WorldWideScience

Sample records for blue haze enhanced

  1. Enhanced Haze Ratio on Glass by Novel Vapor Texturing Method.

    Science.gov (United States)

    Lee, Seunghwan; Balaji, Nagarajan; Ju, Minkyu; Park, Cheolmin; Kim, Jungmo; Chung, Sungyoun; Lee, Youn-Jung

    2016-05-01

    State-of-the-art optical trapping designs are required to enhance the light trapping capabilities of tandem thin film silicon solar cells. The wet etch process is used to texture the glass surface by dipping in diluted acidic solutions such as HNO3 (nitric acid) and HF (hydrofluoric acid). For vapor texturing, the vapor was generated by adding silicon to HF:HNO3 acidic solution. The anisotropic etching of vapor textured wafers resulted in an etching depth of about 2.78 μm with reduced reflectance of 5%. We achieved a high haze value of 74.6% at a 540 nm wavelength by increasing the etching time and HF concentration. PMID:27483862

  2. Urban heat islands in China enhanced by haze pollution

    Science.gov (United States)

    Cao, Chang; Lee, Xuhui; Liu, Shoudong; Schultz, Natalie; Xiao, Wei; Zhang, Mi; Zhao, Lei

    2016-08-01

    The urban heat island (UHI), the phenomenon of higher temperatures in urban land than the surrounding rural land, is commonly attributed to changes in biophysical properties of the land surface associated with urbanization. Here we provide evidence for a long-held hypothesis that the biogeochemical effect of urban aerosol or haze pollution is also a contributor to the UHI. Our results are based on satellite observations and urban climate model calculations. We find that a significant factor controlling the nighttime surface UHI across China is the urban-rural difference in the haze pollution level. The average haze contribution to the nighttime surface UHI is 0.7+/-0.3 K (mean+/-1 s.e.) for semi-arid cities, which is stronger than that in the humid climate due to a stronger longwave radiative forcing of coarser aerosols. Mitigation of haze pollution therefore provides a co-benefit of reducing heat stress on urban residents.

  3. Urban heat islands in China enhanced by haze pollution.

    Science.gov (United States)

    Cao, Chang; Lee, Xuhui; Liu, Shoudong; Schultz, Natalie; Xiao, Wei; Zhang, Mi; Zhao, Lei

    2016-01-01

    The urban heat island (UHI), the phenomenon of higher temperatures in urban land than the surrounding rural land, is commonly attributed to changes in biophysical properties of the land surface associated with urbanization. Here we provide evidence for a long-held hypothesis that the biogeochemical effect of urban aerosol or haze pollution is also a contributor to the UHI. Our results are based on satellite observations and urban climate model calculations. We find that a significant factor controlling the nighttime surface UHI across China is the urban-rural difference in the haze pollution level. The average haze contribution to the nighttime surface UHI is 0.7±0.3 K (mean±1 s.e.) for semi-arid cities, which is stronger than that in the humid climate due to a stronger longwave radiative forcing of coarser aerosols. Mitigation of haze pollution therefore provides a co-benefit of reducing heat stress on urban residents. PMID:27551987

  4. Urban heat islands in China enhanced by haze pollution.

    Science.gov (United States)

    Cao, Chang; Lee, Xuhui; Liu, Shoudong; Schultz, Natalie; Xiao, Wei; Zhang, Mi; Zhao, Lei

    2016-08-23

    The urban heat island (UHI), the phenomenon of higher temperatures in urban land than the surrounding rural land, is commonly attributed to changes in biophysical properties of the land surface associated with urbanization. Here we provide evidence for a long-held hypothesis that the biogeochemical effect of urban aerosol or haze pollution is also a contributor to the UHI. Our results are based on satellite observations and urban climate model calculations. We find that a significant factor controlling the nighttime surface UHI across China is the urban-rural difference in the haze pollution level. The average haze contribution to the nighttime surface UHI is 0.7±0.3 K (mean±1 s.e.) for semi-arid cities, which is stronger than that in the humid climate due to a stronger longwave radiative forcing of coarser aerosols. Mitigation of haze pollution therefore provides a co-benefit of reducing heat stress on urban residents.

  5. Haze over Beijing

    Science.gov (United States)

    2007-01-01

    Thick haze collected over the Beijing region in late March 2007. Earlier that month, the BBC News reported that an international team of scientists had documented how increasing pollution in China led to decreasing rainfall over the region. The Moderate Resolution Imaging Spectroradiometer (MODIS) flying onboard the Aqua satellite captured these images of the Beijing region on March 22, 2007. The top image is a 'true-color' picture, similar to a digital photo. The bottom, 'false-color,' image uses a combination of visible and infrared light to more clearly show vegetation, water, and clouds. Even sparse vegetation appears bright green, while water appears deep blue (bright blue when tinged with sediment). Clouds dominated by water droplets appear white, while clouds made of ice crystals appear light blue. The false-color image highlights water bodies, perhaps aqua-culture ponds, that are all but invisible in the true-color image, especially along the shores of the Bo Hai. While vegetation and water show up more clearly in the false-color image, haze is much more transparent. Although dingy gray haze dominates the true-color picture, it is all but invisible in the false-color view. The haze 'disappears' in the infrared-enhanced image because tiny haze particles do not reflect longer-wavelength infrared light very well, making this type of image useful for distinguishing haze from clouds. The bank of clouds in the upper right corner shows up clearly in both pictures. As China industrializes, factories, power plants, and automobiles all contribute to pollution in the region. In examining pollutants and rainfall, the team of scientists examined records covering more than 50 years, concluding that pollution decreased precipitation at Mount Hua near Xi'an in central China. They concluded that when conditions are so hazy that visibility is reduced to less than 8 kilometers (5 miles), hilly precipitation can drop by 30 to 50 percent. When moist air passes over mountains

  6. Tapered photonic crystal fibers for blue-enhanced supercontinuum generation

    DEFF Research Database (Denmark)

    Møller, Uffe; Sørensen, Simon Toft; Larsen, Casper;

    2012-01-01

    Tapering of photonic crystal fibers is an effective way of shifting the blue edge of a supercontinuum spectrum down in the deep-blue. We discuss the optimum taper profile for enhancing the power in the blue edge.......Tapering of photonic crystal fibers is an effective way of shifting the blue edge of a supercontinuum spectrum down in the deep-blue. We discuss the optimum taper profile for enhancing the power in the blue edge....

  7. Urban Heat Islands in China Enhanced by Haze Pollution

    Science.gov (United States)

    Cao, C.; Lee, X.; Liu, S.; Oleson, K. W.; Schultz, N. M.; Xiao, W.; Zhang, M.; Zhao, L.

    2015-12-01

    Land conversion from natural surfaces to artificial urban structures has led to the phenomenon of urban heat island (UHI). The intensity of UHI is thought to be controlled primarily by biophysical factors such as changes in albedo, aerodynamic resistance and evapotranspiration, while influences of biogeochemical factors such as aerosol pollution have long been ignored. We hypothesize that increased downward longwave radiation associated with anthropogenic aerosols in urban air will exacerbate nighttime UHI intensity. Here we tested this hypothesis by using the MODIS satellite land surface temperature product and the Community Land Model (CLM) for 39 cities in China. Our results showed that in contrast to observations in North America and elsewhere, nighttime surface UHI of these Chinese cities (3.34 K) was greater than daytime UHI (2.06 K). Variations in the nighttime UHI among the cities were positively correlated with difference in the aerosol optical depth between urban and the adjacent rural area (confidence level p < 0.01). The CLM was able to reproduce the MODIS UHI intensity in the daytime but underestimated the observed UHI intensity at night. The model performance was improved by including an aerosol-enhanced downward longwave radiation in urban land and a more realistic anthropogenic heat flux. Our study illustrates that although climate background largely determine spatial differences in the daytime UHI, in countries like China with serious air quality problems, aerosol-induced pollution plays an important role in the night-time UHI formation. Mitigation of particulate pollution therefore has the added co-benefit by reducing UHI-related heat stress on urban residents.

  8. Titan Haze

    Science.gov (United States)

    Anderson, Carrie M.; West, Robert; Lavvas, Panayotis

    2011-01-01

    The Titan haze exerts a dominating influence on surface visibility and atmospheric radiative heating at optical and near-infrared wavelengths and our desire to understand surface composition and atmospheric dynamics provides a strong motivation to study the properties of the haze. Prior to the Cassini/Huygens missions the haze was known to be global in extent, with a hemispheric contrast asymmetry, with a complicated structure in the polar vortex region poleward of about 55 deg latitude, and with a distinct layer near 370 km altitude outside of the polar vortex at the time of the Voyager 2 flyby. The haze particles measured by the Pioneer and Voyager spacecraft were both highly polarizing and strongly forward scattering, a combination that seems to require an aggregation of small (several tens of nm radius) primary particles. These same properties were seen in the Cassini orbiter and Huygens Probe data. The most extensive set of optical measurements were made inside the atmosphere by the Descent Imager/Spectral Radiometer (DISR) instrument on the Huygens Probe. At the probe location as determined by the DISR measurements the average haze particle contained about 3000 primary particles whose radius is about 40 nm. Three distinct vertical regions were seen in the DISR data with differing particle properties. Refractive indices of the particles in the main haze layer resemble those reported by Khare et al. between O.3S and about 0.7 micron but are more absorbing than the Khare et al. results between 0.7 micron and the long-wavelength limit of the DISR spectra at 1.6 micron. These and other results are described by Tomasko et al., and a broader summary of results was given by Tomasko and West,. New data continue to stream in from the Cassini spacecraft. New data analyses and new laboratory and model results continue to move the field forward. Titan's 'detached' haze layer suffered a dramatic drop in altitude near equinox in 2009 with implications for the circulation

  9. Wintertime haze deterioration in Beijing by industrial pollution deduced from trace metal fingerprints and enhanced health risk by heavy metals.

    Science.gov (United States)

    Lin, Yu-Chi; Hsu, Shih-Chieh; Chou, Charles C-K; Zhang, Renjian; Wu, Yunfei; Kao, Shuh-Ji; Luo, Li; Huang, Chao-Hao; Lin, Shuen-Hsin; Huang, Yi-Tang

    2016-01-01

    Airborne particulate matter (PM) was collected in Beijing between 24 February and 12 March 2014 to investigate chemical characteristics and potential industrial sources of aerosols along with health risk of haze events. Results showed secondary inorganic aerosol was the major contributor to PM2.5 during haze days. Utilizing specific elements, including Fe, La, Tl and As, as fingerprinting tracers, four emission sources, namely iron and steel manufacturing, petroleum refining, cement plant, and coal combustion were explicitly identified; their elevated contributions to PM during haze days were also estimated. The average cancer risk from exposure to inhalable PM toxic metals was 1.53 × 10(-4) on haze days, which is one order of magnitude higher than in other developed cities. These findings suggested heavy industries emit large amounts of not only primary PM but also precursor gas pollutants, leading to secondary aerosol formation and harm to human health during haze days.

  10. Enhanced Deep Blue Aerosol Retrieval Algorithm: The Second Generation

    Science.gov (United States)

    Hsu, N. C.; Jeong, M.-J.; Bettenhausen, C.; Sayer, A. M.; Hansell, R.; Seftor, C. S.; Huang, J.; Tsay, S.-C.

    2013-01-01

    The aerosol products retrieved using the MODIS collection 5.1 Deep Blue algorithm have provided useful information about aerosol properties over bright-reflecting land surfaces, such as desert, semi-arid, and urban regions. However, many components of the C5.1 retrieval algorithm needed to be improved; for example, the use of a static surface database to estimate surface reflectances. This is particularly important over regions of mixed vegetated and non- vegetated surfaces, which may undergo strong seasonal changes in land cover. In order to address this issue, we develop a hybrid approach, which takes advantage of the combination of pre-calculated surface reflectance database and normalized difference vegetation index in determining the surface reflectance for aerosol retrievals. As a result, the spatial coverage of aerosol data generated by the enhanced Deep Blue algorithm has been extended from the arid and semi-arid regions to the entire land areas.

  11. Optimization of Tapered Photonic Crystal Fibers for Blue-Enhanced Supercontinuum Generation

    DEFF Research Database (Denmark)

    Møller, Uffe; Sørensen, Simon Toft; Larsen, Casper;

    2012-01-01

    Tapering of photonic crystal fibers is an effective way of shifting the dispersive wavelength edge of a supercontinuum spectrum down in the deep-blue. We discuss the optimum taper profile for blue-enhanced supercontinuum generation.......Tapering of photonic crystal fibers is an effective way of shifting the dispersive wavelength edge of a supercontinuum spectrum down in the deep-blue. We discuss the optimum taper profile for blue-enhanced supercontinuum generation....

  12. Seagrass restoration enhances "blue carbon" sequestration in coastal waters.

    Directory of Open Access Journals (Sweden)

    Jill T Greiner

    Full Text Available Seagrass meadows are highly productive habitats that provide important ecosystem services in the coastal zone, including carbon and nutrient sequestration. Organic carbon in seagrass sediment, known as "blue carbon," accumulates from both in situ production and sedimentation of particulate carbon from the water column. Using a large-scale restoration (>1700 ha in the Virginia coastal bays as a model system, we evaluated the role of seagrass, Zosteramarina, restoration in carbon storage in sediments of shallow coastal ecosystems. Sediments of replicate seagrass meadows representing different age treatments (as time since seeding: 0, 4, and 10 years, were analyzed for % carbon, % nitrogen, bulk density, organic matter content, and ²¹⁰Pb for dating at 1-cm increments to a depth of 10 cm. Sediment nutrient and organic content, and carbon accumulation rates were higher in 10-year seagrass meadows relative to 4-year and bare sediment. These differences were consistent with higher shoot density in the older meadow. Carbon accumulation rates determined for the 10-year restored seagrass meadows were 36.68 g C m⁻² yr⁻¹. Within 12 years of seeding, the restored seagrass meadows are expected to accumulate carbon at a rate that is comparable to measured ranges in natural seagrass meadows. This the first study to provide evidence of the potential of seagrass habitat restoration to enhance carbon sequestration in the coastal zone.

  13. Optimum PCF tapers for blue-enhanced supercontinuum sources

    DEFF Research Database (Denmark)

    Møller, Uffe Visbech; Sørensen, Simon Toft; Larsen, Casper;

    2012-01-01

    Tapering of photonic crystal fibers has proven to be an effective way of blueshifting the dispersive wavelength edge of a supercontinuum spectrum down in the deep-blue. In this article we will review the state-of-the-art in fiber tapers, and discuss the underlying mechanisms of supercontinuum gen...... and tapered fibers, and we demonstrate that the intensity noise at the spectral edges of the generated supercontinuum is at a constant level independent on the pump power in both tapered and uniform fibers....

  14. Fog and Haze in California's San Joaquin Valley

    Science.gov (United States)

    2001-01-01

    This illustration features images of southern California and southwestern Nevada acquired on January 3, 2001 (Terra orbit 5569), and includes data from three of MISR's nine cameras. The San Joaquin Valley, which comprises the southern extent of California's Central Valley, covers much of the viewed area. Also visible are several of the Channel Islands near the bottom, and Mono and Walker Lakes, which stand out as darker patches near the top center, especially in the vertical and backward oblique images. Near the lower right of each image is the Los Angeles Basin, with the distinctive chevron shape of the Mojave Desert to its north.The Central Valley is a well-irrigated and richly productive agricultural area situated between the Coast Range and the snow-capped Sierra Nevadas. During the winter, the region is noted for its hazy overcasts and a low, thick ground fog known as the Tule. Owing to the effects of the atmosphere on reflected sunlight, dramatic differences in the MISR images are apparent as the angle of view changes. An area of thick, white fog in the San Joaquin Valley is visible in all three of the images. However, the pervasive haze that fills most of the valley is only slightly visible in the vertical view. At the oblique angles, the haze is highly distinguishable against the land surface background, particularly in the forward-viewing direction. Just above image center, the forward view also reveals bluish-tinged plumes near Lava Butte in Sequoia National Forest, where the National Interagency Coordination Center reported an active forest fire.The changing surface visibility in the multi-angle data allows us to derive the amount of atmospheric haze. In the lower right quadrant is a map of haze amount determined from automated processing of the MISR imagery. Low amounts of haze are shown in blue, and a variation in hue through shades of green, yellow, and red indicates progressively larger amounts of airborne particulates. Due to the topographically

  15. Constraints on the Microphysics of Pluto's Photochemical Haze from New Horizons Observations

    CERN Document Server

    Gao, Peter; Wong, Michael L; Liang, Mao-Chang; Shia, Run-Lie; Kammer, Joshua A; Yung, Yuk L; Summers, Michael E; Gladstone, G Randall; Young, Leslie A; Olkin, Catherine B; Ennico, Kimberly; Weaver, Harold A; Stern, S Alan

    2016-01-01

    The New Horizons flyby of Pluto confirmed the existence of hazes in its atmosphere. Observations of a large high- to low- phase brightness ratio, combined with the blue color of the haze, suggest that the haze particles are fractal aggregates, analogous to the photochemical hazes on Titan. Therefore, studying the Pluto hazes can shed light on the similarities and differences between the Pluto and Titan atmospheres. We model the haze distribution using the Community Aerosol and Radiation Model for Atmospheres assuming that the distribution is shaped by sedimentation and coagulation of particles originating from photochemistry. Hazes composed of both purely spherical and purely fractal aggregate particles are considered. Agreement between model results and occultation observations is obtained with aggregate particles when the downward flux of photochemical products is equal to the column-integrated methane destruction rate ~1.2 $\\times$ 10$^{-14}$ g cm$^{-2}$ s$^{-1}$, while for spherical particles the mass flu...

  16. Light harvesting in photonic crystals revisited: why do slow photons at the blue edge enhance absorption?

    Science.gov (United States)

    Deparis, O; Mouchet, S R; Su, B-L

    2015-11-11

    Light harvesting enhancement by slow photons in photonic crystal catalysts or dye-sensitized solar cells is a promising approach for increasing the efficiency of photoreactions. This structural effect is exploited in inverse opal TiO2 photocatalysts by tuning the red edge of the photonic band gap to the TiO2 electronic excitation band edge. In spite of many experimental demonstrations, the slow photon effect is not fully understood yet. In particular, observed enhancement by tuning the blue edge has remained unexplained. Based on rigorous couple wave analysis simulations, we quantify light harvesting enhancement in terms of absorption increase at a specific wavelength (monochromatic UV illumination) or photocurrent increase (solar light illumination), with respect to homogeneous flat slab of equivalent material thickness. We show that the commonly accepted explanation relying on light intensity confinement in high (low) dielectric constant regions at the red (blue) edge is challenged in the case of TiO2 inverse opals because of the sub-wavelength size of the material skeleton. The reason why slow photons at the blue edge are also able to enhance light harvesting is the loose confinement of the field, which leads to significant resonantly enhanced field intensity overlap with the skeleton in both red and blue edge tuning cases, yet with different intensity patterns. PMID:26517229

  17. Green-light supplementation for enhanced lettuce growth under red- and blue-light-emitting diodes

    Science.gov (United States)

    Kim, Hyeon-Hye; Goins, Gregory D.; Wheeler, Raymond M.; Sager, John C.

    2004-01-01

    Plants will be an important component of future long-term space missions. Lighting systems for growing plants will need to be lightweight, reliable, and durable, and light-emitting diodes (LEDs) have these characteristics. Previous studies demonstrated that the combination of red and blue light was an effective light source for several crops. Yet the appearance of plants under red and blue lighting is purplish gray making visual assessment of any problems difficult. The addition of green light would make the plant leave appear green and normal similar to a natural setting under white light and may also offer a psychological benefit to the crew. Green supplemental lighting could also offer benefits, since green light can better penetrate the plant canopy and potentially increase plant growth by increasing photosynthesis from the leaves in the lower canopy. In this study, four light sources were tested: 1) red and blue LEDs (RB), 2) red and blue LEDs with green fluorescent lamps (RGB), 3) green fluorescent lamps (GF), and 4) cool-white fluorescent lamps (CWF), that provided 0%, 24%, 86%, and 51% of the total PPF in the green region of the spectrum, respectively. The addition of 24% green light (500 to 600 nm) to red and blue LEDs (RGB treatment) enhanced plant growth. The RGB treatment plants produced more biomass than the plants grown under the cool-white fluorescent lamps (CWF treatment), a commonly tested light source used as a broad-spectrum control.

  18. Enhanced Photocatalytic Performance of NiO-Decorated ZnO Nanowhiskers for Methylene Blue Degradation

    Directory of Open Access Journals (Sweden)

    I. Abdul Rahman

    2014-01-01

    Full Text Available ZnO nanowhiskers were used for photodecomposition of methylene blue in aqueous solution under UV irradiation. The rate of methylene blue degradation increased linearly with time of UV irradiation. 54% of degradation rate was observed when the ZnO nanowhiskers were used as photocatalysts for methylene blue degradation for 80 min under UV irradiation. The decoration of p-type NiO nanoparticles on n-type ZnO nanowhiskers significantly enhanced photocatalytic activity and reached 72% degradation rate of methylene blue by using the same method. NiO-decorated ZnO was recycled for second test and shows 66% degradation from maximal peak of methylene blue within the same period. The increment of photocatalytic activity of NiO-decorated ZnO nanowhiskers was explained by the extension of the electron depletion layer due to the formation of nanoscale p-n junctions between p-type NiO and n-type ZnO. Hence, these products provide new alternative proficient photocatalysts for wastewater treatment.

  19. Sulfate Formation Enhanced by a Cocktail of High NOx, SO2, Particulate Matter, and Droplet pH during Haze-Fog Events in Megacities in China: An Observation-Based Modeling Investigation.

    Science.gov (United States)

    Xue, Jian; Yuan, Zibing; Griffith, Stephen M; Yu, Xin; Lau, Alexis K H; Yu, Jian Zhen

    2016-07-19

    In recent years in a few Chinese megacities, fog events lasting one to a few days have been frequently associated with high levels of aerosol loading characterized by high sulfate (as high as 30 μg m(-3)), therefore termed as haze-fog events. The concomitant pollution characteristics include high gas-phase mixing ratios of SO2 (up to 71 ppbv) and NO2 (up to 69 ppbv), high aqueous phase pH (5-6), and smaller fog droplets (as low as 2 μm), resulting from intense emissions from fossil fuel combustion and construction activities supplying abundant Ca(2+). In this work, we use an observation-based model for secondary inorganic aerosols (OBM-SIA) to simulate sulfate formation pathways under conditions of haze-fog events encountered in Chinese megacities. The OBM analysis has identified, at a typical haze-fogwater pH of 5.6, the most important pathway to be oxidation of S(IV) by dissolved NO2, followed by the heterogeneous reaction of SO2 on the aerosol surface. The aqueous phase oxidation of S(IV) by H2O2 is a very minor formation pathway as a result of the high NOx conditions suppressing H2O2 formation. The model results indicate that the unique cocktail of high fogwater pH, high concentrations of NO2, SO2, and PM, and small fog droplets are capable of greatly enhancing sulfate formation. Such haze-fog conditions could lead to rapid sulfate production at night and subsequently high PM2.5 in the morning when the fog evaporates. Sulfate formation is simulated to be highly sensitive to fogwater pH, PM, and precursor gases NO2 and SO2. Such insights on major contributing factors imply that reduction of road dust and NOx emissions could lessen PM2.5 loadings in Chinese megacities during fog events. PMID:27331615

  20. Titan-like exoplanets: Variations in geometric albedo and effective transit height with haze production rate

    Science.gov (United States)

    Checlair, Jade; McKay, Christopher P.; Imanaka, Hiroshi

    2016-09-01

    Extensive studies characterizing Titan present an opportunity to study the atmospheric properties of Titan-like exoplanets. Using an existing model of Titan's atmospheric haze, we computed geometric albedo spectra and effective transit height spectra for six values of the haze production rate (zero haze to twice present) over a wide range of wavelengths (0.2-2 μm). In the geometric albedo spectra, the slope in the UV-visible changes from blue to red when varying the haze production rate values from zero to twice the current Titan value. This spectral feature is the most effective way to characterize the haze production rates. Methane absorption bands in the visible-NIR compete with the absorbing haze, being more prominent for smaller haze production rates. The effective transit heights probe a region of the atmosphere where the haze and gas are optically thin and that is thus not effectively probed by the geometric albedo. The effective transit height decreases smoothly with increasing wavelength, from 376 km to 123 km at 0.2 and 2 μm, respectively. When decreasing the haze production rate, the methane absorption bands become more prominent, and the effective transit height decreases with a steeper slope with increasing wavelength. The slope of the geometric albedo in the UV-visible increases smoothly with increasing haze production rate, while the slope of the effective transit height spectra is not sensitive to the haze production rate other than showing a sharp rise when the haze production rate increases from zero. We conclude that geometric albedo spectra provide the most sensitive indicator of the haze production rate and the background Rayleigh gas. Our results suggest that important and complementary information can be obtained from the geometric albedo and motivates improvements in the technology for direct imaging of nearby exoplanets.

  1. Enhanced Training for Cyber Situational Awareness in Red versus Blue Team Exercises

    Energy Technology Data Exchange (ETDEWEB)

    Carbajal, Armida J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Human Factors and Statistics; Stevens-Adams, Susan Marie [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Risk and Reliability Analysis; Silva, Austin Ray [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Cognitive Modeling; Nauer, Kevin S. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Cyber Security Technologies; Anderson, Benjamin Robert [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Assurance Technologies and Assessment; Forsythe, James Chris [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Cognitive Modeling

    2012-09-01

    This report summarizes research conducted through the Sandia National Laboratories Enhanced Training for Cyber Situational Awareness in Red Versus Blue Team Exercises Laboratory Directed Research and Development project. The objective of this project was to advance scientific understanding concerning how to best structure training for cyber defenders. Two modes of training were considered. The baseline training condition (Tool-Based training) was based on current practices where classroom instruction focuses on the functions of a software tool with various exercises in which students apply those functions. In the second training condition (Narrative-Based training), classroom instruction addressed software functions, but in the context of adversary tactics and techniques. It was hypothesized that students receiving narrative-based training would gain a deeper conceptual understanding of the software tools and this would be reflected in better performance within a red versus blue team exercise.

  2. Broken Pledges: The Deadly Rite of Hazing.

    Science.gov (United States)

    Nuwer, Hank

    The practice of hazing in college fraternities, sororities, high school clubs, professional societies, business, the military, and secret societies is investigated. Through the retelling of actual stories involving hazing, the book addresses the questions of why men and women haze and allow themselves to be hazed, how the problems of hazing can be…

  3. Feasibility of Haze Governance Based on Carbon Sink Mode

    Institute of Scientific and Technical Information of China (English)

    Jie; HE; Quanquan; WANG

    2015-01-01

    In recent years,there are research findings of haze formation in various fields of academic circle. It has proved that causes of haze take on diverse characteristics. Thus,from both the natural and human perspective,haze governance should be diverse. Research conclusions on causes of haze formation mainly focus on special geographical structure,and meteorological factors such as relatively stable atmosphere,high rate of calm wind,high relative humidity and temperature of air,and human factors such as industrial pollution,automotive exhaust emissions,aerosol pollution,eutrophication of soil water,and change of city underlying surface. Carbon sink mode is a new channel for haze governance.In carbon sink mode,it is feasible to regulate relative humidity and temperature in air,enhance global wind,and reduce fine particles and microorganisms of air pollution,so as to reduce haze pollution. Besides,China’s special potential of carbon sink market makes it possible to govern haze on the base of carbon sink.

  4. Effectiveness of Alkali-Acid Treatment in Enhancement the Adsorption Capacity for Rice Straw: The Removal of Methylene Blue Dye

    OpenAIRE

    Nady A. Fathy; El-Shafey, Ola I.; Khalil, Laila B.

    2013-01-01

    The effectiveness of alkali-acid modification in enhancement the adsorption capacity of rice straw (RS) for removing a basic dye was studied. The obtained adsorbents were characterized by slurry pH, pHPZC, iodine number, methylene blue number, FTIR, and SEM analyses. Adsorption of methylene blue (MB) was described by the Langmuir, Freundlich, Tempkin, and Redlich-Peterson isotherm models. Effects of contact time, initial concentration of MB dye, pH of solution, adsorbent dose, salt concentrat...

  5. Electroluminescence enhancement in blue phosphorescent organic light-emitting diodes based on different hosts

    Science.gov (United States)

    Zhang, Wei; Zhang, Fang-hui; Huang, Jin; Zhang, Mai-li; Ma, Ying

    2013-09-01

    Blue phosphorescent organic light-emitting diodes (OLEDs) are fabricated by utilizing the hole transport-type host material of 1,3-bis(carbazol-9-yl)benzene (MCP) combined with the electron transport-type host material of 1,3-bis (triphenylsilyl) benzene (UGH3) with the ratios of 1:0, 8:2 and 6:4, and doping with blue phosphorescent dopant of bis(4,6-difluorophenylpyridinato-N,C2)picolinatoiridium (FIrpic). The device with an optimum concentration proportion of MCP:UGH3 of 8:2 exhibits the maximum current efficiency of 19.18 cd/A at luminance of 35.71 cd/m2 with maintaining Commission Internationale de L'Eclairage (CIE) coordinates of (0.1481, 0.2695), which is enhanced by 35.7% compared with that of 1:0 with (0.1498, 0.2738). The improvements are attributed to the effective carrier injection and transport in emitting layer (EML) because of mixed host materials. In addition, electron and exciton are confined in the EML, and 4,4',4″-Tris(carbazol-9-yl)-triphenylamine (TCTA) and Di-[4-(N,N-ditolyl-amino)-phenyl]cyclohexane (TAPC) have the high lowest unoccupied molecular orbital (LUMO) energy level and triplet exiton energy.

  6. High-pressure homogenization associated hydrothermal process of palygorskite for enhanced adsorption of Methylene blue

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Zhifang [Center of Eco-materials and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); University of the Chinese Academy of Sciences, Beijing 100049 (China); Wang, Wenbo [Center of Eco-materials and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); R& D Center of Xuyi Attapulgite Applied Technology, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Xuyi 211700 (China); Wang, Aiqin, E-mail: aqwang@licp.cas.cn [Center of Eco-materials and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); R& D Center of Xuyi Attapulgite Applied Technology, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Xuyi 211700 (China)

    2015-02-28

    Graphical abstract: - Highlights: • Palygorskite was modified by a homogenization associated hydrothermal process. • The crystal bundles of PAL were disaggregated efficiently after modification. • The adsorption of palygorskite for Methylene blue was greatly enhanced. • MB-loaded palygorskite exhibits excellent resistance to acid and alkali solution. - Abstract: Palygorskite (PAL) was modified by a high-pressure homogenization assisted hydrothermal process. The effects of modification on the morphology, structure and physicochemical properties of PAL were systematically investigated by Field-emission scanning electron microscopy (FESEM), Transmission electron microscopy (TEM), Fourier transform infrared spectrometry (FTIR), Brunauer–Emmett–Teller (BET) analysis, X-ray diffraction (XRD) and Zeta potential analysis techniques, and the adsorption properties were systematically evaluated using Methylene blue (MB) as the model dye. The results revealed that the crystal bundles were disaggregated and the PAL nanorods became more even after treated via associated high-pressure homogenization and hydrothermal process, and the crystal bundles were dispersed as nanorods. The intrinsic crystal structure of PAL was remained after hydrothermal treatment, and the pore size calculated by the BET method was increased. The adsorption properties of PAL for MB were evidently improved (from 119 mg/g to 171 mg/g) after modification, and the dispersion of PAL before hydrothermal reaction is favorable to the adsorption. The desorption evaluation confirms that the modified PAL has stronger affinity with MB, which is benefit to fabricate a stable organic–inorganic hybrid pigment.

  7. Magnetic enhancement of photoluminescence from blue-luminescent graphene quantum dots

    Science.gov (United States)

    Chen, Qi; Shi, Chentian; Zhang, Chunfeng; Pu, Songyang; Wang, Rui; Wu, Xuewei; Wang, Xiaoyong; Xue, Fei; Pan, Dengyu; Xiao, Min

    2016-02-01

    Graphene quantum-dots (GQDs) have been predicted and demonstrated with fascinating optical and magnetic properties. However, the magnetic effect on the optical properties remains experimentally unexplored. Here, we conduct a magneto-photoluminescence study on the blue-luminescence GQDs at cryogenic temperatures with magnetic field up to 10 T. When the magnetic field is applied, a remarkable enhancement of photoluminescence emission has been observed together with an insignificant change in circular polarization. The results have been well explained by the scenario of magnetic-field-controlled singlet-triplet mixing in GQDs owing to the Zeeman splitting of triplet states, which is further verified by temperature-dependent experiments. This work uncovers the pivotal role of intersystem crossing in GQDs, which is instrumental for their potential applications such as light-emitting diodes, photodynamic therapy, and spintronic devices.

  8. Microstructure and blue photoluminescence enhancement of silicon nanoporous pillar array embedded in ferroelectric barium strontium titanate

    International Nuclear Information System (INIS)

    A silicon nanoporous pillar array (Si-NPA) with micrometer/nanometer hierarchical structure was fabricated by hydrothermal etching, followed by spin-coating barium strontium titanate (BST) on Si-NPA substrate. The photoluminescence (PL) spectra of the Si-NPA and BST/Si-NPA thin film were investigated. The emission band of freshly prepared Si-NPA located at ∼630 nm, and a blueshift at ∼425 nm as well as degradation in intensity after annealing at 600 deg. C for 1 h was observed, which might be explained by a quantum confinement effect model. BST ferroelectric material provided a static-electric field and induced the excited carriers in Si-NPA to migrate toward the opposite direction and recombine in an interfacial oxide layer. Therefore, BST enhanced blue emission of Si-NPA as well as passivated Si-NPA

  9. Enhanced blue light emission in transparent ZnO:PVA nanocomposite free standing polymer films

    Science.gov (United States)

    Karthikeyan, B.; Pandiyarajan, T.; Mangalaraja, R. V.

    2016-01-01

    ZnO:PVA nanocomposite films were prepared and their fluorescence and time resolved photoluminescence properties were discussed. X-ray diffraction and infrared spectroscopy results confirmed the ZnO:PVA interaction. Optical absorption spectra showed two bands at 280 and 367 nm which were ascribed to PVA and excitonic absorption band, respectively. Fluorescence spectra showed that the blue emission of ZnO was enhanced about tenfold through chemical interface electron transfer. The electron transfer from ZnO to PVA and its decay dynamics were experimentally analyzed through time resolved fluorescence measurements. The study revealed that the excited electrons found pathway through PVA to ground state which was slower than the pure ZnO nanoparticles.

  10. Blue-enhanced supercontinuum generation pumped by a giant-chirped SESAM mode-locked fiber laser

    Science.gov (United States)

    Gao, Shoufei; Wang, Yingying; Sun, Ruoyu; Jin, Dongchen; Liu, Jiang; Wang, Pu

    2016-08-01

    We report on a blue-enhanced supercontinuum generation pumped by a giant-chirped SESAM mode-locked 1064-nm fiber laser, in which the giant chirp is introduced by a piece of 3.5-km single-mode fiber outside of the cavity. The giant-chirped pump source with 2.2-nm spectral bandwidth and 186-ps pulse width is used to enhance dispersive waves generation in blue wavelength. An extremely wide optical spectrum with a broad 3-dB spectral bandwidth of 311 nm (from 446 to 757 nm) and a maximum spectral power density of 4 mW/nm at 464 nm is obtained.

  11. Kinetic Modeling for Microwave-Enhanced Degradation of Methylene Blue Using Manganese Oxide

    Directory of Open Access Journals (Sweden)

    Wen-Hui Kuan

    2013-01-01

    Full Text Available This study was originally performed to compare the MnO2-based degradation of aqueous methylene blue (MB under microwave irradiation- (MW- enhanced and conventional heating- (CH- enhanced conditions. The degradation process and kinetics were investigated to elucidate the microwave effect on the reaction. The results showed that all three tested conditions, sole MnO2, MnO2/CH, and MnO2/MW, followed the third-order (second upon MB and first upon MnO2 kinetic model. However, a higher degradation rate of MB was available under the MW-enhanced process, which implies that the “athermal effect” of MW might be of more benefit for the generation of electrophilic oxygen ions (, , and to degrade MB. The results showed that the degradation percentage of MB could reach 100%, corresponding to 92% total organic carbon (TOC removal under microwave irradiation at pH 7.20 for 10 min.

  12. Potential for use of methylene blue index testing to enhance geotechnical characterization of oil sands ores and tailings

    Energy Technology Data Exchange (ETDEWEB)

    Boxill, Lois [SRK Consulting (Canada)

    2011-07-01

    At the CONRAD conference held in Edmonton in 2011, clay scientist expressed their concern over the variability of clay structures and its impact both on oil sands ores and on tailings. This paper discusses the potential for using methylene blue index testing to enhance geotechnical understanding of the impact of the cation exchange capacity of clay present in oil sands ores and both solid and fluid components of the tailings stream. A description of the methylene blue index test procedure is provided. This process is most commonly used for characterization in the oil sands industry. The requirements for obtaining consistency in the test results are discussed. The test is often used to enhance geotechnical characterization of clays in other areas. The potential for developing correlations between methylene blue index test results and other geotechnical parameters is also discussed. It can be concluded from the study that geotechnical data on soil indicate the effect of clay minerals on the overall plasticity of the soil.

  13. Did the widespread haze pollution over China increase during the last decade? A satellite view from space

    Science.gov (United States)

    Tao, Minghui; Chen, Liangfu; Wang, Zifeng; Wang, Jun; Tao, Jinhua; Wang, Xinhui

    2016-05-01

    Widespread haze layers usually cover China like low clouds, exerting marked influence on air quality and regional climate. With recent Collection 6 MODIS Deep Blue aerosol data in 2000–2015, we analyzed the trends of regional haze pollution and the corresponding influence of atmospheric circulation in China. Satellite observations show that regional haze pollution is mainly concentrated in northern and central China. The annual frequency of regional haze in northern China nearly doubles between 2000 and 2006, increasing from 30–50 to 80–90 days. Though there is a marked decrease in annual frequency during 2007–2009 due to both reduction of anthropogenic emissions and changes of meteorological conditions, regional pollution increases slowly but steadily after 2009, and maintains at a high level of 70–90 days except for the sudden decrease in 2015. Generally, there is a large increase in the number of regional-scale haze events during the last decade. Seasonal frequency of regional haze exhibits distinct spatial and temporal variations. The increasing winter haze events reach a peak in 2014, but decrease strongly in 2015 due partly to synoptic conditions that are favorable for dispersion. Trends of summer regional haze pollution are more sensitive to changes of atmospheric circulation. Our results indicate that the frequency of regional haze events is associated not only with the strength of atmospheric circulation, but also with its direction and position, as well as variations in anthropogenic emissions.

  14. Efficiency of Blue Organic Light-emitting Diodes Enhanced by Employing an Exciton Feedback Layer

    Institute of Scientific and Technical Information of China (English)

    Qian-Qian Yu; Xu Zhang; Jing-Xuan Bi; Guan-Ting Liu; Qi-Wen Zhang; Xiao-Ming Wu; Yu-Lin Hua

    2016-01-01

    We report that a novel exciton feedback effect is observed by introducing the bis(2-methyl-8-quinolinolato)(4-phenylphenolato)aluminum (BAlq) inserted between the emitting layer (EML) and the electron transporting layer in blue organic light emitting diodes.As an exciton feedback layer (EFL),the BAlq does not act as a traditional hole blocking effect.The design of this kind of device structure can greatly reduce excitons' quenching due to accumulated space charge at the exciton formation interface.Meanwhile,the non-radiative energy transfer from EFL to the EML can also be utilized to enhance the excitons' formation,which is confirmed by the test of photolumimescent transient lifetime decay and electroluminescence enhancement of these devices.Accordingly,the optimal device presents the improved performances with the maximum current e~ciency of 4.2 cd/A and the luminance of 24600cd/m2,which are about 1.45 times and 1.75 times higher than those of device A (control device) without the EFL,respectively.Simultaneously,the device shows an excellent color stability with a tiny offset of the CIE coordinates (Ax =±0.003,Ay =±0.004) and a relatively lower efficiency roll-off of 26.2% under the driving voltage varying from 3 V to 10 V.

  15. Enhanced photodynamic therapy efficacy of methylene blue-loaded calcium phosphate nanoparticles.

    Science.gov (United States)

    Seong, Da-Young; Kim, Young-Jin

    2015-05-01

    Although methylene blue (MB) is the most inexpensive photosensitizer with promising applications in the photodynamic therapy (PDT) for its high quantum yield of singlet oxygen generation, the clinical use of MB has been limited by its rapid enzymatic reduction in the biological environment. To enhance PDT efficacy of MB by preventing the enzymatic reduction, we have developed a new mineralization method to produce highly biocompatible MB-loaded calcium phosphate (CaP-MB) nanoparticles in the presence of polymer templates. The resulting CaP-MB nanoparticles exhibited spherical shape with a size of under 50 nm. Fourier transform infrared (FT-IR) and zeta-potential analyses confirmed the insertion of MB into the CaP-MB nanoparticles. The encapsulation of MB in CaP nanoparticles could effectively protect MB from the enzymatic reduction. In addition, the CaP-MB nanoparticles exhibited a good biocompatibility in the dark condition and significantly enhanced PDT efficacy due to apoptotic cell death against human breast cancer cells as compared with free MB, implying that CaP-MB nanoparticle system might be potentially applicable in PDT.

  16. Micellar-enhanced ultrafiltration of cadmium and methylene blue in synthetic wastewater using SDS

    International Nuclear Information System (INIS)

    Single and simultaneous removal of Cd2+ and methylene blue (MB) with sodium dodecyl sulfate (SDS) by micellar-enhanced ultrafiltration under different experimental conditions was investigated. In single removal process, with initial SDS concentration increasing, the removal efficiency of Cd2+ and MB kept increasing and then decreased. When the initial concentrations of SDS and Cd2+ were 1.0 cmc and 50 mg L-1, respectively, the maximum removal efficiency of Cd2+ was obtained as 99.2%. Removal efficiency of MB could achieve more than 99.9% with initial SDS concentration below 2.0 cmc. As compared with single Cd2+ removal, the removal efficiency of Cd2+ in the presence of MB was slightly higher with initial SDS concentration below 1.0 cmc, while decreased with the SDS concentration above 1.0 cmc. The maximum removal efficiency of Cd2+ was 98.8% when initial concentrations of SDS and MB were 1.0 cmc and 4 mg L-1, respectively. The removal efficiency of MB in the presence of Cd2+ could achieve higher than 96.5%, which was only 3.4% less than the optimum result of the single removal. Meanwhile, effect of pH on removal efficiency of Cd2+ was more significant than that of MB.

  17. Methylene blue-mediated photodynamic therapy enhances apoptosis in lung cancer cells.

    Science.gov (United States)

    Lim, Eun Jin; Oak, Chul-Ho; Heo, Jeonghoon; Kim, Young-Ho

    2013-08-01

    Combined treatment with a photosensitizer and iodide laser [photodynamic therapy (PDT)] has improved the outcome of various cancers. In this study, we investigated the effects of using the photosensitizer methylene blue (MB) in PDT in human lung adenocarcinoma cells. We found that MB enhances PDT-induced apoptosis in association with downregulation of anti-apoptotic proteins, reduced mitochondrial membrane potential (MMP), increased phosphorylation of the mitogen-activated protein kinase (MAPK) and the generation of reactive oxygen species (ROS). In MB-PDT-treated A549 cells, we observed PARP cleavage, procaspase-3 activation, downregulation of the anti-apoptotic proteins Bcl-2 and Mcl-1, and the reduction of mitochondrial membrane potential (MMP). Western blot data showed that phosphorylation of p38 was increased in MB-PDT-treated A549 cells, indicating that several signaling molecules participate in the apoptotic cascade. Our data also showed that apoptotic cell death in MB-PDT-treated cells occurred through a series of steps beginning with the photochemical generation of ROS. Demonstrating the role of ROS, pretreatment of A549 cells with the antioxidant N-acetylcysteine (NAC) followed by MB-PDT resulted in increased cell viability and reduced proteolytic cleavage of PARP.

  18. Comparative evaluation of methylene blue and demeclocycline for enhancing optical contrast of gliomas in optical images

    Science.gov (United States)

    Wirth, Dennis; Snuderl, Matija; Curry, William; Yaroslavsky, Anna

    2014-09-01

    Contrast agents have shown to be useful in the detection of cancers. The goal of this study was to compare enhancement of brain cancer contrast using reflectance and fluorescence confocal imaging of two fluorophores, methylene blue (MB) and demeclocycline (DMN). MB absorbs light in the red spectral range and fluoresces in the near-infrared. It is safe for in vivo staining of human skin and breast tissue. However, its safety for staining human brain is questionable. Thus, DMN, which absorbs light in the violet spectral range and fluoresces between 470 and 570 nm, could provide a safer alternative to MB. Fresh human gliomas, obtained from surgeries, were cut in half and stained with aqueous solutions of MB and DMN, respectively. Stained tissues were imaged using multimodal confocal microscopy. Resulting reflectance and fluorescence optical images were compared with hematoxylin and eosin histopathology, processed from each imaged tissue. Results indicate that images of tissues stained with either stain exhibit comparable contrast and resolution of morphological detail. Further studies are required to establish the safety and efficacy of these contrast agents for use in human brain.

  19. Comparative evaluation of methylene blue and demeclocycline for enhancing optical contrast of brain neoplasms

    Science.gov (United States)

    Wirth, Dennis J.

    Brain tumors cause significant morbidity and mortality even when benign. Completeness of resection of brain tumors has been associated with better quality of life. However, that is often difficult to accomplish. The goal of this study was to evaluate the feasibility of using contrast enhanced multimodal confocal imaging for intraoperative detection of brain neoplasms. Different types of benign and malignant, primary and metastatic brain tumors, stained with Methylene Blue (MB) as a contrast agent, were imaged. MB is a traditional histopathologic stain that absorbs light in the red spectral range and fluoresces in the near infrared. It is FDA-approved for in vivo staining of human skin and breast tissue. Optical images showed good correlation with histopathology, demonstrating the potential of contrast enhanced multimodal confocal imaging for intraoperative detection of brain neoplasms ex vivo. However, the safety of MB for staining human brain in vivo is questionable. Demeclocycline (DMN), an antibiotic of the tetracycline family, has shown to be effective in differentiating normal from cancerous tissue in various organs. DMN is a fluorophore, which absorbs light in the violet spectral range and has a broad emission band covering green and yellow wavelengths. It is commonly used to treat infection and inflammatory disorders, and could provide a safer alternative to MB. To test this hypothesis, fresh excess human brain tissues were bisected and stained with aqueous solutions of either MB or DMN and then imaged. Reflectance and fluorescence images acquired from tissues stained with the two dyes were compared, and correlated with processed H&E histopathology. Comparison showed similar staining patterns and contrast of diagnostic features in glioblastomas, stained using either MB or DMN. The results show potential of both MB and DMN for the intraoperative detection of microscopic nests of brain neoplasms. Further studies will establish safety and efficacy of these

  20. Evidence from action and fluorescence spectra that UV-induced violet-blue-green fluorescence enhances leaf photosynthesis.

    Science.gov (United States)

    Mantha, S V; Johnson, G A; Day, T A

    2001-03-01

    We assessed the contribution of UV-induced violet-blue-green leaf fluorescence to photosynthesis in Poa annua, Sorghum halepense and Nerium oleander by measuring UV-induced fluorescence spectra (280-380 nm excitation, 400-550 nm emission) from leaf surfaces and determining the monochromatic UV action spectra for leaf photosynthetic O2-evolution. Peak fluorescence emission wavelengths from leaf surfaces ranged from violet (408 nm) to blue (448 nm), while excitation peaks for these maxima ranged from 333 to 344 nm. Action spectra were developed by supplementing monochromatic radiation from 280 to 440 nm, in 20 nm increments, to a visible nonsaturating background of 500 mumol m-2 s-1 photosynthetically active radiation and measuring photosynthetic O2-evolution rates. Photosynthetic rates tended to be higher with the 340 nm supplement than with higher or lower wavelength UV supplements. Comparing photosynthetic rates with the 340 nm supplement to those with the 400 nm supplement, the percentage enhancement in photosynthetic rates at 340 nm ranged from 7.8 to 9.8%. We suspect that 340 nm UV improves photosynthetic rates via fluorescence that provides violet-blue-green photons for photosynthetic energy conversion because (1) the peak excitation wavelength (340 nm) for violet-blue-green fluorescence from leaves was also the most effective UV wavelength at enhancing photosynthetic rates, and (2) the magnitude of photosynthetic enhancements attributable to supplemental 340 nm UV was well correlated (R2 = 0.90) with the apparent intensity of 340 nm UV-induced violet-blue-green fluorescence emission from leaves.

  1. A new method of satellite-based haze aerosol monitoring over the North China Plain and a comparison with MODIS Collection 6 aerosol products

    Science.gov (United States)

    Yan, Xing; Shi, Wenzhong; Luo, Nana; Zhao, Wenji

    2016-05-01

    With worldwide urbanization, hazy weather has been increasingly frequent, especially in the North China Plain. However, haze aerosol monitoring remains a challenge. In this paper, MODerate resolution Imaging Spectroradiometer (MODIS) measurements were used to develop an enhanced haze aerosol retrieval algorithm (EHARA). This method can work not only on hazy days but also on normal weather days. Based on 12-year (2002-2014) Aerosol Robotic Network (AERONET) aerosol property data, empirical single scattering albedo (SSA) and asymmetry factor (AF) values were chosen to assist haze aerosol retrieval. For validation, EHARA aerosol optical thickness (AOT) values, along with MODIS Collection 6 (C6) dark-pixel and deep blue aerosol products, were compared with AERONET data. The results show that the EHARA can achieve greater AOT spatial coverage under hazy conditions with a high accuracy (73% within error range) and work a higher resolution (1-km). Additionally, this paper presents a comprehensive discussion of the differences between and limitations of the EHARA and the MODIS C6 DT land algorithms.

  2. Magnetic field assisted Fenton reactions for the enhanced degradation of methyl blue

    Institute of Scientific and Technical Information of China (English)

    Xiao Long Hao; Lu Yi Zou; Guang Sheng Zhang; Yi Bo Zhang

    2009-01-01

    Magnetic field was tentatively introduced into Fenton reactions system for the degradation and discoloration of methyl blue as the represent of organic chemical dye, which was a bio-refractory organic pollutant in industry wastewater. It was found that under optimal Fenton reaction conditions, with the assistant of magnetic field in Fenton reactions, the degradation rate of methyl blue, the decomposition rate of H2O2 and the conversion rate of Fe2+ were accelerated, the extent of them would be improved by the increase of magnetic field intensity. Meanwhile, the mineralization of methyl blue (CODcr) was improved by over 10% with magnetic fiold.

  3. Concentrations and chemical compositions of fine particles (PM2.5) during haze and non-haze days in Beijing

    Science.gov (United States)

    Zhang, Yang; Huang, Wei; Cai, Tianqi; Fang, Dongqing; Wang, Yuqin; Song, Jian; Hu, Min; Zhang, Yuanxun

    2016-06-01

    To investigate the chemical properties of PM2.5 and put forward reasonable control measures, daily samples of PM2.5 were collected at an urban site in Beijing from August 4 to September 3 of 2012 using two 2-channel samplers. Chemical analysis was conducted for eight water soluble inorganic ions (WSII, including Na+, NH4+, K+, Mg2 +, Ca2 +, Cl-, NO3-, and SO42 -), organic carbon (OC) and elementary carbon (EC). PM2.5 concentrations ranged from 8.8 to 218.6 μg m- 3, with an average concentration of 80.6 ± 57.3 μg m- 3. WSII, the most dominant PM2.5 constituents contributing 60 ± 18% of its mass, ranged from 3.1 to 172.2 μg m- 3. SO42 -, NO3-, and NH4+ dominated WSII (90 ± 28%) and their concentrations were 1.3-105.7 μg m- 3, 0.5-52.7 μg m- 3 and 0.3-33.5 μg m- 3, respectively. The concentrations of OC and EC were 3.0-28.8 μgC m- 3 and 0.8-7.4 μgC m- 3, constituting 17.6% and 4.9% of PM2.5, respectively. Three serious pollution episodes (haze days) occurred during the campaign. PM2.5 and its chemical species showed substantial increases during haze episodes. The greater enhancement factors for SO42 - (4.5), NO3- (4.0), and NH4+ (4.2) during haze days compared to non-haze days were obtained, suggesting that these secondary inorganic ions play important roles in the formation of haze. The average ratio of NO3-/SO42 - was 0.52. Ion balance calculations showed that PM2.5 samples were acidic during haze periods and close to neutral during non-haze days. Correlation analysis between the major ions was conducted and the results suggested that the main forms of NH4+ might be (NH4)2SO4. In addition, the variations between haze days and non-haze days for OC, EC, and the ratio of OC/EC were discussed.

  4. Enhancement of the blue photoluminescence intensity for the porous silicon with HfO2 filling into microcavities.

    Science.gov (United States)

    Jiang, Ran; Du, Xianghao; Sun, Weideng; Han, Zuyin; Wu, Zhengran

    2015-01-01

    With HfO2 filled into the microcavities of the porous single-crystal silicon, the blue photoluminescence was greatly enhanced at room temperature. On one hand, HfO2 contributes to the light emission with the transitions of the defect levels for oxygen vacancy. On the other hand, the special filling-into-microcavities structure of HfO2 leads to the presence of ferroelectricity, which greatly enhances the blue emission from porous silicon. Since both HfO2 and Si are highly compatible with Si-based electronic industry, combined the low-cost and convenient process, the HfO2-filled porous Si shows a promising application prospect. PMID:26503804

  5. The disappearance and reappearance of Titan's detached haze layer

    Science.gov (United States)

    West, Robert; Rannou, Pascal; Lavvas, Panayotis; Seignovert, Benoit; Turtle, Elizabeth P.; Perry, Jason; Ovanessian, Aida; Roy, Mou

    2016-10-01

    Titan's extended haze is a prominent and long-lived feature of the atmosphere that encompasses a rich variety of chemical, dynamical and microphysical processes operating over a wide range of temporal and spatial scales. The so-called 'detached' haze layer is easily seen in high-resolution short-wave (near-UV and blue wavelengths) images and is a consequence of a nearly global (outside of the winter polar hood region) layer depleted in aerosol content. It was first seen near 350 Km altitude in Voyager images (Rages and Pollack, 1983) and later observed by the Cassini ISS cameras (Porco et al., 2005; West et al., 2010) and UV stellar occultation profiles (Koskinen et al. 2011). A series of Cassini images from 2009 to 2010 revealed what appears to be a seasonally related altitude variation with remarkable regularity (comparing the Voyager and Cassini images). The drop in altitude is most rapid at equinox. Here we report on images of the upper haze layer over the period 2012 to early 2016. In the early part of this period the detached haze continued to drop in altitude and disappeared. There was no evidence for it beginning late in 2012 and extending to early 2016 when it was again detected with very low contrast at an altitude near 500 Km. We document this behavior and examine the evolution of the haze as functions of both latitude and time. These new details put additional constraints on models that attempt to account for the existence of the detached layer. Part of this work was done by the Jet Propulsion Laboratory, California Institute of Technology. References: Rages, K., and J. B. Pollack (1983), Vertical distribution of scattering hazes in Titan's upper atmosphere, Icarus, 55, 50–62, doi:10.1016/0019-1035 (83)90049-0; Porco, C. C. et al., Imaging Titan from the Cassini Spacecraft, Nature 434, 159-168 (2005); West, R. A. et al., The evolution of Titans detached haze layer near equinox in 2009", Geophys. Res. Lett. 38, L06204, doi:10.1029/2011GL046843, 2011

  6. Facile synthesis and step by step enhancement of blue photoluminescence from Ag-doped ZnS quantum dots

    OpenAIRE

    Sahai, Sonal; Husain, Mushahid; Shanker, Virendra; Singh, Nahar; Haranath, D.

    2012-01-01

    Our results pertaining to the step by step enhancement of photoluminescence (PL) intensity from ZnS:Ag,Al quantum dots (QDs) are presented. Initially, these QDs were synthesized using a simple co-precipitation technique involving a surfactant, polyvinylpyrrolidone (PVP), in de-ionised water. It was observed that the blue PL originated from ZnS:Ag,Al QDs was considerably weak and not suitable for any practical display application. Upon UV (365 nm) photolysis, the PL intensity augmented to ~170...

  7. Analysis of the formation of fog and haze in North China Plain (NCP

    Directory of Open Access Journals (Sweden)

    J. Quan

    2011-04-01

    Full Text Available North China Plain (NCP is one of the most populated and polluted regions in China. During the recent years, haze and fog occur frequently and cause severely low visibility in this region. In order to better understand the impact of aerosol particles on the formation of haze and fog, a long-term record of haze and fog occurrences in the past 56 years (from 1954–2009 over NCP is analyzed. The results show that there are rapid changes in the occurrences of haze and fog over NCP. The occurrences of haze and fog were low during 1970–1980, and reached a maximum during 1981–1998. After 1999, the occurrences of haze and fog slightly decreased. There was a nonlinear relationship between the occurrences of haze and fog. When the occurrence of haze was lower than 40 days yr−1, the occurrence of fog was strongly proportional to the occurrence of haze. However, when the occurrence of haze was high (larger than 75 days yr−1, the occurrence of fog was not sensitive to the occurrence of haze. In order to better understand the relationship between the occurrences of haze and fog as well as the effect of aerosol particles on the formation of haze and fog, an in-situ field experiment was conducted during a period with a mixed occurrence of haze and fog. The analysis of the experiment suggests that there were considerably high aerosol concentrations during the measurement period, with an averaged aerosol number concentration of 24 000 cm−3. The measurement also shows that a large amount of aerosol particles can act as condensation nuclei to enhance the formation of fog droplets. As a result, a large amount of fog droplets (>1000 cm−3 with small size in radius (5–6 μm were observed during the fog period, resulting in extremely low visibility (less than 100 m.

  8. Enhanced training for cyber situational awareness in Red versus Blue Team Exercises.

    Energy Technology Data Exchange (ETDEWEB)

    Carbajal, Armida J.; Stevens-Adams, Susan Marie; Silva, Austin Ray; Nauer, Kevin S.; Anderson, Benjamin Robert; Forsythe, James Chris

    2012-09-01

    This report summarizes research conducted through the Sandia National Laboratories Enhanced Training for Cyber Situational Awareness in Red Versus Blue Team Exercises Laboratory Directed Research and Development project. The objective of this project was to advance scientific understanding concerning how to best structure training for cyber defenders. Two modes of training were considered. The baseline training condition (Tool-Based training) was based on current practices where classroom instruction focuses on the functions of a software tool with various exercises in which students apply those functions. In the second training condition (Narrative-Based training), classroom instruction addressed software functions, but in the context of adversary tactics and techniques. It was hypothesized that students receiving narrative-based training would gain a deeper conceptual understanding of the software tools and this would be reflected in better performance within a red versus blue team exercise. A study was conducted in which participants (students) received either tool-based or narrative-based training. Following classroom training, three teams were formed to compete in an exercise requiring they use the selected software tools to solve various challenges associated with threats to network security. For this study, training focused on a set of software tools selected because they represented commonly used tools within operational cyber settings. The three teams were: (1) Tool-Based, for which each participant received tool-based training; (2) Narrative-Based, for which each participant received narrative-based training and (3) Combined, for which two participants received tool-based training and two received narrative-based training. Statistical comparison of team performance did not reveal significant differences between the three teams, although this was not unexpected given the small number of participants. However, when each team was asked to provide their

  9. Wintertime Haze Formation in Beijing

    Science.gov (United States)

    Levy Zamora, M. E.

    2015-12-01

    Recent severe haze events in China have attracted significant public attention due to the severely reduced visibility and unprecedentedly high pollutant concentrations. Particular attention has been given to the high concentrations of particulate matter with a diameter less than 2.5 microns (PM2.5), which can exceed several hundred micrograms per cubic meter over several days. During January and February of 2015, a suite of aerosol instruments was deployed in Beijing to directly measure a comprehensive set of aerosol properties, including the particle size distribution, effective density, and chemical composition. In this presentation, we will discuss the particulate matter formation mechanisms, the evolution of aerosol properties throughout the event, and how the winter formation mechanisms compare with the warmer seasons. We show that the periodic cycles of severe haze episodes in Beijing are largely driven by meteorological conditions. During haze events, stagnation typically develops as a result of a low planetary boundary layer and weak southerly wind from polluted industrial source regions. Stronger northerly winds were frequently observed during the clean period, which carry unpolluted air masses from the less populated northern mountainous areas. Nucleation consistently occurs on clean days, producing a high number concentration of nano particles. The particle mass concentration exceeding several hundred micrograms per cubic meter is attributed to the continuous size growth from the nucleation-mode particles (diameter less than 10 nm) over multiple days to produce a high concentration of larger particles (diameter greater than 100 nm). The particle chemical composition in Beijing is similar to those commonly measured in other urban centers, which is indicative of chemical constituents dominated by secondary aerosol formation. Our results reveal that the severe haze formation in Beijing during the wintertime is similar to the mechanism of haze formation

  10. Seagrass Restoration EnhancesBlue Carbon” Sequestration in Coastal Waters

    OpenAIRE

    Jill T Greiner; Karen J McGlathery; John Gunnell; McKee, Brent A.

    2013-01-01

    Seagrass meadows are highly productive habitats that provide important ecosystem services in the coastal zone, including carbon and nutrient sequestration. Organic carbon in seagrass sediment, known as “blue carbon,” accumulates from both in situ production and sedimentation of particulate carbon from the water column. Using a large-scale restoration (>1700 ha) in the Virginia coastal bays as a model system, we evaluated the role of seagrass, Zostera marina , restoration in carbon storage in ...

  11. Reticle haze: an industrial approach

    Science.gov (United States)

    Gough, Stuart; Gérard, Xavier; Bichebois, Pascal; Roche, Agnès; Sundermann, Frank; Guyader, Véronique; Bièron, Yann; Galvier, Jean; Nicoleau, Serge

    2007-02-01

    Crystal growth on advanced reticles is currently a world wide industrial problem in high end semiconductor production environment, crystals are mainly found on reticles that use high energy photons at 193nm wavelength. The most common crystals to be found on masks are ammonium sulphate, a combination of sulphate, from maskshop residues after clean, pellicle materials and storage conditions and amines from clean room, tool and storage environments. High energy photons act as a catalyst to form crystals on both the pattern side as well as the backglass surface. After a number of exposures crystals can grow in size and eventually become printable. In order to detect HAZE before critical dimensions have been reached suitable detection methods need to be implemented to ensure image integrity. These detection methods are different and complementary depending on the surface to be inspected. Once crystals have started growing, the only method to regain mask quality is to clean the mask at the manufacturers site. This brings with it several undesirable situations, not only is the mask unavailable for production but the cleaning of a mask leads to a potential risk of damaging the mask especially for sub resolution patterns such as scatter bars and phase and transmission changes for eaPSM (Embedded Attenuated Phase Shift Mask) masks. This paper will discuss the initial haze issues seen in a 300mm wafer fab and actions put in place to address the problem. An explanation of results gained from haze reduction actions implemented in a wafer fab will be given. Haze seen by reticle inspection and surface analysis tools can be characterised by typical contamination patterns. These signatures appear after a certain number of wafers exposed depending on several reticle variables such as transmission, Binary, eaPSM, Pellicle. Details will be given of how reticles are managed to ensure minimum impact to a production environment with an appropriate reticle control plan. AMC (Airborne

  12. Haze detection by using modified normalized difference haze index in Beijing, Tianjin, and Hebei province

    Science.gov (United States)

    Han, Xinlei; Yao, Fengmei; Zhang, Jiahua; Waqar, Mirza Muhammad; Zha, Yong; He, Junliang

    2016-04-01

    This paper presents the development of index to detect haze from moderate resolution imaging spectroradiometer remote sensing data. Detection of haze over a large area has always been a problem. This study focuses on Beijing, Tianjin, and Shijiazhuang cities in China. These cities have suffered the worst hazy weather in recent years. The spectral influence of haze on surface features was determined through analysis of the spectral variations of surface covers between hazy and haze-free days. A spectral index known as modified normalized difference haze index (m-NDHI) is developed that can be used to monitor haze distribution and intensity. Correlation analysis of the derived m-NDHI and previously developed NDHI with in situ PM2.5 (particulate matter with diameter haze in large scales from remotely sensing data and characterize the situation of urban atmospheric pollution.

  13. Episode-Based Evolution Pattern Analysis of Haze Pollution: Method Development and Results from Beijing, China.

    Science.gov (United States)

    Zheng, Guangjie; Duan, Fengkui; Ma, Yongliang; Zhang, Qiang; Huang, Tao; Kimoto, Takashi; Cheng, Yafang; Su, Hang; He, Kebin

    2016-05-01

    Haze episodes occurred in Beijing repeatedly in 2013, resulting in 189 polluted days. These episodes differed in terms of sources, formation processes, and chemical composition and thus required different control policies. Therefore, an overview of the similarities and differences among these episodes is needed. For this purpose, we conducted one-year online observations and developed a program that can simultaneously divide haze episodes and identify their shapes. A total of 73 episodes were identified, and their shapes were linked with synoptic conditions. Pure-haze events dominated in wintertime, whereas mixed haze-dust (PM2.5/PM10 haze-fog (Aerosol Water/PM2.5 ∼ 0.3) events dominated in spring and summer-autumn, respectively. For all types, increase of ratio of PM2.5 in PM10 was typically achieved before PM2.5 reached ∼150 μg/m(3). In all PM2.5 species observed, organic matter (OM) was always the most abundant component (18-60%), but it was rarely the driving factor: its relative contribution usually decreased as the pollution level increased. The only OM-driven episode observed was associated with intensive biomass-burning activities. In comparison, haze evolution generally coincided with increasing sulfur and nitrogen oxidation ratios (SOR and NOR), indicating the enhanced production of secondary inorganic species. Applicability of these conclusions required further tests with simultaneously multisite observations.

  14. [Characteristics of water-soluble organic nitrogen of PM2.5 in Xi'an during wintertime non-haze and haze periods].

    Science.gov (United States)

    Cheng, Yu-Ting; Wang, Ge-Hui; Sun, Tao; Cheng, Chun-Lei; Meng, Jing-Jing; Ren, Yan-Qin; Li, Jian-Jun

    2014-07-01

    High-volume PM2.5 samples were collected hourly from 4 December to 13 December 2012 at an urban site in Xi'an and analyzed for organic carbon (OC), elemental carbon (EC), water-soluble organic carbon (WSOC), water-soluble total nitrogen (WSTN), water-soluble organic nitrogen (WSON) and inorganic ions to investigate the sources and formation mechanism of WSON. The results showed that during the sampling period the averaged hourly concentration of WSON was (12 +/- 9.4) microg x m(-3) and maximized at 31 microg x m(-3), accounting for 47% +/- 9.8% of WSTN with NH4(+) -N and NO3(-) -N being 29% +/- 8.5% and 23% +/- 8.1%, respectively. WSON: WSOC (N: C) mass ratios ranged from 0.04 to 0.65 with an average of 0.31 +/- 0.13 during the observation period. WSON was (1.6 +/- 0.9) microg x m(-3), (6.5 +/- 3.9) microg x m(-3) and (23 +/- 4.7) microg x m(-3) in non-haze days (visibility > 10 km), light haze days (5 km haze days (visibility haze days to 0.3 +/- 0.1 on light haze days and 0.4 +/- 0.1 on heavy haze days, in consistence with the enhanced acidity of the fine particles. In addition, during the whole sampling period, WSON was strongly correlated with NH4(+), SO4(2-) and NO3(-) (R2 > 0.80), and negatively correlated with cation-anion equivalent ratio (R2 = 0.53). These phenomena can be mainly ascribed to a gas-particle conversion of gaseous water-soluble nitrogen-containing organic compounds like amines via acid-base reactions, which was sharply increased under the favorable meteorological conditions (e.g., low temperature and high humidity) during the heavy haze days.

  15. Deteriorating haze situation and the severe haze episode during December 18-25 of 2013 in Xi'an, China, the worst event on record

    Science.gov (United States)

    Liu, Xiaodong; Hui, Ying; Yin, Zhi-Yong; Wang, Zhaosheng; Xie, Xiaoning; Fang, Jiangang

    2016-07-01

    Frequent occurrence of haze weather has been considered an urgent environmental problem in China and has attracted much attention worldwide in recent years. In this study, we examined the trend in the occurrence of haze days based on horizontal visibility in Xi'an, a major city in central China, since 2000. There were 49 haze days per year on average in Xi'an during 2000-2013, and the number of haze days has increased significantly since 2008, reaching 102 days in 2013. December is the month of the highest frequency of occurrence. During December 18-25 of 2013, the longest-lasting and most severe haze event in the recent decades occurred. The 8-day mean visibility in Xi'an was only 2.5 km with 5 days below 2 km. The mean air quality index in Xi'an during this period was 486.5, and in four of those days, it reached or exceeded the index's upper limit of 500. The exceptionally high level of PM2.5 concentration was inferred as the main reason of this severe haze episode. The local weather conditions were characterized by weak winds, enhanced atmospheric stability, and high relative humidity. Strong mid-tropospheric zonal flows in combination with weakened East Asian winter monsoon limited the cold air invasion from the higher latitudes, creating a condition of low pressure gradients in the lower troposphere and near the surface for a large region in central and eastern China. With high background emission levels, the suppressed dispersion of air pollutants eventually caused this severe haze episode affecting a large region in China.

  16. A broadband cavity-enhanced spectrometer for measuring the extinction of aerosols at blue and near-UV wavelengths

    Science.gov (United States)

    Venables, Dean; Fullam, Donovan; Hoa Le, Phuoc; Chen, Jun; Böge, Olaf; Herrmann, Hartmut

    2016-04-01

    We describe a new broadband cavity-enhanced absorption spectrometer for sensitive extinction measurements of aerosols. The instrument is distinguished by its broad and continuous spectral coverage from the near-UV to blue wavelengths (ca. 320 to 450 nm). The short wavelength region has been little explored compared to visible wavelengths, but is important because (1) brown carbon (BrC) absorbs strongly in this wavelength region, and (2) absorption of near-UV radiation in the atmosphere alters the photolysis rate of the key atmospheric species O3, NO2, and HONO, with implications for air quality and atmospheric oxidation capacity. The instrument performance and the effect of a switchable in-line filter are characterised. Early results using the instrument in the TROPOS atmospheric simulation chamber are presented. These experiments include studies of secondary organic aerosol formation (SOA), and biomass burning experiments of rice and wheat straw, followed by experiments simulating particle aging under daytime and nighttime conditions.

  17. METEOROLOGICAL FACTORS IN THE FORMATION OF REGIONAL HAZE

    Science.gov (United States)

    The purpose of this research project was to determine the role of meteorological factors in the formation of widespread areas of haze in the eastern United States. Three case studies were made: A summer haze episode, an off-season haze episode and a non-haze episode.

  18. Haze insights and mitigation in China: an overview.

    Science.gov (United States)

    Zhuang, Xuliang; Wang, Yuesi; He, Hong; Liu, Jianguo; Wang, Xinming; Zhu, Tingyu; Ge, Maofa; Zhou, Ju; Tang, Guiqian; Ma, Jinzhu

    2014-01-01

    The present article provides an overview of the chemical and physical features of haze in China, focusing on the relationship between haze and atmospheric fine particles, and the formation mechanism of haze. It also summarizes several of control technologies and strategies to mitigate the occurrence of haze. The development of instruments and the analysis of measurements of ambient particles and precursor concentrations have provided important information about haze formation. Indeed, the use of new instruments has greatly facilitated current haze research in China. Examples of insightful results include the relationship between fine particles and haze, the chemical compositions and sources of particles, the impacts of the aging process on haze formation, and the application of technologies that control the formation of haze. Based on these results, two relevant issues need to be addressed: understanding the relationship between haze and fine particles and understanding how to control PM2.5.

  19. Polygyny and extra-pair paternity enhance the opportunity for sexual selection in blue tits

    NARCIS (Netherlands)

    Vedder, Oscar; Komdeur, Jan; van der Velde, Marco; Schut, Elske; Magrath, Michael J. L.

    2011-01-01

    Polygyny and extra-pair paternity are generally thought to enhance sexual selection. However, the extent to which these phenomena increase variance in male reproductive success will depend on the covariance between success at these two strategies. We analysed these patterns over four breeding season

  20. Aluminum Nanostructured Films as Substrates for Enhanced Fluorescence in the Ultraviolet-Blue Spectral Region

    OpenAIRE

    Ray, Krishanu; Chowdhury, Mustafa H.; Lakowicz, Joseph R.

    2007-01-01

    Particulate aluminum films of varied thicknesses were deposited on quartz substrates by thermal evaporation. These nanostructured substrates were characterized by scanning electron microscopy (SEM). With the increase of aluminum thickness, the films progress from particulate toward smooth surfaces as observed by SEM images. To date, metal-enhanced fluorescence (MEF) has primarily been observed in the visible–NIR wavelength region using silver or gold island films or roughened surfaces. We now...

  1. Postpartum Blues

    Medline Plus

    Full Text Available ... blues The postpartum blues E-mail to a friend Please fill in all fields. Please enter a ... blues: Talk to your partner or a good friend about how you feel Get plenty of rest ...

  2. Core-shell Mn3O4/birnessite-MnO2 hierachical structure with enhanced adsorption towards methylene blue

    Science.gov (United States)

    Huang, Feifan; Zhou, Bowen; Xiao, Han; Xiao, Wei

    2016-01-01

    The core-shell Mn3O4/birnessite-MnO2 (Mn3O4/MnO2) was successfully established by assembly of birnessite-type MnO2 over Mn3O4 backbones. The product was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), as well as UV-vis absorption spectra (UV-vis) to assess its adsorption of methylene blue (MB) from neutral aqueous solutions. Compared to the individual Mn3O4, the prepared Mn3O4/MnO2 shows enhanced adsorption capability towards MB. Such enhancement is due to the higher surface area and the unique nanosheet shells. The adsorption of MB on the surface of Mn3O4/MnO2 was studied in terms of pseudo-first-order and the pseudo-second-order kinetic models, and the latter was found better. The present study indicates that hierarchically structured core-shell manganese oxides are promising adsorbents for wastewater treatment.

  3. Metal-Organic Coordination Networks: Prussian Blue and Its Synergy with Pt Nanoparticles to Enhance Oxygen Reduction Kinetics.

    Science.gov (United States)

    Du, Lei; Du, Chunyu; Chen, Guangyu; Kong, Fanpeng; Yin, Geping; Wang, Yong

    2016-06-22

    Oxygen reduction reaction (ORR) is the cornerstone in the electrochemical energy conversion devices such as fuel cells and metal-air batteries. It remains a great challenge to develop the ORR electrocatalysts with fast kinetics and high durability. Herein, we report the synthesis of a novel metal-organic coordination networks material, prussian blue crystalline nanograins mosaicked within amorphous membrane (PB CNG-M-AM). Such unique PB CNG-M-AM is designed to enhance the electrocatalysis of Pt toward the ORR by the electrostatic self-assembly. Thus, obtained Pt-PB/C catalysts form numerous Pt-PB-gas three-phase boundaries and present rather high intrinsic activity, four-electron selectivity and superior stability. Moreover, a completely new synergetic mechanism between PB and Pt is discovered, which delicately alters the ORR route and significantly enhances the ORR kinetics. This work provides not only a new strategy and mechanism for developing highly efficient ORR electrocatalysts, but also an alternative way to utilize metal-organic coordination networks materials. PMID:27253719

  4. Facile preparation of a Pt/Prussian blue/graphene composite and its application as an enhanced catalyst for methanol oxidation

    International Nuclear Information System (INIS)

    Graphical abstract: - Highlights: • Pt/Prussian blue/graphene catalyst was easily synthesized by the sequential electrodeposition method. • Prussian blue can promote the homogeneous growth of small Pt nanoparticles. • The as-made catalyst exhibited enhanced electro-catalytic performance for methanol oxidation. • The interplay of Prussian blue and Pt plays a significant role in reducing CO poisoning of the catalyst. - Abstract: Graphene nanosheets (GN) are modified by electrodeposition of Prussian blue (PB) followed by shape-regulated depositing of small Pt nanoparticles via the interaction between PB and PtCl62− to form a novel catalyst Pt/PB/GN. The Pt/PB/GN composite exhibits significantly enhanced electrocatalytic activity with a mass activity of 445 mA mg−1Pt (at 0.68 V vs. SCE) and high stability towards methanol oxidation. The high catalytic activity can be attributed to the unique porous architecture and peculiar electrical property of Prussian blue integrated with graphene layers which can not only well accommodate Pt nanoparticles but also provide multidimensional pathways to facilitate the mass and electron transport for methanol oxidation. This strategy can be readily extended to fabrication of other graphene-based hybrid supports for precious metal catalysts in fuel cell applications

  5. Hazing: Collective Stupidity, Insensitivity and Irresponsibility.

    Science.gov (United States)

    Buchanan, E. T. "Joe", III; And Others

    1982-01-01

    Provides a basis for colleges and universities to develop regulations sanctioning hazing. Describes the types of activities that have caused death. Presents state laws and discusses the legal context leading to civil or criminal liability. (RC)

  6. Application of DARLAM to Regional Haze Modeling

    Science.gov (United States)

    Koe, L. C. C.; Arellano, A. F., Jr.; McGregor, J. L.

    - The CSIRO Division of Atmospheric Research limited area model (DARLAM) is applied to atmospheric transport modeling of haze in southeast Asia. The 1998 haze episode is simulated using an emission inventory derived from hotspot information and adopting removal processes based on SO2.Results show that the model is able to simulate the transport of haze in the region. The model images closely resemble the plumes of NASA Total Ozone Mapping Spectrometer and Meteorological Service Singapore haze maps. Despite the limitation of input data, particularly for haze emissions, the three-month average pattern correlation obtained for the whole episode is 0.61. The model has also been able to reproduce the general features of transboundary air pollution over a long period of time. Predicted total particulate matter concentration also agrees reasonably well with observation.The difference in the model results from the satellite images may be attributed to the large uncertainties of emission, simplification of haze deposition and transformation mechanisms and the relatively coarse horizontal and vertical resolution adopted for this particular simulation.

  7. Different Techniques for Enhancing the Removal of Methylene Blue (MB)dye From Aqueous Solution

    International Nuclear Information System (INIS)

    Different techniques were conducted for removal of MB dye from aqueous solution. These techniques which were used separately are: (i) adsorption using activated carbon (AC) prepared from composite of different ratios of Date Pits-Clay (DP-C); (II) Chemical oxidation using H2O2; and (III) photo degradation using UV irradiation. In the adsorption technique, a series of experiments were undertaken in an agitated batch to assess the effect of the system variables; types of activated carbon, ph, adsorbent and adsorbate concentration, temperature and interfering ions. From the isotherm studies, the Langmuir monolayer capacity was 416.67 mg/g. The kinetic parameters have shown that they could be fitted well to the pseudo second- order kinetic and intra-particle diffusion models. The temperature study showed that the MB adsorption is endothermic and spontaneous with increased randomness at the solid solution interface. The presence of interfering ions has an insignificant effect with the exception of Cl- anion that slightly decreases the adsorption of MB. Finally, the addition of H2O2 and UV irradiation in the presence AC enhances the removal of MB dye. The rates of the second order for the removal of MB dye take the following order: AC+H2O2+UV > AC+UV >AC+H2O2 > AC.

  8. Enhanced photocatalytic activity of CeO2 using β-cyclodextrin on visible light assisted decoloration of methylene blue.

    Science.gov (United States)

    Pitchaimuthu, Sakthivel; Velusamy, Ponnusamy

    2014-01-01

    An attempt has been made to enhance the photocatalytic activity of CeO(2) for visible light assisted decoloration of methylene blue (MB) dye in aqueous solutions by β-cyclodextrin (β-CD). The inclusion complexation patterns between host and guest (i.e., β-CD and MB) have been confirmed with UV-visible spectral data. The interaction between CeO(2) and β-CD has also been characterized by field emission scanning electron microscopy analysis. The photocatalytic activity of the catalyst under visible light was investigated by measuring the photodegradation of MB in aqueous solution. The effects of key operational parameters such as initial dye concentration, initial pH, CeO(2) concentration as well as illumination time on the decolorization extents were investigated. Among the processing parameters, the pH of the reaction solution played an important role in tuning the photocatalytic activity of CeO(2). The maximum photodecoloration rate was achieved at basic pH (pH 11). Under the optimum operational conditions, approximately 99.6% dye removal was achieved within 120 min. The observed results indicate that the decolorization of the MB followed a pseudo-first order kinetics. PMID:24434976

  9. Rare Earth Oxide-Treated Fullerene and Titania Composites with Enhanced Photocatalytic Activity for the Degradation of Methylene Blue

    Institute of Scientific and Technical Information of China (English)

    MENG Zada; ZHU Lei; CHOI Jong-geun; PARK Chong-yeon; OH Won-chun

    2011-01-01

    Rare earth oxide-treated fullerene and titania composites (Y-fullerene/TiO2) were prepared by the sol-gel method.The products had interesting surface compositions.X-ray diffraction patterns of the composites showed that the Y-fullerene/TiO2 composites contained a single and clear anatase phase.The surface properties were observed by scanning electron microscopy,which gave a characterization of the texture on the Y-fullerene/TiO2 composites and showed a homogenous distribution of titanium particles.The energy-dispersive X-ray spectra showed the presence of C and Ti with strong Y peaks.The composite obtained was also characterized with transmission electron microscopy and UV-Vis spectroscopy.The photocatalytic results showed that the y-fullerene/TiO2 composites had excellent activity for the degradation of methylene blue under visible light irradiation.This was attributed to both the effects on the photocatalysis of the supported TiO2 by charge transfer by the fullerene,and the introduction of yttrium to enhance photo-generated electron transfer.

  10. Enhanced Photocatalytic Degradation of Methylene Blue Using ZnFe2O4/MWCNT Composite Synthesized by Hydrothermal Method

    Directory of Open Access Journals (Sweden)

    Sonal Singhal

    2013-01-01

    Full Text Available Multiwalled carbon nanotubes (MWCNTs were synthesized using arc discharge method at a magnetic field of 430 G and purified using HNO3/H2O2. Transmission electron micrographs revealed that MWCNTs had inner and outer diameter of ~2 nm and ~4 nm, respectively. Raman spectroscopy confirmed formation of MWCNTs showing G-band at 1577 cm−1. ZnFe2O4 and ZnFe2O4/MWCNT were produced using one step hydrothermal method. Powder X-ray diffraction (XRD confirmed the formation of cubic spinel ZnFe2O4 as well as incorporation of MWCNT into ZnFe2O4. Visible light photocatalytic degradation of methylene blue (MB was studied using pure ZnFe2O4 and ZnFe2O4/MWCNT. The results showed that ZnFe2O4/MWCNT composite had higher photocatalytic activity as compared to pure ZnFe2O4. After irradiation for 5 hours in the visible light, MB was almost 84% degraded in the presence of ZnFe2O4 photocatalyst, while 99% degradation was observed in case of ZnFe2O4/MWCNT composite. This enhancement in the photocatalytic activity of composite may be attributed to the inhibition of recombination of photogenerated charge carriers.

  11. Enhanced methylene blue oxidative removal by copper electrode-based plasma irradiation with the addition of hydrogen peroxide.

    Science.gov (United States)

    Son, Guntae; Kim, Do-Hyung; Lee, Jung Seok; Lee, Hongshin

    2016-08-01

    Submerged plasma irradiation (SPI)-based advanced oxidation processes have been studied for the oxidation of recalcitrant organic compounds because of their various physical and chemical properties. However, SPI technologies still have a few drawbacks such as relatively low efficiency for wastewater treatment and high energy consumption. In order to overcome these drawbacks, in this study, we proposed the combination of SPI and the Cu(II)-catalyzed Fenton-like system. The removal of methylene blue (MB) by the SPI system was significantly enhanced upon the addition of H2O2. The pseudo-first-order rate constants of MB removal increased with the increase of applied voltage. In addition, the optimum H2O2 dose and initial solution pH were 100 mM and 9, respectively. The reactive oxidants responsible for MB removal in copper electrode-based SPI/H2O2 systems are likely to be hydroxyl radicals (OH) or cupryl ion (Cu(III)), wherein Cu(III) is especially important. Furthermore, the copper electrode-based SPI/H2O2 system is a novel advanced oxidation process capable of oxidizing water recalcitrant and toxic organic pollutants at neutral pH. PMID:27236847

  12. Rapid formation and evolution of an extreme haze episode in Northern China during winter 2015

    Science.gov (United States)

    Sun, Yele; Chen, Chen; Zhang, Yingjie; Xu, Weiqi; Zhou, Libo; Cheng, Xueling; Zheng, Haitao; Ji, Dongsheng; Li, Jie; Tang, Xiao; Fu, Pingqing; Wang, Zifa

    2016-05-01

    We investigate the rapid formation and evolutionary mechanisms of an extremely severe and persistent haze episode that occurred in northern China during winter 2015 using comprehensive ground and vertical measurements, along with receptor and dispersion model analysis. Our results indicate that the life cycle of a severe winter haze episode typically consists of four stages: (1) rapid formation initiated by sudden changes in meteorological parameters and synchronous increases in most aerosol species, (2) persistent evolution with relatively constant variations in secondary inorganic aerosols and secondary organic aerosols, (3) further evolution associated with fog processing and significantly enhanced sulfate levels, and (4) clearing due to dry, cold north-northwesterly winds. Aerosol composition showed substantial changes during the formation and evolution of the haze episode but was generally dominated by regional secondary aerosols (53–67%). Our results demonstrate the important role of regional transport, largely from the southwest but also from the east, and of coal combustion emissions for winter haze formation in Beijing. Also, we observed an important downward mixing pathway during the severe haze in 2015 that can lead to rapid increases in certain aerosol species.

  13. Rapid formation and evolution of an extreme haze episode in Northern China during winter 2015.

    Science.gov (United States)

    Sun, Yele; Chen, Chen; Zhang, Yingjie; Xu, Weiqi; Zhou, Libo; Cheng, Xueling; Zheng, Haitao; Ji, Dongsheng; Li, Jie; Tang, Xiao; Fu, Pingqing; Wang, Zifa

    2016-01-01

    We investigate the rapid formation and evolutionary mechanisms of an extremely severe and persistent haze episode that occurred in northern China during winter 2015 using comprehensive ground and vertical measurements, along with receptor and dispersion model analysis. Our results indicate that the life cycle of a severe winter haze episode typically consists of four stages: (1) rapid formation initiated by sudden changes in meteorological parameters and synchronous increases in most aerosol species, (2) persistent evolution with relatively constant variations in secondary inorganic aerosols and secondary organic aerosols, (3) further evolution associated with fog processing and significantly enhanced sulfate levels, and (4) clearing due to dry, cold north-northwesterly winds. Aerosol composition showed substantial changes during the formation and evolution of the haze episode but was generally dominated by regional secondary aerosols (53-67%). Our results demonstrate the important role of regional transport, largely from the southwest but also from the east, and of coal combustion emissions for winter haze formation in Beijing. Also, we observed an important downward mixing pathway during the severe haze in 2015 that can lead to rapid increases in certain aerosol species. PMID:27243909

  14. Unlinking absorption and haze in thin film silicon solar cells front electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Boccard, Mathieu; Cuony, Peter; Battaglia, Corsin; Despeisse, Matthieu; Ballif, Christophe [Ecole Polytechnique Federale de Lausanne (EPFL), Institute of Microengineering (IMT), Photovoltaics and Thin Film Electronics Laboratory, Rue A.-L. Breguet 2, 2000 Neuchatel (Switzerland)

    2010-11-15

    We study the respective influence of haze and free carrier absorption (FCA) of transparent front electrodes on the photogenerated current of micromorph thin film silicon solar cells. To decouple the haze and FCA we develop bi-layer front electrodes: a flat indium tin oxide layer assures conduction and allows us to tune FCA while the haze is adjusted by varying the thickness of a highly transparent rough ZnO layer. We show how a minimum amount of FCA leads only to a few percents absorption for a single light path but to a strong reduction of the cell current in the infrared part of the spectrum. Conversely, a current enhancement is shown with increasing front electrode haze up to a saturation of the current gain. This saturation correlates remarkably well with the haze of the front electrode calculated in silicon. This allows us to clarify the requirements for the front electrodes of micromorph cells. (copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  15. Rapid formation and evolution of an extreme haze episode in Northern China during winter 2015.

    Science.gov (United States)

    Sun, Yele; Chen, Chen; Zhang, Yingjie; Xu, Weiqi; Zhou, Libo; Cheng, Xueling; Zheng, Haitao; Ji, Dongsheng; Li, Jie; Tang, Xiao; Fu, Pingqing; Wang, Zifa

    2016-05-31

    We investigate the rapid formation and evolutionary mechanisms of an extremely severe and persistent haze episode that occurred in northern China during winter 2015 using comprehensive ground and vertical measurements, along with receptor and dispersion model analysis. Our results indicate that the life cycle of a severe winter haze episode typically consists of four stages: (1) rapid formation initiated by sudden changes in meteorological parameters and synchronous increases in most aerosol species, (2) persistent evolution with relatively constant variations in secondary inorganic aerosols and secondary organic aerosols, (3) further evolution associated with fog processing and significantly enhanced sulfate levels, and (4) clearing due to dry, cold north-northwesterly winds. Aerosol composition showed substantial changes during the formation and evolution of the haze episode but was generally dominated by regional secondary aerosols (53-67%). Our results demonstrate the important role of regional transport, largely from the southwest but also from the east, and of coal combustion emissions for winter haze formation in Beijing. Also, we observed an important downward mixing pathway during the severe haze in 2015 that can lead to rapid increases in certain aerosol species.

  16. Heterogeneous chemistry: a mechanism missing in current models to explain secondary inorganic aerosol formation during the January 2013 haze episode in North China

    Directory of Open Access Journals (Sweden)

    B. Zheng

    2014-06-01

    Full Text Available Severe regional haze pollution events occurred in eastern and central China in January 2013, which had adverse effects on the environment and public health. Extremely high levels of particulate matter with aerodynamic diameter of 2.5 μm or less (PM2.5 with dominant components of sulfate and nitrate are responsible for the haze pollution. Although heterogeneous chemistry is thought to play an important role in the production of sulfate and nitrate during haze episodes, few studies have comprehensively evaluated the effect of heterogeneous chemistry on haze formation in China by using the 3-D models due to of a lack of treatments for heterogeneous reactions in most climate and chemical transport models. In this work, the offline-coupled WRF-CMAQ model with newly added heterogeneous reactions is applied to East Asia to evaluate the impacts of heterogeneous chemistry and the meteorological anomaly during January 2013 on regional haze formation. The revised CMAQ with heterogeneous chemistry not only captures the magnitude and temporal variation of sulfate and nitrate, but also reproduces the enhancement of relative contribution of sulfate and nitrate to PM2.5 mass from clean days to polluted haze days. These results indicate the significant role of heterogeneous chemistry in regional haze formation and improve the understanding of the haze formation mechanisms during the January 2013 episode.

  17. Haze detection by using modified normalized difference haze index in Beijing, Tianjin, and Hebei province

    Science.gov (United States)

    Han, Xinlei; Yao, Fengmei; Zhang, Jiahua; Waqar, Mirza Muhammad; Zha, Yong; He, Junliang

    2016-04-01

    This paper presents the development of index to detect haze from moderate resolution imaging spectroradiometer remote sensing data. Detection of haze over a large area has always been a problem. This study focuses on Beijing, Tianjin, and Shijiazhuang cities in China. These cities have suffered the worst hazy weather in recent years. The spectral influence of haze on surface features was determined through analysis of the spectral variations of surface covers between hazy and haze-free days. A spectral index known as modified normalized difference haze index (m-NDHI) is developed that can be used to monitor haze distribution and intensity. Correlation analysis of the derived m-NDHI and previously developed NDHI with in situ PM2.5 (particulate matter with diameter water bodies has a coefficient of 0.7096, 0.5864, and 0.4857 and NDHI has coefficient of 0.5625, 0.5321, and 0.4618 with PM2.5 for Beijing, Tianjin, and Shijiazhuang, respectively, in winter. Moreover, the correlation of m-NDHI with PM2.5 is 0.4097, 0.8092, and 0.5546 during the spring, summer, and autumn, respectively, in Beijing. This developed index can be a much easier and more effective method to detect haze in large scales from remotely sensing data and characterize the situation of urban atmospheric pollution.

  18. Visible-light-induced blue MoO{sub 3}–C{sub 3}N{sub 4} composite with enhanced photocatalytic activity

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yeping, E-mail: ypli@ujs.edu.cn [School of Pharmacy, Jiangsu University, Zhenjiang 212013 (China); Huang, Liying [School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Xu, Jingbo [School of Pharmacy, Jiangsu University, Zhenjiang 212013 (China); Xu, Hui [Institute for Energy Research, Jiangsu University, Zhenjiang 212013 (China); Xu, Yuanguo; Xia, Jixiang [School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Li, Huaming, E-mail: lihm@ujs.edu.cn [Institute for Energy Research, Jiangsu University, Zhenjiang 212013 (China)

    2015-10-15

    Highlights: • Novel MoO{sub 3}–C{sub 3}N{sub 4} composite was prepared by a mixing-calcination method. • The MoO{sub 3}–C{sub 3}N{sub 4} composite shows remarkably enhanced absorption of visible light. • The MoO{sub 3}–C{sub 3}N{sub 4} composite shows superior visible-light photocatalytic activity. - Abstract: Composite photocatalyst of blue MoO{sub 3}/g-C{sub 3}N{sub 4} (denoted as MoO{sub 3}–C{sub 3}N{sub 4}) was prepared by a simple mixing-calcination method. The obtained MoO{sub 3}–C{sub 3}N{sub 4} composite contains a low amount of molybdenum blue and shows remarkably enhanced absorption of visible light and high efficiency for the degradation of methylene blue dye (MB) under visible light. The enhancement of visible light photocatalytic activity in MoO{sub 3}–C{sub 3}N{sub 4} is attributed to the synergetic effect: (i) the strong and wide absorption of visible light, (ii) the high separation and easy transfer of photogenerated electron–hole pairs at the heterojunction interfaces derived from the match of band position between the g-C{sub 3}N{sub 4} and MoO{sub 3}.

  19. Postpartum Blues

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    Full Text Available ... Quality Collaboratives Launch Prematurity research centers What is team science? More than 75 years of solving problems ... delivery cause the postpartum blues. How can you manage the baby blues? The American College of Obstetricians ...

  20. Postpartum Blues

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    Full Text Available ... with this condition are happy most of the time. But compared to how she usually feels, the ... the "blues" usually lessens and goes away over time. What causes the baby blues? Medical experts believe ...

  1. Postpartum Blues

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    Full Text Available ... Postpartum care > The postpartum blues The postpartum blues E-mail to a friend Please fill in all fields. Please enter a valid e-mail address. Your information: Your recipient's information: Your ...

  2. Postpartum Blues

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    Full Text Available ... can you manage the baby blues? The American College of Obstetricians and Gynecologists recommends that women do ... can you manage the baby blues? The American College of Obstetricians and Gynecologists recommends that women do ...

  3. Postpartum Blues

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    Full Text Available ... Feels sad Feels confused The postpartum blues peak three to five days after delivery. They usually end ... Feels sad Feels confused The postpartum blues peak three to five days after delivery. They usually end ...

  4. Postpartum Blues

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    Full Text Available ... postpartum blues The postpartum blues E-mail to a friend Please fill in all fields. Please enter ... hear about breakthroughs for babies and families. Ask a question Our health experts can answer questions about ...

  5. Postpartum Blues

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    Full Text Available ... Medical experts believe that changes in the woman's hormones after delivery cause the postpartum blues. How can ... Medical experts believe that changes in the woman's hormones after delivery cause the postpartum blues. How can ...

  6. Haze in China: current and future challenges.

    Science.gov (United States)

    Li, Meina; Zhang, Lulu

    2014-06-01

    Regional haze which triggered both public anxiety and official concerns has been one of the most disastrous weather events in China in recent years. Haze not only had negative impact on daily life, but also an indicator of high concentrations of PM2.5 with the potential to adversely impact public health by damaging people's respiratory, cardiovascular, blood vessel of brain and nervous system. The dust-haze is an accumulated result for a long time of both natural factors and unhealthy economic growth model. In order to tackle air pollution, a number of policies and measures which target at reducing pollution emission and promoting alternative energy production had been implemented. Although significant improvement has occurred in China, change the development mode of "high growth, high pollution" and balance environmental conservation with the well-being of the population remains a challenge for China.

  7. Source appointment of fine particle number and volume concentration during severe haze pollution in Beijing in January 2013.

    Science.gov (United States)

    Liu, Zirui; Wang, Yuesi; Hu, Bo; Ji, Dongsheng; Zhang, Junke; Wu, Fangkun; Wan, Xin; Wang, Yonghong

    2016-04-01

    Extreme haze episodes repeatedly shrouded Beijing during the winter of 2012-2013, causing major environmental and health problems. To better understand these extreme events, particle number size distribution (PNSD) and particle chemical composition (PCC) data collected in an intensive winter campaign in an urban site of Beijing were used to investigate the sources of ambient fine particles. Positive matrix factorization (PMF) analysis resolved a total of eight factors: two traffic factors, combustion factors, secondary aerosol, two accumulation mode aerosol factors, road dust, and long-range transported (LRT) dust. Traffic emissions (54%) and combustion aerosol (27%) were found to be the most important sources for particle number concentration, whereas combustion aerosol (33%) and accumulation mode aerosol (37%) dominated particle volume concentrations. Chemical compositions and sources of fine particles changed dynamically in the haze episodes. An enhanced role of secondary inorganic species was observed in the formation of haze pollution. Regional transport played an important role for high particles, contribution of which was on average up to 24-49% during the haze episodes. Secondary aerosols from urban background presented the largest contributions (45%) for the rapid increase of fine particles in the severest haze episode. In addition, the invasion of LRT dust aerosols further elevated the fine particles during the extreme haze episode. Our results showed a clear impact of regional transport on the local air pollution, suggesting the importance of regional-scale emission control measures in the local air quality management of Beijing.

  8. Effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events

    Science.gov (United States)

    Quan, Jiannong; Liu, Quan; Li, Xia; Gao, Yang; Jia, Xingcan; Sheng, Jiujiang; Liu, Yangang

    2015-12-01

    The effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events was investigated by analysis of comprehensive measurements of aerosol composition and concentrations [e.g., particular matters (PM2.5), nitrate (NO3), sulfate (SO4), ammonium (NH4)], gas-phase precursors [e.g., nitrogen oxides (NOx), sulfur dioxide (SO2), and ozone (O3)], and relevant meteorological parameters [e.g., visibility and relative humidity (RH)]. The measurements were conducted in Beijing, China from Sep. 07, 2012 to Jan. 16, 2013. The results show that the conversion ratios of N from NOx to nitrate (Nratio) and S from SO2 to sulfate (Sratio) both significantly increased in haze events, suggesting enhanced conversions from NOx and SO2 to their corresponding particle phases in the late haze period. Further analysis shows that Nratio and Sratio increased with increasing RH, with Nratio and Sratio being only 0.04 and 0.03, respectively, when RH aqueous reactions, because solar radiation and thus the photochemical capacity are reduced by the increases in aerosols and RH. This point was further affirmed by the relationships of Nratio and Sratio to O3: the conversion ratios increase with decreasing O3 concentration when O3 concentration is lower than aqueous reactions likely changed aerosols and their precursors during the haze events: in the beginning of haze events, the precursor gases accumulated quickly due to high emission and low reaction rate; the occurrence of heterogeneous aqueous reactions in the late haze period, together with the accumulated high concentrations of precursor gases such as SO2 and NOx, accelerated the formation of secondary inorganic aerosols, and led to rapid increase of the PM2.5 concentration.

  9. Lack of association of dengue activity with haze.

    Science.gov (United States)

    Wilder-Smith, A; Earnest, A; Tan, S B; Ooi, E E; Gubler, D J

    2010-07-01

    Dengue activity depends on fluctuations in Aedes populations which in turn are known to be influenced by climate factors including temperature, humidity and rainfall. It has been hypothesized that haze may reduce dengue transmission. Due to its geographical location Singapore suffers almost every year from hazes caused by wildfires from Indonesia. Such hazes have a significant impact on pollution indexes in Singapore. We set out to study the relationship of dengue activity and haze (measured as pollution standard index) in Singapore, using ARIMA models. We ran different univariate models, each encompassing a different lag period for the effects of haze and temperature (from lag 0 to lag 12 weeks). We analysed the data on a natural logarithmic scale to stabilize the variance and improve the estimation. No association between dengue activity and haze was found. Our findings do not lend support to the hypothesis that haze is associated with reduced dengue activity in Singapore.

  10. Edge-Preserving Decomposition-Based Single Image Haze Removal.

    Science.gov (United States)

    Li, Zhengguo; Zheng, Jinghong

    2015-12-01

    Single image haze removal is under-constrained, because the number of freedoms is larger than the number of observations. In this paper, a novel edge-preserving decomposition-based method is introduced to estimate transmission map for a haze image so as to design a single image haze removal algorithm from the Koschmiedars law without using any prior. In particular, weighted guided image filter is adopted to decompose simplified dark channel of the haze image into a base layer and a detail layer. The transmission map is estimated from the base layer, and it is applied to restore the haze-free image. The experimental results on different types of images, including haze images, underwater images, and normal images without haze, show the performance of the proposed algorithm.

  11. PhotoCatalytic Degradation of Methyl Blue Dye and Enhanced Antibacterial Properties of Treated Wool with ZrCL4 and Dyeing with Madder

    Directory of Open Access Journals (Sweden)

    Arash Almasian

    2015-03-01

    Full Text Available This research aims to create the photo catalytic degradation of methyl blue dye and enhanced antibacterial properties on wool fabric using ZrCl4 particles. Wool fabrics were treated with different concentrations of zirconium salt in water solution including %1, %3, %6 and 9% o.w.f. and the dyeing process was carried out on the fabrics in the states before, simultaneously and after the mordanting with madder.Formic acid was used to generate acidic pH.The photo catalytic properties of the fabrics were examined through evaluating the color removal from the stained fabric with Methylene Blue. The antibacterial properties were determined by reduction growth of a Gram-negative bacterium E. coli and a Gram-positive bacterium Staphylococcus aureus. Furthermore, the FTIR spectrum of some samples was analyzed. The SEM pictures and EDX spectrums of some samples were also reported.

  12. Analysis of a winter regional haze event and its formation mechanism in the North China Plain

    Directory of Open Access Journals (Sweden)

    X. J. Zhao

    2013-01-01

    these source regions. The accumulation of pollutants was one main factor in the haze formation. The enhanced southwest wind in the last period of this episode transported pollutants to the downwind area and expanded the regional scope of the haze.

  13. Blue-shifted emission and enhanced quantum efficiency viaπ-bridge elongation in carbazole-carborane dyads.

    Science.gov (United States)

    Wang, Zhaojin; Jiang, Peng; Wang, Tianyu; Moxey, Graeme J; Cifuentes, Marie P; Zhang, Chi; Humphrey, Mark G

    2016-06-21

    Carbazole-carborane linear dyads and di(carbazole)-carborane V-shaped dyads with phenyleneethynylene-based bridges have been synthesized. The V-shaped dyads display the expected red-shifts in the location of their UV-Vis absorption maxima on bridge-lengthening, but show unusual blue-shifts in charge-transfer (CT) emission on the same π-system lengthening. These blue-shifts can be attributed to the 2n + 3 electron count within the carborane cluster in the excited state. The linear dyads luminesce via a combination of local excited (LE) and CT emission, with a red-shift in LE emission and a blue-shift in CT emission accompanying π-bridge elongation. A quantum efficiency as high as 86% in the solution state is achieved from the hybrid LE/CT emission. Time-dependent density functional theory (TD-DFT) calculations at the excited state of these compounds have clarified the photoluminescence blue-shift and suggested a typical cluster C-C bond elongation in the V-shaped dyads. Calculations on the elongated linear dyads have suggested that the electron density is localized at the phenyleneethynylene-containing bridge. PMID:27225829

  14. Size-resolved aerosol chemical analysis of extreme haze pollution events during early 2013 in urban Beijing, China

    International Nuclear Information System (INIS)

    Highlights: • Anthropogenic species substantially accumulated in both fine and coarse particles. • Secondary organic carbon in PM1.1 decreased from clear to haze days. • The mass peak shifted to larger particles from clear to haze days. • The NO3−/SO42− ratio decreased with enhanced haze pollution. • Both mobile local and stationary regional sources were vital for haze formation. - Abstract: Using size-resolved filter sampling and chemical characterization, high concentrations of water-soluble ions, carbonaceous species and heavy metals were found in both fine (PM2.1) and coarse (PM2.1–9) particles in Beijing during haze events in early 2013. Even on clear days, average mass concentration of submicron particles (PM1.1) was several times higher than that previously measured in most of abroad urban areas. A high concentration of particulate matter on haze days weakens the incident solar radiation, which reduces the generation rate of secondary organic carbon in PM1.1. We show that the peak mass concentration of particles shifted from 0.43–0.65 μm on clear days to 0.65–1.1 μm on lightly polluted days and to 1.1–2.1 μm on heavily polluted days. The peak shifts were also found for the following species: organic carbon, elemental carbon, NH4+, SO42−, NO3−, K, Cu, Zn, Cd and Pb. Our findings demonstrate that secondary inorganic aerosols (36%) and organic matter (26%) dominated the fine particle mass on heavily polluted days, while their contribution reduced to 29% and 18%, respectively, on clear days. Besides fine particles, anthropogenic chemical species also substantially accumulated in the coarse mode, which suggests that particles with aerodynamic diameter larger than 2.1 μm cannot be neglected during severe haze events

  15. The effect of pollutional haze on pulmonary function.

    Science.gov (United States)

    Liu, Shao-Kun; Cai, Shan; Chen, Yan; Xiao, Bing; Chen, Ping; Xiang, Xu-Dong

    2016-01-01

    Detrimental health effects of atmospheric exposure to ambient particulate matter (PM) have been investigated in numerous studies. Exposure to pollutional haze, the carrier of air pollutants such as PM and nitrogen dioxide (NO2) has been linked to lung and cardiovascular disease, resulting increases in both hospital admissions and mortality. This review focuses on the constituents of pollutional haze and its effects on pulmonary function. The article presents the available information and seeks to correlate pollutional haze and pulmonary function.

  16. Kind of Blue - Europa Blues

    DEFF Research Database (Denmark)

    Mortensen, Tore; Kirkegaard, Peter

    2009-01-01

    Bidraget reflekterer over sammenhænge mellem to værker fra det musikalske og litterære område. Det drejer sig om Miles Davis' Kind of Blue fra 1959 og Arne Dahls krimi, Europa Blues fra 2001. Den grundlæggende indfaldsvinkel er det performative, den frie, men samtidigt disciplinerede musikalske...

  17. Photon-avalanche upconversion of Ho3+ in NaYF4 and enhancement of violet, blue and green emissions induced by sensitization of Tm3+

    International Nuclear Information System (INIS)

    Ho3+ singly doped and Ho3+/Tm3+ co-doped hexagonal NaYF4 powders have been synthesized by a solid-state reaction method. Under excitation of 671 nm diode laser, upconverted blue, green and red emission bands are observed in Ho3+ singly doped sample. Temporal evolution and excitation power dependent behavior for the green emission are explored, indicating that a photon-avalanche mechanism is responsible for the upconversion processes in Ho3+ singly doped hexagonal NaYF4 sample. With the introduction of Tm3+, the intensities of both blue and green emissions of Ho3+ are efficiently enhanced, which are attributed to two energy transfer processes from Tm3+ to Ho3+, i.e., 3F4 (Tm3+) + 5I8(Ho3+) → 3H6 (Tm3+) + 5I7(Ho3+) and 1G4 (Tm3+) + 5I8(Ho3+) → 3H6 (Tm3+) + 5F3(Ho3+). The result offers a new sensitization approach to enhance the upconversion efficiency of Ho3+ under 671 nm excitation.

  18. Perilesional Inflammation in Neurocysticercosis - Relationship Between Contrast-Enhanced Magnetic Resonance Imaging, Evans Blue Staining and Histopathology in the Pig Model.

    Directory of Open Access Journals (Sweden)

    Carla Cangalaya

    2016-07-01

    Full Text Available Disease manifestations in neurocysticercosis (NCC are frequently due to inflammation of degenerating Taenia solium brain cysts. Exacerbated inflammation post anthelmintic treatment is associated with leakage of the blood brain barrier (BBB using Evans blue (EB staining. How well EB extravasation into the brain correlates with magnetic resonance imaging (MRI using gadolinium (Gd enhancement as a contrast agent and pericystic inflammation was analyzed in pigs harboring brain cysts of Taenia solium.Three groups of 4 naturally infected pigs were assessed. The first and second groups were treated with both praziquantel plus albendazole and sacrificed two and five days post treatment, respectively. A third untreated group remained untreated. Pigs were injected with EB two hours prior to evaluation by Gd-enhanced T1-MRI, and euthanized. The EB staining for each cyst capsule was scored (EB grades were 0: 0%; 1: up to 50%; 2: over 50% but less than 100%; 3: 100%. Similarly, the Gd enhancement around each cyst was qualitatively and quantitatively scored from the MRI. The extent of pericystic inflammation on histology was scored in increasing severity as IS1, IS2, IS3 and IS4. Grade 3 EB staining and enhancement was only seen in treated capsules. Also, treated groups had higher Gd intensity than the untreated group. Grades of enhancement correlated significantly with Gd enhancement intensity. EB staining was correlated with Gd enhancement intensity and with IS4 in the treated groups. These correlations were stronger in internally located cysts compared to superficial cysts in treated groups.EB staining and Gd enhancement strongly correlate. The intensity of enhancement determined by MRI is a good indication of the degree of inflammation. Similarly, EB staining highly correlates with the degree of inflammation and may be applied to study inflammation in the pig model of NCC.

  19. Perilesional Inflammation in Neurocysticercosis - Relationship Between Contrast-Enhanced Magnetic Resonance Imaging, Evans Blue Staining and Histopathology in the Pig Model

    Science.gov (United States)

    Bustos, Javier A.; Calcina, Juan; Vargas-Calla, Ana; Suarez, Diego; Gonzalez, Armando E.; Chacaltana, Juan; Guerra-Giraldez, Cristina; Mahanty, Siddhartha; Nash, Theodore E.; García, Hector H.

    2016-01-01

    Background Disease manifestations in neurocysticercosis (NCC) are frequently due to inflammation of degenerating Taenia solium brain cysts. Exacerbated inflammation post anthelmintic treatment is associated with leakage of the blood brain barrier (BBB) using Evans blue (EB) staining. How well EB extravasation into the brain correlates with magnetic resonance imaging (MRI) using gadolinium (Gd) enhancement as a contrast agent and pericystic inflammation was analyzed in pigs harboring brain cysts of Taenia solium. Methodology/Principal Findings Three groups of 4 naturally infected pigs were assessed. The first and second groups were treated with both praziquantel plus albendazole and sacrificed two and five days post treatment, respectively. A third untreated group remained untreated. Pigs were injected with EB two hours prior to evaluation by Gd-enhanced T1-MRI, and euthanized. The EB staining for each cyst capsule was scored (EB grades were 0: 0%; 1: up to 50%; 2: over 50% but less than 100%; 3: 100%). Similarly, the Gd enhancement around each cyst was qualitatively and quantitatively scored from the MRI. The extent of pericystic inflammation on histology was scored in increasing severity as IS1, IS2, IS3 and IS4. Grade 3 EB staining and enhancement was only seen in treated capsules. Also, treated groups had higher Gd intensity than the untreated group. Grades of enhancement correlated significantly with Gd enhancement intensity. EB staining was correlated with Gd enhancement intensity and with IS4 in the treated groups. These correlations were stronger in internally located cysts compared to superficial cysts in treated groups. Significance EB staining and Gd enhancement strongly correlate. The intensity of enhancement determined by MRI is a good indication of the degree of inflammation. Similarly, EB staining highly correlates with the degree of inflammation and may be applied to study inflammation in the pig model of NCC. PMID:27459388

  20. Postpartum Blues

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    Full Text Available ... leader Partner Spotlight Become a partner World Prematurity Day Your support helps babies We are determined to ... confused The postpartum blues peak three to five days after delivery. They usually end by the tenth ...

  1. Postpartum Blues

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    Full Text Available ... Saving Just a moment, please. You've saved this page It's been added to your dashboard . After ... blues" is not really correct since women with this condition are happy most of the time. But ...

  2. Postpartum Blues

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    Full Text Available ... dashboard . After the baby is born, many new mothers have the postpartum blues (also called the baby ... compared to how she usually feels, the new mother: Is more irritable Cries more easily Feels sad ...

  3. Postpartum Blues

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    Full Text Available ... for your baby Feeding your baby Common illnesses New parents Family health & safety Complications & Loss Pregnancy complications ... your dashboard . After the baby is born, many new mothers have the postpartum blues (also called the ...

  4. A possible formation channel for blue hook stars in globular cluster - II. Effects of metallicity, mass ratio, tidal enhancement efficiency and helium abundance

    CERN Document Server

    Lei, Zhenxin; Zeng, Aihua; Shen, Lihua; Lan, Zhongjian; Jiang, Dengkai; Han, Zhanwen

    2016-01-01

    Employing tidally enhanced stellar wind, we studied in binaries the effects of metallicity, mass ratio of primary to secondary, tidal enhancement efficiency and helium abundance on the formation of blue hook (BHk) stars in globular clusters (GCs). A total of 28 sets of binary models combined with different input parameters are studied. For each set of binary model, we presented a range of initial orbital periods that is needed to produce BHk stars in binaries. All the binary models could produce BHk stars within different range of initial orbital periods. We also compared our results with the observation in the Teff-logg diagram of GC NGC 2808 and {\\omega} Cen. Most of the BHk stars in these two GCs locate well in the region predicted by our theoretical models, especially when C/N-enhanced model atmospheres are considered. We found that mass ratio of primary to secondary and tidal enhancement efficiency have little effects on the formation of BHk stars in binaries, while metallicity and helium abundance would...

  5. Temporal variations of black carbon during haze and non-haze days in Beijing

    Science.gov (United States)

    Liu, Qingyang; Ma, Tangming; Olson, Michael R.; Liu, Yanju; Zhang, Tingting; Wu, Yu; Schauer, James J.

    2016-09-01

    Black carbon (BC) aerosol has been identified as one of key factors responsible for air quality in Beijing. BC emissions abatement could help slow regional climate change while providing benefits for public health. In order to quantify its variations and contribution to air pollution, we systematically studied real-time measurements of equivalent black carbon (eBC) in PM2.5 aerosols at an urban site in Beijing from 2010 to 2014. Equivalent black carbon (eBC) is used instead of black carbon (BC) for data derived from Aethalometer-31 measurement. Equivalent BC concentrations showed significant temporal variations with seasonal mean concentration varying between 2.13 and 5.97 μg m-3. The highest concentrations of eBC were found during autumn and winter, and the lowest concentrations occurred in spring. We assessed the temporal variations of eBC concentration during haze days versus non-haze days and found significantly lower eBC fractions in PM2.5 on haze days compared to those on non-haze days. Finally, we observed a clear inverse relationship between eBC and wind speed. Our results show that wind disperses PM2.5 more efficiently than eBC; so, secondary aerosols are not formed to the same degree as primary aerosols over the same transport distance during windy conditions.

  6. Temporal variations of black carbon during haze and non-haze days in Beijing.

    Science.gov (United States)

    Liu, Qingyang; Ma, Tangming; Olson, Michael R; Liu, Yanju; Zhang, Tingting; Wu, Yu; Schauer, James J

    2016-01-01

    Black carbon (BC) aerosol has been identified as one of key factors responsible for air quality in Beijing. BC emissions abatement could help slow regional climate change while providing benefits for public health. In order to quantify its variations and contribution to air pollution, we systematically studied real-time measurements of equivalent black carbon (eBC) in PM2.5 aerosols at an urban site in Beijing from 2010 to 2014. Equivalent black carbon (eBC) is used instead of black carbon (BC) for data derived from Aethalometer-31 measurement. Equivalent BC concentrations showed significant temporal variations with seasonal mean concentration varying between 2.13 and 5.97 μg m(-3). The highest concentrations of eBC were found during autumn and winter, and the lowest concentrations occurred in spring. We assessed the temporal variations of eBC concentration during haze days versus non-haze days and found significantly lower eBC fractions in PM2.5 on haze days compared to those on non-haze days. Finally, we observed a clear inverse relationship between eBC and wind speed. Our results show that wind disperses PM2.5 more efficiently than eBC; so, secondary aerosols are not formed to the same degree as primary aerosols over the same transport distance during windy conditions. PMID:27634102

  7. Temporal variations of black carbon during haze and non-haze days in Beijing.

    Science.gov (United States)

    Liu, Qingyang; Ma, Tangming; Olson, Michael R; Liu, Yanju; Zhang, Tingting; Wu, Yu; Schauer, James J

    2016-09-16

    Black carbon (BC) aerosol has been identified as one of key factors responsible for air quality in Beijing. BC emissions abatement could help slow regional climate change while providing benefits for public health. In order to quantify its variations and contribution to air pollution, we systematically studied real-time measurements of equivalent black carbon (eBC) in PM2.5 aerosols at an urban site in Beijing from 2010 to 2014. Equivalent black carbon (eBC) is used instead of black carbon (BC) for data derived from Aethalometer-31 measurement. Equivalent BC concentrations showed significant temporal variations with seasonal mean concentration varying between 2.13 and 5.97 μg m(-3). The highest concentrations of eBC were found during autumn and winter, and the lowest concentrations occurred in spring. We assessed the temporal variations of eBC concentration during haze days versus non-haze days and found significantly lower eBC fractions in PM2.5 on haze days compared to those on non-haze days. Finally, we observed a clear inverse relationship between eBC and wind speed. Our results show that wind disperses PM2.5 more efficiently than eBC; so, secondary aerosols are not formed to the same degree as primary aerosols over the same transport distance during windy conditions.

  8. Does Pluto Have a Haze Layer?

    Science.gov (United States)

    Elliot, James L.

    1997-01-01

    The goal of this research was to determine whether Pluto has a haze layer through observations (with the Kuiper Airborne Observatory) of a stellar occultation by Pluto that was originally predicted to occur on 1993 October 3. As described in the attached material, our extensive astrometric measurements determined that this occultation would not be visible from Earth, and we canceled plans to observe it with the KAO. Efforts were then directed toward improving our astrometric techniques so that we could find future occultations with which we could satisfy the original goals of the research proposed for this grant.

  9. Enhancement of power conversion efficiency of dye-sensitized solar cells by co-sensitization of Phloxine B and Bromophenol blue dyes on ZnO photoanode

    Energy Technology Data Exchange (ETDEWEB)

    Kushwaha, Suman; Bahadur, Lal, E-mail: lbahadur@bhu.ac.in

    2015-05-15

    A single dye usually absorbs light only in a limited range of solar spectrum. In order to widen the absorption range, a combination of dyes, namely, Phloxine B and Bromophenol blue have been used as sensitizers in ZnO based dye sensitized solar cell (DSSC). It has been found that the DSSC sensitized by mixed dyes exhibited better photovoltaic performance than those observed with the DSSCs using test dyes individually. It has been ascribed to the enhanced absorption of light particularly in higher energy region (λ=400–550 nm) when both dyes were used together as was evident from the absorption spectra of dyes adsorbed onto ZnO electrode. The DSSC using ZnO electrode sensitized by mixed dyes provided J{sub SC}=5.6 mA cm{sup −2}, V{sub OC}=0.606 V, FF=0.53 and maximum energy conversion efficiency (η) of 1.35% on illuminating the cell with visible light of 150 mW cm{sup −2} intensity. - Highlights: • Phloxine B and Bromophenol blue have been used as sensitizers in ZnO based DSSC. • DSSC sensitized by mixed dyes exhibited better photovoltaic performance than those observed with the DSSCs using test dyes individually. • Enhanced absorption of light particularly in higher energy region (λ=400–550 nm) have been observed when both dyes were used together. • The DSSC using ZnO electrode sensitized by mixed dyes provided J{sub sc}=5.6 mA cm{sup −2}, V{sub oc}=0.606 V, FF=0.53. • Efficiency of 1.35% is achieved at visible light intensity of 150 mW cm{sup −2}.

  10. Ascorbic acid enhances oxidative stress tolerance and biological control efficacy of Pichia caribbica against postharvest blue mold decay of apples.

    Science.gov (United States)

    Li, Chaolan; Zhang, Hongyin; Yang, Qiya; Komla, Mahunu Gustav; Zhang, Xiaoyun; Zhu, Shuyun

    2014-07-30

    The effect of ascorbic acid (VC) on improving oxidative stress tolerance of Pichia caribbica and biocontrol efficacy against blue mold caused by Penicillium expansum on apples was investigated. P. caribbica showed susceptibility to the oxidative stress in vitro test, and 250 μg/mL VC treatment improved its oxidative stress tolerance. The higher viability exhibited by VC-treated yeast was associated with a lower intracellular ROS level. The activities of antioxidant enzymes of P. caribbica were improved by VC treatment, including catalase (CAT), superoxide dismutase (SOD), and glutathione peroxidase (GPX). Additionally, VC-treated yeast exhibited greater biocontrol activity against P. expansum and faster growth when stored at 25 and 4 °C, respectively, compared to the performance of the non-VC-treated yeast. In response to the VC treatment under oxidative stress, several differentially expressed proteins were identified in P. caribbica, and most of the poteins were confirmed to be related to basic metabolism. Therefore, the application of ascorbic acid is a useful approach to improve oxidative stress tolerance of P. caribbica and its biocontrol efficacy on apples.

  11. 77 FR 38509 - Approval and Promulgation of Implementation Plans; South Carolina; Regional Haze State...

    Science.gov (United States)

    2012-06-28

    ... promulgated a rule to address regional haze on July 1, 1999 (64 FR 35714), the Regional Haze Rule (RHR). The... address the first implementation period for regional haze.\\1\\ See 77 FR 11894. EPA proposed a limited..., 2012, proposal action on the South Carolina regional haze SIP submittal (77 FR 11906), the states...

  12. 77 FR 38501 - Approval and Promulgation of Implementation Plans; State of Georgia; Regional Haze State...

    Science.gov (United States)

    2012-06-28

    ... haze on July 1, 1999 ] (64 FR 35714), the Regional Haze Rule (RHR). The RHR revised the existing... period for regional haze.\\1\\ See 77 FR 11452. EPA proposed a limited approval of Georgia's SIP revisions... discussed in the proposed rulemaking (77 FR 11474-11475), Georgia's regional haze SIP satisfies the...

  13. 77 FR 38515 - Approval and Promulgation of Implementation Plans; State of Alabama; Regional Haze State...

    Science.gov (United States)

    2012-06-28

    ... haze on July 1, 1999 (64 FR 35713), the Regional Haze Rule (RHR). The RHR revised the existing... also 70 FR 39121. Alabama's analysis in the regional haze SIP revision was consistent with EPA's... February 28, 2012, proposal action on the Alabama regional haze SIP submittal (77 FR 11949), the RHR...

  14. 78 FR 53250 - Approval and Promulgation of Air Quality Implementation Plans; State of Florida; Regional Haze...

    Science.gov (United States)

    2013-08-29

    ... regional haze issues. EPA promulgated a rule to address regional haze on July 1, 1999 (64 FR 35713... first implementation period for regional haze.\\1\\ See 77 FR 31240. EPA's May 25, 2012, proposed... Florida regional haze SIP, and on June 7, 2012 (77 FR 33642), EPA finalized a limited disapproval of...

  15. 77 FR 38185 - Approval and Promulgation of Implementation Plans; State of North Carolina; Regional Haze State...

    Science.gov (United States)

    2012-06-27

    ... regional haze issues. EPA promulgated a rule to address regional haze on July 1, 1999 (64 FR 35713), the..., 2007, SIP revision to address the first implementation period for regional haze.\\1\\ See 77 FR 11858...' test.'' See also 70 FR 39121. North Carolina's analysis in the regional haze SIP revision...

  16. 77 FR 38191 - Approval and Promulgation of Implementation Plans; State of Mississippi; Regional Haze State...

    Science.gov (United States)

    2012-06-27

    ... regional haze issues. EPA promulgated a rule to address regional haze on July 1, 1999 (64 FR 35713), the... address the first implementation period for regional haze.\\1\\ See 77 FR 11879. EPA proposed a limited... FR 33642), EPA finalized a limited disapproval of the Mississippi regional haze SIP because...

  17. Blue gods, blue oil, and blue people.

    Science.gov (United States)

    Fairbanks, V F

    1994-09-01

    Studies of the composition of coal tar, which began in Prussia in 1834, profoundly affected the economies of Germany, Great Britain, India, and the rest of the world, as well as medicine and surgery. Such effects include the collapse of the profits of the British indigo monopoly, the growth in economic power of Germany based on coal tar chemistry, and an economic crisis in India that led to more humane tax laws and, ultimately, the independence of India and the end of the British Empire. Additional consequences were the development of antiseptic surgery and the synthesis of a wide variety of useful drugs that have eradicated infections and alleviated pain. Many of these drugs, particularly the commonly used analgesics, sulfonamides, sulfones, and local anesthetics, are derivatives of aniline, originally called "blue oil" or "kyanol." Some of these aniline derivatives, however, have also caused aplastic anemia, agranulocytosis, and methemoglobinemia (that is, "blue people"). Exposure to aniline drugs, particularly when two or three aniline drugs are taken concurrently, seems to be the commonest cause of methemoglobinemia today. PMID:8065194

  18. An integrated campaign for investigation of winter-time continental haze over Indo-Gangetic Basin and its radiative effects

    International Nuclear Information System (INIS)

    An outflow of continental haze occurs from Indo-Gangetic Basin (IGB) in the North to Bay of Bengal (BoB) in the South. An integrated campaign was organized to investigate this continental haze during December 2013–February 2014 at source and remote regions within IGB to quantify its radiative effects. Measurements were carried out at three locations in eastern India; 1) Kalas Island, Sundarban (21.68°N, 88.57°E) — an isolated island along the north-east coast of BoB, 2) Kolkata (22.57°N, 88.42°E) — an urban metropolis and 3) Siliguri (26.70°N, 88.35°E) — an urban region at the foothills of eastern Himalayas. Ground-based AOD (at 0.5 μm) is observed to be maximum (1.25 ± 0.18) over Kolkata followed by Siliguri (0.60 ± 0.17) and minimum over Sundarban (0.53 ± 0.18). Black carbon concentration is found to be maximum at Kolkata (21.6 ± 6.6 μg·m−3) with almost equal concentrations at Siliguri (12.6 ± 5.2 μg·m−3) and Sundarban (12.3 ± 3.0 μg·m−3). Combination of MODIS-AOD and back-trajectories analysis shows an outflow of winter-time continental haze originating from central IGB and venting out through Sundarban towards BoB. This continental haze with high extinction coefficient is identified up to central BoB using CALIPSO observations and is found to contribute ~ 75% to marine AOD over central BoB. This haze produces significantly high aerosol radiative forcing within the atmosphere over Kolkata (75.4 Wm−2) as well as over Siliguri and Sundarban (40 Wm−2) indicating large forcing over entire IGB, from foothills of the Himalayas to coastal region. This winter-time continental haze also causes about similar radiative heating (1.5 K·day−1) from Siliguri to Sundarban which is enhanced over Kolkata (3 K·day−1) due to large emission of local urban aerosols. This high aerosol heating over entire IGB and coastal region of BoB can have considerable impact on the monsoonal circulation and more importantly, such haze transported over to

  19. An integrated campaign for investigation of winter-time continental haze over Indo-Gangetic Basin and its radiative effects

    Energy Technology Data Exchange (ETDEWEB)

    Das, Sanat Kumar, E-mail: sanatkrdas@gmail.com [Environmental Sciences Section, Bose Institute, Kolkata (India); Center for Astroparticle Physics and Space Science, Bose Institute, Kolkata (India); Chatterjee, Abhijit [Environmental Sciences Section, Bose Institute, Kolkata (India); Center for Astroparticle Physics and Space Science, Bose Institute, Kolkata (India); National Facility on Astroparticle Physics and Space Science, Darjeeling (India); Ghosh, Sanjay K. [Center for Astroparticle Physics and Space Science, Bose Institute, Kolkata (India); National Facility on Astroparticle Physics and Space Science, Darjeeling (India); Raha, Sibaji [Environmental Sciences Section, Bose Institute, Kolkata (India); Center for Astroparticle Physics and Space Science, Bose Institute, Kolkata (India); National Facility on Astroparticle Physics and Space Science, Darjeeling (India)

    2015-11-15

    An outflow of continental haze occurs from Indo-Gangetic Basin (IGB) in the North to Bay of Bengal (BoB) in the South. An integrated campaign was organized to investigate this continental haze during December 2013–February 2014 at source and remote regions within IGB to quantify its radiative effects. Measurements were carried out at three locations in eastern India; 1) Kalas Island, Sundarban (21.68°N, 88.57°E) — an isolated island along the north-east coast of BoB, 2) Kolkata (22.57°N, 88.42°E) — an urban metropolis and 3) Siliguri (26.70°N, 88.35°E) — an urban region at the foothills of eastern Himalayas. Ground-based AOD (at 0.5 μm) is observed to be maximum (1.25 ± 0.18) over Kolkata followed by Siliguri (0.60 ± 0.17) and minimum over Sundarban (0.53 ± 0.18). Black carbon concentration is found to be maximum at Kolkata (21.6 ± 6.6 μg·m{sup −3}) with almost equal concentrations at Siliguri (12.6 ± 5.2 μg·m{sup −3}) and Sundarban (12.3 ± 3.0 μg·m{sup −3}). Combination of MODIS-AOD and back-trajectories analysis shows an outflow of winter-time continental haze originating from central IGB and venting out through Sundarban towards BoB. This continental haze with high extinction coefficient is identified up to central BoB using CALIPSO observations and is found to contribute ~ 75% to marine AOD over central BoB. This haze produces significantly high aerosol radiative forcing within the atmosphere over Kolkata (75.4 Wm{sup −2}) as well as over Siliguri and Sundarban (40 Wm{sup −2}) indicating large forcing over entire IGB, from foothills of the Himalayas to coastal region. This winter-time continental haze also causes about similar radiative heating (1.5 K·day{sup −1}) from Siliguri to Sundarban which is enhanced over Kolkata (3 K·day{sup −1}) due to large emission of local urban aerosols. This high aerosol heating over entire IGB and coastal region of BoB can have considerable impact on the monsoonal circulation and more

  20. Upper limits of possible photochemical hazes on Pluto

    International Nuclear Information System (INIS)

    Elliot et al. [1989] invoked a haze layer near the surface of Pluto to explain certain features of a stellar occultation by that planet in June, 1988. The primary requirements for this haze layer were that it achieve unity tangential optical depth at a radius of 1174 km and be essentially transparent above 1189 km. The authors explore here the possibility that aerosols generated through methane photolysis could be responsible for such a haze layer. A comprehensive model of aerosol production, particle growth, sedimentation and condensation is applied to the atmosphere of Pluto using pressures, temperatures and composition derived from the stellar occultation and other data. They test two atmosphere models proposed in the literature, one from Elliot et al. [1989], and one from Hubbard et al. [1989], as well as a range of optical properties for the particles. In order to produce a haze with unity tangential optical depth at 1174 km, they had to use an aerosol mass production rate equal to twice the total methane dissociation rate due to solar UV expected for Pluto and assume that the particles produced were 10 times more absorbing than those in other hazes in the outer solar system. The possibility of condensation in the atmosphere was considered but did not result in distinctly different haze optical depths. If a photochemical haze on Pluto was responsible for the occultation lightcurve measured by Elliot et al., operation of a photochemical system different from those on Titan, Uranus or Neptune is indicated

  1. Slicing The 2010 Saturn's Storm: Upper Clouds And Hazes

    Science.gov (United States)

    Perez-Hoyos, Santiago; Sanz-Requena, J. F.; Sanchez-Lavega, A.; Hueso, R.

    2012-10-01

    At the end of 2010 a small storm erupted in Saturn's northern mid-latitudes. Starting from a localized perturbation, it grew up to be a global-scale disturbance and cover the whole latitude band by February, 2011 (Fletcher et al. 2011, Science 332; Sánchez-Lavega et al. 2011, Nature 475; Fischer et al. 2011, Nature 475). By June, 2011 the storm was facing its end and gradually disappeared (Sánchez-Lavega et al. 2012, Icarus 220). In this work we use the observations acquired by the Cassini ISS instrument during the whole process to investigate the vertical cloud and haze structure above the ammonia condensation level (roughly 1 bar). Cassini ISS observations cover visual wavelengths from the blue to the near-infrared including two methane absorption bands. Such observations have been modeled using a radiative transfer code which reproduces the atmospheric reflectivity as a function of observation/illumination geometry and wavelength together with a retrieval technique to find maximum likelihood atmospheric models. This allows to investigate some atmospheric parameters: cloud-top pressures, aerosol optical thickness and particle absorption, among others. We will focus on two aspects: (1) maximum likelihood models for the undisturbed reference atmosphere in the 15°N to 45°N band before and after the disturbance; (2) models for particular structures during the development of the global-scale phenomenon. Our results show a general increase of particle density and single-scattering albedo inside the storm. However, some discrete features showing anomalous structure and related to the storm peculiar dynamics will also be discussed. Acknowledgments: This work was supported by the Spanish MICIIN project AYA2009-10701 with FEDER funds, by Grupos Gobierno Vasco IT-464-07 and by Universidad País Vasco UPV/EHU through program UFI11/55.

  2. Wavelength-Scale Structures as Extremely High Haze Films for Efficient Polymer Solar Cells.

    Science.gov (United States)

    Ham, Juyoung; Dong, Wan Jae; Jung, Gwan Ho; Lee, Jong-Lam

    2016-03-01

    Wavelength-scale inverted pyramid structures with low reflectance and excellent haze have been designed for application to polymer solar cells (PSCs). The wavelength-scale structured haze films are fabricated on the back surface of glass without damages to organic active layer by using a soft lithographic technique with etched GaN molds. With a rigorous coupled-wave analysis of optical modeling, we find the shift of resonance peaks with the increase of pattern's diameter. Wavelength-scale structures could provide the number of resonances at the long wavelength spectrum (λ = 650-800 nm), yielding enhancement of power conversion efficiency (PCE) in the PSCs. Compared with a flat device (PCE = 7.12%, Jsc = 15.6 mA/cm(2)), improved PCE of 8.41% is achieved in a haze film, which is mainly due to the increased short circuit current density (Jsc) of 17.5 mA/cm(2). Hence, it opens up exciting opportunities for a variety of PSCs with wavelength-scale structures to further improve performance, simplify complicated process, and reduce costs. PMID:26901630

  3. Wavelength-Scale Structures as Extremely High Haze Films for Efficient Polymer Solar Cells.

    Science.gov (United States)

    Ham, Juyoung; Dong, Wan Jae; Jung, Gwan Ho; Lee, Jong-Lam

    2016-03-01

    Wavelength-scale inverted pyramid structures with low reflectance and excellent haze have been designed for application to polymer solar cells (PSCs). The wavelength-scale structured haze films are fabricated on the back surface of glass without damages to organic active layer by using a soft lithographic technique with etched GaN molds. With a rigorous coupled-wave analysis of optical modeling, we find the shift of resonance peaks with the increase of pattern's diameter. Wavelength-scale structures could provide the number of resonances at the long wavelength spectrum (λ = 650-800 nm), yielding enhancement of power conversion efficiency (PCE) in the PSCs. Compared with a flat device (PCE = 7.12%, Jsc = 15.6 mA/cm(2)), improved PCE of 8.41% is achieved in a haze film, which is mainly due to the increased short circuit current density (Jsc) of 17.5 mA/cm(2). Hence, it opens up exciting opportunities for a variety of PSCs with wavelength-scale structures to further improve performance, simplify complicated process, and reduce costs.

  4. Light extraction efficiency enhancement of GaN-based blue LEDs based on ITO/ InxO ohmic contacts with microstructure formed by annealing in oxygen.

    Science.gov (United States)

    Luo, Yi; Bai, Yiming; Han, Yanjun; Li, Hongtao; Wang, Lai; Wang, Jian; Sun, Changzheng; Hao, Zhibiao; Xiong, Bing

    2016-05-16

    Indium tin oxide (ITO)/ indium oxide (InxO) double layer structure was adopted as the transparent conduction and light scattering function layer to improve the light extraction efficiency of the GaN-based blue LEDs. The double layer structure was first deposited in one run by electron beam evaporation using ITO and Indium as the source respectively, and then annealed in an oxygen environment. This method can fabricate transparent electrode with microstructure and low specific contact resistivity one time free from lithography and etching, which makes the fabrication process simple and at a ower cost. For the 220 nm ITO/ 170 nm InxO double layer sample annealed at 600°C for 15 min in oxygen, measurement results show that its root mean square of roughness of the surface microstructure can be as high as 85.2 nm which introduces the strongest light scattering. Its light transmittance at 450 nm can maintain 92.4%. At the same time, it can realize lower specific contact resistivity with p-InGaN. Compared with the GaN-based blue LEDs with only 220 nm ITO electrode, the light output power of the LEDs with 220 nm ITO/ 170 nm InxO double layer structure can be increased about 58.8%, and working voltage at 20 mA injection current is decreased about 0.23 V due to the enhanced current spreading capability. The light output power improvement is also theoretically convinced by finite difference time domain simulations. PMID:27409953

  5. Compositions and pollutant sources of haze in Beijing urban sites.

    Science.gov (United States)

    Wang, Junmei; Song, Yujun; Zuo, Jiangnan; Wu, Hongwen

    2016-05-01

    Haze from urban sites in Beijing was collected with a self-assembled electrostatic dust collector. The sizes and morphologies, thermal properties, and compositions of the particles in the haze were characterized by scanning electronic microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), and X-ray photoelectric spectroscopy (XPS), respectively. Based on these results, the causes and pollutant sources of the chemicals in the haze were analyzed, and some countermeasures were further advanced to reduce the related pollutant sources. Graphical abstract ᅟ. PMID:26810665

  6. Compositions and pollutant sources of haze in Beijing urban sites.

    Science.gov (United States)

    Wang, Junmei; Song, Yujun; Zuo, Jiangnan; Wu, Hongwen

    2016-05-01

    Haze from urban sites in Beijing was collected with a self-assembled electrostatic dust collector. The sizes and morphologies, thermal properties, and compositions of the particles in the haze were characterized by scanning electronic microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), and X-ray photoelectric spectroscopy (XPS), respectively. Based on these results, the causes and pollutant sources of the chemicals in the haze were analyzed, and some countermeasures were further advanced to reduce the related pollutant sources. Graphical abstract ᅟ.

  7. Scattering and extinction: interpreting hazes in stellar occultation data

    Science.gov (United States)

    Bosh, Amanda S.; Levine, Stephen; Sickafoose, Amanda A.; Person, Michael J.

    2016-10-01

    There has been debate concerning interpretation of stellar occultation data and whether those data contain evidence for hazes within Pluto's atmosphere. Multiple layers of haze have been imaged in at Pluto with the New Horizons spacecraft; color-dependent differences in minimum flux from stellar occultations also suggests haze. We look at a purely geometric approach, to evaluate whether it is valid to sidestep details of atmospheric temperature structure and, in an approximate manner, conduct an analysis of the 2015 stellar occultation data that is consistent with the New Horizons imaging results. Support for this work was provided by NASA SSO grant NNX15AJ82G to Lowell Observatory.

  8. Regional Haze Evolved from Peat Fires - an Overview

    Science.gov (United States)

    Hu, Yuqi; Rein, Guillermo

    2016-04-01

    This work provides an overview of haze episodes, their cause, emissions and health effects found in the scientific literature. Peatlands, the terrestrial ecosystems resulting from the accumulation of partially decayed vegetation, become susceptible to smouldering fires because of natural droughts or anthropogenic-induced drainages. Once ignited, smouldering peat fires persistently consume large amounts of soil carbon in a flameless form. It is estimated that the average annual carbon gas emissions (mainly CO2 and CO) from peat fires are equivalent to 15% of manmade emissions, representing influential perturbation of global carbon circle. In addition to carbon emissions, smouldering peat fires emit substantial quantities of heterogeneous smoke, which is responsible for haze phenomena, has not yet been fully studied. Peat-fire-derived smoke is characterized by high concentration of particulate matter (PM), ranging from nano-scale ultrafine fraction (PM1, particle diameter tourism and agriculture-based industries. For example, an unprecedented peatland mega-fire burst on the Indonesian islands Kalimantan and Sumatra during the 1997 El-Niño event, resulting in transboundary smoke-haze disaster. Severe haze events continue to appear in Southeast Asia every few years due to periodical peat fires in this region. In addition, smouldering peat fires have been frequently reported in tropical, temperate and boreal regions (Botswana in 2000, North America in 2004, Scotland in 2006 and Central Russia in 2010 et al.), peat-fire-induced haze has become a regional seasonal phenomenon. Exposure to smoky haze results in deleterious physiologic responses, predominantly to the respiratory and cardiovascular systems. In 1997, an estimation of 100 million people in 5 countries in Southeast Asia were affected by Indonesia haze episode while 20 million people suffered from respiratory problems in Indonesia alone. Fine PM fraction generated from peat fires could penetrate into lower

  9. Aerosol characterization over the North China Plain: Haze life cycle and biomass burning impacts in summer

    Science.gov (United States)

    Sun, Yele; Jiang, Qi; Xu, Yisheng; Ma, Yan; Zhang, Yingjie; Liu, Xingang; Li, Weijun; Wang, Fei; Li, Jie; Wang, Pucai; Li, Zhanqing

    2016-03-01

    The North China Plain experiences frequent severe haze pollution during all seasons. Here we present the results from a summer campaign that was conducted at Xianghe, a suburban site located between the megacities of Beijing and Tianjin. Aerosol particle composition was measured in situ by an Aerosol Chemical Speciation Monitor along with a suite of collocated measurements during 1-30 June 2013. Our results showed that aerosol composition at the suburban site was overall similar to that observed in Beijing, which was mainly composed of organics (39%), nitrate (20%), and sulfate (18%). Positive matrix factorization of organic aerosol (OA) identified four OA factors with different sources and processes. While secondary organic aerosol dominated OA, on average accounting for 70%, biomass burning OA (BBOA) was also observed to have a considerable contribution (11%) for the entire study period. The contribution of BBOA was increased to 21% during the BB period in late June, indicating a large impact of agricultural burning on air pollution in summer. Biomass burning also exerted a significant impact on aerosol optical properties. It was estimated that ~60% enhancement of absorption at the ultraviolet spectral region was caused by the organic compounds from biomass burning. The formation mechanisms and sources of severe haze pollution episodes were investigated in a case study. The results highlighted two different mechanisms, i.e., regional transport and local sources, driving the haze life cycles differently in summer in the North China Plain. While secondary aerosol species dominated aerosol composition in the episode from regional transport, organics and black carbon comprised the major fraction in the locally formed haze episode.

  10. Detection of haze and/or cloud

    Science.gov (United States)

    Mukai, Sonoyo; Sano, Itaru; Mukai, Makiko; Kokhanovsky, Alexander

    2015-04-01

    It is highly likely that large-scale air pollution will continue to occur because air pollution becomes severe due to both the increasing emissions of the anthropogenic aerosols and the complicated behavior of natural aerosols, especially in Asia. It is natural to consider that incident solar light multiply interacts with the atmospheric aerosols due to dense radiation field in such a heavy haze. Accordingly efficient and practical algorithms for radiation simulation are indispensable to retrieve aerosol characteristics in a hazy atmosphere. It has been shown that aerosol retrieval in the hazy atmosphere is achieved based on MSOS (method of successive order of scattering) [1]. The satellite polarimetric sensor POLDER-1, 2, 3 has shown that the spectro-photopolarimetry of the terrestrial atmosphere is very useful for the observation of the Earth, especially for atmospheric particles. JAXA has been developing the new Earth observing system, GCOM satellite. GCOM-C will board the polarimetric sensor SGLI (second-generation global imager) in 2017. The SGLI has two polarization channels at near-infrared wavelengths of 670 and 870 nm. Furthermore, EUMETSAT plans to collect polarization measurements with a POLDER follow on 3MI/EPS-SG in 2021. Then the efficient algorithms for radiation simulation in the optically thick atmosphere by using polarization information denoted by Stokes parameters are shown in this work. It is of interest to mention that multi-spectral data are available for detection and/or distinction of hazy aerosol and/or cloud. In this work our MSOS is expected to be available for atmospheric particle retrieval in a mixture case of cloud and haze. The MSOS is available for the radiation simulation reflected from the optically semi-infinite atmosphere.[1]. Here we intend to improve MSOS-scalar into more efficient and practical form, and further into MSOS-vector form. We show here that a dense aerosol episode can be well simulated by a semi-infinite radiation

  11. Clouds and Hazes in Exoplanet Atmospheres

    CERN Document Server

    Marley, Mark S; Cuzzi, Jeffrey N; Kitzmann, Daniel

    2013-01-01

    Clouds and hazes are commonplace in the atmospheres of solar system planets and are likely ubiquitous in the atmospheres of extrasolar planets as well. Clouds affect every aspect of a planetary atmosphere, from the transport of radiation, to atmospheric chemistry, to dynamics and they influence - if not control - aspects such as surface temperature and habitability. In this review we aim to provide an introduction to the role and properties of clouds in exoplanetary atmospheres. We consider the role clouds play in influencing the spectra of planets as well as their habitability and detectability. We briefly summarize how clouds are treated in terrestrial climate models and consider the far simpler approaches that have been taken so far to model exoplanet clouds, the evidence for which we also review. Since clouds play a major role in the atmospheres of certain classes of brown dwarfs we briefly discuss brown dwarf cloud modeling as well. We also review how the scattering and extinction efficiencies of cloud p...

  12. Energetics study of West African dust haze

    International Nuclear Information System (INIS)

    The causes of the large and often persistent negative anomalies of equivalent potential temperature observed in the 900-700 hpa layer and which occurs in association with dust haze outbreaks over Kano in winter is investigated. Energetics results indicate that the primary mechanism for such anomalies is the horizontal transport of drier and, to a lesser extent, colder air at the upper levels by eddy motions, with consequent destabilization of the atmospheric boundary layer over the station. This is suggested as the mobilization mechanism responsible for raising dust from the surface over the Bilma/Faya-Largeau source region much further poleward. Temperature inversions were also found to be more pronounced during dust spells than in clear periods. (author). 18 refs, 6 figs, 2 tabs

  13. A new structure of p-GaN/InGaN heterojunction to enhance hole injection for blue GaN-based LEDs

    Science.gov (United States)

    Lin, Zhiting; Wang, Haiyan; Lin, Yunhao; Yang, Meijuan; Li, Guoqiang; Xu, Bingshe

    2016-07-01

    A new structure of p-GaN/InGaN heterojunction has been proposed to enhance hole injection for blue GaN-based light-emitting diodes (LEDs). It is demonstrated by the simulation results that a p-GaN (50 nm)/In0.05Ga0.95N (150 nm) heterojunction can make a 25% and 10% increment of hole and electron concentration in the active region, respectively, finally resulting in a 55% improvement on the LED’s radiative recombination intensity. The simulation also reveals that the efficiency droop is alleviated from 32.9% to 21.7% at the current density of 100 A cm‑2. The enhanced hole injection is mainly attributed to the increased average background hole concentration of the area between the p-AlGaN electron blocking layer (EBL) to the p-GaN/InGaN heterojunction. The increasing potential barrier of the conduction band, resulting from the introduction of p-GaN/InGaN heterojunction, would also weaken electron leakage and is favorable to the LED’s luminous performance. The experimental results show that the wall-plug efficiency (WPE) of the p-GaN/InGaN LED increases by 26.0% at the injection current of 75 mA, in spite of the increasing electric resistance, which impairs the improvement of the LED’s performance from the enhanced hole injection. The structure of the p-GaN/InGaN heterojunction is novel in the field of p-type region design, and is a simple but effective way to promote the LED’s performance, which is very promising for application in further high-performance LED fabrication.

  14. Exploring the severe winter haze in Beijing

    Directory of Open Access Journals (Sweden)

    G. J. Zheng

    2014-07-01

    Full Text Available Extreme haze episodes repeatedly shrouded Beijing during the winter of 2012–2013, causing major environmental and health problems. To better understand these extreme events, we analyzed the hourly observation data of PM2.5 and its major chemical composition, with support of model simulations. Severe winter haze was shown to result from stable synoptic meteorological conditions over a large part of northeastern China, rather than from an abrupt increase in emissions. Build-up of secondary species, including organics, sulfate, nitrate, and ammonium, was the major driving force behind these polluted periods. The contribution of organic matter decreased with increasing pollution level while sulfate and nitrate contributions increased. Correspondingly, the ratio of secondary organic carbon to elemental carbon decreased and had a stable diurnal pattern during heavily polluted periods, indicating weakened photochemical activity due to the dimming effect of high loading of aerosol particles. Under such conditions, the strong increase in sulfate and nitrate contributions to PM2.5 was attributed to an elevated conversion ratio, reflecting more active heterogeneous reactions with gradually increasing relative humidity. Moreover, we found that high aerosol concentration was a regional phenomenon. The accumulation process of aerosol particles occurred successively from southeast cities to Beijing. The "apparent" sharp increase in PM2.5 concentration of up to several hundred μg m−3 per hour recorded in Beijing represented rapid "recovery" from an "interruption" to the continuous pollution accumulation over the region, rather than purely local chemical production. This suggests that regional transport of pollutants played an important role during these severe pollution events.

  15. Atmospheric Prebiotic Chemistry and Organic Hazes

    Science.gov (United States)

    Trainer, Melissa G.

    2012-01-01

    Earth's atmospheric composition at the time of the origin of life is not known, but it has often been suggested that chemical transformation of reactive species in the atmosphere was a significant source of pre biotic organic molecules. Experimental and theoretical studies over the past half century have shown that atmospheric synthesis can yield molecules such as amino acids and nucleobases, but these processes are very sensitive to gas composition and energy source. Abiotic synthesis of organic molecules is more productive in reduced atmospheres, yet the primitive Earth may not have been as reducing as earlier workers assumed, and recent research has reflected this shift in thinking. This work provides a survey of the range of chemical products that can be produced given a set of atmospheric conditions, with a particular focus on recent reports. Intertwined with the discussion of atmospheric synthesis is the consideration of an organic haze layer, which has been suggested as a possible ultraviolet shield on the anoxic early Earth. Since such a haze layer - if formed - would serve as a reservoir for organic molecules, the chemical composition of the aerosol should be closely examined. The results highlighted here show that a variety of products can be formed in mildly reducing or even neutral atmospheres, demonstrating that contributions of atmospheric synthesis to the organic inventory on early Earth should not be discounted. This review intends to bridge current knowledge of the range of possible atmospheric conditions in the prebiotic environment and pathways for synthesis under such conditions by examining the possible products of organic chemistry in the early atmosphere.

  16. Decadal variability in the occurrence of wintertime haze in central eastern China tied to the Pacific Decadal Oscillation.

    Science.gov (United States)

    Zhao, Sen; Li, Jianping; Sun, Cheng

    2016-06-10

    Haze is a serious issue in China with increasing concerns, and understanding the factors driving decadal-scale variations in haze occurrence is relevant for government policymaking. Using a comprehensive observational haze dataset, we demonstrate notable decadal fluctuations in the number of haze days (HD) during winter in central eastern China, showing a decline since the mid-1980s. The leading mode of the wintertime HD features an increasing trend for 1959-2012 in eastern China, highly correlated with China's gross domestic product (GDP) that represents increasing trend of pollutant emissions, and to a lesser extent meteorological factors. The second mode shows decadal variations in central eastern China associated with Pacific Decadal Oscillation (PDO). Observations and numerical simulations suggest that Mongolia High and corresponding descending motion tend to be enhanced (weakened) in central eastern China during the positive (negative) phase of PDO. With PDO shifting towards a negative phase, the weakened Mongolia High and ascending anomalies make the air unstable and conduce to the spread of pollutants, leading to the decline in the wintertime HD over central eastern China since the mid-1980s. Based on above physical mechanisms, a linear model based on PDO and GDP metrics provided a good fit to the observed HD.

  17. Decadal variability in the occurrence of wintertime haze in central eastern China tied to the Pacific Decadal Oscillation

    Science.gov (United States)

    Zhao, Sen; Li, Jianping; Sun, Cheng

    2016-06-01

    Haze is a serious issue in China with increasing concerns, and understanding the factors driving decadal-scale variations in haze occurrence is relevant for government policymaking. Using a comprehensive observational haze dataset, we demonstrate notable decadal fluctuations in the number of haze days (HD) during winter in central eastern China, showing a decline since the mid-1980s. The leading mode of the wintertime HD features an increasing trend for 1959–2012 in eastern China, highly correlated with China’s gross domestic product (GDP) that represents increasing trend of pollutant emissions, and to a lesser extent meteorological factors. The second mode shows decadal variations in central eastern China associated with Pacific Decadal Oscillation (PDO). Observations and numerical simulations suggest that Mongolia High and corresponding descending motion tend to be enhanced (weakened) in central eastern China during the positive (negative) phase of PDO. With PDO shifting towards a negative phase, the weakened Mongolia High and ascending anomalies make the air unstable and conduce to the spread of pollutants, leading to the decline in the wintertime HD over central eastern China since the mid-1980s. Based on above physical mechanisms, a linear model based on PDO and GDP metrics provided a good fit to the observed HD.

  18. Biomass-burning emissions and associated haze layers over Amazonia

    Science.gov (United States)

    Andreae, M. O.; Browell, E. V.; Gregory, G. L.; Harriss, R. C.; Hill, G. F.; Sachse, G. W.; Talbot, R. W.; Garstang, M.; Jacob, D. J.; Torres, A. L.

    1988-01-01

    The characteristics of haze layers, which were visually observed over the central Amazon Basin during many of the Amazon Boundary Layer Experiment 2A flights in July/August 1985, were investigated by remote and in situ measurements, using the broad range of instrumentation and sampling equipment on board the Electra aircraft. It was found that these layers strongly influenced the chemical and optical characteristics of the atmosphere over the eastern Amazon Basin. Relative to the regional background, the concentrations of CO, CO2, O3, and NO were significantly elevated in the plumes and haze layers, with the NO/CO ratio in fresh plumes much higher than in the aged haze layers. The haze aerosol was composed predominantly of organic material, NH4, K(+), NO3(-), SO4(2-), and organic anions (formate, acetate, and oxalate).

  19. Photochemical hazes in planetary atmospheres: solar system bodies and beyond

    Science.gov (United States)

    Imanaka, Hiroshi; Cruikshank, Dale P.; McKay, Christopher P.

    2015-11-01

    Recent transit observations of exoplanets have demonstrated the possibility of a wide prevalence of haze/cloud layers at high altitudes. Hydrocarbon photochemical haze could be the candidate for such haze particles on warm sub-Neptunes, but the lack of evidence for methane poses a puzzle for such hydrocarbon photochemical haze. The CH4/CO ratios in planetary atmospheres vary substantially from their temperature and dynamics. An understanding of haze formation rates and plausible optical properties in a wide diversity of planetary atmospheres is required to interpret the current and future observations.Here, we focus on how atmospheric compositions, specifically CH4/CO ratios, affect the haze production rates and their optical properties. We have conducted a series of cold plasma experiments to constrain the haze mass production rates from gas mixtures of various CH4/CO ratios diluted either in H2 or N2 atmosphere. The mass production rates in the N2-CH4-CO system are much greater than those in the H2-CH4-CO system. They are rather insensitive to the CH4/CO ratios larger than at 0.3. Significant formation of solid material is observed both in H2-CO and N2-CO systems without CH4 in the initial gas mixtures. The complex refractive indices were derived for haze samples from N2-CH4, H2-CH4, and H2-CO gas mixtures. These are the model atmospheres for Titan, Saturn, and exoplanets, respectively. The imaginary part of the complex refractive indices in the UV-Vis region are distinct among these samples, which can be utilized for modeling these planetary atmospheres.

  20. Characterization and estimation of human airway deposition of size-resolved particulate-bound trace elements during a recent haze episode in Southeast Asia.

    Science.gov (United States)

    Behera, Sailesh N; Betha, Raghu; Huang, Xian; Balasubramanian, Rajasekhar

    2015-03-01

    Toxic elements present in airborne particulate matter (PM) are associated with human health effects; however, their toxic characteristics depend on the source of their origins and their concentrations in ambient air. Twenty four elements (Al, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, K, Li, Mg, Mn, Na, Ni, Pb, Se, Sr, Te, Tl, and Zn) in 12 different size fractions of PM ranging from 10 nm to 10 μm were characterized in Singapore during two different atmospheric conditions (smoke haze and non-haze periods) in 2012 for the first time. In addition, their possible sources were identified based on backward air trajectory analysis and principal component analysis (PCA). The health implications of inhalable particles were assessed using a human airway deposition model, the Multiple-Path Particle Dosimetry model (MPPD). The results concerning particle-bound trace elements are interpreted in terms of coarse (PM2.5-10), fine (PM2.5), ultrafine (PM0.01-0.1, 0.01 μm haze episode and the non-haze period in coarse, fine, ultrafine, and nano particles varied from 1.2 (Bi) to 6.6 (Co). Both the PCA and backward trajectory analysis revealed that trans-boundary biomass-burning emissions from Indonesia were primarily responsible for enhanced concentrations of particulate-bound elements during the smoke haze episode. The particle depositions in the respiratory system were higher during the smoke haze episode compared to the non-haze period. The study finds that ultrafine and nano particles present in the atmosphere have higher tendencies to be deposited into the deeper parts of the respiratory system, compared to coarse and fine particles.

  1. Posthuman blues

    CERN Document Server

    Tonnies, Mac

    2013-01-01

    Posthuman Blues, Vol. I is first volume of the edited version of the popular weblog maintained by author Mac Tonnies from 2003 until his tragic death in 2009. Tonnies' blog was a pastiche of his original fiction, reflections on his day-to-day life, trenchant observations of current events, and thoughts on an eclectic range of material he culled from the Internet. What resulted was a remarkably broad portrait of a thoughtful man and the complex times in which he lived, rendered with intellige...

  2. Effect of operational parameters on the decolorization of C.I. Reactive Blue 19 in aqueous solution by ozone-enhanced electrocoagulation

    Energy Technology Data Exchange (ETDEWEB)

    Song Shuang; Yao Jie [College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310032 (China); He Zhiqiao [College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310032 (China)], E-mail: zqhe@zjut.edu.cn; Qiu Jianping; Chen Jianmeng [College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310032 (China)

    2008-03-21

    The aim of this paper was to investigate the efficiency of the ozone-enhanced electrocoagulation (EC) process in the decolorization of C.I. Reactive Blue 19 in water using iron electrodes. We determined the effects of various operating parameters such as initial pH, initial dye concentration, current density, salt concentration, temperature, ozone flow rate, and distance between electrodes on decolorization efficiency in a laboratory-scale reactor. Increasing the initial dye concentration decreased the decolorization efficiency, whereas increasing the distance between electrodes increased it. The other operating factors had both positive and negative effects. With an initial pH of 10.0, an initial dye concentration of 100 mg/L, current density of 10 mA/cm{sup 2}, salt concentration of 3000 mg/L, temperature of 30 deg. C, ozone flow rate of 20 mL/min, and distance between electrodes of 3 cm, over 96% of the color was removed after 10 min. As a consequence, removal of total organic carbon (TOC) was over 80%.

  3. Analysis on the Change Characteristics of Haze in Dezhou City in Recent 40 Years

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    [Objective] The aim was to analyze the change characteristics of haze in Dezhou City. [Method] Based on the data of haze and sunshine duration from 11 counties or cities in Dezhou City from 1970 to 2009, the daily, monthly, seasonal and annual variation of haze and their variation reasons were studied, meanwhile, the effects of haze on sunshine duration were discussed. [Result] Haze occurred most frequently from 09:00 to 14:00 and daily variation was different in various seasons; haze days were the most in ...

  4. Synthesis and Characterization of Ag-Ag2O/TiO2@polypyrrole Heterojunction for Enhanced Photocatalytic Degradation of Methylene Blue

    Directory of Open Access Journals (Sweden)

    Rajeev Kumar

    2016-05-01

    Full Text Available Hybrid multi-functional nanomaterials comprising two or more disparate materials have become a powerful approach to obtain advanced materials for environmental remediation applications. In this work, an Ag-Ag2O/TiO2@polypyrrole (Ag/TiO2@PPy heterojunction has been synthesized by assembling a self-stabilized Ag-Ag2O (p type semiconductor (denoted as Ag and polypyrrole (π-conjugated polymer on the surface of rutile TiO2 (n type. Ag/TiO2@PPy was synthesized through simultaneous oxidation of pyrrole monomers and reduction of AgNO3 in an aqueous solution containing well-dispersed TiO2 particles. Thus synthesized Ag/TiO2@PPy was characterized using X-ray diffraction (XRD, X-ray photoelectron spectroscopy (XPS, field emission scanning electron microscopy (FE-SEM, transmission electron microscopy (TEM, and UV-Vis diffuse reflectance spectroscopy (UV-vis DSR. The photocatalytic activity of synthesized heterojunction was investigated for the decomposition of methylene blue (MB dye under UV and visible light irradiation. The results revealed that π-conjugated p-n heterojunction formed in the case of Ag/TiO2@PPy significantly enhanced the photodecomposition of MB compared to the p-n type Ag/TiO2 and TiO2@PPy (n-π heterojunctions. A synergistic effect between Ag-Ag2O and PPy leads to higher photostability and a better electron/hole separation leads to an enhanced photocatalytic activity of Ag/TiO2@PPy under both UV and visible light irradiations.

  5. Size-resolved aerosol chemical analysis of extreme haze pollution events during early 2013 in urban Beijing, China

    Energy Technology Data Exchange (ETDEWEB)

    Tian, Shili; Pan, Yuepeng, E-mail: panyuepeng@mail.iap.ac.cn; Liu, Zirui; Wen, Tianxue; Wang, Yuesi, E-mail: wys@mail.iap.ac.cn

    2014-08-30

    Highlights: • Anthropogenic species substantially accumulated in both fine and coarse particles. • Secondary organic carbon in PM{sub 1.1} decreased from clear to haze days. • The mass peak shifted to larger particles from clear to haze days. • The NO{sub 3}{sup −}/SO{sub 4}{sup 2−} ratio decreased with enhanced haze pollution. • Both mobile local and stationary regional sources were vital for haze formation. - Abstract: Using size-resolved filter sampling and chemical characterization, high concentrations of water-soluble ions, carbonaceous species and heavy metals were found in both fine (PM{sub 2.1}) and coarse (PM{sub 2.1–9}) particles in Beijing during haze events in early 2013. Even on clear days, average mass concentration of submicron particles (PM{sub 1.1}) was several times higher than that previously measured in most of abroad urban areas. A high concentration of particulate matter on haze days weakens the incident solar radiation, which reduces the generation rate of secondary organic carbon in PM{sub 1.1}. We show that the peak mass concentration of particles shifted from 0.43–0.65 μm on clear days to 0.65–1.1 μm on lightly polluted days and to 1.1–2.1 μm on heavily polluted days. The peak shifts were also found for the following species: organic carbon, elemental carbon, NH{sub 4}{sup +}, SO{sub 4}{sup 2−}, NO{sub 3}{sup −}, K, Cu, Zn, Cd and Pb. Our findings demonstrate that secondary inorganic aerosols (36%) and organic matter (26%) dominated the fine particle mass on heavily polluted days, while their contribution reduced to 29% and 18%, respectively, on clear days. Besides fine particles, anthropogenic chemical species also substantially accumulated in the coarse mode, which suggests that particles with aerodynamic diameter larger than 2.1 μm cannot be neglected during severe haze events.

  6. Determination and analysis of trace metals and surfactant in air particulate matter during biomass burning haze episode in Malaysia

    Science.gov (United States)

    Ahmed, Manan; Guo, Xinxin; Zhao, Xing-Min

    2016-09-01

    Trace metal species and surface active agent (surfactant) emitted into the atmosphere from natural and anthropogenic source can cause various health related and environmental problems. Limited data exists for determinations of atmospheric particulate matter particularly trace metals and surfactant concentration in Malaysia during biomass burning haze episode. We used simple and validated effective methodology for the determination of trace metals and surfactant in atmospheric particulate matter (TSP & PM2.5) collected during the biomass burning haze episode in Kampar, Malaysia from end of August to October 2015. Colorimetric method of analysis was undertaken to determine the concentration of anionic surfactant as methylene blue active substance (MBAS) and cationic surfactant as disulphine blue active substance (DBAS) using a UV-Visible spectrophotometer. Particulate samples were also analyzed for trace metals with inductive coupled plasma mass spectrometer (ICP-MS) followed by extraction from glass microfiber filters with close vessel microwave acid digestion. The result showed that the concentrations of surfactant in both samples (TSP & PM2.5) were dominated by MBAS (0.147-4.626 mmol/m3) rather than DBAS (0.111-0.671 mmol/m3) and higher than the other researcher found. Iron (147.31-1381.19 μg/m3) was recorded leading trace metal in PM followed by Al, Zn, Pb, Cd, Cr and others. During the haze period the highest mass concentration of TSP 313.34 μg/m3 and 191.07 μg/m3 for PM2.5 were recorded. Furthermore, the backward air trajectories from Kampar in north of peninsular Malaysia confirmed that nearly all the winds paths originate from Sumatera and Kalimantan, Indonesia.

  7. Condensation in Saturn's Stratospheric Haze Layers

    Science.gov (United States)

    Barth, Erika L.; Moses, Julianne I.

    2016-10-01

    Haze particles in Saturn's stratosphere can be seen in the visible limb images of Cassini's Imaging Science Subsystem (ISS). These hazes are likely a mix of particles, including solid organics formed as a result of methane photolysis and electron deposition, as well as the condensation of water and hydrocarbon ices. We have examined data from both Cassini and Voyager to study the detailed vertical structure of absorbing/scattering particulates in Saturn's stratosphere and developed a Saturn version of the Community Aerosol and Radiation Model for Atmospheres (CARMA), adding a large database of hydrocarbons that are observed or expected to be present in Saturn's atmosphere.Our modeling indicates that water ice condenses independently of the hydrocarbons to form a thin layer above the 0.1 mbar pressure level. Between about 5 and 50 mbar, the hydrocarbons reach their condensation levels (in order of increasing pressure level): C6H6, C5H12, C4H2, C4H10, and C2H2. Because of the proximity of their condensation levels and due to the gravitational settling of the particles, the hydrocarbons are likely condensing on one another and forming a thicker layer of mixed composition. Interestingly, butane (C4H10) has a triple point around 135 K which is much lower than most of the other condensing species we've explored. Given an approximate condensation level of 10 mbar and the observed temperature changes at this pressure level following the December 2010 northern-hemisphere storm (stratospheric temperatures were elevated by as much as 50-70 K in a region near 40° N latitude.), melting and further nucleation of droplets could be occurring.A number of factors including temperature profile, vapor pressure equation, volatile abundance, nucleation critical saturation, and coagulation efficiency will affect the altitudes of the individual ice layers. We will present a summary of results following the nucleation and growth of compounds in order to quantify the likely size and

  8. Size-resolved source apportionment of particulate matter in urban Beijing during haze and non-haze episodes

    Science.gov (United States)

    Tian, S. L.; Pan, Y. P.; Wang, Y. S.

    2016-01-01

    Additional size-resolved chemical information is needed before the physicochemical characteristics and sources of airborne particles can be understood; however, this information remains unavailable in most regions of China due to lacking measurement data. In this study, we report observations of various chemical species in size-segregated particle samples that were collected over 1 year in the urban area of Beijing, a megacity that experiences severe haze episodes. In addition to fine particles, high concentrations of coarse particles were measured during the periods of haze. The abundance and chemical compositions of the particles in this study were temporally and spatially variable, with major contributions from organic matter and secondary inorganic aerosols. The contributions of organic matter to the particle mass decreased from 37.9 to 31.2 %, and the total contribution of sulfate, nitrate and ammonium increased from 19.1 to 33.9 % between non-haze and haze days, respectively. Due to heterogeneous reactions and hygroscopic growth, the peak concentrations of the organic carbon, cadmium and sulfate, nitrate, ammonium, chloride and potassium shifted from 0.43 to 0.65 µm on non-haze days to 0.65-1.1 µm on haze days. Although the size distributions of lead and thallium were similar during the observation period, their concentrations increased by a factor of more than 1.5 on haze days compared with non-haze days. We observed that sulfate and ammonium, which have a size range of 0.43-0.65 µm, sulfate and nitrate, which have a size range of 0.65-1.1 µm, calcium, which has a size range of 5.8-9 µm, and the meteorological factors of relative humidity and wind speed were responsible for haze pollution when the visibility was less than 10 km. Source apportionment using Positive Matrix Factorization showed six PM2.1 sources and seven PM2.1-9 common sources: secondary inorganic aerosol (25.1 % for fine particles vs. 9.8 % for coarse particles), coal combustion (17

  9. Elucidating severe urban haze formation in China

    Science.gov (United States)

    Guo, Song; Hu, Min; Zamora, Misti L.; Peng, Jianfei; Shang, Dongjie; Zheng, Jing; Du, Zhuofei; Wu, Zhijun; Shao, Min; Zeng, Limin; Molina, Mario J.; Zhang, Renyi

    2014-12-01

    As the world's second largest economy, China has experienced severe haze pollution, with fine particulate matter (PM) recently reaching unprecedentedly high levels across many cities, and an understanding of the PM formation mechanism is critical in the development of efficient mediation policies to minimize its regional to global impacts. We demonstrate a periodic cycle of PM episodes in Beijing that is governed by meteorological conditions and characterized by two distinct aerosol formation processes of nucleation and growth, but with a small contribution from primary emissions and regional transport of particles. Nucleation consistently precedes a polluted period, producing a high number concentration of nano-sized particles under clean conditions. Accumulation of the particle mass concentration exceeding several hundred micrograms per cubic meter is accompanied by a continuous size growth from the nucleation-mode particles over multiple days to yield numerous larger particles, distinctive from the aerosol formation typically observed in other regions worldwide. The particle compositions in Beijing, on the other hand, exhibit a similarity to those commonly measured in many global areas, consistent with the chemical constituents dominated by secondary aerosol formation. Our results highlight that regulatory controls of gaseous emissions for volatile organic compounds and nitrogen oxides from local transportation and sulfur dioxide from regional industrial sources represent the key steps to reduce the urban PM level in China.

  10. The impact of haze on the adolescent's acute respiratory disease: A single institution study

    Directory of Open Access Journals (Sweden)

    Wan Fairos Wan Yaacob

    2016-05-01

    Conclusions: Student with haze effect documented much higher symptoms during haze especially female students. Symptoms such as headache, wheezing and mucus were noted among the normal secondary school children in Kota Bharu.

  11. 77 FR 24952 - Agency Information Collection Activities; Proposed Collection; Comment Request; Regional Haze...

    Science.gov (United States)

    2012-04-26

    ... ICR (August 26, 2009; 74 FR 43118). The last collection request anticipated the program progressing... AGENCY Agency Information Collection Activities; Proposed Collection; Comment Request; Regional Haze... organizations and facilities potentially regulated under the regional haze rule. Title: Regional...

  12. 77 FR 76173 - Approval and Promulgation of Implementation Plans; State of Washington; Regional Haze State...

    Science.gov (United States)

    2012-12-26

    ... Implementation Plans; State of Washington; Regional Haze State Implementation Plan; Federal Implementation Plan for Best Available Retrofit Technology for Alcoa Intalco Operations and Tesoro Refining and Marketing... Plans; State of Washington; Regional Haze State Implementation Plan; Federal Implementation Plan...

  13. A critical evaluation of the ability of the Spinning Enhanced Visible and Infrared Imager (SEVIRI) thermal infrared red-green-blue rendering to identify dust events: Theoretical analysis

    Science.gov (United States)

    Brindley, Helen; Knippertz, Peter; Ryder, Claire; Ashpole, Ian

    2012-04-01

    Using a combination of idealized radiative transfer simulations and a case study from the first field campaign of the Saharan Mineral Dust Experiment (SAMUM) in southern Morocco, this paper provides a systematic assessment of the limitations of the widely used Spinning Enhanced Visible and Infrared Imager (SEVIRI) red-green-blue (RGB) thermal infrared dust product. Both analyses indicate that the ability of the product to identify dust, via its characteristic pink coloring, is strongly dependent on the column water vapor, the lower tropospheric lapse rate, and dust altitude. In particular, when column water vapor exceeds ˜20-25 mm, dust presence, even for visible optical depths of the order 0.8, is effectively masked. Variability in dust optical properties also has a marked impact on the imagery, primarily as a result of variability in dust composition. There is a moderate sensitivity to the satellite viewing geometry, particularly in moist conditions. The underlying surface can act to confound the signal seen through variations in spectral emissivity, which are predominantly manifested in the 8.7μm SEVIRI channel. In addition, if a temperature inversion is present, typical of early morning conditions over the Sahara and Sahel, an increased dust loading can actually reduce the pink coloring of the RGB image compared to pristine conditions. Attempts to match specific SEVIRI observations to simulations using SAMUM measurements are challenging because of high uncertainties in surface skin temperature and emissivity. Recommendations concerning the use and interpretation of the SEVIRI RGB imagery are provided on the basis of these findings.

  14. Enhancing the Applicability of Satellite Remote Sensing for PM2.5 Estimation Using MODIS Deep Blue AOD and Land Use Regression in California, United States.

    Science.gov (United States)

    Lee, Hyung Joo; Chatfield, Robert B; Strawa, Anthony W

    2016-06-21

    We estimated daily ground-level PM2.5 concentrations combining Collection 6 deep blue (DB) Moderate Resolution Imaging Spectroradiometer (MODIS) aerosol optical depth (AOD) data (10 km resolution) with land use regression in California, United States, for the period 2006-2012. The Collection 6 DB method for AOD provided more reliable data retrievals over California's bright surface areas than previous data sets. Our DB AOD and PM2.5 data suggested that the PM2.5 predictability could be enhanced by temporally varying PM2.5 and AOD relations at least at a seasonal scale. In this study, we used a mixed effects model that allowed daily variations in DB AOD-PM2.5 relations. Because DB AOD might less effectively represent local source emissions compared to regional ones, we added geographic information system (GIS) predictors into the mixed effects model to further explain PM2.5 concentrations influenced by local sources. A cross validation (CV) mixed effects model revealed reasonably high predictive power for PM2.5 concentrations with R(2) = 0.66. The relations between DB AOD and PM2.5 considerably varied by day, and seasonally varying effects of GIS predictors on PM2.5 suggest season-specific source emissions and atmospheric conditions. This study indicates that DB AOD in combination with land use regression can be particularly useful to generate spatially resolved PM2.5 estimates. This may reduce exposure errors for health effect studies in California. We expect that more detailed PM2.5 concentration patterns can help air quality management plan to meet air quality standards more effectively.

  15. Enhancing the Applicability of Satellite Remote Sensing for PM2.5 Estimation Using MODIS Deep Blue AOD and Land Use Regression in California, United States.

    Science.gov (United States)

    Lee, Hyung Joo; Chatfield, Robert B; Strawa, Anthony W

    2016-06-21

    We estimated daily ground-level PM2.5 concentrations combining Collection 6 deep blue (DB) Moderate Resolution Imaging Spectroradiometer (MODIS) aerosol optical depth (AOD) data (10 km resolution) with land use regression in California, United States, for the period 2006-2012. The Collection 6 DB method for AOD provided more reliable data retrievals over California's bright surface areas than previous data sets. Our DB AOD and PM2.5 data suggested that the PM2.5 predictability could be enhanced by temporally varying PM2.5 and AOD relations at least at a seasonal scale. In this study, we used a mixed effects model that allowed daily variations in DB AOD-PM2.5 relations. Because DB AOD might less effectively represent local source emissions compared to regional ones, we added geographic information system (GIS) predictors into the mixed effects model to further explain PM2.5 concentrations influenced by local sources. A cross validation (CV) mixed effects model revealed reasonably high predictive power for PM2.5 concentrations with R(2) = 0.66. The relations between DB AOD and PM2.5 considerably varied by day, and seasonally varying effects of GIS predictors on PM2.5 suggest season-specific source emissions and atmospheric conditions. This study indicates that DB AOD in combination with land use regression can be particularly useful to generate spatially resolved PM2.5 estimates. This may reduce exposure errors for health effect studies in California. We expect that more detailed PM2.5 concentration patterns can help air quality management plan to meet air quality standards more effectively. PMID:27218887

  16. Haze Research in Brunei Darussalam During the 1998 Episode

    Science.gov (United States)

    Radojevic, M.

    - Brunei Darussalam experienced a severe haze episode between the beginning of February and the end of April 1998 due mainly to local peat and forest fires in Brunei and in neighbouring Sabah and Sarawak. The extensive research studies of the haze carried out in Brunei are outlined together with selected results. Particulate matter (PM10) was the only significant criteria pollutant and it exceeded WHO guidelines and accepted air quality standards on most days during the haze episode. Gaseous criteria pollutants (CO, SO2, NO2, O3) were generally well below WHO guidelines and at these concentrations they are expected to have no significant health or environmental effects. Measurements of volatile organic compounds (VOCs) revealed the presence of benzene, toluene, ethylbenzene, and xylenes (BTEX), aldehydes, phenol, and polynuclear aromatic hydrocarbons (PAHs). Personal exposure monitoring of PM10 revealed significant differences in exposure patterns between different individuals depending on the location, time and activity. Data on outpatient visits showed an increase for some illnesses (e.g., acute respiratory infection) during the months of haze. No significant impacts of haze on rainwater acidity or deposition were noted. Emission factors for some volatile compounds were determined in combustion experiments in which peat was burned at temperatures typical of smouldering.

  17. Variations of fine particle physiochemical properties during a heavy haze episode in the winter of Beijing.

    Science.gov (United States)

    Niu, Hongya; Hu, Wei; Zhang, Daizhou; Wu, Zhijun; Guo, Song; Pian, Wei; Cheng, Wenjing; Hu, Min

    2016-11-15

    Chemical composition, morphology, size and mixture of fine particles were measured in a heavy haze and the post-haze air in Beijing in January 2012. With the occurrence of haze, the concentrations of gaseous and particulate pollutants including organics, sulfate, nitrate, and ammonium grew gradually. The hourly averaged PM2.5 concentration increased from 118μgm(-3) to 402μgm(-3) within 12h. In contrast, it was less than 10μgm(-3) in the post-haze air. Occupying approximately 46% in mass, organics were the major component of PM1 in both the haze and post-haze air. Analysis of individual particles in the size range of 0.2-1.1μm revealed that secondary-like particles and soot particles were always the majority, and most soot particles had a core-shell structure. The number ratio of secondary-like particles to soot particles in accumulation mode in the haze air was about 2:1, and that in the post-haze air was 8:1. These results indicate both secondary particle formation and primary emission contributed substantially to the haze. The mode size of the haze particles was about 0.7μm, and the mode size of the post-haze particles was 0.4μm, indicating the remarkable growth of particles in haze. However, the ratios of the core size to shell size of core-shell structure soot particles in the haze were similar to those in the post-haze air, suggesting a quick aging of soot particles in either the haze air or the post-haze air. PMID:27470669

  18. Variations of fine particle physiochemical properties during a heavy haze episode in the winter of Beijing.

    Science.gov (United States)

    Niu, Hongya; Hu, Wei; Zhang, Daizhou; Wu, Zhijun; Guo, Song; Pian, Wei; Cheng, Wenjing; Hu, Min

    2016-11-15

    Chemical composition, morphology, size and mixture of fine particles were measured in a heavy haze and the post-haze air in Beijing in January 2012. With the occurrence of haze, the concentrations of gaseous and particulate pollutants including organics, sulfate, nitrate, and ammonium grew gradually. The hourly averaged PM2.5 concentration increased from 118μgm(-3) to 402μgm(-3) within 12h. In contrast, it was less than 10μgm(-3) in the post-haze air. Occupying approximately 46% in mass, organics were the major component of PM1 in both the haze and post-haze air. Analysis of individual particles in the size range of 0.2-1.1μm revealed that secondary-like particles and soot particles were always the majority, and most soot particles had a core-shell structure. The number ratio of secondary-like particles to soot particles in accumulation mode in the haze air was about 2:1, and that in the post-haze air was 8:1. These results indicate both secondary particle formation and primary emission contributed substantially to the haze. The mode size of the haze particles was about 0.7μm, and the mode size of the post-haze particles was 0.4μm, indicating the remarkable growth of particles in haze. However, the ratios of the core size to shell size of core-shell structure soot particles in the haze were similar to those in the post-haze air, suggesting a quick aging of soot particles in either the haze air or the post-haze air.

  19. Color vision: retinal blues.

    Science.gov (United States)

    Johnston, Jamie; Esposti, Federico; Lagnado, Leon

    2012-08-21

    Two complementary studies have resolved the circuitry underlying green-blue color discrimination in the retina. A blue-sensitive interneuron provides the inhibitory signal required for computing green-blue color opponency.

  20. 78 FR 8083 - Partial Disapproval of State Implementation Plan; Arizona; Regional Haze Requirements

    Science.gov (United States)

    2013-02-05

    ... regional haze on July 1, 1999. 64 FR 35714 (July 1, 1999) codified at ] 40 CFR part 51, subpart P (Regional... of the required SIP submissions to address regional haze. See 74 FR 2392. Specifically, EPA found... Arizona's 309 Regional Haze SIP, if finalized, will not create a new FIP obligation.\\18\\ \\16\\ 74 FR...

  1. 76 FR 76646 - Approval and Promulgation of Implementation Plans; South Dakota; Regional Haze State...

    Science.gov (United States)

    2011-12-08

    .... 64 FR 35714 (July 1, 1999), codified at 40 CFR part 51, subpart P. The Regional Haze Rule revised the... the regional ] haze requirements. 74 FR 2392. Once EPA has found that a state has failed to make a...\\ The preamble to the Regional Haze Rule provides additional details about the deciview. 64 FR...

  2. 77 FR 30454 - Approval and Promulgation of Implementation Plans; State of Oregon; Regional Haze State...

    Science.gov (United States)

    2012-05-23

    ... approved certain provisions in Oregon's Regional Haze SIP submission. 76 FR 38997. This previous action... regional haze on July 1, 1999 (64 FR 35713) (the regional haze rule or RHR). The RHR revised the existing... (BART). 76 FR 38997. The action in this Federal Register notice addresses the remaining requirements...

  3. 78 FR 5158 - Approval and Promulgation of Air Quality Implementation Plans; Connecticut; Regional Haze

    Science.gov (United States)

    2013-01-24

    ... rule to address regional haze on July 1, 1999 (64 FR 35714) (``the Regional Haze Rule''). The... Connecticut Regional Haze SIP. See 77 FR 12367. \\1\\ Areas designated as mandatory Class I Federal areas..., promulgated a list of 156 areas where visibility is identified as an important value (44 FR 69122, November...

  4. 76 FR 33662 - Approval and Promulgation of Air Quality Implementation Plans; State of Tennessee; Regional Haze...

    Science.gov (United States)

    2011-06-09

    ... address regional haze issues. EPA promulgated a rule to address regional haze on July 1, 1999 (64 FR 35713... revising the regional haze program, EPA made just such a demonstration for CAIR. See 70 FR 39104 (July 6... FR 39104, 39142-4143 (July 6, 2005). CAIR, as originally promulgated, requires significant...

  5. 77 FR 30932 - Approval and Promulgation of Air Quality Implementation Plans; Massachusetts; Regional Haze

    Science.gov (United States)

    2012-05-24

    .... EPA promulgated a rule to address regional haze on July 1, 1999 (64 FR 35714), the Regional Haze Rule... the Regional Haze Rule, Part II, How to Identify BART-Eligible Sources. See 70 FR 39158. This guidance... the visual range that would exist under estimated natural conditions. See 64 FR 35715 (July 1,...

  6. 77 FR 33021 - Approval, Disapproval and Promulgation of Implementation Plans; State of Wyoming; Regional Haze...

    Science.gov (United States)

    2012-06-04

    ... address regional haze issues. EPA promulgated a rule to address regional haze on July 1, 1999. 64 FR 35714... addressing the regional haze requirements. 74 FR 2392. Once EPA has found that a state has failed to make a... conditions. 64 FR 35715 (July 1, 1999). \\1\\ Visual range is the greatest distance, in kilometers or miles,...

  7. 77 FR 17367 - Approval and Promulgation of Air Quality Implementation Plans; Connecticut; Regional Haze

    Science.gov (United States)

    2012-03-26

    .... EPA promulgated a rule to address regional haze on July 1, 1999 (64 FR 35714), the Regional Haze Rule... significance to be assigned to each factor. See 70 FR 39170 (July 6, 2005). A regional haze SIP must include... the visual range that would exist under estimated natural conditions. See 64 FR 35715 (July 1,...

  8. 77 FR 11452 - Approval and Promulgation of Air Quality Implementation Plans; State of Georgia; Regional Haze...

    Science.gov (United States)

    2012-02-27

    ... submittal arising from the State's reliance on CAIR to meet certain regional haze requirements. See 76 FR... promulgated a rule to address regional haze on July 1, 1999 (64 FR 35713), the RHR. The RHR revised the... ] revising the regional haze program, EPA made just such a demonstration for CAIR. See 70 FR 39104 (July...

  9. 77 FR 11928 - Approval and Promulgation of Air Quality Implementation Plans; Wisconsin; Regional Haze

    Science.gov (United States)

    2012-02-28

    ... regional haze issues. EPA promulgated a rule to address regional haze, the RHR, on July 1, 1999 (64 FR... issued in 2005 revising the regional haze program. 70 FR 39104 ] (July 6, 2005). EPA's regulations... would exist under estimated natural conditions. See 64 FR 35715 (July 1, 1999). \\1\\ Areas designated...

  10. 77 FR 34801 - Approval and Promulgation of Air Quality Implementation Plans; Minnesota; Regional Haze

    Science.gov (United States)

    2012-06-12

    ... haze plan on January 25, 2012 (77 FR 3681). The proposed rule described the nature of the regional haze... July 1, 1999 RHR (64 FR 35714) required states to submit a regional haze plan by December 17, 2007... (RHR) as codified at 40 CFR 51.308. This rule was promulgated on July 1, 1999 (64 FR 35713),...

  11. Study on the Variation Characteristics of Haze Weather in Hubei Province during 1980-2012

    Institute of Scientific and Technical Information of China (English)

    Tianxing SU; Mingfang XU; Xiang ZHOU; Zaiqiang YANG; Jijian YUAN; Haiyan ZHANG

    2015-01-01

    This paper, using the method of "the combination of 14 o ’clock relative humidity, visibility and weather phenomena" , selected haze days during 1980-2012 from 13 stations of Hubei Province, and studied years of variation characteristics of haze weather in Hubei Province. The results showed that the average annual haze days showed a fluctuant rising trend in whole from 1980 to 2012, but there were many peak value and val ey value during the whole changing process; haze days of most stations showed an increasing trend, among which the stations with less than 50 d haze days had a more obvious increasing trend, and the spatial distribution of annual mean haze days had distinct inhomogeneity. Haze days of Hubei Province presented the distribution characteristics of more in autumn and winter, and less in spring and summer, in which haze days during December-January were the most, and haze days during July -August were the least. Terrain had a big impact on lo-cal haze days, piedmont leeward zones were prone to haze days, mountainous re-gions were just the opposite. The research suggested that we should combine dif-ferent situations with different stations instead of exclusively from the mean value of multiple stations when we analyze the mean change of haze days in a broader area, to investigate the overal changing trend and the reasons.

  12. 78 FR 40654 - Approval, Disapproval and Promulgation of Implementation Plans; State of Wyoming; Regional Haze...

    Science.gov (United States)

    2013-07-08

    ... partially approving and partially disapproving Wyoming's 40 CFR 51.309(g) regional haze SIP. 78 FR 34738. In.... at both locations. The comment period for the proposed rule published June 10, 2013 at 78 FR 34738 is...; Regional Haze State Implementation Plan; Federal Implementation Plan for Regional Haze; Notice of...

  13. 77 FR 3975 - Approval and Promulgation of Air Quality Implementation Plans; Indiana; Regional Haze

    Science.gov (United States)

    2012-01-26

    ... regional haze issues. EPA promulgated a rule to address regional haze, the RHR, on July ] 1, 1999 (64 FR... regulations issued in 2005 revising the regional haze program. 70 FR 39104 (July 6, 2005). EPA's regulations...-fifth of the visual range that would exist under estimated natural conditions. See 64 FR 35715 (July...

  14. 77 FR 71111 - Approval and Promulgation of Air Quality Implementation Plans; State of Florida; Regional Haze...

    Science.gov (United States)

    2012-11-29

    ... regional haze on July 1, 1999 (64 FR 35713), the Regional Haze Rule (RHR). The RHR revised the existing... haze SIP, and on June 7, 2012 (77 FR 33642), the EPA finalized a limited disapproval of the regional... of sources, i.e., ``reasonably attributable visibility impairment.'' See 45 FR 80084....

  15. 77 FR 46911 - Approval and Promulgation of Air Quality Implementation Plans; Michigan; Regional Haze State...

    Science.gov (United States)

    2012-08-06

    ... July 1, 1999 (64 FR 35713). The regional haze rule, which amended 40 CFR part 50, subpart P, integrated... haze rule provides additional details about the deciview. 64 FR 35714 (July 1, 1999). To track changes... which revised the regional haze program. 70 FR 39104 (July 6, 2005). EPA's regulations provided...

  16. Size-resolved source apportionment of particulate matter in urban Beijing during haze and non-haze episodes

    Science.gov (United States)

    Tian, S. L.; Pan, Y. P.; Wang, Y. S.

    2015-03-01

    More size-resolved chemical information is needed before the physicochemical characteristics and sources of airborne particles can be understood, but this information remains unavailable in most regions of China due to a paucity of measurement data. In this study, we report a one-year observation of various chemical species in size-segregated particle samples collected in urban Beijing, a mega city that experiences severe haze episodes. In addition to fine particles, the measured particle size distributions showed high concentrations of coarse particles during the haze periods. The abundance and chemical compositions of the particles in this study were temporally and spatially variable, with major contributions from organic matter and secondary inorganic aerosols. The contribution of the organic matter to the mass decreased from 37.9 to 33.1%, whereas the total contribution of SO42-, NO3- and NH4+ increased from 19.1 to 32.3% on non-haze and haze days, respectively. Due to heterogeneous reactions and hygroscopic growth, the peaks in the size distributions of organic carbon, SO42-, NO3-, NH4+, Cl-, K+ and Cu shifted from 0.43-0.65 μm on non-haze days to 0.65-1.1 μm on haze days. Although the size distributions are similar for the heavy metals Pb, Cd and Tl during the observation period, their concentrations increased by a factor of more than 1.5 on haze days compared with non-haze days. We found that NH4+ with a size range of 0.43-0.65 μm, SO42- and NO3- with a size range of 0.65-1.1 μm and Ca2+ with a size range of 5.8-9 μm as well as the meteorological factors of relative humidity and wind speed were responsible for the haze pollution when the visibility was less than 15 km. Source apportionment using positive matrix factorization identified six common sources: secondary inorganic aerosols (26.1% for fine particles vs. 9.5% for coarse particles), coal combustion (19 vs. 23.6%), primary emissions from vehicles (5.9 vs. 8.0%), biomass burning (8.5 vs. 2

  17. Haze of surface random systems: An approximate analytic approach

    CERN Document Server

    Simonsen, Ingve; Andreassen, Erik; Ommundsen, Espen; Nord-Varhaug, Katrin

    2009-01-01

    Approximate analytic expressions for haze (and gloss) of Gaussian randomly rough surfaces for various types of correlation functions are derived within phase-perturbation theory. The approximations depend on the angle of incidence, polarization of the incident light, the surface roughness, $\\sigma$, and the average of the power spectrum taken over a small angular interval about the specular direction. In particular it is demonstrated that haze(gloss) increase(decrease) with $\\sigma/\\lambda$ as $\\exp(-A(\\sigma/\\lambda)^2)$ and decreases(increase) with $a/\\lambda$, where $a$ is the correlation length of the surface roughness, in a way that depends on the specific form of the correlation function being considered. These approximations are compared to what can be obtained from a rigorous Monte Carlo simulation approach, and good agreement is found over large regions of parameter space. Some experimental results for the angular distribution of the transmitted light through polymer films, and their haze, are presen...

  18. Aerosols optical propertites in Titan's Detached Haze Layer

    Science.gov (United States)

    Seignovert, Benoît; Rannou, Pascal; Lavvas, Panayotis; Cours, Thibaud; West, Robert A.

    2016-06-01

    Titan's Detached Haze Layer (DHL) first observed in 1983 by Rages and Pollack during the Voyager 2 [1] is a consistent spherical haze feature surrounding Titan's upper atmosphere and detached from the main haze. Since 2005, the Imaging Science Subsystem (ISS) instrument on board the Cassini mission performs a continuous survey of the Titan's atmosphere and confirmed its persistence at 500 km up to the equinox (2009) before its drop and disappearance in 2012 [2]. Previous analyses showed, that this layer corresponds to the transition area between small spherical aerosols and large fractal aggregates and play a key role in the aerosols formation in Titan's atmosphere [3-5]. In this study we perform UV photometric analyses on ISS observations taken from 2005 to 2007 based on radiative transfer inversion to retrieve aerosols particles properties in the DHL (bulk and monomer size, fractal dimension and local density).

  19. Fluorescence enhancement of single-phase red-blue emit-ting Ba_3MgSi_2O_8:Eu~(2+),Mn~(2+) phosphors via Dy~(3+) addition for plant cultivation

    Institute of Scientific and Technical Information of China (English)

    刘凌云; 王达健; 毛智勇; 刘艳华; 李雪征; 陆启飞

    2009-01-01

    Fluorescence enhancement of red and blue concurrently emitting Ba3MgSi2O8:Eu2+,Mn2+ phosphors for plant cultivation has been investigated by Dy3+ addition.The Ba3MgSi2O8:Eu2+,Mn2+,Dy3+(BMS-EMD) phosphors have two-color emissions at the wavelength peak values of 437 nm and 620 nm at the excitation of 350 nm.The two emission bands are coincident with the absorption spectrum for photosynthesis of plants.An obvious enhancement effect has been observed upon addition of Dy3+ with amount of 0.03 mol%,in which the ...

  20. Radiative effects of tropospheric aerosols on the evolution of the atmospheric boundary layer and its feedback on the haze formation

    Science.gov (United States)

    Wei, Chao; Su, Hang; Cheng, Yafang

    2016-04-01

    Planetary boundary layer (PBL) plays a key role in air pollution dispersion and influences day-to-day air quality. Some studies suggest that high aerosol loadings during severe haze events may modify PBL dynamics by radiative effects and hence enhance the development of haze. This study mainly investigates the radiative effects of tropospheric aerosols on the evolution of the atmospheric boundary layer by conducting simulations with Weather Research and Forecasting single-column model (WRF-SCM). We find that high aerosol loading in PBL depressed boundary layer height (PBLH). But the magnitude of the changes of PBLH after adding aerosol loadings in our simulations are small and can't explain extreme high aerosol concentrations observed. We also investigate the impacts of the initial temperature and moisture profiles on the evolution of PBL. Our studies show that the impact of the vertical profile of moisture is comparable with aerosol effects.

  1. Development of textured ZnO-coated low-cost glass substrate with very high haze ratio for silicon-based thin film solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Hongsingthong, Aswin, E-mail: aswin.hongsingthong@nectec.or.th [Solar Energy Technology Laboratory, National Electronics and Computer Technology Center, 112 Thailand Science Park, Phahonyothin Road, Khlong 1, Khlong Luang, Pathumthani 12120 (Thailand); Krajangsang, Taweewat; Limmanee, Amornrat; Sriprapha, Kobsak; Sritharathikhun, Jaran [Solar Energy Technology Laboratory, National Electronics and Computer Technology Center, 112 Thailand Science Park, Phahonyothin Road, Khlong 1, Khlong Luang, Pathumthani 12120 (Thailand); Konagai, Makoto [Department of Physical Electronics, Tokyo Institute of Technology, 2-12-1, NE-15, O-okayama, Meguro-ku, Tokyo 152-8552 (Japan)

    2013-06-30

    Zinc oxide (ZnO) films with a very high haze ratio and low resistivity were developed on soda–lime glass substrate by using reactive ion etching (RIE) treatment with carbon tetrafluoride (CF{sub 4}) to modify the substrate surface morphology before the deposition of ZnO films. We found that the surface morphology of the ZnO films deposited by metal organic chemical vapor deposition (MOCVD) technique could be modified by varying the glass treatment conditions and the gas pressure was a key parameter. With increasing glass-etching pressure, the surface morphology of the ZnO films changed from conventional pyramid-like single texture to greater cauliflower-like double texture, leading to significant increases in root mean square roughness and haze ratio of the films. By employing the developed high-haze ZnO films as a front transparent conductive oxide (TCO) layer in microcrystalline silicon solar cells, an enhancement in the quantum efficiency in the long-wavelength region has been achieved. Experimental results have verified that our unique and original glass etching treatment is a simple and effective technique to improve the light-scattering properties of the ZnO films while preserving their good transparency and electrical properties. Thus, the ZnO films deposited on etched soda–lime glass have a high potential for the use as a front TCO layer in thin-film Si solar cells. - Highlights: • High-haze zinc oxide (ZnO) grown on low cost soda–lime glass has been developed. • Surface of the ZnO can be modified by varying glass-substrate etching conditions. • Glass-etching pressure is a key to increase haze ratio of the ZnO films. • Higher cell efficiency has been achieved from cell using etched glass. • High-haze ZnO coated glass is a promising transparent conductive oxide coated glass.

  2. Improvement of Light Extraction Efficiency in Flip-Chip Light Emitting Diodes on SiC Substrate via Transparent Haze Films with Morphology-Controlled Collapsed Alumina Nanorods.

    Science.gov (United States)

    Baek, Seunghwa; Kang, Gumin; Shin, Dongheok; Bae, Kyuyoung; Kim, Yong Hyun; Kim, Kyoungsik

    2016-01-13

    We demonstrate GaN-based flip-chip light emitting diodes (FC-LEDs) on SiC substrate achieving high extraction efficiency by simply attaching the optically transparent haze films consisting of collapsed alumina nanorods. Through controlled etching time of alumina nanorods, we obtain four types of films that have different morphologies with different optical transmittance and haze properties. We show that the light output power of the FC-LEDs with film, which has 95.6% transmittance and 62.7% haze, increases by 20.4% in comparison to the bare LEDs. The angular radiation pattern of the LEDs also follows the Lambertian emission pattern without deteriorating the electrical properties of the device. The improvement of light extraction is mainly attributed to the reduced total internal reflection (TIR) via efficient out-coupling of guided light from SiC substrate to air by collapsed alumina nanorod structures in the film. The high transparency of film and reduced Fresnel reflection via graded refractive index transition between the film and SiC substrate also contribute to the extraction enhancement of the device. We systematically investigate the influence of haze film's geometrical or optical properties on the extraction efficiency of FC-LEDs, and this study will provide a novel approach to enhance the performance of various optoelectronic devices.

  3. A drought-based predictor of recent haze events in western Indonesia

    Science.gov (United States)

    Field, Robert D.; Wang, Yonghe; Roswintiarti, Orbita; Guswanto

    Indonesia's fire and haze problem is reviewed, and a model quantifying the relationship between drought and haze from biomass burning in western Indonesia is presented. Visibility observations from weather stations in Sumatra and Kalimantan were used as a haze indicator. The Drought Code component of the Canadian Forest Fire Weather Index System was used as a drought indicator. Using meteorological data from 1994 to 1998, we obtained regional haze and drought signals for western Indonesia. Nonlinear regression analysis was performed between the two signals to obtain a model of haze potential based on the Drought Code. Using the curvature properties of the nonlinear model, we estimated that severe haze is likely above a threshold Drought Code of 388.2. Using this threshold value, we propose four levels of drought that can be used operationally as an early warning tool in managing Indonesia's serious haze problem.

  4. Invasive blue mussels threaten regional scale genetic diversity in mainland and remote offshore locations: the need for baseline data and enhanced protection in the Southern Ocean.

    Science.gov (United States)

    Gardner, Jonathan P A; Zbawicka, Małgorzata; Westfall, Kristen M; Wenne, Roman

    2016-09-01

    Human-mediated biological transfers of species have substantially modified many ecosystems with profound environmental and economic consequences. However, in many cases, invasion events are very hard to identify because of the absence of an appropriate baseline of information for receiving sites/regions. In this study, use of high-resolution genetic markers (single nucleotide polymorphisms - SNPs) highlights the threat of introduced Northern Hemisphere blue mussels (Mytilus galloprovincialis) at a regional scale to Southern Hemisphere lineages of blue mussels via hybridization and introgression. Analysis of a multispecies SNP dataset reveals hotspots of invasive Northern Hemisphere blue mussels in some mainland New Zealand locations, as well as the existence of unique native lineages of blue mussels on remote oceanic islands in the Southern Ocean that are now threatened by invasive mussels. Samples collected from an oil rig that has moved between South Africa, Australia, and New Zealand were identified as invasive Northern Hemisphere mussels, revealing the relative ease with which such non-native species may be moved from region to region. In combination, our results highlight the existence of unique lineages of mussels (and by extension, presumably of other taxa) on remote offshore islands in the Southern Ocean, the need for more baseline data to help identify bioinvasion events, the ongoing threat of hybridization and introgression posed by invasive species, and the need for greater protection of some of the world's last great remote areas. PMID:27124277

  5. Dispensability of the major coat protein of oat blue dwarf virus in genome replication: Substitution of the open reading frame with the enhanced green fluorescent protein gene

    Science.gov (United States)

    Oat blue dwarf virus (OBDV) is a representative marafivirus that infects monocots and a limited number of dicot species and is vectored propagatively by the leafhopper Macrosteles fascifrons.Recently, we reported the generation of clone pOBDV-2r, the first clone of a marafivirus from which infectiou...

  6. Invasive blue mussels threaten regional scale genetic diversity in mainland and remote offshore locations: the need for baseline data and enhanced protection in the Southern Ocean.

    Science.gov (United States)

    Gardner, Jonathan P A; Zbawicka, Małgorzata; Westfall, Kristen M; Wenne, Roman

    2016-09-01

    Human-mediated biological transfers of species have substantially modified many ecosystems with profound environmental and economic consequences. However, in many cases, invasion events are very hard to identify because of the absence of an appropriate baseline of information for receiving sites/regions. In this study, use of high-resolution genetic markers (single nucleotide polymorphisms - SNPs) highlights the threat of introduced Northern Hemisphere blue mussels (Mytilus galloprovincialis) at a regional scale to Southern Hemisphere lineages of blue mussels via hybridization and introgression. Analysis of a multispecies SNP dataset reveals hotspots of invasive Northern Hemisphere blue mussels in some mainland New Zealand locations, as well as the existence of unique native lineages of blue mussels on remote oceanic islands in the Southern Ocean that are now threatened by invasive mussels. Samples collected from an oil rig that has moved between South Africa, Australia, and New Zealand were identified as invasive Northern Hemisphere mussels, revealing the relative ease with which such non-native species may be moved from region to region. In combination, our results highlight the existence of unique lineages of mussels (and by extension, presumably of other taxa) on remote offshore islands in the Southern Ocean, the need for more baseline data to help identify bioinvasion events, the ongoing threat of hybridization and introgression posed by invasive species, and the need for greater protection of some of the world's last great remote areas.

  7. Ice haze, snow, and the Mars water cycle

    Science.gov (United States)

    Kahn, Ralph

    1990-01-01

    Light curves and extinction profiles derived from Martian limb observations are used to constrain the atmospheric temperature structure in regions of the atmosphere with thin haze and to analyze the haze particle properties and atmospheric eddy mixing. Temperature between 170 and 190 K are obtained for three cases at levels in the atmosphere ranging from 20 to 50 km. Eddy diffusion coefficients around 100,000 sq cm/s, typical of a nonconvecting atmosphere, are derived in the haze regions at times when the atmosphere is relatively clear of dust. This parameter apparently changes by more than three orders of magnitude with season and local conditions. The derived particle size parameter varies systematically by more than an order of magnitude with condensation level, in such a way that the characteristic fall time is always about one Martian day. Ice hazes provide a mechanism for scavenging water vapor in the thin Mars atmosphere and may play a key role in the seasonal cycle of water on Mars.

  8. Surface Haze and Surface Morphology of Blown Film Compositions

    OpenAIRE

    Patel, Rajen; Ratta, Varun; Saavedra, Pepe; Li, Jing

    2005-01-01

    Abstract Reduction in surface haze is a very attractive way to improve the optical properties of most polyolefin films. This route becomes very viable for coextruded multilayer films where the inner layers may be utilized to provide the desired mechanical properties, such as high modulus, controlled shrinkage, and good tear strength while the outer 'skin' layers are utilized to give low surface and ...

  9. Identifying the Radio Bubble Nature of the Microwave Haze

    CERN Document Server

    Dobler, Gregory

    2012-01-01

    Using 7-year data from the Wilkinson Microwave Anisotropy Probe I identify a sharp "edge" in the microwave haze at high Galactic latitude (35 deg < |b| < 55 deg) that is spatially coincident with the edge of the "Fermi Haze/Bubbles". This finding proves conclusively that the edge in the gamma-rays is real (and not a processing artifact), demonstrates explicitly that the microwave haze and the gamma-ray bubbles are indeed the same structure observed at multiple wavelengths, and strongly supports the interpretation of the microwave haze as a separate component of Galactic synchrotron (likely generated by a transient event) as opposed to a simple variation of the spectral index of disk synchrotron. In addition, combining these data sets allows for the first determination of the magnetic field within a radio bubble using microwaves and gamma-rays by taking advantage of the fact that the inverse Compton gamma-rays are primarily generated by scattering of CMB photons at these latitudes, thus minimizing uncert...

  10. Low-haze, annealing-free, very long Ag nanowire synthesis and its application in a flexible transparent touch panel

    Science.gov (United States)

    Moon, Hyunjin; Won, Phillip; Lee, Jinhwan; Ko, Seung Hwan

    2016-07-01

    Since transparent conducting films based on silver nanowires (AgNWs) have shown higher transmittance and electrical conductivity compared to those of indium tin oxide (ITO) films, the electronics industry has recognized them as promising substitutes. However, due to the higher haze value of AgNW transparent conducting films compared to ITO films, the clarity is decreased when AgNW films are applied to optoelectronic devices. In this study, we develop a highly transparent, low-haze, very long AgNW percolation network. Moreover, we confirm that analyzed chemical roles can easily be applied to different AgNW synthesis methods, and that they have a direct impact on the nanowire shape. Consequently, the lengths of the wires are increased up to 200 μm and the diameters of the wires are decreased up to 45 nm. Using these results, we fabricate highly transparent (96%) conductors (100 Ω/sq) with low-haze (2%) without any annealing process. This electrode shows enhanced clarity compared to previous results due to the decreased diffusive transmittance and scattering. In addition, a flexible touchscreen using a AgNW network is demonstrated to show the performance of modified AgNWs.

  11. Impact of aerosol–meteorology interactions on fine particle pollution during China’s severe haze episode in January 2013

    International Nuclear Information System (INIS)

    In January 2013, a severe regional haze occurred over the North China Plain. An online-coupled meteorology-chemistry model was employed to simulate the impacts of aerosol–meteorology interactions on fine particles (PM2.5) pollution during this haze episode. The response of PM2.5 to meteorology change constituted a feedback loop whereby planetary boundary layer (PBL) dynamics amplified the initial perturbation of PM2.5. High PM2.5 concentrations caused a decrease of surface solar radiation. The maximal decrease in daily average solar radiation reached 53% in Beijing, thereby leading to a more stable PBL. The peak PBL height in Beijing decreased from 690 m to 590 m when the aerosol extinction was considered. Enhanced PBL stability suppressed the dispersion of air pollutants, and resulted in higher PM2.5 concentrations. The maximal increase of PM2.5 concentrations reached 140 μg m−3 in Beijing. During most PM2.5 episodes, primary and secondary particles increased simultaneously. These results imply that the aerosol–radiation interactions played an important role in the haze episode in January 2013. (letter)

  12. Low-haze, annealing-free, very long Ag nanowire synthesis and its application in a flexible transparent touch panel.

    Science.gov (United States)

    Moon, Hyunjin; Won, Phillip; Lee, Jinhwan; Ko, Seung Hwan

    2016-07-22

    Since transparent conducting films based on silver nanowires (AgNWs) have shown higher transmittance and electrical conductivity compared to those of indium tin oxide (ITO) films, the electronics industry has recognized them as promising substitutes. However, due to the higher haze value of AgNW transparent conducting films compared to ITO films, the clarity is decreased when AgNW films are applied to optoelectronic devices. In this study, we develop a highly transparent, low-haze, very long AgNW percolation network. Moreover, we confirm that analyzed chemical roles can easily be applied to different AgNW synthesis methods, and that they have a direct impact on the nanowire shape. Consequently, the lengths of the wires are increased up to 200 μm and the diameters of the wires are decreased up to 45 nm. Using these results, we fabricate highly transparent (96%) conductors (100 Ω/sq) with low-haze (2%) without any annealing process. This electrode shows enhanced clarity compared to previous results due to the decreased diffusive transmittance and scattering. In addition, a flexible touchscreen using a AgNW network is demonstrated to show the performance of modified AgNWs. PMID:27276174

  13. Low-haze, annealing-free, very long Ag nanowire synthesis and its application in a flexible transparent touch panel.

    Science.gov (United States)

    Moon, Hyunjin; Won, Phillip; Lee, Jinhwan; Ko, Seung Hwan

    2016-07-22

    Since transparent conducting films based on silver nanowires (AgNWs) have shown higher transmittance and electrical conductivity compared to those of indium tin oxide (ITO) films, the electronics industry has recognized them as promising substitutes. However, due to the higher haze value of AgNW transparent conducting films compared to ITO films, the clarity is decreased when AgNW films are applied to optoelectronic devices. In this study, we develop a highly transparent, low-haze, very long AgNW percolation network. Moreover, we confirm that analyzed chemical roles can easily be applied to different AgNW synthesis methods, and that they have a direct impact on the nanowire shape. Consequently, the lengths of the wires are increased up to 200 μm and the diameters of the wires are decreased up to 45 nm. Using these results, we fabricate highly transparent (96%) conductors (100 Ω/sq) with low-haze (2%) without any annealing process. This electrode shows enhanced clarity compared to previous results due to the decreased diffusive transmittance and scattering. In addition, a flexible touchscreen using a AgNW network is demonstrated to show the performance of modified AgNWs.

  14. Impact of aerosol-meteorology interactions on fine particle pollution during China’s severe haze episode in January 2013

    Science.gov (United States)

    Wang, Jiandong; Wang, Shuxiao; Jiang, Jingkun; Ding, Aijun; Zheng, Mei; Zhao, Bin; Wong, David C.; Zhou, Wei; Zheng, Guangjie; Wang, Long; Pleim, Jonathan E.; Hao, Jiming

    2014-09-01

    In January 2013, a severe regional haze occurred over the North China Plain. An online-coupled meteorology-chemistry model was employed to simulate the impacts of aerosol-meteorology interactions on fine particles (PM2.5) pollution during this haze episode. The response of PM2.5 to meteorology change constituted a feedback loop whereby planetary boundary layer (PBL) dynamics amplified the initial perturbation of PM2.5. High PM2.5 concentrations caused a decrease of surface solar radiation. The maximal decrease in daily average solar radiation reached 53% in Beijing, thereby leading to a more stable PBL. The peak PBL height in Beijing decreased from 690 m to 590 m when the aerosol extinction was considered. Enhanced PBL stability suppressed the dispersion of air pollutants, and resulted in higher PM2.5 concentrations. The maximal increase of PM2.5 concentrations reached 140 μg m-3 in Beijing. During most PM2.5 episodes, primary and secondary particles increased simultaneously. These results imply that the aerosol-radiation interactions played an important role in the haze episode in January 2013.

  15. A shift in Jupiter's equatorial haze distribution imaged with the Multi-Conjugate Adaptive Optics Demonstrator at the VLT

    CERN Document Server

    Wong, Michael H; Marchetti, Enrico; Amico, Paola; Tordo, Sebastien; Bouy, Herve; de Pater, Imke

    2008-01-01

    Jupiter was imaged during the Science Demonstration of the MCAO Demonstrator (MAD) at the European Southern Observatory's UT3 Very Large Telescope unit. Io and Europa were used as natural guide stars on either side of Jupiter, separated from each other by about 1.6 arcmin from 23:41 to 01:32 UT (2008 Aug 16/17). The corrected angular resolution was 0.090 arcsec across the entire field of view, as measured on background stars. The observations at 2.02, 2.14, and 2.16 micrometers were sensitive to portions of the Jovian spectrum with strong methane absorption. The data probe the upper troposphere, which is populated with a fine (~0.5 micrometer) haze. Two haze sources have been proposed: lofting of fine cloud particles into the stable upper troposphere, and condensation of hydrazine produced via ammonia photochemistry. The upper tropospheric haze is enhanced over Jupiter's equatorial region. Dramatic changes in the underlying cloud cover--part of the 2006/2007 "global upheaval"--may be associated with changes i...

  16. Constraints on Pluto's Hazes from 2-Color Occultation Lightcurves

    Science.gov (United States)

    Hartig, Kara; Barry, T.; Carriazo, C. Y.; Cole, A.; Gault, D.; Giles, B.; Giles, D.; Hill, K. M.; Howell, R. R.; Hudson, G.; Loader, B.; Mackie, J. A.; Olkin, C. B.; Rannou, P.; Regester, J.; Resnick, A.; Rodgers, T.; Sicardy, B.; Skrutskie, M. F.; Verbiscer, A. J.; Wasserman, L. H.; Watson, C. R.; Young, E. F.; Young, L. A.; Buie, M. W.; Nelson, M.

    2015-11-01

    The controversial question of aerosols in Pluto's atmosphere first arose in 1988, when features in a Pluto occultation lightcurve were alternately attributed to haze opacity (Elliot et al. 1989) or a thermal inversion (Eshleman 1989). A stellar occultation by Pluto in 2002 was observed from several telescopes on Mauna Kea in wavelengths ranging from R- to K-bands (Elliot et al. 2003). This event provided compelling evidence for haze on Pluto, since the mid-event baseline levels were systematically higher at longer wavelengths (as expected if there were an opacity source that scattered more effectively at shorter wavelengths). However, subsequent occultations in 2007 and 2011 showed no significant differences between visible and IR lightcurves (Young et al. 2011).The question of haze on Pluto was definitively answered by direct imaging of forward-scattering aerosols by the New Horizons spacecraft on 14-JUL-2015. We report on results of a bright stellar occultation which we observed on 29-JUN-2015 in B- and H-bands from both grazing and central sites. As in 2007 and 2011, we see no evidence for wavelength-dependent extinction. We will present an analysis of haze parameters (particle sizes, number density profiles, and fractal aggregations), constraining models of haze distribution to those consistent with and to those ruled out by the occultation lightcurves and the New Horizons imaging.References:Elliot, J.L., et al., "Pluto's Atmosphere." Icarus 77, 148-170 (1989)Eshleman, V.R., "Pluto's Atmosphere: Models based on refraction, inversion, and vapor pressure equilibrium." Icarus 80 439-443 (1989)Elliot, J.L., et al., "The recent expansion of Pluto's atmosphere." Nature 424 165-168 (2003)Young, E.F., et al., "Search for Pluto's aerosols: simultaneous IR and visible stellar occultation observations." EPSC-DPS Joint Meeting 2011, held 2-7 October 2011 in Nantes, France (2011)

  17. Spatial and temporal variation of haze in China from 1961 to 2012.

    Science.gov (United States)

    Han, Rui; Wang, Shuxiao; Shen, Wenhai; Wang, Jiandong; Wu, Kang; Ren, Zhihua; Feng, Mingnong

    2016-08-01

    The purpose of this study is to analyze the climatic characteristics and long-term spatial and temporal variations of haze occurrence in China. The impact factors of haze trends are also discussed. Meteorological data from 1961 to 2012 and daily PM10 concentrations from 2003 to 2012 were employed in this study. The results indicate that the annual-average hazy days at all stations have been increasing rapidly from 4 days in 1961 to 18 days in 2012. The maximum number of haze days occur in winter (41.1%) while the minimum occur in summer (10.4%). During 1961-2012, the high occurrence areas of haze shifted from central to south and east regions of China. The Beijing-Tianjin-Hebei (Jing-Jin-Ji) region, Shanxi, Shaanxi, and Henan Province are the high occurrence areas for haze, while the Yangtze River Delta (YRD) and the Pearl River Delta (PRD) have become regions with high haze occurrences in the last 25 years. Temperature and pressure are positively correlated with the number of haze days. However, wind, relative humidity, precipitation, and sunshine duration are negatively correlated with the number of haze days. The key meteorological factors affecting the formation and dissipation of haze vary for high and low altitudes, and are closely related to anthropogenic activities. In recent years, anthropogenic activities have played a more important role in haze occurrences compared with meteorological factors. PMID:27521945

  18. Spatial and temporal variation of haze in China from 1961 to 2012.

    Science.gov (United States)

    Han, Rui; Wang, Shuxiao; Shen, Wenhai; Wang, Jiandong; Wu, Kang; Ren, Zhihua; Feng, Mingnong

    2016-08-01

    The purpose of this study is to analyze the climatic characteristics and long-term spatial and temporal variations of haze occurrence in China. The impact factors of haze trends are also discussed. Meteorological data from 1961 to 2012 and daily PM10 concentrations from 2003 to 2012 were employed in this study. The results indicate that the annual-average hazy days at all stations have been increasing rapidly from 4 days in 1961 to 18 days in 2012. The maximum number of haze days occur in winter (41.1%) while the minimum occur in summer (10.4%). During 1961-2012, the high occurrence areas of haze shifted from central to south and east regions of China. The Beijing-Tianjin-Hebei (Jing-Jin-Ji) region, Shanxi, Shaanxi, and Henan Province are the high occurrence areas for haze, while the Yangtze River Delta (YRD) and the Pearl River Delta (PRD) have become regions with high haze occurrences in the last 25 years. Temperature and pressure are positively correlated with the number of haze days. However, wind, relative humidity, precipitation, and sunshine duration are negatively correlated with the number of haze days. The key meteorological factors affecting the formation and dissipation of haze vary for high and low altitudes, and are closely related to anthropogenic activities. In recent years, anthropogenic activities have played a more important role in haze occurrences compared with meteorological factors.

  19. Individual particle analysis of aerosols collected under haze and non-haze conditions at a high-elevation mountain site in the North China plain

    Science.gov (United States)

    Li, W. J.; Zhang, D. Z.; Shao, L. Y.; Zhou, S. Z.; Wang, W. X.

    2011-11-01

    The North China plain is a region with megacities and huge populations. Aerosols over the highly polluted area have a significant impact on the regional and global climate. In order to investigate the physical and chemical characteristics of aerosol particles in elevated layers there, observations were carried out at the summit of Mt. Tai (1534 m a.s.l.) from 19 to 28 April, 2010, when the air masses were advected from the east (phase-I: 19-21 April), from the south (phase-II: 22-25 April), and from the northwest (phase-III: 26-28 April). Individual aerosol particles were identified with transmission electron microscopy (TEM), new particle formation (NPF) and growth events were monitored by a wide-range particle spectrometer, and ion concentrations in PM2.5 were analyzed. During phase-I and phase-II, haze layers caused by anthropogenic pollution were observed, and a high percentage of particles were sulfur-rich (47-49%). In phase-III, the haze disappeared due to the intrusion of cold air from the northwest, and mineral dust particles from deserts were dominant (43%). NPF followed by particle growth during daytime was more pronounced on hazy than on clear days. Particle growth during daytime resulted in an increase of particle geometric mean diameter from 10-22 nm in the morning to 56-96 nm in the evening. TEM analysis suggests that sulfuric acid and secondary organic compounds should be important factors for particle nucleation and growth. However, the presence of fine anthropogenic particles (e.g., soot, metal, and fly ash) embedded within S-rich particles indicates that they could weaken NPF and enhance particle growth through condensation and coagulation. Abundant mineral particles in phase-III likely suppressed the NPF processes because they supplied sufficient area on which acidic gases or acids condensed.

  20. Individual particle analysis of aerosols collected under haze and non-haze conditions at a high-elevation mountain site in the North China plain

    Directory of Open Access Journals (Sweden)

    W. J. Li

    2011-11-01

    Full Text Available The North China plain is a region with megacities and huge populations. Aerosols over the highly polluted area have a significant impact on the regional and global climate. In order to investigate the physical and chemical characteristics of aerosol particles in elevated layers there, observations were carried out at the summit of Mt. Tai (1534 m a.s.l. from 19 to 28 April, 2010, when the air masses were advected from the east (phase-I: 19–21 April, from the south (phase-II: 22–25 April, and from the northwest (phase-III: 26–28 April. Individual aerosol particles were identified with transmission electron microscopy (TEM, new particle formation (NPF and growth events were monitored by a wide-range particle spectrometer, and ion concentrations in PM2.5 were analyzed. During phase-I and phase-II, haze layers caused by anthropogenic pollution were observed, and a high percentage of particles were sulfur-rich (47–49%. In phase-III, the haze disappeared due to the intrusion of cold air from the northwest, and mineral dust particles from deserts were dominant (43%. NPF followed by particle growth during daytime was more pronounced on hazy than on clear days. Particle growth during daytime resulted in an increase of particle geometric mean diameter from 10–22 nm in the morning to 56–96 nm in the evening. TEM analysis suggests that sulfuric acid and secondary organic compounds should be important factors for particle nucleation and growth. However, the presence of fine anthropogenic particles (e.g., soot, metal, and fly ash embedded within S-rich particles indicates that they could weaken NPF and enhance particle growth through condensation and coagulation. Abundant mineral particles in phase-III likely suppressed the NPF processes because they supplied sufficient area on which acidic gases or acids condensed.

  1. Blue cures blue but be cautious

    Directory of Open Access Journals (Sweden)

    Pranav Sikka

    2011-01-01

    Full Text Available Methemoglobinemia is a disorder characterized by the presence of >1% methemoglobin (metHb in the blood. Spontaneous formation of methemoglobin is normally counteracted by protective enzyme systems, for example, nicotinamide adenine dinucleotide phosphate (NADPH methemoglobin reductase. Methemoglobinemia is treated with supplemental oxygen and methylene blue (1-2 mg/kg administered slow intravenously, which acts by providing an artificial electron acceptor for NADPH methemoglobin reductase. But known or suspected glucose-6-phosphate dehydrogenase (G6PD deficiency is a relative contraindication to the use of methylene blue because G6PD is the key enzyme in the formation of NADPH through pentose phosphate pathway and G6PD-deficient individuals generate insufficient NADPH to efficiently reduce methylene blue to leukomethylene blue, which is necessary for the activation of the NADPH-dependent methemoglobin reductase system. So, we should be careful using methylene blue in methemoglobinemia patient before G6PD levels.

  2. Significant concentration changes of chemical components of PM1 in the Yangtze River Delta area of China and the implications for the formation mechanism of heavy haze-fog pollution.

    Science.gov (United States)

    Zhang, Y W; Zhang, X Y; Zhang, Y M; Shen, X J; Sun, J Y; Ma, Q L; Yu, X M; Zhu, J L; Zhang, L; Che, H C

    2015-12-15

    Since the winter season of 2013, a number of persistent haze-fog events have occurred in central-eastern China. Continuous measurements of the chemical and physical properties of PM1 at a regional background station in the Yangtze River Delta area of China from 16 Nov. to 18 Dec., 2013 revealed several haze-fog events, among which a heavy haze-fog event occurred between 6 Dec. and 8 Dec. The mean concentration of PM1 was 212μgm(-3) in the heavy haze-fog period, which was about 10 times higher than on clean days and featured a peak mass concentration that reached 298μgm(-3). Organics were the largest contributor to the dramatic rise of PM1 on heavy haze-fog days (average mass concentration of 86μgm(-3)), followed by nitrate (58μgm(-3)), sulfate (35μgm(-3)), ammonium (29μgm(-3)), and chloride (4.0μgm(-3)). Nitrate exhibited the largest increase (~20 factors), associated with a significant increase in NOx. This was mainly attributable to increased coal combustion emissions, relative to motor vehicle emissions, and was caused by short-distance pollutant transport within surrounding areas. Low-volatility oxidized organic aerosols (OA) (LV-OOA) and biomass-burning OA (BBOA) also increased sharply on heavy haze-fog days, exhibiting an enhanced oxidation capacity of the atmosphere and increased emissions from biomass burning. The strengthening of the oxidation capacity during the heavy pollution episode, along with lower solar radiation, was probably due to increased biomass burning, which were important precursors of O3. The prevailing meteorological conditions, including low wind and high relative humidity, and short distance transported gaseous and particulate matter surrounding of the sampling site, coincided with the increased pollutant concentrations mainly from biomass-burning mentioned above to cause the persistent haze-fog event in the YRD area. PMID:26298245

  3. Significant concentration changes of chemical components of PM1 in the Yangtze River Delta area of China and the implications for the formation mechanism of heavy haze-fog pollution.

    Science.gov (United States)

    Zhang, Y W; Zhang, X Y; Zhang, Y M; Shen, X J; Sun, J Y; Ma, Q L; Yu, X M; Zhu, J L; Zhang, L; Che, H C

    2015-12-15

    Since the winter season of 2013, a number of persistent haze-fog events have occurred in central-eastern China. Continuous measurements of the chemical and physical properties of PM1 at a regional background station in the Yangtze River Delta area of China from 16 Nov. to 18 Dec., 2013 revealed several haze-fog events, among which a heavy haze-fog event occurred between 6 Dec. and 8 Dec. The mean concentration of PM1 was 212μgm(-3) in the heavy haze-fog period, which was about 10 times higher than on clean days and featured a peak mass concentration that reached 298μgm(-3). Organics were the largest contributor to the dramatic rise of PM1 on heavy haze-fog days (average mass concentration of 86μgm(-3)), followed by nitrate (58μgm(-3)), sulfate (35μgm(-3)), ammonium (29μgm(-3)), and chloride (4.0μgm(-3)). Nitrate exhibited the largest increase (~20 factors), associated with a significant increase in NOx. This was mainly attributable to increased coal combustion emissions, relative to motor vehicle emissions, and was caused by short-distance pollutant transport within surrounding areas. Low-volatility oxidized organic aerosols (OA) (LV-OOA) and biomass-burning OA (BBOA) also increased sharply on heavy haze-fog days, exhibiting an enhanced oxidation capacity of the atmosphere and increased emissions from biomass burning. The strengthening of the oxidation capacity during the heavy pollution episode, along with lower solar radiation, was probably due to increased biomass burning, which were important precursors of O3. The prevailing meteorological conditions, including low wind and high relative humidity, and short distance transported gaseous and particulate matter surrounding of the sampling site, coincided with the increased pollutant concentrations mainly from biomass-burning mentioned above to cause the persistent haze-fog event in the YRD area.

  4. Models for Polar Haze Formation in Jupiter's Stratosphere

    Science.gov (United States)

    Friedson, A. James; Wong, Ah-San; Yung, Yuk L.

    2002-08-01

    We present coupled chemical-microphysical models for the formation, growth, and physical properties of the jovian polar haze based on a gas-phase photochemical model for the auroral regions developed by A. S. Wong et al. (2000, Astrophys. J.534, L215-217). In this model, auroral particle precipitation provides an important energy source for enhanced decomposition of methane and production of benzene and polycyclic aromatic hydrocarbons (PAHs). We find that at high altitude, A 4 (pyrene, a hydrocarbon consisting of four fused aromatic rings) should homogeneously nucleate to form tiny primary particles. At lower altitudes, A 3 (phenanthrene) and A 2 (naphthalene) heterogeneously nucleate on the A 4 nuclei. These particles subsequently grow by additional condensation of A 2 on the nucleated particles and by coagulation and eventually sediment out to the troposphere. We run different cases of the aerosol microphysical model for different assumptions regarding the fractal dimension of aggregate particles formed by the coagulation process. If coagulation is assumed to produce spherical particles (of dimensionality 3), then their mean radius at altitudes below the 20-mbar pressure level is computed to be approximately 0.1 μm. If coagulation produces fractal aggregates of dimension 2.1, then their equivalent mean radius below the 20-mbar level is much larger, of order 0.7 μm. Aggregates with fractal dimensions between 2.1 and 3 form with equivalent mean radii between 0.1 and 0.7 μm. In every case, mean particle radius is found to decrease with increasing altitude, as expected for a system approximately in sedimentation-coagulation equilibrium. The predicted range of altitudes where aerosol formation occurs and the mean size to which particles grow are found to be generally consistent with observations. However, our calculations cannot presently account for the large amount of total aerosol loading inferred by M. G. Tomasko et al. (1986, Icarus65, 218-243). We suggest

  5. Seasonal size distribution of airborne culturable bacteria and fungi and preliminary estimation of their deposition in human lungs during non-haze and haze days

    Science.gov (United States)

    Gao, Min; Jia, Ruizhi; Qiu, Tianlei; Han, Meilin; Song, Yuan; Wang, Xuming

    2015-10-01

    In recent years, haze events in Beijing have significantly increased in frequency. On haze days, airborne microorganisms are considered to be a potential risk factor for various health concerns. However, limited information on bioaerosols has prevented our proper understanding of the possible threat to human health due to these bioaerosols. In this study, we used a six-stage impactor for sampling culturable bioaerosols and the LUDEP 2.07 computer-based model for calculating their deposition on human lungs to investigate seasonal concentration, size distribution, and corresponding deposition efficiency and flux in the human respiratory tract during different haze-level events. The current results of the analysis of 398 samples over four seasons indicate that the concentration of culturable airborne bacteria decreased with increasing haze severity. The bioaerosol concentration ratio was skewed towards larger particle sizes on heavy haze days leading to larger bioaerosol aerodynamic diameters than on non-haze days. During nasal breathing by an adult male engaged in light exercise in an outdoor environment, the total deposition efficiency of culturable bioaerosols is 80-90% including approximately 70% in the upper respiratory tract, 5-7% in the alveoli, and about 3% in the bronchial couple with bronchiolar regions. Although the difference in culturable bioaerosol aerodynamic diameters at different haze levels was not large enough to cause obvious differences in lung deposition efficiency, the deposition fluxes clearly varied with the degree of haze owing to the varied concentration of culturable airborne bacteria and fungi. The results here could improve our understanding of the seasonal health threat due to culturable bioaerosols during non-haze and haze days.

  6. 提高太湖蓝藻厌氧发酵产丁酸的预处理方法%Pretreatment Methods to Enhance the Butyric Acid Production by Anaerobic Fermentation on Taihu Lake Blue-Green Algae

    Institute of Scientific and Technical Information of China (English)

    任洪艳; 吕娴; 阮文权

    2011-01-01

    Butyric acid oriented production via anaerobic fermentation is a desirable pathway to the recycling treatment of blue-green algae. In the study four different pretreatment methodsnamely acidalkalineheat and microwave were used to enhance the fermentation. The content of butyric acid and total organic acids produced from pretreated blue-green algae was evaluated. The results indicated that all pretreatments enhanced the t the production of butyric acid and total organic acids. Among of themalkaline pretreatment at pH 10 exhibited the highest production of butyric acid and total organic acids from the blue-green algae feedstockthe value achieved at 4390 mg/L and 5962 mg/L respectively which both doubled as compared to that before pretreatment.%蓝藻厌氧发酵定向产丁酸是蓝藻资源化处置的理想方式.作者选择4种操作简单易行的预处理方法,即酸法、碱法、加热和微波法对蓝藻进行预处理,考察处理后蓝藻厌氧发酵的丁酸和有机酸产量.结果表明,各预处理方法均能不同程度地提高蓝藻厌氧发酵过程中的丁酸产量和有机酸产量.其中蓝藻经过pH 10碱性预处理后调节初始pH 5.0厌氧发酵的丁酸及有机酸产量最高,分别为4390 mg/L和5962 mg/L,比空白提高了近1倍.

  7. Photon-avalanche upconversion of Ho{sup 3+} in NaYF{sub 4} and enhancement of violet, blue and green emissions induced by sensitization of Tm{sup 3+}

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Huabing; Bu Yanyan [Institute for Nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan 411105, Hunan (China); Yang Xiaoliang, E-mail: xiaoliangy@xtu.edu.cn [Institute for Nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan 411105, Hunan (China); Xiao Siguo; Ding, J.W. [Institute for Nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan 411105, Hunan (China)

    2011-02-25

    Ho{sup 3+} singly doped and Ho{sup 3+}/Tm{sup 3+} co-doped hexagonal NaYF{sub 4} powders have been synthesized by a solid-state reaction method. Under excitation of 671 nm diode laser, upconverted blue, green and red emission bands are observed in Ho{sup 3+} singly doped sample. Temporal evolution and excitation power dependent behavior for the green emission are explored, indicating that a photon-avalanche mechanism is responsible for the upconversion processes in Ho{sup 3+} singly doped hexagonal NaYF{sub 4} sample. With the introduction of Tm{sup 3+}, the intensities of both blue and green emissions of Ho{sup 3+} are efficiently enhanced, which are attributed to two energy transfer processes from Tm{sup 3+} to Ho{sup 3+}, i.e., {sup 3}F{sub 4} (Tm{sup 3+}) + {sup 5}I{sub 8}(Ho{sup 3+}) {yields} {sup 3}H{sub 6} (Tm{sup 3+}) + {sup 5}I{sub 7}(Ho{sup 3+}) and {sup 1}G{sub 4} (Tm{sup 3+}) + {sup 5}I{sub 8}(Ho{sup 3+}) {yields} {sup 3}H{sub 6} (Tm{sup 3+}) + {sup 5}F{sub 3}(Ho{sup 3+}). The result offers a new sensitization approach to enhance the upconversion efficiency of Ho{sup 3+} under 671 nm excitation.

  8. Overexpression of the Synthetic Chimeric Native-T-phylloplanin-GFP Genes Optimized for Monocot and Dicot Plants Renders Enhanced Resistance to Blue Mold Disease in Tobacco (N. tabacum L.

    Directory of Open Access Journals (Sweden)

    Dipak K. Sahoo

    2014-01-01

    Full Text Available To enhance the natural plant resistance and to evaluate the antimicrobial properties of phylloplanin against blue mold, we have expressed a synthetic chimeric native-phylloplanin-GFP protein fusion in transgenic Nicotiana tabacum cv. KY14, a cultivar that is highly susceptible to infection by Peronospora tabacina. The coding sequence of the tobacco phylloplanin gene along with its native signal peptide was fused with GFP at the carboxy terminus. The synthetic chimeric gene (native-phylloplanin-GFP was placed between the modified Mirabilis mosaic virus full-length transcript promoter with duplicated enhancer domains and the terminator sequence from the rbcSE9 gene. The chimeric gene, expressed in transgenic tobacco, was stably inherited in successive plant generations as shown by molecular characterization, GFP quantification, and confocal fluorescent microscopy. Transgenic plants were morphologically similar to wild-type plants and showed no deleterious effects due to transgene expression. Blue mold-sensitivity assays of tobacco lines were performed by applying P. tabacina sporangia to the upper leaf surface. Transgenic lines expressing the fused synthetic native-phyllopanin-GFP gene in the leaf apoplast showed resistance to infection. Our results demonstrate that in vivo expression of a synthetic fused native-phylloplanin-GFP gene in plants can potentially achieve natural protection against microbial plant pathogens, including P. tabacina in tobacco.

  9. The effect of carbon monoxide on planetary haze formation

    International Nuclear Information System (INIS)

    Organic haze plays a key role in many planetary processes ranging from influencing the radiation budget of an atmosphere to serving as a source of prebiotic molecules on the surface. Numerous experiments have investigated the aerosols produced by exposing mixtures of N2/CH4 to a variety of energy sources. However, many N2/CH4 atmospheres in both our solar system and extrasolar planetary systems also contain carbon monoxide (CO). We have conducted a series of atmosphere simulation experiments to investigate the effect of CO on the formation and particle size of planetary haze analogues for a range of CO mixing ratios using two different energy sources, spark discharge and UV. We find that CO strongly affects both number density and particle size of the aerosols produced in our experiments and indicates that CO may play an important, previously unexplored, role in aerosol chemistry in planetary atmospheres.

  10. The effect of carbon monoxide on planetary haze formation

    Energy Technology Data Exchange (ETDEWEB)

    Hörst, S. M.; Tolbert, M. A, E-mail: sarah.horst@colorado.edu [Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO (United States)

    2014-01-20

    Organic haze plays a key role in many planetary processes ranging from influencing the radiation budget of an atmosphere to serving as a source of prebiotic molecules on the surface. Numerous experiments have investigated the aerosols produced by exposing mixtures of N{sub 2}/CH{sub 4} to a variety of energy sources. However, many N{sub 2}/CH{sub 4} atmospheres in both our solar system and extrasolar planetary systems also contain carbon monoxide (CO). We have conducted a series of atmosphere simulation experiments to investigate the effect of CO on the formation and particle size of planetary haze analogues for a range of CO mixing ratios using two different energy sources, spark discharge and UV. We find that CO strongly affects both number density and particle size of the aerosols produced in our experiments and indicates that CO may play an important, previously unexplored, role in aerosol chemistry in planetary atmospheres.

  11. The Effect of CO on Planetary Haze Formation

    CERN Document Server

    Hörst, Sarah M

    2014-01-01

    Organic haze plays a key role in many planetary processes ranging from influencing the radiation budget of an atmosphere to serving as a source of prebiotic molecules on the surface. Numerous experiments have investigated the aerosols produced by exposing mixtures of N$_{2}$/CH$_{4}$ to a variety of energy sources. However, many N$_{2}$/CH$_{4}$ atmospheres in both our solar system and extrasolar planetary systems also contain CO. We have conducted a series of atmosphere simulation experiments to investigate the effect of CO on formation and particle size of planetary haze analogues for a range of CO mixing ratios using two different energy sources, spark discharge and UV. We find that CO strongly affects both number density and particle size of the aerosols produced in our experiments and indicates that CO may play an important, previously unexplored, role in aerosol chemistry in planetary atmospheres.

  12. Impact of relative humidity on visibility degradation during a haze event: A case study.

    Science.gov (United States)

    Deng, Hua; Tan, Haobo; Li, Fei; Cai, Mingfu; Chan, P W; Xu, Hanbing; Huang, Xiaoying; Wu, Dui

    2016-11-01

    Light scattering of aerosols depends on ambient relative humidity (RH) since hygroscopic particles absorb significant water at high RH, and this results in low visibility. This paper used custom-made parallel nephelometers (PNEPs) to measure aerosol light scattering enhancement factor ƒ(RH), and utilized data including visibility, PM2.5, black carbon, water-soluble ions mass concentrations and surface meteorological parameters, in conjunction with background weather conditions, to analyze a haze event in Guangzhou during 8th-15th Dec. 2013. Unfavorable weather conditions, such as high RH and low wind speed, were observed during the haze event. The hourly average mass concentration of PM2.5 was 127μg/m(3), with concentration of 192.4μg/m(3) on 9th and 196μg/m(3) on 13th. The ƒ(RH) did not exhibit significant changes during this haze process, with value of ƒ(80%)=1.58±0.07. Although the mass fraction of water-soluble ions to PM2.5 decreased after 12th Dec., the aerosol hygroscopicity might not have changed significantly since the mass fraction of nitrate became more dominant, which has stronger ability to take up water. The best-fitted parameterized function for ƒ(RH) is ƒ(RH)=0.731+0.1375∗(1-RH/100)(-1)+0.00719∗(1-RH/100)(-2). Combining the fixed parameterization of ƒ(RH) above, the visibility was calculated with the measured light scattering and absorption coefficient of particles and gas under dry condition, as well as ambient RH. The predicted visibility range agrees well with the measurements without precipitation. Using ISORROPIA II model, the calculated aerosol liquid water content (ALWC) at ambient RH varied consistently with the PM2.5 under lower RH, while it was more influenced by high RH. This work also show that high RH accompanied with precipitation will enhance aerosol hygroscopic growth effect, leading to further visibility degradation, even if PM2.5 mass decreased due to precipitation. PMID:27395081

  13. Impact of relative humidity on visibility degradation during a haze event: A case study.

    Science.gov (United States)

    Deng, Hua; Tan, Haobo; Li, Fei; Cai, Mingfu; Chan, P W; Xu, Hanbing; Huang, Xiaoying; Wu, Dui

    2016-11-01

    Light scattering of aerosols depends on ambient relative humidity (RH) since hygroscopic particles absorb significant water at high RH, and this results in low visibility. This paper used custom-made parallel nephelometers (PNEPs) to measure aerosol light scattering enhancement factor ƒ(RH), and utilized data including visibility, PM2.5, black carbon, water-soluble ions mass concentrations and surface meteorological parameters, in conjunction with background weather conditions, to analyze a haze event in Guangzhou during 8th-15th Dec. 2013. Unfavorable weather conditions, such as high RH and low wind speed, were observed during the haze event. The hourly average mass concentration of PM2.5 was 127μg/m(3), with concentration of 192.4μg/m(3) on 9th and 196μg/m(3) on 13th. The ƒ(RH) did not exhibit significant changes during this haze process, with value of ƒ(80%)=1.58±0.07. Although the mass fraction of water-soluble ions to PM2.5 decreased after 12th Dec., the aerosol hygroscopicity might not have changed significantly since the mass fraction of nitrate became more dominant, which has stronger ability to take up water. The best-fitted parameterized function for ƒ(RH) is ƒ(RH)=0.731+0.1375∗(1-RH/100)(-1)+0.00719∗(1-RH/100)(-2). Combining the fixed parameterization of ƒ(RH) above, the visibility was calculated with the measured light scattering and absorption coefficient of particles and gas under dry condition, as well as ambient RH. The predicted visibility range agrees well with the measurements without precipitation. Using ISORROPIA II model, the calculated aerosol liquid water content (ALWC) at ambient RH varied consistently with the PM2.5 under lower RH, while it was more influenced by high RH. This work also show that high RH accompanied with precipitation will enhance aerosol hygroscopic growth effect, leading to further visibility degradation, even if PM2.5 mass decreased due to precipitation.

  14. Investigating the impact of haze on MODIS cloud detection

    Science.gov (United States)

    Mao, Feiyue; Duan, Miaomiao; Min, Qilong; Gong, Wei; Pan, Zengxin; Liu, Guangyi

    2015-12-01

    The cloud detection algorithm for passive sensors is usually based on a fuzzy logic system with thresholds determined from previous observations. In recent years, haze and high aerosol concentrations with high aerosol optical depth (AOD) occur frequently in China and may critically impact the accuracy of the Moderate Resolution Imaging Spectroradiometer (MODIS) cloud detection. Thus, we comprehensively explore this impact by comparing the results from MODIS/Aqua (passive sensor), Cloud-Aerosol Lidar with Orthogonal Polarization/CALIPSO (lidar sensor), and Cloud Profiling Radar/CloudSat (microwave sensor) of the A-Train suite of instruments using an averaged AOD as an index for an aerosol concentration value. Case studies concerning the comparison of the three sensors indicate that MODIS cloud detection is reduced during haze events. In addition, statistical studies show that an increase in AOD creates an increase in the percentage of uncertain flags and a decrease in hit rate, a consistency index between consecutive sets of cloud retrievals. On average, AOD values lower than 0.1 give hit rate values up to 80.0% and uncertainty values lower than 16.8%, while AOD values greater than 1.0 reduce the hit rate below to 66.6% and increase the percentage of uncertain flags up to 46.6%. Therefore, we can conclude that the ability of MODIS cloud detection is weakened by large concentrations of aerosols. This suggests that use of the MODIS cloud mask, and derived higher-level products, in situations with haze requires caution. Further improvement of this retrieval algorithm is desired as haze studies based on MODIS products are of great interest in a number of related fields.

  15. Comparison of physical and chemical properties of ambient aerosols during the 2009 haze and non-haze periods in Southeast Asia.

    Science.gov (United States)

    Xu, Jingsha; Tai, Xuhong; Betha, Raghu; He, Jun; Balasubramanian, Rajasekhar

    2015-10-01

    Recurrent smoke-haze episodes that occur in Southeast Asia (SEA) are of much concern because of their environmental and health impacts. These haze episodes are mainly caused by uncontrolled biomass and peat burning in Indonesia. Airborne particulate matter (PM) samples were collected in the southwest coast of Singapore from 16 August to 9 November in 2009 to assess the impact of smoke-haze episodes on the air quality due to the long-range transport of biomass and peat burning emissions. The physical and chemical characteristics of PM were investigated during pre-haze, smoke-haze, and post-haze periods. Days with PM2.5 mass concentrations of ≥35 μg m(-3) were considered as smoke-haze events. Using this criterion, out of the total 82 sampling days, nine smoke-haze events were identified. The origin of air masses during smoke-haze episodes was studied on the basis of HYSPLIT backward air trajectory analysis for 4 days. In terms of the physical properties of PM, higher particle surface area concentrations and particle gravimetric mass concentrations were observed during the smoke-haze period, but there was no consistent pattern for particle number concentrations during the haze period as compared to the non-haze period except that there was a significant increase at about 08:00, which could be attributed to the entrainment of PM from aloft after the breakdown of the nocturnal inversion layer. As for the chemical characteristics of PM, among the six key inorganic water-soluble ions (Cl(-), NO3(-), nss-SO4(2-), Na(+), NH4(+), and nss-K(+)) measured in this study, NO3(-), nss-SO4(2-), and NH4(+) showed a significant increase in their concentrations during the smoke-haze period together with nss-K(+). These observations suggest that the increased atmospheric loading of PM with higher surface area and increased concentrations of optically active secondary inorganic aerosols [(NH4)2SO4 or NH4HSO4 and NH4NO3] resulted in the atmospheric visibility reduction in SEA due to

  16. Single Image Haze Removal Method for Inland River

    Directory of Open Access Journals (Sweden)

    Qiu Liu

    2013-01-01

    Full Text Available Due to environmental pollution, the climate is worsening. The fog days up to 60% of the year in inland certain segments, which it has seriously affected the marine electronic cruise normal operation and navigation safety. According to the inland video image becomes gray and lack of visibility in foggy weather conditions, and in order to remove the haze to get a clear image color and contour, this paper presents a method based on Jones Extension Matrix and the Dark Channel Prior. First, we obtain the light intensity in the atmosphere and the estimated concentration of the haze by using Dark Channel Prior, and via using the Jones Extension Matrix and the parameters of Stokes' Law to eliminate part of the scattered light. At last, we have completed the function of image dehazing by brightness adjustment factor based on N pixels in the field of step brightness and improve the brightness based on Retinex Principle for the recovered image. Experimental results show this algorithm improves scenery visual effect in condition of haze. It is provided a clear video image for the marine electronic cruise in the foggy day.

  17. Photolytic Hazes in the Atmosphere of 51 Eri b

    CERN Document Server

    Zahnle, Kevin J; Morley, Caroline V; Moses, Julianne I

    2016-01-01

    We use a 1D model to address photochemistry and possible haze formation in the irradiated warm Jupiter, 51 Eridani b. The intended focus was to be carbon, but sulfur photochemistry turns out to be important. The case for organic photochemical hazes is intriguing but falls short of being compelling. If organic hazes form, they are likeliest to do so if vertical mixing in 51 Eri b is weaker than in Jupiter, and they would be found below the altitudes where methane and water are photolyzed. The more novel result is that photochemistry turns H$_2$S into elemental sulfur, here treated as S$_8$. In the cooler models, S$_8$ is predicted to condense in optically thick clouds of solid sulfur particles, whilst in the warmer models S$_8$ remains a vapor along with several other sulfur allotropes that are both visually striking and potentially observable. For 51 Eri b, the division between models with and without condensed sulfur is at an effective temperature of 700 K, which is within error its actual effective temperat...

  18. The impact of haze on the adolescent's acute respiratory disease:A single institution study

    Institute of Scientific and Technical Information of China (English)

    Wan Fairos Wan Yaacob; Nor Suhana Mohamad Noor; Nor Ili Che A Bakar; Nurulhuda Afisah Mat Zin; Fahisham Taib

    2016-01-01

    Objective: To examine the impact of haze in the reduction of peak expiratory flow rate (PEFR) reading and identify the risk factors affecting respiratory function due to haze. Methods: This study was conducted during haze period among secondary school stu-dents in Kota Bharu. We analyzed data on a total of 126 secondary school children measuring the respiratory health and symptoms in October 2015 using standardized questionnaire and PEFR measurement. Clinical characteristics on the risk factor and prevalence of haze effect were explored. Chi-square test and independent sample t-test was used to investigate the relationship between risk factors and haze effect and logistic regression analysis for the odds of having haze effect. Results: The findings revealed a significant reduction in PEFR reading of more than 15%from the expected PEFR values. It was also noted that the children with headache, cough, mucus and sore throat respiratory symptoms had consistently higher rates of respiratory illness of having haze effect compared to those who did not. Conclusions: Student with haze effect documented much higher symptoms during haze especially female students. Symptoms such as headache, wheezing and mucus were noted among the normal secondary school children in Kota Bharu.

  19. [Aerosol Optical Properties in the Northern Suburb of Nanjing During Haze Days in January 2013].

    Science.gov (United States)

    Wang, Li-peng; Ma, Yan; Zheng, Jun; Cui, Fen-ping; Zhou, Yao-yao

    2016-03-15

    In January 2013 large-scale, continuous and severe haze occurred in Nanjing. Three-wavelength photoacoustic soot spectrometer (PASS-3) was used for real-time, online and situ measurements of aerosol absorption and scattering coefficients in the northern suburb of Nanjing during January 2013. The results indicated that the average aerosol absorption and scattering coefficients were (83.20 ± 35.24) Mm⁻¹ and (670.16 ± 136.44) Mm⁻¹ during haze days, which were 3.85 and 3.45 times higher than those on clean days, respectively. The diurnal variation of absorption and scattering coefficients showed a bimodal distribution. The mean single scattering albedo and scattering Angstrom exponent were (0.89 ± 0.04) and (1.30 ± 0.27) respectively, indicating the predominance of scattering fine particles during haze days in Nanjing. Aerosols could be significantly removed by precipitation. The absorption and scattering coefficients showed negative correlations with surface wind speed, and the single scattering albedo and Angstrom exponent showed positive correlations with wind speed. Aerosol scattering coefficient was highest under southeasterly wind, whereas the absorption coefficient was highest under the southwesterly wind. In the three haze pollution events, Haze 1 and Haze 2 were mainly affected by long-range transportation of pollutants. Haze 1 was mainly affected by aging air mass from north Nanjing, Haze 2 was mainly affected by biomass burning air mass from southwest Nanjing, while Haze 3 was mainly caused by the high sulfate.

  20. Blue organic light-emitting diodes with low driving voltage and maximum enhanced power efficiency based on buffer layer MoO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Khizar-ul-Haq, E-mail: khizar_bhr@yahoo.co [School of Materials Science and Engineering, Shanghai University, Jiading Shanghai 201800 (China); Khan, M.A.; Jiang, X.Y. [School of Materials Science and Engineering, Shanghai University, Jiading Shanghai 201800 (China); Zhang, Z.L. [School of Materials Science and Engineering, Shanghai University, Jiading Shanghai 201800 (China)] [Key Laboratories of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072 (China); Zhang, X.W. [School of Materials Science and Engineering, Shanghai University, Jiading Shanghai 201800 (China); Wei, Bin [School of Materials Science and Engineering, Shanghai University, Jiading Shanghai 201800 (China)] [Key Laboratories of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072 (China); Wei, J.M.; Zhang Liang; Li Jun [School of Materials Science and Engineering, Shanghai University, Jiading Shanghai 201800 (China)

    2009-10-15

    Blue organic light-emitting devices based on wide bandgap host material, 2-(t-butyl)-9, 10-di-(2-naphthyl) anthracene (TBADN), blue fluorescent styrylamine dopant, p-bis(p-N,N-diphenyl-amino-styryl)benzene (DSA-Ph) have been realized by using molybdenum oxide (MoO{sub 3}) as a buffer layer and 4,7-diphenyl-1,10-phenanthroline (BPhen) as the ETL. The typical device structure used was glass substrate/ITO/MoO{sub 3} (5 nm)/NPB (30 nm)/[TBADN: DSA-Ph (3 wt%)](35 nm)/BPhen (12 nm)/LiF (0.8 nm)/Al (100 nm). It was found that the MoO{sub 3}-parallel BPhen-based device shows the lowest driving voltage and highest power efficiency among the referenced devices. At the current density of 20 mA/cm{sup 2}, its driving voltage and power efficiency are 5.4 V and 4.7 Lm/W, respectively, which is independently reduced 46%, and improved 74% compared with those the m-MTDATA-parallel Alq{sub 3} is based on, respectively. The J-V curves of 'hole-only' devices reveal that a small hole injection barrier between MoO{sub 3}-parallel NPB leads to a strong hole injection, resulting low driving voltage and high power efficiency. The results strongly indicate that carrier injection ability and balance shows a key significance in OLED performance.

  1. Diversity and Composition of Airborne Fungal Community Associated with Particulate Matters in Beijing during Haze and Non-haze Days.

    Science.gov (United States)

    Yan, Dong; Zhang, Tao; Su, Jing; Zhao, Li-Li; Wang, Hao; Fang, Xiao-Mei; Zhang, Yu-Qin; Liu, Hong-Yu; Yu, Li-Yan

    2016-01-01

    To assess the diversity and composition of airborne fungi associated with particulate matters (PMs) in Beijing, China, a total of 81 PM samples were collected, which were derived from PM2.5, PM10 fractions, and total suspended particles during haze and non-haze days. The airborne fungal community in these samples was analyzed using the Illumina Miseq platform with fungi-specific primers targeting the internal transcribed spacer 1 region of the large subunit rRNA gene. A total of 797,040 reads belonging to 1633 operational taxonomic units were observed. Of these, 1102 belonged to Ascomycota, 502 to Basidiomycota, 24 to Zygomycota, and 5 to Chytridiomycota. The dominant orders were Pleosporales (29.39%), Capnodiales (27.96%), Eurotiales (10.64%), and Hypocreales (9.01%). The dominant genera were Cladosporium, Alternaria, Fusarium, Penicillium, Sporisorium, and Aspergilus. Analysis of similarities revealed that both particulate matter sizes (R = 0.175, p = 0.001) and air quality levels (R = 0.076, p = 0.006) significantly affected the airborne fungal community composition. The relative abundance of many fungal genera was found to significantly differ among various PM types and air quality levels. Alternaria and Epicoccum were more abundant in total suspended particles samples, Aspergillus in heavy-haze days and PM2.5 samples, and Malassezia in PM2.5 samples and heavy-haze days. Canonical correspondence analysis and permutation tests showed that temperature (p < 0.01), NO2 (p < 0.01), PM10 (p < 0.01), SO2(p < 0.01), CO (p < 0.01), and relative humidity (p < 0.05) were significant factors that determine airborne fungal community composition. The results suggest that diverse airborne fungal communities are associated with particulate matters and may provide reliable data for studying the responses of human body to the increasing level of air pollution in Beijing.

  2. The Impact of Clouds and Hazes in Substellar Atmospheres

    Science.gov (United States)

    Morley, Caroline; Fortney, Jonathan J.; Marley, Mark S.

    2016-01-01

    The formation of clouds significantly alters the spectra of cool substellar atmospheres from terrestrial planets to brown dwarfs. In cool planets like Earth and Jupiter, volatile species like water and ammonia condense to form ice clouds. In hot planets and brown dwarfs, iron and silicates instead condense, forming dusty clouds. Irradiated methane-rich planets may have substantial hydrocarbon hazes. During my thesis, I have studied the impact of clouds and hazes in a variety of substellar objects. First, I present results for cool brown dwarfs including clouds previously neglected in model atmospheres. Model spectra that include sulfide and salt clouds can match the spectra of T dwarf atmospheres; water ice clouds will alter the spectra of the newest and coldest brown dwarfs, the Y dwarfs. These sulfide/salt and ice clouds potentially drive spectroscopic variability in these cool objects, and this variability should be distinguishable from variability caused by hot spots.Next, I present results for small, cool exoplanets between the size of Earth and Neptune, so-called super Earths. They likely have sulfide and salt clouds and also have photochemical hazes caused by stellar irradiation. Vast resources have been dedicated to characterizing the handful of super Earths accessible to current telescopes, yet of the planets smaller than Neptune studied to date, all have radii in the near-infrared consistent with being constant in wavelength, likely showing that these small planets are consistently enshrouded in thick hazes and clouds. Very thick, lofted clouds of salts or sulfides in high metallicity (1000× solar) atmospheres create featureless transmission spectra in the near-infrared. Photochemical hazes with a range of particle sizes also create featureless transmission spectra at lower metallicities. I show that despite these challenges, there are promising avenues for understanding this class of small planets: by observing the thermal emission and reflectivity of

  3. Performance enhancement of blue light-emitting diodes with InGaN/GaN multi-quantum wells grown on Si substrates by inserting thin AlGaN interlayers

    Science.gov (United States)

    Kimura, Shigeya; Yoshida, Hisashi; Uesugi, Kenjiro; Ito, Toshihide; Okada, Aoi; Nunoue, Shinya

    2016-09-01

    We have grown blue light-emitting diodes (LEDs) having InGaN/GaN multi-quantum wells (MQWs) with thin AlyGa1-yN (0 transmission electron microscopy observations and three-dimensional atom probe analysis that 1-nm-thick interlayers with an AlN mole fraction of less than y = 0.3 were continuously formed between GaN barriers and InGaN wells, and that the AlN mole fraction up to y = 0.15 could be consistently controlled. The external quantum efficiency of the blue LED was enhanced in the low-current-density region (≤45 A/cm2) but reduced in the high-current-density region by the insertion of the thin Al0.15Ga0.85N interlayers in the MQWs. We also found that reductions in both forward voltage and wavelength shift with current were achieved by inserting the interlayers even though the inserted AlGaN layers had potential higher than that of the GaN barriers. The obtained peak wall-plug efficiency was 83% at room temperature. We suggest that the enhanced electroluminescence (EL) performance was caused by the introduction of polarization-induced hole carriers in the InGaN wells on the side adjacent to the thin AlGaN/InGaN interface and efficient electron carrier transport through multiple wells. This model is supported by temperature-dependent EL properties and band-diagram simulations. We also found that inserting the interlayers brought about a reduction in the Shockley-Read-Hall nonradiative recombination component, corresponding to the shrinkage of V-defects. This is another conceivable reason for the observed performance enhancement.

  4. Typical types and formation mechanisms of haze in an eastern Asia megacity, Shanghai

    Directory of Open Access Journals (Sweden)

    K. Huang

    2011-08-01

    Full Text Available An intensive aerosol and gases campaign has been performed at Shanghai in the Yangtze River Delta region over Eastern China from late March to early June 2009. This study provided a complementary picture of typical haze types and formation mechanisms in megacities over China by using a synergy of ground-based monitoring, satellite observation and lidar inversion. During the whole study period, several extreme low visibility periods were observed with distinct characteristics, and three typical haze types were identified, i.e. secondary inorganic pollution, dust, and biomass burning. Sulfate, nitrate and ammonium accounted for a major part of PM2.5 mass during the secondary inorganic pollution, and the good correlation between SO2/NOx/CO and PM2.5 indicated that coal burning and vehicle emission were the major sources. Large-scale regions with high AOD and low Ångström exponent were detected by remote-sensing observation during the dust pollution episode, and this episode corresponded to coarse particles rich in mineral components such as Al and Ca with mineral aerosol contributing 76.8 % to TSP. The relatively low Ca/Al ratio of 0.75 combined with the air mass backward trajectory analysis suggested the dust source from Gobi Desert. Typical tracers for biomass burning from satellite observation (column CO and HCHO and from ground measurement (CO, particulate K+, OC, and EC were greatly enhanced during the biomass burning pollution episode. The exclusive linear correlation between CO and PM2.5 corroborated that organic aerosol dominated aerosol chemistry during biomass burning, and the high concentration and enrichment degree of arsenic (As could be also partly derived from biomass burning. Aerosol optical profile observed by lidar demonstrated that aerosol was mainly constrained below the boundary layer and comprised of spheric aerosol (depolarization ratio <5 % during the

  5. What have we learned from HaChi (HAZE IN CHINA) project?

    Science.gov (United States)

    Zhao, Chunsheng; Wiedensohler, Alfred

    2016-04-01

    HaChi (Haze in China) project, a joint research between Chinese NSFC and German DFG, focuses on investigating the aerosol hygroscopic properties in the North China Plain and their relationships to aerosol optics, radiation, cloud physics and ozone photochemistry. As we know, Eastern China has suffered from severe pollution caused by large concentrations of aerosol particles resulting from emissions from fossil fuel and biomass burning, transportation and some other combustion sources. Low visibility events are frequently encountered and mainly accompanied with haze as a result of either high aerosol loading or the strong hygroscopic growth of the aerosol particles. Especially at relative humidities between 90 and 99%, the aerosol particles grow exponentially. The hygroscopic behaviors at relative humidities close to 100% are also strongly linked to the particles ability to grow into cloud droplets at supersaturation. In my talk, I will present an overview of the up to date results from a serial of intensive and comprehensive field campaigns conducted at the sites of Wuqing and Xianghe, China, between 2009 and 2014. The measurements of the ambient aerosol hygroscopic properties at high RH between 90 and 98.5% are reported first. These in situ field measurements of atmospheric aerosol are unique with respect to their high RH range and especially of importance to better understand the widespread anthropogenic haze over the North China Plain. Then I will introduce the methods for calculating of aerosol hygroscopicity and their parameterization schemes derived from size-segregated chemical composition and the light scattering enhancement factor measurements in the North China Plain. A new method was proposed to retrieve the ratio of the externally mixed light absorbing carbon mass to the total mass of light absorbing carbon. A new parameterization scheme of light extinction for low visibilities on hazy days is proposed based on visibility, relative humidity, aerosol

  6. Impact of crop field burning and mountains on heavy haze in the North China Plain: a case study

    Science.gov (United States)

    Long, Xin; Tie, Xuexi; Cao, Junji; Huang, Rujin; Feng, Tian; Li, Nan; Zhao, Suyu; Tian, Jie; Li, Guohui; Zhang, Qiang

    2016-08-01

    With the provincial statistical data and crop field burning (CFB) activities captured by Moderate Resolution Imaging Spectroradiometer (MODIS), we extracted a detailed CFB emission inventory in the North China Plain (NCP). The WRF-CHEM model was applied to investigate the impact of CFB on air pollution during the period from 6 to 12 October 2014, corresponding to a heavy haze incident with high concentrations of PM2.5 (particulate matter with aerodynamic diameter less than 2.5 µm). The WRF-CHEM model generally performed well in simulating the surface species concentrations of PM2.5, O3 and NO2 compared to the observations; in addition, it reasonably reproduced the observed temporal variations of wind speed, wind direction and planetary boundary layer height (PBLH). It was found that the CFB that occurred in southern NCP (SNCP) had a significant effect on PM2.5 concentrations locally, causing a maximum of 34 % PM2.5 increase. Under continuous southerly wind conditions, the CFB pollution plume went through a long-range transport to northern NCP (NNCP; with several mega cities, including Beijing, the capital city of China), where few CFBs occurred, resulting in a maximum of 32 % PM2.5 increase. As a result, the heavy haze in Beijing was enhanced by the CFB, which occurred in SNCP. Mountains also play significant roles in enhancing the PM2.5 pollution in NNCP through the blocking effect. The mountains blocked and redirected the airflows, causing the pollutant accumulations along the foothills of mountains. This study suggests that the prohibition of CFB should be strict not only in or around Beijing, but also on the ulterior crop growth areas of SNCP. PM2.5 emissions in SNCP should be significantly limited in order to reduce the occurrences of heavy haze events in the NNCP region.

  7. Characteristics of bacterial and fungal aerosols during the autumn haze days in Xi'an, China

    Science.gov (United States)

    Li, Yanpeng; Fu, Honglei; Wang, Wei; Liu, Jun; Meng, Qinglong; Wang, Wenke

    2015-12-01

    In recent years, haze pollution has become one of the most critical environmental issues in Xi'an, China, with particular matter (PM) being one of the top pollutants. As an important fraction of PM, bioaerosols may have adverse effects on air quality and human health. In this study, to better understand the characteristics of such biological aerosols, airborne microbial samples were collected by using an Andersen six-stage sampler in Xi'an from October 8th to 22nd, 2014. The concentration, size distribution and genera of airborne viable bacteria and fungi were comparably investigated during the haze days and non-haze days. Correlations of bioaerosol levels with meteorological parameters and PM concentrations were also examined. The results showed that the daily average concentrations of airborne viable bacteria and fungi during the haze days, 1102.4-1736.5 and 1466.2-1703.9 CFU/m3, respectively, were not only much higher than those during the non-haze days, but also exceeded the recommended permissible limit values. Comparing to size distributions during the non-haze days, slightly different patterns for bacterial aerosols and similar single-peak distribution pattern for fungal aerosols were observed during the haze days. Moreover, more allergic and infectious genera (e.g. Neisseria, Aspergillus, and Paecilomyces) in bioaerosols were identified during the haze days than during non-haze days. The present results reveal that bioaerosols may have more significant effects on public health and urban air quality during the haze days than during non-haze days.

  8. Blue and White Pot

    Institute of Scientific and Technical Information of China (English)

    1996-01-01

    Many recent archaeological studies have proven that the earliest blue and white porcelain was produced from the kiln in Gongxian County, Henan Province in the Tang Dynasty (618-907). It was an important variety of porcelain available for export then. The early blue and white porcelain in the Yuan Dynasty appeared dark and gray. During the reign of Zhizheng, clear blue and white porcelain was produced, indicating

  9. 77 FR 66929 - Approval and Promulgation of Implementation Plans; State of Idaho; Regional Haze State...

    Science.gov (United States)

    2012-11-08

    ... a previous action EPA approved certain provisions in Idaho's Regional Haze SIP submission, 76 FR...]. regional haze SIP elements as proposed in the May 22, 2012 notice. 77 FR 30248. 0 3. Section 52.672 is... toward improving visibility in mandatory Class I Federal areas \\1\\ (Class I areas). 64 FR 35714 (July...

  10. 76 FR 43963 - Regional Haze State Implementation Plan; State of Nevada; Extension of Comment Period

    Science.gov (United States)

    2011-07-22

    ... plan. DATES: The comment period for the proposed rule published June 22, 2011 (76 FR 36450), is... AGENCY 40 CFR Part 51 Regional Haze State Implementation Plan; State of Nevada; Extension of Comment... (SIP) to implement the regional haze program for the first planning period through July 31, 2018....

  11. 77 FR 11022 - Approval and Promulgation of Implementation Plans; State of Alaska; Regional Haze State...

    Science.gov (United States)

    2012-02-24

    ... address regional haze on July 1, 1999 (64 FR 35713), the regional haze rule or RHR. The RHR revised the... Federal areas \\1\\ (Class I areas). 64 FR 35714 (July 1, 1999); see also 70 FR 39104 (July 6, 2005) and 71 FR 60612 (October 13, 2006). \\1\\ Areas designated as mandatory Class I Federal areas consist...

  12. 77 FR 76871 - Approval and Promulgation of Implementation Plans; State of Colorado; Regional Haze State...

    Science.gov (United States)

    2012-12-31

    ... haze in 1999 (64 FR 35714, July 1, 1999, codified at 40 CFR part 51, subpart P). The requirements for... the regional haze requirements (74 FR 2392). Once EPA has found that a state has failed to make a... Register on March 26, 2012 (77 FR 18052). In that notice, we provided a detailed description of the...

  13. 77 FR 50611 - Approval and Promulgation of Implementation Plans; State of Oregon; Regional Haze State...

    Science.gov (United States)

    2012-08-22

    ... approved certain provisions in Oregon's Regional Haze SIP submission. 76 FR 38997. This previous action... developing a LTS. 76 FR 38997. A detailed explanation of the Regional Haze Rule including the requirements... retrofit technology (BART). 76 FR 38997. On May 23, 2012, EPA proposed approving the remaining portion...

  14. 77 FR 30248 - Approval and Promulgation of Implementation Plans; State of Idaho; Regional Haze State...

    Science.gov (United States)

    2012-05-22

    ... regional haze on July 1, 1999 (64 FR 35713) (the regional haze rule or RHR). The RHR revised the existing... toward improving visibility in mandatory Class ] I Federal areas \\1\\ (Class I areas). 64 FR 35714 (July 1, 1999); see also 70 FR 39104 (July 6, 2005) and 71 FR 60612 (October 13, 2006). \\1\\ Areas designated...

  15. 77 FR 20893 - Approval and Promulgation of Implementation Plans; North Dakota; Regional Haze State...

    Science.gov (United States)

    2012-04-06

    ... regional haze issues, and we promulgated regulations addressing regional haze in 1999. 64 FR 35714 (July 1... requirements. 74 FR 2392. Once EPA has found that a state has failed to make a required submission, EPA is.... 62 FR 38652. Section 110(a)(2) of the CAA lists the elements that such new SIPs must address,...

  16. 76 FR 44534 - Approval and Promulgation of Air Quality Implementation Plans; Tennessee; Regional Haze State...

    Science.gov (United States)

    2011-07-26

    .... The Commenters requested the extension in order to determine any potential impacts of the CSAPR on the... potential impacts of the final CSAPR on EPA's proposed rulemaking to approve Tennessee's Regional Haze State... the Regional Haze requirements and, specifically, any potential impacts on the Tennessee Regional...

  17. 77 FR 19098 - Approval and Promulgation of Implementation Plans; Commonwealth of Kentucky; Regional Haze State...

    Science.gov (United States)

    2012-03-30

    ..., 1999 (64 FR 35713), the Regional Haze Rule (RHR). The RHR revised the existing visibility regulations... for regional haze. See 76 FR 78194. EPA proposed a limited approval of Kentucky's two SIP revisions to....e., ``reasonably attributable visibility impairment.'' See 45 FR 80084. These...

  18. 77 FR 30467 - Approval and Promulgation of Implementation Plans; State of Washington; Regional Haze State...

    Science.gov (United States)

    2012-05-23

    ... regional haze on July 1, 1999 (64 FR 35713) (the Regional Haze Rule or RHR). The RHR revised the existing... toward improving visibility in mandatory Class I Federal areas \\1\\ (Class I areas). 64 FR 35714 (July 1, 1999); see also 70 FR 39104 (July 6, 2005) and 71 FR 60612 (October 13, 2006). \\1\\ Areas designated...

  19. 77 FR 17334 - Approval and Promulgation of Air Quality Implementation Plans; State of Nevada; Regional Haze...

    Science.gov (United States)

    2012-03-26

    ... promulgated a rule to address regional haze on July 1, 1999 known as the Regional Haze Rule (RHR). See 64 FR... program. EPA proposed to approve all parts of Nevada's SIP revisions on June 22, 2011 (76 FR 36450). This... conditions. 64 FR 35715 (July 1, 1999). \\1\\ Visual range is the greatest distance, in kilometers or miles,...

  20. 77 FR 11914 - Approval and Promulgation of Air Quality Implementation Plans; Vermont; Regional Haze

    Science.gov (United States)

    2012-02-28

    .... EPA promulgated a rule to address regional haze on July 1, 1999 (64 FR 35714), the Regional Haze Rule... the visual range that would exist under estimated natural conditions. See 64 FR 35715, (July 1, 1999....e., ``reasonably attributable visibility impairment'' (RAVI). See 45 FR 80084 (Dec. 2,1980)....

  1. 77 FR 11809 - Approval and Promulgation of Air Quality Implementation Plans; New Hampshire; Regional Haze

    Science.gov (United States)

    2012-02-28

    .... EPA promulgated a rule to address regional haze on July 1, 1999 (64 FR 35714), the Regional Haze Rule... FR 35715, (July 1, 1999). B. Background Information In section 169A(a)(1) of the 1977 Amendments to... of sources, i.e., ``reasonably attributable visibility impairment'' (RAVI). See 45 FR 80084, (Dec....

  2. 77 FR 41279 - Approval and Promulgation of Air Quality Implementation Plans; Pennsylvania; Regional Haze State...

    Science.gov (United States)

    2012-07-13

    ... CAA and EPA's Regional Haze Rule (64 FR 35714, July 1, 1999) and the rationale for EPA's proposed... under the Regional Haze Rule at Appendix Y to 40 CFR part 51 (hereafter the BART Rule). See 70 FR 39104... (NPR) for Pennsylvania (77 FR 3984). The NPR proposed limited approval of Pennsylvania's RH SIP....

  3. 77 FR 11894 - Approval and Promulgation of Air Quality Implementation Plans; South Carolina; Regional Haze...

    Science.gov (United States)

    2012-02-28

    ... haze requirements. See 76 FR 82219 (December 30, 2011). EPA is not proposing to take action in today's... haze on July 1, 1999 (64 FR 35713), the RHR. The RHR revised the existing visibility regulations to... approved into the South Carolina SIP. See 50 FR 28544 (July 12, 1985) and 52 FR 45132 (November 24,...

  4. 77 FR 22550 - Approval and Promulgation of Air Quality Implementation Plans; New Hampshire; Regional Haze...

    Science.gov (United States)

    2012-04-16

    ..., 2012 (77 FR 11809) is reopened. Comments must be received on or before April 27, 2012. ADDRESSES...; Regional Haze; Reopening of Comment Period AGENCY: Environmental Protection Agency (EPA). ACTION: Proposed... 26, 2011, that addresses regional haze for the first planning period from 2008 through 2018....

  5. 78 FR 49684 - Approval and Disapproval of Air Quality State Implementation Plans; Arizona; Regional Haze and...

    Science.gov (United States)

    2013-08-15

    ... INFORMATION: In Federal Register document 2013-18022 published in the Federal Register on July 30, 2013 (78 FR...; Regional Haze and Interstate Transport Requirements AGENCY: Environmental Protection Agency (EPA). ACTION... of Arizona's State Implementation Plan (SIP) to implement the regional haze program for the...

  6. 77 FR 39938 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Regional Haze State...

    Science.gov (United States)

    2012-07-06

    ... approving into the Maryland SIP. \\1\\ EPA promulgated the RHR to address regional haze on July 1, 1999 (64 FR... which the SIP relies,'' which is ``defined as 2002 for regional haze purposes.'' See 64 FR 35742, July 1..., 2012 (77 FR 11839), EPA published a notice of proposed rulemaking (NPR) for the State of Maryland....

  7. 77 FR 39177 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Regional Haze

    Science.gov (United States)

    2012-07-02

    ..., 2012 (77 FR 3712). The proposal notice described the nature of the regional haze problem and the... December 30, 2011 (76 FR 82219), EPA did in fact propose a limited disapproval of the Ohio regional haze... codified at 40 CFR 51.308. This rule was promulgated on July 1, 1999 (64 FR 35713). Further...

  8. 77 FR 11798 - Approval and Promulgation of Air Quality Implementation Plans; Rhode Island; Regional Haze

    Science.gov (United States)

    2012-02-28

    ... (64 FR 35714), the Regional Haze Rule. The Regional Haze Rule revised the existing visibility... conditions. See 64 FR 35715, (July 1, 1999). B. Background Information In section 169A(a)(1) of the 1977... FR 80084 (Dec. 2, 1980). These regulations represented the first phase in addressing...

  9. 76 FR 27973 - Approval and Promulgation of Air Quality Implementation Plans; State of Delaware; Regional Haze...

    Science.gov (United States)

    2011-05-13

    .... EPA promulgated a rule to address regional haze on July 1, 1999 (64 FR 35714), the Regional Haze Rule... kilometers or about one-fifth of the visual range that would exist under estimated natural conditions (64 FR... of sources, i.e., ``reasonably attributable visibility impairment'' (45 FR 80084). These...

  10. Male Team Sport Hazing Initiations in a Culture of Decreasing Homohysteria

    Science.gov (United States)

    Anderson, Eric; McCormack, Mark; Lee, Harry

    2012-01-01

    In this longitudinal ethnographic research, we report on 7 years of hazing rituals on two separate men's sports teams at one university in the United Kingdom. Using 38 in-depth interviews alongside naturalistic observations of the initiation rituals, we demonstrate that hazing activities have changed from being centered around homophobic same-sex…

  11. Feeling blue? Blue phosphors for OLEDs

    Directory of Open Access Journals (Sweden)

    Hungshin Fu

    2011-10-01

    Full Text Available Research on organic light emitting diodes (OLEDs has been revitalized, partly due to the debut of the OLED TV by SONY in 2008. While there is still plenty of room for improvement in efficiency, cost-effectiveness and longevity, it is timely to report on the advances of light emitting materials, the core of OLEDs, and their future perspectives. The focus of this account is primarily to chronicle the blue phosphors developed in our laboratory. Special attention is paid to the design strategy, synthetic novelty, and their OLED performance. The report also underscores the importance of the interplay between chemistry and photophysics en route to true-blue phosphors.

  12. Photolytic Hazes in the Atmosphere of 51 Eri b

    Science.gov (United States)

    Zahnle, K.; Marley, M. S.; Morley, C. V.; Moses, J. I.

    2016-06-01

    We use a 1D model to address photochemistry and possible haze formation in the irradiated warm Jupiter, 51 Eridani b. The intended focus was to be carbon, but sulfur photochemistry turns out to be important. The case for organic photochemical hazes is intriguing but falls short of being compelling. If organic hazes form, they are likeliest to do so if vertical mixing in 51 Eri b is weaker than in Jupiter, and they would be found below the altitudes where methane and water are photolyzed. The more novel result is that photochemistry turns H2S into elemental sulfur, here treated as S8. In the cooler models, S8 is predicted to condense in optically thick clouds of solid sulfur particles, while in the warmer models S8 remains a vapor along with several other sulfur allotropes that are both visually striking and potentially observable. For 51 Eri b, the division between models with and without condensed sulfur is at an effective temperature of 700 K, which is within error its actual effective temperature; the local temperature where sulfur condenses is between 280 and 320 K. The sulfur photochemistry we have discussed is quite general and ought to be found in a wide variety of worlds over a broad temperature range, both colder and hotter than the 650–750 K range studied here, and we show that products of sulfur photochemistry will be nearly as abundant on planets where the UV irradiation is orders of magnitude weaker than it is on 51 Eri b.

  13. Titan's Oxygen Chemistry and its Impact on Haze Formation

    Science.gov (United States)

    Vuitton, Veronique; Carrasco, Nathalie; Flandinet, Laurene; Horst, Sarah; Klippenstein, Stephen; Lavvas, Panayotis; Orthous-Daunay, Francois-Regis; Thissen, Roland; Yelle, Roger

    2016-06-01

    Though Titan's atmosphere is reducing with its 98% N2, 2% CH4 and 0.1% H2, CO is the fourth most abundant molecule with a uniform mixing ratio of ˜50 ppm. Two other oxygen bearing molecules have also been observed in Titan's atmosphere: CO2 and H2O, with a mixing ratio of ˜15 and ˜1 ppb, respectively. The physical and chemical processes that determine the abundances of these species on Titan have been at the centre of a long-standing debate as they place constraints on the origin and evolution of its atmosphere [1]. Moreover, laboratory experiments have shown that oxygen can be incorporated into complex molecules, some of which are building blocks of life [2]. Finally, the presence of CO modifies the production rate and size of tholins [3,4], which transposed to Titan's haze may have some strong repercussions on the temperature structure and dynamics of the atmosphere. We present here our current understanding of Titan's oxygen chemistry and of its impact on the chemical composition of the haze. We base our discussion on a photochemical model that describes the first steps of the chemistry and on state-of-the-art laboratory experiments for the synthesis and chemical analysis of aerosol analogues. We used a very-high resolution mass spectrometer (LTQ-Orbitrap XL instrument) to characterize the soluble part of tholin samples generated from N2/CH4/CO mixtures at different mixing ratios and with two different laboratory set-ups. These composition measurements provide some understanding of the chemical mechanisms by which CO affects particle formation and growth. Our final objective is to obtain a global picture of the fate and impact of oxygen on Titan, from its origin to prebiotic molecules to haze particles to material deposited on the surface.

  14. Enhanced orange-red emission from KSrVO4:Sm3+ nanophosphor for possible application in blue light-emitting diode based white LED

    International Nuclear Information System (INIS)

    In this paper, the combustion synthesis and photoluminescence properties of Sm3+ doped KSrVO4 nanophosphors are reported. The samples were characterized by different techniques such as x-ray powder diffraction, transmission electron microscopy, UV–vis spectrophotometry and photoluminescence spectroscopy. The lattice parameters were calculated as a=7.4688 (4) A-ring ´, b=5.8171 (4) A-ring ´, c=9.9490 (5) A-ring ´ and V=432.2485 (5) Ǻ3. The average grain size of the samples was estimated as 42 nm using the modified Scherrer’s equation. Under near UV excitation, the sharp emission line at 560, 600, 646 and 704 nm due to characteristic transitions of Sm3+ were observed. The maximum PL emission intensity was observed at 1.5 mol.% of the Sm3+ ions. The band gap of the phosphor was calculated from diffused reflectance data and was found to be 3.74 eV. The CIE 1931 chromaticity coordinates (x, y) of the phosphor were (0.61, 0.39), in a shade of orange-red color. The potential applications of this material as a down conversion phosphor under blue light excitation were evaluated for possible application as a high color-purity phosphor in light emitting diodes (LEDs) that can fill the 590–600 nm gap. (paper)

  15. A facile modification of g-C{sub 3}N{sub 4} with enhanced photocatalytic activity for degradation of methylene blue

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Fei, E-mail: feichang@usst.edu.cn [School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093 (China); Xie, Yunchao; Li, Chenlu; Chen, Juan; Luo, Jieru [School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093 (China); Hu, Xuefeng, E-mail: xfhu@yic.ac.cn [Key Laboratory of Coastal Zone Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, Shandong 264003 (China); Shen, Jiaowen [School of Urban Development and Environmental Engineering, Shanghai Second Polytechnic University, Shanghai 201209 (China)

    2013-09-01

    In this investigation, a facile modification of g-C{sub 3}N{sub 4} through co-pyrolysis of melamine and sodium nitrate or potassium nitrate was reported and the as-synthesized samples were characterized by a collection of techniques, such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, UV–vis diffuse reflectance spectroscopy, nitrogen adsorption–desorption, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and elemental analysis. Based upon the analysis, we speculated that the g-C{sub 3}N{sub 4} framework was partially destroyed to produce cyano-containing fragments, which resulted into the variation of physical and optical properties, further affecting the adsorption and photocatalytic performance of g-C{sub 3}N{sub 4} on the dye methylene blue. Furthermore, we found that nitrate anions rather than sodium or potassium ions had important effect on the structure and photocatalytic performance of g-C{sub 3}N{sub 4}. In addition, the photocatalysis mechanism and reusability test were also investigated and discussed in the study.

  16. Titan's Oxygen Chemistry and its Impact on Haze Formation

    Science.gov (United States)

    Vuitton, Veronique; Carrasco, Nathalie; Flandinet, Laurene; Horst, Sarah; Klippenstein, Stephen; Lavvas, Panayotis; Orthous-Daunay, Francois-Regis; Quirico, Eric; Thissen, Roland; Yelle, Roger V.

    2016-10-01

    Though Titan's atmosphere is reducing with its 98% N2, 2% CH4 and 0.1% H2, CO is the fourth most abundant molecule with a uniform mixing ratio of ~50 ppm. Two other oxygen bearing molecules have also been observed in Titan's atmosphere: CO2 and H2O, with a mixing ratio of ~15 and ~1 ppb, respectively. The physical and chemical processes that determine the abundances of these species on Titan have been at the centre of a long-standing debate as they place constraints on the origin and evolution of its atmosphere [1]. Moreover, laboratory experiments have shown that oxygen can be incorporated into complex molecules, some of which are building blocks of life [2]. Finally, the presence of CO modifies the production rate and size of tholins [3, 4], which transposed to Titan's haze may have some strong repercussions on the temperature structure and dynamics of the atmosphere.We present here our current understanding of Titan's oxygen chemistry and of its impact on the chemical composition of the haze. We base our discussion on a photochemical model that describes the first steps of the chemistry and on state-of-the-art laboratory experiments for the synthesis and chemical analysis of aerosol analogues. We used a very-high resolution mass spectrometer (LTQ-Orbitrap XL instrument) to characterize the soluble part of tholin samples generated from N2/CH4/CO mixtures at different mixing ratios and with two different laboratory set-ups. These composition measurements provide some understanding of the chemical mechanisms by which CO affects particle formation and growth. Our final objective is to obtain a global picture of the fate and impact of oxygen on Titan, from its origin to prebiotic molecules to haze particles to material deposited on the surface.[1] S.M. Hörst et al., The origin of oxygen species in Titan's atmosphere, J. Geophys. Res., 113, E10006 (2008).[2] S.M. Hörst et al., Formation of amino acids and nucleotide bases in a Titan atmosphere simulation experiment

  17. Blue Willow Story Plates

    Science.gov (United States)

    Fontes, Kris

    2009-01-01

    In the December 1997 issue of "SchoolArts" is a lesson titled "Blue Willow Story Plates" by Susan Striker. In this article, the author shares how she used this lesson with her middle-school students many times over the years. Here, she describes a Blue Willow plate painting project that her students made.

  18. From blue jeans to blue genes.

    Science.gov (United States)

    Boon, Laurence M; Vikkula, Miikka

    2009-03-01

    Cutaneous venous anomalies are common. They are blue and vary in size, number, and location and account for most consultations at specialized interdisciplinary clinics for vascular anomalies. Venous lesions are clinically important because they cause pain, dysfunction, destruction of adjacent tissues, and esthetic concern. Only resection and sclerotherapy are helpful, although not always curative. Understanding etiopathogenesis could help design animal models and develop novel therapeutic approaches. John B. Mulliken, MD, envisioned a project to uncover the genetic basis of an inherited form of venous malformation in a large New England family. Recruitment of 2 young fellows resulted in a collaborative project that unraveled the searched-for gene and its mutation. This was an opening for a new era in vascular anomalies. Two blue genes' mutations were discovered, which account for most, if not all, of the inherited forms of venous anomalies, but other genes as well, for rheologically diverse lesions. Differential diagnosis and management has improved, and animal models are being made. This was achieved through the help of Dr Mulliken, who inspired 2 young investigators in blue jeans to find 2 blue genes.

  19. Vertically-aligned sandwich nanowires enhance the photoelectrochemical reduction of hydrogen peroxide: hierarchical formation on carbon nanotubes of cadmium sulfide quantum dots and Prussian blue nanocoatings.

    Science.gov (United States)

    Gong, Kuanping

    2015-07-01

    We describe a vertically-aligned array of sandwiched nanowires comprising Prussian blue (PB) nanocoating-carbon nanotube (CNT) core-shell structures with CdS particles positioning at the core/shell interface, viz. PB/CdS/CNT. The PB/CdS/CNT electrode thus constructed are noticeable in synchronically harvesting photon-, ionic-, and chemical-energies, respectively, from visible light radiation, K(+) uptaking and releasing, and the reduction of H2O2. In 0.2 M K2SO4 aqueous solution, the photoelectrocatalytic reduction of 1.5 mM H2O2 at PB/CdS/CNT delivered the current density as high as 1.91 mA/cm(2) at reduced overpotential, that is, three times that at the Pt/C. This superb performance is causally linked to the judicious choice of materials and their assembly into defining sandwich nanostructures wherein the three components closely cooperate with each other in the photoelectrocatalytic reduction of H2O2, including photo-induced charge separation in CdS, spontaneous electron injection into PB due to its relatively low Fermi level, and the electrocatalytic reduction of H2O2 by PB via an electrochemical-chemical-electrochemical reaction mechanism. The structural alignment of PB/CdS/CNT ensures the simplest pathway for the mass diffusion and electron shuttle, and a high surface area accessible to the chemical and electrochemical reactions, so as to minimize the concentration- and electrochemical-polarization and thus ensure the fast overall kinetics of the electrode reaction. PMID:25458868

  20. Enhanced adsorptive and photocatalytic achievements in removal of methylene blue by incorporating tungstophosphoric acid-TiO2 into MCM-41

    International Nuclear Information System (INIS)

    The use of titania-dispersed materials in photocatalytic processes has been proposed as an alternative to the conventional bare TiO2, in order to modify the surface area and activity of the catalyst. A homogeneously dispersed Keggin unit into TiO2 was synthesized using tungstophosphoric acid (TPA) and titanium tetraisopropoxide. This compound was then loaded into MCM-41 by dispersing it in a suspension containing the mesoporous phase. Two other titanium-containing MCM-41 catalysts, Ti-MCM-41 and TiO2/MCM-41 were also prepared using isomorphous substitution synthesis method and impregnation method, respectively, for the sake of comparison. The prepared photocatalysts were characterized by X-ray diffraction (XRD), nitrogen physisorption (BET) and chemical analysis. The catalysts were used to study degradation of methylene blue (MB) in aqueous solution. XRD result shows a pure anatase crystalline phase for TPA-containing TiO2 indicating that there is good molecular distribution of tungstophosphoric acid into TiO2 structure. Supported TPA-TiO2 into MCM-41 shows both TPA-TiO2 and MCM-41 characteristic X-ray reflections in the high-angle and low-angle parts of the XRD patterns, respectively. The experimental results show that adsorption is a major constituent in the elimination of MB from the dye solutions by the TPA-containing materials. Exploitation of both adsorption and photocatalytic processes speeds up the removal of the dye using the TPA-TiO2-loaded MCM-41 photocatalyst. The elimination of MB is completed within 15 min for a 30 mg l-1 MB solution containing a catalyst dose of 100 mg/100 ml. The efficiencies of the other photocatalysts such as commercial TiO2, Ti-MCM-41, TiO2/MCM-41 and TPA-TiO2 for adsorption and degradation of MB were also studied and compared with that of the prepared catalyst.

  1. Societal-Equity-Enhancing Criteria and Facility-Host Incentives Supporting Five Key Elements in the January 2012 Blue Ribbon Commission Report - 13015

    International Nuclear Information System (INIS)

    In February 2009, the Obama Administration announced it would abandon USA's only candidate SNF/HLW-disposal facility since 1987. In 2010, all related activities were stopped and the Blue Ribbon Commission on America's Nuclear Future was established 'to recommend a new strategy for managing the back end of the nuclear fuel cycle', which it did in January 2012, emphasizing eight key elements. However, Key Element 1, 'A new, consent-based approach to siting future nuclear facilities', is qualitative/indeterminate rather than quantitative/measurable. It is thus highly-susceptible to semantic permutations that could extend rather than, as intended, expedite the siting of future nuclear facilities unless it also defines: a) Whose consent is needed?; and b) What constitutes consent? The following 'generic', radiation-risk- and societal-equity-based criteria address these questions: 1. Identify areas affected by projected radiation and other health risks from: a. The proposed nuclear facility (facility stakeholders); and b. The related nuclear-materials-transportation routes (transportation stakeholders); then 2. Surround each stakeholder area with a buffer zone and use this enlarged foot print to identify: a. Stakeholder hosts; and b. Areas not hosting any stakeholder category (interested parties). 3. Define 'consent-based' as being at least 60 percent of the 'population' in the respective stakeholder category and apply this yardstick to both 'in favor' and 'against' votes. Although criteria 1 and 2 also need facility-based definitions to make Key Element 1 measurable, the described siting approach, augmented by related facility-host incentives, would expedite the schedule and reduce the cost for achieving Key Elements 4-6 and 8, politics permitting. (authors)

  2. Proteome-Based Analysis of Colloidal Instability Enables the Detection of Haze-Active Proteins in Beer.

    Science.gov (United States)

    Schulte, Fabian; Flaschel, Erwin; Niehaus, Karsten

    2016-09-01

    Colloidal haze is a serious quality defect of bright beers that considerably reduces their shelf life and is thought to be triggered by hordeins, a class of proline-rich barley proteins. In this work, the proteomes of fresh and old beers were investigated in bottled pilsners and compared to the protein inventory of haze to identify specific haze-active proteins. Haze isolates dissolved in rehydration buffer contained high concentrations of proteins and sugars but provided protein gels with weak spot signals. Consequently, a treatment for the chemical deglycation with trifluoromethanesulfonic acid was applied, which resulted in the identification of protein Z4, LTP1, CMb, CMe, pUP13, 3a, and Bwiph as constituents of the haze proteome. Because only one hordein was detectable and the proline content in haze hydrolysates was lower than those of barley prolamins, our results suggest that this class of proteins is of minor importance for haze development. PMID:27515584

  3. Proteome-Based Analysis of Colloidal Instability Enables the Detection of Haze-Active Proteins in Beer.

    Science.gov (United States)

    Schulte, Fabian; Flaschel, Erwin; Niehaus, Karsten

    2016-09-01

    Colloidal haze is a serious quality defect of bright beers that considerably reduces their shelf life and is thought to be triggered by hordeins, a class of proline-rich barley proteins. In this work, the proteomes of fresh and old beers were investigated in bottled pilsners and compared to the protein inventory of haze to identify specific haze-active proteins. Haze isolates dissolved in rehydration buffer contained high concentrations of proteins and sugars but provided protein gels with weak spot signals. Consequently, a treatment for the chemical deglycation with trifluoromethanesulfonic acid was applied, which resulted in the identification of protein Z4, LTP1, CMb, CMe, pUP13, 3a, and Bwiph as constituents of the haze proteome. Because only one hordein was detectable and the proline content in haze hydrolysates was lower than those of barley prolamins, our results suggest that this class of proteins is of minor importance for haze development.

  4. Characteristics of atmospheric particulate mercury in size-fractionated particles during haze days in Shanghai

    Science.gov (United States)

    Chen, Xiaojia; Balasubramanian, Rajasekhar; Zhu, Qiongyu; Behera, Sailesh N.; Bo, Dandan; Huang, Xian; Xie, Haiyun; Cheng, Jinping

    2016-04-01

    Atmospheric particulate mercury (PHg) is recognized as a global pollutant that requires regulation because of its significant impacts on both human health and wildlife. The haze episodes that occur frequently in China could influence the transport and fate of PHg. To examine the characteristics of PHg during haze and non-haze days, size-fractioned particles were collected using thirteen-stage Nano-MOUDI samplers (10 nm-18 μm) during a severe haze episode (from December 2013 to January 2014) in Shanghai. The PHg concentration on haze days (4.11 ± 0.53 ng m-3) was three times higher than on non-haze days (1.34 ± 0.15 ng m-3). The ratio of the PHg concentration to total gaseous mercury (TGM) ranged from 0.42 during haze days to 0.21 during non-haze days, which was possibly due to the elevated concentration of particles for gaseous elemental mercury (GEM) adsorption, elevated sulfate and nitrate contributing to GEM oxidation, and the catalytic effect of elevated water-soluble inorganic metal ions. PHg/PM10 during haze days (0.019 ± 0.004 ng/μg) was lower than during non-haze days (0.024 ± 0.002 ng/μg), and PHg/PM10 was significantly reduced with an increasing concentration of PM10, which implied a relatively lower growth velocity of mercury than other compositions on particles during haze days, especially in the diameter range of 0.018-0.032 μm. During haze days, each size-fractioned PHg concentration was higher than the corresponding fraction on non-haze days, and the dominant particle size was in the accumulation mode, with constant accumulation to a particle size of 0.56-1.0 μm. The mass size distribution of PHg was bimodal with peaks at 0.32-0.56 μm and 3.1-6.2 μm on non-haze days, and 0.56-1.0 μm and 3.1-6.2 μm on haze days. There was a clear trend that the dominant size for PHg in the fine modes shifted from 0.32-0.56 μm during non-haze days to 0.56-1.0 μm on haze days, which revealed the higher growth velocity of PHg on haze days due to the

  5. Blue ocean strategy.

    Science.gov (United States)

    Kim, W Chan; Mauborgne, Renée

    2004-10-01

    Despite a long-term decline in the circus industry, Cirque du Soleil profitably increased revenue 22-fold over the last ten years by reinventing the circus. Rather than competing within the confines of the existing industry or trying to steal customers from rivals, Cirque developed uncontested market space that made the competition irrelevant. Cirque created what the authors call a blue ocean, a previously unknown market space. In blue oceans, demand is created rather than fought over. There is ample opportunity for growth that is both profitable and rapid. In red oceans--that is, in all the industries already existing--companies compete by grabbing for a greater share of limited demand. As the market space gets more crowded, prospects for profits and growth decline. Products turn into commodities, and increasing competition turns the water bloody. There are two ways to create blue oceans. One is to launch completely new industries, as eBay did with online auctions. But it's much more common for a blue ocean to be created from within a red ocean when a company expands the boundaries of an existing industry. In studying more than 150 blue ocean creations in over 30 industries, the authors observed that the traditional units of strategic analysis--company and industry--are of limited use in explaining how and why blue oceans are created. The most appropriate unit of analysis is the strategic move, the set of managerial actions and decisions involved in making a major market-creating business offering. Creating blue oceans builds brands. So powerful is blue ocean strategy, in fact, that a blue ocean strategic move can create brand equity that lasts for decades. PMID:15559577

  6. Blue ocean strategy.

    Science.gov (United States)

    Kim, W Chan; Mauborgne, Renée

    2004-10-01

    Despite a long-term decline in the circus industry, Cirque du Soleil profitably increased revenue 22-fold over the last ten years by reinventing the circus. Rather than competing within the confines of the existing industry or trying to steal customers from rivals, Cirque developed uncontested market space that made the competition irrelevant. Cirque created what the authors call a blue ocean, a previously unknown market space. In blue oceans, demand is created rather than fought over. There is ample opportunity for growth that is both profitable and rapid. In red oceans--that is, in all the industries already existing--companies compete by grabbing for a greater share of limited demand. As the market space gets more crowded, prospects for profits and growth decline. Products turn into commodities, and increasing competition turns the water bloody. There are two ways to create blue oceans. One is to launch completely new industries, as eBay did with online auctions. But it's much more common for a blue ocean to be created from within a red ocean when a company expands the boundaries of an existing industry. In studying more than 150 blue ocean creations in over 30 industries, the authors observed that the traditional units of strategic analysis--company and industry--are of limited use in explaining how and why blue oceans are created. The most appropriate unit of analysis is the strategic move, the set of managerial actions and decisions involved in making a major market-creating business offering. Creating blue oceans builds brands. So powerful is blue ocean strategy, in fact, that a blue ocean strategic move can create brand equity that lasts for decades.

  7. Co-precipitation synthesis of nano-composites consists of zinc and tin oxides coatings on glass with enhanced photocatalytic activity on degradation of Reactive Blue 160 KE2B.

    Science.gov (United States)

    Habibi, Mohammad Hossein; Mardani, Maryam

    2015-02-25

    Nano-composite containing zinc oxide-tin oxide was obtained by a facile co-precipitation route using tin chloride tetrahydrate and zinc chloride as precursors and coated on glass by Doctor Blade deposition. The crystalline structure and morphology of composites were evaluated by X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). The XRD results showed peaks relative to zinc oxide with hexagonal wurtzite structure and tin oxide with tetragonal structure. FESEM observations showed that the nano-composite consisted of aggregates of particles with an average particle size of 18 nm. The photocatalytic activity of the pure SnO2, pure ZnO, ZnSnO3-Zn2SnO4 and ZnO-SnO2 nano-structure thin films was examined using the degradation of a textile dye Reactive Blue 160 (KE2B). ZnO-SnO2 nano-composite showed enhanced photo-catalytic activity than the pure zinc oxide and tin oxide. The enhanced photo-catalytic activity of the nano-composite was ascribed to an improved charge separation of the photo-generated electron-hole pairs. PMID:25265524

  8. Ambient bioaerosol particle dynamics observed during haze and sunny days in Beijing.

    Science.gov (United States)

    Wei, Kai; Zou, Zhuanglei; Zheng, Yunhao; Li, Jing; Shen, Fangxia; Wu, Chang-Yu; Wu, Yusheng; Hu, Min; Yao, Maosheng

    2016-04-15

    The chemical characteristics of airborne particulate matter (PM) have been extensively studied; however, little information exists for its biological components (bioaerosol) especially during a haze event in mega cities. Herein, we studied the bioaerosol (fluorescent particle) dynamics on both haze and sunny days in Beijing from Dec. 2013 to March 2014 by employing a widely used real-time bioaerosol sensor-ultraviolet aerodynamic particle spectrometer (UV-APS). Firstly, we studied the fluorescent particle (BioPM) concentration and size distributions during three independent haze and three independent sunny days. Secondly, we investigated BioPM dynamics over a two-week long monitoring period which included consecutive haze days and alternated sunny days. In addition, we analyzed bacterial community structures and endotoxin levels in the air samples using pyrosequencing and Limulus amebocyte lysate (LAL) method, respectively. More than 6-fold higher fluorescent particle concentrations up to 5×10(5)/m(3) with peaks at night or early dawn were detected at the time of haze occurrences than those observed on sunny days. When the haze episode progressed for 3-5days, the BioPM concentrations were observed to decrease to the levels that were typically observed on sunny days. In general, ozone levels were found to be elevated at noon, while BioPM, NOx and relative humidity were reduced. Gene sequence analysis revealed no significant difference in abundances and community structures for top 13 bacterial genera between haze and sunny days, yet about twice higher endotoxin levels (12.4EU/m(3)) were detected on haze days than on sunny days. The results here facilitate a better understanding of atmospheric fluorescent particle dynamics including those under haze events. PMID:26849339

  9. Chemical characteristics of PM2.5 during a typical haze episode in Guangzhou

    Institute of Scientific and Technical Information of China (English)

    TAN Jihua; DUAN Jingchun; HE Kebin; MA Yuanliang; DUAN Fengkui; CHEN Yuan; FU Jiamo

    2009-01-01

    The chemical characteristics (water-soluble ions and carbonaceous species) of PM2.5 in Guangzhou were measured during a typical haze episode.Most of the chemical species in PM2.5 showed significant difference between normal and haze days.The highest contributors to PM2.5 were organic carbon (OC),nitrate,and sulfate in haze days and were OC,sulfate,and elemental carbon (EC) in normal days.The concentrations of secondary species such as,NO3-,SO42-,and NH4+ in haze days were 6.5,3.9 and 5.3 times higher than those in normal days,respectively,while primary species (EC,Ca2+,K+) show similar increase from normal to haze days by a factor about 2.2-2.4.OC/EC ratio ranged from 2.8 to 6.2 with an average of 4.7 and the estimation on a minimum OC/EC ratio showed that SOC (secondary organic carbon) accounted more than 36.6% for the total organic carbon in haze days.The significantly increase in the secondary species (SOC,NO3-,SO42-,and NH4+),especially in NO3-,caused the worst air quality in this region.Simultaneously,the result illustrated that the serious air pollution in haze episodes was strongly correlated with the meteorological conditions.During the sampling periods,air pollution and visibility have a good relationship with the air mass transport distance;the shorter air masses transport distance,the worse air quality and visibility in Guangzhou,indicating the strong domination of local sources contributing to haze formation.High concentration of the secondary aerosol in haze episodes was likely due to the higher oxidation rates of sulfur and nitrogen species.

  10. Ambient bioaerosol particle dynamics observed during haze and sunny days in Beijing.

    Science.gov (United States)

    Wei, Kai; Zou, Zhuanglei; Zheng, Yunhao; Li, Jing; Shen, Fangxia; Wu, Chang-Yu; Wu, Yusheng; Hu, Min; Yao, Maosheng

    2016-04-15

    The chemical characteristics of airborne particulate matter (PM) have been extensively studied; however, little information exists for its biological components (bioaerosol) especially during a haze event in mega cities. Herein, we studied the bioaerosol (fluorescent particle) dynamics on both haze and sunny days in Beijing from Dec. 2013 to March 2014 by employing a widely used real-time bioaerosol sensor-ultraviolet aerodynamic particle spectrometer (UV-APS). Firstly, we studied the fluorescent particle (BioPM) concentration and size distributions during three independent haze and three independent sunny days. Secondly, we investigated BioPM dynamics over a two-week long monitoring period which included consecutive haze days and alternated sunny days. In addition, we analyzed bacterial community structures and endotoxin levels in the air samples using pyrosequencing and Limulus amebocyte lysate (LAL) method, respectively. More than 6-fold higher fluorescent particle concentrations up to 5×10(5)/m(3) with peaks at night or early dawn were detected at the time of haze occurrences than those observed on sunny days. When the haze episode progressed for 3-5days, the BioPM concentrations were observed to decrease to the levels that were typically observed on sunny days. In general, ozone levels were found to be elevated at noon, while BioPM, NOx and relative humidity were reduced. Gene sequence analysis revealed no significant difference in abundances and community structures for top 13 bacterial genera between haze and sunny days, yet about twice higher endotoxin levels (12.4EU/m(3)) were detected on haze days than on sunny days. The results here facilitate a better understanding of atmospheric fluorescent particle dynamics including those under haze events.

  11. [Aerosol Optical Properties in the Northern Suburb of Nanjing During Haze Days in January 2013].

    Science.gov (United States)

    Wang, Li-peng; Ma, Yan; Zheng, Jun; Cui, Fen-ping; Zhou, Yao-yao

    2016-03-15

    In January 2013 large-scale, continuous and severe haze occurred in Nanjing. Three-wavelength photoacoustic soot spectrometer (PASS-3) was used for real-time, online and situ measurements of aerosol absorption and scattering coefficients in the northern suburb of Nanjing during January 2013. The results indicated that the average aerosol absorption and scattering coefficients were (83.20 ± 35.24) Mm⁻¹ and (670.16 ± 136.44) Mm⁻¹ during haze days, which were 3.85 and 3.45 times higher than those on clean days, respectively. The diurnal variation of absorption and scattering coefficients showed a bimodal distribution. The mean single scattering albedo and scattering Angstrom exponent were (0.89 ± 0.04) and (1.30 ± 0.27) respectively, indicating the predominance of scattering fine particles during haze days in Nanjing. Aerosols could be significantly removed by precipitation. The absorption and scattering coefficients showed negative correlations with surface wind speed, and the single scattering albedo and Angstrom exponent showed positive correlations with wind speed. Aerosol scattering coefficient was highest under southeasterly wind, whereas the absorption coefficient was highest under the southwesterly wind. In the three haze pollution events, Haze 1 and Haze 2 were mainly affected by long-range transportation of pollutants. Haze 1 was mainly affected by aging air mass from north Nanjing, Haze 2 was mainly affected by biomass burning air mass from southwest Nanjing, while Haze 3 was mainly caused by the high sulfate. PMID:27337871

  12. Developing the urban blue: Comparative health responses to blue and green urban open spaces in Germany.

    Science.gov (United States)

    Völker, Sebastian; Kistemann, Thomas

    2015-09-01

    Recently, new perspectives upon healthy urban open spaces propose that open spaces can be regarded as urban green or blue spaces. However, there has so far been very little research into blue environments and their benefits for mental well-being. Our article focuses on the effects of water in cities, "urban blue" (as compared to "urban green"), on human health and well-being. To assess the mental well-being of visitors, we conducted qualitative semi-standardised interviews (n=113), asking which differences in well-being occur when visiting urban green and blue spaces in high-density areas of the inner city in Dusseldorf and Cologne, Germany. Although we found many similarities, some health-enhancing effects for users turned out to be prominent for urban blue in the four conceptual therapeutic landscape dimensions: experienced, symbolic, social and activity space. These effects include enhanced contemplation, emotional bonding, participation, and physical activity. The results suggest that urban blue as a health-promoting factor needs more detailed and accurate determination and examination of its general and local health-enhancing effects.

  13. Effect of onion extract on corneal haze suppression after air assisted lamellar keratectomy

    OpenAIRE

    Kim, Soohyun; Park, Young Woo; LEE, Euiri; PARK, Sang Wan; Park, Sungwon; Noh, Hyunwoo; Kim, Jong Whi; Seong, Je Kyung; SEO, Kangmoon

    2015-01-01

    This study evaluated the effect of onion extract on corneal haze suppression after applying the air assisted lamellar keratectomy. The air assisted lamellar keratectomy was performed on 24 canine eyes. They were treated with an artificial tear (group C), prednisolone acetate (group P), onion extract (group O) and TGF-β1 (group T) three times per day from 7 to 28 days after the surgery. Corneal haze occurred on the all eyes and was observed beginning 7 days after the surgery. The haze was sign...

  14. Unlinking absorption and haze in thin film silicon solar cells front electrodes

    OpenAIRE

    Boccard, Mathieu; Cuony, Peter; Battaglia, Corsin; Despeisse, Matthieu; Ballif, Christophe

    2010-01-01

    We study the respective influence of haze and free carrier absorption (FCA) of transparent front electrodes on the photogenerated current of micromorph thin film silicon solar cells. To decouple the haze and FCA we develop bi-layer front electrodes: a flat indium tin oxide layer assures conduction and allows us to tune FCA while the haze is adjusted by varying the thickness of a highly transparent rough ZnO layer. We show how a minimum amount of FCA leads only to a few percents absorption for...

  15. 浅谈雾和霾%Discussion on Fog and Haze

    Institute of Scientific and Technical Information of China (English)

    苗万强

    2013-01-01

    The paper discusses the causes, hazards of fog and haze, describes the influence of fog and haze on people's lives and puts forward scientific methods control fog and haze.%从雾和霾的成因、危害等方面的不同,进行了详细的论述,阐述了雾和霾对人们生活的影响,提出了应对雾和霾,科学预防、减小危害的方法。

  16. Pollutional haze and COPD: etiology, epidemiology, pathogenesis, pathology, biological markers and therapy.

    Science.gov (United States)

    Wang, Fei; Ni, Song-Shi; Liu, Hua

    2016-01-01

    In recent years, serious pollutional haze occurs in the mainland of China thanks to the development of urbanization and industrialization. There is a close relationship between air pollution and the occurrence and development of chronic obstructive pulmonary disease (COPD), but there are some new characteristics in some aspects of COPD associated with pollutional haze compared with COPD induced by traditional physical and chemical factors. This article attempts to summarize the new progress from these new features of COPD related to pollutional haze, focus on etiology, epidemiology, pathogenesis, pathology, biological markers and therapy.

  17. Latitudinal variations in Titan's methane and haze from Cassini VIMS observations

    Science.gov (United States)

    Penteado, P.F.; Griffith, C.A.; Tomasko, M.G.; Engel, S.; See, C.; Doose, L.; Baines, K.H.; Brown, R.H.; Buratti, B.J.; Clark, R.; Nicholson, P.; Sotin, C.

    2010-01-01

    We analyze observations taken with Cassini's Visual and Infrared Mapping Spectrometer (VIMS), to determine the current methane and haze latitudinal distribution between 60??S and 40??N. The methane variation was measured primarily from its absorption band at 0.61 ??m, which is optically thin enough to be sensitive to the methane abundance at 20-50 km altitude. Haze characteristics were determined from Titan's 0.4-1.6 ??m spectra, which sample Titan's atmosphere from the surface to 200 km altitude. Radiative transfer models based on the haze properties and methane absorption profiles at the Huygens site reproduced the observed VIMS spectra and allowed us to retrieve latitude variations in the methane abundance and haze. We find the haze variations can be reproduced by varying only the density and single scattering albedo above 80 km altitude. There is an ambiguity between methane abundance and haze optical depth, because higher haze optical depth causes shallower methane bands; thus a family of solutions is allowed by the data. We find that haze variations alone, with a constant methane abundance, can reproduce the spatial variation in the methane bands if the haze density increases by 60% between 20??S and 10??S (roughly the sub-solar latitude) and single scattering absorption increases by 20% between 60??S and 40??N. On the other hand, a higher abundance of methane between 20 and 50 km in the summer hemisphere, as much as two times that of the winter hemisphere, is also possible, if the haze variations are minimized. The range of possible methane variations between 27??S and 19??N is consistent with condensation as a result of temperature variations of 0-1.5 K at 20-30 km. Our analysis indicates that the latitudinal variations in Titan's visible to near-IR albedo, the north/south asymmetry (NSA), result primarily from variations in the thickness of the darker haze layer, detected by Huygens DISR, above 80 km altitude. If we assume little to no latitudinal methane

  18. Blue Ribbon Panel Report

    Science.gov (United States)

    An NCI Cancer Currents blog by the NCI acting director thanking the cancer community for contributing to the Cancer Moonshot Blue Ribbon Panel report, which was presented to the National Cancer Advisory Board on September 7.

  19. New York Blue

    Data.gov (United States)

    Federal Laboratory Consortium — New York Blue is used cooperatively by the Laboratory and Stony Brook University as part of the New York Center for Computation Sciences. Ranked as the 28th fastest...

  20. Visualising DNA in Classrooms Using Nile Blue

    Science.gov (United States)

    Milne, Christine; Roche, Scott; McKay, David

    2008-01-01

    Giving students the opportunity to extract, manipulate and visualise DNA molecules enhances a constructivist approach to learning about modern techniques in biology and biotechnology Visualisation usually requires agarose gel electrophoresis and staining. In this article, we report on an alternative DNA stain, Nile Blue A, that may be used in the…

  1. Measuring Corneal Haze by Using Scheimpflug Photography and Confocal Microscopy

    Science.gov (United States)

    McLaren, Jay W.; Wacker, Katrin; Kane, Katrina M.; Patel, Sanjay V.

    2016-01-01

    Purpose We compared corneal backscatter estimated from a Scheimpflug camera with backscatter estimated from a clinical confocal microscope across a wide range of corneal haze. Methods A total of 59 corneas from 35 patients with a range of severity of Fuchs' endothelial corneal dystrophy and 15 corneas from 9 normal participants were examined using a Scheimpflug camera (Pentacam) and a confocal microscope (ConfoScan 4). The mean image brightness from the anterior 120 μm, midcornea, and posterior 60 μm of the cornea across the central 2 mm recorded by the Scheimpflug camera and analogous regions from the confocal microscope were measured and standardized. Differences between instruments and correlations between backscatter and disease severity were determined by using generalized estimating equation models. Results Backscatter measured by the two instruments in the anterior and midcornea were correlated (r = 0.67 and 0.43, respectively, P < 0.001), although in the posterior cornea they were not correlated (r = 0.13, P = 0.66). Measured with the Scheimpflug camera, mean backscatter from the anterior and midcornea were greater, whereas backscatter from the posterior cornea was lower (P < 0.001) than that measured by the confocal microscope. Backscatter from the anterior cornea was correlated with disease severity for both instruments (Scheimpflug, r = 0.55, P < 0.001; confocal, r = 0.49, P = 0.003). Conclusions The Scheimpflug camera and confocal microscope should not be used interchangeably to measure corneal haze. The ability to detect changes in backscatter with disease severity is superior with the Scheimpflug camera. However, the confocal microscope provides higher resolution of corneal structure. PMID:26803798

  2. Haze defect control and containment in a high volume DRAM manufacturing environment

    Science.gov (United States)

    Chen, Jerry X.; Nguyen, Maihan; Arasaki, Osamu; Maraquin, Tammy; Sawyer, Daniel; Morrison, Pedro

    2005-11-01

    Haze and other progressive reticle defects have been known in the semiconductor industry for more than a decade [1]. Extensive research and experiments have been carried out to determine the sources and origins of the progressive haze growth, but the true mechanisms of its cause are still under speculation. To minimize the wafer yield loss at Samsung Austin Semiconductor (SAS), we introduced a practical method to control the haze defects in a DRAM manufacturing environment that integrates reticle and wafer inspections, reticle cleaning, and a dose-based and time-based control forecast software system. This development has been proven to be very effective in controlling the haze defects and reducing the related yield loss while still supporting high volume wafer production.

  3. A Fast Single Image Haze Removal Algorithm Using Color Attenuation Prior.

    Science.gov (United States)

    Zhu, Qingsong; Mai, Jiaming; Shao, Ling

    2015-11-01

    Single image haze removal has been a challenging problem due to its ill-posed nature. In this paper, we propose a simple but powerful color attenuation prior for haze removal from a single input hazy image. By creating a linear model for modeling the scene depth of the hazy image under this novel prior and learning the parameters of the model with a supervised learning method, the depth information can be well recovered. With the depth map of the hazy image, we can easily estimate the transmission and restore the scene radiance via the atmospheric scattering model, and thus effectively remove the haze from a single image. Experimental results show that the proposed approach outperforms state-of-the-art haze removal algorithms in terms of both efficiency and the dehazing effect.

  4. Structure of haze forming proteins in white wines: Vitis vinifera thaumatin-like proteins.

    Directory of Open Access Journals (Sweden)

    Matteo Marangon

    Full Text Available Grape thaumatin-like proteins (TLPs play roles in plant-pathogen interactions and can cause protein haze in white wine unless removed prior to bottling. Different isoforms of TLPs have different hazing potential and aggregation behavior. Here we present the elucidation of the molecular structures of three grape TLPs that display different hazing potential. The three TLPs have very similar structures despite belonging to two different classes (F2/4JRU is a thaumatin-like protein while I/4L5H and H2/4MBT are VVTL1, and having different unfolding temperatures (56 vs. 62°C, with protein F2/4JRU being heat unstable and forming haze, while I/4L5H does not. These differences in properties are attributable to the conformation of a single loop and the amino acid composition of its flanking regions.

  5. Transboundary smoke haze pollution in Malaysia: inpatient health impacts and economic valuation.

    Science.gov (United States)

    Othman, Jamal; Sahani, Mazrura; Mahmud, Mastura; Ahmad, Md Khadzir Sheikh

    2014-06-01

    This study assessed the economic value of health impacts of transboundary smoke haze pollution in Kuala Lumpur and adjacent areas in the state of Selangor, Malaysia. Daily inpatient data from 2005, 2006, 2008, and 2009 for 14 haze-related illnesses were collected from four hospitals. On average, there were 19 hazy days each year during which the air pollution levels were within the Lower Moderate to Hazardous categories. No seasonal variation in inpatient cases was observed. A smoke haze occurrence was associated with an increase in inpatient cases by 2.4 per 10,000 populations each year, representing an increase of 31 percent from normal days. The average annual economic loss due to the inpatient health impact of haze was valued at MYR273,000 ($91,000 USD).

  6. The Occurrence of Haze in Malaysia: A Case Study in an Urban Industrial Area

    Science.gov (United States)

    Soleiman, A.; Othman, M.; Samah, A. A.; Sulaiman, N. M.; Radojevic, M.

    - Klang Valley, a heavily industrialized urban area in Malaysia, has experienced severe haze episodes since the early 1980s. Total Suspended Particulate matter (TSP) is used in studying this phenomenon. Three severe haze episodes during the early 1990s are reviewed; August 1990, October 1991, and August-October 1994. The nature of these episodes, their possible causes, and their major features are discussed. Meteorological conditions associated with these episodes were analyzed. Results of the study indicate that stability and trapping of particles are the main factors affecting the pollution during haze periods. Maximum total suspended matter (TSP) was recorded in October 1991. The August-October 1994 episode was the most persistent and least affected by meteorological variables. Analysis of wind direction data showed that southerly and southwesterly winds coincided with the worst haze periods.

  7. The Blues of David Lynch

    OpenAIRE

    Roche, David

    2009-01-01

    This article is an attempt to elaborate a typology of the color blue in the color films of David Lynch up to and including Mulholland Drive (2001). The color blue is considered alternately as light, matter or verbal language. The author studies the use, function, value and meaning of blue lighting, divided into static and flashing light, and of the blue objects in Blue Velvet (1986) and Mulholland Drive. The author shows how Lynch appropriates connotations Western culture, under the influence...

  8. Characteristics and issues of haze management in a wafer fabrication environment

    Science.gov (United States)

    Woo, Sung Ha; Hwang, Dae Ho; Jeong, Goo Min; Lee, Young Mo; Kim, Sang Pyo; Yim, Dong Gyu

    2014-10-01

    The haze nucleation and growth phenomenon on critical photomask surfaces has periodically gained attention as it has significantly impacted wafer printability for different technology nodes over the years. A number of process solutions have been promoted in the semiconductor industry which has been shown to suppress or minimize the propensity for haze formation, but none of these technologies can stop every instance of haze. Fortunately, a novel technology which uses a dry (no chemical effluents) removal system, laser-based, through pellicle process has been reported recently. The technology presented here avoids many of the shortcomings of the wet clean process mentioned previously. The dry clean process extends the life of the photomask; maintains more consistent CD's, phase, and transmission; avoids adjustment to the exposure dose to account for photomask changes, reduces the number of required inspections and otherwise improves the efficiency and predictability of the lithography cell. We report on the performance of photomask based on a design developed to study the impact of metrology variations on dry clean process. In a first step we focus on basic characteristics: CD variation, phase, Cr/MoSi transmission, pellicle transmission, registration variations. In a second step, we evaluate haze removal and prevention performance and wafer photo margin. Haze removal is studied on the masks for several haze types and various exposure conditions. The results of this study show that some of metrology variation are likely to be a problem at high technology node, and haze removal performance is determined whether the component of haze is remained or not after treatment.

  9. The Link between Knowledge, Attitudes and Practices in Relation to Atmospheric Haze Pollution in Peninsular Malaysia

    OpenAIRE

    Laura De Pretto; Stephen Acreman; Matthew J Ashfold; Mohankumar, Suresh K.; Ahimsa Campos-Arceiz

    2015-01-01

    Transboundary haze episodes caused by seasonal forest fires have become a recurrent phenomenon in Southeast Asia, with serious environmental, economic, and public health implications. Here we present a cross-sectional survey conducted among people in Kuala Lumpur and surrounds to assess the links between knowledge, attitudes, and practices in relation to the transboundary haze episodes. Of 305 respondents, 125 were amateur athletes participating in a duathlon event and the remainder were surv...

  10. NIR-light-induced surface-enhanced Raman scattering for detection and photothermal/photodynamic therapy of cancer cells using methylene blue-embedded gold nanorod@SiO2 nanocomposites.

    Science.gov (United States)

    Seo, Sun-Hwa; Kim, Bo-Mi; Joe, Ara; Han, Hyo-Won; Chen, Xiaoyuan; Cheng, Zhen; Jang, Eue-Soon

    2014-03-01

    Methylene blue-loaded gold nanorod@SiO2 (MB-GNR@SiO2) core@shell nanoparticles are synthesized for use in cancer imaging and photothermal/photodynamic dual therapy. For the preparation of GNR@SiO2 nanoparticles, we found that the silica coating rate of hexadecylcetyltrimethylammonium bromide (CTAB)-capped GNRs is much slower than that of PEGylated GNRs due to the densely coated CTAB bilayer. Encapsulated MB molecules have both monomer and dimer forms that result in an increase in the photosensitizing effect through different photochemical pathways. As a consequence of the excellent plasmonic properties of GNRs at near-infrared (NIR) light, the embedded MB molecules showed NIR light-induced SERS performance with a Raman enhancement factor of 3.0 × 10(10), which is enough for the detection of a single cancer cell. Moreover, the MB-GNR@SiO2 nanoparticles exhibit a synergistic effect of photodynamic and photothermal therapies of cancer under single-wavelength NIR laser irradiation.

  11. Clearance capacity of the atmosphere: the reason that the number of haze days reaches a ceiling.

    Science.gov (United States)

    Liu, Qian; Cao, Ziqi; Xu, Hua

    2016-04-01

    China has experienced rapid development in the past 30 years but, alongside and associated with this growth, increased levels of pollution too. However, despite the continued increase in emissions of haze-forming aerosols in the twenty-first century, the annual number of haze days in some megacities has not risen in tandem. Various mechanisms have been proposed for "city dimming", but the cause of the hiatus remains unclear. We found that the number of haze days in Taiyuan experienced a sharp increase during 1980-1998, with a growth rate 51.6 days/10a, and then exhibited fluctuating variation around a stable high level from 1998 to 2014, while at the same time the average visibility during haze days started to decrease. We present a novel method to explain the long-term variation in the number of haze days via a temporal-piecewise function of human activities and atmospheric cleaning processes: the number of haze days increases with the level of human activity before reaching the upper limit and then remains at a high level due to the restriction of a relatively stable number of strong cleaning days.

  12. Changes in chemical components of aerosol particles in different haze regions in China from 2006 to 2013 and contribution of meteorological factors

    Directory of Open Access Journals (Sweden)

    X. Y. Zhang

    2015-07-01

    components were similar to those in YRD; accounted approximately 60–80 % of these in HBP. Since 2010, a decline was found for winter concentrations, which can be partially attributable to a persistent bettering meteorological conditions and the emission cutting with an emphasis on coal-combustion in this area. In addition to the scattered and centralized coal-combustion for heating, burning biomass fuel contributed to the large increase in the concentrations of carbonaceous aerosol in major haze regions, except in PRD, in winter. No obvious changes were found for the proportions of each chemical components of PM10 from 2006 to 2013. Among all of the emissions recorded in chemical compositions in 2013, coal-combustion was still the largest anthropogenic source of aerosol pollution in various areas in China, with higher sulphate proportion of PM10 in most areas of China. OC normally ranked the third. PM10 concentration increased by approximately 25 % in January of 2013 relative to 2012 that caused persistent haze-fog events in HBP; emission also reduced by approximately 35 % in Beijing and its vicinity (BIV in late fall of 2014, thereby producing "APEC" blue; thus one can expect that the persistent haze-fog events would be reduced significantly in the BIV, if ~ one-third of the 2013 winter emission could be reduced, which can also be viewed as the upper limit of atmospheric aerosol pollution capacity in this area.

  13. Changes in chemical components of aerosol particles in different haze regions in China from 2006 to 2013 and contribution of meteorological factors

    Science.gov (United States)

    Zhang, X. Y.; Wang, J. Z.; Wang, Y. Q.; Liu, H. L.; Sun, J. Y.; Zhang, Y. M.

    2015-11-01

    significant changes. In the Pearl River Delta (PRD) area, the regional background concentrations of the major chemical components were similar to those in the YRD, accounting for approximately 60-80 % of those in HBP. Since 2010, a decline has been found for winter concentrations, which can be partially attributable to persistently improving meteorological conditions and emission cutting with an emphasis on coal combustion in this area. In addition to the scattered and centralized coal combustion for heating, burning biomass fuels contributed to the large increase in concentrations of carbonaceous aerosol in major haze regions in winter, except in the PRD. No obvious changes were found for the proportions of each chemical components of PM10 from 2006 to 2013. Among all of the emissions recorded in chemical compositions in 2013, coal combustion was still the largest anthropogenic source of aerosol pollution in various areas in China, with a higher sulfate proportion of PM10 in most areas of China, and OC was normally ranked third. PM10 concentrations increased by approximately 25 % in January of 2013 relative to 2012, which caused persistent haze-fog events in HBP; emissions also reduced by approximately 35 % in Beijing and its vicinity (BIV) in late autumn of 2014, thereby producing the Asia Pacific Economic Cooperation (APEC) blue (extremely good air quality); thus, one can expect that the persistent haze-fog events would be reduced significantly in the BIV, if approx. one-third of the 2013 winter emissions were reduced, which can also be viewed as the upper limit of atmospheric aerosol pollution capacity in this area.

  14. Beyond Deep Blue

    CERN Document Server

    Newborn, Monty

    2011-01-01

    More than a decade has passed since IBM's Deep Blue computer stunned the world by defeating Garry Kasparov, the world chess champion at that time. Beyond Deep Blue tells the continuing story of the chess engine and its steady improvement. The book provides analysis of the games alongside a detailed examination of the remarkable technological progress made by the engines - asking which one is best, how good is it, and how much better can it get. Features: presents a total of 118 games, played by 17 different chess engines, collected together for the first time in a single reference; details the

  15. A Blue Lagoon Function

    DEFF Research Database (Denmark)

    Markvorsen, Steen

    2007-01-01

    We consider a specific function of two variables whose graph surface resembles a blue lagoon. The function has a saddle point $p$, but when the function is restricted to any given straight line through $p$ it has a {\\em{strict local minimum}} along that line at $p$.......We consider a specific function of two variables whose graph surface resembles a blue lagoon. The function has a saddle point $p$, but when the function is restricted to any given straight line through $p$ it has a {\\em{strict local minimum}} along that line at $p$....

  16. The Blue Collar Brain

    Directory of Open Access Journals (Sweden)

    Guy eVan Orden

    2012-06-01

    Full Text Available Much effort has gone into elucidating control of the body by the brain, less so the role of the body in controlling the brain. This essay develops the idea that the brain does a great deal of work in the service of behavior that is controlled by the body, a blue collar role compared to the white collar control exercised by the body. The argument that supports a blue collar role for the brain is also consistent with recent discoveries clarifying the white collar role of synergies across the body's tensegrity structure, and the evidence of critical phenomena in brain and behavior.

  17. Impact of 2013 south Asian haze crisis: study of physical and psychological symptoms and perceived dangerousness of pollution level

    OpenAIRE

    Ho, Roger C; Zhang, Melvyn W; Ho, Cyrus S; Pan, Fang; Lu, Yanxia; Sharma, Vijay K.

    2014-01-01

    Background The widespread forest fires in Indonesia in June 2013 led to widespread haze to neighbouring countries. This is the first study in the medical literature reporting the acute physical and psychological symptoms of the general population during a haze crisis. We evaluated the factors that are associated with psychological stress of haze exposure. Methods This study was conducted between June 21 to June 26, 2013. Participants were recruited by an online recruitment post and snowball s...

  18. The distribution and trends of fog and haze in the North China Plain over the past 30 years

    Directory of Open Access Journals (Sweden)

    G. Q. Fu

    2014-06-01

    Full Text Available Frequent low visibility, haze and fog events were found in the North China Plain (NCP. Data throughout the NCP during the past 30 years were examined to determine the horizontal distribution and decadal trends of low visibility, haze and fog events. The impact of meteorological factors such as wind and RH on those events was investigated. Results reveal distinct distributions of haze and fog days, due to their different formation mechanisms. Low visibility, haze and fog days all display increasing trends of before 1995, a steady stage during 1995–2003 and a drastically drop thereafter. All three events occurred most frequently during the heating season. Benefiting from emission control measures, haze and fog both show decreasing trends in winter during the past 3 decades, while summertime haze displays continuous increasing trends. The distribution of wind speed and wind direction as well as the topography within the NCP has determinative impacts on the distribution of haze and fog. Weakened south-easterly winds in the southern part of the NCP has resulted in high pollutant concentrations and frequent haze events along the foot of the Taihang Mountains. The orographic wind convergence zone in the central band area of the southern NCP is responsible for the frequent fog events in this region. Wind speed has been decreasing throughout the entire southern NCP, resulting in more stable atmospheric conditions and weaker dispersion abilities, calling for harder efforts to control emissions to prevent haze events. Haze events are strongly influenced by the ambient RH. RH values associated with haze days are evidently increasing, suggesting that an increasing fraction of haze events are caused by the hygroscopic growth of aerosols, rather than simply by high aerosol loadings.

  19. Singapore Haze in June 2013: Consequences of Land-Use Change, Fires, and Anomalous Meteorology for Air Quality in Equatorial Asia

    Science.gov (United States)

    Koplitz, S.; Mickley, L. J.; Jacob, D. J.; Kim, P. S.; DeFries, R. S.; Marlier, M. E.; Schwartz, J.; Buonocore, J.; Myers, S. S.

    2014-12-01

    Much of Equatorial Asia is currently undergoing extensive burning from agricultural fires and rapid land-use conversion to oil palm plantations, with substantial consequences for air quality and health. In June 2013, Singapore experienced severe smoke levels, with surface particulate matter concentrations greater than ten times average. Unlike past haze events in Singapore (e.g. September 1997 and October 2006), the June 2013 pollution event occurred during El Nino-neutral conditions. Using a combination of observations and chemical transport modeling, we examine relationships between sea surface temperatures, wind fields, fire patterns, and aerosol optical depth during the June 2013 haze event. We find reasonable agreement between satellite measurements of aerosol optical depth (AOD) from the MODIS and MISR instruments and in-situ measurements from the AERONET stations across Equatorial Asia for 2005-2010 (MODIS R2 = 0.39, bias = -1.6%; MISR R2 = 0.27, bias = -42%). However, AOD observations fail to capture the Singapore pollution event of June 2013. Simulations with the GEOS-Chem model suggest that anomalously high dust concentrations during June 2013 may have impaired the ability of MODIS to monitor the haze over Singapore. In contrast, we show that the OMI Aerosol Index can effectively capture these smoke events and may be used to monitor future haze episodes in Equatorial Asia. We find that the June 2013 haze in Singapore may be attributed to anomalously strong westerlies carrying smoke from Riau Province in Indonesia. These westerlies, 5 m s-1 faster than the 2005-2010 mean June winds, are consistent with the phase of the Madden-Julian Oscillation (MJO) crossing the Maritime Continent at that time. These westerlies may have been further enhanced by a negative phase of the Indian Ocean Dipole (IOD), an east-west gradient in sea surface temperature anomalies across the Indian Ocean, with cold sea surface temperature anomalies (-3 C°) off the Arabian coast and

  20. [Chemical Characteristics of Particulate Matters and Trajectory Influence on Air Quality in Shanghai During the Heavy Haze Episode in December, 2013].

    Science.gov (United States)

    Zhou, Min; Qiao, Li-ping; Zhu, Shu-hui; Li, Li; Lou, Sheng-rong; Wang, Hong-li; Tao, Shi-kang; Huang, Cheng; Chen, Chang-hong

    2016-04-15

    Intensive haze shrouded central and eastern parts of China in Dec. 2013. In this study, the mass concentrations of gaseous and particulate pollutants, and also the chemical compositions of fine particulate matters were obtained based on in-situ measurement in Shanghai urban area. The characteristics of PM2.5 were investigated during different pollution episodes, including dust, haze, fog-haze and long-rang transport episodes. The results showed that pollution was most serious during the fog-haze episode, during which the maximum daily mass concentrations of PM10 and PM2.5 reached 536 microg x m(-3) and 411 microg x m(-3), respectively. During the fog-haze episode, the ratio of PM2.5 to PM10 was over 76.7%, suggesting that high humidity enhanced the secondary formation of NO3-, SO4(2-) and NH4+ in PM2.5. Highest concentration of Ca2+ in PM2.5 occurred during the dust episode and the proportion of primary components in PM2.5 increased obviously. Highest concentration of SO2- was observed in PM25 during the long-range transport episode, with a fast growth rate. Meanwhile, the trajectories reaching Shanghai urban area and cluster analysis during different pollution episodes were simulated by HYSPLIT model. Combined with observation data of PM2.5 in Shanghai urban area, chemical characteristics of PM2.5 in different clusters and potential source apportionment of various pollution episodes were also studied in this study. The result revealed that the air trajectories could be grouped into six clusters based on their spatial similarities. Among these clusters, cluster6 which moved fast was associated with clean air. Cluster2 and cluster3 originating from Mongolia region had strong correlations to dust pollution, along with low PM2.5/PM10 ratio and high concentration of Ca2+ in PM2.5. Compared with other clusters, cluster5 and cluster4 with slow moving speed were more favorable for reactions between particulate species and formation of secondary pollutants during transport

  1. [Chemical Characteristics of Particulate Matters and Trajectory Influence on Air Quality in Shanghai During the Heavy Haze Episode in December, 2013].

    Science.gov (United States)

    Zhou, Min; Qiao, Li-ping; Zhu, Shu-hui; Li, Li; Lou, Sheng-rong; Wang, Hong-li; Tao, Shi-kang; Huang, Cheng; Chen, Chang-hong

    2016-04-15

    Intensive haze shrouded central and eastern parts of China in Dec. 2013. In this study, the mass concentrations of gaseous and particulate pollutants, and also the chemical compositions of fine particulate matters were obtained based on in-situ measurement in Shanghai urban area. The characteristics of PM2.5 were investigated during different pollution episodes, including dust, haze, fog-haze and long-rang transport episodes. The results showed that pollution was most serious during the fog-haze episode, during which the maximum daily mass concentrations of PM10 and PM2.5 reached 536 microg x m(-3) and 411 microg x m(-3), respectively. During the fog-haze episode, the ratio of PM2.5 to PM10 was over 76.7%, suggesting that high humidity enhanced the secondary formation of NO3-, SO4(2-) and NH4+ in PM2.5. Highest concentration of Ca2+ in PM2.5 occurred during the dust episode and the proportion of primary components in PM2.5 increased obviously. Highest concentration of SO2- was observed in PM25 during the long-range transport episode, with a fast growth rate. Meanwhile, the trajectories reaching Shanghai urban area and cluster analysis during different pollution episodes were simulated by HYSPLIT model. Combined with observation data of PM2.5 in Shanghai urban area, chemical characteristics of PM2.5 in different clusters and potential source apportionment of various pollution episodes were also studied in this study. The result revealed that the air trajectories could be grouped into six clusters based on their spatial similarities. Among these clusters, cluster6 which moved fast was associated with clean air. Cluster2 and cluster3 originating from Mongolia region had strong correlations to dust pollution, along with low PM2.5/PM10 ratio and high concentration of Ca2+ in PM2.5. Compared with other clusters, cluster5 and cluster4 with slow moving speed were more favorable for reactions between particulate species and formation of secondary pollutants during transport

  2. Blue-green algae

    Science.gov (United States)

    ... for 6 months relieves allergy symptoms in adults. Arsenic poisoning. Early research shows that taking a combination of blue-green algae and zinc by mouth twice daily for 12 weeks reduces arsenic levels and its effects on the skin in ...

  3. The Blue Denmark

    DEFF Research Database (Denmark)

    Hansen, Carsten Ørts; Sornn-Friese, Henrik

    This paper makes an important contribution to the discussion about knowledge based localised externalities in the context of shipping and the maritime sector in Denmark. In the paper we ask if there is a national, knowledge‐based maritime cluster configured around the shipowners in Denmark. This ...... talk about The Blue Denmark....

  4. The "Blue Banana" Revisited

    NARCIS (Netherlands)

    Faludi, A.K.F.

    2015-01-01

    This essay is about the “Blue Banana”. Banana is the name given subsequently by others to a Dorsale européenne (European backbone) identified empirically by Roger Brunet. In a background study to the Communication of the European Commission ‘Europe 2000’, Klaus Kunzmann and Michael Wegener put forwa

  5. Formation and evolution mechanism of regional haze: a case study in the megacity Beijing, China

    Directory of Open Access Journals (Sweden)

    X. Liu

    2012-07-01

    Full Text Available The main objective of this study is to investigate the formation and evolution mechanism of the regional haze in megacity Beijing by analyzing the process of a severe haze that occurred 20–27 September 2011. Mass concentration and size distribution of aerosol particles as well as aerosol optical properties were concurrently measured at the Beijing urban atmospheric environment monitoring station. Gaseous pollutants (SO2, NO-NO2-NOx, O3, CO and meteorological parameters (wind speed, wind direction, and relative humidity (RH were simultaneously monitored. Meanwhile, aerosol spatial distribution and the height of planetary boundary layer (PBL were retrieved from the signal of satellite and LIDAR (light detection and ranging. Results showed that high intensity of local pollutants from Beijing urban source is the fundamental cause that led to the regional haze. Meteorological factors such as higher RH, weak surface wind speed, and decreasing height of PBL played an important role on the deterioration of air quality. New particle formation was considered to be the most important factor contributing the formation of haze. In order to improve the atmospheric visibility and reduce the occurrence of the haze, the mass concentration of PM2.5 at dry condition should be less than 60 µg m−3 in Beijing according to the empirical relationship of visibility, PM2.5 mass concentration and RH. This case study may provide valuable information for the public to recognize the formation mechanism of the regional haze event over the megacity, which is also useful for the government to adopt scientific approach to forecast and eliminate the occurrence of regional haze in China.

  6. A case-crossover analysis of forest fire haze events and mortality in Malaysia

    Science.gov (United States)

    Sahani, Mazrura; Zainon, Nurul Ashikin; Wan Mahiyuddin, Wan Rozita; Latif, Mohd Talib; Hod, Rozita; Khan, Md Firoz; Tahir, Norhayati Mohd; Chan, Chang-Chuan

    2014-10-01

    The Southeast Asian (SEA) haze events due to forest fires are recurrent and affect Malaysia, particularly the Klang Valley region. The aim of this study is to examine the risk of haze days due to biomass burning in Southeast Asia on daily mortality in the Klang Valley region between 2000 and 2007. We used a case-crossover study design to model the effect of haze based on PM10 concentration to the daily mortality. The time-stratified control sampling approach was used, adjusted for particulate matter (PM10) concentrations, time trends and meteorological influences. Based on time series analysis of PM10 and backward trajectory analysis, haze days were defined when daily PM10 concentration exceeded 100 μg/m3. The results showed a total of 88 haze days were identified in the Klang Valley region during the study period. A total of 126,822 cases of death were recorded for natural mortality where respiratory mortality represented 8.56% (N = 10,854). Haze events were found to be significantly associated with natural and respiratory mortality at various lags. For natural mortality, haze events at lagged 2 showed significant association with children less than 14 years old (Odd Ratio (OR) = 1.41; 95% Confidence Interval (CI) = 1.01-1.99). Respiratory mortality was significantly associated with haze events for all ages at lagged 0 (OR = 1.19; 95% CI = 1.02-1.40). Age-and-gender-specific analysis showed an incremental risk of respiratory mortality among all males and elderly males above 60 years old at lagged 0 (OR = 1.34; 95% CI = 1.09-1.64 and OR = 1.41; 95% CI = 1.09-1.84 respectively). Adult females aged 15-59 years old were found to be at highest risk of respiratory mortality at lagged 5 (OR = 1.66; 95% CI = 1.03-1.99). This study clearly indicates that exposure to haze events showed immediate and delayed effects on mortality.

  7. A Long-Term Prediction Model of Beijing Haze Episodes Using Time Series Analysis

    Science.gov (United States)

    Zhang, Zhongqiu; Sun, Liren; Xu, Cui

    2016-01-01

    The rapid industrial development has led to the intermittent outbreak of pm2.5 or haze in developing countries, which has brought about great environmental issues, especially in big cities such as Beijing and New Delhi. We investigated the factors and mechanisms of haze change and present a long-term prediction model of Beijing haze episodes using time series analysis. We construct a dynamic structural measurement model of daily haze increment and reduce the model to a vector autoregressive model. Typical case studies on 886 continuous days indicate that our model performs very well on next day's Air Quality Index (AQI) prediction, and in severely polluted cases (AQI ≥ 300) the accuracy rate of AQI prediction even reaches up to 87.8%. The experiment of one-week prediction shows that our model has excellent sensitivity when a sudden haze burst or dissipation happens, which results in good long-term stability on the accuracy of the next 3–7 days' AQI prediction. PMID:27597861

  8. A Long-Term Prediction Model of Beijing Haze Episodes Using Time Series Analysis.

    Science.gov (United States)

    Yang, Xiaoping; Zhang, Zhongxia; Zhang, Zhongqiu; Sun, Liren; Xu, Cui; Yu, Li

    2016-01-01

    The rapid industrial development has led to the intermittent outbreak of pm2.5 or haze in developing countries, which has brought about great environmental issues, especially in big cities such as Beijing and New Delhi. We investigated the factors and mechanisms of haze change and present a long-term prediction model of Beijing haze episodes using time series analysis. We construct a dynamic structural measurement model of daily haze increment and reduce the model to a vector autoregressive model. Typical case studies on 886 continuous days indicate that our model performs very well on next day's Air Quality Index (AQI) prediction, and in severely polluted cases (AQI ≥ 300) the accuracy rate of AQI prediction even reaches up to 87.8%. The experiment of one-week prediction shows that our model has excellent sensitivity when a sudden haze burst or dissipation happens, which results in good long-term stability on the accuracy of the next 3-7 days' AQI prediction. PMID:27597861

  9. A Long-Term Prediction Model of Beijing Haze Episodes Using Time Series Analysis.

    Science.gov (United States)

    Yang, Xiaoping; Zhang, Zhongxia; Zhang, Zhongqiu; Sun, Liren; Xu, Cui; Yu, Li

    2016-01-01

    The rapid industrial development has led to the intermittent outbreak of pm2.5 or haze in developing countries, which has brought about great environmental issues, especially in big cities such as Beijing and New Delhi. We investigated the factors and mechanisms of haze change and present a long-term prediction model of Beijing haze episodes using time series analysis. We construct a dynamic structural measurement model of daily haze increment and reduce the model to a vector autoregressive model. Typical case studies on 886 continuous days indicate that our model performs very well on next day's Air Quality Index (AQI) prediction, and in severely polluted cases (AQI ≥ 300) the accuracy rate of AQI prediction even reaches up to 87.8%. The experiment of one-week prediction shows that our model has excellent sensitivity when a sudden haze burst or dissipation happens, which results in good long-term stability on the accuracy of the next 3-7 days' AQI prediction.

  10. A Long-Term Prediction Model of Beijing Haze Episodes Using Time Series Analysis

    Directory of Open Access Journals (Sweden)

    Xiaoping Yang

    2016-01-01

    Full Text Available The rapid industrial development has led to the intermittent outbreak of pm2.5 or haze in developing countries, which has brought about great environmental issues, especially in big cities such as Beijing and New Delhi. We investigated the factors and mechanisms of haze change and present a long-term prediction model of Beijing haze episodes using time series analysis. We construct a dynamic structural measurement model of daily haze increment and reduce the model to a vector autoregressive model. Typical case studies on 886 continuous days indicate that our model performs very well on next day’s Air Quality Index (AQI prediction, and in severely polluted cases (AQI ≥ 300 the accuracy rate of AQI prediction even reaches up to 87.8%. The experiment of one-week prediction shows that our model has excellent sensitivity when a sudden haze burst or dissipation happens, which results in good long-term stability on the accuracy of the next 3–7 days’ AQI prediction.

  11. Vertical structure of foggy haze over the Beijing-Tianjin-Hebei area in January 2013

    Science.gov (United States)

    Han, Feng; Xu, Jun; He, Youjiang; Dang, Hongyan; Yang, Xuezhen; Meng, Fan

    2016-08-01

    In January 2013, frequent episodes of intense air pollution occurred in the Beijing-Tianjin-Hebei area (BTH), China. Besides the occurrence of region-wide dry haze pollution, foggy haze conditions also developed across the region on numerous days, lasting into the afternoon. Synergistic analysis, using multisatellite datasets, air sounding and surface meteorological observations, indicated that there was a vertical overlap of fog and aerosol layers during the foggy haze episodes in the region. Fog appeared at a low level of the atmosphere. The altitude of the upper boundary of the fog differed across the region, but it was always below 1 km. The aerosol layer that closely contacted with the top of the underlying fog was rather dense, having a high concentration comparable to that during severe pollution on the ground. Above the dense aerosol layer, aerosol with a concentration equivalent to that of moderate pollution stretched up to an altitude of 2 km. Beyond that, a tenuous aerosol layer extended 5 km into the atmosphere. This overlapping of fog and haze layers frequently occurred across the region in January 2013. The occurrence of a foggy haze over BTH could worsen the regional air quality, and its appearance across this region would have notable effects on the radiation balance.

  12. The Blue Emu

    Science.gov (United States)

    Descalzi, Doug; Gillett, John; Gordon, Carlton; Keener, ED; Novak, Ken; Puente, Laura

    1993-01-01

    The primary goal in designing the Blue Emu was to provide an airline with a cost efficient and profitable means of transporting passengers between the major cities in Aeroworld. The design attacks the market where a demand for inexpensive transportation exists and for this reason the Blue Emu is an attractive investment for any airline. In order to provide a profitable aircraft, special attention was paid to cost and economics. For example, in manufacturing, simplicity was stressed in structural design to reduce construction time and cost. Aerodynamic design employed a tapered wing which reduced the induced drag coefficient while also reducing the weight of the wing. Even the propulsion system was selected with cost effectiveness in mind, yet also to maintain the marketability of the aircraft. Thus, in every aspect of the design, consideration was given to economics and marketability of the final product.

  13. Synthesizing a Blue Ocean

    OpenAIRE

    Vester, Daniel

    2012-01-01

    The purpose of this Master thesis was to determine how electronic musical instrument companies could utilize innovation strategies to add value to their products and create new business markets beyond their core. The theoretical framework was established by outlining competitive strategies suitable for adoption by electronic musical instrument companies. The Blue Ocean Strategy was compared to traditional competitive strategies such as Porter’s Five Forces, and subsequently chosen because of ...

  14. Exploring the severe winter haze in Beijing: the impact of synoptic weather, regional transport and heterogeneous reactions

    Science.gov (United States)

    Zheng, Guangjie; Su, Hang; zhang, qiang; cheng, yafang; he, kebin

    2016-04-01

    Extreme haze episodes repeatedly shrouded Beijing during the winter of 2012-2013, causing major environmental and health problems. To better understand these extreme events, we performed a model-assisted analysis of the hourly observation data of PM2.5 and its major chemical compositions. The synthetic analysis shows that, (1) the severe winter haze was driven by stable synoptic meteorological conditions over northeastern China, and not by an abrupt increase in anthropogenic emissions. (2) Secondary species, including organics, sulfate, nitrate, and ammonium, were the major constituents of PM2.5 during this period. (3) Due to the dimming effect of high loading of aerosol particles, gaseous oxidant concentrations decreased significantly, suggesting a reduced production of secondary aerosols through gas phase reactions. Surprisingly, the observational data reveals an enhanced production rate of secondary aerosols, suggesting an important contribution from other formation pathways, most likely heterogeneous reactions. These reactions appeared to be more efficient in producing secondary inorganics aerosols than organic aerosols resulting in a strongly elevated fraction of inorganics during heavily polluted periods. (4) Moreover, we found that high aerosol concentration was a regional phenomenon. The accumulation process of aerosol particles occurred successively from southeast cities to Beijing. The apparent sharp increase in PM2.5 concentration of up to several hundred μg m-3 per hour recorded in Beijing represented rapid recovery from an interruption to the continuous pollution accumulation over the region, rather than purely local chemical production. This suggests that regional transport of pollutants played an important role during these severe pollution events.

  15. Simulations of sulfate-nitrate-ammonium (SNA) aerosols during the extreme haze events over northern China in October 2014

    Science.gov (United States)

    Chen, Dan; Liu, Zhiquan; Fast, Jerome; Ban, Junmei

    2016-08-01

    Extreme haze events have occurred frequently over China in recent years. Although many studies have investigated the formation mechanisms associated with PM2.5 for heavily polluted regions in China based on observational data, adequately predicting peak PM2.5 concentrations is still challenging for regional air quality models. In this study, we evaluate the performance of one configuration of the Weather Research and Forecasting model coupled with chemistry (WRF-Chem) and use the model to investigate the sensitivity of heterogeneous reactions on simulated peak sulfate, nitrate, and ammonium concentrations in the vicinity of Beijing during four extreme haze episodes in October 2014 over the North China Plain. The highest observed PM2.5 concentration of 469 µg m-3 occurred in Beijing. Comparisons with observations show that the model reproduced the temporal variability in PM2.5 with the highest PM2.5 values on polluted days (defined as days in which observed PM2.5 is greater than 75 µg m-3), but predictions of sulfate, nitrate, and ammonium were too low on days with the highest observed concentrations. Observational data indicate that the sulfur/nitric oxidation rates are strongly correlated with relative humidity during periods of peak PM2.5; however, the model failed to reproduce the highest PM2.5 concentrations due to missing heterogeneous/aqueous reactions. As the parameterizations of those heterogeneous reactions are not well established yet, estimates of SO2-to-H2SO4 and NO2/NO3-to-HNO3 reaction rates that depend on relative humidity were applied, which improved the simulation of sulfate, nitrate, and ammonium enhancement on polluted days in terms of both concentrations and partitioning among those species. Sensitivity simulations showed that the extremely high heterogeneous reaction rates and also higher emission rates than those reported in the emission inventory were likely important factors contributing to those peak PM2.5 concentrations.

  16. Simulations of Sulfate-Nitrate-Ammonium (SNA) aerosols during the extreme haze events over Northern China in 2014

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Dan; Liu, Zhiquan; Fast, Jerome D.; Ban, Junmei

    2016-08-30

    Extreme haze events have occurred frequently over China in recent years. Although many studies have investigated the formation mechanisms associated with PM2.5 for heavily polluted regions in China based on observational data, adequately predicting peak PM2.5 concentrations is still challenging for regional air quality models. In this study, we evaluate the performance of one configuration of the Weather Research and Forecasting model coupled with chemistry (WRF-Chem) and use the model to investigate the sensitivity of heterogeneous reactions on simulated peak sulfate, nitrate, and ammonium concentrations in the vicinity of Beijing during four extreme haze episodes in October 2014 over the North China Plain. The highest observed PM2.5 concentration of 469 μg m-3 occurred in Beijing. Comparisons with observations show that the model reproduced the temporal variability in PM2.5 with the highest PM2.5 values on polluted days (defined as days in which observed PM2.5 is greater than 75 μg m-3), but predictions of sulfate, nitrate, and ammonium were too low on days with the highest observed concentrations. Observational data indicate that the sulfur/nitric oxidation rates are strongly correlated with relative humidity during periods of peak PM2.5; however, the model failed to reproduce the highest PM2.5 concentrations due to missing heterogeneous reactions. As the parameterizations of those reactions is not well established yet, estimates of SO2-to-H2SO4 and NO2/NO3-to-HNO3 reaction rates that depend on relative humidity were applied which improved the simulation of sulfate, nitrate, and ammonium enhancement on polluted days in terms of both concentrations and partitioning among those species. Sensitivity simulations showed that the extremely high heterogeneous reaction rates and also higher emission rates than those reported in the emission inventory

  17. Analytical solution for haze values of aluminium-induced texture (AIT) glass superstrates for a-Si:H solar cells.

    Science.gov (United States)

    Sahraei, Nasim; Forberich, Karen; Venkataraj, Selvaraj; Aberle, Armin G; Peters, Marius

    2014-01-13

    Light scattering at randomly textured interfaces is essential to improve the absorption of thin-film silicon solar cells. Aluminium-induced texture (AIT) glass provides suitable scattering for amorphous silicon (a-Si:H) solar cells. The scattering properties of textured surfaces are usually characterised by two properties: the angularly resolved intensity distribution and the haze. However, we find that the commonly used haze equations cannot accurately describe the experimentally observed spectral dependence of the haze of AIT glass. This is particularly the case for surface morphologies with a large rms roughness and small lateral feature sizes. In this paper we present an improved method for haze calculation, based on the power spectral density (PSD) function of the randomly textured surface. To better reproduce the measured haze characteristics, we suggest two improvements: i) inclusion of the average lateral feature size of the textured surface into the haze calculation, and ii) considering the opening angle of the haze measurement. We show that with these two improvements an accurate prediction of the haze of AIT glass is possible. Furthermore, we use the new equation to define optimum morphology parameters for AIT glass to be used for a-Si:H solar cell applications. The autocorrelation length is identified as the critical parameter. For the investigated a-Si:H solar cells, the optimum autocorrelation length is shown to be 320 nm. PMID:24922000

  18. The effects of dust–haze on mortality are modified by seasons and individual characteristics in Guangzhou, China

    International Nuclear Information System (INIS)

    This study aimed to investigate the effects of dust–haze on mortality and to estimate the seasonal and individual-specific modification effects in Guangzhou, China. Mortality, air pollution and meteorological data were collected for 2006–2011. A dust–haze day was defined as daily visibility 10. We concluded that dust–haze significantly increased mortality risk in Guangzhou, China, and this effect appears to be dominated by particulate mass and modified by season and individual-specific factors. - Highlights: • We assessed the health impact of dust–haze in a megacity of southern China. • A dust–haze was defined according to visibility and relative humidity. • Dust–haze increased mortality risk, which may be dominated by particulate mass. • The dust–haze effects were modified by season and individual-specific factors. - This study extends our understanding of the health impact of dust–haze in southern China, and provides local evidence for health to advocate for improved air emissions control and strategies to reduce population exposure

  19. Chemical characteristics and source apportionment of PM10 during a brown haze episode in Harbin,China

    Institute of Scientific and Technical Information of China (English)

    Likun Huang; Chung-Shin Yuan; Guangzhi Wang; Kun Wang

    2011-01-01

    This study investigates the correlation between PM10 and meteorological factors such as wind speed,atmospheric visibility,dew point,relative humidity,and ambient temperature during a brown haze episode. In order to identify the potential sources of PM10 during brown haze episode,respirable particulate matter (PM10) was collected during both non-haze days and haze days and further analyzed for metallic elements,ionic species,and carbonaceous contents. Among them,ionic species contributed 45-64% to PM10,while metallic elements contributed 7-21% to PM10 which was smaller than the other chemical constituents. The average OC/EC ratio (42) in haze days was about three times of the average OC/EC ratio (14) in non-haze days. By using chemical mass balance (CMB) receptor model,the major sources were apportioned,including traffics,incinerators,coal combustion,steel industry,petrochemical industry,and secondary aerosols,etc. The contribution to PM10 concentration of each source was calculated for all the samples collected. The results showed that coal combustion was the major source of PM10 in non-haze days and secondary aerosols were the major source in haze days,followed by petrochemical industry,incinerators,and traffics,while other sources had negligible effect.

  20. Suppression of local haze variations in MERIS images over turbid coastal waters for retrieval of suspended sediment concentration

    NARCIS (Netherlands)

    Shen, F.; Verhoef, W.

    2010-01-01

    Atmospheric correction over turbid waters can be problematic if atmospheric haze is spatially variable. In this case the retrieval of water quality is hampered by the fact that haze variations could be partly mistaken for variations in suspended sediment concentration (SSC). In this study we propose

  1. ANALYSIS OF WMAP 7 YEAR TEMPERATURE DATA: ASTROPHYSICS OF THE GALACTIC HAZE

    Energy Technology Data Exchange (ETDEWEB)

    Pietrobon, Davide; Gorski, Krzysztof M.; Bartlett, James; Colombo, Loris P. L.; Jewell, Jeffrey B.; Pagano, Luca; Rocha, Graca; Lawrence, Charles R. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109-8099 (United States); Banday, A. J. [Universie de Toulouse, UPS-OMP, IRAP, Toulouse (France); Dobler, Gregory [Kavli Institute for Theoretical Physics, University of California, Santa Barbara Kohn Hall, Santa Barbara, CA 93106 (United States); Hildebrandt, Sergi R. [Division of Physics, Mathematics and Astronomy, California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125 (United States); Eriksen, Hans Kristian [Institute of Theoretical Astrophysics, University of Oslo, P.O. Box 1029, Blindern, N-0315 Oslo (Norway); Saha, Rajib, E-mail: davide.pietrobon@jpl.nasa.gov [Physics Department, Indian Institute of Science Education and Research Bhopal, Bhopal, MP 462023 (India)

    2012-08-10

    We perform a joint analysis of the cosmic microwave background (CMB) and Galactic emission from the WMAP 7 year temperature data. Using the Commander code, based on Gibbs sampling, we simultaneously derive the CMB and Galactic components on scales larger than 1 Degree-Sign with improved sensitivity over previous work. We conduct a detailed study of the low-frequency Galactic foreground, focusing on the 'microwave haze' emission around the Galactic center. We demonstrate improved performance in quantifying the diffuse Galactic emission when including Haslam 408 MHz data and when jointly modeling the spinning and thermal dust emission. We examine whether the hypothetical Galactic haze can be explained by a spatial variation of the synchrotron spectral index, and find that the excess of emission around the Galactic center is stable with respect to variations of the foreground model. Our results demonstrate that the new Galactic foreground component-the microwave haze-is indeed present.

  2. What Causes Haze Pollution? An Empirical Study of PM2.5 Concentrations in Chinese Cities

    Directory of Open Access Journals (Sweden)

    Jiannan Wu

    2016-01-01

    Full Text Available In recent years, many areas of China have suffered from serious haze pollution, which greatly affects human health and daily life. It is of policy importance to understand the factors that influence the spatial concentration of PM2.5. Based on data from 74 cities with PM2.5 monitoring stations in 2013 and 2014, this study presents the overall haze situation in China and explores the determinants of PM2.5 using a random-effects model, as well as a set of OLS regressions. The results indicate that PM2.5 is significantly correlated with the industrial proportion, the number of motor vehicles, and household gas consumption, while public financial expenditure on energy saving and environmental protection does not show statistically significant effects. The analysis implies that China should adjust its economic structure and optimizes environmental governance to effectively respond to haze pollution.

  3. Predicting Intention to Take Protective Measures During Haze: The Roles of Efficacy, Threat, Media Trust, and Affective Attitude.

    Science.gov (United States)

    Lin, Trisha T C; Bautista, John Robert

    2016-07-01

    The annual Southeast Asian haze pollution raises public health concerns in this region. Based on a modified extended parallel process model, this study examines efficacy (self-efficacy and response efficacy) and perceived threat (susceptibility and severity) and incorporates new constructs of media trust and affective attitude. Results from a Web survey of 410 undergraduate students in Singapore show that response efficacy to seek haze-related information mediates the association between perceived self-efficacy and intention to take protective measures during haze. Moreover, self-efficacy is negatively associated with affective attitude (e.g., fear and worry) toward haze-related health problems. Next, perceived severity and perceived susceptibility are positively associated with response efficacy and affective attitude. Affective attitude toward haze is a stronger predictor than response efficacy for behavioral intention. Finally, trust in new media is positively associated with young Singaporeans' affective attitude, which positively affects their behavioral intention to take protective measures. PMID:27315440

  4. Predicting Intention to Take Protective Measures During Haze: The Roles of Efficacy, Threat, Media Trust, and Affective Attitude.

    Science.gov (United States)

    Lin, Trisha T C; Bautista, John Robert

    2016-07-01

    The annual Southeast Asian haze pollution raises public health concerns in this region. Based on a modified extended parallel process model, this study examines efficacy (self-efficacy and response efficacy) and perceived threat (susceptibility and severity) and incorporates new constructs of media trust and affective attitude. Results from a Web survey of 410 undergraduate students in Singapore show that response efficacy to seek haze-related information mediates the association between perceived self-efficacy and intention to take protective measures during haze. Moreover, self-efficacy is negatively associated with affective attitude (e.g., fear and worry) toward haze-related health problems. Next, perceived severity and perceived susceptibility are positively associated with response efficacy and affective attitude. Affective attitude toward haze is a stronger predictor than response efficacy for behavioral intention. Finally, trust in new media is positively associated with young Singaporeans' affective attitude, which positively affects their behavioral intention to take protective measures.

  5. The effects of dust-haze on mortality are modified by seasons and individual characteristics in Guangzhou, China.

    Science.gov (United States)

    Liu, Tao; Zhang, Yong Hui; Xu, Yan Jun; Lin, Hua Liang; Xu, Xiao Jun; Luo, Yuan; Xiao, Jianpeng; Zeng, Wei Lin; Zhang, Wan Fang; Chu, Cordia; Keogh, Kandice; Rutherford, Shannon; Qian, Zhengmin; Du, Yao Dong; Hu, Mengjue; Ma, Wen Jun

    2014-04-01

    This study aimed to investigate the effects of dust-haze on mortality and to estimate the seasonal and individual-specific modification effects in Guangzhou, China. Mortality, air pollution and meteorological data were collected for 2006-2011. A dust-haze day was defined as daily visibility haze (haze days were associated with increased mortality of 3.4%, 6.8% and 10.4% respectively, at a lag of 0-6 days. This effect was more pronounced during the cold season, for cardiovascular mortality (CVD), respiratory mortality (RESP), in males and people ≥60years. These effects became insignificant after adjustment for PM10. We concluded that dust-haze significantly increased mortality risk in Guangzhou, China, and this effect appears to be dominated by particulate mass and modified by season and individual-specific factors.

  6. Assessing the Performance of the Photovoltaic Cells on the Effects of Yellow Dust Events and Haze in Seoul, Korea

    Science.gov (United States)

    Choi, Jiyeon; Kim, Yong Pyo; Wee, DaeHyun

    2016-04-01

    We analyze the potential effects of the Asian yellow dust Events and haze on the performance of Korean photovoltaic systems. Particulate matters from the Asian yellow dust outbreaks in the deserts of Mongolia and northern China are typically transported to Korea. Haze is an atmospheric phenomenon where dust, smoke and other dry particles obscure the clarity of the sky. Hence, we conjecture that the effects of the Asian yellow dust and haze block the incident solar irradiance. The potential reduction of the solar spectral irradiance due to Asian yellow dust events and haze in Korea is investigated using a clear-sky spectral radiation model, and the performance of photovoltaic systems under reduced irradiance is estimated by using a simple analytic model representing typical photovoltaic cells. Comparison of photovoltaic performance under Asian dust events, haze and that under a clear condition is made to evaluate overall influence of the particulate air pollution, respectively.

  7. The Composition of Organic Aerosols in Southeast Asia During The 2006 Haze Episode

    Science.gov (United States)

    Jun, H.; Zielinska, B.; Balasubramanian, R.

    2007-12-01

    The regional smoke haze in Southeast Asia is a recurring air pollution problem. Uncontrolled forest fires from land-clearing activities in Sumatra and Borneo, and to a lesser extent Malaysia, have occurred almost every dry season since the late 1990s. The smoke haze that took place in October 2006 shrouded an estimated 215,000 square miles of land on Indonesia's islands of Sumatra and Borneo, and persisted for several weeks. Satellite pictures showed numerous hotspots in both Sumatra and Kalimantan. The prevailing, South-Southwesterly, winds blew smoke from land and forest fires in central and south Sumatra to Singapore, affecting the regional air quality significantly and reducing atmospheric visibility. During this haze episode, we carried out an intensive field study in Singapore to characterize the composition of organic aerosols, which usually account for a large fraction of airborne particulate matter (PM). A total of 17 PM samples were collected while the hazy atmospheric conditions persisted in Singapore, and subjected to accelerated solvent extraction with dichloromethane and acetone. The extracted compounds were grouped into three major fractions (n-alkanes, polycyclic aromatic hydrocarbons, and polar organic compounds). More than 180 particulate-bound organic compounds were determined using gas chromatography/mass spectrometry (GC-MS). In order to investigate the origin of organic species, the carbon preference indexes as well as diagnostic ratios were used. The compositional differences of organic aerosols between the haze- and non- haze periods will be presented. The atmospheric implications of the composition of organic aerosols of biomass burning origin will be discussed. Keywords: smoke haze, organic aerosols, n-alkanes, polycyclic aromatic hydrocarbons, polar organic compounds

  8. Severe haze episodes and seriously polluted fog water in Ji'nan, China.

    Science.gov (United States)

    Wang, Xinfeng; Chen, Jianmin; Sun, Jianfeng; Li, Weijun; Yang, Lingxiao; Wen, Liang; Wang, Wenxing; Wang, Xinming; Collett, Jeffrey L; Shi, Yang; Zhang, Qingzhu; Hu, Jingtian; Yao, Lan; Zhu, Yanhong; Sui, Xiao; Sun, Xiaomin; Mellouki, Abdelwahid

    2014-09-15

    Haze episodes often hit urban cities in China recently. Here, we present several continuous haze episodes with extremely high PM2.5 levels that occurred over several weeks in early 2013 and extended across most parts of the northern and eastern China-far exceeding the Beijing-Tianjin-Hebei region. Particularly, the haze episode covered ~1 million km(2) on January 14, 2013 and the daily averaged PM2.5 concentration exceeded 360 μg m(-3) in Ji'nan. The observed maximum hourly PM2.5 concentration in urban Ji'nan reached 701 μg m(-3) at 7:00 am (local time) in January 30. During these haze episodes, several fog events happened and the concurrent fog water was found to be seriously polluted. For the fog water collected in Ji'nan from 10:00 pm in January 14 to 11:00 am in January 15, sulfate, nitrate, and ammonium were the major ions with concentrations of 1.54 × 10(6), 8.98 × 10(5), and 1.75 × 10(6) μeq L(-1), respectively, leading to a low in-situ pH of 3.30. The sulfate content in the fog sample was more than 544 times as high as those observed in other areas. With examination of the simultaneously observed data on PM2.5 and its chemical composition, the fog played a role in scavenging and removing fine particles from the atmosphere during haze episodes and thus was seriously contaminated. However, the effect was not sufficient to obviously cleanse air pollution and block haze episodes.

  9. Blue nano titania made in diffusion flames.

    Science.gov (United States)

    Teleki, Alexandra; Pratsinis, Sotiris E

    2009-05-21

    Blue titanium suboxide nanoparticles (including Magneli phases) were formed directly without any post-processing or addition of dopants by combustion of titanium-tetra-isopropoxide (TTIP) vapor at atmospheric pressure. Particle size, phase composition, rutile and anatase crystal sizes as well as the blue coloration were controlled by rapid quenching of the flame with a critical flow nozzle placed at various heights above the burner. The particles showed a broad absorption in the near-infrared region and retained their blue color upon storage in ambient atmosphere. A high concentration of paramagnetic Ti3+ centres was found in the substoichiometric particles by electron paramagnetic resonance (EPR) spectroscopy. Furthermore particles with controlled band gap energy from 3.2 to 3.6 eV were made by controlling the burner-nozzle-distance from 10 to 1 cm, respectively. The color robustness and extent of suboxidation could be further enhanced by co-oxidation of TTIP with hexamethyldisiloxane in the flame resulting in SiO2-coated titanium suboxide particles. The process is cost-effective and green while the particles produced can replace traditional blue colored, cobalt-containing pigments. PMID:19421486

  10. [Comparative analysis on meteorological condition for persistent haze cases in summer and winter in Beijing].

    Science.gov (United States)

    Liao, Xiao-Nong; Zhang, Xiao-Ling; Wang, Ying-Chun; Liu, Wei-Dong; Du, Jia; Zhao, Ling-Hui

    2014-06-01

    Summer is another peak season for haze besides winter in Beijing area, which is different from that in South China. The data of microwave radiometer, profiler, sounding, AWS, NCEP (NCAR) and air pollution monitors were used in the analysis of two haze cases which occurred in winter and summer, respectively. Both cases lasted for 6 days. This research focused on the difference in the mechanism of the formation and persistence of haze cases in various seasons. In winter, north-westerly flow dominated Beijing at upper-levels and a few of shallow troughs passed by during persistent haze development. The main meteorological reasons for lower visibility in 6 days were: there was an inversion in the boundary layer all the time; wind was weak at surface and moisture went up gradually. The change of inversion height and humidity day and night led to the diurnal variation of PM2.5 concentration and visibility. The surface wind speed kept lower because the weak cold air could not often hit the surface during the haze case. In addition, three factors played key roles in the inversion formation in boundary layer. One was that the rapid decrease in the surface temperature after sunset due to the radiation. At the same time, there was some warm advection at upper boundary layer. The third one attributed to the temperature increase after the air flowing over the mountains and down. However, in summer, regional transportation of aerosol, sustained convective stability and high air saturation were very important factors for the haze formation. Under the sub-tropic high control, the wind direction at lower troposphere was south. The PM2.5 concentration went up when the speed of south wind increased. The south flow caused by both synoptic scale systems and mountain-valley breeze near Beijing transported the aerosol northward from higher polluted area. There was no inversion in the summer haze case. But, the convective inhibition was kept over 200 J x kG(-1). As the result, it was not

  11. Estruturas fundamentais no blues

    OpenAIRE

    Silva, Rafael Palmeira da

    2012-01-01

    Resumo: Esta pesquisa tem como objeto de estudo a aplicação e adaptação da teoria de Schenker como ferramenta analítica aplicada ao jazz, tendo em vista a possibilidade de encontrar estruturas fundamentais distintas na música popular. Tendo como base as análises feitas por Larson (1998; 2009), Forte (2011) e Stock (1993) a pesquisa abordará, em um primeiro momento, as origens do jazz (blues e ragtime) como parte essencial para sua abordagem analítica, através da ótica etno-schenkeriana propos...

  12. Identification of chemical compositions and sources of atmospheric aerosols in Xi'an, inland China during two types of haze events.

    Science.gov (United States)

    Li, Jianjun; Wang, Gehui; Ren, Yanqin; Wang, Jiayuan; Wu, Can; Han, Yanni; Zhang, Lu; Cheng, Chunlei; Meng, Jingjing

    2016-10-01

    High time resolution (1h) of TSP filter samples was collected in Xi'an in inland China from December 5 to 13, 2012, during which a 9-day long of haze episode occurred. The hazy days were classified as two types, i.e., Light-haze period with moderate degradation in visibility (5-10km) and relatively dry conditions (RH: 53±19%) and Severe-haze period with a daily visibility less than 5km and humid conditions (RH: 73±14%). TSP in the two periods (415±205 and 530±180μgm(-3) in Light-haze and Severe-haze periods, respectively) was comparable, but crustal Fe and Ca elements presented higher concentrations and strong correlation (R(2)=0.72) with TSP in Light-haze period. SO4(2-), NO3(-) and NH4(+) in Light-haze period were 16±5.9, 12±6.7 and 4.1±2.8μgm(-3), respectively, and increased dramatically to 51±15, 44±9.7 and 23±5.6μgm(-3) in Severe-haze period. Contributions of Fe and Ca to TSP decreased from 9.2% in Light-haze period to 5.3% in Severe-haze period, but those of SO4(2-), NO3(-) and NH4(+) increased from 3.8%, 2.9% and 1.0% in Light-haze period to 9.6%, 8.3% and 4.4% in Severe-haze period, respectively. These results suggest that dust-derived particles were more significant in Light-haze period while secondary aerosols were more important in Severe-haze period. Hopanes (33±24 and 38±29ngm(-3) in Light-haze and Severe-haze periods, respectively) during the two types of haze periods are comparable, indicating that differences in contribution of primary organic aerosols from fossil fuel combustions to TSP were insignificant. In contrast, the ratio of secondary organic aerosols (e.g., o-phthalic acid) to EC was much higher in Severe-haze period (5.8±2.7ngμg(-1)) than in Light-haze period (3.4±2.1ngμg(-1)), probably indicating that the humid conditions in Severe-haze period are favorable for secondary organic aerosol formation. PMID:27220100

  13. Identification of chemical compositions and sources of atmospheric aerosols in Xi'an, inland China during two types of haze events.

    Science.gov (United States)

    Li, Jianjun; Wang, Gehui; Ren, Yanqin; Wang, Jiayuan; Wu, Can; Han, Yanni; Zhang, Lu; Cheng, Chunlei; Meng, Jingjing

    2016-10-01

    High time resolution (1h) of TSP filter samples was collected in Xi'an in inland China from December 5 to 13, 2012, during which a 9-day long of haze episode occurred. The hazy days were classified as two types, i.e., Light-haze period with moderate degradation in visibility (5-10km) and relatively dry conditions (RH: 53±19%) and Severe-haze period with a daily visibility less than 5km and humid conditions (RH: 73±14%). TSP in the two periods (415±205 and 530±180μgm(-3) in Light-haze and Severe-haze periods, respectively) was comparable, but crustal Fe and Ca elements presented higher concentrations and strong correlation (R(2)=0.72) with TSP in Light-haze period. SO4(2-), NO3(-) and NH4(+) in Light-haze period were 16±5.9, 12±6.7 and 4.1±2.8μgm(-3), respectively, and increased dramatically to 51±15, 44±9.7 and 23±5.6μgm(-3) in Severe-haze period. Contributions of Fe and Ca to TSP decreased from 9.2% in Light-haze period to 5.3% in Severe-haze period, but those of SO4(2-), NO3(-) and NH4(+) increased from 3.8%, 2.9% and 1.0% in Light-haze period to 9.6%, 8.3% and 4.4% in Severe-haze period, respectively. These results suggest that dust-derived particles were more significant in Light-haze period while secondary aerosols were more important in Severe-haze period. Hopanes (33±24 and 38±29ngm(-3) in Light-haze and Severe-haze periods, respectively) during the two types of haze periods are comparable, indicating that differences in contribution of primary organic aerosols from fossil fuel combustions to TSP were insignificant. In contrast, the ratio of secondary organic aerosols (e.g., o-phthalic acid) to EC was much higher in Severe-haze period (5.8±2.7ngμg(-1)) than in Light-haze period (3.4±2.1ngμg(-1)), probably indicating that the humid conditions in Severe-haze period are favorable for secondary organic aerosol formation.

  14. Blue ocean leadership.

    Science.gov (United States)

    Kim, W Chan; Mauborgne, Renée

    2014-05-01

    Ten years ago, two INSEAD professors broke ground by introducing "blue ocean strategy," a new model for discovering uncontested markets that are ripe for growth. In this article, they apply their concepts and tools to what is perhaps the greatest challenge of leadership: closing the gulf between the potential and the realized talent and energy of employees. Research indicates that this gulf is vast: According to Gallup, 70% of workers are disengaged from their jobs. If companies could find a way to convert them into engaged employees, the results could be transformative. The trouble is, managers lack a clear understanding of what changes they could make to bring out the best in everyone. Here, Kim and Mauborgne offer a solution to that problem: a systematic approach to uncovering, at each level of the organization, which leadership acts and activities will inspire employees to give their all, and a process for getting managers throughout the company to start doing them. Blue ocean leadership works because the managers' "customers"-that is, the people managers oversee and report to-are involved in identifying what's effective and what isn't. Moreover, the approach doesn't require leaders to alter who they are, just to undertake a different set of tasks. And that kind of change is much easier to implement and track than changes to values and mind-sets. PMID:24956870

  15. Blue ocean leadership.

    Science.gov (United States)

    Kim, W Chan; Mauborgne, Renée

    2014-05-01

    Ten years ago, two INSEAD professors broke ground by introducing "blue ocean strategy," a new model for discovering uncontested markets that are ripe for growth. In this article, they apply their concepts and tools to what is perhaps the greatest challenge of leadership: closing the gulf between the potential and the realized talent and energy of employees. Research indicates that this gulf is vast: According to Gallup, 70% of workers are disengaged from their jobs. If companies could find a way to convert them into engaged employees, the results could be transformative. The trouble is, managers lack a clear understanding of what changes they could make to bring out the best in everyone. Here, Kim and Mauborgne offer a solution to that problem: a systematic approach to uncovering, at each level of the organization, which leadership acts and activities will inspire employees to give their all, and a process for getting managers throughout the company to start doing them. Blue ocean leadership works because the managers' "customers"-that is, the people managers oversee and report to-are involved in identifying what's effective and what isn't. Moreover, the approach doesn't require leaders to alter who they are, just to undertake a different set of tasks. And that kind of change is much easier to implement and track than changes to values and mind-sets.

  16. Blue emitting undecaplatinum clusters

    Science.gov (United States)

    Chakraborty, Indranath; Bhuin, Radha Gobinda; Bhat, Shridevi; Pradeep, T.

    2014-07-01

    A blue luminescent 11-atom platinum cluster showing step-like optical features and the absence of plasmon absorption was synthesized. The cluster was purified using high performance liquid chromatography (HPLC). Electrospray ionization (ESI) and matrix assisted laser desorption ionization (MALDI) mass spectrometry (MS) suggest a composition, Pt11(BBS)8, which was confirmed by a range of other experimental tools. The cluster is highly stable and compatible with many organic solvents.A blue luminescent 11-atom platinum cluster showing step-like optical features and the absence of plasmon absorption was synthesized. The cluster was purified using high performance liquid chromatography (HPLC). Electrospray ionization (ESI) and matrix assisted laser desorption ionization (MALDI) mass spectrometry (MS) suggest a composition, Pt11(BBS)8, which was confirmed by a range of other experimental tools. The cluster is highly stable and compatible with many organic solvents. Electronic supplementary information (ESI) available: Details of experimental procedures, instrumentation, chromatogram of the crude cluster; SEM/EDAX, DLS, PXRD, TEM, FT-IR, and XPS of the isolated Pt11 cluster; UV/Vis, MALDI MS and SEM/EDAX of isolated 2 and 3; and 195Pt NMR of the K2PtCl6 standard. See DOI: 10.1039/c4nr02778g

  17. REMOTE SENSING MEASUREMENTS OF AEROSOL OPTICAL THICKNESS AND CORRELATION WITH IN-SITU AIR QUALITY PARAMETERS DURING A SMOKE HAZE EPISODE IN SOUTHEAST ASIA

    Science.gov (United States)

    Chew, B.; Salinas Cortijo, S. V.; Liew, S.

    2009-12-01

    Transboundary smoke haze due to biomass burning is a major environmental problem in Southeast Asia which has not only affected air quality in the source region, but also in the surrounding countries. Air quality monitoring stations and meteorological stations can provide valuable information on the concentrations of criteria pollutants such as sulphur dioxide, nitrogen oxide, carbon monoxide, ozone and particulate mass (PM10) as well as health advisory to the general public during the haze episodes. Characteristics of aerosol particles in the smoke haze such as the aerosol optical thickness (AOT), aerosol size distribution and Angstrom exponent are also measured or retrieved by sun-tracking photometers, such as those deployed in the world-wide AErosol RObotic NETwork (AERONET). However, due to the limited spatial coverage by the air quality monitoring stations and AERONET sites, it is difficult to study and monitor the spatial and temporal variability of the smoke haze during a biomass burning episode, especially in areas without ground-based instrumentation. As such, we combine the standard in-situ measurements of PM10 by air quality monitoring stations with the remote sensing imagery from the Moderate Resolution Imaging Spectroradiometer (MODIS) on board NASA's Terra and Aqua satellites. The columnar AOT is first derived from the MODIS images for regions where PM10 measurements are available. Empirical correlations between AOT and PM10 measurements are then established for 50 sites in both Malaysia and Singapore during the smoke haze episode in 2006. When available, vertical feature information from the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) is used to examine the validity of the correlations. Aloft transport of aerosols, which can weaken the correlations between AOT and PM10 measurements, is also identified by CALIPSO and taken into consideration for the analysis. With this integrated approach, we hope to enhance and

  18. 引导滤波在雾天图像清晰化中的应用%Application of Guided Filter to Haze Image Sharpening

    Institute of Scientific and Technical Information of China (English)

    王伟鹏; 戴声奎

    2015-01-01

    According to the physical model of atmospheric scattering,this paper analyses and addresses major problems for single image haze removal to eliminate the effects of fog or haze for outdoor machine vision system.The experimental results show that the proposed method overcomes the limits of halo artifacts and over-saturation through estimating the atmospheric veil using the local smoothing characteristics of guided filter.By computing the average values of the most dense haze to obtain the global atmospheric light intensity,this algorithm could adjust the color cast of the image.Final-ly,a post-processing procedure is adopted to enhance the visual effect of the recovered image.As compared with typical haze removal algorithms,the proposed method achieves good restoration for contrast and color fidelity more effectively and allows a very fast implementation to achieve real-time.%根据大气散射物理模型,分析并解决单幅图像去雾的关键问题,以消除雾气对室外机器视觉系统的影响。实验结果表明:利用引导滤波器的局部平滑特性估计大气光幕,可有效克服光晕效应和颜色过饱和现象;通过计算雾气最浓区域的平均值获取大气光强度值,可解决部分图像偏色问题;对复原的图像进行自适应增强处理,提高了图像的整体视觉效果。通过与多种典型的图像去雾算法的比较,说明该方法能更有效地消除图像中的雾气、真实复原场景的对比度和颜色,同时具有很快的执行速度,有利于算法的实时实现。

  19. Postpartum Blues and Postpartum Depression

    Directory of Open Access Journals (Sweden)

    Erdem Ö et al.

    2009-09-01

    Full Text Available Postpartum blues which is seen during the postpartum period is a transient psychological state. Most of the mothers experience maternity blues in postpartum period. It remains usually unrecognized by the others. Some sensitive families can misattribute these feelings as depression. In this article, we tried to review the characteristics of maternity blues and its differences from depression. We defined depression and presented the incidence and diagnostic criteria, of major depression as well as the risk factors and clinic findings of postpartum depression. Thus, especially at primary care we aimed to prevent misdiagnosis of both maternity blues and depression

  20. Progress towards a post-Venus Express Clouds & Haze reference model for Venus

    Science.gov (United States)

    Marcq, Emmanuel; Belyaev, Denis; Wilson, Colin; Wilquet, Valérie; Luginin, Mikhail

    2016-07-01

    With the end of Venus Express in 2014, the focus of the scientific community has gradually moved from the study of Venus Express mono-instrumental data sets to cross-instrumental studies involving pure modelization as well. This is especially true for the clouds and hazes that surround most of the planet between 48 and 70 km. They play a major role at the crossroads of various atmospheric processes among which the radiative budget as well as the dynamical and chemical coupling between the lower and upper atmosphere. In order to support such efforts, ISSI has supported from 2013 to 2015 a "Clouds & Hazes of Venus" scientific team involving Venus Express and ground-based observers as well as microphysical modelers. Together, they compared their results in order to achieve a more unified and consistent view of Venus' clouds and hazes, taking into account its spatial and temporal variability more in detail than previously available VIRA-1 and 2 cloud models. We will review the individual data sets and models that have been used, and then present our strategy towards a unified cloud model. We will first make available some observable parameters to the wider community through a web-based repository. Our future steps will involve more advanced techniques (data assimilation) in order to achieve our objective of a unified Venus clouds & haze model that encompasses its various variabilities as well as possible.

  1. 78 FR 16452 - Approval and Promulgation of Implementation Plans; North Dakota; Regional Haze State...

    Science.gov (United States)

    2013-03-15

    ... discussion of regional haze requirements, please see our proposal at 76 FR 58574, 58576. In our proposed action, we proposed to disapprove the State's NO X BART determinations for these units. See 76 FR 58570... BART determinations for these units. 77 FR 20894, 20897 (April 6, 2012). We based our change on...

  2. Modeling study of the 2010 regional haze event in the North China Plain

    Science.gov (United States)

    Gao, M.; Carmichael, G. R.; Wang, Y.; Saide, P. E.; Yu, M.; Xin, J.; Liu, Z.; Wang, Z.

    2016-02-01

    The online coupled Weather Research and Forecasting-Chemistry (WRF-Chem) model was applied to simulate a haze event that happened in January 2010 in the North China Plain (NCP), and was validated against various types of measurements. The evaluations indicate that WRF-Chem provides reliable simulations for the 2010 haze event in the NCP. This haze event was mainly caused by high emissions of air pollutants in the NCP and stable weather conditions in winter. Secondary inorganic aerosols also played an important role and cloud chemistry had important contributions. Air pollutants outside Beijing contributed about 64.5 % to the PM2.5 levels in Beijing during this haze event, and most of them are from south Hebei, Tianjin city, Shandong and Henan provinces. In addition, aerosol feedback has important impacts on surface temperature, relative humidity (RH) and wind speeds, and these meteorological variables affect aerosol distribution and formation in turn. In Shijiazhuang, Planetary Boundary Layer (PBL) decreased about 278.2 m and PM2.5 increased more than 20 µg m-3 due to aerosol feedback. It was also shown that black carbon (BC) absorption has significant impacts on meteorology and air quality changes, indicating more attention should be paid to BC from both air pollution control and climate change perspectives.

  3. The Link between Knowledge, Attitudes and Practices in Relation to Atmospheric Haze Pollution in Peninsular Malaysia.

    Science.gov (United States)

    De Pretto, Laura; Acreman, Stephen; Ashfold, Matthew J; Mohankumar, Suresh K; Campos-Arceiz, Ahimsa

    2015-01-01

    Transboundary haze episodes caused by seasonal forest fires have become a recurrent phenomenon in Southeast Asia, with serious environmental, economic, and public health implications. Here we present a cross-sectional survey conducted among people in Kuala Lumpur and surrounds to assess the links between knowledge, attitudes, and practices in relation to the transboundary haze episodes. Of 305 respondents, 125 were amateur athletes participating in a duathlon event and the remainder were surveyed in an inner-city shopping mall. Across the whole sample, people who possessed more factual information about the haze phenomenon showed significantly higher levels of concern. Duathletes were more knowledgeable than non-duathletes and also more concerned about the negative effects of haze, especially on health. For all people who regularly practice outdoor sports (including people interviewed at the shopping mall), higher levels of knowledge and concerned attitudes translated into a greater likelihood of engaging in protective practices, such as cancelling their outdoor training sessions, while those with greater knowledge were more likely to check the relevant air pollution index on a daily basis. Our results indicate that the provision of accurate and timely information about air quality to residents will translate into beneficial practices, at least among particularly exposed individuals, such as amateur athletes who regularly practice outdoor sports.

  4. The Link between Knowledge, Attitudes and Practices in Relation to Atmospheric Haze Pollution in Peninsular Malaysia.

    Directory of Open Access Journals (Sweden)

    Laura De Pretto

    Full Text Available Transboundary haze episodes caused by seasonal forest fires have become a recurrent phenomenon in Southeast Asia, with serious environmental, economic, and public health implications. Here we present a cross-sectional survey conducted among people in Kuala Lumpur and surrounds to assess the links between knowledge, attitudes, and practices in relation to the transboundary haze episodes. Of 305 respondents, 125 were amateur athletes participating in a duathlon event and the remainder were surveyed in an inner-city shopping mall. Across the whole sample, people who possessed more factual information about the haze phenomenon showed significantly higher levels of concern. Duathletes were more knowledgeable than non-duathletes and also more concerned about the negative effects of haze, especially on health. For all people who regularly practice outdoor sports (including people interviewed at the shopping mall, higher levels of knowledge and concerned attitudes translated into a greater likelihood of engaging in protective practices, such as cancelling their outdoor training sessions, while those with greater knowledge were more likely to check the relevant air pollution index on a daily basis. Our results indicate that the provision of accurate and timely information about air quality to residents will translate into beneficial practices, at least among particularly exposed individuals, such as amateur athletes who regularly practice outdoor sports.

  5. Haze event monitoring and investigation in Penang Island, Malaysia using a ground-based backscatter Lidar

    International Nuclear Information System (INIS)

    During 24th July 2013 to 1st August 2013, a haze event struck Penang Island, causing the visibility to decrease and increase in Air Pollution Index (API). A ground-based backscatter Lidar, operate at 355 nm which was setup at the roof top of the School of Physics, Universiti Sains Malaysia. It was used to monitor and investigate the haze event. For this work, we studied the daytime variation of the aerosol intensity, distribution, planetary boundary layer (PBL) height and the aerosol optical depth (AOD) values during these days. We found that the aerosol are very intense during the first two days of the haze event and slowly decline as time passed. Finally the haze event died off on 1st August 2013. As for daily aerosol distribution, aerosols are generally more intense during the afternoon. Its intensity is slightly lower in the morning and evening. Similar trends were observed for AOD values as they increase from morning to afternoon and slowly decrease in the evening. Most aerosols are found contained below the PBL which generally found at around 1000 – 2000 m in height

  6. 77 FR 61477 - Approval and Promulgation of Implementation Plans; State of Hawaii; Regional Haze Federal...

    Science.gov (United States)

    2012-10-09

    ... worst polluters in Hawaii. The commenter noted that EPA has not proposed additional pollution controls... address regional haze in the State of Hawaii. This FIP addresses the requirements of the Clean Air Act... ``from manmade air pollution'' . According to the commenter, failing to include the volcano in...

  7. 77 FR 27671 - State of Hawaii; Regional Haze Federal Implementation Plan

    Science.gov (United States)

    2012-05-11

    ... air pollution.'' Hawaii has two Class I areas: Hawaii Volcanoes National Park on the Big Island and... available by May 16, 2012 on the following Web site: http://www.epa.gov/region9/air/actions/hawaii.html and... AGENCY 40 CFR Part 52 State of Hawaii; Regional Haze Federal Implementation Plan AGENCY:...

  8. Planck Intermediate Results. IX. Detection of the Galactic haze with Planck

    CERN Document Server

    Ade, P A R; Arnaud, M; Ashdown, M; Atrio-Barandela, F; Aumont, J; Baccigalupi, C; Balbi, A; Banday, A J; Barreiro, R B; Bartlett, J G; Battaner, E; Benabed, K; Benoît, A; Bernard, J -P; Bersanelli, M; Bonaldi, A; Bond, J R; Borrill, J; Bouchet, F R; Burigana, C; Cabella, P; Cardoso, J -F; Catalano, A; Cayón, L; Chary, R -R; Chiang, L -Y; Christensen, P R; Clements, D L; Colombo, L P L; Coulais, A; Crill, B P; Cuttaia, F; Danese, L; D'Arcangelo, O; Davis, R J; de Bernardis, P; de Gasperis, G; de Rosa, A; de Zotti, G; Delabrouille, J; Dickinson, C; Diego, J M; Dobler, G; Dole, H; Donzelli, S; Doré, O; Dörl, U; Douspis, M; Dupac, X; Efstathiou, G; Enßlin, T A; Eriksen, H K; Finelli, F; Forni, O; Frailis, M; Franceschi, E; Galeotta, S; Ganga, K; Giard, M; Giardino, G; González-Nuevo, J; Górski, K M; Gratton, S; Gregorio, A; Gruppuso, A; Hansen, F K; Harrison, D; Helou, G; Henrot-Versillé, S; Hernández-Monteagudo, C; Hildebrandt, S R; Hivon, E; Hobson, M; Holmes, W A; Hornstrup, A; Hovest, W; Huffenberger, K M; Jaffe, T R; Jagemann, T; Jones, W C; Juvela, M; Keihänen, E; Knoche, J; Knox, L; Kunz, M; Kurki-Suonio, H; Lagache, G; Lähteenmäki, A; Lamarre, J -M; Lasenby, A; Lawrence, C R; Leach, S; Leonardi, R; Lilje, P B; Linden-Vørnle, M; López-Caniego, M; Lubin, P M; Macías-Pérez, J F; Maffei, B; Maino, D; Mandolesi, N; Maris, M; Martin, P G; Martínez-González, E; Masi, S; Massardi, M; Matarrese, S; Matthai, F; Mazzotta, P; Meinhold, P R; Melchiorri, A; Mendes, L; Mennella, A; Mitra, S; Miville-Deschênes, M -A; Moneti, A; Montier, L; Morgante, G; Munshi, D; Murphy, J A; Naselsky, P; Natoli, P; Nørgaard-Nielsen, H U; Noviello, F; Osborne, S; Pajot, F; Paladini, R; Paoletti, D; Partridge, B; Pearson, T J; Perdereau, O; Perrotta, F; Piacentini, F; Piat, M; Pierpaoli, E; Pietrobon, D; Plaszczynski, S; Pointecouteau, E; Polenta, G; Ponthieu, N; Popa, L; Poutanen, T; Pratt, G W; Prunet, S; Puget, J -L; Rachen, J P; Rebolo, R; Reinecke, M; Renault, C; Ricciardi, S; Riller, T; Rocha, G; Rosset, C; Rubiño-Martín, J A; Rusholme, B; Sandri, M; Savini, G; Schaefer, B M; Scott, D; Smoot, G F; Stivoli, F; Sudiwala, R; Suur-Uski, A -S; Sygnet, J -F; Tauber, J A; Terenzi, L; Toffolatti, L; Tomasi, M; Tristram, M; Türler, M; Umana, G; Valenziano, L; Van Tent, B; Vielva, P; Villa, F; Vittorio, N; Wade, L A; Wandelt, B D; White, M; Yvon, D; Zacchei, A; Zonca, A

    2012-01-01

    Using precise full-sky observations from Planck, and applying several methods of component separation, we identify and characterize the emission from the Galactic "haze" at microwave wavelengths. The haze is a distinct component of diffuse Galactic emission, roughly centered on the Galactic centre, and extends to |b| ~35 deg in Galactic latitude and |l| ~15 deg in longitude. By combining the Planck data with observations from the WMAP we are able to determine the spectrum of this emission to high accuracy, unhindered by the large systematic biases present in previous analyses. The derived spectrum is consistent with power-law emission with a spectral index of -2.55 +/- 0.05, thus excluding free-free emission as the source and instead favouring hard-spectrum synchrotron radiation from an electron population with a spectrum (number density per energy) dN/dE ~ E^-2.1. At Galactic latitudes |b|<30 deg, the microwave haze morphology is consistent with that of the Fermi gamma-ray "haze" or "bubbles," indicating ...

  9. 77 FR 40149 - Approval, Disapproval and Promulgation of Implementation Plans; State of Nebraska; Regional Haze...

    Science.gov (United States)

    2012-07-06

    ... rain, ozone formation, and nitrogen deposition. The commenter also stated that haze-causing pollutants... acid rain. We agree that the same emissions that cause visibility impairment can form fine PM and be... Implementation Plans to Reduce Interstate Transport of Fine Particulate Matter and Ozone, 76 FR 48208 (August...

  10. 77 FR 75703 - Partial Approval and Disapproval of Air Quality Implementation Plans; Arizona; Regional Haze and...

    Science.gov (United States)

    2012-12-21

    ... reasonable progress toward the national goal of achieving natural visibility conditions in 156 national parks... refer to nitrogen oxides. (17) The initials NM mean or refer to National Monument. (18) The initials NP... Implementation Plans A. Regional Haze Rule B. Determination of Baseline, Natural and Current...

  11. Redefining the importance of nitrate during haze pollution to help optimize an emission control strategy

    Science.gov (United States)

    Pan, Yuepeng; Wang, Yuesi; Zhang, Junke; Liu, Zirui; Wang, Lili; Tian, Shili; Tang, Guiqian; Gao, Wenkang; Ji, Dongsheng; Song, Tao; Wang, Yonghong

    2016-09-01

    Nitrate salts represent a major component of fine mode aerosols, which play an important role in air pollution worldwide. Based on on-line and off-line aerosol measurements in urban Beijing for both clean and haze conditions, we demonstrate that the absolute and relative concentrations of nitrate increased with visibility degradation (relative humidity), whereas the variations of organics tracked the patterns of mixing-layer height and temperature. We propose that the increase in the relative contribution of nitrate to PM1 observed during the early stages of haze pollution was due to new particle formation, whereas the nitrate formed in PM1-2.5 during the latter stages was due to heterogeneous formation and hygroscopic growth. The increasing trend of nitrate (and also sulfate and ammonium) but decreasing trends of organics during haze development, together with the increase of the NO2/SO2 molar ratio with increasing proximity to downtown Beijing and with visibility degradation, provide further evidence that controlling NOx emissions should be a priority for improving air quality in mega cities. Additional large-scale investigation is required to adequately characterize the regional features of NOx-induced haze pollution in China. Such studies may provide insight into the formation of critical nuclei or the subsequent growth of freshly nucleated particles and advance our understanding of the role of nitrate in new particle formation.

  12. 78 FR 51686 - Approval and Promulgation of Implementation Plans; Oklahoma; Regional Haze and Interstate...

    Science.gov (United States)

    2013-08-21

    ... dioxide (SO 2 ) and oxides of nitrogen (NO X ) for Units 3 and 4 of the American Electric Power/Public... Regional Haze Rule. We are also proposing to approve a related SIP revision submitted to address the impact... various portions of this SIP submittal (76 FR 81727, December 28, 2011). Even as significant portions...

  13. Archean Earth Atmosphere Fractal Haze Aggregates: Light Scattering Calculations and the Faint Young Sun Paradox

    Science.gov (United States)

    Boness, D. A.; Terrell-Martinez, B.

    2010-12-01

    As part of an ongoing undergraduate research project of light scattering calculations involving fractal carbonaceous soot aggregates relevant to current anthropogenic and natural sources in Earth's atmosphere, we have read with interest a recent paper [E.T. Wolf and O.B Toon,Science 328, 1266 (2010)] claiming that the Faint Young Sun paradox discussed four decades ago by Carl Sagan and others can be resolved without invoking heavy CO2 concentrations as a greenhouse gas warming the early Earth enough to sustain liquid water and hence allow the origin of life. Wolf and Toon report that a Titan-like Archean Earth haze, with a fractal haze aggregate nature due to nitrogen-methane photochemistry at high altitudes, should block enough UV light to protect the warming greenhouse gas NH3 while allowing enough visible light to reach the surface of the Earth. To test this hypothesis, we have employed a rigorous T-Matrix arbitrary-particle light scattering technique, to avoid the simplifications inherent in Mie-sphere scattering, on haze fractal aggregates at UV and visible wavelenths of incident light. We generate these model aggregates using diffusion-limited cluster aggregation (DLCA) algorithms, which much more closely fit actual haze fractal aggregates than do diffusion-limited aggregation (DLA) algorithms.

  14. 78 FR 18280 - Approval and Promulgation of Air Quality Implementation Plans; Nevada; Regional Haze Federal...

    Science.gov (United States)

    2013-03-26

    ... project to reduce emissions of NO X at RGGS. This project, as documented in a Gantt chart created by S&L... have developed a compressed 42-month (three and one-half year) schedule set forth in the Gantt chart in.... See, for example, EPA's proposed approval of the Nevada Regional Haze SIP on June 22, 2011 (76...

  15. 76 FR 41158 - Approval and Promulgation of Air Quality Implementation Plans; West Virginia; Regional Haze State...

    Science.gov (United States)

    2011-07-13

    .... EPA promulgated a rule to address regional haze on July 1, 1999 (64 FR 35713), the RHR. The RHR... FR 39104, 39142-4143, July 6, 2005). CAIR, as originally promulgated, requires significant reductions.... (75 FR 45210, Aug. 2, 2010) (``the Transport Rule''). EPA explained in that proposal that...

  16. Highly transparent, low-haze, hybrid cellulose nanopaper as electrodes for flexible electronics.

    Science.gov (United States)

    Xu, Xuezhu; Zhou, Jian; Jiang, Long; Lubineau, Gilles; Ng, Tienkhee; Ooi, Boon S; Liao, Hsien-Yu; Shen, Chao; Chen, Long; Zhu, J Y

    2016-06-16

    Paper is an excellent candidate to replace plastics as a substrate for flexible electronics due to its low cost, renewability and flexibility. Cellulose nanopaper (CNP), a new type of paper made of nanosized cellulose fibers, is a promising substrate material for transparent and flexible electrodes due to its potentially high transparency and high mechanical strength. Although CNP substrates can achieve high transparency, they are still characterized by high diffuse transmittance and small direct transmittance, resulting in high optical haze of the substrates. In this study, we proposed a simple methodology for large-scale production of high-transparency, low-haze CNP comprising both long cellulose nanofibrils (CNFs) and short cellulose nanocrystals (CNCs). By varying the CNC/CNF ratio in the hybrid CNP, we could tailor its total transmittance, direct transmittance and diffuse transmittance. By increasing the CNC content, the optical haze of the hybrid CNP could be decreased and its transparency could be increased. The direct transmittance and optical haze of the CNP were 75.1% and 10.0%, respectively, greatly improved from the values of previously reported CNP (31.1% and 62.0%, respectively). Transparent, flexible electrodes were fabricated by coating the hybrid CNP with silver nanowires (AgNWs). The electrodes showed a low sheet resistance (minimum 1.2 Ω sq(-1)) and a high total transmittance (maximum of 82.5%). The electrodes were used to make a light emitting diode (LED) assembly to demonstrate their potential use in flexible displays.

  17. 77 FR 31240 - Approval and Promulgation of Air Quality Implementation Plans; State of Florida; Regional Haze...

    Science.gov (United States)

    2012-05-25

    ... haze on July 1, 1999 (64 FR 35713), the RHR. The RHR revised the existing visibility regulations to... 76 FR 82219 (December 30, 2011). EPA is not proposing to take action in today's rulemaking on issues... natural conditions. See 64 FR 35715 (July 1, 1999). \\5\\ Visual range is the greatest distance,...

  18. 77 FR 3681 - Approval and Promulgation of Air Quality Implementation Plans; Minnesota; Regional Haze

    Science.gov (United States)

    2012-01-25

    ... CAIR under regulations issued in 2005 revising the regional haze program. 70 FR 39104 (July 6, 2005... would exist under estimated natural conditions. See 64 FR 35715 (July 1, 1999). \\1\\ Areas designated as... important value. 44 FR 69122 (November 30, 1979). The extent of a mandatory Class I area includes...

  19. 78 FR 57487 - Approval and Promulgation of Air Quality Implementation Plans; Massachusetts; Regional Haze

    Science.gov (United States)

    2013-09-19

    ... relies''), 70 FR 39104, 39143 (``The baseline date for regional haze SIPs is 2002. . . .'') & id. n.84... published a Notice of Proposed Rulemaking (NPR) for the State of Massachusetts. See 77 FR 30932. The NPR... upheld in Utility Air Regulatory Group v. EPA, 471 F.3d 1333 (D.C. Cir. 2006). See 77 FR 33642,...

  20. 77 FR 71533 - Approval and Promulgation of Air Quality Implementation Plans; Michigan; Regional Haze State...

    Science.gov (United States)

    2012-12-03

    ... Regional Haze Rule was promulgated on July 1, 1999 (64 FR 35713), with further significant provisions promulgated on July 6, 2005 (70 FR 39104), that provided guidance related to BART. On August 6, 2012 (77 FR... Michigan and a number of other states in a separate rulemaking, published on June 7, 2012 (77 FR...

  1. 77 FR 38006 - Approval and Promulgation of Implementation Plans; State of Iowa: Regional Haze

    Science.gov (United States)

    2012-06-26

    ... Regional Haze SIP and imposed a FIP for Iowa. 77 FR 33642. V. Statutory and Executive Order Requirements... Executive Order Reviews I. Background On February 28, 2012 (77 FR 11974), EPA published a notice of proposed... Executive Order 12866 (58 FR 51735, October 4, 1993); Does not impose an information collection burden...

  2. 77 FR 73369 - Approval and Promulgation of Air Quality Implementation Plans; State of Florida; Regional Haze...

    Science.gov (United States)

    2012-12-10

    ... CAIR to meet certain regional haze requirements. See 76 FR 82219 (December 30, 2011). On May 25, 2012... first implementation period. See 77 FR 31240. EPA's May 25, 2012, proposed rulemaking covered Florida's... sources. On November 29, 2012 (77 FR 71111), EPA took final action fully approving the unit-specific...

  3. Effect of Homoharringtonine on Corneal Haze after Excimer Laser Photorefractive Keratectomy in Rabbits

    Institute of Scientific and Technical Information of China (English)

    ZHANG Mingchang; WANG Li; WANG Yong; DING Zhengping; MAI Caikeng; NIE Shaosong; CHEN Fei

    2005-01-01

    To evaluate the inhibiting effect of Homoharringtonine HHT) on the corneal haze after excimer laser photorefractive keratectomy (PRK) in rabbits. 18 healthy rabbits which underwent PRK were randomly divided into three groups (A, B and C). The refractive degree of ablation was -10. 0DS in each group. Group A was locally treated with a piece of filter paper soaked with 1 mg/mi HHT for 5 min, and then the entire cornea was repeatedly irrigated with balance solution;Group B was dropped with 0.1 mg/mL HHT after PRK for 3 months; Group C was the control group. Corneal haze, histopathology, response, ect. were investigated. The corneal haze was sig nificantly less in group A, while the difference between group B and group C was insignificant.Keratocytes and fibrocytes in corneal stroma were more active up to 3 months in group B and group C. Intraoperative use of topical HHT can reduce corneal haze after PRK in rabbits.

  4. 77 FR 3712 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Regional Haze

    Science.gov (United States)

    2012-01-25

    ... the regional haze program. 70 FR 39104 (July 6, 2005). EPA's regulations provided that states... natural conditions. See 64 FR 35715 (July 1, 1999). \\1\\ Areas designated as mandatory Class I Federal..., promulgated a list of 156 areas where visibility is identified as an important value. 44 FR 69122 (November...

  5. 77 FR 35287 - Approval and Promulgation of Air Quality Implementation Plans; Virginia; Regional Haze State...

    Science.gov (United States)

    2012-06-13

    ... Haze Rule (RH rule) (64 FR 35732, July 1, 1999) and the rationale for EPA's proposed action are...,'' or ``our'' is used, we mean EPA. On January 25, 2012 (77 FR 3691), EPA published a notice of proposed... Virginia). (76 FR 82219, December 30, 2011). Given the significance of the emissions reductions from...

  6. 77 FR 34218 - Approval and Promulgation of Air Quality Implementation Plans; Indiana; Regional Haze

    Science.gov (United States)

    2012-06-11

    ... SIP.' The baseline date for regional haze SIPs is 2002 * * *'' 70 FR 39143. Comment #2: For the Alcoa... CFR 51.308. This rule was promulgated on July 1, 1999 (64 FR 35713). Further significant provisions... proposed a limited approval of Indiana's submittal on January 26, 2012 (77 FR 3975). That action...

  7. Aspartic Acid Protease from Botrytis cinerea Removes Haze-Forming Proteins during White Winemaking

    NARCIS (Netherlands)

    Sluyter, Van S.C.; Warnock, N.I.; Schmidt, S.; Anderson, P.; Kan, van J.A.L.; Bacic, A.; Waters, E.J.

    2013-01-01

    White wines suffer from heat-induced protein hazes during transport and storage unless the proteins are removed prior to bottling. Bentonite fining is by far the most commonly used method, but it is inefficient and creates several other process challenges. An alternative to bentonite is the enzymati

  8. 77 FR 11827 - Approval and Promulgation of Air Quality Implementation Plans; State of Maryland; Regional Haze...

    Science.gov (United States)

    2012-02-28

    ... promulgated a rule to address regional haze on July 1, 1999 (64 FR 35714), the RHR. The RHR revised the... under estimated natural conditions (64 FR 35714, July 1, 1999). \\1\\ Visual range is the greatest... visibility impairment'' (45 FR 80084). These regulations represented the first phase in addressing...

  9. 77 FR 11937 - Approval and Promulgation of Air Quality Implementation Plans; State of Alabama; Regional Haze...

    Science.gov (United States)

    2012-02-28

    ... submittal arising from the State's reliance on CAIR to meet certain regional haze requirements. See 76 FR... in 40 CFR 52.61 that were approved into the Alabama SIP. See 52 FR 45138 (November 24, 1987). EPA is... 64 FR 35715 (July 1, 1999). \\3\\ Visual range is the greatest distance, in kilometers or miles,...

  10. Cloud and Haze in the Atmospheres of Wide-Separation Exoplanets

    Science.gov (United States)

    Hu, Renyu

    2016-10-01

    Imaging and characterizing wide-separation exoplanets with spaceborne coronagraph will write a new chapter of exoplanet science. Most of the exoplanets to be observed by coronagraph will be located further away from their parent stars than is Earth from the Sun. These "cold" exoplanets have atmospheric environments conducive for the formation of water and/or ammonia clouds by condensation. Above the condensation clouds, photochemical processes driven by UV irradiation can lead to formation of haze particles. Understanding the cloud and haze in the atmosphere of wide-separation exoplanets is essential, because they determine the planets' spectral signal and how well we can measure the planets' atmospheric abundances. Using atmospheric chemistry and radiative transfer models, I find that the mixing ratio of methane and the pressure level of the uppermost cloud deck on these planets can be uniquely determined from their reflection spectra, if a strong band and a weak band of methane are measured at moderate spectral resolutions. This determination can however be biased by a haze layer above the cloud. To constrain the uncertainty, atmospheric photochemistry models are used to estimate the amount of haze particles.

  11. Modeling study of the 2010 regional haze event in the North China Plain

    Directory of Open Access Journals (Sweden)

    M. Gao

    2015-08-01

    Full Text Available The online coupled Weather Research and Forecasting-Chemistry (WRF-Chem model was applied to simulate a haze event that happened in January 2010 in the North China Plain (NCP, and was validated against various types of measurements. The evaluations indicate that WRF-Chem provides reliable simulations for the 2010 haze event in the NCP. This haze event is mainly caused by high emissions of air pollutants in the NCP and stable weather conditions in winter. Secondary inorganic aerosols also played an important role and cloud chemistry had important contributions. Air pollutants outside Beijing contributed about 47.8 % to the PM2.5 levels in Beijing during this haze event, and most of them are from south Hebei, Shandong and Henan provinces. In addition, aerosol feedback has important impacts on surface temperature, Relative Humidity (RH and wind speeds, and these meteorological variables affect aerosol distribution and formation in turn. In Shijiazhuang, Planetary Boundary Layer (PBL decreased about 300 m and PM2.5 increased more than 20 μg m-3 due to aerosol feedback. Feedbacks associated to Black Carbon (BC account for about 50 % of the PM2.5 increases and 50 % of the PBL decreases in Shijiazhuang, indicating more attention should be paid to BC from both air pollution control and climate change perspectives.

  12. Particulate Characteristics during a Haze Episode Based on Two Ceilometers with Different Wavelengths

    Directory of Open Access Journals (Sweden)

    Jing Yuan

    2016-01-01

    Full Text Available To investigate the particulate characteristics of a haze episode, data from two ceilometers with wavelengths of 532 nm and 910 nm, respectively, were studied intensively. By combining the data from the ceilometers with data from a sounding balloon, an automatic meteorological station, and a Grimm 180 PM instrument, analyses of the haze process of a short haze event were performed. The results showed that the relatively calm weather conditions were favorable to the occurrence of the haze and that higher relative humidity had a great influence on visibility. The extinction profiles from the ceilometers reflected the existence of an inverted structure of the temperature profiles and demonstrated the extinction differences at two different wavelengths. Because extinction has a positive correlation with relative humidity, the effect of hygroscopic growth was analyzed at the two different wavelengths. As hygroscopic growth of the particles proceeded, the longer wavelength became more sensitive to the large particles, and vice versa. The hygroscopic growth factor and the Angstrom exponent showed a negative correlation, and the correlation coefficients at 532 nm and 910 nm were 0.54 and 0.86, respectively. The accumulation mode particles were more stable through time than the coarse mode particles, and the variation of the coarse mode particles coincided well with the variation of the Angstrom exponent from the two ceilometers.

  13. Haze event monitoring and investigation in Penang Island, Malaysia using a ground-based backscatter Lidar

    Science.gov (United States)

    Hee, W. S.; Tan, F.; Lim, H. S.; Matjafri, M. Z.

    2014-06-01

    During 24th July 2013 to 1st August 2013, a haze event struck Penang Island, causing the visibility to decrease and increase in Air Pollution Index (API). A ground-based backscatter Lidar, operate at 355 nm which was setup at the roof top of the School of Physics, Universiti Sains Malaysia. It was used to monitor and investigate the haze event. For this work, we studied the daytime variation of the aerosol intensity, distribution, planetary boundary layer (PBL) height and the aerosol optical depth (AOD) values during these days. We found that the aerosol are very intense during the first two days of the haze event and slowly decline as time passed. Finally the haze event died off on 1st August 2013. As for daily aerosol distribution, aerosols are generally more intense during the afternoon. Its intensity is slightly lower in the morning and evening. Similar trends were observed for AOD values as they increase from morning to afternoon and slowly decrease in the evening. Most aerosols are found contained below the PBL which generally found at around 1000 - 2000 m in height.

  14. Laboratory Simulation of Haze/Aerosol formation in warm and hot Jupiters

    Science.gov (United States)

    Gharib-Nezhad, Ehsan; Lyons, James R.; Wright, David P.

    2016-10-01

    During the transit of an exoplanet across its host star, transmitted starlight through exoplanet atmosphere is absorbed and scattered, and the recorded transit spectra reveal important chemical information. There are many detected exoplanets in which hazes/aerosols obscure the incident photons, and consequently, fewer photons are transmitted through the atmosphere, contributing to a flat/nearly flat transit spectrum. Here, we have carried out two complementary approaches to address haze formation. First, laboratory simulations of haze condensation in exoplanet atmospheres are carried out using an electric discharge tube. A mixture of likely gas species (i.e. H2, He, H2O, CH4, N2 and H2S) is inserted into a glass manifold on a vacuum line, at a pressure ~100-10 mbar, and depending on the exoplanet category (e.g., warm or hot Jupiters), the temperature is set. Applying a few kilovolts produces plasma in the discharge tube, and as a result, particles are formed. We use spectroscopic ellipsometry to measure the optical constants (complex refractive index) of the collected laboratory hazes. Then, chemical characterization is made using RBS (Rutherford Backscattering Spectroscopy) and XPS (X-ray Photoelectron Spectroscopy). Second, we developed a transit modeling code by which the transit spectra are generated using observational and laboratory data as an input. The model accounts for Mie scattering from haze particles in the vis-NIR spectral region, and Rayleigh scattering which comes from gases and particles (effective in UV-vis). The measured refractive indexes (real and imaginary part) describe the absorption and scattering in the vis-NIR transmission region, and, by generating transit spectra close to the observed ones from exoplanets, constraints on atmospheric chemical characterization can be revealed. Our laboratory results show that haze particles formed in the presence of water and with the solar C/O ratio = 0.5. The other outcome of our experiment is that

  15. Characterization of major pollution events (dust, haze, and two festival events) at Agra, India.

    Science.gov (United States)

    Pachauri, Tripti; Singla, Vyoma; Satsangi, Aparna; Lakhani, Anita; Kumari, K Maharaj

    2013-08-01

    Total suspended particulate (TSP) samples were collected during dust, haze, and two festival events (Holi and Diwali) from February 2009 to June 2010. Pollutant gases (NO2, SO2, and O3) along with the meteorological parameters were also measured during the four pollution events at Agra. The concentration of pollutant gases decreases during dust events (DEs), but the levels of the gases increase during other pollution events indicating the impact of anthropogenic emissions. The mass concentrations were about two times higher during pollution events than normal days (NDs). High TSP concentrations during Holi and Diwali events may be attributed to anthropogenic activities while increased combustion sources in addition to stagnant meteorological conditions contributed to high TSP mass during haze events. On the other hand, long-range transport of atmospheric particles plays a major role during DEs. In the dust samples, Ca(2+), Cl(-), NO3 (-), and SO4 (2-) were the most abundant ions and Ca(2+) alone accounted for 22 % of the total ionic mass, while during haze event, the concentrations of secondary aerosols species, viz., NO3 (-), SO4 (2-), and NH4 (+), were 3.6, 3.3, and 5.1 times higher than the normal days. During Diwali, SO4 (2-) concentration (17.8 μg m(-3)) was highest followed by NO3 (-), K(+), and Cl(-) while the Holi samples were strongly enriched with Cl(-) and K(+) which together made up 32.7 % of the total water-soluble ions. The ion balances indicate that the haze samples were acidic. On the other hand, Holi, Diwali, and DE samples were enriched with cations. The carbonaceous aerosol shows strong variation with the highest concentration during Holi followed by haze, Diwali, DEs, and NDs. However, the secondary organic carbon concentration follows the order haze > DEs > Diwali > Holi > NDs. The scanning electron microscope/EDX results indicate that KCl and carbon-rich particles were more dominant during Holi and haze events while DE samples were enriched

  16. Characterization of major pollution events (dust, haze, and two festival events) at Agra, India.

    Science.gov (United States)

    Pachauri, Tripti; Singla, Vyoma; Satsangi, Aparna; Lakhani, Anita; Kumari, K Maharaj

    2013-08-01

    Total suspended particulate (TSP) samples were collected during dust, haze, and two festival events (Holi and Diwali) from February 2009 to June 2010. Pollutant gases (NO2, SO2, and O3) along with the meteorological parameters were also measured during the four pollution events at Agra. The concentration of pollutant gases decreases during dust events (DEs), but the levels of the gases increase during other pollution events indicating the impact of anthropogenic emissions. The mass concentrations were about two times higher during pollution events than normal days (NDs). High TSP concentrations during Holi and Diwali events may be attributed to anthropogenic activities while increased combustion sources in addition to stagnant meteorological conditions contributed to high TSP mass during haze events. On the other hand, long-range transport of atmospheric particles plays a major role during DEs. In the dust samples, Ca(2+), Cl(-), NO3 (-), and SO4 (2-) were the most abundant ions and Ca(2+) alone accounted for 22 % of the total ionic mass, while during haze event, the concentrations of secondary aerosols species, viz., NO3 (-), SO4 (2-), and NH4 (+), were 3.6, 3.3, and 5.1 times higher than the normal days. During Diwali, SO4 (2-) concentration (17.8 μg m(-3)) was highest followed by NO3 (-), K(+), and Cl(-) while the Holi samples were strongly enriched with Cl(-) and K(+) which together made up 32.7 % of the total water-soluble ions. The ion balances indicate that the haze samples were acidic. On the other hand, Holi, Diwali, and DE samples were enriched with cations. The carbonaceous aerosol shows strong variation with the highest concentration during Holi followed by haze, Diwali, DEs, and NDs. However, the secondary organic carbon concentration follows the order haze > DEs > Diwali > Holi > NDs. The scanning electron microscope/EDX results indicate that KCl and carbon-rich particles were more dominant during Holi and haze events while DE samples were enriched

  17. Research on Haze Value of Wafer Surface%晶片表面Haze值研究

    Institute of Scientific and Technical Information of China (English)

    张伟才; 宋晶; 杨洪星; 赵权

    2011-01-01

    The Haze value of wafer surface is introduced from the definitions and theories based on the principle of SSIS. The Haze is explained as optical signals which can indirectly reflect the state of the wafer surface. The different materials and different surface were scanned by SSIS, and the effect of surface roughness and reflection coefficient on the Haze value and its distribution were studied. The results show that the Haze value of the same material increases with the increase of surface roughness, and the Haze value shows significant differences between different materials with similar roughness. Through the Analysis of the characteristics of scans, the relationship between Haze value distribution and the consistency of wafer surface state was studied. A new process feedback method for chemical mechanical polishing and wet cleaning process using Haze value was proposed.%介绍了晶片表面Haze值的定义和理论依据,通过对SSIS系统的原理分析,揭示了H aze是一种间接反映晶片表面状态的光学信号.通过对不同表面状态抛光片的光学扫描,研究了晶片表面粗糙度与Haze值的关系;通过对Si抛光片和砷化镓抛光片的扫描对比,研究了晶片本体反射系数对Haze值的影响.研究结果表明,同种材料的Haze值随着表面粗糙度的增大而增大,而不同的材料即使拥有相似的表面粗糙度,Haze值也会因本体反射系数的不同而呈现很大差异.通过对Haze扫描图的特征分析,研究了Haze值分布与晶片表面均匀性的关系,成功地利用Haze值分布将表面性状化,为化学机械抛光和湿法清洗工艺提供了一个新的反馈手段.

  18. Instant BlueStacks

    CERN Document Server

    Judge, Gary

    2013-01-01

    Get to grips with a new technology, understand what it is and what it can do for you, and then get to work with the most important features and tasks. A fast-paced, example-based approach guide for learning BlueStacks.This book is for anyone with a Mac or PC who wants to run Android apps on their computer. Whether you want to play games that are freely available for Android but not your computer, or you want to try apps before you install them on a physical device or use it as a development tool, this book will show you how. No previous experience is needed as this is written in plain English

  19. White light emitting diodes with enhanced CCT uniformity and luminous flux using ZrO2 nanoparticles.

    Science.gov (United States)

    Chen, Kuo-Ju; Han, Hau-Vei; Chen, Hsin-Chu; Lin, Chien-Chung; Chien, Shih-Hsuan; Huang, Chung-Ching; Chen, Teng-Ming; Shih, Min-Hsiung; Kuo, Hao-Chung

    2014-05-21

    To enhance the uniformity of correlated color temperature (CCT) and luminous flux, we integrated ZrO2 nanoparticles into white light-emitting diodes. This novel packaging scheme led to a more than 12% increase in luminous flux as compared to that in conventional dispensing structures. This was attributed to the scattering effect of ZrO2 nanoparticles, which enhanced the utilization of blue light. Moreover, the CCT deviation was reduced from 522 to 7 K in a range of -70 to +70°, and essentially eliminated the yellow ring phenomenon. The haze measurement indicated strong scattering across the visible spectrum in the presence of ZrO2 in the silicone layer, and this finding also substantiates our claim. In addition, the chromaticity coordinate shift was steady in the ZrO2 dispensing package structure as the drive current increased, which is crucial for indoor lighting. Combined with its low cost, easy fabrication, and superior optical characteristics, ZrO2 nanoparticles can be an effective performance enhancer for the future generation of white light-emitting devices. PMID:24706049

  20. Investigating the haze transport from 1997 biomass burning in Southeast Asia: its impact upon Singapore

    Science.gov (United States)

    Koe, Lawrence C. C.; Arellano, Avelino F.; McGregor, John L.

    The 1997 Indonesia forest fires was an environmental disaster of exceptional proportions. Such a disaster caused massive transboundary air pollution and indiscriminate destruction of biodiversity in the world. The immediate consequence of the fires was the production of large amounts of haze in the region, causing visibility and health problems within Southeast Asia. Furthermore, fires of these magnitudes are potential contributors to global warming and climate change due to the emission of large amounts of greenhouse gases and other pyrogenic products.The long-range transport of fire-related haze in the region is investigated using trajectories from the CSIRO Division of Atmospheric Research Limited Area Model (DARLAM). Emission scenarios were constructed for hotspot areas in Sumatra and Kalimantan for the months of September and October 1997 to determine the period and fire locations most critical to Singapore. This study also examines some transport issues raised from field observations. Results show that fires in the coastal areas of southeast Sumatra and southwest Kalimantan can be potential contributors to transboundary air pollution in Singapore. Singapore was directly affected by haze from these areas whereas Kuala Lumpur was heavily affected by the haze coming from Sumatra. In most cases, Singapore was more affected by fires from Kalimantan than was Kuala Lumpur. This was mainly a result of the shifting of monsoons. The transition of monsoons resulted in weaker low-level winds and shifted convergence zones near to the southeast of Peninsular Malaysia. In addition to severe drought and massive fire activity in 1997, the timing of the monsoon transition has a strong influence on haze transport in the region.

  1. Characteristics of aerosol pollution during heavy haze events in Suzhou, China

    Science.gov (United States)

    Tian, Mi; Wang, Huanbo; Chen, Yang; Yang, Fumo; Zhang, Xiaohua; Zou, Qiang; Zhang, Renquan; Ma, Yongliang; He, Kebin

    2016-06-01

    Extremely severe haze weather events occurred in many cities in China, especially in the east part of the country, in January 2013. Comprehensive measurements including hourly concentrations of PM2.5 and its major chemical components (water-soluble inorganic ions, organic carbon (OC), and elemental carbon (EC)) and related gas-phase precursors were conducted via an online monitoring system in Suzhou, a medium-sized city in Jiangsu province, just east of Shanghai. PM2.5 (particulate matter with an aerodynamic diameter of 2.5 µm or less) frequently exceeded 150 µg m-3 on hazy days, with the maximum reaching 324 µg m-3 on 14 January 2013. Unfavorable weather conditions (high relative humidity (RH), and low rainfall, wind speed, and atmospheric pressure) were conducive to haze formation. High concentrations of secondary aerosol species (including SO42-, NO3-, NH4+, and SOC) and gaseous precursors were observed during the first two haze events, while elevated primary carbonaceous species emissions were found during the third haze period, pointing to different haze formation mechanisms. Organic matter (OM), (NH4)2SO4, and NH4NO3 were found to be the major contributors to visibility impairment. High concentrations of sulfate and nitrate might be explained by homogeneous gas-phase reactions under low RH conditions and by heterogeneous processes under relatively high RH conditions. Analysis of air mass trajectory clustering and potential source contribution function showed that aerosol pollution in the studied areas was mainly caused by local activities and surrounding sources transported from nearby cities.

  2. The classification study of the heavy haze during autumn and winter of Jiangsu%江苏秋冬季重度霾的分型研究

    Institute of Scientific and Technical Information of China (English)

    戴竹君; 刘端阳; 王宏斌; 魏建苏; 姜有山

    2016-01-01

    By analyzing the conventional observation data,sounding data and reanalysis data of NCEP/NCAR,the circulation background,boundary layer characteristics,dynamic conditions,thermal conditions and the airflow trajectory of the heavy haze in Jiangsu Province during autumn and winter of 2014 are discussed.The results show that zonal circulation at 500 hPa was of more straightly west or northwest airflow.The airflow at 500 hPa changed to the northwest can be an indicator that heavy haze will disappear in 6 to 12 hours later.The main surface situations were uniform pattern of pressure,cold front and inverted trough with low pressure.The surface situation changed when heavy haze occurrs.Just before cold front coming,the haze was heaviest.The east path of cold air was more effective for eliminating haze than the middle or western path.In most of the heavy haze days,the bottom of the temperature inversion was near the ground.Lower wind speed of less than 4 m/s was shown to be favorable for the development of haze.The daily variation was obvious with the haze mitigated in the afternoon.As the intensi-ty and duration of temperature inversion are concerned,the inverted trough type was stronger than the cold front west path type,both of them were stronger than the uniform pressure type.But the three types were almost the same in terms of the thickness of inversion. Different types show different inversion intensity,which may be related to the prefrontal temperature enhancement and wind speed on 925 hPa and near ground,as well as air sources.The height of inversion layer is mostly under 300 m,with the intensity of temperature inversion for every hundred meters between 1 to 5℃,and higher relative humidity of greater than 40%and less than 90% were shown to be favorable for the development of haze.Underlying sink motion provided a favorable dy-namic condition for haze,and,weak upward motion at 850 hPa was conducive to the upward development of haze.By using backward trajectory

  3. Analysis of China’s Haze Days in the Winter Half-Year and the Climatic Background during 1961-2012

    Institute of Scientific and Technical Information of China (English)

    SONG Lian-Chun; GAO Rong; LI Ying; WANG Guo-Fu

    2014-01-01

    The characteristics of haze days and the climatic background are analyzed by using daily observations of haze, precipitation, mean and maximum wind speed of 664 meteorological stations for the period of 1961-2012. The results show that haze days occur significantly more often in eastern China than in western China. The annual number of haze days is 5-30 d in most parts of central-eastern China, with some areas experiencing more than 30 d, while less than 5 d are averagely occurring in western China. Haze days are mainly concentrated in the winter half-year, with most in winter, followed by autumn, spring, and then summer. Nearly 20% of annual haze days are experienced in December. The haze days in central-eastern China in the winter half-year have a significant increasing trend of 1.7 d per decade during 1961-2012. There were great increases in haze days in the 1960s, 1970s and the beginning of the 21st century. There was also significant abrupt changes of haze days in the early 1970s and 2000s. From 1961 to 2012, haze days in the winter half-year increased in South China, the middle-lower reaches of the Yangtze River, and North China, but decreased in Northeast China, eastern Northwest China and eastern Southwest China. The number of persistent haze is rising. The Longer the haze, the greater the proportion to the number persistent haze. Certain climatic conditions exacerbated the occurrence of haze. The correlation coefficient between haze days and precipitation days in the winter half-year is mainly negative in central-eastern China. The precipitation days show a decreasing trend in most parts of China, with a rate of around -4.0 d per decade in central-eastern China, which reduces the sedimentation capacity of atmospheric pollutants. During the period of 1961-2012, the correlation coefficients between haze days and mean wind speed and strong wind days are mainly negative in central-eastern China, while there exists positive correlation between haze days and

  4. Research Progress on Haze in China for the Past Ten Years%近10年来中国霾天气研究进展

    Institute of Scientific and Technical Information of China (English)

    万春燕

    2015-01-01

    文章从霾的判别研究、霾天气的成因、霾天气预报研究、霾天气监测技术研究、霾天气治理研究及霾天气尺度研究等6个方面进行梳理。未来需要加强对霾天气的持续动态监测,重视科学技术的更新应用,从动态、整体的视角进行霾天气的综合监测,为制定更为科学的霾天气应对措施提供依据。%The paper reviews the research on haze from the following six aspects:the criteria of haze,the cause of the haze weather,weather forecast of the haze,monitoring technology of the haze weather,the control and governance of the haze and the dimension research of haze weather. To provide a basis for making more scientific measures for haze weather,a continuous dynamic monitoring on haze weather should be strengthened,much more importance shall be attached to the updating and the application of science and technology,and a comprehensive monitoring on haze weather from both the dynamic and holistic perspective shall be conducted in the future research.

  5. Correlation of polishing-induced shallow subsurface damages with laser-induced gray haze damages in fused silica optics

    Science.gov (United States)

    He, Xiang; Zhao, Heng; Wang, Gang; Zhou, Peifan; Ma, Ping

    2016-08-01

    Laser-induced damage in fused silica optics greatly restricts the performances of laser facilities. Gray haze damage, which is always initiated on ceria polished optics, is one of the most important damage morphologies in fused silica optics. In this paper, the laser-induced gray haze damages of four fused silica samples polished with CeO2, Al2O3, ZrO2, and colloidal silica slurries are investigated. Four samples all present gray haze damages with much different damage densities. Then, the polishing-induced contaminant and subsurface damages in four samples are analyzed. The results reveal that the gray haze damages could be initiated on the samples without Ce contaminant and are inclined to show a tight correlation with the shallow subsurface damages.

  6. Characterization of individual aerosol particles collected during a haze episode in Incheon, Korea using the quantitative ED-EPMA technique

    Directory of Open Access Journals (Sweden)

    H. Geng

    2010-11-01

    Full Text Available Haze is an atmospheric phenomenon that leads to low visibility, and is mostly due to elevated levels of fine particulate matter. It can have effects on cloud formation, public health, agriculture, and even the global climate. Although urban haze has been increasing in occurrence over the past several years over the Seoul-Incheon metropolis, Korea, studies of the morphology and chemical composition of ambient aerosol particles by single-particle analysis during haze episodes have rarely been conducted. Herein, a quantitative energy-dispersive electron probe microanalysis (ED-EPMA, called low-Z particle EPMA, was used to analyze individual aerosol particles collected in Incheon, Korea on 13–18 October 2008 (a typical haze episode occurred from 15 to 18 October. Overall, 3600 particles in 12 aerosol samples collected on haze and non-haze days were measured by low-Z particle EPMA. Based on quantitative X-ray analysis, together with secondary electron images of individual particles, we successfully identified the aerosol particle types as follows: elemental carbon (EC, organic carbon (OC, (NH42SO4/NH4HSO4-containing, genuine (fresh and reacted (aged sea-salt, mineral dust (such as aluminosilicate, SiO2, CaCO3/CaMg(CO32, etc., and K-containing, Fe-rich, and fly ash particles. By analyzing the relative abundances of different particle types, it was concluded that (a on non-haze days, reacted sea-salts and reacted mineral dust particles were abundant in both the PM2.5–10 and PM1.0–2.5 fractions (with relative abundances of 65.0% and 57.7%, respectively; whereas on haze days, the relative abundances of OC and (NH42SO4/NH4HSO4-containing particles were significantly elevated, indicating that organic matter and secondary aerosols were abundant in the atmosphere

  7. 雾霾的产生与防治措施%Cause Amalysis amd Prevemtiom Measures of Fog - haze

    Institute of Scientific and Technical Information of China (English)

    李亚新

    2014-01-01

    近年来,我国中东部地区先后出现大面积持续雾霾天气,给人们生产生活造成了严重的影响。本文对雾霾天气形成的条件和污染源进行了分析,阐述了防治雾霾污染、改善空气质量的对策措施。%The fog - haze weather appears frequently in the area of Middle East China in recent years. It seriously affects human production and living. In this article the cause of fog - haze weather formation was analyzed in aspects of fog - haze weather condition and pollution resource. The measures and suggestions to improve the air quality for the prevention and control of fog - haze weather especially were expounded.

  8. Blue-sky thinking

    International Nuclear Information System (INIS)

    Global environmental problems - such as the greenhouse effect, the depletion of natural resources and the accumulation of wastes - have been recognized as common international issues affecting humanity since the 1990s. Sustainable development on a global scale is now sought, for instance, with the establishment of the targets for greenhouse gas reduction in the 1997 Kyoto Protocol, and with the adoption of the Declaration on Sustainable Development at the 2002 Johannesburg Summit. Honda launched the slogan 'Blue Sky for Children' in the 1960s when environmental pollution became a highly visible issue. During that decade we started an aggressive approach aimed at substantial environmental improvement, and unveiled the Compound Vortex Controlled Combustion (CVCC) engine - which used unique low-emission technology - in the United States and Japan. Since then, we have developed the Variable Valve Timing and Lift Electric Control System (VTEC) and the i-VTEC series with innovative engine technology, permitting global production of vehicles that combine high performance with state-of-the-art low-emission technologies. And we continued to work to preserve the global environment by releasing a hybrid vehicle, the Insight, which achieved the most efficient fuel consumption in the world at the time of its introduction in 1998

  9. 亚甲蓝对恶性胸腔积液腔内化疗增敏作用的研究与护理%Intracavitary Chemotherapy and Effect of Enhanced Sensitivity Researchand Nursing of Methylene Blue to Malignant Pleural Effusion

    Institute of Scientific and Technical Information of China (English)

    郭公慧; 王茂桂; 牟静

    2002-01-01

    目的探讨亚甲蓝在治疗恶性胸腔积液中对抗癌药物的增敏作用,提出有效护理措施,减少抗癌药物的副作用.方法对30例用亚甲蓝联合顺氯氨铂治疗恶性胸腔积液患者疗效进行了观察,同时设对照组,并就其副作用进行了观察与护理.结果治疗组有效率为86.6%;对照组有效率为73%,两组疗效、副作用相比较均具有明显差异,P<0.05.结论亚甲蓝在治疗恶性胸腔积液中对抗癌药物具有增敏和减毒作用.%Objective Purposes probed the effect of enhanced sensitivity of methylene blue to anti-cancer medicine when treating malignant pleural effusion. Put the effective nursing measures forward, reduced the side effect of anti-cancer medicine.Methods 30 patients` therapeutic effectiveness of malignant pleural effusion treated by methylene blue connecting with cis-platinium aminodichloride was observed, control group was set at the same time and its side effect was observed and nursed.Results Effective rate of treatment group was 86.6%; Control group was 73%.There was obvious difference between therapeutic effectives and side effect in two groups, P<0.05.Conclusions Methylene blue had effect of enhanced sensitivity to anti-cancer medicine when treating malignant pleural effusion.

  10. Local causes, regional co-operation and global financing for environemntal problems: the case of Southeast Asian Haze pollution

    OpenAIRE

    Luca Tacconi; Frank Jotzo; R. Quentin Grafton

    2006-01-01

    Lack of action on cross-border environmental problems in developing countries is often ascribed to gaps in local capacity and resources, failure of regional cooperation, and lack of financial support from rich countries. Using the case of the Southeast Asian Haze pollution from forest and peat fires in Indonesia, we explore the challenges posed by environmental problems whose causes are closely linked to local development and livelihood strategies, and whose impacts are local, regional (haze)...

  11. Seasonal variation of Titan's haze at low and high altitudes from HST-STIS spectroscopy

    Science.gov (United States)

    Karkoschka, Erich

    2016-05-01

    The Space Telescope Imaging Spectrograph accumulated image cubes of Titan in five years between 1997 and 2004 that we calibrated and analyzed. The observations probe Titan's early northern fall to early winter. Methane bands between 543 and 990 nm wavelength are well resolved spectrally, and Titan's latitudinal and center-to-limb reflectivity variations are resolved spatially. A principal component analysis revealed two large components and two small components of less significance. The first principal component describes a variation of Titan's haze below 80 ± 20 km altitude. Haze particles change their size, opacity, and/or shape of the single scattering phase function. The largest and smallest opacities occurred both in 1997 at high southern latitudes and northern latitudes, respectively. The hemispherical asymmetry switched sign in 2002 at low latitudes, in 2003 at mid latitudes, and in early 2004 at high latitudes. The seasonal amplitude increased almost linearly with distance from the Equator. Tropical latitudes had slightly lower opacities than the annual and global average if the observed variation is seasonally symmetric and shaped like a sine curve. The cause for the variation may be condensation of gases onto aerosols seasonally driven by atmospheric dynamics. The second principal component describes a variation of haze opacity at altitudes above 150 ± 50 km. Largest and smallest opacities both occurred in 2004 at northern and high southern latitudes, respectively. The asymmetry switched in late 2001. Tropical latitudes had significantly higher haze opacity than the annual and global average, opposite to the case at low altitudes. The cause for the high-altitude variation may be aerosols transported at varying speeds driven by atmospheric dynamics. We present a seasonal model that completely describes the haze parameters at each altitude, latitude, and time. It compares fairly well with Cassini results obtained since 2004. The north-south asymmetry may

  12. Haze types in Beijing and the influence of agricultural biomass burning

    Directory of Open Access Journals (Sweden)

    W. J. Li

    2010-09-01

    Full Text Available Emissions from agricultural biomass burning (ABB in northern China have a significant impact on the regional and global climate. The monthly average aerosol optical depth (AOD at 550 nm in northern China in 2007 had a maximum of 0.7 in June. The AOD measurements are consistent with regional brown hazes that occurred at that time, which was a period of severe aerosol pollution. Aerosol particles were collected in urban Beijing from 12 to 30 June 2007, during a period of high haze, and studied using transmission electron microscopy with energy-dispersive X-ray spectrometry. The dominant particle types collected in the fine fraction (diameter <1 μm were ammonium sulfate, soot, K2SO4, KNO3, and organic matter, except that the K salts were minor between 21 and 30 June. K-rich particles as tracers of biomass burning, together with wildfire maps, show that intense regional ABB in northern China contributed significantly to the regional haze between 12 and 20 June. We therefore grouped the episodes into type-1 and -2 haze, with the former occurring between 12 and 20 June and the latter between 21 and 30 June. After long-range transport, ABB particles in the type-1 haze exhibited marked changes in morphology, composition, and mixing state. KCl particles were absent, presumably having been converted by heterogeneous reactions to K2SO4 and KNO3. Soot particles were mixed with the other particle types. Abundant organic matter and soluble salts emitted by ABB increased their sizes during transport and resulted in more hygroscopic aerosol particles in downwind areas, becoming additional cloud condensation nuclei. The high AOD (average value 2.2 in Beijing during 12 to 20 June is partly explained by the hygroscopic growth of fine aerosol particles and by the strong absorption of internally mixed soot particles, both coming from regional ABB emissions. Therefore, it is important to consider the

  13. Effects of meteorology and secondary particle formation on visibility during heavy haze events in Beijing, China.

    Science.gov (United States)

    Zhang, Qiang; Quan, Jiannong; Tie, Xuexi; Li, Xia; Liu, Quan; Gao, Yang; Zhao, Delong

    2015-01-01

    The causes of haze formation in Beijing, China were analyzed based on a comprehensive measurement, including PBL (planetary boundary layer), aerosol composition and concentrations, and several important meteorological parameters such as visibility, RH (relative humidity), and wind speed/direction. The measurement was conducted in an urban location from Nov. 16, 2012 to Jan. 15, 2013. During the period, the visibility varied from >20 km to less than a kilometer, with a minimum visibility of 667 m, causing 16 haze occurrences. During the haze occurrences, the wind speeds were less than 1m/s, and the concentrations of PM2.5 (particle matter with radius less than 2.5 μm) were often exceeded 200 μg/m(3). The correlation between PM2.5 concentration and visibility under different RH values shows that visibility was exponentially decreased with the increase of PM2.5 concentrations when RH was less than 80%. However, when RH was higher than 80%, the relationship was no longer to follow the exponentially decreasing trend, and the visibility maintained in very low values, even with low PM2.5 concentrations. Under this condition, the hygroscopic growth of particles played important roles, and a large amount of water vapor acted as particle matter (PM) for the reduction of visibility. The variations of meteorological parameters (RH, PBL heights, and WS (wind speed)), chemical species in gas-phase (CO, O3, SO2, and NOx), and gas-phase to particle-phase conversions under different visibility ranges were analyzed. The results show that from high visibility (>20 km) to low visibility (<2 km), the averaged PBL decreased from 1.24 km to 0.53 km; wind speeds reduced from 1m/s to 0.5m/s; and CO increased from 0.5 ppmv to 4.0 ppmv, suggesting that weaker transport/diffusion caused the haze occurrences. This study also found that the formation of SPM (secondary particle matter) was accelerated in the haze events. The conversions between SO2 and SO4 as well as NOx to NO3(-) increased

  14. Satellite based classification (haze, fog) and affected area estimation over Indo - Pak Sub-Continent

    Science.gov (United States)

    Ghauri, Badar; Zafar, Sumaira

    2016-07-01

    Northern Pakistan and bordering Indian Punjab experience intense smog and fog during fall and winters. Environmentalists have been raising their voices over the situation and demanded control over regional emissions to save the livelihood of millions of dwellers whose trade, commerce and agriculture is at stake because of long smog/ fog spells.. This paper estimates the area affected by haze, smog and fog during 2006- 2010. MODIS (geo-referenced MODIS subsets India1, 2 &3) of the area in Pakistan and India from 2006 to 2010 for the period October to February) were analyzed using state of the art software ENVI 4.2 and ArcGIS 10.2. This process resulted in area belonging to each class that is; haze, smog and fog. On the basis of density, haze and fog cover was determined. Variations in fog cover, its density and identification of location of fog initiation process were also determined using near real time (30 minutes) METEOSAT-7 IODC data where actually fog formation started and then extended to the area of favorable conditions. Haze has been noticed to intensify due to massive burning of agricultural waste (rice husk) in India and Pakistan towards the end of October each year. MODIS thermal anomalies/fire data (MYD 14) were also used to verify this activity on the ground, which results in hazy conditions at regional level during fall months. Haze-affected area during 2006 to 2010 in Pakistan ranged from 155,000 Km2 to 354,000 Km2 and in India it ranged from 333,000 Km2 to 846,000 Km2. Similarly winter fog cover during this period in Pakistan varied from 136,000 Km2 to 381,000 Km2 and in India it was estimated at 327,000 Km2 to 566,000 Km2. This phenomenon was more prominent in India than in Pakistan where and fog cover was at least twice than that was observed in Pakistan. It has been noted that area covered by fog, smog and haze doubled during the study period in the region. Atmospheric dimming during autumn/ fall also reduces the mixing height leading to greater

  15. Blue Man袭东京

    Institute of Scientific and Technical Information of China (English)

    Naomi Saeki; 李宝怡

    2008-01-01

    <正>20年前在美国曼克顿风靡一时的Blue Man Group,最近在东京出现,马上成为城中话题。在东京,每年有不少舞台剧演出,但是像Blue Man Group这样备受注目的,近年罕见。Blue Man Group in Tokyo于上年12月开始公演·1个月的门票早在9月中旬

  16. Blue Angel for green electronics

    Energy Technology Data Exchange (ETDEWEB)

    Boettcher-Tiedemann, C.; Jacobs, B. [Federal Environmental Agency, Berlin (Germany)

    2004-07-01

    The Blue Angel was the first eco-label worldwide. It has been in existence for 26 years. For the last 12 years, modern electronic office and communications equipment has been among the products that are eligible for award of the Blue Angel. The Blue Angel eco-label is an important element of integrated product policy and is aimed towards environmentally sound product design. In addition, health aspects are increasingly being taken into account in criteria development. The use of the label gives innovative companies better market opportunities for products so labelled. For consumers and for purchasers in businesses and public administrations, it gives valuable guidance for product purchase. (orig.)

  17. 1 Mixing state and absorbing properties of black carbon during Arctic haze

    Science.gov (United States)

    Zanatta, Marco; Gysel, Martin; Eleftheriadis, Kosas; Laj, Paolo; Hans-Werner, Jacobi

    2016-04-01

    The Arctic atmosphere is periodically affected by the Arctic haze occurring in spring. One of its particulate components is the black carbon (BC), which is considered to be an important contributor to climate change in the Arctic region. Beside BC-cloud interaction and albedo reduction of snow, BC may influence Arctic climate interacting directly with the solar radiation, warming the corresponding aerosol layer (Flanner, 2013). Such warming depends on BC atmospheric burden and also on the efficiency of BC to absorb light, in fact the light absorption is enhanced by mixing of BC with other atmospheric non-absorbing materials (lensing effect) (Bond et al., 2013). The BC reaching the Arctic is evilly processed, due to long range transport. Aging promote internal mixing and thus absorption enhancement. Such modification of mixing and is quantification after long range transport have been observed in the Atlantic ocean (China et al., 2015) but never investigated in the Arctic. During field experiments conducted at the Zeppelin research site in Svalbard during the 2012 Arctic spring, we investigated the relative precision of different BC measuring techniques; a single particle soot photometer was then used to assess the coating of Arctic black carbon. This allowed quantifying the absorption enhancement induced by internal mixing via optical modelling; the optical assessment of aged black carbon in the arctic will be of major interest for future radiative forcing assessment.Optical characterization of the total aerosol indicated that in 2012 no extreme smoke events took place and that the aerosol population was dominated by fine and non-absorbing particles. Low mean concentration of rBC was found (30 ng m-3), with a mean mass equivalent diameter above 200 nm. rBC concentration detected with the continuous soot monitoring system and the single particle soot photometer was agreeing within 15%. Combining absorption coefficient observed with an aethalometer and rBC mass

  18. Leaf Positioning of Arabidopsis in Response to Blue Light

    Institute of Scientific and Technical Information of China (English)

    Shin-ichiro Inoue; Toshinori Kinoshita; Atsushi Takemiya; Michio Doi; Ken-ichiro Shimazaki

    2008-01-01

    Appropriate leaf positioning is essential for optimizing photosynthesis and plant growth. However, it has not been elucidated how green leaves reach and maintain their position for capturing light. We show here the regulation of leaf positioning under blue light stimuli. When 1-week-old Arabidopsis seedlings grown under white light were transferred to red light (25 μmol m-2s-t) for 5 d, new petioles that appeared were almost horizontal and their leaves were curled and slanted downward. However, when a weak blue light from above (0.1 μmol m-2s-1) was superimposed on red light, the new petioles grew obliquely upward and the leaves were flat and horizontal. The leaf positioning required both phototropin1 (phot1) and nonphototropic hypocotyl 3 (NPH3), and resulted in enhanced plant growth. In an nph3 mutant, neither optimal leaf positioning nor leaf flattening by blue light was found, and blue light-induced growth enhancement was drastically reduced. When blue light was increased from 0.1 to 5 μmol m-2s-1, normal leaf positioning and leaf flattening were induced in both phot1 and nph3 mutants, suggesting that phot2 signaling became functional and that the signaling was independent of phot1 and NPH3 in these responses. When plants were irradiated with blue light (0.1 μmol m-2s-1) from the side and red light from above, the new leaves became oriented toward the source of blue light. When we transferred these plants to both blue light and red light from above, the leaf surface changed its orientation to the new blue light source within a few hours, whereas the petioles initially were unchanged but then gradually rotated, suggesting the plasticity of leaf positioning in response to blue light. We showed the tissue expression of NPH3 and its plasma membrane localization via the coiled-coil domain and the C-terminal region. We conclude that NPH3-mediated phototropin signaling optimizes the efficiency of light perception by inducing both optimal leaf positioning and leaf

  19. Blue-green photoluminescence in MCM-41 mesoporous nanotubes

    CERN Document Server

    Shen, J L; Lui, Y L; Cheng, P W; Cheng, C F

    2003-01-01

    Different photoluminescence (PL) techniques have been used to study the blue-green emission from siliceous MCM-41 nanotubes. It was found that the intensity of the blue-green PL is enhanced by rapid thermal annealing (RTA). This enhancement is explained by the generation of twofold-coordinated Si centres and non-bridging oxygen hole centres, in line with the surface properties of MCM-41. On the basis of the analysis of the PL following RTA, polarized PL, and PL excitation, we suggest that the triplet-to-singlet transition of twofold-coordinated silicon centres is responsible for the blue-green PL in MCM-41 nanotubes. (letter to the editor)

  20. Tourists’ Perception of Haze Pollution and the Potential Impacts on Travel: Reshaping the Features of Tourism Seasonality in Beijing, China

    Directory of Open Access Journals (Sweden)

    Aiping Zhang

    2015-02-01

    Full Text Available Haze pollution has worsened and has received close attention by news agencies in the past two years. This type of environmental pollution might have a great effect on tourism image and the entire tourism industry of a destination. This study aimed to reveal the potential impacts of haze pollution on the tourism industry. Based on a case study in Beijing using questionnaires for potential tourists, awareness of haze pollution, impacts of haze pollution on travel and attitudes toward the impacts were discussed. The results indicated that haze pollution has a considerable potential impact on travel, and there are distinct differences among travel elements and tourism market segments. Due to its impacts, haze pollution could be taken into account in tourists’ decision-making processes, causing a portion of potential tourists to cancel tourism plans. As a result, tourist arrivals to similar destinations could decrease by a small margin, but the most significant impact could be on the temporal distribution of tourist arrivals, namely tourism seasonality, due to tourists’ “avoiding” psychology.

  1. Ecology of blue straggler stars

    CERN Document Server

    Carraro, Giovanni; Beccari, Giacomo

    2015-01-01

    The existence of blue straggler stars, which appear younger, hotter, and more massive than their siblings, is at odds with a simple picture of stellar evolution. Such stars should have exhausted their nuclear fuel and evolved long ago to become cooling white dwarfs. They are found to exist in globular clusters, open clusters, dwarf spheroidal galaxies of the Local Group, OB associations and as field stars. This book summarises the many advances in observational and theoretical work dedicated to blue straggler stars. Carefully edited extended contributions by well-known experts in the field cover all the relevant aspects of blue straggler stars research: Observations of blue straggler stars in their various environments; Binary stars and formation channels; Dynamics of globular clusters; Interpretation of observational data and comparison with models. The book also offers an introductory chapter on stellar evolution written by the editors of the book.

  2. Karner Blue Butterfly Recovery Plan

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This recovery plan has been prepared by the Karner Blue Butterfly Recovery Team under the leadership of Dr. David Andow, University of Minnesota-St. Paul. Dr. John...

  3. China Mobile: Expanding "Blue Ocean"

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Driving force is crucial for realizing high-speed growth. The strong driving force from "Blue Ocean Strategy" is an important advantage for China Mobile to realize harmonious and leap-forward development.

  4. Blue Ocean vs. Five Forces

    OpenAIRE

    Burke, Andrew; Stel, André; Thurik, Roy

    2010-01-01

    textabstractThe article reports on the authors' research in the Netherlands which focused on a profit model in Dutch retail stores and a so-called blue-ocean approach which requires a new market that attracts consumers and increases profits. Topics include the competitive strategy approach to increasing profits. The authors conclude that the blue-ocean strategy or innovation approach is sustainable.

  5. Biomass burning as the main source of organic aerosol particulate matter in Malaysia during haze episodes.

    Science.gov (United States)

    Radzi bin Abas, M; Oros, Daniel R; Simoneit, B R T

    2004-05-01

    The haze episodes that occurred in Malaysia in September-October 1991, August-October 1994 and September-October 1997 have been attributed to suspended smoke particulate matter from biomass burning in southern Sumatra and Kalimantan, Indonesia. In the present study, polar organic compounds in aerosol particulate matter from Malaysia are converted to their trimethylsilyl derivatives and analyzed by gas chromatography-mass spectrometry in order to better assess the contribution of the biomass burning component during the haze episodes. On the basis of this analysis, levoglucosan was found to be the most abundant organic compound detected in almost all samples. The monosaccharides, alpha- and beta-mannose, the lignin breakdown products, vanillic and syringic acids and the minor steroids, cholesterol and beta-sitosterol were also present in some samples. The presence of the tracers from smoke overwhelmed the typical signatures of emissions from traffic and other anthropogenic activities in the urban areas.

  6. Biomass burning as the main source of organic aerosol particulate matter in Malaysia during haze episodes

    Energy Technology Data Exchange (ETDEWEB)

    Abas, M. Radzi bin [Malaya Univ., Dept. of Chemistry, Kuala Lumpur (Malaysia); Oros, Daniel R.; Simoneit, B.R.T. [Oregon State Univ., Environmental and Petroleum Geochemistry Group, Corvallis, OR (United States)

    2004-05-01

    The haze episodes that occurred in Malaysia in September-October 1991, August-October 1994 and September-October 1997 have been attributed to suspended smoke particulate matter from biomass burning in southern Sumatra and Kalimantan, Indonesia. In the present study, polar organic compounds in aerosol particulate matter from Malaysia are converted to their trimethylsilyl derivatives and analyzed by gas chromatography-mass spectrometry in order to better assess the contribution of the biomass burning component during the haze episodes. On the basis of this analysis, levoglucosan was found to be the most abundant organic compound detected in almost all samples. The monosaccharides, {alpha}- and {beta}-mannose, the lignin breakdown products, vanillic and syringic acids and the minor steroids, cholesterol and {beta}-sitosterol were also present in some samples. The presence of the tracers from smoke overwhelmed the typical signatures of emissions from traffic and other anthropogenic activities in the urban areas. (Author)

  7. Rationale for Haze Formation after Carboxymethyl Cellulose (CMC) Addition to Red Wine.

    Science.gov (United States)

    Sommer, Stephan; Dickescheid, Christian; Harbertson, James F; Fischer, Ulrich; Cohen, Seth D

    2016-09-14

    The aim of this study was to identify the source of haze formation in red wine after the addition of carboxymethyl cellulose (CMC) and to characterize the dynamics of precipitation. Ninety commercial wines representing eight grape varieties were collected, tested with two commercial CMC products, and analyzed for susceptibility to haze formation. Seventy-four of these wines showed a precipitation within 14 days independent of the CMC product used. The precipitates of four representative samples were further analyzed for elemental composition (CHNS analysis) and solubility under different conditions to determine the nature of the solids. All of the precipitates were composed of approximately 50% proteins and 50% CMC and polyphenols. It was determined that the interactions between CMC and bovine serum albumin are pH dependent in wine-like model solution. Furthermore, it was found that the color loss associated with CMC additions required the presence of proteins and cannot be observed with CMC and anthocyanins alone. PMID:27571332

  8. Rationale for Haze Formation after Carboxymethyl Cellulose (CMC) Addition to Red Wine.

    Science.gov (United States)

    Sommer, Stephan; Dickescheid, Christian; Harbertson, James F; Fischer, Ulrich; Cohen, Seth D

    2016-09-14

    The aim of this study was to identify the source of haze formation in red wine after the addition of carboxymethyl cellulose (CMC) and to characterize the dynamics of precipitation. Ninety commercial wines representing eight grape varieties were collected, tested with two commercial CMC products, and analyzed for susceptibility to haze formation. Seventy-four of these wines showed a precipitation within 14 days independent of the CMC product used. The precipitates of four representative samples were further analyzed for elemental composition (CHNS analysis) and solubility under different conditions to determine the nature of the solids. All of the precipitates were composed of approximately 50% proteins and 50% CMC and polyphenols. It was determined that the interactions between CMC and bovine serum albumin are pH dependent in wine-like model solution. Furthermore, it was found that the color loss associated with CMC additions required the presence of proteins and cannot be observed with CMC and anthocyanins alone.

  9. Highly transparent, low-haze, hybrid cellulose nanopaper as electrodes for flexible electronics

    Science.gov (United States)

    Xu, Xuezhu; Zhou, Jian; Jiang, Long; Lubineau, Gilles; Ng, Tienkhee; Ooi, Boon S.; Liao, Hsien-Yu; Shen, Chao; Chen, Long; Zhu, J. Y.

    2016-06-01

    Paper is an excellent candidate to replace plastics as a substrate for flexible electronics due to its low cost, renewability and flexibility. Cellulose nanopaper (CNP), a new type of paper made of nanosized cellulose fibers, is a promising substrate material for transparent and flexible electrodes due to its potentially high transparency and high mechanical strength. Although CNP substrates can achieve high transparency, they are still characterized by high diffuse transmittance and small direct transmittance, resulting in high optical haze of the substrates. In this study, we proposed a simple methodology for large-scale production of high-transparency, low-haze CNP comprising both long cellulose nanofibrils (CNFs) and short cellulose nanocrystals (CNCs). By varying the CNC/CNF ratio in the hybrid CNP, we could tailor its total transmittance, direct transmittance and diffuse transmittance. By increasing the CNC content, the optical haze of the hybrid CNP could be decreased and its transparency could be increased. The direct transmittance and optical haze of the CNP were 75.1% and 10.0%, respectively, greatly improved from the values of previously reported CNP (31.1% and 62.0%, respectively). Transparent, flexible electrodes were fabricated by coating the hybrid CNP with silver nanowires (AgNWs). The electrodes showed a low sheet resistance (minimum 1.2 Ω sq-1) and a high total transmittance (maximum of 82.5%). The electrodes were used to make a light emitting diode (LED) assembly to demonstrate their potential use in flexible displays.Paper is an excellent candidate to replace plastics as a substrate for flexible electronics due to its low cost, renewability and flexibility. Cellulose nanopaper (CNP), a new type of paper made of nanosized cellulose fibers, is a promising substrate material for transparent and flexible electrodes due to its potentially high transparency and high mechanical strength. Although CNP substrates can achieve high transparency, they are

  10. Trans-Boundary Haze Pollution in Southeast Asia: Sustainability through Plural Environmental Governance

    Directory of Open Access Journals (Sweden)

    Md Saidul Islam

    2016-05-01

    Full Text Available Recurrent haze in Southeast Asian countries including Singapore is largely attributable to rampant forest fires in Indonesia due to, for example, extensive slash-and-burn (S & B culture. Drawing on the “treadmill of production” and environmental governance approach, we examine causes and consequences of this culture. We found that, despite some perceived benefits, its environmental consequences include deforestation, soil erosion and degradation, global warming, threats to biodiversity, and trans-boundary haze pollution, while the societal consequences comprise regional tension, health risks, economic and productivity losses, as well as food insecurity. We propose sustainability through a plural coexistence framework of governance for targeting S & B that incorporates strategies of incentives, education and community resource management.

  11. Direct observations of organic aerosols in common wintertime hazes in North China: insights into their size, shape, mixing state, and source

    OpenAIRE

    Chen, S. R.; Xu, L.; Zhang, Y X; Chen, B; Wang, X F; X. Y. Zhang; Zheng, M; Chen, J. M.; Wang, W. X.; Sun, Y L; P. Q. Fu; Z. F. Wang; Li, W. J.

    2016-01-01

    Many studies have focused on the physicochemical properties of aerosol particles in unusually severe haze episodes instead of the more freqent and less severe hazes. Consistent with this lack of attention, the morphology and mixing state of organic matter (OM) particles in the frequent light and moderate (L&M) hazes in winter in North China Plain (NCP) have not been examined, even though OM dominates these fine particles. In the present work, morphology, mixing state, and size of organic aero...

  12. After Indonesia’s Ratification: The ASEAN Agreement on Transboundary Haze Pollution and Its Effectiveness As a Regional Environmental Governance Tool

    OpenAIRE

    Daniel Heilmann

    2015-01-01

    On 20 January 2015 Indonesia deposited its instrument of ratification for the ASEAN Agreement on Transboundary Haze Pollution with the ASEAN Secretariat, becoming the last ASEAN member state to join the treaty. Haze pollution poses a serious health threat to the people of Indonesia, Singapore and Malaysia, and for decades haze pollution has been a highly contentious issue among ASEAN member states. This article argues that Indonesia's ratification will not be an immediate game changer. The me...

  13. Nile Blue derivatives as lysosomotropic photosensitizers

    Science.gov (United States)

    Lin, Chi-Wei; Shulok, Janine R.; Kirley, S. D.; Cincotta, Louis; Foley, James W.

    1991-06-01

    The benzophenoxazines, including several Nile blue analogues, are a unique group of dyes that localize selectively in animal tumors. Chemical modifications of Nile blue A can yield derivatives with high 1O2 quantum yields. These derivatives represent a group of potentially effective photosensitizers for selective phototherapy of malignant tumors. In vitro evaluation of these derivatives has indicated that those with high 1O2 yields are very effective in mediating the photocytotoxicity of tumor cells. This photodynamic effect is most likely mediated through the action of 1O2, since photoirradiation under D2O enhanced and under hypoxic conditions diminished the photocytotoxic action. The subcellular localization of these photosensitizers in bladder tumor cells in culture was examined by light and fluorescence microscopies as well as by histochemical and biochemical studies. The results indicate that these dyes are localized primarily in the lysosome. The cellular uptake and retention of these dyes is energy- and pH-dependent. Agents such as nigericin, which alter the transmembrane pH gradient, reduced uptake and enhanced efflux of the dyes, while agents such as valinomycin, which reduce cellular membrane potential, had no effect on the uptake. These findings are consistent with having ion-trapping as the mechanism for the uptake of these dyes. Photoirradiation of sensitizer-treated cells obliterated lysosomes in a light-dose and drug-dose dependent fashion. Release of the hydrolytic enzymes may be the main cause for subsequent cell death since the cytolytic effect was reduced by a specific inhibitor of lysosomal proteolytic enzyme. A lysosomotropic photosensitization mechanism is therefore proposed for the photocytotoxic action of the Nile blue derivatives. This mechanism may provide an approach to the development of new photosensitizers for the effective and selective destruction of malignant tumors.

  14. 江苏霾灾害风险与地区差异研究%STUDY OF HAZE RISK AND THE DIFFERENCE OF HAZE AMONG ALL AREAS IN JIANGSU

    Institute of Scientific and Technical Information of China (English)

    田心如; 陈广昌; 武艳; 王伟丽

    2014-01-01

    利用江苏省69个地面气象观测站1980~2012年的气象资料,采用适当的方法定义了霾时概念,讨论了重度、中度、轻度及轻微霾时数的时空分布特征.根据霾灾害特点,以区县为评估单元,综合考虑了致灾因子危险性、孕灾环境敏感性、承载体易损性和防灾减灾能力4个因素,选取中度霾时数、重度霾时数、水域面积、植被面积、人口密度、公路里程、公共财政支出、每万人拥有医生数等8个因子作为评估的主要指标,利用层次分析法建立霾灾害风险评估模型,并借助于GIS分析工具,进行了霾灾害风险区划.%Based on the data collected from 69 surface observation stations during 1961-2012 in Jiangsu province,using proper measures to define the concept of haze hours,the temporal and spatial distribution features of severe,moderate,mild and slight haze hours are discussed in the research.According to the characteristics of haze disasters,the administrative regions (districts and counties) are taken as the basic evaluation unit,considering four factors such as the hazard risk,disaster pregnant environment sensitivity,vulnerability and disaster prevention and reduction capacity.This study selects eight factors including the moderate haze hours,severe haze hours,water area,vegetation area,population density,road mileage,public finance expenditure,the number of doctors per million people possessing as the evaluation indexes,uses the analytic hierarchy process to establish a risk assessment model,and with the help of GIS analysis tool,the haze disaster risk regionalization is given.The research shows that the slight haze is the most haze weather in Jiangsu province,with proportion of 77% in all haze weather.The frequency of severe and moderate haze weather is lower,with proportion of 2% and 4% respectively.The trend of annual haze hours of every grade is identical,rising slightly during 1980-2010,and obviously during 2011-2012.The

  15. Trans-Boundary Haze Pollution in Southeast Asia: Sustainability through Plural Environmental Governance

    OpenAIRE

    Md. Saidul Islam; Yap Hui Pei; Shrutika Mangharam

    2016-01-01

    Recurrent haze in Southeast Asian countries including Singapore is largely attributable to rampant forest fires in Indonesia due to, for example, extensive slash-and-burn (S & B) culture. Drawing on the “treadmill of production” and environmental governance approach, we examine causes and consequences of this culture. We found that, despite some perceived benefits, its environmental consequences include deforestation, soil erosion and degradation, global warming, threats to biodiversity, ...

  16. Characteristics of aerosol pollution during heavy haze events in Suzhou, China

    OpenAIRE

    Tian, Mi; Wang, Huanbo; Chen, Yang; Yang, Fumo; Zhang, Xiaohua; Zou, Qiang; Zhang, Renquan; Ma, Yongliang; He, Kebin

    2016-01-01

    Extremely severe haze weather events occurred in many cities in China, especially in the east part of the country, in January 2013. Comprehensive measurements including hourly concentrations of PM2.5 and its major chemical components (water-soluble inorganic ions, organic carbon (OC), and elemental carbon (EC)) and related gas-phase precursors were conducted via an online monitoring system in Suzhou, a medium-sized city in Jiangsu province, just east of Shanghai. PM2.5 (part...

  17. Public concerns about transboundary haze: a comparison of Indonesia, Singapore, and Malaysia

    OpenAIRE

    Forsyth, Tim

    2014-01-01

    Public concerns about environmental problems create narrative structures that influence policy by allocating roles of blame, responsibility, and appropriate behavior. This paper presents an analysis of public concerns about transboundary haze resulting from forest fires in Indonesia, Singapore, and Malaysia for crises experienced in 1997, 2005 and 2013. The source of the information is content analysis of 2231 articles from representative newspapers in each country. The study shows that newsp...

  18. [Characteristics of mass size distributions of water-soluble, inorganic ions during summer and winter haze days of Beijing].

    Science.gov (United States)

    Huang, Yi-Min; Liu, Zi-Rui; Chen, Hong; Wang, Yue-Si

    2013-04-01

    To investigate the size distribution characteristics of water soluble inorganic ions in haze days, the particle samples were collected by two Andersen cascade impactors in Beijing during summer and winter time and each sampling period lasted two weeks. Online measurement of PM10 and PM2.5 using TEOM were also conducted at the same time. Sources and formation mechanism of water soluble inorganic ions were analyzed based on their size distributions. The results showed that average concentrations of PM10 and PM 2.5 were (245.5 +/- 8.4) microg x m(-3) and (120.2 +/- 2.0) microg x m(-3) during summer haze days (SHD), and were (384.2 +/- 30.2) microg x m(-3) and (252.7 +/- 47.1) microg x m(-3) during winter haze days (WHD), which suggested fine particles predominated haze pollution episode in both seasons. Total water-soluble inorganic ions concentrations were higher in haze days than those in non-haze days, especially in fine particles. Furthermore, concentrations of secondary inorganic ions (SO4(2-), NO3(-) and NH4(+)) increased quicker than other inorganic ions in fine particles during haze days, indicating secondary inorganic ions played an important role in the formation of haze pollution. Similar size distributions were found for all Sinorganic water soluble ions except for NO3(-), during SHD and WHD. SO4(2-) and NH4(+) dominated in the fine mode (PM1.0) while Mg2+ and Ca2+ accumulated in coarse fraction, Na+, Cl- and K+ showed a bimodal distribution. For NO3(-), however, it showed a bimodal distribution during SHD and a unimodal distribution dominated in the fine fraction was found during WHD. The average mass median aerodynamic diameter (MMAD) of SO4(2-) was 0.64 microm in SHD, which suggested the formation of SO4(2-) was mainly attributed to in-cloud processes. Furthermore, a higher apparent conversion rate of sulfur dioxide (SOR) was found in SHD, indicating more fine particles were produced by photochemical reaction in haze days than that in non-haze days. The

  19. Long-term trend and spatiotemporal variations of haze over China by satellite observations from 1979 to 2013

    Science.gov (United States)

    Zhang, Xingying; Wang, Ling; Wang, Weihe; Cao, Dongjie; Wang, Xi; Ye, Dianxiu

    2015-10-01

    With the fast development of economy and industry in the past thirty years, many large cities in the eastern and southwestern areas of China are experiencing increased haze events and atmospheric pollution, which causes significant impacts on the regional environment, human health, and even climate. The long-term trend and spatiotemporal variations of haze over China during recent 30 years are investigated using TOMS AAI products. In addition, the heavy haze events that occurred in January 2013 over eastern China are explored using AAI products from TOU on board FY-3A. Validation results show that satellite AAI products can be used for haze monitoring since it is sensitive to the carbonaceous aerosol, which is one of the main components of haze. In China, the high AAI values (>1.0) mainly located in the main four areas with intense anthropogenic activities, except for the desert region in Northwestern China. In the eastern and northeastern region, AAI peaks dominate in spring before 2005 since those areas were always affected by dust in spring. However, after 2005, AAI peaks appear in winter over eastern China because of haze. Moreover, in the northeastern region, AAI peaks dominate in winter with a secondary peak in spring because this area is affected by both dust and haze. In the southern region, the AAI peaks always dominate in spring since the high-level air pollution often occur in spring, but a decreasing trend is acquired during recent ten years. Over eastern China and northeastern China, AAI shows an increasing trend during recent 30 years in winter, which reveals that the haze over these areas is strengthen. A case study result shows that the heavy haze events occurred in January 2013 in eastern China can be clearly identified from the AAI products of TOU/FY-3A. The daily coverage area with AAI > 3.0 peaks at five periods at this time, i.e. Jan. 7-8, Jan. 13, Jan. 18, Jan. 23, and, Jan. 28-29, which agrees well with the haze events recorded by in

  20. Titan's 2 micron Surface Albedo and Haze Optical Depth in 1996-2004

    Energy Technology Data Exchange (ETDEWEB)

    Gibbard, S; de Pater, I; Macintosh, B; Roe, H; Max, C; Young, E; McKay, C

    2004-05-04

    We observed Titan in 1996-2004 with high-resolution 2 {micro}m speckle and adaptive optics imaging at the W.M. Keck Observatory. By observing in a 2 {micro}m broadband filter we obtain images that have contributions from both Titan's surface and atmosphere. We have modeled Titan's atmosphere using a plane-parallel radiative transfer code that has been corrected to agree with 3-D Monte Carlo predictions. We find that Titan's surface albedo ranges from {le} 0:02 in the darkest equatorial region of the trailing hemisphere to {approx_equal} 0:1 in the brightest areas of the leading hemisphere. Over the past quarter of a Saturnian year haze optical depth in Titan's Southern hemisphere has decreased substantially from a value of 0.48 in 1996 down to 0.18 in 2004, while the northern haze has been increasing over the past few years. As a result of these changes, in 2004 the North/South haze asymmetry at K' band has disappeared.

  1. Impact of the June 2013 Riau province Sumatera smoke haze event on regional air pollution

    Science.gov (United States)

    Dewi Ayu Kusumaningtyas, Sheila; Aldrian, Edvin

    2016-07-01

    Forest and land fires in Riau province of Sumatera increase along with the rapid deforestation, land clearing, and are induced by dry climate. Forest and land fires, which occur routinely every year, cause trans-boundary air pollution up to Singapore. Economic losses were felt by Indonesia and Singapore as the affected country thus creates tensions among neighboring countries. A high concentration of aerosols are emitted from fire which degrade the local air quality and reduce visibility. This study aimed to analyze the impact of the June 2013 smoke haze event on the environment and air quality both in Riau and Singapore as well as to characterize the aerosol properties in Singapore during the fire period. Air quality parameters combine with aerosols from Aerosol Robotic Network (AERONET) data and some environmental parameters, i.e. rainfall, visibility, and hotspot numbers are investigated. There are significant relationships between aerosol and environmental parameters both in Riau and Singapore. From Hysplit modeling and a day lag correlation, smoke haze in Singapore is traced back to fire locations in Riau province after propagated one day. Aerosol characterization through aerosol optical depth (AOD), Ångstrom parameter and particle size distribution indicate the presence of fine aerosols in a great number in Singapore, which is characteristic of biomass burning aerosols. Fire and smoke haze even impaired economic activity both in Riau and Singapore, thus leaving some accounted economic losses as reported by some agencies.

  2. Protein/polysaccharide interactions and their impact on haze formation in white wines.

    Science.gov (United States)

    Dufrechou, Marie; Doco, Thierry; Poncet-Legrand, Céline; Sauvage, François-Xavier; Vernhet, Aude

    2015-11-18

    Proteins in white wines may aggregate and form hazes at room temperature. This was previously shown to be related to pH-induced conformational changes and to occur for pH wine polysaccharides on pH-induced haze formation by proteins but also the consequences of their interactions with these proteins on the colloidal stability of white wines. To this end, model systems and purified global pools of wine proteins and polysaccharides were used first. Kinetics of aggregation, proteins involved, and turbidities related to final hazes were monitored. To further identify the impact of each polysaccharide, fractions purified to homogeneity were used in a second phase. These included two neutral (mannoprotein and arabinogalactan) and two negatively charged (rhamnogalacturonan II dimer (RG-II) and arabinogalactan) polysaccharides. The impact of major wine polysaccharides on wine protein aggregation at room temperature was clearly less marked than those of the pH and the ionic strength. Polysaccharides modulated the aggregation kinetics and final haziness, indicating that they interfere with the aggregation process, but could not prevent it.

  3. Insights into a historic severe haze event in Shanghai: synoptic situation, boundary layer and pollutants

    Science.gov (United States)

    Leng, Chunpeng; Duan, Junyan; Xu, Chen; Zhang, Hefeng; Wang, Yifan; Wang, Yanyu; Li, Xiang; Kong, Lingdong; Tao, Jun; Zhang, Renjian; Cheng, Tiantao; Zha, Shuping; Yu, Xingna

    2016-07-01

    A historic haze event, characterized by lengthy, large-scale and severe pollution, occurred in the Yangtze River Delta (YRD) of China from 1 to 10 December 2013. This haze event significantly influenced air quality throughout the region, especially in urban areas. Aerosol physical, chemical and optical properties were measured in Shanghai. Sometimes the 1 h average particle concentration (e.g., PM2.5) exceeded 600 µg m-3. Inorganic water-soluble ions in particles, trace gases and aerosol optical coefficients had a similar tendency to increase evidently from clear to hazy episodes. A combination of various factors contributed to the formation and evolution of the haze event, among which meteorological conditions, local anthropogenic emissions and pollutants are the major factors. High pressure system, calm surface wind and subsidence airflow were responsible for the decrease of planetary boundary layer (PBL) and the accumulation of pollutants. Atmospheric visibility correlated strongly with relative humidity (RH), particle number in size of 600-1400 nm other than particulate water-soluble species and particle mass (PM2.5). The particle hygroscopicity plays an important role in atmospheric visibility reduction. The results are somewhat helpful to forecast and eliminate regional atmospheric pollution in China.

  4. Scattering properties of the heterogeneous and non-spherical haze particles in the SWIR band

    International Nuclear Information System (INIS)

    To effectively estimate the influence of multiple scattering caused by haze particles on the misestimating of CO2 concentrations, it is necessary to understand the scattering properties of haze particles in the shortwave infrared (SWIR) wavelength range (∼1.6um) using satellite data. Due to the complexity of structures and components of haze particles, this paper investigates effects of particle size and chemical component on the scattering properties of both single non-spherical particles and aggregates for the 1.6um by using numerically effective medium theory and core-mantle theory. For the single non-spherical particles, the scattering parameters (e.g. scattering phase function, single scattering albedo, extinction coefficient and scattering coefficient) are calculated by combining the T-matrix method and the Maxwell-Garnett effective medium theory. For the aggregates, the particle-cluster aggregation algorithm is used to generate aggregates with different monomer numbers. And then, the Core-Mantle Generalized Multi-particle Mie (CMGMM) method is used to compute the scattering parameters. The results indicate that the scattering characteristics are significantly different for both single non-spherical particles and aggregates

  5. On the latitudinal distribution of Titan's haze at the Voyager epoch

    Science.gov (United States)

    Negrao, A.; Roos-Serote, M.; Rannou, P.; Rages, K.; McKay, C.

    2002-09-01

    In this work, we re-analyse a total of 10 high phase angle images of Titan (2 from Voyager 1 and 8 from Voyager 2). The images were acquired in different filters of the Voyager Imaging Sub System in 1980 - 1981. We apply a model, developed and used by Rannou etal. (1997) and Cabane etal. (1992), that calculates the vertical (1-D) distribution of haze particles and the I/F radial profiles as a function of a series of parameters. Two of these parameters, the haze particle production rate (P) and imaginary refractive index (xk), are used to obtain fits to the observed I/F profiles at different latitudes. Differerent from previous studies is that we consider all filters simultaneously, in an attempt to better fix the parameter values. We also include the filter response functions, not considered previously. The results show that P does not change significantly as a function of latitude, eventhough somewhat lower values are found at high northern latitudes. xk seems to increase towards southern latitudes. We will compare our results with GCM runs, that can give the haze distribution at the epoch of the observations. Work financed by portuguese Foundation for Science and Tecnology (FCT), contract ESO/PRO/40157/2000

  6. Net effect of wort osmotic pressure on fermentation course, yeast vitality, beer flavor, and haze.

    Science.gov (United States)

    Sigler, K; Matoulková, D; Dienstbier, M; Gabriel, P

    2009-04-01

    The net effect of increased wort osmolarity on fermentation time, bottom yeast vitality and sedimentation, beer flavor compounds, and haze was determined in fermentations with 12 degrees all-malt wort supplemented with sorbitol to reach osmolarity equal to 16 degrees and 20 degrees. Three pitchings were performed in 12 degrees/12 degrees/12 degrees, 16 degrees/16 degrees/12 degrees, and 20 degrees/20 degrees/12 degrees worts. Fermentations in 16 degrees and 20 degrees worts decreased yeast vitality measured as acidification power (AP) by a maximum of 10%, lowered yeast proliferation, and increased fermentation time. Repitching aggravated these effects. The 3rd "back to normal" pitching into 12 degrees wort restored the yeast AP and reproductive abilities while the extended fermentation time remained. Yeast sedimentation in 16 degrees and 20 degrees worts was delayed but increased about two times at fermentation end relative to that in 12 degrees wort. Third "back-to-normal" pitching abolished the delay in sedimentation and reduced its extent, which became nearly equal in all variants. Beer brewed at increased osmolarity was characterized by increased levels of diacetyl and pentanedione and lower levels of dimethylsulfide and acetaldehyde. Esters and higher alcohols displayed small variations irrespective of wort osmolarity or repitching. Increased wort osmolarity had no appreciable effect on the haze of green beer and accelerated beer clarification during maturation. In all variants, chill haze increased with repitching. PMID:19122996

  7. Regional contribution to PM1 pollution during winter haze in Yangtze River Delta, China.

    Science.gov (United States)

    Tang, Lili; Yu, Hongxia; Ding, Aijun; Zhang, Yunjiang; Qin, Wei; Wang, Zhuang; Chen, Wentai; Hua, Yan; Yang, Xiaoxiao

    2016-01-15

    To quantify regional sources contributing to submicron particulate matter (PM1) pollution in haze episodes, on-line measurements combining two modeling methods, namely, positive matrix factorization (PMF) and backward Lagrangian particle dispersion modeling (LPDM), were conducted for the period of one month in urban Nanjing, a city located in the western part of Yangtze River Delta (YRD) region of China. Several multi-day haze episodes were observed in December 2013. Long-range transport of biomass burning from the southwestern YRD region largely contributed to PM1 pollution with more than 25% of total organics mass in a lasting heavy haze. The LPDM analysis indicates that regional transport is a main source contributing to secondary low-volatility production. The high-potential source regions of secondary low-volatility production are mainly located in areas to the northeast of the city. High aerosol pollution was mainly contributed by regional transport associated with northeastern air masses. Such regional transport on average accounts for 46% of total NR-PM1 with sulfate and aged low-volatility organics being the largest fractions (>65%).

  8. The rural carbonaceous aerosols in coarse, fine, and ultrafine particles during haze pollution in northwestern China.

    Science.gov (United States)

    Zhu, Chong-Shu; Cao, Jun-Ji; Tsai, Chuen-Jinn; Shen, Zhen-Xing; Liu, Sui-Xin; Huang, Ru-Jin; Zhang, Ning-ning; Wang, Ping

    2016-03-01

    The carbonaceous aerosol concentrations in coarse particle (PM10: Dp ≤ 10 μm, particulate matter with an aerodynamic diameter less than 10 μm), fine particle (PM2.5: Dp ≤ 2.5 μm), and ultrafine particle (PM0.133: Dp ≤ 0.133 μm) carbon fractions in a rural area were investigated during haze events in northwestern China. The results indicated that PM2.5 contributed a large fraction in PM10. OC (organic carbon) accounted for 33, 41, and 62 % of PM10, PM2.5, and PM0.133, and those were 2, 2.4, and 0.4 % for EC (elemental carbon) in a rural area, respectively. OC3 was more abundant than other organic carbon fractions in three PMs, and char dominated EC in PM10 and PM2.5 while soot dominated EC in PM0.133. The present study inferred that K(+), OP, and OC3 are good biomass burning tracers for rural PM10 and PM2.5, but not for PM0.133 during haze pollution. Our results suggest that biomass burning is likely to be an important contributor to rural PMs in northwestern China. It is necessary to establish biomass burning control policies for the mitigation of severe haze pollution in a rural area.

  9. Effect of onion extract on corneal haze suppression after air assisted lamellar keratectomy.

    Science.gov (United States)

    Kim, Soohyun; Park, Young Woo; Lee, Euiri; Park, Sang Wan; Park, Sungwon; Noh, Hyunwoo; Kim, Jong Whi; Seong, Je Kyung; Seo, Kangmoon

    2016-03-01

    This study evaluated the effect of onion extract on corneal haze suppression after applying the air assisted lamellar keratectomy. The air assisted lamellar keratectomy was performed on 24 canine eyes. They were treated with an artificial tear (group C), prednisolone acetate (group P), onion extract (group O) and TGF-β1 (group T) three times per day from 7 to 28 days after the surgery. Corneal haze occurred on the all eyes and was observed beginning 7 days after the surgery. The haze was significantly decreased in groups P and O from day 14 compared with the group C using the clinical (group P; P=0.021, group O; P=0.037) and objective evaluation method (group P; P=0.021, group O; P=0.039). In contrast, it was significantly increased in group T from day 14 compared with group C based on the clinical (P=0.002) and objective evaluation method (Phaze development by suppressing the differentiation of fibroblasts into myofibroblasts.

  10. SEASONAL DISAPPEARANCE OF FAR-INFRARED HAZE IN TITAN'S STRATOSPHERE

    Energy Technology Data Exchange (ETDEWEB)

    Jennings, Donald E.; Anderson, C. M.; Flasar, F. M.; Cottini, V. [Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Samuelson, R. E.; Nixon, C. A.; Kunde, V. G.; Achterberg, R. K. [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); De Kok, R. [SRON Netherlands Institute for Space Research, Sorbonnelaan 2, 3584 CA Utrecht (Netherlands); Coustenis, A.; Vinatier, S. [LESIA, Observatoire de Paris-Meudon, 92195 Meudon Cedex (France); Calcutt, S. B., E-mail: donald.e.jennings@nasa.gov [Department of Physics, University of Oxford, Parks Road, Oxford OX1 3PU (United Kingdom)

    2012-07-20

    A far-infrared emission band attributed to volatile or refractory haze in Titan's stratosphere has been decreasing in intensity since Cassini's arrival in 2004. The 220 cm{sup -1} feature, first seen by the Voyager Infrared Interferometer Spectrometer, has only been found in Titan's winter polar region. The emission peaks at about 140 km altitude near the winter stratospheric temperature minimum. Observations recorded over the period 2004-2012 by the Composite Infrared Spectrometer on Cassini show a decrease in the intensity of this feature by about a factor of four. Possible seasonal causes of this decline are an increase in photolytic destruction of source chemicals at high altitude, a lessening of condensation as solar heating increased, or a weakening of downwelling of vapors. As of early 2012, the 220 cm{sup -1} haze has not yet been detected in the south. The haze composition is unknown, but its decrease is similar to that of HC{sub 3}N gas in Titan's polar stratosphere, pointing to a nitrile origin.

  11. The development of Haze Events observed by multi-satellite retrievals and Meteorological Analysis: A Case Study over Eastern China in December 2013

    Science.gov (United States)

    Zhang, Xiaoyu; Jiang, Binbin; Du, Yong; Yao, Lingling; Huang, Dasong

    2015-04-01

    With the rapid development of national economy and urbanization, the haze has been one of the environment disasters in eastern China. It is necessary that building a model of monitoring the haze for preventing and solving it in the future. In this study, NPP/AOT(550nm) >1and GOCI/AOT(555nm) >1 are adopted to dynamically monitor severe haze events in December 2013 over eastern China. Meanwhile, wind field data from CDAS-NCEP/DOE Reanalysis data and air temperature data from CDAS-NCEP/FNL are adopted to study the mechanism of the occurrence, migration and decay of the haze events. The haze event is composed of two consecutive cases. The first case occurred during 4-9 December is an exogenous haze for Yangtze River Delta, whereas the second case appeared during 11-15 December is an endogenous haze. This result shows:1) With the improved two-stream approximation model, GOCI is successful used to retrieve AOT with compared AERONET AOT, which demonstrates to be feasible in monitoring severe haze events. 2)Because of the large-scale observation capacity of NPP/AOT(550nm) product (×6km) and the high temporal resolution of GOCI/AOT(555nm), this study establishes a framework that detect the large-scale haze events using both data sets. 3)Weak wind speed of less than 5 m*s-1 is important for the development of the haze but the inversion is not a necessary condition for the haze. The strong cold air mass from the northern Siberia area and from East China Sea is the main force for the immigration, diffusion and decay of this haze event. 4)The air quality around Yangtze River Delta in winter is apt to suffer widely divergent influences including exogenous hazes carried by winter northwestward monsoon flows from northern Asia, and endogenous hazes induced by the rapid development of urbanization. The hit of multiple hazes over Yangtze River Delta lead to one of the most severe polluted regions of haze in China. Key words: NPP/AOT;GOCI/AOT; Haze;dynamic monitoring

  12. 21 CFR 73.50 - Ultramarine blue.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Ultramarine blue. 73.50 Section 73.50 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES GENERAL LISTING OF COLOR ADDITIVES EXEMPT FROM CERTIFICATION Foods § 73.50 Ultramarine blue. (a) Identity. The color additive ultramarine blue is a blue pigment obtained...

  13. 40 CFR 51.308 - Regional haze program requirements.

    Science.gov (United States)

    2010-07-01

    ... the program are needed to enhance performance of the program. (3) A State which opts under 40 CFR 51... stationary sources, mobile sources, and area sources. (v) The State must consider, at a minimum, the... administrative barriers to the operation of the allowance market, and ensure that such procedures apply...

  14. PLAM - a meteorological pollution index for air quality and its applications in fog-haze forecasts in North China

    Science.gov (United States)

    Yang, Y. Q.; Wang, J. Z.; Gong, S. L.; Zhang, X. Y.; Wang, H.; Wang, Y. Q.; Wang, J.; Li, D.; Guo, J. P.

    2016-02-01

    Using surface meteorological observation and high-resolution emission data, this paper discusses the application of the PLAM/h index (Parameter Linking Air-quality to Meteorological conditions/haze) in the prediction of large-scale low visibility and fog-haze events. Based on the two-dimensional probability density function diagnosis model for emissions, the study extends the diagnosis and prediction of the meteorological pollution index PLAM to the regional visibility fog-haze intensity. The results show that combining the influence of regular meteorological conditions and emission factors together in the PLAM/h parameterization scheme is very effective in improving the diagnostic identification ability of the fog-haze weather in North China. The determination coefficients for four seasons (spring, summer, autumn, and winter) between PLAM/h and visibility observation are 0.76, 0.80, 0.96, and 0.86, respectively, and all of their significance levels exceed 0.001, showing the ability of PLAM/h to predict the seasonal changes and differences of fog-haze weather in the North China region. The high-value correlation zones are located in Jing-Jin-Ji (Beijing, Tianjin, Hebei), Bohai Bay rim, and southern Hebei-northern Henan, indicating that the PLAM/h index is related to the distribution of frequent heavy fog-haze weather in North China and the distribution of emission high-value zone. Through comparative analysis of the heavy fog-haze events and large-scale clear-weather processes in winter and summer, it is found that PLAM/h index 24 h forecast is highly correlated with the visibility observation. Therefore, the PLAM/h index has good capability in identification, analysis, and forecasting.

  15. Modeling analysis of the seasonal characteristics of haze formation in Beijing

    Science.gov (United States)

    Han, X.; Zhang, M.; Gao, J.; Wang, S.; Chai, F.

    2014-09-01

    The air quality modeling system RAMS-CMAQ (Regional Atmospheric Modeling System-Community Multiscale Air Quality), coupled with an aerosol optical property scheme, was applied to simulate the meteorological field, major aerosol components (sulfate, nitrate, ammonium, black carbon, organic carbon, dust, and sea salt), and surface visibility over the North China Plain (NCP) in 2011. The modeled results in February and July 2011 were selected and analyzed to obtain an in-depth understanding of the haze formation mechanism in Beijing for different seasons. The simulation results showed that the visibility was below 10 km for most regions of the NCP, and dropped to less than 5 km over the megacities of Beijing and Tianjin, the whole of Hebei Province, and the northwest part of Shandong Province during pollution episodes in February and July. The heavy mass concentration of PM2.5 ranged from 120 to 300 μg m-3 and was concentrated in the areas with low visibility. The haze formation mechanism in Beijing in winter was different from that in summer. The mass concentration of PM2.5 was higher, and the components more complicated, in winter. While the mass concentration of PM2.5 in summer was lower than that in winter, the mass concentrations of hygroscopic inorganic salts were comparable with those in winter, and the relative humidity was, as expected, higher. Therefore, the water uptake of hygroscopic aerosols played a key role in summer. Moreover, the analysis showed that the influence of the PM2.5 mass burden on visibility was very weak when its value was larger than 100 μg m-3. Only when the mass burden of PM2.5 decreased to a certain threshold interval did the visibility increase rapidly. This indicates that, when emission reduction measures are taken to control haze occurrence, the mass burden of PM2.5 must be cut to below this threshold interval. The relationship between the threshold of haze occurrence and the relative humidity in Beijing was fitted by an

  16. "Clothed in triple blues": sorting out the Italian blues.

    Science.gov (United States)

    Bimler, David; Uusküla, Mari

    2014-04-01

    Cross-cultural comparisons of color perception and cognition often feature versions of the "similarity sorting" procedure. By interpreting the assignment of two color samples to different groups as an indication that the dissimilarity between them exceeds some threshold, sorting data can be regarded as low-resolution similarity judgments. Here we analyze sorting data from speakers of Italian, Russian, and English, applying multidimensional scaling to delineate the boundaries between perceptual categories while highlighting differences between the three populations. Stimuli were 55 color swatches, predominantly from the blue region. Results suggest that at least two Italian words for "blue" are basic, a similar situation to Russian, in contrast to English where a single "blue" term is basic.

  17. Why Do Proteins Glow Blue?

    CERN Document Server

    Sarkar, Sohini; Hazra, Partha; Mandal, Pankaj

    2014-01-01

    Recent literatures reported blue-green emission from amyloid fibril as exclusive signature of fibril formation. This unusual visible luminescence is regularly used to monitor fibril growth. Blue-green emission has also been observed in crystalline protein and in solution. However, the origin of this emission is not known exactly. Our spectroscopic study of serum proteins reveals that the blue-green emission is a property of protein monomer. Evidences suggest that semiconductor-like band structure of proteins with the optical band-gap in the visible region is possibly the origin of this phenomenon. We show here that the band structure of proteins is primarily the result of electron delocalization through the peptide chain, rather than through the hydrogen bond network in secondary structure.

  18. Chemical characteristics of PM2.5 during haze episodes in the urban of Fuzhou,China

    Institute of Scientific and Technical Information of China (English)

    Fuwang Zhang; Lingling Xu; Jinsheng Chen; Xiaoqiu Chen; Zhenchuan Niu; Tong Lei; Chunming Li

    2013-01-01

    Atmospheric fine particles (PM2.5) were collected in this study with middle volume samplers in Fuzhou,China,during both normal days and haze days in summer (September 2007) and winter (January 2008).The concentrations,distributions,and sources of polycyclic aromatic hydrocarbons (PAHs),organic carbon (OC),elemental carbon (EC),and water soluble inorganic ions (WSIIs) were determinated.The results showed that the concentrations of PM2.5,PAHs,OC,EC,and WSIIs were in the orders of haze > normal and winter > summer.The dominant PAHs of PM2.5 in Fuzhou were Fluo,Pyr,Chr,BbF,BkF,BaP,BghiP,and IcdP,which represented about 80.0% of the total PAHs during different sampling periods.The BaPeq concentrations of ∑ PAHs were 0.78,0.99,1.22,and 2.43 ng/m3 in summer normal,summer haze,winter normal,and winter haze,respectively.Secondary pollutants (SO42-,NO3-,NH4+,and OC) were the major chemical compositions of PM2.5,accounting for 69.0%,55.1%,63.4%,and 64.9% of PM2.5 mass in summer normal,summer haze,winter normal,and winter haze,respectively.Correspondingly,secondary organic carbon (SOC) in Fuzhou accounted for 20.1%,48.6%,24.5%,and 50.5% of OC.The average values of nitrogen oxidation ratio (NOR) and sulfur oxidation ratio (SOR) were higher in haze days (0.08 and 0.27) than in normal days (0.05 and 0.22).Higher OC/EC ratios were also found in haze days (5.0) than in normal days (3.3).Correlation analysis demonstrated that visibility had positive correlations with wind speed,and negative correlations with relative humidity and major air pollutants.Overall,the enrichments of PM2.5,OC,EC,SO42-,and NO3-promoted haze formation.Furthermore,the diagnostic ratios of IcdP/(IcdP+ BghiP),IcdP/BghiP,OC/EC,andNO3-/SO42-indicated that vehicle exhaust and coal consumption were the main sources of pollutants in Fuzhou.

  19. The development of corannulene-based blue emitters.

    Science.gov (United States)

    Mack, James; Vogel, Philip; Jones, Derek; Kaval, Necati; Sutton, Art

    2007-08-01

    Novel blue emitters were synthesized based on the fullerene fragment corannulene. 1,2- bis(corannulenylethynyl)benzene and 1,4-bis(corannulenylethynyl)benzene were designed, synthesized, and shown to exhibit significant red shifts in their absorption spectra as compared to that of the parent corannulene. Photoluminescence studies show both 1,2- bis(corannulenylethynyl)benzene and 1,4- bis(corannulenylethynyl)benzene gives enhanced blue luminescence compared to the parent corannulene structure. 1,4-bis(corannulenylethynyl)benzene was observed to give intense blue luminescence when excited at 400 nm. DFT and TD-DFT calculations were performed and shown to be consistent with the observed experimental results.

  20. A Bump in the Blue Axion Isocurvature Spectrum

    CERN Document Server

    Chung, Daniel J H

    2016-01-01

    Blue axion isocurvature perturbations are both theoretically well-motivated and interesting from a detectability perspective. These power spectra generically have a break from the blue region to a flat region. Previous investigations of the power spectra were analytic, which left a gap in the predicted spectrum in the break region due to the non-applicability of the used analytic techniques. We therefore compute the isocurvature spectrum numerically for an explicit supersymmetric axion model. We find a bump that enhances the isocurvature signal for this class of scenarios. A fitting function of three parameters is constructed that fits the spectrum well for the particular axion model we study. This fitting function should be useful for blue isocurvature signal hunting in data and making experimental sensitivity forecasts.

  1. Causation mechanism analysis for haze pollution related to vehicle emission in Guangzhou, China by employing the fault tree approach.

    Science.gov (United States)

    Huang, Weiqing; Fan, Hongbo; Qiu, Yongfu; Cheng, Zhiyu; Xu, Pingru; Qian, Yu

    2016-05-01

    Recently, China has frequently experienced large-scale, severe and persistent haze pollution due to surging urbanization and industrialization and a rapid growth in the number of motor vehicles and energy consumption. The vehicle emission due to the consumption of a large number of fossil fuels is no doubt a critical factor of the haze pollution. This work is focused on the causation mechanism of haze pollution related to the vehicle emission for Guangzhou city by employing the Fault Tree Analysis (FTA) method for the first time. With the establishment of the fault tree system of "Haze weather-Vehicle exhausts explosive emission", all of the important risk factors are discussed and identified by using this deductive FTA method. The qualitative and quantitative assessments of the fault tree system are carried out based on the structure, probability and critical importance degree analysis of the risk factors. The study may provide a new simple and effective tool/strategy for the causation mechanism analysis and risk management of haze pollution in China. PMID:26923237

  2. Process analysis of characteristics of the boundary layer during a heavy haze pollution episode in an inland megacity, China.

    Science.gov (United States)

    Wang, Shan; Liao, Tingting; Wang, Lili; Sun, Yang

    2016-02-01

    Ground observation data from 8 meteorological stations in Xi'an, air mass concentration data from 13 environmental quality monitoring sites in Xi'an, as well as radiosonde observation and wind profile radar data, were used in this study. Thereby, the process, causes and boundary layer meteorological characteristics of a heavy haze episode occurring from 16 to 25 December 2013 in Xi'an were analyzed. Principal component analysis showed that this haze pollution was mainly caused by the high-intensity emission and formation of gaseous pollutants (NO2, CO and SO2) and atmospheric particles (PM2.5 (fine particles) and PM10 (respirable suspended particle). The second cause was the relative humidity and continuous low temperature. The third cause was the allocation of the surface pressure field. The presence of a near-surface temperature inversion at the boundary layer formed favorable stratification conditions for the formation and maintenance of heavy haze pollution. The persistent thick haze layer weakened the solar radiation. Meanwhile, a warming effect in the urban canopy layer and in the transition zone from the urban friction sublayer to the urban canopy was indicated. All these conditions facilitated the maintenance and reinforcement of temperature inversion. The stable atmospheric stratification finally acted on the wind field in the boundary layer, and further weakened the exchange capacity of vertical turbulence. The superposition of a wind field with the horizontal gentle wind induced the typical air stagnation and finally caused the deterioration of air quality during this haze event. PMID:26969553

  3. Across the Threshold: A Comparative Analysis of Communitas and Rites of Passage in Sport Hazing and Initiations

    Directory of Open Access Journals (Sweden)

    Jay Johnson

    2011-01-01

    Full Text Available Hazing rituals and ceremonies have been described in traditional,historical world cultures, junior and high school, the military, private schools, paramilitary organizations, fraternities and sororities, as well as sport (Allan and Madden 2008; Bryshun and Young 1999; Campo, Poulos, and Sipple 2005; Fields, Collins, and Comstock 2010; Johnson 2000, 2009; Linhares de Albuquerque and Paes-Machado 2004; Nuwer 1999; Winslow 1999; Zacharda 2009. Student athletes often endure hazing practices with 80% of NCAA athletes reporting some form of initiation (Hoover 1999 in exchange for membership affiliation. This qualitative study compared the similarities and deviationsbetween contemporary initiations and historical traditions defining both the importance of cultures to establish “Rites of Passage” membership gateways and metamorphoses from nonmember to group. Results indicated that despite often abusive hazing ceremonies in sport, marked by hierarchies, power imbalances, and, at times, criminal behaviour, there still exists a demand for an entry ritual by the rookie contingency to mark their membership and identity within theteam structure. Hazing traditions continue in the belief in what Turner (1986describes as Communitas, despite indications from participants that hazing fractured relationships on the team — a marked contradiction of Communitas.

  4. Causation mechanism analysis for haze pollution related to vehicle emission in Guangzhou, China by employing the fault tree approach.

    Science.gov (United States)

    Huang, Weiqing; Fan, Hongbo; Qiu, Yongfu; Cheng, Zhiyu; Xu, Pingru; Qian, Yu

    2016-05-01

    Recently, China has frequently experienced large-scale, severe and persistent haze pollution due to surging urbanization and industrialization and a rapid growth in the number of motor vehicles and energy consumption. The vehicle emission due to the consumption of a large number of fossil fuels is no doubt a critical factor of the haze pollution. This work is focused on the causation mechanism of haze pollution related to the vehicle emission for Guangzhou city by employing the Fault Tree Analysis (FTA) method for the first time. With the establishment of the fault tree system of "Haze weather-Vehicle exhausts explosive emission", all of the important risk factors are discussed and identified by using this deductive FTA method. The qualitative and quantitative assessments of the fault tree system are carried out based on the structure, probability and critical importance degree analysis of the risk factors. The study may provide a new simple and effective tool/strategy for the causation mechanism analysis and risk management of haze pollution in China.

  5. Process analysis of characteristics of the boundary layer during a heavy haze pollution episode in an inland megacity, China.

    Science.gov (United States)

    Wang, Shan; Liao, Tingting; Wang, Lili; Sun, Yang

    2016-02-01

    Ground observation data from 8 meteorological stations in Xi'an, air mass concentration data from 13 environmental quality monitoring sites in Xi'an, as well as radiosonde observation and wind profile radar data, were used in this study. Thereby, the process, causes and boundary layer meteorological characteristics of a heavy haze episode occurring from 16 to 25 December 2013 in Xi'an were analyzed. Principal component analysis showed that this haze pollution was mainly caused by the high-intensity emission and formation of gaseous pollutants (NO2, CO and SO2) and atmospheric particles (PM2.5 (fine particles) and PM10 (respirable suspended particle). The second cause was the relative humidity and continuous low temperature. The third cause was the allocation of the surface pressure field. The presence of a near-surface temperature inversion at the boundary layer formed favorable stratification conditions for the formation and maintenance of heavy haze pollution. The persistent thick haze layer weakened the solar radiation. Meanwhile, a warming effect in the urban canopy layer and in the transition zone from the urban friction sublayer to the urban canopy was indicated. All these conditions facilitated the maintenance and reinforcement of temperature inversion. The stable atmospheric stratification finally acted on the wind field in the boundary layer, and further weakened the exchange capacity of vertical turbulence. The superposition of a wind field with the horizontal gentle wind induced the typical air stagnation and finally caused the deterioration of air quality during this haze event.

  6. Clouds in the Forecast? A Joint Spitzer and HST Investigation of Clouds and Hazes for Two Exo-Neptunes

    Science.gov (United States)

    Kreidberg, Laura; Morley, Caroline; Line, Michael; Stevenson, Kevin; Dragomir, Diana

    2016-08-01

    Recent observations of transiting planets have revealed that clouds and hazes are common in exoplanet atmospheres. Little is known, however, about how the clouds/hazes form, what their composition is, and how their properties vary with planet parameters. We propose to characterize the atmospheres of two exo-Neptunes, GJ 436b and GJ 3470b, both of which show evidence for clouds or hazes in their near-infrared spectra. We will measure precise 3.6 and 4.5 micron transit depths for these planets, to compare with existing high-precision data at shorter wavelengths. We will also obtain a UV spectrum for GJ 3470 with HST/COS to enable accurate models of the planet's photochemistry. These observations will enable us to distinguish at high confidence between a range of physically realistic models for the atmospheric chemistry, including methanogenic photochemical hazes and equilibrium salt/sulfide clouds. The measurements will enable comparative planetology with the handful of other small, cool worlds currently accessible to observation, and serve as a first assessment of the prevalence, origin, and composition of clouds and haze in metal-enriched atmospheres below 1000 K. Our findings will guide the design of future observations of increasingly Earth-like worlds with JWST.

  7. The blue-collar brain.

    Science.gov (United States)

    Van Orden, Guy; Hollis, Geoff; Wallot, Sebastian

    2012-01-01

    Much effort has gone into elucidating control of the body by the brain, less so the role of the body in controlling the brain. This essay develops the idea that the brain does a great deal of work in the service of behavior that is controlled by the body, a blue-collar role compared to the white-collar control exercised by the body. The argument that supports a blue-collar role for the brain is also consistent with recent discoveries clarifying the white-collar role of synergies across the body's tensegrity structure, and the evidence of critical phenomena in brain and behavior. PMID:22719730

  8. How does the blue-ringed octopus (Hapalochlaena lunulata) flash its blue rings?

    Science.gov (United States)

    Mäthger, Lydia M; Bell, George R R; Kuzirian, Alan M; Allen, Justine J; Hanlon, Roger T

    2012-11-01

    The blue-ringed octopus (Hapalochlaena lunulata), one of the world's most venomous animals, has long captivated and endangered a large audience: children playing at the beach, divers turning over rocks, and biologists researching neurotoxins. These small animals spend much of their time in hiding, showing effective camouflage patterns. When disturbed, the octopus will flash around 60 iridescent blue rings and, when strongly harassed, bite and deliver a neurotoxin that can kill a human. Here, we describe the flashing mechanism and optical properties of these rings. The rings contain physiologically inert multilayer reflectors, arranged to reflect blue-green light in a broad viewing direction. Dark pigmented chromatophores are found beneath and around each ring to enhance contrast. No chromatophores are above the ring; this is unusual for cephalopods, which typically use chromatophores to cover or spectrally modify iridescence. The fast flashes are achieved using muscles under direct neural control. The ring is hidden by contraction of muscles above the iridophores; relaxation of these muscles and contraction of muscles outside the ring expose the iridescence. This mechanism of producing iridescent signals has not previously been reported in cephalopods and we suggest that it is an exceptionally effective way to create a fast and conspicuous warning display.

  9. The Blue Revolution in Asia

    DEFF Research Database (Denmark)

    Ponte, Stefano; Kelling, Ingrid; Jespersen, Karen Sau;

    2014-01-01

    In this article, we examine the upgrading trajectories of selected aquaculture value chains in four Asian countries and the links between upgrading and three factors of value chain governance: coordination mechanisms; types of drivers; and domestic regulation. We find instances of improving produ...... of upgrading the "blue revolution" in Asia...

  10. Liquid biofuels from blue biomass

    DEFF Research Database (Denmark)

    Kádár, Zsófia; Jensen, Annette Eva; Bangsø Nielsen, Henrik;

    2011-01-01

    Marine (blue) biomasses, such as macroalgaes, represent a huge unexploited amount of biomass. With their various chemical compositions, macroalgaes can be a potential substrate for food, feed, biomaterials, pharmaceuticals, health care products and also for bioenergy. Algae use seawater as a growth...

  11. Nobel Prize for blue LEDs

    Science.gov (United States)

    Kraftmakher, Yaakov

    2015-05-01

    A brief review of lighting technologies is presented. Unavoidable restrictions for incandescent light bulbs caused by the Planck distribution and properties of the human eye are illustrated. The efficiency and luminous efficacy of thermal radiation are calculated for various temperatures; the results clearly show the limitations for thermal radiators. The only way to overcome these limitations is using non-thermal radiators, such as fluorescent lamps and light-emitting diodes (LEDs). Unique advantages of LEDs undoubtedly made a revolution in this field. A crucial element of this progress is the blue LEDs (Nobel Prize 2014). Some experiments with a blue and a green LED are described: (i) the luminescence triggered in a green-yellow phosphor inside a white LED by the blue LED; (ii) radiant spectra and ‘efficiency droop’ in the LEDs; (iii) modulation of the blue LED up to 4 MHz; and (iv) the h/e ratio from the turn-on voltage of the green LED. The experiments are suitable for undergraduate laboratories and usable as classroom demonstrations.

  12. Blue Ocean vs. Five Forces

    NARCIS (Netherlands)

    A.E. Burke (Andrew); A.J. van Stel (André); A.R. Thurik (Roy)

    2010-01-01

    textabstractThe article reports on the authors' research in the Netherlands which focused on a profit model in Dutch retail stores and a so-called blue-ocean approach which requires a new market that attracts consumers and increases profits. Topics include the competitive strategy approach to increa

  13. Efficiency of enzymatic and other alternative clarification and fining treatments on turbidity and haze in cherry juice

    DEFF Research Database (Denmark)

    Meyer, Anne Boye Strunge; Köser, C.; Adler-Nissen, Jens

    2001-01-01

    function. Individual and interactive effects on turbidity and haze formation in precentrifuged and uncentrifuged cherry juice of treatments with pectinase, acid protease, bromelain, gallic acid, and gelatin-silica sol were investigated in a factorial experimental design with 32 different parameter...... combinations. Gelatin-silica sol consistently had the best effect on juice clarity. Centrifugation of cherry juice (10000g for 15 min) prior to clarification treatment significantly improved juice clarity and diminished the rate of haze formation during cold storage of juice. Both treatment of precentrifuged...... cherry juice with Novozym 89L protease and co- addition of pectinase and gallic acid improved cherry juice clarity and diminished haze levels. None of the alternative treatments produced the unwieldy colloids notorious to gelatin- silica sol treatment. The data suggest that several alternative...

  14. TEM Study of Aerosol Particles in Brown Haze Episodes over Northern China in Spring 2007

    Science.gov (United States)

    Li, W.; Shao, L.; Buseck, P. R.

    2008-12-01

    Airborne aerosol collections were performed in eight brown haze episodes from 31 May to 21 June 2007 in Beijing, China. Morphologies, compositions, and mixing states of individual aerosol particles having different sizes were obtained using transmission electron microscopy (TEM). Aerosol particle types less than 2 μ m in diameter include mineral dust, fly ash, soot, organic material, and K-rich, S-rich, and metal particles (Fe- and Zn-rich). Mineral dust particles dominate in the range of 2 to 10 μ m. In addition to finding contributions from vehicle emissions and soil dust in Beijing, TEM results from the study provide new insights into sources such as agricultural biomass burning, industrial activities, and waste incineration. These sources can contribute not only great amounts of K-rich and metal particles but also reactive gases such as NH3, NOx, SO2, and VOCs to the haze. More than 80% of the analyzed aerosol particles are internally mixed. K- and S-rich particles tend to be coagulated with fly ash, soot, metal, and fine-grained mineral dust particles. Organic materials can act as inclusions in the K- and S-rich particles and their coatings. Over 90% of the analyzed internally mixed mineral particles are covered with Ca-, Mg-, or Na-rich coatings, and only 8% are associated with K- or S-rich coatings. The compositions of Ca-, Mg-, and Na-rich coatings suggest that they are possibly nitrates mixed with minor sulfates and chlorides. Calcium sulfate particles with diameters from 10 to 500 nm were also detected within Ca(NO3)2 and Mg(NO3)2 coatings. These results indicate that mineral dust particles in the brown haze episodes participated in heterogeneous reactions in the atmosphere with one or more of SO2, NO2, HCl, and HNO3. The development of coatings altered some mineral dust particles from hydrophobic to hydrophilic.

  15. Persistent and Widespread Winter Haze & Fog over the Indo-Gangetic Plains: A climatological perspective from satellite observations

    Science.gov (United States)

    Gautam, R.

    2014-12-01

    Each year during winter season (December-January), dense fog engulfs the Indo-Gangetic Plains (IGP) in southern Asia, for more than a month, disrupting daily life of millions of people inhabiting the IGP. The widespread nature of the fog is frequently visible in satellite imagery, extending over a stretch of ~1500 km; that covers parts of Pakistan, northern India, Nepal and Bangladesh. Both, haze and fog are a tightly-coupled system over the IGP, during winter months, and have been a major environmental/climatic issue since the past several decades. Trends in poor visibility suggest a significant increase in worsening air quality and foggy days over the IGP. The persistent and widespread nature of the winter haze and fog is strongly influenced by the regional meteorology during wintertime, i.e. a stable boundary layer, low temperatures, high relative humidity and light winds. The valley-type topography of the IGP, adjacent to the towering Himalaya, and high concentrations of pollution aerosols, further favors the persistence of hazy/foggy conditions. A satellite-based observational portrayal will be presented, using various cloud, aerosol and radiation datasets, to characterize the widespread nature of winter haze and fog, based on a multi-sensor assessment from MODIS, CERES, AVHRR and CALIPSO datasets. More specifically, based on these observations, we will present results on: long-term trends/variability of winter haze and fog, vertical characterization of aerosol/fog/low-clouds, as well as assessment of the direct radiative effect of the region-wide haze/fog system. Results from this work are anticipated to shed light on the overall interactions within the highly persistent and tightly-coupled haze-fog phenomena. Additionally, against the backdrop of a changing climate scenario, possible linkages between the winter-time fog cover, regional meteorology and aerosol loading will also be discussed over the IGP.

  16. Interannual increase of regional haze-fog in North China Plain in summer by intensified easterly winds and orographic forcing

    Science.gov (United States)

    Cao, Ziqi; Sheng, Lifang; Liu, Qian; Yao, Xiaohong; Wang, Wencai

    2015-12-01

    Regional haze-fog events over the North China Plain (NCP) have attracted much attention in recent years. Their increase has been attributed to anthropogenic emissions of air pollutants and synoptic weather conditions. We investigated the influence of local meteorological conditions and large-scale circulation on the haze-fog events over the NCP during 2001-2012, and found a significant interannual increase in the number of summer regional haze-fog days. Analysis indicated that local meteorological conditions could partly explain the increase but failed to explain the spatial variation; meanwhile, regional circulation change induced by large-scale circulation and orographic forcing unveiled a possible spatiotemporal variation mechanism. In summer, the prevalent southerly winds over the NCP were obstructed by the Taihang and Yanshan mountains, steadying the outflow direction to the southeast, while different inflow direction controlled by large-scale circulation had different effects on regional circulation. In weak (strong) East Asian summer monsoon years, an intensified eastward (westward) zonal inflow wind component reinforced (weakened) the negative vorticity and formed an anomalous anticyclone (cyclone), which strengthened (weakened) the downward motion, so the dissipation capability was weakened (strengthened) and the wind speed decreased (increased), ultimately resulting in the increased (decreased) occurrence of haze-fog. We also found that the circulation anomaly had a good relationship with strong El Niño and La Niña events. There was more haze-fog over the NCP in the summers that followed a La Niña event, and less in summers that followed an El Niño event. This suggested the possibility that summer haze-fog phenomena could be predicted based on the phase of ENSO.

  17. Chromophore Deprotonation State Alters the Optical Properties of Blue Chromoprotein.

    Directory of Open Access Journals (Sweden)

    Cheng-Yi Chiang

    Full Text Available Chromoproteins (CPs have unique colors and can be used in biological applications. In this work, a novel blue CP with a maximum absorption peak (λmax at 608 nm was identified from the carpet anemone Stichodactyla gigantea (sgBP. In vivo expression of sgBP in zebrafish would change the appearance of the fishes to have a blue color, indicating the potential biomarker function. To enhance the color properties, the crystal structure of sgBP at 2.25 Å resolution was determined to allow structure-based protein engineering. Among the mutations conducted in the Gln-Tyr-Gly chromophore and chromophore environment, a S157C mutation shifted the λmax to 604 nm with an extinction coefficient (ε of 58,029 M-1·cm-1 and darkened the blue color expression. The S157C mutation in the sgBP chromophore environment could affect the color expression by altering the deprotonation state of the phenolic group in the chromophore. Our results provide a structural basis for the blue color enhancement of the biomarker development.

  18. Lucifer's Planet: Photolytic Hazes in the Atmosphere of 51 Eri b

    Science.gov (United States)

    Zahnle, Kevin; Marley, Mark; Morley, Caroline; Moses, Julianne I.

    2016-10-01

    The star 51 Eridani is a pre-main-sequence F dwarf that is only 20 million years old. Direct-imaging observations with GPI (Gemini Planet Imager) reveal that the star is orbited by a self-radiant young Jupiter, designated 51 Eri b, that emits with an effective temperature on the order of 700 K (Macintosh et al (2015) Science 350, 64). Thermal evolution models predict that the planet has Jupiter's radius and twice its mass.We use a 1D model to address photochemistry and possible haze formation in the irradiated atmosphere of 51 Eri b (2016arXiv160407388Z). The intended focus was to have been on carbon and organic hazes, but sulfur photochemistry turns out to be interesting and possibly more important. The case for organic photochemical hazes is intriguing but falls short of being compelling. If organic hazes form abundantly, they are likeliest to do so if vertical mixing in 51 Eri b is weaker than in Jupiter, and they would be found below the altitudes where methane and water are photolyzed. The more novel result is that photochemistry turns H2S into elemental sulfur, here treated as S8. In the cooler models, S8 is predicted to condense in optically significant clouds of solid sulfur particles, whilst in the warmer models S8 remains a vapor along with several other sulfur allotropes that are both visually striking and potentially observable. For 51 Eri b, the division between models with and without condensed sulfur is at an effective temperature of 700 K, which is within error its actual effective temperature; the local temperature where sulfur condenses is between 280 and 320 K. The sulfur photochemistry we discuss is quite general and ought to be found in a wide variety of worlds over a broad temperature range, both colder and hotter than the 650-750 K range studied here, and we show that products of sulfur photochemistry will be nearly as abundant on planets where the UV irradiation is orders of magnitude weaker than it is on 51 Eri b.

  19. Aerosol properties in the upper haze of Venus from SPICAV IR data

    Science.gov (United States)

    Luginin, M.; Fedorova, A.; Belyaev, D.; Montmessin, F.; Wilquet, V.; Korablev, O.; Bertaux, J.-L.; Vandaele, A. C.

    2016-10-01

    SPICAV IR, a channel of the SPICAV/SOIR suite of instruments onboard Venus Express spacecraft measured spectra in nadir and solar occultation modes in the range of 0.65-1.7 μm. We report results from 222 solar occultations observed from May 2006 to November 2014. The vertical resolution of measurements varies from 1 to 25 km depending on the distance of the spacecraft to the limb of Venus. The vertical profiles of atmospheric extinction were obtained at 10 near-IR wavelengths in the altitude range from 70 to 95 km. This allowed us to derive microphysical properties of the mesospheric haze. The aerosol haze top is higher near the equator than near the pole. In the upper haze, the aerosol scale height is found to be 3.3 ± 0.7 km. Detached haze layers were detected at altitudes from 70 to 90 km. Particle size and number density profiles are retrieved from extinction coefficients using Mie scattering theory adopting H2SO4 refractive indices. Bimodal distribution of particles is consistent with data for some orbits with mean radius for mode 1 reff1 = 0.12 ± 0.03 μm and reff2 = 0.84 ± 0.16 μm for mode 2. Particle radii tend to cluster within occultation campaign and vary on the time scale of several months. The radius for the single mode case equals Reff = 0.54 ± 0.25 μm, and they are also 1.5-2 times smaller in the polar region (60°N-90°N) than in nonpolar regions (60°S-60°N). In bimodal case the number density profiles decrease smoothly for both modes, from ∼500 cm-3 at 75 km to ∼50 cm-3 at 90 km for mode 1, and from ∼1 cm-3 at 75 km to ∼0.1 cm-3 at 90 km for mode 2.

  20. Photophysics of the blue fluorescent protein

    International Nuclear Information System (INIS)

    The blue fluorescent protein (BFP) is a mutant of the green fluorescent protein, where the phenolic ring of the chromophore has been replaced by imidazole cycle of histidine residue. The usability of BFP as a fluorescent marker is hampered by its low fluorescence quantum yield at room temperature. The intensity of fluorescence increases by a factor of 4.5 when the temperature is decreased from 320 K down to 225 K. The fluorescence is also enhanced by hydrostatic pressure. Both effects have been explained by shift of the equilibrium between hydrogen nonbonded and hydrogen-bonded chromophores. Our semi-empirical quantum chemical calculations show that the fluorescence quantum yield of the BFP chromophore is low due to isomerization in the electronically excited state -twisting of the bridging bond by 90 deg. At this twisted geometry the potential energy surfaces of ground and excited states are situated close to each other facilitating efficient nonradiative decay

  1. Artificial intelligence based approach to forecast PM2.5 during haze episodes: A case study of Delhi, India

    Science.gov (United States)

    Mishra, Dhirendra; Goyal, P.; Upadhyay, Abhishek

    2015-02-01

    Delhi has been listed as the worst performer across the world with respect to the presence of alarmingly high level of haze episodes, exposing the residents here to a host of diseases including respiratory disease, chronic obstructive pulmonary disorder and lung cancer. This study aimed to analyze the haze episodes in a year and to develop the forecasting methodologies for it. The air pollutants, e.g., CO, O3, NO2, SO2, PM2.5 as well as meteorological parameters (pressure, temperature, wind speed, wind direction index, relative humidity, visibility, dew point temperature, etc.) have been used in the present study to analyze the haze episodes in Delhi urban area. The nature of these episodes, their possible causes, and their major features are discussed in terms of fine particulate matter (PM2.5) and relative humidity. The correlation matrix shows that temperature, pressure, wind speed, O3, and dew point temperature are the dominating variables for PM2.5 concentrations in Delhi. The hour-by-hour analysis of past data pattern at different monitoring stations suggest that the haze hours were occurred approximately 48% of the total observed hours in the year, 2012 over Delhi urban area. The haze hour forecasting models in terms of PM2.5 concentrations (more than 50 μg/m3) and relative humidity (less than 90%) have been developed through artificial intelligence based Neuro-Fuzzy (NF) techniques and compared with the other modeling techniques e.g., multiple linear regression (MLR), and artificial neural network (ANN). The haze hour's data for nine months, i.e. from January to September have been chosen for training and remaining three months, i.e., October to December in the year 2012 are chosen for validation of the developed models. The forecasted results are compared with the observed values with different statistical measures, e.g., correlation coefficients (R), normalized mean square error (NMSE), fractional bias (FB) and index of agreement (IOA). The performed

  2. Flavour production of Stilton blue cheese microflora

    OpenAIRE

    Gkatzionis, Konstantinos

    2010-01-01

    In the blue cheese Stilton the starter mould Penicillium roqueforti grows and sporulates during the ripening period and is considered to be responsible for the unique blue cheese aroma. However, the sporulation of the mould, which results in the formation of blue veins, takes place in a fraction of the Stilton matrix which overall is very heterogeneous. Most blue cheeses develop a secondary microflora of yeasts which may affect their aroma. The aim of this study was to investigate the yeast f...

  3. Computational mask defect review for contamination and haze inspections

    Science.gov (United States)

    Morgan, Paul; Rost, Daniel; Price, Daniel; Corcoran, Noel; Satake, Masaki; Hu, Peter; Peng, Danping; Yonenaga, Dean; Tolani, Vikram; Wolf, Yulian; Shah, Pinkesh

    2013-09-01

    As optical lithography continues to extend into sub-0.35 k1 regime, mask defect inspection and subsequent review has become tremendously challenging, and indeed the largest component to mask manufacturing cost. The routine use of various resolution enhancement techniques (RET) have resulted in complex mask patterns, which together with the need to detect even smaller defects due to higher MEEFs, now requires an inspection engineer to use combination of inspection modes. This is achieved in 193nm AeraTM mask inspection systems wherein masks are not only inspected at their scanner equivalent aerial exposure conditions, but also at higher Numerical Aperture resolution, and special reflected-light, and single-die contamination modes, providing better coverage over all available patterns, and defect types. Once the required defects are detected by the inspection system, comprehensively reviewing and dispositioning each defect then becomes the Achilles heel of the overall mask inspection process. Traditionally, defects have been reviewed manually by an operator, which makes the process error-prone especially given the low-contrast in the convoluted aerial images. Such manual review also limits the quality and quantity of classifications in terms of the different types of characterization and number of defects that can practically be reviewed by a person. In some ways, such manual classification limits the capability of the inspection tool itself from being setup to detect smaller defects since it often results in many more defects that need to be then manually reviewed. Paper 8681-109 at SPIE Advanced Lithography 2013 discussed an innovative approach to actinic mask defect review using computational technology, and focused on Die-to-Die transmitted aerial and high-resolution inspections. In this approach, every defect is characterized in two different ways, viz., quantitatively in terms of its print impact on wafer, and qualitatively in terms of its nature and origin in

  4. Enhanced visible light photocatalytic degradation of eriochrome black T and eosin blue shade in water using tridoped titania decorated on SWCNTs and MWCNTs: Effect of the type of carbon nanotube incorporated

    Energy Technology Data Exchange (ETDEWEB)

    Mamba, G.; Mbianda, X.Y. [Department of Applied Chemistry, University of Johannesburg, Faculty of Science, P.O. Box 17011, Doornfontein, 2028 Johannesburg (South Africa); DST-NRF Centre of Excellence in Strong Materials, School of Physics, University of the Witwatersrand, Private Bag 3, WITS 2050 Johannesburg (South Africa); Mishra, A.K., E-mail: amishra@uj.ac.za [Department of Applied Chemistry, University of Johannesburg, Faculty of Science, P.O. Box 17011, Doornfontein, 2028 Johannesburg (South Africa); DST-NRF Centre of Excellence in Strong Materials, School of Physics, University of the Witwatersrand, Private Bag 3, WITS 2050 Johannesburg (South Africa)

    2015-01-15

    Oxidised single walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs) were each incorporated into a neodymium, nitrogen and sulphur tridoped TiO{sub 2} (Nd,N,S–TiO{sub 2}) to form composite photocatalysts: SWCNT/Nd,N,S–TiO{sub 2} and MWCNT/Nd,N,S–TiO{sub 2}. The fabricated composite photocatalysts were exploited for the photocatalytic degradation of eriochrome black T (EBT) and eosin blue shade (EBS) from single and mixed dye solutions. Incorporation of the carbon nanotubes significantly improved visible light response and the photocatalytic activity of the composites compared to MWCNT/TiO{sub 2}, SWCNT/TiO{sub 2} and tridoped TiO{sub 2}. The SWCNTs incorporating photocatalyst displayed superior photocatalytic activity over its MWCNTs incorporating counterpart. From single dye solutions degradation studies, the SWCNT/Nd,N,S–TiO{sub 2} reached maximum degradation efficiencies of 96.9% and 89.2% for EBS and EBT, respectively. Similarly, maximum degradation efficiencies of 61.4% and 54.1% were recorded from mixed dye solutions using SWCNT/Nd,N,S–TiO{sub 2}, for EBS and EBT, respectively. First order kinetics studies revealed that EBS is degraded faster than EBT both from single and mixed dye solutions. Total organic carbon (TOC) analyses suggest a relatively high degree of complete mineralisation of both EBS (73.6% TOC removal) and EBT (66.2% TOC removal). The SWCNT/Nd,N,S–TiO{sub 2} composite photocatalyst displayed sufficient stability (88.8% EBS removal) after being reused for five times. - Highlights: • SWCNT/Nd,N,S–TiO{sub 2} and MWCNT/Nd,N,S–TiO{sub 2} were prepared via sol–gel method. • EBS and EBT degradation was studied in single and mixed dye solution. • SWCNT/Nd,N,S–TiO{sub 2} displayed higher photocatalytic activity than MWCNT/Nd,N,S–TiO{sub 2}. • Relatively high TOC removal for EBS and EBT by SWCNT/Nd,N,S–TiO{sub 2}. • SWCNT/Nd,N,S–TiO{sub 2} displayed good stability for reuse.

  5. Food habits of blue grouse

    Science.gov (United States)

    Stewart, R.E.

    1944-01-01

    The food habits of Blue Grouse vary from a simple winter diet that is made up predominantly of coniferous needles to a complex diet during the summer months, characterized by great variety of foods including green leaves, fruits and seeds, flowers, animal matter and coniferous needles. The spring and fall, which represent the transition periods between these two, are characterized by feeding habits that are generally intermediate. The diets of the two species of Blue Grouse, Dendrugapus obscurus and Dendragapus juliginosus, are quite similar as far as major types of food are concerned, but they differ considerably in the species that are taken. Such differences reflect differences in the vegetation within the ecologic and geographic ranges occupied by the two species.

  6. Thermoluminescence (TL) of Egyptian Blue

    Energy Technology Data Exchange (ETDEWEB)

    Schvoerer, M.; Delavergne, M.-C.; Chapoulie, R.

    1988-01-01

    Egyptian Blue is a synthesized crystalline pictorial pigment with formula CaCuSi/sub 4/O/sub 10/. It has been used in Egypt and Mesopotamia from the 3rd millenium B.C. A preliminary experiment on a recently synthesized sample showed that this pigment is thermoluminescent after ..beta.. irradiation (/sup 90/Sr). As the signal intensity grows linearly with the administered dose within the temperature range commonly used in TL dating, we have been looking for this phenomenon from archaeological pigments. It was encountered with two samples found in excavation. From its intensity and stability we concluded that Egyptian Blue can be dated using TL. This first and positive result encouraged us to extend the method to other types of mineral pigments synthesized by early man, and to suggest that it may be used for direct dating of ancient murals.

  7. The Physics of the Blues

    Science.gov (United States)

    Gibson, J. Murray

    2009-03-01

    In looking at the commonalities between music and science, one sees that the musician's palette is based on the principles of physics. The pitch of a musical note is determined by the frequency of the sound wave. The scales that musicians use to create and play music can be viewed as a set of rules. What makes music interesting is how musicians develop those rules and create ambiguity with them. I will discuss the evolution of western musical scales in this context. As a particular example, ``Blue'' notes are very harmonic notes that are missing from the equal temperament scale. The techniques of piano blues and jazz represent the melding of African and Western music into something totally new and exciting. Live keyboard demonstrations will be used. Beyond any redeeming entertainment value the talk will emphasize the serious connections between science and art in music. Nevertheless tips will be accepted.

  8. Clinical application of sentinel lymph node biopsy under the guidance of contrast-enhanced ultrasound pins methylene blue in patients with breast cancer%超声造影结合亚甲蓝定位在乳腺癌前哨淋巴结活检中的应用

    Institute of Scientific and Technical Information of China (English)

    胡慧; 韦伟; 孙德胜; 刘荫华

    2013-01-01

    Objective To explore the application feasibility of contrast-emhanced ultrasound (CEUS) plus methylene blue in sentinel lymph node biopsy (SLNB) for breast cancer and determine the ultrasonographic features of sentinel lymph node (SLN).Methods The microbubbles of SonoVue were injected subcutaneously and intradermally into tumor side of areola.The images were observed to record the size,number,lymphatic door,aspect ratio,enhanced time and enhanced mode of SLN.Methylene blue was injected into SLN under the guidance of ultrasound.The marked SLNs were dissected for pathological examinations.Based upon the results,the specimens were divided into SLN metastasis and SLN nonmetastasis groups.Results A total of 34 breast cancer patients were recruited.Among them,SLN was detected preoperatively in 31 patients by CEUS and the rate was 91.2%.And the postoperative results showed that 14 were confirmed positive (metastasis group) and 17 negative (non-metastasis group).The sensitivity,specificity,accuracy and false negative rate of CEUS for detecting SLNs were 93.3% (14/15),100%(16/16),96.8% (30/31) and 6.7% (1/15) respectively.The model of stepwise regression analysis showed that lymphatic door,aspect ratio and enhanced mode were helpful to differentiate SLN metastasis and SLN nonmetastasis groups.Conclusions SLNB under the guidance of CEUS plus methylene blue offer prompt and accurate localization with a lower cost.It may enhance the detection rate of SLNB in breast cancer.%目的 探讨超声造影结合亚甲蓝行乳腺癌前哨淋巴结活检(SLNB)的可行性以及超声造影图像特征.方法 2011年10月至2012年5月北京大学深圳医院对34例乳腺癌患者在患侧乳晕区皮内及皮下注射造影剂,观察前哨淋巴结(SLN)超声造影增强情况,记录SLN大小、数量、淋巴门结构、纵横比、增强时间及增强模式;在B超声引导下对确定的SLN进行亚甲蓝定位后切除SLN,行病理检查,并根据有无肿瘤转移

  9. Chemical composition and bioreactivity of PM2.5 during 2013 haze events in China

    Science.gov (United States)

    Ho, Kin-Fai; Ho, Steven Sai Hang; Huang, Ru-Jin; Chuang, Hsiao-Chi; Cao, Jun-Ji; Han, Yongming; Lui, Ka-Hei; Ning, Zhi; Chuang, Kai-Jen; Cheng, Tsun-Jen; Lee, Shun-Cheng; Hu, Di; Wang, Bei; Zhang, Renjian

    2016-02-01

    Chemical composition and bioreactivity of PM2.5 samples collected from Beijing (BJ), Xi'an (XA), Xiamen (XM) and Hong Kong (HK) in China during haze events were characterized. PM2.5 mass concentrations in BJ, XA, XM and HK in the episodes were found to be 258 ± 100 μg m-3, 233 ± 52 μg m-3, 46 ± 9 μg m-3 and 48 ± 13 μg m-3, respectively. Significant increase of sulfate, nitrate and ammonium concentrations in northern cities were observed. High contributions of biomass burning emissions to organic carbon (OC) in northern cities were estimated in this study implying frequent biomass burning during the haze periods. The urea concentrations in PM2.5 were 1855 ± 755 ng m-3 (BJ), 1124 ± 243 ng m-3 (XA), 543 ± 104 ng m-3 (XM) and 363 ± 61 ng m-3 (HK) suggesting higher or close to upper limits compared to other regions in the world. Dose-dependent alterations in oxidative potential, IL-6, IFN-γ and TNF-α levels were also investigated. The oxidative potential levels are BJ > XM > XA > HK, whereas levels of IL-6, IFN-γ and TNF-α were BJ > XA > XM > HK. The sulfate, nitrate, ammonium, OC, urea and levoglucosan are associated with oxidative-inflammatory responses. These experimental results are crucial for the policymakers to implement cost-effective abatement strategies for improving air quality.

  10. Air quality in Southern Thailand during haze episode in relation to air mass trajectory

    Directory of Open Access Journals (Sweden)

    Prapat Pentamwa

    2008-07-01

    Full Text Available Southeast Asia haze with elevated particulate matter (PM10 often blankets Southern Thailand during June-Augustperiod. During the haze period of August 2005, the highest 24h PM10 concentration was 92 µg/m3 in Songkhla and 108 µg/m3in Phuket. Though the levels were still below the 24h PM10 National Ambient Air Quality Standard of 120 µg/m3, they wereconsiderably higher than the annual average levels of 32 µg/m3 in Songkhla and 56 µg/m3 in Phuket. The variation in dailyPM10 levels during this period was largely dependent on the prevailing wind directions and the intensity of fire, expressed asthe number of hotspots on NOAA satellite images, at the upwind regions. The backward trajectories obtained by HYSPLIT4model revealed that on the days when PM10 peaked the air masses arriving at the cities passed over the intensive fire regionin Sumatra Island. The peak PM10 levels were observed in Phuket on 16th and in Songkhla on 13th August 2005, i.e. duringthe same period when a large number of hotspots were seen in Sumatra Island of Indonesia (10th-16th August 2005. The PM10level dropped when the wind changed direction from southwesterly to southeasterly hence the air mass trajectory did notpass the fire region. The transport time of air masses from the source region to Southern Thailand during this period wasaround 2-3 days.

  11. Estimating the direct radiative forcing due to haze from the 1997 forest fires in Indonesia

    Science.gov (United States)

    Davison, P. S.; Roberts, D. L.; Arnold, R. T.; Colvile, R. N.

    2004-05-01

    The El Niño event of 1997-1998 caused a severe reduction of rainfall in Indonesia that promoted the spread of forest fires, leading to a pervasive haze in the region. Here we use fire coverage data from the 1997 World Fire Atlas with a review of other available data and literature to estimate the distribution of particulate emissions from August to November 1997 and the particle size and radiative properties. Our preferred estimate of the total particulate emissions is approximately 41 Tg. The emissions have been used to drive an atmospheric model to simulate the distribution of the haze and its direct radiative effect, with and without allowing for the effects of the smoke on the atmospheric evolution. Model diagnostics of the aerosol and its radiative impact are compared with measurements and output from other models. Large decreases in the incident solar flux at the surface are obtained in the region. The simulated global mean shortwave radiative forcing at the top of the atmosphere, averaged over the 4 months, is -0.32 Wm-2. The accuracy of this calculation is discussed, and the importance of the Indonesian fires in particular and of biomass burning in general is assessed.

  12. Mariner 9 television limb observations of dust and ice hazes on Mars

    International Nuclear Information System (INIS)

    Over 3000 Mariner 9 television reflectance profiles crossing the limb of Mars were analyzed statistically during the period from the decaying phase of a global dust storm (southern summer) until southern winter solstice. Most of the profiles were obtained during the first 100 days of the mission. The ''top'' of the dust, as defined by the inflection point in the reflectance profiles, decreased with time during the decay of the dust storm, but more rapidly in the higher latitudes of both hemispheres than in the tropics. The inflection point due to dust haze remained above 20 km in the tropics throughout the period. These variations support the hypothesis that the diurnal tide is the primary agent of vertical dust transport. Scale heights of the upper portion of the dust cloud were highest in the tropics early in the mission, decaying with time and/or depth in the atmosphere. If interpreted in terms of vertical eddy diffusion, the scale heights suggest diffusion coefficients of order 103 m2 s-1 in the 40--60 km height range. Distribution, color and polarization of higher limb hazes were also analyzed. These are interpreted as condensate layers associated with convective overshoot from the dusty lower atmosphere. A long internal gravity wave revealed by one of these layers is discussed

  13. Effect of heavy haze and aerosol pollution on rice and wheat productions in China.

    Science.gov (United States)

    Tie, Xuexi; Huang, Ru-Jin; Dai, Wenting; Cao, Junji; Long, Xin; Su, Xiaoli; Zhao, Shuyu; Wang, Qiyuan; Li, Guohui

    2016-01-01

    In China, regional haze pollution is a serious environmental problem. The impact on ecosystem, however, is not clearly understood. This study investigates the effect of regional haze pollution on the yields of rice and wheat in China. The spatial and temporal distributions of aerosol optical depth (AOD) show high particulate pollution in the North China Plain region, Yangtze River Delta region, the central eastern China, and the Si Chuan Basin, coexisted largely with crop growth in time and space. The solar irradiance reaching these regions is estimated to reduce by up to 28-49%, calculated using the AOD distributions and tropospheric ultraviolet-visible (TUV) model. Reduction of solar irradiance in these regions can depress optimal yields of about 45% of rice and 75% of wheat growth in China, leading to 2% reduction in total rice production and 8% reduction in total wheat production in China. However, there are large uncertainties of the estimate related to the diffuse solar radiation. For high diffuse radiation case, the estimate reductions of rice and wheat decrease to 1% and 4.5%, respectively. A further detailed study is needed to clearly understand this effect to meet the growing food demand in the nation in the coming decades. PMID:27388031

  14. Effect of heavy haze and aerosol pollution on rice and wheat productions in China

    Science.gov (United States)

    Tie, Xuexi; Huang, Ru-Jin; Dai, Wenting; Cao, Junji; Long, Xin; Su, Xiaoli; Zhao, Shuyu; Wang, Qiyuan; Li, Guohui

    2016-07-01

    In China, regional haze pollution is a serious environmental problem. The impact on ecosystem, however, is not clearly understood. This study investigates the effect of regional haze pollution on the yields of rice and wheat in China. The spatial and temporal distributions of aerosol optical depth (AOD) show high particulate pollution in the North China Plain region, Yangtze River Delta region, the central eastern China, and the Si Chuan Basin, coexisted largely with crop growth in time and space. The solar irradiance reaching these regions is estimated to reduce by up to 28-49%, calculated using the AOD distributions and tropospheric ultraviolet-visible (TUV) model. Reduction of solar irradiance in these regions can depress optimal yields of about 45% of rice and 75% of wheat growth in China, leading to 2% reduction in total rice production and 8% reduction in total wheat production in China. However, there are large uncertainties of the estimate related to the diffuse solar radiation. For high diffuse radiation case, the estimate reductions of rice and wheat decrease to 1% and 4.5%, respectively. A further detailed study is needed to clearly understand this effect to meet the growing food demand in the nation in the coming decades.

  15. Simulating Atmospheric Free-Space Optical Propagation; Part II: Haze, Fog, and Low Clouds Attenuations

    Science.gov (United States)

    Achour, Maha

    2002-12-01

    One of the biggest challenges facing Free-Space Optics deployment is proper understanding of optical signal propagation in different atmospheric conditions. In an earlier study by the author (30), attenuation by rain was analyzed and successfully modeled for infrared signal transmission. In this paper, we focus on attenuation due to scattering by haze, fog and low clouds droplets using the original Mie Scattering theory. Relying on published experimental results on infrared propagation, electromagnetic waves scattering by spherical droplet, atmospheric physics and thermodynamics, UlmTech developed a computer-based platform, Simulight, which simulates infrared signal (750 nm-12 μm) propagation in haze, fog, low clouds, rain and clear weather. Optical signals are scattered by fog droplets during transmission in the forward direction preventing the receiver from detecting the minimum required power. Weather databases describe foggy conditions by measuring the visibility parameter, which is, in general, defined as the maximum distance that the visible 550 nm signal can travel while distinguishing between the target object and its background at 2% contrast. Extrapolating optical signal attenuations beyond 550 nm using only visibility is not as straightforward as stated by the Kruse equation which is unfortunately widely used. We conclude that it is essential to understand atmospheric droplet sizes and their distributions based on measured attenuations to effectively estimate infrared attenuation. We focus on three types of popular fogs: Evolving, Stable and Selective.

  16. Degradation of white wine haze proteins by Aspergillopepsin I and II during juice flash pasteurization.

    Science.gov (United States)

    Marangon, Matteo; Van Sluyter, Steven C; Robinson, Ella M C; Muhlack, Richard A; Holt, Helen E; Haynes, Paul A; Godden, Peter W; Smith, Paul A; Waters, Elizabeth J

    2012-12-01

    Bentonite is commonly used to remove grape proteins responsible for haze formation in white wines. Proteases potentially represent an alternative to bentonite, but so far none has shown satisfactory activity under winemaking conditions. A promising candidate is AGP, a mixture of Aspergillopepsins I and II.; a food grade, well characterized and inexpensive protease, active at wine pH and at high temperatures (60-80°C). AGP was added to two clarified grape juices with and without heat treatments (75°C, 1min) prior to fermentation. AGP showed some activity at fermentation temperatures (≈20% total protein reduction compared to control wine) and excellent activity when combined with juice heating (≈90% total protein reduction). The more heat stable grape proteins, i.e. those not contributing to wine hazing, were not affected by the treatments and therefore accounted for the remaining 10% of protein still in solution after the treatments. The main physicochemical parameters and sensorial characteristics of wines produced with AGP were not different from controls.

  17. Approaches to prevent the patients with chronic airway diseases from exacerbation in the haze weather.

    Science.gov (United States)

    Ren, Jin; Li, Bo; Yu, Dan; Liu, Jing; Ma, Zhongsen

    2016-01-01

    Haze weather is becoming one of the biggest problems in many big cities in China. It triggers both public anxiety and official concerns. Particulate matter (PM) plays the most important role in causing the adverse health effects. Chemical composition of PM2.5 includes primary particles and secondary particles. The toxicological mechanisms of PM2.5 to the human body include the oxidative stress, inflammation and carcinogenesis. Short or long-term exposure to PM (especially PM2.5) can cause a series of symptoms including respiratory symptoms such as cough, wheezing and dyspnea as well as other symptoms. There are positive associations between PM2.5 and mortality due to a number of causes. PM2.5 is considered to contribute to the onset of asthma, the exacerbation of chronic obstructive pulmonary disease (COPD) in haze weather. Some approaches including outdoor health care, indoor health care and preventive medications can prevent the patients with chronic airway diseases from exacerbations.

  18. Critical role of meteorological conditions in a persistent haze episode in the Guanzhong basin, China.

    Science.gov (United States)

    Bei, Naifang; Xiao, Bo; Meng, Ning; Feng, Tian

    2016-04-15

    In the present study, the critical role of the meteorological condition in a persistent extreme haze episode that occurred in Guanzhong basin of China on December 16 to 25, 2013 has been investigated. Analyses of the large-scale meteorological conditions on 850hPa during the episode have been performed using the NCEP FNL data set, indicating that synoptic situations generally facilitate the accumulation of pollutants either in horizontal or vertical directions in the basin. The FLEXPART model has been utilized to illustrate the pollutant transport patterns during the episode, further showing the dominant role of synoptic conditions in accumulation of pollutants in the basin. Detailed meteorological conditions, such as temperature inversion, and low-level horizontal wind speed also contribute to the extreme haze episode. In addition, the WRF-CHEM model has been used to evaluate the responses of the surface PM2.5 level to the emission mitigation. Generally, the predicted PM2.5 spatial patterns and temporal variations agree well with the observations at the ambient monitoring sites. Sensitivity studies show that the emissions in the basin need to be mitigated by more than 91% to meet the excellent level of the China National Air Quality Standard under the extremely unfavorable meteorological conditions, demonstrating that it is imperative to implement stringent controls on emissions to improve the air quality.

  19. Impact of haze-fog days to radon progeny equilibrium factor and discussion of related factors.

    Science.gov (United States)

    Hou, Changsong; Shang, Bing; Zhang, Qingzhao; Cui, Hongxing; Wu, Yunyun; Deng, Jun

    2015-11-01

    The equilibrium factor F between radon and its short-lived progenies is an important parameter to estimate radon exposure of humans. Therefore, indoor and outdoor concentrations of radon and its short-lived radon progeny were measured in Beijing area using a continuously measuring device, in an effort to obtain information on the F value. The results showed that the mean values of F were 0.58 ± 0.13 (0.25-0.95, n = 305) and 0.52 ± 0.12 (0.31-0.91, n = 64) for indoor and outdoor, respectively. The indoor F value during haze-fog days was higher than the typical value of 0.4 recommended by the United Nations Scientific Committee on the Effects of Atomic Radiation, and it was also higher than the values of 0.47 and 0.49 reported in the literature. A positive correlation was observed between indoor F values and PM2.5 concentrations (R (2) = 0.71). Since 2013, owing to frequent heavy haze-fog events in Beijing and surrounding areas, the number of the days with severe pollution remains at a high level. Future studies on the impact of the ambient fine particulate matter on indoor radon progeny equilibrium factor F could be important.

  20. Effect of heavy haze and aerosol pollution on rice and wheat productions in China.

    Science.gov (United States)

    Tie, Xuexi; Huang, Ru-Jin; Dai, Wenting; Cao, Junji; Long, Xin; Su, Xiaoli; Zhao, Shuyu; Wang, Qiyuan; Li, Guohui

    2016-07-08

    In China, regional haze pollution is a serious environmental problem. The impact on ecosystem, however, is not clearly understood. This study investigates the effect of regional haze pollution on the yields of rice and wheat in China. The spatial and temporal distributions of aerosol optical depth (AOD) show high particulate pollution in the North China Plain region, Yangtze River Delta region, the central eastern China, and the Si Chuan Basin, coexisted largely with crop growth in time and space. The solar irradiance reaching these regions is estimated to reduce by up to 28-49%, calculated using the AOD distributions and tropospheric ultraviolet-visible (TUV) model. Reduction of solar irradiance in these regions can depress optimal yields of about 45% of rice and 75% of wheat growth in China, leading to 2% reduction in total rice production and 8% reduction in total wheat production in China. However, there are large uncertainties of the estimate related to the diffuse solar radiation. For high diffuse radiation case, the estimate reductions of rice and wheat decrease to 1% and 4.5%, respectively. A further detailed study is needed to clearly understand this effect to meet the growing food demand in the nation in the coming decades.

  1. Effect of heavy haze and aerosol pollution on rice and wheat productions in China

    Science.gov (United States)

    Tie, Xuexi; Huang, Ru-Jin; Dai, Wenting; Cao, Junji; Long, Xin; Su, Xiaoli; Zhao, Shuyu; Wang, Qiyuan; Li, Guohui

    2016-07-01

    In China, regional haze pollution is a serious environmental problem. The impact on ecosystem, however, is not clearly understood. This study investigates the effect of regional haze pollution on the yields of rice and wheat in China. The spatial and temporal distributions of aerosol optical depth (AOD) show high particulate pollution in the North China Plain region, Yangtze River Delta region, the central eastern China, and the Si Chuan Basin, coexisted largely with crop growth in time and space. The solar irradiance reaching these regions is estimated to reduce by up to 28–49%, calculated using the AOD distributions and tropospheric ultraviolet-visible (TUV) model. Reduction of solar irradiance in these regions can depress optimal yields of about 45% of rice and 75% of wheat growth in China, leading to 2% reduction in total rice production and 8% reduction in total wheat production in China. However, there are large uncertainties of the estimate related to the diffuse solar radiation. For high diffuse radiation case, the estimate reductions of rice and wheat decrease to 1% and 4.5%, respectively. A further detailed study is needed to clearly understand this effect to meet the growing food demand in the nation in the coming decades.

  2. Approaches to prevent the patients with chronic airway diseases from exacerbation in the haze weather.

    Science.gov (United States)

    Ren, Jin; Li, Bo; Yu, Dan; Liu, Jing; Ma, Zhongsen

    2016-01-01

    Haze weather is becoming one of the biggest problems in many big cities in China. It triggers both public anxiety and official concerns. Particulate matter (PM) plays the most important role in causing the adverse health effects. Chemical composition of PM2.5 includes primary particles and secondary particles. The toxicological mechanisms of PM2.5 to the human body include the oxidative stress, inflammation and carcinogenesis. Short or long-term exposure to PM (especially PM2.5) can cause a series of symptoms including respiratory symptoms such as cough, wheezing and dyspnea as well as other symptoms. There are positive associations between PM2.5 and mortality due to a number of causes. PM2.5 is considered to contribute to the onset of asthma, the exacerbation of chronic obstructive pulmonary disease (COPD) in haze weather. Some approaches including outdoor health care, indoor health care and preventive medications can prevent the patients with chronic airway diseases from exacerbations. PMID:26904232

  3. Organic composition of aerosol particulate matter during a haze episode in Kuala Lumpur, Malaysia

    Science.gov (United States)

    Radzi Bin Abas, M.; Rahman, Noorsaadah A.; Omar, Nasr Yousef M. J.; Maah, M. Jamil; Abu Samah, Azizan; Oros, Daniel R.; Otto, Angelika; Simoneit, Bernd R. T.

    The solvent-extractable compounds of urban airborne particulate matter were analyzed to determine the distributions of homologous and biomarker tracers. Samples were collected by high-volume air filtration during the haze episode of 1997 around the University of Malaya campus near Petaling Jaya, a suburb of Kuala Lumpur, Malaysia. These results show that the samples contain n-alkanes, n-alkan-2-ones, n-alkanols, methyl n-alkanoates, n-alkyl nitriles, n-alkanals, n-alkanoic acids, levoglucosan, PAHs, and UCM as the dominant components, with minor amounts of terpenoids, glyceryl esters and sterols, all derived from natural biogenic sources (vascular plant wax), from burning of biomass, and from anthropogenic utilization of fossil fuel products (lubricating oil, vehicle emissions, etc.). Some compositional differences are observed in the samples and greater atmospheric concentrations were found for almost all organic components in the samples collected near a roadway. The results interpreted in terms of major sources are due to local build-up of organic contaminants from vehicular emissions, smoke from biomass burning, and natural background as a result of the atmospheric stability during the haze episodes. The organic components transported in from areas outside the region, assuming all smoke components are external to the city, amount to about 30% of the total organic particle burden.

  4. Localized Eruptive Blue Nevi after Herpes Zoster

    Science.gov (United States)

    Colson, Fany; Arrese, Jorge E.; Nikkels, Arjen F.

    2016-01-01

    A 52-year-old White man presented with a dozen small, well-restricted, punctiform, asymptomatic, blue-gray macules on the left shoulder. A few months earlier, he had been treated with oral acyclovir for herpes zoster (HZ) affecting the left C7–C8 dermatomes. All the blue macules appeared over a short period of time and then remained stable. The patient had not experienced any previous trauma or had tattooing in this anatomical region. The clinical diagnosis suggested blue nevi. Dermatoscopy revealed small, well-limited, dark-blue, compact, homogeneous areas evoking dermal blue nevi. An excisional biopsy was performed and the histological examination confirmed a blue nevus. As far as we are aware of, this is the first report of eruptive blue nevi following HZ, and it should be included in the differential diagnosis of zosteriform dermatoses responding to an isotopic pathway. In addition, a brief review concerning eruptive nevi is presented. PMID:27462219

  5. Inflation and alternatives with blue tensor spectra

    International Nuclear Information System (INIS)

    We study the tilt of the primordial gravitational waves spectrum. A hint of blue tilt is shown from analyzing the BICEP2 and POLARBEAR data. Motivated by this, we explore the possibilities of blue tensor spectra from the very early universe cosmology models, including null energy condition violating inflation, inflation with general initial conditions, and string gas cosmology, etc. For the simplest G-inflation, blue tensor spectrum also implies blue scalar spectrum. In general, the inflation models with blue tensor spectra indicate large non-Gaussianities. On the other hand, string gas cosmology predicts blue tensor spectrum with highly Gaussian fluctuations. If further experiments do confirm the blue tensor spectrum, non-Gaussianity becomes a distinguishing test between inflation and alternatives

  6. Fractionation of airborne particulate-bound elements in haze-fog episode and associated health risks in a megacity of southeast China.

    Science.gov (United States)

    Li, Huiming; Wang, Qin'geng; Shao, Min; Wang, Jinhua; Wang, Cheng; Sun, Yixuan; Qian, Xin; Wu, Hongfei; Yang, Meng; Li, Fengying

    2016-01-01

    Haze caused by high particulate matter loadings is an important environmental issue. PM2.5 was collected in Nanjing, China, during a severe haze-fog event and clear periods. The particulate-bound elements were chemically fractionated using sequential extractions. The average PM2.5 concentration was 3.4 times higher during haze-fog (96-518 μg/m(3)) than non-haze fog periods (49-142 μg/m(3)). Nearly all elements showed significantly higher concentrations during haze-fog than non-haze fog periods. Zn, As, Pb, Cd, Mo and Cu were considered to have higher bioavailability and enrichment degree in the atmosphere. Highly bioavailable fractions of elements were associated with high temperatures. The integrated carcinogenic risk for two possible scenarios to individuals exposed to metals was higher than the accepted criterion of 10(-6), whereas noncarcinogenic risk was lower than the safe level of 1. Residents of a city burdened with haze will incur health risks caused by exposure to airborne metals.

  7. A model study of smoke-haze influence on clouds and warm precipitation formation in Indonesia 1997/1998

    Science.gov (United States)

    Langmann, Bärbel

    In the last few decades, fire and smoke-haze occurrence increased in Indonesia by intentionally set land clearing fires and higher fire susceptibility of disturbed forests. Particularly, during El Niño years with prolonged droughts in Indonesia, land clearing fires become uncontrolled wildfires and produce large amounts of gaseous and particulate emissions. This paper investigates the influence of smoke-haze aerosols from such fires on clouds and precipitation over Indonesia during the El Niño event 1997/1998 by numerical modelling. Warm precipitation formation in both layered and convective clouds is calculated dependent on the atmospheric aerosol concentration. In the smoke-haze affected regions of Indonesia, aerosol-cloud interactions induce events with both precipitation suppression and increase compared to a reference simulation without aerosol-cloud interactions. The effect of precipitation suppression is found to dominate with about 2/3 of all precipitation modification events pointing to a prolongation of smoke-haze episodes. The corresponding convective cloud top height of shallow clouds is increased whereas distinct lower deep convective cloud top heights are found. The remaining about 1/3 events are characterised by increased precipitation and cloud liquid water content, accompanied by lower convective cloud top heights of shallow clouds and higher deep convective clouds.

  8. Effective prevention of chill-haze in beer using an acid proline-specific endoprotease from Aspergillus niger.

    Science.gov (United States)

    Lopez, Michel; Edens, Luppo

    2005-10-01

    Chill-haze formation during beer production is known to involve polyphenols that interact with proline-rich proteins. We hypothesized that incubating beer wort with a proline-specific protease would extensively hydrolyze these proline-rich proteins, yielding a peptide fraction that is unable to form a haze. Predigestion of the proline-rich wheat gliadin with different proteases pointed toward a strong haze-suppressing effect by a proline-specific enzyme. This finding was confirmed in small-scale brewing experiments using a recently identified proline-specific protease with an acidic pH optimum. Subsequent pilot plant trials demonstrated that, upon its addition during the fermentation phase of beer brewing, even low levels of this acidic enzyme effectively prevented chill-haze formation in bottled beer. Results of beer foam stability measurements indicated that the enzyme treatment leaves the beer foam almost unaffected. In combination with the enzyme's cost-effectiveness and regulatory status, these preliminary test results seem to favor further industrial development of this enzymatic beer stabilization method.

  9. Investigating the impact of haze on cloud detection of passive satellite by comparing MODIS, CloudSat and CALIPSO

    Science.gov (United States)

    Gong, W.; Mao, F.

    2015-12-01

    The cloud detection algorithm for passive sensors is usually based on a fuzzy logic system with thresholds determined from previous observations. In recent years, haze and high aerosol concentrations with high AOD occur frequently in China and may critically impact the accuracy of the MODIS cloud detection. Thus, we comprehensively explore this impact by comparing the results from MODIS/Aqua (passive sensor), CALIOP/CALIPSO (lidar sensor), and CPR/CloudSat (microwave sensor) of the A-Train suite of instruments using an averaged AOD as an index for an aerosol concentration value. Case studies concerning the comparison of the three sensors indicate that MODIS cloud detection is reduced during haze events. In addition, statistical studies show that an increase in AOD creates an increase in the percentage of uncertain flags and a decrease in hit rate, a consistency index between consecutive sets of cloud retrievals. Therefore, we can conclude that the ability of MODIS cloud detection is weakened by large concentrations of aerosols. This suggests that use of the MODIS cloud mask, and derived higher level products, in situations with haze requires caution. Further improvement of this retrieval algorithm, is desired as haze studies based on MODIS products are of great interest in a number of related fields.

  10. Hoe hoger de haze bij diffuus glas, hoe hoger de meerproductie (interview met Jan Janse en Sonny Moerenhout)

    NARCIS (Netherlands)

    Kierkels, T.; Janse, J.; Moerenhout, S.

    2012-01-01

    Een vroege komkommerteelt onder diffuus glas gaf vanaf het begin een grotere opbrengst dan onder gewoon glas. Jan Janse van Wageningen UR Glastuinbouw durft na de reeks proeven in de afgelopen jaren de conclusie te trekken: hoe hoger de haze, hoe hoger de meerproductie. Dus ook in een vroege teelt.

  11. Polish Terms for "Blue" in the Perspective of Vantage Theory

    Science.gov (United States)

    Stanulewicz, Danuta

    2010-01-01

    The Polish set of terms for blue includes, inter alia, the following adjectives: "niebieski" "blue", "blekitny" "(sky) blue", "granatowy" "navy blue", "lazurowy" "azure", "modry" "(intense) blue" and "siny" "(grey) violet-blue". The adjective "niebieski" is the basic term; however, it shares some of its functions with "blekitny", which is…

  12. Characteristics and formation mechanism of continuous extreme hazes in China: a case study in autumn of 2014 in the North China Plain

    Directory of Open Access Journals (Sweden)

    Y. R. Yang

    2015-04-01

    Full Text Available Four extreme haze episodes occurred in October 2014 in the North China Plain (NCP. To clarify the formation mechanism of hazes in the autumn, strengthened observations were conducted in Beijing from 5 October to 2 November. The meteorological parameters, satellite data, chemical compositions and optical properties of aerosols were obtained. The hazes originated from NCP, developing in the southwest and northeast directions, with the highest concentration of PM2.5 of 469 μg m−3 in Beijing. NCP was dominated by a weak high pressure system during the haze episode, which resulted in low surface wind speed and relatively stagnant weather. Moreover, the wind slowed down around Beijing city. The secondary aerosols NO3− was always higher than that of SO42−, which indicated the motor vehicles played a more important part in the hazes in October 2014, even though the oxidation rate from SO2 to SO42− was faster than that of NOx to NO3−. Sudden increases of the concentrations of organic matter, Cl− and BC (Black carbon before each haze episode implied that regional transport of pollutants by biomass burning was important for haze formation during the autumn. A satellite map of fire points and the backward trajectories of the air masses also indicated this pollution source. The distinct decrease in the PBL (planetary boundary layer height during four haze episodes restrained the vertical dispersion of the air pollutants. Water vapor also played a vital role in the formation of hazes by accelerating the chemical transformation of secondary pollutants, leading to hygroscopic growth of aerosols and altering the thermal balance of the atmosphere.

  13. Characteristics and formation mechanism of continuous hazes in China: a case study during the autumn of 2014 in the North China Plain

    Science.gov (United States)

    Yang, Y. R.; Liu, X. G.; Qu, Y.; An, J. L.; Jiang, R.; Zhang, Y. H.; Sun, Y. L.; Wu, Z. J.; Zhang, F.; Xu, W. Q.; Ma, Q. X.

    2015-07-01

    Four extreme haze episodes occurred in October 2014 in the North China Plain (NCP). To clarify the formation mechanism of hazes in autumn, strengthened observations were conducted in Beijing from 5 October to 2 November. The meteorological parameters, satellite data, chemical compositions and optical properties of aerosols were obtained. The hazes originated from the NCP, developing in the southwest and northeast directions, with the highest concentration of PM2.5 of 469 μg m-3 in Beijing. The NCP was dominated by a weak high pressure system during the haze episode, which resulted in low surface wind speed and relatively stagnant weather. Moreover, the wind slowed down around Beijing city. The secondary aerosols NO3- was always higher than that of SO42-, which indicated the motor vehicles played a more important part in the hazes in October 2014, even though the oxidation rate from SO2 to SO42- was faster than that of NOx to NO3-. Sudden increases of the concentrations of organic matter, Cl- and BC (black carbon) before each haze episode implied that regional transport of pollutants by biomass burning was important for haze formation during autumn. A satellite map of fire points and the backward trajectories of the air masses also indicated this pollution source. The distinct decrease in the PBL (planetary boundary layer) height during four haze episodes restrained the vertical dispersion of the air pollutants. Water vapor also played a vital role in the formation of hazes by accelerating the chemical transformation of secondary pollutants, leading to hygroscopic growth of aerosols and altering the thermal balance of the atmosphere.

  14. Study on governance of water resources and haze pollution%水资源与雾霾污染治理研究

    Institute of Scientific and Technical Information of China (English)

    张春华

    2015-01-01

    近年来,随着雾霾的频繁发生,水资源的污染更加严重。在阐述雾霾对水资源影响的基础上,提出了水资源与雾霾污染的同步治理。%In recent years, pollution of water resources is more serious with the frequent occurrence of haze, through the analy-sis of influence of haze on water resources, we suggest the simultaneous governance of water resources and haze pollution.

  15. Evolution process and sources of ambient volatile organic compounds during a severe haze event in Beijing, China.

    Science.gov (United States)

    Wu, Rongrong; Li, Jing; Hao, Yufang; Li, Yaqi; Zeng, Limin; Xie, Shaodong

    2016-08-01

    108 ambient volatile organic compounds (VOCs) were measured continuously at a time resolution of an hour using an online gas chromatography-frame ionization detector/mass spectrometry (GC-FID/MS) in October 2014 in Beijing, and positive matrix factorization (PMF) was performed with online data. The evolution process and causes for high levels of VOCs during a haze event were investigated through comprehensive analysis. Results show that mixing ratios of VOCs during the haze event (89.29 ppbv) were 2 to 5 times as that in non-haze days, There was a distinct accumulation process of VOCs at the beginning of the haze event, and the mixing ratios of VOCs maintained at the high levels until to the end of pollution when the mixing ratios of ambient VOCs recovered to the normal concentration levels in a few hours. Some reactive and toxic species increased remarkably as well, which indicates a potential health risk to the public in terms of VOCs. Eight sources were resolved by PMF, and results revealed gasoline exhaust was the largest contributor (32-46%) to the ambient VOCs in Beijing. Emissions of gasoline exhaust surged from 13.46 to 40.36 ppbv, with a similar variation pattern to total VOCs, indicating that high levels of VOCs were largely driven to by expanded vehicular emissions. Emissions of biomass burning also increased noticeably (from 2.32 to 11.12 ppbv), and backward trajectories analysis indicated regional transport of biomass burning emissions. Our findings suggested that extremely high levels of VOCs during the haze event was primarily attributed to vehicular emissions, biomass burning and regional transport, as well as stationary synoptic conditions. PMID:27093124

  16. Evolution process and sources of ambient volatile organic compounds during a severe haze event in Beijing, China.

    Science.gov (United States)

    Wu, Rongrong; Li, Jing; Hao, Yufang; Li, Yaqi; Zeng, Limin; Xie, Shaodong

    2016-08-01

    108 ambient volatile organic compounds (VOCs) were measured continuously at a time resolution of an hour using an online gas chromatography-frame ionization detector/mass spectrometry (GC-FID/MS) in October 2014 in Beijing, and positive matrix factorization (PMF) was performed with online data. The evolution process and causes for high levels of VOCs during a haze event were investigated through comprehensive analysis. Results show that mixing ratios of VOCs during the haze event (89.29 ppbv) were 2 to 5 times as that in non-haze days, There was a distinct accumulation process of VOCs at the beginning of the haze event, and the mixing ratios of VOCs maintained at the high levels until to the end of pollution when the mixing ratios of ambient VOCs recovered to the normal concentration levels in a few hours. Some reactive and toxic species increased remarkably as well, which indicates a potential health risk to the public in terms of VOCs. Eight sources were resolved by PMF, and results revealed gasoline exhaust was the largest contributor (32-46%) to the ambient VOCs in Beijing. Emissions of gasoline exhaust surged from 13.46 to 40.36 ppbv, with a similar variation pattern to total VOCs, indicating that high levels of VOCs were largely driven to by expanded vehicular emissions. Emissions of biomass burning also increased noticeably (from 2.32 to 11.12 ppbv), and backward trajectories analysis indicated regional transport of biomass burning emissions. Our findings suggested that extremely high levels of VOCs during the haze event was primarily attributed to vehicular emissions, biomass burning and regional transport, as well as stationary synoptic conditions.

  17. Long-term trend of haze pollution and impact of particulate matter in the Yangtze River Delta, China

    International Nuclear Information System (INIS)

    Haze pollution caused by heavy particulate matter (PM) loading brings significant damage in eastern China. Long-term monitoring from 1980 to 2011 and 1-year field measurement in 2011–2012 are used for investigating visibility variation and the impact of PM pollution for the Yangtze River Delta (YRD). It was found that visual range in the YRD endured a sharp reduction from 13.2 km to 10.5 km during 1980–2000. Average mass extinction efficiency (MEE) for inhalable PM (PM10) is 2.25 m2/g in 2001–2011, and extinction coefficient due to PM10 is 207 Mm−1, accounting for 36.2% of total extinction coefficient. MEE of PM2.5 and PM2.5–10 are 4.08 m2/g and 0.58 m2/g, respectively. Extinction coefficient due to PM2.5 and PM2.5–10 is 198 Mm−1 (39.6%) and 20 Mm−1 (4.0%) in 2011–2012. Maximum daily concentration of PM10 and PM2.5 is estimated to be 63 μg/m3 (RH: 73%) and 38 μg/m3 (RH: 70%) to keep visual range above 10 km. Fine particulate matter is the key factor for haze pollution improvement in the YRD area. -- Highlights: •Long-term visual range variation and its causes in the Yangtze River Delta are analyzed. •Quantitative contribution of particulate matter to haze pollution is estimated. •Mass extinction efficiency of PM10, PM2.5, and PM2.5–10 is estimated. -- The long-term variation of haze pollution in the YRD and its cause is investigated and the quantitative contribution of particulate matter to haze pollution is estimated

  18. Laboratory Investigations of Titan Haze Formation: Characterization of Gas Phase and Particle Phase Nitrogen

    Science.gov (United States)

    Horst, Sarah; Yoon, Heidi; Li, Rui; deGouw, Joost; Tolbert, Margaret

    2014-11-01

    Prior to the arrival of the Cassini-Huygens spacecraft, aerosol production in Titan’s atmosphere was believed to begin in the stratosphere where chemical processes are predominantly initiated by far ultraviolet (FUV) radiation. However, the discovery of very heavy ions, coupled with Cassini Ultraviolet Imaging Spectrograph (UVIS) occultation measurements that show haze absorption up to 1000 km altitude (Liang et al., 2007), indicates that haze formation initiates in the thermosphere. The energy environment of the thermosphere is significantly different from the stratosphere; in particular there is a greater flux of extreme ultraviolet (EUV) photons and energetic particles available to initiate chemical reactions, including the destruction of N2, in the upper atmosphere. The discovery of previously unpredicted nitrogen species in measurements of Titan’s atmosphere by the Cassini Ion and Neutral Mass Spectrometer (INMS) indicates that nitrogen participates in the chemistry to a much greater extent than was appreciated before Cassini (Vuitton et al., 2007). Additionally, measurements obtained by the Aerosol Collector Pyrolyzer (ACP) carried by Huygens to Titan’s surface may indicate that Titan’s aerosols contain significant amounts of nitrogen (Israël et al., 2005, 2006). The degree of nitrogen incorporation in the haze particles is important for understanding the diversity of molecules that may be present in Titan’s atmosphere and on its surface. We have conducted a series of Titan atmosphere simulation experiments using either spark discharge (tesla coil) or FUV photons (deuterium lamp) to initiate chemistry in CH4/N2 gas mixtures ranging from 0.01% CH4/99.99% N2 to 10% CH4/90% N2. We obtained in situ measurements using a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) to measure the particle composition as a function of particle size and a proton-transfer ion-trap mass spectrometer (PIT-MS) to measure the composition of gas phase

  19. Various Shades of Blue's Functions

    CERN Document Server

    Janik, R A; Papp, G; Zahed, I; Janik, Romuald A.; Nowak, Maciej A.; Papp, Gabor; Zahed, Ismail

    1997-01-01

    We discuss random matrix models in terms of elementary operations on Blue's functions (functional inverse of Green's functions). We show that such operations embody the essence of a number of physical phenomena whether at/or away from the critical points. We illustrate these assertions by borrowing on a number of recent results in effective QCD in vacuum and matter. We provide simple physical arguments in favor of the universality of the continuum QCD spectral oscillations, whether at zero virtuality, in the bulk of the spectrum or at the chiral critical points. We also discuss effective quantum systems of disorder with strong or weak dissipation (Hatano-Nelson localization).

  20. Regional Haze

    Science.gov (United States)

    This indicator presents visibility trends measured at 41 locations in National Parks and Wilderness Areas between 1992 and 2008. Visibility impairment is caused by air pollution, especially particulate matter pollution, and limits the distance one can see and degrades the colo...