WorldWideScience

Sample records for bitumen waterproofing industry

  1. Retrospective exposure assessment for carcinogenic agents in bitumen waterproofing industry in Finland and Denmark

    Energy Technology Data Exchange (ETDEWEB)

    Anttila, P.; Heikkila, P.; Makela, M.; Schlunssen, V.; Priha, E. [Finnish Institute of Occupational Health, Helsinki (Finland)

    2009-03-15

    The purpose of the study was (I) to identify the carcinogenic agents that may cause confounding when studying the exposure-response relationship between bitumen fume exposure and cancer among roofing membrane-manufacturing workers and roofers and (ii) to assess exposures to the identified carcinogens and bitumen fume in roofing membrane manufacturing and roofing in Finland and Denmark from 1950 to 2005. Information on the use of carcinogenic agents and other relevant data were collected through semi-structured interviews of senior employees in the industry. Semi-quantitative exposure assessments were made on the basis of available measurement data and information obtained from the interviews and literature. Most of the production line workers in roofing membrane plants in Finland were exposed to asbestos until the mid-1970s. Also, some of the mixer operators in the plants were exposed to asbestos in Finland during the 1970s and in Denmark from the mid-1960s to the mid-1980s. In both countries, coal tar pitch was used in roofing membrane manufacturing until the mid-1960s, and consequently, exposure to polycyclic aromatic hydrocarbons (PAHs) in the plants was high in the 1950s and still significant in the early 1960s. Exposure of production line workers to quartz dust was high until the 1980s and is still relatively high compared with current occupational exposure limit values. Bitumen roofers' exposure to coal tar-derived PAHs may have been significant in both countries until the end of 1960s. Roofers' exposure to asbestos and quartz was estimated to have been near background level.

  2. Volatility of bitumen prices and implications for the industry

    Science.gov (United States)

    Attanasi, E.D.

    2008-01-01

    Sustained crude oil price increases have led to increased investment in and production of Canadian bitumen to supplement North American oil supplies. For new projects, the evaluation of profitability is based on a prediction of the future price path of bitumen and ultimately light/medium crude oil. This article examines the relationship between the bitumen and light crude oil prices in the context of a simple error-correction economic-adjustment model. The analysis shows bitumen prices to be significantly more volatile than light crude prices. Also, the dominant effect of an oil price shock on bitumen prices is immediate and is amplified, both in absolute terms and percentage price changes. It is argued that the bitumen industry response to such market risks will likely be a realignment toward vertical integration via new downstream construction, mergers, or on a de facto basis by the establishment of alliances. ?? 2008 International Association for Mathematical Geology.

  3. Physico-chemical modification of asphalt bitumens by reactive agents

    OpenAIRE

    Cuadri Vega, Antonio Abad

    2013-01-01

    Bitumen, a by-product from crude oil distillation, has long been used in numerous engineering applications that range from the construction of road pavements to waterproof membranes for the roofing industry. On account of its properties (impermeability, adhesiveness, elasticity, ductility, etc.), bitumen is the most suitable material to be used as a binder of mineral aggregates for paving industry, and consequently, roads are mainly constructed using a composite mixture of bitumen (~ 5 wt.%) ...

  4. Other solutions for the plastic residue from the automobile industry and used as additives in the asphaltic bitumens; Alternativas de los residuos plasticos de la automocion y su empleo como aditivos de los betunes asfalticos. Parte I

    Energy Technology Data Exchange (ETDEWEB)

    Lopez-Vidriero, E.; Castillo, F. [CEDEX. Ministerio de Fomento. Madrid (Spain)

    1999-08-01

    This article forms part of an investigation which aims to achieve two adjectives. The first is to cooperate in the improvement of the environment by decreasing the amount of plastic residue from the automobile industry. The second is to improve the characteristics of asphaltic bitumens used in roofing and waterproofing in civil engineering, through the addition of plastic residue from the automobile industry. (Author) 4 refs.

  5. Analysis of SBS Modified Bitumen Waterproofing Membrane Cracking and Quality Control%浅析屋面 SBS 改性沥青防水卷材开裂及质量控制

    Institute of Scientific and Technical Information of China (English)

    冯锦

    2013-01-01

    SBS modified bitumen waterproofing membrane cra-cking was widely used in the roof, toilet water proof. Because the product quality of their own and human operator improper proc-es, which make serious problem of leaks between the roof and th-e toilet with the bathroom. The article analysis it’s performance and the Construction points in the process, and puts forward so-me treatment methods%  SBS 改性沥青防水卷材在屋面、卫生间防水中被广泛采用,但由于产品的自身质量原因和在人为操作过程中的不当,使屋面及厕浴间渗漏等问题突出。本文通过对 SBS改性沥青防水卷材的性能、使用过程中施工的要点进行了分析,并提出了一些处理方法。

  6. The problem of the compatibility of bitumen sheets for the reconstruction and ehabilitation of roofs

    Directory of Open Access Journals (Sweden)

    Plachý Jan

    2017-01-01

    Full Text Available During the renovation of flat roofs, the waterproofing layer is often repaired locally rather than completely replaced. When making such repairs, it is very important to know whether the proposed bitumen sheets are compatible in order to prevent delamination and the release of the joints. This paper deals with the determination of the resistance of bitumen sheet joints against peeling when combined with different bitumen materials. On the basis of the described test methodology it was possible to determine whether the selected bitumen materials were compatible with bitumen sheets. As part of the experiments, modified bitumen sheets with plastomers (PO, oxidized bitumen (OX, and elastomers (SBS, were tested.

  7. Oxidation of visbreaker bitumens

    Energy Technology Data Exchange (ETDEWEB)

    Giavarini, C.; Saporito, S.

    1989-07-01

    A series of oxidation tests was carried out on a small-scale blowing unit fed with two different visbreaker (VB) bitumens, and with two straight-run (SR) soft bitumens for reference. The purpose was to study the possibility of applying the blowing process to VB feeds, and to evaluate process kinetics and product characteristics. The results showed that industrial blowing of VB bitumens is feasible and that the rate of reaction can be expressed by a first order equation with respect to change in softening point. Production of distillate oils was quite high, especially when iron trichloride was used as a catalyst; in industrial application it is suggested that VB bitumens may be oxidized without any catalyst, the kinetics of the non-catalytic process being satisfactory. Air consumption was unsteady compared with the SR operation, and plugging of the air coil was more frequent. 20 refs., 3 figs., 3 tabs.

  8. Aerogel Composites: Strong and Waterproof

    Science.gov (United States)

    White, Susan; Hsu, Ming-ta; Arnold, James O. (Technical Monitor)

    1999-01-01

    Aerogels are exotic materials having superior thermal and physical properties with great potential for both space and industrial uses. Although aerogels are excellent low-density insulators with unique acoustic and optical properties, their commercialization potential is currently limited by moisture absorption, fragility, and cost. This paper describes useful, easily scaled-up solutions to the first two of these three problems. The waterproofing and water-repellent method described here is a cheaper and simpler improvement over previous permanent methods.

  9. The problem of the compatibility of bitumen sheets for the reconstruction and ehabilitation of roofs

    OpenAIRE

    Plachý Jan

    2017-01-01

    During the renovation of flat roofs, the waterproofing layer is often repaired locally rather than completely replaced. When making such repairs, it is very important to know whether the proposed bitumen sheets are compatible in order to prevent delamination and the release of the joints. This paper deals with the determination of the resistance of bitumen sheet joints against peeling when combined with different bitumen materials. On the basis of the described test methodology it was possibl...

  10. Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation

    Science.gov (United States)

    Tumanyan, B. P.; Petrukhina, N. N.; Kayukova, G. P.; Nurgaliev, D. K.; Foss, L. E.; Romanov, G. V.

    2015-11-01

    The results of studies of alterations in the elemental and SARA compositions and physicochemical and rheological properties of highly viscous heavy crude oils upon catalytic and non-catalytic aquathermolysis are generalized. The chemistry of transformations of model hydrocarbons and heteroatomic compounds in aqueous media at high temperature, including subcritical and supercritical conditions, is considered. Comparative analysis of methods for activation of oil conversion via aquathermolysis using hydrogen donors, oil-soluble and water-soluble nanodispersed catalysts, ionic hydrogenation processes and various ways for reservoir heating is presented. Problems and prospects of oil-field implementation of catalytic aquathermolysis for upgrading heavy oils and natural bitumen are discussed. The bibliography includes 234 references.

  11. Cooee bitumen:

    DEFF Research Database (Denmark)

    Lemarchand, Claire; Schrøder, Thomas; Dyre, J. C.

    2013-01-01

    We study chemical aging in “Cooee bitumen” using molecular dynamic simulations. This model bitumen is composed of four realistic molecule types: saturated hydrocarbon, resinous oil, resin, and asphaltene. The aging reaction is modelled by the chemical reaction: “2 resins → 1 asphaltene.” Molecular...... dynamic simulations of four bitumen compositions, obtained by a repeated application of the aging reaction, are performed. The stress autocorrelation function, the fluid structure, the rotational dynamics of the plane aromatic molecules, and the diffusivity of each molecule are determined for the four...

  12. A novel method for recovery of acidic sludge of used-motor oil reprocessing industries to bitumen using bentonite and SBS

    OpenAIRE

    Ahmad Jonidi Jafari; malek hassanpour; Mitra Gholam; Mehdi Farzadkia

    2014-01-01

    ABSTRACT Acidic sludge is a by-product from used motor oil reprocessing industries, which thousand tons of this sludge are disposed into the environment as a hazardous waste material daily. The acidic sludge contains unsaturated compounds that are polar and asphaltene. The bitumen under certain conditions is produced from mixing of bentonite, polymer styrene – butadiene – styrene (SBS), and acidic sludge. Context and purpose: The objective of this study was the recovery of acidic sludge...

  13. Impact of salinity on bitumen extraction

    Energy Technology Data Exchange (ETDEWEB)

    Kaminsky, H.A.W; Schaffer, M. [Total EandP Canada Ltd (Canada); Gingras, J.P. [TOTAL Petrochemicals Mont-Lacq Research and Development (France)

    2011-07-01

    In the oil sands industry, the hot water extraction process is used to extract bitumen. Recovery of bitumen is thus dependent on the water chemistry. Previous studies identified that divalent cations such as calcium present in water have a negative effect on bitumen recovery but the effect of monovalent cations such as sodium at high concentrations is still unknown. This paper assessed the potential impact of both monovalent and divalent cations on bitumen recovery. Extraction tests were conducted with two low grade and one average grade ore and with different water chemistries. Results showed that monovalent cations can have a negative impact on bitumen recovery for specific ore types. The study was not successful in determining the responsible mechanism but it is presumed to be related to coagulation of fine clays. This paper highlighted that monovalent cations can impact the bitumen recovery; further work is required to determine the responsible factors.

  14. Simplified Waterproofing of Aerogels

    Science.gov (United States)

    Hsu, Ming-Ta S.; Chen, Timothy S.; White, Susan; Rasky, Daniel J.

    2003-01-01

    A relatively simple silanization process has been developed for waterproofing or rewaterproofing aerogels, xerogels, and aerogel/tile composites, and other, similar low-density, highly microporous materials. Such materials are potentially attractive for a variety of applications especially for thermal-insulation panels that are required to be thin and lightweight. Unfortunately, such materials are also hydrophilic and tend to collapse after adsorbing water from the air. Hence, an effective means of waterproofing is necessary to enable practical exploitation of aerogels and the like. Older processes for waterproofing aerogels are time-consuming, labor-intensive, and expensive, relative to the present process. Each of the older processes includes a number of different chemical treatment steps, and some include the use of toxic halogenated surface-modifying compounds, pressures as high as hundreds of atmospheres, and/or temperatures as high as 1,000 C.

  15. A novel method for recovery of acidic sludge of used-motor oil reprocessing industries to bitumen using bentonite and SBS

    Directory of Open Access Journals (Sweden)

    Ahmad Jonidi Jafari

    2014-04-01

    Full Text Available ABSTRACT Acidic sludge is a by-product from used motor oil reprocessing industries, which thousand tons of this sludge are disposed into the environment as a hazardous waste material daily. The acidic sludge contains unsaturated compounds that are polar and asphaltene. The bitumen under certain conditions is produced from mixing of bentonite, polymer styrene – butadiene – styrene (SBS, and acidic sludge. Context and purpose: The objective of this study was the recovery of acidic sludge to bitumen using additives such as bentonite and SBS. Also, the effect of additives with different weight percentages (wt%(on the performance parameters of bitumen was evaluated. At first, spilled oil was separated from the acidic sludge by a centrifugal concentrator. Then, concentrated acidic sludge and additives were mixed in together. Finally, the performance tests were carried out to compare the quality of acidic sludge with the obtained products.The results indicated that performance parameters such as softening point (SP, weight loss, penetration degree, PI, Frass breaking point, and temperature susceptibility (TS were promoted from 37°C, 1.3%, 230 dmm, -0.07854, -5°C and 0.0451 to 54°C, 1%, 130 dmm, 2.7094, -11°C , 0.02721, respectively. According to the paired sample t-test analysis, a significant difference was found between the bentonite dosage and the improved performance parameters from concentrated acidic sludge and obtained products (pvalue ≤.001. The bentonite and SBS with 2 and 4 wt%, respectively were determined as the suitable additives in the recovery of acidic sludge to bitumen.

  16. Development of Techniques for Separating Waterproof Layer from XLPE Cable Sheath by Hot Water Heating

    Science.gov (United States)

    Okazaki, Masato; Nakade, Masahiko; Okashita, Minoru; Tanimoto, Mihoko

    Waterproof layer is used to prevent penetration of water which is one of the factors of dielectric breakdown in XLPE cables more than 66kV class. A XLPE cable sheath with waterproof layer is done landfill disposal as industrial waste because separation of waterproof layer is difficult for technology and cost. However, around 20 years passes after waterproof layer was introduced, and social consciousness for environment changes during these 20 years, and responsibility of company for environment of a society grows bigger. We report the result that examined techniques for separating waterproof layer.

  17. Effect of styrene-butadiene-styrene content on the adhesion properties of bitumen before and after heat aging

    Energy Technology Data Exchange (ETDEWEB)

    Zielinski, K. [Poznan Univ. of Technology, Poznan (Poland). Inst. of Structural Engineering

    2008-05-15

    Styrene-butadiene-styrene (SBS) is a common modifying polymer used in bitumen-based waterproofing building materials. SBS is used to improve the heat aging resistance of bitumen as well as to increase its resistance to temperature changes. This paper compared SBS-modified bitumen products with nonmodified bitumen products. The aim of the study was to assess the effect of heat aging and SBS content on the adhesion properties of 2 bitumen types to concrete and steel substrates. Two types of bitumen were tested: (1) paving-grade bitumen; and (2) an oxidized bitumen with a softening point at 25 degrees C. The thin film oven test was used to heat age the samples. Adhesion properties were measured before and after heat aging. The tests demonstrated that the adhesion strength of bituminous mastics to concrete and steel substrates decreased as SBS content increased. Bitumen products modified with 9 to 12 per cent of SBS showed a weaker bond with concrete and steel substrates than nonmodified equivalents. It was concluded that after heat aging, the adhesion strength of the nonmodified bitumen was higher than that of the bitumen modified with SBS. 7 refs., 4 tabs., 5 figs.

  18. Frost resistance of concrete surfaces coated with waterproofing materials

    Science.gov (United States)

    Klovas, A.; Dauksys, M.; Ciuprovaite, G.

    2015-03-01

    Present research lays emphasis on the problem of concrete surface exposed to aggressive surrounding quality. The test was conducted with concrete surfaces coated with different waterproofing materials exposed in solution of 3 % of sodium sulphate. Research was performed according to LST EN 1338:2003 standard requirements. Technological properties of concrete mixture as well as physical-mechanical properties of formed concrete specimens were established. The resistance of concrete to freezing - thawing cycles was prognosticated according to the porosity parameters established by the kinetic of water absorption. Five different waterproofing materials (coatings) such as liquid bitumen-rubber based, elastic fiber-strengthened, silane-siloxane based emulsion, mineral binder based and liquid rubber (caoutchouc) based coatings were used. Losses by mass of coating materials and specimens surface fractures were calculated based on the results of frost resistance test. Open code program "ImageJ" was used for visual analysis of concrete specimens. Based on the results, aggressive surrounding did not influence specimens coated with elastic, fibre-strengthened, mineral materials. On the other hand, specimens coated with liquid rubber (caoutchouc) based material were greatly influenced by aggressive surrounding. The biggest losses of specimen surface concrete (fractures) were obtained with silane-siloxane based emulsion coating. Generally, specimens coated with waterproofing materials were less influenced by aggressive surrounding compared with those without.

  19. Interaction forces in bitumen extraction from oil sands.

    Science.gov (United States)

    Liu, Jianjun; Xu, Zhenghe; Masliyah, Jacob

    2005-07-15

    Water-based extraction process (WBEP) has been successfully applied to bitumen recovery from Athabasca oil sand ore deposits in Alberta. In this process, two essential steps are involved. The bitumen first needs to be "liberated" from sand grains, followed by "aeration" with air bubbles. Bitumen "liberation" from the sand grains is controlled by the interaction between the bitumen and sand grains. Bitumen "aeration" is dependent, among other mechanical and hydrodynamic variables, on the hydrophobicity of the bitumen surface, which is controlled by water chemistry and interactions between bitumen and fine solids. In this paper, the interaction force measured with an atomic force microscope (AFM) between bitumen-bitumen, bitumen-silica, bitumen-clays and bitumen-fines is summarized. The measured interaction force barrier coupled with the contacted adhesion force allows us to predict the coagulative state of colloidal systems. Zeta potential distribution measurements, in terms of heterocoagulation, confirmed the prediction of the measured force profiles using AFM. The results show that solution pH and calcium addition can significantly affect the colloidal interactions of various components in oil sand extraction systems. The strong attachment of fines from a poor processing ore on bitumen is responsible for the corresponding low bitumen flotation recovery. The identification of the dominant non-contact forces by fitting with the classical DLVO or extended DLVO theory provides guidance for controlling the interaction behavior of the oil sand components through monitoring the factors that could affect the non-contact forces. The findings provide insights into megascale industrial operations of oil sand extraction.

  20. Waterproofing Materials for Ammonium Nitrate

    Directory of Open Access Journals (Sweden)

    R.S. Damse

    2004-10-01

    Full Text Available This study explores the possibility of overcoming the problem of hygroscopicity of ammonium nitrate by coating the particles with selected waterproofing materials. Gravimetric analysis ofthe samples of ammonium nitrate coated with eight different waterproofing materials, vis-a-vis, uncoated ammonium nitrate, were conducted at different relative humidity and exposuretime. The results indicate that mineral jelly is the promising waterproofing material for ammonium nitrate among the materials tested, viz, calcium stearate, dioctyl phthalate, kaoline, diethylphthalate, dinitrotoluene, shelac varnish, and beeswax. Attempts were made to confirm the waterproofing ability of mineral jelly to ammonium nitrate using differential thermal analysisand x-ray diffraction patterns as an experimental tool. Suitability of mineral jelly as an additive for the gun propellant was also assessed on the basis of theoretical calculations using THERMprogram.

  1. Industrialization of the Protective Layer for Waterproof Roof%屋面防水保护层轻质、工业化生产

    Institute of Scientific and Technical Information of China (English)

    李继文

    2014-01-01

    Most of the protective layer chosen for the waterproof layer is the fine stone concrete protection layer in wet oper -ation.To reduce the deformation caused by the temperature difference of the structural disadvantages , used in the process of repair and trouble , the construction speed is slow , the seasonal construction conditions , but also bring hidden trouble of quality and not the economy .In the development of science and technology today , along with the construction technology and the progress of the material science , if taken in light , high-strength material roof panel , can achieve the purpose of pro-tecting the waterproof layer , but also can solve the repair , hidden quality problems caused wet construction .Discuss the ad-vantages and disadvantages of this paper is through the use of light plate , thus roof waterproof protection layer of light , the plate to be popularized .%在现在在建工程中,大多数防水保护层主要还是采取湿作业的细石砼保护层。对降低屋面温度、降低温差引起的结构变形不利,使用过程中的维修带来很大麻烦,施工速度慢,在季节性施工条件下,还会带来质量隐患而且不经济。在科学技术大发展的今天,随着施工技术和材料科学的进步,如果采取轻质、高强成品材料屋面板,既可以达到保护防水层的目的,又可以解决湿作业施工带来的维修、质量隐患方面的问题。本文就是通过轻质板使用的利与弊的讨论,从而使屋面防水保护层轻质、板块化得以推广。

  2. The Positive Ion Emulsified Bitumen Applies in the Road Maintenance%阳离子乳化沥青应用于道路养护

    Institute of Scientific and Technical Information of China (English)

    范林眼; 王慧

    2009-01-01

    文章论述了乳化沥青的概念,详细叙述了乳化沥青在道路透层、黏层、路面防水层、稀浆封层和桥面防水层等部位中的应用情况.%This article elaborated the emulsified bitumen concept.Narrated spot in detail and so on in emulsified bitumen application situations, Seeps in the path, mounted the level, the road surface waterproof layer, spot and so on in thin paste sealing course and bridge floor waterproof layer.

  3. Characteristics of the mechanically fastened joints of one-layer bitumen sheets

    Directory of Open Access Journals (Sweden)

    Petříček Tomá¡

    2017-01-01

    Full Text Available The system of mechanic fastening is one of the most frequently used variants of roof membrane stabilization against the impacts of wind sucking. With the growing number of applications of mechanically fastened roofs the number of defects is also growing. We particularly see them in the joints of waterproofing membranes. The contribution is thus dedicated to examination of mutual dependence between the type of the carrier and the strength characteristics of mechanically fastened joints of these sheets. Bitumen sheets with different types of carrier used for onelayer mechanically fastened waterproofing membranes of flat roofs were chosen as samples. The above mentioned dependence is frequently stated in the practice, but is not explicitly documented. The aim of the contribution is to confirm or refute a hypothesis that a relation between the bitumen sheet carrier type and the strength of their joints exists. The results were arranged on the base of statistic evaluation of data obtained by laboratory measurement.

  4. The analysis of implementation options of transverse joints of bitumen sheets

    Directory of Open Access Journals (Sweden)

    Plachý Jan

    2017-01-01

    Full Text Available One of the most frequent sources of faults on flat roofs is a violation of the waterproof layers along the transverse joints between bitumen sheets. This fault is caused by a failure to adhere to the technological methodologies. This paper presents current solutions, as well as a new solution, for creating such joints. The new solutions are experimentally compared with existing solutions.

  5. COOEE bitumen: chemical aging

    CERN Document Server

    Lemarchand, Claire A; Dyre, Jeppe C; Hansen, Jesper S

    2013-01-01

    We study chemical aging in "COOEE bitumen" using molecular dynamic simulations. The model bitumen is composed of four realistic molecule types: saturated hydrocarbon, resinous oil, resin, and asphaltene. The aging reaction is modelled by the chemical reaction: "2 resins $\\rightarrow$ 1 asphaltene". Molecular dynamic simulations of four bitumen compositions, obtained by a repeated application of the aging reaction, are performed. The stress autocorrelation function, the fluid structure, the rotational dynamics of the plane aromatic molecules, and the diffusivity of each molecule, are determined for the four different compositions. The aging reaction causes a significant dynamics slowdown, which is correlated to the aggregation of asphaltene molecules in larger and dynamically slower nanoaggregates. Finally, a detailed description of the role of each molecule types in the aggregation and aging processes is given.

  6. Surface microstructure of bitumen characterized by atomic force microscopy.

    Science.gov (United States)

    Yu, Xiaokong; Burnham, Nancy A; Tao, Mingjiang

    2015-04-01

    Bitumen, also called asphalt binder, plays important roles in many industrial applications. It is used as the primary binding agent in asphalt concrete, as a key component in damping systems such as rubber, and as an indispensable additive in paint and ink. Consisting of a large number of hydrocarbons of different sizes and polarities, together with heteroatoms and traces of metals, bitumen displays rich surface microstructures that affect its rheological properties. This paper reviews the current understanding of bitumen's surface microstructures characterized by Atomic Force Microscopy (AFM). Microstructures of bitumen develop to different forms depending on crude oil source, thermal history, and sample preparation method. While some bitumens display surface microstructures with fine domains, flake-like domains, and dendrite structuring, 'bee-structures' with wavy patterns several micrometers in diameter and tens of nanometers in height are commonly seen in other binders. Controversy exists regarding the chemical origin of the 'bee-structures', which has been related to the asphaltene fraction, the metal content, or the crystallizing waxes in bitumen. The rich chemistry of bitumen can result in complicated intermolecular associations such as coprecipitation of wax and metalloporphyrins in asphaltenes. Therefore, it is the molecular interactions among the different chemical components in bitumen, rather than a single chemical fraction, that are responsible for the evolution of bitumen's diverse microstructures, including the 'bee-structures'. Mechanisms such as curvature elasticity and surface wrinkling that explain the rippled structures observed in polymer crystals might be responsible for the formation of 'bee-structures' in bitumen. Despite the progress made on morphological characterization of bitumen using AFM, the fundamental question whether the microstructures observed on bitumen surfaces represent its bulk structure remains to be addressed. In addition

  7. TECHNOLOGY AND EFFICIENT USE OF PEAT ASH IN MASTICS FOR WATERPROOFING OF BRIDGE AND TUNNEL STRUCTURES

    Directory of Open Access Journals (Sweden)

    G. D. Lyahevich

    2015-01-01

    Full Text Available A prospective method for protection of  bridges and tunnels against aggressive water action is surface waterproofing on the basis of an organo-mineral binder. Its structural strength can be increased by introduction of particles which are similar to the size of  asphaltenes and an elasticity of disperse medium has been increased due to introduction of polymers. These theoretical suppositions point out the possibility for simultaneous provision of flexibility at low temperatures and high heat resistance for mastics on the basis  of organo-mineral binders. In this regard a goal has been set to obtain a mastic high flexibility and high heat resistance  while using finely divided activated peat ash.Rubber crushed in accordance with ТУ (Technical Specifications 38.108035–87,  divinyl-styrene thermoelastoplast DСT-30Р-20ПС,  bitumen of grade 20/30 in accordance with СТБ ЕН 12591–2010, ash from burning peat at the Lida Peat Briquette Plant, multi-purpose industrial oil of solvent refining with high viscosity index, super-plasticizer – sodium salt which is a condensation product of aromatic carbon sulfo-oxidation with formaldehyde and neutralization with the help of sodium hydroxide (type 1 have been used in order to obtain the stated objective. While using these materials compositions and technology for preparation of organo-mineral mastics have been developed in the paper. Their tests have shown that a modification of finely divided  mastics carried out with the help of peat ash which is activated by super-plasticizer НСПКСАУсФ-1, various polymer additives, contributes to an increase in their heat resistance, elasticity, water resistance, and also allows to control their technological and operational characteristics. The paper has experimentally confirmed that peat ash can be successfully used for preparation of high-quality waterproofing mastics which are so necessary for  protection of bridge and tunnel

  8. Tunnel Waterproofing with Membranes Waterproofing at Senoko Cabele Tunnel in comparison with International Standards

    Institute of Scientific and Technical Information of China (English)

    Stefan Hotz

    2004-01-01

    Waterproofing of tunnels is and has always been a challenge, worldwide: Changing Geology with hardly predictable water inflow, limited space underground and only very little intervention opportunities once the tunnel is completed. This paper elaborates such challenges and focuses on the waterproofing solutions of mined tunnels with membranes. Different standards and approaches for the waterproofing system. In Singapore, a membrane waterproofing system is used for the shafts and adits at Senoko Cable Tunnel. The paper project specific waterproofing challenges and emphasizes on solution for them.

  9. 香港东海工业大厦SBS沥青旧屋面防水翻修%Repair of the Old SBS Bitumen Membrane Roof Waterproof of Hongkong Oriental Industrial Building

    Institute of Scientific and Technical Information of China (English)

    余建平; 刘志聪

    2014-01-01

    香港东海工业大厦钢混SBS沥青卷材新旧屋面年久渗漏,经清理后采用暴露型单组分聚脲液体涂层材料并植入胎基布作为主要弹性防水层,不仅可作为屋面加强层,还可防止裂缝的产生,预期新屋面的防水效果能达到香港建筑寿命质保期的要求.

  10. A regenerable bitumen composition

    Energy Technology Data Exchange (ETDEWEB)

    Sudzuki, K.; Asakava, Y.; Matsui, A.; Ogava, A.

    1982-10-18

    The regenerable bitumin composition includes the bitumen material (asphalt, oxidized bitumen, petroleum or asphalt pitch) emulsified by an cation emulsifier (alkylamine or an imidazole derivative) and additionally by a noniononic emulsifier (polyoxyethylenamine), an amide, which contains greater than 1 amide groups per molecule (amide derivative, imidazoline), an epoxide compound with greater than 1 epoxide group per molecule (preferably with an epoxy equivalent of 180 to 500), an inorganic compound which hardens in water (Portland cement or silicate cement) and additionally, water. The total content of the second third components is 1 to 200 parts per million to 100 parts of the first component, while the content of the fourth component is from 1 to 400 parts. The water content in the composition is 5 to 1,000 percent of the total content of the first three components. The patented composition is characterized by high stability, strength, chemical stability, resistance to water and good adhesion properties.

  11. Pressurized waterproof case electronic device

    KAUST Repository

    Berumen, Michael L.

    2013-01-31

    A pressurized waterproof case for an electronic device is particularly adapted for fluid-tight containment and operation of a touch-screen electronic device or the like therein at some appreciable water depth. In one example, the case may be formed as an enclosure having an open top panel or face covered by a flexible, transparent membrane or the like for the operation of the touchscreen device within the case. A pressurizing system is provided for the case to pressurize the case and the electronic device therein to slightly greater than ambient in order to prevent the external water pressure from bearing against the transparent membrane and pressing it against the touch screen, thereby precluding operation of the touch screen device within the case. The pressurizing system may include a small gas cartridge or may be provided from an external source.

  12. Fractal harmonic law and waterproof/dustproof

    Directory of Open Access Journals (Sweden)

    Kong Hai-Yan

    2014-01-01

    Full Text Available The fractal harmonic law admits that the friction between the pure water and the moving surface is the minimum when fractal dimensions of water in Angstrom scale are equal to fractal dimensions of the moving surface in micro scale. In the paper, the fractal harmonic law is applied to demonstrate the mechanism of waterproof/ dustproof. The waterproof phenomenon of goose feathers and lotus leaves is illustrated to verify our results and experimental results agree well with our theoretical analysis.

  13. Some peculiarities of bitumen emulsion modification

    Directory of Open Access Journals (Sweden)

    A. Batyrbayev

    2013-09-01

    Full Text Available Polymer modification of bitumen emulsions obtained from bitumen of domestic production with the use of several commercial emulsifiers was studied. The influence of the polymer modifier concentration on bitumen emulsion physical-mechanical properties was considered. Possibility of obtaining of modified bitumen emulsion with high impact resistance was shown.

  14. Analysis of failures of waterproofing cladding layers of terracotta tiles

    Directory of Open Access Journals (Sweden)

    Koláčný Milan

    2017-01-01

    Full Text Available The article is focused on one of the most important roof cladding layers – the waterproofing cladding layer of terracotta tiles. Its detailed analysis covers the main waterproofing cladding layers in terms of their material characteristics and installation methods. The article concludes by formulating principles for the correct design of the main waterproofing layer/construction.

  15. Effect of Temperature and Process on Quantity and Composition of Laboratory-generated Bitumen Emissions.

    Science.gov (United States)

    Bolliet, Christophe; Kriech, Anthony J; Juery, Catherine; Vaissiere, Mathieu; Brinton, Michael A; Osborn, Linda V

    2015-01-01

    In this study we investigated the impact of temperature on emissions as related to various bitumen applications and processes used in commercial products. Bitumen emissions are very complex and can be influenced in quantity and composition by differences in crude source, refining processes, application temperature, and work practices. This study provided a controlled laboratory environment to study five bitumen test materials from three European refineries; three paving grade, one used for primarily roofing and some paving applications, and one oxidized industrial specialty bitumen. Emissions were generated at temperatures between 140°C and 230°C based on typical application temperatures of each product. Emissions were characterized by aerodynamic particle size, total organic matter (TOM), simulated distillation, 40 individual PACs, and fluorescence (FL-PACs) spectroscopy. Results showed that composition of bitumen emissions is influenced by temperature under studied experimental conditions. A distinction between the oxidized bitumen with flux oil (industrial specialty bitumen) and the remaining bitumens was observed. Under typical temperatures used for paving (150°C-170°C), the TOM and PAC concentrations in the emissions were low. However, bitumen with flux oil produced significantly higher emissions at 230°C, laden with high levels of PACs. Flux oil in this bitumen mixture enhanced release of higher boiling-ranged compounds during application conditions. At 200°C and below, concentrations of 4-6 ring PACs were ≤6.51 μg/m(3) for all test materials, even when flux oil was used. Trends learned about emission temperature-process relationships from this study can be used to guide industry decisions to reduce worker exposure during processing and application of hot bitumen.

  16. Preparation of low-cost waterproofing materials

    Institute of Scientific and Technical Information of China (English)

    Al-Hadidy AI; TAN Yi-qiu; DONG Ze-jiao; WANG Jia-ni

    2008-01-01

    To address the need for producing a cheap, single-component, hot-applied compound joint sealant with high quality for sealing joints and cracks in concrete and flexible pavements without using primer for instal-lation, a hot-applied modified asphalt sealant was produced by blending up about 30% starch into 20% citric acid. The starch and the asphalt cement were mixed at a temperature of above 160 ℃. Thus the waterproofing asphalt was manufactured to protect the surface of various shapes and types from water leakage using the citric acid. Results indicate that this sealant complies with the requirements of ASTM D-1191, D-6690-O6a and D-7116-05. The citric acid is a kind of reliable materials for asphalt cement, which can be widely used in paving and waterproofing construction materials, and this offers profound engineering and economic advantages.

  17. Pressurized waterproof case for electronic device

    KAUST Repository

    Berumen, Michael L.

    2013-01-31

    The pressurized waterproof case for an electronic device is particularly adapted for the waterproof containment and operation of a touch-screen computer or the like therein at some appreciable water depth. The case may be formed as an enclosure having an open top panel or face covered by a flexible, transparent membrane or the like for the operation of the touch-screen device within the case. A pressurizing system is provided for the case to pressurize the case and the electronic device therein to slightly greater than ambient in order to prevent the external water pressure from bearing against the transparent membrane and pressing it against the touch screen, thereby precluding operation of the touch screen device within the case. The pressurizing system may be a small gas cartridge (e.g., CO2), or may be provided from an external source, such as the diver\\'s breathing air. A pressure relief valve is also provided.

  18. Characterizing worker exposure to bitumen during hot mix paving and asphalt mixing operations.

    Science.gov (United States)

    Burstyn, Igor; Ferrari, Pietro; Wegh, Hillion; Heederik, Dick; Kromhout, Hans

    2002-01-01

    A survey of bitumen exposure was carried out during hot mix paving and asphalt mixing. Four methods of characterizing and quantifying bitumen fume in inhalable particles were used: gravimetric, infrared spectroscopy, gas chromatography, and total absorbance (of the particle filter surface). Dermal deposition of bitumen was assessed by determination of cyclohexanesoluble matter in the material collected by paper or cotton pads worn on the inside of a person's wrists. The researchers studied the correlation patterns between results of these methods using pairwise correlation coefficients and principal component analysis (for air concentrations only). For hot mix paving, within- and between-worker variance components were evaluated, adjusting for area paved. Collected fume was dark in color and mainly consisted of aliphatic hydrocarbons of less than 20 carbon atoms. Inconsistent correlation patterns between dermal deposition and air levels were observed. Quantification of organic matter using either infrared spectroscopy or gas chromatography appeared to be good methods for monitoring inhalable bitumen fume. Cotton pads seem to be more promising than paper pads for measuring dermal exposure during paving. Paving workers were uniformly exposed to bitumen fume. Assessment of the uniformity of dermal exposure depended on the type of pad used. Day-to-day variability and intensity of inhalable and dermal bitumen exposures depended on area paved. The small size of the study limits the potential application of the results to the asphalt industry in general. More research is needed to develop a valid and inexpensive method of assessing total bitumen exposure.

  19. The extraction of bitumen from western tar sands

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1990-07-01

    Topics discussed include: characterization of bitumen impregnated sandstone, water based tar sand separation technology, electrophoretic characterization of bitumen and fine mineral particles, bitumen and tar sand slurry viscosity, the hot water digestion-flotation process, electric field use on breaking water-in-oil emulsions, upgrading of bitumens and bitumen-derived liquids, solvent extraction.

  20. The extraction of bitumen from western tar sands. Annual report

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1990-07-01

    Topics discussed include: characterization of bitumen impregnated sandstone, water based tar sand separation technology, electrophoretic characterization of bitumen and fine mineral particles, bitumen and tar sand slurry viscosity, the hot water digestion-flotation process, electric field use on breaking water-in-oil emulsions, upgrading of bitumens and bitumen-derived liquids, solvent extraction.

  1. The Human Bitumen Study: executive summary.

    Science.gov (United States)

    Raulf-Heimsoth, Monika; Pesch, Beate; Rühl, Reinhold; Brüning, Thomas

    2011-06-01

    Bitumen has attracted attention from the scientific community and regulating agencies. The debate on health effects of exposure to vapours and aerosols of bitumen during the hot application of bitumen ranges from respiratory and neurological effects to carcinogenicity. In 2000, the German Hazardous Substances Committee (AGS), in collaboration with the German Bitumen Forum, initiated the examination of a group of mastic asphalt workers and a same number of construction workers without exposure bitumen using a cross-shift design. The study was then extended to the Human Bitumen Study, and the recruitment was finished in 2008 after examination of 500 workers on 80 construction sites. Three hundred and twenty workers exposed to vapours and aerosols of bitumen at high processing temperatures and 118 workers at outdoor construction sites were included. In the Human Bitumen Study external exposure to vapours and aerosols of bitumen, internal exposure to PAH by analysing urinary 1-hydroxypyrene, the sum of hydroxyphenanthrenes and the sum of 1- and 2-hydroxynaphthalenes, irritative effects in the upper and lower airways and genotoxic effects in blood cells were investigated. The study turned out to be one of the largest investigations of workers exposed to vapours and aerosols of bitumen under current exposure conditions. The present paper summarizes its background and main topics.

  2. Column flotation of bitumen at Fort Hills

    Energy Technology Data Exchange (ETDEWEB)

    Lizama, H.M. [Teck Cominco, Vancouver, BC (Canada); Romero, D. [UTS Energy Corp., Calgary, AB (Canada); Armour, M. [Petro-Canada, Calgary, AB (Canada)

    2008-05-15

    Flotation columns are used by mineral processors to separate mineral species. The separation is based on the premise that different mineral particles have different surface hydrophobicities. There are 2 carrier phases, notably air bubbles moving up and aqueous pulp moving down. Hydrophobic particles predominantly adhere to rising air bubbles and form a froth, while hydrophilic particles remain in aqueous suspension and flow down and out the bottom of the column. This paper described a demonstration plant near Fort McMurray where bitumen extraction was tested. The plant included 2 columns for bitumen flotation. Oil sands material was passed through a roll sizer and fed to a countercurrent drum separator, where it was mixed with water at 75 degrees C. Column data from the demonstration plant provided the opportunity to examine the separation behaviour during flotation of bitumen. The bitumen grade was described only in terms of bitumen content and solids content in order to simplify the interpretation of the bitumen flotation data. Bitumen/solids separation in the first column was successful at 50 to 60 degrees C, with feeds having bitumen grades between 1 and 19 per cent, and where the solids had about 60 per cent fines. Bitumen/solids separation did not occur in the second column at 50 to 60 degrees C, with feeds having bitumen grades between 8 and 63 per cent, and where the solids had about 90 per cent fines. The lack of separation was probably due to high solids entrainment in the flotation froth. It was concluded that bitumen column flotation data can be analyzed and interpreted by adopting mineral processing principles. Bitumen/solids separation can be evaluated and predicted by plotting solids recovery as a function of bitumen recovery. 7 refs., 1 tab., 6 figs.

  3. Phenomena occurring at the bitumen /Water and the bitumen/Mineral substrate interfaces

    OpenAIRE

    2012-01-01

    For decades, project contracting officials have been using bitumen-in-water emulsions in the manufacture of cold mixes for wearing and base courses or surface rehabilitations. These emulsions are a complex system in which bitumen and water are solubilised by an emulsifier. Regardless the applications of bitumen emulsions, four main properties are always controlled: viscosity, bitumen/mineral surface adhesion, storage stability and rupture at the mineral surface. The two latter are related to ...

  4. Application of polymers to modify bitumen obtained from waxy oils

    OpenAIRE

    Гринишин, Олег Богданович; Фридер, Ірина Вікторівна

    2013-01-01

    The article describes one of the ways of solution of the actual problem of obtaining quality bituminous materials from residues of paraffin oil recycling. The authors examined the modification of bitumen with polymers, in particular with petroleum resins, polyethylene, and industrial modifiers Elvaloy 4170 and Butonal NS 198. The study was carried out in two ways. We have studied the basic regularities of the joint oxidation of paraffin tar and oil polymerous resins. It was found that the pre...

  5. Decreasing polycyclic aromatic hydrocarbons emission from bitumen using alternative bitumen production process.

    Science.gov (United States)

    Rasoulzadeh, Y; Mortazavi, S B; Yousefi, A A; Khavanin, A

    2011-01-30

    In 1988, the National Institute for Occupational Safety and Health (NIOSH) recommended that bitumen fumes should also be considered a potential occupational carcinogen and management practices such as engineering controls should be implemented. Changing the production process of bitumen, as a source control method, was investigated in our study. For the first time, a novel alternative process was used to produce paving grade bitumen with decreased PAH emissions as well as improved bitumen performance grade (PG). Post-consumer latex and natural bitumen (NB) were used as additives to obtain 60/70 modified bitumen directly from the vacuum bottom (VB) without any need for air-blowing. The emissions were produced by a laboratory fume generation rig and were sampled and analyzed by GC-Mass and GC-FID as described in NIOSH method 5515. The PG of the resulting modified 60/70 bitumen in this study covers a wider range of climatic conditions and has higher total resistance against deformation than conventional 60/70 bitumen. The total PAH emissions from modified 60/70 bitumen (100.2619 ng/g) were decreased approximately to 50% of PAHs emitted from conventional 60/70 bitumen (197.696 ng/g). Therefore, it is possible to obtain modified bitumen with lower PAH emissions and better quality than conventional bitumen via additives and without air-blowing.

  6. ECONOMIC SIGNIFICANCE OF DESIGN, DEVELOPMENT, AND EXTRACTION OF BITUMEN FROM BITUMINOUS SAND AND HEAVY OIL IN NIGERIA

    Directory of Open Access Journals (Sweden)

    Nwizug-bee L. K.

    2016-09-01

    Full Text Available Nigeria has the largest oil sands and bitumen resources in Africa and is one of the main leading countries in the world from the point of view of its significant potential heavy oil deposits. Research of geological and physicochemical properties confirmed that the Nigerian bitumen is an important energy source and an alternative source of hydrocarbon feedstock for the petrochemical industry. Nigeria imports black oil for the petrochemical industry and its heavy oil can act in place of this black oil. In addition, researchers have successfully established the possibility of producing electrical energy from this heavy oil. Tar sands and bitumen are able to help improve the economy of Nigeria

  7. 49 CFR 192.189 - Vaults: Drainage and waterproofing.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Vaults: Drainage and waterproofing. 192.189 Section 192.189 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND... Components § 192.189 Vaults: Drainage and waterproofing. (a) Each vault must be designed so as to...

  8. Waterproof camera case for intraoperative photographs.

    Science.gov (United States)

    Raigosa, Mauricio; Benito-Ruiz, Jesús; Fontdevila, Joan; Ballesteros, José R

    2008-03-01

    Accurate photographic documentation has become essential in reconstructive and cosmetic surgery for both clinical and scientific purposes. Intraoperative photographs are important not only for record purposes, but also for teaching, publications, and presentations. Communication using images proves to be the superior way to persuade audiences. This article presents a simple and easy method for taking intraoperative photographs that uses a presterilized waterproof camera case. This method allows the user to take very good quality pictures with the photographic angle matching the surgeon's view, minimal interruption of the operative procedure, and minimal risk of contaminating the operative field.

  9. ECONOMIC SIGNIFICANCE OF DESIGN, DEVELOPMENT, AND EXTRACTION OF BITUMEN FROM BITUMINOUS SAND AND HEAVY OIL IN NIGERIA

    OpenAIRE

    Nwizug-bee L. K.

    2016-01-01

    Nigeria has the largest oil sands and bitumen resources in Africa and is one of the main leading countries in the world from the point of view of its significant potential heavy oil deposits. Research of geological and physicochemical properties confirmed that the Nigerian bitumen is an important energy source and an alternative source of hydrocarbon feedstock for the petrochemical industry. Nigeria imports black oil for the petrochemical industry and its heavy oil can act in place of this bl...

  10. 波形沥青防水板在某住宅工程中的应用%Application of Corrugated Bitumen Sheets on a Residential Building

    Institute of Scientific and Technical Information of China (English)

    肖磊; 原世伟; 何巍; 周励强

    2012-01-01

    波形沥青防水板作为下覆层在坡瓦屋面中应用,除具防水功能外,同时还能通风、除湿、隔热.结合波形沥青防水板在某住宅项目中的实际应用,总结了其在施工过程中的工艺做法,以及施工中的重点和难点.结果表明,波形沥青防水板能确保防水质量,缩短工期,并降低造价.%Corrugated bitumen sheets can be used on sloped roofs as covering layer under roof tiles. Apart from being waterproofing, they also provide functions such as roof ventilation, dehumidification and insulation to the roof. Combined with the application of corrugated bitumen sheets on a residential building, the construction technologies and key points in construction process are summarized. The application results show that the corrugated bitumen sheets can ensure the waterproof quality, reduce the construction cost and shorten the construction time.

  11. Colloidal interactions between Langmuir-Blodgett bitumen films and fine solid particles.

    Science.gov (United States)

    Long, Jun; Zhang, Liyan; Xu, Zhenghe; Masliyah, Jacob H

    2006-10-10

    In oil sand processing, accumulation of surface-active compounds at various interfaces imposes a significant impact on bitumen recovery and bitumen froth cleaning (i.e., froth treatment) by altering the interfacial properties and colloidal interactions among various oil sand components. In the present study, bitumen films were prepared at toluene/water interfaces using a Langmuir-Blodgett (LB) upstroke deposition technique. The surface of the prepared LB bitumen films was found to be hydrophobic, comprised of wormlike aggregates containing a relatively high content of oxygen, sulfur, and nitrogen, indicating an accumulation of surface-active compounds in the films. Using an atomic force microscope, colloidal interactions between the LB bitumen films and fine solids (model silica particles and clay particles chosen directly from an oil sand tailing stream) were measured in industrial plant process water and compared with those measured in simple electrolyte solutions of controlled pH and divalent cation concentrations. The results show a stronger long-range repulsive force and weaker adhesion force in solutions of higher pH and lower divalent cation concentration. In plant process water, a moderate long-range repulsive force and weak adhesion were measured despite its high electrolyte content. These findings provide more insight into the mechanisms of bitumen extraction and froth treatment.

  12. Experimental research on bitumen preheating (fluidization) by using solar energy in passive mode

    Energy Technology Data Exchange (ETDEWEB)

    Luminosu, Ioan [Department of Physics, ' Politehnica' University Timisoara, 1, Regina Maria Plaza, RO 300004, Timisoara (Romania); Fara, Laurentiu [Department of Physics, ' ' Politehnica' ' University Bucharest, 313, Splaiul Independentei Blvd, RO 060032, Bucuresti (Romania)

    2009-01-15

    An important aim of worldwide research engineering is to identify new industries to introduce solar energy installations for average thermal level. Due to the mechanical and thermal properties of bitumen, such as the 44-49 C softening point of D80/100 type bitumen, this material can be preheated by using solar thermal installations. The Physics Department of 'Politehnica' University of Timisoara designed and studied a laboratory installation for preheating in environmental conditions an amount of 25.1 kg of bitumen up to 55 C per day. The paper developed a previous original research regarding bitumen preheating by using solar energy. The experimental installation was improved and experimental data were statistically processed. The main improvements were based on:-increasing the amount of incident solar radiation by: (a) reducing the height of the brick walls and replacing them with transparent glass plates; (b) painting the inner faces of the brick walls in white; -cutting down thermal losses by: (a) achievement of the double greenhouse effect in the transparent areas of the installation; (b) change of the brick walls into passive walls. The performances of the installation were improved as follows:-increasing time of the bitumen temperature increased from 7 hours to 8 hours, in the interval 8 am-4 pm; -bitumen maximum temperature increased from 55 to 63.3 C; -average temperature in bitumen increased from 41.4 to 46.4 C; -maximum efficiency increased from 12 to 14.4%; -daily average efficiency increased from 6.3 to 7.3%; -maximum difference between the bitumen temperature and environmental one increased from 24 to 32 C. (author)

  13. Mechanism of Solid Bitumen in Silurian Sandstones of Tarim Basin

    Institute of Scientific and Technical Information of China (English)

    Zhang Jinglian; Zhu Bingquan

    1997-01-01

    @@ There are a large amount of solid bitumen within Silurian sandstones in Tabei, Tazhong, Kalpin uprifts of the Tarim Basin. Petroleum geochemists are interested in the super giant fossil oil pool. Unfortunately,some key questions have not been solved, such as: what generated the bitumen? When did the bitumen generate and when did the bitumen accumulated in the sandstones?

  14. Pathological changes waterproof membranes and their identification

    Directory of Open Access Journals (Sweden)

    Novotný Marek

    2017-01-01

    Full Text Available With the development of waterproofing systems based on synthetic membranes, especially mPVC, there is an increase in pathological changes of these membranes. Competing manufacturers and pressure on price of the final product have resulted in usage of unstable or low quality raw materials. After production, these materials keep their specific characteristics, however, their aging is accelerated, i.e. they lose their essential qualitative characteristics very quickly. Very important is the detection of these processes which is possible using chemical analysis (gas chromatography, IR analysis and others as well as using visual inspection of surface by microscope, including 3D modeling. Very important are weldability tests which identify glass transition temperature of the material. The results can then be used as a basis for correct identification of problems with weldability, nonweldability of synthetic membranes, respectively, as well as for identification of normal or abnormal aging of these materials.

  15. Siberian Platform: Geology and Natural Bitumen Resources

    Science.gov (United States)

    Meyer, Richard F.; Freeman, P.A.

    2006-01-01

    Summary: The Siberian platform is located between the Yenisey River on the west and the Lena River on the south and east. The Siberian platform is vast in size and inhospitable in its climate. This report is concerned principally with the setting, formation, and potential volumes of natural bitumen. In this report the volumes of maltha and asphalt referred to in the Russian literature are combined to represent natural bitumen. The generation of hydrocarbons and formation of hydrocarbon accumulations are discussed. The sedimentary basins of the Platform are described in terms of the Klemme basin classification system and the conditions controlling formation of natural bitumen. Estimates of in-place bitumen resources are reviewed and evaluated. If the bitumen volume estimate is confined to parts of identified deposits where field observations have verified rock and bitumen grades values, the bitumen resource amounts to about 62 billion barrels of oil in-place. However, estimates of an order of magnitude larger can be obtained if additional speculative and unverified rock volumes and grade measures are included.

  16. Is there widespread metal contamination from in-situ bitumen extraction at Cold Lake, Alberta heavy oil field?

    Science.gov (United States)

    Skierszkan, Elliott K; Irvine, Graham; Doyle, James R; Kimpe, Linda E; Blais, Jules M

    2013-03-01

    The extraction of oil sands by in-situ methods in Alberta has expanded dramatically in the past two decades and will soon overtake surface mining as the dominant bitumen production process in the province. While concerns regarding regional metal emissions from oil sand mining and bitumen upgrading have arisen, there is a lack of information on emissions from the in-situ industry alone. Here we show using lake sediment records and regionally-distributed soil samples that in the absence of bitumen upgrading and surface mining, there has been no significant metal (As, Cd, Cu, Hg, Ni, Pb, V) enrichment from the Cold Lake in-situ oil field. Sediment records demonstrate post-industrial Cd, Hg and Pb enrichment beginning in the early Twentieth Century, which has leveled off or declined since the onset of commercial in-situ bitumen production at Cold Lake in 1985.

  17. Self lubrication of bitumen froth in pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Joseph, D.D. [Univ. of Minnesota, Minneapolis, MN (United States)

    1997-12-31

    In this paper I will review the main properties of water lubricated pipelines and explain some new features which have emerged from studies of self-lubrication of Syncrudes` bitumen froth. When heavy oils are lubricated with water, the water and oil are continuously injected into a pipeline and the water is stable when in a lubricating sheath around the oil core. In the case of bitumen froth obtained from the Alberta tar sands, the water is dispersed in the bitumen and it is liberated at the wall under shear; water injection is not necessary because the froth is self-lubricating.

  18. CNOOC Builds Bitumen Plant in Sichuan

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    @@ In the petrochemical sector, CNOOC is building a 300,000 tonsper-year bitumen plant in western China, marking its first such investment in the remote but fast developing region, the company said on December 3. CNOOC, which produces 20 per cent of China's domestic bitumen output, will own 88 per cent of the US$36 million project in Sichuan Province and two local firms will own the remaining 12 per cent. Bitumen, or asphalt, production is scheduled to begin by the end of June 2004.

  19. INVESTIGATION OF RHEOLOGICAL PROPERTIES OF MODIFIED BITUMEN

    Directory of Open Access Journals (Sweden)

    Erofeev Vladimir Trofimovich

    2016-08-01

    Full Text Available At the present time the most widely used type of road pavement is asphalt-concrete pavement produced on the basis of oil bitumen. One of the efficient ways to increase the quality and durability of asphalt-concrete pavement is modification of bitumen. Though Russian specialists still don’t have the global view of the ideal and real asphalt cement, the requirements to its quality and durability indicators in the composition of road structure haven’t yet formed. The authors present the investigation results of the properties of oil asphalt cement containing 0.5-2.0% of modifier “Olazol”. The physical, mechanical and rheological properties of the modified bitumen are determined. The dependences of the dynamic viscosity of the modified bitumen from the quantity of introduced modifier, shear rate and reheat temperature are analyzed.

  20. Modular mobility investigation of polymer binder bitumen

    Science.gov (United States)

    Ayupov, D.; Makarov, D.; Murafa, A.; Khozin, V.; Khakimullin, Y.; Sundukov, V.; Khakimov, A.; Gizatullin, B.

    2015-01-01

    This paper is aimed to obtain polymer binder bitumen for the road applications with improved properties. Objectives included studying the degradation of crumb rubber during devulcanization in melted petroleum bitumen for its modification and resulted structural properties of bitumen. Using equilibrium swelling technique reduced density of the polymer chains was observed and analysis of sol-gel fractions showed a significant decrease in gel fraction. Under selected method of devulcanization 64% of the backbone rubber remained. With The H1 NMR relaxation method the reduction of bitumen molecular mobility was observed due to thickening of its light fractions. The effectiveness of devulcanization was optimized using a new agent in a powder form and vacuum application. The developed binder has an improved spectrum of physical and technical properties such as softening point temperature, hardness, elasticity, frost resistance, low temperature characteristics.

  1. A New Approach for Evaluating Rejuvenator Diffusing into Aged Bitumen

    Institute of Scientific and Technical Information of China (English)

    KUANG Dongliang; FENG Zhengang; YU Jianying; CHEN Xing; ZHOU Bo

    2011-01-01

    Rejuvenator diffusing into aged bitumen was evaluated by determining penetration and chemical components of aged bitumen with rejuvenator coat before and after diffusing experiment.Effects of temperature, time and viscosity of rejuvenator on the diffusing ability of rejuvenator into aged bitumen were investigated. Results indicated that the diffusing ability of rejuvenator into aged bitumen could be enhanced with the increasing of temperature and time, however, the diffusing of rejuvenator into aged bitumen would be restricted due to the volatilization of light component and aging of rejuvenator under high temperature (over 170 ℃). Rejuvenator with low viscosity diffused into aged bitumen more easily.

  2. Microstructure and Properties of Desulfurized Crumb Rubber Modified Bitumen

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The microstructures of general crumb rubber(CR), dynamic desulfurized crumb rubber(DDCR) and high speed agitation desulfurized crumb rubber(HSADCR) modified bitumens were investigated by a fluorescence microscope, and the physical properties of these three modified bitumens were studied.The results show that the dynamic desulfuration can improve the swelling capacity of crumb rubber in bitumen by destroying the sulfuratized bond of the crumb rubber,but the reunion of rubber particles during dynamic desulfuration also makes the swelling and the DDCR in bitumen difficult, so properties of the DDCR modified bitumen are not superior to the general crumb rubber modified bitumen.However,high speed agitation desulfuration can not only improve the swelling capacity of crumb rubber in bitumen,but also avoid the reunion of rubber particles,so some properties of bitumen can be improved by the modification of HSADCR.

  3. Waterproof casts for immobilization of children's fractures and sprains.

    Science.gov (United States)

    Shannon, Elizabeth G; DiFazio, Rachel; Kasser, James; Karlin, Lawrence; Gerbino, Peter

    2005-01-01

    This study was designed to determine the efficacy of waterproof cast-lining materials in children with short-arm, long-arm, and short-leg casts. Eligible patients had healing fractures 2 weeks after reduction, stable fractures requiring no reduction, or sprains. A total of 165 waterproof-lined casts were applied and 124 children and parents completed a survey (76.9%) upon cast removal. Results revealed 79% very satisfied, 21% satisfied, and 0% dissatisfied. There were 16 (12.9%) minor skin integrity issues. Waterproof casts in stable fractures and sprains allow acceptable immobilization with no significant associated unusual risk and allow children to resume their usual recreational water activities and hygiene regimen without risk of adverse results.

  4. Cooee bitumen. II. Stability of linear asphaltene nanoaggregates

    DEFF Research Database (Denmark)

    Lemarchand, Claire; Schrøder, Thomas; Dyre, J. C.;

    2014-01-01

    Asphaltene and smaller aromatic molecules tend to form linear nanoaggregates in bitumen. Over the years bitumen undergoes chemical aging and during this process, the size of the nanoaggregate increases. This increase is associated with an increase in viscosity and brittleness of the bitumen...

  5. [Use of bitumen in medicine throughout the ages].

    Science.gov (United States)

    Bourée, Patrice; Blanc-Valleron, Marie-Madeleine; Ensaf, Mansour; Ensaf, Alireza

    2011-01-01

    Bitumen, which results of the storage of organic material and of the decomposition in process of time, was used since ancient times for cosmetic, art and the caulk of boats. So, mummies were treated by bitumen to improve their preservation. But bitumen was held to be useful to cure varying pulmonary, digestive, ENT troubles and even to set fractures. Besides, bitumen was used to realize the first photograph. In Iran, bitumen is yet used to improve the quality of the skin, but mixed with to limit its toxicity.

  6. Technology of Anticorrosive Protection of Steel Constructions by Coatings Based on Rapid-Hardening Bitumen-Latex Emulsion

    Directory of Open Access Journals (Sweden)

    Nykyforchyn, H.M.

    2016-01-01

    Full Text Available The recipes of rapid-hardening bitumen-latex emulsions and coatings on its base are created, in-laboratory tests of their physical, chemical and anticorrosive properties are carried out. The technology of anticorrosive protection and the installation technical documentation for making of aqueous bitumen-latex emulsion is developed, installation is mounted and a pilot lot of rapid-hardening emulsion is produced. Experimental-industrial approbation of the technology of coating formation on pipes in oil and gas industry is carried out.

  7. Bitumen recovery from surface mined oil sands recycle water ponds

    Energy Technology Data Exchange (ETDEWEB)

    Mikula, R.J.; Munoz, V.A.; Elliott, G. L. [Natural Resources Canada, CanmetENERGY, Devon, Alberta (Canada)

    2011-07-01

    In surface mined oil sands, high bitumen recovery can be achieved but tailings have accumulated over the years. Several technologies have been proposed for recovering bitumen from tailings, but because this bitumen carries high surfactant concentrations there have been processing problems. This paper presents the application of oxidized ore characterization and processing methods to process tailings pond bitumen. Laboratory tests were carried out to characterize bitumen samples coming from four different tailings sources and tests were run with caustic additive. Results showed that high caustic additions can be applied to surfactant rich tailings pond bitumen to avoid downstream froth treatment emulsion problems; the oxidation degree should be carefully monitored. This study demonstrated that the use of caustic additive, already used for oxidized ores, can be applied to treat the bitumen recovered from tailings streams.

  8. Valorization of phosphogypsum waste as asphaltic bitumen modifier.

    Science.gov (United States)

    Cuadri, A A; Navarro, F J; García-Morales, M; Bolívar, J P

    2014-08-30

    The accumulation of phosphogypsum waste from the fertilizer industries, which remain in regulated stacks occupying considerable land resources, is causing significant environment problems worldwide. In that sense, the scientific community is being pressured to find alternative ways for their disposal. In this research, we propose a novel application for phosphogypsum waste, as a modifier of bitumen for flexible road pavements. Viscous flow tests carried out on bitumen modified with a phosphogypsum waste and doped with sulfuric acid demonstrated an extraordinary increase in viscosity, at 60°C, when compared to a counterpart sample which had been modified with gypsum, the main component of phosphogypsum. Similarly, a significant improvement in the viscoelastic response of the resulting material at high temperatures was also found. FTIR (Fourier transform infrared spectroscopy) scans provided evidences of the existence of chemical reactions involving phosphorus, as revealed by a new absorption band from 1060 to 1180cm(-1), related to COP vibrations. This result points at phosphorus contained in the phosphogypsum impurities to be the actual "modifying" substance. Furthermore, no COP band was observed in the absence of sulfuric acid, which seems to be the "promoting" agent of this type of bond.

  9. Full recovery of Arundo donax particleboard from swelling test without waterproofing additives

    Directory of Open Access Journals (Sweden)

    Jose-Antonio Flores-Yepes

    2012-11-01

    Full Text Available This paper presents the development of particleboard based on common reed, reproducing the industry standard manufacturing process applied to wood chipboard. One of the main properties of the resulting board was its resistance to water, due to the hydrophobic properties of the common reed, despite there being no incorporation of melamine or any other waterproofing additive. The boards that were developed were analyzed using 2 mm and 4 mm sieves for fibre selection, a manufacturing pressure of 3 N/mm2 and 25 N/mm2, and a volume of urea formaldehyde resin content ranging from 5.2% to 13% (8 to 20% liquid format. Standard destructive tests were performed. It was found that under certain applied conditions, namely high pressure and adequate resin proportion (a pressure of over 3 N/mm2 and over 15% liquid resin, Arundo donax L. particleboard demonstrated full recovery from the swelling test. This finding highlights an unmatched property in terms of recovery from the swelling test of the designed board. This property confers a interesting property to be used in high humidity environments without the need for special resin or waterproofing process.

  10. Effect of processing temperature on the bitumen/MDI-PEG reactivity

    Energy Technology Data Exchange (ETDEWEB)

    Martin-Alfonso, M.J.; Partal, P.; Navarro, F.J.; Garcia-Morales, M. [Departamento de Ingenieria Quimica, Facultad de Ciencias Experimentales, Campus de ' El Carmen' , Universidad de Huelva, 21071, Huelva (Spain); Bordado, J.C.M. [Chemical and Biological Engineering Department, IBB, Instituto Superior Tecnico, Av. Rovisco Pais 1049-001 Lisbon (Portugal); Diogo, A.C. [Materials Engineering Department, Instituto Superior Tecnico, Av. Rovisco Pais 1049-001 Lisbon (Portugal)

    2009-04-15

    Reactive polymers are lately gaining acceptance to give added value to a residue of the crude oil refining process such as bitumen. The resulting material should display enhanced mechanical properties to be considered for advanced applications in construction. In the present paper, we report the effect of processing temperature on the reaction between bitumen compounds and an isocyanate-based reactive polymer, synthesized by reaction of polymeric MDI (4,4'-diphenylmethane diisocyanate) with a low molecular weight polyethylene-glycol (PEG). Rheokinetics experiments, viscosity measurements at 60 C, atomic force microscopy (AFM) characterization, thin layer chromatography (TLC-FID) analysis and thermogravimetric studies (TGA) were performed on the reactive polymer and on samples of MDI-PEG modified bitumen containing 2 wt.% of the polymer. Results showed the existence of an optimum processing temperature arisen as a consequence of opposite effects: microstructural availability for the formation of a polymer-bitumen network, reaction ability and polymer thermal degradation. Consequently, this study aims to serve as a guideline for the refining and asphalt industries facing the stage of selecting the optimum processing parameters. (author)

  11. Origin of Unliberated Bitumen in Athabasca Oil Sands

    Institute of Scientific and Technical Information of China (English)

    TuYun; J.B.O'Carroll; B.D.Sparks; L.S.Kotlyar; S.Ng; K.H.Chung; G.Cuddy

    2005-01-01

    Oil sands contain a so-called organic rich solids component (ORS), i.e., solids whose surfaces are strongly associated with toluene insoluble organic matter (TIOM). Typically, humic material is the major component of TIOM.It provides sites for adsorption and chemical fixation of bitumen. This bound bitumen is """"""""unliberated"""""""", and considerable mechanical or chemical energy may be required to release it. In order to establish a correlation between bitumen recovery and ORS content, a few selected oil sands were processed in a Batch Extraction Unit (BEU).Analysis of the middlings and coarse tailings streams from these tests indicated a relatively constant bitumen to ORS ratio of 2.8±0.7. This value allows the liberated-unliberated bitumen balance (LUBB) to be calculated for any given oil sands. The amounts of bitumen recovered as primary froth during the BEU experiments are close to the estimated liberated bitumen contents in each case tested. This observation indicates that the liberated-unliberated bitumen calculation is an important quantitative parameter for prediction of bitumen recovery under specific recovery conditions. Preliminary results indicate that the ORS content of an oil sands may be estimated from the carbon content of bitumen free oil sands solids.

  12. The production of stable bitumen-polymer blends

    Energy Technology Data Exchange (ETDEWEB)

    Jovanovic, J.; Sokic, M. (Faculty of Technology and Metallurgy, Univ. Belgrade (Yugoslavia)); Smiljanic, M.; Pab, I. (Highway Inst., Belgrade (Yugoslavia)); Neumann, H.J.; Rahimian, I. (German Inst. for Petroleum Research, Clausthal-Zellerfeld (Germany))

    1993-01-01

    If either blown bitumen or bitumens of inadequate origin and type are used for the production of bitumen-polymer blends containing SBS- and/or SBR-elastomers, it is often not possible to obtain stable homogeneous bitumen-polymer blends. In that case pretreatment of the elastomer component is necessary. The production of stable bitumen-polymer blends from SBS- and SBR-elastomers and blown bitumens from Yugoslav refineries in Novi Sad and Pancevo were studied in this paper. Pretreatment of the elastomer components was performed with a residue of the distillation of fatty acids and/or with pyrolysis oil from a naphtha steam pyrolysis unit. Infrared spectroscopy was used to determine the kinetics of the dissolution of the elastomers in the bitumen. The rate of dissolution of SBR-elastomer was practically independent of the bitumen type. In the case of SBS-elastomer, however, the kinetics of the dissolving process was strongly influenced by the bitumen type. The origin of bitumen influenced the dissolution kinetics too. (orig.).

  13. Influence of the association of the EVA and NBR on the characteristics of modified bitumen

    Science.gov (United States)

    Bensaada, A.; Soudani, K.; Haddadi, S.; Saoula, S.

    2015-03-01

    Durability and the performance of pavement depend mainly on the characteristics of materials which change over time like all other organic substances. They are subject to significant changes due to environmental conditions during the different phases of use. In the present work we investigated experimentally the influence of the association of ethyl vinyl acetate polymer (EVA) with an industrial waste, acrylonitrile-butadiene rubber (NBR) on the modification of bitumen AC 35-50 and its rheological behavior. The incorporation of NBR and EVA in the bitumen improved its intrinsic characteristics (softening point, penetration and ductility). In addition to improving the characteristics of bituminous binders that will affect the durability of bituminous structures, the environment will be preserved by the recycling of industrial waste.

  14. Use of Bitumen Emulsion for Flexible Road Construction

    Directory of Open Access Journals (Sweden)

    Shivani Singh Dhriyan

    2017-02-01

    Full Text Available In the present study bitumen is replaced by bitumen emulsion for the construction of flexible pavement. The conventional method of road construction involves the burning of bitumen which produces toxic gases which degrades the environment. In colder region it is difficult to maintain the paving temperature of hot mix. To overcome these problems and conserve the energy bitumen emulsion is considered as good option. Likewise emulsion can be used in the areas having higher rate of rainfall where the hot mix plant is closed most of the time because of rain. Emulsified bitumen can be used during rainy season and colder regions. To study the suitability of emulsion Marshal Test is carried out to find the stability value, flow value and optimum binder content. Experiments performed shows that bitumen emulsion (Cold Mix have high stability value therefore it can be used as binder.

  15. Investigation of rheological properties of TPS modified bitumen

    Institute of Scientific and Technical Information of China (English)

    刘全涛; 吴少鹏; 刘聪慧; 王金刚

    2008-01-01

    Rheological properties of the virgin bitumen and TPS modified bitumen binders with several percentages of TPS additives were studied.All TPS modified bituminous binders were prepared on a laboratory scale.Dynamic shear rheometer(DSR) strain sweep test was made to measure the linear viscoelasticity areas of various bitumen binders at -20-70 ℃,then temperature sweep test and frequency sweep test were made in the linear viscoelasticity areas.Complex modulus master curves were drawn to analyze and compare various bitumen binders’ rheological properties.Based on the test results,the ideal percentage of TPS additive was brought forward.The results show that TPS modified bitumen binders have more excellent properties at high,medium and low temperatures compared with original bitumen.The dosages of TPS additive are vital to their properties.

  16. Volume Stability of Bitumen Bound Building Blocks

    Directory of Open Access Journals (Sweden)

    Thanaya I.N.A.

    2010-01-01

    Full Text Available This paper covers results of laboratory investigations on the volume stability of masonry units incorporating waste materials bound with bitumen (Bitublocks, due to moisture adsorption, thermal exposure and vacuum saturation. The materials used were steel slag, crushed glass, coal fly ash, and 50 pen bitumen. The samples were produced in hot mix method, compacted, then exposed to moist and temperature. It was found that moisture adsorption from the environment caused the Bitublock to expand. The samples with less intense curing regime experienced lower expansion and became stable faster, and vice versa. Under thermal condition (at 70°C, the samples with less intense curing regime underwent higher expansion, and vice versa. They were also highly reversible. Their volume stability was found unique under water exposure. The expansion on first vacuum saturation cycle was irreversible, then largely reversible on the following cycles.

  17. Effect of base bitumen composition on asphalt rubber binder properties

    OpenAIRE

    Partl, M.N.; Ould-Henia, M.; Dumont, A.-G.

    2008-01-01

    The asphalt rubber blend properties are strongly related to its base components properties. The base bitumen composition is considered as a key factor influencing the final rheological properties of asphalt rubber binder. This paper describes results from a laboratory investigation of the interaction between crumb rubber and different composition bitumen according to the wet process. The bitumen composition is determined according to the SARA decomposition approac...

  18. Mutagenicity of bitumen and asphalt fumes.

    Science.gov (United States)

    Heikkilä, P R; Väänänen, V; Hämeilä, M; Linnainmaa, K

    2003-08-01

    The mutagenicity of asphalt fumes was tested with the Salmonella bioassays. The aim was to investigate if recycled additives modify the genotoxicity of emissions. Recycling of old asphalt is increasing, and we studied also the mutagenicity of emissions sampled during the re-use of asphalt. The composition of vapours and fumes were analysed by gas chromatography and by liquid chromatography. Bitumens containing coal fly ash (CFA) or waste plastics were heated to the paving temperatures in the laboratory. In the field, bitumen fumes were collected during paving of stone mastic asphalts (lime or CFA as a filler), remixing of stone mastic asphalt (lime or CFA as a filler), and of asphalt concrete. All the lab-generated vapour fractions were non-mutagenic. The particulate fractions were mutagenic with TA98 in the presence of the S9 activation. In addition, the lab-fumes from bitumen containing waste plastics were positive with both strains without S9. Only particulate fractions sampled in the field were tested. They were mutagenic with and without metabolic activation with both strains. The mutagenic potency of the field samples was higher than that of the lab-generated fumes without S9, and the remixing fumes were more mutagenic than the normal paving and lab-generated fumes with S9. The use of inorganic additive, CFA, did not change the mutagenicity of the fumes, whereas the organic additive, waste plastics, increased the mutagenicity of the laboratory emissions significantly.

  19. Autosolvent effect of bitumen in thermal cracking; Netsubunkai hanno ni okeru bitumen no jiko yobai koka

    Energy Technology Data Exchange (ETDEWEB)

    Mikuni, M.; Sato, M.; Hattori, H. [Hokkaido University, Sapporo (Japan). Center for Advanced Research of Energy Technology; Nagaishi, H.; Sasaki, M.; Yoshida, T. [Hokkaido National Industrial Research Institute, Sapporo (Japan)

    1996-10-28

    Tar sand bitumen is petroleum-based ultra-heavy oil, and has a great amount of reserve like coal. However, there are still a lot of problems for its highly effective utilization. This paper discusses whether the light components in bitumen show independent behavior during the thermal cracking of heavy components, or not. Solvent effect and reaction mechanism during the thermal cracking are also derived from the change of their chemical structures. Athabasca tar sand bitumen was separated into light and heavy fractions by vacuum distillation based on D-1660 of ASTM. Mixtures of the both fractions at various ratios were used as samples. Negative effect of the light fraction on cracking of the heavy fraction was observed with dealkylation and paraffin formation Polymerization of the dealkylated light fraction to the heavy fraction was suggested due to lack of hydrogen in the thermal cracking under nitrogen atmosphere, which resulted in the formation of polymer. 3 refs., 6 figs.

  20. Investigations of Physical and Rheological Properties of Aged Rubberised Bitumen

    Directory of Open Access Journals (Sweden)

    Asim Hassan Ali

    2013-01-01

    Full Text Available Several road pavement distresses are related to rheological bitumen properties. Rutting and fatigue cracking are the major distresses that lead to permanent failures in pavement construction. Influence of crumb rubber modifier (CRM on rheological properties of bitumen binder such as improvement of high and intermediate temperatures is investigated in the binder’s fatigue and rutting resistance through physical-rheological changes in this research. The bitumen binders were aged by rolling thin film oven (RTFOT to simulate short-term aging and pressure aging vessel (PAV to simulate long-term aging. The effects of aging on the rheological and physical properties of bitumen binders were studied conducting dynamic shear rheometer test (DSR, Brookfield viscometer test, softening point test, and penetration test. The results showed that the use of rubberised bitumen binder reduces the aging effect on physical and rheological properties of the bitumen binder as illustrated through lower aging index of viscosity, lower aging index of , and an increase in with crumb rubber modifier content increasing, indicating that the crumb rubber might improve the aging resistance of rubberised bitumen binder. In addition, the results showed that the softening point increment ( and penetration aging ratio (PAR of the rubberised bitumen binder decreased significantly due to crumb rubber modification. Furthermore, the higher crumb rubber content, the lower after PAV aging, which led to higher resistance to fatigue cracking bitumen.

  1. Rheological properties of styrene butadiene styrene polymer modified road bitumens

    Energy Technology Data Exchange (ETDEWEB)

    Gordon D. Airey [University of Nottingham, Nottingham (United Kingdom). Nottingham Centre for Pavement Engineering, School of Civil Engineering

    2003-10-01

    The use of polymers for the modification of bitumen in road paving applications has been growing rapidly over the last decade as government authorities and paving contractors seek to improve road life in the face of increased traffic. Currently, the most commonly used polymer for bitumen modification is the elastomer styrene butadiene styrene (SBS) followed by other polymers such as styrene butadiene rubber, ethylene vinyl acetate and polyethylene. This paper describes the polymer modification of two penetration grade bitumens with SBS. Six polymer modified bitumens (PMBs) were produced by mixing the bitumens from two crude oil sources with a linear SBS copolymer at three polymer contents. The rheological characteristics of the SBS PMBs were analysed by means of conventional as well as dynamic mechanical analysis using a dynamic shear rheometer (DSR). The results of the investigation indicate that the degree of SBS modification is a function of bitumen source, bitumen polymer compatibility and polymer concentration, with the higher polymer concentrations in a high aromatic content bitumen producing a highly elastic network which increases the viscosity, complex modulus and elastic response of the PMB, particularly at high service temperatures. However, ageing of the SBS PMBs tends to result in a reduction of the molecular size of the SBS copolymer with a decrease in the elastic response of the modified road bitumen. 25 refs., 11 figs., 6 tabs.

  2. The comparative study of solvents to expedite removal of bitumen.

    Science.gov (United States)

    Iuchi, Manabu; Sugiyama, Masahide; Oyatsu, Yasuyuki; Fukai, Takao

    2009-03-01

    Hot-bitumen burn is a unique case in all types of burns. This melting substance is difficult to remove when it adheres to the skin and solidifies. It causes burns and sticks to the skin when it is cooled to the skin temperature. Some reports are available on many kinds of solvents for the removal of solid bitumen. However, there have thus far been no comparative studies. It is necessary to seek for an optimum method to remove bitumen without consuming so much time and with minimum injury to the skin. The selected solvents in this study were petrolatum, olive oil, salad oil, butter, Neosporin ointment and De-solv-it. They were often reported as being effective for hot-bitumen burn injuries with little irritation for a damaged skin. It is easy to purchase them commercially. Each solvent was poured over the bitumen in a test tube. Afterwards, the concentrations of the bitumen in the solvents were quantified with the fluorescence measurement technique. We consider De-solv-it is the one of the best solvent for the removal of bitumen and highly recommended for hot-bitumen burns. The results of this study suggest that dressing change should be done every 4 to 8 h or as frequently as needed until the bitumen is entirely removed.

  3. FTIR instrumentation to monitor vapors from Shuttle tile waterproofing materials

    Science.gov (United States)

    Mattson, C. B.; Schwindt, C. J.

    1995-11-01

    The Space Shuttle Thermal Protection System (TPS) tiles and blankets are waterproofed using DimethylEthoxySilane (DMEX) in the Orbiter Processing Facilities (OPF). DMES has a Threshold Limit Value (TLV) for exposure of personnel to vapor concentration in air of 0.5 ppm. The OPF high bay cannot be opened for normal work after a waterproofing operation until the DMES concentration is verified by measurement to be below the TLV. On several occasions the high bay has been kept closed for up to 8 hours following waterproofing operations due to high DMES measurements. In addition, the Miran 203 and Miran 1 BX infrared analyzers calibrated at different wavelengths gave different readings under the same conditions. There was reason to believe that some of the high DMES concentration readings were caused by interference form water and ethanol vapors. The Toxic Vapor Detection Laboratory (TVDL) was asked to test the existing DMES instruments and identify the best qualified instrument. In addition the TVDL was requested to develop instrumentation to ensure the OPF high bay could be opened safely as soon as possible after a waterproofing operation. A Fourier Transform Infrared (FTIR) spectrophotometer instrument developed for an earlier project was reprogrammed to measure DMES vapor along with ethanol, water, and several common solvent vapors. The FTIR was then used to perform a series of laboratory and field tests to evaluate the performance of the single wavelength IR instruments in use. The results demonstrated that the single wavelength IR instruments did respond to ethanol and water vapors, more or less depending on the analytical IR wavelength selected. The FTIR was able to separate the responses to DMES, water and ethanol, and give consistent readings for the DMES vapor concentration. The FTIR was then deployed to the OPF to monitor real waterproofing operations. The FTIR was also used to measure the time for DMES to evaporate from TPS tile under a range of humidity

  4. Effect of different montmorillonites on rheological properties of bitumen/clay nanocomposites

    Institute of Scientific and Technical Information of China (English)

    陶园园; 余剑英; 李斌; 冯鹏程

    2008-01-01

    Different composites of organomodified montmorillonite(OMMT)/bitumen were prepared by melt blending with hexadecyl dimethyl benzyl ammonium modified montmorillonite(HBM) and double octadecyl dimethyl ammonium modified montmorillonite(DOM).The structures of two kinds of montmorillonite modified bitumen were characterized by X-ray diffraction(XRD).The effects of different montmorillonites on the dynamic rheological properties of the modified bitumens were investigated by dynamic shear rheometer(DSR).The XRD results show that DOM modified bitumen forms an intercalated structure,whereas the HBM modified bitumen forms an exfoliated structure.DSR results indicate that OMMT modified bitumens exhibit higher complex modulus,lower phase angle than pristine bitumen,which means that the resistance to rutting at high temperatures of pristine bitumen is improved due to the introduction of OMMT.Compared with DOM modified bitumen,HBM modified bitumen shows better rutting resistance,which is contributed to the formation of exfoliated structure in HBM modified bitumen.

  5. Orinoco bitumen in water emulsion (Orimulsion): untapping an unlimited premium fuel

    Energy Technology Data Exchange (ETDEWEB)

    Polanco, D.R.; Euler Jimenez G.; Javier Izaguirre M.; Jose Salazar P.; Carrizo, R.; Alcantara, J.

    1987-01-01

    Venezuela has extensive recoverable reserves of extra heavy crudes and natural bitumens located in the Orinoco Oil Belt. INTEVEP, S.A. and LAGOVEN, S.A. have developed the Orinoco bitumen in water emulsion (ORIMULSION) for the production, handling and transportation of those hydrocarbons. This emulsion is considered a premium fuel due to its performance in conventional liquid firing systems. Pilot scale combustion tests, conducted during 1986, at INTEVEP Combustion Research Facility (ICRF) and Nagasaki Technical Institute (NTI-Mitsubishi Heavy Industries), Japan, have demonstrated the technical feasibility of burning this natural fuel steam-assisted, obtaining high combustion efficiency values (99.90%), which resemble those of a No.6 fuel-oil. This allows forecasting a promising future for ORIMULSION as a new fuel for thermal power stations.

  6. Aqueous leaching of polycyclic aromatic hydrocarbons from bitumen and asphalt.

    Science.gov (United States)

    Brandt, H C; de Groot, P C

    2001-12-01

    The application of bitumen in, e.g. asphalt roads, roofs and hydraulic applications will lead to the leaching of compounds from the bitumen/asphalt into the environment. Because polycyclic aromatic hydrocarbons (PAHs) are present in bitumen, static and dynamic leach tests have been performed to study the leaching behaviour of this class of compounds. Nine petroleum bitumens covering a representative range of commercially available products and one asphalt made from one of the bitumens have been tested in a static leach test. The asphalt has been also subjected to a dynamic leach test. The main conclusions are that a 30h dynamic leach test is sufficient to determine the equilibrium concentration that will be reached after bitumen or asphalt has been in contact with the water for more than 3-6 days. As an alternative to performing a leach test, this concentration can be calculated from the PAH concentrations in the bitumen, and their distribution coefficients, as calculated here, or from their aqueous solubilities. The equilibrium PAH concentrations in the leach water from bitumens stay well below the surface water limits that exist in several EEC-countries and are also more than an order of magnitude lower than the current EEC limits for potable water.

  7. Vergelijkend AFM Onderzoek: microstructuur van bitumen in relatie tot healing

    NARCIS (Netherlands)

    Schmets, A.J.M.; Nahar, S.N.; Dillingh, B.; Fischer, H.; Scarpas, A.; Erkens, S.

    2012-01-01

    In this report we present the background, the scientific and experimental approach and the results of AFM experiments performed on two different batches of bitumen. The specific bitumen researched in this project has also been studied in the context of the InfraQuest project ‘Pragmatisch Healing On

  8. Developments in the uses of foamed bitumen in road pavements

    NARCIS (Netherlands)

    Jenkins, K.J.; Molenaar, A.A.A.; De Groot, J.L.A.; Van de Ven, M.E.C.

    2000-01-01

    Following the lapse in patent rights on foam-producing nozzles, the use of foamed bitumen for the improvement of road construction materials has become more accessible and as a result, it's use increased considerably in the 1990's. In addition, the applications of foamed bitumen process have diversi

  9. Extraction of Peace River bitumen using supercritical ethane

    Science.gov (United States)

    Rose, Jeffrey Lawrence

    2000-10-01

    As the supply of conventional crude oil continues to decline, petroleum companies are looking for alternative hydrocarbon sources. The vast reserves of heavy oil and bitumen located in northern Alberta are among the alternatives. The challenge facing engineers is to develop a process for recovering this oil which is economic, efficient and environmentally acceptable. Supercritical fluid extraction is one method being investigated which could potentially meet all of these criteria. In this study, Peace River bitumen was extracted using supercritical ethane. The bitumen was mixed with sand and packed into a semi-batch extractor. Ethane contacted the bitumen/sand mixture and the fraction of the bitumen soluble in the ethane was removed and subsequently collected in a two phase separator. The flow of ethane was such that the experiments were governed by equilibrium and not mass transfer. Experimental temperatures and pressures were varied in order to observe the effect of these parameters on the mass and composition of the extracted material. The extraction yields increased as the temperature decreased and pressure increased. Samples were collected at various time intervals to measure changes in the properties of the extracted bitumen over the duration of the process. As the extraction proceeded, the samples became heavier and more viscous. The bitumen feed was characterised and the experimental data was then modelled using the Peng-Robinson equation of state. The characterisation process involved the distillation of the bitumen into five fractions. The distillation curve and density of each fraction was measured and this data was used in conjunction with correlations to determine the critical properties of the bitumen. Interaction parameters in the equation of state were then optimised until the predicted composition of extracted bitumen matched the experimental results.

  10. The extraction of bitumen from western oil sands. Final report, July 1989--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1994-03-01

    Research and development of surface extraction and upgrading processes of western tar sands are described. Research areas included modified hot water, fluidized bed, and rotary kiln pyrolysis of tar sands for extraction of bitumen. Bitumen upgrading included solvent extraction of bitumen, and catalytic hydrotreating of bitumen. Characterization of Utah tar sand deposits is also included.

  11. The extraction of bitumen from western oil sands. Quarterly report, April--June 1993

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1993-07-01

    Accomplishments are briefly described for the following tasks: environmental impact statement; coupled fluidized bed bitumen recovery and coked sand combustion; water-based recovery of bitumen; rotary kiln process for recovery of bitumen and combustion of coke sand; recovery of bitumen from oil sands using fluidized bed reactors and combustion of spent sands in transport reactors; recovery of bitumen from oil sand and upgrading of bitumen by solvent extraction; catalytic and thermal upgrading of bitumens and bitumen-derived liquids; evaluation of Utah`s major oil sand deposits for the production of asphalt, high energy jet fuels and other specialty products; development of mathematical models for bitumen recovery and processing; completion of the cost examination study of the pilot plant restoration; development studies of equipment for three-product gravity separation of bitumen and sand; determine thickener requirements; and environmental studies of the North Salt Lake pilot plant rehabilitation and eventual operation and those environmental problems associated with eventual commercial products.

  12. A rheological study of behavior of polymer-bitumen blends

    Energy Technology Data Exchange (ETDEWEB)

    Djonlagic, J. [Belgrade Univ. (Yugoslavia). Faculty of Technology and Metallurgy; Dunjic, B. [Belgrade Univ. (Yugoslavia). Faculty of Technology and Metallurgy; Javanovic, J.A. [Belgrade Univ. (Yugoslavia). Faculty of Technology and Metallurgy

    1996-12-01

    The influence of the elastomer such as SBS and SBR and their mixtures on the structure and rheological properties of blown bitumen B 65 blends, was studied. The crude oil denoted as SEB (Soviet Export Blend) was used to obtain the B 65 sample. (orig./HS) [Deutsch] Es wurde die Wirkung der SBR- und SBS-Elastomere und ihrer Mischungen, auf die Struktur und die rheologischen Eigenschaften des aus geblasenem Bitumen B 65 hergestellten Polymer-Bitumens (PmB), untersucht. Die B 65 Probe stammte aus dem Erdoel SEB (Soviet Export Blend). (orig./HS)

  13. The fatty acyl-CoA reductase Waterproof mediates airway clearance in Drosophila.

    Science.gov (United States)

    Jaspers, Martin H J; Pflanz, Ralf; Riedel, Dietmar; Kawelke, Steffen; Feussner, Ivo; Schuh, Reinhard

    2014-01-01

    The transition from a liquid to a gas filled tubular network is the prerequisite for normal function of vertebrate lungs and invertebrate tracheal systems. However, the mechanisms underlying the process of gas filling remain obscure. Here we show that waterproof, encoding a fatty acyl-CoA reductase (FAR), is essential for the gas filling of the tracheal tubes during Drosophila embryogenesis, and does not affect branch network formation or key tracheal maturation processes. However, electron microscopic analysis reveals that in waterproof mutant embryos the formation of the outermost tracheal cuticle sublayer, the envelope, is disrupted and the hydrophobic tracheal coating is damaged. Genetic and gain-of-function experiments indicate a non-cell-autonomous waterproof function for the beginning of the tracheal gas filling process. Interestingly, Waterproof reduces very long chain fatty acids of 24 and 26 carbon atoms to fatty alcohols. Thus, we propose that Waterproof plays a key role in tracheal gas filling by providing very long chain fatty alcohols that serve as potential substrates for wax ester synthesis or related hydrophobic substances that ultimately coat the inner lining of the trachea. The hydrophobicity in turn reduces the tensile strength of the liquid inside the trachea, leading to the formation of a gas bubble, the focal point for subsequent gas filling. Waterproof represents the first enzyme described to date that is necessary for tracheal gas filling without affecting branch morphology. Considering its conservation throughout evolution, Waterproof orthologues may play a similar role in the vertebrate lung.

  14. Electroarc vapourtron for bitumen extraction and transportation

    Science.gov (United States)

    Ganieva, G. R.; Timerkaev, B. A.

    2017-01-01

    In this article, we propose the unique submersible arc vapourtron designed to generate very large amount of highly overheated water vapour. The most prospective application of such vapourtron is producing and processing of heavy oil and natural bitumen. The vapourtron represents an electroarc plasmatron using water or water vapour as a working media. Firstly arriving from an external source water enters the cooling jackets of the cathode and the cylindrical anode, where it is preheated to high temperatures. In extreme cases. Water can be heated till the boiling point. Then, this water is supplied to the plasmatron where it is sprayed as the media for the plasma generation. A special twist of the water flow protects the anode walls from overheating.

  15. Waterproofed photomultiplier tube assemblies for the Daya Bay reactor neutrino experiment

    Energy Technology Data Exchange (ETDEWEB)

    Chow, Ken [Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Cummings, John [Department of Physics and Astronomy, Siena College, Loudonville, NY 12211 (United States); Edwards, Emily [Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Edwards, William [Physics Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Ely, Ry [Department of Physics, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Hoff, Matthew [Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Lebanowski, Logan [Department of Physics, University of Houston, Houston, TX 77204-5005 (United States); Li, Bo; Li, Piyi [School of Physics, Shandong University, Jinan 250100 (China); Lin, Shih-Kai [Department of Physics, University of Houston, Houston, TX 77204-5005 (United States); Liu, Dawei [Department of Physics, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Liu, Jinchang [Key Laboratory of Particle Astrophysics, Institute of High Energy Physics, Beijing 100049 (China); Luk, Kam-Biu, E-mail: k_luk@berkeley.edu [Department of Physics, University of California, Berkeley, CA 94720 (United States); Physics Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Miao, Jiayuan [School of Physics, Shandong University, Jinan 250100 (China); Napolitano, Jim [Department of Physics, Temple University, Philadelphia, PA 19122 (United States); Ochoa-Ricoux, Juan Pedro [Physics Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Peng, Jen-Chieh [Department of Physics, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Qi, Ming [Department of Physics, Nanjing University, Nanjing 210000 (China); and others

    2015-09-11

    In the Daya Bay Reactor Neutrino Experiment 960 20-cm-diameter waterproof photomultiplier tubes are used to instrument three water pools as Cherenkov detectors for detecting cosmic-ray muons. Of these 960 photomultiplier tubes, 341 are recycled from the MACRO experiment. A systematic program was undertaken to refurbish them as waterproof assemblies. In the context of passing the water leakage check, a success rate better than 97% was achieved. Details of the design, fabrication, testing, operation, and performance of these waterproofed photomultiplier-tube assemblies are presented.

  16. Waterproofed Photomultiplier Tube Assemblies for the Daya Bay Reactor Neutrino Experiment

    CERN Document Server

    Chow, Ken; Edwards, Emily; Edwards, William; Ely, Ry; Hoff, Matthew; Lebanowski, Logan; Li, Bo; Li, Piyi; Lin, Shih-Kai; Liu, Dawei; Liu, Jinchang; Luk, Kam-Biu; Miao, Jiayuan; Napolitano, Jim; Ochoa-Ricoux, Juan Pedro; Peng, Jen-Chieh; Qi, Ming; Steiner, Herbert; Stoler, Paul; Stuart, Mary; Wang, Lingyu; Yang, Changgen; Zhong, Weili

    2015-01-01

    In the Daya Bay Reactor Neutrino Experiment 960 20-cm-diameter waterproof photomultiplier tubes are used to instrument three water pools as Cherenkov detectors for detecting cosmic-ray muons. Of these 960 photomultiplier tubes, 341 are recycled from the MACRO experiment. A systematic program was undertaken to refurbish them as waterproof assemblies. In the context of passing the water leakage check, a success rate better than 97% was achieved. Details of the design, fabrication, testing, operation, and performance of these waterproofed photomultiplier-tube assemblies are presented.

  17. Rheological characteristics of polymer modified and aged bitumens

    OpenAIRE

    Airey, Gordon Dan

    1997-01-01

    The demands on asphalt pavements, as a result of the growth in traffic volumes, traffic loads and tyre contact pressures, has resulted in an increased interest in the use of modified bitumens, particularly over the last ten years. Of the various types of modified and specialised binders that are available worldwide, polymer modified bitumens (PMB’s) have tended to be the most popular. Polymer modification significantly alters the rheological characteristics of the binder, thereby requiring th...

  18. Modelling viscosity and mass fraction of bitumen - diluent mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Miadonye, A.; Latour, N.; Puttagunta, V.R. [Lakehead Univ., Thunder Bay, ON (Canada)

    1999-07-01

    In recovery of bitumen in oil sands extraction, the reduction of the viscosity is important above and below ground. The addition of liquid diluent breaks down or weakens the intermolecular forces that create a high viscosity in bitumen. The addition of even 5% of diluent can cause a viscosity reduction in excess of 8%, thus facilitating the in situ recovery and pipeline transportation of bitumen. Knowledge of bitumen - diluent viscosity is highly important because without it, determination of upgrading processes, in situ recovery, well simulation, heat transfer, fluid flow and a variety of other engineering problems would be difficult or impossible to solve. The development of a simple correlation to predict the viscosity of binary mixtures of bitumen - diluent in any proportion is described. The developed correlation used to estimate the viscosities and mass fractions of bitumen - diluent mixtures was within acceptable limits of error. For the prediction of mixture viscosities, the developed correlation gave the best results with an overall average absolute deviation of 12% compared to those of Chironis (17%) and Cragoe (23%). Predictions of diluent mass fractions yielded a much better result with an overall average absolute deviation of 5%. The unique features of the correlation include its computational simplicity, its applicability to mixtures at temperatures other than 30 degrees C, and the fact that only the bitumen and diluent viscosities are needed to make predictions. It is the only correlation capable of predicting viscosities of mixtures, as well as diluent mass fractions required to reduce bitumen viscosity to pumping viscosities. The prediction of viscosities at 25, 60.3, and 82.6 degrees C produced excellent results, particularly at high temperatures with an average absolute deviation of below 10%. 11 refs., 3 figs., 8 tabs.

  19. ELASTICITY OF BITUMEN BINDERS AND THE FACTORS CAUSING IT

    Directory of Open Access Journals (Sweden)

    A. Galkin

    2015-12-01

    Full Text Available The article deals with the influence of the initial bitumen penetration grade and different con-centrations of the mineral filler on the elasticity of the polymer-modified bitumen (PMB with 3 and 6 % of SBS type polymer. The dependences of elasticity of the PMB on the test conditions – such as the temperature and the stress state level are shown additionally.

  20. ESTIMATE OF WORLD HEAVY CRUDE OIL AND NATURAL BITUMEN RESOURCES.

    Science.gov (United States)

    Meyer, Richard F.; Schenk, Christopher J.

    1985-01-01

    The quantity of heavy hydrocarbons - heavy crude oil and natural bitumens - known or surmised to be present in the earth is large. The total is estimated to fall in the range of 5,879,712-5,942,139 million barrels. The portion of this that may ultimately prove recoverable is small, perhaps on the order of 500,000 million barrels of heavy crude oil and 200,000 million barrels of bitumen.

  1. Investigation of the possibility of using waste cooking oil as a rejuvenating agent for aged bitumen.

    Science.gov (United States)

    Zargar, Majid; Ahmadinia, Esmaeil; Asli, Hallizza; Karim, Mohamed Rehan

    2012-09-30

    The ageing of the bitumen during storage, mixing, transport and laying on the road, as well as in service life, are the most important problems presented by the use of bitumen in pavements. This paper investigates the possibility of using waste cooking oil (WCO), which is a waste material that pollutes landfills and rivers, as an alternative natural rejuvenating agent for aged bitumen to a condition that resembles the original bitumen. With this target, the physical and chemical properties of the original bitumen, aged bitumen and rejuvenated bitumen were measured and compared by the bitumen binder tests - softening point, penetration, Brookfield viscosity, dynamic shear rheometer and Fourier transform infrared spectroscopy. In addition, the behaviour of the WCO rejuvenated bitumen is investigated and compared with virgin bitumen after using the rolling thin film oven ageing process. In general, the results showed that using 3-4% of WCO the aged bitumen group 40/50 was rejuvenated to a condition that closely resembled the physical, rheological properties of the original bitumen (80/100), however, there was a difference in the tendency to ageing between the WCO rejuvenated bitumen and the virgin bitumen during mixing, transport and laying on the road.

  2. Storage stability of SBS/sulfur modified bitumens at high temperature: influence of bitumen composition and structure

    OpenAIRE

    Aguirre de Carcer, I.; Masegosa Fanego, Rosa María; Viñas Sánchez, María Teresa; Sanchez-Cabezudo Tirado, Marta; Salom Coll, Catalina; González Prolongo, Margarita; Contreras, Verónica; Barceló, Francisco; Páez, Antonio

    2014-01-01

    Polymer modified bitumens, PMBs, are usually prepared at high temperature and subsequently stored for a period of time, also at high temperature. The stability of PMBs, in these conditions, has a decisive influence in order to obtain the adequate performances for practical applications. In this article the attention is focused in the analysis of the factors that determine the stability of styrene–butadiene–styrene copolymer (SBS)/sulfur modified bitumens when the mixtures are maintained at hi...

  3. Modulation of urinary polycyclic aromatic hydrocarbon metabolites by enzyme polymorphisms in workers of the German Human Bitumen Study.

    Science.gov (United States)

    Rihs, Hans-Peter; Spickenheuer, Anne; Heinze, Evelyn; Pesch, Beate; Raulf-Heimsoth, Monika; Angerer, Jürgen; Brüning, Thomas

    2011-06-01

    Data concerning the influence of sequence variants of metabolizing enzymes on the effect modulation of current exposure to vapors and aerosols of bitumen in humans are limited. To assess the influence of 18 single-nucleotide polymorphisms (SNP) in genes coding for enzymes involved in polycyclic aromatic hydrocarbon (PAH) and amine metabolism regarding their impact on urinary markers 1-hydroxpyrene (1-OHP) and the sum of 1-, 2+9-, 3-, 4-hydroxyphenanthrene (OHPHE). Based on personal ambient monitoring data for bitumen emissions, 218 German workers exposed to vapors and aerosols of bitumen during a shift and 96 German roadside construction workers without exposure to bitumen but with similar working tasks were studied. SNP determination based on DNA aliquots isolated from blood samples by real-time PCR or direct sequencing. The impact of sequence variants on the urinary levels of 1-OHP and sum of OHPHE was estimated with mixed linear models, adjusted for age, creatinine, exposure, smoking, SNP, and time of measurement. In the mixed linear model, an increasing metabolite level of OHPHE was only slightly modulated by the CC variant of the cytochrome P450 SNP CYP1A1 3801T>C (rs4646903; P = 0.051). In contrast, GSTM1 carriers showed a significant (P= 0.046) and double-mutated variants of three NAT2-specific SNP (NAT2*341CC, P = 0.06; NAT2*481TT, P = 0.06; NAT2*803GG, P = 0.042) displayed a decreasing influence on OHPHE levels. None of the SNP studied showed a significant effect on 1-OHP. The modulating SNP effects on OHPHE in the adjusted model were less pronounced when compared with the effects observed in a recent study with 170 workers occupationally exposed to PAH in German industries. This may be due to the much lower PAH exposure in the Human Bitumen Study.

  4. Bitumen modifiers for reduced temperature asphalts: a comparative analysis between three polymeric and non-polymeric additives

    OpenAIRE

    Cuadri Vega, Antonio Abad; Carrera Páez, Virginia; Izquierdo Rodríguez, María Angeles; García Morales, Moisés; Navarro Domínguez, Francisco Javier

    2014-01-01

    This study presents three bitumen modifiers which may find successful application in the fabrication of binders for warm mix asphalt in the paving industry. In that sense, two non-polymeric additives, thiourea and thiourea dioxide, along with a reactive isocyanate-terminated prepolymer have been evaluated. Viscous flow and linear viscoelasticity tests, at 60 ºC, reveal bituminous modified binders which evolve towards highly viscous materials when subjected to ambient curing. However, at 135 º...

  5. The extraction of bitumen from western tar sands. Annual report, July 1990--July 1991

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1992-04-01

    Contents of this report include the following: executive summary; characterization of the native bitumen from the Whiterocks oil sand deposit; influence of carboxylic acid content on bitumen viscosity; water based oil sand separation technology; extraction of bitumen from western oil sands by an energy-efficient thermal method; large- diameter fluidized bed reactor studies; rotary kiln pyrolysis of oil sand; catalytic upgrading of bitumen and bitumen derived liquids; ebullieted bed hydrotreating and hydrocracking; super critical fluid extraction; bitumen upgrading; 232 references; Appendix A--Whiterocks tar sand deposit bibliography; Appendix B--Asphalt Ridge tar sand deposit bibliography; and Appendix C--University of Utah tar sands bibliography.

  6. Roofing waterproof Engineering%浅谈屋面防水工程

    Institute of Scientific and Technical Information of China (English)

    黄萍

    2012-01-01

      屋面防水工程是一个系统工程,若想解决防水的防渗问题,就要从工程的设计选材、施工及维修管理着手,综合管理,严格控制,以提高防水工程质量,增强防水效果,延长屋面防水使用寿命。%  roofing waterproof project is project of a system, to solve the water seepage problem, must from the engineering design material selection, construction and repair management to begin, comprehensive management, strict control, in order to improve the quality of waterproof engineering, reinforced waterproof effect, prolonging the service life of the roofing waterproof.

  7. Cohesion in crumb rubber modified bitumen

    Directory of Open Access Journals (Sweden)

    Páez Dueñas, A.

    2006-12-01

    Full Text Available This article reports on a study of crumb rubber-mediated improvement in bitumen cohesion, analyzed with the UCL method. UCL, a procedure developed to characterize bituminous binders, evaluates the cohesion obtained by adding a certain amount of bitumen or bituminous mastic to a standard mix aggregate. This method was chosen because it can be used to assess bitumen containing crumb rubber added by either the wet or the dry mix process. In the dry mix process crumb rubber is combined with the mix as if it were a fine aggregate; i.e., crumb rubber and binder are blended during mix manufacture, laying and compaction. In the wet mix process, the binder is blended with the crumb rubber prior to mixing with the aggregate; i.e., when added to the mix, it has already been modified. The effect of digesting this dry mixed material prior to use was also analyzed in the present study. A comparison of the dry (with and without digestion and wet mix processes showed the latter to be more effective, particularly when the crumb rubber was blended with the binder via microscopic dispersion.El objetivo de este artículo es estudiar la influencia del polvo de neumático en la mejora de la cohesión proporcionada por la adición del polvo de neumático al betún mediante el método UCL. El método UCL es un procedimiento desarrollado para caracterizar ligantes bituminosos, basado en la evaluación de la cohesión dada por una cantidad determinada de un betún o un mástico bituminoso a unos áridos de granulometría establecida (mezcla patrón. Se ha empleado este método porque permite valorar al mismo tiempo los dos procedimientos de incorporación del polvo de neumático al betún: vía seca y vía húmeda.El procedimiento seco se lleva a cabo añadiendo el polvo de neumático a la mezcla como si fuera un filler, de modo que el polvo de neumático y el ligante se mezclan durante la fabricación, extendido y compactación de la mezcla. En el procedimiento h

  8. Reducing CO2 emission from bitumen upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, John

    2011-07-15

    The treatment of sand oil can result in significant CO2 emission. Ceramatec Inc. has developed a technology to reduce the emission of CO2 during the upgrading of feedstocks bearing heteroatoms. This technology can be applied to kerogen derived oil (shale oil) and heavy oil as well as to bitumen from oil sands. Metallic sodium is used as the reducing and heteroatom scavenging agent. Hydrogen, methane or other hydrocarbons may be used to cap radicals formed in the process. But using methane can lead to lower material and capital costs, greater product yield, and lower CO2 emission. During the upgrading process, the aromatic constituents remain in the product, after treatment with sodium and removal of sulphur, nitrogen and metals. Aromatic saturation is not required with sodium, so less hydrogen is needed which leads to reduced CO2 emission. The reason is that CO2 is emitted in the steam methane reforming (SMR) process where hydrogen is produced. An example is introduced to demonstrate the reduction of CO2 emission from hydrogen production. Another advantage of the sodium/methane upgrading process is the incorporation of methane into the fuel. In addition, the total acid number, TAN, becomes negligible in the sodium upgrading processes. Ceramatec has also developed a process for the recovery of sodium from the sodium salts generated in the sodium/methane upgrading process.

  9. Optical and UV-Aging Properties of LDH-Modified Bitumen

    Directory of Open Access Journals (Sweden)

    Xing Liu

    2015-07-01

    Full Text Available Layered double hydroxides (LDHs are an ultraviolet-light (UV resistant material. In this study, LDHs were used to modify bitumen. The optical and UV aging properties of LDHs modified bitumen were investigated. Firstly, the thin films of bitumen, with and without LDHs, were prepared. By using the UV-Vis spectrophotometer, absorbance, reflectance, and transmittance of bituminous thin film were evaluated. The morphology of LDHs-modified bitumen was observed by using fluorescence microscopy (FM. Finally, the aging resistance of LDH-modified bitumen was investigated by using the UV-aging oven. Results indicated that the LDHs, especially with 5 wt % in the bitumen, can effectively absorb and reflect the UV light and improve the UV-aging resistance of bitumen. This implied that the addition of LDHs into bitumen had the potential to prolong the service life of asphalt pavement.

  10. Effect of Layered Double Hydroxides on Ultraviolet Aging Resistance of SBS Modifi ed Bitumen Membrane

    Institute of Scientific and Technical Information of China (English)

    XU Song; YU Jianying; XUE Lihui; SUN Yubin; XIE Dong

    2015-01-01

    Layered double hydroxides (LDHs)/styrene-butadiene-styrene (SBS) copolymer modified bitumen was prepared by melt blending. The effect of LDHs on the ultraviolet (UV) aging behavior of SBS modifi ed bitumen was investigated. The changes of chemical structures of modifi ed bitumen before and after UV aging were characterized by Fourier transform infrared spectroscopy (FTIR). The results show that LDHs obviously reduce the variation of softening point and low temperaturefl exibility of SBS modifi ed bitumen under different UV radiation intensities, which indicates that the UV aging resistance performance of SBS modifi ed bitumen is improved effectively by LDHs. Compared with SBS modifi ed bitumen, the changes of carbonyl, sulfoxide and butadienyl of LDHs/SBS modified bitumen decrease significantly after UV aging according to FTIR analysis, demonstrating that the oxidation and degradation reactions of SBS modifi ed bitumen were restrained effectively by adding LDHs.

  11. Effect of bitumen emulsion on setting, strength, soundness and moisture resistance of oxychloride cement

    Indian Academy of Sciences (India)

    M P S Chandrawat; T N Ojha; R N Yadav

    2001-06-01

    Addition of bitumen emulsion to the matrix has been found to improve strength and soundness of the product while decreasing the initial setting periods. Thus, bitumen emulsion as an admixture in magnesia cement is a moisture proofing and strengthening material.

  12. Air sampling and determination of vapours and aerosols of bitumen and polycyclic aromatic hydrocarbons in the Human Bitumen Study.

    Science.gov (United States)

    Breuer, Dietmar; Hahn, Jens-Uwe; Höber, Dieter; Emmel, Christoph; Musanke, Uwe; Rühl, Reinhold; Spickenheuer, Anne; Raulf-Heimsoth, Monika; Bramer, Rainer; Seidel, Albrecht; Schilling, Bernd; Heinze, Evelyn; Kendzia, Benjamin; Marczynski, Boleslaw; Welge, Peter; Angerer, Jürgen; Brüning, Thomas; Pesch, Beate

    2011-06-01

    The chemical complexity of emissions from bitumen applications is a challenge in the assessment of exposure. Personal sampling of vapours and aerosols of bitumen was organized in 320 bitumen-exposed workers and 69 non-exposed construction workers during 2001-2008. Area sampling was conducted at 44 construction sites. Area and personal sampling of vapours and aerosols of bitumen showed similar concentrations between 5 and 10 mg/m(3), while area sampling yielded higher concentrations above the former occupational exposure limit (OEL) of 10 mg/m(3). The median concentration of personal bitumen exposure was 3.46 mg/m(3) (inter-quartile range 1.80-5.90 mg/m(3)). Only few workers were exposed above the former OEL. The specificity of the method measuring C-H stretch vibration is limited. This accounts for a median background level of 0.20 mg/m³ in non-exposed workers which is likely due to ubiquitous aliphatic hydrocarbons. Further, area measurements of polycyclic aromatic hydrocarbons (PAHs) were taken at 25 construction sites. U.S. EPA PAHs were determined with GC/MS, with the result of a median concentration of 2.47 μg/m(3) at 15 mastic asphalt worksites associated with vapours and aerosols of bitumen, with a Spearman correlation coefficient of 0.45 (95% CI -0.13 to 0.78). PAH exposure at mastic-asphalt works was higher than at reference worksites (median 0.21 μg/m(3)), but about one order of magnitude lower compared to coke-oven works. For a comparison of concentrations of vapours and aerosols of bitumen and PAHs in asphalt works, differences in sampling and analytical methods must to be taken into account.

  13. The significance of petroleum bitumen in ancient Egyptian mummies

    Science.gov (United States)

    Clark, K. A.; Ikram, S.

    2016-01-01

    Mummification was practised in ancient Egypt for more than 3000 years, emerging from initial observations of buried bodies preserved by natural desiccation. The use of organic balms (and other funerary practices) was a later introduction necessitated by more humid burial environments, especially tombs. The dark colour of many mummies led to the assumption that petroleum bitumen (or natural asphalt) was ubiquitous in mummification; however, this has been questioned for more than 100 years. We test this by investigating 91 materials comprising balms, tissues and textiles from 39 mummies dating from ca 3200 BC to AD 395. Targeted petroleum bitumen biomarker (steranes and hopanes) analyses by gas chromatography-mass spectrometry selected ion monitoring (GC-MS SIM, m/z 217 and 191) showed no detectable bitumen use before the New Kingdom (ca 1550–1070 BC). However, bitumen was used in 50% of New Kingdom to Late Period mummies, rising to 87% of Ptolemaic/Roman Period mummies. Quantitative determinations using 14C analyses reveal that even at peak use balms were never more than 45% w/w bitumen. Critically, the dark colour of balms can be simulated by heating/ageing mixtures of fats, resins and beeswax known to be used in balms. The application of black/dark brown balms to bodies was deliberate after the New Kingdom reflecting changing funerary beliefs and shifts in religious ideology. This article is part of the themed issue ‘Quantitative mass spectrometry’. PMID:27644983

  14. Bitumen fume-induced gene expression profile in rat lung.

    Science.gov (United States)

    Gate, Laurent; Langlais, Cristina; Micillino, Jean-Claude; Nunge, Hervé; Bottin, Marie-Claire; Wrobel, Richard; Binet, Stéphane

    2006-08-15

    Exposure to bitumen fumes during paving and roofing activities may represent an occupational health risk. To date, most of the studies performed on the biological effect of asphalt fumes have been done with regard to their content in carcinogenic polycyclic aromatic hydrocarbons (PAH). In order to gain an additional insight into the mechanisms of action of bitumen fumes, we studied their pulmonary effects in rodents following inhalation using the microarray technology. Fisher 344 rats were exposed for 5 days, 6 h/day to bitumen fumes generated at road paving temperature (170 degrees C) using a nose-only exposition device. With the intention of studying the early transcriptional events induced by asphalt fumes, lung tissues were collected immediately following exposure and gene expression profiles in control and exposed rats were determined by using oligonucleotide microarrays. Data analysis revealed that genes involved in lung inflammatory response as well as genes associated with PAH metabolization and detoxification were highly expressed in bitumen-exposed animals. In addition, the expression of genes related to elastase activity and its inhibition which are associated with emphysema was also modulated. More interestingly genes coding for monoamine oxidases A and B involved in the metabolism of neurotransmitters and xenobiotics were downregulated in exposed rats. Altogether, these data give additional information concerning the bitumen fumes biological effects and would allow to better review the health effects of occupational asphalt fumes exposure.

  15. Microscale investigation of thin film surface ageing of bitumen.

    Science.gov (United States)

    Das, P K; Kringos, N; Birgisson, B; Wallqvist, V

    2014-05-01

    This paper investigates the mechanism of bitumen surface ageing, which was validated utilizing the atomic force microscopy and the differential scanning calorimetry. To validate the surface ageing, three different types of bitumen with different natural wax content were conditioned in four different modes: both ultraviolet and air, only ultraviolet, only air and without any exposure, for 15 and 30 days. From the atomic force microscopy investigation after 15 and 30 days of conditioning period, it was found that regardless the bitumen type, the percentage of microstructure on the surface reduced with the degree of exposure and time. Comparing all the four different exposures, it was observed that ultraviolet radiation caused more surface ageing than the oxidation. It was also found that the combined effect was not simply a summation or multiplication of the individual effects. The differential scanning calorimetry investigation showed that the amount of crystalline fractions in bitumen remain constant even after the systematic conditioning. Interestingly, during the cooling cycle, crystallization of wax molecules started earlier for the exposed specimens than the without exposed one. The analysis of the obtained results indicated that the ageing created a thin film upon the exposed surface, which acts as a barrier and creates difficulty for the wax induced microstructures to float up at the surface. From the differential scanning calorimetry analysis, it can be concluded that the ageing product induced impurities in the bitumen matrix, which acts as a promoter in the crystallization process.

  16. The significance of petroleum bitumen in ancient Egyptian mummies.

    Science.gov (United States)

    Clark, K A; Ikram, S; Evershed, R P

    2016-10-28

    Mummification was practised in ancient Egypt for more than 3000 years, emerging from initial observations of buried bodies preserved by natural desiccation. The use of organic balms (and other funerary practices) was a later introduction necessitated by more humid burial environments, especially tombs. The dark colour of many mummies led to the assumption that petroleum bitumen (or natural asphalt) was ubiquitous in mummification; however, this has been questioned for more than 100 years. We test this by investigating 91 materials comprising balms, tissues and textiles from 39 mummies dating from ca 3200 BC to AD 395. Targeted petroleum bitumen biomarker (steranes and hopanes) analyses by gas chromatography-mass spectrometry selected ion monitoring (GC-MS SIM, m/z 217 and 191) showed no detectable bitumen use before the New Kingdom (ca 1550-1070 BC). However, bitumen was used in 50% of New Kingdom to Late Period mummies, rising to 87% of Ptolemaic/Roman Period mummies. Quantitative determinations using (14)C analyses reveal that even at peak use balms were never more than 45% w/w bitumen. Critically, the dark colour of balms can be simulated by heating/ageing mixtures of fats, resins and beeswax known to be used in balms. The application of black/dark brown balms to bodies was deliberate after the New Kingdom reflecting changing funerary beliefs and shifts in religious ideology.This article is part of the themed issue 'Quantitative mass spectrometry'.

  17. Studies Concerning Heat-Resisting Additives for Bitumens

    Directory of Open Access Journals (Sweden)

    Livia Groll

    2008-01-01

    Full Text Available The improvement of causeway’s bitumen adhesiveness is becoming a current practice in our country, especially when is used acid (siliceous aggregate. One of the most important properties of bitumen is its adhesiveness to aggregate, and this property determine the using of bitumen in causeways area. Usually the adhesiveness is defined as the capacity of a binder to cover an aggregate without dispersing itself when touching the water or the traffic aggressions. Therefore, the adhesiveness additives are products that improve the adhesiveness of the bitumen to a certain aggregate. The used additives – ADETEN type (A01 and A03 have a high stocking stability, a low toxicity degree toward the amine, diamine, polyamine-based additives and are liquid products perfectly compatible with all bitumens and easy to use, in comparison to the paste or solid additives, which must be made liquid to be used. But a very important condition, which must be fulfilled by these promoters is the heat-resisting condition.

  18. Optical and UV-Aging Properties of LDH-Modified Bitumen

    OpenAIRE

    Xing Liu; Shaopeng Wu; Gang Liu; Liping Li

    2015-01-01

    Layered double hydroxides (LDHs) are an ultraviolet-light (UV) resistant material. In this study, LDHs were used to modify bitumen. The optical and UV aging properties of LDHs modified bitumen were investigated. Firstly, the thin films of bitumen, with and without LDHs, were prepared. By using the UV-Vis spectrophotometer, absorbance, reflectance, and transmittance of bituminous thin film were evaluated. The morphology of LDHs-modified bitumen was observed by using fluorescence microscopy (FM...

  19. Response of the microstructure of bitumen upon stress–damage initiation and recovery

    NARCIS (Netherlands)

    Fischer, H.R.; Dillingh, E.C.

    2014-01-01

    The occurrence of discrete cracking of bitumen and asphalt is difficult to observe/analyse mainly because of the viscous nature of the bitumen binder. Many techniques simply do not have the required resolution or analysis techniques do not get a good response from the highly dissipative bitumen. In

  20. Condensation of Water Vapor on Waterproof Breathable Fabrics

    Institute of Scientific and Technical Information of China (English)

    周小红; 王善元; 袁观洛

    2003-01-01

    Condensation occurs when the local vapor pressure rises above the saturation vapor pressure at the local temperature in theory. A new measuring apparatus were made to obtain temperature and relative humidity simultaneously for the purpose of investigating the mechanism of condensation occurred on the fabrics. The experiment conducted at the standard condition of temperature of 20°C and relative humidity of 65%. The result obtained from experiment showed that condensation could occur under the situation closed to saturation line as the temperature on fabric may be lower than dew point of water vapor in the measuring box depending on the experiment conducted at an ambient environment temperature of 20℃. The range of fabrics studied showed that PTFE laminated fabrics except nylon gingham PTFE laminated fabric facilitates the loss of water vapor and therefore prevent condensation. It is necessary to develop studies from a wide range of fabrics, especially breathable fabrics and under bad experiment condition in order to develop fabrics,which could eliminate condensation, or transport water vapor through the fabric while remaining waterproof.

  1. Waterproof, Ultrahigh Areal-Capacitance, Wearable Supercapacitor Fabrics.

    Science.gov (United States)

    Yang, Yu; Huang, Qiyao; Niu, Liyong; Wang, Dongrui; Yan, Casey; She, Yiyi; Zheng, Zijian

    2017-02-24

    High-performance supercapacitors (SCs) are promising energy storage devices to meet the pressing demand for future wearable applications. Because the surface area of a human body is limited to 2 m(2) , the key challenge in this field is how to realize a high areal capacitance for SCs, while achieving rapid charging, good capacitive retention, flexibility, and waterproofing. To address this challenge, low-cost materials are used including multiwall carbon nanotube (MWCNT), reduced graphene oxide (RGO), and metallic textiles to fabricate composite fabric electrodes, in which MWCNT and RGO are alternatively vacuum-filtrated directly onto Ni-coated cotton fabrics. The composite fabric electrodes display typical electrical double layer capacitor behavior, and reach an ultrahigh areal capacitance up to 6.2 F cm(-2) at a high areal current density of 20 mA cm(-2) . All-solid-state fabric-type SC devices made with the composite fabric electrodes and water-repellent treatment can reach record-breaking performance of 2.7 F cm(-2) at 20 mA cm(-2) at the first charge-discharge cycle, 3.2 F cm(-2) after 10 000 charge-discharge cycles, zero capacitive decay after 10 000 bending tests, and 10 h continuous underwater operation. The SC devices are easy to assemble into tandem structures and integrate into garments by simple sewing.

  2. Diesel and Jet Fuels from Bitumen-derived Middle Distillates

    Institute of Scientific and Technical Information of China (English)

    SokYui

    2004-01-01

    Narrow fractions of light gas oils obtained from various upgrading processes of Athabasca oilsands bitumen were investigated as diesel and jet fuels. The relationship among the boiling range, cetane number, smoke point, and other properties such as aromatics content, aniline point, and the sulfur and nitrogen content was also studied. The study reveals that when appropriate processes and distillation boiling ranges are selected, oilsands bitumen can produce diesel and jet fuels that meet stringent environmental regulations and future product specifications. New correlations to predict CN and smoke point were developed as a function of density, boiling ranges by simulated distillation, and mono- and total aromatics by supercriticaL fluid chromatography. The correlations apply to bitumen-derived middle distiLLates that have a wide range of boiling points.

  3. Cooee bitumen II: Stability of linear asphaltene nanoaggregates

    CERN Document Server

    Lemarchand, Claire A; Dyre, Jeppe C; Hansen, Jesper S

    2014-01-01

    Asphaltene and smaller aromatic molecules tend to form linear nanoaggregates in bitumen.Over the years bitumen undergoes chemical aging and during this process, the size of the nanoaggregate increases. This increase is associated with an increase in viscosity and brittleness of the bitumen, eventually leading to road deterioration. This paper focuses on understanding the mechanisms behind nanoaggregate size and stability. We used molecular dynamics simulations to quantify the probability of having a nanoaggregate of a given size in the stationary regime. To model this complicated behavior, we chose first to consider the simple case where only asphaltene molecules are counted in a nanoaggregate. We used a master equation approach and a related statistical mechanics model. The linear asphaltene nanoaggregates behave as a rigid linear chain. The most complicated case where all aromatic molecules are counted in a nanoaggregate is then discussed. The linear aggregates where all aromatic molecules are counted seem ...

  4. Calculations of the effect of boiling water on bitumen production

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J.; Kantzas, A. [Calgary Univ., AB (Canada). Dept. of Chemical and Petroleum Engineering]|[Calgary Univ., AB (Canada). Tomographic Imaging and Porous Media Laboratory; McGee, B. [E-T Energy Limited, Calgary, AB (Canada)

    2006-07-01

    Alberta's vast resources of heavy oil and bitumen are playing an increasing role as a main resource for crude oil. Thermal recovery methods for heavy oil and bitumen include steam injection and steam flooding in which thermal energy is given to the oil to reduce its viscosity and allow it to flow towards a production spot. A viable alternative to steam injection is the electromagnetic heating method for heavy oil and bitumen reservoirs. Electromagnetic heating transfers heat to heavy oil reservoirs based on electromagnetic energy and can be used in situations where steam injection may not work well. The process can also be used to preheat the reservoir before steam injection. This study examined the possible displacement mechanisms of such processes with particular focus on the physics of boiling water in porous media as a potential displacement agent for heavy oil and bitumen. It is very possible that water could vaporize while being electrically heated and the vaporized water could push more heavy oil or bitumen out of reservoir. As such, higher oil recovery could be expected due to water vaporization. The role of water vaporization during electrical heating process was examined and a methodology to estimate the magnitude of incremental oil recovery was developed based on simple conceptual models with numerical simulators and illustrative experiments. The primary contributors of this process appear to be a combination of drainage, imbibition, viscosity reduction and gas expansion. The study showed that the expansion of water into steam could very efficiently flush oil out of pore spaces. It was concluded that water vaporization inside the reservoir can be an additional driving force for heavy oil or bitumen production, and that this alternative to steam injection can offer energy savings for the recovery process. 10 refs., 4 tabs., 6 figs., 1 appendix.

  5. Investigation on the effects of gamma irradiation on bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Mello, M.S.; Braz, D.; Motta, L.M.G., E-mail: Laura@coc.ufrj.br [Universidade Federal Rio de Janeiro (COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Centro de Tecnologia; Leite, L.F.M., E-mail: leniml@petrobras.com.br [Centro de Pesquisa e Desenvolvimento Leopoldo Americo Miguez de Mello (CENPES/RJ), Rio de Janeiro (Brazil)

    2011-07-01

    Brazil has more than 218,000 km of asphalt-paved highways. Bitumen is a generic term for natural or manufactured black or dark-colored solid, semisolid, or viscous cementitious materials that are composed mainly of high molecular weight hydrocarbons (90-95%). Several papers have shown that the irradiation process has changed the mechanical behavior in some polymers. This work aims to analyze the behavior of Brazilian irradiated Bitumen (CAP 50-70). In order to provide a preliminary evaluation, bitumen samples and cylindrical specimens of asphaltic mixture were tested. The bitumen samples were irradiated 0.1 to 300 kGy, and asphaltic mixture specimen was irradiated 5 to 300 kGy. The cylindrical asphaltic mixture specimen of 10.16 cm diameter used in this study was molded using an asphalt-aggregate mixture. The specimens were irradiated in LIN/UFRJ/Brazil using a Gamma cell Co{sup 60} source of gamma irradiation with an applied dose rate of 29.7 Gy/min. After irradiated, the bitumen samples were subjected to penetration test and the asphaltic mixtures were subjected to indirect tensile strength test (diametral compression) for determination of the resilient modulus, according to ASTM method D 4123. The results of these experiments for each dose were compared with the control (nonirradiated). As expected, the penetration results showed that the ratio (irradiated/non-irradiated) decreases with increasing of irradiation dose for bitumen samples and the resilient modulus results showed that the ratio (irradiated/non-irradiated) increases with increasing of irradiation dose for asphaltic mixture. (author)

  6. Non-Newtonian behavior and molecular structure of Cooee bitumen under shear flow

    DEFF Research Database (Denmark)

    Lemarchand, Claire; Bailey, Nicholas; Daivis, Peter

    2015-01-01

    The rheology and molecular structure of a model bitumen (Cooee bitumen) under shear are investigated in the non-Newtonian regime using non-equilibrium molecular dynamics simulations. The shear viscosity, normal stress differences, and pressure of the bitumen mixture are computed at different shear...... rates and different temperatures. The model bitumen is shown to be a shear-thinning fluid at all temperatures. In addition, the Cooee model is able to reproduce experimental results showing the formation of nanoaggregates composed of stacks of flat aromatic molecules in bitumen. These nanoaggregates...

  7. Research on Viscoelasticity of Modiifed Bitumen Containing LDHs Anti-UV Aging Agent

    Institute of Scientific and Technical Information of China (English)

    LIU Xing; WU Shaopeng; LIU Gang; MA Shankui

    2015-01-01

    We applied LDHs to modify the bitumen by melt blending, and studied the viscoelasticity of LDHs modiifed bitumen by means of dynamic shear rheometer (DSR). The creep test was used to evaluate the viscoelastic behavior. The experimental results indicated that, due to the addition of the LDHs, the viscoelastic properties of modiifed bitumen were superior to those of pristine bitumen. Therefore, the LDHs would be an alternative to modiifers used in the bitumen to improve the UV-aging resistance during the service of asphalt pavement.

  8. Natural and artificial ageing for evaluating waterproofing treatments for marble

    Directory of Open Access Journals (Sweden)

    Mecchi, Anna María

    1992-06-01

    Full Text Available Exposure of samples to artificial ageing is commonly carried out to test the durability of natural and artificial stones and the effectiveness of products used for their conservation. Correlations between artificial and natural ageing, however, are not always well understood mainly because the former can only try to simulate, in a faster but simplified way, the effects of the many causes interacting ín natural environments. In the present study, marble samples from Carrara and Proconnesion quarries, were treated with four waterproofing products (or mixtures of products and exposed to artificial ageing while an analogous set was exposed outdoor, in the town center of Rome for two years. Several physical parameters were measured before and after the ageing and the experimental results enabled us to compare the effects produced by the different types of ageing and to estimate the correlations between them. As for the durability of the tested waterproofing products, the two systems are in good agreement even if two years of natural ageing resulted to be slightly more severe than 33 days of exposure to saline fog, to UV radiation and to wetting-drying cycles.

    La exposición de muestras a envejecimiento artificial se lleva a cabo comúnmente para chequear la duración de las piedras naturales y artificiales y la eficacia de los productos usados para su cuidado. Las correlaciones entre el envejecimiento artificial y natural, sin embargo, no siempre se entienden bien principalmente porque el envejecimiento trata de simular, de una manera rápida pero sencilla, los efectos de las muchas causas que actúan en el ambiente natural. En este estudio, muestras de mármol de las canteras de Carrara y Proconnesio, han sido tratadas con cuatro productos o mezclas de productos, para su impermeabilización y expuestos a envejecimiento artificial. Mientras, un juego análogo de piedras se exponía al exterior en el centro de la ciudad de Roma, por un

  9. Brewster angle microscopy of Langmuir films of athabasca bitumens, n-C5 asphaltenes, and SAGD bitumen during pressure-area hysteresis.

    Science.gov (United States)

    Hua, Yujuan; Angle, Chandra W

    2013-01-08

    Bitumen films formed on water surfaces have negative consequences, both environmental and economic. CanmetENERGY has placed considerable research emphasis on understanding the structures of the bitumen films on water as a necessary step before optimization of bitumen extraction. The detailed structures of the adsorbed molecules and, especially, the role of asphaltene molecules at the interfaces are still under scrutiny and debate. In the present study, we compared bitumen and asphaltene films as they were compressed and expanded under various surface pressures in order to achieve a clearer understanding of bitumen film structures. We used a customized NIMA Langmuir trough interfaced to a Brewster angle microscope (BAM) and CCD camera (Nanofilm_ep3BAM, Accurion, previously Nanofilm Gmbh) to study images of bitumen films at the air/water interface. The bitumen film appeared uniform with high reflectivity at a surface pressure of 18 mN·m(-1) and exhibited a coarse pebblelike interface with reduced reflectivity in the liquid condensed (LC) phase at higher pressures (18-35 mN·m(-1)). During the first cycle of compression asphaltene films showed well-defined phase transitions and a uniformly smooth interface in the LC phase between 9 and 35 mN·m(-1). However, folding or buckling occurred at surface pressures from 35 to 44 mN·m(-1). On expansion, asphaltene films appeared to break into islands. The hysteresis of the pressure-area isotherm was much larger for asphaltenes than for bitumen. In both compression and expansion cycles, BAM images for bitumen films appeared to be more reproducible than those of the asphaltene films at the same surface pressures. Films for low-°API SAGD bitumen were almost identical to those for surface-mined bitumen. Films formed from partially deasphalted surface-mined bitumens showed higher compressibility and lower rigidity than the original bitumen. The BAM images illustrated significant differences between the partially deasphalted and

  10. Bitumen recovery from oil-sand extraction tailings: Part One: Bench-scale tests

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Y. H.; Mikhail, M. W.; Salama, A. I. A. [Canada Centre for Mineral and Energy Technology Western Research Centre, Devon, AB (Canada); Burns, B. [Suncor Energy Inc., Calgary, AB (Canada)

    1999-09-01

    Residual bitumen from extraction plant tailings were recovered in bench-scale tests using conventional froth flotation, flotation columns, air-sparged hydrocyclones, and various combinations of these techniques. A flowsheet combining the use of mechanically agitated flotation cells with a stationary separator was developed. Results indicate that this process is effective in recovering bitumen from tailings with low bitumen content. Investigation of the flotation kinetics in a batch flotation cell provided information on the relationship between retention and froth quality. The effect of operating parameters on bitumen flotation and the dispersion of bubbles and bitumen was also examined. Results suggests that properly increasing the turbulence energy level in flotation units will improve the recovery of bitumen by flotation. It is believed that that this is due to the interaction between bitumen droplets and bubbles and the increase in of liquid/air interfacial area. 3 refs., 13 figs.

  11. Modificación físico-química de betunes asfálticos mediante agentes reactivos

    OpenAIRE

    Cuadri Vega, Antonio Abad

    2016-01-01

    Bitumen, a by-product from crude oil distillation, has long been used in numerous engineering applications that range from the construction of road pavements to waterproof membranes for the roofing industry. On account of its properties (impermeability, adhesiveness, elasticity, ductility, etc.), bitumen is the most suitable material to be used as a binder of mineral aggregates for paving industry, and consequently, roads are mainly constructed using a composite mixture of bitumen (~ 5 wt.%) ...

  12. Ageing by UV radiation of an elastomer modified bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Virginie Mouillet; Fabienne Farcas; Stanislas Besson [CETE Mediterranee Pole d' activite, Aix-en-Provence (France). Laboratoire Regional des Ponts et Chaussees d' Aix-en-Provence

    2008-09-15

    Laboratory methods to simulate the short- and long-term ageing occurring during the service life of pure and polymer modified bitumens in a pavement are standardized but none of them takes into account the influence of UV radiations. If the impact of thermal ageing on the degradation of SBS elastomers in bitumens has been extensively studied, there is not study dealing with the photo-oxidation of these copolymers in a bituminous matrix. So, the aim of our study was to investigate, by FTIR spectrometry and SEC chromatography, whether the architecture of elastomers (linear or radial) might have any influence on their ageing by UV radiation in a bituminous matrix. The results show that the elastomers oxidation kinetic, unlike the disappearance kinetic of trans-butadiene double bond, does not depend on their architecture. But, when putted into the same base bitumen, the two copolymers show exactly the same oxidation kinetic and the same decreasing kinetic of trans-butadiene double bond. So, this study has revealed that inside the bituminous matrix, on the one hand, the elastomers architecture does not influence on its degradation when submitted to UV radiation and, on the other hand, there is a 'protection' of the elastomers by the studied bitumen towards UV radiation. 46 refs., 13 figs., 2 tabs.

  13. The formation of explosive compounds in bitumen/nitrate mixtures

    Science.gov (United States)

    Okada; Nur; Fujii

    1999-11-15

    Ignition of various bitumen/nitrate mixtures was examined using a new method of thermal analysis, developed in the present study, in order to determine the self-ignition temperatures (SIT) of the sample materials. The effects on the SIT of transition elements, particularly silver, and the heating rates were examined. The same bitumen/nitrate mixtures were prepared by mixing bitumen, NaNO(3), Ni(NO(3))(2) and either AgNO(3) or AgI. The sample heating rates were in the range from 0.5 to 4.0 degrees C/min. In the present work, SIT was found to be independent on the heating rate when AgI is added, while SIT was found to depend on the heating rate when AgNO(3) was added. The activation energy E(a) for the ignition of bitumen/nitrate mixtures has been calculated to be 30 kJ/mol. The suspected initiator of the ignition is thought to be silver fulminates or related compounds.

  14. Dynamics and structure of water-bitumen mixtures

    DEFF Research Database (Denmark)

    Lemarchand, Claire; Greenfield, Michael L.; Hansen, Jesper Schmidt

    2016-01-01

    Systems of Cooee bitumen and water up to 4% mass are studied by molecular dynamics simulations. The cohesive energy density of the system is shown to decrease with an increasing water content. This decrease is due mainly to an increase in the interaction energy which is not high enough to counter...

  15. Self-healing bitumen by microcapsules containing rejuvenator

    NARCIS (Netherlands)

    Su, J.F.; Qiu, J.; Schlangen, H.E.J.G.

    2013-01-01

    Preservation and renovation bitumen of pavement is a big problem for the whole world. Traditionally, application rejuvenators is the only one method that can restore the original properties of the pavements. However, some puzzles still restrict its successful usage. Microencapsulation is a promising

  16. Application and Analysis of Emulsified Bitumen Slurry Seal in Maintenance of Highway%乳化沥青稀浆封层在公路养护中的应用分析

    Institute of Scientific and Technical Information of China (English)

    张楠

    2014-01-01

    Abrasion and deterioration problem often happens in the use of a period of time for most of the asphalt pavement due to long-term suffers from the vehicle load. The applied technology of emulsified bitumen slurry seal can make the pavement has a high wear-resistant performance, skid resista-nce performance and waterproof performance, in order to achieve the purpose of maintaining. This article analyses the application of emulsified bitumen slurry seal in maintenance of highway.%由于长期承受车辆的载荷作用,大部分沥青路面在使用一段时间后会出现路面的磨损、老化问题。沥青路面应用乳化沥青稀浆封层,可以使沥青路面具有耐磨、抗滑、防水等能力,以达到养护的目的。本文分析了乳化沥青稀浆封层在公路养护中的应用。

  17. SBS改性沥青防水卷材防水构造%Waterproofing Construction of SBS Modified Bitumen Roll-roofing

    Institute of Scientific and Technical Information of China (English)

    朱克娟

    2007-01-01

    文章在10多个城市近300幢屋面防水工程的实地调查,以及分析影响防水工程质量的诸多因素基础上,提出了从合理设计、正确选材、精心施工、维护保养等方面综合处理解决屋面防水工程质量的途径.

  18. Synthesis and characterization of organic intercalated layered double hydroxides and their application in bitumen modification

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Song [State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070 (China); Yu, Jianying, E-mail: jyyu@whut.edu.cn [State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070 (China); Sun, Yubin [Center for Materials Research and Analysis, Wuhan University of Technology, Wuhan 430070 (China); Wu, Shaopeng [State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070 (China)

    2015-02-15

    Organic layered double hydroxides (LDHs) intercalated by sodium dodecylbenzenesulfonate (SDBS) were prepared by anion-exchange method and applied to modify bitumen aiming at improving ageing resistance of bitumen. The organic LDHs (SDBS–LDHs) were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and Ultraviolet and visible (UV–vis) spectrophotometry. The effect of SDBS–LDHs and LDHs on physical and anti-ageing properties of bitumen was evaluated by means of conventional and rheological test. The results of XRD, FTIR and SEM show that SDBS is successfully intercalated into interlayer of LDHs, and the UV–vis reflectance and absorbance curves illustrate that intercalation of SDBS enhances the UV shielding effect of LDHs. The addition of SDBS–LDHs or LDHs has little influence on physical properties of bitumen because SDBS–LDHs and LDHs are physically mixed in bitumen. Compared with pristine bitumen after TFOT and UV irradiation ageing, the introduction of SDBS–LDHs and LDHs significantly improves thermal- and photo-oxidative ageing resistance of bitumen. Notably, bitumen with SDBS–LDHs exhibits better anti-ageing performance than that with LDHs, implying more effective modification of SDBS-LDHs which is due to the enhanced UV protective ability and compatibility with bitumen of SDBS–LDHs. - Highlights: • XRD, FTIR and SEM were used to confirm the successful intercalation. • SDBS–LDHs show superior UV protective ability. • SDBS–LDHs improved the anti-ageing properties of bitumen.

  19. The extraction of bitumen from western oil sands: Volume 2. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1997-11-26

    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains reports on nine of these projects, references, and a bibliography. 351 refs., 192 figs., 65 tabs.

  20. The extraction of bitumen from western oil sands. Quarterly report, July--September, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1993-11-01

    This report cites task number followed by a brief statement of each task and the action taken this quarter. The tasks are: NEPA environmental information statement; coupled fluidized-bed bitumen recovery and coked sand combustion; water-based recovery of bitumen; rotary kiln process for recovery of bitumen and combustion of coke sand; recovery of bitumen from oil sands using fluidized bed reactors and combustion of spent sands in transport reactors; recovery of bitumen from oil sand and upgrading of bitumen by solvent extraction; catalytic and thermal upgrading of bitumens and bitumen-derived liquids; evaluation of Utah`s major oil sand deposits for the production of asphalt, high energy jet fuels, and other specialty products; development of mathematical models for bitumen recovery and processing; completion of the cost estimation study of the pilot plant restoration; development studies of equipment for three-product gravity separation of bitumen and sand; development studies of disposal of sand by conveying or pumping of high solids concentration sand-water slurries; and environmental studies of the North Salt Lake pilot plant rehabilitation and eventual operation and those environmental problems associated with eventual commercial products.

  1. The extraction of bitumen from western oil sands: Volume 1. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1997-11-26

    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains an executive summary and reports for five of these projects. 137 figs., 49 tabs.

  2. Effects of thermal-oxidative aging on rheological properties of montmorillonite modified bitumen

    Institute of Scientific and Technical Information of China (English)

    冯鹏程; 余剑英; 王骁; 陶园园

    2008-01-01

    Organic montmorillonite(OMMT) modified bitumen nanocomposites was prepared by melt blending.The effects of thin-film oven test(TFOT) and pressure ageing vessel(PAV) on rheological properties of pristine bitumen and OMMT modified bitumen were investigated by dynamic shear rheometer(DSR).The results show that complex modulus(G*) increases,phase angle(δ) decreases and rutting factor(G*/sin δ) is enhanced for the pristine bitumen after TFOT,whereas G*,δ and G*/sin δ of OMMT modified bitumen have a little change before and after TFOT.Besides,the pristine bitumen exhibits a large increase of G* and a great decrease of δ after PAV aging.However,the changes in G* and δ of OMMT modified bitumen are small before and after PAV.Compared with the pristine bitumen,OMMT modified bitumen presents a lower fatigue factor(G*sin δ) after PAV.As a consequence,resistance to thermal-oxidative aging of bitumen is remarkably improved due to the introduction of OMMT.

  3. Biological effects and toxicity of diluted bitumen and its constituents in freshwater systems.

    Science.gov (United States)

    Dew, William A; Hontela, Alice; Rood, Stewart B; Pyle, Greg G

    2015-11-01

    Approximately 50 billion cubic meters of bitumen resides within the oil sands region of Alberta, Canada. To facilitate the transport of bitumen from where it is extracted to where it is processed, the bitumen is diluted with natural gas condensate ('dilbit'), synthetic crude from hydrocracking bitumen ('synbit'), or a mixture of both ('dilsynbit'). A primary consideration for the effects of diluted bitumen products on freshwater organisms and ecosystems is whether it will float on the water surface or sink and interact with the stream or lake sediments. Evidence from a spill near Kalamazoo, MI, in 2010 and laboratory testing demonstrate that the nature of the spill and weathering of the dilbit, synbit or dilsynbit prior to and during contact with water will dictate whether the product floats or sinks. Subsequent toxicological data on the effects of dilbit and other diluted bitumen products on freshwater organisms and ecosystems are scarce. However, the current literature indicates that dilbit or bitumen can have significant effects on a wide variety of toxicological endpoints. This review synthesizes the currently available literature concerning the fate and effects of dilbit and synbit spilled into freshwater, and the effects of bitumen and bitumen products on aquatic organisms and ecosystems. Dilbit is likely to provide ecological impacts that are similar to and extend from those that follow from exposure to lighter crude oil, but the prospect of bitumen settling after binding to suspended sediments elevates the risk for benthic impacts in streams and lakes.

  4. Survey of cochlear implant user satisfaction with the Neptune™ waterproof sound processor

    Directory of Open Access Journals (Sweden)

    Jeroen J. Briaire

    2016-04-01

    Full Text Available A multi-center self-assessment survey was conducted to evaluate patient satisfaction with the Advanced Bionics Neptune™ waterproof sound processor used with the AquaMic™ totally submersible microphone. Subjective satisfaction with the different Neptune™ wearing options, comfort, ease of use, sound quality and use of the processor in a range of active and water related situations were assessed for 23 adults and 73 children, using an online and paper based questionnaire. Upgraded subjects compared their previous processor to the Neptune™. The Neptune™ was most popular for use in general sports and in the pool. Subjects were satisfied with the sound quality of the sound processor outside and under water and following submersion. Seventyeight percent of subjects rated waterproofness as being very useful and 83% of the newly implanted subjects selected waterproofness as one of the reasons why they chose the Neptune™ processor. Providing a waterproof sound processor is considered by cochlear implant recipients to be useful and important and is a factor in their processor choice. Subjects reported that they were satisfied with the Neptune™ sound quality, ease of use and different wearing options.

  5. The Construction of Roof Waterproof%浅谈屋面防水施工

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    There are great influences of roof waterproof qua-lity on the service life of construction, the poor roof waterproof wil seriously affect the daily life of the people. The roof sho-uld meet the durable, waterproof, thermal insulation, heat ins-ulation, fire and resist the bad influence of various functional requirements. The service life of roofing construction quality is good or bad, is directly related to the building. According to the author's working practice, this paper discusses the const-ruction technology of waterproof roof in detail.%  屋面防水的质量对建筑工程的使用寿命有很大的影响,粗劣的屋面防水必然会严重影响人们的日常生活。屋面应满足坚固耐久、防水、保温、隔热、防火和抵御各种不良影响的功能要求。屋面施工质量的好坏、优劣直接关系到建筑物的使用寿命。本文根据笔者的工作实践,对屋面防水施工技术进行了详细的阐述。

  6. Mechanistic study on demulsification of water-in-diluted bitumen emulsions by ethylcellulose.

    Science.gov (United States)

    Feng, Xianhua; Mussone, Paolo; Gao, Song; Wang, Shengqun; Wu, Shiau-Yin; Masliyah, Jacob H; Xu, Zhenghe

    2010-03-02

    In our previous study, ethylcellulose (EC), an effective, nontoxic, and biodegradable natural polymer, was found effective in dewatering water-in-diluted bitumen emulsions. In this study, the demulsification mechanism of water-in-diluted bitumen emulsions by EC is investigated. In situ experiments using a micropipet apparatus provided direct evidence on both flocculation and coalescence of water droplets in diluted bitumen by EC. The addition of EC was found to decrease naphtha-diluted bitumen-water interfacial tension significantly. At the molecular level, AFM imaging revealed disruption of the continuous interfacial films formed from surface-active components of bitumen by EC. Our study clearly indicates that the demulsification by EC is through both flocculation and coalescence of water droplets, attained by competitive adsorption of EC at the oil-water interface and disruption of the original protective interfacial films formed from the surface-active components of bitumen.

  7. Four-component united-atom model of bitumen

    DEFF Research Database (Denmark)

    Hansen, Jesper Schmidt; Lemarchand, Claire; Nielsen, Erik

    2013-01-01

    We propose a four-component united-atom molecular model of bitumen. The model includes realistic chemical constituents and introduces a coarse graining level that suppresses the highest frequency modes. Molecular dynamics simulations of the model are carried out using graphic-processor-units based...... software in time spans in order of microseconds, which enables the study of slow relaxation processes characterizing bitumen. This paper also presents results of the model dynamics as expressed through the mean-square displacement, the stress autocorrelation function, and rotational relaxation...... the stress autocorrelation function, the shear viscosity and shear modulus are evaluated, showing a viscous response at frequencies below 100 MHz. The model predictions of viscosity and diffusivities are compared to experimental data, giving reasonable agreement. The model shows that the asphaltene, resin...

  8. Four-component united-atom model of bitumen

    CERN Document Server

    Hansen, Jesper S; Nielsen, Erik; Dyre, Jeppe C; Schrøder, Thomas B

    2013-01-01

    We propose a four-component molecular model of bitumen. The model includes realistic chemical constituents and introduces a coarse-graining level that suppresses the highest frequency modes. Molecular dynamics simulations of the model are being carried out using Graphic-Processor-Units based software in time spans in order of microseconds, and this enables the study of slow relaxation processes characterizing bitumen. This paper focuses on the high-temperature dynamics as expressed through the mean-square displacement, the stress autocorrelation function, and rotational relaxation. The diffusivity of the individual molecules changes little as a function of temperature and reveals distinct dynamical time scales as a result of the different constituents in the system. Different time scales are also observed for the rotational relaxation. The stress autocorrelation function features a slow non-exponential decay for all temperatures studied. From the stress autocorrelation function, the shear viscosity and shear ...

  9. Characterization of Ultra Fine Solids(BS) in Athabasca Bitumen

    Institute of Scientific and Technical Information of China (English)

    LI Zai-Feng(李再峰); Judy KUNG; TU Yun(涂云); Luba S.KOTLYAR; Keng H.CHUNG

    2004-01-01

    The ultra fine (<200 nm) inorganic solids (BS) were separated from bitumen which was washed by toluene and centrifugated at 2000 rpm.The result of PAS FTIR and image of TEM showed that the structure of BS particles was smiliar to that of kaolinite clay.On the surface of BS,both toluene insoluble organic matter and structural OH group are detected at the same time.The surface characteristics imparted a bi-wettable nature to the BS.As a result,the BS is able to stabilize fine water emulsion in the bitumen phase.The organic matter associated with BS is a possible factor of the fouling on catalyst and equipment.

  10. Building Blocks Incorporating Waste Materials Bound with Bitumen

    Directory of Open Access Journals (Sweden)

    Thanaya I.N.A.

    2010-01-01

    Full Text Available This paper described an investigation and evaluation which was carried out in the United Kingdom-UK, on the properties of masonry building block materials that incorporate waste materials, namely: steel slag, crushed glass, coal fly ash, rice husk ash (RHA, incinerator sewage sludge ash (ISSA, municipal solid waste incinerator bottom ash (MSWIBA or shortened as IBA, bound with bitumen or asphalt, named as Bitublock. The binder used was 50 pen bitumen. The properties of the blocks evaluated were: compressive strength, density, porosity, initial rate of suction (IRS, creep, and volume stability. It was found that the Bitublock performance can be improved by optimizing porosity and curing regime. Compaction level of 2 MPa and curing regime of 200°C for 24 hours gave satisfactory bitublock performances that at least comparable to concrete block found in the United Kingdom (UK. The Volume stability (expansion of the unit is affected by environment relative humidity.

  11. Thermal recovery of bitumen from carbonate reservoirs: formation damage aspects

    Energy Technology Data Exchange (ETDEWEB)

    Thimm, H.F. [Thimm Petroleum Technologies Inc. (Canada)

    2011-07-01

    In Alberta, about a third of bitumen resources are located in carbonate reservoirs but none of it is considered as a reserve by the Alberta Energy Resources Conservation Board (ERCB). In fact no pilot has been successful in recovering bitumen from carbonate reservoirs due to formation damage problems. Carbonate rock is chemically active at the high temperatures reached in thermal recovery processes, carbon dioxide is generated and carbonate minerals are precipitated. The aim of this paper is to find methods to control the phenomenon. Kinetic and thermodynamic controls were used. Results showed that formation damage is due to aqueous carbon dioxide attacking the reservoir rock. They found that a reduction of the partial pressure of carbon dioxide could inhibit the initial dissolution of rock material by reducing the concentration of aqueous carbon dioxide. A method to overcome the formation damage problem was found and a co-injection of gas and steam process was developed to apply it.

  12. Three-Year Field Test Summary for Experimental Modified Bitumen Roofing at Fort Polk, Louisiana

    Science.gov (United States)

    1992-12-01

    forcement and factory-applied granule surfacing (area A), Membrane B-a hot-mopped SBS (styrene butadiene styrene) modified bitumen with polyester...membrane C) were in excellent condition. No visible changes were noted. However, the hot-mopped SBS modified bitumen (membrane B) had several problems...all of which seemed to be caused by the membrane plys slipping down the roof slope. Slippage of hot-mopped SBS modified bitumen membrane systems has

  13. Investigation of microstructures and ultraviolet aging properties of organo-montmorillonite/SBS modified bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Henglong [Key Laboratory of Silicate Materials Science and Engineering of Ministry of Education, Wuhan University of Technology, Wuhan (China); Yu Jianying, E-mail: jyyu@whut.edu.cn [Key Laboratory of Silicate Materials Science and Engineering of Ministry of Education, Wuhan University of Technology, Wuhan (China); Wang Huacai; Xue Lihui [Center for Materials Research and Analysis, Wuhan University of Technology, Wuhan 430070 (China)

    2011-10-03

    Highlights: {yields} Microstructures and ultraviolet (UV) aging properties of organo-montmorillonite (OMMT)/Styrene-butadiene-styrene(SBS) modified bitumen were investigated by X-ray diffraction, Fourier transform infrared spectroscopy, atomic force microscopy and physical properties tests. {yields} OMMT/SBS modified bitumen forms an intercalated structure. {yields} The phase contrast between the dispersed domains and the matrix is inverted in SBS modified bitumen, which is decreased with the introduction of OMMT. {yields} The UV aging resistance of SBS modified bitumen can be improved obviously with the addition of OMMT. - Abstract: Organo-montmorillonite(OMMT)/Styrene-butadiene-styrene(SBS) modified bitumen nanocomposites were prepared by melt blending. The microstructures of OMMT/SBS modified bitumen were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and atomic force microscopy (AFM), respectively. The effect of OMMT on ultraviolet (UV) aging properties of SBS modified bitumen was investigated. FTIR and XRD analyses indicate that the OMMT/SBS modified bitumen forms an intercalated structure. It is observed that the phase contrast between the dispersed domains and the matrix is inverted in SBS modified bitumen, which is decreased with the introduction of OMMT according to AFM analysis. As a result of UV aging, both viscosity aging index and softening point increment of OMMT/SBS modified bitumen decrease significantly. There is a single phase trend in the morphology of the bitumen after aging, which is accelerated by the existence of SBS. However, these changes can be effectively prevented under the influence of OMMT, indicating the good UV aging resistance of OMMT/SBS modified bitumen.

  14. Rheological Behaviour of Ethylene-Vinyl-Acetate [EVA] Modified Road Bitumen

    OpenAIRE

    DEKHLI, Samy; AIT MOKHTAR, Kkedidja; Hammoum, Ferhat; SI BACHIR, Djaffar

    2015-01-01

    In this present study, the effects of Ethylene-Vinyl-Acetate (EVA) on the conventional characteristics and rheological properties of pure bitumen were investigated. The modified bitumen (PMB) has been prepared in laboratory by mixing bitumen with copolymer EVA. Three different contents of polymer have been tested to evaluate the modification. The basic properties of the PMBs have been determined by using conventional test methods. The results indicated that polymer modification improved the c...

  15. Characteristics of volatile organic compounds emission profiles from hot road bitumens.

    Science.gov (United States)

    Boczkaj, Grzegorz; Przyjazny, Andrzej; Kamiński, Marian

    2014-07-01

    A procedure for the investigation and comparison of volatile organic compounds (VOCs) emission profiles to the atmosphere from road bitumens with various degrees of oxidation is proposed. The procedure makes use of headspace analysis and gas chromatography with universal as well as selective detection, including gas chromatography-mass spectrometry (GC-MS). The studies revealed that so-called vacuum residue, which is the main component of the charge, contains variable VOC concentrations, from trace to relatively high ones, depending on the extent of thermal cracking in the boiler of the vacuum distillation column. The VOC content in the oxidation product, so-called oxidized paving bitumen, is similarly varied. There are major differences in VOC emission profiles between vacuum residue and oxidized bitumens undergoing thermal cracking. The VOC content in oxidized bitumens, which did not undergo thermal cracking, increases with the degree of oxidation of bitumens. The studies revealed that the total VOC content increases from about 120 ppm for the raw vacuum residue to about 1900 ppm for so-called bitumen 35/50. The amount of volatile sulfur compounds (VSCs) in the volatile fraction of fumes of oxidized bitumens increases with the degree of oxidation of bitumen and constitutes from 0.34% to 3.66% (w/w). The contribution of volatile nitrogen compounds (VNCs) to total VOC content remains constant for the investigated types of bitumens (from 0.16 to 0.28% (w/w) of total VOCs). The results of these studies can also find use during the selection of appropriate bitumen additives to minimize their malodorousness. The obtained data append the existing knowledge on VOC emission from oxidized bitumens. They should be included in reports on the environmental impact of facilities in which hot bitumen binders are used.

  16. Parameters which Affect the Stiffness of Bitumen and Bituminous Hot Mixes

    OpenAIRE

    2001-01-01

    This paper deals with bitumen and bituminous mixes, using suitable mathematical models that take into account the parameters affecting their elastic and plastic stiffnesses. These parameters are stress level and acting time, penetration index, softening time and temperature. Viscosity and the total acting time of the load affect the elastic stiffness of bitumen. The elastic stiffness of bitumen and the voluminous concentration of the aggregate influence the elastic stiffness of th...

  17. Membrane and Flashing Condition Indexes for Modified Bitumen Roofs: Inspection and Distress Manual

    Science.gov (United States)

    2010-03-01

    ER D C/ CE R L TR -1 0 -5 Membrane and Flashing Condition Indexes for Modified Bitumen Roofs Inspection and Distress Manual David M...ERDC/CERL TR-10-5 March 2010 Membrane and Flashing Condition Indexes for Modified Bitumen Roofs Inspection and Distress Manual David M...Compliance” ERDC/CERL TR-10-5 ii Abstract: The U.S. Army is currently responsible for maintaining mil- lions of square feet of modified bitumen roofing

  18. Does a more refined assessment of exposure to bitumen fume and confounders alter risk estimates from a nested case-control study of lung cancer among European asphalt workers?

    DEFF Research Database (Denmark)

    Agostini, Michela; Ferro, Gilles; Burstyn, Igor

    2013-01-01

    To investigate whether a refined assessment of exposure to bitumen fume among workers in the European asphalt industry within a nested case-control study resulted in a different interpretation pertaining to risk of lung cancer mortality compared with the cohort study....

  19. Effect of aging on the morphology of bitumen by atomic force microscopy.

    Science.gov (United States)

    Zhang, H L; Yu, J Y; Feng, Z G; Xue, L H; Wu, S P

    2012-04-01

    Effect of aging on the morphology of bitumen was investigated. Two bitumens were aged according to the thin film oven test (TFOT), pressure aging vessel (PAV) test and ultraviolet (UV) radiation, respectively. The morphology of the binders before and after aging was characterized by atomic force microscopy. The physical properties and chemical compositions of the binders were also measured. The results showed that aging affected the bitumen morphology significantly. Aging increased the overall surface stiffness of the bitumen and made the bitumen surface more solid-like. The extent of these changes was dependent on aging conditions. TFOT decreased the contrast between the dispersed domains and the matrix, which contributed to the single-phase trend of the binders. The effect of PAV aging on morphology of the binders was dependent on the base bitumen. In one case, it further accelerated the single-phase trend of bitumen in comparison with that after TFOT. In the other case, it caused the phase separation of bitumen. In both cases, PAV aging increased the surface roughness of the binders obviously. As a result of UV aging, the contrast between the matrix phase and dispersed phase was increased due to the difference in sensitivity to UV radiation of the bitumen molecules, which caused or further promoted the phase separation in the binders. Regardless of the aging procedure carried out, a strong correlation was observed between the changes in morphology and physical properties as well as chemical compositions of the binders before and after aging.

  20. Common ground : bitumen and gas producers come together to find gas-over-bitumen solutions

    Energy Technology Data Exchange (ETDEWEB)

    Ross, E.

    2005-08-01

    The gas-over-bitumen issue has meant that hundreds of natural gas wells remain closed while regulatory hearings and research activities continue. The Alberta Energy and Utilities Board should soon reach a final decision on the status of gas wells considered to be a threat to thermal extraction of underlying oil sands. This article discussed collaborative efforts by oil and gas companies to resolve these issues, including the use of fluid injection technology, low pressure Steam-Assisted Gravity Drainage (SAGD) and artificial lift. The objective of the Gas Reinjection and Production Experiment (GRIPE) is to reinject gas to displace natural gas being produced. The pilot project, conducted by Paramount Resources Ltd., consists of 2 injector wells, 4 producers and 12 observation wells that measure gas pressure in the reservoir. The project also includes a 2 stage compressor modified to handle flue gas. According to reservoir simulations, Paramount should be able to recover between 50 to 60 per cent of the remaining gas in place. Results from the pilot suggest that the technique could result in more than half the currently shut-in pools being re-opened. It was suggested that gas-by-gas displacement may result in higher recovery rates because there is usually more remaining gas in place. It was noted that EnCana Corporation has also been repressurizing a depleted natural gas pool by injecting compressed air rather than flue gas. Various other projects were reviewed, including the use of electric submersible pumps, low pressure SAGD and new SAGD well pair configurations. It was concluded that the artificial lift and low pressure SAGD technical sub-committee have now filed 10 applications for funding under the Alberta Energy Department's Innovative Energy Technology Program.

  1. Reclaim and Evaluation of SBS Modified Bitumen%S BS改性沥青的回收与评价

    Institute of Scientific and Technical Information of China (English)

    马翔; 倪富健; 李强

    2014-01-01

    通过残留物、老化对回收 SBS 改性沥青性能的影响分析,研究了相应的改进措施,并对旧沥青的回收及再生效果进行了评价。研究表明:少量的矿粉和三氯乙烯均能明显影响回收沥青的性能,研究提出的改进措施能有效减少残留物的含量和回收过程中的老化,保证回收沥青的真实性能;老化使沥青明显变硬,常用的再生剂对 SBS 改性沥青的改善效果有限,过多掺加量将减低沥青的高温性能。%Based on the analysis of residues,aging effects on the performance of reclaimed SBS modified bitumen,corresponding improvement measures was studied,and effectiveness of reclaimed and recycling of aging asphalt effects were evaluated.The test results indicate that a small amount of filler and trichloroethylene can significantly affect the properties of the reclaimed asphalt,and improvement meas-ures proposed in this study can effectively decrease the content of the residues and aging during recove-ring process,ensured the actual performance of reclaimed bitumen.Aging makes the asphalt harden,and the improved effectiveness of common rejuvenator was limited to the properties of the reclaimed bitumen. Adding too much rejuvenator will degrade high-temperature performance of the reclaimed bitumen.

  2. Suggestions on building roof waterproofing construction suggestions%建筑屋面防水施工建议

    Institute of Scientific and Technical Information of China (English)

    张海强

    2015-01-01

    从设计、材料、排水、管道四方面分析了建筑屋面出现积水、渗水以及漏水的原因,并深入探讨了建筑屋面防水施工的措施,分析了不同屋面结构防水施工的要求,以选择合理的防水技术,达到良好的防水效果。%The paper analyzes building roof ponding,seepaging and leakaging causes from four aspects of design,materials,drainage and pipe-line,explores building roof waterproofing measures,and analyzes different roof structure waterproofing construction demands,with a view to select rational waterproofing techniques and achieve good waterproofing effect as well.

  3. Shear resistance properties of TPS modified bitumen binders and asphalt mixtures

    Institute of Scientific and Technical Information of China (English)

    曹庭维; 吴少鹏; 刘聪慧; 张涛

    2008-01-01

    Shear resistance properties of the virgin bitumen and modified bitumen binders with Tafpack Super(TPS) modifier and SBS modified bitumen were discussed.Dynamic shear rheometer(DSR) was used to measure the laboratory creep data for these binders over a wide range of constant shear stresses at 20 ℃ to characterize the shear creep behaviors of all kinds of asphalt binders,and the rutting test system was used to investigate the permanent deformation of porous asphalt mixtures using the above bitumen binders for a fixed compressive stress.The shear strain rate and shear creep modulus were used to characterize the shear creep behavior of the TPS modified bitumen,and the rutting test results were used to show the consistency of porous asphalt mixtures with the bitumen binders.Results indicate that a distinction of shear creep strain can be made among different contents of TPS modified bitumen at the same stress level,where the shear creep strain-time response curve of the SBS modified bitumen binder is between the curves of the 8% TPS and 12% TPS modified bitumen binders.The shear strain rate and the shear creep modulus of the TPS modified bitumen binders are obtained to compare with those of the SBS modified bitumen binder which results in the same trend as the shear creep strain-time response curve.Permanent deformation results of all the porous asphalt mixtures from the rutting test show reasonable agreement with the findings of the shear strain rates and shear creep modulus over the range of shear stress levels.

  4. Impact of oxidation process on polycyclic aromatic hydrocarbon (PAH) content in bitumen.

    Science.gov (United States)

    Bolliet, Christophe; Juery, Catherine; Thiebaut, Benoit

    2013-01-01

    This study investigated the impact of the oxidation process on the concentration of polycyclic aromatic hydrocarbons (PAH) in blown bitumen and identified some key contributing parameters. The U.S. Environmental Protection Agency's PAH list was used for this study. PAHs are considered a good toxicological marker, and measurement of PAHs in bitumen can be performed easily. The results of PAH content in blown bitumen and the corresponding feedstock was determined from the limit of detection up to 120 mg/kg for 24 samples. Compared to PAH levels in coal tar pitch, PAH levels in bitumen are very low. Measurements were performed by three laboratories using different methods to allow robust conclusions. The results highlight the difficulties in measuring PAHs in bitumen with accuracy for values below 30 mg/kg; therefore the discussion is based on summary statistics by adding concentrations of PAHs with common ring sizes. Incorporation of flux oil in the feed of the blowing bitumen unit tends to increase PAH content in feed stock and in blown bitumen, particularly the 4- to 6-ring PAHs, which are the most carcinogenic as identified by an animal skin painting test. The amount of PAH content from blown bitumen with flux oil can be at least three times higher than the amount in blown bitumen without flux oil, depending on the quality and quantity of the flux oil used. This study shows that the blowing process does not produce PAHs in bitumen. Conversely, it appears to reduce them in the final product. Close to 10 to 30% of PAHs are probably stripped from the liquid phase of bitumen during the blowing operation.

  5. A Management and Economic Survey in Implementation of Blown Bitumen Production Using Acidic Sludge Recycling (A Case Study

    Directory of Open Access Journals (Sweden)

    Malek Hassanpour

    2016-10-01

    Full Text Available Many units of blown bitumen and used-motor oil reprocessing industries have been currently implemented and many modern technologies and additives are being developed and requested continuously. The objective of current study was a management and economic survey in implementation of blown bitumen production using acidic sludge recycling as a new additive that encompasses financial views and other success factors so carried out using a Kanji’s Business Excellence Model, empirical equations, professional experiences and observations during establishment an industry. Using acidic sludge had promoted the product quality in parallel with the TQM parameters. Current study had shown the indices values such as value-added percent, profit, annual income, breakeven point, value-added, output value, data value, variable cost of commodity unit and production costs were found to be about 44%, $ 5308605.14, $ 5252251.65, $ 1183.67 , $ 5401935.47, $ 6748064.5, $ 12150000, $ 140.93 and $ 6897748.4 respectively. The breakeven point about 2.46%, time of return on investment about 0.07, BES about 800.2 (for KBEM and 806.77 (for EFQM was represented a systematic practice so that thrift outlays and boost the strength and weakness points to improve.

  6. Characterization of Bitumen Micro-Mechanical Behaviors Using AFM, Phase Dynamics Theory and MD Simulation

    Directory of Open Access Journals (Sweden)

    Yue Hou

    2017-02-01

    Full Text Available Fundamental understanding of micro-mechanical behaviors in bitumen, including phase separation, micro-friction, micro-abrasion, etc., can help the pavement engineers better understand the bitumen mechanical performances at macroscale. Recent researches show that the microstructure evolution in bitumen will directly affect its surface structure and micro-mechanical performance. In this study, the bitumen microstructure and micro-mechanical behaviors are studied using Atomic Force Microscopy (AFM experiments, Phase Dynamics Theory and Molecular Dynamics (MD Simulation. The AFM experiment results show that different phase-structure will occur at the surface of the bitumen samples under certain thermodynamic conditions at microscale. The phenomenon can be explained using the phase dynamics theory, where the effects of stability parameter and temperature on bitumen microstructure and micro-mechanical behavior are studied combined with MD Simulation. Simulation results show that the saturates phase, in contrast to the naphthene aromatics phase, plays a major role in bitumen micro-mechanical behavior. A high stress zone occurs at the interface between the saturates phase and the naphthene aromatics phase, which may form discontinuities that further affect the bitumen frictional performance.

  7. Adhesion of single polyelectrolyte molecules on silica, mica, and bitumen surfaces.

    Science.gov (United States)

    Long, Jun; Xu, Zhenghe; Masliyah, Jacob H

    2006-02-14

    In a recent study (Energy Fuels 2005, 19, 936), a partially hydrolyzed polyacrylamide (HPAM) was used as a process aid to recover bitumen from oil sand ores. It was found that HPAM addition at the bitumen extraction step not only improved bitumen recovery but also enhanced fine solids settling in the tailings stream. To understand the role of HPAM, single-molecule force spectroscopy was employed for the first time to measure the desorption/adhesion forces of single HPAM molecules on silica, mica, and bitumen surfaces using an atomic force microscope (AFM). Silicon wafers with an oxidized surface layer and newly cleaved mica were used, respectively, to represent sand grains and clays in oil sands. The force measurements were carried out in deionized water and in commercial plant process water under equilibrium conditions. The desorption/adhesion forces of HPAM obtained on mica, silica, and bitumen surfaces were approximately 200, 40, and 80 pN in deionized water and approximately 100, 50, and 40 pN in the plant process water, respectively. The measured adhesion forces together with the zeta potential values of these surfaces indicate that the polymer would preferentially adsorb onto clay surfaces rather than onto bitumen surfaces. It is the selective adsorption of HPAM that benefits both bitumen recovery and tailings settling when the polymer was added directly to the bitumen extraction process at an appropriate dosage.

  8. Influence of styrene-butadiene-styrene polymer modification on bitumen viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Lu, X.; Isacsson, U. [Royal Institute of Technology, Stockholm (Sweden). Division of Highway Engineering

    1997-11-01

    It is reported that the effects of polymer content/structure and bitumen type on viscosity characteristics of styrene-butadiene-styrene (SBS) polymer modified bitumens were investigated. The study indicated that SBS polymers were not inert additives and increases in kinematic and dynamic viscosities of the modified bitumens were not directly proportional to polymer content; a marked viscosity increase was observed when the polymer content increased from 3 to 6% by weight of the blend. Modification with a sufficiently high polymer content also increased the degree of non-Newtonian behaviour of the bitumens. The base bitumens and modified bitumens containing 3% SBS were observed to be essentially shear rate independent, while those containing 6 to 9% SBS displayed shear-thinning behaviour. Compared to the modified bitumens with linear SBS, the modified bitumens with branched SBS demonstrated a higher degree of shear-thinning behaviour. These effects were dependent on ranges of shear rate and temperature. The increased degree of non-Newtonian behaviour was observed to influence the correlations between kinematic and dynamic viscosities. 12 refs., 7 figs., 2 tabs.

  9. High and Low Temperature Properties of FT-Paraffin-Modified Bitumen

    Directory of Open Access Journals (Sweden)

    Hassan Fazaeli

    2012-01-01

    Full Text Available This paper presents the results of an experimental research on the effects of “Fischer Tropsch-Paraffin” (Sasobit content on physical and rheological properties of Sasobit modified bitumen at various operational temperatures. For this purpose, bitumen with a Performance Grade (PG of 58–22 is selected as the base and later it is modified with 1, 2, 2.5, 3, and 4 weight percent of FT-Paraffin (Sasobit. The performance of modified bitumen at high, intermediate, and low temperatures is evaluated based on Strategic Highway Research Program (SHRP Superpave tests. Results of the study show that FT-paraffin improves the performance of bitumen at high temperatures in addition to increasing the resistance of mixture against permanent deformation. Despite the advantages of FT-paraffin on bitumen performance at high temperatures, it does not show a considerable influence on the intermediate and low temperature performance of bitumen. The effect of FT-paraffin content on the viscosity of modified bitumen is also investigated using Brookfield Viscometer Apparatus. Results show that increasing the additive content lowers the viscosity of modified bitumen. This in return can reduce the mixing and compaction temperature of asphalt mixtures.

  10. Quantification of bitumen particles in aerosol and soil samples using HP-GPC

    DEFF Research Database (Denmark)

    Fauser, Patrik; Tjell, Jens Christian; Mosbæk, Hans;

    2000-01-01

    A method for identifying and quantifying bitumen particles, generated from the wear of roadway asphalts, in aerosol and soil samples has been developed. Bitumen is found to be the only contributor to airborne particles containing organic molecules with molecular weights larger than 2000 g pr. mol...

  11. Assessment of DNA damage in WBCs of workers occupationally exposed to fumes and aerosols of bitumen.

    Science.gov (United States)

    Marczynski, Boleslaw; Raulf-Heimsoth, Monika; Preuss, Ralf; Kappler, Martin; Schott, Klaus; Pesch, Beate; Zoubek, Gerd; Hahn, Jens-Uwe; Mensing, Thomas; Angerer, Jürgen; Käfferlein, Heiko U; Brüning, Thomas

    2006-04-01

    We conducted a cross-shift study with 66 bitumen-exposed mastic asphalt workers and 49 construction workers without exposure to bitumen. Exposure was assessed using personal monitoring of airborne bitumen exposure, urinary 1-hydroxypyrene (1-OHP), and the sum of 1-, 2 + 9-,3-,4-hydroxyphenanthrene (OHPH). Genotoxic effects in WBC were determined with nonspecific DNA adduct levels of 8-oxo-7,8-dihydro-2'-deoxyguanosine (8-oxodGuo) and the formation of DNA strand breaks and alkali-labile sites. Concentration of fumes and aerosols of bitumen correlated significantly with the concentrations of 1-OHP and OHPH after shift (r(s) = 0.27; P = 0.03 and r(s) = 0.55; P Bitumen-exposed workers had more DNA strand breaks than the reference group (P bitumen nor with urinary metabolite concentrations. Significantly more DNA adducts were observed after shift not only in bitumen-exposed workers but also in the reference group. Only low-exposed workers had significantly elevated 8-oxodGuo adduct levels before as well as after shift (P = 0.0002 and P = 0.02, respectively). Our results show that exposure to fumes and aerosols of bitumen may contribute to an increased DNA damage assessed with strand breaks.

  12. On the investigation of the bulk microstructure of bitumen - Introducing two new techniques

    NARCIS (Netherlands)

    Fischer, H.R.; Dillingh, E.C.

    2014-01-01

    Bitumen, the residue of oil distillation and applied e.g. as binder in asphalt pavements displays a rich microstructure at the bitumen surface-to-air surface with several clearly distinguishable phases. However, uncertainty still remains whether this micro-structure is just present at free surfaces

  13. Impact of maltene and asphaltene fraction on mechanical behavior and microstructure of bitumen

    NARCIS (Netherlands)

    Hofko, B.; Eberhardsteiner, L.; Fussl, J.; Grothe, H.; Handle, F.; Hospodka, M.; Grossegger, D.; Nahar, S.N.; Schmets, A.J.M.; Scarpas, A.

    2015-01-01

    As a widely accepted concept, bitumen consists of four fractions that can be distinguished by their polarity. Highly polar asphaltene micelles are dispersed in a viscous phase of saturates, aromatics and resins (maltene phase). Different concentrations of asphaltenes in the bitumen result in a range

  14. Heavy Oil and Natural Bitumen Resources in Geological Basins of the World

    Science.gov (United States)

    Meyer, Richard F.; Attanasi, E.D.; Freeman, P.A.

    2007-01-01

    Heavy oil and natural bitumen are oils set apart by their high viscosity (resistance to flow) and high density (low API gravity). These attributes reflect the invariable presence of up to 50 weight percent asphaltenes, very high molecular weight hydrocarbon molecules incorporating many heteroatoms in their lattices. Almost all heavy oil and natural bitumen are alteration products of conventional oil. Total resources of heavy oil in known accumulations are 3,396 billion barrels of original oil in place, of which 30 billion barrels are included as prospective additional oil. The total natural bitumen resource in known accumulations amounts to 5,505 billion barrels of oil originally in place, which includes 993 billion barrels as prospective additional oil. This resource is distributed in 192 basins containing heavy oil and 89 basins with natural bitumen. Of the nine basic Klemme basin types, some with subdivisions, the most prolific by far for known heavy oil and natural bitumen volumes are continental multicyclic basins, either basins on the craton margin or closed basins along convergent plate margins. The former includes 47 percent of the natural bitumen, the latter 47 percent of the heavy oil and 46 percent of the natural bitumen. Little if any heavy oil occurs in fore-arc basins, and natural bitumen does not occur in either fore-arc or delta basins.

  15. TECHNOLOGY AND EFFICIENT USE OF PEAT ASH IN MASTICS FOR WATERPROOFING OF BRIDGE AND TUNNEL STRUCTURES

    OpenAIRE

    G. D. Lyahevich; A. G. Lyahevich; Agababa Rangraz Alireza Najib; A. A. Dalidovskaya

    2015-01-01

    A prospective method for protection of  bridges and tunnels against aggressive water action is surface waterproofing on the basis of an organo-mineral binder. Its structural strength can be increased by introduction of particles which are similar to the size of  asphaltenes and an elasticity of disperse medium has been increased due to introduction of polymers. These theoretical suppositions point out the possibility for simultaneous provision of flexibility at low temperatures and high heat ...

  16. The Feasibility of Waterproof Microcapsule System for Bacteria-Based Self-Healing Cementitious Material

    OpenAIRE

    2016-01-01

    In this study, a waterproof material was used to fabricate microcapsule by interfacial curing reaction to encapsulate an alkaliphilic spore-forming bacterium. The technical feasibility of encapsulated spores and the influence of three kinds of curing agent on the calcium precipitation activity (CPA) of the bacterium were studied. Furthermore, micromorphology of microcapsules was observed by Scanning Electron Microscopy (SEM). Afterwards, the thermal stability and thermolysis temperature were ...

  17. Waterproofing in Arabidopsis: Following phenolics and lipids in situ by Confocal Raman Microscopy

    Science.gov (United States)

    Prats Mateu, Batirtze; Hauser, Marie-Theres; Heredia, Antonio; Gierlinger, Notburga

    2016-02-01

    Waterproofing of the aerial organs of plants imposed a big evolutionary step during the colonization of the terrestrial environment. The main plant polymers responsible of water repelling are lipids and lignin, which play also important roles in the protection against biotic/abiotic stresses, regulation of flux of gases and solutes and mechanical stability against negative pressure, among others. While the lipids, non-polymerized cuticular waxes together with the polymerized cutin, protect the outer surface, lignin is confined to the secondary cell wall within mechanical important tissues. In the present work a micro cross-section of the stem of Arabidopsis thaliana was used to track in situ the distribution of these non-carbohydrate polymers by Confocal Raman Microscopy. Raman hyperspectral imaging gives a molecular fingerprint of the native waterproofing tissues and cells with diffraction limited spatial resolution (~300 nm) at relatively high speed and without any tedious sample preparation. Lipids and lignified tissues as well as their effect on water content was directly visualized by integrating the 1299 cm-1, 1600 cm-1 and 3400 cm-1 band, respectively. For detailed insights into compositional changes of these polymers vertex component analysis was performed on selected sample positions. Changes have been elucidated in the composition of lignin within the lignified tissues and between interfascicular fibers and xylem vessels. Hydrophobising changes were revealed from the epidermal layer to the cuticle as well as a change in the aromatic composition within the cuticle of trichomes. To verify Raman signatures of different waterproofing polymers additionally Raman spectra of the cuticle and cutin monomer from tomato (Solanum lycopersicum) as well as aromatic model polymers (milled wood lignin and dehydrogenation polymer of coniferyl alcohol) and phenolic acids were acquired. Keywords: Arabidopsis thaliana, lignin, cutin, wax, Raman, cuticle, waterproofing

  18. Waterproofing in Arabidopsis: Following phenolics and lipids in situ by Confocal Raman Microscopy

    Directory of Open Access Journals (Sweden)

    Batirtze ePrats Mateu

    2016-02-01

    Full Text Available Waterproofing of the aerial organs of plants imposed a big evolutionary step during the colonization of the terrestrial environment. The main plant polymers responsible of water repelling are lipids and lignin, which play also important roles in the protection against biotic/abiotic stresses, regulation of flux of gases and solutes and mechanical stability against negative pressure, among others. While the lipids, non-polymerized cuticular waxes together with the polymerized cutin, protect the outer surface, lignin is confined to the secondary cell wall within mechanical important tissues. In the present work a micro cross-section of the stem of Arabidopsis thaliana was used to track in situ the distribution of these non-carbohydrate polymers by Confocal Raman Microscopy. Raman hyperspectral imaging gives a molecular fingerprint of the native waterproofing tissues and cells with diffraction limited spatial resolution (~300 nm at relatively high speed and without any tedious sample preparation. Lipids and lignified tissues as well as their effect on water content was directly visualized by integrating the 1299 cm-1, 1600 cm-1 and 3400 cm-1 band, respectively. For detailed insights into compositional changes of these polymers vertex component analysis was performed on selected sample positions. Changes have been elucidated in the composition of lignin within the lignified tissues and between interfascicular fibers and xylem vessels. Hydrophobising changes were revealed from the epidermal layer to the cuticle as well as a change in the aromatic composition within the cuticle of trichomes. To verify Raman signatures of different waterproofing polymers additionally Raman spectra of the cuticle and cutin monomer from tomato (Solanum lycopersicum as well as aromatic model polymers (milled wood lignin and dehydrogenation polymer of coniferyl alcohol and phenolic acids were acquired. Keywords: Arabidopsis thaliana, lignin, cutin, wax, Raman

  19. Sustainability Life Cycle Cost Analysis of Roof Waterproofing Methods Considering LCCO2

    Directory of Open Access Journals (Sweden)

    Sangyong Kim

    2013-12-01

    Full Text Available In a construction project, selection of an appropriate method in the planning/design stage is very important for ensuring effective project implementation and success. Many companies have adopted the life cycle cost (LCC method, one of the methods for analyzing economic efficiency, for appropriate decision-making in the basic/detailed design stage by estimating overall costs and expenses generated over the entire project. This paper presents an LCC method for calculating the LCC of CO2 (LCCO2, based on materials committed during the lifecycle of a structure for each roof waterproofing method and adding this cost to the LCC for comparative analysis. Thus, this technique presents the LCC that includes the cost of CO2 emission. The results show that in terms of initial construction cost, asphalt waterproofing had the highest CO2 emission cost, followed by sheet waterproofing. LCCO2 did not greatly influence the initial construction cost and maintenance cost, as it is relatively smaller than the LCC. However, when the number of durable years was changed, the LCC showed some changes.

  20. Durability assessment of concrete bridge deck considering waterproof membrane and epoxy-coated reinforcement

    Directory of Open Access Journals (Sweden)

    Petr Konečný

    2016-03-01

    Full Text Available The effect of waterproof membrane and steel reinforcement protection on the concrete bridge deck is modeled. The attention is paid to the durability prediction related to steel reinforcement corrosion initiation based on the chloride penetration. Thus 2-D finite element chloride ingress model is applied. The transient finite element model serves to solve Fick's second diffusion law using the computer tool compatible with the Matlab environment. The model focuses on the transport of chloride ions through a reinforced concrete bridge deck with and without the effect of waterproof membrane and on an estimate of the concentration of chlorides at the reinforcement level or in places with damage to the epoxide coating of the reinforcement. The model allows the incorporation of damage to the waterproof insulation under the asphalt coating. The time to chloride induced onset of corrosion is predicted and results are compared. The effect of water proof membrane reinforcement protection strategy typical for Central Europe and epoxy-coating protection widely used in North-Western United States is evaluated.

  1. Rheological effects of commercial waxes and polyphosphoric acid in bitumen 160/220 low temperature performance

    Energy Technology Data Exchange (ETDEWEB)

    Ylva Edwards; Yuksel Tasdemir; Ulf Isacsson [Royal Institute of Technology (KTH), Stockholm (Sweden). Division of Highway Engineering

    2006-05-15

    Effects of adding three commercial waxes and a polyphosphoric acid to three bitumens of 160/220 penetration grade were studied using different types of laboratory equipment, such as dynamic shear rheometer (DSR), bending beam rheometer (BBR), differential scanning calorimeter (DSC), force ductilometer (FD) as well as equipment for determining conventional parameters like penetration, softening point and Fraass breaking point. The paper deals with low-temperature effects, which could influence the thermal cracking resistance of asphalt concrete pavements. The results show that magnitude and type of effect on bitumen rheology depend on the bitumen itself as well as type and amount of additive used. Bitumen composition was found to be of decisive importance. Adding polyethylene wax or polyphosphoric acid, especially to non-waxy 160/220-penetration grade bitumen, showed positive effects on the rheological behaviour at low temperatures. 24 refs., 6 figs., 5 tabs.

  2. Levels and determinants of exposure to vapours and aerosols of bitumen.

    Science.gov (United States)

    Spickenheuer, Anne; Rühl, Reinhold; Höber, Dieter; Raulf-Heimsoth, Monika; Marczynski, Boleslaw; Welge, Peter; Breuer, Dietmar; Gabriel, Stefan; Musanke, Uwe; Rode, Peter; Heinze, Evelyn; Kendzia, Benjamin; Bramer, Rainer; Knecht, Udo; Hahn, Jens-Uwe; Brüning, Thomas; Pesch, Beate

    2011-06-01

    Bitumen (referred to as asphalt in the United States) is a widely used construction material, and emissions from hot bitumen applications have been a long-standing health concern. One objective of the Human Bitumen Study was to identify potential determinants of the exposure to bitumen. The study population analysed comprised 259 male mastic asphalt workers recruited between 2003 and 2008. Personal air sampling in the workers' breathing zone was carried out during the shift to measure exposure to vapours and aerosols of bitumen. The majority of workers were engaged in building construction, where exposure levels were lower than in tunnels but higher than at road construction sites. At building construction sites, exposure levels were influenced by the room size, the processing temperature of the mastic asphalt and the job task. The results show that protective measures should include a reduction in the processing temperature.

  3. Reservoir design of a shallow LP-SAGD project for in situ extraction of Athabasca bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Palmgren, C.; Walker, I. [Alberta Oilsands (Canada); Carlson, M.; Uwiera, M. [Inc RPS Energy (Canada); Torlak, M. [Siemens AG (Canada)

    2011-07-01

    Alberta Oilsands Inc. is developing a project 8 km southeast of Fort McMurray, Alberta, Canada. The Clearwater project aims to extract bitumen from a shallow bitumen reservoir through in situ production; the aim of this paper is to present this project and to evaluate the commercial viability of combining different technologies such as steam assisted gravity drainage (SAGD), solvent co-injection and electro-magnetic heating. Alberta Oilsands will put 6 SAGD well pairs and infill wells in place to effectively recover the bitumen. Reservoir simulations were carried out using reservoir models based on geological, petrophysical and geostatical work. Results showed that the combination of SAGD, solvent co-injection and electro-magnetic heating can increase bitumen production while reducing the steam oil ratio. This paper provides information on the Phase I reservoir design of the Clearwater project; steam injection and bitumen recovery are expected to start in 2012.

  4. Foamed bitumen stabilization of MSWI bottom ash; Skumbitumenstabilisering av bottenaska fraan avfallsfoerbraenning

    Energy Technology Data Exchange (ETDEWEB)

    Bendz, David [Swedish Geotechnical Inst., Linkoeping (Sweden); Jacobsson, Torbjoern [Swedish National Road and Transport Research Inst., Linkoeping (Sweden); Svensson, Mikael; Flyhammar, Peter [Lund Inst. of Technology (Sweden). Dept. of Water Resources Engineering

    2006-04-15

    Foamed bitumen is a mixture of bitumen, water and air. Bitumen that is heated to 175 deg C expands about 10-30 times compared to its original volume when injecting small amounts of water and air under high pressure. By exposing a granulate material to foamed bitumen the particles will be covered with a bitumen film. This will give the particles hydrophobic properties, as well as a smaller specific surface. At the same time the mechanical properties of the material are expected to improve due to the cohesive properties of the bitumen covered particles. The treatment can be made both offsite and in situ. The objective of this project was to investigate the possibility to treat municipal solid waste bottom ash with foamed bitumen to achieve improved leaching and mechanical properties. The following leaching tests have been performed on the original bottom ash and two foamed bitumen treated ashes with 2 and 4.5 % bitumen, respectively: one-stage batch test (EN 12457-4), pH-static test (prEN 14997), column test (prEN 14405) and monolithic leaching test (NEN 7345). In addition, the specific surface and intra-particle porosity were determined by BET N2 adsorption experiments on selected fractions of bottom ash. The results showed that the specific surface decreased with more than 50 % and manifested itself in a lower buffer capacity at both low and high pH. For most elements no significant difference in leaching behavior where found when comparing the results from the leaching tests for the three materials at their own pH. This is thought to be due to that sufficient specific area available for leaching exists to reach equilibrium despite the foam bitumen treatment. The results from the one-stage batch test show a minor reduction in leaching for Cl{sup -}, S, SO{sub 4}{sup -2}, NO{sub 3}{sup -}, Sb, and Ca for the foamed bitumen treated ashes. The results from the column test of the foamed bitumen stabilized ashes showed an increased leaching of some elements, especially

  5. Base Course Modification through Stabilization using Cement and Bitumen

    Directory of Open Access Journals (Sweden)

    S. M. Marandi

    2009-01-01

    Full Text Available The main objectives of this research was to analyze the use of combined cement and bitumen emulsion in base course stabilization in details and examine its replacement with conventional pavement in regions with low quality materials and limited construction period. To conduct the objectives, the research divided into three phases. Phase I involved the optimization of cement and bitumen emulsion. In this case, a series of Indirect Tensile Strength (ITS, Unconfined Compressive Strength (UCS and Marshal Tests carried out. In the second phase, various alternative roadway sections examined for minimizing the pavement thickness and increasing the bearing capacity and finally in third phase, a Falling Weight Deflectometer (FWD machine used to examine the pavement bearing capacity for three sections of the roadway. It was found that, the optimum values to eliminate the creation of shrinkage cracks in the whole project and minimize the execution period and construction costs were 3% for both binders in stabilization and its replacement with conventional pavement method (i.e., stabilized layer with conventional sub-base and base layers. Also, FWD results showed that, the bearing capacity of the constructed pavement using stabilization method is far beyond the predicted values in pavement design. Furthermore, it was found that, with high inflation rate and political situation in the region, base stabilized method decreased the final roadway construction costs in compare with conventional pavement method.

  6. Trace metals in heavy crude oils and tar sand bitumens

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, J.G.

    1990-11-28

    Fe, Ni, and V are considered trace impurities in heavy crude oils and tar sand bitumens. In order to understand the importance of these metals, we have examined several properties: (1) bulk metals levels, (2) distribution in separated fractions, (3) size behavior in feeds and during processing, (4) speciation as a function of size, and (5) correlations with rheological properties. Some of the results of these studies show: (1) V and Ni have roughly bimodal size distributions, (2) groupings were seen based on location, size distribution, and Ni/V ratio of the sample, (3) Fe profiles are distinctively different, having a unimodal distribution with a maximum at relatively large molecular size, (4) Fe concentrations in the tar sand bitumens suggest possible fines solubilization in some cases, (5) SARA separated fractions show possible correlations of metals with asphaltene properties suggesting secondary and tertiary structure interactions, and (6) ICP-MS examination for soluble ultra-trace metal impurities show the possibility of unexpected elements such as U, Th, Mo, and others at concentrations in the ppB to ppM range. 39 refs., 13 figs., 5 tabs.

  7. 水基提取技术用于油砂分离的研究进展%Research progress in water-based bitumen extraction from oil sands

    Institute of Scientific and Technical Information of China (English)

    任嗣利

    2011-01-01

    As an unconventional oil resource, oil sands and its processing technology has attracted much attention in China in recent years. Water-based extraction processes are the most important method to recover bitumen from oil sands. Two key steps are involved in this process: bitumen liberation from the sand grains and bitumen aeration followed by flotation to form a bitumen-rich froth. Any factor that causes poor liberation or poor aeration will result in a poor bitumen recovery. With the use of the advanced analytical instrumentations, such as the atomic force microscope (AFM), the understanding for the bitumen extraction from oil sands is extended from the macroscopic scale to the molecular level. It is found that the wettability of solids and water chemistry play significant roles in the processability of oil sands. Mechanisms related to the bitumen extraction processes are discussed in detail. The procedures of recovering bitumen from oil sands in industry are also briefly described.%油砂作为一种重要的非常规油气资源,其分离技术的研究近些年来引起了国内科研工作人员的重视.介绍了目前世界上最重要的油砂分离技术——水基提取技术的基本原理及影响油砂分离的重要影响因素,阐述了油砂结构、特性与水基提取分离的重要关系及分离条件对沥青回收率的重要影响作用,同时探讨了原子力显微镜用于油砂水基分离过程中相关微观机理研究的重要应用,最后对水基提取技术用于油砂工业生产的流程进行了简单介绍.

  8. Evaluation of the properties of bitumen and cement pastes and mortars used in the immobilization of waste radioactive

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, Vanessa Mota; de Tello, Cledola Cassia Oliveira, E-mail: vanessamotavieira@gmail.com, E-mail: tellocc@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2013-07-01

    The Project RBMN was launched in November 2008 and aims to establish, manage and execute all tasks for implementing the Brazilian Repository, from its conception to its construction. The concept to be adopted will be a near-surface repository. The inventory includes wastes from the operation of nuclear power plants, fuel cycle facilities and from the use of radionuclides in medicine, industry and activities research and development. The implementation of the national repository is an important technical requirement, and a legal requirement for the entry into operation of the nuclear power plant Angra 3. In Brazil, for the immobilization and solidification of radioactive waste of low and intermediate level of radiation from NPPs are used cement, in Angra 1, and bitumen, in Angra 2. Studies indicate serious concerns about the risks associated with bituminization radioactive waste, much related to the process as the product. There are two major problems due to the presence of products bituminization in repositories, swelling of the waste products and their degradation in the long term. To accommodate the swelling, filling the drums must be limited to 70 - 90% of its volume, which reduces the structural stability of the repository and the optimization of deposition. This study aims to evaluate of the properties of bitumen and cement pastes and mortars used in the immobilization of waste radioactive. (author)

  9. Alternatives for Benzene in the Extraction of Bitumen Fume from Exposure Sample Media.

    Science.gov (United States)

    Sutter, Benjamin; Ravera, Christel; Hussard, Caroline; Langlois, Eddy

    2016-01-01

    Benzene is frequently used to extract collected bitumen fumes from personal sampler substrates. However, this solvent is particularly dangerous because of its carcinogenicity (group 1 of the International Agency for Research on Cancer classification). Therefore, to prevent the exposure of laboratory technicians to benzene during the fume extraction step from samplers, a compromise had to be found to identify a less toxic solvent with the same extraction capacity. To compare the extraction capacities of selected solvents, bitumen fumes were generated in the laboratory from three different batches of road surfacing bitumen collected on dedicated bitumen fume samplers. The samplers were then extracted by benzene and the solvents tested. Of 11 selected solvents less toxic than benzene and used in studies on bitumen and bitumen fume analyses, n-hexane and n-heptane were identified as alternatives to benzene. In particular, the results demonstrated that n-heptane was the best candidate solvent for benzene replacement, due to its extraction efficiency comparable to benzene for the three bitumen fumes tested and its low toxicity, which is highly compatible with benzene replacement.

  10. Analysis of styrene-butadiene-styrene polymer modified bitumen using fluorescent microscopy and conventional test methods.

    Science.gov (United States)

    Sengoz, Burak; Isikyakar, Giray

    2008-01-31

    This paper presents a laboratory study of modified bitumen containing styrene-butadiene-styrene (SBS) copolymer. Polymer modified bitumen (PMB) samples have been produced by mixing a 50/70 penetration grade unmodified (base) bitumen with SBS Kraton D1101 copolymer at five different polymer contents. The fundamental characteristics of the SBS PMB samples have been determined using conventional methods. The morphology of the samples as well as the percent area (%) distribution of SBS polymers throughout the base bitumen have been characterized and determined by means of fluorescence microscopy and Qwin Plus image analysis program, respectively. The mechanical properties of the hot-mix asphalt (HMA) containing SBS PMBs have also been analyzed and compared with HMA incorporating base bitumen. The effect of polymer addition on the short and long term aging characteristics of HMA have been evaluated by indirect tensile strength (ITS) test. The results indicated that polymer modification improved the conventional properties (penetration, softening point, etc.) and the mechanical properties (Marshall, ITS, etc.) of the base bitumen. It was also concluded that at low polymer contents, the samples revealed the existence of dispersed polymer particles in a continuous bitumen phase, whereas at high polymer contents a continuous polymer phase has been observed. Moreover, it was found out that the polymer addition minimizes the short and long term aging of HMA.

  11. Effects of Fibers on Properties of Bitumens; Senitenkazai ga asufuaruto no seijo ni oyobosu eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Ishikawa, Hiroshi.; Moriyoshi, Akihiro. [Hokkaido University, Hokkaido (Japan). Faculty of Engineering; Takahashi, Shigeki.; Cabrera, J.G. [University of Leeds, Leeds (United Kingdom). Civil Engineering Materials Unit

    1999-07-01

    High-viscosity bitumen blended with Styrene Butadiene Copolymer (SBS) and fibers is used, of late, for drainage pavement, for the purpose to prevent cracking and rutting, as well as to prevent flow carrying bituminous mixtures. However, it was not impossible to evaluate whether, or not, the mechanical properties and durability of such bitumens are suitable, at extremes of low or high temperatures. The authors, therefore, have developed a method for determining the mechanical properties of these bitumens, using some new testes, such as the Improved Fraass Breaking Point (IFBP) Test, the Moriyoshi Breaking Point (MBP) Test, the High-Temperature Long-Time Durability (HTLTD) Test and the Bending Test. The method employed for measuring viscosity at high temperature was the Flow Test by rheometer. This paper describes the various results of tests for high-viscosity bitumens blended with the SBS and Fibers. The authors obtained some brittle points and mechanical properties of these bitumens by using the said testers. The authors found the fracture properties and durability of bitumen blend-ed with various fibers unfavorable, compared with the original bitumens. (author)

  12. Effect of Ultraviolet Aging on Rheology and Chemistry of LDH-Modified Bitumen

    Directory of Open Access Journals (Sweden)

    Xing Liu

    2015-08-01

    Full Text Available Layered double hydroxides (LDHs are an ultravioletlight (UV-resistant material. In this study, two types of LDHs (Mg-Al-LDHs and Zn-Al-LDHs were applied to modify bitumen by melt-blending. The effect of ultraviolet aging on the rheology and chemistry of LDH-modified bitumen was studied by means of dynamic shear rheometer (DSR, thin-layer chromatography with flame ionization detection (TLC-FID, Fourier transform infrared spectroscopy (FTIR, and Ultraviolet-Visible (UV-Vis spectrophotometry to reveal the mechanisms of action for LDHs and bitumen. The results showed that within the UV spectra (220–400 nm, the reflectance of Zn-Al-LDHs was larger than that of Mg-Al-LDHs. These two LDHs have different influences on the performance of bitumen. Mg-Al-LDHs had a more obvious influence on the physical and dynamic rheological properties of bitumen than Zn-Al-LDHs. Zn-Al-LDHs improved the UV-aging resistance of bitumen more. The reason can be that the reflectance of the Zn-Al-LDHs to the UV light is larger than that of the Mg-Al-LDHs. The Zn-Al-LDH-modified bitumen had more potential to improve the UV-aging resistance during the service life of asphalt pavement.

  13. Influencia del bitumen sobre la calidad de un reservorio siliciclástico: Aplicación al campo de Salam en el desierto occidental de Egipto

    OpenAIRE

    1998-01-01

    Bitumen are rarely taken into account in the petrophysical characterization of reservoirs because they may be rather difficult to distinguish. This paper focuses on the effects of bitumen on the reservoir quality of the sandstones from the Salam Field in the Western Desert (Egypt). We describe the various morphologies of the bitumen by SEM and we relate these data with the chemical composition of the bitumen and with the porosity determined by Hg injection. The coatings of bitumen affect ...

  14. In-situ analysis of solid bitumen in coal: Examples from the Bowen Basin and the Illinois Basin

    Science.gov (United States)

    Mastalerz, Maria; Glikson, M.

    2000-01-01

    Solid bitumen and associated vitrinite from selected coals from the Bowen Basin and the Illinois Basin were studied using electron microprobe and micro-FTIR techniques. The coal studied covers a range of vitrinite reflectance from 0.59% to 1.33%. Carbon content in the bitumen is generally lower than in vitrinite in coals with vitrinite reflectance below 0.67%. In coals with reflectance above 0.67%, carbon content of bitumen is higher than in vitrinite, reflecting higher aromaticity due to hydrocarbon generation. Sulfur and iron content are comparable between vitrinite and bitumen. Functional group distribution suggests the presence of two types of bitumen in the Illinois Basin coals. The more aliphatic variety occurring in veins and cleats is interpreted as pre-gas generation bitumen, and the more aromatic variety filling cells and voids in inertinite as post-gas generation bitumen. (C) 2000 Elsevier Science B.V. All rights reserved.Solid bitumen and associated vitrinite from selected coals from the Bowen Basin and the Illinois Basin were studied using electron microprobe and micro-FTIR techniques. The coal studied covers a range of vitrinite reflectance from 0.59% to 1.33%. Carbon content in the bitumen is generally lower than in vitrinite in coals with vitrinite reflectance below 0.67%. In coals with reflectance above 0.67%, carbon content of bitumen is higher than in vitrinite, reflecting higher aromaticity due to hydrocarbon generation. Sulfur and iron content are comparable between vitrinite and bitumen. Functional group distribution suggests the presence of two types of bitumen in the Illinois Basin coals. The more aliphatic variety occurring in veins and cleats is interpreted as pre-gas generation bitumen, and the more aromatic variety filling cells and voids in inertinite as post-gas generation bitumen.

  15. Experimental study of CT test on the failure of acrylate spray-applied waterproof layer in the groundwater environment

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    In this study the computerized tomography (CT) was first used to quantitatively analyze the failure of acrylate spray-applied waterproof membrane in the groundwater environment. The results of the CT tests show that it is feasible to use the CT to quantitatively analyze the failure of the waterproof membrane and the CT method has the advantages of speediness and accuracy that can eliminate the fussy operation process in routine tests. The main conclusions summarized from the study are as follows. First, there are two combined-indexes that can be used to decide the failure of the spray-on waterproof layer: one is that the reduced percentage of the CT number of the spray-on waterproof layer is less than 40.0% and the other is that the variance of the CT number decreases first and then increases. Second, the applicability for the spray-on waterproof layer in the groundwater environment is the SO 24-concentration ≤ 1%, the Cl-concentration ≤ 7.5% and the pH value ≤ 12.0 of the groundwater, respectively.

  16. Industry

    Energy Technology Data Exchange (ETDEWEB)

    Bernstein, Lenny; Roy, Joyashree; Delhotal, K. Casey; Harnisch, Jochen; Matsuhashi, Ryuji; Price, Lynn; Tanaka, Kanako; Worrell, Ernst; Yamba, Francis; Fengqi, Zhou; de la Rue du Can, Stephane; Gielen, Dolf; Joosen, Suzanne; Konar, Manaswita; Matysek, Anna; Miner, Reid; Okazaki, Teruo; Sanders, Johan; Sheinbaum Parado, Claudia

    2007-12-01

    This chapter addresses past, ongoing, and short (to 2010) and medium-term (to 2030) future actions that can be taken to mitigate GHG emissions from the manufacturing and process industries. Globally, and in most countries, CO{sub 2} accounts for more than 90% of CO{sub 2}-eq GHG emissions from the industrial sector (Price et al., 2006; US EPA, 2006b). These CO{sub 2} emissions arise from three sources: (1) the use of fossil fuels for energy, either directly by industry for heat and power generation or indirectly in the generation of purchased electricity and steam; (2) non-energy uses of fossil fuels in chemical processing and metal smelting; and (3) non-fossil fuel sources, for example cement and lime manufacture. Industrial processes also emit other GHGs, e.g.: (1) Nitrous oxide (N{sub 2}O) is emitted as a byproduct of adipic acid, nitric acid and caprolactam production; (2) HFC-23 is emitted as a byproduct of HCFC-22 production, a refrigerant, and also used in fluoroplastics manufacture; (3) Perfluorocarbons (PFCs) are emitted as byproducts of aluminium smelting and in semiconductor manufacture; (4) Sulphur hexafluoride (SF{sub 6}) is emitted in the manufacture, use and, decommissioning of gas insulated electrical switchgear, during the production of flat screen panels and semiconductors, from magnesium die casting and other industrial applications; (5) Methane (CH{sub 4}) is emitted as a byproduct of some chemical processes; and (6) CH{sub 4} and N{sub 2}O can be emitted by food industry waste streams. Many GHG emission mitigation options have been developed for the industrial sector. They fall into three categories: operating procedures, sector-wide technologies and process-specific technologies. A sampling of these options is discussed in Sections 7.2-7.4. The short- and medium-term potential for and cost of all classes of options are discussed in Section 7.5, barriers to the application of these options are addressed in Section 7.6 and the implication of

  17. Dating hydrocarbon genera-tion and migration based on bitumen reflectance

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    On the basis of thermal maturation theories of organic matter in sediments and an improved Karweil's method, a method for dating hydrocarbon generation and migration by means of bitumen reflectance has been suggested. A few representative boreholes in the Tazhong Area of the Tarim Basin was investigated by this method. The results indicate that the three phases of bitumen from the Tazhong Area formed during Middle and Late Ordovician, Late Cretaceous-Early Tertiary, and Late Tertiary, respectively. This implicates that there were three phases of hydrocarbon generation and migration occurring in this area during geological history. This study provided a new idea for the geological application of geochemical data of bitumen.

  18. [Determination of the four generic fractions of aged bitumen by thin-layer chromatography with flame ionization detection].

    Science.gov (United States)

    Feng, Zhengang; Zhang, Jianbin; Li, Xinjun; Yu, Jianying

    2015-02-01

    The aging process of bitumen has been paid more and more attention by the researchers. The four generic fractions (saturates, aromatics, resins and asphaltenes) of bitumen change significantly during the aging process. The analysis of the changes of the four generic fractions of bitumen is very helpful to reveal the bitumen aging mechanisms and guide its engineering applications. In this study, the bitumen was aged by thin film oven test (TFOT) , pressurized aging vessel (PAV) test and ultraviolet (UV) aging test, respectively. Then the four generic fractions of bitumen before and after aging were analyzed by thin-layer chromatography with flame ionization detection (TLC-FID) , which was further compared with the solubility procedures and chromatographic technique ( named as Corbett method). The compositions of the expanded solvents were also investigated. Finally, the correlation between the TLC-FID and Corbett method was further studied, which revealed a proper TLC-FID meth- od for detection of aged bitumen. The bitumen solution dissolved by dichloromethane was successively expanded by n-heptane, toluene/n-heptane (80 :20, v/v) and toluene/ethanol (55: 45, v/v) , followed by TLC-FID. This method is of great significance for the analysis of the four generic fractions of bitumen and for the exploration of bitumen aging mechanisms.

  19. Visbreaking based integrated process for bitumen upgrading and hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Sosa, C.; Gonzalez, M.F.; Carbognani, L.; Perez-Zurita, M.J.; Lopez-Linares, F.; Husein, M.; Moore, G.; Pereira, P. [Calgary Univ., AB (Canada). Alberta In Situ Centre For In Situ Energy, Schulich School Of Engineering

    2006-07-01

    New and cost effective upgrading schemes for distillates production and residue disposal are needed in order to recover Alberta's vast heavy oil and bitumen reserves. On average, heavy oils and bitumen contain 50 per cent (w/w) of components remaining after vacuum distillation. A new alternative for upgrading vacuum resids was proposed. The method involves the following 3 processing steps: production of modified, nearly unstable heavy molecules by mild thermal cracking known as visbreaking; adsorption of modified heavy molecules over inexpensive, tailor-designed porous sorbents or catalysts; and, production of hydrogen by low temperature catalytic steam gasification of the adsorbed molecules. This cost effective way of producing hydrogen is based on the selective segregation of a minimal fraction of the heaviest hydrocarbon molecules, those most instable, followed by their gasification at low temperature. This paper presented results on the combined processing as well as using both a model molecule and real feedstock from the Athabasca vacuum resids for the adsorption and hydrogen production steps. The study showed that this new process can obtain high rates of hydrogen production when a kaolin based solid formulation is used as both, adsorbent and catalysts, for these heavy molecules. It was concluded that this alternative method for producing hydrogen at upgrading sites in northern Alberta has potential for both installed and future up-graders to improve the quality of synthetic crude being produced. The hydrogen produced from the gasification of these heavy compounds could be used for both refining purposes or for in-situ reservoir upgrading. 27 refs., 3 figs.

  20. Rheology and microstructure of MDI PEG reactive prepolymer-modified bitumen

    Science.gov (United States)

    Navarro, F. J.; Partal, P.; Martínez-Boza, F.; Gallegos, C.; Bordado, J. C. M.; Diogo, A. C.

    2006-12-01

    This paper deals with the use of a new bitumen modifier, a reactive prepolymer, based on the reaction of 4,4‧-diphenylmethane diisocyanate (MDI) and a low molecular weight polyethylene glycol (PEG). The rheological and thermal behaviours of modified bitumen containing a low MDI PEG concentration, as well as its morphology, have been studied. A relatively low amount of MDI PEG (0.5 to 1.5% wt.) yields a significant improvement in the modified bitumen rheological properties, mainly in the high in-service temperature region. In this range of temperature, the rheological properties are clearly affected by curing time at room temperature. These results indicate that chemical changes, due to the reaction of MDI isocyanate groups with the most polar groups ( OH; NH) of asphaltenes and resins, are produced. Thus, new chemical structures, non-visible by optical microscopy, slowly develop in MDI PEG modified bitumen when samples are cured at room temperature.

  1. Low temperature extraction and upgrading of oil sands and bitumen in supercritical fluid mixtures.

    Science.gov (United States)

    Brough, Sarah A; Riley, Sandra H; McGrady, G Sean; Tanhawiriyakul, Supaporn; Romero-Zerón, Laura; Willson, Christopher D

    2010-07-21

    Preliminary results are reported for the extraction and catalytic hydrocracking of Alberta bitumen and oil sands using supercritical fluid mixtures; high levels of extraction and upgrading were attained using reaction conditions significantly milder than those previously reported.

  2. Biological markers in bitumens and pyrolyzates of Upper Cretaceous bituminous chalks from the Ghareb Formation (Israel)

    Science.gov (United States)

    Rullkötter, Jürgen; Aizenshtat, Zeev; Spiro, Baruch

    1984-01-01

    The sterane and triterpane distributions of three bituminous chalks from the Upper Cretaceous Ghareb Formation (Israel) were investigated both in the original extractable bitumens and in extracts obtained after pyrolysis of whole rock and isolated kerogen samples at 450°C. Pyrolysis was performed in a closed system under hydrous (whole rock) and anhydrous conditions (isolated kerogens). The carbon number distributions of steranes and triterpanes differ significantly between original bitumen and pyrolyzates. Unlike the bitumens in which diasteranes were not detected, the anhydrous pyrolyzates contain small amounts of diasteranes. The presence of water during pyrolysis leads to an increase of sterane isomerization, the abundant formation of diasteranes and an increase of the 18α( H)- trisnorneohopane/17α( H)- trisnorhopane ratio. Sterane isomerization maturation parameters show a closer match between original bitumen and pyrolyzates after pyrolysis in a closed system when compared with an open system.

  3. Numerical Simulation Study on Parameters related to Athabasca Bitumen Recovery with SAGD

    OpenAIRE

    Marianayagam, Kristin Reka

    2012-01-01

    The world’s total oil reserves are to some extent dominated by heavy oil. The heavy oil reserves are doubled in volume compared to conventional oil reserves. As conventional oil reservoirs are depleting, heavy oil and bitumen possesses a great potential in covering parts of the future energy demand. The possibility of horizontal drilling has created a pathway for SAGD (Steam Assisted Gravity Drainage), which is the most preferred heavy oil and bitumen recovery method. The mechanism of SAGD in...

  4. Analys av Nedbrytningsprodukter av Polymerer för Bitumenändamål

    OpenAIRE

    Lindström, Björn

    2007-01-01

    This project was aimed to study the degradation of polystyrene-butadiene-styrene block copolymer (SBS). SBS is used to modify bitumen, the binder in asphalt. From earlier studies it is known that SBS degrades in bitumen, but the degradation products have not been identified. To be able to determine the long term effects of SBS in the environment, degradation products need to be identified. Polystyrene forms rigid blocks with polybutadiene as a rubbery matrix between the ridgid blocks. When bl...

  5. Effects of SBS Configuration on Performance of High Modulus Bitumen Based on Dynamic Mechanical Analysis

    OpenAIRE

    Ming Liang; Yong Hu; Xiangjun Kong; Weiyu Fan; Xue Xin; Hui Luo

    2016-01-01

    High modulus bitumens modified by polystyrene-block-polybutadiene-block-polystyrene (SBS) with different molecular structure were investigated on dynamic shear rheometer and fluorescence microscopy to evaluate viscoelastic properties and morphology of binders. The results shows that storage modulus (G’) is obviously less than loss modulus (G”), which means viscous behaviour of bitumen is dominant, and anti-rutting factor (G* ⁄ sin δ) is markedly enhanced by star SBS than by linear SBS. The mo...

  6. Distinguishing solid bitumens formed by thermochemical sulfate reduction and thermal chemical alteration

    Science.gov (United States)

    Kelemen, S.R.; Walters, C.C.; Kwiatek, P.J.; Afeworki, M.; Sansone, M.; Freund, H.; Pottorf, R.J.; Machel, H.G.; Zhang, T.; Ellis, G.S.; Tang, Y.; Peters, K.E.

    2008-01-01

    Insoluble solid bitumens are organic residues that can form by the thermal chemical alteration (TCA) or thermochemical sulfate reduction (TSR) of migrated petroleum. TCA may actually encompass several low temperature processes, such as biodegradation and asphaltene precipitation, followed by thermal alteration. TSR is an abiotic redox reaction where petroleum is oxidized by sulfate. It is difficult to distinguish solid bitumens associated with TCA of petroleum from those associated with TSR when both processes occur at relatively high temperature. The focus of the present work was to characterize solid bitumen samples associated with TCA or TSR using X-ray photoelectron spectroscopy (XPS). XPS is a surface analysis conducted on either isolated or in situ (>25 ??m diameter) solid bitumen that can provide the relative abundance and chemical speciation of carbon, organic and inorganic heteroatoms (NSO). In this study, naturally occurring solid bitumens from three locations, Nisku Fm. Brazeau River area (TSR-related), LaBarge Field Madison Fm. (TSR-related), and the Alaskan Brooks range (TCA-related), are compared to organic solids generated during laboratory simulation of the TSR and TCA processes. The abundance and chemical nature of organic nitrogen and sulfur in solid bitumens can be understood in terms of the nature of (1) petroleum precursor molecules, (2) the concentration of nitrogen by way of thermal stress and (3) the mode of sulfur incorporation. TCA solid bitumens originate from polar materials that are initially rich in sulfur and nitrogen. Aromaticity and nitrogen increase as thermal stress cleaves aliphatic moieties and condensation reactions take place. Organic sulfur in TCA organic solids remains fairly constant with increasing maturation (3.5 to ???17 sulfur per 100 carbons) into aromatic structures and to the low levels of nitrogen in their hydrocarbon precursors. Hence, XPS results provide organic chemical composition information that helps to

  7. Chemically modified bitumens with enhanced rheology and adhesion properties to siliceous aggregates

    OpenAIRE

    Cuadri Vega, Antonio Abad; Partal López, Pedro; Ahmad, Naveed; Grenfell, James; Airey, Gordon

    2015-01-01

    Moisture damage is one of the major premature failures that worsens the performance and shortens service life of pavements. This research assesses the effect that two chemical modifiers (thiourea and an isocyanate-functionalized castor oil prepolymer) exerts on the bitumen rheology and on the resistance to potential moisture damage of asphalt mixtures based on siliceous aggregates. Both thiourea and the isocyanate-based prepolymer improve the viscous and viscoelastic behaviours of bitumen at ...

  8. Three-phase gas-liquid-solid foaming bubble reactors and self-lubricated transport of bitumen froth

    Science.gov (United States)

    Mata, Clara E.

    Two distinct topics in multi-phase flow of interest of the oil industry are considered in this thesis. Studies of three-phase gas-liquid-solid foaming bubble reactors and self-lubricated transport of bitumen froth are reported. Applications of foams and foaming are found in many industrial processes such as flotation of minerals, enhanced oil recovery, drilling in oil reservoirs, and refining processes. However the physics of foaming and defoaming are not fully understood. Foams trap gas and are not desirable in some processes such as oil refining. Previously, it has been found that foaming may be strongly suppressed in a cold slit bubble reactor by fluidizing hydrophilic particles in the bubbly mixture below the foam. In this work, we fluidized hydrophobic and hydrophilic versions of two different sands in a cold slit foaming bubble reactor. We found that the hydrophobic sands suppress the foam substantially better than their hydrophilic counterparts. To study the capacity of foams to carry particles, we built a new slit foaming bubble reactor, which can be continuously fed with solid particles. Global gas, liquid, and solid holdups were measured for given gas and liquid velocities and solid flow rates. This research provides the fundamental ground work for the identification of flow types in a slit three-phase foaming bubble reactor with continuous injection of particles. Bitumen froth is produced from the oil sands of Athabasca, Canada. When transported in a pipeline, water present in the froth is released in regions of high shear (at the pipe wall). This results in a lubricating layer of water that allows bitumen froth pumping at greatly reduced pressures and hence the potential for savings in pumping energy consumption. Experimental results establishing the features of this self lubrication phenomenon are presented. The pressure gradient of lubricated flows closely follow the empirical law of Blasius for turbulent pipe flow with a constant of proportionality

  9. Chemical and rheological evaluation of ageing properties of SBS polymer modified bitumens

    Energy Technology Data Exchange (ETDEWEB)

    Lu, X.; Isacsson, U. [Royal Institute of Technology, Stockholm (Sweden). Division of Highway Engineering

    1998-07-01

    The ageing properties of Styrene-Butadiene-Styrene (SBS) polymer modified bitumens were evaluated using Dynamic Mechanical Analysis (DMA), Gel Permeation Chromatography (GPC) and Fourier Transform InfraRed (FTIR) spectroscopy. The binders were aged by means of the Thin Film Oven Test (TFOT) and the Rolling Thin Film Oven Test (RTFOT), respectively. It was observed that ageing resulted in degradation of the SBS polymer containing molecules and increase in bitumen molecular weight. The polymer was observed to resist formation of sulphoxides. Changes in the rheological properties of aged-modified binders were dependent on a combined effect of bitumen oxidation and polymer degradation, which varied with bitumen source/grade and polymer type/content. In all cases, the aged modified binders showed better rheological properties than aged base bitumens. The study also indicated that the ageing index obtained using DMA was largely influenced by temperature and frequency. This parameter may be applied for evaluating the base bitumens and modified binders with a low polymer content (3% in this study), but not for modified binders with a high (6%) polymer content. 18 refs., 9 figs., 4 tabs.

  10. Quantitative studies of hydrocarbon loss of the Silurian bitumen sandstone in the Tarim Basin

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The evolution of Tarim Basin experienced several tectonic movements,of which Caledonian movement caused a serious damage to reservoirs of Silurian. The earlier reservoirs size and the later hydrocarbon loss are two key factors to exploration prospect of Silurian. On the basis of net thickness of bituminous sandstone and recovery coefficient of crude oil converting to bitumen,the scale of the hydrocarbon loss of palaeo-accumulation in bitumen sandstone of Silurian was calculated (86.30×108t). The deter-mination of net thickness of bitumen sandstone was completed mainly by several methods,such as physical property demarcation,observing lithology,grains with oil inclusion (GOI) technology,and quantitative grains fluorescence (QGF) technology. The samples of black sandstone and white sand-stone were collected and compared by means of the methods mentioned above. The results showed that there was little hydrocarbon,or none,in the white sandstone. The recovery coefficient was ob-tained by the analyses of plentiful physical parameters of crude oil and bitumen sandstone,based on the hypothesis that nonhydrocarbon compounds and bitumen were invariable in the process of bitu-men forming. The calculated result,which is more scientific and actual,indicates the exploration pros-pect is more promising in Silurian of the Tarim Basin.

  11. Biological marker distribution in coexisting kerogen, bitumen and asphaltenes in Monterey Formation diatomite, California

    Science.gov (United States)

    Tannenbaum, E.; Ruth, E.; Huizinga, B. J.; Kaplan, I. R.

    1986-01-01

    Organic-rich (18.2%) Monterey Formation diatomite from California was studied. The organic matter consist of 94% bitumen and 6% kerogen. Biological markers from the bitumen and from pyrolysates of the coexisting asphaltenes and kerogen were analyzed in order to elucidate the relationship between the various fractions of the organic matter. While 17 alpha(H), 18 alpha(H), 21 alpha(H)-28,30-bisnorhopane was present in the bitumen and in the pryolysate of the asphaltenes, it was not detected in the pyrolysates of the kerogen. A C40-isoprenoid with "head to head" linkage, however, was present in pyrolysates of both kerogen and asphaltenes, but not in the bitumen from the diatomite. The maturation level of the bitumen, based on the extent of isomerization of steranes and hopanes, was that of a mature oil, whereas the pyrolysate from the kerogen showed a considerably lower maturation level. These relationships indicate that the bitumen may not be indigenous to the diatomite and that it is a mature oil that migrated into the rock. We consider the possibility, however, that some of the 28,30-bisnorhopane-rich Monterey Formation oils have not been generated through thermal degradation of kerogen, but have been expelled from the source rock at an early stage of diagenesis.

  12. Integrated Flexible, Waterproof, Transparent, and Self-Powered Tactile Sensing Panel.

    Science.gov (United States)

    Jiang, Xu-Zhou; Sun, Yi-Jing; Fan, Zhiyong; Zhang, Tong-Yi

    2016-08-23

    Portable and wearable electronic devices are human-centered devices; therefore, many unique attributes are highly desirable, such as flexibility, being self-powered, and waterproof. These properties render devices excellent adaptivity in harsh operation environments. In this work, we report an integrated triboelectric tactile sensor array with flexible, transparent, self-powered, and waterproof features. Each tactile sensor is a surface nano/microtexture enhanced triboelectric nanogenerator. The sensor array can serve as a touch panel for electronic devices. Owing to a unique design of a built-in triboelectric contact pair and an electrical shielding layer, an individual pixel of the fabricated tactile sensor array can generate an open circuit voltage up to 1.613 V and a short circuit current density of 47.308 mA/m(2) under 612.5 kPa. The tactile sensors can produce stable voltage signals regardless of the materials of the touching objects, and work stably both in ambient and aqueous environments. To examine the touch panel function of a sensor array, a matrix of 10 × 10 individually addressable 4 mm × 4 mm triboelectric sensors has been integrated into a thin, transparent, and flexible film, and the 2-D touch mapping has been successfully demonstrated. The unique triboelectric tactile sensor array reported here is robust and highly versatile, and it may find broad applications in display, wearable electronics, artificial skins, Internet of Things (IoT), etc.

  13. Non-Newtonian behavior and molecular structure of Cooee bitumen under shear flow: a non-equilibrium molecular dynamics study

    CERN Document Server

    Lemarchand, Claire A; Todd, Billy D; Daivis, Peter J; Hansen, Jesper S

    2015-01-01

    The rheology and molecular structure of a model bitumen (Cooee bitumen) under shear is investigated in the non-Newtonian regime using non-equilibrium molecular dynamics simulations. The shear viscosity and normal stress differences of the bitumen mixture are computed at different shear rates and different temperatures. The model bitumen is shown to be a shear-thinning fluid. The corresponding molecular structure is studied at the same shear rates and temperatures. The Cooee bitumen is able to reproduce experimental results showing the formation of nanoaggregates composed of stacks of flat aromatic molecules. These nanoaggregates are immersed in a solvent of saturated hydrocarbon molecules. The nanoaggregates are shown to break up at very high shear rates, leading only to a minor effect on the viscosity of the mixture. At low shear rates, bitumen can be seen as a colloidal suspension of nanoaggregates in a solvent. The slight anisotropy of the whole sample due to the nanoaggregates is considered and quantified...

  14. Studi Proses Pemisahan Bitumen dari Asbuton dengan Proses Hot Water Menggunakan Bahan Pelarut Kerosin dan Larutan Surfaktan

    Directory of Open Access Journals (Sweden)

    Mochamad Sidiq

    2013-09-01

    Full Text Available Penelitian ini merupakan studi proses pemisahan bitumen dari asbuton dengan proses hot water menggunakan bahan pelarut kerosin dan larutan surfaktan. Asbuton adalah aspal alam yang terdeposit dalam batuan dengan kadar bitumen antara 15-30% yang terdapat di Pulau Buton, Sulawesi Tenggara dengan jumlah deposit aspal sebesar 677juta ton. Bitumen dapat digunakan sebagai campuran aspal minyak untuk pembangunan dan pemeliharaan sarana infrastruktur berupa jalan raya. Salah satu cara pemisahan bitumen dari mineral adalah dengan proses hot water menggunakan bahan pelarut kerosin dan larutan surfaktan. Sistem yang ditinjau dalam penelitian ini adalah tangki berpengaduk berbentuk silinder dengan kapasitar 2000cm2. Dalam penelitian ini akan ditinjau pengaruh dari penambahan ratio larutan surfaktan/asbuton dan penambahan kerosin terhadap %recovery bitumen. Proses ekstraksi dilakukan selama 20 menit dengan suhu proses 90oC dan kecepatan putar pengaduk 1500 rpm. Hasil proses ini akan terbentuk 3 lapisan yaitu lapisan atas terdiri dari larutan bitumen (kerosin dan bitumen, lapisan tengah terdiri dari air, larutan surfaktan dan mineral murni yang terpisah, dan lapisan bawah terdiri dari asbuton yang tidak terekstrak, kerosin dan sedikit air. Lapisan paling atas di ambil dan dilakukan analisa densitasnya untuk diketahui konsentrasi bitumennya. Sehingga dapat dihitung %recovery bitumen yang dihasilkan. Lapisan paling atas dipisahkan dan dianalisa konsentrasi bitumennya dengan mengukur densitasnya. Dari hasil eksperimen diperoleh kesimpulan bahwa (% recovery bitumen tertinggi adalah pada penambahan kerosin 50% dan 0,1% konsentrasi larutan surfaktan 35 % sebesar 80,797%.

  15. Interaction between plasticized polyvinyl chloride waterproofing membrane and extruded polystyrene board, in the inverted flat roof

    Directory of Open Access Journals (Sweden)

    Pedrosa, A.

    2014-12-01

    Full Text Available The inverted flat roof is a constructive system widely used in flat roof construction. In this constructive solution, the insulation is placed over the waterproofing material as a protection. It is believed that this solution provides a longer life cycle; given the fact that it limits the thermal variation the waterproofing material bears up to the end of its life cycle. Consequently, the result will be providing a longer life to the waterproofing membrane. This constructive solution always incorporates polymers or other materials with a thermoplastic addition in their composition. Some polymers show interactions between them that can affect their integrity, and, at the same time, the bulk of the polymeric materials are incompatible. The extruded polystyrene board is always present in the inverted flat roof, and although it is an unbeatable product for this use, it presents incompatibilities and interactions with other materials, and these can affect their properties and therefore the durability of them.La cubierta plana invertida es un sistema constructivo muy utilizado en las cubiertas planas. En esta solución constructiva, el aislamiento se coloca sobre el material impermeabilizante a modo de protección. Se cree que esta solución proporciona un ciclo de vida más largo; dado que se limita la variación térmica de la impermeabilización hasta el final de su ciclo de vida. En consecuencia, el resultado proporciona una vida más larga a la membrana impermeable. Esta solución constructiva siempre incorpora polímeros u otros materiales con adición termoplástica en su composición. Algunos polímeros muestran interacciones entre ellos que pueden afectar a su integridad, además, la mayor parte de los materiales poliméricos son incompatibles. La plancha de poliestireno extrusionado está siempre presente en la cubierta plana invertida, y aunque es un producto inmejorable para este uso, presenta incompatibilidades e interacciones con otros

  16. Physical and chemical characterization of asphalt (bitumen) paving exposures.

    Science.gov (United States)

    Herrick, Robert F; McClean, Michael D; Meeker, John D; Zwack, Leonard; Hanley, Kevin

    2007-01-01

    The purpose of this research was to characterize the physical and chemical properties of asphalt (bitumen) fume and vapor in hot mix asphalt roadway paving operations. Area and personal air samples were taken using real-time equipment and extractive sampling and analytical methods to determine worker asphalt exposure, as well as to characterize the properties of the particulate and vapor phase components. Analysis of personal inhalation and dermal samples by gas chromatography/mass spectroscopy showed that the polycyclic aromatic hydrocarbon profile is dominated by compounds with molecular weights below 228, and that substituted and heterocyclic polycyclic aromatic hydrocarbons comprised approximately 71% of the detectable mass concentration (vapor and particulate combined). Principal components analysis shows that the polycyclic aromatic hydrocarbons with molecular weights greater than 190 are the driving force behind the polycyclic aromatic compound exposures measured for the dermal and particulate phases; there was no clear trend for the vapor phase Most of the aerosol particles are fine (mass median aerodynamic diameter 1.02 microm; count median diameter 0.24 microm).

  17. Waterproofing Underground Structures: Lessons from the Past, Systems for the Future

    Institute of Scientific and Technical Information of China (English)

    Martin Smith

    2004-01-01

    The paper describes some of the key issues that need to be addressed in the design and execution of underground structures to ensure their long term suitability as watertight units and outlines through practical examples of structures that have not achieved their design requirements which situations need to be considered. Waterproofing is not an exact science but a combination of theoretical knowledge and practical experience based on the five key factors: Environment, Design, Materials, Application and Use of the Structure.In conclusion the paper outlines the advances in crack control to date that can provide the necessary long term guarantees.The adoption of re - injectable crack inducers permitted the Client to save over 10% on construction costs and reduced the construction time by six months.

  18. Waterproof AlInGaP optoelectronics on stretchable substrates with applications in biomedicine and robotics

    Science.gov (United States)

    Kim, Rak-Hwan; Kim, Dae-Hyeong; Xiao, Jianliang; Kim, Bong Hoon; Park, Sang-Il; Panilaitis, Bruce; Ghaffari, Roozbeh; Yao, Jimin; Li, Ming; Liu, Zhuangjian; Malyarchuk, Viktor; Kim, Dae Gon; Le, An-Phong; Nuzzo, Ralph G.; Kaplan, David L.; Omenetto, Fiorenzo G.; Huang, Yonggang; Kang, Zhan; Rogers, John A.

    2010-11-01

    Inorganic light-emitting diodes and photodetectors represent important, established technologies for solid-state lighting, digital imaging and many other applications. Eliminating mechanical and geometrical design constraints imposed by the supporting semiconductor wafers can enable alternative uses in areas such as biomedicine and robotics. Here we describe systems that consist of arrays of interconnected, ultrathin inorganic light-emitting diodes and photodetectors configured in mechanically optimized layouts on unusual substrates. Light-emitting sutures, implantable sheets and illuminated plasmonic crystals that are compatible with complete immersion in biofluids illustrate the suitability of these technologies for use in biomedicine. Waterproof optical-proximity-sensor tapes capable of conformal integration on curved surfaces of gloves and thin, refractive-index monitors wrapped on tubing for intravenous delivery systems demonstrate possibilities in robotics and clinical medicine. These and related systems may create important, unconventional opportunities for optoelectronic devices.

  19. A Comparative Study on Properties of Malaysian Porous Asphalt Mixes with Different Bitumen Contents

    Directory of Open Access Journals (Sweden)

    Mohamad Yusri Aman

    2015-04-01

    Full Text Available Inadequate bitumen content in porous pavement construction may result in incomplete coating of aggregates which a thin bitumen film can oxidize rapidly resulting in premature failure of the pavement. This and presents the effects of porous asphalt prepared with 4.0% and up to 6.0% binder content with 0.5% increments binder. Bitumen penetration grade 60/70 and crushed granite were used in preparing the porous asphalt specimen. The porous asphalt mixes were compacted by applying 50 blows on each face using a Marshall Impact compactor. The specimens were tested for air voids, indirect tensile strength and water permeability and abrasion loss. The moisture sensitivity was assessed according to the AASHTO T283 procedures. The result shows that the increasing of bitumen content has decreased the, bulk density air voids, coefficient of permeability and abrasion loss values However, the Indirect Tensile Strength (ITS has significantly increased and this is a good indication to resistance against moisture sensitivity. It can be concluded that the increasing of bitumen content in porous asphalt has increased the thickness of binder coating around the aggregates. This results reduction in air voids and water permeability, on the other hands it increases resistance to disintegration and ITS value which give better resistance to moisture sensitivity of porous specimens.

  20. Bitumen on Water: Charred Hay as a PFD (Petroleum Flotation Device

    Directory of Open Access Journals (Sweden)

    Nusrat Jahan

    2015-10-01

    Full Text Available Global demand for petroleum keeps increasing while traditional supplies decline. One alternative to the use of conventional crude oils is the utilization of Canadian bitumen. Raw bitumen is a dense, viscous, semi-liquid that is diluted with lighter crude oil to permit its transport through pipelines to terminals where it can then be shipped to global markets. When spilled, it naturally weathers to its original form and becomes dense enough to sink in aquatic systems. This severely limits oil spill recovery and remediation options. Here we report on the application of charred hay as a method for modifying the surface behavior of bitumen in aquatic environments. Waste or surplus hay is abundant in North America. Its surface can easily be modified through charring and/or chemical treatment. We have characterized the modified and charred hay using solid-state NMR, contact angle measurements and infrared spectroscopy. Tests of these materials to treat spilled bitumen in model aquatic systems have been undertaken. Our results indicate that bitumen spills on water will retain their buoyancy for longer periods after treatment with charred hay, or charred hay coated with calcium oxide, improving recovery options.

  1. Assessment of dermal exposure to bitumen condensate among road paving and mastic crews with an observational method

    NARCIS (Netherlands)

    Agostini, M.; Fransman, W.; Vocht, F.D.; Joode, B.V.W.D.; Kromhout, H.

    2011-01-01

    Objective: To assess dermal exposure to bitumen condensate among road pavers and indoor mastic workers in multiple crews using a semi-quantitative observational method [DeRmal Exposure Assessment Method (DREAM)].Methods: Two skilled observers assessed dermal exposure to bitumen condensate among 85 a

  2. Rate of bitumen film transfer from a quartz surface to an air bubble as observed by optical microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Lelinski, D. [FFE Minerals USA Inc., Salt Lake City, UT (United States); Drelich, J. [Michigan Technological Univ., Houghton, MI (United States). Dept. of Materials Science and Engineering; Miller, J.D. [Utah Univ., Salt Lake City, UT (United States). Dept. of Metallurgical Engineering; Hupka, J. [Gdansk Univ. of Technology, Gdansk (Poland). Dept. of Chemical Technology

    2004-08-01

    Froth flotation is a separation process used to recover oil from oil sands. The two separation steps in froth flotation include the release of oil from mineral matter, and oil flotation from the slurry. During flotation, gas bubbles collide with and attach to oil droplets and to oily soil particles. The flotation of oil-in water emulsions in the absence of solids has been studied extensively. This study focused on liquid/liquid spreading. It was limited to simple systems involving pure single-component liquids. Multi-component oils were only used in a few experiments. In particular, this paper discussed the rate of high viscosity bitumen transfer from a bitumen-coated quartz slide to an air bubble surface that occurred in an aqueous alkaline solution. Bitumen spreading observations were recorded with a video camera attached to a stereoscopic microscope. The objective was to improve hot-water processing technology for bitumen recovery from Utah oil sands. The study showed that during bitumen spreading, a bulk layer followed the formation of thin bitumen films. The spreading velocity was one order of magnitude less than the velocity of the precursor film. The study provided a better understanding of the basic separation techniques encountered in the sequence of oil sand slurry digestion, aeration, gravity separation and flotation. It was concluded that a strong intermolecular attraction exists between the bitumen molecules. This interaction reduces the rate of bitumen spreading at the water surface. 33 refs., 2 tabs., 12 figs.

  3. Observations and morphological analysis of supermolecular structure of natural bitumens by atomic force microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Yevgeny A. Golubev; Olga V. Kovaleva; Nikolay P. Yushkin [Institute of Geology of RAS, Syktyvkar (Russian Federation)

    2008-01-15

    The supermolecular structures of natural bitumens of the thermal consequent row asphaltites lower kerites (albertites), higher kerites (impsonites), anthraxolites from the Timan-Pechora petroleum province and Karelian shungite rocks, Russia, were studied in details. The experimental technique used was atomic force microscopy (AFM), following fracture preparation. The element distribution of the sample surfaces was analyzed by an X-ray microanalyser 'Link ISIS', combined with a scanning electron microscope (SEM). In this work, we characterized the supermolecular evolution of natural solid bitumens in the carbonization sequence by quantitative parameters. We showed that supermolecular structure can be important in defining to which classification group solid bitumens belong. 29 refs., 7 figs., 2 tabs.

  4. Diluent and bitumen, an uneasy mix : considerations for treating, blending, transportation, marketing and refining

    Energy Technology Data Exchange (ETDEWEB)

    Todd, C. [Connacher Oil and Gas Ltd., Calgary, AB (Canada)

    2009-07-01

    This presentation evaluated several issues regarding the use of diluent as a blending agent with Canadian bitumen. Heavy and viscous crude oils are commonly diluted with condensates and gasolines. This improves field processing, transportability in pipelines and acceptability in markets and refineries. The demand for such diluent is increasing because of the large amounts of heavy oil and bitumen currently produced in Canada. The current tenable price of diluents has meant that a wide range of diluent sources and components are finding their way into the Canadian diluent supply stream. This has raised concerns regarding diluent performance and the affect on blended crude oils. The cost of diluent is among the most controllable expense associated with most bitumen production projects. Market factors were considered in this presentation, such as supply demand; price and infrastructure; operational processing and blending issues; diluent quality and component variability; and downstream issues such as refinery processing and production. tabs., figs.

  5. Performance Test for Open Grade Bitumen and Cement Mixture OGBC-20

    Science.gov (United States)

    Li, Y. Y.; Wu, Z. L.; Li, C. M.; Gan, X. Z.; Xiong, X. J.

    For effective prevention of urban road intersection special sections for nit diseases and improving the pavement durability, an open grade bitumen and cement (OGBC-20) mixture is proposed. In organic hydraulic cement mixture design, mix proportion designs of cement mortar and matrix open-graded bitumen were done. The matrix mixture gradation was adjusted .It has greater void of air volume than that of ATPB-25. A variety of tests in laboratory for OGBC-20 were performed. The experimental results show that: The void of air volume of adjusted gradation matrix asphalt mixture is up to 23%. and binder drainage loss is ≤ 0.3%. Cement mortar filling is fuller and better water stability and low temperature crack resistance compared to ordinary bitumen mixture. It has the absolute advantage on high temperature stability and shows the superiority of the new pavement materials.

  6. Modification of Bitumen with Desulfurized Crumb Rubber in the Present of Reactive Additives

    Institute of Scientific and Technical Information of China (English)

    YE Zhigang; ZHANG Yuzhen; KONG Xianming

    2005-01-01

    Bitumen was modified with desulfurized crumb rubber (DCR) in the present of reactive additives. The effect of the kinds and content of the reactive additive on properties of DCR modified bitumen (DCRMB) was investigated. The morphology of DCRMB was characterized by SEM and the changes of the chemical structure of DCRMB without and with the addition of the reactive additive were analyzed by FTIR. The experimented results show that the softening point,the elasticity recovery and the storage stability of DCRMB were improved significantly by the addition of the reactive additive. This is because that a network structure of rubber in DCRMB was formed and the chemical reaction between C=C double bonds in bitumen and DCR has happened after the reactive additive was added into DCRMB.

  7. Effects of Different Ultrasound Irradiation Frequencies and Water Temperatures on Extraction Rate of Bitumen from Oil Sand

    Science.gov (United States)

    Okawa, Hirokazu; Saito, Tomonao; Hosokawa, Ryota; Nakamura, Takashi; Kawamura, Youhei; Sugawara, Katsuyasu

    2010-07-01

    Low (28 kHz) and high (200 kHz) frequency sonication combined with hot water treatments at 45 and 75 °C were investigated to assess the effects of different ultrasound frequencies and water temperatures on the extraction of bitumen from oil sand. A mechanical stirrer was also used to compare the efficiency of separation. Bitumen extraction tests were performed under argon, air, and nitrogen atmospheres. Sonication at 200 kHz was shown to extract bitumen effectively from oil sand at 75 °C. The bitumen extraction rate for sonication at 200 kHz was slightly higher than that at 28 kHz. For low temperature (45 °C) solutions, only sonication at 28 kHz could extract bitumen from oil sand, demonstrating that sonication at 28 kHz can effectively breakdown the oil sand aggregates into a suspension.

  8. Sterane distribution of solid bitumen pyrolyzates. Changes with biodegradation of crude oil in the Ouachita Mountains, Oklahoma

    Science.gov (United States)

    Curiale, J.A.; Harrison, W.E.; Smith, G.

    1983-01-01

    Solid bitumens (grahamite and impsonite) of southeastern Oklahoma have been shown to originate from near-surface alteration of crude oil (Curiale, 1981; Curiale and Harrison, 1981). Pyrolysis of these solids has been employed to compare the sterane distribution of geographically proximate oils to that of the bitumens. The ratio of rearranged to regular steranes is higher in the pyrolyzates than in the oils, a finding consistent with a bitumen origin due to biodegradation of oil. The remaining presence of steranes, particularly regular steranes, in the bitumens suggests that sterane occlusion may have occurred prior to or during the alteration process, thus removing tetracyclic compounds from the influence of microbial attack. These data suggest that pyrolysis- GC MS offers a viable approach to correlation problems involving solid bitumens. ?? 1983.

  9. Foamed Bitumen Decay Equation and Bitumen Foaming Characteristics Evaluation%泡沫沥青衰变方程与发泡特性评价

    Institute of Scientific and Technical Information of China (English)

    李峰; 黄颂昌; 徐剑

    2011-01-01

    The expansion ratio and the half-life are usually utilized to evaluate the characteristics of foamed bitumen at present, but it' s hard to determine the optimum foaming parameters due to lack of definite numerical evaluation criteria. Therefore,an index is developed in this study to solve the problem. One of the existing decay equations is chosen as the basic form of the foamed bitumen decay equation. Then the general equation is derived by differential for the actual maximum expansion ratio, and a general decay equation is obtained with corrected boundary conditions of foamed bitumen decay. The foam energy index is defined from the view of energy,and the index formula is derived by integral. The foaming test data of four kinds of bitumen used in actual works are analyzed. The result shows that the foam energy index quantifies the bitumen foaming characteristics with a clear physical meaning, and it can be used to determine the optimum foaming parameters and evaluate the characteristics of different foamed bitumen.%目前常用膨胀率和半衰期指标来评价沥青的发泡特性,由于缺乏明确的数值评价标准,有时难以判断最佳发泡参数.比较了现有的4种衰变方程,选定了泡沫沥青衰变方程的基本形式,应用微分方法推导出实际最大膨胀率的通式,由泡沫沥青衰变的边界条件修正得到标准衰变方程,从能量角度出发定义了泡沫能量指标,通过积分给出了计算公式.对实际工程所用4种沥青的发泡试验数据进行分析,泡沫能量指标物理意义明确,量化了沥青的发泡特性,既可确定沥青的最佳发泡参数,又可评价不同沥青的发泡特性.

  10. 防水鞋面革和防水变色革的水性涂饰%Aqueous Finishing of Waterproof Shoe Upper Leathers and Waterproof Pull-ups

    Institute of Scientific and Technical Information of China (English)

    Hartmut Huber

    2009-01-01

    详细介绍了防水鞋面革和防水变色革的涂饰方法,包括坯革的准备、粘合层、底涂、顶涂过程中产品的选择和过程参数的确定,以及涂饰过程中的注意事项.%The finishing technology of waterproof shoe upper leathers and waterproof pull-ups were introduced in detail,in-cluding preparation of crust,products choice and process parameters of adhesion coating,base coating and top finishing,as well as the key problems in the finishing process.

  11. Urinary metabolites of polycyclic aromatic hydrocarbons in workers exposed to vapours and aerosols of bitumen.

    Science.gov (United States)

    Pesch, Beate; Spickenheuer, Anne; Kendzia, Benjamin; Schindler, Birgit Karin; Welge, Peter; Marczynski, Boleslaw; Rihs, Hans-Peter; Raulf-Heimsoth, Monika; Angerer, Jürgen; Brüning, Thomas

    2011-06-01

    Urinary hydroxylated metabolites of polycyclic aromatic hydrocarbons (PAH) were investigated as potential biomarkers of bitumen exposure in a cross-shift study in 317 exposed and 117 non-exposed workers. Personal measurements of the airborne concentration of vapours and aerosols of bitumen during a working shift were weakly associated with post-shift concentrations of 1-hydroxypyrene (1-OHP) and 1-, 2+9-, 3- and 4-hydroxyphenanthrenes (further referred to their sum as OHPHE), but not 1- and 2-hydroxynaphthalene (OHNA). Smoking showed a strong influence on the metabolite concentrations, in particular on OHNA. Pre-shift concentrations of 1-OHP and OHPHE did not differ between the study groups (P = 0.16 and P = 0.89, respectively). During shift, PAH metabolite concentrations increased in exposed workers and non-exposed smokers. Statistical modelling of post-shift concentrations revealed a small increase in 1-OHP by a factor of 1.02 per 1 mg/m(3) bitumen (P = 0.02) and 1.04 for OHPHE (P < 0.001). A group difference was observed that was diminished in non-smokers. Exposed non-smokers had a median post-shift 1-OHP concentration of 0.42 μg/l, and non-smoking referents 0.13 μg/l. Although post-shift concentrations of 1-OHP and OHPHE were slightly higher than those in the general population, they were much lower than in coke-oven workers. The small content of PAHs in vapours and aerosols of bitumen, the increasing use of additives to asphalt mixtures, the strong impact of smoking and their weak association with airborne bitumen limit the use of PAH metabolites as specific biomarkers of bitumen exposure.

  12. Elevated cancer mortality in a German cohort of bitumen workers: extended follow-up through 2004.

    Science.gov (United States)

    Behrens, Thomas; Schill, Walter; Ahrens, Wolfgang

    2009-09-01

    The mortality follow-up in a cohort of German asphalt workers covered an additional 6 years. Male workers (N = 7919) were classified into four exposure categories: (1) exposure to bitumen only, (2) to bitumen and coal tar, (3) neither to tar nor to bitumen, and (4) unknown exposure. Exposure-specific standardized mortality ratios (SMR) and associated 95% confidence intervals (CI) based on age- and calendar period-specific national mortality rates were calculated. To compare exposed and unexposed workers, relative risks were estimated by Poisson regression. By the end of 2004, 835 workers had died. The SMR for lung cancer was 1.77 (95% CI 1.46-2.16). Head and neck cancer showed an SMR of 2.36 (95% CI 1.78-3.07). Bladder cancer mortality was elevated threefold. Significantly elevated cancer-related SMRs were also found for all malignant tumors. In addition, elevated mortality rates of nonmalignant causes such as alcoholism, liver cirrhosis, and unnatural causes of deaths including accidents were observed. After stratification by exposure group, cancer mortality was elevated among bitumen-exposed and unexposed subjects. In the internal analysis, the association between lung cancer and bitumen exposure was weakened as compared with the previous follow-up (relative risk [RR] = 1.15; 95% CI 0.72-1.84). The follow-up demonstrated an excess of cancer in this cohort of asphalt workers. However, the observed mortality patterns were not clear. Although exposure to bitumen cannot be ruled out as being responsible for the observed results, a higher prevalence of alcohol and tobacco consumption may partially explain the observed risk increases. Exposure assessment in future studies should account for multiple occupational agents and nonoccupational factors to rule out that the observed differences in SMR are not due simply to random variation.

  13. Waste reduction algorithm used as the case study of simulated bitumen production process

    Directory of Open Access Journals (Sweden)

    Savić Marina A.

    2011-01-01

    Full Text Available Waste reduction algorithm - WAR is a tool helping process engineers for environmental impact assessment. WAR algorithm is a methodology for determining the potential environmental impact (PEI of a chemical process. In particular, the bitumen production process was analyzed following three stages: a atmospheric distillation unit, b vacuum distillation unit, and c bitumen production unit. Study was developed for the middle sized oil refinery with capacity of 5000000 tones of crude oil per year. Results highlight the most vulnerable aspects of the environmental pollution that arise during the manufacturing process of bitumen. The overall rates of PEI leaving the system (PEI/h - Iout PEI/h are: a 2.14105, b 7.17104 and c 2.36103, respectively. The overall rates of PEI generated within the system - Igen PEI/h are: a 7.75104, b -4.31104 and c -4.32102, respectively. Atmospheric distillation unit have the highest overall rate of PEI while the bitumen production unit have the lowest overall rate of PEI. Comparison of Iout PEI/h and Igen PEI/h values for the atmospheric distillation unit, shows that the overall rate of PEI generated in the system is 36.21% of the overall rate of PEI leaving the system. In the cases of vacuum distillation and bitumen production units, the overall rate of PEI generated in system have negative values, i.e. the overall rate of PEI leaving the system is reduced at 60.11% (in the vacuum distillation unit and at 18.30% (in the bitumen production unit. Analysis of the obtained results for the overall rate of PEI, expressed by weight of the product, confirms conclusions.

  14. Terrestrial bitumen analogue of orgueil organic material demonstrates high sensitivity to usual HF-HCl treatment

    Science.gov (United States)

    Korochantsev, A. V.; Nikolaeva, O. V.

    1993-01-01

    The relationship between the chemical composition and the interlayer spacing (d002) of organic materials (OM's) is known for various terrestrial OM's. We improved this general trend by correlation with corresponding trend of natural solid bitumens (asphaltite-kerite-anthraxolite) up to graphite. Using the improved trend we identified bitumen analogs of carbonaceous chondrite OM's residued after HF-HCl treatment. Our laboratory experiment revealed that these analogs and, hence, structure and chemical composition of carbonaceous chondrite OM's are very sensitive to the HF-HCl treatment. So, usual extraction of OM from carbonaceous chondrites may change significantly structural and chemical composition of extracted OM.

  15. Study on low temperature performance of Gussasphalt on steel decks with hard bitumen

    Institute of Scientific and Technical Information of China (English)

    YangJun

    2003-01-01

    Using a Hamburg wheel-traek test device, the resistance to rutting of Gussasphalt is tested and compared.Gussasphalt with hard bitumen has good resistance to rutting. The related resistance abilities to cracking at low temperature of Gussasphalt are tested and compared through flexural experiments and the composite structure fatigue test with temperature dropping. Gussasphalt with high pedormanee polymer modified bitumen has a longer fatigue life and a lower breaking temperature; they can be used in the future sudaces for steel bridge decks in Germany.

  16. Reflectance measurements of zooclasts and solid bitumen in Lower Paleozoic shales, southern Scandinavia

    DEFF Research Database (Denmark)

    Petersen, Henrik I.; Schovsbo, Niels H.; Nielsen, Arne T.

    2013-01-01

    to that of graptolites at the same level of maturity. Reflectance measurements of solid bitumen are a poor maturity indicator, probably because bitumen can have various origins and morphologies and it may not be indigenous to the host rock. (C) 2013 Elsevier B.V. All rights reserved.......-Lower Paleozoic rocks containing vitrinite, starts, accordingly, at 1.56% R-o graptolite reflectance. Porous/granular vitrinite-like particles occur in minor amounts and they may represent graptolite fragments with a non-smooth surface. They generally yield slightly higher reflectance than non-granular vitrinite...

  17. Effect of Ultraviolet Aging on Rheology and Chemistry of LDH-Modified Bitumen

    OpenAIRE

    Xing Liu; Shaopeng Wu; Gang Liu; Liping Li

    2015-01-01

    Layered double hydroxides (LDHs) are an ultravioletlight (UV)-resistant material. In this study, two types of LDHs (Mg-Al-LDHs and Zn-Al-LDHs) were applied to modify bitumen by melt-blending. The effect of ultraviolet aging on the rheology and chemistry of LDH-modified bitumen was studied by means of dynamic shear rheometer (DSR), thin-layer chromatography with flame ionization detection (TLC-FID), Fourier transform infrared spectroscopy (FTIR), and Ultraviolet-Visible (UV-Vis) spectrophotome...

  18. Upstream petroleum industry flaring and venting report : industry performance for year ending December 31, 2005

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-10-15

    This report provided statistical data concerning solution gas flaring and venting in the upstream petroleum industry in Alberta. In their 2003 Upstream Petroleum Industry Flaring and Venting Report, the Alberta Energy and Utilities Board (EUB) made commitments to identify and implement a number of conservation measures aimed at reducing the volumes of solution gas vented from crude bitumen operations. As a result of the measures, venting from crude bitumen batteries decreased by 18.9 per cent in 2005. Solution gas conservation for 2005 was 96.3 per cent, the highest conservation level achieved to date. Solution gas flaring for 2005 was 71.9 per cent less than the 1996 baseline. A slight increase in solution gas flaring was attributed to crude bitumen operations. Solution gas venting for 2005 was 58.6 per cent less than the 2000 venting baseline. An analysis of the data suggested that significant progress has been made in reducing solution gas flaring in Alberta, and that venting reductions realized in 2005 continue the trend of significant reductions since 2000. Although the downward trend in the reduction of venting since 2000 is encouraging, the EUB continues to be concerned about solution gas venting associated with crude bitumen projects. It was concluded that the EUB will continue to work with all stakeholders to identify additional venting reduction strategies. 5 tabs., 3 figs.

  19. Investigation of the Self-Healing Behaviors of Microcapsules/Bitumen Composites by a Repetitive Direct Tension Test

    Directory of Open Access Journals (Sweden)

    Jun-Feng Su

    2016-07-01

    Full Text Available The aim of this work was to evaluate the self-healing behaviors of bitumen using microcapsules containing rejuvenator by a modified fracture healing–refracture method through a repetitive tension test. Microcapsules had mean size values of 10, 20 and 30 μm with a same core/shell ratio of 1/1. Various microcapsules/bitumen samples were fabricated with microcapsule contents of 1.0, 3.0 and 5.0 wt. %, respectively. Tension strength values of microcapsules/bitumen samples were measured by a reparative fracture-healing process under different temperatures. It was found that these samples had tensile strength values larger than the data of pure bitumen samples under the same conditions after the four tensile fracture-healing cycles. Fracture morphology investigation and mechanism analysis indicated that the self-healing process was a process consisting of microcapsules being broken, penetrated and diffused. Moreover, the crack healing of bitumen can be considered as a viscosity driven process. The self-healing ability partly repaired the damage of bitumen during service life by comparing the properties of virgin and rejuvenated bitumen.

  20. Influence of Polyphosphoric Acid on the Consistency and Composition of Formulated Bitumen: Standard Characterization and NMR Insights

    Science.gov (United States)

    Varanda, Catarina; Ribeiro, Jorge

    2016-01-01

    Over the recent years, bitumen modification with polymers, acids, or mineral fillers has gained relevance to adjust its performance properties. This work reports the use of polyphosphoric acid (PPA) for the modification of formulated bitumen. With this objective, an in-depth literature review on PPA modification was firstly performed. Subsequently, five individual refinery components were selected for the preparation of bitumen blends, namely, asphaltic residue, vacuum residue, and three lube oils extracts. Seven binary/ternary bitumen blends were prepared and then treated with PPA. Afterwards, the five components and the unmodified and PPA-modified bitumen were characterized by standard methods (penetration, softening point, and penetration index), SARA analysis, elemental analysis, and 31P and 1H nuclear magnetic resonance (NMR) spectroscopy. The results evidenced higher asphaltenes and lower saturates/resins contents in PPA-modified bitumen. The NMR data suggest that the paraffinic chains became longer, the content of condensed aromatics increased, more substituted aromatic structures appeared, and α-hydrogen in aromatic structures diminished. These findings disclosed the improved consistency and oxidation stability of PPA-modified bitumen blends. PMID:27579214

  1. Influence of Polyphosphoric Acid on the Consistency and Composition of Formulated Bitumen: Standard Characterization and NMR Insights.

    Science.gov (United States)

    Varanda, Catarina; Portugal, Inês; Ribeiro, Jorge; Silva, Artur M S; Silva, Carlos M

    2016-01-01

    Over the recent years, bitumen modification with polymers, acids, or mineral fillers has gained relevance to adjust its performance properties. This work reports the use of polyphosphoric acid (PPA) for the modification of formulated bitumen. With this objective, an in-depth literature review on PPA modification was firstly performed. Subsequently, five individual refinery components were selected for the preparation of bitumen blends, namely, asphaltic residue, vacuum residue, and three lube oils extracts. Seven binary/ternary bitumen blends were prepared and then treated with PPA. Afterwards, the five components and the unmodified and PPA-modified bitumen were characterized by standard methods (penetration, softening point, and penetration index), SARA analysis, elemental analysis, and (31)P and (1)H nuclear magnetic resonance (NMR) spectroscopy. The results evidenced higher asphaltenes and lower saturates/resins contents in PPA-modified bitumen. The NMR data suggest that the paraffinic chains became longer, the content of condensed aromatics increased, more substituted aromatic structures appeared, and α-hydrogen in aromatic structures diminished. These findings disclosed the improved consistency and oxidation stability of PPA-modified bitumen blends.

  2. Bitumen modification with a low-molecular-weight reactive isocyanate-terminated polymer

    Energy Technology Data Exchange (ETDEWEB)

    F.J. Navarro; P. Partal; M. Garcia-Morales; F.J. Martinez-Boza; C. Gallegos [Universidad de Huelva, Huelva (Spain). Departamento de Ingenieria Quimica, Facultad de Ciencias Experimentales

    2007-10-15

    A low-molecular-weight polyethyleneglycol functionalized with a polymeric MDI (4,4'-diphenylmethane diisocynate) was used as a modifying agent for a 60/70 penetration grade bitumen. The rheological properties of the resulting modified binder, at both low and intermediate temperatures, before and after curing at room temperature were studied and compared with those corresponding to a SBS modified bitumen. The analysis showed that the addition of a small quantity of this reactive polymer leads to enhanced rheological properties mainly at high in-service temperature (50{sup o}C). However, modification was found to be rather slow during binder curing at room temperature. Moreover, storage stability analysis showed that phase separation did not take place after bitumen storage at 163{sup o}C, though storage at high temperature affects the modification capability of the reactive polymer. Atomic force microscopy measurements showed that the reactive polymer addition leads to asphaltene-rich regions with lower thermal susceptibility, which are present even at high temperature, yielding an improved bitumen viscosity in this range of in-service temperatures. 38 refs., 7 figs., 2 tabs.

  3. Electro-thermal dynamic stripping process : integrating environmentalism with bitumen production

    Energy Technology Data Exchange (ETDEWEB)

    McGee, B.C.W.; McDonald, C.W. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[E-T Energy, Calgary, AB (Canada); Little, L. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Alberta Energy Research Inst., Edmonton, AB (Canada)

    2008-10-15

    This paper presented a new method of in situ oil sands extraction developed by Calgary-based E-T Energy. The Electro-Thermal Dynamic Stripping Process (ET-DSP) uses electricity to melt oil sands deposits that are too deep for open pit mining. The energy intensity of production compares favourably with alternative thermal bitumen extraction techniques and water consumption for the process is comparatively low, with all produced water being re-injected into the producing formation without any treatment. With ET-DSP, electrodes are drilled and completed next to the oil sands formation which ensures that the electrical currents are forced to flow to the oil sands formation. The viscosity of the bitumen is lowered by the heat from the current, thereby making the fluid flow more readily into vertical extraction wells. ET-DSP uses electricity directly from the power grid, and does not produce any greenhouse gas (GHG) emissions of its own. The process has the potential to allow operators to focus on areas of oil sands reservoirs that have remained inaccessible. Field studies confirmed that the production of bitumen using this method was achieved with reduced greenhouse gas emissions as compared to other thermal recovery process. The bitumen had trace amount of sand and no emulsions. 5 refs., 5 figs.

  4. In-situ water vaporization improves bitumen production during electrothermal processes

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J. [Calgary Univ., AB (Canada); McGee, B. [E-T Energy, Calgary, AB (Canada); Kantzas, A. [Calgary Univ., AB (Canada). Tomographic Imaging and Porous Media Laboratory

    2008-10-15

    Electro-thermal processes are now being considered as an alternative or complementary process to steam injection processes. This study used an in situ vaporized water process to optimize electrothermal processes for steam injection enhanced oil recovery (EOR). A simulation tool was used to model electro-thermal processes in an Athabasca oil sands reservoir. Incremental oil recovery was estimated based on a 3-block conceptual model. A field scale model was then used to investigate the effects of electrode spacing, water injection rates, and electrical heating rates on bitumen recovery. Results of the simulation studies were then analyzed using a statistical tool in order to determine optimal conditions for maximizing bitumen production. Results of the study showed that incremental recovery using the water vaporization technique resulted in oil recovery rates of 25 per cent original oil in place (OOIP). Sensitivity analyses showed that medium electrical heating rates, low water injection rates, and small spacings between electrodes maximized bitumen production rates. It was concluded that the technique can be used alone or combined with other methods to economically produce bitumens. 2 refs., 7 tabs., 9 figs.

  5. Laboratory investigation of bitumen based on round robin DSC and AFM tests

    NARCIS (Netherlands)

    Soenen, H.; Besamusca, J.; Fischer, H.R.; Poulikakos, L.D.; Planche, J.P.; Das, P.K.; Kringos, N.; Grenfell, J.R.A.; Lu, X.; Chailleux, E.

    2014-01-01

    In the past years a wide discussion has been held among asphalt researchers regarding the existence and interpretation of observed microstructures on bitumen surfaces. To investigate this, the RILEM technical committee on nano bituminous materials 231-NBM has conducted a round robin study combining

  6. Phase-Separation Characteristics of Bitumen and their Relation to Damage-Healing

    NARCIS (Netherlands)

    Nahar, S.N.

    2016-01-01

    During the service life of flexible asphalt pavements, asphalt concrete degrades due to traffic loading and environmental conditions like temperature, rain, oxidation, ultraviolet-radiation from the sun. All these environmental factors have adverse effects on the performance of bitumen, which is the

  7. Solubility of methane, nitrogen, and carbon dioxide in bitumen and water for SAGD modelling

    Energy Technology Data Exchange (ETDEWEB)

    Al-Murayri, M.T.; Harding, T.G.; Maini, B.B.

    2011-07-15

    The steam assisted gravity-drainage (SAGD) process is a technology used in unconventional reservoirs to enhance oil recovery, this technique sometimes uses the co-injection of noncondensable gases (NCGs). The co-injection of NCGs with steam is used to reduce energy consumption and greenhouse gas emissions in SAGD, but this technique also affects the performance of SAGD, making the knowledge of gas solubility in bitumen and water important. This study was undertaken to develop a systematic approach to predict the K-values for the gas-bitumen and gas water phase equilibria at different temperatures and pressures. This research has been carried out by using different existing correlations. It has been observed that the Mehrotra and Svrcek gas-solubility correlation should be used to calculate NCG's solubility in bitumen and that NCGs' solubility in water could be calculated with Harvey's correlation. This study defined successfully an approach to calculate NCGs' solubility in bitumen and water.

  8. Chemical modification of bitumen heavy ends and their non-fuel uses

    Energy Technology Data Exchange (ETDEWEB)

    Moschopedis, S.E.; Speight, J.G.

    1976-01-01

    Bitumen asphaltenes undergo a variety of simple chemical conversions. For example, asphaltenes can be oxidized, sulfonated, sulfomethylated, halogenated, and phosphorylated. The net result is the introduction of functional entities into the asphaltene structure which confers interesting properties on the products for which a variety of uses are proposed.

  9. Tire-tread and bitumen particle concentrations in aerosol and soil samples

    DEFF Research Database (Denmark)

    Fauser, Patrik; Tjell, Jens Christian; Mosbæk, Hans;

    2002-01-01

    ire and bitumen particle concentrations are determined in aerosol and soil samples. They each constitute about 5 wt-% of the total suspended particulate matter (TSP) in inner city air, collected with a Berner low pressure impactor, 5 m from a road. The particle size distribution shows that 92% of...

  10. Towards the Development of Bitumen Carbonates: An Integrated Analysis of Grosmont Steam Pilots

    Directory of Open Access Journals (Sweden)

    Ezeuko C.C.

    2015-11-01

    Full Text Available The Grosmont Formation in Alberta, Canada is a highly fractured, karstified and vuggy bitumen-rich carbonate reservoir located west of and below the Athabasca oil sands deposit. The bitumen carbonate platform extends about 500 km in length and up to 150 km in width and contains an estimated 64.5 billion m3 (406.5 billion barrels of oil. The Grosmont Formation is larger than the combined total of all other known carbonate bitumen deposits in the world. Here, we analyze early Grosmont steam pilots to improve the design of future pilots and commercial development of this massive bitumen deposit. In agreement with the conclusions of earlier analysis of these Grosmont pilots, they were reasonably successful considering the heterogeneous nature of the Grosmont Formation. Operational factors such as poor steam quality, non-optimized high injection pressures and completion issues appear to have heavily impacted recovery performances. Clearly, steam-based recovery operations have good potential for Grosmont, especially considering that it is mature commercial technology. Following an integrated analysis of early Grosmont pilots, we posit that Cyclic Steam Stimulation (CSS using horizontal wells exhibits greater potential for the development of Grosmont carbonate, compared with Steam-Assisted Gravity Drainage technology (SAGD.

  11. How Thermal Fatigue Cycles Change the Rheological Behavior of Polymer Modified Bitumen?

    NARCIS (Netherlands)

    Glaoui, B.; Merbouh, M.; Van de Ven, M.F.C.; Chailleux, E.; Youcefi, A.

    2013-01-01

    The paper deals with the problem of thermal fatigue cycles phenomenon, which affects the performance of flexible pavement. The purpose of the paper is to extent the knowledge on the rheology of polymer modified bitumen which was affected by cycles of thermal fatigue. The aim of this research is to d

  12. Specifying, Installing and Maintaining Built-Up and Modified Bitumen Roofing Systems.

    Science.gov (United States)

    Hobson, Joseph W.

    2000-01-01

    Examines built-up, modified bitumen, and hybrid combinations of the two roofing systems and offers advise on how to assure high- quality performance and durability when using them. Included is a glossary of commercial roofing terms and asphalt roofing resources to aid in making decisions on roofing and systems product selection. (GR)

  13. 广州地铁车站暗挖隧道防水施工技术%Waterproofing Construction Technology for Subsurface- excavated Tunnel of Guangzhou Metro Station

    Institute of Scientific and Technical Information of China (English)

    祝和意

    2011-01-01

    研究目的:隧道工程防水施工历来是隧道施工的难点与重点.而防排水施工的成功与否,直接关系到隧道工程的质量及使用寿命.特别是地铁车站暗挖隧道其防水施工的难度更大,对工程质量和施工安全影响重大.因此,对地铁暗挖隧道的防水施工关键技术进行研究,确保隧道工程质量、使用寿命和运营安全就显得尤为重要.本文以广州地铁车站暗挖隧道防水施工为例,对地铁车站暗挖隧道防水施工关键技术进行探讨分析.研究结论:暗挖隧道防水施工成败的关键在于选择合理的防水施工体系.本隧道防水施工采取全包防水方式即以结构自防水为主,外防水(附加防水)为辅的施工方案,重点抓好结构自防水混凝土施工质量,关键处理好施工缝、变形缝、穿墙管、结构预留孔等薄弱环节的防水质量,使隧道防水施工取得了良好的效果,保证了隧道工程质量和施工安全.%Research purposes: Tunnel waterproofing construction is always a difficult and crucial work in construction of tunnel.The waterproofing quality of tunnel directly influences the tunnel construction quality and the tunnel service life.The waterproofing engineering of metro subsurface - excavated tunnel is more difficult, and its engineering quality has more influence on the tunnel construction quality and safety.So it is very important to do the research on the waterproofing construction technology for metro subsurface- excavated tunnel to guarantee the construction quality,service life and operational safety of tunnel.This paper discusses and anlyzes the key waterproofing construction technologies for the subsurface -excavated tunnel of Guangzhou metro station.Research conclusions:Whether the waterproofing construction system is reasonable or not is crucial to the waterproofing construction of the subsurface - excavated tunnel.The full waterproofing way was adopted to this tunnel.That was to take

  14. Irritative effects of vapours and aerosols of bitumen on the airways assessed by non-invasive methods.

    Science.gov (United States)

    Raulf-Heimsoth, Monika; Pesch, Beate; Kendzia, Benjamin; Spickenheuer, Anne; Bramer, Rainer; Marczynski, Boleslaw; Merget, Rolf; Brüning, Thomas

    2011-06-01

    Irritative effects caused by vapours and aerosols of bitumen were assessed by non-invasive methods including spirometry, nasal lavage fluid (NALF) and induced sputum (IS) in a cross-shift study comparing 320 bitumen-exposed workers with 118 road construction workers as the reference group. Lung function parameters, forced vital capacity (FVC) and forced expiratory volume in one second (FEV(1)) were within normal ranges in both the reference and the bitumen-exposed groups pre- and post-shift with marginally lower values in smokers of both groups. During the shift, a slight decline in FEV(1) and FVC was observed in the bitumen-exposed group independent of their smoking habits, whereas in the non-smoking reference group, the decline in FEV(1) was not observed. No significant differences between bitumen-exposed workers and the reference group and no significant shift effect were observed on the upper airways using NALF analysis. The IS concentrations of interleukin (IL)-8, total protein and matrix metalloproteinase-9 were significantly higher in bitumen-exposed workers than in the reference group. However, the concentration of these three biomarkers in the IS samples, which are indicators of inflammatory effects on the lower airways of bitumen-exposed workers, was already higher in exposed workers before shift and did not show an increase during the shift. Therefore, the key finding of this aspect of the Human Bitumen Study is the detection of potentially (sub-) chronic irritative inflammatory effects in the lower airways of bitumen-exposed workers.

  15. Bitumen recovery from oil sands using deep eutectic solvent and its aqueous solutions

    Science.gov (United States)

    Pulati, Nuerxida

    Oil sands compose a significant proportion of the world's known oil reserves. Oil sands are also known as tar sands and bituminous sands, are complex mixtures of sand, clays, water and bitumen, which is "heavy" and highly viscous oil. The extraction and separation of bitumen from oil sands requires significant amount of energy and large quantities of water and poses several environmental challenges. Bitumen can be successfully separated from oil sands using imidazolium based ionic liquids and nonpolar solvents, however, ionic liquids are expensive and toxic. In this thesis, the ionic liquid alternatives- deep eutectic solvent, were investigated. Oil sands separation can be successfully achieved by using deep eutectic solvents DES (choline chloride and urea) and nonpolar solvent naphtha in different types of oil sands, including Canadian ("water-wet"), Utah ("oil-wet") and low grade Kentucky oil sands. The separation quality depends on oil sands type, including bitumen and fine content, and separation condition, such as solvent ratio, temperature, mixing time and mechanical centrifuge. This separation claims to the DES ability to form ion /charge layering on mineral surface, which results in reduction of adhesion forces between bitumen and minerals and promote their separation. Addition of water to DES can reduce DES viscosity. DES water mixture as a media, oil sands separation can be achieved. However, concentration at about 50 % or higher might be required to obtain a clear separation. And the separation efficiency is oil sands sample dependent. The highest bitumen extraction yield happened at 75% DES-water solution for Utah oil sands samples, and at 50 60% DES-water solutions for Alberta oil sands samples. Force curves were measured using Atomic Force Microscopy new technique, PeakForce Tapping Quantitative Nanomechanical Mapping (PFTQNM). The results demonstrate that, by adding DES, the adhesion force between bitumen and silica and dissipation energy will

  16. Ovarian dual oxidase (Duox) activity is essential for insect eggshell hardening and waterproofing.

    Science.gov (United States)

    Dias, Felipe A; Gandara, Ana Caroline P; Queiroz-Barros, Fernanda G; Oliveira, Raquel L L; Sorgine, Marcos H F; Braz, Glória R C; Oliveira, Pedro L

    2013-12-06

    In insects, eggshell hardening involves cross-linking of chorion proteins via their tyrosine residues. This process is catalyzed by peroxidases at the expense of H2O2 and confers physical and biological protection to the developing embryo. Here, working with Rhodnius prolixus, the insect vector of Chagas disease, we show that an ovary dual oxidase (Duox), a NADPH oxidase, is the source of the H2O2 that supports dityrosine-mediated protein cross-linking and eggshell hardening. RNAi silencing of Duox activity decreased H2O2 generation followed by a failure in embryo development caused by a reduced resistance to water loss, which, in turn, caused embryos to dry out following oviposition. Phenotypes of Duox-silenced eggs were reversed by incubation in a water-saturated atmosphere, simultaneous silencing of the Duox and catalase genes, or H2O2 injection into the female hemocoel. Taken together, our results show that Duox-generated H2O2 fuels egg chorion hardening and that this process plays an essential role during eggshell waterproofing.

  17. Transparent, self-cleaning and waterproof surfaces with tunable micro/nano dual-scale structures

    Science.gov (United States)

    Lee, Yujin; You, Eun-Ah; Ha, Young-Geun

    2016-09-01

    The rational design and facile fabrication of optically transparent, superhydrophobic surfaces can advance their versatile applications, including optoelectronic devices. For the easily accessible and scalable preparation of transparent, superhydrophobic surfaces, various coating methods using a solution-process have been developed. However, obtaining highly transparent, non-wetting surfaces with excellent properties is challenging due to the difficulty in controlling surface roughness. Here, we report on a novel approach to control the surface roughness by fabricating tailorable micro/nano dual-scale surface structures via solution-processed nanoparticle coating. The surface roughness was able to be controlled by micro/nano dual-scale structures that can be manipulated by varying the mixture ratio of two different sizes of Al2O3 nanoparticles. The controllable micro/nano dual-scale structures were optimized to achieve the superior surface properties in both hydrophobicity and transparency, exhibiting a high water contact angle (>160°), low sliding angle (90%). These characteristics allowed an excellent transparency and self-cleaning capability as well as a superior waterproof ability even under applied voltage. Furthermore, we demonstrated the versatile applicability of the developed surface-coating method to a wide range of substrates including glass, paper, fabrics, and even flexible plastics.

  18. Radial patterns of bitumen dykes around Quaternary volcanoes, provinces of northern Neuquén and southernmost Mendoza, Argentina

    Science.gov (United States)

    Cobbold, Peter R.; Ruffet, Gilles; Leith, Leslie; Loseth, Helge; Rodrigues, Nuno; Leanza, Hector A.; Zanella, Alain

    2014-12-01

    Where the Neuquén Basin of Argentina abuts the Andes, hundreds of veins of solid hydrocarbon (bitumen) are visible at the surface. Many of these veins became mines, especially in the last century. By consensus, the bitumen has resulted from maturation of organic-rich shales, especially the Vaca Muerta Fm of Late Jurassic age, but also the Agrio Fm of Early Cretaceous age. To account for their maturation, recent authors have invoked regional subsidence, whereas early geologists invoked magmatic activity. During 12 field seasons (since 1998), we have tracked down the bitumen localities, mapped the veins and host rocks, sampled them, studied their compositions, and dated some of them. In the provinces of northern Neuquén and southernmost Mendoza, the bitumen veins are mostly sub-vertical dykes. They tend to be straight and continuous, crosscutting regional structures and strata of all ages, from Jurassic to Palaeocene. Most of the localities lie within 70 km of Tromen volcano, although four are along the Rio Colorado fault zone and another two are at the base of Auca Mahuida volcano. On both volcanic edifices, lavas are of late Pliocene to Pleistocene age. Although regionally many of the bitumen dykes tend to track the current direction of maximum horizontal tectonic stress (ENE), others do not. However, most of the dykes radiate outward from the volcanoes, especially Tromen. Thicknesses of dykes tend to be greatest close to Tromen and where the host rocks are the most resistant to fracturing. Many of the dykes occur in the exhumed hanging walls of deep thrusts, especially at the foot of Tromen. Here the bitumen is in places of high grade (impsonite), whereas further out it tends to be of medium grade (grahamite). A few bitumen dykes contain fragments of Vaca Muerta shale, so that we infer forceful expulsion of source rock. At Curacó Mine, some shale fragments contain bedding-parallel veins of fibrous calcite (beef) and these contain some bitumen, which is

  19. Influence of mineral fillers on the rheological response of polymer-modified bitumens and mastics

    Directory of Open Access Journals (Sweden)

    F. Cardone

    2015-12-01

    Full Text Available The rheological properties of the bituminous components (bitumen and bituminous mastic within asphalt mixtures contribute significantly to the major distresses of flexible pavements (i.e. rutting, fatigue and low temperature cracking. Asphalt mixtures are usually composed of mastic-coated aggregates rather than pure bitumen-coated aggregates. The purpose of this study is to investigate the effects of mineral fillers on the rheological behaviour of several polymer-modified bitumens (PMBs through laboratory mixing. A neat bitumen and two types of polymers (elastomeric and plastomeric were used to produce PMBs, and two fillers with different minerals (limestone and basalt were selected to obtain mastics. The dynamic shear rheometer (DSR and bending beam rheometer (BBR were used to characterize the rheological properties of PMBs and mastics. In particular, multiple stress creep recovery (MSCR tests were performed to evaluate the rutting potential at high temperatures, whereas BBR tests were carried out to investigate the low temperature behaviour of these materials. BBR results for unmodified mastics show that the increase of stiffness is similar regardless of the filler type, whereas results for polymer-modified mastics indicate that the degree of stiffening depends on the combination of filler/polymer types. MSCR results show that adding filler leads to a reduced susceptibility of permanent deformation and an enhanced elastic response, depending on the combination of filler/polymer types. Overall results suggest that a physical–chemical interaction between the filler and bitumen occurs, and that the interaction level is highly dependent on the type of polymer modification.

  20. Roles of Thermophiles and Fungi in Bitumen Degradation in Mostly Cold Oil Sands Outcrops.

    Science.gov (United States)

    Wong, Man-Ling; An, Dongshan; Caffrey, Sean M; Soh, Jung; Dong, Xiaoli; Sensen, Christoph W; Oldenburg, Thomas B P; Larter, Steve R; Voordouw, Gerrit

    2015-10-01

    Oil sands are surface exposed in river valley outcrops in northeastern Alberta, where flat slabs (tablets) of weathered, bitumen-saturated sandstone can be retrieved from outcrop cliffs or from riverbeds. Although the average yearly surface temperature of this region is low (0.7°C), we found that the temperatures of the exposed surfaces of outcrop cliffs reached 55 to 60°C on sunny summer days, with daily maxima being 27 to 31°C. Analysis of the cooccurrence of taxa derived from pyrosequencing of 16S/18S rRNA genes indicated that an aerobic microbial network of fungi and hydrocarbon-, methane-, or acetate-oxidizing heterotrophic bacteria was present in all cliff tablets. Metagenomic analyses indicated an elevated presence of fungal cytochrome P450 monooxygenases in these samples. This network was distinct from the heterotrophic community found in riverbeds, which included fewer fungi. A subset of cliff tablets had a network of anaerobic and/or thermophilic taxa, including methanogens, Firmicutes, and Thermotogae, in the center. Long-term aerobic incubation of outcrop samples at 55°C gave a thermophilic microbial community. Analysis of residual bitumen with a Fourier transform ion cyclotron resonance mass spectrometer indicated that aerobic degradation proceeded at 55°C but not at 4°C. Little anaerobic degradation was observed. These results indicate that bitumen degradation on outcrop surfaces is a largely aerobic process with a minor anaerobic contribution and is catalyzed by a consortium of bacteria and fungi. Bitumen degradation is stimulated by periodic high temperatures on outcrop cliffs, which cause significant decreases in bitumen viscosity.

  1. Assessment of micronuclei in lymphocytes from workers exposed to vapours and aerosols of bitumen.

    Science.gov (United States)

    Welge, Peter; Marczynski, Boleslaw; Raulf-Heimsoth, Monika; Spickenheuer, Anne; Kendzia, Benjamin; Heinze, Evelyn; Angerer, Jürgen; Käfferlein, Heiko U; Pesch, Beate; Brüning, Thomas

    2011-06-01

    We investigated the micronucleus frequencies in peripheral blood lymphocytes of 225 mastic asphalt workers (age 17-62 years) and 69 non-bitumen-exposed road construction workers (age 18-64 years) in Germany before and after the working shift. Median shift exposure to vapours and aerosols of bitumen of exposed workers was 3.0 mg/m³. Micronuclei (MN) were determined with a standard method using cytochalasin B. Median MN frequency was 6.0 (interquartile range (IQR) 4.0-8.5) MN/1,000 binucleated lymphocytes (MN/1,000 BNC) in exposed workers and 6.0 (IQR 4.0-8.3) MN/1,000 BNC in non-exposed workers before shift. After shift, we observed 6.5 (IQR 4.4-9.3) MN/1,000 BNC in exposed workers and 6.5 (IQR 4.0-9.0) MN/1,000 BNC in non-exposed workers. Regression models were applied with the log-transformed MN frequency as the dependent variable in order to estimate the effects of exposure to vapours and aerosols of bitumen and of potential confounders. Age was the strongest predictor of MN formation in both exposed workers and referents. Our data suggest that MN formation was not associated with concentration of vapours and aerosols of bitumen during shift at the individual level. Although similar MN frequencies were observed in both groups, the modelling of factors potentially influencing MN frequency revealed a weak group difference in the post-shift model. We conclude that this small difference cannot be judged to be a relevant mutagenic effect of exposure to vapours and aerosols of bitumen, also with regard to the lack of adjustment for multiple testing and the lack of a group effect in the original data.

  2. 加拿大Athabasca油砂中部分沥青质油不易分离的原因%Origin of Unliberated Bitumen in Athabasca Oil Sands

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Oil sands contain a so-called organic rich solids component (ORS), i.e., solids whose surfaces are strongly associated with toluene insoluble organic matter (TIOM). Typically, humic material is the major component of TIOM.It provides sites for adsorption and chemical fixation of bitumen. This bound bitumen is "unliberated", and considerable mechanical or chemical energy may be required to release it. In order to establish a correlation between bitumen recovery and ORS content, a few selected oil sands were processed in a Batch Extraction Unit (BEU).Analysis of the middlings and coarse tailings streams from these tests indicated a relatively constant bitumen to ORS ratio of 2.8±0.7. This value allows the liberated-unliberated bitumen balance (LUBB) to be calculated for any given oil sands. The amounts of bitumen recovered as primary froth during the BEU experiments are close to the estimated liberated bitumen contents in each case tested. This observation indicates that the liberated-unliberated bitumen calculation is an important quantitative parameter for prediction of bitumen recovery under specific recovery conditions. Preliminary results indicate that the ORS content of an oil sands may be estimated from the carbon content of bitumen free oil sands solids.

  3. RESEARCH AND APPLICATION OF BENTONITE WATERPROOF CARPET CONSTRUCTION TECHNIQUE%膨润土防水毯施工技术的研究与应用

    Institute of Scientific and Technical Information of China (English)

    曲春珑; 周卉鑫

    2011-01-01

    膨润土防水毯的国家或行业标准尚未正式颁布.在施工中针对具体情况,采用了相应的施工方法,解决了膨润土防水毯的大面积铺设、防水毯与其他防水材料的搭接、防水毯破损处的修补、施工缝及变形缝处细部构造等施工难题,收到了预期效果,形成了一套完整的专项技术.%At present, national or professional standard for bentonite waterproof carpet has not be officially issued, so relevant construction methods are adopted during the construction according to practical conditions to overcome construction difficulties, such as large laying area of bentonite waterproof carpet, overlapping between waterproof carpet and other waterproof material, repair of damaged waterproof carpet, detail construction at construction joint and deformation joint, etc. The expected effects are realized and a full set of special techniques are formed.

  4. Upstream petroleum industry flaring and venting report : industry performance for year ending December 31, 2001

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    Solution gas, gas from oil and bitumen batteries, is the largest source of flaring and venting in Alberta. A summary of solution gas conserved, flared and vented in Alberta during the year ending December 31, 2001 was presented along with flared volumes for the various oil and gas industry sectors such as gas plants, gas gathering systems, well tests and oil, bitumen and gas batteries. The report identifies the sources of flaring and venting in Alberta and monitors the progress the industry has made in reducing the volume of solution gas flared since 1996. Operators were ranked provincially, as well as within each field centre of the Alberta Energy and Utilities Board, based on solution gas flared, vented, total solution gas produced, and total oil from crude oil and bitumen batteries. The report demonstrates the significant progress industry has made towards reducing solution flare gas and vent volumes in the province. In 2001, the industry decreased overall flared and vented volumes by 16 per cent compared to year 2000 from all sources. Two new tables in this year's report indicate the top 25 solution gas producers in Alberta and the top 25 companies venting solution gas. The table provides information regarding each company's conservation performance and production volumes as a percentage of the provincial total.

  5. Coliquefaction of coal, tar sand bitumen and plastic (interaction among coal, bitumen and plastic); Sekitan/tar sand bitumen/plastic no kyoekika ni okeru kyozon busshitsu no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Yamaguchi, H.; Okuyama, Y.; Matsubara, K. [NKK Corp., Tokyo (Japan); Kamo, T.; Sato, Y. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    For the improvement of economy, coliquefaction of coal, tar sand bitumen and plastic was performed under low hydrogen pressure, to investigate the influence of interaction among these on the liquefaction characteristics. For comparison, coliquefaction was also performed under the hydrogen pressure same as the NEDOL process. In addition, for clarifying its reaction mechanism, coliquefaction of dibenzyl and plastic was performed as a model experiment, to illustrate the distribution of products and composition of oil, and to discuss the interaction between dibenzyl and various plastics, and between various plastics. Under direct coal liquefaction conditions, coprocessing of Tanito Harum coal, Athabasca tar sand and plastic was carried out under low hydrogen pressure with an autoclave. The observed value of oil yield was higher than the calculated value based on the values from separate liquefaction of coal and plastic, which suggested the interaction between coal and the mixed plastic. The results of coliquefaction of coal, tar sand bitumen and plastic could be explained from the obtained oil yield and its composition by the coliquefaction of dibenzyl and plastic. 2 refs., 3 tabs.

  6. Coagulation of bitumen with kaolinite in aqueous solutions containing Ca2+, Mg2+ and Fe3+: effect of citric acid.

    Science.gov (United States)

    Gan, Weibing; Liu, Qi

    2008-08-01

    Heterocoagulation experiments of kaolinite with solvent-diluted-bitumen were carried out to investigate the effect of hydrolyzable metal cations and citric acid on the liberation of bitumen from kaolinite. The adsorption of Ca(2+) and Mg(2+) on kaolinite, and zeta potentials of kaolinite and bitumen droplets in solutions containing 10(-3)mol/L of Ca(2+), Mg(2+) and Fe(3+) with or without citric acid were also measured. It was found that the heterocoagulation of bitumen with kaolinite was enhanced in the presence of the metal cations from pH 7 to pH 10.5, accompanied by a decrease in the magnitude of the zeta potentials and an increase in the adsorption of the metal cations on kaolinite and possibly on bitumen droplets. The addition of 5 x 10(-4)mol/L citric acid reduced the degree of coagulation from 90% to less than 40% in the presence of 10(-3)mol/L Ca(2+) and Mg(2+) cations at pH approximately 10, and at pH approximately 8 for Fe(3+). It was found that hydrolyzable metal cations enhanced bitumen-kaolinite interactions through electrical double layer compression and specific adsorption of the metal hydrolysis species on the surface of kaolinite. The effect of metal cations was removed by citric acid through formation of metal-citrate complexes and/or the adsorption of citrate anions, which restored the zeta potentials of both kaolinite and bitumen. Therefore, electrostatic attraction or repulsion was responsible for the coagulation or dispersion of kaolinite particles from bitumen droplets in the tested system.

  7. Effect of hydrated lime and cement on moisture damage of recycled mixtures with foamed bitumen and emulsion

    OpenAIRE

    Nosetti, R.A.; Pérez Jiménez, Félix Edmundo; Martínez Reguero, Adriana Haydée; Miró Recasens, José Rodrigo

    2016-01-01

    Cold recycling with foamed bitumen can be used as a sustainable and cost-effective rehabilitation technique. This paper focuses on the evaluation of the resistance to the water action in mixtures with reclaimed asphalt pavement (RAP) and foamed bitumen by means of indirect tensile test, comparing the effect of two active fillers: cement and hydrated lime. Additionally, mixtures recycled with RAP and asphalt emulsions were also tested in order to compare the response of both technologies. Resu...

  8. 目视化管理在防水材料生产管理中的应用%Application of visual management in production management of waterproof materials

    Institute of Scientific and Technical Information of China (English)

    蒋强

    2016-01-01

    防水材料生产制造行业因涉及的产品品类和产品型号多,所以对现场管理提出了很高的要求,生产现场存在原材料类型差异大、生产流程不连贯、重要管理节点多、人员分散、操作复杂等特点,规范生产现场可以提高生产效率和质量,减少生产和安全的隐患,提升管理效率。文章以防水材料生产现场的目视化管理为例,简述了如何在其生产现场进行有效的目视化管理,让生产管理透明、直观、易懂、创造良好的工作环境。%Because waterproof material production and manufacturing industry involves a number of product categories and product models, so it puts forward high demands on site management. There are many characteristics, such as raw material type is large difference, the production process is not coherent, the important management nodes are too many, the personnel are scattered, the operation is complex and so on. Regulate the production site can improve the production efficiency and quality, reduce the hidden dangers of production and safety, improve management efficiency. Taking waterproof material production field of visual management as an example, this article briefly describes how to make effective visual management in the production site, so that the production management is transparent, intuitive, straightforward and create a good working environment.

  9. A Review on the Effect of Crumb Rubber Addition to the Rheology of Crumb Rubber Modified Bitumen

    Directory of Open Access Journals (Sweden)

    Mohd Rasdan Ibrahim

    2013-01-01

    Full Text Available Crumb rubber modification has been proven to enhance the properties of pure bitumen. This paper looks at some of the international standards for producing crumb rubber modified bitumen (CRMB and reviews the effect of crumb rubber to the rheology of crumb rubber modified bitumen. The review shows that the rheology of CRMB depends on internal factors such as crumb rubber quantity, particle size, and pure bitumen composition, and external factors such as the mixing time, temperature, and also the modification technique. These factors govern the swelling process of crumb rubber particles that lead to the increase of viscosity of the modified bitumen. However, the mixing temperature and duration can cause rubber particles to depolymerize and subsequently cause loss of viscosity. Crumb rubber modification also improves the properties of bitumen by increasing the storage and loss modulus and enhancing the high and low temperature susceptibility. The effect of crumb rubber to aging properties of CRMB is also discussed. Finally several techniques of chemical modification to terminal blends of CRMB and the subsequent improvement to the settling property of CRMB are explained.

  10. Non-Newtonian behavior and molecular structure of Cooee bitumen under shear flow: A non-equilibrium molecular dynamics study

    Science.gov (United States)

    Lemarchand, Claire A.; Bailey, Nicholas P.; Todd, Billy D.; Daivis, Peter J.; Hansen, Jesper S.

    2015-06-01

    The rheology and molecular structure of a model bitumen (Cooee bitumen) under shear are investigated in the non-Newtonian regime using non-equilibrium molecular dynamics simulations. The shear viscosity, normal stress differences, and pressure of the bitumen mixture are computed at different shear rates and different temperatures. The model bitumen is shown to be a shear-thinning fluid at all temperatures. In addition, the Cooee model is able to reproduce experimental results showing the formation of nanoaggregates composed of stacks of flat aromatic molecules in bitumen. These nanoaggregates are immersed in a solvent of saturated hydrocarbon molecules. At a fixed temperature, the shear-shinning behavior is related not only to the inter- and intramolecular alignments of the solvent molecules but also to the decrease of the average size of the nanoaggregates at high shear rates. The variation of the viscosity with temperature at different shear rates is also related to the size and relative composition of the nanoaggregates. The slight anisotropy of the whole sample due to the nanoaggregates is considered and quantified. Finally, the position of bitumen mixtures in the broad literature of complex systems such as colloidal suspensions, polymer solutions, and associating polymer networks is discussed.

  11. 地下防水工程设计探讨%Discussion on the Design of Underground Waterproof Engineering

    Institute of Scientific and Technical Information of China (English)

    薛秉亮

    2015-01-01

    With the continuous development of the urban construction and a reducing number of resi-dential land,the longitudinal development of underground space has become the direction of the development of modern architectures,and the design of the underground parking garage becomes indispensable to residential district.Meanwhile,the waterproof design of underground engineering is more outstanding,and it has become a vital part of the whole project.The quality of the water-proof engineering is related to the safety and durability of buildings directly.Based on the design of underground parking garage,points for attention of the design of underground waterproof engi-neering and the selection of materials as well as technologies have been expounded emphatically in this paper.%随着城市建设的不断发展及住宅用地资源的日益紧张,地下空间的纵向发展已成为现代建筑的发展方向,相应的地下停车库的设计成为居住小区必不可少的配套设施。而地下工程防水设计比较突出,成为整个项目的重要部分。本文以地下停车库的设计为依托,着重阐述地下工程防水设计中应注意的事项以及对材料、技术构造的选择。地下防水工程的优劣,直接关系到建筑本身的安全性、耐久性。

  12. Molecular Structure Characteristics of Leather Waterproof Materials%皮革防水材料的分子结构特征

    Institute of Scientific and Technical Information of China (English)

    但年华; 王康建; 但卫华; 郝艳玲; 刘兰; 曾睿

    2011-01-01

    The waterproof materials including filling type and superficial water repellent type were introduced. The relationship between molecular structure characteristics and waterproof properties of emulsion type, metal complex type, organic silicon type and organic fluoro - compounds type was reviewed. It is pointed out that the future trend is to develop multiple functions, pollution - free and economical waterproof materials.%综述了填充阻塞型和表面疏水型皮革防水材料,重点阐述了乳胶型、金属配合物型、含硅型、含氟型皮革防水材料的分子结构特征和防水性能之间的关系.认为皮革防水材料今后将向功能化、环境友好和经济性方向发展.

  13. 雨虹外墙防水保温一体化外墙外保温系统%Exterior insulation and waterproof integration system of oriental Yuhong

    Institute of Scientific and Technical Information of China (English)

    宋明宇; 刘晓斌

    2014-01-01

    北京东方雨虹防水技术股份有限公司结合多年建筑防水及外保温施工经验,在总结EPS板薄抹灰外墙保温做法的基础上研发出防水保温一体化的雨虹外墙防水保温一体化外墙外保温系统,本文介绍该系统的构造性能及施工方法。%Beijing Oriental Yuhong Waterproof Technology Co.,combined with years of building waterproofing and insulation construction experience,on the basis of EPS thin plaster external wall insulation practices,developed the exterior insulation and waterproof integration system,this article describes the structure of the system performance and construction methods.

  14. The construction of SBS modified bitumen water-proof rolling material%屋面高聚物SBS改性沥青防水卷材施工技术

    Institute of Scientific and Technical Information of China (English)

    朱双双

    2008-01-01

    高聚物SBs改性沥青防水卷材属弹性体沥青防水卷材,具有良好的弹性、柔性、耐疲劳性、抗拉强度高及温度稳定性,广泛应用于各类建筑防水防潮工程,被列为重点发展的沥青改性物料.为确保SBS改性沥青防水卷材达到最佳使用效果,采用热熔法施工技术具有重要意义.

  15. Exploration on durability of modified bitumen waterproofing membrane with polyester reinforcements%改性沥青聚酯胎防水卷材的耐久性探讨

    Institute of Scientific and Technical Information of China (English)

    张广彬; 尚华胜; 杜奎义

    2007-01-01

    通过对两种典型改性沥青(SBS和橡胶粉)聚酯胎防水卷材的自然曝晒老化性能、耐酸碱盐腐蚀性能、耐水性以及抗冻融性能的测试,分析了改性沥青防水卷材的耐久性.结果显示:SBS改性沥青聚酯胎防水卷材表现出优异的耐久性,相比之下橡胶粉改性沥青聚酯胎防水卷材的耐久性较差.

  16. The application of SBS modified bitumen membrane in roof waterproof engineering%谈SBS改性沥青防水卷材在屋面工程中的应用

    Institute of Scientific and Technical Information of China (English)

    郭青梅

    2004-01-01

    介绍了SBS改性沥青防水卷材在屋面防水工程中的应用情况,从防水材料、工程设计等方面分析了影响SBS改性沥青卷材防水工程质量的几种因素,提出了提高防水工程质量的措施.

  17. A discussion about quality specification of SBS modified bitumen waterproofing membrane%SBS改性沥青防水卷材指标体系若干问题的探讨

    Institute of Scientific and Technical Information of China (English)

    阮政卿

    2004-01-01

    针对SBS改性沥青防水卷材从胎基材料、浸涂油到卷材产品的三大标准,分析其在技术指标的设置和确定、定义概念的表述、标准间的统一性等方面的问题,提出相应的修改意见.

  18. The role of multivalent metal cations and organic complexing agents in bitumen-mineral interactions in aqueous solutions

    Science.gov (United States)

    Gan, Weibing

    A systematic investigation was carried out to study the interactions between bitumen (or hexadecane) and minerals (quartz, kaolinite and illite) in aqueous solutions containing multivalent metal cations Ca2+, Mg2+ and Fe2+/Fe3+, in the absence and presence of organic complexing agents (oxalic acid, EDTA and citric acid). A range of experimental techniques, including coagulation measurement, visualization of bitumen-mineral attachment, metal ion adsorption measurement, zeta potential measurement, Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopic analyses, were employed in the investigation. Free energy changes of adsorption of metal cations on the minerals and bitumen were evaluated using the James & Healy thermodynamic model. Total interaction energies between the minerals and bitumen were calculated using classical DLVO theory. It was observed that while the tested minerals showed varying degrees of mutual-coagulation with bitumen (or hexadecane), the presence of the multivalent metal cations could prominently increase the mutual coagulation. It was also found that such enhancement of the mutual coagulation was only significant when the metal cations formed first-order hydroxyl complexes (such as CaOH +, MgOH+, etc.) or metal hydroxides (such as Fe(OH) 3, Mg(OH)2, etc.). Therefore, the increase of the bitumen-mineral mutual coagulation by the metal cations was strongly pH dependent. Organic complexing agents (oxalic acid, citric acid and EDTA) used in this study, citric acid in particular, significantly reduced or virtually eliminated the mutual coagulation between bitumen (or hexadecane) and minerals caused by metal cations Ca2+, Mg2+, Fe 2+ and Fe3+. Due to its ability to substantially lower the mutual coagulation between bitumen and mineral particles, citric acid was found the most effective in improving bitumen-mineral liberation in solutions containing the multivalent metal cations at pH 8--10. In small scale flotation experiments

  19. Waterproof Technology in Underground Project of HNA International Mansion%海控国际广场地下工程防水技术

    Institute of Scientific and Technical Information of China (English)

    鄢长; 李玥

    2011-01-01

    Based on analysis of the ground water and geological condition of HNA International Mansion, the design of waterproof for underground project is researched. A series of special requirements are indicated for building waterproof in Hainan province for its hot and moist environment. Comparing with the traditional waterproof membrane, the anti-salinization flexible waterproof material, such as CPS waterproofing membrane is decided to applied in this project. The construction process and key points for quality control of the waterproof membrane is described in detail. The product maintenance and repair measures are also introduced. The application effect is good, which proves the economy and efficiency of the material.%针对海控国际广场地下水及基坑土质情况,对其地下工程防水进行设计研究.因海南常年高温、多台风、多雨水,潮湿性较强,其建筑防水工程存在诸多特殊要求,经与传统卷材防水方案进行比对,决定使用耐盐碱的柔性防水材料——CPS反应粘防水卷材技术进行防水设计.详细介绍了此种防水卷材的施工工艺流程及施工中的主要质量控制要点,以及后期的成品养护及检查修补措施.此技术的应用效果良好,既经济又合理.

  20. Toxicological assessment of fish (Clarias gariepinus) from bitumen-polluted River Oluwa, Nigeria.

    Science.gov (United States)

    Ayandiran, T A; Dahunsi, S O

    2016-02-01

    Toxicological evaluation of Clarias gariepinus from bitumen-polluted River Oluwa, Nigeria, was carried out in furtherance of studies on the environmental impacts of the bitumen exploration in Ondo State, Nigeria. Samples were taken from three different (two polluted and one as control) sites. The effect of changes in monthly seasonal flow rate was assessed for the sites of study. Blood plasma clinical-chemical parameters (BCCPs) and histological changes/lesions in various organs were evaluated as markers of pollution in the fish blood using standard methods. The result of the physicochemical properties of water from the sampling points revealed some of the values conforming to approved standards while others showed deviation. Significant differences were found in the blood and histological endpoints between the control and the polluted sites as well as between the two seasons evaluated across the sites. The public health implications of consuming this fish are fully discussed.

  1. RADIATION CHEMICAL CONVERSION OF OIL DERIVED FROM OIL-BITUMEN ROCK

    Directory of Open Access Journals (Sweden)

    Lala Jabbarova

    2014-06-01

    Full Text Available The results of research in the radiation processing of synthetic oil derived from oil–bitumen rock of the Balakhany deposit in Azerbaijan are presented. The study has been conducted on a 60Co gamma-source at a dose rate of P = 0.5 Gy/s and various absorbed doses of D = 43–216 kGy. Samples of synthetic oil from natural bitumen rocks have been analyzed by chromatography, gas chromatography–mass spectrometry, and IR-spectroscopy, and their radiation resistance has been evaluated. The results of the study allow for both assessment of the feasibility of manufacturing petrochemicals for various applications by radiation processing and use of these materials for isolating radioactive sources to preclude their impact on the environment.

  2. Electromagnetic Heating of Heavy Oil and Bitumen: A Review of Experimental Studies and Field Applications

    Directory of Open Access Journals (Sweden)

    Albina Mukhametshina

    2013-01-01

    Full Text Available Viscosity is a major obstacle in the recovery of low API gravity oil resources from heavy oil and bitumen reservoirs. While thermal recovery is usually considered the most effective method for lowering viscosity, for some reservoirs introducing heat with commonly implemented thermal methods is not recommended. For these types of reservoirs, electromagnetic heating is the recommended solution. Electromagnetic heating targets part of the reservoir instead of heating the bulk of the reservoir, which means that the targeted area can be heated up more effectively and with lower heat losses than with other thermal methods. Electromagnetic heating is still relatively new and is not widely used as an alternate or addition to traditional thermal recovery methods. However, studies are being conducted and new technologies proposed that could help increase its use. Therefore, the objective of this study is to investigate the recovery of heavy oil and bitumen reservoirs by electromagnetic heating through the review of existing laboratory studies and field trials.

  3. Quasi-Brittle Fracture Modeling of Preflawed Bitumen Using a Diffuse Interface Model

    Directory of Open Access Journals (Sweden)

    Yue Hou

    2016-01-01

    Full Text Available Fundamental understandings on the bitumen fracture mechanism are vital to improve the mixture design of asphalt concrete. In this paper, a diffuse interface model, namely, phase-field method is used for modeling the quasi-brittle fracture in bitumen. This method describes the microstructure using a phase-field variable which assumes one in the intact solid and negative one in the crack region. Only the elastic energy will directly contribute to cracking. To account for the growth of cracks, a nonconserved Allen-Cahn equation is adopted to evolve the phase-field variable. Numerical simulations of fracture are performed in bituminous materials with the consideration of quasi-brittle properties. It is found that the simulation results agree well with classic fracture mechanics.

  4. Early Maritime Activity on the Dead Sea: Bitumen Harvesting and the Possible Use of Reed Watercraft

    Science.gov (United States)

    Oron, Asaf; Galili, Ehud; Hadas, Gideon; Klein, Micha

    2015-04-01

    Most studies of ancient maritime activity on the Dead Sea focus on the Hellenistic to the Early Byzantine periods, for which a rich body of archaeological and historic data exists. However, finds of Dead Sea bitumen at distant prehistoric sites and an anchor dating to the seventh century BC indicate that maritime activity on the lake preceded the Greek and Roman periods, and raise questions regarding this activity's origins and nature. By linking the exploitation of Dead Sea bitumen with the use of watercraft, and through consideration of a broader early maritime record of the ancient Near East, this study pushes back the dating of this activity on the lake and suggests the nature of its watercraft.

  5. Paleoenvironmental implications of novel C 30 steranes in Precambrian to Cenozoic Age petroleum and bitumen

    Science.gov (United States)

    McCaffrey, Mark A.; Michael Moldowan, J.; Lipton, Paul A.; Summons, Roger E.; Peters, Kenneth E.; Jeganathan, Alwarsamy; Watt, David S.

    1994-01-01

    Petroleums and bitumens from Early Proterozoic (≈ 1800 Ma) to Miocene (≈ 15 Ma) age marine strata contain 24-isopropylcholestanes, a novel group of C 30 steroids. The abundance of these compounds, relative to 24- n-propylcholestanes, varies with source rock age. Late Proterozoic (Vendian) and Early Cambrian oils and/or bitumens from Siberia, the Urals, Oman, Australia, and India have a high ratio of 24-isopropylcholestanes to 24- n-propylcholestanes (≥1), while younger and older samples have a lower ratio (≤0.4). Temporal changes in this parameter may reflect the relative abundance of certain Porifera (sponges) and certain marine algae through time. Geochemical indicators such as this, which can constrain the source rock age of a migrated oil, are useful in source rock identification during petroleum exploration.

  6. The Quality Control of Roof Waterproof Engineering%浅析屋面防水工程的质量控制

    Institute of Scientific and Technical Information of China (English)

    张洪飞

    2013-01-01

    This paper in view of roofing waterproof problems expounds from the relevant control points and measures of ma-terial, design, construction, repair management, to strengthen t-he whole process quality control of roof waterproof engineeri-ng.%  本文鉴于屋面防水存在的问题从材料、设计、施工、维修管理角度阐述相关控制要点及措施,旨在加强屋面防水工程全过程的质量控制。

  7. Experimental Investigationand Numerical Simulation ofThermal Recovery ProcessesApplicable in AthabascaBitumen Reservoirs

    OpenAIRE

    Souraki, Yaser

    2013-01-01

    Due to reduction of high quality oil resources and consequently increase of oil price around the world, new sources of energy should be found to relief the high demand of energy. Hence, countries like Venezuela, United States and particularly Canada came up with their unconventional reservoirs which contain bitumen, extra heavy oil and heavy oil as remarkable sources of energy. Exploitation of such kind of reservoirs was not beneficial in the past but in recent years due to the increase of oi...

  8. Electromagnetic Heating of Heavy Oil and Bitumen: A Review of Experimental Studies and Field Applications

    OpenAIRE

    Albina Mukhametshina; Elena Martynova

    2013-01-01

    Viscosity is a major obstacle in the recovery of low API gravity oil resources from heavy oil and bitumen reservoirs. While thermal recovery is usually considered the most effective method for lowering viscosity, for some reservoirs introducing heat with commonly implemented thermal methods is not recommended. For these types of reservoirs, electromagnetic heating is the recommended solution. Electromagnetic heating targets part of the reservoir instead of heating the bulk of the reservoir, w...

  9. Rheological analysis of bitumens dy dynamic shear rheometer : effect of thermical history on the results

    OpenAIRE

    MOUILLET, V; LAPALU, L; PLANCHE, JP; DURRIEU, F

    2004-01-01

    In order to prevent binder-related pavement failures, it is very important to be able to characterize the performances of bituminous binders that play an essential role in the construction and reinforcement of pavements. However, because of its specific and complex composition, bitumen is a visco-elastic material whose intrinsic rheological properties depend upon the temperature and the loading time. One way to characterize this particular behaviour is to measure the response of the material ...

  10. 沥青燃烧特性的实验研究%Experimental research on combustion characteristics of bitumen

    Institute of Scientific and Technical Information of China (English)

    黄亚东; 冯丹丹; 吴珂; 敖文; 黄志义

    2011-01-01

    采用热重分析法对SBS改性沥青和阻燃沥青及其胶浆的燃烧特性进行研究,实验条件为空气环境、升温速率为20℃/min.结果表明:两种沥青胶浆的燃烧特性曲线形状十分相近,大致分为5个阶段.两种沥青燃烧过程较一致,主要分为4个阶段.沥青二次挥发分燃烧与残炭燃烧同时进行.目前的阻燃技术对沥青自燃点的影响不大,其主要作用是减缓沥青的燃烧速度.阻燃沥青的平均燃烧速率约为SBS改性沥青的60%.两种沥青胶浆的灰分含量相差不大,其平均燃烧速率也相差不大.%The combustion characteristics of SBS modification bitumen and fire retardant bitumen and their mortar were studied by thermo-gravimetric analysis with air as the ambient gas and 20 ℃/min heating rate. The experimental results showed that the combustion characteristics curves of the mortar of these two kinds of bitumen are very similar, and all have 5 sections. The combustion processes of two kinds of bitumen are similar and have 4 sections. The secund volatile component and carbon residue of bitumen burned at the same time. The flame- resistant technology has little effect on the bitumen' s self - ignition point at present, and its primary action is to slow down the reaction rate of bitumen combustion. The average combustion rate of flame-retardant bitumen is 60% of that of SBS modification bitumen The mortar of two kinds of bitumen has the similar ash content, so has the similar average combustion rate.

  11. Impact of some field factors on inhalation exposure levels to bitumen emissions during road paving operations.

    Science.gov (United States)

    Deygout, François; Auburtin, Guy

    2015-03-01

    Variability in occupational exposure levels to bitumen emissions has been observed during road paving operations. This is due to recurrent field factors impacting the level of exposure experienced by workers during paving. The present study was undertaken in order to quantify the impact of such factors. Pre-identified variables currently encountered in the field were monitored and recorded during paving surveys, and were conducted randomly covering current applications performed by road crews. Multivariate variance analysis and regressions were then used on computerized field data. The statistical investigations were limited due to the relatively small size of the study (36 data). Nevertheless, the particular use of the step-wise regression tool enabled the quantification of the impact of several predictors despite the existing collinearity between variables. The two bitumen organic fractions (particulates and volatiles) are associated with different field factors. The process conditions (machinery used and delivery temperature) have a significant impact on the production of airborne particulates and explain up to 44% of variability. This confirms the outcomes described by previous studies. The influence of the production factors is limited though, and should be complemented by studying factors involving the worker such as work style and the mix of tasks. The residual volatile compounds, being part of the bituminous binder and released during paving operations, control the volatile emissions; 73% of the encountered field variability is explained by the composition of the bitumen batch.

  12. Gaps in scientific knowledge about the carcinogenic potential of asphalt/bitumen fumes.

    Science.gov (United States)

    Schulte, Paul A

    2007-01-01

    Despite a relatively large body of published research, the potential carcinogenicity of asphalt/bitumen fumes is still a vexing question. Various uncertainties and gaps in scientific knowledge need to be addressed. These include uncertainties in chemistry, animal studies, and human studies. The chemistry of asphalt/bitumen fumes is complex and varies according to the source of the crude oil and the application parameters. The epidemiological studies, while showing weak evidence of lung cancer, are inconsistent and many confounding factors have not been addressed. Studies of animal exposure are also inconsistent regarding laboratory and field-generated fumes. There is a need for further human studies that address potential confounding factors such as smoking, diet, coal tar, and diesel exposures. Animal inhalation studies need to be conducted with asphalt/bitumen fumes that are chemically representative of roofing and paving fumes. Underlying all of this is the need for continued characterization of fumes so their use in animal and field studies can be properly assessed. Nonetheless, uncertainties such as these should not preclude appropriate public health actions to protect workers in the even that asphalt fumes are found to be a carcinogenic hazard.

  13. 关于隧道防水技术的探讨%Discussion on the Tunnel Waterproof Technology

    Institute of Scientific and Technical Information of China (English)

    聂凯良

    2013-01-01

    地铁隧道的防水处理不好,将造成隧道漏水、渗水,其结果是引起隧道内各种设备机能降低、失效,加速衬砌劣化,减少隧道使用寿命,增加维修费用,尤其在寒冷地区,漏、渗水会使路面结冰或形成冰棱,在衬砌表面形成冰柱,直接影响行车安全。本文结合工程实例探讨了地铁隧道防水工程的施工技术。%The bad subway tunnel waterproof processing will cause the tunnel leakage, water seepage, the result will make the equipment function reduce and lose efficacy, accelerate the lining cracking, reduce the service life of the tunnel, and increase maintenance costs, especially in cold areas, water seepage can make the road be icy, and form ice, and form icicles in the lining surface, it directly influences the train operation safety. Combined with engineering example, the paper discusses the construction technology of waterproof engineering of metro tunnel.

  14. DNA adducts and strand breaks in workers exposed to vapours and aerosols of bitumen: associations between exposure and effect.

    Science.gov (United States)

    Marczynski, Boleslaw; Raulf-Heimsoth, Monika; Spickenheuer, Anne; Pesch, Beate; Kendzia, Benjamin; Mensing, Thomas; Engelhardt, Beate; Lee, Eun-Hyun; Schindler, Birgit K; Heinze, Evelyn; Welge, Peter; Bramer, Rainer; Angerer, Jürgen; Breuer, Dietmar; Käfferlein, Heiko U; Brüning, Thomas

    2011-06-01

    To study the associations between exposure to vapours and aerosols of bitumen and genotoxic effects, a cross-sectional and cross-shift study was conducted in 320 exposed workers and 118 non-exposed construction workers. Ambient air measurements were carried out to assess external exposure to vapours and aerosols of bitumen. Hydroxylated metabolites of naphthalene, phenanthrene and pyrene were measured in urine, whereas (+)-anti-benzo[a]pyrene-7,8-diol-9,10-epoxide ((+)-anti-BPDE), 8-oxo-7,8-dihydro-2'-deoxyguanosine (8oxodGuo) and DNA strand breaks were determined in blood. Significantly higher levels of 8-oxodGuo adducts and DNA strand breaks were found in both pre- and post-shift blood samples of exposed workers compared to those of the referents. No differences between exposed workers and referents were observed for (+)-anti-BPDE. Moreover, no positive associations between DNA damage and magnitude of airborne exposure to vapours and aerosols of bitumen could be observed in our study. Additionally, no relevant association between the urinary metabolites of PAH and the DNA damage in blood was observed. Overall, our results indicate increased oxidative DNA damage in workers exposed to vapours and aerosols of bitumen compared to non-exposed referents at the group level. However, increased DNA strand breaks in bitumen workers were still within the range of those found in non-exposed and healthy persons as reported earlier. Due to the lack of an association between oxidative DNA damage and exposure levels at the workplaces under study, the observed increase in genotoxic effects in bitumen workers cannot be attributed to vapours and aerosols of bitumen.

  15. 单层SBS防水卷材机械固定系统在屋面防水改造项目上的应用%Application of Single Ply SBS Modified Bitumen Waterproofing Membrane Mechanical Fasten System in the Roof Waterproofing Renovation

    Institute of Scientific and Technical Information of China (English)

    魏连中

    2014-01-01

    某混凝土屋面热熔满粘法施工的SBS改性沥青卷材防水层因材料质量和设计施工不合理而过早失效渗漏,采用单层SBS防水卷材机械固定系统对此屋面进行翻新,不仅节材、缩短工期,而且防水效果显著.

  16. Research Progress on Waterproof Additive in Phosphogypsum Building Materials%磷石膏建材防水添加剂研究进展

    Institute of Scientific and Technical Information of China (English)

    李兵

    2015-01-01

    磷石膏是硫酸湿法萃取磷酸时排出的固体废弃物,每生产1t湿法磷酸约产生5t磷石膏。如何有效地利用磷石膏,生产建筑材料是人们极力寻求解决的问题,进行磷石膏防水剂的开发利用具有重要意义。本文总结了磷石膏防水剂的研究现状,然后对磷石膏的防水性作用原理进行了详细的介绍,对磷石膏防水添加剂研究进展进行了综述。%Phosphogypsum is discharged when phosphoric acid was extracted by WPA , 5 t phosphogypsum was produced when 1 t wet phosphoric acid was produced.How to effectively use phosphogypsum , product building materials is the problem that people struggle to solve , development and utilization of phosphogypsum waterproofing agent is important.The research status of phosphogypsum waterproofing agent was summarized , the role of the principle of waterproof phosphogypsum was detaily presented , research progress of phosphogypsum waterproof additives was reviewed.

  17. Robotics and automation for oil sands bitumen production and maintenance

    Energy Technology Data Exchange (ETDEWEB)

    Lipsett, M.G. [Alberta Univ., Edmonton, AB (Canada). Dept. of Mechanical Engineering

    2008-07-01

    This presentation examined technical challenges and commercial challenges related to robotics and automation processes in the mining and oil sands industries. The oil sands industry has on-going cost pressures. Challenges include the depths to which miners must travel, as well as problems related to equipment reliability and safety. Surface mines must operate in all weather conditions with a variety of complex systems. Barriers for new technologies include high capital and operating expenses. It has also proven difficult to integrate new technologies within established mining practices. However, automation has the potential to improve mineral processing, production, and maintenance processes. Step changes can be placed in locations that are hazardous or inaccessible. Automated sizing, material, and ventilation systems are can also be implemented as well as tele-operated equipment. Prototypes currently being developed include advanced systems for cutting; rock bolting; loose rock detection systems; lump size estimation; unstructured environment sensing; environment modelling; and automatic task execution. Enabling technologies are now being developed for excavation, haulage, material handling systems, mining and reclamation methods, and integrated control and reliability. tabs., figs.

  18. Solar energy based industrial applications at the "Politehnica" University of Timisoara

    Directory of Open Access Journals (Sweden)

    Luminosu Ioan V.

    2011-01-01

    Full Text Available A short overview of a more than 30 years long activity in industrial and home applications of solar energy at the "Politehnica" University of Timişoara, Romania is presented. A built "Solar House", an industrial system for preheating bitumen, a solution for waste water cleaning and an industrial hall for drying ceramic products are described. Some recent studies on solar concentrators are reported.

  19. Physical factors affecting the electrically assisted thermal bitumen recovery

    Energy Technology Data Exchange (ETDEWEB)

    Bogdanov, I.I.; Torres, J.-A.; Kamp, A.M. [CHLOE, University of Pau (France); Corre, B. [CSTJF, Total (France)

    2011-07-01

    In the heavy oil industry, thermal processes are used to enhance oil recovery by increasing the reservoir temperature which results in better oil mobility. Low frequency heating (LFH) is a technology using electrical conductivity of connate water to propagate current between electrodes, thus generating heat in the reservoir through the Joule effect. During the preheating and production periods, many physical factors may affect the LFH process and the aim of this study was to determine which factors affect the process and how, using a particular pattern of electrodes. Simulations were conducted using the CMG Stars reservoir simulator under different configurations, conditions and parameters. Important physical properties and operational conditions affecting the LFH process were determined and results showed that convection heat, bulk electrical conductivity and power distribution can be improved by salt water circulation. This paper highlighted the physical factors affecting LFH efficiency and these findings will be useful for future process design.

  20. Quantitative temperature-depending mapping of mechanical properties of bitumen at the nanoscale using the AFM operated with PeakForce TappingTM mode

    NARCIS (Netherlands)

    Fischer, H.R.; Stadler, H.; Erina, N.

    2013-01-01

    The mechanical properties of bitumen, such as elasticity/Young's modulus, stickiness/adhesion, hardness and energy loss, and sample deformation were acquired quantitatively and simultaneously with the topology at the microscale, discriminating clearly two separate phases within the bitumen. Temperat

  1. Determination of organic products resulting of chemical and radiochemical decompositions of bitumen. Applications to embedded bitumens; Determination des produits organiques d'alterations chimiques et radiochimiques du bitume. Applications aux enrobes bitumes

    Energy Technology Data Exchange (ETDEWEB)

    Walczak, I

    2000-01-27

    Bitumen can be used for embedding most of wastes because of its high impermeability and its relatively low reactivity with of chemicals. Bituminization is one of selected solutions in agreement with nuclear safety, waste compatibility and economic criteria. Bitumen, during storage, undergoes an auto-irradiation due to embedded radio-elements. During this stage,drums are not airtight then oxygen is present. In disposal configuration, water, which is a potential vector of radioactivity and organic matter, is an other hazard factor liable to deteriorate the containment characteristics of bitumen wastes. The generation of water-soluble organic complexing agents can affect the integrity of the wasteform due to an increase of the radionuclides solubility. The first aim of this work is the quantitative and qualitative characterisation of soluble organic matter in bitumen leachates. Different leaching solutions were tested (various pH, ionic strength, ratio S/V). When the pH of the leaching solutions increases, the total organic carbon released increases as well. Identified molecules are aromatics like naphthalene, oxidised compounds like alcohols, linear carbonyls, aromatics, glycols and nitrogen compounds. For the cement equilibrated solution (pH 13.5), the effect of ionic strength becomes significative and influences the release of soluble organic matter. This soluble organic matter can be bio-degraded if microorganisms can growth. The second aim of this work is to study the effect of radio-oxidative ageing on the bitumen confinement properties. During radio-oxidation, the chemical properties of bitumen are modified. The {mu}-IRTF analysis shows the formation of hydroxyl compounds and aromatic acids. The formation of these polar groups does not influence in our study the water uptake. However the organic matter release increases significantly with the irradiation dose. (author)

  2. Organic metamorphism in the California petroleum basins; Chapter B, Insights from extractable bitumen and saturated hydrocarbons

    Science.gov (United States)

    Price, Leigh C.

    2000-01-01

    Seventy-five shales from the Los Angeles, Ventura, and Southern San Joaquin Valley Basins were extracted and analyzed. Samples were chosen on the basis of ROCK-EVAL analyses of a much larger sample base. The samples ranged in burial temperatures from 40 ? to 220 ? C, and contained hydrogen-poor to hydrogen-rich organic matter (OM), based on OM visual typing and a correlation of elemental kerogen hydrogen to carbon ratios with ROCK-EVAL hydrogen indices. By extractable bitumen measurements, rocks with hydrogen- poor OM in the Los Angeles Basin began mainstage hydrocarbon (HC) generation by 90 ? C. The HC concentrations maximized by 165 ? C, and beyond 165 ? C, HC and bitumen concentrations and ROCK-EVAL hydrogen indices all began decreasing to low values reached by 220 ? C, where HC generation was largely complete. Rocks with hydrogen-poor OM in the Southern San Joaquin Valley Basin commenced mainstage HC generation at 135 ? C and HC concentrations maximized by 180 ? C. Above 180 ? C, HC and bitumen concentrations and ROCK-EVAL hydrogen indices all decreased to low values reached by 214 ? C, again the process of HC generation being largely complete. In both cases, bell-shaped HC-generation curves were present versus depth (burial temperature). Mainstage HC generation had not yet begun in Ventura Basin rocks with hydrogen-poor OM by 140 ? C. The apparent lower temperature for initiation of mainstage generation in the Los Angeles Basin is attributed to very recent cooling in that basin from meteoric-water flow. Thus, HC generation there most probably occurred at higher burial temperatures. In contrast, mainstage HC generation, and all aspects of organic metamorphism, were strongly suppressed in rocks with hydrogen-rich OM at temperatures as high as 198 ? C. For example, shales from the Wilmington field (Los Angeles Basin) from 180 ? to 198 ? C retained ROCK-EVAL hydrogen indices of 550- 700 and had saturated-HC coefficients of only 4-15 mg/g organic carbon. The rocks

  3. Ecotoxicological impacts of effluents generated by oil sands bitumen extraction and oil sands lixiviation on Pseudokirchneriella subcapitata.

    Science.gov (United States)

    Debenest, T; Turcotte, P; Gagné, F; Gagnon, C; Blaise, C

    2012-05-15

    The exploitation of Athabasca oil sands deposits in northern Alberta has known an intense development in recent years. This development has raised concern about the ecotoxicological risk of such industrial activities adjacent to the Athabasca River. Indeed, bitumen extraction generated large amounts of oil sands process-affected water (OSPW) which are discharged in tailing ponds in the Athabasca River watershed. This study sought to evaluate and compare the toxicity of OSPW and oil sands lixiviate water (OSLW) with a baseline (oil sands exposed to water; OSW) on a microalgae, Pseudokirchneriella subcapitata, at different concentrations (1.9, 5.5, 12.25, 25 and 37.5%, v/v). Chemical analyses of water-soluble contaminants showed that OSPW and OSLW were enriched in different elements such as vanadium (enrichment factor, EF=66 and 12, respectively), aluminum (EF=64 and 15, respectively), iron (EF=52.5 and 17.1, respectively) and chromium (39 and 10, respectively). The toxicity of OSPW on cells with optimal intracellular esterase activity and chlorophyll autofluorescence (viable cells) (72h-IC 50%37.5%, v/v). OSLW was 4.4 times less toxic (IC 50%=8.5%, v/v) than OSPW and 4.5 times more toxic than OSW. The inhibition of viable cell growth was significantly and highly correlated (<-0.7) with the increase of arsenic, beryllium, chromium, copper, lead, molybdenum and vanadium concentrations. The specific photosynthetic responses studied with JIP-test (rapid and polyphasic chlorophyll a fluorescence emission) showed a stimulation of the different functional parameters (efficiency of PSII to absorb energy from photons, size of effective PSII antenna and vitality of photosynthetic apparatus for energy conversion) in cultures exposed to OSPW and OSLW. To our knowledge, our study highlights the first evidence of physiological effects of OSPW and OSLW on microalgae.

  4. Ecotoxicological impacts of effluents generated by oil sands bitumen extraction and oil sands lixiviation on Pseudokirchneriella subcapitata

    Energy Technology Data Exchange (ETDEWEB)

    Debenest, T., E-mail: tdebenest@yahoo.fr [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada); Turcotte, P. [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada); Gagne, F., E-mail: francois.gagne@ec.gc.ca [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada); Gagnon, C.; Blaise, C. [Environment Canada, Fluvial Ecosystem Research, 105 McGill Street, 7 floor, Montreal, Quebec, H2Y 2E7 (Canada)

    2012-05-15

    The exploitation of Athabasca oil sands deposits in northern Alberta has known an intense development in recent years. This development has raised concern about the ecotoxicological risk of such industrial activities adjacent to the Athabasca River. Indeed, bitumen extraction generated large amounts of oil sands process-affected water (OSPW) which are discharged in tailing ponds in the Athabasca River watershed. This study sought to evaluate and compare the toxicity of OSPW and oil sands lixiviate water (OSLW) with a baseline (oil sands exposed to water; OSW) on a microalgae, Pseudokirchneriella subcapitata, at different concentrations (1.9, 5.5, 12.25, 25 and 37.5%, v/v). Chemical analyses of water-soluble contaminants showed that OSPW and OSLW were enriched in different elements such as vanadium (enrichment factor, EF = 66 and 12, respectively), aluminum (EF = 64 and 15, respectively), iron (EF = 52.5 and 17.1, respectively) and chromium (39 and 10, respectively). The toxicity of OSPW on cells with optimal intracellular esterase activity and chlorophyll autofluorescence (viable cells) (72 h-IC 50% < 1.9%) was 20 times higher than the one of OSW (72 h-IC 50% > 37.5%, v/v). OSLW was 4.4 times less toxic (IC 50% = 8.5%, v/v) than OSPW and 4.5 times more toxic than OSW. The inhibition of viable cell growth was significantly and highly correlated (<-0.7) with the increase of arsenic, beryllium, chromium, copper, lead, molybdenum and vanadium concentrations. The specific photosynthetic responses studied with JIP-test (rapid and polyphasic chlorophyll a fluorescence emission) showed a stimulation of the different functional parameters (efficiency of PSII to absorb energy from photons, size of effective PSII antenna and vitality of photosynthetic apparatus for energy conversion) in cultures exposed to OSPW and OSLW. To our knowledge, our study highlights the first evidence of physiological effects of OSPW and OSLW on microalgae.

  5. Geothermal waste heat utilization from in situ thermal bitumen recovery operations.

    Science.gov (United States)

    Nakevska, Nevenka; Schincariol, Robert A; Dehkordi, S Emad; Cheadle, Burns A

    2015-01-01

    In situ thermal methods for bitumen extraction introduce a tremendous amount of energy into the reservoirs raising ambient temperatures of 13 °C to as high as 200 °C at the steam chamber edge and 50 °C along the reservoir edge. In essence these operations have unintentionally acted as underground thermal energy storage systems which can be recovered after completion of bitumen extraction activities. Groundwater flow and heat transport models of the Cold Lake, Alberta, reservoir, coupled with a borehole heat exchanger (BHE) model, allowed for investigating the use of closed-loop geothermal systems for energy recovery. Three types of BHEs (single U-tube, double U-tube, coaxial) were tested and analyzed by comparing outlet temperatures and corresponding heat extraction rates. Initial one year continuous operation simulations show that the double U-tube configuration had the best performance producing an average temperature difference of 5.7 °C, and an average heat extraction of 41 W/m. Given the top of the reservoir is at a depth of 400 m, polyethylene piping provided for larger extraction gains over more thermally conductive steel piping. Thirty year operation simulations illustrate that allowing 6 month cyclic recovery periods only increases the loop temperature gain by a factor of 1.2 over continuous operation. Due to the wide spacing of existing boreholes and reservoir depth, only a small fraction of the energy is efficiently recovered. Drilling additional boreholes between existing wells would increase energy extraction. In areas with shallower bitumen deposits such as the Athabasca region, i.e. 65 to 115 m deep, BHE efficiencies should be larger.

  6. Stretchable and Waterproof Self-Charging Power System for Harvesting Energy from Diverse Deformation and Powering Wearable Electronics.

    Science.gov (United States)

    Yi, Fang; Wang, Jie; Wang, Xiaofeng; Niu, Simiao; Li, Shengming; Liao, Qingliang; Xu, Youlong; You, Zheng; Zhang, Yue; Wang, Zhong Lin

    2016-07-26

    A soft, stretchable, and fully enclosed self-charging power system is developed by seamlessly combining a stretchable triboelectric nanogenerator with stretchable supercapacitors, which can be subject to and harvest energy from almost all kinds of large-degree deformation due to its fully soft structure. The power system is washable and waterproof owing to its fully enclosed structure and hydrophobic property of its exterior surface. The power system can be worn on the human body to effectively scavenge energy from various kinds of human motion, and it is demonstrated that the wearable power source is able to drive an electronic watch. This work provides a feasible approach to design stretchable, wearable power sources and electronics.

  7. Use of high resolution images of orbital surface of waterproofing with different levels of urban land: case Irati-PR

    Directory of Open Access Journals (Sweden)

    Paulo Costa de Oliveira Filho

    2012-11-01

    Full Text Available The objective of this research was to present a detailed diagnosis for use and occupation of urban land aimed at different levels of sealing, in a downtownIrati area of 14 blocks, totaling 0.23 km2, from the Quickbird satellite images with spatial resolution of 0.60 m, by the method of interpretation and vectorization on the screen followed by classification. The area occupied by the classes that represent the highest level of waterproof is 33,218% of the total study area, since the area occupied by classes representing less impermeable level is 22,488% of the same area. The results show that the study area is well sealed.

  8. Preparation of waterproof OSL dosimeters from hygroscopic materials with a special reference to NaCl:Cu

    Science.gov (United States)

    More, Y. K.; Wankhede, S. P.; Patil, R. R.; Kulkarni, M. S.; Kumar, Munish; Moharil, S. V.

    2016-05-01

    Optically stimulated luminescence (OSL) originally developed for geological/archaeological dating, has been found very useful for diverse applications in the field of radiation dosimetry. There is still a scarcity of OSL materials with demonstrated properties suited to dosimetry applications. Progress on the development of OSL materials with engineered properties has been slow and most research has focused on the OSL characterization of existing materials. One of the reasons for availability of only a handful of OSL dosimetry materials with adequate properties is that they have to satisfy certain stringent conditions necessary for such applications. Especially, hygroscopic materials are considered totally unsuitable. The efforts were made in our laboratory to overcome this problem. It is shown here that "water-proof" dosimeters can be prepared from even hygroscopic materials such as NaCl.

  9. Bitumen/Water Emulsions as Fuels for High-Speed Ci Engines Preliminary Investigations

    DEFF Research Database (Denmark)

    Schramm, Jesper; Sigvardsen, R.; Forman, M.

    2003-01-01

    Mixtures of bitumen and water, are cheap fuel alternatives for combustion engines. There are, however, several problems that have to be solved before these fuels can be applied in high-speed diesel engines. These are: - emulsion break up due to high temperature or high shear stress in the injection...... system - high content of heavy metals - high emissions of particulate matter and PAH This investigation deals with the problem of separation due to high shear stress in the injection system. It is shown that the viscosity of the injected fuel can be used to estimate whether the emulsion has separated...

  10. Study of oil and residual fractions in products of thermal destruction of bitumen beds

    Energy Technology Data Exchange (ETDEWEB)

    Diskina, D.Ye.; Kadyrov, M.U.; Shabalina, T.N.; Soldatova, V.G.; Tokareva, R.V.; Tyshchenko, N.Ye.; Usacheva, G.M.; Vigdergauz, M.S.

    1981-01-01

    Investigation of average and heavy fractions derived from thermodestruction products in the bitumen bed at Mordovo-Karmal in Tatariya. Composition of average fractions is characterized by presence of unsaturated and a certain volume of oxygen-containing compounds, as well as high content of S and a low congelation temp. With respect to content of aromatic compounds, these fractions are similar to fractions of sulphurous oils. Residual fractions (..-->..350/sup 0/) were studied by conversion chromatography; these have low values of viscosity, density, content of S (in comparison with the same fractions of Mordovo-Karmal oil). Examines potential directions for utilizing these fractions.

  11. Ion exchange resin immobilization into bitumen; Imobilizacao de resinas de troca-ionica em betume

    Energy Technology Data Exchange (ETDEWEB)

    Guzella, Marcia Flavia Righi; Silva, Tania Valeria da [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil)

    2002-07-01

    This work presents the results of a research carried out at CDTN/CNEN (Nuclear Technology Development Center) to incorporate spent ion exchange resin into national bitumen. The campaigns were performed at a bituminization pilot plant in CDTN. The waste products properties were evaluated according national and international standards to determine the softening point, penetration, flash point, water content, the thermo differential analysis and homogeneity. These properties are important to evaluate the waste products in order to allow for the system to be operated safely. The so obtained products should meet the standard safety criteria for disposal. (author)

  12. Effect of Organophilic Montmorillonite on Ther-mal-oxidative Aging Behavior of SBS Modified Bitumen Crack Filling Material

    Institute of Scientific and Technical Information of China (English)

    YU Jianying; WANG Xilin; KUANG Dongliang; ZHANG Henglong

    2009-01-01

    Styrene-butadiene-styrene(SBS)modified bitumen crack filling material with or-ganophilic montmorillonite(OCFM)was prepared by melt blending.X-ray diffraction analysis shows that the interlayer spacing of organophilic montmorillonite(OMMT)in OCFM is widened and an exfoliated structure may be formed.Thermal-oxidative aging behavior of OCFM and SBS modified bitumen crack filling material(SCFM)was investigated.The experimental results indicate that the rate of thermal-oxidative aging of OCFM is much slower than that of SCFM,which can be attributed to barrier of exfoliated structure of OCFM to oxygen.

  13. Bitumen workers handling mastic versus rolled asphalt in a tunnel: assessment of exposure and biomarkers of irritation and genotoxicity.

    Science.gov (United States)

    Raulf-Heimsoth, Monika; Marczynski, Boleslaw; Spickenheuer, Anne; Pesch, Beate; Welge, Peter; Rühl, Reinhold; Bramer, Rainer; Kendzia, Benjamin; Heinze, Evelyn; Angerer, Jürgen; Brüning, Thomas

    2011-06-01

    Emission levels of vapours and aerosols of bitumen are different when processing rolled asphalt compared to mastic asphalt, with working temperatures up to 180 and 250°C, respectively. During the Human Bitumen Study, we examined six workers handling rolled asphalt and mastic asphalt in two consecutive weeks at the same construction site in a tunnel. In addition to the determination of exposure to bitumen and polycyclic aromatic hydrocarbons (PAH) during shift, we examined urinary PAH metabolites, irritative and genotoxic effects before and after shift. Median personal shift concentration of vapours and aerosols of bitumen was 1.8 (range 0.9-2.4) mg/m(3) during the application of rolled asphalt and 7.9 (range 4.9-11.9) mg/m(3) when mastic asphalt was applied. Area measurement of vapours and aerosols of bitumen revealed higher concentrations than the personal measurements for mastic asphalt (mastic asphalt: 34.9 mg/m(3); rolled asphalt: 1.8 mg/m(3)). Processing mastic asphalt was associated also with higher PAH concentrations. Urinary 1-hydroxypyrene and the sum of 1-, 2+ 9-, 3- and 4-hydroxyphenanthrene increased slightly during shift without clear difference between mastic and rolled asphalt application. However, the post-shift urinary PAH-metabolite concentrations did not reflect the different PAH exposure during mastic and rolled asphalt application. Individual workers could be identified by their spirometry results indicating that these data reflect more chronic than acute effects. In most cases, an increase of 8-oxodGuo adducts was observed during shift that was independent of the asphalt application. 8-oxodGuo and (+)-anti-BPDE-DNA adducts were higher than in exposed workers of the Human Bitumen Study independent of the asphalt application. The DNA-strand breaks were considerably higher pre-shift and decreased during shift. In this study, mastic asphalt application led to significantly higher exposure to vapours and aerosols of bitumen, as well as to airborne

  14. Discussion on Technical Requirements and Methods in Underground Waterproof Engineering Construction%浅谈地下防水工程施工的技术要求和方法

    Institute of Scientific and Technical Information of China (English)

    张龙; 唐玉东

    2011-01-01

    The underground waterproof project generally includes waterproofing of concrete waterproofing, cement mortar, painting, plastic sheeting,and metal plates and so on. This paper analyzes the technical points of the construction of underground waterproof works from this perspective.%地下防水工程一般包括防水混凝土防水、水泥砂浆防水、卷材防水、涂料防水、塑料板防水、金属板防水等.本文从这个角度出发,对地下防水工程施工的技术要点进行了分析.

  15. 保温隔热防水一体化的新型屋面水泥波形瓦及施工%ONE KIND OF HEAT PRESERVATION HEAT INSULATION WATERPROOFING INTEGRATION NEW ROOFING CEMENT PANTILE AND CONSTRUCTION

    Institute of Scientific and Technical Information of China (English)

    张杰; 王元有

    2011-01-01

    Heat preservation heat insulation waterproofing cement pantile raw material by the cement, the thermal insulation material, the waterproof hatred water emulsion is composed.The heat preservation heat insulation waterproofing tile collection heat preservation heat insulation, the waterproofing, the light quality integration, the construction are simple, the construction time is short, the comprehensive cost is low. Construction technology included groove construction, roof tile construction, ridge tile construction and node management.%保温隔热防水的水泥波形瓦的原材料由水泥、保温材料、防水憎水乳液组成.该瓦集保温隔热、防水、轻质于一体,施工简便,施工时间短,综合成本低.施工技术包括阴槽流沟施工、屋面瓦施工、脊瓦施工和节点处理.

  16. Penetron水泥基渗透结晶型防水材料施工的应用%Application of Penetron cement foundation infiltration crystalline waterproofing material in construction

    Institute of Scientific and Technical Information of China (English)

    晋斌

    2012-01-01

    The paper introduces the waterproofing mechanism and characteristics of Penetron cement foundation infiltration crystalline waterproofing material.Combining with the underground waterproofing construction practice of Shanxi Haitang international hotel,it specifically describes the construction technology and operation points of Penetron cement foundation infiltration crystalline waterproofing material,which has certain guiding meaning for similar engineering in future.%简要介绍了Penetron膨内传水泥基渗透结晶型防水材料的防水机理、特点,并结合山西海棠国际酒店地下防水施工实践,具体阐述了Penetron水泥基渗透结晶型防水材料施工工艺及操作要点,对今后同类工程具有指导意义。

  17. Life Cycle Analysis of Bitumen Transportation to Refineries by Rail and Pipeline.

    Science.gov (United States)

    Nimana, Balwinder; Verma, Aman; Di Lullo, Giovanni; Rahman, Md Mustafizur; Canter, Christina E; Olateju, Babatunde; Zhang, Hao; Kumar, Amit

    2017-01-03

    Crude oil is currently transported primarily by pipelines and rail from extraction sites to refineries around the world. This research evaluates energy use and greenhouse gas (GHG) emissions for three scenarios (synthetic crude oil and dilbit with and without diluent return) in which 750 000 bpd of Alberta's bitumen is transported 3000 km to determine which method has a lower environmental impact. Each scenario has a pipeline and rail pathway, and the dilbit without diluent return scenario has an additional heated bitumen pathway, which does not require diluent. An Excel based bottom-up model is developed using engineering first-principles to calculate mass and energy balances for each process. Results show that pipeline transportation produced between 61% and 77% fewer GHG emissions than by rail. The GHG emissions decreased by 15% and 73% for rail and pipelines as the capacity increased from 100 000 to 800 000 bpd. A Monte Carlo simulation was performed to determine the uncertainty in the emissions and found that the uncertainty was larger for pipelines (up to ±73%) and smaller for rail (up to ±28%). The uncertainty ranges do not overlap, thus confirming that pipelines have lower GHG emissions, which is important information for policy makers conducting pipeline reviews.

  18. The mechanisms of electrical heating for the recovery of bitumen from oil sands

    Energy Technology Data Exchange (ETDEWEB)

    McGee, B.C.W. [McMillan-McGee Corp., Edmonton, AB (Canada); Vermeulen, F.E. [Alberta Univ., Edmonton, AB (Canada)

    2004-07-01

    This paper described the Electro-Thermal Dynamic Stripping Process (ET-DSP), a thermal recovery process in which oil sands are electrically heated. This technology has evolved since the 1970s as an alternative to steam assisted gravity drainage (SAGD) and surface mining of Alberta's oil sands. The heat and mass transfer mechanisms associated with electrical heating were examined along with the gravity forces to better understand how the heated bitumen is recovered from the oil sand. Initially, all fluids are immobile. Heat is created in the oil sand as a current flows through the connate water. This results in a pressure and temperature distribution that is characteristic to an electrical heating process. The electrical heating process changes as the temperature of the oil sand increases and as the bitumen is produced. The heat, mass and electromagnetic fields are strongly coupled and are in a transient state throughout the recovery process. This paper presented the main mechanism for electrical heating in terms of equations. A 3-dimensional quasi-harmonic finite element electromagnetic model was coupled to a mass and energy equation and solved in time. A thermal recovery strategy was then presented in terms of electrode spacing, duration of heating, energy supply and ideal operating conditions.

  19. Reactivity modeling of the visbreaking of Athabasca bitumen using molecular representations

    Energy Technology Data Exchange (ETDEWEB)

    McCaffrey, W.C.; Gray, M.R. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical and Materials Engineering; Dettman, H.D. [Natural Resources Canada, Devon, AB (Canada). CANMET Energy Technology Centre

    2008-07-01

    The visbreaking of an Athabasca bitumen feedstock was modeled using a Monte Carlo approach. A rule based construction algorithm was then used to create a molecular representation for the Athabasca bitumen. The molecular representation was consistent with many types of data, including 13C-NMR spectroscopy, 1H-NMR spectroscopy, elemental analysis, vapor pressure osmometry, and simulated distillation. Molecular representations that contained a minimum number of molecules were produced using sequential optimization. Each feed molecule was represented using connection and structural matrices. Model compound reactivity studies published in the literature were used to determine the probability of cracking of various C-C and CS bonds. These probabilities were used in a continuous reaction algorithm that used matrix transformations to react feed molecules into product molecules. The reaction simulations were broken down into reaction steps. At each reaction step, molecules were first stochastically chosen to react, and then specific bonds were stochastically chosen to crack. The boiling point of each molecule in the feed and product fractions was calculated using the group contribution theory. The aromaticity, molecular weight, and sulfur content of the cracked liquid product were found to be consistent with the experimental properties.

  20. Flume tank studies to elucidate the fate and behavior of diluted bitumen spilled at sea.

    Science.gov (United States)

    King, Thomas L; Robinson, Brian; Boufadel, Michel; Lee, Kenneth

    2014-06-15

    An economical alternative to conventional crudes, Canadian bitumen, harvested as a semi-liquid, is diluted with condensate to make it viable to transport by pipeline to coastal areas where it would be shipped by tankers to global markets. Not much is known about the fate of diluted bitumen (dilbit) when spilled at sea. For this purpose, we conducted dilbit (Access Western Blend; AWB and Cold Lake Blend; CLB) weathering studies for 13 days in a flume tank containing seawater. After six days of weathering, droplets detached from the AWB slick and were dense enough to sink in seawater. The density of CLB also increased, but at a slower rate compared to AWB, which was attributed to the high concentration of alkylated polycyclic aromatic hydrocarbons in it, which are more resistant to weathering. An empirical, Monod-type model was introduced and was found to closely simulate the increase in oil density with time. Such a model could be used within oil spill models.

  1. Physico-chemical interactions at the concrete-bitumen interface of nuclear waste repositories

    Directory of Open Access Journals (Sweden)

    Sablayrolles C.

    2013-07-01

    Full Text Available This study investigates the fate of nitrate and organic acids at the bitumenconcrete-steel interface within a repository storage cell for long-lived, intermediatelevel, radioactive wastes. The interface was simulated by a multiphase system in which cementitious matrices (CEM V-paste specimens were exposed to bitumen model leachates consisting of nitrates and acetic acid with and without oxalic acid, chemical compounds likely to be released by bitumen. Leaching experiments were conducted with daily renewal of the solutions in order to accelerate reactions. C-steel chips, simulating the presence of steel in the repository, were added in the systems for some experiments. The concentrations of anions (acetate, oxalate, nitrate, and nitrite and cations (calcium, potassium, ammonium and the pH were monitored over time. Mineralogical changes of the cementitious matrices were analysed by XRD. The results confirmed the stability of nitrates in the absence of steel, whereas, reduction of nitrates was observed in the presence of steel (production of NH4+. The action of acetic acid on the cementitious matrix was similar to that of ordinary leaching; no specific interaction was detected between acetate and cementitious cations. The reaction of oxalic acid with the cementitious phases led to the precipitation of calcium oxalate salts in the outer layer of the matrix. The concentration of oxalate was reduced by 65% inside the leaching medium.

  2. The composition of acids in bitumen and in products from saponification of kerogen: Investigation of their role as connecting kerogen and mineral matrix

    Energy Technology Data Exchange (ETDEWEB)

    Razvigorova, M.; Budinova, T.; Tsyntsarski, B.; Petrova, B. [Bulgarian Academy of Sciences, Institute of Organic Chemistry, 1113 Sofia, Acad. Bonchev Str., bl. 9 (Bulgaria); Ekinci, E. [ISIK University, Kumbaba Mevkii, 34980 Istanbul (Turkey); Atakul, H. [Istanbul Technical University, Department of Chemical Engineering, Maslak, 34469 Istanbul (Turkey)

    2008-11-03

    In order to obtain more information and to understand the nature of relation between organic and mineral matter in oil shales, the compositions of soluble bitumen fractions obtained by extraction from Bulgarian oil shales before and after demineralization with 10% HCl, concentrated HF, and a HF/HCl mixture were investigated. The four extracts were quantitatively examined by IR and {sup 1}H NMR spectroscopy. The investigation of isolated acidic material of the bitumen fractions showed that the fatty acids are present in bitumen fractions as free acids, esters and salts. The amount of free acids in bitumen is very small. The dominant part of bitumen acids is associated with mineral components of the oil shales as well as part of them is included in the mineral matrix, and can be separated only after deep demineralization. The kerogen of the oil shales, obtained after separation of the bitumen fractions and mineral components, was subjected to saponification in order to determine the amount of acids, bound as esters to the kerogen matrix. The major components found were n-carboxylic, {alpha},{omega}-di-carboxylic, and aromatic acids. The connection of kerogen with mineral components is accomplished by the participation of carboxylic and complicated ester bonds. Experimental data for the composition of bitumen acids give evidence that algae and terrestrial materials are initial sources in the formation of soluble organic matter of Bulgarian oil shale. (author)

  3. Sulfur species in source rock bitumen before and after hydrous pyrolysis determined by X-ray absorption near-edge structure

    Science.gov (United States)

    Bolin, Trudy B.; Birdwell, Justin E.; Lewan, Michael; Hill, Ronald J.; Grayson, Michael B.; Mitra-Kirtley, Sudipa; Bake, Kyle D.; Craddock, Paul R.; Abdallah, Wael; Pomerantz, Andrew E.

    2016-01-01

    The sulfur speciation of source rock bitumen (chloroform-extractable organic matter in sedimentary rocks) was examined using sulfur K-edge X-ray absorption near-edge structure (XANES) spectroscopy for a suite of 11 source rocks from around the world. Sulfur speciation was determined for both the native bitumen in thermally immature rocks and the bitumen produced by thermal maturation of kerogen via hydrous pyrolysis (360 °C for 72 h) and retained within the rock matrix. In this study, the immature bitumens had higher sulfur concentrations than those extracted from samples after hydrous pyrolysis. In addition, dramatic and systematic evolution of the bitumen sulfur moiety distributions following artificial thermal maturation was observed consistently for all samples. Specifically, sulfoxide sulfur (sulfur double bonded to oxygen) is abundant in all immature bitumen samples but decreases substantially following hydrous pyrolysis. The loss in sulfoxide sulfur is associated with a relative increase in the fraction of thiophene sulfur (sulfur bonded to aromatic carbon) to the extent that thiophene is the dominant sulfur form in all post-pyrolysis bitumen samples. This suggests that sulfur moiety distributions might be used for estimating thermal maturity in source rocks based on the character of the extractable organic matter.

  4. Rheological and chemical evaluation on the ageing properties of SBS polymer modified bitumen: From the laboratory to the field

    NARCIS (Netherlands)

    Liu, G.; Nielsen, E.; Komacka, J.; Greet, L.; Ven, M.V.D.

    2014-01-01

    This study investigated the ageing properties of the styrene-butadiene- styrene polymer modified bitumen (SBS PMB) from the laboratory to the field. The virgin SBS PMB had been kept for 23 years and its field-aged binder was extracted from the reclaimed stone matrix asphalt (SMA) after the 22-year s

  5. Influence of reclaimed asphalt with polymer modified bitumen on properties of different asphalts for a wearing course

    NARCIS (Netherlands)

    Komačka, J.; Remišová, E.; Liu, G.; Leegwater, G.; Nielsen, E.

    2014-01-01

    A laboratory investigation was performed to study the effect of reclaimed asphalt with polymer modified bitumen on the properties describing asphalt performance. Three types of asphalts used for wearing courses in Europe (SMA 11, AC 11 and PA 8) were investigated. Five combinations of reclaimed asph

  6. The Preparation of the Quick-Drying Bitumen Emulsion for the Protection of the Road Surface Asphalt Concrete Layer

    Directory of Open Access Journals (Sweden)

    Victoria S. Ryabenko

    2016-10-01

    Full Text Available The paper considered getting fast drying bitumen emulsion and study its main operating parameters of the film drying rate and durability of the emulsion. The optimum ratio of the components of the emulsion "binder" – "solvent" – "water".

  7. The role of minerals in the thermal alteration of organic matter. III - Generation of bitumen in laboratory experiments

    Science.gov (United States)

    Huizinga, Bradley J.; Tannenbaum, Eli; Kaplan, I. R.

    1987-01-01

    A series of pyrolysis experiments, utilizing two different immature kerogens (from the Monterey and Green River Formations) mixed with common sedimentary minerals (calcite, illite, or Na-montmorillonite), was conducted to study the impact of the mineral matrix on the bitumen that was generated. Calcite has no significant influence on the thermal evolution of bitumen and also shows virtually no adsorption capacity for any of the pyrolysate. In contrast, montmorillonite (M) and illite, to a lesser extent, alter bitumen during dry pyrolysis. M and illite also display strong adsorption capacities for the polar constituents of bitumen. By this process, hydrocarbons are substantially concentrated within the pyrolysate that is not strongly adsorbed on the clay matrices. The effects of the clay minerals are significantly reduced during hydrous pyrolysis. The strong adsorption capacities of M and illite, as well as their thermocatalytic properties, may in part explain why light oils and gases are generated from certain argillaceous source-rock assemblages, whereas heavy immature oils are often derived from carbonate source rocks.

  8. First Observation of the Blending Zone Morphology at the Interface of Reclaimed Asphalt Binder and Virgin Bitumen

    NARCIS (Netherlands)

    Nahar, S.N.; Mohajeri, M.; Schmets, A.J.M.; Scarpas, T.; Van de Ven, M.F.C.; Schitter, G.

    2013-01-01

    One of the challenges in designing recycled asphalt mixtures with a high amount of RAP is to estimate the blending degree between RAP binder and the added virgin bitumen. The extent of blending is crucial in this case as asphalt concrete response is influenced by the final binder properties. This pa

  9. Characterization and utilization of hydrotreated products produced from the Whiterocks (Utah) tar sand bitumen-derived liquid

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, C.H.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.

    1991-12-31

    The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the mined and crushed ore from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor. The purpose was to determine the extent of upgrading as a function of process operating variable. A sulfided nickel-molybendum on alumina hydrodenitrogenation catalyst was used in all experiments. Moderately severe operating conditions were employed; that is, high reaction temperature (617--680 K) high reactor pressure (11.0--17.1 MPa) and low liquid feed rate (0.18--0.77 HSV); to achieve the desired reduction in heteroatom content. Detailed chemical structures of the bitumen-derived liquid feedstock and the hydrotreated total liquid products were determined by high resolution gas chromatography - mass spectrometry analyses. The compounds identified in the native bitumen included isoprenoids; bicyclic, tricycle, and tetracyclic terpenoids; steranes; hopanes; and perhydro-{beta}-carotenes. In addition, normal and branched alkanes and alkenes and partially dehydrogenated hydroaromatics were identified in the bitumen-derived liquid. The dominant pyrolysis reactions were: (1) the dealkylation of long alkyl side chains to form {alpha} - and isoolefins; and (2) the cleavage of alkyl chains linking aromatic and hydroaromatic clusters. Olefinic bonds were not observed in the hydrotreated product and monoaromatic hydrocarbons were the predominant aromatic species. The properties of the jet fuel fractions from the hydrotreated products met most of the jet fuel specifications. The cetane indices indicated these fractions would be suitable for use as diesel fuels.

  10. Characterization and utilization of hydrotreated products produced from the Whiterocks (Utah) tar sand bitumen-derived liquid

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, C.H.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.

    1991-01-01

    The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the mined and crushed ore from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor. The purpose was to determine the extent of upgrading as a function of process operating variable. A sulfided nickel-molybendum on alumina hydrodenitrogenation catalyst was used in all experiments. Moderately severe operating conditions were employed; that is, high reaction temperature (617--680 K) high reactor pressure (11.0--17.1 MPa) and low liquid feed rate (0.18--0.77 HSV); to achieve the desired reduction in heteroatom content. Detailed chemical structures of the bitumen-derived liquid feedstock and the hydrotreated total liquid products were determined by high resolution gas chromatography - mass spectrometry analyses. The compounds identified in the native bitumen included isoprenoids; bicyclic, tricycle, and tetracyclic terpenoids; steranes; hopanes; and perhydro-{beta}-carotenes. In addition, normal and branched alkanes and alkenes and partially dehydrogenated hydroaromatics were identified in the bitumen-derived liquid. The dominant pyrolysis reactions were: (1) the dealkylation of long alkyl side chains to form {alpha} - and isoolefins; and (2) the cleavage of alkyl chains linking aromatic and hydroaromatic clusters. Olefinic bonds were not observed in the hydrotreated product and monoaromatic hydrocarbons were the predominant aromatic species. The properties of the jet fuel fractions from the hydrotreated products met most of the jet fuel specifications. The cetane indices indicated these fractions would be suitable for use as diesel fuels.

  11. 如何确定场地抗浮设防水位%How to determine the in-situ anti-floating waterproof location

    Institute of Scientific and Technical Information of China (English)

    熊维; 王瑞海; 刘佳忆

    2012-01-01

    Integrating with the definition of anti-floating waterproof location and relevant norms, taking the specific engineering as an example, the paper explores how to determine the in-situ anti-floating waterproof location, describes the factors influencing the field groundwater level, and analyzes parameters of groundwater level period and groundwater yearly variation scope. In the end, it draws some guiding conclusions.%结合抗浮设防水位的定义及相关规范规定,以具体工程为例,探讨了场地抗浮设防水位如何确定,阐述了影响该场地地下水的因素,并对地下水位期和地下水位年变幅等参数进行了分析,从而得出了一些指导性结论。

  12. 软土基坑隔水帷幕渗漏检测技术%Leakage Detection in Waterproof Curtain of Soft Soil Foundation Pit

    Institute of Scientific and Technical Information of China (English)

    孟庆生; 韩凯; 刘涛; 高镇

    2016-01-01

    隔水帷幕渗漏是影响软土基坑稳定性的关键问题。针对隔水帷幕渗漏检测技术,开展了数值模拟和物理模型试验,深入研究了不同采集装置类型三维电阻率法和探地雷达法对渗漏异常的反映能力及在探测剖面上表现出来的异常特征,给出了判断帷幕是否渗漏和确定渗漏点位置的解释方法。结果表明:温纳装置、偶极装置和温纳施龙贝格装置都能有效反映渗漏点的存在;降水后帷幕未发生渗漏时,与基坑外侧软土含水层相比,内侧软土层电阻率表现为高阻异常;帷幕渗漏后基坑内侧底部软土层电阻率降低,外侧电阻率升高,并呈现漏斗状异常,两侧低阻异常与帷幕的交叉点可正确指示渗漏点位置;帷幕发生渗漏后,基于基坑外侧的探地雷达探测剖面中会出现双曲型反射波同相轴,通过其顶点可确定渗漏点的位置。研究结果证实了两种地球物理手段开展软土基坑隔水帷幕渗漏检测的可行性。%The leakage of waterproof curtain is a serious problem for the stability of soft soil foundation pit. In respect of the leakage detection methods of waterproof curtain, the numerical simulation and indoor physical model test were performed to verify the ability to determine the leakage position of the three different arrays of 3D resistivity methods and GPR method,and to discuss the anomaly characteristics in detecting profile.At the same time,the judgment of whether the waterproof curtain leak or not and the interpretation method of leakage position were also made.The research shows that:the resistivity method can reflect the existence of leakage position effectively by Wenner array,dipole-dipole array,and Wenner-Schlumberger array;it reveals high resistivity of soil inside foundation pit compared with that of outside the foundation pit without leakage of waterproof curtain;on the contrary,the resistivity will decrease at the

  13. 智能防水透湿聚氨酯研究进展%Development of Shape Memory Polyurethane on Intelligent Waterproof and Water Vapour Permeable

    Institute of Scientific and Technical Information of China (English)

    王玮玲; 于伟东

    2014-01-01

    简要介绍了实现形状记忆聚氨酯( SMPU)的智能透湿机理,综述了SMPU在智能透湿性方面的研究进展及智能防水透湿膜和织物研究中存在的问题,提出了研究开发具有创新功能的智能防水透湿织物是未来纺织工业发展的趋势。%The mechanism of waterproof and water vapor permeable of shape memory polyurethane was brief in⁃troduced. The research progress of shape memory polyurethane(SMPU) in intelligent water vapor permeability and problem which existed in membrane and fabrics of smart waterproof breathable were summerized. The research of in⁃telligent water proof and breathable fabrics with innovation function was the trend of textiles in the future.

  14. Design and development of outdoor intelligent waterproof clothes-drying device%室外智能防风雨晾衣装置的研制

    Institute of Scientific and Technical Information of China (English)

    梁永; 林诗怡; 黄鉴昆; 李安然

    2013-01-01

    The design and development process of outdoor intelligent waterproof clothes-drying device is introduced in this paper. The device will control DC motor to shrink the clothes rod and delay control electromagnet to lay down the waterproof along the groove in the aluminum profiles when it has rain or snow,even other odious weather.Through commanding the DC motor to spin the rope winding stick and raise the waterproof,then stretch the clothes rod when the weather becomes good.It can be operated manually to raise the waterproof and take back the clothes when it meets the situation like the power shortage or other breakdown of mechanical control.The mechatronics device has simple structure,convenient operation and good market prospects.%设计研制一种智能防雨晾衣装置,当遇到雨雪等恶劣天气时,该装置先控制伸缩衣杆的收缩,再由电磁铁延迟加电让遮雨布沿着铝型材内的导槽自动放下;而当天气晴朗时,可驱动绕绳杆将遮雨布收起后伸展晾衣杆。遇到电源失电或者其它故障时则可手动卷起遮雨布收回衣物。该装置结构简单,操纵便捷,具有较好的市场应用前景。

  15. 浅议屋面卷材防水的施工与维护%Construction and Maintenance of Waterproof Reefing with Coiled Material

    Institute of Scientific and Technical Information of China (English)

    魏周苔

    2011-01-01

    屋面防水工程是保证建筑物能够发挥正常使用功能和使用年限的一项重要因素.合理选择卷材品种、严格控制卷材质量、规范防水施工工艺是保证防水质量的关键环节;科学管理、定期检查、及时维修是决定屋面使用寿命的重要因素.探讨了对屋面卷材防水施工及维护的有关技术问题.%Waterproof roofing is an important factor to guarantee the function and the service life of the building. Reasonable choice of the coiled material, the Quality control inspection and construction technology standard is the key to waterproof quality. Scientific managencent, timely repairment are decisive to the service life of the roof. The technological problem about the construction and maintenance of the waterproof roofing with coiled material were disscussed in detail.

  16. Construction Control Method for Waterproof and Drainage of Highway Tunnel%公路隧道防排水施工控制方法

    Institute of Scientific and Technical Information of China (English)

    雷永刚

    2014-01-01

    隧道施工期间防排水施工不达标,对于隧道后期运营以及隧道使用寿命存在很大的影响,且进行防排水处理难度大、费用高,效果差.以米仓山隧道为例,介绍了公路隧道防排水施工方法,铺设PVC复合土工布防水板工艺、排水管道施工等,希望对相关领域工程设计与施工实践等起到一定的借鉴作用.%The non-compliance waterproof and drainage system during tunnel construction would be a huge threat to operation and the service life of the tunnel.Besides,it will increase the difficulties and costs for repairing,and normally will receive poor effect.Taking Micangshan Tunnel as an example,this paper introduces the highway tunnel waterproof and drainage construction,PVC composite geotextile waterproof board technology,drainage pipeline construction,etc.Hopefully,it may provide some reference to related engineering design and construction practice.

  17. 氟硅树脂石膏防水剂的制备与应用%Application and preparation of water-proofing fluorin silicon gypsum additive

    Institute of Scientific and Technical Information of China (English)

    潘红; 李国忠

    2011-01-01

    以有机氟﹑有机硅以及(甲基)丙烯酸酯为原料,采用溶液聚合的方法制备了氟硅树脂防水剂,探讨了软硬单体配比、反应温度和单体投入方式对防水剂性能的影响,确定了工艺参数。研究了此防水剂对石膏试样耐水性能的影响。试验结果表明:该氟硅树脂石膏防水剂对石膏试样的短期防水性能具有显著改善,但长期使用时,防水性能有一定程度的削弱。%Organic fluorine,organic silicon,and(methyl) acrylate are used to prepare a water-proofing gypsum additive which is a fluorosilicon resin by liquor polymerization method.Effects of soft hard monomer ratio,reaction temperature and the introducing model of monomers on the properties of the waterproofing additive are discussed,and the process parameters are determined.Experiment shows that the early waterproofing performance of gypsum samples with the additive is significantly improved,but the water resistance is weakened to a certain extent for a long time.

  18. Fluidized bed pyrolysis of bitumen-impregnated sandstone at sub-atmospheric conditions

    Energy Technology Data Exchange (ETDEWEB)

    Fletcher, J.V.; Deo, M.D.; Hanson, F.V.

    1993-01-01

    A 15.2 cm diameter fluidized bed reactor was designed, built, and operated to study the pyrolysis of oil sands at pressures slightly less than atmospheric. Fluidizing gas flow through the reactor was caused by reducing the pressure above the bed with a gas pump operating in the vacuum mode. Pyrolysis energy was supplied by a propane burner, and the hot propane combustion gases were used for fluidization. The fluidized bed pyrolysis at reduced pressure using combustion gases allowed the reactor to be operated at significantly lower temperatures than previously reported. At 450[degree], over 80% of the bitumen fed was recovered as a liquid product, and the spent sand contained less than 1% coke. The liquid product recovery system, by design, yielded three liquid streams with distinctly different properties.

  19. Fluidized bed pyrolysis of bitumen-impregnated sandstone at sub-atmospheric conditions

    Energy Technology Data Exchange (ETDEWEB)

    Fletcher, J.V.; Deo, M.D.; Hanson, F.V.

    1993-03-01

    A 15.2 cm diameter fluidized bed reactor was designed, built, and operated to study the pyrolysis of oil sands at pressures slightly less than atmospheric. Fluidizing gas flow through the reactor was caused by reducing the pressure above the bed with a gas pump operating in the vacuum mode. Pyrolysis energy was supplied by a propane burner, and the hot propane combustion gases were used for fluidization. The fluidized bed pyrolysis at reduced pressure using combustion gases allowed the reactor to be operated at significantly lower temperatures than previously reported. At 450{degree}, over 80% of the bitumen fed was recovered as a liquid product, and the spent sand contained less than 1% coke. The liquid product recovery system, by design, yielded three liquid streams with distinctly different properties.

  20. Modeling of a three-phase reactor for bitumen-derived gas oil hydrotreating

    Directory of Open Access Journals (Sweden)

    R. Chacón

    2012-03-01

    Full Text Available A three-phase reactor model for describing the hydrotreating reactions of bitumen-derived gas oil was developed. The model incorporates the mass-transfer resistance at the gas-liquid and liquid-solid interfaces and a kinetic rate expression based on a Langmuir-Hinshelwood-type model. We derived three correlations for determining the solubility of hydrogen (H2, hydrogen sulfide (H2S and ammonia (NH3 in hydrocarbon mixtures and the calculation of the catalyst effectiveness factor was included. Experimental data taken from the literature were used to determine the kinetic parameters (stoichiometric coefficients, reaction orders, reaction rate and adsorption constants for hydrodesulfuration (HDS and hydrodenitrogenation (HDN and to validate the model under various operating conditions. Finally, we studied the effect of operating conditions such as pressure, temperature, LHSV, H2/feed ratio and the inhibiting effect of H2S on HDS and NH3 on HDN.

  1. Preparation and application of gypsum block waterproofing agent%石膏砌块防水剂的制备与应用研究

    Institute of Scientific and Technical Information of China (English)

    潘红; 李国忠

    2012-01-01

    选用自由基溶液聚合的方式合成氟硅改性丙烯酸酯树脂,加入固化剂制得双组分石膏砌块防水剂。研究了有机硅功能单体、有机氟功能单体对防水剂憎水性能的改性效果,探讨了功能单体的作用机理。分别选用外涂和内掺的方法将制得的防水剂用于石膏砌块试样中,研究其对石膏砌块试样的抗折、抗压强度、吸水率以及软化系数的影响。试验结果表明:外涂防水剂的方法可明显降低石膏砌块试样浸水2h的吸水率;内掺防水剂的方法对石膏砌块试样的浸水2h、24h吸水率均有了一定程度的改善,其24h软化系数为0.71,达到防潮石膏砌块的标准要求。%A kind of gypsum block waterproofing agent is introduced, which is made of fluorine silicon modified acrylate resin and hardener. The modification effect of organic silicon and organic fluorine monomers on the water resistant of the waterproofing agent is researched. The waterproofing agent is respectively applied on gypsum block samples by coating or doping method. Effects of the agent on flexural strength, compressive strength and water absorption of gypsum block samples are studied. The experimental results show that the water absorption of gypsum block sample coated with waterproofing agent in water for 2h is significantly reduced; and the water absorption of gypsum block sample added waterproofing agent in water for 2h and 24h is also reduced, which softening coefficient reaches 0.71 for 24h, and fulfills the standard requirement of moisture resistant gypsum blocks.

  2. Improvement of Life Expectancy of Jute Based Needlepunched Geotextiles Through Bitumen Treatment

    Science.gov (United States)

    Ghosh, S. K.; Ray Gupta, K.; Bhattacharyya, R.; Sahu, R. B.; Mandol, S.

    2014-12-01

    Geotextiles have witnessed unrivalled growth worldwide in recent years in the field of different civil engineering constructions. The world of Geotextiles includes mainly non-biodegradable synthetic materials which are not environmentally compatible. With the increasing human awareness on environmental pollution aspects, biodegradable Jute Geotextile is increasingly gaining ground over its synthetic non-biodegradable counterpart. Though Jute is advantageous for its complete biodegradability in one hand but on the other hand it is disadvantageous for its poor microbial resistance and quicker biodegradation particularly under moist soil conditions, when applied as Geotextiles under soil. Therefore, it is a great challenge to the present researchers to make jute more microbial resistant (rot resistant) keeping its biodegradability intact during its performance period. Thorough investigation and study regarding the improvement of the durability of natural Jute Geotextile reveals the fact that though several attempts including chemical treatments have been made to enhance the life expectancy of jute fabrics yet these methods were neither found to be suitable nor techno-economically viable. Therefore, in order to accomplish the objective and based on the researchers' report of satisfactory thermal compatibility between hot bitumen and jute nonwoven fabrics, in the present study Bitumen emulsion with essential additives has been applied following a special technique, apart from the conventional method, on the Grey Jute Nonwoven Fabrics in different add on percentages to make a comparative assessment of the performance of both Grey Jute Fabrics and Bituminized Jute Nonwoven Fabrics by Soil Burial Test as per the BIS standard test method. The test results revealed that the durability and performance of the Bituminized Nonwoven Jute Fabrics are much better than that of Grey Jute Nonwoven Fabrics.

  3. Purification of Indonesian oil sands bitumen%印尼油砂沥青的净化工艺

    Institute of Scientific and Technical Information of China (English)

    罗宽勇; 韩冬云; 李福起; 石薇薇; 庞海全; 曹祖宾

    2016-01-01

    溶剂萃取法分离油砂制得油砂沥青中含大量机械杂质,影响沥青的品质及后期加工利用。通过XRD和激光粒度仪表征了机械杂质的矿物组成和粒度分布等特性。针对机械杂质的特性,开发了复配试剂,通过稀释剂降黏沥青、复配试剂净化沥青、稀释剂回收再生及循环利用3个操作单元对油砂沥青进行了脱杂净化实验,并分析了净化机理。结果表明:降黏过程,温度70℃、时间10min、稀释剂与沥青比0.3g/g,稀释沥青70℃黏度为3.2Pa·s;净化过程,6%盐酸与稀释沥青比0.2mL/g、CaCl2与稀释沥青比0.01g/g,温度70℃,混合时间10min,沉降时间20min,机械杂质脱除率可达到93.5%;回收及循环过程,稀释剂回收率为98%,循环使用5次,机械杂质脱除率仍92%以上。该工艺具有沉降时间短、机械杂质脱除彻底的优点。%Oil sands bitumen obtained from solvent extraction contained a great amount of mechanical impurities(MI),which was harmful to the post processing of bitumen. The characterization of mineral components of MI by XRD and particle size distribution of MI by laser particle analyzer were presented. Compound reagent was developed for the removal of MI and the reaction mechanism was presented. The technology consisted of three steps,namely,dilution of bitumen by diluent(P1), purification of diluted bitumen by compound reagent(P2)and recovery of diluent(P3). In P1,under the optimal reaction conditions of 70℃,10min,m(diluent)/m(bitumen)=0.3g/g,the viscosity of diluted bitumen at 70℃ was 3.2Pa·s. In P2,under the optimal reaction conditions ofV(HCl,6%)/m(diluted bitumen)=0.2mL/g,m(CaCl2)/m(diluted bitumen)=0.01g/g,70℃,mixing time 10min,settling time 20min,the mechanical impurities removal rate(MIRR)could reach 93.5%. In P3,the recovery rate of diluent was 98%,MIRR remained above 92% after diluent being recycled 5 times. The technology has the advantages of short

  4. Differences in bitumen and kerogen-bound fatty acid fractions during diagenesis and early catagenesis in a maturity series of New Zealand coals

    DEFF Research Database (Denmark)

    Glombitza, Clemens; Mangelsdorf, Kai; Horsfield, Brian

    2016-01-01

    differences in the fatty acid composition between bitumen and kerogen-bound acids, both in the short (fatty acid range. The compositions of these two acid fractions changed independently as a function of maturation. This points to the long and short chain fatty acids in bitumen......Oxygen-bearing functional groups, in particular the carboxylic groups of acids and esters, are mainly responsible for the chemical reactivity of sedimentary organic matter. We have studied kerogen and bitumen fractions from a coalification series from the New Zealand Coal Band covering the rank...... range from 0.28% to 0.80% vitrinite reflectance. We investigated the composition of fatty acids separated from the bitumen, and compared this to the distribution of kerogen-bound fatty acids (esters) obtained after selective chemical degradation of the macromolecular organic matter. We found remarkable...

  5. Characterization of the viscoelastic behavior of the pure bitumen grades 10/20 and 35/50 with macroindentation and finite element computation

    KAUST Repository

    Hamzaoui, Rabah

    2013-06-23

    In this article, we present an identification procedure that allows the determination of the viscoelasticity behavior of different grades of pure bitumen (bitumen 35/50 and bitumen 10/20). The procedure required in the first stage a mechanical response based on macroindentation experiments with a cylindrical indenter. A finite element simulation was performed in the second stage to compute the mechanical response corresponding to a viscoelasticity model described by three mechanical parameters. The comparison between the experimental and numerical responses showed a perfect matching. In addition, the identification procedure helped to discriminate between different bitumens characterized by different asphaltene and maltene contents. Finally, the developed procedure could be used as an efficient tool to characterize the mechanical behavior of the viscoelastic materials, thanks to the quantified relationship between the viscoleastic parameters and the force-penetration response. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3440-3450, 2013 Copyright © 2013 Wiley Periodicals, Inc.

  6. Encapsulated, High-Performance, Stretchable Array of Stacked Planar Micro-Supercapacitors as Waterproof Wearable Energy Storage Devices.

    Science.gov (United States)

    Kim, Hyoungjun; Yoon, Jangyeol; Lee, Geumbee; Paik, Seung-Ho; Choi, Gukgwon; Kim, Daeil; Kim, Beop-Min; Zi, Goangseup; Ha, Jeong Sook

    2016-06-29

    We report the fabrication of an encapsulated, high-performance, stretchable array of stacked planar micro-supercapacitors (MSCs) as a wearable energy storage device for waterproof applications. A pair of planar all-solid-state MSCs with spray-coated multiwalled carbon nanotube electrodes and a drop-cast UV-patternable ion-gel electrolyte was fabricated on a polyethylene terephthalate film using serial connection to increase the operation voltage of the MSC. Additionally, multiple MSCs could be vertically stacked with parallel connections to increase both the total capacitance and the areal capacitance owing to the use of a solid-state patterned electrolyte. The overall device of five parallel-connected stacked MSCs, a microlight-emitting diode (μ-LED), and a switch was encapsulated in thin Ecoflex film so that the capacitance remained at 82% of its initial value even after 4 d in water; the μ-LED was lit without noticeable decrease in brightness under deformation including bending and stretching. Furthermore, an Ecoflex encapsulated oximeter wound around a finger was operated using the stored energy of the MSC array attached to the hand (even in water) to give information on arterial pulse rate and oxygen saturation in the blood. This study suggests potential applications of our encapsulated MSC array in wearable energy storage devices especially in water.

  7. Discuss the Fire Elevator Waterproof Measures%浅谈消防电梯防水的措施

    Institute of Scientific and Technical Information of China (English)

    陈玉茂

    2014-01-01

    高层建筑已成为城市建筑的主要选择,超过一定规模的建筑,按照现行规范的规定一定要设置消防电梯。本文从消防电梯的重要性着手,分析消防电梯不防水的原因及危害,有针对性地提出应对方法,确保消防电梯在关键时候不“罢工”。%High-rise buildings have become the main choice of urban buildings. In excess of a certain size of city con-struction buildings, where must set the fire elevator on the basis of the regulation of current specification. This article starts from the importance of fire elevator, analyzes the cause and damage of the fire lift with no waterproof, and ensures the fire elevator does not"strike"in the right time.

  8. 浅谈铁路隧道防水施工技术%On Waterproof Construction Technology of Railway Tunnel

    Institute of Scientific and Technical Information of China (English)

    张伟

    2014-01-01

    铁路一直都是我国重要的交通运输方式之一,在铁路施工的过程中,隧道防水就是工程质量好坏与否的关键点。本文就铁路隧道防水施工技术的意义和基本的防水施工工艺方法进行了简要的分析,阐述了我国铁路隧道渗漏水的主要原因及应对措施。%Railway has always been one of China's important transportation way, and in the process of railway construction, tunnel waterproof is the key point of engineering quality. This paper makes a brief analysis on the significance of the waterpr- oof construction technique of railway tunnel and basic wate- rproof construction technology and method, elaborates the ma- in reason and countermeasures of railway tunnels water leak- age infiltration in China.

  9. In-situ bitumen extraction associated with increased petrogenic polycyclic aromatic compounds in lake sediments from the Cold Lake heavy oil fields (Alberta, Canada).

    Science.gov (United States)

    Korosi, Jennifer B; Cooke, Colin A; Eickmeyer, David C; Kimpe, Linda E; Blais, Jules M

    2016-11-01

    Most future growth in the Alberta bituminous sands will be based on thermal in-situ recovery technologies. To date, however, most attention on the environmental effects of bitumen recovery has focused on surface mining in the Athabasca region. Recent uncontrolled bitumen flow-to-surface incidents (FTS; appearance at the surface of bitumen emulsions from deep subsurface recovery zones) reported at the Cold Lake heavy oil fields highlight the need to better understand the potential role of in-situ extraction as a source of contaminants to landscapes and surface waters. We analyzed sediment cores from a lake located ∼2 km away from a recent bitumen FTS incident to provide a long-term perspective on the delivery of metals, polycyclic aromatic compounds (PACs), and polychlorinated biphenyls (PCBs) to surface freshwaters, and to assess whether the onset of local in-situ bitumen extraction can be linked to contaminant increases in nearby lakes. An increase in alkyl PACs coincided with the onset and expansion of commercial in-situ bitumen extraction, and multiple lines of evidence indicate a petrogenic source for recent alkyl PAC enrichment. However, no coincident increase in vanadium (enriched in bitumen) occurred that would suggest the source of petrogenic PAC enrichment is direct input of bituminous particles. Our results show that, similar to surface mining in the Athabasca region, activities associated with in-situ extraction can increase the burden of petrogenic PACs in nearby lakes, but many questions still remain regarding the exact sources and pathways of PACs into the environment. Given that more than 80% of Alberta's bitumen reserves can only be accessed using in-situ technologies, we recommend that this be made a research priority.

  10. Upstream petroleum industry flaring and venting report : industry performance for year ending December 31, 2008

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-06-15

    The Energy Resources Conservation Board (ERCB) has developed recommendations for a flaring and venting management framework for the province of Alberta. This report fulfilled the ERCB's information mandate regarding flaring and venting as part of a commitment made in Directive 060 for upstream petroleum industry flaring, incineration, and venting to make flaring and venting data more accessible. It included data on upstream petroleum industry flaring and venting with particular reference to solution gas conserved, flared and vented, from 1996 to 2008; solution gas flaring and venting performance; flaring from all upstream oil and gas sources, from 2000 to 2008; venting from all upstream oil and gas sources, from 2000 to 2008; solution gas flaring and venting maps; and solution gas emissions ranking of operators for 2007. The report also provided a summary of flaring and venting from various oil and gas industry sources, such as well tests, gas plants, gas gathering systems, transmission lines, and batteries. Ranking of companies was established based on solution gas flared plus vented; solution gas flared; and solution gas vented from crude oil and bitumen batteries. The data used in the preparation of this report was submitted by companies. The report revealed that considerable progress has been made in the reduction of flaring and venting volumes for all upstream oil and gas sources. The reduction can be attributed to the decline in new conventional oil production. It can also be correlated to the decline in volumes of solution gas formerly being flared, and now being vented. Solution gas vented in 2008 was 40.7 per cent less than the 2000 venting baseline. However, in 2008, there was a 25.9 per cent increase in venting from crude bitumen batteries which can be correlated to the increase in crude bitumen production. The ERCB is continuing to work with the Clean Air Strategic Alliance to examine options to further address solution gas venting. tabs., figs.

  11. Development of an on-line coupling of liquid-liquid extraction, normal-phase liquid chromatography and high-resolution gas chromatography producing an analytical marker for the prediction of mutagenicity and carcinogenicity of bitumen and bitumen fumes.

    Science.gov (United States)

    Blomberg, J; de Groot, P C; Brandt, H C; van der Does, J J; Schoenmakers, P J

    1999-07-23

    A fast and fully automated system for the determination of polycyclic aromatic compounds (PACs) is described. The system has been developed to produce an analytical 'marker', correlating chemical characteristics (including PAC analysis) with mutagenicity and carcinogenicity. The products of interest are bitumen fumes, bitumen and other (heavy or even residual) oil products, regardless of their boiling range. Dimethyl sulphoxide (DMSO) extractables obtained from a flow-injection analysis (FIA) system are introduced on-line in a normal-phase liquid chromatographic (NPLC) system. Here, the PACs are separated from the DMSO and possible co-extracted heavy residual species. The final step incorporates on-line gas chromatographic analysis of the three-to-six-ring PAC fraction, followed by flame-ionisation detection for quantification. It was demonstrated that data obtained from samples in the distillate lubrication-oil range correlate well with data obtained from the manual DMSO-extraction method standardised by the Institute of Petroleum as IP346.

  12. An NMR (Nuclear Magnetic Resonance) Investigation of the Chemical Association and Molecular Dynamics in Asphalt Ridge Tar Sand Ore and Bitumen

    Science.gov (United States)

    Netzel, D. A.; Coover, P. T.

    1987-09-01

    Preliminary studies on tar sand bitumen given in this report have shown that the reassociation of tar sand bitumen to its original molecular configuration after thermal stressing is a first-order process requiring nearly a week to establish equilibrium. Studies were also conducted on the dissolution of tar sand bitumen in solvents of varying polarity. At a high-weight fraction of solute to solvent the apparent molecular weight of the bitumen molecules was greater than that of the original bitumen when dissolved in chloroform-d{sub 1} and benzene-d{sub 6}. This increase in the apparent molecular weight may be due to micellar formation or a weak solute-solvent molecular complex. Upon further dilution with any of the solvents studied, the apparent molecular weight of the tar sand bitumen decreased because of reduced van der Waals forces of interaction and/or hydrogen bonding. To define the exact nature of the interactions, it will be necessary to have viscosity measurements of the solutions.

  13. The investigation of the bitumen from ancient Greek amphora using FT ICR MS, H/D exchange and novel spectrum reduction approach.

    Science.gov (United States)

    Kostyukevich, Yury; Solovyov, Sergey; Kononikhin, Alexey; Popov, Igor; Nikolaev, Eugene

    2016-06-01

    Recently Russian archeologists have discovered on Taman peninsula an ancient (V B.C.) Greek amphora full of dense bitumen. This is the oldest amphora in the world that contains bitumen. We report the investigation of this bitumen using ultrahigh resolution Fourier transform mass spectrometry. Also we used recently developed in-ESI source Hydrogen/Deuterium exchange approach for the structural characterization of the individual molecules and estimation of the biodegradation of the bitumen. The increase of number of the labile hydrogens compared to the non-degraded oil can serve as an additional evidence of the degradation of bitumen via oxidation. For the facilitation of the spectrum processing we have developed the special iterative spectrum reduction approach. It was observed that molecules that have only oxygen heteroatoms possess two -OH groups what is unusual for the petroleum. Based on this we suggested that the bitumen degraded during its being in amphora for 2500 years. Copyright © 2016 John Wiley & Sons, Ltd.

  14. Application of natural sodium base bentonite waterproof blanket in artificial lake (Longzi Lake) project%天然钠基膨润土防水毯在人工湖(龙子湖)工程中的应用

    Institute of Scientific and Technical Information of China (English)

    雷松; 谢长福

    2015-01-01

    Natural sodium base bentonite waterproof blanket belongs to a novel geosynthetic waterproof material. In the paper, application condition of natural sodium base bentonite waterproof blanket in artificial lake ( Longzi Lake ) is expounded. Meanwhile, waterproof blanket anti-seepage technology is compared with traditional anti-seepage technology. Practice proves that natural sodium base bentonite waterproof blanket has wider application prospect than traditional anti-seepage technology.%天然钠基膨润土防水毯是一种新型的土工合成防水材料。本文详细阐述了在人工湖(龙子湖)的湖体防渗中应用天然钠基膨润土防水毯的情况,同时将防水毯防渗技术与传统的防渗技术进行对比。实践证明,天然钠基膨润土防水毯防渗技术比传统的防渗技术具有更广阔的应用前景。

  15. 浅谈监理在建筑防水工程中的主要监控措施%The Main Control Measures of the Supervision of Building Waterproofing Engineering

    Institute of Scientific and Technical Information of China (English)

    谭兵

    2014-01-01

    Building waterproof technology plays a functional role in protection of housing construction, That the housing construction can ensure al parts to be not subjected to various water leakage is directly related to the use of housing function, quality of life of owners and living environment. This paper di-scussed some supervision measures of quality control of wate-rproof engineering including basement waterproof, floor wat-erproof and building surface waterproof.%建筑防水技术在房屋建筑中发挥功能保障作用,房屋建筑所有部位能否保证免受各种水的侵入而不渗漏,直接关系到房屋的使用功能、生活质量和人居环境。本文着重谈了监理对地下室防水工程、屋面防水和楼面防水质量控制的一些监理措施。

  16. Paleoenvironmental implications of novel C[sub 30] steranes in Precambrian to Cenozoic age petroleum and bitumen

    Energy Technology Data Exchange (ETDEWEB)

    McCaffrey, M.A.; Lipton, P.A. (Chevron Petroleum Technology Company, La Habra, CA (United States)); Moldowan, J.M. (Cheveron Petroleum Technology Company, Richmond, CA (United States) Stanford Univ., CA (United States)); Summons, R.E. (Australian Geological Survey Organization, Canberra City (Australia)); Peters, K.E. (Chevron Overseas Petroleum Inc., San Ramon, CA (United States) Mobil Exploration and Producing Technical Center, Dallas, TX (United States)); Jeganathan, A.; Watt, D.S. (Univ. of Kentucky, Lexington, KY (United States))

    1994-01-01

    Petroleums and bitumens from Early Proterozoic ([approx] 1800 Ma) to Miocene ([approx] 15 Ma) age marine strata contain 24-isopropylcholestanes, a novel group of C[sub 30] steroids. The abundance of these compounds, relative to 24-n-propylcholestanes, varies with source rock age. Late Proterozoic (Vendian) and Early Cambrian oils and/or bitumens from Siberia, the Urals, Oman, Australia, and India have a high ratio of 24-isopropylcholestanes to 24-n-propylcholestanes ([ge] 1), while younger and older samples have a low ratio ([le]0.4). Temporal changes in this parameter may reflect the relative abundance of certain Porifera (sponges) and certain Marine algae through time. Geochemical indicators such as this, which can constrain the source rock age of a migrated oil, are useful in source rock identification during petroleum exploration.

  17. Geostatistical modeling of facies, bitumen grade and particle size distribution for the Joslyn oil sand open pit mine project

    Energy Technology Data Exchange (ETDEWEB)

    Babak, Olena; Insalaco, Enzo; Mittler, Andreas [Total EandP Canada Ltd. (Canada)

    2011-07-01

    The Joslyn North Mine Project is currently in the pre-development stage; the aim of this study is to use different available data to draw a geological model of facies, bitumen grade, full particle size distribution (PSD) and ore/waste discrimination. The study was conducted with the database of around 800 wells, stochastic, indicator and Gaussian simulations were performed along with a sensitivity study. Results demonstrated the importance of some parameters for evaluating grade cases including variogram uncertainty, sampling limitations and errors in geostatistical workflow. In addition, modeling the full PSD dataset was shown to be useful. This study demonstrated how to use available database through an overall workflow to develop case scenarios for bitumen in place in ore and characterize the ore material.

  18. The influence of UV aging of a styrene/butadiene/styrene modified bitumen: comparison between laboratory and on site aging

    Energy Technology Data Exchange (ETDEWEB)

    Francoise Durrieu; Fabienne Farcas; Virginie Mouillet [Service Physico-chimie des Materiaux, Paris (France). Laboratoire Central des Ponts et Chaussees

    2007-07-15

    During the service life in a pavement, neat bitumen and modified bitumen age as the result of the mixing with aggregates, the process of laying, the climatic conditions and the traffic. Laboratory methods for simulating the short-term and long-term ageing (RTFOT and PAV, respectively) are standardized. None of them takes into account the influence of UV radiations. In the particular case of a pavement located in south France, a comparison is drawn through Fourier Transformed InfraRed (FTIR) analysis. Three types of ageing are compared: the standard simulated ageings, the actual on site ageing after 12 and 26 months of road service and the ageing when UV exposure in a weathering oven follows RTFOT simulation. According to carbonyle function evolution by FTIR spectroscopy, this work shows that for all tested binders, the same ageing level as the one simulated by PAV is reached in a few hours when a thin film of binder is submitted to UV exposure after RTFOT. It is also to be noted that the level of the on site ageing of a SBS Polymer modified Bitumen (PmB) reaches the simulated PAV ageing after 12 months of pavement life. 23 refs., 7 figs., 4 tabs.

  19. Bitumen II from the Paleoproterozoic Here’s Your Chance Pb/Zn/Ag deposit: Implications for the analysis of depositional environment and thermal maturity of hydrothermally-altered sediments

    Science.gov (United States)

    Holman, Alex I.; Grice, Kliti; Jaraula, Caroline M. B.; Schimmelmann, Arndt

    2014-08-01

    The formation of sedimentary exhalative (SEDEX) Pb/Zn deposits is linked to ocean euxinia, but recent evidence suggests that ferruginous conditions may have dominated the deep ocean during the Middle Proterozoic, a maximum period for SEDEX distribution. Biomarkers of sulfate-reducing and sulfide-oxidising bacteria are valuable indicators of euxinic conditions in such settings. Organic matter (OM) from SEDEX deposits is often affected by alteration and/or migration, but OM entrapped within the kerogen/mineral matrix (Bitumen II) may be less affected than the freely-extractable OM (Bitumen I). We analysed Bitumen II from the Paleoproterozoic Here’s Your Chance (HYC) Pb/Zn/Ag deposit to find evidence of euxinic conditions in the depositional environment. n-Alkane distributions in Bitumen II are markedly distinct from previously-reported Bitumen I. Bitumen II contains long-chain n-alkanes (up to C36 or C38) and a strong even-over-odd distribution in a number of samples, which are 4‰ to 7‰ depleted in 13C compared to n-alkanes in Bitumen I and verified as indigenous by comparison with δ13C of isolated kerogen. These features are interpreted as evidence of sulfate-reducing and sulfide-oxidising bacteria, confirming that HYC was deposited under euxinic conditions. Bitumen II has the potential to reveal information from OM that is degraded and/or overprinted in Bitumen I. Commonly-used methylphenanthrene maturity ratios give conflicting information as to the relative maturity of Bitumens I and II. Bitumen I contains a far higher proportion of methylated phenanthrenes than Bitumen II. As Bitumen II is sequestered within the kerogen/mineral matrix it may have restricted access to the ‘methyl pool’ of organic compounds that can donate methyl groups to aromatic hydrocarbons. Parameters that include both phenanthrene and methylphenanthrenes do not appear suitable to compare the maturity of Bitumens I and II; hence there is no clear evidence that Bitumen II is of

  20. Mechanical Retention and Waterproof Properties of Bacterial Cellulose-Reinforced Thermoplastic Starch Biocomposites Modified with Sodium Hexametaphosphate

    Directory of Open Access Journals (Sweden)

    Da-wei Wang

    2015-06-01

    Full Text Available The waterproof and strength retention properties of bacterial cellulose (BC-reinforced thermoplastic starch (TPS resins were successfully improved by reacting with sodium hexametaphosphate (SHMP. After modification with SHMP, the tensile strength (σf and impact strength (Is values of initial and conditioned BC-reinforced TPS, modified with varying amounts of SHMP(TPS100BC0.02SHMPx, and their blends with poly(lactic acid((TPS100BC0.02SHMPx75PLA25 specimens improved significantly and reached a maximal value as SHMP content approached 10 parts per hundred parts of TPS resin (phr, while their moisture content and elongation at break (ɛf was reduced to a minimal value as SHMP contents approached 10 phr. The  σf, Is and ɛf retention values of a (TPS100BC0.02SHMP1075PLA25 specimen conditioned for 56 days are 52%, 50% and 3 times its initial σf, Is and ɛf values, respectively, which are 32.5 times, 8.9 times and 40% of those of a corresponding conditioned TPS100BC0.02 specimen, respectively. As evidenced by FTIR analyses of TPS100BC0.02SHMPx specimens, hydroxyl groups of TPS100BC0.02 resins were successfully reacted with the phosphate groups of SHMP molecules. New melting endotherms and diffraction peaks of VH-type crystals were found on DSC thermograms and WAXD patterns of TPS or TPS100BC0.02 specimens conditioned for 7 days, while no new melting endotherm or diffraction peak was found for TPS100BC0.02SHMPx and/or (TPS100BC0.02SHMPx75PLA25 specimens conditioned for less than 14 and 28 days, respectively.

  1. Research on waterproofness of expanded perlite thermal insulation mortar%膨胀珍珠岩保温砂浆防水性研究

    Institute of Scientific and Technical Information of China (English)

    徐长伟; 马世方; 陈勇; 曾伟

    2015-01-01

    Hydrophobe modified expangded perlite were prepared by soaking method. The change law of water absorption,compressive strength and dry density of perlite thermal insulation mortar were investigated by the change of mass-volume concentration and the ad-dition of waterproof agent,basing on the modification of expanded perlite. The results show that the water absorption of perlite can be decreased from 290%to 90%when the surface of expanded perlite is modified by silicone water-proofing agent. With the decreasing of mass-volume concentration,the water absorption of perlite insulation mortar increases,the compressive strength and dry density de-crease.The water absorption of perlite insulation mortar can be decreased further by adding water-proofing agent for perlite,supposing the optimal mass-volume concentration is selected.%采用浸泡法制得了憎水剂改性膨胀珍珠岩,以此为基础,通过调整质体比和加入防水剂,研究了膨胀珍珠岩保温砂浆吸水率、强度和干密度的变化规律。试验结果表明:通过有机硅憎水剂对膨胀珍珠岩表面改性,可以把珍珠岩的吸水率从290%降低到90%;随着质体比的减小,砂浆的吸水率增大,强度和干密度减小;在选择最优质体比的基础上,加入珍珠岩专用防水剂,可进一步降低膨胀珍珠岩保温砂浆的吸水率。

  2. 一种新型防水剂的性能研究%Performance of new-kind water-proofing additive

    Institute of Scientific and Technical Information of China (English)

    沈尔卜; 李遵云; 李顺凯; 屠柳青

    2015-01-01

    A new kind water-proofing additive can fundamentally prevent water absorption through the capillary pore and keep chlorine ion out of the concrete structure,so as to prevent reinforcement corrosion.This paper studies the performance of the new-kind water-proofing additive,including the influence on both mortar and concrete;Takes the lead to use the British Standard to evaluate the water absorption rate of concrete;Furthermore,it compares it with the same-kind similar foreign products.The new-kind water-proofing additive can improve 7 d and 28 d compressive strength and the anti-permeability of both mortar and concrete in case of no changing the working performance.%该新型防水剂产品能从根本上解决混凝土中毛细孔吸水问题,防止混凝土结构被氯离子渗透,从而防止钢筋锈蚀。对该防水剂的性能进行测试研究,综合测试其对砂浆和混凝土相关性能的影响;率先采用英国标准评价混凝土吸水率;并比对该新型防水剂与某国外同类成熟产品的相关性能。该防水剂对混凝土和砂浆的7 d和28 d抗压强度均有良好的增益效果,在不改变工作性能的情况下,能有效改善混凝土和砂浆的抗渗能力。

  3. Effects of diluted bitumen exposure on juvenile sockeye salmon: From cells to performance.

    Science.gov (United States)

    Alderman, Sarah L; Lin, Feng; Farrell, Anthony P; Kennedy, Christopher J; Gillis, Todd E

    2017-02-01

    Diluted bitumen (dilbit; the product of oil sands extraction) is transported through freshwater ecosystems critical to Pacific salmon. This is concerning, because crude oil disrupts cardiac development, morphology, and function in embryonic fish, and cardiac impairment in salmon can have major consequences on migratory success and fitness. The sensitivity of early life-stage salmon to dilbit and its specific cardiotoxic effects are unknown. Sockeye salmon parr were exposed to environmentally relevant concentrations of the water-soluble fraction (WSF) of dilbit for 1 wk and 4 wk, followed by an examination of molecular, morphological, and organismal endpoints related to cardiotoxicity. We show that parr are sensitive to WSF of dilbit, with total polycyclic aromatic hydrocarbon (PAH) concentrations of 3.5 µg/L sufficient to induce a liver biomarker of PAH exposure, and total PAH of 16.4 µg/L and 66.7 µg/L inducing PAH biomarkers in the heart. Furthermore, WSF of dilbit induces concentration-dependent cardiac remodeling coincident with performance effects: fish exposed to 66.7 µg/L total PAH have relatively fewer myocytes and more collagen in the compact myocardium and impaired swimming performance at 4 wk, whereas the opposite changes occur in fish exposed to 3.5 µg/L total PAH. The results demonstrate cardiac sensitivity to dilbit exposure that could directly impact sockeye migratory success. Environ Toxicol Chem 2017;36:354-360. © 2016 SETAC.

  4. Thermomechanical properties of bitumen modified with crumb tire rubber and polymeric additives

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, V.; Martinez-Boza, F.J.; Navarro, F.J.; Gallegos, C. [Departamento de Ingenieria Quimica, Universidad de Huelva, Campus del Carmen, 21071 Huelva (Spain); Perez-Lepe, A.; Paez, A. [Centro de Tecnologia, Repsol-YPF, Carretera de Extremadura, N-V, km 18, 28931 Mostoles-Madrid (Spain)

    2010-09-15

    In this paper, the influence of some additives on the rheological and technological properties of crumb rubber modified binders has been studied. The research has been mainly focused on the degree of bitumen modification, measured as the improvement of the mechanical properties, produced by the additives used, and the storage stability of these binders at high temperature. The experimental results obtained reveal that all the polymeric additives used yield an improvement in both rheological and technological properties of the binder. The storage instability of these binders has been associated to sedimentation processes of insoluble CR particles that strongly influence the mechanical properties of the binder. The additives and processing conditions selected in this study do not completely prevent problems associated with the poor stability of CRMBs during storage at high temperature. Nevertheless, the use of polyoctenamer, FT-wax or SBS-containing additives improves CRMB stability. In this sense, similar loss tangent values were found before and after hot storage of these binders. (author)

  5. Hydrothermal bitumen generated from sedimentary organic matter of rift lakes - Lake Chapala, Citala Rift, western Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Zarate del Valle, Pedro F. [Departamento de Quimica, Universidad de Guadalajara - CUCEI, Ap. Postal 4-021, Guadalajara, Jalisco CP 44410 (Mexico); Simoneit, Bernd R.T. [Environmental and Petroleum Geochemistry Group, College of Oceanic and Atmospheric Sciences, Oregon State University, Building 104, Corvallis, OR 97331-5503 (United States)]. E-mail: simoneit@coas.oregonstate.edu

    2005-12-15

    Lake Chapala is in the Citala Rift of western Mexico, which in association with the Tepic-Zacoalco and Colima Rifts, form the well-known neotectonic Jalisco continental triple junction. The rifts are characterized by evidence for both paleo- and active hydrothermal activity. At the south shore of the lake, near the Los Gorgos sublacustrine hydrothermal field, there are two tar emanations that appear as small islands composed of solid, viscous and black bitumen. Aliquots of tar were analyzed by GC-MS and the mixtures are comprised of geologically mature biomarkers and an UCM. PAH and n-alkanes are not detectable. The biomarkers consist mainly of hopanes, gammacerane, tricyclic terpanes, carotane and its cracking products, steranes, and drimanes. The biomarker composition and bulk C isotope composition ({delta} {sup 13}C = -21.4%) indicate an organic matter source from bacteria and algae, typical of lacustrine ecosystems. The overall composition of these tars indicates that they are hydrothermal petroleum formed from lacustrine organic matter in the deeper sediments of Lake Chapala exceeding 40 ka ({sup 14}C) in age and then forced to the lakebed by tectonic activity. The absence of alkanes and the presence of an UCM with mature biomarkers are consistent with rapid hydrothermal oil generation and expulsion at temperatures of 200-250 deg. C. The occurrence of hydrothermal petroleum in continental rift systems is now well known and should be considered in future energy resource exploration in such regions.

  6. Asphalt fume dermal carcinogenicity potential: I. dermal carcinogenicity evaluation of asphalt (bitumen) fume condensates.

    Science.gov (United States)

    Clark, Charles R; Burnett, Donald M; Parker, Craig M; Arp, Earl W; Swanson, Mark S; Minsavage, Gary D; Kriech, Anthony J; Osborn, Linda V; Freeman, James J; Barter, Robert A; Newton, Paul E; Beazley, Shelley L; Stewart, Christopher W

    2011-10-01

    Asphalt (bitumen) fume condensates collected from the headspace above paving and Type III built up roofing asphalt (BURA) tanks were evaluated in two-year dermal carcinogenicity assays in male C3H/HeNCrl mice. A third sample was generated from the BURA using a NIOSH laboratory generation method. Similar to earlier NIOSH studies, the BURA fume condensates were applied dermally in mineral oil twice per week; the paving sample was applied 7 days/week for a total weekly dose of 50 mg/wk in both studies. A single benign papilloma was observed in a group of 80 mice exposed to paving fume condensate at the end of the two-year study and only mild skin irritation was observed. The lab generated BURA fume condensate resulted in statistically significant (P<0.0001) increases in squamous cell carcinomas (35 animals or 55% of animals at risk). The field-matched BURA condensate showed a weaker but significant (P=0.0063) increase (8 carcinomas or 13% of animals) and a longer average latency (90 weeks vs. 76 for the lab fume). Significant irritation was observed in both BURA condensates. It is concluded that the paving fume condensate was not carcinogenic under the test conditions and that the field-matched BURA fume condensate produced a weak tumor response compared to the lab generated sample.

  7. Kinetics of hydrolysis of emulsified salts in Canadian bitumens and inhibition of hydrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Gray, M.R.; Kaur, H. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical and Materials Engineering; Eaton, P.E. [Champion Technologies, Fresno, TX (United States)

    2009-07-01

    The challenge of desalting heavy oils and diluted bitumens was discussed. Chloride is released from the salts when crude oil is heated by steam, resulting in corrosion and fouling of refinery equipment. Several physical and chemical factors are responsible for the rate of reaction of the salts and the rate of release of the chloride. These factors include the concentration of mineral solids, naphthenic acids, and the size and composition of the salt crystals. This study investigated the hydrolysis of chloride salts to better understand the factors causing the release of hydrochloric acid (HCl) in refinery units. A model was used in which heavy crude oil blends were in contact with flowing steam at 100 to 350 degrees C. The study showed that the decomposition of brine salts depended greatly on the components of the crude oil medium. Pure CaCl{sub 2}.2H{sub 2}O was very reactive in actual crudes because of the presence of naphthenic acids. It was concluded that inhibitor formulations based on alkaline earth elements may provide protection for refinery equipment since they successfully reduce the extent and rate of hydrolysis. tabs., figs.

  8. Phenols in hydrothermal petroleums and sediment bitumen from Guaymas Basin, Gulf of California

    Science.gov (United States)

    Simoneit, B. R.; Leif, R. N.; Ishiwatari, R.

    1996-01-01

    The aliphatic, aromatic and polar (NSO) fractions of seabed petroleums and sediment bitumen extracts from the Guaymas Basin hydrothermal system have been analyzed by gas chromatography and gas chromatography-mass spectrometry (free and silylated). The oils were collected from the interiors and exteriors of high temperature hydrothermal vents and represent hydrothermal pyrolyzates that have migrated to the seafloor by hydrothermal fluid circulation. The downcore sediments are representative of both thermally unaltered and thermally altered sediments. The survey has revealed the presence of oxygenated compounds in samples with a high degree of thermal maturity. Phenols are one class of oxygenated compounds found in these samples. A group of methyl-, dimethyl- and trimethyl-isoprenoidyl phenols (C27-C29) is present in all of the seabed NSO fractions, with the methyl- and dimethyl-isoprenoidyl phenols occurring as major components, and a trimethyl-isoprenoidyl phenol as a minor component. A homologous series of n-alkylphenols (C13-C33) has also been found in the seabed petroleums. These phenols are most likely derived from the hydrothermal alteration of sedimentary organic matter. The n-alkylphenols are probably synthesized under hydrothermal conditions, but the isoprenoidyl phenols are probably hydrothermal alteration products of natural product precursors. The suites of phenols do not appear to be useful tracers of high temperature hydrothermal processes.

  9. Preparation of bitumen from charkchemical tar by catalytic oxidation and study of its structure and properties

    Directory of Open Access Journals (Sweden)

    Zhaksyntay Kairbekov

    2012-12-01

    Full Text Available Optimal conditions (temperature, time are determined for processes of oxidation of chark-chemical tar in the presence of FеСl3·6H2O catalyst. In the course of oxidation during increase of quantity of catalyst from 0.4 mass. % to 1.0 mass. % in the composition of initial tar the amount of tar decreased from 42,75 mass.% to 28,56 mass.%, the amount of hydrocarbons from 30,18 mass.% to  28,92 mass.%, and the quantity of asphaltene increased from 15,84 mass.% to   38 mass.%. The  values of physical-mechanical indicators of obtained products in the presence of 0,8 mass.% to 1,0 mass.% catalyst corresponds to the requirements of the standard, hence they may be quantitatively attributed to viscous construction oil bitumen of mark BH 70/30, BN 90/10. Chemical transformation in the composition of obtained products during catalytic oxidation is proved by the results of IR-spectroscopic analysis.

  10. Modeling of a three-phase reactor for bitumen-derived gas oil hydrotreating

    Energy Technology Data Exchange (ETDEWEB)

    Chacon, R.; Canale, A.; Bouza, A. [Departamento de Termodinamica y Fenomenos de Transporte. Universidad Simon Bolivar, Caracas (Venezuela, Bolivarian Republic of); Sanchez, Y. [Departamento de Procesos y Sistemas. Universidad Simon Bolivar (Venezuela, Bolivarian Republic of)

    2012-01-15

    A three-phase reactor model for describing the hydrotreating reactions of bitumen-derived gas oil was developed. The model incorporates the mass-transfer resistance at the gas-liquid and liquid-solid interfaces and a kinetic rate expression based on a Langmuir-Hinshelwood-type model. We derived three correlations for determining the solubility of hydrogen (H{sub 2}), hydrogen sulfide (H{sub 2}S) and ammonia (NH{sub 3}) in hydrocarbon mixtures and the calculation of the catalyst effectiveness factor was included. Experimental data taken from the literature were used to determine the kinetic parameters (stoichiometric coefficients, reaction orders, reaction rate and adsorption constants for hydrodesulfuration (HDS) and hydrodenitrogenation (HDN)) and to validate the model under various operating conditions. Finally, we studied the effect of operating conditions such as pressure, temperature, LHSV, H{sub 2}/feed ratio and the inhibiting effect of H{sub 2}S on HDS and NH{sub 3} on HDN. (author)

  11. Biohydrogen production from forest and agricultural residues for upgrading of bitumen from oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Sarkar, Susanjib; Kumar, Amit [Department of Mechanical Engineering, University of Alberta, Edmonton, Alberta (Canada)

    2010-02-15

    In this study, forest residues (limbs, tops, and branches) and straw (from wheat and barley) are considered for producing biohydrogen in Western Canada for upgrading of bitumen from oil sands. Two types of gasifiers, namely, the Battelle Columbus Laboratory (BCL) gasifier and the Gas Technology Institute (GTI) gasifier are considered for biohydrogen production. Production costs of biohydrogen from forest and agricultural residues from a BCL gasification plant with a capacity of 2000 dry tonnes/day are 1.17 and 1.29/kg of H{sub 2}, respectively. For large-scale biohydrogen plant, GTI gasification is the optimum technology. The delivered-biohydrogen costs are 2.19 and 2.31/kg of H{sub 2} at a plant capacity of 2000 dry tonnes/day from forest and agricultural residues, respectively. Optimum capacity for biohydrogen plant is 3000 dry tonnes/day for both residues in a BCL gasifier. In a GTI gasifier, although the theoretical optimum sizes are higher than 3000 dry tonnes/day for both feedstocks, the cost of production of biohydrogen is flat above a plant size of 3000 dry tonnes/day. Hence, a plant at the size of 3000 dry tonnes/day could be built to minimize risk. Carbon credits of 119 and 124/tonne of CO{sub 2} equivalent are required for biohydrogen from forest and agricultural residues, respectively. (author)

  12. Technology Status of Extracting Bitumen from Oil Sand using Hot alkaline Water%油砂沥青热碱水萃取分离技术现状

    Institute of Scientific and Technical Information of China (English)

    罗茂; 耿安松; 廖泽文

    2011-01-01

    作为非常规石油资源的油砂受到愈来愈多的重视.本文评述了世界油砂资源开发现状和中国油砂资源的利用前景,总结了工业上成熟的油砂沥青热碱水萃取技术分离沥青的流程,论述了热碱水萃取过程中沥青与矿物、粘土和气泡之间相互作用及其对沥青分离效率的影响;全面总结了油砂沥青热碱水萃取过程中温度、pH值、多价阳离子和加工助剂等物理化学条件对沥青与矿物之间相互作用和沥青有效分离的影响.最后指出油砂沥青热碱水萃取分离的最优化实验技术研究是值得进一步深入研究的方向,原子力显微镜的运用和不同萃取技术的综合运用将在改善沥青的萃取分离效果上发挥作用.%As an unconventional fuel resource, tar sand is widely considered to be an important supplement for oil production in the near future due to the skyrocketing price of crude oil and the increasing demand of fuel resources in the world. This paper reviewed oil sand utilization worldwide and the prospect of oil sand exploitation in China.The commercial procedures for hot water based bitumen extraction and subsequent bitumen purification were reviewed. Interactions of bitumen-minerals, bitumen-clay and bitumen-gas bubbles were discussed. The effect of various physical, chemical parameters, such as water temperature, pH value, metal ions in the slurring water and various processing additives, to the interactions of bitumen-mineral and the final recovery of bitumen is systematically summarized. The reviewers believed that finding optimized technique for the hot water based bitumen extraction and separation will be a potential future research focus, and believed that application of Atom Force Microscopy and synthetic utilization of various extraction methods will play an important role in enhancing oil sand bitumen extraction.

  13. 含沥青储层的测井识别及评价%Log Identification and Evaluation for Bitumen-bearing Reservoir

    Institute of Scientific and Technical Information of China (English)

    陈明江; 任兴国

    2012-01-01

    以塔里木盆地某区块泥盆系K组含沥青储层为例探讨含沥青储层的测井评价方法.分析沥青对储层物性及产能的影响,通过2口井测井曲线的对比分析,指出含沥青储层的测井响应特征,并建立含沥青储层的测井识别图版,将含沥青储层与泥质区分开.在定性识别的基础上,利用自然伽马与中子一密度交会法计算储层泥质含量的差值作为储层沥青相对含量,建立有效孔隙度校正模型,提高有效孔隙度计算精度,为准确评价储层提供依据.通过分析储层沥青相对含量及孔隙度在平面上的变化趋势,指出区块内油藏东部受破坏程度比西部强.%The deposition of bitumen in reservoir has serious bad effect on physical properties and productivity of reservoir, which may leads to wrong log interpretation results. This paper takes the bitumen-bearing reservoir in Devonian K group in a zone in Talimu basin as an example to discuss how to evaluate bitumen-bearing reservoir. First of all, the effect of bitumen on the physical properties and productivity of reservoir is analyzed and then the log responses of bitumen-bearing reservoir are identified by comparing logs from two different wells. A cross-plot for identifying bitumen-bearing reservoir is created to distinguish between bitumen and shale. The relative abundance of bitumen in reservoir is derived from the difference between shale content which is calculated with gamma log and from neutron-density cross-plot. A formula for porosity correction is created, which helps to improve the accuracy of porosity and provide foundation for accurate reservoir evaluation. At last, the horizontal variation trend of relative abundance of bitumen in reservoir is studied, which shows that the oil pool is damaged more seriously in the east part of the area than in the west.

  14. Waterproofing Design for Shield Tunnels on High-Speed Railways%高速铁路盾构隧道防水设计

    Institute of Scientific and Technical Information of China (English)

    邓朝辉

    2013-01-01

    根据高速铁路的运营养护特点,在广深港高速铁路狮子洋隧道设计过程中提出了盾构管片接缝防水采用双道密封与分区隔断的防水技术方案.文章针对弹性密封垫防水特点,分析了弹性密封垫及分区防水的关键技术参数,并针对弹性密封垫的正常工作状态,提出了接缝的错台量、张开量及施工期沟槽修补要求.%Considering the characteristics of operation and maintenance of high-speed railways, an option featuring a double seal and partition separation was adopted in the waterproofing design for the segment joint in the Shiziyang Tunnel on the Guangzhou-Shenzhen-Hongkong high-speed railway. The key technical parameters of an elastic seal gasket and partition separation are analyzed in regard to waterproofing, and the requirements for joint staggering, joint opening, and groove repair during construction are addressed.

  15. 基于防腐考虑的TPO防水施工技术%TPO Waterproof Construction Technology Based on the Anti-corrosion

    Institute of Scientific and Technical Information of China (English)

    颜斌; 江涛; 汪绍元; 吴卓; 张爽

    2015-01-01

    在地下防水施工过程中,由于土壤被污染,普通防水材料容易被有机物腐蚀溶解,无法满足直接接触二氯乙烷等环境的防水要求。结合北京某住宅项目工程实例,探索TPO防水材料在特殊环境中的应用,并总结出了其技术特点及应用要点,介绍了TPO防水卷材具体施工工艺流程及关键节点做法,取得良好的经济和环保效益。%During the construction of the underground waterproof engineering, it is found that ordinary building waterproof materials can be corroded easily, the construction can’ t meet the requirements for the direct contact with the dichloromethane( CH2 Cl2 ) because of the soil contamination. Combining with the engineering example of some residential buildings in Beijing, this paper explores the TPO system application in the particular environment, and summarizes the characteristics for the technical and the application of the TPO system. Moreover, it introduces the construction process and key joints structure of TPO system, then good economic and environmental benefits are achieved.

  16. Water Touch-and-Bounce from a Soft Viscoelastic Substrate: Wetting, Dewetting, and Rebound on Bitumen.

    Science.gov (United States)

    Lee, Jae Bong; Dos Santos, Salomé; Antonini, Carlo

    2016-08-16

    Understanding the interaction between liquids and deformable solid surfaces is a fascinating fundamental problem, in which interaction and coupling of capillary and viscoelastic effects, due to solid substrate deformation, give rise to complex wetting mechanisms. Here we investigated as a model case the behavior of water drops on two smooth bitumen substrates with different rheological properties, defined as hard and soft (with complex shear moduli in the order of 10(7) and 10(5) Pa, respectively, at 1 Hz), focusing both on wetting and on dewetting behavior. By means of classical quasi-static contact angle measurements and drop impact tests, we show that the water drop behavior can significantly change from the quasi-static to the dynamic regime on soft viscoelastic surfaces, with the transition being defined by the substrate rheological properties. As a result, we also show that on the hard substrate, where the elastic response is dominant under all investigated conditions, classical quasi-static contact angle measurements provide consistent results that can be used to predict the drop dynamic wetting behavior, such as drop deposition or rebound after impact, as typically observed for nondeformable substrates. Differently, on soft surfaces, the formation of wetting ridges did not allow to define uniquely the substrate intrinsic advancing and receding contact angles. In addition, despite showing a high adhesion to the soft surface in quasi-static measurements, the drop was surprisingly able to rebound and escape from the surface after impact, as it is typically observed for hydrophobic surfaces. These results highlight that measurements of wetting properties for viscoelastic substrates need to be critically used and that wetting behavior of a liquid on viscoelastic surfaces is a function of the characteristic time scales.

  17. Diluted bitumen causes deformities and molecular responses indicative of oxidative stress in Japanese medaka embryos.

    Science.gov (United States)

    Madison, Barry N; Hodson, P V; Langlois, V S

    2015-08-01

    This study characterized the toxicity and physiological effects of unweathered diluted bitumen (Access Western Blend dilbit; AWB) to fish. Embryos of Japanese medaka (Oryzias latipes) were exposed for 17 days to dilutions of physically-dispersed (water accommodated fraction; WAF) and chemically-dispersed (chemically-enhanced WAF; CEWAF) dilbit. AWB dilbit exposure was not lethal to medaka, but resulted in a high prevalence of blue sac disease (BSD), impaired development, and abnormal or un-inflated swim bladders at hatch. Physiological effects were indicated by the relative mRNA levels of key genes associated with, among others, cell cycling and the response to mutations (p53), xenobiotic metabolism (ahr, arnt2), phase I (cyp1a) and II processes associated with oxidative stress (cat, g6pdh, hsp70, gst, gpx, gsr, nfe2, and sod). AWB dilbit treatment increased p53 and cyp1a transcript levels (1.5-fold and >15-fold, respectively), with significant, but less pronounced changes in indicators of oxidative stress and metabolism. The exposure-related changes in embryotoxicity and mRNA synthesis were consistent with metabolism of polycyclic aromatic hydrocarbons (PAHs) to reactive and toxic metabolites. Medaka embryos responded similarly to WAF and CEWAF treatments, but CEWAF was about 100 times more efficient in delivering toxic concentrations of PAHs. The toxicity of chemically-dispersed nujol, a non-toxic mineral oil used as an experimental control, suggested that a portion of the observed effects of AWB could be attributed to excess dispersant in solution. This first study of the physiological effects of dilbit toxicity to fish embryos provides a baseline to compare toxicity between dilbit and conventional crude oils, and the groundwork for the development of molecular biomarkers of the sensitivity and level of risk of native Canadian fish species to dilbit exposure.

  18. 建筑屋面节能与保温防水材料的应用%Applications of the Energy Conservation and Thermal Insulation Waterproof Material of Building Roof

    Institute of Scientific and Technical Information of China (English)

    陈颖杰

    2014-01-01

    The application of energy conservation and thermal insulation waterproof technology in housing construction plays an important role. This article analyzes the concrete applicati-on of roof energy saving materials and waterproof insulation materials, application status and development trend of thermal insulation roofing waterproof materials, discusses problems a-nd solutions of a new energy-saving material of roofing water-proof insulation board in the application.%建筑屋面节能与保温防水技术的应用在房屋建设中发挥着重要的作用。文章先后分析了屋面节能材料与保温防水材料的具体运用,屋面保温节能防水材料的应用现状与发展趋势,就屋面保温防水板这一新型节能材料应用中存在的问题与解决对策进行了探讨。

  19. ZnCl sub 2 catalyzed flash hydropyrolysis of +525 sup 0 C pitch from Cold Lake bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Pandey, R.N.; Ingard, E. (Guelph Chemical Labs., Guelph, ON (Canada)); Ternan, M. (Energy, Mines and Resources Canada, Ottawa, ON (Canada))

    1989-06-01

    Flash hydropyrolysis experiments have been performed on the vacuum bottoms fraction of Cold Lake bitumen, using zinc chloride as a catalyst. Milligram size samples of vacuum bottoms resid were heated rapidly (120 - 400{sup 0}C/s) by passing a large electric current through the reactor tube. The variables studied included temperature, heating rate, catalysts/pitch ratio, vapour phase residence time and pressure. Temperature and catalysts/pitch ratio caused major changes in yields. In contrast pressure had little effect. It was found that high conversions could be obtained at hydrogen pressures which are much lower than those normally used in catalytically hydrocracking residual oils. 16 refs., 10 figs., 2 tabs.

  20. European project RE-ROAD: round robin test on extraction and recovery methods for Reclaimed Asphalts with Polymer modified Bitumens

    OpenAIRE

    MOUILLET, Virginie; PIERARD, Nathalie; Mollenhauer, Konrad; GINOUX, Marc Stéphane; Gabet, Thomas; Farcas, Fabienne; MIRSKI, Krzysztof; KEMPERLE, Ema

    2012-01-01

    The recycling of Reclaimed Asphalt (RA) in new hot-mix asphalt (HMA) is a common practice throughout Europe. However, Reclaimed Asphalts (RA) are complex materials and the use of significant proportions of RA involves a more accurate control of their characteristics. This is an essential step for asphalt mix design and a key factor to obtain good performances. At this time there is clearly a lack of knowledge and adequate test methods to analyse RA with Polymer modified Bitumens (PmBs). The p...

  1. Irritative effects of fumes and aerosols of bitumen on the airways: results of a cross-shift study

    Energy Technology Data Exchange (ETDEWEB)

    Raulf-Heimsoth, Monika; Pesch, Beate; Kappler, Martin; Marczynski, Boleslaw; Rihs, Hans Peter; Merget, Rolf; Bruening, Thomas [Institut der Ruhr-Universitaet Bochum, Berufsgenossenschaftliches Forschungsinstitut fuer Arbeitsmedizin (BGFA), Bochum (Germany); Schott, Klaus [Berufsgenossenschaft der Bauwirtschaft (BG BAU), Munich (Germany); Preuss, Ralf; Angerer, Juergen [Universitaet Erlangen, Institut und Poliklinik fuer Arbeits-, Sozial- und Umweltmedizin (IPASUM), Erlangen (Germany); Hahn, Jens Uwe [Berufsgenossenschaftliches Institut fuer Arbeitsschutz (BGIA), Sankt Augustin (Germany)

    2007-01-15

    Possible health hazards of fumes and aerosols of bitumen are in discussion, and data on their adverse effects on human airways under current exposure conditions are limited. To assess the irritative effects of exposure to fumes and aerosols of bitumen on the airways, a cross-sectional cross-shift study was conducted including external and internal exposure measurements, spirometry and especially non-invasive methods like nasal lavage collection and induction of sputum in order to identify and evaluate more precisely inflammatory process in the upper and lower airways. The cross-shift study comprised 74 mastic asphalt workers who were exposed to fumes and aerosols of bitumen and 49 construction workers without this exposure as reference group. Questionnaire, spirometry, ambient monitoring and urinary analysis were performed. Humoral and cellular parameters were measured in nasal lavage fluid (NALF) and induced sputum. For data analysis, a mixed linear model was performed on the different outcomes with exposure group, time of measurement (pre-, post-shift), current smoking, German nationality and age as fixed factors and subjects as random factor. Based on personal exposure measurements during shift, mastic asphalt workers were classified into a low ({<=}10 mg/m{sup 3}; n = 46) and a high (>10 mg/m{sup 3}; n = 28) exposure group. High exposure was accompanied by significant higher urinary post-shift concentrations of 1-hydroxypyrene and the sum of hydroxyphenanthrenes. Acute respiratory symptoms were reported more frequently in the high exposure group after shift. Significant cross-shift declines in lung function parameters (forced expiratory volume in 1 s [FEV{sub 1} (% predicted)] and forced vital capacity [FVC (% predicted)]) were measured in mastic asphalt workers. Pre-shift FEV{sub 1} (% predicted) and FVC (% predicted) were higher in the low exposure group. In pre- and post-shift NALF samples, interleukin (IL)-1{beta}-, IL-8- and total protein concentrations

  2. Irritative effects of fumes and aerosols of bitumen on the airways: results of a cross-shift study.

    Science.gov (United States)

    Raulf-Heimsoth, Monika; Pesch, Beate; Schott, Klaus; Kappler, Martin; Preuss, Ralf; Marczynski, Boleslaw; Angerer, Jürgen; Rihs, Hans Peter; Hahn, Jens Uwe; Merget, Rolf; Brüning, Thomas

    2007-01-01

    Possible health hazards of fumes and aerosols of bitumen are in discussion, and data on their adverse effects on human airways under current exposure conditions are limited. To assess the irritative effects of exposure to fumes and aerosols of bitumen on the airways, a cross-sectional cross-shift study was conducted including external and internal exposure measurements, spirometry and especially non-invasive methods like nasal lavage collection and induction of sputum in order to identify and evaluate more precisely inflammatory process in the upper and lower airways. The cross-shift study comprised 74 mastic asphalt workers who were exposed to fumes and aerosols of bitumen and 49 construction workers without this exposure as reference group. Questionnaire, spirometry, ambient monitoring and urinary analysis were performed. Humoral and cellular parameters were measured in nasal lavage fluid (NALF) and induced sputum. For data analysis, a mixed linear model was performed on the different outcomes with exposure group, time of measurement (pre-, post-shift), current smoking, German nationality and age as fixed factors and subjects as random factor. Based on personal exposure measurements during shift, mastic asphalt workers were classified into a low (10 mg/m(3); n = 28) exposure group. High exposure was accompanied by significant higher urinary post-shift concentrations of 1-hydroxypyrene and the sum of hydroxyphenanthrenes. Acute respiratory symptoms were reported more frequently in the high exposure group after shift. Significant cross-shift declines in lung function parameters (forced expiratory volume in 1 s [FEV(1) (% predicted)] and forced vital capacity [FVC (% predicted)]) were measured in mastic asphalt workers. Pre-shift FEV(1) (% predicted) and FVC (% predicted) were higher in the low exposure group. In pre- and post-shift NALF samples, interleukin (IL)-1beta-, IL-8- and total protein concentrations were lower in the low exposure group compared to the

  3. The control of the surface evenness in the Urban road bitumen pavement%城市道路沥青路面平整度控制浅析

    Institute of Scientific and Technical Information of China (English)

    覃志学

    2012-01-01

      根据城市沥青路面的施工经验,分析了影响城市道路沥青路面平整度的各种因素,提出了城市道路各结构层平整度的质量控制要点。%  According to the construction experience of the urban bitumen pavement,analyze the various factors that affect the surface evenness of the bitumen pavement on urban road,and propose the quality control points of the evenness on structural layer for the urban road .

  4. Waterproof Fire Stations

    DEFF Research Database (Denmark)

    Bundgaard, Peer; Stjernfelt, Frederik; Østergaard, Svend

    2006-01-01

    The paper develops a characterization of nominal compounds. The analysis is carried out on frame-schematic and construction-grammatical grounds.  It rests on assumptions about cognitive processing long since known within cognitive linguistics, but it criticizes certain linguistic applications of ...

  5. Effect of Rejuvenator on Properties of Aged Bitumen of Different Aging Degree%再生剂对不同老化程度沥青再生性能的影响

    Institute of Scientific and Technical Information of China (English)

    况栋梁; 余剑英; 蔡正文; 宋献东

    2011-01-01

    采用再生剂对不同老化程度的沥青进行再生,研究了再生剂对不同老化程度沥青再生性能的影响,并探讨了再生沥青的化学组成与物理性能之间的关系.结果表明,对于轻度老化沥青和中度老化沥青,当新沥青的用量分别为40%和60%时,掺入10%~15%的再生剂即可使再生沥青的物理性能满足新沥青的规范要求,而重度老化沥青由于其沥青质含量较高,只有当新沥青用量在60%以上、再生剂用量为25%时,其物理性能才能符合新沥青的规范要求.化学组成分析表明再生沥青的沥青质含量和芳香分含量是影响再生沥青性能的关键指标,当再生沥青的沥青质含量和芳香分含量与新沥青的相近时,其物理性能可以得到很好恢复.%Effect of rejuvenator on the reclaimed properties of aged bitumen of different aging degree is investigated and relationship between physical properties and chemical component of recycled bitumen is explored. The results indicate that for slightly and medially aged bitumen, when content of fresh bitumen is 40% to 60%, the physical properties of recycled bitumen can be restored to meet the fresh bitumen standards by adding 10% to 15% rejuvenator. However, for severely aged bitumen, only when content of fresh bitumen exceed 60% and rejuvenator content is up to 25%, the physical properties of recycled bitumen can be restored to meet the fresh bitumen standards. The contents ofasphaltenes and aromatics have strong influence on the physical properties of recycled bitumen. The physical properties of recycled bitumen can be well restored when it has almoslly closed the fresh bitumen on content of asphaltenes and aromatics.

  6. Modification of an Amposta origin bitumen by using tlie Friedel and Crafts reaction with toluyiene-2,4-diisocyanate

    Directory of Open Access Journals (Sweden)

    Blanco, M.

    1988-03-01

    Full Text Available In this works, we have modified a bitumen from Amposta by using the Friedel and Crafts reaction with toluylene-2,4-diisocyanate in presence of aluminium trichloride, presenting as well as the characteristics of the original bitumen as the ones of the modification products. We have made technological test, aging of thin film, rheological test, thermical susceptibility and components analyses.

    En el presente trabajo se ha modificado un betún procedente de Amposta por reacción de Friedei y Crafts con 4-metil-1,3-bencenodiisocianato, en presencia de tricloruro de aluminio. Se han determinado las características del betún original así como las de los productos obtenidos en la modificación. Se han llevado a cabo ensayos de tipo tecnológico, envejecimiento en película delgada, propiedades reológicas, susceptibilidad térmica y análisis de componentes.

  7. Geochemical features and genesis of the natural gas and bitumen in paleo-oil reservoirs of Nanpanjiang Basin, China

    Institute of Scientific and Technical Information of China (English)

    ZHAO MengJun; ZHANG ShuiChang; ZHAO Lin; DA Jiang

    2007-01-01

    Bitumen from the Nanpanjiang Basin occurs mainly in the Middle Devonian and Upper Permian reef limestone paleo-oil reservoirs and reserves primarily in holes and fractures and secondarily in minor matrix pores and bio-cavities. N2 is the main component of the natural gas and is often associated with pyrobitumen in paleo-oil reservoirs. The present study shows that the bitumen in paleo-oil reservoirs was sourced from the Middle Devonian argillaceous source rock and belongs to pyrobitumen by crude oil cracking under high temperature and pressure. But the natural gas with high content of N2 is neither an oil-cracked gas nor a coal-formed gas generated from the Upper Permian Longtan Formation source rock, instead it is a kerogen-cracked gas generated at the late stage from the Middle Devonian argillaceous source rock. The crude oil in paleo-oil reservoirs completely cracked into pyrobitumen and methane gas by the agency of hugely thick Triassic deposits. After that, the abnormal high pressure of methane gas reservoirs was completely destroyed due to the erosion of 2000-4500-m-thick Triassic strata. But the kerogen-cracked gas with normal pressure was preserved under the relatively sealed condition and became the main body of the gas shows.

  8. Geochemical features and genesis of the natural gas and bitumen in paleo-oil reservoirs of Nanpanjiang Basin, China

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Bitumen from the Nanpanjiang Basin occurs mainly in the Middle Devonian and Upper Permian reef limestone paleo-oil reservoirs and reserves primarily in holes and fractures and secondarily in minor matrix pores and bio-cavities. N2 is the main component of the natural gas and is often associated with pyrobitumen in paleo-oil reservoirs. The present study shows that the bitumen in paleo-oil reservoirs was sourced from the Middle Devonian argillaceous source rock and belongs to pyrobitumen by crude oil cracking under high temperature and pressure. But the natural gas with high content of N2 is neither an oil-cracked gas nor a coal-formed gas generated from the Upper Permian Longtan Formation source rock, instead it is a kerogen-cracked gas generated at the late stage from the Middle Devonian argilla- ceous source rock. The crude oil in paleo-oil reservoirs completely cracked into pyrobitumen and methane gas by the agency of hugely thick Triassic deposits. After that, the abnormal high pressure of methane gas reservoirs was completely destroyed due to the erosion of 2000--4500-m-thick Triassic strata. But the kerogen-cracked gas with normal pressure was preserved under the relatively sealed condition and became the main body of the gas shows.

  9. 细石混凝土刚性防水屋面渗漏及防治%FINE AGGREGATE CONCRETE RIGID WATERPROOF ROOF LEAKAGE AND PREVENTION

    Institute of Scientific and Technical Information of China (English)

    谭皓; 张电吉; 卢海林

    2011-01-01

    细石混凝土刚性防水屋面在我国一些经济欠发达地区的居民住宅、中小学校以及广房建筑等,还在大量应用.文中通过分析细石混凝土刚性防水屋面产生渗漏的原因,提出其渗漏的防治措施.%Rigid waterproofing fine aggregate concrete is still widely used in some of our underdeveloped residential areas, schools and widespread housing constructions. By analyzing the causes of the leakage, we come along with the control measures for the leakage.

  10. Polymeric synthetic geo membranes in reservoirs waterproofing in the Kingdom of Morocco; Las geomembranas sinteticas polimericas en la impermeabilizacion de balsas en el Reino de Marruecos

    Energy Technology Data Exchange (ETDEWEB)

    Blanco Fernandez, M.

    2015-07-01

    This essay aims to address some of the aspects related to polymeric synthetic geo membranes that could be used in reservoirs of water located in the Kingdom of Morocco. In this regard, it offers a description of the two basic components geo membranes consist of, that is, resins and additives. It also gives an overview of the key pieces of legislation affecting such an issue. Furthermore, it stresses the paramount importance of implementing monitoring procedures in order to assess the condition of geo membranes over time and, if necessary, to proceed to provide for new waterproofing. Lastly, the characteristics of the process monitoring aforementioned are detailed in terms of tensile strength, elongation, tear resistance, dynamic impact, puncture resistance, low-temperature folding. Shore hardness, stress cracking, oxidation induction times, joint strength shear and peeling test, content and dispersion of carbon black and reflection-optical and scanning-electron microscopy. (Author)

  11. Synthesis of new water expandable waterproofing sealant and its application%新型水膨胀防水密封胶的合成与应用

    Institute of Scientific and Technical Information of China (English)

    徐文君

    2009-01-01

    重点阐述了一种新型水膨胀防水密封胶的合成,包括丙烯酸类专用吸水树脂的组成配方和合成过程,以及以氯丁胶为主的基体胶料的选择;扼要介绍了该水膨胀防水密封胶的工程应用.%The article focuses on synthesis of a new water ex-pandable waterproofing sealant, including formulation of acrylic specific hydroscopic resin and its synthesis process and selection of neoprene -based rubbers. It also briefs the application of the sealant.

  12. Factors Influencing the Quality of the Roof Waterproof Construction and Exploration%影响建筑屋面防水质量的因素和探索

    Institute of Scientific and Technical Information of China (English)

    唐勇

    2014-01-01

    屋面渗漏严重影响了屋主的起居生活。因为屋面结构复杂,如果在抢修过程要求速度将导致工程积压繁多甚至可能修缮不当。对于建筑屋面的防水质量从两方面分析:一是影响建筑屋面防水质量的因素;二是如何应对的措施。%The roof leakage seriously affected homeowners living life. Because the roof structure is complex, if the repair process requires speed wil lead to many engineering backlog may even repair improper. Water quality for the building roof is analyzed from two aspects: one is the influence factors of building roofing waterproof quality;the two is measures how to deal with.

  13. 575 nm laser oscillation in Dy3+-doped waterproof fluoro-aluminate glass fiber pumped by violet GaN laser diodes

    Science.gov (United States)

    Fujimoto, Yasushi; Ishii, Osamu; Yamazaki, Masaaki

    2011-02-01

    We successfully drew a low-loss Dy-doped optical fiber (0.3dB/m at 532nm) of a waterproof fluoro-aluminate glass system and demonstrated yellow laser oscillation in the Dy3+-doped fluoride fiber pumped by a 398.8-nm GaN laser diode. The maximum output power was 10.3 mW and the slope efficiency was 17.1% at 575 nm. Since the fluoro-aluminate- glass system has a remarkable water resistance advantage compared to ZBLAN glass, Dy-doped fluoro-aluminate glass fiber is expected to contribute to making a solid-state yellow fiber laser with high chemical durability without a frequency doubling technique.

  14. the Research Progress of Water-Proofing Gypsum Block%石膏砌块耐水性研究进展

    Institute of Scientific and Technical Information of China (English)

    黄丹; 杨林; 曹建新

    2009-01-01

    Owing to gypsum block's disadvantage of poor water-proofing, the paper summarized some methods which can improve gypsum block's disadvantage by looking up lots of literatures. The results showed that there were mainly three methods: one was adding the activated pozzolana to gypsum; the other was adding organic water repellents; thirdly, the two materials (the activated pozzolana and organic water repellents) were added to gypsum at some rate. The first method was the most economical. If the gypsum block could be water-proofing only by adding the activated pozzolana, the prospect would be broad.%石膏砌块具有耐水性差的缺点,从而限制其使用领域.基于这一问题,文章总结了目前耐水石膏砌块处理技术的研究进展,其中采用在建筑石膏中掺入有机防水剂与活性火山灰质等材料制备耐水石膏砌块的方法具有防水效果好、强度高的优点.但是成本较单独掺活性火山质材料高,并且还存在石膏掺量低、制备工艺复杂等不足,若能在建筑石膏中只掺入活性火山灰质等材料,同时提高石膏掺量制备耐水石膏砌块,该制备技术的应用前景将更为广阔.

  15. 纳米材料拒水织物加工技术及应用%Technology and Application of Nanomaterials in Waterproof Fabric Processing

    Institute of Scientific and Technical Information of China (English)

    党美娟; 林娜; 王飞龙

    2011-01-01

    Application of nanomaterials in waterproof fabric production was summarized. Principle of applying nanomaterials in surface waterproof fabric were researched, characterization of nanomaterial was introduced as well as fabric water repellency test index, method of doing fabric water repellency for nanomaterials, applications at home and a-broad. It is considered that advantages of nano water repellence materials in both materials manufacture process and function application are obviously. It is pointed out that research of nano water repellence materials should be strengthened, agglomeration phenomenon of nanomaterials in applications and its effect on human body should be paid attention to specially.%概述纳米材料在拒水织物生产中的应用情况.探究了纳米材料应用于表面拒水性织物的机理,介绍了纳米材料的表征方法、织物拒水性测试指标及纳米材料进行织物拒水整理加工的方法和国内外应用状况.认为:不论是从材料的加工过程,还是功能性应用方面,纳米拒水材料都具有明显优势,并指出应加强纳米拒水材料的研究,着重关注纳米材料在应用中的团聚现象及时人体的影响.

  16. The synthesis and application of fluorinated-containing acrylate waterproof agent%含氟丙烯酸酯防水剂的合成及应用

    Institute of Scientific and Technical Information of China (English)

    刘梦毅; 贺江平; 马科

    2014-01-01

    以甲基丙烯酸甲酯(MMA)、丙烯酸丁酯(BA)为单体,脂肪醇聚氧乙烯醚(AEO-9)和十二烷基硫酸钠(SDS)为复合乳化剂,过硫酸铵(APS)为引发剂,采用乳液聚合方法制备含氟防水整理剂乳液。结果表明:当m(BA)︰m(MMA)=3︰2,乳化剂用量为6%,引发剂用量为0.6%(均为对单体总质量),制得的聚合物乳液外观透亮、细腻、稳定性好。经该防水整理剂整理后的棉织物对水的接触角可达140°。%A fluorinated-containing waterproof agent emulsion was synthesized by emulsion polymerization using methyl methacrylate (MMA) and butyl acrylate (BA) as monomer, fatty alcohol-polyoxyethylene ether(AEO-9) and sodium dodecyl sulfate(SDS) as compound emulsifier, and ammonium persulfate (APS) as initiator. The results showed that with m(BA)︰m(MMA) of 3︰2, 0.6%initiator, and 0.6%emulsifier(compared to total mass of monomers), the prepared copolymer emulsion was transparent, fine and stable. The water contact angle of fabric treated by this prepared waterproof agent could reach up to 140°.

  17. Freeze-Thaw Performance and Moisture-Induced Damage Resistance of Base Course Stabilized with Slow Setting Bitumen Emulsion-Portland Cement Additives

    Directory of Open Access Journals (Sweden)

    Mojtaba Shojaei Baghini

    2015-01-01

    Full Text Available Freeze-thaw (FT cycles and moisture susceptibility are important factors influencing the geotechnical characteristics of soil-aggregates. Given the lack of published information on the behavior of cement-bitumen emulsion-treated base (CBETB under environmental conditions, especially freezing and thawing, this study investigated the effects of these additives on the CBETB performance. The primary goal was to evaluate the resistance of CBETB to moisture damage by performing FT, Marshall conditioning, and AASHTO T-283 tests and to evaluate the long-term stripping susceptibility of CBETB while also predicting the liquid antistripping additives to assess the mixture’s durability and workability. Specimens were stabilized with Portland cement (0%–6%, bitumen emulsion (0%–5%, and Portland cement-bitumen emulsion mixtures and cured for 7 days, and their short- and long-term performances were studied. Evaluation results of both the Marshall stability ratio and the tensile strength ratio show that the additions of additives increase the resistance of the mixtures to moisture damage. Results of durability tests performed for determining the resistance of compacted specimens to repeated FT cycles indicate that the specimen with the 4% cement-3% bitumen emulsion mixture significantly improves water absorption, volume changes, and weight losses. This indicates the effectiveness of this additive as a road base stabilizer with excellent engineering properties for cold regions.

  18. Chemical modification of a bitumen and its non-fuel uses. [Reactions of tar sand asphaltenes in synthesis of non-fuel products

    Energy Technology Data Exchange (ETDEWEB)

    Moschopedis, S.E.; Speight, J.G.

    1974-01-01

    Simple reactions are described whereby tar sand bitumen can be converted to a whole range of materials. Examples are given to illustrate the non-fuel uses of the products. The following reactions of Athabasca asphaltenes are considered: oxidation, halogenation, sulfonation and sulfomethylation, phosphorylation, hydrogenation, reactions with S and O, reactions with metal salts, and miscellaneous chemical conversions. (JGB)

  19. Organic Solvent Extraction of Bitumen from Canada Oil Sands%有机溶剂萃取加拿大油砂应用研究

    Institute of Scientific and Technical Information of China (English)

    冯杰; 李鑫钢; 许宁津; 隋红

    2015-01-01

    Organic solvent extraction used for extraction of bitumen from oil sand was introduced,and the process has two stages:bitumen phase dissolution and separation of bitumen,solvent and sands.In this study,toluene,heptane,acetone,ethyl acetate,toluene/heptane,acetone/heptane and ethyl acetate/heptane were used as the solvent to investigate the total recovery of bitumen and the extraction efficiency of four defined fractions (saturates,aromatics,resins and asphaltenes) in bitumen.The result of the surface tension of bitumen/solvent showed that the surface tension varied only based on the type of solvent used and remained relatively unchanged during the extraction process of bitumen from oil sands.Mixture solvent systems were good for oil sand separation due to the extraction efficiency and the low surface tension.%介绍了溶剂作为萃取剂分离油砂的技术,溶剂萃取油砂过程包含两个阶段:沥青相向溶剂的溶解过程和沥青、溶剂与砂粒的分离过程.考察了单一溶剂甲苯、丙酮、乙酸乙酯和甲苯/正庚烷、丙酮/正庚烷、乙酸乙酯/正庚烷组成的复合溶剂体系在相同条件下对油砂沥青的萃取率,在此基础上进一步对比了不同溶剂体系对沥青四组分饱和分、芳香分、胶质和沥青质的萃取效果,同时考察了不同浓度的沥青-溶剂溶液的表面张力,结果表明在油砂萃取过程中沥青-溶剂体系的表面张力主要取决于所选溶剂的种类,而沥青的浓度对溶液表面张力的影响不大.混合溶剂体系甲苯/正庚烷、丙酮/正庚烷、乙酸乙酯/正庚烷相比纯溶剂萃取率较高,其沥青溶液表面张力较低,是良好的分离油砂溶剂体系.

  20. Solvent extraction of bitumen from oil sands amended with ionic liquid%离子液体促进溶剂萃取油砂沥青

    Institute of Scientific and Technical Information of China (English)

    张坚强; 李鑫钢; 隋红

    2014-01-01

    Both traditional water extraction and solvent extraction to extract bitumen from oil sands have their drawbacks,such as sand/clay entraining into bitumen and bitumen remaining in residual sands. To resolve these problems,an ionic liquid ([Emim]BF4) was used to enhance bitumen recovery from Canadian oil sands by methyl acetate/n-heptane. FTIR and SEM were used to qualitatively analyze the cleanliness of bitumen and residual sand. Quantitative results of fine sand/clay in bitumen and organic matter remaining in residual sand were also obtained by coupling SEM with Elementar and ICP. The optimal volume ratio of methyl acetate to n-heptane was 2∶3. Meanwhile [Emim]BF4 increased bitumen recovery ratio to 94.20%, 7.92% higher than composite solvent extraction without [Emim]BF4. The results obtained from FTIR , SEM , Elementar and ICP demonstrated that [Emim]BF4 could enhance bitumen separation efficiently. Negligible sand/clay was entrained in extracted bitumen,and no IL or bitumen was found in the treated sand.%传统水洗法和溶剂萃取法萃取油砂沥青时,存在沥青中含有沙土和残沙中含有油等缺点。为解决上述缺点,本文采用不同比例的乙酸甲酯/正庚烷复合溶剂萃取油砂沥青,研究了离子液体(1-丁基-3-甲基咪唑四氟硼酸盐,[Emim]BF4)对该溶剂萃取体系的萃取率和分离洁净程度的影响。采用红外光谱仪和扫描电镜对萃取后的残沙和沥青的洁净程度进行了定性分析,并结合元素分析仪和电感耦合等离子体发射光谱仪获得萃取后残沙和沥青的洁净程度的定量结果。实验结果表明:当复合溶剂体积比为2∶3时,[Emim]BF4促使沥青回收率达到最大值94.20%,比单纯复合溶剂萃取体系的最大萃取率高7.92%;通过上述测试方法的定性和定量分析,证明了[Emim]BF4能有效解决沥青夹带沙土和残沙中含油的问题。

  1. Study on the Effect of Fly Ash to Modified Bitumen%粉煤灰含量对SBS改性沥青性能影响研究

    Institute of Scientific and Technical Information of China (English)

    冯松锴; 杨遂中; 杨广军

    2011-01-01

    主要研究了粉煤灰含量对石油沥青性能的影响,探讨了不同质量比的石油沥青/粉煤灰对于SBS改性沥青性能的影响,同时研究了不同用量的芳烃油、SBS对改性石油沥青性能的影响.研究结果表明,石油沥青和粉煤灰的比例在一定范围内,使改性沥青的延度等指标完全满足SBSI-C标准.当石油沥青与煤沥青的质量比为60/22时,其综合性价比达到最佳值,为降低改性沥青的生产成本进行了有益的尝试.研究还发现,对于本改性体系,芳烃油和SBS的用量对于沥青的改性有较大的影响.%Modified bitumen had been mainly studied in this thesis. The effect of the different quality ratio of petroleum asphalt/fly ash to modified bitumen had been discussed. The effects of different aromatic oil and SBS to the properties of modified bitumen were also studied. The results showed that the ductility of modified bitumen can satisfy standard of SBS I-C by the addition of the ratio of asphalt and coal tar pitch in a certain range. When the different quality ratio of Petroleum asphalt and fly ash was 60/20, the comprehensive cost achieved the best value. The result also revealed that there is an obvious influence of the modified bitumen as a result of content of aromatic oil and SBS in this modified system.

  2. SBS改性沥青路用性能试验研究%Experimental Research on Pavement Performance of SBS Polymer Modified Bitumen

    Institute of Scientific and Technical Information of China (English)

    丁永灿; 覃德伟

    2012-01-01

    在沥青混凝土路面建设过程中,由于基质沥青性能受原油属性制约,其技术性能不能满足交通增长的需要.寻找优异的改性材料和改性方法,是提高沥青路面综合性能的有效途径.本文通过对各种聚合物改性沥青性能的比较,从中选择出改性效果较优的SBS,并分析其用量对沥青的温度敏感性、高温特性、低温抗裂性、弹性及耐久性的影响,提出SBS的最佳用量建议值.%In the construction of bitumen concrete pavement, the bitumen performance is restricted by the attribute of crude petroleum and is unable to technically fulfill the needs of transportation development. To develop the adaptive and excellent modified materials and modified methods is the effective approach to improve the bitumen pavement. In the paper the SBS with better modification has been selected by comparing the performances of diverse polymer modified bitumen. The influence of SBS usage volume upon the temperature sensitivity, high-temperature characteristics, iow-temperatu.ee crack resistance, elasticity and durability of bitumen is also analyzed and the optimum SBS usage volume recommended.

  3. Investigation on the Combined Effect of Fibers and Cement on the Mechanical Performance of Foamed Bitumen Mixtures Containing 100% RAP

    Directory of Open Access Journals (Sweden)

    Ehsan Ashouri Taziani

    2016-01-01

    Full Text Available Concerns about virgin aggregate sources and increasing demands for construction materials of transport infrastructures as the key parameters in development are the most important reasons, which convinced pavement engineers to develop new methods in order to use higher amount of recycled asphalt pavement (RAP. One of the common methodologies to produce mixtures containing RAP is foamed bitumen mix (FBM. In addition, according to previous research studies, incorporating various types of fibers and hydraulic binders such as cement could significantly improve the mechanical performance of mixtures. The present research study evaluated FBM containing 100% RAP and two types of fiber and Portland cement. Dynamic modulus, unconfined dynamic creep compression, and indirect tensile strength were evaluated in the laboratory at optimum moisture content, which was investigated in this research. Both types of fiber and cement proved to enhance specific properties of mixtures.

  4. Experimental investigation of changes in methane adsorption of bitumen-free Woodford Shale with thermal maturation induced by hydrous pyrolysis

    Science.gov (United States)

    Hu, Haiyan; Zhang, Tongwei; Wiggins-Camacho, Jaclyn D.; Ellis, Geoffrey S.; Lewan, Michael D.; Zhang, Xiayong

    2014-01-01

    This study quantifies the effects of organic-matter (OM) thermal maturity on methane (CH4) sorption, on the basis of five samples that were artificially matured through hydrous pyrolysis achieved by heating samples of immature Woodford Shale under five different time–temperature conditions. CH4-sorption isotherms at 35 °C, 50 °C, and 65 °C, and pressures up to 14 MPa on dry, solvent-extracted samples of the artificially matured Woodford Shale were measured. The results showed that CH4-sorption capacity, normalized to TOC, varied with thermal maturity, following the trend: maximum oil (367 °C) > oil cracking (400 °C) > maximum bitumen/early oil (333 °C) > early bitumen (300 °C) > immature stage (130 °C). The Langmuir constants for the samples at maximum-oil and oil-cracking stages are larger than the values for the bitumen-forming stages. The total pore volume, determined by N2 physisorption at 77 K, increases with increased maturation: mesopores, 2–50 nm in width, were created during the thermal conversion of organic-matter and a dramatic increase in porosity appeared when maximum-bitumen and maximum-oil generation stages were reached. A linear relationship between thermal maturity and Brunauer–Emmett–Teller (BET) surface area suggests that the observed increase in CH4-sorption capacity may be the result of mesopores produced during OM conversion. No obvious difference is observed in pore-size distribution and pore volume for samples with pores 2 physisorption at 273 K. The isosteric heat of adsorption and the standard entropy for artificially matured samples ranged from 17.9 kJ mol−1 to 21.9 kJ mol−1 and from −85.4 J mol−1 K−1 to −101.8 J mol−1 K−1, respectively. These values are similar to the values of immature Woodford kerogen concentrate previously observed, but are larger than naturally matured organic-rich shales. High-temperature hydrous pyrolysis might have induced Lewis acid sites on both organic and mineral surfaces

  5. 大连北站雨棚屋面多层中空阳光板防水施工技术%The Waterproofing Construction Technology of Awning Roof Multilayer Hollow Slab in the North Station of Dalian

    Institute of Scientific and Technical Information of China (English)

    方源

    2013-01-01

    In recent years, the awning roof system of railway station increasingly perfect, highlighting the characteristics of architectural diversity and aesthetic. But people increasingly pursuing the aesthetic architectural, while the waterproof roof lighting system issue has become a key point of quality control. Therefore, the waterproofing technology of multi-layer hol ow slab can effectively ensure the roofing performance.%近年来,铁路客站雨棚屋面系统日益完美,突出了建筑的多样性、美学性等特点。但在日益追求建筑美感的同时,屋面采光系统的防水问题成为了质量控制的关键点。因此,多层中空阳光板防水施工技术可有效地保证屋面防水性能。

  6. Research Progress and Application of Thermo-sensitive Waterproof and Moisture Permeable Polyurethane%温敏型防水透湿聚氨酯的研究进展及应用

    Institute of Scientific and Technical Information of China (English)

    赵宁; 李冰; 律微波; 李金辉; 彭丹

    2014-01-01

    温敏型防水透湿聚氨酯为当前智能高分子材料研究的热点之一。介绍了该类聚氨酯的结构和温敏特性,介绍了温敏型防水透湿聚氨酯的研究进展,并对其在纺织、医疗、食品包装等领域的应用前景进行了概述。%Thermo-sensitive waterproof and moisture permeable polyurethane is one of the hotspots in current research on intelligent polymer materials. In this paper, the structure and thermo-sensitive characteristics of this polyurethane were summarized, research progress of thermo-sensitive waterproof and moisture permeable polyurethane was introduced, and its application prospect in textile, medical, food packaging and other fields was described.

  7. Waterproofing methods of comprehensive underground pipe ditch pipeline engineering in Zhenhua street%振华街地下综合管沟管道工程防水做法

    Institute of Scientific and Technical Information of China (English)

    史拉明

    2015-01-01

    通过研究某地下综合沟的工程现状,对地下综合管沟防水工程的技术复杂性和难度性进行了分析,阐述了施工缝部分、施工工艺、要求等具体的防水技术,指出完工后达到了良好的使用效果。%Through analyzing comprehensive underground pipe ditch engineering status,the paper analyzes technological complexity and difficulty of comprehensive underground pipe ditch waterproofing engineering,describes its construction joint,construction technology and other specific waterproofing techniques,and finally points out its good utilization effect after completion.

  8. On quality control of single-floor SBS roof waterproof craft with heat fusion method%热熔法单层 SBS 屋面防水工艺工程质量控制

    Institute of Scientific and Technical Information of China (English)

    赵基平

    2015-01-01

    结合工作经验,介绍了热熔法单层SBS屋面防水工艺原材料的控制要点,主要阐述了单层SBS屋面防水施工的质量控制措施,并对施工时适宜的气候条件进行了研究,以避免屋面防水质量问题的发生。%Combining with the work experience,the paper introduces the controlling measures for the single-floor SBS roof waterproof craft with heat fusion method,mainly illustrates the quality control measures for the construction,and researches the suitable climate conditions of the con-struction,so as to avoid the defects in the roof waterproof quality.

  9. Biological monitoring as a useful tool for the detection of a coal-tar contamination in bitumen-exposed workers

    Energy Technology Data Exchange (ETDEWEB)

    Raulf-Heimsoth, M.; Angerer, J.; Pesch, B.; Marczynski, B.; Hahn, J.U.; Spickenheuer, A.; Preuss, R.; Ruhl, R.; Rode, P.; Bruning, T. [Institute at the Ruhr University of Bochum, Bochum (Germany)

    2008-07-01

    In our research project entitled 'Chemical irritative and/or genotoxic effect of fumes of bitumen under high processing temperatures on the airways,' 73 mastic asphalt workers exposed to fumes of bitumen and 49 construction nonexposed workers were analyzed and compared with respect to polycyclic aromatic hydrocarbons (PAHs) exposure and exposure-related health effects. In order to assess the internal exposure the monohydroxylated metabolites of pyrene, 1-hydroxypyrene (1-OHP), and phenanthrene, 1-, 2- and 9-, and 3- and 4-hydroxyphenanthrene (OHPH) were determined in pre- and post-shift urinary samples. Significantly higher concentrations 1-OHP and OHPH were detected in the post-shift urine samples of 7 mastic asphalt workers working on the same construction site compared to the reference workers and all other 66 mastic asphalt workers. The adjusted mean OHPH in the reference, 66 mastic worker, and 7 worker subgroups was 1022, 1544, and 12919 ng/g creatinine (crn) respectively, indicating a marked rise in the 7 worker subgroup. In addition, there was a more than 12-fold increase of PAH metabolites from pre- to post-shift in these 7 workers, whereas in the other mastic asphalt workers there was only a twofold rise in PAH-metabolite concentration between pre- and post-shift values. The analysis of a drilling core from the construction site of the seven workers led to the detection of the source for this marked PAH exposure during the working shift as being coal tar plates, which were, without knowledge of the workers and coordinators, the underground material of the mastic asphalt layer. The evaluation of the stationary workplace concentration showed enhanced levels of phenanthrene, pyrene, fluorene, anthracene, and acenaphthene during working shifts at the construction site of these seven workers. Our study shows that biological monitoring is also a useful tool for the detection of unrecognized sources with high PAH concentrations.

  10. Biological monitoring as a useful tool for the detection of a coal-tar contamination in bitumen-exposed workers.

    Science.gov (United States)

    Raulf-Heimsoth, Monika; Angerer, Jürgen; Pesch, Beate; Marczynski, Boleslaw; Hahn, Jens Uwe; Spickenheuer, Anne; Preuss, Ralf; Rühl, Reinhold; Rode, Peter; Brüning, Thomas

    2008-01-01

    In our research project entitled "Chemical irritative and/or genotoxic effect of fumes of bitumen under high processing temperatures on the airways," 73 mastic asphalt workers exposed to fumes of bitumen and 49 construction nonexposed workers were analyzed and compared with respect to polycyclic aromatic hydrocarbons (PAHs) exposure and exposure-related health effects. In order to assess the internal exposure the monohydroxylated metabolites of pyrene, 1- hydroxypyrene (1-OHP), and phenanthrene, 1-, 2- and 9-, and 3- and 4-hydroxyphenanthrene (OHPH) were determined in pre- and post-shift urinary samples. Significantly higher concentrations 1-OHP and OHPH were detected in the post-shift urine samples of 7 mastic asphalt workers working on the same construction site compared to the reference workers and all other 66 mastic asphalt workers. The adjusted mean OHPH in the reference, 66 mastic worker, and 7 worker subgroups was 1022, 1544, and 12919 ng/g creatinine (crn) respectively, indicating a marked rise in the 7 worker subgroup. In addition, there was a more than 12-fold increase of PAH metabolites from pre- to post-shift in these 7 workers, whereas in the other mastic asphalt workers there was only a twofold rise in PAH-metabolite concentration between pre- and post-shift values. The analysis of a drilling core from the construction site of the seven workers led to the detection of the source for this marked PAH exposure during the working shift as being coal tar plates, which were, without knowledge of the workers and coordinators, the underground material of the mastic asphalt layer. The evaluation of the stationary workplace concentration showed enhanced levels of phenanthrene, pyrene, fluorene, anthracene, and acenaphthene during working shifts at the construction site of these seven workers. Our study shows that biological monitoring is also a useful tool for the detection of unrecognized sources with high PAH concentrations.

  11. Reactivity of nitrate and organic acids at the concrete–bitumen interface of a nuclear waste repository cell

    Energy Technology Data Exchange (ETDEWEB)

    Bertron, A., E-mail: bertron@insa-toulouse.fr [Université de Toulouse (France); UPS, INSA (France); LMDC (Laboratoire Matériaux et Durabilité des Constructions), 135, avenue de Rangueil, F-31 077, Toulouse Cedex 04 (France); Jacquemet, N. [Université de Toulouse (France); UPS, INSA (France); LMDC (Laboratoire Matériaux et Durabilité des Constructions), 135, avenue de Rangueil, F-31 077, Toulouse Cedex 04 (France); Erable, B. [Université de Toulouse (France); INPT, UPS (France); CNRS, Laboratoire de Génie Chimique, 4, Allée Emile Monso, F-31030 Toulouse (France); Sablayrolles, C. [Université de Toulouse (France); INP (France); LCA (Laboratoire de Chimie Agro-Industrielle), ENSIACET, 4 allée Emile Monso, BP 44 362, 31432 Toulouse Cedex 4 (France); INRA (France); LCA (Laboratoire de Chimie Agro-Industrielle), F-31029 Toulouse (France); Escadeillas, G. [Université de Toulouse (France); UPS, INSA (France); LMDC (Laboratoire Matériaux et Durabilité des Constructions), 135, avenue de Rangueil, F-31 077, Toulouse Cedex 04 (France); Albrecht, A. [Andra, 1-7, rue Jean-Monnet, 92298 Châtenay-Malabry (France)

    2014-03-01

    Highlights: • Interactions of cement paste and organic acid–nitrate solutions were investigated. • Cement leaching imposed alkaline pH (>10) very rapidly in the liquid media. • Acetic acid action on cement paste was similar to that of classical leaching. • Oxalic acid attack formed Ca-oxalate salts; organic matter in solution decreased. • Nitrate was stable under abiotic conditions and with organic matter. - Abstract: This study investigates the fate of nitrate and organic acids at the bitumen–concrete interface within repository cell for long-lived, intermediate-level, radioactive wastes. The interface was simulated by a multiphase system in which cementitious matrices (CEM V cement paste specimens) were exposed to bitumen model leachates consisting of nitrates and acetic acid with and without oxalic acid, chemical compounds likely to be released by bitumen. Leaching experiments were conducted with daily renewal of the solutions in order to accelerate reactions. The concentrations of anions (acetate, oxalate, nitrate, and nitrite) and cations (calcium, potassium) and the pH were monitored over time. Mineralogical changes of the cementitious matrices were analysed by XRD. The results confirmed the stability of nitrates in the abiotic conditions of the experiments. The action of acetic acid on the cementitious matrix was similar to that of ordinary leaching in the absence of organic acids (i.e. carried out with water or strong acids); no specific interaction was detected between acetate and cementitious cations. The reaction of oxalic acid with the cementitious phases led to the precipitation of calcium oxalate salts in the outer layer of the matrix. The concentration of oxalate was reduced by 65% inside the leaching medium.

  12. 复合型胶粉改性沥青胶浆的流变性能研究%Research on the Rheological Properties of the Compound Rubber Power Modified Bitumen Mortar

    Institute of Scientific and Technical Information of China (English)

    韩颖; 涂亮亮

    2015-01-01

    通过 Brookfield 粘度试验及动态剪切流变试验,测试分析了复合型改性沥青胶浆的流变性能。研究结果表明,与 SBS 沥青相比,复合型改性沥青胶浆明显改善了沥青在高温下的稳定性,同时也降低了沥青的温度敏感性。%Through the Brookfield revolving viscosity test and the dynamic shear rheometer test,this paper analyzed the rheological properties of the compound rubber power modified bitumen mortar.The results indicated that,com-pared with the SBS bitumen mortar,the high-temperature stability of the compound rubber power modified bitumen mortar was significantly improved,and the temperature sensitivity of the bitumen was also reduced.

  13. Application of permeable crystalline waterproof material in Three Gorges Project%渗透结晶防水材料在三峡工程中的应用研究

    Institute of Scientific and Technical Information of China (English)

    陈磊

    2014-01-01

    水泥基渗透结晶型防水材料是以水泥、砂等为基料,渗入活性化学物质制成的新型防水材料。自2000年起,陆续应用于三峡工程碾压混凝土围堰和枢纽主体建筑物的表面防渗、裂缝修复等方面,是国内水电行业最早应用该类材料的大型工程。应用效果表明,裂缝内水流不能快速流动时,该材料才能析出钙质结晶填充裂缝从而达到防渗目的;渗透结晶的深度可随着水流的扩散而深入;由于该材料具有与混凝土相近的性质,未来可开发出具有防水特性的各种新型混凝土专用材料,应用前景广阔。%Cement-based permeable crystalline waterproof material is a new type of waterproof material that adopts cement and sand as base materials while incorporates other active substances. Since 2000, it had been used as surface waterproof and crack repairing for roller concrete cofferdam and main structures in the Three Gorges Project, which was the first application of this type of material in hydropower project in China. The application cases show that the material can only crystallize calcareous-crystal and play a role of waterproof when the adjacent water in crack flows slowly;the depth of permeable crystallization could be extended with dispersion process of flow;due to similar features of the material with normal concrete, several new special con-crete material with waterproof feature could be developed in future.

  14. Modification of waterproof property for foamed polystyrene grain and foaming gypsum thermal insulation material%聚苯颗粒/发泡石膏保温材料的防水性能改性

    Institute of Scientific and Technical Information of China (English)

    潘红; 高子栋

    2015-01-01

    采用掺加自制憎水性能优异的SFA防水剂和外喷甲基硅酸钠防水剂两种方式对聚苯颗粒/发泡石膏保温材料进行复合防水改性,研究了不同掺量SFA防水剂对保温材料吸水率、软化系数、密度、导热系数和绝干抗折抗压强度的影响,以及SFA防水剂最优掺量下外喷不同次数甲基硅酸钠防水剂对保温材料吸水率、软化系数的影响,并分析了其作用机理。结果表明:当SFA防水剂的掺量为16%并外喷三次甲基硅酸钠防水剂时,保温材料的各项性能明显改善,其中2h、24h吸水率分别降至40.30%、40.36%,软化系数升高至0.61。%The waterproof property of foamed polystyrene grain and foaming gypsum thermal insulation material is modified by SFA waterproof agent with good hydrophobic property and spraying methyl-sodium. The influences of SFA waterproof agent on the absorption rate, softening coefficient, density, coefficient of thermal conductivity and dry flexural, compressive strength of insulation material are investigated. Based on doping the optimum amount of SFA waterproof agent, the effects of different spraying times of methyl-sodium on the absorption rate and softening coefficient are studied, and their mechanism is also analyzed. The experimental results show that the properties of the thermal insulation material are improved obviously with doping of 16%of SFA waterproof agent and spraying methyl-sodium 3 times. The absorption rates for 2h and 24h reduce to 40.30%and 40.36%respectively and the softening coefficient rises to 0.61.

  15. 水泥基复合保温材料的防水性能研究%Study on the waterproofing properties of thermal insulation cement-based composite materials

    Institute of Scientific and Technical Information of China (English)

    李静; 李国忠

    2015-01-01

    Polystyrene granules (EPS) for lightweight aggregate and cement for cementing material, while adding a variety of additives, were used to prepare cement-based composite thermal insulation materials by the method of vibration molding. The effects of different waterproof agent on water absorption, flexural softening resistance coefficient and strength of cement-based composite thermal insulation materials were studied contrastively by adding emulsified stearic acid and emulsified composite waterproofing agent, and the related mechanisms were analyzed. Results showed that the waterproofing effect and strengthen effect of emulsified composite waterproofing agent is superior to emulsified stearic acid, when the content of emulsified stearic acid and emulsified composite waterproofing agent are 5% and 5%, respectively, the 2h, 24h water absorption of samples are 20.59%, 47.64%and 15.53%, 34.53%, the flexural softening resistance coefficient of samples are 0.71 and 0.75, the flexural and compressive strength of samples are 0.32MPa, 0.42MPa and 0.35MPa, 0.47MPa respectively.%以聚苯乙烯颗粒(EPS)为轻骨料、水泥为胶凝材料,同时掺加多种外加剂,经振动成型制备水泥基复合保温材料,通过掺加乳化硬脂酸和乳化复合防水剂,对比研究了不同防水剂对水泥基复合保温材料吸水率、抗折软化系数和强度的影响,并对其相关作用机理进行了分析。结果表明:乳化复合防水剂的防水效果和增强效果均明显优于乳化硬脂酸,当乳化硬脂酸和乳化复合防水剂掺量分别为5%和5%时,试样的2 h、24 h吸水率分别为20.59%、47.64%和15.53%、34.53%,试样的抗折软化系数分别为0.71和0.75,试样的抗折、抗压强度分别为0.32 MPa、0.42 MPa和0.35 MPa、0.47 MPa。

  16. Diagenetic bitumen in Ordovician carbonate reservoirs of the northern Tarim Basin%塔北地区奥陶系碳酸盐岩中的储层沥青

    Institute of Scientific and Technical Information of China (English)

    张鼐; 王招明; 鞠凤萍; 肖中尧; 房启飞; 张宝收; 卢玉红; 余小庆

    2013-01-01

    According to the relationship between the relative intensity of D-peak, G-peak and G-D peak spacing of bitumens and the maturity of bitumen evolution, we deduced that the Dh/Gh ratio and G-D peak spacing are positively proportional to bitumen maturity. Bitumens in Ordovician reservoir in the northern Tarim Basin are thought to have evolved in three stages and the Dh/Gh ratio and G-D peak spacing of Raman measurements on these bitumens indicated that the first-stage bitumen is highly-mature carbonaceous reservoir bitumen, the second-stage one is mature asphaltene reservoir bitumen, and the third-stage one is a combination of overmature oily reservoir bitumen and asphaltene reservoir bitumen. The formation of the first- and second-stage bitumens is attributed to thermal metamorphism, while the co-existence of two different bitumens for the third-stage bitumen is mainly due to selective adsorption of rocks. The distribution and property of these three-stages bitumens in Ordovician reservoirs of the northern Tarim Basin may determine the nature of Ordovician reservoirs, which is characterized by the southern condensate oil later than the northern heavy oil. The observation of oily reservoir bitumen in the northern Halahatang-Yingmaili region can provide evidence and targets for exploring Himalayan condensate oil reservoirs in this area.%利用沥青质拉曼D峰相对强度、G峰相对强度、两峰间距宽窄与沥青演化成熟度关系,推出Dh/Gh和G-D与沥青成熟度成正比关系图.塔北奥陶系储层中发育3期储层沥青,通过3期储层沥青拉曼Dh/Gh和G-D认为:第Ⅰ期为高热成熟炭质储层沥青,第Ⅱ期为成熟沥青质储层沥青,第Ⅲ期为过成熟油质储层沥青和沥青质储层沥青共存.前两期储层沥青是由于热变质而成,第Ⅲ期两种储层沥青共存主要是岩石选择性吸附导致.3期储层沥青的分布及性质决定塔北奥陶系成藏北部老、南部新,北部重质油、南部凝析油的

  17. Localized enrichment of polycyclic aromatic hydrocarbons in soil, spruce needles, and lake sediments linked to in-situ bitumen extraction near Cold Lake, Alberta.

    Science.gov (United States)

    Korosi, J B; Irvine, G; Skierszkan, E K; Doyle, J R; Kimpe, L E; Janvier, J; Blais, J M

    2013-11-01

    The extraction of bitumen from the Alberta oil sands using in-situ technologies is expanding at a rapid rate; however, investigations into the environmental impacts of oil sands development have focused on surface mining in the Athabasca region. We measured polycyclic aromatic hydrocarbons (PAH) in soils, spruce needles, and lake sediment cores in the Cold Lake oil sands region to provide a historical and spatial perspective on PAH contamination related to in-situ extraction activities. A pronounced increase in PAH concentrations was recorded in one of two study lakes (Hilda Lake) corresponding to the onset of commercial bitumen production in ~1985. Distance from extraction rigs was not an important predictor of PAH concentrations in soils, although two samples located near installations were elevated in alkyl PAHs. Evidence of localized PAH contamination in Hilda Lake and two soil samples suggests that continued environmental monitoring is justified to assess PAH contamination as development intensifies.

  18. Synthesis of quaternary derivatives of ortho-coco di-amido toluene and investigation of these compounds as cationic bitumen emulsifier

    Energy Technology Data Exchange (ETDEWEB)

    Hassanzadeh, Masoumeh; Tayebi, Leila; Dezfouli, Hedieh; Kambarani, Masoud; Avval, Parviz Ahmadi [Tehran Univ. (Iran, Islamic Republic of). ACECR, Designing Chemical Process Research Group

    2012-05-15

    Bitumen emulsions are preferred over conventional pavement systems due to their biologically and environmentally acceptable formulation, safety, low viscosity, storage stability, and cost effectiveness. The present investigation deals with the systematic study to synthesize ortho-cocodi-amido toluene and four quaternary derivatives by amidation of coconut oil and ortho toluene diamine (OTD), followed by quaternization with formaldehyde, formic acid mixture, and acrylonitrile, resulted in a new quaternary compound useful as cationic emulsifier in bitumen emulsions. The roles of temperature and reaction time in determining optimum conditions were investigated as well. Emulsifying behavior of these quaternary compounds was studied by sieve residue test, settlement and storage stability test of emulsified asphalt, and water solubility. The results show that the acrylonitrile imidazolinium derivative of o-cocodi-amido toluene (VI) can be used as a rapid-medium setting emulsifier. (orig.)

  19. A new modifier for asphalt waterproof material%一种新型沥青防水材料改性剂

    Institute of Scientific and Technical Information of China (English)

    范新宇; 孔繁和

    2001-01-01

    The influence of environmental status and process thought on asphalt waterproof material is presented.The asphalt performance is improved by means of interior preparation, exterior addition, blowing (oxdation) and dosing raw material of asphalt. The asphalt is modified by addition process of high molecule polymer. This article introduces a new asphalt madifier with main compositions of ethylene acrylate n- butyl ester and glycidyl methacrylate co- polymer. The asphalt modification is achieved through chemical reaction between the copolymer and asphalt.%介绍环境气候、工艺思路对沥青防水材料的影响 ,通过内配法、外掺法、吹制(氧化)沥青及调配沥青的原料, 达到改善沥青性能的方法;掺加高分子聚合物改性石油沥青 的方法及改性性能。较详细介绍一种新的沥青改性剂,它的主 要成份为乙烯丙烯酸正丁脂和甲基丙烯酸缩水甘油脂共聚物 ,通过与沥青之间产生化学反应达到对沥青改性的目的。

  20. LmCYP4G102: An oenocyte-specific cytochrome P450 gene required for cuticular waterproofing in the migratory locust, Locusta migratoria.

    Science.gov (United States)

    Yu, Zhitao; Zhang, Xueyao; Wang, Yiwen; Moussian, Bernard; Zhu, Kun Yan; Li, Sheng; Ma, Enbo; Zhang, Jianzhen

    2016-07-22

    Cytochrome P450 superfamily proteins play important roles in detoxification of xenobiotics and during physiological and developmental processes. To contribute to our understanding of this large gene family in insects, we have investigated the function of the cytochrome P450 gene LmCYP4G102 in the migratory locust Locusta migratoria. Suppression of LmCYP4G102 expression by RNA interference (RNAi) does not interfere with moulting but causes rapid loss of body weight - probably due to massive loss of water, and death soon after moulting. Accordingly, maintaining these animals at 90% relative humidity prevented lethality. Consistently, RNAi against LmCYP4G102 provoked a decrease in the content of cuticular alkanes, which as an important fraction of cuticular hydrocarbons have been shown to confer desiccation resistance. In addition, the cuticle of LmCYP4G102-knockdown locusts was fragile and easier deformable than in control animals. Presumably, this phenotype is due to decreased amounts of cuticular water that is reported to modulate cuticle mechanics. Interestingly, LmCYP4G102 was not expressed in the epidermis that produces the cuticle but in the sub-epdiermal hepatocyte-like oenocytes. Together, our results suggest that the oenocyte-specific LmCYP4G102 plays a critical role in the synthesis of cuticular hydrocarbons, which are important for cuticle waterproofing and mechanical stability in L. migratoria.

  1. High power red laser oscillation in Pr3+-doped waterproof fluoroaluminate glass fiber excited by a GaN laser diode

    Science.gov (United States)

    Nakanishi, J.; Yamada, T.; Fujimoto, Y.; Ishii, O.; Yamazaki, M.

    2011-02-01

    We have demonstrated a high power red fiber laser with a Pr-doped waterproof fluoro-aluminate glass fiber (Pr:WPFGF). When 800 mW pumping power of a blue/violet GaN laser diode (GaN-LD) was launched into the Pr:WPFGF (core diameter 8 μm, length 40 mm) with dielectric coating on both end surfaces to construct a resonator, the maximum output laser power at 638 nm was obtained to be 311.4 mW that is higher than previously reported Pr:ZBLAN fibers. The threshold power was evaluated to be 52.1 mW, and the slope efficiency was calculated to be 41.6%. Assuming the resonator to be a Fabry-Perot resonator, we can calculate the output power to be 336 mW at 800 mW pump power and the slop efficiency to be 44.2%. These theoretical values show good agreement with experimental ones.

  2. Weaving Processing Optimization of Waterproof Permeable Fabric%防水透湿织物织造工艺的优化

    Institute of Scientific and Technical Information of China (English)

    蔡东照; 胥正安

    2011-01-01

    探讨防水透湿织物的织造工艺要点.选用超细涤纶高收缩纤维,结合高密度织物组织设计,通过优选卷取方式、经纱张力、开口时间、送经张力补偿弹簧圈数、筘的空间率等工艺参数,认为选用W型卷取方式、适当降低经纱张力、适当提早开口时间、合理选择筘的空间率等,可使织机效率得到有效提高.%Weaving processing key points of waterproof permeable fabric were discussed. Superfine polyester shrinkage fiber was selected, combining high density fabric weave design, processing parameter was optimized including take-up style,warp tension, shed time,warp let-off tension compensation spring coils,reed density et al. It is considered that loom efficiency could be improved effectively when adopting W type take-up, reducing warp tension properly, setting shed time early,selecting reed density rationally et al.

  3. 环保型 SBS 改性沥青防水涂料的研制%Development of Eco -friendly SBS Modified Bitumen Coating

    Institute of Scientific and Technical Information of China (English)

    郭树平

    2016-01-01

    formulation,manufacturing process,construction considerations of SBS modified bitumen coatingwere introduced,the main factors affecting the coating properties were discussed.%介绍了 SBS 改性沥青防水涂料的配方、生产工艺、施工注意事项,讨论了影响涂料性能的主要因素。

  4. Micrometer scale carbon isotopic study of bitumen associated with Athabasca uranium deposits: Constraints on the genetic relationship with petroleum source-rocks and the abiogenic origin hypothesis

    Science.gov (United States)

    Sangély, L.; Chaussidon, M.; Michels, R.; Brouand, M.; Cuney, M.; Huault, V.; Landais, P.

    2007-06-01

    In situ analytical techniques - Fourier transform infrared microspectroscopy (μFTIR) and ion microprobe - have been used to unravel the origin of solid bitumen associated with the uranium deposits of Athabasca (Saskatchewan, Canada). Both aliphaticity and carbon isotopic compositions within the samples are heterogeneous but spatially organized in concentric zonations at the micrometer scale. Finally, the δ13C values are positively correlated to the aliphatic contents over an extremely large isotopic range from ˜ - 49‰ to ˜ - 31‰. We infer that this positive correlation may be related to the carbon isotopic fractionations associated with the synthesis of bitumen through the catalytic hydrogenation of CO 2, rather than the result of pre-existing petroleum product precipitation and/or alteration (such as radiolysis). This explanation is consistent with (i) published results of abiogenic synthesis experiments, in which the differences in δ13C values between saturated and unsaturated hydrocarbons range from + 2 and + 19‰, in contrast to the differences systematically observed in conventional bitumen and petroleum ranging from 0‰ to - 4‰; (ii) the absence of a similar positive correlation between aliphatic contents and δ13C values in the other bitumen analyzed in the present study, for which a biogenic origin has been unequivocally established (samples from Oklo, Gabon, and Lodève, France, uranium deposits); (iii) the presence of CO 2 and H 2 in the gas-phase of fluid inclusions in the Athabasca uranium deposits, H 2 resulting from water radiolysis. The present results suggest that the δ13C vs. aliphaticity correlation could be used as a criterion to discriminate between abiogenic vs. biogenic origin of macromolecular organic matter.

  5. CO2驱油中沥青质沉积条件及对驱油效果影响的研究%The Study on Depositional Condition of Bitumen and Displacement Characteristics Effect of CO2 Flooding

    Institute of Scientific and Technical Information of China (English)

    赵明国; 赵宇

    2011-01-01

    Reservoir conditions in Yushulin Oil field, through PVT Parameters and CO2 flooding experiments is simulated. The depositional condition of bitumen after CO2 injection is studied and analyzd the displacement characteristics of CO2 flooding on the effect of bitumen deposition. The results show that: at the reservoir temperature (108℃), the bitumen deposition is appeared when the injection pressure reaches 28.4 MPa, with the temperature increases, the pressure of the formation of bitumen deposition and the degree of bitumen deposition increases; with the pressure of CO2 injection increase, the bitumen deposition increases, and the bitumen in the crude oil decreased, the content of colloid, aromatics, saturated hydrocarbon increased, after the pressure of CO2 injection reach 28 MPa, the content of bitumen deposition decreased, the bitumen content of recovery oil increased. Bitumen deposition reduce the recovery ratio of 12.29% and the recovery ratio decrease sharpest when the injection pressure of 25-28 MPa.%在模拟榆树林油田地层条件下,通过高压物性及CO2驱油实验,研究了注CO2后沥青质的沉积条件,并对沥青质沉积对CO2驱油效果的影响进行了分析.结果表明:在地层温度(108℃)下,注气压力达到28.4 MPa时可明显出现沥青质沉积.随着温度增加,形成沥青质沉积的压力增加,沥青质沉积的程度增加;随CO2注入压力的增加,沥青质沉积量增加,原油中的沥青质含量降低,胶质、芳烃、饱和烃含量增加;达到28 MPa后沥青质沉积量逐渐减少,采出油中沥青质含量增加.沥青质沉积使采收率降低12.29%以上,在(25-28) MPa时采收率降低幅度最大.

  6. SBS改性沥青混合料性能对比试验研究%Testing Research on Pavement Performance of SBS Modified Bitumen

    Institute of Scientific and Technical Information of China (English)

    李宇峙; 刘朝晖; 黄云涌

    2001-01-01

    结合长沙市五一路改造工程中改性沥青路面的工程实际,对比研究了SBS改性沥青的技术指标、沥青与矿料的粘附性、沥青混合料的马歇尔稳定度、浸水马歇尔稳定度、沥青混合料车辙动稳定度、劈裂强度、无侧限抗压强度、抗压模量等参数,对改性沥青的效果与路用性能指标进行了全面的试验研究。%Combining with modified asphalt pavement engineering of the Wuyi Road in Changsha City, the parameter of the technica l index of SBS modified bitumen, the bond between bitumen and aggregate, the Mar shall stability of asphalt mixture, the Marshall stability of impregnated asphal t mixture, the rut dynamic stability of asphalt mixture, the cleavage st rength and unconfined compression strength as well as compression modulus we re researched by comparative test. The effect of modified bitumen and the index of pavement performance were comprehensively studied through testing.

  7. Application of instrumental techniques like NMR and GPC in the field of polymer modified bitumens; Determinazione mediante NMR e GPC di polimeri incorporati in bitumi modificati

    Energy Technology Data Exchange (ETDEWEB)

    Barbieri, M.; Di Gennaro, E.; Mascherpa, A.; Vecchi, C. [Stazione Sperimentale per i Combustibili, San Donato Milanese, Milan (Italy)

    1996-05-01

    In the present work a simple method is proposed to determine, at the same time, the nature of the polymer, the composition of polymer/bitumen blends and the origin of the bitumen. The procedure is based on nuclear magnetic resonance (NMR). In a few minutes and without any sample manipulation, a simple NMR proton spectrum reveals the presence and the nature of the polymer in road bitumens modified with different contents of SBS, SIS, EVA. EMA. The detection limits are function of the instrument used and the nature of the polymer. NMR data have been compared with those obtained by gel permeation chromatography (GPC) which is a less expensive technique than NMR, but does not allow can easy identification of the polymer. When the polymer concentration in the mixture is very low (1-2%), the difference between know and calculated values increases: better results can be obtained analysing the n-pentane insolubles, where the whole amount of the modifier is observed.

  8. Characterization of nickel and vanadium compounds in tar sand bitumen by petroporphyrin quantitation and size exclusion chromatography coupled with element specific detection

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, J.G.; Jones, E.L.; Bennett, J.A.; Biggs, W.R.

    1988-02-01

    Previously, we have examined the Ni and V in heavy crude oils, residua, and processed products by several metal speciation techniques to ascertain molecular structure and processing behavior. Two classes of metal compounds were found/--/metallopetroporphyrins and metallo-nonporphyrins/--/each having unique reactivity during processing. In efforts to better understand the binding of metals in the oil medium, we have now examined Ni and V in tar sand bitumens. The bitumen was solvent extracted from the sand matrix and was separated by column chromatography to quantitate petroporphyrin content. The petroporphyrin contents ranged from virtually none to over 36% of the total metals. Asphalt Ridge (Utah) has primarily Ni petroporphyrins; Big Clifty (Kentucky) and Athabasca (Canada) have primarily V petroporphyrins; Arroyo Grande and McKittrick (California) have roughly equal amounts of both types; and Sunnyside (Utah) has virtually none of either. Size characteristic profiles (SEC-HPLC-ICP) were generated for the extracted bitumens. The profiles are generally bimodal in shape and resemble several different specific heavy crude oils and residua. For examples, Arroyo Grande and McKittrick appear to be similar to Kern River (California) 650/degree/F+ residuum, while Athabasca resembles Morichal (Venezuela) 650/degree/F+ residuum. These results will be discussed in terms of generalized profile and petroporphyrin behavior. 23 refs., 3 figs., 3 tabs.

  9. Application of thermal analysis in characterization of bitumen%热分析技术在沥青表征中的应用

    Institute of Scientific and Technical Information of China (English)

    李吉广; 侯焕娣; 董明; 权奕

    2013-01-01

    介绍了近些年来国内外热分析技术在沥青分析中的应用进展.首先阐述了热分析技术在沥青产品的相态与结构、硬化过程、低温抗裂能力、老化、热稳定性、流变性等六方面的应用,最后展望了热分析技术在沥青表征方面的应用前景.%The progress of thermal analysis technique on characterization of bitumen in recent years was introduced.The analysis of the phase behavior and structure,hardening process,low temperature cracking resistance capacity,aging,thermal stability and rheology property of bitumen by thermal analysis technique,are focused in this study.The development prospects of thermal analysis technique in characterization of bitumen are proposed as well.

  10. SBS改性沥青防水卷材在路桥防水系统的应用及全自动铺设工艺%The utilization of SBS modified bitumen waterproof membrane on bridge decks and automatic installation technology

    Institute of Scientific and Technical Information of China (English)

    贾伟一

    2005-01-01

    简要回顾了桥面防水的发展史,分析了防水层被破坏的原因及防水层应具有的功能,介绍了SBS改性沥青桥梁专用防水卷材的构成、特点,并对索普瑞玛公司的全自动铺设系统Macaden、配套的200m长卷材Antirock及其铺设过程作了介绍,最后对桥面防水的发展提出了几点建设.

  11. Application of Non-penetrating PVC Flexible Waterproofing System in Repair Engineering of Failed Self-adhesive Bitumen Membrane Roof%无穿孔PVC柔性系统在失效自粘沥青卷材屋面维修工程中的应用

    Institute of Scientific and Technical Information of China (English)

    万常彪; 韩啸

    2016-01-01

    杭州地铁2号线蜀山车辆段综合基地屋面为轻质太空板钢网架结构,新建时采用自粘型SBS防水卷材,两年后即由于卷材老化等原因出现漏水.本文介绍了采用PVC防水卷材无穿孔施工工艺,对该屋面进行翻修的技术,重点对屋面变形缝、气楼、天窗等细部节点的处理作了阐述.

  12. The Waterproof Effect Analysis and Improvement Techniques for Underground Stations of Xi’an Metro Line No .3%西安地铁3号线地下车站防水效果分析及其改进技术研究

    Institute of Scientific and Technical Information of China (English)

    王军琪; 邓国华

    2015-01-01

    Based on the study of the waterproof design and its effect for the underground stations of Xi’an Metro Line No . 3 ,a set of waterproof design schemes which are suitable for these stations were proposed .In the study ,the waterproof ef-fects of different schemes were tested out on a few typical stations ,and then the subsequent waterproof schemes were de-termined ,which were the combination of outer waterproof coating of the structure ,joint and roof waterproofing .More-over ,the improvement measures and suggestions for the subsequent construction were put forward based on the waterproof effects .It is suggested that macromolecule polythene self-adhesive waterproof roofing should be adopted in the sections with complex strata and abundant ground water .During the construction of the joint waterproofing ,the installation of steel-edged rubber water stop in the middle of the vertical joints and galvanized steel plate water stop in the middle of the horizontal joints should be handled with extra attention .%通过对西安地铁3号线地下车站防水设计及其效果研究,提出了一套适用于西安地铁地下车站的防水设计方案。研究中选择典型车站进行试验,比较了不同防水方案下的防水效果,确定了后续西安地铁地下车站外包防水、接缝防水和顶板防水的设计方案,并根据防水效果,提出了相应的改进措施和建议。建议在地下水丰富且地层复杂地段采用聚乙烯高分子自粘防水卷材;在施工缝防水管理中建议重点把控对垂直施工缝中部设置钢边橡胶止水带、水平施工缝中部设置镀锌钢板止水带的接头处理。

  13. Synthesis and investigation dark polymer hydrocarbon resins in the bitumen composites

    OpenAIRE

    Никулишин, Ірена Євгенівна; Піх, Зорян Григорович; Шевчук, Лілія Іванівна; Рипка, Анна Мирославівна; Чайківська, Руслана Тарасівна

    2016-01-01

    Thermal gas-phase pyrolysis of hydrocarbon raw materials in pipe furnaces remains to be the main strategic process of ethylene and propylene production. Nowadays, the possibility of the pyrolysis process intensification to increase the target product yield draws attention of scientists. But besides the olefins (target products) the pyrolysis process is the source of heavy pyrolysis pitch. Considerable development of petrochemical industry requires finding new applications of the by-products f...

  14. Investigation on water-assisted solvent extraction of bitumen from oil sands%水辅助溶剂法提取油砂中的沥青

    Institute of Scientific and Technical Information of China (English)

    杨红强; 丁明山; 胡斌; 任嗣利

    2014-01-01

    开发了一种水辅助溶剂法从油砂中提取沥青的技术。该方法通过在油砂固相与有机溶剂间介入水层提取油砂中的沥青。以内蒙古扎赉特旗油砂矿为研究对象,考察了温度、剂砂质量比、提取时间、甲苯在复合溶剂中的含量及溶剂的种类与性质对沥青回收率高低的影响,结果表明:最佳提取条件为提取温度50℃,剂砂质量比1∶1,提取时间25min。沥青回收率与提取溶剂的性质紧密相关,水层介入有效降低了固体微粒组分在有机相中的含量,且便于后续的有机相与泥砂相的分离。通过对各种溶剂提取的沥青进行组分分析,发现各种溶剂对沥青提取能力的差异性源于溶剂的化学组成和结构不同。本文相关研究结果对溶剂法提取油砂中沥青技术及溶剂种类的选择具有指导作用。%Water-assisted solvent extraction processes (WASEPs) were developed by introducing a water layer between the oil sands and solvent to extract bitumen. The function of the introduced water layer in the WASEPs is to effectively reduce the fine solids content in the solvent phase and make it easy to separate bitumen solution from solids. Effects of the solvent type on bitumen recovery were investigated and the extraction conditions were optimized. The results showed that bitumen recovery was closely related to the solvent compositions and chemical structure. The optimal extraction condition was stirring at 50℃ for 25 minutes using a ratio of oil sands to solvent at 1∶1(wt/wt). The reason of different extraction abilities for various solvents was revealed by analyzing the component of extracted bitumen. It may be useful to guide the solvent extraction processes and solvent selection.

  15. 建筑中防水性能造价约束与抗冲击能力建模%Modeling of Cost Constraints in Building Waterproof Performance and Shock Resistance

    Institute of Scientific and Technical Information of China (English)

    绳晓庆

    2015-01-01

    The relationship between the anti shock ability analysis of cost and building waterproof engineering in civil and structural engineering, cost constrained optimal and anti impact performance ratio is achieved. Waterproof construction in the traditional relational model, empirical mode decomposition and by the stiffness degradation model design of building waterproof performance of remainder binding and shock resistant ability, model affected by impact fatigue damage and ma⁃terial cost ratio, the relationship between model, it should use less value. A waterproof performance cost constraint model based on impact damage cracking point and the yield point is proposed, the characteristic energy limited, the relationship between anti impact ability analysis of cost constraints and building body. Impact Damage Cracking point analysis of the building results and the yield point, the characteristic energy confinement model, constructing the element equilibrium equation, on the basis of Euler-Bernoulli waterproof performance cost residue theory establishment of steel frame, nonlin⁃ear finite element model of multi scale, from the overall structure of the layer structure in the face of the yield mechanism to evaluate, get in waterproofing design impact the longitudinal residual stress distribution model. By using the finite element analysis software ANSYS waterproof performance cost constraint parameters in architecture, implementation of modeling waterproof performance cost constraint construction and anti impact capability analysis. Test results, using this model, can realize to waterproof the most under cost, realize the impact resistance performance of building structure of the biggest im⁃pact, the anti damage strength under the same cost saving, the waterproof is saved by 28%, improve the quality of construc⁃tion, it has the important meaning to save the project cost.%分析土建结构中防水工程造价与建筑体抗冲击能力的关系,达到最优的

  16. Extraction of bitumen, crude oil and its products from tar sand and contaminated sandy soil under effect of ultrasound.

    Science.gov (United States)

    Abramov, O V; Abramov, V O; Myasnikov, S K; Mullakaev, M S

    2009-03-01

    In the present paper, the kinetics of the water extraction of bitumen from tar sand and crude oil or residual fuel oil from model contaminated soils under the effect of ultrasound is studied. The influence of process temperature, ultrasound power, the nature, and properties of the components of heterogeneous mixtures being separated, and the concentration of added alkaline reagents on the rate and degree of oil recovery is investigated. A functional form of the dependencies of separation efficiency on the mean size of solid particles and the temperature of a working medium is found. Optimum concentrations of reagents in the process solution are determined. It is shown that the spent solution of sodium silicate can be multiply used for separation, its reuse even speeding up the yield of oil in the initial period. Taking into account obtained results, a multipurpose pilot plant with a flow-type reactor for ultrasonic extraction of petroleum and its products from contaminated soils was manufactured and tested. During tests, the purification of sandy soil contaminated with residual fuel oil was carried out which verified the results of laboratory studies.

  17. Geochemical characteristics of light hydrocarbons in cracking gases from chloroform bitumen A,crude oil and its fractions

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The composition characteristics of light hydrocarbons from crude oil,chloroform bitumen A,saturated hydrocarbon fraction,aromatic hydrocarbon fraction,and asphaltene fraction during cracking have been studied systematically. The results revealed that the content of n-alkanes,branched alkanes and cycloalkanes in light hydrocarbons from the samples gradually decreased as the simulation temperature increased,and finally almost depleted completely,while the abundance of methane,benzene and its homologues increased obviously and became the main products. The ratios of benzene/n-hexane and toluene/n-heptane can be used as measures for oil cracking levels. Variation characteristics of maturity parameters of light hydrocarbons,for example,iC4/nC4,iC5/nC5,isoheptane value,2,2-DMC4/nC6,and 2-MC6+3-MC6/nC7 for different samples with increasing pyrolysis temperature,are consistent with those in petroleum reservoirs,indicating that these parameters may be efficient maturity index.

  18. Strategic human resources study of the upstream petroleum industry : the decade ahead

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-10-01

    This report presents the results of a 10 month study of the human resources issues in Canada's upstream petroleum industry. The study identifies workforce demographics, skills, and supply and demand. It also discusses the impact of technology and other key challenges facing human resources issues. The upstream petroleum industry includes exploration and production, service industries, pipeline transmission, natural gas processing, and heavy oil and bitumen extracting and upgrading. The study defined four regions in Canada: Western Canada Sedimentary Basin, the oil sands, the north, and the east coast. The main influences on the management practices within the upstream petroleum industry are: globalization; cyclical economic conditions; operational excellence business models; government regulatory requirements; stakeholder expectations for involvement; technological advances; changing demographics, and workplace skills. The study also presented suggestions for changes in best practices to improve the efficiency and effectiveness of product and service delivery. refs., tabs., figs.

  19. The Application of Waterproofing Membrane in Automotive Interior Acoustic Environment%新型防水膜在汽车内饰声学环境中的应用

    Institute of Scientific and Technical Information of China (English)

    田佳平; 梁鹏; 高玉香; 潘萍萍

    2011-01-01

    In order to reduce noise of automotive interior acoustic environment, based on acoustic properties of laminated materials and waterproofing membrane material characteristics, adopting spot test data, combined with interior design experience, acoustic performance, cost and operational characteristic of waterproofing membrane materials and combination lining materials of three main doors are contrasted. The results indicated that waterproofing membrane of X-PE materials meets the design requirements. It shows good effect in sound insulation and sound absorption. High rigidity materials can improve the efficiency of sound insulation in composite materials. It provides reference for new materials used in function expansion of door trim pieces.%为降低汽车内饰声学环境的噪声,依据层复合材料的声学特性与防水膜材料特点,采用现场实测数据,结合内饰设计工作经验,对3种主流车门防水膜材料及其组合内衬材料的声学性能、成本及使用特性进行对比,结果表明,XPE材料防水膜满足设计要求,吸声和隔声效果良好,在层复合材料中,刚性高的材料能提高隔声效果。为新型材料用于车门内饰件功能扩展方面的设计提供了参考。

  20. LDHs 对 SBS 沥青流变性能及微观结构的影响%Effect of LDHs on the Rheological Properties and Microstructure of SBS Bitumen

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    采用 LDHs 改性剂对 SBS 沥青进行改性,制备 LDHs/SBS 改性沥青,并对其流变性能和微观结构进行研究,探讨 LDHs 对 SBS 沥青性能的影响。试验结果表明,LDHs 的加入使沥青的复合模量增大,相位角减小;通过 X-ray 射线衍射、红外光谱及光学显微镜分析可知 LDHs 只是分散在 SBS 沥青中,没有发生化学反应或形成插层结构。%This paper aimed at manufacturing LDHs modified SBS bitumen,and researched the properties and mi-crostructure of LDHs/SBS modified bitumen,explored the influences of LDHs on the modified bitumen.The results indicated that the complex modulus of LDHs/SBS modified bitumen increased,while the phase angle decreased with the introduction of LDHs.Meanwhile,seen through the X-ray diffraction,optical microscope and infrared spectrome-ter,the structure of LDHs was dispersed in the SBS bitumen instead of intercalation.

  1. 地下室外墙聚合物柔性防水监理工作经验探讨%Discussion on Supervision Experience on Flexible Waterproof of Basement Exterior Wall Polymer

    Institute of Scientific and Technical Information of China (English)

    李志勇

    2014-01-01

    This article discusses the supervision control method in the application of polymer flexible waterproof of basement exterior wall from aspects of quality control, schedule control and safety management, which provides reference for professional technical management personnel.%本文从质量控制、进度控制、安全管理等方面,探讨地下室外墙聚合物柔性防水应用中的监理控制方法,以供专业技术管理人员借鉴。

  2. 基于Leaky Noisy OR模型的运营隧道防水系统可靠性研究%Reliability Research of Operating Tunnel Waterproof System Based on the Leaky Noisy OR

    Institute of Scientific and Technical Information of China (English)

    赵长庆; 李晓钟

    2015-01-01

    The concealment of the operating tunnel and the uncertain and complex risk factors both increase the difficulty in the reliability research of operational tunnel waterproof system. Firstly this paper established the bayesian network topology and identified the root node prior probability of the failure of values based on the history data and expert experience. Secondly the Leaky Noisy OR model is introduced into the bayesian network,which greatly reduced the demand of the conditional probability value,at the same time improved the accuracy of the models. Then this paper applied GeNIe Ver 2.0 software to model deduction,calculated the tunnel waterproof system failure probability and posterior probability of each risk factor respectively. The size of the posterior probability can provide theoretical guidance for tunnel waterproofing system operation maintenance,and improve the work efficiency. Finally through the sensitivities analysis of each risk factor,this paper found out the sensitivity of the system factor, provided guidance to reduce the occurring probability of sensitive factors to improve the reliability of tunnel waterproofing system in the tunnel construction.%由于运营隧道的隐蔽性和风险因素的不确定性、复杂性增加了运营隧道防水系统可靠性研究的难度.根据历史数据和专家经验建立了贝叶斯网络拓扑结构并确定根节点发生故障的先验概率值,将Leaky Noisy OR模型引入到贝叶斯网络中,大大降低对条件概率值的需求量,同时提高模型的准确性.并应用GeNIe Ver 2.0软件对模型进行推导,分别计算出隧道防水系统的失效概率和各风险因子的后验概率,根据后验概率的大小可以为隧道防水系统运营维护提供理论指导,提高工作效率.通过对各风险因子进行敏感性分析,找到系统中存在的敏感性因子,指导在隧道施工中降低敏感因子的发生概率以提高隧道防水系统的可靠性.

  3. Grey Target Optimization of Waterproof Adhesive Material for Concrete Bridge Deck Pavement Based on Mechanical Analysis%基于力学分析的桥面铺装防水粘结层材料灰靶优选

    Institute of Scientific and Technical Information of China (English)

    于新; 李英涛; 刘云

    2012-01-01

    为了优选与混凝土箱梁桥防水粘结层实际受力状态相匹配的材料,以沪杭高速公路拓宽改建工程高架桥为例,采用有限元法建立了全桥模型,在分析刹车、超载、随机动荷载等因素对防水粘结层力学响应的基础上,利用灰靶理论优选室内实测典型防水粘结层的相关技术参数.研究结果表明:刹车超载使防水粘结层产生的剪应力大于由桥面不平度引起的防水粘结层剪应力,最大可达0.397 MPa;橡胶沥青和SBS改性沥青防水粘结层综合性能较优,可作为混凝土桥防水粘结层材料.%In order to select the optimal waterproof adhesive material that meets the stress needs of concrete box girder bridge deck pavement, taking the viaduct in widening project of the Shanghai-Hangzhou Expressway as an example, a composite structure model of the whole bridge was established using the finite element method, and the influence of braking, overloading, random dynamic loading on the mechanical response of the waterproof adhesive layer was analyzed. The technique parameters of some typical materials for waterproof adhesive layer were tested in lab, and then analyzed by the grey target theory. The result shows that braking plus overloading has a larger effect on the shear stress of adhesive layer than the random dynamic loading caused by bridge deck roughness, and may produce a maximum shear stress of 0. 397 MPa. The rubber asphalt and SBS modified asphalt both have good performance, and can be used as the material of waterproof adhesive layer.

  4. Industrial Chain: Industrial Vertical Definition

    Institute of Scientific and Technical Information of China (English)

    YifeiDu; GuojunJiang; ShimingLi

    2004-01-01

    Like value chain and supply chain, “industrial chain” becomes the focus of attention. The implication of “industrial chain” has gained a large range of extension. It not only expresses the industrial “chain” structure and relationship of “back and forward”in order or “up and down” in direction, but also it represents a cluster of large scale of firms in an area or colony. It is a network, or a community. Consequently, we conclude that “industrial chain” is a synthesis of industrial chain, industrial cluster, or industrial network.In this article, firstly we will distinguish industry chain from industry. An industry is the collection of firms that have the same attribute, so an industry can be defined by firm collection of certain attribute. We indicate that industrial chain is a kind of vertical and orderly industrial link. It is defined according to a series of specific product or service created. Secondly we analyze the vertical orderly defiinition process from the aspects of social division of labor and requirement division, self-organization system, and value analysis.Non-symmetry and depending on system or community of large scale of industrial units lead to entire industry to “orderly” structure. On the other hand, the draught of diversity and complexity of requirement simultaneously lead to entire industry to be more “orderly”. Along with processes of self-organization, industrial will appi'oach the state of more orderly and steady, and constantly make industrial chain upgrade. Each firm or unit, who will gain the value, has to establish channels of value, which we called “industrial value chain”. Lastly,we discuss the consequence of vertical and orderly definition, which is exhibited by a certain relationship body. The typical forms of industrial chain include industrial cluster, strategy alliance and vertical integration etc.

  5. Coating of evaporation concentrates with bitumen. Progress Report No. 1; Enrobage des concentrats d'evaporation par le bitume. Etat d'avancement no. 1

    Energy Technology Data Exchange (ETDEWEB)

    Rodier, J.; Lefillatre, G.; Rodi, L.; Cudel, Y. [Commissariat a l' Energie Atomique, Chusclan (France). Centre de Production de Plutonium de Marcoule

    1968-07-01

    Laboratory tests have been carried out on the coating by bitumen of evaporation concentrates having a free nitric acidity of 1 N or 2.5 N, and a high mineralization (400 gm/litre). In order to neutralize the free acidity and to trap the radio-elements, these concentrates have been subjected before coating to various treatments designed to decrease the solubility. As a result of these treatments, sludges were obtained which could be coated directly with the bitumen. By measuring the radioactive diffusion factors of the bitumen coated products immersed both in ordinary and sea water, it was possible to compare the efficiency of the processes developed and of the various types of bitumen used. On the whole the radioactive diffusion tests were satisfactory and the process using successive co-precipitations (hydroxides, nickel ferrocyanide, barium sulphate) was chosen. From the bitumens tried out, a straight - asphalt, Mexphalt 40/50 was selected for low and medium activity concentrates as it ensures good isolation of the radio-elements; an air-blowing asphalt, Mexphalte R 90/40, was chosen for concentrates of high activity because of its higher resistance to irradiation. As a result of this work, a simple coating technology was evolved and pilot experiments will soon begin. Briefly, it appears that although a method for coating evaporation concentrates with bitumen has been defined, it will inevitably be necessary to devise a specific decontamination process each time that a new type of concentrate is encountered (composition, nature of the salts, radio-element distribution). (author) [French] Des essais d'enrobage par le bitume des concentrats d'evaporation ayant une acidite nitrique libre de 1 N ou de 2.5 N et une mineralisation elevee (400 g/litre) ont ete realises en laboratoire. Dans le but de neutraliser l'acidite libre et de pieger les radio-elements, ces concentrats ont ete soumis avant leur enrobage a divers traitements d

  6. 非均质超厚活跃沥青层安全钻井技术探讨%Discussion on Safe Drilling Technology for Heterogeneous,Ultra-Thick and Active Bitumen Zone

    Institute of Scientific and Technical Information of China (English)

    何青水; 宋明全; 肖超; 黄在福; 王学杰

    2013-01-01

    During development of Y Oilfield, several wells were drilled through Kazhdumi Formation which contains ultra-thick active bitumen. Those heterogeneous and scatterly-distributed formations brought severe challenges to drilling operation. In particular,drilling fluid contamination,simultaneous mud loss and well kick,escaping H2 S and other complexities have caused abandonment of several wells and tampered with the overall progress of Y Oilfield development. Based on actual drilling data, the active bitumen zone is investigated in respect to formation pressure,connecting channel,bitumen feature and its distribution, and treatment difficulties are also analyzed. Then,the technical solution is proposed for further study on the distribution of bitumen and optimize casing program and managed pressure drilling(MPD)along with bitumen hardening process. The results show that the pressure of active bitumen is 1. 58-1. 65 g/cm3 and the long open hole where bitumen zone is encountered in current casing program is a bottleneck in the treatment of active bitumen. However,bitumen hardening agent YHJ-6 can increase the softening point of bitumen by over 60癈. Field test shows that this agent can effectively reduce the volume of bitumen invading into wellbore and enhance the sealing of leaking channel in bitumen environment.%Y油田开发过程中多口井钻遇Kazhdumi层超厚活跃沥青,沥青地层的非均质性、空间分布的不确定性给钻井施工带来极大挑战,钻井液污染、涌漏并发、硫化氢逸出等复杂情况导致多口井工程弃井,严重影响了Y油田的整体开发进度.根据已钻井实钻资料,从沥青层压力、连通通道、沥青特征及分布规律等方面研究了沥青层环境因素,分析了活跃沥青层处理难点.在此基础上,提出强化沥青层分布规律研究、优化调整井身结构和控压钻井技术配合沥青硬化处理等技术对策.分析认为,活跃沥青层地层压力当量钻井液密度1

  7. 龙门山-米仓山地区下组合地表沥青特征研究%Study on characteristics of Sinian-Silurian bitumen outcrops in the Longmenshan-Micangshan area, Southwest China

    Institute of Scientific and Technical Information of China (English)

    代寒松; 刘树根; 孙玮; 韩克猷; 罗志立; 谢志良; 黄耀综

    2009-01-01

    Through analyzing the development and distribution of the lower group's bitumen (Sinian-Silurian, containing Devonian) outcrops in the Longmenshan-Micangshan area, the authors find that the Devonian and Cambrian bitumen are concentrated in the Longmenshan area, but the Sinian bitumen mainly develops in Micangshan area. The bitumen in the Longmenshan area is oxidized bitumen with lower thermal maturity. In the Micangshan area, the bitumen is cracking bitumen with high thermal maturity. The difference in thermal maturity elucidates that the bitumen in the two areas has undergone different formation and evolution processes. The paleo-oil pools in the Longmenshan area were uplifted and oxidized to form bitumen before oil-cracking, and the bitumen has never undergone deep bury. The paleo-oil pools in the Micangshan area have undergone deep bury and oil cracked and uplifted to form the bitumen outcrops. By analyzing the Tianjingshan Devonian and Cambrian's bitumen and Sinian paleo-oil pool in the Micangshan area, the authors suggest that the paleo-oil pools of the lower group around the edge of Sichuan Basin are common and large scale. Combined with the analyzation of the drilling information, the authors suggest that there are good petroleum geological preserve conditions and good petroleum exploration prospects for the lower group (especially Sinian) in the front area (foreland basin area) of the Longmenshan and Micangshan areas.%通过对川西、川北龙门山-米仓山地区下组合(震旦系-志留系, 本文含泥盆系)地表沥青发育及分布的研究,发现龙门山构造带下组合沥青多集中在寒武系以及泥盆系内,而米仓山地区则多集中于震旦系.龙门山北段下组合沥青热演化程度低,属典型的氧化沥青;米仓山地区下组合(震旦系灯影组)沥青热演化程度高,属典型的热裂解沥青.表明两区下组合古油藏后期分别经历了隆升氧化降解、深埋裂解+隆升暴露两个全然不同的

  8. Analysis on the Reasonable Application of the Bitumen Mixed Station Burning System%探讨沥青拌和站燃烧系统的合理应用

    Institute of Scientific and Technical Information of China (English)

    黄志华

    2011-01-01

    This paper, through the introduction of the structure principle on the bitumen mixed station burning system, analyzes the elements of the bitumen from both physics and chemistry on burning quality; through a kind of economic analysis, the author sum sup bitumen mixed station burning system reasonal application and the effect of the oil burning system with non-standard method.%文中通过沥青拌和站燃烧系统的结构原理介绍,分析影响燃烧质量的物理和化学因素,并进行经济性分析,总结沥青拌和站燃烧系统的合理应用和非标准燃烧油对系统的影响。

  9. Reduction of light cycle oil in catalytic cracking of bitumen-derived crude HGOs through catalyst selection

    Energy Technology Data Exchange (ETDEWEB)

    Ding, Fuchen; Xu, Chunming [State Key Laboratory of Heavy Oil Processing, China University of Petroleum Beijing, 102200 (China); Ng, Siauw H. [National Centre for Upgrading Technology, 1 Oil Patch Drive, Suite A202, Devon, Alberta (Canada); Yui, Sok [Syncrude Research Centre, 9421-17 Avenue, Edmonton, Alberta (Canada)

    2007-09-15

    In an attempt to reduce the production of light cycle oil (LCO), a non-premium fluid catalytic cracking (FCC) product in North America, a large-pore catalyst containing rare-earth-exchanged Y (REY) zeolite, was used to crack two Canadian bitumen-derived crude heavy gas oils (HGOs) hydrotreated to different extents. For comparison, a regular equilibrium FCC catalyst with ultra-stable Y (USY) zeolite and a conventional western Canadian crude HGO were also included in the study. Cracking experiments were conducted in a fixed-bed microactivity test (MAT) reactor at 510 C, 30 s oil injection time, and varying catalyst-to-oil ratios for different conversions. The results show that pre-cracking of heavy molecules with wide-pore matrix, followed by zeolite cracking, enhanced conversion at the expense of light and heavy cycle oils at a constant catalyst-to-oil ratio, giving improved product selectivities (e.g., higher gasoline and lower dry gas, LCO, and coke yields, in general, at a given conversion). To systematically assess the benefits of employing the specialty catalyst over the regular catalyst in cracking Canadian HGOs, individual product yields were compared at common bases, including constant catalyst-to-oil ratios, conversions, and coke yields for three feeds, and at maximum gasoline yield for one feed. In most cases, the preferred choice of large-pore zeolite-rich catalyst over its counterpart was evident. The observed cracking phenomena were explained based on properties of catalysts and characterization data of feedstocks, including their hydrocarbon type analyses by gas chromatograph with a mass-selective detector (GC-MSD). (author)

  10. Carboxymethylated lignins with low surface tension toward low viscosity and highly stable emulsions of crude bitumen and refined oils.

    Science.gov (United States)

    Li, Shuai; Ogunkoya, Dolanimi; Fang, Tiegang; Willoughby, Julie; Rojas, Orlando J

    2016-11-15

    Kraft and organosolv lignins were subjected to carboxymethylation to produce fractions that were soluble in water, displayed a minimum surface tension as low as 34mN/m (25°C) and a critical aggregation concentration of ∼1.5wt%. The carboxymethylated lignins (CML), which were characterized in terms of their degree of substitution ((31)P NMR), elemental composition, and molecular weight (GPC), were found suitable in the formulation of emulsions with bitumens of ultra-high viscosity, such as those from the Canadian oil sands. Remarkably, the interfacial features of the CML enabled fuel emulsions that were synthesized in a very broad range of internal phase content (30-70%). Cryo-replica transmission electron microscopy, which was used here the first time to assess the morphology of the lignin-based emulsions, revealed the droplets of the emulsion stabilized with the modified lignin. The observed drop size (diametersoperations for power generation, which also take advantage of the high heating value of the emulsion components. The ability of CML to stabilize emulsions and to contribute in their combustion was tested with light fuels (kerosene, diesel, and jet fuel) after formulation of high internal phase systems (70% oil) that enabled operation of a fuel engine. A significant finding is that under certain conditions and compared to the respective pure fuel, combustion of the O/W emulsions stabilized by CML presented lower NOx and CO emissions and maintained a relatively high combustion efficiency. The results highlight the possibilities in high volume application for lignin biomacromolecules.

  11. Identification of organic sulfur compounds in coal bitumen obtained by different extraction techniques using comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometric detection.

    Science.gov (United States)

    Machado, Maria Elisabete; Fontanive, Fernando Cappelli; de Oliveira, José Vladimir; Caramão, Elina Bastos; Zini, Cláudia Alcaraz

    2011-11-01

    The determination of organic sulfur compounds (OSC) in coal is of great interest. Technically and operationally these compounds are not easily removed and promote corrosion of equipment. Environmentally, the burning of sulfur compounds leads to the emission of SO(x) gases, which are major contributors to acid rain. Health-wise, it is well known that these compounds have mutagenic and carcinogenic properties. Bitumen can be extracted from coal by different techniques, and use of gas chromatography coupled to mass spectrometric detection enables identification of compounds present in coal extracts. The OSC from three different bitumens were tentatively identified by use of three different extraction techniques: accelerated solvent extraction (ASE), ultrasonic extraction (UE), and supercritical-fluid extraction (SFE). Results obtained from one-dimensional gas chromatography (1D GC) coupled to quadrupole mass spectrometric detection (GC-qMS) and from two-dimensional gas chromatography with time-of-flight mass spectrometric detection (GC × GC-TOFMS) were compared. By use of 2D GC, a greater number of OSC were found in ASE bitumen than in SFE and UE bitumens. No OSC were identified with 1D GC-qMS, although some benzothiophenes and dibenzothiophenes were detected by use of EIM and SIM modes. GC × GC-TOFMS applied to investigation of OSC in bitumens resulted in analytical improvement, as more OSC classes and compounds were identified (thiols, sulfides, thiophenes, naphthothiophenes, benzothiophenes, and benzonaphthothiophenes). The roof-tile effect was observed for OSC and PAH in all bitumens. Several co-elutions among analytes and with matrix interferents were solved by use of GC × GC.

  12. Processing of tailings in Canadian oil sands industry

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Vast amounts of tailings are produced daily in bitumen extraction from the Athabasca oil sands. The coarse sand from the tailings stream is used to build dykes around the containment basin. The run-off slurry arrives at the water's edge in the tailings pond at a solids concentration of about 3%~8% by mass. Settling of the solids takes place "relatively fast", over several days, creating a "free water zone" that contains little solids. When the fine mineral solids concentration has reached about 15% by mass, the suspension develops non-Newtonian properties. After 2~3 years, the suspension concentration reaches a value of about 30% by mass at which the settling rate becomes extremely slow. Methods to handle the already created tailings ponds and new approaches to eliminate the creation of new ones will be discussed both from the industrial and fundamental prospective.

  13. Industrial Engineering

    DEFF Research Database (Denmark)

    Karlsson, Christer

    2015-01-01

    Industrial engineering is a discipline that is concerned with increasing the effectiveness of (primarily) manufacturing and (occasionally).......Industrial engineering is a discipline that is concerned with increasing the effectiveness of (primarily) manufacturing and (occasionally)....

  14. APPLICATION OF POLYETHYLENE FOAM PLASTIC SHEET IN WATERPROOF PROTECTION LAYER%聚乙烯泡沫塑料片材在防水保护层中的应用

    Institute of Scientific and Technical Information of China (English)

    吕文良

    2011-01-01

    新型聚乙烯泡沫塑料片材防水保护层区别于传统材料,既可满足图集和施工要求,又可大大降低成本.在某工程地下室防水保护层施工中采用了横向粘贴方法,并与其他保护层进行技术经济对比分析,提出了实践过程中需探讨的几个问题.%The waterproof protection layer made of new polyethylene foam plastic sheet is different from traditional material. It can not only satisfy the drawing collection and construction requirements, but also reduce the cost greatly. During the construction of basement waterproof layer in this engineering, transverse sticking method is adopted, technical and economic comparison and analysis are made with other protective layer. Finally, several problems which shall be discussed in practice are put forward.

  15. Application of High Pressure Jet Waterproof Curtain to Dock Cofferdam Project%高压旋喷止水帷幕在船坞围堰工程中的应用

    Institute of Scientific and Technical Information of China (English)

    陈东俊

    2013-01-01

    泉州船厂船坞围堰工程采用基床双排高喷连续墙和帷幕灌浆止水施工工艺。本文对主围堰基床采用2排高压旋喷桩、土石坝围堰采用1排高压旋喷桩的帷幕灌浆止水施工工艺进行简要叙述,对施工过程质量控制和成果、以及工程中出现的几个问题进行了分析。%Dock cofferdam phase-1 project in the ship-repairing zone of Quanzhou shipyard adopts the construction technologies of two-row high-pressure jet diaphragm wall supported on the bedding and curtain grouting waterproofing. The construction technology of curtain grouting waterproofing is briefly described in which two rows of high pressure jet grouting piles are used for main cofferdam bedding and one row for earth-and-rock dam cofferdam. In addition,the construction quality control,results and problems are analyzed in detail.

  16. Analysis of the Waterproofing Construction Weight Control of a Building Basement%某大厦地下室防水工程施工重量控制探讨分析

    Institute of Scientific and Technical Information of China (English)

    赵世益

    2013-01-01

      地下室墙板砼的浇筑质量优劣直接影响地下室的抗渗能力。超大超长地下室工程一旦产生渗漏,补修工作较困难。本文以某大厦地下室防水工程为例,详细阐述了如何做好地下室防水施工质量控制,希望能够给类似项目提供一些参考和建议。%The basement wal concrete pouring quality direct-ly affects the basement impermeability. Super-long oversized basement project once produced leakage, repair work is more difficult. This paper taking waterproof engineering in the base-ment of a building as the example, elaborates how to do qualit-y control of basement waterproof construction, hoping to be able to provide some reference and suggestions for similar pro-jects.

  17. 掺澎内传 PNC-803的防水混凝土在工程中的应用%On application of penetron admix PNC-803 waterproof concrete in projects

    Institute of Scientific and Technical Information of China (English)

    戴鲜英

    2015-01-01

    From the main features of materials,the paper illustrates the main features of penetron admix PNC-803,illustrates its waterproof mechanism,analyzes from the construction methods to economic effects according to engineering cases,and proves the waterproof effect and eco-nomic benefits have advantages,so as to extend its application in projects.%从材料的主要特性入手,阐述了澎内传PNC-803的主要特性,并进一步阐述了它的防水机理,然后附以工程实例,从施工方法到工程实体效果及经济效果进行了分析,证明在防水效果与经济效益方面确实有很大的优势,值得在工程项目中推广。

  18. Upstream petroleum industry flaring report for year ending December 31, 2000

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    A summary of flared volumes for the various oil and gas industry sectors including well tests, gas plants, gas gathering systems and batteries were presented in this report along with data on solution gas conserved, flared and vented in Alberta during 2000. This report is published in response to a commitment that the Alberta Energy and Utilities Board (EUB) made to ensure that flaring data is more accessible to the public and industry. The data included in the report is based on information submitted by companies. The information is tabulated and operators are ranked based on solution gas flared, solution gas vented, total gas produced, and total oil from crude oil and crude bitumen batteries. The report demonstrates the significant progress industry has made towards reducing solution flare gas and vent volumes in the province. The volume of solution gas flared and vented in Alberta decreased by 38 per cent in 2000. tabs.

  19. The preparation of waterproof luminous coated fabric and its properties%夜光涂层拒水织物的制备及其性能∗

    Institute of Scientific and Technical Information of China (English)

    吴仁芬; 葛明桥

    2015-01-01

    Have a water repellent finish on fabric by using fluoride from water and organic silicon from agent re-spectively setting the concentration at 30 g/L firstly,and then coated with luminous materials.Discuss the influ-ence of two different repellent finishing agents on the coated fabric’s fastness,luminous property,washing prop-erty,waterproof property,moisture permeation property,breathability property and surface morphology.The results show that luminous coated fabric has no water repellent finish was better at fastness luminance and moisture permeation than that has,but show worse at washing,water resistance and breathability.Luminous coated fabric that has be finshed by organic silicon from agent was better at fastness,luminance,washing and moisture permeation than that has be finshed by fluoride from water,but do worse at water resistance and breathability.%采用30 g/L的含氟和有机硅拒水剂分别对织物先进行拒水整理,再对拒水整理的织物进行夜光涂层,讨论两种不同拒水剂整理对夜光涂层织物的牢度性能、发光性能、耐水洗性能、防水透湿透气性能以及表面形态的影响。结果显示,未经拒水整理的夜光涂层织物的牢度、发光性能和透湿性比经拒水整理的要好,但是耐水洗、透气性和拒水性能要差;有机硅拒水剂整理的夜光涂层织物的牢度、发光性能、耐水洗性和透湿性均比含氟拒水剂整理的要好,但是透气性和拒水性均不如含氟拒水剂整理的夜光涂层织物。

  20. Incorporation of evaporator concentrates mock-up waste in Brazilian bitumen; Incorporacao de rejeitos simulados de concentrado de evaporador em betume nacional

    Energy Technology Data Exchange (ETDEWEB)

    Guzella, Marcia Flavia Righi; Silva, Tania Valeria da [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil)]. E-mail: mfrg@cdtn.br; silvatv@cdtn.br

    2005-07-01

    The solidification of radioactive liquid waste generated in nuclear power plants is required by the safety standards for the transportation, storage and deposition. CDTN/CNEN has carried out studies and experimental research aiming at the solidification and stabilization of radioactive wastes on different matrixes, such as cement and bitumen, therefore contributing to the improvement of treatment processes of low and intermediate radioactive waste from NPPs in Brazil. Experiments with solidification of waste in national bitumen, using NPP Angra 2 mock-up equipment, were carried out at a pilot-scale at CDTN. The evaporator concentrates were simulated by boric acid solution, salts and corrosion products. Caesium chloride was added to the solution for comparison with former experiments that evaluated the influence of boron and sodium in the matrix resistance to leaching. This word presents the results of the waste form characterization, obtained according to the softening point, flash point, resistance to leaching and penetration tests, plus thermodifferencial analysis. The experiments were performed according to either ABNT or ISO standards. The correct characterization of the waste form is important not only for a safe disposal but also to obtain the necessary safety level during the operation of the radioactive waste bituminization system. (author)

  1. Waterproofing with polymeric geo synthetic barriers (GBR-P) in the manual for the design, construction, management and maintenance of reservoirs; La impermeabilizacion con barreras geosinteticas polimericas (GBR-P) en el manual para el diseno, construccion, explotacion y mantenimiento de balsas

    Energy Technology Data Exchange (ETDEWEB)

    Blanco, M.; Cea, J. C.; Garcia, F.; Sanchez, F. J.; Castillo, F.; Mora, J.; Crespo, M. A.

    2010-07-01

    This article presents a part of Manual for the Design, Construction, Management and Maintenance of Reservoirs relative to waterproofing with Polymeric Geo synthetic Barriers (GBR-P). the nature materials of geo membranes is studied also theirs characteristics and specifications. (Author) 26 refs.

  2. SBS聚合物改性沥青的试验分析%Analysis on SBS Polymer Modified Bitumens

    Institute of Scientific and Technical Information of China (English)

    王忠伟; 杨云波; 吕晓虎

    2001-01-01

    By way of conventional tests (penetration, softening point, kinematic viscosity and Fraass breaking point) and dynamic mechanical analysis (DMA), physical properties as well as rheological properties of styrene-butadiene-styrene polymer (SBS) modified bitumens were studied. It is demonstrated that SBS modification causes a reduction in penetration at 25℃, an increase in softening point, a decrease of temperature susceptibility and an increase of kinematic viscosity. And SBS modification can effectively improve dynamic mechanical moduli and decrease phase angle at high temperatures, as well as reduce complex modulus and increase phase angle at low temperatures. In addition, both Fraass breaking point and glass transition temperature are lowered and low temperature (5℃) penetration is increased because of SBS modification.%用针入度、软化点、动粘度及脆点等常规试验方法与动态力学分析方法对Styrene-Butadiene-Styrene(苯乙烯-丁二烯-苯乙烯,简称SBS)聚合物改性沥青的物理特性及流变特性进行了研究.结果表明:SBS改性沥青在25℃时的针入度降低,软化点升高,温感性降低,动粘度也有所增加;SBS聚合物可有效地提高沥青粘合料在高温状态下的动态力学模量,降低相位角,而在低温状态下,SBS可以降低沥青粘合料的复合模量,增加相位角;此外,由于SBS的改性作用,导致沥青粘合料的脆点降低和低温(5℃)针入度的增加,SBS还可降低沥青的玻璃质过渡温度及温感性.

  3. Drilling rig noise assessment model vs. field monitoring results Imperial Oil Resources Cold Lake in-situ bitumen development area

    Energy Technology Data Exchange (ETDEWEB)

    Nixon, J.; MacDonald, T. [Imperial Oil Resources, Calgary, AB (Canada). Cold Lake Projects; Wright, R. [HFP Acoustical Consultants Corp., Calgary, AB (Canada)

    2007-07-01

    Oil and gas companies in Alberta must comply with the noise-emissions standards in the Noise Control Directive 038 of the Alberta Energy and Utilities Board (EUB). Licensees are responsible for risk when choosing sites and designing facilities. As such, they are required to work proactively to minimize potential impacts of new developments and must report existing noise levels. Imperial Oil Resources (IOR) Cold Lake operation is Canada's largest in-situ bitumen development facility which undergoes significant, ongoing development including the addition of up to 10 new multi-well production sites per year. In this study, the following equipment was assessed as a component of the noise impact assessment: the draw works, rotary table and drilling floor operations of a typical pad-drilling rig; the equipment skid for a typical diesel-electric rig, which includes two diesel engines, mud pumps and mud tanks; and, the equipment skid for a typical all electric rig, which includes only the mud pumps and mud tanks. Drilling rig noise measurements taken in 2006 at at two operating drill rigs were compared with 1996 drilling rig noise measurements. Sound level measurements at the U08 and U09 operating drill rigs were completed at distances of 5 m, 10 m, 20 m and 40 m and the measurements were used to calculate sound power levels for the drilling floor. A comparison of predicted sound levels to measured sound levels was then presented. Higher sound power level values in the 2006 measurements were due to equipment noise being centered at the drilling complex as opposed to the rig floor in 1996. The 2006 field monitoring data were then used by HFP Acoustical Consultants to update the predictive model which was provided to IOR in January 2006. The updated sound levels around the electric drilling rigs range from approximately 60 dBA near the edge of the lease up to 83 dBA near the noisiest equipment. It was concluded that the predictions from the model remain conservative and

  4. Industrial Waste

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund

    2011-01-01

    generation rates and material composition as well as determining factors are discussed in this chapter. Characterizing industrial waste is faced with the problem that often only a part of the waste is handled in the municipal waste system, where information is easily accessible. In addition part...... of the system industry has to inform at the planning stage and afterwards in yearly reports on their waste arising and how the waste is managed. If available such information is very helpful in obtaining information about that specific industry. However, in many countries there is very little information...... available about industrial waste – maybe also influenced by the policy of the industry as to making information publicly available. The data presented in this chapter is scarce and maybe not fully representative for the industrial sectors and hence should be used with caution only....

  5. Longshoring Industry

    Science.gov (United States)

    2001-01-01

    a)(1). (5) ANSI Z-89.1-1986, Personnel Protection-Protective Headwear for Industrial Workers-Requirements; IBR approved for 1917.93(b). (6) ANSI Z-41... Headwear for Industrial Workers-Requirements.” (c) Protective hats previously worn shall be cleaned and disinfected before issuance by the employer to... Headwear for Industrial Workers-Requirements; IBR approved for §1918.103(b). (6) ANSI Z-41-1991, American National Standard for Personal Protection

  6. Biotechnology Industry

    Science.gov (United States)

    2007-01-01

    Countries Growing GMO , 2007). Herbicide and insect resistance traits will continue to be pursued since 25% of food crops are lost each year to insect...daily lives from the clothing we wear, the fuel we use, the food we eat, and the medicines we take. From the earliest days, humans have used the...industry is very broad and includes health care, food , agriculture, industrial, and environmental industries. It is one of the fastest growing sciences

  7. 粉胶比对冷补沥青混合料性能的影响%Influence of Filler-Bitumen Ratio on Cold Patch Asphalt Mixture Performance

    Institute of Scientific and Technical Information of China (English)

    雷宗建; 黄国威; 张争奇

    2013-01-01

    The asphalt mortar which composed of reasonable filler-bitumen ratio has important influence on performances of asphalt mixture.Because the existence of thinner and additive,the properties,the best filler-bitumen ratio range and composition of cold patch asphalt mortar are different from general asphalt mortar.In order to put forward reasonable filler-bitumen ratio range of cold patch asphalt mixture,test methods are proposed to study on the influence law of filler-bitumen ratio on cold patch asphalt mixture by analyzing the high temperature stability,the forming strength and water stability of cold patch asphalt mixture in different filler-bitumen ratio.The test results show that reasonable filler-bitumen ratio range can make the best performance of cold patch asphalt mixture.Considering all kinds of road performances and economical efficiency requirements,it is suggested that the appropriate filler-bitumen ratio range of cold patch asphalt mixture in Guangdong Province is 1.0~1.3.But this rang can be reduced in drought or cold areas.%合理粉胶比的沥青胶浆是影响沥青混合料性能的重要因素.由于稀释剂和添加剂的存在,冷补沥青胶浆的性质和组成均与一般沥青胶浆不同,最佳粉胶比范围也有所差异.为了提出冷补沥青混合料合理的粉胶比范围,采用室内试验方法,通过分析冷补沥青混合料在不同粉胶比下的高温稳定性、成型强度和水稳定性等路用性能,研究粉胶比对冷补沥青混合料性能的影响规律.试验结果表明,合理的粉胶比范围能取得最佳的冷补沥青混合料性能,综合考虑各种路用性能和经济性的要求,建议广东地区冷补沥青混合料的粉胶比范围宜为1.0~1.3,但干旱或寒冷地区可以适当降低.

  8. 贵州晴隆锑矿古油藏沥青地球化学特征及成因%Geochemical Characteristics and Genesis of Bitumen in Paleo-oil Reservoir in Qinglong Antimony Deposit,Guizhou

    Institute of Scientific and Technical Information of China (English)

    王鹏鹏; 胡煜昭; 刘路; 张桂权

    2016-01-01

    There is rich organic inclusion in Qinglong antimony deposit. However,the source of this organic matter hasnˊt been found out. A paleo-oil reservoir was found in the periphery of Qinglong antimony mine. The bitumen in the paleo-oil reservoir mainly distrib-utes in the Emeishan basalt and the Dachang tuff of Upper Permian and the Maokou limestone of Middle Permian. Bitumen mainly oc-curs in crevices,pores and caves. In order to find the source and origin of the bitumen,the geochemical characteristics of the bitumen are tested and analyzed to provide a new basis for the exploration of Qinglong antimony deposit. The test results show that the average mass fraction of C,H,N and O in the bitumen is 86. 67%,3. 32%,0. 27% and 3. 52% separately,and the average atom ratio of H to C and O to C is 0. 46 and 0. 03 separately. The maturity of the bitumen is high,and its Ro is 1. 99% ~2. 30%. The measured value of carbon isotope of the bitumen is -27. 7‰~ -28. 8‰,and the average is -28. 1‰. Based on the study of the geochemical character-istics of the bitumen in the paleo-oil reservoir,it is held that the bitumen in the paleo-oil reservoir is mainly from Devonian hydrocarbon source rock. The bitumen is the pyrobitumen formed by thermal cracking due to the rise of the Paleo geothermal temperature in paleo-oil reservoir.%晴隆锑矿含有丰富的有机包裹体,然而这些有机质的来源一直未能查清。在晴隆锑矿外围找矿时发现一个古油藏。晴隆锑矿古油藏的沥青主要分布在上二叠统峨眉山玄武岩、上二叠统大厂层凝灰岩和中二叠统茅口组灰岩中,主要储集空间以裂缝、孔隙和溶洞为主。本文旨在通过对沥青地球化学特征进行分析测试来探讨沥青来源及成因,试图为晴隆锑矿找矿勘查提供新依据。测试结果表明:晴隆锑矿古油藏沥青C元素质量分数平均86.67%,H平均3.32%,N平均0.27%,O平均3.52%;H、C原子比平均0.46

  9. Foaming Chamber Design and Evaluation Based on the Analysis of Bitumen Foaming Essential Characteristics%沥青发泡本质特征解析下的腔体设计与评价

    Institute of Scientific and Technical Information of China (English)

    程海鹰; 张昱; 王安麟; 贺向新

    2012-01-01

    一定条件下沥青产生泡沫现象即为沥青发泡过程,是在特定容积的腔体中多物理场和流场耦合效应的结果.发泡性能受控制参数(压力、温度、流量),沥青物理性质(针入度、粘度)以及装备中关键部件结构参数(发泡腔体的结构形式、各喷嘴的尺寸、位置)的影响.为制备高品质(膨胀率大,半衰期长)泡沫沥青,必须遵循沥青发泡行为的本质特征,在多参数条件下对多相流的耦合场进行精确的过程控制.为此,以沥青发泡装置的关键部件为研究对象,总结国内外典型发泡腔的结构形式,并提出一种新型发泡腔结构形式.采用理论与试验并行的研究方法,分析沥青发泡的本质特征,并在强模糊性的多相流耦合场中探寻沥青发泡效果的评价指标,最终构建出沥青发泡本质特征与发泡腔体设计之间的映射规律.%The phenomenon of producing foams from bitumen under a certain condition is called bitumen foaming process, which is the coupling effect of the multi-physical field and the flow field in a certain volume chamber. The foaming performance is affected by the control parameters (pressure, temperature and flow), bitumen physical properties (needle penetration and viscosity) and the structure parameters of the key device parts (the foaming chamber structure type and the nozzle size and position). In order to make high quality foamed bitumen, the essential characteristics of bitumen foaming behavior should be followed. Thus the process control of the multiphase flow coupling field should be accurately executed. Then the bitumen foaming chamber, a key part of bitumen foaming device is deeply studied by analyzing the typical structure forms of foaming chamber world-widely. A novel structure form of foaming chamber is put forward. By utilizing the theoretical and experimental research and analyzing the essential characteristics of bitumen foaming, at the same time, the evaluation indexes

  10. Industrial Communications.

    Science.gov (United States)

    Lindsay, Dan

    Intended for seniors planning a career in industry as skilled laborers, this specialized course in Industrial Communications offers the student basic communications skills which he will need in his work and in his daily life. Since class activities center around short, factual oral reports, class size will be limited to 20, providing a maximum of…

  11. 煤田巷道防水侵水泥浆材的封堵试验%Sealing Test of Waterproof Cement Slurry Material in Coalfield Tunnel

    Institute of Scientific and Technical Information of China (English)

    李军; 姚平均; 陈道元; 张相乾; 曾艳军

    2015-01-01

    井下巷道掘进仍然是地下煤炭开采的主要方式,在开采过程中必然要穿过一些断裂地层带以及无胶结的松软地层及煤层顶板上的含水层。在掘进过程中,如果处理不当,地层中的水将沿着裂缝和采空塌陷区大量进入巷道内,造成严重的透水事故,使掘进工作无法顺利进行,严重时将导致井巷的报废,甚至造成重大的人身伤亡事故。针对传统水泥浆经水侵后不凝固或被流动水稀释而完全漏失,起不到应有的封堵固化作用等问题,研制出一种防水侵水泥浆封堵材料。该水泥浆与水按1∶1的比例掺混后仍具有凝结时间快、凝结强度高等特点,可在25℃以上的温度条件下使用。在某煤矿840 m井深、120 m3/h出水量情况下进行堵水作业试验,堵水效果良好,可在类似的条件下推广应用。%Underground tunnel excavation is still the main way of coal mining, some fracture stratum zones, non cemented soft strata and aquifer on coal seam roof must be encountered in the mining process.If there is misconduct in the excava-tion, a large amount of formation water may enter along the cracks and through mined-out subsidence areas into the tunnel to cause severe flooding accident, the excavation work will be severely affected, the well lane might be abandoned and even serious personal injury accident might happen.According to the disadvantages of traditional cement slurry, a kind of water-proof has been developed, which is mixed with water at ratio of 1∶1 with rapid condensation and high condensation strength and can be used at the temperature over 25℃.This cement slurry is tested in a mine water plugging operation, the well is 840m in height with outflow of 120m3/h, good water plugging effect is received.

  12. Industry honoured

    CERN Multimedia

    2008-01-01

    CERN has organised a day to thank industry for its exceptional contributions to the LHC project. Lucio Rossi addresses CERN’s industrial partners in the Main Auditorium.The LHC inauguration provided an opportunity for CERN to thank all those who have contributed to transforming this technological dream into reality. Industry has been a major player in this adventure. Over the last decade it has lent its support to CERN’s teams and participating institutes in developing, building and assembling the machine, its experiments and the computing infrastructure. CERN involved its industrial partners in the LHC inauguration by organising a special industry prize-giving day on 20 October. Over 70 firms accepted the invitation. The firms not only made fundamental contributions to the project, but some have also supported LHC events in 2008 and the inauguration ceremony through generous donations, which have been coordinated by Carmen Dell’Erba, who is responsible for secu...

  13. Effect of Photo-thermal Coupling on Performance of SBS Modified Bitumen%光热耦合对 SBS 改性沥青性能的影响

    Institute of Scientific and Technical Information of China (English)

    郭成洲; 丁卫青; 贾晓娟; 吴少鹏; 谢君; 余剑英

    2014-01-01

    The effects of ultraviolet and thermal coupling on performance of SBS modified bitumen were investigated by methods of photo-thermal coupling aging and thermo-oxidative aging.The re-sults show that photo-thermal coupling aging and thermo-oxidative aging accelerate the aging rate of SBS modified bitumen and change the morphology of SBS dispersed in bitumen phase,leading to transforming to homogeneous one phase.Meanwhile,increasing in aging,temperature and ultraviolet irradiation intensity can aggravate the aging of SBS modified bitumen.Ultraviolet and heat exhibit sig-nificant coupling effect,resulting in more severe aging of SBS modified bitumen in comparison with single thermo-oxidative aging.%采用光热耦合老化和热氧老化的方法研究了紫外光与热耦合对 SBS 改性沥青的影响。结果表明,光热耦合老化和热氧老化加速了 SBS 改性沥青的老化速率,并改变 SBS 在沥青中的分散相形貌,使其向一相化转变。同时,延长老化时间、提高老化温度和增大紫外光辐照强度均能使得 SBS 改性沥青的老化程度增加。光和热具有明显耦合效应,使得 SBS 改性沥青的老化程度比单独的热氧老化程度更为严重。

  14. A multiple lines of evidence approach for the ecological risk assessment of an accidental bitumen release from a steam assisted gravity drainage (SAGD) well in the Athabasca oil sands region.

    Science.gov (United States)

    Berger, Robert G; Aslund, Melissa Whitfield; Sanders, Greg; Charlebois, Michael; Knopper, Loren D; Bresee, Karl E

    2016-01-15

    To assess the ecological impacts of two independent accidental bitumen releases from two steam assisted gravity drainage (SAGD) wells in the Athabasca oil sands region, a multiple lines of evidence (LOE) approach was developed. Following the release in 2010, action was taken to minimize environmental impact, including the selective removal of the most highly impacted vegetation and the use of oil socks to minimize possible runoff. An ecological risk assessment (ERA) was then conducted based on reported concentrations of bitumen related contaminants in soil, vegetation, and water. Results of biological assessments conducted at the site were also included in the risk characterization. Overall, the conclusion of the ERA was that the likelihood of long-term adverse health effects to ecological receptors in the area was negligible. To provide evidence for this conclusion, a small mammal sampling plan targeting Southern red-back voles (Myodes gapperi) was carried out at two sites and two relevant reference areas. Voles were readily collected at all locations and no statistically significant differences in morphometric measurements (i.e., body mass, length, foot length, and adjusted liver weight) were found between animals collected from impact zones of varying levels of coverage. Additionally, no trends corresponding with bitumen coverage were observed with respect to metal body burden in voles for metals that were previously identified in the source bitumen. Hepatic ethoxyresorufin-O-deethylase (EROD) activity was statistically significantly elevated in voles collected from the high impact zones of sites compared to those collected from the reference areas, a finding that is indicative of continued exposure to contaminants. However, this increase in EROD was not correlated with any observable adverse population-wide biological outcomes. Therefore the biological sampling program supported the conclusion of the initial ERA and supported the hypothesis of no significant

  15. D/H isotope ratios of kerogen, bitumen, oil, and water in hydrous pyrolysis of source rocks containing kerogen types-I,-II,IIS, and -III

    Science.gov (United States)

    Schimmelmann, Arndt; Lewan, Michael D.; Wintsch, Robert P.

    1999-11-01

    Immature source rock chips containing different types of kerogen (I, II, IIS, III) were artificially matured in isotopically distinct waters by hydrous pyrolysis and by pyrolysis in supercritical water. Converging isotopic trends of inorganic (water) and organic (kerogen, bitumen, oil) hydrogen with increasing time and temperature document that water-derived hydrogen is added to or exchanged with organic hydrogen, or both, during chemical reactions that take place during thermal maturation. Isotopic mass-balance calculations show that, depending on temperature (310-381°C), time (12-144 h), and source rock type, between ca. 45 and 79% of carbon-bound hydrogen in kerogen is derived from water. Estimates for bitumen and oil range slightly lower, with oil-hydrogen being least affected by water-derived hydrogen. Comparative hydrous pyrolyses of immature source rocks at 330°C for 72 h show that hydrogen in kerogen, bitumen, and expelled oil/wax ranks from most to least isotopically influenced by water-derived hydrogen in the order IIS > II ≈ III > I. Pyrolysis of source rock containing type II kerogen in supercritical water at 381°C for 12 h yields isotopic results that are similar to those from hydrous pyrolysis at 350°C for 72 h, or 330°C for 144 h. Bulk hydrogen in kerogen contains several percent of isotopically labile hydrogen that exchanges fast and reversibly with hydrogen in water vapor at 115°C. The isotopic equilibration of labile hydrogen in kerogen with isotopic standard water vapors significantly reduces the analytical uncertainty of D/H ratios when compared with simple D/H determination of bulk hydrogen in kerogen. If extrapolation of our results from hydrous pyrolysis is permitted to natural thermal maturation at lower temperatures, we suggest that organic D/H ratios of fossil fuels in contact with formation waters are typically altered during chemical reactions, but that D/H ratios of generated hydrocarbons are subsequently little or not affected

  16. D/H isotope ratios of kerogen, bitumen, oil, and water in hydrous pyrolysis of source rocks containing kerogen types I, II, IIS, and III

    Science.gov (United States)

    Schimmelmann, A.; Lewan, M.D.; Wintsch, R.P.

    1999-01-01

    Immature source rock chips containing different types of kerogen (I, II, IIS, III) were artificially matured in isotopically distinct waters by hydrous pyrolysis and by pyrolysis in supercritical water. Converging isotopic trends of inorganic (water) and organic (kerogen, bitumen, oil) hydrogen with increasing time and temperature document that water-derived hydrogen is added to or exchanged with organic hydrogen, or both, during chemical reactions that take place during thermal maturation. Isotopic mass-balance calculations show that, depending on temperature (310-381??C), time (12-144 h), and source rock type, between ca. 45 and 79% of carbon-bound hydrogen in kerogen is derived from water. Estimates for bitumen and oil range slightly lower, with oil-hydrogen being least affected by water-derived hydrogen. Comparative hydrous pyrolyses of immature source rocks at 330??C for 72 h show that hydrogen in kerogen, bitumen, and expelled oil/wax ranks from most to least isotopically influenced by water-derived hydrogen in the order IIS > II ~ III > I. Pyrolysis of source rock containing type II kerogen in supercritical water at 381 ??C for 12 h yields isotopic results that are similar to those from hydrous pyrolysis at 350??C for 72 h, or 330??C for 144 h. Bulk hydrogen in kerogen contains several percent of isotopically labile hydrogen that exchanges fast and reversibly with hydrogen in water vapor at 115??C. The isotopic equilibration of labile hydrogen in kerogen with isotopic standard water vapors significantly reduces the analytical uncertainty of D/H ratios when compared with simple D/H determination of bulk hydrogen in kerogen. If extrapolation of our results from hydrous pyrolysis is permitted to natural thermal maturation at lower temperatures, we suggest that organic D/H ratios of fossil fuels in contact with formation waters are typically altered during chemical reactions, but that D/H ratios of generated hydrocarbons are subsequently little or not affected

  17. Disccusion on Waterproofing and Draining Design of Railway Tunnel in Severe Cold and Cold Regions%寒冷及严寒地区铁路隧道防排水设计探讨

    Institute of Scientific and Technical Information of China (English)

    朱国伟

    2013-01-01

    研究目的:我国寒冷及严寒地区已建成的隧道存在渗漏水影响造成的仰拱翻浆冒泥、衬砌开裂、底鼓甚至侵限等一系列病害.通过对东北地区既有铁路隧道防排水技术现状及运营维护状况进行的调研,分析严寒及寒冷地区防排水设计、施工和运营中存在的问题,指出防排水设计技术需要不断提升水平,从而简化运营维护及保证行车安全.研究结论:结合拟建及在建隧道的防排水设计、施工中存在的实际问题以及新工艺、新材料的实用,总结出保温水沟、中心深埋水沟、防寒泄水洞以及保温盲沟等保温排水的设计应优先采用新型保温材料,减少施工工序以及减低施工难度,以充分解决寒冷及严寒地区隧道的冻害问题.%Research purposes; The water leakage has happened to the tunnel in the severe cold and cold regions, resulting in a series of the disasters, such as rising soil of the inverted arch, lining cracking, heaving floor and even invasion of limitation. Based on investigation and analysis of the current situation of the waterproofing and draining technologies and current maintenance situation of the existing the railway tunnels in the Northeast China, the analysis of the problems in design, construction and maintenance of the waterproofing and draining facilities was made and it was proposed that the waterproofing and draining technologies could be continuously improved to simplify the operation and maintenance and ensure the traffic safety. Research conclusions; Combining with the real problems in design and construction of the waterproofing and draining facilities for the planned tunnel and the tunnel under construction and the application of the new technologies and new materials, it is proposed that the new type heat insulating material should be used for the heat insulating ditch, central deep buried ditch, cold - proof weepage hole and heat insulating blind ditch to reduce

  18. 防水剂对受荷开裂下PVA-SHCC渗透性能的影响%Influences by waterproofing agent on impermeability of strain hardening cement-based composite on the loading state

    Institute of Scientific and Technical Information of China (English)

    高嵩; 李秋义; 金祖权; 吴本清

    2014-01-01

    受荷载时产生的多重裂缝是SHCC的薄弱部位和外界介质侵入的通路,会加速了结构的耐久性劣化。而对SHCC进行防水处理是提高耐久性的有效措施,研究了防水剂对PVA-SHCC试件抗氯离子渗透性能和受荷开裂下的试件水毛细吸收系数的影响。试验结果表明:对PVA-SHCC进行防水处理可以显著降低试件中的氯离子扩散系数,外涂防水剂试件的氯离子扩散系数只是不掺防水剂的试样的8%到20%,内掺防水剂的试件的氯离子扩散系数只是不掺防水剂试件的60%左右。试件在受荷开裂下的抗渗性比未施加应力试件的抗渗性差,采取防水处理可以有效提高受荷试件的抗渗性能,外涂和内掺处理方式对提高抗渗的效果相差不大。SHCC渗透性能的研究可以为SHCC结构耐久性研究和服役寿命预测提供重要参考。%Cracks in strain hardening cement-based composite(SHCC)structures caused by mechanical load are the weakness under ser-vice condition,and they provide pathways for access of water and solution containing chloride into strain hardening cement-based com-posite. In the present paper,the influences by waterproofing agent to chloride resisting performances and capillary suction coefficient of specimen on the loading state are experimental studied.The experimental results indicate that water proof treatment can significantly reduce the chloride diffusion coefficient.The chloride diffusion coefficient of the specimen by external application of waterproofing agent is only between 8%and 20%of normal strain hardening cement-based composite specimen. And which of blended with waterproofing agent is ap-proximately 60%of normal strain hardening cement-based composite.Furthermore,the impermeability of strain hardening cement-based composite specimen under the loading state is much worse than that of unloaded strain hardening cement-based composite specimen.The water proofing treatments are

  19. Composite nanofiber membrane based on electrospun PVDF/PVDF-HFP and evaluation for waterproof & breathable properties%电纺PVDF/PVDF-HFP复合纳米纤维膜及其防水透湿性能评价

    Institute of Scientific and Technical Information of China (English)

    刘延波; 马营; 孙健; 宋学礼; 陈国贵

    2014-01-01

    通过静电纺丝技术制备PVDF/PVDF-HFP复合纳米纤维膜,然后对其进行热压处理,采用FE-SEM对其形貌进行表征,并对其力学性能和防水透湿性能进行评价。结果表明:PVDF和PVDF-HFP溶液的最佳纺丝质量分数分别为9%和12%;热压处理后PVDF/PVDF-HFP复合纳米纤维膜具有优异的防水透湿性能,当复合纳米纤维膜中PVDF与PVDF-HFP的质量比为2∶1时,其耐静水压达到7220 mmH2O,透湿量达到7300 g/(m2·24 h)。%Poly(vinylidene fluoride)/Poly(vinylidene fluoride-co-hexafluoropropylene) composite nanofiber membrane was prepared by electrospinning, followed by thermal calendaring process. The morphology of the membrane was characterized by FE-SEM, and the mechanical property and waterproof-breathable property were evaluated. The results indicate that the best solution concentration of PVDF and PVDF-HFP are 9% and 12% respectively. PVDF/PVDF-HFP composite nanofiber membrane possesses excellent waterproof-breathable property after thermal calendaring. When the mass ratio of PVDF and PVDF-HFP is 2∶1 in the composite nanofiber membrane, the hydrohead of membrane achieves to 7 220 mmH2O and water vapor transmission rate amounts to 7 600 g/(cm2· 24 h).

  20. Industrial vision

    DEFF Research Database (Denmark)

    Knudsen, Ole

    1998-01-01

    This dissertation is concerned with the introduction of vision-based application s in the ship building industry. The industrial research project is divided into a natural seq uence of developments, from basic theoretical projective image generation via CAD and subpixel analysis to a description...... of the experienc e achieved during the project is provided. The project is industrial oriented. An essential part of the project has been focused on the possi-bilities for immediate use of the results. A full implemented application doing vision ba sed positioning is described. It is concluded that visionbased...

  1. Industrial pioneers

    NARCIS (Netherlands)

    Wassink, J.

    2014-01-01

    With their knowledge of metallurgy, mechanics and thermodynamics, mechanical engineers had to give shape to the industrial revolution in the Netherlands 150 years ago. This revolution only slowly gathered momentum, however, especially in comparison with England.

  2. Underwater behaviour of bitumen coated radioactive wastes: experimental validation of the Colonbo degradation model; Comportement sous eau des dechets radioactifs bitumes: validation experimentale du modele de degradation Colonbo

    Energy Technology Data Exchange (ETDEWEB)

    Gwinner, B

    2004-03-01

    In the release scenario considered for geologic repository, water is thought to be the main aggressive agent with regards to bituminized radioactive waste (composed in general of 60 weight % of bitumen, 40% of soluble/insoluble salts and a few ppm of radionuclides). Since liquid water can diffuse in pure bitumen, leaching of bituminized waste results in the dissolution of the most soluble salts and leads to the development of a more or less concentrated saline solution-filled pore structure (called permeable layer). In consequence of the generation of a porous layer in the bituminized waste, leaching of salts and radionuclides can then take place. Research performed at the Atomic Energy Commission (CEA) aims therefore at understanding the consequences of ground-water immersion on the transport properties and radionuclides leaching of bituminized waste materials. To this end, a constitutive model (called COLONBO) which describes mathematically the leaching of bituminized waste has been developed. The COLONBO model is based on the following assumptions: 1. Water and dissolved salts migrate in the permeable layer according to Fick's first law. The diffusion of water and salts are quantified by effective diffusion coefficients which are unknown. 2. The mechanical properties of the bitumen matrix are not considered during leaching (free swelling). Up to now, the COLONBO model has been used only to model experimental water uptake and salt leach curves, leading (theoretical) estimates of the effective diffusion coefficients of water and salts in the permeable layer. The aim of this work was to validate experimentally the numerical results obtained with the COLONBO model. First, the correspondence between experimental and simulated water uptake and salt leach rates obtained on various bituminized waste materials is checked, leading estimates of the effective diffusion coefficients of water and salts in the permeable layer. Second, the evolution of the thickness and of

  3. Prediction on the softening point of bitumen in producing by using SVR%沥青生产过程中软化点的SVR预测

    Institute of Scientific and Technical Information of China (English)

    蔡从中; 王桂莲; 裴军芳; 朱星键

    2011-01-01

    According to an experimental dataset on the softening points of 30 bitumen samples under different resistances and temperatures,the support vector regression(SVR) approach combined with particle swarm optimization(PSO) for its parameter optimization is proposed to conduct leave-one-out cross validation(LOOCV) for modeling and predicting the softening point of bitumen,and its prediction result is compared with that of multivariate linear regression(MLR).The maximum error 2.1 ℃ predicted by SVR is much less than 7.9 ℃ which is calculated by MLR modeling.The statistical results reveal that the root mean square error(RMSE=0.75 ℃),mean absolute error(MAE=0.32 ℃) and mean absolute percentage error(MAPE=0.28%) achieved by SVR-LOOCV are all less than those(RMSE=3.3 ℃,MAE=2.6 ℃ and MAPE=2.34%) calculated via MLR model.This study suggests that the softening point of bitumen can be forecasted timely by SVR to provide an accurate guidance for producing of high-quality bitumen.%根据30组不同电阻和温度下的沥青软化点的实测数据集,应用基于粒子群算法(PSO)寻优的支持向量回归(SVR)方法,并结合留一交叉验证(LOOCV)法对沥青软化点进行了建模和预测研究,将其预测结果与多元线性回归(MLR)模型的计算结果进行了比较。SVR-LOOCV预测的最大误差为2.1℃,远比MLR模型计算的最大误差7.9℃要小得多。统计结果表明:基于SVR-LOOCV预测结果的均方根误差(RMSE=0.75℃)、平均绝对误差(MAE=0.32℃)和平均绝对百分误差(MAPE=0.28%)相应也比MLR回归模型的预测结果(RMSE=3.3℃,MAE=2.6℃和MAPE=2.34%)要小。因此,应用SVR实时预测沥青产品的软化点,可为生产优质沥青提供准确的科学指导。

  4. Evaluation of pulp and mortar to pack bitumen radioactive waste; Avaliacao de pastas e argamassas para o embalado de rejeitos radioativos betuminizados

    Energy Technology Data Exchange (ETDEWEB)

    Gregorio, Marina da S.; Vieira, Vanessa M.; Tello, Cledola C.O., E-mail: msg@cdtn.br, E-mail: vanessamotavieira@gmail.com, E-mail: tellocc@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2013-07-01

    According to international experience, for the deposition of cement in surface repository, is necessary the use of cement mortar pastes to immobilize the product. Determining the most efficient folder or for the packed mortar, as well as its ideal formulation, is the goal of this study. To do various experiments with samples of cement paste and mortar, with presence of fluxing and / or clay were performed. Viscosity, density, setting time and compressive strength were evaluated. This study will be presented only the results found in testing of compressive strength to be an essential parameter in the transport, storage and disposal of the product. From the results found will be selected the best formulations for use in packed bitumen tailings from the National Radioactive Waste Repository.

  5. Electronics Industry

    Science.gov (United States)

    2006-01-01

    companies to begin listing stock options as expenses on financial reports (Chappell, 2005). The industry had used stock options extensively to help... stock options (Chappell, 2005). Industry representatives interviewed by the group argued against the requirement since they predict U.S. companies...may be less inclined now to offer stock options , and subsequently talent may be lost to aggressive foreign competition (Anonymous interviews, 2006

  6. Chabazite-Clay Composite for Bitumen Upgrading%菱沸石-粘土复合物在沥青精制中的应用

    Institute of Scientific and Technical Information of China (English)

    卞俊杰; Steven M. KUZNICKI; William C. McCAFFREY; Andree KOENIG; Christopher C. H. LIN

    2008-01-01

    The Alberta oilsands resource is increasingly recognized as a strategic source for North American energy supply. We synthesized a novel chabazite-clay composite for improved oilsand bitumen upgrading by growing chabazite on kaolin under alkaline conditions. XRD, SEM, TEM, N2 physical adsorption, and XPS surface elemental analysis confirmed that the chabazite-clay composite has a unique exterior surface, accessible to large hydrocarbon molecules, that could moderate bitumen upgrading reaction with high performance contaminant (sulfur, nitrogen, nickel, and vanadium) removal.%阿尔伯塔的油砂资源日益成为北美重要的战略性能源供给. 本实验室通过采用碱性条件下在高岭土表面上组装菱沸石的方法,合成了新型的菱沸石-粘土复合材料,并证明此复合材料是比菱沸石更好的油砂沥青精制剂. XRD, SEM, TEM, N2物理吸附和XPS表面元素分析结果表明,菱沸石-粘土复合材料具有大体积烃类分子可及的独特的外表面,该复合材料不仅可降低油砂沥青的裂解反应温度,同时还可大幅度脱除沥青中的硫、氮、镍和钒等杂质.

  7. Characterizing baseline concentrations, proportions, and processes controlling deposition of river-transported bitumen-associated polycyclic aromatic compounds at a floodplain lake (Slave River Delta, Northwest Territories, Canada).

    Science.gov (United States)

    Elmes, Matthew C; Wiklund, Johan A; Van Opstal, Stacey R; Wolfe, Brent B; Hall, Roland I

    2016-05-01

    Inadequate knowledge of baseline conditions challenges ability for monitoring programs to detect pollution in rivers, especially where there are natural sources of contaminants. Here, we use paleolimnological data from a flood-prone lake ("SD2", informal name) in the Slave River Delta (SRD, Canada), ∼ 500 km downstream of the Alberta oil sands development and the bitumen-rich McMurray Formation to identify baseline concentrations and proportions of "river-transported bitumen-associated indicator polycyclic aromatic compounds" (indicator PACs; Hall et al. 2012) and processes responsible for their deposition. Results show that indicator PACs are deposited in SD2 by Slave River floodwaters in concentrations that are 45 % lower than those in sediments of "PAD31compounds", a lake upstream in the Athabasca Delta that receives Athabasca River floodwaters. Lower concentrations at SD2 are likely a consequence of sediment retention upstream as well as dilution by sediment influx from the Peace River. In addition, relations with organic matter content reveal that flood events dilute concentrations of indicator PACs in SD2 because the lake receives high-energy floods and the lake sediments are predominantly inorganic. This contrasts with PAD31 where floodwaters increase indicator PAC concentrations in the lake sediments, and concentrations are diluted during low flood influence intervals due to increased deposition of lacustrine organic matter. Results also show no significant differences in concentrations and proportions of indicator PACs between pre- (1967) and post- (1980s and 1990 s) oil sands development high flood influence intervals (t = 1.188, P = 0.279, d.f. = 6.136), signifying that they are delivered to the SRD by natural processes. Although we cannot assess potential changes in indicator PACs during the past decade, baseline concentrations and proportions can be used to enhance ongoing monitoring efforts.

  8. Industrial diamond

    Science.gov (United States)

    Olson, D.W.

    2013-01-01

    Estimated 2012 world production of natural and synthetic industrial diamond was about 4.45 billion carats. During 2012, natural industrial diamonds were produced in at least 20 countries, and synthetic industrial diamond was produced in at least 12 countries. About 99 percent of the combined natural and synthetic global output was produced in Belarus, China, Ireland, Japan, Russia, South Africa and the United States. During 2012, China was the world’s leading producer of synthetic industrial diamond followed by the United States and Russia. In 2012, the two U.S. synthetic producers, one in Pennsylvania and the other in Ohio, had an estimated output of 103 million carats, valued at about $70.6 million. This was an estimated 43.7 million carats of synthetic diamond bort, grit, and dust and powder with a value of $14.5 million combined with an estimated 59.7 million carats of synthetic diamond stone with a value of $56.1 million. Also in 2012, nine U.S. firms manufactured polycrystalline diamond (PCD) from synthetic diamond grit and powder. The United States government does not collect or maintain data for either domestic PCD producers or domestic chemical vapor deposition (CVD) diamond producers for quantity or value of annual production. Current trade and consumption quantity data are not available for PCD or for CVD diamond. For these reasons, PCD and CVD diamond are not included in the industrial diamond quantitative data reported here.

  9. Investigation to Identify Performance Criteria and Test Methods for Evaluating Single-Ply Roofing Systems.

    Science.gov (United States)

    1987-03-01

    Waterproof Coverings of Styrene-Butadiene-Styrene ( SBS ) Elastomer Bitumen (UEAtc, August 1984). MRCA MB-30, Recommended Performance Criteria for Modified...MOATs) are Nos. 30 and 31 for modified bitumen roofing. No. 30 covers atactic polypropylene (APP) and No. 31 discusses styrene- butadiene styrene ( SBS ...involve modified bitumen roofing products (both SBS and APP). NRCC plans to evaluate the following criteria: 1. Puncture resistance (membrane and systems

  10. Upstream petroleum industry flaring and venting report : Industry performance for year ending December 31, 2002

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-09-01

    The largest source of flaring and venting in Alberta is solution gas, accounting for 66 per cent of total emissions in 2002. A summary of flared and vented volumes for the different oil and gas industry sources, such as well tests, gas plants, gas gathering systems, transmission lines, and batteries was presented in this report. It also contained detailed information on solution gas conserved, flared, and vented during 2002. Rankings of companies was established based on solution gas flared plus vented, solution gas flared, and solution gas vented, from crude oil and bitumen batteries. The ranking is provincial and also by the Energy Utilities Board (EUB) Field Centre area. The data used in the preparation of this report is submitted by companies. Considerable progress was made in the reduction of flaring and venting volumes for all upstream oil and gas sources, as demonstrated by the data. A reduction of 62 per cent from the 1996 flaring baseline was achieved. A reduction of 29 per cent was achieved for the venting of solution gas from the 2000 venting baseline. There was a 44 per cent reduction in the volume of solution gas flared and vented from the 1996 volume. tabs., figs.

  11. Hospitality Industry

    Directory of Open Access Journals (Sweden)

    Marian Ionel

    2017-03-01

    Full Text Available Development of accommodation, as basic services offered to tourists, led to the creation of a genuine hospitality industry. Currently, the hospitality industry is no longer just the accommodation service itself but also requires an atmosphere that ensures leisure tourists in the hotel. Thus, hospitable unit manager offers its service in addition to accommodation and catering services, leisure services, treatment services, business services required.. The existence of factors such as revenue growth, increasing leisure time, the development of transport services, the emergence of new tourist attractions have caused increasing international flows of tourists, with consequent development of units hospitable, and therefore a strong hospitality industry. In Romania, after 1990, the tourism sector experienced a true expansion, both through the development of the hotel sector, but also by developing rural hospitality units.

  12. Industrial Networks

    DEFF Research Database (Denmark)

    Karlsson, Christer

    2015-01-01

    the focus of operations management from managing the own organization to continuously developing and managing a network of external and internal resources forming a production system. This perspective may be called managing an “extraprise” rather than an “enterprise.” It should be noted that “an industrial...... network” should not be seen as an organizational form but as a perspective that can be used to enrich one's understanding of organizations. The industrial network perspective has three basic building blocks: actors, resources, and activities. The three building blocks and their relations constitute...

  13. Fiabilidad industrial

    OpenAIRE

    Griful Ponsati, Eulàlia

    2001-01-01

    El presente libro ha sido escrito y editado para los estudios de segundo ciclo de Ingeniería de Organización Industrial que se imparten en la ETSEIT de la UPC. La materia de fiabilidad que se imparte en este texto es una introducción a las técnicas estadísticas para resolver cuestiones de fiabilidad industrial. Se estudian distintos modelos probabilísticos del tiempo de vida y se presentan distintas formas de recabar información y de estimar, en cada caso, la fiabilidad de los componentes y s...

  14. Fermentation Industry.

    Science.gov (United States)

    Grady, C. P. L., Jr.; Grady, J. K.

    1978-01-01

    Presents a literature review of wastes from the fermentation industry, covering publications of 1976-77. This review focuses on: (1) alcoholic beverage production; (2) pharmaceuticals and biochemicals production; and (3) biomass production. A list of 62 references is also presented. (HM)

  15. Shifting Industries

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Coastal city Beihai aspires to revive its economy by developing its electronic information industry Against a clear sky,the blue sea hums along a shining beach,with villas in the distance.This beautiful scene is in Beihai,in south China’s Guangxi Zhuang Autonomous Region.

  16. Variation of chemical composition of thermal bitumen during Huadian oil shale pyrolysis%桦甸油页岩热解过程中热沥青的组成变化规律

    Institute of Scientific and Technical Information of China (English)

    畅志兵; 初茉; 张超; 白书霞; 林浩

    2016-01-01

    将桦甸油页岩分别在300、350、400、450、500和550℃热解得到半焦,对半焦进行逐级抽提和酸洗,得到自由沥青、碳酸盐束缚沥青和硅酸盐束缚沥青,采用柱层析、FT-IR和GC-MS表征不同沥青的化学组成和结构特征,探讨沥青的化学组成变化及与矿物质的相互作用。结果表明,沥青总产率先增大后减小并在400℃取得最大值4.63%,400-450℃大量沥青分解生成页岩油,使沥青产率降至0.98%。350-450℃自由沥青主要发生羧酸脱羧、酯基分解和长链烷烃裂解反应,使羧酸和酯类化合物含量降低、烷烃碳链长度缩短。干酪根分解生成的羧酸与碳酸盐反应生成羧酸盐,使400℃碳酸盐束缚沥青中羧酸含量达78.82%;含氧化合物可与黏土矿物结合,且烷烃可进入蒙脱石层间,使400℃硅酸盐束缚沥青中含氧化合物和烷烃各占80.79%和19.21%。%The variation of chemical composition of thermal bitumen during Huadian oil shale pyrolysis was studied. Spent shale samples obtained by retorting oil shale at 300-550℃ were subjected to sequential Soxhlet extraction-acid pickling-Soxhlet extraction procedures to obtain free bitumen ( FB ) , bitumen bound with carbonates ( BB-1 ) and bitumen bound with silicates ( BB-2 ) . The bitumen samples were characterized by liquid chromatography fractionation, FT-IR and GC-MS. The results show that the total bitumen yield first increases and then decreases with increasing temperature from 300 to 550℃, and reached the maximum value of 4 . 63% at 400℃. Especially, the intense vaporization and decomposition of bitumen occurring at 400-450 ℃ causes a dramatic decrease in bitumen yield from 4. 63% to 0. 98%. Decarboxylation of aliphatic acids, decomposition of esters and cracking of long-chain alkanes take place at 350-450 ℃, which decreases the contents of acids and esters in FB and shortens the chain length of alkanes. The carboxylic acids derived from kerogen

  17. 绿色环保型高性能沥青混凝土排水铺装用防水材料应用研究%Application research on the green high-performance waterproof material for asphalt concrete drainage pavement

    Institute of Scientific and Technical Information of China (English)

    杨冲; 冉千平; 孙德文

    2013-01-01

    This article introduces a high-performance resin-based waterproof materials for drainage pavement with asphalt con-crete,and its performance advantages as waterproof layer. Its excellent performance includes:4.07 MPa of adhesion to asphalt concrete base surface, 3.51 MPa of adhesion to the concrete surface, low temperature flexibility of up to -20℃,no impervious after 24 h under 1.8 MPa pressure, excellent abrasion resistance. It can not only achieve good compatibility between the waterproof layer with the substrate, but also avoid the economic losses due to performance deficiencies in the waterproof layer exist in the real project.%介绍了一种沥青混凝土排水铺装用的高性能树脂型防水材料以及其作为防水层所具备的性能优势.其优异性能表现在与沥青混凝土基面的粘结强度达4.07 MPa,与混凝土基面的粘结强度达3.51 MPa,低温弯折性可达-20℃,同时在1.8 MPa的压力下24 h不透水,耐磨性优良.不仅能够实现防水层与基层之间良好的相容性,同时避免了在实际工程中存在的因防水层性能缺陷带来的经济损失.

  18. In vitro studies of the genotoxic effects of bitumen and coal-tar fume condensates: comparison of data obtained by mutagenicity testing and DNA adduct analysis by 32P-postlabelling.

    Science.gov (United States)

    De Méo, M; Genevois, C; Brandt, H; Laget, M; Bartsch, H; Castegnaro, M

    1996-08-14

    Bitumens contain traces of polycyclic aromatic compounds (PACs), a part of which will end up in the fumes emitted during hot handling of bitumen-containing products, e.g. during roadpaving. Although exposure of workers to these fumes is low, it might lead to health problems. Studies on bitumen fume condensates (BFCs) showed weak to moderate mutagenic activities, but studies on DNA adduct formation have not been reported. Therefore, a study was initiated in which fumes were generated from two road grade bitumens, in such a way that they were representative of the fumes produced in the field. The combined vapour/particulates were tested in vitro for their ability to produce DNA adducts and in modified Ames mutation assays, using a number of different strains. An attempt was made to relate the results to chemical data, such as the content of a number of individual polycyclic aromatic hydrocarbons (PAHs) and with a measure for the total PAC content. As a reference material fume condensate from coal-tar (coal-tar pitch volatiles; CTPV) were subjected to the same tests. All fume condensates tested were mutagenic to all strains and induced the formation of DNA adducts. The patterns of DNA adducts, obtained by 32P-postlabelling, arising from the BFCs were qualitatively different from the patterns of adducts obtained from the CTPVs, implying qualitative differences in the nature of the compounds responsible for the formation of these adducts. This is corroborated by the observation that for BFCs quantitative adduct levels are higher than would be expected based on the PAH content. These data thus indicate that the PAHs analysed are not the sole components responsible for adduct formation from BFCs, but that an important contribution comes from other (hetero- and/or substituted-) PACs.

  19. AnaIysis of performance and microstructure of waterproof and anti-crack phosphorus sIag mortar%磷渣砂防水抗裂砂浆的性能及显微结构分析

    Institute of Scientific and Technical Information of China (English)

    杨林; 刘亚明; 张冰; 左健; 周坤; 刘秀伟

    2015-01-01

    Performance and micro-structure of waterproof and anti-crack phosphorus slag mortar were explored,and the mineral composition,microstructure and pore size distribution of phosphorus slag mortarˊs hardening body were studied by the means of XRD, SEM and Physical Adsorption Instrument. The results show that with the content of waterproof agent increasing,water retention,the orig-inal tensile bond strength and soaking the tensile bond strength increase and ratio of compressive strength to flexural,compressive strength and water permeability reduce. With the content of redispersion emulsoid powder decreasing,compressive strength,soaking the tensile bond strength and ratio of compressive strength to flexural reduce,and water retention,water permeability,and original tensile bond strength increase. The main mineral composition of hydration and hardening of the mortar are silica,hydrated calcium silicate,cal-cium hydroxide and wollastonite. With hydration time extending,active material of fly ash and phosphorus slag powder react with calci-um hydroxide to generate massive hydrated calcium silicate gel. These hydrated calcium silicate fill the gap between fine aggregate,thus the specific surface area and bore diameter of the slurry decrease,and the performance of phosphorus slag mortar(smaple M3)meet re-spectively the technical requirements of M10 waterproof mortar in JG/T 230—2007 and the anti-crack mortar in JGJ 253—2011.%考察了常用添加剂对磷渣砂防水抗裂浆性能的影响,并结合XRD、SEM及物理吸附仪等测试技术分析了磷渣砂浆水化硬化体的矿物组成,微观形貌及孔径分布。试验结果表明:提高防水剂掺量可使砂浆的保水性,原拉伸黏结强度以及浸水拉伸黏结强度增大,而压折比,抗压强度与透水性却降低。减小可再分散乳胶粉的掺量可使砂浆的抗压强度,浸水拉伸黏结强度及压折比减小,而保水性,透水性及原拉伸黏结强度增加。

  20. 橡胶沥青防水粘结层层间抗剪性能试验分析%Test Analysis on Shear Resistance Performance between Rubber Asphalt Waterproofing Adhesive Layers

    Institute of Scientific and Technical Information of China (English)

    李正中; 宋晓燕; 肖庆一; 魏连雨

    2012-01-01

    Based on the indoor shear test stimulation of the interface bonding force status of concrete bridge deck waterproof layers, conduct systematically analysis of various factors and rules in layer shear resistance, in terms of asphalt spray amount, gravel spreading type, bridge panel interface treatment conditions and environmental temperature, etc, to propose various technical measures for improving the shear resistance performance between rubber asphalt waterproofing adhesive layers thus provide experimental basis and data support for the practical applications and construction quality. Research concludes that; in order to give full play to the shear resistance performance between rubber asphalt waterproofing adhesive layers, the shear resistance and bond performance in high temperature state must be strictly controlled, the spray volume and spray temperature should be controlled at 1. 8 ~2. 2 kg/m2 and 190 - 200 ℃ ; meanwhile, the spreading gravels should be clean with preheating treatment, the diameter ranging from 2. 36mm to 4. 75 mm; the spraying volume should be 10 kg/m2. In addition, the bridge panel surface roughness degree should be controlled within a reasonable context, when the anti-sliding value is between 45 to 55, the maximum value of interlayer shear resistance strength appears.%利用室内剪切试验模拟水泥混凝土桥面防水粘结层的界面受力状态,从沥青喷涂量、碎石撒布类型、桥面板界面处理状况、环境温度等方面系统分析影响其层间抗剪性能的各种因素及变化规律,以此提出提高橡胶沥青防水粘结层层间抗剪性能的各项技术措施,为充分发挥橡胶沥青防水粘结层的层间抗剪性能,必须严格控制其在高温状态下的抗剪和粘结性能,喷洒量和喷洒温度应控制在1.8~2.2 kg/m2和190~200℃,同时,撤布粒径为2.36~4.75mm、撒布量为10 kg/m2左右且经过预热处理的洁净碎石,而且,还应将桥面板的表面粗糙程度控