WorldWideScience

Sample records for bitumen waterproofing industry

  1. Concrete waterproofing in nuclear industry.

    Science.gov (United States)

    Scherbyna, Alexander N; Urusov, Sergei V

    2005-01-01

    One of the main points of aggregate safety during the transportation and storage of radioactive materials is to supply waterproofing for all constructions having direct contact with radiating substances and providing strength, seismic shielding etc. This is the problem with all waterside structures in nuclear industry and concrete installations in the treatment and storage of radioactive materials. In this connection, the problem of developing efficient techniques both for the repair of operating constructions and the waterproofing of new objects of the specified assignment is genuine. Various techniques of concrete waterproofing are widely applied in the world today. However, in conditions of radiation many of these techniques can bring not a profit but irreparable damage of durability and reliability of a concrete construction; for instance, when waterproofing materials contain organic constituents, polymers etc. Application of new technology or materials in basic construction elements requires in-depth analysis and thorough testing. The price of an error might be very large. A comparative analysis shows that one of the most promising types of waterproofing materials for radiation loaded concrete constructions is "integral capillary systems" (ICS). The tests on radiation, thermal and strength stability of ICS and ICS-treated concrete samples were initiated and fulfilled in RFNC-VNIITF. The main result is--ICS applying is increasing of waterproofing and strength properties of concrete in conditions of readiation The paper is devoted to describing the research strategy, the tests and their results and also to planning of new tests. PMID:16604701

  2. Physico-chemical modification of asphalt bitumens by reactive agents

    OpenAIRE

    Cuadri Vega, Antonio Abad

    2013-01-01

    Bitumen, a by-product from crude oil distillation, has long been used in numerous engineering applications that range from the construction of road pavements to waterproof membranes for the roofing industry. On account of its properties (impermeability, adhesiveness, elasticity, ductility, etc.), bitumen is the most suitable material to be used as a binder of mineral aggregates for paving industry, and consequently, roads are mainly constructed using a composite mixture of bitumen (~ 5 wt.%) ...

  3. Study of radioactivity diffusion for bitumen-coated blocks produced by an industrial coating plant

    International Nuclear Information System (INIS)

    The solidification by bitumen of chemical coprecipitation sludges from the Marcoule waste treatment station has been studied in the laboratory and has led to the construction of an industrial coating plant. The quality of the coated material obtained has been controlled by the lixiviation test carried out with ordinary water and with sea-water on 45 ml laboratory samples and on industrial coated blocks of 150 litres. Tests on blocks of such a size have necessitated the installation of three special tanks. Two, each of 2000 litres capacity, contain ordinary and sea-water which was continuously recycled at a rate of 2.5 cm/hr and renewed periodically. In the third tank having a capacity of 11000 litres, the coated block was buried in earth and sprinkled with ordinary water with a view to studying the migration of radioelements in soil. The results of these tests confirm those obtained during the laboratory experiments. (authors)

  4. Market Brief : The insulation and waterproofing products market in Italy

    International Nuclear Information System (INIS)

    The use of thermal insulation in buildings in Italy is among the lowest in Western Europe. Soon, operational regulations will be in place, creating considerable opportunity for Canadian companies interested in gaining access to the Italian market through materials that provide better insulation and waterproofing for existing buildings. Approximately three fifths of the Italian insulation demand is for foamed plastics. Areas with strong commercial potential include products such as lightweight acoustic insulation materials, polymer bitumen membranes, fire-retardant foam plastic insulation, water-based waterproofing products as well as advanced waterproofing products. In 1999, the demand for insulation in Italy reached 352 million square metres of R-1 value. Currently, the most active exporters to Italy are neighbouring European countries. Italy's leading domestic insulation manufacturers are Saint-Gobin-Isover Italia, Dow, BASF and Sirap Gema. Italian industry experts recognize that in addition to heat savings, thermal insulation in buildings can contribute to reducing carbon dioxide emissions through energy efficiency. Demand for insulation products in Italy is expected to grow by 2.6 per cent per year through 2004. Demand is expected to reach $814 million in 2004. Approximately 3500 apartment buildings are in need of major renovations due to their age and because of poor construction systems used in the 1960s. Canadian imports of insulation and waterproofing products to Europe are recognized for their high quality and innovation. However, transportation costs are generally prohibitive. In January 2001, Canada Mortgage and Housing Corporation signed a Memorandum of Understanding with the Italian government to promote and extend exchange of information on building standards and practices, increasing Canada-Italy collaboration within the building sector. 1 tab

  5. Cooee bitumen:

    DEFF Research Database (Denmark)

    Lemarchand, Claire; Schrøder, Thomas; Dyre, J. C.; Hansen, Jesper Schmidt

    2013-01-01

    We study chemical aging in “Cooee bitumen” using molecular dynamic simulations. This model bitumen is composed of four realistic molecule types: saturated hydrocarbon, resinous oil, resin, and asphaltene. The aging reaction is modelled by the chemical reaction: “2 resins → 1 asphaltene.” Molecular...... dynamic simulations of four bitumen compositions, obtained by a repeated application of the aging reaction, are performed. The stress autocorrelation function, the fluid structure, the rotational dynamics of the plane aromatic molecules, and the diffusivity of each molecule are determined for the four...

  6. Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation

    Science.gov (United States)

    Tumanyan, B. P.; Petrukhina, N. N.; Kayukova, G. P.; Nurgaliev, D. K.; Foss, L. E.; Romanov, G. V.

    2015-11-01

    The results of studies of alterations in the elemental and SARA compositions and physicochemical and rheological properties of highly viscous heavy crude oils upon catalytic and non-catalytic aquathermolysis are generalized. The chemistry of transformations of model hydrocarbons and heteroatomic compounds in aqueous media at high temperature, including subcritical and supercritical conditions, is considered. Comparative analysis of methods for activation of oil conversion via aquathermolysis using hydrogen donors, oil-soluble and water-soluble nanodispersed catalysts, ionic hydrogenation processes and various ways for reservoir heating is presented. Problems and prospects of oil-field implementation of catalytic aquathermolysis for upgrading heavy oils and natural bitumen are discussed. The bibliography includes 234 references.

  7. Waterproofing EMG Instrumentation.

    Science.gov (United States)

    Benfield, Rebecca D; Newton, Edward R; Hortobágyi, Tibor

    2007-01-01

    While still experimental, measurement of external uterine electromyographic (EMG) activity is a more sensitive and noninvasive method for measuring uterine contractility in human labor than the methods currently used in clinical practice. Hydrotherapy is purported to improve contractility in labor, yet there have been no reports of abdominal uterine EMG activity measured during immersion. To test telemetric EMG equipment and different waterproofing techniques under dry and immersed conditions, the authors recorded surface EMG activity from the abdominal muscles of 11 healthy, nonpregnant women, 22 to 51 years of age. After attaching one pair of electrodes to the skin on either side of the umbilicus and applying the waterproofing material, the authors tested the signal by asking participants to perform a short series of leg lifts while seated in a chair to evoke abdominal muscle contractions. They were then immersed to the chest in a hydrotherapy tub while performing two to three leg lifts over 60 s every 5 min for 60 min with 20 lb of weight suspended from their ankles to counteract the buoyancy effect of water. EMG activity was continuously recorded. They then repeated the dry-measures sequence. While waterproofing remained intact, EMG signals were essentially unchanged between dry and wet conditions. Of the 11 waterproofing applications tested, 10 failed at some point. In the data from the successful application, EMG signals in both channels exhibited stable baselines throughout and an absence of low-frequency artifact. The development of this technique allows for the recording of external uterine EMG activity during hydrotherapy. The authors have begun using it to investigate the effects of hydrotherapy on uterine contractility during human labor. PMID:17172318

  8. Development of Techniques for Separating Waterproof Layer from XLPE Cable Sheath by Hot Water Heating

    Science.gov (United States)

    Okazaki, Masato; Nakade, Masahiko; Okashita, Minoru; Tanimoto, Mihoko

    Waterproof layer is used to prevent penetration of water which is one of the factors of dielectric breakdown in XLPE cables more than 66kV class. A XLPE cable sheath with waterproof layer is done landfill disposal as industrial waste because separation of waterproof layer is difficult for technology and cost. However, around 20 years passes after waterproof layer was introduced, and social consciousness for environment changes during these 20 years, and responsibility of company for environment of a society grows bigger. We report the result that examined techniques for separating waterproof layer.

  9. Impact of salinity on bitumen extraction

    Energy Technology Data Exchange (ETDEWEB)

    Kaminsky, H.A.W; Schaffer, M. [Total EandP Canada Ltd (Canada); Gingras, J.P. [TOTAL Petrochemicals Mont-Lacq Research and Development (France)

    2011-07-01

    In the oil sands industry, the hot water extraction process is used to extract bitumen. Recovery of bitumen is thus dependent on the water chemistry. Previous studies identified that divalent cations such as calcium present in water have a negative effect on bitumen recovery but the effect of monovalent cations such as sodium at high concentrations is still unknown. This paper assessed the potential impact of both monovalent and divalent cations on bitumen recovery. Extraction tests were conducted with two low grade and one average grade ore and with different water chemistries. Results showed that monovalent cations can have a negative impact on bitumen recovery for specific ore types. The study was not successful in determining the responsible mechanism but it is presumed to be related to coagulation of fine clays. This paper highlighted that monovalent cations can impact the bitumen recovery; further work is required to determine the responsible factors.

  10. Bitumen pyrolysis

    International Nuclear Information System (INIS)

    In the past bitumen was a preferred matrix for the embedding of low and intermediate level radioactive waste: its geological history promised long term stability in final repositories. A great variety of waste has been embedded: technological waste, spent ion exchange resins, concrete, rubble, etc. Liquid waste like evaporator concentrates can be dried and embedded simultaneously in extruders, allowing simple processes and equipment. Unfortunately, during long term intermediate storage the bituminized waste drums proved out being not as stable as expected: a significant number turned out to be no longer acceptable for final disposal, and some of them even needed repacking to enable further intermediate storage. A method to rework such drums with bituminized radioactive waste seems to be urgently needed. Pyrolysis and pyro-hydrolysis (= pyrolysis with water steam added) have a long history for the treatment of organic waste: spent solvent (TBP), spent ion exchange resins, alpha waste (predominantly PVC), etc. Due to its low process temperature and the endothermic character, such processes offer significant safety advantages, as compared to incineration or dissolving in organic solvents. Results of lab-scale investigations and concepts for facilities are presented. (authors)

  11. The big bitumen breakthrough

    International Nuclear Information System (INIS)

    The ongoing transformation of the oilsands and heavy oil sector from a poor cousin a few years ago into the cornerstone of the Alberta oil industry, was discussed. Much of this change is due to the development of SAGD (steam assisted gravity drainage) technology for the underground recovery of heavy oil and tarry bitumens, aided by partly government-funded research, and boosted by a revised provincial royalty regime. The thermal recovery process makes use of a pair of horizontal injection and recovery wells, drilled one above the other. The efficiency of this new technology could produce a shift in the petroleum industry's spending towards oil sands and heavy oil if investors conclude that it is more profitable to produce heavy oil than conventional light oil. Some of the oil sands producers that are poised to invest billions of dollars in various underground bitumen projects in Alberta over the next five years include Suncor, Syncrude, Alberta Energy Co., Amoco Canada, Elan Energy, Imperial Oil Resources, CS Resources, Koch Oil, and Gulf Resources. The ultimate goal is recovery costs of $6 per barrel, which is comparable to the costs of the conventional oil sector. The added advantage of oil sands production is, of course, the virtual elimination of the exploration risk. 3 figs

  12. Waterproofing Materials for Ammonium Nitrate

    Directory of Open Access Journals (Sweden)

    R.S. Damse

    2004-10-01

    Full Text Available This study explores the possibility of overcoming the problem of hygroscopicity of ammonium nitrate by coating the particles with selected waterproofing materials. Gravimetric analysis ofthe samples of ammonium nitrate coated with eight different waterproofing materials, vis-a-vis, uncoated ammonium nitrate, were conducted at different relative humidity and exposuretime. The results indicate that mineral jelly is the promising waterproofing material for ammonium nitrate among the materials tested, viz, calcium stearate, dioctyl phthalate, kaoline, diethylphthalate, dinitrotoluene, shelac varnish, and beeswax. Attempts were made to confirm the waterproofing ability of mineral jelly to ammonium nitrate using differential thermal analysisand x-ray diffraction patterns as an experimental tool. Suitability of mineral jelly as an additive for the gun propellant was also assessed on the basis of theoretical calculations using THERMprogram.

  13. Method for Waterproofing Ceramic Materials

    Science.gov (United States)

    Cagliostro, Domenick E. (Inventor); Hsu, Ming-Ta S. (Inventor)

    1998-01-01

    Hygroscopic ceramic materials which are difficult to waterproof with a silane, substituted silane or silazane waterproofing agent, such as an alumina containing fibrous, flexible and porous, fibrous ceramic insulation used on a reentry space vehicle, are rendered easy to waterproof if the interior porous surface of the ceramic is first coated with a thin coating of silica. The silica coating is achieved by coating the interior surface of the ceramic with a silica precursor converting the precursor to silica either in-situ or by oxidative pyrolysis and then applying the waterproofing agent to the silica coated ceramic. The silica precursor comprises almost any suitable silicon containing material such as a silane, silicone, siloxane, silazane and the like applied by solution, vapor deposition and the like. If the waterproofing is removed by e.g., burning, the silica remains and the ceramic is easily rewaterproofed. An alumina containing TABI insulation which absorbs more that five times its weight of water, absorbs less than 10 wt. % water after being waterproofed according to the method of the invention.

  14. Aostra: how a government-industry partnership bridged the technology 'valley of death' and helped trump Venezuela's natural bitumen advantages

    Energy Technology Data Exchange (ETDEWEB)

    Bott, Robert

    2011-10-15

    The scale of Venezuela's in-place bitumen and heavy oil resources is comparable with Alberta's and is much more producible. Maurice Dusseault thinks that political stability and investment are the reasons that Alberta has surged ahead of Venezuela both in investment and production. The Canadian government began to foster the development of the oilsands from the late '60s and early '70s. Government and industry made financial support available for pilot projects and university research. The Alberta Oil Sands Technology and Research Authority (AOSTRA) was established in 1974. AOSTRA has played a critical role in fostering research and testing techniques and technologies on a pre-commercial scale. Successful examples of AOSTRA initiatives were cited in this article. By investing in R and D and creating a favorable investment climate, Alberta has become the centre of the heavy oil research and commercialization industry.

  15. The need for a marketing strategy for Alberta bitumen

    International Nuclear Information System (INIS)

    Over the past 15 years, government and industry have invested heavily in research and development of new technology for extracting bitumen from the Alberta oil sands. The results have been a dramatic increase in the fraction of oil sands deposits that could be economically exploited and a drop in production costs. However, no rapid increase in bitumen recovery has been achieved and most new bitumen production projects have been postponed or cancelled. This is the result of very variable prices for bitumen and the inadequacy of a marketing strategy which relies on the sale of raw bitumen. Options such as transport of bitumen to southern markets are limited by the need to reduce bitumen viscosity for pipelining and by the limited market for emulsified or diluted bitumen. Another possible strategy, conversion of the bitumen to synthetic crude oil, is limited by high costs, product characteristics (too much diesel and not enough gasoline), and a market limited to specialized refineries. A third strategy is to convert and refine bitumen to transportation fuels in Alberta, using inexpensive local natural gas, and transporting the products through existing pipeline facilities. 3 figs

  16. Disjoining pressure isotherms of water-in-bitumen emulsion films.

    Science.gov (United States)

    Taylor, Shawn D; Czarnecki, Jan; Masliyah, Jacob

    2002-08-01

    In the oil sands industry, undesirable water-in-oil emulsions are often formed during the bitumen recovery process where water is used to liberate bitumen from sand grains. Nearly all of the water is removed except for a small percentage (approximately 1 to 2%), which remains in the solvent-diluted bitumen as micrometer-sized droplets. Knowledge of the colloidal forces that stabilized these water droplets would help to increase our understanding of how these emulsions are stabilized. In this study, the thin liquid film-pressure balance technique has been used to measure isotherms of disjoining pressure in water/toluene-diluted bitumen/water films at five different toluene-bitumen mass ratios. Even though a broad range of mass ratios was studied, only two isotherms are obtained, indicating a possible change in the molecular orientation of surfactant molecules at the bitumen/water interfaces. At low toluene-bitumen mass ratios, the film stability appears to be due to a strong, short-range steric repulsion created by a surfactant bilayer. Similar isotherms were obtained for water/toluene-diluted asphaltene/water films, indicating that the surface active material at the interface probably originated from the asphaltene fraction of the bitumen. However, unlike the bitumen films, films of toluene-diluted asphaltenes often formed very rigid interfaces similar to the "protective skin" described by other researcher. PMID:16290773

  17. Tunnel Waterproofing with Membranes Waterproofing at Senoko Cabele Tunnel in comparison with International Standards

    Institute of Scientific and Technical Information of China (English)

    Stefan Hotz

    2004-01-01

    Waterproofing of tunnels is and has always been a challenge, worldwide: Changing Geology with hardly predictable water inflow, limited space underground and only very little intervention opportunities once the tunnel is completed. This paper elaborates such challenges and focuses on the waterproofing solutions of mined tunnels with membranes. Different standards and approaches for the waterproofing system. In Singapore, a membrane waterproofing system is used for the shafts and adits at Senoko Cable Tunnel. The paper project specific waterproofing challenges and emphasizes on solution for them.

  18. COOEE bitumen: chemical aging

    CERN Document Server

    Lemarchand, Claire A; Dyre, Jeppe C; Hansen, Jesper S

    2013-01-01

    We study chemical aging in "COOEE bitumen" using molecular dynamic simulations. The model bitumen is composed of four realistic molecule types: saturated hydrocarbon, resinous oil, resin, and asphaltene. The aging reaction is modelled by the chemical reaction: "2 resins $\\rightarrow$ 1 asphaltene". Molecular dynamic simulations of four bitumen compositions, obtained by a repeated application of the aging reaction, are performed. The stress autocorrelation function, the fluid structure, the rotational dynamics of the plane aromatic molecules, and the diffusivity of each molecule, are determined for the four different compositions. The aging reaction causes a significant dynamics slowdown, which is correlated to the aggregation of asphaltene molecules in larger and dynamically slower nanoaggregates. Finally, a detailed description of the role of each molecule types in the aggregation and aging processes is given.

  19. TECHNOLOGY AND EFFICIENT USE OF PEAT ASH IN MASTICS FOR WATERPROOFING OF BRIDGE AND TUNNEL STRUCTURES

    Directory of Open Access Journals (Sweden)

    G. D. Lyahevich

    2015-01-01

    Full Text Available A prospective method for protection of  bridges and tunnels against aggressive water action is surface waterproofing on the basis of an organo-mineral binder. Its structural strength can be increased by introduction of particles which are similar to the size of  asphaltenes and an elasticity of disperse medium has been increased due to introduction of polymers. These theoretical suppositions point out the possibility for simultaneous provision of flexibility at low temperatures and high heat resistance for mastics on the basis  of organo-mineral binders. In this regard a goal has been set to obtain a mastic high flexibility and high heat resistance  while using finely divided activated peat ash.Rubber crushed in accordance with ТУ (Technical Specifications 38.108035–87,  divinyl-styrene thermoelastoplast DСT-30Р-20ПС,  bitumen of grade 20/30 in accordance with СТБ ЕН 12591–2010, ash from burning peat at the Lida Peat Briquette Plant, multi-purpose industrial oil of solvent refining with high viscosity index, super-plasticizer – sodium salt which is a condensation product of aromatic carbon sulfo-oxidation with formaldehyde and neutralization with the help of sodium hydroxide (type 1 have been used in order to obtain the stated objective. While using these materials compositions and technology for preparation of organo-mineral mastics have been developed in the paper. Their tests have shown that a modification of finely divided  mastics carried out with the help of peat ash which is activated by super-plasticizer НСПКСАУсФ-1, various polymer additives, contributes to an increase in their heat resistance, elasticity, water resistance, and also allows to control their technological and operational characteristics. The paper has experimentally confirmed that peat ash can be successfully used for preparation of high-quality waterproofing mastics which are so necessary for  protection of bridge and tunnel

  20. Pressurized waterproof case electronic device

    KAUST Repository

    Berumen, Michael L.

    2013-01-31

    A pressurized waterproof case for an electronic device is particularly adapted for fluid-tight containment and operation of a touch-screen electronic device or the like therein at some appreciable water depth. In one example, the case may be formed as an enclosure having an open top panel or face covered by a flexible, transparent membrane or the like for the operation of the touchscreen device within the case. A pressurizing system is provided for the case to pressurize the case and the electronic device therein to slightly greater than ambient in order to prevent the external water pressure from bearing against the transparent membrane and pressing it against the touch screen, thereby precluding operation of the touch screen device within the case. The pressurizing system may include a small gas cartridge or may be provided from an external source.

  1. Waterproofing improvement of radioactive waste asphalt solid

    International Nuclear Information System (INIS)

    Purpose: To improve the waterproofing of asphalt solid by adding an alkaline earth metal salt and, further, paraffin, into radioactive liquid waste when processing asphalt solidification of the radioactive liquid waste. Method: Before processing molten asphalt solidification of radioactive liquid waste, soluble salts of alkaline earth metal such as calcium chloride, magnesium chloride, or the like is added to the radioactive liquid waste. Paraffin having a melting point of higher than 600C, for example, is added to the asphalt, and waterproofing can be remarkably improved. The waste asphalt solid thus fabricated can prevent the swelling thereof, and can improve its waterproofing. (Yoshihara, H.)

  2. Surface microstructure of bitumen characterized by atomic force microscopy.

    Science.gov (United States)

    Yu, Xiaokong; Burnham, Nancy A; Tao, Mingjiang

    2015-04-01

    Bitumen, also called asphalt binder, plays important roles in many industrial applications. It is used as the primary binding agent in asphalt concrete, as a key component in damping systems such as rubber, and as an indispensable additive in paint and ink. Consisting of a large number of hydrocarbons of different sizes and polarities, together with heteroatoms and traces of metals, bitumen displays rich surface microstructures that affect its rheological properties. This paper reviews the current understanding of bitumen's surface microstructures characterized by Atomic Force Microscopy (AFM). Microstructures of bitumen develop to different forms depending on crude oil source, thermal history, and sample preparation method. While some bitumens display surface microstructures with fine domains, flake-like domains, and dendrite structuring, 'bee-structures' with wavy patterns several micrometers in diameter and tens of nanometers in height are commonly seen in other binders. Controversy exists regarding the chemical origin of the 'bee-structures', which has been related to the asphaltene fraction, the metal content, or the crystallizing waxes in bitumen. The rich chemistry of bitumen can result in complicated intermolecular associations such as coprecipitation of wax and metalloporphyrins in asphaltenes. Therefore, it is the molecular interactions among the different chemical components in bitumen, rather than a single chemical fraction, that are responsible for the evolution of bitumen's diverse microstructures, including the 'bee-structures'. Mechanisms such as curvature elasticity and surface wrinkling that explain the rippled structures observed in polymer crystals might be responsible for the formation of 'bee-structures' in bitumen. Despite the progress made on morphological characterization of bitumen using AFM, the fundamental question whether the microstructures observed on bitumen surfaces represent its bulk structure remains to be addressed. In addition

  3. Fractal harmonic law and waterproof/dustproof

    Directory of Open Access Journals (Sweden)

    Kong Hai-Yan

    2014-01-01

    Full Text Available The fractal harmonic law admits that the friction between the pure water and the moving surface is the minimum when fractal dimensions of water in Angstrom scale are equal to fractal dimensions of the moving surface in micro scale. In the paper, the fractal harmonic law is applied to demonstrate the mechanism of waterproof/ dustproof. The waterproof phenomenon of goose feathers and lotus leaves is illustrated to verify our results and experimental results agree well with our theoretical analysis.

  4. Project scenarios for bitumen upgrading

    International Nuclear Information System (INIS)

    The established reserves of Alberta's heavy oil resources are 178 billion barrels, and potential recoverable reserves are 315 billion barrels. The challenge of production includes the logistics of recovery, upgrading and transportation to market. Utilization of the bitumen is not simple because bitumen is too viscous to transport by pipeline. In addition, it is not processable by most existing refineries unless it can be upgraded through dilution. This paper examined different factors regarding the economic viability of various upgrading methods of a wide range of bitumen feedstocks. The study also examined the sensitivity of refinery demand to the prices of these feedstocks, along with the competitiveness among bitumen-based feedstock and conventional crudes. Western Canada, Ontario and the PADD II district in the United States are the 3 major markets for western Canadian bitumen based feedstock, the demand for which depends on refinery configurations and asphalt demand. This paper described the following 4 generic scenarios that describe Alberta bitumen upgrading projects: (1) adjacent to open pit mines, (2) adjacent to steam assisted gravity drainage (SAGD) facilities, (3) remotely located from resource production at an existing refinery, and (4) pipeline bitumen. It was noted that producers should determine the best way to upgrade the bitumen to ensure there is an economic market for the product, but they should also be aware not to over process the bitumen so as not to leave existing refinery facilities under-utilized. 2 refs., 1 tab., 3 figs

  5. Diluent evaluation for bitumen pipelining

    Energy Technology Data Exchange (ETDEWEB)

    Rahimi, P.; Cooper, S.; Alem, T. [National Centre for Upgrading Technology, Devon, AB (Canada)

    2009-07-01

    Oil sands crudes are expected to represent over 75 per cent of the crude produced in Western Canada. Since bitumen is too viscous to be shipped in pipelines, it must be diluted with a lighter hydrocarbon. Although thermal processing could be used together with a smaller quantity of diluent, the resulting fuel would be less stable. This presentation reported on a study that examined the compatibility and stability of virgin and cracked bitumen in natural diluents and synthetic diluents. Diluent ranking for asphaltene stability in virgin bitumen and cracked bitumen was also examined. Four heavy oils and bitumens were used in this study, notably Athabasca bitumen (AB), cracked Athabasca bitumen, heavy oil B and a light crude C. Natural gas condensate and oil sand derived liquids were the 2 diluents used to investigate the insolubility number and solubility blending number of different crudes, diluents and their blends. It was concluded that the stability of different heavy oils can be determined accurately by observing flocculation of asphaltenes. The study also evaluated and ranked the strength of different diluents for keeping asphaltenes soluble in the oil matrix. Although synthetic diluents were found to be better solvents than natural gas condensates for bitumen, the order of the solvent strength was reversed when bitumen was processed. tabs., figs.

  6. Angra 2 - qualification of the bitumen waste product

    International Nuclear Information System (INIS)

    In Angra Nuclear Power Plant, Unit 2, the concentrates from the liquid waste processing system and spent resins from the reactor coolant purification system, represent the low and intermediate level radioactive waste to be incorporate into a bitumen matrix. In order to attempt the Process Control Program aimed to obtain a waste product qualified to an intermediate and a final store, a program to qualify a Brazilian supplier bitumen manufacture, simulated tests in pilot scale in Centro de Desenvolvimento da Tecnologia Nuclear CDTN and tests in industrial scale, in Angra 2 during the commissioning and licensing phase was performed. The paper presents the team experience gained since the bitumen selection up to the bitumen characterization simulated waste product. (author)

  7. Processing options for bitumen upgrading

    International Nuclear Information System (INIS)

    It is estimated that 178 billion barrels of oil can be recovered from Alberta's vast heavy oil reserves. The challenge lies in the logistics of recovering, upgrading and transporting the oil to market. The Canadian Energy Research Institute conducted a recent study to determine market potential by 2007 for diluted bitumen and synthetic crude oil produced from upgraded bitumen. The viability for a wide range of bitumen feedstocks was assessed along with the sensitivity of refinery demand to their prices. The 3 major markets for western Canadian bitumen include PADD 2 in the United States, western Canada, and Ontario. Bitumen is too viscous to transport by pipeline and cannot be processed by most of the existing refineries. Therefore, in order to develop a mass market for the product, bitumen must undergo the energy intensive upgrading process at existing refineries. The factors impacting which method of upgrading is most suitable were discussed with particular attention to the impact that Canada's ratification of the Kyoto Protocol may have on Alberta's bitumen resource in terms of costs of complying with greenhouse gas reduction initiatives. The authors emphasized that it is crucial to customize an upgrading project to meet site and market specific factors. 8 refs., 3 tabs., 3 figs

  8. Waterproofing of facades - an efficient measure

    Energy Technology Data Exchange (ETDEWEB)

    Franke, L.; Kittl, R.; Witt, S.

    1987-09-01

    A discussion follows on the possibilities to estimate the water absorption of masonry facades exposed to pelting rain and the subsequent drying behaviour. In addition, proposals are given on how to check the efficiency of waterproofing carried out at masonry facades, particularly with regard to joint permeabilities which might still exist.

  9. Pressurized waterproof case for electronic device

    KAUST Repository

    Berumen, Michael L.

    2013-01-31

    The pressurized waterproof case for an electronic device is particularly adapted for the waterproof containment and operation of a touch-screen computer or the like therein at some appreciable water depth. The case may be formed as an enclosure having an open top panel or face covered by a flexible, transparent membrane or the like for the operation of the touch-screen device within the case. A pressurizing system is provided for the case to pressurize the case and the electronic device therein to slightly greater than ambient in order to prevent the external water pressure from bearing against the transparent membrane and pressing it against the touch screen, thereby precluding operation of the touch screen device within the case. The pressurizing system may be a small gas cartridge (e.g., CO2), or may be provided from an external source, such as the diver\\'s breathing air. A pressure relief valve is also provided.

  10. Selective extraction of natural bitumen

    International Nuclear Information System (INIS)

    The work performed in the field of natural bitumen extraction is aimed at maximum separation of organic phase. On treating bituminous rocks with solvents, the associated metals are extracted together with the organic phase and may further exert a negative effect on refining of natural bitumen. the authors propose a simplified two stage technique for the extraction of bitumen which enables to utilize V and Ni contained in the concentrate of the second stage extraction (Table). At the first stage, negative bitumen is extracted with the summary content of metals not exceeding 0.005%. This allows to avoid de metallization of native bitumen and subject it to treatment by catalytic cracking. during this stage gasoline and kerosene fractions, different oil distillates and condensates can be used as solvents. at the second stage, aromatic and halo id compounds bearing wastes and by-products, i.e. cheap and non deficient reagents, serve as solvents. The technology was tested under laboratory conditions using Tatar bituminous sands. It is also possible to use one solvent only, however, on condition that at first the oil product with the summary metal content below 0.005%, and then the remaining product is extracted. The proposed technology has proved so universal that it can be applied to refining any type of raw material to be found in the territory of the Tatar republic, using surface extraction complexes. (author). 9 refs., tab

  11. Control of thermal cracking and waterproof of J-PARC

    International Nuclear Information System (INIS)

    The switchyard structure of Japan Proton Accelerator Research Complex (J-PARC) is a concrete structure with high performance of execution and waterproof. High performance of waterproof was secured by prevention work of thermal cracking, waterproof in the exterior surface and construction joint, and increasing water-tightness. Many measures to the thermal cracking and increase of water-tightness of concrete decreased the cracks introducing to leakage water. Work process, items for waterproof, example of results of temperature analysis and distribution of thermal cracking index, placing of concrete, and results of measures are stated. (S.Y.)

  12. The Human Bitumen Study: executive summary.

    Science.gov (United States)

    Raulf-Heimsoth, Monika; Pesch, Beate; Rühl, Reinhold; Brüning, Thomas

    2011-06-01

    Bitumen has attracted attention from the scientific community and regulating agencies. The debate on health effects of exposure to vapours and aerosols of bitumen during the hot application of bitumen ranges from respiratory and neurological effects to carcinogenicity. In 2000, the German Hazardous Substances Committee (AGS), in collaboration with the German Bitumen Forum, initiated the examination of a group of mastic asphalt workers and a same number of construction workers without exposure bitumen using a cross-shift design. The study was then extended to the Human Bitumen Study, and the recruitment was finished in 2008 after examination of 500 workers on 80 construction sites. Three hundred and twenty workers exposed to vapours and aerosols of bitumen at high processing temperatures and 118 workers at outdoor construction sites were included. In the Human Bitumen Study external exposure to vapours and aerosols of bitumen, internal exposure to PAH by analysing urinary 1-hydroxypyrene, the sum of hydroxyphenanthrenes and the sum of 1- and 2-hydroxynaphthalenes, irritative effects in the upper and lower airways and genotoxic effects in blood cells were investigated. The study turned out to be one of the largest investigations of workers exposed to vapours and aerosols of bitumen under current exposure conditions. The present paper summarizes its background and main topics. PMID:21369765

  13. The extraction of bitumen from western tar sands

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1990-07-01

    Topics discussed include: characterization of bitumen impregnated sandstone, water based tar sand separation technology, electrophoretic characterization of bitumen and fine mineral particles, bitumen and tar sand slurry viscosity, the hot water digestion-flotation process, electric field use on breaking water-in-oil emulsions, upgrading of bitumens and bitumen-derived liquids, solvent extraction.

  14. The extraction of bitumen from western tar sands. Annual report

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1990-07-01

    Topics discussed include: characterization of bitumen impregnated sandstone, water based tar sand separation technology, electrophoretic characterization of bitumen and fine mineral particles, bitumen and tar sand slurry viscosity, the hot water digestion-flotation process, electric field use on breaking water-in-oil emulsions, upgrading of bitumens and bitumen-derived liquids, solvent extraction.

  15. Bitumen-rubber mixture for effective vibration damping sheet

    Directory of Open Access Journals (Sweden)

    V.D. Cherkasov

    2013-12-01

    Full Text Available The results of researches of a bitumen-rubber mixture design for the damping sheet are presented. Application of vibration damping sheet in thin-walled construction designs allows reducing negative vibrations considerably. Existent bituminous and bituminous-rubber materials have insufficient vibration damping in the range of negative temperatures that is inadmissible in Russian climate conditions. Selection of structure bitumen-rubber mixture and regularity establishment of its properties will allow receiving a material with a wide temperature range of application. As an object of research there was chosen the polymeric matrix representing a mix of two materials – butyl rubber and bitumen, plasticized by industrial oil I-20A; the filler – swept of MTD-2 brands. The dependence of physical and mechanical properties of a material on the contents of bitumen-butyl rubber in a mix was established. The material based on the received mixture has effective vibration damping in the range of temperatures from -40 to +40 °C.

  16. Rheological, structural and chemical evolution of bitumen under gamma irradiation

    International Nuclear Information System (INIS)

    Bitumen derived from crude oil by fractional distillation has been used in the nuclear industry as a radioactive waste encapsulation matrix. When subjected to α, β and γ self-irradiation, this organic matrix undergoes radiolysis, generating hydrogen bubbles and modifying the physical and chemical properties of the material. In this paper, the effects of irradiation on bitumen materials, especially in terms of its physical, chemical, structural and rheological properties, were characterized at radiation doses ranging from 1 to 7 MGy. An increase in the shear viscosity and melt yield stress was observed with increasing doses. Similarly, the elastic and viscous moduli (G' and G'') increase with the dose, with a more pronounced increase for G' that reflects enhanced elasticity arising from radiation-induced cross-linking. In addition, a low-frequency plateau is observed for G', reflecting pseudo-solid behavior and leading to an increase of the complex viscosity. This behavior is due to increased interactions between asphaltene particles, and to aromatization of the bitumen by γ-radiations. Cross-linking of bitumen enhances its strength, as confirmed by various techniques (modulated DSC, DTA/TGA, SEC, FTIR and XRD). (authors)

  17. The bitumen situation : a Heartland group's hopes to buck the trend of upgrading and refining outside Alberta, and the government initiative that's starting to help

    International Nuclear Information System (INIS)

    This article discussed a campaign aimed at promoting bitumen refining at the site where it is mined. This initiative would increase the amount of bitumen upgraded in Alberta. Rather than investing in new upgrader capacity in Alberta, bitumen producers currently favour processing alliances with upgraders in the United States or Mexico. Bitumen production is valuable, but the end products of upgrading and refining would bring more value to the province. Processing the bitumen within Alberta would provide the basis for a petrochemical industry, supplying feedstock or the building blocks for end products, and create a talent pool of professionals. Alberta currently processes two-thirds of its bitumen, but this is expected to fall to less than 40 percent by 2020. Industry and government cooperation is needed for developing common infrastructure needed for multiple upgraders. Developing facilities in a cluster would lower the entry cost for new upgrader developers, but government would have to take a lead role in such a project. Upgraders are capital-intensive projects, and it currently costs half as much to construct on the Gulf of Mexico coast. The price difference between heavy and light oil has narrowed, leaving little incentive for upgrading bitumen. The Alberta Government's Bitumen Royalty in Kind Program, which gives the government the option of collecting royalties in bitumen (kind) instead of cash, is being used as a lever to attract new upgrading capacity. 1 fig.

  18. Self lubrication of bitumen froth in pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Joseph, D.D. [Univ. of Minnesota, Minneapolis, MN (United States)

    1997-12-31

    In this paper I will review the main properties of water lubricated pipelines and explain some new features which have emerged from studies of self-lubrication of Syncrudes` bitumen froth. When heavy oils are lubricated with water, the water and oil are continuously injected into a pipeline and the water is stable when in a lubricating sheath around the oil core. In the case of bitumen froth obtained from the Alberta tar sands, the water is dispersed in the bitumen and it is liberated at the wall under shear; water injection is not necessary because the froth is self-lubricating.

  19. Possible Concepts for Waterproofing of Norwegian TBM Railway Tunnels

    Science.gov (United States)

    Dammyr, Øyvind; Nilsen, Bjørn; Thuro, Kurosch; Grøndal, Jørn

    2014-05-01

    The aim of this paper is to evaluate and compare the durability, life expectancy and maintenance needs of traditional Norwegian waterproofing concepts to the generally more rigid waterproofing concepts seen in other European countries. The focus will be on solutions for future Norwegian tunnel boring machine railway tunnels. Experiences from operation of newer and older tunnels with different waterproofing concepts have been gathered and analyzed. In the light of functional requirements for Norwegian rail tunnels, some preliminary conclusions about suitable concepts are drawn. Norwegian concepts such as polyethylene panels and lightweight concrete segments with membrane are ruled out. European concepts involving double shell draining systems (inner shell of cast concrete with membrane) and single shell undrained systems (waterproof concrete segments) are generally evaluated as favorable. Sprayable membranes and waterproof/insulating shotcrete are welcomed innovations, but more research is needed to verify their reliability and cost effectiveness compared to the typical European concepts. Increasing traffic and reliance on public transport systems in Norway result in high demand for durable and cost effective solutions.

  20. Upgrading of bitumen using supercritical water

    Energy Technology Data Exchange (ETDEWEB)

    Kayukawa, T. [JGC Corp., Ibaraki (Japan)

    2009-07-01

    This presentation outlined the technical and economic aspects of thermal cracking by supercritical water. Supercritical water (SCW) is a commonly used method for upgrading heavy oil to produce pipeline-transportable oil from high-viscous bitumen. The process uses water and does not require hydrogen nor catalysts. Pre-heated bitumen and water enter a vertical reactor with flows of counter current at the supercritical point of water. The upgraded synthetic crude oil (SCO) and pitch are obtained from the top of the reactor when the bitumen is thermally cracked. Bench-scale studies have shown that Canadian oil sands bitumen can be converted to 80 volume per cent of SCO and 20 volume per cent of pitch. The SCO has satisfied Canadian pipeline specifications in terms of API gravity and kinetic viscosity. The kinetic viscosity of the pitch has also satisfied boiler fuel specifications. tabs., figs.

  1. Building waterproofing remediation applying the 'total cut' method

    Directory of Open Access Journals (Sweden)

    Gavrilović Dragan J.

    2011-01-01

    Full Text Available The paper analyzes the specific problems of construction of a waterproofing system with an absolute control of the vertical penetration of ground water and dampness from the ground into higher levels of building masonry structure. This method can very suitably be applied in rehabilitation of old brick buildings where the usual waterproofing remediation systems cannot be implemented because of specific structure system The 'total cut' method is very suitable for use in the old traditional masonry buildings, which do not have reinforced concrete vertical beams and where using this method would not interfere with the continuous stability of the building.

  2. A New Approach for Evaluating Rejuvenator Diffusing into Aged Bitumen

    Institute of Scientific and Technical Information of China (English)

    KUANG Dongliang; FENG Zhengang; YU Jianying; CHEN Xing; ZHOU Bo

    2011-01-01

    Rejuvenator diffusing into aged bitumen was evaluated by determining penetration and chemical components of aged bitumen with rejuvenator coat before and after diffusing experiment.Effects of temperature, time and viscosity of rejuvenator on the diffusing ability of rejuvenator into aged bitumen were investigated. Results indicated that the diffusing ability of rejuvenator into aged bitumen could be enhanced with the increasing of temperature and time, however, the diffusing of rejuvenator into aged bitumen would be restricted due to the volatilization of light component and aging of rejuvenator under high temperature (over 170 ℃). Rejuvenator with low viscosity diffused into aged bitumen more easily.

  3. Market challenges for SCO and bitumen

    International Nuclear Information System (INIS)

    The various options available to producers of bitumen to market their product are reviewed. Marketing as bitumen blend is one of the options, however, the ability of doing this becomes constrained by the availability of diluent and refinery capacity to utilize the crude. Building a complex upgrader and produce an upgraded synthetic crude is another option, but that too will face marketing constraints as oilsands development continues to grow. A third option is to partially upgrade the bitumen, enough to be pumpable, and then sell it to a refiner for further upgrading. Partial upgrading in the field appears to be the most viable option but it will likely require long term integration with refineries to be effective. Refiners are faced with the challenge to reduce sulphur in gasoline, which means that they may well be reluctant to take bitumen as feedstock due its being hydrogen deficient, requiring substantial hydrogen addition or coke withdrawal to make them more compatible with existing refiners, most of which are not able to deal with bitumen efficiently. Regardless of the option chosen, increased production of bitumen will require new markets (perhaps PADD II, the US Midwest or more remote markets) and may require investments in new refining facilities to absorb all new synthetic supplies. While the availability of an adequate diluent supply is the major issue, there is also the added pressure on refiners to reduce greenhouse gas emissions; this in itself could be a significant factor in deciding where upgrading of bitumen should occur. The paper concludes by saying that to meet these challenges it will be necessary for producers, upgraders and refiners to work much more closely together than they have in the past

  4. 49 CFR 192.189 - Vaults: Drainage and waterproofing.

    Science.gov (United States)

    2010-10-01

    ... Components § 192.189 Vaults: Drainage and waterproofing. (a) Each vault must be designed so as to minimize the entrance of water. (b) A vault containing gas piping may not be connected by means of a drain connection to any other underground structure. (c) Electrical equipment in vaults must conform to...

  5. Markets for Canadian bitumen-based feedstock

    International Nuclear Information System (INIS)

    This study was undertaken in an effort to determine the market potential for crude bitumen and derivative products from the Western Canadian Sedimentary Basin in 2007. As part of the study, CERI assessed the economic viability of a wide range of bitumen-based feedstock based on their refining values, investigated the sensitivity of refinery demand to the prices of these feedstocks, and examined the competitiveness of bitumen-based feedstocks and conventional crudes. A US$18.00 per barrel price for West Texas Intermediate at Cushing, Oklahoma, was assumed in all calculations, including other crude prices, as well as for Western Canadian and US crude oil production forecasts. Four different scenarios have been considered, but only the 'most plausible' scenario is discussed in the report. Consequently, Hydrocracked/Aromatics Saturated Synthetic Crude Oil, which is currently only a hypothetical product, is excluded from consideration. The availability of historical price differentials for the various competing crudes was another assumption used in developing the scenario. Proxy prices for the bitumen-based feedstock were based on their respective supply costs. The study concludes that the principal dilemma facing bitumen producers in Western Canada is to determine the amount of upgrading necessary to ensure an economic market for their product in the future. In general, the greater the degree of upgrading, the higher is the demand for bitumen-based feedstock. However, it must be kept in mind that the upgrading decisions of other bitumen producers, along with many other factors, will have a decisive impact on the economics of any individual project. The combination of coking capacity and asphalt demand limits the market for heavy and extra-heavy crudes. As a result, the researchers concluded that major expansion of heavy crude conversion capacity may have to wait until the end of the current decade. The economic market for bitumen-based blends in 2007 is estimated at

  6. Research on swelling clays and bitumen as sealing materials for radioactive waste repositories

    International Nuclear Information System (INIS)

    This report describes a programme of research to investigate the performance of composite seals incorporating adjacent blocks of swelling clay and bitumen. It is shown that the interaction of the materials can promote a self-sealing mechanism which prevents water penetration, even when defects are present in the bitumen layer. A review of the swelling properties of highly compacted bentonite and magnesium oxide is presented, and the characteristic sealing properties of bituminous materials are described. On the basis of this review, it is concluded that bentonite is the preferred candidate material for use in composite clay/bitumen seals for intermediate-level radioactive waste repositories. However, it is thought that magnesium oxide may have other sealing applications for high-level waste repositories. A programme of laboratory experiments is described in which relevant swelling and intrusion properties of highly compacted bentonite blocks and the annealing characteristics of oxidised and hard-grade industrial bitumens are examined. The results of composite sealing experiments involving different water penetration routes are reported, and factors governing the mechanism of self-sealing are described. The validation of the sealing concept at a laboratory scale indicates that composite bentonite/bitumen seals could form highly effective barriers for the containment of radioactive wastes. Accordingly, recommendations are made concerning the development of the research, including the implementation of full-scale demonstration experiments to simulate conditions in an underground repository. 13 tabs., 41 figs., 62 refs

  7. Langmuir films of solids-free bitumen and bitumen fractions at toluene/water interface

    Energy Technology Data Exchange (ETDEWEB)

    Solovyev, A.; Zhang, L.; Xu, Z.; Masliyah, J. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical and Materials Engineering

    2006-07-01

    This study examined the interfacial behaviour of bitumen and bitumen fractions at an organic solvent/water interface using a Langmuir trough and atomic force microscope (AFM). The objective was to better understand the stability of water-in-solvent diluted bitumen emulsions. The accumulation of interfacially active components at the oil/water interfaces promotes the formation of interfacial films, which resist the coalescence of water droplets thereby stabilizing water-in-oil emulsions. The bitumen fractions included maltene, and asphaltene films at the toluene/de-ionized water interface. Langmuir films of bitumen, maltene and asphaltene were spread at toluene/water interfaces where they exhibited different interfacial pressure-area isotherms. Asphaltenes were found to be irreversibly adsorbed at the toluene/water interface when the films were subjected to multiple washings with fresh toluene. Interfacial pressure-area isotherms remained unchanged. Consecutive washings of maltene films with fresh toluene showed a progressive loss of interfacial materials from the toluene/water interface. However, the pressure-area isotherms showed a consistent shift during the first 2 consecutive bitumen film washings and then no further shift with subsequent washings. After the first 2 washings, the isotherms were same as the original asphaltene films. According to AFM images of Langmuir-Blodgett films deposited from the toluene/water interface, the topographical features of asphaltene films resembled that of bitumen films. However, they were very different from that of maltene films. The study results demonstrated that the bitumen film at a toluene/water interface is composed primarily of asphaltenes. The asphaltenes contribute to the stability of water-in-diluted bitumen emulsions because they are irreversibly adsorbed at the interface. tabs., figs.

  8. Vergelijkend AFM Onderzoek: microstructuur van bitumen in relatie tot healing

    OpenAIRE

    Schmets, A. J. M.; Nahar, S.N.; Dillingh, B.; Fischer, H.; Scarpas, A.; Erkens, S.

    2012-01-01

    In this report we present the background, the scientific and experimental approach and the results of AFM experiments performed on two different batches of bitumen. The specific bitumen researched in this project has also been studied in the context of the InfraQuest project ‘Pragmatisch Healing Onderzoek’. It has been known for quite some time already that bitumen posessess a microstructure at the typical length scale of micrometers. This can be shown experimentally by imaging the bitumen su...

  9. Efficient, environmentally acceptable method for waterproofing insulation material

    Science.gov (United States)

    Blohowiak, Kay Y. (Inventor); Krienke, Kenneth A. (Inventor); Olli, Larry K. (Inventor); Newquist, Charles W. (Inventor)

    2000-01-01

    A process of waterproofing alumina-rich or silica-rich fibrous thermal insulation material, the process including the steps of: (a) providing an alumina-rich or a silica-rich fibrous material; (b) providing a waterproofing solution including: (1) a carrier solvent selected from the group consisting of aliphatic alcohols having from 1C to 6C, water, and mixtures thereof; and (2) an alkoxysilane defined by the formula R.sub.4-x -Si-(O-R').sub.x where x is 1-3 and R is selected from the group consisting of alkyl groups having from 1C to 10C, hydrogen, or fluorocarbon groups having from 1F to 15F; and where O-R' is an alkoxy group having from 1C to 5C, or a mixture of alkoxysilanes defined by the above formula R.sub.4-x -Si-(O-R').sub.x ; and optionally (3) modifiers including acids, such as acetic acid or nitric acid, or bases, such as ammonium hydroxide, RNH.sub.2, R.sub.2 NH, or R.sub.3 N, or MOH, where R is selected from the group consisting of alkyl groups having from 1C to 10C or hydrogen, and where M=Na, Li, or K; (c) contacting the fibrous material with the waterproofing solution for a sufficient amount of time to waterproof the fibrous material; and (d) curing the coated fibrous material to render it sufficiently waterproof. A chemical solution for waterproofing alumina-rich or silica-rich fibrous thermal insulation materials, the solution including: (a) a carrier solvent selected from the group consisting of aliphatic alcohols having from 1C to 6C, water, and mixtures thereof; and (b) an alkoxysilane defined by the formula R.sub.4-x -Si-(O-R').sub.x where x is 1-3 and R is selected from the group consisting of alkyl groups having from 1C to 10C, hydrogen, or fluorocarbon groups having from 1F to 15F; and where O-R' is an alkoxy group having from 1C to 5C, or a mixture of alkoxysilanes defined by the above formula R.sub.4-x -Si-(O-R').sub.x ; and optionally (c) modifiers including acids, such as acetic acid or nitric acid, or bases, such as ammonium hydroxide

  10. Full recovery of Arundo donax particleboard from swelling test without waterproofing additives

    Directory of Open Access Journals (Sweden)

    Jose-Antonio Flores-Yepes

    2012-11-01

    Full Text Available This paper presents the development of particleboard based on common reed, reproducing the industry standard manufacturing process applied to wood chipboard. One of the main properties of the resulting board was its resistance to water, due to the hydrophobic properties of the common reed, despite there being no incorporation of melamine or any other waterproofing additive. The boards that were developed were analyzed using 2 mm and 4 mm sieves for fibre selection, a manufacturing pressure of 3 N/mm2 and 25 N/mm2, and a volume of urea formaldehyde resin content ranging from 5.2% to 13% (8 to 20% liquid format. Standard destructive tests were performed. It was found that under certain applied conditions, namely high pressure and adequate resin proportion (a pressure of over 3 N/mm2 and over 15% liquid resin, Arundo donax L. particleboard demonstrated full recovery from the swelling test. This finding highlights an unmatched property in terms of recovery from the swelling test of the designed board. This property confers a interesting property to be used in high humidity environments without the need for special resin or waterproofing process.

  11. Degradation of polymer waterproofing by alpha particles and soil bacteria

    International Nuclear Information System (INIS)

    This was a preparatory study aimed at addressing two issues: (i) Ageing and degradation of normal types of polymeric waterproofing materials during long-time exposure to radon and soil bacteria and (ii) Temperature dependence (0 deg C to 40 deg C) of the radon diffusion coefficient for common non-degraded insulating materials. Shore D hardness was measured for unexposed and exposed high-density and low-density polyethylene. Module of elasticity, elongation, and tensile strength were also measured. (orig)

  12. Markets for Canadian bitumen-based feedstock

    International Nuclear Information System (INIS)

    The best types of refineries for processing western Canadian bitumen-based feedstock (BBF) were identified and a potential market for these feedstock for year 2007 was calculated. In addition, this power point presentation provided an estimation of potential regional and total demand for BBF. BBF included Athabasca bitumen blend, de-asphalted blend, coked sour crude oil (SCO), coked sweet SCO, hydrocracked SCO and hydrocracked/aromatic saturated SCO (HAS). Refinery prototypes included light and mixed prototypes for primary cracking units, light and heavy prototypes for primary coking units, as well as no coking, coking severe and residuum prototypes for primary hydrocracking units. The presentation included graphs depicting the natural market for Western Canadian crudes as well as U.S. crude oil production forecasts by PADD districts. It was forecasted that the market for bitumen-based feedstock in 2007 will be tight and that the potential demand for bitumen-based blends would be similar to expected production. It was also forecasted that the potential demand for SCO is not as promising relative to the expected production, unless price discounting or HAS will be available. 11 figs

  13. The conditioning of radioactive waste by bitumen

    International Nuclear Information System (INIS)

    The separation of radioactive sludge and waste by bitumen is studied. Results are given concerning various trials carried out on the lixiviation of the final product by water as a function of the pH, of the time, and of the composition. The conditions for carrying out this process of coating the waste are controlled from a radioactive point of view. (author)

  14. Market outlook for Athabasca bitumen: the economics of location

    International Nuclear Information System (INIS)

    The use of steam assisted gravity drainage (SAGD) was shown to have lowered supply costs and made Athabasca bitumen competitive in the North American market for heavy crudes and bitumen. As part of a SAGD commercialization study, the potential market for Athabasca bitumen, its transportation and netback prices were studied. While both Syncrude and Suncor have identified a need for additional bitumen in the future, it was also recognized that Athabasca bitumen prices must be cost competitive with Syncrude's and Suncor's own products. The study also revealed that the most significant obstacle for Athabaska bitumen to being fully competitive in the North American market was the lack of transportation infrastructure. It was suggested that using larger volume pipelines would aid in keeping pipeline tariffs low , which in turn, would improve Athabaska bitumen's competitiveness and enable further development of the deposit. 8 figs., 1 table

  15. Comparable Evaluation of Leather Waterproofing Behaviour upon Hide Quality. II. Influence of Finishing on Leather Properties

    OpenAIRE

    Virginija JANKAUSKAITĖ; Ada GULBINIENĖ; Indira JIYEMBETOVA; Justa ŠIRVAITYTĖ; Virginijus URBELIS; Kazys Vytautas MICKUS

    2014-01-01

    Unfinished leather has high water vapour permeability and low waterproofness because of its natural porous structure. To modify the surface appearance and hide any defects, to improve physical properties, such as light and rub fastness, resistance to water, solvents, abrasion, etc., leather needs to be finished. In this study the influence of waterborne finishing agents on the waterproofness and breathability of the hydrophobic leather obtained using different retanning, waterproofing, neutra...

  16. Properties and long-term behaviour of bitumen and radioactive waste-bitumen mixtures

    International Nuclear Information System (INIS)

    Part I represents a survey of the properties and the long-term behaviour of pure bitumens and mixtures of bitumens with radioactive reactor and reprocessing wastes. This survey includes information on the origin, amounts, and composition of the various wastes considered for bituminization and the different waste bituminization techniques used. The influence of various factors on the quality of waste-bitumen products and on the radiological safety during transport, short- and long-term storage of the final products is described. Special consideration is given to the most important safety relevant factors associated to the use of bitumen as matrix material for radioactive wastes, such as leach-resistance, radiolysis, chemical and mechanical stability, combustibility, and microbial attack. Part II consists of a comprehensive bibliography on the bituminization of radioactive wastes, giving about 300 references to literature published from the beginning of the use of bitumen in radioactive waste management in 1960 until the beginning of 1979. Methods for the quality control of bituminous materials and some useful data are given in an annex. (author)

  17. Experimental PVT property analyses for Athabasca bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Ashrafi, Mohammad; Souraki, Yaser; Karimaie, Hassan; Torsaeter, Ole [Norwegian University of Science and Technology (Norway); Bjorkvik, Bard J.A. [SINTEF Petroleum Research (Norway)

    2011-07-01

    To study fluid behavior in a reservoir it is very important to find out exact and complete data on the rock system, fluid properties, and rock-fluid interactions. PVT properties are among the most critical data that reservoir engineers need to evaluate the reservoir. This paper presents the experimental study of a few PVT properties of Athabasca bitumen. The viscosity of Athabasca heavy crude was measured using a rotational viscometer. These viscosity data are a reliable input for simulation purposes. The Athabasca oil was characterized using gas chromatography analysis. Whole sample molar mass was measured at 534 g/mol by cryoscopy. Density and molar mass were also measured. Based on the experimental study, a formula was derived for Athabasca bitumen density prediction in the temperature and pressure range studied. From the results, the interfacial tension between oil and steam was measured, using the pendant drop method, and found to be between 25 and 18 mN/m.

  18. Volume Stability of Bitumen Bound Building Blocks

    Directory of Open Access Journals (Sweden)

    Thanaya I.N.A.

    2010-01-01

    Full Text Available This paper covers results of laboratory investigations on the volume stability of masonry units incorporating waste materials bound with bitumen (Bitublocks, due to moisture adsorption, thermal exposure and vacuum saturation. The materials used were steel slag, crushed glass, coal fly ash, and 50 pen bitumen. The samples were produced in hot mix method, compacted, then exposed to moist and temperature. It was found that moisture adsorption from the environment caused the Bitublock to expand. The samples with less intense curing regime experienced lower expansion and became stable faster, and vice versa. Under thermal condition (at 70°C, the samples with less intense curing regime underwent higher expansion, and vice versa. They were also highly reversible. Their volume stability was found unique under water exposure. The expansion on first vacuum saturation cycle was irreversible, then largely reversible on the following cycles.

  19. FTIR instrumentation to monitor vapors from Shuttle tile waterproofing materials

    Science.gov (United States)

    Mattson, C. B.; Schwindt, C. J.

    1995-01-01

    The Space Shuttle Thermal Protection System (TPS) tiles and blankets are waterproofed using DimethylEthoxySilane (DMEX) in the Orbiter Processing Facilities (OPF). DMES has a Threshold Limit Value (TLV) for exposure of personnel to vapor concentration in air of 0.5 ppm. The OPF high bay cannot be opened for normal work after a waterproofing operation until the DMES concentration is verified by measurement to be below the TLV. On several occasions the high bay has been kept closed for up to 8 hours following waterproofing operations due to high DMES measurements. In addition, the Miran 203 and Miran 1 BX infrared analyzers calibrated at different wavelengths gave different readings under the same conditions. There was reason to believe that some of the high DMES concentration readings were caused by interference form water and ethanol vapors. The Toxic Vapor Detection Laboratory (TVDL) was asked to test the existing DMES instruments and identify the best qualified instrument. In addition the TVDL was requested to develop instrumentation to ensure the OPF high bay could be opened safely as soon as possible after a waterproofing operation. A Fourier Transform Infrared (FTIR) spectrophotometer instrument developed for an earlier project was reprogrammed to measure DMES vapor along with ethanol, water, and several common solvent vapors. The FTIR was then used to perform a series of laboratory and field tests to evaluate the performance of the single wavelength IR instruments in use. The results demonstrated that the single wavelength IR instruments did respond to ethanol and water vapors, more or less depending on the analytical IR wavelength selected. The FTIR was able to separate the responses to DMES, water and ethanol, and give consistent readings for the DMES vapor concentration. The FTIR was then deployed to the OPF to monitor real waterproofing operations. The FTIR was also used to measure the time for DMES to evaporate from TPS tile under a range of humidity

  20. Effect of processing temperature on the bitumen/MDI-PEG reactivity

    Energy Technology Data Exchange (ETDEWEB)

    Martin-Alfonso, M.J.; Partal, P.; Navarro, F.J.; Garcia-Morales, M. [Departamento de Ingenieria Quimica, Facultad de Ciencias Experimentales, Campus de ' El Carmen' , Universidad de Huelva, 21071, Huelva (Spain); Bordado, J.C.M. [Chemical and Biological Engineering Department, IBB, Instituto Superior Tecnico, Av. Rovisco Pais 1049-001 Lisbon (Portugal); Diogo, A.C. [Materials Engineering Department, Instituto Superior Tecnico, Av. Rovisco Pais 1049-001 Lisbon (Portugal)

    2009-04-15

    Reactive polymers are lately gaining acceptance to give added value to a residue of the crude oil refining process such as bitumen. The resulting material should display enhanced mechanical properties to be considered for advanced applications in construction. In the present paper, we report the effect of processing temperature on the reaction between bitumen compounds and an isocyanate-based reactive polymer, synthesized by reaction of polymeric MDI (4,4'-diphenylmethane diisocyanate) with a low molecular weight polyethylene-glycol (PEG). Rheokinetics experiments, viscosity measurements at 60 C, atomic force microscopy (AFM) characterization, thin layer chromatography (TLC-FID) analysis and thermogravimetric studies (TGA) were performed on the reactive polymer and on samples of MDI-PEG modified bitumen containing 2 wt.% of the polymer. Results showed the existence of an optimum processing temperature arisen as a consequence of opposite effects: microstructural availability for the formation of a polymer-bitumen network, reaction ability and polymer thermal degradation. Consequently, this study aims to serve as a guideline for the refining and asphalt industries facing the stage of selecting the optimum processing parameters. (author)

  1. Bitumens from the Barrandian Basin, Czech Republic

    Czech Academy of Sciences Publication Activity Database

    Sýkorová, Ivana; Suchý, Václav

    Porto: Departamento de geologia, Centro de geologia da Universidade do Porto, 1998, s. 54-55. ISSN 0873-741X. [Symposium on Gondwana Coals and 50th ICCP Meeting/2./. Porto (PT), 20.09.1998-26.09.1998] R&D Projects: GA AV ČR IAA3012703 Institutional research plan: CEZ:AV0Z3046908 Keywords : bitumens * maturation Subject RIV: DB - Geology ; Mineralogy

  2. Investigation of rheological properties of TPS modified bitumen

    Institute of Scientific and Technical Information of China (English)

    刘全涛; 吴少鹏; 刘聪慧; 王金刚

    2008-01-01

    Rheological properties of the virgin bitumen and TPS modified bitumen binders with several percentages of TPS additives were studied.All TPS modified bituminous binders were prepared on a laboratory scale.Dynamic shear rheometer(DSR) strain sweep test was made to measure the linear viscoelasticity areas of various bitumen binders at -20-70 ℃,then temperature sweep test and frequency sweep test were made in the linear viscoelasticity areas.Complex modulus master curves were drawn to analyze and compare various bitumen binders’ rheological properties.Based on the test results,the ideal percentage of TPS additive was brought forward.The results show that TPS modified bitumen binders have more excellent properties at high,medium and low temperatures compared with original bitumen.The dosages of TPS additive are vital to their properties.

  3. Autosolvent effect of bitumen in thermal cracking; Netsubunkai hanno ni okeru bitumen no jiko yobai koka

    Energy Technology Data Exchange (ETDEWEB)

    Mikuni, M.; Sato, M.; Hattori, H. [Hokkaido University, Sapporo (Japan). Center for Advanced Research of Energy Technology; Nagaishi, H.; Sasaki, M.; Yoshida, T. [Hokkaido National Industrial Research Institute, Sapporo (Japan)

    1996-10-28

    Tar sand bitumen is petroleum-based ultra-heavy oil, and has a great amount of reserve like coal. However, there are still a lot of problems for its highly effective utilization. This paper discusses whether the light components in bitumen show independent behavior during the thermal cracking of heavy components, or not. Solvent effect and reaction mechanism during the thermal cracking are also derived from the change of their chemical structures. Athabasca tar sand bitumen was separated into light and heavy fractions by vacuum distillation based on D-1660 of ASTM. Mixtures of the both fractions at various ratios were used as samples. Negative effect of the light fraction on cracking of the heavy fraction was observed with dealkylation and paraffin formation Polymerization of the dealkylated light fraction to the heavy fraction was suggested due to lack of hydrogen in the thermal cracking under nitrogen atmosphere, which resulted in the formation of polymer. 3 refs., 6 figs.

  4. The long-term stability of natural bitumen

    International Nuclear Information System (INIS)

    Natural bitumen can be an aid in the assessment of the long-term behaviour of technical bitumen. Natural occurrences of bitumen usually have the drawback that the original material before alteration or degration began is not known. The present work applies an alternative approach: on the basis of the geology and stratigraphy at a site where bitumen samples have been taken, the existence of a gradient in the parameters of subaerial and microbial degradation processes may be assumed. Therefore relative variation in properties, composition and structure (bitumen content, volative fraction, elemental composition, chromatographic fractions, saturated hydrocarbons, trace metals, humic substances) at different locations within the deposit have been analysed. The bitumen impregnates a bed of porous Jurassic limestone which crops out at the surface and dips under sediments of various permeability. The quality of the bitumen is in compliance with standards for soft technical bitumen, although it can be characterized as highly biodegraded. It has probably not been affected to any marked degree by degradation since the Quarternary or possibly even late Tertiary, however, as observable variations in composition and properties are only minor and seem to exhibit no clear relation to the present geological setting. Only near the present outcrop do there seem to be signs of increased oxidation. Direct exposure to the weather at the surface leads to destruction of the bitumen within a very thin surface layer. Traces of humic substances probably originating from the decomposition of bitumen were found. The rate of bitumen degradation at outcrops seems to coincide with the rate of weathering and erosion of the host rock. It can be concluded from the results that the time scales necessary to achieve significant alteration of bitumen under the given conditions far exceed the time scales dictated by the half-lives of radionuclides in low- and medium-level radioactive waste

  5. Cooee bitumen II: Stability of linear asphaltene nanoaggregates

    OpenAIRE

    Lemarchand, Claire,; Schrøder, Thomas; Dyre, J.C.; Hansen, Jesper Schmidt

    2014-01-01

    Asphaltene and smaller aromatic molecules tend to form linear nanoaggregates in bitumen. Over the years bitumen undergoes chemical aging and during this process, the size of the nanoaggregate increases. This increase is associated with an increase in viscosity and brittleness of the bitumen, eventually leading to road deterioration. This paper focuses on understanding the mechanisms behind nanoaggregate size and stability. We used molecular dynamics simulations to quantify the probability of ...

  6. Effect of base bitumen composition on asphalt rubber binder properties

    OpenAIRE

    Partl, M.N.; Ould-Henia, M.; Dumont, A.-G.

    2008-01-01

    The asphalt rubber blend properties are strongly related to its base components properties. The base bitumen composition is considered as a key factor influencing the final rheological properties of asphalt rubber binder. This paper describes results from a laboratory investigation of the interaction between crumb rubber and different composition bitumen according to the wet process. The bitumen composition is determined according to the SARA decomposition approac...

  7. Determination of organic products resulting of chemical and radiochemical decompositions of bitumen. Applications to embedded bitumens

    International Nuclear Information System (INIS)

    Bitumen can be used for embedding most of wastes because of its high impermeability and its relatively low reactivity with of chemicals. Bituminization is one of selected solutions in agreement with nuclear safety, waste compatibility and economic criteria. Bitumen, during storage, undergoes an auto-irradiation due to embedded radio-elements. During this stage,drums are not airtight then oxygen is present. In disposal configuration, water, which is a potential vector of radioactivity and organic matter, is an other hazard factor liable to deteriorate the containment characteristics of bitumen wastes. The generation of water-soluble organic complexing agents can affect the integrity of the wasteform due to an increase of the radionuclides solubility. The first aim of this work is the quantitative and qualitative characterisation of soluble organic matter in bitumen leachates. Different leaching solutions were tested (various pH, ionic strength, ratio S/V). When the pH of the leaching solutions increases, the total organic carbon released increases as well. Identified molecules are aromatics like naphthalene, oxidised compounds like alcohols, linear carbonyls, aromatics, glycols and nitrogen compounds. For the cement equilibrated solution (pH 13.5), the effect of ionic strength becomes significative and influences the release of soluble organic matter. This soluble organic matter can be bio-degraded if microorganisms can growth. The second aim of this work is to study the effect of radio-oxidative ageing on the bitumen confinement properties. During radio-oxidation, the chemical properties of bitumen are modified. The μ-IRTF analysis shows the formation of hydroxyl compounds and aromatic acids. The formation of these polar groups does not influence in our study the water uptake. However the organic matter release increases significantly with the irradiation dose. (author)

  8. Pipeline transportation of emerging partially upgraded bitumen

    International Nuclear Information System (INIS)

    The recoverable reserves of Canada's vast oil deposits is estimated to be 335 billion barrels (bbl), most of which are in the Alberta oil sands. Canada was the largest import supplier of crude oil to the United States in 2001, followed by Saudi Arabia. By 2011, the production of oil sands is expected to increase to 50 per cent of Canada's oil, and conventional oil production will decline as more production will be provided by synthetic light oil and bitumen. This paper lists the announced oil sands projects. If all are to proceed, production would reach 3,445,000 bbl per day by 2011. The three main challenges regarding the transportation and marketing of this new production were described. The first is to expand the physical capacity of existing pipelines. The second is the supply of low viscosity diluent (such as natural gas condensate or synthetic diluent) to reduce the viscosity and density of the bitumen as it passes through the pipelines. The current pipeline specifications and procedures to transport partially upgraded products are presented. The final challenge is the projected refinery market constraint to process the bitumen and synthetic light oil into consumer fuel products. These challenges can be addressed by modifying refineries and increasing Canadian access in Petroleum Administration Defense District (PADD) II and IV. The technology for partial upgrading of bitumen to produce pipeline specification oil, reduce diluent requirements and add sales value, is currently under development. The number of existing refineries to potentially accept partially upgraded product is listed. The partially upgraded bitumen will be in demand for additional upgrading to end user products, and new opportunities will be presented as additional pipeline capacity is made available to transport crude to U.S. markets and overseas. The paper describes the following emerging partial upgrading methods: the OrCrude upgrading process, rapid thermal processing, CPJ process for

  9. Investigations of Physical and Rheological Properties of Aged Rubberised Bitumen

    Directory of Open Access Journals (Sweden)

    Asim Hassan Ali

    2013-01-01

    Full Text Available Several road pavement distresses are related to rheological bitumen properties. Rutting and fatigue cracking are the major distresses that lead to permanent failures in pavement construction. Influence of crumb rubber modifier (CRM on rheological properties of bitumen binder such as improvement of high and intermediate temperatures is investigated in the binder’s fatigue and rutting resistance through physical-rheological changes in this research. The bitumen binders were aged by rolling thin film oven (RTFOT to simulate short-term aging and pressure aging vessel (PAV to simulate long-term aging. The effects of aging on the rheological and physical properties of bitumen binders were studied conducting dynamic shear rheometer test (DSR, Brookfield viscometer test, softening point test, and penetration test. The results showed that the use of rubberised bitumen binder reduces the aging effect on physical and rheological properties of the bitumen binder as illustrated through lower aging index of viscosity, lower aging index of , and an increase in with crumb rubber modifier content increasing, indicating that the crumb rubber might improve the aging resistance of rubberised bitumen binder. In addition, the results showed that the softening point increment ( and penetration aging ratio (PAR of the rubberised bitumen binder decreased significantly due to crumb rubber modification. Furthermore, the higher crumb rubber content, the lower after PAV aging, which led to higher resistance to fatigue cracking bitumen.

  10. Oil sands supply outlook : potential supply and costs of crude bitumen and synthetic crude oil in Canada, 2003-2017

    International Nuclear Information System (INIS)

    This assessment of the Canadian oil sands industry addressed bitumen and synthetic crude oil supply costs based on extraction, production and upgrading technologies. Forecasts of production under various global scenarios and energy price outlooks were also presented. It was revealed that the future for the already well-established oil sands industry is promising, particularly given the outlook for oil prices. Alberta's bitumen resources are one of the world's largest hydrocarbon deposits. At year-end 2002, the remaining established reserves of crude bitumen in Alberta were estimated to be 174.4 billion barrels and further growth is expected. The challenges facing the industry include higher industry supply costs and the need for innovative commercial and technological solutions to address the risks of irregularities and changes in crude oil prices. This report discussed the resource base, recovery technologies, history of the oil sands industry, proposed oil sands development projects, and capital and operating costs. Supply costs for a range of oil sands recovery technologies and production projections under various business scenarios were included. Environmental issues were also addressed along with energy requirements, water requirements, water supply, diluent requirements, infrastructure constraints, and market constraints. The potential effect of natural gas production on the recovery of crude bitumen in the Athabasca oil sands area was also reviewed. Information on every operating, proposed and planned oil sands project in Alberta is available to organizations who provided funding for this study. 84 refs., 42 tabs., 24 figs

  11. Briquetting mechanism and waterproof performance of bio-briquette

    Energy Technology Data Exchange (ETDEWEB)

    Huang, G.; Chen, L.; Cao, J. [Henen Polytechnic University, Jiaozuo (China)

    2008-07-15

    Maize stalk and bio-briquette binder made from it were studied comparatively by FTIR and the microstructure of bio-briquette was observed and analyzed by microscopy. It was found that a large amount of unreacted biomass fibers exist in the binder. These form a multi-level network structure inside the bio-briquette and could make fine coal particles connect together. The multi-level network structure would be still present after the bio-briquettes are immersed in water for 24 hours. On the other hand, stalk materials could be partly degraded after treatment and, with other liquid ingredients in the binder, the degradation products could form a viscous fluid which would work as a bonding ingredient inside the bio-briquette and could improve the waterproofing ability of the binder after solidification. Therefore, the multi-level network structure of the biomaterial and the presence of viscous fluid are very important to the shaping and the improvement of the waterproofing ability of bio-briquettes. 11 refs., 3 figs.

  12. Investigating the rheological properties of crumb rubber modified bitumen and its correlation with temperature susceptibility

    Directory of Open Access Journals (Sweden)

    Nuha Salim Mashaan

    2013-02-01

    Full Text Available There is substantial evidence on the advantages of using crumb rubber in enhancing conventional bitumen properties, gaining environmental protection and boosting industrial-economical benefits. Thus, the use of this ingenious additive in bitumen modification through sustainable technology is highly advocated.The main objective of this research is to investigate the effects of different blending conditions (of time and temperature and various crumb rubber contents on the properties of bitumen binders. Testing was conducted using the Dynamic shear rheometer (DSR test and softening point test. The results showed that differing crumb rubber contents and blending temperature have significant effects on modified binder properties whereas the blending time showed an insignificant effect. Higher blending temperature and crumb rubber content were found to influence the interaction of bitumen-rubber blends and also increased the swelling rate of rubber particles, resulting in an increase in complex shear modulus (G*, storage modulus (G', loss modulus (G" and softening point as well as a decrease in phase angle (δ. Thus, the modified bitumen became less susceptible to deformation after stress removals. The study also presented a considerable relationship between rheological parameters (G*, G', G' and δ and softening point in terms of predicting physical-mechanical properties regardless of blending conditions. Thus, in terms of elasticity for the softening point data, the storage modulus and phase angle were found to be good indicators of binder elasticity. When softening point is made available, a prediction about binder ability to recover its original shape after stress removals can be done.

  13. Investigating the rheological properties of crumb rubber modified bitumen and its correlation with temperature susceptibility

    Directory of Open Access Journals (Sweden)

    Nuha Salim Mashaan

    2012-01-01

    Full Text Available There is substantial evidence on the advantages of using crumb rubber in enhancing conventional bitumen properties, gaining environmental protection and boosting industrial-economical benefits. Thus, the use of this ingenious additive in bitumen modification through sustainable technology is highly advocated.The main objective of this research is to investigate the effects of different blending conditions (of time and temperature and various crumb rubber contents on the properties of bitumen binders. Testing was conducted using the Dynamic shear rheometer (DSR test and softening point test. The results showed that differing crumb rubber contents and blending temperature have significant effects on modified binder properties whereas the blending time showed an insignificant effect. Higher blending temperature and crumb rubber content were found to influence the interaction of bitumen-rubber blends and also increased the swelling rate of rubber particles, resulting in an increase in complex shear modulus (G*, storage modulus (G', loss modulus (G" and softening point as well as a decrease in phase angle (δ. Thus, the modified bitumen became less susceptible to deformation after stress removals. The study also presented a considerable relationship between rheological parameters (G*, G', G' and δ and softening point in terms of predicting physical-mechanical properties regardless of blending conditions. Thus, in terms of elasticity for the softening point data, the storage modulus and phase angle were found to be good indicators of binder elasticity. When softening point is made available, a prediction about binder ability to recover its original shape after stress removals can be done.

  14. Impact of fugitive bitumen on polymer-based flocculation of mature fine tailings

    OpenAIRE

    Klein, C.; Harbottle, D; Alagha, L; Xu, Z.

    2013-01-01

    In bitumen recovery from oil sands, a percentage of the bitumen is lost to tailings. The effect of fugitive bitumen on fines settling and consolidation in tailings ponds remains controversial. In the current study, the settling performance of mature fine tailings (MFT) in response to flocculant addition was considered by studying MFT of varying bitumen content. Bitumen content in the MFT was adjusted by controlled removal of bitumen using a Denver flotation cell. The initial settling rate of ...

  15. Vergelijkend AFM Onderzoek: microstructuur van bitumen in relatie tot healing

    NARCIS (Netherlands)

    Schmets, A.J.M.; Nahar, S.N.; Dillingh, B.; Fischer, H.; Scarpas, A.; Erkens, S.

    2012-01-01

    In this report we present the background, the scientific and experimental approach and the results of AFM experiments performed on two different batches of bitumen. The specific bitumen researched in this project has also been studied in the context of the InfraQuest project ‘Pragmatisch Healing On

  16. Natural analogues of bitumen and bituminized radioactive waste

    International Nuclear Information System (INIS)

    Occurrences of natural bitumen provide possibilities to identify and assess materials, processes, phenomena and conditions in nature which can serve as model cases valid also with respect to a final repository. Natural bitumens meet the basic requirements for use as natural analogues. In natural sites, processes of bitumen formation and degradation often work simultaneously. The major processes are thermal alteration, evaporation, reaction with water, biodegradation, oxidation, weathering and radiation degradation. Progress in analytical organic geochemistry made during recent years has enabled a deeper understanding of the structural and compositional effects of these processes on bitumen. This is necessary in natural analogue applications. The time scales involved in degradation processes, as observed in natural occurrences, exceed the time scales dictated by the half-lives of most important fission products in low and medium level waste by orders of magnitude. Only exposure to the weather at the surface leads to a more rapid destruction of bitumen. Trace metals in bitumen arenot released until the matrix is completely destroyed. Products of radiation degradation and weathering of bitumen are able, to a certain degree, to delay migration of the metal ions released. Impregnation with bitumen may effectively reduce the microbial decomposition of easily destructable organic waste components, as can be deduced on the basis of the excellent preservation of fossils observed in bitumen. The complexity of all the natural sites described requires extensive understanding of the origin and kind of organic material in bitumen, its maturation, migration, alteration and degradation and of the geological and tectonic evolution of the site. The latter is used for establishing the time scale

  17. Waterproofed photomultiplier tube assemblies for the Daya Bay reactor neutrino experiment

    Science.gov (United States)

    Chow, Ken; Cummings, John; Edwards, Emily; Edwards, William; Ely, Ry; Hoff, Matthew; Lebanowski, Logan; Li, Bo; Li, Piyi; Lin, Shih-Kai; Liu, Dawei; Liu, Jinchang; Luk, Kam-Biu; Miao, Jiayuan; Napolitano, Jim; Ochoa-Ricoux, Juan Pedro; Peng, Jen-Chieh; Qi, Ming; Steiner, Herbert; Stoler, Paul; Stuart, Mary; Wang, Lingyu; Yang, Changgen; Zhong, Weili

    2015-09-01

    In the Daya Bay Reactor Neutrino Experiment 960 20-cm-diameter waterproof photomultiplier tubes are used to instrument three water pools as Cherenkov detectors for detecting cosmic-ray muons. Of these 960 photomultiplier tubes, 341 are recycled from the MACRO experiment. A systematic program was undertaken to refurbish them as waterproof assemblies. In the context of passing the water leakage check, a success rate better than 97% was achieved. Details of the design, fabrication, testing, operation, and performance of these waterproofed photomultiplier-tube assemblies are presented.

  18. Comparable Evaluation of Leather Waterproofing Behaviour upon Hide Quality. II. Influence of Finishing on Leather Properties

    Directory of Open Access Journals (Sweden)

    Virginija JANKAUSKAITĖ

    2014-06-01

    Full Text Available Unfinished leather has high water vapour permeability and low waterproofness because of its natural porous structure. To modify the surface appearance and hide any defects, to improve physical properties, such as light and rub fastness, resistance to water, solvents, abrasion, etc., leather needs to be finished. In this study the influence of waterborne finishing agents on the waterproofness and breathability of the hydrophobic leather obtained using different retanning, waterproofing, neutralization and dispersing agents has been investigated. The leather was characterized using morphological analysis and permeability studies. DOI: http://dx.doi.org/10.5755/j01.ms.20.2.2339

  19. Waterproofed photomultiplier tube assemblies for the Daya Bay reactor neutrino experiment

    International Nuclear Information System (INIS)

    In the Daya Bay Reactor Neutrino Experiment 960 20-cm-diameter waterproof photomultiplier tubes are used to instrument three water pools as Cherenkov detectors for detecting cosmic-ray muons. Of these 960 photomultiplier tubes, 341 are recycled from the MACRO experiment. A systematic program was undertaken to refurbish them as waterproof assemblies. In the context of passing the water leakage check, a success rate better than 97% was achieved. Details of the design, fabrication, testing, operation, and performance of these waterproofed photomultiplier-tube assemblies are presented

  20. Waterproofed photomultiplier tube assemblies for the Daya Bay reactor neutrino experiment

    Energy Technology Data Exchange (ETDEWEB)

    Chow, Ken [Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Cummings, John [Department of Physics and Astronomy, Siena College, Loudonville, NY 12211 (United States); Edwards, Emily [Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Edwards, William [Physics Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Ely, Ry [Department of Physics, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Hoff, Matthew [Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Lebanowski, Logan [Department of Physics, University of Houston, Houston, TX 77204-5005 (United States); Li, Bo; Li, Piyi [School of Physics, Shandong University, Jinan 250100 (China); Lin, Shih-Kai [Department of Physics, University of Houston, Houston, TX 77204-5005 (United States); Liu, Dawei [Department of Physics, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Liu, Jinchang [Key Laboratory of Particle Astrophysics, Institute of High Energy Physics, Beijing 100049 (China); Luk, Kam-Biu, E-mail: k_luk@berkeley.edu [Department of Physics, University of California, Berkeley, CA 94720 (United States); Physics Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Miao, Jiayuan [School of Physics, Shandong University, Jinan 250100 (China); Napolitano, Jim [Department of Physics, Temple University, Philadelphia, PA 19122 (United States); Ochoa-Ricoux, Juan Pedro [Physics Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Peng, Jen-Chieh [Department of Physics, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Qi, Ming [Department of Physics, Nanjing University, Nanjing 210000 (China); and others

    2015-09-11

    In the Daya Bay Reactor Neutrino Experiment 960 20-cm-diameter waterproof photomultiplier tubes are used to instrument three water pools as Cherenkov detectors for detecting cosmic-ray muons. Of these 960 photomultiplier tubes, 341 are recycled from the MACRO experiment. A systematic program was undertaken to refurbish them as waterproof assemblies. In the context of passing the water leakage check, a success rate better than 97% was achieved. Details of the design, fabrication, testing, operation, and performance of these waterproofed photomultiplier-tube assemblies are presented.

  1. Waterproofed Photomultiplier Tube Assemblies for the Daya Bay Reactor Neutrino Experiment

    CERN Document Server

    Chow, Ken; Edwards, Emily; Edwards, William; Ely, Ry; Hoff, Matthew; Lebanowski, Logan; Li, Bo; Li, Piyi; Lin, Shih-Kai; Liu, Dawei; Liu, Jinchang; Luk, Kam-Biu; Miao, Jiayuan; Napolitano, Jim; Ochoa-Ricoux, Juan Pedro; Peng, Jen-Chieh; Qi, Ming; Steiner, Herbert; Stoler, Paul; Stuart, Mary; Wang, Lingyu; Yang, Changgen; Zhong, Weili

    2015-01-01

    In the Daya Bay Reactor Neutrino Experiment 960 20-cm-diameter waterproof photomultiplier tubes are used to instrument three water pools as Cherenkov detectors for detecting cosmic-ray muons. Of these 960 photomultiplier tubes, 341 are recycled from the MACRO experiment. A systematic program was undertaken to refurbish them as waterproof assemblies. In the context of passing the water leakage check, a success rate better than 97% was achieved. Details of the design, fabrication, testing, operation, and performance of these waterproofed photomultiplier-tube assemblies are presented.

  2. The extraction of bitumen from western oil sands. Final report, July 1989--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1994-03-01

    Research and development of surface extraction and upgrading processes of western tar sands are described. Research areas included modified hot water, fluidized bed, and rotary kiln pyrolysis of tar sands for extraction of bitumen. Bitumen upgrading included solvent extraction of bitumen, and catalytic hydrotreating of bitumen. Characterization of Utah tar sand deposits is also included.

  3. RHEOLOGICAL PROPERTIES AND STORAGE STABILITY OF SEBS POLYMER MODIFIED BITUMEN

    Directory of Open Access Journals (Sweden)

    SI BACHIR DJAFFAR

    2013-05-01

    Full Text Available In this research work, the effects of Styrene–Ethylene-Butylene–Styrene (SEBS modification on the conventional properties and rheological characteristics of pure bitumen were investigated. The polymer modified bitumens (PMBs were prepared by mixing bitumen with SEBS to four polymer contents using laboratory mixer. The physical properties of the PMBs have been determined using conventional test methods. The results indicated that polymer modification improved the conventional properties of the base bitumen such as; penetration, softening point and temperature susceptibility. The results of storage stability test showed that the storage-stable mixtures could be obtained if the polymer content was maintained below about 5 wt%. The rheological properties of the modified binders were characterized using dynamic shear rheometer (DSR. The results of the investigation indicate that the SEBS polymer improve rheological properties of base bitumen, such as increased elastic responses (increased complex shear modulus and decreased phase angle at low to high temperatures. The softening point and TSHRP of the modified bitumen become higher, indicating the improvement of high-temperature property of the modified bitumen.

  4. Marshall properties of waste polymer and nanoclay modified bitumen

    Directory of Open Access Journals (Sweden)

    Sadeque Mohammed

    2014-01-01

    Full Text Available Polymer modified bitumen is emerging as one of the important construction materials for flexible pavements. The addition of polymers in bitumen improves the deformational stability and durability of bitumen. Also Montmorillonite nanoclay has been successfully used as additive in polymer to significantly improve the thermal stability and mechanical properties. The present study, the effect of waste low density polyethylene (LDPE, polypropylene (PP obtained from waste carry bag, crumb rubber obtained from Waste tyre (CRand nanoclay (MMT on Marshall stability have been evaluated. Waste plastics, whose disposal is a matter of concern can be used successfully to modify the bitumen, these waste polymers are added in 2%, 4% and 6% whereas nanoclay is added in 1,2 and 3 % in 60/70 penetration grade bitumen and its effect on stability and flow of bitumen are evaluated. The result of experimental study shows that there is significant improvement in the Marshall Stability of bitumen due addition of waste polymer and nanoclay.

  5. Bitumen pressure cell installation and monitoring procedure: Draft

    International Nuclear Information System (INIS)

    A 6-in. (150-mm)-thick bitumen layer will be placed between the upper shaft preliminary concrete lining and the steel lining component of the final lining. The function of this layer is twofold; first, it will act as a compliant sealing layer which, because of the bitumen's fluid properties, will remain effective even if the concrete and steel lining components suffer significant strains; and second, it will help to ensure a uniform transmission of rock or hydrostatic loads to the inner lining components. A type 200--300 penetration grade bitumen (ASTM D946) will be used, with 32% by weight of added limestone flour. The purpose of the limestone flour is to ensure that the bitumen has a density which is greater than that of the formation fluids, resulting in a positive pressure gradient from the bitumen to the ground water. The resulting mixture will have a specific gravity of about 1.25 at 60/degree/F (15/degree/C). Pressure measurements in the bitumen layer are needed in order to determine loads on the inner lining components. Although some initial loading will occur in response to excavation, full rock and hydrostatic loads will not develop until post-construction thawing of the freeze wall is complete. Loads transmitted by the bitumen layer to the other lining components will be those which act radially, i.e., the bitustatic pressure, or the radial stress if deviatoric stresses develop

  6. Estimation of bitumen and clay content in fine tailings

    International Nuclear Information System (INIS)

    Fine tailings are the components of tailings ponds and the by-product of the oil sand extraction process, consisting mostly of water with small amounts of bitumen, sand, silts and clays. Because of the large volumes of tailings, an important environmental and production process issue involves the reduction of the remaining bitumen in the tailings stream. This paper presented the results of a study that used low field nuclear magnetic resonance (NMR) in order to estimate the bitumen, clay and water content of synthetic tailings samples. NMR is a non-destructive technique that is utilized to determine compositions of oil and brine emulsions and the viscosity of heavy oil and bitumen as well as in reservoir characterization, measuring properties such as permeability, porosity, mobile and immobile fluids, and fluid saturations. The study prepared and tested numerous samples with variable water, bitumen, sand and clay concentrations in the NMR tool under ambient conditions. Two qualities of water and bitumen were used to prepare the synthetic samples. Each type of water and bitumen was analyzed as a single substance and in a mixture with the typical solids found in tailings composition. These included kaolinite, illite, sodium montmorillonite and sand. These synthetic samples were analyzed using different mixing configurations, as a function of time and in two different NMR tools. It was concluded that NMR is a potential application for on-line determination of tailings streams composition. 18 refs., 3 tabs., 17 figs

  7. Rapid method for determining the penetration of bitumens

    Energy Technology Data Exchange (ETDEWEB)

    Frolov, A.F.; Aminov, A.N.; Denisova, T.P.

    1980-01-01

    A rapid method for determining the penetration (for bitumens and other viscous materials) without changing the penetrometer, used according to GOST 1150-73 is proposed. The essence of the method consists in using in place of a cup for bitumen a vessel 83Cm/sup 3/ of cyclindrical tubes with diameter 10-15 mm and height 25 mm. Reducing the amount of bitumen and development of Pv cooling allows one to sharply reduce the test duration from 1.5-2 hours to 15-20 minutes.)

  8. Waterproofed Photomultiplier Tube Assemblies for the Daya Bay Reactor Neutrino Experiment

    OpenAIRE

    Chow, Ken,; Cummings, John; Edwards, Emily; Edwards, William; Ely, Ry; Hoff, Matthew; Lebanowski, Logan; Li, Bo; Li, Piyi; Lin, Shih-Kai; Liu, Dawei; Liu, Jinchang; Luk, Kam-Biu; Miao, Jiayuan; Napolitano, Jim

    2015-01-01

    In the Daya Bay Reactor Neutrino Experiment 960 20-cm-diameter waterproof photomultiplier tubes are used to instrument three water pools as Cherenkov detectors for detecting cosmic-ray muons. Of these 960 photomultiplier tubes, 341 are recycled from the MACRO experiment. A systematic program was undertaken to refurbish them as waterproof assemblies. In the context of passing the water leakage check, a success rate better than 97% was achieved. Details of the design, fabrication, testing, oper...

  9. Investigation of hydrogen and methane production when irradiation of bitumen B45 and bitumen B45 mixed with solid substances

    International Nuclear Information System (INIS)

    Radiolysis of the bitumen components on influence of ionizing radiation causing gases generation, chiefly hydrogen and methane has been investigated. To avoid formation of explosive mixtures of some gases, for example, hydrogen with air, and to avoid heating of mixtures of bitumen and radioactive wastes because of the heat generation during decay, there is necessary to have cooling of bituminized wastes and removal of the radiolysis products in the stores for bituminized radioactive wastes with high specific activity. Investigations has shown that with specific activity higher than 10 Ci/kg heat remowal and remowal af radiolysis products were necessary. Bitumen B45 and bitumen compounds based on it has been exposed both to external irradiation by Cobalt-60 and to internal irradiation by incorporated into bitumen and bitumen compounds Strontium-90, Cesium-137 and Polonium-270. Internal irradiation is modeling real conditions of bituminized radioactive wastes burial. Parameters of the bitumen B45 are given. After irradiation, by means of the gas chromatography method it has been determined that the main components of the gases produced were hydrogen and methane. Volume of hydrogen and methane produced, depending on absorbed dose has been determined and coefficients of the hydrogen and methane production have been calculated. The results of investigations of methane and hydrogene production coefficients dependance from different conditions during external and internal irradiation are given. (I.T.)

  10. Installation of a bitumen coating plant for high-activity concentrates

    International Nuclear Information System (INIS)

    Following the excellent results obtained on the industrial coating of radioactive sludges, the possibility of solidifying also the evaporation concentrates with bitumen has been considered. For high activity concentrates, the use of bitumen is however limited by two main parameters: temperature resistance, irradiation resistance. By making use of the characteristics of a blown bitumen, it has been possible to design a high activity coating pilot plant treating concentrations of several tens of curies per litre. This plant will make use of a screw-type extrusion machine capable of coating treated concentrates at a rate of 20 l/hr. Before being coated, the concentrates will be subjected to a coprecipitation treatment designed to make the radioelements insoluble. This installation will make possible, apart from technological studies, laboratory experiments on the coated material (measurements on self-heating, on electrical charges, on radiolytic gases, and also lixiviation tests. It is at present believed, on the basis of available data, that it is possible to coat concentrates having an activity of 20 Ci/l at a price of 1840 F per cubic metre. (authors)

  11. Mechanisms of chloride decomposition in upgrading oil sands bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Le, T.; Diaz, D.; Gray, M. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical and Materials Engineering; Eaton, P. [Champion Technologies, Fresno, TX (United States); Wu, A. [Syncrude Canada Ltd., Edmonton, AB (Canada). Edmonton Research Centre

    2004-07-01

    In addition to clay minerals, bitumens from mining operations contain chloride salts because of the salinity of the extraction process water and the connate water in the ore. These chlorides form corrosive hydrochloric acid. High concentrations of organic acid components known as naphthenic acids are also found in bitumen from Alberta's oil sands. These also cause corrosion. Chloride salts, clays and organic acids may interact in the presence of steam to promote hydrochloric acid formation causing major corrosion problems in downstream facilities. This study examined the behaviour of these components under upgrading conditions. In particular, it examined the rate and the extent of the hydrolysis reactions for salts found in bitumen. Mixtures of bitumen, salts and organic acids were exposed to flowing steam at 100 to 400 degrees C under nitrogen purge. Ion chromatography was used to analyze the condensed vapours for chloride.

  12. Condensation of Water Vapor on Waterproof Breathable Fabrics

    Institute of Scientific and Technical Information of China (English)

    周小红; 王善元; 袁观洛

    2003-01-01

    Condensation occurs when the local vapor pressure rises above the saturation vapor pressure at the local temperature in theory. A new measuring apparatus were made to obtain temperature and relative humidity simultaneously for the purpose of investigating the mechanism of condensation occurred on the fabrics. The experiment conducted at the standard condition of temperature of 20°C and relative humidity of 65%. The result obtained from experiment showed that condensation could occur under the situation closed to saturation line as the temperature on fabric may be lower than dew point of water vapor in the measuring box depending on the experiment conducted at an ambient environment temperature of 20℃. The range of fabrics studied showed that PTFE laminated fabrics except nylon gingham PTFE laminated fabric facilitates the loss of water vapor and therefore prevent condensation. It is necessary to develop studies from a wide range of fabrics, especially breathable fabrics and under bad experiment condition in order to develop fabrics,which could eliminate condensation, or transport water vapor through the fabric while remaining waterproof.

  13. Bitumen immobilization of aqueous radwaste by thin-film evaporation

    International Nuclear Information System (INIS)

    In the early 1980s, AECL built a Waste Treatment Centre (WTC) for managing low-level solid and aqueous liquid wastes for converting CANDU wastes. At present, two liquid waste streams are being treated at the WTC. The liquid waste streams are volume-reduced by a combination of continuous crossflow microfiltration (MF), spiral wound reverse osmosis (SWRO) and tubular reverse osmosis (TRO) membrane technologies. The concentrate produced from the TRO system and the volume-reduced MF backwash solutions are evaporated while simultaneously adding bitumen in a thin-film evaporator. A water-free product of chemical and radiochemical salts and bitumen is removed in 200-L galvanized steel drums for storage. The radiation field of product drums on contact typically has a value of 0.5 to 3 R/h depending upon the feed concentration of radioactivity to the evaporator. The total solids content in the 200-L drum ranges from 25 to 35%. Encapsulated in the bitumen matrix are a variety of nonradiochemical salts, which comprise the bulk of the total solids that are in the product drum. This report discusses the immobilization of the aqueous waste with bitumen in a thin-film evaporator. Simulated bituminized waste forms were leached in accordance with the ANS/ANSI 16.1 leach test. In this test, the waste form is immersed under water for an extended period of time, and the leachate is periodically removed and chemically analysed. The Leachability index varied between 7 and 9 for the emulsified bitumen waste forms produced at the WTC. Bitumen samples were unconfined and subjected to immersion and frequent leachate replenishment. The results of leach tests will be a lower bound for the performance of the bitumen waste product in an unsaturated environment. The Leachability indexes reported exceeds the USNRC minimum requirement for wasteform criteria. Adding protective overcoats of either Portland cement or oxidized bitumen enhanced the Leachability index. 8 refs., 3 tabs., 6 figs

  14. ELASTICITY OF BITUMEN BINDERS AND THE FACTORS CAUSING IT

    Directory of Open Access Journals (Sweden)

    A. Galkin

    2015-12-01

    Full Text Available The article deals with the influence of the initial bitumen penetration grade and different con-centrations of the mineral filler on the elasticity of the polymer-modified bitumen (PMB with 3 and 6 % of SBS type polymer. The dependences of elasticity of the PMB on the test conditions – such as the temperature and the stress state level are shown additionally.

  15. ESTIMATE OF WORLD HEAVY CRUDE OIL AND NATURAL BITUMEN RESOURCES.

    Science.gov (United States)

    Meyer, Richard F.; Schenk, Christopher J.

    1985-01-01

    The quantity of heavy hydrocarbons - heavy crude oil and natural bitumens - known or surmised to be present in the earth is large. The total is estimated to fall in the range of 5,879,712-5,942,139 million barrels. The portion of this that may ultimately prove recoverable is small, perhaps on the order of 500,000 million barrels of heavy crude oil and 200,000 million barrels of bitumen.

  16. Waterproof Anti-Explosive Powders for Coal Mines

    Science.gov (United States)

    Buczek, Bronisław; Vogt, Elżbieta

    2014-03-01

    Limestone powder characterized by hydrophobic properties is used as an anti-explosive agent in coal mining industry. Unfortunately, the standard method of producing such powder by milling limestone with stearic acid is practically unprofitable in many modernized quarries and plants, and sometimes literally impossible due to the introduction of technological changes and implementation of modern mills. Then new methods of hydrophobization of limestone surfaces ought be searched. In the work two methods hydrophobization: from the stearic acid vapour phase and from silicone solutions are proposed. Lime dust from the Czatkowice Quarry of Lime was used as a raw material during investigations. It is a good agent for research because it is possible to compare the properties of samples modified in this work to the properties of anti-explosive lime powder (Polish Standard, 1994) used in mining industry in Poland. The first technique of limestone powder hydrophobization was carried out in an apparatus of own design (Vogt, 2008, 2011), and it consisted in free sedimentation of the powder layer dispersed by stearic acid vapour in powder counter current flow. The second way of modification consisted in mixing in the evaporating dish substrates: limestone powder and dope - silicone solution - Sarsil® H-15 (Vogt & Opaliński, 2009; Vogt & Hołownia, 2010). Evaluation of properties so-obtained waterproof powders was carried out according to the Polish Standard, as well as using original powder determination ways, with the Powder Characteristic Tester (Index tables, Tablets & Capsules, 2005). Moreover water vapour adsorption isotherms were obtained and the thermal decomposition of powder was made. All modified samples acquired the hydrophobic character. Therefore we can state that the both proposed methods of hydrophobization of the limestone powder are useful. The parameters obtained with the use of Powder Characteristics Tester enable us to make a characterization of limestone

  17. Storage stability of SBS/sulfur modified bitumens at high temperature: influence of bitumen composition and structure

    OpenAIRE

    Aguirre de Carcer, I.; Masegosa Fanego, Rosa María; Viñas Sánchez, María Teresa; Sanchez-Cabezudo Tirado, Marta; Salom Coll, Catalina; González Prolongo, Margarita; Contreras, Verónica; Barceló, Francisco; Páez, Antonio

    2014-01-01

    Polymer modified bitumens, PMBs, are usually prepared at high temperature and subsequently stored for a period of time, also at high temperature. The stability of PMBs, in these conditions, has a decisive influence in order to obtain the adequate performances for practical applications. In this article the attention is focused in the analysis of the factors that determine the stability of styrene–butadiene–styrene copolymer (SBS)/sulfur modified bitumens when the mixtures are maintained at hi...

  18. The extraction of bitumen from western tar sands. Annual report, July 1990--July 1991

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1992-04-01

    Contents of this report include the following: executive summary; characterization of the native bitumen from the Whiterocks oil sand deposit; influence of carboxylic acid content on bitumen viscosity; water based oil sand separation technology; extraction of bitumen from western oil sands by an energy-efficient thermal method; large- diameter fluidized bed reactor studies; rotary kiln pyrolysis of oil sand; catalytic upgrading of bitumen and bitumen derived liquids; ebullieted bed hydrotreating and hydrocracking; super critical fluid extraction; bitumen upgrading; 232 references; Appendix A--Whiterocks tar sand deposit bibliography; Appendix B--Asphalt Ridge tar sand deposit bibliography; and Appendix C--University of Utah tar sands bibliography.

  19. Bitumen modifiers for reduced temperature asphalts: a comparative analysis between three polymeric and non-polymeric additives

    OpenAIRE

    Cuadri Vega, Antonio Abad; Carrera Páez, Virginia; Izquierdo Rodríguez, María Angeles; García Morales, Moisés; Navarro Domínguez, Francisco Javier

    2014-01-01

    This study presents three bitumen modifiers which may find successful application in the fabrication of binders for warm mix asphalt in the paving industry. In that sense, two non-polymeric additives, thiourea and thiourea dioxide, along with a reactive isocyanate-terminated prepolymer have been evaluated. Viscous flow and linear viscoelasticity tests, at 60 ºC, reveal bituminous modified binders which evolve towards highly viscous materials when subjected to ambient curing. However, at 135 º...

  20. Solubility bitumen testing by VIS-NIR method

    International Nuclear Information System (INIS)

    Complete text of publication follows. Bitumen is a semi-solid material which can be produced from certain oils by distillation or can be found in nature as 'natural asphalt' like 'tar sands, oil sands, etc'. It consists of a mixture of hydrocarbons of different molecular size, aromatic moieties and polarity. The largest use of bitumen is in for road pavements. Asphalt consists of bitumen and mineral mixed together at different amounts. Bituminous binders have varying solubility in different solvents; this property is an important parameter for their quality. The solubility is conventionally determined with a standard European test based on gravimetric differences of the asphalt before and after dissolution; this method is quite time-consuming and gives no information about the chemical nature of the dissolved bitumen. In this work a VIS-NIR (l: 500 - 900 nm) method is proposed based on the dissolution of the asphalt in an suitable filtering funnel equipped with a 270 Mesh (53 mm) filter clamped to a base. The asphalt is grinded and put into the filtering funnel; a specific quantity of solvent is added and after a fixed period of time the solution is filtered and poured into a flask. This solution is diluted in CH2Cl2 in well defined ratios, to become suitable for VIS-NIR analysis. Concentration of the bitumen is obtained from the absorbance values at determined VIS-NIR wavelengths, previously chosen to have no interferences from absorptions of the solvents; for each wavelength, absorbance calibration curves have been carried out. The calculated concentrations are compared to the maximum concentration of bitumen achievable by dissolving the whole bitumen contained in the asphalt, which is inferred from Thermo-Gravimetric Analysis (TGA). Some simple algorithms allow obtaining the degree of solubility of bituminous binders in different solvents. Moreover, the VIS-NIR spectra give information about the aromatic nature of dissolved bitumen. Some ratios between

  1. Studies Concerning Heat-Resisting Additives for Bitumens

    Directory of Open Access Journals (Sweden)

    Livia Groll

    2008-01-01

    Full Text Available The improvement of causeway’s bitumen adhesiveness is becoming a current practice in our country, especially when is used acid (siliceous aggregate. One of the most important properties of bitumen is its adhesiveness to aggregate, and this property determine the using of bitumen in causeways area. Usually the adhesiveness is defined as the capacity of a binder to cover an aggregate without dispersing itself when touching the water or the traffic aggressions. Therefore, the adhesiveness additives are products that improve the adhesiveness of the bitumen to a certain aggregate. The used additives – ADETEN type (A01 and A03 have a high stocking stability, a low toxicity degree toward the amine, diamine, polyamine-based additives and are liquid products perfectly compatible with all bitumens and easy to use, in comparison to the paste or solid additives, which must be made liquid to be used. But a very important condition, which must be fulfilled by these promoters is the heat-resisting condition.

  2. Case study: modeling the phase behavior of solvent diluted bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, P.; Schoeggl, F.F.; Yarranton, H.W. [University of Calgary (Canada); Satyro, M.A. [Virtual Materials Group (Canada)

    2011-07-01

    To recover heavy oil and bitumen, thermal recovery methods such as cyclic steam stimulation and steam assisted gravity drainage are widely used in western Canada. Accurate predictions of phase behavior are required for the design of solvent-based and solvent-assisted heavy oil recovery. This paper presents the phase behavior modeling of solvent-diluted bitumen. The saturation pressures of live and dead bitumen were measured in a JEFRI PVT cell at various concentrations and temperatures. The onset of asphaltene precipitation was also measured for bitumen diluted with n-pentane by titrating bitumen with pentane and constantly circulating the mixture around a high-pressure microscope. The data were modeled using the advanced Peng-Robinson equation of state (APR EoS). By adjusting the binary interaction parameter between the solvent and the pseudo-components, the APR EoS was tuned to match the saturation pressures. The unrealistic phase behavior predictions were made based on the extrapolated SimDist data characterizations.

  3. Bitumen fume-induced gene expression profile in rat lung

    International Nuclear Information System (INIS)

    Exposure to bitumen fumes during paving and roofing activities may represent an occupational health risk. To date, most of the studies performed on the biological effect of asphalt fumes have been done with regard to their content in carcinogenic polycyclic aromatic hydrocarbons (PAH). In order to gain an additional insight into the mechanisms of action of bitumen fumes, we studied their pulmonary effects in rodents following inhalation using the microarray technology. Fisher 344 rats were exposed for 5 days, 6 h/day to bitumen fumes generated at road paving temperature (170 oC) using a nose-only exposition device. With the intention of studying the early transcriptional events induced by asphalt fumes, lung tissues were collected immediately following exposure and gene expression profiles in control and exposed rats were determined by using oligonucleotide microarrays. Data analysis revealed that genes involved in lung inflammatory response as well as genes associated with PAH metabolization and detoxification were highly expressed in bitumen-exposed animals. In addition, the expression of genes related to elastase activity and its inhibition which are associated with emphysema was also modulated. More interestingly genes coding for monoamine oxidases A and B involved in the metabolism of neurotransmitters and xenobiotics were downregulated in exposed rats. Altogether, these data give additional information concerning the bitumen fumes biological effects and would allow to better review the health effects of occupational asphalt fumes exposure

  4. Application of new concept waterproofing in Xiang'an undersea tunnel, China

    Science.gov (United States)

    Chen, Tie-lin; Zhang, Ding-li; Zeng, Chao; Ying, Guo-gang

    2013-03-01

    As a kind of transportation mode for crossing channels, undersea tunnel has incomparable advantages for its directness, convenience, fastness, insusceptibility to weather conditions, and smaller influences on environments. In recent years, with the development of undersea tunnel construction, the design and construction technologies have been greatly enhanced. The first undersea tunnel in China has just been built. Waterproofing is the key technique of undersea tunneling. A new concept of waterproofing scheme of grouting, sealing, draining and divided sections was adopted in the construction of the tunnel based on the researches, the in-situ geological features, the astuteness of the current technology, and the cost of construction. The structural details of the sealing and draining system are introduced to illustrate the salient features of the new waterproofing technique. It is hoped that experiences described in the paper can offer guidance for the construction of the extensive undersea tunnels in the coming years.

  5. Optical and UV-Aging Properties of LDH-Modified Bitumen

    Directory of Open Access Journals (Sweden)

    Xing Liu

    2015-07-01

    Full Text Available Layered double hydroxides (LDHs are an ultraviolet-light (UV resistant material. In this study, LDHs were used to modify bitumen. The optical and UV aging properties of LDHs modified bitumen were investigated. Firstly, the thin films of bitumen, with and without LDHs, were prepared. By using the UV-Vis spectrophotometer, absorbance, reflectance, and transmittance of bituminous thin film were evaluated. The morphology of LDHs-modified bitumen was observed by using fluorescence microscopy (FM. Finally, the aging resistance of LDH-modified bitumen was investigated by using the UV-aging oven. Results indicated that the LDHs, especially with 5 wt % in the bitumen, can effectively absorb and reflect the UV light and improve the UV-aging resistance of bitumen. This implied that the addition of LDHs into bitumen had the potential to prolong the service life of asphalt pavement.

  6. Effect of bitumen emulsion on setting, strength, soundness and moisture resistance of oxychloride cement

    Indian Academy of Sciences (India)

    M P S Chandrawat; T N Ojha; R N Yadav

    2001-06-01

    Addition of bitumen emulsion to the matrix has been found to improve strength and soundness of the product while decreasing the initial setting periods. Thus, bitumen emulsion as an admixture in magnesia cement is a moisture proofing and strengthening material.

  7. Cooee bitumen. II. Stability of linear asphaltene nanoaggregates

    DEFF Research Database (Denmark)

    Lemarchand, Claire; Schrøder, Thomas; Dyre, J. C.;

    2014-01-01

    chose first to consider the simple case where only asphaltene molecules are counted in a nanoaggregate. We used a master equation approach and a related statistical mechanics model. The linear asphaltene nanoaggregates behave as a rigid linear chain. The most complicated case where all aromatic......Asphaltene and smaller aromatic molecules tend to form linear nanoaggregates in bitumen. Over the years bitumen undergoes chemical aging and during this process, the size of the nanoaggregate increases. This increase is associated with an increase in viscosity and brittleness of the bitumen...... molecules are counted in a nanoaggregate is then discussed. The linear aggregates where all aromatic molecules are counted seem to behave as a flexible linear chain...

  8. Uranium-rich xenotime in bitumen, Moonta mines, South Australia

    International Nuclear Information System (INIS)

    Bitumen from the Moonta copper mines is known to exhibit anomalous radioactivity. The bitumen contains abundant metalliferous inclusions, many of which are copper and iron sulphide minerals. Electron microscope studies reported show that the radioactive mineral is an yttrium phosphate phase, resembling xenotime which exhibits significant substitution by uranium, calcium and silicon. An average of 20 analyses yields the formula (Y0.66 U0.23 Ca0.12)1.01(P0.80 Si0.20)O4. A deficiency in the measured element total suggests that the formula may include up to 6 or 7 water molecules. It is assumed that the carbon in the bitumen was derived from younger sedimentary rocks which formerly overlay the ore deposit. 14 refs., 1 tab., 1 fig

  9. Cooee bitumen II: Stability of linear asphaltene nanoaggregates

    CERN Document Server

    Lemarchand, Claire A; Dyre, Jeppe C; Hansen, Jesper S

    2014-01-01

    Asphaltene and smaller aromatic molecules tend to form linear nanoaggregates in bitumen.Over the years bitumen undergoes chemical aging and during this process, the size of the nanoaggregate increases. This increase is associated with an increase in viscosity and brittleness of the bitumen, eventually leading to road deterioration. This paper focuses on understanding the mechanisms behind nanoaggregate size and stability. We used molecular dynamics simulations to quantify the probability of having a nanoaggregate of a given size in the stationary regime. To model this complicated behavior, we chose first to consider the simple case where only asphaltene molecules are counted in a nanoaggregate. We used a master equation approach and a related statistical mechanics model. The linear asphaltene nanoaggregates behave as a rigid linear chain. The most complicated case where all aromatic molecules are counted in a nanoaggregate is then discussed. The linear aggregates where all aromatic molecules are counted seem ...

  10. Cooee bitumen. II. Stability of linear asphaltene nanoaggregates

    Science.gov (United States)

    Lemarchand, Claire A.; Schrøder, Thomas B.; Dyre, Jeppe C.; Hansen, Jesper S.

    2014-10-01

    Asphaltene and smaller aromatic molecules tend to form linear nanoaggregates in bitumen. Over the years bitumen undergoes chemical aging and during this process, the size of the nanoaggregate increases. This increase is associated with an increase in viscosity and brittleness of the bitumen, eventually leading to road deterioration. This paper focuses on understanding the mechanisms behind nanoaggregate size and stability. We used molecular dynamics simulations to quantify the probability of having a nanoaggregate of a given size in the stationary regime. To model this complicated behavior, we chose first to consider the simple case where only asphaltene molecules are counted in a nanoaggregate. We used a master equation approach and a related statistical mechanics model. The linear asphaltene nanoaggregates behave as a rigid linear chain. The most complicated case where all aromatic molecules are counted in a nanoaggregate is then discussed. The linear aggregates where all aromatic molecules are counted seem to behave as a flexible linear chain.

  11. Evaluation of Venezuela's Orinoco bitumen as an MHD fuel

    International Nuclear Information System (INIS)

    The Orinoco Belt in Venezuela contains huge deposits of a bitumen that is complex to handle and refine into lighter hydrocarbon fractions. These deposits are in the early commercialization stage, being marketed as an emulsion with 30% water as a boiler fuel. The fuel is similar to oil in heating value (about 18,100 BTU/lbm) and ash (less than 0.4%). It has an extremely high carbon to hydrogen ratio, a parameter that is important in MHD for electrical conductivity. In this paper, the authors evaluate the potential for this bitumen as a fuel for an MHD Steam Combined Cycle Power Plant. An experimental program to demonstrate the merit of the bitumen as an MHD fuel and validate the calculations is suggested

  12. Diesel and Jet Fuels from Bitumen-derived Middle Distillates

    Institute of Scientific and Technical Information of China (English)

    SokYui

    2004-01-01

    Narrow fractions of light gas oils obtained from various upgrading processes of Athabasca oilsands bitumen were investigated as diesel and jet fuels. The relationship among the boiling range, cetane number, smoke point, and other properties such as aromatics content, aniline point, and the sulfur and nitrogen content was also studied. The study reveals that when appropriate processes and distillation boiling ranges are selected, oilsands bitumen can produce diesel and jet fuels that meet stringent environmental regulations and future product specifications. New correlations to predict CN and smoke point were developed as a function of density, boiling ranges by simulated distillation, and mono- and total aromatics by supercriticaL fluid chromatography. The correlations apply to bitumen-derived middle distiLLates that have a wide range of boiling points.

  13. Four-component united-atom model of bitumen

    DEFF Research Database (Denmark)

    Hansen, Jesper Schmidt; Lemarchand, Claire; Nielsen, Erik; Dyre, J. C.; Schrøder, Thomas

    2013-01-01

    We propose a four-component united-atom molecular model of bitumen. The model includes realistic chemical constituents and introduces a coarse graining level that suppresses the highest frequency modes. Molecular dynamics simulations of the model are carried out using graphic-processor-units based...... software in time spans in order of microseconds, which enables the study of slow relaxation processes characterizing bitumen. This paper also presents results of the model dynamics as expressed through the mean-square displacement, the stress autocorrelation function, and rotational relaxation. The...

  14. Survey of cochlear implant user satisfaction with the Neptune™ waterproof sound processor

    Directory of Open Access Journals (Sweden)

    Jeroen J. Briaire

    2016-04-01

    Full Text Available A multi-center self-assessment survey was conducted to evaluate patient satisfaction with the Advanced Bionics Neptune™ waterproof sound processor used with the AquaMic™ totally submersible microphone. Subjective satisfaction with the different Neptune™ wearing options, comfort, ease of use, sound quality and use of the processor in a range of active and water related situations were assessed for 23 adults and 73 children, using an online and paper based questionnaire. Upgraded subjects compared their previous processor to the Neptune™. The Neptune™ was most popular for use in general sports and in the pool. Subjects were satisfied with the sound quality of the sound processor outside and under water and following submersion. Seventyeight percent of subjects rated waterproofness as being very useful and 83% of the newly implanted subjects selected waterproofness as one of the reasons why they chose the Neptune™ processor. Providing a waterproof sound processor is considered by cochlear implant recipients to be useful and important and is a factor in their processor choice. Subjects reported that they were satisfied with the Neptune™ sound quality, ease of use and different wearing options.

  15. Mechanical properties of dual phase steel quenched in bitumen medium

    Directory of Open Access Journals (Sweden)

    Adeolu A. ADEDIRAN

    2015-05-01

    Full Text Available The mechanical properties of a dual phase steel treated in different intercritical windows and subjected to bitumen as the quenching medium was investigated. The viscosity of the quenchant was altered at several rate, the morphology of phases formed was characterized. Also, the quenched samples produced ferrite-martensite phases obtained at different intercritical windows. The tensile and hardness behaviour of the structures was examined; and the microstructures were characterized. It was observed that samples intercriticaly heat treated at 790°C and held for 60mins, bitumen quenched at 125°C, offers the highest impact toughness, while its counterpart at 730°C soaked for 30mins, bitumen quenched at 125°C offered the least impact toughness value. Sample intercriticaly treated at 790°C and held for 45mins in a 150°C quenching, offered the peak hardness factor. However, samples at 790°C held at 45mins and bitumen quenched at 150°C possessed relatively the best combination of tensile properties, hardness and impact energy. The water quenched samples at 790°C held for 60mins has the peak hardness value. The micrographs as well showed a uniformly distributed dual phase structure of ferrite and martensite at various volume fractions.

  16. Bitumen emulsions based on Ukrainian surface-active substances

    OpenAIRE

    Pyshyev, Serhiy; Grytsenko, Yuriy; Koval, Tetyana

    2013-01-01

    Bitumen emulsions can be obtained based on surface-active substances (SAS) according to DSTU B V.2.7- 129:200 produced at JSC “Barva” (Ukraine). These emulsions meet the demands of mentioned standard relative to sieve residue homogeneity, storage quality after 7 and 14 days and conventional viscosity at 25 C.

  17. Field investigation of potential contamination by bitumen-coated piles

    International Nuclear Information System (INIS)

    Coating piles with bitumen down to their neutral points to debond them from embedding soil is a feasible method to minimize the adverse effects of negative skin friction. Bitumen is a petroleum product composed of numerous extremely complex organic compounds including polycyclic aromatic hydrocarbons (PAHs) that have been identified by the US Environmental Protection Agency (EPA) as toxic and carcinogenic materials. To investigate the engineering behavior of bitumen-coated piles under extreme weather conditions, full-scale field tests were performed in New Orleans, Louisiana, and Edmonton, Alberta, Canada. Instrumented piles were installed at these sites from 1989 to 1990. This paper presents the results of geoenvironmental field investigations performed at these sites to determine the spatial distribution of target PAHs in the subsurface after the piles had been installed for 2--3 1/2 yr. The findings of the investigation indicate that the subsurface contamination, if there is any, caused by the installation of bitumen-coated piles is well within acceptable limits

  18. Rheological properties of nanofiltered Athabasca bitumen and Maya crude oil

    Czech Academy of Sciences Publication Activity Database

    Hasan, M.D.A.; Fulem, Michal; Bazyleva, A.; Shaw, J.M.

    2009-01-01

    Roč. 23, - (2009), s. 5012-5021. ISSN 0887-0624 Institutional research plan: CEZ:AV0Z10100521 Keywords : viscosity * rheology * Athabasca bitumen * Maya crude oil * phase behavior * asphaltenes * nanofiltration Subject RIV: JJ - Other Materials Impact factor: 2.319, year: 2009

  19. Bitumen and heavy oil rheological properties: reconciliation with viscosity measurements

    Czech Academy of Sciences Publication Activity Database

    Bazyleva, A.B.; Hasan, M.D.A.; Fulem, Michal; Becerra, M.; Shaw, J.M.

    2010-01-01

    Roč. 55, č. 3 (2010), s. 1389-1397. ISSN 0021-9568 Institutional research plan: CEZ:AV0Z10100521 Keywords : Athabasca bitumen * Maya crude oil * rheological properties * viscosity measurements Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.089, year: 2010

  20. Catalytic pyrolysis of oilsand bitumen over nanoporous catalysts.

    Science.gov (United States)

    Lee, See-Hoon; Heo, Hyeon Su; Jeong, Kwang-Eun; Yim, Jin-Heong; Jeon, Jong-Ki; Jung, Kyeong Youl; Ko, Young Soo; Kim, Seung-Soo; Park, Young-Kwon

    2011-01-01

    The catalytic cracking of oilsand bitumen was performed over nanoporous materials at atmospheric conditions. The yield of gas increased with application of nanoporous catalysts, with the catalytic conversion to gas highest for Meso-MFI. The cracking activity seemed to correlate with pore size rather than weak acidity or surface area. PMID:21446540

  1. The effect of waterproofing sleeves on the response of FARMER like ionization chambers

    International Nuclear Information System (INIS)

    According to most recent dosimetry protocols, the determination of the absorbed dose to water for photon and electron beams should be performed with non-water-proof ionization chamber along with plastic waterproofing sleeves whose thickness should be less than 1 mm. In these protocols, the correction for the waterproofing sleeve is incorporated in the equation of the perturbation factor pwall. Many SSDLs and hospitals were previously provided with thicker sleeves and are probably still using them for routine calibrations. The objective of the work presented in this paper is to investigate the effect of the waterproofing sleeves on the response of a WELLHOFER IC 70 ionization chambers in a 60Co and two high energy X-ray beams, 6MV and 18 MV. This chamber is inherently waterproof, thus, the ionisation current obtained with sleeves of different thickness is compared to the current obtained without sleeve. The results are improved by performing, for each thickness, at least two series of measurements with and without sleeve. The results show that with 60Co, the ionization response increases from 0.08% to 0.47% for sleeves from 0.75 mm to 1.75 mm. For 6 MV and 18 MV X-rays, the signal decreases respectively by 0.8% and 1%. When taking into account the perturbation correction factor including the waterproofing sleeve component, the ratio R/Ro , where R is the product of the chamber signal and the perturbation factor (the subscript is for the response without sleeve) is increasing from 0.14% to 0.55% for 60Co. For X-rays, this ratio decreases up to 0.75% and 0.59% respectively for 6 MV and for 18 MV. Similar results are obtained with FARMER like ionization chambers

  2. Brewster angle microscopy of Langmuir films of athabasca bitumens, n-C5 asphaltenes, and SAGD bitumen during pressure-area hysteresis.

    Science.gov (United States)

    Hua, Yujuan; Angle, Chandra W

    2013-01-01

    Bitumen films formed on water surfaces have negative consequences, both environmental and economic. CanmetENERGY has placed considerable research emphasis on understanding the structures of the bitumen films on water as a necessary step before optimization of bitumen extraction. The detailed structures of the adsorbed molecules and, especially, the role of asphaltene molecules at the interfaces are still under scrutiny and debate. In the present study, we compared bitumen and asphaltene films as they were compressed and expanded under various surface pressures in order to achieve a clearer understanding of bitumen film structures. We used a customized NIMA Langmuir trough interfaced to a Brewster angle microscope (BAM) and CCD camera (Nanofilm_ep3BAM, Accurion, previously Nanofilm Gmbh) to study images of bitumen films at the air/water interface. The bitumen film appeared uniform with high reflectivity at a surface pressure of 18 mN·m(-1) and exhibited a coarse pebblelike interface with reduced reflectivity in the liquid condensed (LC) phase at higher pressures (18-35 mN·m(-1)). During the first cycle of compression asphaltene films showed well-defined phase transitions and a uniformly smooth interface in the LC phase between 9 and 35 mN·m(-1). However, folding or buckling occurred at surface pressures from 35 to 44 mN·m(-1). On expansion, asphaltene films appeared to break into islands. The hysteresis of the pressure-area isotherm was much larger for asphaltenes than for bitumen. In both compression and expansion cycles, BAM images for bitumen films appeared to be more reproducible than those of the asphaltene films at the same surface pressures. Films for low-°API SAGD bitumen were almost identical to those for surface-mined bitumen. Films formed from partially deasphalted surface-mined bitumens showed higher compressibility and lower rigidity than the original bitumen. The BAM images illustrated significant differences between the partially deasphalted and

  3. The road that's taken : Alberta's bitumen and the world of asphalt

    International Nuclear Information System (INIS)

    Approximately one third of the bitumen produced by the oil sands industry in Canada is used as asphalt in roads and roofing materials. Crude oils used for asphalt production require very little refining. The asphalt market has become a key profit centre for some Cold Lake operators. Imperial Oil has established a research centre devoted to asphalt production at its Sarnia-based refinery. A decline in heavy oil supplies from Mexico and Venezuela has left Canada with a larger margin of the asphalt market. Industry leaders predict that demand for asphalt products will grow by 2.6 per cent per year. A sharp increase in asphalt prices led to many construction delays in 2007. Trials are now being conducted on a new warm mix paving technology that allows users to lower the temperature of asphalt by 20 to 30 degrees C when paving. 2 figs

  4. Does a more refined assessment of exposure to bitumen fume and confounders alter risk estimates from a nested case-control study of lung cancer among European asphalt workers?

    DEFF Research Database (Denmark)

    Agostini, Michela; Ferro, Gilles; Burstyn, Igor;

    2013-01-01

    To investigate whether a refined assessment of exposure to bitumen fume among workers in the European asphalt industry within a nested case-control study resulted in a different interpretation pertaining to risk of lung cancer mortality compared with the cohort study.......To investigate whether a refined assessment of exposure to bitumen fume among workers in the European asphalt industry within a nested case-control study resulted in a different interpretation pertaining to risk of lung cancer mortality compared with the cohort study....

  5. The extraction of bitumen from western oil sands: Volume 1. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1997-11-26

    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains an executive summary and reports for five of these projects. 137 figs., 49 tabs.

  6. The extraction of bitumen from western oil sands: Volume 2. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1997-11-26

    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains reports on nine of these projects, references, and a bibliography. 351 refs., 192 figs., 65 tabs.

  7. The extraction of bitumen from western oil sands. Quarterly report, July--September, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1993-11-01

    This report cites task number followed by a brief statement of each task and the action taken this quarter. The tasks are: NEPA environmental information statement; coupled fluidized-bed bitumen recovery and coked sand combustion; water-based recovery of bitumen; rotary kiln process for recovery of bitumen and combustion of coke sand; recovery of bitumen from oil sands using fluidized bed reactors and combustion of spent sands in transport reactors; recovery of bitumen from oil sand and upgrading of bitumen by solvent extraction; catalytic and thermal upgrading of bitumens and bitumen-derived liquids; evaluation of Utah`s major oil sand deposits for the production of asphalt, high energy jet fuels, and other specialty products; development of mathematical models for bitumen recovery and processing; completion of the cost estimation study of the pilot plant restoration; development studies of equipment for three-product gravity separation of bitumen and sand; development studies of disposal of sand by conveying or pumping of high solids concentration sand-water slurries; and environmental studies of the North Salt Lake pilot plant rehabilitation and eventual operation and those environmental problems associated with eventual commercial products.

  8. Synthesis and characterization of organic intercalated layered double hydroxides and their application in bitumen modification

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Song [State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070 (China); Yu, Jianying, E-mail: jyyu@whut.edu.cn [State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070 (China); Sun, Yubin [Center for Materials Research and Analysis, Wuhan University of Technology, Wuhan 430070 (China); Wu, Shaopeng [State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070 (China)

    2015-02-15

    Organic layered double hydroxides (LDHs) intercalated by sodium dodecylbenzenesulfonate (SDBS) were prepared by anion-exchange method and applied to modify bitumen aiming at improving ageing resistance of bitumen. The organic LDHs (SDBS–LDHs) were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and Ultraviolet and visible (UV–vis) spectrophotometry. The effect of SDBS–LDHs and LDHs on physical and anti-ageing properties of bitumen was evaluated by means of conventional and rheological test. The results of XRD, FTIR and SEM show that SDBS is successfully intercalated into interlayer of LDHs, and the UV–vis reflectance and absorbance curves illustrate that intercalation of SDBS enhances the UV shielding effect of LDHs. The addition of SDBS–LDHs or LDHs has little influence on physical properties of bitumen because SDBS–LDHs and LDHs are physically mixed in bitumen. Compared with pristine bitumen after TFOT and UV irradiation ageing, the introduction of SDBS–LDHs and LDHs significantly improves thermal- and photo-oxidative ageing resistance of bitumen. Notably, bitumen with SDBS–LDHs exhibits better anti-ageing performance than that with LDHs, implying more effective modification of SDBS-LDHs which is due to the enhanced UV protective ability and compatibility with bitumen of SDBS–LDHs. - Highlights: • XRD, FTIR and SEM were used to confirm the successful intercalation. • SDBS–LDHs show superior UV protective ability. • SDBS–LDHs improved the anti-ageing properties of bitumen.

  9. Synthesis and characterization of organic intercalated layered double hydroxides and their application in bitumen modification

    International Nuclear Information System (INIS)

    Organic layered double hydroxides (LDHs) intercalated by sodium dodecylbenzenesulfonate (SDBS) were prepared by anion-exchange method and applied to modify bitumen aiming at improving ageing resistance of bitumen. The organic LDHs (SDBS–LDHs) were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and Ultraviolet and visible (UV–vis) spectrophotometry. The effect of SDBS–LDHs and LDHs on physical and anti-ageing properties of bitumen was evaluated by means of conventional and rheological test. The results of XRD, FTIR and SEM show that SDBS is successfully intercalated into interlayer of LDHs, and the UV–vis reflectance and absorbance curves illustrate that intercalation of SDBS enhances the UV shielding effect of LDHs. The addition of SDBS–LDHs or LDHs has little influence on physical properties of bitumen because SDBS–LDHs and LDHs are physically mixed in bitumen. Compared with pristine bitumen after TFOT and UV irradiation ageing, the introduction of SDBS–LDHs and LDHs significantly improves thermal- and photo-oxidative ageing resistance of bitumen. Notably, bitumen with SDBS–LDHs exhibits better anti-ageing performance than that with LDHs, implying more effective modification of SDBS-LDHs which is due to the enhanced UV protective ability and compatibility with bitumen of SDBS–LDHs. - Highlights: • XRD, FTIR and SEM were used to confirm the successful intercalation. • SDBS–LDHs show superior UV protective ability. • SDBS–LDHs improved the anti-ageing properties of bitumen

  10. Thermal recovery of bitumen from carbonate reservoirs: formation damage aspects

    Energy Technology Data Exchange (ETDEWEB)

    Thimm, H.F. [Thimm Petroleum Technologies Inc. (Canada)

    2011-07-01

    In Alberta, about a third of bitumen resources are located in carbonate reservoirs but none of it is considered as a reserve by the Alberta Energy Resources Conservation Board (ERCB). In fact no pilot has been successful in recovering bitumen from carbonate reservoirs due to formation damage problems. Carbonate rock is chemically active at the high temperatures reached in thermal recovery processes, carbon dioxide is generated and carbonate minerals are precipitated. The aim of this paper is to find methods to control the phenomenon. Kinetic and thermodynamic controls were used. Results showed that formation damage is due to aqueous carbon dioxide attacking the reservoir rock. They found that a reduction of the partial pressure of carbon dioxide could inhibit the initial dissolution of rock material by reducing the concentration of aqueous carbon dioxide. A method to overcome the formation damage problem was found and a co-injection of gas and steam process was developed to apply it.

  11. Four-component united-atom model of bitumen

    CERN Document Server

    Hansen, Jesper S; Nielsen, Erik; Dyre, Jeppe C; Schrøder, Thomas B

    2013-01-01

    We propose a four-component molecular model of bitumen. The model includes realistic chemical constituents and introduces a coarse-graining level that suppresses the highest frequency modes. Molecular dynamics simulations of the model are being carried out using Graphic-Processor-Units based software in time spans in order of microseconds, and this enables the study of slow relaxation processes characterizing bitumen. This paper focuses on the high-temperature dynamics as expressed through the mean-square displacement, the stress autocorrelation function, and rotational relaxation. The diffusivity of the individual molecules changes little as a function of temperature and reveals distinct dynamical time scales as a result of the different constituents in the system. Different time scales are also observed for the rotational relaxation. The stress autocorrelation function features a slow non-exponential decay for all temperatures studied. From the stress autocorrelation function, the shear viscosity and shear ...

  12. Common ground : bitumen and gas producers come together to find gas-over-bitumen solutions

    Energy Technology Data Exchange (ETDEWEB)

    Ross, E.

    2005-08-01

    The gas-over-bitumen issue has meant that hundreds of natural gas wells remain closed while regulatory hearings and research activities continue. The Alberta Energy and Utilities Board should soon reach a final decision on the status of gas wells considered to be a threat to thermal extraction of underlying oil sands. This article discussed collaborative efforts by oil and gas companies to resolve these issues, including the use of fluid injection technology, low pressure Steam-Assisted Gravity Drainage (SAGD) and artificial lift. The objective of the Gas Reinjection and Production Experiment (GRIPE) is to reinject gas to displace natural gas being produced. The pilot project, conducted by Paramount Resources Ltd., consists of 2 injector wells, 4 producers and 12 observation wells that measure gas pressure in the reservoir. The project also includes a 2 stage compressor modified to handle flue gas. According to reservoir simulations, Paramount should be able to recover between 50 to 60 per cent of the remaining gas in place. Results from the pilot suggest that the technique could result in more than half the currently shut-in pools being re-opened. It was suggested that gas-by-gas displacement may result in higher recovery rates because there is usually more remaining gas in place. It was noted that EnCana Corporation has also been repressurizing a depleted natural gas pool by injecting compressed air rather than flue gas. Various other projects were reviewed, including the use of electric submersible pumps, low pressure SAGD and new SAGD well pair configurations. It was concluded that the artificial lift and low pressure SAGD technical sub-committee have now filed 10 applications for funding under the Alberta Energy Department's Innovative Energy Technology Program.

  13. Mechanical properties of dual phase steel quenched in bitumen medium

    OpenAIRE

    Adeolu A.ADEDIRAN; Aribo, Sunday; Muhammed Olalekan Hakeem AMUDA

    2015-01-01

    The mechanical properties of a dual phase steel treated in different intercritical windows and subjected to bitumen as the quenching medium was investigated. The viscosity of the quenchant was altered at several rate, the morphology of phases formed was characterized. Also, the quenched samples produced ferrite-martensite phases obtained at different intercritical windows. The tensile and hardness behaviour of the structures was examined; and the microstructures were characterized. It was obs...

  14. A Different Approach of the Adhesiveness of Bitumens to Aggregates

    Directory of Open Access Journals (Sweden)

    Loredana Judele

    2007-01-01

    Full Text Available The estimation of the capacity of coverage in the laboratory may be made visually as well. The operator ’s subjective perspective, the angle of view, the luminosity, the nature and colour of aggregates are many factors that may influence the result. The computer-assisted image analysis qualifies and quantifies objectively enough the capacity of coverage of bitumen on aggregates, removing any exterior influences. It is a simple, repeatable and reproducible used method.

  15. Kinetic of the reaction between bitumen and sulphur

    International Nuclear Information System (INIS)

    The utilization of sulphur in bituminous binders has been tried for many years in a number of countries, mainly USA and Canada. The overall purpose of this study was to evaluate the kinetics of the reaction between elemental sulphur and bitumen, with the production of hydrogen sulfide. The work was carried out with the help of a thermo balance. It was shown that H2S evolution starts immediately after sulphur melting and that the rate of reaction is of second order

  16. Waterproofing in Arabidopsis: Following phenolics and lipids in situ by Confocal Raman Microscopy

    Directory of Open Access Journals (Sweden)

    Batirtze ePrats Mateu

    2016-02-01

    Full Text Available Waterproofing of the aerial organs of plants imposed a big evolutionary step during the colonization of the terrestrial environment. The main plant polymers responsible of water repelling are lipids and lignin, which play also important roles in the protection against biotic/abiotic stresses, regulation of flux of gases and solutes and mechanical stability against negative pressure, among others. While the lipids, non-polymerized cuticular waxes together with the polymerized cutin, protect the outer surface, lignin is confined to the secondary cell wall within mechanical important tissues. In the present work a micro cross-section of the stem of Arabidopsis thaliana was used to track in situ the distribution of these non-carbohydrate polymers by Confocal Raman Microscopy. Raman hyperspectral imaging gives a molecular fingerprint of the native waterproofing tissues and cells with diffraction limited spatial resolution (~300 nm at relatively high speed and without any tedious sample preparation. Lipids and lignified tissues as well as their effect on water content was directly visualized by integrating the 1299 cm-1, 1600 cm-1 and 3400 cm-1 band, respectively. For detailed insights into compositional changes of these polymers vertex component analysis was performed on selected sample positions. Changes have been elucidated in the composition of lignin within the lignified tissues and between interfascicular fibers and xylem vessels. Hydrophobising changes were revealed from the epidermal layer to the cuticle as well as a change in the aromatic composition within the cuticle of trichomes. To verify Raman signatures of different waterproofing polymers additionally Raman spectra of the cuticle and cutin monomer from tomato (Solanum lycopersicum as well as aromatic model polymers (milled wood lignin and dehydrogenation polymer of coniferyl alcohol and phenolic acids were acquired. Keywords: Arabidopsis thaliana, lignin, cutin, wax, Raman

  17. Waterproofing in Arabidopsis: Following phenolics and lipids in situ by Confocal Raman Microscopy

    Science.gov (United States)

    Prats Mateu, Batirtze; Hauser, Marie-Theres; Heredia, Antonio; Gierlinger, Notburga

    2016-02-01

    Waterproofing of the aerial organs of plants imposed a big evolutionary step during the colonization of the terrestrial environment. The main plant polymers responsible of water repelling are lipids and lignin, which play also important roles in the protection against biotic/abiotic stresses, regulation of flux of gases and solutes and mechanical stability against negative pressure, among others. While the lipids, non-polymerized cuticular waxes together with the polymerized cutin, protect the outer surface, lignin is confined to the secondary cell wall within mechanical important tissues. In the present work a micro cross-section of the stem of Arabidopsis thaliana was used to track in situ the distribution of these non-carbohydrate polymers by Confocal Raman Microscopy. Raman hyperspectral imaging gives a molecular fingerprint of the native waterproofing tissues and cells with diffraction limited spatial resolution (~300 nm) at relatively high speed and without any tedious sample preparation. Lipids and lignified tissues as well as their effect on water content was directly visualized by integrating the 1299 cm-1, 1600 cm-1 and 3400 cm-1 band, respectively. For detailed insights into compositional changes of these polymers vertex component analysis was performed on selected sample positions. Changes have been elucidated in the composition of lignin within the lignified tissues and between interfascicular fibers and xylem vessels. Hydrophobising changes were revealed from the epidermal layer to the cuticle as well as a change in the aromatic composition within the cuticle of trichomes. To verify Raman signatures of different waterproofing polymers additionally Raman spectra of the cuticle and cutin monomer from tomato (Solanum lycopersicum) as well as aromatic model polymers (milled wood lignin and dehydrogenation polymer of coniferyl alcohol) and phenolic acids were acquired. Keywords: Arabidopsis thaliana, lignin, cutin, wax, Raman, cuticle, waterproofing

  18. Durability assessment of concrete bridge deck considering waterproof membrane and epoxy-coated reinforcement

    OpenAIRE

    Petr Konečný; Petr Lehner

    2016-01-01

    The effect of waterproof membrane and steel reinforcement protection on the concrete bridge deck is modeled. The attention is paid to the durability prediction related to steel reinforcement corrosion initiation based on the chloride penetration. Thus 2-D finite element chloride ingress model is applied. The transient finite element model serves to solve Fick's second diffusion law using the computer tool compatible with the Matlab environment. The model focuses on the transport of chloride i...

  19. Baseline air quality evaluation for the Venezuelan Orinoco Bitumen Belt

    International Nuclear Information System (INIS)

    To achieve a harmonic relationship between oil exploration and production activities and the environment, Petroleos de Venezuela and its affiliated companies conducted environmental evaluations of the physical and bionic media in the Orinoco Bitumen Belt. This region covers an area of approximately 42000 km2 with estimated bitumen reserves on the order of 3 x 1012 barrels, one of the largest bitumen reservoirs in the world. This paper presents the results of a study of baseline air quality conditions: an emissions inventory, surface and upper layer meteorological conditions and measurements of air quality parameters of interest (CO, HC, NOx, SO2, H2S and T.S.P.) taken by a network of automated air quality stations using standard international reference techniques. The temporal (hourly and daily basis) and spatial air quality variability and the variables/activities that might determine the observed trends are discussed. NO, NO2, SO2 and H2S concentrations were lower than the detection limits of the analytical methods, while O3 and CO 1-hour average levels ranged from 5-30 ppb and 0.5-1.8 ppm, respectively, and T.S.P. daily means varied from 10-50 μg/m3, all of which is close to natural background concentrations. Maximum hourly average reactive hydrocarbon concentrations of 0.37 ppm were found near a producing oil field

  20. Application of New Concept Waterproofing in Xiang'an Undersea Tunnel, China

    Institute of Scientific and Technical Information of China (English)

    CHEN Tie-lin; ZHANG Ding-li; ZENG Chao; YING Guo-gang

    2013-01-01

    As a kind of transportation mode for crossing channels,undersea tunnel has incomparable advantages for its directness,convenience,fastness,insusceptibility to weather conditions,and smaller influences on environments.In recent years,with the development of undersea tunnel construction,the design and construction technologies have been greatly enhanced.The first undersea tunnel in China has just been built.Waterproofing is the key technique of undersea tunneling.A new concept of waterproofing scheme of grouting,sealing,draining and divided sections was adopted in the construction of the tunnel based on the researches,the in-situ geological features,the astuteness of the current technology,and the cost of construction.The structural details of the sealing and draining system are introduced to illustrate the salient features of the new waterproofing technique.It is hoped that experiences described in the paper can offer guidance for the construction of the extensive undersea tunnels in the coming years.

  1. Sustainability Life Cycle Cost Analysis of Roof Waterproofing Methods Considering LCCO2

    Directory of Open Access Journals (Sweden)

    Sangyong Kim

    2013-12-01

    Full Text Available In a construction project, selection of an appropriate method in the planning/design stage is very important for ensuring effective project implementation and success. Many companies have adopted the life cycle cost (LCC method, one of the methods for analyzing economic efficiency, for appropriate decision-making in the basic/detailed design stage by estimating overall costs and expenses generated over the entire project. This paper presents an LCC method for calculating the LCC of CO2 (LCCO2, based on materials committed during the lifecycle of a structure for each roof waterproofing method and adding this cost to the LCC for comparative analysis. Thus, this technique presents the LCC that includes the cost of CO2 emission. The results show that in terms of initial construction cost, asphalt waterproofing had the highest CO2 emission cost, followed by sheet waterproofing. LCCO2 did not greatly influence the initial construction cost and maintenance cost, as it is relatively smaller than the LCC. However, when the number of durable years was changed, the LCC showed some changes.

  2. Does long term exposure to radon gas influence the properties of polymeric waterproof materials?

    International Nuclear Information System (INIS)

    The technical state of buildings and the quality of the indoor environment depend on the quality of the waterproofing course and on the properties of the insulating materials that are applied, in particular on their durability, long-term functional reliability and resistance to corrosive effects of the subsoil. Underground water chemistry and soil bacteria are well-known corrosive agents. Our investigations indicate that the ageing process of waterproof materials can be significantly accelerated by alpha particles emitted by radon and radon progenies which are present in soil gas. Materials commonly available on the building market, e.g. LDPE and HDPE of various densities, PVC, TPO (thermoplastic polyolefin), PP (polypropylene) and EPDM were selected for our experimental study. The preliminary results for 3-year exposure to radon gas show a decrease in tensile strength to 60%, elongation to 80% and hardness to 95% for samples based on PE. The diffusion coefficient of radon for samples based on PVC decreased to 20% of the initial value after 1-year exposure to radon and soil bacteria. - Highlights: • Long-term exposure of waterproof materials to radon and soil bacteria. • Changes in mechanical properties shown. • Major changes in diffusion coefficient of radon found for PVC

  3. Durability assessment of concrete bridge deck considering waterproof membrane and epoxy-coated reinforcement

    Directory of Open Access Journals (Sweden)

    Petr Konečný

    2016-03-01

    Full Text Available The effect of waterproof membrane and steel reinforcement protection on the concrete bridge deck is modeled. The attention is paid to the durability prediction related to steel reinforcement corrosion initiation based on the chloride penetration. Thus 2-D finite element chloride ingress model is applied. The transient finite element model serves to solve Fick's second diffusion law using the computer tool compatible with the Matlab environment. The model focuses on the transport of chloride ions through a reinforced concrete bridge deck with and without the effect of waterproof membrane and on an estimate of the concentration of chlorides at the reinforcement level or in places with damage to the epoxide coating of the reinforcement. The model allows the incorporation of damage to the waterproof insulation under the asphalt coating. The time to chloride induced onset of corrosion is predicted and results are compared. The effect of water proof membrane reinforcement protection strategy typical for Central Europe and epoxy-coating protection widely used in North-Western United States is evaluated.

  4. Non-Newtonian behavior and molecular structure of Cooee bitumen under shear flow

    DEFF Research Database (Denmark)

    Lemarchand, Claire; Bailey, Nicholas; Daivis, Peter; Todd, Billy; Hansen, Jesper Schmidt

    2015-01-01

    The rheology and molecular structure of a model bitumen (Cooee bitumen) under shear are investigated in the non-Newtonian regime using non-equilibrium molecular dynamics simulations. The shear viscosity, normal stress differences, and pressure of the bitumen mixture are computed at different shear...... rates and different temperatures. The model bitumen is shown to be a shear-thinning fluid at all temperatures. In addition, the Cooee model is able to reproduce experimental results showing the formation of nanoaggregates composed of stacks of flat aromatic molecules in bitumen. These nanoaggregates are...... viscosity with temperature at different shear rates is also related to the size and relative composition of the nanoaggregates. The slight anisotropy of the whole sample due to the nanoaggregates is considered and quantified. Finally, the position of bitumen mixtures in the broad literature of complex...

  5. Lessons learned from IOR steamflooding in a bitumen-light oil heterogeneous reservoir

    OpenAIRE

    Al Mudhafar, W.J.M.; Hosseini Nasab, S.M.

    2015-01-01

    The Steamflooding was considered in this research to extract the discontinuous bitumen layers that are located at the oil-water contact for the heterogeneous light oil sandstone reservoir of South Rumaila Field. The reservoir heterogeneity and the bitumen layers impede water aquifer approaching into the reservoir; therefore, Steamflooding would be efficient to extract bitumen layers and improve oil recovery. This research focused on adopting three Design of Experiments (DoE) approaches with t...

  6. Combustion and heat transfer characteristics of pipelineable water-bitumen emulsions

    International Nuclear Information System (INIS)

    This paper reports on a research program undertaken by CANMET's Energy Research Laboratories to compare the combustion and heat transfer characteristics of Western Canadian bitumen emulsions with those of heavy fuel oil. It has been shown that heavy bitumen burns and transfers heat in much the same manner as heavy fuel oil. It was concluded from this research program that bitumen emulsions would make excellent fuels for boilers and process combustors, providing the combustion and handling equipment

  7. Investigation of microstructures and ultraviolet aging properties of organo-montmorillonite/SBS modified bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Henglong [Key Laboratory of Silicate Materials Science and Engineering of Ministry of Education, Wuhan University of Technology, Wuhan (China); Yu Jianying, E-mail: jyyu@whut.edu.cn [Key Laboratory of Silicate Materials Science and Engineering of Ministry of Education, Wuhan University of Technology, Wuhan (China); Wang Huacai; Xue Lihui [Center for Materials Research and Analysis, Wuhan University of Technology, Wuhan 430070 (China)

    2011-10-03

    Highlights: {yields} Microstructures and ultraviolet (UV) aging properties of organo-montmorillonite (OMMT)/Styrene-butadiene-styrene(SBS) modified bitumen were investigated by X-ray diffraction, Fourier transform infrared spectroscopy, atomic force microscopy and physical properties tests. {yields} OMMT/SBS modified bitumen forms an intercalated structure. {yields} The phase contrast between the dispersed domains and the matrix is inverted in SBS modified bitumen, which is decreased with the introduction of OMMT. {yields} The UV aging resistance of SBS modified bitumen can be improved obviously with the addition of OMMT. - Abstract: Organo-montmorillonite(OMMT)/Styrene-butadiene-styrene(SBS) modified bitumen nanocomposites were prepared by melt blending. The microstructures of OMMT/SBS modified bitumen were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and atomic force microscopy (AFM), respectively. The effect of OMMT on ultraviolet (UV) aging properties of SBS modified bitumen was investigated. FTIR and XRD analyses indicate that the OMMT/SBS modified bitumen forms an intercalated structure. It is observed that the phase contrast between the dispersed domains and the matrix is inverted in SBS modified bitumen, which is decreased with the introduction of OMMT according to AFM analysis. As a result of UV aging, both viscosity aging index and softening point increment of OMMT/SBS modified bitumen decrease significantly. There is a single phase trend in the morphology of the bitumen after aging, which is accelerated by the existence of SBS. However, these changes can be effectively prevented under the influence of OMMT, indicating the good UV aging resistance of OMMT/SBS modified bitumen.

  8. Study on possible explosive reactions of sodium nitrate-bitumen mixtures initiated by a shock wave

    International Nuclear Information System (INIS)

    Potential hazards of the mixture sodium nitrate-bitumen obtained by embedding in bitumen liquid radioactive effluents concentrated by evaporation are studied in case of accidental shock wave. A theoretical evaluation based on thermodynamical data show a low probability, nevertheless different from zero. No explosion occurred in tests realized in severe conditions. In conclusion there is no risk of detonation of large quantity of bitumen-nitrates stored in 200-liter drum in radioactive waste storage

  9. Determining the Rheological Properties of Neat and Rubber Modified Soft Bitumen

    OpenAIRE

    Kjosavik, Andreas Meling

    2013-01-01

    The properties of bitumen as an asphalt binder are dependent on temperature. At high temperatures, the bitumen softens enabling permanent deformation of the pavement. At low temperatures, the bitumen becomes stiff and inflexible and can crack as a result of strain and thermal contraction. Adding rubber from ground car tires increases the stiffness at high temperatures while maintaining or improving the flexibility of the binder at low temperatures. This thesis studies the interaction between ...

  10. Impact of maltene and asphaltene fraction on mechanical behavior and microstructure of bitumen

    OpenAIRE

    Hofko, B.; L. Eberhardsteiner; Fussl, J.; H. Grothe; Handle, F.; Hospodka, M.; Grossegger, D.; Nahar, S.N.; Schmets, A. J. M.; Scarpas, A.

    2015-01-01

    As a widely accepted concept, bitumen consists of four fractions that can be distinguished by their polarity. Highly polar asphaltene micelles are dispersed in a viscous phase of saturates, aromatics and resins (maltene phase). Different concentrations of asphaltenes in the bitumen result in a range of mechanical response properties. In an interdisciplinary study the impact of the maltene phase and asphaltenes on the linear viscoelastic behavior and the microstructure of bitumen were analyzed...

  11. Rheological Behaviour of Ethylene-Vinyl-Acetate [EVA] Modified Road Bitumen

    OpenAIRE

    2015-01-01

    In this present study, the effects of Ethylene-Vinyl-Acetate (EVA) on the conventional characteristics and rheological properties of pure bitumen were investigated. The modified bitumen (PMB) has been prepared in laboratory by mixing bitumen with copolymer EVA. Three different contents of polymer have been tested to evaluate the modification. The basic properties of the PMBs have been determined by using conventional test methods. The results indicated that polymer modification improved the c...

  12. 双组份涂料机理及其防水效果探究%Mechanism of Two-component Coatings and Its Waterproofing Effect

    Institute of Scientific and Technical Information of China (English)

    许荣章

    2011-01-01

    目前公路建设、公路养护等普遍采用新型的双组份涂料,双组份涂料以其施工简便、干燥迅速、防水效果好等优点备受各涂料消耗行业青睐.但是随着我国经济的发展,涂料业也如雨后春笋般迅速成长,大大小小的涂料品牌,多种多样的涂料品种混杂在一起使消费者难以辨别.而在众多涂料种类中消费者最常用到的就是防水双组份涂料,由于市场的双组份防水涂料种类繁多,消费者对其作用机理又不是很了解,所以在选购时很难着手.本文就将就这一问题做深入细致的讨论,一方面阐述双足分涂料的作用机理,另一方面分析一下市场状况,为消费这或者企业在选购时提供一些参考.%Current road construction and road maintenance widely use new two-component coatings. For its advantages of simple construction, quick drying, good waterproof effect, two-component coating get much favor of paint industry consumes. But as China's economic development, paint industry has grew rapidly, large and small paint brands and kinds of paint make consumers be difficult to distinguish. In many types of paint, two-component coating is most common kind. Because there are varieties of two-component waterproof coating in market, the consumers do not very understand its role,so it is difficult to purchase. This paper will discuss this issue in depth, on the one hand describes the role mechanism of two-component waterproof coating, on the other hand analyzes the market situation, to provide some reference for the consumer and business.

  13. Hydrogen production from wind energy in Western Canada for upgrading bitumen from oil sands

    International Nuclear Information System (INIS)

    Hydrogen is produced via steam methane reforming (SMR) for bitumen upgrading which results in significant greenhouse gas (GHG) emissions. Wind energy based hydrogen can reduce the GHG footprint of the bitumen upgrading industry. This paper is aimed at developing a detailed data-intensive techno-economic model for assessment of hydrogen production from wind energy via the electrolysis of water. The proposed wind/hydrogen plant is based on an expansion of an existing wind farm with unit wind turbine size of 1.8 MW and with a dual functionality of hydrogen production and electricity generation. An electrolyser size of 240 kW (50 Nm3 H2/h) and 360 kW (90 Nm3 H2/h) proved to be the optimal sizes for constant and variable flow rate electrolysers, respectively. The electrolyser sizes aforementioned yielded a minimum hydrogen production price at base case conditions of $10.15/kg H2 and $7.55/kg H2. The inclusion of a Feed-in-Tariff (FIT) of $0.13/kWh renders the production price of hydrogen equal to SMR i.e. $0.96/kg H2, with an internal rate of return (IRR) of 24%. The minimum hydrogen delivery cost was $4.96/kg H2 at base case conditions. The life cycle CO2 emissions is 6.35 kg CO2/kg H2 including hydrogen delivery to the upgrader via compressed gas trucks. -- Highlights: ► This study involves development of a data intensive techno-economic model for estimation cost of hydrogen production from wind energy. ► Wind energy based electricity is used for electrolysis to produce hydrogen in Western Canada for bitumen upgrading for oil sands. ► Several scenarios were developed to study the electricity generation and hydrogen production from wind energy. ► The cost of production of hydrogen is significantly higher than natural based hydrogen in Western Canada.

  14. Should Alberta upgrade oil sands bitumen? An integrated life cycle framework to evaluate energy systems investment tradeoffs

    International Nuclear Information System (INIS)

    The inclusion of greenhouse gas (GHG) emissions costs in energy systems investment decision-making requires the development of a framework that accounts for GHG and economic tradeoffs. This paper develops such a framework by integrating partial cost–benefit analysis with life cycle assessment to explore the question of whether bitumen should be upgraded in the Canadian province of Alberta to produce synthetic crude oil (SCO), or blended with light hydrocarbons to produce lower-quality diluted bitumen (dilbit). The net present value (NPV) of these options is calculated from the stakeholder perspectives of the oil sands industry, the Alberta public, and a climate-concerned Alberta resident. This calculation includes monetized GHG emissions costs stemming from a hypothetical economy-wide GHG price, and a sensitivity analysis explores the effects of variations in technical and economic conditions on stakeholders’ preferences. We find that under most plausible sets of conditions, industry would prefer the dilution option, while the climate-concerned Alberta resident would prefer the upgrading option. In contrast, the preferences of the general Alberta public depend on the values of key variables (e.g., the SCO-dilbit price differential). Key drivers of differences among stakeholders’ preferences include different perceptions of risks and responsibilities for life cycle GHG emissions. - Highlights: • We develop a novel integrated partial cost-benefit analysis/LCA framework. • We consider stakeholder perspectives, and technical and GHG price variations. • Upgrading is typically less GHG-intensive than dilution per barrel of bitumen. • Dilution is typically less GHG-intensive than upgrading per mega joule of gasoline. • Even stringent GHG prices may not align preferences on energy systems investment decisions

  15. Canadian heavy crude oil and bitumen: Some new and old ideas

    International Nuclear Information System (INIS)

    Canadian conventional heavy oil and bitumen production has been steadily increasing over the last five years. This rise is forecast to continue under modest future crude oil pricing assumptions. During 1990 and 1991, the heavy oil market suffered from wide pricing differentials relative to light crude due to market reductions in Montreal and a feedstock shift at Uno-Ven's Chicago refinery, as well as an increase in the percentage of heavy in the world crude oil supply because of the Iraqi war. These have been offset by price-related bitumen production cuts and minor refinery capacity growth at other locations. The industry is poised for positive change with modest but stable prices and reduced light-heavy differentials caused, in part, by anticipated market expansion due to the June start-up of the Conco coker (50,000 bbl/d) in Montana and the anticipated late fall start up of the Bi-Provincial Upgrader in Saskatchewan (50,000 bbl/d blend). For the future, refinery upgrading and new grass roots refinery additions are suggested for western Canada. Associated transportation savings and condensate blending stock costs are two areas of advantage. Taken together with environmental problems in other densely populated market areas, it makes sense to build new heavy processing capacity near Edmonton but only after all current capacity is debottlenecked and inexpensive additions to current facilities are completed. New capacity will only be built when the heavy/light price differential on feed stock provides economic justification. 11 refs., 2 tabs

  16. Experimental study of CT test on the failure of acrylate spray-applied waterproof layer in the groundwater environment

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    In this study the computerized tomography (CT) was first used to quantitatively analyze the failure of acrylate spray-applied waterproof membrane in the groundwater environment. The results of the CT tests show that it is feasible to use the CT to quantitatively analyze the failure of the waterproof membrane and the CT method has the advantages of speediness and accuracy that can eliminate the fussy operation process in routine tests. The main conclusions summarized from the study are as follows. First, there are two combined-indexes that can be used to decide the failure of the spray-on waterproof layer: one is that the reduced percentage of the CT number of the spray-on waterproof layer is less than 40.0% and the other is that the variance of the CT number decreases first and then increases. Second, the applicability for the spray-on waterproof layer in the groundwater environment is the SO 24-concentration ≤ 1%, the Cl-concentration ≤ 7.5% and the pH value ≤ 12.0 of the groundwater, respectively.

  17. Isocyanate-functionalized castor oil as a novel bitumen modifier

    OpenAIRE

    Cuadri Vega, Antonio Abad; García Morales, Moisés; Navarro Domínguez, Francisco Javier; Partal López, Pedro

    2013-01-01

    The use of biomaterials from renewable sources in the synthesis of polyurethane-derived polymers is lately receiving great attention from social, environmental and economic standpoints. In this work, prepolymers having different -NCO/-OH ratio were synthesized, by reaction of 4,4´-diphenylmethane diisocyanate (MDI) with castor oil (CO), to be used as modifying agent of asphaltic bitumen. Reactions between MDI and CO, performed with -NCO/-OH molar ratios of 8:1 and 4:1, have led to suitable bi...

  18. Prediction of the viscosity of solvent diluted live bitumen at temperatures up to 175 degree Celsius

    Energy Technology Data Exchange (ETDEWEB)

    Motahhari, H.; Schoeggl, F. F.; Yarranton, H. W. [University of Calgary (Canada); Satyro, M. A. [Virtual Materials Group (Canada)

    2011-07-01

    The methodology for predicting heavy and diluted oil bitumen was discussed in this work. The main objective of this paper is to investigate the effectiveness of the expanded fluid (EF) viscosity correlation in predicting live and dead bitumen viscosity. Samples of live and dead Alberta bitumen were prepared and tested at a temperature range of 20 to 175 C and pressures up to 10 MPa. The different sample types identified were: pure bitumen, condensate, diluted dead bitumen, and diluted live bitumen. Oil viscosities were calculated from density measurements obtained using the mixing rule, both ideal and non-ideal. The EF correlation validity was tested from the measured data. It was shown that live bitumen viscosity obtained from the correlation deviated from measured data by 20 to 28%, whereas deviations in the dead bitumen were lower. In general, it was shown that the EF correlation proved to be a practical method for predicting the viscosity of heavy crudes subjected to thermal and solvent treatment.

  19. On the investigation of the bulk microstructure of bitumen - Introducing two new techniques

    NARCIS (Netherlands)

    Fischer, H.R.; Dillingh, E.C.

    2014-01-01

    Bitumen, the residue of oil distillation and applied e.g. as binder in asphalt pavements displays a rich microstructure at the bitumen surface-to-air surface with several clearly distinguishable phases. However, uncertainty still remains whether this micro-structure is just present at free surfaces

  20. High and Low Temperature Properties of FT-Paraffin-Modified Bitumen

    Directory of Open Access Journals (Sweden)

    Hassan Fazaeli

    2012-01-01

    Full Text Available This paper presents the results of an experimental research on the effects of “Fischer Tropsch-Paraffin” (Sasobit content on physical and rheological properties of Sasobit modified bitumen at various operational temperatures. For this purpose, bitumen with a Performance Grade (PG of 58–22 is selected as the base and later it is modified with 1, 2, 2.5, 3, and 4 weight percent of FT-Paraffin (Sasobit. The performance of modified bitumen at high, intermediate, and low temperatures is evaluated based on Strategic Highway Research Program (SHRP Superpave tests. Results of the study show that FT-paraffin improves the performance of bitumen at high temperatures in addition to increasing the resistance of mixture against permanent deformation. Despite the advantages of FT-paraffin on bitumen performance at high temperatures, it does not show a considerable influence on the intermediate and low temperature performance of bitumen. The effect of FT-paraffin content on the viscosity of modified bitumen is also investigated using Brookfield Viscometer Apparatus. Results show that increasing the additive content lowers the viscosity of modified bitumen. This in return can reduce the mixing and compaction temperature of asphalt mixtures.

  1. Quantification of bitumen particles in aerosol and soil samples using HP-GPC

    DEFF Research Database (Denmark)

    Fauser, Patrik; Tjell, Jens Christian; Mosbæk, Hans;

    2000-01-01

    A method for identifying and quantifying bitumen particles, generated from the wear of roadway asphalts, in aerosol and soil samples has been developed. Bitumen is found to be the only contributor to airborne particles containing organic molecules with molecular weights larger than 2000 g pr. mol...

  2. Heavy Oil and Natural Bitumen Resources in Geological Basins of the World

    Science.gov (United States)

    Meyer, Richard F.; Attanasi, E.D.; Freeman, P.A.

    2007-01-01

    Heavy oil and natural bitumen are oils set apart by their high viscosity (resistance to flow) and high density (low API gravity). These attributes reflect the invariable presence of up to 50 weight percent asphaltenes, very high molecular weight hydrocarbon molecules incorporating many heteroatoms in their lattices. Almost all heavy oil and natural bitumen are alteration products of conventional oil. Total resources of heavy oil in known accumulations are 3,396 billion barrels of original oil in place, of which 30 billion barrels are included as prospective additional oil. The total natural bitumen resource in known accumulations amounts to 5,505 billion barrels of oil originally in place, which includes 993 billion barrels as prospective additional oil. This resource is distributed in 192 basins containing heavy oil and 89 basins with natural bitumen. Of the nine basic Klemme basin types, some with subdivisions, the most prolific by far for known heavy oil and natural bitumen volumes are continental multicyclic basins, either basins on the craton margin or closed basins along convergent plate margins. The former includes 47 percent of the natural bitumen, the latter 47 percent of the heavy oil and 46 percent of the natural bitumen. Little if any heavy oil occurs in fore-arc basins, and natural bitumen does not occur in either fore-arc or delta basins.

  3. Reservoir design of a shallow LP-SAGD project for in situ extraction of Athabasca bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Palmgren, C.; Walker, I. [Alberta Oilsands (Canada); Carlson, M.; Uwiera, M. [Inc RPS Energy (Canada); Torlak, M. [Siemens AG (Canada)

    2011-07-01

    Alberta Oilsands Inc. is developing a project 8 km southeast of Fort McMurray, Alberta, Canada. The Clearwater project aims to extract bitumen from a shallow bitumen reservoir through in situ production; the aim of this paper is to present this project and to evaluate the commercial viability of combining different technologies such as steam assisted gravity drainage (SAGD), solvent co-injection and electro-magnetic heating. Alberta Oilsands will put 6 SAGD well pairs and infill wells in place to effectively recover the bitumen. Reservoir simulations were carried out using reservoir models based on geological, petrophysical and geostatical work. Results showed that the combination of SAGD, solvent co-injection and electro-magnetic heating can increase bitumen production while reducing the steam oil ratio. This paper provides information on the Phase I reservoir design of the Clearwater project; steam injection and bitumen recovery are expected to start in 2012.

  4. 倒置式屋面防水现状调查及结构自防水技术研究%Investigation of inverted roof waterproofing and study to structure waterproof--self technology

    Institute of Scientific and Technical Information of China (English)

    刘立

    2012-01-01

    本文通过对目前常见的屋面工程外防水作法的现状调查和探讨,提出了加强屋面结构自防水的结构原理和技术措施,并推导出了砼结构体实际抗渗等级的经验公式。%Passing the familiar outside waterproof method of roof engineering currently, it is discussed and studied in this paper, and put forward the structure waterproofing-- self principle or technical measures, and derive the empirical formula of concrete structure of actual pervious grades.

  5. Four-component united-atom model of bitumen

    Science.gov (United States)

    Hansen, J. S.; Lemarchand, Claire A.; Nielsen, Erik; Dyre, Jeppe C.; Schrøder, Thomas

    2013-03-01

    We propose a four-component united-atom molecular model of bitumen. The model includes realistic chemical constituents and introduces a coarse graining level that suppresses the highest frequency modes. Molecular dynamics simulations of the model are carried out using graphic-processor-units based software in time spans in order of microseconds, which enables the study of slow relaxation processes characterizing bitumen. This paper also presents results of the model dynamics as expressed through the mean-square displacement, the stress autocorrelation function, and rotational relaxation. The diffusivity of the individual molecules changes little as a function of temperature and reveals distinct dynamical time scales. Different time scales are also observed for the rotational relaxation. The stress autocorrelation function features a slow non-exponential decay for all temperatures studied. From the stress autocorrelation function, the shear viscosity and shear modulus are evaluated, showing a viscous response at frequencies below 100 MHz. The model predictions of viscosity and diffusivities are compared to experimental data, giving reasonable agreement. The model shows that the asphaltene, resin, and resinous oil tend to form nano-aggregates. The characteristic dynamical relaxation time of these aggregates is larger than that of the homogeneously distributed parts of the system, leading to strong dynamical heterogeneity.

  6. Base Course Modification through Stabilization using Cement and Bitumen

    Directory of Open Access Journals (Sweden)

    S. M. Marandi

    2009-01-01

    Full Text Available The main objectives of this research was to analyze the use of combined cement and bitumen emulsion in base course stabilization in details and examine its replacement with conventional pavement in regions with low quality materials and limited construction period. To conduct the objectives, the research divided into three phases. Phase I involved the optimization of cement and bitumen emulsion. In this case, a series of Indirect Tensile Strength (ITS, Unconfined Compressive Strength (UCS and Marshal Tests carried out. In the second phase, various alternative roadway sections examined for minimizing the pavement thickness and increasing the bearing capacity and finally in third phase, a Falling Weight Deflectometer (FWD machine used to examine the pavement bearing capacity for three sections of the roadway. It was found that, the optimum values to eliminate the creation of shrinkage cracks in the whole project and minimize the execution period and construction costs were 3% for both binders in stabilization and its replacement with conventional pavement method (i.e., stabilized layer with conventional sub-base and base layers. Also, FWD results showed that, the bearing capacity of the constructed pavement using stabilization method is far beyond the predicted values in pavement design. Furthermore, it was found that, with high inflation rate and political situation in the region, base stabilized method decreased the final roadway construction costs in compare with conventional pavement method.

  7. Foamed bitumen stabilization of MSWI bottom ash; Skumbitumenstabilisering av bottenaska fraan avfallsfoerbraenning

    Energy Technology Data Exchange (ETDEWEB)

    Bendz, David [Swedish Geotechnical Inst., Linkoeping (Sweden); Jacobsson, Torbjoern [Swedish National Road and Transport Research Inst., Linkoeping (Sweden); Svensson, Mikael; Flyhammar, Peter [Lund Inst. of Technology (Sweden). Dept. of Water Resources Engineering

    2006-04-15

    Foamed bitumen is a mixture of bitumen, water and air. Bitumen that is heated to 175 deg C expands about 10-30 times compared to its original volume when injecting small amounts of water and air under high pressure. By exposing a granulate material to foamed bitumen the particles will be covered with a bitumen film. This will give the particles hydrophobic properties, as well as a smaller specific surface. At the same time the mechanical properties of the material are expected to improve due to the cohesive properties of the bitumen covered particles. The treatment can be made both offsite and in situ. The objective of this project was to investigate the possibility to treat municipal solid waste bottom ash with foamed bitumen to achieve improved leaching and mechanical properties. The following leaching tests have been performed on the original bottom ash and two foamed bitumen treated ashes with 2 and 4.5 % bitumen, respectively: one-stage batch test (EN 12457-4), pH-static test (prEN 14997), column test (prEN 14405) and monolithic leaching test (NEN 7345). In addition, the specific surface and intra-particle porosity were determined by BET N2 adsorption experiments on selected fractions of bottom ash. The results showed that the specific surface decreased with more than 50 % and manifested itself in a lower buffer capacity at both low and high pH. For most elements no significant difference in leaching behavior where found when comparing the results from the leaching tests for the three materials at their own pH. This is thought to be due to that sufficient specific area available for leaching exists to reach equilibrium despite the foam bitumen treatment. The results from the one-stage batch test show a minor reduction in leaching for Cl{sup -}, S, SO{sub 4}{sup -2}, NO{sub 3}{sup -}, Sb, and Ca for the foamed bitumen treated ashes. The results from the column test of the foamed bitumen stabilized ashes showed an increased leaching of some elements, especially

  8. A PDMS-Based 2-Axis Waterproof Scanner for Photoacoustic Microscopy

    Directory of Open Access Journals (Sweden)

    Jin Young Kim

    2015-04-01

    Full Text Available Optical-resolution photoacoustic microscopy (OR-PAM is an imaging tool to provide in vivo optically sensitive images in biomedical research. To achieve a small size, fast imaging speed, wide scan range, and high signal-to-noise ratios (SNRs in a water environment, we introduce a polydimethylsiloxane (PDMS-based 2-axis scanner for a flexible and waterproof structure. The design, theoretical background, fabrication process and performance of the scanner are explained in details. The designed and fabricated scanner has dimensions of 15 × 15 × 15 mm along the X, Y and Z axes, respectively. The characteristics of the scanner are tested under DC and AC conditions. By pairing with electromagnetic forces, the maximum scanning angles in air and water are 18° and 13° along the X and Y axes, respectively. The measured resonance frequencies in air and water are 60 and 45 Hz along the X axis and 45 and 30 Hz along the Y axis, respectively. Finally, OR-PAM with high SNRs is demonstrated using the fabricated scanner, and the PA images of micro-patterned samples and microvasculatures of a mouse ear are successfully obtained with high-resolution and wide-field of view. OR-PAM equipped with the 2-axis PDMS based waterproof scanner has lateral and axial resolutions of 3.6 μm and 26 μm, respectively. This compact OR-PAM system could potentially and widely be used in preclinical and clinical applications.

  9. Does long term exposure to radon gas influence the properties of polymeric waterproof materials?

    Science.gov (United States)

    Navratilova Rovenska, Katerina; Jiranek, Martin; Kokes, Pavel; Wasserbauer, Richard; Kacmarikova, Veronika

    2014-01-01

    The technical state of buildings and the quality of the indoor environment depend on the quality of the waterproofing course and on the properties of the insulating materials that are applied, in particular on their durability, long-term functional reliability and resistance to corrosive effects of the subsoil. Underground water chemistry and soil bacteria are well-known corrosive agents. Our investigations indicate that the ageing process of waterproof materials can be significantly accelerated by alpha particles emitted by radon and radon progenies which are present in soil gas. Materials commonly available on the building market, e.g. LDPE and HDPE of various densities, PVC, TPO (thermoplastic polyolefin), PP (polypropylene) and EPDM were selected for our experimental study. The preliminary results for 3-year exposure to radon gas show a decrease in tensile strength to 60%, elongation to 80% and hardness to 95% for samples based on PE. The diffusion coefficient of radon for samples based on PVC decreased to 20% of the initial value after 1-year exposure to radon and soil bacteria.

  10. Upgrading of Bitumen in Super Critical Water — Activation of Water

    Science.gov (United States)

    Miyamoto, D.; Kishita, A.; Jin, F.; Kazuyuki, T.; Enomoto, H.

    2007-03-01

    Recently, oil sand in Canada has been gathering attention because of its huge storage, and the lack of fossil fuels. However, the bitumen from the oil sand has the problems for commercial use due to its high viscosity, high sulfur and high heavy metal content. Our research group has been carrying heavy oil/bitumen upgrading by hydrothermal visbreaking in supercritical water with the addition of alkali. Results showed that by supercritical water treatment with alkali was very effective for upgrading heavy oil/bitumen. However, water activation for upgrading bitumen remains poorly understood. An understanding of water activation is needed for improving upgrading bitumen in supercritical water reaction. In this study, therefore, the effect of water on upgrading bitumen in supercritical water reaction was investigated by varying reaction pressure and temperature. Experiments were performed in both a batch reactor and a continuous-flow reactor. In batch experiment, experiments were performed at temperature of 380°C to 460°C, the reaction pressure of 24 MPa to 40 MPa, and the reaction time of 30 min. Results showed that pressure and temperature, particularly pressure, have great effect on upgrading bitumen in supercritical water reaction This suggests that that the desired product could be obtained by controlling the reaction pressure and temperature.

  11. Effect of Ultraviolet Aging on Rheology and Chemistry of LDH-Modified Bitumen

    Directory of Open Access Journals (Sweden)

    Xing Liu

    2015-08-01

    Full Text Available Layered double hydroxides (LDHs are an ultravioletlight (UV-resistant material. In this study, two types of LDHs (Mg-Al-LDHs and Zn-Al-LDHs were applied to modify bitumen by melt-blending. The effect of ultraviolet aging on the rheology and chemistry of LDH-modified bitumen was studied by means of dynamic shear rheometer (DSR, thin-layer chromatography with flame ionization detection (TLC-FID, Fourier transform infrared spectroscopy (FTIR, and Ultraviolet-Visible (UV-Vis spectrophotometry to reveal the mechanisms of action for LDHs and bitumen. The results showed that within the UV spectra (220–400 nm, the reflectance of Zn-Al-LDHs was larger than that of Mg-Al-LDHs. These two LDHs have different influences on the performance of bitumen. Mg-Al-LDHs had a more obvious influence on the physical and dynamic rheological properties of bitumen than Zn-Al-LDHs. Zn-Al-LDHs improved the UV-aging resistance of bitumen more. The reason can be that the reflectance of the Zn-Al-LDHs to the UV light is larger than that of the Mg-Al-LDHs. The Zn-Al-LDH-modified bitumen had more potential to improve the UV-aging resistance during the service life of asphalt pavement.

  12. Proceedings of the 3. NCUT meeting on upgrading and refining of heavy oil, bitumen and synthetic crude oil and the 2. symposium on stability and compatibility during the production, transportation and refining of petroleum

    International Nuclear Information System (INIS)

    This conference highlights new developments in refining processes for heavy oil, bitumen, and synthetic crudes. The oil sands/heavy oil industry in Canada has grown significantly in the last decade and could triple by 2012 to reach 2.6 million barrels per day. Experts from the petroleum industry, government organizations and technology providers attended this conference which identified technology gaps and areas where improvements are needed. The presentations demonstrated that many new technologies associated with heavy oil bitumen upgrading and refining have posed compatibility and stability challenges for pipeliners, upgraders and refiners. One of the issues addressed at the conference was the effect of upgrading technologies on market price due to the expected increase in production. Another important issue is how production of bitumen can be increased without significantly increasing greenhouse gas emissions from the refineries and upgrading facilities. The sessions of the conference were entitled: new technology developments in bitumen upgrading; secondary upgrading developments and expanded product opportunities; environmental issues and expanded oil sands development; and, stability and compatibility during the production, transportation and refining of petroleum. Twenty six presentations were indexed separately for inclusion in this database. tabs., figs

  13. Evaluation of the properties of bitumen and cement pastes and mortars used in the immobilization of waste radioactive

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, Vanessa Mota; de Tello, Cledola Cassia Oliveira, E-mail: vanessamotavieira@gmail.com, E-mail: tellocc@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2013-07-01

    The Project RBMN was launched in November 2008 and aims to establish, manage and execute all tasks for implementing the Brazilian Repository, from its conception to its construction. The concept to be adopted will be a near-surface repository. The inventory includes wastes from the operation of nuclear power plants, fuel cycle facilities and from the use of radionuclides in medicine, industry and activities research and development. The implementation of the national repository is an important technical requirement, and a legal requirement for the entry into operation of the nuclear power plant Angra 3. In Brazil, for the immobilization and solidification of radioactive waste of low and intermediate level of radiation from NPPs are used cement, in Angra 1, and bitumen, in Angra 2. Studies indicate serious concerns about the risks associated with bituminization radioactive waste, much related to the process as the product. There are two major problems due to the presence of products bituminization in repositories, swelling of the waste products and their degradation in the long term. To accommodate the swelling, filling the drums must be limited to 70 - 90% of its volume, which reduces the structural stability of the repository and the optimization of deposition. This study aims to evaluate of the properties of bitumen and cement pastes and mortars used in the immobilization of waste radioactive. (author)

  14. Evaluation of the properties of bitumen and cement pastes and mortars used in the immobilization of waste radioactive

    International Nuclear Information System (INIS)

    The Project RBMN was launched in November 2008 and aims to establish, manage and execute all tasks for implementing the Brazilian Repository, from its conception to its construction. The concept to be adopted will be a near-surface repository. The inventory includes wastes from the operation of nuclear power plants, fuel cycle facilities and from the use of radionuclides in medicine, industry and activities research and development. The implementation of the national repository is an important technical requirement, and a legal requirement for the entry into operation of the nuclear power plant Angra 3. In Brazil, for the immobilization and solidification of radioactive waste of low and intermediate level of radiation from NPPs are used cement, in Angra 1, and bitumen, in Angra 2. Studies indicate serious concerns about the risks associated with bituminization radioactive waste, much related to the process as the product. There are two major problems due to the presence of products bituminization in repositories, swelling of the waste products and their degradation in the long term. To accommodate the swelling, filling the drums must be limited to 70 - 90% of its volume, which reduces the structural stability of the repository and the optimization of deposition. This study aims to evaluate of the properties of bitumen and cement pastes and mortars used in the immobilization of waste radioactive. (author)

  15. It's all about the bitumen : oilsands producers have the attention of the world

    International Nuclear Information System (INIS)

    Within 10 years, oilsands growth will make Canada the fifth largest oil producing country in the world, thereby greatly increasing Canada's political power. A review of oil sands development was presented, with reference to the way in which Steam Assisted Gravity Drainage (SAGD) has revolutionized the industry. Recent acquisitions have pointed to the growing level of international interest in the oilsands industry. Construction details of the Surmont project were discussed along with Devon Canada's SAGD project at Jackfish where about 100 well-pairs are expected to be drilled. Petrobank Energy and Resources is constructing its Whitesands project, which will employ the first field-scale application of the toe-to-heel air injection (THAI) recovery method which has lower operating costs and which uses less water and creates fewer greenhouse (GHG) emissions. The pilot was designed to produce up to 1800 barrels per day of partially upgraded bitumen. Details of CNRI's Horizon project were presented, including construction plans and schedules. Shell Canada's increased budget for the first expansion of the Athabasca Oilsands Project was reviewed with reference to their strategic decision to pre-build infrastructure for future expansions. Details of Suncor Energy's production goals were also reviewed, including details of new upgraders and applications. Syncrude's continuing expansions were discussed, as well as their current production levels. An outline of UTS Energy Corporation and Petro-Canada's plans concerning the Fort Hills Mining Project was presented, with details of the new BITMIN extraction process. It was noted that Imperial Oil has filed regulatory applications for the Kearl Oilsands Project, which have estimated total recoverable bitumen resources of 4.4 billion barrels. Husky Energy's Sunrise Project was discussed, as well as MEG Energy's regulatory approval for the first phase of the Christina Lake Regional Project. The Canadian Association of Petroleum

  16. In-situ analysis of solid bitumen in coal: Examples from the Bowen Basin and the Illinois Basin

    Science.gov (United States)

    Mastalerz, Maria; Glikson, M.

    2000-01-01

    Solid bitumen and associated vitrinite from selected coals from the Bowen Basin and the Illinois Basin were studied using electron microprobe and micro-FTIR techniques. The coal studied covers a range of vitrinite reflectance from 0.59% to 1.33%. Carbon content in the bitumen is generally lower than in vitrinite in coals with vitrinite reflectance below 0.67%. In coals with reflectance above 0.67%, carbon content of bitumen is higher than in vitrinite, reflecting higher aromaticity due to hydrocarbon generation. Sulfur and iron content are comparable between vitrinite and bitumen. Functional group distribution suggests the presence of two types of bitumen in the Illinois Basin coals. The more aliphatic variety occurring in veins and cleats is interpreted as pre-gas generation bitumen, and the more aromatic variety filling cells and voids in inertinite as post-gas generation bitumen. (C) 2000 Elsevier Science B.V. All rights reserved.Solid bitumen and associated vitrinite from selected coals from the Bowen Basin and the Illinois Basin were studied using electron microprobe and micro-FTIR techniques. The coal studied covers a range of vitrinite reflectance from 0.59% to 1.33%. Carbon content in the bitumen is generally lower than in vitrinite in coals with vitrinite reflectance below 0.67%. In coals with reflectance above 0.67%, carbon content of bitumen is higher than in vitrinite, reflecting higher aromaticity due to hydrocarbon generation. Sulfur and iron content are comparable between vitrinite and bitumen. Functional group distribution suggests the presence of two types of bitumen in the Illinois Basin coals. The more aliphatic variety occurring in veins and cleats is interpreted as pre-gas generation bitumen, and the more aromatic variety filling cells and voids in inertinite as post-gas generation bitumen.

  17. Towards the Development of Bitumen Carbonates: An Integrated Analysis of Grosmont Steam Pilots

    OpenAIRE

    Ezeuko C.C.; Wang J; Kallos M.S.; Gates I.D.

    2015-01-01

    The Grosmont Formation in Alberta, Canada is a highly fractured, karstified and vuggy bitumen-rich carbonate reservoir located west of and below the Athabasca oil sands deposit. The bitumen carbonate platform extends about 500 km in length and up to 150 km in width and contains an estimated 64.5 billion m3 (406.5 billion barrels) of oil. The Grosmont Formation is larger than the combined total of all other known carbonate bitumen deposits in the world. Here, we analyze early Grosmont steam pi...

  18. Reflectance measurements of zooclasts and solid bitumen in Lower Paleozoic shales, southern Scandinavia

    DEFF Research Database (Denmark)

    Petersen, Henrik I.; Schovsbo, Niels H.; Nielsen, Arne T.

    2013-01-01

    Reflectance measurements have been carried out on zooclasts (graptolites, chitinozoans, and vase-shaped microfossils) and other organic particles (vitrinite-like particles, porous/granular vitrinite-like particles, and solid bitumen) in Middle Cambrian to Upper Silurian shales from central and...... graptolites at the same level of maturity. Reflectance measurements of solid bitumen are a poor maturity indicator, probably because bitumen can have various origins and morphologies and it may not be indigenous to the host rock. (C) 2013 Elsevier B.V. All rights reserved....

  19. Dating hydrocarbon genera-tion and migration based on bitumen reflectance

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    On the basis of thermal maturation theories of organic matter in sediments and an improved Karweil's method, a method for dating hydrocarbon generation and migration by means of bitumen reflectance has been suggested. A few representative boreholes in the Tazhong Area of the Tarim Basin was investigated by this method. The results indicate that the three phases of bitumen from the Tazhong Area formed during Middle and Late Ordovician, Late Cretaceous-Early Tertiary, and Late Tertiary, respectively. This implicates that there were three phases of hydrocarbon generation and migration occurring in this area during geological history. This study provided a new idea for the geological application of geochemical data of bitumen.

  20. The Self- waterproof Concrete Design Essentials%自防水混凝土设计要点

    Institute of Scientific and Technical Information of China (English)

    图门恩和

    2012-01-01

    The design key points of self - waterproof concrete should be paid attention to the self - waterproof con- crete use range, the environment, the impermeability of design, design requirements and design ratio of mix. The de- sign and engineering application of waterproof concrete are illustrated importance of the design of the key points in the design of the waterproof concrete.%本文从自防水混凝土的使用范围、使用环境、抗渗等级设计、设计构造要求及其设计配合比要求等全方位分析自防水混凝土的设计中应注意要点,并通过地下室底板工程中成功应用自防水混凝土案例,说明上述设计要点对自防水混凝土设计中的重要性.

  1. Interaction between plasticized polyvinyl chloride waterproofing membrane and extruded polystyrene board, in the inverted flat roof

    Directory of Open Access Journals (Sweden)

    Pedrosa, A.

    2014-12-01

    Full Text Available The inverted flat roof is a constructive system widely used in flat roof construction. In this constructive solution, the insulation is placed over the waterproofing material as a protection. It is believed that this solution provides a longer life cycle; given the fact that it limits the thermal variation the waterproofing material bears up to the end of its life cycle. Consequently, the result will be providing a longer life to the waterproofing membrane. This constructive solution always incorporates polymers or other materials with a thermoplastic addition in their composition. Some polymers show interactions between them that can affect their integrity, and, at the same time, the bulk of the polymeric materials are incompatible. The extruded polystyrene board is always present in the inverted flat roof, and although it is an unbeatable product for this use, it presents incompatibilities and interactions with other materials, and these can affect their properties and therefore the durability of them.La cubierta plana invertida es un sistema constructivo muy utilizado en las cubiertas planas. En esta solución constructiva, el aislamiento se coloca sobre el material impermeabilizante a modo de protección. Se cree que esta solución proporciona un ciclo de vida más largo; dado que se limita la variación térmica de la impermeabilización hasta el final de su ciclo de vida. En consecuencia, el resultado proporciona una vida más larga a la membrana impermeable. Esta solución constructiva siempre incorpora polímeros u otros materiales con adición termoplástica en su composición. Algunos polímeros muestran interacciones entre ellos que pueden afectar a su integridad, además, la mayor parte de los materiales poliméricos son incompatibles. La plancha de poliestireno extrusionado está siempre presente en la cubierta plana invertida, y aunque es un producto inmejorable para este uso, presenta incompatibilidades e interacciones con otros

  2. FTIR Study of Vapor Offgassing from Orbiter Tile Re-Waterproofing Materials

    Science.gov (United States)

    Mattson, C. B.

    1999-01-01

    The work presented in this paper was performed to identify and quantify the offgassing behavior of alternative re-waterproofmg materials under investigation for application to Shuttle Orbiter Thermal Protection System (TPS) tile and blanket materials. The purpose was to determine whether the new materials would cause a problem with the operational analysis of residual vapors using the current portable vapor analyzer, a Miran 203. The materials investigated were limited to dimethylethoxysilane (DMES) and proposed solvent selected as suitable for use in re-waterproofing Orbiter TPS. The solvent was selected in another phase of the overall project. Obiter TPS tiles were injected with the re-waterproofing materials under constant conditions of temperature, relative humidity and air flow. The vapor concentrations of offgassing materials were monitored using Fourier Transform Infrared (FTIR) multi-component analysis, and with the Miran 203 instruments. The procedure was to record the time dependent concentrations of offgassing materials as analyzed by the FTIR, and the time response of the Miran 203 to the materials under consideration. The FTIR was calibrated for vapor phase DMES, tetramethyldisiloxane (TMDS), ethanol and the hydrocarbon solvents to be used to dilute the DMES for application to the TPS tile. The Miran 203 was calibrated for the operational measurement of DMES airborne vapors. The FTIR data, shows for the first time that the principal product which offgases from the tile after the first hour is not DMES, but TMDS and ethanol. The Miran 203 response to TMDS is the primary reading after the re-waterproofing operation is completed. The operational use of the Miran 203 to measure DMES vapors after re-waterproofmg operations has been responding to TMDS. The results of this study suggest that the historical complaints that have contributed to the low threshold limit value (TLV) for DMES concentrations, as read with the Miran 203, are actually based on

  3. Waterproof and translucent wings at the same time: problems and solutions in butterflies

    Science.gov (United States)

    Perez Goodwyn, Pablo; Maezono, Yasunori; Hosoda, Naoe; Fujisaki, Kenji

    2009-07-01

    Although the colour of butterflies attracts the most attention, the waterproofing properties of their wings are also extremely interesting. Most butterfly wings are considered “super-hydrophobic” because the contact angle (CA) with a water drop exceeds 150°. Usually, butterfly wings are covered with strongly overlapping scales; however, in the case of transparent or translucent wings, scale cover is reduced; thus, the hydrophobicity could be affected. Here, we present a comparative analysis of wing hydrophobicity and its dependence on morphology for two species with translucent wings Parantica sita (Nymphalidae) and Parnassius glacialis (Papilionidae). These species have very different life histories: P. sita lives for up to 6 months as an adult and migrates over long distance, whereas P. glacialis lives for less than 1 month and does not migrate. We measured the water CA and analysed wing morphology with scanning electron microscopy and atomic force microscopy. P. sita has super-hydrophobic wing surfaces, with CA > 160°, whereas P. glacialis did not (CA = 100-135°). Specialised scales were found on the translucent portions of P. sita wings. These scales were ovoid and much thinner than common scales, erect at about 30°, and leaving up to 80% of the wing surface uncovered. The underlying bare wing surface had a remarkable pattern of ridges and knobs. P. glacialis also had over 80% of the wing surface uncovered, but the scales were either setae-like or spade-like. The bare surface of the wing had an irregular wavy smooth pattern. We suggest a mode of action that allows this super-hydrophobic effect with an incompletely covered wing surface. The scales bend, but do not collapse, under the pressure of a water droplet, and the elastic recovery of the structure at the borders of the droplet allows a high apparent CA. Thus, P. sita can be translucent without losing its waterproof properties. This characteristic is likely necessary for the long life and migration

  4. Waterproofing Underground Structures: Lessons from the Past, Systems for the Future

    Institute of Scientific and Technical Information of China (English)

    Martin Smith

    2004-01-01

    The paper describes some of the key issues that need to be addressed in the design and execution of underground structures to ensure their long term suitability as watertight units and outlines through practical examples of structures that have not achieved their design requirements which situations need to be considered. Waterproofing is not an exact science but a combination of theoretical knowledge and practical experience based on the five key factors: Environment, Design, Materials, Application and Use of the Structure.In conclusion the paper outlines the advances in crack control to date that can provide the necessary long term guarantees.The adoption of re - injectable crack inducers permitted the Client to save over 10% on construction costs and reduced the construction time by six months.

  5. Waterproof AlInGaP optoelectronics on stretchable substrates with applications in biomedicine and robotics

    Science.gov (United States)

    Kim, Rak-Hwan; Kim, Dae-Hyeong; Xiao, Jianliang; Kim, Bong Hoon; Park, Sang-Il; Panilaitis, Bruce; Ghaffari, Roozbeh; Yao, Jimin; Li, Ming; Liu, Zhuangjian; Malyarchuk, Viktor; Kim, Dae Gon; Le, An-Phong; Nuzzo, Ralph G.; Kaplan, David L.; Omenetto, Fiorenzo G.; Huang, Yonggang; Kang, Zhan; Rogers, John A.

    2010-11-01

    Inorganic light-emitting diodes and photodetectors represent important, established technologies for solid-state lighting, digital imaging and many other applications. Eliminating mechanical and geometrical design constraints imposed by the supporting semiconductor wafers can enable alternative uses in areas such as biomedicine and robotics. Here we describe systems that consist of arrays of interconnected, ultrathin inorganic light-emitting diodes and photodetectors configured in mechanically optimized layouts on unusual substrates. Light-emitting sutures, implantable sheets and illuminated plasmonic crystals that are compatible with complete immersion in biofluids illustrate the suitability of these technologies for use in biomedicine. Waterproof optical-proximity-sensor tapes capable of conformal integration on curved surfaces of gloves and thin, refractive-index monitors wrapped on tubing for intravenous delivery systems demonstrate possibilities in robotics and clinical medicine. These and related systems may create important, unconventional opportunities for optoelectronic devices.

  6. Electricity generation of microbial fuel cell with waterproof breathable membrane cathode

    Science.gov (United States)

    Xing, Defeng; Tang, Yu; Mei, Xiaoxue; Liu, Bingfeng

    2015-12-01

    Simplification of fabrication and reduction of capital cost are important for scale-up and application of microbial electrochemical systems (MES). A fast and inexpensive method of making cathode was developed via assembling stainless steel mesh (SSM) with waterproof breathable membrane (WBM). Three assemble types of cathodes were fabricated; Pt@SSM/WBM (SSM as cathode skeleton, WBM as diffusion layer, platinum (Pt) catalyst applied on SSM), SSM/Pt@WBM and Pt@WBM. SSM/Pt@WBM cathode showed relatively preferable with long-term stability and favorable power output (24.7 W/m3). Compared to conventional cathode fabrication, air-cathode was made for 0.5 h. The results indicated that the novel fabrication method could remarkably reduce capital cost and simplify fabrication procedures with a comparable power output, making MFC more prospective for future application.

  7. A miniature cell for gas solubility measurements in oils and bitumen

    Science.gov (United States)

    Foroughi, Hooman; Acosta, Edgar J.; Kawaji, Masahiro

    2011-03-01

    A miniature cell has been designed and constructed to measure gas solubility in crude oils and bitumen. The cell was made of stainless steel with a total internal volume of 1.835 cc and only an oil sample of 0.4 cc was required for one set of measurements at different pressures. By using this small cell, the waiting time for reaching equilibrium was less than 10 min. The technique was validated by measuring CO2 gas solubility in two bitumen samples. The results were compared and found to be in very good agreement with available data. The apparatus was also used to study the effect of ashphaltene on CO2 solubility in bitumen. It was shown that ashphaltene had a negligible effect on CO2 solubility in bitumen.

  8. Effects of SBS Configuration on Performance of High Modulus Bitumen Based on Dynamic Mechanical Analysis

    Directory of Open Access Journals (Sweden)

    Ming Liang

    2016-07-01

    Full Text Available High modulus bitumens modified by polystyrene-block-polybutadiene-block-polystyrene (SBS with different molecular structure were investigated on dynamic shear rheometer and fluorescence microscopy to evaluate viscoelastic properties and morphology of binders. The results shows that storage modulus (G’ is obviously less than loss modulus (G”, which means viscous behaviour of bitumen is dominant, and anti-rutting factor (G* ⁄ sin δ is markedly enhanced by star SBS than by linear SBS. The morphology indicated that star SBS improved the softening point more obviously, tending to form a cross-linked network in bitumen. As for linear SBS, it is dispersed in bitumen in the form of globules and enhances the ductility of binder.

  9. Study of the thermal and mechanical sensitivity of bitumen/oxygen salt mixtures

    International Nuclear Information System (INIS)

    The safe handling characteristics of radioactive wastes containing nitrate salts to be fixed in bitumen for ultimate storage in salt mines according to a process developed at the Karlsruhe Nuclear Research Center have been examined with respect to their combustibility and shock sensitivity in tests of inactive bitumen/salt mixtures. Samples containing 40% bitumen and 60% nitrates of alkali, alkaline earth, and heavy metals, organic acids and rare earths were used to determine the thermal sensitivity (ignition temperature, duration of burning, heating under contained conditions), the mechanical sensitivity (shock sensitivity) and, in order to simulate major shock stresses, the sensitivity against detonation stresses. A few basic experiments were also performed on some beta-irradiated inactive samples. It appeared that although the addition of nitrates increased the combustibility of bitumen, neither the high thermal nor the detonation stresses resulted in any explosion-type reaction. (orig.)

  10. Use and trade of bitumen in antiquity and prehistory: molecular archaeology reveals secrets of past civilizations

    OpenAIRE

    Connan, J.

    1999-01-01

    Natural asphalt (or bitumen) deposits, oil seepage and liquid oil shows are widespread in the Middle East, especially in the Zagros mountains of Iran. Ancient people from northern Iraq, south-west Iran and the Dead Sea area extensively used this ubiquitous natural resource until the Neolithic period (7000 to 6000 BC). Evidence of earlier use has been recently documented in the Syrian desert near El Kown, where bitumen-coated flint implements, dated to 40,000 BC (Mousterian period), have been ...

  11. New maturity indicators based on spectral fluorescence of alginite and bitumen, Monterey Formation, California

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Chungi; Kennicutt, M.C. II (Texas A and M Univ., College Station (United States)); Lo, H.B. (Exxon Production Research Co., Houston, TX (United States))

    1991-03-01

    Conventional assessment of maturation level in the Monterey has been problematic, since sporinite and vitrinite are rare or absent. Organic matter is largely alginite and amorphous material, and reliable vitrinite reflectance (R{sub o}%) and Thermal Alteration Index (TAI) are difficult to obtain. Large amounts of bitumen often imbedded in the highly fractured Monterey shales cause a suppression of T{sub max} and low values of S{sub 1}S{sub 1} + S{sub 2}. It is often difficult to determine whether bitumen is indigenous or migrated from other more mature strata. Spectral fluorescence measurements of alginite and bitumen have proved useful in assessing the maturity of the Monterey. A maturity scale based on red/green quotient (Q{sub v}) measured as the fluorescence of alginite B when excited by violet-light has been developed and applied to the Monterey. Alginite B is common in the Monterey, and accurate fluorescent measurements can be readily obtained given the highly fluorescent character of alginite B. A total scanning fluorescence technique was used to develop a maturity scale based on bitumen aromatic content and composition. The maturity parameter (R{sub 1}) developed in this study uses the intensity of fluorescence emitted at 360 nm ratioed to that at 320 nm when the solvent-dissolved bitumen is excited at the 270 nm. These parameters allow for the evaluation of the thermal maturity of algal organic matter and bitumen from the Monterey with R{sub o}% {lt} 1. Indigenous bitumen is also indicated by a comparison of maturity based on Q{sub v} (the solid phase) and bitumen maturity (the liquid phase) based on R{sub 1}.

  12. Numerical Simulation Study on Parameters related to Athabasca Bitumen Recovery with SAGD

    OpenAIRE

    Marianayagam, Kristin Reka

    2012-01-01

    The world’s total oil reserves are to some extent dominated by heavy oil. The heavy oil reserves are doubled in volume compared to conventional oil reserves. As conventional oil reservoirs are depleting, heavy oil and bitumen possesses a great potential in covering parts of the future energy demand. The possibility of horizontal drilling has created a pathway for SAGD (Steam Assisted Gravity Drainage), which is the most preferred heavy oil and bitumen recovery method. The mechanism of SAGD in...

  13. Analys av Nedbrytningsprodukter av Polymerer för Bitumenändamål

    OpenAIRE

    Lindström, Björn

    2007-01-01

    This project was aimed to study the degradation of polystyrene-butadiene-styrene block copolymer (SBS). SBS is used to modify bitumen, the binder in asphalt. From earlier studies it is known that SBS degrades in bitumen, but the degradation products have not been identified. To be able to determine the long term effects of SBS in the environment, degradation products need to be identified. Polystyrene forms rigid blocks with polybutadiene as a rubbery matrix between the ridgid blocks. When bl...

  14. Bitumen on Water: Charred Hay as a PFD (Petroleum Flotation Device)

    OpenAIRE

    Nusrat Jahan; Jason Fawcett; Thomas L. King; Alexander M. McPherson; Katherine N. Robertson; Ulrike Werner-Zwanziger; Clyburne, Jason A. C.

    2015-01-01

    Global demand for petroleum keeps increasing while traditional supplies decline. One alternative to the use of conventional crude oils is the utilization of Canadian bitumen. Raw bitumen is a dense, viscous, semi-liquid that is diluted with lighter crude oil to permit its transport through pipelines to terminals where it can then be shipped to global markets. When spilled, it naturally weathers to its original form and becomes dense enough to sink in aquatic systems. This severely limits oil ...

  15. Towards a Viscoelastic Model for Phase Separation in Polymer Modified Bitumen

    OpenAIRE

    Zhu, Jiqing

    2015-01-01

    In this thesis, a review is given on the most popular polymers used today for polymer modification of bitumen. Furthermore, the development of a model for phase separation in polymer modified bitumen (PMB) is proposed, that will enable a better control and understanding of PMB phase behaviour, allowing thus to enhanced long-term performance. PMB is hereby considered as a blend and focus is placed on its structure, its equilibrium thermodynamics and its phase separation dynamics. The effects o...

  16. Chemically modified bitumens with enhanced rheology and adhesion properties to siliceous aggregates

    OpenAIRE

    Cuadri Vega, Antonio Abad; Partal López, Pedro; Ahmad, Naveed; Grenfell, James; Airey, Gordon

    2015-01-01

    Moisture damage is one of the major premature failures that worsens the performance and shortens service life of pavements. This research assesses the effect that two chemical modifiers (thiourea and an isocyanate-functionalized castor oil prepolymer) exerts on the bitumen rheology and on the resistance to potential moisture damage of asphalt mixtures based on siliceous aggregates. Both thiourea and the isocyanate-based prepolymer improve the viscous and viscoelastic behaviours of bitumen at ...

  17. High-sulphur shale oil as a prime matter for bitumen production

    International Nuclear Information System (INIS)

    The composition and properties of heavy residues of Israeli shale oil (S content 6.8 %) were investigated as a source for bitumens. Both principal methods of asphalt production - vacuum distillation and oxidizing with air -were studied. Straight-run bitumen had satisfactory characteristics. As to oxidized bitumen, the values of its penetration, ductility and softening point were also satisfactory. The drawback of shale oil bitumens is their high viscosity after the thin film oven test, which means their high sensitivity to aging. The shale oil composition changes significantly as a result of distillation and oxidation. The content of asphaltenes sharply increases: from 3.5 to 20-22 % in straight-run bitumen and to 30 % in oxidized bitumen. It is explained by the reactions of condensation and polymerization of the most unstable polar components during heating and oxidation. Unlike petroleum, shale oil is a product of pyrogenic origin, i.e., it is formed as a result of thermal decomposition of large molecules of kerogen and a part of this cracked material consists of unstable fragments of these molecules, which have a tendency to polymerization. The C/H ratio and nitrogen content increase significantly in the order 'saturated hydrocarbons-naphthenoaromatics - aromatics - asphaltenes'. (author)

  18. Bitumen casting of 14 C contaminated ion exchangers in view of final disposal

    International Nuclear Information System (INIS)

    After Cernavoda NPP commissioning in the frame of radioactive waste management the important issue of processing the ion organic resin exchangers occurred. This waste, generated in different processes of water purification, represents a source of low and intermediate level activity. 14 C occurs in important amounts during the purification of the moderator and transport primary circuit. To secure the environmental safety 14 C contaminating the ion exchangers must be immobilized into a monolithic block of cement, bitumen or organic polymers. Our studies indicated as optimal the immobilization in Romanian 160-70 type bitumen. The barrel containing the immobilized waste in bitumen is then cast in concrete into a stainless steel container. In this work the following stages were achieved: - establishing the technological process of 14 C contaminated ion exchangers conditioning; - conceiving, designing and building the pilot installation for 14 C contaminated ion exchangers conditioning; - conducting experiments of immobilization of the resins used in bitumen on the pilot installation to establish the optimal parameters of installation's operation; - choosing a method of retaining 14 C released in the bitumen incorporation process, in a material able of total absorption; - leaching studies on the bitumen-resin and cement-bituminated resin to determine the 14 C leaching rate

  19. Molecular dynamics in bitumen compounds. A combined study by NMR and neutron scattering techniques

    International Nuclear Information System (INIS)

    The comparative studies by the combined NMR and neutron scattering techniques opened new possibilities for the investigations of the molecular structures and molecular dynamics in liquids as well as in solids. One of the first works of this type, reported in the literature was carried out in our Institute on supercooled liquid phenol. Later, the idea was extended to molecular crystals by a joint research project, between IFIN-HH, Bucharest and Max-Planck Institute-MD Heidelberg, using advanced solid-state NMR and stronger neutron fluxes. Here, we report preliminary results of the combined NMR and neutron scattering investigations on bitumen compounds that are micellar structures with important industrial applications. The goal of the study is to bring information about the molecular dynamics in various phases of these compounds and on this basis to test and/or improve their microscopic models.The neutron scattering measurements were carried out at IBR-2 high flux reactor at JNIR-Dubna. The neutron energy in the incident beam was 4.43 meV and scattering angles ranging from 6 angle to 134 angle. The scattered neutron spectra at room temperature are shown, for several angles. The quasielastic peak gives direct information about the molecular dynamics via the linewidth dependence on the transfer momentum k2. On this basis we calculated an overall diffusion constant Dn = 1.26·10-7 cm2/s. Dn is a superposition of contributions from the various rotational diffusions as well as the Translational diffusion. The neutron scattering data can hardly distinguish between them. This ambiguity can be partially removed by the information brought in by NMR. The temperature dependence of the NMR spin-lattice relaxation time T1 of ESSO-bitumen, measured at ω0/2φ = 25 MHz indicates several particular features: a) The relaxation process cannot be explained by a single relaxation mechanism. The superposition of two V-type mechanisms produces a reasonable agreement with experimental

  20. Three-phase gas-liquid-solid foaming bubble reactors and self-lubricated transport of bitumen froth

    Science.gov (United States)

    Mata, Clara E.

    Two distinct topics in multi-phase flow of interest of the oil industry are considered in this thesis. Studies of three-phase gas-liquid-solid foaming bubble reactors and self-lubricated transport of bitumen froth are reported. Applications of foams and foaming are found in many industrial processes such as flotation of minerals, enhanced oil recovery, drilling in oil reservoirs, and refining processes. However the physics of foaming and defoaming are not fully understood. Foams trap gas and are not desirable in some processes such as oil refining. Previously, it has been found that foaming may be strongly suppressed in a cold slit bubble reactor by fluidizing hydrophilic particles in the bubbly mixture below the foam. In this work, we fluidized hydrophobic and hydrophilic versions of two different sands in a cold slit foaming bubble reactor. We found that the hydrophobic sands suppress the foam substantially better than their hydrophilic counterparts. To study the capacity of foams to carry particles, we built a new slit foaming bubble reactor, which can be continuously fed with solid particles. Global gas, liquid, and solid holdups were measured for given gas and liquid velocities and solid flow rates. This research provides the fundamental ground work for the identification of flow types in a slit three-phase foaming bubble reactor with continuous injection of particles. Bitumen froth is produced from the oil sands of Athabasca, Canada. When transported in a pipeline, water present in the froth is released in regions of high shear (at the pipe wall). This results in a lubricating layer of water that allows bitumen froth pumping at greatly reduced pressures and hence the potential for savings in pumping energy consumption. Experimental results establishing the features of this self lubrication phenomenon are presented. The pressure gradient of lubricated flows closely follow the empirical law of Blasius for turbulent pipe flow with a constant of proportionality

  1. Industry

    International Nuclear Information System (INIS)

    This chapter of the environmental control report deals with the environmental impact of the industry in Austria. It gives a review of the structure and types of the industry, the legal framework and environmental policy of industrial relevance. The environmental situation of the industry in Austria is analyzed in detail, concerning air pollution (SO2, NOx, CO2, CO, CH4, N2O, NH3, Pb, Cd, Hg, dioxin, furans), waste water, waste management and deposit, energy and water consumption. The state of the art in respect of the IPPC-directives (European Integrated Pollution Prevention and Control Bureau) concerning the best available techniques of the different industry sectors is outlined. The application of European laws and regulations in the Austrian industry is described. (a.n.)

  2. Non-Newtonian behavior and molecular structure of Cooee bitumen under shear flow: a non-equilibrium molecular dynamics study

    CERN Document Server

    Lemarchand, Claire A; Todd, Billy D; Daivis, Peter J; Hansen, Jesper S

    2015-01-01

    The rheology and molecular structure of a model bitumen (Cooee bitumen) under shear is investigated in the non-Newtonian regime using non-equilibrium molecular dynamics simulations. The shear viscosity and normal stress differences of the bitumen mixture are computed at different shear rates and different temperatures. The model bitumen is shown to be a shear-thinning fluid. The corresponding molecular structure is studied at the same shear rates and temperatures. The Cooee bitumen is able to reproduce experimental results showing the formation of nanoaggregates composed of stacks of flat aromatic molecules. These nanoaggregates are immersed in a solvent of saturated hydrocarbon molecules. The nanoaggregates are shown to break up at very high shear rates, leading only to a minor effect on the viscosity of the mixture. At low shear rates, bitumen can be seen as a colloidal suspension of nanoaggregates in a solvent. The slight anisotropy of the whole sample due to the nanoaggregates is considered and quantified...

  3. Use of a density meter for analysis of process streams obtained during solvent extraction of bitumen from Athabasca oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Woods, J.R.; Kumar, A.; Sparks, B.D.; Kotlyar, L.S.

    A fast and accurate densimetry method has been developed that allows analysis of concentrated solutions of bitumen in diluents (such as naptha, varsol, etc.) used in solvent extraction processes. By means of an equation described in this paper, densimetry can also be applied to the determination of diluent occluded in agglomerated sand in the presence of bitumen. In this case a prior determination of bitumen content by some other method is required for complete determination.

  4. Polymer and bitumen modified OPC for the immobilisation of ILW

    International Nuclear Information System (INIS)

    A detailed study has been made of the modification of ordinary Portland cement with polymeric additives, and of the properties of waste forms based on these matrix materials. The additives were styrene butadiene and bitumen emulsions, and epoxide and polyurethane resins: the simulated wastes were organic ion exchanger beads, PWR evaporator concentrate, reprocessing concentrate and Magnox metal. The effect of polymer:cement (p:c) and water:cement ratios on the properties of the hardened cement paste has been comprehensively investigated. Substantial increases in strain to failure, and modest reductions in permeability to water and leach rates for 137Cs, are obtained at p:c >= 0.2. Much larger volume fractions of organic ion exchange beads can be encapsulated in polymer modified OPC than in unmodified OPC, perhaps because of their better strain capability. The radiation stability of cemented PWR evaporator concentrate is better for a polymer modified matrix than an unmodified OPC matrix. Two hundred litre trials have been successfully demonstrated. (author)

  5. Incoherent quasielastic scattering of slow neutrons on bitumen

    International Nuclear Information System (INIS)

    The paper presents the results of the cold neutron quasielastic scattering measurements on ESSO bitumen compound at room temperature. The area of the quasielastic peak as a function of the impulse transfer has an oscillatory behavior having a very prominent peak at 0.5 A-1. As the translational motions are too slow in this case, the dynamical behavior of the system is given by rotational motions of different molecular groups of the compound. The so-called 'elastic incoherent structure factor' (E.I.S.F.) of rotational motions depends mainly on the squared Bessel function j0(κd) (where κ is the impulse transfer and d is the gyration radius of the scattering cluster). Using the position of the main maximum in the E.I.S.F. plot as a function of κ we obtained a diameter of about 10 A for the molecular scattering cluster. This value can be assigned to polynuclear aromatic sheets inside of a asphaltene-micelle aggregate, according to Yen colloidal model proposed for compounds of this type. (authors)

  6. The Canadian oil sands industry under carbon constraints

    International Nuclear Information System (INIS)

    We investigate the impact of climate policies on Canada’s oil sands industry, the largest of its kind in the world. Deriving petroleum products such as gasoline and diesel from oils sands involves significant amounts of energy, and that contributes to a high level of CO2 emissions. We apply the MIT Emissions Prediction and Policy Analysis (EPPA) model, a computable general equilibrium model of the world economy, augmented to include detail on the oil sands production processes, including the possibility of carbon capture and storage (CCS). We find: (1) without climate policy, annual Canadian bitumen production increases almost 4-fold from 2010 to 2050; (2) with climate policies implemented in developed countries, Canadian bitumen production drops by 32% to 68% from the reference 4-fold increase, depending on the viability of large-scale CCS implementation, and bitumen upgrading capacity moves to the developing countries; (3) with climate policies implemented worldwide, the Canadian bitumen production is significantly reduced even with CCS technology, which lowers CO2 emissions at an added cost. This is mainly because upgrading bitumen abroad is no longer economic with the global climate policies. - Highlights: ► We investigate the impact of climate policies on Canada’s oil sands industry. ► A computable general equilibrium model of the world economy is applied for the assessment. ► Without climate policy, Canadian bitumen production increases almost 4 fold from 2010 to 2050. ► With regional policy, bitumen output may drop by up to 68% and upgrading moves to no-policy countries. ► With global policy, bitumen production is significantly reduced since upgrading abroad is no longer viable.

  7. Waterproof Structure Design of Car Camera%车载摄像头的防水结构设计

    Institute of Scientific and Technical Information of China (English)

    吴广峰; 朱文坚

    2013-01-01

    主要阐述车载摄像头的用途、分类和结构特点。分析车载摄像头防水结构设计的主要部位,阐述不同部位的防水要求及其结构设计要点。最后介绍了车载视觉系统技术的发展的趋势。%This article has mainly explained the use, classification and structural characteristics of car cameras. Analysis waterproof structure design of the main parts of the car camera,explain different parts of the waterproof requirements and structural design elements of car camera. Introduce the trends of automotive vision system technology at last.

  8. Industrialization

    International Nuclear Information System (INIS)

    This chapter discusses the role-plays by nuclear technology to enhance productivity in industry. Some of the techniques, Non-Destructive Testing (NDT) - x, gamma, electron and neutron radiography, nuclear gauges, materials characterization are discussed thoroughly

  9. Fourier transform infrared spectroscopy as a suitable technique in the study of the materials used in waterproofing of archaeological amphorae

    International Nuclear Information System (INIS)

    The resinous materials from the interior surfaces of two Roman and one Iberian amphora were studied with Fourier transform infrared (FTIR) spectroscopy. The results were then compared with those obtained by synchrotron radiation-FTIR, scanning electron microscopy (SEM), and gas chromatography-mass spectrometry (GC-MS). The FTIR spectra obtained by the technique of KBr micropellets, prepared directly with the materials scraped from the amphora without any further sample preparation, provided enough information to establish their diterpenoic nature, and even to differentiate between the two main materials employed for waterproofing purposes, pitch and wood tar. Methyl dehydroabietic acid (DHAM) is the main chemical marker that allows a distinction to be made between these two materials. Pitch and wood tar were prepared in the laboratory heating pine resin and resinous pine wood, respectively. These resinous waterproofing materials were compared with the coatings extracted from the amphorae. The samples whose direct FTIR spectra showed a signal at ∼1740 cm-1, attributed to a carbonyl group of methyl ester, presented as well a peak of DHAM in the GC-MS chromatogram of the neutral fraction of their extract. Samples without this signal in their spectra did not present DHAM in their chromatogram. This work studies, for the first time, waterproofing of an amphora attributed to the Iberian culture

  10. On the determination of diffusivities of volatile hydrocarbons in semi-solid bitumen

    International Nuclear Information System (INIS)

    Carbon dioxide, supercritical ethane and propane have been considered as solvents to recover heavy oil. Given that mixing solvent with bitumen is one of the important parameters governing the performance of the solvent extraction processes, good understanding of solvent dispersion is essential for the proper design of the process. Produced bitumen can still contain some residual volatile hydrocarbons after gas flashing off a three-phase separator. When exposed to the air due to a spill or ruptured line, these residual hydrocarbons can escape and create air pollution problems. Consequently, knowledge of the diffusivities of volatile components in bitumen is needed to assess the extent of environmental damage that may result from bitumen spill or working loss of vapour to the atmosphere. This paper discusses the de-coupled transfer model developed by this author (and described in a paper in vol. 78 of this journal) and its limiting solution, and provides a re-intrepretation of the method by Fu and Phillips (1979) which in turn was based on the late-time limiting solution advanced by Tang and Zhang (2000). The analysis indicates that gas purging is a valid method for determining the diffusion coefficients of trace, volatile hydrocarbons in bitumen. However, the assumption of de-coupling may not be appropriate for large diffusion flux and slow gas flow. Furthermore, improper use of the limiting solution theory could lead to a 25 per cent error in calculating the diffusion coefficient. 14 refs., 2 tabs., 8 figs

  11. Bitumen on Water: Charred Hay as a PFD (Petroleum Flotation Device

    Directory of Open Access Journals (Sweden)

    Nusrat Jahan

    2015-10-01

    Full Text Available Global demand for petroleum keeps increasing while traditional supplies decline. One alternative to the use of conventional crude oils is the utilization of Canadian bitumen. Raw bitumen is a dense, viscous, semi-liquid that is diluted with lighter crude oil to permit its transport through pipelines to terminals where it can then be shipped to global markets. When spilled, it naturally weathers to its original form and becomes dense enough to sink in aquatic systems. This severely limits oil spill recovery and remediation options. Here we report on the application of charred hay as a method for modifying the surface behavior of bitumen in aquatic environments. Waste or surplus hay is abundant in North America. Its surface can easily be modified through charring and/or chemical treatment. We have characterized the modified and charred hay using solid-state NMR, contact angle measurements and infrared spectroscopy. Tests of these materials to treat spilled bitumen in model aquatic systems have been undertaken. Our results indicate that bitumen spills on water will retain their buoyancy for longer periods after treatment with charred hay, or charred hay coated with calcium oxide, improving recovery options.

  12. Transparent, self-cleaning and waterproof surfaces with tunable micro/nano dual-scale structures

    Science.gov (United States)

    Lee, Yujin; You, Eun-Ah; Ha, Young-Geun

    2016-09-01

    The rational design and facile fabrication of optically transparent, superhydrophobic surfaces can advance their versatile applications, including optoelectronic devices. For the easily accessible and scalable preparation of transparent, superhydrophobic surfaces, various coating methods using a solution-process have been developed. However, obtaining highly transparent, non-wetting surfaces with excellent properties is challenging due to the difficulty in controlling surface roughness. Here, we report on a novel approach to control the surface roughness by fabricating tailorable micro/nano dual-scale surface structures via solution-processed nanoparticle coating. The surface roughness was able to be controlled by micro/nano dual-scale structures that can be manipulated by varying the mixture ratio of two different sizes of Al2O3 nanoparticles. The controllable micro/nano dual-scale structures were optimized to achieve the superior surface properties in both hydrophobicity and transparency, exhibiting a high water contact angle (>160°), low sliding angle (90%). These characteristics allowed an excellent transparency and self-cleaning capability as well as a superior waterproof ability even under applied voltage. Furthermore, we demonstrated the versatile applicability of the developed surface-coating method to a wide range of substrates including glass, paper, fabrics, and even flexible plastics.

  13. Anti-Reflective and Waterproof Hard Coating for High Power Laser Optical Elements

    Science.gov (United States)

    Murahara, Masataka; Yabe, Takashi; Uchida, Shigeaki; Yoshida, Kunio; Okamoto, Yoshiaki

    2006-05-01

    A hard coating method of single crystalline porous silica film is widely used for high power laser optical elements in the air. However, there is no protective hard coating method for the elements to survive high power laser irradiance while in the water. We, thus, developed a new method for a waterproof coating with photo-oxidation of silicone oil. The silicone oil was spin-coated onto the surface of optical elements, and then irradiated with a xenon excimer lamp in the air. In this treatment, a protective coating for plastic lenses, mirrors, and nonlinear optical crystals, which are highly deliquescent, was developed by taking advantage of the phenomenon in which organic silicone oil is transformed to inorganic amorphous glass by a process of photo-oxidation. This technique has enabled an optical thin coating film to transmit ultraviolet rays of wavelengths under 200 nm and possess the characteristics of homogeneity, high density, resistance to environment, anti-reflectiveness, resistance to water, and Mohs' scale of 5, which is comparable to apatite. This allows us to cool a slab laser head and use as a mirror for underwater laser welding.

  14. Industry

    Energy Technology Data Exchange (ETDEWEB)

    Bernstein, Lenny; Roy, Joyashree; Delhotal, K. Casey; Harnisch, Jochen; Matsuhashi, Ryuji; Price, Lynn; Tanaka, Kanako; Worrell, Ernst; Yamba, Francis; Fengqi, Zhou; de la Rue du Can, Stephane; Gielen, Dolf; Joosen, Suzanne; Konar, Manaswita; Matysek, Anna; Miner, Reid; Okazaki, Teruo; Sanders, Johan; Sheinbaum Parado, Claudia

    2007-12-01

    This chapter addresses past, ongoing, and short (to 2010) and medium-term (to 2030) future actions that can be taken to mitigate GHG emissions from the manufacturing and process industries. Globally, and in most countries, CO{sub 2} accounts for more than 90% of CO{sub 2}-eq GHG emissions from the industrial sector (Price et al., 2006; US EPA, 2006b). These CO{sub 2} emissions arise from three sources: (1) the use of fossil fuels for energy, either directly by industry for heat and power generation or indirectly in the generation of purchased electricity and steam; (2) non-energy uses of fossil fuels in chemical processing and metal smelting; and (3) non-fossil fuel sources, for example cement and lime manufacture. Industrial processes also emit other GHGs, e.g.: (1) Nitrous oxide (N{sub 2}O) is emitted as a byproduct of adipic acid, nitric acid and caprolactam production; (2) HFC-23 is emitted as a byproduct of HCFC-22 production, a refrigerant, and also used in fluoroplastics manufacture; (3) Perfluorocarbons (PFCs) are emitted as byproducts of aluminium smelting and in semiconductor manufacture; (4) Sulphur hexafluoride (SF{sub 6}) is emitted in the manufacture, use and, decommissioning of gas insulated electrical switchgear, during the production of flat screen panels and semiconductors, from magnesium die casting and other industrial applications; (5) Methane (CH{sub 4}) is emitted as a byproduct of some chemical processes; and (6) CH{sub 4} and N{sub 2}O can be emitted by food industry waste streams. Many GHG emission mitigation options have been developed for the industrial sector. They fall into three categories: operating procedures, sector-wide technologies and process-specific technologies. A sampling of these options is discussed in Sections 7.2-7.4. The short- and medium-term potential for and cost of all classes of options are discussed in Section 7.5, barriers to the application of these options are addressed in Section 7.6 and the implication of

  15. It's all about the bitumen : oilsands producers have the attention of the world

    Energy Technology Data Exchange (ETDEWEB)

    Jaremko, D.

    2005-09-01

    Within 10 years, oilsands growth will make Canada the fifth largest oil producing country in the world, thereby greatly increasing Canada's political power. A review of oil sands development was presented, with reference to the way in which Steam Assisted Gravity Drainage (SAGD) has revolutionized the industry. Recent acquisitions have pointed to the growing level of international interest in the oilsands industry. Construction details of the Surmont project were discussed along with Devon Canada's SAGD project at Jackfish where about 100 well-pairs are expected to be drilled. Petrobank Energy and Resources is constructing its Whitesands project, which will employ the first field-scale application of the toe-to-heel air injection (THAI) recovery method which has lower operating costs and which uses less water and creates fewer greenhouse (GHG) emissions. The pilot was designed to produce up to 1800 barrels per day of partially upgraded bitumen. Details of CNRI's Horizon project were presented, including construction plans and schedules. Shell Canada's increased budget for the first expansion of the Athabasca Oilsands Project was reviewed with reference to their strategic decision to pre-build infrastructure for future expansions. Details of Suncor Energy's production goals were also reviewed, including details of new upgraders and applications. Syncrude's continuing expansions were discussed, as well as their current production levels. An outline of UTS Energy Corporation and Petro-Canada's plans concerning the Fort Hills Mining Project was presented, with details of the new BITMIN extraction process. It was noted that Imperial Oil has filed regulatory applications for the Kearl Oilsands Project, which have estimated total recoverable bitumen resources of 4.4 billion barrels. Husky Energy's Sunrise Project was discussed, as well as MEG Energy's regulatory approval for the first phase of the Christina Lake Regional

  16. Thermal Fatigue with Freeze-thaw Cycles of Polymer Modified Bitumen

    Directory of Open Access Journals (Sweden)

    Bachir Glaoui

    2011-01-01

    Full Text Available This research contributes to characterize the EVA polymer modified bitumen, which was subjected to thermal fatigue. The aim of this work was to determine the rheological components and their evolutions under thermal fatigue with freezing - thawing cycles. To represent thermal fatigue phenomenon of polymer modified bitumen in laboratory, both freezer and controlled temperature room were used to produce the real cycles of freeze-thaw of winter season. The results suggest that thermal fatigue is more complicated on rheological behavior of polymer modified bitumen. It is shown that thermal fatigue influenced thermal cracking, fatigue cracking and permanent deformation resistance. It is concluded that thermal fatigue due to thermal cycling, is a big problem to accelerate the degradation of pavement.

  17. Diterpanes, triterpanes, steranes, and aromatic hydrocarbons in natural bitumens and pyrolysates from different humic coals

    Science.gov (United States)

    Lu, Shan-Tan; Kaplan, Isaac R.

    1992-07-01

    Data are presented on the distribution of diterpanes, triterpanes, steranes, and aromatic hydrocarbons in the natural bitumens extracted from unheated coals identified as Rocky Mountain coal (RMC), Australian Gippsland Latrobe Eocene coal (GEC), Australian Gippsland Latrobe Cretaceous coal (GCC), and Texas Wilcox lignite (WL), as well as from pyrolysates obtained from heating of these coals. It was found that pentacyclic triterpanes are dominant in GEC, GCC, and WL, whereas diterpanes strongly predominate in the bitumen of RMC, indicating that resin is a more important constituent of RMC than of the other coals and that it releases the diterpenoids at an early stage of diagenesis. It was also found that the composition of diterpanes is different among these coals and that the distributions of sterane and triterpane in the natural bitumen of coals are very different from those of pyrolysates.

  18. Diluent and bitumen, an uneasy mix : considerations for treating, blending, transportation, marketing and refining

    International Nuclear Information System (INIS)

    This presentation evaluated several issues regarding the use of diluent as a blending agent with Canadian bitumen. Heavy and viscous crude oils are commonly diluted with condensates and gasolines. This improves field processing, transportability in pipelines and acceptability in markets and refineries. The demand for such diluent is increasing because of the large amounts of heavy oil and bitumen currently produced in Canada. The current tenable price of diluents has meant that a wide range of diluent sources and components are finding their way into the Canadian diluent supply stream. This has raised concerns regarding diluent performance and the affect on blended crude oils. The cost of diluent is among the most controllable expense associated with most bitumen production projects. Market factors were considered in this presentation, such as supply demand; price and infrastructure; operational processing and blending issues; diluent quality and component variability; and downstream issues such as refinery processing and production. tabs., figs

  19. Performance Test for Open Grade Bitumen and Cement Mixture OGBC-20

    Science.gov (United States)

    Li, Y. Y.; Wu, Z. L.; Li, C. M.; Gan, X. Z.; Xiong, X. J.

    For effective prevention of urban road intersection special sections for nit diseases and improving the pavement durability, an open grade bitumen and cement (OGBC-20) mixture is proposed. In organic hydraulic cement mixture design, mix proportion designs of cement mortar and matrix open-graded bitumen were done. The matrix mixture gradation was adjusted .It has greater void of air volume than that of ATPB-25. A variety of tests in laboratory for OGBC-20 were performed. The experimental results show that: The void of air volume of adjusted gradation matrix asphalt mixture is up to 23%. and binder drainage loss is ≤ 0.3%. Cement mortar filling is fuller and better water stability and low temperature crack resistance compared to ordinary bitumen mixture. It has the absolute advantage on high temperature stability and shows the superiority of the new pavement materials.

  20. Modeling the release, behavior, and fate of bitumen-water emulsions

    International Nuclear Information System (INIS)

    A modeling approach was developed for simulating the release, fate, and transport of an Orimulsion spill in lakes, rivers or seas. Orimulsion (a new substitute for heavy fuel oils), is a bitumen and water emulsion which can have a positive, neutral or negative buoyancy depending on the properties of the surrounding water. The unique physical characteristics of Orimulsion make it necessary to modify existing oil behaviour models. Three areas of experimentation were identified: (1) estimating discharge rates from a leaking tanker, (2) understanding weathering of the product, and (3) examining the consequences of subsurface transport. A formula was devised for generalizing oil sedimentation models to include bitumens. It was shown that any bitumen in a marine spill that does not aggregate, sink to the bottom, or adhere to suspended sediment will be transported by the subsurface current. 25 refs

  1. Observations and morphological analysis of supermolecular structure of natural bitumens by atomic force microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Yevgeny A. Golubev; Olga V. Kovaleva; Nikolay P. Yushkin [Institute of Geology of RAS, Syktyvkar (Russian Federation)

    2008-01-15

    The supermolecular structures of natural bitumens of the thermal consequent row asphaltites lower kerites (albertites), higher kerites (impsonites), anthraxolites from the Timan-Pechora petroleum province and Karelian shungite rocks, Russia, were studied in details. The experimental technique used was atomic force microscopy (AFM), following fracture preparation. The element distribution of the sample surfaces was analyzed by an X-ray microanalyser 'Link ISIS', combined with a scanning electron microscope (SEM). In this work, we characterized the supermolecular evolution of natural solid bitumens in the carbonization sequence by quantitative parameters. We showed that supermolecular structure can be important in defining to which classification group solid bitumens belong. 29 refs., 7 figs., 2 tabs.

  2. Diluent and bitumen, an uneasy mix : considerations for treating, blending, transportation, marketing and refining

    Energy Technology Data Exchange (ETDEWEB)

    Todd, C. [Connacher Oil and Gas Ltd., Calgary, AB (Canada)

    2009-07-01

    This presentation evaluated several issues regarding the use of diluent as a blending agent with Canadian bitumen. Heavy and viscous crude oils are commonly diluted with condensates and gasolines. This improves field processing, transportability in pipelines and acceptability in markets and refineries. The demand for such diluent is increasing because of the large amounts of heavy oil and bitumen currently produced in Canada. The current tenable price of diluents has meant that a wide range of diluent sources and components are finding their way into the Canadian diluent supply stream. This has raised concerns regarding diluent performance and the affect on blended crude oils. The cost of diluent is among the most controllable expense associated with most bitumen production projects. Market factors were considered in this presentation, such as supply demand; price and infrastructure; operational processing and blending issues; diluent quality and component variability; and downstream issues such as refinery processing and production. tabs., figs.

  3. Modification of Bitumen with Desulfurized Crumb Rubber in the Present of Reactive Additives

    Institute of Scientific and Technical Information of China (English)

    YE Zhigang; ZHANG Yuzhen; KONG Xianming

    2005-01-01

    Bitumen was modified with desulfurized crumb rubber (DCR) in the present of reactive additives. The effect of the kinds and content of the reactive additive on properties of DCR modified bitumen (DCRMB) was investigated. The morphology of DCRMB was characterized by SEM and the changes of the chemical structure of DCRMB without and with the addition of the reactive additive were analyzed by FTIR. The experimented results show that the softening point,the elasticity recovery and the storage stability of DCRMB were improved significantly by the addition of the reactive additive. This is because that a network structure of rubber in DCRMB was formed and the chemical reaction between C=C double bonds in bitumen and DCR has happened after the reactive additive was added into DCRMB.

  4. Hydroprocessing full-range of heavy oils and bitumen using ultradispersed catalysts at low severity

    Science.gov (United States)

    Peluso, Enzo

    The progressive exhaustion of light crude oils is forcing the petroleum industry to explore new alternatives for the exploitation of unconventional oils. New approaches are searching for technologies able to produce, transport and refine these feedstocks at lower costs, in which symbiotic processes between the enhanced oil recovery (EOR) and the conventional upgrading technologies are under investigation. The process explored in this thesis is an interesting alternative for in-situ upgrading of these crude oils in the presence of ultradispersed (UD) catalysts, which are included as a disperse phase able to circulate along with the processed feed. The objectives of this work are: (a) study the performance of UD catalysts in the presence of a full range (non fractioned) heavy oil and bitumen and (b) evaluate the recyclability of the UD catalysts. Four different heavy crude oils were evaluated in the presence with UD catalysts at a total pressure of 2.8 MPa, residence time of 8 hours and reaction temperatures from 360 up to 400ºC. Thermal and catalytic hydro-processing were compared in terms of conversion and product stability. A comparison between the different crude oils was additionally derived in terms of SARA, initial micro-carbon content and virgin oil stability among other properties. Advantages of catalytic hydro-processing over thermal hydro-processing were evidenced, with UD catalysts playing an essential hydrogenating role while retarding coke formation; microcarbon and asphaltenes reduction in the presence of UD catalysts was observed. To evaluate the feasibility of recycling the UD catalysts, a micro-slurry recycled unit was developed as part of this research. These main results showed: (a) a successful design of this unit, (b) that temperature, LHSV and fractional recycling ratio have more impact on VGO conversion, while pressure has almost no effect, and (c) an UD catalysts agglomeration process was detected, however this process is slow and reversible.

  5. Diterpanes, triterpanes, steranes and aromatic hydrocarbons in natural bitumens and pyrolysates from different humic coals

    Energy Technology Data Exchange (ETDEWEB)

    Lu, S.T.; Kaplan, I.R. (California University, Los Angeles, CA (USA). Inst. of Geophysics and Planetary Physics)

    1992-07-01

    There is a significant difference in the distribution of terpanes in natural bitumen extracted from Rocky Mountain coal (RMC), Australian Gippsland Latrobe Eocene coal (GEC), Australian Gippsland Latrobe Eocene Cretaceous coal (GCC), and Texas Wilcox lignite (WL). Pentacyclic triterpanes are dominant in GEC, GCC, and WL, diterpanes strongly predominate in the bitumen of RMC indicating that resin is a more important constituent of RMC than in the other coals and releases the diterpenoids at an early stage of diagenesis. Furthermore, the composition of diterpanes is also different among these coals. The diterpenoid content is negligible in the pyrolysates of all coals. The sterane and triterpane distributions in the natural bitumen of coals are very different from those in pyrolysates e.g. C31 alpha-beta-22R hopane predominates in the m/z 191 mass fragmentograms of the natural bitumens, whereas a homologous series of hopanes (C27-C35; except C28) is present in the coal pyrolysates. C27 steranes are absent in the natural bitumen, but are generated in pyrolysates during lengthy heating of coal kerogen. C29 monoaromatic steroid hydrocarbons are abundant in the natural bitumen of the four coals. Triaromatic steroid hydrocarbons are only present in GCC, whereas significant amounts of tetra- and triaromatic triterpenoid hydrocarbons are present in the other three coals (GEC, RMC, and WL). The ratio of benzo(e)pyrene/perylene may be potentially useful as a maturity parameter because the amount of benzo(e)pyrene increases with thermal stress, whereas perylene decreases with heating time. Benzohopanes are widely present in four humic coals.

  6. Waste reduction algorithm used as the case study of simulated bitumen production process

    Directory of Open Access Journals (Sweden)

    Savić Marina A.

    2011-01-01

    Full Text Available Waste reduction algorithm - WAR is a tool helping process engineers for environmental impact assessment. WAR algorithm is a methodology for determining the potential environmental impact (PEI of a chemical process. In particular, the bitumen production process was analyzed following three stages: a atmospheric distillation unit, b vacuum distillation unit, and c bitumen production unit. Study was developed for the middle sized oil refinery with capacity of 5000000 tones of crude oil per year. Results highlight the most vulnerable aspects of the environmental pollution that arise during the manufacturing process of bitumen. The overall rates of PEI leaving the system (PEI/h - Iout PEI/h are: a 2.14105, b 7.17104 and c 2.36103, respectively. The overall rates of PEI generated within the system - Igen PEI/h are: a 7.75104, b -4.31104 and c -4.32102, respectively. Atmospheric distillation unit have the highest overall rate of PEI while the bitumen production unit have the lowest overall rate of PEI. Comparison of Iout PEI/h and Igen PEI/h values for the atmospheric distillation unit, shows that the overall rate of PEI generated in the system is 36.21% of the overall rate of PEI leaving the system. In the cases of vacuum distillation and bitumen production units, the overall rate of PEI generated in system have negative values, i.e. the overall rate of PEI leaving the system is reduced at 60.11% (in the vacuum distillation unit and at 18.30% (in the bitumen production unit. Analysis of the obtained results for the overall rate of PEI, expressed by weight of the product, confirms conclusions.

  7. Research on swelling clays and bitumen as sealing materials for radioactive waste repositories

    International Nuclear Information System (INIS)

    This report describes a programme of research to investigate the performance of composite seals comprising juxtaposed blocks of highly compacted bentonite clay and bitumen. It is shown that interaction of the materials can promote a self-sealing mechanism which prevents weather penetration, even when defects are present in the bitumen layer. Factors affecting seal performance are examined by means of laboratory experiments, and implications for the design of repository backfilling and sealing systems are discussed. It is concluded that design principles and material specifications should be further developed on the basis of large scale experiments. (author)

  8. Quantification of bitumen particles in aerosol and soil samples using HP-GPC

    DEFF Research Database (Denmark)

    Fauser, Patrik; Tjell, Jens Christian; Mosbæk, Hans;

    2000-01-01

    A method for identifying and quantifying bitumen particles, generated from the wear of roadway asphalts, in aerosol and soil samples has been developed. Bitumen is found to be the only contributor to airborne particles containing organic molecules with molecular weights larger than 2000 g pr. mol....... These are separated and identified using High Performance Gel Permeation Chromatography (HP-GPC) with fluorescence detection. As an additional detection method Infra Red spectrometry (IR) is employed for selected samples. The methods have been used on aerosol, soil and other samples....

  9. Determination of the bitumen content in asphalt concrete using a neutron reflection method

    International Nuclear Information System (INIS)

    A neutron physical method (reflection method) for the fast, nondestructive determination of the bitumen content in asphalt concrete has been developed. The determination is performed on cylindrical asphalt concrete samples containing desiccated rubble matrix. Using samples of about 1000g and measuring times of 20 min, the reproducibility of the bitumen determination is 0.15 w%, the sensitivity is 3.10-3 g/g. The thus obtained results were compared with data obtained by chemical analysis, using two different type of matrix. The mean values and the standard deviations are in good agreement for both cases. (T.G.)

  10. Solubility of methane, nitrogen, and carbon dioxide in bitumen and water for SAGD modelling

    Energy Technology Data Exchange (ETDEWEB)

    Al-Murayri, M.T.; Harding, T.G.; Maini, B.B.

    2011-07-15

    The steam assisted gravity-drainage (SAGD) process is a technology used in unconventional reservoirs to enhance oil recovery, this technique sometimes uses the co-injection of noncondensable gases (NCGs). The co-injection of NCGs with steam is used to reduce energy consumption and greenhouse gas emissions in SAGD, but this technique also affects the performance of SAGD, making the knowledge of gas solubility in bitumen and water important. This study was undertaken to develop a systematic approach to predict the K-values for the gas-bitumen and gas water phase equilibria at different temperatures and pressures. This research has been carried out by using different existing correlations. It has been observed that the Mehrotra and Svrcek gas-solubility correlation should be used to calculate NCG's solubility in bitumen and that NCGs' solubility in water could be calculated with Harvey's correlation. This study defined successfully an approach to calculate NCGs' solubility in bitumen and water.

  11. Thermal maturity, alginite-bitumen transformation, and hydrocarbon generation in Upper Ordovician source rocks, Saskatchewan, Canada

    Energy Technology Data Exchange (ETDEWEB)

    Stasiuk, L.D.; Osadetz, K.G. (Inst. of Sedimentary and Petroleum Geology, Calgary, Alberta (Canada))

    Organic petrological techniques have been used to study the alginite-bitumen-oil transformation in Upper Ordovician Yeoman Formation kukersite source rocks of the northern Williston Basin, Saskatchewan, Canada. The kukersites are characterized by two distinct interlaminated microfacies, disseminated and stromatolitic, each representing a growth stage of the precursor to the alginite maceral Gloeocapsomorpha prisca. Different rates of thermal maturation and thresholds of petroleum generation for the two G. prisca maceral subvarieties are indicated by different rates of percent reflectance in oil increase and are verified by shifts in fluorescence spectra and observations on transformation into bitumen. With increasing thermal maturation, disseminated G.prisca reaches a softening stage, losing its primary morphological features as it is transformed from a primary to a secondary maceral (bitumen). The stromatolitic subvariety of G. prisca does not display comparable alteration in response to increasing thermal stress. Hot stage experiments conducted on doubly polished thin sections of the kukersites support the optical discrepancies observed between the two maceral subvarieties in the subsurface. These findings indicate that hydrocarbon generation from kukersites may involve two steps controlled largely by organic microfacies. Inception of petroleum generation appears to occur at a depth of 3000 m for the disseminated alginite. Bitumen has been cracked to anisotropic 'coke' on a local thermal anomaly, and peak to postgeneration of petroleum has occurred at a maximum temperature of 148[degree]C, as suggested by homogenization temperatures for fluid inclusions.

  12. Chemical modification of bitumen heavy ends and their non-fuel uses

    Energy Technology Data Exchange (ETDEWEB)

    Moschopedis, S.E.; Speight, J.G.

    1976-01-01

    Bitumen asphaltenes undergo a variety of simple chemical conversions. For example, asphaltenes can be oxidized, sulfonated, sulfomethylated, halogenated, and phosphorylated. The net result is the introduction of functional entities into the asphaltene structure which confers interesting properties on the products for which a variety of uses are proposed.

  13. Characterization of cement and bitumen waste forms containing simulated low-level waste incinerator ash

    International Nuclear Information System (INIS)

    Incinerator ash from the combustion of general trash and ion exchange resins was immobilized in cement and bitumen. Tests were conducted on the resulting waste forms to provide a data base for the acceptability of actual low-level waste forms. The testing was done in accordance with the US Nuclear Regulatory Commission Technical Position on Waste Form. Bitumen had a measured compressive strength of 130 psi and a leachability index of 13 as measured with the ANS 16.1 leach test procedure. Cement demonstrated a compressive strength of 1400 psi and a leachability index of 7. Both waste forms easily exceed the minimum compressive strength of 50 psi and leachability index of 6 specified in the Technical Position. Irradiation to 108 Rad and exposure to 31 thermal cycles ranging from +600) to -300C did not significantly impact these properties. Neither waste form supported bacterial or fungal growth as measured with ASTM G21 and G22 procedures. However, there is some indication of biodegradation due to co-metabolic processes. Concentration of organic complexants in leachates of the ash, cement and bitumen were too low to significantly affect the release of radionuclides from the waste forms. Neither bitumen nor cement containing incinerator ash caused any corrosion or degradation of potential container materials including steel, polyethylene and fiberglass. However, moist ash did cause corrosion of the steel

  14. Solidification of low and medium level wastes in bitumen at Barsebaeck nuclear power station

    International Nuclear Information System (INIS)

    Operating experience is presented from 4 years of bitumen solidification of wastes coming from two boiling water reactors. Methods used to sample, analyse and document the wastes are described. Transport and storage methods without remote handling have been adopted. The risk of fire is discussed and a description is given of the measures taken for fire protection. (author)

  15. In situ analytical pyrolysis of coal macerals and solid bitumens by laser micropyrolysis GC-MS

    Energy Technology Data Exchange (ETDEWEB)

    Greenwood, P.F.; George, S.C.; Pickel, W. [CSIRO Petroleum, PO Box 136, NSW 1670 N. Ryde (Australia); Zhu, Y. [Petroleum Geochemistry Research Center, Jianghan Petroleum University, Jingzhou, 434102 Hubei (China); Zhong, N. [Applied Geochemistry Laboratory, University of Petroleum, Changping, 102200 Beijing (China)

    2001-04-01

    Specific macerals in coals and distinct solid organic bitumens within limestones from northern China were separately analysed in situ by laser micropyrolysis gas chromatography-mass spectrometry. The major pyrolysates from the resinite and cutinite macerals included aromatic hydrocarbons such as alkylnaphthalenes, alkylbenzenes, alkyltetralins (in the resinite) and alkylphenols (in the cutinite), and aliphatic hydrocarbons such as n-alk-1-enes, n-alkanes, pristane and phytane. The same classes of hydrocarbons were also detected in co-occurring vitrinites, including very similar relative distributions of alkylnaphthalenes in the case of the resin-rich coal. Several observed quantitative differences are consistent with previous molecular data from maceral concentrates. The qualitative similarity of the maceral data suggest (1) extensive assimilation of free hydrocarbons by all macerals within the coals; or (2) inefficient targeting of the macerals by the laser, although microscopic observation showed that the laser craters were generally constrained within surface boundaries of the maceral. The organic composition of a solid bitumen within a Carboniferous limestone was characterised by a distinctive distribution of C{sub 0}-C{sub 4} alkyldibenzofurans, as well as alkylbenzenes, alkylnaphthalenes and a low molecular weight distribution of n-alk-1-enes and n-alkanes. These data suggest the solid bitumen comprises a strongly aromatic matrix with terrestrially-derived oxygen functionality and alkyl linkages. The same aromatic and aliphatic hydrocarbon products were also detected in the morphologically homogenous carbonates hosting the solid bitumens, indicating the presence of sub-microscopic organic moieties throughout the limestone.

  16. Infrared microscopy investigation of oxidation and phase evolution in bitumen modified with polymers

    Energy Technology Data Exchange (ETDEWEB)

    Virginie Mouillet; Jerome Lamontagne; Francoise Durrieu; Jean-Pascal Planche; Laurence Lapalu [Laboratoire Regional des Ponts et Chaussees, Aix-en-Provence (France)

    2008-06-15

    Polymer modified bitumens (PmB) were studied in their original state and after conventional tests claimed to simulate the ageing during the mixing process and several years of road service (RTFOT + PAV). The PmB's included plastomers and elastomers, some of them being in situ crosslinked. Infrared microscopy was used to determine for each phase the polymer rate and functional indices characterizing the bitumen such as aromaticity, aliphaticity and condensation, and also to map the polymer distribution in the PmB. The characterization of PmB in their original state points out which species of the bitumen are involved in the polymer swelling and the effect of the polymer nature. The characterization of the same PmB's after the RTFOT + PAV ageing shows how the bitumen species responsible for the swelling evolve during ageing. In addition, kinetic studies were performed using an heating cell fitted to the IR microscope. They confirmed the tendencies obtained with the conventional ageing tests. These studies come to the conclusion of an interdependence of the ageing of the different constitutive phases in a PmB and of chemical exchanges between them. They make clear the micro-morphological modification induced by ageing in a PmB. They finally help to better understand the effect of a crosslinking on the PmB microstructure and its ageing mechanism. 44 refs., 15 figs., 7 tabs.

  17. Bitumen modification with a low-molecular-weight reactive isocyanate-terminated polymer

    Energy Technology Data Exchange (ETDEWEB)

    F.J. Navarro; P. Partal; M. Garcia-Morales; F.J. Martinez-Boza; C. Gallegos [Universidad de Huelva, Huelva (Spain). Departamento de Ingenieria Quimica, Facultad de Ciencias Experimentales

    2007-10-15

    A low-molecular-weight polyethyleneglycol functionalized with a polymeric MDI (4,4'-diphenylmethane diisocynate) was used as a modifying agent for a 60/70 penetration grade bitumen. The rheological properties of the resulting modified binder, at both low and intermediate temperatures, before and after curing at room temperature were studied and compared with those corresponding to a SBS modified bitumen. The analysis showed that the addition of a small quantity of this reactive polymer leads to enhanced rheological properties mainly at high in-service temperature (50{sup o}C). However, modification was found to be rather slow during binder curing at room temperature. Moreover, storage stability analysis showed that phase separation did not take place after bitumen storage at 163{sup o}C, though storage at high temperature affects the modification capability of the reactive polymer. Atomic force microscopy measurements showed that the reactive polymer addition leads to asphaltene-rich regions with lower thermal susceptibility, which are present even at high temperature, yielding an improved bitumen viscosity in this range of in-service temperatures. 38 refs., 7 figs., 2 tabs.

  18. Tire-tread and bitumen particle concentrations in aerosol and soil samples

    DEFF Research Database (Denmark)

    Fauser, Patrik; Tjell, Jens Christian; Mosbæk, Hans;

    2002-01-01

    ire and bitumen particle concentrations are determined in aerosol and soil samples. They each constitute about 5 wt-% of the total suspended particulate matter (TSP) in inner city air, collected with a Berner low pressure impactor, 5 m from a road. The particle size distribution shows that 92% of...

  19. Bitumen/Water Emulsions as Fuels for High-Speed Ci Engines Preliminary Investigations

    DEFF Research Database (Denmark)

    Schramm, Jesper; Sigvardsen, R.; Forman, M.

    2003-01-01

    Mixtures of bitumen and water, are cheap fuel alternatives for combustion engines. There are, however, several problems that have to be solved before these fuels can be applied in high-speed diesel engines. These are: - emulsion break up due to high temperature or high shear stress in the injection...

  20. Towards the Development of Bitumen Carbonates: An Integrated Analysis of Grosmont Steam Pilots

    Directory of Open Access Journals (Sweden)

    Ezeuko C.C.

    2015-11-01

    Full Text Available The Grosmont Formation in Alberta, Canada is a highly fractured, karstified and vuggy bitumen-rich carbonate reservoir located west of and below the Athabasca oil sands deposit. The bitumen carbonate platform extends about 500 km in length and up to 150 km in width and contains an estimated 64.5 billion m3 (406.5 billion barrels of oil. The Grosmont Formation is larger than the combined total of all other known carbonate bitumen deposits in the world. Here, we analyze early Grosmont steam pilots to improve the design of future pilots and commercial development of this massive bitumen deposit. In agreement with the conclusions of earlier analysis of these Grosmont pilots, they were reasonably successful considering the heterogeneous nature of the Grosmont Formation. Operational factors such as poor steam quality, non-optimized high injection pressures and completion issues appear to have heavily impacted recovery performances. Clearly, steam-based recovery operations have good potential for Grosmont, especially considering that it is mature commercial technology. Following an integrated analysis of early Grosmont pilots, we posit that Cyclic Steam Stimulation (CSS using horizontal wells exhibits greater potential for the development of Grosmont carbonate, compared with Steam-Assisted Gravity Drainage technology (SAGD.

  1. Use of a thin-film evaporator for bitumen coating of radioactive concentrates

    International Nuclear Information System (INIS)

    Following the development in the laboratory of a process for coating evaporation concentrates with bitumen, a technological study of this coating process has been undertaken. The report describes a pilot installation for the bitumen coating of concentrates, which uses a thin-film evaporator LUWA L 150. The first, inactive series of tests was designed to determine the maximum and optimum capacities of the evaporator by varying the amounts of bitumen and of concentrate, the rotor speed and the thermo-fluid temperature. Two rotors were tested, one of conventional type, the other a model especially designed for high viscosity products. The maximum capacity of evaporation of the apparatus is 72 kg/hr for a heating temperature of 221 deg. C. During normal operation, the evaporator can produce 50 kg/hr of coated product containing 55 to 60 per cent of bitumen (Mexphalte 40/50), the water content of the product remaining under 0.5 per cent. A second series of tests will shortly be carried out on this pilot installation using, in particular, bituminous emulsions containing mainly Mexphalte 40/50 and 80/100. (authors)

  2. Effect of ageing under gamma radiations on the long term behaviour of bitumen material

    International Nuclear Information System (INIS)

    The referential scenario considered for bituminized waste drums is an intermediate storage likely to be followed by a deep geological disposal. Under geological disposal conditions, when site will be re-saturated with water and containers will be corroded, the main phenomenon likely to alter bituminized waste is linked to the presence of water. During intermediate storage conditions, drums will be submitted to the effect of irradiation, and for the external part of the wasteform to the effect of oxidation by surrounding air. The combined effect of air and radiation may increase bitumen oxidation. In further disposal conditions, alteration phenomena of drums will concern aged drums. The aim of these studies dealing with ageing, is to characterise the effect of alteration factors such as irradiation and radio-oxidation on the potential release of radionuclides from bituminized waste in disposal conditions. Radio-oxidation depends on: - the diffusion of O2 in the matrix (diffusion coefficient, solubility), -the intensity of radiation (dose rate), -the time of exposure to radiations. Low dose rates of radiation, near realistic dose rates are here investigated in order to characterise the effect of ageing phenomena on the long term behaviour of bitumen properties. Results concern Infra-red characterization of oxidized bitumen, gases evolution and diffusion of water. The evolution of the thickness of the oxidized layer with the dose and the dose rate for bitumen sample can be deduced from profiles of oxidised compounds concentration obtained with FTIR (Fourier transformed Infrared Spectroscopy). (authors)

  3. Influence of mineral fillers on the rheological response of polymer-modified bitumens and mastics

    Directory of Open Access Journals (Sweden)

    F. Cardone

    2015-12-01

    Full Text Available The rheological properties of the bituminous components (bitumen and bituminous mastic within asphalt mixtures contribute significantly to the major distresses of flexible pavements (i.e. rutting, fatigue and low temperature cracking. Asphalt mixtures are usually composed of mastic-coated aggregates rather than pure bitumen-coated aggregates. The purpose of this study is to investigate the effects of mineral fillers on the rheological behaviour of several polymer-modified bitumens (PMBs through laboratory mixing. A neat bitumen and two types of polymers (elastomeric and plastomeric were used to produce PMBs, and two fillers with different minerals (limestone and basalt were selected to obtain mastics. The dynamic shear rheometer (DSR and bending beam rheometer (BBR were used to characterize the rheological properties of PMBs and mastics. In particular, multiple stress creep recovery (MSCR tests were performed to evaluate the rutting potential at high temperatures, whereas BBR tests were carried out to investigate the low temperature behaviour of these materials. BBR results for unmodified mastics show that the increase of stiffness is similar regardless of the filler type, whereas results for polymer-modified mastics indicate that the degree of stiffening depends on the combination of filler/polymer types. MSCR results show that adding filler leads to a reduced susceptibility of permanent deformation and an enhanced elastic response, depending on the combination of filler/polymer types. Overall results suggest that a physical–chemical interaction between the filler and bitumen occurs, and that the interaction level is highly dependent on the type of polymer modification.

  4. The adsorption of Cs+, Sr2+ and Ni2+ on bitumen: a mechanistic model

    International Nuclear Information System (INIS)

    The adsorption of radionuclides on the waste matrix is a positive effect and contributes to the retardation of released radionuclides migrating to the geo-and biosphere. For the safety assessment studies, it is important to know whether or not radionuclides do adsorb on the waste matrix. In the present work the adsorption of 134Cs+, 85Sr2+ and 63Ni2+ on bitumen was studied as a function of the pH and ionic strength of the equilibrium solution. Bitumen emulsions with well defined surfaces were used. The surface of bitumen is negatively charged due to the deprotonation of weak acid carboxyl groups at the interface. The functional group density amounts to 1.37.1018 groups/m2 and their deprotonation behaviour can be well described by the 'Ionizable Surface Group' model. Cs+, Sr2+ and Ni2+ adsorb on the surface by three different processes, i.e. ion exchange, outer sphere complexation and inner sphere surface complexation respectively. The adsorption depends on the pH and the ionic strength of the contact solution. Under near field conditions, Cs+ and Sr2+ do not adsorb on the bitumen due to the competition with Na+, K+ and Ca2+ present in the cement pore water in contact with the bitumen. Ni2+ adsorption can also be neglected because the formation of neutral and anionic hydroxo complexes in solution competes strongly with the adsorption reaction. Other hydrolysable radionuclides of interest are expected to behave similarly to Ni2+. The main conclusion of the study is that the adsorption of radionuclides under near field conditions is expected to be very low. Consequently, this process need not to be considered in safety assessment studies. (author) figs., tabs., 30 refs

  5. Investigation of the Self-Healing Behaviors of Microcapsules/Bitumen Composites by a Repetitive Direct Tension Test

    OpenAIRE

    Jun-Feng Su; Peng Yang; Ying-Yuan Wang; Shan Han; Ning-Xu Han; Wei Li

    2016-01-01

    The aim of this work was to evaluate the self-healing behaviors of bitumen using microcapsules containing rejuvenator by a modified fracture healing–refracture method through a repetitive tension test. Microcapsules had mean size values of 10, 20 and 30 μm with a same core/shell ratio of 1/1. Various microcapsules/bitumen samples were fabricated with microcapsule contents of 1.0, 3.0 and 5.0 wt. %, respectively. Tension strength values of microcapsules/bitumen samples were measured by a repar...

  6. Reactor building 3D-model for evaluating the pressures on concrete regularization and foundation waterproofing membrane

    International Nuclear Information System (INIS)

    Angra dos Reis site in Brazil has already 2 operating PWR NPPs. Unit 3, with identical design to Unit 2, also a 1350 MW PWR, is expected to have its construction started in 2009. This new plant shall be founded directly on sound rock. The first step is to prepare this rock surface with a concrete regularization and a foundation waterproofing membrane. This study presents a 3D model approach of the corresponding reactor building to verify the maximum pressure acting on this surface. The 3D model permits to show a more realistic pressure distribution at every foundation specific detail. A static analysis is performed using ANSYS Mechanical Release 11.1. Dead weight, permanent and live loads, Safe Shutdown Earthquake (SSE) combined with Burst Pressure Wave (BPW) from the Feedwater Tank (SSB=SSE+BPW) and differences of temperature are taken into account. Considering all foundation nodes , the pressure distribution on the waterproofing membrane for each load case is obtained for vertical and horizontal directions, which corresponds to compression and tangential reaction loads. The maximum values occur in distinct positions for each load case. The maximum results are obtained according to DIN 25449 (2008) load combination criteria. The results are compared to a simplified analysis performed before, showing a good agreement in global values. (author)

  7. Electrochemical performance of mixed carbon material with waterproof membrane for lithium air battery in the ambient atmosphere

    International Nuclear Information System (INIS)

    A waterproof membrane made in-house is applied on the lithium air battery, which can effectively block the water molecules and carbon dioxide in the air, so as to reduce the occurrence of the side reaction, e.g. lithium ions react with water or carbon dioxide to form lithium hydroxide or lithium carbonate. Physicochemical analyses are conducted via XRD (X-ray diffraction), SEM (scanning electron microscope), nitrogen adsorption-desorption, EIS (electrochemical impedance spectroscopy) and LSV (linear sweep voltammetry) test. Under different hydrothermal reaction time and temperatures, α-MnO2 specific surface area, pore size distribution and catalytic properties are evaluated. The first and second discharge capacities are 649.5 mA h/g and 775.4 mA h/g, respectively. The relationship between the air electrode with graphite mixed Super P and α-MnO2 is evaluated as well as the relationship between pore size distribution and the battery discharge performance. An air electrode structure model is also established. - Highlights: • All electrochemistry characterizations were achieved in the ambient atmosphere. • A first made waterproof membrane can reduce the occurrence of the side reaction. • A cathodal structure model was constructed

  8. Coliquefaction of coal, tar sand bitumen and plastic (interaction among coal, bitumen and plastic); Sekitan/tar sand bitumen/plastic no kyoekika ni okeru kyozon busshitsu no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Yamaguchi, H.; Okuyama, Y.; Matsubara, K. [NKK Corp., Tokyo (Japan); Kamo, T.; Sato, Y. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    For the improvement of economy, coliquefaction of coal, tar sand bitumen and plastic was performed under low hydrogen pressure, to investigate the influence of interaction among these on the liquefaction characteristics. For comparison, coliquefaction was also performed under the hydrogen pressure same as the NEDOL process. In addition, for clarifying its reaction mechanism, coliquefaction of dibenzyl and plastic was performed as a model experiment, to illustrate the distribution of products and composition of oil, and to discuss the interaction between dibenzyl and various plastics, and between various plastics. Under direct coal liquefaction conditions, coprocessing of Tanito Harum coal, Athabasca tar sand and plastic was carried out under low hydrogen pressure with an autoclave. The observed value of oil yield was higher than the calculated value based on the values from separate liquefaction of coal and plastic, which suggested the interaction between coal and the mixed plastic. The results of coliquefaction of coal, tar sand bitumen and plastic could be explained from the obtained oil yield and its composition by the coliquefaction of dibenzyl and plastic. 2 refs., 3 tabs.

  9. Effect of hydrated lime and cement on moisture damage of recycled mixtures with foamed bitumen and emulsion

    OpenAIRE

    Nosetti, R.A.; Pérez Jiménez, Félix Edmundo; Martínez Reguero, Adriana Haydée; Miró Recasens, José Rodrigo

    2016-01-01

    Cold recycling with foamed bitumen can be used as a sustainable and cost-effective rehabilitation technique. This paper focuses on the evaluation of the resistance to the water action in mixtures with reclaimed asphalt pavement (RAP) and foamed bitumen by means of indirect tensile test, comparing the effect of two active fillers: cement and hydrated lime. Additionally, mixtures recycled with RAP and asphalt emulsions were also tested in order to compare the response of both technologies. Resu...

  10. First Observation of the Blending Zone Morphology at the Interface of Reclaimed Asphalt Binder and Virgin Bitumen

    OpenAIRE

    Nahar, S.N.; Mohajeri, M.; Schmets, A. J. M.; Scarpas, T.; Van de Ven, M.F.C.; Schitter, G.

    2013-01-01

    One of the challenges in designing recycled asphalt mixtures with a high amount of RAP is to estimate the blending degree between RAP binder and the added virgin bitumen. The extent of blending is crucial in this case as asphalt concrete response is influenced by the final binder properties. This paper focuses on the evaluation of interaction and extent of blending between RAP-binder and virgin bitumen by studying the microstructures of the ‘blending zone’ with atomic force microscopy (AFM). ...

  11. Analysis of the Influence of the Modernized Bitumen Batching System on the Composition of the Hot Mix Asphalt Mixture

    Directory of Open Access Journals (Sweden)

    Justas Bražiūnas

    2011-04-01

    Full Text Available The weighted mass of a binder in the bucket of the bitumen batcher of a batch-type asphalt plant should be such that its percentage of hot mix asphalt (HMA mixture lot would comply with the design amount of the job-mix formula in all mix batches. A bitumen batcher does not always weigh bitumen portions precisely. Their mass deviations from the amount determined by the project and its variation impair HMA composition and performance. The paper provides data on a statistical evaluation of bitumen batcher modernization performed at Lithuanian enterprise „LL“. The article analyzes differences in the structures of reconstructed and not reconstructed bitumen batching systems and presents methods for determining modernization effectiveness. The paper also focuses on the effectiveness of the batching system, determining deviations from bitumen content in subsamples taken and extracted everyday during two seasons (before and after batcher‘s modernization of producing HMA from the value of job-mix formula and comparing them to the values of tolerances.Article in Lithuanian

  12. Non-Newtonian behavior and molecular structure of Cooee bitumen under shear flow: A non-equilibrium molecular dynamics study

    Science.gov (United States)

    Lemarchand, Claire A.; Bailey, Nicholas P.; Todd, Billy D.; Daivis, Peter J.; Hansen, Jesper S.

    2015-06-01

    The rheology and molecular structure of a model bitumen (Cooee bitumen) under shear are investigated in the non-Newtonian regime using non-equilibrium molecular dynamics simulations. The shear viscosity, normal stress differences, and pressure of the bitumen mixture are computed at different shear rates and different temperatures. The model bitumen is shown to be a shear-thinning fluid at all temperatures. In addition, the Cooee model is able to reproduce experimental results showing the formation of nanoaggregates composed of stacks of flat aromatic molecules in bitumen. These nanoaggregates are immersed in a solvent of saturated hydrocarbon molecules. At a fixed temperature, the shear-shinning behavior is related not only to the inter- and intramolecular alignments of the solvent molecules but also to the decrease of the average size of the nanoaggregates at high shear rates. The variation of the viscosity with temperature at different shear rates is also related to the size and relative composition of the nanoaggregates. The slight anisotropy of the whole sample due to the nanoaggregates is considered and quantified. Finally, the position of bitumen mixtures in the broad literature of complex systems such as colloidal suspensions, polymer solutions, and associating polymer networks is discussed.

  13. Effect of Gamma-Irradiated Recycled Low-Density Polyethylene on the High- and Low-Temperature Properties of Bitumen

    Directory of Open Access Journals (Sweden)

    Perviz Ahmedzade

    2013-01-01

    Full Text Available This paper describes polymer modification of bitumen with gamma-irradiated recycled (γ-LDPER low-density polyethylene. The recycled low-density polyethylene (LDPER was obtained from greenhouse films exposed to sunlight at least one year. The surface of the LDPER was treated by gamma beam irradiation that provided formation of free radicals and some functional groups that may contribute to the creation of strong chemical bonds between polymer modifier and bitumen. Five different samples of bitumen/γ-LDPER compositions with the modifier content, wt. %: 1, 3, 5, 7 and 9, were prepared. The effects of the γ-LDPER on original and aged bitumen were investigated by means of morphological, chemical, and physical testing program, including FTIR spectroscopy, conventional tests, rotational viscosity (RV, dynamic shear rheometer (DSR, and bending beam rheometer (BBR tests. Superior performing asphalt pavements (Superpave specifications were used to analyze mechanical test results as well as to determine the performance grades (PG of the binders. Optimum usage of the γ-LDPER as modifier in bitumen were suggested after testing program. The results reveal the stiffening effect of the γ-LDPER on bitumen that provide enhanced temperature susceptibility and also promise better performance grades (PG with γ-LDPER polymer modification.

  14. A Review on the Effect of Crumb Rubber Addition to the Rheology of Crumb Rubber Modified Bitumen

    Directory of Open Access Journals (Sweden)

    Mohd Rasdan Ibrahim

    2013-01-01

    Full Text Available Crumb rubber modification has been proven to enhance the properties of pure bitumen. This paper looks at some of the international standards for producing crumb rubber modified bitumen (CRMB and reviews the effect of crumb rubber to the rheology of crumb rubber modified bitumen. The review shows that the rheology of CRMB depends on internal factors such as crumb rubber quantity, particle size, and pure bitumen composition, and external factors such as the mixing time, temperature, and also the modification technique. These factors govern the swelling process of crumb rubber particles that lead to the increase of viscosity of the modified bitumen. However, the mixing temperature and duration can cause rubber particles to depolymerize and subsequently cause loss of viscosity. Crumb rubber modification also improves the properties of bitumen by increasing the storage and loss modulus and enhancing the high and low temperature susceptibility. The effect of crumb rubber to aging properties of CRMB is also discussed. Finally several techniques of chemical modification to terminal blends of CRMB and the subsequent improvement to the settling property of CRMB are explained.

  15. Paleoenvironmental implications of novel C 30 steranes in Precambrian to Cenozoic Age petroleum and bitumen

    Science.gov (United States)

    McCaffrey, Mark A.; Michael Moldowan, J.; Lipton, Paul A.; Summons, Roger E.; Peters, Kenneth E.; Jeganathan, Alwarsamy; Watt, David S.

    1994-01-01

    Petroleums and bitumens from Early Proterozoic (≈ 1800 Ma) to Miocene (≈ 15 Ma) age marine strata contain 24-isopropylcholestanes, a novel group of C 30 steroids. The abundance of these compounds, relative to 24- n-propylcholestanes, varies with source rock age. Late Proterozoic (Vendian) and Early Cambrian oils and/or bitumens from Siberia, the Urals, Oman, Australia, and India have a high ratio of 24-isopropylcholestanes to 24- n-propylcholestanes (≥1), while younger and older samples have a lower ratio (≤0.4). Temporal changes in this parameter may reflect the relative abundance of certain Porifera (sponges) and certain marine algae through time. Geochemical indicators such as this, which can constrain the source rock age of a migrated oil, are useful in source rock identification during petroleum exploration.

  16. RADIATION CHEMICAL CONVERSION OF OIL DERIVED FROM OIL-BITUMEN ROCK

    Directory of Open Access Journals (Sweden)

    Lala Jabbarova

    2014-06-01

    Full Text Available The results of research in the radiation processing of synthetic oil derived from oil–bitumen rock of the Balakhany deposit in Azerbaijan are presented. The study has been conducted on a 60Co gamma-source at a dose rate of P = 0.5 Gy/s and various absorbed doses of D = 43–216 kGy. Samples of synthetic oil from natural bitumen rocks have been analyzed by chromatography, gas chromatography–mass spectrometry, and IR-spectroscopy, and their radiation resistance has been evaluated. The results of the study allow for both assessment of the feasibility of manufacturing petrochemicals for various applications by radiation processing and use of these materials for isolating radioactive sources to preclude their impact on the environment.

  17. Experimental study of simultaneous Athabasca bitumen recovery and upgrading using ultradispersed catalysts injection

    Energy Technology Data Exchange (ETDEWEB)

    Hashemi, R.; Pereira, P. [University of Calgary (Canada)

    2011-07-01

    As the demand for oil is continuously increasing, the need for unconventional resources is rising. Oil extraction from bitumen and heavy oil reservoirs requires advanced techniques in order to decrease the viscosity of the oil. To increase the recovered original oil in place (OOIP) of a reservoir and decrease refining costs, new techniques to upgrade oil in situ are being developed. The current study investigates the use of ultra-dispersed (UD) submicronic catalysts to decrease oil viscosity. The experiment involved the injection of the catalyst and hydrogen gas in a sand pack saturated with Athabasca bitumen. Analysis was carried out by building recovery curves, and by comparing the oil recovery from the catalyzed process with that of catalyst-free processes. The study demonstrated that the oil recovered from the new technique had higher API gravity and lower viscosity, indicating the success of the in situ upgrading process.

  18. A parametric simulation study for solvent co-injection process in bitumen deposits

    Energy Technology Data Exchange (ETDEWEB)

    Yazdani, A.; Alvestad, J.; Kjonsvik, D.; Gilje, E.; Kowalewski, E. [Statoil Canada (Canada)

    2011-07-01

    The extraction of very large Canadian extra heavy oil and bitumen deposits is facing major challenges, such as energy requirements and access to sustainable water resources. Steam assisted gravity drainage (SAGD) is the most common commercial in-situ recovery process used for the extraction but it has many associated economic and environmental challenges. Moreover, current knowledge of the fundamental physics and mechanics involved in the process is not satisfactory. This paper presents a parametric simulation study for a solvent co-injection (SCI) process in bitumen deposits. This process has the potential to improve the efficiency of steam processes as well as to reduce energy use and CO2 emissions. The study contributes to further understanding of the development process. Several operational and geological parameters were evaluated to assess their impact on SAGD operations. The results demonstrated that the basis for selecting the optimum solvent should not only be mobility improvement capability but should also include other operational and geological conditions.

  19. Electromagnetic Heating of Heavy Oil and Bitumen: A Review of Experimental Studies and Field Applications

    Directory of Open Access Journals (Sweden)

    Albina Mukhametshina

    2013-01-01

    Full Text Available Viscosity is a major obstacle in the recovery of low API gravity oil resources from heavy oil and bitumen reservoirs. While thermal recovery is usually considered the most effective method for lowering viscosity, for some reservoirs introducing heat with commonly implemented thermal methods is not recommended. For these types of reservoirs, electromagnetic heating is the recommended solution. Electromagnetic heating targets part of the reservoir instead of heating the bulk of the reservoir, which means that the targeted area can be heated up more effectively and with lower heat losses than with other thermal methods. Electromagnetic heating is still relatively new and is not widely used as an alternate or addition to traditional thermal recovery methods. However, studies are being conducted and new technologies proposed that could help increase its use. Therefore, the objective of this study is to investigate the recovery of heavy oil and bitumen reservoirs by electromagnetic heating through the review of existing laboratory studies and field trials.

  20. Radiation chemical conversion of oil derived from oil-bitumen rock

    International Nuclear Information System (INIS)

    The results of research in the radiation processing of synthetic oil derived from oil-bitumen rock of the Balakhany deposit in Azerbaijan are presented. The study has been conducted on a 60Co gamma-source at a dose rate of P = 0.5 Gy/s and various absorbed doses of D = 43-216 kGy. Samples of synthetic oil from natural bitumen rocks have been analyzed by chromatography, gas chromatography-mass spectrometry, and IR-spectroscopy, and their radiation resistance has been evaluated. The results of the study allow for both assessment of the feasibility of manufacturing petrochemicals for various applications by radiation processing and use of these materials for isolating radioactive sources to preclude their impact on the environment. (authors)

  1. Unlocking bitumen in thin and/or lower pressure pay using cross SAGD (XSAGD)

    Energy Technology Data Exchange (ETDEWEB)

    Stalder, J.L. [ConocoPhillips Canada Resources Corp., Calgary, AB (Canada)

    2007-07-01

    This paper investigated the effect of rate limits, pay thickness, steam injection pressure, and heterogeneity for steam assisted gravity drainage (SAGD) and cross SAGD (XSAGD) processes. The results of symmetry element model simulations demonstrated that XSAGD offers significant advantages over SAGD in thin and/or low-pressured bitumen sands. By combining both gravity drainage and lateral displacement, XSAGD accelerated recovery, reduced steam requirements, and improved the economic potential of the reservoir when compared to SAGD. XSAGD efficiencies relative to SAGD increased in inverse proportion to pay thickness and injection pressures increases. Optimal accelerated bitumen recovery with lower steam requirement occurred in a homogenous payzone between 10 to 40 m thick with a pressure range of 1500 kPa at 100 m spacing. 3 refs., 1 tab., 8 figs.

  2. Early Maritime Activity on the Dead Sea: Bitumen Harvesting and the Possible Use of Reed Watercraft

    Science.gov (United States)

    Oron, Asaf; Galili, Ehud; Hadas, Gideon; Klein, Micha

    2015-04-01

    Most studies of ancient maritime activity on the Dead Sea focus on the Hellenistic to the Early Byzantine periods, for which a rich body of archaeological and historic data exists. However, finds of Dead Sea bitumen at distant prehistoric sites and an anchor dating to the seventh century BC indicate that maritime activity on the lake preceded the Greek and Roman periods, and raise questions regarding this activity's origins and nature. By linking the exploitation of Dead Sea bitumen with the use of watercraft, and through consideration of a broader early maritime record of the ancient Near East, this study pushes back the dating of this activity on the lake and suggests the nature of its watercraft.

  3. Toxicological assessment of fish (Clarias gariepinus) from bitumen-polluted River Oluwa, Nigeria.

    Science.gov (United States)

    Ayandiran, T A; Dahunsi, S O

    2016-02-01

    Toxicological evaluation of Clarias gariepinus from bitumen-polluted River Oluwa, Nigeria, was carried out in furtherance of studies on the environmental impacts of the bitumen exploration in Ondo State, Nigeria. Samples were taken from three different (two polluted and one as control) sites. The effect of changes in monthly seasonal flow rate was assessed for the sites of study. Blood plasma clinical-chemical parameters (BCCPs) and histological changes/lesions in various organs were evaluated as markers of pollution in the fish blood using standard methods. The result of the physicochemical properties of water from the sampling points revealed some of the values conforming to approved standards while others showed deviation. Significant differences were found in the blood and histological endpoints between the control and the polluted sites as well as between the two seasons evaluated across the sites. The public health implications of consuming this fish are fully discussed. PMID:26725477

  4. Experimental Investigationand Numerical Simulation ofThermal Recovery ProcessesApplicable in AthabascaBitumen Reservoirs

    OpenAIRE

    Souraki, Yaser

    2013-01-01

    Due to reduction of high quality oil resources and consequently increase of oil price around the world, new sources of energy should be found to relief the high demand of energy. Hence, countries like Venezuela, United States and particularly Canada came up with their unconventional reservoirs which contain bitumen, extra heavy oil and heavy oil as remarkable sources of energy. Exploitation of such kind of reservoirs was not beneficial in the past but in recent years due to the increase of oi...

  5. Influence of the bitumen properties on the functional and rheological behaviour of asphalt rubber binders

    OpenAIRE

    Peralta, J.; Silva, Hugo Manuel Ribeiro Dias da; Machado, A.V.; Pais, Jorge C.

    2009-01-01

    It is estimated that about ten kilograms of tires are discarded per inhabitant annually. The negative impact of this residue can be reduced since rubber can be reused as a constituent of asphalt rubber (AR) builder in road pavements. However, the materials which constitute the AR binders and their interaction are not sufficiently characterized, In this work several base bitumens interacted with crumb rubber in order to produce AR binders, which were subsequently separated, by using a modified...

  6. Electromagnetic Heating of Heavy Oil and Bitumen: A Review of Experimental Studies and Field Applications

    OpenAIRE

    Albina Mukhametshina; Elena Martynova

    2013-01-01

    Viscosity is a major obstacle in the recovery of low API gravity oil resources from heavy oil and bitumen reservoirs. While thermal recovery is usually considered the most effective method for lowering viscosity, for some reservoirs introducing heat with commonly implemented thermal methods is not recommended. For these types of reservoirs, electromagnetic heating is the recommended solution. Electromagnetic heating targets part of the reservoir instead of heating the bulk of the reservoir, w...

  7. Quantitative and qualitative analysis of hydrosoluble organic matter in bitumen leachates

    OpenAIRE

    Walczak, Isabelle; Libert, Marie-Françoise; Camaro, Sylvie; Blanchard, Jean-Marie

    2001-01-01

    International audience Bitumen is currently used as an embedding matrix for low and intermediate level radioactive waste disposal in deep sediments. High impermeability and a great resistance to most chemicals are the two main properties sought. Indeed, the generation of water-soluble organic complexing agents could affect the integrity of the wasteform due to an increase of radionuclide solubility. Therefore, the aim of this study is the quantitative and qualitative characterisation of so...

  8. The role of multivalent metal cations and organic complexing agents in bitumen-mineral interactions in aqueous solutions

    Science.gov (United States)

    Gan, Weibing

    A systematic investigation was carried out to study the interactions between bitumen (or hexadecane) and minerals (quartz, kaolinite and illite) in aqueous solutions containing multivalent metal cations Ca2+, Mg2+ and Fe2+/Fe3+, in the absence and presence of organic complexing agents (oxalic acid, EDTA and citric acid). A range of experimental techniques, including coagulation measurement, visualization of bitumen-mineral attachment, metal ion adsorption measurement, zeta potential measurement, Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopic analyses, were employed in the investigation. Free energy changes of adsorption of metal cations on the minerals and bitumen were evaluated using the James & Healy thermodynamic model. Total interaction energies between the minerals and bitumen were calculated using classical DLVO theory. It was observed that while the tested minerals showed varying degrees of mutual-coagulation with bitumen (or hexadecane), the presence of the multivalent metal cations could prominently increase the mutual coagulation. It was also found that such enhancement of the mutual coagulation was only significant when the metal cations formed first-order hydroxyl complexes (such as CaOH +, MgOH+, etc.) or metal hydroxides (such as Fe(OH) 3, Mg(OH)2, etc.). Therefore, the increase of the bitumen-mineral mutual coagulation by the metal cations was strongly pH dependent. Organic complexing agents (oxalic acid, citric acid and EDTA) used in this study, citric acid in particular, significantly reduced or virtually eliminated the mutual coagulation between bitumen (or hexadecane) and minerals caused by metal cations Ca2+, Mg2+, Fe 2+ and Fe3+. Due to its ability to substantially lower the mutual coagulation between bitumen and mineral particles, citric acid was found the most effective in improving bitumen-mineral liberation in solutions containing the multivalent metal cations at pH 8--10. In small scale flotation experiments

  9. Electromagnetic heating for in-situ production of heavy oil and bitumen reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Wacker, Bernd; Karmeileopardus, Denny; Trautmann, Bernd; Helget, Andreas; Torlak, Muris [Siemens AG (Canada)

    2011-07-01

    This paper presents the electro-magnetic (EM) heating process for in-situ production of heavy oil and bitumen reservoirs. The method aims at heavy oil and in-situ bitumen production in an environmentally friendly way that minimizes the surface footprint. The objective is to reduce the viscosity of heavy oil or bitumen by a rise in temperature and enable displacement and transport towards the producer. The paper outlines and documents the step-by-step approach which must follow the technology analysis laid out in a government white paper on commissioning and field testing. A simulation example on the reservoir is also provided for in-situ production with EM heating. The paper also describes different electrical heating techniques, feasibility studies and simulation of inductive heating methods, the process of implementation and the benefits of EM heating. The study shows that the new technology is promising and also has other advantages which include cost effectiveness, energy efficiency, and a minimal environmental footprint.

  10. Physico-chemical interactions at the concrete-bitumen interface of nuclear waste repositories

    International Nuclear Information System (INIS)

    This study investigates the fate of nitrate and organic acids at the bitumen concrete-steel interface within a repository storage cell for long-lived, intermediate level, radioactive wastes. The interface was simulated by a multiphase system in which cementitious matrices (CEM V-paste specimens) were exposed to bitumen model leachates consisting of nitrates and acetic acid with and without oxalic acid, chemical compounds likely to be released by bitumen. Leaching experiments were conducted with daily renewal of the solutions in order to accelerate reactions. C-steel chips, simulating the presence of steel in the repository, were added in the systems for some experiments. The concentrations of anions (acetate, oxalate, nitrate, and nitrite) and cations (calcium, potassium, ammonium) and the pH were monitored over time. Mineralogical changes of the cementitious matrices were analysed by XRD. The results confirmed the stability of nitrates in the absence of steel, whereas, reduction of nitrates was observed in the presence of steel (production of NH4+). The action of acetic acid on the cementitious matrix was similar to that of ordinary leaching; no specific interaction was detected between acetate and cementitious cations. The reaction of oxalic acid with the cementitious phases led to the precipitation of calcium oxalate salts in the outer layer of the matrix. The concentration of oxalate was reduced by 65% inside the leaching medium. (authors)

  11. Management of the basal McMurray watersand during bitumen and heavy oil extraction

    Energy Technology Data Exchange (ETDEWEB)

    Baxter, K.C. [CH2M Hill Canada Ltd., Calgary, AB (Canada)

    2002-07-01

    The risks associated with basal aquifers in steam-assisted gravity drainage (SAGD) recovery of heavy oils were discussed. Bitumen distribution within the McMurray Formation varies with facies changes in the deposit. The coarse-grained sand at the base of the formation forms a basal aquifer where the bitumen content is low and where pore pressures are high. The confined aquifer is very permeable which poses a major management issue for both open bit bitumen extraction and in situ heavy oil production. This is because the basal aquifer often requires depressurization, particularly in open pit mining because the high pore pressure can reduce pit wall stability. In addition, seepage to the pit floor can reduce the rate of traffic flow. Oilsand and basal aquifers, which provide the foundation for tailings ponds, can potentially form a groundwater flow path for pond seepage. One way to remedy this situation is to develop a strategy for wastewater injection into the basal aquifer, but before this is done certain issues must be addressed, including the effects of pressure interference, fracture initiation and related seepage. Other issues that must be addressed include the affect of increased discharge of poor quality insitu water into the Athabasca River.

  12. Use of high resolution images of orbital surface of waterproofing with different levels of urban land: case Irati-PR

    Directory of Open Access Journals (Sweden)

    Paulo Costa de Oliveira Filho

    2012-11-01

    Full Text Available The objective of this research was to present a detailed diagnosis for use and occupation of urban land aimed at different levels of sealing, in a downtownIrati area of 14 blocks, totaling 0.23 km2, from the Quickbird satellite images with spatial resolution of 0.60 m, by the method of interpretation and vectorization on the screen followed by classification. The area occupied by the classes that represent the highest level of waterproof is 33,218% of the total study area, since the area occupied by classes representing less impermeable level is 22,488% of the same area. The results show that the study area is well sealed.

  13. Preparation of waterproof OSL dosimeters from hygroscopic materials with a special reference to NaCl:Cu

    Science.gov (United States)

    More, Y. K.; Wankhede, S. P.; Patil, R. R.; Kulkarni, M. S.; Kumar, Munish; Moharil, S. V.

    2016-05-01

    Optically stimulated luminescence (OSL) originally developed for geological/archaeological dating, has been found very useful for diverse applications in the field of radiation dosimetry. There is still a scarcity of OSL materials with demonstrated properties suited to dosimetry applications. Progress on the development of OSL materials with engineered properties has been slow and most research has focused on the OSL characterization of existing materials. One of the reasons for availability of only a handful of OSL dosimetry materials with adequate properties is that they have to satisfy certain stringent conditions necessary for such applications. Especially, hygroscopic materials are considered totally unsuitable. The efforts were made in our laboratory to overcome this problem. It is shown here that "water-proof" dosimeters can be prepared from even hygroscopic materials such as NaCl.

  14. Stretchable and Waterproof Self-Charging Power System for Harvesting Energy from Diverse Deformation and Powering Wearable Electronics.

    Science.gov (United States)

    Yi, Fang; Wang, Jie; Wang, Xiaofeng; Niu, Simiao; Li, Shengming; Liao, Qingliang; Xu, Youlong; You, Zheng; Zhang, Yue; Wang, Zhong Lin

    2016-07-26

    A soft, stretchable, and fully enclosed self-charging power system is developed by seamlessly combining a stretchable triboelectric nanogenerator with stretchable supercapacitors, which can be subject to and harvest energy from almost all kinds of large-degree deformation due to its fully soft structure. The power system is washable and waterproof owing to its fully enclosed structure and hydrophobic property of its exterior surface. The power system can be worn on the human body to effectively scavenge energy from various kinds of human motion, and it is demonstrated that the wearable power source is able to drive an electronic watch. This work provides a feasible approach to design stretchable, wearable power sources and electronics. PMID:27351212

  15. BREATHING SHOES AND COMPLEMENTARITIES: STRATEGIC INNOVATION IN A MATURE INDUSTRY

    OpenAIRE

    ARNALDO CAMUFFO; ANDREA FURLAN; PIETRO ROMANO; ANDREA VINELLI

    2008-01-01

    This paper tells the story of Geox, an Italian footwear manufacturer that, in less than a decade, has become one of the world's largest shoe manufacturers. Applying the related notions of complementarity and performance landscape to study strategic positioning in the footwear industry, we show that, though grounded on product innovation (the original Geox breathes® patented system which allows ventilation in waterproof rubber sole), Geox's competitive advantage has not grown out of operationa...

  16. Techno-economic assessment of hydrogen production from underground coal gasification (UCG) in Western Canada with carbon capture and sequestration (CCS) for upgrading bitumen from oil sands

    International Nuclear Information System (INIS)

    Highlights: • Development of a techno-economic model for UCG-CCS and SMR-CCS. • Estimation of H2 production costs with and without CCS for UCG and SMR. • UCG is more economical for H2 production with CCS. • SMR is more cost efficient for H2 production without CCS. • Cost competiveness is highly sensitive to the IRR differential between UCG and SMR. - Abstract: This paper examines the techno-economic viability of hydrogen production from underground coal gasification (UCG) in Western Canada, for the servicing of the oil sands bitumen upgrading industry. Hydrogen production for bitumen upgrading is predominantly achieved via steam methane reforming (SMR); which involves significant greenhouse gas (GHG) emissions along with considerable feedstock (natural gas) cost volatility. UCG is a formidable candidate for cost-competitive environmentally sustainable hydrogen production; given its negligible feedstock cost, the enormity of deep coal reserves in Western Canada and the favourable CO2 sequestration characteristics of potential UCG sites in the Western Canadian sedimentary basin (WCSB). Techno-economic models were developed for UCG and SMR with and without CCS, to estimate the cost of hydrogen production including delivery to a bitumen upgrader. In this paper, at base case conditions, a 5% internal rate of return (IRR) differential between UCG and SMR was considered so as to account for the increased investment risk associated with UCG. The cost of UCG hydrogen production without CCS is estimated to be $1.78/kg of H2. With CCS, this increases to range of $2.11–$2.70/kg of H2, depending on the distance of the site for CO2 sequestration from the UCG plant. The SMR hydrogen production cost without CCS is estimated to be $1.73/kg of H2. In similar fashion to UCG, this rises to a range of $2.14 to $2.41/kg of H2 with the consideration of CCS. Lastly, for hydrogen production without CCS, UCG has a superior cost competitiveness in comparison to SMR for an IRR

  17. Installation of a bitumen coating plant for high-activity concentrates; Installation pilote d'enrobage par le bitume de concentrats de haute activite

    Energy Technology Data Exchange (ETDEWEB)

    Rodier, J.; Lefillatre, G.; Seyfried, P. [Commissariat a l' Energie Atomique, Chusclan (France). Centre de Production de Plutonium de Marcoule

    1969-07-01

    Following the excellent results obtained on the industrial coating of radioactive sludges, the possibility of solidifying also the evaporation concentrates with bitumen has been considered. For high activity concentrates, the use of bitumen is however limited by two main parameters: temperature resistance, irradiation resistance. By making use of the characteristics of a blown bitumen, it has been possible to design a high activity coating pilot plant treating concentrations of several tens of curies per litre. This plant will make use of a screw-type extrusion machine capable of coating treated concentrates at a rate of 20 l/hr. Before being coated, the concentrates will be subjected to a coprecipitation treatment designed to make the radioelements insoluble. This installation will make possible, apart from technological studies, laboratory experiments on the coated material (measurements on self-heating, on electrical charges, on radiolytic gases, and also lixiviation tests. It is at present believed, on the basis of available data, that it is possible to coat concentrates having an activity of 20 Ci/l at a price of 1840 F per cubic metre. (authors) [French] A la suite des excellents resultats obtenus pour l'enrobage industriel des boues radioactives, il a ete envisage de solidifier egalement les concentrats d'evaporation par le bitume. Pour les concentrats de haute activite, l'emploi du bitume est cependant limite par deux parametres essentiels: tenue a la temperature, tenue a l'irradiation. Grace aux caracteristiques d'un bitume souffle, il a ete possible de concevoir une installation pilote d'enrobage haute activite contenant plusieurs dizaines de curies par litre. Cette installation utilisera une machine du type extrudeuse a vis qui peut enrober 20 l/h de concentrats traites. Avant leur enrobage, les concentrats subiront un traitement de coprecipitation destine a insolubiliser les radioelements. En dehors des etudes

  18. Pilot plant studies for a new hot water process for extraction of bitumen from Utah tar sands

    Energy Technology Data Exchange (ETDEWEB)

    Dahlstrom, D.A.

    1996-12-31

    A process development pilot plant for extracting bitumen from tar sands under arid conditions are described. The hot water recovery process under development is required to maximize heat and water recovery, recover more than 90% of the bitumen, minimize the operating cost, and eliminate the use of a tailings pond by increasing the effectiveness of solids separation and dewatering. Technical aspects of process flow conditions, the liquid cyclone separator under development, and testing to analyze the influence of flow rates, size distribution in discharge streams, amount of bitumen recovery from different streams, and air addition are summarized. Test results indicate that bitumen recovery should be at least 90%, water content from thickener underflow and dewater coarse solids averages about 30 weight percent moisture, and the forced vortex cyclone can produce an underflow solids concentration of 69 to 72 weight percent moisture. The proposed flow sheet is believed to be a very low-cost method for bitumen recovery. 5 refs., 3 figs., 2 tabs.

  19. Determination of organic products resulting of chemical and radiochemical decompositions of bitumen. Applications to embedded bitumens; Determination des produits organiques d'alterations chimiques et radiochimiques du bitume. Applications aux enrobes bitumes

    Energy Technology Data Exchange (ETDEWEB)

    Walczak, I

    2000-01-27

    Bitumen can be used for embedding most of wastes because of its high impermeability and its relatively low reactivity with of chemicals. Bituminization is one of selected solutions in agreement with nuclear safety, waste compatibility and economic criteria. Bitumen, during storage, undergoes an auto-irradiation due to embedded radio-elements. During this stage,drums are not airtight then oxygen is present. In disposal configuration, water, which is a potential vector of radioactivity and organic matter, is an other hazard factor liable to deteriorate the containment characteristics of bitumen wastes. The generation of water-soluble organic complexing agents can affect the integrity of the wasteform due to an increase of the radionuclides solubility. The first aim of this work is the quantitative and qualitative characterisation of soluble organic matter in bitumen leachates. Different leaching solutions were tested (various pH, ionic strength, ratio S/V). When the pH of the leaching solutions increases, the total organic carbon released increases as well. Identified molecules are aromatics like naphthalene, oxidised compounds like alcohols, linear carbonyls, aromatics, glycols and nitrogen compounds. For the cement equilibrated solution (pH 13.5), the effect of ionic strength becomes significative and influences the release of soluble organic matter. This soluble organic matter can be bio-degraded if microorganisms can growth. The second aim of this work is to study the effect of radio-oxidative ageing on the bitumen confinement properties. During radio-oxidation, the chemical properties of bitumen are modified. The {mu}-IRTF analysis shows the formation of hydroxyl compounds and aromatic acids. The formation of these polar groups does not influence in our study the water uptake. However the organic matter release increases significantly with the irradiation dose. (author)

  20. Biogeochemical modelling of the Mont Terri in situ bitumen-nitrate-clay interaction experiment

    International Nuclear Information System (INIS)

    Document available in extended abstract form only. The Bitumen-Nitrate-Clay Interaction experiment (BN) currently being performed at the Mont Terri Rock Laboratory (Switzerland) provides an in situ examination of redox reactions expected between nitrate containing wastes and mineral and organic electron donors present in clay host rocks and as degradation products of organic wastes. The BN experiment has been designed to examine the fate of nitrate that is present in the form of soluble salts within a bitumen matrix; they are part of intermediate-level long-lived radioactive waste (ILW) manufactured in France and Belgium and planned for disposal in deep geological clay formations. The nitrate component of this bituminized waste form, as well as that present in other ILW, has the potential to affect the chemical conditions and the speciation and transport behaviour of redox sensitive radionuclides (e.g. Se, Tc, U, Np, Pu) in the near field and in host rocks with initially reducing conditions. A sequence of tests undertaken in the BN experiment will examine the reactions of nitrate with the Opalinus Clay together with acetate as a reference bitumen degradation product. The BN experiment includes comprehensive chemical and microbial characterisation of samples recovered during the nitrate injection tests that record the phases of microbial denitrification and other biogeochemical processes. As such the BN experiment provides an insight into the potential biogeochemical processes that may occur in the excavation and chemically disturbed zones (EDZ/CDZ) of a deep geological repository. In this paper the results of the BN experiment are modelled using the Generalised Repository Model (GRM) originally developed in the UK to examine biogeochemical processes occurring in cellulose containing low-level waste disposed in a near surface facility. The GRM simulation of the BN experiment provides further interpretation of the BN data. In addition, the study is aimed at building

  1. Application of thermodynamics to the estimation of the biodegradation of bitumen wastes package underground stored

    International Nuclear Information System (INIS)

    A modelling approach to evaluate microbial activity in a geological system is adopted. It focusses upon the availability of key nutrients (C, H, O, N, P, S) and energy sources required for bacterial growth. The model is applied to determine the possible consequences of such microbiological activity in the presence of bitumen embedded waste in a repository for low - and intermediate - level waste. Taking into account this particular environment, thermodynamic and experimental results are given in terms of gas and organic complexant production. (authors)

  2. Gas chromatograph study of bitumen from oil shale of Amman Formation (upper cretaceous), NW Jordan

    International Nuclear Information System (INIS)

    The extractable organic matter of seven outcrop samples of Amman Formation Oil Shale have been analysed by Gas Chromatography (GC). The bitumen is rich in heterocompounds contents (> 60 wt%). Gas chromatograms show a predominance of iosprenoids, specially phytane over n-alkanes, and low carbon preference index (CPI). This indicates that the organic matter is immature, and its origin is mainly of marine organisms. These rocks could be possible source rocks due to the high content of hydrocarbon. (authors). 22 refs., 4 figs. 3 tabs

  3. Effect of waste plastic as modifier on thermal stability and degradation kinetics of bitumen/waste plastics blend

    International Nuclear Information System (INIS)

    Different modified bituminous binders are used in pavement construction for improved durability and for enhanced performance in resisting cracking and permanent deformation of bituminous layers. Waste plastics, whose disposal is a matter of concern, have been used successfully for modifying bitumen. This paper reports the thermogravimetric studies conducted on waste plastic modified bituminous binders. Modified bituminous binders prepared using different plastic contents (0-7 wt% by weight of bitumen) were investigated. The activation energies were determined from thermogravimetric analysis (TGA) data using Kissinger and the Flynn-Wall-Ozawa methods, which do not require knowledge of the reaction mechanism. Modified bitumen (WPMB5) with 5 wt% plastic was found to have the highest thermal stability compared to other binders investigated. Differential scanning calorimetry (DSC) studies were carried out to find crystalline melting temperature and fusion enthalpy. Rheological parameters of modified binders prepared with different plastic contents also suggest that the 5 wt% plastic content is expected to yield optimal performance.

  4. Upstream petroleum industry flaring and venting report : industry performance for year ending December 31, 2001

    International Nuclear Information System (INIS)

    Solution gas, gas from oil and bitumen batteries, is the largest source of flaring and venting in Alberta. A summary of solution gas conserved, flared and vented in Alberta during the year ending December 31, 2001 was presented along with flared volumes for the various oil and gas industry sectors such as gas plants, gas gathering systems, well tests and oil, bitumen and gas batteries. The report identifies the sources of flaring and venting in Alberta and monitors the progress the industry has made in reducing the volume of solution gas flared since 1996. Operators were ranked provincially, as well as within each field centre of the Alberta Energy and Utilities Board, based on solution gas flared, vented, total solution gas produced, and total oil from crude oil and bitumen batteries. The report demonstrates the significant progress industry has made towards reducing solution flare gas and vent volumes in the province. In 2001, the industry decreased overall flared and vented volumes by 16 per cent compared to year 2000 from all sources. Two new tables in this year's report indicate the top 25 solution gas producers in Alberta and the top 25 companies venting solution gas. The table provides information regarding each company's conservation performance and production volumes as a percentage of the provincial total

  5. Design of waterproof high performance concrete mix%浅谈地铁防水高性能混凝土配合比设计

    Institute of Scientific and Technical Information of China (English)

    况钟

    2012-01-01

    In this paper, based on the construction of BaiHuting Station of FuZhou subway NO. 1 Line project, optimal design Of waterproof high performance concrete mix was discussed.%本文结合在建福州地铁1号线白湖亭站工程实际,浅谈地铁防水高性能混凝土配合比优化设计。

  6. Quantitative temperature-depending mapping of mechanical properties of bitumen at the nanoscale using the AFM operated with PeakForce TappingTM mode

    NARCIS (Netherlands)

    Fischer, H.R.; Stadler, H.; Erina, N.

    2013-01-01

    The mechanical properties of bitumen, such as elasticity/Young's modulus, stickiness/adhesion, hardness and energy loss, and sample deformation were acquired quantitatively and simultaneously with the topology at the microscale, discriminating clearly two separate phases within the bitumen. Temperat

  7. Ecotoxicological impacts of effluents generated by oil sands bitumen extraction and oil sands lixiviation on Pseudokirchneriella subcapitata

    Energy Technology Data Exchange (ETDEWEB)

    Debenest, T., E-mail: tdebenest@yahoo.fr [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada); Turcotte, P. [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada); Gagne, F., E-mail: francois.gagne@ec.gc.ca [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada); Gagnon, C.; Blaise, C. [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada)

    2012-05-15

    The exploitation of Athabasca oil sands deposits in northern Alberta has known an intense development in recent years. This development has raised concern about the ecotoxicological risk of such industrial activities adjacent to the Athabasca River. Indeed, bitumen extraction generated large amounts of oil sands process-affected water (OSPW) which are discharged in tailing ponds in the Athabasca River watershed. This study sought to evaluate and compare the toxicity of OSPW and oil sands lixiviate water (OSLW) with a baseline (oil sands exposed to water; OSW) on a microalgae, Pseudokirchneriella subcapitata, at different concentrations (1.9, 5.5, 12.25, 25 and 37.5%, v/v). Chemical analyses of water-soluble contaminants showed that OSPW and OSLW were enriched in different elements such as vanadium (enrichment factor, EF = 66 and 12, respectively), aluminum (EF = 64 and 15, respectively), iron (EF = 52.5 and 17.1, respectively) and chromium (39 and 10, respectively). The toxicity of OSPW on cells with optimal intracellular esterase activity and chlorophyll autofluorescence (viable cells) (72 h-IC 50% < 1.9%) was 20 times higher than the one of OSW (72 h-IC 50% > 37.5%, v/v). OSLW was 4.4 times less toxic (IC 50% = 8.5%, v/v) than OSPW and 4.5 times more toxic than OSW. The inhibition of viable cell growth was significantly and highly correlated (<-0.7) with the increase of arsenic, beryllium, chromium, copper, lead, molybdenum and vanadium concentrations. The specific photosynthetic responses studied with JIP-test (rapid and polyphasic chlorophyll a fluorescence emission) showed a stimulation of the different functional parameters (efficiency of PSII to absorb energy from photons, size of effective PSII antenna and vitality of photosynthetic apparatus for energy conversion) in cultures exposed to OSPW and OSLW. To our knowledge, our study highlights the first evidence of physiological effects of OSPW and OSLW on microalgae.

  8. Ecotoxicological impacts of effluents generated by oil sands bitumen extraction and oil sands lixiviation on Pseudokirchneriella subcapitata

    International Nuclear Information System (INIS)

    The exploitation of Athabasca oil sands deposits in northern Alberta has known an intense development in recent years. This development has raised concern about the ecotoxicological risk of such industrial activities adjacent to the Athabasca River. Indeed, bitumen extraction generated large amounts of oil sands process-affected water (OSPW) which are discharged in tailing ponds in the Athabasca River watershed. This study sought to evaluate and compare the toxicity of OSPW and oil sands lixiviate water (OSLW) with a baseline (oil sands exposed to water; OSW) on a microalgae, Pseudokirchneriella subcapitata, at different concentrations (1.9, 5.5, 12.25, 25 and 37.5%, v/v). Chemical analyses of water-soluble contaminants showed that OSPW and OSLW were enriched in different elements such as vanadium (enrichment factor, EF = 66 and 12, respectively), aluminum (EF = 64 and 15, respectively), iron (EF = 52.5 and 17.1, respectively) and chromium (39 and 10, respectively). The toxicity of OSPW on cells with optimal intracellular esterase activity and chlorophyll autofluorescence (viable cells) (72 h-IC 50% 37.5%, v/v). OSLW was 4.4 times less toxic (IC 50% = 8.5%, v/v) than OSPW and 4.5 times more toxic than OSW. The inhibition of viable cell growth was significantly and highly correlated (<−0.7) with the increase of arsenic, beryllium, chromium, copper, lead, molybdenum and vanadium concentrations. The specific photosynthetic responses studied with JIP-test (rapid and polyphasic chlorophyll a fluorescence emission) showed a stimulation of the different functional parameters (efficiency of PSII to absorb energy from photons, size of effective PSII antenna and vitality of photosynthetic apparatus for energy conversion) in cultures exposed to OSPW and OSLW. To our knowledge, our study highlights the first evidence of physiological effects of OSPW and OSLW on microalgae.

  9. 新型环保型防水涂料的改性研究进展%Research Progress in Modification of Environment Friendly Waterproof Coatings

    Institute of Scientific and Technical Information of China (English)

    窦国庆; 吕兆萍; 刘道辉; 王瑞海; 边伟强

    2012-01-01

    Three kinds of modification methods for waterproof coatings are introduced. The reaction mechanism and performance change of acry-late waterproof coating, water-bome polyurethane and polyurea after modification are described in detail. After modification by using epoxy resin and organic silicon, the tensile strength, elongation at break and adhesion are improved obviously, but the water absorption decreased. The development trend of polyurea waterproof coating is also discussed.%综述了三种防水涂料的改性方法.重点介绍了丙烯酸酯类乳液防水涂料,水性聚氨酯和聚脲的反应机理及改性后材料的性能变化,用环氧树脂和有机硅等对其改性后,提高了防水涂料的拉伸强度,断裂伸长率和附着力,降低了吸水率.探讨了聚脲防水涂料的发展方向.

  10. The most appropriate mixing method of polypropylene fiber with aggregates and bitumen based on binder mix design

    Directory of Open Access Journals (Sweden)

    Mohsen Zahedi

    2014-06-01

    Full Text Available Asphalt is used in road pavements as the binder of aggregates in a great extent all around the world. Asphalt Modifiers have used in pavement engineering in order to enhance the physical and mechanical properties of asphalt mixtures. One of the most important of them is Polypropylene Fiber that causes increasing stability in the mixture. In this article usage of this fiber in civil engineering and especially in asphalt mixtures is investigated; Mixing methods of fiber with aggregates and bitumen are dry, wet and complex are investigated and the most appropriate method because of homogenous mixing and better result is introduced. Keywords: Polypropylene Fiber, Mixing, Bitumen, Aggregates, Binder.

  11. Changes in composition of sapropelic organic acid A and S bitumens from Lake Lakheper in relation to depth of origin

    Energy Technology Data Exchange (ETDEWEB)

    Bondar' , Ye.; Palu, V.; Veski, R.

    1982-01-01

    Test results are presented for acid bitumens (from A and S sapropelic post-glacier lake (Lakheper) in Estonian SSR). Using liquid gas chromatography and chromato-mass spectrometry normally saturated and unsaturated monocarbonic acids were determined (figures provided), as well as iso- and antiiso-monocarbonic acids, oxycarbonic, and cyclopropane acids (formulas provided). Analysis of derived data makes it possible to assume that changes in bitumen acids at early stages of diagenesis of the sapropelic mud is determined not only by diagenesis itself, but by changes in conditions under which sedimentation occurred.

  12. Physico-chemical interactions at the concrete-bitumen interface of nuclear waste repositories

    Science.gov (United States)

    Bertron, A.; Ranaivomanana, H.; Jacquemet, N.; Erable, B.; Sablayrolles, C.; Escadeillas, G.; Albrecht, A.

    2013-07-01

    This study investigates the fate of nitrate and organic acids at the bitumenconcrete-steel interface within a repository storage cell for long-lived, intermediatelevel, radioactive wastes. The interface was simulated by a multiphase system in which cementitious matrices (CEM V-paste specimens) were exposed to bitumen model leachates consisting of nitrates and acetic acid with and without oxalic acid, chemical compounds likely to be released by bitumen. Leaching experiments were conducted with daily renewal of the solutions in order to accelerate reactions. C-steel chips, simulating the presence of steel in the repository, were added in the systems for some experiments. The concentrations of anions (acetate, oxalate, nitrate, and nitrite) and cations (calcium, potassium, ammonium) and the pH were monitored over time. Mineralogical changes of the cementitious matrices were analysed by XRD. The results confirmed the stability of nitrates in the absence of steel, whereas, reduction of nitrates was observed in the presence of steel (production of NH4+). The action of acetic acid on the cementitious matrix was similar to that of ordinary leaching; no specific interaction was detected between acetate and cementitious cations. The reaction of oxalic acid with the cementitious phases led to the precipitation of calcium oxalate salts in the outer layer of the matrix. The concentration of oxalate was reduced by 65% inside the leaching medium.

  13. Physico-chemical interactions at the concrete-bitumen interface of nuclear waste repositories

    Directory of Open Access Journals (Sweden)

    Sablayrolles C.

    2013-07-01

    Full Text Available This study investigates the fate of nitrate and organic acids at the bitumenconcrete-steel interface within a repository storage cell for long-lived, intermediatelevel, radioactive wastes. The interface was simulated by a multiphase system in which cementitious matrices (CEM V-paste specimens were exposed to bitumen model leachates consisting of nitrates and acetic acid with and without oxalic acid, chemical compounds likely to be released by bitumen. Leaching experiments were conducted with daily renewal of the solutions in order to accelerate reactions. C-steel chips, simulating the presence of steel in the repository, were added in the systems for some experiments. The concentrations of anions (acetate, oxalate, nitrate, and nitrite and cations (calcium, potassium, ammonium and the pH were monitored over time. Mineralogical changes of the cementitious matrices were analysed by XRD. The results confirmed the stability of nitrates in the absence of steel, whereas, reduction of nitrates was observed in the presence of steel (production of NH4+. The action of acetic acid on the cementitious matrix was similar to that of ordinary leaching; no specific interaction was detected between acetate and cementitious cations. The reaction of oxalic acid with the cementitious phases led to the precipitation of calcium oxalate salts in the outer layer of the matrix. The concentration of oxalate was reduced by 65% inside the leaching medium.

  14. Integral migration and source-term experiments on cement and bitumen waste forms

    International Nuclear Information System (INIS)

    This is the final report of a programme of research which formed a part of the CEC joint research project into radionuclide migration in the geosphere (MIRAGE). This study addressed the aspects of integral migration and source term. The integral migration experiment simulated, in the laboratory, the intrusion of water into the repository, the leaching of radionuclides from two intermediate-level waste-forms and the subsequent migration through the geosphere. The simulation consisted of a source of natural ground water which flowed over a sample of waste-form, at a controlled redox potential, and then through backfill and geological material packed in columns. The two waste forms used here were cemented waste from the WAK plant at Karlsruhe in the Federal Republic of Germany and bitumenized intermediate concentrates from the Marcoule plant in France. The soluble fission products such as caesium were rapidly released from the cemented waste but the actinides, and technetium in the reduced state, were retained in the waste-form. The released of all nuclides from the bitumenized waste was very low

  15. Hydrocarbon-bearing fluid inclusions in fluorite associated with the Windy Knoll bitumen deposit, UK

    Science.gov (United States)

    Moser, M. R.; Rankin, A. H.; Milledge, H. J.

    1992-01-01

    Hydrocarbon-bearing fluid inclusions in fluorite, associated with an outcropping bitumen deposit at Windy Knoll, Derbyshire, have been analysed in situ using a combination of microthermometry, Fourier transform infrared (FTIR) microspectrometry, and ultraviolet (UV) microscopy. The inclusions in these samples can be considered as a series with two endmembers: aqueous inclusions containing a low-density vapour phase and inclusions containing liquid "oil" with no detectable aqueous phase. The majority of the inclusions are mixed types containing both aqueous and liquid hydrocarbon phases. Although microthermometry distinguishes at least two different aqueous fluids with varying homogenization temperatures and salinities, the oil fraction is cogenetic and trapped together with just one fluid, a low-salinity, low-calcium brine with an average homogenization temperature of 134°C. The majority of the liquid hydrocarbon-bearing inclusions fluoresce bright blue under UV illumination with peaks around 475 nm, characteristic of paraffinic oils. The FTIR spectra of these inclusions are dominated by peaks assigned to aliphatic C - H bonding. However, inclusions have also been found which display a fluorescence typical of the red-shift associated with less mature oils. The FTIR spectra display peaks assigned to CO, C - O, and O - CH 2 bonding. This study presents new data on the in-situ analysis of hydrocarbon-bearing fluid inclusions from this important area of natural petroleum seepage and ore mineralization. The results suggest a direct link between the fluid inclusion populations, the outcropping bitumens, and fluorite deposition.

  16. Breaking through the bitumen upgrading barriers with the UOP Uniflex Process

    Energy Technology Data Exchange (ETDEWEB)

    Gillis, D. [UOP LLC, Des Plaines, IL (United States)

    2009-07-01

    High costs and environmental concerns are some of the challenges facing bitumen upgrading. In addition, yields from conventional process such as coking and ebullated bed hydrocracking are much lower than desired. As such, there is a need for processes that can maximize conversion and selectively produce transportation boiling range products, particularly distillates. There are both technical and financial challenges in providing a reliable high-conversion technology. UOP has developed the UOP Uniflex Process, a commercially based high-conversion residue upgrading process that selectively converts residues from conventional crude oils and bitumen to transportation fuels and high quality synthetic crude oil. The unique features of this technology were described along with commercialization background. Recent advances being developed by UOP under the AERI Hydrocarbon Upgrading Demonstration Program were also described, with particular reference to catalyst design, engineering design and residue by-product utilization. This presentation also outlined UOP's latest flow scheme options for use with existing upgrading technologies. tabs., figs.

  17. A New Method of Detecting Leaks in Reservoirs or Canals Using Labelled Bitumen Emulsions

    International Nuclear Information System (INIS)

    The paper describes a method of detecting and localizing leaks in natural or artificial stored-water bodies such as lakes, canals, basins, reservoirs or wells. The method consists of injecting into the stored water an emulsion labelled with a radioactive tracer. The labelled emulsion is entrained into the leakage areas where emulsion particles separate from the water and accumulate. The distribution of these particles, which can be considered as proportional to the specific infiltration flow for structures with interstitial permeability, is then determined ''in situ'' simply by measuring the radioactivity. Where the labelled emulsion is an emulsion of bitumen, the plastic properties of this product are useful in promoting the agglomeration of the particles and their adhesion to the materials of the revetment or wall to be studied. The paper describes the preparation of an emulsion of bitumen labelled with iodine-131 and its application in determining permeability gradients and detecting leaks in canal revetments. It is pointed out in conclusion that this original method has a vast range of applications. It can, for example, be successfully used to study the relative permeabilities of strata in which wells, pits or boreholes have been drilled, and to distinguish between areas of varying permeabilities. (author)

  18. Fire test on a storage container filled with sodium nitrate-bitumen

    International Nuclear Information System (INIS)

    When using combustible material e.g. bitumen, in the solidification of radioactive wastes from processing burnt fuel rods of nuclear power plants, the question always arises: What happens if this hardening material catches fire. The authors put this question to the test by filling a 100 l barrel of sheet steel with a test mixture (bitumen with 52% NaNO3) and placing the barrel in a larger sheet steel barrel (200 l) and filling the intermediate space with sand as well as covering the test barrel by approx. 15 cm. 74 l petrol are poured into this sand and ignited. Result: The barrel does not become noticeably warm at any position. If one assumes that such barrels are not piled ontop of one another and there is a good air supply, as well as - as the authors propose - the space between the barrels is filled, one can exclude any considerable damage, even if e.g. hydrogen should ignite. Should there be no ventilation (closed cavity in rock), then the fire will in any case extinguish when the available oxygen is consumed, there will be no damage in this case either. (orig./RB)

  19. A new method of detecting leaks in reservoirs or canals using labelled bitumen emulsions

    International Nuclear Information System (INIS)

    The paper describes a method of detecting and localizing leaks in natural or artificial stored-water bodies such as lakes, canals, basins, reservoirs or wells. The method consists of injecting into the stored water an emulsion labelled with a radioactive tracer. The labelled emulsion is entrained into the leakage areas where emulsion particles separate from the water and accumulate. The distribution of these particles, which can be considered as proportional to the specific infiltration flow for structures with interstitial permeability, is then determined 'in situ' simply by measuring the radioactivity. Where the labelled emulsion is an emulsion of bitumen, the plastic properties of this product are useful in promoting the agglomeration of the particles and their adhesion to the materials of the revetment or wall to be studied. The paper describes the preparation of an emulsion of bitumen labelled with iodine-131 and its application in determining permeability gradients and detecting leaks in canal revetments. It is pointed out in conclusion that this original method has a vast range of applications. It can, for example, be successfully used to study the relative permeabilities of strata in which wells, pits or boreholes have been drilled, and to distinguish between areas of varying permeabilities. (author)

  20. Bitumen Applicator

    OpenAIRE

    Pettersson, Daniel; Lejdeby, Mikael; Zarate, Inigo Oz. de; Delamarliere, Mathieu

    2002-01-01

    This bachelor degree thesis was assigned to us in the fall semester of 2001. The purpose was to redesign a machine for the company Asea Brown Boveri (ABB) in Karlskrona. ABB HVC in Karlskrona is manufacturing high voltage cables. Amongst these the seacables are the largest and most complex. The seacables are heavy naval cables and lies on the bottom of the sea. For these heavy-duty applications the cables need good armouring. The armouring, which is made of steel, needs a corrosion protection...

  1. Energy consumption and greenhouse gas emissions in the recovery and extraction of crude bitumen from Canada’s oil sands

    International Nuclear Information System (INIS)

    Highlights: • A model to estimate energy consumption and GHG emissions in oil sands is presented. • The model is developed from fundamental engineering principles. • Cogeneration in the oil sands has the ability to offset GHG emissions. • The effect of key parameters is investigated through a sensitivity analysis. - Abstract: A model – FUNNEL-GHG-OS (FUNdamental ENgineering PrinciplEs-based ModeL for Estimation of GreenHouse Gases in the Oil Sands) was developed to estimate project-specific energy consumption and greenhouse gas emissions (GHGs) in major recovery and extraction processes in the oil sands, namely surface mining and in situ production. This model estimates consumption of diesel (4.4–7.1 MJ/GJ of bitumen), natural gas (52.7–86.4 MJ/GJ of bitumen) and electricity (1.8–2.1 kW h/GJ of bitumen) as fuels in surface mining. The model also estimates the consumption of natural gas (123–462.7 MJ/GJ of bitumen) and electricity (1.2–3.5 kW h/GJ of bitumen) in steam assisted gravity drainage (SAGD), based on fundamental engineering principles. Cogeneration in the oil sands, with excess electricity exported to Alberta’s grid, was also explored. Natural gas consumption forms a major portion of the total energy consumption in surface mining and SAGD and thus is a main contributor to GHG emissions. Emissions in surface mining and SAGD range from 4.4 to 7.4 gCO2eq/MJ of bitumen and 8.0 to 34.0 gCO2eq/MJ of bitumen, respectively, representing a wide range of variability in oil sands projects. Depending upon the cogeneration technology and the efficiency of the process, emissions in oil sands recovery and extraction can be reduced by 16–25% in surface mining and 33–48% in SAGD. Further, a sensitivity analysis was performed to determine the effects of key parameters on the GHG emissions in surface mining and SAGD. Temperature and the consumption of warm water in surface mining and the steam-to-oil ratio (SOR) in SAGD are major parameters

  2. Design of Hybrid Steam-In Situ Combustion Bitumen Recovery Processes

    International Nuclear Information System (INIS)

    Given enormous capital costs, operating expenses, flue gas emissions, water treatment and handling costs of thermal in situ bitumen recovery processes, improving the overall efficiency by lowering energy requirements, environmental impact, and costs of these production techniques is a priority. Steam-assisted gravity drainage (SAGD) is the most widely used in situ recovery technique in Athabasca reservoirs. Steam generation is done on surface and consequently, because of heat losses, the energy efficiency of SAGD can never be ideal with respect to the energy delivered to the sandface. An alternative to surface steam generation is in situ combustion (ISC) where heat is generated within the formation through injection of oxygen at a sufficiently high pressure to initiate combustion of bitumen. In this manner, the heat from the combustion reactions can be used directly to mobilize the bitumen. As an alternative, the heat can be used to generate steam within the formation which then is the agent to move heat in the reservoir. In this research, alternative hybrid techniques with simultaneous and sequential steam-oxygen injection processes are examined to maximize the thermal efficiency of the recovery process. These hybrid processes have the advantage that during ISC, steam is generated within the reservoir from injected and formation water and as a product of oxidation. This implies that ex situ steam generation requirements are reduced and if there is in situ storage of combustion gases, that overall gas emissions are reduced. In this research, detailed reservoir simulations are done to examine the dynamics of hybrid processes to enable design of these processes. The results reveal that hybrid processes can lower emitted carbon dioxide-to-oil ratio by about 46%, decrease the consumed natural gas-to-oil ratio by about 73%, reduce the cumulative energy-to-oil ratio by between 40% and 70% compared to conventional SAGD, and drop water consumption per unit oil produced

  3. Sulfur species in source rock bitumen before and after hydrous pyrolysis determined by X-ray absorption near-edge structure

    Science.gov (United States)

    Bolin, Trudy B.; Birdwell, Justin E.; Lewan, Michael; Hill, Ronald J.; Grayson, Michael B.; Mitra-Kirtley, Sudipa; Bake, Kyle D.; Craddock, Paul R.; Abdallah, Wael; Pomerantz, Andrew E.

    2016-01-01

    The sulfur speciation of source rock bitumen (chloroform-extractable organic matter in sedimentary rocks) was examined using sulfur K-edge X-ray absorption near-edge structure (XANES) spectroscopy for a suite of 11 source rocks from around the world. Sulfur speciation was determined for both the native bitumen in thermally immature rocks and the bitumen produced by thermal maturation of kerogen via hydrous pyrolysis (360 °C for 72 h) and retained within the rock matrix. In this study, the immature bitumens had higher sulfur concentrations than those extracted from samples after hydrous pyrolysis. In addition, dramatic and systematic evolution of the bitumen sulfur moiety distributions following artificial thermal maturation was observed consistently for all samples. Specifically, sulfoxide sulfur (sulfur double bonded to oxygen) is abundant in all immature bitumen samples but decreases substantially following hydrous pyrolysis. The loss in sulfoxide sulfur is associated with a relative increase in the fraction of thiophene sulfur (sulfur bonded to aromatic carbon) to the extent that thiophene is the dominant sulfur form in all post-pyrolysis bitumen samples. This suggests that sulfur moiety distributions might be used for estimating thermal maturity in source rocks based on the character of the extractable organic matter.

  4. The composition of acids in bitumen and in products from saponification of kerogen: Investigation of their role as connecting kerogen and mineral matrix

    Energy Technology Data Exchange (ETDEWEB)

    Razvigorova, M.; Budinova, T.; Tsyntsarski, B.; Petrova, B. [Bulgarian Academy of Sciences, Institute of Organic Chemistry, 1113 Sofia, Acad. Bonchev Str., bl. 9 (Bulgaria); Ekinci, E. [ISIK University, Kumbaba Mevkii, 34980 Istanbul (Turkey); Atakul, H. [Istanbul Technical University, Department of Chemical Engineering, Maslak, 34469 Istanbul (Turkey)

    2008-11-03

    In order to obtain more information and to understand the nature of relation between organic and mineral matter in oil shales, the compositions of soluble bitumen fractions obtained by extraction from Bulgarian oil shales before and after demineralization with 10% HCl, concentrated HF, and a HF/HCl mixture were investigated. The four extracts were quantitatively examined by IR and {sup 1}H NMR spectroscopy. The investigation of isolated acidic material of the bitumen fractions showed that the fatty acids are present in bitumen fractions as free acids, esters and salts. The amount of free acids in bitumen is very small. The dominant part of bitumen acids is associated with mineral components of the oil shales as well as part of them is included in the mineral matrix, and can be separated only after deep demineralization. The kerogen of the oil shales, obtained after separation of the bitumen fractions and mineral components, was subjected to saponification in order to determine the amount of acids, bound as esters to the kerogen matrix. The major components found were n-carboxylic, {alpha},{omega}-di-carboxylic, and aromatic acids. The connection of kerogen with mineral components is accomplished by the participation of carboxylic and complicated ester bonds. Experimental data for the composition of bitumen acids give evidence that algae and terrestrial materials are initial sources in the formation of soluble organic matter of Bulgarian oil shale. (author)

  5. Mechanical Retention and Waterproof Properties of Bacterial Cellulose-Reinforced Thermoplastic Starch Biocomposites Modified with Sodium Hexametaphosphate

    Directory of Open Access Journals (Sweden)

    Da-wei Wang

    2015-06-01

    Full Text Available The waterproof and strength retention properties of bacterial cellulose (BC-reinforced thermoplastic starch (TPS resins were successfully improved by reacting with sodium hexametaphosphate (SHMP. After modification with SHMP, the tensile strength (σf and impact strength (Is values of initial and conditioned BC-reinforced TPS, modified with varying amounts of SHMP(TPS100BC0.02SHMPx, and their blends with poly(lactic acid((TPS100BC0.02SHMPx75PLA25 specimens improved significantly and reached a maximal value as SHMP content approached 10 parts per hundred parts of TPS resin (phr, while their moisture content and elongation at break (ɛf was reduced to a minimal value as SHMP contents approached 10 phr. The  σf, Is and ɛf retention values of a (TPS100BC0.02SHMP1075PLA25 specimen conditioned for 56 days are 52%, 50% and 3 times its initial σf, Is and ɛf values, respectively, which are 32.5 times, 8.9 times and 40% of those of a corresponding conditioned TPS100BC0.02 specimen, respectively. As evidenced by FTIR analyses of TPS100BC0.02SHMPx specimens, hydroxyl groups of TPS100BC0.02 resins were successfully reacted with the phosphate groups of SHMP molecules. New melting endotherms and diffraction peaks of VH-type crystals were found on DSC thermograms and WAXD patterns of TPS or TPS100BC0.02 specimens conditioned for 7 days, while no new melting endotherm or diffraction peak was found for TPS100BC0.02SHMPx and/or (TPS100BC0.02SHMPx75PLA25 specimens conditioned for less than 14 and 28 days, respectively.

  6. Decision 99-8 : Shell Canada Limited application to construct and operate an oil sands bitumen upgrader in the Fort Saskatchewan area : Shell Canada Products Limited application to amend refinery approval in the Fort Saskatchewan area

    International Nuclear Information System (INIS)

    The Alberta Energy and Utilities Board considered an application by Shell Canada Limited to construct and operate an oil sands bitumen upgrader on Shell's property adjoining the existing Scotford refinery in the County of Strathcona. The upgrader would process bitumen from Shell's proposed Muskeg River Mine, located 70 km north of Fort McMurray, and other feedstocks available in the area. The Board also considered an application for an amendment to the existing Scotford refinery approval, Industrial Development Permit 89-10, for the processing of 3.75 million cubic metres per year of sour conversion feedstock. Under a coordinated application process, Shell filed a joint Shell Scotford Upgrader application/Environmental Impact Assessment. Issues considered with respect to these applications were: technology selection, air/health, sulphur recovery, noise/traffic, and land use conflict. Shell stated that its Scotford refinery is the most energy efficient refinery in the Americas and that is has the highest liquid yield per unit volume of crude oil feedstock of any refinery in the world. The refinery's hydrocracking capacity would make it possible to use hydro-conversion technology for its upgrader which is environmentally advantageous. After examining all of the evidence pertaining to the applications, the Board found the projects to be in the public interest and is prepared to approve the Scotford Upgrader and Scotford Refinery modifications assuming that certain prescribed conditions are met

  7. Solar energy based industrial applications at the "Politehnica" University of Timisoara

    Directory of Open Access Journals (Sweden)

    Luminosu Ioan V.

    2011-01-01

    Full Text Available A short overview of a more than 30 years long activity in industrial and home applications of solar energy at the "Politehnica" University of Timişoara, Romania is presented. A built "Solar House", an industrial system for preheating bitumen, a solution for waste water cleaning and an industrial hall for drying ceramic products are described. Some recent studies on solar concentrators are reported.

  8. Solar energy based industrial applications at the "Politehnica" University of Timisoara

    OpenAIRE

    Luminosu Ioan V.; de Sabata Coleta T.; de Sabata Aldo I.

    2011-01-01

    A short overview of a more than 30 years long activity in industrial and home applications of solar energy at the "Politehnica" University of Timişoara, Romania is presented. A built "Solar House", an industrial system for preheating bitumen, a solution for waste water cleaning and an industrial hall for drying ceramic products are described. Some recent studies on solar concentrators are reported.

  9. Modeling of a three-phase reactor for bitumen-derived gas oil hydrotreating

    International Nuclear Information System (INIS)

    A three-phase reactor model for describing the hydrotreating reactions of bitumen-derived gas oil was developed. The model incorporates the mass-transfer resistance at the gas-liquid and liquid-solid interfaces and a kinetic rate expression based on a Langmuir-Hinshelwood-type model. We derived three correlations for determining the solubility of hydrogen (H2), hydrogen sulfide (H2S) and ammonia (NH3) in hydrocarbon mixtures and the calculation of the catalyst effectiveness factor was included. Experimental data taken from the literature were used to determine the kinetic parameters (stoichiometric coefficients, reaction orders, reaction rate and adsorption constants for hydrodesulfuration (HDS) and hydrodenitrogenation (HDN)) and to validate the model under various operating conditions. Finally, we studied the effect of operating conditions such as pressure, temperature, LHSV, H2/feed ratio and the inhibiting effect of H2S on HDS and NH3 on HDN. (author)

  10. Delayed coking studies on Athabasca bitumen and Cold Lake heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Govindhakannan, J.; Khulbe, C. [National Centre for Upgrading Technology, Devon, AB (Canada); Natural Resources Canada, Devon, AB (Canada). CanmetENERGY

    2009-07-01

    This poster highlighted the results of a study that quantified the delayed coking product yields of Athabasca bitumen and Cold Lake heavy oil. It also investigated the effect of operating pressure and feed rates on product yield and quality. The effect of pressure on conversion of sulphur and nitrogen was also examined. Experimental results revealed that the yield of liquid products decreases and the yields of coke and gases increase as the operating pressure increases. Sulphur and nitrogen conversions increase with increasing pressure. In this study, the yield and quality of delayed coking products were not influenced by the variation in feed rates. It was concluded that feed rate changes do not significantly affect the yield and quality of delayed coking products because the residual liquid and coke trapped in the coker drum reside there for a duration that approaches infinity, compared to much smaller average residence time for vapor-phase compounds. tabs., figs.

  11. Modeling of a three-phase reactor for bitumen-derived gas oil hydrotreating

    Directory of Open Access Journals (Sweden)

    R. Chacón

    2012-03-01

    Full Text Available A three-phase reactor model for describing the hydrotreating reactions of bitumen-derived gas oil was developed. The model incorporates the mass-transfer resistance at the gas-liquid and liquid-solid interfaces and a kinetic rate expression based on a Langmuir-Hinshelwood-type model. We derived three correlations for determining the solubility of hydrogen (H2, hydrogen sulfide (H2S and ammonia (NH3 in hydrocarbon mixtures and the calculation of the catalyst effectiveness factor was included. Experimental data taken from the literature were used to determine the kinetic parameters (stoichiometric coefficients, reaction orders, reaction rate and adsorption constants for hydrodesulfuration (HDS and hydrodenitrogenation (HDN and to validate the model under various operating conditions. Finally, we studied the effect of operating conditions such as pressure, temperature, LHSV, H2/feed ratio and the inhibiting effect of H2S on HDS and NH3 on HDN.

  12. Generation of smoke and clogging of ventilation filter under burning of bitumen/salt mixture

    International Nuclear Information System (INIS)

    The fire and explosion accident happened at the bituminization demonstration facility of Power Reactor and Nuclear Fuel Development Corporation (PNC) of Japan on March 11, 1997. To elucidate smoke generation and clogging mechanism of ventilation filters under burning of bitumen/salt mixture in the PNC facility, small-scale simulation experiments were performed. The mock mixtures were prepared by referring to the composition of the real liquid waste and were burnt by heating. The burning behavior of the mixture was observed and the filter pressure drop, which was caused by loading smoke, was measured. Moreover, mass, energy and smoke release rate as direct source term from the burnt mixture and the empirical equation, which could represent the relationship between the pressure drop and burnt mass, were determined by comparing between the calculation results based on a one-dimensional thermofluid analysis code CELVA-1D, and the experimental results. (author)

  13. Fire test a storage container filled with sodium nitrate-bitumen

    International Nuclear Information System (INIS)

    A test was carried out by filling a 100 l barrel of sheet steel with a test mixture (bitumen with 52% NaNO3) and placing the barrel in a larger sheet steel barrel (200 l) and filling the intermediate space with sand as well as covering the test barrel by approx. 15 cm. 74 l petroleum are poured into this sand and ignited. The barrel does not become noticeably warm at any position. If one assumes that such barrels are not piled ontop of one another and there is a good air supply, and the space between the barrels is filled, one can exclude any considerable damage, even if hydrogen should ignite. Should there be no ventilation (closed cavity in rock), then the fire will in any case extinguish when the available oxygen is consumed

  14. Underwater behaviour of bitumen coated radioactive wastes: experimental validation of the Colonbo degradation model

    International Nuclear Information System (INIS)

    In the release scenario considered for geologic repository, water is thought to be the main aggressive agent with regards to bituminized radioactive waste (composed in general of 60 weight % of bitumen, 40% of soluble/insoluble salts and a few ppm of radionuclides). Since liquid water can diffuse in pure bitumen, leaching of bituminized waste results in the dissolution of the most soluble salts and leads to the development of a more or less concentrated saline solution-filled pore structure (called permeable layer). In consequence of the generation of a porous layer in the bituminized waste, leaching of salts and radionuclides can then take place. Research performed at the Atomic Energy Commission (CEA) aims therefore at understanding the consequences of ground-water immersion on the transport properties and radionuclides leaching of bituminized waste materials. To this end, a constitutive model (called COLONBO) which describes mathematically the leaching of bituminized waste has been developed. The COLONBO model is based on the following assumptions: 1. Water and dissolved salts migrate in the permeable layer according to Fick's first law. The diffusion of water and salts are quantified by effective diffusion coefficients which are unknown. 2. The mechanical properties of the bitumen matrix are not considered during leaching (free swelling). Up to now, the COLONBO model has been used only to model experimental water uptake and salt leach curves, leading (theoretical) estimates of the effective diffusion coefficients of water and salts in the permeable layer. The aim of this work was to validate experimentally the numerical results obtained with the COLONBO model. First, the correspondence between experimental and simulated water uptake and salt leach rates obtained on various bituminized waste materials is checked, leading estimates of the effective diffusion coefficients of water and salts in the permeable layer. Second, the evolution of the thickness and of the

  15. An optimized setup for determining the bitumen content in asphalt concrete by the neutron reflection method

    International Nuclear Information System (INIS)

    A setup was developed in order to determine the bitumen content in asphalt concrete by neutron reflection. The main parts of this setup are an Am-Be neutron source of 37 GBq and a 3He neutron detector. To avoid geometrical effects of the measurements, the optimum volume of the samples was determined by plotting the reflected neutron response versus the sample volume. For the calibration of the system, the American Standard Method (ASTM) was used when preparing aggregate and asphalt concrete samples. The method was then compared to the conventional chemical method by analyzing unknown samples taken from an asphalt concrete producing plant and finally the method was assessed in terms of reproducibility, sensitivity and precision. (author)

  16. Characterization of the viscoelastic behavior of the pure bitumen grades 10/20 and 35/50 with macroindentation and finite element computation

    KAUST Repository

    Hamzaoui, Rabah

    2013-06-23

    In this article, we present an identification procedure that allows the determination of the viscoelasticity behavior of different grades of pure bitumen (bitumen 35/50 and bitumen 10/20). The procedure required in the first stage a mechanical response based on macroindentation experiments with a cylindrical indenter. A finite element simulation was performed in the second stage to compute the mechanical response corresponding to a viscoelasticity model described by three mechanical parameters. The comparison between the experimental and numerical responses showed a perfect matching. In addition, the identification procedure helped to discriminate between different bitumens characterized by different asphaltene and maltene contents. Finally, the developed procedure could be used as an efficient tool to characterize the mechanical behavior of the viscoelastic materials, thanks to the quantified relationship between the viscoleastic parameters and the force-penetration response. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3440-3450, 2013 Copyright © 2013 Wiley Periodicals, Inc.

  17. Differences in bitumen and kerogen-bound fatty acid fractions during diagenesis and early catagenesis in a maturity series of New Zealand coals

    DEFF Research Database (Denmark)

    Glombitza, Clemens; Mangelsdorf, Kai; Horsfield, Brian

    2016-01-01

    Oxygen-bearing functional groups, in particular the carboxylic groups of acids and esters, are mainly responsible for the chemical reactivity of sedimentary organic matter. We have studied kerogen and bitumen fractions from a coalification series from the New Zealand Coal Band covering the rank...... range from 0.28% to 0.80% vitrinite reflectance. We investigated the composition of fatty acids separated from the bitumen, and compared this to the distribution of kerogen-bound fatty acids (esters) obtained after selective chemical degradation of the macromolecular organic matter. We found remarkable...... differences in the fatty acid composition between bitumen and kerogen-bound acids, both in the short (< C20) and long chain (≥ C20) fatty acid range. The compositions of these two acid fractions changed independently as a function of maturation. This points to the long and short chain fatty acids in bitumen...

  18. Measurements of the dielectric constant and dielectric loss at MHz and GHz frequencies for ionic exchange resin embedded in concrete and bitumen

    International Nuclear Information System (INIS)

    Dielectric measurements have been carried out on concrete and bitumen containing ion exchange resin. The results indicate that absorption of radio waves would not prohibit measurements being made on full size waste forms, except in the case of concrete at high frequencies. The results also indicate that dielectric measurements on wastes may provide information related to the water content of concrete and bitumen, and possibly also to the curing time of concrete. (Auth.)

  19. An NMR (Nuclear Magnetic Resonance) Investigation of the Chemical Association and Molecular Dynamics in Asphalt Ridge Tar Sand Ore and Bitumen

    Science.gov (United States)

    Netzel, D. A.; Coover, P. T.

    1987-09-01

    Preliminary studies on tar sand bitumen given in this report have shown that the reassociation of tar sand bitumen to its original molecular configuration after thermal stressing is a first-order process requiring nearly a week to establish equilibrium. Studies were also conducted on the dissolution of tar sand bitumen in solvents of varying polarity. At a high-weight fraction of solute to solvent the apparent molecular weight of the bitumen molecules was greater than that of the original bitumen when dissolved in chloroform-d{sub 1} and benzene-d{sub 6}. This increase in the apparent molecular weight may be due to micellar formation or a weak solute-solvent molecular complex. Upon further dilution with any of the solvents studied, the apparent molecular weight of the tar sand bitumen decreased because of reduced van der Waals forces of interaction and/or hydrogen bonding. To define the exact nature of the interactions, it will be necessary to have viscosity measurements of the solutions.

  20. Paleoenvironmental implications of novel C[sub 30] steranes in Precambrian to Cenozoic age petroleum and bitumen

    Energy Technology Data Exchange (ETDEWEB)

    McCaffrey, M.A.; Lipton, P.A. (Chevron Petroleum Technology Company, La Habra, CA (United States)); Moldowan, J.M. (Cheveron Petroleum Technology Company, Richmond, CA (United States) Stanford Univ., CA (United States)); Summons, R.E. (Australian Geological Survey Organization, Canberra City (Australia)); Peters, K.E. (Chevron Overseas Petroleum Inc., San Ramon, CA (United States) Mobil Exploration and Producing Technical Center, Dallas, TX (United States)); Jeganathan, A.; Watt, D.S. (Univ. of Kentucky, Lexington, KY (United States))

    1994-01-01

    Petroleums and bitumens from Early Proterozoic ([approx] 1800 Ma) to Miocene ([approx] 15 Ma) age marine strata contain 24-isopropylcholestanes, a novel group of C[sub 30] steroids. The abundance of these compounds, relative to 24-n-propylcholestanes, varies with source rock age. Late Proterozoic (Vendian) and Early Cambrian oils and/or bitumens from Siberia, the Urals, Oman, Australia, and India have a high ratio of 24-isopropylcholestanes to 24-n-propylcholestanes ([ge] 1), while younger and older samples have a low ratio ([le]0.4). Temporal changes in this parameter may reflect the relative abundance of certain Porifera (sponges) and certain Marine algae through time. Geochemical indicators such as this, which can constrain the source rock age of a migrated oil, are useful in source rock identification during petroleum exploration.

  1. Bitumen coating as a tool for improving the porosity and chemical stability of simulated cement-waste forms

    International Nuclear Information System (INIS)

    Coating process of simulated cement-based waste form with bitumen was evaluated by performing physical and chemical experimental tests. X-ray diffraction (X-RD), Fourier transform infrared spectroscopy (FT-IR) and electron microscope investigations were applied on coated and non-coated simulated waste forms. Experimental results indicated that coating process improved the applicable properties of cement-based waste form such as porosity and leachability. Diffusion coefficients and leach indecies of coated specimens were calculated and show acceptable records. It could be stated that coating cemented waste form by bitumen emulsion, isolate the radioactive contaminants, thus reduces their back release to surrounding and in consequently save the environment proper and safe

  2. Microbiological analysis of the in situ bitumen-nitrate-Opalinus clay interaction

    International Nuclear Information System (INIS)

    Document available in extended abstract form only. Clay formations like the Opalinus Clay are foreseen to serve as the host rock for geological disposal of high and intermediate-level long-lived radioactive waste in several countries, because of their favourable properties to delay the migration of radionuclides over time. However, bituminized intermediate-level long-lived radioactive waste may physico-chemically perturb the clay barrier properties because in time it will leach substantial amounts of nitrate and organic bitumen degradation products (BDP). To study the physico-chemical impact of intermediate-level radioactive waste containing bitumen and nitrate, an in situ experiment in the Opalinus Clay (Saint Ursanne, Switzerland) named the Bitumen-Nitrate- Clay interaction (BN) experiment, is being performed at the Mont Terri Rock Laboratory. The in situ equipment of the BN-experiment consists of three separate packed-off intervals, supplied with a filter screen. Each interval is equipped with its own stainless steel water circulation unit. Such water circulation unit contains water sampling containers, circulation pumps and flow meters. One of the circulation units is equipped with an on-line UV spectrophotometer and pH electrode intervals, allowing a continuous monitoring of nitrate, nitrite concentrations, organic carbon level and pH. In a first series of tests, the microbial and biogeochemical effect of a nitrate and/or acetate perturbation is studied. Acetate is used as it a good representation of BDP. Hereto, nitrate was injected in interval 1 while a mixture of nitrate and acetate is injected in interval 2. As an active microbial community can have a significant impact on the physical and (geo)chemical conditions of the clay surrounding the disposal gallery, microbial analyses were performed on samples taken from the interval solutions before, during and after this first series of tests. Our microbial investigations which included Scanning Electron

  3. Measurement of bitumen viscosity in the room-temperature drop experiment: student education, public outreach and modern science in one

    OpenAIRE

    Widdicombe, A. T.; Ravindrarajah, P.; Sapelkin, A.; A E Phillips; Dunstan, D.; Dove, M. T.; Brazhkin, V. V.; Trachenko, K.

    2014-01-01

    Slow flow of the viscous liquid is a thought-provoking experiment that challenges students, academics and public to think about some fundamental questions in modern science. In the Queensland demonstration, the world-longest running experiment earning the Ig Nobel prize, one drop of pitch takes about 10 years to fall, leading to problems of actually observing the drops. Here, we describe our recent demonstration of slowly-flowing bitumen where appreciable flow is observed on the time scale of...

  4. Influence of the prepolymer molecular weight and free isocyanate content on the rheology of polyurethane modified bitumens

    OpenAIRE

    Carrera Páez, Virginia; Cuadri Vega, Antonio Abad; García Morales, Moisés; Partal López, Pedro

    2014-01-01

    Isocyanate-based modification is lately gaining acceptance as a successful way to give added value to bitumen, a crude oil refining by-product. In order to study the influence of prepolymer type on the rheological properties of the resulting binders, six prepolymers synthesized from polypropylene-glycols (PPG) with varying molecular weight (between 440 and 2425) and different molar excess of a polymeric MDI (4,4’-diphenylmethane diisocyanate) were used. Two modification procedures, either inv...

  5. Radioactivity concentrations and dose assessment for bitumen and soil samples around a bituminous deposit in Ondo State, Nigeria

    International Nuclear Information System (INIS)

    Bitumen samples and soil samples around a bituminous deposit in Ondo State, Nigeria, were analysed for 40K, 226Ra and 232Th employing gamma-ray spectrometry. The activity concentrations of 40K, 226Ra and 232Th in soil varied from (45.2 ± 5.3) to (484.2 ± 25.9), BDL (below detectable limit) to (27.7 ± 2.1) and (22.8 ± 2.7) to (62.4 ± 6.8) Bq.kg-1, respectively. The corresponding mean values were (240.2 ± 133.5), (13.3 ± 8.0) and (40.0 ± 10.2) Bq.kg-1, respectively. The mean activity concentrations of the radionuclides in the bitumen were (58.4 ± 36.4), (16.1 ± 13.3) and (32.5 ± 13.1) Bq.kg-1, respectively, for 40K, 226Ra and 232Th. The mean absorbed dose and effective dose for the soil samples were (41.5 ± 8.9) nGy.h-1 and (50.7 ± 10.9) μSv.y-1, respectively, while those of the bitumen samples were (29.5 ± 15.6) nGy.h-1 and (36.1 ± 19.1) μSv.y-1, respectively. For radiological hazard assessment, the radium equivalent activity and the external hazard index were determined. The values of the radium equivalent activity and external hazard index obtained for the soil and bitumen samples were lower than the recommended limit. (authors)

  6. Waterproof Fire Stations

    DEFF Research Database (Denmark)

    Bundgaard, Peer; Stjernfelt, Frederik; Østergaard, Svend

    2006-01-01

    The paper develops a characterization of nominal compounds. The analysis is carried out on frame-schematic and construction-grammatical grounds.  It rests on assumptions about cognitive processing long since known within cognitive linguistics, but it criticizes certain linguistic applications of ...

  7. Laboratory performance testing of an extruded bitumen containing a surrogate, sodium nitrate-based, low-level aqueous waste

    International Nuclear Information System (INIS)

    Laboratory results of a comprehensive regulatory performance test program, using an extruded bitumen and a surrogate, sodium nitrate-based waste, have been compiled at the Oak Ridge National Laboratory (ORNL). The testing has shown that the relatively viscous form of oxidized bitumen that was used has been able to meet all performance requirements. Using a 53-mm Werner and Pfleiderer extruder, operated by personnel of WasteChem Corporation of Paramus, New Jersey, laboratory-scale, molded samples of ASTM D312, type III, air-blown bitumen were prepared for laboratory performance testing. A surrogate, low-level, mixed liquid waste, formulated to represent an actual on-site waste at ORNL, was used. The mixed liquid waste contained approximately 30 wt % sodium nitrate, in addition to eight heavy metals, cold cesium, and strontium. Samples tested contained three levels of waste loading: that is, 40, 50, and 60 wt % salt. Performance test results include the 90-day American Nuclear Society (ANS) 16.1 leach test, with leach indices reported for all cations and anions, in addition to the EP toxicity test, at all levels of waste loading. Additionally, test results presented include the unconfined compressive strength and surface morphology utilizing scanning electron microscopy (SEM). Data presented include correlations between waste form loading and test results, in addition to their relationship to regulatory performance requirements

  8. Proceedings of the 4. NCUT conference on upgrading and refining of heavy oil, bitumen, and synthetic crude oil

    International Nuclear Information System (INIS)

    The Canadian oil sands are held as a prime resource opportunity as well as a key to future global energy needs. Expansion projects in Northern Alberta are expected to increase production from the current 1 million barrels per day to 3 million by 2020. However, significant research needs to be conducted to increase the economics of oil sands production. This conference examined various upgrading technologies related to bitumen production and presented details of new innovations in upgrading processes. Many of the presentations focused on issues related to the compatibility and stability of upgraded bitumen and heavy crudes to fuel and pipeline specifications. Research developments in asphaltene behaviour research were presented. Various hydrocracking techniques were evaluated. Issues concerning water use, energy efficiency, and greenhouse gas (GHG) emissions were also discussed. A technical program was presented in which a keynote address examined issues concerning oil sands and the global marketplace. The main conference was divided into 5 sessions: (1) new technologies for bitumen upgrading; (2) energy independence and increased opportunities for value addition; (3) secondary upgrading developments and increasingly tight fuel specifications; (4) corrosion; and (5) fouling. Each session was followed by a question and answer period. The conference featured 31 presentations, of which 29 have been catalogued separately for inclusion in this database

  9. Proceedings of the 4. NCUT conference on upgrading and refining of heavy oil, bitumen, and synthetic crude oil

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The Canadian oil sands are held as a prime resource opportunity as well as a key to future global energy needs. Expansion projects in Northern Alberta are expected to increase production from the current 1 million barrels per day to 3 million by 2020. However, significant research needs to be conducted to increase the economics of oil sands production. This conference examined various upgrading technologies related to bitumen production and presented details of new innovations in upgrading processes. Many of the presentations focused on issues related to the compatibility and stability of upgraded bitumen and heavy crudes to fuel and pipeline specifications. Research developments in asphaltene behaviour research were presented. Various hydrocracking techniques were evaluated. Issues concerning water use, energy efficiency, and greenhouse gas (GHG) emissions were also discussed. A technical program was presented in which a keynote address examined issues concerning oil sands and the global marketplace. The main conference was divided into 5 sessions: (1) new technologies for bitumen upgrading; (2) energy independence and increased opportunities for value addition; (3) secondary upgrading developments and increasingly tight fuel specifications; (4) corrosion; and (5) fouling. Each session was followed by a question and answer period. The conference featured 31 presentations, of which 29 have been catalogued separately for inclusion in this database. refs., tabs., figs.

  10. Effect of radio-oxidative ageing and pH on the release of soluble organic matter from bitumen

    International Nuclear Information System (INIS)

    Bitumen is employed as an embedding matrix for low and medium level radioactive wastes. An high impermeability and a great resistance against most of chemicals are two of main bitumen properties. These characteristics of bitumen confinement properties may be modified under environmental parameters during intermediate storage or deep repository such as radiations or the presence of water. The radio-oxidation induces an increase of the quantity of leached organic matter. The evolution of the soluble organic species release seems to be linear with the irradiation dose, as soon as the dose is higher than 20 kGy, and seems to be no dependant of the dose rate. The generation of water-soluble organic complexing agents can affect the integrity of the wasteform due to an increase of the radionuclides solubility. An increase of the quantity of leached organic matter is also observed in presence of alkaline solutions. Identified molecules, by GC/MS analysis, are aromatics like naphthalene, oxidised compounds like alcohols, linear carbonyls, aromatics, glycols and nitrogen compounds. (authors)

  11. Thermomechanical properties of bitumen modified with crumb tire rubber and polymeric additives

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, V.; Martinez-Boza, F.J.; Navarro, F.J.; Gallegos, C. [Departamento de Ingenieria Quimica, Universidad de Huelva, Campus del Carmen, 21071 Huelva (Spain); Perez-Lepe, A.; Paez, A. [Centro de Tecnologia, Repsol-YPF, Carretera de Extremadura, N-V, km 18, 28931 Mostoles-Madrid (Spain)

    2010-09-15

    In this paper, the influence of some additives on the rheological and technological properties of crumb rubber modified binders has been studied. The research has been mainly focused on the degree of bitumen modification, measured as the improvement of the mechanical properties, produced by the additives used, and the storage stability of these binders at high temperature. The experimental results obtained reveal that all the polymeric additives used yield an improvement in both rheological and technological properties of the binder. The storage instability of these binders has been associated to sedimentation processes of insoluble CR particles that strongly influence the mechanical properties of the binder. The additives and processing conditions selected in this study do not completely prevent problems associated with the poor stability of CRMBs during storage at high temperature. Nevertheless, the use of polyoctenamer, FT-wax or SBS-containing additives improves CRMB stability. In this sense, similar loss tangent values were found before and after hot storage of these binders. (author)

  12. Modeling of a three-phase reactor for bitumen-derived gas oil hydrotreating

    Energy Technology Data Exchange (ETDEWEB)

    Chacon, R.; Canale, A.; Bouza, A. [Departamento de Termodinamica y Fenomenos de Transporte. Universidad Simon Bolivar, Caracas (Venezuela, Bolivarian Republic of); Sanchez, Y. [Departamento de Procesos y Sistemas. Universidad Simon Bolivar (Venezuela, Bolivarian Republic of)

    2012-01-15

    A three-phase reactor model for describing the hydrotreating reactions of bitumen-derived gas oil was developed. The model incorporates the mass-transfer resistance at the gas-liquid and liquid-solid interfaces and a kinetic rate expression based on a Langmuir-Hinshelwood-type model. We derived three correlations for determining the solubility of hydrogen (H{sub 2}), hydrogen sulfide (H{sub 2}S) and ammonia (NH{sub 3}) in hydrocarbon mixtures and the calculation of the catalyst effectiveness factor was included. Experimental data taken from the literature were used to determine the kinetic parameters (stoichiometric coefficients, reaction orders, reaction rate and adsorption constants for hydrodesulfuration (HDS) and hydrodenitrogenation (HDN)) and to validate the model under various operating conditions. Finally, we studied the effect of operating conditions such as pressure, temperature, LHSV, H{sub 2}/feed ratio and the inhibiting effect of H{sub 2}S on HDS and NH{sub 3} on HDN. (author)

  13. Polymer and bitumen-modified OPC for the immobilization of ILW

    International Nuclear Information System (INIS)

    A detailed study has been made of the modification of ordinary Portland cement with polymeric additives, and of the properties of waste forms based on these matrix materials. The additives were styrene butadiene and bitumen emulsions, and epoxide and polyurethane resins: the simulated wastes were organic ion exchanger beads, PWR evaporator concentrate, reprocessing concentrate and Magnox metal. The effect of polymer: cement (p:c) and water:cement ratios on the properties of the hardened cement paste has been comprehensively investigated. Substantial increases in strain to failure, and modest reductions in permeability to water and leach rates for Cs137, are obtained at p:c > 0.2. Much larger volume fractions of organic ion exchange beads can be encapsulated in polymer modified OPC than in unmodified OPC, perhaps because of their better strain capability. The radiation stability of cemented PWR evaporator concentrate is better for a polymer-modified matrix than an unmodified OPC matrix. Two hundred litre trials have been successfully demonstrated. 20 refs, 20 tabs, 10 figs

  14. Super critical water reactor for use in steam generation for recovery of bitumen resources

    International Nuclear Information System (INIS)

    The process of recovering the bitumen (oil sand) resources in Alberta requires steam at high pressures. To help reduce the carbon footprint of exploiting these fuel resources, an innovative new design of a CANDU super critical water reactor (CANDU-SCWR) is being considered to provide the high pressure steam required for the steam assisted gravity drainage (SAGD) process. The high temperature and pressure associated with the CANDU-SCWR allow for the high pressure, temperature steam to be produced without supplementary energy. The Petroleum Technology Alliance of Canada (PTAC) has specified the SAGD process requires steam at 11 MPa and near 100% steam quality, and net electrical power of 106 MWe. This paper examines steam cycle and design options to meet the steam and power requirements defined by PTAC. Steam cycle options are examined focusing on the optimization of steam and power conversion. Additionally passive safety and cooling for both the heat transport and moderation systems are considered and their impact on performance are examined. As the CANDU-SCWR is at a preliminary stage of design, basic design parameters have been defined based on preliminary assessments. This paper is focused on a reactor with the following basic design assumptions: Vertical fuel channel; Re-entrant fuel channels; Pu-Th fuel; and Batch refuelling. (author)

  15. The Study Of Briquettes Produced With Bitumen, Caso4 And Starch As Binders.

    Directory of Open Access Journals (Sweden)

    ,Ikelle Issie Ikelle

    2014-06-01

    Full Text Available The work was based on production and study of the properties of smokeless briquettes of various compositions with coal and rice husk. Different briquettes were produced with starch, bitumen and CaSO4 as the binders while Ca(OH2 was the desulphurizing agent. The proximate analysis of the raw coal sample showed ash content 19.12%, moisture content 6.25%, volatile matter 41.12%, fixed carbon 33.51% and calorific value 117 KJ/g, the rice husk had the following values ash content 7.53%, moisture content 10.48%, volatile matter 68.74%, fixed carbon 13.25% and calorific value 65.24 KJ/g. The briquettes produced are in the following ratio of mixtures of coal and rice husk 100:0, 80:20, 60:40, 40:60, 20:80 and 0:100 respectively. The prepared briquettes were sun dried for seven days, subjected to various tests to assess their fuel quality. The briquettes produced with starch as the binder had better results for faster ignition time, lower amounts of sulphur emissions during burning, highest calorific values and longer burning time for all the different compositions.

  16. Hydrothermal bitumen generated from sedimentary organic matter of rift lakes - Lake Chapala, Citala Rift, western Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Zarate del Valle, Pedro F. [Departamento de Quimica, Universidad de Guadalajara - CUCEI, Ap. Postal 4-021, Guadalajara, Jalisco CP 44410 (Mexico); Simoneit, Bernd R.T. [Environmental and Petroleum Geochemistry Group, College of Oceanic and Atmospheric Sciences, Oregon State University, Building 104, Corvallis, OR 97331-5503 (United States)]. E-mail: simoneit@coas.oregonstate.edu

    2005-12-15

    Lake Chapala is in the Citala Rift of western Mexico, which in association with the Tepic-Zacoalco and Colima Rifts, form the well-known neotectonic Jalisco continental triple junction. The rifts are characterized by evidence for both paleo- and active hydrothermal activity. At the south shore of the lake, near the Los Gorgos sublacustrine hydrothermal field, there are two tar emanations that appear as small islands composed of solid, viscous and black bitumen. Aliquots of tar were analyzed by GC-MS and the mixtures are comprised of geologically mature biomarkers and an UCM. PAH and n-alkanes are not detectable. The biomarkers consist mainly of hopanes, gammacerane, tricyclic terpanes, carotane and its cracking products, steranes, and drimanes. The biomarker composition and bulk C isotope composition ({delta} {sup 13}C = -21.4%) indicate an organic matter source from bacteria and algae, typical of lacustrine ecosystems. The overall composition of these tars indicates that they are hydrothermal petroleum formed from lacustrine organic matter in the deeper sediments of Lake Chapala exceeding 40 ka ({sup 14}C) in age and then forced to the lakebed by tectonic activity. The absence of alkanes and the presence of an UCM with mature biomarkers are consistent with rapid hydrothermal oil generation and expulsion at temperatures of 200-250 deg. C. The occurrence of hydrothermal petroleum in continental rift systems is now well known and should be considered in future energy resource exploration in such regions.

  17. Hot solvent injection for heavy oil-bitumen recovery : an experimental investigation

    Energy Technology Data Exchange (ETDEWEB)

    Pathak, V.; Babadagli, T. [Alberta Univ., Edmonton, AB (Canada); Edmunds, N.R. [Laricina Energy Ltd., Calgary, AB (Canada)

    2010-07-01

    Steam injection and generation costs can have a significant influence on the overall economics of thermal heavy oil and bitumen recovery processes. The economic feasibility of miscible recovery methods is based on the use of effective solvent retrieval procedures. This study investigated the performance of solvents at higher temperatures. Glass bead packs and Berea sandstone cores were used to represent different types of pore structures in a series of laboratory experiments. The samples were saturated with heavy oil and exposed to paraffinic solvent vapors at temperatures above boiling point at a pressure of 1500 kPa. The solvents were then collected from each sample and analyzed in order to determine composition, viscosity, and asphaltene content. The amounts of oil recovered were also analyzed and the quantity of the asphaltene precipitated with each of the tested solvents was determined. Results of the study were then used to determine optimal conditions for each solvent type and to assess which solvents had the highest recovery rates. Butane diluted the oil more than propane, which resulted in a lower asphaltene content and decreased viscosity in the oil samples. 18 refs., 4 tabs., 11 figs.

  18. Hydrothermal bitumen generated from sedimentary organic matter of rift lakes - Lake Chapala, Citala Rift, western Mexico

    International Nuclear Information System (INIS)

    Lake Chapala is in the Citala Rift of western Mexico, which in association with the Tepic-Zacoalco and Colima Rifts, form the well-known neotectonic Jalisco continental triple junction. The rifts are characterized by evidence for both paleo- and active hydrothermal activity. At the south shore of the lake, near the Los Gorgos sublacustrine hydrothermal field, there are two tar emanations that appear as small islands composed of solid, viscous and black bitumen. Aliquots of tar were analyzed by GC-MS and the mixtures are comprised of geologically mature biomarkers and an UCM. PAH and n-alkanes are not detectable. The biomarkers consist mainly of hopanes, gammacerane, tricyclic terpanes, carotane and its cracking products, steranes, and drimanes. The biomarker composition and bulk C isotope composition (δ 13C = -21.4%) indicate an organic matter source from bacteria and algae, typical of lacustrine ecosystems. The overall composition of these tars indicates that they are hydrothermal petroleum formed from lacustrine organic matter in the deeper sediments of Lake Chapala exceeding 40 ka (14C) in age and then forced to the lakebed by tectonic activity. The absence of alkanes and the presence of an UCM with mature biomarkers are consistent with rapid hydrothermal oil generation and expulsion at temperatures of 200-250 deg. C. The occurrence of hydrothermal petroleum in continental rift systems is now well known and should be considered in future energy resource exploration in such regions

  19. Rubber bearing and bitumen infill support system for seismic protection of nuclear power plant structures

    International Nuclear Information System (INIS)

    The prestressed concrete pressure vessel (PCPV) for the AGR is of cylindrical type. The whole of the reactor primary circuit is contained within the PCPV vault and includes the reactor core and support structures, boilers and gas circulators. The PCPV is essentially free standing on its foundation raft. In order to transmit gravitational and seismic loads between the PCPV and the foundation raft, a support system is used which consists of concentric rings of neoprene pads and a thin annulus of bitumen infill. In order to assess the importance of both stiffness and damping of the PCPV support system on the overall AGR response, detailed parametric studies were carried out using time-history dynamic analysis in conjunction with the modal superposition technique. The effects of both stiffness and damping are compared in terms of the maximum dynamic response (maximum accelerations and maximum relative displacements) and also floor response spectra at various locations on the nuclear island. It is clearly apparent from these investigations that for an appropriate range of structures on the nuclear island (such as the PCPV and its internals), greater reduction in seismic loading can be achieved by proper selection of stiffnesses and damping of the PCPV support system without resorting to strengthening techniques. (orig./HP)

  20. 建筑屋面节能与保温防水材料的应用%Applications of the Energy Conservation and Thermal Insulation Waterproof Material of Building Roof

    Institute of Scientific and Technical Information of China (English)

    陈颖杰

    2014-01-01

    The application of energy conservation and thermal insulation waterproof technology in housing construction plays an important role. This article analyzes the concrete applicati-on of roof energy saving materials and waterproof insulation materials, application status and development trend of thermal insulation roofing waterproof materials, discusses problems a-nd solutions of a new energy-saving material of roofing water-proof insulation board in the application.%建筑屋面节能与保温防水技术的应用在房屋建设中发挥着重要的作用。文章先后分析了屋面节能材料与保温防水材料的具体运用,屋面保温节能防水材料的应用现状与发展趋势,就屋面保温防水板这一新型节能材料应用中存在的问题与解决对策进行了探讨。

  1. Polymeric synthetic geo membranes in reservoirs waterproofing in the Kingdom of Morocco; Las geomembranas sinteticas polimericas en la impermeabilizacion de balsas en el Reino de Marruecos

    Energy Technology Data Exchange (ETDEWEB)

    Blanco Fernandez, M.

    2015-07-01

    This essay aims to address some of the aspects related to polymeric synthetic geo membranes that could be used in reservoirs of water located in the Kingdom of Morocco. In this regard, it offers a description of the two basic components geo membranes consist of, that is, resins and additives. It also gives an overview of the key pieces of legislation affecting such an issue. Furthermore, it stresses the paramount importance of implementing monitoring procedures in order to assess the condition of geo membranes over time and, if necessary, to proceed to provide for new waterproofing. Lastly, the characteristics of the process monitoring aforementioned are detailed in terms of tensile strength, elongation, tear resistance, dynamic impact, puncture resistance, low-temperature folding. Shore hardness, stress cracking, oxidation induction times, joint strength shear and peeling test, content and dispersion of carbon black and reflection-optical and scanning-electron microscopy. (Author)

  2. Chemistry and mineralogy of natural bitumens and heavy oils and their reservoir rocks from the United States, Canada, Trinidad and Tobago, and Venezuela

    Science.gov (United States)

    Hosterman, John W.; Meyer, R.F.; Palmer, C.A.; Doughten, M.W.; Anders, D.E.

    1990-01-01

    Twenty-one samples from natural bitumen and heavy oil deposits in seven States of the United States and six samples from outside the United States form the basis of this initial study. This Circular gives the mineral content of the reservoir rock, the trace-element distribution in the reservoir rock and hydrocarbons, and the composition of the heavy oil and natural bitumen. The reservoir rock and sediment residues from California contain more trace-element maximum amounts than any of the other rock samples. These relatively high concentrations of trace elements may be due, in part, to the low quartz content of the rock and to the presence of heulandite, cristobalite, siderite, and pyrite. The reservoir rock and sediment residues from Oklahoma contain more minimum amounts of trace elements than any of the other rock samples. This pattern probably results from the large amount of quartz in four of the samples and a large amount of calcite in the other sample. The maximum and minimum amounts of trace elements in the bitumen and heavy oil do not correlate with those in the reservoir rocks. The bitumen from Utah contains the greatest number of trace-element maxima, whereas there is no trend in the trace-element minima in the bitumen and heavy oil.

  3. Indoor Test Analysis on Performance of Waterproof Binding Course of Bridge Deck%桥面防水黏结层性能室内试验分析

    Institute of Scientific and Technical Information of China (English)

    朱建富

    2014-01-01

    对4种防水黏结材料进行黏结力试验,结果表明环氧沥青的黏结效果最优。不同试验温度及喷砂构造深度下的室内剪切试验结果表明:抗剪强度随试验温度的升高而减低,且在最佳构造深度时,抗剪强度达到最大。不同试验温度、浸水及冻融条件下的拉拔试验结果表明:防水黏结材料的拉拔强度随着温度的升高而明显降低,且温度越高,衰减越快;在浸水和冻融条件下,拉拔强度出现不同幅度的下降。%The cohesive force test is carried out on four kinds of waterproof. The results show that the ep-oxy asphalt is of the optimal binder effect. The results of indoor shearing tests with different temperatures and different sandblasting structure depth show that the shear strength decreases as the test temperature increases, and when the optimal sandblasting structure depth is achieved, the shear strength reaches maxi-mum. The results of drawing tests under the condition of different test temperatures, soaking and freeze thawing show that with the increase of temperature, the drawing strength of waterproof cohesive materials significantly reduces, the higher the temperature is, the faster the drawing strength decays, and under the condition of soaking and freeze-thaw, the drawing strength drops with different amplitude.

  4. 纳米材料拒水织物加工技术及应用%Technology and Application of Nanomaterials in Waterproof Fabric Processing

    Institute of Scientific and Technical Information of China (English)

    党美娟; 林娜; 王飞龙

    2011-01-01

    Application of nanomaterials in waterproof fabric production was summarized. Principle of applying nanomaterials in surface waterproof fabric were researched, characterization of nanomaterial was introduced as well as fabric water repellency test index, method of doing fabric water repellency for nanomaterials, applications at home and a-broad. It is considered that advantages of nano water repellence materials in both materials manufacture process and function application are obviously. It is pointed out that research of nano water repellence materials should be strengthened, agglomeration phenomenon of nanomaterials in applications and its effect on human body should be paid attention to specially.%概述纳米材料在拒水织物生产中的应用情况.探究了纳米材料应用于表面拒水性织物的机理,介绍了纳米材料的表征方法、织物拒水性测试指标及纳米材料进行织物拒水整理加工的方法和国内外应用状况.认为:不论是从材料的加工过程,还是功能性应用方面,纳米拒水材料都具有明显优势,并指出应加强纳米拒水材料的研究,着重关注纳米材料在应用中的团聚现象及时人体的影响.

  5. Comparison of the chemical structure of coal hydrogenation products, Athabasca tar sand bitumen and Green River shale oil

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, R.; Yoshida, T.; Nakata, Y.; Hasegawa, Y.; Hino, M.; Ikawa, Y.; Makabe, M.; Bodily, D.M.

    1983-03-01

    Coal hydrogenation products, Athabasca tar sand bitumen, and Green River shale oil produced by retorting were analyzed by the Brown-Ladner method and the Takeya et al. method on the basis of elemental analysis and /sup 1/H-NMR data, by /sup 13/C NMR spectroscopy and by FT-IR spectroscopy. Structural characteristics were compared. The results show that the chemical structure of oils from Green River shale oil and Athabasca tar sand bitumen, and the oils produced in the initial stage of hydrogenation of Taiheiyo coal and Clear Creek, Utah, coal is characterized as monomers consisting of units of one aromatic ring substituted highly with C/sub 5//sub -//sub 6/ aliphatic chains and heteroatom-containing functional groups. The chemical structure of asphaltenes from Green River shale oil and Athabasca tar sand bitumen is characterized by oligomers consisting of units of 1-2 aromatic rings substituted highly with C/sub 3//sub -//sub 5/ aliphatic chains and heteroatom-containing functional groups. The chemical structure of asphaltenes from coal hydrogenation is characterized by dimers and/or trimers of unit structures of 2 to 5 condensed aromatic rings, substituted moderately with C/sub 2//sub -//sub 5/ aliphatic chains and heteroatom-containing functional groups. The close agreement between f/SUB/a(/sup 1/H-NMR) and f/SUB/a(/sup 13/C-NMR) for Green River shale oil derivatives indicates that the assumption of 2 for the atomic H/C ratio of aliphatic structures is reasonable. For coal hydrogenation products, a value of 1.6-1.7 for the H/C ratio of aliphatic structures would be more reasonable. (25 refs).

  6. Upstream petroleum industry flaring and venting report : industry performance for year ending December 31, 2008

    International Nuclear Information System (INIS)

    The Energy Resources Conservation Board (ERCB) has developed recommendations for a flaring and venting management framework for the province of Alberta. This report fulfilled the ERCB's information mandate regarding flaring and venting as part of a commitment made in Directive 060 for upstream petroleum industry flaring, incineration, and venting to make flaring and venting data more accessible. It included data on upstream petroleum industry flaring and venting with particular reference to solution gas conserved, flared and vented, from 1996 to 2008; solution gas flaring and venting performance; flaring from all upstream oil and gas sources, from 2000 to 2008; venting from all upstream oil and gas sources, from 2000 to 2008; solution gas flaring and venting maps; and solution gas emissions ranking of operators for 2007. The report also provided a summary of flaring and venting from various oil and gas industry sources, such as well tests, gas plants, gas gathering systems, transmission lines, and batteries. Ranking of companies was established based on solution gas flared plus vented; solution gas flared; and solution gas vented from crude oil and bitumen batteries. The data used in the preparation of this report was submitted by companies. The report revealed that considerable progress has been made in the reduction of flaring and venting volumes for all upstream oil and gas sources. The reduction can be attributed to the decline in new conventional oil production. It can also be correlated to the decline in volumes of solution gas formerly being flared, and now being vented. Solution gas vented in 2008 was 40.7 per cent less than the 2000 venting baseline. However, in 2008, there was a 25.9 per cent increase in venting from crude bitumen batteries which can be correlated to the increase in crude bitumen production. The ERCB is continuing to work with the Clean Air Strategic Alliance to examine options to further address solution gas venting. tabs., figs.

  7. Improved set-up for determination of bitumen content in asphalt concrete by the neutron reflection method

    International Nuclear Information System (INIS)

    A set-up was developed for the determination of bitumen in asphalt concrete by the neutron reflection method. The main parts of this set-up include an Am-Be neutron source (1 Ci) and a 3He neutron detector. To avoid geometrical effects on the measurements, the optimum sample volume was determined from the neutron response vs volume sample plot. The AST method (ASTM) was used for calibration when preparing the aggregate and asphalt concrete samples. The method was compared to the conventional chemical method by analysing unknown samples taken from the asphalt concrete producing plant. The method was characterized by its reproducibility, sensitivity and precision

  8. Irritative effects of fumes and aerosols of bitumen on the airways: results of a cross-shift study

    Energy Technology Data Exchange (ETDEWEB)

    Raulf-Heimsoth, Monika; Pesch, Beate; Kappler, Martin; Marczynski, Boleslaw; Rihs, Hans Peter; Merget, Rolf; Bruening, Thomas [Institut der Ruhr-Universitaet Bochum, Berufsgenossenschaftliches Forschungsinstitut fuer Arbeitsmedizin (BGFA), Bochum (Germany); Schott, Klaus [Berufsgenossenschaft der Bauwirtschaft (BG BAU), Munich (Germany); Preuss, Ralf; Angerer, Juergen [Universitaet Erlangen, Institut und Poliklinik fuer Arbeits-, Sozial- und Umweltmedizin (IPASUM), Erlangen (Germany); Hahn, Jens Uwe [Berufsgenossenschaftliches Institut fuer Arbeitsschutz (BGIA), Sankt Augustin (Germany)

    2007-01-15

    Possible health hazards of fumes and aerosols of bitumen are in discussion, and data on their adverse effects on human airways under current exposure conditions are limited. To assess the irritative effects of exposure to fumes and aerosols of bitumen on the airways, a cross-sectional cross-shift study was conducted including external and internal exposure measurements, spirometry and especially non-invasive methods like nasal lavage collection and induction of sputum in order to identify and evaluate more precisely inflammatory process in the upper and lower airways. The cross-shift study comprised 74 mastic asphalt workers who were exposed to fumes and aerosols of bitumen and 49 construction workers without this exposure as reference group. Questionnaire, spirometry, ambient monitoring and urinary analysis were performed. Humoral and cellular parameters were measured in nasal lavage fluid (NALF) and induced sputum. For data analysis, a mixed linear model was performed on the different outcomes with exposure group, time of measurement (pre-, post-shift), current smoking, German nationality and age as fixed factors and subjects as random factor. Based on personal exposure measurements during shift, mastic asphalt workers were classified into a low ({<=}10 mg/m{sup 3}; n = 46) and a high (>10 mg/m{sup 3}; n = 28) exposure group. High exposure was accompanied by significant higher urinary post-shift concentrations of 1-hydroxypyrene and the sum of hydroxyphenanthrenes. Acute respiratory symptoms were reported more frequently in the high exposure group after shift. Significant cross-shift declines in lung function parameters (forced expiratory volume in 1 s [FEV{sub 1} (% predicted)] and forced vital capacity [FVC (% predicted)]) were measured in mastic asphalt workers. Pre-shift FEV{sub 1} (% predicted) and FVC (% predicted) were higher in the low exposure group. In pre- and post-shift NALF samples, interleukin (IL)-1{beta}-, IL-8- and total protein concentrations

  9. Upstream petroleum industry flaring report, 1999

    International Nuclear Information System (INIS)

    A summary of flared volumes for the various oil and gas industry sectors including well tests, gas plants, gas gathering systems and batteries were presented in this report along with data on solution gas conserved, flared and vented in Alberta during 1999. This report is published in response to a commitment that the Alberta Energy and Utilities Board (EUB) made to ensure that flaring data is more accessible to the public and industry. The data included in the report is based on information submitted by companies. The information is tabulated and operators are ranked based on solution gas flared, solution gas vented, total gas produced, and total oil from crude oil and crude bitumen batteries. The report demonstrates the significant progress industry has made towards reducing solution flare gas and vent volumes in the province. Flaring solution gas in Alberta has been reduced by about 30 per cent from the 1996 level. tabs

  10. Sorption of cesium, strontium, iodine, nickel and carbon in mixtures of concrete, crushed rock and bitumen

    International Nuclear Information System (INIS)

    Sorption of Cs-134, Sr-85, I-125, Ni-63 and C-14 on simulated mixtures of materials present in the repositories for low and medium level wastes were studied. Samples were selected according to the Finnish plans for the repositories. The components of the mixtures were crushed rock, concrete (IVO and TVO) and bitumen (TVO) to be used as waste package, backfill and construction material. The ground water used was collected from the planned disposal sites for the low and medium level wastes. The solution-to-solid mass-ratios (V/M) have been chosen to simulate the conditions prevailing in repositories. The Ksub(d)-values of the mixtures were determined by the batch method. The Ksub(d)-values of the mixtures were also calculated using the relative mass of each component and the Ksub(d)-values determined for each component separately. The effect of concrete water as well as the correction due to the ratio of the liquid volume to solid mass (V/M-ratio) was taken into account in the determinations of the calculated Ksub(d)-values. The experimental Ksub(d)-values of cesium were 10 - 115 and 1 - 3 ml/g for TVO's and IVO's mixtures, respectively. The calculated Ksub(d)-values were 2 - 26 times higher than the experimental Ksub(d)-values. The experimental and calculated Ksub(d)-values of strontium, iodine and nickel were the same order of magnitude. The Ksub(d)-values of strontium were about 1 - 16 ml/g. Low sorption of iodine in all samples was found, the Ksub(d)-values were < 0.6 ml/g. The Ksub(d)-values of nickel were 2 - 15 ml/g. The experimental Ksub(d)-values of carbon were 0.1 - 12 ml/g. The calculated Ksub(d)-values of carbon were lower than the experimental Ksub(d)-values. The effect of V/M on Ksub(d) of sample mixtures was low for Sr. For cesium and iodine the Ksub(d) was lower by a factor of 5 for the V/M ratio 0.28:1 than 10:1. For nickel and carbon the Ksub(d)-values were 1 - 3 orders of magnitude smaller for low V/M ratio (0.28:1). (author)

  11. Modification of an Amposta origin bitumen by using tlie Friedel and Crafts reaction with toluyiene-2,4-diisocyanate

    Directory of Open Access Journals (Sweden)

    Blanco, M.

    1988-03-01

    Full Text Available In this works, we have modified a bitumen from Amposta by using the Friedel and Crafts reaction with toluylene-2,4-diisocyanate in presence of aluminium trichloride, presenting as well as the characteristics of the original bitumen as the ones of the modification products. We have made technological test, aging of thin film, rheological test, thermical susceptibility and components analyses.

    En el presente trabajo se ha modificado un betún procedente de Amposta por reacción de Friedei y Crafts con 4-metil-1,3-bencenodiisocianato, en presencia de tricloruro de aluminio. Se han determinado las características del betún original así como las de los productos obtenidos en la modificación. Se han llevado a cabo ensayos de tipo tecnológico, envejecimiento en película delgada, propiedades reológicas, susceptibilidad térmica y análisis de componentes.

  12. Research Progress and Application of Thermo-sensitive Waterproof and Moisture Permeable Polyurethane%温敏型防水透湿聚氨酯的研究进展及应用

    Institute of Scientific and Technical Information of China (English)

    赵宁; 李冰; 律微波; 李金辉; 彭丹

    2014-01-01

    温敏型防水透湿聚氨酯为当前智能高分子材料研究的热点之一。介绍了该类聚氨酯的结构和温敏特性,介绍了温敏型防水透湿聚氨酯的研究进展,并对其在纺织、医疗、食品包装等领域的应用前景进行了概述。%Thermo-sensitive waterproof and moisture permeable polyurethane is one of the hotspots in current research on intelligent polymer materials. In this paper, the structure and thermo-sensitive characteristics of this polyurethane were summarized, research progress of thermo-sensitive waterproof and moisture permeable polyurethane was introduced, and its application prospect in textile, medical, food packaging and other fields was described.

  13. 对独立基础加防水板地基承载力修正分析%The correction analysis on independent foundation plus waterproof board foundation bearing capacity

    Institute of Scientific and Technical Information of China (English)

    刘正伟; 冯鑫

    2014-01-01

    依据相关规范对地下车库或地下室常用的独立基础加防水板的基础形式进行了分析,指出独立基础地基承载力特征值可以用规范规定修正后的数值加防水板所抵抗的净水头压力值作为地基承载力最终的特征值。%This paper analyzed the commonly used independent foundation plus waterproof board foundation to underground garage or basement according to relevant norms, pointed out the independent foundation bearing capacity characteristic value could as the foundation bearing capacity final characteristic value using the value modified by specification plus clear water head pressure value resistance of waterproof board clear water.

  14. 某地下车库独基加防水板的抗浮计算%The anti floating calculation of an underground garage independent foundation and waterproof board

    Institute of Scientific and Technical Information of China (English)

    赵淑英

    2015-01-01

    结合相关理论研究,分析了独立基础与防水板所应单独承担的荷载及计算原则,并根据受力构造要求,对某地下车库独基加防水板基础的抗浮计算进行了详细研究,以供类似工程参考借鉴。%Combining with the related theory research,this paper analyzed the loading and calculation principles of independent foundation and waterproof board,and according to the force structure requirements,researched in detail the anti floating calculation of an underground garage in-dependent foundation and waterproof board,in order to offer reference for similar engineering.

  15. Industrial applications of accelerator-based infrared sources: Analysis using infrared microspectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Bantignies, J.L.; Fuchs, G.; Wilhelm, C. [Elf Atochem, Pierre-Benite (France); Carr, G.L. [Brookhaven National Lab., Upton, NY (United States). National Synchrotron Light Source; Dumas, P. [Centre Univ. Paris-Sud, Orsay (France)

    1997-09-01

    Infrared Microspectroscopy, using a globar source, is now widely employed in the industrial environment, for the analysis of various materials. Since synchrotron radiation is a much brighter source, an enhancement of an order of magnitude in lateral resolution can be achieved. Thus, the combination of IR microspectroscopy and synchrotron radiation provides a powerful tool enabling sample regions only few microns size to be studied. This opens up the potential for analyzing small particles. Some examples for hair, bitumen and polymer are presented.

  16. 防排水施工技术在隧道施工中的应用分析%The Application of Waterproof and Drainage Construction Technology in Tunnel Construction

    Institute of Scientific and Technical Information of China (English)

    程海滨

    2014-01-01

    Tunnel engineering design should fol ow the prin-ciple of “a combination of waterproof, drainage and blocking, local conditions and comprehensive treatment” to achieve the purpose of ensuring the quality of tunnel waterproof and drainage engineering construction. Combining with the mun-icipal roads and related accessory works of Guangzhou new station area, this article simply introduces the application of waterproof and drainage construction technology in the tunnel construction.%隧道工程设计遵循“防、排、截堵相结合,因地制,宜综合治理”的原则,以达到隧道工程防排水施工质量可靠的目的。本文结合广州新客站地区市政道路及相关附属工程,简单介绍了防排水施工技术在隧道施工中的应用。

  17. On development of waterproof materials caused by roof reforestation and its prospect%谈屋顶绿化引发防水材料发展及愿景

    Institute of Scientific and Technical Information of China (English)

    吴凤梅; 屈媚媚; 陈弘

    2015-01-01

    According to the urgent demands for the green architectural development at home and abroad and the appearance of a great deal of roof reforestation currently, the paper analyzes the performance requirement, existing problems and solutions for the waterproof materials of buildings’ roof with the roof reforestation, points out the respective implementation strategies by combining with the crack-resistance siliceous waterproof agent, and has the prospect for the green roof construction and waterproof materials in China, so as to accelerate the development of the green pro-jects in China.%针对国内外绿色建筑发展的迫切需求,以及现阶段大量屋顶绿化的出现,分析了屋顶绿化对于建筑屋面防水材料的性能要求、存在问题、现阶段的解决方式等,并结合抗裂硅质防水剂材料提出了相应的实施对策,同时对我国绿色屋顶建设和防水材料发展进行了展望,以推进屋顶绿化工程的快速发展。

  18. Microbial processes in the final repository, the silo part. Theoretical approach and preliminary experiments on the biodegradation of bitumen. Part 1

    International Nuclear Information System (INIS)

    On Commission of SKBF/KBS the microbial processes that are likely to occur in the silo part of SFR, the final repository for medium- and low-level nuclear wastes, have been put together. The experimental studies concerning microbial degradation of bitumen are described. From a microbial point of view it is the biodegradation of bitumen that constitutes the greatest risk in the silo part of SFR. The degradation, aerobic as well as anaerobic, leads to production of carbon dioxide which might cause a decrease in pH to such an extent that hydrogen-gas producing corrosion of metal could occur. This production of gas can cause an increase in internal pressure of the repository. A culture of bacteria able to degrade bitumen aerobically has been enriched. Uptil now no culture degrading bitumen under anaerobic conditions have been obtained. When making a risk assessment of the SFR at the present time it is not possible to completely disregard the microbial activity. An account is also given for some international contacts in this area. 11 references

  19. Chemical modification of a bitumen and its non-fuel uses. [Reactions of tar sand asphaltenes in synthesis of non-fuel products

    Energy Technology Data Exchange (ETDEWEB)

    Moschopedis, S.E.; Speight, J.G.

    1974-01-01

    Simple reactions are described whereby tar sand bitumen can be converted to a whole range of materials. Examples are given to illustrate the non-fuel uses of the products. The following reactions of Athabasca asphaltenes are considered: oxidation, halogenation, sulfonation and sulfomethylation, phosphorylation, hydrogenation, reactions with S and O, reactions with metal salts, and miscellaneous chemical conversions. (JGB)

  20. Localized enrichment of polycyclic aromatic hydrocarbons in soil, spruce needles, and lake sediments linked to in-situ bitumen extraction near Cold Lake, Alberta

    International Nuclear Information System (INIS)

    The extraction of bitumen from the Alberta oil sands using in-situ technologies is expanding at a rapid rate; however, investigations into the environmental impacts of oil sands development have focused on surface mining in the Athabasca region. We measured polycyclic aromatic hydrocarbons (PAH) in soils, spruce needles, and lake sediment cores in the Cold Lake oil sands region to provide a historical and spatial perspective on PAH contamination related to in-situ extraction activities. A pronounced increase in PAH concentrations was recorded in one of two study lakes (Hilda Lake) corresponding to the onset of commercial bitumen production in ∼1985. Distance from extraction rigs was not an important predictor of PAH concentrations in soils, although two samples located near installations were elevated in alkyl PAHs. Evidence of localized PAH contamination in Hilda Lake and two soil samples suggests that continued environmental monitoring is justified to assess PAH contamination as development intensifies. -- Highlights: •In-situ bitumen extraction linked to rise in alkyl PAHs in one of two study lakes. •Alkyl PAHs elevated in two soil samples. •PAH contamination likely related to effluent sources, not atmospheric deposition. -- PAHs in sediments and soils were generally low in areas adjacent to in-situ bitumen extraction rigs in the Cold Lake Alberta oil sands, but evidence of localized contamination at some sites was evident

  1. Oil-bearing inclusions in vein quartz and kalcite and, bitumens in veins: Testament to multiple phases of hydrocarbon migration in the Barrandian basin (lower Palaeozoic), Czech Republic

    Czech Academy of Sciences Publication Activity Database

    Suchý, V.; Dobeš, P.; Sýkorová, Ivana; Machovič, Vladimír; Stejskal, M.; Kroužek, J.; Chudoba, J.; Matějovský, L.; Havelcová, Martina; Matysová, Petra

    2010-01-01

    Roč. 27, č. 1 (2010), s. 285-297. ISSN 0264-8172 R&D Projects: GA AV ČR(CZ) IAA3012703; GA AV ČR IAA300460804 Institutional research plan: CEZ:AV0Z30460519 Keywords : hydrocarbon * fluid inclusion * bitumen Subject RIV: DD - Geochemistry Impact factor: 2.130, year: 2010

  2. Alberta's reserves 2002 and supply/demand outlook 2003-2012 : crude bitumen, crude oil, natural gas and liquids, coal, sulphur

    International Nuclear Information System (INIS)

    In this document, stake holders find reliable information concerning the state of reserves, supply, and demand for Alberta's energy resources such as bitumen, crude oil, natural gas, natural gas liquids, coal, and sulphur. Estimates of initial reserves, remaining established reserves, and ultimate potential were also included in the report, along with a 10-year supply and demand forecast for Alberta's energy resources. The development of Alberta's energy resources depend on factors such as reserve supply, costs of development, energy demands, conservation, and social, economic and environmental considerations. The energy development landscape in 2002 was determined in large part by changes in energy prices, drilling activity, and planned investments in the range of billions of dollars in oil sands projects. For the first time in 2001, conventional crude oil production was surpassed by raw bitumen production, and this growth continued in 2002. During 2002, 48 per cent of the province's crude oil and equivalent production was in the form of non-upgraded bitumen and synthetic crude oil production. This growth can be explained by increased bitumen production from oil sands mining. Levels similar to those of 2001 were achieved for in situ bitumen production. Approval was recently granted for several steam-assisted gravity drainage (SAGD) schemes, and many are currently under review by the Alberta Energy and Utilities Board (EUB). Higher volumes of commercial production are expected from those schemes in future years. Decline in natural gas production in 2002 was due to less drilling activity, but this is expected to increase in 2003. For the remaining forecast period, production is expected to decline. Continued growth in coalbed methane (CBM) development activity is expected for 2002 and for the next few years. In response to this increased activity, the EUB will begin to calculate CBM reserves. 31 tabs., 66 figs., 3 appendices

  3. Experimental investigation of changes in methane adsorption of bitumen-free Woodford Shale with thermal maturation induced by hydrous pyrolysis

    Science.gov (United States)

    Hu, Haiyan; Zhang, Tongwei; Wiggins-Camacho, Jaclyn D.; Ellis, Geoffrey S.; Lewan, Michael D.; Zhang, Xiayong

    2014-01-01

    This study quantifies the effects of organic-matter (OM) thermal maturity on methane (CH4) sorption, on the basis of five samples that were artificially matured through hydrous pyrolysis achieved by heating samples of immature Woodford Shale under five different time–temperature conditions. CH4-sorption isotherms at 35 °C, 50 °C, and 65 °C, and pressures up to 14 MPa on dry, solvent-extracted samples of the artificially matured Woodford Shale were measured. The results showed that CH4-sorption capacity, normalized to TOC, varied with thermal maturity, following the trend: maximum oil (367 °C) > oil cracking (400 °C) > maximum bitumen/early oil (333 °C) > early bitumen (300 °C) > immature stage (130 °C). The Langmuir constants for the samples at maximum-oil and oil-cracking stages are larger than the values for the bitumen-forming stages. The total pore volume, determined by N2 physisorption at 77 K, increases with increased maturation: mesopores, 2–50 nm in width, were created during the thermal conversion of organic-matter and a dramatic increase in porosity appeared when maximum-bitumen and maximum-oil generation stages were reached. A linear relationship between thermal maturity and Brunauer–Emmett–Teller (BET) surface area suggests that the observed increase in CH4-sorption capacity may be the result of mesopores produced during OM conversion. No obvious difference is observed in pore-size distribution and pore volume for samples with pores 2 physisorption at 273 K. The isosteric heat of adsorption and the standard entropy for artificially matured samples ranged from 17.9 kJ mol−1 to 21.9 kJ mol−1 and from −85.4 J mol−1 K−1 to −101.8 J mol−1 K−1, respectively. These values are similar to the values of immature Woodford kerogen concentrate previously observed, but are larger than naturally matured organic-rich shales. High-temperature hydrous pyrolysis might have induced Lewis acid sites on both organic and mineral surfaces

  4. Reactivity of nitrate and organic acids at the concrete–bitumen interface of a nuclear waste repository cell

    Energy Technology Data Exchange (ETDEWEB)

    Bertron, A., E-mail: bertron@insa-toulouse.fr [Université de Toulouse (France); UPS, INSA (France); LMDC (Laboratoire Matériaux et Durabilité des Constructions), 135, avenue de Rangueil, F-31 077, Toulouse Cedex 04 (France); Jacquemet, N. [Université de Toulouse (France); UPS, INSA (France); LMDC (Laboratoire Matériaux et Durabilité des Constructions), 135, avenue de Rangueil, F-31 077, Toulouse Cedex 04 (France); Erable, B. [Université de Toulouse (France); INPT, UPS (France); CNRS, Laboratoire de Génie Chimique, 4, Allée Emile Monso, F-31030 Toulouse (France); Sablayrolles, C. [Université de Toulouse (France); INP (France); LCA (Laboratoire de Chimie Agro-Industrielle), ENSIACET, 4 allée Emile Monso, BP 44 362, 31432 Toulouse Cedex 4 (France); INRA (France); LCA (Laboratoire de Chimie Agro-Industrielle), F-31029 Toulouse (France); Escadeillas, G. [Université de Toulouse (France); UPS, INSA (France); LMDC (Laboratoire Matériaux et Durabilité des Constructions), 135, avenue de Rangueil, F-31 077, Toulouse Cedex 04 (France); Albrecht, A. [Andra, 1-7, rue Jean-Monnet, 92298 Châtenay-Malabry (France)

    2014-03-01

    Highlights: • Interactions of cement paste and organic acid–nitrate solutions were investigated. • Cement leaching imposed alkaline pH (>10) very rapidly in the liquid media. • Acetic acid action on cement paste was similar to that of classical leaching. • Oxalic acid attack formed Ca-oxalate salts; organic matter in solution decreased. • Nitrate was stable under abiotic conditions and with organic matter. - Abstract: This study investigates the fate of nitrate and organic acids at the bitumen–concrete interface within repository cell for long-lived, intermediate-level, radioactive wastes. The interface was simulated by a multiphase system in which cementitious matrices (CEM V cement paste specimens) were exposed to bitumen model leachates consisting of nitrates and acetic acid with and without oxalic acid, chemical compounds likely to be released by bitumen. Leaching experiments were conducted with daily renewal of the solutions in order to accelerate reactions. The concentrations of anions (acetate, oxalate, nitrate, and nitrite) and cations (calcium, potassium) and the pH were monitored over time. Mineralogical changes of the cementitious matrices were analysed by XRD. The results confirmed the stability of nitrates in the abiotic conditions of the experiments. The action of acetic acid on the cementitious matrix was similar to that of ordinary leaching in the absence of organic acids (i.e. carried out with water or strong acids); no specific interaction was detected between acetate and cementitious cations. The reaction of oxalic acid with the cementitious phases led to the precipitation of calcium oxalate salts in the outer layer of the matrix. The concentration of oxalate was reduced by 65% inside the leaching medium.

  5. Reactivity of nitrate and organic acids at the concrete–bitumen interface of a nuclear waste repository cell

    International Nuclear Information System (INIS)

    Highlights: • Interactions of cement paste and organic acid–nitrate solutions were investigated. • Cement leaching imposed alkaline pH (>10) very rapidly in the liquid media. • Acetic acid action on cement paste was similar to that of classical leaching. • Oxalic acid attack formed Ca-oxalate salts; organic matter in solution decreased. • Nitrate was stable under abiotic conditions and with organic matter. - Abstract: This study investigates the fate of nitrate and organic acids at the bitumen–concrete interface within repository cell for long-lived, intermediate-level, radioactive wastes. The interface was simulated by a multiphase system in which cementitious matrices (CEM V cement paste specimens) were exposed to bitumen model leachates consisting of nitrates and acetic acid with and without oxalic acid, chemical compounds likely to be released by bitumen. Leaching experiments were conducted with daily renewal of the solutions in order to accelerate reactions. The concentrations of anions (acetate, oxalate, nitrate, and nitrite) and cations (calcium, potassium) and the pH were monitored over time. Mineralogical changes of the cementitious matrices were analysed by XRD. The results confirmed the stability of nitrates in the abiotic conditions of the experiments. The action of acetic acid on the cementitious matrix was similar to that of ordinary leaching in the absence of organic acids (i.e. carried out with water or strong acids); no specific interaction was detected between acetate and cementitious cations. The reaction of oxalic acid with the cementitious phases led to the precipitation of calcium oxalate salts in the outer layer of the matrix. The concentration of oxalate was reduced by 65% inside the leaching medium

  6. Carboxymethylated lignins with low surface tension toward low viscosity and highly stable emulsions of crude bitumen and refined oils.

    Science.gov (United States)

    Li, Shuai; Ogunkoya, Dolanimi; Fang, Tiegang; Willoughby, Julie; Rojas, Orlando J

    2016-11-15

    Kraft and organosolv lignins were subjected to carboxymethylation to produce fractions that were soluble in water, displayed a minimum surface tension as low as 34mN/m (25°C) and a critical aggregation concentration of ∼1.5wt%. The carboxymethylated lignins (CML), which were characterized in terms of their degree of substitution ((31)P NMR), elemental composition, and molecular weight (GPC), were found suitable in the formulation of emulsions with bitumens of ultra-high viscosity, such as those from the Canadian oil sands. Remarkably, the interfacial features of the CML enabled fuel emulsions that were synthesized in a very broad range of internal phase content (30-70%). Cryo-replica transmission electron microscopy, which was used here the first time to assess the morphology of the lignin-based emulsions, revealed the droplets of the emulsion stabilized with the modified lignin. The observed drop size (diametersdistribution. Such characteristics led to stable emulsified systems that are amenable for a wide range of applications. Emulsification with CML afforded bitumen emulsions with very high colloidal stability (no change was noted for over one month) and with a strong shear thinning behavior. Both features indicate excellent prospects for storage, transport and spraying, which are relevant in operations for power generation, which also take advantage of the high heating value of the emulsion components. The ability of CML to stabilize emulsions and to contribute in their combustion was tested with light fuels (kerosene, diesel, and jet fuel) after formulation of high internal phase systems (70% oil) that enabled operation of a fuel engine. A significant finding is that under certain conditions and compared to the respective pure fuel, combustion of the O/W emulsions stabilized by CML presented lower NOx and CO emissions and maintained a relatively high combustion efficiency. The results highlight the possibilities in high volume application for lignin

  7. Fast and compact optical-resolution photoacoustic microscopy using a water-proofing two-axis MEMS scanner, and a step forward to clinical applications

    Science.gov (United States)

    Kim, Jin Young; Lee, Changho; Lim, Geunbae; Kim, Chulhong

    2016-03-01

    Optical-resolution photoacoustic microscopy (OR-PAM) is a novel microscopic tool to provide in vivo optically sensitive images in biomedical research. Conventional OR-PAM systems are typically slow and bulky because of the linear scanning stages with stepping motors. For practical purposes, however, fast imaging speed and small footprint are crucial. To address these issues, we have developed a real-time compact OR-PAM system equipped with a waterproof two-axis MEMS scanner. The OR-PAM system consists of key components such as an ultrasonic transducer with a bandwidth of 50 MHz, an opto-acoustic beam combiner (BC), and an MEMS scanner. These are all installed inside a small water tank, with dimensions of 30 mm × 90 mm × 30 mm along the x-, y-, and z-axes, respectively. A pulsed laser with a repetition rate of 50 kHz is confocally aligned with the photoacoustic (PA) waves in the BC to maximize the SNRs. The fast scanning ability of the MEMS scanner fully utilizes the A-scan speed of 50 kHz. For instance, the B- and C-scan imaging speeds are 125 Hz and 0.625 Hz, respectively, when the acquired PA maximum amplitude projection image has 200 × 200 pixels along the x- and y-axes, respectively. The measured lateral resolution of 3.6 μm and axial resolution of 27 μm are sufficient to resolve the small capillaries. Finally, we have successfully obtained in vivo PA images of iris microvasculatures in mice. This real-time and compact OR-PAM system is optimized to examine small animals in clinical studies.

  8. 不同添加剂对防水透湿涂层整理的影响%Effects of different additives on waterproof and moisture permeable coating

    Institute of Scientific and Technical Information of China (English)

    王志佳; 陈英

    2012-01-01

    为了改善芳砜纶/棉混纺织物的涂层效果,在水性聚氨酯涂层胶中加入添加剂羧甲基纤维素(CMC)或海藻酸钠(ALG);通过分析涂层织物的透湿性、淋雨性和硬挺弯曲长度,添加剂CMC的综合效果优于ALG;在含有CMC涂层胶中加入聚乙二醇(PEG)能显著改善织物的透湿性能以及织物手感;当CMC添加量为0.25%,PEG添加量为10%时,涂层织物的透湿量达到6721.5g/(m2·24h),淋雨性为5级,织物弯曲长度为5.51 cm,具有较好的防水透湿性能以及织物手感.%In order to improve the coating properties of polysulfonamide (PSA)/cotton blend fabric, additives such as earboxymethyl cellulose ( CMC) and sodium alginate ( ALG) were added into waterborne polyurethane. By comparing the coating properties like moisture permeability, rain drop repellency and bending length, the results showed that CMC was superior to ALG. Addition of polyethylene glycol (PEG) into the CMC-containing waterborne polyurethane could significantly improve the moisture permeability and hand feeling of the coated fabric. It was found that under the conditions of coating agent with CMC 0. 25% and PEG 10% , moisture permeability of the coated fabric was up to 6 721. 5 g/(m2·24 h) , and bending length of the fabric was 5. 51 cm, with rain drop repellency rating of 5, indicating it had better waterproof, permeability and hand feeling.

  9. Synthesis of quaternary derivatives of ortho-coco di-amido toluene and investigation of these compounds as cationic bitumen emulsifier

    Energy Technology Data Exchange (ETDEWEB)

    Hassanzadeh, Masoumeh; Tayebi, Leila; Dezfouli, Hedieh; Kambarani, Masoud; Avval, Parviz Ahmadi [Tehran Univ. (Iran, Islamic Republic of). ACECR, Designing Chemical Process Research Group

    2012-05-15

    Bitumen emulsions are preferred over conventional pavement systems due to their biologically and environmentally acceptable formulation, safety, low viscosity, storage stability, and cost effectiveness. The present investigation deals with the systematic study to synthesize ortho-cocodi-amido toluene and four quaternary derivatives by amidation of coconut oil and ortho toluene diamine (OTD), followed by quaternization with formaldehyde, formic acid mixture, and acrylonitrile, resulted in a new quaternary compound useful as cationic emulsifier in bitumen emulsions. The roles of temperature and reaction time in determining optimum conditions were investigated as well. Emulsifying behavior of these quaternary compounds was studied by sieve residue test, settlement and storage stability test of emulsified asphalt, and water solubility. The results show that the acrylonitrile imidazolinium derivative of o-cocodi-amido toluene (VI) can be used as a rapid-medium setting emulsifier. (orig.)

  10. Leaching and comprehensive regulatory performance testing of an extruded bitumen containing a surrogate, sodium nitrate-based, low-level waste

    International Nuclear Information System (INIS)

    Performance test results obtained from laboratory testing of an extruded bitumen containing a surrogate, sodium nitrate-based waste are presented. A relatively viscous form of oxidized bitumen (ASTM D 312, Type III) has been tested and has been shown to meet all of the current regulatory performance criteria. Molded specimens were obtained using a 53-mm extruder. A surrogate, low-level, mixed, liquid waste was used. The surrogate waste contained ∼30 weight percent sodium nitrate, in addition to eight heavy metals, cold cesium, and strontium. Waste form specimens contained three levels of waste loading: 40, 50, and 60 weight percent salt. Results include thermal testing, extraction procedure toxicity tests, and 90-day American Nuclear Society 16.1 leach tests, as well as compressive strength tests

  11. Study on the Waterproof and Breathable Properties of Polyether/Polyester Hydrophilic Polyurethane%聚醚/聚酯型亲水性聚氨酯防水透湿性能研究

    Institute of Scientific and Technical Information of China (English)

    权衡; 倪丽杰; 姜会钰; 黎谦; 涂超

    2013-01-01

    Six groups of segmented waterproof and breathable hydrophilic polyurethanes coatings based on mixed polyether or polyether/polyester hydrophilic soft monomers were prepared using 4,4'-diphenylmethane diisocyanate (MDI) and 1,4-butanediol (BDO) as hard segments.Furthermore,the effect of microstructure and soft segment on moisture permeability and water resistance of the hydrophilic polyurethanes was researched.The results showed that some factors had remarkable effects on the waterproof and breathable,including the soft segment structure,composition,molecular weight,concentration and the degree of microphase separation.The most important factor on waterproof and breathable of hydrophilic polyurethane was the soft segment hydrophilic and activity.%以4,4'-二苯基甲烷二异氰酸酯(MDI)和1,4-丁二醇(BDO)为硬单体,制备了6组聚醚与聚酯或不同聚醚混合单体为软链段的嵌段型亲水性聚氨酯防水透湿涂层剂.研究了聚氨酯材料的微结构和软段结构对其防水、透湿性能的影响.结果表明,亲水性聚氨酯软链段的结构、组成、相对分子质量和含量及软、硬段相区间的微相分离程度对材料防水透湿性能的影响较大,亲水性聚氨酯的防水透湿性能主要取决于其中亲水性软链段的亲水性及其活动性.

  12. FORECASTING OF DURABILITY OF THE LAYER OF SUPERFICIAL PROCESSING OF ROAD COVERINGS ON THE BASIS OF THE MODIFIED BITUMENS WITH APPLICATION OF NEURAL NETWORKS

    Directory of Open Access Journals (Sweden)

    E. B. Tyukov

    2009-01-01

    Full Text Available The opportunity of application of system of neural networks for forecasting durability of a layer of superficial processing of road coverings is considered. The offered technique of definition of efficiency of application of any additive in-tended for improvement of properties of bitumens at the device of layers of su-perficial processing of road coverings allows to receive the most authentic fore-cast of safety of a layer.

  13. Effect of non-homogeneous spatial distributions of surfactants on the stability of high-content bitumen-in-water emulsions

    International Nuclear Information System (INIS)

    In order to study the effects of non-homogeneous spatial distributions of surfactants on the drop size of high-content bitumen-in-water emulsions, a modification of a standard Brownian Dynamics algorithm was employed. The new algorithm is able to simulate the evolution of oil/water emulsions towards flocculation and coalescence. The simulation boxes contain 216 and 125 particles initially distributed in a homogeneous simple cubic arrangement, corresponding to bitumen/water volume fractions of 0.30 and 0.51, respectively. The particles interact through a DLVO potential dependent on the total surfactant concentration, spatial surfactant distribution, and the amount of surfactant adsorbed to the bitumen/water interface. As will be shown in this article, certain combinations of the referred variables can produce a wide variety of repulsive potentials between similar drops. The variation of the total number of drops with time does not obey the usual analytical formalisms developed for more diluted cases, and instead, a simple exponential decrease of the number of drops with time is found. Such behavior has already been confirmed by experiment. Some similarities between the present results and those previously published for more diluted systems are discussed

  14. Investigation of the possibility of decontamination of bitumen concrete pavement contaminated with radionuclides

    International Nuclear Information System (INIS)

    Radioactive contamination of the environment is possible during operation of nuclear power plants and the utilization of radionuclide sources in the economy. The problem of decontaminating the surfaces of industrial objects and environmental objects which are contaminated by radionuclides can be solved by different methods of depending on the character of the object: chemical treatment of metallic surfaces of equipment parts by application of different washing fluids, mechanical removal of contaminants or washing contaminants off with a jet of liquid, as well as adding different abrasive additives, the use of film-forming substances for sorption and removal of the decontaminating layer from the surface being cleaned, and other methods

  15. Native bitumens in surficial soils of the Athabasca oil sands region : preliminary characterization and assessment of contaminant mobility

    Energy Technology Data Exchange (ETDEWEB)

    Fleming, M.; Fleming, I. [Saskatchewan Univ., Saskatoon, SK (Canada). Dept. of Civil and Geological Engineering; Headley, J. [Environment Canada, Saskatoon, SK (Canada). National Hydrology Research Centre

    2009-07-01

    A study was conducted on bitumen tarballs located in surficial soils in Alberta's Athabasca region. The tarballs occur in every soil type in the region, and pose a challenge to oil sands operators who hope to use the soils for reclamation activities. Chromatographic analyses have shown that the tarballs contain variable petroleum hydrocarbon concentrations and possess a characteristic chromatographic footprint. The Canadian Council of Ministers of the Environment has characterized the hydrocarbons according to various fractions. A soil-column leaching study is also being conducted by the University of Saskatchewan on heavily-impacted tarball soil under unsaturated conditions. Results of the study have indicated that the soil has low levels of contaminant mobility and degradation. Hydrocarbon concentrations in leachate water are less than 20 per cent of ground water guidelines for Alberta. It was concluded that after respiration over 9 months, the most active soil column in the study degraded only 2.7 g of an estimated 650 g.

  16. Nailing tailings : researchers close in on innovative ways to speed up reclamation of bitumen mine tailings ponds

    Energy Technology Data Exchange (ETDEWEB)

    Harrison, L.

    2009-09-15

    This article reviewed the collaborative research that is ongoing at the Canadian Oil Sands Network for Research and Development (CONRAD). Directive 74 issued by the Alberta Energy Resources Conservation Board stipulates that oilsand operators must accelerate their pace at developing tailings technologies. It requires the reduction of fluid tailings and their capture in ERCB-approved dedicated disposal areas. CONRAD's tailings consortium has representation from the 4 existing oilsands operators, namely Suncor Energy Inc., Syncrude Canada Ltd., Shell Canada Limited and Canadian Natural Resources Limited (CNRL), as well as 3 companies with proposed projects. Technologies being considered include water capping, centrifugation, composite tails, mature fine tailings (MFT) drying, accelerated dewatering and the use of carbon dioxide (CO{sub 2}). CO{sub 2} works chemically works on the fluid fine tails to create consolidated tailings, using MFT in the mix. Operators have the added advantage of receiving some credit for the CO{sub 2} that is sequestered in the tailings. These new processes are designed to reduce the footprint of the tailings pond, and by increasing the amount of water available for recycling, decrease the amount of river water needed to process bitumen. 3 figs.

  17. Portable instrument for acquisition and processing data from radiometric experiments performed in the field industrial conditions

    International Nuclear Information System (INIS)

    To facilitate radiotracer investigations in field or industrial environment a battery operated FIR-1 Field Industrial Radiometer has been developed. The radiometer is equipped with 4 splash-proof NaI(Tl) operating in counting mode, 4 water-proof GM probes, 1 splash-proof spectrometric scintillation probe NaI(Tl) Φ50 x 50 mm equipped with 256 channel analyser. The detectors are connected to controller by means of 4 water-proof connecting cables 100 m long, or 4 splash-proof connecting cables 100 m long. Pulses originating from gamma radiation are periodically counted and stored in non-volatile memory. The measured count rate against time is displayed on graphic display. Radiation spectra measured with spectrometric probe are also stored in the memory and are displayed on graphic display. Total count number in selected range of energy of the spectrum can be computed. Stored in memory measuring data are transmitted to an external computer employing serial port RS232. (author)

  18. Foreign investment opportunities in the Venezuelan upstream industry

    International Nuclear Information System (INIS)

    An overview is provided of the Venezuelan petroleum industry, and the advantages of Venezuela for petroleum industry investment are noted. Proven reserves of hydrocarbons consist of 64 billion bbl of oil and condensates, 3.7 trillion m3 of natural gas, and some 270 billion bbl of recoverable oil from vast reserves of heavy oil and bitumen. Additional reserves of light and medium crude awaiting discovery are estimated at 40 billion bbl. The state petroleum company PDVSA plans to increase proven reserves and to raise oil production capacity from the present level of 2.8 million bbl/d to 4 million bbl/d. To achieve those increases, it is estimated that PDVSA will need to invest ca $40 billion by the year 2000, of which $28 billion will come from PDVSA's own resources. It is intended that the remainder of the investment will be from foreign enterprises as part of joint ventures. PDVSA already has experience with joint ventures in the refining and petrochemical sectors, and a PDVSA subsidiary, Lagoven, is conducting a natural gas export project with several foreign firms. Another subsidiary, Maraven, is engaging in the first of several ventures to exploit the extensive heavy oil resources of the Orinoco belt. Foreign firms are also acting as contractors to reactivate inactive oil fields. PDVSA also markets Orimulsion, a bitumen-based emulsion fuel which competes with coal as a boiler fuel, through its joint venture subsidiary BITOR

  19. The composite waterproof and facing integration construction technology of large outdoor stands%大型室外看台复合防水及饰面一体化施工技术

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    This paper described the design principle and its advantages of outdoor stands composite waterproof and facing integration construction technology,introduced in detail the basic cleaning,detail process,brushing primer sealer,polyurea spraying construction and other process,and proposed corresponding improvement strategy according to existing problems in construction application,in order to ensure the waterproof effect and use function of outdoor stands.%阐述了室外看台复合防水及饰面一体化施工技术的设计原理及其所具有的优势,对基层清理、细部处理、涂刷封闭底漆、聚脲喷涂施工等工艺流程进行了详细介绍,并针对施工应用中存在的问题,提出了相应的改进策略,以保证室外看台的防水效果及使用功能。

  20. Application Research of Self-compact and Self-waterproofing Concrete in Underground Engineering%地下工程自密实自防水混凝土应用研究

    Institute of Scientific and Technical Information of China (English)

    叶勇; 杨大志; 易永臻

    2011-01-01

    针对地下工程泵送混凝土施工时易产生裂缝、渗水现象,采用粉煤灰、膨胀剂、缓凝高效减水剂"三掺"技术,优化配合比设计,配制自密实混凝土,有效控制裂缝,以达到自防水目的。试验研究和工程实践表明:复合外掺剂有效地提高了混凝土流动性,增加了混凝土的密实度,提高了混凝土的抗渗性能,满足地下工程结构自防水的设计要求。%Against the problems of crack and water penetration during underground construction using pump concrete,with the admixture of fly ash,expansion agent and retarded high range water-reducing agent,the proportion design is optimized and self-compact concrete is prepared in order to control the crack and meet the requirement of self-waterproofing.Through the laboratory test and engineering practice,it is proven that compound mixed agent effectively improved the fluidity and compactness of concrete,and thus improved the impermeability of concrete,which satisfied the design requirement of self-waterproofing of underground structure.

  1. 倾斜煤层防水煤岩柱尺寸留设的技术优化研究%Research on reasonable size of waterproof pillar in mining inclined coal seam

    Institute of Scientific and Technical Information of China (English)

    王志强; 陈超凡; 王磊; 李鹏飞; 郭晓菲; 高运

    2013-01-01

    采用传统方法对4#煤层需要留设的防水煤岩柱尺寸进行计算,分析结果认为传统方法对于倾斜煤层防水煤柱中央弹性核区存在重复计算的问题,因此造成留设的防水煤柱尺寸偏大。为了改善传统方法存在的弊端,在保证安全的前提下对4#煤层屈服区尺寸进行计算并考虑覆岩移动角度的影响,得到设计方法优化后的防水煤岩柱尺寸。为了进一步提高采区回采率,综合分析煤柱留设的共性问题,提出巷道布置的优化方案。研究结果表明,设计优化后留设防水煤柱的尺寸仅为原方法的42.42%,综合起坡段带来的三角煤损结合防水煤岩柱尺寸,优化后的煤炭损失仅为原方法煤炭损失的45.42%,按照采区设计的推进长度计算,相邻工作面之间可多采出煤炭资源近1.58 Mt。另外,优化方案中起坡段回采工艺可以改善工作面倾角大带来的设备稳定性的问题。%In the study, we calculated the pillar size of 4# coal seam with the traditional method, the analysis result showed that repeated calculation was existed in calculation of the central elastic area of the waterproof pillar in inclined seam, which results in oversized waterproof pillar left. In order to im-prove the disadvantages of traditional methods, in the premise of ensuring safety, we calculated the yield zone size of 4# seam, considered the impact of the overburden rock moving angle and we obtained the reasonable waterproof pillar size after the design method had been optimized. In order to further im-prove the recovery rate in the mining area, we comprehensively analyzed the common problems of coal pillar design and proposed optimization. Findings showed that the size of waterproof coal pillars after the design was optimized is only 42.42%of the size calculated in traditional method. Integrated the tri-angle coal loss of the slope segment and combined with a waterproof coal pillar size, coal

  2. Measurements of the speed of sound and the absorption coefficient for ion exchange resin embedded in concrete and bitumen using ultrasonic waves at around 0.1 MHz

    International Nuclear Information System (INIS)

    Ultrasonic measurements have been carried out on concrete and bitumen containing ion exchange resin. The speed and absorption of sound was determined for different amounts of resin, different times after preparation of the samples, and for different temperatures. The absorption data indicate that it should be possible to use the technique on full-scale waste products. The data also indicate that the velocity of sound is sensitive to several parameters of interest in radioactive waste treatment and storage. The technique may also be used to gain information on the internal disposition of a waste package. (Auth.)

  3. Numerical Study on Waterproof Failure Mechanism of Elastic Sealing Gasket of Underwater Shield-bored Tunnel%水下盾构隧道弹性密封垫防水失效数值模拟研究

    Institute of Scientific and Technical Information of China (English)

    王湛

    2015-01-01

    In the paper,numerical simulation study is made on the waterproof failure mechanism of elastic sealing gaskets by means of ABAQUS program,with the design of the waterproof system of an underwater shield-bored tunnel as example.The finite element model used in the paper is compared with the previous simplified model,and the waterproof failure mechanism of elastic sealing gaskets in the case of joint opening and that in the case of joint staggering are analyzed respectively.Conclusions drawn are as follows:1 )In the case of joint opening,the water leakage mainly occurs at the contact surface between the sealing gaskets;2)In the case of joint staggering,the water leakage at the contact surface between the sealing gaskets turns into water leakage at the contact surface between the sealing gasket and the concrete segment as the staggering displacement grows.%结合某水下盾构隧道工程的防水设计,采用大型有限元软件 ABAQUS 对弹性密封垫的防水失效机理进行数值模拟研究。将本文有限元模型与前人简化模型进行了对比分析,并对接缝张开及接缝错开情况下的密封垫防水失效机理进行了分析。研究表明,在接缝张开的情况下,渗漏主要发生在密封垫间的接触面上;接缝错开的情况下,随错缝位移的增大,渗漏将由发生在密封垫接触面上而转变为发生在密封垫与混凝土间的接触面上。

  4. Identification of organic sulfur compounds in coal bitumen obtained by different extraction techniques using comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometric detection

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Maria Elisabete; Cappelli Fontanive, Fernando; Bastos Caramao, Elina; Alcaraz Zini, Claudia [Universidade Federal do Rio Grande do Sul, Instituto de Quimica, Porto Alegre, RS (Brazil); Oliveira, Jose Vladimir de [URI, Universidade Regional Integrada do Alto Uruguai e das Missoes, Erechim, RS (Brazil)

    2011-11-15

    The determination of organic sulfur compounds (OSC) in coal is of great interest. Technically and operationally these compounds are not easily removed and promote corrosion of equipment. Environmentally, the burning of sulfur compounds leads to the emission of SO{sub x} gases, which are major contributors to acid rain. Health-wise, it is well known that these compounds have mutagenic and carcinogenic properties. Bitumen can be extracted from coal by different techniques, and use of gas chromatography coupled to mass spectrometric detection enables identification of compounds present in coal extracts. The OSC from three different bitumens were tentatively identified by use of three different extraction techniques: accelerated solvent extraction (ASE), ultrasonic extraction (UE), and supercritical-fluid extraction (SFE). Results obtained from one-dimensional gas chromatography (1D GC) coupled to quadrupole mass spectrometric detection (GC-qMS) and from two-dimensional gas chromatography with time-of-flight mass spectrometric detection (GC x GC-TOFMS) were compared. By use of 2D GC, a greater number of OSC were found in ASE bitumen than in SFE and UE bitumens. No OSC were identified with 1D GC-qMS, although some benzothiophenes and dibenzothiophenes were detected by use of EIM and SIM modes. GC x GC-TOFMS applied to investigation of OSC in bitumens resulted in analytical improvement, as more OSC classes and compounds were identified (thiols, sulfides, thiophenes, naphthothiophenes, benzothiophenes, and benzonaphthothiophenes). The roof-tile effect was observed for OSC and PAH in all bitumens. Several co-elutions among analytes and with matrix interferents were solved by use of GC x GC. (orig.)

  5. Preparation of High Performance Polyurethane Waterproof Coating for Railway Bridge%铁路桥梁用高性能聚氨酯防水涂料的研制

    Institute of Scientific and Technical Information of China (English)

    崔定伟; 陈小庆; 王军; 宋欢欢

    2011-01-01

    采用自制预聚物、液体填料、固化剂、颜填料等按一定比例混合均匀制备高性能聚氨酯防水涂料。探讨了异氰酸酯含量、—NCO和活性H当量比、液体填料和固化剂配比、以及填料加量的不同等对聚氨酯防水涂料综合性能的影响。%High performance polyurethane waterproof coating was prepared by using the self-made prepolymer,liquid filler,curing agent,pigments,fillers and others mixed according to a certain proportion.The influence of isocyanate content,ratio of NCO,—NCO and activi

  6. 表面防水处理对机场混凝土道面耐久性的影响%The Impact of Surface Waterproofing Treatment on the Durability of Airport Concrete Pavement

    Institute of Scientific and Technical Information of China (English)

    朱剑; 袁捷

    2011-01-01

    文章通过抗渗、冻融、化学侵蚀试验及现场摩擦系数测试,研究了涂刷两种新型混凝土保护剂进行表面防水处理对机场混凝土道面耐久性的影响。结果表明:两种混凝土保护剂均能大幅改善混凝土的抗渗性能,降低混凝土冻融后的动弹性模量损失以及道面除冰液侵蚀下的强度损失,且不影响道面的抗滑性能。通过涂刷新型混凝土保护剂进行表面防水处理是提高混凝土道面耐久性的有效方法。%Through tests on impermeability,freeze thawing,chemical attack and on field friction factor,the article studied the impact of using two new concrete protective agents to perform surface waterproofing treatment on the durability of airport concrete pavement.The result shows that these two agents can improve the impermeability of concrete,decrease the loss of dynamic modulus of elasticity after freeze thawing and the loss of strength after corrosion caused by deicing fluid.It does not affect the anti-resistance of pavement.It is proved that using the new concrete protective agent to perform surface waterproofing treat-ment is an efficient way to improve the durability of concrete pavement

  7. Implication of cytochrome P-450 1A isoforms and the AH receptor in the genotoxicity of coal-tar fume condensate and bitumen fume condensates.

    Science.gov (United States)

    Genevois, C; Pfohl-Leszkowicz, A; Boillot, K; Brandt, H; Castegnaro, M

    1998-06-01

    During the hot application of bitumen- or coal-tar-containing materials, fumes are emitted that contain polycyclic aromatic compounds. Although workers' exposure to these fumes is low, it might lead to health problems. No study has reported the metabolic pathways involved in the genotoxicity of coal tar or bitumen fume condensates (CTFC, BFCs). We have therefore studied the DNA adducts formed by incubation of CTFC or BFCs with liver microsomes from several type of mice and with yeast microsomes expressing individual human CYP enzymes. Our results demonstrates that: (1) the aryl hydrocarbon receptor (AHR) plays an important role in the biotransformation of BFCs and to a lesser extent of CTFC; (2) for CTFC, both cytochrome P450 (CYP) 1A isoforms are involved in the formation of genotoxic compounds, and the reactive metabolites formed via CYP 1A1, are substrates for epoxide hydrolase (mEH); (3) for BFCs, the genotoxicity is partially dependent upon CYP 1A1 and the reactive metabolites are not substrates for mEH; (4) CYP 1A isoforms are not exclusively responsible for the genotoxicity of the CTFC and BFCs as other CYPs and also enzymes of the [AH] gene battery, may play an important role. PMID:21781875

  8. Alberta's reserves 2001 and supply/demand outlook 2002-2011 : crude bitumen, crude oil, natural gas and liquids, coal, sulphur

    International Nuclear Information System (INIS)

    This document provides stakeholders with a reliable source of information on the state of reserves, supply and demand for Alberta's energy resources including crude bitumen, crude oil, natural gas, natural gas liquids, sulphur and coal. The report also includes estimates of initial reserves, remaining established reserves, and ultimate potential. A 10-year supply and demand forecast for Alberta's energy resources is also presented. The economic factors that determine the development of Alberta's energy resources depend on resource supply, development costs, energy demand, conservation and environmental and social considerations. Energy development in 2001 was driven in part by changes in energy prices, drilling activity and planned investments of billions of dollars in the oil sands projects. Production of raw bitumen exceeded conventional crude oil for the first time in 2001, with the first commercial steam-assisted gravity drainage (SAGD) production. Several SAGD schemes have been approved and more are under review. Although natural gas production is expected to decline in the second half of the forecast period, interest in coalbed methane development will likely increase. Alberta has the largest oil sands resource in the world, with nearly 50 billion cubic meters that are potentially recoverable. Alberta's remaining established reserves of conventional crude oil was estimated at 278 million cubic metres. 35 tabs., 55 figs., 3 appendices

  9. Strategic human resources study of the upstream petroleum industry : the decade ahead

    International Nuclear Information System (INIS)

    This report presents the results of a 10 month study of the human resources issues in Canada's upstream petroleum industry. The study identifies workforce demographics, skills, and supply and demand. It also discusses the impact of technology and other key challenges facing human resources issues. The upstream petroleum industry includes exploration and production, service industries, pipeline transmission, natural gas processing, and heavy oil and bitumen extracting and upgrading. The study defined four regions in Canada: Western Canada Sedimentary Basin, the oil sands, the north, and the east coast. The main influences on the management practices within the upstream petroleum industry are: globalization; cyclical economic conditions; operational excellence business models; government regulatory requirements; stakeholder expectations for involvement; technological advances; changing demographics, and workplace skills. The study also presented suggestions for changes in best practices to improve the efficiency and effectiveness of product and service delivery. refs., tabs., figs

  10. 40 CFR 60.591 - Definitions.

    Science.gov (United States)

    2010-07-01

    ... Bitumen) is a black or dark brown solid or semi-solid thermo-plastic material possessing waterproofing and... compressor contains a process fluid that meets the conditions specified in § 60.593(b). In light...

  11. Inhibition of the radiolytic hydrogen production in the nuclear waste of 'bitumen coated' type: study of the interaction between hydrogen and cobalt hydroxo-sulphide

    International Nuclear Information System (INIS)

    In the nuclear field in France, the bitumen is mainly used for the conditioning of the radioactive muds generated by the fuel reprocessing. However, the self-irradiation of the bitumen induces a production of hydrogen which generates safety problems. The comparison of various storage sites showed that the presence of cobalt hydroxo sulphide limited such a production. Consequently, this compound was regarded as an 'inhibitor of radiolytic hydrogen production'. However, the origin of this phenomenon was not clearly identified. In order to propose an explanation to this inhibition phenomenon, model organic molecules were used to represent the components of the bitumen. Irradiations were carried out by protons to simulate the alpha radiolysis. The organic molecules irradiations by a proton beam showed that cobalt hydroxo sulphide CoSOH, does not act as a hydrogenation catalyst of unsaturated hydrocarbons, nor as a radicals scavenger, but consists of a trap of hydrogen. Experiments of hydrogen trapping at ambient temperature were carried out according to two techniques: gravimetry and manometry. The solid was characterized before and after interaction with hydrogen (infrared and Raman spectroscopies, X-ray diffraction). The initial solid was composed of amorphous cobalt hydroxo sulphide and a minor phase of cobalt hydroxide. The gravimetry and manometry experiments showed that the maximum of hydrogen trapping capacity is equal to 0.59 ± 0.18 mole of hydrogen per mole of cobalt. After interaction with hydrogen, the Co(OH)2 phase disappeared and a new solid phase appeared corresponding to Co9S8. These observations, as well as the analysis of the gas phase, made it possible to conclude with the following reaction (1): 9 CoSOH + 11/2 H2 = Co9S8 + 9 H2O + H2S (1). Gravimetry experiments at temperatures between 50 and 210 C revealed the desorption of water but not of hydrogen sulphide. The absence of hydrogen sulphide in gaseous phase and the Co(OH)2 phase disappearance

  12. Industry Employment

    Science.gov (United States)

    Occupational Outlook Quarterly, 2012

    2012-01-01

    This article illustrates projected employment change by industry and industry sector over 2010-20 decade. Workers are grouped into an industry according to the type of good produced or service provided by the establishment for which they work. Industry employment projections are shown in terms of numeric change (growth or decline in the total…

  13. A multiple lines of evidence approach for the ecological risk assessment of an accidental bitumen release from a steam assisted gravity drainage (SAGD) well in the Athabasca oil sands region.

    Science.gov (United States)

    Berger, Robert G; Aslund, Melissa Whitfield; Sanders, Greg; Charlebois, Michael; Knopper, Loren D; Bresee, Karl E

    2016-01-15

    To assess the ecological impacts of two independent accidental bitumen releases from two steam assisted gravity drainage (SAGD) wells in the Athabasca oil sands region, a multiple lines of evidence (LOE) approach was developed. Following the release in 2010, action was taken to minimize environmental impact, including the selective removal of the most highly impacted vegetation and the use of oil socks to minimize possible runoff. An ecological risk assessment (ERA) was then conducted based on reported concentrations of bitumen related contaminants in soil, vegetation, and water. Results of biological assessments conducted at the site were also included in the risk characterization. Overall, the conclusion of the ERA was that the likelihood of long-term adverse health effects to ecological receptors in the area was negligible. To provide evidence for this conclusion, a small mammal sampling plan targeting Southern red-back voles (Myodes gapperi) was carried out at two sites and two relevant reference areas. Voles were readily collected at all locations and no statistically significant differences in morphometric measurements (i.e., body mass, length, foot length, and adjusted liver weight) were found between animals collected from impact zones of varying levels of coverage. Additionally, no trends corresponding with bitumen coverage were observed with respect to metal body burden in voles for metals that were previously identified in the source bitumen. Hepatic ethoxyresorufin-O-deethylase (EROD) activity was statistically significantly elevated in voles collected from the high impact zones of sites compared to those collected from the reference areas, a finding that is indicative of continued exposure to contaminants. However, this increase in EROD was not correlated with any observable adverse population-wide biological outcomes. Therefore the biological sampling program supported the conclusion of the initial ERA and supported the hypothesis of no significant

  14. Industrial Chain: Industrial Vertical Definition

    Institute of Scientific and Technical Information of China (English)

    YifeiDu; GuojunJiang; ShimingLi

    2004-01-01

    Like value chain and supply chain, “industrial chain” becomes the focus of attention. The implication of “industrial chain” has gained a large range of extension. It not only expresses the industrial “chain” structure and relationship of “back and forward”in order or “up and down” in direction, but also it represents a cluster of large scale of firms in an area or colony. It is a network, or a community. Consequently, we conclude that “industrial chain” is a synthesis of industrial chain, industrial cluster, or industrial network.In this article, firstly we will distinguish industry chain from industry. An industry is the collection of firms that have the same attribute, so an industry can be defined by firm collection of certain attribute. We indicate that industrial chain is a kind of vertical and orderly industrial link. It is defined according to a series of specific product or service created. Secondly we analyze the vertical orderly defiinition process from the aspects of social division of labor and requirement division, self-organization system, and value analysis.Non-symmetry and depending on system or community of large scale of industrial units lead to entire industry to “orderly” structure. On the other hand, the draught of diversity and complexity of requirement simultaneously lead to entire industry to be more “orderly”. Along with processes of self-organization, industrial will appi'oach the state of more orderly and steady, and constantly make industrial chain upgrade. Each firm or unit, who will gain the value, has to establish channels of value, which we called “industrial value chain”. Lastly,we discuss the consequence of vertical and orderly definition, which is exhibited by a certain relationship body. The typical forms of industrial chain include industrial cluster, strategy alliance and vertical integration etc.

  15. Evaluation of pulp and mortar to pack bitumen radioactive waste; Avaliacao de pastas e argamassas para o embalado de rejeitos radioativos betuminizados

    Energy Technology Data Exchange (ETDEWEB)

    Gregorio, Marina da S.; Vieira, Vanessa M.; Tello, Cledola C.O., E-mail: msg@cdtn.br, E-mail: vanessamotavieira@gmail.com, E-mail: tellocc@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2013-07-01

    According to international experience, for the deposition of cement in surface repository, is necessary the use of cement mortar pastes to immobilize the product. Determining the most efficient folder or for the packed mortar, as well as its ideal formulation, is the goal of this study. To do various experiments with samples of cement paste and mortar, with presence of fluxing and / or clay were performed. Viscosity, density, setting time and compressive strength were evaluated. This study will be presented only the results found in testing of compressive strength to be an essential parameter in the transport, storage and disposal of the product. From the results found will be selected the best formulations for use in packed bitumen tailings from the National Radioactive Waste Repository.

  16. Underwater behaviour of bitumen coated radioactive wastes: experimental validation of the Colonbo degradation model; Comportement sous eau des dechets radioactifs bitumes: validation experimentale du modele de degradation Colonbo

    Energy Technology Data Exchange (ETDEWEB)

    Gwinner, B

    2004-03-01

    In the release scenario considered for geologic repository, water is thought to be the main aggressive agent with regards to bituminized radioactive waste (composed in general of 60 weight % of bitumen, 40% of soluble/insoluble salts and a few ppm of radionuclides). Since liquid water can diffuse in pure bitumen, leaching of bituminized waste results in the dissolution of the most soluble salts and leads to the development of a more or less concentrated saline solution-filled pore structure (called permeable layer). In consequence of the generation of a porous layer in the bituminized waste, leaching of salts and radionuclides can then take place. Research performed at the Atomic Energy Commission (CEA) aims therefore at understanding the consequences of ground-water immersion on the transport properties and radionuclides leaching of bituminized waste materials. To this end, a constitutive model (called COLONBO) which describes mathematically the leaching of bituminized waste has been developed. The COLONBO model is based on the following assumptions: 1. Water and dissolved salts migrate in the permeable layer according to Fick's first law. The diffusion of water and salts are quantified by effective diffusion coefficients which are unknown. 2. The mechanical properties of the bitumen matrix are not considered during leaching (free swelling). Up to now, the COLONBO model has been used only to model experimental water uptake and salt leach curves, leading (theoretical) estimates of the effective diffusion coefficients of water and salts in the permeable layer. The aim of this work was to validate experimentally the numerical results obtained with the COLONBO model. First, the correspondence between experimental and simulated water uptake and salt leach rates obtained on various bituminized waste materials is checked, leading estimates of the effective diffusion coefficients of water and salts in the permeable layer. Second, the evolution of the thickness and of

  17. Processing of tailings in Canadian oil sands industry

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Vast amounts of tailings are produced daily in bitumen extraction from the Athabasca oil sands. The coarse sand from the tailings stream is used to build dykes around the containment basin. The run-off slurry arrives at the water's edge in the tailings pond at a solids concentration of about 3%~8% by mass. Settling of the solids takes place "relatively fast", over several days, creating a "free water zone" that contains little solids. When the fine mineral solids concentration has reached about 15% by mass, the suspension develops non-Newtonian properties. After 2~3 years, the suspension concentration reaches a value of about 30% by mass at which the settling rate becomes extremely slow. Methods to handle the already created tailings ponds and new approaches to eliminate the creation of new ones will be discussed both from the industrial and fundamental prospective.

  18. The oil and gas industry and the Canadian economy: a backgrounder

    International Nuclear Information System (INIS)

    The technological and economic significance of the Canadian petroleum industry to the national economy and to Canada's standing in the world are reviewed. The six key ways in which the oil and gas industry affects Canada, namely employment, balance of trade, products, government revenues, international technology trade and community support are stressed within the context of describing present and future oil and gas resources, Canada's petroleum and natural gas trade balance, and capital spending and product sales. Attention is also drawn to the role of the Canadian petroleum and natural gas industry as a producer and exporter of world class technology, especially in the areas of high tech exploration methods, cold-climate and offshore operations, enhanced recovery techniques, heavy oil production and and processing, mining and upgrading of oil sands bitumen, oil well firefighting, and environmental protection technology. maps, figs

  19. Upstream petroleum industry flaring report for year ending December 31, 2000

    International Nuclear Information System (INIS)

    A summary of flared volumes for the various oil and gas industry sectors including well tests, gas plants, gas gathering systems and batteries were presented in this report along with data on solution gas conserved, flared and vented in Alberta during 2000. This report is published in response to a commitment that the Alberta Energy and Utilities Board (EUB) made to ensure that flaring data is more accessible to the public and industry. The data included in the report is based on information submitted by companies. The information is tabulated and operators are ranked based on solution gas flared, solution gas vented, total gas produced, and total oil from crude oil and crude bitumen batteries. The report demonstrates the significant progress industry has made towards reducing solution flare gas and vent volumes in the province. The volume of solution gas flared and vented in Alberta decreased by 38 per cent in 2000. tabs

  20. Process water treatment in Canada's oil sands industry : 2 : a review of emerging technologies

    International Nuclear Information System (INIS)

    This review was conducted to identify candidate treatment technologies for treating oil sands process water. The oil sands industry in Canada uses large volumes of fresh water in order to extract bitumen deposits. The development of process water treatment technologies has become a critical issue for the industry, particularly as oil sand production is expected to triple in the next decade. However, treatment technologies must be adapted to consider the fouling potential of bitumens and fine clays as well as the effect of alkaline process water on treatment performance. The review included developments in chemical modifications to membranes and adsorbents designed to improve pollutant removal and reduce fouling; hybridization technologies designed to enhance the biological treatment of toxic feedwaters; recent advances in photocatalytic oxidation technologies for organic compounds; and new designs for large-scale treatment wetlands for polluted waste waters. It was concluded that major knowledge gaps must be optimized and preliminary studies must be conducted in order to understand how the treatment technologies will be affected by the chemical and physical characteristics of oil sands process water. 188 refs., 8 tabs

  1. 在仓房屋面喷涂菲柯特防水隔热涂料进行控温储粮实验报告%The report of the experiment that spraying Feikete waterproof paint on the warehouse roof to insulated temperature of stored grain

    Institute of Scientific and Technical Information of China (English)

    陈诗学; 张翠华

    2012-01-01

    在仓房屋面喷涂菲柯特防水隔热涂料后,在夏季,对仓温、表层粮温和全仓平均粮温进行检测记录,同时记录气温。试验结果表明,在仓房屋面喷涂菲柯特防水隔热涂料可以有效控制仓温和粮温随气温上升的速度和上升幅度,是一种低成本的控温储粮方法。%After spraying Feikete waterproof paint on the warehouse roof, in summer, record warehouse temperature, grain surface temperature and average grain temperature. The experimental results showed that spraying Feikete waterproof paint on the warehouse roof could effectively control grain warehouse temperature and grain temperature moderate rise with the temperature increase in the speed and in the degree, spraying Feikete waterproof paint on the warehouse roof is a low-cost method of temperature control in stored grain.

  2. Industrial Engineering

    DEFF Research Database (Denmark)

    Karlsson, Christer

    2015-01-01

    Industrial engineering is a discipline that is concerned with increasing the effectiveness of (primarily) manufacturing and (occasionally).......Industrial engineering is a discipline that is concerned with increasing the effectiveness of (primarily) manufacturing and (occasionally)....

  3. Fotografische industrie

    NARCIS (Netherlands)

    Booij H

    1992-01-01

    This document on photographic industry has been published within the SPIN project. In this project information has been collected on industrial plants or industrial processes to afford support to governmental policy on emission reduction. This document contains information on the processes, emissi

  4. 利用硬质PU泡沫醇解回收料制备PU防水涂料的研究%Preparation of Polyurethane Waterproof Coating Using the Recycled Materials by the Alcoholysis of Rigid Polyurethane Foam

    Institute of Scientific and Technical Information of China (English)

    付新建; 徐亚娟; 刘少兵; 周思凯; 张华

    2011-01-01

    The glycolysis of rigid polyurethane foam with potassium acetate as catalyst, triethylene glycol (TEG) as the agent was investigated. PUP was used as raw material to produce preformed polymer. It was also discussed the effect of the amount of the alcohlysis product in the preformed polymer on the physical and mechanical properties of PU waterproof coating. The results showed that excellent performance sample was obtained when the recycled polyols content in A component was 0. 2, using potassium acetate as catalyst and the content was 2. 0 wt% .%研究了以醋酸钾为催化剂、三甘醇(TEG)为醇解剂对硬质聚氨酯(PU)泡沫的醇解规律,并以醇解产物(PUP)作为原料制备预聚体;探讨了预聚体中醇解产物用量对制备PU防水涂料物理、机械性能的影响.研究结果表明:当催化剂醋酸钾(KAc)/PU质量比为0.02,醇解产物掺量w(PUP)/w(N220) =0.2时,制备的预聚体可以得到满足性能要求的聚氨酯防水涂料.

  5. Comparative study of three different kinds of geo membranes (PVC-P, HDPE, EPDM) used in the waterproofing of reservoirs; Estudio comparativo de tres geomembranas de distinta naturaleza (PVC-P, PEAD, EPDM) empleadas en la impermeabilizacion de balsas

    Energy Technology Data Exchange (ETDEWEB)

    Blanco Fernandez, M.; Castillo Rubi, F.; Soriano Carrillo, J.; Noval Arango, A. M.; Touze-Foltz, N.; Pargada Iglesias, L.; Rico Arnaiz, G.; Aguilar gonzalez, E.

    2014-02-01

    This work describes the long-term behaviour of three kinds of geo membranes which are constituted by plasticised poly vinyl chloride (PVC-P), high density polyethylene (HDPE) and terpolymer rubber of ethylene-propylene-dienic monomer (EPDM) used as the waterproofing system of the reservoirs Los Llanos de Mesa, San Isidro and El Golfo, respectively. Characteristics of the three original geo membranes and their behaviour along time are presented. Thicknesses, content and nature of the plasticizers ( in PVC-P), tensile properties dynamic and static puncture, fold ability at low temperature, shore hardness, tear resistance and carbon black ( in HDPE), joint strength (shear and peeling test) and microscopy, both optical and electronic scanning tests were carried out. Results obtained conclude with a long-term durability of geo membranes, independently of their macromolecular nature. These characteristics were determined by advanced analytical techniques in PVC-P samples, such as fourier Transform Infrared Spectroscopy (FTIR), Gas Chromatography (GC) and Mass Spectrometry (MS). Spectrometry (MS). (Author)

  6. Industrial electrification

    International Nuclear Information System (INIS)

    The technical and economic scope for industrial process electrification in Canada is assessed in the light of increasing costs of combustion fuels relative to electricity. It is concluded that electricity is capable of providing an increasing share of industrial energy, eventually aproaching 100 percent. The relatively low cost of electricity in Canada offers industry the opportunity of a head start in process electrification with consequent advantages in world markets both for industrial products and for electrical process equipment and technology. A method is described to promote the necessary innovation by providing access to technology and financing. The potential growth of electricity demand due to industrial electrification is estimated

  7. Industrial Waste

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund

    2011-01-01

    Industrial waste is waste from industrial production and manufacturing. Industry covers many industrial sectors and within each sector large variations are found in terms of which raw materials are used, which production technology is used and which products are produced. Available data on unit...... generation rates and material composition as well as determining factors are discussed in this chapter. Characterizing industrial waste is faced with the problem that often only a part of the waste is handled in the municipal waste system, where information is easily accessible. In addition part of the...... industrial waste may in periods, depending on market opportunities and prices, be traded as secondary rawmaterials. Production-specificwaste from primary production, for example steel slag, is not included in the current presentation. In some countries industries must be approved or licensed and as part of...

  8. 超高水压大直径盾构隧道管片接缝防水设计与试验研究%Design and experimental study on waterproof gasket of large-diameter shield tunnel under ultra high water pressure

    Institute of Scientific and Technical Information of China (English)

    拓勇飞; 舒恒; 郭小红; 丁文其; 王建

    2013-01-01

    For the project of large-diameter shield tunnel under the highest water pressure in China,a set of design process and research method is proposed for the waterproof gasket for segrnent joints,and the related pattern is studied.First of all,based on the worldwide research progress,combined with the engineering characteristics,a double seal elastomer arrangement for segment joint waterproof gasket of large-diameter shield tunnel under the ultra high water pressure is determined.Secondly,the technical standard of waterproof is studied,and it lays the basis for further analysis of the elastic gasket design and experiment.Thirdly,comparative analysis of several sections of elastic seal gaskets is performed.Finally,a set of unique device and method is adopted,performing the experiments on the waterproof ability and assembly force of the gaskets,and through the comprehensive analysis of the experiment data,the optimal design scheme of the waterproof gasket for segment joint is determined.%针对目前国内承受水压最高的大直径盾构隧道工程,提出一套较系统的弹性密封垫设计流程与研究方法,研究该类管片接缝防水的规律.首先,基于国内外现有研究成果,结合工程特点,确定了超高水压大直径盾构管片接缝防水双道弹性体的布置方式;其次,对防水技术标准进行研究,为深入分析弹性密封垫的相关设计内容与试验成果奠定基础;再次,重点对弹性密封垫的断面形式进行多方案比选分析;最后,通过独特的试验系统与试验方法,对不同断面的弹性密封垫进行高水压防水能力试验以及密封垫装配力试验,综合分析试验成果,最终确定最优防水设计方案.

  9. A crash programme scenario for the Canadian oil sands industry

    International Nuclear Information System (INIS)

    The report Peaking of World Oil Production: Impacts, Mitigation and Risk Management, by Robert L. Hirsch et al., concludes that Peak Oil is going to happen and that worldwide large-scale mitigation efforts are necessary to avoid its possible devastating effects for the world economy. These efforts include accelerated production, referred to as crash programme production, from Canada's oil sands. The objective of this article is to investigate and analyse what production levels that might be reasonable to expect from a crash programme for the Canadian oil sands industry, within the time frame 2006-2018 and 2006-2050. The implementation of a crash programme for the Canadian oil sands industry is associated with serious difficulties. There is not a large enough supply of natural gas to support a future Canadian oil sands industry with today's dependence on natural gas. It is possible to use bitumen as fuel and for upgrading, although it seems to be incompatible with Canada's obligations under the Kyoto treaty. For practical long-term high production, Canada must construct nuclear facilities to generate energy for the in situ projects. Even in a very optimistic scenario Canada's oil sands will not prevent Peak Oil. A short-term crash programme from the Canadian oil sands industry achieves about 3.6 mb/d by 2018. A long-term crash programme results in a production of approximately 5 mb/d by 2030

  10. In vitro studies of the genotoxic effects of bitumen and coal-tar fume condensates: comparison of data obtained by mutagenicity testing and DNA adduct analysis by 32P-postlabelling.

    Science.gov (United States)

    De Méo, M; Genevois, C; Brandt, H; Laget, M; Bartsch, H; Castegnaro, M

    1996-08-14

    Bitumens contain traces of polycyclic aromatic compounds (PACs), a part of which will end up in the fumes emitted during hot handling of bitumen-containing products, e.g. during roadpaving. Although exposure of workers to these fumes is low, it might lead to health problems. Studies on bitumen fume condensates (BFCs) showed weak to moderate mutagenic activities, but studies on DNA adduct formation have not been reported. Therefore, a study was initiated in which fumes were generated from two road grade bitumens, in such a way that they were representative of the fumes produced in the field. The combined vapour/particulates were tested in vitro for their ability to produce DNA adducts and in modified Ames mutation assays, using a number of different strains. An attempt was made to relate the results to chemical data, such as the content of a number of individual polycyclic aromatic hydrocarbons (PAHs) and with a measure for the total PAC content. As a reference material fume condensate from coal-tar (coal-tar pitch volatiles; CTPV) were subjected to the same tests. All fume condensates tested were mutagenic to all strains and induced the formation of DNA adducts. The patterns of DNA adducts, obtained by 32P-postlabelling, arising from the BFCs were qualitatively different from the patterns of adducts obtained from the CTPVs, implying qualitative differences in the nature of the compounds responsible for the formation of these adducts. This is corroborated by the observation that for BFCs quantitative adduct levels are higher than would be expected based on the PAH content. These data thus indicate that the PAHs analysed are not the sole components responsible for adduct formation from BFCs, but that an important contribution comes from other (hetero- and/or substituted-) PACs. PMID:8760390

  11. In vitro studies of the genotoxic effects of bitumen and coal-tar fume condensates: comparison of data obtained by mutagenicity testing and DNA adduct analysis by {sup 32}P-postlabelling

    Energy Technology Data Exchange (ETDEWEB)

    De Meo, M.; Genevois, C.; Brandt, H.; Laget, M.; Bartsch, H.; Castegnaro, M. [Laboratoire de Biogenotoxicologie et Mutagenese Environnementale, Marseille (France). Faculte de Pharmcie

    1996-08-14

    Bitumens contain traces of polycyclic aromatic compounds (PACs), a part of which will end up in fumes emitted during hot handling of bitumen-containing products, e.g. during road paving. Exposure of workers to these fumes might lead to health problems. Studies on bitumen fume condensates (BFCs) showed mutagenic activities, but studies on DNA adduct formation have not been reported. Thus a study was initiated in which fumes were generated from two road grade bitumens which were representative of the fumes produced in the field. The combined vapour/particulates were tested in vitro for their ability to produce DNA adducts and in modified Ames mutation assays. Results were related to chemical data, such as the content of a number of individual polycyclic aromatic hydrocarbons (PAHs) and with a measure for total PAC content. As a reference material fume condensate from coal tar (coal-tar pitch volatiles; CTPV) were subjected to the same tests. All fume condensates were tested were mutagenic to all strains and induced the formation of DNA adducts. The patterns of DNA adducts arising from the BFCs were qualitatively different from the patterns of adducts obtained from the CTPVs, implying qualitative differences in the nature of the compounds responsible for their formation. This is corroborated by the observation that for BFCs quantitative adduct levels are higher than would be expected based on the PAH content. These data thus indicate that the PAHs analysed are not the sole components responsible for adduct formation from BFCs, but that an important contribution comes from other (hetero- and/or substituted-) PACs. 32 refs., 2 figs., 3 tabs.

  12. Alteración,mineralización de Cu y bitumen en el prospecto Barda González, Neuquén

    Directory of Open Access Journals (Sweden)

    Josefina M. Pons

    2009-06-01

    Full Text Available Barda González esun prospecto de Cu hospedado en las rocas sedimentarias cretácicas de la FormaciónPortezuelo (Grupo Neuquén y localizado en la zona de fallas de la dorsal deHuincul, próximo a los yacimientos hidrocarburíferos Barda González, Bajo BardaGonzález y Puesto Espinosa. La mineralización de Cu se extiende en un frente de600 m por 2.000 m de largo en sentido nornoreste, siguiendo los niveles deareniscas gruesas y conglomerádicas que demarcan paleocanales fluviales. Estasrocas están decoloradas, alteradas y muy permeables por la ausencia de óxidos ehidróxidos de hierro, la disolución total a parcial de los cementos, losfeldespatos y líticos volcánicos y la alteración de estos últimos aargilominerales (illita> caolinita. Los minerales de cobre estándiseminados, en tubos o nódulos siempre en contacto con bitumen. Consisten enrestos de calcosina, covellina, trazas de calcopirita y una variedad deminerales de cobre supergénicos (malaquita, con crisocola, brochantita,azurita, tenorita, turquesa, atacamita, volbortita. También hay piritadiseminada y trazas de psilomelano. En las muestras con las mayoresconcentraciones de Cu (16% se detectaron anomalías de Mo (810 ppm, U (9,43ppm, Th (40,6 ppm y V (127-221 ppm. La geoquímica del bitumen indica que setrata de un residuo dejado por la migración de hidrocarburos generados a partirde rocas de origen marino del Jurásico (Formaciones Los Molles o Vaca Muerta.Las aguas de formación ricas en cloruros que migraron junto con loshidrocarburos, pudieron transportar el cobre y el azufre en solución. Lamigración de estos fluidos desde las rocas fuentes hacia los reservorios através de las fallas y estratos permeables, habría desempeñado un rol muyimportante en la extracción del cobre a partir del lavado de los óxidos ehidróxidos de hierro de los estratos rojos continentales infrayacentes. En sutransporte y en contacto con los niveles permeables de la Formación Portezuelo

  13. Applications in the oil sands industry for Particlear{sup R} silica microgel

    Energy Technology Data Exchange (ETDEWEB)

    Moffett, B. [DuPont Chemical Solutions Enterprise, Wilmington, DE (United States)

    2009-07-01

    This presentation demonstrated the use of Particlear{sup R} silica microgel in the oil sands industry. The silica-based coagulant is an amorphous silicon dioxide microgel solution. The surface area of a football field can be obtained using 2.7 grams of the substance. The coagulation mechanism is achieved by charge neutralization and inter-particle bridging. The microgel is manufactured at the point of use from commodity chemicals, water, and carbon dioxide (CO{sub 2}). Applications for the microgel include potable water treatment, paper retention, and animal processing wastewater. In the oil sands industry, Particlear{sup R} can be used in tailings flocculation, thickened tailings drying, steam assisted gravity drainage (SAGD) water treatment, and enhanced bitumen recovery. It was concluded that the microgel can be used in many oil sands processing and liquid-solid separation processes in order to remove dissolved solids and organics and increase the rate of solids dewatering. tabs., figs.

  14. Industrial Robots.

    Science.gov (United States)

    Reed, Dean; Harden, Thomas K.

    Robots are mechanical devices that can be programmed to perform some task of manipulation or locomotion under automatic control. This paper discusses: (1) early developments of the robotics industry in the United States; (2) the present structure of the industry; (3) noneconomic factors related to the use of robots; (4) labor considerations…

  15. Industry honoured

    CERN Multimedia

    2008-01-01

    CERN has organised a day to thank industry for its exceptional contributions to the LHC project. Lucio Rossi addresses CERN’s industrial partners in the Main Auditorium.The LHC inauguration provided an opportunity for CERN to thank all those who have contributed to transforming this technological dream into reality. Industry has been a major player in this adventure. Over the last decade it has lent its support to CERN’s teams and participating institutes in developing, building and assembling the machine, its experiments and the computing infrastructure. CERN involved its industrial partners in the LHC inauguration by organising a special industry prize-giving day on 20 October. Over 70 firms accepted the invitation. The firms not only made fundamental contributions to the project, but some have also supported LHC events in 2008 and the inauguration ceremony through generous donations, which have been coordinated by Carmen Dell’Erba, who is responsible for secu...

  16. Bitumen coating of the radio-active sludges from the effluent treatment plant at the Marcoule centre. Review of the progress reports 1, 2, 3 and 4 (1963)

    International Nuclear Information System (INIS)

    Besides the very high activity liquids containing fission products, the chemical treatment of irradiated fuels produces a large volume of aqueous effluents and solid waste of relatively low radioactivity. These weakly active products can be eliminated in the ground, in a hydrographic land system or in the sea. Techniques of evaporation, of resin concentration, and of coprecipitation give rise to inorganic sludges with a high water content. All these residues occupy a large volume and represent a far from negligible weight. In the case of the sludge, their relative fluidity necessitates a conditioning guaranteeing safe storage. The solution to the problem will consist in passing directly from a liquid or a suspension, to a solid whose structure is homogeneous and whose matter is inert with respect to the storage medium (soil, sea, etc. ). We have proposed to coat the radioactive products with bitumen. This article is designed to give a review of the studies undertaken on this method. It consists of a progress report rather than a final assessment. (authors)

  17. Heavy oil and bitumen : thinking caps on : researchers look at new and greener ways to get at the heavy oil prize

    Energy Technology Data Exchange (ETDEWEB)

    Harrison, L.

    2008-01-15

    New steam stimulation processes developed by the Alberta Ingenuity Centre for In Situ Energy were discussed. The J-well and gravity-assisted steam stimulation (JAGD) process uses a steam injection well located within the top few metres of a reservoir and a production well comprised of an inclined J-shaped well. JAGD is a transitional cold production-to-thermal-production technology. High pressure steam is used to heat and loosen the bitumen so that it flows to the producer well below. The configuration was designed to cut through mud and shale layers and is suitable for poor quality reservoirs. Simulations conducted in Athabasca reservoirs have demonstrated that JAGD uses approximately 75 per cent of the steam typically used in steam assisted gravity drainage (SAGD) processes. The iSAGD process was designed to reposition parallel wells in order to increase oil mobility. Researchers at the centre are also investigating a catalytic air-stream process called CASPAR which aims to upgrade oil from 10 degrees API to 16 degrees API within the reservoir. The process involves a mixture of heat, catalyst hydrogen, steam, air and water in the reservoir. The process leaves heavier ends of oil underground as well as fractions of greenhouse gases (GHGs). Research is also being conducted on expanding-solvent SAGD (ES-SAGD) a process that adds butane to steam in order to reduce water use. 3 figs.

  18. Air Blowing of Bitumens: Process Variables and Structural Parameters Soufflage des bitumes : variables du procédé et paramètres structuraux

    Directory of Open Access Journals (Sweden)

    Bahl J. S.

    2006-11-01

    Full Text Available Effect of process variables viz. air rate, time of air blowing, temperature and catalyst concentration has been investigated and optimised to determine the possibility of making paving grade bitumen from 500°C+ Aghajari Short residue, of appropriate temperature susceptibility. Structural parameters of feed and some typical air blown products determined through NMR spectroscopy to follow the reaction mechanism leading to formation of increased asphaltene content during air blowing are also described. On a étudié et optimisé l'effet des variables du procédé comme le débit de l'air, le temps de soufflage, la température et la concentration en catalyseurs afin de déterminer la possibilité de fabriquer du bitume routier d'une susceptibilité à la température convenable, à partir d'un résidu Aghajari 500 °C+ de distillation poussée. On présente également les paramètres structuraux de la charge et de quelques produits types du soufflage, déterminés par résonance magnétique nucléaire, pour suivre le mécanisme de la réaction conduisant à une augmentation de la teneur en asphaltènes durant le soufflage d'air.

  19. Development of a measurement system for the online inspection of microstructured surfaces in harsh industrial conditions

    Science.gov (United States)

    Mueller, Thomas; Langmann, Benjamin; Reithmeier, Eduard

    2014-05-01

    Microscopic imaging techniques are usually applied for the inspection of microstructured surfaces. These techniques require clean measurement conditions. Soilings, e.g. dust or splashing liquids, can disturb the measurement process or even damage instruments. Since these soilings occur in the majority of manufacturing processes, microscopic inspection usually must be carried out in a separate laboratory. We present a measurement system which allows for a microscopic inspection and a 3D reconstruction of microstructured surfaces in harsh industrial conditions. The measurement system also enables precise positioning, e.g. of a grinding wheel, with an accuracy of 5 μm. The main component of the measurement system is a CCD camera with a high-magnification telecentric lens. By means of this camera it is even possible to measure structures with dimensions in the range of 30 to 50 μm. The camera and the lens are integrated into a waterproof and dustproof enclosure. The inspection window of the enclosure has an air curtain which serves as a splash guard. The workpiece illumination is crucial in order to obtain good measurement results. The measuring system includes high-power LEDs which are integrated in a waterproof enclosure. The measurement system also includes a laser with a specially designed lens system to form an extremely narrow light section on the workpiece surface. It is possible to obtain a line width of 25 μm. This line and the camera with the high-magnification telecentric lens are used to perform a laser triangulation of the microstructured surface. This paper describes the system as well as the development and evaluation of the software for the automatic positioning of the workpiece and the automatic three-dimensional surface analysis.

  20. Effect of Waterproofing Agent B and Curing Temperature on Properties of the Burning-free, Autoclave Curing-free and Non-cement Building Bricks Made from Iron Tailings%防水剂B和养护温度对铁尾矿三免砖性能的影响

    Institute of Scientific and Technical Information of China (English)

    徐民主; 雷国元; 宋均平; 罗文斌; 谭青; 李瑞杰

    2015-01-01

    Burning-free,autoclave curing-free and non-cement building bricks( three-free for short) were prepared with the fine low-silica iron ore tailing and the self-made non-cement curing agent as the raw material. The effect of the content of waterproofing agent B and curing temperature on the properties of the products such as the compressive strength,water resist-ance,frost resistance and anti-carbonization,and also its mechanisms were studied. The results showed that with the dosage of waterproofing agent B increase,compressive strength and 24 h water absorption of products decreased while saturated compres-sive strength and softening coefficient are increased first and then decreased. With the increase of initial curing temperature, water resistance,frost resistance and compressive strength in every curing time are improved significantly. According to the mechanism analysis by XRD and FI-TR,the results show that hydrated calcium silicate gel and ettringite are strength binder phase of three-free bricks. Meanwhile,the addition of waterproofing agent B does not affect the composition of binding phase. The increase of initial curing temperature and the addition of waterproofing agent B can inhibit the carbonation reaction within products and improve water resistance. The results of theoretical analysis can explain the effect of curing temperature and water-proofing agent B on performance of the products. It provides theory basis for the high-effect waterproofing agent and the optimi-zation of the curing conditions.%以某细粒低硅铁尾矿和无水泥固化剂为原料,制备免烧免蒸免水泥建材砖(简称“三免砖”)。研究了防水剂B和养护温度对制品抗压强度、耐水性和抗冻性的影响及其机制。试验结果表明:随着防水剂B掺量的增加,制品的干抗压强度和24 h吸水率均下降,饱和抗压强度和软化系数均先升后降;随着初期养护温度的升高,制品的耐水性、抗冻性和各龄期

  1. Industrial practices

    International Nuclear Information System (INIS)

    This document reports the industrial practices carried out by the author viewing the requirements fulfilled for obtention the academic degree in chemical engineering of the San Andres University - Bolivia

  2. Industrial pioneers

    NARCIS (Netherlands)

    Wassink, J.

    2014-01-01

    With their knowledge of metallurgy, mechanics and thermodynamics, mechanical engineers had to give shape to the industrial revolution in the Netherlands 150 years ago. This revolution only slowly gathered momentum, however, especially in comparison with England.

  3. Industrial ceramics

    International Nuclear Information System (INIS)

    After having given the definition of the term 'ceramics', the author describes the different manufacturing processes of these compounds. These materials are particularly used in the fields of 1)petroleum industry (in primary and secondary reforming units, in carbon black reactors and ethylene furnaces). 2)nuclear industry (for instance UO2 and PuO2 as fuels; SiC for encapsulation; boron carbides for control systems..)

  4. Industrial Noise

    OpenAIRE

    Mehran zolfaghari

    1996-01-01

    Various risk factors in industrial environments can affect hearing status and healthy in today’s modern society. Noise control and hearing conservation program is very crucial in preventing workers exposed to high levels of noise in the work places. In the current article we are going to discuss issues such as industrial noise control, noise characteristics and standards and techniques for noise control. Then the methods for individual hearing conservation and medical care will be described i...

  5. The oil and gas industry and the Canadian economy: a backgrounder

    International Nuclear Information System (INIS)

    The impact of the oil and natural gas industry on the Canadian economy is explained in terms of employment, balance of trade, products, government revenues, international technology trade and industry support to the community. It is reported that the industry employs almost one half million people in Canada; is the second largest contributor to Canada's balance of trade; generate billions of dollars for the economy and pays hundreds of millions of dollars in taxes and its employees contribute millions of dollars and thousands of hours of time to charitable and community organizations. The industry is also one of the major contributors to Canada's technology export through its leadership in high technology exploration methods, cold climate and offshore operations, enhanced recovery technologies, producing and processing heavy oil; mining and upgrading oil sands bitumen, oil-well firefighting techniques and environmental protection technologies, among others. Citing Canada's cold climate and energy-intensive industries, hence the need for large quantities of energy, the booklet offers a rationale for the industry's need to continue to be profitable in order to develop new sources of oil and gas production and invest in energy-efficient technologies. Assuming continued profitability, combined with more efficient use of oil and gas, the Foundation remains confident that the industry will provide energy security and export revenues for the benefit of all Canadians. 12 refs., photos

  6. Industrial gases

    International Nuclear Information System (INIS)

    Industrial gas companies have fought hard to boost sales and hold margins in the tough economic climate, and investments are well down from their 1989-'91 peak. But 'our industry is still very strong long term' says Alain Joly, CEO of industry leader L'Air Liquide (AL). By 1994, if a European and Japanese recovery follows through on one in the U.S., 'we could see major [investment] commitments starting again,' he says. 'Noncryogenic production technology is lowering the cost of gas-making possible new applications, oxygen is getting plenty of attention in the environmental area, and hydrogen also fits into the environmental thrust,' says Bob Lovett, executive v.p./gases and equipment with Air Products ampersand Chemicals (AP). Through the 1990's, 'Industrial gases could grow even faster than in the past decade,' he says. Virtually a new generation of new gases applications should become reality by the mid-1990s, says John Campbell, of industry consultants J.R. Campbell ampersand Associates (Lexington, MA). Big new oxygen volumes will be required for powder coal injection in blast furnaces-boosting a steel mill's requirement as much as 40% and coal gasification/combined cycle (CGCC). Increased oil refinery hydroprocessing needs promise hydrogen requirements

  7. 泡沫沥青冷再生混合料力学特性试验%Test of Mechanical Property of Cold Recycled Mixture with Foamed Bitumen

    Institute of Scientific and Technical Information of China (English)

    徐金枝; 郝培文; 刘丽

    2011-01-01

    采用间接拉伸强度、无侧限抗压强度及抗压回弹模量试验,分析了沥青路面旧料掺量及水泥用量对泡沫沥青冷再生混合料力学特性的影响.研究表明:随旧料掺量的增大或其中旧沥青含量的增多,泡沫沥青冷再生混合料设计最佳沥青用量减少,冷再生混合料抗拉、抗压、抗剪性能呈下降趋势,而抗压回弹模量逐渐增大;水泥用量的增大有助于提高冷再生混合料的强度、刚度及其水稳定性,但用量过大不利于冷再生混合料的抗裂性能,建议不超过2%;水泥用量较小(≤1.5%)的冷再生混合料强度增长主要集中于室温养生的24h以及40℃烘箱养生的第1个24h内,而水泥用量较大(1.5%~3%)的冷再生混合料养生期内强度增长比较匀速.%By indirect tensile strength test, unconfined compressive strength test and compressive resilient modulus test, the influences of recycled asphalt pavement (RAP) content and cement content on mechanical property of cold recycled mixture with foamed bitumen ( CRMFB) were studied. The results indicate that ( 1) Increase of RAP content or content of old bitumen in RAP led to decrease of optimum foamed asphalt content and tensile, compressive, and shear strengths, but increase of compressive resilient modulus for CRMFB. (2) Increase of cement content contributed to the enhancement of mechanical property and water susceptibility of CRMFB. However, an excess of cement would have negative effect on crack resistance of CRMFB, so the cement content is suggested to be limited to 2% or less. (3) For the CRMFB with lower cement content ( ≤1. 5% ) , the strength increase mainly concentrated in the period of the 24 h at open air curing and the first 24 h at 40 t oven curing, while for the CRMFB with higher cement content (1.5% -3% ) , an uniform strength increase appeared in the whole curing period.

  8. Fiabilidad industrial

    OpenAIRE

    Griful Ponsati, Eulàlia

    2001-01-01

    El presente libro ha sido escrito y editado para los estudios de segundo ciclo de Ingeniería de Organización Industrial que se imparten en la ETSEIT de la UPC. La materia de fiabilidad que se imparte en este texto es una introducción a las técnicas estadísticas para resolver cuestiones de fiabilidad industrial. Se estudian distintos modelos probabilísticos del tiempo de vida y se presentan distintas formas de recabar información y de estimar, en cada caso, la fiabilidad de los componentes y s...

  9. Industrial sector

    International Nuclear Information System (INIS)

    The industrial sector is categorized as related to among others, the provision of technical and engineering services, supply of products, testing and troubleshooting of parts, systems and industrial plants, quality control and assurance as well as manufacturing and processing. A total of 161 entities comprising 47 public agencies and 114 private companies were selected for the study in this sector. The majority of the public agencies, 87 %, operate in Peninsular Malaysia. The remainders were located in Sabah and Sarawak. The findings of the study on both public agencies and private companies are presented in subsequent sections of this chapter. (author)

  10. Fermentation Industry.

    Science.gov (United States)

    Grady, C. P. L., Jr.; Grady, J. K.

    1978-01-01

    Presents a literature review of wastes from the fermentation industry, covering publications of 1976-77. This review focuses on: (1) alcoholic beverage production; (2) pharmaceuticals and biochemicals production; and (3) biomass production. A list of 62 references is also presented. (HM)

  11. Shifting Industries

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Coastal city Beihai aspires to revive its economy by developing its electronic information industry Against a clear sky,the blue sea hums along a shining beach,with villas in the distance.This beautiful scene is in Beihai,in south China’s Guangxi Zhuang Autonomous Region.

  12. Industrial infrastructure

    International Nuclear Information System (INIS)

    A substantial prerequisite for an increase of the domestic participation is the existence of an ''industrial infrastructure''. As long as a structure such as that described in this paper does not exist, domestic industry participation will continue to be confined to the assembly of components, while most of the supplies (materials, accessory parts) would have to be imported. The scope and set-up of the ''industrial infrastructure'' will be determined by a study of the required capacity and organization, which has to be prepared at a very early stage (second phase of an envisaged transfer of technology), and which will be included within the scope of a nuclear programme. Experience has shown that the different state institutes, the universities, private industry and the State companies work independently without any co-ordination of their activities. By the assignment of tasks, after taking into account existing conditions, an infrastructure can be built up which can be developed more intensively in the different fields co-operating with the institutes of the partner country. In the past good co-ordination of the different activities by an experienced partner has turned out to be absolutely necessary. This, too, presents the opportunity of co-operation with the main contractor who has extensive experience in constructing nuclear power plants. In the course of time, this co-ordination function can be transferred to a specially qualified domestic institute or company, which will undertake further development and co-ordination. (author)

  13. Industrial radiography

    International Nuclear Information System (INIS)

    This publication is meant to be a manual for industrial radiography. As such the manual concentrates on the practical aspects, presenting existing radiographic system and techniques of operation to satisfy specified quality requirements. The manual also reviews the safety aspect of performing radiographic work. (author) systems

  14. Industrial Microorganisms.

    Science.gov (United States)

    Phaff, Herman J.

    1981-01-01

    Describes industrially important yeasts, molds, bacteria, and actinomycetes. Discussed in detail are microbial products, such as primary metabolites, secondary metabolites, enzymes, and capsular polysaccharides. Traces the historical background of human cell culture, mentioning recombinant DNA research and hybridization of normal mammalian cells…

  15. Use of a thin-film evaporator for bitumen coating of radioactive concentrates; Utilisation d'un evaporateur a couche mince pour l'enrobage par le bitume de concentrats radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Lefillatre, G.; Rodier, J.; Hullo, R.; Cudel, Y.; Rodi, L. [Commissariat a l' Energie Atomique, Chusclan (France). Centre de Production de Plutonium de Marcoule

    1969-07-01

    Following the development in the laboratory of a process for coating evaporation concentrates with bitumen, a technological study of this coating process has been undertaken. The report describes a pilot installation for the bitumen coating of concentrates, which uses a thin-film evaporator LUWA L 150. The first, inactive series of tests was designed to determine the maximum and optimum capacities of the evaporator by varying the amounts of bitumen and of concentrate, the rotor speed and the thermo-fluid temperature. Two rotors were tested, one of conventional type, the other a model especially designed for high viscosity products. The maximum capacity of evaporation of the apparatus is 72 kg/hr for a heating temperature of 221 deg. C. During normal operation, the evaporator can produce 50 kg/hr of coated product containing 55 to 60 per cent of bitumen (Mexphalte 40/50), the water content of the product remaining under 0.5 per cent. A second series of tests will shortly be carried out on this pilot installation using, in particular, bituminous emulsions containing mainly Mexphalte 40/50 and 80/100. (authors) [French] A la suite de la mise au point en laboratoire d'un procede d'enrobage par le bitume de concentrats d'evaporation, une etude technologique de cet enrobage a ete entreprise. Ce rapport decrit une installation pilote d'enrobage par le bitume de concentrats utilisant un evaporateur a couche mince LUWA L 150. La premiere serie d'essais en inactif a eu pour but de definir les capacites maximales et optimales de l'evaporateur en faisant varier les dosages en bitume et en concentrats, la vitesse du rotor et la temperature du thermo-fluide. Deux rotors ont ete testes, l'un de type classique, l'autre d'un modele special concu pour les produits de haute viscosite. La capacite d'evaporation maximale de l'appareil est de 72 kg/h d'eau pour une temperature de chauffage de 221 deg. C. En marche normale l

  16. Extractive industry a burden or an opportunity for sustainable development?

    Directory of Open Access Journals (Sweden)

    2013-04-01

    Full Text Available The shortage of raw materials in global markets and the sky rocketing of commodityprices, have induced European authorities to take initiatives to improve innovation inEurope by creating the European Innovation Partnership on Raw Materials (2012 andmake inventory of the existing European raw materials. Albania is a rich country innatural raw materials, such as chromium, copper, ferronickel, coal, bitumen as well ascrude oil which might supply primary and secondary raw materials for some of theEuropean needs. This literature review discusses the role of the Albanian institutions, thenatural resources industry, potential investors and stakeholders in order to provide a setof indicators and platforms that can help to develop the extractive industry in Albania andmonitor amelioration within sustainable development principles. A map with the potentialprospects of the natural resources will be a first step in identifying the further potentialfor exploitation. Mineral resource policies and governance, sustainable processing andsupply chain as well as environmental management information system (EMIS are someof the crucial tools identified, which will help to set up the indicators and quantify theachievements in environmental management in Albania. Moreover, the integration ofpractices that will support institutional capacity building; follow-up practices; themainstreaming of global environment into planning; and the compliance monitoringprocess will additionally improve the environmental situation in Albania. Aligningbusiness strategy with environmental policy, socio-economic analysis, environmentalauditing are decisive tools in order to provide the Albanian authorities with a clearoverview of the economic costs and the social benefits for sustainable development ofthe extractive sector in Albania.

  17. 某传媒产业园屋顶花园绿化景观工程施工技术%On construction technique for reforestation landscape projects at roof gardens of some media industrial park

    Institute of Scientific and Technical Information of China (English)

    王俊

    2014-01-01

    In order to beautify garden environment and broaden cultural entertainment channels to reduce the resource consumption on roofs, the paper indicates the roof design for some production workshop of the media industrial park into the garden reforestation landscape roof, mainly in-troduces some main points for the construction technique in the roof reforestation and landscape construction process from the waterproof protection construction, construction of waterproof wall penetrating well, and root layer, so as to achieve the expected aims.%为了美化园区环境,拓宽职工文化娱乐渠道,同时使厂房屋面减少能源消耗,某传媒产业园区将生产车间屋面设计为花园式绿化景观屋面,从防水保护层施工、隔水墙透水井砌筑等方面出发,就屋面绿化和景观施工过程中的施工技术做了一些重点的介绍,以达到预期的施工目标。

  18. Industry perspectives

    Science.gov (United States)

    Fuqua, Don; Hannemann, Tim; Iacobellis, Sam F.; Young, A. Thomas

    This discussion addresses the question of whether or not the space industry will take up the slack in the aerospace industry that is created by budget cuts in defense. Armed forces' research has provided an invaluable base for national technological and engineering resources for aerospace companies. It is noted that the space program should maximize the country's advances in national, scientific, and technical capabilities. It is also noted that NASA has done well in a most complicated business, but that Congress has failed to make a firm commitment to NASA's plans outlined in Vision 21 (based on the Augustine report) as evidenced by the Congressional reactions to NASA's budget requests. International cooperation and competition are discussed as well as the need for a political concensus on the direction of the space program in the U.S.

  19. Industrial vision

    DEFF Research Database (Denmark)

    Knudsen, Ole

    1998-01-01

    This dissertation is concerned with the introduction of vision-based application s in the ship building industry. The industrial research project is divided into a natural seq uence of developments, from basic theoretical projective image generation via CAD and subpixel analysis to a description...... is present ed, and the variability of the parameters is examined and described. The concept of using CAD together with vision information is based on the fact that all items processed at OSS have an associated complete 3D CAD model that is accessible at all production states. This concept gives numerous...... possibilities for using vision in applications which otherwise would be very difficult to automate. The requirement for low tolerances in production is, despite the huge dimensions of the items involved, extreme. This fact makes great demands on the ability to do robust sub pixel estimation. A new method based...

  20. Industrial Networks

    DEFF Research Database (Denmark)

    Karlsson, Christer

    2015-01-01

    Companies organize in a way that involves many activities that are external to the traditional organizational boundaries. This presents challenges to operations management and managing operations involves many issues and actions dealing with external networks. Taking a network perspective changes...... the focus of operations management from managing the own organization to continuously developing and managing a network of external and internal resources forming a production system. This perspective may be called managing an “extraprise” rather than an “enterprise.” It should be noted that “an industrial...... network” should not be seen as an organizational form but as a perspective that can be used to enrich one's understanding of organizations. The industrial network perspective has three basic building blocks: actors, resources, and activities. The three building blocks and their relations constitute...

  1. Upstream petroleum industry flaring and venting report : Industry performance for year ending December 31, 2003

    International Nuclear Information System (INIS)

    Solution gas is the largest source of flaring and venting in Alberta. The Alberta Energy and Utilities Board (EUB) has been acknowledged internationally for its success in reducing flaring and venting. The EUB's target is to eliminate the routine flaring and venting of solution gas to address conservation and public safety. This report describes how the EUB fulfills its information mandate regarding flaring and venting. It is published in response to a commitment made by the EUB to make flaring and venting data more accessible. The EUB and the Clean Air Strategic Alliance have established baselines for flaring and venting. Regulations, enforcement and industry cooperation have resulted in major reductions in the amount of solution gas flared and vented. This report provides a summary of flared and vented volumes for the different oil and gas industry sources, such as well tests, gas plants, gas gathering systems, transmission lines, and batteries. It also contains detailed information on solution gas conserved, flared, and vented during 2003. Ranking of companies was established based on solution gas flared plus vented, solution gas flared, and solution gas vented, from crude oil and bitumen batteries. The data used in the preparation of this report was submitted by companies. The data demonstrates that considerable progress has been made in the reduction of flaring and venting volumes for all upstream oil and gas sources. Solution gas conservation for 2003 was 95.4 per cent, the highest conservation level achieved to date. Solution gas flaring for 2003 was 70 per cent less than the 1996 flaring baseline. tabs., figs

  2. Alteración,mineralización de Cu y bitumen en el prospecto Barda González, Neuquén Alteration,Cu mineralization and bitumen in the Barda González prospect, Neuquén

    Directory of Open Access Journals (Sweden)

    Josefina M. Pons

    2009-06-01

    Full Text Available Barda González esun prospecto de Cu hospedado en las rocas sedimentarias cretácicas de la FormaciónPortezuelo (Grupo Neuquén y localizado en la zona de fallas de la dorsal deHuincul, próximo a los yacimientos hidrocarburíferos Barda González, Bajo BardaGonzález y Puesto Espinosa. La mineralización de Cu se extiende en un frente de600 m por 2.000 m de largo en sentido nornoreste, siguiendo los niveles deareniscas gruesas y conglomerádicas que demarcan paleocanales fluviales. Estasrocas están decoloradas, alteradas y muy permeables por la ausencia de óxidos ehidróxidos de hierro, la disolución total a parcial de los cementos, losfeldespatos y líticos volcánicos y la alteración de estos últimos aargilominerales (illita> caolinita. Los minerales de cobre estándiseminados, en tubos o nódulos siempre en contacto con bitumen. Consisten enrestos de calcosina, covellina, trazas de calcopirita y una variedad deminerales de cobre supergénicos (malaquita, con crisocola, brochantita,azurita, tenorita, turquesa, atacamita, volbortita. También hay piritadiseminada y trazas de psilomelano. En las muestras con las mayoresconcentraciones de Cu (16% se detectaron anomalías de Mo (810 ppm, U (9,43ppm, Th (40,6 ppm y V (127-221 ppm. La geoquímica del bitumen indica que setrata de un residuo dejado por la migración de hidrocarburos generados a partirde rocas de origen marino del Jurásico (Formaciones Los Molles o Vaca Muerta.Las aguas de formación ricas en cloruros que migraron junto con loshidrocarburos, pudieron transportar el cobre y el azufre en solución. Lamigración de estos fluidos desde las rocas fuentes hacia los reservorios através de las fallas y estratos permeables, habría desempeñado un rol muyimportante en la extracción del cobre a partir del lavado de los óxidos ehidróxidos de hierro de los estratos rojos continentales infrayacentes. En sutransporte y en contacto con los niveles permeables de la Formación Portezuelo

  3. The influence of organic complexing agents upon the mobilization and migration of radionuclides from ILW contained in cement and bitumen under nearfield conditions for a repository in a salt dome

    International Nuclear Information System (INIS)

    Within the frame of this project the influence of the synthetic organic complexing agents dibutylphosphate, tributylphosphate, ethylenediamine-tetra acetic acid, citrate and oxalate on the solubilities, the migration and sorption behaviour of the elements iodine, cesium, uranium neptunium, plutonium and americium was investigated in electrolyte solutions, representing the conditions of a near field of a waste repository in a salt dome after an intrusion of brines, considered as a hypothetical scenario. The electrolyte solutions were saturated NaCl solution and Q-brine, which were equilibrated with corrosion products of the matrices Portland 35-F cement and bitumen (Shell Mexphalte R 80-100) before starting the experiments, in order to simulate their influence on the chemical behaviour of the solutions used for the experiments. The temperature, at which the experiments were carried out, was 298 K. After determining the relevant pH- and Eh-values, pH was adapted to 12.3 for saturated NaCl solution equilibrated with cement and to 6.4 for Q-brine also being at equilibrium with cement. The electrolyte systems on the other hand containing bitumen were kept at those pH-values, which resulted from saturation with the complexing agents. 120 tabs., 87 figs., 67 refs

  4. Industrial ventilation

    Science.gov (United States)

    Goodfellow, H. D.

    Industrial ventilation design methodology, using computers and using fluid dynamic models, is considered. It is noted that the design of a ventilation system must be incorporated into the plant design and layout at the earliest conceptual stage of the project. A checklist of activities concerning the methodology for the design of a ventilation system for a new facility is given. A flow diagram of the computer ventilation model shows a typical input, the initialization and iteration loop, and the output. The application of the fluid dynamic modeling techniques include external and internal flow fields, and individual sources of heat and contaminants. Major activities for a ventilation field test program are also addressed.

  5. Industrial radiography

    International Nuclear Information System (INIS)

    Industrial radiography is a non-destructive testing (NDT) method which allows components to be examined for flaws without interfering with their usefulness. It is one of a number of inspection methods which are commonly used in industry to control the quality of manufactured products and to monitor their performance in service. Because of its involvement in organizing training courses in all the common NDT methods in regional projects in Asia and the Pacific and Latin America and the Caribbean and in many country programmes, the Agency is aware of the importance of standardizing as far as possible the syllabi and training course notes used by the many experts who are involved in presenting the training courses. IAEA-TECDOC-628 ''Training Guidelines in Non-destructive Testing'' presents syllabi which were developed by an Agency executed UNDP project in Latin America and the Caribbean taking into account the developmental work done by the International Committee for Non-destructive Testing. Experience gained from using the radiography syllabi from TECDOC-628 at national and regional radiography training courses in the Agency executed UNDP project in Asia and the Pacific (RAS/86/073) showed that some guidance needed to be given to radiography experts engaged in teaching at these courses on the material which should be covered. The IAEA/UNDP Asia and Pacific Project National NDT Coordinators therefore undertook to prepare Radiography Training Course Notes which could be used by experts to prepare lectures for Level 1,2 and 3 radiography personnel. The notes have been expanded to cover most topics in a more complete manner than that possible at a Level 1, 2 or 3 training course and can now be used as source material for NDT personnel interested in expanding their knowledge of radiography. Refs, figs and tabs

  6. 沥青样品铼-锇同位素分析溶解实验研究%Dissolving Experimental Research of Re-Os Isotope System for Bitumen Samples

    Institute of Scientific and Technical Information of China (English)

    李超; 屈文俊; 王登红; 陈郑辉; 杜安道; 张长青

    2011-01-01

    The content of Re-Os in asphalt samples is relatively low, and CO2 are released in digestion because of large amounts of organic matter. It is important to control the amount of asphalt in the sample and the proportion of oxidant to ensure the Os recovery and stability of the measured signal. The method for the Re-Os isotope was improved because of large amounts of organic matter contained in bitumen samples. The Oxidants was changed to 3 mL HC1, 4 mL HNO3 and 3mL H2 O2 from the original 3 mL HC1 and 6 mL HNO3, the improved method making the Os measured signal approximately 2 times larger than before. Changes in oxidants composition increase the amount of the bitumen sample weight greatly from th eoriginal 0.2 g to 0. 4 g. Influence of H2 O2 added with routine reverse aqua regia and direct distillation from a Carius tube on the signal intensity of osmium measured by Inductively Coupled Plasma-MassSpectrometry( ICP-MS ). Was studied. Bitumen samples were dissolved and equilibrated with a known amount of 185Re and 190Os tracers in 2 mL HC1, 5 mL HNO3 and 2 mL H2O2 by a Carius tube at 200℃ for 12 h and 240℃ for 12 h, with the Os and Re separated using direct distillation or routine distillation and solvent extraction techniques, respectively. 187Re/185 Re, 187Os/190Os and 192Os/190Os were determined by ICP-MS. Bitumen samples in lead-zinc deposits from Yunnan Province were analyzed. The isochron ages was (60 ± 2 ) Ma ( MSWD = 2. 5, n = 7 ), and the initial 187Os/188Os values was 4. 36 ±0. 14. The results show that Re-Os isotope is an effective tool to date bitumen samples and the Os in the bitumen originated from the crust. The established method can be used to date and trace the source of bitumen samples.%沥青样品中Re、Os含量较低,且组成复杂,因含有大量有机质,在溶样过程中会释放大量CO2,需要大量氧化剂.控制样品称样量和氧化剂比例、用量对保证Os的回收率以及测量信号的稳定性非常重要.本文根

  7. Recent technological advances in the application of nano-catalytic technology to the enhanced recovery and upgrading of bitumen and heavy oils

    Energy Technology Data Exchange (ETDEWEB)

    Pereira Almao, P. [Calgary Univ., AB (Canada). Schulich School of Engineering

    2013-11-01

    Advances in Nanotechnology, such as manufacturing of nano-catalysts allow the online (during processing) and on site production of nano-catalysts for heavy oils upgrading. These inventions have also facilitated the development of two lines of heavy oils upgrading processes that make use of nano-catalysts for producing upgraded oil: In Situ Upgrading and Field Upgrading. Producing chemical upgrading of heavy oils is achievable and economically viable at lower temperatures and lower pressures than used in most upgraders if the use of nano-catalysts were implemented. The spontaneity of thermal, steam and hydro processing reactions for converting the different chemical families of hydrocarbons present in the heaviest fractions of heavy oils and bitumen (HO-B) into lighter products was shown recently. Spontaneity was measured by the value of the change of free energy at low pressure. These undesirable paths are spontaneous and uncontrollable under thermal cracking conditions, and require providing years of residence time for intermolecular hydrogen redistribution to minimize olefins polymerization, if at all possible. Instead, hydroprocessing in the presence of hydrogen activating catalysts would create an abundance of hydrogen radicals impeding large molecules condensation and olefins proliferation. In Situ Upgrading: performs coupled Enhanced Oil Recovery with In Reservoir Upgrading via Hot Fluid Injection (HFI). The heat handling of this HFI process and the production of transportable oil with no need of diluent from the start of operation completes the originality of it. This technology uses heavy fractions separated from produced oil to reintroduce heat into the reservoir along with suspended nano-catalysts and hydrogen. These components react in the well bore and inside the reservoir to release more heat (hydroprocessing reactions are exothermic) producing light gases and volatile hydrocarbons that contribute to increase oil detachment from the rock resulting in

  8. Industrial radiographies

    CERN Multimedia

    2005-01-01

    The Radiation Protection group wishes to remind CERN staff responsible for contractors performing X-ray inspections on the CERN sites that the firms must apply the legislation in force in their country of origin, in particular with regard to the prevention of risks relating to ionizing radiation. Industrial radiography firms called on to work on the CERN sites must also comply with the rules laid down in CERN's Radiation Safety Manual and be registered in the relevant CERN database. Since CERN is responsible for safety on its own site, a number of additional rules have been laid down for this kind of work, as set out in Radiation Protection Procedure PRP30 https://edms.cern.ch/file/346848/LAST_RELEASED/PRP30.pdf The CERN Staff Member responsible for the contract shall register the company and issue notification that an X-ray inspection is to be performed via the web interface at the following address: http://cern.ch/rp-radio

  9. Industrial Productivity

    Science.gov (United States)

    1977-01-01

    NASTRAN is an offshoot of the computer-design technique used in construction of airplanes and spacecraft. [n this technique engineers create a mathematical model of the aeronautical or space vehicle and "fly" it on the ground by means of computer simulation. The technique enables them to study performance and structural behavior of a number of different designs before settling on the final configuration and proceeding with construction. From this base of aerospace experience, NASA-Goddard developed the NASTRAN general purpose computer program, which offers an exceptionally wide range of analytic capability with regard to structures. NASTRAN has been applied to autos, trucks, railroad cars, ships, nuclear power reactors, steam turbines, bridges, and office buildings. NASA-Langley provides program maintenance services regarded as vital by many NASTRAN users. NASTRAN is essentially a predictive tool. It takes an electronic look at a computerire$.dedgn and reports how the structure will react under a great many different conditions. It can, for example, note areas where high stress levels will occur-potential failure points that need strengthening. Conversely, it can identify over-designed areas where weight and material might be saved safely. NASTRAN can tell how pipes stand up under strong fluid flow, how metals are affected by high temperatures, how a building will fare in an earthquake or how powerful winds will cause a bridge to oscillate. NASTRAN analysis is quick and inexpensive. It minimizes trial-and-error in the design process and makes possible better, safe, lighter structures affording large-scale savings in development time and materials. Some examples of the broad utility NASTRAN is finding among industrial firms are shown on these pages.

  10. In situ and laboratory investigation of the alteration of Boom Clay (Oligocene) at the air–geological barrier interface within the Mol underground facility (Belgium): Consequences on kerogen and bitumen compositions

    International Nuclear Information System (INIS)

    The Boom Clay formation (Oligocene) is studied as a reference host rock for methodological studies on deep geological disposal of radioactive waste. During excavation of galleries within the Clay formation (HADES underground research facility, Mol, Belgium), the physico-chemical conditions are significantly modified as an air–clay interface is created. In order to study the long-term impact of the air–clay contact on the organic matter contained in the Boom Clay, two types of samples were studied: (1) a reference series of clay samples having been in contact with the atmosphere of the HADES gallery for increasing times up to several years and (2) unaltered clay samples submitted to artificial oxidation in a ventilated oven at 80 °C. The evolution of geochemical data of the two series was compared using Rock-Eval pyrolysis, GC–MS and size exclusion chromatography. The organic matter of the unaltered clays sampled in the HADES galleries is dominated by type III kerogen (terrestrial) with some contribution of type II (marine) and is thermally immature. The evolution of geochemical parameters during air alteration for the two series are very similar. They show progressive oxidation of kerogen accompanied by the release of bitumen enriched in low molecular weight constituents. Molecular analysis evidences the presence of a complex mixture of aliphatic and aromatic O-bearing compounds, inherited from the degradation of kerogen as well as from the clay catalyzed oxidation of the bitumen. These results show that (1) air oxidation is a major process in the in situ alteration of the organic matter of Boom Clay within the HADES galleries, (2) laboratory oxidation experiments at 80 °C yield similar results as in situ air alteration of Boom Clay and (3) artificial air oxidation may be used to assess the long term exposure of the organic matter to air.

  11. 16 CFR 24.3 - Misuse of the terms “waterproof,” “dustproof,” “warpproof,” “scuffproof,” “scratchproof,” “scuff...

    Science.gov (United States)

    2010-01-01

    ... indicating that the product is not subject to wear in any other respect, to describe an industry product unless the outside surface of the product is immune to scratches or scuff marks, or is not subject...

  12. Porter's Industry Clusters in Irish Indigenous Industry

    OpenAIRE

    Chris van Egeraat; Eoin O'Malley

    1999-01-01

    Studies by Porter (1990) and others find that competitive and successful industries usually occur in the form of clusters of industries which are linked together through vertical or horizontal relationships. This paper assesses whether the sectors of Irish indigenous industry which look most competitive and successful form such clusters. It is concluded that there is only limited or qualified evidence of Porter-type clusters in Irish indigenous industry but, despite this, there has been a rel...

  13. Trajectory for Industrial Upgrade

    Institute of Scientific and Technical Information of China (English)

    LIU YUNYUN

    2010-01-01

    @@ The Ministry of Industry and Information Technology (MIIT) ordered the closure of outdated production lines in 18 industries as part of the country's plan to upgrade its industrial structure and move up the value chain.

  14. Trajectory for Industrial Upgrade

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The Ministry of Industry and Information Technology(MIIT) ordered the closure of outdated production lines in 18 industries as part of the country’s plan to upgrade its industrial structure and move up the

  15. Boosting Cultural Industry

    Institute of Scientific and Technical Information of China (English)

    Li Zhen

    2009-01-01

    @@ On July 22 of 2009, the State Council released the Revitalization Plan of Cultural Industry, which is the 11th revitalization plan for an industry following plans for steel, auto, textile, equipment manufacturing, ship-making, IT and other industries.

  16. Chemicals Industry Vision

    Energy Technology Data Exchange (ETDEWEB)

    none,

    1996-12-01

    Chemical industry leaders articulated a long-term vision for the industry, its markets, and its technology in the groundbreaking 1996 document Technology Vision 2020 - The U.S. Chemical Industry. (PDF 310 KB).

  17. Understanding the Canadian oil sands industry's greenhouse gas emissions

    International Nuclear Information System (INIS)

    The magnitude of Canada's oil sands reserves, their rapidly expanding and energy intensive production, combined with existing and upcoming greenhouse gas (GHG) emissions regulations motivate an evaluation of oil sands-derived fuel production from a life cycle perspective. Thirteen studies of GHG emissions associated with oil sands operations are reviewed. The production of synthetic crude oil (SCO) through surface mining and upgrading (SM and Up) or in situ and upgrading (IS and Up) processes is reported to result in emissions ranging from 62 to 164 and 99 to 176 kgCO2eq/bbl SCO, respectively (or 9.2-26.5 and 16.2-28.7 gCO2eq MJ-1 SCO, respectively), compared to 27-58 kgCO2eq/bbl (4.5-9.6 gCO2eq MJ-1) of crude for conventional oil production. The difference in emissions intensity between SCO and conventional crude production is primarily due to higher energy requirements for extracting bitumen and upgrading it into SCO. On a 'well-to-wheel' basis, GHG emissions associated with producing reformulated gasoline from oil sands with current SM and Up, IS and Up, and in situ (without upgrading) technologies are 260-320, 320-350, and 270-340 gCO2eq km-1, respectively, compared to 250-280 gCO2eq km-1 for production from conventional oil. Some variation between studies is expected due to differences in methods, technologies studied, and operating choices. However, the magnitude of the differences presented suggests that a consensus on the characterization of life cycle emissions of the oil sands industry has yet to be reached in the public literature. Recommendations are given for future studies for informing industry and government decision making.

  18. Extractive industry a burden or an opportunity for sustainable development?

    Directory of Open Access Journals (Sweden)

    Aurela SHTIZA

    2013-04-01

    Full Text Available The shortage of raw materials in global markets and the sky rocketing of commodityprices, have induced European authorities to take initiatives to improve innovation inEurope by creating the European Innovation Partnership on Raw Materials (2012 and make inventory of the existing European raw materials. Albania is a rich country in natural raw materials, such as chromium, copper, ferronickel, coal, bitumen as well ascrude oil which might supply primary and secondary raw materials for some of the European needs. This literature review discusses the role of the Albanian institutions, the natural resources industry, potential investors and stakeholders in order to provide a setof indicators and platforms that can help to develop the extractive industry in Albania and monitor amelioration within sustainable development principles. A map with the potential prospects of the natural resources will be a first step in identifying the further potential for exploitation. Mineral resource policies and governance, sustainable processing and supply chain as well as environmental management information system (EMIS are some of the crucial tools identified, which will help to set up the indicators and quantify the achievements in environmental management in Albania. Moreover, the integration of practices that will support institutional capacity building; follow-up practices; the mainstreaming of global environment into planning; and the compliance monitoring process will additionally improve the environmental situation in Albania. Aligning business strategy with environmental policy, socio-economic analysis, environmental auditing are decisive tools in order to provide the Albanian authorities with a clear overview of the economic costs and the social benefits for sustainable development of the extractive sector in Albania.

  19. Air quality in the Industrial Heartland of Alberta, Canada and potential impacts on human health

    Science.gov (United States)

    Simpson, Isobel J.; Marrero, Josette E.; Batterman, Stuart; Meinardi, Simone; Barletta, Barbara; Blake, Donald R.

    2013-12-01

    The “Industrial Heartland” of Alberta is Canada's largest hydrocarbon processing center, with more than 40 major chemical, petrochemical, and oil and gas facilities. Emissions from these industries affect local air quality and human health. This paper characterizes ambient levels of 77 volatile organic compounds (VOCs) in the region using high-precision measurements collected in summer 2010. Remarkably strong enhancements of 43 VOCs were detected, and concentrations in the industrial plumes were often similar to or even higher than levels measured in some of the world's largest cities and industrial regions. For example maximum levels of propene and i-pentane exceeded 100 ppbv, and 1,3-butadiene, a known carcinogen, reached 27 ppbv. Major VOC sources included propene fractionation, diluent separation and bitumen processing. Emissions of the measured VOCs increased the hydroxyl radical reactivity (kOH), a measure of the potential to form downwind ozone, from 3.4 s-1 in background air to 62 s-1 in the most concentrated plumes. The plume value was comparable to polluted megacity values, and acetaldehyde, propene and 1,3-butadiene contributed over half of the plume kOH. Based on a 13-year record (1994-2006) at the county level, the incidence of male hematopoietic cancers (leukemia and non-Hodgkin lymphoma) was higher in communities closest to the Industrial Heartland compared to neighboring counties. While a causal association between these cancers and exposure to industrial emissions cannot be confirmed, this pattern and the elevated VOC levels warrant actions to reduce emissions of known carcinogens, including benzene and 1,3-butadiene.

  20. INDUSTRI KREATIF INDONESIA: PENDEKATAN ANALISIS KINERJA INDUSTRI

    Directory of Open Access Journals (Sweden)

    Ahmad Kamil

    2015-10-01

    Full Text Available In 2008, the Department of Commerce of the Republic of Indonesia has launched a creative economic development documents interpreted the 2025 Indonesia became the starting point and guide the development of the creative economy in Indonesia. With the existence of this document, the industry and its stakeholders or other stakeholders can readily develop the creative economy in Indonesia. Economic development in the direction of the creative industries is one manifestation of optimism aspiration to support the Master Plan for the Acceleration and Expansion of Indonesia's Economic Development in realizing the vision of Indonesia are being developed nation. The main objective of this study is the first to analyze the role of the creative industries in Indonesia for labor, value added and productivity, secondly, to analyze the performance trend of the creative industries sector, and third, to analyze the factors affecting the performance of the creative industries sector in Indonesia. Under Indonesia Standard Industrial Classification (ISIC and codes 151-372 (manufacturing industries category identified 18 industry groups belonging to the creative industries, showed that the performance of the national creative industries has been relatively high (in terms of trend analysis of the performance of the industrial creative. Furthermore, regression analysis of panel data (econometrics indicates that company size (SIZE, wages for workers (WAGE and the content of local inputs (LOCAL has a significant impact on the performance of Indonesia's creative industry. Meanwhile, the concentration ratio (CR4 no consequences but have koresi significantly positive effect on the performance of Indonesia’s creative industry.

  1. Athletic Apparel Industry Analysis

    Institute of Scientific and Technical Information of China (English)

    JIE; TAN; NAFISUL; ISLAM; MILAN; MITRASINOVIC

    2015-01-01

    Industry Overview The athletic apparel industry is the fastest growing segment of global clothing industry differentiated by offering high quality athletic apparel made of technically advanced fabrics.The athletic apparel is made for a variety of sports and physical activities for children,men and women and enhances comfort and performance of athletes.The industry consists of companies that design and market

  2. Automotive Industry in Malaysia

    DEFF Research Database (Denmark)

    Wad, Peter; Govindaraju, V.G.R. Chandran

    2011-01-01

    This paper explains the evolution and assesses the development of the Malaysian automotive industry within the premise of infant industry and trade protection framework as well as extended arguments of infant industry using a global value chain perspective. The Malaysian automotive industry...

  3. Opportunities for Taiwan's industry

    OpenAIRE

    Jen-Lien Lin; Guang-Way Jang

    2004-01-01

    The Industrial Technology Research Institute (ITRI) in Taiwan recently introduced nanotechnology to local traditional industries. Nanotechnologies provide a great opportunity for these companies to meet outside challenges and join the blooming electronic and optoelectronic industries. The Nanotechnology Community (NTC) was established in 2003, with the goal of finding commercial applications. This year, the Taiwan Nanotechnology Industrialization Promotion Association (TANIPA) was established...

  4. Opportunities for Taiwan's industry

    Directory of Open Access Journals (Sweden)

    Jen-Lien Lin

    2004-12-01

    Full Text Available The Industrial Technology Research Institute (ITRI in Taiwan recently introduced nanotechnology to local traditional industries. Nanotechnologies provide a great opportunity for these companies to meet outside challenges and join the blooming electronic and optoelectronic industries. The Nanotechnology Community (NTC was established in 2003, with the goal of finding commercial applications. This year, the Taiwan Nanotechnology Industrialization Promotion Association (TANIPA was established, with the support of the Industrial Development Bureau, Ministry of Economic Affairs (MOEA, to formulate a strategy for industrial applications in Taiwan and to facilitate cooperation between industries, universities, and research institutes.

  5. BioDiesel as Additive in High Pressure and Temperature Steam Recovery of Heavy Oil and Bitumen Utilisation d’un biogazole comme additif pour la récupération d’huile lourde et de bitume par injection de vapeur à hautes pression et température

    OpenAIRE

    Babadagli T.; Ozum B.

    2012-01-01

    Use of additives to improve the efficiency of thermal heavy oil and bitumen recovery processes has been studied extensively over the decades. Two common types of additives used in thermal applications, mainly steam assisted recovery, are solvents and surfactants. Commercial use of solvents has setbacks due to their high costs and retrieval difficulties. Cost and stability of the surfactants under reservoir operating temperature and pressure are the major concerns. We propose the use of bioDie...

  6. Radioactivity concentrations and dose assessment for bitumen and soil samples around a bituminous deposit in Ondo State, Nigeria; Radioactivite et evaluation de la dose dans des echantillons de bitume et de sol autour d'un depot bitumineux dans l'etat d'Ondo, Nigeria

    Energy Technology Data Exchange (ETDEWEB)

    Ademola, J.A.; Ademonehin, S. [Department of Physics, University of Ibadan, Ibadan (Nigeria)

    2010-07-15

    Bitumen samples and soil samples around a bituminous deposit in Ondo State, Nigeria, were analysed for {sup 40}K, {sup 226}Ra and {sup 232}Th employing gamma-ray spectrometry. The activity concentrations of {sup 40}K, {sup 226}Ra and {sup 232}Th in soil varied from (45.2 {+-} 5.3) to (484.2 {+-} 25.9), BDL (below detectable limit) to (27.7 {+-} 2.1) and (22.8 {+-} 2.7) to (62.4 {+-} 6.8) Bq.kg{sup -1}, respectively. The corresponding mean values were (240.2 {+-} 133.5), (13.3 {+-} 8.0) and (40.0 {+-} 10.2) Bq.kg{sup -1}, respectively. The mean activity concentrations of the radionuclides in the bitumen were (58.4 {+-} 36.4), (16.1 {+-} 13.3) and (32.5 {+-} 13.1) Bq.kg{sup -1}, respectively, for {sup 40}K, {sup 226}Ra and {sup 232}Th. The mean absorbed dose and effective dose for the soil samples were (41.5 {+-} 8.9) nGy.h{sup -1} and (50.7 {+-} 10.9) {mu}Sv.y{sup -1}, respectively, while those of the bitumen samples were (29.5 {+-} 15.6) nGy.h{sup -1} and (36.1 {+-} 19.1) {mu}Sv.y{sup -1}, respectively. For radiological hazard assessment, the radium equivalent activity and the external hazard index were determined. The values of the radium equivalent activity and external hazard index obtained for the soil and bitumen samples were lower than the recommended limit. (authors)

  7. Development of Viscosity Model for Petroleum Industry Applications

    Science.gov (United States)

    Motahhari, Hamed reza

    Heavy oil and bitumen are challenging to produce and process due to their very high viscosity, but their viscosity can be reduced either by heating or dilution with a solvent. Given the key role of viscosity, an accurate viscosity model suitable for use with reservoir and process simulators is essential. While there are several viscosity models for natural gases and conventional oils, a compositional model applicable to heavy petroleum and diluents is lacking. The objective of this thesis is to develop a general compositional viscosity model that is applicable to natural gas mixtures, conventional crudes oils, heavy petroleum fluids, and their mixtures with solvents and other crudes. The recently developed Expanded Fluid (EF) viscosity correlation was selected as a suitable compositional viscosity model for petroleum applications. The correlation relates the viscosity of the fluid to its density over a broad range of pressures and temperatures. The other inputs are pressure and the dilute gas viscosity. Each fluid is characterized for the correlation by a set of fluid-specific parameters which are tuned to fit data. First, the applicability of the EF correlation was extended to asymmetric mixtures and liquid mixtures containing dissolved gas components. A new set of mass-fraction based mixing rules was developed to calculate the fluid-specific parameters for mixtures. The EF correlation with the new set of mixing rules predicted the viscosity of over 100 mixtures of hydrocarbon compounds and carbon dioxide with overall average absolute relative deviations (AARD) of less than 10% either with measured densities or densities estimated by Advanced Peng-Robinson equation of state (APR EoS). To improve the viscosity predictions with APR EoS-estimated densities, general correlations were developed for non-zero viscosity binary interaction parameters. The EF correlation was extended to non-hydrocarbon compounds typically encountered in natural gas industry. It was

  8. Input chains and industrialization

    OpenAIRE

    Ciccone, Antonio

    2000-01-01

    A key aspect of industrialization is the adoption of increasing-returns-to-scale, industrial, technologies. Two other, well-documented aspects are that industrial technologies are adopted throughout intermediate-input chains and that they use intermediate inputs intensively relative to the technologies they replace. These features of industrial technologies combined imply that countries with access to similar technologies may have very different levels of industrial...

  9. Diagnosis on Exhibition Industry

    Institute of Scientific and Technical Information of China (English)

    Yan Manman

    2010-01-01

    @@ China's exhibition industry, often renowned as the locomotive of the tertiary industry, has developed rapidly in recent years and has become the sunrise industry and gets much concern. However, in exhibition industry circles in China, there is a saying being passed around "rushed exhibitions with bad service, property rights protection is badly needed; a low threshold with high demand, and 5 out of 10 exhibitions are disorganized." This jingle reflects many problems that currently exist in the exhibition industry in China.

  10. EUB Decision 2006-112 : Suncor Energy Inc. application for expansion of an oil sands mine (North Steepbank mine extension) and a bitumen upgrading facility (Voyageur Upgrader) in the Fort McMurray area

    International Nuclear Information System (INIS)

    needed to increase the recovery of bitumen resources and provide the upgrading capacity required by Suncor for additional bitumen production from its mining and in situ projects. 1 fig

  11. The voice of Canada's oil and natural gas industry : oil and natural gas

    International Nuclear Information System (INIS)

    The Canadian Association of Petroleum Producers (CAPP) represents 150 members of the oil and gas industry, which together are responsible for approximately 95 per cent of the oil and natural gas produced in Canada. The upstream sector comprises companies that explore for, develop and produce petroleum resources, while the downstream sector involves companies that refine and market the resources. CAPP works closely with governments of 11 of Canada's 13 provinces and territories and with public groups to represent upstream producers active across the country. The enhancement of the economic well-being and sustainability of the upstream petroleum industry is the mission of the CAPP. The main priorities of the CAPP are: Environment, Health and Safety Stewardship, reasonable and timely access to resources, competitiveness of the Canadian industry on a global basis, the secure and efficient access to markets, and open and constructive public, government and media affairs. Some of the issues dealt with by the CAPP are sour gas, flaring, venting and industry-landowner relations, improved safety performance, federal issues such as corporate taxes and environmental issues, Aboriginal and First Nations issues, transportation costs for natural gas on major pipelines, and oil and sands bitumen issues, to name a few. The board of the CAPP is made up of 32 members. The work is carried out by hundreds of volunteers from member companies who provide their time and expertise for various committees and working groups, as well as a staff of approximately 40 people to assist them. The members provide the entire funding for CAPP, which is located in Calgary, Alberta. The document concluded with a few facts concerning the petroleum industry in general. 12 figs

  12. Industrial initiatives in the wind industry

    International Nuclear Information System (INIS)

    Industrial initiatives are methods of lobbying and marketing to increase the activity, revenues, profits, and commercial viability of an industry. They may be undertaken by industry individuals or firms, industry groups, government agencies, or combinations of all these. In Canada, one example of an industrial initiative is the Canadian Wind Energy Association. Other initiatives relevant to the wind power industry include Technology Inflow Programs sponsored by External Affairs Canada, used for visiting foreign firms with the view to licensing foreign technology, and Industrial Research Assistance Programs to develop or adapt new technologies in partnership with government. The Conservation/Renewable Energy Council, Small Power Producers of Alberta, and Independent Power Producers Society of Ontario are also active in supporting wind energy initiatives. In other countries, notable initiatives for wind energy include the Danish wind turbine warranty guarantee program. The Western Wind Industry Network of Canada conducts regional lobbying. It is suggested that in Canada, more such networks are needed, as well as joint ventures with utilities and governments, and more work with the regulatory agencies, to promote wind energy

  13. Long-Term Performance of the Laguna de Barlovento Reservoir Water-Proofing using a PVC-P Geo membrane; Impermeabilizacion de la balsa de la Laguna de Barlovento con geomembrana de PVC-P: evolucion a lo largo del tiempo

    Energy Technology Data Exchange (ETDEWEB)

    Blanco Fernandez, M.; Leiro Lopez, A.; Soriano Carrillo, J.; Crespo Mucientes, M.; Zornberg, J.; Aguilar Gonzalez, E.; Rico Arnaiz, G.; Pargada Iglesias, L.

    2014-02-01

    The Laguna de Barlovento reservoir was one of the most important European hydraulic projects at the time of its construction because of its high capacity and challenging location. At the time, the designers decided to waterproof this reservoirs with a geo membrane of plasticized polyvinyl chloride (PVC-P). This paper documents the initial characteristics of the geo membrane and its performance since its installation until 2010. The material characterization includes a comprehensive testing program, the results of which are presented. They include quantification of the geo membrane thickness, amount and nature of plasticizers, tensile properties, fold ability under low temperatures, dynamic impact resistance, puncture resistance, welding strength (both in the manufacturing facility and in the field), as well as the use of techniques involving optical and scanning electron microscopy. In addition, advanced analytical techniques, such as Fourier Transform Infrared Spectroscopy (FTIR), Gas Chromatography (GC) and Mass spectrometry (MS), were used in order to identify the plasticizers used in the geo membrane formulation. Fold ability tests were found to provide early indication of degradation. Results from reflection optical and electron scanning microscopy showed that, after 19 nineteen years of installation, the geo membrane remains in good conditions, particularly on the non-exposed side. (Author)

  14. Industrial communication technology handbook

    CERN Document Server

    Zurawski, Richard

    2005-01-01

    The Industrial Communication Technology Handbook focuses on current and newly emerging communication technologies and systems that are evolving in response to the needs of industry and the demands of industry-led consortia and organizations.Organized into two parts, the text first summarizes the basics of data communications and IP networks, then presents a comprehensive overview of the field of industrial communications. This book extensively covers the areas of fieldbus technology, industrial Ethernet and real-time extensions, wireless and mobile technologies in industrial applications, the

  15. Application of foamed bitumen cold-place recycling in heavy repair of highway%泡沫沥青就地冷再生在公路大修中的应用

    Institute of Scientific and Technical Information of China (English)

    周勇

    2009-01-01

    The paper introduces the application of the foamed bitumen cold-place recycling in the heavy repair of highways in Anhui province, illustrates the scheme selection and construction craft, and evaluates the application effect from conomy, the durability and well resistant reflection crack in foundation, so it provides experience for the selection for heavy repair of highways and the recycling utility of pavement used materials.%介绍了泡沫沥青就地冷再生在安徽省公路大修工程中的应用情况,就其方案比选及施工工艺流程进行了阐述,从其经济性、耐久性及良好的抗基层反射裂缝等方面对其使用效果进行了评价,为公路大修方案的选择及路面废旧料再生利用提供了可借鉴的经验.

  16. An Emerging Pillar Industry

    Institute of Scientific and Technical Information of China (English)

    LI ZHENYU

    2010-01-01

    @@ The Fifth Beijing International Cultural and Creative Industry Exposition (ICCIE), held November 17-21 in Beijing, was a feast for the eyes and mind. It showcased the enormous glamour and commercial opportunities promised by the cultural and creative industry.

  17. FERMILAB: Working with industry

    International Nuclear Information System (INIS)

    Highlighting the increasing interplay between high energy physics and industry, this year's annual meeting of Fermilab's Industrial Affiliates featured two roundtable discussions on new technology related to high energy physics

  18. The World Oil Industry

    Science.gov (United States)

    Rand, Christopher T.

    1976-01-01

    America's domestic petroleum industry and the international industry have been dominated by seven major firms. Although production costs decreased, sale prices soared with developing political-corporate interrelationships. (MR)

  19. Industry Lecture 2010

    DEFF Research Database (Denmark)

    Kragh, Helge

    2010-01-01

    Sammendrag af "Industry Lecture", Norsk Kjemisk Selskap, Universitetet i Oslo, givet 15/10 2010.......Sammendrag af "Industry Lecture", Norsk Kjemisk Selskap, Universitetet i Oslo, givet 15/10 2010....

  20. Innovation and Industrial Strategy

    OpenAIRE

    Haustein, H.-D.

    1981-01-01

    The conditions and consequences of industrial development are currently being widely discussed. One reason for this attention is the marked decline in industrial growth rates in many countries of the world, including those with low levels of industrialization. Aware that the successful management of innovation might be a cornerstone in solving the problem of industrial growth in both the market and planned economies, the members of IIASA's Innovation Management Task held a task force mee...

  1. Conditions for industrial production

    DEFF Research Database (Denmark)

    Jensen, Karsten Ingerslev; Schultz, Jørgen Munthe; Brauer, H.

    1996-01-01

    The possibility of an industrial aerogel glazing production is discussed with respect to sample size, sales volume and prices. Different ways of an industrial assembling line is outlined and the total costs of a 1 square meter aerogel glazing is calculated.......The possibility of an industrial aerogel glazing production is discussed with respect to sample size, sales volume and prices. Different ways of an industrial assembling line is outlined and the total costs of a 1 square meter aerogel glazing is calculated....

  2. Security in Industrial Networks

    OpenAIRE

    Sørensen, Jan Tore

    2007-01-01

    A major trend in the automation and power industries is the transition from closed proprietary network solutions to open TCP/IP protocols running on Ethernet technologies. As these industries converge on an all IP platform, new challenges and requirements on the security level of the devices arise. The introduction of integrated operations in the oil and gas industry has provided many benefits for the industry, but it has also opened up the information flow between Distributed Control Systems...

  3. The pharmaceutical industry

    OpenAIRE

    1982-01-01

    The attitude of general practitioners to the drug industry is interesting: on the one hand the industry researches and produces new drugs which are essential to the practice of modern medicine; on the other hand, doctors are sceptical that the information received from the industry is too biased. It is time for students and doctors to be trained in a more critical approach to the industry and its representatives.

  4. PROSPEK INDUSTRI PARIWISATA INDONESIA

    OpenAIRE

    Siregar, Nurhayati

    2010-01-01

    Indonesia's tourism industry developed serious since the mid-1980s following a decline in revenue from oil and gas (oil). Since the 1997 economic crisis, Indonesia's tourism industry to survive. This study showed that Indonesia's tourism sector has great potential. There are five factors that will make the tourism industry has the potential to grow. First, the trend of world tourism industry will increase in the 21st century. Second, the contribution of tourism sector in economic development ...

  5. Kenya Leather Industry

    OpenAIRE

    World Bank Group

    2015-01-01

    In 2014, Kenya’s Ministry of Industrialization requested technical assistance from the World Bank to conduct competitiveness assessments and develop competitiveness strategies for four key industries: textiles and apparel, food processing, furniture, and leather and leather products. In the context of Kenya’s long-term vision to become an industrialized middle-income country by 2030, its l...

  6. Networks and Industry Structure

    OpenAIRE

    Johnson, F P

    1995-01-01

    This paper explores how the network approach to marketing might be informed by concepts drawn from traditional industry structure analysis. It argues that industry structures defined by small numbers of participants such as oligopolies are more likely to lead to network effects while industry structures that approach perfect competition are unlikely to involve network formation.

  7. 2011 Training Industry Report

    Science.gov (United States)

    Training, 2011

    2011-01-01

    This article presents "Training" magazine's exclusive analysis of the U.S. training industry, featuring 2011 training expenditures, budgetary allocations, delivery methods, and training priorities. Now in its 30th year, The Industry Report is recognized as the training industry's most trusted source of data on budgets, staffing, and programs. This…

  8. Industry recession to persist

    International Nuclear Information System (INIS)

    This paper reports that the depressed U.S. oil and gas industry is not likely to recover soon, witnesses told the Texas Railroad Commission's state of the petroleum industry hearing. Major companies and independent operators agreed the U.S. petroleum industry is near a state of collapse. Many the producers are despairing about the chances of surviving the latest economic downturn

  9. Robotics and Industrial Arts.

    Science.gov (United States)

    Edmison, Glenn A.; And Others

    Robots are becoming increasingly common in American industry. By l990, they will revolutionize the way industry functions, replacing hundreds of workers and doing hot, dirty jobs better and more quickly than the workers could have done them. Robotics should be taught in high school industrial arts programs as a major curriculum component. The…

  10. Contract Training for Industry.

    Science.gov (United States)

    Averill, Donald F.

    1983-01-01

    Describes contract training whereby industries arrange with community colleges, technical institutes, and vocational schools to prepare employees for specific job assignments. Indicates that industrial training performed under contract with public institutions should be encouraged in favor of expansion of training that industry performs for…

  11. 有机硅在皮革中的应用%Application of the Organic Silicone in Leather Industry

    Institute of Scientific and Technical Information of China (English)

    张建雨; 桑莹莹

    2011-01-01

    The characteristics and applications of organic silicone in leather industry were described. They were mainly used as waterproof agents, tanning agents, fatliquoring agents, finishing agents and so on. Main manufacturers and performance of organic silicone compounds used as leather chemical materials at home and abroad were reviewed. Finally, the suggestions about development of organic silicone leather chemical materials were pointed out and their applications in the future were prospected.%介绍了有机硅的特性及在皮革工业中的主要应用,其主要用作皮革防水剂、鞣剂、加脂剂、涂饰剂等.综述了国内外有机硅皮化材料的主要生产厂家及产品性能.对未来发展有机硅皮化材料提出了几点意见,并对其在皮革中的应用前景进行了展望.

  12. INDUSTRI KREATIF INDONESIA: PENDEKATAN ANALISIS KINERJA INDUSTRI

    OpenAIRE

    Ahmad Kamil

    2015-01-01

    In 2008, the Department of Commerce of the Republic of Indonesia has launched a creative economic development documents interpreted the 2025 Indonesia became the starting point and guide the development of the creative economy in Indonesia. With the existence of this document, the industry and its stakeholders or other stakeholders can readily develop the creative economy in Indonesia. Economic development in the direction of the creative industries is one manifestation of optimism aspiration...

  13. Industrial statistics with Minitab

    CERN Document Server

    Cintas, Pere Grima; Llabres, Xavier Tort-Martorell

    2012-01-01

    Industrial Statistics with MINITAB demonstrates the use of MINITAB as a tool for performing statistical analysis in an industrial context. This book covers introductory industrial statistics, exploring the most commonly used techniques alongside those that serve to give an overview of more complex issues. A plethora of examples in MINITAB are featured along with case studies for each of the statistical techniques presented. Industrial Statistics with MINITAB: Provides comprehensive coverage of user-friendly practical guidance to the essential statistical methods applied in industry.Explores

  14. The UK Casting Industry

    Institute of Scientific and Technical Information of China (English)

    Jincheng Liu

    2006-01-01

    The casting production in the UK in 2004 is presented and analysed. The UK casting industry has played an important role in world casting and manufacturing production. However recent years the rapid development of some developing countries has been shifting the casting production from the western industrialized countries including the UK. The UK casting industry and associated research and technology organizations, universities have been working together very hard to face the serious competition to make the UK casting industry have a sustainable future. The UK casting industry remains strong and plays an important role in world casting and manufacturing production.

  15. Uranium industry annual 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-04-22

    The Uranium Industry Annual 1998 (UIA 1998) provides current statistical data on the US uranium industry`s activities relating to uranium raw materials and uranium marketing. It contains data for the period 1989 through 2008 as collected on the Form EIA-858, ``Uranium Industry Annual Survey.`` Data provides a comprehensive statistical characterization of the industry`s activities for the survey year and also include some information about industry`s plans and commitments for the near-term future. Data on uranium raw materials activities for 1989 through 1998, including exploration activities and expenditures, EIA-estimated reserves, mine production of uranium, production of uranium concentrate, and industry employment, are presented in Chapter 1. Data on uranium marketing activities for 1994 through 2008, including purchases of uranium and enrichment services, enrichment feed deliveries, uranium fuel assemblies, filled and unfilled market requirements, and uranium inventories, are shown in Chapter 2. The methodology used in the 1998 survey, including data edit and analysis, is described in Appendix A. The methodologies for estimation of resources and reserves are described in Appendix B. A list of respondents to the ``Uranium Industry Annual Survey`` is provided in Appendix C. The Form EIA-858 ``Uranium Industry Annual Survey`` is shown in Appendix D. For the readers convenience, metric versions of selected tables from Chapters 1 and 2 are presented in Appendix E along with the standard conversion factors used. A glossary of technical terms is at the end of the report. 24 figs., 56 tabs.

  16. Metalcasting Industry Technology Roadmap

    Energy Technology Data Exchange (ETDEWEB)

    none,

    1998-01-01

    The Roadmap sets out the strategy for pursuing near-, mid-, and long-term goals set out by industry and for carrying out the cooperative agreement between the U.S. Department of Energy and industry. The Roadmap outlines key goals for products and markets, materials technology, manufacturing technology, environmental technology, human resources, and industry health programs. The Roadmap sets out the strategy for pursuing near-, mid-, and long-term goals set out by industry and for carrying out the cooperative agreement between the U.S. Department of Energy and industry. The Roadmap sets out the strategy for pursuing near-, mid-, and long-term goals set out by industry and for carrying out the cooperative agreement between the U.S. Department of Energy and industry.

  17. Landscape of Industry: Transformation of (Eco Industrial Park through history

    Directory of Open Access Journals (Sweden)

    Archana Sharma

    2013-11-01

    Full Text Available The landscape of industry has been changing over time. Industry has transformed and many tangents have emerged from the sporadic home-based cottage industries to geographically scattered large manufacturing industries to co-located industrial parks to environment friendly eco-industrial parks. Curiosity about the catalysts that bring about the transformation of industrial landscape is the motivation of this article. Through the narrative on Industrial Park and the gradual shift towards Eco-Industrial Park, this article aims to shed light on the context and conditions that act as catalysts for industrial transformations, so as to serve as a reference for predicting future changes in industrial landscape.

  18. 接枝杜仲胶对干法橡胶沥青混合料的改性机理与效果%Modification mechanism and effect of grafted eucommia ulmoides gum on dry-process rubber bitumen mixture

    Institute of Scientific and Technical Information of China (English)

    李志刚; 李聪; 蔡敏东

    2014-01-01

    Domestic natural rubber, the eucommia ulmoides gum( EUG) , was used to create chemi-cal links between rubber crumb and asphalt.After rubber crumb was mixed with EUG, it was found that by the microscopic analysis and macroscopic representation of mixture, EUG owns double bond structure which could be vulcanized with the sulfur of rubber crumb.EUG was grafted with maleic anhydride ( MA) reacting with the asphalt amino-group, and thus chemical links were built between the EUG and asphalt.Then the modification effect of grafted eucommia ulmoides gum, EUG and imports was experimented by the microscopic and performance test of rubber bitumen, the high and low temperature performance, water stability and mechanical property of dry-process rubber bitumen mixture.Test results show that EUG can contribute to the vulcanization of rubber crumb, but it can-not create the reaction network between the vulcanized rubber crumb and asphalt,so the rubber as-phalt mixture performance improvement is not obvious.EUG grafted with MA establishes the re-sponse network of vulcanized rubber crumb and asphalt, so the rubber asphalt mixture performance improvement is obvious, and the modification effect can reach the level of foreign products.There-fore, EUG can only achieve chemical reaction between rubber powder and asphalt through grafting, which is the fundament of the dry rubber asphalt mixture.%利用国内特有天然橡胶---杜仲胶来建立橡胶粉与沥青之间的化学链接。首先通过橡胶粉干拌杜仲胶后的微观分析和宏观表象,发现杜仲胶的双键结构可以与橡胶粉的硫交联硫化;并将杜仲胶接枝于沥青氨基反应的马来酸酐,在杜仲胶与沥青之间产生化学链接。然后通过对橡胶沥青微观和路用性能,以及干法橡胶沥青混合料高低温、水稳性及力学性能进行试验,研究了杜仲胶、国外进口橡胶反应剂的改性效果。试验结果表明:杜仲胶可以促进橡胶粉的硫化

  19. Calculation of the thermodynamic properties at elevated temperatures and pressures of saturated and aromatic high molecular weight solid and liquid hydrocarbons in kerogen, bitumen, petroleum, and other organic matter of biogeochemical interest

    Energy Technology Data Exchange (ETDEWEB)

    Richard, L.; Helgeson, H.C. [Univ. of California, Berkeley, CA (United States). Dept. of Geology and Geophysics

    1998-12-01

    To supplement the relatively sparse set of calorimetric data available for the multitude of high molecular weight organic compounds of biogeochemical interest, group additivity algorithms have been developed to estimate heat capacity power function coefficients and the standard molal thermodynamic properties at 25 C and 1 bar of high molecular weight compounds in hydrocarbon source rocks and reservoirs, including crystalline and liquid isoprenoids, steroids, tricyclic diterpenoids, hopanoids, and polynuclear aromatic hydrocarbons. A total of ninety-six group contributions for each coefficient and property were generated from the thermodynamic properties of lower molecular weight reference species for which calorimetric data are available in the literature. These group contributions were then used to compute corresponding coefficients and properties for {approximately}360 representative solid and liquid high molecular weight compounds in kerogen, bitumen, and petroleum for which few or no experimental data are available. The coefficients and properties of these high molecular weight compounds are summarized in tables, together with those of the groups and reference species from which they were generated. The tabulated heat capacity power function coefficients and standard molal thermodynamic properties at 25 C and 1 bar include selected crystalline and liquid regular, irregular and highly branched isoprenoids, tricyclic diterpanes, 17{alpha}(H)- and 17{beta}(H)-hopanes, 5{alpha}(H),14{alpha}(H)-, 5{beta}(H),14{alpha}(H)-, 5{alpha}(H),14{beta}(H)-, and 5{beta}(H),14{beta}(H)-steranes, double ether- and ester-bonded n-alkanes, and various polynuclear aromatic hydrocarbons, including methylated biphenyls, naphthalenes, phenanthrenes, anthracenes, pyrenes, and chrysenes. However, corresponding coefficients and properties for many more saturated and unsaturated high molecular weight hydrocarbons can be estimated from the equations of state group additivity algorithms

  20. Calculation of the thermodynamic properties at elevated temperatures and pressures of saturated and aromatic high molecular weight solid and liquid hydrocarbons in kerogen, bitumen, petroleum, and other organic matter of biogeochemical interest

    Science.gov (United States)

    Richard, Laurent; Helgeson, Harold C.

    1998-12-01

    To supplement the relatively sparse set of calorimetric data available for the multitude of high molecular weight organic compounds of biogeochemical interest, group additivity algorithms have been developed to estimate heat capacity power function coefficients and the standard molal thermodynamic properties at 25°C and 1 bar of high molecular weight compounds in hydrocarbon source rocks and reservoirs, including crystalline and liquid isoprenoids, steroids, tricyclic diterpenoids, hopanoids, and polynuclear aromatic hydrocarbons. A total of ninety-six group contributions for each coefficient and property were generated from the thermodynamic properties of lower molecular weight reference species for which calorimetric data are available in the literature. These group contributions were then used to compute corresponding coefficients and properties for ˜360 representative solid and liquid high molecular weight compounds in kerogen, bitumen, and petroleum for which few or no experimental data are available. The coefficients and properties of these high molecular weight compounds are summarized in tables, together with those of the groups and reference species from which they were generated. The tabulated heat capacity power function coefficients and standard molal thermodynamic properties at 25°C and 1 bar include selected crystalline and liquid regular, irregular and highly branched isoprenoids, tricyclic diterpanes, 17α(H)- and 17β(H)-hopanes, 5α(H),14α(H)-, 5β(H),14α(H)-, 5α(H),14β(H)-, and 5β(H),14β(H)-steranes, double ether- and ester-bonded n-alkanes, and various polynuclear aromatic hydrocarbons, including methylated biphenyls, naphthalenes, phenanthrenes, anthracenes, pyrenes, and chrysenes. However, corresponding coefficients and properties for many more saturated and unsaturated high molecular weight hydrocarbons can be estimated from the equations of state group additivity algorithms. Calculations of this kind permit comprehensive