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Sample records for boiler soot blowers

  1. Optimum geometry for boiler soot blowers nozzles; Geometria optima de toberas para deshollinadores de caldera

    Energy Technology Data Exchange (ETDEWEB)

    Espinoza Garza, Jesus; Garcia Tinoco, Guillermo J.; Martinez Flores, Jose Oscar [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1989-12-31

    For boiler soot blowing converging-diverging nozzles are employed, whose function is to convert thermal energy of a gas into kinetic energy to remove the deposits that adhere to the heat exchanger surfaces. In this paper are described the experimental equipment and the methods for flow, dynamic pressure, discharge velocity and air expansion factor calculation in each nozzle, as a function of its design geometry, utilizing air from a five stage centrifugal compressor. The graphic analysis of the results, concludes that the most efficient nozzles are not the ones than develop the greatest velocity, but the ones of highest dynamic pressure at the outlet. The nozzle geometry that allows obtaining the maximum dynamic air pressure at the discharge is A{sub 2}/A{sub g}=1.3676 [Espanol] Para el deshollinado de calderas se utilizan las toberas convergentes-divergentes, cuya funcion es convertir la energia termica de un gas en energia cinetica para remover los depositos que se adhieren a las superficies de intercambio de calor. En este trabajo se describen el equipo experimental y los metodos de calculo para flujo, presion dinamica, velocidad a la descarga y factor de expansion del aire en cada tobera, como funcion de su geometria de diseno. Durante la experimentacion se evaluaron siete disenos diferentes de toberas, empleando aire de un compresor centrifugo de cinco etapas. Del analisis grafico de los resultados, se concluye que las toberas mas eficientes no son las que desarrollan mayor velocidad sino las de mayor presion dinamica de la salida. La geometria de tobera que permite obtener la maxima presion dinamica del aire a la descarga es A{sub 2}/A{sub g} = 1.3676.

  2. Optimization in the design and efficiency of retractable soot blowers; Optimacion del diseno y la eficiencia de sopladores de hollin retractiles

    Energy Technology Data Exchange (ETDEWEB)

    Diego Marin, Antonio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1987-12-31

    In this article the importance of soot blowers in the subject of design, operation and maintenance are described and the effects that its inefficient functioning causes in the steam generators. The activities and the results of a project for the evaluation of the functioning of the soot blowers in the Comision Federal de Electricidad (CFE) boilers. Finally, the scope of a new project oriented towards the retractable soot blowers efficiency optimization, and to the creation of the infra-structure to substitute the import of its components. [Espanol] En este articulo se describe la importancia de los sopladores de hollin en los aspectos de diseno, operacion y mantenimiento, y los efectos que su funcionamiento deficiente produce en los generadores de vapor. Se presentan tambien las actividades y los resultados de un proyecto para evaluar el funcionamiento de los deshollinadores de las calderas de la Comision Federal de Electricidad (CFE). Finalmente, se presenta el alcance de un nuevo proyecto que se orienta a optimar la eficiencia de los sopladores de hollin retractiles y a crear la infraestructura para sustituir las importaciones de sus componentes.

  3. Characterization and quantification of deposits build up and removal in straw suspension fired boilers. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Arendt Jensen, Peter; Wedel, S.; Jappe Frandsen, F.; Dam-Johansen, K.; Shafique Bashir, M. [Technical Univ. of Denmark. CHEC Research Centre, Kgs. Lyngby (Denmark); Wadenback, J.; Thaaning Pedersen, S. [Vattenfall A/S, Copenhagen (Denmark)

    2013-07-15

    This project deals with ash deposit formation in suspension fired biomass power plant boilers. The project has been conducted in a tight collaboration between Vattenfall and the CHEC Research Centre at DTU Department of Chemical Engineering. A large part of the project has been performed by conducting advanced probe measurements at the Amagervaerkets Vattenfall owed boilers. It was the objective of the project to provide an improved understanding of ash deposit formation and removal in biomass suspension fired boilers. The project have provided a large amount of knowledge on the following issues: 1) The influence of local boiler conditions on deposit formation in suspension fired boilers using wood or co-firing straw and wood, 2) quantification of deposit removal in biomass suspension firing boilers with regards both to natural shedding and soot blower induced shedding, 3) established relations of the properties of fuel ash, fly ash and deposits, 4) use of coal ash to remedy biomass ash induced boiler deposit problems. (Author)

  4. Needs-driven soot blowing in waste boilers; Behovsstyrd sotblaasning i avfallspannor

    Energy Technology Data Exchange (ETDEWEB)

    Niklasson, Fredrik; Davidsson, Kent

    2009-09-15

    The increased use of alternative and waste fuels has resulted in an increased number of plants having trouble with fouling and corrosion on boiler banks and superheater tubes. Frequent sootblowing will keep the surfaces relatively clean, but on the other hand, it may erode the tube material. An intelligent sootblowing system will initiate sootblowings on individual tube banks only when needed for that specific tube bank. Such a system depends on the detection of the degree of fouling of specific tube banks. In this project, the conditions for an intelligent sootblowing system at the waste fired boilers in Boraas are investigated from measured flows, temperatures and pressure drop. New thermocouples at the water tubes between the banks of the economiser have been installed and connected to the control and monitoring system of the boiler. From measured temperatures and flows, heat transfer coefficients are calculated and used to detect the fouling on the heat exchangers. A pressure transducer has been altered to measure the pressure over the boiler bank. At the superheaters, the measurements show a significant improvement of the heat transfer coefficients immediately following sootblowing. Thereafter, the heat transfer coefficients decline more slowly, almost linearly. The measurements indicate that the fouling rate is almost same for the two superheaters and do not motivate individual sootblowing sequences of the two superheaters. The pressure drop over the boiler bank was found too insensitive a measure to be used as an indicator for an intelligent sootblowing system, at least in this specific boiler. In the economiser, the decline of calculated heat transfer coefficients showed a relative rate of fouling on individual tube banks. The results show that the fouling rate is significantly higher in the top tube banks, which comes first in the direction of the flue gas, compared to downstream banks. Experiments by sootblowing the top tube bank more frequently than the

  5. Characterization and quantification of deposits build up and removal in straw suspension fired boilers

    DEFF Research Database (Denmark)

    Jensen, Peter Arendt; Shafique Bashir, Muhammad; Wedel, Stig

    This project deals with ash deposit formation in suspension fired biomass power plant boilers. The project has been conducted in a tight collaboration between Vattenfall and the CHEC Research Centre at DTU Department of Chemical Engineering. A large part of the project has been performed by condu......This project deals with ash deposit formation in suspension fired biomass power plant boilers. The project has been conducted in a tight collaboration between Vattenfall and the CHEC Research Centre at DTU Department of Chemical Engineering. A large part of the project has been performed...... by conducting advanced probe measurements at the Amagerværkets Vattenfall owed boilers. It was the objective of the project to provide an improved understanding of ash deposit formation and removal in biomass suspension fired boilers. The project have provided a large amount of knowledge on the following issues......: 1) The influence of local boiler conditions on deposit formation in suspension fired boilers using wood or co-firing straw and wood, 2) quantification of deposit removal in biomass suspension firing boilers with regards both to natural shedding and soot blower induced shedding, 3) established...

  6. Evaluation of the behavior of shrouded plasma spray coatings in the platen superheater of coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Sidhu, B.S.; Prakash, S. [GZS College of Engineering & Technology, Bathinda (India). Dept. of Mechanical Engineering

    2006-06-15

    Nickel- and cobalt-based coatings were formulated by a shrouded plasma spray process on boiler tube steels, namely, ASTM-SA210-grade A1 (GrA1), ASTM-SA213-T-11 (T11), and ASTM-SA213-T-22 (T22). The Ni-22Cr-10A1-1Y alloy powder was sprayed as a bond in each case before the final coating. The degradation behavior of the bared and coated steels was studied in the platen superheater of the coal-fired boiler. The samples were inserted through the soot blower dummy points with the help of stainless steel wires. The coatings were found to be effective in increasing resistance to degradation in the given boiler environment. The maximum protection was observed in the case of Stellite-6 (St-6) coating.

  7. Fuel cell system blower configuration

    Energy Technology Data Exchange (ETDEWEB)

    Patel, Kirtikumar H.; Saito, Kazuo

    2017-11-28

    An exemplary fuel cell system includes a cell stack assembly having a plurality of cathode components and a plurality of anode components. A first reactant blower has an outlet situated to provide a first reactant to the cathode components. A second reactant blower has an outlet situated to provide a second reactant to the anode components. The second reactant blower includes a fan portion that moves the second reactant through the outlet. The second reactant blower also includes a motor portion that drives the fan portion and a bearing portion associated with the fan portion and the motor portion. The motor portion has a motor coolant inlet coupled with the outlet of the first reactant blower to receive some of the first reactant for cooling the motor portion.

  8. A simple FASTBUS blower

    International Nuclear Information System (INIS)

    Frisch, H.J.

    1986-01-01

    The trigger system for CDF is a hybrid analog-digital system physically based in 26 FASTBUS crates. Analog signals originate in the front end cards of the CDF detector components, and come upstairs on dedicated cables to the trigger crates. The cables emerge from the computer flooring in the counting room under the racks, and rise to the individual crates. For the photomultiplier-based calorimetry of the central detector, the cables come to the front panels of the cards. For the gas-based calorimetry, the cables are brought in through auxiliary cards plugged into the auxiliary connector behind the crates. The requirements of good access by these cables to the crates has made special requirements on the cooling system in these racks. In particular the cables preclude the use of large blowers which cover the bottom of the rack. Other requirements on the cooling system were low electrical noise (there is after all a very sensitive analog system in these racks), low audio noise, and a low height to conserve rack space. Rack space is of special concern not only for cable access, but because the analog system requires six different linear power supplies for each of the two crates per rack

  9. Design, Development and Analysis of Centrifugal Blower

    Science.gov (United States)

    Baloni, Beena Devendra; Channiwala, Salim Abbasbhai; Harsha, Sugnanam Naga Ramannath

    2017-05-01

    Centrifugal blowers are widely used turbomachines equipment in all kinds of modern and domestic life. Manufacturing of blowers seldom follow an optimum design solution for individual blower. Although centrifugal blowers are developed as highly efficient machines, design is still based on various empirical and semi empirical rules proposed by fan designers. There are different methodologies used to design the impeller and other components of blowers. The objective of present study is to study explicit design methodologies and tracing unified design to get better design point performance. This unified design methodology is based more on fundamental concepts and minimum assumptions. Parametric study is also carried out for the effect of design parameters on pressure ratio and their interdependency in the design. The code is developed based on a unified design using C programming. Numerical analysis is carried out to check the flow parameters inside the blower. Two blowers, one based on the present design and other on industrial design, are developed with a standard OEM blower manufacturing unit. A comparison of both designs is done based on experimental performance analysis as per IS standard. The results suggest better efficiency and more flow rate for the same pressure head in case of the present design compared with industrial one.

  10. VARIABLE SPEED INTEGRATED INTELLIGENT HVAC BLOWER

    Energy Technology Data Exchange (ETDEWEB)

    Shixiao Wang; Herman Wiegman; Wilson Wu; John Down; Luana Iorio; Asha Devarajan; Jing Wang; Ralph Carl; Charlie Stephens; Jeannine Jones; Paul Szczesny

    2001-11-14

    This comprehensive topical report discusses the key findings in the development of a intelligent integrated blower for HVAC applications. The benefits of rearward inclined blades over that of traditional forward inclined blades is well documented and a prototype blower design is presented. A comparison of the proposed blower to that of three typical units from the industry is presented. The design of the blower housing is also addressed and the impact of size limitations on static efficiency is discussed. Issues of air flow controllability in the rearward inclined blower is addressed and a solution to this problem is proposed. Several motor design options are discussed including inside-out radial flux designs and novel axial flux designs, all are focused on the various blower needs. The control of the motor-blower and airflow through the use of a high density inverter stage and modern digital signal processor is presented. The key technical challenges of the approach are discussed. The use of the motor as a sensor in the larger heating/ventilating system is also discussed. Diagnostic results for both the motor itself and the blower system are presented.

  11. Development and implementation of Intelligent Soot Blowing Optimization System for TNB Janamanjung

    Directory of Open Access Journals (Sweden)

    Sundaram Taneshwaren

    2017-01-01

    Full Text Available With an ever increasing demand for energy, Malaysia has become a nation that thrives on solid power generation sector to meet the energy demand and supply market. In a coal fired power plant, soot blowing operation is commonly used as a cleaning mechanism inside the boiler. There are many types of sequence available for this soot blowing operation. Hence, there is no efficient ways in utilizing the soot blowing operation to enhance the efficiency of boiler. Soot blowing optimization requires specific set of data preparation and simulation in order to achieve the best modal. Computational Fluid Dynamics (CFD is used to model a 700MW super-critical boiler, whereby parameters with effect to soot blowing operation is studied. Two different boiler condition is studied to analyze parameters in a clean and faulty boiler. Artificial Neural Network (ANN is used to train neural network modal with back propagation method to determine the best modal that will be used to predict soot blowing operation. Combination of neural network different number of neurons, hidden layers, training algorithm, and training functions is trained to find the modal with lowest error. By improving soot blowing sequence, efficiency of boiler can be improved by providing best parameter and model. This model is then used as a reference for advisory tool whereby a Neural Network Predictive Tool is suggested to the station to predict the soot blowing operation that occurs.

  12. Regenerative Blower for EVA Suit Ventilation Fan

    Science.gov (United States)

    Izenson, Michael G.; Chen, Weibo; Paul, Heather L.

    2010-01-01

    Portable life support systems in future space suits will include a ventilation subsystem driven by a dedicated fan. This ventilation fan must meet challenging requirements for pressure rise, flow rate, efficiency, size, safety, and reliability. This paper describes research and development that showed the feasibility of a regenerative blower that is uniquely suited to meet these requirements. We proved feasibility through component tests, blower tests, and design analysis. Based on the requirements for the Constellation Space Suit Element (CSSE) Portable Life Support System (PLSS) ventilation fan, we designed the critical elements of the blower. We measured the effects of key design parameters on blower performance using separate effects tests, and used the results of these tests to design a regenerative blower that will meet the ventilation fan requirements. We assembled a proof-of-concept blower and measured its performance at sub-atmospheric pressures that simulate a PLSS ventilation loop environment. Head/flow performance and maximum efficiency point data were used to specify the design and operating conditions for the ventilation fan. We identified materials for the blower that will enhance safety for operation in a lunar environment, and produced a solid model that illustrates the final design. The proof-of-concept blower produced the flow rate and pressure rise needed for the CSSE ventilation subsystem while running at 5400 rpm, consuming only 9 W of electric power using a non-optimized, commercial motor and controller and inefficient bearings. Scaling the test results to a complete design shows that a lightweight, compact, reliable, and low power regenerative blower can meet the performance requirements for future space suit life support systems.

  13. Emissions of soot particles from heat generators

    Science.gov (United States)

    Lyubov, V. K.; Popov, A. N.; Popova, E. I.

    2017-11-01

    «Soot carbon» or «Soot» - incomplete combustion or thermal decomposition particulate carbon product of hydrocarbons consisting of particles of various shapes and sizes. Soot particles are harmful substances Class 2 and like a dust dispersed by wind for thousands of kilometers. Soot have more powerful negative factor than carbon dioxide. Therefore, more strict requirements on ecological and economical performance for energy facilities at Arctic areas have to be developed to protect fragile Arctic ecosystems and global climate change from degradation and destruction. Quantity of soot particles in the flue gases of energy facilities is a criterion of effectiveness for organization of the burning process. Some of heat generators do not provide the required energy and environmental efficiency which results in irrational use of energy resources and acute pollution of environment. The paper summarizes the results of experimental study of solid particles emission from wide range of capacity boilers burning different organic fuels (natural gas, fuel oil, coal and biofuels). Special attention is paid to environmental and energy performance of the biofuels combustion. Emissions of soot particles PM2.5 are listed. Structure, composition and dimensions of entrained particles with the use of electronic scanning microscope Zeiss SIGMA VP were also studied. The results reveal an impact of several factors on soot particles emission.

  14. High temperature corrosion in biomass- and waste fired boilers. A status report; Kunskapslaeget betraeffande hoegtemperaturkorrosion i aangpannor foer biobraensle och avfall

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, P.; Ifwer, K.; Staalenheim, A.; Montgomery, M.; Hoegberg, J.; Hjoernhede, A.

    2006-12-15

    Many biomass- or waste-fired plants have problems with high temperature corrosion on the furnace walls or at the superheaters, especially if the steam temperature is greater than 500 deg C. An increase in the combustion of waste fuels means that an increasing number of boilers have had problems. Therefore, there is great interest from plant owners to reduce the costs associated with high temperature corrosion. At the same time there exists a considerable driving force towards improving the electrical efficiency of a plant by the use of more advanced steam data. The purpose of the work presented here was to answer three main questions: What can be done to reduce high temperature corrosion with current fuel blends and steam temperatures? How can more waste fuels be burnt without an increased risk for corrosion? What needs to be done to reach higher steam temperatures in the future? The level of knowledge of high temperature corrosion in biomass- and waste-fired boilers has been described and summarised. The following measures are recommended to reduce corrosion in existing plant: Make sure that the fuel is well mixed and improve fuel feeding to obtain a more even spread of the fuel over the cross-section of the boiler. Use combustion technology methods to stabilize the oxygen content of the flue gases near the membrane walls and other heat transfer surfaces. Experiment with additives and/or supplementary fuels which contain sulphur in some form, for example peat. Reduce the flue gas temperature at the superheaters. Review soot-blowing procedures or protect heat transfer surfaces from soot blowers. Evaluate coated membrane wall panels in parts of the furnace that experience the worst corrosion. Test more highly alloyed steels suitable for superheaters and when replacing a superheater change to a more highly alloyed steel. For the future, the following should be considered: The role of sulphur needs to be investigated more and other additives should be investigated

  15. Improved soot blowing, based on needs, using the mechanical characteristics of the steam pipe - stage 2; Foerbaettrad behovsstyrd sotning med hjaelp av vaermeoeverfoerande tubens mekaniska egenskaper - etapp 2

    Energy Technology Data Exchange (ETDEWEB)

    Blom, Elisabet; Fredoe, Claes; Gabrielsson, Lars; Eriksson, Daniel

    2011-10-15

    The detection of contamination of the boiler tubes through the tube mechanical properties has been studied. The project has carried out measurements and detection of three different boilers with different conditions in terms of sooting philosophy, combustion method and sooting method. The assembly of the detecting strain gauge takes place on a clip which is screwed and glued onto the tube.

  16. New controls spark boiler efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Engels, T. (Monsanto, University Park, IL (United States))

    1993-09-01

    Monsanto's NutraSweet plant in University Park, IL, produces aspartame, the patented NutraSweet artificial sweetener product. Until recently, boiler control was managed by a '60s-era Fireye jackshaft system in which air and natural gas were mechanically linked with an offset to compensate for oxygen trim. The interlocking devices on the Fireye system were becoming obsolete, and the boiler needed a new front end retrofitted for low emissions. In order to improve boiler control efficiency, we decided to modernize and automate the entire boiler control system. We replaced the original jackshaft system, and installed a Gordon-Piet burner system, including gas valves, air dampers, blowers, and burner. The upgrade challenges included developing a control strategy and selecting and implementing a process control system. Since our plant has standardized on the PROVOX process management information system from Fisher Controls (now Fisher-Rosemount Systems) to support most of our process, it was a natural and logical choice for boiler controls as well. 2 figs.

  17. Improved soot blowing, based on needs, through measurement of the natural frequency of the heat transferring tubes; Foerbaettrad behovsstyrd sotning genom maetning av oeverfoerande tubernas egenfrekvens

    Energy Technology Data Exchange (ETDEWEB)

    Blom, Elisabet; Ivarsson, Christofer

    2007-11-15

    The aim of the project is to develop a method for detecting soot on the transferring tubes by measuring the Eigen frequency of the tubes as a function of the soot deposit growth. The project is a pilot study independent of boiler type and it is applicable to all boilers where soot deposit on transferring tubes is a repeating issue. The report is supposed to answer two major questions. Is it possible to make use of Eigen frequencies in order to trace soot deposit on transferring tubes? What governing parameters are related to the Eigen frequency of transferring tubes? By today, soot blowing is executed after recommendations from the manufacturer in terms of number of soot blowing per time unit. The fuel type as well as boiler type has great influence on the soot deposit growth. The objective of the project is to investigate whether the mechanical properties of the transferring tube can be used to detect soot deposit. The project is divided into a theoretical and a practical part. The theoretical part covers the design of the probe and the change of its mechanical properties when soot deposit is present. Practical experiments were then carried out in a laboratory were the probes mechanical properties with and without soot deposit were investigated. It was shown that the Eigen frequency of the probe decreased with an increased mass due to soot deposit. A test was also made in a boiler at SAKAB but difficulties in attaching the probe to the inspection hatch. The results varied and the interpretation of the results become difficult. However, it was obvious that the mechanical properties of the probe changed with the amount of soot deposit. It was concluded that detection of soot deposit by studying the mechanical properties of the transferring tubes is possible. Yet, using a probe is no optimal solution, instead measurements should be done directly on the heat transferring tubes. In addition, a strategy for controlling the soot deposit has to be developed

  18. Production Facility Prototype Blower 1000 Hour Test Results

    Energy Technology Data Exchange (ETDEWEB)

    Woloshun, Keith Albert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dale, Gregory E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Romero, Frank Patrick [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dalmas, Dale Allen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-10-18

    The roots blower in use at ANL for in-beam experiments and also at LANL for flow tests was sized for 12 mm diameter disks and significantly less beam heating. Currently, the disks are 29 mm in diameter, with a 12 mm FWHM Gaussian beam spot at 42 MeV and 2.86 μA on each side of the target, 5.72 μA total. The target design itself is reported elsewhere. With the increased beam heating, the helium flow requirement increased so that a larger blower was needed for a mass flow rate of 400 g/s at 2.76 MPa (400 psig). An Aerzen GM 12.4 blower was selected, and is now installed at the LANL facility for target and component flow testing. Two extended tests of >1000 hr operation have been completed. Those results and discussion thereof are reported herein. Also included in Appendix A is the detailed description of the blower and its installation, while Appendix B documents the pressure vessel design analysis. The blower has been operated for 1000 hours as a preliminary investigation of long-term performance, operation and possible maintenance issues. The blower performed well, with no significant change in blower head or mass flow rate developed under the operating conditions. Upon inspection, some oil had leaked out of the shaft seal of the blower. The shaft seal and bearing race have been replaced. Test results and conclusions are in Appendix B.

  19. Production Facility Prototype Blower 1000 Hour Test Results II

    Energy Technology Data Exchange (ETDEWEB)

    Wass, Alexander Joseph [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Woloshun, Keith Albert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dale, Gregory E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dalmas, Dale Allen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Romero, Frank Patrick [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2018-01-08

    Long duration tests of the Aerzen GM 12.4 roots style blower in a closed loop configuration provides valuable data and lessons learned for long-term operation at the Mo-99 production facility. The blower was operated in a closed loop configuration with the flow conditions anticipated in plant operation with a Mo-100 target inline. The additional thermal energy generated from beam heating of the Mo-100 disks were not included in these tests. Five 1000 hour tests have been completed since the first test was performed in January of 2016. All five 1000 hour tests have proven successful in exposing preventable issues related to oil and helium leaks. All blower tests to this date have resulted in stable blower performance and consistency. A summary of the results for each test, including a review of the first and second tests, are included in this report.

  20. Dynamical system analysis of unstable flow phenomena in centrifugal blower

    Directory of Open Access Journals (Sweden)

    Garcia David

    2015-09-01

    Full Text Available Methods of dynamical system analysis were employed to analyze unsteady phenomena in a centrifugal blower. Pressure signals gathered at different control points were decomposed into their Principal Components (PCs by means of Singular Spectrum Analysis (SSA. Certain number of PCs was considered in the analysis based on their statistical correlation. Projection of the original signal onto its PCs allowed to draw the phase trajectory that clearly separated non-stable blower working conditions from its regular operation.

  1. Vibration and Stability of 3000-hp, Titanium Chemical Process Blower

    Directory of Open Access Journals (Sweden)

    Les Gutzwiller

    2003-01-01

    Full Text Available This 74-in-diameter blower had an overhung rotor design of titanium construction, operating at 50 pounds per square inch gauge in a critical chemical plant process. The shaft was supported by oil-film bearings and was directdriven by a 3000-hp electric motor through a metal disk type of coupling. The operating speed was 1780 rpm. The blower shaft and motor shaft motion was monitored by Bently Nevada proximity probes and a Model 3100 monitoring system.

  2. LES of Sooting Flames

    Science.gov (United States)

    2006-12-01

    investigated the formation of carbon in a well-stirred reactor. The critical C/O ratio for soot inception was observed and compared to Bunsen -Type flames ...The computations reproduced the flame structure, with reasonable agreement of the velocity field. They designed the swirl burner to match the...the vortex breakdown. 121 [203] introduced the compositional structure and flow field of two flames on the same burner . The two flames have the same

  3. 42 CFR 84.145 - Motor-operated blower test; minimum requirements.

    Science.gov (United States)

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Motor-operated blower test; minimum requirements... Supplied-Air Respirators § 84.145 Motor-operated blower test; minimum requirements. (a) Motor-operated... connection between the motor and the blower shall be so constructed that the motor may be disengaged from the...

  4. Energy efficiency in boilers; Eficiencia energetica em caldeiras

    Energy Technology Data Exchange (ETDEWEB)

    Ponte, Ricardo Silva The [Universidade Federal do Ceara (UFCE), Fortaleza, CE (Brazil). Dept. de Engenharia Eletrica], email: ricthe@dee.ufc.br; Barbosa, Marcos Antonio Pinheiro; Rufino, Maria da Gracas [Universidade de Fortaleza (UNIFOR), CE (Brazil). Dept. de Engenharia Eletrica], emails: marcos_apb@unifor.br, gsrufino@unifor.br

    2010-07-01

    The boiler is vapor generator equipment that has been widely used in industrial milieu as in electric energy generation in thermoelectric plants. Since their first conception, the boilers have been changed in order to provide security and energetic efficiency. They can present high losses of energy if they don't be operated according to some criteria. A considerable part of boilers operation cost include fuel expenses. So, the adoption of effective steps in order to reduce fuel consumption is important to industry economy, besides it brings environmental benefits through the reduction of pollution liberation. The present article has the objective of emphasizing the effective steps for the economy of energy in boilers, such as, the regulation of combustion; the control of soot and incrustations; the installation of economizers, air heaters and super heaters; the reduction in purges and reintroduction of condensed steam. (author)

  5. SEM Investigation of Superheater Deposits from Biomass-Fired Boilers

    DEFF Research Database (Denmark)

    Jensen, Peter Arendt; Frandsen, Flemming; Hansen, Jørn

    2004-01-01

    Straw is used as fuel in relatively small-scale combined heat and power producing (CHP) grate boilers in Denmark. The large content of potassium and chlorine in straw greatly increases the deposit formation and corrosion of the superheater coils, compared to boilers firing coal. In this study......, mature superheater deposit samples were extracted from two straw-fired boilers, Masnedø and Ensted, with fuel inputs of 33 MWth and 100 MWth, respectively. SEM (scanning electron microscopy) images and EDX (energy dispersive X-ray) analyses were performed on the deposit samples. Different strategies...... are adopted to minimize deposit problems at the two boilers. At Masnedø the final superheater steam temperature is 520 °C, no soot blowing of the superheaters is applied and a relatively large superheater area is used. At Ensted, an external wood-fired superheater is used in order to obtain a final steam...

  6. Maintenance free gas bearing helium blower for nuclear plant

    Science.gov (United States)

    Molyneaux, A., Dr; Harris, M., Prof; Sharkh, S., Prof; Hill, S.; de Graaff, T.

    2017-08-01

    This paper describes the design, testing and operation of novel helium blowers used to recirculate the helium blanketing gas in the nuclear reactor used as a neutron source at the Institut Laue Langevan, Grenoble, France. The laser sintered shrouded centrifugal wheel operates at speeds up to 45000 rpm supported on helium lubricated hydrodynamic spiral groove bearings, and is driven by a sensorless permanent magnet motor. The entire machine is designed to keep the helium gas (polluted by a small amount of D2O) out of contact with any iron or copper materials which would contribute to the corrosion of parts of the circuit. It is designed to have zero maintenance during a lifetime of 40,000 hours of continuous operation. This paper will describe the spiral groove journal and thrust bearings. Design and manufacture of the 1 kW motor and centrifugal wheel will be explained including their CFD and FEA analyses. Measurements of rotor displacement will be presented showing the behaviour under factory testing as well as details of the measured centrifugal wheel and motor performances. Two machines are incorporated into the circuit to provide redundancy and the first blower has been in continuous operation since Jan 2015. The blower was designed, manufactured, assembled and tested in the UK using predominantly UK suppliers.

  7. Ash fouling monitoring and key variables analysis for coal fired power plant boiler

    Directory of Open Access Journals (Sweden)

    Shi Yuanhao

    2015-01-01

    Full Text Available Ash deposition on heat transfer surfaces is still a significant problem in coal-fired power plant utility boilers. The effective ways to deal with this problem are accurate on-line monitoring of ash fouling and soot-blowing. In this paper, an online ash fouling monitoring model based on dynamic mass and energy balance method is developed and key variables analysis technique is introduced to study the internal behavior of soot-blowing system. In this process, artificial neural networks (ANN are used to optimize the boiler soot-blowing model and mean impact values method is utilized to determine a set of key variables. The validity of the models has been illustrated in a real case-study boiler, a 300MW Chinese power station. The results on same real plant data show that both models have good prediction accuracy, while the ANN model II has less input parameters. This work will be the basis of a future development in order to control and optimize the soot-blowing of the coal-fired power plant utility boilers.

  8. Gas-cooled reactor coolant circulator and blower technology

    International Nuclear Information System (INIS)

    1988-08-01

    In the previous 17 meetings held within the framework of the International Working Group on Gas-Cooled Reactors, a wide variety of topics and components have been addressed, but the San Diego meeting represented the first time that a group of specialists had been convened to discuss circulator and blower related technology. A total of 20 specialists from 6 countries attended the meeting in which 15 technical papers were presented in 5 sessions: circulator operating experience I and II (6 papers); circulator design considerations I and II (6 papers); bearing technology (3 papers). A separate abstract was prepared for each of these papers. Refs, figs and tabs

  9. Production Facility Prototype Blower Installation Report with 1000 Hour Test Results

    Energy Technology Data Exchange (ETDEWEB)

    Woloshun, Keith Albert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dale, Gregory E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Romero, Frank Patrick [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dalmas, Dale Allen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-04-01

    The roots blower in use at ANL for in-beam experiments and also at LANL for flow tests was sized for 12 mm diameter disks and significantly less beam heating. Currently, the disks are 29 mm in diameter, with a 12 mm FWHM Gaussian beam spot at 42 MeV and 2.86 μA on each side of the target, 5.72 μA total. The target design itself is reported elsewhere. With the increased beam heating, the helium flow requirement increased so that a larger blower was needed for a mass flow rate of 400 g/s at 2.76 MPa (400 psig). An Aerzen GM 12.4 blower was selected, and is currently being installed at the LANL facility for target and component flow testing. This report describes this blower/motor/pressure vessel package and the status of the facility preparations. The blower has been operated for 1000 hours as a preliminary investigation of long term performance, operation and possible maintenance issues. The blower performed well, with no significant change in blower head or mass flow rate developed under the operating conditions. Upon inspection, some oil had leaked out of the shaft seal of the blower. The shaft seal and bearing race have been replaced. Test results and conclusions are reported.

  10. Production Facility Prototype Blower Installation Report with 1000 Hr Test Results

    Energy Technology Data Exchange (ETDEWEB)

    Woloshun, Keith Albert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Olivas, Eric Richard [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dale, Gregory E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Romero, Frank Patrick [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dalmas, Dale Allen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-09-23

    The roots blower in use at ANL for in-beam experiments and also at LANL for flow tests was sized for 12 mm diameter disks and significantly less beam heating. Currently, the disks are 29 mm in diameter, with a 12 mm FWHM Gaussian beam spot at 42 MeV and 2.86 μA on each side of the target, 5.72 μA total. The target design itself is reported elsewhere. With the increased beam heating, the helium flow requirement increased so that a larger blower was needed for a mass flow rate of 400 g/s at 2.76 MPa (400 psig). An Aerzen GM 12.4 blower was selected, and is currently being installed at the LANL facility for target and component flow testing. This report describes this blower/motor/pressure vessel package and the status of the facility preparations. The blower has been operated for 1000 hours as a preliminary investigation of long-term performance, operation and possible maintenance issues. The blower performed well, with no significant change in blower head or mass flow rate developed under the operating conditions. Upon inspection, some oil had leaked out of the shaft seal of the blower. The shaft seal and bearing race have been replaced.

  11. Boundary model-based reference control of blower cooled high temperature polymer electrolyte membrane fuel cells

    DEFF Research Database (Denmark)

    Jensen, Hans-Christian Becker; Kær, Søren Knudsen

    2011-01-01

    life time of a fuel cell significantly. On air cooled HTPEMFCs, the blower, which supplies the fuel cell with oxygen for the chemical process, also functions as the cooling system. This makes the blower bi-functional and as a result a higher supply of oxygen is often available, hence changes...

  12. Boiler conversions for biomass

    Energy Technology Data Exchange (ETDEWEB)

    Kinni, J. [Tampella Power Inc., Tampere (Finland)

    1996-12-31

    Boiler conversions from grate- and oil-fired boilers to bubbling fluidized bed combustion have been most common in pulp and paper industry. Water treatment sludge combustion, need for additional capacity and tightened emission limits have been the driving forces for the conversion. To accomplish a boiler conversion for biofuel, the lower part of the boiler is replaced with a fluidized bed bottom and new fuel, ash and air systems are added. The Imatran Voima Rauhalahti pulverized-peat-fired boiler was converted to bubbling fluidized bed firing in 1993. In the conversion the boiler capacity was increased by 10 % to 295 MWth and NO{sub x} emissions dropped. In the Kymmene Kuusankoski boiler, the reason for conversion was the combustion of high chlorine content biosludge. The emissions have been under general European limits. During the next years, the emission limits will tighten and the boilers will be designed for most complete combustion and compounds, which can be removed from flue gases, will be taken care of after the boiler. (orig.) 3 refs.

  13. Pumping characteristics of roots blower pumps for light element gases

    International Nuclear Information System (INIS)

    Hiroki, Seiji; Abe, Tetsuya; Tanzawa, Sadamitsu; Nakamura, Jun-ichi; Ohbayashi, Tetsuro

    2002-07-01

    The pumping speed and compression ratio of the two-stage roots blower pumping system were measured for light element gases (H 2 , D 2 and He) and for N 2 , in order to assess validity of the ITER torus roughing system as an ITER R and D task (T234). The pumping system of an Edwards EH1200 (nominal pumping speed of 1200 m 3 /s), two EH250s (ibid. 250 m 3 /s) and a backing pump (ibid. 100 m 3 /s) in series connection was tested under PNEUROP standards. The maximum pumping speeds of the two-stage system for D 2 and N 2 were 1200 and 1300 m 3 /h, respectively at 60 Hz, which satisfied the nominal pumping speed. These experimental data support the design validity of the ITER torus roughing system. (author)

  14. Investigation of optical properties of aging soot

    Science.gov (United States)

    Migliorini, F.; Thomson, K. A.; Smallwood, G. J.

    2011-08-01

    The optical properties of soot, in particular the propensity of soot to absorb and scatter light as a function of wavelength, are key parameters for the correct interpretation of soot optical diagnostics. An overview of the data available in the literature highlights the differences in the reported optical properties of aging soot. In many cases, the properties of mature soot are used when evaluating in-flame soot but this assumption might not be suitable for all conditions and should be checked. This need has been demonstrated by performed spectral resolved line-of-sight attenuation (Spec-LOSA) measurements on an ethylene/air premixed and non-premixed flame. Transmission electron microscopy of thermophoretically sampled soot was also performed to qualify the soot aging and to establish soot morphology in order to correct light extinction coefficients for the scattering contribution. The measured refractive index absorption function, E( m) λ , showed a very strong spectral dependence which also varied with height above the burner for both flames. However, above 700 nm, the slope of the refractive index function was near zero for both flames and all measurement heights. The upper visible and near infrared wavelengths are therefore recommended for soot optical measurements.

  15. Electric utility CFB boilers

    International Nuclear Information System (INIS)

    Fairbanks, D.A.

    1991-01-01

    This paper reports on Circulating Fluidized Bed (CFB) boiler technology which caught the attention of boiler users: first for its technical advantages of reduced air emissions and low grade fuel tolerance, then later for its problems in becoming a reliable process. Refractory longevity and fuel feed reliability plagued a number of new installations. The efficacy of CFB technology is now more assured with the recent success of Texas-New Mexico Power Company's 160 MWe CFB based units, the world's largest operating CFB boilers. Most of the more notable CFB development problems have been successfully addressed by these units. The TNP units have demonstrated that CFB's can reliable produce high capacity factors at low emission rates using a fuel that has traditionally hampered the operation of pulverized coal (PC) boilers and without the attendant problems associated with sulfur scrubbers required by PC boilers

  16. Light Absorption By Coated Soot

    Science.gov (United States)

    Sedlacek, A. J.; Lee, J.; Onasch, T. B.; Davidovits, P.; Cross, E. S.

    2009-12-01

    The contribution of aerosol absorption on direct radiative forcing is still an active area of research, in part, because aerosol extinction is dominated by light scattering and, in part, because the primary absorbing aerosol of interest, soot, exhibits complex aging behavior that alters its optical properties. The consequences of this can be evidenced by the work of Ramanathan and Carmichael (2008) who suggest that incorporating the atmospheric heating due to brown clouds will increase black carbon (BC) radiative forcing from the IPCC best estimate of 0.34 Wm-2 (±0.25 Wm-2) (IPCC 2007) to 0.9 Wm-2. This noteworthy degree of the uncertainty is due largely to the interdependence of BC optical properties on particle mixing state and aggregate morphology, each of which changes as the particle ages in the atmosphere and becomes encapsulated within a coating of inorganic and/or organic substances. With the advent of techniques that can directly measure aerosol light absorption without influences due to collection substrate or light scattering (e.g., photoacoustic spectroscopy (Arnott et al., 2005; Lack et al., 2006) and photothermal interferometry (Sedlacek and Lee 2007)) the potential exists for quantifying this interdependence. In July 2008, a laboratory-based measurement campaign, led by Boston College and Aerodyne, was initiated to begin addressing this interdependence. To achieve this objective measurements of both the optical and physical properties of flame-generated soot under nascent, coated and denuded conditions were conducted. In this paper, light absorption by dioctyl sebacate (DOS) encapsulated soot and sulfuric acid coated soot using the technique of photothermal interferometry will be presented. In the case of DOS-coated soot, a monotonic increase in light absorption as a function DOS coating thickness to nearly 100% is observed. This observation is consistent with a coating-induced amplification in particle light absorption. (Bond et al. 2006) However

  17. Modelling maximum adsorption capacities of soot and soot-like materials for PAHs and PCBs

    NARCIS (Netherlands)

    Noort, van P.C.M.; Jonker, M.T.O.; Koelmans, A.A.

    2004-01-01

    Recent studies have shown that not partitioning but adsorption is the main mechanism for sorption of hydrophobic organic compounds to soot and soot-like materials. For compounds that adsorb by van der Waals forces only, variation in soot-water distribution coefficients will result from differences

  18. Dielectric properties of PMMA/Soot nanocomposites.

    Science.gov (United States)

    Clayton, Lanetra M; Cinke, Martin; Meyyappan, M; Harmon, Julie P

    2007-07-01

    Dielectric analysis (DEA) of relaxation behavior in poly(methyl methacrylate) (PMMA) soot nanocomposites is described herein. The soot, an inexpensive material, consists of carbon nanotubes, amorphous and graphitic carbon and metal particles. Results are compared to earlier studies on PMMA/multi-walled nanotube (MWNT) composites and PMMA/single-walled nanotube (SWNT) composites. The beta relaxation process appeared to be unaffected by the presence of the soot, as was noted earlier in nanotube composites. The gamma relaxation region in PMMA, normally dielectrically inactive, was "awakened" in the PMMA/soot composite. This occurrence is consistent with previously published data on nanotube composites. The dielectric permittivity, s', increased with soot content. The sample with 1% soot exhibited a permittivity (at 100 Hz and 25 degrees C) of 7.3 as compared to 5.1 for neat PMMA. Soot increased the dielectric strength, deltaE, of the composites. The 1% soot sample exhibited a dielectric strength of 6.38, while the neat PMMA had a value of 2.95 at 40 degrees C. The symmetric broadening term (alpha) was slightly higher for the 1% composite at temperatures near the secondary relaxation and near the primary relaxation, but all samples deviated from symmetrical semi-circular behavior (alpha = 1). The impact of the soot filler is seen more clearly in dielectric properties than in mechanical properties studies conducted earlier.

  19. Response of centrifugal blowers to simulated tornado transients, July-September 1981

    International Nuclear Information System (INIS)

    Idar, E.S.; Gregory, W.S.; Martin, R.A.; Littleton, P.E.

    1982-03-01

    During this quarter, quasi-steady and dynamic testing of the 24-in. centrifugal blower was completed using the blowdown facility located at New Mexico State University. The data were obtained using a new digital data-acquisition system. Software was developed at the Los Alamos National Laboratory to reduce the dynamic test data and create computer-generated movies showing the dynamic performance of the blower under simulated tornado transient pressure conditions relative to its quasi-steady-state performance. Currently, quadrant-four (outrunning flow) data have been reduced for the most severe and a less severe tornado pressure transient. The results indicate that both the quasi-steady and dynamic blower performance are very similar. Some hysteresis in the dynamic performance occurs because of rotational inertia effects in the blower rotor and drive system. Currently quadrant-two (backflow) data are being transferred to the LTSS computer system at Los Alamos and will be reduced shortly

  20. Coronary air embolism in off-pump surgery caused by blower-mister device.

    Science.gov (United States)

    Korkmaz, Askin Ali; Guden, Mustafa; Korkmaz, Feride; Yuce, Murat

    2008-01-01

    Gaseous emboli caused by the blower-mister result in air locks within coronary vessels. We describe the case of a coronary air embolism caused by a blower-mister device on off-pump surgery. The tip of the device unexpectedly entered the coronary artery through arteriotomy and caused the air emboli. Air locks in the coronary circulation led to hemodynamic deterioration, and cardiopulmonary bypass was started following the emergency cannulation.

  1. Simulation of soot size distribution in an ethylene counterflow flame

    KAUST Repository

    Zhou, Kun

    2014-01-06

    Soot, an aggregate of carbonaceous particles produced during the rich combustion of fossil fuels, is an undesirable pollutant and health hazard. Soot evolution involves various dynamic processes: nucleation soot formation from polycyclic aromatic hydrocarbons (PAHs) condensation PAHs condensing on soot particle surface surface processes hydrogen-abstraction-C2H2-addition, oxidation coagulation two soot particles coagulating to form a bigger particle This simulation work investigates soot size distribution and morphology in an ethylene counterflow flame, using i). Chemkin with a method of moments to deal with the coupling between vapor consumption and soot formation; ii). Monte Carlo simulation of soot dynamics.

  2. ENERGY STAR Certified Boilers

    Data.gov (United States)

    U.S. Environmental Protection Agency — Certified models meet all ENERGY STAR requirements as listed in the Version 3.0 ENERGY STAR Program Requirements for Boilers that are effective as of October 1,...

  3. Design and Experiment of Auxiliary Bearing for Helium Blower of HTR-PM

    International Nuclear Information System (INIS)

    Yang Guojun; Shi Zhengang; Liu Xingnan; Zhao Jingjing

    2014-01-01

    The helium blower is the important equipment for HTR-PM. Active magnetic bearing (AMB) instead of mechanical bearing is selected to support the rotor of the helium blower. However, one implication of AMB is the requirement to provide the auxiliary bearing to mitigate the effects of failures or overload conditions. The auxiliary bearing is used to support the rotor when the AMB fails to work. It must support the dropping rotor and bear the great impact force and friction heat. The design of the auxiliary bearing is one of the challenging problems in the whole system. It is very important for the helium blower with AMB of HTR-PM to make success. The rotor’s length of helium blower of HTR-PM is about 3.3 m, its weight is about 4000 kg and the rotating speed is 4000 r/min. The axial load is 4500kg, and the radial load is 1950kg. The angular contact ball bearing was selected as the auxiliary bearing. The test rig has been finished. It is difficult to analyze the falling course of the rotor. The preliminary analysis of the dropping rotor was done in the special condition. The impact force of auxiliary bearing was computed for the axial and radial load. And the dropping test of the blower rotor for HTR-10 will be introduced also in this paper. Results offer the important theoretical base for the protector design of the helium blower with AMB for HTR-PM. (author)

  4. NASA: Black soot fuels global warming

    CERN Multimedia

    2003-01-01

    New research from NASA's Goddard Space Center scientists suggests emissions of black soot have been altering the way sunlight reflects off Earth's snow. The research indicates the soot could be responsible for as much as 25 percent of global warming over the past century (assorted news items, 1 paragraph each).

  5. MODELLING, SIMULATING AND OPTIMIZING BOILERS

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    2004-01-01

    In the present work a framework for optimizing the design of boilers for dynamic operation has been developed. A cost function to be minimized during the optimization has been formulated and for the present design variables related to the Boiler Volume and the Boiler load Gradient (i.e. ring rate...... on the boiler) have been dened. Furthermore a number of constraints related to: minimum and maximum boiler load gradient, minimum boiler size, Shrinking and Swelling and Steam Space Load have been dened. For dening the constraints related to the required boiler volume a dynamic model for simulating the boiler...... performance has been developed. Outputs from the simulations are shrinking and swelling of water level in the drum during for example a start-up of the boiler, these gures combined with the requirements with respect to allowable water level uctuations in the drum denes the requirements with respect to drum...

  6. NOx Control Options and Integration for US Coal Fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

    2006-06-30

    This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected

  7. Super Boiler: First Generation, Ultra-High Efficiency Firetube Boiler

    Energy Technology Data Exchange (ETDEWEB)

    None

    2006-06-01

    This factsheet describes a research project whose goal is to develop and demonstrate a first-generation ultra-high-efficiency, ultra-low emissions, compact gas-fired package boiler (Super Boiler), and formulate a long-range RD&D plan for advanced boiler technology out to the year 2020.

  8. Light changes the atmospheric reactivity of soot

    Science.gov (United States)

    D'Anna, Barbara; Monge, Maria-Eugenia; George, Christian; Ammann, Markus; Donaldson, D. Jamie

    2010-05-01

    Soot particles formed by incomplete combustion processes comprise a significant portion of the fine aerosol loading (below 1micron). These particles affect the radiative forcing contributing to global warming and have increased toxicity relative to larger particles because they may settle and persist in the deeper respiratory tract, and can even cross biological barriers. In addition, they are often coated with polycyclic aromatic hydrocarbons (PAHs). Soot particles exhibit a large specific surface area, approx. 100 m2 g-1, which suggests a potential for heterogeneous interactions with atmospheric trace gases. Consequently, soot was suggested to be an important sink for some atmospheric oxidants such as O3 or NOx and its heterogeneous chemistry has been largely investigated in the past years. However, its atmospheric impact was suggested to be negligible due to a rapid soot surface deactivation under atmospheric conditions. As previous studies were done under dark conditions, we decided to investigate the effect of light on the heterogeneous reaction of NO2 on various soot samples. As well, we studied the effect of O3 and light exposure on the aging of soot samples. The heterogeneous reaction between soot particles and NO2 was studied by means of a coated flow tube equipped with near-UV emitting lamps (300-420 nm). The effect of O3 and light on the wettability of soot was studied by contact angle measurements. The characterization of the soot particles was performed by TEM, ESEM and AMS. Different combustion conditions were used to produce the soot samples, which were generated with a mini-CAST soot generator using propane as fuel. We determined the uptake coefficients for different gas phase NO2 concentrations (15-120 ppbv) under near UV irradiation. The results showed that the heterogeneous reaction of NO2 and soot under irradiation leads to NO and HONO production with different yields according to the combustion conditions of the generated soot particles. The

  9. Effect of strain rate on sooting limits in counterflow diffusion flames of gaseous hydrocarbon fuels: Sooting temperature index and sooting sensitivity index

    KAUST Repository

    Wang, Yu

    2014-05-01

    The effect of the strain rate on the sooting limits in counterflow diffusion flames was investigated in various gaseous hydrocarbon fuels by varying the nitrogen dilution in the fuel and oxidizer streams. The sooting limit was defined as the critical fuel and oxygen mole fraction at which soot started to appear in the elastic light scattering signal. The sooting region for normal alkane fuels at a specified strain rate, in terms of the fuel and oxygen mole fraction, expanded as the number of carbon atoms increased. The alkene fuels (ethylene, propene) tested had a higher propensity for sooting as compared with alkane fuels with the same carbon numbers (ethane, propane). Branched iso-butane had a higher propensity for sooting than did n-butane. An increase in the strain rate reduced the tendency for sooting in all the fuels tested. The sensitivity of the sooting limit to the strain rate was more pronounced for less sooting fuels. When plotted in terms of calculated flame temperature, the critical oxygen mole fraction exhibited an Arrhenius form under sooting limit conditions, which can be utilized to significantly reduce the effort required to determine sooting limits at different strain rates. We found that the limiting temperatures of soot formation flames are viable sooting metrics for quantitatively rating the sooting tendency of various fuels, based on comparisons with threshold soot index and normalized smoke point data. We also introduce a sooting temperature index and a sooting sensitivity index, two quantitative measures to describe sooting propensity and its dependence on strain rate. © 2013 The Combustion Institute.

  10. Dynamic Boiler Performance

    DEFF Research Database (Denmark)

    Sørensen, Kim

    for buying and selling energy has increased the focus on the dynamic operation capability, efciency, emissions etc. For optimizing the design of boilers for dynamic operation a quantication of the dynamic capability is needed. A framework for optimizing design of boilers for dynamic operation has been...... developed. Analyzing boilers for dynamic operation gives rise to a number of opposing aims: shrinking and swelling, steam quality, stress levels, control system/philosophy, pressurization etc. Common for these opposing aims is that an optimum can be found for selected operation conditions. The framework has...... been developed as open, i.e. more dimensions and their corresponding quanti- cation can be added. In the present study the dynamic capability has been quantied and the feasible set for the optimization has been limited by means of a number of constraints. The constraints are: (i) simple constraints...

  11. Monte carlo simulation for soot dynamics

    KAUST Repository

    Zhou, Kun

    2012-01-01

    A new Monte Carlo method termed Comb-like frame Monte Carlo is developed to simulate the soot dynamics. Detailed stochastic error analysis is provided. Comb-like frame Monte Carlo is coupled with the gas phase solver Chemkin II to simulate soot formation in a 1-D premixed burner stabilized flame. The simulated soot number density, volume fraction, and particle size distribution all agree well with the measurement available in literature. The origin of the bimodal distribution of particle size distribution is revealed with quantitative proof.

  12. Modelling and simulation of soot generation and transport

    OpenAIRE

    Hu, Xiaoqin

    2016-01-01

    Soot released from fires not only causes danger to lives and property damage, but also effects fire spread by altering the radiation characteristics of fire effluents. In many situations, it is the soot concentration that controls the fire development. Therefore, soot modelling is of great importance in fire safety science. This necessitates the development of a global and general soot model within fire field models that can simulate the amount of soot generated and transported in large-scale...

  13. Electrically heated particulate matter filter soot control system

    Science.gov (United States)

    Gonze, Eugene V.; Paratore, Jr., Michael J.; Bhatia, Garima

    2016-03-15

    A regeneration system includes a particulate matter (PM) filter with an upstream end for receiving exhaust gas and a downstream end. A control module determines a current soot loading level of the PM filter and compares the current soot loading level to a predetermined soot loading level. The control module permits regeneration of the PM filter when the current soot loading level is less than the predetermined soot loading level.

  14. Retrofit device to improve vapor compression cooling system performance by dynamic blower speed modulation

    Science.gov (United States)

    Roth, Robert Paul; Hahn, David C.; Scaringe, Robert P.

    2015-12-08

    A device and method are provided to improve performance of a vapor compression system using a retrofittable control board to start up the vapor compression system with the evaporator blower initially set to a high speed. A baseline evaporator operating temperature with the evaporator blower operating at the high speed is recorded, and then the device detects if a predetermined acceptable change in evaporator temperature has occurred. The evaporator blower speed is reduced from the initially set high speed as long as there is only a negligible change in the measured evaporator temperature and therefore a negligible difference in the compressor's power consumption so as to obtain a net increase in the Coefficient of Performance.

  15. Electrometric Aviation Soot Monitor, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to develop a sensitive PM measurement instrument to determine soot particle mass distribution from aircraft engine exhausts as well as from other IC...

  16. Non-thermal soot denuder, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to develop a non-thermal soot denuder for measuring chemical components of the nucleation mode particulate matter emissions from gas turbine engines, in...

  17. Method for removing soot from exhaust gases

    Science.gov (United States)

    Suib, Steven L.; Dharmarathna, D. A. Saminda; Pahalagedara, Lakshitha R.

    2018-01-16

    A method for oxidizing soot from diesel exhaust gas from a diesel engine. The method involves providing a diesel particulate filter for receiving the diesel exhaust gas; coating a catalyst composition on the diesel particulate filter; and contacting the soot from the diesel exhaust gas with the catalyst coated diesel particulate filter at a temperature sufficient to oxidize the soot to carbon dioxide. The catalyst composition is a doped or undoped manganese oxide octahedral molecular sieve (OMS-2) material. A diesel exhaust gas treatment system that includes a diesel particulate filter for receiving diesel exhaust gas from a diesel engine and collecting soot; and a catalyst composition coated on the diesel particulate filter. The catalyst composition is a doped or undoped manganese oxide octahedral molecular sieve (OMS-2).

  18. Electrometric aviation soot monitor, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to develop a highly sensitive and portable device to monitor soot particle mass distribution from aircraft engine exhaust. The proposed method is based on...

  19. Atmospheric soot aerosol measurements in Moscow

    Energy Technology Data Exchange (ETDEWEB)

    Kopeikin, V.M.; Pekour, M.S. [Institute of Atmospheric Physics, Moscow (Russian Federation)

    1996-12-31

    The results of regular soot concentration measurement in Moscow`s air for the period February 1989 - December 1995 are presented. The data obtained show that the level of soot contamination increased with the rate of approximately 0.42 mkg/m{sup 3} per year. 24-hour measurements of soot concentration and atmospheric boundary layer (ABL) parameters were carried out during 3 campaigns: May-June 1990, February 1991 and October-November 1993. Direct comparisons of local soot concentration with ABL characteristics reveals certain relationships, but also shows that local contamination strongly depends on many other parameters, such as source productivity, chemical reactions, air mass pre-history and so on.

  20. Using CO to Determine Inhaled Contaminant Volumes and Blower Effectiveness in Several Types of Respirators

    Directory of Open Access Journals (Sweden)

    Arthur T. Johnson

    2011-01-01

    Full Text Available This experiment was conducted to determine how much contaminant could be expected to be inhaled when overbreathing several different types of respirators. These included several tight-fitting and loose-fitting powered air-purifying respirators (PAPRs and one air-purifying respirator (APR. CO2 was used as a tracer gas in the ambient air, and several loose-and tight-fitting respirators were tested on the head form of a breathing machine. CO2 concentration in the exhaled breath was monitored as well as CO2 concentration in the ambient air. This concentration ratio was able to give a measurement of protection factor, not for the respirator necessarily, but for the wearer. Flow rates in the filter/blower inlet and breathing machine outlet were also monitored, so blower effectiveness (defined as the blower contribution to inhaled air could also be determined. Wearer protection factors were found to range from 1.1 for the Racal AirMate loose-fitting PAPR to infinity for the 3M Hood, 3M Breath-Easy PAPR, and SE 400 breath-responsive PAPR. Inhaled contaminant volumes depended on tidal volume but ranged from 2.02 L to 0 L for the same respirators, respectively. Blower effectiveness was about 1.0 for tight-fitting APRs, 0.18 for the Racal, and greater than 1.0 for two of the loose-fitting PAPRs. With blower effectiveness greater than 1.0, some blower flow during the exhalation phase contributes to the subsequent inhalation. Results from this experiment point to different ways to measure respirator efficacy.

  1. Using CO2 to Determine Inhaled Contaminant Volumes and Blower Effectiveness in Several Types of Respirators

    Science.gov (United States)

    Johnson, Arthur T.; Koh, Frank C.; Scott, William H.; Rehak, Timothy E.

    2011-01-01

    This experiment was conducted to determine how much contaminant could be expected to be inhaled when overbreathing several different types of respirators. These included several tight-fitting and loose-fitting powered air-purifying respirators (PAPRs) and one air-purifying respirator (APR). CO2 was used as a tracer gas in the ambient air, and several loose-and tight-fitting respirators were tested on the head form of a breathing machine. CO2 concentration in the exhaled breath was monitored as well as CO2 concentration in the ambient air. This concentration ratio was able to give a measurement of protection factor, not for the respirator necessarily, but for the wearer. Flow rates in the filter/blower inlet and breathing machine outlet were also monitored, so blower effectiveness (defined as the blower contribution to inhaled air) could also be determined. Wearer protection factors were found to range from 1.1 for the Racal AirMate loose-fitting PAPR to infinity for the 3M Hood, 3M Breath-Easy PAPR, and SE 400 breath-responsive PAPR. Inhaled contaminant volumes depended on tidal volume but ranged from 2.02 L to 0 L for the same respirators, respectively. Blower effectiveness was about 1.0 for tight-fitting APRs, 0.18 for the Racal, and greater than 1.0 for two of the loose-fitting PAPRs. With blower effectiveness greater than 1.0, some blower flow during the exhalation phase contributes to the subsequent inhalation. Results from this experiment point to different ways to measure respirator efficacy. PMID:21792358

  2. Large boiler modularization

    Energy Technology Data Exchange (ETDEWEB)

    MacKenzie, Malcolm [Babcock and Wilcox Canada Ltd (Canada)

    2011-07-01

    This paper presents the modularization strategy in boiler manufacture of Babcock and Wilcox Canada Ltd, designed specifically to provide steam capacities up to 1,000,000 lb/hr. Designed as a solution for the oil sands market, the boiler responds to the needs of steam assisted gravity drainage (SAGD) and other in situ processes. Manufacture of three modules: furnace, superheater, and saturated module, is detailed assembly phases are shown as well as the construction sequence. The boiler is bottom-supported and features a unique modularized design that maximizes shop assembly and provides certainty to delivery and overall project schedule. Moreover, it is adaptable for all liquid and gaseous fuel types, including natural gas, produced gas and emulsified liquid fuels. This highly modular solution makes it a comprehensive solution for projects where construction risks and costs would otherwise be prohibitive. Maximum modularization of the boiler and minimal site labour are key design features, ensuring compliance with the weight and dimensional constraints of Alberta's high load corridor.

  3. Sooting limit in counterflow diffusion flames of ethylene/propane fuels and implication to threshold soot index

    KAUST Repository

    Joo, Peter H.

    2013-01-01

    Sooting limits in counterflow diffusion flames of propane/ethylene fuels have been studied experimentally using a light scattering technique, including the effects of dilution, fuel mixing, and strain rate. The results are discussed in view of the threshold soot index (TSI). In soot-formation (SF) flames, where the flame is located on the oxidizer side of the stagnation plane, the sooting limit depends critically on fuel type and subsequently on flame temperature. The sooting limit has a non-linear dependence on the fuel-mixing ratio, which is similar to the non-linear mixing rule for TSI observed experimentally in rich premixed flames, where soot oxidation is absent for both SF and rich premixed flames. In soot-formation-oxidation (SFO) flames, where the flame is located on the fuel side, the sooting limit depends critically on flame temperature, while it is relatively independent on fuel type. This result suggests a linear mixing rule for sooting limits in SFO flames, which is similar to the TSI behavior for coflow diffusion flames. Soot oxidation takes place for both types of flames. The aerodynamic strain effect on the sooting limits has also been studied and an appreciable influence has been observed. Under sooting conditions, soot volume fraction was measured using a light extinction technique. The soot loadings in SF flames of the mixture fuels demonstrated a synergistic effect, i.e., soot production increased for certain mixture fuels as compared to the respective singlecomponent fuels. © 2012 The Combustion Institute.

  4. MODELLING, SIMULATING AND OPTIMIZING BOILERS

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    2003-01-01

    This paper describes the modelling, simulating and optimizing including experimental verification as being carried out as part of a Ph.D. project being written resp. supervised by the authors. The work covers dynamic performance of both water-tube boilers and fire tube boilers. A detailed dynamic...... model of the boiler has been developed and simulations carried out by means of the Matlab integration routines. The model is prepared as a dynamic model consisting of both ordinary differential equations and algebraic equations, together formulated as a Differential-Algebraic-Equation system. Being able...... to operate a boiler plant dynamically means that the boiler designs must be able to absorb any fluctuations in water level and temperature gradients resulting from the pressure change in the boiler. On the one hand a large water-/steam space may be required, i.e. to build the boiler as big as possible. Due...

  5. Curbing Air Pollution and Greenhouse Gas Emissions from Industrial Boilers in China

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Bo [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Price, Lynn K [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Lu, Hongyou [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Liu, Xu [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Tsen, Katherine [Univ. of California, Berkeley, CA (United States); Xiangyang, Wei [National Energy Conservation Center (China); Yunpeng, Zhang [National Energy Conservation Center (China); Jian, Guan [China Special Equipment Inspection & Test Inst. (China); Rui, Hou [China Machinery Industry Conservation & Resource Utilization Center (China); Junfeng, Zhang [China National Offshore Oil Corp. (China); Yuqun, Zhuo [Tsinghua Univ., Beijing (China); Shumao, Xia [China Energy Conservation & Environmental Protection Group (China); Yafeng, Han [Xi' an Jiatong Univ. (China); Manzhi, Liu [China Univ. of Mining and Technology (China)

    2015-10-28

    China’s industrial boiler systems consume 700 million tons of coal annually, accounting for 18% of the nation’s total coal consumption. Together these boiler systems are one of the major sources of China’s greenhouse gas (GHG) emissions, producing approximately 1.3 gigatons (Gt) of carbon dioxide (CO2) annually. These boiler systems are also responsible for 33% and 27% of total soot and sulfur dioxide (SO2) emissions in China, respectively, making a substantial contribution to China’s local environmental degradation. The Chinese government - at both the national and local level - is taking actions to mitigate the significant greenhouse gas (GHG) emissions and air pollution related to the country’s extensive use of coal-fired industrial boilers. The United States and China are pursuing a collaborative effort under the U.S.-China Climate Change Working Group to conduct a comprehensive assessment of China’s coal-fired industrial boilers and to develop an implementation roadmap that will improve industrial boiler efficiency and maximize fuel-switching opportunities. Two Chinese cities – Ningbo and Xi’an – have been selected for the assessment. These cities represent coastal areas with access to liquefied natural gas (LNG) imports and inland regions with access to interprovincial natural gas pipelines, respectively.

  6. Aromatics Oxidation and Soot Formation in Flames

    Energy Technology Data Exchange (ETDEWEB)

    Howard, J. B.; Richter, H.

    2005-03-29

    This project is concerned with the kinetics and mechanisms of aromatics oxidation and the growth process to polycyclic aromatic hydrocarbons (PAH) of increasing size, soot and fullerenes formation in flames. The overall objective of the experimental aromatics oxidation work is to extend the set of available data by measuring concentration profiles for decomposition intermediates such as phenyl, cyclopentadienyl, phenoxy or indenyl radicals which could not be measured with molecular-beam mass spectrometry to permit further refinement and testing of benzene oxidation mechanisms. The focus includes PAH radicals which are thought to play a major role in the soot formation process while their concentrations are in many cases too low to permit measurement with conventional mass spectrometry. The radical species measurements are used in critical testing and improvement of a kinetic model describing benzene oxidation and PAH growth. Thermodynamic property data of selected species are determined computationally, for instance using density functional theory (DFT). Potential energy surfaces are explored in order to identify additional reaction pathways. The ultimate goal is to understand the conversion of high molecular weight compounds to nascent soot particles, to assess the roles of planar and curved PAH and relationships between soot and fullerenes formation. The specific aims are to characterize both the high molecular weight compounds involved in the nucleation of soot particles and the structure of soot including internal nanoscale features indicative of contributions of planar and/or curved PAH to particle inception.

  7. NATO Workshop on Soot in Combustion Systems

    CERN Document Server

    Prado, G

    1983-01-01

    Our interest in Mulhouse for carbon black and soot began some 30 years ago when J.B. Donnet developed the concept of surface chemistry of carbon and its involvement in interactions with gas, liquid and solid phases. In the late sixties, we began to study soot formation in pyrolytic systems and later on in flames. The idea of organ1z1ng a meeting on soot formation originated some four or five years ago, through discussions among Professor J.B. Howard, Dr. A. D'Alessio and ourselves. At that time the scientific community was becoming aware of the necessity to strictly control soot formation and emission. Being involved in the study of surface properties of carbon black as well as of formation of soot, we realized that the combustion community was not always fully aware of the progress made by the physical-chemists on carbon black. Reciprocally, the carbon specialists were often ignoring the research carried out on soot in flames. One objective of this workshop was to stimulate discussions between these two scie...

  8. CHP Integrated with Burners for Packaged Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Castaldini, Carlo; Darby, Eric

    2013-09-30

    division of Sempra Energy. These match funds were provided via concurrent contracts and investments available via CMCE, Altex, and Leva Energy The project attained all its objectives and is considered a success. CMCE secured the support of GI&E from Italy to supply 100 kW Turbec T-100 microturbines for the project. One was purchased by the project’s subcontractor, Altex, and a second spare was purchased by CMCE under this project. The microturbines were then modified to convert from their original recuperated design to a simple cycle configuration. Replacement low-NOx silo combustors were designed and bench tested in order to achieve compliance with the California Air Resources Board (CARB) 2007 emission limits for NOx and CO when in CHP operation. The converted microturbine was then mated with a low NOx burner provided by Altex via an integration section that allowed flow control and heat recovery to minimize combustion blower requirements; manage burner turndown; and recover waste heat. A new fully integrated control system was designed and developed that allowed one-touch system operation in all three available modes of operation: (1) CHP with both microturbine and burner firing for boiler heat input greater than 2 MMBtu/hr; (2) burner head only (BHO) when the microturbine is under service; and (3) microturbine only when boiler heat input requirements fall below 2 MMBtu/hr. This capability resulted in a burner turndown performance of nearly 10/1, a key advantage for this technology over conventional low NOx burners. Key components were then assembled into a cabinet with additional support systems for generator cooling and fuel supply. System checkout and performance tests were performed in the laboratory. The assembled system and its support equipment were then shipped and installed at a host facility where final performance tests were conducted following efforts to secure fabrication, air, and operating permits. The installed power burner is now in commercial

  9. Development of a no-moving-part blower for difficult operating conditions

    Czech Academy of Sciences Publication Activity Database

    Tesař, Václav

    2013-01-01

    Roč. 91, č. 12 (2013), s. 2401-2411 ISSN 0263-8762 R&D Projects: GA ČR GA13-23046S Institutional research plan: CEZ:AV0Z20760514 Keywords : blower * fluidics * hazardous fluids Subject RIV: BK - Fluid Dynamics Impact factor: 2.281, year: 2013 http://www.sciencedirect.com/science/article/pii/S0263876213001081

  10. Impact of relative position vehicle-wind blower in a roller test bench under climatic chamber

    International Nuclear Information System (INIS)

    Fernández-Yáñez, P.; Armas, O.; Martínez-Martínez, S.

    2016-01-01

    Highlights: • Air simulation model was developed for a vehicle test bench under climatic chamber. • Good accuracy between experimental data and simulated values were obtained. • Wind blower-vehicle relative position alters external cooling of after-treatment devices. • Vehicle emission certification can be affected by wind blower-vehicle relative position. - Abstract: In terms of energy efficiency and exhaust emissions control, an appropriate design of cooling systems of climatic chambers destined to vehicle certification and/or perform scientific research is becoming increasingly important. European vehicle emissions certification (New European Driving Cycle, NEDC) establishes the position of the wind-simulation blower at 200 mm above floor level. This height is fixed and kept constant independently of the vehicle tested. The position of the blower with respect to the vehicle can modify the external forced convection under the car, where after-treatment devices are located. Consequently, the performance of such devices could be modified and emission results during the certification cycle could be non-representative of real-world driving conditions. The aim of this work is to study the influence of different wind blower-vehicle relative heights on the air velocity and temperature profiles under the car by means of a simple computational fluid dynamics (CFD) approach. A steady state three-dimensional CFD model was developed and applied to the estimation of the air velocity and temperature profiles inside of a climatic chamber equipped with a vehicle roller (chassis dyno) test bench. The simulations reproduce one steady-state condition from NEDC, specifically the EU17 mode (120 km/h, maximum velocity during the cycle). The cool air propelling temperature was 20 °C (minimum temperature in the NEDC range). Simulations were performed employing the Reynolds-Averaged Navier-Stokes (RANS) approach with the realizable k-ε model to provide closure. Air velocity and

  11. Mod increases AGR boiler output

    International Nuclear Information System (INIS)

    Jones, W.K.C.; Rider, G.; Taylor, D.E.

    1986-01-01

    During the commissioning runs of the first reactor units at Heysham I and Hartlepool Advanced Gas-cooled Reactors (AGRs), non-uniform temperature distributions were observed across individual boiler units which were more severe than those predicted from the design analysis. This article describes the re-orificing (referruling) of the boilers to overcome this problem. The referruling has reduced boiler sensitivity and resulted in an increase of load of 7 or 8%. (U.K.)

  12. Super Boiler 2nd Generation Technology for Watertube Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Mr. David Cygan; Dr. Joseph Rabovitser

    2012-03-31

    This report describes Phase I of a proposed two phase project to develop and demonstrate an advanced industrial watertube boiler system with the capability of reaching 94% (HHV) fuel-to-steam efficiency and emissions below 2 ppmv NOx, 2 ppmv CO, and 1 ppmv VOC on natural gas fuel. The boiler design would have the capability to produce >1500 F, >1500 psig superheated steam, burn multiple fuels, and will be 50% smaller/lighter than currently available watertube boilers of similar capacity. This project is built upon the successful Super Boiler project at GTI. In that project that employed a unique two-staged intercooled combustion system and an innovative heat recovery system to reduce NOx to below 5 ppmv and demonstrated fuel-to-steam efficiency of 94% (HHV). This project was carried out under the leadership of GTI with project partners Cleaver-Brooks, Inc., Nebraska Boiler, a Division of Cleaver-Brooks, and Media and Process Technology Inc., and project advisors Georgia Institute of Technology, Alstom Power Inc., Pacific Northwest National Laboratory and Oak Ridge National Laboratory. Phase I of efforts focused on developing 2nd generation boiler concepts and performance modeling; incorporating multi-fuel (natural gas and oil) capabilities; assessing heat recovery, heat transfer and steam superheating approaches; and developing the overall conceptual engineering boiler design. Based on our analysis, the 2nd generation Industrial Watertube Boiler when developed and commercialized, could potentially save 265 trillion Btu and $1.6 billion in fuel costs across U.S. industry through increased efficiency. Its ultra-clean combustion could eliminate 57,000 tons of NOx, 460,000 tons of CO, and 8.8 million tons of CO2 annually from the atmosphere. Reduction in boiler size will bring cost-effective package boilers into a size range previously dominated by more expensive field-erected boilers, benefiting manufacturers and end users through lower capital costs.

  13. Numerical investigation on soot particles emission in compression ignition diesel engine by using particulate mimic soot model

    Directory of Open Access Journals (Sweden)

    Ibrahim Fadzli

    2017-01-01

    Full Text Available Research via computational method, specifically by detailed-kinetic soot model offers much more advantages than the simple model as more detailed formation/oxidation process is taken into consideration, thus providing better soot mass concentration, soot size, soot number density as well as information regarding other related species. In the present computational study, investigation of in-cylinder soot concentration as well as other emissions in a single cylinder diesel engine has been conducted, using a commercial multidimensional CFD software, CONVERGE CFD. The simulation was carried out for a close-cycle combustion environment from inlet valve closing (IVC to exhaust valve opening (EVO. In this case, detailed-kinetic Particulate Mimic (PM soot model was implemented as to take benefit of the method of moment, instead of commonly implemented simple soot model. Analyses of the results are successfully plotted to demonstrate that the soot size and soot mass concentration are strongly dependent on the detailed soot formation and oxidation process rates. The calculated of soot mass concentration and average soot size at EVO provide the end value of 29.2 mg/m3 and 2.04 × 10−8 m, respectively. Besides, post-processing using EnSight shows the qualitative results of soot concentration along simulation period in the combustion chamber.

  14. Kinetics and mechanism of soot formation in hydrocarbon combustion

    Science.gov (United States)

    Frenklach, Michael

    1990-01-01

    The focus of this work was on kinetic modeling. The specific objectives were: detailed modeling of soot formation in premixed flames, elucidation of the effects of fuel structure on the pathway to soot, and the development of a numerical technique for accurate modeling of soot particle coagulation and surface growth. Those tasks were successfully completed and are briefly summarized.

  15. Soot precursor measurements in benzene and hexane diffusion flames

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, Y.; Furuhata, T.; Amagai, K.; Arai, M. [Department of Mechanical System Engineering, Graduate School of Engineering, Gunma University, 1-5-1 Tenjin-cho, Kiryu-shi, Gunma 376-8515 (Japan)

    2008-08-15

    To clarify the mechanism of soot formation in diffusion flames of liquid fuels, measurements of soot and its precursors were carried out. Sooting diffusion flames formed by a small pool combustion equipment system were used for this purpose. Benzene and hexane were used as typical aromatic and paraffin fuels. A laser-induced fluorescence (LIF) method was used to obtain spatial distributions of polycyclic aromatic hydrocarbons (PAHs), which are considered as soot particles. Spatial distributions of soot in test flames were measured by a laser-induced incandescence (LII) method. Soot diameter was estimated from the temporal change of LII intensity. A region of transition from PAHs to soot was defined from the results of LIF and LII. Flame temperatures, PAH species, and soot diameters in this transition region were investigated for both benzene and hexane flames. The results show that though the flame structures of benzene and hexane were different, the temperature in the PAHs-soot transition region of the benzene flame was similar to that of the hexane flame. Furthermore, the relationship between the PAH concentrations measured by gas chromatography in both flames and the PAH distributions obtained from LIF are discussed. It was found that PAHs with smaller molecular mass, such as benzene and toluene, remained in both the PAHs-soot transition and sooting regions, and it is thought that molecules heavier than pyrene are the leading candidates for soot precursor formation. (author)

  16. Boiler tube failure prevention in fossil fired boilers

    International Nuclear Information System (INIS)

    Townsend, R.D.

    1993-01-01

    It is the common experience of power generating companies worldwide that the main causes of forced outages on power plant are those due to boiler tube failures on fossil units. The main reason for the large number of failures are the severe environmental conditions in fossil boilers as the effects of stress, temperature, temperature gradients, corrosion, erosion and vibration combine to produce degradation of the tube steel. Corrosion by oxidation, by combustion products and by impure boiler water can significantly reduce the tube wall thickness and result in failure of a tube many years before its designed service life. Errors can also occur in the design manufacturer, storage, operation, and maintenance of boiler tubing and the wrong material installed in a critical location can lead to premature failure. Altogether, experts in the US and UK, from many different disciplines, have identified seven broad categories of boiler tube failure mechanisms. 1 tab., 2 figs

  17. Improved nuclear boiler

    International Nuclear Information System (INIS)

    Pierart, Robert.

    1980-01-01

    The improved nuclear boiler concerned in this invention is of the kind comprising, inter alia, a nuclear reactor supported by a metallic structure and of which the vessel is at least enclosed in part by a casing acting as a protective containment integrated in this structure. It is essentially characterized in that this casing is fitted into and maintained in position in the metallic structure by removable locking devices which enable the casing to be withdrawn from the remainder of the structure. Hence, after the casing has been withdrawn or removed from the metallic structure, access to the reactor vessel is readily obtained for inspection and/or testing from without [fr

  18. Quality and nuclear boilers

    International Nuclear Information System (INIS)

    Cante, C.

    1977-08-01

    The design and manufacture of the components, assembly, erection and tests, these different stages in the making of a nuclear boiler are carried out according to very accurately defined techniques and organization. From the technical viewpoint, it is shown how standard practice, experience, tests, the respect of codes and standard specifications contribute to the quality of achievement. The organizing of the assurance of quality is exposed by more particularly bringing to mind an American text which sets forth a certain number of principles widely applied beyond the frontiers of the United States. (author)

  19. Evaluation of a Lagrangian Soot Tracking Method for the prediction of primary soot particle size under engine-like conditions

    DEFF Research Database (Denmark)

    Cai Ong, Jiun; Pang, Kar Mun; Walther, Jens Honore

    2018-01-01

    particles when the mass of incipient soot exceeds a designated threshold value. Their trajectories are then computed using the particle momentum equation. The change of primary soot particle size is dependent on the modified Lagrangian surface growth and soot oxidation models. Performance of the LST model...

  20. The many faces of soot: characterization of soot nanoparticles produced by engines.

    Science.gov (United States)

    Niessner, Reinhard

    2014-11-10

    Soot nanoparticles produced by engines constitute a threat to human health. For the analytical chemist, soot is a hard nut to crack as the released particles undergo rapid changes in their size, shape, and number concentration. The complete characterization of soot will be essential to meet future low-emission standards. Besides measuring the light extinction, modern analytical chemistry can determine a variety of less-known effects, such as condensation properties, immune response in vertebrates, and impact on the cardiovascular function of a beating heart. Photon emission and in particular Raman spectroscopy provides information on the nanocrystallinity, while thermoelectron emission allows the number of electrical particles to be counted. Even the "simple" combustion of soot nanoparticles offers potential for the characterization of the particles. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. MODELLING, SIMULATING AND OPTIMIZING BOILERS

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    2003-01-01

    This paper describes the modelling, simulating and optimizing including experimental verification as being carried out as part of a Ph.D. project being written resp. supervised by the authors. The work covers dynamic performance of both water-tube boilers and fire tube boilers. A detailed dynamic...... to the internal pressure the consequence of the increased volume (i.e. water-/steam space) is an increased wall thickness in the pressure part of the boiler. The stresses introduced in the boiler pressure part as a result of the temperature gradients are proportional to the square of the wall thickness...... model of the boiler has been developed and simulations carried out by means of the Matlab integration routines. The model is prepared as a dynamic model consisting of both ordinary differential equations and algebraic equations, together formulated as a Differential-Algebraic-Equation system. Being able...

  2. Multi-circulation boiler design

    Energy Technology Data Exchange (ETDEWEB)

    MacKenzie, Malcolm [Babcock and Wilcox Canada Ltd (Canada)

    2011-07-01

    Steam assisted gravity drainage (SAGD) requires steam, which was historically supplied by once-through steam generators (OTSG). OTSGs are now often replaced by drum boilers for steam generation. Drum boilers have a higher capacity than OTSGs and produce reduced blowdown. However, the volume of contaminants in feedwater is generally significant and ASME criteria require high-quality feedwater. The current study investigates a new design for a multi-circulation boiler that would allow cleaner steam to be generated from lower quality feedwater. In drum boilers, water circulates in one zone. By analyzing circulation fundamentals (notably heat flux and void fraction), the design of multiple circulation zones was envisaged to separate the clean water from the contaminated water. Working with distinct circulation zones would allow the quality of the steam from low quality feedwater to be improved, all the while maintaining the blowdown. The new design would result in a boiler which is easier to clean and would meet ASME criteria.

  3. Electron Microscopic and Spectroscopic Characterization for Soot Source Differentiation by Laser Derivatization

    Science.gov (United States)

    Gaddam, Chethan K.

    by electron energy loss spectroscopy (EELS), showing significant differences between particles as large as 60%. The nanostructure of soots from different transportation sources (such as diesel, jet and gasoline engines) evolved distinctively upon laser annealing. Laser derivatization of soot collected from same platform (engine-type) revealed that fuel commonality leads to similar nanostructure for the same class of combustion source, whereas, fuel dependence and ensuing chemistry differences were prominently illustrated by comparison of laser-annealed soots originating from ultra-low sulfur diesel (ULSD) and an oxygenated fuel blend. The origin for this dependence was identified by X-ray photoelectron spectroscopy (XPS), revealing a significantly lower sp2/sp3 carbon bonding for the oxygenated fuels compared to their pure hydrocarbon fuels. As another example, laser annealing of residential boiler soot produced highly intertwined lamellae; this was attributed to inherent chemistry differences relative to the biodiesel (B100) soot that similarly lacked recognizable nanostructure. These observations suggest that the initial soot nanostructure in conjunction with the chemistry of construction governs the material transformation under pulsed laser annealing. (Abstract shortened by ProQuest.).

  4. DESIGN OPTIMIZATION AND EXPERIMENTAL STUDY ON THE BLOWER FOR FLUFFS COLLECTION SYSTEM

    Directory of Open Access Journals (Sweden)

    C. N. JAYAPRAGASAN

    2017-05-01

    Full Text Available Centrifugal fans play an important role in the fluffs collection system for industrial cleaner. Therefore it has become necessary to study on the parameters which influences the performance of the blower. Parameters chosen for optimization are - fan outer diameter, number of blades and fan blade angle. Taguchi’s orthogonal array method helps to find out the optimum number of cases and the modelling has been carried out using SOLIDWORKS. ICEM CFD is used for meshing the blowers and analysed using FLUENT. In this study, analytical results are compared with experimental values. ANOVA is used to find out the percentage contribution of parameters on the output. Using Minitab software the optimum combination is identified. The result shows that the optimum combinations are 190 mm outer diameter, 80° blade angle and 8 numbers of blades.

  5. Pellet wood gasification boiler / Combination boiler. Market review. 7. ed.; Scheitholzvergaser-/Kombikessel. Marktuebersicht

    Energy Technology Data Exchange (ETDEWEB)

    Uth, Joern

    2010-08-15

    In the market review under consideration on pellet wood gasification boilers and combination boilers, the Federal Ministry of Food, Agriculture and Consumer Protection (Bonn, Federal Republic of Germany) report on planning and installation of wood-fired heating systems, recommendations regarding to the technical assessment of boiler systems, buffers/combination boilers, prices of pellet wood gasification boilers, data sheets of the compared pellet wood gasification boilers, pellet wood combination boilers, prices of pellet wood combination boilers, data sheets of the compared pellet wood gasification boilers, list of providers.

  6. Market review. Pellet wood gasification boiler / combination boiler. 8. ed.; Marktuebersicht. Scheitholzvergaser-/Kombikessel

    Energy Technology Data Exchange (ETDEWEB)

    Uth, Joern

    2012-01-15

    In the market review under consideration on pellet wood gasification boilers and combination boilers, the Federal Ministry of Food, Agriculture and Consumer Protection (Bonn, Federal Republic of Germany) reports on planning and installation of wood-fired heating systems, recommendations regarding to the technical assessment of boiler systems, buffers/combination boilers, prices of pellet wood gasification boilers, data sheets of the compared pellet wood gasification boilers, pellet wood combination boilers, prices of pellet wood combination boilers, data sheets of the compared pellet wood gasification boilers, list of providers.

  7. PERLINDUNGAN HUKUM TERHADAP WHISTLE-BLOWER DALAM PENYELESAIAN TINDAK PIDANA KORUPSI

    OpenAIRE

    Astuti, Syafriana Novi

    2014-01-01

    Corruption is a serious problem, this criminal act could endanger the stability and safety in the society, social-economic, and also politic development, and could ruining the value of democracy and morality. In the corruption eradication, recently we heard about “whistle-blower” as one of the efforts in corruption eradication process. Whistle blower is the person that gives reports or witnessed about the existence of corruption assessment, he also the person who does corruption. The existenc...

  8. Fuel consumption in an air blower for agricultural use under different operating conditions

    OpenAIRE

    Silva, Robson L. da

    2017-01-01

    ABSTRACT Evaluation of fuel consumption in internal combustion engines (ICE) of agricultural machinery and equipment is important in determining the performance under various operating conditions, especially when using biofuels. This study consisted of experimental evaluation of the gasoline (petrol)/ethanol consumption in a two-stroke 1-cylinder ICE, Otto cycle, functioning as an air blower for agriculture and related applications. A methodology for tests of non-automotive ICE, based on ABNT...

  9. A study on the boiler efficiency influenced by the boiler operation parameter in fossil power plant

    International Nuclear Information System (INIS)

    Kwon, Y. S.; Suh, J. S.

    2002-01-01

    The main reason to analyze the boiler operation parameter in fossil power plant is to increase boiler high efficiency and energy saving movement in the government. This study intends to have trend and analyze the boiler efficiency influenced by the boiler parameter in sub-critical and super-critical type boiler

  10. Comparison between 3D and 1D simulations of a regenerative blower for fuel cell applications

    International Nuclear Information System (INIS)

    Badami, M.; Mura, M.

    2012-01-01

    Highlights: ► A hydrogen recirculation blower for automotive fuel cells applications is studied. ► A 3D CFD analysis has been carried out to better understand the internal flows of the machine. ► The CFD results are compared to a 1D model set up by the authors in previous works. ► The main hypotheses put forward for the theoretical 1D model are compatible with the 3D analysis. - Abstract: A 3D Computational Fluid Dynamics (CFD) analysis has been carried out to better understand the internal fluid dynamics of a regenerative blower used for hydrogen recirculation in a Proton Exchange Membrane (PEM), Fuel Cell (FC) utilized for automotive applications. The obtained results are used to highlight the motion of the fluid in the vanes and in the side channel of the machine and to verify the main hypotheses put forward concerning the theoretical 1D model set up by the authors in previous works on the basis of the momentum exchange theory. Finally, the CFD analysis has been used to point out the effect of the slope of the vanes on the performance of the regenerative blower, and the results have been compared with those obtained using of the 1D model.

  11. Modification and Application of a Leaf Blower-vac for Field Sampling of Arthropods.

    Science.gov (United States)

    Zou, Yi; van Telgen, Mario D; Chen, Junhui; Xiao, Haijun; de Kraker, Joop; Bianchi, Felix J J A; van der Werf, Wopke

    2016-08-10

    Rice fields host a large diversity of arthropods, but investigating their population dynamics and interactions is challenging. Here we describe the modification and application of a leaf blower-vac for suction sampling of arthropod populations in rice. When used in combination with an enclosure, application of this sampling device provides absolute estimates of the populations of arthropods as numbers per standardized sampling area. The sampling efficiency depends critically on the sampling duration. In a mature rice crop, a two-minute sampling in an enclosure of 0.13 m(2) yields more than 90% of the arthropod population. The device also allows sampling of arthropods dwelling on the water surface or the soil in rice paddies, but it is not suitable for sampling fast flying insects, such as predatory Odonata or larger hymenopterous parasitoids. The modified blower-vac is simple to construct, and cheaper and easier to handle than traditional suction sampling devices, such as D-vac. The low cost makes the modified blower-vac also accessible to researchers in developing countries.

  12. Thermal fragmentation and deactivation of combustion-generated soot particles

    KAUST Repository

    Raj, Abhijeet

    2014-09-01

    The effect of thermal treatment on diesel soot and on a commercial soot in an inert environment under isothermal conditions at intermediate temperatures (400-900°C) is studied. Two important phenomena are observed in both the soot samples: soot fragmentation leading to its mass loss, and loss of soot reactivity towards O2. Several experimental techniques such as high resolution transmission electron microscopy, electron energy loss spectroscopy, thermo-gravimetric analysis with mass spectrometry, elemental analysis, Fourier transform infrared spectroscopy and X-ray diffraction have been used to identify the changes in structures, functional groups such as oxygenates and aliphatics, σ and π bonding, O/C and H/C ratios, and crystallite parameters of soot particles, introduced by heat. A decrease in the size of primary particles and an increase in the average polycyclic aromatic hydrocarbon (PAH) size was observed in soots after thermal treatment. The activation energies of soot oxidation for thermally treated soot samples were found to be higher than those for the untreated ones at most conversion levels. The cyclic or acyclic aliphatics with sp3 hybridization were present in significant amounts in all the soot samples, but their concentration decreased with thermal treatment. Interestingly, the H/C and the O/C ratios of soot particles increased after thermal treatment, and thus, they do not support the decrease in soot reactivity. The increase in the concentration of oxygenates on soot surface indicate that their desorption from soot surface in the form of CO, CO2 and other oxygenated compounds may not be significant at the temperatures (400-900°C) studied in this work. © 2014 The Combustion Institute.

  13. 30 CFR 77.413 - Boilers.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Boilers. 77.413 Section 77.413 Mineral... Mechanical Equipment § 77.413 Boilers. (a) Boilers shall be equipped with guarded, well-maintained water... the gages shall be kept clean and free of scale and rust. (b) Boilers shall be equipped with automatic...

  14. 30 CFR 56.13030 - Boilers.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Boilers. 56.13030 Section 56.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Compressed Air and Boilers § 56.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges, pressure gauges...

  15. 30 CFR 57.13030 - Boilers.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Boilers. 57.13030 Section 57.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Compressed Air and Boilers § 57.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges, pressure...

  16. 29 CFR 1915.162 - Ship's boilers.

    Science.gov (United States)

    2010-07-01

    ... 29 Labor 7 2010-07-01 2010-07-01 false Ship's boilers. 1915.162 Section 1915.162 Labor Regulations... Ship's boilers. (a) Before work is performed in the fire, steam, or water spaces of a boiler where... dead boiler with the live system or systems shall be secured, blanked, and tagged indicating that...

  17. 46 CFR 61.05-10 - Boilers in service.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boilers in service. 61.05-10 Section 61.05-10 Shipping... INSPECTIONS Tests and Inspections of Boilers § 61.05-10 Boilers in service. (a) Each boiler, including superheater, reheater, economizer, auxiliary boiler, low-pressure heating boiler, and unfired steam boiler...

  18. CFB boilers in multifuel application

    International Nuclear Information System (INIS)

    Goral, D.; Krzton, B.

    2007-01-01

    Fuel flexibility characteristic for CFB boilers plays an important rule in industrial and utility size applications. Possibility to use wider range of fuels that has been long time considered as by-products or wastes and possibility to design boilers able to operate with alternative fuels is an important factor that improves fuel delivery security and plant economy. Presented article is based on similar publications that present Foster Wheeler's experience in design and delivery of the CFB boilers for wide range of coals and cofiring by- products of crude oil refining and coal processing. Aspects of biomass cofiring will be also presented. (author)

  19. Catalytic oxidation of soot over alkaline niobates

    International Nuclear Information System (INIS)

    Pecchi, G.; Cabrera, B.; Buljan, A.; Delgado, E.J.; Gordon, A.L.; Jimenez, R.

    2013-01-01

    Highlights: ► No previous reported studies about alkaline niobates as catalysts for soot oxidation. ► NaNbO 3 and KNbO 3 perovskite-type oxides show lower activation energy than other lanthanoid perovskite-type oxides. ► The alkaline niobate does not show deactivation by metal loss. - Abstract: The lack of studies in the current literature about the assessment of alkaline niobates as catalysts for soot oxidation has motivated this research. In this study, the synthesis, characterization and assessment of alkaline metal niobates as catalysts for soot combustion are reported. The solids MNbO 3 (M = Li, Na, K, Rb) are synthesized by a citrate method, calcined at 450 °C, 550 °C, 650 °C, 750 °C, and characterized by AAS, N 2 adsorption, XRD, O 2 -TPD, FTIR and SEM. All the alkaline niobates show catalytic activity for soot combustion, and the activity depends basically on the nature of the alkaline metal and the calcination temperature. The highest catalytic activity, expressed as the temperature at which combustion of carbon black occurs at the maximum rate, is shown by KNbO 3 calcined at 650 °C. At this calcination temperature, the catalytic activity follows an order dependent on the atomic number, namely: KNbO 3 > NaNbO 3 > LiNbO 3 . The RbNbO 3 solid do not follow this trend presumably due to the perovskite structure was not reached. The highest catalytic activity shown by of KNbO 3 , despite the lower apparent activation energy of NaNbO 3 , stress the importance of the metal nature and suggests the hypothesis that K + ions are the active sites for soot combustion. It must be pointed out that alkaline niobate subjected to consecutive soot combustion cycles does not show deactivation by metal loss, due to the stabilization of the alkaline metal inside the perovskite structure.

  20. Soot oxidation over NOx storage catalysts. Activity and deactivation

    International Nuclear Information System (INIS)

    Krishna, K.; Makkee, M.

    2006-01-01

    Soot oxidation activity and deactivation of NO x storage and reduction (NSR) catalysts containing Pt, K, and Ba supported on Al 2 O 3 , are studied under a variety of reaction conditions. K-containing catalysts decrease soot oxidation temperature with O 2 alone and the presence of Pt further enhance the activity due to synergetic effect. The active species responsible for synergism on Pt/K-Al 2 O 3 are unstable and cannot be regenerated. Soot oxidation temperature decreases by about 150 o C with NO+O 2 exhaust feed gas and under lean conditions NSR system acts as catalysed soot filter (CSF). The reactions that are mainly responsible for decreasing soot oxidation temperature are: (1) soot oxidation with NO 2 followed by NO recycles to NO 2 , and (2) soot oxidation with O 2 assisted by NO 2 . Only a part of the stored NO x that is decomposed at high temperatures under lean conditions is found to be useful for soot oxidation. NO x storage capacity of NSR catalysts decreases upon ageing under soot oxidising conditions. This will lead to a decreased soot oxidation activity on stored nitrate decomposition. Pt/K-Al 2 O 3 catalyst is more active, but least stable compared with Pt/Ba-Al 2 O 3 . (author)

  1. On the Response of Nascent Soot Nanostructure and Oxidative Reactivity to Photoflash Exposure

    Directory of Open Access Journals (Sweden)

    Wei Wang

    2017-07-01

    Full Text Available Soot particles are a kind of major pollutant from fuel combustion. To enrich the understanding of soot, this work focuses on investigating detailed influences of instantaneous external irradiation (conventional photoflash exposure on nanostructure as well as oxidation reactivity of nascent soot particles. By detailed soot characterizations flash can reduce the mass of soot and soot nanostructure can be reconstructed substantially without burning. After flash, the degree of soot crystallization increases while the soot reactive rate decreases and the activation energy increases. In addition, nanostructure and oxidative reactivity of soot in air and Ar after flash are different due to their different thermal conductivities.

  2. Hybrid model of steam boiler

    International Nuclear Information System (INIS)

    Rusinowski, Henryk; Stanek, Wojciech

    2010-01-01

    In the case of big energy boilers energy efficiency is usually determined with the application of the indirect method. Flue gas losses and unburnt combustible losses have a significant influence on the boiler's efficiency. To estimate these losses the knowledge of the operating parameters influence on the flue gases temperature and the content of combustible particles in the solid combustion products is necessary. A hybrid model of a boiler developed with the application of both analytical modelling and artificial intelligence is described. The analytical part of the model includes the balance equations. The empirical models express the dependence of the flue gas temperature and the mass fraction of the unburnt combustibles in solid combustion products on the operating parameters of a boiler. The empirical models have been worked out by means of neural and regression modelling.

  3. ENERGY STAR Certified Commercial Boilers

    Data.gov (United States)

    U.S. Environmental Protection Agency — Certified models meet all ENERGY STAR requirements as listed in the Version 1.0 ENERGY STAR Program Requirements for Commercial Boilers that are effective as of...

  4. Boiler-turbine life extension

    Energy Technology Data Exchange (ETDEWEB)

    Natzkov, S. [TOTEMA, Ltd., Sofia (Bulgaria); Nikolov, M. [CERB, Sofia (Bulgaria)

    1995-12-01

    The design life of the main power equipment-boilers and turbines is about 105 working hours. The possibilities for life extension are after normatively regulated control tests. The diagnostics and methodology for Boilers and Turbines Elements Remaining Life Assessment using up to date computer programs, destructive and nondestructive control of metal of key elements of units equipment, metal creep and low cycle fatigue calculations. As well as data for most common damages and some technical decisions for elements life extension are presented.

  5. Sooting Characteristics and Modeling in Counterflow Diffusion Flames

    KAUST Repository

    Wang, Yu

    2013-11-01

    Soot formation is one of the most complex phenomena in combustion science and an understanding of the underlying physico-chemical mechanisms is important. This work adopted both experimental and numerical approaches to study soot formation in laminar counterfl ow diffusion flames. As polycyclic aromatic hydrocarbons (PAHs) are the precursors of soot particles, a detailed gas-phase chemical mechanism describing PAH growth upto coronene for fuels with 1 to 4 carbon atoms was validated against laminar premixed and counter- flow diffusion fl ames. Built upon this gas-phase mechanism, a soot model was then developed to describe soot inception and surface growth. This soot model was sub- sequently used to study fuel mixing effect on soot formation in counterfl ow diffusion flames. Simulation results showed that compared to the baseline case of the ethylene flame, the doping of 5% (by volume) propane or ethane in ethylene tends to increase the soot volume fraction and number density while keeping the average soot size almost unchanged. These results are in agreement with experimental observations. Laser light extinction/scattering as well as laser induced fluorescence techniques were used to study the effect of strain rate on soot and PAH formation in counterfl ow diffusion ames. The results showed that as strain rate increased both soot volume fraction and PAH concentrations decreased. The concentrations of larger PAH were more sensitive to strain rate compared to smaller ones. The effect of CO2 addition on soot formation was also studied using similar experimental techniques. Soot loading was reduced with CO2 dilution. Subsequent numerical modeling studies were able to reproduce the experimental trend. In addition, the chemical effect of CO2 addition was analyzed using numerical data. Critical conditions for the onset of soot were systematically studied in counterfl ow diffusion ames for various gaseous hydrocarbon fuels and at different strain rates. A sooting

  6. CFD Simulation On CFBC Boiler

    Directory of Open Access Journals (Sweden)

    Amol S. Kinkar

    2015-02-01

    Full Text Available Abstract Heavy industrialization amp modernization of society demands in increasing of power cause to research amp develop new technology amp efficient utilization of existing power units. Variety of sources are available for power generation such as conventional sources like thermal hydro nuclear and renewable sources like wind tidal biomass geothermal amp solar. Out of these most common amp economical way for producing the power is by thermal power stations. Various industrial boilers plays an important role to complete the power generation cycle such as CFBC Circulating Fluidized Bed Combustion FBC Fluidized Bed Combustion AFBC Atmospheric Fluidized Bed Combustion Boiler CO Boiler RG amp WHR Boiler Waster heat recovery Boiler. This paper is intended to comprehensively give an account of knowledge related to refractory amp its failure in CFBC boiler with due effect of flue gas flow during operation on refractory by using latest technology of CAD Computer aided Design amp CAE Computer aided Engineering. By conceptual application of these technology the full scale model is able to analyze in regards the flow of flue gas amp bed material flow inside the CFBC loop via CFD Computational Fluid Dynamics software. The results obtained are helpful to understand the impact of gas amp particles on refractory in different areas amp also helped to choose suitable refractory material in different regions.

  7. Empirical soot formation and oxidation model

    Directory of Open Access Journals (Sweden)

    Boussouara Karima

    2009-01-01

    Full Text Available Modelling internal combustion engines can be made following different approaches, depending on the type of problem to be simulated. A diesel combustion model has been developed and implemented in a full cycle simulation of a combustion, model accounts for transient fuel spray evolution, fuel-air mixing, ignition, combustion, and soot pollutant formation. The models of turbulent combustion of diffusion flame, apply to diffusion flames, which one meets in industry, typically in the diesel engines particulate emission represents one of the most deleterious pollutants generated during diesel combustion. Stringent standards on particulate emission along with specific emphasis on size of emitted particulates have resulted in increased interest in fundamental understanding of the mechanisms of soot particulate formation and oxidation in internal combustion engines. A phenomenological numerical model which can predict the particle size distribution of the soot emitted will be very useful in explaining the above observed results and will also be of use to develop better particulate control techniques. A diesel engine chosen for simulation is a version of the Caterpillar 3406. We are interested in employing a standard finite-volume computational fluid dynamics code, KIVA3V-RELEASE2.

  8. Comparison of particle emissions from small heavy fuel oil and wood-fired boilers

    Science.gov (United States)

    Sippula, Olli; Hokkinen, Jouni; Puustinen, Harri; Yli-Pirilä, Pasi; Jokiniemi, Jorma

    Flue gas emissions of wood and heavy fuel oil (HFO) fired district heating units of size range 4-15 MW were studied. The emission measurements included analyses of particle mass, number and size distributions, particle chemical compositions and gaseous emissions. Thermodynamic equilibrium calculations were carried out to interpret the experimental findings. In wood combustion, PM1 (fine particle emission) was mainly formed of K, S and Cl, released from the fuel. In addition PM1 contained small amounts of organic material, CO 3, Na and different metals of which Zn was the most abundant. The fine particles from HFO combustion contained varying transient metals and Na that originate from the fuel, sulphuric acid, elemental carbon (soot) and organic material. The majority of particles were formed at high temperature (>800 °C) from V, Ni, Fe and Na. At the flue gas dew point (125 °C in undiluted flue gas) sulphuric acid condensed forming a liquid layer on the particles. This increases the PM1 substantially and may lead to partial dissolution of the metallic cores. Wood-fired grate boilers had 6-21-fold PM1 and 2-23-fold total suspended particle (TSP) concentrations upstream of the particle filters when compared to those of HFO-fired boilers. However, the use of single field electrostatic precipitators (ESP) in wood-fired grate boilers decreased particle emissions to same level or even lower as in HFO combustion. On the other hand, particles released from the HFO boilers were clearly smaller and higher in number concentration than those of wood boilers with ESPs. In addition, in contrast to wood combustion, HFO boilers produce notable SO 2 emissions that contribute to secondary particle formation in the atmosphere. Due to vast differences in concentrations of gaseous and particle emissions and in the physical and chemical properties of the particles, HFO and wood fuel based energy production units are likely to have very different effects on health and climate.

  9. Technical Note: The single particle soot photometer fails to reliably detect PALAS soot nanoparticles

    Directory of Open Access Journals (Sweden)

    M. Gysel

    2012-12-01

    Full Text Available The single particle soot photometer (SP2 uses laser-induced incandescence (LII for the measurement of atmospheric black carbon (BC particles. The BC mass concentration is obtained by combining quantitative detection of BC mass in single particles with a counting efficiency of 100% above its lower detection limit. It is commonly accepted that a particle must contain at least several tenths of a femtogram BC in order to be detected by the SP2.

    Here we show the result that most BC particles from a PALAS spark discharge soot generator remain undetected by the SP2, even if their BC mass, as independently determined with an aerosol particle mass analyser (APM, is clearly above the typical lower detection limit of the SP2. Comparison of counting efficiency and effective density data of PALAS soot with flame generated soot (combustion aerosol standard burner, CAST, fullerene soot and carbon black particles (Cabot Regal 400R reveals that particle morphology can affect the SP2's lower detection limit. PALAS soot particles are fractal-like agglomerates of very small primary particles with a low fractal dimension, resulting in a very low effective density. Such loosely packed particles behave like "the sum of individual primary particles" in the SP2's laser. Accordingly, most PALAS soot particles remain undetected as the SP2's laser intensity is insufficient to heat the primary particles to their vaporisation temperature because of their small size (Dpp ≈ 5–10 nm. Previous knowledge from pulsed laser-induced incandescence indicated that particle morphology might have an effect on the SP2's lower detection limit, however, an increase of the lower detection limit by a factor of ∼5–10, as reported here for PALAS soot, was not expected.

    In conclusion, the SP2's lower detection limit at a certain laser power depends primarily on the total BC mass per particle for compact particles with sufficiently high effective

  10. Testicular cancer trends as 'whistle blowers' of testicular developmental problems in populations

    DEFF Research Database (Denmark)

    Skakkebaek, N E; Rajpert-De Meyts, E; Jørgensen, N

    2007-01-01

    /disorders of sex differentiation and male fertility problems may be symptoms with varying penetration. In spite of their fetal origin, most of the TDS symptoms, including TGCC and poor semen quality, can only be diagnosed in adulthood. Data from a Danish-Finnish research collaboration strongly suggest that trends...... in TGCC rates of a population may be 'whistle blowers' of other reproductive health problems. As cancer registries are often of excellent quality - in contrast to registries for congenital abnormalities - health authorities should consider an increase in TGCC as a warning that other reproductive health...

  11. Room acoustic analysis of blower unit and noise control plan in the typical steel industry

    Directory of Open Access Journals (Sweden)

    2013-02-01

    Full Text Available Introduction: In the steel industry,air blowers used to supply compressed air are considered as sources of annoying noise. This study aims to acoustics analysis of theairblower workroomand sound source characteristics in order to present noise controlmeasuresinthe steel industry. .Material and Method: Measurement of noiselevel and its frequency analysis was performed usingsound levelmetermodelof CASELLA-Cell.450. Distribution of noise level in the investigated workroom in form of noise map was provided using Surfer software. In addition, acoustic analysis of workroom and control room was performed in view point of soundabsorption andinsulation. Redesignofdoor and window of controlroom and installation of soundabsorbing materialson theceiling of the workroom were proposed and the efficiency of these interventionswasestimated. .Result: The totalsound pressurelevelin the blower workroom was 95.4 dB(L and the dominant frequency was 2000Hz. Sound pressure level inside the room control was 80.1dB(A. The average absorption coefficient and reverberation time in the blower workroom was estimated equal to 0.082 Sab.m2 and 3.9 seconds respectively. These value in control room was 0.04 Sab.m2 and 3/4 seconds respectively. In control room, sound transmission loss between the two parts of the wall dividing was 13.7 dB(A. The average of noise dose in blower operators was 230%. With the installation of sound absorber on ceiling of workroom, average of absorption coefficient can increase to 0.33 Sab.m2 and sound transmission loss of the new designed door and window was estimated equal to 20dB. . Conclusion: The main cause of noise leakage in the control room was insufficient insulation properties of door and windows. By replacing the door and window and installation of sound absorbing on ceiling of workroom, the noise dose can reduce to 49.6%. New Improved door and window of control room can reduce noise dose to 69.65% solely.

  12. Failure analysis of boiler tube

    International Nuclear Information System (INIS)

    Mehmood, K.; Siddiqui, A.R.

    2007-01-01

    Boiler tubes are energy conversion components where heat energy is used to convert water into high pressure superheated steam, which is then delivered to a turbine for electric power generation in thermal power plants or to run plant and machineries in a process or manufacturing industry. It was reported that one of the tubes of a fire-tube boiler used in a local industry had leakage after the formation of pits at the external surface of the tube. The inner side of the fire tube was working with hot flue gasses with a pressure of 10 Kg/cm/sup 2/ and temperature 225 degree C. The outside of the tube was surrounded by feed water. The purpose of this study was to determine the cause of pits developed at the external surface of the failed boiler tube sample. In the present work boiler tube samples of steel grade ASTM AI61/ASTM A192 were analyzed using metallographic analysis, chemical analysis, and mechanical testing. It was concluded that the appearance of defects on the boiler tube sample indicates cavitation type corrosion failure. Cavitation damage superficially resembled pitting, but surface appeared considerably rougher and had many closely spaced pits. (author)

  13. Optimizing the Integrated Design of Boilers - Simulation

    DEFF Research Database (Denmark)

    Sørensen, K.; Karstensen, C.; Condra, T.

    2004-01-01

    Boilers can be considered as consisting of three main components: (i) the pressure part, (ii) the burner and (iii) the control system. To be able to develop the boilers of the future (i.e. the boilers with the lowest emissions, the highest efciency, the best dynamic performance etc....... Traditionally boiler control systems have been designed in a rather simple manner consisting of a feed water controller and a pressure controller; two controllers which, in principle, operated without any interaction - for more details on boiler control see [4]. During the last year Aalborg Industries A/S has...... into account. The present study covers re-tube boilers. To be able to minimize the size (i.e. volume) of the boiler and, at the same time, obtain the best possible dynamic performance, it is important to minimize the water level uctuations in the boiler as much as possible. In the present study a detailed...

  14. Pumice in the interglacial Whidbey Formation at Blowers Bluff, central Whidbey Island, WA, USA

    Science.gov (United States)

    Dethier, D.P.; Dragovich, J.D.; Sarna-Wojcicki, A. M.; Fleck, R.J.

    2008-01-01

    A new 40Ar/39Ar age of 128??9 ka and chemical analyses of pumice layers from interglacial alluvium at Blowers Bluff, Whidbey Island, WA, show that the deposits are part of the Whidbey Formation, a widespread, mainly subsurface unit. Glass chemistry of the dated dacitic pumice does not match any analyzed northern Cascade source, but upper Pleistocene dacites from Glacier Peak and early Pleistocene silicic rocks from the Kulshan caldera are chemically similar. The chemistry of pumiceous dacite in younger units, including the latest Pleistocene Partridge Gravel, is similar to that of the dated material. The deep troughs of the modern northern Puget lowland must have been filled during deposition of the Whidbey Formation, allowing volcanic-rich sediment to reach what is now Whidbey Island. Topographic analysis of LIDAR images demonstrates that extensive erosion occurred during latest Pleistocene ice retreat. The Partridge Gravel likely records subglacial fluvial erosion along an ice tunnel and ice-marginal deposition into adjacent marine waters. Pumice in the Partridge Gravel probably was reworked from stratigraphically and topographically lower deposits, including those at Blowers Bluff. ?? 2007 Elsevier Ltd and INQUA.

  15. ECUT energy data reference series: boilers

    Energy Technology Data Exchange (ETDEWEB)

    Chockie, A.D.; Johnson, D.R.

    1984-09-01

    Information on the population and fuel consumption of water-tube, fire-tube and cast iron boilers is summarized. The use of each boiler type in the industrial and commercial sector is examined. Specific information on each boiler type includes (for both 1980 and 2000) the average efficiency of the boiler, the capital stock, the amount of fuel consumed, and the activity level as measured by operational load factor.

  16. Aromatics oxidation and soot formation in flames

    Energy Technology Data Exchange (ETDEWEB)

    Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T. [Massachusetts Institute of Technology, Cambridge (United States)

    1993-12-01

    This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify and to determine or confirm rate constants for the main benzene oxidation reactions in flames, and to characterize fullerenes and their formation mechanisms and kinetics.

  17. Fractal-like dimension of nanometer Diesel soot particles

    Energy Technology Data Exchange (ETDEWEB)

    Skillas, G.; Baltensperger, U. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Siegmann, K. [Eidgenoessische Technische Hochschule, Zurich (Switzerland)

    1997-11-01

    Measurements with a low-pressure impactor and a differential mobility analyser were conducted for Diesel soot at various engine loads. By means of these measurements a fractal-like dimension of Diesel soot particles, with diameters ranging from 55 up to 260 nm, was established. (author) 2 figs., 7 refs.

  18. Modeling polychlorinated biphenyl sorption isotherms for soot and coal

    NARCIS (Netherlands)

    Jantunen, A.P.K.; Koelmans, A.A.; Jonker, M.T.O.

    2010-01-01

    Sorption isotherms (pg-ng/L) were measured for 11 polychlorinated biphenyls (PCBs) of varying molecular planarity from aqueous solution to two carbonaceous geosorbents, anthracite coal and traffic soot. All isotherms were reasonably log-log-linear, but smooth for traffic soot and staircase-shaped

  19. Mutagenicity of diesel exhaust soot dispersed in phospholipid surfactants

    Energy Technology Data Exchange (ETDEWEB)

    Wallace, W.; Keane, M.; Xing, S.; Harrison, J.; Gautam, M.; Ong, T.

    1994-06-01

    Organics extractable from respirable diesel exhaust soot particles by organic solvents have been known for some time to be direct acting frameshift mutagens in the Ames Salmonella typhimurium histidine reversion assay. Upon deposition in a pulmonary alveolus or respiratory bronchiole, respirable diesel soot particles will contact first the hypophase which is coated by and laden with surfactants. To model interactions of soot and pulmonary surfactant, the authors dispersed soots in vitro in the primary phospholipid pulmonary surfactant dipalmitoyl glycerophosphorylcholine (lecithin) (DPL) in physiological saline. They have shown that diesel soots dispersed in lecithin surfactant can express mutagenic activity, in the Ames assay system using S. typhimurium TA98, comparable to that expressed by equal amounts of soot extracted by dichloromethane/dimethylsulfoxide (DCM/DMSO). Here the authors report additional data on the same system using additional exhaust soots and also using two other phospholipids, dipalmitoyl glycerophosphoryl ethanolamine (DPPE), and dipalmitoyl phosphatidic acid (DPPA), with different ionic character hydrophilic moieties. A preliminary study of the surfactant dispersed soot in an eucaryotic cell test system also is reported.

  20. Sootblowing optimization for improved boiler performance

    Science.gov (United States)

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J.

    2012-12-25

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  1. Site radiography in boiler industry

    International Nuclear Information System (INIS)

    Hemachandran, P.

    1977-01-01

    Isotope radiography enjoys a unique position in radiography of weldments made at erection sites of industrial boilers. It also faces problems due to unfavourable conditions existing in these sites. The over-all approach to radiography at boiler erection sites has been dealt with. The advantages of modern X-ray and gamma ray equipment for these particular applications are discussed. A few useful accessories which reduce the complexity of source positioning and allied problems due to elevated position are suggested. Safety problems at sites are also dealt with. (author)

  2. Cracking and corrosion recovery boiler

    Energy Technology Data Exchange (ETDEWEB)

    Suik, H. [Tallinn Technical University, Horizon Pulp and Paper, Tallinn (Estonia)

    1998-12-31

    The corrosion of heat surfaces and the cracking the drums are the main problems of the recovery boiler. These phenomena have been appeared during long-term operation of boiler `Mitsubishi - 315` erected at 1964. Depth of the crack is depending on the number of shutdowns and on operation time. Corrosion intensity of different heat surfaces is varying depend on the metal temperature and the conditions at place of positioning of tube. The lowest intensity of corrosion is on the bank tubes and the greatest is on the tubes of the second stage superheater and on the tubes at the openings of air ports. (orig.) 5 refs.

  3. Computational Investigation of Soot and Radiation in Turbulent Reacting Flows

    Science.gov (United States)

    Lalit, Harshad

    This study delves into computational modeling of soot and infrared radiation for turbulent reacting flows, detailed understanding of both of which is paramount in the design of cleaner engines and pollution control. In the first part of the study, the concept of Stochastic Time and Space Series Analysis (STASS) as a numerical tool to compute time dependent statistics of radiation intensity is introduced for a turbulent premixed flame. In the absence of high fidelity codes for large eddy simulation or direct numerical simulation of turbulent flames, the utility of STASS for radiation imaging of reacting flows to understand the flame structure is assessed by generating images of infrared radiation in spectral bands dominated by radiation from gas phase carbon dioxide and water vapor using an assumed PDF method. The study elucidates the need for time dependent computation of radiation intensity for validation with experiments and the need for accounting for turbulence radiation interactions for correctly predicting radiation intensity and consequently the flame temperature and NOx in a reacting fluid flow. Comparison of single point statistics of infrared radiation intensity with measurements show that STASS can not only predict the flame structure but also estimate the dynamics of thermochemical scalars in the flame with reasonable accuracy. While a time series is used to generate realizations of thermochemical scalars in the first part of the study, in the second part, instantaneous realizations of resolved scale temperature, CO2 and H2O mole fractions and soot volume fractions are extracted from a large eddy simulation (LES) to carry out quantitative imaging of radiation intensity (QIRI) for a turbulent soot generating ethylene diffusion flame. A primary motivation of the study is to establish QIRI as a computational tool for validation of soot models, especially in the absence of conventional flow field and measured scalar data for sooting flames. Realizations of

  4. Studies of propane flame soot acting as heterogeneous ice nuclei in conjunction with single particle soot photometer measurements

    Directory of Open Access Journals (Sweden)

    I. Crawford

    2011-09-01

    Full Text Available The ice nucleation efficiency of propane flame soot particles with and without a sulphuric acid coating was investigated using the aerosol and cloud chamber facility AIDA (Aerosol Interaction and Dynamics in the Atmosphere. The test soot for cloud formation simulations was produced using a propane flame Combustion Aerosol Standard generator (CAST, Jing-CAST Technologies. The organic carbon content (OC of the test soot was altered in a reproducible fashion by changing the fuel/air mixture of the generator. The soot content of ice nuclei was subsequently investigated using a combination of a pumped counterflow virtual impactor (PCVI to separate and evaporate the ice crystals, and a DMT single particle soot photometer (SP2 to examine the mixing state of the BC containing ice residuals.

    Ice nucleation was found to be most efficient for uncoated soot of low organic carbon content (~5 % organic carbon content where deposition freezing occurred at an ice saturation ratio Sice ~ 1.22 at a temperature T = 226.6 K with 25 % of the test soot becoming active as ice nuclei. Propane flame soot of higher organic carbon content (~30 % and ~70 % organic carbon content showed significantly lower ice nucleation efficiency (an activated fraction of the order of a few percent in the experiments than the low organic carbon content soot, with water saturation being required for freezing to occur. Ice nucleation occurred over the range Sice = 1.22–1.70, and T = 223.2–226.6 K. Analysis of the SP2 data showed that the 5 % organic carbon content soot had an undetectable OC coating whereas the 30 % organic carbon content soot had a thicker or less volatile OC coating.

    The application of a sulphuric acid coating to the flame soot shifted the threshold of the onset of freezing towards that of the homogeneous freezing of sulphuric acid; for the minimum OC flame soot this inhibited nucleation since the

  5. The application of 'innovative' QC activities in the online monitoring system of DVC air blower

    International Nuclear Information System (INIS)

    Xia Hao; Li Xiaoquan

    2012-01-01

    Large quantities of practice from the domestic and abroad has proved that the QC (quantity control) group activity is one kind of effective way that large employee can participate in improving the built-up quality. The QC group activity is so effective because it follows a scientific procedure which can bring on better purpose with less time and cost. It is introduced a new method of the online monitoring system of DVC AIR BLOWER according to the use of 'innovative' QC activities with new thought and creative way in this paper, according to the introduce of this method. we can explore a new way of the solution to the problem in the future. (author)

  6. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    Energy Technology Data Exchange (ETDEWEB)

    Mike Bockelie; Marc Cremer; Kevin Davis; Temi Linjewile; Connie Senior; Hong-Shig Shim; Bob Hurt; Eric Eddings; Larry Baxter

    2003-01-30

    This is the tenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, progress was made on the computational simulation of a full-scale boiler with the purpose of understanding the potential impacts of burner operating conditions on soot and NO{sub x} generation. Sulfation tests on both the titania support and vanadia/titania catalysts were completed using BYU's in situ spectroscopy reactor this quarter. These experiments focus on the extent to which vanadia and titania sulfate in an SO{sub 2}-laden, moist environment. Construction of the CCS reactor system is essentially complete and the control hardware and software are largely in place. A large batch of vanadia/titania catalyst in powder form has been prepared for use in poisoning tests. During this quarter, minor modifications were made to the multi-catalyst slipstream reactor and to the control system. The slipstream reactor was installed at AEP's Rockport plant at the end of November 2002. In this report, we describe the reactor system, particularly the control system, which was created by REI specifically for the reactor, as well as the installation at Rockport.

  7. A new approach for function approximation in boiler combustion optimization based on modified structural AOSVR

    Energy Technology Data Exchange (ETDEWEB)

    Si, F.Q.; Romero, C.E.; Yao, Z.; Xu, Z.G.; Morey, R.L.; Liebowitz, B.N. [Lehigh University, Bethlehem, PA (United States). Energy Research Center

    2009-05-15

    In the scheme of boiler combustion optimization, a group of optimal controller settings is found to provide recommendations to balance desired thermal efficiency and lowest emissions limit. Characteristic functions between particular objectives and controlling variables can be approximated based on data sets obtained from field tests. These relationships can change with variations in coal quality, slag/soot deposits and the condition of plant equipment, which can not be sampled on-line. Thus, approximation relationships based on test conditions could have little applicability for on-line optimization of the combustion process. In this paper, a new approach is proposed to adaptively perform function approximation based on a modified accurate on-line support vector regression method. Two modified criteria are proposed for selection of the unwanted trained sample to be removed. A structural matrix is used to process and save the model parameters and training data sets, which can be adaptively regulated by the online learning method. The proposed method is illustrated with an example and is also applied to real boiler data successfully. The results reveal their validity in the prediction of NOx emissions and function approximation, which can correctly be adapted to actual variable operating conditions in the boiler.

  8. Biomass boiler still best choice

    International Nuclear Information System (INIS)

    Wallace, Paula

    2014-01-01

    Full text: The City of Mount Gambier upgraded its boiler in September after analysis showed that biomass was still the optimal energy option. The Mount Gambier Aquatic Centre was built by the local city council in the 1980s as an outdoor pool facility for the public. The complex has three pools — an Olympic-sized, toddler and a learner pool — for a total volume of 1.38ML (including balance tanks). The large pool is heated to 27-28°C, the smaller one 30-32°C. From the very beginning, the pool water was heated by a biomass boiler, and via two heat exchangers whose combined capacity is 520 kW. The original biomass boiler ran on fresh sawdust from a local timber mill. After thirty years of dedicated service the original boiler had become unreliable and difficult to operate. Replacement options were investigated and included a straight gas boiler, a combined solar hot water and gas option, and biomass boilers. The boiler only produces heat, not electricity. All options were subjected to a triple bottom line assessment, which included potential capital costs, operating costs, community and environmental benefits and costs. The project was also assessed using a tool developed by Mount Gambier City Council that considers the holistic benefits — the CHAT Tool, which stands for Comprehensive Holistic Assessment Tool. “Basically it is a survey that covers environmental, social, economic and governance factors,” the council's environmental sustainability officer, Aaron Izzard told WME. In relation to environmental considerations, the kinds of questions explored by the CHAT Tool included: Sustainable use of resources — objective is to reduce council's dependence on non-renewable resources; Greenhouse emissions — objective is to reduce council's contribution of GHG into the atmosphere; Air quality — objective is to improve local air quality. The conclusion of these analyses was that while a biomass boiler would have a higher capital cost than a

  9. Camphor soot: a tunable light emitter

    Science.gov (United States)

    Swapna, M. S.; Saritha Devi, H. V.; Sankararaman, S.

    2018-01-01

    The work in this paper is the first report on the green synthesis of the blue light emitter from waxy, flammable solid collected from Cinnamomum camphora by controlled combustion for photonic applications. Analysis with field emission scanning electron microscope and high-resolution transmission electron microscope provides the morphology, whereas the thermogravimetric analysis gives the thermal stability of the soot. The optical and structural characterizations are done by recording UV-Visible, Photoluminescent, and Raman Spectrum. The CIE plot and the power spectrum of the sample show a blue emission at an excitation of 350 nm at room temperature with a quantum yield of 46.15%. The dependence of luminescent behavior on temperature and excitation wavelength reveals that the material is a tunable blue emitter. This green synthesis of the blue light emitter is highly significant, when the world is in search of a simple, phosphor-free, non-toxic, cost-effective material with good quantum efficiency.

  10. Visualizing the mobility of silver during catalytic soot oxidation

    DEFF Research Database (Denmark)

    Gardini, Diego; Christensen, Jakob M.; Damsgaard, Christian Danvad

    2016-01-01

    The catalytic activity and mobility of silver nanoparticles used as catalysts in temperature programmed oxidation of soot:silver (1:5 wt:wt) mixtures have been investigated by means of flow reactor experiments and in situ environmental transmission electron microscopy (ETEM). The carbon oxidation...... temperature was significantly lower compared to uncatalyzed soot oxidation with soot and silver loosely stirred together (loose contact) and lowered further with the two components crushed together (tight contact). The in situ TEM investigations revealed that the silver particles exhibited significant...

  11. Towards predictive simulations of soot formation: from surrogate to turbulence

    Energy Technology Data Exchange (ETDEWEB)

    Blanquart, Guillaume [California Inst. of Technology (CalTech), Pasadena, CA (United States)

    2017-03-28

    The combustion of transportation fuels leads to the formation of several kinds of pollutants, among which are soot particles. These particles, also formed during coal combustion and in fires, are the source of several health problems and environmental issues. Unfortunately, our current understanding of the chemical and physical phenomena leading to the formation of soot particles remains incomplete, and as a result, the predictive capability of our numerical tools is lacking. The objective of the work was to reduce the gap in the present understanding and modeling of soot formation both in laminar and turbulent flames. The effort spanned several length scales from the molecular level to large scale turbulent transport.

  12. Investigations of Sooting Laminar Coflow Diffusion Flames at Elevated Pressures

    KAUST Repository

    Steinmetz, Scott A.

    2016-12-01

    Soot is a common byproduct of hydrocarbon based combustion systems. It poses a risk to human and environmental health, and can negatively or positively affect combustor performance. As a result, there is significant interest in understanding soot formation in order to better control it. More recently, the need to study soot formation in engine relevant conditions has become apparent. One engine relevant parameter that has had little focus is the ambient pressure. This body of work focuses on the formation of soot in elevated pressure environments, and a number of investigations are carried out with this purpose. Laminar coflow diffusion flames are used as steady, simple soot producers. First, a commonly studied flame configuration is further characterized. Coflow flames are frequently used for fundamental flame studies, particularly at elevated pressures. However, they are more susceptible to buoyancy induced instabilities at elevated pressures. The velocity of the coflow is known to have an effect on flame stability and soot formation, though these have not been characterized at elevated pressures. A series of flames are investigated covering a range of flowrates, pressures, and nozzle diameters. The stability limits of coflow flames in this range is investigated. Additionally, an alternative strategy for scaling these flames to elevated pressures is proposed. Finally, the effect of coflow rate on soot formation is evaluated. Identification of fundamental flames for coordinated research can facilitate our understanding of soot formation. The next study of this work focuses on adding soot concentration and particle size information to an existing fundamental flame dataset for the purpose of numerical model validation. Soot volume fraction and average particle diameters are successfully measured in nitrogen-diluted ethylene-air laminar coflow flames at pressures of 4, 8, 12, and 16 atm. An increase in particle size with pressure is found up to 12 atm, where particle

  13. Characterization and reactivity of soot from fast pyrolysis of lignocellulosic compounds and monolignols

    DEFF Research Database (Denmark)

    Trubetskaya, Anna; Brown, Avery; Tompsett, Geoffrey

    2018-01-01

    This study presents the effect of lignocellulosic compounds and monolignols on the yield, nanostructure and reactivity of soot generated at 1250 °C in a drop tube furnace. The structure of soot was characterized by electron microscopy techniques, Raman spectroscopy and electron spin resonance spe...... of the extraction solvent had a strong influence on the soot reactivity. The Soxhlet extraction of softwood and wheat straw lignin soot using methanol decreased the soot reactivity, whereas acetone extraction had only a modest effect....

  14. 46 CFR 52.25-20 - Exhaust gas boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING POWER BOILERS Other Boiler Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure...

  15. 46 CFR 63.25-1 - Small automatic auxiliary boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Small automatic auxiliary boilers. 63.25-1 Section 63.25... AUXILIARY BOILERS Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-1 Small automatic auxiliary boilers. Small automatic auxiliary boilers defined as having heat-input ratings of 400,000 Btu/hr...

  16. Drum rotor blowers in EC technology. Energy conservation, comfortable control, low noise; Trommellaeufer-Ventilatoren in EC-Technik. Energieersparnis, komfortable Regelung und geringe Geraeuschentwicklung

    Energy Technology Data Exchange (ETDEWEB)

    Sigloch, U. [ebm-papst Mulfingen GmbH und Co. KG (Germany). Projektmanagement Vertrieb Europa; Reiff, E.C. [Redaktionsbuero Stutensee (Germany)

    2008-07-01

    Compact drum rotor blowers with forward-curved blades are quite common in air conditioning and ventilation because of their high efficiency and compact dimensions. They are found in air conditioner boxes, in air current systems in department stores, or in fan coils in hotel rooms, wherever other types of blowers would be too big. Until recently, EC technology was not available for the blower motors so the users had do accept low efficiency and the poor control options of conventional AC drives. This has changed by now. (orig.)

  17. Soot, unburned carbon and ultrafine particle emissions from air- and oxy-coal flames

    International Nuclear Information System (INIS)

    Morris, W.J.; Yu, Dunxi; Wendt, J.O.L.

    2010-01-01

    Oxy-coal combustion is one possible solution for the mitigation of greenhouse gases. In this process coal is burned in oxygen, rather than air, and the temperatures in the boiler are mitigated by recycling flue gases, so that the inlet mixture may contain either 27 % O 2 to match adiabatic flame temperatures, or 32 % O 2 to match gaseous radiation heat fluxes in the combustion chamber. However, a major issue for heat transfer from coal combustion is the radiative heat transmission from soot. For this research, air and oxy coal firing were compared regarding the emission of soot. A 100 kW down-fired laboratory combustor was used to determine effects of switching from air to oxy-firing on soot, unburned carbon and ultrafine particle emissions from practical pulverized coal flames. Of interest here were potential chemical effects of substitution of the N 2 in air by CO 2 in practical pulverized coal flames. The oxy-coal configuration investigated used once-through CO 2 , simulating cleaned flue gas recycle with all contaminants and water removed. Three coals were each burned in: a) air, b) 27 % O 2 / 73 % CO 2 , c) 32 % O 2 / 68 % CO 2 . Tests were conducted at (nominally) 3 %, 2 %, 1 % and 0 % O 2 in the exhaust (dry basis). For each condition, particulate samples were iso kinetically withdrawn far from the radiant zone, and analyzed using a photoacoustic analyzer (PA) for black carbon, a scanning mobility particle sizer (SMPS) for ultrafine particles, and a total sample loss on ignition (LOI) method for unburned carbon in ash. Data suggest that at low stoichiometric ratios, ultrafine particles consist primarily of black carbon, which, for the bituminous coal, is produced in lesser amounts under oxy-fired conditions than under the air-fired condition, even when adiabatic flame temperatures are matched. However, significant changes in mineral matter vaporization were not observed unless the flames were hotter. These and other results are interpreted in the light of

  18. Ultrasensitive, Fast-Response Size-Dependent Soot Spectrometer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to develop a "black carbon" (soot) monitor for measuring non-volatile particulate emissions from gas turbine engines employing a proprietary optical...

  19. Water interaction with hydrophobic and hydrophilic soot particles.

    Science.gov (United States)

    Popovicheva, Olga; Persiantseva, Natalia M; Shonija, Natalia K; DeMott, Paul; Koehler, Kirsten; Petters, Markus; Kreidenweis, Sonia; Tishkova, Victoria; Demirdjian, Benjamin; Suzanne, Jean

    2008-05-07

    The interaction of water with laboratory soots possessing a range of properties relevant for atmospheric studies is examined by two complementary methods: gravimetrical measurement of water uptake coupled with chemical composition and porosity analysis and HTDMA (humidified tandem differential mobility analyzer) inference of water uptake accompanied by separate TEM (transmission electron microscopy) analysis of single particles. The first method clarifies the mechanism of water uptake for bulk soot and allows the classification of soot with respect to its hygroscopicity. The second method highlights the dependence of the soot aerosol growth factor on relative humidity (RH) for quasi-monodisperse particles. Hydrophobic and hydrophilic soot are qualitatively defined by their water uptake and surface polarity: laboratory soot particles are thus classified from very hydrophobic to very hydrophilic. Thermal soot particles produced from natural gas combustion are classified as hydrophobic with a surface of low polarity since water is found to cover only half of the surface. Graphitized thermal soot particles are proposed for comparison as extremely hydrophobic and of very low surface polarity. Soot particles produced from laboratory flame of TC1 aviation kerosene are less hydrophobic, with their entire surface being available for statistical monolayer water coverage at RH approximately 10%. Porosity measurements suggest that, initially, much of this surface water resides within micropores. Consequently, the growth factor increase of these particles to 1.07 at RH > 80% is attributed to irreversible swelling that accompanies water uptake. Hysteresis of adsorption/desorption cycles strongly supports this conclusion. In contrast, aircraft engine soot, produced from burning TC1 kerosene in a gas turbine engine combustor, has an extremely hydrophilic surface of high polarity. Due to the presence of water soluble organic and inorganic material it can be covered by many water

  20. Numerical Investigation of Soot Formation in Non-premixed Flames

    KAUST Repository

    Abdelgadir, Ahmed Gamaleldin

    2017-05-01

    Soot is a carbon particulate formed as a result of the combustion of fossil fuels. Due to the health hazard posed by the carbon particulate, government agencies have applied strict regulations to control soot emissions from road vehicles, airplanes, and industrial plants. Thus, understanding soot formation and evolution is critical. Practical combustion devices operate at high pressure and in the turbulent regime. Elevated pressures and turbulence on soot formation significantly and fundamental understanding of these complex interactions is still poor. In this study, the effects of pressure and turbulence on soot formation and growth are investigated numerically. As the first step, the evolution of the particle size distribution function (PSDF) and soot particles morphology are investigated in turbulent non-premixed flames. A Direct Simulation Monte Carlo (DSMC) code is developed and used. The stochastic reactor describes the evolution of soot in fluid parcels following Lagrangian trajectories in a turbulent flow field. The trajectories are sampled from a Direct Numerical Simulation (DNS) of an n-heptane turbulent non-premixed flame. Although individual trajectories display strong bimodality as in laminar flames, the ensemble-average PSDF possesses only one mode and a broad tail, which implies significant polydispersity induced by turbulence. Secondly, the effect of the flow and mixing fields on soot formation at atmospheric and elevated pressures is investigated in coflow laminar diffusion flames. The experimental observation and the numerical prediction of the spatial distribution are in good agreement. Based on the common scaling methodology of the flames (keeping the Reynolds number constant), the scalar dissipation rate decreases as pressure increases, promoting the formation of PAH species and soot. The decrease of the scalar dissipation rate significantly contributes to soot formation occurring closer to the nozzle and outward on the flames wings as pressure

  1. Investigating Soot Morphology in Counterflow Flames at Elevated Pressures

    KAUST Repository

    Amin, Hafiz Muhammad Fahid

    2018-01-01

    Practical combustion devices such as gas turbines and diesel engines operate at high pressures to increase their efficiency. Pressure significantly increases the overall soot yield. Morphology of these ultra-fine particles determines their airborne lifetime and their interaction with the human respiratory system. Therefore, investigating soot morphology at high pressure is of practical relevance. In this work, a novel experimental setup has been designed and built to study the soot morphology at elevated pressures. The experimental setup consists of a pressure vessel, which can provide optical access from 10° to 165° for multi-angle light scattering, and a counterflow burner which produces laminar flames at elevated pressures. In the first part of the study, N2-diluted ethylene/air and ethane air counterflow flames are stabilized from 2 to 5 atm. Two-angle light scattering and extinction technique have been used to study the effects of pressure on soot parameters. Path averaged soot volume fraction is found to be very sensitive to pressure and increased significantly from 2 to 5 atm. Primary particle size and aggregate size also increased with pressure. Multi-angle light scattering is also performed and flames are investigated from 3 to 5 atm. Scattering to absorption ratio is calculated from multi-angle light scattering and extinction data. Scattering to absorption ratio increased with pressure whereas the number of primary particles in an aggregate decreased with increasing pressure. In the next part of the study, Thermophoretic Sampling of soot is performed, in counterflow flames from 3 to 10 atm, followed by transmission electron microscopy. Mean primary particle size increased with pressure and these trends are consistent withour light scattering measurements. Fractal properties of soot aggregates are found to be insensitive to pressure. 2D diffused light line of sight attenuation (LOSA) and Laser Induced Incandescence (LII) are used to measure local soot

  2. Inception report and gap analysis. Boiler inspection

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-06-01

    This inception and gap analysis report on boilers in Latvia, has been prepared in the framework of the 'Implementation of the EU directive on energy performance of buildings: development of the Latvian Scheme for energy auditing of building and inspection of boilers'. The report is the basis for the establishment of training of boiler inspectors; it develops a gap analysis for better understanding and estimating the number of installations in Latvia and develops suggestions for the institutional set up. In particular includes information on existing standard and regulation on boiler, suggestion for the content of the training material of experts for boiler inspections and a syllabus of the training course. A specific section is dedicated to the suggestion for certification system of trained boiler inspectors. (au)

  3. Further development of recovery boiler; Soodakattilan kehitystyoe

    Energy Technology Data Exchange (ETDEWEB)

    Janka, K.; Siiskonen, P.; Sundstroem, K. [Tampella Power Oy, Tampere (Finland)] [and others

    1996-12-01

    The global model of a recovery boiler was further developed. The aim is to be able to model the velocity, temperature and concentration fields in a boiler. At this moment the model includes submodels for: droplet drying, pyrolysis, char burning, gas burning and for droplet trajectory. The preliminary study of NO{sub x} and fly ash behaviour in a boiler was carried out. The study concerning flow field in the superheater area was carried out a 2-dimensional case in which the inflow parameters were taken from global model of a recovery boiler. Further the prediction methods of fouling in a recovery boiler were developed based on theoretical calculations of smelting behaviour of multicomponent mixtures and measurements at operating recovery boilers. (author)

  4. The reduction of soot formation from fuels using oxygenates additives

    International Nuclear Information System (INIS)

    Burshaid, K.I.; Hamdan, M.A.

    2013-01-01

    Highlights: ► Understanding of the performance of thermo chemical heat pump. ► Tool for storing thermal energy. ► Parameters that affect the amount of thermal stored energy. ► Lithium chloride has better effect on storing thermal energy. - Abstract: This work presents an experimental technique for the measurement of the soot formation in pure fuel, biofuel and emulsified fuel, that constitute this fuels was studied in heated shock tube and investigated the possibility of reducing soot production in locally refined diesel, locally produced biofuel and emulsified fuel. This reduction was conducted using certain oxygenated additives (methane, ethane and acetone). It was found that soot concentration is maximum when pure diesel was burned, followed by emulsified fuels and the lease concentration was obtained when biofuel was burned. Further, methanol has the most significant effect on the reduction of soot once added to each fuel, while acetone has the lease effect on soot reduction. The results gave good indication of the effect for oxygenated additives in reduction the soot formation.

  5. Emission of ions and charged soot particles by aircraft engines

    Directory of Open Access Journals (Sweden)

    A. Sorokin

    2003-01-01

    Full Text Available In this article, a model which examines the formation and evolution of chemiions in an aircraft engine is proposed. This model which includes chemiionisation, electron thermo-emission, electron attachment to soot particles and to neutral molecules, electron-ion and ion-ion recombination, ion-soot interaction, allows the determination of the ion concentration at the exit of the combustor and at the nozzle exit of the engine. It also allows the determination of the charge of the soot particles. For the engine considered, the upper limit for the ion emission index EIi is of the order of (2-5 x1016 ions/kg-fuel if ion-soot interactions are ignored and the introduction of ion-soot interactions lead about to a 50% reduction. The results also show that most of the soot particles are either positively or negatively charged, the remaining neutral particles representing approximately 20% of the total particles. A comparison of the model results with the available ground-based experimental data obtained on the ATTAS research aircraft engines during the SULFUR experiments (Schumann, 2002 shows an excellent agreement.

  6. Durable superhydrophobic carbon soot coatings for sensor applications

    Science.gov (United States)

    Esmeryan, K. D.; Radeva, E. I.; Avramov, I. D.

    2016-01-01

    A novel approach for the fabrication of durable superhydrophobic (SH) carbon soot coatings used in quartz crystal microbalance (QCM) based gas or liquid sensors is reported. The method uses modification of the carbon soot through polymerization of hexamethyldisiloxane (HMDSO) by means of glow discharge RF plasma. The surface characterization shows a fractal-like network of carbon nanoparticles with diameter of ~50 nm. These particles form islands and cavities in the nanometer range, between which the plasma polymerized hexamethyldisiloxane (PPHMDSO) embeds and binds to the carbon chains and QCM surface. Such modified surface structure retains the hydrophobic nature of the soot and enhances its robustness upon water droplet interactions. Moreover, it significantly reduces the insertion loss and dynamic resistance of the QCM compared to the commonly used carbon soot/epoxy resin approach. Furthermore, the PPHMDSO/carbon soot coating demonstrates durability and no aging after more than 40 probing cycles in water based liquid environments. In addition, the surface layer keeps its superhydrophobicity even upon thermal annealing up to 540 °C. These experiments reveal an opportunity for the development of soot based SH QCMs with improved electrical characteristics, as required for high-resolution gas or liquid measurements.

  7. Uptake of HNO3 on hexane and aviation kerosene soots.

    Science.gov (United States)

    Talukdar, Ranajit K; Loukhovitskaya, Ekaterina E; Popovicheva, Olga B; Ravishankara, A R

    2006-08-10

    The uptake of HNO(3) on aviation kerosene (TC-1) soot was measured as a function of temperature (253-295 K) and the partial pressure of HNO(3), and the uptake of HNO(3) on hexane soot was studied at 295 K and over a limited partial pressure of HNO(3). The HNO(3) uptake was mostly reversible and did not release measurable amounts of gas-phase products such as HONO, NO(3), NO(2) or N(2)O(5). The heat of adsorption of HNO(3) on soot was dependent on the surface coverage. The isosteric heats of adsorption, Delta(0)H(isosteric), were determined as a function of coverage. Delta(0)H(isosteric) values were in the range -16 to -13 kcal mol(-1). The heats of adsorption decrease with increasing coverage. The adsorption data were fit to Freundlich and to Langmuir-Freundlich isotherms. The heterogeneity parameter values were close to 0.5, which suggested that a HNO(3) molecule can occupy two sites on the surface with or without being dissociated and that the soot surface could be nonuniform. Surface FTIR studies on the interaction of soot with HNO(3) did not reveal formation of any minor product such as organic nitrate or nitro compound on the soot surface. Using our measured coverage, we calculate that the partitioning of gas-phase nitric acid to black carbon aerosol is not a significant loss process of HNO(3) in the atmosphere.

  8. Durable superhydrophobic carbon soot coatings for sensor applications

    International Nuclear Information System (INIS)

    Esmeryan, K D; Radeva, E I; Avramov, I D

    2016-01-01

    A novel approach for the fabrication of durable superhydrophobic (SH) carbon soot coatings used in quartz crystal microbalance (QCM) based gas or liquid sensors is reported. The method uses modification of the carbon soot through polymerization of hexamethyldisiloxane (HMDSO) by means of glow discharge RF plasma. The surface characterization shows a fractal-like network of carbon nanoparticles with diameter of ∼50 nm. These particles form islands and cavities in the nanometer range, between which the plasma polymerized hexamethyldisiloxane (PPHMDSO) embeds and binds to the carbon chains and QCM surface. Such modified surface structure retains the hydrophobic nature of the soot and enhances its robustness upon water droplet interactions. Moreover, it significantly reduces the insertion loss and dynamic resistance of the QCM compared to the commonly used carbon soot/epoxy resin approach. Furthermore, the PPHMDSO/carbon soot coating demonstrates durability and no aging after more than 40 probing cycles in water based liquid environments. In addition, the surface layer keeps its superhydrophobicity even upon thermal annealing up to 540 °C. These experiments reveal an opportunity for the development of soot based SH QCMs with improved electrical characteristics, as required for high-resolution gas or liquid measurements. (paper)

  9. Measurement of Soot Deposition in Automotive Components Using Neutron Radiography

    International Nuclear Information System (INIS)

    Zekveld, David; Liu, Liaohui; Harrison, Andrew; Gill, Spencer; Harvel, Glenn; Chang, Jen-Shih

    2008-01-01

    About 40% of air pollution is generated by vehicles and transportation. The particulate matter (PM) emission significantly impacts human health. Fine particles below 2.5 μm (PM2.5) can enter the lungs and lead to respiratory problems. These particles not only influence human health, but also reduce the capability of many automobile exhaust heat exchanging devices. Neutron radiography is a non-destructive method of analyzing carbonaceous PM. While neutron radiography has been demonstrated for soot measurement in the past, the application has not considered the presence of unburned hydrocarbons, significant amounts of moisture nor examined complex geometrical configurations. The purpose of this work is to study a reliable non-destructive testing methodology using neutron radiography for measurement of soot distribution in automotive components. A soot standard (aluminium target) was designed and manufactured as a calibration tool. The standard is radiographed and used to measure the differences between various soot thickness and compositions. The radiograph images are analyzed to determine a calibration curve based upon the composition of the materials which can then be used for analysis of the automotive components. Experiments are performed using a diesel engine to produce soot deposits on exhaust piping. Soot distribution on exhaust piping is measured using neutron radiography. (authors)

  10. Response to Comment on “Modeling Maximum Adsorption Capacities of Soot and Soot-like Materials for PAHs and PCBs”

    NARCIS (Netherlands)

    Noort, van P.C.M.; Jonker, M.T.O.; Koelmans, A.A.

    2005-01-01

    A comment by John C. Fetzer on modeling maximum adsorption capacities of soot and soot-like materials for PAH and PCB and the adsorption behavior of PAH on soots and on other adsorptive materials is presented. The authors (van Noort et al.) base their model on van der Waal's forces only. This may be

  11. Stress-Assisted Corrosion in Boiler Tubes

    Energy Technology Data Exchange (ETDEWEB)

    Preet M Singh; Steven J Pawel

    2006-05-27

    A number of industrial boilers, including in the pulp and paper industry, needed to replace their lower furnace tubes or decommission many recovery boilers due to stress-assisted corrosion (SAC) on the waterside of boiler tubes. More than half of the power and recovery boilers that have been inspected reveal SAC damage, which portends significant energy and economic impacts. The goal of this project was to clarify the mechanism of stress-assisted corrosion (SAC) of boiler tubes for the purpose of determining key parameters in its mitigation and control. To accomplish this in-situ strain measurements on boiler tubes were made. Boiler water environment was simulated in the laboratory and effects of water chemistry on SAC initiation and growth were evaluated in terms of industrial operations. Results from this project have shown that the dissolved oxygen is single most important factor in SAC initiation on carbon steel samples. Control of dissolved oxygen can be used to mitigate SAC in industrial boilers. Results have also shown that sharp corrosion fatigue and bulbous SAC cracks have similar mechanism but the morphology is different due to availability of oxygen during boiler shutdown conditions. Results are described in the final technical report.

  12. Boiler plants completed in record time

    International Nuclear Information System (INIS)

    Anon.

    2001-01-01

    Bubbling fluidised bed (BFB) combustion has steadily increased its share of the boiler market in recent years, particularly in the Nordic region, where it is particularly well-suited to handling the high moisture content biofuels produced and used by the forest products industry. Foster Wheeler is the world's leading supplier of fluidised bed combustion technology. Over 200 of the more than 300 fluidised bed boilers supplied by the company are circulating fluidised bed (CFB) designs, a market in which Foster Wheeler has more than a 40% share. Foster Wheeler Energia Oy supplied the Myllykoski project at Anjalankoski with a fluidised bed boiler, auxiliary steam boilers, and flue gas scrubber systems

  13. Developing Boiler Concepts as Integrated Units

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    2004-01-01

    With the objective to be able to optimize the design and operation of steam boiler concepts Aalborg Industries A/S [1] has together with Aalborg University, Institute of Energy Technology [9] carried out a development project paying special attention to the boiler concept as an integrated unit......, emissions and to obtain long time operation experiences with the boiler concept, a full scale prototype has been built and these tests have been accomplished on the prototype. By applying this integrated unit approach to the boiler concept development it has been possible to optimize the different building...

  14. Enhancing the efficiency of a three-lobe roots blower by means of by-passing gas to the working cavity through an ejector adaptor

    Science.gov (United States)

    Vizgalov, S. V.; Volkov, M. V.; Chekushkin, G. N.; Khisameev, I. G.

    2017-08-01

    A positive displacement Roots blower with two- or three-lobe straight-tooth or twisted rotors demonstrates high performance with small specific dimensions and is used to boost internal combustion engines, aerate tanks of treatment facilities, is employed in air and gas transport systems in the food, petrochemical and metallurgical industry. It is common knowledge that several solutions have been implemented in Roots blower designs with straight-tooth with three-lobe or more-lobes rotors. It is more practical to bypass a portion of the compressed gas to the working cavity of the blower through an ejector. The purpose of developing a mathematical model for a blower working in conjunction with an ejector adapter and the further research is to determine the efficiency of this scheme un-der different discharge pressure conditions and different ejector active flow temperatures (the gas cooling effect before the nozzle).

  15. Soot Surface Growth in Laminar Hydrocarbon/Air Diffusion Flames. Appendix B

    Science.gov (United States)

    El-Leathy, A. M.; Xu, F.; Kim, C. H.; Faeth, G. M.; Urban, D. L. (Technical Monitor); Yuan, Z.-G. (Technical Monitor)

    2001-01-01

    The structure and soot surface growth properties of round laminar jet diffusion flames were studied experimentally. Measurements were made along the axes of ethylene-, propylene-propane- and acetylene-benzene-fueled flames burning in coflowing air at atmospheric pressure with the reactants at normal temperature. The measurements included soot structure, soot concentrations, soot temperatures, major gas species concentrations, some radial species (H, OH and O) concentrations, and gas velocities. These measurements yielded the local flame properties that are thought to affect soot surface growth as well as local soot surface growth rates. When present results were combined with similar earlier observations of acetylene-fueled laminar jet diffusion flames, the results suggested that soot surface growth involved decomposition of the original fuel to form acetylene and H, which were the main reactants for soot surface growth, and that the main effect of the parent fuel on soot surface growth involved its yield of acetylene and H for present test conditions. Thus, as the distance increased along the axes of the flames, soot formation (which was dominated by soot surface growth) began near the cool core of the flow once acetylene and H appeared together and ended near the flame sheet when acetylene disappeared. Species mainly responsible for soot oxidation - OH and O2 were present throughout the soot formation region so that soot surface growth and oxidation proceeded at the same time. Present measurements of soot surface growth rates (corrected for soot surface oxidation) in laminar jet diffusion flames were consistent with earlier measurements of soot surface growth rates in laminar premixed flames and exhibited good agreement with existing Hydrogen-Abstraction/Carbon-Addition (HACA) soot surface growth mechanisms in the literature with steric factors in these mechanisms having values on the order of unity, as anticipated.

  16. Soot Surface Growth in Laminar Hydrocarbon/Air Diffusion Flames. Appendix J

    Science.gov (United States)

    El-Leathy, A. M.; Xu, F.; Kim, C. H.; Faeth, G. M.; Yuan, Z.-G. (Technical Monitor); Urban, D. L. (Technical Monitor); Yuan, Z.-G. (Technical Monitor)

    2003-01-01

    The structure and soot surface growth properties of round laminar jet diffusion flames were studied experimentally. Measurements were made along the axes of ethylene-, propylene-propane- and acetylene-benzene-fueled flames burning in coflowing air at atmospheric pressure with the reactants at normal temperature. The measurements included soot structure, soot concentrations, soot temperatures, major gas species concentrations, some radial species (H, OH and 0) concentrations, and gas velocities. These measurements yielded the local flame properties that are thought to affect soot surface growth as well as local soot surface growth rates. When present results were combined with similar earlier observations of acetylene-fueled laminar jet diffusion flames, the results suggested that soot surface growth involved decomposition of the original fuel to form acetylene and H, which were the main reactants for soot surface growth, and that the main effect of the parent fuel on soot surface growth involved its yield of acetylene and H for present test conditions. Thus, as the distance increased along the axes of the flames, soot formation (which was dominated by soot surface growth) began near the cool core of the flow once acetylene and H appeared together and ended near the flame sheet when acetylene disappeared. Species mainly responsible for soot oxidation - OH and 02 were present throughout the soot formation region so that soot surface growth and oxidation proceeded at the same time. Present measurements of soot surface growth rates (corrected for soot surface oxidation) in laminar jet diffusion flames were consistent with earlier measurements of soot surface growth rates in laminar premixed flames and exhibited good agreement with existing Hydrogen-Abstraction/Carbon-Addition (HACA) soot surface growth mechanisms in the literature with steric factors in these mechanisms having values on the order of unity, as anticipated.

  17. A Review on Diesel Soot Emission, its Effect and Control

    Directory of Open Access Journals (Sweden)

    R. Prasad

    2011-01-01

    Full Text Available The diesel engines are energy efficient, but their particulate (soot emissions are responsible of severe environmental and health problems. This review provides a survey on published information regarding diesel soot emission, its adverse effects on the human health, environment, vegetations, climate, etc. The legislations to limit diesel emissions and ways to minimize soot emission are also summarized. Soot particles are suspected to the development of cancer; cardiovascular and respiratory health effects; pollution of air, water, and soil; impact agriculture productivity, soiling of buildings; reductions in visibility; and global climate change. The review covers important recent developments on technologies for control of particulate matter (PM; diesel particulate filters (DPFs, summarizing new filter and catalyst materials and DPM measurement. DPF technology is in a state of optimization and cost reduction. New DPF regeneration strategies (active, passive and plasma-assisted regenerations as well as the new learning on the fundamentals of soot/catalyst interaction are described. Recent developments in diesel oxidation catalysts (DOC are also summarized showing potential issues with advanced combustion strategies, important interactions on NO2 formation, and new formulations for durability. Finally, systematic compilation of the concerned newer literature on catalytic oxidation of soot in a well conceivable tabular form is given. A total of 156 references are cited. ©2010 BCREC UNDIP. All rights reserved(Received: 2nd June 2010, Revised: 17th June 2010; Accepted: 24th June 2010[How to Cite: R. Prasad, V.R. Bella. (2010. Review on Diesel Soot Emission, its Effect and Control. Bulletin of Chemical Reaction Engineering and Catalysis, 5(2: 69-86. doi:10.9767/bcrec.5.2.794.69-86][DOI: http://dx.doi.org/10.9767/bcrec.5.2.794.69-86 || or local:   http://ejournal.undip.ac.id/index.php/bcrec/article/view/794 ]Cited by in: ACS 1 |

  18. Experimental determination of soot refractive index in the infrared

    International Nuclear Information System (INIS)

    Ouf, F.X.; Vendel, J.; Ouf, F.X.; Coppalle, A.; Weil, M.E.; Yon, J.

    2007-01-01

    The study of physical properties of soot particles produced during combustion is a complex subject but of a great interest within the framework of the study of the safety of an installation, with respect to the fire hazard. These characteristics are, in this case, particularly useful in order to predict the behaviour of containment barriers in situation of fire, but also in order to estimate the contribution of these particles to radiative transfers. The aim of this study is to determine the radiative properties of soot particles produced during combustion. A specific device, which establishes extinction and vertical-vertical scattering coefficients, has been developed and has allowed to determine the refractive index of soot particles in the infrared. This determination also needed the establishment of size distribution and morphological properties of soot aggregates. We present in this document the experimental device developed, and the validation of this device on latex spheres which optical properties are well known. First results of extinction coefficients will be presented and will underline the similar optical behaviour of different soot aggregates. Values of refractive index will be detailed and discussed, and a direct application of these values will be carried out in order to determine the soot volume fraction. A comparison with reference method will underline the efficiency of our method. We will conclude on the validity of the information brought by this device and on the prospects of this study. A discussion is included, on the utility of mean values of refractive index and on the determination of total emissivity of soot particles. (authors)

  19. Effects of inlet radius and bell mouth radius on flow rate and sound quality of centrifugal blower

    International Nuclear Information System (INIS)

    Son, Pham Ngoc; Kim, Jae Won; Byun, S. M.; Ahn, E. Y.

    2012-01-01

    The effect of inlet radius and bell mouth radius on flow rate of centrifugal blower were numerically simulated using a commercial CFD program, FLUENT. In this research, a total of eight numerical models were prepared by combining different values of bell mouth radii and inlet radii (the cross section of bell mouth was chosen as a circular arc in this research). The frozen rotor method combined with a realizable k-epsilon turbulence model and non-equilibrium wall function was used to simulate the three-dimensional flow inside the centrifugal blowers. The inlet radius was then revealed to have significant impact on flow rate with the maximum difference between analyzed models was about 4.5% while the bell mouth radius had about 3% impact on flow rate. Parallel experiments were carried out to confirm the results of CFD analysis. The CFD results were thereafter validated owning to the good agreement between CFD results and the parallel experiment results. In addition to performance analysis, noise experiments were carried out to analyze the dependence of sound quality on inlet radius and bell mouth radius with different flow rate. The noise experiment results showed that the loudness and sharpness value of different models were quite similar, which mean the inlet radius and the bell mouth radius didn't have a clear impact on sound quality of centrifugal blower

  20. 46 CFR 109.555 - Propulsion boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Propulsion boilers. 109.555 Section 109.555 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS OPERATIONS Miscellaneous § 109.555 Propulsion boilers. The master or person in charge and the engineer in charge shall...

  1. Developing Boiler Concepts as Integrated Units

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    2004-01-01

    - consisting of pressure part, burner and control system. The Technical University of Denmark, MEK - Energy Engineering Section [12] has participated in the modelling process. The project has included static and dynamic modelling of the boiler concept. For optimization of operation, verication of performance......With the objective to be able to optimize the design and operation of steam boiler concepts Aalborg Industries A/S [1] has together with Aalborg University, Institute of Energy Technology [9] carried out a development project paying special attention to the boiler concept as an integrated unit......, emissions and to obtain long time operation experiences with the boiler concept, a full scale prototype has been built and these tests have been accomplished on the prototype. By applying this integrated unit approach to the boiler concept development it has been possible to optimize the different building...

  2. Ignition delay and soot oxidative reactivity of MTBE blended diesel fuel

    KAUST Repository

    Yang, Seung Yeon

    2014-04-01

    Methyl tert-butyl ether (MTBE) was added to diesel fuel to investigate the effect on ignition delay and soot oxidative reactivity. An ignition quality tester (IQT) was used to study the ignition propensity of MTBE blended diesel fuels in a reactive spray environment. The IQT data showed that ignition delay increases linearly as the MTBE fraction increases in the fuel. A four-stroke single cylinder diesel engine was used to generate soot samples for a soot oxidation study. Soot samples were pre-treated using a tube furnace in a nitrogen environment to remove any soluble organic fractions and moisture content. Non-isothermal oxidation of soot samples was conducted using a thermogravimetric analyzer (TGA). It was observed that oxidation of \\'MTBE soot\\' started began at a lower temperature and had higher reaction rate than \\'diesel soot\\' across a range of temperatures. Several kinetic analyses including an isoconversional method and a combined model fitting method were carried out to evaluate kinetic parameters. The results showed that Diesel and MTBE soot samples had similar activation energy but the pre-exponential factor of MTBE soot was much higher than that of the Diesel soot. This may explain why MTBE soot was more reactive than Diesel soot. It is suggested that adding MTBE to diesel fuel is better for DPF regeneration since an MTBE blend can significantly influence the ignition characteristics and, consequently, the oxidative reactivity of soot. Copyright © 2014 SAE International.

  3. Microscopic investigation of soot and ash particulate matter derived from biofuel and diesel: implications for the reactivity of soot

    Science.gov (United States)

    Liati, Anthi; Spiteri, Alexander; Dimopoulos Eggenschwiler, Panayotis; Vogel-Schäuble, Nina

    2012-11-01

    Investigation of soot and ash particulate matter deposited in diesel particulate filters (DPFs) operating with biofuel (B100) and diesel (pure diesel: B0 and diesel80/biofuel20 blend: B20) by means of optical microscopy, scanning electron microscopy, and high resolution transmission electron microscopy (HRTEM) reveals the following: the rapeseed methyl ester biofuel used for this study contributes to ash production, mainly of Ca-S- and P-bearing compounds ranging in size between 50 and 300 nm. Smaller ash particles are less common and build aggregates. Ash is deposited on the inlet DPF surface, the inlet channel walls, and in B100-DPF at the plugged ends of inlet channels. The presence of Fe-Cr-Ni fragments, down to tens of nanometers in size within the ash is attributed to engine wear. Pt particles (50-400 nm large) within the ash indicate that the diesel oxidation catalyst (DOC) upstream of the DPF shows aging effects. Radial cracks on the coating layer of the DOC confirm this assumption. The B100-DPF contains significantly less soot than B20 and B0. Based on the generally accepted view that soot reactivity correlates with the nanostructure of its primary particles, the length and curvature of graphene sheets from biofuel- and diesel-derived soot were measured and computed on the basis of HRTEM images. The results show that biofuel-derived soot can be more easily oxidized than diesel soot, not only during early formation but also during and after considerable particle growth. Differences in the graphene sheet separation distance, degree of crystalline order and size of primary soot particles between the two fuel types are in line with this inference.

  4. Microscopic investigation of soot and ash particulate matter derived from biofuel and diesel: implications for the reactivity of soot

    International Nuclear Information System (INIS)

    Liati, Anthi; Spiteri, Alexander; Dimopoulos Eggenschwiler, Panayotis; Vogel-Schäuble, Nina

    2012-01-01

    Investigation of soot and ash particulate matter deposited in diesel particulate filters (DPFs) operating with biofuel (B100) and diesel (pure diesel: B0 and diesel 80 /biofuel 20 blend: B20) by means of optical microscopy, scanning electron microscopy, and high resolution transmission electron microscopy (HRTEM) reveals the following: the rapeseed methyl ester biofuel used for this study contributes to ash production, mainly of Ca–S– and P-bearing compounds ranging in size between 50 and 300 nm. Smaller ash particles are less common and build aggregates. Ash is deposited on the inlet DPF surface, the inlet channel walls, and in B100-DPF at the plugged ends of inlet channels. The presence of Fe–Cr–Ni fragments, down to tens of nanometers in size within the ash is attributed to engine wear. Pt particles (50–400 nm large) within the ash indicate that the diesel oxidation catalyst (DOC) upstream of the DPF shows aging effects. Radial cracks on the coating layer of the DOC confirm this assumption. The B100-DPF contains significantly less soot than B20 and B0. Based on the generally accepted view that soot reactivity correlates with the nanostructure of its primary particles, the length and curvature of graphene sheets from biofuel- and diesel-derived soot were measured and computed on the basis of HRTEM images. The results show that biofuel-derived soot can be more easily oxidized than diesel soot, not only during early formation but also during and after considerable particle growth. Differences in the graphene sheet separation distance, degree of crystalline order and size of primary soot particles between the two fuel types are in line with this inference.

  5. Chemical cleaning of UK AGR boilers

    International Nuclear Information System (INIS)

    Rudge, A.; Turner, P.; Ghosh, A.; Clary, W.; Tice, D.

    2002-01-01

    For the first time in their operational lives, UK advanced gas-cooled reactor once-through boilers have been chemically cleaned. Chemical cleaning was necessary to avoid lost output resulting from boiler pressure drops, which had been increasing for a number of years. Chemical cleaning of these boilers presents a number of unique difficulties. These include lack of access to the boilers, highly sensitised 316H superheater sections that cannot be excluded from the cleaning flow path, relatively thin boiler tube walls and an intolerance to boiler tube failure because of the role of the boilers in nuclear decay heat removal. The difficulties were overcome by implementing the clean in a staged manner, starting with an extensive materials testwork programme to select and then to substantiate the cleaning process. The selected process was based on ammoniated citric acid plus formic acid for the principal acid cleaning stage. Materials testwork was followed by an in-plant trial clean of six boiler tubes, further materials testwork and the clean of a boiler tube in a full-scale test rig. An overview is presented of the work that was carried out to demonstrate that the clean could be carried out safely, effectively and without leading to unacceptable corrosion losses. Full-scale chemical cleaning was implemented by using as much of the existing plant as possible. Careful control and monitoring was employed to ensure that the cleaning was implemented according to the specified design, thus ensuring that a safe and effective clean was carried out. Full-scale cleaning has resulted in significant boiler pressure drop recovery, even though the iron burden was relatively low and cleaning was completed in a short time. (orig.)

  6. PAH emission from the industrial boilers.

    Science.gov (United States)

    Li, C; Mi, H; Lee, W; You, W; Wang, Y

    1999-10-01

    Polycyclic aromatic hydrocarbons (PAHs) emitted from 25 industrial boilers were investigated. The fuels used for these 25 boilers included 21 heavy oil, two diesel, a co-combustion of heavy oil and natural gas (HO+NG) and a co-combustion of coke oven gas and blast furnace gas (COG+BFG) boilers. PAH samples from the stack flue gas (gas and particle phases) of these 25 boilers were collected by using a PAH stack sampling system. Twenty one individual PAHs were analyzed primarily by a gas chromatography/mass spectrometer (GC/MS). Total-PAH concentration in the flue gas of 83 measured data for these 25 boiler stacks ranged between 29.0 and 4250 microg/m(3) and averaged 488 microg/m(3). The average of PAH-homologue mass (F%) counted for the total-PAH mass was 54.7%, 9.47% and 15.3% for the 2-ring, 3-ring and 4-ring PAHs, respectively. The PAHs in the stack flue gas were dominant in the lower molecular weight PAHs. The emission factors (EFs) of total-PAHs were 13,300, 2920, 2880 and 208 microg/kg-fuel for the heavy oil, diesel, HO+NG and COG+BFG fueled-boiler, respectively. Nap was the most predominant PAH occurring in the stack flue gas. In addition, the EF of 21 individual PAHs in heavy-oil boiler were almost the highest among the four various fueled-boilers except for those of FL and BkF in the diesel boiler. Furthermore, the EF of total-PAHs or BaP for heavy oil were both one order of magnitude higher than that for the diesel-fueled boiler.

  7. Soot Superaggregates from Flaming Wildfires and Their Direct Radiative Forcing

    Science.gov (United States)

    Chakrabarty, Rajan K.; Beres, Nicholas D.; Moosmuller,Hans; China, Swarup; Mazzoleni, Claudio; Dubey, Manvendra K.; Liu, Li; Mishchenko, Michael I.

    2014-01-01

    Wildfires contribute significantly to global soot emissions, yet their aerosol formation mechanisms and resulting particle properties are poorly understood and parameterized in climate models. The conventional view holds that soot is formed via the cluster-dilute aggregation mechanism in wildfires and emitted as aggregates with fractal dimension D(sub f) approximately equals 1.8 mobility diameter D(sub m) (is) less than or equal to 1 micron, and aerodynamic diameter D(sub a) (is) less than or equal to 300 nm. Here we report the ubiquitous presence of soot superaggregates (SAs) in the outflow from a major wildfire in India. SAs are porous, low-density aggregates of cluster-dilute aggregates with characteristic D(sub f) approximately equals 2.6,D(sub m) (is) greater than 1 micron, and D(sub a) is less than or equal to 300 nm that form via the cluster-dense aggregation mechanism.We present additional observations of soot SAs in wildfire smoke-laden air masses over Northern California, New Mexico, and Mexico City. We estimate that SAs contribute, per unit optical depth, up to 35% less atmospheric warming than freshly-emitted (D(sub f) approximately equals 1.8) aggregates, and approximately equals 90% more warming than the volume-equivalent spherical soot particles simulated in climate models.

  8. Chinese Soot on a Vietnamese Soup

    Science.gov (United States)

    Mari, X.

    2015-12-01

    Black Carbon (BC) is an aerosol emitted as soot during biomass burning and fossil fuels combustion together with other carbonaceous aerosols such as organic carbon (OC) and polyaromatic hydrocarbons (PAHs). While the impacts of BC on health and climate have been studied for many years, studies about its deposition and impact on marine ecosystems are scares. This is rather surprising considering that a large fraction of atmospheric BC deposits on the surface of the ocean via dry or wet deposition. On a global scale, deposition on the ocean is about 45 Tg C per year, with higher fluxes in the northern hemisphere and in inter-tropical regions, following the occurrence of the hot-spots of concentration. In the present study conducted on shore, in Haiphong and Halong cities, North Vietnam, we measured the seasonal variations of atmospheric BC, OC and PAHs during a complete annual cycle. The presentation will discuss the atmospheric results in terms of seasonal variability and sources. Inputs to the marine system are higher during the dry season, concomitantly with the arrival of air masses enriched in BC coming from the North. However, the carbon fingerprint can significantly differ at shorter time periods depending on the air mass pathway and speed. Our work leads to the characterization and the determination of the relative contribution of more specific sources like local traffic, which includes tourism and fishing boats, coal dust emitted from the nearby mine, and long-range transported aerosols. This variable input of carbonaceous aerosols might have consequences for the cycling and the repartition of carbon and nutrients in the marine ecosystem of Halong Bay.

  9. Chemical cleaning of AGR boilers

    International Nuclear Information System (INIS)

    Moore, S.V.; Moore, W.; Rantell, A.

    1978-01-01

    AGR boilers are likely to require post service chemical cleaning to remove accumulated oxides at intervals of 15 - 35 kh. The need to clean will be based on an assessment of such factors as the development of flow imbalances through parallel tubes induced by the formation of rough oxide surfaces, an increasing risk of localised corrosion as the growth of porous oxides proceeds and the risk of tube blockage caused by the exfoliation of steam-grown oxides. The study has shown what heterogeneous multilayer oxides possessing a range of physical and chemical properties form on the alloy steels. They include porous and compact magnetites, chromium spinels and sesquioxide. Ammoniated citric acid has been shown to remove deposited and water-grown magnetites from the carbon and alloy steels but will not necessarily remove the substituted spinels grown on the alloy steels or the potentially spalling steam-grown magnetite on the A1SI 316 superheater. Citric acid supplemented with the reducing agent glyoxal completely removes all oxides from the boiler except the protective inner spinel formed on the 316. Removal of the spinels and compact magnetites occurs more by undercutting and physical detachment than by the dissolution. (author)

  10. Diesel soot aging in urban plumes within hours under cold dark and humid conditions.

    Science.gov (United States)

    Eriksson, A C; Wittbom, C; Roldin, P; Sporre, M; Öström, E; Nilsson, P; Martinsson, J; Rissler, J; Nordin, E Z; Svenningsson, B; Pagels, J; Swietlicki, E

    2017-09-28

    Fresh and aged diesel soot particles have different impacts on climate and human health. While fresh diesel soot particles are highly aspherical and non-hygroscopic, aged particles are spherical and hygroscopic. Aging and its effect on water uptake also controls the dispersion of diesel soot in the atmosphere. Understanding the timescales on which diesel soot ages in the atmosphere is thus important, yet knowledge thereof is lacking. We show that under cold, dark and humid conditions the atmospheric transformation from fresh to aged soot occurs on a timescale of less than five hours. Under dry conditions in the laboratory, diesel soot transformation is much less efficient. While photochemistry drives soot aging, our data show it is not always a limiting factor. Field observations together with aerosol process model simulations show that the rapid ambient diesel soot aging in urban plumes is caused by coupled ammonium nitrate formation and water uptake.

  11. Fast Soot Aging and Pronounced Diurnal Evolution of Size-dependent Soot Mixing State in the Megacity Beijing

    Science.gov (United States)

    Cheng, Y.; Su, H.; Wiedensohler, A.; Berghof, M.; Wehner, B.; Achtert, P.; Nowak, A.; Zhang, Y.; Shao, M.; Zhu, T.; Zeng, L.; Carmichael, G. R.

    2009-12-01

    The mixing state of soot has great implication in its optical and hygroscopic properties, and hence on its direct/indirect radiative effects. Up to date, understanding about the mechanism of the soot mixing state evolution is still poor and only a few techniques are able to measure the soot mixing state with a high-time and -size resolution. During the CAREBEIJING-2006 (Aug-Sep), a Volatility Tandem Differential Mobility Analyzer was applied to measure the soot mixture in a particle size range of 30 to 320 nm at a regional polluted site in the area of megacity Beijing [Wehner et al., 2009]. The number fraction of externally mixed soot (Fex) varied from 5 to 60% and showed a clear size-dependent diurnal variation. After a peak in the morning, Fex started decreasing and reached a minimum at around noon. Smaller particles reached the minimum earlier than the larger ones, i.e., Fex of 30 nm particles reached its minimum at 8:00-9:00 while that of 320 nm reached the minimum at 13:00-14:00. The different Fex variations among different sizes reflect a combined effect of size-dependent condensable vapor supersaturations and particle growth rates. Fast evolution of soot mixing states was found. During a typical day with new particle formation followed by continuously condensational growth [Wiedensohler et al., 2009], the coating enhancement in light absorption (σap) and scattering of coated soot can simultaneously reach up to a factor of 8-10 within several hours. It was contributed not only by the increasing thickness of coating shell but also by the fast transition from externally mixed soots to coated ones [Cheng et al., 2009]. The number fraction of coated soot (Fcoat) is strongly correlated with the photochemical aging process (e.g., OH time integrals (TOH) calculated by the ratio of m+p xylnene to ethylbenzen). Similar phenomena were found by Moteki et al. [2007] and Shiraiwa et al. [2007]. Interestingly, an “exponential decay” of the external mixed to coated

  12. Laser-induced incandescence: Towards quantitative soot volume fraction measurements

    Energy Technology Data Exchange (ETDEWEB)

    Tzannis, A.P.; Wienbeucker, F.; Beaud, P.; Frey, H.-M.; Gerber, T.; Mischler, B.; Radi, P.P. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    Laser-Induced Incandescence has recently emerged as a versatile tool for measuring soot volume fraction in a wide range of combustion systems. In this work we investigate the essential features of the method. LII is based on the acquisition of the incandescence of soot when heated through a high power laser pulse. Initial experiments have been performed on a model laboratory flame. The behaviour of the LII signal is studied experimentally. By applying numerical calculations we investigate the possibility to obtain two-dimensional soot volume fraction distributions. For this purpose a combination of LII with other techniques is required. This part is discussed in some extent and the future work is outlined. (author) 4 figs., 3 refs.

  13. 40 CFR 65.149 - Boilers and process heaters.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 15 2010-07-01 2010-07-01 false Boilers and process heaters. 65.149... System or a Process § 65.149 Boilers and process heaters. (a) Boiler and process heater equipment and operating requirements. (1) Owners or operators using boilers and process heaters to meet the 98 weight...

  14. 46 CFR 63.25-7 - Exhaust gas boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Exhaust gas boilers. 63.25-7 Section 63.25-7 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING AUTOMATIC AUXILIARY BOILERS Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-7 Exhaust gas boilers. (a) Construction...

  15. 49 CFR 230.30 - Lap-joint seam boilers.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Lap-joint seam boilers. 230.30 Section 230.30..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Inspection and Repair § 230.30 Lap-joint seam boilers. Every boiler having lap-joint longitudinal seams...

  16. 49 CFR 230.36 - Hydrostatic testing of boilers.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Hydrostatic testing of boilers. 230.36 Section 230... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Pressure Testing of Boilers § 230.36 Hydrostatic testing of boilers. (a) Time of test. The...

  17. Effect of lubricant additives on the prowear characteristics of synthetic diesel soots

    Energy Technology Data Exchange (ETDEWEB)

    Rounds, F.G.

    1986-01-01

    Soot in the crankcase of diesel engines promotes wear. The theory is that this soot preferentially adsorbs the active antiwear species, probably a zinc dithiophosphate (ZDP) decomposition product, before the protective antiwear surface coating can be formed on the rubbing surfaces. Previous studies indicated that the prowear characteristics of diesel soot depend on the engine operating conditions and the lubricant used. This observation suggested that, by properly formulating the oil, the adverse effects of the soot might be minimized.

  18. Ice Formation by Soot-Containing Aerosol Particles

    Science.gov (United States)

    Demott, P. J.; Petters, M. D.; Prenni, A. J.; Kreidenweis, S. M.; Carrico, C. M.; Bennett, M. R.; Stanglmaier, R.; Volckens, J.; Popovicheva, O. B.

    2006-12-01

    A role for soot particles as atmospheric ice forming nuclei remains highly uncertain and poorly quantified. A relatively small amount of data exists and most of this is for laboratory surrogates that may not be well characterized or of assured relevance to the atmosphere. It is important to constrain the role of soot particles as ice nuclei due to their abundance in the atmosphere and the large contribution from anthropogenic activities. Further, global climate models are beginning to be capable of treating the impact of different aerosol types, including soot particles. This paper reports on studies of ice formation by or within surrogates for hydrophobic soot and realistic carbonaceous particles from combustion of fuel in a diesel engine, burning of an assortment biomass materials, and real jet fuel combustor particles. Measurements of primarily monodisperse particles were focused below -30°C to emphasize the transition between temperatures where heterogeneous ice nucleation is required for ice formation and those for which homogeneous freezing processes are also possible. Ice nucleation measurements were made with a continuous flow diffusion chamber. Simultaneous measurements of hygroscopic water uptake and cloud condensation nucleation behavior were also made at 30°C for each aerosol type. Small fractions of hydrophobic soot particles are found capable of initiating heterogeneous ice formation at low temperatures. Results of studies of more realistic particles suggest that any process that increases hygroscopicity tends to limit the conditions for ice formation within soot particles. Most biomass burning particles, showing a range of dry/wet diameter hygroscopic growth factors (1.03 activity as CCN to 102% RH, yet behaved as particles containing solutions in which homogeneous freezing was supported at temperatures below -38°C. This is tentatively attributed to condensation of semi-volatiles during cooling. Ice forming ability as warm as -30°C was limited to

  19. Electrical design requirements for electrode boilers for nuclear plants

    International Nuclear Information System (INIS)

    Kempker, M.J.

    1979-01-01

    Medium-voltage steam electrode boilers, in the 20- to 50-MW range, have become an attractive alternative to comparable fossil-fueled boilers as a source of auxiliary steam during the startup and normal shutdown of nuclear power plants. The electrode boiler represents a favorable option because of environmental, fire protection, and licensing considerations. However, this electrical option brings some difficult design problems for which solutions are required in order to integrate the electrode boiler into the plant low resistance grounded power system. These considerations include the effects of an unbalanced electrode boiler on the performance of polyphase induction motors, boiler grounding for personnel safety, boiler neutral grounding, and ground relaying

  20. Environmental performance assessment of utility boiler energy conversion systems

    International Nuclear Information System (INIS)

    Li, Changchun; Gillum, Craig; Toupin, Kevin; Park, Young Ho; Donaldson, Burl

    2016-01-01

    Highlights: • Sustainability analyses of utility boilers are performed. • Natural gas fired boilers have the least CO 2 emissions in fossil fueled boilers. • Solar boilers rank last with an emergy yield ratio of 1.2. • Biomass boilers have the best emergy sustainability index. - Abstract: A significant amount of global electric power generation is produced from the combustion of fossil fuels. Steam boilers are one of the most important components for steam and electricity production. The objective of this paper is to establish a theoretical framework for the sustainability analysis of a utility boiler. These analyses can be used by decision-makers to diagnose and optimize the sustainability of a utility boiler. Seven utility boiler systems are analyzed using energy and embodied solar energy (emergy) principles in order to evaluate their environmental efficiencies. They include a subcritical coal fired boiler, a supercritical coal fired boiler, an oil fired boiler, a natural gas fired boiler, a concentrating solar power boiler utilizing a tower configuration, a biomass boiler, and a refuse derived fuel boiler. Their relative environmental impacts were compared. The results show that the natural gas boiler has significantly lower CO 2 emission than an equivalent coal or oil fired boiler. The refuse derived fuel boiler has about the same CO 2 emissions as the natural gas boiler. The emergy sustainability index of a utility boiler system is determined as the measure of its sustainability from an environmental perspective. Our analyses results indicate that the natural gas boiler has a relatively high emergy sustainability index compared to other fossil fuel boilers. Converting existing coal boilers to natural gas boilers is a feasible option to achieve better sustainability. The results also show that the biomass boiler has the best emergy sustainability index and it will remain a means to utilize the renewable energy within the Rankine steam cycle. Before

  1. New Nanotech from an Ancient Material: Chemistry Demonstrations Involving Carbon-Based Soot

    Science.gov (United States)

    Campbell, Dean J.; Andrews, Mark J.; Stevenson, Keith J.

    2012-01-01

    Carbon soot has been known since antiquity, but has recently been finding new uses as a robust, inexpensive nanomaterial. This paper describes the superhydrophobic properties of carbon soot films prepared by combustion of candle wax or propane gas and introduces some of the optical absorption and fluorescence properties of carbon soot particles.…

  2. Effects of dicarboxylic acid coating on the optical properties of soot.

    Science.gov (United States)

    Xue, Huaxin; Khalizov, Alexei F; Wang, Lin; Zheng, Jun; Zhang, Renyi

    2009-09-28

    Soot is a major component of atmospheric aerosols responsible for absorption of visible solar radiation. Internal mixing of soot with transparent materials can enhance its ability to absorb and scatter light, resulting in a larger role of soot in climate forcing. We have investigated the absorption and scattering of visible light (532 nm) by soot aerosol internally mixed with succinic and glutaric acids using a combination of a cavity ring-down spectrometer and an integrating nephelometer. The measurements were performed for flame-generated soot aerosol with well-characterized morphology and mixing state in the particle size range from 155 to 320 nm. Thin coatings of dicarboxylic acids on soot aggregates (with a mass fraction of 0.1-0.4) enhance significantly light scattering (up to 3.8 fold) and slightly light absorption (less than 1.2 fold). Cycling the coated soot aerosol through high relative humidity (humidified to 90% RH and then dried to 5% RH) promotes further increase in light absorption and scattering for soot internally mixed with glutaric acid, but not for soot mixed with succinic acid. The larger effect of glutaric acid on light absorption and scattering is caused by the irreversible restructuring of soot aggregates induced by the coating material. Our results indicate that the enhancement in the optical properties of soot by transparent coatings is strongly related to the ability of the coating materials to change the morphology of soot aggregates.

  3. Chemical cleaning of UK AGR boilers

    International Nuclear Information System (INIS)

    Rudge, A.; Turner, P.; Ghosh, S.; Clary, W.; Tice, D.R.

    2002-01-01

    For a number of years, the waterside pressure drops across the advanced gas-cooled reactor (AGR) pod boilers have been increasing. The pressure drop increases have accelerated with time, which is the converse behaviour to that expected for rippled magnetite formation (rapid initial increase slowing down with time). Nonetheless, magnetite deposition remains the most likely cause for the increasing boiler resistances. A number of potential countermeasures have been considered in response to the boiler pressure drop increases. However, there was no detectable reduction in the rate of pressure drop increase. Chemical cleaning was therefore considered and a project to substantiate and then implement chemical cleaning was initiated. (authors)

  4. Boiler economy. Terms and application

    International Nuclear Information System (INIS)

    Boehm, G.

    1995-01-01

    Economy calculations are nearly exclusively made by computers. Undisputed advantage is apart from the high speed in which even complex calculations are made the 'document character' of the printout. Disadvantageous is that apart from the soft manufacturer almost nobody knows the calculation formulations, basic assumptions and logical connections. One can only accept the result without being able to prove the 'correctness'. There is also hardly the possibility to gain knowledge as the reason for certain results is not explained. Based on known terms of boiler economy many questions arising in practice can be answered with sufficient accuracy. Excessive accuracy is with the many unknown or only estimated operating data anyhow not reasonable. (orig.) [de

  5. Treatment of Berkeley boilers in Studsvik. Project description and experiences - Berkeley Boilers Project

    International Nuclear Information System (INIS)

    Saul, Dave; Davidson, Gavin; Wirendal, Bo

    2014-01-01

    In November 2011 Studsvik was awarded a contract to transport five decommissioned boilers from the Berkeley Nuclear Licensed Site in the UK to the Studsvik Nuclear Site in Sweden for metal treatment and recycling. A key objective of the project was to remove the boilers from the site by 31 March 2012 and this was successfully achieved with all boilers off site by 22 March and delivered to Studsvik on 6 April. In November 2012 Studsvik was awarded a further contract for the remaining ten Berkeley Boilers with the requirement to remove all boilers from the Berkeley site by 31 March 2013. Again this was successfully achieved ahead of programme with all boilers in Sweden by 1 April 2013. A total of nine boilers have now been processed and all remaining boilers will be completed by end of September 2014. The projects have had many challenges including a very tight timescale and both have been successfully delivered to cost and ahead of the baseline programme. This paper describes the project and the experience gained from treatment of the boilers to date. (authors)

  6. Dynamics of flow–soot interaction in wrinkled non-premixed ethylene–air flames

    KAUST Repository

    Arias, Paul G.

    2015-08-17

    A two-dimensional simulation of a non-premixed ethylene–air flame was conducted by employing a detailed gas-phase reaction mechanism considering polycyclic aromatic hydrocarbons, an aerosol-dynamics-based soot model using a method of moments with interpolative closure, and a grey gas and soot radiation model using the discrete transfer method. Interaction of the sooting flame with a prescribed decaying random velocity field was investigated, with a primary interest in the effects of velocity fluctuations on the flame structure and the associated soot formation process for a fuel-strip configuration and a composition with mature soot growth. The temporally evolving simulation revealed a multi-layered soot formation process within the flame, at a level of detail not properly described by previous studies based on simplified soot models utilizing acetylene or naphthalene precursors for initial soot inception. The overall effect of the flame topology on the soot formation was found to be consistent with previous experimental studies, while a unique behaviour of localised strong oxidation was also noted. The imposed velocity fluctuations led to an increase of the scalar dissipation rate in the sooting zone, causing a net suppression in the soot production rate. Considering the complex structure of the soot formation layer, the effects of the imposed fluctuations vary depending on the individual soot reactions. For the conditions under study, the soot oxidation reaction was identified as the most sensitive to the fluctuations and was mainly responsible for the local suppression of the net soot production. © 2015 Taylor & Francis

  7. Physical and chemical characterization of residential oil boiler emissions.

    Science.gov (United States)

    Hays, Michael D; Beck, Lee; Barfield, Pamela; Lavrich, Richard J; Dong, Yuanji; Vander Wal, Randy L

    2008-04-01

    The toxicity of emissions from the combustion of home heating oil coupled with the regional proximity and seasonal use of residential oil boilers (ROB) is an important public health concern. Yet scant physical and chemical information about the emissions from this source is available for climate and air quality modeling and for improving our understanding of aerosol-related human health effects. The gas- and particle-phase emissions from an active ROB firing distillate fuel oil (commonly known as diesel fuel) were evaluated to address this deficiency. Ion chromatography of impactor samples showed that the ultrafine ROB aerosol emissions were approximately 45% (w/w) sulfate. Gas chromatography-mass spectrometry detected various n-alkanes at trace levels, sometimes in accumulation mode particles, and out of phase with the size distributions of aerosol mass and sulfate. The carbonaceous matter in the ROB aerosol was primarily light-adsorbing elemental carbon. Gas chromatography-atomic emission spectroscopy measured a previously unrecognized organosulfur compound group in the ROB aerosol emissions. High-resolution transmission electron microscopy of ROB soot indicated the presence of a highly ordered primary particle nanostructure embedded in larger aggregates. Organic gas emissions were measured using EPA Methods TO-15 and TO-11A. The ROB emitted volatile oxygenates (8 mg/(kg of oil burned)) and olefins (5 mg/(kg of oil burned)) mostly unrelated to the base fuel composition. In the final analysis, the ROB tested was a source of numerous hazardous air pollutants as defined in the Clean Air Act Amendments. Approximations conducted using emissions data from the ROB tests show relatively low contributions to a regional-level anthropogenic emissions inventory for volitile organic compounds, PM2.5, and SO2 mass.

  8. Modelling and simulating fire tube boiler performance

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    2003-01-01

    A model for a flue gas boiler covering the flue gas and the water-/steam side has been formulated. The model has been formulated as a number of sub models that are merged into an overall model for the complete boiler. Sub models have been defined for the furnace, the convection zone (split in 2......: a zone submerged in water and a zone covered by steam), a model for the material in the boiler (the steel) and 2 models for resp. the water/steam zone (the boiling) and the steam. The dynamic model has been developed as a number of Differential-Algebraic-Equation system (DAE). Subsequently Mat......Lab/Simulink has been applied for carrying out the simulations. To be able to verify the simulated results experiments has been carried out on a full scale boiler plant....

  9. Water side corrosion prevention in boilers

    International Nuclear Information System (INIS)

    Zeid, A.

    1993-01-01

    Corrosion may be defined as a naturally occurring physical and chemical deterioration of a material due to reaction with the environment or surrounding atmosphere. In boilers the material is subjected on both sides to two different media which may cause severe corrosion. At the water side the content of O 2 considered one of the principal factors which determine the extent of corrosion in the boiler tubes. This paper deals with certain conditions that result in the increase of O 2 in the boiler water and hence increase the corrosion rate, to minimize the effect of these conditions a chemical treatment was carried out the results obtained indicated the success of the treatment procedure in corrosion prevention and boiler material protection. The treatment is traditional. But the study indicates how a simple mean could be applied to solve a serious problem. 4 tab

  10. New thinking for the boiler room.

    Science.gov (United States)

    Rose, Wayne

    2008-09-01

    Wayne Rose, marketing manager at integrated plant room manufacturer Armstrong Integrated Systems, explains how increasing use of off-site manufacture, the latest 3D modelling technology, and advances in control technology, are revolutionising boiler room design and construction.

  11. Morphological effects on the radiative properties of soot aerosols in different internally mixing states with sulfate

    Science.gov (United States)

    Dong, J.; Zhao, J. M.; Liu, L. H.

    2015-11-01

    The radiative properties of soot aerosols largely depend on their mixing state and morphology factors. In this paper, we generated soot aggregates in four mixing states with sulfate, including bare soot, partly coated soot, heavily coated soot and soot with inclusion. The number of monomers and fractal dimension of soot were varied in each mixing state while the radius of monomers was fixed at 0.025 μm. Using the discrete dipole approximation method (DDA), we calculated optical parameters relevant for climate forcing simulation at mid-visible wavelength (0.55 μm). Internal mixing results in enhanced absorption, scattering cross sections as well as the single scattering albedo. The enhancement ratio of the absorption is largest for heavily coated soot, which ranges from 1.5 to 1.65 with a soot volume fraction of 0.15 and is larger for soot with larger fractal dimension. The scattering cross section can be dramatically increased by factors larger than 10 when soot is heavily coated. The increasing of both the scattering cross section and the single scattering albedo is larger for soot aggregates with smaller number of monomers and fractal dimension. The asymmetry parameter is insensitive to the fractal dimension for heavily coated soot and soot with inclusion. Two simplified models including the homogeneous sphere model (HS) and the core shell sphere model (CS) were examined using the DDA results as references. The performance of the HS and CS model largely depends on the morphology factors and the mixing state of soot. For bare and partly coated soot, both the HS and CS model can introduce relative errors as large as several tens percent. For heavily coated soot, the HS model predicts the absorption with relative errors within 10%, while it overestimates the absorption with relative errors no larger than 20% for soot with inclusion. The HS model predicts the single scattering albedo and the asymmetry parameter with relative errors no larger than 10% for heavily

  12. Nanoparticle production by UV irradiation of combustion generated soot particles

    International Nuclear Information System (INIS)

    Stipe, Christopher B.; Choi, Jong Hyun; Lucas, Donald; Koshland, Catherine P.; Sawyer, Robert F.

    2004-01-01

    Laser ablation of surfaces normally produce high temperature plasmas that are difficult to control. By irradiating small particles in the gas phase, we can better control the size and concentration of the resulting particles when different materials are photofragmented. Here, we irradiate soot with 193 nm light from an ArF excimer laser. Irradiating the original agglomerated particles at fluences ranging from 0.07 to 0.26 J/cm 2 with repetition rates of 20 and 100 Hz produces a large number of small, unagglomerated particles, and a smaller number of spherical agglomerated particles. Mean particle diameters from 20 to 50 nm are produced from soot originally having a mean electric mobility diameter of 265nm. We use a non-dimensional parameter, called the photon/atom ratio (PAR), to aid in understanding the photofragmentation process. This parameter is the ratio of the number of photons striking the soot particles to the number of the carbon atoms contained in the soot particles, and is a better metric than the laser fluence for analyzing laser-particle interactions. These results suggest that UV photofragmentation can be effective in controlling particle size and morphology, and can be a useful diagnostic for studying elements of the laser ablation process

  13. Ecological boiler modernization, feasible energy solutions

    International Nuclear Information System (INIS)

    Krcek, F.; Matev, M.; Sykora, J.; Chladek, J.

    2005-01-01

    Alstom Power, s.r.o., ALSTOM GROUP in Brno, Czech Republic is a successor of PBS (First Brno Machine Works). PBS was a well-known company in Bulgaria - mainly as Heating Power Plant (HPP) and Industrial Plant supplier of boilers, industrial steam turbines, milling systems, heat exchangers Btc. PBS has been privatised in two stages starting at1993 year. Alstom recently deals with boiler and heat exchanger products. Industrial turbine but has been sold to Siemens in 2004

  14. Performance of biomorphic Silicon Carbide as particulate filter in diesel boilers.

    Science.gov (United States)

    Orihuela, M Pilar; Gómez-Martín, Aurora; Becerra, José A; Chacartegui, Ricardo; Ramírez-Rico, Joaquín

    2017-12-01

    Biomorphic Silicon Carbide (bioSiC) is a novel porous ceramic material with excellent mechanical and thermal properties. Previous studies have demonstrated that it may be a good candidate for its use as particle filter media of exhaust gases at medium or high temperature. In order to determine the filtration efficiency of biomorphic Silicon Carbide, and its adequacy as substrate for diesel particulate filters, different bioSiC-samples have been tested in the flue gases of a diesel boiler. For this purpose, an experimental facility to extract a fraction of the boiler exhaust flow and filter it under controlled conditions has been designed and built. Several filter samples with different microstructures, obtained from different precursors, have been tested in this bench. The experimental campaign was focused on the measurement of the number and size of particles before and after placing the samples. Results show that the initial efficiency of filters made from natural precursors is severely determined by the cutting direction and associated microstructure. In biomorphic Silicon Carbide derived from radially cut wood, the initial efficiency of the filter is higher than 95%. Nevertheless, when the cut of the wood is axial, the efficiency depends on the pore size and the permeability, reaching in some cases values in the range 70-90%. In this case, the presence of macropores in some of the samples reduces their efficiency as particle traps. In continuous operation, the accumulation of particles within the porous media leads to the formation of a soot cake, which improves the efficiency except in the case when extra-large pores exist. For all the samples, after a few operation cycles, capture efficiency was higher than 95%. These experimental results show the potential for developing filters for diesel boilers based on biomorphic Silicon Carbide. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. The Ice Nucleation Activity of Surface Modified Soot

    Science.gov (United States)

    Häusler, Thomas; Witek, Lorenz; Felgitsch, Laura; Hitzenberger, Regina; Grothe, Hinrich

    2017-04-01

    The ice nucleation efficiency of many important atmospheric particles remains poorly understood. Since soot is ubiquitous in the Earth's troposphere, they might have the potential to significantly impact the Earth's climate (Finlayson-Pitts and Pitts, 2000; Seinfeld and Pandis, 1998). Here we present the ice nucleation activity (INA) in immersion freezing mode of different types of soot. Therefor a CAST (combustion aerosol standard) generator was used to produce different kinds of soot samples. The CAST generator combusts a propane-air-mixture and deposits thereby produced soot on a polyvinyl fluoride filter. By varying the propane to air ratio, the amount of organic portion of the soot can be varied from black carbon (BC) with no organic content to brown carbon (BrC) with high organic content. To investigate the impact of functional sites of ice nuclei (IN), the soot samples were exposed to NO2 gas for a certain amount of time (30 to 360 minutes) to chemically modify the surface. Immersion freezing experiments were carried out in a unique reaction gadget. In this device a water-in-oil suspension (with the soot suspended in the aqueous phase) was cooled till the freezing point and was observed through a microscope (Pummer et al., 2012; Zolles et al., 2015) It was found that neither modified nor unmodified BC shows INA. On the contrary, unmodified BrC shows an INA at -32˚ C, which can be increased up to -20˚ C. The INA of BrC depends on the duration of NO2- exposure. To clarify the characteristics of the surface modifications, surface sensitive analysis like infrared spectroscopy and X-ray photoelectron spectroscopy were carried out. Finlayson-Pitts, B. J. and Pitts, J. N. J.: Chemistry of the Upper and Lower Atmosphere, Elsevier, New York, 2000. Pummer, B. G., Bauer, H., Bernardi, J., Bleicher, S., and Grothe, H.: Suspendable macromolecules are responsible for ice nucleation activity of birch and conifer pollen, Atmos Chem Phys, 12, 2541-2550, 2012. Seinfeld, J

  16. Increasing the thermal efficiency of boiler plant

    Directory of Open Access Journals (Sweden)

    Uyanchinov Evgeniy

    2017-01-01

    Full Text Available The thermal efficiency increase of boiler plant is actual task of scientific and technical researches. The optimization of boiler operating conditions is task complex, which determine by most probable average load of boiler, operating time and characteristics of the auxiliary equipment. The work purpose – the determination of thermodynamic efficiency increase ways for boiler plant with a gas-tube boiler. The tasks, solved at the research are the calculation of heat and fuel demand, the exergetic analysis of boilerhouse and heat network equipment, the determination of hydraulic losses and exergy losses due to restriction. The calculation was shown that the exergy destruction can be reduced by 2.39% due to excess air reducing to 10%; in addition the oxygen enrichment of air can be used that leads to reducing of the exergy destruction rate. The processes of carbon deposition from the side of flame and processes of scale formation on the water side leads to about 4.58% losses of fuel energy at gas-tube boiler. It was shown that the exergy losses may be reduced by 2.31% due to stack gases temperature reducing to 148 °C.

  17. Fragmentation and bond strength of airborne diesel soot agglomerates

    Directory of Open Access Journals (Sweden)

    Messerer Armin

    2008-06-01

    Full Text Available Abstract Background The potential of diesel soot aerosol particles to break up into smaller units under mechanical stress was investigated by a direct impaction technique which measures the degree of fragmentation of individual agglomerates vs. impact energy. Diesel aerosol was generated by an idling diesel engine used for passenger vehicles. Both the aerosol emitted directly and aerosol that had undergone additional growth by Brownian coagulation ("aging" was investigated. Optionally a thermo-desoption technique at 280°C was used to remove all high-volatility and the majority of low-volatility HC adsorbates from the aerosol before aging. Results It was found that the primary soot agglomerates emitted directly from the engine could not be fragmented at all. Soot agglomerates permitted to grow additionally by Brownian coagulation of the primary emitted particles could be fragmented to a maximum of 75% and 60% respectively, depending on whether adsorbates were removed from their surface prior to aging or not. At most, these aged agglomerates could be broken down to roughly the size of the agglomerates from the primary emission. The energy required for a 50% fragmentation probability of all bonds within an agglomerate was reduced by roughly a factor of 2 when aging "dry" agglomerates. Average bond energies derived from the data were 0.52*10-16 and 1.2*10-16 J, respectively. This is about 2 orders of magnitude higher than estimates for pure van-der-Waals agglomerates, but agrees quite well with other observations. Conclusion Although direct conclusions regarding the behavior of inhaled diesel aerosol in contact with body fluids cannot be drawn from such measurements, the results imply that highly agglomerated soot aerosol particles are unlikely to break up into units smaller than roughly the size distribution emitted as tail pipe soot.

  18. Fragmentation and bond strength of airborne diesel soot agglomerates

    Science.gov (United States)

    Rothenbacher, Sonja; Messerer, Armin; Kasper, Gerhard

    2008-01-01

    Background The potential of diesel soot aerosol particles to break up into smaller units under mechanical stress was investigated by a direct impaction technique which measures the degree of fragmentation of individual agglomerates vs. impact energy. Diesel aerosol was generated by an idling diesel engine used for passenger vehicles. Both the aerosol emitted directly and aerosol that had undergone additional growth by Brownian coagulation ("aging") was investigated. Optionally a thermo-desoption technique at 280°C was used to remove all high-volatility and the majority of low-volatility HC adsorbates from the aerosol before aging. Results It was found that the primary soot agglomerates emitted directly from the engine could not be fragmented at all. Soot agglomerates permitted to grow additionally by Brownian coagulation of the primary emitted particles could be fragmented to a maximum of 75% and 60% respectively, depending on whether adsorbates were removed from their surface prior to aging or not. At most, these aged agglomerates could be broken down to roughly the size of the agglomerates from the primary emission. The energy required for a 50% fragmentation probability of all bonds within an agglomerate was reduced by roughly a factor of 2 when aging "dry" agglomerates. Average bond energies derived from the data were 0.52*10-16 and 1.2*10-16 J, respectively. This is about 2 orders of magnitude higher than estimates for pure van-der-Waals agglomerates, but agrees quite well with other observations. Conclusion Although direct conclusions regarding the behavior of inhaled diesel aerosol in contact with body fluids cannot be drawn from such measurements, the results imply that highly agglomerated soot aerosol particles are unlikely to break up into units smaller than roughly the size distribution emitted as tail pipe soot. PMID:18533015

  19. Modelling thermal radiation and soot formation in buoyant diffusion flames

    International Nuclear Information System (INIS)

    Demarco Bull, R.A.

    2012-01-01

    The radiative heat transfer plays an important role in fire problems since it is the dominant mode of heat transfer between flames and surroundings. It controls the pyrolysis, and therefore the heat release rate, and the growth rate of the fire. In the present work a numerical study of buoyant diffusion flames is carried out, with the main objective of modelling the thermal radiative transfer and the soot formation/destruction processes. In a first step, different radiative property models were tested in benchmark configurations. It was found that the FSCK coupled with the Modest and Riazzi mixing scheme was the best compromise in terms of accuracy and computational requirements, and was a good candidate to be implemented in CFD codes dealing with fire problems. In a second step, a semi-empirical soot model, considering acetylene and benzene as precursor species for soot nucleation, was validated in laminar co flow diffusion flames over a wide range of hydrocarbons (C1-C3) and conditions. In addition, the optically-thin approximation was found to produce large discrepancies in the upper part of these small laminar flames. Reliable predictions of soot volume fractions require the use of an advanced radiation model. Then the FSCK and the semi-empirical soot model were applied to simulate laboratory-scale and intermediate-scale pool fires of methane and propane. Predicted flame structures as well as the radiant heat flux transferred to the surroundings were found to be in good agreement with the available experimental data. Finally, the interaction between radiation and turbulence was quantified. (author)

  20. Optimized Heating Rate and Soot-catalyst Ratio for Soot Oxidation over MoO3 Catalyst

    Directory of Open Access Journals (Sweden)

    Congwei Mei

    2017-10-01

    Full Text Available MoO3 is now utilized as a promising catalyst due to its high activity and favorable mobility at low temperature. Its spectral data and surface microstructures were characterized by Fourier transform infrared spectra (FT-IR and Field emission scanning electron microscope (FESEM. Thermo-analysis of the carbon black was performed over nano-MoO3 catalyst in a thermogravimetric analyzer (TGA at various heating rates and soot-catalyst ratios. Through the analysis of kinetic parameters, we found that the heat transfer effect and diffusion effect can be removed by setting lower heating rates and soot-catalyst ratios. Therefore, a strategy for selecting proper thermogravimetric parameters were established, which can contribute to the better understanding of thermo-analytical process. Copyright © 2017 BCREC Group. All rights reserved Received: 4th December 2016; Revised: 13rd June 2017; Accepted: 9th April 2017; Available online: 27th October 2017; Published regularly: December 2017 How to Cite: Mei, C., Mei, D., Yue, S, Chen, Z., Yuan, Y. (2017. Optimized Heating Rate and Soot-catalyst Ratio for Soot Oxidation over MoO3 Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (3: 408-414 (doi:10.9767/bcrec.12.3.845.408-414

  1. Soot modeling of counterflow diffusion flames of ethylene-based binary mixture fuels

    KAUST Repository

    Wang, Yu

    2015-03-01

    A soot model was developed based on the recently proposed PAH growth mechanism for C1-C4 gaseous fuels (KAUST PAH Mechanism 2, KM2) that included molecular growth up to coronene (A7) to simulate soot formation in counterflow diffusion flames of ethylene and its binary mixtures with methane, ethane and propane based on the method of moments. The soot model has 36 soot nucleation reactions from 8 PAH molecules including pyrene and larger PAHs. Soot surface growth reactions were based on a modified hydrogen-abstraction-acetylene-addition (HACA) mechanism in which CH3, C3H3 and C2H radicals were included in the hydrogen abstraction reactions in addition to H atoms. PAH condensation on soot particles was also considered. The experimentally measured profiles of soot volume fraction, number density, and particle size were well captured by the model for the baseline case of ethylene along with the cases involving mixtures of fuels. The simulation results, which were in qualitative agreement with the experimental data in the effects of binary fuel mixing on the sooting structures of the measured flames, showed in particular that 5% addition of propane (ethane) led to an increase in the soot volume fraction of the ethylene flame by 32% (6%), despite the fact that propane and ethane are less sooting fuels than is ethylene, which is in reasonable agreement with experiments of 37% (14%). The model revealed that with 5% addition of methane, there was an increase of 6% in the soot volume fraction. The average soot particle sizes were only minimally influenced while the soot number densities were increased by the fuel mixing. Further analysis of the numerical data indicated that the chemical cross-linking effect between ethylene and the dopant fuels resulted in an increase in PAH formation, which led to higher soot nucleation rates and therefore higher soot number densities. On the other hand, the rates of soot surface growth per unit surface area through the HACA mechanism were

  2. Characterization of Oxy-combustion Impacts in Existing Coal-fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Adams, Bradley [Univ. of Utah, Salt Lake City, UT (United States); Davis, Kevin [Univ. of Utah, Salt Lake City, UT (United States); Senior, Constance [Univ. of Utah, Salt Lake City, UT (United States); Shim, Hong Shim [Univ. of Utah, Salt Lake City, UT (United States); Otten, Brydger Van [Univ. of Utah, Salt Lake City, UT (United States); Fry, Andrew [Univ. of Utah, Salt Lake City, UT (United States); Wendt, Jost [Univ. of Utah, Salt Lake City, UT (United States); Eddings, Eric [Univ. of Utah, Salt Lake City, UT (United States); Paschedag, Alan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Shaddix, Christopher [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Cox, William [Brigham Young Univ., Provo, UT (United States); Tree, Dale [Brigham Young Univ., Provo, UT (United States)

    2013-09-30

    Reaction Engineering International (REI) managed a team of experts from University of Utah, Siemens Energy, Praxair, Vattenfall AB, Sandia National Laboratories, Brigham Young University (BYU) and Corrosion Management Ltd. to perform multi-scale experiments, coupled with mechanism development, process modeling and CFD modeling, for both applied and fundamental investigations. The primary objective of this program was to acquire data and develop tools to characterize and predict impacts of CO{sub 2} flue gas recycle and burner feed design on flame characteristics (burnout, NO{sub x}, SO{sub x}, mercury and fine particle emissions, heat transfer) and operational concerns (fouling, slagging and corrosion) inherent in the retrofit of existing coal-fired boilers for oxy-coal combustion. Experimental work was conducted at Sandia National Laboratories’ Entrained Flow Reactor, the University of Utah Industrial Combustion Research Facility, and Brigham Young University. Process modeling and computational fluid dynamics (CFD) modeling was performed at REI. Successful completion of the project objectives resulted in the following key deliverables: 1) Multi-scale test data from 0.1 kW bench-scale, 100 kW and 200 kW laboratory-scale, and 1 MW semi-industrial scale combustors that describe differences in flame characteristics, fouling, slagging and corrosion for coal combustion under air-firing and oxygen-firing conditions, including sensitivity to oxy-burner design and flue gas recycle composition. 2) Validated mechanisms developed from test data that describe fouling, slagging, waterwall corrosion, heat transfer, char burnout and sooting under coal oxy-combustion conditions. The mechanisms were presented in a form suitable for inclusion in CFD models or process models. 3) Principles to guide design of pilot-scale and full-scale coal oxy-firing systems and flue gas recycle configurations, such that boiler operational impacts from oxy-combustion retrofits are minimized. 4

  3. MSWI Boiler Ashes: Production and Quality Through the Horizontal Section of a Boiler

    DEFF Research Database (Denmark)

    Allegrini, Elisa; Boldrin, Alessio; Astrup, Thomas Fruergaard

    of the first phase of a wider study about the solid residues produced at the heat recovery system (boiler) of a waste incineration plant. The characterization was carried out not on the total output of the boiler but on the different solid residues produced at ten different horizontal sections. The aim...

  4. An investigation of late-combustion soot burnout in a DI diesel engine using simultaneous planar imaging of soot and OH radical

    Energy Technology Data Exchange (ETDEWEB)

    John E. Dec; Peter L. Kelly-Zion

    1999-10-01

    Diesel engine design continues to be driven by the need to improve performance while at the same time achieving further reductions in emissions. The development of new designs to accomplish these goals requires an understanding of how the emissions are produced in the engine. Laser-imaging diagnostics are uniquely capable of providing this information, and the understanding of diesel combustion and emissions formation has been advanced considerably in recent years by their application. However, previous studies have generally focused on the early and middle stages of diesel combustion. These previous laser-imaging studies do provide important insight into the soot formation and oxidation processes during the main combustion event. They indicate that prior to the end of injection, soot formation is initiated by fuel-rich premixed combustion (equivalence ratio > 4) near the upstream limit of the luminous portion of the reacting fuel jet. The soot is then oxidized at the diffusion flame around the periphery of the luminous plume. Under typical diesel engine conditions, the diffusion flame does not burn the remaining fuel and soot as rapidly as it is supplied, resulting in an expanding region of rich combustion products and soot. This is evident in natural emission images by the increasing size of the luminous soot cloud prior to the end of injection. Hence, the amount of soot in the combustion chamber typically increases until shortly after the end of fuel injection, at which time the main soot formation period ends and the burnout phase begins. Sampling valve and two-color pyrometry data indicate that the vast majority (more than 90%) of the soot formed is oxidized before combustion ends; however, it is generally thought that a small fraction of this soot from the main combustion zones is not consumed and is the source of tail pipe soot emissions.

  5. On the formation and early evolution of soot in turbulent nonpremixed flames

    KAUST Repository

    Bisetti, Fabrizio

    2012-01-01

    A Direct Numerical Simulation (DNS) of soot formation in an n-heptane/air turbulent nonpremixed flame has been performed to investigate unsteady strain effects on soot growth and transport. For the first time in a DNS of turbulent combustion, Polycyclic Aromatic Hydrocarbons (PAH) are included via a validated, reduced chemical mechanism. A novel statistical representation of soot aggregates based on the Hybrid Method of Moments is used [M.E. Mueller, G. Blanquart, H. Pitsch, Combust. Flame 156 (2009) 1143-1155], which allows for an accurate state-of-the-art description of soot number density, volume fraction, and morphology of the aggregates. In agreement with previous experimental studies in laminar flames, Damköhler number effects are found to be significant for PAH. Soot nucleation and growth from PAH are locally inhibited by high scalar dissipation rate, thus providing a possible explanation for the experimentally observed reduction of soot yields at increasing levels of mixing in turbulent sooting flames. Furthermore, our data indicate that soot growth models that rely on smaller hydrocarbon species such as acetylene as a proxy for large PAH molecules ignore or misrepresent the effects of turbulent mixing and hydrodynamic strain on soot formation due to differences in the species Damköhler number. Upon formation on the rich side of the flame, soot is displaced relative to curved mixture fraction iso-surfaces due to differential diffusion effects between soot and the gas-phase. Soot traveling towards the flame is oxidized, and aggregates displaced away from the flame grow primarily by condensation of PAH on the particle surface. In contrast to previous DNS studies based on simplified soot and chemistry models, surface reactions are found to contribute barely to the growth of soot, for nucleation and condensation processes occurring in the fuel stream are responsible for the most of soot mass generation. Furthermore, the morphology of the soot aggregates is

  6. Effect of Dimethyl Ether Mixing on Soot Size Distribution in Premixed Ethylene Flame

    KAUST Repository

    Li, Zepeng

    2016-04-21

    As a byproduct of incomplete combustion, soot attracts increasing attentions as extensive researches exploring serious health and environmental effects from soot particles. Soot emission reduction requires a comprehensive understanding of the mechanism for polycyclic aromatic hydrocarbons and of soot formation and aging processes. Therefore, advanced experimental techniques and numerical simulations have been conducted to investigate this procedure. In order to investigate the effects of dimethyl ether (DME) mixing on soot particle size distribution functions (PSDFs), DME was mixed in premixed ethylene/oxygen/argon at flames at the equivalence ratio of 2.0 with a range of mixing ratio from 0% to 30% of the total carbon fed. Two series of atmospheric pressure flames were tested in which cold gas velocity was varied to obtain different flame temperatures. The evolution of PSDFs along the centerline of the flame was determined by burner stabilized stagnation probe and scanning mobility particle sizer (SMPS) techniques, yielding the PSDFs for various separation distances above the burner surface. Meanwhile, the flame temperature profiles were carefully measured by a thermocouple and the comparison to that of simulated laminar premixed burner-stabilized stagnation flame was satisfactory. Additionally, to understand the chemical role of DME mixing in soot properties, characterization measurements were conducted on soot samples using thermo-gravimetric analysis (TGA) and elemental analysis (EA). Results of the evolution of PSDFs and soot volume fraction showed that adding DME into ethylene flame could reduce soot yield significantly. The addition of DME led to the decrease of both the soot nucleation rate and the particle mass growth rate. To explain the possible mechanism for the observation, numerical simulations were performed. Although DME addition resulted in the slight increase of methyl radicals from pyrolysis, the decrease in acetylene and propargyl radicals

  7. Formation of Soot in Counterflow Diffusion Flames with Carbon Dioxide Dilution

    KAUST Repository

    Wang, Yu

    2016-05-04

    Experimental and numerical modeling studies have been performed to investigate the effect of CO2 dilution on soot formation in ethylene counterflow diffusion flames. Thermal and chemical effects of CO2 addition on soot growth was numerically identified by using a fictitious CO2 species, which was treated as inert in terms of chemical reactions. The results showed that CO2 addition reduces soot formation both thermodynamically and chemically. In terms of chemical effect, the addition of CO2 decreases soot formation through various pathways, including: (1) reduced soot precursor (PAH) formation leading to lower inception rates and soot number density, which in turn results in lower surface area for soot mass addition; (2) reduced H, CH3, and C3H3 concentrations causing lower H abstraction rate and therefore less active site per surface area for soot growth; and (3) reduced C2H2 mole fraction and thus a slower C2H2 mass addition rate. In addition, the sooting limits were also measured for ethylene counterflow flames in both N2 and CO2 atmosphere and the results showed that sooting region was significantly reduced in the CO2 case compared to the N2 case. © 2016 Taylor & Francis.

  8. Effects of Fuel Quantity on Soot Formation Process for Biomass-Based Renewable Diesel Fuel Combustion

    KAUST Repository

    Jing, Wei

    2016-12-01

    Soot formation process was investigated for biomass-based renewable diesel fuel, such as biomass to liquid (BTL), and conventional diesel combustion under varied fuel quantities injected into a constant volume combustion chamber. Soot measurement was implemented by two-color pyrometry under quiescent type diesel engine conditions (1000 K and 21% O2 concentration). Different fuel quantities, which correspond to different injection widths from 0.5 ms to 2 ms under constant injection pressure (1000 bar), were used to simulate different loads in engines. For a given fuel, soot temperature and KL factor show a different trend at initial stage for different fuel quantities, where a higher soot temperature can be found in a small fuel quantity case but a higher KL factor is observed in a large fuel quantity case generally. Another difference occurs at the end of combustion due to the termination of fuel injection. Additionally, BTL flame has a lower soot temperature, especially under a larger fuel quantity (2 ms injection width). Meanwhile, average soot level is lower for BTL flame, especially under a lower fuel quantity (0.5 ms injection width). BTL shows an overall low sooting behavior with low soot temperature compared to diesel, however, trade-off between soot level and soot temperature needs to be carefully selected when different loads are used.

  9. Molecular mechanics and quantum mechanical modeling of hexane soot structure and interactions with pyrene

    Directory of Open Access Journals (Sweden)

    Kubicki JD

    2000-09-01

    Full Text Available Molecular simulations (energy minimizations and molecular dynamics of an n-hexane soot model developed by Smith and co-workers (M. S. Akhter, A. R. Chughtai and D. M. Smith, Appl. Spectrosc., 1985, 39, 143; ref. 1 were performed. The MM+ (N. L. Allinger, J. Am. Chem. Soc., 1977, 395, 157; ref. 2 and COMPASS (H. Sun, J. Phys. Chem., 1998, 102, 7338; ref. 3 force fields were tested for their ability to produce realistic soot nanoparticle structure. The interaction of pyrene with the model soot was simulated. Quantum mechanical calculations on smaller soot fragments were carried out. Starting from an initial 2D structure, energy minimizations are not able to produce the observed layering within soot with either force field. Results of molecular dynamics simulations indicate that the COMPASS force field does a reasonably accurate job of reproducing observations of soot structure. Increasing the system size from a 683 to a 2732 atom soot model does not have a significant effect on predicted structures. Neither does the addition of water molecules surrounding the soot model. Pyrene fits within the soot structure without disrupting the interlayer spacing. Polycyclic aromatic hydrocarbons (PAH, such as pyrene, may strongly partition into soot and have slow desorption kinetics because the PAH-soot bonding is similar to soot–soot interactions. Diffusion of PAH into soot micropores may allow the PAH to be irreversibly adsorbed and sequestered so that they partition slowly back into an aqueous phase causing dis-equilibrium between soil organic matter and porewater.

  10. Measuring and predicting sooting tendencies of oxygenates, alkanes, alkenes, cycloalkanes, and aromatics on a unified scale

    Energy Technology Data Exchange (ETDEWEB)

    Das, Dhrubajyoti D.; St. John, Peter C.; McEnally, Charles S.; Kim, Seonah; Pfefferle, Lisa D.

    2018-04-01

    Databases of sooting indices, based on measuring some aspect of sooting behavior in a standardized combustion environment, are useful in providing information on the comparative sooting tendencies of different fuels or pure compounds. However, newer biofuels have varied chemical structures including both aromatic and oxygenated functional groups, which expands the chemical space of relevant compounds. In this work, we propose a unified sooting tendency database for pure compounds, including both regular and oxygenated hydrocarbons, which is based on combining two disparate databases of yield-based sooting tendency measurements in the literature. Unification of the different databases was made possible by leveraging the greater dynamic range of the color ratio pyrometry soot diagnostic. This unified database contains a substantial number of pure compounds (greater than or equal to 400 total) from multiple categories of hydrocarbons important in modern fuels and establishes the sooting tendencies of aromatic and oxygenated hydrocarbons on the same numeric scale for the first time. Using this unified sooting tendency database, we have developed a predictive model for sooting behavior applicable to a broad range of hydrocarbons and oxygenated hydrocarbons. The model decomposes each compound into single-carbon fragments and assigns a sooting tendency contribution to each fragment based on regression against the unified database. The model's predictive accuracy (as demonstrated by leave-one-out cross-validation) is comparable to a previously developed, more detailed predictive model. The fitted model provides insight into the effects of chemical structure on soot formation, and cases where its predictions fail reveal the presence of more complicated kinetic sooting mechanisms. This work will therefore enable the rational design of low-sooting fuel blends from a wide range of feedstocks and chemical functionalities.

  11. Strain rate effect on sooting characteristics in laminar counterflow diffusion flames

    KAUST Repository

    Wang, Yu

    2016-01-20

    The effects of strain rate, oxygen enrichment and fuel type on the sooting characteristics of counterflow diffusion flames were studied. The sooting structures and relative PAH concentrations were measured with laser diagnostics. Detailed soot modeling using recently developed PAH chemistry and surface reaction mechanism was performed and the results were compared with experimental data for ethylene flames, focusing on the effects of strain rates. The results showed that increase in strain rate reduced soot volume fraction, average size and peak number density. Increase in oxygen mole fraction increased soot loading and decreased its sensitivity on strain rate. The soot volume fractions of ethane, propene and propane flames were also measured as a function of global strain rate. The sensitivity of soot volume fraction to strain rate was observed to be fuel dependent at a fixed oxygen mole fraction, with the sensitivity being higher for more sooting fuels. However, when the soot loadings were matched at a reference strain rate for different fuels by adjusting oxygen mole fraction, the dependence of soot loading on strain rate became comparable among the tested fuels. PAH concentrations were shown to decrease with increase in strain rate and the dependence on strain rate is more pronounced for larger PAHs. Soot modeling was performed using detailed PAH growth chemistry with molecular growth up to coronene. A qualitative agreement was obtained between experimental and simulation results, which was then used to explain the experimentally observed strain rate effect on soot growth. However, quantitatively, the simulation result exhibits higher sensitivity to strain rate, especially for large PAHs and soot volume fractions.

  12. 46 CFR 52.25-5 - Miniature boilers (modifies PMB-1 through PMB-21).

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Miniature boilers (modifies PMB-1 through PMB-21). 52.25... ENGINEERING POWER BOILERS Other Boiler Types § 52.25-5 Miniature boilers (modifies PMB-1 through PMB-21). Miniature boilers must meet the applicable provisions in this part for the boiler type involved and the...

  13. Boiler house modernization through shared savings program

    Energy Technology Data Exchange (ETDEWEB)

    Breault, R.W. [Tecogen, Waltham, MA (United States)

    1995-12-31

    Throughout Poland as well as the rest of Eastern Europe, communities and industries rely on small heat only boilers to provide district and process heat. Together these two sectors produce about 85,000 MW from boilers in the 2 to 35 MW size range. The bulk of these units were installed prior to 1992 and must be completely overhauled to meet the emission regulations which will be coming into effect on January 1, 1998. Since the only practical fuel is coal in most cases, these boilers must be either retrofit with emission control technology or be replaced entirely. The question that arises is how to accomplish this given the current tight control of capital in Poland and other East European countries. A solution that we have for this problem is shared savings. These boilers are typically operating with a quiet low efficiency as compared to western standards and with excessive manual labor. Installing modernization equipment to improve the efficiency and to automate the process provides savings. ECOGY provides the funds for the modernization to improve the efficiency, add automation and install emission control equipment. The savings that are generated during the operation of the modernized boiler system are split between the client company and ECOGY for a number of years and then the system is turned over in entirety to the client. Depending on the operating capacity, the shared savings agreement will usually span 6 to 10 years.

  14. Increasing the efficiency of the condensing boiler

    Science.gov (United States)

    Zaytsev, ON; Lapina, EA

    2017-11-01

    Analysis of existing designs of boilers with low power consumption showed that the low efficiency of the latter is due to the fact that they work in most cases when the heating period in the power range is significantly less than the nominal power. At the same time, condensing boilers do not work in the most optimal mode (in condensing mode) in the central part of Russia, a significant part of their total operating time during the heating season. This is due to existing methods of equipment selection and joint operation with heating systems with quantitative control of the coolant. It was also revealed that for the efficient operation of the heating system, it is necessary to reduce the inertia of the heat generating equipment. Theoretical patterns of thermal processes in the furnace during combustion gas at different radiating surfaces location schemes considering the influence of the very furnace configuration, characterized in that to reduce the work condensing boiler in conventional gas boiler operation is necessary to maintain a higher temperature in the furnace (in the part where spiral heat exchangers are disposed), which is possible when redistributing heat flow - increase the proportion of radiant heat from the secondary burner emitter allow Perey For the operation of the condensing boiler in the design (condensation) mode practically the entire heating period.

  15. The load structure of electro boilers

    International Nuclear Information System (INIS)

    Feilberg, N.; Livik, K.

    1995-01-01

    Load measurements have been performed on 24 electro boilers with a time resolution of one hour throughout a period of one year. The boilers are used for space heating and heating of tap water in office buildings, shopping centres and apartment buildings. All boilers have tariffs with disconnection agreements. This report presents load analyses of the measurements from each boiler, and typical load profiles are calculated and presented. It also analyses how boilers are used in relation to the outdoor temperature and the power price on the spot market. All the measurements are performed in Bergen, Norway, in the period August 1993 - August 1994. Typical load profiles are shown, both annual and daily, as well as specific load parameters in addition to key figures used in calculating the total power load on the distribution network. The climate impact on energy and power load is evaluated. The report also shows examples of how the results may be applied in various special fields. 8 figs., 9 tabs

  16. Impacts of fuel formulation and engine operating parameters on the nanostructure and reactivity of diesel soot

    Science.gov (United States)

    Yehliu, Kuen

    This study focuses on the impacts of fuel formulations on the reactivity and nanostructure of diesel soot. A 2.5L, 4-cylinder, turbocharged, common rail, direct injection light-duty diesel engine was used in generating soot samples. The impacts of engine operating modes and the start of combustion on soot reactivity were investigated first. Based on preliminary investigations, a test condition of 2400 rpm and 64 Nm, with single and split injection strategies, was chosen for studying the impacts of fuel formulation on the characteristics of diesel soot. Three test fuels were used: an ultra low sulfur diesel fuel (BP15), a pure soybean methyl-ester (B100), and a synthetic Fischer-Tropsch fuel (FT) produced in a gas-to-liquid process. The start of injection (SOI) and fuel rail pressures were adjusted such that the three test fuels have similar combustion phasing, thereby facilitating comparisons between soots from the different fuels. Soot reactivity was investigated by thermogravimetric analysis (TGA). According to TGA, B100 soot exhibits the fastest oxidation on a mass basis followed by BP15 and FT derived soots in order of apparent rate constant. X-ray photoelectron spectroscopy (XPS) indicates no relation between the surface oxygen content and the soot reactivity. Crystalline information for the soot samples was obtained using X-ray diffraction (XRD). The basal plane diameter obtained from XRD was inversely related to the apparent rate constants for soot oxidation. For comparison, high resolution transmission electron microscopy (HRTEM) provided images of the graphene layers. Quantitative image analysis proceeded by a custom algorithm. B100 derived soot possessed the shortest mean fringe length and greatest mean fringe tortuosity. This suggests soot (nano)structural disorder correlates with a faster oxidation rate. Such results are in agreement with the X-ray analysis, as the observed fringe length is a measure of basal plane diameter. Moreover the relation

  17. Blue light emitting diesel soot for photonic applications

    Science.gov (United States)

    Swapna, M. S.; Sankararaman, S.

    2018-01-01

    The present work is the first report of producing blue light emission from phosphor free and low-cost material—the diesel soot from the internal combustion engines (ICEs). The structural morphology is analyzed by field emission scanning electron microscopy and high-resolution transmission electron microscopy. The optical characterization is done by recording UV–visible spectrum and photoluminescent Spectrum. The CIE plot and the power spectrum for the sample show blue emission. This is further verified by collecting diesel soot from the ICE of different year of make. A visual confirmation of blue emission is obtained by exciting the sample with UV laser. The presence of various allotropic forms of carbon in the sample is identified by x-ray diffraction, Fourier transform infrared and Raman spectroscopic analysis.

  18. Soot in the atmosphere and snow surface of Antarctica

    International Nuclear Information System (INIS)

    Warren, S.G.; Clarke, A.D.

    1990-01-01

    Samples of snow collected near the south pole during January and February 1986 were analyzed for the presence of light-absorbing particles by passing the melted snow through a nuclepore filter. Transmission of light through the filter showed that snow far from the station contains the equivalent of 0.1-0.3 ng of carbon per gram of snow (ng/g). Samples of ambient air were filtered and found to contain about 1-2 ng of carbon per kilogram of air, giving a scavenging ratio of about 150. The snow downwind of the station exhibited a well-defined plume of soot due to the burning of diesel fuel, but even in the center of the plume 1 km downwind, the soot concentration was only 3 ng/g, too small to affect snow albedo significantly. Measurements of snow albedo near large inland stations are therefore probably representative of their surrounding regions

  19. Temperature and velocity profiles in sooting free boundary layer flames

    Science.gov (United States)

    Ang, J. A.; Pagni, P. J.; Mataga, T. G.; Margle, J. M.; Lyons, V. J.

    1986-01-01

    Temperature and velocity profiles are presented for cyclohexane, n-heptane, and iso-octane free, laminar, boundary layer, sooting, diffusion flames. Temperatures are measured with 3 mil Pt/Pt-13 percent Rh thermocouples. Corrected gas temperatures are derived by performing an energy balance of convection to and radiation from the thermocouple bead incorporating the variation of air conductivity and platinum emissivity with temperature. Velocities are measured using laser doppler velocimetry techniques. Profiles are compared with previously reported analytic temperature and velocity fields. Comparison of theoretical and experimental temperature profiles suggests improvement in the analytical treatment is needed, which accounts more accurately for the local soot radiation. The velocity profiles are in good agreement, with the departure of the theory from observation partially due to the small fluctuations inherent in these free flows.

  20. Single Particle Soot Photometer intercomparison at the AIDA chamber

    Directory of Open Access Journals (Sweden)

    M. Laborde

    2012-12-01

    Full Text Available Soot particles, consisting of black carbon (BC, organic carbon (OC, inorganic salts, and trace elements, are emitted into the atmosphere during incomplete combustion. Accurate measurements of atmospheric BC are important as BC particles cause adverse health effects and impact the climate.

    Unfortunately, the accurate measurement of the properties and mass concentrations of BC particles remains difficult. The Single Particle Soot Photometer (SP2 can contribute to improving this situation by measuring the mass of refractory BC in individual particles as well as its mixing state.

    Here, the results of the first detailed SP2 intercomparison, involving 6 SP2s from 6 different research groups, are presented, including the most evolved data products that can presently be calculated from SP2 measurements.

    It was shown that a detection efficiency of almost 100% down to 1 fg BC per particle can readily be achieved, and that this limit can be pushed down to ∼0.2 fg BC with optimal SP2 setup. Number and mass size distributions of BC cores agreed within ±5% and ±10%, respectively, in between the SP2s, with larger deviations in the range below 1 fg BC.

    The accuracy of the SP2's mass concentration measurement depends on the calibration material chosen. The SP2 has previously been shown to be equally sensitive to fullerene soot and ambient BC from sources where fossil fuel was dominant and less sensitive to fullerene soot than to Aquadag. Fullerene soot was therefore chosen as the standard calibration material by the SP2 user community; however, many data sets rely solely on Aquadag calibration measurements. The difference in SP2 sensitivity was found to be almost equal (fullerene soot to Aquadag response ratio of ∼0.75 at 8.9 fg BC for all SP2s. This allows the calculation of a fullerene soot equivalent calibration curve from a measured Aquadag calibration, when no fullerene soot calibration is available. It could be

  1. Computer simulation of the fire-tube boiler hydrodynamics

    Directory of Open Access Journals (Sweden)

    Khaustov Sergei A.

    2015-01-01

    Full Text Available Finite element method was used for simulating the hydrodynamics of fire-tube boiler with the ANSYS Fluent 12.1.4 engineering simulation software. Hydrodynamic structure and volumetric temperature distribution were calculated. The results are presented in graphical form. Complete geometric model of the fire-tube boiler based on boiler drawings was considered. Obtained results are suitable for qualitative analysis of hydrodynamics and singularities identification in fire-tube boiler water shell.

  2. Investigation of soot optical properties by spectral line-of-sight attenuation

    Energy Technology Data Exchange (ETDEWEB)

    Migliorini, F.; Thomson, K.A.; Smallwood, G.J. [National Research Council of Canada, Ottawa, ON (Canada); Geigle, K.P. [DLR, Stuttgart (Germany). Inst. of Combustion Technology; Johnson, M.J. [Carleton Univ., Ottawa, ON (Canada)

    2009-07-01

    Optical soot diagnostics are a non-intrusive method to measure, understand and hopefully control soot formation. This presentation discussed an investigation of soot optical properties by spectral line-of-sight attenuation. Topics that were presented included optical properties in soot diagnostics; the soot refractive index absorption function E(m); E(m) from the literature; variation of E(m) with wavelength; governing equations; one-dimensional spectral LOSA; the gulder burner; the McKenna burner; zero-dimensional spectral LOSA; relative E(m) for the McKenna burner; and a discussion on relative E(m) in a McKenna flame. It was concluded that future work should include thermophoretic sampling at measurement locations in Gulder and McKenna burner to establish morphology and aging of soot and emission measurements to determine if multi-wavelength pyrometry agrees with multiwavelength attenuation. figs.

  3. Effects of morphology and wavelength on the measurement accuracy of soot volume fraction by laser extinction

    Science.gov (United States)

    Wang, Ya-fei; Huang, Qun-xing; Wang, Fei; Chi, Yong; Yan, Jian-hua

    2018-01-01

    A novel method to evaluate the quantitative effects of soot morphology and incident wavelength on the measurement accuracy of soot volume fraction, by the laser extinction (LE) technique is proposed in this paper. The results indicate that the traditional LE technique would overestimate soot volume fraction if the effects of morphology and wavelength are not considered. Before the agglomeration of isolated soot primary particles, the overestimation of the LE technique is in the range of 2-20%, and rises with increasing primary particle diameter and with decreasing incident wavelength. When isolated primary particles are agglomerated into fractal soot aggregates, the overestimation would exceed 30%, and rise with increasing primary particle number per soot aggregate, fractal dimension and fractal prefactor and with decreasing incident wavelength to a maximum value of 55%. Finally, based on these results above, the existing formula of the LE technique gets modified, and the modification factor is 0.65-0.77.

  4. Conductometric Sensor for Soot Mass Flow Detection in Exhausts of Internal Combustion Engines.

    Science.gov (United States)

    Feulner, Markus; Hagen, Gunter; Müller, Andreas; Schott, Andreas; Zöllner, Christian; Brüggemann, Dieter; Moos, Ralf

    2015-11-13

    Soot sensors are required for on-board diagnostics (OBD) of automotive diesel particulate filters (DPF) to detect filter failures. Widely used for this purpose are conductometric sensors, measuring an electrical current or resistance between two electrodes. Soot particles deposit on the electrodes, which leads to an increase in current or decrease in resistance. If installed upstream of a DPF, the "engine-out" soot emissions can also be determined directly by soot sensors. Sensors were characterized in diesel engine real exhausts under varying operation conditions and with two different kinds of diesel fuel. The sensor signal was correlated to the actual soot mass and particle number, measured with an SMPS. Sensor data and soot analytics (SMPS) agreed very well, an impressing linear correlation in a double logarithmic representation was found. This behavior was even independent of the used engine settings or of the biodiesel content.

  5. Aspects of new material application for boilers construction

    International Nuclear Information System (INIS)

    Czerniawski, R.

    1996-01-01

    Review of steel types commonly used for energetic boilers construction has been done. The worldwide trends in new materials application for improvement of boilers quality have been discussed. The mechanical properties of boiler construction steels have been shown and compared. 3 refs, 5 figs, 1 tab

  6. 21 CFR 173.310 - Boiler water additives.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Boiler water additives. 173.310 Section 173.310... FOR HUMAN CONSUMPTION (CONTINUED) SECONDARY DIRECT FOOD ADDITIVES PERMITTED IN FOOD FOR HUMAN CONSUMPTION Specific Usage Additives § 173.310 Boiler water additives. Boiler water additives may be safely...

  7. 46 CFR 176.812 - Pressure vessels and boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Pressure vessels and boilers. 176.812 Section 176.812... TONS) INSPECTION AND CERTIFICATION Material Inspections § 176.812 Pressure vessels and boilers. (a.... (b) Periodic inspection and testing requirements for boilers are contained in § 61.05 in subchapter F...

  8. 10 CFR 431.82 - Definitions concerning commercial packaged boilers.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 3 2010-01-01 2010-01-01 false Definitions concerning commercial packaged boilers. 431.82... COMMERCIAL AND INDUSTRIAL EQUIPMENT Commercial Packaged Boilers § 431.82 Definitions concerning commercial packaged boilers. The following definitions apply for purposes of this subpart E, and of subparts A and J...

  9. 46 CFR 115.812 - Pressure vessels and boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Pressure vessels and boilers. 115.812 Section 115.812... CERTIFICATION Material Inspections § 115.812 Pressure vessels and boilers. (a) Pressure vessels must be tested... testing requirements for boilers are contained in § 61.05 in subchapter F of this chapter. [CGD 85-080, 61...

  10. 40 CFR 761.71 - High efficiency boilers.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false High efficiency boilers. 761.71... PROHIBITIONS Storage and Disposal § 761.71 High efficiency boilers. (a) To burn mineral oil dielectric fluid containing a PCB concentration of ≥50 ppm, but boiler shall comply with the following...

  11. 46 CFR 109.205 - Inspection of boilers and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Inspection of boilers and machinery. 109.205 Section 109... OPERATIONS Tests, Drills, and Inspections § 109.205 Inspection of boilers and machinery. The chief engineer or engineer in charge, before he assumes charge of the boilers and machinery of a unit shall inspect...

  12. 40 CFR 63.988 - Incinerators, boilers, and process heaters.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Incinerators, boilers, and process... Routing to a Fuel Gas System or a Process § 63.988 Incinerators, boilers, and process heaters. (a) Equipment and operating requirements. (1) Owners or operators using incinerators, boilers, or process...

  13. Development of Filter-Blower Unit for use in the Advanced Nuclear Biological Chemical Protection System (ANBCPS) Helicopter/Transport-aircraft version

    NARCIS (Netherlands)

    Sabel, R.; Reffeltrath, P.A.; Jonkman, A.; Post, T.

    2006-01-01

    As a participant in the three-nation partnership for development of the ANBCP-S for use in Helicopters, Transport Aircraft and Fast Jet, the Royal Netherlands Airforce (RNLAF) picked up the challenge to design a Filter- Blower-Unit (FBU). Major Command (MajCom) of the RNLAF set priority to develop a

  14. 42 CFR 84.142 - Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators...

    Science.gov (United States)

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Air supply source; hand-operated or motor driven air blowers; Type A supplied-air respirators; minimum requirements. 84.142 Section 84.142 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF...

  15. Condensing boiler applications in the process industry

    International Nuclear Information System (INIS)

    Chen, Qun; Finney, Karen; Li, Hanning; Zhang, Xiaohui; Zhou, Jue; Sharifi, Vida; Swithenbank, Jim

    2012-01-01

    Major challenging issues such as climate change, energy prices and fuel security have focussed the attention of process industries on their energy efficiency and opportunities for improvement. The main objective of this research study was to investigate technologies needed to exploit the large amount of low grade heat available from a flue gas condensing system through industrial condensing boilers. The technology and application of industrial condensing boilers in various heating systems were extensively reviewed. As the condensers require site-specific engineering design, a case study was carried out to investigate the feasibility (technically and economically) of applying condensing boilers in a large scale district heating system (40 MW). The study showed that by recovering the latent heat of water vapour in the flue gas through condensing boilers, the whole heating system could achieve significantly higher efficiency levels than conventional boilers. In addition to waste heat recovery, condensing boilers can also be optimised for emission abatement, especially for particle removal. Two technical barriers for the condensing boiler application are corrosion and return water temperatures. Highly corrosion-resistant material is required for condensing boiler manufacture. The thermal design of a 'case study' single pass shell-and-tube condensing heat exchanger/condenser showed that a considerable amount of thermal resistance was on the shell-side. Based on the case study calculations, approximately 4900 m 2 of total heat transfer area was required, if stainless steel was used as a construction material. If the heat transfer area was made of carbon steel, then polypropylene could be used as the corrosion-resistant coating material outside the tubes. The addition of polypropylene coating increased the tube wall thermal resistance, hence the required heat transfer area was approximately 5800 m 2 . Net Present Value (NPV) calculations showed that the choice of a carbon

  16. Control Properties of Bottom Fired Marine Boilers

    DEFF Research Database (Denmark)

    Solberg, Brian; Andersen, Palle; Karstensen, Claus M. S.

    2005-01-01

    This paper focuses on model analysis of a dynamic model of a bottom fired one-pass smoke tube boiler. Linearised versions of the model are analysed to determine how gain, time constants and right half plane zeros (caused by the shrink-and-swell phenomenon) depend on the steam flow load. Furthermore...... the interactions in the system are inspected to analyse potential benefit from using a multivariable control strategy in favour of the current strategy based on single loop theory. An analysis of the nonlinear model is carried out to further determine the nonlinear characteristics of the boiler system...

  17. Optimal load allocation of multiple fuel boilers.

    Science.gov (United States)

    Dunn, Alex C; Du, Yan Yi

    2009-04-01

    This paper presents a new methodology for optimally allocating a set of multiple industrial boilers that each simultaneously consumes multiple fuel types. Unlike recent similar approaches in the utility industry that use soft computing techniques, this approach is based on a second-order gradient search method that is easy to implement without any specialized optimization software. The algorithm converges rapidly and the application yields significant savings benefits, up to 3% of the overall operating cost of industrial boiler systems in the examples given and potentially higher in other cases, depending on the plant circumstances. Given today's energy prices, this can yield significant savings benefits to manufacturers that raise steam for plant operations.

  18. Boiler inspection manipulator for Torness Power Station

    International Nuclear Information System (INIS)

    Carrey, R.T.A.; Yule, I.Y.; Sibson, S.; Playle, M.J.

    1996-01-01

    The Advanced Gas-cooled Reactors at Torness and Heysham 2 are provided with dedicated access for remote inspection equipment. These in-service inspection (ISI) accesses comprise 12 penetrations above the core for inspection of the above core area and boilers, 12 below core penetrations for inspection of the lower boiler area and access through any of the 8 gas circulator penetrations for inspection of the sub-diagrid area. This paper describes a manipulator which will access the reactor from above the core via any of the 8 peripheral penetrations. (UK)

  19. Central heating: fossil-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Blazek, C.F.; Baker, N.R.; Tison, R.R.

    1979-05-01

    This evaluation provides performance and cost data for fossil-fuel-fired steam boilers, hot-water generators, and thermal fluid generators currently available from manufacturers. Advanced-technology fluidized-bed boilers also are covered. Performance characteristics investigated include unit efficiencies, turndown capacity, and pollution requirements. Costs are tabulated for equipment and installation of both field-erected and packaged units. The information compiled in this evaluation will assist in the process of selecting energy-conversion units required for industrial, commercial, and residential applications.

  20. Effects of carbon dioxide on isolated droplet combustion for sooting and non-sooting fuels in microgravity

    Science.gov (United States)

    Nakaya, Shinji; Furuta, Tomoya; Nagashima, Yoshiaki; Segawa, Daisuke; Kadota, Toshikazu

    The combustion behavior of ethanol, n-buthanol and n-decane droplets in high concentration of CO2 was experimentally investigated at atmospheric pressure in microgravity. Experiments were performed during a fall of the experimental setup at 1 s drop tower with the total height of 9 m. The initial droplet diameter was ranged from about 0.3 to 0.8 mm. Detail measurements of the projected image of the droplet are conducted by using a high speed video camera and the effective droplet diameter squared are calculated from the surface area of the rotating body of the projected object. Effects of ambient carbon dioxide on unsteady behavior of the instantaneous burning rate for sooting and non-sooting droplet flames were investigated. The behavior of the instantaneous burning rate clearly showed events of the initial thermal expansion, ignition and subsequent burning of the fuel droplet, and it was different from the behavior predicted by d2 law. These fundamental behaviors for ethanol, n-buthanol and n-decane were shown in air and high concentrations of ambient carbon dioxide. In the case of n-decane (sooting fuel), the change in the burning rate after ignition was great while it was small in the case of ethanol. A stepwise increase in the burning rate after ignition could be clearly seen for n-decane droplet when initial droplet diameter was large although the tendency was not observed for ethanol. However, this stepwise behavior disappeared in high concentration of ambient carbon dioxide. In high concentration of ambient carbon dioxide, non-luminous flame was formed. The mitigation of soot production by ambient carbon dioxide was clearly observed and this effect was greater for the smaller droplet.

  1. Correlation of Soot Formation in Turbojet Engines and in Laboratory Flames.

    Science.gov (United States)

    1981-02-01

    tendency of a fuel to soot (cf. Refs. 18 and 19); for Bunsen burner flames the calculated adiabatic flame temperatures at the incipient soot point... flame burner is used to measure the smoke point. An objection can also be made to using a smoke point defined by using small laboratory diffusion...in Appendix A, it is possible to calibrate a wide variety of laboratory-scale diffusion or premixed flame burners so that if soot thresh- olds for a

  2. Numerical modeling of soot formation in a turbulent C2H4/air diffusion flame

    Directory of Open Access Journals (Sweden)

    Manedhar Reddy Busupally

    2016-06-01

    Full Text Available Soot formation in a lifted C2H4-Air turbulent diffusion flame is studied using two different paths for soot nucleation and oxidation; by a 2D axisymmetric RANS simulation using ANSYS FLUENT 15.0. The turbulence-chemistry interactions are modeled using two different approaches: steady laminar flamelet approach and flamelet-generated manifold. Chemical mechanism is represented by POLIMI to study the effect of species concentration on soot formation. P1 approximation is employed to approximate the radiative transfer equation into truncated series expansion in spherical harmonics while the weighted sum of gray gases is invoked to model the absorption coefficient while the soot model accounts for nucleation, coagulation, surface growth, and oxidation. The first route for nucleation considers acetylene concentration as a linear function of soot nucleation rate, whereas the second route considers two and three ring aromatic species as function of nucleation rate. Equilibrium-based and instantaneous approach has been used to estimate the OH concentration for soot oxidation. Lee and Fenimore-Jones soot oxidation models are studied to shed light on the effect of OH on soot oxidation. Moreover, the soot-radiation interactions are also included in terms of absorption coefficient of soot. Furthermore, the soot-turbulence interactions have been invoked using a temperature/mixture fraction-based single variable PDF. Both the turbulence-chemistry interaction models are able to accurately predict the flame liftoff height, and for accurate prediction of flame length, radiative heat loss should be accounted in an accurate way. The soot-turbulence interactions are found sensitive to the PDF used in present study.

  3. Blower door tests of a group of identical flats in a new student accommodation in the Arctic

    DEFF Research Database (Denmark)

    Kotol, Martin; Rode, Carsten; Vahala, Jan

    is as high as 400%. This result is without consideration of one particular flat which had the extreme result of being 940% as leaky as the unit with the highest air tightness. The reasons for such poor air tightness are lack of the installation gap between the vapour barrier and the inner wall......, and insufficient connections of the vapour barrier to the interior walls as explained in the paper. The large variation in results can be attributed to insufficient consideration of the importance of airtighness during construction of some parts of the building – despite of an intent to make a rather air tight...... air quality (IAQ) as well as performance of some single components. In summer 2012 a blower door test was performed on all 37 living units out of which 33 are identical single room flats and 4 are larger double room flats. The purpose was to evaluate the air tightness of the envelope and to find out...

  4. Latitudinal distribution of black carbon soot in the upper troposphere and lower stratosphere

    Science.gov (United States)

    Blake, David F.; Kato, Katharine

    1995-01-01

    Black carbon soot from the upper troposphere and lower stratosphere has been systematically collected at latitudes from 90 deg N to 45 deg S. The measured latitudinal distribution of this soot at 10 to 11 km altitude is found to covary with commercial air traffic fuel use, suggesting that aircraft fuel combustion at altitude is the principal source. In addition, at latitudes where the commercial air traffic is high, measured black carbon soot values are high even at 20 km altitude, suggesting that aircraft-generated soot injected just above the tropopause may be transported to higher altitudes. During the volcanically influenced period in which these samples were collected, the number abundances, total mass, and calculated total surface area of black carbon soot are 2-3 orders of magnitude lower than similar measures of sulfuric acid aerosol. During volcanically quiescent periods, the calculated total surface area of black carbon soot aerosol is of the same order of magnitude as that of the background sulfuric acid aerosol. It appears from this comparison that black carbon soot is only capable of influencing lower stratosphere or upper troposphere chemistry during periods when the aerosol budget is not dominated by volcanic activity. It remains to determine the extent to which black carbon soot particles act as nuclei for sulfuric acid aerosol formation. However, mass balance calculations suggest that aircraft soot injected at altitude does not represent a significant source of condensation nuclei for sulfuric acid aerosols.

  5. Soot Formation in Laminar Premixed Methane/Oxygen Flames at Atmospheric Pressure

    Science.gov (United States)

    Xu, F.; Lin, K.-C.; Faeth, G. M.

    1998-01-01

    Flame structure and soot formation were studied within soot-containing laminar premixed mc1hane/oxygen flames at atmospheric pressure. The following measurements were made: soot volume fractions by laser extinction, soot temperatures by multiline emission, gas temperatures (where soot was absent) by corrected fine-wire thermocouples, soot structure by thermophoretic sampling and transmission electron microscope (TEM), major gas species concentrations by sampling and gas chromatography, and gas velocities by laser velocimetry. Present measurements of gas species concentrations were in reasonably good agreement with earlier measurements due to Ramer et al. as well as predictions based on the detailed mechanisms of Frenklach and co-workers and Leung and Lindstedt: the predictions also suggest that H atom concentrations are in local thermodynamic equilibrium throughout the soot formation region. Using this information, it was found that measured soot surface growth rates could be correlated successfully by predictions based on the hydrogen-abstraction/carbon-addition (HACA) mechanisms of both Frenklach and co-workers and Colket and Hall, extending an earlier assessment of these mechanisms for premixed ethylene/air flames to conditions having larger H/C ratios and acetylene concentrations. Measured primary soot particle nucleation rates were somewhat lower than the earlier observations for laminar premixed ethylene/air flames and were significantly lower than corresponding rates in laminar diffusion flames. for reasons that still must be explained.

  6. Comparative Study of Different Methods for Soot Sensing and Filter Monitoring in Diesel Exhausts

    Directory of Open Access Journals (Sweden)

    Markus Feulner

    2017-02-01

    Full Text Available Due to increasingly tighter emission limits for diesel and gasoline engines, especially concerning particulate matter emissions, particulate filters are becoming indispensable devices for exhaust gas after treatment. Thereby, for an efficient engine and filter control strategy and a cost-efficient filter design, reliable technologies to determine the soot load of the filters and to measure particulate matter concentrations in the exhaust gas during vehicle operation are highly needed. In this study, different approaches for soot sensing are compared. Measurements were conducted on a dynamometer diesel engine test bench with a diesel particulate filter (DPF. The DPF was monitored by a relatively new microwave-based approach. Simultaneously, a resistive type soot sensor and a Pegasor soot sensing device as a reference system measured the soot concentration exhaust upstream of the DPF. By changing engine parameters, different engine out soot emission rates were set. It was found that the microwave-based signal may not only indicate directly the filter loading, but by a time derivative, the engine out soot emission rate can be deduced. Furthermore, by integrating the measured particulate mass in the exhaust, the soot load of the filter can be determined. In summary, all systems coincide well within certain boundaries and the filter itself can act as a soot sensor.

  7. Soot formation characteristics of gasoline surrogate fuels in counterflow diffusion flames

    KAUST Repository

    Choi, Byungchul

    2011-01-01

    The characteristics of polycyclic aromatic hydrocarbon (PAH) and soot for gasoline surrogate fuels have been investigated in counterflow diffusion flames by adopting laser-induced fluorescence (LIF) and laser-induced incandescence (LII) techniques for both soot formation and soot formation/oxidation flames. Tested fuels were three binary mixtures from the primary reference fuels of n-heptane, iso-octane, and toluene. The result showed that PAH and soot maintained near zero level for all mixtures of n-heptane/iso-octane case under present experimental conditions. For n-heptane/toluene and iso-octane/toluene mixtures, PAH initially increased and then decreased with the toluene ratio, exhibiting a synergistic effect. The soot formation increased monotonically with the toluene ratio, however the effect of toluene on soot formation was minimal for relatively small toluene ratios. These results implied that even though toluene had a dominant role in soot and PAH formations, small amount of toluene had a minimal effect on soot formation. Numerical simulations have also been conducted by adopting recently proposed two kinetic mechanisms. The synergistic behavior of aromatic rings was predicted similar to the experimental PAH measurement, however, the degree of the synergistic effect was over-predicted for the soot formation flame, indicating the need for refinements in the kinetic mechanisms. © 2010 Published by Elsevier Inc. on behalf of The Combustion Institute. All rights reserved.

  8. The Role of Biogenic and Anthropogenic Hydrocarbons in Aging of Atmospheric Soot

    Science.gov (United States)

    Khalizov, A. F.; Qiu, C.; Lin, Y.; Ma, Y.; Wang, L.; Zhang, R.

    2012-12-01

    Atmospheric soot is often found to be internally mixed with other aerosol constituents, yet the processes responsible for the soot aging are not well understood. We have conducted a systematic study on the role of several representative biogenic and anthropogenic volatile organic compounds (VOCs), including monoterpenes and aromatics, in atmospheric aging of combustion soot. Aging experiments were conducted in a fluoropolymer chamber on size-classified soot aerosols in the presence of a VOC and an oxidant, either ozone or photolytically generated hydroxyl radical (OH). The evolution in the aging state of soot was monitored from measurements of the particle mobility size and mass, which were used to derive information about particle effective density, dynamic shape factor, and coating thickness. When exposed to VOC and oxidant, soot particles promptly gain mass due to condensation of low-volatility and partitioning of semi-volatile VOC oxidation products. Depending on the VOC, the increase in the particle mass is accompanied by an increase or a decrease in the particle mobility diameter. In either case, the effective density of coated soot particles increases during aging because the condensed material fills in the voids of fractal soot aggregates, forcing their restructuring. The latter is confirmed by thermal denuding experiments, which show an increase in the effective density for soot that was first aged and then heated to remove the coating from the soot core. Hygroscopic and optical properties of soot are significantly altered by aging. Upon humidification, the coating absorbs water, increasing in volume and causing an additional restructuring of soot aggregates. Coated particles are sufficiently hygroscopic to activate to cloud droplets at atmospherically relevant water supersaturations. Aged soot shows stronger light absorption and scattering, with an enhancement magnitude depending on the coating thickness and nature of the coating precursor. The rate of

  9. A computational study of soot formation in opposed-flow diffusion flame interacting with vortices

    KAUST Repository

    Selvaraj, Prabhu

    2017-01-05

    The flame-vortex interaction enables the study of basic phenomena that control the coupling between combustion and turbulence. Employing a gas phase reaction mechanism considering polycyclic aromatic hydrocarbons (PAH), a two dimensional counterflow ethylene-air flame is simulated. A reduced mechanism with PAH pathways that includes until coronene and method of moments with interpolative closure (MOMIC) has been employed to calculate the soot characteristics. Interaction of sooting flame with a prescribed decaying random velocity field is being investigated. Counterflow nonpremixed flames at low strain rate sooting conditions are considered. Effects of vortices are studied on the flame structures and its sensitivity on the soot formation characteristics. As the vortex rolls up the flame, integrated soot volume fraction is found to be larger for the air-side vortex. A detailed analysis on the flame structure and its influence on the formation of soot were carried out. The results indicate that the larger PAH species contributes to the soot formation in the airside perturbation regimes, whereas the soot formation is dominated by the soot transport in fuel-side perturbation.

  10. Source identification of individual soot agglomerates in Arctic air by transmission electron microscopy

    Science.gov (United States)

    Weinbruch, S.; Benker, N.; Kandler, K.; Schütze, K.; Kling, K.; Berlinger, B.; Thomassen, Y.; Drotikova, T.; Kallenborn, R.

    2018-01-01

    Individual soot agglomerates collected at four different locations on the Arctic archipelago Svalbard (Norway) were characterised by transmission electron microscopy and energy-dispersive X-ray microanalysis. For source identification of the ambient soot agglomerates, samples from different local sources (coal burning power plants in Longyearbyen and Barentsburg, diesel and oil burning for power generation in Sveagruva and Ny Ålesund, cruise ship) as well as from other sources which may contribute to Arctic soot concentrations (biomass burning, aircraft emissions, diesel engines) were investigated. Diameter and graphene sheet separation distance of soot primary particles were found to be highly variable within each source and are not suited for source identification. In contrast, concentrations of the minor elements Si, P, K, Ca and Fe showed significant differences which can be used for source attribution. The presence/absence of externally mixed particle groups (fly ashes, tar balls, mercury particles) gives additional hints about the soot sources. Biomass/wood burning, ship emissions and coal burning in Barentsburg can be excluded as major source for ambient soot at Svalbard. The coal power plant in Longyearbyen is most likely a major source of soot in the settlement of Longyearbyen but does not contribute significantly to soot collected at the Global Atmosphere Watch station Zeppelin Mountain near Ny Ålesund. The most probable soot sources at Svalbard are aircraft emissions and diesel exhaust as well as long range transport of coal burning emissions.

  11. Soot reduction under DC electric fields in counterflow non-premixed laminar ethylene flames

    KAUST Repository

    Park, Daegeun

    2014-04-23

    The effects of DC electric fields on non-premixed ethylene flames in a counterflow burner were studied experimentally with a focus on the reduction of soot particles. The experiment was conducted by connecting a high voltage terminal and a ground terminal to a lower (fuel) and upper (oxidizer) nozzle, respectively. We applied direct current (DC) potentials in a range of -5 kV < Vdc < 5 kV. Uniform electric fields were then generated in the gap between the two nozzles. The experimental conditions were selected to cover both soot formation (SF) and soot formation oxidation (SFO) flames. The flames subjected to the negative electric fields moved toward the fuel nozzle because of an ionic wind due to the Lorentz force acting on the positive ions in the flames. In addition, the yellow luminosity significantly decreased, indicating changes in the sooting characteristics. To analyze the sooting characteristics under the electric fields, planar laser induced incandescence (PLII) and fluorescence (PLIF) techniques were used to visualize the soot, polycyclic aromatic hydrocarbons (PAHs), and OH radicals. The sooting limits in terms of the fuel and oxygen mole fractions were measured. No substantial soot formation due to the effects of the DC electric fields for the tested range of voltages and reactant mole fractions could be identified. The detailed flame behaviors and sooting characteristics under the DC electric fields are discussed. Copyright © Taylor & Francis Group, LLC.

  12. Super Boiler: Packed Media/Transport Membrane Boiler Development and Demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Liss, William E; Cygan, David F

    2013-04-17

    Gas Technology Institute (GTI) and Cleaver-Brooks developed a new gas-fired steam generation system the Super Boiler for increased energy efficiency, reduced equipment size, and reduced emissions. The system consists of a firetube boiler with a unique staged furnace design, a two-stage burner system with engineered internal recirculation and inter-stage cooling integral to the boiler, unique convective pass design with extended internal surfaces for enhanced heat transfer, and a novel integrated heat recovery system to extract maximum energy from the flue gas. With these combined innovations, the Super Boiler technical goals were set at 94% HHV fuel efficiency, operation on natural gas with <5 ppmv NOx (referenced to 3%O2), and 50% smaller than conventional boilers of similar steam output. To demonstrate these technical goals, the project culminated in the industrial demonstration of this new high-efficiency technology on a 300 HP boiler at Clement Pappas, a juice bottler located in Ontario, California. The Super Boiler combustion system is based on two stage combustion which combines air staging, internal flue gas recirculation, inter-stage cooling, and unique fuel-air mixing technology to achieve low emissions rather than external flue gas recirculation which is most commonly used today. The two-stage combustion provides lower emissions because of the integrated design of the boiler and combustion system which permit precise control of peak flame temperatures in both primary and secondary stages of combustion. To reduce equipment size, the Super Boiler's dual furnace design increases radiant heat transfer to the furnace walls, allowing shorter overall furnace length, and also employs convective tubes with extended surfaces that increase heat transfer by up to 18-fold compared to conventional bare tubes. In this way, a two-pass boiler can achieve the same efficiency as a traditional three or four-pass firetube boiler design. The Super Boiler is consequently

  13. Heterogeneous reaction of SO2 with soot: The roles of relative humidity and surface composition of soot in surface sulfate formation

    Science.gov (United States)

    Zhao, Yan; Liu, Yongchun; Ma, Jinzhu; Ma, Qingxin; He, Hong

    2017-03-01

    The conversion of SO2 to sulfates on the surface of soot is still poorly understood. Soot samples with different fractions of unsaturated hydrocarbons and oxygen-containing groups were prepared by combusting n-hexane under well-controlled conditions. The heterogeneous reaction of SO2 with soot was investigated using in situ attenuated total internal reflection infrared (ATR-IR) spectroscopy, ion chromatography (IC) and a flow tube reactor at the ambient pressure and relative humidity (RH). Water promoted SO2 adsorption and sulfate formation at the RH range from 6% to 70%, while exceeded water condensed on soot was unfavorable for sulfate formation due to inhibition of SO2 adsorption when RH was higher than 80%. The surface composition of soot, which was governed by combustion conditions, also played an important role in the heterogeneous reaction of SO2 with soot. This effect was found to greatly depend on RH. At low RH of 6%, soot with the highest fuel/oxygen ratio of 0.162 exhibited a maximum uptake capacity for SO2 because it contained a large amount of aromatic Csbnd H groups, which acted as active sites for SO2 adsorption. At RH of 54%, soot produced with a fuel/oxygen ratio of 0.134 showed the highest reactivity toward SO2 because it contained appropriate amounts of aromatic Csbnd H groups and oxygen-containing groups, subsequently leading to the optimal surface concentrations of both SO2 and water. These results suggest that variation in the surface composition of soot from different sources and/or resulting from chemical aging in the atmosphere likely affects the conversion of SO2 to sulfates.

  14. The investigation of the locomotive boiler material

    International Nuclear Information System (INIS)

    Tucholski, Z.; Wasiak, J.; Bilous, W.; Hajewska, E.

    2006-01-01

    In the paper, the history of narrow-gauge railway system is described. The other information about the steam locomotive construction, as well as the technical regulations of its construction and exploitation are also done. The results of the studies of the locomotive boiler material are presented. (authors)

  15. Modelling and simulating fire tube boiler performance

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    2003-01-01

    : a zone submerged in water and a zone covered by steam), a model for the material in the boiler (the steel) and 2 models for resp. the water/steam zone (the boiling) and the steam. The dynamic model has been developed as a number of Differential-Algebraic-Equation system (DAE). Subsequently Mat...

  16. Model boiler studies on deposition and corrosion

    International Nuclear Information System (INIS)

    Balakrishnan, P.V.; McVey, E.G.

    1977-09-01

    Deposit formation was studied in a model boiler, with sea-water injections to simulate the in-leakage which could occur from sea-water cooled condensers. When All Volatile Treatment (AVT) was used for chemistry control the deposits consisted of the sea-water salts and corrosion products. With sodium phosphate added to the boiler water, the deposits also contained the phosphates derived from the sea-water salts. The deposits were formed in layers of differing compositions. There was no significant corrosion of the Fe-Ni-Cr alloy boiler tube under deposits, either on the open area of the tube or in crevices. However, carbon steel that formed a crevice around the tube was corroded severely when the boiler water did not contain phosphate. The observed corrosion of carbon steel was caused by the presence of acidic, highly concentrated chloride solution produced from the sea-water within the crevice. Results of theoretical calculations of the composition of the concentrated solution are presented. (author)

  17. Environmental control during steam boiler washing

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, Marcio A.B.; Abreu Pereira, Vera L. de [Companhia Petroquimica do Nordeste (COPENE), Camacari, BA (Brazil). Div. de Engenharia Ambiental; Ringler, Ulrich E.S. [PROMON Engenharia Ltda., Salvador, BA (Brazil)

    1993-12-31

    The washing and chemical cleaning of boilers, activities of a high polluting potential, are responsible for the generation of wastewater of high contents of heavy metals, suspended solids and chemical oxygen demand (COD). This paper describes the actions carried out by COPENE - Petroquimica do Nordeste S/A - in order to reduce this problem. (author). 10 refs., 3 figs., 2 tabs.

  18. Variation of diesel soot characteristics by different types and blends of biodiesel in a laboratory combustion chamber

    Energy Technology Data Exchange (ETDEWEB)

    Omidvarborna, Hamid; Kumar, Ashok [Department of Civil Engineering, The University of Toledo, Toledo, OH (United States); Kim, Dong-Shik, E-mail: dong.kim@utoledo.edu [Department of Chemical and Environmental Engineering, The University of Toledo, Toledo, OH (United States)

    2016-02-15

    Very little information is available on the physical and chemical properties of soot particles produced in the combustion of different types and blends of biodiesel fuels. A variety of feedstock can be used to produce biodiesel, and it is necessary to better understand the effects of feedstock-specific characteristics on soot particle emissions. Characteristics of soot particles, collected from a laboratory combustion chamber, are investigated from the blends of ultra-low sulfur diesel (ULSD) and biodiesel with various proportions. Biodiesel samples were derived from three different feedstocks, soybean methyl ester (SME), tallow oil (TO), and waste cooking oil (WCO). Experimental results showed a significant reduction in soot particle emissions when using biodiesel compared with ULSD. For the pure biodiesel, no soot particles were observed from the combustion regardless of their feedstock origins. The overall morphology of soot particles showed that the average diameter of ULSD soot particles is greater than the average soot particles from the biodiesel blends. Transmission electron microscopy (TEM) images of oxidized soot particles are presented to investigate how the addition of biodiesel fuels may affect structures of soot particles. In addition, inductively coupled plasma mass spectrometry (ICP-MS), Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA) were conducted for characterization of soot particles. Unsaturated methyl esters and high oxygen content of biodiesel are thought to be the major factors that help reduce the formation of soot particles in a laboratory combustion chamber. - Highlights: • The unsaturation of biodiesel fuel was correlated with soot characteristics. • Average diameters of biodiesel soot were smaller than that of ULSD. • Eight elements were detected as the marker metals in biodiesel soot particles. • As the degree of unsaturation increased, the oxygen content in FAMEs increased. • Biodiesel

  19. On-line monitoring system for utility boiler diagnostics

    International Nuclear Information System (INIS)

    Radovanovic, P.M.; Afgan, N.H.; Caralho, M.G.

    1997-01-01

    The paper deals with the new developed modular type Monitoring System for Utility Boiler Diagnostics. Each module is intended to assess the specific process and can be used as a stand alone application. Four modules are developed, namely: LTC - module for the on-line monitoring of parameters related to the life-time consumption of selected boiler components; TRD - module for the tube rupture detection by the position and working fluid Ieakage quantity; FAM - module for the boiler surfaces fouling (slagging) assessment and FLAP - module for visualization of the boiler furnace flame position. All four modules are tested on respective pilot plants built oil the 200 and 300 MWe utility boilers. Monitoring System is commercially available and can be realized in any combination of its modules depending on demands induced by the operational problems of specific boiler. Further development of Monitoring System is performed in accordance with the respective EU project on development of Boiler Expert System. (Author)

  20. Experimental Investigation of Nascent Soot Physical Properties and The Influence on Particle Morphology and Growth

    Science.gov (United States)

    Lieb, Sydnie Marie

    Soot released to the atmosphere is a dangerous pollutant for human health and the environment. Understanding the physical properties and surface properties of these particles is important to properly explaining the growth of soot particles in flames as well as their interactions with other particles and gases in the environment. Particles below 15 nm in diameter, nascent soot particles, dominate the early growth stages of soot formation; previously these particles were characterized as hard graphitic spheres. New evidence derived from the current dissertation work, to a large extent, challenges this prior characterization. This dissertation study begins by revisiting the use of atomic force microscope (AFM) as a tool to investigate the structural properties of nascent soot. The impact of tip artifacts, which are known to complicate measurements of features below 10 nm in diameter, are carefully considered so as to provide a concise interpretation of the morphology of nascent soot as seen by AFM. The results of the AFM morphology collaborate with earlier photo- and thermal-fragmentation particle mass spectrometry and Fourier transform infrared spectroscopy that nascent soot is not a graphitized carbon material and that they are not spherical. Furthermore, phase mode imaging is introduced as a method to investigate the physical properties of nascent soot particles in a greater detail and finer resolution. The helium ion microscope (HIM) has been identified as a useful technique for the imaging of nascent soot. Using this imaging method nascent soot particles were imaged with a high resolution that had not been obtained by prior techniques. The increased contrast provides a closer look at the nascent soot particles and further suggested that these particles are not as structurally homogeneous as previously thought. Geometric shape analysis was performed to characterize the particles in terms of sphericity, circularity, and fractal dimension. The geometric analysis

  1. Enhanced light absorption and scattering by carbon soot aerosol internally mixed with sulfuric acid.

    Science.gov (United States)

    Khalizov, Alexei F; Xue, Huaxin; Wang, Lin; Zheng, Jun; Zhang, Renyi

    2009-02-12

    Light absorption by carbon soot increases when the particles are internally mixed with nonabsorbing materials, leading to increased radiative forcing, but the magnitude of this enhancement is a subject of great uncertainty. We have performed laboratory experiments of the optical properties of fresh and internally mixed carbon soot aerosols with a known particle size, morphology, and the mixing state. Flame-generated soot aerosol is size-selected with a double-differential mobility analyzer (DMA) setup to eliminate multiply charged particle modes and then exposed to gaseous sulfuric acid (10(9)-10(10) molecule cm(-3)) and water vapor (5-80% relative humidity, RH). Light extinction and scattering by fresh and internally mixed soot aerosol are measured at 532 nm wavelength using a cavity ring-down spectrometer and an integrating nephelometer, respectively, and the absorption is derived as the difference between extinction and scattering. The optical properties of fresh soot are independent of RH, whereas soot internally mixed with sulfuric acid exhibits significant enhancement in light absorption and scattering, increasing with the mass fraction of sulfuric acid coating and relative humidity. For soot particles with an initial mobility diameter of 320 nm and a 40% H(2)SO(4) mass coating fraction, absorption and scattering are increased by 1.4- and 13-fold at 80% RH, respectively. Also, the single scattering albedo of soot aerosol increases from 0.1 to 0.5 after coating and humidification. Additional measurements with soot particles that are first coated with sulfuric acid and then heated to remove the coating show that both scattering and absorption are enhanced by irreversible restructuring of soot aggregates to more compact globules. Depending on the initial size and density of soot aggregates, restructuring acts to increase or decrease the absorption cross-section, but the combination of restructuring and encapsulation always results in an increased absorption for

  2. A computational study of ethylene–air sooting flames: Effects of large polycyclic aromatic hydrocarbons

    KAUST Repository

    Selvaraj, Prabhu

    2015-11-05

    An updated reduced gas-phase kinetic mechanism was developed and integrated with aerosol models to predict soot formation characteristics in ethylene nonpremixed and premixed flames. A primary objective is to investigate the sensitivity of the soot formation to various chemical pathways for large polycyclic aromatic hydrocarbons (PAH). The gas-phase chemical mechanism adopted the KAUST-Aramco PAH Mech 1.0, which utilized the AramcoMech 1.3 for gas-phase reactions validated for up to C2 fuels. In addition, PAH species up to coronene (C24H12 or A7) were included to describe the detailed formation pathways of soot precursors. In this study, the detailed chemical mechanism was reduced from 397 to 99 species using directed relation graph with expert knowledge (DRG-X) and sensitivity analysis. The method of moments with interpolative closure (MOMIC) was employed for the soot aerosol model. Counterflow nonpremixed flames at low strain rate sooting conditions were considered, for which the sensitivity of soot formation characteristics to different nucleation pathways were investigated. Premixed flame experiment data at different equivalence ratios were also used for validation. The findings show that higher PAH concentrations result in a higher soot nucleation rate, and that the total soot volume and average size of the particles are predicted in good agreement with experimental results. Subsequently, the effects of different pathways, with respect to pyrene- or coronene-based nucleation models, on the net soot formation rate were analyzed. It was found that the nucleation processes (i.e., soot inception) are sensitive to the choice of PAH precursors, and consideration of higher PAH species beyond pyrene is critical for accurate prediction of the overall soot formation.

  3. On the radiative properties of soot aggregates - Part 2: Effects of coating

    Science.gov (United States)

    Liu, Fengshan; Yon, Jérôme; Bescond, Alexandre

    2016-03-01

    The effects of weakly absorbing material coating on soot have attracted considerable research attention in recent years due to the significant influence of such coating on soot radiative properties and the large differences predicted by different numerical models. Soot aggregates were first numerically generated using the diffusion limited cluster aggregation algorithm to produce fractal aggregates formed by log-normally distributed polydisperse spherical primary particles in point-touch. These aggregates were then processed by adding a certain amount of primary particle overlapping and necking to simulate the soot morphology observed from transmission electron microscopy images. After this process, a layer of WAM coating of different thicknesses was added to these more realistic soot aggregates. The radiative properties of these coated soot aggregates over the spectral range of 266-1064 nm were calculated by the discrete dipole approximation (DDA) using the spectrally dependent refractive index of soot for four aggregates containing Np=1, 20, 51 and 96 primary particles. The considered coating thicknesses range from 0% (no coating) up to 100% coating in terms of the primary particle diameter. Coating enhances both the particle absorption and scattering cross sections, with much stronger enhancement to the scattering one, as well as the asymmetry factor and the single scattering albedo. The absorption enhancement is stronger in the UV than in the visible and the near infrared. The simple corrections to the Rayleigh-Debye-Gans fractal aggregates theory for uncoated soot aggregates are found not working for coated soot aggregates. The core-shell model significantly overestimates the absorption enhancement by coating in the visible and the near infrared compared to the DDA results of the coated soot particle. Treating an externally coated soot aggregate as an aggregate formed by individually coated primary particles significantly underestimates the absorption

  4. Ceria-catlyzed soot oxidation studied by environmental transmission electron microscopy

    DEFF Research Database (Denmark)

    Simonsen, S.B.; Dahl, S.; Johnson, Erik

    2008-01-01

    Environmental tranmission electron microscopy (ETEM) was used to monitor in situ ceria-catalyzed oxidation of soot in relation to diesel engine emission control.  From time-lapsed ETEM image series of soot particles in contact with CeO2. or with Al2O3 as inert reference, mechanistic and kinetic...

  5. Soot Reactivity in Conventional Combustion and Oxy-fuel Combustion Environments

    DEFF Research Database (Denmark)

    Abián, María; Jensen, Anker D.; Glarborg, Peter

    2012-01-01

    A study of the reactivity of soot produced from ethylene pyrolysis at different temperatures and CO2 atmospheres toward O2 and CO2 has been carried out using a thermogravimetric analyzer. The purpose was to quantify how soot reactivity is affected by the gas environment and temperature history of...

  6. Microwave-assisted in-situ regeneration of a perovskite coated diesel soot filter

    NARCIS (Netherlands)

    Zhang-Steenwinkel, Y.; van der Zande, L.M.; Castricum, H.L.; Bliek, A.; van den Brink, R.W.; Elzinga, G.D.

    2005-01-01

    Dielectric heating may be used as an in situ technique for the periodic regeneration of soot filters, as those used in Diesel engines. As generally the Diesel exhaust temperatures are below the soot light-off temperature, passive regeneration is not possible. Presently, we have investigated the

  7. Nanostructure and Oxidation Reactivity of Nascent Soot Particles in Ethylene/Pentanol Flames

    Directory of Open Access Journals (Sweden)

    Yaoyao Ying

    2017-01-01

    Full Text Available As byproducts of the combustion process of hydrocarbon fuels, soot particles are difficult to remove, and they can greatly harm human health and pollute the environment. Therefore, the formation and growth processes of the soot particles has become a study focus of researchers. In this paper, the nanostructure and oxidation reactivity of carbonaceous particles collected from ethylene inverse diffusion flames with or without the additions of three pentanol isomers (1-pentanol, 3-methyl-1-butanol, and 2-methyl-1-butanol were investigated in detail. The nanostructure and oxidation characteristics of nascent soot particles were characterized using high resolution transmission electron microscopy (HRTEM, X-ray diffractometry (XRD and thermogravimetric analysis (TGA. It was found that the nascent soot cluster of pure ethylene flame had a loose structure, while the additions of pentanol isomers made the soot agglomerates more compact and delayed the growth of graphitic structures. The pentanol isomer additions also contributed to a higher disorder of the crystallite arrangement in the soot nanostructure. According to the TGA experiments, the results showed that the addition of pentanol isomers enhanced the oxidation reactivity of soot particles, which could help to reduce soot particle emissions.

  8. Effects of Large Polycyclic Aromatic Hydrocarbons on the Soot Formation in Ethylene-Air Nonpremixed Flames

    KAUST Repository

    Prabhu, S.

    2015-03-30

    This study presents updated comprehensive gas-phase kinetic mechanism and aerosol models to predict soot formation characteristics in ethylene-air nonpremixed flames. A main objective is to investigate the sensitivity of the soot formation rate to various chemical pathways for large polycyclic aromatic hydrocarbons (PAH). In this study, the detailed chemical mechanism was reduced from 397 to 99 species using directed relation graph (DRG) and sensitivity analysis. The method of moments with interpolative closure (MOMIC) was employed for the soot aerosol model. Counterflow nonpremixed flames of pure ethylene at low strain rate sooting conditions are considered, for which the sensitivity of soot formation characteristics with respect to hetrogeneous nucleation is investigated. Results show that higher PAH concentrations result in higher soot nucleation rate, and that the average size of the particles are in good agreement with experimental results. It is found that the nucleation processes (i.e., soot inception) from higher PAH precursors, coronene in particular, is critical for accurate prediction of the overall soot formation.

  9. Effect of NO2 and water on the catalytic oxidation of soot

    DEFF Research Database (Denmark)

    Christensen, Jakob Munkholt; Grunwaldt, Jan-Dierk; Jensen, Anker Degn

    2017-01-01

    The influence of adding NO2 to 10 vol% O2/N2 on non-catalytic soot oxidation and soot oxidation in intimate or loose contact with a catalyst has been investigated. In non-catalytic soot oxidation the oxidation rate is increased significantly at lower temperatures by NO2. For soot oxidation in tig...... exhibited a volcano-curve dependence on the heat of oxygen chemisorption, and among the tested pure metals and oxides Cr2O3 was the most active catalyst. Further improvements were achieved with a FeaCrbOx binary oxide catalyst.......The influence of adding NO2 to 10 vol% O2/N2 on non-catalytic soot oxidation and soot oxidation in intimate or loose contact with a catalyst has been investigated. In non-catalytic soot oxidation the oxidation rate is increased significantly at lower temperatures by NO2. For soot oxidation in tight...... contact with a Co3O4 catalyst a more reactive NO2-containg atmosphere did not change the oxidation profile significantly during temperature programmed oxidation. This is consistent with the expected Mars van Krevelen mechanism, where the rate limiting step is reaction between carbon and lattice oxygen...

  10. CoFlame: A refined and validated numerical algorithm for modeling sooting laminar coflow diffusion flames

    Science.gov (United States)

    Eaves, Nick A.; Zhang, Qingan; Liu, Fengshan; Guo, Hongsheng; Dworkin, Seth B.; Thomson, Murray J.

    2016-10-01

    Mitigation of soot emissions from combustion devices is a global concern. For example, recent EURO 6 regulations for vehicles have placed stringent limits on soot emissions. In order to allow design engineers to achieve the goal of reduced soot emissions, they must have the tools to so. Due to the complex nature of soot formation, which includes growth and oxidation, detailed numerical models are required to gain fundamental insights into the mechanisms of soot formation. A detailed description of the CoFlame FORTRAN code which models sooting laminar coflow diffusion flames is given. The code solves axial and radial velocity, temperature, species conservation, and soot aggregate and primary particle number density equations. The sectional particle dynamics model includes nucleation, PAH condensation and HACA surface growth, surface oxidation, coagulation, fragmentation, particle diffusion, and thermophoresis. The code utilizes a distributed memory parallelization scheme with strip-domain decomposition. The public release of the CoFlame code, which has been refined in terms of coding structure, to the research community accompanies this paper. CoFlame is validated against experimental data for reattachment length in an axi-symmetric pipe with a sudden expansion, and ethylene-air and methane-air diffusion flames for multiple soot morphological parameters and gas-phase species. Finally, the parallel performance and computational costs of the code is investigated.

  11. Investigation of Chemical Kinetics on Soot Formation Event of n-Heptane Spray Combustion

    DEFF Research Database (Denmark)

    Pang, Kar Mun; Jangi, Mehdi; Bai, Xue-Song

    2014-01-01

    In this reported work, 2-dimsensional computational fluid dynamics studies of n-heptane combustion and soot formation processes in the Sandia constant-volume vessel are carried out. The key interest here is to elucidate how the chemical kinetics affects the combustion and soot formation events...

  12. Potassium and soot interaction in fast biomass pyrolysis at high temperatures

    DEFF Research Database (Denmark)

    Trubetskaya, Anna; Hofmann Larsen, Flemming; Shchukarev, Andrey

    2018-01-01

    This study aims to investigate the interaction between potassium and carbonaceous matrix of soot produced from wood and herbaceous biomass pyrolysis at high heating rates at 1250°C in a drop tube reactor. The influence of soot carbon chemistry and potassium content in the original biomass on the CO...

  13. A mechanistic study on the simultaneous elimination of soot and nitric oxide from engine exhaust

    KAUST Repository

    Raj, Abhijeet

    2011-04-01

    The non-catalytic interaction between soot and nitric oxide (NO) resulting in their simultaneous elimination was studied on different types of reactive site present on soot. The reaction mechanism proposed previously was extended by including seven new reaction pathways for which the reaction energetics and kinetics were studied using density functional theory and transition state theory. This has led to the calculation of a new rate for the removal of carbon monoxide (CO) from soot. The new pathways have been added to our polycyclic aromatic hydrocarbon (PAH) growth model and used to simulate the NO-soot interaction to form CO, N2 and N2O. The simulation results show satisfactory agreement with experiment for the new CO removal rate. The NO-soot reaction was found to depend strongly on the soot site type and temperature. For a set of temperatures, computed PAH structures were analysed to determine the functional groups responsible for the decrease in the reactivity of soot with NO with increasing reaction time. In isothermal conditions, it was found that as temperature is increased, the number of oxygen atoms remaining on the soot surface decreases, while the number of nitrogen atoms increases for a given reaction time. © 2010 Elsevier Ltd. All rights reserved.

  14. Dexpler: Converting Android Dalvik Bytecode to Jimple for Static Analysis with Soot

    OpenAIRE

    Bartel, Alexandre; Klein, Jacques; Monperrus, Martin; Le Traon, Yves

    2012-01-01

    International audience; This paper introduces Dexpler, a software package which converts Dalvik bytecode to Jimple. Dexpler is built on top of Dedexer and Soot. As Jimple is Soot's main internal rep- resentation of code, the Dalvik bytecode can be manipu- lated with any Jimple based tool, for instance for performing point-to or flow analysis.

  15. Oxy-Combustion Boiler Material Development

    Energy Technology Data Exchange (ETDEWEB)

    Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year

  16. Oxy-Combustion Boiler Material Development

    Energy Technology Data Exchange (ETDEWEB)

    Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to

  17. Guide to Low-Emission Boiler and Combustion Equipment Selection

    Energy Technology Data Exchange (ETDEWEB)

    Oland, CB

    2002-05-06

    Boiler owners and operators who need additional generating capacity face a number of legal, political, environmental, economic, and technical challenges. Their key to success requires selection of an adequately sized low-emission boiler and combustion equipment that can be operated in compliance with emission standards established by state and federal regulatory agencies. Recognizing that many issues are involved in making informed selection decisions, the U.S. Department of Energy (DOE), Office of Industrial Technologies (OIT) sponsored efforts at the Oak Ridge National Laboratory (ORNL) to develop a guide for use in choosing low-emission boilers and combustion equipment. To ensure that the guide covers a broad range of technical and regulatory issues of particular interest to the commercial boiler industry, the guide was developed in cooperation with the American Boiler Manufacturers Association (ABMA), the Council of Industrial Boiler Owners (CIBO), and the U.S. Environmental Protection Agency (EPA). The guide presents topics pertaining to industrial, commercial, and institutional (ICI) boilers. Background information about various types of commercially available boilers is provided along with discussions about the fuels that they burn and the emissions that they produce. Also included are discussions about emissions standards and compliance issues, technical details related to emissions control techniques, and other important selection considerations. Although information in the guide is primarily applicable to new ICI boilers, it may also apply to existing boiler installations.

  18. On Soot Inception in Nonpremixed Flames and the Effects of Flame Structure

    Science.gov (United States)

    Chao, B. H.; Liu, S.; Axelbaum, R. L.; Gokoglu, Suleyman (Technical Monitor)

    1998-01-01

    A simplified three-step model of soot inception has been employed with high activation energy asymptotics to study soot inception in nonpremixed counterflow systems with emphasis on understanding the effects of hydrodynamics and transport. The resulting scheme yields three zones: (1) a fuel oxidation zone wherein the fuel and oxidizer react to form product as well as a radical R, (e.g., H), (2) a soot/precursor formation zone where the radical R reacts with fuel to form "soot/precursor" S, and (3) a soot/precursor consumption zone where S reacts with the oxidizer to form product. The kinetic scheme, although greatly simplified, allows the coupling between soot inception and flame structure to be assessed. The results yield flame temperature, flame location, and a soot/precursor index S(sub I) as functions of Damkohler number for S formation. The soot/precursor index indicates the amount of S at the boundary of the formation region. The flame temperature indirectly indicates the total amount of S integrated over the formation region because as S is formed less heat release is available. The results show that unlike oxidation reactions, an extinction turning-point behavior does not exist for soot. Instead, the total amount of S slowly decreases with decreasing Damkohler number (increasing strain rate), which is consistent with counterflow flame experiments. When the Lewis number of the radical is decreased from unity, the total S reduces due to reduced residence time for the radical in the soot formation region. Similarly, when the Lewis number of the soot/precursor is increased from unity the amount of S increases for all Damkohler numbers. In addition to studying fuel-air (low stoichiometric mixture fraction) flames, the air-side nitrogen was substituted into the fuel, yielding diluted fuel-oxygen (high stoichiometric mixture fraction) flames with the same flame temperature as the fuel - air flames. The relative flame locations were different however, and

  19. Measurements of soot formation and hydroxyl concentration in near critical equivalence ratio premixed ethylene flame

    Science.gov (United States)

    Inbody, Michael Andrew

    1993-01-01

    The testing and development of existing global and detailed chemical kinetic models for soot formation requires measurements of soot and radical concentrations in flames. A clearer understanding of soot particle inception relies upon the evaluation and refinement of these models in comparison with such measurements. We present measurements of soot formation and hydroxyl (OH) concentration in sequences of flat premixed atmospheric-pressure C2H4/O2/N2 flames and 80-torr C2H4/O2 flames for a unique range of equivalence ratios bracketting the critical equivalence ratio (phi(sub c)) and extending to more heavily sooting conditions. Soot volume fraction and number density profiles are measured using a laser scattering-extinction apparatus capable of resolving a 0.1 percent absorption. Hydroxyl number density profiles are measured using laser-induced fluorescence (LIF) with broadband detection. Temperature profiles are obtained from Rayleigh scattering measurements. The relative volume fraction and number density profiles of the richer sooting flames exhibit the expected trends in soot formation. In near-phi(sub c) visibility sooting flames, particle scattering and extinction are not detected, but an LIF signal due to polycyclic aromatic hydrocarbons (PAH's) can be detected upon excitation with an argon-ion laser. A linear correlation between the argon-ion LIF and the soot volume fraction implies a common mechanistic source for the growth of PAH's and soot particles. The peak OH number density in both the atmospheric and 80-torr flames declines with increasing equivalence ratio, but the profile shape remains unchanged in the transition to sooting, implying that the primary reaction pathways for OH remain unchanged over this transition. Chemical kinetic modeling is demonstrated by comparing predictions using two current reaction mechanisms with the atmospheric flame data. The measured and predicted OH number density profiles show good agreement. The predicted benzene

  20. Detection of Soot Using a Resistivity Sensor Device Employing Thermophoretic Particle Deposition

    Directory of Open Access Journals (Sweden)

    Doina Lutic

    2010-01-01

    Full Text Available Results are reported for thermophoretic deposition of soot particles on resistivity sensors as a monitoring technique for diesel exhaust particles with the potential of improved detection limit and sensitivity. Soot with similar characteristics as from diesel exhausts was generated by a propane flame and diluted in stages. The soot in a gas flow at 240–270C∘ was collected on an interdigitated electrode structure held at a considerably lower temperature, 105–125C∘. The time delay for reaching measurable resistance values, the subsequent rate, and magnitude of resistance decrease were a function of the distance between the fingers in the electrodes and the degree of dilution of the soot containing flow. Soot deposition and subsequent removal by heating the sensor support was also performed in a real diesel exhaust. Good similarities between the behavior in our laboratory system and the real diesel exhaust were noticed.

  1. A Progress Review on Soot Experiments and Modeling in the Engine Combustion Network (ECN)

    KAUST Repository

    Skeen, Scott A.

    2016-04-05

    The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

  2. Stationary Engineers Apprenticeship. Related Training Modules. 12.1-12.9. Boilers.

    Science.gov (United States)

    Lane Community Coll., Eugene, OR.

    This learning module, one in a series of 20 related training modules for apprentice stationary engineers, deals with boilers. Addressed in the individual instructional packages included in the module are the following topics: firetube and watertube boilers; boiler construction; procedures for operating and cleaning boilers; and boiler fittings,…

  3. 46 CFR 63.25-3 - Electric hot water supply boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Electric hot water supply boilers. 63.25-3 Section 63.25... AUXILIARY BOILERS Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-3 Electric hot water supply boilers. (a) Electric hot water supply boilers that have a capacity not greater than 454...

  4. 46 CFR 52.25-7 - Electric boilers (modifies PEB-1 through PEB-19).

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Electric boilers (modifies PEB-1 through PEB-19). 52.25... ENGINEERING POWER BOILERS Other Boiler Types § 52.25-7 Electric boilers (modifies PEB-1 through PEB-19). Electric boilers required to comply with this part must meet the applicable provisions in this part and the...

  5. 40 CFR 76.6 - NOX emission limitations for Group 2 boilers.

    Science.gov (United States)

    2010-07-01

    ... boilers. 76.6 Section 76.6 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... for Group 2 boilers. (a) Beginning January 1, 2000 or, for a unit subject to section 409(b) of the Act... owner or operator of a Group 2, coal-fired boiler with a cell burner boiler, cyclone boiler, a wet...

  6. Investigations of the long-term effects of LII on soot and bath gas

    KAUST Repository

    Cenker, Emre

    2017-08-24

    A combination of high-repetition rate imaging, laser extinction measurements, two-colour soot pyrometry imaging, and high-resolution transmission electron microscopy of thermophoretically sampled soot is used to investigate the long-term and permanent effects of rapid heating of in-flame soot during laser-induced incandescence (LII). Experiments are carried out on a laminar non-premixed co-annular ethylene/air flame with various laser fluences. The high-repetition rate images clearly show that the heated and the neighbouring laser-border zones undergo a permanent transformation after the laser pulse, and advect vertically with the flow while the permanent marking is preserved. The soot volume fraction at the heated zone reduces due to the sublimation of soot and the subsequent enhanced oxidation. At the laser-border zones, however, optical thickness increases that may be due to thermophoretic forces drawing hot particles towards relatively cooler zones and the rapid compression of the bath gas induced by the pressure waves created by the expansion of the desorbed carbon clusters. Additionally sublimed carbon clusters can condense onto existing particles and contribute to increase of the optical thickness. Time-resolved two-colour pyrometry imaging show that the increased temperature of soot both in the heated and neighbouring laser-border zones persists for several milliseconds. This can be associated to the increase in the bath-gas temperature, and a change in the wavelength-dependent emissivity of soot particles induced by the thermal annealing of soot. Ex-situ analysis show that the lattice structure of the soot sampled at the laser-border zones tend to change and soot becomes more graphitic. This may be attributed to thermal annealing induced by elevated temperature.

  7. Smoke and soot control in buildings housing metalclad switchgear

    Energy Technology Data Exchange (ETDEWEB)

    Filter, R.; Jarv, T.

    1988-01-01

    Smoke, soot and pressure rise attendant to arcing faults inside metalclad switchgear compartments can cause prolonged station outages and can increase the severity of fault damages. Over 75 tests were carried out to investigate methods of limiting the damages caused by arcing faults inside metalclad switchgear. Ventilation system enhancements involving the use of a specially designed false ceiling, associated ducting, fans, and sealing of the switchgear were assessed with simulated and actual faults inside a transmission station building mock-up. Test results demonstrate that the new ventilation system design, along with metalclad sealing, can be effective in limiting smoke and soot propagation through a transmission station building during and immediately after an arcing fault. With the newly developed false ceiling design, improved personnel safety is provided through better control of hot toxic gases and aerosol resulting from an arcing fault. With the new ventilation system, rapid access to corridors and metalclad sections is possible so that clean-up after a fault can proceed almost immediately. It is concluded that the false ceiling, ventilation system enhancements, and switchgear sealing are effective and can be immediately applied. 11 refs., 18 figs., 15 tabs.

  8. Linkage between [|#11#|]morphology and optical properties of soot

    Science.gov (United States)

    Scarnato, B.; Richard, D. T.; vahidinia, S.; Hillyard, P.; Strawa, A. W.; Kirchstetter, T. W.; Preble, C.; Cuzzi, J. N.

    2011-12-01

    Black Carbon (BC) containing aerosols that are generally hydrophobic upon emission become increasingly mixed with other aerosol material through condensation and coagulation. In polluted urban air, BC becomes internally mixed with organics and sulfate on a time scale of about 12 hours. Recent studies have indicated that the photo-absorption by BC is enhanced as a consequence of the internal mixing of BC with these other aerosol materials. To estimate this absorption enhancement, we have undertaken laboratory studies involving the mixing of initially uncoated BC produced from the combustion of a methane diffusion flame with inorganic and organic compounds. Particle size distributions are used as a first indicator of coating. We use Scanning Electron Microscopy (SEM) to characterize the fractal and shape factors of the generated uncoated and coated BC (see Fig.1 and Fig.2). We create modeled aggregates with the same characteristics as those analyzed at the SEM and we initialize a radiation transfer model (ddscatt) to estimate optical properties of uncoated and coated BC. We quantify absorption enhancement due to coating as a function of aggregate morphology. We use Transmission Electron Microscopy (TEM) to determine the mixing state and to aid in distinguishing between absorption enhancement caused by fractal collapse and surface coating. This paper will show the relationships between soot morphology, coating and optical properties. SEM and TEM imaged of uncoated and coated soot a will be presented.

  9. Reduced Bed Temperature in FB-Boilers Burning Waste - part II; Saenkt baeddtemperatur i FB-pannor foer avfallsfoerbraenning - etapp 2

    Energy Technology Data Exchange (ETDEWEB)

    Niklasson, Fredrik; Pettersson, Anita; Claesson, Frida; Johansson, Andreas; Gunnarsson, Anders; Gyllenhammar, Marianne; Victoren, Anders; Gustafsson, Goeran

    2010-07-01

    This project focuses on evaluating whether lowered bed temperature in FB-boilers for waste combustion gives operational benefits, such as reduced fouling in the convection pass. If so, this mode of operation could reduce the number of unplanned boiler outages, reduce the need for soot blowing, and extend the lifetime of the superheaters at unaltered steam temperature. The project is based on full-scale experiments performed at Ryaverket in Boraas. The plant has two waste-fired 20 MW{sub t} FB-boilers. The study is based on a comparison between operational data and measurement results from two different operating conditions of the boilers. In addition to the data that normally are logged by the control system, samples of fuel, ashes, particles, and deposits were taken and subsequently analyzed. The structure of the bed ash was altered by lowering the bed temperature. Under normal boiler operation, the bed ash contains many small agglomerates that disappeared when the bed temperature was lowered. Due to this, the sand consumption of the plant could be reduced by roughly 25 %. At lowered bed temperature, the concentration of chlorine increased in the bed ash and in the recycled sand while it decreased in the ashes from the cyclone and fabric filter. The concentration of HCl in the flue gas increased as the bed temperature was lowered. This is considered a consequence of less chlorine forming alkali chlorides. Moreover, the particle measurements showed that the amount of submicron particles decreased during lowered bed temperature, which also is an indication of less alkali chlorides in the flue gas. The deposit probes showed an approximate 20 % reduction of the fouling rate when the bed temperature was lowered from 876 to 714 deg C. The chlorine content also decreased in the deposits. For the deposit probes at 500 deg C, (corresponds to a steam temperature of 465 deg C) significant amounts of KCl were found in the deposits, even when the bed temperature was lowered

  10. Control Properties of Bottom Fired Marine Boilers

    DEFF Research Database (Denmark)

    Solberg, Brian; Andersen, Palle; Karstensen, Claus M. S.

    2005-01-01

    This paper focuses on model analysis of a dynamic model of a bottom fired one-pass smoke tube boiler. Linearised versions of the model are analysed to determine how gain, time constants and right half plane zeros (caused by the shrink-and-swell phenomenon) depend on the steam flow load. Furthermore...... the interactions in the system are inspected to analyse potential benefit from using a multivariable control strategy in favour of the current strategy based on single loop theory. An analysis of the nonlinear model is carried out to further determine the nonlinear characteristics of the boiler system...... and to verify whether nonlinear control is needed. Finally a controller based on single loop theory is used to analyse if input constraints become active when rejecting transient behaviour from the disturbance steam flow. The model analysis shows large variations in system gains at steady state as function...

  11. Recovery boiler model; Soodakattilan kehitystyoe III

    Energy Technology Data Exchange (ETDEWEB)

    Janka, K.; Ylitalo, M.; Sundstroem, K.; Helke, R.; Heinola, M. [Kvaerner Pulping Oy, Tampere (Finland)

    1997-10-01

    The recovery boiler model was further tested and developed. At this moment the model includes submodels for: droplet drying, pyrolysis, char burning, gas burning and for droplet trajectory. During 1996 the formation of CH{sub 4} during pyrolysis and release of sulfur was included to the model. Further the formation of NO from fuel nitrogen and formation of thermal- NO were included to the model using Arrhenius type reaction rate equations. The calculated results are realistic and the model is used as a tool to find out methods to increase the efficiency and availability and decrease the emissions. Analysing the results of the earlier field study of 8 boilers showed that the furnace heat load, fuming rate, find the black liquor composition have influence on the enrichment of the potassium to the fly ash. (orig.)

  12. Chemical cleaning of boilers and corrosion protection

    International Nuclear Information System (INIS)

    Elhosary, A.A.

    1993-01-01

    While being assembled and installed, thermal-power equipment accumulates a large amount of corrosion products, scale (as much as 350 g/m 2 ), welding residue, and other contaminants that must be removed before the equipment is started up. This is generally done with various acids and inhibitors. For boilers this chemical cleaning process is termed pre start cleaning. In contrast, an operational cleaning of boilers is also carried out, in order to remove carbonate deposits, that interfere with heat transfer, as well as the corrosion products that accumulate with use. The techniques include rinsing with water to remove contaminants not firmly adhering to the metal surfaces, decreasing in alkali reagents to remove grease and to loosen scale, pickling in mineral and organic acids for scale removal, and passivation of the metal surface. decreasing is usually carried out in alkali reagents used are caustic soda, soda ash, tri sodium phosphate ammonia, and surface-active agents

  13. Circulating fluidized bed boiler numerical modeling

    Energy Technology Data Exchange (ETDEWEB)

    Di Maggio, T. [Electricite de France, 75 - Paris (France). Direction des Etudes et Recherches; Bursi, J.M.; Lafanechere, L.; Jestin, L. [Electricite de France (EDF), 69 - Villeurbanne (France); Roulet, V. [E.D.F./DE/CNET, 92 - La Defense (France)

    1996-12-31

    Electricite de France (EdF) is actively involved in the development of CFB power plants. Thanks to a wide Research and Development program around the 125 MWe Emile Huchet and the 250 MWe Provence units (two boilers designed by Stein-Lurgi), EdF has been able to get a good knowledge of hydrodynamics and heat transfer in the circulating loop as well as the back pass. One of the main objectives of the R and D program was to gather this information and results in a steady state operating model of a CFB boiler and to simulate the operation of the 250 MWe Provence power plant. This model has been developed before the first ignition of the Provence power plant in order to check the design and to help on-field engineers during the start-up phase. Furthermore, this model allows R and D engineers to make parametric studies and to evaluate new designs. (authors) 5 refs.

  14. Changes in radiative properties of soot contaminated maize canopy

    Science.gov (United States)

    Illes, B.; Anda, A.

    2012-04-01

    The effect of particle (Black Carbon, BC) on certain radiative characteristics of maize plants was studied over 2011 growing season in a field experiment carried out in Keszthely Agrometeorological Research Station. As the main constituent of BC, the soot that is almost exclusively responsible for light absorption by particles in the atmosphere, thus changing the radiation balance of the Earth and contributing to global warming. Maize hybrid Perlona (FAO 340) with short-season was applied as test plant. Of the two water supply treatments, the rainfed variant was sown in field plots, while compensation evapotranspirometers of the Thornthwaite type were used for the "ad libitum" treatment. The BC applied as pollutant was coming from the Hankook Tyre Company (Dunaújváros, Hungary), where it is used to improve the wear resistance of the tyres. The black carbon was chemically "pure", i.e. it is free of other contaminants (heavy metals etc.), so the reproducibility of the experiment is not problematic, unlike that of tests on other atmospheric air pollutants. Road traffic was simulated by using frequent low particle rates (3 g m-2 week-1) with a motorised sprayer of SP 415 type, during the season. The leaf area index was measured each week on the same 12 sample plants in each treatment using an LI 3000A automatic planimeter (LI-COR, Lincoln, NE). The impact of black carbon on plant radiative properties were analysed in the field (about 0.3 ha/treatment). Pyranometers of the CMA-11 type (Kipp & Zonen, Vaisala) were installed on columns of adjustable height in the centre of the 0.3 ha plots designated for albedo measurements. Data were collected using a Logbox SD (Kipp & Zonen, Vaisala) datalogger in the form of 10-minute means of samples taken every 6 seconds. BC pollution had no effect on maize growth and development. Compared with soot contaminated and control plants, we concluded that the LAI was a few percent higher in polluted plants, but this increment was not

  15. Circulating fluidized bed boilers design and operations

    CERN Document Server

    Basu, Prabir

    1991-01-01

    This book provides practicing engineers and students with insight into the design and operation of circulating fluidized bed (CFB) boilers. Through a combination of theoretical concepts and practical experience, this book gives the reader a basic understanding of the many aspects of this subject.Important environmental considerations, including solid waste disposal and predicted emissions, are addressed individually in separate chapters. This book places an emphasis on combustion, hydrodynamics, heat transfer, and material issues, and illustrates these concepts with numerous examples of pres

  16. The behavior of ash species in suspension fired biomass boilers

    DEFF Research Database (Denmark)

    Jensen, Peter Arendt

    technology a long range of research studies have been conducted, to improve our understanding of the influence and behavior of biomass ash species in suspension fired boilers. The fuel ash plays a key role with respect tooptimal boiler operation and influences phenomena’s as boiler chamber deposit formation...... formation in suspension fired boilers. The presentation provides an overview of the knowledge obtained with respect to ash species behavior insuspension fired biomass boilers. A mechanistic understanding of the fly ash formation process in biomass fired PF boilers isobtained today. A high fraction of alkali...... salt species are released to the gas phase during the initial fuel combustion process. The salt species are present in gas phase in the boil chamberand upon cooling in the convective pass aerosols are formed. Recent studies indicates that a large fraction of the residual condensed phase ash fragments...

  17. Life extension of boilers using weld overlay protection

    Energy Technology Data Exchange (ETDEWEB)

    Lai, G.; Hulsizer, P. [Welding Services Inc., Norcross, GA (United States); Brooks, R. [Welding Services Inc., Welding Services Europe, Spijkenisse (Netherlands)

    1998-12-31

    The presentation describes the status of modern weld overlay technology for refurbishment, upgrading and life extension of boilers. The approaches to life extension of boilers include field overlay application, shop-fabricated panels for replacement of the worn, corroded waterwall and shop-fabricated overlay tubing for replacement of individual tubes in superheaters, generating banks and other areas. The characteristics of weld overlay products are briefly described. Also discussed are successful applications of various corrosion-resistant overlays for life extension of boiler tubes in waste-to-energy boilers, coal-fired boilers and chemical recovery boilers. Types of corrosion and selection of weld overlay alloys in these systems are also discussed. (orig.) 14 refs.

  18. A Rule-Based Industrial Boiler Selection System

    Science.gov (United States)

    Tan, C. F.; Khalil, S. N.; Karjanto, J.; Tee, B. T.; Wahidin, L. S.; Chen, W.; Rauterberg, G. W. M.; Sivarao, S.; Lim, T. L.

    2015-09-01

    Boiler is a device used for generating the steam for power generation, process use or heating, and hot water for heating purposes. Steam boiler consists of the containing vessel and convection heating surfaces only, whereas a steam generator covers the whole unit, encompassing water wall tubes, super heaters, air heaters and economizers. The selection of the boiler is very important to the industry for conducting the operation system successfully. The selection criteria are based on rule based expert system and multi-criteria weighted average method. The developed system consists of Knowledge Acquisition Module, Boiler Selection Module, User Interface Module and Help Module. The system capable of selecting the suitable boiler based on criteria weighted. The main benefits from using the system is to reduce the complexity in the decision making for selecting the most appropriate boiler to palm oil process plant.

  19. Field Test of Boiler Primary Loop Temperature Controller

    Energy Technology Data Exchange (ETDEWEB)

    Glanville, P. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Rowley, P. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Schroeder, D. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Brand, L. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States)

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and, in some cases, return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential.

  20. Particulate emission abatement for Krakow boiler houses

    Energy Technology Data Exchange (ETDEWEB)

    Wysk, R.

    1995-12-31

    Among the many strategies for improving air quality in Krakow, one possible method is to adapt new and improved emission control technology. This project focuses on such a strategy. In order to reduce dust emissions from coal-fueled boilers, a new device called a Core Separator has been introduced in several boiler house applications. This advanced technology has been successfully demonstrated in Poland and several commercial units are now in operation. Particulate emissions from the Core Separator are typically 3 to 5 times lower than those from the best cyclone collectors. It can easily meet the new standard for dust emissions which will be in effect in Poland after 1997. The Core Separator is a completely inertial collector and is based on a unique recirculation method. It can effectively remove dust particles below 10 microns in diameter, the so-called PM-10 emissions. Its performance approaches that of fabric filters, but without the attendant cost and maintenance. It is well-suited to the industrial size boilers located in Krakow. Core Separators are now being marketed and sold by EcoInstal, one of the leading environmental firms in Poland, through a cooperative agreement with LSR Technologies.

  1. Boiler systems for nuclear powered reactors

    International Nuclear Information System (INIS)

    Cook, R.K.; George, B.V.

    1979-01-01

    A power generating plant which comprises a heat source, at least one main steam turbine and at least one main boiler heated by heat from the heat source and providing the steam to drive the turbine, comprises additionally at least one further steam turbine, smaller than the main turbine, and at least one further boiler, of lower capacity than the main boiler, and heated from the same heat source and providing steam for the further turbine. Particularly advantageous in nuclear power stations, where the heat source is a nuclear reactor, the invention enables peak loads, above the normal continuous rating of the main generators driven by the main turbines, to be met by the further turbine(s) and one or more further generators driven thereby. This enables the main turbines to be freed from the thermal stresses of rapid load changes, which stresses are more easily accommodated by the smaller and thus more tolerant further turbine(s). Thus auxiliary diesel-driven or other independent power plant may be made partly or wholly unnecessary. Further, low-load running which would be inefficient if achieved by means of the main turbine(s), can be more efficiently effected by shutting them down and using the smaller further turbine(s) instead. These latter may also be used to provide independent power for servicing the generating plant during normal operation or during emergency or other shutdown, and in this latter case may also serve as a heat sink for the shutdown reactor

  2. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2003-10-20

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  3. Role of Fluid-Dynamics in Soot Formation and Microstructure in Acetylene-Air Laminar Diffusion Flames

    Directory of Open Access Journals (Sweden)

    Praveen Pandey

    2015-03-01

    Full Text Available Residence time and thermo-chemical environment are important factors in the soot-formation process in flames. Studies have revealed that flow-dynamics plays a dominant role in soot formation process. For understanding the effect of flow dynamics on soot formation and physical structure of the soot formed in different combustion environments two types of laminar diffusion flames of Acetylene and air, a normal diffusion flame (NDF and an inverse diffusion flame (IDF have been investigated. The fuel and air supply in the reaction zone in two flame types were kept constant but the interchange of relative position of fuel and air altered the burner exit Reynolds and Froude numbers of gases, fuel/air velocity ratio and flame shape. Soot samples were collected using thermophoretic sampling on transmission electron microscope (TEM grids at different flame heights and were analyzed off-line in a Transmission Electron Microscope. Soot primary particle size, soot aggregate size and soot volume fraction were measured using an image analysis software. In NDF the maximum flame temperature was about 1525 K and 1230 K for IDF. The soot primary particles are distinctly smaller in size in IDF (between 19 – 26 nm compared to NDF (between 29–34 nm. Both NDF and IDF show chainlike branched structure of soot agglomerate with soot particles of a nearly spherical shape. The average number of soot primary particles per aggregate in NDF was in the range of 24 to 40 and in IDF it varied between 16 to 24. Soot volume fraction was between 0.6 to 1.5 ppm in NDF where as it was less than 0.2 ppm in IDF. The change in sooting characteristics of the two flame types is attributed to changed fuel/air velocity ratio, entrainment of gas molecules and thermophoresis on soot particles.

  4. Laboratory Measurements of the Effect of Sulfuric and Organic Acid Coatings on the Optical Properties of Carbon Soot Aerosols

    Science.gov (United States)

    Xue, H.; Khalizov, A.; Zhang, R.

    2008-12-01

    Aerosol particles perturb the Earth-atmosphere radiative balance through scattering and absorption of the solar energy. Soot or black carbon, produced during combustion of fossil fuels and biofuels, is the major component responsible for light absorption by aerosol particles. The variation in the reported mass-specific absorption cross-sections (MAC) of fresh soot and increased light absorption by aged soot aerosols internally mixed with non-absorbing materials are the major factors leading to large uncertainties in the evaluation of the aerosol optical effects. We have investigated the optical properties of submicron carbon soot aerosols during simulated atmospheric processing with sulfuric acid and dicarboxylic organic acids. Internally mixed soot particles with known size, morphology, and the mixing state were produced by exposing the size-classified, flame-generated soot to sulfuric acid and organic acid vapor. Light extinction and scattering by fresh and internally mixed soot were measured at 532 nm wavelength using a cavity ring-down spectrometer and an integrating nephelometer, respectively; light absorption was derived as the difference between extinction and scattering. Mass-specific absorption cross-sections for fresh and internally mixed soot aggregates were calculated using the measured effective densities of soot cores. The optical properties of fresh soot were independent of the relative humidity (RH). Internally mixed soot exhibited significant enhancement in light absorption and scattering, increasing with the mass fraction of the coating material and RH. Sulfuric acid was found to cause greater enhancement in soot optical properties than organic acids. The higher absorption and scattering resulted in the increased single scattering albedo of coated soot aerosol. The measurements indicate that the irreversible restructuring of soot aggregates to more compact globules is a major contributor to the enhanced optical properties of internally mixed soot.

  5. Emission, Structure and Optical Properties of Overfire Soot from Buoyant Turbulent Diffusion Flames

    Science.gov (United States)

    Koylu, Umit Ozgur

    The present study investigated soot and carbon monoxide emissions, and evaluated the optical properties of soot, in the overfire region of buoyant turbulent diffusion flames burning in still air. Soot and carbon monoxide emissions, and the corresponding correlation between these emissions, were studied experimentally. The optical properties of soot were investigated both experimentally and theoretically. The experiments involved gas (acetylene, propylene, ethylene, propane, methane) and liquid (toluene, benzene, n-heptane, iso-propanol, ethanol, methanol) fuels. The investigation was limited to the fuel-lean (overfire) region of buoyant turbulent diffusion flames burning in still air. Measurements included flame heights, characteristic flame residence times, carbon monoxide and soot concentrations, mixture fractions, ex-situ soot structure parameters (primary particle sizes, number of primary particles in aggregates, fractal dimensions), and in-situ optical cross sections (differential scattering, total scattering, and absorption) of soot in the overfire region of buoyant turbulent diffusion flames, emphasizing conditions in the long residence time regime where these properties are independent of position in the overfire region and flame residence time. The predictions of optical cross sections for polydisperse aggregates were based on Rayleigh-Debye-Gans theory for fractal aggregates; the predictions of this theory were evaluated by combining the TEM structure and the light scattering/extinction measurements. Carbon monoxide concentrations and mixture fractions were correlated in the overfire region of gas- and liquid -fueled turbulent diffusion flames. Soot volume fraction state relationships were observed for liquid fuels, supporting earlier observations for gas fuels. A strong correlation between carbon monoxide and soot concentrations was established in the fuel-lean region of both gas- and liquid-fueled turbulent diffusion flames. The structure and emission

  6. Soot measurements for diesel and biodiesel spray combustion under high temperature highly diluted ambient conditions

    KAUST Repository

    Zhang, Ji

    2014-11-01

    This paper presents the soot temperature and KL factor for biodiesel, namely fatty acid methyl ester (FAME) and diesel fuel combustion in a constant volume chamber using a two-color technique. The KL factor is a parameter for soot concentration, where K is an absorption coefficient and proportional to the number density of soot particles, L is the geometric thickness of the flame along the optical detection axis, and KL factor is proportional to soot volume fraction. The main objective is to explore a combustion regime called high-temperature and highly-diluted combustion (HTHDC) and compare it with the conventional and low-temperature combustion (LTC) modes. The three different combustion regimes are implemented under different ambient temperatures (800 K, 1000 K, and 1400 K) and ambient oxygen concentrations (10%, 15%, and 21%). Results are presented in terms of soot temperature and KL factor images, time-resolved pixel-averaged soot temperature, KL factor, and spatially integrated KL factor over the soot area. The time-averaged results for these three regimes are compared for both diesel and biodiesel fuels. Results show complex combined effects of the ambient temperature and oxygen concentration, and that two-color temperature for the HTHDC mode at the 10% oxygen level can actually be lower than the conventional mode. Increasing ambient oxygen and temperature increases soot temperature. Diesel fuel results in higher soot temperature than biodiesel for all three regimes. Results also show that diesel and biodiesel fuels have very different burning and sooting behavior under the three different combustion regimes. For diesel fuel, the HTHDC regime offers better results in terms of lower soot than the conventional and LTC regimes, and the 10% O2, 1400 K ambient condition shows the lowest soot concentration while maintaining a moderate two-color temperature. For biodiesel, the 15% O2, 800 K ambient condition shows some advantages in terms of reducing soot

  7. Understanding and predicting soot generation in turbulent non-premixed jet flames.

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hai (University of Southern California, Los Angeles, CA); Kook, Sanghoon; Doom, Jeffrey; Oefelein, Joseph Charles; Zhang, Jiayao; Shaddix, Christopher R.; Schefer, Robert W.; Pickett, Lyle M.

    2010-10-01

    This report documents the results of a project funded by DoD's Strategic Environmental Research and Development Program (SERDP) on the science behind development of predictive models for soot emission from gas turbine engines. Measurements of soot formation were performed in laminar flat premixed flames and turbulent non-premixed jet flames at 1 atm pressure and in turbulent liquid spray flames under representative conditions for takeoff in a gas turbine engine. The laminar flames and open jet flames used both ethylene and a prevaporized JP-8 surrogate fuel composed of n-dodecane and m-xylene. The pressurized turbulent jet flame measurements used the JP-8 surrogate fuel and compared its combustion and sooting characteristics to a world-average JP-8 fuel sample. The pressurized jet flame measurements demonstrated that the surrogate was representative of JP-8, with a somewhat higher tendency to soot formation. The premixed flame measurements revealed that flame temperature has a strong impact on the rate of soot nucleation and particle coagulation, but little sensitivity in the overall trends was found with different fuels. An extensive array of non-intrusive optical and laser-based measurements was performed in turbulent non-premixed jet flames established on specially designed piloted burners. Soot concentration data was collected throughout the flames, together with instantaneous images showing the relationship between soot and the OH radical and soot and PAH. A detailed chemical kinetic mechanism for ethylene combustion, including fuel-rich chemistry and benzene formation steps, was compiled, validated, and reduced. The reduced ethylene mechanism was incorporated into a high-fidelity LES code, together with a moment-based soot model and models for thermal radiation, to evaluate the ability of the chemistry and soot models to predict soot formation in the jet diffusion flame. The LES results highlight the importance of including an optically-thick radiation

  8. ASME Based Quality Documentation Guidelines for Power- and Recovery Boilers

    OpenAIRE

    Lappalainen, Tuomas

    2015-01-01

    The goal of this thesis was to create ASME-based quality documentation guidelines for power- and recovery boilers. The client was a large international power- and recovery boiler manufacturer. The content of this thesis is mainly a report of ASME code and its effects on quality documentation. In thesis are widely compared ASME based quality documention differences between PED/EN projects quality documentation. Also ASMEs most important elements for power- and recovery boiler projects needs fo...

  9. Optimisation of Marine Boilers using Model-based Multivariable Control

    OpenAIRE

    Solberg, Brian

    2008-01-01

    Traditionally, marine boilers have been controlled using classical single loop controllers. To optimise marine boiler performance, reduce new installation time and minimise the physical dimensions of these large steel constructions, a more comprehensive and coherent control strategy is needed. This research deals with the application of advanced control to a specific class of marine boilers combining well-known design methods for multivariable systems.This thesis presents contributions for mo...

  10. MINIMIZATION OF NO EMISSIONS FROM MULTI-BURNER COAL-FIRED BOILERS

    Energy Technology Data Exchange (ETDEWEB)

    E.G. Eddings; A. Molina; D.W. Pershing; A.F. Sarofim; T.H. Fletcher; H. Zhang; K.A. Davis; M. Denison; H. Shim

    2002-01-01

    The focus of this program is to provide insight into the formation and minimization of NO{sub x} in multi-burner arrays, such as those that would be found in a typical utility boiler. Most detailed studies are performed in single-burner test facilities, and may not capture significant burner-to-burner interactions that could influence NO{sub x} emissions. Thus, investigations of such interactions were made by performing a combination of single and multiple burner experiments in a pilot-scale coal-fired test facility at the University of Utah, and by the use of computational combustion simulations to evaluate full-scale utility boilers. In addition, fundamental studies on nitrogen release from coal were performed to develop greater understanding of the physical processes that control NO formation in pulverized coal flames--particularly under low NO{sub x} conditions. A CO/H{sub 2}/O{sub 2}/N{sub 2} flame was operated under fuel-rich conditions in a flat flame reactor to provide a high temperature, oxygen-free post-flame environment to study secondary reactions of coal volatiles. Effects of temperature, residence time and coal rank on nitrogen evolution and soot formation were examined. Elemental compositions of the char, tar and soot were determined by elemental analysis, gas species distributions were determined using FTIR, and the chemical structure of the tar and soot was analyzed by solid-state {sup 13}C NMR spectroscopy. A laminar flow drop tube furnace was used to study char nitrogen conversion to NO. The experimental evidence and simulation results indicated that some of the nitrogen present in the char is converted to nitric oxide after direct attack of oxygen on the particle, while another portion of the nitrogen, present in more labile functionalities, is released as HCN and further reacts in the bulk gas. The reaction of HCN with NO in the bulk gas has a strong influence on the overall conversion of char-nitrogen to nitric oxide; therefore, any model that

  11. Dual direction blower system powered by solar energy to reduce car cabin temperature in open parking condition

    Science.gov (United States)

    Hamdan, N. S.; Radzi, M. F. M.; Damanhuri, A. A. M.; Mokhtar, S. N.

    2017-10-01

    El-nino phenomenon that strikes Malaysia with temperature recorded more than 35°C can lead to extreme temperature rise in car cabin up to 80°C. Various problems will arise due to this extreme rising of temperature such as the occupant are vulnerable to heat stroke, emission of benzene gas that can cause cancer due to reaction of high temperature with interior compartments, and damage of compartments in the car. The current solution available to reduce car cabin temperature including tinted of window and portable heat rejection device that are available in the market. As an alternative to reduce car cabin temperature, this project modifies the car’s air conditioning blower motor into dual direction powered by solar energy and identifies its influence to temperature inside the car, parked under scorching sun. By reducing the car cabin temperature up to 10°C which equal to 14% of reduction in the car cabin temperature, this simple proposed system aims to provide comfort to users due to its capability in improving the quality of air and moisture in the car cabin.

  12. Evaluation and optimisation of phenomenological multi-step soot model for spray combustion under diesel engine-like operating conditions

    DEFF Research Database (Denmark)

    Pang, Kar Mun; Jangi, Mehdi; Bai, Xue-Song

    2015-01-01

    -empirical soot model in predicting the associated events. Numerical computation is performed using an open-source code and a chemistry coordinate mapping approach is used to expedite the calculation. A library consisting of various phenomenological multi-step soot models is constructed and integrated......, a comprehensive sensitivity analysis is carried out to appraise the existing soot formation and oxidation submodels. It is revealed that the soot formation is captured when the surface growth rate is calculated using a square root function of the soot specific surface area and when a pressure-dependent model...

  13. Energy, exergy and economic analysis of industrial boilers

    International Nuclear Information System (INIS)

    Saidur, R.; Ahamed, J.U.; Masjuki, H.H.

    2010-01-01

    In this paper, the useful concept of energy and exergy utilization is analyzed, and applied to the boiler system. Energy and exergy flows in a boiler have been shown in this paper. The energy and exergy efficiencies have been determined as well. In a boiler, the energy and exergy efficiencies are found to be 72.46% and 24.89%, respectively. A boiler energy and exergy efficiencies are compared with others work as well. It has been found that the combustion chamber is the major contributor for exergy destruction followed by heat exchanger of a boiler system. Furthermore, several energy saving measures such as use of variable speed drive in boiler's fan energy savings and heat recovery from flue gas are applied in reducing a boiler energy use. It has been found that the payback period is about 1 yr for heat recovery from a boiler flue gas. The payback period for using VSD with 19 kW motor found to be economically viable for energy savings in a boiler fan.

  14. Residual strain distribution in bent composite boiler tubes

    International Nuclear Information System (INIS)

    Tang Fei; Hubbard, Camden R.; Sarma, Gorti; Keiser, James

    2006-01-01

    Kraft recovery boilers are typically constructed of carbon steel boiler tubes clad with a corrosion resistant layer, and these composite tubes are bent and welded together to form air port panels which enable the combustion air to enter the boiler. In this paper, the through-thickness residual strain in the carbon steel layer of non-heat-treated and heat-treated composite bent tubes were measured by neutron diffraction techniques and modeled by finite element modeling. The results can be used to optimize material selection and manufacturing processes to prevent stress corrosion and corrosion fatigue cracking in the boiler tubes

  15. Simulation and testing of a new condensing boiler

    International Nuclear Information System (INIS)

    Rosa, L.; Tosato, R.

    1987-01-01

    The paper describes a new condensing boiler, characterized by the evacuation of flue-gases by natural draft. The best result is the consequent simplification of manufacturing, hook-up and operation of the boiler. Seasonal efficiency of the boiler, which operates with flue-gases conditioning to assure natural draft, rests about at same levels as for conventional condensing boilers. The authors emphasize the difficulty of simulate natural draft mechanism by mathematics because, in this case, flow of flue-gases and air at the draft diverter is strongly three-dimensional

  16. Field Test of Boiler Primary Loop Temperature Controller

    Energy Technology Data Exchange (ETDEWEB)

    Glanville, P.; Rowley, P.; Schroeder, D.; Brand, L.

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and in some cases return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential. PARR installed and monitored the performance of one type of ALM controller, the M2G from Greffen Systems, at multifamily sites in the city of Chicago and its suburb Cary, IL, both with existing OTR control. Results show that energy savings depend on the degree to which boilers are over-sized for their load, represented by cycling rates. Also savings vary over the heating season with cycling rates, with greater savings observed in shoulder months. Over the monitoring period, over-sized boilers at one site showed reductions in cycling and energy consumption in line with prior laboratory studies, while less over-sized boilers at another site showed muted savings.

  17. Small particles big effect? - Investigating ice nucleation abilities of soot particles

    Science.gov (United States)

    Mahrt, Fabian; David, Robert O.; Lohmann, Ulrike; Stopford, Chris; Wu, Zhijun; Kanji, Zamin A.

    2017-04-01

    Atmospheric soot particles are primary particles produced by incomplete combustion of biomass and/or fossil fuels. Thus soot mainly originates from anthropogenic emissions, stemming from combustion related processes in transport vehicles, industrial and residential uses. Such soot particles are generally complex mixtures of black carbon (BC) and organic matter (OM) (Bond et al., 2013; Petzold et al., 2013), depending on the sources and the interaction of the primary particles with other atmospheric matter and/or gases BC absorbs solar radiation having a warming effect on global climate. It can also act as a heterogeneous ice nucleating particle (INP) and thus impact cloud-radiation interactions, potentially cooling the climate (Lohmann, 2002). Previous studies, however, have shown conflicting results concerning the ice nucleation ability of soot, limiting the ability to predict its effects on Earth's radiation budget. Here we present a laboratory study where we systematically investigate the ice nucleation behavior of different soot particles. Commercial soot samples are used, including an amorphous, industrial carbon frequently used in coatings and coloring (FW 200, Orion Engineered Carbons) and a fullerene soot (572497 ALDRICH), e.g. used as catalyst. In addition, we use soot generated from a propane flame Combustion Aerosol Standard Generator (miniCAST, JING AG), as a proxy for atmospheric soot particles. The ice nucleation ability of these soot types is tested on size-selected particles for a wide temperature range from 253 K to 218 K, using the Horizontal Ice Nucleation Chamber (HINC), a Continuous Flow Diffusion Chamber (CFDC) (Kanji and Abbatt, 2009). Ice nucleation results from these soot surrogates will be compared to chemically more complex real world samples, collected on filters. Filters will be collected during the 2016/2017 winter haze periods in Beijing, China and represent atmospheric soot particles with sources from both industrial and residential

  18. High-throughput approach to the catalytic combustion of diesel soot

    Energy Technology Data Exchange (ETDEWEB)

    Iojoiu, Eduard Emil; Bassou, Badr; Guilhaume, Nolven; Farrusseng, David; Desmartin-Chomel, Arnold; Bianchi, Daniel; Mirodatos, Claude [Institut de recherches sur la catalyse et l' environnement de Lyon IRCELYON, UMR5256 CNRS Universite Lyon 1, 2 avenue Albert Einstein, F-69626 Villeurbanne Cedex (France); Lombaert, Karine [Renault, Diesel Innovative Catalytic Materials, Direction de l' Ingenierie Materiaux, 1 Allee Cornuel, 91510 Lardy (France)

    2008-08-30

    A methodology for the evaluation of diesel soot oxidation catalysts by high-throughput (HT) screening was developed. The optimal experimental conditions (soot amount, catalyst/soot ratio, type of contact, composition and flow rate of gas reactants) ensuring a reliable and reproducible detection of light-off temperatures in a 16 parallel channels reactor were set up. The temperature profile measured in the catalyst/soot bed under TPO conditions when the exothermic combustion of soot takes place was shown to provide an accurate measurement of the ignition. Its reproducibility and relevance were checked. The results obtained with a reference noble metal free catalyst (La{sub 0.8}Cr{sub 0.8}Li{sub 0.2}O{sub 3} perovskite) agree very well with literature data. Qualitative mechanistic features could be derived from these experiments, stressing the likely limiting step of oxygen transfer from catalyst surface to soot particulates to ignite the soot combustion. Ceria material was shown to be more appropriate than perovskite one. From an HT screening of a large diverse library (over 100 mixed oxides catalysts) under optimized conditions, about 10 new formulations were found to perform better than selected noble metal free reference materials. (author)

  19. Numerical simulation of combustion and soot under partially premixed combustion of low-octane gasoline

    KAUST Repository

    An, Yanzhao

    2017-09-23

    In-cylinder combustion visualization and engine-out soot particle emissions were investigated in an optical diesel engine fueled with low octane gasoline. Single injection strategy with an early injection timing (−30 CAD aTDC) was employed to achieve partially premixed combustion (PPC) condition. A high-speed color camera was used to record the combustion images for 150 cycles. The regulated emission of carbon dioxide, carbon monoxide, nitrogen oxides and soot mass concentration were measured experimentally. Full cycle engine simulations were performed using CONVERGE™ and the simulation results matched with the experimental results. The in-cylinder soot particle evolution was performed by coupling a reduced toluene reference fuel mechanism including the PAHs formation/oxidation reactions with particulate size mimic model. The results showed that PPC presents typical stratified combustion characteristics, which is significantly different from the conventional diesel spray-driven combustion. The in-cylinder temperature and equivalence ratio overlaid with soot-NO formation regime revealed that PPC operating condition under study mostly avoided the main sooting conditions throughout the entire combustion. The evaluation of temperature distribution showed formaldehyde could be regarded as an indicator for low temperature reactions, while hydroxyl group represents the high temperature reactions. Soot evolution happened during the combustion process, hydroxyl radicals promoted the soot oxidation.

  20. Soot Oxidation in Laminar Hydrocarbon/Air Diffusion Flames at Atmospheric Pressure. Appendix D

    Science.gov (United States)

    Xu, F.; El-Leathy, A. M.; Faeth, G. M.

    2000-01-01

    Soot oxidation was studied experimentally in laminar hydrocarbon/air diffusion flames at atmospheric pressure. Measurements were carried out along the axes of round jets burning in coflowing air considering acetylene, ethylene, proplyene and propane as fuels. Measurements were limited to the initial stages of soot oxidation (carbon consumption less than 70%) where soot oxidation mainly occurs at the surface of primary soot particles. The following properties were measured as a function of distance above the burner exit: soot concentrations by deconvoluted laser extinction, soot temperatures by deconvoluted multiline emission, soot structure by thermophoretic sampling and analysis using Transmission Electron Microscopy (TEM), concentrations of stable major gas species (N2, H2O, H2, 02, CO, CO2, CH4, C2H2, C2H4, C2H6, C3H6, and C3H8) by sampling and gas chromatography, concentrations of some radical species (H, OH, O) by the deconvoluted Li/LiOH atomic absorption technique and flow velocities by laser velocimetry. It was found that soot surface oxidation rates are not particularly affected by fuel type for laminar diffusion flames and are described reasonably well by the OH surface oxidation mechanism with a collision efficiency of 0.10, (standard deviation of 0.07) with no significant effect of fuel type in this behavior; these findings are in good agreement with the classical laminar premixed flame measurements of Neoh et al. Finally, direct rates of surface oxidation by O2 were small compared to OH oxidation for present conditions, based on estimated O2 oxidation rates due to Nagle and Strickland-Constable, because soot oxidation was completed near the flame sheet where O2 concentrations were less than 1.2% by volume.

  1. Soot Oxidation in Hydrocarbon/Air Diffusion Flames at Atmospheric Pressure. Appendix K

    Science.gov (United States)

    Xu, F.; El-Leathy, A. M.; Faeth, G. M.; Urban, D. L. (Technical Monitor); Yuan, Z.-G. (Technical Monitor)

    2001-01-01

    Soot oxidation was studied experimentally in laminar hydrocarbon/air diffusion flames at atmospheric pressure. Measurements were carried out along the axes of round jets burning in coflowing air considering acetylene, ethylene, propylene and propane as fuels. Measurements were limited to the initial stages of soot oxidation (carbon consumption less than 70%) where soot oxidation mainly occurs at the surface of primary soot particles. The following properties were measured as a function of distance above the burner exit: soot concentrations by deconvoluted laser extinction, soot temperatures by deconvoluted multiline emission, soot structure by thermophoretic sampling and analysis using Transmission Electron Microscopy (TEM), concentrations of stable major gas species (N2, H2O, H2, O2, CO, CO2, CH4, C2H2,C2H4, C2H6, C3H6, and C3H8) by sampling and gas chromatography, concentrations of some radical species (H, OH, O) by the deconvoluted Li/LiOH atomic absorption technique and flow velocities by laser velocimetry. It was found that soot surface oxidation rates are not particularly affected by fuel type for laminar diffusion flames and are described reasonably well by the OH surface oxidation mechanism with a collision efficiency of 0.10, (standard deviation of 0.07) with no significant effect of fuel type in this behavior; these findings are in good agreement with the classical laminar premixed flame measurements of Neoh et al. Finally, direct rates of surface oxidation by O2 were small compared to OH oxidation for present conditions, based on estimated O2 oxidation rates due to Nagle and Strickland-Constable (1962), because soot oxidation was completed near the flame sheet where O2 concentrations were less than 1.2% by volume.

  2. Damköhler number effects on soot formation and growth in turbulent nonpremixed flames

    KAUST Repository

    Attili, Antonio

    2015-01-01

    The effect of Damköhler number on turbulent nonpremixed sooting flames is investigated via large scale direct numerical simulation in three-dimensional n-heptane/air jet flames at a jet Reynolds number of 15,000 and at three different Damköhler numbers. A reduced chemical mechanism, which includes the soot precursor naphthalene, and a high-order method of moments are employed. At the highest Damköhler number, local extinction is negligible, while flames holes are observed in the two lowest Damköhler number cases. Compared to temperature and other species controlled by fuel oxidation chemistry, naphthalene is found to be affected more significantly by the Damköhler number. Consequently, the overall soot mass fraction decreases by more than one order of magnitude for a fourfold decrease of the Damköhler number. On the contrary, the overall number density of soot particles is approximately the same, but its distribution in mixture fraction space is different in the three cases. The total soot mass growth rate is found to be proportional to the Damköhler number. In the two lowest Da number cases, soot leakage across the flame is observed. Leveraging Lagrangian statistics, it is concluded that soot leakage is due to patches of soot that cross the stoichiometric surface through flame holes. These results show the leading order effects of turbulent mixing in controlling the dynamics of soot in turbulent flames. © 2014 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

  3. Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts

    Energy Technology Data Exchange (ETDEWEB)

    Pisarello, M.L.; Milt, V.; Peralta, M.A.; Querini, C.A.; Miro, E.E. [INCAPE, CONICET, Fac. Ingenieria Quimica, UNL, Santiago del Estero 2829, 3000 Santa Fe (Argentina)

    2002-07-03

    In this paper, previously reported findings and new results presented here are discussed with the main objective of establishing the reaction mechanism for soot oxidation on different supports and catalysts formulations. Catalysts containing Co, K and/or Ba supported on MgO, La{sub 2}O{sub 3} and CeO{sub 2} have been studied for diesel soot catalytic combustion. Among them, K/La{sub 2}O{sub 3} and K/CeO{sub 2} showed the best activity and stability for the combustion of soot with oxygen. A reaction mechanism involving the redox sites and the surface-carbonate species takes place on these catalysts. On the other hand, Co,K/La{sub 2}O{sub 3} and Co,K/CeO{sub 2} catalysts display activity for the simultaneous removal of soot and nitric oxide. The soot-catalyst contacting phenomenon was also addressed. A synergic La-K effect was observed in which the mechanical mixtures of soot with K-La{sub 2}O{sub 3} showed higher combustion rates than those observed when K and La were directly deposited on the soot surface. The effect of the addition of Ba was explored with the aim of promoting the interaction of the solid with NO{sub 2}, thus combining the NO{sub x} catalytic trap concept with the soot combustion for filter regeneration. Ba/CeO{sub 2} and Ba,K/CeO{sub 2} were effective in NO{sub x} absorption as shown in the microbalance experiments. However, the formation of stable nitrate species inhibits the soot combustion reaction.

  4. Developing a predictive model for the chemical composition of soot nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Violi, Angela [Univ. of Michigan, Ann Arbor, MI (United States); Michelsen, Hope [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Hansen, Nils [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Wilson, Kevin [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2017-04-07

    In order to provide the scientific foundation to enable technology breakthroughs in transportation fuel, it is important to develop a combustion modeling capability to optimize the operation and design of evolving fuels in advanced engines for transportation applications. The goal of this proposal is to develop a validated predictive model to describe the chemical composition of soot nanoparticles in premixed and diffusion flames. Atomistic studies in conjunction with state-of-the-art experiments are the distinguishing characteristics of this unique interdisciplinary effort. The modeling effort has been conducted at the University of Michigan by Prof. A. Violi. The experimental work has entailed a series of studies using different techniques to analyze gas-phase soot precursor chemistry and soot particle production in premixed and diffusion flames. Measurements have provided spatial distributions of polycyclic aromatic hydrocarbons and other gas-phase species and size and composition of incipient soot nanoparticles for comparison with model results. The experimental team includes Dr. N. Hansen and H. Michelsen at Sandia National Labs' Combustion Research Facility, and Dr. K. Wilson as collaborator at Lawrence Berkeley National Lab's Advanced Light Source. Our results show that the chemical and physical properties of nanoparticles affect the coagulation behavior in soot formation, and our results on an experimentally validated, predictive model for the chemical composition of soot nanoparticles will not only enhance our understanding of soot formation since but will also allow the prediction of particle size distributions under combustion conditions. These results provide a novel description of soot formation based on physical and chemical properties of the particles for use in the next generation of soot models and an enhanced capability for facilitating the design of alternative fuels and the engines they will power.

  5. Experimental Study of the Oxidation, Ignition, and Soot Formation Characteristics of Jet Fuel

    Science.gov (United States)

    2010-09-29

    by liquid vol Derived cetane number ( DNC ) = 47.1 Threshold soot index (TSI) = 14.1 Liquid density (kg/m3) = 750 RPI surrogate 1 Molar: 25.8% n...20% n-propylbenzene H/C = 1.87 MW =151 kg/kmol Aromatic content = 20% by liquid vol Derived cetane number ( DNC ) = 42.8 Threshold soot index... DNC ) = 32-57, avg = 44 Threshold soot index (TSI) = 16-26, avg = 18 Liquid density (kg/m3) = ~804 POSF 4658: average Jet A, blended from several Jet

  6. Effect of aging on morphology, hygroscopicity, and optical properties of soot aerosol

    Science.gov (United States)

    Khalizov, A. F.; Xue, H.; Pagels, J.; McMurry, P. H.; Zhang, R.

    2009-12-01

    Soot from incomplete combustion represents one of the major forms of particulate matter pollution, profoundly impacting human health, air quality, and climate. The direct and indirect radiative effects of soot aerosol depend on particle composition and morphology, which may vary significantly when aerosol is subjected to atmospheric aging. We will present an overview of a comprehensive set of experimental measurements performed in our laboratory at Texas A&M to study the effect of internal mixing with atmospheric species on morphology, hygroscopicity, and optical properties of combustion soot. In our experiments, size-classified soot aerosol was exposed to 0.1 - 1000 ppb (part per billion) mixing ratios of sulfuric acid and dicarboxylic organic acids and resulting changes particle morphology and mixing state under dry and humid conditions were characterized through mass-mobility measurements by aerosol particle mass analyzer (APM) and tandem differential mobility analyzer (TDMA). Light absorption and scattering cross-sections for well-characterized fresh and coated soot aerosol were derived using a cavity ring-down spectrometer and an integrating nephelometer in order to assess the effect of atmospheric processing on the radiative properties of atmospheric soot. Internally mixed soot shows significant changes in particle morphology, increasing with the mass fraction of the coating material and relative humidity. Restructuring was the strongest for aggregates coated by sulfuric and glutaric acids whereas succinic acid coating did not result in observable morphology change. Sulfuric acid - coated particles experienced large hygroscopic growth at sub-saturated conditions and activated to cloud droplets at atmospherically relevant supersaturations. Furthermore, coating and subsequent hygroscopic growth considerably altered the optical properties of soot aerosol, increasing light scattering and absorption cross-sections. We found that irreversible restructuring of soot

  7. Subsonic aircraft soot. A tracer documenting barriers to inter-hemispheric mixing

    Energy Technology Data Exchange (ETDEWEB)

    Pueschel, R.F. [NASA Ames Research Center, Moffett Field, CA (United States)

    1997-12-31

    Meridional observations of soot aerosols and radioactive {sup 14}C, and models of the geographic distribution of nuclear bomb-released {sup 14}C and aircraft-emitted NO{sub x}, all show strong gradients between the hemispheres. Reason for it are decade-long inter-hemispheric mixing times which are much in excess of yearlong stratospheric residence times of tracers. Vertical mixing of soot aerosol is not corroborated by {sup 14}C observations. The reason could be radiometric forces that act on strongly absorbing soot. (author) 10 refs.

  8. Effects of Structure and Hydrodynamics on the Sooting Behavior of Spherical Microgravity Diffusion Flames

    Science.gov (United States)

    Sunderland, P. B.; Axelbaum, R. L.; Urban, D. L.

    1999-01-01

    Recent experimental, numerical and analytical work has shown that the stoichiometric mixture fraction (Z(sub st)) can have a profound effect on soot formation in diffusion flames. These findings were obtained at constant flame temperature (T(sub ad)), employing the approach described in Du and Axelbaum (1995, 1996). For example, a fuel mixture containing 1 mole of ethylene and 11.28 moles of nitrogen burning in pure oxygen ((Z(sub st)) = 0.78) has the same adiabatic flame temperature (2370 K) as that of pure ethylene burning in air ((Z(sub st)) = 0.064). An important finding of these works was that at sufficiently high (Z(sub st)), flames remain blue as strain rate approaches zero in counterflow flames, or as flame height and residence time approach infinity in coflowing flames. Lin and Faeth (1996a) coined the term permanently blue to describe such flames. Two theories have been proposed to explain the appearance of permanently-blue flames at high (Z(sub st)). They are based on (1) hydrodynamics and (2) flame structure. Previous experimental studies in normal gravity are not definitive as to which, if either, mechanism is dominant because both hydrodynamics and structure suppress soot formation at high (Z(sub st)) in coflowing and counterflowing diffusion flames. In counterflow flames with (Z(sub st)) 0.5, convection at the flame is toward the oxidizer, thus enhancing soot oxidization. Thus, in counterflow flames, hydrodynamics causes soot to be convected towards the oxidizer at high (Z(sub st)) which suppresses soot formation. Axelbaum and co-workers maintain that while the direction of convection can impact soot growth and oxidation, these processes alone cannot cause permanently-blue flames. Soot growth and oxidation are dependent on the existence of soot particles and the presence of soot is invariably accompanied by yellow luminosity. Soot-particle inception, on the other hand, arises from gas-phase reactions and its dependence on flow direction is weak

  9. Deposit Probe Measurements in Large Biomass-Fired Grate Boilers and Pulverized-Fuel Boilers

    DEFF Research Database (Denmark)

    Hansen, Stine Broholm; Jensen, Peter Arendt; Jappe Frandsen, Flemming

    2014-01-01

    A number of full-scale deposit probe measuring campaigns conducted in grate-fired and suspension-fired boilers, fired with biomass, have been reviewed and compared. The influence of operational parameters on the chemistry of ash and deposits, on deposit build-up rates, and on shedding behavior has...... of the deposits formed is determined by the fly ash composition and the flue gas temperature; increases in the local flue gas temperature lead to higher contents of Si and Ca and lower contents of Cl in the deposits. The net deposit build-up rates in grate-fired and suspension-fired boilers are at similar levels......, 0–100 g/m2·h, while the ash deposit propensity is an order of magnitude larger in grate fired boilers than in suspension-fired boilers. Deposit build-up rates were found to increase at flue gas temperatures close to the melting temperatures of the fly ash. Furthermore, the rate of deposit build...

  10. Application of 1-hydroxyethylidene-1, 1-diphosphonic acid in boiler water for industrial boilers.

    Science.gov (United States)

    Zeng, Bin; Li, Mao-Dong; Zhu, Zhi-Ping; Zhao, Jun-Ming; Zhang, Hui

    2013-01-01

    The primary method used for boiler water treatment is the addition of chemicals to industrial boilers to prevent corrosion and scaling. The static scale inhibition method was used to evaluate the scale inhibition performance of 1-hydroxyethylidene-1, 1-diphosphonic acid (HEDP). Autoclave static experiments were used to study the corrosion inhibition properties of the main material for industrial boilers (20# carbon steel) with an HEDP additive in the industrial boiler water medium. The electrochemical behavior of HEDP on carbon steel corrosion control was investigated using electrochemical impedance spectroscopy and Tafel polarization techniques. Experimental results indicate that HEDP can have a good scale inhibition effect when added at a quantity of 5 to 7 mg/L at a test temperature of not more than 100 °C. To achieve a high scale inhibition rate, the HEDP dosage must be increased when the test temperature exceeds 100 °C. Electrochemical and autoclave static experimental results suggest that HEDP has a good corrosion inhibition effect on 20# carbon steel at a concentration of 25 mg/L. HEDP is an excellent water treatment agent.

  11. Materials and boiler rig testing to support chemical cleaning of once-through AGR boilers

    International Nuclear Information System (INIS)

    Tice, D.R.; Platts, N.; Raffel, A.S.; Rudge, A.

    2002-01-01

    An extensive programme of work has been carried out to evaluate two candidate inhibited cleaning solutions for possible implementation on plant, which would be the first chemical clean of an AGR boiler. The two candidate cleaning solutions considered were a Stannine-inhibited citric acid/formic acid mixture (GOM106) and inhibited hydrofluoric acid. Citric acid-based cleaning processes are widely used within the UK Power Industry. The GOM106 solution, comprising a mixture of 3% citric acid, 0.5% formic acid and 0.05% Stannine LTP inhibitor, buffered with ammonia to pH 3.5, was developed specifically for the AGR boilers during the 1970's. Although a considerable amount of materials testing work was carried out by British Energy's predecessor companies to produce a recommended cleaning procedure there were some remaining concerns with the use of GOM106, from these earlier studies, for example, an increased risk of pitting attack associated with the removal of thick 9Cr oxide deposits and a risk of unacceptable damage in critical locations such as the upper transition joints and other weld locations. Hence, additional testing was still required to validate the solution for use on plant. Inhibited hydrofluoric acid (HFA) was also evaluated as an alternative reagent to GOM106. HFA has been used extensively for cleaning mild and low'alloy steel boiler tubes in fossil-fired plant in the UK and elsewhere in Europe and is known to remove oxide quickly. Waste treatment is also easier than for the GOM106 process and some protection against damage to the boiler tube materials is provided by complexing of fluoride with ferric ion. Validation of the potential reagents and inhibitors was achieved by assessing the rate and effectiveness of oxide removal from specimens of helical boiler tubing and welds, together with establishing the extent of any metal loss or localised damage. The initial materials testing resulted in the inhibited ammoniated citric / formic acid reagent being

  12. Exergetic Modelling of Oil-Fired Steam Boilers | Ohijeagbon ...

    African Journals Online (AJOL)

    The performance variables and potential for energy savings in oil-fired industrial steam boilers were studied. Operational parameters of steam boilers using low pour fuel oil (LPFO) and diesel were used to determine thermodynamic properties of material streams and exergetic parameters. Analysis of thermodynamic ...

  13. Assessment of Some Performance Characteristics of Refuse Boiler ...

    African Journals Online (AJOL)

    A pioneer palm oil boiler unit, in an immense power self-contained oil mill, impaired by many years of accumulated depreciation, was rebuilt in the pattern of a design-out scheme aimed primarily at rehabilitating the entire boiler system to a state of functionality. The research work studied the pre-maintenance and post ...

  14. DESIGN REPORT: LOW-NOX BURNERS FOR PACKAGE BOILERS

    Science.gov (United States)

    The report describes a low-NOx burner design, presented for residual-oil-fired industrial boilers and boilers cofiring conventional fuels and nitrated hazardous wastes. The burner offers lower NOx emission levels for these applications than conventional commercial burners. The bu...

  15. Test of a small domestic boiler using different pellets

    International Nuclear Information System (INIS)

    Dias, J.; Costa, M.; Azevedo, J.L.T.

    2004-01-01

    This paper presents results from an experimental study performed on a 13 kW th commercial domestic boiler using pellets as fuel. Four different types of pellets were used and, for each one, the boiler was tested as a function of its capacity and the fan regulation affecting excess air. Measurements were performed for boiler heat load, pellet consumption rate, flue-gas temperature and composition. Mass balances allowed the calculation of the flue-gas flow rate and associated heat losses. Losses from incomplete combustion have also been quantified. Under boiler steady-state conditions the flue-gas O 2 concentration changes with boiler load and ventilation due to the regulation scheme of the boiler. Flue-gas CO shows a minimum for values of O 2 in the flue-gases of about 13%. NO x emissions are independent of excess air for low values of nitrogen in the fuel whereas, for larger values, NO x emissions increase with the O 2 present in the combustion products. The fractional conversion of the pellet nitrogen into NO x is in line with literature data. The boiler start-up was characterised by the temperature evolution inside and above the bed showing the propagation of combustion in the bed during about 10 min. During boiler start-up, a maximum in CO emissions was observed which is associated with the maximum combustion intensity, as typified by the flue-gas O 2 concentration and temperature, regardless the pellet type. (Author)

  16. Solved and unsolved problems in boiler systems. Learning from accidents

    International Nuclear Information System (INIS)

    Ozawa, Mamoru

    2000-01-01

    This paper begins with a brief review on the similarity law of conventional fossil-fuel-fired boilers. The concept is based on the fact that the heat release due to combustion in the furnace is restricted by the furnace volume but the heat absorption is restricted by the heat transfer surface area. This means that a small-capacity boiler has relatively high specific furnace heat release rate, about 10 MW/m 3 , and on the contrary a large-capacity boiler has lower value. The surface-heat-flux limit is mainly dominated by the CHF inside the water-wall tubes of the boiler furnace, about 350 kW/m 2 . This heat-flux limit is almost the same order independently on the capacity of boilers. For the safety of water-walls, it is essential to retain suitable water circulation, i.e. circulation ratio and velocity of water. This principle is a common knowledge of boiler designer, but actual situation is not the case. Newly designed boilers often suffer from similar accidents, especially burnout due to circulation problems. This paper demonstrates recent accidents encountered in practical boilers, and raises problems of rather classical but important two-phase flow and heat transfer. (author)

  17. Thermomechanical finite element analysis of hot water boiler structure

    Directory of Open Access Journals (Sweden)

    Živković Dragoljub S.

    2012-01-01

    Full Text Available The paper presents an application of the Finite Elements Method for stress and strain analysis of the hot water boiler structure. The aim of the research was to investigate the influence of the boiler scale on the thermal stresses and strains of the structure of hot water boilers. Results show that maximum thermal stresses appear in the zone of the pipe carrying wall of the first reversing chamber. This indicates that the most critical part of the boiler are weld spots of the smoke pipes and pipe carrying plate, which in the case of significant scale deposits can lead to cracks in the welds and water leakage from the boiler. The nonlinear effects were taken into account by defining the bilinear isotropic hardening model for all boiler elements. Temperature dependency was defined for all relevant material properties, i. e. isotropic coefficient of thermal expansion, Young’s modulus, and isotropic thermal conductivity. The verification of the FEA model was performed by comparing the measured deformations of the hot water boiler with the simulation results. As a reference object, a Viessmann - Vitomax 200 HW boiler was used, with the installed power of 18.2 MW. CAD modeling was done within the Autodesk Inventor, and stress and strain analysis was performed in the ANSYS Software.

  18. 46 CFR 56.50-30 - Boiler feed piping.

    Science.gov (United States)

    2010-10-01

    ... boiler. (c) Feed water regulators, heaters, and grease extractors. (1) Where feed water regulators, tubular feed water heaters, and grease extractors are installed, an alternate means of operation with... least two separate means of supplying feed water for the boilers. All feed pumps shall be fitted with...

  19. Assessment of the candidate markets for liquid boiler fuels

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-12-01

    Liquid fuels can be produced from coal in a number of indirect and direct liquefaction processes. While indirect coal liquefaction has been proved commercially outside the United States, most attention in this country has focused on the direct liquefaction processes, which include the processes under examination in this report; namely, the Exxon Donor Solvent (EDS), the H-Coal, and the Solvent Refined Coal (SRC) II processes. The objectives of the study were to: compare the boiler fuels of direct coal liquefaction with residual fuel oil (No. 6 fuel oil) including physical characteristics and environmental hazards, such as carcinogenic characteristics and toxic hazard characteristics; determine whether a boiler fuel market would exist for the coal liquefaction products given their physical characteristics and potential environmental hazards; determine the advantages of utilizing methanol as a boiler fuel on a continuous basis in commercial boilers utilizing existing technology; identify the potential regional candidate markets for direct coal liquefaction products as liquid boiler fuels; determine the distributing and handling costs associated with marketing coal liquefaction products as liquid boiler fuels; determine the current regulatory issues associated with the marketing of coal liquefaction products as boiler fuels; and determine and evaluate other institutional issues associated with the marketing of direct coal liquefaction products as boiler fuels.

  20. 30 CFR 77.411 - Compressed air and boilers; general.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Compressed air and boilers; general. 77.411 Section 77.411 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE... COAL MINES Safeguards for Mechanical Equipment § 77.411 Compressed air and boilers; general. All...

  1. Boiler inspection manipulator for Torness Power Station

    International Nuclear Information System (INIS)

    Carrey, R.T.A.; Playle, M.J.

    1996-01-01

    In-service inspection at Torness Advanced Gas-cooled Reactor is achieved, via penetrations above and below the core area and boilers and through eight circulator penetrations for inspection of the sub-diagrid area. A manipulator is described which can access the area above the reactor core via any of these eight peripheral penetrations. The design and fabrication of the manipulator has led to innovation with a number of possible solutions being tendered. In reactor deployment of the successful design is expected in early 1997. (UK)

  2. Optimisation of Marine Boilers using Model-based Multivariable Control

    DEFF Research Database (Denmark)

    Solberg, Brian

    Traditionally, marine boilers have been controlled using classical single loop controllers. To optimise marine boiler performance, reduce new installation time and minimise the physical dimensions of these large steel constructions, a more comprehensive and coherent control strategy is needed....... This research deals with the application of advanced control to a specific class of marine boilers combining well-known design methods for multivariable systems. This thesis presents contributions for modelling and control of the one-pass smoke tube marine boilers as well as for hybrid systems control. Much...... of the focus has been directed towards water level control which is complicated by the nature of the disturbances acting on the system as well as by low frequency sensor noise. This focus was motivated by an estimated large potential to minimise the boiler geometry by reducing water level fluctuations...

  3. Boiling process modelling peculiarities analysis of the vacuum boiler

    Science.gov (United States)

    Slobodina, E. N.; Mikhailov, A. G.

    2017-06-01

    The analysis of the low and medium powered boiler equipment development was carried out, boiler units possible development directions with the purpose of energy efficiency improvement were identified. Engineering studies for the vacuum boilers applying are represented. Vacuum boiler heat-exchange processes where boiling water is the working body are considered. Heat-exchange intensification method under boiling at the maximum heat- transfer coefficient is examined. As a result of the conducted calculation studies, heat-transfer coefficients variation curves depending on the pressure, calculated through the analytical and numerical methodologies were obtained. The conclusion about the possibility of numerical computing method application through RPI ANSYS CFX for the boiling process description in boiler vacuum volume was given.

  4. The structure and behavior of salts in kraft recovery boilers

    Energy Technology Data Exchange (ETDEWEB)

    Backman, R.; Badoi, R.D.; Enestam, S. [Aabo Akademi Univ., Turku (Finland). Combustion Chemistry Research Group

    1997-10-01

    The melting behavior in the salt system (Na,K)(CO{sub 3},SO{sub 4},S,Cl,OH) is investigated by laboratory methods to enhance and further develop a chemical model for salt mixtures with compositions relevant for recovery boilers. The model, based on both literature data and experimental work can be used as (a) submodel in models for the over-all chemistry in recovery boilers and to estimate (b) deposit formation on heat transfer surfaces (fouling), (c) the melting properties of the fly ash, and (d) the smelt bed in recovery boilers. Experimental techniques used are thermal analysis, high temperature microscopy` and scanning electron microscopy. The model is implemented in a global calculation model which can handle both gas phases and condensed phases in the recovery boiler. The model gives a detailed description of the chemical reactions involved in the fume and dust formation in different locations of the flue gas channel in the boiler. (orig.)

  5. Instabilities and soot formation in spherically expanding, high pressure, rich, iso-octane-air flames

    Energy Technology Data Exchange (ETDEWEB)

    Lockett, R D [School of Engineering and Mathematical Sciences, City University, Northampton Square, London EC1V OHB (United Kingdom)

    2006-07-15

    Flame instabilities, cellular structures and soot formed in high pressure, rich, spherically expanding iso-octane-air flames have been studied experimentally using high speed Schlieren cinematography, OH fluorescence, Mie scattering and laser induced incandescence. Cellular structures with two wavelength ranges developed on the flame surface. The larger wavelength cellular structure was produced by the Landau-Darrieus hydrodynamic instability, while the short wavelength cellular structure was produced by the thermal-diffusive instability. Large negative curvature in the short wavelength cusps caused local flame quenching and fracture of the flame surface. In rich flames with equivalence ratio {phi} > 1.8, soot was formed in a honeycomb-like structure behind flame cracks associated with the large wavelength cellular structure induced by the hydrodynamic instability. The formation of soot precursors through low temperature pyrolysis was suggested as a suitable mechanism for the initiation of soot formation behind the large wavelength flame cracks.

  6. Laser-Induced Emissions Sensor for Soot Mass in Rocket Plumes Project

    Data.gov (United States)

    National Aeronautics and Space Administration — A method is proposed to measure soot mass concentration non-intrusively from a distance in a rocket engine exhaust stream during ground tests using laser-induced...

  7. Laser-Induced Emissions Sensor for Soot Mass in Rocket Plumes, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — A method is proposed to measure soot mass concentration non-intrusively from a distance in a rocket engine exhaust stream during ground tests using laser-induced...

  8. Development of a novel heterogeneous flow reactor -- Soot formation and nanoparticle catalysis

    Science.gov (United States)

    Camacho, Joaquin

    The development of novel experimental approaches to investigate fundamental surface kinetics is presented. Specifically, fundamental soot formation and surface catalysis processes are examined in isolation from other competing processes. In terms of soot formation, two experimental techniques are presented: the Burner Stabilized Stagnation (BSS) flame configuration is extended to isolate the effect of the parent fuel structure on soot formation and the fundamental rate of surface oxidation for nascent soot is measured in a novel aerosol flow reactor. In terms of nanoparticles, the physical and chemical properties of freely suspended nanoparticles are investigated in a novel aerosol flow reactor for methane oxidation catalyzed by palladium. The role of parent fuel structure within soot formation is examined by following the time resolved formation nascent soot from the onset of nucleation to later growth stages for premixed BSS flames. Specifically, the evolution of the detailed particle size distribution function (PSDF) is compared for butanol, butane and C6 hydrocarbons in two separate studies where the C/O ratio and temperature are fixed. Under this constraint, the overall sooting process were comparable as evidenced by similar time resolved bimodal PSDF. However, the nucleation time and the persistence of nucleation with time is strongly dependent upon the structure of the parent fuel. For the C6 hydrocarbon fuels, the fastest onset of soot nucleation is observed in cyclohexane and benzene flames and this may be due to significant aromatic formation that is predicted in the pre-flame region. In addition, the evolution of the PSDF shows that nucleation ends sooner in cylclohexane and benzene flames and this may be due to relatively quick depletion of soot precursors such as acetylene and benzene. Interestingly,within the butanol fuels studied the effect of the branched chain in i-butanol and i-butane was more significant than the presence of fuel bound oxygen. A

  9. Effects of methyl group on aromatic hydrocarbons on the nanostructures and oxidative reactivity of combustion-generated soot

    KAUST Repository

    Guerrero Peña, Gerardo D.J.

    2016-07-23

    The substituted and unsubstituted aromatic hydrocarbons, present in transportation fuels such as gasoline and diesel, are thought to be responsible for most of the soot particles produced during their combustion. However, the effects of the substituted alkyl groups on the aromatic hydrocarbons on their sooting tendencies, and on the physical and chemical properties of soot produced from them are not well understood. In this work, the effect of the presence of methyl groups on aromatic hydrocarbons on their sooting propensity, and on the oxidative reactivity, morphology, and chemical composition of soot generated from them in diffusion flames is studied using benzene, toluene, and m-xylene as fuels. Several experimental techniques including high resolution transmission electron microscopy and X-ray diffraction are used to identify the morphological changes in soot, whereas the elemental and thermo-gravimetric analyses, electron energy loss spectroscopy, and Fourier transform infrared spectroscopy are used to study the changes in its chemical properties and reactivity. The activation energies for soot oxidation are calculated at different conversion levels, and a trend in the reactivity of soots from benzene, toluene and m-xylene is reported. It is observed that the sizes of primary particles and graphene-like sheets, and the concentrations of aliphatics and oxygenated groups in soot particles decreased with the addition of methyl group(s) on the aromatic ring. The physicochemical changes in soot are found to support the oxidative reactivity trends. © 2016 The Combustion Institute

  10. Establishing an energy efficiency recommendation for commercial boilers

    International Nuclear Information System (INIS)

    Ware, Michelle J.

    2000-01-01

    To assist the federal government in meeting its energy reduction goals, President Clinton's Executive Order 12902 established the Procurement Challenge, which directed all federal agencies to purchase equipment within the top 25th percentile of efficiency. Under the direction of DOE's Federal Energy Management Program (FEMP), the Procurement Challenge's goal is to create efficiency recommendations for all energy-using products that could substantially impact the government's energy reduction goals, like commercial boilers. A typical 5,000,000 Btuh boiler, with a thermal efficiency of 83.2%, can have lifetime energy cost savings of$40,000 when compared to a boiler with a thermal efficiency of 78%. For the federal market, which makes up 2% of the boiler market, this means lifetime energy cost savings of over$25,600,000. To establish efficiency recommendations, FEMP uses standardized performance ratings for products sold in the marketplace. Currently, the boiler industry uses combustion efficiency and, sometimes, thermal efficiency performance measures when specifying a commercial boiler. For many years, the industry has used these efficiency measures interchangeably, causing confusion about boiler performance measurements, and making it difficult for FEMP to establish the top 25th percentile of efficiency. This paper will illustrate the method used to establish FEMP's recommendation for boilers. The method involved defining a correlation between thermal and combustion efficiency among boiler classifications; using the correlation to model a data set of all the boiler types available in the market; and identifying how the correlation affected the top 25th percentile analysis. The paper also will discuss the applicability of this method for evaluating other equipment for which there are limited data on performance ratings

  11. Establishing an energy efficiency recommendation for commercial boilers

    Energy Technology Data Exchange (ETDEWEB)

    Ware, Michelle J.

    2000-08-01

    To assist the federal government in meeting its energy reduction goals, President Clinton's Executive Order 12902 established the Procurement Challenge, which directed all federal agencies to purchase equipment within the top 25th percentile of efficiency. Under the direction of DOE's Federal Energy Management Program (FEMP), the Procurement Challenge's goal is to create efficiency recommendations for all energy-using products that could substantially impact the government's energy reduction goals, like commercial boilers. A typical 5,000,000 Btuh boiler, with a thermal efficiency of 83.2%, can have lifetime energy cost savings of $40,000 when compared to a boiler with a thermal efficiency of 78%. For the federal market, which makes up 2% of the boiler market, this means lifetime energy cost savings of over $25,600,000. To establish efficiency recommendations, FEMP uses standardized performance ratings for products sold in the marketplace. Currently, the boiler industry uses combustion efficiency and, sometimes, thermal efficiency performance measures when specifying a commercial boiler. For many years, the industry has used these efficiency measures interchangeably, causing confusion about boiler performance measurements, and making it difficult for FEMP to establish the top 25th percentile of efficiency. This paper will illustrate the method used to establish FEMP's recommendation for boilers. The method involved defining a correlation between thermal and combustion efficiency among boiler classifications; using the correlation to model a data set of all the boiler types available in the market; and identifying how the correlation affected the top 25th percentile analysis. The paper also will discuss the applicability of this method for evaluating other equipment for which there are limited data on performance ratings.

  12. Comparison of Preparation Methods of Copper Based PGMFree Diesel-Soot Oxidation Catalysts

    Directory of Open Access Journals (Sweden)

    R. Prasad

    2011-05-01

    Full Text Available CuO-CeO2 systems have been proposed as a promising catalyst for low temperature diesel-soot oxidation. CuO-CeO2 catalysts prepared by various methods were examined for air oxidation of the soot in a semi batch tubular flow reactor. The air oxidation of soot was carried out under tight contact with soot/catalyst ratio of 1/10. Air flow rate was 150 ml/min, soot-catalyst mixture was 110 mg, heating rate was 5 0C/min. Prepared catalysts were calcined at 500 0C and their stability was examined by further heating to 800 0C for 4 hours. It was found that the selectivity of all the catalysts was nearly 100% to CO2 production. It was observed that the activity and stability of the catalysts greatly influenced by the preparation methods. The strong interaction between CuO and CeO2 is closely related to the preparation route that plays a crucial role in the soot oxidation over the CuO-CeO2 catalysts. The ranking order of the preparation methods of the catalysts in the soot oxidation performance is as follows: sol-gel > urea nitrate combustion > Urea gelation method > thermal decomposition > co-precipitation. Copyright © 2011 BCREC UNDIP. All rights reserved.(Received: 27th June 2010, Revised: 7th August 2010; Accepted: 13rd October 2010[How to Cite: R. Prasad, V.R. Bella. (2011. Comparison of Preparation Methods of Copper Based PGMFree Diesel-Soot Oxidation Catalysts. Bulletin of Chemical Reaction Engineering and Catalysis, 6(1: 15-21. doi:10.9767/bcrec.6.1.822.15-21][How to Link / DOI: http://dx.doi.org/10.9767/bcrec.6.1.822.15-21 || or local: http://ejournal.undip.ac.id/index.php/bcrec/article/view/822 | View in 

  13. Effects of ambient oxygen concentration on soot temperature and concentration for biodiesel and diesel spray combustion

    KAUST Repository

    Zhang, Ji

    2015-06-01

    Ambient oxygen concentration, a key variable directly related to exhaust gas recirculation (EGR) levels in diesel engines, plays a significant role in particulate matter (PM) and nitrogen oxides (NOx) emissions. The utilization of biodiesel in diesel engines has been investigated over the last decades for its renewable characteristics and lower emissions compared to diesel. In an earlier work, we demonstrated that the soot temperature and concentration of biodiesel were lower than diesel under regular diesel engine conditions without EGR. Soot concentration was quantified by a parameter called KL factor. As a continuous effort, this paper presents an experimental investigation of the ambient oxygen concentration on soot temperature and KL factor during biodiesel and diesel spray combustion. The experiment was implemented in a constant volume chamber system, where the ambient oxygen concentration varied from 21 to 10% and the ambient temperature was kept to 1,000 K. A high speed two-color pyrometry technique was used to measure transient soot temperature and the KL factor of the spray flame. The soot temperature of biodiesel is found to be lower than that of diesel under the same conditions, which follows the same trend from our previous results found when the ambient temperature changes to 21% oxygen conditions. A reduction in ambient oxygen concentration generally reduces the soot temperature for both fuels. However, this is a complicated effect on soot processes as the change of oxygen concentration greatly affects the balance between soot formation and oxidation. The KL factor is observed to be the highest at 12% O2 for diesel and 18% O2 for biodiesel, respectively. On the other hand, the 10% O2 condition shows the lowest KL factor for both fuels. These results can provide quantitative experimental evidences to optimize the ambient oxygen concentration for diesel engines using different fuels for better emissions characteristics. © 2014 American Society of

  14. The monolithic transition metal oxide crossed nanosheets used for diesel soot combustion under gravitational contact mode

    Science.gov (United States)

    Cao, Chunmei; Xing, Lingli; Yang, Yuexi; Tian, Ye; Ding, Tong; Zhang, Jing; Hu, Tiandou; Zheng, Lirong; Li, Xingang

    2017-06-01

    Crossed nanosheets of transition metal oxide (TMO-NS: Co-NS, Mn-NS and Fe-NS) were synthesized by a facile hydrothermal method and employed for soot combustion in the NO/O2/N2 and O2/N2 atmosphere under gravitational contact mode (GCM). They show high catalytic activities for soot combustion due to the macroporous structure of the as-prepare catalysts increasing the soot-catalyst contact efficiency. The XRD and XPS results reveal that the active phases in the corresponding catalysts exist as Co3O4, Mn2O3 and Fe2O3, respectively. Among these catalysts, the Co-NS shows the best activity for soot combustion, especially in the presence of NO, whose catalytic activity of T50 (391 °C) and SCO2 (100%) is as good as that of the Pt/Al2O3 catalyst. The excellent performance of the Co-NS catalyst results from several factors: the highest intrinsic activity (TOF = 1.77 × 10-5 s-1); the highest redox property as revealed by H2-TPR and soot-TPR; the largest amount of active oxygen species as clarified by XPS; the highest ability of NO oxidation to NO2 supported by NO-TPO. In addition, the multiporous structure of Co3O4 nanosheets is facilitated for the mass transfer. In the O2 atmosphere, soot particulates are directly oxidized by the surface adsorbed oxygen. After introducing of NO, the soot particulates are readily oxidized by NO2 at the low temperature (< 330 °C); with the increase of the reaction temperature (330-450 °C), both the active oxygen species and NO2 involve in soot combustion.

  15. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-10-27

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2005.

  16. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2004-10-30

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April to June 30, 2004.

  17. 'Boilers' along the southeast coast of Bermuda

    Science.gov (United States)

    2002-01-01

    Along the south shore of Bermuda, waves break continuously along algal/vermetid reefs (composed of algae and molluscs, not coral), forming 'boilers.' Boilers are named because the continuous breaking of waves makes it look as if the sea is boiling. This photograph taken from the International Space Station shows the eastern half of the main islands of Bermuda. Land use is about 6 percent cropland, 55 percent developed and 34 percent rural. Reflective white-colored areas are buildings and other developments surrounded by green areas of vegetation. St. David's Island is also home to the airport, with runways built out into Castle Harbour. Hurricane Erin passed northeast of Bermuda early on September 10 with 115 mile-per-hour winds (a Category 3 storm on the Saffir-Simpson Scale), but causing very minimal damage. Astronauts aboard Space Station Alpha photographed the area on September 14, 2001. By then, the skies had cleared and Erin had become an extratropical low near Newfoundland. Image ISS003-E-5735, was provided by the Earth Sciences and Image Analysis Laboratory at Johnson Space Center. Additional images taken by astronauts and cosmonauts can be viewed at the NASA-JSC Gateway to Astronaut Photography of Earth.

  18. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2004-07-30

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April to June 30, 2004.

  19. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-01-31

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  20. Code boiler and pressure vessel life assessment

    International Nuclear Information System (INIS)

    Farr, J.R.

    1992-01-01

    In the United States of America and in Canada, laws and controls for determining life assessment for continued operation of equipment exist only for those pressure vessels built to Section III and evaluated according to Section XI. In this presentation, some of those considerations which are made in the USA and Canada for deciding on life or condition assessment of boilers and pressure vessels designed and constructed to other sections of the ASME Boiler and Pressure Vessel Code are reviewed. Life assessment or condition assesssment is essential in determining what is necessary for continued operation. With no ASME rules being adopted by laws or regulations, other than OSHA in the USA and similar environmental controls in Canada, to control life assessment for continued operation, the equipment owner must decide if assessment is to be done and how much to do. Some of those considerations are reviewed along with methods and procedures to make an assessment along with a discussion of where the ASME B and PV Code currently stands regarding continued operation. (orig.)

  1. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    K. Coleman; R. Viswanathan; J. Shingledecker; J. Sarver; G. Stanko; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2004-01-23

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2003.

  2. Internally mixed soot, sulfates, and organic matter in aerosol particles from Mexico City

    Science.gov (United States)

    Adachi, K.; Buseck, P. R.

    2008-05-01

    Soot particles are major aerosol constituents that result from emissions of burning of fossil fuel and biomass. Because they both absorb sunlight and contribute to cloud formation, they are an influence on climate on local, regional, and global scales. It is therefore important to evaluate their optical and hygroscopic properties and those effects on the radiation budget. Those properties commonly change through reaction with other particles or gases, resulting in complex internal mixtures. Using transmission electron microscopy, we measured ~8000 particles (25 samples) with aerodynamic diameters from 0.05 to 0.3 μm that were collected in March 2006 from aircraft over Mexico City (MC) and adjacent areas. More than 50% of the particles consist of internally mixed soot, organic matter, and sulfate. Imaging combined with chemical analysis of individual particles show that many are coated, consist of aggregates, or both. Coatings on soot particles can amplify their light absorption, and coagulation with sulfates changes their hygroscopic properties, resulting in shorter lifetime. Our results suggest that a mixture of materials from multiple sources such as vehicles, power plants, and biomass burning occurs in individual particles, thereby increasing their complexity. Through changes in their optical and hygroscopic properties, internally mixed soot particles have a greater effect on the regional climate than uncoated soot particles. Moreover, soot occurs in more than 60% of all particles in the MC plumes, suggesting its important role in the formation of secondary aerosol particles.

  3. Diffusion air effects on the soot axial distribution concentration in a premixed acetylene/air flame

    Energy Technology Data Exchange (ETDEWEB)

    Fassani, Fabio Luis; Santos, Alex Alisson Bandeira; Goldstein Junior, Leonardo [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Engenharia Termica e de Fluidos]. E-mails: fassani@fem.unicamp.br; absantos@fem.unicamp.br; leonardo@fem.unicamp.br; Ferrari, Carlos Alberto [Universidade Estadual de Campinas, SP (Brazil). Inst. de Fisica. Dept. de Eletronica Quantica]. E-mail: ferrari@ifi.unicamp.br

    2000-07-01

    Soot particles are produced during the high temperature pyrolysis or combustion of hydrocarbons. The emission of soot from a combustor, or from a flame, is determined by the competition between soot formation and its oxidation. Several factors affect these processes, including the type of fuel, the air-to-fuel ratio, flame temperature, pressure, and flow pattern. In this paper, the influence of the induced air diffusion on the soot axial distribution concentration in a premixed acetylene/air flame was studied. The flame was generated in a vertical axis burner in which the fuel - oxidant mixture flow was surrounded by a nitrogen discharge coming from the annular region between the burner tube and an external concentric tube. The nitrogen flow provided a shield that protected the flame from the diffusion of external air, enabling its control. The burner was mounted on a step-motor driven, vertical translation table. The use of several air-to-fuel ratios made possible to establish the sooting characteristics of this flame, by measuring soot concentration along the flame height with a non-intrusive laser light absorption technique. (author)

  4. The pH-dependent adsorption of tributyltin to charcoals and soot

    International Nuclear Information System (INIS)

    Fang Liping; Borggaard, Ole K.; Marcussen, Helle; Holm, Peter E.; Bruun Hansen, Hans Christian

    2010-01-01

    Widespread use of tributyltin (TBT) poses a serious environmental problem. Adsorption by black carbon (BC) may strongly affect its behavior. The adsorption of TBT to well characterized soot and two charcoals with specific surface area in the range of 62-111 m 2 g -1 have been investigated with main focus on pH effects. The charcoals but not soot possess acidic functional groups. TBT adsorption reaches maximum at pH 6-7 for charcoals, and at pH > 6 for soot. Soot has between 1.5 and 15 times higher adsorption density (0.09-1.77 μmol m -2 ) than charcoals, but charcoals show up to 17 times higher sorption affinities than soot. TBT adsorption is successfully described by a new pH-dependent dual Langmuir model considering electrostatic and hydrophobic adsorption, and pH effects on TBT speciation and BC surface charge. It is inferred that strong sorption of the TBTOH species to BC may affect TBT toxicity. - Tributyltin adsorption to black carbon increases at increasing pH but charcoal exhibits electrostatic and hydrophobic adsorption, whereas soot only adsorbs hydrophobically.

  5. Development of high fidelity soot aerosol dynamics models using method of moments with interpolative closure

    KAUST Repository

    Roy, Subrata P.

    2014-01-28

    The method of moments with interpolative closure (MOMIC) for soot formation and growth provides a detailed modeling framework maintaining a good balance in generality, accuracy, robustness, and computational efficiency. This study presents several computational issues in the development and implementation of the MOMIC-based soot modeling for direct numerical simulations (DNS). The issues of concern include a wide dynamic range of numbers, choice of normalization, high effective Schmidt number of soot particles, and realizability of the soot particle size distribution function (PSDF). These problems are not unique to DNS, but they are often exacerbated by the high-order numerical schemes used in DNS. Four specific issues are discussed in this article: the treatment of soot diffusion, choice of interpolation scheme for MOMIC, an approach to deal with strongly oxidizing environments, and realizability of the PSDF. General, robust, and stable approaches are sought to address these issues, minimizing the use of ad hoc treatments such as clipping. The solutions proposed and demonstrated here are being applied to generate new physical insight into complex turbulence-chemistry-soot-radiation interactions in turbulent reacting flows using DNS. © 2014 Copyright Taylor and Francis Group, LLC.

  6. Simultaneous schlieren photography and soot foil in the study of detonation phenomena

    Science.gov (United States)

    Kellenberger, Mark; Ciccarelli, Gaby

    2017-10-01

    The use of schlieren photography has been essential in unravelling the complex nature of high-speed combustion phenomena, but its line-of-sight integration makes it difficult to decisively determine the nature of multi-dimensional combustion wave propagation. Conventional schlieren alone makes it impossible to determine in what plane across the channel an observed structure may exist. To overcome this, a technique of simultaneous high-speed schlieren photography and soot foils was demonstrated that can be applied to the study of detonation phenomena. Using a kerosene lamp, soot was deposited on a glass substrate resulting in a semi-transparent sheet through which schlieren source light could pass. In order to demonstrate the technique, experiments were carried out in mixtures of stoichiometric hydrogen-oxygen at initial pressures between 10 and 15 kPa. Compared to schlieren imaging obtained without a sooted foil, high-speed video results show schlieren images with a small reduction of contrast with density gradients remaining clear. Areas of high temperature cause soot lofted from the foil to incandescence strongly, resulting in the ability to track hot spots and flame location. Post-processing adjustments were demonstrated to make up for camera sensitivity limitations to enable viewing of schlieren density gradients. High-resolution glass soot foils were produced that enable direct coupling of schlieren video to triple-point trajectories seen on the soot foils, allowing for the study of three-dimensional propagation mechanisms of detonation waves.

  7. Optical measurements of soot size and number density in a complex flow, swirl-stabilized combustor

    Science.gov (United States)

    Samuelsen, G. S.; Wood, C. P.; Jackson, T. A.

    1984-01-01

    In-flame optical measurements of soot particulates in a turbulent, recirculating (i.e., complex flow) model laboratory combustor are described. A nonintrusive optical probe based on large angle (60 deg, 20 deg) intensity ratio scattering was used to yield a point measurement of particulate in the size range of 0.08 to 0.38 micrometers. The performance of the optical technique was evaluated, and an exploratory assessment of the spatial distribution of soot was conducted with attention to fuel molecular structure, fuel loading, and a smoke-suppressant additive (ferrocene). Isooctane and mixtures of isooctane with various ring and aromatic compounds blended to yield the smoke point of a JP-8 stock were prevaporized and introduced through a hollow cone nozzle. The addition of ring compounds to the base isooctane substantially changed the distribution of soot and increased the overall emission by 300%. The production of soot was substantially reduced by a decrease in fuel loading, and marginally reduced or not affected by the additive depending on fuel structure. The optical technique is a potentially powerful tool for providing the experimental evidence necessary to understand the processes of soot formation and burnout in complex flows typical of gas turbine combustors. However, scanning electron micrographs of extracted sample established that the technique is limited to the large particle wing of the soot size distribution, and optical and electronic processing can induce biasing and uncertainties which must be understood and controlled before the potential of the technique can be fulfilled.

  8. Asymptotic analysis soot model and experiment for a directed injection engine

    Science.gov (United States)

    Liu, Yongfeng; Pei, Pucheng; Xiong, Qinghui; Lu, Yong

    2012-09-01

    The existing soot models are either too complex and can not be applied to the internal combustion engine, or too simple to make calculation errors. Exploring the soot model becomes the pursuit of the goal of many researchers within the error range in the current computer speed. On the basis of the latest experimental results, TP (temperature phases) model is presented as a new soot model to carry out optimization calculation for a high-pressure common rail diesel engine. Temperature and excess air factor are the most important two parameters in this model. When zone temperature T0.6, only the soot precursors—polycyclic aromatic hydrocarbons(PAH) is created and there is no soot emission. When zone temperature T ⩾ 1 500 K and excess air factor Φinjection time, variation of rail pressure and variation of speed among TP models. The experimental results indicate that the TP model can carry out optimization and computational fluid dynamics can be a tool to calculate for a high-pressure common rail directed injection diesel engine. The TP model result is closer than the use of the original KIVA-3V results of soot model accuracy by about 50% and TP model gives a new method for engine researchers.

  9. Variability in morphology, hygroscopicity, and optical properties of soot aerosols during atmospheric processing

    Science.gov (United States)

    Zhang, Renyi; Khalizov, Alexei F.; Pagels, Joakim; Zhang, Dan; Xue, Huaxin; McMurry, Peter H.

    2008-01-01

    The atmospheric effects of soot aerosols include interference with radiative transfer, visibility impairment, and alteration of cloud formation and are highly sensitive to the manner by which soot is internally mixed with other aerosol constituents. We present experimental studies to show that soot particles acquire a large mass fraction of sulfuric acid during atmospheric aging, considerably altering their properties. Soot particles exposed to subsaturated sulfuric acid vapor exhibit a marked change in morphology, characterized by a decreased mobility-based diameter but an increased fractal dimension and effective density. These particles experience large hygroscopic size and mass growth at subsaturated conditions (Coating with sulfuric acid and subsequent hygroscopic growth enhance the optical properties of soot aerosols, increasing scattering by ≈10-fold and absorption by nearly 2-fold at 80% relative humidity relative to fresh particles. In addition, condensation of sulfuric acid is shown to occur at a similar rate on ambient aerosols of various types of a given mobility size, regardless of their chemical compositions and microphysical structures. Representing an important mechanism of atmospheric aging, internal mixing of soot with sulfuric acid has profound implications on visibility, human health, and direct and indirect climate forcing. PMID:18645179

  10. 9 CFR 91.22 - Protection from heat of boilers and engines.

    Science.gov (United States)

    2010-01-01

    ... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Protection from heat of boilers and... Protection from heat of boilers and engines. No animals shall be stowed along the alleyways leading to the engine or boiler rooms unless the sides of said engine or boiler rooms are covered by a tongue and groove...

  11. 46 CFR 91.15-1 - Standards in inspection of hulls, boilers, and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Standards in inspection of hulls, boilers, and machinery... hulls, boilers, and machinery. In the inspection of hulls, boilers, and machinery of vessels, the..., respecting material and inspection of hulls, boilers, and machinery, and the certificate of classification...

  12. 30 CFR 57.13001 - General requirements for boilers and pressure vessels.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false General requirements for boilers and pressure... NONMETAL MINES Compressed Air and Boilers § 57.13001 General requirements for boilers and pressure vessels. All boilers and pressure vessels shall be constructed, installed, and maintained in accordance with...

  13. 40 CFR 63.7506 - Do any boilers or process heaters have limited requirements?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 13 2010-07-01 2010-07-01 false Do any boilers or process heaters have..., and Institutional Boilers and Process Heaters General Compliance Requirements § 63.7506 Do any boilers or process heaters have limited requirements? (a) New or reconstructed boilers and process heaters in...

  14. 46 CFR 189.15-1 - Standards in inspection of hulls, boilers, and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Standards in inspection of hulls, boilers, and machinery... inspection of hulls, boilers, and machinery. In the inspection of hulls, boilers, and machinery of vessels... chapter, respecting material and construction of hulls, boilers, and machinery, and certificate of...

  15. 49 CFR 230.20 - Alteration and repair report for steam locomotive boilers.

    Science.gov (United States)

    2010-10-01

    ... boilers. 230.20 Section 230.20 Transportation Other Regulations Relating to Transportation (Continued... boilers. (a) Alterations. When an alteration is made to a steam locomotive boiler, the steam locomotive... maintained for the life of the boiler. (See appendix B of this part.) (b) Welded and riveted repairs to...

  16. 46 CFR 61.05-5 - Preparation of boilers for inspection and test.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Preparation of boilers for inspection and test. 61.05-5... PERIODIC TESTS AND INSPECTIONS Tests and Inspections of Boilers § 61.05-5 Preparation of boilers for... preparing the boilers for the hydrostatic test, they shall be filled with water at not less than 70 °F. and...

  17. 40 CFR 63.7491 - Are any boilers or process heaters not subject to this subpart?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 13 2010-07-01 2010-07-01 false Are any boilers or process heaters not..., and Institutional Boilers and Process Heaters What This Subpart Covers § 63.7491 Are any boilers or process heaters not subject to this subpart? The types of boilers and process heaters listed in paragraphs...

  18. 40 CFR 63.7499 - What are the subcategories of boilers and process heaters?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 13 2010-07-01 2010-07-01 false What are the subcategories of boilers..., and Institutional Boilers and Process Heaters Emission Limits and Work Practice Standards § 63.7499 What are the subcategories of boilers and process heaters? The subcategories of boilers and process...

  19. 46 CFR 71.15-1 - Standards in inspection of hulls, boilers, and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 3 2010-10-01 2010-10-01 false Standards in inspection of hulls, boilers, and machinery..., boilers, and machinery. In the inspection of hulls, boilers, and machinery of vessels, the standards... and inspection of hulls, boilers, and machinery, and the certificate of classification referring...

  20. 30 CFR 56.13001 - General requirements for boilers and pressure vessels.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false General requirements for boilers and pressure... MINES Compressed Air and Boilers § 56.13001 General requirements for boilers and pressure vessels. All boilers and pressure vessels shall be constructed, installed, and maintained in accordance with the...

  1. Fuel to the nuclear debate : [Rezension von:] Nuclear power in crisis, Andrew Blowers and David Pepper (editors), New York, Nichols; London ..., Croom Helm, 1987

    OpenAIRE

    Renn, Ortwin

    1988-01-01

    Nuclear energy is one of the most popular topics of today’s publication market. The literature about the pros and cons of nuclear power may easily fill a whole library. Is there anything new to add to this voluminous body of arguments and contra-arguments that would justify editing another book on nuclear energy? Andrew Blowers and David Pepper obviously felt that way and published a reader on Nuclear Power in Crisis. The book consists of 13 articles covering mainly the political, social and ...

  2. Up-date on cyclone combustion and cyclone boilers

    Energy Technology Data Exchange (ETDEWEB)

    Carmo, Felipe Alfaia do; Nogueira, Manoel Fernandes Martins; Rocha, Rodrigo Carnera Castro da; Gazel, Hussein Felix; Martins, Diego Henrique dos Reis [Universidade Federal do Para (UFPA), Belem, PA (Brazil). Campus Universitario Jose da Silveira Netto], E-mails: mfmn@ufpa.br, mfmn@ufpa.br

    2010-07-01

    The boiler concept has been around for more than 70 years, and there are many types available. Boilers provide steam or hot water for industrial and commercial use. The Federal University of Para (UFPA) through the research group EBMA (Energy,Biomass and Environment) has been developing cyclonic furnace with a water wall, a boiler, aiming to use regional timbers (sawdust) and agro-industries residues as fuel to produce steam to be used in industrial processes as well as in power generation,. The use of cyclonic combustion for burning waste instead of burning in a fixed bed is mainly due to two factors efficiency improvement causing a more compact boiler and less risk of explosion, since their process does not generate an accumulation of volatile. Present state-of-art for commercial cyclone boilers has as set up a cyclone combustor with two combustion chambers, in fluid communication, where there ducts for supplying air and fuel directly into the first chamber and for forming a cyclonic flow pattern and a heat exchanger surrounding the second chamber for keeping low combustion temperature in both chambers. This paper shows the results of a literature review about design, construction and operation of cyclonic boilers using solid, liquid or gaseous fuel. This information has been used for the design of a cyclone boiler to be constructed at UFPA for research purposes and its basic concept is presented at the end of this article. (author)

  3. Supercritical boiler material selection using fuzzy analytic network process

    Directory of Open Access Journals (Sweden)

    Saikat Ranjan Maity

    2012-08-01

    Full Text Available The recent development of world is being adversely affected by the scarcity of power and energy. To survive in the next generation, it is thus necessary to explore the non-conventional energy sources and efficiently consume the available sources. For efficient exploitation of the existing energy sources, a great scope lies in the use of Rankin cycle-based thermal power plants. Today, the gross efficiency of Rankin cycle-based thermal power plants is less than 28% which has been increased up to 40% with reheating and regenerative cycles. But, it can be further improved up to 47% by using supercritical power plant technology. Supercritical power plants use supercritical boilers which are able to withstand a very high temperature (650-720˚C and pressure (22.1 MPa while producing superheated steam. The thermal efficiency of a supercritical boiler greatly depends on the material of its different components. The supercritical boiler material should possess high creep rupture strength, high thermal conductivity, low thermal expansion, high specific heat and very high temperature withstandability. This paper considers a list of seven supercritical boiler materials whose performance is evaluated based on seven pivotal criteria. Given the intricacy and difficulty of this supercritical boiler material selection problem having interactions and interdependencies between different criteria, this paper applies fuzzy analytic network process to select the most appropriate material for a supercritical boiler. Rene 41 is the best supercritical boiler material, whereas, Haynes 230 is the worst preferred choice.

  4. Cross connecting absorber module inlets of multiple boiler units

    International Nuclear Information System (INIS)

    Cirillo, A.J.; Sperber, P.K.; Belavadi, V.N.; Mukherji, A.

    1991-01-01

    The retrofitting of scrubbers downstream of existing balanced draft boilers is often accomplished by the addition of induced draft (ID) booster fans. By creating a common plenum between the ID fans and the ID booster fans of two or more boiler-absorber trains, absorber module capacity may be shared among multiple boiler units. At Harrison Power Station, three (3) 4,900,000 lb/hour boilers (640 MWe Gross) will be linked through a common plenum. This sharing capability precludes the need to add standby module capacity, thereby saving capital dollars and keeping project critical path schedules, which typically run through absorber procurement and construction, to a minimum. Through damper placement in the ductwork cross connections, unitized boiler-absorber module operation or common plenum operation may be obtained, thus providing both operational flexibility and reliability. Additionally, open plenum operation allows the removal of an absorber unit from service, while keeping its associated boiler on line, thereby precluding 'cold starts' and maintaining overall unit availabilities. As either unitized or common plenum operation is possible with the cross connection, the furnace draft control systems of each boiler must be examined for varying load operation and trip conditions. This paper addresses the means by which to analyze such cross connection operational scenarios while maintaining compliance with furnace flame out safety guidelines, and will discuss the physical design considerations, ramifications and benefits of same, with select emphasis on what is being implemented at the Harrison Power Station

  5. A novel direct-fired porous-medium boiler

    Science.gov (United States)

    Prasartkaew, Boonrit

    2018-01-01

    Nowadays, power and heat generation systems pay an important role in all economic sectors. These systems are mainly based on combustion reaction and operated under the second law of thermodynamics. A conventional boilers, a main component of heat and power generators, have thermal efficiency in the range of 70 to 85%, mainly owing to they have flue gas heat loss. This paper proposes a novel type of boiler, called a Direct-fired Porous-medium Boiler (DPB). Due to being operated without flue gas heat loss, its thermal efficiency cloud be approximately close to 100%. The steam produced from the proposed boiler; however, is not pure water steam. It is the composite gases of steam and combustion-product-gases. This paper aims at presenting the working concept and reporting the experimental results on the performance of the proposed boiler. The experiments of various operating parameters were performed and collected data were used for the performance analysis. The experimental results demonstrated that the proposed boiler can be operated as well as the conceptual design and then it is promising. It can be possibly further developed to be a high efficiency boiler by means of reducing or suppressing the surface heat loss with better insulator and/or refractory lined.

  6. Evaluation of conditions of SNCR in small boilers

    International Nuclear Information System (INIS)

    Kullendorff, A.; Lorentzon, K.

    1996-04-01

    The report describes the first part of a project 'SNCR for small boilers', supported by Vaermeforsk (Thermal Engineering Research Institute), with the purpose of assessing the potential for SNCR in small boilers. Given favourable conditions, the project was to be continued in a second part with the demonstration of a SNCR system in a small boiler (or several boilers). During the base establishment, the temperatures in four locations per boiler, in a couple of horizontal or vertical levels and at 2-3 thermal outputs, were measured. Out of the four locations two showed temperatures mainly within the theoretical temperature window for SNCR. These locations were used during the try-out tests to inject urea and ammonia. The locations and the equipment used during the try-out tests together with existing operation strategies seem to limit the reduction levels to approximately 10-20% at acceptable levels of ammonia slip. The measurements and try-out tests carried out does not provide enough basis for forming any general conclusions concerning SNCR in small boilers. Neither the base establishment nor the try-out tests included any optimisation of the boilers regarding the operation strategy or, for the try-out tests, locations and equipment (drop size, flow shape and direction). Therefore, it is likely to believe that better results can be obtained, given other conditions of operation and using well established SNCR technology, adapted to the circumstances. 2 refs, 27 figs, 5 tabs

  7. Apparatus and method of controlling the thermal performance of an oxygen-fired boiler

    Energy Technology Data Exchange (ETDEWEB)

    Levasseur, Armand A.; Kang, Shin G.; Kenney, James R.; Edberg, Carl D.

    2017-09-05

    Disclosed herein is a method of controlling the operation of an oxy-fired boiler; the method comprising combusting a fuel in a boiler; producing a heat absorption pattern in the boiler; discharging flue gases from the boiler; recycling a portion of the flue gases to the boiler; combining a first oxidant stream with the recycled flue gases to form a combined stream; splitting the combined stream into several fractions; and introducing each fraction of the combined stream to the boiler at different points of entry to the boiler.

  8. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman

    2003-01-20

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to

  9. Evaluation and optimisation of phenomenological multi-step soot model for spray combustion under diesel engine-like operating conditions

    Science.gov (United States)

    Pang, Kar Mun; Jangi, Mehdi; Bai, Xue-Song; Schramm, Jesper

    2015-05-01

    In this work, a two-dimensional computational fluid dynamics study is reported of an n-heptane combustion event and the associated soot formation process in a constant volume combustion chamber. The key interest here is to evaluate the sensitivity of the chemical kinetics and submodels of a semi-empirical soot model in predicting the associated events. Numerical computation is performed using an open-source code and a chemistry coordinate mapping approach is used to expedite the calculation. A library consisting of various phenomenological multi-step soot models is constructed and integrated with the spray combustion solver. Prior to the soot modelling, combustion simulations are carried out. Numerical results show that the ignition delay times and lift-off lengths exhibit good agreement with the experimental measurements across a wide range of operating conditions, apart from those in the cases with ambient temperature lower than 850 K. The variation of the soot precursor production with respect to the change of ambient oxygen levels qualitatively agrees with that of the conceptual models when the skeletal n-heptane mechanism is integrated with a reduced pyrene chemistry. Subsequently, a comprehensive sensitivity analysis is carried out to appraise the existing soot formation and oxidation submodels. It is revealed that the soot formation is captured when the surface growth rate is calculated using a square root function of the soot specific surface area and when a pressure-dependent model constant is considered. An optimised soot model is then proposed based on the knowledge gained through this exercise. With the implementation of optimised model, the simulated soot onset and transport phenomena before reaching quasi-steady state agree reasonably well with the experimental observation. Also, variation of spatial soot distribution and soot mass produced at oxygen molar fractions ranging from 10.0 to 21.0% for both low and high density conditions are reproduced.

  10. Fractal and spectroscopic analysis of soot from internal combustion engines

    Science.gov (United States)

    Swapna, M. S.; Saritha Devi, H. V.; Raj, Vimal; Sankararaman, S.

    2018-03-01

    Today diesel engines are used worldwide for various applications and very importantly in transportation. Hydrocarbons are the most widespread precursors among carbon sources employed in the production of carbon nanotubes (CNTs). The aging of internal combustion engine is an important parameter in deciding the carbon emission and particulate matter due to incomplete combustion of fuel. In the present work, an attempt has been made for the effective utilization of the aged engines for potential applicationapplications in fuel cells and nanoelectronics. To analyze the impact of aging, the particulate matter rich in carbon content areis collected from diesel engines of different ages. The soot with CNTs is purified by the liquid phase oxidation method and analyzed by Field Emission Scanning Electron Microscopy, High-Resolution Transmission Electron Microscopy, Energy Dispersive Spectroscopy, UV-Visible spectroscopy, Raman spectroscopy and Thermogravimetric analysis. The SEM image contains self-similar patterns probing fractal analysis. The fractal dimensions of the samples are determined by the box counting method. We could find a greater amount of single-walled carbon nanotubes (SWCNTs) in the particulate matter emitted by aged diesel engines and thereby giving information about the combustion efficiency of the engine. The SWCNT rich sample finds a wide range of applicationapplications in nanoelectronics and thereby pointing a potential use of these aged engines.

  11. Sulfuric Acid and Soot Particle Formation in Aircraft Exhaust

    Science.gov (United States)

    Pueschel, Rudolf F.; Verma, S.; Ferry, G. V.; Howard, S. D.; Vay, S.; Kinne, S. A.; Baumgardner, D.; Dermott, P.; Kreidenweis, S.; Goodman, J.; hide

    1997-01-01

    A combination of CN counts, Ames wire impactor size analyses and optical particle counter data in aircraft exhaust results in a continuous particle size distribution between 0.01 micrometer and 1 micrometer particle radius sampled in the exhaust of a Boeing 757 research aircraft. The two orders of magnitude size range covered by the measurements correspond to 6-7 orders of magnitude particle concentration. CN counts and small particle wire impactor data determine a nucleation mode, composed of aircraft-emitted sulfuric acid aerosol, that contributes between 62% and 85% to the total aerosol surface area and between 31% and 34% to its volume. Soot aerosol comprises 0.5% of the surface area of the sulfuric acid aerosol. Emission indices are: EIH2SO4 = 0.05 g/kgFUEL and (0.2-0.5) g/kgFUEL (for 75 ppmm and 675 ppmm fuel-S, respectively), 2.5E4sulfur (gas) to H2SO4 (particle) conversion efficiency is between 10% and 25%.

  12. Model-based Control of a Bottom Fired Marine Boiler

    DEFF Research Database (Denmark)

    Solberg, Brian; Karstensen, Claus M. S.; Andersen, Palle

    This paper focuses on applying model based MIMO control to minimize variations in water level for a specific boiler type. A first principles model is put up. The model is linearized and an LQG controller is designed. Furthermore the benefit of using a steam °ow measurement is compared to a strategy...... relying on estimates of the disturbance. Preliminary tests at the boiler system show that the designed controller is able to control the boiler process. Furthermore it can be concluded that relying on estimates of the steam flow in the control strategy does not decrease the controller performance...

  13. Modelling transition states of a small once-through boiler

    Energy Technology Data Exchange (ETDEWEB)

    Talonpoika, T. [Lappeenranta Univ. of Technology (Finland). Dept. of Energy Technology

    1997-12-31

    This article presents a model for the unsteady dynamic behaviour of a once-through counter flow boiler that uses an organic working fluid. The boiler is a compact waste-heat boiler without a furnace and it has a preheater, a vaporiser and a superheater. The relative lengths of the boiler parts vary with the operating conditions since they are all parts of a single tube. The boiler model is presented using a selected example case that uses toluene as the process fluid and flue gas from natural gas combustion as the heat source. The dynamic behaviour of the boiler means transition from the steady initial state towards another steady state that corresponds to the changed process conditions. The solution method chosen is to find such a pressure of the process fluid that the mass of the process fluid in the boiler equals the mass calculated using the mass flows into and out of the boiler during a time step, using the finite difference method. A special method of fast calculation of the thermal properties is used, because most of the calculation time is spent in calculating the fluid properties. The boiler is divided into elements. The values of the thermodynamic properties and mass flows are calculated in the nodes that connect the elements. Dynamic behaviour is limited to the process fluid and tube wall, and the heat source is regarded as to be steady. The elements that connect the preheater to the vaporiser and the vaporiser to the superheater are treated in a special way that takes into account a flexible change from one part to the other. The initial state of the boiler is received from a steady process model that is not a part of the boiler model. The known boundary values that may vary during the dynamic calculation were the inlet temperature and mass flow rates of both the heat source fluid and the process fluid. The dynamic boiler model is analysed for linear and step charges of the entering fluid temperatures and flow rates. The heat source side tests show that

  14. Numerical modelling of a straw-fired grate boiler

    DEFF Research Database (Denmark)

    Kær, Søren Knudsen

    2004-01-01

    The paper presents a computational fluid dynamics (CFD) analysis of a 33 MW straw-fired grate boiler. Combustion on the grate plays akey-role in the analysis of these boilers and in this work a stand-alone code was used to provide inlet conditions for the CFD analysis. Modelpredictions were...... compared with available gas temperature and species concentration measurements showing good agreement. Combustionof biomass in grate-based boilers is often associated with high emission levels and relatively high amounts of unburnt carbon in the fly ash.Based on the CFD analysis, it is suggested that poor...

  15. Model-based Control of a Bottom Fired Marine Boiler

    DEFF Research Database (Denmark)

    Solberg, Brian; Karstensen, Claus M. S.; Andersen, Palle

    2005-01-01

    This paper focuses on applying model based MIMO control to minimize variations in water level for a specific boiler type. A first principles model is put up. The model is linearized and an LQG controller is designed. Furthermore the benefit of using a steam °ow measurement is compared to a strategy...... relying on estimates of the disturbance. Preliminary tests at the boiler system show that the designed controller is able to control the boiler process. Furthermore it can be concluded that relying on estimates of the steam flow in the control strategy does not decrease the controller performance...

  16. Vacuum boilers developed heating surfaces technic and economic efficiency evaluation

    Science.gov (United States)

    Slobodina, E. N.; Mikhailov, A. G.; Semenov, B. A.

    2018-01-01

    The vacuum boilers as manufacturing proto types application analysis was carried out, the possible directions for the heating surfaces development are identified with a view to improving the energy efficiency. Economic characteristics to evaluate the vacuum boilers application efficiency (Net Discounted Income (NDI), Internal Rate of Return (IRR), Profitability Index (PI) and Payback Period) are represented. The given type boilers application technic and economic efficiency criteria were established. NDI changing curves depending on the finning coefficient and operating pressure were obtained as a result of the conducted calculation studies.

  17. Maintenance of immersion ultrasonic testing on the water tube boiler

    International Nuclear Information System (INIS)

    Ishiyama, Toru; Kawasaki, Ichio; Miura, Hirohito

    2014-01-01

    There are 4-boiler in nuclear fuel cycle engineering laboratories (NCL). These boilers have been operated in the long term over 20 years. One of them, the leakage of boiler water was found at one of the generating tubes, and 2 adjoining generating tubes were corroded in Dec, 2011. These generating tubes were investigated by immersion ultrasonic testing (UT) for measure thickness of the tube. As a result, thinner tube was found in a part of a bend and near the water drum. These parts are covered with sulfide deposit, it seems that the generating tubes were corroded by sulfide. (author)

  18. Smooth Surfaces: A review of current and planned smooth surface technologies for fouling resistance in boiler

    Energy Technology Data Exchange (ETDEWEB)

    Corkery, Robert; Baefver, Linda; Davidsson, Kent; Feiler, Adam

    2012-02-15

    Here we have described the basics of boilers, fuels, combustion, flue gas composition and mechanisms of deposition. We have reviewed coating technologies for boiler tubes, including their materials compositions, nano structures and performances. The surface forces in boilers, in particular those relevant to formation of unwanted deposits in boilers have also been reviewed, and some comparative calculations have been included to indicate the procedures needed for further study. Finally practical recommendations on the important considerations in minimizing deposition on boiler surfaces are made

  19. Effects of Biomass Feedstock on the Yield and Reactivity of Soot from Fast Pyrolysis at High Temperatures

    DEFF Research Database (Denmark)

    Trubetskaya, Anna; Jensen, Peter A.; Glarborg, Peter

    microscopy techniques, X-ray diffraction and N2-adsorption. The reactivity of soot was investigated by thermogravimetric analysis. The results showed that the reactivity of soot, generated at 1400°C was higher than that at 1250°C for all biomass types. Wood and wheat straw soot demonstrated differences......This study investigated the effect of feedstock on the yield, nanostructure and reactivity of soot. Woody and herbaceous biomass were pyrolyzed at high heating rates and temperatures of 1250 and 1400°C in a drop tube furnace. The collected solid residues were structurally characterized by electron...

  20. Effects of Lignocellulosic Compounds on the Yield, Nanostructure and Reactivity of Soot from Fast Pyrolysis at High Temperatures

    DEFF Research Database (Denmark)

    Trubetskaya, Anna; Broström, Markus; Kling, Jens

    a possible plant shut down. The reduction of soot formation increases the overall production system efficiency and improves the economic feasibility and reliability of the gasification plant. Soot from biomass pyrolysis contains greater inherent oxygen functionalities than hydrocarbons soot and adsorbs...... primary, secondary and teriary pyrolysis products such as organic acids, aldehydes and phenolics [1]. In this study, therefore, the impacts of lignocellulosic compounds and monolignols (syringol, guaiacol, p-hydroxyphenol) on the yield and characteristics of soot were investigated at 1250°C in a drop tube...

  1. In-situ measurements of the mixing state and optical properties of soot with implications for radiative forcing estimates.

    Science.gov (United States)

    Moffet, Ryan C; Prather, Kimberly A

    2009-07-21

    Our ability to predict how global temperatures will change in the future is currently limited by the large uncertainties associated with aerosols. Soot aerosols represent a major research focus as they influence climate by absorbing incoming solar radiation resulting in a highly uncertain warming effect. The uncertainty stems from the fact that the actual amount soot warms our atmosphere strongly depends on the manner and degree in which it is mixed with other species, a property referred to as mixing state. In global models and inferences from atmospheric heating measurements, soot radiative forcing estimates currently differ by a factor of 6, ranging between 0.2-1.2 W/m(2), making soot second only to CO(2) in terms of global warming potential. This article reports coupled in situ measurements of the size-resolved mixing state, optical properties, and aging timescales for soot particles. Fresh fractal soot particles dominate the measured absorption during peak traffic periods (6-9 AM local time). Immediately after sunrise, soot particles begin to age by developing a coating of secondary species including sulfate, ammonium, organics, nitrate, and water. Based on these direct measurements, the core-shell arrangement results in a maximum absorption enhancement of 1.6x over fresh soot. These atmospheric observations help explain the larger values for soot forcing measured by others and will be used to obtain closure in optical property measurements to reduce one of the largest remaining uncertainties in climate change.

  2. Failure Analysis Of Industrial Boiler Pipe

    International Nuclear Information System (INIS)

    Natsir, Muhammad; Soedardjo, B.; Arhatari, Dewi; Andryansyah; Haryanto, Mudi; Triyadi, Ari

    2000-01-01

    Failure analysis of industrial boiler pipe has been done. The tested pipe material is carbon steel SA 178 Grade A refer to specification data which taken from Fertilizer Company. Steps in analysis were ; collection of background operation and material specification, visual inspection, dye penetrant test, radiography test, chemical composition test, hardness test, metallography test. From the test and analysis result, it is shown that the pipe failure caused by erosion and welding was shown porosity and incomplete penetration. The main cause of failure pipe is erosion due to cavitation, which decreases the pipe thickness. Break in pipe thickness can be done due to decreasing in pipe thickness. To anticipate this problem, the ppe will be replaced with new pipe

  3. Control Properties of Bottom Fired Marine Boilers

    DEFF Research Database (Denmark)

    Solberg, Brian; Andersen, Palle; Karstensen, Claus M. S.

    2007-01-01

    This paper focuses on model analysis of a dynamic model of a bottom fired one-pass smoke tube boiler. Linearized versions of the model are analyzed and show large variations in system gains at steady state as function of load whereas gain variations near the desired bandwidth are small. An analysis...... of the potential benefit from using a multivariable control strategy in favor of the current strategy based on single loop theory is carried out and proves that the interactions in the system are not negligible and a subsequent controller design should take this into account. A design using dynamical decoupling...... showed substantial improvement compared to a decentralized scheme based on sequential loop closing. Similar or better result is expected to be obtainable using a full Multiple input Multiple output scheme. Furthermore closed loop simulations, applying a linear controller to the nonlinear plant model...

  4. Optical characterization of multi-scale morphologically complex heterogeneous media - Application to snow with soot impurities

    Science.gov (United States)

    Dai, Xiaoyu; Haussener, Sophia

    2018-02-01

    A multi-scale methodology for the radiative transfer analysis of heterogeneous media composed of morphologically-complex components on two distinct scales is presented. The methodology incorporates the exact morphology at the various scales and utilizes volume-averaging approaches with the corresponding effective properties to couple the scales. At the continuum level, the volume-averaged coupled radiative transfer equations are solved utilizing (i) effective radiative transport properties obtained by direct Monte Carlo simulations at the pore level, and (ii) averaged bulk material properties obtained at particle level by Lorenz-Mie theory or discrete dipole approximation calculations. This model is applied to a soot-contaminated snow layer, and is experimentally validated with reflectance measurements of such layers. A quantitative and decoupled understanding of the morphological effect on the radiative transport is achieved, and a significant influence of the dual-scale morphology on the macroscopic optical behavior is observed. Our results show that with a small amount of soot particles, of the order of 1ppb in volume fraction, the reduction in reflectance of a snow layer with large ice grains can reach up to 77% (at a wavelength of 0.3 μm). Soot impurities modeled as compact agglomerates yield 2-3% lower reduction of the reflectance in a thick show layer compared to snow with soot impurities modeled as chain-like agglomerates. Soot impurities modeled as equivalent spherical particles underestimate the reflectance reduction by 2-8%. This study implies that the morphology of the heterogeneities in a media significantly affects the macroscopic optical behavior and, specifically for the soot-contaminated snow, indicates the non-negligible role of soot on the absorption behavior of snow layers. It can be equally used in technical applications for the assessment and optimization of optical performance in multi-scale media.

  5. Compositional effects on PAH and soot formation in counterflow diffusion flames of gasoline surrogate fuels

    KAUST Repository

    Park, Sungwoo

    2017-02-05

    Gasoline surrogate fuels are widely used to understand the fundamental combustion properties of complex refinery gasoline fuels. In this study, the compositional effects on polycyclic aromatic hydrocarbons (PAHs) and soot formation were investigated experimentally for gasoline surrogate mixtures comprising n-heptane, iso-octane, and toluene in counterflow diffusion flames. A comprehensive kinetic model for the gasoline surrogate mixtures was developed to accurately predict the fuel oxidation along with the formation of PAHs and soot in flames. This combined model was first tested against ignition delay times and laminar burning velocities data. The proposed model for the formation and growth of PAHs up to coronene (C24H12) was based on previous studies and was tested against existing and present new experimental data. Additionally, in the accompanied soot model, PAHs with sizes larger than (including) pyrene were used for the inception of soot particles, followed by particle coagulations and PAH condensation/chemical reactions on soot surfaces. The major pathways for the formation of PAHs were also identified for the surrogate mixtures. The model accurately captures the synergistic PAH formation characteristics observed experimentally for n-heptane/toluene and iso-octane/toluene binary mixtures. Furthermore, the present experimental and modeling results also elucidated different trends in the formation of larger PAHs and soot between binary n-heptane/iso-octane and ternary n-heptane/iso-octane/toluene mixtures. Propargyl radicals (C3H3) were shown to be important in the formation and growth of PAHs for n-heptane/iso-octane mixtures when the iso-octane concentration increased; however, reactions involving benzyl radicals (C6H5CH2) played a significant role in the formation of PAHs for n-heptane/iso-octane/toluene mixtures. These results indicated that the formation of PAHs and subsequently soot was strongly affected by the composition of gasoline surrogate mixtures.

  6. On transient climate change at the Cretaceous-Paleogene boundary due to atmospheric soot injections

    Science.gov (United States)

    Bardeen, Charles G.; Garcia, Rolando R.; Toon, Owen B.; Conley, Andrew J.

    2017-09-01

    Climate simulations that consider injection into the atmosphere of 15,000 Tg of soot, the amount estimated to be present at the Cretaceous-Paleogene boundary, produce what might have been one of the largest episodes of transient climate change in Earth history. The observed soot is believed to originate from global wildfires ignited after the impact of a 10-km-diameter asteroid on the Yucatán Peninsula 66 million y ago. Following injection into the atmosphere, the soot is heated by sunlight and lofted to great heights, resulting in a worldwide soot aerosol layer that lasts several years. As a result, little or no sunlight reaches the surface for over a year, such that photosynthesis is impossible and continents and oceans cool by as much as 28 °C and 11 °C, respectively. The absorption of light by the soot heats the upper atmosphere by hundreds of degrees. These high temperatures, together with a massive injection of water, which is a source of odd-hydrogen radicals, destroy the stratospheric ozone layer, such that Earth’s surface receives high doses of UV radiation for about a year once the soot clears, five years after the impact. Temperatures remain above freezing in the oceans, coastal areas, and parts of the Tropics, but photosynthesis is severely inhibited for the first 1 y to 2 y, and freezing temperatures persist at middle latitudes for 3 y to 4 y. Refugia from these effects would have been very limited. The transient climate perturbation ends abruptly as the stratosphere cools and becomes supersaturated, causing rapid dehydration that removes all remaining soot via wet deposition.

  7. Exploring Soot Particle Concentration and Emissivity by Transient Thermocouples Measurements in Laminar Partially Premixed Coflow Flames

    Directory of Open Access Journals (Sweden)

    Gianluigi De Falco

    2017-02-01

    Full Text Available Soot formation in combustion represents a complex phenomenon that strongly depends on several factors such as pressure, temperature, fuel chemical composition, and the extent of premixing. The effect of partial premixing on soot formation is of relevance also for real combustion devices and still needs to be fully understood. An improved version of the thermophoretic particle densitometry (TPD method has been used in this work with the aim to obtain both quantitative and qualitative information of soot particles generated in a set of laminar partially-premixed coflow flames characterized by different equivalence ratios. To this aim, the transient thermocouple temperature response has been analyzed to infer particle concentration and emissivity. A variety of thermal emissivity values have been measured for flame-formed carbonaceous particles, ranging from 0.4 to 0.5 for the early nucleated soot particles up to the value of 0.95, representing the typical value commonly attributed to mature soot particles, indicating that the correct determination of the thermal emissivity is necessary to accurately evaluate the particle volume fraction. This is particularly true at the early stage of the soot formation, when particle concentration measurement is indeed particularly challenging as in the central region of the diffusion flames. With increasing premixing, an initial increase of particles is detected both in the maximum radial soot volume fraction region and in the central region of the flame, while the further addition of primary air determines the particle volume fraction drop. Finally, a modeling analysis based on a sectional approach has been performed to corroborate the experimental findings.

  8. Orion Ammonia Boiler System Preflight Test Preparations

    Science.gov (United States)

    Levitt, Julia L.

    2017-01-01

    The Environmental Controls and Life Support Systems (ECLSS) branch at Kennedy Space Center (KSC) is currently undergoing preparations for ground testing of the Orion Multi-Purpose Crew Vehicle (MPCV) to prepare its subsystems for EM-1 (Exploration Mission-1). EM-1, Orions second unmanned flight, is a three-week long lunar mission during which the vehicle will complete a 6-day retrograde lunar orbit before returning to Earth. This paper focuses on the work done during the authors 16-week internship with the Mechanical Engineering Branch of KSCs Engineering Directorate. The authors project involved assisting with the preparations for testing the Orion MPCVs ammonia boiler system. The purpose of the ammonia boiler system is to keep the spacecraft sufficiently cool during the reentry portion of its mission, from service module (SM) separation to post-landing. This system is critical for keeping both the spacecraft (avionics and electronics) and crew alive during reentry, thus a successful test of the system is essential to the success of EM-1. XXXX The author was able to draft a detailed outline of the procedure for the ammonia system functional test. More work will need to be done on the vehicle power-up and power-down portions of the procedure, but the ammonia system testing portion of the procedure is thorough and includes vehicle test configurations, vehicle commands, and GSE. The author was able to compile a substantial list of questions regarding the ammonia system functional test with the help of her mentors. A significant number of these questions were answered in the teleconferences with Lockheed Martin.

  9. Mixing state of regionally transported soot particles and the coating effect on their size and shape at a mountain site in Japan

    Science.gov (United States)

    Adachi, Kouji; Zaizen, Yuji; Kajino, Mizuo; Igarashi, Yasuhito

    2014-05-01

    Soot particles influence the global climate through interactions with sunlight. A coating on soot particles increases their light absorption by increasing their absorption cross section and cloud condensation nuclei activity when mixed with other hygroscopic aerosol components. Therefore, it is important to understand how soot internally mixes with other materials to accurately simulate its effects in climate models. In this study, we used a transmission electron microscope (TEM) with an auto particle analysis system, which enables more particles to be analyzed than a conventional TEM. Using the TEM, soot particle size and shape (shape factor) were determined with and without coating from samples collected at a remote mountain site in Japan. The results indicate that ~10% of aerosol particles between 60 and 350 nm in aerodynamic diameters contain or consist of soot particles and ~75% of soot particles were internally mixed with nonvolatile ammonium sulfate or other materials. In contrast to an assumption that coatings change soot shape, both internally and externally mixed soot particles had similar shape and size distributions. Larger aerosol particles had higher soot mixing ratios, i.e., more than 40% of aerosol particles with diameters >1 µm had soot inclusions, whereas <20% of aerosol particles with diameters <1 µm included soot. Our results suggest that climate models may use the same size distributions and shapes for both internally and externally mixed soot; however, changing the soot mixing ratios in the different aerosol size bins is necessary.

  10. Characterization of Air Plane Soot Surrogates using Raman spectroscopy and laser ablation techniques

    Science.gov (United States)

    Chazallon, Bertrand; Ortega, Ismael Kenneth; Ikhenazene, Raouf; Pirim, Claire; Carpentier, Yvain; Irimiea, Cornelia; Focsa, Cristian; Ouf, François-Xavier

    2016-04-01

    Aviation alters the composition of the atmosphere globally and can thus drive climate change and ozone depletion [1]. Aircraft exhaust plumes contain species (gases and soot particles) produced by the combustion of kerosene with ambient air in the combustion chamber of the engine. Soot particles emitted by air-planes produce persistent contrails in the upper troposphere in ice-supersaturated air masses that contribute to cloudiness and impact the radiative properties of the atmosphere. These aerosol-cloud interactions represent one of the largest sources of uncertainty in global climate models [2]. Though the formation of atmospheric ice particles has been studied for many years [3], there are still numerous opened questions on nucleation properties of soot particles [4], as the ice nucleation experiments showed a large spread in results depending on the nucleation mode chosen and origin of the soot produced. The reasons behind these discrepancies reside in the different physico-chemical properties (composition, structure) of soot particles produced in different conditions, e.g., with respect to fuel or combustion techniques. In this work, we use Raman microscopy (514 and 785 nm excitation wavelengths) and ablation techniques (Secondary Ions Mass Spectrometry, and Laser Desorption Mass Spectrometry) to characterize soot particle surrogates produced from a CAST generator (propane fuel, four different global equivalence ratios). They are produced as analogues of air-plane soot collected at different engine regimes (PowerJet SaM-146 turbofan) simulating a landing and take-off (LTO) cycle (MERMOSE project (http://mermose.onera.fr/)) [6]. The spectral parameters of the first-order Raman bands of these soot samples are analyzed using a de-convolution approach described by Sadezky et al. (2005) [5]. A systematic Raman analysis is carried out to select a number of parameters (laser wavelength, irradiance at sample, exposure time) that will alter the sample and the

  11. Numerical simulation of a biomass fired grate boiler

    DEFF Research Database (Denmark)

    Yin, Chungen; Rosendahl, Lasse; Kær, Søren Knudsen

    2006-01-01

    Computational fluid dynamic (CFD) analysis of the thermal flow in the combustion furnace of a biomass-fired grate boiler provides crucial insight into the boiler's performance. Quite a few factors play important roles in a general CFD analysis, such as grid, models, discretization scheme and so on....... For a grate boiler, the modeling the interaction of the fuel bed and the gas phase above the bed is also essential. Much effort can be found in literature on developing bed models whose results are introduced into CFD simulations of freeboard as inlet conditions. This paper presents a CFD analysis...... of the largest biomass-fired grate boiler in Denmark. The focus of this paper is to study how significantly an accurate bed model can affect overall CFD results, i.e., how necessarily it is to develop an accurate bed model in terms of the reliability of CFD results. The ultimate purpose of the study is to obtain...

  12. Emissions from Power Plant and Industrial Boiler Sector

    Data.gov (United States)

    U.S. Environmental Protection Agency — This asset provides hourly data on SO2, NOx, and CO2 emissions; gross load, steam load, and heat input; from electricity generation units and industrial boilers from...

  13. Convective and radiative heat transfer in MHD radiant boilers

    Science.gov (United States)

    Im, K. H.; Ahluwalia, R. K.

    1981-10-01

    A combined convection-gas radiation, two-zone flow model is formulated for study of the heat transfer characteristics of MHD radiant boilers. The radiative contributions of carbon dioxide, water vapor, potassium atoms, and slag particles are included in the formulation, and are determined by solving the radiation transport equation using the P1 approximation. The scattering and absorption cross sections of slag particles are calculated from Mie theory. The model is used to analyze the scale-up of heat transfer in radiant boilers with refractory thickness, wall emissivity, and boiler size under conditions of a gas composition and slag particle spectrum typical of coal-fired MHD combustion. A design procedure is suggested for sizing radiant boilers so as to achieve the required heat extraction rate and to provide a flow residence time that is adequate for decomposition of NO(x) to acceptable levels.

  14. Cloud droplet activity changes of soot aerosol upon smog chamber ageing

    Science.gov (United States)

    Wittbom, C.; Eriksson, A. C.; Rissler, J.; Carlsson, J. E.; Roldin, P.; Nordin, E. Z.; Nilsson, P. T.; Swietlicki, E.; Pagels, J. H.; Svenningsson, B.

    2014-09-01

    Particles containing soot, or black carbon, are generally considered to contribute to global warming. However, large uncertainties remain in the net climate forcing resulting from anthropogenic emissions of black carbon (BC), to a large extent due to the fact that BC is co-emitted with gases and primary particles, both organic and inorganic, and subject to atmospheric ageing processes. In this study, diesel exhaust particles and particles from a flame soot generator spiked with light aromatic secondary organic aerosol (SOA) precursors were processed by UV radiation in a 6 m3 Teflon chamber in the presence of NOx. The time-dependent changes of the soot nanoparticle properties were characterised using a Cloud Condensation Nuclei Counter, an Aerosol Particle Mass Analyzer and a Soot Particle Aerosol Mass Spectrometer. The results show that freshly emitted soot particles do not activate into cloud droplets at supersaturations ≤2%, i.e. the BC core coated with primary organic aerosol (POA) from the exhaust is limited in hygroscopicity. Before the onset of UV radiation it is unlikely that any substantial SOA formation is taking place. An immediate change in cloud-activation properties occurs at the onset of UV exposure. This change in hygroscopicity is likely attributed to SOA formed from intermediate volatility organic compounds (IVOCs) in the diesel engine exhaust. The change of cloud condensation nuclei (CCN) properties at the onset of UV radiation implies that the lifetime of soot particles in the atmosphere is affected by the access to sunlight, which differs between latitudes. The ageing of soot particles progressively enhances their ability to act as cloud condensation nuclei, due to changes in: (I) organic fraction of the particle, (II) chemical properties of this fraction (e.g. primary or secondary organic aerosol), (III) particle size, and (IV) particle morphology. Applying κ-Köhler theory, using a κSOA value of 0.13 (derived from independent input

  15. Particulate matter emission modelling based on soot and SOF from direct injection diesel engines

    International Nuclear Information System (INIS)

    Tan, P.Q.; Hu, Z.Y.; Deng, K.Y.; Lu, J.X.; Lou, D.M.; Wan, G.

    2007-01-01

    Particulate matter (PM) emission is one of the major pollutants from diesel engines, and it is harmful for human health and influences the atmospheric visibility. In investigations for reducing PM emission, a simulation model for PM emission is a useful tool. In this paper, a phenomenological, composition based PM model of direct injection (DI) diesel engines has been proposed and formulated to simulate PM emission. The PM emission model is based on a quasi-dimensional multi-zone combustion model using the formation mechanisms of the two main compositions of PM: soot and soluble organic fraction (SOF). First, the quasi-dimensional multi-zone combustion model is given. Then, two models for soot and SOF emissions are established, respectively, and after that, the two models are integrated into a single PM emission model. The soot emission model is given by the difference between a primary formation model and an oxidation model of soot. The soot primary formation model is the Hiroyasu soot formation model, and the Nagle and Strickland-Constable model is adopted for soot oxidation. The SOF emission model is based on an unburned hydrocarbons (HC) emission model, and the HC emission model is given by the difference between a HC primary formation model and a HC oxidation model. The HC primary formation model considers fuel injected and mixed beyond the lean combustion limit during ignition delay and fuel effusing from the nozzle sac volume at low pressure and low velocity. In order to validate the PM emission model, experiments were performed on a six cylinder, turbocharged and intercooled DI diesel engine. The simulation results show good agreement with the experimental data, which indicates the validity of the PM emission model. The calculation results show that the distinctions between PM and soot formation rates are mainly in the early combustion stage. The SOF formation has an important influence on the PM formation at lower loads, and soot formation dominates the

  16. Structural effects on the oxidation of soot particles by O2: Experimental and theoretical study

    KAUST Repository

    Raj, Abhijeet

    2013-09-01

    Soot particles are composed of polycyclic aromatic hydrocarbons (PAHs), which have either planar or curved structures. The oxidation behaviors of soot particles differ depending on their structures, arrangement of PAHs, and the type of surface functional groups. The oxidation rate of curved PAHs in soot is thought to be higher than that of planar ones. To understand the role that PAH structure plays in soot reactivity towards O2, experimental studies are conducted on two types of commercially produced soot, Printex-U and Fullerene soot, using high resolution transmission electron microscopy, electron energy loss spectroscopy, thermo-gravimetric analysis and elemental analysis. The relative concentrations of active sites, oxygenated functional groups, aliphatics and aromatics present in soots are evaluated. The activation energies for soot oxidation at different conversion levels are determined. The average activation energies of the two soots are found to differ by 26kJ/mol. To understand the reason for this difference, quantum calculations using density functional (B3LYP) and Hartree-Fock theories are conducted to study the reaction pathways of the oxidation by O2 of planar and curved PAHs using 4-pyrenyl and 1-corannulenyl as their model molecules, respectively. The energetically preferred channels for curved PAH oxidation differ from the planar one. The addition of O2 on a radical site of a six-membered ring to form a peroxyl radical is found to be barrierless for both the model PAHs. For peroxyl decomposition, three pathways are suggested, each of which involve the activation energies of 108, 170 and 121kJ/mol to form stable molecules in the case of planar PAH, and 94, 155 and 125kJ/mol in the case of curved PAH. During the oxidation of a five-membered ring, to form stable molecules, the activation energies of 90kJ/mol for the curved PAH and 169kJ/mol for the planar PAH relative to the energy of the peroxyl radical are required. The low activation barriers of

  17. Soot and Spectral Radiation Modeling for a High-Pressure Turbulent Spray Flame

    Energy Technology Data Exchange (ETDEWEB)

    Ferreryo-Fernandez, Sebastian [Pennsylvania State Univ., University Park, PA (United States); Paul, Chandan [Pennsylvania State Univ., University Park, PA (United States); Sircar, Arpan [Pennsylvania State Univ., University Park, PA (United States); Imren, Abdurrahman [Pennsylvania State Univ., University Park, PA (United States); Haworth, Daniel C [Pennsylvania State Univ., University Park, PA (United States); Roy, Somesh P [Marquette University (United States); Modest, Michael F [University of California Merced (United States)

    2017-04-26

    Simulations are performed of a transient high-pressure turbulent n-dodecane spray flame under engine-relevant conditions. An unsteady RANS formulation is used, with detailed chemistry, a semi-empirical two-equation soot model, and a particle-based transported composition probability density function (PDF) method to account for unresolved turbulent fluctuations in composition and temperature. Results from the PDF model are compared with those from a locally well-stirred reactor (WSR) model to quantify the effects of turbulence-chemistry-soot interactions. Computed liquid and vapor penetration versus time, ignition delay, and flame lift-off height are in good agreement with experiment, and relatively small differences are seen between the WSR and PDF models for these global quantities. Computed soot levels and spatial soot distributions from the WSR and PDF models show large differences, with PDF results being in better agreement with experimental measurements. An uncoupled photon Monte Carlo method with line-by-line spectral resolution is used to compute the spectral intensity distribution of the radiation leaving the flame. This provides new insight into the relative importance of molecular gas radiation versus soot radiation, and the importance of turbulent fluctuations on radiative heat transfer.

  18. Simulation of an electrostatic soot-filter with continuous electrochemical conversion during the stages of development

    International Nuclear Information System (INIS)

    Muri, M.

    1996-04-01

    The dissertation describes the simulation of an electrostatic Diesel-Soot-Converter during its stages of development. This simulation is not only necessary for the interpretation of the experimental results, it also shows results for assumptions that cannot be received experimentally. The Diesel-Soot-Converter consists of a charging electrode, which charges the particles by a high-voltage and a ceramic monolith, where the particles are precipitated in the open channels because of an electric field created also by a high-voltage. Afterwards the particles are burned by a plasma. The filter-function of the Diesel-Soot-Converter was formulated and the efficiency for a vehicle was calculated. In the first part of the calculation the mass flow of a BMW 318tds and a BMW 325tds was determined for an US-FTP75-testcycle and for fuel load. In the second part the efficiency of different Diesel-Soot-Converter-types was calculated for the US-FTP75-testcycle and for full load. The use of the program with other testcycles is possible. The results of the calculations show the best configuration of the Diesel-Soot-Converter for the corresponding vehicle. Therefore with the help of this program time and money for the production of the ceramic can be saved. (author)

  19. Determination of polycyclic aromatic hydrocarbons in kerosene and bio-kerosene soot.

    Science.gov (United States)

    Andrade-Eiroa, Auréa; Leroy, Valérie; Dagaut, Philippe; Bedjanian, Yuri

    2010-03-01

    Here we report a new, efficient and reliable analytical methodology for sensitive and selective quantification of Polycyclic Aromatic Hydrocarbons (PAHs) in soot samples. The methodology developed is based on ultrasonic extraction of the soot-bound PAHs into small volumes of acetonitrile, purification of the extracts through C(18) Solid Phase Extraction (SPE) cartridges and analysis by Reverse Phase Liquid Chromatography (RPLC) with UV and fluorimetric detection. For the first time, we report the convenience of adapting the SPE procedure to the nature of the soot samples. As a matter of fact, extracts containing high percentage of unpolar material are recommended to be cleaned with acetone, whereas extracts poor in unpolar compounds can be efficiently cleaned with methanol. The method was satisfactorily applied to kerosene and bio-kerosene soot from atmospheric open diffusion flames (pool fires) and premixed flames achieving Quantification and Detection limits in the range ng mg(-1) soot and recoveries about 90% for most of the PAHs studied. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  20. Experimental study on burning behaviors of liquid fuels with different sooting levels at high altitude

    Directory of Open Access Journals (Sweden)

    Liu Jiahao

    2017-01-01

    Full Text Available To validate the feasibility of classical fire scaling laws under low pressure, three typical liquid fuels with different sooting levels, i. e. ethanol, n-heptane and jet-A, were employed in this paper to perform a sequence of pool fires in a high altitude city, Lhasa, Tibet, China (3650 m, 64.3 kPa. Mass loss, axial temperature profile and radiative heat flux were recorded in each test. From the assessment of experimental data, it can be concluded that the dimensionless burning intensity m”μ /D can be correlated against the Grashof number to different powers for all the three fuels, and the exponent increases with the sooting level of fuels. A correlated relationship expressed as ΔT ~ [z(P/Q2/5 ]η can be applied to analyze the axial temperature rises, partitioning flame region, intermittent region and plume region with the modified demarcations, i. e. 0.42 and 1.06. In addition, the averaged flame temperature grows higher with declining sooting level of fuels, while the radiative heat fluxes exhibit the opposite results. Moreover, the measured radiative heat fluxes for different fuels are proportional to 5 m f L T , and the soot volume fraction apparently increases with the sooting level of the fuels under low pressure condition.

  1. A study of radiative properties of fractal soot aggregates using the superposition T-matrix method

    International Nuclear Information System (INIS)

    Li Liu; Mishchenko, Michael I.; Patrick Arnott, W.

    2008-01-01

    We employ the numerically exact superposition T-matrix method to perform extensive computations of scattering and absorption properties of soot aggregates with varying state of compactness and size. The fractal dimension, D f , is used to quantify the geometrical mass dispersion of the clusters. The optical properties of soot aggregates for a given fractal dimension are complex functions of the refractive index of the material m, the number of monomers N S , and the monomer radius a. It is shown that for smaller values of a, the absorption cross section tends to be relatively constant when D f f >2. However, a systematic reduction in light absorption with D f is observed for clusters with sufficiently large N S , m, and a. The scattering cross section and single-scattering albedo increase monotonically as fractals evolve from chain-like to more densely packed morphologies, which is a strong manifestation of the increasing importance of scattering interaction among spherules. Overall, the results for soot fractals differ profoundly from those calculated for the respective volume-equivalent soot spheres as well as for the respective external mixtures of soot monomers under the assumption that there are no electromagnetic interactions between the monomers. The climate-research implications of our results are discussed

  2. Dependence of soot optical properties on particle morphology: measurements and model comparisons.

    Science.gov (United States)

    Radney, James G; You, Rian; Ma, Xiaofei; Conny, Joseph M; Zachariah, Michael R; Hodges, Joseph T; Zangmeister, Christopher D

    2014-03-18

    We report the first mass-specific absorption and extinction cross sections for size- and mass-selected laboratory-generated soot aerosol. Measurement biases associated with aerosols possessing multiple charges were eliminated using mass selection to isolate singly charged particles for a specified electrical mobility diameter. Aerosol absorption and extinction coefficients were measured using photoacoustic and cavity ring-down spectroscopy techniques, respectively, for lacey and compacted soot morphologies. The measurements show that the mass-specific absorption cross sections are proportional to particle mass and independent of morphology, with values between 5.7 and 6 m(2) g(-1). Mass-specific extinction cross sections were morphology dependent and ranged between 12 and 16 m(2) g(-1) for the lacey and compact morphologies, respectively. The resulting single-scattering albedos ranged from 0.5 to 0.6. Results are also compared to theoretical calculations of light absorption and scattering from simulated particle agglomerates. The observed absorption is relatively well modeled, with minimum differences between the calculated and measured mass absorption cross sections ranging from ∼ 5% (lacey soot) to 14% (compact soot). The model, however, was unable to satisfactorily reproduce the measured extinction, underestimating the single-scattering albedo for both particle morphologies. These discrepancies between calculations and measurements underscore the need for validation and refinement of existing models of light scattering and absorption by soot agglomerates.

  3. AUTOMATIC CONTROL SYSTEM OF THE DRUM BOILER SUPERHEATED STEAM TEMPERATURE.

    Directory of Open Access Journals (Sweden)

    Juravliov A.A.

    2006-04-01

    Full Text Available The control system of the temperature of the superheated steam of the drum boiler is examined. Main features of the system are the PI-controller in the external control loop and introduction of the functional component of the error signal of the external control loop with the negative feedback of the error signal between the prescribed value of steam flowrate and the signal of the steam flowrate in the exit of the boiler in the internal control loop.

  4. [Emission characteristics of fine particles from grate firing boilers].

    Science.gov (United States)

    Wang, Shu-Xiao; Zhao, Xiu-Juan; Li, Xing-Hua; Wei, Wei; Hao, Ji-Ming

    2009-04-15

    Grate firing boilers are the main type of Chinese industrial boilers, which accounts for 85% of the industrial boilers and is one of the most important emission sources of primary air pollutants in China. In this study, five boilers in three cities were selected and tested to measure the emission characteristics of PM2.5, and gaseous pollutants were applied by a compact dilution sampling system, which was developed for this field study. Results showed that particles mass size distributions for the five industrial boilers presented single peak or double peak, former peaks near 0.14 microm and the later peaks after 1.0 microm; the cyclone dust remover and wet scrubber dust remover had effective removal efficiencies not only to PM2.5, but also to PM1.0; and under the condition of same control techniques, grate firing boiler with high capacity has less PM2.5 emission than the boiler with low capacity. In the PM2.5 collected from flue gases, SO4(2-) was the most abundant ion, accounted for 20%-40% of the PM2.5; and C was the most abundant element (7.5%-31.8%), followed by S (8.4%-18.7%). Carbon balance method was applied to calculate the emission factors of these pollutants. The emission factors of PM2.5, NO, and SO2 were in the range of 0.046-0.486 g x kg(-1), 1.63-2.47 g x kg(-1), 1.35-9.95 g x kg(-1) respectively. The results are useful for the emission inventory development of industrial boilers and the source analysis of PM2.5 in atmospheric environment.

  5. CFD Studies on Multi Lead Rifled [MLR] Boiler Tubes

    OpenAIRE

    Dr T C Mohankumar

    2013-01-01

    This paper reports the merits of multi lead rifled [MLR] tubes in vertical water tube boiler using CFD tool. Heat transfer enhancement of MLR tubes was mainly taken in to consideration. Performance of multi lead rifled tube was studied by varying its influencing geometrical parameter like number of rifling, height of rifling, length of pitch of rifling for a particular length. The heat transfer analysis was done at operating conditions of an actual coal fired water tube boiler situated at Apo...

  6. Installations of SNCR on bark-fired boilers

    International Nuclear Information System (INIS)

    Hjalmarsson, A.K.; Hedin, K.; Andersson, Lars

    1997-01-01

    Experience has been collected from the twelve bark-fired boilers in Sweden with selective non catalytic reduction (SNCR) installations to reduce emissions of nitrogen oxides. Most of the boilers have slope grates, but there are also two boilers with cyclone ovens and two fluidized bed boilers. In addition to oil there are also possibilities to burn other fuel types in most boilers, such as sludge from different parts of the pulp and paper mills, saw dust and wood chips. The SNCR installations seems in general to be of simple design. In most installations the injection nozzles are located in existing holes in the boiler walls. The availability is reported to be good from several of the SNCR installations. There has been tube leakage in several boilers. The urea system has resulted in corrosion and in clogging of one oil burner. This incident has resulted in a decision not to use SNCR system with the present design of the system. The fuel has also caused operational problems with the SNCR system in several of the installations due to variations in the moisture content and often high moisture content in bark and sludge, causing temperature variations. The availability is presented to be high for the SNCR system at several of the plants, in two of them about 90 %. The results in NO x reduction vary between the installations depending on boiler, fuel and operation. The emissions are between 45 and 100 mg NO 2 /MJ fuel input and the NO x reduction rates are in most installations between 30 and 40 %, the lowest 20 and the highest 70 %. 13 figs, 3 tabs

  7. Brief introduction of GEF efficient industrial boiler project in China

    Energy Technology Data Exchange (ETDEWEB)

    Meijian, T.

    1996-12-31

    The present situation of installed industrial boilers, their efficiency and environmental impact are assessed. And the factors contribute to the low efficiency and serious pollution are summarized. Based on WB-assisted GEF project, {open_quotes}Efficient Industrial Boiler Project{close_quotes} aimed at CO{sub 2} mitigation in China, a series of effective measures to bring the GHG emission under control are addressed, in technology, system performance, and operation management aspects.

  8. Investigation of Turbulators for Fire Tube Boilers Using Exergy Analysis

    OpenAIRE

    AYHAN, Betül

    2001-01-01

    In this paper, an experimental study of five different types of ``turbulator" inserts for fire tube boilers is presented. The experimental setup was constructed in the Department of Mechanical Engineering Laboratory of Karadeniz Technical University. It was tested to evaluate the boiler efficiency according to TS 4040 standard, and to evaluate the second law efficiency of thermodynamics for the cases with and without inserts under the same operating conditions. Four new typ...

  9. Sources and burial fluxes of soot black carbon in sediments on the Mackenzie, Chukchi, and Bering Shelves

    Science.gov (United States)

    Yang, Weifeng; Guo, Laodong

    2018-03-01

    Black carbon (BC) has been recognized as a climate forcing and a major component in the global carbon budget. However, studies on BC in the Arctic Ocean remain scarce. We report here variations in the abundance, sources and burial fluxes of sedimentary soot black carbon (soot-BC) in the western Arctic Ocean. The soot-BC contents averaged 1.6 ± 0.3, 0.46 ± 0.04 and 0.56 ± 0.10 mg-C g-1 on the Mackenzie, Chukchi and Bering Shelves, respectively, accounting for 16.6%, 10.2% and 10.4% of the total organic carbon in surface sediment. Temporally, contents of soot-BC remained fairly stable before 1910, but increased rapidly after the 1970s on the Mackenzie Shelf, indicating enhanced source input related to warming. Comparable δ13C signatures of soot-BC (- 24.95‰ to - 24.57‰) to C3 plants pointed to a major biomass source of soot-BC to the Beaufort Sea. Soot-BC showed similar temporal patterns with large fluctuations in the Chukchi/Bering shelf regions, implying the same source terms for soot-BC in these areas. Two events with elevated soot-BC corresponded to a simultaneous increase in biomass combustion and fossil fuel (coal and oil) consumption in Asia. The similar temporal variability in sedimentary soot-BC between the Arctic shelves and Asian lakes and the comparable δ13C values manifested that anthropogenic emission from East Asia was an important source of soot-BC in the western Arctic and subarctic regions. The burial fluxes of soot-BC, estimated from both 137Cs- and 210Pb-derived sedimentation rates, were 2.43 ± 0.42 g-C m-2 yr-1 on the Mackenzie Shelf, representing an efficient soot-BC sink. Soot-BC showed an increase in buried fluxes from 0.56 ± 0.02 g-C m-2 yr-1 during 1963-1986 to 0.88 ± 0.05 g-C m-2 yr-1 after 1986 on the Chukchi Shelf, and from 1.00 ± 0.18 g-C m-2 yr-1 to 2.58 ± 1.70 g-C m-2 yr-1 on the Bering Shelf, which were consistent with recent anthropogenically enhanced BC input observed especially in Asia. Overall, the three Arctic

  10. Effects of diluents on soot surface temperature and volume fraction in diluted ethylene diffusion flames at pressure

    KAUST Repository

    Kailasanathan, Ranjith Kumar Abhinavam

    2014-05-20

    Soot surface temperature and volume fraction are measured in ethylene/air coflowing laminar diffusion flames at high pressures, diluted with one of four diluents (argon, helium, nitrogen, and carbon dioxide) using a two-color technique. Both temperature and soot measurements presented are line-of-sight averages. The results aid in understanding the kinetic and thermodynamic behavior of the soot formation and oxidation chemistry with changes in diluents, ultimately leading to possible methods of reducing soot emission from practical combustion hardware. The diluted fuel and coflow exit velocities (top-hat profiles) were matched at all pressures to minimize shear effects. In addition to the velocity-matched flow rates, the mass fluxes were held constant for all pressures. Addition of a diluent has a pronounced effect on both the soot surface temperature and volume fraction, with the helium diluted flame yielding the maximum and carbon dioxide diluted flame yielding minimum soot surface temperature and volume fraction. At low pressures, peak soot volume fraction exists at the tip of the flame, and with an increase in pressure, the location shifts lower to the wings of the flame. Due to the very high diffusivity of helium, significantly higher temperature and volume fraction are measured and explained. Carbon dioxide has the most dramatic soot suppression effect. By comparing the soot yield with previously measured soot precursor concentrations in the same flame, it is clear that the lower soot yield is a result of enhanced oxidation rates rather than a reduction in precursor formation. Copyright © 2014 Taylor & Francis Group, LLC.

  11. Feasibility of recovery boiler in paper and pulp industry

    International Nuclear Information System (INIS)

    Rashid, H.

    2010-01-01

    in this paper feasibility of recovery boiler in terms of economics and environmental impacts in studied. Recovery boilers are employed in the pulp and paper industry where the cooking agent is recovered by burning black liquor. Cooking agent is exhausted due to the absorption of lignin (a burnable component) in cooking agent in the process of straw cooking. The process of recovery boiler is to remove lignin by combustion from black liquor, and heat is produced during the combustion of lignin which is used to produce steam. Recovery boiler is economical as it is recovering valuable chemicals and steam is produced as a byproduct. Steam from recovery boiler is also used for concentrating weak black liquor to concentrated black liquor recovering 50% of the utility water being used at the plant. The regenerated water in the form of foul condensate is reused in the process. The recovery of hazardous chemicals also reduces load of environmental pollution. Which otherwise can pollute the water reservoirs, and regeneration of water makes it environmentally friendly plant. Construction and challenges in operation of recovery boiler such as smelt-water explosion are also discussed in this paper. (author)

  12. Failure analysis of boiler tubes in lakhra coal power plant

    International Nuclear Information System (INIS)

    Shah, A.; Baluch, M.M.; Ali, A.

    2010-01-01

    Present work deals with the failure analysis of a boiler tube in Lakhra fluidized bed combustion power station. Initially, visual inspection technique was adopted to analyse the fractured surface. Detailed microstructural investigations of the busted boiler tube were carried out using light optical microscope and scanning electron microscope. The hardness tests were also performed. A 50 percent decrease in hardness of intact portion of the tube material and from area adjacent to failure was measured, which was found to be in good agreement with the wall thicknesses measured of the busted boiler tube i.e. 4 mm and 2 mm from unaffected portion and ruptured area respectively. It was concluded that the major cause of failure of boiler tube is erosion of material which occurs due the coal particles strike at the surface of the tube material. Since the temperature of boiler is not maintained uniformly. The variations in boiler temperature can also affect the material and could be another reason for the failure of the tube. (author)

  13. ANALISIS KEGAGALAN SOOTBLOWER TERHADAP PERPINDAHAN PANAS DI PIPA BOILER

    Directory of Open Access Journals (Sweden)

    Nurul Chandra Purnama

    2017-11-01

    Full Text Available Kementerian Energi dan Sumber Daya Mineral (ESDM menyebut konsumsi listrik nasional saat ini masih terbilang mini, yaitu seperempat dari indikator negara maju di dunia. Dengan angka 956 per Kilowatt-hour (kWh per kapita, konsumsi listrik Indonesia baru mencapai 23,9 persen dari konsumsi listrik negara maju sebanyak 4 ribu kWh per kapita. Salah satu komponen utama pada sistem pembangkit adalah boiler. Uap hasil produksi Boiler ini digunakan untuk memutar turbine yang akan menggerakkan generator guna menghasilkan listrik. Sootblower merupakan peralatan penunjang pada boiler yang berfungsi untuk membersihkan jelaga. Oleh karena itu peranan sootblower sangat penting dalam menjaga effisiensi boiler. Tujuan dari dilakukan analisis ini adalah mampu mengidentifikasi penurunan perpindahan panas yang terjadi pada pipa boiler, mengidentifikasi faktor penyebab kegagalan pada Sootblower, mengurangi energi yang terbuang akibat pengoperasian Sootblower. Metode penelitian untuk melakukan pelaksanaan analisis sootblower ini terdiri atas berbagai bagian, antara lain: studi literatur, proses pengumpulan data, kemudian data diolah dan dilakukan analisis guna mengetahui penyebab kegagalan pada sootblower. Hasil dari analisis kegagalan pada sootblower ini didapatkan bahwa sootblower gagal beroperasi karena ada masalah pada lance tube yang sering bengkok sehingga mempengaruhi proses perpindahan panas di pipa boiler, oleh sebab itu di rekomendasikan untuk penggantian material lance tube dari carbon steel A105 dengan defleksi 1,1 m menjadi chrome moly (AISI 4130 dengan defleksi 1,05 cm  dan dilakukan perawatan sootblower lebih baik dan rutin lagi.

  14. Hybrid Intelligent Warning System for Boiler tube Leak Trips

    Directory of Open Access Journals (Sweden)

    Singh Deshvin

    2017-01-01

    Full Text Available Repeated boiler tube leak trips in coal fired power plants can increase operating cost significantly. An early detection and diagnosis of boiler trips is essential for continuous safe operations in the plant. In this study two artificial intelligent monitoring systems specialized in boiler tube leak trips have been proposed. The first intelligent warning system (IWS-1 represents the use of pure artificial neural network system whereas the second intelligent warning system (IWS-2 represents merging of genetic algorithms and artificial neural networks as a hybrid intelligent system. The Extreme Learning Machine (ELM methodology was also adopted in IWS-1 and compared with traditional training algorithms. Genetic algorithm (GA was adopted in IWS-2 to optimize the ANN topology and the boiler parameters. An integrated data preparation framework was established for 3 real cases of boiler tube leak trip based on a thermal power plant in Malaysia. Both the IWSs were developed using MATLAB coding for training and validation. The hybrid IWS-2 performed better than IWS-1.The developed system was validated to be able to predict trips before the plant monitoring system. The proposed artificial intelligent system could be adopted as a reliable monitoring system of the thermal power plant boilers.

  15. Establishing an Energy Efficiency Recommendation for Commercial Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Ware, Michelle, J.

    2000-08-01

    To assist the federal government in meeting its energy reduction goals, President Clinton’s Executive Order 12902 established the Procurement Challenge, which directed all federal agencies to purchase equipment within the top 25~ percentile of efficiency. Under the direction of DOE’s Federal Energy Management Program (FEMP), the Procurement Challenge’s goal is to create efficiency recommendations for all energy-using products (e.g. commercial boilers, chillers, motors) that could substantially impact the government’s energy reduction goals. When establishing efficiency recommendations, FEMP looks at standardized performance ratings for products sold in the U.S. marketplace. Currently, the commercial boiler industry uses combustion efficiency and, sometimes, thermal efficiency as metrics when specifying boiler performance. For many years, the industry has used both metrics interchangeably, causing confusion in the market place about boiler performance. This paper discusses the method used to establish FEMP’s efficiency recommendation for commercial boilers in lieu of the various, and somewhat confusing, efficiency ratings currently available. The paper also discusses potential energy cost savings for federal agencies that improve the efficiency of boilers specified and purchased.

  16. Soot formation of lignin derived fuels in a laminar co-flow diffusion flame

    Energy Technology Data Exchange (ETDEWEB)

    Bertrand, P.A.M.

    2009-07-15

    Due to limited fossil fuels reserves and increasing CO2 and soot concentration in the atmosphere, other cleaner fuels are needed. Use of biomass waste for the production of second generation bio-fuels might lead to a reduction of CO2 emissions. Second generation bio-fuels from biomass waste do not compete with food stock markets. Although limited available per unit time, biomass waste will be produced for ever. Therefore this resource is sustainable. Research on sooting tendency of different types of fuels is needed to find low sooting fuels which decrease air pollution, thereby killing two birds with one stone. Current research investigated sooting tendencies of possible biofuels from lignin. Lignin is a biopolymer which accounts for 15-30 wt.% of woody biomass. Besides lignin, woody biomass consists of mainly cellulose and hemicellulose. Lignin is responsible for mechanical support of the plant, water conduction and protection against biodegradation. A method was searched to assign a value to a fuel which corresponds to the sooting tendency of that fuel. The method should be validated with Threshold Sooting Index (TSI) and Yield Sooting Index (YSI). The former is an aviation fuel testing method based on smoke point height while the latter is a recently developed method which measures soot concentrations using LII, both using laminar diffusion flames. In the current investigation sooting tendency was measured using line-of-sight attenuation in combination with inverse Abel transformation to determine the spatially resolved soot volume fraction. Different concentrations of test fuel (acetone, ethanol, cyclohexene, cyclohexanone, methane and toluene) mixed with base fuel (33,3 wt.% toluene and 66,7 wt.% n-heptane) were investigated. To enable rapid fuel changing a new fuel accumulator system was designed. In this system a syringe with a small amount of test fuel can easily be placed. Therefore no cleaning of the fuel accumulator is required since the syringes are

  17. Biomass Gasification Behavior in an Entrained Flow Reactor: Gas Product Distribution and Soot Formation

    DEFF Research Database (Denmark)

    Qin, Ke; Jensen, Peter Arendt; Lin, Weigang

    2012-01-01

    Biomass gasification and pyrolysis were studied in a laboratory-scale atmospheric pressure entrained flow reactor. Effects of operating parameters and biomass types on the syngas composition were investigated. In general, the carbon conversion during biomass gasification was higher than 90......% at the optimal conditions of 1400 °C with steam addition. The biomass carbon that was not converted to gas in the gasification process only appeared as soot particles in the syngas in all of the experiments, except for the two experiments performed at 1000 °C, where a very small amount of char was also left....... In comparison to pyrolysis, lower yields of soot, H2, and CO were produced during gasification. The yield of soot could be reduced by a longer residence time, larger feeder air flow, lower oxygen concentration, higher excess air ratio, higher steam/carbon ratio, and higher reactor temperature. Changes...

  18. Soot and Spectral Radiation Modeling in ECN Spray A and in Engines

    Energy Technology Data Exchange (ETDEWEB)

    Haworth, Daniel C [Pennsylvania State Univ., University Park, PA (United States); Ferreyro-Fernandez, Sebastian [Pennsylvania State Univ., University Park, PA (United States); Paul, Chandan [Pennsylvania State Univ., University Park, PA (United States); Sircar, Arpan [Pennsylvania State Univ., University Park, PA (United States); Imren, Abdurrahman [Pennsylvania State Univ., University Park, PA (United States); Roy, Somesh P [Marquette University (United States); Modest, Michael F [University of California Merced (United States); Ge, Wenjun [University of California Merced (United States)

    2017-04-03

    The amount of soot formed in a turbulent combustion system is determined by a complex system of coupled nonlinear chemical and physical processes. Different physical subprocesses can dominate, depending on the hydrodynamic and thermochemical environments. Similarly, the relative importance of reabsorption, spectral radiation properties, and molecular gas radiation versus soot radiation varies with thermochemical conditions, and in ways that are difficult to predict for the highly nonhomogeneous in-cylinder mixtures in engines. Here it is shown that transport and mixing play relatively more important roles as rate-determining processes in soot formation at engine-relevant conditions. It is also shown that molecular gas radiation and spectral radiation properties are important for engine-relevant conditions.

  19. A review of the literature on soot production during in-situ burning of oil

    International Nuclear Information System (INIS)

    Fraser, J.; Buist, I.

    1997-01-01

    Available literature on soot production during in-situ burning of oil was reviewed to determine the range of smoke yields generated by in-situ burning of petroleum oils in water, and to determine the effects of the size of fire and the type of oil burned. For crude oil, data sets statistical analysis showed that, with a fairly high degree of confidence, smoke yield increases with fire diameter. Based on a limited number of available data sets for identifiable oil types, it appears that most oils (Arabian crude the only exception) show roughly the same correlation of smoke yield with fire diameter. Pool fires from aromatic hydrocarbons such as toluene appear to produce more soot than similar fires with crude oil. Fires of lower molecular weight non-aromatics produce an order of magnitude less soot than crude oil fires. Predictive equations with correlation coefficients are provided for specific crude oils. 50 refs., 5 tabs., 13 figs

  20. DBSSP - A computer program for simulation of controlled circulation boiler and natural circulation boiler start up behavior

    International Nuclear Information System (INIS)

    Li Bin; Chen Tingkuan; Yang Dong

    2005-01-01

    In this paper, a computer program, Drum Boiler Start-up Simulation Program (DBSSP), is developed for simulating the start up behavior of controlled circulation and natural circulation boilers. The mathematical model developed here is based on the first principles of mass, energy and momentum conservations. In the boiler model, heat transfer in the waterwall, the superheater, the reheater and the economizer is simulated by the distributing parameter method, while heat transfer in the drum and the downcomer is simulated by lumped parameter analysis. The program can provide detailed flow and thermodynamic characteristics of the boiler components. The development of this program is based only on design data, so it can be used for any subcritical, controlled or natural circulation boiler. The simulation results were compared with experimental measurements, and good agreements between them were found. This program is expected to be useful for predicting the characteristics and the performance of controlled circulation and natural circulation boilers during the start up process. It also can be used to optimize a start up system for minimum start up time

  1. Analysis of turbulence and surface growth models on the estimation of soot level in ethylene non-premixed flames

    Science.gov (United States)

    Yunardi, Y.; Munawar, Edi; Rinaldi, Wahyu; Razali, Asbar; Iskandar, Elwina; Fairweather, M.

    2018-02-01

    Soot prediction in a combustion system has become a subject of attention, as many factors influence its accuracy. An accurate temperature prediction will likely yield better soot predictions, since the inception, growth and destruction of the soot are affected by the temperature. This paper reported the study on the influences of turbulence closure and surface growth models on the prediction of soot levels in turbulent flames. The results demonstrated that a substantial distinction was observed in terms of temperature predictions derived using the k-ɛ and the Reynolds stress models, for the two ethylene flames studied here amongst the four types of surface growth rate model investigated, the assumption of the soot surface growth rate proportional to the particle number density, but independent on the surface area of soot particles, f ( A s ) = ρ N s , yields in closest agreement with the radial data. Without any adjustment to the constants in the surface growth term, other approaches where the surface growth directly proportional to the surface area and square root of surface area, f ( A s ) = A s and f ( A s ) = √ A s , result in an under- prediction of soot volume fraction. These results suggest that predictions of soot volume fraction are sensitive to the modelling of surface growth.

  2. Changes of ns-soot mixing states and shapes in an urban area during CalNex

    Science.gov (United States)

    Adachi, Kouji; Buseck, Peter R.

    2013-05-01

    Aerosol particles from megacities influence the regional and global climate as well as the health of their occupants. We used transmission electron microscopes (TEMs) to study aerosol particles collected from the Los Angeles area during the 2010 CalNex campaign. We detected major amounts of ns-soot, defined as consisting of carbon nanospheres, sulfate, sea salt, and organic aerosol (OA) and lesser amounts of brochosome particles from leaf hoppers. Ns-soot-particle shapes, mixing states, and abundances varied significantly with sampling times and days. Within plumes having high CO2 concentrations, much ns-soot was compacted and contained a relatively large number of carbon nanospheres. Ns-soot particles from both CalNex samples and Mexico City, the latter collected in 2006, had a wide range of shapes when mixed with other aerosol particles, but neither sets showed spherical ns-soot nor the core-shell configuration that is commonly used in optical calculations. Our TEM observations and light-absorption calculations of modeled particles indicate that, in contrast to ns-soot particles that are embedded within other materials or have the hypothesized core-shell configurations, those attached to other aerosol particles hardly enhance their light absorption. We conclude that the ways in which ns-soot mixes with other particles explain the observations of smaller light amplification by ns-soot coatings than model calculations during the CalNex campaign and presumably in other areas.

  3. Simulation and analysis of the soot particle size distribution in a turbulent nonpremixed flame

    KAUST Repository

    Lucchesi, Marco

    2017-02-05

    A modeling framework based on Direct Simulation Monte Carlo (DSMC) is employed to simulate the evolution of the soot particle size distribution in turbulent sooting flames. The stochastic reactor describes the evolution of soot in fluid parcels following Lagrangian trajectories in a turbulent flow field. The trajectories are sampled from a Direct Numerical Simulation (DNS) of a n-heptane turbulent nonpremixed flame. The DSMC method is validated against experimentally measured size distributions in laminar premixed flames and found to reproduce quantitatively the experimental results, including the appearance of the second mode at large aggregate sizes and the presence of a trough at mobility diameters in the range 3–8 nm. The model is then applied to the simulation of soot formation and growth in simplified configurations featuring a constant concentration of soot precursors and the evolution of the size distribution in time is found to depend on the intensity of the nucleation rate. Higher nucleation rates lead to a higher peak in number density and to the size distribution attaining its second mode sooner. The ensemble-averaged PSDF in the turbulent flame is computed from individual samples of the PSDF from large sets of Lagrangian trajectories. This statistical measure is equivalent to time-averaged, scanning mobility particle size (SMPS) measurements in turbulent flames. Although individual trajectories display strong bimodality as in laminar flames, the ensemble-average PSDF possesses only one mode and a long, broad tail, which implies significant polydispersity induced by turbulence. Our results agree very well with SMPS measurements available in the literature. Conditioning on key features of the trajectory, such as mixture fraction or radial locations does not reduce the scatter in the size distributions and the ensemble-averaged PSDF remains broad. The results highlight and explain the important role of turbulence in broadening the size distribution of

  4. Laboratory measurements of soot particle density change due to water uptake.

    Science.gov (United States)

    Crosbie, E.

    2015-12-01

    Black carbon containing soot particles are an important aerosol subclass owing to their light-absorbing properties. Furthermore, soot particles present challenges with regard to characterization and modeling of their microphysical, chemical, and optical properties, because of their inherent non-spherical, fractal morphology. Aggregation/coagulation of soot adds to the complexity of the particle morphology, while co-emitted organic compounds affect the chemical composition both during emission and though aging, which causes partitioning of secondary organic aerosol. Measurements of soot particles from vehicular and jet engine exhaust plumes have shown that the effective density can vary over a broad range (0.3-1.8 gm-3) and is affected by the fuel burn characteristics (fuel type, fuel equivalence ratio, combustion temperature), the particle size, and the extent of the aggregation. The action of organic coatings and the uptake of particle water, through hygroscopic growth, can cause a dramatic change in the morphology of soot. Restructuring of the fractal morphology into a more compact form has the effect of increasing the effective particle density, thus reducing the particle size, with important implications for the optical and hygroscopic properties. We present measurements of size-resolved particle density from laboratory generated fresh soot particles, under a range of operating conditions. We first filter by particle mass using an aerosol particle mass (APM) centrifugal analyzer and then subject the sample to a pre-humidification cycle in order to initiate particle restructuring. Finally, the sample is dried and the mobility size distribution is measured using a scanning mobility particle sizer (SMPS). A range of particle masses is scanned to determine the density as a function of size and, for each mass set point, a range of relative humidity settings are scanned to determine the extent of restructuring. We discuss the findings in relation to atmospherically

  5. A comparative study on the sooting tendencies of various 1-alkene fuels in counterflow diffusion flames

    KAUST Repository

    Wang, Yu

    2018-02-19

    Alkenes are important components in transportation fuels, and are known to have increased sooting tendencies compared to analogous saturated hydrocarbons with the same carbon number. This work aims to understand the sooting tendencies of various 1-alkenes through experiments and numerical simulations for counterflow diffusion flames. Soot and PAH formation tendencies of 1-alkene fuels, including ethylene (C2H4), propene (C3H6), 1-butene (1-C4H8), 1-pentene (1-C5H10), 1-hexene (1-C6H12) and 1-octene (1-C8H16), were experimentally studied using laser induced-incandescence (LII) and laser-induced fluorescence (LIF) techniques, respectively. From the LII results, 1-C4H8 was found to be the most sooting fuel, followed by C3H6 > 1-C5H10 > 1-C6H12 > 1-C8H16 > C2H4. The LIF data with a detection wavelength of 500 nm indicated the PAH formation tendencies followed the order of 1-C4H8 > 1-C5H10 ∼1-C6H12 > C3H6 > 1-C8H16 > C2H4, which were different from the order of sooting tendencies. Numerical simulations with a comprehensive chemical kinetic model including PAH growth chemistry for the tested 1-alkene fuels were conducted to elucidate the aromatic formation pathways and rationalize the experimentally observed trends. The numerical results highlighted the importance of intermediate species with odd carbon numbers in aromatic species formation, such as propargyl, allyl, cyclopentadienyl and indenyl radicals. Their concentration differences, which could be traced back to the parent fuel molecules through rate of production analysis, rationalize the experimentally observed differences in soot and PAH formation tendencies.

  6. Catalytic soot oxidation over Ce- and Cu-doped hydrotalcites-derived mesoporous mixed oxides.

    Science.gov (United States)

    Wang, Zhongpeng; Wang, Liguo; He, Fang; Jiang, Zheng; Xiao, Tiancun; Zhang, Zhaoliang

    2014-09-01

    Ce- and Cu-doped hydrotalcites derived mixed oxides were prepared through co-precipitation and calcination method, and their catalytic activities for soot oxidation with O2 and O2/NO were investigated. The solids were characterized by XRD, TG-DTG, BET, H2-TPR, in situ FTIR and TPO techniques. All the catalysts precursors showed the typical diffraction patterns of hydrotalcite-like materials having layered structure. The derived mixed oxides exhibited mesoporous properties with specific surface area of 45-160 m2/g. After both Ce and Cu incorporated, mixed crystalline phases of CuO (tenorite), CeO2 (fluorite) and MgAl2O4 (spinel) were formed. As a result, the NO(x) adsorption capacity of this catalyst was largely increased to 201 μmol/g, meanwhile, it was also the most effective to convert NO into NO2 in the sorption process due to the enhanced reducibility. The in situ FTIR spectra revealed that NO(x) were stored mainly as chelating bidentate and monodentate nitrate. The interaction effect between Cu and Ce in the mixed oxide resulted in different NO(x) adsorption behavior. Compared with the non-catalyzed soot oxidation, soot conversion curves over the mixed oxides catalysts shift to low temperature in O2. The presence of NO in the gas phase significantly enhanced the soot oxidation activity with ignition temperature decreased to about 320 degrees C, which is due to NO conversion to NO2 over the catalyst followed by the reaction of NO2 with soot. This explains the cooperative effect of Ce and Cu in the mixed oxide on soot oxidation with high activity and 100% selectivity to CO2 formation.

  7. Characterizing germania concentration and structure in fiber soot using multiphoton microscopy and spectroscopy technology

    Science.gov (United States)

    Chen, Minghan; Li, Ming-Jun; Liu, Anping

    2015-02-01

    Germania doping is commonly used in the core of optical fiber due to its advantages compared to other materials such as superior transparency in near-infrared telecommunication wavelength region. During fiber preform manufacturing using the outside vapor deposition (OVD) process, Ge is doped into a silica soot preform by chemical vapor deposition. Since the Ge doping concentration profile is directly correlated with the fiber refractive index profile, its characterization is critical for the fiber industry. Electron probe micro-analyzer (EPMA) is a conventional analysis method for characterizing the Ge concentration profile. However, it requires extensive sample preparation and lengthy measurement. In this paper, a multiphoton microscopy technique is utilized to measure the Ge doping profile based on the multiphoton fluorescence intensity of the soot layers. Two samples, one with ramped and another with stepped Ge doping profiles were prepared for measurements. Measured results show that the technique is capable of distinguishing ramped and stepped Ge doping profiles with good accuracy. In the ramped soot sample, a sharp increment of doping level was observed in about 2 mm range from soot edge followed by a relative slow gradient doping accretion. As for the stepped doping sample, step sizes ranging from around 1 mm (at soot edge) to 3 mm (at soot center) were observed. All the measured profiles are in close agreement with that of the EPMA measurements. In addition, both multiphoton fluorescence (around 420 nm) and sharp second harmonic generations (at 532 nm) were observed, which indicates the co-existence of crystal and amorphous GeO2.

  8. Steam generators and waste heat boilers for process and plant engineers

    CERN Document Server

    Ganapathy, V

    2014-01-01

    Incorporates Worked-Out Real-World ProblemsSteam Generators and Waste Heat Boilers: For Process and Plant Engineers focuses on the thermal design and performance aspects of steam generators, HRSGs and fire tube, water tube waste heat boilers including air heaters, and condensing economizers. Over 120 real-life problems are fully worked out which will help plant engineers in evaluating new boilers or making modifications to existing boiler components without assistance from boiler suppliers. The book examines recent trends and developments in boiler design and technology and presents novel idea

  9. Model-free adaptive control of supercritical circulating fluidized-bed boilers

    Science.gov (United States)

    Cheng, George Shu-Xing; Mulkey, Steven L

    2014-12-16

    A novel 3-Input-3-Output (3.times.3) Fuel-Air Ratio Model-Free Adaptive (MFA) controller is introduced, which can effectively control key process variables including Bed Temperature, Excess O2, and Furnace Negative Pressure of combustion processes of advanced boilers. A novel 7-input-7-output (7.times.7) MFA control system is also described for controlling a combined 3-Input-3-Output (3.times.3) process of Boiler-Turbine-Generator (BTG) units and a 5.times.5 CFB combustion process of advanced boilers. Those boilers include Circulating Fluidized-Bed (CFB) Boilers and Once-Through Supercritical Circulating Fluidized-Bed (OTSC CFB) Boilers.

  10. Thermal and optical analysis of selective absorber coatings based on soot for applications in solar cookers

    Science.gov (United States)

    Servín, H.; Peña, M.; Sobral, H.; González, M.

    2017-01-01

    The thermal and optical properties of selective absorber coatings of a solar cooker have been investigated. Coatings have been prepared using soot from pine resin, wood stove and sugarcane, previously separated by size. Results show that the cooking power and the overall efficiency of these pots are higher than others painted with black primer. Besides, by using an integrating sphere, the diffuse reflectance of absorbers has been obtained. Lower values of the reflectance have been measured for the pots covered with soot, showing a high correlation with the results achieved from the thermal tests, considering the measurement errors.

  11. Combustion and Gasification Collection of Diesel Soot by Means of Microwave Heating

    Directory of Open Access Journals (Sweden)

    Xueshi YAO

    2014-06-01

    Full Text Available The experiment of integrated purification of diesel soot was made by means of microwave heating. The experiment includes combustion and gasification collection. The catalytic effect of ceramic carrier was used in the combustion process. In order to improve the purification efficiency of PM2.5 particles, the surfactants were used in gasification collection. The model of computer control was set up so that the purification course could be controlled. The experimental principle was analyzed. Experiment result indicated that the diesel soot purifying efficiency is more than 90 %. The purification efficiency can be improved further by the optimization design of experimental device.

  12. Soot formation in a blast furnace - Prediction via a parametric study, using detailed kinetic modeling

    Energy Technology Data Exchange (ETDEWEB)

    Nordstroem, T.; Kilpinen, P.; Hupa, M. [Aabo Akademi, Turku (Finland). Combustion Chemistry Group

    1996-12-31

    The objective of this work has been to investigate the soot formation in a blast furnace fired with heavy fuel oil, using detailed kinetic modelling. This work has been concentrated on parameter studies that could explain under which conditions soot is formed and how that formation could be avoided. The parameters investigated were temperature, pressure, stoichiometric ratio, pyrolysis gas composition and reactor model. The calculations were based on a reaction mechanism that consists of 100 species and 446 reactions including polyaromatic hydrocarbons (PAM) up to 7 aromatic rings SULA 2 Research Programme; 4 refs.

  13. Chemical mechanism for high temperature combustion of engine relevant fuels with emphasis on soot precursors

    OpenAIRE

    Blanquart, G.; Pepiot-Desjardins, P.; Pitsch, H.

    2009-01-01

    This article presents a chemical mechanism for the high temperature combustion of a wide range of hydrocarbon fuels ranging from methane to iso-octane. The emphasis is placed on developing an accurate model for the formation of soot precursors for realistic fuel surrogates for premixed and diffusion flames. Species like acetylene (C_2H_2), propyne (C_3H_4), propene (C_3H_6), and butadiene (C_4H_6) play a major role in the formation of soot as their decomposition leads to the production of rad...

  14. Measurements and Modeling of Soot Formation and Radiation in Microgravity Jet Diffusion Flames. Volume 4

    Science.gov (United States)

    Ku, Jerry C.; Tong, Li; Greenberg, Paul S.

    1996-01-01

    This is a computational and experimental study for soot formation and radiative heat transfer in jet diffusion flames under normal gravity (1-g) and microgravity (0-g) conditions. Instantaneous soot volume fraction maps are measured using a full-field imaging absorption technique developed by the authors. A compact, self-contained drop rig is used for microgravity experiments in the 2.2-second drop tower facility at NASA Lewis Research Center. On modeling, we have coupled flame structure and soot formation models with detailed radiation transfer calculations. Favre-averaged boundary layer equations with a k-e-g turbulence model are used to predict the flow field, and a conserved scalar approach with an assumed Beta-pdf are used to predict gaseous species mole fraction. Scalar transport equations are used to describe soot volume fraction and number density distributions, with formation and oxidation terms modeled by one-step rate equations and thermophoretic effects included. An energy equation is included to couple flame structure and radiation analyses through iterations, neglecting turbulence-radiation interactions. The YIX solution for a finite cylindrical enclosure is used for radiative heat transfer calculations. The spectral absorption coefficient for soot aggregates is calculated from the Rayleigh solution using complex refractive index data from a Drude- Lorentz model. The exponential-wide-band model is used to calculate the spectral absorption coefficient for H20 and C02. It is shown that when compared to results from true spectral integration, the Rosseland mean absorption coefficient can provide reasonably accurate predictions for the type of flames studied. The soot formation model proposed by Moss, Syed, and Stewart seems to produce better fits to experimental data and more physically sound than the simpler model by Khan et al. Predicted soot volume fraction and temperature results agree well with published data for a normal gravity co-flow laminar

  15. Simultaneous Elimination of Soot and NOX through Silver-Barium Based Catalytic Materials

    Directory of Open Access Journals (Sweden)

    Ganesh Chandra Dhal

    2017-04-01

    Full Text Available In this research paper, the nanometric size effect, the effects of the intrinsic factors including structure, and the redox properties of three systems of nanometric of silver-based catalysts were summarized. In this work, these catalysts were investigated for the simultaneous removal of particulate matter (diesel soot, and NOX was compared with that of a model of Pt-Ba/Al2O3 catalyst. The Silver-Barium based catalytic materials of Ag (5 wt%-Ba(10 wt%/MO (MO=Al2O3, CeO2, ZrO2, and Ag (5 wt%-Sr (10 wt%/CeO2 catalysts have been prepared by wetness impregnation method and characterized by BET, XRD, HRTEM, XPS and TPR (temperature-programmed reduction experiments. The behavior of the catalyst in the soot combustion (under tight conditions and NOX elimination has been separately analyzed by means of temperature programmed oxidation and isothermal concentration step change experiments, respectively. The results showed that all the catalysts were active in soot combustion with an indicative decrease of oxidation onset temperature compared to uncatalyzed soot oxidation. The removal of NOX in the presence and in the absence of soot was investigated under cycling conditions, i.e. alternating lean-rich phases according to the LNT approach. It has been found that the Ag-based samples were able to simultaneously remove soot and NOX. In particular, studying the behavior of the prepared catalysts, the Ba-containing systems exhibited higher NOX storage capacity than Sr-catalyst; also, the nitrogen selectivity increased even if resulted lower than the traditional LNT Pt-based catalyst. An adverse effect of soot on the NOX storage activity has been also observed. Copyright © 2017 BCREC GROUP. All rights reserved Received: 18th August 2016; Revised: 19th October 2016; Accepted: 19th October 2016 How to Cite: Dhal, G.C., Dey, S., Prasad, R., Mohan, D. (2017. Simultaneous Elimination of Soot and NOX through Silver-Barium Based Catalytic Materials. Bulletin of

  16. Fundamental insight in soot oxidation over a Ag/Co3O4 catalyst by means of Environmental TEM

    DEFF Research Database (Denmark)

    Gardini, Diego; Christiansen, J. M.; Jensen, Anker Degn

    A novel Ag/Co3O4 catalyst for low-temperature soot oxidation has been studied by means of environmental TEM in order to get fundamental insight in the oxidation mechanism. Soot particles generated in diesel engines are responsible for respiratory diseases, lung cancer and affect the climate both....... Catalytic tests of the novel Ag/Co3O4 system carried out in a flow reactor show high conversion efficiencies. The temperature dependence of the soot oxidation rate for this new system cannot be directly described in terms of the activity of the single Ag and Co3O4 components, but is strongly dependent...... on preparation method, degree of contact with the soot and temperature range. In order to fully understand the role of the single constituents and the influence of different operating conditions in the overall catalytic activity, flow reactor experiments have been coupled with in situ soot oxidation...

  17. Temporal Evolution of Soot Particles from C2H2/O2 Combustion in a Closed Chamber

    Directory of Open Access Journals (Sweden)

    Bertran Celso A.

    2002-01-01

    Full Text Available An experimental study of soot formation in C2H2/O2 flames at different C/O ratios in a closed chamber was carried out. The evolution temporal behavior and the volume fraction of soot particles were determined by laser extinction. It was found that total time for the soot formation phenomenon in flames from C2H2/O2 with C/O ratio > 0.75 or C2H2/O2/Ar with C/O ratio = 1.00 was around 3.0-4.0 ms after ignition. At almost the same time the excited radicals reached their maximum emission intensity and the gases under combustion reached their maximum pressure. The micrographs show compact and approximately spherical soot particles with diameters within 60-150 nm. However, soot aggregates are not compact and they present a netlike structure similar to that of an aerogel.

  18. A Chemical Kinetic Modeling Study of the Effects of Oxygenated Hydrocarbons on Soot Emissions from Diesel Engines

    Energy Technology Data Exchange (ETDEWEB)

    Westbrook, C K; Pitz, W J; Curran, H J

    2005-11-14

    A detailed chemical kinetic modeling approach is used to examine the phenomenon of suppression of sooting in diesel engines by addition of oxygenated hydrocarbon species to the fuel. This suppression, which has been observed experimentally for a few years, is explained kinetically as a reduction in concentrations of soot precursors present in the hot products of a fuel-rich diesel ignition zone when oxygenates are included. Oxygenates decrease the overall equivalence ratio of the igniting mixture, producing higher ignition temperatures and more radical species to consume more soot precursor species, leading to lower soot production. The kinetic model is also used to show how different oxygenates, ester structures in particular, can have different soot-suppression efficiencies due to differences in molecular structure of the oxygenated species.

  19. Morphological study of fluorescent carbon Nanoparticles (F-CNPs) from ground coffee waste soot oxidation by diluted acid

    Science.gov (United States)

    Gea, S.; Tjandra, S.; Joshua, J.; Wirjosentono, B.

    2018-02-01

    Coffee ground waste utilization for fluorescent carbon nanoparticles (F-CNPs) through soot oxidation with diluted HNO3 has been conducted. Soot was obtained through three different treatments to coffee ground waste; which was burned in furnaceat 550°C and 650°C and directly burned in a heat-proofcontainer. Then they were analyzed morphologically with Scanning Electron Microscope (SEM) instrument. Soot from direct burning indicated the optimum result where it has denser pores compared to other two soots. Soot obtained from direct burning was refluxed in diluted HNO3 for 12 hours to perform the oxidation. Yellowish brown supernatant was later observed which lead to green fluorescent under the UV light. F-CNPs characterization was done in Transmission Electron Microscopy, which showed that 7.4-23.4 nm of particle size were distributed.

  20. Uptake of HNO3 on aviation kerosene and aircraft engine soot: influences of H2O or/and H2SO4.

    Science.gov (United States)

    Loukhovitskaya, Ekaterina E; Talukdar, Ranajit K; Ravishankara, A R

    2013-06-13

    The uptake of HNO3 on aviation kerosene soot (TC-1 soot) was studied in the absence and presence of water vapor at 295 and 243 K. The influence of H2SO4 coating of the TC-1 soot surface on HNO3 uptake was also investigated. Only reversible uptake of HNO3 was observed. HONO and NO2, potential products of reactive uptake of HNO3, were not observed under any conditions studied here. The uptake of nitric acid increased slightly with relative humidity (RH). Coating of the TC-1 soot surface with sulfuric acid decreased the uptake of HNO3 and did not lead to displacement of H2SO4 from the soot surface. A limited set of measurements was carried out on soot generated by aircraft engine combustor (E-soot) with results similar to those on TC-1 soot. The influence of water on HNO3 uptake on E-soot appeared to be more pronounced than on TC-1 soot. Our results suggest that HNO3 loss in the upper troposphere due to soot is not significant except perhaps in aircraft exhaust plumes. Our results also suggest that HNO3 is not converted to either NO2 or HONO upon its uptake on soot in the atmosphere.

  1. Morphology and nano-structure analysis of soot particles sampled from high pressure diesel jet flames under diesel-like conditions

    Science.gov (United States)

    Jiang, Hao; Li, Tie; Wang, Yifeng; He, Pengfei

    2018-04-01

    Soot particles emitted from diesel engines have a significant impact on the atmospheric environment. Detailed understanding of soot formation and oxidation processes is helpful for reducing the pollution of soot particles, which requires information such as the size and nano-structure parameters of the soot primary particles sampled in a high-temperature and high-pressure diesel jet flame. Based on the thermophoretic principle, a novel sampling probe minimally disturbing the diesel jet flame in a constant volume combustion vessel is developed for analysing soot particles. The injected quantity of diesel fuel is less than 10 mg, and the soot particles sampled by carriers with a transmission electron microscope (TEM) grid and lacey TEM grid can be used to analyse the morphologies of soot aggregates and the nano-structure of the soot primary particles, respectively. When the quantity of diesel fuel is more than 10 mg, in order to avoid burning-off of the carriers in higher temperature and pressure conditions, single-crystal silicon chips are employed. Ultrasonic oscillations and alcohol extraction are then implemented to obtain high quality soot samples for observation using a high-resolution transmission electron microscope. An in-house Matlab-based code is developed to extract the nano-structure parameters of the soot particles. A complete sampling and analysis procedure of the soot particles is provided to study the formation and oxidation mechanism of soot.

  2. Computations of NOx emissions of domestic boilers

    Energy Technology Data Exchange (ETDEWEB)

    Thevenin, D. [Ecole Centrale de Paris, 92 - Chatenay-Malabry (France). EM2C Lab.; Gicquel, O.; Darabiha, N.

    2001-07-01

    Due to severe regulations concerning pollutant emissions, practical devices using combustion to release energy must be designed from the start using accurate, predictive numerical tools. A partially premixed methane/air flame in a two-dimensional configuration is investigated in this work. This configuration is close to those used in real domestic gas boilers. The flame structure and flow pattern are calculated using complex chemistry and detailed transport models. A post-processing method is then used to predict NO emission. Computations are performed for two configurations. The two cases have the same primary and secondary mass flow-rates and equivalence ratio. The only difference between them is the introduction of an insert inside the primary injector. Both results have been compared to measurements. Calculations are found to be in good agreement with the flame shapes observed experimentally. The classical burner shows a Bunsen-type flame while the one with an insert has a totally different shape (butterfly-type flame). NO emission levels are also well predicted in both configurations. The butterfly flame induces a reduction in NO emission. This reduction seems to be due to the increased mixing between the burnt gases and the secondary air jet, which homogenizes the temperature distribution and reduces the maximum temperature. (orig.)

  3. Ultra-Supercritical Pressure CFB Boiler Conceptual Design Study

    Energy Technology Data Exchange (ETDEWEB)

    Zhen Fan; Steve Goidich; Archie Robertson; Song Wu

    2006-06-30

    Electric utility interest in supercritical pressure steam cycles has revived in the United States after waning in the 1980s. Since supercritical cycles yield higher plant efficiencies than subcritical plants along with a proportional reduction in traditional stack gas pollutants and CO{sub 2} release rates, the interest is to pursue even more advanced steam conditions. The advantages of supercritical (SC) and ultra supercritical (USC) pressure steam conditions have been demonstrated in the high gas temperature, high heat flux environment of large pulverized coal-fired (PC) boilers. Interest in circulating fluidized bed (CFB) combustion, as an alternative to PC combustion, has been steadily increasing. Although CFB boilers as large as 300 MWe are now in operation, they are drum type, subcritical pressure units. With their sizes being much smaller than and their combustion temperatures much lower than those of PC boilers (300 MWe versus 1,000 MWe and 1600 F versus 3500 F), a conceptual design study was conducted herein to investigate the technical feasibility and economics of USC CFB boilers. The conceptual study was conducted at 400 MWe and 800 MWe nominal plant sizes with high sulfur Illinois No. 6 coal used as the fuel. The USC CFB plants had higher heating value efficiencies of 40.6 and 41.3 percent respectively and their CFB boilers, which reflect conventional design practices, can be built without the need for an R&D effort. Assuming construction at a generic Ohio River Valley site with union labor, total plant costs in January 2006 dollars were estimated to be $1,551/kW and $1,244/kW with costs of electricity of $52.21/MWhr and $44.08/MWhr, respectively. Based on the above, this study has shown that large USC CFB boilers are feasible and that they can operate with performance and costs that are competitive with comparable USC PC boilers.

  4. Identification of boiler tube leak in PHWR by measuring short lived radioisotope Iodine-134 in boiler water using gamma spectrometric techniques

    International Nuclear Information System (INIS)

    Pal, P.K.; Bohra, R.C.

    2015-01-01

    The boiler tube made up of Monel-400 of RAPS-2 has failed on few occasions. Due to the failure of boiler tube, the active heavy water enters into boiler and feed water leading to contamination of radioactivity in secondary water circuit. The identification of boiler tube failure was done by measuring gamma ray activity of Iodine-134 in the boiler water with sample using gamma spectrometry with high purity germanium detector. In order to increase the sensitivity of the method 5 liters of Boiler water sample was passed through a plastic column containing 40 ml of anion resin and 10 ml of activated charcoal to capture the isotopes of Iodine in the anionic form and molecular form. Samples were collected from all 8 Boilers of RAPS-2. The activity of 134 I was shown only by Boiler - 5. No other boilers showed any activity of 134 I. This indicated that Boiler - 5 had leaky tubes. The leaky hairpin of boiler - 5 was identified by measuring Tritium and IP in the riser and down comer of all 10 HXs. On the basis of Tritium and IP result, HX-7 was identified as leaky hairpin. (author)

  5. Models for the optical simulations of fractal aggregated soot particles thinly coated with non-absorbing aerosols

    Science.gov (United States)

    Wu, Yu; Cheng, Tianhai; Zheng, Lijuan; Chen, Hao

    2016-10-01

    Light absorption enhancement of aged soot aerosols is highly sensitive to the morphologies and mixing states of soot aggregates and their non-absorbing coatings, such as organic materials. The quantification of these effects on the optical properties of thinly coated soot aerosols is simulated using an effective model with fixed volume fractions. Fractal aggregated soot was simulated using the diffusion limited aggregation (DLA) algorithm and discretized into soot dipoles. The dipoles of non-absorbing aerosols, whose number was fixed by the volume fraction, were further generated from the neighboring random edge dipoles. Their optical properties were calculated using the discrete dipole approximation (DDA) method and were compared with other commonly used models. The optical properties of thinly coated soot calculated using the fixed volume fraction model are close to (less than ~10% difference) the results of the fixed coating thickness model, except their asymmetry parameters (up to ~25% difference). In the optical simulations of thinly coated soot aerosols, this relative difference of asymmetry parameters and phase functions between these realistic models may be notable. The realizations of the fixed volume fraction model may introduce smaller variation of optical results than those of the fixed coating thickness model. Moreover, the core-shell monomers model and homogeneous aggregated spheres model with the Maxwell-Garnett (MG) theory may underestimate (up to ~20%) the cross sections of thinly coated soot aggregates. The single core-shell sphere model may largely overestimate (up to ~150%) the cross sections and single scattering albedo of thinly coated soot aggregates, and it underestimated (up to ~60%) their asymmetry parameters. It is suggested that the widely used single core-shell sphere approximation may not be suitable for the single scattering calculations of thinly coated soot aerosols.

  6. A statistical estimator for the boiler power and its related parameters

    International Nuclear Information System (INIS)

    Tang, H.

    2001-01-01

    To determine the boiler power accurately is important for both controlling the plant and maximizing the plant productivity. There are two computed boiler powers for each boiler. They are steam based boiler power and feedwater based boiler power. The steam based boiler power is computed as the enthalpy difference between the feedwater enthalpy and the boiler steam enthalpy. The feedwater based boiler power is computed as enthalpy absorbed by the feedwater. The steam based boiler power is computed in RRS program and used in calibrating the measured reactor power, while the feedwater based boiler power is computed in CSTAT program and used for indication. Since the steam based boiler power is used as feedback in the reactor control, it is chosen to be the one estimated in this work. Because the boiler power employs steam flow, feedwater flow and feedwater temperature measurements, and because any measurement contains constant or drifting noise and bias, the reconciliation and rectification procedures are needed to determine the boiler power more accurately. A statistic estimator is developed to perform the function of data reconciliation, gross error detection and instruments performance monitoring

  7. Corrective Action Decision Document/Closure Report for Corrective Action Unit 559: T Tunnel Compressor/Blower Pad, Nevada Test Site

    Energy Technology Data Exchange (ETDEWEB)

    NSTec Environmental Restoration

    2010-03-15

    This Corrective Action Decision Document (CADD)/Closure Report (CR) was prepared by the Defense Threat Reduction Agency (DTRA) for Corrective Action Unit (CAU) 559, T-Tunnel Compressor/Blower Pad. This CADD/CR is consistent with the requirements of the Federal Facility Agreement and Consent Order (FFACO) agreed to by the State of Nevada, the U.S. Department of Energy, and the U.S. Department of Defense. Corrective Action Unit 559 is comprised of one Corrective Action Site (CAS): • 12-25-13, Oil Stained Soil and Concrete The purpose of this CADD/CR is to provide justification and documentation supporting the recommendation for closure in place with use restrictions for CAU 559.

  8. Vibration analysis and online thermodynamic assessment of a turbo-blower turbine; Analisis de vibraciones y evaluacion termodinamica en linea de la turbina de un turbosoplador

    Energy Technology Data Exchange (ETDEWEB)

    Munoz Q, Rodolfo; Marino L, Carlos; Ramirez S, Jose A.; Rivera G, Juan J. [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2007-11-15

    In this paper are presented the results of the analysis of dynamic and thermodynamic behavior analysis of a turbo-blower integrated by one 13,080 KW steam turbine and a blower with a flow of 131,520 ft{sup 3}/m, to determine the cause of the excessive wearing of the axial trust bearing of the steam turbine. The main cause of failure is the wearing and severe dirtiness of the turbine stages that contributes with an increment of the turbine axial load. The consequences of the turbine deterioration are: greater axial load due to the additional heating rotor (requires greater steam to generate the same power that in design conditions); turbine motive power reduction and the reduction of isentropic efficiency of the same, for similar average steam consumption between reference and test. Due to the former the turbine power represents a deviation of the 34.74% in Steam Specific Consumption (SSC). [Spanish] Se presenta los resultados del analisis del comportamiento dinamico y termodinamico de un turbosoplador integrado por una turbina de vapor de 13,080 KW y un soplador con un caudal de 131,520 pies{sup 3}/m, para determinar la causa del desgaste excesivo de la chumacera de empuje axial de la turbina de vapor. La causa principal de la falla es el desgaste y ensuciamiento severo de las etapas de la turbina que contribuye con un incremento de la carga axial de la turbina. Las consecuencias del deterioro de la turbina son: mayor carga axial debida al calentamiento adicional del rotor (requiere mayor vapor para generar la misma potencia que en condiciones de diseno); reduccion de la potencia motriz de la turbina y de la eficiencia isoentropica de las mismas, para un consumo de vapor promedio similar entre referencia y prueba. Debido a lo anterior la potencia de la turbina representa una desviacion del 34.74% en el Consumo Especifico de Vapor (CVE).

  9. Investing in efficient industrial boiler systems in China and Vietnam

    International Nuclear Information System (INIS)

    Yang Ming; Dixon, Robert K.

    2012-01-01

    Energy efficiency in industrial boiler steam systems can be very low due to old technologies, improper design and non-optimal operation of the steam systems. Solutions include efficiency assessments and investments in steam system optimizations, education and training for operators of the systems. This paper presents case studies on assessing and investing in boiler steam systems in China and Vietnam. Methodologies and approaches for data collection and analyses were designed specifically for each of the two countries. This paper concludes: (1) investing in energy efficiency in industrial boiler steam system in China and Vietnam are cost effective; (2) government should not sent national energy efficiency standards lower than that of energy companies or energy equipment manufactures. - Highlights: ► GEF successfully catalyzed investment in industrial energy efficiency boilers in China in 1990s. ► With about $100 million of investment by the GEF/World Bank/Chinese government, the project will mitigate 40 million tons of CO 2 by 2019. ► This generated lowest unit cost of carbon reduction in the world: about $2.5 per ton of CO 2 mitigation. ► Investing in energy efficiency in industrial boiler steam system today in Vietnam will be the same cost effective as in China: $2.1 per ton of CO 2 mitigation.

  10. Analysis of a waste-heat boiler by CFD simulation

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yongziang; Jokilaakso, A. [Helsinki Univ. of Technology, Otaniemi (Finland)

    1996-12-31

    Waste-heat boilers play important roles in the continuous operation of a smelter and in the conservation of energy. However, the fluid flow and heat transfer behaviour has not been well studied, concerning the boiler performance and design. This presentation describes simulated gas flow and heat transfer of a waste-heat boiler in the Outokumpu copper flash smelting process. The governing transport equations for the conservation of mass, momentum and enthalpy were solved with a commercial CFD-code PHOENICS. The standard k-{epsilon} turbulence model and a composite-flux radiation model were used in the computations. The computational results show that the flow is strongly recirculating and distinctly three-dimensional in most part of the boiler, particularly in the radiation section. The predicted flow pattern and temperature distribution were in a good agreement with laboratory models and industrial measurements. The results provide detailed information of flow pattern, the temperature distribution and gas cooling efficiency. The CFD proved to be a useful tool in analysing the boiler operation. (author)

  11. Numerical simulation of a small-scale biomass boiler

    International Nuclear Information System (INIS)

    Collazo, J.; Porteiro, J.; Míguez, J.L.; Granada, E.; Gómez, M.A.

    2012-01-01

    Highlights: ► Simplified model for biomass combustion was developed. ► Porous zone conditions are used in the bed. ► Model is fully integrated in a commercial CFD code to simulate a small scale pellet boiler. ► Pollutant emissions are well predicted. ► Simulation provides extensive information about the behaviour of the boiler. - Abstract: This paper presents a computational fluid dynamic simulation of a domestic pellet boiler. Combustion of the solid fuel in the burner is an important issue when discussing the simulation of this type of system. A simplified method based on a thermal balance was developed in this work to introduce the effects provoked by pellet combustion in the boiler simulation. The model predictions were compared with the experimental measurements, and a good agreement was found. The results of the boiler analysis show that the position of the water tubes, the distribution of the air inlets and the air infiltrations are the key factors leading to the high emission levels present in this type of system.

  12. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Gandy, David W. [Electric Power Research Institute, Inc., Palo Alto, CA (United States); Shingledecker, John P. [Electric Power Research Institute, Inc., Palo Alto, CA (United States)

    2011-05-11

    Coal-fired power plants are a significant part of the nation's power generating capacity, currently accounting for more than 55% of the country's total electricity production. Extending the reliable lifetimes of fossil fired boiler components and reducing the maintenance costs are essential for economic operation of power plants. Corrosion and erosion are leading causes of superheater and reheater boiler tube failures leading to unscheduled costly outages. Several types of coatings and weld overlays have been used to extend the service life of boiler tubes; however, the protection afforded by such materials was limited approximately one to eight years. Power companies are more recently focused in achieving greater plant efficiency by increasing steam temperature and pressure into the advanced-ultrasupercritical (A-USC) condition with steam temperatures approaching 760°C (1400°F) and operating pressures in excess of 35MPa (5075 psig). Unfortunately, laboratory and field testing suggests that the resultant fireside environment when operating under A-USC conditions can potentially cause significant corrosion to conventional and advanced boiler materials1-2. In order to improve reliability and availability of fossil fired A-USC boilers, it is essential to develop advanced nanostructured coatings that provide excellent corrosion and erosion resistance without adversely affecting the other properties such as toughness and thermal fatigue strength of the component material.

  13. Formation, growth, and transport of soot in a three-dimensional turbulent non-premixed jet flame

    KAUST Repository

    Attili, Antonio

    2014-07-01

    The formation, growth, and transport of soot is investigated via large scale numerical simulation in a three-dimensional turbulent non-premixed n-heptane/air jet flame at a jet Reynolds number of 15,000. For the first time, a detailed chemical mechanism, which includes the soot precursor naphthalene and a high-order method of moments are employed in a three-dimensional simulation of a turbulent sooting flame. The results are used to discuss the interaction of turbulence, chemistry, and the formation of soot. Compared to temperature and other species controlled by oxidation chemistry, naphthalene is found to be affected more significantly by the scalar dissipation rate. While the mixture fraction and temperature fields show fairly smooth spatial and temporal variations, the sensitivity of naphthalene to turbulent mixing causes large inhomogeneities in the precursor fields, which in turn generate even stronger intermittency in the soot fields. A strong correlation is apparent between soot number density and the concentration of naphthalene. On the contrary, while soot mass fraction is usually large where naphthalene is present, pockets of fluid with large soot mass are also frequent in regions with very low naphthalene mass fraction values. From the analysis of Lagrangian statistics, it is shown that soot nucleates and grows mainly in a layer close to the flame and spreads on the rich side of the flame due to the fluctuating mixing field, resulting in more than half of the total soot mass being located at mixture fractions larger than 0.6. Only a small fraction of soot is transported towards the flame and is completely oxidized in the vicinity of the stoichiometric surface. These results show the leading order effects of turbulent mixing in controlling the dynamics of soot in turbulent flames. Finally, given the difficulties in obtaining quantitative data in experiments of turbulent sooting flames, this simulation provides valuable data to guide the development of

  14. On synthesis and optimization of steam system networks. 1. Sustained boiler efficiency

    CSIR Research Space (South Africa)

    Majozi, T

    2010-08-01

    Full Text Available situations. This paper presents a process integration technique for network synthesis using conceptual and mathematical analysis without compromising boiler efficiency. It was found that the steam flow rate to the HEN could be reduced while maintaining boiler...

  15. Alumina supported Co-K-Mo based catalytic material for diesel soot oxidation

    Czech Academy of Sciences Publication Activity Database

    Dhakad, M.; Joshi, A.G.; Rayalu, S.; Tanwar, P.; Bassin, J.K.; Kumar, R.; Lokhande, S.; Šubrt, Jan; Mitsuhashi, T.; Labhsetwar, N.

    2009-01-01

    Roč. 52, 13-20 (2009), s. 2070-2075 ISSN 1022-5528 Institutional research plan: CEZ:AV0Z40320502 Keywords : soot oxidation * diesel particulate filter * catalyst carbon oxidation Subject RIV: CA - Inorganic Chemistry Impact factor: 2.379, year: 2009

  16. Low cost, ceria promoted perovskite type catalysts for diesel soot oxidation

    Czech Academy of Sciences Publication Activity Database

    Dhakad, M.; Rayalu, S.; Kumar, R.; Doggali, P.; Bakardjieva, Snejana; Šubrt, Jan; Mitsuhashi, T.; Haneda, H.; Labhsetwar, N.

    2008-01-01

    Roč. 121, 1-2 (2008), s. 137-143 ISSN 1011-372X Institutional research plan: CEZ:AV0Z40320502 Keywords : soot oxidation * perovskite * diesel emissions Subject RIV: CA - Inorganic Chemistry Impact factor: 1.867, year: 2008

  17. Efficient low-temperature soot combustion by bimetallic Ag-Cu/SBA-15 catalysts.

    Science.gov (United States)

    Wen, Zhaojun; Duan, Xinping; Hu, Menglin; Cao, Yanning; Ye, Linmin; Jiang, Lilong; Yuan, Youzhu

    2018-02-01

    In this study, the effects of copper (Cu) additive on the catalytic performance of Ag/SBA-15 in complete soot combustion were investigated. The soot combustion performance of bimetallic Ag-Cu/SBA-15 catalysts was higher than that of monometallic Ag and Cu catalysts. The optimum catalytic performance was acquired with the 5Ag 1 -Cu 0.1 /SBA-15 catalyst, on which the soot combustion starts at T ig =225°C with a T 50 =285°C. The temperature for 50% of soot combustion was lower than that of conventional Ag-based catalysts to more than 50°C (Aneggi et al., 2009). Physicochemical characterizations of the catalysts indicated that addition of Cu into Ag could form smaller bimetallic Ag-Cu nanolloy particles, downsizing the mean particle size from 3.7nm in monometallic catalyst to 2.6nm in bimetallic Ag-Cu catalyst. Further experiments revealed that Ag and Cu species elicited synergistic effects, subsequently increasing the content of surface active oxygen species. As a result, the structure modifications of Ag by the addition of Cu strongly intensified the catalytic performance. Copyright © 2017. Published by Elsevier B.V.

  18. The Ångström Exponent and Turbidity of Soot Component in the ...

    African Journals Online (AJOL)

    ABSTRACT: In this work, we extracted data from Optical Properties of Aerosols and Clouds (OPAC) using. FORTRAN program to model the effect of soot on optical depth, scattering coefficient, absorption coefficient, single scattering albedo, extinction coefficient and asymmetry parameter at spectral range of 0.25 to 1.00 μm ...

  19. In vitro Effects of Three Metallic Salts and Carbon Black (Soot) on ...

    African Journals Online (AJOL)

    The antifungal effects of zinc chloride (Zn Cl2) calcium chloride (CaCl2), magnesium chloride (MgCl2) as well as soot collected from a local kitchen were tested on five isolated species of the dermatophytes from cases of human dermatophytoses. Of these three metallic salts, ZnCl2 showed the highest inhibitory effect on the ...

  20. Investigation of soot by two-color four-wave mixing

    Energy Technology Data Exchange (ETDEWEB)

    Hemmerling, B.; Stampanoni-Panariello, A. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    A novel, non-intrusive technique has been used for the temporally resolved investigation of the interaction of laser radiation and soot in a flame. While there is a fairly good agreement between measurement and simulation remaining discrepancies indicate some shortcomings of the model employed. (author) 2 figs., 2 refs.

  1. The Ångström Exponent and Turbidity of Soot Component in the ...

    African Journals Online (AJOL)

    OPAC) using FORTRAN program to model the effect of soot on optical depth, scattering coefficient, absorption coefficient, single scattering albedo, extinction coefficient and asymmetry parameter at spectral range of 0.25 to 1.00 ƒÝm for eight ...

  2. Effective density of Aquadag and fullerene soot black carbon reference materials used for SP2 calibration

    Directory of Open Access Journals (Sweden)

    M. Gysel

    2011-12-01

    Full Text Available The mass and effective density of black carbon (BC particles generated from aqueous suspensions of Aquadag and fullerene soot was measured and parametrized as a function of their mobility diameter. The measurements were made by two independent research groups by operating a differential mobility analyser (DMA in series with an aerosol particle mass analyser (APM or a Couette centrifugal particle mass analyser (CPMA. Consistent and reproducible results were found in this study for different production lots of Aquadag, indicating that the effective density of these particles is a stable quantity and largely unaffected by differences in aerosol generation procedures and suspension treatments. The effective density of fullerene soot particles from one production lot was also found to be stable and independent of suspension treatments. Some differences to previous literature data were observed for both Aquadag and fullerene soot at larger particle diameters. Knowledge of the exact relationship between mobility diameter and particle mass is of great importance, as DMAs are commonly used to size-select particles from BC reference materials for calibration of single particle soot photometers (SP2, which quantitatively detect the BC mass in single particles.

  3. Soot and chemiluminescence in diesel combustion of bio-derived, oxygenated and reference fuels

    NARCIS (Netherlands)

    Klein-Douwel, R. J. H.; Donkerbroek, A. J.; van Vliet, A. P.; Boot, M. D.; Somers, L. M. T.; Baert, R. S. G.; Dam, N. J.; ter Meulen, J. J.

    2009-01-01

    High-speed imaging, spectroscopy and thermodynamical characterization are applied to an optically accessible, heavy-duty diesel engine in order to compare sooting and chemilunlinescence behaviour of bio-derived, oxygenated fuels and various reference fuels. The fuels concerned include the

  4. Soot and chemiluminescence in diesel combustion of bio-derived, oxygenated and reference fuels

    NARCIS (Netherlands)

    Klein-Douwel, R.J.H.; Donkerbroek, A.J.; Vliet, A.P. van; Boot, M.D.; Somers, L.M.T.; Baert, R.S.G.; Dam, N.J.; Meulen, J.J. ter

    2009-01-01

    High-speed imaging, spectroscopy and thermodynamical characterization are applied to an optically accessible, heavy-duty diesel engine in order to compare sooting and chemiluminescence behaviour of bio-derived, oxygenated fuels and various reference fuels. The fuels concerned include the bio-derived

  5. Biodiesel soot incandescence and NO emission studied in an optical engine

    NARCIS (Netherlands)

    Klein-Douwel, R.J.H.; Donkerbroek, A.J.; Vliet, A.P. van; Boot, M.D.; Somers, L.M.T.; Baert, R.S.G.; Dam, N.J.; Meulen, J.J. ter

    2009-01-01

    High-speed imaging and thermodynamical characterization are applied to an optically accessible, heavy-duty diesel engine in order to compare soot incandescence and NO emission behaviour of four bioderived fuels: rapeseed-methylester, Jatropha oil (pure), Jatropha-methylester and a 50/50 blend of

  6. Extraction and identification of organic materials present in soot from a natural gas flame

    Energy Technology Data Exchange (ETDEWEB)

    Vick, R.D.; Avery, M.J.

    1978-01-01

    Aliphatic and polynuclear aromatic hydrocarbons are readily extracted from soot formed from a natural gas flame using methylene chloride and ultrasonic agitation. Identification of 24 organic compounds via capillary column GC retention times and GC-MS data is reported along with details of experimental procedures.

  7. Soot particle size measurements in ethylene diffusion flames at elevated pressures

    KAUST Repository

    Steinmetz, Scott

    2016-05-07

    Soot particle size is investigated in laminar nitrogen-diluted ethylene coflow diffusion flames at 4, 8, 12 and 16 atm. Line of sight attenuation and scattering are used to measure two-dimensional soot volume fraction and particle size fields for the first time at elevated pressures. Soot volume fraction dependence on pressure is consistent with the observations of similar studies, scaling approximately with the square of pressure. Scattering intensity is analyzed through Rayleigh and Rayleigh-Debye-Gans polydisperse fractal aggregate theories to provide two estimates of particle size. An increase in overall particle sizes with pressure is found, consistent with similar one-dimensional studies. Particle diameters in the annulus of the flame increase faster with pressure than those on centerline. Contrary to previous studies, the dependence of particle size on pressure was found to taper off between 8 and 12 atm, with little observed growth beyond 12 atm. The measurements provide additional data for one of the International Sooting Flame (ISF) workshop\\'s target pressurized flames.

  8. New configurations of a heat recovery absorption heat pump integrated with a natural gas boiler for boiler efficiency improvement

    International Nuclear Information System (INIS)

    Qu, Ming; Abdelaziz, Omar; Yin, Hongxi

    2014-01-01

    Highlights: • Thermal and heat transfer models of absorption heat pumps driven by exhaust gas, hot water, or natural gas. • Natural gas boiler combustion model. • Heat exchanger for condensing. • Experimental data of a hot water absorption heat pump. • Economic assessment of heat recovery absorption heat pump for improving natural gas boilers. - Abstract: Conventional natural gas-fired boilers exhaust flue gas direct to the atmosphere at 150–200 °C, which, at such temperatures, contains large amount of energy and results in relatively low thermal efficiency ranging from 70% to 80%. Although condensing boilers for recovering the heat in the flue gas have been developed over the past 40 years, their present market share is still less than 25%. The major reason for this relatively slow acceptance is the limited improvement in the thermal efficiency of condensing boilers. In the condensing boiler, the temperature of the hot water return at the range of 50–60 °C, which is used to cool the flue gas, is very close to the dew point of the water vapor in the flue gas. Therefore, the latent heat, the majority of the waste heat in the flue gas, which is contained in the water vapor, cannot be recovered. This paper presents a new approach to improve boiler thermal efficiency by integrating absorption heat pumps with natural gas boilers for waste heat recovery (HRAHP). Three configurations of HRAHPs are introduced and discussed. The three configurations are modeled in detail to illustrate the significant thermal efficiency improvement they attain. Further, for conceptual proof and validation, an existing hot water-driven absorption chiller is operated as a heat pump at operating conditions similar to one of the devised configurations. An overall system performance and economic analysis are provided for decision-making and as evidence of the potential benefits. These three configurations of HRAHP provide a pathway to achieving realistic high-efficiency natural

  9. PERFORMANCE EVALUATION OF BOILERS (80 AND 40 TPH) AND 21MW STEAM TURBINE OF COGEN PLANT

    OpenAIRE

    D.P.TAWARE; P.E.CHAUDHARI; U.M.SHIRSAT

    2014-01-01

    The proposed study is conducted at The Malegaon Sugar Mills, Baramati, and District Pune. Data is collected for a high pressure 80 TPH & 40TPH bagasse fired boiler. The boilers are natural circulation and bi-drum water tube type. The both boilers are equipped with super heater, air heater and economizer in order to utilize maximum available heat of flue gases. Boiler efficiency is calculated by indirect method. Also plant has 21 MW cogeneration capacity, with two turbines are installed with c...

  10. DYMEL code for prediction of dynamic stability limits in boilers

    International Nuclear Information System (INIS)

    Deam, R.T.

    1980-01-01

    Theoretical and experimental studies of Hydrodynamic Instability in boilers were undertaken to resolve the uncertainties of the existing predictive methods at the time the first Advanced Gas Cooled Reactor (AGR) plant was commissioned. The experiments were conducted on a full scale electrical simulation of an AGR boiler and revealed inadequacies in existing methods. As a result a new computer code called DYMEL was developed based on linearisation and Fourier/Laplace Transformation of the one-dimensional boiler equations in both time and space. Beside giving good agreement with local experimental data, the DYMEL code has since shown agreement with stability data from the plant, sodium heated helical tubes, a gas heated helical tube and an electrically heated U-tube. The code is now used widely within the U.K. (author)

  11. Engineering and economic aspects of centalized heating from nuclear boilers

    International Nuclear Information System (INIS)

    Emel'yanov, I.Ya.; Baturov, B.B.; Korytnikov, V.P.; Koryakin, Yu.I.; Chernyaev, V.A.; Kovylyanskij, Ya.A.; Galaktionov, I.V.

    1979-01-01

    Some engineering and economic aspects for deployment of centralized nuclear boilers (NB) in the USSR are considered. Engineering, maintenance and economic features of NB as compared to organic-fuelled boilers and nuclear thermal power plants are discussed. Among major factors governing economic efficiency of NB underlined are oraganic fuel costs, reactor unit power, location relative to heat-consuming centres and capacity factor. It is concluded that NB can be economical for heating large consumers (more than 1500 G kal/hr). At the periphery NB can be competitive already at reactor unit power of several MWth. The development of HTGR type reactor-based nuclear-chemical boilers and lines for heat transport in a chemically bound state (e.g., CH 4 → H 2 +CO 2 +CO → CH 4 ) opens the way for a substantial breakthrow in the centralized NB efficiency

  12. Laser-Diagnostic Mapping of Temperature and Soot Statistics in a 2-m Diameter Turbulent Pool Fire

    Science.gov (United States)

    Kearney, Sean

    2013-11-01

    We present spatial profiles of temperature and soot-volume-fraction statistics from a sooting 2-m base diameter turbulent pool fire. Dual-pump coherent anti-Stokes Raman scattering (CARS) and laser-induced incandescence (LII) are utilized to obtain profiles of temperature and soot probability density functions (pdf) at three vertical heights above the surface of the methanol/toluene fuel pool. The experiments are conducted in the unique Sandia FLAME facility, which has recently been modified to allow for vertical translation of the optical systems and horizontal translation of the liquid fuel burner. Results are presented both in the fuel vapor-dome region at 0.25 base diameter and in the actively burning region at 0.5 and 0.75 diameters above the fuel surface. The evolution of the soot and temperature pdfs is discussed, profiles of the temperature and soot mean and rms statistics are provided, and initial estimates of the joint temperature/soot statistics, which describe soot radiative emission, are presented.

  13. Post-depositional enrichment of black soot in snow-pack and accelerated melting of Tibetan glaciers

    International Nuclear Information System (INIS)

    Xu Baiqing; Joswiak, Daniel R; Zhao Huabiao; Cao Junji; Liu Xianqin; He Jianqiao

    2012-01-01

    The post-depositional enrichment of black soot in snow-pack was investigated by measuring the redistribution of black soot along monthly snow-pits on a Tien Shan glacier. The one-year experiment revealed that black soot was greatly enriched, defined as the ratio of concentration to original snow concentration, in the unmelted snow-pack by at least an order of magnitude. Greatest soot enrichment was observed in the surface snow and the lower firn-pack within the melt season percolation zone. Black carbon (BC) concentrations as high as 400 ng g −1 in the summer surface snow indicate that soot can significantly contribute to glacier melt. BC concentrations reaching 3000 ng g −1 in the bottom portion of the firn pit are especially concerning given the expected equilibrium-line altitude (ELA) rise associated with future climatic warming, which would expose the dirty underlying firn and ice. Since most of the accumulation area on Tibetan glaciers is within the percolation zone where snow densification is characterized by melting and refreezing, the enrichment of black soot in the snow-pack is of foremost importance. Results suggest the effect of black soot on glacier melting may currently be underestimated. (letter)

  14. Th effectiveness of soot removal techniques for the recovery of fingerprints on glass fire debris in petrol bomb cases

    International Nuclear Information System (INIS)

    Umi Kalthom Ahmad; Mei, Y.S.; Mohd Shahru Bahari; Raramasivam, V.K.

    2011-01-01

    The increased use of petrol bombs as an act of vengeance in Malaysia has heightened awareness for the need of research relating physical evidence found at the crime scene to the perpetrator of the crime. A study was therefore carried out to assess the effectiveness of soot removal techniques on glass fire debris without affecting the fingerprints found on the evidence. Soot was removed using three methods which were brushing, 2 % NaOH solution and tape lifting. Depending on the visibility of prints recovered, prints which were visible after soot removal were lifted directly while prints that were not visible were subjected to enhancement. Glass microscope slides were used in laboratory experiment and subjected to control burn for the formation of soot. Soot was later removed following enhancement of the prints over time (within 1 day, within 2 days and after 2 days). While in simulated petrol bomb ground experiment, petrol bombs were hurled in glass bottles and the fragments were collected. Favorable results were obtained in varying degrees using each soot removal methods. In laboratory testing, brushing and 2 % NaOH solution revealed fingerprints that were visible after removal of excess soot and were lifted directly. As for tape lifting technique, some prints were visible and were successfully lifted while those that were not visible were subjected to super glue fuming for effective fingerprint identification. (author)

  15. Ultra-small-angle X-ray scattering characterization of diesel/gasoline soot: sizes and particle-packing conditions

    Science.gov (United States)

    Kameya, Yuki; Lee, Kyeong O.

    2013-10-01

    Regulations on particulate emissions from internal combustion engines tend to become more stringent, accordingly the importance of particulate filters in the after-treatment system has been increasing. In this work, the applicability of ultra-small-angle X-ray scattering (USAXS) to diesel soot cake and gasoline soot was investigated. Gasoline-direct-injection engine soot was collected at different fuel injection timings. The unified fits method was applied to analyze the resultant scattering curves. The validity of analysis was supported by comparing with carbon black and taking the sample images using a transmission electron microscope, which revealed that the primary particle size ranged from 20 to 55 nm. In addition, the effects of particle-packing conditions on the USAXS measurement were demonstrated by using samples suspended in acetone. Then, the investigation was extended to characterization of diesel soot cake deposited on a diesel particulate filter (DPF). Diesel soot was trapped on a small piece of DPF at different deposition conditions which were specified using the Peclet number. The dependence of scattering curve on soot-deposition conditions was demonstrated. To support the interpretation of the USAXS results, soot cake samples were observed using a scanning electron microscope and the influence of particle-packing conditions on scattering curve was discussed.

  16. Ultra-small-angle X-ray scattering characterization of diesel/gasoline soot: sizes and particle-packing conditions

    International Nuclear Information System (INIS)

    Kameya, Yuki; Lee, Kyeong O.

    2013-01-01

    Regulations on particulate emissions from internal combustion engines tend to become more stringent, accordingly the importance of particulate filters in the after-treatment system has been increasing. In this work, the applicability of ultra-small-angle X-ray scattering (USAXS) to diesel soot cake and gasoline soot was investigated. Gasoline-direct-injection engine soot was collected at different fuel injection timings. The unified fits method was applied to analyze the resultant scattering curves. The validity of analysis was supported by comparing with carbon black and taking the sample images using a transmission electron microscope, which revealed that the primary particle size ranged from 20 to 55 nm. In addition, the effects of particle-packing conditions on the USAXS measurement were demonstrated by using samples suspended in acetone. Then, the investigation was extended to characterization of diesel soot cake deposited on a diesel particulate filter (DPF). Diesel soot was trapped on a small piece of DPF at different deposition conditions which were specified using the Peclet number. The dependence of scattering curve on soot-deposition conditions was demonstrated. To support the interpretation of the USAXS results, soot cake samples were observed using a scanning electron microscope and the influence of particle-packing conditions on scattering curve was discussed

  17. Synthetic fuel combustion: pollutant formation. Soot initiation mechanisms in burning aromatics. First quarterly report, 19 September-31 December 1980

    Energy Technology Data Exchange (ETDEWEB)

    Rawlins, W. T.; Tanzawa, T.

    1981-01-01

    Although considerable progress has been made in recent years in understanding the phenomenology of soot formation in the combustion of hydrocarbon fuels, relatively little attention has been focused upon aromatic fuels of the types commonly found in coal liquids. In particular, the effects of gas-phase free radicals, formed during combustion, on the kinetics of formation of incipient soot particles have not been characterized. Accordingly, an experimental investigation of the detailed kinetics of incipient soot formation in the combustion and pyrolysis of aromatic fuels of the benzene, anisole, phenol, and pyrrole families has been initiated in order to determine soot formation mechanisms and rate parameters. The experiments will be performed in a shock tube over the temperature range 1300 to 2500 K, using multiple ultraviolet, visible, and infrared diagnostics to monitor the kinetic behavior of free radicals (such as OH), incipient soot particles, and combustion products. Experiments will be conducted with artificially enhanced concentrations of free radicals such as OH and O to determine their effects on the kinetics of soot and soot precursors. The experimental work will be supported and directed by a parallel analytical effort using a detailed mechanistic model of the chemical kinetics and dynamics of the reacting systems. In this report, the design and configuration of the experimental apparatus are described, the details of the kinetic model are outlined, and possible reaction pathways are discussed.

  18. Delayed condensation and frost formation on superhydrophobic carbon soot coatings by controlling the presence of hydrophilic active sites

    Science.gov (United States)

    Esmeryan, Karekin D.; Castano, Carlos E.; Mohammadi, Reza; Lazarov, Yuliyan; Radeva, Ekaterina I.

    2018-02-01

    Condensation frosting is an undesired natural phenomenon that could be impeded efficiently using appropriate wettability and morphologically patterned surfaces. The icephobic properties of carbon soot and the fabrication scalability of its synthesis method are a good foundation for anti-frosting applications; however, the fundamentals of frost growth and spreading on sooted surfaces have not been examined yet. In this study, we investigate the anti-frosting performance of three groups of superhydrophobic soot coatings by means of 16 MHz quartz crystal microbalances (QCMs). The analysis of the real-time sensor signal of each soot coated QCM pattern shows that frost formation and its propagation velocity depend on the quantity of oxygen functionalities and structural defects in the material. In turn, the reduction of both parameters shifts the onset of frost growth to temperatures below  -20 °C, whereas the interdroplet ice bridging is slowed by a factor of four. Moreover, high-resolution scanning electron micrographs of the samples imply delamination upon defrosting of the soot with spherical-like morphology via polar interactions driven mechanism. These results reveal an opportunity for control of frost incipiency on sooted surfaces by adjusting the synthesis conditions and depositing soot coatings with as low as possible content of hydrophilic active sites.

  19. Soot, organics, and ultrafine ash from air- and oxy-fired coal combustion

    KAUST Repository

    Andersen, Myrrha E.

    2016-10-19

    Pulverized bituminous coal was burned in a 10. W externally heated entrained flow furnace under air-combustion and three oxy-combustion inlet oxygen conditions (28, 32, and 36%). Experiments were designed to produce flames with practically relevant stoichiometric ratios (SR. =1.2-1.4) and constant residence times (2.3. s). Size-classified fly ash samples were collected, and measurements focused on the soot, elemental carbon (EC), and organic carbon (OC) composition of the total and ultrafine (<0.6. μm) fly ash. Results indicate that although the total fly ash carbon, as measured by loss on ignition, was always acceptably low (<2%) with all three oxy-combustion conditions lower than air-combustion, the ultrafine fly ash for both air-fired and oxy-fired combustion conditions consists primarily of carbonaceous material (50-95%). Carbonaceous components on particles <0.6. μm measured by a thermal optical method showed that large fractions (52-93%) consisted of OC rather than EC, as expected. This observation was supported by thermogravimetric analysis indicating that for the air, 28% oxy, and 32% oxy conditions, 14-71% of this material may be OC volatilizing between 100. C and 550. C with the remaining 29-86% being EC/soot. However, for the 36% oxy condition, OC may comprise over 90% of the ultrafine carbon with a much smaller EC/soot contribution. These data were interpreted by considering the effects of oxy-combustion on flame attachment, ignition delay, and soot oxidation of a bituminous coal, and the effects of these processes on OC and EC emissions. Flame aerodynamics and inlet oxidant composition may influence emissions of organic hazardous air pollutants (HAPs) from a bituminous coal. During oxy-coal combustion, judicious control of inlet oxygen concentration and placement may be used to minimize organic HAP and soot emissions.

  20. Effect of diluents on soot precursor formation and temperature in ethylene laminar diffusion flames

    KAUST Repository

    Abhinavam Kailasanathan, Ranjith Kumar

    2013-03-01

    Soot precursor species concentrations and flame temperature were measured in a diluted laminar co-flow jet diffusion flame at pressures up to eight atmospheres while varying diluent type. The objective of this study was to gain a better understanding of soot production and oxidation mechanisms, which could potentially lead to a reduction in soot emissions from practical combustion devices. Gaseous samples were extracted from the centerline of an ethylene-air laminar diffusion flame, which was diluted individually with four diluents (argon, helium, nitrogen, and carbon dioxide) to manipulate flame temperature and transport properties. The diluted fuel and co-flow exit velocities (top-hat profiles) were matched at all pressures to minimize shear-layer effects, and the mass fluxes were fixed over the pressure range to maintain constant Reynolds number. The flame temperature was measured using a fine gauge R-type thermocouple at pressures up to four atmospheres. Centerline concentration profiles of major non-fuel hydrocarbons collected via extractive sampling with a quartz microprobe and quantification using GC/MS+FID are reported within. The measured hydrocarbon species concentrations are vary dramatically with pressure and diluent, with the helium and carbon dioxide diluted flames yielding the largest and smallest concentrations of soot precursors, respectively. In the case of C2H2 and C6H6, two key soot precursors, helium diluted flames had concentrations more than three times higher compared with the carbon dioxide diluted flame. The peak flame temperature vary with diluents tested, as expected, with carbon dioxide diluted flame being the coolest, with a peak temperature of 1760K at 1atm, and the helium diluted flame being the hottest, with a peak temperature of 2140K. At four atmospheres, the helium diluted flame increased to 2240K, but the CO2 flame temperature increased more, decreasing the difference to approximately 250K. © 2012 The Combustion Institute.