrosion processes. The kinetics of corrosion and the properties of the resulting patinas were monitored weekly by electrochemical impedance spectroscopy and open-circuit potential measurements. The sizes and appearances of the corrosion products were monitored and used to estimate the progress of the corrosion, whose crystalline structures were visualized using scanning electron microscopy with energy dispersive spectroscopy, identified by X-ray diffraction, and characterized by spectrocolorimetry. The electrochemical measurements demonstrated that greater damage (in terms of color change and corrosion product formation did not correspond to deficiencies in protection. The mixed-acid solution did not corrode the bronzes, as would be expected from the additive effects of the single acids. The postulated mechanisms of metal dissolution appear to be specific to a particular bronze alloy, with the tin component playing an important role.

  17. Dating simple flakes: Early Bronze Age flake production technology on the Middle Euphrates Steppe, Syria

    Directory of Open Access Journals (Sweden)

    Yoshihiro Nishiaki

    2014-03-01

    Full Text Available Aceramic flint scatters, comprising very crude cores or flakes and no formalised tools, are frequently found on the Middle Euphrates steppe of northern Syria. Previous studies suggest that many of them are residues of short-term activities by the nomads or shepherds of the Early Bronze Age. In order to verify this interpretation, a more precise chronological framework needs to be established for the Early Bronze Age lithic industry. This paper analyses stratified flake assemblages of the Early Bronze Age at Tell Ghanem al-Ali, a securely radiocarbon-dated settlement on the Middle Euphrates, and examines which occupation level yields assemblages most similar to those of the steppe. Results demonstrate that the lithic industry of this period underwent significant diachronic changes in terms of core reduction technology. Based on the chronological framework developed at Tell Ghanem al-Ali, the steppe assemblages in question can be assigned to different phases of the Early Bronze Age. This finding will help identify processes at the beginning of the extensive exploitation of the steppe, which is regarded as one of the most important socioeconomic changes that occurred among Early Bronze Age communities of the Middle Euphrates.

  18. 青铜乐器自名研究%A Study of the Names Inscribed on Bronze Musical Instruments

    Institute of Scientific and Technical Information of China (English)

    陈双新

    2001-01-01

    Based on his studies of the bronze musical instruments, the author analyses the inscriptions referring the self-named modifiers and tries to give them new explanations. The study is important to understand the function and values of the bronze musical instruments.

  19. Preliminary study on corrosion layers of unearthed bronzes relics of Xizhou dynasty, China

    International Nuclear Information System (INIS)

    Engineering barrier for HLW repository is composed of vitrified waste, canister and buffer/backfill material. Assessment of the applicability of metal as candidate materials of canister for HLW has been conducted in some countries.. Many bronze relics in Xizhou Dynasty, China, dated from more than 3000 years ago, have been preserved perfectly. The study on the corrosion of the bronze relics would contribute to the material selection and design of canister for HLW. The corrosion products of ancient bronzes consist of copper carbonate hydrate, lead carbonate, copper oxides etc. The corrosion mechanism of the substrate were mainly characterized by electrochemical corrosion, whereas the corrosion mechanism of surface layers was characterized by direct chemical corrosion and electrochemical corrosion. (author)

  20. DEGRADATION WORKS OF MONUMENTAL ART CAST BRONZE UNDER THE INFLUENCE OF ENVIRONMENTAL FACTORS

    Directory of Open Access Journals (Sweden)

    Delia NICA-BADEA

    2012-11-01

    Full Text Available Intensive pollution, combined with the lack of conservation of monuments exposed to these environments make the main cause of deterioration of cultural objects to atmospheric corrosion metal. This paper proposes a study of the main factors leading to degradation Bronze alloy, cast bronze monuments exposed to open atmosphere: corrosive environmental factors, stability and products of corrosion of bronze. In general, all corrosion products present on a metal surface are indicated as 'skate', can be composed of single-layer or multilayer products. The paper also includes a case study on the influence of environmental factors on degradation Matthias monument statue in Cluj-Napoca, Romania. Visual inspection of the monument informs us that have white spots, gray, reddish not consistent with the base color green patina, surfaces showing depigmentation, the rain washed areas, crystallization, deposition of air-borne particles.

  1. Tool wear mechanism in turning of novel wear-resisting aluminum bronze

    Institute of Scientific and Technical Information of China (English)

    倪东惠; 夏伟; 张大童; 郭国文; 邵明

    2003-01-01

    Tool wear and wear mechanism during the turning of a wear-resisting aluminum bronze have been stud-ied. Tool wear samples were prepared by using M2 high-speed steel and YW1 cemented carbide tools to turn a novelhigh strength, wear resisting aluminum bronze without coolant and lubricant. Adhesion of workpiece materials wasfound on tool's surface. Under the turning condition used in this study major wear mechanisms for turning aluminumbronze using M2 high-speed steel tool are diffusion wear, adhesive wear and plastic deformation and shear on thecrater. Partial melting of high-speed steel on the rake plays a role in the tool wear also. Major wear mechanisms forturning aluminum bronze using YW1 cemented carbide tool are diffusion wear, attrition wear and sliding wear. Tocontrol the machining temperature is essential to reduce tool wear.

  2. The huastec region: a second locus for the production of bronze alloys in ancient mesoamerica.

    Science.gov (United States)

    Hosler, D; Stresser-Pean, G

    1992-08-28

    Chemical analyses of 51 metal artifacts, one ingot, and two pieces of intermediate processed material from two Late Post Classic archeological sites in the Huastec area of Eastern Mesoamerica point to a second production locus for copper-arsenic-tin alloys, copper-arsenic-tin artifacts, and probably copper-tin and copper-arsenic bronze artifacts. Earlier evidence had indicated that these bronze alloys were produced exclusively in West Mexico. West Mexico was the region where metallurgy first developed in Mesoamerica, although major elements of that technology had been introduced from the metallurgies of Central and South America. The bronze working component of Huastec metallurgy was transmitted from the metalworking regions of West Mexico, most likely through market systems that distributed Aztec goods. PMID:17742754

  3. Bronze and Iron Age sites in Srem and the stratigraphy of Gomolava

    Directory of Open Access Journals (Sweden)

    Tasić Nikola

    2005-01-01

    Full Text Available Systematic excavation at Gomolava conducted almost interruptedly between 1953 and 1985 provided an almost full insight into the human occupation of the southern Pannonian Plain from the Early Neolithic to the successive arrival of Celts and Romans. This fact makes it possible for many of the excavated short-lived or horizontally-stratified settlements to be defined in relation to Gomolava's stratigraphic sequence. As a result, the paper attempts to establish a relative chronology for Bronze and Iron Age sites in the area between the Sava and Danube rivers. By way of illustration, it offers four maps suggesting synchronous developments. Thus Map 1 shows chronological parallelism between the Early Bronze Age layers and late Vučedol and Vinkovci sites (such as Pećine near Vrdnik, or Belegiš, Vojka and Batajnica belonging to the final Eneolithic and Early Bronze, while Map 2 shows synchronisms between Gomolava IVb-c and the Vinkovci layers at the sites of Gradina on the Bosut, Gradac at Belegiš, Petrovaradin Fortress, and Asfaltna Baza on the outskirts of Zemun. The end of the Bronze Age represented by Gomolava IVb1 to IVc is shown to be synchronous with the settlements, necropolises and hoard horizons of an Ha A1 and A2 date. Finally, Early Iron Age sites are easy to fit in with the Srem sites owing to systematic excavations at Gradina on the Bosut near Šid, Kalakača near Beška and numerous hoards of bronze artefacts marking a clear boundary between the Bronze and Early Iron Ages. At Gomolava this transition is reflected in horizons Va to Vd: the earliest is represented by black channeled pottery of the Gava type, while the other three are connected with the evolution of the Bosut-Basarabi complex.

  4. Dynamic characteristics of Great Bronze Buddha of Kamakura using microtremor

    International Nuclear Information System (INIS)

    The second largest bronze Buddha in Japan built in around 1250AD at Kamakura immediately above the focal region of the 1923 Kanto earthquake. Great Buddha of Kamakura has still remained basically its original shape, though it has been suffered several natural disasters as losing its hall. Especially, although the 1703 and 1923 Kanto earthquakes caused settlement and sliding of the basement over 0.3 m., the body has been not suffered serious damage. This statue was casted in order from the bottom with many joints. The joint between the head and the body was noticed because it is reinforced by FRP, Fiber Reinforced Plastic, at the time of the last major repair in 1961. And ingenuity was exercised to fence off the earthquake motion over 400 Gal with sliding the body on the basement, to reduce the load for the neck during earthquake. This is the first example of the earthquake isolation system for cultural properties in Japan. Over 50 years passed after the during earthquake motion, microtremor measurement was conducted. As a result of the primary investigation in 2009, the surrounding ground was estimated that liquefaction was occurred at the front and right sides of the basement and the basement suffered damage as settlement. However, it is considered that the propagation of the earthquake motion for the statue was interrupted because of the liquefaction. Thus, it seems that the damage for the statue itself was prevented because of namely the natural isolation system. Additional y in 2013 microtremor of the statue itself was measured for making clear the connection status between the body and the head.

  5. Spinal arthritis and physical stress at Bronze Age Harappa.

    Science.gov (United States)

    Lovell, N C

    1994-02-01

    This study examines joint changes in the vertebral skeleton in human remains excavated in 1987 and 1988 at Bronze Age Harappa, an urban center of the Indus Valley civilization. The sample consists of 23 complete skeletons from primary burial context, the partial remains of more than 69 other individuals, and hundreds of skeletal elements from secondary context, totalling 3,084 vertebral joint margins and articular surfaces. Marginal bone proliferation, pitting of articular surfaces, eburnation, and ankylosis were scored macroscopically for vertebral body margins and surfaces and posterior apophyseal facet joints. Marginal lipping is far more prevalent on the vertebral bodies than on the apophyseal facets and surface pitting is also more frequent on vertebral bodies although its expression is relatively low overall. Cervical vertebrae in this sample exhibit the same amount of marginal new bone and much more surface pitting of the vertebral bodies than do either thoracic or lumbar vertebrae; the cervical segment also exhibits the most severe expressions of both types of lesions. In addition, although the frequencies of cervical and lumbar posterior facet involvement are similar, the cervical facets exhibit much more severe lipping as well as the only cases of eburnation and ankylosis. Pitting of the posterior facets is most common in the lumbar segment, but the cervical examples are the only severe cases. It is proposed that the severe joint changes in the cervical spine result from trauma, perhaps accumulated microtrauma from activity stresses. There are no age or sex associated patterns in the frequency of arthritis although this result may be influenced by the small proportions of the total sample for which age and sex could be determined. PMID:8147433

  6. Elemental analysis of ancient Chinese bronze artifacts with external-beam PIXE

    International Nuclear Information System (INIS)

    External-beam PIXE has been applied for the determination of the elemental composition of ancient Chinese bronze artifacts. Characteristic x-ray spectra from the samples bombarded with protons of 3 MeV have been measured with a HPGe detector. At each sample three spots were irradiated per run. Results of measurements on three fragments of bronze drinking vessels and helmet of Chinese ancient Chou and Shang dynasties (17th-8th century B.C.) are presented. To check the analytical method, we have also made measurements on the elemental composition of some modern coins. The results are discussed. (author)

  7. Symbolic metal bit and saddlebag fastenings in a Middle Bronze Age donkey burial.

    Directory of Open Access Journals (Sweden)

    Guy Bar-Oz

    Full Text Available Here we report the unprecedented discovery of the skeleton of a ritually interred donkey with a metal horse bit in association with its teeth and saddlebag fastenings on its back. This discovery in the Middle Bronze Age III sacred precinct (1700/1650-1550 BCE at Tel Haror, Israel, presents a unique combination of evidence for the early employment of equid harnessing equipment, both for chariot bridling (horse bit and pack animals (saddlebags. The ritually deposited donkey with its unique accoutrements advances our understanding of the broad social and religious significance of equids in the Levantine Bronze Age, previously known mainly from textual and iconographical sources.

  8. O bronze final na região de Mértola

    OpenAIRE

    BARROS, Pedro de

    2012-01-01

    Mértola fica localizada num local com boa defensibilidade, no final do longo estuário do Rio Guadiana no Sudoeste Peninsular entre uma peneplanicíe e os vales encaixados, onde as linhas de água subsidiárias têm o seu percurso. A ocupação do Bronze Final de Mértola é revelada pela presença de cerâmica com ornatos brunidos, formas cerâmicas manuais, cerâmica frequentemente designada "tipo Carambolo" e um exemplar de foice em bronze do "tipo Rocanes". Apesar de serem poucos os elementos, estes r...

  9. Pressure Effects on Solid State Phase Transformation of Aluminium Bronze in Cooling Process

    Institute of Scientific and Technical Information of China (English)

    WANG Hai-Yan; CHEN Yan; LIU Yu-Wen; LI Fei; LIU Jian-Hua; PENG Gui-Rong; WANG Wen-Kui

    2009-01-01

    Effects of high pressure (6 GPa) on the solid state phase transformation kinetic parameters of aluminum bronze during the cooling process are investigated, based on the measurement and calculation of its solid state phase transformation temperature, duration and activation energy and the observation of its microstructures. The results show that high pressure treatment can reduce the solid phase transformation temperature and activation energy in the cooling process and can shorten the phase transformation duration, which is favorable when forming fine-grained aluminum bronze.

  10. Bronze Age moss fibre garments from Scotland – the jury’s out

    OpenAIRE

    Harris, Susanna; Gleba, Margarita

    2015-01-01

    In the light of recent discoveries of early to middle Bronze Age burials with mats and fibrous material in Scotland, for example at Langwell farm and Forteviot, it was deemed timely to re-evaluate earlier finds of this period, several of which were discovered and initially reported on nearly a century ago. As part of this research it was noted that three Bronze Age finds from the old literature were reported as clothing or shrouds made of hair moss (Polytrichum commune). Three of these are r...

  11. Vegetation reconstruction of Bronze Age by using microscopic structure of charcoals

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The microscopic structure of charcoals was determined in two sites of Bronze Age, Chifeng area by using the scanning electronic microscope. The results showed that these charcoals are all timbers of Mongolian oak (Quercus mongolica). It has powerful climatic indicative significance. Based on the assemblage of pollen composition, their eco-climatic index and character of community, the vegetation reconstruction of Bronze Age was obtained. The reconstruction showed that the zonal vegetation was Mongolian oak forest and Chinese pine forest in the loess hills in the Chifeng area, which suggested that the climatic condition was warmer and wetter at that time than present time.

  12. Symbolic Metal Bit and Saddlebag Fastenings in a Middle Bronze Age Donkey Burial

    Science.gov (United States)

    Bar-Oz, Guy; Nahshoni, Pirhiya; Motro, Hadas; Oren, Eliezer D.

    2013-01-01

    Here we report the unprecedented discovery of the skeleton of a ritually interred donkey with a metal horse bit in association with its teeth and saddlebag fastenings on its back. This discovery in the Middle Bronze Age III sacred precinct (1700/1650-1550 BCE) at Tel Haror, Israel, presents a unique combination of evidence for the early employment of equid harnessing equipment, both for chariot bridling (horse bit) and pack animals (saddlebags). The ritually deposited donkey with its unique accoutrements advances our understanding of the broad social and religious significance of equids in the Levantine Bronze Age, previously known mainly from textual and iconographical sources. PMID:23484046

  13. Nomadic pastoralism in the Early Bronze Age of the central Balkans evaluation of background knowledge

    Directory of Open Access Journals (Sweden)

    Porčić Marko

    2008-01-01

    Full Text Available The aim of the paper is to examine background knowledge about the orga­nizational properties of mobile pastoral groups in order to assess the likelihood of the existence of pastoral nomads in the Early Bronze Age in the central Balkans. The patterning found by A. L. Johnson (2002 is taken as a point of departure for the cross-cultural analysis conducted in this study. Johnson’s findings are in the main corroborated. Acquired knowledge about the workings of pastoral societies suggests that highly mobile pastoral groups should not be expected in the Early Bronze Age of the central Balkans.

  14. Formation and Oxidation of Hydrogen Molybdenum Bronze on platinum electrode in sulfuric acid solution

    Institute of Scientific and Technical Information of China (English)

    Jin LU; Jun Hua DU; Wei Shan Li; Jia Mo FU

    2004-01-01

    Hydrogen molybdenum bronze (HxMoO3) can be electrodeposited on platinum and oxidized in two steps to the hydrogen molybdenum bronze with less amount of hydrogen HyMoO3 (y

  15. Strangers in a strange land: Egyptians in southern Palestine during the Bronze Age

    Directory of Open Access Journals (Sweden)

    Rachael Sparks

    2002-10-01

    Full Text Available When the Institute of Archaeology was formally established in 1937, it became responsible for housing Sir Flinders Petrie’s collection of archaeological material from Palestine. This unique inheritance has great value as a research collection, as its curator demonstrates here in her discussion of interaction between Egypt and Palestine in the Bronze Age.

  16. La médaille de bronze du CNRS à un physicien clermontois

    CERN Multimedia

    2005-01-01

    Evey year, the National center for scientific research (CNRS), rewards around fifty of searchers at various stages of their career. The bronze medal rewards the first work of a searcher, making of him a specialist in his field; Philippe Crochet was awarded this medal

  17. Celestial Symbolism in Central European Later Prehistory - Case Studies from the Bronze Age Carpathian Basin

    Science.gov (United States)

    Pásztor, Emília

    It is commonly held that the sun played a particularly important cultural role in later prehistoric Europe. The rise of a general European sun cult has even been suggested for the Bronze Age. During this period, the increasing use of special symbols assumed to represent the sun is easily discernible on different types of archaeological finds.

  18. Antibacterial drugs as corrosion inhibitors for bronze surfaces in acidic solutions

    International Nuclear Information System (INIS)

    Graphical abstract: - Highlights: • All four investigated antibacterial drugs act as corrosion inhibitors for bronze surface. • In the presence of antibiotics, a 3RC electric circuit simulates the corrosion system. • The electrochemical results indicate as best inhibitors Doxy, followed by Strepto. • HOMO–LUMO energy gap increases in the order: Doxy > Strepto > Cipro > Amoxi. • The thin protective film on bronze is reinforced by the presence of the antibiotics. - Abstract: The present study is aiming to investigate the effect of four antibiotics (amoxicillin, ciprofloxacin, doxycycline and streptomycin,) belonging to different classes of antibacterial drugs on bronze corrosion in a solution simulating an acid rain (pH 4). Due to their ability to form protective films on the metal surface, the tested antibiotics act as corrosion inhibitors for bronze. The antibiotics were tested at various concentrations in order to determine the optimal concentration range for the best corrosion inhibiting effect. In evaluating the inhibition efficiency, polarization curves, electrochemical impedance spectroscopy, SEM and XPS measurements were used. Moreover, a correlation between the inhibition efficiency of some antibacterial drugs and certain molecular parameters was determined by quantum chemical computations. Parameters like energies EHOMO and ELUMO and HOMO–LUMO energy gap were used for correlation with the corrosion data

  19. Antibacterial drugs as corrosion inhibitors for bronze surfaces in acidic solutions

    Energy Technology Data Exchange (ETDEWEB)

    Rotaru, Ileana [Department of Chemical Engineering, “Babes-Bolyai” University, 11 Arany-Janos St., 400028 Cluj-Napoca (Romania); Varvara, Simona, E-mail: svarvara@uab.ro [Department of Exact Sciences and Engineering, “1 Decembrie 1918” University, 11-13 Nicolae Iorga St., 510009 Alba Iulia (Romania); Gaina, Luiza [Department of Chemical Engineering, “Babes-Bolyai” University, 11 Arany-Janos St., 400028 Cluj-Napoca (Romania); Muresan, Liana Maria, E-mail: limur@chem.ubbcluj.ro [Department of Chemical Engineering, “Babes-Bolyai” University, 11 Arany-Janos St., 400028 Cluj-Napoca (Romania)

    2014-12-01

    Graphical abstract: - Highlights: • All four investigated antibacterial drugs act as corrosion inhibitors for bronze surface. • In the presence of antibiotics, a 3RC electric circuit simulates the corrosion system. • The electrochemical results indicate as best inhibitors Doxy, followed by Strepto. • HOMO–LUMO energy gap increases in the order: Doxy > Strepto > Cipro > Amoxi. • The thin protective film on bronze is reinforced by the presence of the antibiotics. - Abstract: The present study is aiming to investigate the effect of four antibiotics (amoxicillin, ciprofloxacin, doxycycline and streptomycin,) belonging to different classes of antibacterial drugs on bronze corrosion in a solution simulating an acid rain (pH 4). Due to their ability to form protective films on the metal surface, the tested antibiotics act as corrosion inhibitors for bronze. The antibiotics were tested at various concentrations in order to determine the optimal concentration range for the best corrosion inhibiting effect. In evaluating the inhibition efficiency, polarization curves, electrochemical impedance spectroscopy, SEM and XPS measurements were used. Moreover, a correlation between the inhibition efficiency of some antibacterial drugs and certain molecular parameters was determined by quantum chemical computations. Parameters like energies E{sub HOMO} and E{sub LUMO} and HOMO–LUMO energy gap were used for correlation with the corrosion data.

  20. Protection of bronze artefacts through polymeric coatings based on nanocarriers filled with corrosion inhibitors

    Science.gov (United States)

    de Luna, Martina Salzano; Buonocore, Giovanna; Di Carlo, Gabriella; Giuliani, Chiara; Ingo, Gabriel M.; Lavorgna, Marino

    2016-05-01

    Protective coatings based on polymers synthesized from renewable sources (chitosan or an amorphous vinyl alcohol based polymer) have been prepared for the protection of bronze artifacts from corrosion. Besides acting as an effective barrier against corrosive species present in the environment, the efficiency of the coatings has been improved by adding corrosion inhibitor compounds (benzotriazole or mercaptobenzothiazole) to the formulations. The liquid medium of the formulations has been carefully selected looking at maximizing the wettability on the bronze substrate and optimizing the solvent evaporation rate. The minimum amount of inhibitor compounds has been optimized by performing accelerated corrosion tests on coated bronze substrates. The inhibitors have been directly dissolved in the coating-forming solutions and/or introduced by means of nanocarriers, which allow to control the release kinetics. The free dissolved inhibitor molecules immediately provide a sufficient protection against corrosion. On the other hand, the inhibitor molecules contained in the nanocarriers serve as long-term reservoir, which can be activated by external corrosion-related stimuli in case of particularly severe conditions. Particular attention has been paid to other features which affect the coating performances. Specifically, the adhesion of the protective polymer layer to the bronze substrate has been assessed, as well as its permeability properties and transparency, the latter being a fundamental feature of protective coating for cultural heritages. Finally, the protective efficiency of the produced smart coatings has been assessed through accelerated corrosion tests.

  1. The Agro Pontino region, refuge after the Early Bronze Age Avellino eruption of Mount Vesuvius, Italy?

    NARCIS (Netherlands)

    C. Bakels; J. Sevink; W. Kuijper; H. Kamermans

    2015-01-01

    In recent years it was discovered that the Middle to Late Holocene infi ll of the Agro Pontino graben (Central Italy) held a tephra layer originating from the Avellino eruption of the Vesuvius volcano. The eruption is dated to 1995 ± 10 calBC and took therefore place during the Early Bronze Age. Thi

  2. Corrosion investigation of fire-gilded bronze involving high surface resolution spectroscopic imaging

    Science.gov (United States)

    Masi, G.; Chiavari, C.; Avila, J.; Esvan, J.; Raffo, S.; Bignozzi, M. C.; Asensio, M. C.; Robbiola, L.; Martini, C.

    2016-03-01

    Gilded bronzes are often affected by severe corrosion, due to defects in the Au layer and Au/Cu alloy galvanic coupling, stimulated by large cathodic area of the gilded layer. Galvanic corrosion, triggered by gilding defects, leads to products growth at the Au/bronze interface, inducing blistering or break-up of the Au layer. In this context, fire-gilded bronze replicas prepared by ancient methods (use of spreadable Au-Hg paste) was specifically characterised by compiling complementary spectroscopic and imaging information before/after accelerated ageing with synthetic rain. Fire-gilded bronze samples were chemically imaged in cross-section at nano-metric scale (XPS). We have found a net surface enrichment in Zn and Sn after fire-gilding and presence of metallic Hg, Pb and Cu within the Au layer. Moreover, the composition distribution of the elements together with their oxidation has been determined. It was also revealed that metallic phases including Hg and Pb remain in the gilding after corrosion. Moreover, selective dissolution of Zn and Cu occurs in the crater due to galvanic coupling, which locally induces relative Sn species enrichment (decuprification). The feasibility advantages and disadvantages of chemical imaging using HR-SRPES to study artworks have been investigated on representative replicas.

  3. The study of bronze statuettes with the help of neutron-imaging techniques

    NARCIS (Netherlands)

    Van Langh, R.; Lehmann, E.; Hartmann, S.; Kaestner, A.; Scholten, F.

    2009-01-01

    Until recently fabrication techniques of Renaissance bronzes have been studied only with the naked eye, microscopically, videoscopically and with X-radiography. These techniques provide information on production techniques, yet much important detail remains unclear. As part of an interdisciplinary s

  4. Electrodeposition and corrosion resistance of nanocrystalline white bronze (CuSn) coatings

    NARCIS (Netherlands)

    Hovestad, A.; Lekka, M.; Willemsen, R.M.R.; Tacken, R.A.; Bonora, P.L.

    2008-01-01

    For jewellery applications electroplated white bronze (CuSn) was investigated as undercoating for noble metal finishes as alternative to nickel. A strongly acidic plating bath was developed with an organic additive to suppress hydrogen evolution and obtain bright coatings. An electrochemical study o

  5. Isotopic dietary reconstruction of humans from Middle Bronze Age Lerna, Argolid, Greece

    NARCIS (Netherlands)

    Triantaphyllou, S.; Richards, M. P.; Zerner, C.; Voutsaki, S.

    2008-01-01

    This study presents the results of a carbon and nitrogen stable isotope analysis of 39 human bone and 8 animal samples from Middle Bronze Age (or Middle Helladic, MH, ca. 2100-1700 BC) Lerna, Greece. The isotopic data indicate that the humans had a C-3 terrestrial diet while certain individuals appe

  6. Dating Archaeological Copper/Bronze Artifacts by Using the Voltammetry of Microparticles

    OpenAIRE

    Doménech-Carbó, Antonio; Doménech-Carbó, Maria Teresa; Capelo, Sofia; Pasíes, Trinidad; Martínez-Lázaro, Isabel

    2014-01-01

    A method for dating copper/bronze archaeological objects aged in atmospheric environments is proposed based on the specific signals for cuprite and tenorite corrosion products measured through the voltammtry of microparticles method. The tenorite/cuprite ratio increased with the corrosion time and fitted to a potential law that yielded a calibration curve usable for dating purposes.

  7. Cold Spraying of Cu-Al-Bronze for Cavitation Protection in Marine Environments

    Science.gov (United States)

    Krebs, S.; Gärtner, F.; Klassen, T.

    2015-01-01

    Traveling at high speeds, ships have to face the problem of rudder cavitation-erosion. At present, the problem is countered by fluid dynamically optimized rudders, synthetic, and weld-cladded coatings on steel basis. Nevertheless, docking and repair is required after certain intervals. Bulk Cu-Al-bronzes are in use at ships propellers to withstand corrosion and cavitation. Deposited as coatings with bulk-like properties, such bronzes could also enhance rudder life times. The present study investigates the coating formation by cold spraying CuAl10Fe5Ni5 bronze powders. By calculations of the impact conditions, the range of optimum spray parameters was preselected in terms of the coating quality parameter η on steel substrates with different temperatures. As-atomized and annealed powders were compared to optimize cavitation resistance of the coatings. Results provide insights about the interplay between the mechanical properties of powder and substrate for coating formation. Single particle impact morphologies visualize the deformation behavior. Coating performance was assessed by analyzing microstructures, bond strength, and cavitation resistance. These first results demonstrate that cold-sprayed bronze coatings have a high potential for ensuring a good performances in rudder protection. With further optimization, such coatings could evolve towards a competitive alternative to existing anti-cavitation procedures.

  8. Randomised controlled trials of staged teaching for basic life support. 1. Skill acquisition at bronze stage.

    Science.gov (United States)

    Assar, D; Chamberlain, D; Colquhoun, M; Donnelly, P; Handley, A J; Leaves, S; Kern, K B

    2000-06-01

    We have investigated a method of teaching community CPR in three stages instead of in a single session. These have been designated bronze, silver, and gold stages. The first involves only opening of the airway and chest compression with back blows for choking, the second adds ventilation in a ratio of compressions to breaths of 50:5, and the third is a conversion to conventional CPR. In a controlled randomised trial of 495 trainees we compared the performance in tests immediately after instruction of those who had received a conventional course and those who had had the simpler bronze level tuition. The tests were based on video recordings of simulated resuscitation scenarios and the readouts from recording manikins. Differences occurred as a direct consequence of ventilation being required in one group and not the other, some variation probably followed from unforeseen minor changes in the way that instruction was given, whilst others may have followed from the greater simplicity in the new method of training. A careful approach was followed by slightly more trainees in the conventional group whilst appreciably more in the bronze group remembered to shout for help (44% vs. 71%). A clear advantage was also seen for bronze level training in terms of those who opened the airway as taught (35% vs. 56%), for checking breathing (66% vs. 88%), and for mentioning the need to phone for an ambulance (21% vs. 32%). Little difference was observed in correct or acceptable hand position between the conventional group who were given detailed guidance and the bronze group who were instructed only to push on the centre of the chest. The biggest differences related to the number of compressions given. The mean delay to first compression was 63 s and 34 s, and the mean duration of pauses between compressions was 16 s and 9 s, respectively. Average performed rates were similar in the two groups, but more in the conventional group compressed too slowly whereas more in the bronze group

  9. Grain refinement of bronze alloy by equal-channel angular pressing (ECAP and its effect on corrosion behaviour

    Directory of Open Access Journals (Sweden)

    M.M. Sadawy

    2016-08-01

    Full Text Available The corrosion behaviour of bronze alloy prepared by equal channel angular pressing (ECAP was investigated in 3.5 wt. % NaCl solution. Immersion corrosion tests and different electrochemical techniques were carried out. The results showed that ECAPed bronze samples exhibited higher corrosion resistance compared with the as-cast alloy and the passive current density decreased with increasing number of passes. Moreover, the morphology of alloys indicated that the corrosion damage on the surface of ECAPed bronze was smooth and uniform while the as-cast alloy suffered from selective corrosion.

  10. Selection of the temperature of casting the bronzes to plaster moulds

    Directory of Open Access Journals (Sweden)

    B. Pisarek

    2009-07-01

    Full Text Available The results of the investigations of the process of solidification of the bronze CuSn5Zn5Pb5-C (B555 and CuSn10-C (B10 in the hot plaster mould show in the work. For four temperatures of casting: 1200 ° C, 1180 ° C, 1160 ° C and 1140 ° C was conducted the investi-gation: the size of contraction cavity, the fulfillment of the mould cavity formative the casts of test slats about the thickness: 4 mm, 0,8 mm and 0,5 mm. It was conducted the investigation the processes sets in the arrangement the cast-mould and X-ray analysis phase XRD of compound coming into being in indirect layer created among mould and cast in the result of the thermal decomposition of the anhy-drite. It results that the temperature 1140 ° C is the optimum temperature of casting the bronze to hot plaster mould from carried out investiga-tions. The minimum thickness of the wall of the cast from the bronze B555 is 0.5 mm, and from the bronze B10 0.8 mm.The realization of casts about thinner walls is made difficult because of giving off formed gases in the result of the thermal decomposition of the anhydrite. The products of the decomposition of the anhydrite react with elements steps in the chemical composition of studied bronzes, create in the arrangement the cast-mould the indirect layer folded from: sulphites, sulphides, oxides and clean metals (Pb or their compounds, especially Sn and Sb.

  11. Chemical bath deposition and characterization of electrochromic thin films of sodium vanadium bronzes

    Energy Technology Data Exchange (ETDEWEB)

    Najdoski, Metodija, E-mail: metonajd@yahoo.com [Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Sts. Cyril and Methodius University, POB 162, Arhimedova 5, 1000 Skopje, Republic of Macedonia (Macedonia, The Former Yugoslav Republic of); Koleva, Violeta [Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, 1113 Sofia (Bulgaria); Demiri, Sani [Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Sts. Cyril and Methodius University, POB 162, Arhimedova 5, 1000 Skopje, Republic of Macedonia (Macedonia, The Former Yugoslav Republic of)

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer We report a new chemical bath method for the deposition of vanadium bronze thin films. Black-Right-Pointing-Pointer The films are phase mixture of NaV{sub 6}O{sub 15} and Na{sub 1.1}V{sub 3}O{sub 7.9} with 10.58% lattice water. Black-Right-Pointing-Pointer The as-deposited vanadium bronze films exhibit two-step electrochromism. Black-Right-Pointing-Pointer They change their yellow-orange color to green and then from green to blue color. Black-Right-Pointing-Pointer The method allows the preparation of films on substrates with low melting point. -- Abstract: Thin yellow-orange films of sodium vanadium oxide bronzes have been prepared from a sodium-vanadium solution (1:1) at 75 Degree-Sign C and pH = 3. The composition, structure and morphology of the films have been studied by XRD, IR spectroscopy, TG and SEM-EDX analyses. It has been established that the prepared films are a phase mixture of hydrated NaV{sub 6}O{sub 15} (predominant component) and Na{sub 1.1}V{sub 3}O{sub 7.9} with total water content of 10.58%. The sodium vanadium bronze thin films exhibit two-step electrochromism followed by color change from yellow-orange to green, and then from green to blue. The cyclic voltammetry measurements on the as-deposited and annealed vanadium bronze films reveal the existence of different oxidation/reduction vanadium sites which make these films suitable for electrochromic devices. The annealing of the films at 400 Degree-Sign C changes the composition, optical and electrochemical properties.

  12. Chemical bath deposition and characterization of electrochromic thin films of sodium vanadium bronzes

    International Nuclear Information System (INIS)

    Highlights: ► We report a new chemical bath method for the deposition of vanadium bronze thin films. ► The films are phase mixture of NaV6O15 and Na1.1V3O7.9 with 10.58% lattice water. ► The as-deposited vanadium bronze films exhibit two-step electrochromism. ► They change their yellow-orange color to green and then from green to blue color. ► The method allows the preparation of films on substrates with low melting point. -- Abstract: Thin yellow-orange films of sodium vanadium oxide bronzes have been prepared from a sodium–vanadium solution (1:1) at 75 °C and pH = 3. The composition, structure and morphology of the films have been studied by XRD, IR spectroscopy, TG and SEM–EDX analyses. It has been established that the prepared films are a phase mixture of hydrated NaV6O15 (predominant component) and Na1.1V3O7.9 with total water content of 10.58%. The sodium vanadium bronze thin films exhibit two-step electrochromism followed by color change from yellow-orange to green, and then from green to blue. The cyclic voltammetry measurements on the as-deposited and annealed vanadium bronze films reveal the existence of different oxidation/reduction vanadium sites which make these films suitable for electrochromic devices. The annealing of the films at 400 °C changes the composition, optical and electrochemical properties

  13. Preliminary Study of Corrosion Status on Bronzes Excavated from Qin Dynasty Tombs at Xinfeng Town in China

    Directory of Open Access Journals (Sweden)

    Qian-li Fu

    2012-01-01

    Full Text Available From 2007 to 2008, many bronze wares of Qin Dynasty were excavated from tombs at Xinfeng town. Being an important finding, these bronze wares attracted people’s attention, especially for their conservation. Therefore, the corrosive products were explored by using Scanning Electron Microscope with Energy Dispersive X-ray Detector (SEM/EDS, X-Ray diffraction (XRD, and Raman spectroscopy (RM, which provided much valuable information on the conservation of these bronze wares. According to tested results, the corrosive products of bronzes were found to be comprised of cuprite (Cu2O, covellite (CuS, lead carbonate (PbCO3, and malachite (CuCO3·Cu(OH2. Meantime, the multilayer corrosive structure was found in some samples due to the cracks in Cu2O layer which had formed many microchannels to promote the material migration.

  14. Grain refinement of bronze alloy by equal-channel angular pressing (ECAP) and its effect on corrosion behaviour

    OpenAIRE

    M.M. Sadawy; Ghanem, M

    2016-01-01

    The corrosion behaviour of bronze alloy prepared by equal channel angular pressing (ECAP) was investigated in 3.5 wt. % NaCl solution. Immersion corrosion tests and different electrochemical techniques were carried out. The results showed that ECAPed bronze samples exhibited higher corrosion resistance compared with the as-cast alloy and the passive current density decreased with increasing number of passes. Moreover, the morphology of alloys indicated that the corrosion damage on the surface...

  15. Characterisation of passive layers of bronze patinas (Cu-Sn alloys) in relation with the tin content of the alloy

    OpenAIRE

    Robbiola, Luc; Fiaud, C.; Harch, A.

    1993-01-01

    International audience In order to develop our knowledge of the relations between the high degree of protectiveness of passive layers and their composition, corroded archaeological bronzes of Bronze Age (1500-950 BC) have been characterised by different methods of analysis. Results reveal that the passive layers have a bilayer structure and are due to the selective dissolution of copper from the copper solid solution of the alloy to the electrolyte. For all of the objects, the ratio [(Sn/C...

  16. Wet and dry accelerated aging tests in a spray chamber to understand the effects of acid rain frequencies on bronze corrosion

    OpenAIRE

    Gianni, Liliana; Cavallini, Mauro; Natali, Stefano; Adriaens, Annemie

    2013-01-01

    We have conducted controlled laboratory experiments using a series of bronze alloys exposed to frequent, repeated wet and dry cycles, to simulate frequent acid rain exposure and study the resultant corrosion processes in bronze artifacts exposed to an outdoor urban environment. To simulate rainwater and condensation, a spray chamber for the corrosion tests was assembled, which delivered homogeneous vapor diffusion and drop deposition. Three bi-component bronzes, with 3%, 7% and 20% tin conten...

  17. Marks of heliacal rising of Sirius on the sundial of the Bronze Age

    CERN Document Server

    Vodolazhskaya, Larisa N; Nevsky, Mikhail Yu

    2015-01-01

    The article presents the results of interdisciplinary research made with the help of archaeological, physical and astronomical methods. The aim of the study were analysis and interpretation corolla marks of the vessel of the Late Bronze Age, belonging to Srubna culture and which was found near the Staropetrovsky village in the northeast of the Donetsk region (Central Donbass). Performed calculations and measurements revealed that the marks on the corolla of Staropetrovsky vessel are marking of horizontal sundial with a sloping gnomon. Several marks on the corolla of the vessel have star shape. Astronomical calculations show that their position on the corolla, as on "dial" of watch, indicates the time of qualitative change the visibility of Sirius in the day its heliacal rising and the next few days in the Late Bronze Age at the latitude of detection of Staropetrovsky vessel. Published in the article the results of astronomical calculations allow to state that astronomical year in the Srubna tradition began wi...

  18. Chronology for the Aegean Late Bronze Age 1700-1400 B.C.

    Science.gov (United States)

    Manning, Sturt W; Ramsey, Christopher Bronk; Kutschera, Walter; Higham, Thomas; Kromer, Bernd; Steier, Peter; Wild, Eva M

    2006-04-28

    Radiocarbon (carbon-14) data from the Aegean Bronze Age 1700-1400 B.C. show that the Santorini (Thera) eruption must have occurred in the late 17th century B.C. By using carbon-14 dates from the surrounding region, cultural phases, and Bayesian statistical analysis, we established a chronology for the initial Aegean Late Bronze Age cultural phases (Late Minoan IA, IB, and II). This chronology contrasts with conventional archaeological dates and cultural synthesis: stretching out the Late Minoan IA, IB, and II phases by approximately 100 years and requiring reassessment of standard interpretations of associations between the Egyptian and Near Eastern historical dates and phases and those in the Aegean and Cyprus in the mid-second millennium B.C. PMID:16645092

  19. DIFFUSION COUPLE BETWEEN HIGH STRENGTH WEAR-RESISTING ALUMINUM BRONZE AND MACHINING TOOLS MATERIALS

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    Diffusion couples of tool materials (prepared from commercially available high speed steel and YW1 carbide tools) and the wear-resisting aluminum bronze (KK) were prepared by casting to study the diffusion pattern and phase formation sequence in order to clarify the diffusion wear of the tools during the turning of the wear-resisting aluminum bronze. Optical micrographs show that good contact was obtained at the tool material-KK interface. After annealed at 900 ℃ for 6 h, strong inter-diffusion across the interface was observed. Microprobe analysis was used to study the elemental distribution across the interface and X-ray diffractometry was used to study the phases formed at the interface.

  20. Biological affinities and adaptations of Bronze Age Bactrians: III. An initial craniometric assessment.

    Science.gov (United States)

    Hemphill, B E

    1998-07-01

    Discovery of a previously unknown Bronze Age civilization (Oxus Civilization) centered on the oases of Central Asia immediately raised questions concerning the origin and interregional impacts of this civilization. Fifteen craniometric variables from 12 Bronze Age samples--encompassing 544 adults from Central Asia, Iran, the Indus Valley, and Anatolia--are compared to test which, if any, of the current hypotheses offered by archaeologists are best supported by the pattern of phenetic affinities possessed by the Oxus Civilization inhabitants of the north Bactrian oasis. Craniometric differences between samples are compared with Mahalanobis generalized distance, and patterns of phenetic affinity are assessed with two types of cluster analysis (WPGMA, neighbor-joining method), multidimensional scaling, and principal coordinates analysis. Results obtained by this analysis indicate that current hypotheses for both the origin and interregional impacts of Oxus Civilization populations are incomplete. PMID:9696149

  1. Studies on bronze pre-monetary signs found in Dobroudja using XRF and micro-PIXE

    Science.gov (United States)

    Constantinescu, B.; Cristea-Stan, D.; Talmatchi, G.; Ceccato, D.

    2016-03-01

    We performed compositional analyses on 180 Scythian-type arrowheads and pre-monetary signs using XRF method and on 60 small fragments of such items (approx. 100 microns diameter), sampling being performed on previously corrosion-cleaned areas on their surface, using micro-PIXE. The items are found in Dobroudja, Istros-Histria region. The most relevant for numismatists result is that for each finding place the same type of alloy was used both for fighting arrowheads and for pre-monetary signs. Our analyses revealed three types of alloys: Cu-Sn-Pb ("normal" bronze), Cu-Sn-Mn-Pb and Cu-Sn-Sb-Pb. The presence of antimony suggests the use of fahlore-type poly-metals deposits, most probably from Caucasus Mountains. The problem of ancient bronze containing manganese is more complicated; an explanation could be the use of manganese oxides as flux necessary to smelt oxidized ores.

  2. Radiocarbon dating of ancient bronze statues: Preliminary results from the Riace statues

    Energy Technology Data Exchange (ETDEWEB)

    Calcagnile, L., E-mail: lucio.calcagnile@unile.i [CEDAD, Department of Innovation Engineering, University of Salento, Via per Monteroni, 73100 Lecce (Italy); D' Elia, M.; Quarta, G. [CEDAD, Department of Innovation Engineering, University of Salento, Via per Monteroni, 73100 Lecce (Italy); Vidale, M. [Istituto Centrale per il Restauro, Piazza San Francesco di Paola, 9, 00184 Rome (Italy)

    2010-04-15

    The low amount of material needed for the measurements makes AMS radiocarbon a technique suitable for the dating of ancient bronze artefacts through the analysis of the organic residues contained into the casting cores. We present the results of the AMS radiocarbon dating analyses carried out on the organic remains extracted from the casting cores of the Riace bronzes, among the most famous and well preserved sculptures of the Greek-Classical period. Although different dating hypotheses have been suggested on the base of stylistic considerations, no conclusive answers are, so far, available. The sample selection and preparation protocols of the different kind of organic materials (charred wood, vegetal remains and animal hairs) are described as well as the interpretation of the results in the frame of the current dating hypotheses and available analytical information about the casting technology.

  3. Comparative modeling of Bronze Age land use in the Malatya Plain (Turkey)

    Science.gov (United States)

    Arıkan, Bülent; Restelli, Francesca Balossi; Masi, Alessia

    2016-03-01

    Computational modeling in archeology has proven to be a useful tool in quantifying changes in the paleoenvironment. This especially useful method combines data from diverse disciplines to answer questions focusing on the complex and non-linear aspects of human-environment interactions. The research presented here uses various proxy records to compare the changes in climate during the Bronze Age in the Malatya Plain in eastern Anatolia, which is situated at the northern extremity of northern Mesopotamia. Extensive agropastoral land use modeling was applied to three sites of different size and function in the Malatya Plain during the Early Bronze Age I period to simulate the varying scale and intensity of human impacts in relation to changes in the level of social organization, demography, and temporal length. The results suggest that even in land use types subjected to a light footprint, the scale and intensity of anthropogenic impacts change significantly in relation to the level of social organization.

  4. Connections: the relationships between Neolithic and Bronze Age Megalithic Astronomy in Britain

    CERN Document Server

    Higginbottom, Gail

    2015-01-01

    It has already been empirically verified that for many Bronze Age monuments erected in Scotland between 1400-900 BC, there was a concerted effort on behalf of the builders to align their monuments to astronomical bodies on the horizon. It has also been found that there are two common sets of complex landscape and astronomical patternings, combining specific horizon qualities, like distance and elevation, with the rising and setting points of particular astronomical phenomena. However, it has only been very recently demonstrated by us that that the visible astronomical-landscape variables found at Bronze Age sites on the inner isles and mainland of western Scotland were first established nearly two millennia earlier, with the erection of the mooted first standing-stone 'great circles' in Britain: Callanish and Stenness of Scotland (see G. Higginbottom and R. Clay, The Origins of Standing Stone Astronomy in Britain submitted to Journal of Archaeological Science & available on ArXiv). In the current paper we...

  5. Neolithic and Bronze Age migration to Ireland and establishment of the insular Atlantic genome.

    Science.gov (United States)

    Cassidy, Lara M; Martiniano, Rui; Murphy, Eileen M; Teasdale, Matthew D; Mallory, James; Hartwell, Barrie; Bradley, Daniel G

    2016-01-12

    The Neolithic and Bronze Age transitions were profound cultural shifts catalyzed in parts of Europe by migrations, first of early farmers from the Near East and then Bronze Age herders from the Pontic Steppe. However, a decades-long, unresolved controversy is whether population change or cultural adoption occurred at the Atlantic edge, within the British Isles. We address this issue by using the first whole genome data from prehistoric Irish individuals. A Neolithic woman (3343-3020 cal BC) from a megalithic burial (10.3× coverage) possessed a genome of predominantly Near Eastern origin. She had some hunter-gatherer ancestry but belonged to a population of large effective size, suggesting a substantial influx of early farmers to the island. Three Bronze Age individuals from Rathlin Island (2026-1534 cal BC), including one high coverage (10.5×) genome, showed substantial Steppe genetic heritage indicating that the European population upheavals of the third millennium manifested all of the way from southern Siberia to the western ocean. This turnover invites the possibility of accompanying introduction of Indo-European, perhaps early Celtic, language. Irish Bronze Age haplotypic similarity is strongest within modern Irish, Scottish, and Welsh populations, and several important genetic variants that today show maximal or very high frequencies in Ireland appear at this horizon. These include those coding for lactase persistence, blue eye color, Y chromosome R1b haplotypes, and the hemochromatosis C282Y allele; to our knowledge, the first detection of a known Mendelian disease variant in prehistory. These findings together suggest the establishment of central attributes of the Irish genome 4,000 y ago. PMID:26712024

  6. Computed Tomography and Computed Radiography of late Bronze Age Cremation Urns from Denmark

    DEFF Research Database (Denmark)

    Harvig, Lise Lock; Lynnerup, Niels; Amsgaard Ebsen, Jannie

    2012-01-01

    To improve methods used to study prehistoric cremation rituals, cremation urns from the Danish late Bronze Age were examined using Computed Tomography and Computed Radiography (Digital X-ray). During microexcavation, the digital images were used as registration tool. Our results suggest that oste...... intensity show markedly poorer preservation and recovery than white calcined fragments do. Thus post-excavation estimations of cremation intensity are systematically biased...

  7. The metallurgy in Romagna and surrounding area in the Bronze Age.

    Directory of Open Access Journals (Sweden)

    Marcello Ravaglia

    2009-10-01

    Full Text Available The outline of the metallurgical production in Romagna and western limit represented by the province of Bologna shows a solid activity during the entire Bronze Age. Despite the preliminary state of the research, through the collection of records and the distributive analysis, it is possible to evaluate some of the peculiarities of the region. In particular, the presence of hoards in EBA and FBA suggests the main focus for the analysis of exchange dynamics between Northern and Central Italy.

  8. Electrolytic surface hardening of steel,cast iron and aluminium-bronze

    Institute of Scientific and Technical Information of China (English)

    Suhas Keshav Paknikar

    2006-01-01

    Electrolytic hardening process was developed in USSR in the 1950s. The process was developed but was not commercially exploited. There is no evidence of work done on this process in India. The author has done this original work applied to different materials like steel,cast iron and aluminum-bronze. This paper gives details of microstructural transformations along with hardness value achieved. There is vital scope for this process to become viable for surface hardening and selective hardening of small components.

  9. On the Origin of Bronze Belt Plaques of Ancient Nomads in Northern China

    Institute of Scientific and Technical Information of China (English)

    WUEn; 丁小雷

    2003-01-01

    The bronze plaques decorated with animal, human or geometric designs were the ornaments on the leather belts of the nomadic people, such as Xiongnu (Hun) and Xianbei (Sienpi) in Northern China in the Qin and Han Dynasties. These plaques had unique regional and ethnical characteristics. There have been many different ideas on the origination of this kind of plaques. The author plans to give his own opinion hereby on this issue.

  10. Towards mineralogical and geochemical reference groups for some Bronze Age ceramics 
from Transylvania (Romania)

    OpenAIRE

    Volker Hoeck; Corina Ionescu; Lucretia Ghergari; Carmen Precup

    2009-01-01

    Based on their chemical composition ceramic shards from three Bronze Age sites in Transylvania, i.e., Copăceni, Derşida and Palatca respectively, were distinguished by major, trace, and RE elements. Within the Copăceni samples, two subgroups (A and B) showing different chemistry and mineralogy were additionally separated out. The link between chemistry and mineralogy showed clearly the important contribution of the temper to the overall chemistry of the ceramic shards. In turn, the chemistry ...

  11. 黑豆嘴类型青铜器中的西来因素%Western Elements in the Bronzes of Heidouzui Type

    Institute of Scientific and Technical Information of China (English)

    张文立; 林沄

    2004-01-01

    The cultural elements contained in the bronzes of Heidouzui type have often been studied in academic circles,but no unanimous views have been reached.The present paper discusses two forms of bronze ornaments of the Kayao culture in the Qinghai region and their date,as well as the relationship of some bronzes handed down from ancient times with those unearthed from Qinghai.On the basis of their comparative study the authors put forward that the Heidouzui-type bronzes contain cultural elements coming from the Qinghai region and even farther areas.These western elements might have been spread eastward and northward to still farther regions.

  12. Nordic and Celtic: religion in southern Scandinavia during the late bronze age and early iron age

    Directory of Open Access Journals (Sweden)

    Marianne Görman

    1990-01-01

    Full Text Available By means of modern archeological research it is today possible to gain much information even from non-written material, This paper covers the late bronze age and early iron age, ca. 1000 B.C. —O. It is based on material from Denmark, the Southwest of Sweden, and the Southeast of Norway. This region formed a cultural unity since the sea bound the area together. Our main sources of knowledge of Nordic religion during this time span are votive offerings and rock-carvings. During the bronze age and early iron age the Nordic peasant population had intensive contacts with the Southeastern and Centralparts of Europe. A great quantity of imported objects bear evidence of widespread connections. The inhabitants of the Nordic area not only brought home objects, but also ideas and religious conceptions. This is clearly reflected in the iconography. The cultures with which connections were upheld and from which ideas were introduced were those of Hallstatt and La Tène. They were both Celtic iron age cultures prospering in Central Europe at the same time as the late bronze age and early iron age in the Nordic area. This means that the new symbols in the Nordic area come from a Celtic environment. Consequently, Celtic religion such as it may be found in the pre-Roman period, can clarify the meaning of the conceptions, linked with these symbols.

  13. Effect of heat treatment on microstructure and properties of hot-extruded nickel-aluminum bronze

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The effect of heat treatment on the microstructure and properties of a hot-extruded nickel-aluminum bronze was investigated. Experimental materials were heat treated through different processes, including quenching, normalizing, aging and annealing, and their microstructure, corrosion resistance and mechanical properties were characterized. It is found that quenching causes all β phase transformed into β' phase, however, normalizing causes β phase transformed into β', α and κ phases. When the quenched sample is aged, fine κ phase is precipitated from the as-quenched microstructure of β' phase. Annealing causes the transformation of β' into a and κ phases. The results of mechanical property tests show that quenching, normalizing and aging improve the tensile strength and hardness of the experimental material, with a corresponding fall in elongation. Annealing raises the elongation but reduces the tensile strength and hardness. Furthermore, corrosion resistance of nickel-aluminum bronze ranks from worse to better in the following order: aged, quenched, normalized, hot-extruded and annealed. However, with the exposure time of corrosion test increasing, the difference of average corrosion rate between those nickel-aluminum bronzes tums small.

  14. Evaluation of the inhibitive effect of benzotriazole on archeological bronze in acidic medium

    Science.gov (United States)

    Hassairi, Hèla; Bousselmi, Latifa; Khosrof, Slim; Triki, Ezzeddine

    2013-12-01

    An archaeological bronze artefact was a Punic coin excavated from the north east of Tunisia in 2001. The composition of the copper alloy revealed a content of 3.5 % of tin and 1.4 % of lead with the presence of some sulphur heterogeneity. The surface presents some roughnesses and cracks and is covered by a corrosion layer of 20-40 μm thickness. The use of benzotriazole (BTA) as an inhibitor has become a standard element for the preservation of cuprous-based metals. In order to investigate the behaviour of BTA in an acidic medium, an Electrochemical Impedance Spectroscopy (EIS) investigation was performed to characterize the electrochemical behaviour of the interface of the archaeological bronze sample/acidic medium without and with BTA addition. Impedance diagrams obtained at different immersion times show that the presence of the inhibitor prevents the diffusional process observed in the absence of BTA. The inhibition of the pre-polarized bronze surface revealed that the mechanism of action of the benzotriazole molecule in an acidic medium is governed by the chemisorption process.

  15. Analysis of the Quintilii’s Villa Bronzes by Spectroscopy Techniques

    Directory of Open Access Journals (Sweden)

    Fabio Stranges

    2014-01-01

    Full Text Available The aim of this work is the characterization, with different diagnostic tests, of three fragments of bronze artefacts recovered from the Villa of the Quintilii (located in the south of Rome. In particular, the sample alloys were investigated by different chemical and morphological analysis. Firstly, an analysis of the alloy, implemented through the electronic spectroscopy, was taken to discriminate the bronze morphology and its elemental composition. Subsequently, a surface analysis was realized by molecular spectroscopy to identify the alteration patinas on surfaces (such as bronze disease. Two diagnostic techniques are used for the alloy analysis: scanning electron microscopy (SEM connected to the EDX spectroscopy (to study the morphology and alloy composition and Auger electron spectroscopy (AES (to identify the oxidation state of each element. Moreover, for the study of surface patinas, IR and Raman spectroscopies were implemented. All studies were performed on the “as received” samples, covered by a thin layer of excavated soil and on samples processed in an aqueous solution of sulphuric acid (10%, to remove patinas and alterations.

  16. A systematic approach to Bronze corrosion products and the methods of treatment , applied on three bronze anklets from Dhamar museum , Yemen

    Directory of Open Access Journals (Sweden)

    Hazem Mohamed

    2014-04-01

    Full Text Available Three bronze anklets were found during the archaeological excavation of Yemeni mission 2002 A.D, in Gabal al- lawd , Jawf area , Yemen , they dated back to Minaean period in Yemen [sixth century B.C – 24 B.C] , and now they are situated in Dhamar regional museum .They were suffered from the deterioration aspects , two of these anklets had a thick corrosion products of pale green / brown , the third anklet had a rust-colored Black and Brown with the presence of small parts and scattered pale green. The aim of this paper is to examine, in detail, the corrosion of the selected objects that was grown during the long-term burial and identify its products that will help us to understand the corrosive factors and the degradation mechanisms , as well as their constituting metals in order to carry out scientific treatment and conservation .For this purpose ,samples from the objects were examined by Metallographic Microscope (ME , Scanning Electron Microscope (SEM, the corrosion products were analyzed by X-ray diffraction (XRD and X-ray fluorescence( XRF was used to determine the objects metallic constituents . XRD data showed that the corrosion products constitute of cuprite , atacamite , and paratacamite , whereas XRF analysis declared that the anklets compose of bronze alloy . Microscopic examination reveals that the three anklets were suffered from the deterioration spots , which dispersed on the metal surface . Chemical cleaning was chosen for treating the objects , finally they were isolated to preserve them against further attack.

  17. The Relationship Between Ambiently Formed Oxides and the Tribological Behavior of Aluminum Bronze

    Science.gov (United States)

    Poggie, Robert Andre

    1992-01-01

    The relationship between ambiently formed oxides and the tribological behavior of aluminum bronze has been investigated. As the aluminum content of Al-bronze increases from zero to eight weight percent, the mechanical properties, oxidation kinetics, and tribological behavior of the alloy are significantly affected. This research has shown that the friction and wear behavior of Al-bronze depends primarily on the composition and mechanical stability of the ambiently formed surface oxide. Adhesive transfer of Al-bronze to the slider counterfaces increased with increasing aluminum content which corresponded to increased damage to the alloy surfaces and the formation of wear debris. The majority of surface damage (plastic deformation and galling) of the Cu-4 and 6 w/o Al alloys occurred during the initial portion (run-in) of wear testing. The Cu-1 w/o Al alloy wore via an oxidative wear mechanism throughout the course of wear testing. Galling, severe plastic deformation, the formation of metallic wear debris, and adhesive transfer were not observed for the Cu-1 AL w/o alloy. XPS and SEM analysis of the Cu-1 w/o Al alloy showed the worn surfaces to consist of a smooth and adherent Cu_2O layer. Long term ambient oxidation of the Cu-4 and 6 w/o Al alloys resulted in a layered oxide structure with Cu(OH)_2 at the surface followed by CuO, Cu_2O, Al_2O_3, and, lastly, the metallic substrate. The differences in elastic moduli, crystal structures, and composition between the copper alloy and the Al _2O_3 enriched surface oxide decreases the mechanical integrity of the surface oxide. The tensile and compressive stresses generated at the surface of the Al-bronze samples via frictional interaction with the opposing slider is sufficient to cause a large differential in strain across the oxide-metal interface and disruption of the brittle, Al_2O _3 enriched surface oxide. The exposed metal immediately repassivates itself by reforming a surface oxide or forming an adhesive bond with

  18. Lead isotopic study of Shang Dynasty bronzes (13-11 B.C.) and their ore sources

    International Nuclear Information System (INIS)

    The Shang Dynasty civilization in China is based on the development of the bronze techniques. A large amount of Shang Dynasty bronzes, excavated from Jiangxi, Hubei and Henan Provinces, have become a focus of world attention. However, the Shang Dynasty center was located at Zhenzhou and Anyang city areas, Henan Province, where no large copper ores have been found so far. Therefore, where did the huge ore material for casting the bronzes come from? It is an unsettled question paid attention by the archaeologists and scientists. 35 Shang Dynasty bronzes and 21 copper and lead ore materials aged in the Shang-Zhou Dynasty, the Spring-Autumn Period and the modern time, have been measured by the use of mass spectrometry. Based upon lead isotopic ratios, the ore material for casting the bronzes with the middle isotopic ratios of 207Pb/206Pb ranged in 0.8∼0.9 could come from the ancient copper mine of Tongling, Jiangxi Province and Tong Lushan , Hubei Province and that with the high isotopic ratios (>0.9) could be from the northern part of the Shang Empire, called 'Gongfang' in the historical records, e.g. today's Hebei and Liaoning Provinces. the others with the low isotopic ratios (238U/204Pb in the ore flux or in the magma

  19. Pioneering farmers cultivating new lands in the North – The expansion of agrarian societies during the Neolithic and Bronze Age in Scandinavia

    DEFF Research Database (Denmark)

    Sørensen, Lasse

    2012-01-01

    Pioneering farmers cultivating new lands in the North – The expansion of agrarian societies during the Neolithic and Bronze Age in Scandinavia......Pioneering farmers cultivating new lands in the North – The expansion of agrarian societies during the Neolithic and Bronze Age in Scandinavia...

  20. Microstructure and mechanical properties of Ti6Al4V/Cu-10Sn bronze diffusion-bonded joint

    Institute of Scientific and Technical Information of China (English)

    ZHAO He; CAO Jian; FENG Ji-cai

    2009-01-01

    The microstructures and mechanical properties of Ti6Al4V/Cu-10Sn bronze diffusion-bonded joint were studied via scanning electron microscopy(SEM) and energy dispersive spectrometry(EDS). Diffusion bonding of Ti6Al4V to Cu-10Sn bronze was investigated at different holding time. Four obvious interracial layers were observed in the joint. It is revealed that the bonding joint has high shear strength up to 102 MPa bonded at 830 ℃, bonding pressure 10 MPa and bonding time 15 min. Shear test results show that the fracture takes place between the reaction layer and the Cu-10Sn bronze substrate, and the shear strength is strongly related to the formation of Cu-Ti-Sn intermetallic compounds.

  1. Corrosion and wear behaviors of Al-bronzes in 5.0% H2SO4 solution

    Institute of Scientific and Technical Information of China (English)

    LI Wen-sheng; WANG Zhi-ping; LU Yang; YUAN Li-hua; XIAO Rong-zhen; ZHAO Xu-dong

    2009-01-01

    Steady-state corrosion and wear behaviors of two Al-bronzes, Cu-14Al-X and QAl9-4, in 5.0% H2SO4 solution were investigated. It is found that wear loss of bronzes in 5.0% H2SO4 solution is lower than that in water or in air, namely, it exhibits negative synergy between corrosion and wear. Further analysis shows that corrosive solution plays an important role in cooling of specimen during the sliding wear to prevent the reduction of the surface hardness of specimen, induced by frictional heat. On the other hand, the bronzes suffer a de-alloying corrosion, and a noble copper subsurface and patina form on the specimen surface in corrosive solution, which has a passive function for further corrosion. The noble copper subsurface experiences strain hardening during the corrosion and wear, resulting in the increase of the surface hardness thus the increase in wear resistance.

  2. A Preliminary Study of Bronzes in the Kayao Culture%卡约文化青铜器初步研究

    Institute of Scientific and Technical Information of China (English)

    三宅俊彦

    2005-01-01

    A chronological study of its pottery suggests that the Kayao culture remains can be divided into the groups of Huangshui River and Yellow River valleys and each group fall into six phases.On this basis the typology and combination of bronzes in the Kayao culture can be further studied. The results indicate that bronze-making technology in the Huangshui River valley was higher than that in the Yellow River valley, and that the sexual difference of tomb-owners is reflected from the distinction of funeral objects. Furthermore, the chronological study of the Kayao's bronzes provides reference data for dating the phases of this culture. These bronzes possess three categories of cultural elements: the elements of their own, common elements of bronzes in the Central Plains and North China, and those in northern Eurasia.

  3. Analysis of the Portevin - Le Chatelier effect in tin bronzes at elevated temperatures

    Directory of Open Access Journals (Sweden)

    W. Ozgowicz

    2008-12-01

    Full Text Available Purpose: The aim of the present paper is the determination of the effect of the chemical composition and temperature of deformation of standardized tin bronzes and bronze modified with zirconium on the Portevin – Le Chatelier (PLC phenomenon, mainly basing on the shape of stress-strain curves within the temperature range of 100-300oC and observations of their structure. The reasons of the occurrence of such en effect are so far no fully known and explained and the opinions concerning is physical basis vary.Design/methodology/approach: Of essential design in this research is determination of the dependence of PLC effect on the chemical composition, temperature and strain rate and the preliminary heat treatment and grain size. The main method used in this investigation is tensile test at elevated temperature.Findings: The main conclusions are following: the PLC effect on tin bronzes with a micro-addition of zirconium in an amount of 0.01-0.05% depends the temperature of deformation in the tensile test in the range of 100-300oC and the chemical composition of the alloys; the type of serration revealed on the σ–ε curve depend mainly on the temperature of deformation and can be differ during the respective stages of the analyzed curves.Practical implications: In this paper implications for practice are not taken into consideration.Originality/value: In this paper an additive type of serration observed on the curves σ–ε, denoted by the symbol D, is new.

  4. On the degradation factors of an archaeological bronze bowl belonging to a private collection

    Energy Technology Data Exchange (ETDEWEB)

    Soffritti, C., E-mail: chiara.soffritti@unife.it [TekneHub, Department of Architecture, University of Ferrara, Via Quartieri 8, 44122 Ferrara (Italy); Department of Engineering, University of Ferrara, Via Saragat 1, 44122 Ferrara (Italy); Fabbri, E., E-mail: elettra.fabbri@unife.it [Department of Engineering, University of Ferrara, Via Saragat 1, 44122 Ferrara (Italy); Merlin, M., E-mail: mattia.merlin@unife.it [Department of Engineering, University of Ferrara, Via Saragat 1, 44122 Ferrara (Italy); Garagnani, G.L., E-mail: gian.luca.garagnani@unife.it [Department of Engineering, University of Ferrara, Via Saragat 1, 44122 Ferrara (Italy); “A. Daccò” Corrosion and Metallurgy Study Centre, University of Ferrara, Via Saragat 1, 44122 Ferrara (Italy); Monticelli, C., E-mail: cecilia.monticelli@unife.it [Department of Engineering, University of Ferrara, Via Saragat 1, 44122 Ferrara (Italy); “A. Daccò” Corrosion and Metallurgy Study Centre, University of Ferrara, Via Saragat 1, 44122 Ferrara (Italy)

    2014-09-15

    Highlights: • Bronze bowl from Iran belonging to a private collection. • Style and manufacturing consistent with the Achaemenid art (I century B.C.). • Modified Type I patinas. • Apparently continuous tenorite layer at the metal surface on the internal bowl side. • Fragmentation attributed to a severe intergranular attack. - Abstract: A bronze bowl belonging to a private collection, stylistically consistent with the Achaemenid art was investigated to determine the cause of the artwork local fragmentation. The corrosion products were characterised by energy dispersive X-ray fluorescence spectrometry (EDXRF), Raman spectroscopy and scanning electron microscopy (SEM) equipped with energy dispersive spectroscopy (EDS). The last technique was also used to determine the chemical composition of the alloy. The metallographic analysis showed that the bowl was obtained from a monophasic bronze alloy, containing about 11% tin and other elements in traces. The presence of an inhomogeneous microstructure with both thermal twin bands and slip lines was consistent with multiple hammering steps followed by partial annealing treatments. On the bowl a very limited chloride contamination was observed and chlorides were never detected in proximity to the metal. These findings and the morphological/compositional characteristics of the patinas permitted to classify that on the internal side of the bowl as a modified Type I morphology, while the patina on the external side of the bowl was less compact, so that it was judged borderline between a “noble” patina and a disfiguring one. On this side, a significant intergranular attack was found, reputed responsible for the fragmentation occurred.

  5. Characterization and Photocatalytic Activity of KSr_2Nb_5O_(15) with Tungsten Bronze Structure

    Institute of Scientific and Technical Information of China (English)

    ZHANG Gaoke; LI Yiqiu; WANG Junting; TU Haibin; YU Xinyi

    2009-01-01

    Tungsten bronze(TB)type potassium strontium niobate KSr_2Nb_5O_(15) was prepared by solid-state reaction method,and was characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM)and UV-vis diffuse spectrum.The photocatalyst shows high photocatalytic activity of photodegrading acid red G.The effects of photocatalyst dosage and initial concentration of acid red G on the photodegradation process were studied.The kinetics of photocatalytic degradation of acid red G by KSr_2Nb_5O_(15) catalyst follows the first order reaction.

  6. Electrolytic surface hardening of steel,castiron and aluminium-bronze

    Directory of Open Access Journals (Sweden)

    Suhas Keshav Paknik a r

    2006-08-01

    Full Text Available Electrolytic hardening process w as developed in USSR in the 1950s. The process w as developed but w as not com m ercially exploited. There is no evidence of w ork done on this process in India. The author has done this originalw ork applied to different m aterials like steel, castiron and alum inum -bronze.This paper gives details ofm icrostructuraltransform ations along w ith hardness value achieved. There is vitalscope for this process to becom e viable for surfacehardening and selective hardening ofsm allcom ponents.

  7. THE EFFECTS OF PERFORMANCE CHARACTERISTICS TO THE COEFFICIENT OF FRICTION IN SINTERED BRONZE BEARINGS

    Directory of Open Access Journals (Sweden)

    Gültekin KARADERE

    2001-01-01

    Full Text Available In this study, the effects of performance characteristics of self-lubricating, sintered bronze journal bearings to the coefficient of friction is investigated via an experimental test rig. In the experiments, the variation of the coefficient of friction for different velocities and pressures has been investigated for the cases in which an additional oil mass is fed and not fed into the bearing. Furthermore, in the cases where the other parameters are kept constant, the effects of velocity, pressure and temperature to the coefficient of friction are separately investigated, and the results are plotted.

  8. The Chalcolithic and the Bronze Age in the river Neiva Basin, NW of Portugal

    OpenAIRE

    Magalhães, Marisa Cardoso

    2016-01-01

    Relatório de estágio de mestrado em Arqueologia O presente relatório deseja expor os resultados da investigação sobre o Calcolítico e a Idade do Bronze da bacia do Neiva, desenvolvida durante o segundo ano de Mestrado em Arqueologia na Universidade do Minho. Relativamente a estes períodos cronológicos podemos destacar a diversidade de estratégias de povoamento, com tendências para ocupações de locais de menor altitude e mais próximas de vales. Estas comunidades que se estabelec...

  9. Synthesis and structure of a quadratic oxygen bronze containing uranium of valence six

    International Nuclear Information System (INIS)

    (Nb7.6U2.4)(Ba5.2K0.8)O30 is a quadratic bronze with space group P4bm and lattice parameters a = 12.608(5) and c = 4.012(2) A, Z=1. The structure of a single crystal was refined to R = 0.056 (RW = 0.072) for 967 independent reflections with I ≥ 3σI. The U6+ ion is located inside octahedral sites with Nb5+ and Nb4+. (orig.)

  10. THE PALEODEMOGRAPHIC PATTERN OF OYLUM HOYUK POPULATION (THE MIDDLE BRONZE AGE, KİLİS)

    OpenAIRE

    Ayşen Açıkkol Yıldırım

    2013-01-01

    In this study skeleton remaining of 72 individuals excavated from Middle Bronze Age layers of Oylum Höyük (mound) situated in Kilis province, were studied. Sex and age of skeletons, unearthed between 2007-2012, were determined and life tables of the population were formed. Mortality of infants and children of Oylum population was very high. Death rates were determined as 36.6 % for 0-5 years of age group, 57.75 % for 0-15 years of age group. 34.62 % of infants and children from 0-5 years of a...

  11. ARCHAEOMETALLURGICAL STUDIES OF SPEAR HEADS AND ARROW HEADS OF THE MIDDLE BRONZE AGE SITES OF AZERBAIJAN

    OpenAIRE

    Hasanova, Aziza

    2015-01-01

    Quantitative spectroscopy analysis of spear heads and arrow heads of Middle Bronze Age sites of Azerbaijan (second part of the III to the middle of the II millennium BC) has been made to determine the type of the alloy taking into account the accepted limits of natural impurity in metals ( - 0.5% and more). The analyses have shown that copper is the basic materials in all of them. Metallurgical classification the results of sixteen analysis spear heads have shown three of them made of arsenic...

  12. Compositional analyses of a Reutlingen Bronze Age sword discovered at Giurgiu, Romania

    CERN Document Server

    Olariu, A; Avram, A; Badica, T; Olariu, Agata; Alexandrescu, Emilian; Avram, Alexandru; Badica, Teodor

    2003-01-01

    The compositional scheme of a Bronze Age sword, found near the town of Giurgiu in Romania has been determined by the method of particle-induced X-ray emission (PIXE), at the tandem accelerator of the National Institute for Physics and Nuclear Engineering from Bucharest, Magurele, Romania. The results of the analyses and the comparison with the composition of other swords from the same geographic area, the Danubian plane from Bulgaria and Transylvania regions, show that the sword from Giurgiu could be relatively associated with the swords from Bulgaria, having also the same stylistic, temporal and geographical similitude.

  13. 夏商周青铜器铅同位素示踪研究数据库的构建%A Lead Isotope Ratio Data Base of Ancient Chinese Bronzes

    Institute of Scientific and Technical Information of China (English)

    金正耀

    2005-01-01

    A data base of lead isotope ratio of ancient Chinese bronzes is set up. There are 2 888 members, including bronze objects, casting remains, and related ores, etc. in the file. The file contents of data base are made from analysis work on Chinese bronze previously carried out in several laboratories in China, Japan and USA. The main body of the file contents is formed from records, analysis data, reference documents, and images. The data base is designed for sharing information in provenance study on raw metal material for bronze production in China Bronze Age.

  14. Integrated analytical methodologies for the study of corrosion processes in archaeological bronzes

    Energy Technology Data Exchange (ETDEWEB)

    Alberghina, Maria Francesca; Barraco, Rosita; Brai, Maria; Schillaci, Tiziano, E-mail: tschillaci@unipa.it; Tranchina, Luigi

    2011-02-15

    The investigations on structure and micro-chemical composition of archaeological metal alloys are needed in archaeometry. The aim of this study is devoted both to acquire information about their provenance and production technology, and to improve our understanding about the corrosion processes. In this paper we present the study of the corrosion phenomena of bronze samples, laboratory-made according to binary, ternary and quaternary alloys typical of Roman archaeometallurgical production through an integrated methodology based on the use of non or micro invasive physical techniques. Among the analysed samples, two were artificially aged through burial in the archaeological site of Tharros, along the west coast of Sardinia (Italy). The corrosion products, typical of the bronzes in archaeological sites near the sea, have been characterized by non invasive and micro-destructive measurements. In particular, the corrosion patinas were examined through optical microscopy, scanning electron microscopy and microanalysis, X-ray fluorescence and laser ablation spectroscopy. The use of integrated technologies allowed us to determine both the elemental composition and surface morphology of the patina, highlighting the correlation between patina nature and chemical composition of the burial context. Moreover, data obtained by the laser-induced breakdown spectroscopy along the depth profile on the samples, have yielded information about the stratigraphic layers of corrosion products and their growth. Finally, the depth profiles allowed us to verify both the chemical elements constituting the patina, the metal ions constituting the alloy and the occurrence of migration phenomena from bulk to the surface.

  15. Las Lunas (Yuncler, Toledo. A Bronze Age hoard with metallic materials from the southern Iberian Meseta

    Directory of Open Access Journals (Sweden)

    Urbina Martínez, Dionisio

    2010-06-01

    Full Text Available Here we present the results of the preliminary study carried out on a new group of metallic materials of the Final Bronze Age, recovered at the end of 2008 in the archaeological excavations at the settlement of Las Lunas (Yuncler, Toledo, Spain. Its geographical situation far away from the main zones of distribution of this type of finds, the singularity of the materials, and the evidence of Atlantic and Mediterranean relations make these materials a remarkable sample for the study of the Final Bronze Age in the centre of the Iberian Peninsula.

    Se exponen los resultados del primer estudio realizado sobre un nuevo conjunto de materiales metálicos del Bronce Final recuperado a finales de 2008 en las excavaciones arqueológicas del yacimiento de Las Lunas (Yuncler, Toledo, España. La localización geográfica del hallazgo, lejos de las principales zonas de dispersión conocidas para este tipo de conjuntos, la singularidad de los objetos que integra, y las relaciones atlánticas y mediterráneas que evidencian sus materiales, lo convierten en un ejemplo destacado para el estudio de este período en el centro de la Península Ibérica.

  16. Thermal conductance at millikelvin temperatures of woven ribbon cable with phosphor-bronze clad superconducting wires

    Science.gov (United States)

    Woodcraft, Adam L.; Ventura, Guglielmo; Martelli, Valentina; Holland, Wayne S.

    2010-08-01

    Woven Nomex® ribbon cables made up with superconducting niobium-titanium wire are used at millikelvin temperatures in many large cryogenic instruments. It is important to know how much heat in transmitted down such cables. However, the conductivity of the materials used is not well known. Another problem is that the wires are normally clad with alloys which exhibit some magnetism. This is a potential problem for instruments employing superconducting detectors. A safe non-magnetic alternative to the usual materials is phosphor-bronze clad niobium-titanium wiring. However, there is little experience with such wires. We have therefore measured the conductance of a ribbon cable made up with these wires. The measured values are in good agreement with our predictions, suggesting that the values we have used to model the cable are sufficiently accurate, and could therefore be used to predict the performance of ribbon cables using other cladding materials, so long as the conductivity of the cladding is reasonably well known. As part of our analysis, we consider the likely variation in thermal conductivity values for C51000 phosphor bronze caused by legitimate variations in composition.

  17. Ancient bronze coins from Mediterranean basin: LAMQS potentiality for lead isotopes comparative analysis with former mineral

    Science.gov (United States)

    Torrisi, L.; Italiano, A.; Torrisi, A.

    2016-11-01

    Bronze coins coming from the area of the Mediterranean basin, dated back the II-X Cent. A.D., were analyzed using different physical analytical techniques. Characteristic X-ray fluorescence was used with electrons and photons, in order to investigate the elemental composition of both the surface layers and bulk. Moreover, the quadrupole mass spectrometry coupled to laser ablation (LAMQS technique) in high vacuum was used to analyse typical material compounds from surface contamination. Mass spectrometry, at high resolution and sensitivity, extended up to 300 amu, allowed measuring the 208Pb/206Pb and 207Pb/206Pb isotopic ratios into the coins. Quantitative relative analyses of these isotopic ratios identify the coin composition such as a "fingerprint" depending on the mineral used to extract the lead. Isotopic ratios in coins can be compared to those of the possible minerals used to produce the bronze alloy. A comparison between the measured isotope ratios in the analyzed coins and the literature database, related to the mineral containing Pb as a function of its geological and geophysical extraction mine, is presented. The analysis, restricted to old coins and the mines of the Mediterranean basin, indicates a possible correlation between the coin compositions and the possible geological sites of the extracted mineral.

  18. The bronze shields found at the Ayanis fortress (Van region, Turkey): manufacturing techniques and corrosion phenomena

    Science.gov (United States)

    Ingo, G. M.; Çilingiroğlu, A.; Faraldi, F.; Riccucci, C.; Casaletto, M. P.; Erdem, A.; Batmaz, A.

    2010-09-01

    The manufacturing techniques, chemical composition and corrosion products grown on archaeological bronze shields found during the excavation of the Ayanis fortress (Lake Van region, Eastern Anatolia, Turkey) were studied by means of the combined use of scanning electron microscopy combined with energy dispersive spectrometry (SEM-EDS), X-ray diffraction (XRD) and optical microscopy (OM) techniques. The shields are dated back to 673-645 BC and in some cases are decorated with cuneiform inscriptions and ornaments representing various animals, such as lions and bulls. The micro-chemical and structural results show the presence of corrosion products constituted by copper carbonates (azurite and malachite), cuprite and dangerous chlorine-based compounds (nantokite, atacamite, clinoatacamite and paratacamite) due to the Cl-enriched soil of Ayanis. Furthermore, the results show that the bronze shields are coated with a Sn-enriched thin layer, likely due to an intentional tinning process carried out in ancient times to achieve a silver-like finish. Analytical data show an inter-granular corrosion phenomenon that heavily corroded the boundaries of the large equiassic grains inducing mechanical weakness. This latter phenomenon was induced by the repeated cycles of mechanical work and annealing thermal treatments carried out to restore the ductility and malleability of the alloy. Such processing caused the crystallisation and growth of the flattened grains, as well as impurities segregation phenomena along grain boundaries, thus enhancing the inter-granular long-term corrosion.

  19. Neutron activation analysis of Lerna ceramics (Greece) at Early Bronze Age: local production and trade exchanges

    International Nuclear Information System (INIS)

    Neutron activation analysis is a powerful tool for determining the provenance of ancient ceramics. A sophisticated analytical system for gamma-ray spectrometry, designed specifically for the chemical analysis of ceramics by thermal neutron activation, was used to determine the concentrations of twenty elements in samples of ancient pottery. The measurements were made relative to the standard pottery of Perlman and Asaro. The purpose of the work was to study the production of fine pottery at the settlement of Lerna, in the Argolid of Greece, during the Early Bronze Age (third millennium BC). About half of the 50 samples analysed formed the major compositional group, which was attributed to Lerna. It included, besides the majority of the samples from the second phase of the Early Bronze Age (Lerna III), several samples from the third phase (Lerna IV); that is, from levels immediately succeeding the great destruction which marks the end of the Lerna III settlement. A small number of objects forms a second group of local origin and includes 4 of the 5 clay sealings sampled. Among the archaeologically unusual objects, several could be attributed to Lerna, while others were characterized as imports

  20. The atmospheric corrosion of quaternary bronzes: An evaluation of the dissolution rate of the alloying elements

    Science.gov (United States)

    Bernardi, E.; Chiavari, C.; Martini, C.; Morselli, L.

    2008-07-01

    A comparative evaluation of the corrosion behaviour of a G85 bronze in acid rain solutions was performed. As weathering technique, a wet dry device was used to simulate a cyclic exposure to stagnant rain. The weathering solutions were a collected natural rain and an artificial solution reproducing the natural rain. The solutions were periodically monitored as concerns pH and metallic ion concentrations. On the aged specimens, surface studies were performed through OM, SEM and Raman analyses. At the end of weathering tests (40 days), weight loss measurements were carried out. The aim of this work was to examine the reproducibility in laboratory of the corrosive conditions determined by a natural acid rain. The final goal of this research is to investigate the dissolution of a quaternary alloy exposed to acid rains. The results showed slightly different corrosion behaviours as a consequence of the exposure to natural or synthetic rain. Concerning the mechanism of corrosion of G85 bronze, the innovative approach adopted in this study allowed one to point out the contribution of each alloying element to the general corrosion. Actually, while Cu and Pb progressively form insoluble corrosion compounds, Zn continuously dissolves, without forming detectable insoluble products. The absence of dissolved tin is remarkable.

  1. The Pranemuru project and the radiocarbon chronology of the Sardinian Bronze Age

    Directory of Open Access Journals (Sweden)

    Rubinos, Antonio

    2003-12-01

    Full Text Available New C-14 data collected by a Spanish team working in the Sardinian Pranemuru area, allow usthe possibility of revising the C-14 Chronology for the Nuragic Bronze Age and discussing the reliability of some of the dates, as well as the way they have been published, and their matching with the new official chronology for the Sardinian Bronze and Iron Ages, built on Dendro and C14 sequences for the Italian Peninsula.

    La obtención por parte del Proyecto Pranemuru de cerca de una veintena de dataciones radiocarbónicas para una microregión en época nurágica, de las que aquí se recogen discuten catorce, abre la posibilidad de revisar la cronología de la Edad del Bronce en Cerdeña, a la luz de las dataciones recogidas desde los años 90 por Trump (1990 y Tykot (1994 y, más recientemente, por Webster (2001, discutir la validez de las fechas en función de los criterios de recogida de muestra, contexto arqueológico, desviación estándar y forma en que ha sido publicada, así como contrastarla con la cronología propuesta recientemente para la Protohistoria sarda, de acuerdo con la Dendrocronología y Cronología Radiocarbónica para la Italia peninsular (Lo Schiavo 2002.

  2. $Nb_{3}Sn macrostructure, microstructure, and property comparisons for bronze and internal Sn process strands

    CERN Document Server

    Lee, P J; Larbalestier, D C

    2000-01-01

    The variation in irreversibility field, B*(T), with temperature has been measured for Nb/sub 3/Sn superconducting strands manufactured for ITER using vibrating sample and SQUID magnetometers. The high performance strands were developed for both high transport critical current density, J/sub c/, and low hysteresis loss. Despite a wide variety of designs and components, the strands could be split into two distinctive groups, based on the extrapolated irreversibility fields, which lie about 10% lower than the upper critical field. "Bronze-process" strands exhibited consistently higher B*(T) (28 T to 31 T) compared with "internal Sn" process (24 T to 26 T) conductors. The intrinsic critical current density of the superconductor, J/sub c (sc)/, and the specific pinning force of the grain boundaries, Q/sub gb/, were evaluated using the measured J/sub c/, and image analysis of the macro- and micro-structures. A bronze-processed Nb(-Ta)/sub 3 /Sn was found to have a higher J/sub c(sc)/ but lower Q/sub gb/ than Nb/sub...

  3. Investigation on corrosion stratigraphy and morphology in some Iron Age bronze alloys vessels by OM, XRD and SEM-EDS methods

    Science.gov (United States)

    Oudbashi, Omid; Hasanpour, Ata; Davami, Parviz

    2016-04-01

    The recently study of the corrosion in some bronze artefacts from the Sangtarashan Iron Age site, western Iran, was established to identify corrosion morphology and mechanism in these objects. The corrosion layers in 22 samples were studied by optical microscopy, scanning electron microscopy-energy-dispersive X-ray spectroscopy and X-ray diffraction methods. The results showed that a thin corrosion crust has formed on the surface of bronzes with a triple-layer structure, including two internal and one external corrosion layers. The formation of these layers is due to copper leaching from the bronze surface. The internal corrosion part has been a compact, tin-rich corrosion/oxidation product (noble patina) with some evidences from original metallurgical aspects of the bronze as well as a very thin layer beneath the tin-rich layer. External corrosion products have been identified as basic copper carbonates, malachite and azurite. Based on the results, the corrosion morphology in the Sangtarashan Iron Age bronzes is due to long-term burial in an appropriate environment in a moderately corrosive soil. Although it is the first time to investigate Iron Age bronzes from Iran, this corrosion morphology is partially similar to type I corrosion morphology observed in archaeological bronze objects; nevertheless, some deviations are visible in comparison with previously established patterns.

  4. 3D scanning and printing as conversation tools: an innovative treatment of a vandalized bronze statue, The Thinker by Rodin

    NARCIS (Netherlands)

    T. Beentjes; R. van der Molen

    2011-01-01

    This contribution discusses the innovative treatment of a severely vandalized bronze sculpture, The Thinker by Auguste Rodin, from the Singer Museum in Laren, The Netherlands. Additional aspects of this controversial treatment such as decision making and documentation are also discussed. In 2007 the

  5. THE RELATIONSHIP BETWEEN EGYPT AND PALESTINE IN THE MIDDLE BRONZE AGE (CA.2000-1550/1500 BCE.)

    Institute of Scientific and Technical Information of China (English)

    GuoDantong

    2004-01-01

    The relationship between Egypt and Palestine during the Bronze Age has been discussed since the 1940s. For the period of the Middle Bronze Age, the problem is both chronological and interpretative. The end of the Middle Bronze Age is fixed by the initial military activities of Dynasty 18 in Palestine around the end of the 16th century BCE. But the dates for the beginning of this period and the transition from one archaeological phase to another are still debated. Lacking a generally accepted solution, the chronology adopted here is that of Dever --- the transition from MB Ⅰ to MB Ⅱ occurred around 1800 BCE,

  6. Use of portable X-ray fluorescence instrument for bulk alloy analysis on low corroded indoor bronzes

    Energy Technology Data Exchange (ETDEWEB)

    Šatović, D., E-mail: dsatovic@alu.hr [Department of Conservation and Restoration, Academy of Fine Arts, Ilica 85, 10000 Zagreb (Croatia); Desnica, V. [Department of Conservation and Restoration, Academy of Fine Arts, Ilica 85, 10000 Zagreb (Croatia); Fazinić, S. [Laboratory for Ion Beam Interactions, Ruđer Bošković Institute, Bijenička 54, 10000 Zagreb (Croatia)

    2013-11-01

    One of the most often used non-destructive methods for elemental analysis when performing field measurements on bronze sculptures is X-ray fluorescence (XRF) analysis based on portable instrumentation. However, when performing routine in-situ XRF analysis on corroded objects obtained results are sometimes considerably influenced by the corrosion surface products. In this work the suitability of portable XRF for bulk analysis of low corroded bronzes, which were initially precisely characterized using sophisticated and reliable laboratory methods, was investigated and some improvements in measuring technique and data processing were given. Artificially corroded bronze samples were analyzed by a portable XRF instrument using the same methodology and procedures as when performing in-situ analysis on real objects. The samples were first investigated using sophisticated complementary laboratory techniques: Scanning Electron Microscopy, Proton-Induced X-ray Emission Spectroscopy and Rutherford Backscattering Spectrometry, in order to gain precise information on the formation of the corrosion product layers and in-depth elemental profile of corrosion layers for different aging parameters. It has been shown that for corrosion layers of up to ca. 25 μm a portable XRF can yield very accurate quantification results. - Highlights: • XRF quantification is very accurate for bronze corrosion layers of up to ca. 25 μm. • Corrosion layer formation on bronze described in two phases. • Corrosion layers precisely characterized using PIXE, RBS and SEM. • Corrosion approximated as CuO for layer thickness calculations via X-ray attenuations • Increasingly lighter corrosion matrix may cause SnLα radiation intensity inversion.

  7. Settlement and landscape history of the Northern Franconian Jura during the Bronze and Iron Ages

    Science.gov (United States)

    Kothieringer, Katja; Lambers, Karsten; Seregély, Timo; Schäfer, Andreas

    2014-05-01

    This paper describes the results of initial archaeological and geoarchaeological fieldwork in the Northern Franconian Jura between the cities of Bayreuth and Bamberg. Our research aims at the reconstruction of settlement patterns and strategies of land use during the Metal Ages (Bronze Age and Iron Age) in the catchment area of the river Weismain. The project is designed as a case study for research into the settlement and landscape history of a rural region of the Central German Uplands during the last two millennia before our era. During the Bronze Age and Iron Age (about 2.100 BC to 30 BC), the Northern Franconian Jura must have been densely populated, as evidenced by numerous burial monuments, prominent hillforts like the Staffelberg, and ritual places on the Jurassic plateau. However, little is known about small rural settlements and hamlets which would have accounted for most of the settlement activity in the region. Thus, we lack the most important element for understanding the cultural history and development of the region as well as the consequences of human impact on the landscape. This impact must have induced changes in vegetation and subsequent erosion processes, leading to the formation of geoarchives like colluvial layers. During our initial fieldwork we identified such colluvial layers in depressions on the Jurassic plateau or at footslope positions. As radiocarbon datings of charcoal fragments showed, some of them date from the Metal Ages. The type is wood of these charcoal fragments is oak, which recently only occurs sporadically in mixed forests with beeches. The quantification of the shift of sediments from the plateau to the valleys will be the next important step of geoarchaeological research. Thus, investigations both on the plateau and in the river valleys will accompany archaeological survey. Apart from landscape reconstruction, they will also provide information on the state of preservation and the conditions for identifying archaeological

  8. GPR Surveys for Archaeological Investigation in a Bronze Age site from NW Portugal

    Science.gov (United States)

    Gonçalves, L.; Sampaio, H. A.; Bettencourt, A. M. S.; Alves, M. I. C.

    2012-04-01

    This work describes the use of Ground-penetrating Radar (GPR) surveys in the identification and mapping of subtle cultural remains, from Pego Late Bronze Age settlement, located near the city of Braga, in NW Portugal. Bronze Age settlements from NW Portugal are characterized by the presence archaeological structures such as storage pits, postholes and trenches. These subtle structures have a very low dielectric contrast, making them quite difficult to detect in GPR surveys. In the case of Pego Site, previous investigations using conventional archaeological techniques, during a rescue excavation, partially revealed a residential area, a necropolis, and a stockade foundation trench that encircle the whole settlement. Different GPR prospection approaches were performed using GSSI Sir 3000 System, with 400 MHz antennae, with the objective of identify and define the borders between the different areas of human occupation inside the settlement. For the GPR survey, a grid-based approach with closely spaced parallels transects was defined, covering different areas inside the site. A first survey was conducted with a pseudo-3D methodology, with 50 cm profile separation, followed by a second survey with a dense data acquisition methodology, with 10 cm profile separation. Processed two-dimensional GPR profiles and constructed amplituded-slice maps were produced and analysed. Wave velocities were determined by reflected wave methods and by Hyperbola-Fitting method. The background analysis of the archaeological and geological features of the site, integrated with the preliminary interpretation of GPR data (profiles and amplitude slice-maps) suggest the presence of flat graves, in the west part of the site, and storage pits, post holes and some small trenches, in the centre and north area of the settlement. This interpretation indicates that the settlement is individualized in two different areas, a necropolis and a residential area, such as the first archaeological study

  9. Armorican arrowhead biographies: Production and function of an Early Bronze Age prestige good from Brittany (France

    Directory of Open Access Journals (Sweden)

    Clément Nicolas

    2014-09-01

    Full Text Available Brittany can pride itself on the Armorican arrowheads found in Early Bronze Age graves (2150-1700 BC. In the present state of knowledge, these are the only specialized craft products in knapped flint produced in this region at the western edge of continental Europe. Admired since the 19th century, these flint arrowheads have never really been studied. Due to the wealth of graves and grave-goods, a relatively precise study can be undertaken of the development of these craft products, despite the low number of reliable radiocarbon dates.These arrowheads are characterized by a well-defined type (pointed tang and oblique barbs most often combined with ogival form. Raw materials show the selection of a high quality yellow translucent flint, of which the origin has to be sought at more than 400 kilometers (Lower Turonian flint from Cher Valley. From a technical point of view, Armorican arrowheads reveal a great mastery of retouch by pressure-flaking. This skill is written in stone by the perfection of forms, the extreme thinness (until 2,5 mm thick and very long barbs (until 25 mm long. Such work could not have been done without the use of copper, even bronze, awls. Moreover, some marks may testify to the implication of these tools. On 549 arrowheads that have reached to us, none of them presents diagnostical impact features. However, use-wear analysis indicates that most of them were hafted (adhesive traces, bright spots, blunt edges. These facts suggest that they are less functional arrowheads than objects for the show. In the graves, Armorican arrowheads are frequently set down carefully in wooden boxes taking the shaft off.The Armorican arrowheads with their exotic raw materials, their high-degree of technicality, and their absence of use, have all features of a prestige good. They have been discovered by dozens in few graves under barrows with very rich funeral items (bronze daggers decorated with golden pins, precious bracers, silver beakers

  10. Earthquake and the Catastrophic End of the Late Bronze Age in the Eastern Mediterranean

    Science.gov (United States)

    Nur, A.

    2009-04-01

    The reasons for the catastrophic and wide spread political as well as physical collapse in the Aegean and Eastern Mediterranean areas that define the end of the Bronze age ca. 1225 BC to 1175 BC remain a major enigma. It has been attributed by historian to attacks by outsiders with the most favored group being the (enigmatic) so-called sea people. Unfortunately there is no real evidence for this. However combined geological, geophysical and archaeological evidence suggests that earthquakes may have played a key role in this extraordinary collapse during the late 13th and early 12th centuries . Based on the instrumentally recorded earthquakes occurring in the Aegean and Eastern Mediterranean region during the 20th century, several events that have clear historical information, and the geography of seismically active faults it is obvious that numerous earthquakes of magnitude 6·5 or greater (enough to destroy modern buildings, let alone those of antiquity) occurred here frequently in the past. Furthermore major earthquakes often occur in this region in groups, known as ‘‘sequences'' or ‘‘storms'', in which one large quake is followed days, months, or a few years later by others elsewhere on the plate boundary fault lines. When a map of the areas in the Aegean and Eastern Mediterranean region shaken by 20th century  earthquakes of magnitude 6·5 and greater and with an intensity of VII or greater is overlaid on Robert Drews' map of sites destroyed in these same regions during the so-called ‘‘Catastrophe'' near the end of the Late Bronze Age, it is readily apparent that virtually all of these LBA sites lie within the affected (‘‘high-shaking'') areas. This would suggest that a major ‘‘earthquake storm'' may have occurred in the Late Bronze Age Aegean and Eastern Mediterranean during the years 1225-1175 . This ‘‘storm'' may have interacted with societal, political and economic forces at work in these areas c. 1200  and

  11. Crystallographic conditions for the initiation of cavitation erosion in CuMn11Al11 bronze

    Directory of Open Access Journals (Sweden)

    D. Zasada

    2008-09-01

    Full Text Available Purpose: The basic aim of this paper is to examine and present specific destruction processes connected with cavitation erosion of multi-component Cu-Mn-Al bronzes. In technical operational conditions these processes are ‘masked’ by the effects of electrochemical corrosion phenomena. However, these destructive processes may significantly accelerate the destruction of flow devices and marine propulsion systems. The essential phenomena occurring during these processes are incubation and propagation of brittle cracks in the planes of cleavage planes of the ordered phase β (Cu3Mn2Al that occurs in the examined group of alloys. Additional purpose is the assessment of possible applications of alloys with single-phase structure of intermetallic phases as model materials for research into erosion-cavitation resistance.Design/methodology/approach: This work presents research results concerning erosion cavitation resistance of a model alloy examined at a cavitation jet stand. The destructed areas were examined by gravimetric methods and those using scanning microscopy combined with computer image analysis. As the test materials used were single phase model alloys with the composition simulating selected phase components of Cu-Mn-Al bronzes, it was possible to examine erosion cavitation phenomena in the conditions of minimized effect of electrochemical phenomena.Findings: It has been found that at the initial period of destruction of the phase β in multi-component Mn-Al bronzes the prevailing form of destruction was a classical attack along grain boundaries, starting from the grain boundary junctions while in cases where the Cu3Mn2Al superstructure was present, the major mechanism of the incubation of erosion cavitation damage in the phase β is brittle cracking along cleavage planes {001} oriented at 45° angle to the exposed surface.Research limitations/implications: An essential problem is the verification of the results obtained using the

  12. Structural Analysis and Electrical Property of Tungsten Bronze Prepared by Rare Earth Gaseous Permeation

    Institute of Scientific and Technical Information of China (English)

    李中华; 李昕; 陈刚; 苏铭汉; 韦永德

    2004-01-01

    The cubic sodium tungsten bronzes, NaxWO3(x=0.854 and 0.814)were prepared by rare earths gaseous permeation method. Structural analysis was carried out by Rietveld method from powder X-ray diffraction data. The X-ray diffraction profile calculated with cubic P32 models are in good agreement with the observed X-ray diffraction patterns. There is only a little difference in W-O bond and Na-O bond between Na0.854WO3 and Na0.814WO3. Conductivity measurements indicate that NaxWO3 show anomalous semiconducting behavior and percolation model was used to interpret it.

  13. Influence of precipitate size and morphology on grain refinement in nickel aluminium bronze

    Science.gov (United States)

    Barr, C. J.; Xia, K.

    2015-08-01

    Nickel aluminium bronze (NAB) was subjected to equal channel angular pressing (ECAP) using routes BA and C at 400°C to investigate the effect of precipitate size and morphology on grain refinement in low stacking fault energy alloys. Both routes produced dynamically recrystallised grains of ∼550 nm in size although only route BA was able to create a uniform distribution of the refined grains. The large unrefined regions in NAB processed via route C was thought to arise from its inability to redistribute the various precipitate phases, as recrystallisation was enhanced around the coarse κII rosettes and refined κIII lamellae but reduced in the areas containing fine κIV precipitates.

  14. Aromatic quinoxaline as corrosion inhibitor for bronze in aqueous chloride solution

    Indian Academy of Sciences (India)

    N Saoudi; A Bellaouchou; A Guenbour; A Ben Bachir; E M Essassi; M El Achouri

    2010-06-01

    A new corrosion inhibitor, viz. 3-ethyl-6-méthyl-quinoxalin-2-one, 1-benzyl-6-methyl-quinoxalin- 2-one, 2-benzyloxy-3,6-dimethyl-quinoxaline, 1-benzyl-3-methyl-quinoxalin-2-one, were synthesized in the laboratory. Their influence on the inhibition on corrosion of bronze in aqueous chloride solution (3% NaCl) was studied by electrochemical polarization methods and weight-loss measurements. The impact of temperature on the effectiveness of the substances mentioned above has been determined between 20 and 60°C. The results showed that the corrosion resistance was greatly enhanced in the presence of inhibitor and that the effectiveness depends on some physicochemical properties of the molecule, related to its functional groups. These compounds act through the formation of a protective film on the surface of the alloy.

  15. Paysages funéraires de l’âge du Bronze

    OpenAIRE

    Gomez de  Soto, José

    2015-01-01

    Du 15 au 18 octobre 2008 s’est tenu au musée de Herne en Westphalie un colloque international intitulé « Gräberlandschaften der Bronzezeit. Paysages funéraires de l’âge du Bronze ». Cette manifestation s’insère dans une succession de colloques bi-annuels inaugurée par celui sur le RSFO tenu à Nemours en 1986. Les actes, qui viennent de paraître, réunissent trente-sept contributions, rédigées en allemand, en français ou en anglais. Les résumés, donnés dans les trois langues, permettront à ceux...

  16. Studies of solids at low temperatures. Final scientific report. [Fluoro-tungsten bronzes

    Energy Technology Data Exchange (ETDEWEB)

    Moulton, W.G.

    1970-10-01

    One of the primary objectives of this research has been to investigate the magnetic properties of materials which are likely to exhibit unusual magnetic transitions which may prove to be useful for microwave or switching devices. Experimental techniques used in this research included nuclear magnetic resonance, magnetic susceptibility measurements, optical spectroscopy, and electron spin resonance. A second goal was to develop relationships between magnetic properties and chemical bonding so that eventually magnetic properties could be predicted from the structure of a compound. Another objective of this research was to investigate the possibility of superconductivity in the fluoro-tungsten bronzes. Forty-two of these compounds were synthesized and all were found to have superconducting transition temperatures between one and one half degrees and five degrees kelvin. Relationships between the critical fields and the transition temperature and the composition have been established.

  17. Performance evaluation of grid-enabled registration algorithms using bronze-standards

    CERN Document Server

    Glatard, T; Montagnat, J

    2006-01-01

    Evaluating registration algorithms is difficult due to the lack of gold standard in most clinical procedures. The bronze standard is a real-data based statistical method providing an alternative registration reference through a computationally intensive image database registration procedure. We propose in this paper an efficient implementation of this method through a grid-interfaced workflow enactor enabling the concurrent processing of hundreds of image registrations in a couple of hours only. The performances of two different grid infrastructures were compared. We computed the accuracy of 4 different rigid registration algorithms on longitudinal MRI images of brain tumors. Results showed an average subvoxel accuracy of 0.4 mm and 0.15 degrees in rotation.

  18. Strengthening Mechanisms in NiAl Bronze: Hot Deformation by Rolling and Friction-Stir Processing

    Science.gov (United States)

    Menon, Sarath K.; Pierce, Frank A.; Rosemark, Brian P.; Oh-Ishi, Keiichiro; Swaminathan, Srinivasan; McNelley, Terry R.

    2012-10-01

    Microstructures produced by isothermal hot rolling of a NiAl bronze material were evaluated by quantitative microscopy methods and parameters describing the contributions of precipitate dispersions, grain size, solute content, and dislocation density to the yield strengths of the individual constituents of microstructure were determined. Models for the strengths of the individual constituents were combined to predict the temperature dependence of the yield strength as a function of hot rolling temperature, and the prediction was found to be in good agreement with measured yield strengths. The models were applied to microstructures in a stir zone produced by multipass friction-stir processing (FSP) and, again, found to predict measured yield strengths with high accuracy. Such models may aid in assessing the role of microstructure gradients produced during FSP and other processes.

  19. Silvery hair with bronze-tan in a child: A case of Elejalde disease

    Directory of Open Access Journals (Sweden)

    Inamadar Arun

    2007-01-01

    Full Text Available A 5-year-old boy was admitted for severe neurological impairment including hypotonia and loss of consciousness without preceding febrile illness. On examination, he had silver colored hair and bronze-tan over photo-exposed body parts. He was born of consanguineous parents and three of his elder siblings, who died in early childhood, had similar colored hair. Complete blood count and serum immunoglobulin levels were within normal limits. Peripheral blood smear did not show any cytoplasmic granules in neutrophils. Cerebro-spinal fluid examination did not reveal any abnormality. Light microscopic examination of the hair revealed irregular clumping of the melanin throughout the shafts. The patient died on the second day following admission. A clinical diagnosis of Elejalde disease was made. The clinical and genetic overlapping of the three silvery-hair syndromes has been discussed.

  20. Influence of heat treatment on tribological behaviors of novel wrought aluminum bronze

    Institute of Scientific and Technical Information of China (English)

    张卫文; 倪东惠; 夏伟; 邱诚; 陈维平

    2002-01-01

    Influence of heat treatment on mechanica l properties and tribologica l behaviors of Ti and B modified wrought aluminum bronze were studied. The res ults show that different strength and plasticity combination of the alloy after solu tion treatment can be obtained by adjusting the ageing temperature. When aged at 45 0 ℃, the tensile strength σb, yield strength σ0.2, elongatio n δ and hardness of the alloy are 1 050 MPa, 780 MPa, 4.5%, HB282, respectively. When aged at 650 ℃, those of the alloy are 905 MPa, 600 MPa, 12%, HB232, respectively. Under boundary l ubri cation condition with pressure above 22.2 MPa, alloy with low temperature agei ng has the best wear property. However, under the condition involving impact or sh ock loading, alloy with high temperature ageing is preferable. If the load is no t heavy, the alloy under extrusion state is favorable for wear-resisting parts.

  1. A mineralogical study of Late Bronze Age ceramics from Palatca (Transylvania, Romania

    Directory of Open Access Journals (Sweden)

    Lucretia Ghergari

    2012-01-01

    Full Text Available Our paper studies the mineralogical and petrographical characteristics of 28 ceramic fragments that were excavated in the village of Palatca, Transylvania (Romania. Optical microscopy, X-Ray powder diffraction (XRD, scanning electron microscopy (SEM, grain size analyses, and porosity measurements were used to investigate the samples. Our objective was to describe or reconstruct the corresponding products and to elucidate the manufacturing process, the firing techniques, and the transformation pathways. Based on our results, we conclude that the Late Bronze Age ceramics (1600-1300 BC were produced from clay and temper material such as river sand and ceramoclasts. It has been modeled by hand and fired between 800 and 950°C. For most samples, we can narrow the temperature range to 850-900°C. We interpret the data further from a geoarchaeological point of view with respect to the historical evolution of the local culture.

  2. Corrosion atmosphérique des bronzes et Spectroscopie Mössbauer.

    OpenAIRE

    Sougrati, Moulay Tahar

    2008-01-01

    Afin d'améliorer la compréhension de la corrosion atmosphérique des bronzes, nous avons mis en oeuvre : - La caractérisation des composés d'étain, susceptibles d'être formés en corrosion atmosphérique, par une approche multi-analytique, la spectroscopie Mössbauer joue un rôle central (analyse sélective et quantitative). Les paramètres hyperfins et les facteurs Lamb-Mössbauer de plusieurs oxydes, sulfates et chlorures d'étain ont été déterminés. Les facteurs f sont dispersés et dépendants de t...

  3. Analysis of neutron diffraction profiles in bronze archaeological statuettes produced by solid lost wax casting

    Science.gov (United States)

    Giuliani, Alessandra; Fiori, Fabrizio; Gysens, Jacqueline; Manescu, Adrian; Rustichelli, Franco

    2008-03-01

    In the framework of a research aiming to assess the suitability of neutron/x-ray non-destructive techniques for the characterization of archaeological objects, two bronze items were studied by neutron diffraction. The origins of two small statues are, respectively, Egyptian (XXI-XXX Dynasties, c1070-343 B.C.) and Etruscan (IV-III centuries B.C.), belonging to a private collection. By hard x-ray diffraction we previously verified that both statuettes have a coarse microstructure (big grains). From historical considerations we believe that both items were produced by solid lost wax processes of casting. This processing technique does not completely justify the presence of microstrains; as a consequence, due to unexpected neutron diffraction peak broadening, a non-uniform Sn wt% is suspected. In the present work we discuss this deduction by means of Rietveld analysis of the neutron diffraction profiles.

  4. Combining X-ray based methods to study the protohistoric bronze technology in Western Iberia

    Energy Technology Data Exchange (ETDEWEB)

    Valério, P., E-mail: pvalerio@ctn.ist.utl.pt [Centro de Ciências e Tecnologias Nucleares (C2TN), Instituto Superior Técnico, Universidade de Lisboa, Campus Tecnológico e Nuclear, Estrada Nacional 10 (km 139,7), 2695-066 Bobadela LRS (Portugal); Silva, R.J.C., E-mail: rjcs@fct.unl.pt [CENIMAT/I3N, Departamento de Ciência dos Materiais, Faculdade de Ciências e Tecnologia, FCT, Universidade Nova de Lisboa, 2829-516 Monte de Caparica (Portugal); Soares, A.M.M., E-mail: amsoares@ctn.ist.utl.pt [Centro de Ciências e Tecnologias Nucleares (C2TN), Instituto Superior Técnico, Universidade de Lisboa, Campus Tecnológico e Nuclear, Estrada Nacional 10 (km 139,7), 2695-066 Bobadela LRS (Portugal); Araújo, M.F., E-mail: faraujo@ctn.ist.utl.pt [Centro de Ciências e Tecnologias Nucleares (C2TN), Instituto Superior Técnico, Universidade de Lisboa, Campus Tecnológico e Nuclear, Estrada Nacional 10 (km 139,7), 2695-066 Bobadela LRS (Portugal); Gonçalves, A.P., E-mail: apg@ctn.ist.utl.pt [Centro de Ciências e Tecnologias Nucleares (C2TN), Instituto Superior Técnico, Universidade de Lisboa, Campus Tecnológico e Nuclear, Estrada Nacional 10 (km 139,7), 2695-066 Bobadela LRS (Portugal); Soares, R.M., E-mail: ruigusmao@hotmail.com [UNIARQ, Centro de Arqueologia da Universidade de Lisboa, Faculdade de Letras, Alameda da Universidade, 1600-214 Lisboa (Portugal)

    2015-09-01

    The Phoenician arrival at Iberian coastal regions had an actual influence on indigenous technology. A collection of coeval metallurgical remains and artefacts was studied by EDXRF, micro-EDXRF, SEM–EDS and XRD, to identify certain features of the production and utilisation of metal in protohistoric Western Iberia. The composition of artefacts indicates a prevalence of Cu–Sn alloys with low content of impurities (Pb, As, Sb and Fe) during Late Bronze and Early Iron Ages, while the composition of slags points to a smaller loss of copper in Phoenician smelting operations. Moreover, the amount of iron impurities in metal proved to be a helpful discriminator between indigenous and Phoenician-based metallurgies, showing that later alloys have higher amounts of iron. Besides, the indigenous alloys have higher tin contents that can probably be explained by the easier access to metal sources of local communities.

  5. Towards mineralogical and geochemical reference groups for some Bronze Age ceramics 
from Transylvania (Romania

    Directory of Open Access Journals (Sweden)

    Volker Hoeck

    2009-09-01

    Full Text Available Based on their chemical composition ceramic shards from three Bronze Age sites in Transylvania, i.e., Copăceni, Derşida and Palatca respectively, were distinguished by major, trace, and RE elements. Within the Copăceni samples, two subgroups (A and B showing different chemistry and mineralogy were additionally separated out. The link between chemistry and mineralogy showed clearly the important contribution of the temper to the overall chemistry of the ceramic shards. In turn, the chemistry facilitated the provenance study of the raw materials, which were collected in the vicinity of the sites. In combination with the mineralogy of the ceramics, the chemical analyses can serve as a basis for a geochemical reference set used by further studies.

  6. The inhibition effect and mechanism of L-cysteine on the corrosion of bronze covered with a CuCl patina

    International Nuclear Information System (INIS)

    Highlights: • CuCl patina was synthesized on bronze electrodes with electrochemical method. • L-cysteine was used as a green inhibitor for bronze covered with CuCl patina. • The inhibition efficiency reached above 90%. • The inhibition mechanism of L-cysteine on CuCl patina was investigated. - Abstract: CuCl patina was synthesized on bronze electrodes with electrochemical method. The inhibition effect and mechanism of L-cysteine (Cys) on bronze covered with CuCl patina have been studied with electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS) techniques. The EIS results show that Cys stabilized the CuCl patina to a great extent. The hydrolysis reaction of CuCl was inhibited effectively and an inhibition efficiency of over 90% was achieved. The XPS analyses indicate that the chemisorption of Cys molecules on CuCl surface occurred through sulfur atom in thiol and nitrogen atom in amino group

  7. Biological affinities and adaptations of Bronze Age Bactrians: IV. A craniometric investigation of Bactrian origins.

    Science.gov (United States)

    Hemphill, B E

    1999-02-01

    Discovery of a previously unknown Bronze Age civilization (Oxus civilization) centered on the oases of Central Asia revealed the presence of large, preplanned urban centers immediately above sterile soil. Given the absence of local antecedents, the sudden appearance and proliferation of these Oxus civilization urban centers in the oases of Bactria and Margiana immediately raised the issue of where the inhabitants of these urban centers came from. Three hypotheses have been offered by archaeologists to account for the origins of Oxus civilization populations. These include the early influence model, the late colonization model, and the trichotomy model. Eleven craniometric variables from 12 Aeneolithic and Bronze Age samples, encompassing 657 adults from Central Asia, Iran, and the Indus Valley, are compared to test which if any of these hypotheses are supported by the pattern of phenetic affinities possessed by the Oxus civilization inhabitants of the north Bactrian oasis. Craniometric differences between samples are compared with Mahalanobis generalized distance (d2), and patterns of phenetic affinity are assessed with two types of cluster analysis (WPGMA, neighbor-joining method), multidimensional scaling, and principal coordinates analysis. Results of this analysis provide no support for either the late colonization model or the trichotomy model but do offer some support for the early influence model. Nevertheless, it is clear that the early influence model fails to account for a shift in interregional contacts, perhaps from western China to the north around 2000 BC, that appears to have played a major role in the origins of the Oxus civilization inhabitants of the north Bactrian oasis. PMID:9988380

  8. Comparison of LIBS and {mu}-XRF measurements on bronze alloys for monitoring plasma effects

    Energy Technology Data Exchange (ETDEWEB)

    Alberghina, M F; Barraco, R; Brai, M; Schillaci, T; Tranchina, L, E-mail: tschillaci@unipa.it [Dipartimento di Fisica e Tecnologie Relative, Universita di Palermo, Viale delle Scienze Ed. 18, 90128 Palermo (Italy)

    2011-01-01

    The laser-induced breakdown spectroscopy (LIBS) technique is often used as atomic spectroscopic technique for elemental analysis of materials. However, it presents some drawbacks that make an accurate quantitative analysis difficult. Since the plasma properties, such as spatial inhomogeneity and plume stoichiometry strongly depend on the experimental conditions, the measurements are less reproducible. In order to evaluate the measurement fluctuations, we propose to use the more established micro X-Ray fluorescence ({mu}-XRF) technique for validating LIBS data. In particular, the quantitative data, obtained by varying the laser fluence, the shot numbers and the temporal acquisition parameters, were compared with those obtained by {mu}-XRF on laboratory made samples of binary, ternary and quaternary bronze alloys. For LIBS measurements a mobile double pulse laser instrument equipped with an high resolution Echelle type monochromator coupled to an intensified CCD camera was used. {mu}-XRF analyses were performed with a portable instrument that uses a micro collimated X-Ray beam and it is equipped with an high resolution detector. The LIBS results show a strong dependence both on the instrumental set up and the chemical-physical properties of the sample. With our findings we could identify the most suitable parameters to be used in the investigation of the different bronze alloys. The possibility to carry out a quantitative analysis by using the LIBS technique was checked through the comparison with related {mu}-XRF data. In particular in this paper we identified a set of reliable LIBS parameters for the quantitative analysis of copper, tin and zinc. Further analyses will be necessary to reach this goal also for the minor constituents as lead.

  9. Late Bronze Age in Alcáçova de Santarém (Portugal

    Directory of Open Access Journals (Sweden)

    Arruda, Ana Margarida

    2015-06-01

    Full Text Available The field work that took place in the restaurant area in Jardim das Portas do Sol (Alcáçova de Santarém recovered well-preserved archaeological layers dated to the Late Bronze Age, lying directly underneath the Iron Age phase. The excavation made it possible to collect an important set of ceramics that incorporate printed and incised decoration, which can be easily decoration related to the Cogotas 1 cultural background. Burnished decorations, with grooves on the inner surface and outer strips, are less common. The formal repertoire does not deviate from what is known about the Late Bronze Age in central and southern Iberian Peninsula. The data allow us to propose a chronology centered in the early 1st millennium BCE for this occupation.Durante los trabajos de campo, realizados en el área del restaurante del Jardim das Portas do Sol, se documentaron, por primera vez en Alcáçova de Santarém, niveles conservados del final de la Edad del Bronce, inmediatamente infrapuestos a los de la Edad del Hierro. Su excavación permitió recoger un conjunto de materiales cerámicos que incorpora varios fragmentos decorados por impresión e incisión, que pueden ser fácilmente relacionados con el universo cultural de Cogotas 1. Las decoraciones bruñidas con surcos en la superficie interna y con franjas al exterior son mucho menos frecuentes. El repertorio formal no difiere del conocido para el Bronce Final del centro y sur de la Península Ibérica. Los datos permiten proponer una cronologia del inicio del 1 milenio a.n.e. (siglo IX para esta ocupación.

  10. Bronze age cosmology and rock art images. Solar ships, deer and charts

    Science.gov (United States)

    Dimitriadis, G.

    Bronze Age societies were technologically complex. The impressive production of metal artefacts embodies clearly their astronomical culture and cosmological viewpoint. Same ascertainment is valid also for rock art. In fact, around the European landscape were discovered several cliffs engraved with solar ships, deer and charts. How one could be interpret them? Which is the hidden mentality? From the end of 3rd millennium-early 2nd millennium B. C. deep technological transformations are made by metals. New inventions such metal extraction for weapon production, horse pulling chariot used for war and the bull pulling one used for trade may shorten the culture and material distances between Central Europe and South Mediterranean area. Indeed, taphonomic studies indicate a specific modification of the human body mortuary traditional disposition (orientated to significant astronomical targets) below a substantial transformation of mortuary apparatus with spot evidence of weapons (halberds, swords, knifes) and ornaments (double spiral, lunar shape pectorals). The famous Trundhold Solar chart, the 2nd millennium terracotta chart form Dupljaja, the solar boats petroglyph in Bohusland and the horse rider carved on Philippi's cliffs were conceived by the same mentality: communion with the divinity. Culture expressions as communicate manifestation attested in rock art were produced by the same mentality presented in Bronze Age art-crafts such as, 1. Culture epidemiologic patterns dispersion took place through out iconographic motives, and, 2. Animals can play a double face function inside an analogical-mythological system: a. animal-reflex; b. animal-agent. The question is: Could such petroglyphs help us to "read" archaeoastronomical properly in an archaeological site?

  11. Archaeological fieldwork in the Bronze Age site of Cerro de la Encina (Monachil, Granada

    Directory of Open Access Journals (Sweden)

    Aranda Jiménez, Gonzalo

    2005-06-01

    Full Text Available New archaeological fieldwork has been carried out from November 2003 to May 2004 in the Bronze Age site of Cerro de la Encina, due to the interest of the regional government of Andalusia in displaying the settlement for visitors. The aim of this fieldwork has been the systematic excavation of a large settlement area partially known thanks to the excavations developed at the beginning of 1980s. A first toccupation period belonging to the Argaric Culture has been documented, highlighting specially the funerary ritual characterized by individual inhumations located below dwellings. After a gap in the occupation of the settlement a new social group belonging to the Late Bronze Age Culture of Southeast of Spain inhabits the Cerro de la Encina.

    El interés de la Consejería de Cultura de la Junta de Andalucía por la musealización del yacimiento del Cerro de la Encina ha motivado el desarrollo de nuevas investigaciones arqueológicas cuya primera fase se ha desarrollado entre Noviembre de 2003 y Mayo de 2004. Los trabajos han consistido en la excavación sistemática de un área de poblado de grandes dimensiones parcialmente conocida por las investigaciones realizadas a principios de los años 80. Los resultados han sido del máximo interés documentándose un primer momento de ocupación perteneciente a la Cultura de El Argar en el que destaca su espectacular registro funerario integrado dentro de las áreas de habitación. Tras un periodo de abandono del yacimiento se produce una nueva ocupación correspondiente a una comunidad del Bronce Final del Sureste.

  12. Effect of additions of Cr, Mo, W and/or Si on the technological properties of aluminum-iron-nickel bronze

    Directory of Open Access Journals (Sweden)

    B. P. Pisarek

    2011-07-01

    Full Text Available The aim of this study was to investigate the effect of additives of Cr, Mo, W and / or Si CuAl10Fe5Ni5 bronze, cast into sand moulds, the bronze technological properties such as: porosity, volumetric shrinkage Sv, linear shrinkage s and prone hot to cracking. The study relate to the newly developed grades aluminum-iron-nickel bronze, with additions of Cr, Mo, W and/or Si. In order to determine the technological properties of the test castings were made in the form of moulding sand, which made the mould cavities designed patterns. To evaluate the porosity and volumetric shrinkage was used for digital image analysis method. Volumetric shrinkage was determined using developed, the new method, the surface shrinkage Svp designation, and then converting it to the volumetric shrinkage, using prepared relation Sv=f(Djs*Svp. It was found that made the bronze alloy additions to reduce the size of pores surface area of gas and shrinkage in the test bronze. The probability of microporosity with an area of 0.002560÷0.120647 mm2 can be described by gamma distribution. Changing the chemical composition of the grades tested bronze strongly alter the first volumetric shrinkage Sv, and less to change the linear shrinkage s. The increase in gas porosity and shrink in bronze reduces the volumetric shrinkage and linear. The addition of Cr, Mo, W and/or Si to the bronze CuAl10Fe5Ni5 does not change its prone to hot cracking.

  13. Corrosion stability of different bronzes in simulsted urban rain: Korozijska stabilnost različnih bronov v umetnem kislem dežju:

    OpenAIRE

    Kosec, Tadeja; Kuhar, Viljem; Legat, Andraž; Švara Fabjan, Erika

    2011-01-01

    Copper and high copper alloys tend to passivate in humid air. In clean humid air, cuprite slowly transforms to black tenorite. If atmosphere contains aggressive species, acid rain might effect the formation of different corrosion products. The patina that forms upon exposure to urban acid rain also depends of the composition of the base alloy. In the present study three different alloys were investigated: leaded bronze, usually used for sculptures, unleaded bronze as an alloy without an impac...

  14. Les techniques de soudage de la grande statuaire antique en bronze: étude des paramètres thermiques et chimiques contrôlant le soudage par fusion au bronze liquide

    OpenAIRE

    Azéma, Aurélia

    2013-01-01

    Ces travaux s'inscrivent dans une recherche interdisciplinaire qui concerne l'évolution de l'ensemble des techniques de la grande statuaire antique en bronze (de la 2nd moitié du 6 siècle avant J.C. au 5e siècle après J.C.). L'objectif de la thèse est de contribuer à la compréhension du procédé de soudage par fusion au bronze liquide, en mettant en œuvre une double approche : étude de soudures antiques et essais expérimentaux en laboratoire. Les statues à étudier ont été choisies parmi les œu...

  15. Dynamic secondary ion mass spectrometry and X-ray photoelectron spectroscopy on artistic bronze and copper artificial patinas

    International Nuclear Information System (INIS)

    To prevent the natural processes of decay and to develop and improve the treatments of conservation and restoration of artistic bronzes meaning statues and sculptures, it is important understanding the patination processes and the knowledge of artificially corroded surfaces. Chemical and physical characterization of artificial patinas obtained on artistic bronzes and coppers by using the 19th century Western traditional patination techniques and recipes by means of SEM-EDS, light microscopy and ATR/FT-IR has been done in previous studies [I.Z. Balta, L. Robbiola, Characterization of artificial black patinas on artistic cast bronze and pure copper by using SEM-EDS and light microscopy, in: Proceedings of the 13th European Microscopy Congress, 22-27 August 2004, Antwerp, Belgium, EMC 2004 CD-Rom Conference Preprints; I.Z. Balta, L. Robbiola, Traditional artificial artistic bronze and copper patinas-an investigation by SEM-EDS and ATR/FT-IR, in: Proceedings of the 8th International Conference on Non Destructive Investigations and Microanalysis for the Diagnostics and Conservation of the Cultural and Environmental Heritage, 15-19 May 2005, Lecce, Italy, ART'05 CD-Rom Conference Preprints]. Differences in morphology (structure, thickness, porosity, adherence, compactity, uniformity, homogeneity) and also in composition, on both artistic cast bronze and pure copper patinas, were clearly evidenced. Further in-depth investigation is required to be carried out in order to better understand the patinas mechanisms of formation and the layers kinetics of growth. The elemental and chemical analysis, either on a surface monolayer or in a depth profile, by using the Secondary Ion Mass Spectrometry (SIMS) and X-ray Photoelectron Spectroscopy (XPS) techniques, can provide this kind of information, unique at trace-level sensitivity. SIMS has proved to be a suitable analytical technique for analyzing small amounts of material with high atomic sensitivity (ppm or even ppb) and high

  16. Dynamic secondary ion mass spectrometry and X-ray photoelectron spectroscopy on artistic bronze and copper artificial patinas

    Science.gov (United States)

    Balta, I. Z.; Pederzoli, S.; Iacob, E.; Bersani, M.

    2009-04-01

    To prevent the natural processes of decay and to develop and improve the treatments of conservation and restoration of artistic bronzes meaning statues and sculptures, it is important understanding the patination processes and the knowledge of artificially corroded surfaces. Chemical and physical characterization of artificial patinas obtained on artistic bronzes and coppers by using the 19th century Western traditional patination techniques and recipes by means of SEM-EDS, light microscopy and ATR/FT-IR has been done in previous studies [I.Z. Balta, L. Robbiola, Characterization of artificial black patinas on artistic cast bronze and pure copper by using SEM-EDS and light microscopy, in: Proceedings of the 13th European Microscopy Congress, 22-27 August 2004, Antwerp, Belgium, EMC 2004 CD-Rom Conference Preprints; I.Z. Balta, L. Robbiola, Traditional artificial artistic bronze and copper patinas—an investigation by SEM-EDS and ATR/FT-IR, in: Proceedings of the 8th International Conference on Non Destructive Investigations and Microanalysis for the Diagnostics and Conservation of the Cultural and Environmental Heritage, 15-19 May 2005, Lecce, Italy, ART'05 CD-Rom Conference Preprints]. Differences in morphology (structure, thickness, porosity, adherence, compactity, uniformity, homogeneity) and also in composition, on both artistic cast bronze and pure copper patinas, were clearly evidenced. Further in-depth investigation is required to be carried out in order to better understand the patinas mechanisms of formation and the layers kinetics of growth. The elemental and chemical analysis, either on a surface monolayer or in a depth profile, by using the Secondary Ion Mass Spectrometry (SIMS) and X-ray Photoelectron Spectroscopy (XPS) techniques, can provide this kind of information, unique at trace-level sensitivity. SIMS has proved to be a suitable analytical technique for analyzing small amounts of material with high atomic sensitivity (ppm or even ppb) and high

  17. Magnetization and Inter-Filament Contact in HEP and ITER Bronze-Route Nb(3)Sn Wires

    CERN Document Server

    Bordini, B; Devred, A; Richter, D; Bessette, D; Jewell, M; Bottura, L

    2011-01-01

    Magnetization measurements are relevant tests for the characterization of superconductors. Practically they are the only measurements that allow estimating the critical current density at low fields of low temperature superconductors, the effective filament size and the hysteresis losses. For this purpose CERN, in collaboration with the University of Geneva, has carried out magnetization measurements on five types of Nb(3)Sn wires: three bronze route strands used in the ITER project; one Powder In Tube (PIT) and one Internal Tin (IT) wires used for developing next generation accelerator magnets. The field dependent magnetization has been determined using three setups: a Vibrating Sample Magnetometer (VSM), a Superconducting Quantum Interference Device (SQUID) and a special system used for the production control of LHC strands. Samples of different lengths have been tested to check the different coupling between the filaments. Unexpectedly, it was found that the magnetization of the tested bronze wires was str...

  18. Magnetization and Inter-Filament Contact in HEP and ITER Bronze-Route Nb3Sn Wires

    CERN Document Server

    Bordini, B; Bottura, L; Devred, A; Jewell, M; Richter, D; Senatore, C

    2011-01-01

    Magnetization measurements are relevant tests for the characterization of superconductors. Practically they are the only measurements that allow estimating the critical current density at low fields of low temperature superconductors, the effective filament size and the hysteresis losses. For this purpose CERN, in collaboration with the University of Geneva, has carried out magnetization measurements on five types of Nb3Sn wires: three bronze route strands used in the ITER project; one Powder In Tube (PIT) and one Internal Tin (IT) wires used for developing next generation accelerator magnets. The field dependent magnetization has been determined using three set-ups: a Vibrating Sample Magnetometer (VSM), a Superconducting Quantum Interference Device (SQUID) and a special system used for the production control of LHC strands. Samples of different lengths have been tested to check the different coupling between the filaments. Unexpectedly, it was found that the magnetization of the tested bronze wires was stro...

  19. Oxygen isotope in archaeological bioapatites from India: Implications to climate change and decline of Bronze Age Harappan civilization

    OpenAIRE

    Anindya Sarkar; Arati Deshpande Mukherjee; Bera, M. K.; Das, B.; Navin Juyal; Morthekai, P.; Deshpande, R. D.; Shinde, V. S.; L. S. Rao

    2016-01-01

    The antiquity and decline of the Bronze Age Harappan civilization in the Indus-Ghaggar-Hakra river valleys is an enigma in archaeology. Weakening of the monsoon after ~5 ka BP (and droughts throughout the Asia) is a strong contender for the Harappan collapse, although controversy exists about the synchroneity of climate change and collapse of civilization. One reason for this controversy is lack of a continuous record of cultural levels and palaeomonsoon change in close proximity. We report a...

  20. MEASURING AND MODELING OF THE MECHANICAL PROPERTIES OF COMPOSITE BEARING PAD MADE OF PLASTIC MATRIX AND FINE BRONZE ELASTIC SPRINGS

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The viscoelastic properties of the normal PTFE plastic and strengthened PTFE plastic for bearing pad are measured. The mechanical properties of the composite material for bearing pad, which is made of the aforementioned plastics as matrix reinforced by fine bronze elastic springs, are modeled and relaxation modulus of the material are presented. The difference between these two kinds of PTFE is studied. The results show that the complex modulus of PTFE plastics for bearing pad is higher than that of normal PTFE plastics.

  1. The Metallurgy of the Sicilian Final Bronze Age/Early Iron Age necropolis of Madonna del Piano (Catania, Sicily)

    OpenAIRE

    Giumlia-Mair, Alessandra; Albanese Procelli, Rosa Maria; Lo Schiavo, Fulvia

    2010-01-01

    This paper presents the analysis results of the copper- based finds, from the important Sicilian necropolis of Madonna del Piano, near Grammichele (Catania), dated between the local Final Bronze Age 2 and the Early Iron Age IA. 122 copper-based finds from the 273 graves (1970-71) of the large cemetery have been analysed. The sampled objects belong to different classes, there are for instance weapons of offence and defence, such as swords and greaves, small decorative objects for personal use,...

  2. A theoretical and experimental study on the pulsed laser dressing of bronze-bonded diamond grinding wheels

    Science.gov (United States)

    Deng, H.; Chen, G. Y.; Zhou, C.; Zhou, X. C.; He, J.; Zhang, Y.

    2014-09-01

    A series of theoretical analyses and experimental investigations were performed to examine a pulsed fiber-laser tangential profiling and radial sharpening technique for bronze-bonded diamond grinding wheels. The mechanisms for the pulsed laser tangential profiling and radial sharpening of grinding wheels were theoretically analyzed, and the four key processing parameters that determine the quality, accuracy, and efficiency of pulsed laser dressing, namely, the laser power density, laser spot overlap ratio, laser scanning track line overlap ratio, and number of laser scanning cycles, were proposed. Further, by utilizing cylindrical bronze wheels (without diamond grains) and bronze-bonded diamond grinding wheels as the experimental subjects, the effects of these four processing parameters on the removal efficiency and the surface smoothness of the bond material after pulsed laser ablation, as well as the effects on the contour accuracy of the grinding wheels, the protrusion height of the diamond grains, the sharpness of the grain cutting edges, and the graphitization degree of the diamond grains after pulsed laser dressing, were explored. The optimal values of the four key processing parameters were identified.

  3. Multipeak self-biased magnetoelectric coupling characteristics in four-phase Metglas/Terfenol-D/Be-bronze/PMN-PT structure

    Science.gov (United States)

    Huang, Dongyan; Lu, Caijiang; Bing, Han

    2015-04-01

    This letter develops a self-biased magnetoelectric (ME) structure Metglas/Terfenol-D/Be-bronze/PMN-PT (MTBP) consisting of a magnetization-graded Metglas/Terfenol-D layer, a elastic Be-bronze plate, and a piezoelectric 0.67Pb(Mg1/3Nb2/3)O3-0.33PbTiO3 (PMN-PT) plate. By using the magnetization-graded Metglas/Terfenol-D layer and the elastic Be-bronze plate, multi-peak self-biased ME responses are obtained in MTBP structure. The experimental results show that the MTBP structure with two layers of Metglas foil has maximum zero-biased ME voltage coefficient (MEVC). As frequency increases from 0.5 to 90 kHz, eleven large peaks of MEVC with magnitudes of 0.75-33 V/(cm Oe) are observed at zero-biased magnetic field. The results demonstrate that the proposed multi-peak self-biased ME structure may be useful for multifunctional devices such as multi-frequency energy harvesters or low-frequency ac magnetic field sensors.

  4. Multipeak self-biased magnetoelectric coupling characteristics in four-phase Metglas/Terfenol-D/Be-bronze/PMN-PT structure

    Directory of Open Access Journals (Sweden)

    Dongyan Huang

    2015-04-01

    Full Text Available This letter develops a self-biased magnetoelectric (ME structure Metglas/Terfenol-D/Be-bronze/PMN-PT (MTBP consisting of a magnetization-graded Metglas/Terfenol-D layer, a elastic Be-bronze plate, and a piezoelectric 0.67Pb(Mg1/3Nb2/3O3-0.33PbTiO3 (PMN-PT plate. By using the magnetization-graded Metglas/Terfenol-D layer and the elastic Be-bronze plate, multi-peak self-biased ME responses are obtained in MTBP structure. The experimental results show that the MTBP structure with two layers of Metglas foil has maximum zero-biased ME voltage coefficient (MEVC. As frequency increases from 0.5 to 90 kHz, eleven large peaks of MEVC with magnitudes of 0.75-33 V/(cm Oe are observed at zero-biased magnetic field. The results demonstrate that the proposed multi-peak self-biased ME structure may be useful for multifunctional devices such as multi-frequency energy harvesters or low-frequency ac magnetic field sensors.

  5. Recent activity in development of bronze-processed Nb3Sn Wires. Improvements in strand performance and cabling

    International Nuclear Information System (INIS)

    Bronze-processed Nb3Sn wires have been used in practical applications of high-field magnets and large-scale magnets. Since the 1980s, Furukawa Electric Co., Ltd. has been developing and manufacturing many high-performance bronze-processed Nb3Sn wires. This paper describes our recent activity in development of the bronze-processed Nb3Sn wires. The non-Cu critical current density of the ITER-type strand was 1,150 A/mm2 at 12 T and 4.2 K, which is 1.8 times higher than that of the ITER-CS model coil 15 years ago. High-strength Nb3Sn wires reinforced with Cu-Ni/Nb-Ti or Cu-Nb composites have been successfully fabricated for high-field magnets. Enhancements of the superconducting properties resulting from pre-bending effects were demonstrated with Cu-Nb reinforced Nb3Sn wires. Mass production of practical cables for JT-60SA CS coils have been completed in exact accordance with the specifications. In addition, experimental manufacture of ITER-CSJA1 cables was properly carried out. Furthermore, a novel type of aluminum-alloy jacketed Nb3Sn conductor has been developed using the friction stir welding (FSW) technique. (author)

  6. Bronze Age pottery from the Aeolian Islands: definition of Temper Compositional Reference Units by an integrated mineralogical and microchemical approach

    Science.gov (United States)

    Brunelli, D.; Levi, S. T.; Fragnoli, P.; Renzulli, A.; Santi, P.; Paganelli, E.; Martinelli, M. C.

    2013-12-01

    An integrated microchemical-petrographic approach is here proposed to discriminate the provenance of archaeological pottery artefacts from distinct production centres. Our study focuses on a statistically significant sampling ( n=186) of volcanic temper-bearing potteries representative of the manufacturing and dispersion among the islands of the Aeolian Archipelago during the Bronze Age. The widespread establishment of new settlements and the abundant recovery of Aeolian-made ceramic in southern Italy attest for the increased vitality of the Archipelago during the Capo Graziano culture (Early Bronze Age-Middle Bronze Age 2; 2300-1430 BC). Potteries from three of the main known ancient communities (Lipari, Filicudi and Stromboli) have been studied integrating old collections and newly excavated material. Volcanic tempers have been first investigated through multivariate analyses of relative abundances of mineral and rock clasts along with petrographic characters. In addition, we performed in-situ mineral chemistry microanalyses by Electron Microprobe and Laser Ablation—Inductively Coupled Plasma Mass Spectrometry to assess major and trace element composition of the most common mineral phases. Four Temper Compositional Reference Units have been recognised based on compositional trends. Two units (AI and AX) are unequivocally distinct by their peculiar trace element enrichment and petrographic composition; they mostly contain samples from the sites of Lipari and Stromboli, respectively. Units AIV and AVIII, restricted to the sites of Filicudi and Stromboli, show distinct petrographic characters but overlapped geochemical fingerprints.

  7. Isotopic Evidence For The Primary Production, Provenance And Trade Of Late Bronze Age Glass In The Mediterranean.

    Science.gov (United States)

    Henderson, J.; Evans, J.; Nikita, K.

    The earliest known man made glass comes from Mesopotamia and dates to the 23rd century BC. By the 16th century BC the first glass vessels appear in Mesopotamia, but the earliest evidence for the fusion of glass from raw materials has been found at the 13th century BC Egyptian site of Qantir. Chemical analyses of this elite Late Bronze Age material have produced compositional distinctions between glasses found in Mesopotamia and Egypt. It is however debatable whether trace element concentrations provide a (geological) provenance for the glasses. By using neodymium and strontium isotopes to fingerprint well-dated chemically analysed 15th to 11th century BC glass samples, we show that independent primary production probably occurred in both Egypt and Mesopotamia in the 14th century BC, and that both of these areas exported glass to Greece. We also discuss the technological implications for glass manufacture and colouring that these new data provide. The results add significant new scientific evidence for glass trade between Late Bronze Age palatial societies. Moreover, it is the first time that this methodology has been used to investigate Bronze Age glass.

  8. Bronze Age metal artefacts found on Cyprus - metal from Anatolia and the Western Mediterranean

    Directory of Open Access Journals (Sweden)

    Stos-Gale, Zofia A.

    2010-12-01

    Full Text Available Hundreds of Bronze Age metal artefacts excavated on archaeological sites in Cyprus have been analysed for their lead isotope and elemental composition in the Isotrace Laboratory, University of Oxford, in the years 1982-2002. In parallel, but in particular after 1995, hundreds of samples of minerals and slags collected from the mines and smelting sites around the Troodos Mountains were also analysed. Most of the results were published in various articles over the years, but the interpretation of some of the lead isotope data needs a current revision in view of new research conducted in Spain, Sardinia and southern France. It has been known that the lead isotope data for metal artefacts from the Cypriot Bronze Age sites shows that not all of the copper is consistent with origin from the Cypriot ores. In addition, the lead and silver artefacts found there must have been imported, because there are no lead or silver ores on Cyprus. The re-evaluation of the data shows that about 11 % of the analysed metal artefacts are consistent with the origin from the deposits in the Aegean and Turkey, while about 14 % with sources in the Western Mediterranean. This paper discusses in detail the current interpretation of the research into the sources of imported metal found in the Bronze Age context on Cyprus.

    Cientos de objetos de metal de la Edad del Bronce excavados en yacimientos de Chipre han sido analizados para conocer su composición elemental y sus isótopos de plomo en el Isotrace Laboratory de la Universidad de Oxford entre los años 1982 y 2002. Especialmente con posterioridad a 1995 cientos de muestras de minerales y escorias recogidas de minas y sitios de reducción de minerales localizadas en el entorno de las montañas de Troodos también fueron analizadas. La mayoría de los resultados fueron publicados en varios artículos a lo largo del tiempo, pero la interpretación de algunos análisis de isótopos de plomo necesitan de una revisión a

  9. The Bronze Age in the Northwestern of Iberian Peninsula: an analysis from funerary practices

    Directory of Open Access Journals (Sweden)

    Bettencourt, Ana M. S.

    2010-06-01

    Full Text Available From the analysis of the funerary practices and of their integration in the different chronological-cultural contexts where they develop, the author works out a new interpretation of the mechanism of negotiation of power and the promotion of social identity through the Bronze Age of the NW Iberian Peninsula. When studying an area so wide she distinguishes two great trends in the type and distribution of the funerary architectures throughout the Bronze Age that she associates with different ways of interaction with, and perception of, the world. Thus, she argues that the necropolises of “cloudy” tombs (cists without tumuli, plain graves and pits, located in areas of great agricultural potential and close to the settlements, may have been constructed by sedentary communities, very involved in agricultural activities, with a great sense of territoriality and a great control over, and deep knowledge of, the territory. On the other hand the communities involved with mountain landscapes, eventually more related to cattle and with ways of life that would imply greater mobility, were responsible for the construction of more visible funerary structures, such as small tumuli of megalithic tradition, located away from the settlements. In relation to the social role of the corpse, the author argues for the Early Bronze Age, that, the occupation of new territories, the emergence of a new form of community interaction with the environment and the emergence of new mechanisms of power and legitimacy of the territory were materialized in burial practices and in the social role of some corpses, in copper and gold grave goods. This social role was represented in old and new places. From the Middle Bronze Age she assumes that the corpse loses importance in collective terms and that death becomes more familiar. The new settings of power negotiation and social identity are transferred to other contexts of action more connected with the sphere of the living

  10. A family of rare earth molybdenum bronzes: Oxides consisting of periodic arrays of interacting magnetic units

    International Nuclear Information System (INIS)

    The family of rare earth molybdenum bronzes, reduced ternary molybdates of composition LnMo16O44, was synthesized and a detailed structural study carried out. Bond valence sum (BVS) calculations clearly show that the molybdenum ions in tetrahedral coordination are hexavalent while the electron count in the primitive unit cell is odd. Yet, measurements show that the phases are semiconductors. The temperature dependence of the magnetic susceptibility of samples containing several different rare earth elements was measured. These measurements verified the presence of a 6.5 K magnetic phase transition not arising from the rare earth constituent, but likely associated with the unique isolated ReO3-type Mo8O36 structural subunits in this phase. To better understand the behavior of these materials, electronic structure calculations were performed within density functional theory. Results suggest a magnetic state in which these structural moieties have an internal ferromagnetic arrangement, with small ~1/8 μB moments on each Mo. We suggest that the Mo8O36 units behave like pseudoatoms with spin 1/2 derived from a single hole distributed over the eight Mo atoms that are strongly hybridized with the O atoms of the subunit. Interestingly, while the compound is antiferromagnetic, our calculations suggest that a field-stabilized ferromagnetic state, if achievable, will be a narrow band half-metal. - Graphical abstract: LnMo16O44 phases comprise corner sharing tetrahedral and octahedral molybdenum ions. The MoO6 octahedra form Mo8O36 units that are well separated and act like pseudo-atoms, accommodating 11 electrons each. - Highlights: • Single crystal X-ray diffraction refinements of LnMo16O44 single crystals for Ln=Ce, Pr, Nd, Tb, Dy and Ho. • DFT calculations based on LaMo16O44. • [Mo8O36] units behaving as superatoms with a net magnetic moment of 1 µB. • Bronze structure containing equal number of molybdenum tetrahedra and octahedral

  11. Alloy characterization of a 7th Century BC archeological bronze vase — Overcoming patina constraints using Monte Carlo simulations

    Energy Technology Data Exchange (ETDEWEB)

    Manso, M. [Laboratório de Instrumentação, Engenharia Biomédica e Fisica da Radiação (LIBPhys-UNL), Departamento de Fisica, Faculdade de Ciências e Tecnologias, Universidade Nova de Lisboa, 2829-516 Monte da Caparica (Portugal); Faculdade de Belas-Artes da Universidade de Lisboa, Largo da Academia Nacional de Belas-Artes, 1249-058 Lisboa (Portugal); Schiavon, N. [Hercules Laboratory, University of Évora, Palácio do Vimioso,Largo Marquês de Marialva 8, 7000-809 Évora Portugal (Portugal); Queralt, I. [Laboratory of X-ray Analytical Applications, Institute of Earth Sciences Jaume Almera, CSIC, Solé Sabaris s/n, 08028 Barcelona (Spain); Arruda, A.M. [Centro de Arqueologia da Universidade de Lisboa (UNIARQ), Alameda da Universidade, 1600-214 Lisboa (Portugal); Sampaio, J.M. [BioISI — Biosystems & Integrative Sciences Institute, Faculdade de Ciências da Universidade de Lisboa (Portugal); Brunetti, A., E-mail: brunetti@uniss.it [Department of Political Science and Communication, University of Sassari, Via Piandanna 2, 07100 Sassari (Italy)

    2015-05-01

    In this work we evaluate the composition of a bronze alloy using X-ray fluorescence spectrometry (XRF) and Monte Carlo (MC) simulations. For this purpose, a 7th Century BC archeological vase from the SW Iberian Peninsula, displaying a well formed corrosion patina was analyzed by means of a portable X-ray fluorescence spectrometer. Realistic MC simulations of the experimental setup were performed with the XRMC code package which is based on an intensive use of variance-reduction techniques and uses XRAYLIB a constantly updated X-ray library of atomic data. A single layer model was applied for simulating XRF of polished/pristine bronze whereas a two-or-three-layer model was developed for bronze covered respectively by a corrosion patina alone or coupled with a superficial soil derived crust. These simulations took into account corrosion (cerussite (PbCO{sub 3}), cuprite (Cu{sub 2}O), malachite (Cu{sub 2}CO{sub 3}(OH){sub 2}), litharge (PbO)) and soil derived products (goethite (FeO(OH)) and quartz (SiO{sub 2})) identified by means of X-ray diffraction and Raman micro analytical techniques. Results confirm previous research indicating that the XRF/Monte Carlo protocol is well suited when a two-layered model is considered, whereas in areas where the patina + soil derived products' crust is too thick, X-rays from the alloy substrate are not able to exit the sample. Quantitative results based on MC simulations indicate that the vase is made of a lead–bronze alloy: Mn (0.2%), Fe (1.0%), Cu (81.8%), As (0.5%), Ag (0.6%), Sn (8.0%) and Pb (8.0%). - Highlights: • We study an archeological bronze vase with patina corrosion using XRF spectrometry. • The experimental setup is modeled using Monte Carlo (MC) simulations. • Combining MC simulations with XRF it is possible to derive concentrations. • We demonstrated that this is possible without removing the patina.

  12. Holes in teeth - Dental caries in Neolithic and Early Bronze Age populations in Central Germany.

    Science.gov (United States)

    Nicklisch, Nicole; Ganslmeier, Robert; Siebert, Angelina; Friederich, Susanne; Meller, Harald; Alt, Kurt W

    2016-01-01

    This study provides diachronic insight into the epidemiology of carious defects in teeth of Neolithic and Early Bronze Age populations in Central Germany over a period of 4000 years. The data were retrieved from skeletal remains uncovered at 21 sites throughout the Middle Elbe-Saale region (MES), comprising a total of 494 individuals with preserved teeth. The data generated were examined for age- and sex-related differences in order to gain information about the dietary habits and socio-economic structures of the period with the goal of identifying potential diachronic changes. The results indicated that dietary habits changed over the course of the Neolithic period: the prevalence of caries significantly decreased between the Early and Late Neolithic. The adults from the Early Neolithic sample, particularly those from the LBK bore the highest rate of caries. This highlights the essential importance of cereals in the diet of the early farmers in the Middle Elbe-Saale region. As time went on, meat and dairy products became more and more important, which had a positive impact on dental health. The data also show sex-specific differences: women were more often affected by caries than men and female jaws also generally exhibited greater numbers of carious teeth than their male counterparts. Dental health is a reflection of both biological factors and of economic and sociocultural structures. PMID:25765291

  13. Astronomical Interpretation of the Signs on the Vessel of the Bronze Age (Central Donbass)

    CERN Document Server

    Vodolazhskaya, Larisa N; Nevsky, Mikhail Yu

    2015-01-01

    The article presents the results of multidisciplinary study carried out with the help of archaeological and astronomical methods. The aim of the study was to analyze and interpret the signs - elements of the composition, incised on the outer side surface of the vessel of the Late Bronze Age, owned to Srubna culture and discovered near the Staropetrovsky village in the northeast of the Donetsk region. The measurements and astronomical calculations revealed that all signs have astronomical meaning. Fourray star has been interpreted as the star Sirius. The sign polyline has been interpreted as an analog of graphic of equation of time in which the testimony of a water clock correspond with average solar time, and the testimony of a sundial - the true solar time. Sign wheel has been interpreted as a complex of lines, reflecting the regularity changing the direction of the shadows from the gnomon at sunset at the equinoxes and solstices. The sign thin polyline has been interpreted as a symbol of change of height of...

  14. Effect of Annealing Atmosphere on the Mechanical Property of Free-cutting Phosphor Bronze Alloy

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The present work is focused on the influence of annealing atmosphere on the microstructure and mechanical property of free-cutting phosphor bronze alloy. The annealing of the alloy was conducted in the three kinds of annealing atmosphere such as air, vacuum and nitrogen. After annealing, a discernable difference in recystallized grain size and lead particle size was not appeared with different annealing atmosphere. The tensile strength of the alloy annealed in air or nitrogen atmosphere was higher than that of those annealed in vacuum atmosphere. In thecase of the alloy annealed in vacuum atmosphere, the mechanical strength was reduced by vaporization of zinc. In the case of annealing in nitrogen and in air atmosphere, the sweating of lead was occurred. However, the inverse segregation of lead was suppressed by copper oxide layer on the surface annealed in air. This copper oxide layer leads to a decrease of the yield during fabrication process. Therefore, annealing of the alloy in nitrogen atmosphere is favorable in terms of the mechanical strength and yield.

  15. Computed tomography of a medium size Roman bronze statue of Cupid

    Energy Technology Data Exchange (ETDEWEB)

    Bettuzzi, M.; Brancaccio, R. [University of Bologna, Department of Physics and Astronomy, Bologna (Italy); Casali, F.; Morigi, M.P. [University of Bologna, Department of Physics and Astronomy, Bologna (Italy); Centro Fermi, Rome (Italy); Carson, D.; Chiari, G. [Getty Conservation Institute, Los Angeles, CA (United States); Maish, J. [The J. Paul Getty Museum, Los Angeles, CA (United States)

    2015-01-14

    Diagnostics based on X-ray computed tomography (CT) are becoming increasingly important, not only in the medical field but in industry and cultural heritage. CT devices typical for medical applications, however, can seldom be used on art objects because both they are not easily transportable and they often present high X-ray absorption. It is therefore necessary to make use of portable instrumentation and/or to develop tomographic systems optimized to the characteristics of the objects under examination. This work describes the computed tomography of a first century A.D. Roman bronze statue of Cupid (96.AB.53) in the collection of the J. Paul Getty Museum, within the collaborative framework between the Getty Conservation Institute and the Department of Physics and Astronomy (DIFA) of the University of Bologna (Italy). The tomography performed at the Getty facilities employed a 450 kV X-ray tube and a detection system developed at DIFA. The study highlighted the casting and construction techniques used by Roman foundry workers and provided information on the status of conservation of the statue. A 3D virtual reconstruction allowed the user to define different cross-sections enabling the study of the internal features. (orig.)

  16. The water clock of the Bronze Age (Northern Black Sea Coast)

    CERN Document Server

    Vodolazhskaya, Larisa N; Nevsky, Mikhail Yu

    2015-01-01

    In the article presents the results of the multidisciplinary study conducted with the help of archaeological, physical and astronomical methods. The aim of the study was to analyze and interpret marks and drawings applied to the surface of the vessel of the Bronze Age (Srubna culture) found near the Staropetrovsky village (Donetsk region, Ukraine) near the border between the Donetsk and Lugansk regions. The carried out calculations and measurements possible to prove that staropetrovsky vessel is the most ancient water clock, discovered on the territory of Europe, and have approximately the same age as the oldest known ancient Egyptian water clock. Such vessels - water clocks were needed for Srubna population to mark sundial, which had recently been discovered in the Northern Black Sea Coast. Based on the analysis of marks on the outside of the vessel, it was revealed that Staropetrovsky vessel is unique ancient complex device for measuring time and at the same time using a water clock, and with the help of a ...

  17. Mitochondrial DNA analysis of Bronze Age horses recovered from Chifeng region, Inner Mongolia, China

    Institute of Scientific and Technical Information of China (English)

    Cai Dawei; Han Lu; Xie Chengzhi; Li Shengnan; Zhou Hui; Zhu Hong

    2007-01-01

    In this study, mitochondrial DNA (mtDNA) analysis was carried out on 9 Bronze Age horses recovered from Dashanqian and Jinggouzi archaeological sites in Chifeng region, Inner Mongolia, China to explore the origin of Chinese domestic horses. Both mtDNA 16S rRNA gene and control region (D-loop) fragments of ancient horses were amplified and sequenced. The analysis of the highly conservative 16S rRNA gene sequences indicated that the burial environment of Chifeng region is suitable for the preservation of ancient DNA (aDNA). Combing 465 mtDNA D-loop sequences representing different breeds from East Asia, Central Asia, Near East and Europe, we constructed a phylogenetic network to investigate the relationship between ancient and modern horses. The phylogenetic network showed that the 9 horses were distributed into different modem horse clusters which were closely related to them representing a certain ge-ographical distribution. Our results showed that the maternal genetic line of the ancient horses in Chifeng region was highly diversified,which contributed to the gene pool of modern domestic horses and suggested a complex origin of domestic horses in China.

  18. Leather material found on a 6th B.C. Chinese bronze sword: A technical study

    Science.gov (United States)

    Luo, Wugan; Si, Yi; Wang, Hongmin; Qin, Ying; Huang, Fengchun; Wang, Changsui

    2011-09-01

    During July to November, 2006, an important archaeological excavation was conducted in Yun country, Hubei province, southern China. Chinese archaeologists found some remnant of leather materials, covered with red pigments, on a 6th century B.C. Chinese bronze sword. To understand the technology/ies that may have been utilized for manufacturing the leathers, a combined of Raman spectroscopy, FT-IR and XRF was thus applied to the remnant of leather materials. Raman analyses showed that red pigment on the leather was cinnabar (HgS). FT-IR and XRF analyses indicated that the content of some elements, such as Ca (existing as CaCO 3) and Fe (existing as Fe 2O 3), were much higher than those in the surrounding grave soil. The results inferred an application of lime depilation and retting, and the Fe-Al compound salt as tanning agent. And it was furthermore implicated that the Fe-Al salt tanning technique had been developed in the middle and late Spring and Autumn Period of China.

  19. Origin of ferroelectric polarization in tetragonal tungsten-bronze-type oxides

    Science.gov (United States)

    Olsen, Gerhard Henning; Aschauer, Ulrich; Spaldin, Nicola A.; Selbach, Sverre Magnus; Grande, Tor

    2016-05-01

    The origin of ferroelectric polarization in tetragonal tungsten-bronze- (TTB-) type oxide strontium barium niobate (SBN) is investigated using first-principles density functional calculations. We study in particular the relationship between the polarization and the cation and vacancy ordering on alkali-earth metal lattice sites. Lattice dynamical calculations for paraelectric structures demonstrate that all cation configurations that can be accommodated in a 1 ×1 ×2 supercell result in a single unstable polar phonon, composed primarily of relative Nb-O displacements along the polar axis, as their dominant instability. The majority of the configurations also have a second octahedral tilt-mode instability which couples weakly to the polar mode. The existence of the tilt mode is strongly dependent on the local cation ordering, consistent with the fact that it is not found experimentally. Our results suggest that ferroelectricity in the SBN system is driven by a conventional second-order Jahn-Teller mechanism caused by the d0 Nb5 + cations, and demonstrate the strong influence of the size of Sr and Ba on the lattice distortions associated with polarization and octahedral tilting. Finally, we suggest a mechanism for the relaxor behavior in Sr-rich SBN based on Sr displacement inside pentagonal channels in the TTB structure.

  20. The examination, analysis and conservation of a bronze Egyptian Horus statuette

    Energy Technology Data Exchange (ETDEWEB)

    Smith, A. [Conservation Department, Ditsong: National Museum of Cultural History, PO Box 28088, Sunnyside, Pretoria 0132 (South Africa); Botha, H. [South African Institute for Objects Conservation, PO Box 122, Joubertina 6410 (South Africa); Beer, F.C. de, E-mail: frikkie.debeer@necsa.co.za [Radiation Science, Necsa, PO Box 582, Pretoria 0001 (South Africa); Ferg, E. [Department of Chemistry, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa)

    2011-09-21

    The production techniques, corrosive deterioration, conservation and questions regarding authenticity of a small Egyptian bronze statuette of the Child Horus (in the collection of the Ditsong: National Museum of Cultural History in Pretoria) was scientifically examined and analysed. The statuette dates to Egypt's 12th Dynasty. When the statuette was damaged, it was considered the appropriate time to obtain valuable information about its history and background through scientific research. Neutron tomography (NT), a relatively new non-destructive technique (NDT) to the South African R and D community to study museum objects, was applied to perform this research. The results from NT were supported by additional tests done through XRF and XRD analyses of samples taken from the damaged statuette. Results revealed that the lost-wax method was used in the manufacturing process. The extent of the restoration and materials used can be verified and as a result the deterioration of the object can now be monitored. This paper describes in detail the analytical techniques used in the study and how it contributed to the conservation of the statuette and its authenticity.

  1. Canine transposition in prehistoric Pakistan: Bronze Age and Iron Age case reports.

    Science.gov (United States)

    Lukacs, J R

    1998-10-01

    This report documents two prehistoric cases of canine-first premolar transposition (Mx.C.P1) from the Indo-Pakistan subcontinent. Recent discussion of the etiology of canine transposition and reports of high prevalence for the condition in modern India accentuate the significance of the ancient cases reported there. Case 1 is from the Iron Age site of Sarai Khola in northern Pakistan (1000 BC). The specimen, an adult female, 25 to 30 years of age at death, exhibits unilateral Mx.C.P1 transposition on the left side. The condition is associated with a barrel-shaped maxillary left third molar in an otherwise normal and healthy maxillary dental arch. Case 2 is from the Bronze Age urban site of Harappa (2500 BC), an important center of the Indus Valley Civilization. In this specimen, an adult female, transposition is bilateral, resulting in displacement of premolars and large diastemata between the maxillary lateral incisors and first premolars. Bilateral agenesis of maxillary third molars and rotation of maxillary and mandibular teeth occur with transposition in this specimen. In neither case are the lateral incisors reduced in size, peg-shaped, or congenitally absent. This report of Mx.C.P1 transposition in prehistoric times is significant because it provides historical documentation for the female predilection of the trait and establishes its co-occurrence with specific dental variants, such as agenesis, reduction, and rotation of teeth. PMID:9770107

  2. Dental paleopathology and agricultural intensification in south Asia: new evidence from Bronze Age Harappa.

    Science.gov (United States)

    Lukacs, J R

    1992-02-01

    Patterns of dental disease among Bronze Age people of the Indus Valley Civilization are currently based on early and incomplete reports by non-specialists. This deficiency precludes accurate diachronic analysis of dental disease and its relationship with increasing agriculturalism in the Indian subcontinent. The objective of this paper is to document prevalence of dental disease at Harappa (2500-2000 B.C.), Punjab Province, Pakistan, comparatively evaluate the Harappan dental pathology profile, and use these data to assess theories regarding the dental health consequences of increasingly intensive agricultural dependence. Pathological conditions of the dentition included in the study are abscesses, ante-mortem tooth loss (AMTL), calculus, caries, hypoplasia, hypercementosis, pulp chamber exposure, and alveolar resorption. The Harappan dentition exhibits a dental pathology profile typical of a population whose subsistence base is agriculture. Dental caries at Harappa are present in 6.8% (n = 751) of the teeth and 43.6% (n = 39) of the more completely preserved dental specimens. The use of a caries correction factor is recommended to permit an estimate of caries induced AMTL in calculating the caries prevalence. All dental lesions are present at higher rates in this Harappan study sample than were reported in previous investigations, and important differences in prevalence of dental disease occur between the genders. Prevalence of dental disease increases in the greater Indus Valley as subsistence becomes more intensive and as food preparation and storage technology becomes more efficient. PMID:1543240

  3. Genetic evidence for an origin of the Armenians from Bronze Age mixing of multiple populations.

    Science.gov (United States)

    Haber, Marc; Mezzavilla, Massimo; Xue, Yali; Comas, David; Gasparini, Paolo; Zalloua, Pierre; Tyler-Smith, Chris

    2016-06-01

    The Armenians are a culturally isolated population who historically inhabited a region in the Near East bounded by the Mediterranean and Black seas and the Caucasus, but remain under-represented in genetic studies and have a complex history including a major geographic displacement during World War I. Here, we analyse genome-wide variation in 173 Armenians and compare them with 78 other worldwide populations. We find that Armenians form a distinctive cluster linking the Near East, Europe, and the Caucasus. We show that Armenian diversity can be explained by several mixtures of Eurasian populations that occurred between ~3000 and ~2000 bce, a period characterized by major population migrations after the domestication of the horse, appearance of chariots, and the rise of advanced civilizations in the Near East. However, genetic signals of population mixture cease after ~1200 bce when Bronze Age civilizations in the Eastern Mediterranean world suddenly and violently collapsed. Armenians have since remained isolated and genetic structure within the population developed ~500 years ago when Armenia was divided between the Ottomans and the Safavid Empire in Iran. Finally, we show that Armenians have higher genetic affinity to Neolithic Europeans than other present-day Near Easterners, and that 29% of Armenian ancestry may originate from an ancestral population that is best represented by Neolithic Europeans. PMID:26486470

  4. Aerobic swimming performance of juvenile largemouth bronze gudgeon (Coreius guichenoti) in the Yangtze River.

    Science.gov (United States)

    Tu, Zhiying; Li, Liping; Yuan, Xi; Huang, Yingping; Johnson, David

    2012-06-01

    Largemouth bronze gudgeon (Coreius guichenoti), a fish species once abundant in the Yangtze River, has been rapidly declining in recent years. One important factor, among many, is the interruption of the free-flowing rivers by dams. To obtain data that can be applied to the design of an effective fishway for C. guichenoti and other species in the fish community, a laboratory study of juvenile C. guichenoti's swimming ability and energetics was conducted in a flume-type respirometer equipped with a high-speed video camera system to record swimming behavior. The critical swimming speed (Ucrit ), standard metabolic rate (SMR), and maximum metabolic rate (MO2,max ) were determined during steady swimming at four water temperatures (10, 15, 20, and 25°C). A power function accurately describes the relationship between oxygen consumption rate (MO2 ) and swimming speed (U) at the four temperatures. The Ucrit , SMR, MO2,max , and metabolic scope increased with increasing temperature. The relationship between cost of transport (COT) and U was characteristically inverse bell-shaped, with minimum COT at Uopt = 4.5-5.0 body lengths per second (bl sec(-1)). This investigation provides data on the swimming ability of C. guichenoti that will add to the basic science required for fishway design.

  5. The questionable contribution of the Neolithic and the Bronze Age to European craniofacial form.

    Science.gov (United States)

    Brace, C Loring; Seguchi, Noriko; Quintyn, Conrad B; Fox, Sherry C; Nelson, A Russell; Manolis, Sotiris K; Qifeng, Pan

    2006-01-01

    Many human craniofacial dimensions are largely of neutral adaptive significance, and an analysis of their variation can serve as an indication of the extent to which any given population is genetically related to or differs from any other. When 24 craniofacial measurements of a series of human populations are used to generate neighbor-joining dendrograms, it is no surprise that all modern European groups, ranging all of the way from Scandinavia to eastern Europe and throughout the Mediterranean to the Middle East, show that they are closely related to each other. The surprise is that the Neolithic peoples of Europe and their Bronze Age successors are not closely related to the modern inhabitants, although the prehistoric/modern ties are somewhat more apparent in southern Europe. It is a further surprise that the Epipalaeolithic Natufian of Israel from whom the Neolithic realm was assumed to arise has a clear link to Sub-Saharan Africa. Basques and Canary Islanders are clearly associated with modern Europeans. When canonical variates are plotted, neither sample ties in with Cro-Magnon as was once suggested. The data treated here support the idea that the Neolithic moved out of the Near East into the circum-Mediterranean areas and Europe by a process of demic diffusion but that subsequently the in situ residents of those areas, derived from the Late Pleistocene inhabitants, absorbed both the agricultural life way and the people who had brought it. PMID:16371462

  6. THE PALEODEMOGRAPHIC PATTERN OF OYLUM HOYUK POPULATION (THE MIDDLE BRONZE AGE, KİLİS

    Directory of Open Access Journals (Sweden)

    Ayşen Açıkkol Yıldırım

    2013-12-01

    Full Text Available In this study skeleton remaining of 72 individuals excavated from Middle Bronze Age layers of Oylum Höyük (mound situated in Kilis province, were studied. Sex and age of skeletons, unearthed between 2007-2012, were determined and life tables of the population were formed. Mortality of infants and children of Oylum population was very high. Death rates were determined as 36.6 % for 0-5 years of age group, 57.75 % for 0-15 years of age group. 34.62 % of infants and children from 0-5 years of age group died before they completed their 1st year. Lifespan of males were longer than females (25 for females, 33 years for males. Average age of adults was 29. Mortality for females was highest in young adult period (18-30 ages however it becomes more prominent at adulthood period (30-45 years in males. Oylum Höyük population has one of the shortest lifespan among ancient Anatolian populations with its very high subadult death ratios. Paleopathological data states that, individuals were exposed to serious stress during growth period and reproductive period is the most dangerous period for females.

  7. Sliding Wear Response of a Bronze Bushing: Influence of Applied Load and Test Environment

    Science.gov (United States)

    Prasad, B. K.

    2012-10-01

    This investigation pertains to the examination of the sliding wear behavior of a leaded-tin bronze bushing under the conditions of varying applied loads and test environments against a steel shaft. The test environment was changed by adding 5% of solid lubricants like talc and lead to an oil lubricant separately as well as in combination; the fraction of the two (solid) lubricants within the solid lubricant mixture was varied in the range of 25-75% in the latter case. The wear performance of the bushing was characterized in terms of the wear rate, frictional heating, and friction coefficient. The increasing load led to deterioration in the wear response, while the addition of the solid lubricant particles produced a reverse effect. Further, an appreciable difference in the wear behavior was not observed when the tests were conducted in the oil plus talc and oil plus lead lubricant mixtures. However, the oil containing lead and talc together brought about a significant improvement in the wear response; best results were obtained in the case of the lubricant mixture consisting of lead and talc together in the ratio of 3:1 in the oil. The observed wear behavior of the samples has been discussed in terms of specific characteristics of various microconstituents. The features of the wear surfaces and subsurface regions further substantiated the wear response and enabled us to understand the operating material removal mechanisms.

  8. Fabricating Superior NiAl Bronze Components through Wire Arc Additive Manufacturing

    Directory of Open Access Journals (Sweden)

    Donghong Ding

    2016-08-01

    Full Text Available Cast nickel aluminum bronze (NAB alloy is widely used for large engineering components in marine applications due to its excellent mechanical properties and corrosion resistance. Casting porosity, as well as coarse microstructure, however, are accompanied by a decrease in mechanical properties of cast NAB components. Although heat treatment, friction stir processing, and fusion welding were implemented to eliminate porosity, improve mechanical properties, and refine the microstructure of as-cast metal, their applications are limited to either surface modification or component repair. Instead of traditional casting techniques, this study focuses on developing NAB components using recently expanded wire arc additive manufacturing (WAAM. Consumable welding wire is melted and deposited layer-by-layer on substrates producing near-net shaped NAB components. Additively-manufactured NAB components without post-processing are fully dense, and exhibit fine microstructure, as well as comparable mechanical properties, to as-cast NAB alloy. The effects of heat input from the welding process and post-weld-heat-treatment (PWHT are shown to give uniform NAB alloys with superior mechanical properties revealing potential marine applications of the WAAM technique in NAB production.

  9. Microstructure and properties of an ordered and a disordered ship propeller bronze

    Energy Technology Data Exchange (ETDEWEB)

    Benkisser, G.; Winkel, G. [Rostock Univ. (Germany); Eberlein, J.; Kaps, R. [Mecklenburger Metallguss Waren (Germany)

    2000-07-01

    The purpose of this paper is a presentation of the investigation results on the influence of the chemical composition and the casting conditions on the transformation behaviour, the microstructure and the properties of the complex aluminium bronzes. By the solidification of the melt is produced the bcc high temperature phase {beta}. In dependence on the cooling time the {beta} - phase transforms in several product phases. In the ordered alloy additionally occur an ordering transformation of the {beta} - phase. Both alloys investigated posses in the sand cast state a heterogenous, coarse grained microstructure. The predominant part of the microstructure is the fcc {alpha} - phase. The lamellar quasieutectoid ({alpha} + {kappa}{sub 3}) and several types of {kappa} - segregates are further parts in the microstructure of the ordered alloy. The {gamma}{sub 2} - phase appears not in the microstructure. In the microstructure of the disordered alloy the retained bcc {beta} - phase and also {kappa} - segregates additionaly exist. The mechanical properties of the alloys depend on the chemical composition and the processing, especially on the cast wall thickness, because the thickness determines the cooling time and in connection with it the transformation behaviour and the phase composition, the grain size and the form and distribution of the phases in the microstructure. The ordered alloy has a higher cavitation resistance in comparison to the disordered alloy. (orig.)

  10. High temperature performance of arc-sprayed aluminum bronze coatings for steel

    Institute of Scientific and Technical Information of China (English)

    ZHANG Zhong-li; LI De-yuan; WANG Shui-yong

    2006-01-01

    The high-temperature oxidation behavior of arc-sprayed aluminum bronze coatings on steel substrate was studied during isothermal exposures in air at 900 ℃. The surface morphologies and interface of the coatings after isothermal oxidation at 900 ℃ for different times were observed. The experiments showed that the coatings on steel substrate were not deteriorated and the substrate was protected well, being exposed to high temperatures up to 900 ℃. The coatings withstood more than ten times thermal shock tests without any coating separation. The thermal expansion coefficient of the coatings was measured, revealing not much difference between it and that of steel substrate. After exposure at high temperature, the coatings were still adhered to steel substrate well.Isothermal mass gain of the coatings at elevated temperature in dry air was measured by means of a thermal balance and the oxidation behavior was evaluated by oxidation kinetic curves, exhibiting the oxidation kinetics curve accorded with a parabolic law.The parabolic rate constant of the oxidation kinetic curve is 1.02× 10-9 g2·cm-4·s-1 for the first 60 min and from 150 min to 2 880 min the constant is 5.1 × 10-12 g2·cm-4·s-1.

  11. Potential of 5-methyl 1-H benzotriazole to suppress the dissolution of α-aluminum bronze in sulfide-polluted salt water

    Energy Technology Data Exchange (ETDEWEB)

    Nazeer, Ahmed Abdel; Ashour, E.A. [National Research Centre, Electrochemistry Laboratory, Dokki, Cairo 12622 (Egypt); Allam, Nageh K., E-mail: nageh.allam@aucegypt.edu [National Research Centre, Electrochemistry Laboratory, Dokki, Cairo 12622 (Egypt); Energy Materials Laboratory, Physics Department, School of Sciences and Engineering, The American University in Cairo, P.O. Box 74, New Cairo 11835 (Egypt)

    2014-03-01

    This work investigates the inhibition effect of 5-methyl 1-H benzotriazole (MBT) on the dissolution behavior of α-aluminum bronze in clean and sulfide-polluted salt water using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), electrochemical frequency modulation (EFM) and scanning electron microscopy (SEM) techniques. The inhibition efficiency increases with the increasing MBT concentration and decreases with the increasing temperature. The adsorption process of MBT is spontaneous and follows Langmuir adsorption isotherm model. MBT possesses excellent inhibiting effect for the corrosion of α-Al-bronze, which acts as a mixed type inhibitor. Thermodynamic and kinetic parameters for the adsorption process were determined. The presence of sulfide ions (2 ppm) decreases the inhibition efficiency of MBT against the corrosion of Al-bronze alloy in chloride solutions from 94.7% to 89% as also confirmed via SEM images. The results obtained from the different techniques were in good agreement, which prove the validity of these tools in the measurements of the tested inhibitor. - Highlights: • MBT is an excellent mixed corrosion inhibitor for bronze. • There is a competitive adsorption between MBT and sulfide ions to adsorb on bronze surface. • The adsorption of MBT is spontaneous and follows Langmuir model. • CPE decreases significantly with the increasing MBT concentration.

  12. The effect of low-dose neutron irradiation on mechanical properties, electrical resistivity and fracture of NiAl bronze for ITER

    International Nuclear Information System (INIS)

    Nickel-aluminum bronze is a candidate material for several applications for ITER in-vessel components such as divertor and blanket attachments and remote handling equipment. This paper presents the first results of an experimental investigation of the effect of neutron irradiation on mechanical properties, fracture characteristics and electrical resistivity of NiAl bronze. Specimens of NiAl bronze were irradiated at 150 oC and 300 oC to doses of 10-3; 10-2; 0.7 * 10-1 dpa in the RBT-6 reactor (Φt therm/Φt fast ∼ 1) in Dimitrovgrad. It was shown that irradiation at 150 oC leads to minor changes of tensile properties, whereas irradiation at 300 oC results in significant loss of ductility at damage dose of 0.07 dpa. The change of electrical resistively of NiAl bronze is low, ∼3% at the maximum dose studied. The reasons for the high-radiation resistance of NiAl bronze in comparison with copper and copper alloys are discussed

  13. 古滇王国青铜器的造型艺术研究%Research on Bronze Aesthetic Art of the Ancient Dian Kinadom

    Institute of Scientific and Technical Information of China (English)

    张吉洪

    2012-01-01

    Bronze art from the Ancient Dian Kingdom of Yunnan is an especially charming segment of China' s ancient bronze culture. Ancient Dian bronze art is famous for its outstanding aesthetics and intricate details. The firm conceptualization and practicality underpinning its stunning appearance has put it in a class of its own. The Ancient Dian had rendered numerous aspects of their civilization' s culture on bronze art -- farming, livestock, textiles, hunting and war, among others. They have created their animated history on bronze.%云南古滇青铜器的艺术魅力,是中华民族古代青铜文化中的一支夺目的奇葩,以其造型精美奇特、纹饰细腻丰富闻名于世,其写实性之强,构思巧妙,独树一帜。滇国的先民们把当时耕作、畜牧、纺织、狩猎、战争等各种社会生活场景凝聚在青铜器上,用自己的双手铸造了一部生动的青铜史诗。

  14. The influence of the chemical composition and temperature of plastic deformation on the PLC effect in tin bronzes

    Directory of Open Access Journals (Sweden)

    W. Ozgowicz

    2006-04-01

    Full Text Available Purpose: The aim of the present paper is the determination of the effect of the chemical composition and temperature of deformation of standardized tin bronzes and bronze modified with zirconium on the Portevin – Le Chatelier (PLC phenomenon, mainly basing on the shape of stress-strain curves within the temperature range of 100÷300oC and observations of their structure. The reasons of the occurrence of such en effect are so far no fully known and explained and the opinions concerning is physical basis vary.Design/methodology/approach: Of essential design in this research is determination of the dependence of PLC effect on the chemical composition, temperature and strain rate and the preliminary heat treatment and grain size. The main method used in this investigation is tensile test at elevated temperature.Findings: The main conclusions are following: the PLC effect on tin bronzes with a miero-addition of zirconium in an amount of 0.01÷0.05% depends the temperature of deformation in the tensile test in the range of 100÷300°C and the chemical composition of the alloys; the type of serration revealed on the δ–ε curve depend mainly on the temperature of deformation and can be differ during the respective stages of the analyzed curves.Practical implications: In this paper implications for practice are not taken into consideration.Originality/value: In this paper an additive type of serration observed on the curves δ–ε, denoted by the symbol D, is new.

  15. Extent of Variation of the Bacillus thuringiensis Toxin Reservoir: the Case of the Geranium Bronze, Cacyreus marshalli Butler (Lepidoptera: Lycaenidae)

    Science.gov (United States)

    Herrero, Salvador; Borja, Marisé; Ferré, Juan

    2002-01-01

    Despite the fact that around 200 cry genes from Bacillus thuringiensis have already been cloned, only a few Cry proteins are toxic towards a given pest. A crucial step in the mode of action of Cry proteins is binding to specific sites in the midgut of susceptible insects. Binding studies in insects that have developed cross-resistance discourage the combined use of Cry proteins sharing the same binding site. If resistance management strategies are to be implemented, the arsenal of Cry proteins suitable to control a given pest may be not so vast as it might seem at first. The present study evaluates the potential of B. thuringiensis for the control of a new pest, the geranium bronze (Cacyreus marshalli Butler), a butterfly that is threatening the popularity of geraniums in Spain. Eleven of the most common Cry proteins from the three lepidopteran-active Cry families (Cry1, Cry2, and Cry9) were tested against the geranium bronze for their toxicity and binding site relationships. Using 125I-labeled Cry1A proteins we found that, of the seven most active Cry proteins, six competed for binding to the same site. For the long-term control of the geranium bronze with B. thuringiensis-based insecticides it would be advisable to combine any of the Cry proteins sharing the binding site (preferably Cry1Ab, since it is the most toxic) with those not competing for the same site. Cry1Ba would be the best choice of these proteins, since it is significantly more toxic than the others not binding to the common site. PMID:12147511

  16. Tungsten bronze-based nuclear waste form ceramics. Part 1. Conversion of microporous tungstates to leach resistant ceramics

    Science.gov (United States)

    Luca, Vittorio; Griffith, Christopher S.; Drabarek, Elizabeth; Chronis, Harriet

    2006-11-01

    The effective immobilization of Cs + and/or Sr 2+ sorbed on hexagonal tungsten oxide bronze (HTB) adsorbent materials has been achieved by heating in air at temperatures in the range 500-1000 °C. Crystalline powdered HTB materials formed by heating at 800 °C displayed leach characteristics comparable to Cs-containing hot-pressed hollandites in the pH range from 0 to 12. If the Cs-loaded HTB sorbents were pressed into pellets prior to calcination, ceramic monoliths could be prepared with negligible Cs volatilization losses. Heating to temperatures in excess of 1250 °C under dynamic air flow resulted in the melting of the sorbent to form phase assemblages consisting of millimetre-sized crystals of bronzoid phases. Up to 5 wt% mass loss was observed for small scale samples of melted materials under dynamic air flow. Both the calcined and melted bronzoid waste forms are multiphase ceramics in which Cs + remains bound within, and appears to stabilize, the hexagonal bronze phase, even after complete melting at 1300 °C. The leachability of Sr from the phases prepared by heating appears to be somewhat worse than that of Cs. Saturation of the HTB adsorbents with lanthanide elements (Nd, La, Ce) gave rise to cubic bronze phases in which we propose that the lanthanides substitute at the tungsten or molybdenum sites rather than the tunnel positions. The lanthanides were rather easily leached from the calcined phases in 0.1 M HNO 3 at 150 °C.

  17. Agricultural production and stability of settlement systems in Upper Mesopotamia during the Early Bronze Age (third millennium BCE)

    Science.gov (United States)

    Kalayci, Tuna

    This study investigates the relationship between rainfall variation and rain-fed agricultural production in Upper Mesopotamia with a specific focus on Early Bronze Age urban settlements. In return, the variation in production is used to explore stability of urban settlement systems. The organization of the flow of agricultural goods is the key to sustaining the total settlement system. The vulnerability of a settlement system increases due to the increased demand for more output from agricultural lands. This demand is the key for the success of urbanization project. However, without estimating how many foodstuffs were available at the end of a production cycle, further discussions on the forces that shaped and sustained urban settlement systems will be lacking. While large scale fluctuations in the flow of agricultural products between settlements are not the only determinants of hierarchical structures, the total available agricultural yield for each urban settlement in a hierarchy must have influenced settlement relations. As for the methodology, first, Early Bronze Age precipitation levels are estimated by using modern day associations between the eastern Mediterranean coastal areas and the inner regions of Upper Mesopotamia. Next, these levels are integrated into a remote-sensing based biological growth model. Also, a CORONA satellite imagery based archaeological survey is conducted in order to map the Early Bronze Age settlement system in its entirety as well as the ancient markers of agricultural intensification. Finally, ancient agricultural production landscapes are modeled in a GIS. The study takes a critical position towards the traditionally held assumption that large urban settlements (cities) in Upper Mesopotamia were in a state of constant demand for food. The results from this study also suggest that when variations in ancient precipitation levels are translated into the variations in production levels, the impact of climatic aridification on ancient

  18. Roman Bronze Vessels From the Late Sarmatian Burial of the Lebedevka Burial-Ground in Western Kazakhstan

    Directory of Open Access Journals (Sweden)

    Treister Mikhail Yuryevich

    2015-12-01

    Full Text Available This paper is devoted to studying cultural monuments – bronze vessels, a jug and a basin from the barrow no. 1/1967 of the Lebedevka Late Sarmatian burial mound (Western Kazakhstan, dating back to the middle of the 3rd century AD at the latest. These items do not find exact parallels among the bronze vessels of provincial Rome. Although the shape of the jug handle with a curved leaf turned upright between two horizontally arranged swan heads has parallels on the so-called “composite jug with handles” (“gegliederten Henkelkrügen”, the cylindrical form of the jug’s neck peculiar of the glass jugs of allegedly Syrian manufacture of the second half of the 3rd-4th centuries AD is very unusual. Even more unusual is a basin with horizontally bent rim and elaborate handles with pearls on a high narrow stand-ring. The XRF analyses of the Lebedevka jug’s metal revealed that its body and handle were made of a copper-based alloy with very high admixtures of zinc (24-27 % and inconsiderable additions of lead (up to 3 %. A similar alloy was used for manufacturing a vessel in the form of a crouching young negro from Niederbieber. Most objects of provincial Roman import reached Western Kazakhstan via the Bosporan kingdom along the Northern branch of the Silk Road. The above discussed bronze vessels from Lebedevka let suggest, that the nomads could receive some import articles that were brought along the caravan routes leading from Egypt and Syria to the East.

  19. Characterizing a Middle Bronze palatial wine cellar from Tel Kabri, Israel.

    Directory of Open Access Journals (Sweden)

    Andrew J Koh

    Full Text Available Scholars have for generations recognized the importance of wine production, distribution, and consumption in relation to second millennium BC palatial complexes in the Mediterranean and Near East. However, direct archaeological evidence has rarely been offered, despite the prominence of ancient viticulture in administrative clay tablets, visual media, and various forms of documentation. Tartaric and syringic acids, along with evidence for resination, have been identified in ancient ceramics, but until now the archaeological contexts behind these sporadic discoveries had been uneven and vague, precluding definitive conclusions about the nature of ancient viticulture. The situation has now changed. During the 2013 excavation season of the Kabri Archaeological Project, a rare opportunity materialized when forty large storage vessels were found in situ in an enclosed room located to the west of the central courtyard within the Middle Bronze Age Canaanite palace. A comprehensive program of organic residue analysis has now revealed that all of the relatively uniform jars contain evidence for wine. Furthermore, the enclosed context inherent to a singular intact wine cellar presented an unprecedented opportunity for a scientifically intensive study, allowing for the detection of subtle differences in the ingredients or additives within similar wine jars of apparently the same vintage. Additives seem to have included honey, storax resin, terebinth resin, cedar oil, cyperus, juniper, and perhaps even mint, myrtle, or cinnamon, all or most of which are attested in the 18th century BC Mari texts from Mesopotamia and the 15th century BC Ebers Papyrus from Egypt. These additives suggest a sophisticated understanding of the botanical landscape and the pharmacopeic skills necessary to produce a complex beverage that balanced preservation, palatability, and psychoactivity. This new study has resulted in insights unachievable in the past, which contribute to a

  20. Fish remnants from the excavations of the Bronze Age barrow near Maryanskoe village (Dnepropetrovsk region, Ukraine

    Directory of Open Access Journals (Sweden)

    O. M. Kovalchuk

    2014-10-01

    Full Text Available The Bronze Age mound (2.5–2.3 kya BC is located near the Maryanskoe village (Apostolovskyi district, Dnepropetrovsk region and was excavated in 1953. The results of determination of the fish remnants, which were found during the excavation, are presented in the paper. Eleven species belonging to 9 genera, 5 families and 5 orders (Acipenseriformes, Cypriniformes, Siluriformes, Esociformes, Perciformes were identified: russian sturgeon Acipenser gueldenstaedtii Brandt et Ratzeburg, 1833, stellate sturgeon A. stellatus Pallas, 1771, common ide Idus idus (Linnaeus, 1758, common roach Rutilus rutilus (Linnaeus, 1758, pontic roach R. frisii (Nordmann, 1840, common bream Abramis brama (Linnaeus, 1758, common carp Cyprinus carpio Linnaeus, 1758, tench Tinca tinca (Linnaeus, 1758, european catfish Silurus glanis Linnaeus, 1758, northern pike Esox lucius (Linnaeus, 1758, and zander Sander lucioperca (Linnaeus, 1758. Most of them are quite common in the Dnieper river basin. It was found that carp fishes predominate in the number of species. Most of the bone remnants in the collection belong to zander, catfish and pike, while common roach, pontic roach and common bream are identified by the few bones. This may indicate a different role of these species in the diet of the local population. The ratio of skeletal elements in the collection is the evidence of the fish cutting on the site. Body length and weight was reconstructed for 64 fish specimens. It was found that they were mature and small-sized, except for catfish, pike and perch. Taking into account the characteristics of the funeral rituals of the Yamna culture population, fish bones from the mound near Maryanskoe can be remnants of the parting meal.

  1. High-Rate Intercalation without Nanostructuring in Metastable Nb2O5 Bronze Phases.

    Science.gov (United States)

    Griffith, Kent J; Forse, Alexander C; Griffin, John M; Grey, Clare P

    2016-07-20

    Nanostructuring and nanosizing have been widely employed to increase the rate capability in a variety of energy storage materials. While nanoprocessing is required for many materials, we show here that both the capacity and rate performance of low-temperature bronze-phase TT- and T-polymorphs of Nb2O5 are inherent properties of the bulk crystal structure. Their unique "room-and-pillar" NbO6/NbO7 framework structure provides a stable host for lithium intercalation; bond valence sum mapping exposes the degenerate diffusion pathways in the sites (rooms) surrounding the oxygen pillars of this complex structure. Electrochemical analysis of thick films of micrometer-sized, insulating niobia particles indicates that the capacity of the T-phase, measured over a fixed potential window, is limited only by the Ohmic drop up to at least 60C (12.1 A·g(-1)), while the higher temperature (Wadsley-Roth, crystallographic shear structure) H-phase shows high intercalation capacity (>200 mA·h·g(-1)) but only at moderate rates. High-resolution (6/7)Li solid-state nuclear magnetic resonance (NMR) spectroscopy of T-Nb2O5 revealed two distinct spin reservoirs, a small initial rigid population and a majority-component mobile distribution of lithium. Variable-temperature NMR showed lithium dynamics for the majority lithium characterized by very low activation energies of 58(2)-98(1) meV. The fast rate, high density, good gravimetric capacity, excellent capacity retention, and safety features of bulk, insulating Nb2O5 synthesized in a single step at relatively low temperatures suggest that this material not only is structurally and electronically exceptional but merits consideration for a range of further applications. In addition, the realization of high rate performance without nanostructuring in a complex insulating oxide expands the field for battery material exploration beyond conventional strategies and structural motifs. PMID:27264849

  2. Ancient road transport devices: Developments from the Bronze Age to the Roman Empire

    Science.gov (United States)

    Rossi, Cesare; Chondros, Thomas G.; Milidonis, Kypros F.; Savino, Sergio; Russo, Flavio

    2016-03-01

    The development of transportation systems has significantly enhanced the welfare and modernization of society. Wooden vehicles pulled by animals have been used for land transportation since the early Bronze Age. Whole-body gharries with rigid wheels pulled by oxen appeared in Crete by 2000 BC or earlier. Horses originating from the East were depicted in early Cretan seal-rings of the same period. The two-wheeled horsedrawn chariot was one of the most important inventions in history. This vehicle provided humanity its first concept of personal transport and was the key technology of war for 2000 years. Chariots of Mycenaean and Archaic Greece with light and flexible four-spoked wheels acting as spring suspensions were depicted in vase paintings. The development of this vehicle incorporated the seeds of a primitive design activity and was important for engineering. The Trojan horse since 1194 BC and the helepolis since 700 BC were the first known machines on a wheeled base transported by horses or self-powered. Ancient engineers invented bearings lubricated with fat, and Romans introduced the ancestors of ball bearings for their wagons and carts. The historic evolution of wheeled transportation systems, along with early traction, suspension, and braking systems, is presented in this paper. Analytical and numerical methods are incorporated to analyze the most conceivable loading situations of typically reconstructed wheeled transportation systems in ancient times. Traction requirements both for horse-driven machines and the power for internal motors are also analyzed. This study can serve as a basis for further development of detailed reconstruction of transportation systems in antiquity.

  3. Cavitation Erosion Corrosion Behaviour of Manganese-nickel -aluminum Bronze in Comparison with Manganese-brass

    Institute of Scientific and Technical Information of China (English)

    Hong Yu; Yugui Zheng; Zhiming Yao

    2009-01-01

    The cavitation erosion corrosion behaviour of ZQMn 12-8-3-2 manganese-nickel-aluminum bronze and ZHMn55-3-1 manganese-brass was investigated by mass loss, electrochemical measurements (polarization curves and electrochemical impedance spectroscopy) and the cavitation damaged surfaces were observed by scanning electron microscopy (SEM). The results showed that ZQMn 12-8-3-2 had better cavitation erosion resistance than ZHMn55-3-l. After the cavitation erosion for 6 h, the cumulative mass loss of ZQMnl2-8-3-2 was about 1/3 that of ZHMn55-3-l. The corrosion current density of ZQMnl2-8-3-2 was less than that of ZHMn55-3-l under both static and cavitaiton condition. The free-corrosion potentials of ZQMnl2-8-3-2 and ZHMn55-3-l were all shifted in positive direction under cavitation condition compared to static condition. In the total cu-mulative mass loss under cavitation condition, the pure erosion played a key role for the two tested materials (74% for ZHMn55-3-l and 60% for ZQMnl2-8-3-2), and the total synergism between corrosion and erosion of ZQMnl2-8-3-2 (39%) was larger than that of ZHMn55-3-l (23%). The high cavitation erosion resistance of ZQMnl2-8-3-2 was mainly attributed to its lower stacking fault energy (SFE), the higher microhardness and work-hardening ability as well as the favorable propagation of cavitation cracks for ZQMn 12-8-3-2, i.e., parallel to the surface rather than perpendicular to the surface for ZHMn55-3-l.

  4. Characterizing a Middle Bronze palatial wine cellar from Tel Kabri, Israel.

    Science.gov (United States)

    Koh, Andrew J; Yasur-Landau, Assaf; Cline, Eric H

    2014-01-01

    Scholars have for generations recognized the importance of wine production, distribution, and consumption in relation to second millennium BC palatial complexes in the Mediterranean and Near East. However, direct archaeological evidence has rarely been offered, despite the prominence of ancient viticulture in administrative clay tablets, visual media, and various forms of documentation. Tartaric and syringic acids, along with evidence for resination, have been identified in ancient ceramics, but until now the archaeological contexts behind these sporadic discoveries had been uneven and vague, precluding definitive conclusions about the nature of ancient viticulture. The situation has now changed. During the 2013 excavation season of the Kabri Archaeological Project, a rare opportunity materialized when forty large storage vessels were found in situ in an enclosed room located to the west of the central courtyard within the Middle Bronze Age Canaanite palace. A comprehensive program of organic residue analysis has now revealed that all of the relatively uniform jars contain evidence for wine. Furthermore, the enclosed context inherent to a singular intact wine cellar presented an unprecedented opportunity for a scientifically intensive study, allowing for the detection of subtle differences in the ingredients or additives within similar wine jars of apparently the same vintage. Additives seem to have included honey, storax resin, terebinth resin, cedar oil, cyperus, juniper, and perhaps even mint, myrtle, or cinnamon, all or most of which are attested in the 18th century BC Mari texts from Mesopotamia and the 15th century BC Ebers Papyrus from Egypt. These additives suggest a sophisticated understanding of the botanical landscape and the pharmacopeic skills necessary to produce a complex beverage that balanced preservation, palatability, and psychoactivity. This new study has resulted in insights unachievable in the past, which contribute to a greater understanding

  5. Archaeomagnetic Dating of Bronze Age Pottery in Syria: New Intensity Data for 2300 to 1000 BCE

    Science.gov (United States)

    Stillinger, M. D.; Feinberg, J. M.; Frahm, E.

    2013-12-01

    In order to construct meaningful site chronologies, Near Eastern archaeologists have traditionally relied on relative dating techniques, such as ceramic seriation and textual/glyptic evidence. The introduction of radiocarbon dating provided archaeologists with an absolute dating tool to address age discrepancies. However, many sites do not contain sufficient or suitable materials for radiocarbon analysis, requiring the need for an alternative absolute dating tool. Archaeomagnetic dating provides such an alternative. Excavations at Tell Mozan (Bronze-Age Urkesh) in northeastern Syria have revealed evidence for nearly 5000 years of occupation in strata containing a variety of diagnostic ceramic artifacts, which form the basis for a well-established relative site chronology. In order to test the agreement between seriation ages and paleomagnetic-derived ages, archaeointensity experiments were conducted on pottery specimens from six well-stratified occupational layers spanning more than a thousand years of the site's primary occupation. Archaeointensity was determined using the IZZI paleointensity protocol of Tauxe and Staudigel (2004), and all estimates were corrected for remanence anisotropy and cooling rate effects, resulting in an 88% success rate (n = 51). The magnetic mineral assemblage of each sample was also characterized using a comprehensive suite of rock magnetic techniques. Final results were compared with previous archaeointensity studies in the region, and 70% of the magnetically-derived ages agree with the archaeologically-derived dates within a 1σ confidence interval, while 76% agreed within 2σ. Artifacts showing disagreement with the seriation chronology are most likely objects in use long after their original firing or the result of contamination of strata from the re-use of previous occupational materials in construction. One specimen appears to confirm the presence of a geomagnetic spike around 1000 BCE previously identified in Syria, Israel

  6. A report on the examination of animal skin artefacts from the Bronze Age salt mines of Hallstatt, Austria

    OpenAIRE

    Susanna Harris

    2006-01-01

    My PhD research focuses on the social context of cloth from the Neolithic to Bronze Age with case studies from the Alpine area. One aspect of this is the interrelationship of the technologies used to create flexible, thin sheets of material that can be wrapped, folded, shaped and tied. This includes fibre-based cloth such as textiles, netting and twining as well as animal skins (leather and fur). This short report summarises preliminary research findings stemming from the examination of anima...

  7. Identification of ancient paths within the Late Bronze Age enclosure Corneşti-Iarcuri, western Romania

    Science.gov (United States)

    Nykamp, Moritz; Heeb, Bernhard S.; Hoelzmann, Philipp; Knitter, Daniel; Krause, Jan; Krause, Rüdiger; Szentmiklosi, Alexandru; Schütt, Brigitta

    2016-04-01

    This study applies a landscape archaeological approach, combining geoscientific and archaeological data, to shed light into the Holocene landscape development in the environs of the Late Bronze Age enclosure of Corneşti-Iarcuri, Romania. Corneşti-Iarcuri is located at the eastern edge of the Great Hungarian Plain and represents with its four earth-filled wooden ramparts the largest known prehistoric enclosure in Europe. Late Bronze Age settlements are documented for the two innermost enclosures. However, the settlement history in its environs started already in the Copper Age. The aims of this study are i) to link hydro-morphological relief anomalies to evidences of settlement occurrence and ii) to document the variations of Holocene geomorphic activity and stability in a selected sub-catchment. The spatio-temporal relation between unnaturally bending tributaries and settled areas is uncovered and the involved formation processes are discussed. The morphometric analyses of the tributaries in the built-up area of Iarcuri show a clear tendency: unnaturally bending tributaries most often occur in the central valley and tend to cluster in the central part between the two innermost enclosures. By comparison of the locations of the strongly bending tributaries and the locations of the most densely settled areas it appears that both are related. It is well known that such linear features form in relation to settlements as a consequence of repeated passage of humans. Due to soil compaction along regular footpaths and the resulting reduced infiltration capacity gully erosion tends to occur forming hollow ways. Usually these hollow ways form contemporaneously with or subsequent to the occupation period of the site. As a consequence alluvial fans form at the outlet of the tributaries documenting former settlement and geomorphic activities. A sediment core obtained from the alluvial fan dumped by the tributary sourcing in the densely settled southern part of enclosure II

  8. The crystal chemistry of the tetragonal tungsten-bronze: Ba6FeNb9O30

    International Nuclear Information System (INIS)

    Solid state reaction of BaCO3, FeC2O4 x 2 H2O and Nb2O5 gave single crystals of Ba6FeNb9O30. The crystal strucuture was solved by X-ray investigations (a = 12.597, c = 3.990 Ao, space group P4 bm - C4v2, Z = 1). Ba6FeNb9O30 crystallyzes in the tetragonal bronze type with a statistical distribution of Fe3+ and Nb5+ in the octahedral framework. The anisotropic temperature factors of barium are discussed with respect to the oxygen coordination. (Author)

  9. CONTRIBUTIONS TO THE STUDY OF THE VIBRATIONS FREQUENCY OF THE DRILL TOOL IN THE PROCESS OF MANUFACTURING THE BRONZE MATERIALS

    Directory of Open Access Journals (Sweden)

    Cosmin-Mihai MIRIŢOIU

    2013-05-01

    Full Text Available In this paper we present the experimental testings used to study the vibration of the drill tool, during the drilling of the bronze products. We have used the experimental setup presented in Miriţoiu (2013[1]. In this paper the vibrations are analyzed during the drilling on the universal lathe machines. The main purpose of to find a correlation between the cutting speed and the frequency of the vibration by using the experimental results and the regression analysis

  10. Increasing Mobility at the Neolithic/Bronze Age Transition - sulphur isotope evidence from Öland, Sweden

    OpenAIRE

    Anna Linderholm; Elin Fornander; Gunilla Eriksson; Carl-Magnus Mörth; Kerstin Lidén

    2014-01-01

    The objective of this investigation is to look at the use of various aquatic, in this case marine, resources in relation to mobility during the Neolithic and Bronze Age periods. On the island of Öland, in the Baltic Sea, different archaeological cultures are represented in the form of material culture and skeletal remains at three sites. We have analysed δ34S values in human remains representing 36 individuals, as well as faunal remains. We investigated intra-individual patterns of mobility f...

  11. Experimental determination of stability margin in a 27 strand bronze matrix, Nb3Sn cable-in-conduit conductor

    International Nuclear Information System (INIS)

    A small coil of internally cooled cabled superconductor was fabricated for experimental determination of the stability margin. The conductor is 27 strands of Nb3Sn in a bronze matrix. The sheath material is JBK-75 superalloy. The bifilar coil was potted in epoxy in the annulus of a pulse coil set. Experimental results are presented defining critical pulse energy as a function of normalized operating current and background field. The relationships between dB/dt, pulse energy and stability margin are derived by calculation and confirmed by experimental calibration

  12. Effect of microstructure on the mechanical and corrosion behaviors of a hot-extruded nickel aluminum bronze

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    In this paper,the influence of microstructure on the corrosion behavior of a hotextruded nickel aluminum bronze was studied.Three kinds of samples subjected to the hot-extrusion,annealing and quenching conditions were prepared and immersion tests in 3.5% NaCl solution were carried out.Microstructures and corrosion surface morphologies of the samples were observed by SEM.It was found that the retained β martensite and(α+κⅢ) lamella eutectoid in the as hot-extruded material were eliminated after annealing,and...

  13. Tribolayer Formation on Bronze Cu Sn12Ni2 in the Tribological Contact between Cy linder and Cont rol Plate in an Axial Piston Pump with Swashplate Design

    OpenAIRE

    Paulus, Andreas; Jacobs, Georg

    2016-01-01

    The present study investigates the f ormation of tribolayers on bronze CuSn12Ni2. Two different test rigs are used, of which one is a sliding bearing test rig in order to perform lubricated thrust bearing tests. Bronze CuSn12Ni2 is used for the sliding elements and the counter body is made of C45 steel. In addition to that, an axial piston pump test rig was used to determine t he transfera bility of the results to th e axial pist on pump. The test conditions are set up in a way t hat the trib...

  14. Methodology for the Construction of a Rule-Based Knowledge Base Enabling the Selection of Appropriate Bronze Heat Treatment Parameters Using Rough Sets

    Directory of Open Access Journals (Sweden)

    Górny Z.

    2015-04-01

    Full Text Available Decisions regarding appropriate methods for the heat treatment of bronzes affect the final properties obtained in these materials. This study gives an example of the construction of a knowledge base with application of the rough set theory. Using relevant inference mechanisms, knowledge stored in the rule-based database allows the selection of appropriate heat treatment parameters to achieve the required properties of bronze. The paper presents the methodology and the results of exploratory research. It also discloses the methodology used in the creation of a knowledge base.

  15. High-Performance Silver Window Electrodes for Top-Illuminated Organic Photovoltaics Using an Organo-molybdenum Oxide Bronze Interlayer.

    Science.gov (United States)

    Tyler, Martin S; Walker, Marc; Hatton, Ross A

    2016-05-18

    We report an organo-molybdenumn oxide bronze that enables the fabrication of high-performance silver window electrodes for top-illuminated solution processed organic photovoltaics without complicating the process of device fabrication. This hybrid material combines the function of wide-band-gap interlayer for efficient hole extraction with the role of metal electrode seed layer, enabling the fabrication of highly transparent, low-sheet-resistance silver window electrodes. Additionally it is also processed from ethanol, which ensures orthogonality with a large range of solution processed organic semiconductors. The key organic component is the low cost small molecule 3-mercaptopropionic acid, which (i) promotes metal film formation and imparts robustness at low metal thickness, (ii) reduces the contact resistance at the Ag/molybdenumn oxide bronze interface, (iii) and greatly improves the film forming properties. Silver electrodes with a thickness of 8 nm deposited by simple vacuum evaporation onto this hybrid interlayer have a sheet resistance as low as 9.7 Ohms per square and mean transparency ∼80% over the wavelength range 400-900 nm without the aid of an antireflecting layer, which makes them well-matched to the needs of organic photovoltaics and applicable to perovskite photovoltaics. The application of this hybrid material is demonstrated in two types of top-illuminated organic photovoltaic devices.

  16. Increasing Mobility at the Neolithic/Bronze Age Transition - sulphur isotope evidence from Öland, Sweden

    Directory of Open Access Journals (Sweden)

    Anna Linderholm

    2014-11-01

    Full Text Available The objective of this investigation is to look at the use of various aquatic, in this case marine, resources in relation to mobility during the Neolithic and Bronze Age periods. On the island of Öland, in the Baltic Sea, different archaeological cultures are represented in the form of material culture and skeletal remains at three sites. We have analysed δ34S values in human remains representing 36 individuals, as well as faunal remains. We investigated intra-individual patterns of mobility from childhood to adulthood, primarily focusing on a passage grave. Taking into account previously published dietary data that demonstrate a wide range of dietary practices involving aquatic resources, we applied a model to estimate the contribution of δ34S from terrestrial protein, to separate mobility from dietary changes, thereby identifying individuals who changed residence, as well as individuals with non-local origins. Evidence of mobility could be demonstrated at two sites. For the third site the consistently marine diet inhibits inferences on mobility based on δ34S analysis. Chronologically, the frequency of non-locals was highest during the Bronze Age, when the diet was very uniform and based on terrestrial resources.

  17. High-Performance Silver Window Electrodes for Top-Illuminated Organic Photovoltaics Using an Organo-molybdenum Oxide Bronze Interlayer.

    Science.gov (United States)

    Tyler, Martin S; Walker, Marc; Hatton, Ross A

    2016-05-18

    We report an organo-molybdenumn oxide bronze that enables the fabrication of high-performance silver window electrodes for top-illuminated solution processed organic photovoltaics without complicating the process of device fabrication. This hybrid material combines the function of wide-band-gap interlayer for efficient hole extraction with the role of metal electrode seed layer, enabling the fabrication of highly transparent, low-sheet-resistance silver window electrodes. Additionally it is also processed from ethanol, which ensures orthogonality with a large range of solution processed organic semiconductors. The key organic component is the low cost small molecule 3-mercaptopropionic acid, which (i) promotes metal film formation and imparts robustness at low metal thickness, (ii) reduces the contact resistance at the Ag/molybdenumn oxide bronze interface, (iii) and greatly improves the film forming properties. Silver electrodes with a thickness of 8 nm deposited by simple vacuum evaporation onto this hybrid interlayer have a sheet resistance as low as 9.7 Ohms per square and mean transparency ∼80% over the wavelength range 400-900 nm without the aid of an antireflecting layer, which makes them well-matched to the needs of organic photovoltaics and applicable to perovskite photovoltaics. The application of this hybrid material is demonstrated in two types of top-illuminated organic photovoltaic devices. PMID:27135377

  18. Aluminum Bronze Alloys to Improve the System Life of Basic Oxygen and Electric Arc Furnace Hoods, Roofs and Side Vents.

    Energy Technology Data Exchange (ETDEWEB)

    Lawrence C. Boyd Jr.; Dr. Vinod K. Sikka

    2006-12-29

    Energy Industries of Ohio was the lead organization for a consortium that examined the current situation involving the service life of electric arc and basic oxygen furnace hoods, roofs and side vents. Republic Engineered Products (REP), one of the project partners, installed a full-scale Al-Bronze “skirt” in their BOF at their Lorain OH facility, believed to be the first such installation of this alloy in this service. In 24 months of operation, the Al-Bronze skirt has processed a total of 4,563 heats, requiring only 2 shutdowns for maintenance, both related to physical damage to the skirt from operational mishaps. Yearly energy savings related to the REP facility are projected to be ~ 10 billion Btu's with significant additional environmental and productivity benefits. In recognition of the excellent results, this project was selected as the winner of the Ohio’s 2006 Governor’s Award for Excellence in Energy, the state’s award for outstanding achievements in energy efficiency.

  19. Manufacture technique of bronze-iron bimetallic objects found in M27 of Liangdaicun Site, Hancheng, Shaanxi

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Analysis of the fabrication technology of a bronze knife with an iron blade and a bronze Ge with an iron blade, two copper-iron bimetallic wares, unearthed in M27 of Liangdaicun Site, Hancheng of Shaanxi, is performed in this paper by using metallographic, EPMA and AMS-14C dating methods. The micro-structures of the two samples are typical wrought bloomery iron containing a substantial amount of carbon, which is also called carburized steel, made from bloomery iron by cementation in the solid state. The objects can be dated back to the early Spring and Autumn period. This study provides new evidence for understanding the beginning of iron smelting in China. Most of the early known iron wares of the period between the late Western Zhou Dynasty and the early Spring and Autumn were unearthed in the region at the junction of Henan, Shanxi and Shaanxi, at the middle reaches of the Yellow River, suggesting that this region may likely be one of the earliest centers of iron smelting technology in China and deserves further archaeological research. As early iron products were also discovered in the area of the upper reaches of the Yellow River and in Xinjiang, appropriate attention also should be paid to the relationship between these two areas in terms of the origin of iron smelting.

  20. Health-hazard evaluation report HETA-88-244-1951, Orrville Bronze and Aluminum Company, Orrville, Ohio

    Energy Technology Data Exchange (ETDEWEB)

    Montopoli, M.; Seligman, P.; O' Brien, D.; Zaebst, D.

    1989-03-01

    An investigation was made of possible hazardous working conditions at the Orrville Bronze and Aluminum Company, Orrville, Ohio. Medical screening at the site had recently discovered a worker with a blood lead level in excess of 100 micrograms/deciliter (microg/dl) and seven workers with blood lead levels in excess of 40 microg/dl. The facility was a nonferrous foundry specializing in small- to medium-sized bronze, brass, and copper castings. Lead concentrations in six personal breathing-zone samples ranged from 38 to 520 micrograms/cubic meter (microg/m{sup 3}). Airborne copper levels ranged from 26 to 2601 microg/m{sup 3}. Airborne zinc concentrations ranged from 291 to 3165 microg/m{sup 3}. Three of 18 workers had blood lead levels in excess of 60 microg/m{sup 3}, the OSHA level which requires immediate medical removal protection. The report concludes that lead and copper exposures represented a serious health hazard to workers. Measures to reduce exposures, including engineering controls, work practices, and housekeeping are recommended.

  1. Particle size and kind of mica in synthesis of nontoxic bronze and gold pearlescent pigments based on nanoencapsulated hematite

    Directory of Open Access Journals (Sweden)

    Maryam Hosseini-Zori

    2015-12-01

    Full Text Available Nano-encapsulated iron oxide in Zirconium oxide-coated mica pigments are thermally stable,innocuous to human health, non-combustible, and they do not conduct electricity. They could beapplied in several industries such as thermoplastics, cosmetics, food packaging, children toys, paints,automobiles coating, security purposes, and banknotes. Nowadays, they are highly desirable inceramic decoration. In the present study, intensively dark gold to bronze colored mica clay pigments,which were based on mica flakes covered with a layer of nano-iron oxide-Zirconium oxide particles,were prepared by homogeneous precipitation of iron nitrate and Zirconium chloride ammonia in thepresence of mica flakes in two kinds of ore clay-based phlogopite and muscovite minerals. The finalcolor was obtained by thermal annealing of precipitates at a temperature of 800◦C. The pigments werecharacterized by X-Ray Diffraction, Particle size analysis, Scanning electron microscopy,Transmission electron microscopy, X-Ray fluorescence, and Simultaneous thermal analysis. Resultsindicate that nano-encapsulated iron oxide in zirconia particles have been formed on mica flakes andkinds of clay-mica can be related to obtained shade from dark gold to bronze pearl. Higher particlesize of mica flakes about phlogopite type of mica introduced pearl effects with higher L* changes indifferent angles. Muscovite performed higher hue and better pearl effect than phlogopite.

  2. Regional models of metal production in Western Asia in the Chalcolithic, Early and Middle Bronze Ages

    Directory of Open Access Journals (Sweden)

    Avilova, Liudmila

    2008-06-01

    Full Text Available The objective of this work is the reconstruction and comparative analysis of regional models of metal production in the Chalcolithic, Early and Middle Bronze Ages. The work is based on the statistical analysis of unique computer database on archaeological metal finds from four regions of the Near East: Anatolia, Mesopotamia, the Levant, and Iran. The materials are analysed by four indicators: distribution by the chronological periods, artefacts’ function, proportion of used metals and copper- based alloys. The author presents a series of conclusions concerning the preconditions for the beginnings of metal production in Western Asia and the pioneering role of Iran in its emergence, the important role the piedmont territories played in the development of metal production, the leap-like pattern of production dynamics shown by the periods, and its relation to the spread of a producing economy, long-distance exchange, and the emergence of the early civilizations.

    El objetivo de este trabajo es la reconstrucción y análisis comparativo de modelos regionales de producción metalúrgica del Calcolítico y la Edad del Bronce Inicial y Media. Se basa en el análisis estadístico de una base de datos única sobre hallazgos metálicos de cuatro regiones del Próximo Oriente: Anatolia, Mesopotamia, el Levante e Irán. Los materiales se analizan atendiendo a cuatro variables: períodos cronológicos, función de los artefactos, proporción de los metales usados y las distintas aleaciones del cobre. La autora aporta una serie de conclusiones respecto a las precondiciones para los inicios de la producción metalúrgica en el Oeste Asiático; sobre el papel pionero de Irán en su aparición; la importancia de los piedemontes en su desarrollo; el patrón no continuo que se observa en las dinámicas de producción por periodos; y su relación con la expansión de la economía de producción, el intercambio a larga distancia y la aparición de las

  3. Effect of two-stage isothermal annealing on microstructure CuAl10Fe5Ni5 bronze with additions of Si, Cr, Mo, W and C

    Directory of Open Access Journals (Sweden)

    B. P. Pisarek

    2011-07-01

    Full Text Available The aim of this study was to investigate the effect of a two-step isothermal annealing respectively at 1000 ̊C for 30 min, then at the range of 900÷450 ̊C increments 50 ̊C on the microstructure CuAl10 Ni5Fe5 bronze with additions of Si, Cr, Mo, W and C, cast into sand moulds. The study concerned the newly developed species, bronze, aluminium-iron-nickel with additions of Si, Cr, Mo, W and C. In order to determine the time and temperature for the characteristic of phase transitions that occur during heat treatment of the test method was used thermal and derivation analysis (TDA. The study was conducted on cylindrical test castings cast in the mould of moulding sand. It was affirmed that one the method TDA can appoint characteristic for phase transformations points about co-ordinates: τ (s, t ( ̊ C, and to plot out curves TTT for the studied bronze with their use. It was also found that there is a fiveisothermalannealingtemperatureranges significantly altering the microstructure of examined bronze.

  4. Robust date for the Bronze Age Avellino eruption (Somma-Vesuvius) : 3945 +/- 10 calBP (1995 +/- 10 calBC)

    NARCIS (Netherlands)

    Sevink, Jan; van Bergen, Manfred J.; van der Plicht, Johannes; Feiken, Hendrik; Anastasia, Carmela; Huizinga, Annika; Maroto, Julià; Vaquero, Manuel; Arrizabalaga, Álvaro; Baena, Javier; Baquedano, Enrique; Jordá, Jesús; Julià, Ramon; Montes, Ramón; Rasines, Pedro; Wood, Rachel; Walsma, A.

    2011-01-01

    We found Bronze Age lake sediments from the Agro Pontino graben (Central Italy) to contain a thin (2-3 cm) continuous tephra layer composed of lithics, crystals and minor volcanic glass. Tephrochronological and compositional constraints strongly suggest that this layer represents the Avellino pumice

  5. Quantitative Analysis of the Combined Funeral Bronze Vessels from Zhou Tombs%两周墓葬青铜容器随葬组合定量分析

    Institute of Scientific and Technical Information of China (English)

    吴十洲

    2001-01-01

    The present paper makes a quantitative analysis of the combined bronze vessels from Zhou tombs by means of the mathematical statistical method. The work is based mainly on the archaeo-logical data related to the date and size (area of tomb-chambers) of the Zhou tombs, the cultural regionto which the Zhou tombs belong, and the tomb-owners' status known from inscriptions in the Zhou tombsthemselves, taking this information as marks for grouping (independent variables) . On the basis ofstatistics by the group, calculations of variable data are carried out to find out the number of the dingtripods used in different groups of tombs, that of the combinations of ding with other bronze vessels, andthat of the combinations of practical vessels with specially-made funeral ones (functions) . Through thisanalysis important data have been obtained as to the movement of the variables related to the combinationof funeral bronze vessels in Zhou tombs. As a result, it has been understood whether there is any relationbetween the nature of tombs and the combination of funeral bronze vessels in the movement of valuablesand what degree this relationship stands at.

  6. A unique late bronze age copper fish-hook from Bet Dwarka Island, Gujarat, west coast of India: Evidence on the advance fishing technology in ancient India

    Digital Repository Service at National Institute of Oceanography (India)

    Gaur, A.S.; Sundaresh

    correspondence. e - mail: jprao2001@hotmail.com A unique Late Bronze Age copper fish - hook from Bet Dwarka Island, Gujarat, west coast of India: Evidence on the advance fis h ing technology in ancient India There are numerous evidences of the e...

  7. Genetic diversity in population of largemouth bronze gudgeon (Coreius guichenoti Sauvage et Dabry) from Yangtze River determined by microsatellite DNA analysis.

    Science.gov (United States)

    Zhang, Futie; Tan, Deqing

    2010-01-01

    Largemouth bronze gudgeon (Coreius guichenoti Sauvage et Dabry 1874), one of the endemic fish species in the upper reaches of the Yangtze River in China, is a benthic and potamodromous fish that is typically found in rivers with torrential flow. Three dams in the Yangtze River, Ertan Dam, Three Gorges Dam and Gezhouba Dam, may have had vital impacts on the habitat and spawning behaviors of largemouth bronze gudgeon, and could ultimately threaten the survival of this fish. We studied the population genetic diversity of C. guichenoti samples collected at seven sites (JH, GLP, BX, HJ, MD, SDP and XB) within the Yangtze River and one of its tributaries, the Yalong River. Genetic diversity patterns were determined by analyzing genetic data from 11 polymorphic microsatellite loci. A high genetic diversity among these largemouth bronze gudgeon populations was indicated by the number of microsatellite alleles (A) and the expected heterozygosity (HE). No significant population variation occurred among GLP, BX, HJ and MD populations, but dramatic population differentiation was observed among JH and XB, two dam-blocked populations, versus other populations. Tests for bottlenecks did not indicate recent dramatic population declines and concurrent losses of genetic diversity in any largemouth bronze gudgeon populations. To the contrary, we found that dams accelerated the population differentiation of this fish. PMID:21317547

  8. The influence of wall thickness on the microstructure of bronze BA1055 with the additions of Si, Cr, Mo and/or W

    Directory of Open Access Journals (Sweden)

    B.P. Pisarek

    2008-12-01

    Full Text Available Aluminium bronzes belong to the high-grade constructional materials applied on the put under strongly load pieces of machines, about good sliding, resistant properties on corrosion both in the cast state how and after the thermal processing. It moves to them Cr and Si in the aim of the improvement of their usable proprieties. Additions Mo and/or W were not applied so far in the larger concentration, these elements were introduced to the melts of the copper as the components of modifiers. It was worked out therefore the new kind of bronzes casting including these elements. Make additions to the Cu-Al-Fe-Ni bronze of Si, Cr, Mo and/or W in the rise of these properties makes possible. The investigations of the influence of the wall thickness of the cast on size of crystallites were conducted: the primary phase β and intermetallic phase κ and the width separates of the secondary phase α precipitate at phase boundary. It results from conducted investigations, that in the aluminium bronze BA1055 after simultaneous makes additions Si, Cr, Mo and in the primary phase β it undergoes considerable reducing size. The addition W reduce size of the grain phase β in the thin walls of the cast 3-6 mm, and addition Cr in the range of the thickness of the wall of the cast 3-6 mm it favors to reducing size the phase β, in walls 12-25 mm the growth causes it. The addition Mo does not influence the change of the size of the grain of the β phase significantly. The make addition singly or simultaneously of the Cr, Mo and W to the bronze CuAl10Fe5Ni5Si it influences the decrease of the quantity separates of the phase α on the interface boundary and of width it separates independently from the thickness of the wall of the cast. The simultaneous make addition of the Si, Cr, Mo and W it enlarges the surface of the phase κFe, κMo. The make addition to the bronze CuAl10Fe5Ni5Si of the Cr, Mo or W the quantity of crystallizing hard phase κ enlarges and the

  9. 河南偃师市二里头遗址发现一件青铜钺%A Bronze Yue Battle-axe Discovered on the Erlitou Site in Yanshi City, Henan

    Institute of Scientific and Technical Information of China (English)

    中国社会科学院考古研究所二里头工作队

    2002-01-01

    A bronze yue battle-axe was picked up in Area Ⅲ of the Erlitou site in June 2000.It has a rectangular plan and seems to come from a tomb.Judging from the shape and the style of decoration,it must be of the late Erlitou culture.This is the earliest among the Chinese bronze yue so far discovered.Metallographical examination and composition analysis reveals that it is made of bronze with low tin content and cast in a double mould.X-ray photography shows insufficient in the compactness of its body structure and other defects,which resulted from a certain primitiveness of its casting technology.

  10. Final report of the key comparison CCQM-K98: Pb isotope amount ratios in bronze

    Science.gov (United States)

    Vogl, Jochen; Yim, Yong-Hyeon; Lee, Kyoung-Seok; Goenaga-Infante, Heidi; Malinowskiy, Dmitriy; Ren, Tongxiang; Wang, Jun; Vocke, Robert D., Jr.; Murphy, Karen; Nonose, Naoko; Rienitz, Olaf; Noordmann, Janine; Näykki, Teemu; Sara-Aho, Timo; Ari, Betül; Cankur, Oktay

    2014-01-01

    Isotope amount ratios are proving useful in an ever increasing array of applications that range from studies unravelling transport processes, to pinpointing the provenance of specific samples as well as trace element quantification by using isotope dilution mass spectrometry (IDMS). These expanding applications encompass fields as diverse as archaeology, food chemistry, forensic science, geochemistry, medicine and metrology. However, to be effective tools, the isotope ratio data must be reliable and traceable to enable the comparability of measurement results. The importance of traceability and comparability in isotope ratio analysis has already been recognized by the Inorganic Analysis Working Group (IAWG) within the CCQM. While the requirements for isotope ratio accuracy and precision in the case of IDMS are generally quite modest, 'absolute' Pb isotope ratio measurements for geochemical applications as well as forensic provenance studies require Pb isotope ratio measurements of the highest quality. To support present and future CMCs on isotope ratio determinations, a key comparison was urgently needed and therefore initiated at the IAWG meeting in Paris in April 2011. The analytical task within such a comparison was decided to be the measurement of Pb isotope amount ratios in water and bronze. Measuring Pb isotope amount ratios in an aqueous Pb solution tested the ability of analysts to correct for any instrumental effects on the measured ratios, while the measurement of Pb isotope amount ratios in a metal matrix sample provided a real world test of the whole chemical and instrumental procedure. A suitable bronze material with a Pb mass fraction between 10 and 100 mg•kg-1 and a high purity solution of Pb with a mass fraction of approximately 100 mg•kg-1 was available at the pilot laboratory (BAM), both offering a natural-like Pb isotopic composition. The mandatory measurands, the isotope amount ratios n(206Pb)/n(204Pb), n(207Pb)/n(204Pb) and n(208Pb)/n(204Pb

  11. Specific corrosion product on interior surface of a bronze wine vessel with loop-handle and its growth mechanism, Shang Dynasty, China

    Energy Technology Data Exchange (ETDEWEB)

    Li Yang; Bao Zhirong; Wu Taotao [School of Physics and Technology, Center for Electron Microscopy and MOE Key Laboratory of Artificial Micro- and Nano-structures, Wuhan University, Wuhan 430072 (China); Jiang, Junchun [Xiaogan Museum, Xiaogan 432000 (China); Chen Guantao [Center for Archaeometry, Wuhan University, Wuhan 430072 (China); Pan Chunxu, E-mail: cxpan@whu.edu.cn [School of Physics and Technology, Center for Electron Microscopy and MOE Key Laboratory of Artificial Micro- and Nano-structures, Wuhan University, Wuhan 430072 (China); Center for Archaeometry, Wuhan University, Wuhan 430072 (China)

    2012-06-15

    In this paper, a kind of specific stalactitic product was found on the interior surface of a covered bronze wine vessel with loop-handle (Chinese name is you), which was fabricated in Shang Dynasty (1700 B.C.-1100 B.C.) and now is collected in Xiaogan Museum, Hubei province of China. The microstructures of the product were characterized systematically by using optical microscopy, scanning electron microscope, transmission electron microscope, X-ray diffraction, and Raman microscopy. The experimental results revealed that the product belonged to a kind of malachite with high purity and high crystallinity. The growth of the product was considered to be a possible reason that the vessel was overly airtight within a museum display cabinet besides a lid of the vessel, which made the excess of H{sub 2}O and CO{sub 2} gas concentrations inside the vessel during long-term storage. This corrosion product is very harmful to bronze cultural relics, because of a large amount of copper consumption from the matrix which will reduce its life. The growth mechanism of the specific stalactitic product and the suggestions for preservation of the similar bronze relics in museum were proposed. - Highlights: Black-Right-Pointing-Pointer The stalactitic product was the high purity and good crystallinity malachite. Black-Right-Pointing-Pointer Its growth was related to the excess of H{sub 2}O and CO{sub 2} gas concentrations in museum. Black-Right-Pointing-Pointer It is harmful to the bronzes, because copper will be consumed from the matrix. Black-Right-Pointing-Pointer The suggestions for preservation of the similar bronzes in museum were proposed.

  12. Specific corrosion product on interior surface of a bronze wine vessel with loop-handle and its growth mechanism, Shang Dynasty, China

    International Nuclear Information System (INIS)

    In this paper, a kind of specific stalactitic product was found on the interior surface of a covered bronze wine vessel with loop-handle (Chinese name is you), which was fabricated in Shang Dynasty (1700 B.C.–1100 B.C.) and now is collected in Xiaogan Museum, Hubei province of China. The microstructures of the product were characterized systematically by using optical microscopy, scanning electron microscope, transmission electron microscope, X-ray diffraction, and Raman microscopy. The experimental results revealed that the product belonged to a kind of malachite with high purity and high crystallinity. The growth of the product was considered to be a possible reason that the vessel was overly airtight within a museum display cabinet besides a lid of the vessel, which made the excess of H2O and CO2 gas concentrations inside the vessel during long-term storage. This corrosion product is very harmful to bronze cultural relics, because of a large amount of copper consumption from the matrix which will reduce its life. The growth mechanism of the specific stalactitic product and the suggestions for preservation of the similar bronze relics in museum were proposed. - Highlights: ► The stalactitic product was the high purity and good crystallinity malachite. ► Its growth was related to the excess of H2O and CO2 gas concentrations in museum. ► It is harmful to the bronzes, because copper will be consumed from the matrix. ► The suggestions for preservation of the similar bronzes in museum were proposed.

  13. A brief analysis of the development of bronze yan's structure and shape%简述青铜形制的时代发展

    Institute of Scientific and Technical Information of China (English)

    胡纬; 解洪兴

    2015-01-01

    青铜器为我国古代重要的礼器,每个时期都有不同的特点。青铜是我国古代重要的炊食器。其在各个时代的造型、特征纹饰都有那个时代的特征。通过对各个时期青铜实物的分析与研究,探究其内在的含义,对其纹饰,造型以及其作为礼器的地位的上升与下降,对我们来分析青铜作为礼器在我国古代社会的重要地位及了解青铜的时代特征,具有十分重要的意义。%As a most important kind of ritual vessel in ancient China,bronze ware has different features in different period in history.The bronze Yan is a important kind of kitchen ware in ancient times, which possess the features of mould and sculpture in the corresponding time.The analysis and research into the bronze Yan in kind of every period, the exploration of bronze Yan’s inherent meaning, and the study of its sculpture,mould as well as the change its position are of great significance for us to analyze the important position and comprehend the characteristics of the times of bronze Yan in ancient China.

  14. Apport de l'analyse statistique de la composition des produits de corrosion à la compréhension des processus de dégradation des bronzes archéologiques (Contribution of statistical analysis of corrosion products to the understanding of the degradation processes of archaeological bronzes)

    OpenAIRE

    Robbiola, Luc; Fiaud, Christian

    1992-01-01

    L'analyse élémentaire des composés de corrosion de trois bronzes monophasés, représentatifs d'un corpus d'objets de l'Age du Bronze, a été effectuée par microanalyse X sur microscope électronique à balayage. Les varations de teneurs en principaux éléments chimiques dans les couches de corrosion ont été caractérisés. Un modèle de formation des deux principales structures de corrosion des bronzes archéologiques enfouis est proposé. La dissolution sélective du cuivre de l'alliage peut être contr...

  15. Early atmospheric metal pollution provides evidence for Chalcolithic/Bronze Age mining and metallurgy in Southwestern Europe.

    Science.gov (United States)

    Martínez Cortizas, Antonio; López-Merino, Lourdes; Bindler, Richard; Mighall, Tim; Kylander, Malin E

    2016-03-01

    Although archaeological research suggests that mining/metallurgy already started in the Chalcolithic (3rd millennium BC), the earliest atmospheric metal pollution in SW Europe has thus far been dated to ~3500-3200 cal.yr. BP in paleo-environmental archives. A low intensity, non-extensive mining/metallurgy and the lack of appropriately located archives may be responsible for this mismatch. We have analysed the older section (>2100 cal.yr. BP) of a peat record from La Molina (Asturias, Spain), a mire located in the proximity (35-100 km) of mines which were exploited in the Chalcolithic/Bronze Age, with the aim of assessing evidence of this early mining/metallurgy. Analyses included the determination of C as a proxy for organic matter content, lithogenic elements (Si, Al, Ti) as markers of mineral matter, and trace metals (Cr, Cu, Zn, Pb) and stable Pb isotopes as tracers of atmospheric metal pollution. From ~8000 to ~4980 cal.yr. BP the Pb composition is similar to that of the underlying sediments (Pb 15 ± 4 μg g(-1); (206)Pb/(207)Pb 1.204 ± 0.002). A sustained period of low (206)Pb/(207)Pb ratios occurred from ~4980 to ~2470 cal.yr. BP, which can be divided into four phases: Chalcolithic (~4980-3700 cal.yr. BP), (206)Pb/(207)Pb ratios decline to 1.175 and Pb/Al ratios increase; Early Bronze Age (~3700-3500 cal.yr. BP), (206)Pb/(207)Pb increase to 1.192 and metal/Al ratios remain stable; Late Bronze Age (~3500-2800 cal.yr. BP), (206)Pb/(207)Pb decline to their lowest values (1.167) while Pb/Al and Zn/Al increase; and Early Iron Age (~2800-2470 cal.yr. BP), (206)Pb/(207)Pb increase to 1.186, most metal/Al ratios decrease but Zn/Al shows a peak. At the beginning of the Late Iron Age, (206)Pb/(207)Pb ratios and metal enrichments show a rapid return to pre-anthropogenic values. These results provide evidence of regional/local atmospheric metal pollution triggered by the earliest phases of mining/metallurgy in the area, and reconcile paleo-environmental and

  16. Early atmospheric metal pollution provides evidence for Chalcolithic/Bronze Age mining and metallurgy in Southwestern Europe.

    Science.gov (United States)

    Martínez Cortizas, Antonio; López-Merino, Lourdes; Bindler, Richard; Mighall, Tim; Kylander, Malin E

    2016-03-01

    Although archaeological research suggests that mining/metallurgy already started in the Chalcolithic (3rd millennium BC), the earliest atmospheric metal pollution in SW Europe has thus far been dated to ~3500-3200 cal.yr. BP in paleo-environmental archives. A low intensity, non-extensive mining/metallurgy and the lack of appropriately located archives may be responsible for this mismatch. We have analysed the older section (>2100 cal.yr. BP) of a peat record from La Molina (Asturias, Spain), a mire located in the proximity (35-100 km) of mines which were exploited in the Chalcolithic/Bronze Age, with the aim of assessing evidence of this early mining/metallurgy. Analyses included the determination of C as a proxy for organic matter content, lithogenic elements (Si, Al, Ti) as markers of mineral matter, and trace metals (Cr, Cu, Zn, Pb) and stable Pb isotopes as tracers of atmospheric metal pollution. From ~8000 to ~4980 cal.yr. BP the Pb composition is similar to that of the underlying sediments (Pb 15 ± 4 μg g(-1); (206)Pb/(207)Pb 1.204 ± 0.002). A sustained period of low (206)Pb/(207)Pb ratios occurred from ~4980 to ~2470 cal.yr. BP, which can be divided into four phases: Chalcolithic (~4980-3700 cal.yr. BP), (206)Pb/(207)Pb ratios decline to 1.175 and Pb/Al ratios increase; Early Bronze Age (~3700-3500 cal.yr. BP), (206)Pb/(207)Pb increase to 1.192 and metal/Al ratios remain stable; Late Bronze Age (~3500-2800 cal.yr. BP), (206)Pb/(207)Pb decline to their lowest values (1.167) while Pb/Al and Zn/Al increase; and Early Iron Age (~2800-2470 cal.yr. BP), (206)Pb/(207)Pb increase to 1.186, most metal/Al ratios decrease but Zn/Al shows a peak. At the beginning of the Late Iron Age, (206)Pb/(207)Pb ratios and metal enrichments show a rapid return to pre-anthropogenic values. These results provide evidence of regional/local atmospheric metal pollution triggered by the earliest phases of mining/metallurgy in the area, and reconcile paleo-environmental and

  17. Reconstructing the Palaeogeographies of a Neolithic - Bronze Age Settlement Mound at Ephesos, Turkey

    Science.gov (United States)

    Ehlers, Lisa; Friederike, Stock; Barbara, Horejs; Helmut, Brückner

    2014-05-01

    Although Ephesos and its surroundings has long been an area of archaeological interest and investigations, the focus has mainly been on sites related to Antiquity and Late Antiquity. Until recently systematic research concerning prehistoric phases of occupation within this region have been lacking. Due to the growing interest in these time periods along the West Anatolian coast, archaeological research projects involving the study of the newly discovered prehistoric settlement mounds located in the vicinity of the prominent ancient city were initiated. The aim of this study was to examine the palaeogeographical and geoarchaeological contexts of the mound (tell), Çukuriçi Höyük, in order to determine the thickness and age of the settlement layers as well as the spatial extent of the tell throughout the different periods of settlement. As additional research to the excavations, 20 sediment cores drilled on and around Çukuriçi Höyük were examined and their physical and geochemical properties as well as existing data were used to reconstruct the palaeoenvironment. The chronostratigraphy relies on AMS-14C ages and findings of diagnostic ceramics; a further attempt was made by luminescence dating. The results reveal that the inhabitants intentionally choose the location due to the beneficial topography, initially, i.e. during Pottery Neolithic times in the early 7th mill. BC, lying upon an elevation within a fertile alluvial plain about 1.5-2 km away from the coast. It seems that during the time of settling (Pottery Neolithic - Early Bronze Age) several rivers flowed in the direct vicinity of the tell. The elevated terrain provided the inhabitants security from the torrents. In addition, the corings reveal that the tell covers an area of about 11,000 m2 and a thickness of settlement layers of c. 8 m. Finally, as a possible result of water management conducted by the inhabitants, sediments related to low-energy depositional conditions are identified at the foot of

  18. Environmental impact of copper mining and metallurgy during the Bronze Age at Kargaly (Orenburg region, Russia

    Directory of Open Access Journals (Sweden)

    Vicent García, Juan Manuel

    2010-12-01

    Full Text Available Kargaly (Orenburg, Russia is a copper-producing region in which two main phases of mining activity have taken place: the 4th-2nd millennia BC and the 18th-20th centuries AD. This article is a comparative study on the impact of those mining episodes in the distribution of the forest resources in the region, aimed to estimate the scale of prehistoric mining and metallurgical works. For that purpose two paleopalinological sequences obtained from natural deposits located in Kargaly are analysed by inferential Statistics and Multivariate Methods. The results are compared both with a regional sampling of recent pollen rain supported by an analytical model of the present day landscape, and with the anthracological data coming from the Late Bronze Age settlement of Gorny 1. Analysis confirm the large scale of the prehistoric mining impact on the forest cover from the beginnings, as well as the strong effect of husbandry once mining works ended. These results allow us to dismiss a climatic change as main explanation for the detected diachronic variability in the palinological record. They also prove the viability of the proposed approach as a means of integrating the paleoenvironmental disciplines in Landscape Archaeology.

    Kargaly (región de Orenburgo, Rusia es una región cuprífera explotada entre los milenios IV y II cal BC y los siglos XVIII y XX d.C. El objetivo del artículo es estudiar comparativamente el impacto de estos episodios mineros en la distribución de los recursos forestales de la región, para aproximar la escala de las operaciones minero-metalúrgicas prehistóricas. Para ello se analizan con métodos estadísticos inferenciales y multivariantes dos secuencias paleopalinológicas procedentes de depósitos naturales de la región y se comparan con un muestreo regional de la lluvia polínica reciente apoyado por un modelo analítico del paisaje actual y con los datos antracol

  19. Solvothermal Synthesis of Caesium Tungsten Bronze in the Presence of Various Organic Acids and Its NIR Absorption Properties

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Chongshen; Yin, Shu; Sato, Tsugio [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai (Japan); Adachi, Kenji; Chonan, Takeshi, E-mail: bigguop@mail.tagen.tohoku.ac.jp [Ichikawa Research Laboratory, Sumitomo Metal Mining Co., Ltd (Japan)

    2011-10-29

    Nanoparticles of caesium tungsten bronze were successfully synthesized by solvothermal reactions in ethanol with the introduction of different organic fatty acids with various carbon numbers of 1 to 5. Compared to the sample prepared in pure ethanol, the samples obtained by mixed solvent of ethanol and fatty acids showed higher production yield, smaller particle size, more uniform particles size distribution and higher Cs/W atomic ratio. In addition, all of samples obtained using acids-ethanol mixed solvent exhibited higher visible light transmittance and greater NIR absorption performance, indicating the potential application for smart window and heat-ray shielding materials. The addition of acetic acid showed the best performance to facilitate the formation of well dispersed Cs{sub x}WO{sub 3} regular nanorods, leading to its excellent optical properties.

  20. Stable Carbon Isotope Evidence for Neolithic and Bronze Age Crop Water Management in the Eastern Mediterranean and Southwest Asia.

    Directory of Open Access Journals (Sweden)

    Michael P Wallace

    Full Text Available In a large study on early crop water management, stable carbon isotope discrimination was determined for 275 charred grain samples from nine archaeological sites, dating primarily to the Neolithic and Bronze Age, from the Eastern Mediterranean and Western Asia. This has revealed that wheat (Triticum spp. was regularly grown in wetter conditions than barley (Hordeum sp., indicating systematic preferential treatment of wheat that may reflect a cultural preference for wheat over barley. Isotopic analysis of pulse crops (Lens culinaris, Pisum sativum and Vicia ervilia indicates cultivation in highly varied water conditions at some sites, possibly as a result of opportunistic watering practices. The results have also provided evidence for local land-use and changing agricultural practices.

  1. Reconstructing hidden landscapes. DC and EM prospections in the Terramara Santa Rosa (bronze age settlement - northern Italy)

    Science.gov (United States)

    Mele, M.; Cremaschi, M.; Giudici, M.; Bassi, A.; Pizzi, C.; Lozej, A.

    2012-04-01

    The Terramara Santa Rosa is an archaeological site, located in the Po alluvial plain (northern Italy), which has been explored since 1986. As as seen by aerial photograph, Santa Rosa site is constituted by two moated villages of the Middle and Late Bronze Ages (1600-1150 BC), delimited by earth rampart. The smaller and older settlement (Villaggio Piccolo; VP), to the North, has a nearly circular shape and was founded during the Middle Bronze age, whereas the larger and younger one, delimited by a wide U-shaped rampart, is mostly dates to the Recent Bronze age. These settlements are surrounded by wide, asymmetrical moats, smooth and gradual on the exterior, steep and inaccessible on the village side, running parallel to the villages fences and being part of a complex hydraulic system; stratigraphic excavation involved the VP, at the transition between the VG and the hydraulic system, to the South. As the Bronze landscape is today sealed by flood plain clays, up to 3-4 m thick, which hide the archeological features and constitutes the present-day topography, a large-scale geophysical survey was planned to integrate to map the buried structure of the settlements and surrounding areas and to yield useful information to plan future archeological excavations. At this purpose, Direct Current Electrical Resistivity Imaging (ERI) and Electro-Magnetic Induction (EMI) geophysical prospections were applied to reveal the near-surface, lateral and vertical heterogeneities in order to improve the likelihood of locating the villages, the moats and other hidden targets in the surroundings. 70 ERI profiles, with Wenner and Wenner-Schlumberger array were collected with roll-along technique and electrode spacing ranging from 1 m to 3 m, for an exploration depth of 15 m below the ground surface and a total length greater than 9000 m. EMI survey was conducted over a 16 ha wide area in order to map shallow heterogeneities at the entire site scale. Data acquisition was conducted with a

  2. Letti in bronzo. Dal modello ellenistico alla Cisalpina romana Bronze beds. From hellenistic model to the Roman Cisalpine

    Directory of Open Access Journals (Sweden)

    Federica Giacobello

    2011-03-01

    Full Text Available

    Il contributo presenta una panoramica generale su una particolare e pregiata classe di arredi domestici quali sono i letti con decorazione in bronzo in età romana. Partendo dai modelli greco-ellenistici  e dalla loro introduzione a Roma, ci si sofferma sulla loro tipologia e sugli elementi da cui erano costituiti, per quindi affrontare nello specifico le problematiche inerenti a ritrovamenti di letti in bronzo in Cisalpina.

    Pezzi eccezionale per completezza e realizzazione sono le gambe di letto tricliniare rinvenute a Modena da una ricca domus della città; tali esemplari, già oggetto di studi ricostruttivi, sono in questa sede esaminati in particolare per la scena plastica che li decorava che presenta l’ immagine di Ercole contro il Centauro. L’ipotesi avanzata è che possa essere una testimonianza della propaganda per immagini di Antonio in un frangente particolare quali le lotte civili che interessarono i territori dell’Italia settentrionale nella tarda repubblica.

    The paper presents a general overview of a particular class and fine home furnishings such as beds decorated with bronze in the roman age. Starting from the hellenistic and greek models since their introduction in Rome, we focus on types and elements from which they then set up, to address the specific issues related to discovery of a bronze bed in Cisalpine.

    Exceptional objects s for completeness and achievement are the legs of bed tricliniar found in Modena in a rich domus of the city; such furniture, already the subject of reconstruction studies, are here examined particularly in the plastic scene which they decorated that has the image of Hercules against the Centaur. The hypothesis is that it can be a testimony to the propaganda images of Antonio in a particular juncture that the civil strife that affected the areas of northern Italy in the late Republic.

  3. Air pollution inside a small bronze foundry plant, measured by the energy dispersive X-ray fluorescence technique

    International Nuclear Information System (INIS)

    The aim of this paper was to evaluate the chemical concentration of some elements in Suspended Particulate Matter (SPM) inside a small bronze (copper and zinc alloy) foundry plant. Using a rotating streaker air-particulate sampler, it was possible to collect fine (aerodynamic diameters between 2.5 to 10 μm) and coarse particulates (aerodynamic diameters larger than 10 μm) in strips deposited on membranes, during eight hours, with a twenty minutes step. This first fraction is particularly important, because it can reach the lung alveoli and, depending on their chemical composition and concentration, cause serious damage to the health. Each sample strip, containing the deposited SPM was analyzed by energy dispersive X-ray Fluorescence (EDXRF) technique, using in the excitation a collimated the X-ray beam coming from a Mo target tube (30 kV, 20 ma, Zr filter). For collimating it was used a bronze collimator with 72 mm long, 10 mm at entrance diameter and 5 x 0.5 mm rectangular slit at exit. The characteristic X-ray detection was carried out using a Si(Li) semiconductor detector coupled to a multi-channel analyzer, and the X-ray spectra were fitted with the AXIL software. The temporal profiles for twelve chemical elements are evaluated. The critical moment to the worker health in that industrial activity was during the molding process, when high concentration peaks for toxic chemical elements were measured: Zn, Pb, Cu e Ni in the fine and coarse fractions, and Cr in the coarse fraction. The Pb concentration found in the suspended particulate was shown very superior to the maximum level established by WHO, suggesting a constant monitoring of the atmosphere in these work places.(Author)

  4. Strong genetic admixture in the Altai at the Middle Bronze Age revealed by uniparental and ancestry informative markers.

    Science.gov (United States)

    Hollard, Clémence; Keyser, Christine; Giscard, Pierre-Henri; Tsagaan, Turbat; Bayarkhuu, Noost; Bemmann, Jan; Crubézy, Eric; Ludes, Bertrand

    2014-09-01

    The Altai Mountains have been a long-term boundary zone between the Eurasian Steppe populations and South and East Asian populations. To disentangle some of the historical population movements in this area, 14 ancient human specimens excavated in the westernmost part of the Mongolian Altai were studied. Thirteen of them were dated from the Middle to the End of the Bronze Age and one of them to the Eneolithic period. The environmental conditions encountered in this region led to the good preservation of DNA in the human remains. Therefore, a multi-markers approach was adopted for the genetic analysis of identity, ancestry and phenotype markers. Mitochondrial DNA analyses revealed that the ancient Altaians studied carried both Western (H, U, T) and Eastern (A, C, D) Eurasian lineages. In the same way, the patrilineal gene pool revealed the presence of different haplogroups (Q1a2a1-L54, R1a1a1b2-Z93 and C), probably marking different origins for the male paternal lineages. To go further in the search of the origin of these ancient specimens, phenotypical characters (i.e. hair and eye color) were determined. For this purpose, we adapted the HIrisPlex assay recently described to MALDI-TOF mass spectrometry. In addition, some ancestry informative markers were analyzed with this assay. The results revealed mixed phenotypes among this group confirming the probable admixed ancestry of the studied Altaian population at the Middle Bronze Age. The good results obtained from ancient DNA samples suggest that this approach might be relevant for forensic casework too. PMID:25016250

  5. Effect of protective release coatings on the basis of superdispersersed zirconium oxide powder on the formation of gas defects in bronze casting

    Science.gov (United States)

    Martyushev, Nikita V.; Risto, Nikolay A.

    2014-10-01

    This paper investigates the use of nanopowders in the composition of foundry coatings when casting leaded tin bronzes. Influence of the composition of the applied protective coating on surface finish is studied. The effects of the coatings of the following compositions are compared: non-stick coating (a mixture of low-dispersed chromium oxide powder and heat-treated vegetable oil); non-stick lubricant ASPF-2/RgU on the basis of low- dispersed graphite powder and heat-treated vegetable oil; patent #2297300 (a mixture of superdispersed zirconium dioxide powder with industrial oil). It is demonstrated that application of foundry coatings containing superdispersed metal oxide powders with low thermal conductivity makes it possible to significantly reduce irregularities and eliminate gas porosity on the surface of tin-leaded bronze castings.

  6. A Facile One-Step Solvothermal Synthesis and Electrical Properties of Reduced Graphene Oxide/Rod-Shaped Potassium Tungsten Bronze Nanocomposite.

    Science.gov (United States)

    Liu, Bin; Yin, Shu; Wang, Yuhua; Guo, Chongshen; Wu, Xiaoyong; Dong, Qiang; Kobayashi, Makoto; Kakihana, Masato; Sato, Tsugio

    2015-09-01

    Reduced graphene oxide (rGO)/rod-shaped potassium tungsten bronze nanocomposites with the different ratio were successfully synthesized by solvothermal reaction and followed by the reduction in H2(5 vol.%)/N2 atmosphere at 550 degrees C. The coupled samples showed excellent shielding ability of NIR light as well as certain visible lights transparency. The synergistic effects could be observed in the composites, i.e., when 15 wt% and 20 wt% of rGO which was fabricated by chemical reduction of graphene oxide, were composed into K(x)WO3, the composite showed the higher electrical conductivity than those of rGO and potassium tungsten bronze. PMID:26716327

  7. Behavior of the monophosphate tungsten bronzes (PO{sub 2}){sub 4}(WO{sub 3}){sub 2m} (m=4 and 6) in electrochemical lithium insertion

    Energy Technology Data Exchange (ETDEWEB)

    Longoria Rodriguez, F.E.; Martinez-de la Cruz, A.; Lopez Cuellar, E. [Division de Estudios de Posgrado, Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon, Pedro de Alba s/n, Ciudad Universitaria, C.P. 66451, San Nicolas de los Garza, NL (Mexico)

    2006-10-06

    The electrochemical lithium insertion process has been studied in the family of monophosphate tungsten bronzes (PO{sub 2}){sub 4}(WO{sub 3}){sub 2m}, where m=4 and 6. Structural changes in the pristine oxides were followed as lithium insertion proceeded. Through potentiostatic intermittent technique, the different processes which take place in the cathode during the discharge of the cell were analysed. The nature of the bronzes Li{sub x}(PO{sub 2}){sub 4}(WO{sub 3}){sub 2m} formed was determined by in situ X-ray diffraction experiments. These results have allowed establishment of a correlation with the reversible/irreversible processes detected during the electrochemical lithium insertion. Measurements of resistivity showed that upon lithium insertion, the metallic pristine oxides become insulating. (author)

  8. 论滇文化的青铜贮贝器%On Shell-storing Bronze Containers in the Dian Culture

    Institute of Scientific and Technical Information of China (English)

    肖明华

    2004-01-01

    Shell-storing bronze containers constitute one of the representative objects of the Dian culture. Unique in function and form and rich in cultural content, they have high value to historical study, artistic appreciation and scientific research. In form they can be divided into five types: bronze drums, drum-shaped, piled-drums-shaped, barrel-shaped, and washer-shaped. Such containers made their first appearance in the Dian culture in the late Spring-and-Autumn period, prevailed in the Warring States period to the early and middle Western Han and stopped function at the turn from the Western Han to the Eastern Han. They are decorated with human activity scenes and designs, such as representations of sacrifice, farming, herding, spinning and weaving, fair attending, boating, dancing, fighting and hunting, as well as animal designs, including tiger and ox fight scenes and other figures. Their casting technology is characterized by the use of composite molds and the lost wax method.

  9. 论安阳殷墟墓葬青铜武器的组合%Combination of Bronze Weapons in Tombs on the Yin Ruins in Anyang

    Institute of Scientific and Technical Information of China (English)

    刘一曼

    2002-01-01

    There are 12 combinations of bronze weapons in Yin tombs at Anyang, with ge dag-ger-axes as the most frequently seen key objects. Among the tombs with bronze weapons, as the tomb-owners varied in status before their death, their funeral weapons bear distinct differences in type, number and quality. High-ranking officers possessed yue battle-axes, ge, spears and arrowheads, with swords added in some cases. Their number ranged from dozens to hundreds, and yue and swords were the symbols of commandership. Middle- and low-ranking officers had some dozen weapons in the ge-spear-arrowhead or ge-spear set. Commanders at the grass-root level used only two types of the ge, spear and arrowhead, which number no more than ten. Ordinary soldiers were armed with one of the ge, spear and arrowhead, in one or two pieces in case of the former two.

  10. Infant/child burials and social reproduction in the Bronze Age and Early Iron Age (c. 2100-800 BC) of Central Italy

    OpenAIRE

    Rossenberg, E.A.; Bacvarov, K

    2008-01-01

    Abstract: Special treatment of the remains of children is a well-known feature in Central Italy from the Neolithic onwards. Here I will focus on the evidence for the Bronze Age and Early Iron Age in two adjacent Central Italian regions (Abruzzo and Lazio). It will be argued that mortuary practice involving neonates, infants and children was connected with domestic symbolism, showing the enhanced cultural significance of infant/child burials. Investing child burials with domestic symbolism, bu...

  11. Au-Sn-W-Cu-Mineralization in the Astaneh-Sarband Area, West Central Iran : including a comparison of the ores with ancient bronze artifacts from Western Asia

    OpenAIRE

    Nezafati, Nima

    2006-01-01

    The present study deals with two primary aims; (1) geological, mineralogical, and geochemical investigations of the Deh Hosein, Astaneh, and Nezam Abad mineralizations in the Astaneh-Sarband area, west central Iran, with the aim to understand the characteristics of the occurrences and their conditions of formation, and (2) geochemical investigations on ancient bronze artifacts from Iran and Western Asia in order to compare their characteristics with the high-tin copper ore of Deh Hosein and e...

  12. Provenance of early bronze age metal artefacts in western Switzerland using elemental and lead isotopic compositions and their possible relation with copper minerals of the nearby Valais

    OpenAIRE

    Cattin, Florence; Guénette-Beck, Barbara; Curdy, Philippe; Meisser, Nicolas; Ansermet, Stefan; Hofmann, Beda; Kündig, Rainer; Hubert, Vera; Wörle, Marie; Hametner, Kathrin; Günther, Detlef; Wichser, Adrian; Ulrich, Andrea; Villa, Igor M.; Besse, Marie

    2011-01-01

    Ten Early Bronze Age (BzA1, 2200-2000 BC) copper artefacts from the central Valais region from Switzerland were studied for their elemental composition and lead isotope ratios. In order to answer the archaeological question of a local copper supply, a database for copper minerals across the Valais (Switzerland) has been established. This database contains 69 data on lead isotope ratios as well as additional information on the minerals and geochemical associations for copper minerals from 38 l...

  13. The pots and potters of Assyria: technology and organization of production, ceramics sequence and vessel function at Late Bronze Age Tell Sabi Abyad, Syria

    OpenAIRE

    Duistermaat, Kim

    2007-01-01

    “The Pots and Potters of Assyria” is a comprehensive discussion of all evidence relating to pottery production from the Late Bronze Age site of Tell Sabi Abyad, Syria. Technological, morphological, stylistic and archaeological data are integrated into the understanding of pottery production and use. The pottery itself and its chronological sequence, the shaping and firing techniques, raw materials, wasters and unfired pottery are presented. In addition, workshops and their layout, tools, as w...

  14. Sous l’angle du genre: analyse de nécropoles de l’âge du Bronze (15e-13e siècle av. J.-C.) d’Italie du Nord et comparaisons avec le nord des Alpes

    OpenAIRE

    David-El Biali, Mireille

    2010-01-01

    The scope of my research is to examine the gender roles of women and men in parts of continental Europe during the Bronze Age. Northern Italy is a very interesting area from this point of view. It is divided into two cultural provinces: the Terramare culture east of the river Oglio and the Western province to its west. Many large cemeteries were established in the Middle Bronze Age and continued to be used in the Recent Bronze Age (Bronzo recente, the phase Bronze D of the Central European ch...

  15. 西周金文中的“贾”%Character“贾”in Bronze Inscriptions of the Western Zhou Period

    Institute of Scientific and Technical Information of China (English)

    彭裕商

    2003-01-01

    The author of the present paper deciphers the character “贾” in Western Zhou bronze inscriptions to be “gu贾”. He believes that its emergence was earlier than that of the character “zhu贮”,and that there was some relationship of inheritance between the “贾”in Warring States period writing and that in Western Zhou bronze inscriptions. In the Western Zhou, it was used mainly as a verb and meant trade and exchange. It could also be used as a noun, meaning officials in charge of commerce, such as “guzheng贾正” and “gushi贾师”.Sometimes it referred to a lcal state. During the early Western Zhou, there must have been traders specially engaged in long-distance transportation of goods for sale, but at present we have no evidence on the Dynastry's management of commercial activities. In the mid Western Zhou, high-ranking officials of the court interposed in trade. In the late Western Zhou, definite records about the Dynastry's sending officials to manage commerce appeared in bronze inscriptions and historical documents.

  16. Genetic characteristics and migration history of a bronze culture population in the West Liao-River valley revealed by ancient DNA.

    Science.gov (United States)

    Li, Hongjie; Zhao, Xin; Zhao, Yongbin; Li, Chunxiang; Si, Dayong; Zhou, Hui; Cui, Yinqiu

    2011-12-01

    In order to study the genetic characteristics of the Lower Xiajiadian culture (LXC) population, a main bronze culture branch in northern China dated 4500-3500 years ago, two uniparentally inherited markers, mitochondrial DNA and Y-chromosome single-nucleotide polymorphisms (Y-SNPs), were analyzed on 14 human remains excavated from the Dadianzi site. The 14 sequences, which contained 13 haplotypes, were assigned to 9 haplogroups, and Y-SNP typing of 5 male individuals assigned them to haplogroups N (M231) and O3 (M122). The results indicate that the LXC population mainly included people carrying haplogroups from northern Asia who had lived in this region since the Neolithic period, as well as genetic evidence of immigration from the Central Plain. Later in the Bronze Age, part of the population migrated to the south away from a cooler climate, which ultimately influenced the gene pool in the Central Plain. Thus, climate change is an important factor, which drove the population migration during the Bronze Age in northern China. Based on these results, the local genetic continuity did not seem to be affected by outward migration, although more data are needed especially from other ancient populations to determine the influence of return migration on genetic continuity.

  17. An Energy-Dispersive X-Ray Fluorescence Spectrometry and Monte Carlo simulation study of Iron-Age Nuragic small bronzes ("Navicelle") from Sardinia, Italy

    Science.gov (United States)

    Schiavon, Nick; de Palmas, Anna; Bulla, Claudio; Piga, Giampaolo; Brunetti, Antonio

    2016-09-01

    A spectrometric protocol combining Energy Dispersive X-Ray Fluorescence Spectrometry with Monte Carlo simulations of experimental spectra using the XRMC code package has been applied for the first time to characterize the elemental composition of a series of famous Iron Age small scale archaeological bronze replicas of ships (known as the "Navicelle") from the Nuragic civilization in Sardinia, Italy. The proposed protocol is a useful, nondestructive and fast analytical tool for Cultural Heritage sample. In Monte Carlo simulations, each sample was modeled as a multilayered object composed by two or three layers depending on the sample: when all present, the three layers are the original bronze substrate, the surface corrosion patina and an outermost protective layer (Paraloid) applied during past restorations. Monte Carlo simulations were able to account for the presence of the patina/corrosion layer as well as the presence of the Paraloid protective layer. It also accounted for the roughness effect commonly found at the surface of corroded metal archaeological artifacts. In this respect, the Monte Carlo simulation approach adopted here was, to the best of our knowledge, unique and enabled to determine the bronze alloy composition together with the thickness of the surface layers without the need for previously removing the surface patinas, a process potentially threatening preservation of precious archaeological/artistic artifacts for future generations.

  18. 西周金文构形特征探析%Structural Features of Inscriptions on Ancient Bronze Objects in Western Zhou Dynasty

    Institute of Scientific and Technical Information of China (English)

    王瑞英

    2012-01-01

    西周金文处于汉字体系的形成和发展时期。西周铜器铭文中图形文字向方块字体转变,偏旁部首增加并趋于成熟,汉字形体结构日益完善,形声结构迅速增长。对西周金文构形特征的考察能够深入了解文字发展变化的过程,从而有助于探求汉字的发展变化规律。%The inscriptions on ancient bronze objects in the Western Zhou Dynasty appeared in the times when Chinese character system formed and developed. In the inscriptions on bronze, the pictographic scripts changed to be square -shaped characters, character components increased and perfected, the form and structure were further perfect and the number of inscriptions rapidly increased. To investigate the structural features of inscriptions on ancient bronze objects will help deepen the understanding of the evolution of Chinese characters.

  19. Foraging behaviour in tadpoles of the bronze frog Rana temporalis: Experimental evidence for the ideal free distribution

    Indian Academy of Sciences (India)

    Dheeraj K Veeranagoudar; Bhagyashri A Shanbhag; Srinivas K Saidapur

    2004-06-01

    The ability of bronze frog Rana temporalis tadpoles (pure or mixed parental lines) to assess the profitability of food habitats and distribute themselves accordingly was tested experimentally using a rectangular choice tank with a non-continuous input design. Food (boiled spinach) was placed at two opposite ends of the choice tank in a desired ratio (1 : 1, 1 : 2 or 1 : 4) to create habitat A and B. The tadpoles in Gosner stage 28–33, pre-starved for 24 h, were introduced in an open ended mesh cylinder placed in the center of the choice tank, held for 4 min (for acclimation) and then released to allow free movement and habitat selection. The number of tadpoles foraging at each habitat was recorded at 10, 15, 20, 25 and 30 min time intervals. The actual suitability, (the food available in a habitat after colonization of tadpoles) of each habitat was obtained from the equation = - () where is basic suitability (amount of food provided at each habitat before release of tadpoles), is the rate of depletion of food (lowering effect) with introduction of each tadpole, and is the density of tadpoles in habitat . The expected number of tadpoles at each habitat was derived from the actual suitability. With no food in the choice tank, movement of the tadpoles in the test arena was random indicating no bias towards any end of the choice tank or the procedure. In tests with a 1 : 1 food ratio, the observed ratio of tadpoles (11.71 : 12.28) was comparable with the expected 12 : 12 ratio. The observed number of tadpoles in the habitats with a 1 : 2 food ratio was 8.71 : 15.29 and 7.87 : 16.13 for pure and mixed parental lines respectively. In both cases, the observed ratios were close to the expected values (7 : 17). Likewise, in experiments with a 1 : 4 food ratio, the observed number of tadpoles in the two habitats (10.78 : 37.22) did not differ significantly from the expected ratio of 7 : 41. In all tests, the number of R. temporalis tadpoles matched ideally with

  20. Tantalum and vanadium substitution in hexagonal K{sub 0.3}WO{sub 3} bronze. Synthesis and characterization

    Energy Technology Data Exchange (ETDEWEB)

    Rahman, Md. Shahidur; Murshed, M. Mangir; Gesing, Thorsten M. [Bremen Univ. (Germany). Chemische Kristallographie fester Stoffe; Baabe, Dirk [Technische Univ. Braunschweig (Germany). Inst. fuer Anorganische und Analytische Chemie

    2016-02-01

    Polycrystalline samples of tantalum and vanadium single and double substituted hexagonal potassium tungsten bronzes (K-HTB's) with nominal compositions of K{sub 0.3}(W{sup 6+}{sub 0.7}W{sup 5+}{sub 0.3-y}Ta{sup 5+}{sub y})O{sub 3} (0 ≤ y ≤ 0.3), K{sub 0.3}(W{sup 6+}{sub 0.7}W{sup 5+}{sub 0.3-y}V{sup 5+}{sub y})O{sub 3} (0 ≤ y ≤ 0.18) and K{sub 0.3}(W{sup 6+}{sub 0.7}W{sup 5+}{sub 0.3-y}Ta{sup 5+}{sub y/2}V{sup 5+}{sub y/2})O{sub 3} (0 ≤ y ≤ 0.3) were synthesized by solid state reactions in quartz tubes at 10{sup -7} MPa and 1073 K. The applied synthesis condition allowed K{sub 0.3}WO{sub 3} to crystallize in space group P6{sub 3}22, confirmed by X-ray powder diffraction and Raman spectroscopic analyses. In this K-HTB composition, W{sup 5+} could fully be replaced by Ta{sup 5+}, whereas V{sup 5+} could only be substituted up to y=0.16. The degree of W{sup 5+} substitution was explained in terms of second-order Jahn-Teller (SOJT) distortion of the d{sup 0} cations W{sup 6+}, Ta{sup 5+} and V{sup 5+}. The applied distortion index also demonstrates why a complete substitution of W{sup 5+} in K{sub 0.3}(W{sup 6+}W{sup 5+})O{sub 3} was allowed by a concomitant sharing of Ta{sup 5+} and V{sup 5+}, which are statistically distributed on the W{sup 5+}/W{sup 6+} sites. As W{sup 5+}(d{sup 1}) is not SOJT susceptible, it is also shown that the concentration of W{sup 5+} in tungsten bronzes plays an important role in the local WO{sub 6} octahedral symmetry as well as in its coordination.

  1. On the aesthetic features of the bronze ware in the ancient Dian Kingdom%古滇国青铜器的美学特征

    Institute of Scientific and Technical Information of China (English)

    张贺; 卫乐; 余敏

    2012-01-01

    In 1957, the "Emperor Seal of Dian" was unearthed at Shizhai Hill in Jinning county, which confirms the existence of the "Dian Kingdom" in ancient times (Dian being the short form of Yunnan province). The bronze ware in the ancient Dian kingdom is diversified with kingdom per se, her vivid artistic actuality often awakens strong local color. As "Dian" is a mysterious ancient a kind of experiencing memory and imagination and gives us aesthetic enjoyment. The subject matter of the ancient Dian bronze sculpture and adornments are wide - ranging and filled with the flavor of life and life practice is the basis of the lively bold expression and strong viva- cious style of the ancient Dian kingdom bronze art. In the ancient Dian kingdom bronze ware, the organic blend of carving adornments and apparatuses is its unique way of construction. Moreover, the realistic style of the bronze ware art endows it with rhythmic sense and decorative beauty in the density of the arrangement of its layout.%1957年在晋宁石寨山出土了“滇王印”,证实了古代“滇国”的存在,古滇国的青铜器种类十分繁杂,具有浓烈的地方色彩,“滇”本身就是一个神秘的古国,其艺术的生动真实常常唤起一种经历的记忆与想象。给予我们美的享受。古滇青铜雕刻与图饰的题材内容非常广泛,充满了生活气息。生活实践,是古滇国青铜器艺术生动大胆的表现力、强悍灵动风格的基础。在古滇国青铜器中,雕刻图饰与器物是融为一体的,是古滇青铜艺术特有晦构成形式。古滇国青铜器的艺术风格是非常写实的,布局上,疏密节奏的安排赋予韵律感与装饰美。

  2. Transformation of Lamellar Structures in Equal Channel Angular Pressing: Geometric Model and Application to Nickel Aluminum Bronze

    Science.gov (United States)

    Barr, Cameron J.; McDonald, Daniel T.; Xia, Kenong

    2015-09-01

    Nickel aluminum bronze (NAB) with a duplex structure was subjected to equal channel angular pressing (ECAP). Samples were pressed for up to four passes at 673 K (400 °C) using routes A, BA, BC, and C, respectively, and the evolution of the microstructures was characterized. A detailed geometric model was developed to enable systematic and quantitative analysis of the transformation of the lamellar structure during ECAP. Depending on their orientations before each ECAP pass, the lamellae were either stretched, leading to fragmentation, or compressed, resulting in buckling and spheroidisation at locations of high curvature. Thanks to the continuous rotation of lamellae into the stretching orientations in route A and the non-plane strain deformation in the two B routes, they are demonstrated to be the most effective in breaking down the lamellar structure. In contrast, partial restoration due to redundant strain in route C makes it least efficient. The model applies generally to materials with a duplex structure, such as NAB and low and medium carbon steels, consisting of a hard and brittle lamellar phase and a softer and ductile matrix phase.

  3. Oxygen isotope in archaeological bioapatites from India: Implications to climate change and decline of Bronze Age Harappan civilization.

    Science.gov (United States)

    Sarkar, Anindya; Mukherjee, Arati Deshpande; Bera, M K; Das, B; Juyal, Navin; Morthekai, P; Deshpande, R D; Shinde, V S; Rao, L S

    2016-01-01

    The antiquity and decline of the Bronze Age Harappan civilization in the Indus-Ghaggar-Hakra river valleys is an enigma in archaeology. Weakening of the monsoon after ~5 ka BP (and droughts throughout the Asia) is a strong contender for the Harappan collapse, although controversy exists about the synchroneity of climate change and collapse of civilization. One reason for this controversy is lack of a continuous record of cultural levels and palaeomonsoon change in close proximity. We report a high resolution oxygen isotope (δ(18)O) record of animal teeth-bone phosphates from an archaeological trench itself at Bhirrana, NW India, preserving all cultural levels of this civilization. Bhirrana was part of a high concentration of settlements along the dried up mythical Vedic river valley 'Saraswati', an extension of Ghaggar river in the Thar desert. Isotope and archaeological data suggest that the pre-Harappans started inhabiting this area along the mighty Ghaggar-Hakra rivers fed by intensified monsoon from 9 to 7 ka BP. The monsoon monotonically declined after 7 ka yet the settlements continued to survive from early to mature Harappan time. Our study suggests that other cause like change in subsistence strategy by shifting crop patterns rather than climate change was responsible for Harappan collapse.

  4. Energy and intensity distributions of 279 keV multiply scattered photons in bronze - an inverse response matrix approach

    Indian Academy of Sciences (India)

    Manpreet Singh; Bhajan Singh; B S Sandhu

    2008-01-01

    An inverse response matrix converts the observed pulse-height distribution of a NaI(Tl) scintillation detector to a true photon spectrum. This also results in extraction of intensity and energy distributions of multiply scattered events originating from interactions of 279 keV photons with thick targets of bronze. The observed pulse-height distributions are a composite of singly and multiply scattered events in addition to bremmstrahlung originating from slowing down of Compton and photo-electrons in thick targets. To evaluate the contribution of multiply scattered events, the spectrum of singly scattered events contributing to inelastic Compton peak is reconstructed analytically. The optimum thickness (saturation depth), at which the number of multiply scattered events saturate, has been evaluated in different energy bin meshes chosen for scintillation detector response unfolding. Monte Carlo calculations based upon the package developed by Bauer and Pattison (Compton scattering experiments at the HMI (1981), HMI-B 364, pp. 1-106) supports the present experimental results.

  5. Oxygen isotope in archaeological bioapatites from India: Implications to climate change and decline of Bronze Age Harappan civilization.

    Science.gov (United States)

    Sarkar, Anindya; Mukherjee, Arati Deshpande; Bera, M K; Das, B; Juyal, Navin; Morthekai, P; Deshpande, R D; Shinde, V S; Rao, L S

    2016-01-01

    The antiquity and decline of the Bronze Age Harappan civilization in the Indus-Ghaggar-Hakra river valleys is an enigma in archaeology. Weakening of the monsoon after ~5 ka BP (and droughts throughout the Asia) is a strong contender for the Harappan collapse, although controversy exists about the synchroneity of climate change and collapse of civilization. One reason for this controversy is lack of a continuous record of cultural levels and palaeomonsoon change in close proximity. We report a high resolution oxygen isotope (δ(18)O) record of animal teeth-bone phosphates from an archaeological trench itself at Bhirrana, NW India, preserving all cultural levels of this civilization. Bhirrana was part of a high concentration of settlements along the dried up mythical Vedic river valley 'Saraswati', an extension of Ghaggar river in the Thar desert. Isotope and archaeological data suggest that the pre-Harappans started inhabiting this area along the mighty Ghaggar-Hakra rivers fed by intensified monsoon from 9 to 7 ka BP. The monsoon monotonically declined after 7 ka yet the settlements continued to survive from early to mature Harappan time. Our study suggests that other cause like change in subsistence strategy by shifting crop patterns rather than climate change was responsible for Harappan collapse. PMID:27222033

  6. Determining sensitive stages for learning to detect predators in larval bronzed frogs: Importance of alarm cues in learning

    Indian Academy of Sciences (India)

    Anuradha Batabyal; Sachin M Gosavi; Narahari P Gramapurohit

    2014-09-01

    Successful survival and reproduction of prey organisms depend on their ability to detect their potential predators accurately and respond effectively with suitable defences. Predator detection can be innate or can be acquired through learning.We studied prey–predator interactions in the larval bronzed frogs (Sylvirana temporalis), which have the innate ability to detect certain predators. We conducted a series of experiments to determine if the larval S. temporalis rely solely on innate predator detection mechanisms or can also learn to use more specific cues such as conspecific alarm cues for the purpose. The results of our study clearly indicate that larval S. temporalis use both innate and learned mechanisms for predator detection. Predator-naïve tadpoles could detect kairomones alone as a potential threat and responded by reducing activity, suggesting an innate predator detection mechanism. Surprisingly, predator-naïve tadpoles failed to detect conspecific alarm cues as a potential threat, but learned to do so through experience. After acquiring the ability to detect conspecific alarm cues, they could associate novel predator cues with conspecific alarm cues. Further, post feeding stages of larval S. temporalis are sensitive for learning to detect conspecific alarm cues to label novel predators.

  7. A Bronze Age Pre-Historic Dolmen: Laser Cleaning Techniques of Paintings and Graffiti (The Bisceglie Dolmen Case Study)

    Science.gov (United States)

    Daurelio, G.

    The whole building was included and covered by an elliptical plan tumulus as reported for other similar monuments situated in the same territory of BISCEGLIE and GIOVINAZZO (in South of Italy). The monument was built by a community established in that area to mark their territory. It has a typical funerary character (funeral urn) and it was destined to the collective sepulture in the Middle Bronze Age, as indicated by the ceramic finds, accompanying the rich dead men, copper objects and ornaments, bones and amber recovered inside together with human rests. Degradation Mapping and Laser Cleaning with Photographs, during and after the process in-situ were carried out. Black incrustations and writings (by some different felt pens, marking pens, permanent black and colored ink pigments — fluorescent and no, as well as permanent text liner markings and spayed black paint) were cleaned by using a portable Nd:YAG Laser (λ 1.06 μm — 0.53 μm, in N-Mode and Q-Switch Mode, Laser pulse duration 150 μs or 6ns — f 1 to 10Hz — E max. 500 mJ per pulse in 1st harmonic and 200 mJ per pulse in 2nd harmonic). So, according to the different ink types three different laser cleaning techniques were used.

  8. Emission of organic compounds from mould and core binders used for casting iron, aluminium and bronze in sand moulds.

    Science.gov (United States)

    Tiedje, Niels; Crepaz, Rudolf; Eggert, Torben; Bey, Niki

    2010-12-01

    Emissions from mould and core sand binders commonly used in the foundry industry have been investigated. Degradation of three different types of binders was investigated: Furfuryl alcohol (FA), phenolic urethane (PU) and resol-CO2 (RC). In each group of binders, at least two different binder compositions were tested. A test method that provides uniform test conditions is described. The method can be used as a general test method to analyse off gases from binders. Moulds, containing a standard size casting, were produced and the amount and type of organic compounds, resulting from thermal degradation of binders, was monitored when cast iron, bronze and aluminium was poured in the moulds. Binder degradation was measured by collecting off gases in a specially designed ventilation hood at a constant flow rate. Samples were taken from the ventilation system and analysed for hydrocarbons and CO content. It is shown how off-gases vary with time after pouring and shake out. Also the composition of off-gases is analysed and shown. It is further shown how the composition of off-gasses varies between different types of binders and with varying composition of the binders as well as function of the thermal load on the moulding sand. PMID:20954042

  9. The preparation and chemical reaction kinetics of tungsten bronze thin films and nitrobenzene with and without a catalyst

    Science.gov (United States)

    Materer, Nicholas F.; Apblett, Allen; Kadossov, Evgueni B.; Khan, Kashif Rashid; Casper, Walter; Hays, Kevin; Shams, Eman F.

    2016-06-01

    Microcrystalline tungsten bronze thin films were prepared using wet chemical techniques to reduce a tungsten oxide thin film that was prepared by thermal oxidation of a sputter deposited tungsten metal film on a quartz substrate. The crystallinity of these films was determined by X-ray diffraction and the surface was characterized by X-ray and Ultra-Violet Photoelectron spectroscopy. The total amount of hydrogen incorporated in the film was monitored using absorbance spectroscopy at 900 nm. The oxidation kinetics of the film and the hydrogenation of nitrobenzene in hexane were measured as a function of film thickness. A satisfactory fit of the resulting kinetics was obtained using a model that involves two simultaneous processes. The first one is the proton diffusion from the bulk of the film to the surface, and the second is a reaction of the surface protons with the oxidants. Finally, the dependence of the reaction rates on the presence of catalytic amounts of first row transition metals on the surface of the film was explored.

  10. A small Bronze Age mining camp: La Loma de la Tejería (Albarracín, Teruel

    Directory of Open Access Journals (Sweden)

    Montero Ruiz, Ignacio

    2008-06-01

    Full Text Available This paper shows the research done at Loma de la Tejería (Albarracín, Teruel where a seasonal camp site linked to a mining-metallurgical works has been discovered. Studies on materials show the use of different geological resources: copper minerals, Keuper clays with “Jacintos de Compostela” and volcanic rocks. Pottery residual analysis has documented dairy milky products and alcoholic drinks. Chronologically the site is classified amongst Chalcolithic and Early Bronze Age, on the presence of Bell Beaker pottery.

    Se presentan los datos de las excavaciones realizadas en la Loma de la Tejería (Albarracín, Teruel en la que se documenta un campamento estacional vinculado a tareas minero-metalúrgicas de pequeña escala. Los estudios realizados sobre el material indican el aprovechamiento de los recursos geológicos locales tanto de mineral de cobre, como de arcillas del Keuper con Jacintos de Compostela y rocas volcánicas. Los análisis de residuos han documentado en la cerámica productos lácteos y bebidas alcohólicas. Cronológicamente el yacimiento se encuadra en el Calcolítico y Bronce Antiguo, con presencia de cerámica campaniforme.

  11. Investigation of microstructure and mechanical properties of hot worked NiAl bronze alloy with different deformation degree

    Energy Technology Data Exchange (ETDEWEB)

    Lv, Yuting; Wang, Liqiang, E-mail: wang_liqiang@sjtu.edu.cn; Han, Yuanfei; Xu, Xiaoyan; Lu, Weijie, E-mail: luweijie@sjtu.edu.cn

    2015-09-03

    In this study, the forged NiAl bronze (NAB) were hot rolled with the deformation degree of 40%, 60%, 80%, 90% and 95% at 850 °C, respectively. Effects of rolling deformation degree on the microstructure and mechanical properties of the NAB alloy were investigated. Scanning electron microscope (SEM), electron backscatter diffraction (EBSD) and transmission electron microscope (TEM) methods were used to characterize the microstructure. The results show that α grains are refined by the dynamic recovery and recrystallization, penetration of β phase into α phase and particle-stimulated nucleation (PSN) of recrystallization during rolling. The refined grains make a main contribution to the increase of mechanical properties of rolled NAB. When the deformation degree is increased to 80%, the optimum tensile properties with ultimate strength of 861.3±8.5 MPa, yield strength of 634.5±7 MPa and elongation of 19.3±0.05% is obtained. With further increasing the deformation degree, the strength of rolled NAB alloy increase and the elongation decrease due to the increase of work hardening effect and the formation of martensitic nano-twins.

  12. Effect of some parameters of formation on surface graphite-bronze composite layer prepared by vacuum infiltration casting technique

    Institute of Scientific and Technical Information of China (English)

    YANG; Gui-rong; HAO; Yuan; SONG; Wen-ming; MA; Ying

    2005-01-01

    Surface composite up to 3.0 mm in thickness with compact microstructure was fabricated successfully via vacuum infiltration casting technique on the bronze substrate under the optimum experimental conditions: the vacuum degree of -0.08 MPa, pouring temperature of 1220℃, grain size of 0. 20-0. 24 mm, preheating temperature of 180℃. The preform was mainly composed of graphite particles and binder NJB (self-fabricated binder). The vacuum degree, pouring temperature, preheating temperature and grain size during infiltration casting play an important role on the process of forming the surface composite. The results show that three cases are obtained in the vacuum infiltration casting technique: no infiltration, partial infiltration and full infiltration. The main reason of no infiltration is that the vacuum degree is not enough so that the force acting on the liquid metal is lower than the resistance due to the surface tension and the pouring temperature is somewhat low. Partial infiltration is because of somewhat lower vacuum degree and pouring temperature. Full desired infiltration is on account of suitable infiltration casting conditions, such as vacuum degree, pouring temperature, grain size and preheating temperature. The influencing effect of vacuum degree is most obvious for the formation of surface composite, then pouring temperature and particle size. The infiltration mechanism is discussed on the bases of the different processing conditions.

  13. On the nature of phase transitions in the tetragonal tungsten bronze GdK2Nb5O15 ceramics

    International Nuclear Information System (INIS)

    Phase transitions in gadolinium potassium niobate GdK2Nb5O15 (GKN) ceramics have been investigated by x-ray diffraction, dielectric susceptibility, differential scanning calorimetry, and Raman scattering. The results of our complementary studies show that GKN exhibits two phase transitions at Tc1 = 238 °C and Tc2 = 375 °C attributed to the ferroelectric-antiferroelectric-paraelectric (FE-AFE-PE) phase transitions. According to the x-ray diffraction analysis, the FE and PE phases were refined in the polar P4bm and centrosymmetric P4/mbm space groups. For the intermediate phase, the structure is refined in the space group P4nc with doubling of the c unit cell parameter, which is compatible with an AFE phase. This result was confirmed by Raman spectroscopy since new low-frequency lines are activated in the AFE phase due to the Brillouin zone-folding effect, typical for the modulated phases. The presence of the AFE phase between the FE and PE phases and the complex nature of tetragonal tungsten bronze crystal structure can explain the large thermal hysteresis observed at the FE-AFE transition between heating and cooling cycle and the strong depression of the Curie-Weiss temperature T0. The semi-phenomenological Ising-like model based on the obtained experimental data is proposed to account for the observed FE-AFE-PE transition sequence

  14. Effect of Post Heat Treatment on the Microstructure and Microhardness of Friction Stir Processed NiAl Bronze (NAB Alloy

    Directory of Open Access Journals (Sweden)

    Yuting Lv

    2015-09-01

    Full Text Available NiAl bronze (NAB alloy is prepared by using friction stir processing (FSP technique at a tool rotation rate of 1200 rpm and a traverse speed of 150 mm/min. A post heat treatment is performed at the temperature of 675 °C. The effect of heat treatment on the microstructure and microhardness is studied. The results show that the microstructure of the FSP NAB alloy consists of high density dislocations, retained β phase (β′ phase and recrystallized grains. When annealed at 675 °C, discontinuous static recrystallization (DSRX takes place. The content of β′ phase gradually decreases and fine κ phase is precipitated. After annealing for 2 h, both the microhardness of the FSP sample in the stir zone (SZ and the difference in hardness between the SZ and base metal decrease due to the reduction of the dislocation density and β′ phase, accompanying recrystallized grain coarsening. With further increasing of the annealing time to 4 h, the aforementioned difference in hardness nearly disappears.

  15. Effects of body mass and temperature on routine metabolic rate of juvenile largemouth bronze gudgeon Coreius guichenoti.

    Science.gov (United States)

    Luo, Y P; Wang, Q Q

    2012-04-01

    The effects of body mass (M) and temperature (T) on routine metabolic rate (m(R) ) were assessed in the largemouth bronze gudgeon Coreius guichenoti, from Three Gorges Reservoir, Yangtze River, China. The m(R) increased with increasing M by factors (b-value in the equation m(R) = aM(b) ) of 0·843, 0·800, 0·767, 0·788 and 0·822 at 10, 15, 20, 25 and 30° C, respectively. A significant interaction between M and T on m(R) was observed. The variation in the b-value at different T suggests that the b-values were not consistent with the universal allometric exponent 0·75. After controlling for M, the relationship between the normalized standard metabolic rate (m(S), mg O(2) kg(-1) h(-1)) and T was described by an exponential equation: m(S) = 9·89e((0·093T)) . The results indicate that the effects of M on m(R) depend on T. The increased water temperature induced by dam construction on the Yangtze River may cause a marked increase in energy demand by this species, with potential ecological consequences. PMID:22471803

  16. Evidence that a West-East admixed population lived in the Tarim Basin as early as the early Bronze Age

    Directory of Open Access Journals (Sweden)

    Zhang Quanchao

    2010-02-01

    Full Text Available Abstract Background The Tarim Basin, located on the ancient Silk Road, played a very important role in the history of human migration and cultural communications between the West and the East. However, both the exact period at which the relevant events occurred and the origins of the people in the area remain very obscure. In this paper, we present data from the analyses of both Y chromosomal and mitochondrial DNA (mtDNA derived from human remains excavated from the Xiaohe cemetery, the oldest archeological site with human remains discovered in the Tarim Basin thus far. Results Mitochondrial DNA analysis showed that the Xiaohe people carried both the East Eurasian haplogroup (C and the West Eurasian haplogroups (H and K, whereas Y chromosomal DNA analysis revealed only the West Eurasian haplogroup R1a1a in the male individuals. Conclusion Our results demonstrated that the Xiaohe people were an admixture from populations originating from both the West and the East, implying that the Tarim Basin had been occupied by an admixed population since the early Bronze Age. To our knowledge, this is the earliest genetic evidence of an admixed population settled in the Tarim Basin.

  17. Study of bronzes excavated from Nanling county,Anhui province%安徽南陵出土部分青铜器研究

    Institute of Scientific and Technical Information of China (English)

    贾莹; 刘平生; 黄允兰

    2012-01-01

    安徽省南陵县是长江下游地区最早而且规模最大的冶炼中心之一,其古代矿冶遗址可上溯至西周晚期。本研究对南陵出土的不同年代和类别的青铜器样品进行了金相检测及合金成分定量分析。结果表明,只有容器存在铜铅二元合金和铜锡铅三元合金,但是热锻淬火的容器却不含铅,含锡量恰好位于适合该工艺操作并具有良好性能的区间。兵器、工具、车马饰均为铜锡二元合金,说明当时的工匠对于合金成分配比与性能的关系有明确的认识。越式鼎腹部样品具有热锻淬火马氏体组织,同样的金属结构还见于汉代铜锣等乐器、峡江地区战国中晚期青铜剑、江都大桥镇南朝青铜器窖藏出土的多件青铜容器,而镇江地区出土吴国青铜戈则具有铸造淬火组织,工艺稍有差别。这些器物中发现高锡青铜淬火组织不是偶然的,高锡青铜热锻淬火技术至少可以上溯至春秋战国时期,用以改善高锡青铜的机械性能。%Ancient mining and smelter remains in Nanling county,Anhui province show that this region is one of earliest and biggest metallurgical industry centers in the lower reaches of Yangzi river of China.The earliest Jiangmuchong site was dated to the late West Zhou dynasty. Microstructures and compositions of various bronze samples from Nanling county and dated from late West Zhou Dynasty to Spring and Autumn and Warring States periods were investigatd.Examination reveals that some vessels are copper-lead or copper-tin-lead alloys.However,those made by hot forging,followed by quenching do not contain lead,but rather have a tin content that is right for the technique and good for their properties.Weapons,tools and horse and cart decorations are all copper-tin alloys,suggesting that the bronze artisans at the time had a good understanding of the relationship between an alloy's composition and its properties.The body of a "Ding" in the

  18. Échanges et circulation des techniques en Europe atlantique à l’âge du Bronze: une modélisation à partir des données archéologiques recueillies sur les épées en bronze

    Directory of Open Access Journals (Sweden)

    Bénédicte Quilliec

    2005-12-01

    Full Text Available From prehistoric times, people traded in the region that extends from modern-day Scotland to Andalusia, partly as a result of the specific geographical location of Atlantic Europe. These trading patterns, viewed from the angle of one type of object, namely bronze swords, were exchanges of both physical objects and ideas, because common or similar practices are apparent. These were both metalworking techniques and cultural and ritual practices.

  19. Thermal Expansion and Second Harmonic Generation Response of the Tungsten Bronze Pb2AgNb5O15.

    Science.gov (United States)

    Lin, Kun; Gong, Pifu; Sun, Jing; Ma, Hongqiang; Wang, You; You, Li; Deng, Jinxia; Chen, Jun; Lin, Zheshuai; Kato, Kenichi; Wu, Hui; Huang, Qingzhen; Xing, Xianran

    2016-03-21

    The incorporation of transition metal element Ag was performed to explore negative thermal expansion (NTE) materials with tetragonal tungsten bronze (TTB) structures. In this study, the structure and thermal expansion behaviors of a polar TTB oxide, Pb2AgNb5O15 (PAN), were systematically investigated by high-resolution synchrotron powder diffraction, high-resolution neutron powder diffraction, transmission electron microscope (TEM), and high-temperature X-ray diffractions. The TEM and Rietveld refinements revealed that the compound PAN displays (√2a(TTB), √2b(TTB), 2c(TTB))-type superstructure. This superstructure within the a-b plane is caused by the ordering of A-site cations, while the doubling of the c axis is mainly induced by a slight tilt distortion of the NbO6 octahedra. The transition metal Ag has larger spontaneous polarization displacements than Pb, but the Pb-O covalence seems to be weakened compared to the potassium counterpart Pb2KNb5O15 (PKN), which may account for the similar Curie temperature and uniaxial NTE behavior for PAN and PKN. Powder second harmonic generation (SHG) measurement indicates that PAN displays a moderate SHG response of ∼0.2 × LiNbO3 (or ∼100 × α-SiO2) under 1064 nm laser radiation. The magnitudes of the local dipole moments in NbO6 and PbOx polyhedra were quantified using bond-valence approach. We show that the SHG response stems from the superposition of dipole moments of both the PbO(x) and NbO6 polyhedra. PMID:26928907

  20. Reconstructing diet by stable isotope analysis: Two case studies from Bronze Age and Early Medieval Lower Austria

    International Nuclear Information System (INIS)

    Carbon and nitrogen stable isotope analysis is nowadays a method frequently applied for the reconstruction of past human diets. The principles of this technique were developed in the late 1970s and 1980s, when it was shown that the isotopic composition of an animal's body reflected that of its diet. Given that the investigated material (often bone collagen) is well enough preserved, several aspects of diet can be investigated by carbon and nitrogen isotopic signatures - expressed as δ13C- und δ15N-values - as e.g. whether nutrition was based on C3 or C4 plants. Furthermore, these signatures can be used for the detection of a marine component in the diet and they contain information about the trophic level of an individual. The goal of the work presented in this talk was to investigate certain aspects of diet using carbon and nitrogen stable isotope analysis of human and animal skeletal remains from Austrian archaeological sites. Two sites (both in Lower Austria) were selected for this study, the Bronze Age Cemetery of Gemeinlebarn and the Early Medieval settlement of Thunau/Gars am Kamp. Previous archaeological and anthropological examinations suggested that both sites were inhabited by socially differentiated populations. Hence, during the stable isotope analysis special attention was paid to the detection of variation in nutritional habits due to sociogenic or gender-related differences. δ13C- und δ15N-values were measured in collagen, extracted from bone samples, by means of elemental analyzer-isotope ratio mass spectrometry (EA-IRMS). The obtained stable isotope data were examined for significant differences between social groups and the sexes using statistical hypothesis testing (MANOVA and ANOVA). (author)

  1. Goblet Cells and Mucus Types in the Digestive Intestine and Respiratory Intestine in Bronze Corydoras (Callichthyidae: Teleostei).

    Science.gov (United States)

    Leknes, I L

    2015-10-01

    The structure and histochemical properties of the intestine in bronze corydoras (Corydoras aeneus), a stomach-containing teleost, are described, with emphasis on goblet cells and mucin types. The proximal intestine displayed a normal structure for teleosts, whereas the distal intestine was wide, translucent, thin-walled, richly vascularized and constantly filled with air, suggesting an important respiratory role. Goblet cells were common throughout the entire intestine and displayed a variable, but mainly faint metachromatic colour after toluidine blue. They were moderately coloured by alcian blue at both pH 2.5 and 0.2 and displayed no colour after periodic acid followed by Schiff's solution (PAS), but a distinct purple-brown colour after high iron diamine followed by alcian blue (pH 2.5). Together, these results suggest that the mucin in the intestine goblet cells consists mainly of sulphated proteoglycans. Further, the results from the present lectin and neuraminidase tests suggest that these mucins contain much N-acetylglucoseamines and some N-acetylgalactosamines and sialic acid, but seem to lack glucose and mannose. They also contain some galactose-N-acetylgalactosamines sequences, normally hidden by sialic acid. The distinct brush border and mucus layer on the epithelial cells in the respiratory intestine may indicate some digestive roles, such as absorption of water, ions and simple carbohydrates. As sulphated proteoglycans are tough and attract much water, this mucus may play important roles in the protection against mechanical and chemical damages and in the defence against micro-organisms throughout the entire intestine, but in the respiratory intestine it may impede significantly the oxygen uptake. However, as this part of the intestine usually contains no digesta, but is completely filled with air, frequently renewed by dry air from the atmosphere, and the main function of the mucus may be to protect the respiratory epithelium against a destroying and

  2. The metamorphosis of Villena trade of gold, tin and salt during the Late Bronze Age I between the Atlantic and the Mediterranean (1625-1300 BC

    Directory of Open Access Journals (Sweden)

    Mederos Martín, Alfredo

    1999-12-01

    Full Text Available During the Late Bronze Age I there was a clear process of population concentration in the regions around the Lower Segura, Middle and Upper Vinalopó (Alicante, Southeast Spain, in settlements as Laderas del Castillo, El Portitxol and Cabezo Redondo. Next to the last one, the hoard of Villena, ca. 1575-1400 BC, is the second most important hoard of golden vessels in Europe, after the Shaft Graves at Mycenae, during the Late Bronze Age. This hoard, which was made from alluvial gold, required the full time work of 130-150 people during, at least, 1 year and 3 months. Also during the Late Bronze Age I in Southeast Spain an increase in new coastal settlements, the use of bronze alloys (Sn, 8-12 % and horse breeding took place. The lion's share of this gold and tin had to be obtained by maritime trade with Northwest Iberia in exchange for salt, which Galicia lacks compared with other European Atlantic regions. The salt probably came from the lagoon of La Mata (Alicante, currently the largest saline complex of Europe.

    Durante el Bronce Final I se produjo un claro proceso de concentración poblacional en las comarcas del Bajo Segura, Medio y Alto Vinalopó (Alicante, en poblados como Laderas del Castillo, El Portitxol y Cabezo Redondo. Próximo a este último, el "tesoro" de Villena, ca. 1575-1400 AC, es el conjunto de vajilla áurea más importante de Europa durante el Bronce Final, después de las tumbas de fosa de Micenas. Este "tesoro", que exigió para su acumulación el trabajo a tiempo completo de 130-150 personas durante, al menos, 1 año y 3 meses, procede de oro aluvial. También durante el Bronce Final I se incrementan en el Sureste los poblados costeros, el uso del bronce (Sn, 8-12 % y la cría de caballos. La mayor parte de este oro y estaño debió obtenerse por comercio marítimo con el Noroeste Peninsular a cambio de sal, de la que Galicia es deficitaria como otras regiones atlánticas europeas. La sal procedería de la laguna de

  3. A portable PIXE system for the in situ characterisation of black and red pigments in neolithic, copper age and bronze age pottery

    International Nuclear Information System (INIS)

    The results of the determination of the chromophoric elements in black and red pigments in ancient neolithic, copper age and bronze age pottery are presented. The measurements were carried out by using a recently developed portable PIXE system and were performed at the Archaeological Museum of Licata (Sicily). The results confirm the presence of Manganese in black pigments of Castelluccio style pottery and indicate, for the first time, a strong presence of manganese in copper age pottery of the Serraferlicchio style, and in neolithic pottery of the Serra d'Alto style

  4. The botanical macroremains from the prehistoric settlement Kalnik-Igrišče (NW Croatia) in the context of current knowledge about cultivation and plant consumption in Croatia and neighboring countries during the Bronze Age

    OpenAIRE

    Sara Mareković; Snježana Karavanić; Andreja Kudelić; Renata Šoštarić

    2015-01-01

    This paper presents the results of the first extensive archaeobotanical research into a Bronze Age site in Croatia. The aim of the study was to reveal what plants were consumed (grown) at Kalnik-Igrišče (NW Croatia) in the Bronze Age and to realize if the plant diet of the local population differed from that of the inhabitants in neighboring countries. The results show that all plant macrofossils found at Kalnik-Igrišče can be classified into one of four functional groups: cereals, cultiv...

  5. A Summary on the Western Zhou Dynasty Bronze Inscription Verbs%西周金文动词研究综述

    Institute of Scientific and Technical Information of China (English)

    寇占民

    2014-01-01

    西周金文是最早的成系统的汉民族书面语之一,保持着当时语言的原貌,是该时期语言的真实记录,因此它是研究上古汉语词汇和语法的重要语料。通过对西周金文动词的判定标准、词义系统、语法功能和复音词进行全面的梳理,为西周金文的释读和应用以及上古汉语动词的研究奠定基础。%The Western Zhou Dynasty bronze inscription is one of the earliest systematic written languages of Han nationality and records the true language phenomena at that time. It is very important to studying the ancient vocabulary and grammar since it keeps in the original states. Bythe thoroughly researches on the criterion, the meaning system and the grammatical function of verbs and the disyllabic verbs in Western Zhou Dynasty bronze inscription, one can learn the verbs’rules and features and lay a solid foundation to apply and study the ancient Chinese language verb system.

  6. Variability of the melanocortin 1 receptor (MC1R) gene explains the segregation of the bronze locus in turkey (Meleagris gallopavo).

    Science.gov (United States)

    Vidal, O; Viñas, J; Pla, C

    2010-08-01

    By sequencing the full coding region of the turkey melanocortin 1 receptor (MC1R) gene, we have found 4 mutations (c.96G > A, c.364A > T, c.450C > T, and c.887C > T) that are organized in 5 different haplotypes (MC1R*1 to MC1R*5). These haplotypes correlate perfectly with the 3 alleles of the bronze locus (i.e., B, b(+), and b(1)). We suggest that the dominant black phenotype, associated with the B allele, results from the constitutive activation of the receptor, an effect that might be mediated by the missense mutation c.364A > T (p.Ile122Phe). Moreover, we propose that the recessive black-winged bronze phenotype (linked to b(1)) might be produced by 2 deleterious mutations of MC1R (c.96G > A and c.887C > T). This is an unexpected finding because in mammals, MC1R deleterious polymorphisms are usually related with either red or lighter fur colors.

  7. Textile production in the Bronze Age: an assemblage of splindes or bobbins of yarn from the site of Terlinques (Villena, Alicante

    Directory of Open Access Journals (Sweden)

    Jover Maestre, Francisco Javier

    2001-06-01

    Full Text Available The archeological field work on the Bronze Age site of Terlinques (Villena, Alicante has given an exceptional sample of spindles or bobbins of rush fibre of yarn in a room destroyed by a violent fire. A meticulous study of these special objects and their process of analysis and restoration yields new perspectives on knowledge in first stages of textile production during Bronze Age in Eastern Spain.

    Los trabajos arqueológicos que se llevan a cabo en el yacimiento de la Edad del Bronce de Terlinques (Villena, Alicante han proporcionado un excepcional conjunto de husos o bobinas de hilo de junco. Éstos se hallaban almacenados en el interior de una habitación destruida por un violento incendio. El detenido estudio de estos singulares objetos y su proceso de análisis y restauración nos permite aproximamos, desde nuevas perspectivas, al conocimiento de la producción textil en las etapas iniciales de la Edad del Bronce en el Levante de la Península Ibérica.

  8. Development and mass production of bronze-processed Nb3Sn strand with low AC loss and high critical-current density for the ITER

    International Nuclear Information System (INIS)

    The development work and mass production of high-performance bronze-processed Nb3Sn superconducting strands for the ITER pulse coils were performed. Using fine hexagonal single-core rods, the undesirable deformation of filament shape was drastically improved and uniform filament-spacing was obtained. As the result, Nb3Sn strand having a bronze/Nb ratio of 2.3 and filament diameter of 3.0 μm showed a very high non-Cu Jc of 667 A/mm2 at 12 T and 4.2 K without external strain. Sufficient low hysteresis loss of 88.2 mJ/cm3 at ±3 T was also observed. These results fully satisfy ITER specifications. The maximum piece length reached 18.9 km, while average piece length was 8.5 km, thus proving excellent workability. By applying the developed technology, mass production of 1,280 km in total was successfully completed. This means that the mass-production technology for the high-performance Nb3Sn superconducting strand of the ITER was established; thus clearing the way for construction of the reactor. (author)

  9. Corrosion evaluation of multi-pass welded nickel–aluminum bronze alloy in 3.5% sodium chloride solution: A restorative application of gas tungsten arc welding process

    International Nuclear Information System (INIS)

    Highlights: • Corrosion of GTA welded nickel–aluminum bronze (C95800) was studied. • Drastic microstructural changes occurred during the welding operations. • The β′ and α phases acts as anode and cathode, correspondingly, in weld region. • A few nanoamperes couple current was measured in ZRA test as galvanic corrosion. • Corrosion resistance of weld parts could not be weakened in marine environments. - Abstract: In this research, the corrosion behavior of a gas tungsten arc welded nickel–aluminum bronze (NAB) alloy is investigated by DC and AC electrochemical techniques in 3.5% sodium chloride solution. Regarding the electrochemical impedance spectroscopy and potentiodynamic results, uniform corrosion resistance of instantly immersed weld and base samples are almost analogous and increased (more in weld region) during the immersion times. Moreover, zero resistant ammeter results demonstrated that the few nanoampere galvanic currents are attributed to microstructural and morphological differences between these two regions. Therefore, the welding procedure could not deteriorate the general corrosion resistance of the restored damaged NAB parts operating in marine environments

  10. Lead isotopic analysis within a multiproxy approach to trace pottery sources. The example of White Slip II sherds from Late Bronze Age sites in Cyprus and Syria

    International Nuclear Information System (INIS)

    Lead isotope analyses were carried out on fragments of White Slip II ware, a Late Bronze Age Cypriote pottery ware, and on raw materials possibly used for their production. Sherds originate from three Late Bronze Age sites (Hala Sultan Tekke and Sanidha in Cyprus and Minet el-Beida in Syria) and clays come from the surroundings of Sanidha, a production site for White Slip ware. X-ray fluorescence (XRF) and a Principal Component Analysis (PCA) are combined with Pb isotope analyses to further investigate the effectiveness of the latter method within a multiproxy approach for pottery provenance study. The pottery sherds from the three sites are compared between themselves and with potential raw material. Additional X-ray diffraction (XRD) and analyses using a scanning electron microscope (SEM) equipped with an energy dispersive X-ray detection (EDX) facility were performed on selected sherds and clays. This work confirms that the clay source used for pottery production in Sanidha derives from local weathered gabbro. It also shows that different origins can be proposed for White Slip II ware sherds from Hala Sultan Tekke and Minet el-Beida and that clays were prepared prior to White Slip II ware production. It finally confirms the effectiveness of Pb isotopes in tracing pottery provenance not only by comparing sherd assemblages but also by comparing sherds to potential raw materials.

  11. A Analysis about the Structure Features of Inscriptions on Ancient Bronze Ware of Xizhou Dynasty%西周金文构形特征探析

    Institute of Scientific and Technical Information of China (English)

    王瑞英

    2012-01-01

    西周金文处于汉字体系的形成和发展时期。西周铜器铭文中图形文字向方块字体转变,偏旁部首增加并趋于成熟,汉字形体结构日益完善,形声结构迅速增长。对西周金文构形特征的考察能够深入了解文字发展变化的过程,从而有助于探求汉字的发展变化规律。%The inscriptions on ancient bronze wares of Xizhou Dynasty are the embryonic characters when the Chinese characters system formed and developed. Its pictographic scripts evolve into square -shaped charac- ters with the increase and perfection of character components. Meanwhile, its form and structure are increas- ingly perfect with the large number of inscriptions on ancient bronze ware. The analysis about the structure fea- tures of inscriptions can help to explore the evolution and the principles of the change and development of Chi- nese characters.

  12. The Metallurgy of the Sicilian Final Bronze Age/Early Iron Age necropolis of Madonna del Piano (Catania, Sicily

    Directory of Open Access Journals (Sweden)

    Giumlia-Mair, Alessandra

    2010-12-01

    Full Text Available This paper presents the analysis results of the copper- based finds, from the important Sicilian necropolis of Madonna del Piano, near Grammichele (Catania, dated between the local Final Bronze Age 2 and the Early Iron Age IA. 122 copper-based finds from the 273 graves (1970-71 of the large cemetery have been analysed. The sampled objects belong to different classes, there are for instance weapons of offence and defence, such as swords and greaves, small decorative objects for personal use, such as rings, fibulae, belt hooks, belt decorations, and small tools, such as the knives used by women, reels, needles and razors, but also small functional parts, such as rivets and nails, repairs and even a kind of musical instrument, such as the tintinnabula. The methods employed were AAS and SEM, where possible, and XRF in all cases. The aim of the research was that of evaluating the skill of the local artisans, of determining the most common copper-based alloys in use in Sicily in this period and comparing the data with the analysis results of contemporary groups of finds from other areas of the Italian peninsula and from other European regions.

    El artículo presenta el resultado de los análisis realizados a los metales de base cobre de la importante necrópolis siciliana de Madonna del Piano, próxima a Grammichele (Catania, fechada entre el Bronce Final 2 y la Primera Edad del Hierro IA. Se han estudiado un total de 122 objetos de base cobre procedentes de 273 tumbas excavadas entre 1970 y 1971. Los objetos muestreados pertenecen a diferentes tipos, armas ofensivas y defensivas tales como espadas y grebas, pequeños objetos de uso personal como anillos, fíbulas, broches de cinturón y pequeñas herramientas como cuchillos usados por las mujeres, carretes, agujas, navajas, pero también elementos funcionales como remaches, clavos y un tipo de instrumento como el tintinábulo. Los métodos de análisis utilizados fueron AAS y SEM, cuando fue

  13. 试论邳州九女墩三号墩出土的青铜器%On the Bronzes from the No. 3 Mound at Jiunüdun in Pizhou

    Institute of Scientific and Technical Information of China (English)

    孔令远

    2002-01-01

    The bronzes from Mound No. 3 at Jiunuudun contain elements of many cultures. In type, for example, there are the ding tripod with an inverted-dish-shaped cover, the swing-chained pot and the covered dou stemmed vessel commonly seen on contemporaneous vestiges in the Central Plains and the Qi and Lu states. On the other hand, among the finds are the Tang ding, zun vase, dragon-head-shaped he tripod and fou pot characteristic of contemporaneous tombs of the Wu and Yue states.Another type of bronze object is the animal-head ding previously yielded mainly from the territory of ancient Shu ethnic group. Moreover, there is a batch of bronzes typical of the Xu State, such as the chime-bells decorated with winged-animal-shaped scrolls, ear-less leg-less washing basin, incense burner tray with the base on a post-shaped ring-foot. In decorative style, one can see elements of the Rong and Di cultures. Evidently the bronze culture of the Xu State in the late Spring and Autumn period possessed rich cultural connotations.

  14. NaCl盐膜对铝青铜高温氧化行为的影响%Effect of NaCl Film on Oxidation Behavior of Aluminum Bronze at High Temperature

    Institute of Scientific and Technical Information of China (English)

    李占鑫

    2009-01-01

    采用金相检验、X射线衍射、扫描电镜/能谱及热重分析法研究了涂有NaCl盐膜的铝青铜在700~900℃的氧化行为.结果表明,在NaCl盐膜的作用下,铝青铜中的铝较铜先腐蚀,所形成的氧化膜结构疏松,易开裂和剥落,从而加速铝的氧化过程.此外,还讨论了NaCl加速铝青铜氧化的机制.%The oxidation behavior of aluminum bronze coated with a NaCl film was studied by means of metallosco-py,XRD,SEM/EDS and thermogravimetry. The results show that because of the effect of NaCl film the aluminum will be eroded earlier than the copper in aluminum bronze and the oxide film produced will be loose and easy to crack and spall, with the oxidation of aluminum bronze accelerated. In addition, the mechanism for NaCl film to ac-celerate the oxidation of aluminum bronze was discussed, too.

  15. Field Installation of the Giant Bronze Sculpture "Horse and Dragon"%巨型青铜雕塑《马与龙》的现场安装

    Institute of Scientific and Technical Information of China (English)

    李国平; 胡春良

    2016-01-01

    对安装于美国佛罗里达州迈阿密市湾流公园的巨型青铜雕塑《马与龙》施工安装过程进行介绍,阐述了数据采集、数据控制、钢结构设计、安装的全过程检查等技术,这对中国铸造大型雕塑的安装具有现实的借鉴意义。%The construction and installation process of the giant bronze sculpture “Horse and Dragon” installed in the gulf stream park in Miami city in Florida has been introduced. The technologies including data acquisition, data control, steel structure design, and the whole process inspection of installation have been described, which has practical reference signiifcance for the large casting sculpture installation in China.

  16. Non-linear transport properties of pure, Rb- and W-doped blue bronze K0.3MoO3

    International Nuclear Information System (INIS)

    The temperature dependence of the dc resistivity and the non-linear transport properties of pure, Rb-doped, and W-doped blue bronze K0.3MoO3 single crystals are presented. These are prototypical charge-density-wave (CDW) compounds. Nonlinear conductivity due to the sliding of the CDW is observed, when the applied electric field exceeds the first threshold field (ET). Furthermore, above a second threshold field (ET*>ET) coherent CDW-sliding sets in. For all studied materials ET and ET* increase monotonically with decreasing temperature. This finding is discussed in terms of the incommensurate-commensurate transition of the CDW and within the frame of the Fukuyama-Lee-Rice model.

  17. Gold pickings and PIXE analysis. More about the Bronze age gold found in the cave of Han-sur-Lesse (Namur, Belgium)

    Energy Technology Data Exchange (ETDEWEB)

    Warmenbol, Eugene E-mail: ewarmenb@ulb.ac.be

    2004-11-01

    Gold remains a rare material during the whole Bronze Age. It is a metal that circulates amongst the elites exclusively. The exchange of gold artefacts over very long distances is fundamental in the build-up of socio-political relations. Fifty artefacts found during subaquatic excavations in the river Lesse in the cave of Han-sur-Lesse have been submitted to quantitative elemental analysis using PIXE, a method never used before on archaeological material found in Belgium. The results show that there are clearly three groups of artefacts. The first one (discs, 'baskets', pearls) proves of local manufacture, as also suggested by the discovery of two ingots. The second one (gilded rings) could have been locally made too, but is a lot less homogeneous. The third one (filigreed and granulated beads or pin's heads) must be imported and most probably originates in the Mediterranean.

  18. Les composantes culturelles des premières productions céramiques au Bronze ancien dans le sud-est de la France

    OpenAIRE

    Vital, Joël

    2013-01-01

    Identifiant de l'opération archéologique : 109 Date de l'opération : 2003 - 2007 (PC) Les travaux du PCR « Composantes culturelles des premières productions céramiques du Bronze ancien dans le sud-est de la France » qui se sont déroulés en 2006 clôturent un cycle de trois années de travaux initiés en 2003 (BSR 2003, p. 124 ; BSR 2004, p. 212 ; BSR 2005, p. 136). Quelques prolongements seront probablement nécessaires en 2007 pour des raisons de difficultés d’accès à certains mobiliers, mais qu...

  19. Iron-Age bronze statuettes in Southern Portugal: combining archaeological data with EDXRF and BSEM + EDS to assess provenance and production technology

    Science.gov (United States)

    Schiavon, Nick; Celauro, Angela; Manso, Marta; Brunetti, Antonio; Susanna, Fiammetta

    2013-12-01

    A simple, fast, and nondestructive analytical methodology combining X-ray Fluorescence (EDXRF) and Back-scattered Electron Microscopy coupled with Energy Dispersive Spectroscopy (BSEM+EDS) has been applied to characterize the alloy's composition of ex-votos metal statuettes of unknown provenance and age stored in the Museum of Évora in Southern Portugal, and to compare it with Iron-Age artefacts of similar typology recovered from the well-known Phoenician settlement (7th century BC) of Alcàcer do Sal located about 50 km W of Évora. The aim of the study was two-fold: (a) to confirm the age and provenance of the bronzes from the Alcàcer settlement; (b) to assess whether the combined archaeometric approach could shed light on the interaction between local (Iberian peninsula) and allochtonous (Phoenician) technological know-how and on how the "Orientalizing" Phoenician influence had been modulated locally in the making of metal artifacts. In this respect, for comparative purposes, selected bronze statuettes displaying "Orientalizing" features of inferred Phoenician origin from the Nuragic collection of the National Archaeological Museum in Cagliari and the G.A. Sanna Museum of Sassari, Sardinia, were also analyzed by EDXRF. Results indicate that all statuettes are made of an alloy of Cu/Sn or Cu/Sn/Pb with variable Sn and Pb content. The presence and content of Pb and of Fe (the latter always >0.05 %) in the alloy suggest a production technology involving the smelting of ferrous minerals and/or the use of reducing firing conditions with locally available Pb intentionally added as fluxing agent. The alloy's compositional data is consistent with a provenance of the Évora statuettes from the known Phoenician settlement of Alcàcer do Sal in Southern Portugal.

  20. Metallurgical and chemical characterization of copper alloy reference materials within laser ablation inductively coupled plasma mass spectrometry: Method development for minimally-invasive analysis of ancient bronze objects

    Energy Technology Data Exchange (ETDEWEB)

    Walaszek, Damian, E-mail: damian.walaszek@empa.ch [Laboratory for Analytical Chemistry, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland); University of Warsaw, Faculty of Chemistry, Pasteura 1, 02-093 Warsaw (Poland); Senn, Marianne [Laboratory for Analytical Chemistry, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland); Faller, Markus [Laboratory for Jointing Technology and Corrosion, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland); Philippe, Laetitia [Laboratory for Mechanics of Materials and Nanostructures, Swiss Federal Laboratories for Materials Science and Technology, Feuerwerkstrasse 39, CH-3602 Thun (Switzerland); Wagner, Barbara; Bulska, Ewa [University of Warsaw, Faculty of Chemistry, Pasteura 1, 02-093 Warsaw (Poland); Ulrich, Andrea [Laboratory for Analytical Chemistry, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland)

    2013-01-01

    The chemical composition of ancient metal objects provides important information for manufacturing studies and authenticity verification of ancient copper or bronze artifacts. Non- or minimal-destructive analytical methods are preferred to mitigate visible damage. Laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) enables the determination of major elements as well as impurities down to lower ppm-levels, however, accuracy and precision of analysis strongly depend on the homogeneity of reference materials used for calibration. Moreover, appropriate analytical procedures are required e.g. in terms of ablation strategies (scan mode, spot size, etc.). This study reviews available copper alloy (certified) reference materials — (C)RMs from different sources and contributes new metallurgical data on homogeneity and spatial elemental distribution. Investigations of the standards were performed by optical and scanning electron microscopy with X-ray spectrometry (SEM-EDX) for the following copper alloy and bronze (certified) reference materials: NIST 454, BAM 374, BAM 211, BAM 227, BAM 374, BAM 378, BAS 50.01-2, BAS 50.03-4, and BAS 50.04-4. Additionally, the influence of inhomogeneities on different ablation and calibration strategies is evaluated to define an optimum analytical strategy in terms of line scan versus single spot ablation, variation of spot size, selection of the most appropriate RMs or minimum number of calibration reference materials. - Highlights: ► New metallographic data for copper alloy reference materials are provided. ► Influence of RMs homogeneity on quality of LA-ICPMS analysis was evaluated. ► Ablation and calibration strategies were critically discussed. ► An LA-ICPMS method is proposed for analyzing most typical ancient copper alloys.

  1. 汉代翠鸟铜饰研究%A Study on the Kingfisher-shaped Bronze Ornaments of the Han Dynasty

    Institute of Scientific and Technical Information of China (English)

    马晓亮

    2011-01-01

    Kingfisher-shaped bronze ornament is a kind of small-sized artifact unearthed in the Southwest China,to date 25 pieces of which have been found.Except for very few ones which are not archaeologically discovered,most of them are recovered from burials.According to the styles of the burials and the coexisting artifacts,these kingfisher ornaments mainly belong to the Eastern Han Dynasty with some later ones to the Three-Kingdoms Period.In addition to that of the kingfisher,some ornaments are also made in the shapes of jars,coins,fish and winged humans.By analyzing the connotations of these ornaments,we can confirm that the kingfisher-shaped ornament is a special talisman or symbol showing the desires of good fortune,richness and immortality and so on of the people at that time.The kingfisher-shaped bronze ornament can be used as components of money tree and also can be used independently.%我国西南地区的汉墓中出土了若干小鸟造型的青铜器,鸟背上或有罐、钱币、羽人等形象,鸟嘴中有的还衔有鱼。在相关考古报告中,对这些鸟的类型有不同的认识,对于器物的用途也缺乏合理解释。通过对相关资料的系统分析和比较,根据这类铜器中小鸟具有头大、颈短、尾短、喙长的特点,

  2. A Preliminary Study on Early Bronze Wares from Western Himalaya%西喜马拉雅早期青铜器初论

    Institute of Scientific and Technical Information of China (English)

    吕红亮

    2012-01-01

    Since the archaeological survey in Tibet in 1990, Chinese archaeologists have found tombs and settlements dated to the early Metal Age in western Tibet, from which several bronze wares have been excavated. This article compares the cultural properties of these bronze wares with those discovered in surrounding areas such as eastern Qinghai-Tibet Plateau, Mustang in northern Nepal, northern Pakistan and northwestern India. The author argues that there were two routes for the transmission of Eurasia Steppe culture to the western Himalaya region - the east route and the west route - and this was related with the long-distance trade across the Qinghai- Tibet Plateau at that time.%1990年西藏文物普查开展以来,我国考古学家陆续在西藏西部发现一批属于早期金属时代的墓葬与居址,其中出土若干青铜器。本文结合周边地区如青藏高原东部、尼泊尔北部的穆斯塘地区、巴基斯坦北部地区、印度西北部的考古发现,对相关青铜器的文化属性予以比较讨论,认为欧亚草原文化因素自东、西两个不同方向辗转进入西喜马拉雅地区,这当与跨青藏高原的长距离贸易相关。

  3. Behavior of the monophosphate tungsten bronzes (PO{sub 2}){sub 4}(WO{sub 3}){sub 2m} (m = 7 and 8) in the course of electrochemical lithium insertion

    Energy Technology Data Exchange (ETDEWEB)

    Martinez-de la Cruz, A. [Division de Estudios de Posgrado, Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon, Pedro de Alba s/n, Ciudad Universitaria, C.P. 66451, San Nicolas de los Garza, N.L. (Mexico); Longoria Rodriguez, F.E.; Gonzalez, Lucy T. [Departamento de Quimica, Unidad de Cursos Basicos, Nucleo Monagas, UDO, Av Universidad Los Guaritos, Maturin, Monagas (Venezuela); Torres-Martinez, Leticia M. [Facultad de Ingenieria Civil, Universidad Autonoma de Nuevo Leon, Av Universidad s/n, San Nicolas de los Garza, N.L. (Mexico)

    2007-07-10

    The electrochemical lithium insertion process has been studied in the family of monophosphate tungsten bronzes (PO{sub 2}){sub 4}(WO{sub 3}){sub 2m}, where m = 7 and 8. Structural changes in the pristine oxides were followed as lithium insertion proceeded. Through potentiostatic intermittent technique the different processes which take place in the cathode during the discharge of the cell were analyzed. The nature of the bronzes Li{sub x}(PO{sub 2}){sub 4}(WO{sub 3}){sub 2m} formed was determined by in situ X-ray diffraction experiments. These results have allowed establishing a correlation with the reversible/irreversible processes detected during the electrochemical lithium insertion. (author)

  4. From the Copper Age to the Bronze Age in the Lower Guadalquivir Basin. The Cerro de San Juan settlement (Coria del Río, Seville, Spain and the ‘replacement model’

    Directory of Open Access Journals (Sweden)

    Daniel GARCÍA RIVERO

    2015-11-01

    Full Text Available The transition between Copper and Bronze Ages in the Southwest of the Iberian Peninsula is poorly known still, especially when compared with the transition between Los Millares culture to El Argar culture in the Southeast. The settlement of Cerro de San Juan, which controlled the Guadalquivir mouth at that time, shows some evidences of human occupations of both periods, an uncommon feature along the South of Iberian Peninsula. The data from this site suggest a sedimentary break between the two periods, and a strong cultural change as well. The culture material sets are different between the Bell Beaker phase and the Bronze Age, and several radiocarbon dates define consistently the chronology of the phenomenon. From this perspective, an analysis of every archaeological stratigraphy that has evidences of both periods is carried out. Against a model of cultural continuity, numerous archaeological features rather suggest a model of demographic replacement. Thus, the Bronze Age can be defined as a new way of life perhaps by human groups that were not direct descendants of the previous communities.

  5. 磷铜网加铅球填料回热器的换热性能分析%Analysis of convection heat transfer performance of regenerator with phosphor bronze and lead matrix

    Institute of Scientific and Technical Information of China (English)

    唐景春; 左承基; 陈长琦; 申晓亮

    2012-01-01

    Based on the structure of the phosphor bronze and lead matrix in the regenerator of G-M cryocooler, numerical simulation of the dynamic laws of the helium temperature in the regenerator of G-M cryocooler is carried out. According to the field synergy principle, the convection heat transfer performance of the regenerator with phosphor bronze and lead matrix is analyzed. Furthermore, the experiments on the refrigerating capability of different kinds of regenerator matrixes are conducted, and the reasonable filling ratio between phosphor bronze and lead, is obtained.%文章基于G-M低温制冷机装置,以磷铜网加铅球填料回热器为研究对象,通过数值模拟方法,得出了G-M制冷机回热器内部氦工质温度参数的动态变化规律;利用对流换热的场协同理论,对比分析采用磷铜网加铅球作为回热器填料的对流换热性能;针对不同填料类型的回热器进行了G-M低温制冷机整机换热性能对比实验,得出了提高整机换热性能的磷铜网与铅球的填充比例.

  6. 榆次猫儿岭战国熊鸟纹青铜带钩的文化内涵%Culture Connotation of Warring States Bronze Belt Hook with Bear and Bird Decoration of Maoerling Yuci

    Institute of Scientific and Technical Information of China (English)

    康艳

    2012-01-01

    Unearthed in Maoerling ancient tomb, Yuci District, Jinzhong City, bronze Belt-hook with bear and bird decoration is the competitive product, because of the unique decoration, beautiful design and fine craft. This bronze belt-hook imitated the shape of bear and bird respectively in hook body and head. And a high relief way was adopted to display the shape of bird and bear. The designer perfectly decorated a piece of bronze belt hook with bares and birds, employed muhiply artistic techniques, for example, imitation, freehand brushwork, pattenaing and so on, which showed the imagination and creativity of the designer and meanwhile invested the hook with colorful culture connotation.%晋中市榆次区猫儿岭战国古墓出土的熊鸟纹青铜带钩以其独特的装饰、秀美的造型和精湛的工艺而成为艺术精品。此带钧钩体肖熊形,钩首模拟鸟形;采用高浮雕形式,结合模拟、写意、图案化等多种手法完美地将熊、鸟饰于一件器物之上,体现了设计者丰富的想象力和创造力,同时也赋予其丰富的文化内涵。

  7. Observações sôbre o bronzeado do algodoeiro Mocó Observations on bronzing of the Mocó cotton

    Directory of Open Access Journals (Sweden)

    A. S. Costa

    1955-01-01

    Full Text Available Uma anomalia do algodoeiro Mocó, denominada bronzeado, vem sendo observada na região do Seridó, Rio Grande do Norte, durante os últimos três anos. Pensou-se, a princípio, que esta anomalia fôsse causada por um vírus, mas as observações relatadas neste trabalho indicam que é causada por um ácaro. As fôlhas das plantas afetadas, especialmente aquelas da metade superior dos galhos, mostram uma coloração bronzeada no lado de baixo. Essa face da fôlha tem também uma superfície rugosa, com brilho vidrado (est. 1, B, as vezes com pequenas áreas de tecido cicatricial. Vistas pelo lado de cima são mais rugosas do que as normais e têm os bordos curvados para baixo. Nos casos graves, as fôlhas do topo dos galhos morrem e caem (est. 2, A e B. A espécie de ácaro causadora do bronzeado do algodoeiro Mocó foi identificada por H. H. Keifer, Sacramento, Calif., como pertencente a um gênero ainda não descrito da família Eriophyidae. Esta espécie está sendo presentemente denominada Anthocoptes sp. até que a sua descrição seja publicada. Populações de 500 a 1.000 indivíduos por centímetro quadrado de fôlha já foram encontradas. Esse ácaro parece ser muito sensível às condições do ambiente, visto que as populações da praga variam entre grandes limites.For the last three years a bronzing anomaly of cotton plants of the Mocó variety (Gossypium hirsutum L. var. maria galante Hutch. has been recorded in the Seridó region (a semi-arid region in the north-eastern part of Brazil, state of Rio Grande do Norte. This anomaly was first thought to be of virus origin, but the observations reported in this paper indicated that it is due to the attack by a species of mite. Leaves from affected plants, especially those on the upper half of the branches, show a bronzing discoloration on the dorsal side, frequently accompanied by a rough and ventral side of these leaves shows some rugosity not present in normal leaves, and in most cases

  8. 中国古青铜器表面富锡铜鎏镀及鎏焊的工艺探索 第一部分——富锡铜鎏镀在古青铜器中的应用%Technological study on amalgam coating and brazing of tin-rich copper on surface of bronze wares of ancient China—Part Ⅰ.Application of amalgam coating of tin-rich copper in ancient bronze wares

    Institute of Scientific and Technical Information of China (English)

    吴元康; 储荣邦

    2012-01-01

    The ancient bronze wares with Sn-rich copper coatings on their surfaces were introduced based on the archaeological findings in China. The definition and classification of amalgam coating were described. It is pointed out that most ancient bronze wares were treated by amalgam coating of Sn-rich copper, not by hot-dip plating or other processes. The removal of Hg by heating after amalgam coating and the decomposition of Sn7-9Hg in soil lead to the fact that Hg is undetectable on the surface of ancient bronze wares.%根据出土文物的情况,介绍了表面具有富锡铜层的古青铜器.阐述了鎏镀的定义及分类.指出古青铜器大多经过富锡铜鎏镀工艺处理,而不是热浸镀或其他工艺.认为鎏镀后加热驱汞及Sn7-9Hg在土壤环境中分解,是导致古青铜器表面测不出汞的原因.

  9. Methodological Developments in 3d Scanning and Modelling of Archaeological French Heritage Site : the Bronze Age Painted Cave of "LES FRAUX", Dordogne (france)

    Science.gov (United States)

    Burens, A.; Grussenmeyer, P.; Guillemin, S.; Carozza, L.; Lévêque, F.; Mathé, V.

    2013-07-01

    For six years, an interdisciplinary team of archaeologists, surveyors, environmentalists and archaeometrists have jointly carried out the study of a Bronze Age painted cave, registrered in the French Historical Monuments. The archaeological cave of Les Fraux (Saint-Martin-de-Fressengeas, Dordogne) forms a wide network of galleries, characterized by the exceptional richness of its archaeological remains such as ceramic and metal deposits, parietal representation and about domestic fireplaces. This cave is the only protohistorical site in Europe wherein are gathered testimonies of domestic, spiritual and artistic activities. Fortunately, the cave was closed at the end of the Bronze Age, following to the collapse of its entrance. The site was re-discovered in 1989 and its study started in 2007. The study in progress takes place in a new kind of tool founded by the CNRS's Institute of Ecology and Environment. The purpose of this observatory is the promotion of new methodologies and experimental studies in Global Ecology. In that framework, 3D models of the cave constitute the common work support and the best way for scientific communication for the various studies conducted on the site by nearly forty researchers. In this specific context, a partnership among archaeologists and surveyors from INSA Strasbourg allows the team to develop, in an interdisciplinary way, new methods of data acquiring based on contact-free measurements techniques in order to acquire a full 3D-documentation. This work is conducted in compliance with the integrity of the site. Different techniques based on Terrestrial Laser Scanning, Digital Photogrammetry and Spatial Imaging System have been used in order to generate a geometric and photorealistic 3D model from the combination of point clouds and photogrammetric images, for both visualization and accurate documentation purposes. Various scales of acquiring and diverse resolutions have been applied according to the subject: global volume cave

  10. Use of ns and fs pulse excitation in laser-induced breakdown spectroscopy to improve its analytical performances: A case study on quaternary bronze alloys

    Energy Technology Data Exchange (ETDEWEB)

    Almaviva, Salvatore [ENEA, UTAPRAD, V. E. Fermi 45, 00044 Frascati (Italy); Fantoni, Roberta, E-mail: roberta.fantoni@enea.it [ENEA, UTAPRAD, V. E. Fermi 45, 00044 Frascati (Italy); Caneve, Luisa; Colao, Francesco [ENEA, UTAPRAD, V. E. Fermi 45, 00044 Frascati (Italy); Fornarini, Lucilla [ENEA,UTTAMB, SP Anguillarese 301, Roma (Italy); Santagata, Antonio [CNR-IMIP, UOS Potenza, Zona Industriale, 85050 Tito Scalo (PZ) (Italy); Teghil, Roberto [Università degli Studi della Basilicata, Dipartimento di Scienze, Via dell' Ateneo Lucano 10, 85100 Potenza (Italy)

    2014-09-01

    Analytical performances of Laser Induced Breakdown Spectroscopy (LIBS) resulted not fully satisfactory in some cases such as historical bronzes, therefore, efforts should be focussed on improving ablation efficiency and on better understanding the plasma parameter evolution. To this aim a set of double pulse experiments have been carried out in almost collinear geometry at about 530 nm laser excitation. The first emitting source was either a ns or a fs laser the second a ns one. Data were collected as a function of the interpulse delay, in order to determine the ablation efficiency increase, to study the kinetics of plasma parameters (temperature, electron density) and the decay of atomic and ionic intensities with respect to the optical background. In parallel a previously developed model for laser ablation, ionization and following plasma decay, was implemented, adding a second laser pulse, to analyse the double pulse excitation in the considered geometry, and the time evolution of the same variables was investigated. Model results are able to reproduce the observed experimental trends and support the possibility of improving analytical performances by using the double pulse technique with inter-pulse delays in the entire investigated range. - Highlights: • The Double Pulse LIBS technique is applied to a quaternary metal alloy sample. • Two different Double Pulse LIBS configurations are investigated. • Signal enhancement was experimentally verified in the Double Pulse technique. • Comparison of the experimental results with the proposed theoretical model • Dependence of the LIBS signal by some experimental parameters.

  11. Paleosols and climate in the southeast of the Central Russian Upland during the Middle and Late Bronze ages (the 25th-15th Centuries BC)

    Science.gov (United States)

    Demkin, V. A.; Borisov, A. V.; Udal'Tsov, S. N.

    2010-01-01

    Paleosol studies of kurgans dating back to the Middle and Late Bronze ages (the Catacomb, Pokrovskaya, and Srubnaya cultural epochs; 4500-3500 BP) have been performed within the dry steppe zone in the southeast of the Central Russian Upland. The studied kurgans occupy the upper parts of local interfluves differing in the lithology of their upper horizons. The specificity of the Middle Holocene pedogenesis as related to the local lithologic and geomorphic conditions has been characterized. During the past 4500 years, local soils have been subjected to evolutionary changes related to climatic fluctuations. These changes manifested themselves at the subtype level with substitution of dark chestnut soils for chestnut soils. The climatic conditions during the Catacomb and Pokrovskaya cultural epochs (4.5-3.8 ka BP) were more arid than those at present. The maximum aridization of the climate took place at the end of the third and the first quarter of the second millennia BC. Detailed descriptions of the morphology of kurgan bodies and buried paleosols make it possible to hypothesize about the seasons of the kurgan construction and the technology of this work.

  12. Study of settlement distribution pattern in the Kolkheti lowland (Black Sea coast of Georgia) starting from early Bronze Age - natural and human influence and adaptation to landscape evolution

    Science.gov (United States)

    Elashvili, Mikheil; Akhvlediani, Dimitri; Navrozashvili, Levan; Sukhishvili, Lasha; Kirkitadze, Giorgi; Kelterbaum, Daniel; Laermans, Hannes

    2015-04-01

    During the past decades the question of a changing environment/nature became crucial. Actually we are trying to understand its nature or to predict future changes and their possible effects represent the main goals of many interdisciplinary studies. Therefore, the study of paleoenvironmental changes delivers key information for a better understanding of the whole process and especially the influence of these changes on human society. The selected research topic is dictated by the fact that the Colchis lowland played an important role in the history of old societies (countries and empires). Especially the interaction between developing human societies under the pressure of a changing environment are most interesting in this context. The Kolkheti valley and the Black Sea shore represent a region involved in many global historical events, starting from the Myth of Argonauts and followed by the ancient greek colonization, the Kingdom of Pontus ending at the Roman and Byzantine empires. River Phasis (present Rioni) was an important segment in trade way between the Mediterranean and India and the East in general. In addition it is the area of the "lost or vanished" city of Phasis, an ancient and early medieval city, founded in the 7th or 6th century BC as a colony of the Milesian Greeks at the mouth of the river Phasis, near the modern-day seaport Poti. Considering the local history of Georgia, this is the area of formation of the Kolkhys (Colchis) culture in late bronze-early iron periods, forming Colchis and later on the Lazika kingdoms. It is important to note that the archaeology and geomorphology of the seashore of Georgia is rather scarcely studied (mainly in the 1970s during soviet era). It is quite clear that the history of the region will not be deciphered without the reconstruction of the paleo and historical environment. The study based on an ongoing collaboration between the University of Cologne and the Ilia State University. Actually, geomorphological and

  13. Maternal and paternal genetic diversity of ancient sheep in Estonia from the Late Bronze Age to the post-medieval period and comparison with other regions in Eurasia.

    Science.gov (United States)

    Rannamäe, E; Lõugas, L; Niemi, M; Kantanen, J; Maldre, L; Kadõrova, N; Saarma, U

    2016-04-01

    Sheep were among the first domesticated animals to appear in Estonia in the late Neolithic and became one of the most widespread livestock species in the region from the Late Bronze Age onwards. However, the origin and historical expansion of local sheep populations in Estonia remain poorly understood. Here, we analysed fragments of the hypervariable D-loop of mitochondrial DNA (mtDNA; 213 bp) and the Y-chromosome SRY gene (130 bp) extracted from 31 archaeological sheep bones dated from approximately 800 BC to 1700 AD. The ancient DNA data of sheep from Estonia were compared with ancient sheep from Finland as well as a set of contemporary sheep breeds from across Eurasia in order to place them in a wider phylogeographical context. The analysis shows that: (i) 24 successfully amplified and analysed mtDNA sequences of ancient sheep cluster into two haplogroups, A and B, of which B is predominant; (ii) four of the ancient mtDNA haplotypes are novel; (iii) higher mtDNA haplotype diversity occurred during the Middle Ages as compared to other periods, a fact concordant with the historical context of expanding international trade during the Middle Ages; (iv) the proportion of rarer haplotypes declined during the expansion of sheep from the Near Eastern domestication centre to the northern European region; (v) three male samples showed the presence of the characteristic northern European haplotype, SNP G-oY1 of the Y-chromosome, and represent the earliest occurrence of this haplotype. Our results provide the first insight into the genetic diversity and phylogeographical background of ancient sheep in Estonia and provide basis for further studies on the temporal fluctuations of ancient sheep populations. PMID:26805771

  14. On the nature of phase transitions in the tetragonal tungsten bronze GdK{sub 2}Nb{sub 5}O{sub 15} ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Gagou, Y.; Lukyanchuk, I.; El Marssi, M., E-mail: mimoun.elmarssi@u-picardie.fr [Laboratoire de Physique de la Matière Condensée, Université de Picardie Jules Verne, 33 rue Saint-Leu, 80039 Amiens Cedex (France); Amira, Y. [Laboratoire de Physique de la Matière Condensée, Université de Picardie Jules Verne, 33 rue Saint-Leu, 80039 Amiens Cedex (France); Laboratoire de la Matière Condensée et Nanostructures, FSTG, Université Cadi Ayyad Marrakech, Maroc (Morocco); Mezzane, D. [Laboratoire de la Matière Condensée et Nanostructures, FSTG, Université Cadi Ayyad Marrakech, Maroc (Morocco); Courty, M.; Masquelier, C. [Laboratoire de Réactivité et Chimie des Solides, UMR 7314, Université de Picardie Jules Verne, Pôle Scientifique, 33 rue Saint-Leu, 80039 Amiens Cedex 1 (France); Yuzyuk, Yu. I. [Faculty of Physics, Southern Federal University, 5, Zorge Str. Rostov-on-Don 344090 (Russian Federation)

    2014-02-14

    Phase transitions in gadolinium potassium niobate GdK{sub 2}Nb{sub 5}O{sub 15} (GKN) ceramics have been investigated by x-ray diffraction, dielectric susceptibility, differential scanning calorimetry, and Raman scattering. The results of our complementary studies show that GKN exhibits two phase transitions at T{sub c1} = 238 °C and T{sub c2} = 375 °C attributed to the ferroelectric-antiferroelectric-paraelectric (FE-AFE-PE) phase transitions. According to the x-ray diffraction analysis, the FE and PE phases were refined in the polar P4bm and centrosymmetric P4/mbm space groups. For the intermediate phase, the structure is refined in the space group P4nc with doubling of the c unit cell parameter, which is compatible with an AFE phase. This result was confirmed by Raman spectroscopy since new low-frequency lines are activated in the AFE phase due to the Brillouin zone-folding effect, typical for the modulated phases. The presence of the AFE phase between the FE and PE phases and the complex nature of tetragonal tungsten bronze crystal structure can explain the large thermal hysteresis observed at the FE-AFE transition between heating and cooling cycle and the strong depression of the Curie-Weiss temperature T{sub 0}. The semi-phenomenological Ising-like model based on the obtained experimental data is proposed to account for the observed FE-AFE-PE transition sequence.

  15. Online, efficient and precision laser profiling of bronze-bonded diamond grinding wheels based on a single-layer deep-cutting intermittent feeding method

    Science.gov (United States)

    Deng, Hui; Chen, Genyu; He, Jie; Zhou, Cong; Du, Han; Wang, Yanyi

    2016-06-01

    In this study, an online, efficient and precision laser profiling approach that is based on a single-layer deep-cutting intermittent feeding method is described. The effects of the laser cutting depth and the track-overlap ratio of the laser cutting on the efficiency, precision and quality of laser profiling were investigated. Experiments on the online profiling of bronze-bonded diamond grinding wheels were performed using a pulsed fiber laser. The results demonstrate that an increase in the laser cutting depth caused an increase in the material removal efficiency during the laser profiling process. However, the maximum laser profiling efficiency was only achieved when the laser cutting depth was equivalent to the initial surface contour error of the grinding wheel. In addition, the selection of relatively high track-overlap ratios of laser cutting for the profiling of grinding wheels was beneficial with respect to the increase in the precision of laser profiling, whereas the efficiency and quality of the laser profiling were not affected by the change in the track-overlap ratio. After optimized process parameters were employed for online laser profiling, the circular run-out error and the parallelism error of the grinding wheel surface decreased from 83.1 μm and 324.6 μm to 11.3 μm and 3.5 μm, respectively. The surface contour precision of the grinding wheel significantly improved. The highest surface contour precision for grinding wheels of the same type that can be theoretically achieved after laser profiling is completely dependent on the peak power density of the laser. The higher the laser peak power density is, the higher the surface contour precision of the grinding wheel after profiling.

  16. Tungsten bronze-based nuclear waste form ceramics. Part 2: Conversion of granular microporous tungstate polyacrylonitrile (PAN) composite adsorbents to leach resistant ceramics

    Science.gov (United States)

    Griffith, Christopher S.; Sebesta, Ferdinand; Hanna, John V.; Yee, Patrick; Drabarek, Elizabeth; Smith, Mark E.; Luca, Vittorio

    2006-11-01

    Conversion of a granular molybdenum-doped, hexagonal tungsten bronze (MoW-HTB)-polyacrylonitrile (PAN) composite adsorbent to a leach resistant ceramic waste form capable of immobilizing adsorbed Cs + and Sr 2+ has been achieved by heating in air at temperatures in the range 600-1200 °C. Thermal treatment of the Cs- and Sr-loaded composite material at 1000 °C was sufficient to invoke a 60% reduction in volume of the composite while still retaining its spherical morphology. Cs-133 MAS NMR studies of this sample suite at 9.4 T and 14.1 T showed that multiple Cs sites are present throughout the entire thermal treatment range. Scanning electron microscopy investigations of the phase assemblages resulting from thermal treatment demonstrated that the full complement of Cs, and the majority of Sr, partitions into HTB phases (A 0.16-0.3MO 3; A = Cs +, Sr 2+ and Na +; M = Mo, W). The potentially reducing conditions resulting from the removal of the PAN matrix or the presence of high concentrations of Na + relative to either Cs + or Sr 2+ does not retard the formation of the high temperature HTB phases. The fraction of Cs + and Sr 2+ leached from the tungstate phase assemblages was superior or comparable with cesium hollandite (Cs 0.8Ba 0.4Ti 8O 18; f = ≈8 × 10 -5; rate = <1.2 × 10 -4 g/m 2/day) and strontium titanate (SrTiO 3; f = 3.1 × 10 -3; rate = 2.63 × 10 -4 g/m 2/day), respectively, using a modified PCT test in Millipore water at 90 °C. Furthermore, where aggressive leaching conditions were employed (0.1 M HNO 3; 150 °C; 4 days), the tungstate phase assemblages displayed leach resistance almost two orders of magnitude greater than the reference phases.

  17. Effect of coal tar pitch modified by sulfur as a binder on the mechanical and tribological properties of bronze-impregnated carbon-matrix composites

    Energy Technology Data Exchange (ETDEWEB)

    Yang Huijun [School of Physics and Nuclear Energy Engineering, Beijing University of Aeronautics and Astronautics, No. 37, Xue Yuan Road, Hai Dian District, Beijing 100191 (China); Luo Ruiying, E-mail: ryluo@buaa.edu.cn [School of Physics and Nuclear Energy Engineering, Beijing University of Aeronautics and Astronautics, No. 37, Xue Yuan Road, Hai Dian District, Beijing 100191 (China)

    2011-03-15

    Research highlights: {yields} Sulfur addition increased the softening point and carbon yield of coal tar pitch. {yields} The mechanical properties of the composites reached a maximum at 7 wt. % of sulfur. {yields} The friction coefficient rose monotonously with increasing the content of sulfur. {yields} The wear rate of the composites reached a minimum at 7 wt. % of sulfur. {yields} The wear mechanism of composites was adhesive wear, abrasive wear and oxidative wear. - Abstract: Bronze-impregnated carbon-matrix composites were prepared through compression molding, carbonization and impregnation. The mechanism of sulfuration was studied, and the effect of coal tar pitch modified by sulfur as a binder on the mechanical and tribological properties of composites was investigated by varying the content of sulfur. The results showed that the sulfur addition increased the softening point, carbon yield and C/H atomic ratio of coal tar pitch but decreased the toluene solubility and quinoline solubility due to the dehydrogenating polymerization of pitch molecules. The micro-hardness, bending strength and compressive strength of the composites were enhanced by increasing the mass percentage of sulfur and reached a maximum of 160 HV, 132.82 MPa and 293 MPa at 7 wt. % of sulfur, respectively. However, both the hardness and strength of the composites decreased as the content of sulfur increased beyond 7 wt. %. The friction coefficient value of composites increased monotonously, but the wear rate decreased with increasing sulfur content; subsequently, the wear rate reached a minimum of 3.045 x 10{sup -7} mm{sup 3}/Nm at 7 wt. % of sulfur and then ascended. The wear mechanisms of the composites were adhesive wear, abrasive wear and oxidative wear. However, adhesive wear and oxidative wear occurred slightly for the composites with the binder modified by sulfur.

  18. Effect of coal tar pitch modified by sulfur as a binder on the mechanical and tribological properties of bronze-impregnated carbon-matrix composites

    International Nuclear Information System (INIS)

    Research highlights: → Sulfur addition increased the softening point and carbon yield of coal tar pitch. → The mechanical properties of the composites reached a maximum at 7 wt. % of sulfur. → The friction coefficient rose monotonously with increasing the content of sulfur. → The wear rate of the composites reached a minimum at 7 wt. % of sulfur. → The wear mechanism of composites was adhesive wear, abrasive wear and oxidative wear. - Abstract: Bronze-impregnated carbon-matrix composites were prepared through compression molding, carbonization and impregnation. The mechanism of sulfuration was studied, and the effect of coal tar pitch modified by sulfur as a binder on the mechanical and tribological properties of composites was investigated by varying the content of sulfur. The results showed that the sulfur addition increased the softening point, carbon yield and C/H atomic ratio of coal tar pitch but decreased the toluene solubility and quinoline solubility due to the dehydrogenating polymerization of pitch molecules. The micro-hardness, bending strength and compressive strength of the composites were enhanced by increasing the mass percentage of sulfur and reached a maximum of 160 HV, 132.82 MPa and 293 MPa at 7 wt. % of sulfur, respectively. However, both the hardness and strength of the composites decreased as the content of sulfur increased beyond 7 wt. %. The friction coefficient value of composites increased monotonously, but the wear rate decreased with increasing sulfur content; subsequently, the wear rate reached a minimum of 3.045 x 10-7 mm3/Nm at 7 wt. % of sulfur and then ascended. The wear mechanisms of the composites were adhesive wear, abrasive wear and oxidative wear. However, adhesive wear and oxidative wear occurred slightly for the composites with the binder modified by sulfur.

  19. X-ray screening of the artificially deformed skulls from the Middle Bronze Age of the Low Volga region (paleopathology aspect

    Directory of Open Access Journals (Sweden)

    Pererva Evgenii Vladimirovich

    2013-11-01

    Full Text Available The impact of the deforming structure on the human skull is one of the most challenging and debated questions in modern archeology and anthropology related to artificial deformation of the skull. This is precisely why the present study attempts to study the pathological artificially deformed skulls of representatives of the Catacomb culture originating from burial mound in the Lower Volga region. The analysis of the bone material was carried out with the use of X-ray method of the frontal and lateral views. Thirteen radiographs of skulls with traces of deliberate artificial deformation were examined. The skull shapes, structure of the skull calvarial bones, state of the cranial sutures, signs of intracranial hypertension, and symptoms of vascular and endocrine pathologies were explored and evaluated. The study discovered that Catacomb culture bearers used a variety of methods of skull deformation. Front occipital, occipital ring strain and conventional acrocephaly deformation modes were revealed. The viability and compatibility with normal human activity of artificial skull deformation was observed. In the childhood and newborn periods, individuals have applied constrictive and restrictive devices, trusses andother appliancesfor a few years, their impact couldresultin the intracranial hypertension syndrome, as well as in problems with cranial sutures obliteration. It is very much likely that the use of strain could stimulate the development of the internal frontal hyperostosis (Morgagni's disease which contributed to the emergence of endocrine abnormities in humans. The increased trauma rate of skeleton bones was observed in population of the Middle Bronze Age, as well as ear diseases which makes us once again address the issue of social and cultural phenomenon of intentional artificial deformation of the head tradition.

  20. The largest art project of bronze sculpture in America:The horse and dragon%美国最大的青铜雕塑艺术工程《马与龙》

    Institute of Scientific and Technical Information of China (English)

    胡春良

    2015-01-01

    In this paper, we introduced the technical process of bronze sculpture the horse and dragon located in the Miami Gulf Stream international park, Florida, America. There are significant reference value for similar castings production.%介绍了在美国佛罗里达州迈阿密湾流国际公园落成的《马与龙》青铜雕塑的生产工艺过程,对生产同类铸件有参考意义。

  1. Trial Production of QSn4-4-2.5 Bronze Plates for Auto Parts%汽车青铜QSn4-4-2.5板材的试制

    Institute of Scientific and Technical Information of China (English)

    张文芹

    2001-01-01

    The technology for producing QSn4-4-2.5 bronze plates for auto parts is explored with reference to the influence of the production program on the properties of the plates.%本文依据国内某用户的要求,对QSn4-4-2.5板材生产从锭坯的熔铸工艺和加工工艺进行探索,并论述了该合金板材生产的工艺制度对其产品性能的影响。

  2. The botanical macroremains from the prehistoric settlement Kalnik-Igrišče (NW Croatia in the context of current knowledge about cultivation and plant consumption in Croatia and neighboring countries during the Bronze Age

    Directory of Open Access Journals (Sweden)

    Sara Mareković

    2015-07-01

    Full Text Available This paper presents the results of the first extensive archaeobotanical research into a Bronze Age site in Croatia. The aim of the study was to reveal what plants were consumed (grown at Kalnik-Igrišče (NW Croatia in the Bronze Age and to realize if the plant diet of the local population differed from that of the inhabitants in neighboring countries. The results show that all plant macrofossils found at Kalnik-Igrišče can be classified into one of four functional groups: cereals, cultivated legumes, useful trees and weeds. As much as 98% of the findings are of cereals and legumes. The most abundant species found are Panicum miliaceum (millet, Hordeum vulgare (barley, Vicia faba (faba bean, Triticum aestivum ssp. aestivum (bread wheat, Triticum turgidum ssp. dicoccon (emmer wheat and Lens culinaris (lentils. The findings from Kalnik-Igrišče do not differ from the findings of neighboring countries, indicating that there were similar diets and agricultural/plant-collecting activities throughout the whole of the studied area (Bosnia and Herzegovina, Slovenia, Serbia, Italy, Austria and Hungary.

  3. [The Dynamics of the Composition of mtDNA Haplotypes of the Ancient Population of the Altai Mountains from the Early Bronze Age (3rd Millennium BC) to the Iron Age (2nd-1st Centuries BC)].

    Science.gov (United States)

    Gubina, M A; Kulikov, I V; Babenko, V N; Chikisheva, T A; Romaschenko, A G; Voevoda, M I; Molodin, V I

    2016-01-01

    The mtDNA polymorphism in representatives of various archaeological cultures of the Developed Bronze Age, Early Scythian, and Hunnish-Sarmatian periods was analyzed (N = 34). It detected the dominance of Western-Eurasian haplotypes (70.6%) in mtDNA samples from the representatives of the ancient population of the Early Bronze Age--Iron Age on the territory of Altai Mountains. Since the 8th to the 7th centuries BC, a sharp increase was revealed in the Eastern-Eurasian haplogroups A, D, C, andZ (43.75%) as compared to previous cultures (16.7%). The presence of haplotype 223-242-290-319 of haplogroup A8 in Dolgans, Itelmens, Evens, Koryaks, and Yakuts indicates the possible long-term presence of its carriers in areas inhabited by these populations. The prevalence of Western-Eurasian haplotypes is observed not only in the Altai Mountains but also in Central Asia (Kazakhstan) and the South of the Krasnoyarsk Krai. All of the three studied samples from the Western-Eurasian haplogroups were revealed to contain U, H, T, and HV. The ubiquitous presence of haplotypes of haplogroup H and some haplogroups of cluster U (U5al, U4, U2e, and K) in the vast territory from the Yenisei River basin to the Atlantic Ocean may indicate the direction of human settlement, which most likely occurred in the Paleolithic Period from Central Asia. PMID:27183799

  4. Thermal hysteresis, threshold, and dynamics of charge-density waves at low temperatures in blue bronzes (K1-xAx)0.3MoO3 (A=Tl or Na)

    International Nuclear Information System (INIS)

    The temperature dependence of Ohmic resistance, threshold, and nonlinear voltage-current (V-I) characteristics were systematically studied in pure potassium/thallium blue bronzes and Tl/Na-doped alloy bronzes. It is found that the thermal hysteresis of low-field resistance at a lower-temperature regime behaves quite differently as compared to that at higher temperatures; doping with metallic Tl+/Na+ ions has remarkable influences on the threshold electric-field properties of charge-density-wave (CDW) depinning, but has little effect on the low-temperature dynamics of CDW conduction below 30 K: the V-I characteristics in all samples still display a sharp breakdown transition. The results indicate that the low-temperature dynamical behavior of CDW depinning may not originate from the external impurities acting as weak pinning centers; rather, an internal mechanism concerning the changes of CDW structures in the presence of an applied electric field must be considered. The two different types of hysteresis behavior are strongly related to the correlation between the normal carriers and CDW configurations. copyright 1996 The American Physical Society

  5. Crystallography properties of solid solution of NaSr{sub 2}(NiNb{sub 4})O{sub 15-{delta}s}tructure of tetragonal tungsten bronze; Propriedades cristalograficas da solucao de NaSr{sub 2}(NiNb{sub 4})O{sub 15-{delta}} de estrutura tetragonal tungstenio bronze

    Energy Technology Data Exchange (ETDEWEB)

    Polini, C.; Dantas, S.A.; Mikaro, C.; Lima, A.R.F.; Nobre, M.A.L.; Lanfredi, S. [Universidade Estadual Paulista (LaCCeF/UNESP), Presidente Prudente, SP (Brazil). Dept. de Fisica, Quimica e Biologia. Lab. de Compositos e Ceramicas Funcionais

    2009-07-01

    In this work was investigated the crystallographic characterization of single phase and nanometric powders of sodium strontium niobate doped with nickel, with NaSr{sub 2}(NiNb{sub 4})O{sub 15-{delta}} stoichiometry, prepared by conventional route from mechanical mixture of oxides / carbonates using the high energy ball milling. The optimization of the parameters as time and calcination temperature for the preparation of the NaSr{sub 2}(NiNb{sub 4})O{sub 15-{delta}} solid solution were monitored by X-ray diffraction, using the Rietveld method. The NaSr{sub 2}(NiNb{sub 4})O{sub 15-{delta}} single phase powders with tetragonal tungsten bronze type structure were obtained with crystallite size at around 30 nm. From crystallographic parameters was constructed the unitary cellule of the NaSr{sub 2}(NiNb{sub 4})O{sub 15-{delta}} using the CaRIne Crystallography 3.1 program. The occupation of sites by the Na{sup +} and Sr{sup 2+} cations and the interatomic distances between nickel and niobium atoms were determined. Changes in structural parameters of sodium strontium niobate by addition of nickel are discussed. (author)

  6. Large-scale River Channel Shifts on the Western Indo-Gangetic Plains and their implications for the Bronze-age Harappan Civilisation Settlement Patterns

    Science.gov (United States)

    Gupta, S.; Singh, A.; Sinha, R.; Thomsen, K.; Murray, A. S.; Carter, A.; Mark, D. F.; Buylaert, J.; Mason, P.; Ferrat, M.

    2011-12-01

    The distribution of settlements in ancient societies is commonly linked to the courses of large river systems. The Bronze Age Harappan civilisation (4800-3500BP) is no exception with the major sites of Harappa and Mohenjo-Daro located along the Indus river system. However, the largest collection of Harappan archaeological sites are associated with the postulated surface trace of a large paleo-river channel in the drainage divide tract between the Ganges and Indus river systems, where no major river currently flows. It has been proposed that this paleo-channel was occupied by a major river sourced in the Himalaya, and that this river provided water resources to sustain the extensive Harappan sites located along its ancient course. The abrupt abandonment of urban centres here at ~3500 BP has been explained as a consequence of river diversion, although alternative explanations for cultural decline have also been entertained. These hypotheses have remained untested because the stratigraphy and chronology of the postulated paleochannel has never been determined. Here we investigate the evolution of these paleodrainage systems using a combination of satellite image analysis, subsurface geophysical analysis and sediment coring to analyse the large-scale planform geometry, and detailed sedimentary and stratigraphic nature of the postulated paleochannel in NW India. We focus our analysis on tracts of the proposed channel that lie adjacent to major Harappan urban centres in NW India, such as the site of Kalibngan in Rajastan. We find that the postulated surface trace of the paleochannel on satellite imagery is is confirmed by subsurface geophysical investigation and detailed coring. The sedimentology and stratigraphy of multiple cores taken at several transects along the trace of the paleochannel shows the evolution of the fluvial system. We determine the provenance of the fluvial channels using U-Pb dating of detrital zircons and Ar-Ar dating of detrital muscovites. These

  7. Tungsten bronze-based nuclear waste form ceramics. Part 2: Conversion of granular microporous tungstate-polyacrylonitrile (PAN) composite adsorbents to leach resistant ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Griffith, Christopher S. [Australian Nuclear Science and Technology Organisation, Institute of Materials and Engineering Sciences, PMB 1, Menai, NSW 2234 (Australia); Sebesta, Ferdinand [Czech Technical University in Prague, Department of Nuclear Chemistry, Brehova 7, 115 19 Prague 1 (Czech Republic); Hanna, John V. [Australian Nuclear Science and Technology Organisation, Institute of Materials and Engineering Sciences, PMB 1, Menai, NSW 2234 (Australia); Yee, Patrick [Australian Nuclear Science and Technology Organisation, Institute of Materials and Engineering Sciences, PMB 1, Menai, NSW 2234 (Australia); Drabarek, Elizabeth [Australian Nuclear Science and Technology Organisation, Institute of Materials and Engineering Sciences, PMB 1, Menai, NSW 2234 (Australia); Smith, Mark E. [Department of Physics, University of Warwick, Gibbett Hill Road, Coventry CV47AL (United Kingdom); Luca, Vittorio [Australian Nuclear Science and Technology Organisation, Institute of Materials and Engineering Sciences, PMB 1, Menai, NSW 2234 (Australia)]. E-mail: vlu@ansto.gov.au

    2006-11-30

    Conversion of a granular molybdenum-doped, hexagonal tungsten bronze (MoW-HTB)-polyacrylonitrile (PAN) composite adsorbent to a leach resistant ceramic waste form capable of immobilizing adsorbed Cs{sup +} and Sr{sup 2+} has been achieved by heating in air at temperatures in the range 600-1200 deg. C. Thermal treatment of the Cs- and Sr-loaded composite material at 1000 deg. C was sufficient to invoke a 60% reduction in volume of the composite while still retaining its spherical morphology. Cs-133 MAS NMR studies of this sample suite at 9.4 T and 14.1 T showed that multiple Cs sites are present throughout the entire thermal treatment range. Scanning electron microscopy investigations of the phase assemblages resulting from thermal treatment demonstrated that the full complement of Cs, and the majority of Sr, partitions into HTB phases (A{sub 0.16-0.3}MO{sub 3}; A = Cs{sup +}, Sr{sup 2+} and Na{sup +}; M = Mo, W). The potentially reducing conditions resulting from the removal of the PAN matrix or the presence of high concentrations of Na{sup +} relative to either Cs{sup +} or Sr{sup 2+} does not retard the formation of the high temperature HTB phases. The fraction of Cs{sup +} and Sr{sup 2+} leached from the tungstate phase assemblages was superior or comparable with cesium hollandite (Cs{sub 0.8}Ba{sub 0.4}Ti{sub 8}O{sub 18}; f = {approx}8 x 10{sup -5}; rate = <1.2 x 10{sup -4} g/m{sup 2}/day) and strontium titanate (SrTiO{sub 3}; f = 3.1 x 10{sup -3}; rate = 2.63 x 10{sup -4} g/m{sup 2}/day), respectively, using a modified PCT test in Millipore water at 90 deg. C. Furthermore, where aggressive leaching conditions were employed (0.1 M HNO{sub 3}; 150 deg. C; 4 days), the tungstate phase assemblages displayed leach resistance almost two orders of magnitude greater than the reference phases.

  8. Process and Performances of Electroless Ni-P Alloy Coating on Tin Bronze%锡青铜化学镀Ni-P合金工艺及镀层性能

    Institute of Scientific and Technical Information of China (English)

    王敏; 刘锦云; 李文鹏; 陈立甲

    2015-01-01

    ABSTRACT:Objective To improve the wear resistance and corrosion resistance of the tin bronze by Ni-P alloy coating. Methods The tin bronze samples were activated by the acid activation solution with zinc and the plating was performed under the same condi-tion. The properties of these state plated samples underwent heat treatment in the different temperatures (250, 400, 500 ℃) were compared, including the matrix, the plating coating and the coating after heat treatment. The impact was investigated of the diffe-rent heat treatment temperatures on microstructure, microhardness, wear resistance and corrosion resistance of electroless Ni-P al-loy coating on the tin bronze. Results The Ni-P alloy coating was formed on the surface of the tin bronze surface, the state plating coa-ting has no void defect with the base;instead, a good combination was observed;moreover, the deposition is faster, namely, 10. 00 μm/h. The microstructure of the coating transforms from amorphous to crystalline after heat treatment was studied, and the microhardness and wearability of the coating was best after 500 ℃ heat treatment, the corrosion resistance of the state plating coa-ting and the coating after 250 ℃ heat treatment was obviously better than the tin bronze substrate in 10% HNO3 solution and 10%H2SO4 solution, and the corrosion rate of the state plating coating was respectively 0. 225 mg/(cm2·d) and 0. 146 mg/(cm2·d) in the two kinds of medium solutions. Conclusion By the acid activation solution with zinc, electroless Ni-P alloy coating can be successfully prepared on the tin bronze surface with a nice plating effect. Our results show that the technology of electroless Ni-P al-loy on copper can be also applied to the tin bronze.%目的:在锡青铜基体上化学镀Ni-P合金镀层,提高锡青铜的耐磨性和耐腐蚀性。方法以酸性含锌活化液活化锡青铜试样,在相同的条件下实施化学镀,并对镀态试样进行不同温度(250,400,500℃)下的

  9. Structure and dielectric properties of Ba{sub 5}NdCu{sub 1.5}Nb{sub 8.5}O{sub 30−δ} tungsten bronze ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Tan, Yan-Qing; Yu, Yuan [College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, 19(A) Yu Quan Road, Beijing 100049 (China); Hao, Yong-Mei, E-mail: ymhao@ucas.ac.cn [College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, 19(A) Yu Quan Road, Beijing 100049 (China); Dong, Su-Ying; Yang, Yi-Wen [Beijing National Day School, 66 Yu Quan Road, Beijing 100039 (China)

    2013-05-15

    Highlights: ► Tetragonal tungsten bronze ceramic Ba{sub 5}NdCu{sub 1.5}Nb{sub 8.5}O{sub 30−δ} was prepared. ► Titanium was replaced by copper in M{sub 5}RTi{sub 3}Nb{sub 7}O{sub 30} for the first time. ► Detailed structural information was retrieved by Rietveld refinement. ► An obvious relaxor-like dielectric behavior was observed in this ceramic, ion disorders in A1 and B sites contribute to this behavior. - Abstract: A new type of tungsten bronze ceramic Ba{sub 5}NdCu{sub 1.5}Nb{sub 8.5}O{sub 30−δ} has been prepared by a conventional solid-state reaction technique. Its structural, dielectric properties were investigated. Rietveld analysis shows that Ba{sub 5}NdCu{sub 1.5}Nb{sub 8.5}O{sub 30−δ} has a single-phase tetragonal (space group P4bm and lattice constants a = b = 12.4961(4) Å, c = 3.9426(8) Å, V = 615.66(4) Å{sup 3}) tungsten bronze structure. The occupations of sites A and B are quite interesting. A1 sites are fully disordered occupied by Ba ions and Nd ions and A2 sites for Ba ions only, while B-sites are equal for both Cu and Nb ions to occupy. This material exhibits an obvious relaxation behavior in the 213–573 K temperature range. The dielectric constants have been fitted by the modified Curie–Weiss law and all the estimated γ values are close to 2, confirming the typical relaxor ferroelectric behavior. The disorders of Ba{sup 2+} or Nd{sup 3+} in A1 sites and Nb{sup 5+}, Cu{sup 2+} in B sites induced by the oxygen vacancies may contribute to this dielectric behavior.

  10. Climate change versus land management in the Po Plain (Northern Italy) during the Bronze Age: New insights from the VP/VG sequence of the Terramara Santa Rosa di Poviglio

    Science.gov (United States)

    Cremaschi, Mauro; Mercuri, Anna Maria; Torri, Paola; Florenzano, Assunta; Pizzi, Chiara; Marchesini, Marco; Zerboni, Andrea

    2016-03-01

    The sedimentary infilling of the moat surrounding the Villaggio Piccolo of the Terramara Santa Rosa di Poviglio was analysed in order to obtain palaeoenvironmental inferences from sediments and pollen assemblage. The high-resolution stratigraphic sequence preserves evidence of the environmental changes that occurred in the Po Plain, in Northern Italy, during the Late Holocene. Our interdisciplinary approach permitted to study climatic and anthropic contributions to the environmental changes in this region. The relationships between these changes and land-use changes were investigated focussing on adaptive strategies of the Terramare people during the Middle and Recent Bronze ages (1550-1170 yr BC). The Terramare are archaeological remains of banked and moated villages, located in the central alluvial plain of the Po river. The Terramara of Santa Rosa consists of two adjoining settlements (Villaggio Grande and Villaggio Piccolo); the moat that separates the two parts of the site is c. 23 m large and reaches a maximum depth of 4 m from the extant ground level. The stratigraphic sequence VP/VG exposed by archaeological excavation inside the moat was sampled for pedosedimentary, thin section, and pollen analyses. Chronology is based on archaeological evidence, stratigraphic correlations and radiocarbon dating. Pedosedimentary features and biological records (pollen of aquatics and algal remains) demonstrate that shallow water, probably subjected to seasonal water-level oscillations, has always been present in the moat. In the lower units of the sequence, the laminations indicate standing water, while occurrence of reworked pollen testified the supply of sediments to the plain from catchment zones located in the Apennine. Open vegetation was widespread; economy was based on wood management, fruit collection on the wild or from cultivated woody plants, crop fields with a fairly diversified set of cereals especially increasing in variety during dryness or phases of water

  11. Deng lives on in bronze

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正> This year is the 100th anniversary of Deng Xiaoping’s birthday. Yuan Xikun, a famous portrait master, spent 180 days painstakingly creating the statue of DengXiaoping, the great man of the century. And in this way, he expresses the Chinese people’s and his own respect and gratitude for Deng’s achievements of having brought the Chinese people a spring of reform and opening

  12. Robert Bagley, Max Loehr and the Study of Chinese Bronzes, Ithaca, NY: Cornell East Asia Series, 2008, translated by Wang Haicheng, originally published in Chinese in Dushu, November 2010, 126-33.

    Directory of Open Access Journals (Sweden)

    Miao Zhe

    2011-12-01

    Full Text Available This essay reviews Robert Bagley’s intellectual portrait of Max Loehr, one of the founding fathers of the western study of Chinese art. Bagley’s book centers on the prolonged controversy between Loehr and Bernhard Karlgren over the history of ancient Chinese bronzes. Karlgren, an eminent philologist, tried to extract chronological information from a classification of décor motifs, an approach that he and many of his readers considered to be scientific and objective. Failing to detect any pattern of change in his material, he declared that all extant bronzes were made during two or three centuries of artistic stagnation, centuries that merely repeated designs invented in some earlier and more creative period that is unknown to us. Loehr by contrast succeeded in tracing a clear sequence of evolving styles in the same corpus of material. These positions were first staked out in the 1930s; most observers sided with Karlgren until the 1960s, when archaeology confirmed Loehr’s sequence. What makes the controversy interesting and instructive is that the right answer did not come from the approach that to this day strikes most readers as the scientific one, it came from a seemingly subjective and intuitive art-historical analysis. In part Bagley explains this unexpected outcome by showing that science as Karlgren conceived it—a rule-bound and mechanical procedure that excludes intuition and judgment—is a layman’s misconception; in essential ways, he shows, it was Loehr’s approach rather than Karlgren’s that was scientific. At a time when the prestige of the hard sciences continues to inspire attempts to import scientific methods into the humanities, Bagley has illuminating things to say about the real substance of those methods. He also has much to say about artistic invention and intentionality, and he clarifies one of art history’s most constantly used yet most ill-defined concepts, the concept of style, by arguing that it is not an

  13. Resistencia al desgaste de recubrimientos de bronce al aluminio producidos con técnica de proyección térmica//Wear resistance of aluminum bronze coatings produced by thermal spray

    Directory of Open Access Journals (Sweden)

    Dayan Carolina Cárdenas-Feria

    2015-09-01

    Full Text Available Se estudió la resistencia al desgaste adhesivo de recubrimientos de bronce al aluminio depositados con la técnica de proyección térmica por llama sobre bronce fosforado SAE 62. Los recubrimientos fueron fabricados variando las presiones parciales de los gases de combustión, oxígeno y acetileno. El material utilizado fue caracterizado estructuralmente mediante difracción de rayosX (X-ray diffraction, XRD y el estudio morfológico mediante microscopía electrónica de barrido (Scanning electron microscopy, SEM. La resistencia al desgaste adhesivo de los recubrimientos se determinó por medio del ensayo de bola sobre disco, utilizando como bola una esférica de acero 100Cr6. Los resultados obtenidos permiten establecer que los recubrimientos proyectados con una presión de oxigeno de 78 psi y una presión de acetileno de 8 psi presentan la mejor resistencia al desgaste en comparación a los tratamientos producidos. El modo de falla de desgaste en los recubrimientos producidos es discutido en esta investigación.Palabras clave: desgaste abrasivo y adhesivo,  proyección térmica,  recubrimientos.______________________________________________________________________________AbstractWe studied the adhesive wear resistance of aluminum bronze coatings deposited by thermal spray on phosphor bronze SAE 62 substrates. The coatings were deposited by varying the partial pressures of the combustion gases: oxygen and acetylene. The structural characterization was made through X-ray diffraction (XRD and the morphological analysis was performed by scanning electron microscopy (SEM. The adhesive wear resistance of the coatings was determined by the bole on disc test using a spherical ball made of steel 100Cr6 and with a diameter of 6 mm. The results obtained show that the coating projected with an oxygen pressure of 78 psi and an acetylene pressure of 8 psi have the better wear resistance compared with the substrate and the others treatments deposited

  14. Un nouvel habitat du Bronze final IIIb dans le Val d’Orléans et ses traces de métallurgie du fer : Bonnée, Les Terres à l’Est du Bourg (Centre, Loiret A new settlement from late Bronze IIIb in the val d’Orléans: Bonnée, Les Terres à l’Est du Bourg (lands to the east of the town (Centre, Loiret

    Directory of Open Access Journals (Sweden)

    Stéphane Joly

    2011-12-01

    Full Text Available La multiplication récente des diagnostics archéologiques autour du petit bourg actuel de Bonnée a permis la détection d’une occupation du Bronze final IIIb (circa 900-750 av. n.-e. sur environ un hectare aux Terres à l’Est du Bourg. Les limites inhérentes à ce type d’intervention réduisent l’interprétation des structures et toute approche spatiale de ce probable habitat repéré. L’étude conjointe des différents mobiliers en particulier céramique et métallurgique, mais aussi le torchis et la faune, atteste de sa culture matérielle et de son intérêt. Ces scories pourraient être parmi les plus anciennes traces en région Centre d’activité métallurgique du fer. Des activités de post-réduction sont avérées et certaines opérations de forgeage sont supposées.La découverte de cet habitat dans ce secteur du lit majeur de la Loire, apporte de nouvelles données concernant l’occupation du sol et ses problématiques évolutives dans le Val d’Orléans sur ces périodes de transition avec le Hallstatt ancien.The recent increase in the archaeological evaluations around the village of Bonnée has enabled the discovery of a final Bronze Age IIIb settlement (circa 900-750 BP on about a hectare of the Terres à l’Est du Bourg. The limits inherent in this type of work restrict the interpretation of structures and all spatial approaches to this likely dwelling. The joint study of the different furnishings, in particular ceramics and metal, but also the cob and fauna, attests to its material culture and its interest. The slag could be amongst the oldest iron metallurgy remains from the Centre region. Some activities of post-forging are proven and certain operations are guessed at. The discovery of this settlement in this sector of the major bed of the Loire, has produced new data concerning the occupation of the land and its evolutionary problems in the valley of Orleans over these periods of transition in the early

  15. Dicrocoelium dendriticum found in a Bronze Age cemetery in western Iran in the pre-Persepolis period: The oldest Asian palaeofinding in the present human infection hottest spot region.

    Science.gov (United States)

    Mowlavi, Gholamreza; Mokhtarian, Kobra; Makki, Mahsa Sadat; Mobedi, Iraj; Masoumian, Mohammad; Naseri, Reza; Hoseini, Ghasem; Nekouei, Parisa; Mas-Coma, Santiago

    2015-10-01

    Dicrocoeliasis of animals and humans is caused by trematode species of the genus Dicrocoelium, mainly Dicrocoelium dendriticum in ruminants of the Holarctic region. D. dendriticum may be considered an old parasite, probably related to the appearance and diversification of Eurasian ovicaprines, occurred 14.7-14.5 million years ago. The oldest palaeoparasitological findings of Dicrocoelium in domestic animals and humans date from more than 5000 years BC in Europe. Eggs of D. dendriticum have been found in a burial of a Bronze Age cemetery (2600-2200 BC) close to Yasuj city, southwestern Iran. This is the oldest finding of D. dendriticum in the Near East, where present human infection reports are more numerous than in other world regions where human dicrocoeliasis is rare and sporadic. This palaeofinding in the Zagros mountainous chain area is of interest by its location close to Persepolis, suggesting a narrow relationship between humans and herbivorous animals in these highlands. Domestic ruminant populations of these highlands were following a repeated contact with those of the western flat lowlands of the Fertile Crescent thanks to annual altitudinal transhumance migrations of the nomadic pastoral tribes with their herds living throughout Zagros Mountains in the several millennium period BC. It is concluded that D. dendriticum spread together with sheep and goats westward throughout Europe from the Fertile Crescent during the 8000-6000 year BC period and somewhat later southward into Africa, both spreads facilitated by the low specificity of that trematode species regarding the snail and ant intermediate hosts. PMID:25748277

  16. Adsorption of Lanthanides by A{sub y}Mo{sub x}W{sub 1-x}O{sub 3} Hexagonal Tungsten Bronzes and Prospects for their Potential Use as Recyclable Inert Matrix Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Luca, Vittorio; Yang, Bin; Yaman, Ilkay; Griffith, Christopher S.; Scales, Nicholas; Sizgek, Erden [Australian Nuclear Science and Technology Organisation (ANSTO), Institute of Materials Engineering, New Illawarra Road, Lucas Heights, New South Wales, 2234 (Australia)

    2008-07-01

    The hexagonal tungsten bronze (HTB) based adsorbents of general formula A{sub y}M{sub x}W{sub 1-x}O{sub 3}.ZH{sub 2}O have been a particular focus of attention in our laboratory for some time. In the context of a potential partition and transmutation strategy our interest in these HTB materials has been stimulated by their particularly high affinity for lanthanide (LN) and minor actinide (MA). In addition to partitioning operations the materials can also be contemplated for mop-up and decontamination applications. With Cs{sup +} as the target species, HTBs can be converted to very effective waste form materials with performances comparable to the best Cs-containing ceramics such as hollandite. However, their excellent affinity for LNs and MAs suggest their use for MA recycling. When granular variants of the HTB adsorbents are loaded with LNs and are heated in air to relatively modest temperatures these elements preferentially partition into relatively soluble phases imbedded within a durable WO{sub 3} matrix. Since the LN-containing phase is relatively soluble, efficient recovery of the LNs or potentially MAs is feasible. This, together with potentially favorable irradiation properties, suggests they may have uses as recyclable inert matrix fuels. In this communication, we discuss LN and MA adsorption and thermal properties of HTB materials with variable x, as well as resistance to {gamma}-radiation and heavy ion bombardment. Finally, recoverability of the LNs is considered. (authors)

  17. Discussion of ‘Style’ from Max Loehr and the Study of Chinese Bronzes, Style and Classification in the History of Art, Ithaca, Cornell University Press: Cornell East Asia Series 2008

    Directory of Open Access Journals (Sweden)

    Robert Bagley

    2010-06-01

    Full Text Available This essay is the concluding chapter of a study of the work of Max Loehr (1903-1988, an art historian whose visual analysis of unprovenanced Chinese bronzes famously anticipated the discoveries of archaeologists. It argues that Loehr’s strictly pragmatic understanding of style is implicit in the daily practice of most art historians, but that most of our explicit uses of the word, including such everyday expressions as ‘Romanesque style’ and ‘style of Raphael’, presume the existence of a mysterious, indefinable entity that is both a property of the object and a disembodied agent evolving independently of artists and objects. Not surprisingly, no procedure for ascertaining the style of an object has ever been described. The failure to recognize that style is not a physical property but only a shorthand for talking about comparisons is responsible for many classic confusions in art history. Finding the causes of a style or explaining its evolution (‘the origin of the Gothic style’, ‘the evolution from Renaissance to Baroque’, relating styles to times or cultures or nations, relating them across media (‘Baroque painting’ and ‘Baroque music’—these are fictitious problems, artefacts of a mistaken belief in a thing called ‘style’.

  18. Date identification of the Zhouji materials during the period of King Xin--The chronology Solving method of oracle boneS and bronzes in the Shang and Zhou dynasties

    Institute of Scientific and Technical Information of China (English)

    李勇

    2002-01-01

    By identifying the dates of the Zhouji materials (one kind of oracle bone) during the period of King Xin (also called Zhou the last monarch in Shang Dynasty), this paper establishes a new "Direct Solving Method" (DSM) to solve the chronology problems in the Shang and Zhou dynasties. The mathematical models are more suitable for those materials with the Ganzhi (the Heavenly Stems and Earthly Branches, the Chinese ancient date recorded method being of the 60-day cycle, that the repetitive cycle is independent of any astronomical parameter, each day within this cycle has its own name and can also be expressed by the numbers from l to 60) record of the date, lunar month, and their year intervals and all of them are in history documents, oracle bones and bronze vessels. For example, taking the 12 Zhouji materials in the period of King Xin,we derive the two best results of the first year when Xin assumed the reins of government in probably 1063 BC or 1052 BC.

  19. 中国古青铜器表面富锡铜鎏镀及鎏焊的工艺探索第三部分——鎏焊%Technological study on amalgam coating and brazing of tin-rich copper on surface of bronze wares of ancient China——Part Ⅲ.Amalgam brazing

    Institute of Scientific and Technical Information of China (English)

    吴元康; 储荣邦

    2012-01-01

    Amalgam brazing is derived from amalgam coating. The definition, characteristics, application, and significance of amalgam brazing were expatiated. A process of amalgam brazing for producing combined bronze wares was developed. The compositions of brazing material and flux were given. The operations of pretreatment, mercury removal by heating, and post-treatment were described. The implementation of amalgam coating and brazing processes was introduced taking the Western Han Dynasty's bronze cowry container with tribute-paying figures excavated in Yunnan as an example. The method for distinguishing whether an antique bronze ware is produced by cast welding after lost-wax casting or by copper brazing with separated small cast parts was presented.%鎏焊是从鎏镀衍生而来的.阐述了鎏焊的定义、特点、应用和意义.设计了用于制作组合青铜器的鎏焊工艺,给出了焊料、焊剂配方,说明了前处理、加热驱汞及后处理的操作方法.以西汉云南纳贡场面青铜贮贝器为例,介绍了鎏镀与鎏焊工艺的具体实施过程.提出了鉴别古青铜器是由失蜡铸造后铸焊而成还是由分铸小件铜焊而成的方法.

  20. Tungsten bronze-based nuclear waste form ceramics. Part 3: The system Cs 0.3M xW 1- xO 3 for the immobilization of radio cesium

    Science.gov (United States)

    Luca, Vittorio; Drabarek, Elizabeth; Chronis, Harriet; McLeod, Terry

    2006-11-01

    Previous studies in this series have indicated that Cs- and Sr-loaded Mo-doped hexagonal tungsten bronze (MoW-HTB) oxides, either in the form of fine grained powders, or as composite granules, can be converted to leach resistant ceramics at modest temperatures in the range 600-1200 °C. In the present study it has been shown that such waste form ceramics can also be readily prepared through very simple conventional routes involving the blending of cesium nitrate with tungstic acid and other oxide components followed by heating in air. The phase chemistry resulting from the blending of these oxides has been explored. In the Cs 0.3M xW 1- xO 3 compositional system where x = Ti, Zr, Nb and Ta the solid solution limit has been found to be where x = 0.2. For all values of x between 0 and 0.2 mixed phase materials of HTB and WO 3 were obtained and Cs was found associated with HTB phases that are both rich and depleted in M element. At temperatures above about 1000 °C, phase pure HTB compounds in the space group P63/ mcm were obtained. Even when x greatly exceeds 0.2, the additional oxide content did not interfere with the formation of the HTB phase. Durability of the Cs 0.3M xW 1- xO 3 compositions as gauged by the fractional Cs loss in de-mineralized water was lowest when M = Ti and Nb, and greatest when M = Zr. From these results the durability appears intimately linked with the unit cell a-dimension which in turn varies with M cation radius.

  1. Study on the Tribological Behavior of Bronze-matrix Self-lubricating Composites%锡青铜基自润滑材料的摩擦学特性研究

    Institute of Scientific and Technical Information of China (English)

    王静波; 吕晋军; 宁莉萍; 孟军虎

    2001-01-01

    Bronze matrix self-lubricating composites were prepared bysintering in hydrogen furnace. The mechanical and tribological properties of the composites were investigated on a pin-on-disk test rig. The self-lubricating mechanism of the composites was analyzed with emphasis on the effect of the solid lubricants. The results show that the composites exhibit good mechanical and tribological properties at room temperature to 450 ℃. XRD analysis of the worn surface of the counterpart AISI1045 steel disk shows that transfer solid lubricant film composed of graphite, Pb, and SnO2 forms and contributes to improve the tribological behavior of the composites at room temperature. The improved tribological behavior of the composites at 450 ℃ is attributed to the transfer film composed of graphite, Pb2O3, and CuO.%采用粉末冶金自由烧结工艺制备出锡青铜基自润滑复合材料,对该类复合材料的力学性能与摩擦磨损特性进行了研究,从固体润滑剂角度就其室温与450℃自润滑机理进行了分析与探讨.研究结果表明,该类材料在室温至450℃温度范围内具有良好的机械性能与摩擦磨损特性.XRD分析结果显示:在室温下磨损表面形成的含石墨、Pb和SnO2的复合膜是其具有润滑性能的主要原因;在高温下则由石墨、Pb2O3和CuO组成的复合膜起主要润滑作用.

  2. Study on the Corrosion of Shang and Zhou Dynasty Bronze Relics---A Case Study of Artificial Analogue of HLW Disposal System Canister%商周青铜文物的腐蚀研究--高放废物处置系统人为类似物研究实例

    Institute of Scientific and Technical Information of China (English)

    陈璋如; 刘月妙; 范光; 温志坚; 孙淑云; 李延祥; 张展适

    2015-01-01

    This paper presents compositional analyses and structure observations of unearthed Shang Zhou dynasty bronze relict samples and environmental conditions of the sites where the samples were collected.Research results revealed that the bronze relics had been continuously corroded with time.The corrosion layer consisted of at least two sub layers ,such as oxide and carbonate.There was a mechani‐cal corrosion sub layer found in few samples (a loose sub layer) . A SnO2 sub layer also occurred in a few samples. The thickness of bronze corrosion layers varied with the different climate environments in which the samples were taken. Their thickness was 50~260μm and 320~800μm and humid climate re‐gions respectively. In the view of natural corrosion resistance , bronze is recommendable as a material for HLW repository system canisters.%文章论述了出土商周时代青铜文物的化学成分和结构特征以及样品采集地区的环境条件。研究表明青铜文物随时间而不断腐蚀。腐蚀层至少由两个亚层组成,即氧化物层和碳酸盐亚层。有些样品出现物理腐蚀亚层,即疏松层;有些样品则产出SnO2亚层。青铜腐蚀层的厚度在不同环境条件下发生变化,干旱条件下为50~260μm ,潮湿条件下为320~800μm。从天然抗腐蚀观点看,青铜可推荐作为高放废物处置系统废物罐的材料。

  3. L’apport des analyses 14C à l’étude de la nécropole de l’âge du Bronze de“ La Croix de la Mission ” à Marolles-sur-Seine The contribution of radiocarbon dating in the study of the Bronze Age cemetery of Marolles-sur-Seine “ La Croix de la Mission ”

    Directory of Open Access Journals (Sweden)

    Rebecca Peake

    2006-12-01

    Full Text Available Quatorze des 41 sépultures de la nécropole de “ la Croix de la Mission ” à Marolles-sur-Seine ont récemment fait l’objet d’une datation par le radiocarbone aux laboratoires de Groningen (Pays-Bas et de Lyon (France. Les résultats obtenus mettent en évidence l'utilisation en continu de la nécropole pendant plus d’un millénaire entre 2000 et 800 av. n. è. La corrélation entre ces nouvelles dates et les données archéologiques permet de cerner, avec plus de précision, l’éventail des différentes étapes chrono-culturelles représentées à travers les sépultures de la nécropole. [Les analyses 14C ont été effectuées par les laboratoires de Groningen (Centrum voor Isotopen Onderzoek Rijksuniversiteit Groningen Nijenborgh 4 NL-9747 AG Groningen et Lyon (Centre de Datation par le Radiocarbone Université Claude Bernard Lyon 1, 43, bd du 11 Novembre 1918 F-69622 Villeurbanne Cedex.]Fourteen of the 41 burials of the “ la Croix de la Mission ” Bronze Age cemetery at Marolles-sur-Seine have recently been carbon dated by the Lyon (France and Groningen (Netherlands laboratories. These new dates confirm the site’s occupation for more than 1000 years from 2000 BC to 800 BC and determine more precisely the different cultural and chronological phases of the cemetery illustrated by the great range of its burials.

  4. 中国古青铜器表面富锡铜鎏镀及鎏焊的工艺探索第二部分——鎏镀的原理及工艺设计%Technological study on amalgam coating and brazing of tin-rich copper on surface of bronze wares of ancient China—Part Ⅱ.Principle and process design of amalgam coating

    Institute of Scientific and Technical Information of China (English)

    吴元康; 储荣邦

    2012-01-01

    The major roles of Cu, Sn, Pd, and Hg in amalgam coating material, the principle of metallurgical reactions between the elements, and the phase transformation involved in the process of removing mercury by heating were described. Three formulations of Sn-rich copper powder for amalgam coating were designed to reproduce antique bronze mirrors. The pretreatment of bronze wares, the preparation of amalgam coating material and its coating method, and the operation procedure of mercury removal by heating were introduced. The reasons why the Sn-rich coatings on ancient bronze wares are produced by amalgam coating of Sn-rich copper were presented.%阐述了鎏镀料中铜、锡、铅、汞的主要作用,以及加热驱汞时各元素之间冶金反应的原理和物相变化.以仿古青铜镜为例,设计了3种鎏镀用富锡铜粉的配方,介绍了青铜件的镀前处理,汞齐涂料配制和涂抹的方法,以及加热驱汞的操作步骤.指出了古青铜器表面富锡镀层为鎏镀富锡铜的依据.

  5. Destructive versus non-destructive methods for geochemical analyses of ceramic artifacts: comparison of portable XRF and ICP-MS data on Bronze Age ceramics from Failaka Island (Kuwait) and Bahrain

    Science.gov (United States)

    Stremtan, Ciprian; Ashkanani, Hasan; Tykot, Robert H.

    2013-04-01

    The study of bi-phase (i.e. matrix and clasts) geochemical composition of ceramic artifacts is a very powerful tool in fingerprinting the raw materials used by ancient manufacturers (clay sources, tempering materials, coloring agents, etc.), as well as in understanding the physical parameters of the manufacturing techniques. Reliable datasets often require the deployment of destructive techniques that will irremediably damage the artifact. Recent advances in portable X-ray fluorescence instrumentation (pXRF) allow for quick measurements of a range of chemical elements that not too long ago were available only through complicated and often destructive means of analytical chemistry (instrumental neutron activation analysis - INAA, inductively coupled plasma mass spectrometry - ICP-MS, direct coupled plasma-optical emission spectroscopy - DCP-OES etc.). In this contribution we present a comparison of datasets acquired by means of pXRF, DCP-OES, and ICP-MS on Bronze Age ceramics from Failaka Island (Kuwait) and Bahrain. The samples chosen for this study are fine grained, with very well sorted mineral components, and lack any visible organic material fragments. The sample preparation for ICP-MS and DCP-OES analyses was carried out on powdered samples, by using LiBO2 flux fusion and Ge (for the DCP-OES) and In (for ICP-MS) were used as internal standards. The measurements were calibrated against certified reference materials ranging from shales to rhyolites (SGR-1, SDo-1, JA-2, and JR-1) and performed at Univerity of South Florida's Center for Geochemical Analyses. The analytical errors for major elements was smaller than 5 %, while for selected trace elements the error was usually smaller than 3 %. The same set of elements was measured on the same samples at University of South Florida's Anthropology Department using a pXRF device equipped with obsidian filter. Each sample was measured three times and the values were averaged. Two certified reference materials (NIST-612

  6. Study on Mt.Tonglu Site, Panlongcheng Site and Bronze Civilization in Early China%铜绿山与盘龙城及中国早期青铜文明之关系

    Institute of Scientific and Technical Information of China (English)

    徐少华

    2014-01-01

    The discovery of the ancient sites of mining and metallurgy in Mt .Tonglu and other places distrib-uted in the Middle and Lower Reaches Area of Yangtze River has proved that the copper mine of this area was exploited and smelted no later than Shang Dynasty , and then lasted more than one thousand years , through-out the shining evolution course of Chinese bronze civilization in Zhou , Qin and Han dynasties.Pan-longcheng Site was the regional center of Shang′s southern territory.Besides its political and military func-tions, the other one acted as a process and transit base to obtain abundant mine sources from the south , and then transported them to the north .The rising and development of Shang culture of Panlongcheng Site has had the close relationship with the mining and smelting of the copper mine in Mt .Tonglu as well as other similar places in the south .%以铜绿山为代表的一大批古矿冶遗址的发现,证明长江中下游地区的铜矿资源最迟于商代即得到开采、冶炼,历两周至秦汉,前后延续有一千多年,几乎伴随着中国青铜文明的整个历程。盘龙城遗址是商王室统治南方的区域中心,除了政治、军事上的作用之外,还起着获取南方丰富的矿料资源,并以此作为加工、中转基地,不断输往中原商王室的重要职能;盘龙城商文化的兴起、发展,与铜绿山等地铜矿资源的采冶具有密切的内在联系。

  7. 周代丧葬礼器“翣”的再探讨--关于“山”字形薄铜片的考证%Further Discussion about Funeral Ceremonial‘Sha’(翣) of Zhou Dynasty-- Research on the Mountain-Shaped Bronze Sheet

    Institute of Scientific and Technical Information of China (English)

    胡; 王米佳

    2015-01-01

    在战国以前,“翣”应该是特指由羽毛编制而成的扇子,将“山”字形薄铜片定为“铜翣”,与文献不符。《礼记·檀弓上》中“周人墙置翣”的“翣”,很可能类似古埃及作为王权象征的半圆形长柄礼仪羽扇,是由羽毛和青铜羽座两部分组成,“山”字形薄铜片或只是羽扇的铜羽座。周代墓葬中出土的所谓“玉戈”,就是古文献中记载的玉圭。《礼记·丧大记》中的“皆戴圭”应该是指棺饰“戴圭”,而不是指翣“戴圭”。%The usage of the Chinese character“Sha”(翣)before the Warring States period should denote the feather-attached fans specifically. Attributing the mountain-shaped bronze sheets as“Sha”is therefore inconsistent with ancient texts. The“Sha”in was likely to be semicircular, long-handled feather fan, similar to the ceremonial feather fans of ancient Egypt symbolizing royal power. The mountain-shaped bronze sheets would more likely be a feather holder as the fan would likely be composed of feathers and a bronze base for mounting. The so-called jade“Ge”(戈)unearthed from the tombs of the Zhou Dynasty should thus be jade“Gui”(圭)recorded in ancient texts as an identification of feudal nobleman.“All wearing Gui”in should thus refer to the coffin decorations wearing“Gui”instead of“Sha”wearing“Gui”.

  8. Meksvideo polutshila tri "bronzõ"

    Index Scriptorium Estoniae

    2006-01-01

    Noorte amatöörfilmistuudio MEKSVIDEO kolm filmi said auhinna Oslos 9. festivalil Euro-Filmforum Scandinavia (Deniss Borissovi dokumentaalfilm "Vetshnõi vopross", Irina Ivanova animafilm "Transformis ja stuudio juhi Igor Glazistovi dokumentaalfilm "Ohrannik")

  9. Randomized Experiments as the Bronze Standard

    OpenAIRE

    Berk, Richard

    2011-01-01

    In this paper, the strengths and weakness of randomized field ex- periments are discussed. Although it seems to be common knowledge that random assignment balances experimental and control groups on all confounders, other features of randomized field experiments are somewhat less appreciated. These include the role of random assign- ment in statistical inference and representations of the mechanisms by which the treatment has its impact. Randomized experiments also have important limit...

  10. Bronze decoration for chariots in Northern Italy

    Directory of Open Access Journals (Sweden)

    Margherita Bolla

    2010-07-01

    Full Text Available Normal 0 14 Si propone un censimento delle attestazioni di decorazione in bronzo per carri in Italia settentrionale, limitando la ricerca agli elementi figurati. L’indagine, per quanto presumibilmente non esaustiva, ha condotto a un considerevole aumento delle testimonianze note (ora una cinquantina, consentendo alcune osservazioni su botteghe di produzione, proprietari, iconografia, cronologia.  

  11. Hecent investigations of a Bronze Age eruprion

    Directory of Open Access Journals (Sweden)

    P. HÉDERVARI

    1970-06-01

    Full Text Available 'l'he firHt part of the paper i8 a sllOrt account about. tllC
    «Int.ernational Seientific Congn'ss on thf', Volcano of Thera >, organized by the
    Greek Arehaeological Serviee. In t.he seeond part, the author deal~ with
    the prolJlcm uf the so-called Minoan tsnnami of vulcano Santurin. Kome
    ('alculatiolls are ma(le concerning the energy of this tHullami in c,ase of (liifer('
    nt waye_heights. 'l'he noj.jon of free tcetonie fmergy is introduccd and
    treated. The aut.hor states that the relationship betwcen the height amI
    the energy of a tsnnami, expressed mathematically by Ii(la i8 nsefnl in
    tllC eaHe of the Santorin Minoan '·Tupt.ion, too.

  12. Bronze Civilization Shines Asia Art Festival

    Institute of Scientific and Technical Information of China (English)

    Hu Chunliang

    2009-01-01

    @@ The 11th Asia Arts Festival (AAF) was held from August 18 through 26, 2009 in Ordos, a city in the northern China's Inner Mongolia autonomous region. This event was jointly sponsored by the Ministry of Culture of the People's Republic of China and the People's Government of Inner Mongolia Autonomous Region, and organized by the Ordos Municipal People's Government, Culture Department of Inner Mongolia Autonomous Region and China Arts and Entertainment Group.

  13. 西辽河上游地区新石器时代至早期青铜时代经济形态研究综述%The research review of economic form during Neolithic-Bronze Age at Western Liao River

    Institute of Scientific and Technical Information of China (English)

    孙永刚

    2014-01-01

    西辽河上游地区是我国近代考古开始较早的地区之一,自新石器时代早期至早期青铜时代,主要的考古学文化有小河西文化、兴隆洼文化、富河文化、赵宝沟文化、小河沿文化和夏家店下层文化。由于这一地区是从半干旱区向干旱区过渡的地区,也是对环境变化反映敏感的生态系统过渡带,在新石器时代至早期青铜时代受到地理条件、气候环境与外部文化的影响,形成了独特而具典型性的采集、渔猎、农业、畜牧并存的经济形态。%the West Liaohe River upstream region is one of the areas which Chinese modem archae-ology started earlier. From the Neolithic Age to Early Bronze Age, the main archaeological cultures are small hexi culture,Xinglongwa culture,Fuhe culture, Zhaobaogou culture, Xiaoheyan culture and Lower Xia-jiadian culture. Since this region is from the semi-arid region to the areas of excessive area and sensitive to environmental changes, this area evolved a unique economic form contains gathering,hunting, farming and animal husbandry in the time of the Neolithic Age to Early Bronze Age under the influence of geo-graphical conditions, climatic environment and external culture.

  14. Vingt ans de recherches à Saint-Véran, Hautes Alpes: état des connaissances de l’activité de production de cuivre à l’âge du Bronze ancien

    Directory of Open Access Journals (Sweden)

    Bourgarit, David

    2010-12-01

    Full Text Available Not available

    Durante la Edad del Bronce en Europa occidental, el aumento drástico de la producción de cobre apenas está documentado en las actividades mineras y metalúrgicas de transformación. En este contexto, el yacimiento minero y metalúrgico de Saint-Véran, Hautes-Alpes constituye un testimonio privilegiado de la producción en masa a fines del III milenio, ya que las obras mineras dan cuenta de una explotación a gran escala, con una producción de casi 7 t de cobre al año. Numerosos sitios de metalurgia extractiva puede haber estado asociados con ella. Desde hace 20 años, diversos equipos, como en el que participan los autores, han emprendido o emprenden investigaciones para intentar documentar el sitio y su actividad. El objetivo de este artículo es presentar el estado actual de la cuestión sobre el yacimiento. Los resultados principales son la puesta en evidencia de la actividad de producción en masa y su cuantificación. Además se ha descrito por primera vez la organización de la producción, poniendo en evidencia la sucesión de fases entre la actividad minera y metalúrgica, así como las técnicas metalúrgicas innovadoras puestas en práctica. El yacimiento revela un estallido muy marcado de la actividad metalúrgica en el espacio que no deja de plantear interrogantes. Igualmente, la cuestión del destino de la producción sigue abierta por completo. Por otro lado, los motores para una implantación semejante en un territorio de alta montaña han comenzado a identificarse. Así se invocan determinismos naturales ya se trate de la mineralización particular de un yacimiento como de la evolución del clima. [fr] A l’âge du Bronze ancien en Europe occidentale, l’augmentation drastique de la production de cuivre est très peu documentée au niveau des activités minières et métallurgiques de transformation. Dans ce contexte, le gisement minier et métallurgique de Saint-Véran, Hautes- Alpes constitue un

  15. Effect of stress on the head kidney of farmed largemouth bronze gud-geon (Coreius guichenoti)%人工养殖圆口铜鱼头肾组织学特征及操作胁迫对其影响

    Institute of Scientific and Technical Information of China (English)

    李茜; 杨德国; 朱永久; 赵建华; 吴兴兵; 何勇凤; 冯宪斌

    2013-01-01

      采用石蜡切片和组织涂片技术,对人工养殖圆口铜鱼(Coreius guichenoti)在正常和操作胁迫下头肾的组织、细胞形态结构及细胞数目进行研究,并探讨了其在操作胁迫后0.1、4、24 h 的变化特征。石蜡切片观察发现,圆口铜鱼头肾实质中无肾单位,主要由淋巴组织、造血组织、血管、肾间组织及黑色素巨噬细胞组成。各组织及细胞结构形态正常,分布规则。在操作胁迫后0.1、4 h 时,头肾中黑色素巨噬细胞数量较正常组显著增多,形成黑色素巨噬细胞中心,同时肾间组织增生,肾间细胞面积、核面积和核直径均有不同程度增大;在操作胁迫后24 h 时,黑色素巨噬细胞数量和肾间细胞面积、核面积、核直径均减小,并均低于正常组。组织涂片观察发现,正常圆口铜鱼头肾中主要有6类细胞:红细胞、淋巴细胞、单核细胞、嗜中性粒细胞、嗜碱性粒细胞、血栓细胞。应激后不规则红细胞增多,红细胞、嗜中性粒细胞数量和嗜碱性粒细胞持续减少;淋巴细胞和单核细胞数量在应激后0.1 h短暂增多,随后持续降低;血栓细胞数量持续增加。研究表明,圆口铜鱼头肾组织和细胞在应激后较短时间(0.1、4 h)内发生显著变化,部分组织的生物功能在24 h 时逐渐恢复正常。本研究可为圆口铜鱼及其他硬骨鱼类头肾的组织学研究、养殖与驯化过程中的健康监测等方面提供参考依据。%We determined the effect of stress on the structure, number and morphology of cells in the head kidney of cultured largemouth bronze gudgeon (Coreius guichenoti). We measured the histological alteration in 0.1, 4, and 24 h after exposure to a handling stress and compared the results with those of control fish (unstressed). In unstressed animals, the head kidney consisted ofnormal and regularly distributed lymphatic tissue, hematopoietic tissue

  16. Phase transitions and electrical characterizations of (K 0.5Na 0.5) 2x(Sr 0.6Ba 0.4) 5-xNb 10O 30 (KNSBN) ceramics with 'unfilled' and 'filled' tetragonal tungsten-bronze (TTB) crystal structure

    KAUST Repository

    Yao, Yingbang

    2012-12-01

    Alkali-doped strontium barium niobate (K 0.5Na 0.5) 2x(Sr 0.6Ba 0.4) 5-xNb 10O 30 (KNSBN) ceramics has been prepared by a conventional solid-state reaction method. The alkali-dopant concentration x has been varied from 0.24 to 1.15 so that the crystal structure was transformed from \\'unfilled\\' to \\'filled\\' tetragonal tungsten-bronze (TTB) structure. Apart from the change in the structural properties, the effects of the alkali-dopants on the phase transition as well as ferroelectric, piezoelectric and pyroelectric properties have also been investigated. Phase transitions have been studied in the temperature range of -200°C to 350°C. The origins of these phase transitions are discussed. The addition of the alkali-dopants enhances the ferroelectric, piezoelectric and pyroelectric properties of the KNSBN ceramics. Alkali-doping also favors abnormal grain growth and thus results in a porous microstructure, which might contribute to the enhancement of the pyroelectric performance. © 2012 Elsevier Ltd.

  17. Como antigas estátuas de bronze

    Directory of Open Access Journals (Sweden)

    Oliver Lubrich

    2010-01-01

    Full Text Available A interpretação de América usando motivos classicistas como modelos imperiais de apropriação, "antiquização", é uma das principais estratégias retóricas nos relatos de viagens de Alexander von Humboldt, Relation historique du voyage aux régions équinoxiales du Nouveau Continent (1814-1831. A partir da experiência colonial, esse discurso está carregado de tensão. O conceito de antiguidade é, assim, desautorizado e desconstruído. Os leitores são testemunhas da dissolução do classicismo europeu como dispositivo político-estético produzido pela diferença cultural."Antiquifying" America is a central rhetorical strategy in Alexander von Humboldt's Relation historique du voyage aux régions équinoxiales du Nouveau Continent (1814-1831. Over the course of the colonial experience, tension infuses the discourse and problems in the use of classicist motifs as imperial models of appropriation become apparent: metaphoric and metonymic references collide; positive and negative connotations overlap; incompatible modes of temporalization contrast with one another; colonial and dissident identifications coincide. The concept of "antiquity" is de-authorized, deconstructed. Readers witness the dissolution of European classicism as a politico-aesthetic 'dispositif' due to the experience of cultural difference.

  18. Nettle as a distinct Bronze Age textile plant

    DEFF Research Database (Denmark)

    Bergfjord, C.; Mannering, Ulla; Frei, Karin Margarita;

    2012-01-01

    It is generally assumed that the production of plant fibre textiles in ancient Europe, especially woven textiles for clothing, was closely linked to the development of agriculture through the use of cultivated textile plants (flax, hemp). Here we present a new investigation of the 2800 year old...

  19. Research into the Bronze and Early Iron Ages / Aivar Kriiska

    Index Scriptorium Estoniae

    Lang, Valter, 1958-

    2006-01-01

    19. sajandil olid mõisted pronksiaeg ja eelrooma rauaaeg praktiliselt tundmatud. Kuni 1950ndateni domineeris rooma rauaaja uurimine. Nüüd on selgunud, et seni kultuurilise depressiooni perioodiks peetud aeg (tuntud kivikirstkalmete perioodina), oli tegelikult üks dünaamilisemaid perioode Eesti esiajaloos. Eesti ala ebaühtlasest asustusest sel perioodil

  20. Sodium tungsten bronze thin films by rf sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Anderegg, J.W.

    1977-03-01

    Polycrystalline Na/sub x/WO/sub 3/ films were produced by rf sputtering. Films of low x-value resulted when co-sputtering WO/sub 3/ on a Na/sub 0.83/WO/sub 3/ target, and Na/sub 0/./sub 83/ on WO/sub 3/ target. Films of high x and of mixed phase were produced by sputtering a powder mixture of Na/sub 2/WO/sub 4/ and WO/sub 3/ on a tungsten target. Of the sputtering parameters studied, the substrate temperature is the most critical with temperatures above 500/sup 0/C producing films which were cubic in structure with only a small amount of Tetragonal I. The presence of oxygen up to 3 percent by volume had minimal effect on film quality or x-value. Auger, electron microprobe, SIMS, SEM, x-ray diffraction, and sheet resistivity techniques were used in characterizing these films. Resistivity of the films was a factor of 10 higher than the bulk crystalline data for Na/sub 0/./sub 83/WO/sub 3/.

  1. Cavitation Erosion of Cermet-Coated Aluminium Bronzes

    Directory of Open Access Journals (Sweden)

    Ion Mitelea

    2016-03-01

    Full Text Available The cavitation erosion resistance of CuAl10Ni5Fe2.5Mn1 following plasma spraying with Al2O3·30(Ni20Al powder and laser re-melting was analyzed in view of possible improvements of the lifetime of components used in hydraulic environments. The cavitation erosion resistance was substantially improved compared with the one of the base material. The thickness of the re-melted layer was in the range of several hundred micrometers, with a surface microhardness increasing from 250 to 420 HV 0.2. Compositional, structural, and microstructural explorations showed that the microstructure of the re-melted and homogenized layer, consisting of a cubic Al2O3 matrix with dispersed Ni-based solid solution is associated with the hardness increase and consequently with the improvement of the cavitation erosion resistance.

  2. A Late Bronze Age Potter's Workshop at Lachish, Israel

    Directory of Open Access Journals (Sweden)

    Andrew Middleton

    2000-10-01

    Full Text Available This paper does not use petrography to specifically provenance pottery, but rather to examine the raw materials used in a single potter's workshop. The authors have sought to reconstruct the manufacture of ceramics from clay procurement, preparation of the raw clay to forming techniques and decoration.

  3. MULTIPLE LEVELS IN THE AEGEAN BRONZE AGE WORLD-SYSTEM

    Directory of Open Access Journals (Sweden)

    Nick Kardulias

    2015-08-01

    Full Text Available Aegean societies in the third and second millennia B.C. developed complex economics based on the accumulation of substantial agricultural surpluses, craft specialization, and intricate distribution systems. The trade items included both utilitarian and luxury goods. To place these activities in a proper context, this paper initially evaluates the world systems literature as it relates to antiquity. The paper then presents some specific evidence to support the contention that the Aegean BA economy was an adjunct to an Eastern Mediterranean world system. While Wallerstein's model offers valuable insights into the operation of trade networks, his approach has certain limitations. The paper explores some of these limitations, in particular the absence of periphery dependence on core areas that is a hallmark of modern capitalist systems, discusses revisions suggested by other scholars, and demonstrates the validity of the altered model with data from the Aegean. The evidence suggests the existence of a system with local, intraregional, and extraregional components. Finally, the paper also suggests that the world systemsapproach needs to place greater emphasis on production, not just exchange, as the crucial nexus of economic activity.

  4. 激光在线修整青铜金刚石砂轮数值仿真与试验%Numerical simulation and experiment for on-line truing and dressing of bronze-bonded diamond grinding wheels with laser

    Institute of Scientific and Technical Information of China (English)

    陈根余; 陈冲; 卜纯; 贾天阳

    2012-01-01

    Based on both numerical simulation and experimental investigation, much research work has been done on online truing and dressing bronze-bonded diamond grinding wheel by acoustic-optic Q-switched YAC pulsed laser. A 3-D mathematical simulation model and a heat transfer model of single pulsed laser ablating the diamond abrasive was established by means of finite element method, where the process of diamond graphitization was taken into account. The removal depth of the diamond abrasive in different laser parameters (such as focal position, pulse width and laser power) was measured, and the relationship between them was analysed, which helped us to select optimal parameters. The results show that: the laser power, pulse width and the focal position are the direct effects of the removal depth of the diamond abrasive; it will increase along with the increase of laser power, and decrease along with the increase of pulse width and the focal position. The on-line grinding wheel dressing was achieved with closed-loop control, CCD and laser triangulation displacement measuring instrument which were used in control of ^-switch and the on-line monitoring of the circular run-out of the grinding wheel. After laser truing and dressing, the accuracy was further improved,the circular run-out error was reduced,and the surface topography was improved loo.%为了研究声光调Q YAG脉冲激光在线修整青铜结合剂金刚石砂轮,采用数值仿真和试验相结合的方法,在考虑金刚石石墨化过程的基础上,通过有限元数值模拟的方法建立了3维单脉冲激光烧蚀金刚石磨粒的数学模型和传热模型,研究了脉冲激光参量(离焦量、脉宽和激光功率)对金刚石磨粒去除厚度的影响规律,为激光修整参量选择提供了指导.结果表明,激光功率、脉宽和离焦量是影响脉冲激光金刚石磨粒去除厚度的最直接的因素,金刚石磨粒去除厚度随着激光功率的增加而变大;随着脉宽的增

  5. Human impact during the Bronze Age on the vegetation at Lago Lucone (northern Italy)

    NARCIS (Netherlands)

    Valsecchi, V.; Tinner, W.; Finsinger, W.; Ammann, B.

    2006-01-01

    Lake-sediment records were used to reconstruct human impact on the landscape around Lago Lucone (45°33′N, 10°29′E, 249 m a.s.l.), a former lake in the western amphitheatre system of the Lago di Garda. Presence of prehistoric human populations is attested by pile-dwelling settlements from the Early-M

  6. Dry metal forming of high alloy steel using laser generated aluminum bronze tools

    Directory of Open Access Journals (Sweden)

    Freiße Hannes

    2015-01-01

    Full Text Available Regarding the optimization of forming technology in economic and environmental aspects, avoiding lubricants is an approach to realize the vision of a new green technology. The resulting direct contact between the tool and the sheet in non-lubricated deep drawing causes higher stress and depends mainly on the material combination. The tribological system in dry sliding has to be assessed by means on the one hand of the resulting friction coefficient and on the other hand of the wear of the tool and sheet material. The potential to generate tailored tribological systems for dry metal forming could be shown within the investigations by using different material combinations and by applying different laser cladding process parameters. Furthermore, the feasibility of additive manufacturing of a deep drawing tool was demonstrated. The tool was successfully applied to form circular cups in a dry metal forming process.

  7. Scientific Bronze Casting Reconstruction of Zhang Heng's Seismograph from the Eastern Han Dynasty

    Institute of Scientific and Technical Information of China (English)

    Hu Chunliang

    2010-01-01

    @@ Commissioned by the state Task Force for scientific reconstruction of Zhang Heng's seismograph, the "Eastern Han Zhang Heng's seismograph" was successfully cast on August 5, 2008 at Shanxi Yuda Group, a national cultural industry demonstration base. After sophisticated assembly and debugging,the 1.7 m tall reconstructed Zhang Heng's seismograph was displayed at the Science and Technology Museum of China in August 2009,making the Eastern Han Zhang Heng's seismograph which had been lost for thousands of years reemerge in the world.

  8. Re-writing the Script: Decoding the Textual Experience in the Bronze Age Levant

    OpenAIRE

    Sparks, R. T. E.

    2013-01-01

    Writing in its many forms was an important part of the political, economic and cultural landscape of the Levant during the Second Millennium BC. Diverse scripts were used to record both local and foreign languages, and included Egyptian hieroglyphics, cursive hieroglyphics, hieratic, cuneiform, alphabetic cuneiform, Proto-Canaanite, Hittite hieroglyphs and linear Aegean scripts. While the corpus is not large, it is significant and hints at the range of writing practices and knowledge availabl...

  9. B3 and B9 huts at the Bronze Age settlement of Mursia (Pantelleria)

    OpenAIRE

    Matteo Cantisani

    2015-01-01

    The hut B3 and B9, located on the southwestern edge of Sector B of the prehistoric settlement of Mursia, identify frequent structural changes inside the residential unit. The huts are characterized by architectural components and floor plans typical of the early phase of this part of the settlement and show clear traces of continuous occupation in spite of the architectural rearrangement. The reconstruction of the stratigraphic sequence, the analysis of the formation processes of the material...

  10. Characterization of Bronze Surface Layer Formed by Microarc Oxidation Process in 12-Tungstophosphoric Acid

    Directory of Open Access Journals (Sweden)

    Zoran Nedić

    2009-12-01

    Full Text Available This paper is a brief review of our recent research into novel uses for heteropoly compounds as precursors for thin films that can be used as catalysts and materials with good optical, conductive and other characteristics. In view of this, we have chosen thin film obtained with 12-tungsphosphoric acid on aluminum substrates. In all cases, a relatively new, microarc oxidation technique has been used to prepare oxide coatings on substrate surfaces. Advanced physicochemical methods, AFM and SEM-EDS, XRD, Raman and Micro-Raman, and luminescence spectroscopy, as the most powerful techniques, have been used for the characterization of new materials. Possible applications have been discussed as well.

  11. Gristhorpe Man: an Early Bronze Age log-coffin burial scientifically defined

    DEFF Research Database (Denmark)

    Melton, Nigel; Montgomery, Janet; Knüsel, Christopher J.;

    2010-01-01

    A log-coffin excavated in the early nineteenth century proved to be well enough preserved in the early twenty-first century for the full armoury of modern scientific investigation to give its occupants and contents new identity, new origins and a new date. In many ways the interpretation is much...

  12. Un relief en bronze sabéen d’inspiration proche-orientale

    Directory of Open Access Journals (Sweden)

    Iris Gerlach

    2003-09-01

    Full Text Available Dans l’étude des relations interculturelles entre l’Arabie du Sud et la région syro-palestinienne d’une part, la Mésopotamie d’autre part, l’examen du tracé des voies commerciales et l’exploitation des sources assyriennes mentionnant les royaumes sudarabiques ou leurs monarques apparaissaient jusqu’ici comme essentiels. Par ailleurs, une étude approfondie des écrits des auteurs classiques a également été entreprise. Hérodote (Histoire, III, 107, Strabon (Géographie, XVI, 765 sq. et Pline l’...

  13. Anomalously strong plasmon resonances in aluminium bronze by modification of the electronic density-of-states.

    Science.gov (United States)

    Shahcheraghi, N; Keast, V J; Gentle, A R; Arnold, M D; Cortie, M B

    2016-10-12

    We use a combination of experimental measurements and density functional theory calculations to show that modification of the band structure of Cu by additions of Al causes an unexpected enhancement of the dielectric properties. The effect is optimized in alloys with Al contents between 10 and 15 at.% and would result in strong localized surface plasmon resonances at suitable wavelengths of light. This result is surprising as, in general, alloying of Cu increases its DC resistivity and would be expected to increase optical loss. The wavelengths for the plasmon resonances in the optimized alloy are significantly blue-shifted relative to those of pure Cu and provide a new material selection option for the range 2.2-2.8 eV. PMID:27518759

  14. 78 FR 56832 - Extension of Import Restrictions Imposed on Archaeological Material From Cambodia From the Bronze...

    Science.gov (United States)

    2013-09-16

    ... Department of State made under the terms of the Convention on Cultural Property Implementation Act in... Cultural Property. CBP Dec. 08-40 contains the Designated List of archaeological material from Cambodia to.... law as the Convention on Cultural Property Implementation Act (Pub. L. 97-446, 19 U.S.C. 2601 et...

  15. Valuable Bronze Wares Unearthed in the Hometown of Terri-Cotta Warriors

    Institute of Scientific and Technical Information of China (English)

    zhouzhi

    2003-01-01

    4 pm on January 19, 2003. A bright day over the Loess Steppe in northwest Shaanxi Province. Five farmers from Yang Village, Meixian, Baoji, was collecting earth at a hill nearby for the village's brick workshop. All of sudden,a farmer's pickax touched a spot which was hollow underneath. He thought it was the entrance of a tomb. He looked

  16. 说“见事”%The Word“Jianshi”(见事) in Bronze Scripts

    Institute of Scientific and Technical Information of China (English)

    朱彩云

    2014-01-01

    Theword“Jianshi”( 见 事 )wasseenintheinscriptionsonYanhouzhiding( 匽侯旨鼎). Scholars have had four different opinions on its meaning----to report in person the performance of one's official duties, to devote oneself to work, an etiquette, and to have an audience with the emperor. We agree with the first one. We also believe、 seen in the inscriptions on Yangfangding(扬方鼎) is exactly the word“Jianshi”(见事) rather than“Shishi”(视事). The word“Jianshi”(见士) found in KangAnnouncementofShangshu (《尚書•康誥》)and“Jianfu”(见服)fromtheinscriptionsonZuocehuyou(作冊 卣) sharethesamemeaningwith“Jianshi”(见事).Themeaningoftheword“Jianshi”(见事) seen in modern Chinese differs a lot from those ancient ones.%提匽侯旨鼎铭文中有“见事”一词,对于其意,众家说法不一。综合来说,约有四种:述职、勤劳政事、一种礼节、朝见。笔者以为“见事”当释作“述职”,铭文中表示“申述职守”之义。方鼎所见、也当释作“见事”,而非“视事”。《尚书•康诰》有“见士”一词,士、事相通,“见士”即“见事”。作册卣“见服”一词亦当与“见事”同义。现代汉语中常见的“见事”已经与铭文中的“见事”大不相同。

  17. Characterization of Bronze Surface Layer Formed by Microarc Oxidation Process in 12-Tungstophosphoric Acid

    OpenAIRE

    Zoran Nedić; Stevan Stojadinović; Ubavka B. Mioč

    2009-01-01

    This paper is a brief review of our recent research into novel uses for heteropoly compounds as precursors for thin films that can be used as catalysts and materials with good optical, conductive and other characteristics. In view of this, we have chosen thin film obtained with 12-tungsphosphoric acid on aluminum substrates. In all cases, a relatively new, microarc oxidation technique has been used to prepare oxide coatings on substrate surfaces. Advanced physicochemical methods, AFM and SEM-...

  18. B14 hut at the Bronze Age settlement of Mursia (Pantelleria

    Directory of Open Access Journals (Sweden)

    Florencia Debandi

    2015-12-01

    Full Text Available This contribute deals with the explanation of the archaeological excavation of the B14 hut, that symbolizes the residential structures of the earliest phase of the village, but at the same time it can be considered exceptional for the size and for the inner setting. The stratigraphic sequence shows several episodes of transformation of inhabited space with real twisting changes that took place early in the history of the hut. In particular, in spite of the initial planning of the dwellings, each single feature adapted shape and size to different requirements among inhabitants, both productive and domestic. Ceramics of each phase of the sequence are presented showing vase types used especially in the earliest phase of the settlement. A the end of the life, the hut was completely covered by other dwellings.

  19. L’eau du Hauran : captages et gestion depuis le Bronze ancien

    OpenAIRE

    Davtian, Gourgen

    2010-01-01

    A l’écart des systèmes hydrauliques des grands fleuves, la maîtrise de l’eau passe, dans les zones sous influence méditerranéenne et à la limite de la steppe aride, par l’exploitation des ressources saisonnières, captages de sources non pérennes et dérivation des crues de rivières temporaires. La Syrie du sud basaltique a préservé des témoignages très importants de ces aménagements, dont la mise en place a commencé au 4ème millénaire. Une deuxième phase d’aménagements a été réalisée à la péri...

  20. Quantifying Multiple Types of Damping Acting on Bronze-Wound Guitar Strings

    OpenAIRE

    Christian, Jonathan

    2011-01-01

    The goal of this study was to quantify the contributions of multiple damping types acting on guitar strings for each mode over a wide frequency range so that design variables could be identified to one day create frequency based damping in guitar strings. Structural dynamic testing was used to obtain the time-response of a vibrating string in open air and in a vacuum. From this signal, each harmonic was filtered and the decay envelope was curve-fitted with a function that was a linear summati...

  1. La incineració funerària a Sardenya durant l'Edat de Bronze

    OpenAIRE

    Malgosa Morera, Assumpció

    2008-01-01

    Els últims estudis arqueològics indicaven que fins a l'arribada de la cultura fenícia al Mediterrani Occidental (s. IX a.C), la inhumació semblava ser l'única pràctica funerària durant la prehistòria de Sardenya. Ara, la història podria reescriure's degut a una recent excavació duta a terme a la Tomba IX de Sa Figu, prop de la ciutat italiana de Sassari. Mitjançant una anàlisi física-química de la combustió dels ossos trobats a la necròpoli s'ha demostrat que sí s'utilitzava el foc durant els...

  2. The Bronze soldier in Tõnismäe bears historical values of democratic Europe / Tiit Toomsalu

    Index Scriptorium Estoniae

    Toomsalu, Tiit, 1949-

    2008-01-01

    Eesti Vasakpartei Tallinna organisatsiooni deklaratsiooni kohaselt lõhestab pronkssõduri teema politiseerimine ühiskonda, häirib riigi sisemist stabiilsust ning kahjustab rahvusvahelisel tasandil Eesti Vabariigi mainet

  3. Characterization of cosmetic sticks at Xiaohe Cemetery in early Bronze Age Xinjiang, China

    Science.gov (United States)

    Mai, Huijuan; Yang, Yimin; Abuduresule, Idelisi; Li, Wenying; Hu, Xingjun; Wang, Changsui

    2016-01-01

    Cosmetics have been studied for a long time in the society and culture research, and its consumption is regarded as a cultural symbol of human society. This paper focuses on the analysis of the red cosmetic sticks, found in Xiaohe Cemetery (1980-1450BC), Xinjiang, China. The structure of the red cosmetic sticks was disclosed by SR-μCT scanning (Synchrotron Radiation Micro-computed Tomography), while the chemical components were characterized by FTIR (Fourier Transform Infrared Spectroscopy), Raman Spectroscopy and Proteomics. The results suggested that the cosmetic sticks were made from the cattle heart and covered with a layer of hematite powders as the pigment. Given the numerous red painted relics in Xiaohe Cemetery, this kind of cosmetic sticks might be used as a primitive form of crayon for makeup and painting. The usage of cattle hearts as cosmetic sticks is firstly reported up to our knowledge, which not only reveals the varied utilizations of cattle in Xiaohe Cemetery but also shows the distinctive religious function. Furthermore, these red cosmetic sticks were usually buried with women, implying that the woman may be the painter and play a special role in religious activities.

  4. Bronze Tiger Sculptures Exhibition at the 4th China Beijing International Cultural & Creative Industry Expo

    Institute of Scientific and Technical Information of China (English)

    Hu Chunliang

    2010-01-01

    @@ Sponsored and organised by the Chinese Ministry of Culture, the Chinese State Administration of Radio, Film and Television, the Chinese General Administration of Press and Publication and the Government of Beijing, the 4th China Beijing International Cultural & Creative Industry Expo (ICCIE) was successfully held in Beijing on November 26-29,2009. The Expo took China International Exhibition Centre as a main exhibition area with additional 9 sub-exhibition areas in the districts and counties of Beijing (total exhibition area 65,000 m2).

  5. The Bronze Soldier in Tallinn : a reminder of the lack of common history / Imbi Sooman

    Index Scriptorium Estoniae

    Sooman, Imbi

    2009-01-01

    Taustast ja sündmustest aprillist augustini 2007. a. seoses pronkssõduri teisaldamisega Tallinnas; väljavõtteid ajakirjandusest ja internetist. Pronkssõduri tähendus eestlastele ja venelastele on erinev

  6. Estonie 2006-2007 : L'ombre du soldat de bronze / Antoine Chalvin

    Index Scriptorium Estoniae

    Chalvin, Antoine

    2007-01-01

    Ülevaade olulisematest poliitilistest sündmustest Eestis aastatel 2006-2007: presidendi- ja parlamendivalimistest, integratsiooniprobleemidest, Tõnismäe pronkssõduri ümberpaigutamisega kaasnenud rahutustest ning küberrünnakutest. Alapeatükis "Une election presidentielle mouvementee" on antud ülevaade Toomas Hendrik Ilvese ja Arnold Rüütli konkureerimisest presidendivalimistel. Tabel: Põhilised majandusnäitajad 1999-2006. Vt. samas: Poliitiliste sündmuste kronoloogia juuni 2006 - juuni 2007; Viimased valimistulemused; Valitsuse koosseis

  7. Bronze solider - chronology when and how he became notorious / Toomas Alatalu

    Index Scriptorium Estoniae

    Alatalu, Toomas, 1942-

    2008-01-01

    Kronoloogiline ülevaade pronkssõduri paigaldamisest Tõnismäele, rahutustele eelnenud sündmusest, tänavarahutustest, pronksõduri teisaldamisest ning sellele järgnenud reaktsioonidest rahvusvahelistes suhetes ja kohalike poliitikute hulgas

  8. A systematic review on the diagnosis of pediatric bacterial pneumonia: when gold is bronze.

    Directory of Open Access Journals (Sweden)

    Tim Lynch

    Full Text Available BACKGROUND: In developing countries, pneumonia is one of the leading causes of death in children under five years of age and hence timely and accurate diagnosis is critical. In North America, pneumonia is also a common source of childhood morbidity and occasionally mortality. Clinicians traditionally have used the chest radiograph as the gold standard in the diagnosis of pneumonia, but they are becoming increasingly aware that it is not ideal. Numerous studies have shown that chest radiography findings lack precision in defining the etiology of childhood pneumonia. There is no single test that reliably distinguishes bacterial from non-bacterial causes. These factors have resulted in clinicians historically using a combination of physical signs and chest radiographs as a 'gold standard', though this combination of tests has been shown to be imperfect for diagnosis and assigning treatment. The objectives of this systematic review are to: 1 identify and categorize studies that have used single or multiple tests as a gold standard for assessing accuracy of other tests, and 2 given the 'gold standard' used, determine the accuracy of these other tests for diagnosing childhood bacterial pneumonia. METHODS AND FINDINGS: Search strategies were developed using a combination of subject headings and keywords adapted for 18 electronic bibliographic databases from inception to May 2008. Published studies were included if they: 1 included children one month to 18 years of age, 2 provided sufficient data regarding diagnostic accuracy to construct a 2x2 table, and 3 assessed the accuracy of one or more index tests as compared with other test(s used as a 'gold standard'. The literature search revealed 5,989 references of which 256 were screened for inclusion, resulting in 25 studies that satisfied all inclusion criteria. The studies examined a range of bacterium types and assessed the accuracy of several combinations of diagnostic tests. Eleven different gold standards were studied in the 25 included studies. Criterion validity was calculated for fourteen different index tests using eleven different gold standards. The most common gold standard utilized was blood culture tests used in six studies. Fourteen different tests were measured as index tests. PCT was the most common measured in five studies each with a different gold standard. CONCLUSIONS: We have found that studies assessing the diagnostic accuracy of clinical, radiological, and laboratory tests for bacterial childhood pneumonia have used a heterogeneous group of gold standards, and found, at least in part because of this, that index tests have widely different accuracies. These findings highlight the need for identifying a widely accepted gold standard for diagnosis of bacterial pneumonia in children.

  9. The roles of Mesopotamian bronze age mathematics tool for state formation and administration

    DEFF Research Database (Denmark)

    Høyrup, Jens

    2007-01-01

    The article describes the social and cultural roles of Mesopotamian mathematics and the interplay of these roles with such patterns of mathematical thought as can be traced through the sources; it covers the period from the first formation of a genuine state, shortly after the mid-fourth millennium...

  10. Bronze Casting Sculptures in Commemoration of the 30th Anniversary of China-US Diplomatic Relations

    Institute of Scientific and Technical Information of China (English)

    Hu Chunliang

    2010-01-01

    @@ The activity of peace and friendship sculptures to commemorate the 30th anniversary of China-US diplomatic relations,co-organized by the Beijing Returned Overseas Chinese Federation,Consolidated Society of Chinese University Alumni Associations(CSCUAA),the Association of Chinese Professionals in Atlanta(ACP),US-China Sculpture Friendship Center,was to commemorate the 30th anniversary of the establishment of formal diplomatic relations between China and the United States,to last peace and friendship between our two countries by means of arts,to advocate the values of our Chinese nation that peace is valuable and to express the sincere hopes and best wishes of our Chinese people for constructing the harmonic world.

  11. The Identification and Treatment of a Unique Cache of Organic Artefacts from Menorca's Bronze Age

    Directory of Open Access Journals (Sweden)

    Howard Wellman

    1996-05-01

    Full Text Available A unique cache of organic artefacts was excavated in March 1995 from Cova d'es Carritx, Menorca, a sealed cave system that was used as a mortuary in the late second or early first millennia BC. This deposit included a set of unique conical tubes made of bovine horn sheath, stuffed with hair or other fibres, and capped with wooden disks. Other materials were found in association with the tubes, including a copper-tin alloy rod. The decision to display some of the tubes required a degree of consolidative strengthening which would conflict with conservation aims of preserving the artefacts essentially unchanged for future study. The two most complete artefacts were treated by localised consolidation (with Paraloid B-72, while the other two were left untreated. The two consolidated tubes were provided with display-ready mounts, while the others were packaged to minimise the effects of handling and long-term storage.

  12. Superconducting properties of (Nb,Ta)3Sn wires fabricated by the bronze process

    International Nuclear Information System (INIS)

    Measurements of the superconducting critical temperature T/sub c/, critical current density, J/sub c/ (83Sn monofilamentary wires. Ta content in the Nb3Sn compound was varied by alloying the Nb core prior to a reaction heat treatment. Core compositions were 0, 3, 7, 10, and 20 wt% Ta and heat treatments for the reaction were 16, 64, and 120 h at 7250C. For the 120 h heat treatment T/sub c/ decreased monotonically with Ta content from 17.5 to 15.7K while H/sub c2/ increased from 19.8 to 24.6 T. With increasing Ta content J/sub c/ (16 T) increased from 0.7 x 105 A/cm2 to a maximum value of 1.3 x 105 at 7 wt% Ta. Further increases in the Ta content produced a decrease in J/sub c/(16 T). At 10 T J/sub c/ decreased with increasing Ta content. An important aspect of this work is the observation that alloying with Ta did not hinder wire ductility during drawing. It appears therefore that the improvements in J/sub c/(16 T) can be incorporated into commercially manufactured conductors

  13. Ansip lays flowers at Bronze Soldier, while government seeks to bridge gap in society

    Index Scriptorium Estoniae

    2007-01-01

    Peaminister Andrus Ansip asetas pärja Pronkssõdurile ja kohtus rahvusvähemuste esindajatega. Eesti meediaruumis oleks vaja enam tähelepanu venekeelsele infole. Linnapea Edgar Savisaare käitumisest rahutuste ajal

  14. Anomalously strong plasmon resonances in aluminium bronze by modification of the electronic density-of-states

    Science.gov (United States)

    Shahcheraghi, N.; Keast, V. J.; Gentle, A. R.; Arnold, M. D.; Cortie, M. B.

    2016-10-01

    We use a combination of experimental measurements and density functional theory calculations to show that modification of the band structure of Cu by additions of Al causes an unexpected enhancement of the dielectric properties. The effect is optimized in alloys with Al contents between 10 and 15 at.% and would result in strong localized surface plasmon resonances at suitable wavelengths of light. This result is surprising as, in general, alloying of Cu increases its DC resistivity and would be expected to increase optical loss. The wavelengths for the plasmon resonances in the optimized alloy are significantly blue-shifted relative to those of pure Cu and provide a new material selection option for the range 2.2–2.8 eV.

  15. Marine Creatures and the Sea in Bronze Age Greece: Ambiguities of Meaning

    Science.gov (United States)

    Berg, Ina

    2013-06-01

    Like most cultures, prehistoric Greek communities had an ambiguous relationship with the sea and the creatures that inhabit it. Positive and negative associations always co-existed, though the particular manifestations changed over time. By drawing together evidence of consumption of marine animals, seafaring, fishing, and iconography, this article unites disparate strands of evidence in an attempt to illuminate the relationship prehistoric Greeks had with marine creatures and the sea. Based on the marked reduction in seafood consumption after the Mesolithic and the use of marine creatures in funerary iconography in the post-palatial period, it becomes apparent that the sea—then as now—is an inherently ambiguous medium that captures both positive and negative emotions. On the one hand, the sea and the animals residing in it are strongly associated with death. On the other hand, the sea's positive dimensions, such as fertility and rebirth, are expressed in conspicuous marine consumption events.

  16. Microstructural and Mechanical Properties of Friction Stir Welded Nickel-Aluminum Bronze (NAB) Alloy

    Science.gov (United States)

    Küçükömeroğlu, T.; Şentürk, E.; Kara, L.; İpekoğlu, G.; Çam, G.

    2016-01-01

    In this study, the applicability of friction stir welding to cast NAB alloy (i.e., C95800) with a thickness of 9 mm has been investigated. The joint performance was determined by conducting optical microscopy, microhardness measurements, and mechanical testing (e.g., tensile and Charpy impact tests). The effect of stir intensity on joint performance was also determined. A grain refinement (equiaxed fine grain structure) as well as evolution of a Widmanstätten structure was achieved within the stir zone of all the joints produced. Thus, all of the joints produced exhibited higher proof stress (i.e., between 512 and 616 MPa) than that of the base material, i.e., 397 MPa. On the other hand, only half of the specimens exhibited higher tensile strength values than that of the base plate (i.e., 794 MPa), whereas the other specimens displayed lower tensile strength than the base plate due to the existence of weld defects, namely cold bonding and/or tunnel defect.

  17. Craftmanship, Production and Distribution of Metalwork in the Early and Middle Northern Bronze Age

    DEFF Research Database (Denmark)

    Nørgaard, Heide Wrobel

    Workshops and their sphere of influence is an important factor in the identification of social groups who are related to what we term workshop. Here the specialization within the workshop based on certain forms and behaviours can be linked to the knowledge of social groups. Statements about the o...

  18. Crystal structure and crystal chemistry of melanovanadite, a natural vanadium bronze.

    Science.gov (United States)

    Konnert, J.A.; Evans, H.T., Jr.

    1987-01-01

    The crystal structure of melanovanadite from Minas Ragra, Peru, has been determined in space group P1. The triclinic unit cell (non-standard) has a 6.360(2), b 18.090(9), c 6.276(2) A, alpha 110.18(4)o, beta 101.62(3)o, gamma 82.86(4)o. A subcell with b' = b/2 was found by crystal-structure analysis to contain CaV4O10.5H2O. The subcell has a layer structure in which the vanadate sheet consists of corner-shared tetrahedral VO4 and double square-pyramidal V2O8 groups, similar to that previously found in synthetic CsV2O5. Refinement of the full structure (R = 0.056) showed that the Ca atom, which half-occupies a general position in the subcell, is 90% ordered at one of these sites in the whole unit cell. Bond length-bond strength estimates indicate that the tetrahedra contain V5+, and the square pyramids, V4+.-J.A.Z.

  19. Bronzino and a bronze boar. Hans Christian Andersen and Stendhal in nineteenth-century Florence

    NARCIS (Netherlands)

    Klerck, A.R. de

    2015-01-01

    Bronzino e il porcellino: Hans Christian Andersen e Stendhal nella Firenze del XIX secolo La storia dell’arte dell’Ottocento non sembra aver avuto particolarmente a cuore gli artisti italiani delle generazioni successive ai grandi maestri rinascimentali, quali Raffaello e Michelangelo. Così, ad ese

  20. Some of Bronze Casting Public Sculptures Received the China's Public Sculpture Achievement Award

    Institute of Scientific and Technical Information of China (English)

    Hu Chunliang

    2010-01-01

    @@ Public sculpture is usually regarded not only as a symbol of a city, but is as a treasure of a city's memory and a point of cohesion for the residents' memory and emotions. Co-sponsored by the Ministry of Housing and Urban- Rural Development, and the Ministry of Culture, organized by the National Urban Sculpture Developing and Guiding Committee, the winning artworks of the China's Public Sculpture Achievement Award were unveiled on December 30, 2009.

  1. Analemmatic and Horizontal Sundials of the Bronze Age (Northern Black Sea Coast)

    CERN Document Server

    Vodolazhskaya, Larisa

    2013-01-01

    The paper presents the results of a study of unique plate with images of Srubna burial of tumuli group Popov Yar-2 (Ukraine) and plate of Srubna burial of tumulus field Tavriya-1 (Russia). A distinctive feature of the images is the orderliness and symmetry of the composition, as well as the location of elliptical cupped depressions. With the help of mathematical and astronomical methods we prove in this paper that the plates with the images are the ancient sundials. At the Popov Yar-2 plate located two sundials, which worked at the same time: the analemmatic sundial and the horizontal sundial with two gnomons and the linear scale. At the Tavriya-1 plate located analemmatic sundial. On the basis of the reconstruction of the linear parameters of the gnomon of both Popov Yar-2 plate sundials and given the scale value of horizontal sundial, in the article that the potential indirect impact protoscientific knowledge of ancient Egypt to the Srubna population in the Northern Black Sea coast. Srubna burial, plate, we...

  2. Late Bronze Age depot from the foothills of the Pilis Mountains

    OpenAIRE

    János Gábor Tarbay

    2015-01-01

    The analyzed assemblage was found in 2008 by Gergely Radovics, in the vicinity of Kesztölc (Hungary, Komárom-Esztergom county). It consists of 107 artefacts (total weight: 12260.31 g) which can be divided into nine groups based on their function: 1. weapons; 2. utensils; 3. clothing parts; 4. metal vessel; 5. wagon part; 7. semi-finished products; 8. metallurgical byproducts; 9. unclassifiable objects. The aim of this study is to give a complete evaluation of the artefacts in question by usin...

  3. Late Bronze Age depot from the foothills of the Pilis Mountains

    Directory of Open Access Journals (Sweden)

    János Gábor Tarbay

    2015-02-01

    Full Text Available The analyzed assemblage was found in 2008 by Gergely Radovics, in the vicinity of Kesztölc (Hungary, Komárom-Esztergom county. It consists of 107 artefacts (total weight: 12260.31 g which can be divided into nine groups based on their function: 1. weapons; 2. utensils; 3. clothing parts; 4. metal vessel; 5. wagon part; 7. semi-finished products; 8. metallurgical byproducts; 9. unclassifiable objects. The aim of this study is to give a complete evaluation of the artefacts in question by using the typo-chronological method and macroscopic observations. In addition, due to the finder’s statement we were able to reconstruct the original context and re-localize the exact finding place.

  4. Bronze Sacrificial Ware and Ancient Chinese Culture of Sorcery%青铜礼器与巫史文化

    Institute of Scientific and Technical Information of China (English)

    王永钊

    2002-01-01

    青铜礼器是以祭祀祖先为核心、具有浓厚宗教性质的巫史文化的代表.它以狰狞的美叙述了奴隶制度下的人类社会如火烈烈的历史.青铜礼器以其独具风格的崇高美的魅力成为人类文化绝无仅有的遗产.

  5. Environmental Influences on Elite Sport Athletes Well Being: From Gold, Silver, and Bronze to Blue Green and Gold.

    Science.gov (United States)

    Donnelly, Aoife A; MacIntyre, Tadhg E; O'Sullivan, Nollaig; Warrington, Giles; Harrison, Andrew J; Igou, Eric R; Jones, Marc; Gidlow, Chris; Brick, Noel; Lahart, Ian; Cloak, Ross; Lane, Andrew M

    2016-01-01

    This paper considers the environmental impact on well-being and performance in elite athletes during Olympic competition. The benefits of exercising in natural environments are recognized, but less is known about the effects on performance and health in elite athletes. Although some Olympic events take place in natural environments, the majority occur in the host city, usually a large densely populated area where low exposure to natural environments is compounded by exposure to high levels of air, water, and noise pollution in the ambient environment. By combining methods and expertise from diverse but inter-related disciplines including environmental psychology, exercise physiology, biomechanics, environmental science, and epidemiology, a transdisciplinary approach will facilitate a greater understanding of the effects of the environment on Olympic athletes. PMID:27540370

  6. Ungueal Morphology and Pathology of the human mummy found in the Val Senales (Eastern Alps, Tyrol, Bronze Age.

    Directory of Open Access Journals (Sweden)

    Luigi Capasso

    1994-01-01

    Full Text Available El autor describe una lámina de uña perteneciente a un dedo de la, actualmente bien conocida, momia de Val Senales. La uña había quedado separada del resto en tiempos antiguos y fue recuperada en el curso de la excavación arqueológica llevada a cabo en el área en agosto de 1992. Esta lámina de uña (hallazgo nº 168/92, es de un enorme interés desde el punto de vista paleopatológico. Varias lesiones destructivas concentradas sobre parte de la región distal de la superficie dorsal de la uña parecen ser atribuibles, tanto por su tipología (onicorrexis y microsurcos como por su topografía, a   microtraumas que tuvieron lugar en el transcurso de la vida del sujeto, como resultado de la utilización de la uña como instrumento. Además, la presencia de tres grupos de líneas de Beau-Reil nos ha   permitido determinar la gravedad, tiempo de ataques o arremetidas y duración de tres periodos de intensa tensión que el sujeto experimentó durante los últimos meses de su vida. El sujeto sufrió tres de dichos episodios, que tuvieron lugar cuatro, tres y dos meses antes de su muerte. El último episodio fue el más serio, y el trastorno sistemático que produjo duró al menos dos semanas.

  7. The haematological profile of female bronze turkeys (Meleagris gallopavo vaccinated with various commercial strains of Newcastle disease

    Directory of Open Access Journals (Sweden)

    Elizabeth M.d.S. Schmidt

    2014-02-01

    Full Text Available The effects of vaccination on avian blood parameters are poorly understood. The present study was designed to evaluate whether different strains (Ulster 2C, B1, live LaSota and inactivated LaSota of Newcastle disease vaccines had an effect on the haematological profile of female turkeys. Seventy-five female turkeys were allocated to treatment groups according to vaccination strain. All the birds, except those in the control group, were vaccinated at 32 weeks of age and revaccinated at 40 and 48 weeks of age. Blood samples were obtained for haematological analyses and serum samples for the haemagglutination inhibition test. Haemoglobin concentration was significantly lower (p < 0.05 in vaccinated female turkeys than in the control birds 28 days after vaccination. Monocytes were significantly higher (p < 0.05 in 44-week-old female turkeys vaccinated with inactivated LaSota strain compared with the other groups. Turkeys vaccinated with the B1 strain showed significantly higher (p < 0.05 total white blood cell counts compared with the other groups vaccinated with various commercial strains of the Newcastle disease virus. In conclusion, female turkeys showed significant differences in haemoglobin concentrations, monocytes and white blood cell counts when vaccinated against Newcastle disease.

  8. The haematological profile of female bronze turkeys (Meleagris gallopavo) vaccinated with various commercial strains of Newcastle disease.

    Science.gov (United States)

    Schmidt, Elizabeth M d S; Santos, Ivan F C; Paulillo, António C; Martins, Gislaine R V; Denadai, Janine; Lapela, Ivan M

    2014-08-25

    The effects of vaccination on avian blood parameters are poorly understood. The present study was designed to evaluate whether different strains (Ulster 2C, B1, live LaSota and inactivated LaSota) of Newcastle disease vaccines had an effect on the haematological profile of female turkeys. Seventy-five female turkeys were allocated to treatment groups according to vaccination strain. All the birds, except those in the control group, were vaccinated at 32 weeks of age and revaccinated at 40 and 48 weeks of age. Blood samples were obtained for haematological analyses and serum samples for the haemagglutination inhibition test. Haemoglobin concentration was significantly lower (p < 0.05) in vaccinated female turkeys than in the control birds 28 days after vaccination. Monocytes were significantly higher (p < 0.05) in 44-week-old female turkeys vaccinated with inactivated LaSota strain compared with the other groups. Turkeys vaccinated with the B1 strain showed significantly higher (p < 0.05) total white blood cell counts compared with the other groups vaccinated with various commercial strains of the Newcastle disease virus. In conclusion, female turkeys showed significant differences in haemoglobin concentrations, monocytes and white blood cell counts when vaccinated against Newcastle disease.

  9. BRONZE, ZINC, ALUMINUM, GALVANIZED STEEL: CORROSION RATES AS A FUNCTION OF SPACE AND TIME OVER THE UNITED STATES

    Science.gov (United States)

    A data base of existing metal corrosion data has been compiled by the National Bureau of Standards. The data base contains only exposure studies that were conducted according to standard ASTM procedures and had adequate documentation of the site characteristics and period of expo...

  10. An influence of solids and processing on physical and mechanical properties of materials on the basis of porous bronze

    OpenAIRE

    Аскеров, Мукафат Гейбат

    2015-01-01

    Выполнены исследования влияния твердых включений - порошков нержавеющей стали, стеллита, ферроборхрома и ультрадисперсного углеродного конденсата и дополнительной технологической обработки на механические свойства материалов на основе оловянистой бронзы БрО10. Показано, что наличие твердых включений в сочетании с технологической обработкой существенно повышает свойства пористой бронзы. Установлено, что наиболее высокие значения прочности достигаются при содержании включений 30 %. Research ...

  11. Emission of organic compounds from mould and core binders used for casting iron, aluminium and bronze in sand moulds

    DEFF Research Database (Denmark)

    Tiedje, Niels Skat; Crepaz, Rudolf; Eggert, Torben;

    2010-01-01

    Emissions from mould and core sand binders commonly used in the foundry industry have been investigated. Degradation of three different types of binders was investigated: Furfuryl alcohol (FA), phenolic urethane (PU) and resol-CO2 (RC). In each group of binders at least two different binder...

  12. The events around the "Bronze Soldier" in the main Russian (language) newspapers of Estonia / Maria Radzhabova, Dominika Laidinen, Olga Pridotchenko

    Index Scriptorium Estoniae

    Radzhabova, Maria

    2008-01-01

    Artiklis analüüsitakse, kuidas kajastasid Eestis ilmuvad venekeelsed ajalehed Postimees : на русском языке, Молодежъ Эстонии ja Вести Дня sündmuseid, mis eelnesid ja järgnesid pronkssõduri teisaldamisele

  13. Breakthrough of the Nordic Bronze Age: Transcultural warriorhood and a Carpathian crossroad in the 16th century BC

    DEFF Research Database (Denmark)

    Vandkilde, Helle

    2014-01-01

    ) and in the northern zone (rock). In a Carpathian crossroad between the Eurasian Steppes, the Aegean world and temperate Europe during this time, a transcultural assemblage coalesced, fusing both tangible and intangible innovations from various different places. Superior warriorhood was coupled to beliefs...... momentous creativity that drew upon Carpathian originals, contacts and a pool of Carpathian ideas, but ultimately drawing on emergent Mycenaean hegemonies in the Aegean. This provided the incentive for a cosmology-rooted resource from which the NBA could take its starting point....

  14. Atypical coastal environmental change during Copper Age - Bronze Age transition (Rio de Moinhos, NW Portugal) - preliminary results

    Science.gov (United States)

    Granja, Helena; Danielsen, Randi

    2015-04-01

    The research is part of an ongoing project of geo-archaeology from Rio de Moinhos beach (Esposende, NW Portugal), where an extensive area of dark sedimentary outcrops and a large amount of ceramic remains from a Roman shipwreck are present. The dark sedimentary deposit, presenting tree stumps and roots in life position, partially covers a rocky platform that extends seawards. Over the platform, that presents many pits of sea urchins (infralittoral environment) as well as salt pans (supratidal environment), a marine rusty conglomerate is present in some places. Several hand gauge cores were extracted in the sedimentary deposit whose maximum depth do not exceed 50cm. Samples from cores and outcrops were analysed for grain size, mineralogical composition, pollen and diatom content and radiocarbon dated. This work concerns sediment size analysis, dating and pollen. Tree stumps and roots of Alnus glutinosa dated 6310-6220 cal BP are in the base of the sedimentary sequence that presents a gradual passage from very fine sands to clayey silts, all of them organic and very poorly sorted. Pollen analysis revealed an initial wetland habitat containing Alnus, inundated ca 5645-5585 cal BP due to rising sea level at the time. A brackish lagoon formed at the site presumably protected by a clastic barrier seaward. Similar formations of lagoons are detected all along the Portuguese coast, typically disappearing with time due to sand infilling. In this case, however, the brackish lagoon turned into a fresh water lake ca 4485-4440 cal BP. This may have been a natural development caused by permanent closing of the clastic barrier but human interference cannot be excluded as anthropic activity was detected since formation of the lagoon. The lake seems to have filled in with sand at some point in time subsequent to ca 3750-3725 cal BP, the date of the top lake sediment. However, shipwreck vestiges from the Roman Period presently dispersed over the lake sediment, suggests a later date for its infilling. Furthermore dating of wooden remains of what was interpreted as a fish trap, found on the sediment surface gave the age 2055-1770 cal BP (Roman Period). The old age of the top level may hence be the result of truncation of the sediment sequence at least in parts of the platform. Landwards, the Roman period is represented by fine and dark sediments similar to those of Rio de Moinhos beach, found in deeper cores. Acknowledgments This research is included in the project PTDC/EPH-ARQ/5204/2012 supported by FCT (Foundation for Science and Technology, Portugal). It is financed also by COMPETE and PEsT-C/MAR/LA0015/2013.

  15. Environmental Influences on Elite Sport Athletes Well Being: From Gold, Silver, and Bronze to Blue Green and Gold

    Science.gov (United States)

    Donnelly, Aoife A.; MacIntyre, Tadhg E.; O’Sullivan, Nollaig; Warrington, Giles; Harrison, Andrew J.; Igou, Eric R.; Jones, Marc; Gidlow, Chris; Brick, Noel; Lahart, Ian; Cloak, Ross; Lane, Andrew M.

    2016-01-01

    This paper considers the environmental impact on well-being and performance in elite athletes during Olympic competition. The benefits of exercising in natural environments are recognized, but less is known about the effects on performance and health in elite athletes. Although some Olympic events take place in natural environments, the majority occur in the host city, usually a large densely populated area where low exposure to natural environments is compounded by exposure to high levels of air, water, and noise pollution in the ambient environment. By combining methods and expertise from diverse but inter-related disciplines including environmental psychology, exercise physiology, biomechanics, environmental science, and epidemiology, a transdisciplinary approach will facilitate a greater understanding of the effects of the environment on Olympic athletes.

  16. Environmental Influences on Elite Sport Athletes Well Being: From Gold, Silver, and Bronze to Blue Green and Gold

    Science.gov (United States)

    Donnelly, Aoife A.; MacIntyre, Tadhg E.; O’Sullivan, Nollaig; Warrington, Giles; Harrison, Andrew J.; Igou, Eric R.; Jones, Marc; Gidlow, Chris; Brick, Noel; Lahart, Ian; Cloak, Ross; Lane, Andrew M.

    2016-01-01

    This paper considers the environmental impact on well-being and performance in elite athletes during Olympic competition. The benefits of exercising in natural environments are recognized, but less is known about the effects on performance and health in elite athletes. Although some Olympic events take place in natural environments, the majority occur in the host city, usually a large densely populated area where low exposure to natural environments is compounded by exposure to high levels of air, water, and noise pollution in the ambient environment. By combining methods and expertise from diverse but inter-related disciplines including environmental psychology, exercise physiology, biomechanics, environmental science, and epidemiology, a transdisciplinary approach will facilitate a greater understanding of the effects of the environment on Olympic athletes. PMID:27540370

  17. Gold, Silver, and Bronze: Determining National Success in Men’s and Women’s Summer Olympic Events

    OpenAIRE

    Eva Marikova Leeds; Michael A. Leeds

    2012-01-01

    We add to the literature on Olympic performance by explicitly studying the determinants of women’s performance at the Games.We estimate separatemodels ofmedal production formen and women over the last four Summer Olympic Games. The production of medals is a function of capital, labor, and total factor productivity (TFP). We use real GDP per capita and population – two variables that appear in almost all Olympic studies – as proxies for capital and labor. Our measure of TFP is a vector of vari...

  18. Large geomagnetic field anomalies revealed in Bronze to Iron Age archeomagnetic data from Tel Megiddo and Tel Hazor, Israel

    Science.gov (United States)

    Shaar, Ron; Tauxe, Lisa; Ron, Hagai; Ebert, Yael; Zuckerman, Sharon; Finkelstein, Israel; Agnon, Amotz

    2016-05-01

    Geomagnetic field measurements from the past few centuries show heightened secular variation activity in the southern hemisphere associated with the south Atlantic anomaly (SAA). It is uncertain whether geomagnetic anomalies at a similar scale have existed in the past owing to limited coverage and uncertainties in the paleomagnetic database. Here we provide new evidence from archaeological sources in the Levant suggesting a large positive northern hemisphere anomaly, similar in magnitude to the SAA during the 9th-8th centuries BCE, called "Levantine Iron Age anomaly". We also report an additional geomagnetic spike in the 8th century. The new dataset comprises 73 high precision paleointensity estimates from ca. 3000 BCE to 732 BCE, and five directional measurements between the 14th and the 9th centuries BCE. Well-dated pottery and cooking ovens were collected from twenty archaeological strata in two large contemporaneous stratigraphical mounds (tells) in Israel: Tel Megiddo and Tel Hazor. The new data are combined with previously published data and interpreted automatically using the PmagPy Thellier GUI program. The Tel Megiddo and Tel Hazor data sets demonstrate excellent internal consistency and remarkable agreement with published data from Mesopotamia (Syria). The data illustrate the evolution of an extreme geomagnetic high that culminated in at least two spikes between the 11th and the 8th centuries BCE (Iron Age in the Levant). The paleomagnetic directional data of the 9th century BCE show positive inclination anomalies, and deviations of up to 22° from the averaged geocentric axial dipole (GAD) direction. From comparison of the Levantine archaeomagnetic data with IGRF model for 2015 we infer the "Levantine Iron Age anomaly" between the 10th and the 8th centuries BCE is a local positive anomaly. The eastward extent of the anomaly is currently unknown.

  19. Laser ablation cleaning of an underwater archaeological bronze spectacle plate from the H.M.S. DeBraak shipwreck

    Science.gov (United States)

    Dajnowski, Bartosz A.

    2013-05-01

    Laser ablation was successfully used to sequentially remove layers of concretion and corrosion from the surface of a copper alloy spectacle plate from the shipwreck of His Majesty's Sloop of War DeBraak. The H.M.S. DeBraak was a single-masted cutter that was originally a Dutch ship until it was taken by the British, refitted, and repurposed as a Royal Navy ship in 1796. The ship sank along the Delaware coast in 1798 and artifacts were recovered from the wreck site in 1984. This spectacle plate is an important part of the ships rudder and it is part of the collection of the Delaware Division of Historical and Cultural Affairs. The object was brought the Winterthur/University of Delaware Program in Art Conservation for treatment. The object was examined with cross section microscopy, Raman spectroscopy, X-ray fluorescence spectroscopy (XRF), and Energy Dispersive Spectroscopy (EDS) as well as Back Scattered Electron (BSE) analysis with a Scanning Electron Microscopy (SEM). Interestingly, layers of both copper and iron corrosion products were identified within the concretion. A 1064nm Long Q-Switch (LQS) laser with 100ns pulses was tested along with a Short Free Running (SFR) with 60 - 130 microseconds pulses, at various fluences and frequencies, to determine optimal cleaning parameters for removing the concretion. Laser cleaning also revealed fragments of wood from the original rudder, which were previously trapped within the concretion. After laser cleaning, the spectacle plate was treated with 3% Benzotriazole in ethanol and then given a protective microcrystalline wax coating.

  20. Environmental influences on Elite Sport Athletes Well Being: From Gold, Silver and Bronze to Blue Green and Gold

    Directory of Open Access Journals (Sweden)

    Aoife A. Donnelly

    2016-08-01

    Full Text Available This paper considers the environmental impact on well-being and performance in elite athletes during Olympic competition. The benefits of exercising in natural environments are recognised, but less is known about the effects on performance and health in elite athletes. Although some Olympic events take place in natural environments, the majority occur in the host city, usually a large densely populated area where low exposure to natural environments is compounded by exposure to high levels of air, water and noise pollution in the ambient environment. By combining methods and expertise from diverse but inter-related disciplines including environmental psychology, exercise physiology, biomechanics, environmental science and epidemiology, a transdisciplinary approach will facilitate a greater understanding of the effects of the environment on Olympic athletes.

  1. Reconstruction of settlement phases at Intermediate Bronze Age structures in the Negev Highlands (Israel) using luminescence dating

    Science.gov (United States)

    Junge, Andrea; Lomax, Johanna; Shahack-Gross, Ruth; Dunseth, Zachary C.; Finkelstein, Israel; Fuchs, Markus

    2016-04-01

    OSL dating is usually applied to sediments in paleoenvironmental sciences. However, there is only limited experience with determining the age of archaeological stone structures by OSL using dust deposits associated with these structures. The age of trapped dust deposits may be used to date the onset of settlement (sediment below structures), settlement activity (occupation layer), or the time after settlement (sediment between collapsed walls and roofs). In this study, OSL dating is applied for establishing a chronology of settlement structures situated in the Negev Highlands, Israel. Two archaeological sites are investigated to identify the occupation history, by dating the aeolian dust trapped within the remains of ancient buildings. OSL dating techniques are applied using coarse grain quartz and a standard SAR protocol. First results indicate that the luminescence properties of the trapped sediments are suitable for OSL dating. Therefore, it was possible to date the onset of sedimentation in a later phase of the human occupation or shortly after the settlement was abandoned, which is supported by archaeological evidence gained from pottery finds and the architecture of the buildings.

  2. Surface hardening characteristics of aluminium bronze for marine propeller; Senpaku propeller yo aluminium seido no hyomen koka tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Kawazoe, T. [Nagasaki University, Nagasaki (Japan). Faculty of Engineering; Furukawa, T.; Kanda, K.; Nishikido, S. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan)

    1997-05-25

    With a marine propeller material AlBC3 as the object of discussion, three kinds of surface hardening tests and a cavitation erosion test were carried out to investigate the relationship among hardenability, microstructures and erosion resistance. Surface hardness of each hardened material was found about 1.5 times greater for water-sprayed flame hardening, about 1.6 times greater for laser hardening, and about 1.3 times greater for high-frequency hardening than that of as-cast materials. The hardness is closely related with the microstructures. In the flame hardening, a hard ({beta}+{beta}prime) phase is distributed in a great quantity on the surface, and the occupying ratio of a soft {alpha} phase increases as the depth increases. In the laser hardening, a micronized {beta} phase is distributed all over the surface, contributing to increase in the surface hardness. Weight loss in the flame-hardened materials due to erosion has stayed at about 35% of that for as-cast materials, showing improvement in the erosion resistance. If the surface hardening process verified by the present test is applied to production propellers, the water-sprayed flame hardening process is thought most suitable when the surface hardness, hardened layer thickness and workability are considered. 8 refs., 17 figs., 4 tabs.

  3. THE RELATIONSHIP BETWEEN EGYPT AND PALESTINE IN THE EARLY BRONZE AGE(ca.3400-2000 BCE)

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The relationship between Egypt and Palestine can be traced back to theChalcolithic Age thanks to the evidence of current excavations in the Nile Deltaand Sinal.Palestinian pottery and cast metal objects from the Delta sites of Maadi,Minshat Abu Omar,and elsewhere have proved contacts with Palestine inProtodynastic(Nagada Ⅱ-Ⅲ)times.The Egyptian Protodynastic Period andDynasty 1 were contemporary with the Palestinian EB Ⅰ and EB Ⅲ,and reliable

  4. Chemical and mineralogical alteration of ceramics from a Late Bronze Age kiln at Kommos, Crete: the effect on the formation of a reference group

    OpenAIRE

    Buxeda i Garrigós, Jaume; Kilikoglou, V; Day, P.M.

    2001-01-01

    The formation of reference groups comprises an important procedure in chemical provenance studies of archaeological pottery. Material from ancient kilns is thought to be especially suitable for reference groups, as it comprises a definite unit of past production. Pottery from the Late Minoan IA kiln excavated at Kommos, Crete was analysed in order to produce a reference group in this important area of Minoan ceramic production. The samples were characterized by a combination of techniques pro...

  5. Density-dependent growth and metamorphosis in the larval bronze frog Rana temporalis is influenced by genetic relatedness of the cohort

    Indian Academy of Sciences (India)

    S Girish; S K Saidapur

    2003-06-01

    Effects of density and kinship on growth and metamorphosis in tadpoles of Rana temporalis were studied in a 2 × 4 factorial experiment. Fifteen egg masses were collected from streams in the Western Ghat region of south India. The tadpoles were raised as siblings or in groups of non-siblings at increasing density levels, viz. 15, 30, 60 and 120/5 l water. With an increase in density level from 15 to 120 tadpoles/5 l water, duration of the larval stage increased and fewer individuals metamorphosed irrespective of whether they belonged to sibling or non-sibling groups by day 100 when the experiments were terminated. The size of individuals at metamorphosis declined significantly with increase in the density of rearing. However, at higher densities (60 and 120 tadpoles/5 l water) sibling group tadpoles performed better compared to mixed groups and took significantly less time to metamorphose. Also, more individuals of sibling groups metamorphosed compared to non-sibling groups at a given density. Mixed rearing retarded growth rates, prolonged larval duration resulting in a wider spectrum of size classes, and lowered the number of individuals recruited to terrestrial life. The study shows that interference competition occurred more strongly in cohorts of mixed relatedness than in sibling groups.

  6. A new clue for investigating the origin of asymmetrical bronze axes%有关不对称形铜钺起源问题的新线索

    Institute of Scientific and Technical Information of China (English)

    豆海锋; 刘莲芳

    2010-01-01

    不对称形铜钺是流行于我国南方地区东周至汉代的一种重要的青铜锋刃器,以往学者们对该类器的起源提出了多种不同的看法.本文在前人研究的基础上,通过对中原地区西周遗存中刃部不对称形铜斧的比较分析,提出不对称形铜钺存在多种来源的可能.

  7. mtDNA from the early Bronze Age to the Roman period suggests a genetic link between the Indian subcontinent and Mesopotamian cradle of civilization.

    Directory of Open Access Journals (Sweden)

    Henryk W Witas

    Full Text Available Ancient DNA methodology was applied to analyse sequences extracted from freshly unearthed remains (teeth of 4 individuals deeply deposited in slightly alkaline soil of the Tell Ashara (ancient Terqa and Tell Masaikh (ancient Kar-Assurnasirpal Syrian archaeological sites, both in the middle Euphrates valley. Dated to the period between 2.5 Kyrs BC and 0.5 Kyrs AD the studied individuals carried mtDNA haplotypes corresponding to the M4b1, M49 and/or M61 haplogroups, which are believed to have arisen in the area of the Indian subcontinent during the Upper Paleolithic and are absent in people living today in Syria. However, they are present in people inhabiting today's Tibet, Himalayas, India and Pakistan. We anticipate that the analysed remains from Mesopotamia belonged to people with genetic affinity to the Indian subcontinent since the distribution of identified ancient haplotypes indicates solid link with populations from the region of South Asia-Tibet (Trans-Himalaya. They may have been descendants of migrants from much earlier times, spreading the clades of the macrohaplogroup M throughout Eurasia and founding regional Mesopotamian groups like that of Terqa or just merchants moving along trade routes passing near or through the region. None of the successfully identified nuclear alleles turned out to be ΔF508 CFTR, LCT-13910T or Δ32 CCR5.

  8. Mollusc-based paleoecological investigations of the Late Copper — Early Bronze Age earth mounds (kurgans) on the Great Hungarian Plain

    Science.gov (United States)

    Szilágyi, Gábor; Sümegi, Pál; Molnár, Dávid; Sávai, Szilvia

    2013-12-01

    The malacological material of the mound bodies (kurgans) of the Great Hungarian Plain indicates a mixed vegetation of dry and humid environments, developed on a mosaic of alkaline and chernozem soils in the period of the construction of the kurgan. The malacofauna that evolved in the upper soil horizon of the mound indicates the extremely dry environmental conditions of steppes, charaterized by the dominance of thermoxerophilous species. Dominant species of this kurgan are Chondrula tridens, Helicopsis striata, Granaria frumentum and Cepaea vindobonensis. The species composition shows that there are differences in the malacofauna of the Danube-Tisa Interfluves region compared to that of the lowlands east of River Tisza, indicated by the higher dominance of Granaria frumentum and Helicopsis striata in the former region. Following the construction of the kurgans an island-like, dry habitat developed on their surface, covered by black soil and populated by a steppe fauna, the composition of which is comparable mostly with the mollusc fauna of loess steppes and forest steppe, irrespectively of the floodplain or wind-blown sand character of the original surface.

  9. Molecular archaeology: Export of Dead Sea asphalt to Canaan and Egypt in the Chalcolithic-Early Bronze Age (4th-3rd millennium BC)

    Science.gov (United States)

    Connan, Jacques; Nissenbaum, Arie; Dessort, Daniel

    1992-07-01

    Nine archaeological bitumens from excavations in Canaan, Sinai and Egypt (Tel Irani, Ein Zik, Palmahim, Tel Arad, Jerusalem, Ein Besor-Site H, Sheik Awad and Maadi), dated 3900-2200 Bc. And two natural asphalts of the Dead Sea area (Ein Gedi floating blocks and Nahal Heimar) have been compared using the following geochemical techniques: chloroform extraction and GC and GC-MS analyses of C 15+ alkanes and C 15+ aromatics, isotopic analysis (δ 13C and δD) on chloroform extracts and asphaltenes and Rock-Eval pyrolysis of the insoluble organic residue. All samples are genetically related and are different from other archaeological bitumens from Syria and Iraq. Tel Irani archaeological bitumen was found to be identical to the floating block asphalts of the Dead Sea. Other archaeological bitumens were recognized as having been weathered and biodegraded to various degrees at archaeological sites in the course of the millennia. They are regarded as counterparts of floating block asphalts altered by aging. This study is the first evidence of the trade and export of raw bitumens from the Dead Sea area within Canaan and to Egyptian trading centers on the mainland route to Egypt between 3900 and 2200 BC, prior to the extensive utilization of bitumen for mummification in ancient Egypt.

  10. Neutron diffraction study of the atomic structure of cubic sodium-tungsten bronze (Na0.69WO3) single crystal

    International Nuclear Information System (INIS)

    The atomic structure of a single crystal of one of four Na0.69WO3 phases, which exist below 293 K, has been refined from neutron diffraction data (WWR-c reactor at the Karpov Institute of Physical Chemistry, Obninsk Branch; λ = 1.168 Å; λ/2 contribution −1). The Na0.69WO3 atomic structure has been refined (198 independent reflections) taking into account the anisotropy of thermal vibrations (Rw = 4.0%). The stoichiometric coefficient Na(0.69) is also refined. A structural distortion is revealed, which is characterized by the displacement of oxygen atoms (0, 0.2609(2), 0.2391(2)) from the ideal perovskite positions (0, 1/4, 1/4); this displacement doubles the ideal perovskite lattice period. The oxygen displacements can be described as rotations of oxygen octahedra by 3.58° around the [111] direction. The structure remains cubic because the octahedra rotations with respect to all three perovskite cubic axes are identical.

  11. Wild carnivore and wild bird deposits in an agro-pastoral community during the Bronze Age: Can Roqueta II (northeast Iberian Peninsula

    Directory of Open Access Journals (Sweden)

    Albizuru, S., Maroto, J., Nadal, J., Majó, T., Sánchez Marco, A., Carlús, X., Rodríguez, A., Palomo, A.

    2015-01-01

    En este caso la identificación taxonómica indica la importancia de los animales domésticos seguramente debido a su papel en la economía, así como su uso en ofrendas alimentarias y también en ofrendas simbólicas que manifiestan el estatus de los muertos. Por el contrario, el estudio tafonómico indica la escasez de animales salvajes depositados intencionalmente –seis aves y dos carnívoros– y muestra el uso diferencial de estas especies respecto a las domésticas, ya que mientras los animales importantes en la alimentación humana fueron normalmente dispuestos como ofrendas de comida para los difuntos, los animales salvajes parecen estar más estrechamente relacionados con símbolos de la vida o totémicos.

  12. Key Points of Melting Quality Control of RECo-Chromium Bronze%一种RECo铬青铜熔炼质量控制要点

    Institute of Scientific and Technical Information of China (English)

    苏义祥; 刘兴寿; 陈改革; 吕松涛; 霍吉平; 王立坤

    2015-01-01

    研究了一种新型RECo铬青铜材料在非真空状态下的熔炼质量控制要点,配置了合金熔炼覆盖洁净溶剂,详细介绍了合金熔炼过程中单质金属的预热温度、加料次序、控制要点、炉前宏观含气量及弯角检验方法,考察了合金的金相组织缺陷等.

  13. Élaboration d'un bronze Cu-8%Sn fritté sous pression et l'étude de son aptitude à l'absorption

    Science.gov (United States)

    Loucif, K.; Keraghel, F.; Alem, S.

    2005-05-01

    L'introduction des píeces miniatures dans le domaine de l'informatique et la microélectronique nécessite une grande précision et un environnement propre. D'autre part, la conservation d'énergie exige des pièces légères et une bonne longévité. Pour résoudre ces problèmes, des pièces autolubrifiées ont été proposées. En effet, plusieurs disciplines peuvent s'ingérer pour élaborer ces pièces: la métallurgie des poudres pour produire des pièces poreuses, la tribologie pour caractériser la pièce en fonctionnement et la mécanique des fluides pour évaluer le comportement échantillon -lubrifiant.
Dans ce présent travail, nous présentons l'évolution de la densité des échantillons élaborés en fonction de: la température d'élaboration, la pression de compactage, et le temps de maintien et l'évolution de l'absorption des lubrifiants par un alliage Cu-8% Sn fritté sous pression. Les lubrifiants choisis sont l'eau et une huile de machine à usage domestique et leur aptitude à l'autolubrification.

  14. mtDNA from the early Bronze Age to the Roman period suggests a genetic link between the Indian subcontinent and Mesopotamian cradle of civilization.

    Science.gov (United States)

    Witas, Henryk W; Tomczyk, Jacek; Jędrychowska-Dańska, Krystyna; Chaubey, Gyaneshwer; Płoszaj, Tomasz

    2013-01-01

    Ancient DNA methodology was applied to analyse sequences extracted from freshly unearthed remains (teeth) of 4 individuals deeply deposited in slightly alkaline soil of the Tell Ashara (ancient Terqa) and Tell Masaikh (ancient Kar-Assurnasirpal) Syrian archaeological sites, both in the middle Euphrates valley. Dated to the period between 2.5 Kyrs BC and 0.5 Kyrs AD the studied individuals carried mtDNA haplotypes corresponding to the M4b1, M49 and/or M61 haplogroups, which are believed to have arisen in the area of the Indian subcontinent during the Upper Paleolithic and are absent in people living today in Syria. However, they are present in people inhabiting today's Tibet, Himalayas, India and Pakistan. We anticipate that the analysed remains from Mesopotamia belonged to people with genetic affinity to the Indian subcontinent since the distribution of identified ancient haplotypes indicates solid link with populations from the region of South Asia-Tibet (Trans-Himalaya). They may have been descendants of migrants from much earlier times, spreading the clades of the macrohaplogroup M throughout Eurasia and founding regional Mesopotamian groups like that of Terqa or just merchants moving along trade routes passing near or through the region. None of the successfully identified nuclear alleles turned out to be ΔF508 CFTR, LCT-13910T or Δ32 CCR5. PMID:24040024

  15. Highly efficient ablation of metastatic breast cancer using ammonium-tungsten-bronze nanocube as a novel 1064 nm-laser-driven photothermal agent.

    Science.gov (United States)

    Guo, Chongshen; Yu, Haijun; Feng, Bing; Gao, Weidong; Yan, Mei; Zhang, Zhiwen; Li, Yaping; Liu, Shaoqin

    2015-06-01

    Photothermal ablation (PTA) therapy has been viewed as an invasive option for cancer therapy with minimal deconstruction of healthy tissues. In this study, a potent candidate of (NH4)xWO3 nanocube was developed for PTA treatment of metastatic breast cancer in the second near-infrared (NIR) window. It was found that the as-synthesized (NH4)xWO3 nanocube had significant photoabsorption across the whole NIR window of 780-2500 nm and exhibited considerable photo-heat conversion efficiency. Moreover, the as-prepared (NH4)xWO3 nanocube displayed good biocompatibility and high cellular uptake efficiency through endocytosis pathway without nuclei entry. The PTA study employing 1064 nm laser in the second NIR window revealed that (NH4)xWO3 nanocubes induced significant cell necrosis and apoptosis by producing obviously hyperthermia effect inside cancer cells. Using an orthotopicly implanted breast tumor model, it demonstrated that the (NH4)xWO3 nanocube was a promising photothermal agent for effective ablation of solid tumors and suppressing their distant metastasis. PMID:25818447

  16. Pyrophosphate complexation of tin(II) in aqueous solutions as applied in electrolytes for the deposition of tin and tin alloys such as white bronze.

    Science.gov (United States)

    Buchner, Magnus R; Kraus, Florian; Schmidbaur, Hubert

    2012-08-20

    Electrodeposition of tin and tin alloys from electrolytes containing tin(II) and pyrophosphates is an important process in metal finishing, but the nature of the tin pyrophosphate complexes present in these solutions in various pH regions has remained unknown. Through solubility and pH studies, IR and (31)P and (119)Sn NMR spectroscopic investigations of solutions obtained by dissolving Sn(2)P(2)O(7) in equimolar quantities of either Na(4)P(2)O(7)·10H(2)O or K(4)P(2)O(7) the formation of anionic 1:1 complexes {[Sn(P(2)O(7))]}(n)(2n-) has now been verified and the molecular structures of the monomer (n = 1) and the dimer (n = 2) have been calculated by density functional theory (DFT) methods. Whereas the alkali pyrophosphates Na/K(4)P(2)O(7) give strongly alkaline aqueous solutions (pH ∼13), because of partial protonation of the [P(2)O(7)](4-) anion, the [Sn(P(2)O(7))](2-) anion is not protonated and the solutions of Na/K(2)[Sn(P(2)O(7))] are almost neutral (pH ∼8). The monomeric dianion appears to have a ground state with C(2v) symmetry with the Sn atom in a square pyramidal coordination and the lone pair of electrons in the apical position, while the dimer approaches C(2) symmetry with the Sn atoms in a rhombic pyramidal coordination, also with a sterically active lone pair. A comparison of experimental and calculated IR details favors the monomer as the most abundant species in solution. With an excess of pyrophosphate, 3:2 and 2:1 complexes (P(2)O(7)):(Sn) are first formed, which, in the presence of more pyrophosphate, undergo rapid ligand exchange on the NMR time scale. The structure of the 2:1 complex [Sn(P(2)O(7))(2)](6-) was calculated to have a pyramidal complexation by two 1,5-chelating pyrophosphate ligands. Neutralization of these alkaline solutions by sulfuric or sulfonic acids (H(2)SO(4), MeSO(3)H), as also practiced in electroplating, appears to afford the tin(II) hydrogen pyrophosphates [Sn(P(2)O(7)H)](-) and [Sn(H(2)P(2)O(7))](0). The molecular structures of the mononuclear model units have also been calculated and were shown to have an unsymmetrical complexation and to feature trigonal pyramidal (pseudotetrahedral) coordination. NMR observations have shown that, contrary to the results obtained for Sn(II) compounds, Sn(IV) as present in K(2)SnO(3) or its hydrated form (K(2)Sn(OH)(6)) does not form a pyrophosphate complex in aqueous solution near pH 7. There is also no interference of sulfite. PMID:22857614

  17. Study of hydrogen in coals, polymers, oxides, and muscle water by nuclear magnetic resonance; extension of solid-state high-resolution techniques. [Hydrogen molybdenum bronze

    Energy Technology Data Exchange (ETDEWEB)

    Ryan, L.M.

    1981-10-01

    Nuclear magnetic resonance (NMR) spectroscopy has been an important analytical and physical research tool for several decades. One area of NMR which has undergone considerable development in recent years is high resolution NMR of solids. In particular, high resolution solid state /sup 13/C NMR spectra exhibiting features similar to those observed in liquids are currently achievable using sophisticated pulse techniques. The work described in this thesis develops analogous methods for high resolution /sup 1/H NMR of rigid solids. Applications include characterization of hydrogen aromaticities in fossil fuels, and studies of hydrogen in oxides and bound water in muscle.

  18. SIMA法制备的ZCuSn10锡青铜的等轴晶组织%Preparation of ZCuSn10 Tin Bronze with Equiaxed Grain Structure by Strain Induced Melt Activation (SIMA) Process

    Institute of Scientific and Technical Information of China (English)

    王佳; 肖寒; 吴龙彪; 卢德宏; 周荣锋; 周荣

    2014-01-01

    采用SIMA法制备了ZCuSn10锡青铜等轴晶试样,然后进行450℃保温15 min后自由锻或室温2道次、4道次轧制,最后在800℃和850℃保温10 min后水淬处理.将SIMA法制备的合金组织与铸态直接重熔保温后水淬和常规退火处理的ZCuSn10锡青铜组织进行了比较.结果表明,采用SIMA法能获得共析组织不超过16%的ZCuSn10锡青铜等轴晶组织,相比常规退火及铸态直接重熔工艺,其平均晶粒直径从250~300 um减小到80~90 um,形状因子从1.97减小到1.75;用SIMA法制备ZCuSn10锡青铜等轴晶组织,预变形过程对晶粒细化及球化起到了关键作用,随着预变形量和重熔保温温度提高,ZCuSn10锡青铜组织晶粒尺寸减小,圆整度提高,共析组织比例增加.

  19. 从三星堆青铜神树到金沙太阳神鸟%From the Holy BronzeTree in Sanxingdui to the Holy Bird in Jinsha Site

    Institute of Scientific and Technical Information of China (English)

    刘道军

    2006-01-01

    金沙遗址文化作为三星堆遗址文化的继承与发展,集中体现在出土器物上.作为三星堆遗址与金沙遗址出土的典型器物--"青铜神树"和金箔"太阳神鸟",则分别是这两种遗址文化的突出代表.二者之间既有区别,又有联系;有继承,也有发展.

  20. 光电直读光谱法测定锡青铜中9种杂质元素%Determinatiaon of Nine Elements in Tin Bronze by Photoelectric Direct-reading Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    程婧娴; 罗舜

    2014-01-01

    利用光电直读光谱仪快速测定了锡青铜中的9种杂质元素,通过调整工作曲线及其它影响测定的因素,最终确定了锡青铜的最佳分析条件,方法的相对标准偏差RSD为0.33%~4.4%,对标准样品的实际测定结果与标准值基本一致,精密度与准确度均能满足日常分析需求.

  1. THE ASTRONOMICALLY ORIENTED MEGALITHS OF THE MONTE JATO AREA (SICILY): THE “CAMPANARU”, THE “PERCIATA” AND THE ENEOLITHIC/EARLY BRONZE AGE WORSHIP SITE OF PIZZO PIETRALUNGA

    OpenAIRE

    Scuderi, A.; Polcaro, V. F.; Mercadante, F.; Lo Cascio1. P.; Maurici, F.

    2013-01-01

    An imposing megalith is visible from many kilometres of distance near the top of the hill named Monte Arcivocalotto (Sicily). It is made by a single sandstone slab, shaped in triangular form with a large circular hole pierced at the centre. It is known to local people as U Campanaru (“The Bell Tower”) and it was considered as a magic place until recently. The megalith is oriented toward the sunrise of the winter solstice, when the Sun rises at the hole centre, becoming visible fro...

  2. Enhancement of Sinter Densification of SrO-BaO-Nb2O5-SiO2 Tungsten-Bronze Glass-Ceramics by Doping with P2O5

    Institute of Scientific and Technical Information of China (English)

    J.C.Chen; Y.Zhang

    2013-01-01

    Densification behaviors of SrO-BaO-Nb2O5-SiO2 based glass-ceramics prepared by conventional sintering were investigated with an emphasis on the influence of P2O5 content.Although P2O5 dopant did not modify the surface crystallization mechanism,it resulted in a decrease of the glass transition temperature,which facilitates the viscous glass flow necessary for sintering.However,premature crystallization of (Sr,Ba)Nb2O6 induced by addition of excess amount of P2O5 essentially retarded sintering due to the formation of closed pores in the matrix.The SrO-BaO-Nb2O5-SiO2 glass with 1.0 mol% P2O5 (SBN-1P) showed the best sinter densification,which was accomplished at about 850 ℃.

  3. 韩国金海良洞出土西汉铜鼎续考%A New Study of the Bronze Tripod of the Western Han in Liang Cave, Jinhai, Korea

    Institute of Scientific and Technical Information of China (English)

    李学勤

    2002-01-01

    韩国东义大学博物馆从1990年11月起,在庆尚南道金海市良洞里的伽倻古墓群进行发掘。其第三次发掘系由1993年9月开始,至1994年1月结束,所掘332号土圹木椁墓,属于公元3世纪前半叶,却出有一件有铭文的西汉青铜鼎。当时有韩国学者把鼎铭照片电传给我看,汉城的《东亚日报》也作了报道。据此我写了一篇小文,

  4. The Decorative Art of the Bronze Ware in the Early Shang Dynasty and a Probe into the Mercantile Ideology%早商青铜器装饰艺术与商人的思想观念探析

    Institute of Scientific and Technical Information of China (English)

    杨远; 朱光华

    2006-01-01

    随着考古发现的增多,早商青铜器的研究逐渐涉及商代社会方方面面,正所谓"透物见人".早商青铜器的丰富造型、华丽装饰,蕴涵着那个时代人们复杂的宗教、政治、审美等思想观念.

  5. 一种含纳米粒子的烧结青铜机械密封材料%One Type of Bronze Sintering Material Containing Nanoparticles for Mechanical Seal

    Institute of Scientific and Technical Information of China (English)

    尹克里; 陈广志; 陈真炎; 田玉清

    2007-01-01

    采用放电等离子体烧结工艺研制了一种含石墨、镍和氧化铝纳米粒子的青铜自润滑复合材料,并对其力学、摩擦学及加工性能进行了研究.实验结果表明:纳米石墨粒子成网状分布,使材料脆化;纳米粒子起到了预期的活化烧结及抗磨效果;用该材料制成的动密封环通过了1 000 h以上的台架考核.

  6. 一种智能PID控制器在铍青铜热处理中的应用%Application of an Intelligent PID Controller in Beryllium-bronze Heat Treatment

    Institute of Scientific and Technical Information of China (English)

    薛凌云; 谢建精

    2005-01-01

    针对常规PID控制参数多是离线人工整定,且一次性整定的PID参数难以保证其控制效果始终处于最佳状态等缺陷,依据专家经验,模仿人类思维,通过辨识系统响应的瞬态特征,提出了一种智能PID控制方法,确定PID控制时系统加速、"刹车"、还是保持,以修正不同阶段的控制作用,改善常规PID控制性能.仿真结果及该方法在铍青铜热处理炉温控制系统中的应用表明,专家经验和传统PID控制的结合既保持了PID控制简捷、可靠,又提高了控制器性能,有实际应用价值.

  7. A Through Introduction and Interpretation to the West Zhou's Bronze Utensil "Gui in Memory of the Xing's Marquis"%西周青铜器"邢侯簋"通释

    Institute of Scientific and Technical Information of China (English)

    杨文山

    2002-01-01

    "邢侯簋"为西周青铜器邢器之一,铭文内容涉及到周王对邢侯的"迁封",是研究西周邢国封建的重要材料.本文除对"邢侯簋"进行通释外,结合有关金文资料和文献记载,就邢国"迁封"有争议的若干历史问题进行了考述.

  8. A Through Introduction and Interpretation to West Zhou's Bronze Utensil"Gui in Memory of Xing's Marquis"(Continued)%西周青铜器"邢侯簋"通释(下)

    Institute of Scientific and Technical Information of China (English)

    杨文山

    2005-01-01

    "邢侯簋"为西周青铜器邢器之一,铭文内容涉及到周王对邢侯的"迁封",是研究西周邢国封建的重要材料.对"邢侯簋"进行通释,并结合有关金文资料和文献记载,就邢国"迁封"有争议的若干历史问题进行了考述.

  9. Preliminary study of slags and slaggy layers on ceramics from the Bronze Age metallurgical site of Peñalosa (Baños de la Encina, Jaén

    Directory of Open Access Journals (Sweden)

    Moreno Onorato, Auxilio

    2010-12-01

    Full Text Available This paper offers a revision of the metallurgical processes carried out at the settlement on the basis of a recent analytical study of slags and slagged metallurgical ceramics. These analyses allowed us to identify the ores processed and the characteristics of this metal production. Therefore, the results obtained provide new perspectives to determining what type of technology was developed and the working conditions of the different processes carried out at the site. In this sense, the use of lead-rich copper ores stands out in explaining the presence of high quantities of lead compounds detected in various metallurgical ceramics and in secondary products, like slags and melting wastes. The present study also includes typological and technological analysis of metallurgical ceramic vessels.

    Este trabajo ofrece una revisión de los procesos metalúrgicos llevados a cabo en el asentamiento I, de acuerdo con los resultados del reciente estudio analítico realizado sobre los restos de escorias y escorificaciones de cerámicas metalúrgicas. A partir de estos análisis, que nos permiten la identificación de los minerales procesados y de las características de la producción metálica obtenida, se aportan nuevas perspectivas para determinar el tipo de tecnología desarrollada y las condiciones en las que se llevaron a cabo los diferentes procesos. En este sentido destaca la utilización de minerales de cobre muy ricos en plomo, que proporcionan altas cantidades de compuestos de plomo en las vasijas cerámicas y en productos secundarios como escorias y restos de fundición. Se completa el estudio con el análisis de la tipología y tecnología de las vasijas cerámicas de uso metalúrgico.

  10. Transdisciplinar study of the EE1 pit of the Cova Colomera (Prepyrenean Lleida: domestic practices and palaeoenvironmental implications in the early Bronze Age of the Northeast of the Iberian Peninsula

    Directory of Open Access Journals (Sweden)

    Oms, F. Xavier

    2009-06-01

    Full Text Available The transdisciplinary study of the EE1 pit of the Cova Colomera has provided a group of data that can bring some important information about the domestic and economical practices developed in the cave and also about the paleoenvironmental characteristics of this area of the Northeast of the peninsula during the third to second millennia cal. BC. The data show that this cave was used by small groups of people with a mixed farming economy, who also had recourse to mobile activities to complete their diet. Moreover, some structures dug in the floor of the cavity were dug by these groups and went out of use during their short stays in the Cova Colomera. The functionality of these structures is discussed in this article. They could have used them to store surpluses and later to contain refuse or to remove the domestic waste.

    El estudio transdisciplinar de la fosa EE1 de la Cova Colomera ha proporcionado un conjunto de datos que aportan importante información sobre las prácticas domésticas y económicas desarrolladas en ella, y sobre las características paleoambientales de esta zona del noreste peninsular en el tránsito III-II milenio cal. AC. Los resultados apuntan a que esta cueva fue ocupada por grupos reducidos, con una economía mixta agropecuaria, que recurrían también a actividades cinegéticas para completar su dieta. En sus cortas estancias en la Cova Colomera, crearon y amortizaron estructuras excavadas en el suelo de la cavidad, como la fosa EE1, bien para almacenar excedentes y después desechar basura, o bien para eliminar residuos de origen doméstico.

  11. 《金文编》附录后成字的图形文字再释%A Re-interpretation of the Pictographs in the Appendix to the Collection of Bronze Inscriptions Characters

    Institute of Scientific and Technical Information of China (English)

    白冰

    2008-01-01

    依据商代甲骨文、西周金文对早期金文"图形文字"进行考察、辨析,可以认定某些图形为氏族徽号,某些图形表示一种生活场景,某些图形后来发展为文字.其中,( )(何)、( )(伐)、( )(重)、( )(卿)、( )( )(竝併並并)、( )(虎)、( )(豕)、( )(牛)、( )羊、( )(崬)等便属于第三类.

  12. 胶印连线冷烫胶水黏度与印刷适性分析%Analysis of Viscosity and Printability of Cold Bronzing Glue Used in Offset Line

    Institute of Scientific and Technical Information of China (English)

    官燕燕; 叶义成

    2013-01-01

    胶印连线冷烫胶水的黏度和印刷适性影响冷烫的质量.通过实验分析了胶印连线冷烫胶水的黏度和印刷适性,设计了胶印连线冷烫测试版,通过上机测试得到了胶印连线冷烫的工艺参数.研究结果能为胶印连线冷烫胶水的选用与冷烫印刷工艺参数的确定提供参考.

  13. Friction and wear of titanium alloys and copper alloys sliding against titanium 6-percent-aluminum - 4-percent-vanadium alloy in air at 430 C

    Science.gov (United States)

    Wisander, D. W.

    1976-01-01

    Experiments were conducted to determine the friction and wear characteristics of aluminum bronzes and copper-tin, titanium-tin, and copper-silver alloys sliding against a titanium-6% aluminum-4% vanadium alloy (Ti-6Al-4V). Hemispherically tipped riders of aluminum bronze and the titanium and copper alloys were run against Ti-6Al-4V disks in air at 430 C. The sliding velocity was 13 cm/sec, and the load was 250 g. Results revealed that high tin content titanium and copper alloys underwent significantly less wear and galling than commonly used aluminum bronzes. Also friction force was less erratic than with the aluminum bronzes.

  14. 40 CFR 60.130 - Applicability and designation of affected facility.

    Science.gov (United States)

    2010-07-01

    ... in secondary brass or bronze production plants: Reverberatory and electric furnaces of 1,000 kg (2205 lb) or greater production capacity and blast (cupola) furnaces of 250 kg/h (550 lb/h) or greater production capacity. Furnaces from which molten brass or bronze are cast into the shape of finished...

  15. Cloth in the Cult

    DEFF Research Database (Denmark)

    Nosch, Marie-Louise Bech; Perna, Massimo

    2000-01-01

    The paper investigates cloth in the Bronze Age cult in Greece and disusses its function. There is a seperation between cloth for offerings and cloth for cult personnel......The paper investigates cloth in the Bronze Age cult in Greece and disusses its function. There is a seperation between cloth for offerings and cloth for cult personnel...

  16. 78 FR 25337 - Culturally Significant Object Imported for Exhibition

    Science.gov (United States)

    2013-04-30

    ... Culturally Significant Object Imported for Exhibition Determinations: ``Bronze Statue of a Boxer, Hellenistic..., 2003), I hereby determine that the object to be included in the exhibition ``Bronze Statue of a Boxer, Hellenistic Period,'' imported from abroad for temporary exhibition within the United States, is of...

  17. Nacre biomimetic design—A possible approach to prepare low infrared emissivity composite coatings

    International Nuclear Information System (INIS)

    Mimicking the highly organized brick-and-mortar structure of nacre, a kind of nacre-like organic–inorganic composite material of polyurethane (PU)/flaky bronze composite coatings with low infrared emissivity was successfully designed and prepared by using PU and flaky bronze powders as adhesives and pigments, respectively. The infrared emissivity and microstructure of the coatings were systematically investigated by infrared emissometer and scanning electron microscopy, respectively, and the cause of low infrared emissivity of the coatings was discussed by using the theories of one-dimensional photonic structure. The results show that the infrared emissivity of the nacre-like PU/flaky bronze composite coatings can be as low as 0.206 at the bronze content of 60 wt. %, and it is significantly lower than the value of PU/sphere bronze composite coatings. Microstructure observation illustrated that the nacre-like PU/flaky bronze composite coatings have similar one-dimensional photonic structural characteristics. The low infrared emissivity of PU/flaky bronze composite coatings is derived from the similar one-dimensional photonic structure in the coatings. Highlights: ► Nacre-like composite coatings with low infrared emissivity were prepared. ► Infrared emissivity of PU/flaky bronze composite coatings can be as low as 0.206. ► One-dimensional photonic structure is the cause for low emissivity of the coatings.

  18. Nacre biomimetic design-A possible approach to prepare low infrared emissivity composite coatings

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Weigang, E-mail: abczwg15@163.com; Xu, Guoyue; Ding, Ruya; Duan, Kaige; Qiao, Jialiang

    2013-01-01

    Mimicking the highly organized brick-and-mortar structure of nacre, a kind of nacre-like organic-inorganic composite material of polyurethane (PU)/flaky bronze composite coatings with low infrared emissivity was successfully designed and prepared by using PU and flaky bronze powders as adhesives and pigments, respectively. The infrared emissivity and microstructure of the coatings were systematically investigated by infrared emissometer and scanning electron microscopy, respectively, and the cause of low infrared emissivity of the coatings was discussed by using the theories of one-dimensional photonic structure. The results show that the infrared emissivity of the nacre-like PU/flaky bronze composite coatings can be as low as 0.206 at the bronze content of 60 wt. %, and it is significantly lower than the value of PU/sphere bronze composite coatings. Microstructure observation illustrated that the nacre-like PU/flaky bronze composite coatings have similar one-dimensional photonic structural characteristics. The low infrared emissivity of PU/flaky bronze composite coatings is derived from the similar one-dimensional photonic structure in the coatings. Highlights: Black-Right-Pointing-Pointer Nacre-like composite coatings with low infrared emissivity were prepared. Black-Right-Pointing-Pointer Infrared emissivity of PU/flaky bronze composite coatings can be as low as 0.206. Black-Right-Pointing-Pointer One-dimensional photonic structure is the cause for low emissivity of the coatings.

  19. Physiological characteristics of an aging Olympic athlete

    DEFF Research Database (Denmark)

    Nybo, Lars; Schmidt, Jakob Friis; Fritzdorf, Stephen;

    2014-01-01

    To investigate the physiological basis of continued world-class performance of a world-class rower who won medals (3 gold and 2 bronze) at five consecutive Olympic Games.......To investigate the physiological basis of continued world-class performance of a world-class rower who won medals (3 gold and 2 bronze) at five consecutive Olympic Games....

  20. “妇好”鸮尊(英文)

    Institute of Scientific and Technical Information of China (English)

    王玮

    2000-01-01

    In traditional Chinese folk wisdom, the owlis deemed as an omen of coming disaster. However, three thousand years ago, people regarded the owl as sacred and the embodiment of power. This is evidenced in the multiude of pottery, jade and bronze owls, which are slowly being excavated. This bronze, owl-shaped wine goblet, inscribed with the characters "Fu Hao", is a beautiful example.