WorldWideScience

Sample records for biogas process propionate

  1. Monitoring and control of the biogas process based on propionate concentration using online VFA measurement

    DEFF Research Database (Denmark)

    Boe, Kanokwan; Steyer, J.P.; Angelidaki, Irini

    2008-01-01

    Simple logic control algorithms were tested for automatic control of a lab-scale CSTR manure digester. Using an online VFA monitoring system, propionate concentration in the reactor was used as parameter for control of the biogas process. The propionate concentration was kept below a threshold...

  2. Regulation and optimization of the biogas process: Propionate as a key parameter

    DEFF Research Database (Denmark)

    Bangsø Nielsen, Henrik; Uellendahl, Hinrich; Ahring, Birgitte Kiær

    2007-01-01

    The use of volatile fatty acids (VFA) as process indicators in biogas reactors treating manure together with industrial waste was studied. At a full-scale biogas plant, an online VFA sensor was installed in order to study VFA dynamics during stable and unstable operation. During stable operation......, a process breakdown caused by organic overloading with meat and bone meal and lipids was indicated by changes in propionate concentration 12-18 days before a decrease in methane production was observed. Furthermore, a more efficient and stable utilization of the substrate was observed when propionate.......6 to 2.9 mM. A process disturbance caused by overloading with industrial waste was reflected by a significant increase in all VFA concentrations. During the recovery of the process, the return of propionate back to the steady-state level was 2-3 days slower than any other VFA and propionate could best...

  3. Regulation and optimization of the biogas process: Propionate as a key parameter

    Energy Technology Data Exchange (ETDEWEB)

    Nielsen, Henrik Bangsoe; Uellendahl, Hinrich; Ahring, Birgitte Kiaer [Bioprocess Science and Technology, BioCentrum-DTU, Building 227, Technical University of Denmark, DK-2800 Lyngby (Denmark)

    2007-11-15

    The use of volatile fatty acids (VFA) as process indicators in biogas reactors treating manure together with industrial waste was studied. At a full-scale biogas plant, an online VFA sensor was installed in order to study VFA dynamics during stable and unstable operation. During stable operation acetate increased significantly during the feeding periods from a level of 2-4 to 12-17 mM, but the concentration generally dropped to about the same level as before feeding. The fluctuations in the propionate were more moderate than for acetate but the average level rose during 1 week of operation from 0.6 to 2.9 mM. A process disturbance caused by overloading with industrial waste was reflected by a significant increase in all VFA concentrations. During the recovery of the process, the return of propionate back to the steady-state level was 2-3 days slower than any other VFA and propionate could best describe the normalizing of the process. In a lab-scale continuously stirred tank reactor experiment, with manure as main substrate, the prospective of using either propionate concentration or methane production as single process indicators was studied. Propionate was found to be the best indicator. Thus, a process breakdown caused by organic overloading with meat and bone meal and lipids was indicated by changes in propionate concentration 12-18 days before a decrease in methane production was observed. Furthermore, a more efficient and stable utilization of the substrate was observed when propionate was used as process indicator. (author)

  4. Process control in biogas plants

    DEFF Research Database (Denmark)

    Holm-Nielsen, Jens Bo; Oleskowicz-Popiel, Piotr

    2013-01-01

    Efficient monitoring and control of anaerobic digestion (AD) processes are necessary in order to enhance biogas plant performance. The aim of monitoring and controlling the biological processes is to stabilise and optimise the production of biogas. The principles of process analytical technology...

  5. Isolation of acetic, propionic and butyric acid-forming bacteria from biogas plants.

    Science.gov (United States)

    Cibis, Katharina Gabriela; Gneipel, Armin; König, Helmut

    2016-02-20

    In this study, acetic, propionic and butyric acid-forming bacteria were isolated from thermophilic and mesophilic biogas plants (BGP) located in Germany. The fermenters were fed with maize silage and cattle or swine manure. Furthermore, pressurized laboratory fermenters digesting maize silage were sampled. Enrichment cultures for the isolation of acid-forming bacteria were grown in minimal medium supplemented with one of the following carbon sources: Na(+)-dl-lactate, succinate, ethanol, glycerol, glucose or a mixture of amino acids. These substrates could be converted by the isolates to acetic, propionic or butyric acid. In total, 49 isolates were obtained, which belonged to the phyla Firmicutes, Tenericutes or Thermotogae. According to 16S rRNA gene sequences, most isolates were related to Clostridium sporosphaeroides, Defluviitoga tunisiensis and Dendrosporobacter quercicolus. Acetic, propionic or butyric acid were produced in cultures of isolates affiliated to Bacillus thermoamylovorans, Clostridium aminovalericum, Clostridium cochlearium/Clostridium tetani, C. sporosphaeroides, D. quercicolus, Proteiniborus ethanoligenes, Selenomonas bovis and Tepidanaerobacter sp. Isolates related to Thermoanaerobacterium thermosaccharolyticum produced acetic, butyric and lactic acid, and isolates related to D. tunisiensis formed acetic acid. Specific primer sets targeting 16S rRNA gene sequences were designed and used for real-time quantitative PCR (qPCR). The isolates were physiologically characterized and their role in BGP discussed.

  6. Online monitoring and control of the biogas process

    Energy Technology Data Exchange (ETDEWEB)

    Boe, K.

    2006-07-01

    The demand for online monitoring and control of biogas process is increasing, since better monitoring and control system can improve process stability and enhance process performance for better economy of the biogas plants. A number of parameters in both the liquid and the gas phase have been suggested as process indicators. These include gas production, pH, alkalinity, volatile fatty acids (VFA) and hydrogen. Of these, VFA is the most widely recognised as a direct, relevant measure of stability. The individual, rather than collective VFA concentrations are recognised as providing significantly more information for diagnosis. However, classic on-line measurement is based on filtration, which suffers from fouling, especially in particulate or slurry wastes. In this project, a new online VFA monitoring system has been developed using gas-phase VFA extraction to avoid sample filtration. The liquid sample is pumped into a sampling chamber, acidified, added with salt and heated to extract VFA into the gas phase before analysis by GC-FID. This allows easy application to manure. Sample and analysis time of the system varies from 25-40 min. depending on the washing duration. The sampling frequency is fast enough for the dynamic of a manure digester, which is in the range of several hours. This system has been validated over more than 6 months and had shown good agreement with offline VFA measurement. Response from this sensor was compared with other process parameters such as biogas production, pH and dissolved hydrogen during overload situations in a laboratory-scale digester, to investigate the suitability of each measure as a process indicator. VFA was most reliable for indicating process imbalance, and propionate was most persistent. However, when coupling the online VFA monitoring with a simple control for automatic controlling propionate level in a digester, it was found that propionate decreased so slow that the biogas production fluctuated. Therefore, it is more

  7. GlidArc-assisted processing of biogas

    Energy Technology Data Exchange (ETDEWEB)

    Czernichowski, A.; Wesolowska, K. (ECP, La Ferte St Aubin (France)), Email: echph@wanadoo.fr

    2009-07-01

    Power generation or chemical applications of biogas can be difficult when CH{sub 4} content is too low and / or in the presence of sulphur compounds. We therefore propose two reformers based on electric discharges (GlidArc) that strike directly either in a poor biogas or in waste CO{sub 2} + H{sub 2}S mixture generated during biogas cleaning. Direct application of GlidArc discharges to the poor biogas enhances its flammability through a partial conversion of CH{sub 4} + CO{sub 2} into hydrogen and carbon monoxide (synthesis gas). Any level of sulphur (and other impurities) is accepted. Roughly 40 % of injected electric power is transferred into upgraded biogas as its additional chemical enthalpy. A few percent of resultant H{sub 2} and CO inside the biogas makes it more flammable, and therefore better to fuel an engine or gas turbine. As a result of biogas purification via amines-washing technologies, one gets concentrated pollutants in CO{sub 2} matrix. Instead of classical neutralisation, we propose H{sub 2}Svalorisation through the SulfArc process converting all H{sub 2}S into additional amounts of synthesis gas, while neutral elemental sulphur is removed from the system. Generated syngas can be injected into the main biogas flow to enhance its flammability. (orig.)

  8. Microbial Community Shifts during Biogas Production from Biowaste and/or Propionate

    Directory of Open Access Journals (Sweden)

    Chaoran Li

    2015-02-01

    Full Text Available Propionate is the most delicate intermediate during anaerobic digestion as its degradation is thermodynamically unfavorable. To determine its maximum possible degradation rates during anaerobic digestion, a reactor was fed Monday to Friday with an organic loading rate (OLR of 12/14 kg CODbiowaste·m−3·d−1 plus propionate up to a final OLR of 18 kg COD·m−3·d−1. No feed was supplied on weekends as it was the case in full-scale. To maintain permanently high propionate oxidizing activity (POA, a basic OLR of 3 kg CODpropionate·m−3·d−1 all week + 11 kg CODbiowaste·m−3·d−1 from Monday to Friday was supplied. Finally a reactor was operated with an OLR of 12 kg CODbiowaste·m−3·d−1 from Monday to Friday and 5 kg CODpropionate·m−3·d−1 from Friday night to Monday morning to maintain a constant gas production for permanent operation of a gas engine. The propionate degradation rates (PDRs were determined for biowaste + propionate feeding. Decreasing PDRs during starvation were analyzed. The POA was higher after propionate supply than after biowaste feeding and decreased faster during starvation of a propionate-fed rather than a biowaste-fed inoculum. Shifts of the propionate-oxidizing and methanogenic community were determined.

  9. Monitoring and controlling the biogas process

    Energy Technology Data Exchange (ETDEWEB)

    Ahring, B.K.; Angelidaki, I. [The Technical Univ. of Denmark, Dept. of Environmental Science and Engineering, Lyngby (Denmark)

    1997-08-01

    Many modern large-scale biogas plants have been constructed recently, increasing the demand for proper monitoring and control of these large reactor systems. For monitoring the biogas process, an easy to measure and reliable indicator is required, which reflects the metabolic state and the activity of the bacterial populations in the reactor. In this paper, we discuss existing indicators as well as indicators under development which can potentially be used to monitor the state of the biogas process in a reactor. Furthermore, data are presented from two large scale thermophilic biogas plants, subjected to temperature changes and where the concentration of volatile fatty acids was monitored. The results clearly demonstrated that significant changes in the concentration of the individual VFA occurred although the biogas production was not significantly changed. Especially the concentrations of butyrate, isobutyrate and isovalerate showed significant changes. Future improvements of process control could therefore be based on monitoring of the concentration of specific VFA`s together with information about the bacterial populations in the reactor. The last information could be supplied by the use of modern molecular techniques. (au) 51 refs.

  10. Near-infrared spectroscopy for process and substrate supervision of a full-scale biogas plant

    Energy Technology Data Exchange (ETDEWEB)

    Jacobi, Hans Fabian

    2012-07-01

    Aim of this study was to investigate the possible use of near-infrared spectroscopy in the supervision of the biogas production process or parts thereof. It was examined, whether the surveillance of (a) the process and (b) substrate was feasible. The following tasks were accomplished to this end: 1. Development, construction and assembly of suitable NIRS-metrology, development of proper control-software as well as of strategies for data acquisition and data handling, 2. calculation and validation of regression models on the basis of acquired spectra and reference data for (a) suitable parameters of the biogas process, (b) composition and biogas potential of the substrate, 3. calculation of continuous time series of all parameters in order to prove the possibility of continuous surveillance, 4. integrated processing of continuously calculated biogas potentials together with plant data for the prediction of the biogas production behavior of the biogas plant. A near-infrared spectrometer was installed and equipped with NIR-measuring heads of own design and construction on a full-scale agricultural biogas plant. For 500 days spectra were continuously logged at (a) a pipe flowed through by fermenter slurry and (b) the feeding station, where silage passed. Based on regularly withdrawn reference samples and the corresponding spectra regression models were calibrated for the several constituents. Continuously logged spectra were used to calculate time series with the aid of the regression models for each constituent. Models and time series were established for the following parameters: (a) process parameters: volatile fatty acids, acetic acid, propionic acid, dry matter, volatile solids; (b) substrate parameters: dry matter, volatile solids, crude fiber, crude fat, crude protein, nitrogen-free extracts, experimentally assessed biogas potential, theoretically assessed biogas potential. Despite the partially low quality of the models it was possible to follow the course of

  11. Improvement of the Biogas Production Process : Explorative project (EP1)

    OpenAIRE

    Karlsson, Anna; Björn, Annika; Sepehr, Shakeri Yekta; Svensson, Bo

    2014-01-01

    There are several ways to improve biogas production in anaerobic digestion processes and a number of strategies may be chosen. Increased organic loading in existing plants will in most cases demand the introduction of new substrate types. However, to substantially increase the Swedish biogas production new, large-scale biogas plants digesting new substrate types need to be established. Better utilization of existing digester volumes can be linked to:  Increase of organic loading rates and/or ...

  12. biogas

    DEFF Research Database (Denmark)

    2015-01-01

    Functions for working with biogas data. Both low- and high-level functions are included for carrying out common tasks for analysis of biogas and related data. Molar mass and calculated oxygen demand (COD') can be determined from a chemical formula. Measured gas volume can be corrected for water...... vapor and to (possibly user-defined) standard temperature and pressure. Gas composition, cumulative production, or other variables can be interpolated to a specified time. Cumulative biogas and methane production (and rates) can be calculated using volumetric, manometric, or gravimetric methods for any...... be summarized in several different ways (e.g., omitting normalization) using the same function. Lastly, biogas and methane production can be predicted from substrate composition and additional, optional data....

  13. Biogas production and methanogenic archaeal community in mesophilic and thermophilic anaerobic co-digestion processes.

    Science.gov (United States)

    Yu, D; Kurola, J M; Lähde, K; Kymäläinen, M; Sinkkonen, A; Romantschuk, M

    2014-10-01

    Over 258 Mt of solid waste are generated annually in Europe, a large fraction of which is biowaste. Sewage sludge is another major waste fraction. In this study, biowaste and sewage sludge were co-digested in an anaerobic digestion reactor (30% and 70% of total wet weight, respectively). The purpose was to investigate the biogas production and methanogenic archaeal community composition in the anaerobic digestion reactor under meso- (35-37 °C) and thermophilic (55-57 °C) processes and an increasing organic loading rate (OLR, 1-10 kg VS m(-3) d(-1)), and also to find a feasible compromise between waste treatment capacity and biogas production without causing process instability. In summary, more biogas was produced with all OLRs by the thermophilic process. Both processes showed a limited diversity of the methanogenic archaeal community which was dominated by Methanobacteriales and Methanosarcinales (e.g. Methanosarcina) in both meso- and thermophilic processes. Methanothermobacter was detected as an additional dominant genus in the thermophilic process. In addition to operating temperatures, the OLRs, the acetate concentration, and the presence of key substrates like propionate also affected the methanogenic archaeal community composition. A bacterial cell count 6.25 times higher than archaeal cell count was observed throughout the thermophilic process, while the cell count ratio varied between 0.2 and 8.5 in the mesophilic process. This suggests that the thermophilic process is more stable, but also that the relative abundance between bacteria and archaea can vary without seriously affecting biogas production.

  14. Long-term stability of thermophilic co-digestion submerged anaerobic membrane reactor encountering high organic loading rate, persistent propionate and detectable hydrogen in biogas.

    Science.gov (United States)

    Qiao, Wei; Takayanagi, Kazuyuki; Niu, Qigui; Shofie, Mohammad; Li, Yu You

    2013-12-01

    The performance of thermophilic anaerobic co-digestion of coffee grounds and sludge using membrane reactor was investigated for 148 days, out of a total research duration of 263 days. The OLR was increased from 2.2 to 33.7 kg-COD/m(3)d and HRT was shortened from 70 to 7 days. A significant irreversible drop in pH confirmed the overload of reactor. Under a moderately high OLR of 23.6 kg-COD/m(3)d, and with HRT and influent total solids of 10 days and 150 g/L, respectively, the COD removal efficiency was 44.5%. Hydrogen in biogas was around 100-200 ppm, which resulted in the persistent propionate of 1.0-3.2g/L. The VFA consumed approximately 60% of the total alkalinity. NH4HCO3 was supplemented to maintain alkalinity. The stability of system relied on pH management under steady state. The 16SrDNA results showed that hydrogen-utilizing methanogens dominates the archaeal community. The propionate-oxidizing bacteria in bacterial community was insufficient.

  15. Methane losses in biogas processing; Methanverluste bei der Biogasaufbereitung

    Energy Technology Data Exchange (ETDEWEB)

    Baum, S.; Baier, U. [ZHAW, Zuercher Hochschule fuer Angewandte Wissenschaften, IBT Institut fuer Biotechnologie, Fachgruppe Umweltbiotechnologie, Waedenswil (Switzerland); Judex, J.; Biollaz, S.; Schneebeli, J. [PSI, Paul Scherrer Institut, Villigen (Switzerland)

    2008-11-15

    This report for the Swiss Federal Office of Energy (SFOE) by the Paul Scherrer Institute PSI and the Zurich University of Applied Sciences, Switzerland, presents the results of a study made on methane losses that occur during the processing of biogas to provide natural gas quality. Such losses are considered as possibly compromising the environmental advantages offered by the feeding-in of processed biogas into the national gas mains. This processing involves the removal of carbon dioxide from the biogas. The state-of-the-art in this area is discussed, relevant factors and analysis methods are looked at. An overview of methods used to prevent methane losses is presented. The results of investigations made at an installation in Lucerne, Switzerland, are presented and discussed.

  16. Influence of biogas flow rate on biomass composition during the optimization of biogas upgrading in microalgal-bacterial processes.

    Science.gov (United States)

    Serejo, Mayara L; Posadas, Esther; Boncz, Marc A; Blanco, Saúl; García-Encina, Pedro; Muñoz, Raúl

    2015-03-03

    The influence of biogas flow rate (0, 0.3, 0.6, and 1.2 m(3) m(-2) h(-1)) on the elemental and macromolecular composition of the algal-bacterial biomass produced from biogas upgrading in a 180 L photobioreactor interconnected to a 2.5 L external bubbled absorption column was investigated using diluted anaerobically digested vinasse as cultivation medium. The influence of the external liquid recirculation/biogas ratio (0.5 biogas, was also evaluated. A L/G ratio of 10 was considered optimum to support CO2 and H2S removals of 80% and 100%, respectively, at all biogas flow rates tested. Biomass productivity increased at increasing biogas flow rate, with a maximum of 12 ± 1 g m(-2) d(-1) at 1.2 m(3) m(-2) h(-1), while the C, N, and P biomass content remained constant at 49 ± 2%, 9 ± 0%, and 1 ± 0%, respectively, over the 175 days of experimentation. The high carbohydrate contents (60-76%), inversely correlated to biogas flow rates, would allow the production of ≈100 L of ethanol per 1000 m(3) of biogas upgraded under a biorefinery process approach.

  17. Evaluation of silage-fed biogas process performance using microbiological and kinetic methods

    Energy Technology Data Exchange (ETDEWEB)

    Jarvis, Aa.

    1996-10-01

    In this study, different kinetic and microbiological methods were used to evaluate the growth and activity of key groups of bacteria degrading ley silage in one-phase and two-phase biogas processes. Emphasis was placed on studying the dynamic behaviour of different trophic groups resulting from the initiation of liquid recirculation in the processes. The microbiological methods included microscopy and most probable number (MPN) counts with different substrates. The kinetic methods included measurements of specific methanogenic activity (SMA) with acetate and H{sub 2}/CO{sub 2} as substrates, batch assays with trace element additions and measurement of conversion rates of mannitol and lactate in the digesters. In general, the initiation of liquid recirculation at first promoted the growth and/or activity of several trophic groups of bacteria, such as butyrate and propionate degraders and acetotrophic and hydrogenotrophic methanogens in the liquefaction/acidogenesis reactors of the two-phase processes. This was probably mainly due to the increased pH. However, after some time of liquid recirculation, an inhibition of some bacterial groups occurred, such as propionate degraders and methanogens in the methanogenic reactors of two-phase processes. This was probably due to increased concentrations of salts and free ammonia. The batch assays proved to be valuable tools in process optimization by the addition of trace elements. Here, the addition of cobalt significantly increased methane production from acetate. In this study, a more comprehensive understanding of the process behaviour in response to the initiation of liquid recirculation was achieved which could not have been obtained by only monitoring routine parameters such as pH, methane production and concentrations of organic acids and salts. 120 refs, 4 figs, 1 tab

  18. Dynamic biogas upgrading based on the Sabatier process

    DEFF Research Database (Denmark)

    Jurgensen, Lars; Ehimen, Ehiazesebhor Augustine; Born, Jens;

    2015-01-01

    This study aimed to investigate the feasibility of substitute natural gas (SNG) generation using biogas from anaerobic digestion and hydrogen from renewable energy systems. Using thermodynamic equilibrium analysis, kinetic reactor modeling and transient simulation, an integrated approach...... for the operation of a biogas-based Sabatier process was put forward, which was then verified using a lab scale heterogenous methanation reactor. The process simulation using a kinetic reactor model demonstrated the feasibility of the production of SNG at gas grid standards using a single reactor setup. The Wobbe...... index, CO2 content and calorific value were found to be controllable by the H2/CO2 ratio fed the methanation reactor. An optimal H2/CO2 ratio of 3.45–3.7 was seen to result in a product gas with high calorific value and Wobbe index. The dynamic reactor simulation verified that the process start...

  19. Effect of temperature and active biogas process on passive separation of digested manure

    DEFF Research Database (Denmark)

    Kaparaju, Prasad Laxmi-Narasimha; Angelidaki, Irini

    2008-01-01

    separation was achieved when digested manure was allowed to settle at 55 degrees C with active biogas process (pre-incubated at 55 degrees C) compared to separation at 55 degrees C without active biogas process (autoclaved at 120 degrees C, for 20 min) or at 10 degrees C with active biogas process. Maximum...... solids separation was noticed 24 h after settling in column incubated at 55 degrees C, with active biogas process. Microbiological analyses revealed that proportion of Archaea and Bacteria, absent in the autoclaved material, varied with incubation temperature, time and sampling depth. Short rod shaped...

  20. Implementation of online volatile fatty acids sensor for control and optimization of anaerobic process for low cost biogas production from manure. Project report

    Energy Technology Data Exchange (ETDEWEB)

    Boe, K.; Angelidaki, I.

    2010-10-15

    Proper monitoring and control can improve process stability and enhance process performance for better economy of the biogas plants. Volatile fatty acid (VFA) is the most widely recognized as a direct, relevant measure of stability. Classic on-line measurement of individual VFA is based on filtration, which suffers from fouling when applied with manure slurries. A VFA sensor developed at DTU Environment, based on headspace chromatography technique could avoid the problems from particulate matters. In this work, the sensor had been implemented for online monitoring of the lab-scale and the pilot-scale manure digester. The industrial prototype of the VFA sensor and sample acquisition system has been constructed and implemented at a pilot scale biogas plant, located at Lundtofte, DTU. The VFA sensor has shown very satisfying results in terms of sensitivity and reliability for monitoring the biogas process. Moreover, the online VFA and biogas registration data were used as process indicators for automatic control of the biogas reactor. The results from control experiments confirmed that the combination of biogas production, total VFA concentration and propionate concentration could effectively reflect the dynamic state of the process which was very crucial for automatic control. Due to the standardized analyzing condition (pH<2, temperature>70 deg. C), the sensor responses were not affected by the manure composition (TS, VS or the addition of extra organics), which made these results representative for implementing in the full-scale biogas plant where some industrial organic wastes were added to increase the biogas production. During the project period, the sensor design and construction had been modified and tested several times to improve the robustness. However, the implementation of the sensor in full-scale biogas plant would need some further development such as improvement of mechanical design and further up-scaling depending on the dry solid content in the

  1. EU Agro Biogas Project

    NARCIS (Netherlands)

    Amon, T.; Mayr, H.; Eder, M.; Hobbs, P.; Rao Ravella, S.; Roth, U.; Niebaum, A.; Doehler, H.; Weiland, P.; Abdoun, E.; Moser, A.; Lyson, M.; Heiermann, M.; Plöchl, M.; Budde, J.; Schattauer, A.; Suarez, T.; Möller, H.; Ward, A.; Hillen, F.; Sulima, P.; Oniszk-Polplawska, A.; Krampe, P.; Pastorek, Z.; Kara, J.; Mazancova, J.; Dooren, van H.J.C.; Wim, C.; Gioelli, F.; Balsari, P.

    2009-01-01

    EU-AGRO-BIOGAS is a European Biogas initiative to improve the yield of agricultural biogas plants in Europe, to optimise biogas technology and processes and to improve the efficiency in all parts of the production chain from feedstock to biogas utilisation. Leading European research institutions and

  2. Life cycle assessment of flexibly fed biogas processes for an improved demand-oriented biogas supply.

    Science.gov (United States)

    Ertem, Funda Cansu; Martínez-Blanco, Julia; Finkbeiner, Matthias; Neubauer, Peter; Junne, Stefan

    2016-11-01

    This paper analyses concepts to facilitate a demand oriented biogas supply at an agricultural biogas plant of a capacity of 500kWhel, operated with the co-digestion of maize, grass, rye silage and chicken manure. In contrast to previous studies, environmental impacts of flexible and the traditional baseload operation are compared. Life Cycle Assessment (LCA) was performed to detect the environmental impacts of: (i) variety of feedstock co-digestion scenarios by substitution of maize and (ii) loading rate scenarios with a focus on flexible feedstock utilization. Demand-driven biogas production is critical for an overall balanced power supply to the electrical grid. It results in lower amounts of emissions; feedstock loading rate scenarios resulted in 48%, 20%, 11% lower global warming (GWP), acidification (AP) and eutrophication potentials, and a 16% higher cumulative energy demand. Substitution of maize with biogenic-waste regarding to feedstock substitution scenarios could create 10% lower GWP and AP.

  3. Effect of propionic acid on citric acid fermentation in an integrated citric acid-methane fermentation process.

    Science.gov (United States)

    Xu, Jian; Bao, Jia-Wei; Su, Xian-Feng; Zhang, Hong-Jian; Zeng, Xin; Tang, Lei; Wang, Ke; Zhang, Jian-Hua; Chen, Xu-Sheng; Mao, Zhong-Gui

    2016-03-01

    In this study, an integrated citric acid-methane fermentation process was established to solve the problem of wastewater treatment in citric acid production. Citric acid wastewater was treated through anaerobic digestion and then the anaerobic digestion effluent (ADE) was further treated and recycled for the next batch citric acid fermentation. This process could eliminate wastewater discharge and reduce water resource consumption. Propionic acid was found in the ADE and its concentration continually increased in recycling. Effect of propionic acid on citric acid fermentation was investigated, and results indicated that influence of propionic acid on citric acid fermentation was contributed to the undissociated form. Citric acid fermentation was inhibited when the concentration of propionic acid was above 2, 4, and 6 mM in initial pH 4.0, 4.5 and, 5.0, respectively. However, low concentration of propionic acid could promote isomaltase activity which converted more isomaltose to available sugar, thereby increasing citric acid production. High concentration of propionic acid could influence the vitality of cell and prolong the lag phase, causing large amount of glucose still remaining in medium at the end of fermentation and decreasing citric acid production.

  4. Biogas utilization

    Energy Technology Data Exchange (ETDEWEB)

    Moser, M.A. [Resource Conservation Management, Inc., Berkeley, CA (United States)

    1996-01-01

    Options for successfully using biogas depend on project scale. Almost all biogas from anaerobic digesters must first go through a gas handling system that pressurizes, meters, and filters the biogas. Additional treatment, including hydrogen sulfide-mercaptan scrubbing, gas drying, and carbon dioxide removal may be necessary for specialized uses, but these are complex and expensive processes. Thus, they can be justified only for large-scale projects that require high-quality biogas. Small-scale projects (less than 65 cfm) generally use biogas (as produced) as a boiler fuel or for fueling internal combustion engine-generators to produce electricity. If engines or boilers are selected properly, there should be no need to remove hydrogen sulfide. Small-scale combustion turbines, steam turbines, and fuel cells are not used because of their technical complexity and high capital cost. Biogas cleanup to pipeline or transportation fuel specifications is very costly, and energy economics preclude this level of treatment.

  5. Anaerobic digestion of different feedstocks: impact on energetic and environmental balances of biogas process.

    Science.gov (United States)

    Bacenetti, Jacopo; Negri, Marco; Fiala, Marco; González-García, Sara

    2013-10-01

    The possibility of limiting the global warming is strictly linked to the reduction of GHG emissions. Renewable energy both allows reducing emissions and permits to delay fossil fuel depletion. The anaerobic digestion of animal manure and energy crops is a promising way of reducing GHG emissions. In Italy agricultural biogas production was considerably increased; nowadays there are about 520 agricultural biogas plants. The increasing number of biogas plants, especially of those larger than 500 kW(e) (electrical power), involves a high consumption of energy crops, large transport distances of biomass and digestate and difficulties on thermal energy valorization. In this study the energetic (CED) and environmental (GHG emissions) profiles associated with the production of electricity derived from biogas have been identified. Three biogas plants located in Northern Italy have been analyzed. The study has been carried out considering a cradle-to-grave perspective and thus, special attention has been paid on the feedstock production and biogas production process. The influences on the results taking into account different plant sizes and feeding rate has been assessed in detail. Energy analysis was performed using the Cumulative Energy Demand method (CED). The climate change was calculated for a 100-year time frame based on GHG emissions indicated as CO2 equivalents (eq) and defined by the IPCC (2006). In comparison to the fossil reference system, the electricity production using biogas saves GHG emissions from 0.188 to 1.193 kg CO2eq per kWh(e). Electricity supply from biogas can also contribute to a considerable reduction of the use of fossil energy carriers (from -3.97 to 10.08 MJ(fossil) per kWh(e)). The electricity production from biogas has a big potential for energy savings and reduction of GHG emissions. Efficient utilization of the cogenerated heat can substantially improve the GHG balance of electricity production from biogas.

  6. Co-digestion of manure and whey for in situ biogas upgrading by the addition of H(2): process performance and microbial insights.

    Science.gov (United States)

    Luo, Gang; Angelidaki, Irini

    2013-02-01

    In situ biogas upgrading was conducted by introducing H(2) directly to the anaerobic reactor. As H(2) addition is associated with consumption of the CO(2) in the biogas reactor, pH increased to higher than 8.0 when manure alone was used as substrate. By co-digestion of manure with acidic whey, the pH in the anaerobic reactor with the addition of hydrogen could be maintained below 8.0, which did not have inhibition to the anaerobic process. The H(2) distribution systems (diffusers with different pore sizes) and liquid mixing intensities were demonstrated to affect the gas-liquid mass transfer of H(2) and the biogas composition. The best biogas composition (75:6.6:18.4) was obtained at stirring speed 150 rpm and using ceramic diffuser, while the biogas in the control reactor consisted of CH(4) and CO(2) at a ratio of 55:45. The consumed hydrogen was almost completely converted to CH(4), and there was no significant accumulation of VFA in the effluent. The study showed that addition of hydrogen had positive effect on the methanogenesis, but had no obvious effect on the acetogenesis. Both hydrogenotrophic methanogenic activity and the concentration of coenzyme F(420) involved in methanogenesis were increased. The archaeal community was also altered with the addition of hydrogen, and a Methanothermobacter thermautotrophicus related band appeared in a denaturing gradient gel electrophoresis gel from the sample of the reactor with hydrogen addition. Though the addition of hydrogen increased the dissolved hydrogen concentration, the degradation of propionate was still thermodynamically feasible at the reactor conditions.

  7. Robust on-line monitoring of biogas processes; Robusta maettekniker on-line foer optimerad biogasproduktion

    Energy Technology Data Exchange (ETDEWEB)

    Nordberg, Aake; Hansson, Mikael; Kanerot, Mija; Krozer, Anatol; Loefving, Bjoern; Sahlin, Eskil

    2010-03-15

    project showed that pH-adjustment with Na{sub 3}PO{sub 4} can be a way of compensating for the losses of volatile compounds (up to 20% of VS), which occurs when standardized reference methods are used. This is a fundamental problem and requires further research. Monitoring of a laboratory-scale anaerobic digester with NIR showed that a previously developed multivariate model could predict propionate concentrations (R2= 0,92; RMSEP 0,39 g/L) in the interval 0-5 g/L, which is a relevant interval for inhibition (limit ca 3 g/L). A commercial FT-NIR instrument was subsequently installed at the production plant. However, the organic loading was decreased during the evaluation period due to process disturbances, at which the dynamic of the process was not in the range needed for prediction of e.g. propionate. Measurements and evaluation will continue during normal conditions after the completion of this project. Evaluation of a potentiometric sensor for ammonia with potential for on-line application showed low stability and a need for daily calibration, which therefore did not fulfill the requested demand. The project has demonstrated technologies with significant potential for on-line monitoring at production scale facilities, thus improving the knowledge base for making important decisions. Knowledge about on-line implementation has increased, and important insights into the limitations of standardized reference methods and substrate characteristics have been achieved. Instrument suppliers have in general a limited insight in the conditions at a biogas plant, which suggests that this type of WR-financed project is important for development in the area

  8. CONTROL PARAMETERS FOR UNDERSTANDING AND PREVENTING PROCESS IMBALANCES IN BIOGAS PLANTS. EMPHAS IS ON VFA DYNAMICS

    DEFF Research Database (Denmark)

    Bangsø Nielsen, Henrik

    H. The experiments were carried out in lab-scale thermophilic continuously stirred tank reactors (CSTR) treating livestock waste. The imbalances included inhibition by long chain fatty acids (LCFA), inhibition by ammonia, organic overloading with proteins and organic overloading with industrial waste, i.e. meat...... out on the basis of the methane production or on the basis of fluctuations in the concentration of propionate. The experiment confirmed that propionate is a useful parameter for (1) indication of process imbalances and (2) for regulation and optimization of the anaerobic digestion process in CSTRs....... In order to gain a better insight in the activity of the propionate degraders under different operational conditions the kinetic parameters of propionate degradation by biomass from 10 CSTRs differing in temperature, hydraulic retention time (HRT) and substrates were estimated in batch substrate...

  9. Causes for inhibitions of biogas process; Aarsager til haemning af biogasprocessen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-11-01

    It is the aim of the project to map reasons to inhibition of the biogas process. Inhibition of Danish common biogas plants in the last 5 years will be investigated in order to try to find the exact reason to the interruption of the process. Scientific literature will be investigated to describe the different reason for inhibition. The results of the project will be published in a report, an article and a popularized paper. (EHS)

  10. Comparison of VFA titration procedures used for monitoring the biogas process

    DEFF Research Database (Denmark)

    Lützhøft, Hans-Christian Holten; Boe, Kanokwan; Fang, Cheng;

    2014-01-01

    Titrimetric determination of volatile fatty acids (VFAs) contents is a common way to monitor a biogas process. However, digested manure from co-digestion biogas plants has a complex matrix with high concentrations of interfering components, resulting in varying results when using different...... (GC) analysis. Two of the procedures are commonly used in biogas plants and two are discussed in literature. The results showed that the optimal titration results were obtained when 40mL of four times diluted digested manure was gently stirred (200rpm). Results from samples with different VFA...

  11. Local biogas producer; Bodenstaendiges Biogas

    Energy Technology Data Exchange (ETDEWEB)

    Wiedemann, Karsten

    2010-02-15

    MT-Energie is a manufacturer of industrial process plants seated in the German state of Niedersachsen. After a period of steep growth, the company is now entering the biogas business and intends to supply biogas into the public gas grid. (orig.)

  12. Processing biogas plant digestates into value-added products - BIOVIRTA

    Energy Technology Data Exchange (ETDEWEB)

    Paavola, T. (MTT Agrifood Research Finland, Jokioinen (Finland)), e-mail: teija.paavola@mtt.fi; Torniainen, M. (Finnish Food Safety Authority, EVIRA, Helsinki (Finland)), e-mail: merja.torniainen@evira.fi; Kaparaju, P. (Jyvaeskylae Univ. (Finland)), e-mail: prasad.kaparaju@jyu.fi (and others)

    2011-11-15

    The objective of BIOVIRTA project is to develop technologies and practices with which digestates, originating from anaerobic digestion of different organic wastes and by-products can be refined to value-added and safe products for various end-uses. It is expected that the operational preconditions for biogas plants will be significantly enhanced when the end-products are proven safe and applicable. Selection of the raw materials for anaerobic co-digestion is the main operational strategy that could influence the nutrient content in the digestate. This has been clearly established in the laboratory and full-scale studies with various digestates originating from different raw materials. The nutrient content in the digestate also affects the opportunities to produce refined digestate products. In this project, the possibilities for several processing technologies, e.g. mechanical separation, stripping, and struvite production have been intensively evaluated for the production of different digestate products. Their mass balances have also been estimated. The feasibility for the use of the digestate products has been assessed based on their chemical and hygienic quality and for various end-uses, including as organic fertiliser and/or soil improver in crop production. The results of these field-experiments showed that the yield of barley fertilised with digestate products was comparable to inorganic fertilisers. (orig.)

  13. Killing of salmonella in the biogas process; Abtoetung von Salmonellen im Biogasprozess

    Energy Technology Data Exchange (ETDEWEB)

    Froeschle, Bianca; Lebuhn, Michael

    2012-08-15

    Pathogenic Salmonella are used in ordinances as an indicator for assessing microbial reduction in biogas plants and for the epidemic-hygienic condition of digestate. This brochure presents results of a study that examined the hygienic effect of the biogas process on Salmonella. [German] Krankheitserregende Salmonellen werden in relevanten Rechtsverordnungen als Indikator zur Beurteilung der Keimreduzierung in Biogasanlagen und des seuchenhygienischen Zustands von Gaerresten herangezogen. Die vorliegende Broschuere stellt Ergebnisse einer Studie dar, die die hygienisierende Wirkung des Biogasprozesses auf Salmonellen untersuchte.

  14. Impact of nickel and cobalt on biogas production and process stability during semi-continuous anaerobic fermentation of a model substrate for maize silage.

    Science.gov (United States)

    Pobeheim, Herbert; Munk, Bernhard; Lindorfer, Harald; Guebitz, Georg M

    2011-01-01

    The importance of nickel and cobalt on anaerobic degradation of a defined model substrate for maize was demonstrated. Five semi-continuous reactors were operated for 250 days at 35 °C and a well-defined trace metal solution was added to all reactors. Two reactors each were limited regarding the concentration of Ni(2+) and Co(2+), respectively, for certain time intervals. The required nickel concentration was depending on the organic loading rates (OLR) while, for example, above 2.6 g ODM L(-1) d(-1) nickel concentrations below 0.06 mg kg(-1) FM in the process significantly decreased biogas production by up to 25% compared to a control reactor containing 0.8 mg Ni(2+) kg(-1) FM. Similarly, limitation of cobalt to 0.02 mg kg(-1) FM decreased biogas production by about 10%. Limitations of nickel as well as cobalt lead to process instability. However, after gradual addition of nickel till 0.6 mg and cobalt till 0.05 mg kg(-1) FM the OLR was again increased to 4.3 g ODM L(-1) d(-1) while process stability was recovered and a fast metabolisation of acetic and propionic acid was detected. An increase of nickel to 0.88 mg kg(-1) FM did not enhance biogas performance. Furthermore, the increase of cobalt from 0.05 mg kg(-1) FM up to 0.07 mg kg(-1) FM did not exhibit a change in anaerobic fermentation and biogas production.

  15. Short-term effect of acetate and ethanol on methane formation in biogas sludge.

    Science.gov (United States)

    Refai, Sarah; Wassmann, Kati; Deppenmeier, Uwe

    2014-08-01

    Biochemical processes in biogas plants are still not fully understood. Especially, the identification of possible bottlenecks in the complex fermentation processes during biogas production might provide potential to increase the performance of biogas plants. To shed light on the question which group of organism constitutes the limiting factor in the anaerobic breakdown of organic material, biogas sludge from different mesophilic biogas plants was examined under various conditions. Therefore, biogas sludge was incubated and analyzed in anaerobic serum flasks under an atmosphere of N2/CO2. The batch reactors mirrored the conditions and the performance of the full-scale biogas plants and were suitable test systems for a period of 24 h. Methane production rates were compared after supplementation with substrates for syntrophic bacteria, such as butyrate, propionate, or ethanol, as well as with acetate and H2+CO2 as substrates for methanogenic archaea. Methane formation rates increased significantly by 35 to 126 % when sludge from different biogas plants was supplemented with acetate or ethanol. The stability of important process parameters such as concentration of volatile fatty acids and pH indicate that ethanol and acetate increase biogas formation without affecting normally occurring fermentation processes. In contrast to ethanol or acetate, other fermentation products such as propionate, butyrate, or H2 did not result in increased methane formation rates. These results provide evidence that aceticlastic methanogenesis and ethanol-oxidizing syntrophic bacteria are not the limiting factor during biogas formation, respectively, and that biogas plant optimization is possible with special focus on methanogenesis from acetate.

  16. The Optimum Mesophilic Temperature of Batch Process Biogas Production from Animal-based Wastes

    Directory of Open Access Journals (Sweden)

    Osita Obineche Obiukwu

    2014-10-01

    Full Text Available The optimum mesophilic temperature of biogas production from blends The optimum temperature of biogas production from blends of animal-based wastes was determined under controlled heat supply to the digester in a batch digestion process. Cow Dung (CD and Poultry Droppings (PD were blended in the ratio of CD: PD: 1:3. The digester was operated at average ambient temperature of 30°C as baseline. Biogas production from the waste blends was monitored under the temperatures of 32 to 45°C. Results obtained indicate maximum cumulative gas yield was observed at the temperature of 40°C. The 40°C temperature gave the highest biogas yield of 2685 mL followed by the 35°C temperature with the cumulative yield of 2535 mL. The ambient temperature of 30°C had the least cumulative biogas yield of 185 mL. These results indicate that increased and steady biogas production can be achieved under the optimum mesophilic temperature of 40°C when these animal-based wastes are digested in batch digestion process.

  17. Biogas production from UASB and polyurethane carrier reactors treating sisal processing wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Rubindamayugi, M.S.T.; Salakana, L.K.P. [Univ. of Dar es Salaam, Faculty of Science, Applied Microbiology Unit (Tanzania, United Republic of)

    1997-12-31

    The fundamental benefits which makes anaerobic digestion technology (ADT) attractive to the poor developing include the low cost and energy production potential of the technology. In this study the potential of using UASB reactor and Polyurethane Carrier Reactor (PCR) as pollution control and energy recovery systems from sisal wastewater were investigated in lab-scale reactors. The PCR demonstrated the shortest startup period, whereas the UASB reactor showed the highest COD removal efficiency 79%, biogas production rate (4.5 l biogas/l/day) and process stability than the PCR under similar HRT of 15 hours and OLR of 8.2 g COD/l/day. Both reactor systems became overloaded at HRT of 6 hours and OLR of 15.7 g COD/l/day, biogas production ceased and reactors acidified to pH levels which are inhibiting to methanogenesis. Based on the combined results on reactor performances, the UASB reactor is recommended as the best reactor for high biogas production and treatment efficiency. It was estimated that a large-scale UASB reactor can be designed under the same loading conditions to produce 2.8 m{sup 3} biogas form 1 m{sup 3} of wastewater of 5.16 kg COD/m{sup 3}. Wastewater from one decortication shift can produce 9,446 m{sup 3} og biogas. The energy equivalent of such fuel energy is indicated. (au)

  18. Does the addition of proteases affect the biogas yield from organic material in anaerobic digestion?

    Science.gov (United States)

    Müller, Liane; Kretzschmar, Jörg; Pröter, Jürgen; Liebetrau, Jan; Nelles, Michael; Scholwin, Frank

    2016-03-01

    The aim of this study was to investigate the biochemical disintegration effect of hydrolytic enzymes in lab scale experiments. Influences of enzyme addition on the biogas yield as well as effects on the process stability were examined. The addition of proteases occurred with low and high dosages in batch and semi-continuous biogas tests. The feed mixture consisted of maize silage, chicken dung and cow manure. Only very high concentrated enzymes caused an increase in biogas production in batch experiments. In semi-continuous biogas tests no positive long-term effects (100 days) were observed. Higher enzyme-dosage led to a reduced biogas-yield (13% and 36% lower than the reference). Phenylacetate and -propionate increased (up to 372 mgl(-1)) before the other volatile fatty acids did. Volatile organic acids rose up to 6.8 gl(-1). The anaerobic digestion process was inhibited.

  19. Biogas Production from Sugarcane Waste: Assessment on Kinetic Challenges for Process Designing.

    Science.gov (United States)

    Janke, Leandro; Leite, Athaydes; Nikolausz, Marcell; Schmidt, Thomas; Liebetrau, Jan; Nelles, Michael; Stinner, Walter

    2015-08-31

    Biogas production from sugarcane waste has large potential for energy generation, however, to enable the optimization of the anaerobic digestion (AD) process each substrate characteristic should be carefully evaluated. In this study, the kinetic challenges for biogas production from different types of sugarcane waste were assessed. Samples of vinasse, filter cake, bagasse, and straw were analyzed in terms of total and volatile solids, chemical oxygen demand, macronutrients, trace elements, and nutritional value. Biochemical methane potential assays were performed to evaluate the energy potential of the substrates according to different types of sugarcane plants. Methane yields varied considerably (5-181 Nm³·tonFM(-1)), mainly due to the different substrate characteristics and sugar and/or ethanol production processes. Therefore, for the optimization of AD on a large-scale, continuous stirred-tank reactor with long hydraulic retention times (>35 days) should be used for biogas production from bagasse and straw, coupled with pre-treatment process to enhance the degradation of the fibrous carbohydrates. Biomass immobilization systems are recommended in case vinasse is used as substrate, due to its low solid content, while filter cake could complement the biogas production from vinasse during the sugarcane offseason, providing a higher utilization of the biogas system during the entire year.

  20. Codigestion of manure and industrial organic waste at centralized biogas plants: process imbalances and limitations

    DEFF Research Database (Denmark)

    Bangsø Nielsen, Henrik; Angelidaki, Irini

    2008-01-01

    The present study focuses on process imbalances in Danish centralized biogas plants treating manure in combination with industrial waste. Collection of process data from various full-scale plants along with a number of interviews showed that imbalances occur frequently. High concentrations...

  1. Biogas Production through the Anaerobic Digestion of Date Palm Tree Wastes - Process Optimization

    Directory of Open Access Journals (Sweden)

    Fahad Y. Al-Juhaimi

    2014-04-01

    Full Text Available A process for the production of biogas through the anaerobic digestion (AD of date palm tree waste (DPTW was developed. The effects of different substrate pretreatments and operating conditions on the yield of biogas and on the chemical composition of DPTW before and after AD were studied. The best results were obtained using alkali pretreatment, with a particle size of 2 to 5 mm, a C:N ratio of 30:1, a digestion temperature of 40 °C, an initial pH of 7.0, and a volatile solids concentration of approximately 10%. The production of flammable biogas containing up to 50% methane started after about one week of operation and continued for approximately 11 weeks. The highest average biogas yield obtained was 342.2 L gas/kg of volatile solids fed to the digester. The highest maximum and average volumetric biogas production rates obtained were 674.5 and 404.4 L/m3 of digester volume per day, respectively. After digestion, there was up to a 58% reduction in the organic matter content of the substrate. Reductions in the contents of cellulose, hemicellulose, and soluble organic compounds were 68.7, 73.4, and 71.9%, respectively, while the ash and lignin contents remained mostly constant. The remaining sludge contained nutrient minerals and some organic matter which qualifies it as a potential soil fertilizer for crop production.

  2. Dynamic biogas upgrading based on the Sabatier process: thermodynamic and dynamic process simulation.

    Science.gov (United States)

    Jürgensen, Lars; Ehimen, Ehiaze Augustine; Born, Jens; Holm-Nielsen, Jens Bo

    2015-02-01

    This study aimed to investigate the feasibility of substitute natural gas (SNG) generation using biogas from anaerobic digestion and hydrogen from renewable energy systems. Using thermodynamic equilibrium analysis, kinetic reactor modeling and transient simulation, an integrated approach for the operation of a biogas-based Sabatier process was put forward, which was then verified using a lab scale heterogenous methanation reactor. The process simulation using a kinetic reactor model demonstrated the feasibility of the production of SNG at gas grid standards using a single reactor setup. The Wobbe index, CO2 content and calorific value were found to be controllable by the H2/CO2 ratio fed the methanation reactor. An optimal H2/CO2 ratio of 3.45-3.7 was seen to result in a product gas with high calorific value and Wobbe index. The dynamic reactor simulation verified that the process start-up was feasible within several minutes to facilitate surplus electricity use from renewable energy systems.

  3. Numerical study on the combustion process of a biogas spark-ignition engine

    Directory of Open Access Journals (Sweden)

    Carrera José L.

    2013-01-01

    Full Text Available The fuel called biogas is obtained through anaerobic digestion of different types of organic waste, providing a way to tap the energy stored in organic matter. The use of this fuel is also attractive from the standpoint of global warming because its application does not register a net emission of carbon dioxide into the atmosphere. One possible use for this fuel is to feed the spark-ignition internal combustion engines. In the present, there is little information available about the process of combustion in internal combustion engines fueled by biogas. The combustion process of an internal combustion engine ignition powered by biogas is characterized in terms of the duration of combustion, i.e., depending on the time elapsed while the reactants (methane and oxygen are transformed into products (mainly carbon dioxide and water. This study numerically evaluates the way in which the geometrical parameters such as the compression ratio and operating parameters like engine speed, the excess air, the time of spark timing and carbon dioxide content of biogas affect the evolution of the combustion process. To carry out this study, a five factors and two levels experiment was designed and conducted, based on which, the most influential parameters were identified. Equations expressing the combustion characteristic parameters, as a function of the geometric and operation parameters of a spark ignited engines, are delivered as a result.

  4. A new multiple-stage electrocoagulation process on anaerobic digestion effluent to simultaneously reclaim water and clean up biogas.

    Science.gov (United States)

    Liu, Zhiguo; Stromberg, David; Liu, Xuming; Liao, Wei; Liu, Yan

    2015-03-21

    A new multiple-stage treatment process was developed via integrating electrocoagulation with biogas pumping to simultaneously reclaim anaerobic digestion effluent and clean up biogas. The 1st stage of electrocoagulation treatment under the preferred reaction condition led to removal efficiencies of 30%, 81%, 37% and >99.9% for total solids, chemical oxygen demand, total nitrogen and total phosphorus, respectively. Raw biogas was then used as a reactant and pumped into the effluent to simultaneously neutralize pH of the effluent and remove H2S in the biogas. The 2nd stage of electrocoagulation treatment on the neutralized effluent showed that under the selected reaction condition, additional 60% and 10% of turbidity and chemical oxygen demand were further removed. The study concluded a dual-purpose approach for the first time to synergistically combine biogas purification and water reclamation for anaerobic digestion system, which well addresses the downstream challenges of anaerobic digestion technology.

  5. Hygiene Aspects of the Biogas Process with Emphasis on Spore-Forming Bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Bagge, Elisabeth

    2009-07-01

    Biogas is a renewable source of energy which can be obtained from processing of biowaste. The digested residues can be used as fertiliser. Biowaste intended for biogas production contains pathogenic micro-organisms. A pre-pasteurisation step at 70 deg C for 60 min before anaerobic digestion reduces non spore-forming bacteria such as Salmonella spp. To maintain the standard of the digested residues it must be handled in a strictly hygienic manner to avoid recontamination and re-growth of bacteria. The risk of contamination is particularly high when digested residues are transported in the same vehicles as the raw material. However, heat treatment at 70 deg C for 60 min will not reduce spore-forming bacteria such as Bacillus spp. and Clostridium spp. Spore-forming bacteria, including those that cause serious diseases, can be present in substrate intended for biogas production. The number of species and the quantity of Bacillus spp. and Clostridium spp. in manure, slaughterhouse waste and in samples from different stages during the biogas process were investigated. The number of species of clostridia seemed to decrease following digestion, likewise the quantity. However, Bacillus spp. seemed to pass unaffected through the biogas process. In laboratory-scale experiments the effects on clostridia during pasteurisation and digestion were investigated. Pathogenic clostridia were inoculated in substrates from homogenisation tanks and digester tanks. The inoculated clostridia remained after pasteurisation, but the impacts of digestion differ between different species. Culture followed by identification of C. chauvoei by PCR in samples from cattle died from blackleg, is faster and safer than culture followed by biochemical identification of C. chauvoei. However, for environmental samples the PCR method is not practically applicable for detection of C. chauvoei. To avoid spreading of diseases via biogas plants when digested residues are spread on arable land, a pasteurisation

  6. Characterisation and treatment of VOCs in process water from upgrading facilities for compressed biogas (CBG).

    Science.gov (United States)

    Nilsson Påledal, S; Arrhenius, K; Moestedt, J; Engelbrektsson, J; Stensen, K

    2016-02-01

    Compression and upgrading of biogas to vehicle fuel generates process water, which to varying degrees contains volatile organic compounds (VOCs) originating from the biogas. The compostion of this process water has not yet been studied and scientifically published and there is currently an uncertainty regarding content of VOCs and how the process water should be managed to minimise the impact on health and the environment. The aim of the study was to give an overview about general levels of VOCs in the process water. Characterisation of process water from amine and water scrubbers at plants digesting waste, sewage sludge or agricultural residues showed that both the average concentration and composition of particular VOCs varied depending on the substrate used at the biogas plant, but the divergence was high and the differences for total concentrations from the different substrate groups were only significant for samples from plants using waste compared to residues from agriculture. The characterisation also showed that the content of VOCs varied greatly between different sampling points for same main substrate and between sampling occasions at the same sampling point, indicating that site-specific conditions are important for the results which also indicates that a number of analyses at different times are required in order to make an more exact characterisation with low uncertainty. Inhibition of VOCs in the anaerobic digestion (AD) process was studied in biomethane potential tests, but no inhibition was observed during addition of synthetic process water at concentrations of 11.6 mg and 238 mg VOC/L.

  7. Insights into siloxane removal from biogas in biotrickling filters via process mapping-based analysis.

    Science.gov (United States)

    Soreanu, Gabriela

    2016-03-01

    Data process mapping using response surface methodology (RSM)-based computational techniques is performed in this study for the diagnosis of a laboratory-scale biotrickling filter applied for siloxane (i.e. octamethylcyclotetrasiloxane (D4) and decamethylcyclopentasiloxane (D5)) removal from biogas. A mathematical model describing the process performance (i.e. Si removal efficiency, %) was obtained as a function of key operating parameters (e.g biogas flowrate, D4 and D5 concentration). The contour plots and the response surfaces generated for the obtained objective function indicate a minimization trend in siloxane removal performance, however a maximum performance of approximately 60% Si removal efficiency was recorded. Analysis of the process mapping results provides indicators of improvement to biological system performance.

  8. Supplying the energy demand in the chicken meat processing poultry with biogas

    Directory of Open Access Journals (Sweden)

    Adriano Henrique Ferrarez

    2016-04-01

    Full Text Available The main use of electrical energy in the chicken meat processing unit is refrigeration. About 70% of the electricity is consumed in the compressors for the refrigeration system. Through this study, the energetic viability of using biogas from poultry litter in supplying the demand for the refrigeration process was found. The meat processing unit studied has the potential to process about a hundred and sixty thousand chickens a day. The potential biogas production from poultry litter is 60,754,298.91 m3.year-1. There will be a surplus of approximately 8,103MWh per month of electric energy generated from biogas. An economic analysis was performed considering a planning horizon of 20 years and the discount rate of 12% per year. The economic analysis was performed considering scenario 1: sale of all electricity generated by the thermoelectric facility, and scenario 2: sale of the surplus electricity generated after complying with the demands of the refrigeration process and all other electrical energy and thermal energy use. Economic indicators obtained for scenarios 1 and 2 were favorable for the project implementation.

  9. An Analysis of Biogas Reforming Process on Ni/YSZ and Ni/SDC Catalysts

    Directory of Open Access Journals (Sweden)

    Janusz Szmyd

    2012-02-01

    Full Text Available The conversion of biogas to electricity presents an attractive niche application for fuel cells. Thus attempts have been made to use biogas as a fuel for high temperature fuel cell systems such as SOFC. Biogas can be converted to hydrogen-rich fuel in a reforming process. For hydrocarbon-based fuel, three types of fuel conversion can be considered in reforming reactions: an external reforming system, an indirect internal reforming system and a direct internal reforming system. High-temperature SOFC eliminates the need for an expensive external reforming system. The possibility of using internal reforming is one of the characteristics of high temperature fuel cells like SOFC. However, for high-temperature operation, thermal management of the SOFC system becomes an important issue. To properly carry out thermal management, both detailed modeling and numerical analyses of the phenomena occurring inside the SOFC system is required. In the present work, the process of reforming biogas on a Ni/YSZ and a Ni/SDC catalyst has been numerically and experimentally investigated. Measurements including different thermal boundary conditions, steam-to-carbon ratios and several different fuel compositions were taken. A numerical model containing methane/steam reforming reaction, dry reforming reaction and shift reaction has been proposed to predict the gas mixture composition at the outlet of the reformer. The results of the numerical computation were compared with experimental data and good agreement has been found. The results indicate the importance of combined, numerical and experimental studies in the design of SOFC reformers. The combined approach used leads to the successful prediction of the outlet gas composition for different modelling conditions.

  10. Colloidal processing of porous membranes for biogas lighting; Processamento coloidal de membranas porosas para iIluminacao por biogas

    Energy Technology Data Exchange (ETDEWEB)

    Santos, S.C.; Mello-Castanho, S.R.H., E-mail: silascs@ipen.br, E-mail: srmello@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo (Brazil)

    2011-07-01

    Nowadays the urban garbage is a great economic and environmental challenge in the whole world. Solid wastes stored in continuous form in landfills are subject of natural variables, transforming them (by bioconversion) in biogas which can be used as energy font in many applications as urban lighting. However, technology to produce it has not been stabilized in Brazil yet. So, in this work porous membranes of rare earth -yttria concentrate (Ctr-Y) with potential to be used as biogas mantles were produced by replica method. The effect of solids and binder concentration on rheological behavior of Ctr-Y suspensions were evaluated by flux curves. According to the results, suspensions with 25vol% and 0,2wt% of CMC showed adequated viscosity and rheological behavior (thixotropy) for replica method. Sintered samples presented the same morphology of template and good handle strength. (author)

  11. Microbiology and Molecular Biology Tools for Biogas Process Analysis, Diagnosis and Control.

    Science.gov (United States)

    Lebuhn, Michael; Weiß, Stefan; Munk, Bernhard; Guebitz, Georg M

    2015-01-01

    Many biotechnological processes such as biogas production or defined biotransformations are carried out by microorganisms or tightly cooperating microbial communities. Process breakdown is the maximum credible accident for the operator. Any time savings that can be provided by suitable early-warning systems and allow for specific countermeasures are of great value. Process disturbance, frequently due to nutritional shortcomings, malfunction or operational deficits, is evidenced conventionally by process chemistry parameters. However, knowledge on systems microbiology and its function has essentially increased in the last two decades, and molecular biology tools, most of which are directed against nucleic acids, have been developed to analyze and diagnose the process. Some of these systems have been shown to indicate changes of the process status considerably earlier than the conventionally applied process chemistry parameters. This is reasonable because the triggering catalyst is determined, activity changes of the microbes that perform the reaction. These molecular biology tools have thus the potential to add to and improve the established process diagnosis system. This chapter is dealing with the actual state of the art of biogas process analysis in practice, and introduces molecular biology tools that have been shown to be of particular value in complementing the current systems of process monitoring and diagnosis, with emphasis on nucleic acid targeted molecular biology systems.

  12. BIOGAS TECHNOLOGY

    Directory of Open Access Journals (Sweden)

    D.B. SALUNKHE

    2012-12-01

    Full Text Available Due to scarcity of petroleum and coal it threatens supply of fuel throughout the world also problem of their combustion leads to research in different corners to get access the new sources of energy, like renewable energy resources. Solar energy, wind energy, different thermal and hydro sources of energy, biogas are all renewable energy resources. But, biogas is distinct from other renewable energies because of its characteristics of using, controlling and collecting organic wastes and at the same time producing fertilizer and water for use in agricultural irrigation. Biogas does not have any geographical limitations nor does it require advanced technology for producing energy, also it is very simple to use and apply. Anaerobic digestion is controlled biological degradation process which allows efficient capturing & utilization of biogas (approximately 60% methane and 40% carbon dioxide for energy generation. Anaerobic digestion of food waste is achievable but different types, composition of food waste results in varying degrees of methane yields, and thus the effects of mixing various types of food waste and their proportions should be determined on case by case basis.

  13. Biogas charging and dissipating process and its accumulation in the Sebei gasfield,Qaidam Basin,China

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The Sebei gasfield is the largest biogas accumulation found in China and many reservoirs and seal rocks superposed on a syndepositional anticline in Quaternary.The biogas charging and dissipating process and its distribution have been a research focus for many years.The authors suggest a diffusing and accumulating model for the biogas,as they find that the shallower the gas producer,the more methane in the biogas,and the lighter stable carbon isotope composition of methane.Based on the diffusing model,diffused biogas is quantitatively estimated for each potential sandy reservoir in the gasfield,and the gas charging quantity for the sandy reservoir is also calculated by the diffused gas quantity plus gas reserve in-place.A ratio of diffusing quantity to charging quantity is postulated to describe biogas accumulating state in a sandy reservoir,if the ratio is less than 0.6,the reservoir forms a good gas-pool and high-production layer in the gasfield,which often occurs in the reservoirs deeper than 900 m;if the ratio is greater than 0.6,a few gas accumulated in the reservoir,which frequently exists in the reservoirs shallower than 900 m.Therefore,a biogas accumulation model is built up as lateral direct charging from gas source for the sands deeper than 900 m and indirect charging from lower gas-bearing sands by diffusion at depth shallower than 900 m.With this charging and diffusion quantitative model,the authors conducted re-evaluation on each wildcat in the central area of the Qaidam Basin,and found many commercial biogas layers.

  14. The formation of propionate and acetate as terminal processes in the energy metabolism of the adult liver fluke Fasciola hepatica

    NARCIS (Netherlands)

    Vugt, F. van; Meer, P. van der; Bergh, S.G. van den

    1979-01-01

    1. 1. The formation of propionate from succinate occurs in the mitochondria of the adult common liver fluke essentially by a reversal of the pathway operating in mammalian mitochondria in the conversion of propionate into succinate. 2. 2. The conversion of succinate into its CoA ester is linked by

  15. Development of an in-line process viscometer for the full-scale biogas process.

    Science.gov (United States)

    Mönch-Tegeder, Matthias; Lemmer, Andreas; Hinrichs, Jörg; Oechsner, Hans

    2015-02-01

    An in-line viscometer was developed to determine the rheological properties of biogas slurries at a full-scale biogas plant. This type of viscometer allows the investigation of flow characteristics without additional pretreatment and has many advantageous aspects in contrast to the rotational viscometer. Various effects were studied: alterations in the feedstock structure, increasing total solid (TS) of the slurry and the disintegration of the feedstock on the rheological properties. The results indicate that the Power-Law model is sufficient for the description of the flow curve of biogas slurries. Furthermore, the use of more fibrous materials increases in viscosity. The increase in TS of 10.1-15.1% resulted in a sharp increase of the viscosity. The mechanical disintegration of the feedstock positively influenced the rheological properties, but the effects were more apparent at higher TS.

  16. Effects of chemical compositions and ensiling on the biogas productivity and degradation rates of agricultural and food processing by-products.

    Science.gov (United States)

    Kafle, Gopi Krishna; Kim, Sang Hun

    2013-08-01

    The objective of this study was to investigate the effects of chemical compositions and ensiling on the biogas productivity and degradation rates of agricultural and food processing by-products (AFPBPs) using the biogas potential test. The AFPBPs were classified based on their chemical compositions (i.e., carbohydrate, protein and fat contents). The biogas and methane potentials of AFPBPs were calculated to range from 450 to 777 mL/g volatile solids (VS) and 260-543 mL/g VS, respectively. AFPBPs with high fat and protein contents produced significantly higher amounts of biogas than AFPBPs with high carbohydrate and low fat contents. The degradation rate was faster for AFPBPs with high carbohydrate contents compared to AFPBPs with high protein and fat contents. The lag phase and biogas production duration were lower when using ensiled AFPBPs than when using nonsilage AFPBPs. Among the four different silages tested, two silages significantly improved biogas production compared to the nonsilage AFPBPs.

  17. Process for increased biogas production and energy efficient hygienisation of sludge; Process foer oekad biogasproduktion och energieffektiv hygienisering av slam

    Energy Technology Data Exchange (ETDEWEB)

    Rogstrand, Gustav; Olsson, Henrik; Andersson Chan, Anneli; Johansson, Niklas; Edstroem, Mats

    2012-07-01

    In Sweden there is a need to increase biogas production to meet the rising demand for biomethane as vehicle fuel but the amount of domestically available biomass to digest is limited. One way to help meet current and future demand for methane is to enhance the digestion of the substrates that are currently utilized. Vaexjoe municipality in southern Sweden is in the process of upgrading their facilities for biogas production at the Sundet waste water treatment plant. Their aim is to produce more biogas in order to meet the demand from an increasing methane-based local transit fleet. This is the backdrop to a joint project between JTI and Vaexjoe municipality where JTI's mobile pilot plant was used to study the possibility of extracting more biogas from the existing sewage sludge. In the future, Vaexjoe municipality also plans to co-digest source separated municipal organics with the sewage sludge, which will likely result in stricter demands in terms of hygienization of all utilized substrates. The goal of the project at hand was to demonstrate the possibility to produce more than enough additional biogas from existing sewage sludge to yield a net energy profit even with the added energy demand of ensuring the hygienic quality of the digestate through conventional pasteurization. Although the project was focused on the conditions at Sundet waste water treatment plant, the issues dealt with are general and the results are relevant to many waste water treatment plants in Sweden. The research, conducted between June 2011 and January 2012 were divided into two trials. The two trials, described schematically in Figure 1, represented two possible process configurations designed to reach the goal stated above. The key component of both process configurations is the addition of a post-digestion step to the existing single-step digestion process. In trial 1 the additional feature of dewatering between the two digestion steps served to reduce energy demand for

  18. Solid-state anaerobic co-digestion of hay and soybean processing waste for biogas production.

    Science.gov (United States)

    Zhu, Jiying; Zheng, Yi; Xu, Fuqing; Li, Yebo

    2014-02-01

    Co-digestion of soybean processing waste (SPW) and hay in solid-state anaerobic digestion (SS-AD) for biogas production was investigated. Effects of the SPW to hay ratio, feedstock to effluent (inoculum) ratio, premixing of effluent with feedstock, and leachate recirculation on biogas production via SS-AD were studied. The highest methane yield of 258 L/kg VS was obtained with a SPW/hay ratio of 75:25 and feedstock/effluent (F/E) ratio of 3, which was 148% and 50% higher than that of 100% SPW and 100% hay, respectively. Increasing the F/E ratio from 1 to 5 decreased methane yield, however the highest volumetric methane yield (16.2L/L reactor) was obtained at an F/E of 3. There was no significant difference in methane yields between premixing 50% and 100% of the effluent. Leachate recirculation significantly accelerated the SS-AD start-up process when effluent was not completely premixed.

  19. Farm Biogas Handbook; Gaardsbiogashandbok

    Energy Technology Data Exchange (ETDEWEB)

    Christensson, Kjell; Bjoernsson, Lovisa; Dahlgren, Stefan; Eriksson, Peter; Lantz, Mikael; Lindstroem, Johanna; Mickelaaker, Maria

    2009-04-15

    A very large share of the total raw material potential for biogas production will be found within the agriculture. The raw material potential of manure in Sweden amounts to 4 - 6 TWh. Within the agriculture there is moreover a big potential in the form of residues from plant cultivation and non-food crops (approximately 7 TWh) that can to be used for biogas production. The potential for biogas production from only residues and manure is around 8-10 TWh. An increased biogas production within the agriculture would give significant environmental effects. Among other things manure, that today is leaking methane gas to the atmosphere, can be fermented, and trough this process the methane losses will be reduced. When the produced biogas replaces fossil fuel, an overall environmental effect will be reached, that is highly significant. This manual deals with biogas plants for agriculture and such plants that do not have extensive transports of different raw materials, as manure, wastes etc. One of the starting points for this manual's set-up is a course plan that Biogas Syd made for the courses they give to farmers, advisors and others. The manual illustrates important aspects in planning and construction of biogas plants, from raw material and technology to dimensioning of plant, use of biogas and planning of local gas grids. We also think it is important to illustrate the legislation that encompasses construction work and operation of a biogas plant. Investment costs are also illustrated, but the book does not give any extensive economic calculations, since we believe that such calculations need their own manual in the form of calculation examples, based on various conditions. The final section is called 'Biogas on farm - from idea to reality' where the entire process from analysis and pre-planning to monitoring and control of plant during operation is briefly described

  20. A novel process for ethanol or biogas production from cellulose in blended-fibers waste textiles.

    Science.gov (United States)

    Jeihanipour, Azam; Karimi, Keikhosro; Niklasson, Claes; Taherzadeh, Mohammad J

    2010-12-01

    A novel process has been developed for separation of the cellulose, i.e. cotton and viscose, from blended-fibers waste textiles. An environmentally friendly cellulose solvent, N-methylmorpholine-N-oxide (NMMO) was used in this process for separation and pretreatment of the cellulose. This solvent was mixed with blended-fibers textiles at 120 °C and atmospheric pressure to dissolve the cellulose and separate it from the undissolved non-cellulosic fibers. Water was then added to the solution in order to precipitate the cellulose, while both water and NMMO were reused after separation by evaporation. The cellulose was then either hydrolyzed by cellulase enzymes followed by fermentation to ethanol, or digested directly to produce biogas. The process was verified by testing 50/50 polyester/cotton and 40/60 polyester/viscose-blended textiles. The polyesters were purified as fibers after the NMMO treatments, and up to 95% of the cellulose fibers were regenerated and collected on a filter. A 2-day enzymatic hydrolysis and 1-day fermentation of the regenerated cotton and viscose resulted in 48 and 50 g ethanol/g regenerated cellulose, which were 85% and 89% of the theoretical yields, respectively. This process also resulted in a significant increase of the biogas production rate. While untreated cotton and viscose fibers were converted to methane by respectively, 0.02% and 1.91% of their theoretical yields in 3 days of digestion, the identical NMMO-treated fibers resulted into about 30% of yield at the same period of time.

  1. DEVELOPMENT TRENDS OF BIOGAS

    Directory of Open Access Journals (Sweden)

    Mariana DUMITRU

    2015-04-01

    Full Text Available All over the world, researches are made in order to improve the technologies, the operational and process stability and performance of biogas plants, because the world markets for biogas increased considerably in Europe and all over the world. In this paper we studied the most important parameters related to a biogas plant, starting from the ecologic landfill of Cristian, Sibiu, a landfill which storages industrial and household waste. In this respect, we studied operational parameters, such as organic load and hydraulic retention time, and parameters for evaluation of a biogas plant. Also, we made a case study concerning the evaluation of used waters in the landfill described above under the aspect of pollution sources, way of treatment and evacuation mode of used waters. The existing biomass resources everywhere in the world can give us an idea of the global potential of biogas production, which is not exploited to its capacity, especially in our country.

  2. Use of the Sabatier Process for Dynamic Biogas Upgrading in Northern Germany

    DEFF Research Database (Denmark)

    Jurgensen, Lars; Ehimen, Ehiazesebhor Augustine; Born, Jens

    2014-01-01

    Approximately 8000 farm scale biogas plants are present in Germany which produce electricity (mainly using energy crops as substrates) . The potential role of biogas plants in energy systems penetrated by high amounts of fluctuating renewable energy production is discussed in this paper. Today th...

  3. Process control of anaerobic biogas fermentation. Process control systems based on microcontroller based computational intelligence; Prozessfuehrung der anaerobe Biogasfermentation. Prozessfuehrungssysteme auf Basis mikrocontrollerbasierter Computational Intelligence

    Energy Technology Data Exchange (ETDEWEB)

    Kramer, K.D. [Hochschule Harz, Wernigerode (Germany); Patzwahl, S.; Nacke, T.

    2005-07-01

    This article presents three system variants for the process control and monitoring of anaerobic biogas fermentation. All three systems were created using a self-developed software called ''EmCoSoft'' and a design process and were tested as microcontroller-based solutions. Strategies of computational intelligence (including Fuzzy Logic and Artificial Neuronal Networks) were considered most suitable for generating system core algorithms and were put to use. Experiments for generating process data and test sequences for each of the system variants were performed on well-equipped laboratory biogas plants.

  4. Stable isotope composition of biogas allows early warning of complete process failure as a result of ammonia inhibition in anaerobic digesters.

    Science.gov (United States)

    Lv, Zuopeng; Hu, Meng; Harms, Hauke; Richnow, Hans Hermann; Liebetrau, Jan; Nikolausz, Marcell

    2014-09-01

    Four 15-L lab-scale continuous stirred tank reactors were operated under mesophilic conditions to investigate the effect of ammonia inhibition. Stable isotope fingerprinting of biogas was applied as a process monitoring tool. Ammonia inhibition was initiated by amendment of chicken manure to maize silage fed reactors. During the accumulation of ammonia, the concentration of volatile fatty acids increased while the biogas production and pH decreased. However, in one reactor, an inhibited steady state with stable gas production even at high ammonia levels was achieved, while the other reactor proceeded to complete process failure. A depletion of the δ(13)CH4 and δ(13)CO2 values preceded the process inhibition. Moreover, the stable isotope composition of biogas also forecasted the complete process failure earlier than other standard parameters. The stable isotope analyses of biogas have a potential for mechanistic insights in anaerobic processes, and may be used to pre-warn process failure under stress conditions.

  5. Improvement of a grass-clover silage-fed biogas process by the addition of cobalt

    Energy Technology Data Exchange (ETDEWEB)

    Jarvis, A.; Jarlsvik, T. [Swedish Univ. of Agricultual Sciences, Uppsala (Sweden). Dept. of Microbiology; Mathisen, B. [Swedish Inst. of Agricultural Engineering, Uppsala (Sweden)] Svensson, B.H. [Linkoeping Univ. (Sweden). Dept. of Water and Environmental Studies

    1997-12-31

    Batch assays were performed with samples from a silage-fed mesophilic biogas process accumulating acetate to examine if the addition of single trace elements (iron, nickel, cobalt and molybdenum) or a mixture of trace elements could improve the process. The results from the batch assays led to the addition of cobalt to reach a concentration of 0.2 mg L{sup -1}. This made it possible to increase the organic loading rate (OLR) above that in a parallel process not receiving any extra cobalt. Problems with low gas production and decreasing pH were overcome by the daily supply of this single element in small amounts. Acetate conversion to methane was improved, which was confirmed by increased specific methanogenic activity (SMA) with acetate as a substrate. As a consequence, an OLR of 7.0 g VS L{sup -1} was achieved at a hydraulic retention time (HRT) of 20 days with an equivalent increase in methane production. Without cobalt addition, an OLR of 5.0 g VS L{sup -1} day{sup -1} with an HRT of 20 days was reached after 70 weeks operation. (Author)

  6. An innovative bioelectrochemical-anaerobic digestion-coupled system for in-situ ammonia recovery and biogas enhancement: process performance and microbial ecology

    OpenAIRE

    Zhang, Yifeng; Angelidaki, Irini

    2014-01-01

    Ammonia (NH4+/NH3) inhibition during anaerobic digestion process is one of the most frequent problems existing in biogas plants, resulting in unstable process and reduced biogas production. In this study, we developed a novel hybrid system, consisted of a submersed microbial resource recovery cell (SMRC) and a continuous stirred tank reactor (CSTR), to prevent ammonia toxicity during anaerobic digestion by in-situ ammonia recovery and electricity production. In batch experiment, the ammonia c...

  7. Enhancing the hydrolysis process of a two-stage biogas technology for the organic fraction of municipal solid waste

    DEFF Research Database (Denmark)

    Nasir, Zeeshan; Uellendahl, Hinrich

    2015-01-01

    the hydrolytic (1st) stage, which enables pump-free feeding of the waste into the 1st stage (processing module), and eliminates the risk for blocking of pumps and pipes by pumping only the percolate from the 1st stage into the 2nd stage (biogas reactor tank). The biogas yield of the AIKAN® two-stage process...... as lab-scale batch and pilot-scale reactor tests. A lab-scale reactor system to mimic the 2-stage set-up in large-scale is currently set-up and the results will be included in the final conference paper. The first pilot-scale tests were performed at Solum’s pilot-scale modules by adjusting the p...

  8. A combined process to treat lemon industry wastewater and produce biogas

    Energy Technology Data Exchange (ETDEWEB)

    Navarro, A.R.; Rubio, M.C.; Maldonado, M.C. [Quimica y Farmacia, Universidad Nacional de Tucuman, Instituto de Biotecnologia, Facultad de Bioquimica, Ayacucho, Tucuman (Argentina)

    2012-02-15

    We studied a process employed for treating lemon industry effluents, using the macrophyte Eishhornia crassipes (water hyacinth) in a phytoremediation tank with a 6000-L workload. The diluted effluents BOD and COD were reduced to 70 and 61%, respectively, working with a 1.5-h hydraulic residence time (HRT). We investigated the effect of adding every 12 h an inoculum consisting of a consortium of microorganisms isolated from the macrophyte roots and recirculating 30% of the outflow. In this way, we achieved a volumetric removal rate (VRR) of BOD = 354 g/m{sup 3} day. Plants were daily harvested from the tank to maintain growth rate and the density originally planted. We studied their use for biogas production in an anaerobic digester working with 12 and 16 days of hydraulic residence time. The yield obtained was 0.87 L/g and productivity 0.87 L/L day with a loading rate of 5 g/L day. Integrating both processes on an industrial scale would solve the effluent pollution problem and generate an energy source that could be used by the industry itself to lower its production costs. (orig.)

  9. Estimation of biogas and methane yields in an UASB treating potato starch processing wastewater with backpropagation artificial neural network.

    Science.gov (United States)

    Antwi, Philip; Li, Jianzheng; Boadi, Portia Opoku; Meng, Jia; Shi, En; Deng, Kaiwen; Bondinuba, Francis Kwesi

    2017-03-01

    Three-layered feedforward backpropagation (BP) artificial neural networks (ANN) and multiple nonlinear regression (MnLR) models were developed to estimate biogas and methane yield in an upflow anaerobic sludge blanket (UASB) reactor treating potato starch processing wastewater (PSPW). Anaerobic process parameters were optimized to identify their importance on methanation. pH, total chemical oxygen demand, ammonium, alkalinity, total Kjeldahl nitrogen, total phosphorus, volatile fatty acids and hydraulic retention time selected based on principal component analysis were used as input variables, whiles biogas and methane yield were employed as target variables. Quasi-Newton method and conjugate gradient backpropagation algorithms were best among eleven training algorithms. Coefficient of determination (R(2)) of the BP-ANN reached 98.72% and 97.93% whiles MnLR model attained 93.9% and 91.08% for biogas and methane yield, respectively. Compared with the MnLR model, BP-ANN model demonstrated significant performance, suggesting possible control of the anaerobic digestion process with the BP-ANN model.

  10. A study of the Apollo aqueous redox process for converting hydrogen sulfide in biogas to elemental sulfur

    Energy Technology Data Exchange (ETDEWEB)

    Ellenor, D.T.

    2004-07-01

    An experimental study was conducted to develop a commercial biogas scrubber for municipal and agricultural use. The specific objectives were to provide design and scaling parameters that would improve the performance while minimizing the capital and operating costs of the biogas scrubber; provide a useful reaction model of the aqueous phase iron chelate catalyzed oxide of hydrogen sulfide to elemental sulfur; develop hypotheses and determine what data are of relevance in comprehending the interfacial phenomena of colloidal sulfur in aqueous solutions that could result in unwanted sulfur deposition and poor sulfur quality; obtain interfacial chemistry data that could improve the understanding of how sulfur particles behave during flocculation and deposition on surfaces, and the factors that lead to poor surface quality; and, determine whether crystal size and characteristics of deposited and flocculated sulfur could be changed by surfactants to enhance sulfur purity and reduce process operability. Interfacial chemistry experiments were performed to determine the factors that influence the operating problems and poor quality associated with the sulfur product. Results suggest that a low foaming nonionic surfactant can improve the quality and processability of the elemental sulfur product. It was concluded that the addition of surfactant to the redox solution reduces the mean hydrogen removal efficiency of the process. The addition of surfactants also decreases the mean particle size of the precipitated sulfur product, but increases the purity of the precipitated product. This study contributed to the successful installation by Apollo Environmental Systems of a commercial biogas scrubber that is very resistant to sulfur plugging.

  11. Increasing biogas production from sewage sludge anaerobic co-digestion process by adding crude glycerol from biodiesel industry.

    Science.gov (United States)

    Nartker, Steven; Ammerman, Michelle; Aurandt, Jennifer; Stogsdil, Michael; Hayden, Olivia; Antle, Chad

    2014-12-01

    In an effort to convert waste streams to energy in a green process, glycerol from biodiesel manufacturing has been used to increase the gas production and methane content of biogas within a mesophilic anaerobic co-digestion process using primary sewage sludge. Glycerol was systematically added to the primary digester from 0% to 60% of the organic loading rate (OLR). The optimum glycerol loading range was from 25% to 60% OLR. This resulted in an 82-280% improvement in specific gas production. Following the feeding schedule described, the digesters remained balanced and healthy until inhibition was achieved at 70% glycerol OLR. This suggests that high glycerol loadings are possible if slow additions are upheld in order to allow the bacterial community to adjust properly. Waste water treatment plant operators with anaerobic digesters can use the data to increase loadings and boost biogas production to enhance energy conversion. This process provides a safe, environmentally friendly method to convert a typical waste stream to an energy stream of biogas.

  12. Changing Feeding Regimes To Demonstrate Flexible Biogas Production: Effects on Process Performance, Microbial Community Structure, and Methanogenesis Pathways.

    Science.gov (United States)

    Mulat, Daniel Girma; Jacobi, H Fabian; Feilberg, Anders; Adamsen, Anders Peter S; Richnow, Hans-Hermann; Nikolausz, Marcell

    2015-10-23

    Flexible biogas production that adapts biogas output to energy demand can be regulated by changing feeding regimes. In this study, the effect of changes in feeding intervals on process performance, microbial community structure, and the methanogenesis pathway was investigated. Three different feeding regimes (once daily, every second day, and every 2 h) at the same organic loading rate were studied in continuously stirred tank reactors treating distiller's dried grains with solubles. A larger amount of biogas was produced after feeding in the reactors fed less frequently (once per day and every second day), whereas the amount remained constant in the reactor fed more frequently (every 2 h), indicating the suitability of the former for the flexible production of biogas. Compared to the conventional more frequent feeding regimes, a methane yield that was up to 14% higher and an improved stability of the process against organic overloading were achieved by employing less frequent feeding regimes. The community structures of bacteria and methanogenic archaea were monitored by terminal restriction fragment length polymorphism (T-RFLP) analysis of 16S rRNA and mcrA genes, respectively. The results showed that the composition of the bacterial community varied under the different feeding regimes, and the observed T-RFLP patterns were best explained by the differences in the total ammonia nitrogen concentrations, H2 levels, and pH values. However, the methanogenic community remained stable under all feeding regimes, with the dominance of the Methanosarcina genus followed by that of the Methanobacterium genus. Stable isotope analysis showed that the average amount of methane produced during each feeding event by acetoclastic and hydrogenotrophic methanogenesis was not influenced by the three different feeding regimes.

  13. Design and scale-up of an oxidative scrubbing process for the selective removal of hydrogen sulfide from biogas

    Energy Technology Data Exchange (ETDEWEB)

    Krischan, J., E-mail: jutta_krischan@hotmail.com [Vienna University of Technology, Institute of Chemical Engineering, Getreidemarkt 9/166, 1060 Vienna (Austria); Makaruk, A., E-mail: aleksander.makaruk@tuwien.ac.at [Vienna University of Technology, Institute of Chemical Engineering, Getreidemarkt 9/166, 1060 Vienna (Austria); Harasek, M., E-mail: michael.harasek@tuwien.ac.at [Vienna University of Technology, Institute of Chemical Engineering, Getreidemarkt 9/166, 1060 Vienna (Austria)

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer Alkaline oxidative scrubbing proved for biogas desulfurization Black-Right-Pointing-Pointer Effect of operating conditions on hydrogen sulfide removal efficiency. Black-Right-Pointing-Pointer Minimization of caustic and oxidant consumption. Black-Right-Pointing-Pointer Process control via pH, redox potential and conductivity measurement. Black-Right-Pointing-Pointer Investigation of long-term behavior of pilot plant operation. - Abstract: Reliable and selective removal of hydrogen sulfide (H{sub 2}S) is an essential part of the biogas upgrading procedure in order to obtain a marketable and competitive natural gas substitute for flexible utilization. A promising biogas desulfurization technology has to ensure high separation efficiency regardless of process conditions or H{sub 2}S load without the use or production of toxic or ecologically harmful substances. Alkaline oxidative scrubbing is an interesting alternative to existing desulfurization technologies and is investigated in this work. In experiments on a stirred tank reactor and a continuous scrubbing column in laboratory-scale, H{sub 2}S was absorbed from a gas stream containing large amounts of carbon dioxide (CO{sub 2}) into an aqueous solution prepared from sodium hydroxide (NaOH), sodium bicarbonate (NaHCO{sub 3}) and hydrogen peroxide (H{sub 2}O{sub 2}). The influence of pH, redox potential and solution aging on the absorption efficiency and the consumption of chemicals was investigated. Because of the irreversible oxidation reactions of dissolved H{sub 2}S with H{sub 2}O{sub 2}, high H{sub 2}S removal efficiencies were achieved while the CO{sub 2} absorption was kept low. At an existing biogas upgrading plant an industrial-scale pilot scrubber was constructed, which efficiently desulfurizes 180 m{sup 3}/h of raw biogas with an average removal efficiency of 97%, even at relatively high and strongly fluctuating H{sub 2}S contents in the crude gas.

  14. District heating for increased biogas production. Technical and economical evaluation of district heating as heating source in biogas processes; Fjaerrvaerme foer utoekad biogasproduktion. Teknisk och ekonomisk utvaerdering av fjaerrvaerme foer uppvaermning av biogasprocesser

    Energy Technology Data Exchange (ETDEWEB)

    Lundqvist, Per (AaF-Consult AB, Stockholm (Sweden))

    2009-11-15

    This report presents a technical evaluation, the potential and an economical evaluation of the increased net biogas production by using district heating as energy supply for different types of biogas production units. The study presents generalized results for different plant sizes. The district heating is considered as replacement of the heat produced by burning biogas in a hot-water boiler. Hence more biogas could be available for upgrading to fuel-gas quality to be used in vehicles as a renewable fuel. The study is aimed at biogas producers, district heating and combined heat and power (CHP) companies. Biogas has a composition of mostly methane (about 65 %) and carbon dioxide (about 35 %) and small amounts of other gases e.g. sulphur dioxide (H{sub 2}S). Biogas up-grading is a process where the methane content is increased to about 97 % by removing most of the other gases in e.g. an absorption unit. The Swedish biogas is mainly produced in several sewage treatment plants and some co-digestion units but is also collected from dumps. Biogas is produced by anaerobic microorganisms at temperatures of about 36 and 55 deg C which correspond to the thermal optimum for mesophile and thermophile bacteria respectively. Co-digestion of animal material which e.g. is contained in collected organic household waste has to be pasteurized at 70 deg C for 1h according to EU-regulations. Such regulations may also be introduced to the sludge from municipal sewage treatment plants. Due to the fact that the process temperature is higher than the temperature of the substrate (sludge or organic waste material) as well as the outdoor temperature, both heating of the incoming substrate and compensation of heat losses are required. Traditionally most of the biogas has been burnt to generate the necessary heat for the process and premises at the plant. The excess gas has been burnt in a torch. In recent years the biogas produced in Sweden has found increased use as a renewable vehicle fuel

  15. An innovative process for biogas upgrading by the microbial electrolysis cell

    DEFF Research Database (Denmark)

    Jin, Xiangdan; Li, Xiaohu; Zhao, Nannan

    cell (BPMEC) was proposed to realize biogas upgrading. The system was composed of the anode, middle and cathode chamber which were separated by a bipolar membrane (BM) and an anion exchange membrane (AEM), respectively. With an external potential, water dissociation occurred and acid was produced......, efficient and sustainable way to extend the application of electrochemical technology....

  16. Biogas production from food-processing industrial wastes by anaerobic digestion

    DEFF Research Database (Denmark)

    Fang, Cheng

    Konfronteret med energikrise og klimaforandringer, har verden brug for grønne, effektive og kulstofneutrale energikilder, som kan erstatte fossile brændstoffer. Biogas, som dannes ved anaerob nedbrydning af organisk materiale, er en bæredygtig, pålidelig og vedvarende energikilde. Der er stor uud...

  17. Utilization of auxiliary means for the enhancement of the efficiency and stability of the biogas process; Einsatz von Hilfsmitteln zur Steigerung der Effizienz und Stabilitaet des Biogasprozesses

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    Within the Guelzow expert discussions at 29th September 2010 in Guelzow (Federal Republic of Germany) the following lectures were held: (1) State of the promotional work of the FNR on the subject auxiliary means - open questions (Petra Schuesseler); (2) Utilization of auxiliary means in the biogas production - Survey and experiences from laboratory and practice (Konrad Koch); (3) ORGA - test: Development of a test procedure for the practical evaluation of the fermentation biology of NaWaRo biogas plants (Nils Engler); (3) Investigations for the utilization of minerals in biogas plants - Significance of minerals for anaerobic microorganisms and causes for concentration differences in biogas fermentation plants (Andreas Lemmer); (4) Quantification of the efficiency of mineral biogas additives at the fermentation of renewable raw materials and their verification in the practice (Dirk Wagner); (5) Optimization of processes by means of enzymes in biogas plants (Monika Heiermann); (6) Utilization of microorganisms for the enhancement of the gas yield (Doris Schmack); (7) Results of the discussion and summary (Petra Schuesseler).

  18. PREPARATION AND CHARACTERIZATION OF CO-PROCESSED EXCIPIENT-PREGELATINIZED CASSAVA STARCH PROPIONATE AS A MATRIX IN THE GASTRORETENTIVE DOSAGE FORM

    Directory of Open Access Journals (Sweden)

    Junaedi

    2011-11-01

    Full Text Available The gastroretentive dosage form is designed to prolong the gastric residence time of the drug delivery system whichalso results in the development of an appropriate excipient. The purpose of this study is to develop and characterize coprocessedexcipient made from carrageenan (kappa-iota = 1:1 and pregelatinized cassava starch propionate (PCSP inratios of 1:1, 1:2, and 1:3. PCSP was prepared with propionic anhydride in an aqueous medium. The product was mixedwith carrageenan (kappa-iota = 1:1, as well as characterized physicochemical and functional properties. The coprocessedexcipient was then used as a mucoadhesive granule and floating tablet. The USP Basket was selected toperform the dissolution test of the granules in HCl buffer (pH 1.2 and distilled water for 8 hours each. Mucoadhesiveproperties were evaluated using bioadhesive through a vitro test and wash-off test. As for the floating tablet, the USPPaddle was selected to perform the dissolution test of the tablets in 0.1 N HCl for 10 hours. The floating lag time andfloating time were tested in 0.1 N HCl for 24 hours. The result of these studies indicated that co-processed excipientcarrageenan-PCSP can retard dosage form in gastric and drug controlled release, thus making it a suitable material forthe gastroretentive dosage form.

  19. Bioenergy, protein and fibres from grass - biogas process monitoring; Bioenergie, Protein und Fasern aus Gras - Monitoring des Biogasprozesses

    Energy Technology Data Exchange (ETDEWEB)

    Baier, U.; Delavy, P.

    2003-07-01

    Starting in Summer 2001 the first full scale Swiss Bio-refinery for grass processing took up operation in Schaffhausen. Grass processing covers the production of technical fibres and protein concentrate as well as anaerobic digestion of residual slops for the production of biogas and 'green' electricity. The refinery is operated by the company Bioenergie Schaffhausen as a P+D (pilot + demonstration) project of the Swiss Federal Office of Energy. Under full load it will deliver 2,000 MWh of 'green' electricity (10% own needs) and 3,000 MWh heat (50% own needs). Prior to start up the Swiss technology holder 2B Biorefineries AG mandated the University of Applied Sciences HSW with lab scale testing of the mesophilic biogas potential and anaerobic degradability of residual grass processing slops. Nutrient limitations and possible inhibition risks were evaluated. During the initial 8 months of full scale operation of the refinery in Schaffhausen an intensive monitoring of the anaerobic digester's performance was carried out. Carbon and nitrogen mass balances have been set up and the development of the granular EGSB sludge was characterised. From operational data a set of performance values was elaborated. The first year of operation was characterised by only partial exploitation of the refinery's grass processing capacity. Furthermore the protein separation and production unit has not yet been incorporated. Consequently, the EGSB biogas reactor showed a significant hydraulic underload when compared to dimensioning basics. Raw residuals were characterised by a higher particulate protein fraction. Operational conditions for the EGSB reactor were worked out to allow stable operation at elevated load conditions and with protein separation in operation. (author)

  20. Technological assumptions for biogas purification.

    Science.gov (United States)

    Makareviciene, Violeta; Sendzikiene, Egle

    2015-01-01

    Biogas can be used in the engines of transport vehicles and blended into natural gas networks, but it also requires the removal of carbon dioxide, hydrogen sulphide, and moisture. Biogas purification process flow diagrams have been developed for a process enabling the use of a dolomite suspension, as well as for solutions obtained by the filtration of the suspension, to obtain biogas free of hydrogen sulphide and with a carbon dioxide content that does not exceed 2%. The cost of biogas purification was evaluated on the basis of data on biogas production capacity and biogas production cost obtained from local water treatment facilities. It has been found that, with the use of dolomite suspension, the cost of biogas purification is approximately six times lower than that in the case of using a chemical sorbent such as monoethanolamine. The results showed travelling costs using biogas purified by dolomite suspension are nearly 1.5 time lower than travelling costs using gasoline and slightly lower than travelling costs using mineral diesel fuel.

  1. A numerical study on combustion process in a small compression ignition engine run dual-fuel mode (diesel-biogas)

    Science.gov (United States)

    Ambarita, H.; Widodo, T. I.; Nasution, D. M.

    2017-01-01

    In order to reduce the consumption of fossil fuel of a compression ignition (CI) engines which is usually used in transportation and heavy machineries, it can be operated in dual-fuel mode (diesel-biogas). However, the literature reviews show that the thermal efficiency is lower due to incomplete combustion process. In order to increase the efficiency, the combustion process in the combustion chamber need to be explored. Here, a commercial CFD code is used to explore the combustion process of a small CI engine run on dual fuel mode (diesel-biogas). The turbulent governing equations are solved based on finite volume method. A simulation of compression and expansions strokes at an engine speed and load of 1000 rpm and 2500W, respectively has been carried out. The pressure and temperature distributions and streamlines are plotted. The simulation results show that at engine power of 732.27 Watt the thermal efficiency is 9.05%. The experiment and simulation results show a good agreement. The method developed in this study can be used to investigate the combustion process of CI engine run on dual-fuel mode.

  2. Comparing methods for measuring the digestibility of miscanthus in bioethanol or biogas processing

    DEFF Research Database (Denmark)

    Nielsen, Susanne Frydendal; Jørgensen, Uffe; Hjorth, Maibritt

    2017-01-01

    the digestibility of miscanthus samples that were tested using three methods: 3,5-dinitrosalicylic acid assay (DNS), anaerobic batch digestion test, and high-throughput pretreatment and hydrolysis method, including a grinding and hydrothermal pretreatment prior to the analysis (HTPH). The miscanthus samples were...... expected to have different digestibilities due to maturity stage, dry matter content and the implementation of extrusion as a mechanical pretreatment. The results of the DNS and the biogas batch test methods were highly correlated (R2 between 0.75 and 0.92), but not with the results of the HTPH method....... The DNS and biogas batch test showed that digestibility differed between samples, probably due to the degree of lignification and content of soluble sugars. For the HTPH method, the digestibility for biorefining was the same irrespective of the variation in the other analyses. The HTPH method had higher...

  3. Anaerobic digestion without biogas?

    NARCIS (Netherlands)

    Kleerebezem, R.; Joosse, B.; Rozendaal, R.; Van Loosdrecht, M.C.M.

    2015-01-01

    Anaerobic digestion for the production of methane containing biogas is the classic example of a resource recovery process that combines stabilization of particulate organic matter or wastewater treatment with the production of a valuable end-product. Attractive features of the process include the pr

  4. Sicilian potential biogas production

    Directory of Open Access Journals (Sweden)

    Antonio Comparetti

    2013-09-01

    Full Text Available This study is aimed at predicting the Sicilian potential biogas production, using the Organic Fraction of Municipal Solid Waste (OFMSW, animal manure and food industry by-products, in a region where only one biogas plant using MSW and one co-digestion plant are nowadays available. The statistical data about OFMSW, the number of animals bred in medium and large farms and the amounts of by-products of food processing industries were evaluated, in order to compute the Sicilian potential biogas and energy production. The OFMSW produced in Sicily, that is 0.8 million tons ca. per year (37% of MSW, could be used in a bio-reactor, together with other raw materials, for Anaerobic Digestion (AD process, producing biogas and “digestate”. Moreover, 3.03 million tons ca. of manure, collected in medium and large animal husbandry farms (where cows, pigs and poultry are bred, and 350 thousand tons ca. of by-products, collected in food processing industries (pomace from olive oil mills and grape marc from wineries, might be used for AD process. The Sicilian potential biogas production from the AD of the above raw materials is 170.2 millions of m3, that is equal to 1023.4 GWh of energy per year, of which 484 GWh from animal manure, 303 GWh from OFMSW and 236.4 GWh from food industry by-products. The highest biogas production is in the province of Palermo (35.6 millions of m3, Ragusa (30.8 millions of m3 and Catania (22.8 millions of m3, having a potential energy production of 213.8, 185 and 137 GWh, respectively.

  5. Evaluation of high-solids anaerobic digestion process for converting excess sludge to biogas%应用高固体浓度厌氧消化工艺转化污泥产沼气研究

    Institute of Scientific and Technical Information of China (English)

    刘晓玲; 李十中; 刘建双; 李天成; 王莉

    2011-01-01

    应用高固体浓度厌氧消化工艺在中温(35±1)℃条件下,考察了进料总固体(TS)含量为17%的污泥在5 L反应器中批式厌氧消化产沼气的发酵过程,并探讨了高固体浓度厌氧消化工艺转化污泥产沼气的可行性.结果表明,沼气和CH4的累积产量在整个厌氧消化期间(73 d)经历产气高峰、相对稳定和结束3个阶段,累积产气量分别达121.3 L和80.3 L,且在产气相对稳定阶段,CH4的含量保持相对稳定,平均为70.7%;虽然总酸、乙酸、丙酸和氨氮在消化阶段最高分别达9.5 g·L-1、4.8 g·L-1、2.6 g·L-1和3653 mg·L-1,但沼气和甲烷的产量在厌氧消化过程中并未受到明显的影响.同时,应用高固体浓度厌氧消化工艺可显著提高有效容积沼气产率和有效容积CH4产率,它们在厌氧消化期间的产率平均分别可达0.498 L·L-1·d-1与0.330 L·L-1·d-1,且厌氧消化结束后总固体和有机质(VS)去除率分别为44.2%和67.3%.%Laboratory-scale evaluation of a high-solids anaerobic digestion process for converting excess sludge to biogas was performed in this study. The batch experiment was carried out in a developed anaerobic reactor (5.0 L), which operated at mesophilic (35 ± 1 ) ℃ and high-solids ( 17% total solids)conditions. Excess sludge exhibited a methanogenic pattern including fast biogae production phase, relatively stable phase and final phase through the whole experimental period (73 days) and this gave cumulative biogas of 121.3 L and cumulative bio-methane of 80.3 L. The content of bio-methane stayed relatively stable during the relatively stable operation phase, and its mean value accounted for 70.7%. Although total volatile fatty acids, acetic acid, propionic acid and ammonia nitrogen significantly increased to 9.5 g· L - 1 ,4.8 g· L - 1 ,2.6 g· L - 1 and 3653 mg· L - 1, respectively, they had no obvious impact on the production of biogae and bio-methane during the anaerobic digestion. The

  6. Innovative CO{sub 2} separation process for biogas upgrading using polymeric resins; Innovatives CO{sub 2}-Abscheideverfahren zur Biogasaufbereitung mit Hilfe von Polymerharzen

    Energy Technology Data Exchange (ETDEWEB)

    Harrivelle, Carole; Safai, Daniel; Raab, Katharina; Klein, Barbara [Stuttgart Univ. (Germany). Abt. Brennstoffe und Rauchgasreinigung; Scheffknecht, Guenter

    2016-08-01

    Upgraded biogas can be injected into the natural gas grid. The Institute of Combustion and Power Plant Technology (IFK) is investigating several innovative biogas upgrading processes with the aim to develop treatment methods adapted for small biogas plants. This paper presents a process to separate CO{sub 2} from CH{sub 4} by concentration swig adsorption using an amine functionalized polymer resin. The experiments were carried out at a continuous laboratory scale plant. The results are compared with previous experiments from earlier work at the IFK. The new resin shows a significant increase of working capacity and CH{sub 4} purity as well as a decrease of CH{sub 4} loss.

  7. Co-digestion of manure and whey for in situ biogas upgrading by the addition of H2: process performance and microbial insights

    DEFF Research Database (Denmark)

    Luo, Gang; Angelidaki, Irini

    2013-01-01

    In situ biogas upgrading was conducted by introducing H2 directly to the anaerobic reactor. As H2 addition is associated with consumption of the CO2 in the biogas reactor, pH increased to higher than 8.0 when manure alone was used as substrate. By co-digestion of manure with acidic whey, the p......H in the anaerobic reactor with the addition of hydrogen could be maintained below 8.0, which did not have inhibition to the anaerobic process. The H2 distribution systems (diffusers with different pore sizes) and liquid mixing intensities were demonstrated to affect the gas-liquid mass transfer of H2 and the biogas...... composition. The best biogas composition (75:6.6:18.4) was obtained at stirring speed 150 rpmand using ceramic diffuser, while the biogas in the control reactor consisted of CH4 and CO2 at a ratio of 55:45. The consumed hydrogen was almost completely converted to CH4, and there was no significant accumulation...

  8. Anaerobic Digestion and Biogas Potential: Simulation of Lab and Industrial-Scale Processes

    Directory of Open Access Journals (Sweden)

    Ihsan Hamawand

    2015-01-01

    Full Text Available In this study, a simulation was carried out using BioWin 3.1 to test the capability of the software to predict the biogas potential for two different anaerobic systems. The two scenarios included: (1 a laboratory-scale batch reactor; and (2 an industrial-scale anaerobic continuous lagoon digester. The measured data related to the operating conditions, the reactor design parameters and the chemical properties of influent wastewater were entered into BioWin. A sensitivity analysis was carried out to identify the sensitivity of the most important default parameters in the software’s models. BioWin was then calibrated by matching the predicted data with measured data and used to simulate other parameters that were unmeasured or deemed uncertain. In addition, statistical analyses were carried out using evaluation indices, such as the coefficient of determination (R-squared, the correlation coefficient (r and its significance (p-value, the general standard deviation (SD and the Willmott index of agreement, to evaluate the agreement between the software prediction and the measured data. The results have shown that after calibration, BioWin can be used reliably to simulate both small-scale batch reactors and industrial-scale digesters with a mean absolute percentage error (MAPE of less than 10% and very good values of the indexes. Furthermore, by changing the default parameters in BioWin, which is a way of calibrating the models in the software, as well, this may provide information about the performance of the digester. Furthermore, the results of this study showed there may be an over estimation for biogas generated from industrial-scale digesters. More sophisticated analytical devices may be required for reliable measurements of biogas quality and quantity.

  9. Biogas document; Dossier Biogaz

    Energy Technology Data Exchange (ETDEWEB)

    Verchin, J.C.; Servais, C. [Club BIOGAZ, 94 - Arcueil (France)

    2002-06-01

    In this document concerning the biogas, the author presents this renewable energy situation in 2001-2002, the concerned actors, the accounting of the industrial methanization installations in France, the three main chains of process for industrial wastes and two examples of methanization implementation in a paper industry and in a dairy. (A.L.B.)

  10. Improvement of biogas production by bioaugmentation.

    Science.gov (United States)

    Kovács, K L; Ács, N; Kovács, E; Wirth, R; Rákhely, G; Strang, Orsolya; Herbel, Zsófia; Bagi, Z

    2013-01-01

    Biogas production technologies commonly involve the use of natural anaerobic consortia of microbes. The objective of this study was to elucidate the importance of hydrogen in this complex microbial food chain. Novel laboratory biogas reactor prototypes were designed and constructed. The fates of pure hydrogen-producing cultures of Caldicellulosiruptor saccharolyticus and Enterobacter cloacae were followed in time in thermophilic and mesophilic natural biogas-producing communities, respectively. Molecular biological techniques were applied to study the altered ecosystems. A systematic study in 5-litre CSTR digesters revealed that a key fermentation parameter in the maintenance of an altered population balance is the loading rate of total organic solids. Intensification of the biogas production was observed and the results corroborate that the enhanced biogas productivity is associated with the increased abundance of the hydrogen producers. Fermentation parameters did not indicate signs of failure in the biogas production process. Rational construction of more efficient and sustainable biogas-producing microbial consortia is proposed.

  11. Press fluid pre-treatment optimisation of the integrated generation of solid fuel and biogas from biomass (IFBB) process approach.

    Science.gov (United States)

    Corton, John; Toop, Trisha; Walker, Jonathan; Donnison, Iain S; Fraser, Mariecia D

    2014-10-01

    The integrated generation of solid fuel and biogas from biomass (IFBB) system is an innovative approach to maximising energy conversion from low input high diversity (LIHD) biomass. In this system water pre-treated and ensiled LIHD biomass is pressed. The press fluid is anaerobically digested to produce methane that is used to power the process. The fibrous fraction is densified and then sold as a combustion fuel. Two process options designed to concentrate the press fluid were assessed to ascertain their influence on productivity in an IFBB like system: sedimentation and the omission of pre-treatment water. By concentrating press fluid and not adding water during processing, energy production from methane was increased by 75% per unit time and solid fuel productivity increased by 80% per unit of fluid produced. The additional energy requirements for pressing more biomass in order to generate equal volumes of feedstock were accounted for in these calculations.

  12. Development of instrumentation systems as a base for control of digestion process stability in full-scale agricultural and industrial biogas plants.

    Science.gov (United States)

    Kujawski, O; Steinmetz, H

    2009-01-01

    This article deals with the analysis of instrumentation from three modern German full-scale biogas plants with different inputs and typical process engineering concepts for German conditions. The measured results from each plant and the suitability of the instrumentation used are evaluated and assessed. Conclusions are also made about improving the use and architecture of the instrumentation. The analysis results show which benefits and optimum combination of on-line and off-line instrumentation could result for the control and automation of industrial and agricultural biogas plants.

  13. Comparison of different procedures to stabilize biogas formation after process failure in a thermophilic waste digestion system: influence of aggregate formation on process stability.

    Science.gov (United States)

    Kleyböcker, A; Liebrich, M; Kasina, M; Kraume, M; Wittmaier, M; Würdemann, H

    2012-06-01

    Following a process failure in a full-scale biogas reactor, different counter measures were undertaken to stabilize the process of biogas formation, including the reduction of the organic loading rate, the addition of sodium hydroxide (NaOH), and the introduction of calcium oxide (CaO). Corresponding to the results of the process recovery in the full-scale digester, laboratory experiments showed that CaO was more capable of stabilizing the process than NaOH. While both additives were able to raise the pH to a neutral milieu (pH>7.0), the formation of aggregates was observed particularly when CaO was used as the additive. Scanning electron microscopy investigations revealed calcium phosphate compounds in the core of the aggregates. Phosphate seemed to be released by phosphorus-accumulating organisms, when volatile fatty acids accumulated. The calcium, which was charged by the CaO addition, formed insoluble salts with long chain fatty acids, and caused the precipitation of calcium phosphate compounds. These aggregates were surrounded by a white layer of carbon rich organic matter, probably consisting of volatile fatty acids. Thus, during the process recovery with CaO, the decrease in the amount of accumulated acids in the liquid phase was likely enabled by (1) the formation of insoluble calcium salts with long chain fatty acids, (2) the adsorption of volatile fatty acids by the precipitates, (3) the acid uptake by phosphorus-accumulating organisms and (4) the degradation of volatile fatty acids in the aggregates. Furthermore, this mechanism enabled a stable process performance after re-activation of biogas production. In contrast, during the counter measure with NaOH aggregate formation was only minor resulting in a rapid process failure subsequent the increase of the organic loading rate.

  14. Anaerobic digestion of fruit and vegetable processing wastes for biogas production

    Energy Technology Data Exchange (ETDEWEB)

    Viswanath, P.; Sumithra Devi, S.; Nand, K. (Central Food Technological Research Inst., Mysore (IN))

    1992-01-01

    The effect of feeding different fruit and vegetable wastes, mango, pineapple, tomato, jackfruit, banana and orange, was studied in a 60-litre digester by cycling each waste every fifth day in order to operate the digester as and when there was supply of feed. The characteristics of the anaerobically digested fluid and digester performance in terms of biogas production were determined at different loading rates (LR) and at different hydraulic retention times (HRT) and the maximum biogas yield of 0.6 m{sup 3}/kg VS added was achieved at a 20-day HRT and 40 kg TS m{sup -3}day{sup -1} loading rate. The hourly gas production was observed in the digesters operated at 16 and 24 days HRT. The major yield (74.5%) of gas was produced within 12h of feeding at a 16-day HRT whereas at a 24-day HRT only 59.03% of the total gas could be obtained at this time. (author).

  15. Enhancing biogas production from vinasse in sugarcane biorefineries: Effects of urea and trace elements supplementation on process performance and stability.

    Science.gov (United States)

    Janke, Leandro; Leite, Athaydes F; Batista, Karla; Silva, Witan; Nikolausz, Marcell; Nelles, Michael; Stinner, Walter

    2016-10-01

    In this study, the effects of nitrogen, phosphate and trace elements supplementation were investigated in a semi-continuously operated upflow anaerobic sludge blanket system to enhance process stability and biogas production from sugarcane vinasse. Phosphate in form of KH2PO4 induced volatile fatty acids accumulation possibly due to potassium inhibition of the methanogenesis. Although nitrogen in form of urea increased the reactor's alkalinity, the process was overloaded with an organic loading rate of 6.1gCODL(-1)d(-1) and a hydraulic retention time of 3.6days. However, by supplementing urea and trace elements a stable operation even at an organic loading rate of 9.6gCODL(-1)d(-1) and a hydraulic retention time of 2.5days was possible, resulting in 79% higher methane production rate with a stable specific methane production of 239mLgCOD(-1).

  16. A membrane based process for the upgrading of biogas to substituted natural gas (SNG) and recovery of carbondioxide for industrial use

    DEFF Research Database (Denmark)

    Norddahl, Birgir; dePreez, Jan

    2007-01-01

    A low pressure carbon molecular sieve (CMS) membrane based process to upgrade biogas from anaerobic digestion of agricultural waste to a substitute natural gas (SNG) has been tested on a pilot scale. The data extracted from the pilot plant was used to estimate membrane permeance and ideal...

  17. Monitoring of biogas test plants

    DEFF Research Database (Denmark)

    Holm-Nielsen, Jens Bo; Esbensen, Kim H.

    2011-01-01

    Most studies reported in the literature have investigated near infrared spectroscopy (NIR) in laboratory-scale or minor pilot biogas plants only; practically no other studies have examined the potential for meso-scale/full-scale on-line process monitoring. The focus of this study is on a meso......-scale biogas test plant implementation of process analytical technologies (PAT) to develop multivariate calibration/prediction models for anaerobic digestion (AD) processes. A 150 L bioreactor was fitted with a recurrent loop at which NIR spectroscopy and attendant reference sampling were carried out. In all...... realistic bioreactor scales, it is necessary to obtain a fairly constant level of volatile fatty acid (VFA) concentration, which furthers a stable biogas production. Uncontrolled VFA contents have a significant negative impact on biogas production; VFA concentrations should not exceed 5–6000 mg/L lest...

  18. Biotechnological intensification of biogas production

    Energy Technology Data Exchange (ETDEWEB)

    Bagi, Z.; Acs, N.; Balint, B.; Horvath, L.; Dobo, K.; Perei, K.R.; Rakhely, G.; Kovacs, K.L. [Szeged Univ. (Hungary). Dept. of Biotechnology; Hungarian Academy of Sciences, Szeged (Hungary). Inst. of Biophysics

    2007-08-15

    The importance of syntrophic relationships among microorganisms participating in biogas formation has been emphasized, and the regulatory role of in situ hydrogen production has been recognized. It was assumed that the availability of hydrogen may be a limiting factor for hydrogenotrophic methanogens. This hypothesis was tested under laboratory and field conditions by adding a mesophilic (Enterobacter cloacae) or thermophilic hydrogen-producing (Caldicellulosyruptor saccharolyticus) strain to natural biogas-producing consortia. The substrates were waste water sludge, dried plant biomass from Jerusalem artichoke, and pig manure. In all cases, a significant intensification of biogas production was observed. The composition of the generated biogas did not noticeably change. In addition to being a good hydrogen producer, C. saccharolyticus has cellulolytic activity; hence, it is particularly suitable when cellulose-containing biomass is fermented. The process was tested in a 5-m{sup 3} thermophilic biogas digester using pig manure slurry as a substrate. Biogas formation increased at least 160-170% upon addition of the hydrogen-producing bacteria as compared to the biogas production of the spontaneously formed microbial consortium. Using the hydrogenase-minus control strain provided evidence that the observed enhancement was due to interspecies hydrogen transfer. The on-going presence of C. saccharolyticus was demonstrated after several months of semicontinuous operation. (orig.)

  19. Biogas production from wheat straw and manure--impact of pretreatment and process operating parameters.

    Science.gov (United States)

    Risberg, Kajsa; Sun, Li; Levén, Lotta; Horn, Svein Jarle; Schnürer, Anna

    2013-12-01

    Non-treated or steam-exploded straw in co-digestion with cattle manure was evaluated as a substrate for biogas production compared with manure as the sole substrate. All digestions were performed in laboratory-scale CSTR reactors (5L) operating with an organic loading late of approximately 2.8 g VS/L/day, independent of substrate mixture. The hydraulic retention was 25 days and an operating temperature of 37, 44 or 52°C. The co-digestion with steam exploded straw and manure was evaluated with two different mixtures, with different proportion. The results showed stable performance but low methane yields (0.13-0.21 N L CH4/kg VS) for both manure alone and in co-digestion with the straw. Straw appeared to give similar yield as manure and steam-explosion treatment of the straw did not increase gas yields. Furthermore, there were only slight differences at the different operating temperatures.

  20. Research on Anaerobic Digestion: Optimization and Scalability of Mixed High-strength Food Processing Wastes for Renewable Biogas Energy

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Zhongtang [The Ohio State Univ., Columbus, OH (United States); Hitzhusen, Fredrick [The Ohio State Univ., Columbus, OH (United States)

    2012-12-27

    This research project developed and improved anaerobic digestion technologies, created a comprehensive Inventory of Ohio Biomass and a database of microorganisms of anaerobic digesters, and advanced knowledge and understanding of the underpinning microbiology of the anaerobic digestion process. The results and finding of this research project may be useful for future development and implementation of anaerobic digesters, especially at livestock farms. Policy makers and investors may also find the information on the biomass availability in Ohio and valuation of energy projects useful in policy making and making of investment decisions. The public may benefit from the information on biogas as an energy source and the potential impact of anaerobic digester projects on their neighborhoods.

  1. Terpenes removal from biogas; Terpenenverwijdering uit biogas

    Energy Technology Data Exchange (ETDEWEB)

    Schulze, P.; Holstein, J.; De Haan, HR.; Vlap, H. [DNV KEMA, Arnhem (Netherlands)

    2013-06-15

    Biogas may contain unwanted and harmful components, including aromatic hydrocarbons such as terpenes. These terpenes (organic oils) are mainly present in citrus peel and plant residues; that is why especially raw biogas from organic waste digestion plants contains high concentrations of terpenes. If terpenes end up in the gas grid (with the injected biomethane) there is a risk that plastics (PE pipes) lose their mechanical properties by absorbing liquids or extracting ethereal plasticizers. This can lead to embrittlement greatly lowering the reliability of the piping. In addition, soft components are als o affected (gaskets and rubber O-rings). Besides the impact on the integrity of the gas grid, terpenes also mask the odor of natural gas odorants such as THT. This impedes the detection of gas leaks which is a significant security risk. Furthermore, the presence of terpenes in biogas leads to fouling of equipment used for the drying of biomethane, as well as contamination of adsorption liquids and membranes used in the upgrading process. Currently, terpenes are removed by activated carbon filters. The tool life of such a filter can be relatively short if terpene concentrations are high in the biogas; this results in a significant increase of the operational costs, due to the replacement of the carbon. This study looked at alternative techniques for removing much of the terpenes from biogas in a simple, efficient and cheap way. In a workshop with stakeholders two techniques were chosen to be tested on laboratory scale in order to demonstrate the proof of principle. These techniques are photo-oxydation and a gas scrubbing. Of all investigated techniques for the removal of limonene the application of UV radiation seems to be the most promising option because of the simplicity of the process, the high efficiency (up to 94%), the comparable operational costs with activated carbon (6.7 to 9.5 euro/kg limonene removed, compared to 10 euro/kg limonene removed for activated

  2. GAS TURBINE ENGINES CONSUMING BIOGAS

    Directory of Open Access Journals (Sweden)

    Е. Ясиніцький

    2011-04-01

    Full Text Available A problem of implementation of biofuel for power plants of big capacity was considered in thisarticle. Up to date in the world practice a wide implementation of biogas plants of low and medialcapacity are integrated. It is explained by the big amount of enterprises in which relatively smallvolumes of organic sediment excrete in the process of its activity. An emphasis of article is on thatenterprises, which have big volumes of sediments for utilizing of which module system of medialcapacity biogas plants are non-effective. The possibility of using biogas and biomethane as a fuelfor gas turbine engine is described. The basic problems of this technology and ways of its solutionsare indicated. Approximate profitability of biogas due to example of compressor station locatednearby poultry factory was determined also. Such factors as process characteristics of engine withcapacity of 5 MW, approximate commercial price for natural gas and equipment costs due toofficial sources of “Zorg Ukraine” company was taken into consideration. The necessity forproviding researches on influence of biogas on the process characteristics of gas turbine engine andits reliability, constructing modern domestic purification system for biogas was shown.

  3. ORGANIC WASTE USED IN AGRICULTURAL BIOGAS PLANTS

    Directory of Open Access Journals (Sweden)

    Joanna Kazimierowicz

    2014-04-01

    Full Text Available Treatment of organic waste is an ecological and economical problem. Searching method for disposal of these wastes, interest is methane fermentation. The use of this process in agricultural biogas plants allows disposal of hazardous waste, obtaining valuable fertilizer, while the production of ecologically clean fuel – biogas. The article presents the characteristics of organic waste from various industries, which make them suitable for use as substrates in agricultural biogas plants.

  4. ORGANIC WASTE USED IN AGRICULTURAL BIOGAS PLANTS

    OpenAIRE

    Joanna Kazimierowicz

    2014-01-01

    Treatment of organic waste is an ecological and economical problem. Searching method for disposal of these wastes, interest is methane fermentation. The use of this process in agricultural biogas plants allows disposal of hazardous waste, obtaining valuable fertilizer, while the production of ecologically clean fuel – biogas. The article presents the characteristics of organic waste from various industries, which make them suitable for use as substrates in agricultural biogas plants.

  5. Planning for Biogas Plant in Denmark

    DEFF Research Database (Denmark)

    Landt, Cristina C.; Gaarsmand, Regin; Palsberg, Aske

    2016-01-01

    This article is about establishing biogas in Denmark in the region of Zealand, the challenges that are related to this establishment and how to overcome this challenges. The article highlights three reasons for these challenges: 1) Regulation, 2) The municipal planning and 3) Involved various...... stakeholders. It investigates how these challenges affected the process and were overcome in the establishment of Solrod Biogas. In terms of ownership and biomass input, this biogas plant is unique compared to other Danish biogas plants. The biogas plant is based on organic by-products from local industries...... and seaweed. The plant solves an essential environmental issue for the municipality and citizens who were affected by the smell of rotten seaweed washed up in Koge Bay. The seaweed is used as input; this solves several problems at the same time. The method used to establish Solrod Biogas was an integrated...

  6. [Progress on biogas technology and engineering].

    Science.gov (United States)

    Liu, Xiaofeng; Yuan, Yuexiang; Yan, Zhiying

    2010-07-01

    Dwindling supplies of conventional energy sources and the demand to increase the share of renewable energy for sustainability have increased the significance of biogas, the product of synergistic fermentation of biodegrable organic wastes from municipal, agricultural and industrial activities by microbial populations under anaerobic conditions. With extensive research and engineering practice, many technologies and modes have been developed for biogas production and application. Currently, the most widely used mode is the complete-mixing mesophilic fermentation. Europe, especially Germany, is leading the world in the combined heat and power production (CHP) from biogas. In this paper, updated progress in biogas technologies is reviewed, with focuses on anaerobic microorganisms, bioreactor configurations and process development, biogas production and applications, in which perspectives of biogas as a clean and renewable energy are projected.

  7. 生物气固体氧化物燃料电池研究进展%Research Process in Solid Oxide Fuel Cell Feeding With Biogas

    Institute of Scientific and Technical Information of China (English)

    王静晖; 田禹; 吴晓燕

    2013-01-01

    对近年来国内外生物气固体氧化物燃料电池发电领域的研究进行了归纳分析。在介绍生物气产生和氧离子型固体氧化物燃料电池产电原理的基础上,总结了固体氧化物燃料电池以生物质产出的生物气为燃料发电所涉及的电化学反应;介绍了国外研究者对该类发电过程进行的试验和模拟研究;同时,对生物气结合固体氧化物燃料电池的研究进展进行了分析。得出的结论为,生物气结合固体氧化物燃料电池进行产电具有重大的实际和环保意义。%Research in the field of power generation by solid oxide fuel cell feeding with biogas in recent years at home and abroad is summarized and analyzed in this paper. First, based on the principle of biogas production and electricity generation by oxygen ions-solid oxide fuel cell, it has summarized electrochemical reactions of power generation by solid oxide fuel cell feeding with biogas produced from biomass as a fuel. Second, it has introduced details on test and simulation conducted by researchers from different countries. Third, it has analyzed the research process of biogas combined with the solid oxide fuel cell. Finally, as a conclusion, the combination biogas with solid oxide fuel cell for electricity production has veryimportant practical and environmental significance.

  8. Effect of Water Volume and Biogas Volumetric Flowrate in Biogas Purification Through Water Scrubbing Method

    Directory of Open Access Journals (Sweden)

    Hendry Sakke Tira

    2016-05-01

    Full Text Available Energy supply is a crucial issue in the world in the last few years. The increase in energy demand caused by population growth and resource depletion of world oil reserves provides determination to produce and to use renewable energies. One of the them is biogas. However, until now the use of biogas has not yet been maximized because of its poor purity. According to the above problem, the research has been carried out using the method of water absorption. Under this method it is expected that the rural community is able to apply it. Therefore, their economy and productivity can be increased. This study includes variations of absorbing water volume (V and input biogas volume flow rate (Q. Raw biogas which is flowed into the absorbent will be analyzed according to the determined absorbing water volume and input biogas volume rate. Improvement on biogas composition through the biogas purification method was obtained. The level of CO2 and H2S was reduced significantly specifically in the early minutes of purification process. On the other hand, the level of CH4 was increased improving the quality of raw biogas. However, by the time of biogas purification the composition of purified biogas was nearly similar to the raw biogas. The main reason for this result was an increasing in pH of absorbent. It was shown that higher water volume and slower biogas volume rate obtained better results in reducing the CO2 and H2S and increasing CH4 compared to those of lower water volume and higher biogas volume rate respectively. The purification method has a good promising in improving the quality of raw biogas and has advantages as it is cheap and easy to be operated.

  9. Effect of Water Volume and Biogas Volumetric Flowrate in Biogas Purification Through Water Scrubbing Method

    Directory of Open Access Journals (Sweden)

    Hendry Sakke Tira

    2014-10-01

    Full Text Available Energy supply is a crucial issue in the world in the last few years. The increase in energy demand caused by population growth and resource depletion of world oil reserves provides determination to produce and to use renewable energies. One of the them is biogas. However, until now the use of biogas has not yet been maximized because of its poor purity. According to the above problem, the research has been carried out using the method of water absorption. Under this method it is expected that the rural community is able to apply it. Therefore, their economy and productivity can be increased. This study includes variations of absorbing water volume (V and input biogas volume flow rate (Q. Raw biogas which is flowed into the absorbent will be analyzed according to the determined absorbing water volume and input biogas volume rate. Improvement on biogas composition through the biogas purification method was obtained. The level of CO2 and H2S was reduced significantly specifically in the early minutes of purification process. On the other hand, the level of CH4 was increased improving the quality of raw biogas. However, by the time of biogas purification the composition of purified biogas was nearly similar to the raw biogas. The main reason for this result was an increasing in pH of absorbent. It was shown that higher water volume and slower biogas volume rate obtained better results in reducing the CO2 and H2S and increasing CH4 compared to those of lower water volume and higher biogas volume rate respectively. The purification method has a good promising in improving the quality of raw biogas and has advantages as it is cheap and easy to be operated.

  10. Energy from whey - comparison of the biogas and bioethanol processes; Energie a partir de petit-lait : comparaison des filieres biogaz et bioethanol

    Energy Technology Data Exchange (ETDEWEB)

    Fruteau de Laclos, H.; Membrez, Y. [Erep SA, Aclens (Switzerland)

    2004-07-01

    This final report for the Swiss Federal Office of Energy (SFOE) presents the results of a project which investigated how energy could be generated from the whey produced in the cheese-making process. The first part of the project aimed to validate a concept for on-site production and use of biogas at a medium-sized cheese factory. The results of the first step, an experimental study carried out using a down-flow fixed-film bio-reactor, are discussed. This allowed the determination of the optimal working parameters as well as providing an estimate of the performance of the process. The second part of the project aimed to compare the bio-ethanol and biogas production processes. It was carried out in collaboration with AlcoSuisse and the Energy Systems Laboratory at the Swiss Federal Institute of Technology (EPFL) in Lausanne. The results of a life-cycle assessment (LCA) are discussed, which compared the two processes from an environmental point of view. Here, two impacts were considered: fossil fuel consumption and greenhouse effect. The replacement of fuel-oil with biogas for heat production and the replacement of conventional petrol with mixture including 5% bio-ethanol were examined. The results are presented that show that there was no significant difference between the two processes. According to the authors, the treatment of one cubic meter of cheese-whey allows savings of more than 20 litres of oil equivalent and 60 kg of CO{sub 2} emissions.

  11. Biogas Production Using Anaerobic Biodigester from Cassava Starch Effluent

    OpenAIRE

    Sunarso, S.; B Budiyono; Siswo Sumardiono

    2010-01-01

    IKMs’ factory activity in Margoyoso produces liquid and solid wastes. The possible alternative was to use the liquid effluent as biogas raw material. This study focuses on the used of urea, ruminant, yeast, microalgae, the treatment of gelled and ungelled feed for biogas production, pH control during biogas production using buffer Na2CO3, and feeding management in the semi-continuous process of biogas production that perform at ambient temperature for 30 days. Ruminant bacteria, yeast, urea, ...

  12. Chemical speciation of sulfur and metals in biogas reactors - Implications for cobalt and nickel bio-uptake processes.

    Science.gov (United States)

    Yekta, Sepehr Shakeri; Skyllberg, Ulf; Danielsson, Åsa; Björn, Annika; Svensson, Bo H

    2017-02-15

    This article deals with the interrelationship between overall chemical speciation of S, Fe, Co, and Ni in relation to metals bio-uptake processes in continuous stirred tank biogas reactors (CSTBR). To address this topic, laboratory CSTBRs digesting sulfur(S)-rich stillage, as well as full-scale CSTBRs treating sewage sludge and various combinations of organic wastes, termed co-digestion, were targeted. Sulfur speciation was evaluated using acid volatile sulfide extraction and X-ray absorption spectroscopy. Metal speciation was evaluated by chemical fractionation, kinetic and thermodynamic analyses. Relative Fe to S content is identified as a critical factor for chemical speciation and bio-uptake of metals. In reactors treating sewage sludge, quantity of Fe exceeds that of S, inducing Fe-dominated conditions, while sulfide dominates in laboratory and co-digestion reactors due to an excess of S over Fe. Under sulfide-dominated conditions, metals availability for microorganisms is restricted due to formation of metal-sulfide precipitates. However, aqueous concentrations of different Co and Ni species were shown to be sufficient to support metal acquisition by microorganisms under sulfidic conditions. Concentrations of free metal ions and labile metal complexes in aqueous phase, which directly participate in bio-uptake processes, are higher under Fe-dominated conditions. This in turn enhances metal adsorption on cell surfaces and bio-uptake rates.

  13. The effect of anaerobic fermentation processing of cattle waste for biogas as a renewable energy resources on the number of contaminant microorganism

    Science.gov (United States)

    Kurnani, Tb. Benito A.; Hidayati, Yuli Astuti; Marlina, Eulis Tanti; Harlia, Ellin

    2016-02-01

    Beef cattle waste has a positive potential that can be exploited, as well as a negative potential that must be controlled so as not to pollute the environment. Beef cattle waste can be processed into an alternative energy, namely biogas. Anaerobic treatment of livestock waste to produce gas can be a solution in providing optional energy, while the resulted sludge as the fermentation residue can be used as organic fertilizer for crops. However, this sludge may containt patogenic microorganism that will damage human and environmet healt. Therefor, this study was aimed to know the potency of beef cattle waste to produce biogas and the decrease of the microorganism's number by using fixed dome digester. Beef cattle waste was processed into biogas using fixed dome digester with a capacity of 12 m3. Biogas composition was measured using Gas Cromatografi, will microorganism species was identified using Total plate Count Methode. The result of this study shows that the produced biogas contains of 75.77% Mol (CH4), 13.28% Mol (N), and 6.96% Mol (CO2). Furthermor, this study show that the anaerobic fermrntation process is capable of reducing microorganisms that could potentially pollute the environment. The number of Escherichia coli and Samonella sp. were <30 MPN/ml respectively save for environment. This process can reduce 84.70% the amount of molds. The only molds still existed after fermentation was A.fumigatus. The number of protozoa can be reduced in order of 94.73%. Protozoa that can be identified in cattle waste before, and after anaerobic fermentation was merely Eimeria sp.. The process also reduced the yeast of 86.11%. The remaining yeast after fermentation was Candida sp. Finally, about 93.7% of endoparasites was reduced by this process. In this case, every trematode and cestoda were 100% reduced, while the nematode only 75%. Reducing some microorganisms that have the potential to pollute the environment signifies sludge anaerobic fermentation residue is safe to

  14. Biogas upgrading to biomethane. Proceedings; Biogasaufbereitung zu Biomethan. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-12-05

    Within the 6th Hanauer Dialogue 'Biogas upgrading to biomethane' at 21st February, 2008, the following lectures were held: (a) Processing of biogas - an introduction (Michael Beil); (b) The climate protecting targets of the Federal Republic of Germany: Which role will play the upgrading of biogas, and which legal boundary conditions are created by the Federal Government? (Uwe Holzhammer); (c) Future strategy: CH{sub 4} grids (Juergen Schmid); (d) Biogas upgrading and biomethane utilization in Sweden (Anneli Petersson); (e) Biogas upgrading and utilization of bio methane in Switzerland (Arthur Wellinger); (f) Biogas upgrading by means of pressure swing adsorption (Alfons Schulte-Schulze Berndt); (g) Biogas upgrading by means of pressurized water washing (Ulf Richter); (h) Biogas upgrading for feeding in public grids. The case of biogas plant Bruck a.d. Leitha (Michael Harasek); (i) Biogas upgrading by means of chemical absorption according to the LP Cooab process (Jerome van Beek); (j) Practical experiences in unpressurized amine washing MT bio methane (Karsten Wuensche); (k) Biogas upgrading by means of organic physical washing with HAASE biogas amplifiers (Roland Kahn); (l) Upgrading using cryogenic technology; the GPP registered -system (Jeroen de Pater); (m) Micro Gas Distribution Systems: Alternatives to biogas upgrading and grid injection (Michael Beil, Bernd Krautkremer); (n) Feeding of exchange gas. The case of project Straelen and Kerpen (Frank Schaefer); (o) Feeding of biogas from the view of grid operators (Norbert Nordmeyer); BIOGASMAX: Biogas as Vehicle Fuel - Market Expansion to 2020 Air Quality (Michael Beil, Uwe Hoffstede); (p) Study: Feeding of biogas into the natural gas distribution system (Fachagentur Nachwachsende Rohstoffe).

  15. Reviewing the anaerobic digestion and co-digestion process of food waste from the perspectives on biogas production performance and environmental impacts.

    Science.gov (United States)

    Chiu, Sam L H; Lo, Irene M C

    2016-12-01

    In this paper, factors that affect biogas production in the anaerobic digestion (AD) and anaerobic co-digestion (coAD) processes of food waste are reviewed with the aim to improve biogas production performance. These factors include the composition of substrates in food waste coAD as well as pre-treatment methods and anaerobic reactor system designs in both food waste AD and coAD. Due to the characteristics of the substrates used, the biogas production performance varies as different effects are exhibited on nutrient balance, inhibitory substance dilution, and trace metal element supplement. Various types of pre-treatment methods such as mechanical, chemical, thermal, and biological methods are discussed to improve the rate-limiting hydrolytic step in the digestion processes. The operation parameters of a reactor system are also reviewed with consideration of the characteristics of the substrates. Since the environmental awareness and concerns for waste management systems have been increasing, this paper also addresses possible environmental impacts of AD and coAD in food waste treatment and recommends feasible methods to reduce the impacts. In addition, uncertainties in the life cycle assessment (LCA) studies are also discussed.

  16. The control of H2S in biogas using iron ores as in situ desulfurizers during anaerobic digestion process.

    Science.gov (United States)

    Zhou, Qiying; Jiang, Xia; Li, Xi; Jiang, Wenju

    2016-09-01

    In this study, five kinds of iron ores, limonite, hematite, manganese ore, magnetite and lava rock, were used as the in situ desulfurizers in the anaerobic digestion reactors to investigate their effects on controlling H2S in biogas. The results show that the addition of the five iron ores could significantly control the content of H2S in biogas, with the best performance for limonite. As limonite dosages increase (10-60 g/L), the contents of H2S in biogas were evidently decreased in the digesters with different initial sulfate concentrations (0-1000 mg/L). After the anaerobic digestion, the removed sulfur was mostly deposited on the surface of limonite. A possible mechanism of H2S control in biogas by limonite was proposed preliminarily, including adsorption, FeS precipitation, and Fe (III) oxidation. The results demonstrated that limonite was a promising in situ desulfurizer for controlling H2S in biogas with low cost and high efficiency.

  17. Feeding biogas into the natural gas network; Einspeisung von Biogas ins Erdgasnetz

    Energy Technology Data Exchange (ETDEWEB)

    Hunziker, P.

    2005-07-01

    This article discusses how the existing use of biogas from the regional sewage treatment plant in Lucerne, Switzerland, has been extended to feed the biogas into the normal natural gas supply mains. The biogas has previously been used to fuel combined heat and power units that provide electricity and heating energy for dwellings in the region. The article describes how excess biogas from sewage treatment has been conditioned for feeding into the area's natural gas network. The use of an eco-balance tool in the choice of the most ecological means of using the biogas is described. The process steps used to purify the biogas are examined, as are the investment costs and yearly operational expenditure for the operation of the installations.

  18. Methanogenesis in Thermophilic Biogas Reactors

    DEFF Research Database (Denmark)

    Ahring, Birgitte Kiær

    1995-01-01

    Methanogenesis in thermophilic biogas reactors fed with different wastes is examined. The specific methanogenic activity with acetate or hydrogen as substrate reflected the organic loading of the specific reactor examined. Increasing the loading of thermophilic reactors stabilized the process...... as indicated by a lower concentration of volatile fatty acids in the effluent from the reactors. The specific methanogenic activity in a thermophilic pilot-plant biogas reactor fed with a mixture of cow and pig manure reflected the stability of the reactor. The numbers of methanogens counted by the most...... against Methanothrix soehngenii or Methanothrix CALS-I in any of the thermophilic biogas reactors examined. Studies using 2-14C-labeled acetate showed that at high concentrations (more than approx. 1 mM) acetate was metabolized via the aceticlastic pathway, transforming the methyl-group of acetate...

  19. A review of chemical absorption of carbon dioxide for biogas upgrading

    Institute of Scientific and Technical Information of China (English)

    Fouad RH Abdeen; Maizirwan Mel; Mohammed Saedi Jami; Sany Izan Ihsan; Ahmad Faris Ismail

    2016-01-01

    Significant attention has been given to biogas production, purification and upgrading as a renewable and clean fuel supplement. Biogas is a product of an anaerobic digestion process comprising methane, carbon dioxide, and trace amounts of other gases. Biogas purification removes trace gases in biogas for safe utilisation. Biogas upgrading produces methane-rich biogas by removing bulk carbon dioxide from the gas mixture. Several carbon dioxide removal techniques can be applied for biogas upgrading. However, chemical absorption of carbon dioxide for biogas upgrading is of special significance due to its operation at ambient or near ambient temperature and pressure, thus reducing energy consumption. This paper reviews the chemical absorption of carbon dioxide using amine scrubbing, caustic solvent scrubbing, and amino acid salt solution scrubbing. Each of these tech-niques for biogas upgrading is discussed. The paper concludes that an optimised implementation of the chemical absorption techniques for biogas upgrading requires further research.

  20. Study of the Process of Hydraulic Mixing in Anaerobic Digester of Biogas Plant

    Directory of Open Access Journals (Sweden)

    Karaeva Julia V.

    2015-03-01

    Full Text Available Two systems of hydraulic mixing in a vertical cylindrical anaerobic digester: standard and modernised are discussed in the paper. Numerical investigations that were carried out are focused on a study of hydrodynamic processes in an aerobic digester using two various systems of hydraulic mixing as well as on analysis of the efficiency of methane fermentation process accomplished under different geometric parameters of an anaerobic digester and systems of hydraulic mixing.

  1. Biogas from lignocellulosic biomass

    Energy Technology Data Exchange (ETDEWEB)

    Berglund Odhner, Peter; Schabbauer, Anna [Grontmij AB, Stockholm (Sweden); Sarvari Horvath, Ilona; Mohseni Kabir, Maryam [Hoegskolan i Boraas, Boraas (Sweden)

    2012-01-15

    Grontmij AB has cooperated with the University of Boraas to evaluate the technological and economical possibilities for biogas production from substrates containing lignocellulose, such as forest residues, straw and paper. The state of knowledge regarding biogas production from cellulosic biomass has been summarized. The research in the field has been described, especially focusing on pretreatment methods and their results on increased gas yields. An investigation concerning commercially available pretreatment methods and the cost of these technologies has been performed. An economic evaluation of biogas production from lignocellulosic materials has provided answers to questions regarding the profitability of these processes. Pretreatment with steam explosion was economically evaluated for three feedstocks - wood, straw and paper - and a combination of steam explosion and addition of NaOH for paper. The presented costs pertain to costs for the pretreatment step as it, in this study, was assumed that the pretreatment would be added to an existing plant and the lignocellulosic substrates would be part of a co-digestion process. The results of the investigation indicate that it is difficult to provide a positive net result when comparing the cost of pretreatment versus the gas yield (value) for two of the feedstocks - forest residues and straw. This is mainly due to the high cost of the raw material. For forest residues the steam pretreatment cost exceeded the gas yield by over 50 %, mainly due to the high cost of the raw material. For straw, the production cost was similar to the value of the gas. Paper showed the best economic result. The gas yield (value) for paper exceeded the pretreatment cost by 15 %, which makes it interesting to study paper further.

  2. Systematic Quantification of Biogas Potential in Urban Organic Waste

    DEFF Research Database (Denmark)

    Fitamo, Temesgen Mathewos

    of biogas from organic waste rather than incineration and landfilling. The production of biogas from urban organic waste is expected to contribute to reaching the EU target of 20% of overall energy production and 10% of vehicle fuel derived from renewable sources by 2020. The Danish energy strategy...... is for Demark to become a 100% fossil fuel-free nation by 2050. However, existing technical challenges and barriers must be overcome to make the production of biogas more attractive. In this respect, a systematic quantification of the biogas production potential of various urban organic waste sources...... is necessary, in order to analyse and improve processes for biogas production. Conventionally, the potential biogas production of organic waste sources is quantified through biochemical methane potential (BMP) analysis and anaerobic digestion in biogas reactors. However, the determination of BMP in batch...

  3. Process model for ammonia volatilization from anaerobic swine lagoons incorporating varying wind speeds and biogas bubbling

    Science.gov (United States)

    Ammonia volatilization from treatment lagoons varies widely with the total ammonia concentration, pH, temperature, suspended solids, atmospheric ammonia concentration above the water surface, and wind speed. Ammonia emissions were estimated with a process-based mechanistic model integrating ammonia ...

  4. Integrated extraction and anaerobic digestion process for recovery of nutraceuticals and biogas from pomegranate marcs

    Science.gov (United States)

    Pomegranate marc (PM), a by-product from pomegranate juice processing, has not been effectively utilized. The objectives of this study were to (1) determine the yields and properties of antioxidants (henceforth referring to total phenolics in terms of tannic acid equivalent) and oil extracted from v...

  5. Replacing Natural Gas by Biogas — Determining the Bacterial Contamination of Biogas by PCR

    Directory of Open Access Journals (Sweden)

    Jiřina Čermáková

    2012-01-01

    Full Text Available A promising way of using biogas is to upgrade it to natural gas, which is referred to as Substitute Natural Gas (SNG or biomethane. Biomethane, or biogas, is produced by biological processes of harnessing the ability of microorganisms to degrade organic material to methane. Some of the microorganisms are aerosolized from the digester into the biogas; afterwards a bio-film is formed that attaches to the surfaces of the distribution pipes, and can find it was to the place where the end use of biogas takes place. This paper deals with the detection of microbial species in biogas, their influenceon corrosion and the potential risk that diseases can be spread via biogas using molecular techniques. Using molecular methods, we found that raw biogas contains about 8 million microorganisms per m3, which is most likely the result of microbial transmission from the anaerobic digestion process. Some bacterial species may contribute to the corrosion of pipelines and equipment; others are opportunistic pathogens that can cause toxic reactions. However, most bacterial species, more than 40 % in biogas, are still unknown, as is their influence on the digestion process and on human health. Further studies are needed to better understand the behavior of microorganisms in anaerobic digestion and to preventmicrobial-influenced corrosion and microbial dissemination.

  6. ANAEROBIC DIGESTION MODEL ANALYSIS OF THE FERMENTATION PROCESS IN PSYCHROPHILIC AND MESOPHILIC CHAMBER IN ACCORDANCE WITH THE AMOUNT OF BIOGAS SOURCED

    Directory of Open Access Journals (Sweden)

    Dariusz Zdebik

    2015-03-01

    Full Text Available The paper presents problems concerning the modelling of anaerobic sludge stabilization, with the additional substrate (waste transported, dairy butchery sewage in psychrophilic fermentation conditions in the range 10–20 °C and mesophilic at 35 °C. Simulation test was conducted in the two digesters. Results of the study allowed to evaluate the effectiveness of conducting these processes in separate chambers, i.e. the psychrophilic and mesophilic chamber. During the simulations, terms of obtaining volatile fatty acids and biogas in conjunction with the operating conditions of the chambers indicated.

  7. Mathematical modelization of physical process of biogas migration in sanitary landfills of urban solid wastes; Modelizacion matematica del proceso fisico de migracion del biogas en vertederos controlados de R.S.U

    Energy Technology Data Exchange (ETDEWEB)

    Maranon Maison, E.; Sastre Andres, H.; Martin Gonzalez, S.

    1997-09-01

    An analysis of the laws that govern the biogas movements inside the landfill is carried out. The mathematical equations needed to resolve the problem are studied. Then, a model is defined and used to calculate the biogas movements in several situations. The results obtained are contrasted with data from the bibliography and with tests carried out at the La Zoreda, Landfill (Asturias Spain). (Author) 11 refs.

  8. Enhanced biogas recovery by applying post-digestion in large-scale centralized biogas plants

    DEFF Research Database (Denmark)

    Angelidaki, Irini; Hejnfelt, Anette; Ellegaard, L.

    2006-01-01

    The main objective of this study was to investigate the degradation efficiency of centralized biogas plants and provide guidance for the design of more efficient digester and post-digestion systems. These centralized biogas plants in Denmark digest manure together with organic waste from the food...... industry to generate biogas, which is used for electricity and thermal energy. A total of 20 such plants are currently active in Denmark, most of which were included in the investigation. From the plants, samples were obtained from various steps of the process. Samples were analysed and the residual biogas...... potential determined by batch post-digestion at various temperature levels. Results were correlated with plant characteristics and production statistics in order to judge the efficiency of various digestion concepts. A simplified model based on a two-step biogas production process was developed...

  9. Effects of fuel processing methods on industrial scale biogas-fuelled solid oxide fuel cell system for operating in wastewater treatment plants

    Science.gov (United States)

    Farhad, Siamak; Yoo, Yeong; Hamdullahpur, Feridun

    The performance of three solid oxide fuel cell (SOFC) systems, fuelled by biogas produced through anaerobic digestion (AD) process, for heat and electricity generation in wastewater treatment plants (WWTPs) is studied. Each system has a different fuel processing method to prevent carbon deposition over the anode catalyst under biogas fuelling. Anode gas recirculation (AGR), steam reforming (SR), and partial oxidation (POX) are the methods employed in systems I-III, respectively. A planar SOFC stack used in these systems is based on the anode-supported cells with Ni-YSZ anode, YSZ electrolyte and YSZ-LSM cathode, operated at 800 °C. A computer code has been developed for the simulation of the planar SOFC in cell, stack and system levels and applied for the performance prediction of the SOFC systems. The key operational parameters affecting the performance of the SOFC systems are identified. The effect of these parameters on the electrical and CHP efficiencies, the generated electricity and heat, the total exergy destruction, and the number of cells in SOFC stack of the systems are studied. The results show that among the SOFC systems investigated in this study, the AGR and SR fuel processor-based systems with electrical efficiency of 45.1% and 43%, respectively, are suitable to be applied in WWTPs. If the entire biogas produced in a WWTP is used in the AGR or SR fuel processor-based SOFC system, the electricity and heat required to operate the WWTP can be completely self-supplied and the extra electricity generated can be sold to the electrical grid.

  10. BIOGAS STATIONS AND THEIR ENVIRONMENTAL IMPACTS

    Directory of Open Access Journals (Sweden)

    Vladimir Lapčik

    2011-12-01

    Full Text Available The article summarizes the authors’ experience with environmental impact assessment in branch of biogas plants. The introductory part of the paper describes legislative obligations of the Czech Republic concerning the fulfilment of the European Union’s limits as for utilization of renewable energy resources. The next parts of the paper deal with an impact analysis of biogas plants on the environment. The final part of the paper deals with experience with implementation of the environmental impact assessment process in the field of biogas plants in the Czech Republic.

  11. Bioelectrochemical treatment of table olive brine processing wastewater for biogas production and phenolic compounds removal.

    Science.gov (United States)

    Marone, A; Carmona-Martínez, A A; Sire, Y; Meudec, E; Steyer, J P; Bernet, N; Trably, E

    2016-09-01

    Industry of table olives is widely distributed over the Mediterranean countries and generates large volumes of processing wastewaters (TOPWs). TOPWs contain high levels of organic matter, salt, and phenolic compounds that are recalcitrant to microbial degradation. This work aims to evaluate the potential of bioelectrochemical systems to simultaneously treat real TOPWs and recover energy. The experiments were performed in potentiostatically-controlled single-chamber systems fed with real TOPW and using a moderate halophilic consortium as biocatalyst. In conventional anaerobic digestion (AD) treatment, ie. where no potential was applied, no CH4 was produced. In comparison, Bio-Electrochemical Systems (BES) showed a maximum CH4 yield of 701 ± 13 NmL CH4·LTOPW(-1) under a current density of 7.1 ± 0.4 A m(-2) and with a coulombic efficiency of 30%. Interestingly, up to 80% of the phenolic compounds found in the raw TOPW (i.e. hydroxytyrosol and tyrosol) were removed. A new theoretical degradation pathway was proposed after identification of the metabolic by-products. Consistently, microbial community analysis at the anode revealed a clear and specific enrichment in anode-respiring bacteria (ARB) from the genera Desulfuromonas and Geoalkalibacter, supporting the key role of these electroactive microorganisms. As a conclusion, bioelectrochemical systems represent a promising bioprocess alternative for the treatment and energy recovery of recalcitrant TOPWs.

  12. Progress in biogas. Biogas production from agricultural biomass and organic residues. Pt. 1 and 2. Proceedings (oral presentations and poster presentations); Fortschritt beim Biogas. Biogas aus landwirtschaftlicher Biomasse and organischen Reststoffen. T. 1 und 2. Tagungsband. Vortraege and Poster

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    Within the International Conference ''Progress in Biogas - Biogas production from agricultural biomass and organic residues'' at the University Hohenheim (Stuttgart, Federal Republic of Germany) from 18th to 21st September, 2007, the following lectures were held: (1) Global relevance and potential of bioenergy for regional development; (2) Biogas electricity for France feed-in tariff and some other things to know before entering French market; (3) Policy drivers and future prospects for on-farm anaerobic digestion in Northern Ireland; (4) Biogas in Belgium, a swot analysis; (5) Status and prospects of biogas energy use in Ukraine; (6) Recent developments in Chinese agricultural biogas production; (7) Opportunities for agricultural based biogas systems in the province of Ontario, Canada; (8) Pre-treatment and digestion of separated collected household waste in Sweden; (9) To the problem of monitoring measures and prophylaxis measures with the utilization of organic residual substances in biological gas facilities from hygienic view; (10) Fermenting residues from biological gas facilities - nutrients and pollutants, possibilities of application in the agriculture; (11) Treatment and utilization of fermentation residues; (12) Potential of residual gas of NaWaRo feeded biogas plants in Baden-Wuerttemberg; (13) Operating analytics of biogas plants to improve efficiency and to ensure process stability; (14) The potential of biogas and electric power production from subproducts in the sugar and alcohol industries by the application of anaerobic digestion; (15) Co-digestion plant in dairy cattle farm in Emilia Romagna region (Italy); (16) Facing operational problems in a biodigeser in Yuvientsa - Amazonian Region of Ecuador; (17) Biogas plant instead of milk cow - payment and occupation with the use of grassilage; (18) Biogas in ecologic agriculture - experiences from 3 years of fermentation of grass-clover ley; (19) Combined solar-biogas basis for the

  13. Improvement of Biogas Production by Bioaugmentation

    Directory of Open Access Journals (Sweden)

    K. L. Kovács

    2013-01-01

    Full Text Available Biogas production technologies commonly involve the use of natural anaerobic consortia of microbes. The objective of this study was to elucidate the importance of hydrogen in this complex microbial food chain. Novel laboratory biogas reactor prototypes were designed and constructed. The fates of pure hydrogen-producing cultures of Caldicellulosiruptor saccharolyticus and Enterobacter cloacae were followed in time in thermophilic and mesophilic natural biogas-producing communities, respectively. Molecular biological techniques were applied to study the altered ecosystems. A systematic study in 5-litre CSTR digesters revealed that a key fermentation parameter in the maintenance of an altered population balance is the loading rate of total organic solids. Intensification of the biogas production was observed and the results corroborate that the enhanced biogas productivity is associated with the increased abundance of the hydrogen producers. Fermentation parameters did not indicate signs of failure in the biogas production process. Rational construction of more efficient and sustainable biogas-producing microbial consortia is proposed.

  14. Wood ash amendment to biogas reactors as an alternative to landfilling? A preliminary study on changes in process chemistry and biology.

    Science.gov (United States)

    Podmirseg, Sabine M; Seewald, Martin S A; Knapp, Brigitte A; Bouzid, Ourdia; Biderre-Petit, Corinne; Peyret, Pierre; Insam, Heribert

    2013-08-01

    Wood ash addition to biogas plants represents an alternative to commonly used landfilling by improving the reactor performance, raising the pH and alleviating potential limits of trace elements. This study is the first on the effects of wood ash on reactor conditions and microbial communities in cattle slurry-based biogas reactors. General process parameters [temperature, pH, electrical conductivity, ammonia, volatile fatty acids, carbon/nitrogen (C/N), total solids (TS), volatile solids, and gas quantity and quality] were monitored along with molecular analyses of methanogens by polymerase chain reaction- denaturing gradient gel electrophoresis and modern microarrays (archaea and bacteria). A prompt pH rise was observed, as was an increase in C/N ratio and volatile fatty acids. Biogas production was inhibited, but recovered to even higher production rates and methane concentration after single amendment. High sulphur levels in the wood ash generated hydrogen sulphide and potentially hampered methanogenesis. Methanosarcina was the most dominant methanogen in all reactors; however, diversity was higher in ash-amended reactors. Bacterial groups like Firmicutes, Proteobacteria and Acidobacteria were favoured, which could improve the hydrolytic efficiency of the reactors. We recommend constant monitoring of the chemical composition of the used wood ash and suggest that ash amendment is adequate if added to the substrate at a rate low enough to allow adaptation of the microbiota (e.g. 0.25 g g(-1) TS). It could further help to enrich digestate with important nutrients, for example phosphorus, calcium and magnesium, but further experiments are required for the evaluation of wood ash concentrations that are tolerable for anaerobic digestion.

  15. Genetics Home Reference: propionic acidemia

    Science.gov (United States)

    ... Propionic acidemia affects about 1 in 100,000 people in the United States. The condition appears to be more common in several populations worldwide, including the Inuit population of Greenland, some Amish communities, and Saudi Arabians. Related Information What information about a genetic ...

  16. Trace compounds affecting biogas energy utilisation - A review

    Energy Technology Data Exchange (ETDEWEB)

    Rasi, S., E-mail: saija.rasi@gmail.com [University of Jyvaeskylae, Department of Biological and Environmental Science, P.O. Box 35, FI-40014 (Finland); Laentelae, J.; Rintala, J. [University of Jyvaeskylae, Department of Biological and Environmental Science, P.O. Box 35, FI-40014 (Finland)

    2011-11-15

    Highlights: {yields} In regards to trace compounds, landfill gases are the most studied biogases. {yields} More strict requirements are set for biogas purity with new biogas applications. {yields} With traditional applications, small variations in biogas quality are acceptable. {yields} New requirements set challenges on raw material control and biogas quality. {yields} In this study, variations in analysing methods and biogas quality are discussed. - Abstract: This paper investigates the trace compounds affecting energy utilisation in biogas that come from different production sites. With biogas being more widely used in different energy applications more interest has arisen for the specific composition of biogas. In traditional energy applications, methane and hydrogen sulphide contents have had the most influence when energy utilisation application has been considered. With more advanced processes also the quantity and quality of trace compounds is more important. In regards to trace compounds, it was found that the concentrations and the variations of volatile organic compounds (VOCs) can be high in different landfills, especially, with compounds originating from the biological degradation process (like aromatics and terpenes) as seasonal variations affect the biological degradation. Trace compounds produced by direct volatilisation (halogenated and silicon compounds) show a smaller seasonal variation. Halogenated compounds are rarely present in high concentrations in waste water treatment plant (WWTP) biogas, but the concentrations of organic silicon compounds and their variation is high. Organic silicon compounds are usually detected only in low concentrations in co-digestion plant biogas, when no WWTP sludge is used as a raw material.

  17. MODERN BIOGAS TECHNOLOGIES

    Directory of Open Access Journals (Sweden)

    Yu. I. Sidorov

    2013-02-01

    Full Text Available The modern technical level of biogas technologies is considered, in particular in Ukraine. It is shown that in Ukraine the level of introduction of these technologies remains unsatisfactory. The main reason of such state is absence of the government program of development of sufficiently not profitable biogas industry, which again depends on availability of investment facilities including the state one. On the example of the company’s data Zorg Biogas AG, which is dominant in Ukraine among the foreign ones that offer their products using the technique of the net present value — NPV — it is shown insolvency of functioning of profitable biogas power plants. A conclusion is done about the necessity of orientation on own development in area of biogas technologies, State support and intensive technologies. The world level of modern intensive biogas technologies, in particular the use of the cogeneration plants.

  18. Increase of Bio-Gas Power Potential

    OpenAIRE

    V. Sednin; О. Kraetskaya; I. Prokoрenia

    2012-01-01

    The paper presents a review of industrial technologies for obtaining gas-synthesis which is applicable for bio-gas enrichment process. Comparative characteristics are given in the paper. The paper thoroughly considers a technology of dry methane conversion as the most expedient variant recommended for the application in this case. The bio-gas enrichment carried out during its production expands possibilities and efficiency of its application.

  19. Biogas Production from Vinasse

    DEFF Research Database (Denmark)

    de Souza Moraes, Bruna; Triolo, Jin Mi; Pulido Lecona, Vanessa

    2014-01-01

    In many developing countries, simple biogas digesters are used to produce energy for domestic purposes from anaerobic digestion of animal manure. We developed a simple, one-dimensional (1-D), thermal model with easily-available input data for unheated, unstirred, uninsulated, fixed-dome digesters...... buried in the soil to study heat transfer between biogas digester and its surroundings. The predicted temperatures in the dome, biogas and slurry inside the digester and the resulting biogas production are presented and validated. The model was well able to estimate digester temperature (linear slope...

  20. Basic Data on Biogas

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-07-01

    Renewable gases such as biogas and biomethane are considered as key energy carrier when the society is replacing fossil fuels with renewable alternatives. In Sweden, almost 80 % of the fossil fuels are used in the transport sector. Therefore, the focus in Sweden has been to use the produced biogas in this sector as vehicle gas. Basic Data on Biogas contains an overview of production, utilisation, climate effects etc. of biogas from a Swedish perspective. The purpose is to give an easy overview of the current situation in Sweden for politicians, decision makers and interested public. 1.4 TWh of biogas is produced annually in Sweden at approximately 230 facilities. The 135 wastewater treatment plants that produce biogas contribute with around half of the production. In order to reduce the sludge volume, biogas has been produced at wastewater treatment plants for decades. New biogas plants are mainly co-digestion plants and farm plants. The land filling of organic waste has been banned since 2005, thus the biogas produced in landfills is decreasing.

  1. Microbiologic handbook for biogas plants; Mikrobiologisk handbok foer biogasanlaeggningar

    Energy Technology Data Exchange (ETDEWEB)

    Jarvis, Aasa; Schnuerer, Anna

    2009-05-15

    There is today great interest in the biogas process. The reason for interest is that this process offers an opportunity to stabilize and reduce various types of organic waste, while also generating clean renewable energy in the form of biogas. Purified biogas is a good alternative to gasoline and diesel as motor fuel and can also be used for heating and electricity production. Behind efficient biogas production lies a complex microbiological process. For biogas to be formed many different species of microorganisms have to be active. A disturbance of this teamwork leads to a reduction in biogas production or in the worst case that the process stops. In order to operate a biogas process in an efficient manner, it is necessary to have knowledge of the underlying microbiology and how microorganisms function. Today Swedish biogas plants have personnel with great technical knowledge, while the biological knowledge often is more limited. It has been difficult to find appropriate Swedish language literature in the field. This handbook aims to increase the microbiological expertise of staff at the biogas plants and thus to facilitate the stable operation and optimization of gas production

  2. Biogas Production: Microbiology and Technology.

    Science.gov (United States)

    Schnürer, Anna

    Biogas, containing energy-rich methane, is produced by microbial decomposition of organic material under anaerobic conditions. Under controlled conditions, this process can be used for the production of energy and a nutrient-rich residue suitable for use as a fertilising agent. The biogas can be used for production of heat, electricity or vehicle fuel. Different substrates can be used in the process and, depending on substrate character, various reactor technologies are available. The microbiological process leading to methane production is complex and involves many different types of microorganisms, often operating in close relationships because of the limited amount of energy available for growth. The microbial community structure is shaped by the incoming material, but also by operating parameters such as process temperature. Factors leading to an imbalance in the microbial community can result in process instability or even complete process failure. To ensure stable operation, different key parameters, such as levels of degradation intermediates and gas quality, are often monitored. Despite the fact that the anaerobic digestion process has long been used for industrial production of biogas, many questions need still to be resolved to achieve optimal management and gas yields and to exploit the great energy and nutrient potential available in waste material. This chapter discusses the different aspects that need to be taken into consideration to achieve optimal degradation and gas production, with particular focus on operation management and microbiology.

  3. Combustion of Biogas Released from Palm Oil Mill Effluent and the Effects of Hydrogen Enrichment on the Characteristics of the Biogas Flame

    Directory of Open Access Journals (Sweden)

    Seyed Ehsan Hosseini

    2015-01-01

    Full Text Available Biogas released from palm oil mill effluent (POME could be a source of air pollution, which has illustrated negative effects on the global warming. To protect the environment from toxic emissions and use the energy of POME biogas, POME is conducted to the closed digestion systems and released biogas is captured. Since POME biogas upgrading is a complicated process, it is not economical and thus new combustion techniques should be examined. In this paper, POME biogas (40% CO2 and 60% CH4 has been utilized as a fuel in a lab-scale furnace. A computational approach by standard k-ε combustion and turbulence model is applied. Hydrogen is added to the biogas components and the impacts of hydrogen enrichment on the temperature distribution, flame stability, and pollutant formation are studied. The results confirm that adding hydrogen to the POME biogas content could improve low calorific value (LCV of biogas and increases the stability of the POME biogas flame. Indeed, the biogas flame length rises and distribution of the temperature within the chamber is uniform when hydrogen is added to the POME biogas composition. Compared to the pure biogas combustion, thermal NOx formation increases in hydrogen-enriched POME biogas combustion due to the enhancement of the furnace temperature.

  4. Application of Aquatic Plants to The Post-processing of Biogas Project%水生植物在沼气工程后处理中的应用

    Institute of Scientific and Technical Information of China (English)

    李劲廷; 蒲小东

    2012-01-01

    针对沼气工程中的厌氧(沼气)-自然处理模式,文章阐释了水生植物的概念,分析了水生植物在沼气工程后处理中的净水机理及运用,并对水生植物在沼气工程后处理中的选配提出了相应的建议.%For the anaerobic (biogas)-natural post treatment model in the biogaa project, this paper briefly explained the concept of aquatic plants, analyzed the mechanism and application of aquatic plants for the post-processing of biogas project. Corresponding aquatic plants matching the biogas project were proposed.

  5. Storage of catch crops to produce biogas

    DEFF Research Database (Denmark)

    Molinuevo-Salces, Beatriz; Ahring, Birgitte Kiær; Uellendahl, Hinrich

    2014-01-01

    Catch crop biomass is a promising co-substrate for manure-based biogas plants in Denmark since the cultivation of catch crops is mandatory to retain nutrients in the soil, contributing to protect the aquatic environment. In general, the growth period for catch crops is from harvest of the previous...... crop in July-August to the end of the growing season and harvest in late October. Hence, for use of the biomass in biogas production there is a need for storage of the biomass. Storage as silage would guarantee the availability of the feedstock for biogas production during the whole year. A proper...... ensiling process determines the storage loss and the quality of the final silage and, thus, the possible use of it as a substrate for biogas production. Moreover, silage has been considered as a pre-treatment since it partially hydrolyses organic matter improving cellulose convertibility. Since a large...

  6. Biogas production in agricultural distilleries. Gewinnung von Biogas in landwirtschaftlichen Brennereien

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    1993-02-01

    The malt residuum obtained during alcoholic fermentation in agricultural distilleries can be used for biogas production. The process of anaerobic fermentation is described, and its application in distilleries and environmental aspects are discussed. (SR)

  7. Clinical Spectrum of Propionic Acidaemia

    Directory of Open Access Journals (Sweden)

    Muhammad Rafique

    2013-01-01

    Full Text Available Objectives. To evaluate the clinical features, physical findings, diagnosis, and laboratory parameters of the patients with propionic acidaemia (PA. Methods. The records of diagnosed cases of propionic acidaemia were reviewed, retrospectively. Results. Twenty-six patients with PA had 133 admissions. The majority (85% of the patients exhibited clinical manifestations in the 1st week of life. Regarding clinical features, lethargy, fever, poor feeding, vomiting, dehydration, muscular hypotonia, respiratory symptoms, encephalopathy, disturbance of tone and reflexes, and malnutrition were observed in 51–92% admissions. Metabolic crises, respiratory diseases, hyperammonaemia, metabolic acidosis, hypoalbuminaemia, and hypocalcaemia were observed in 30–96% admissions. Pancytopenia, ketonuria, hypoproteinemia, hypoglycaemia, and mildly disturbed liver enzymes were found in 12–41% admissions. Generalised brain oedema was detected in 17% and cerebral atrophy in 25% admissions. Gender-wise odd ratio analysis showed value of 1.9 for lethargy, 1.99 for respiratory diseases, 0.55 for anaemia, and 1.82 for hypocalcaemia. Conclusion. Propionic acidaemia usually presents with wide spectrum of clinical features and disturbances of laboratory parameters in early neonatal age. It is associated with significant complications which deteriorate the patients’ quality of life. Perhaps with early diagnosis of the disease and in time intervention, these may be preventable.

  8. Biogas in agriculture. Status and prospects. Proceedings; Biogas in der Landwirtschaft. Stand und Perspektiven. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    Within the congress of the Agency for Renewable Resources (Guelzow, Federal Republic of Germany) and the Association for Technology and Structures in Agriculture (Darmstadt, Federal Republic of Germany) at 20th-21st September, 2011 in Goettingen (Federal Republic of Germany) the following lectures and posters were presented: (1) Perspectives of using biogas as a part of the German power supply (Stefan Rauh); (2) Development of biogas in Europe (Marc Fleureck); (3) Biology of methanogenic archaea and its significance for the microbial process control in biogas plants (Helmut Koenig); (4) Efficiency and behaviour of enzymes in the biogas process (Monika Heiermann); (5) Trace elements in NaWaRo biogas plants for balancing substrate limited deficiency symptoms and stabilizing the fermentation process (Hans Oechsner); (6) EEG - Actual developments for biogas (Ulrich Keymer); (7) Utilization of thermal energy from cogeneration in the practice - Experiences from the view of an environmental expert (Michael Hub); (8) Innovations in the legal aspects of the production and utilization of biogas (Hartwig von Bredow); (9) Damages and deficiencies at biogas plants (Waldemar Gruber); (10) Learning from accidents, damages and their causes as well as their correctives in the operation of biogas plants - Reports from the practice (Wolfgang Horst Stachowitz); (11) Causes and avoidance of container damages by means of biocorrosion (Jan Kuever); (12) Anaerobic degradation of cellulosic substrates - Bionic implementation of the forestomach sysem of a ruminant (Dirk Weichgrebe); (13) Fermentation of renewable raw materials in the up flow procedure (Jan Mumme); (14) Two-phase pressure fermentation for feeding into natural gas grids (Andreas Lemmer); (15) Requirements and potential of sugar beets for fermentation (Christa Hoffmann); (16) Innovation in the area of power beets (Andreas von Felde); (17) Optimization of manuring with fermentation residues in order to reduce the nitrogen

  9. Methods and apparatus for hydrogen based biogas upgrading

    DEFF Research Database (Denmark)

    2013-01-01

    The present invention relates to an anaerobic process for biogas upgrading and hydrogen utilization comprising the use of acidic waste as co-substrate.In this process,H2 and CO2 will be converted to CH4, which will result in lower CO2 content in the biogas. The invention relates to both in situ...

  10. BIOGAS PRODUCTION FROM TOFU LIQUID WASTE ON TREATED AGRICULTURAL WASTES

    OpenAIRE

    Budy Rahmat; Tedi Hartoyo; Yaya Sunarya

    2014-01-01

    The Tofu Liquid Waste (TLW) as a pollution might be processed into biogas which was environmentally friendly and had potential to replace burning wood or oil. However, the waste could not directly be employed as the biogas substrate due to the high nitrogen content which was not suitable to the methanogen microorganism on the biogas digester and did not produce biogas. It was therefore necessary to adapt the carbon-nitrogen ratio in TLW with the addition of other organic materials that had a ...

  11. Biogas Production Using Anaerobic Biodigester from Cassava Starch Effluent

    Directory of Open Access Journals (Sweden)

    S. Sunarso

    2010-12-01

    Full Text Available IKMs’ factory activity in Margoyoso produces liquid and solid wastes. The possible alternative was to use the liquid effluent as biogas raw material. This study focuses on the used of urea, ruminant, yeast, microalgae, the treatment of gelled and ungelled feed for biogas production, pH control during biogas production using buffer Na2CO3, and feeding management in the semi-continuous process of biogas production that perform at ambient temperature for 30 days. Ruminant bacteria, yeast, urea, and microalgae was added 10% (v/v, 0.08% (w/v, 0.04% (w/v, 50% (v/v of mixing solution volume, respectively. The pH of slurry was adjusted with range 6.8-7.2 and was measured daily and corrected when necessary with Na2CO3. The total biogas production was measured daily by the water displacement technique. Biogas production from the ungelling and gelling mixture of cassava starch effluent, yeast, ruminant bacteria, and urea were 726.43 ml/g total solid and 198 ml/g total solid. Biogas production from ungelling mixture without yeast was 58.6 ml/g total solid. Biogas production from ungelling mixture added by microalgae without yeast was 58.72 ml/g total solid and that with yeast was 189 ml/g total solid. Biogas production from ungelling mixture of cassava starch effluent, yeast, ruminant bacteria, and urea in semi-continuous process was 581.15 ml/g total solid. Adding of microalgae as nitrogen source did not give significant effect to biogas production. But adding of yeast as substrate activator was very helpful to accelerate biogas production. The biogas production increased after cassava starch effluent and yeast was added. Requirement of sodium carbonate (Na2CO3 to increase alkalinity or buffering capacity of fermenting solution depends on pH-value

  12. Energy systems analysis of biogas systems; Energianalys av biogassystem

    Energy Technology Data Exchange (ETDEWEB)

    Berglund, Maria; Boerjesson, Paal

    2003-05-01

    The aim of this study was to calculate the net energy output and energy efficiency, from a life-cycle perspective and for Swedish conditions, in anaerobic digestion of various raw materials. Our calculations are based on literature reviews concerning the total primary energy input required for the production of biogas (i.e. direct and indirect energy inputs, e.g. when producing and distributing diesel fuels, electricity, fertilisers) as well as the biogas yield from various raw materials. Our analyses include handling and transportation of raw materials, operation of the biogas plants, and transportation and spreading of digested residues, as well as the biogas yield from manure, ley crops, tops and leaves of sugar beets, straw, municipal organic waste, slaughter waste, and grease separator sludge. All calculations concern individual raw materials. The net energy input required to run a biogas system (i.e. centralised biogas plant) typically corresponds to approximately 20-40% of the energy content in the produced biogas. Theoretically, the raw materials could be transported for some 200 km (manure) up to 700 km (slaughter waste) before the net energy output becomes negative. The variations in energy efficiency between studied biogas systems depend mainly on the type of raw material studied and the calculation methods used. Raw materials with high water content and low biogas yield (e.g. manure) require rather large energy inputs compared to the amount of biogas produced. Energy demanding handling of the raw materials, such as ley crops, could correspond to as much as approximately 40% of the net energy input. Varying energy efficiency in different parts of the biogas system, but most of all, changes in the biogas yield, could considerably affect the total net energy output. In general, operation of the biogas plant is the most energy demanding process in the biogas systems, corresponding to some 40-80% of the net energy input in the biogas systems. This implies

  13. Floating geomembrane cover improves biogas collection

    Energy Technology Data Exchange (ETDEWEB)

    McMahon, J.

    2009-07-15

    Canadian corn products refiner, Casco Inc., recently upgraded a wastewater anaerobic digester at its automated corn wet milling facility on the St. Lawrence River, in Cardinal Ontario. The upgrade includes an improved floating and insulated geomembrane cover, designed and installed by Geomembrane Technologies Inc. The cover effectively streamlines biogas collection, improves biogas odour control and optimizes bioreactor heat retention. Casco's bulk volume fermenter (BVF) was designed and built in 1988 by ADI Systems Inc. It is limited to receiving 641,000 gallons of wastewater per day from several areas of the plant. Wastewater sludge is usually treated by anaerobic digestion. At Casco, raw solids are added directly to the BVF bioreactor, where they are digested, minimizing waste sludge handling. In essence, anaerobic digestion is a renewable energy source which converts wastewater to a methane- and carbon dioxide-rich biogas suitable for energy production, replacing fossil fuels. The insulated geomembrane cover captures and reclaims all the biogas from the treatment process that is going on inside the tank. Without a cover, the biogas would be released to the atmosphere. The new geomembrane cover collects an average of 236,000 cubic feet of biogas per day, at a 65 per cent methane concentration, from the BVF bioreactor. 2 figs.

  14. 基于CSTR和UASB工艺的沼气工程实例分析%Analysis on Biogas Engineering Based on the Processes of CSTR and UASB

    Institute of Scientific and Technical Information of China (English)

    余靖; 顾逸仙; 刘畅; 骆林平; 虞方伯; 翁佳丽; 阮乐华; 单胜道

    2012-01-01

    随着沼气技术的日渐成熟,各相关工艺不断发展完善,其中CSTR和UASB因其具备工艺简单,施工管理方便和运行效果好等优点而得以广泛运用.该文通过分析若干典型CSTR和UASB沼气工程,将二者特性进行对比,笔者认为CSTR具有独特的搅拌处理工艺.该工艺①可处理浓度较高的废液(TS 8%~12%);②发酵均匀产气率高;③处理量大,产沼气量多;④反应器结构简单,便于启动运行和管理.目前国外沼气工程技术先进的国家仍采用该工艺.与CSTR相比UASB工艺具有①占地面积小,前期投资成本低;②有机负荷高,处理高浓度有机废水的效果显著;③水力停留时间短,大量活性污泥聚集底部,发酵效果显著.基于这两种工艺的不同特性建议各地在兴建沼气工程时,应结合当地实情灵活运用,在引进先进技术的同时鼓励自主技术创新,使用适宜我国国情的高效沼气工程技术.%As the techniques of biogas fermentation developed rapidly, relevant processes boomed accordingly. Among these, CSTR and UASB were the most widely used in the biogas engineering due to the advantages of simpleness, convenience and efficiency. In this paper, several typical biogas engineerings based on the processes of CSTR and UASB were analyzed and compared with each other. As concluded by the author, CSTR has unique stirring process, which can treat high-concentration fermentation materials (TS 8% -12% ), and produce the gas largely and uniformly; it also has simple structure , which is easy to be started and managed. It is now used in most advanced countries. Compared with CSTR, UASB occupies little area and needs little investment, it is good to process high-concentration organic wastewater, its retention time is short, most of active sludge concentrates at the bottom, the fermentation effect is remarkable. Based on the features of two processes, they should be flexibly used given local conditions

  15. Investigation of factors influencing biogas production in a large-scale thermophilic municipal biogas plant

    Energy Technology Data Exchange (ETDEWEB)

    Weiss, Agnes; Jerome, Valerie; Freitag, Ruth [Bayreuth Univ. (Germany). Chair for Process Biotechnology; Burghardt, Diana; Likke, Likke; Peiffer, Stefan [Bayreuth Univ. (Germany). Dept. of Hydrology; Hofstetter, Eugen M. [RVT Process Equipment GmbH, Steinwiesen (Germany); Gabler, Ralf [BKW Biokraftwerke Fuerstenwalde GmbH, Fuerstenwalde (Germany)

    2009-10-15

    A continuously operated, thermophilic, municipal biogas plant was observed over 26 months (sampling twice per month) in regard to a number of physicochemical parameters and the biogas production. Biogas yields were put in correlation to parameters such as the volatile fatty acid concentration, the pH and the ammonium concentration. When the residing microbiota was classified via analysis of the 16S rRNA genes, most bacterial sequences matched with unidentified or uncultured bacteria from similar habitats. Of the archaeal sequences, 78.4% were identified as belonging to the genus Methanoculleus, which has not previously been reported for biogas plants, but is known to efficiently use H{sub 2} and CO{sub 2} produced by the degradation of fatty acids by syntrophic microorganisms. In order to further investigate the influence of varied amounts of ammonia (2-8 g/L) and volatile fatty acids on biogas production and composition (methane/CO{sub 2}), laboratory scale satellite experiments were performed in parallel to the technical plant. Finally, ammonia stripping of the process water of the technical plant was accomplished, a measure through which the ammonia entering the biogas reactor via the mash could be nearly halved, which increased the energy output of the biogas plant by almost 20%. (orig.)

  16. Biogas engineering technology screening based on analytic hierarchy process and fuzzy comprehensive evaluation%基于层次分析法和模糊综合评价的沼气工程技术筛选

    Institute of Scientific and Technical Information of China (English)

    向欣; 罗煜; 程红胜; 沈玉君; 王延昌; 张玉华

    2014-01-01

    process were applied to establish an index system for biogas technologies screening. The weights of the indices for the screening were worked out through investigation by experts in this field using AHP. Then, the biogas technologies were collated with the fuzzy comprehensive evaluation method. This decision making process was verified with the actual screening for a case of biogas technologies application site in China. The AHP and fuzzy comprehensive evaluation method combined could be used to solve the complicated multi-factor problem in decision making, thus not only overcoming the issue of subjectiveness of AHP in handling hard-to-quantify indices, but also avoiding the shortcoming of neglecting index weights with the fuzzy comprehensive evaluation method. It is, therefore, a good tool to screen biogas techniques for the recycling of agriculture waste. Comparisons of operating effects between two biogas technologies were carried out; the results from calculations based on the AHP and fuzzy comprehensive evaluation method were consistent with the facts of the real application at the two sites adopted with the two biogas technologies. Compared to completely mixed anaerobic technologies, red-sludge plastic anaerobic technology had better effects in terms of consumption of waste. In addition, red-sludge plastic anaerobic technology generated more electricity to meet the needs of a local village in Hubei on electricity expenditure, provided better solutions to the non source pollution contaminating water and soil, and even potentially helped reduce two released main gases, nitrogen dioxide and methane, that cause global climate change. All in all, the methods in this study will provide the methodology reference for assessing, selecting, integrating, and promoting biogas technology in China.%不同沼气工程技术对地域自然条件、环境制约条件、原料种类等因素的适应性有较大差异,科学客观的沼气工程技术筛选方法,是保证沼气

  17. Energy-Efficient Routes for the Production of Gasoline from Biogas and Pyrolysis Oil—Process Design and Life-Cycle Assessment

    Science.gov (United States)

    2017-01-01

    Two novel routes for the production of gasoline from pyrolysis oil (from timber pine) and biogas (from ley grass) are simulated, followed by a cradle-to-gate life-cycle assessment of the two production routes. The main aim of this work is to conduct a holistic evaluation of the proposed routes and benchmark them against the conventional route of producing gasoline from natural gas. A previously commercialized method of synthesizing gasoline involves conversion of natural gas to syngas, which is further converted to methanol, and then as a last step, the methanol is converted to gasoline. In the new proposed routes, the syngas production step is different; syngas is produced from a mixture of pyrolysis oil and biogas in the following two ways: (i) autothermal reforming of pyrolysis oil and biogas, in which there are two reactions in one reactor (ATR) and (ii) steam reforming of pyrolysis oil and catalytic partial oxidation of biogas, in which there are separated but thermally coupled reactions and reactors (CR). The other two steps to produce methanol from syngas, and gasoline from methanol, remain the same. The purpose of this simulation is to have an ex-ante comparison of the performance of the new routes against a reference, in terms of energy and sustainability. Thus, at this stage of simulations, nonrigorous, equilibrium-based models have been used for reactors, which will give the best case conversions for each step. For the conventional production route, conversion and yield data available in the literature have been used, wherever available.The results of the process design showed that the second method (separate, but thermally coupled reforming) has a carbon efficiency of 0.53, compared to the conventional route (0.48), as well as the first route (0.40). The life-cycle assessment results revealed that the newly proposed processes have a clear advantage over the conventional process in some categories, particularly the global warming potential and primary

  18. Biogas production from potato-juice, a by-product from potato-starch processing, in upflow anaerobic sludge blanket (UASB) and expanded granular sludge bed (EGSB) reactors

    DEFF Research Database (Denmark)

    Fang, Cheng; Boe, Kanokwan; Angelidaki, Irini

    2011-01-01

    In this study, the utilization of potato-juice, the organic by-product from potato-starch processing, for biogas production was investigated in batch assay and in high rate anaerobic reactors. The maximum methane potential of the potato-juice determined by batch assay was 470mL-CH4/g......VS-added. Anaerobic digestion of potato-juice in an EGSB reactor could obtain a methane yield of 380mL-CH4/gVS-added at the organic loading rate of 3.2gCOD/(L-reactor.d). In a UASB reactor, higher organic loading rate of 5.1gCOD/(L-reactor.d) could be tolerated, however, it resulted in a lower methane yield of 240m...

  19. Biogas Production Potential from Waste in Timis County

    Directory of Open Access Journals (Sweden)

    Teodor Vintila

    2012-05-01

    Full Text Available This work is a study of biogas production potential using as substrate the residues generated in the agricultural activities and the organic fraction from municipal wastes collected in Timis County. Data available in regional and national statistics have been reported to Timis County and used to calculate the potential quantity of biogas to be produced by anaerobic fermentation using as fermentable substrate residues generated in various human activities. To estimate the electric and thermal energy potential of the biogas, we considered the productivity of an average biogas plant couplet with a CHP unit with an efficiency of 40% net electric and 40% net thermal output and functioning 7500 hours per year. Processing data for the biogas production potential from livestock manure in Romania, we found that over 500 GWh of energy from biogas can be provided in one year. It is estimated that only half of the theoretical energy potential is technically usable by biogas investments. As for the crops residues, has been shown that the theoretical biogas potential is over 2900 GWh/year. Wastewater sludge can be converted in around 1700MWh/year, and the organic wastes available from municipal wastes can provide over 137 GWh/year. Another potential for renewable energy production in Timis County is the arable land uncultivated yearly, which can be used to cultivate energy crops, as raw material for biogas providing over 2800 GWh/year. All this quantity of biogas can be converted in numerous CHP biogas plants totaling an installed power of over 340 MWel. This potential can contribute to reach the target for 2020 in Romania to build biogas plants totaling at least 195 MWel. installed power, with an output of 950 GW electric power. 

  20. The treatment of balanitis xerotica obliterans with testosterone propionate ointment.

    Science.gov (United States)

    Pasieczny, T A

    1977-01-01

    Balanitis xerotica obliterans (BXO) and kraurosis penis are thought to be synonymous. Clinically and histopathologically they probably represent the same disease process as lichen sclerosus et atrophicus (LSA) but also involve the urethral mucosa. The treatment of choice is considered to be 2 1/2% testosterone propionate ointment which gives better results than strong corticosteroid applications, yet without their side effects.

  1. Anaerobic digestion foaming in full-scale biogas plants: A survey on causes and solutions

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Boe, Kanokwan; O-Thong, Sompong;

    2014-01-01

    Anaerobic digestion foaming is a common operation problem in biogas plants with negative impacts on the biogas plants economy and environment. A survey of 16 Danish full-scale biogas plants on foaming problems revealed that most of them had experienced foaming in their processes up to three times...

  2. Thermal decomposition of lutetium propionate

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude

    2010-01-01

    The thermal decomposition of lutetium(III) propionate monohydrate (Lu(C2H5CO2)3·H2O) in argon was studied by means of thermogravimetry, differential thermal analysis, IR-spectroscopy and X-ray diffraction. Dehydration takes place around 90 °C. It is followed by the decomposition of the anhydrous ...... of the oxycarbonate to the rare-earth oxide proceeds in a different way, which is here reminiscent of the thermal decomposition path of Lu(C3H5O2)·2CO(NH2)2·2H2O...

  3. Improved biogas production from rice straw by co-digestion with kitchen waste and pig manure

    Energy Technology Data Exchange (ETDEWEB)

    Ye, Jingqing [Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640 (China); School of Environmental Sciences and Engineering, Sun Yat-sen University, Guangzhou 510275 (China); Li, Dong; Sun, Yongming [Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640 (China); Wang, Guohui [School of Environmental Sciences and Engineering, Sun Yat-sen University, Guangzhou 510275 (China); Yuan, Zhenhong, E-mail: yuanzh@ms.giec.ac.cn [Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640 (China); Zhen, Feng; Wang, Yao [Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640 (China)

    2013-12-15

    Highlights: • Biogas production was enhanced by co-digestion of rice straw with other materials. • The optimal ratio of kitchen waste, pig manure and rice straw is 0.4:1.6:1. • The maximum biogas yield of 674.4 L/kg VS was obtained. • VFA inhibition occurred when kitchen waste content was more than 26%. • The dominant VFA were propionate and acetate in successful reactors. - Abstract: In order to investigate the effect of feedstock ratios in biogas production, anaerobic co-digestions of rice straw with kitchen waste and pig manure were carried out. A series of single-stage batch mesophilic (37 ± 1 °C) anaerobic digestions were performed at a substrate concentration of 54 g/L based on volatile solids (VS). The results showed that the optimal ratio of kitchen waste, pig manure, and rice straw was 0.4:1.6:1, for which the C/N ratio was 21.7. The methane content was 45.9–70.0% and rate of VS reduction was 55.8%. The biogas yield of 674.4 L/kg VS was higher than that of the digestion of rice straw or pig manure alone by 71.67% and 10.41%, respectively. Inhibition of biogas production by volatile fatty acids (VFA) occurred when the addition of kitchen waste was greater than 26%. The VFA analysis showed that, in the reactors that successfully produced biogas, the dominant intermediate metabolites were propionate and acetate, while they were lactic acid, acetate, and propionate in the others.

  4. Combustion of Biogas Released from Palm Oil Mill Effluent and the Effects of Hydrogen Enrichment on the Characteristics of the Biogas Flame

    OpenAIRE

    Seyed Ehsan Hosseini; Ghobad Bagheri; Mostafa Khaleghi; Mazlan Abdul Wahid

    2015-01-01

    Biogas released from palm oil mill effluent (POME) could be a source of air pollution, which has illustrated negative effects on the global warming. To protect the environment from toxic emissions and use the energy of POME biogas, POME is conducted to the closed digestion systems and released biogas is captured. Since POME biogas upgrading is a complicated process, it is not economical and thus new combustion techniques should be examined. In this paper, POME biogas (40% CO2 and 60% CH4) has...

  5. Microbial analysis in biogas reactors suffering by foaming incidents

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; De Francisci, Davide; Treu, Laura

    2014-01-01

    Foam formation can lead to total failure of digestion process in biogas plants. In the present study, possible correlation between foaming and the presence of specific microorganisms in biogas reactors was elucidated. The microbial ecology of continuous fed digesters overloaded with proteins...

  6. Biogas. Present situation and future potential; Biogas. Nulaege och framtida potential

    Energy Technology Data Exchange (ETDEWEB)

    Nordberg, Ulf [Swedish Inst. of Agricultural and Environmental Engineering, Uppsala (Sweden)

    2006-12-15

    owners need to be improved increase the understanding of the whole management chain, agricultural production, transport, treatment and handling of biofertilizer. The number of production sites for biogas from landfills is decreasing and the amount of biogas from these is diminishing. The number of biogas plants for agricultural crops is likely to increase. Combination processes will increasingly develop towards extracting several different energy products and towards maximising the energy extraction from substrates.

  7. GlidArc-assisted production of synthesis gas from biogas

    Energy Technology Data Exchange (ETDEWEB)

    Czernichowski, A.; Czernichowski, M.; Wesolowska, K. [Etudes Chimiques et Physiques, La Ferte Saint Aubin (France)

    2003-07-01

    This paper elaborates on the use of a biogas reformer process based on the direct use of high-voltage discharges (also called GlidArc) which strike in the flow of renewable feedstock without requiring prior gas separation or purification. The paper describes the partial conversion of a poor biogas into hydrogen and carbon monoxide (syngas). The biogas contained only 35 to 50 volume per cent of methane. The reformer accepts any level of impurities. All the energy and catalytic assistance for endothermic process of dry reforming of methane plus carbon dioxide into hydrogen and carbon monoxide is provided by the discharges. A 1.4-litre reactor operating at atmospheric pressure was used to conduct the tests with simulated biogas, at up to 0.6 kilowatt. This input proved sufficient to process a flow of a poor biogas carrying up to 7 kilowatts of thermal power. 13 refs., 2 tabs., 3 figs.

  8. Mechanism and controlling strategy of the production and accumulation of propionic acid for anaerobic wastewater treatment

    Institute of Scientific and Technical Information of China (English)

    任南琪; 李建政; 赵丹; 陈晓蕾

    2002-01-01

    The production and accumulation of propionic acid affect significantly anaerobic wastewater treatment system, but the reasons are not approached until now. Based on the results of continuous-flow tests and the analysis of biochemistry and ecology, two mechanisms of producing propionic acid have been put forward. It is demonstrated that the reasons of propionic acid production and accumulation are not caused by higher hydrogen partial pressure. The combination of specific pH value and ORP is the ecological factor affecting propionic acid production, and the equilibrium regulation of NADH/NAD+ ratio in cells is the physiological factor. Meanwhile, it is put forward that using the two-phase anaerobic treatment process and the ethanol type fermentation in anaerobic reactor to avoid propionic acid accumulation are efficient methods.

  9. Progress in biogas. Biogas production from agricultural biomass and organic residues. Pt. 1 and 2. Proceedings (oral presentations and poster presentations); Fortschritt beim Biogas. Biogas aus landwirtschaftlicher Biomasse and organischen Reststoffen. T. 1 und 2. Tagungsband. Vortraege and Poster

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    Within the International Conference ''Progress in Biogas - Biogas production from agricultural biomass and organic residues'' at the University Hohenheim (Stuttgart, Federal Republic of Germany) from 18th to 21st September, 2007, the following lectures were held: (1) Global relevance and potential of bioenergy for regional development; (2) Biogas electricity for France feed-in tariff and some other things to know before entering French market; (3) Policy drivers and future prospects for on-farm anaerobic digestion in Northern Ireland; (4) Biogas in Belgium, a swot analysis; (5) Status and prospects of biogas energy use in Ukraine; (6) Recent developments in Chinese agricultural biogas production; (7) Opportunities for agricultural based biogas systems in the province of Ontario, Canada; (8) Pre-treatment and digestion of separated collected household waste in Sweden; (9) To the problem of monitoring measures and prophylaxis measures with the utilization of organic residual substances in biological gas facilities from hygienic view; (10) Fermenting residues from biological gas facilities - nutrients and pollutants, possibilities of application in the agriculture; (11) Treatment and utilization of fermentation residues; (12) Potential of residual gas of NaWaRo feeded biogas plants in Baden-Wuerttemberg; (13) Operating analytics of biogas plants to improve efficiency and to ensure process stability; (14) The potential of biogas and electric power production from subproducts in the sugar and alcohol industries by the application of anaerobic digestion; (15) Co-digestion plant in dairy cattle farm in Emilia Romagna region (Italy); (16) Facing operational problems in a biodigeser in Yuvientsa - Amazonian Region of Ecuador; (17) Biogas plant instead of milk cow - payment and occupation with the use of grassilage; (18) Biogas in ecologic agriculture - experiences from 3 years of fermentation of grass-clover ley; (19) Combined solar-biogas basis for the

  10. Classification of Commercial Biogas Digester and Comparison with Traditional Process%商品化沼气池分类及与传统沼气池比较分析

    Institute of Scientific and Technical Information of China (English)

    冉毅; 彭德全; 王超; 丁自立; 李晋梅; 陈子爱; 席江; 贺莉; 蒋鸿涛

    2012-01-01

    Commercial biogas digester is classified into five categories according to the material properties, marketing, and combining with the characteristics of rural household biogas construction, i. e. glass liber reinforced plastic, hard plastic, flexible plastic (FBR) , glass fiber reinforced cement (GRC) and steel tank. Advantages and disadvantages were expatiated in this paper. The analysis results showed that traditional process biogas digester is the main process in our country. Commercial biogas digester is of important supplement. Glass fiber reinforced plastic type is relatively appropriate material for the biogas digester, followed by PVC (polyvinyl chloride) , PP (polypropylene) and PE (polyethylene). Commercial biogas digester has advantage of better air tightness, short construction period. And construction quality, standard and the cost are easier to control. Therefore, commercial biogas digester could be developed suiting ones measures to local conditions.%文章根据商品化沼气池材料特性与市场行情,结合农村户用沼气池建设特点,将户用商品化沼气池划分为:玻璃钢,塑料硬体,塑料软体(FBR),增强水泥(GRC)和钢制5大类沼气池,分别阐述其优势和劣势,并将玻璃钢沼气池与传统沼气池比较分析得出:传统水泥沼气池是我国沼气建设的主力军,商品化沼气池可作为重要补充;玻璃钢是相对适宜的建池材料,其次是PVC(聚氯乙烯),PP(聚丙烯)和PE(聚乙烯)塑料;商品化沼气池具有气密性好、建设周期短、建池成本较低,建设质量、标准、成本易于统一控制等优势,但塑料材料抗老化性能有待提高,应因地制宜、循序渐进地推广.

  11. 15. Annual Meeting on biogas and bioenergy in agriculture. Proceedings; 15. Jahrestagung Biogas und Bioenergie in der Landwirtschaft. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The volume contains besides the general statements on environmental protection and energy savings in the future and biogas as great potential for the rural development the following contributions in four parts: 1. political enveloping conditions: biogas usage within the frame of the the new EEG; state of biogas usage in Baden-Wuerttemberg; practical experiences end perspectives for the biogas development; renewable raw materials from the view of environmenmental protection; 2. gas utilization: the bioenergy village Mauenheim - model for the rural area; compression ignition gas engines with biogenic ignition oils; realization and economic performance of gas engines with biogas; microgasturbines - engineering and chances, gas processing and feeding into the gas network; 3. substrate: influence of the energy plant agriculture on the regional structures; biogas plants: substrate control by TS sensing; fermentation of fusaria contaminated corn; substrate contracts in the view of revenue and contract legacy; energy plants agriculture in Baden-Wuerttemberg; 4. process biology: comparison of dry and wet fermentation; fundamentals, process stability analytical possibilities; start-up of a biogas plant; biogas process with external hydrolysis; problems in the fermenter - inhibitors and auxiliaries.

  12. Autism in patients with propionic acidemia

    NARCIS (Netherlands)

    Witters, P.; Debbold, E.; Crivelly, K.; Kerckhove, K. Vande; Corthouts, K.; Debbold, B.; Andersson, H.; Vannieuwenborg, L.; Geuens, S.; Baumgartner, M.; Kozicz, L.T.; Settles, L.; Morava, E.

    2016-01-01

    Certain inborn errors of metabolism have been suggested to increase the risk of autistic behavior. In an animal model, propionic acid ingestion triggered abnormal behavior resembling autism. So far only a few cases were reported with propionic acidemia and autistic features. From a series of twelve

  13. BIOGAS PRODUCTION FROM TOFU LIQUID WASTE ON TREATED AGRICULTURAL WASTES

    Directory of Open Access Journals (Sweden)

    Budy Rahmat

    2014-01-01

    Full Text Available The Tofu Liquid Waste (TLW as a pollution might be processed into biogas which was environmentally friendly and had potential to replace burning wood or oil. However, the waste could not directly be employed as the biogas substrate due to the high nitrogen content which was not suitable to the methanogen microorganism on the biogas digester and did not produce biogas. It was therefore necessary to adapt the carbon-nitrogen ratio in TLW with the addition of other organic materials that had a lower nitrogen content so it would be a suitable substrate for generating biogas. The research was aimed to evaluate the addition of the other organic material on the TLW to increase the biogas production. The results showed that TLW combined with sheep dung, cabbage waste, bamboo leaves and paddy straw respectively produced biogas as much as 14,183, 7,250, 2,400, 895 cm3 in 20 days. The 4 treatments gave the same quality of biogas, which was determined using the water boiling test. The pH fluctuation during the process was in the right pH for anaerobic digestion, thus it was not the limiting factor.

  14. New purification and upgrading technologies for biogas; Nya renings- och uppgraderingstekniker foer biogas

    Energy Technology Data Exchange (ETDEWEB)

    Johan Benjaminsson [Linkoeping Univ. (Sweden)

    2006-04-15

    Biogas is a renewable energy source that is produced by anaerobic digestion of organic material. In Sweden, biogas predominately comes from sewage water sludge and landfills or from organic waste of households and industries. Small scale digestion plants at farms are especially expected to contribute to increased biogas production in the future. Biogas can be obtained directly in its raw form and used as fuel in a combustion chamber. However, gas engines require biogas purification from hydrogen sulphide and drying from water to avoid corrosion. In order to increase the calorific value, carbon dioxide is separated and the Swedish Standard Type A requires the methane content to be 97 % for vehicle gas. In the gas treatment process from biogas to vehicle gas, the upgrading step when carbon dioxide is separated represents the highest cost since conventional upgrading techniques require high investments. This makes the upgrading costs for smaller biogas plants relatively high. In this master thesis, six upgrading methods have been evaluated and four of them are expected to be commercialized within two years. The following upgrading methods are of interest for Sweden: - In situ methane enrichment; air desorbs carbon dioxide from the sludge in a desorption column. The method is intended for digestion of sewage water sludge and the total upgrading cost is approximately 0,13 kr/kWh by a raw biogas flow 62,5 Nm{sup 3}/h. - Small scale water scrubber; carbon dioxide is absorbed in water under enhanced pressure. The upgrading process is very similar to the conventional water scrubbing technique and the total upgrading cost is approximately 0,42 kr/kWh by a raw biogas flow of 12 Nm{sup 3}/h. - Cryogenic upgrading; the biogas is chilled to under -85 deg C under a pressure of at least 5,2 barg and carbon dioxide can be separated in the liquid phase. The total upgrading cost is approximately 0,12 kr/kWh by a raw biogas flow of 150 Nm{sup 3}/h. The total upgrading cost can be

  15. Progress in biogas II - Biogas production from agricultural biomass and organic residues. Pt. 1. Proceedings; Progress in Biogas II - Biogasproduktion aus landwirtschaftlicher Biomasse und organischen Reststoffen. T. 1. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-08-12

    biogas production - Methabe yield and energy balance (R. Bolduan); (19) Evaluation of a pre-treatment process for improved methane production from grass silage (A. Orozco); (20) Anaerobic fungi and biogas production (J. Prochazka); (21) Preservation of sugar beets for biogas production (A. Wagner); (22) Fibre, biogas and compost from banana agro-residues (leaves, pseudostem and rachis) by anaerobic digestion in plug flow type digester (H. Chanakya); (23) Extraction of biogas from waste products of he sugarcane industry (J. Rietzler); (24) Practical experiences with the digestion of straw in 2-stage AD plants - Extension of the value chain (W. Danner); (25) Improving biogas production on wastewater treatment plants by co-digestion of grass (D. Klein); (26) Generation of algal biomass for biogas production: energetic and environmental from a Life Cycle Assessment (LCA) perspective (F. Romagnoli); (27) Risk reduction in spreading plant pathogens by anaerobic digestion? First results from laboratory experiments (M. Heiermann); (28) Demand-oriented biogas production for the generation of peak load (R. Wallmann); (29) Investigation of mesophilic and thermophilic bioleaching method in a two-phase anaerobic digestion process (M. Schoenberg): (30) Efficient hydrogen fermentation for 2-stage anaerobic digestion processes: Conversion of sucrose containing substrates (S. Noebauer); (31) Process development of two-phase pressure formation - Influence of gas solubilities (A.-M. Wonneberger); (32) Benefits and limitations when treating liquid pig manure in an anaerobic membrane bioreactor (P. Messerl); (33) Experiences with continuous high-rate thermophilic dry anaerobic digestion of energy crops (L. De Baere); (34) The Sauter-biogas-system: spraying instead of stirring (S. Sauter); (35) Biogas production from raw palm oil mill effluent using a pilot-scale anaerobic hybrid reactor (C. Wangnai); (36) Eta max - the biogas power plant with high biological efficiency (M. Niederbacher); (37

  16. Production of liquid biogas at the biowaste treatment plant Amtzell; Gewinnung von fluessigem Biogas an der Bioabfallbehandlungsanlage Amtzell

    Energy Technology Data Exchange (ETDEWEB)

    Bojahr, Armin [Gesellschaft fuer Umwelttechnik Bojahr mbH und Co. KG, Berg (Germany)

    2013-10-01

    The fermentation plant in Amtzell will be extended to increase the throughput of bio waste. In this context an extension of the gas utilization plant is also required. The produced biogas will be partly transferred to the existing combined heat and power plant. The remaining part of biogas will be used in an proposed GPP-Plus {sup registered} --plant to produce liquid bio methane (LBG). In the LBG gaining process the raw biogas will have to be dried in several steps, de-sulphured, compressed and cooled. Following this process and due to different physical characteristics of the ingredients, the contaminants will be removed from the biogas and the main ingredients, carbon dioxide and methane, separated from each other. Carbon dioxide as well as the methane are then available in liquid form and can be put onto the market. This method of using biogas can utilize almost 100% of its energy potential. (orig.)

  17. Biogas in Burkina Faso. Influential factors of biogas projects in rural areas of Burkina Faso

    Energy Technology Data Exchange (ETDEWEB)

    Aschaber, Andreas

    2010-07-01

    rural areas of Burkina Faso. The material was processed according to the content analyses of Mayring. The study identified altogether 38 factors which were grouped into different categories - socio-cultural, technology, economic, institutional, infrastructure, operational, substrate and competitive energies. The results are thought to provide a sound base for better management of future biogas projects in the rural area of Burkina Faso. (Author)

  18. How to best use biogas; Wohin mit dem Biogas?

    Energy Technology Data Exchange (ETDEWEB)

    Wiedemann, Karsten

    2010-02-15

    Biogas has many uses, e.g. in power generation, space heating or as motor fuel, but not all of them are efficient. The biogas industry debates the most useful future strategies. The contribution goes into detail about the German legislation on biogas supply to the public gas grids and about the deregulation of the heat market. (orig.)

  19. Ultrasound-Enhanced Biogas Production from Different Substrates

    DEFF Research Database (Denmark)

    González-Fernández, Cristina; Timmers, Rudolphus Antonius; Ruiz, Begona

    2015-01-01

    Among the biofuel production processes using different substrates, the biogas generation process is one of the simplest. Compared with bioethanol or biodiesel production processes, anaerobic digestion is a process where all the organic matter (carbohydrates, lipids and proteins) can be biologically...... production. The present chapter is dedicated to providing a review of ultrasound pretreatment applied to different substrates (lignocelullosic materials, manures, sludge and microalgae). The advantages and constraints, that ultrasound pretreatment exhibit towards biogas production, are discussed and compared...

  20. Performance evaluation of biogas burners

    Energy Technology Data Exchange (ETDEWEB)

    Chandra, A.; Tiwari, G.N.; Srivastava, V.K.; Yadav, Y.P. (Indian Inst. of Tech., New Delhi (India). Centre of Energy Studies)

    1991-01-01

    The results of testing some biogas burners of various brands are presented. A wide variation is found in their performance under similar conditions of testing. Parametric investigations have also been carried out on a typical biogas burner. These investigations reveal that the burner efficiency is a strong function of biogas flow pressure, pan-size and its position over the burner head. (author).

  1. Agro-ecological aspects when applying the remaining products from agricultural biogas processes as fertilizer in crop production

    Energy Technology Data Exchange (ETDEWEB)

    Bermejo Dominguez, Gabriela

    2012-06-11

    With the increase of biogas production in recent years, the amount of digestates or the remaining residues increased accordingly. Every year in Germany more than 50 million tons of digestates are produced, which are used as fertilizer. Thus nutrients return into the circulation of agricultural ecosystems. However, the agro-ecological effects have not been deeply researched until now. For this reason, the following parameters were quantified: the influence of dry and liquid fermentation products on the yield of three selected crops in comparison to or in combination with mineral-N-fertilizers in on-farm experiments; the growth, development and yield of two selected crops in comparison to mineral-N-fertilizer, liquid manure and farmyard manure in a randomized complete block design; selected soil organisms as compared to mineral-N-fertilizer, liquid manure and farmyard manure in a randomized complete block design. In addition, the mineralization of dry and wet digestates in comparison with liquid manure and farmyard manure was investigated in order to evaluate the effects of different fertilizers on the humus formation under controlled conditions. The 2-year results of on-farm experiments showed that for a sandy soil, the combination of digestates in autumn and mineral-N-fertilizer in spring for winter crops (wheat, rye and rape) brought the highest yields. The wet digestate achieved the highest dry-matter yield as the only fertilizer for maize in spring. In a clayey soil, the use of 150 kg ha{sup -1} N mineral-N-fertilizer brought the highest grain yield. These results were similar to the ones obtained by the application of dry digestates, if they were applied in two doses. Maize showed no signif-icant differences between the dry-matter yields of the different treatments. The results in the field experiments from 2009 to 2011 showed that the effect of digestates on the yield of winter wheat and Sorghum sudanense was up to 15 % lower than the effect of the mineral

  2. 沼气膜分离工艺参数模拟研究%Simulation Study on Process Parameters of Biogas Membrane Separation

    Institute of Scientific and Technical Information of China (English)

    梁正贤; 黄福川; 马良涛; 符侃; 经建芳

    2016-01-01

    生物天然气是近年来新兴的一种可再生清洁能源,核心技术就是去除沼气中的 CO2.利用聚酰亚胺中空纤维膜,以 CO2/CH4混合体系作为研究对象,通过采用 PRO/II 模拟软件进行模拟,考察了原料气压力、渗透侧压力、膜面积和原料气组成对膜分离过程的影响.结果表明:原料气压力的增加和渗透侧压力的降低,均有利于产品气 CH4纯度的提高,然而会造成 CH4回收率降低和能耗的增加;膜面积的增加,有利于 CH4纯度的提高,但是会造成 CH4回收率降低和设备成本增加;在设计条件下,随着进气 CH4摩尔分数增大,产品气 CH4纯度略有下降,但均能得 CH4纯度大于 97%的车用天然气,满足各种不同比例沼气的分离.%Biogas is a new kind of renewable clean energy in recent years; the core technology is to remove the CO2 in the biogas. In this paper, polyimide hollow fiber membrane was used as membrane module. PRO/II simulation software was used to simulate the CO2/CH4 hybrid system.And the influence of the raw material gas pressure, the osmotic pressure, the membrane area and the composition of raw material on the membrane separation process was investigated. The results show that the increase of feed gas pressure and the decrease of the osmotic pressure are beneficial to the improvement of the purity of product gas CH4. However, the recovery rate of CH4 decreases and the energy consumption increases; The increase of membrane area is beneficial to the improvement of CH4 purity, but it can result in the decrease of CH4 recovery and the increase of the cost of equipment; Under the design conditions, the purity of product gas CH4 decreases slightly with the increase of CH4 mole fraction, but the purity of CH4 is greater than 97%, which can meet the separation of different proportions of biogas.

  3. Biogas in the agriculture. State of the art. Proceedings; Biogas in der Landwirtschaft. Stand und Perspektiven. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    Within the meeting of the Association for Technology and Structures in Agriculture (Darmstadt, Federal Republic of Germany) and the Agency for Renewable Resources (Guelzow, Federal Republic of Germany) between 15th and 16th September, 2009, in Weimar the following lectures were held: (1) Results of the actual biogas measurement II (Peter Weiland); (2) Agitators in biogas plants - Technology with central significance (Kay Rostalski); (3) How much energy is needed by a biogas fermenter? (Ludwig Heinloth); (4) The fermentation concept of Rueckert NatUrgas GmbH (Claus Rueckert, Dominique Pfeufer); (5) Experiences from the construction for the practice of the company MT-Energie GmbH (Bodo Drescher); (6) Fermenter/technology concept of Schmack Biogas AG (Thomas Moeeslinger); (7) Transport of biomass - How much does the logistics of Guelle and Co. cost? (Thore Toews); (8) Which factors determine the efficiency of biogas plants? (Gerd Reinhold); (9) Microbial diversity in biogas reactors in the fermentation of renewable raw materials (Michael Klocke et al.); (10) What do additives and ingredients contribute to the optimisation of the production of biogas? (Udo Hoelker); (11) Process optimisation - An interaction between technology and microbiology (Andreas Gronauer et al.); (12) Emissions at the production of biogas - an analysis if the environmental relevance (Joachim Clemens et al.); (13) Support systems for energy plants - Consequences to soil and environment (Matthias Willms et al.); (14) How ecological is biogas? (Sven Gaertner); (15) Biogas plant - Analysis of construction and operation from licensing view (Hans-Walter Schneichel); (16) Biogas plants - Analysis of construction and operation from contractual legal view (Florian Valentin); (17) Biogasplants - Analysis of construction and operation from remuneration legal view (Helmut Loibl); (18) Process and costs of treatment of residues of fermentation (Sebastian Wulf, Helmut Doehler); (19) How do residues of

  4. The contribution of Slovenian biogas plants to the reduction of agricultural sector green house emissions

    Directory of Open Access Journals (Sweden)

    Romana MARINŠEK LOGAR

    2015-12-01

    Full Text Available Agriculture is a source of emissions of the greenhouse gas methane into the environment. These emissions can be reduced by appropriate storage of animal slurry and manure, with proper fertilization and processing of organic agricultural waste into biogas, where methane is captured and used as an energy source. Biogas is a renewable source of energy that is produced by microbial anaerobic digestion in biogas plants. As a substrate in biogas plants using different types of organic biomass such as animal manure and slurry, crop residues, spoilt silage, waste from food processing industry and biodegradable industrial and municipal waste. Biogas can be used to produce heat and electricity or purified to biomethane as a fuel for vehicles. Digestate can be used as a high-quality fertilizer. Biogas as a renewable energy source represents a replacement for fossil fuels, thus reducing greenhouse gas emissions from fossil sources. The system of financial supports for electricity produced from biogas is applied in Slovenia. There were 24 operating biogas plants in Slovenia in year 2014. Slovenian biogas plants currently produce the majority of biogas from energy crops. As only the minority of biogas is produced from animal excrements we will primarily support the development of agricultural microbiogas plants that will use animal excrements and organic waste biomass from agri-food sector as substrates.

  5. Basic data biogas Germany. Solid fuels, biofuels, biogas; Basisdaten Bioenergie Deutschland. Festbrennstoffe, Biokraftstoffe, Biogas

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-09-15

    The brochure ''Basic data biogas Germany'' gives statistical information about (a) renewable energies: primary energy consumption, power generation, energy supply, avoidance of greenhouse gases; (b) Solid fuels: energetic utilization, wood pellets, energy consumption, comparison to heating oil; (c) Biofuels: consumption, bioethanol, biodiesel, vegetable oils; (d) Biogas: biogas power plants, energy content, production, legal aspects.

  6. Basic data biogas Germany. Solid fuels, biofuels, biogas; Basisdaten Bioenergie Deutschland. Festbrennstoffe - Biokraftstoffe - Biogas

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-08-15

    The brochure ''Basic data biogas Germany'' gives statistical information about (a) renewable energies: primary energy consumption, power generation, energy supply, avoidance of greenhouse gases; (b) Solid fuels: energetic utilization, wood pellets, energy consumption, comparison to heating oil; (c) Biofuels: consumption, bioethanol, biodiesel, vegetable oils; (d) Biogas: biogas power plants, energy content, production, legal aspects.

  7. Progress in biogas II - Biogas production from agricultural biomass and organic residues. Pt. 1. Proceedings; Progress in Biogas II - Biogasproduktion aus landwirtschaftlicher Biomasse und organischen Reststoffen. T. 1. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-08-12

    biogas production - Methabe yield and energy balance (R. Bolduan); (19) Evaluation of a pre-treatment process for improved methane production from grass silage (A. Orozco); (20) Anaerobic fungi and biogas production (J. Prochazka); (21) Preservation of sugar beets for biogas production (A. Wagner); (22) Fibre, biogas and compost from banana agro-residues (leaves, pseudostem and rachis) by anaerobic digestion in plug flow type digester (H. Chanakya); (23) Extraction of biogas from waste products of he sugarcane industry (J. Rietzler); (24) Practical experiences with the digestion of straw in 2-stage AD plants - Extension of the value chain (W. Danner); (25) Improving biogas production on wastewater treatment plants by co-digestion of grass (D. Klein); (26) Generation of algal biomass for biogas production: energetic and environmental from a Life Cycle Assessment (LCA) perspective (F. Romagnoli); (27) Risk reduction in spreading plant pathogens by anaerobic digestion? First results from laboratory experiments (M. Heiermann); (28) Demand-oriented biogas production for the generation of peak load (R. Wallmann); (29) Investigation of mesophilic and thermophilic bioleaching method in a two-phase anaerobic digestion process (M. Schoenberg): (30) Efficient hydrogen fermentation for 2-stage anaerobic digestion processes: Conversion of sucrose containing substrates (S. Noebauer); (31) Process development of two-phase pressure formation - Influence of gas solubilities (A.-M. Wonneberger); (32) Benefits and limitations when treating liquid pig manure in an anaerobic membrane bioreactor (P. Messerl); (33) Experiences with continuous high-rate thermophilic dry anaerobic digestion of energy crops (L. De Baere); (34) The Sauter-biogas-system: spraying instead of stirring (S. Sauter); (35) Biogas production from raw palm oil mill effluent using a pilot-scale anaerobic hybrid reactor (C. Wangnai); (36) Eta max - the biogas power plant with high biological efficiency (M. Niederbacher); (37

  8. Biogas Digester with Simple Solar Heater

    Directory of Open Access Journals (Sweden)

    Kh S Karimov

    2012-10-01

    Full Text Available ABSTRACT: In this research work, the design, fabrication and investigation of a biogas digester with simple solar heater are presented. For the solar heater, a built-in reverse absorber type heater was used. The maximum temperature (50°C inside the methane tank was taken as a main parameter for the design of the digester. Then, the energy balance equation for the case of a static mass of fluid being heated was used to model the process. The parameters of thermal insulation of the methane tank were also included in the calculations. The biogas digester consisted of a methane tank with built-in solar reverse absorber heater to harness the radiant solar energy for heating the slurry comprising of different organic wastes (dung, sewage, food wastes etc.. The methane tank was initially filled to 70% of its volume with organic wastes from the GIK institute’s sewage. The remaining volume was filled with sewage and cow dung from other sources. During a three month period (October-December, 2009 and another two month period (February-March, 2010, the digester was investigated. The effects of solar radiation on the absorber, the slurry’s temperature, and the ambient temperature were all measured during these investigations. It was found that using sewage only and sewage with cow dung in the slurry resulted in retention times of four and two weeks, respectively. The corresponding biogas produced was 0.4 m3 and 8.0 m3, respectively. Finally, this paper also elaborates on the upgradation of biogas through the removal of carbon dioxide, hydrogen sulphide and water vapour, and also the process of conversion of biogas energy into electric powerABSTRAK: Kajian ini membentangkan rekabentuk, fabrikasi dan penyelidikan tentang pencerna biogas dengan pemanas solar ringkas. Sebagai pemanas solar, ia dilengkapkan dengan penyerap pemanas beralik. Suhu maksimum(50oC di dalam tangki metana telah diambil sebagai parameter utama rekabentuk pencerna. Dengan menggunakan

  9. Transfer of Biogas Technology to Support Mixed Crop and Livestock Farming Systems in Indonesia

    DEFF Research Database (Denmark)

    Putra, Ahmad Romadhoni Surya

    for biogas technology dissemination in developing countries. This research aims to develop a relevant model of biogas technology transfer to support MCL farming in Indonesia based on the slow diffusion rate of biogas technology at farm level. Two farm household surveys were carried out to study the following...... such as reduction of air and water pollution and gas emission caused by manure. However, despite its multiple benefits, the biogas technology transfer is facing a slow rate of diffusion in most farm households in developing countries. This phenomenon calls for identification of reasons in order to develop solutions......: 1) To assess the role of biogas technology adoption and its impact at farm level, 2) To examine the factors that influence biogas adoption among farmers, 3) To determine a relevant model of biogas technology transfer in regard to the slow rate of technology diffusion, 4) To describe the process...

  10. The conversion of renewable biogas source into energy; A conversao da fonte renovavel biogas em energia

    Energy Technology Data Exchange (ETDEWEB)

    Coelho, Suani Teixeira; Velazquez, Silvia Maria Stortini Gonzalez; Martins, Osvaldo Stella; Abreu, Fernando Castro de [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Eletrotecnica e Energia]|[Centro Nacional de Referencia em Biomassa (CENBIO), Sao Paulo, SP (Brazil)]. E-mails: suani@iee.usp.br; sgvelaz@iee.sup.br; omartins@iee.usp.br; fcabreu@iee.usp.br

    2006-07-01

    This article intend to present some considerations directed to electricity generation with small systems (micro turbine and conventional engines ), using biogas generated by sewage treatment process in SABESP (Basic Sanitation Company of Sao Paulo State), located at Barueri, Brazil. This project, pioneer in Latin America, is being accomplished together with BUN - Biomass Users Network of Brazil (proponent), in association with CENBIO - Biomass Reference National Center (executer), with patronage of FINEP / CT-ENERG (financial backer), by means of Convention No: 23.01.0653.00, regarding to ENERG-BIOG Project - Installation and Tests of an Electric Energy Generation Demonstration Unit from Biogas Sewage Treatment. The study is being done at Barueri Sewage Treatment Plant.This plant operate with anaerobic digestion process, which has as mainly products biogas (composed mainly by methane) and sludge. Part of the methane produced at the anaerobic process is burnt in a boiler being used to increase digesters temperature. The rest of the methane is burnt in flare to reduce the impacts caused by gases emissions. This article presents some technical, financial and environmental project results, related to the exploitation of sewer biogas for power generation, as well as bigger details about generation systems (biogas micro turbine), used in the facility. (author)

  11. Sewage biogas conversion into electricity; Conversao do biogas de tratamento de esgoto em eletricidade

    Energy Technology Data Exchange (ETDEWEB)

    Coelho, Suani Teixeira; Velazquez, Silvia Maria Stortini Gonzalez; Martins, Osvaldo Stella; Abreu, Fernando Castro de [Universidade de Sao Paulo (CENBIO/IEE/USP), Sao Paulo, SP (Brazil). Inst. de Eletrotecnica e Energia. Centro Nacional de Referencia em Biomassa], e-mails: suani@iee.usp.br, sgvelaz@iee.usp.br, omartins@iee.usp.br, fcabreu@iee.usp.br

    2006-07-01

    This article intend to present some considerations directed to electricity generation with small systems (micro turbine and conventional engines ), using biogas generated by sewage treatment process in SABESP (Basic Sanitation Company of Sao Paulo State), located at Barueri, Brazil. This project, pioneer in Latin America, is being accomplished together with BUN - Biomass Users Network of Brazil (proponent), in association with CENBIO - Biomass Reference National Center (executer), with patronage of FINEP / CT-ENERG (financial backer), by means of Convention no: 23.01.0653.00, regarding to ENERG BIOG Project - 'Installation and Tests of an Electric Energy Generation Demonstration Unit from Biogas Sewage Treatment'. The study is being done at Barueri Sewage Treatment Plant. This plant operate with anaerobic digestion process, which has as mainly products biogas (composed mainly by methane) and sludge. Part of the methane produced at the anaerobic process is burnt in a boiler being used to increase digesters temperature. The rest of the methane is burnt in flare to reduce the impacts caused by gases emissions. This article presents some technical, financial and environmental project results, related to the exploitation of sewer biogas for power generation, as well as bigger details about generation systems (biogas micro turbine), used in the facility. (author)

  12. Ultrasound assisted biogas production from landfill leachate

    Energy Technology Data Exchange (ETDEWEB)

    Oz, Nilgün Ayman, E-mail: nilgunayman@comu.edu.tr; Yarimtepe, Canan Can

    2014-07-15

    Highlights: • Effect of low frequency ultrasound pretreatment on leachate was investigated. • Three different ultrasound energy inputs (200, 400 and 600 W/l) was applied. • Low-frequency ultrasound treatment increased soluble COD in landfill leachate. • Application of ultrasound to leachate increased biogas production about 40%. • Application of ultrasound to leachate increased total methane production rate about 20%. - Abstract: The aim of this study is to increase biogas production and methane yield from landfill leachate in anaerobic batch reactors by using low frequency ultrasound as a pretreatment step. In the first part of the study, optimum conditions for solubilization of organic matter in leachate samples were investigated using various sonication durations at an ultrasound frequency of 20 kHz. The level of organic matter solubilization during ultrasonic pretreatment experiments was determined by calculating the ratio of soluble chemical oxygen demand (sCOD) to total chemical oxygen demand (tCOD). The sCOD/tCOD ratio was increased from 47% in raw leachate to 63% after 45 min sonication at 600 W/l. Non-parametric Friedman’s test indicated that ultrasonic pretreatment has a significant effect on sCOD parameter for leachate (p < 0.05). In the second part of the study, anaerobic batch reactors were operated for both ultrasonically pretreated and untreated landfill leachate samples in order to assess the effect of sonication on biogas and methane production rate. In anaerobic batch reactor feed with ultrasonically pretreated leachate, 40% more biogas was obtained compared to the control reactor. For statistical analysis, Mann–Whitney U test was performed to compare biogas and methane production rates for raw and pretreated leachate samples and it has been found that ultrasonic pretreatment significantly enhanced biogas and methane production rates from leachate (p < 0.05) in anaerobic batch reactors. The overall results showed that low frequency

  13. Experiences with biogas in Denmark

    DEFF Research Database (Denmark)

    Bundgaard, Sirid Sif; Kofoed-Wiuff, Anders

    This report is primarily based on the work of the Danish biogas task force, which was established as a result of the Energy Agreement of 22 March 2012. The purpose of the task force is to examine and support concrete biogas projects in order to facilitate the projected biogas development up to 2020....... The focus of the task force was on the practical integration of the new biogas production in energy system, including the utilization of gas, the necessary infrastructure and contractual relationships. The aim was to ensure effective and appropriate integration of biogas in the Danish energy supply, which...... was consistent with the policy objectives, both in regards to current challenges for specific biogas plants and the role of biogas flexible renewable energy form on longer term. The task force's final report was published in 2014....

  14. Propionic acidemia associated with visual hallucinations.

    Science.gov (United States)

    Shuaib, Taghreed; Al-Hashmi, Nadia; Ghaziuddin, Mohammad; Megdad, Eman; Abebe, Dejene; Al-Saif, Amr; Doubi, Alaa; Aldhalaan, Hesham; Abouzied, Mohei Eldin; Al-Owain, Mohammed

    2012-06-01

    Propionic acidemia, an autosomal recessive disorder, is a common form of organic aciduria resulting from the deficiency of propionyl-CoA carboxylase. It is characterized by frequent and potentially lethal episodes of metabolic acidosis often accompanied by hyperammonemia. A wide range of brain abnormalities have been reported in propionic acidemia. We report recurrent visual hallucinations in 2 children with propionic acidemia. Four visual hallucination events were observed in the 2 patients. Three episodes were preceded by an intercurrent illness, and 2 were associated with mild metabolic decompensation. The 2 events in one patient were associated with a seizure disorder with abnormal electroencephalogram. Brain magnetic resonance imaging showed abnormal basal ganglia and faint temporo-occipital swelling bilaterally. This is probably the first report of visual hallucinations in propionic acidemia and should alert the treating clinicians to look for visual hallucinations in patients with organic acidurias, especially in an unusually anxious child.

  15. Association Mechanism Between Propionic Acid and Trioctylamine

    Institute of Scientific and Technical Information of China (English)

    李振宇; 秦炜; 戴猷元

    2002-01-01

    Tertiary amines dissolved in diluents are attractive extractants for recovery of carboxylic acids from dilute aqueous solutions. Quantitative Fourier transform infrared (FTIR) analysis of organic solutions containing various concentrations of trioctylamine (TOA), n-octanol, and propionic acid was carried out, and liquid-liquid equilibrium was investigated using TOA in n-octanol as the solvent. The fraction of ion-pair association between TOA and propionic acid in the organic phase was quantitatively determined by FTIR. The apparent reactive extraction equilibrium constant, K11, was calculated using the quantitative FTIR spectrum and the equilibrium data. The results show that the fraction of ion-pair association depends on diluent concentration, complex dissolution for propionic acid, and association between TOA and propionic acid. The K11 based on quantitative FTIR has the same loading trend as that from the equilibrium data.

  16. Improved biogas production from rice straw by co-digestion with kitchen waste and pig manure.

    Science.gov (United States)

    Ye, Jingqing; Li, Dong; Sun, Yongming; Wang, Guohui; Yuan, Zhenhong; Zhen, Feng; Wang, Yao

    2013-12-01

    In order to investigate the effect of feedstock ratios in biogas production, anaerobic co-digestions of rice straw with kitchen waste and pig manure were carried out. A series of single-stage batch mesophilic (37±1 °C) anaerobic digestions were performed at a substrate concentration of 54 g/L based on volatile solids (VS). The results showed that the optimal ratio of kitchen waste, pig manure, and rice straw was 0.4:1.6:1, for which the C/N ratio was 21.7. The methane content was 45.9-70.0% and rate of VS reduction was 55.8%. The biogas yield of 674.4 L/kg VS was higher than that of the digestion of rice straw or pig manure alone by 71.67% and 10.41%, respectively. Inhibition of biogas production by volatile fatty acids (VFA) occurred when the addition of kitchen waste was greater than 26%. The VFA analysis showed that, in the reactors that successfully produced biogas, the dominant intermediate metabolites were propionate and acetate, while they were lactic acid, acetate, and propionate in the others.

  17. Simultaneous hydrogen utilization and in situ biogas upgrading in an anaerobic reactor

    DEFF Research Database (Denmark)

    Luo, Gang; Johansson, Sara; Boe, Kanokwan;

    2011-01-01

    . The methane production rate of the reactor with H2 addition was 22% higher, compared to the control reactor only fed with manure. The CO2 content in the produced biogas was only 15%, while it was 38% in the control reactor. However, the addition of hydrogen resulted in increase of pH (from 8.0 to 8.3) due......The possibility of converting hydrogen to methane and simultaneous upgrading of biogas was investigated in both batch tests and fully mixed biogas reactor, simultaneously fed with manure and hydrogen. Batch experiments showed that hydrogen could be converted to methane by hydrogenotrophic...... mixing intensity (shaking speed 300 rpm). Continuous addition of hydrogen (flow rate of 28.6 mL/(L/h)) to an anaerobic reactor fed with manure, showed that more than 80% of the hydrogen was utilized. The propionate and butyrate level in the reactor was not significantly affected by the hydrogen addition...

  18. A review on optimization production and upgrading biogas through CO2 removal using various techniques.

    Science.gov (United States)

    Andriani, Dian; Wresta, Arini; Atmaja, Tinton Dwi; Saepudin, Aep

    2014-02-01

    Biogas from anaerobic digestion of organic materials is a renewable energy resource that consists mainly of CH4 and CO2. Trace components that are often present in biogas are water vapor, hydrogen sulfide, siloxanes, hydrocarbons, ammonia, oxygen, carbon monoxide, and nitrogen. Considering the biogas is a clean and renewable form of energy that could well substitute the conventional source of energy (fossil fuels), the optimization of this type of energy becomes substantial. Various optimization techniques in biogas production process had been developed, including pretreatment, biotechnological approaches, co-digestion as well as the use of serial digester. For some application, the certain purity degree of biogas is needed. The presence of CO2 and other trace components in biogas could affect engine performance adversely. Reducing CO2 content will significantly upgrade the quality of biogas and enhancing the calorific value. Upgrading is generally performed in order to meet the standards for use as vehicle fuel or for injection in the natural gas grid. Different methods for biogas upgrading are used. They differ in functioning, the necessary quality conditions of the incoming gas, and the efficiency. Biogas can be purified from CO2 using pressure swing adsorption, membrane separation, physical or chemical CO2 absorption. This paper reviews the various techniques, which could be used to optimize the biogas production as well as to upgrade the biogas quality.

  19. Mechanisms of cementitious material deterioration in biogas digester.

    Science.gov (United States)

    Voegel, C; Bertron, A; Erable, B

    2016-11-15

    Digesters produce biogas from organic wastes through anaerobic digestion processes. These digesters, often made of concrete, suffer severe premature deterioration caused mainly by the presence of fermentative microorganisms producing metabolites that are aggressive towards cementitious materials. To clarify the degradation mechanisms in an anaerobic digestion medium, ordinary Portland cement paste specimens were immersed in the liquid fraction of a running, lab-scale digester for 4weeks. The anaerobic digestion medium was a mixture of a biowaste substrate and sludge from municipal wastewater treatment plant used as a source of anaerobic bacteria. The chemical characteristics of the anaerobic digestion liquid phase were monitored over time using a pH metre, high performance liquid chromatography (HPLC) and ion chromatography (HPIC). An initial critical period of low pH in the bioreactors was observed before the pH stabilized around 8. Acetic, propionic and butyric acids were produced during the digestion with a maximum total organic acid concentration of 50mmolL(-1). The maximum ammonium content of the liquid phase was 40mmolL(-1), which was about seven times the upper limit of the highly aggressive chemical environment class (XA3) as defined by the European standard for the specification of concrete design in chemically aggressive environments (EN 206). The changes in the mineralogical, microstructural and chemical characteristics of the cement pastes exposed to the solid and liquid phase of the digesters were analysed at the end of the immersion period by X-ray diffraction (XRD), scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectrometry (EDS) and electron-probe micro-analysis (EPMA). A 700-μm thick altered layer was identified in the cement paste specimens. The main biodeterioration patterns in the bioreactors' solid/liquid phase were calcium leaching and carbonation of the cement matrix.

  20. Recent updates on biogas production - a review

    Directory of Open Access Journals (Sweden)

    Ilona Sárvári Horváth

    2016-06-01

    Full Text Available One of the greatest challenges facing the societies now and in the future is the reduction of green house gas emissions and thus preventing the climate change. It is therefore important to replace fossil fuels with renewable sources, such as biogas. Biogas can be produced from various organic waste streams or as a byproduct from industrial processes. Beside energy production, the degradation of organic waste through anaerobic digestion offers other advantages, such as the prevention of odor release and the decrease of pathogens. Moreover, the nutrient rich digested residues can be utilized as fertilizer for recycling the nutrients back to the fields. However, the amount of organic materials currently available for biogas production is limited and new substrates as well as new effective technologies are therefore needed to facilitate the growth of the biogas industry all over the world. Hence, major developments have been made during the last decades regarding the utilization of lignocellulosic biomass, the development of high rate systems, and the application of membrane technologies within the anaerobic digestion process in order to overcome the shortcomings encountered. The degradation of organic material requires a synchronized action of different groups of microorganisms with different metabolic capacities. Recent developments in molecular biology techniques have provided the research community with a valuable tool for improved understanding of this complex microbiological system, which in turn could help optimize and control the process in an effective way in the future.

  1. Microalgal Cultivation in Treating Liquid Digestate from Biogas Systems.

    Science.gov (United States)

    Xia, Ao; Murphy, Jerry D

    2016-04-01

    Biogas production via anaerobic digestion (AD) has rapidly developed in recent years. In addition to biogas, digestate is an important byproduct. Liquid digestate is the major fraction of digestate and may contain high levels of ammonia nitrogen. Traditional processing technologies (such as land application) require significant energy inputs and raise environmental risks (such as eutrophication). Alternatively, microalgae can efficiently remove the nutrients from digestate while producing high-value biomass that can be used for the production of biochemicals and biofuels. Both inorganic and organic carbon sources derived from biogas production can significantly improve microalgal production. Land requirement for microalgal cultivation is estimated as 3% of traditional direct land application of digestate.

  2. Biogas Production on Demand Regulated by Butyric Acid Addition

    Science.gov (United States)

    Kasper, K.; Schiffels, J.; Krafft, S.; Kuperjans, I.; Elbers, G.; Selmer, T.

    2016-03-01

    Investigating effects of volatile fatty acids on the biogas process it was observed that butyric acid can be used for transient stimulation of the methane production in biogas plants operating with low energy substrates like cattle manure. Upon addition of butyrate the methane output of the reactors doubled within 24 h and reached almost 3-times higher methane yields within 3-4 days. Butyrate was quantitatively eliminated and the reactors returned to the original productivity state within 3 days when application of butyrate was stopped. The opportunity to use butyrate feeding for increased biogas production on demand is discussed.

  3. Biogas Production From Cassava Starch Effluent Using Microalgae As Biostabilisator

    Directory of Open Access Journals (Sweden)

    B. Budiyono

    2011-07-01

    Full Text Available The rapid growing of Indonesian population is emerging several critical national issues i.e. energy, food, environmental, water, transportation, as well as law and human right. As an agricultural country, Indonesia has abundant of biomass wastes such as agricultural wastes include the cassava starch wastes. The problem is that the effluent from cassava starch factories is released directly into the river before properly treatment. It has been a great source of pollution and has caused environmental problems to the nearby rural population. The possible alternative to solve the problem is by converting waste to energy biogas in the biodigester. The main problem of the biogas production of cassava starch effluent is acid forming-bacteria quickly produced acid resulting significantly in declining pH below the neutral pH and diminishing growth of methane bacteria. Hence, the only one of the method to cover this problem is by adding microalgae as biostabilisator of pH. Microalgae can also be used as purifier agent to absorb CO2.The general objective of this research project was to develop an integrated process of biogas production and purification from cassava starch effluent by using biostabilisator agent microalgae. This study has been focused on the used of urea, ruminant, yeast, microalgae, the treatment of gelled and ungelled feed for biogas production, pH control during biogas production using buffer Na2CO3, and feeding management in the semi-continuous process of biogas production. The result can be concluded as follows: i The biogas production increased after cassava starch effluent and yeast was added, ii Biogas production with microalgae and cassava starch effluent, yeast, ruminant bacteria, and urea were 726.43 ml/g total solid, iii Biogas production without  microalgae was 189 ml/g total solid.

  4. Linking supply to demand: the neuronal monocarboxylate transporter MCT2 and the alpha-amino-3-hydroxyl-5-methyl-4-isoxazole-propionic acid receptor GluR2/3 subunit are associated in a common trafficking process.

    Science.gov (United States)

    Pierre, Karin; Chatton, Jean-Yves; Parent, Annabelle; Repond, Cendrine; Gardoni, Fabrizio; Di Luca, Monica; Pellerin, Luc

    2009-05-01

    MCT2 is the major neuronal monocarboxylate transporter (MCT) that allows the supply of alternative energy substrates such as lactate to neurons. Recent evidence obtained by electron microscopy has demonstrated that MCT2, like alpha-amino-3-hydroxyl-5-methyl-4-isoxazole-propionic acid (AMPA) receptors, is localized in dendritic spines of glutamatergic synapses. Using immunofluorescence, we show in this study that MCT2 colocalizes extensively with GluR2/3 subunits of AMPA receptors in neurons from various mouse brain regions as well as in cultured neurons. It also colocalizes with GluR2/3-interacting proteins, such as C-kinase-interacting protein 1, glutamate receptor-interacting protein 1 and clathrin adaptor protein. Coimmunoprecipitation of MCT2 with GluR2/3 and C-kinase-interacting protein 1 suggests their close interaction within spines. Parallel changes in the localization of both MCT2 and GluR2/3 subunits at and beneath the plasma membrane upon various stimulation paradigms were unraveled using an original immunocytochemical and transfection approach combined with three-dimensional image reconstruction. Cell culture incubation with AMPA or insulin triggered a marked intracellular accumulation of both MCT2 and GluR2/3, whereas both tumor necrosis factor alpha and glycine (with glutamate) increased their cell surface immunolabeling. Similar results were obtained using Western blots performed on membrane or cytoplasm-enriched cell fractions. Finally, an enhanced lactate flux into neurons was demonstrated after MCT2 translocation on the cell surface. These observations provide unequivocal evidence that MCT2 is linked to AMPA receptor GluR2/3 subunits and undergoes a similar translocation process in neurons upon activation. MCT2 emerges as a novel component of the synaptic machinery putatively linking neuroenergetics to synaptic transmission.

  5. Life cycle analysis of biogas from residues; Livscykelanalys av biogas fraan restprodukter

    Energy Technology Data Exchange (ETDEWEB)

    Tufvesson, Linda; Lantz, Mikael [Dep. for Miljoe- och Energisystem, Lunds Tekniska Hoegskola, Lund (Sweden)

    2012-06-15

    The purpose of this study is to carry out life cycle assessments for different biogas systems where biogas is produced from different residues. The investigated residues are distiller's waste, rapeseed cake, whey permeate, concentrated whey permeate, fodder milk, fish residues, bakery residues and glycerol. The environmental impact categories included are climate change, eutrophication, acidification, photochemical ozone creation potential, particles and energy balance. The calculations include emissions from technical systems, especially the energy input in various operations and processes. A general conclusion is that all studied residues are very well suited for production of biogas if there is no demand for them as animal feed today. All biogas systems also reduce the emissions of greenhouse gases compared to petrol and diesel and meet the requirements presented in the EU renewable energy directive (RED). The results of the study also show that the investigated biogas systems are complex and many different parameters affect the result. These parameters are both integrated in the life cycle assessment method, but also in the inventory data used.

  6. Biogas in the natural gas distribution network; Biogas til nettet

    Energy Technology Data Exchange (ETDEWEB)

    Kvist Jensen, T.

    2009-05-15

    With the Danish 'Thorsoe Biogas Plant' as reference case, an assessment of the possibility of using the existing natural gas distribution network for distributing biogas was carried out. Technologies for and cost of upgrading biogas to natural gas quality are presented. Furthermore, a socio-economic analysis has been performed, including the Danish financial conditions, the market models, and the role of the natural gas distribution companies.

  7. Analysis of the Value Chain for Biogas in Tanzania Northern Zone (Tanga, Kilimanjaro, Arusha, Manyara)

    Energy Technology Data Exchange (ETDEWEB)

    Nyagabona, N.T.

    2009-12-15

    This study aimed at exploring weaknesses in the biogas value chain that hinder wider dissemination of the technology in Tanzania. The research included assessment of processes and activities carried out by the players, the influencers and business supporters of the biogas value chain. The methodology used is holistic, combining literature review with focus group discussions and interviews with actors and observations of processes across the value chain in Arusha and Kilimanjaro regions, where biogas has the longest history in Tanzania.

  8. High cell density propionic acid fermentation with an acid tolerant strain of Propionibacterium acidipropionici.

    Science.gov (United States)

    Wang, Zhongqiang; Jin, Ying; Yang, Shang-Tian

    2015-03-01

    Propionic acid is an important chemical with wide applications and its production via fermentation is of great interest. However, economic production of bio-based propionic acid requires high product titer, yield, and productivity in the fermentation. A highly efficient and stable high cell density (HCD) fermentation process with cell recycle by centrifugation was developed for propionic acid production from glucose using an acid-tolerant strain of Propionibacterium acidipropionici, which had a higher specific growth rate, productivity, and acid tolerance compared to the wild type ATCC 4875. The sequential batch HCD fermentation at pH 6.5 produced propionic acid at a high titer of ∼40 g/L and productivity of 2.98 g/L h, with a yield of ∼0.44 g/g. The product yield increased to 0.53-0.62 g/g at a lower pH of 5.0-5.5, which, however, decreased the productivity to 1.28 g/L h. A higher final propionic acid titer of >55 g/L with a productivity of 2.23 g/L h was obtained in fed-batch HCD fermentation at pH 6.5. A 3-stage simulated fed-batch process in serum bottles produced 49.2 g/L propionic acid with a yield of 0.53 g/g and productivity of 0.66 g/L h. These productivities, yields and propionic acid titers were among the highest ever obtained in free-cell propionic acid fermentation.

  9. Use of biogas in PEM fuel cells; Einsatz von Biogas in PEM-Brennstoffzellen

    Energy Technology Data Exchange (ETDEWEB)

    Scholz, Volkhard; Schmersahl, Ralf; Ellner, Janine (comps.)

    2009-06-15

    This research project was dedicated to two problems: 1. What demands must biogas meet in order to conform to the specifications of PEM fuel cell systems and permit safe operation? 2. How must a fuel cell system be designed and operated in order to be well-adapted to the special features of biogas as opposed to natural gas? For this purpose biogas samples were taken from laboratory-scale and commercial plants and analysed by gas chromatography using various substrates and methods. By combining this with the use of a mass spectroscopy detector (GC-MS system) it was possible to perform a qualitative and quantitative analysis of sulphurious trace gases in the biogas which might cause damage to the fuel cell system. Investigations were performed on an experimental reformer using either modelled or native biogas of different compositions, the intent being to obtain information for the design of the individual process stages. The two operating parameters steam-methane ratio (or S/C ratio) and reforming temperature were varied to optimise parameter settings in terms of energy efficiency. By linking the reformer to a 500 W fuel cell it was possible confirm the suitability of the reformed biogas for use in fuel cells. [German] In diesm Forschungsvorhaben werden zwei Fragestellungen bearbeitet: 1. Welche Anforderungen ergeben sich an das Biogas, um den Spezifikationen von PEM-Brennstoffzellensystemen zu genuegen und eine sicheren Betrieb zu ermoeglichen? 2. Wie muss das Brennstoffzellensystem ausgelegt und gefuehrt werden, um den Besonderheiten von Biogas im Vergleich zu Erdgas Rechnung zu tragen? Dazu wurden Biogasproben aus Labor- und Praxisanlagen unter Beruecksichtigung unterschiedlicher Substrate und Verfahren gaschromatisch analysiert. Die Kopplung mit einem massenspektroskopischen Detektor (GC-MS System) ermoeglicht dabei die Qualifizierung und Quantifizierung der vorhandenen schwefelhaltigen Spurengase, die eine Schaedigung von Brennstoffzellenanlagen verursachen. Die

  10. Microbial Community Dynamics During Biogas Slurry and Cow Manure Compost

    Institute of Scientific and Technical Information of China (English)

    ZHAO Hong-yan; LI Jie; LIU Jing-jing; L Yu-cai; WANG Xiao-fen; CUI Zong-jun

    2013-01-01

    This study evaluated the microbial community dynamics and maturation time of two compost systems: biogas slurry compost and cow manure compost, with the aim of evaluating the potential utility of a biogas slurry compost system. Denaturing gradient gel electrophoresis (DGGE), gene clone library, temperature, C/N ratio, and the germination index were employed for the investigation, cow manure compost was used as the control. Results showed that the basic strip and dominant strips of the DGGE bands for biogas slurry compost were similar to those of cow manure compost, but the brightness of the respective strips for each system were different. Shannon-Weaver indices of the two compost systems differed, possessing only 22%similarity in the primary and maturity stages of the compost process. Using bacterial 16S rRNA gene clone library analysis, 88 bacterial clones were detected. Further, 18 and 13 operational taxonomic units (OTUs) were present in biogas slurry and cow manure compost, respectively. The 18 OTUs of the biogas slurry compost belonged to nine bacterial genera, of which the dominant strains were Bacillus sp. and Carnobacterium sp.;the 13 OTUs of the cow manure compost belonged to eight bacterial genera, of which the dominant strains were Psychrobacter sp., Pseudomonas sp., and Clostridium sp. Results demonstrated that the duration of the thermophilic phase (more than 50°C) for biogas slurry compost was 8 d less than the according duration for cow manure compost, and the maturation times for biogas slurry and cow manure compost were 45 and 60 d, respectively. It is an effective biogas slurry assimilate technology by application of biogas slurry as nitrogen additives in the manufacture of organic fertilizer.

  11. Ultrasound assisted biogas production from landfill leachate.

    Science.gov (United States)

    Oz, Nilgün Ayman; Yarimtepe, Canan Can

    2014-07-01

    The aim of this study is to increase biogas production and methane yield from landfill leachate in anaerobic batch reactors by using low frequency ultrasound as a pretreatment step. In the first part of the study, optimum conditions for solubilization of organic matter in leachate samples were investigated using various sonication durations at an ultrasound frequency of 20 kHz. The level of organic matter solubilization during ultrasonic pretreatment experiments was determined by calculating the ratio of soluble chemical oxygen demand (sCOD) to total chemical oxygen demand (tCOD). The sCOD/tCOD ratio was increased from 47% in raw leachate to 63% after 45 min sonication at 600 W/l. Non-parametric Friedman's test indicated that ultrasonic pretreatment has a significant effect on sCOD parameter for leachate (pbiogas and methane production rate. In anaerobic batch reactor feed with ultrasonically pretreated leachate, 40% more biogas was obtained compared to the control reactor. For statistical analysis, Mann-Whitney U test was performed to compare biogas and methane production rates for raw and pretreated leachate samples and it has been found that ultrasonic pretreatment significantly enhanced biogas and methane production rates from leachate (p<0.05) in anaerobic batch reactors. The overall results showed that low frequency ultrasound pretreatment can be potentially used for wastewater management especially with integration of anaerobic processes.

  12. MODIFIKASI KARBON AKTIF SEBAGAI ADSORBEN UNTUK PEMURNIAN BIOGAS

    Directory of Open Access Journals (Sweden)

    Heru Susanto

    2012-08-01

    Full Text Available The use of biogas as an environmentally friendly fuel is limited by the presence of CO2 and water vapor asimpurities. Therefore, biogas purification for CO2 and water vapor removal is very important step during biogasapplication. This paper presents a process for biogas purification by means of adsorption using either modifiedor unmodified activated carbon as an adsorbent. The modification was performed by passing a pure ammoniagas into activated carbon in a quartz reactor. The results showed that the adsorption process using modifiedactivated carbon decreases CO2 content in biogas up to 67.5% whereas for unmodified activated carbon was of43%. Further, the modification increased CO2 adsorption capacity from ~28 to ~38 mg CO2/g adsorbent. Theincrease in feed temperature decreases CO2 adsorption capacity.

  13. Evaluation of genotoxic effects of sodium propionate, calcium propionate and potassium propionate on the root meristem cells of Allium cepa.

    Science.gov (United States)

    Türkoğlu, Sifa

    2008-06-01

    The effects of different treatments with food preservatives, sodium propionate (SP), calcium propionate (CP) and potassium propionate (PP), on the cytology and DNA content of Allium cepa were investigated. Five concentrations of these additives - 1000, 1500, 2000, 2500, and 3000ppm - were applied for 24, 48, and 72h. All concentrations of these chemicals showed an inhibitory effect on cell division in root-tips of A. cepa and caused a decrease in mitotic index values. Additionally, all treatments changed the frequency of mitotic phases when compared with the control groups. These compounds increased chromosome abnormalities in test material. Among these abnormalities were C-mitosis, anaphase bridges, micronuclei, binucleated cells, stickiness, laggards, and chromosome breaks. The nuclear DNA contents decreased when compared with control groups.

  14. Comparative review of foam formation in biogas plants and ruminant bloat

    Energy Technology Data Exchange (ETDEWEB)

    Moeller, Lucie; Goersch, Kati; Zehnsdorf, Andreas; Mueller, Roland Arno [UFZ - Helmholtz Centre for Environmental Research, Leipzig (Germany). Environmental and Biotechnology Centre; Neuhaus, Juergen [Leipzig Univ. (Germany). Inst. of Bacteriology and Mycology

    2012-12-15

    This review gives an overview of the current knowledge concerning the problem of foam formation in the process of anaerobic digestion in biogas plants that utilize renewable resources or biogenic waste material for biogas production. Process upsets in biogas production induced by foam formation can have a negative impact on the efficiency of biogas plants. The foam can block gas pipes and cause severe damage to the bioreactor equipment, ranging from a failure of the feeders to a damage of the roof of the biogas plant. The most common foam removal methods - stirring in the foam, adding anti-foaming agents, diminishing substrate feeding, and altering the biogas reactor management - are not always successful. However, the reasons for the excessive foam formation during the biogas production process have not yet been elucidated in detail. In contrast, foam building in the rumen of ruminants as a cause for bloat has been studied thoroughly. In general, the interaction between proteins, polysaccharides (mucilage), and small plant particles is assumed to be the crucial factor. As the fermentation process in the rumen has many similarities with the biogas production process, the current research results on bloat in ruminants are summarized and compared with the process of foaming in biogas plants. (orig.)

  15. Biogas : Animal Waste That Can be Alternative Energy Source

    Directory of Open Access Journals (Sweden)

    Tuti Haryati

    2006-09-01

    Full Text Available Biogas is a renewable energy which can be used as alternative fuel to replace fossil fuel such as oil and natural gas . Recently, diversification on the use of energy has increasingly become an important issue because the oil sources are depleting . Utilization of agricultural wastes for biogas production can minimize the consumption of commercial energy source such as kerosene as well as the use of firewood . Biogas is generated by the process of organic material digestion by certain anaerobe bacteria activity in aerobic digester . Anaerobic digestion process is basically carried out in three steps i.e. hydrolysis, acidogenic and metanogenic . Digestion process needs certain condition such as C : N ratio, temperature, acidity and also digester design . Most anaerobic digestions perform best at 32 - 35°C or at 50 - 55°C, and pH 6 .8 - 8 . At these temperatures, the digestion process essentially converts organic matter in the present of water into gaseous energy . Generally, biogas consists of methane about 60 - 70% and yield about 1,000 British Thermal Unit/ft 3 or 252 Kcal/0.028 m3 when burned . In several developing countries, as well as in Europe and the United States, biogas has been commonly used as a subtitute environmental friendly energy . Meanwhile, potentially Indonesia has abundant potential of biomass waste, however biogas has not been used maximally .

  16. Continuous biogas production from fodder beet silage as sole substrate

    Energy Technology Data Exchange (ETDEWEB)

    Scherer, P.A.; Dobler, S.; Rohardt, S. [University of Applied Sciences, Hamburg (Germany). Research Centre of Environmental Bioengineering and Applied Biotechnology; Loock, R.; Buettner, B.; Noeldeke, P.; Brettschuh, A. [Loock Environmental Technologies, Hamburg (Germany)

    2003-07-01

    Since April 2000 a two-step anaerobic plant with two subsequent 500 m{sup 3} reactors has been producing biogas from fodder beet silage (pH 4.1) as the sole substrate. The plant is located at Kirchlengern near Bielefeld, Germany. Initially the reactors were inoculated with swine manure at 37{sup o}C. After a start-up phase the process was sustained at pH 7.5-8.0 by feeding with the silage as sole substrate twice a day. Parallel to the biogas plant at Kirchlengern four one-step laboratory reactors were continuously driven at temperatures of 37{sup o}C, 45{sup o}C, 60{sup o}C and 65{sup o}C. They were fed with the same silage, but only once per day (one impulse). The organic loading rate (OLR) was adjusted to 3.9 g volatile solids (VS)/(l*d) with a concomitant hydraulic retention time (HRT) of 27 d. There was no problem with starting the reactors, but after 86 days the volumetric gas production of the 65{sup o}C reactor ceased and a high amount of approximately 130 mM propionate could be determined. By decreasing the temperature down to 60{sup o}C a stable reactor performance was recovered for a period of at least 250 further days. During impulse feeding it was observed that the quickest recovery of gas production could be observed at 37{sup o}C or at 45{sup o}C. Recovery of 75% gas volume (related to the value before or after impulse feeding) was obtained after 5.5 and 7.5 h of feeding time point whereas the 60{sup o}C reactor needed 16 h. Slight significant differences were seen in the spectrum of volatile fatty acids (VFA) reaching at 37{sup o} or 45{sup o}C its maximum with 10-30 mM total VFA at 2-3 h after feeding. After this the VFA level declined to nearly zero (except for the 60{sup o}C reactor). Therefore the 37{sup o}C reactor was favoured. A double experiment with a second 37{sup o}C reactor was started by a somewhat different inoculation procedure from the remaining 3 reactors, but revealed similar results. By increasing the temperature no significantly

  17. Profile and Perceptions of Biogas as Automobile Fuel : A Study of Svensk Biogas

    OpenAIRE

    Larsson, Anneli

    2008-01-01

    From an environmental- and health perspective, biogas and other biomass-based fuels have several advantages; nevertheless the majority of motorists fill their cars with petroleum-based fuels. This thesis is designed to explore the profile of biogas in relation to its perceptions. It is a study concerning the communication between the biogas producing company Svensk Biogas and their biogas users and non biogas users. To obtain a thorough understanding of the profile and perceptions of biogas a...

  18. Biogas Opportunities Roadmap Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2015-12-01

    In support of the Obama Administration's Climate Action Plan, the U.S. Department of Energy, the U.S. Environmental Protection Agency, and U.S. Department of Agriculture jointly released the Biogas Opportunities Roadmap Progress Report, updating the federal government's progress to reduce methane emissions through biogas systems since the Biogas Opportunities Roadmap was completed by the three agencies in July 2014. The report highlights actions taken, outlines challenges and opportunities, and identifies next steps to the growth of a robust biogas industry.

  19. Efficiency of biogas plants; Effizienz von Biogasanlagen

    Energy Technology Data Exchange (ETDEWEB)

    Haupt, T.; Kraft, E. [Bauhaus-Universitaet Weimar (Germany). Fachbereich Bauingenieurwesen

    2007-02-15

    A stable biological process is a requisite for an efficient operation of biogas plants. Due to increasing flexible conditions, especially in agriculture, higher demands concerning the process performance arising. A sophisticated approach to different procedures seems to be useful. Regarding wet fermentation plants efficient control algorithms on basis of a simple model are of special interest. Analyses to figure the dynamic process behaviour via online measurements represent one possibility. For batch-operated dry fermentation processes, as most suitable application in agriculture, it is more to establish optimal start conditions. The inquiry of master data dealing with the influence of physical parameters of packed beds on the biogas yield has a valueable contingent on that. (orig.)

  20. Propionic acid production by cofermentation of Lactobacillus buchneri and Lactobacillus diolivorans in sourdough.

    Science.gov (United States)

    Zhang, Chonggang; Brandt, Markus J; Schwab, Clarissa; Gänzle, Michael G

    2010-05-01

    Cooperative metabolism of lactobacilli in silage fermentation converts lactate to propionate. This study aimed to determine whether propionate production by Lactobacillus buchneri and Lactobacillus diolivorans can be applied for bread preservation. Propionate formation was observed in cofermentation with L. buchneri and L. diolivorans in modified MRS broth as well as sourdough with low, medium and high ash contents. 48 mM of propionate was formed in sourdough with medium ash content, but only 9 and 28 mM propionate were formed in sourdoughs prepared from white wheat flour or whole wheat flour, respectively. Acetate levels were comparable in all three sourdoughs and ranged from 160 to 175 mM. Sourdough fermented with L. buchneri and L. diolivorans was used in breadmaking and its effect on fungal spoilage was compared to traditional sourdough or propionate addition to straight doughs. Bread slices were inoculated with Aspergillus clavatus, Cladosporium spp., Mortierella spp. or Penicillium roquefortii. The use of 20% experimental sourdough inhibited growth of three of the four moulds for more than 12 days. The use of 10% experimental sourdough deferred growth of two moulds by one day. Bread from traditional sourdough with added acetate had less effect in inhibiting mould growth. In conclusion, cofermentation with L. buchneri and L. diolivorans represents a process to increase antifungal capacities of bread.

  1. COMPARISON BETWEEN BIOGAS PRODUCTION FROM MANURE OF LAYING HENERS AND BROILERS

    Directory of Open Access Journals (Sweden)

    Srećko Kukić

    2010-06-01

    Full Text Available Biogas plants that process raw materials from agriculture, such as poultry manure, are one of the most significant applications of anaerobic fermentation. In Asian countries, particularly in China, India, Nepal and Vietnam, there are several million very simple, small biogas plants that produce gas for household cooking and lighting. In Europe and North America a number of agricultural biogas plants now, are increasing daily, a few thousand biogas plants exist, most of which use modern technologies, anaerobic fermentation. The aim of this paper is to determine the possibility of biogas production from poultry manure with 10% of total solids and through the segments of the quality and quantity, determine the content of total solids (DM, volatile solids (OM, and the amount and composition of biogas. The aim was also to justify the use of poultry manure in biogas production and its application for specific purposes Laboratory research showed that 1 kg of poultry 10% of poultry manure produced 47.01 l of biogas during the 40 days of anaerobic fermentation under mezofilic conditions. Production of biogas has a good potential for development in Croatia, especially in the continental part. Usages of this technology are multiple because of the fact that the Republic of Croatia imports most of the energy. Usage of biogas would reduce the import of certain energy and thus reduce energy dependence; it would increase the number of employers and ease the obligation of Croatia toward EU in replacing some fossil fuels with renewable ones.

  2. Energy efficiency and climate efficiency of biogas plants with processing and supply of biogas utilizing silage maize. Investigations at the biogas plant of HSE AG in Darmstadt-Wixhausen; Energie- und Klimaeffizienz von Biogasanlagen mit Biogasaufbereitung und -einspeisung unter Nutzung von Silomais. Untersuchungen am Beispiel der Biogasanlage der HSE AG in Darmstadt-Wixhausen

    Energy Technology Data Exchange (ETDEWEB)

    Hundt, Baerbel

    2010-07-12

    After the introduction of the German Renewable Energies Act (EEG), a real boom in the biogas sector in Germany took place. As most biogas plants have, until now, been an integrated part of a farm, the biogas produced is converted directly on site. This often leads to an insufficient use of the heat produced due to the isolated location of farms. However, if the biogas is upgraded, fed into a nearby natural gas grid and transported to a location with an existing heat sink, the heat produced can be used in an optimal way. Using the example of the biogas plant in Darmstadt-Wixhausen, the present study analyses how energy and climate efficient biogas plants are, which factors have the greatest influence on the results of energy and greenhouse-gas balances and finally how uncertain the results of life cycle assessments can be. As a result of its sophisticated heat utilization concept, the Darmstadt-Wixhausen biogas plant comes off very well from the point of view of the energy balance. The net energy gain is 4.5, the specific cumulative energy demand amounts to 1.68 MJ/MJ{sub end} {sub energie} and the energetic amortization time is 4.46 years. Regarding the greenhouse gas balance, this plant comes off rather badly due to greenhouse gas savings of only 46.8 % and due to specific greenhouse gas emissions of 72.51 g CO{sub 2eq}/MJ{sub end} {sub energie}, which range in scales similar to those of natural gas fired block heat and power plants. Amongst the most sensitive parameters related to the energy balance is the electricity consumed by the plant itself, especially the electricity demand of the upgrading technology, the silage losses and the methane yield of the used substrate. The greenhouse gas balance is additionally strongly influenced by the parameters ''methane losses'', ''nitrous oxide-emissions'' and ''grassland ploughing''. If the methane losses are reduced to a minimum by closing the digistate storage

  3. Responses of the biogas process to pulses of oleate in reactors treating mixtures of cattle and pig manure

    DEFF Research Database (Denmark)

    Nielsen, Henrik Bjørn; Ahring, Birgitte Kiær

    2006-01-01

    The effect of oleate on the anaerobic digestion process was investigated. Two thermophilic continuously stirred tank reactors (CSTR) were fed with mixtures of cattle and pig manure with different total solid (TS) and volatile solid (VS) content. The reactors were subjected to increasing pulses...

  4. Sustainable sunlight to biogas is via marginal organics.

    Science.gov (United States)

    Shilton, Andy; Guieysse, Benoit

    2010-06-01

    Although biogas production from algae offers higher sunlight to biomass energy conversion efficiencies its production costs simply cannot compete with terrestrial plants. Unfortunately terrestrial plant cropping for biogas production is, in its own right, neither particularly sustainable nor profitable and its ongoing application is only driven by energy security concerns resulting in taxpayer subsidies. By comparison, scavenging the organic energy residual/wastes from food production offers a far more profitable and sustainable proposition and has an energy potential that dwarfs anything biogas production from dedicated energy crops can realistically offer. Thus researchers wanting to assist the development of sustainable biogas systems with viable process economics should forget about terrestrial and algal energy cropping and focus on the realm of scavengers.

  5. Perspectives on Spatial Decision Support Concerning Location of Biogas Production

    DEFF Research Database (Denmark)

    Bojesen, Mikkel

    biomass resource availability is expected to decline by 10% until 2020 but with regional variation. We find that large scale biogas producers enjoy 16% lower transportation costs than small biogas producers. It is argued that biogas producers need to see themselves as agro-based retailers and accordingly...... whilst safeguarding a transparent and informative decision making process. Through the PhD thesis spatial temporal issues regarding slurry biomass resource availability is analysed together with the aspects of spatial competition in order to achieve national biogas policy ambitions. We find that slurry...... are developed through this PhD project, may be combined into integrated spatial planning and decision support systems with a human expert based user interface....

  6. Biogas Production Modelling: A Control System Engineering Approach

    Science.gov (United States)

    Stollenwerk, D.; Rieke, C.; Dahmen, M.; Pieper, M.

    2016-03-01

    Due to the Renewable Energy Act, in Germany it is planned to increase the amount of renewable energy carriers up to 60%. One of the main problems is the fluctuating supply of wind and solar energy. Here biogas plants provide a solution, because a demand-driven supply is possible. Before running such a plant, it is necessary to simulate and optimize the process feeding strategy. Current simulation models are either very detailed like the ADM 1, which leads to very long optimization runtimes or not accurate enough to handle the biogas production kinetics. Therefore this paper provides a new model of a biogas plant, which is easy to parametrize but also has the needed accuracy for the output prediction. It is based on the control system approach of system identification and validated with laboratory results of a real biogas production testing facility.

  7. Isolation of lactic acid-forming bacteria from biogas plants.

    Science.gov (United States)

    Bohn, Jelena; Yüksel-Dadak, Aytül; Dröge, Stefan; König, Helmut

    2017-02-20

    Direct molecular approaches provide hints that lactic acid bacteria play an important role in the degradation process of organic material to methanogenetic substrates in biogas plants. However, their diversity in biogas fermenter samples has not been analyzed in detail yet. For that reason, five different biogas fermenters, which were fed mainly with maize silage and manure from cattle or pigs, were examined for the occurrence of lactic acid-forming bacteria. A total of 197 lactic acid-forming bacterial strains were isolated, which we assigned to 21 species, belonging to the genera Bacillus, Clostridium, Lactobacillus, Pediococcus, Streptococcus and Pseudoramibacter-related. A qualitative multiplex system and a real-time quantitative PCR could be developed for most isolates, realized by the selection of specific primers. Their role in biogas plants was discussed on the basis of the quantitative results and on physiological data of the isolates.

  8. Combined process for ethanol fermentation at high-solids loading and biogas digestion from unwashed steam-exploded corn stover.

    Science.gov (United States)

    Wang, Zhen; Lv, Zhe; Du, Jiliang; Mo, Chunling; Yang, Xiushan; Tian, Shen

    2014-08-01

    A combined process was designed for the co-production of ethanol and methane from unwashed steam-exploded corn stover. A terminal ethanol titer of 69.8 g/kg mass weight (72.5%) was achieved when the fed-batch mode was performed at a final solids loading of 35.5% (w/w) dry matter (DM) content. The whole stillage from high-solids ethanol fermentation was directly transferred in a 3-L anaerobic digester. During 52-day single-stage digester operation, the methane productivity was 320 mL CH₄/g volatile solids (VS) with a maximum VS reduction efficiency of 55.3%. The calculated overall product yield was 197 g ethanol + 96 g methane/kg corn stover. This indicated that the combined process was able to improve overall content utilization and extract a greater yield of lignocellulosic biomass compared to ethanol fermentation alone.

  9. Biogas - the calculable energy

    Science.gov (United States)

    Kith, Károly; Nagy, Orsolya; Balla, Zoltán; Tamás, András

    2015-04-01

    EU actions against climate change are rising energy prices, both have emphasized the use of renewable energy,increase investments and energy efficiency. A number of objectives formulated in the EC decree no. 29/2009 by 2020. This document is based on the share of renewable energies in energy consumption should be increased to 20% (EC, 2009). The EU average is 20% but the share of renewables vary from one member state to another. In Hungary in 2020, 14.65% renewable energy share is planned to be achieved. According to the latest Eurostat data, the share of renewable energy in energy consumption of the EU average was 14.1%, while in Hungary, this share was 9.6% in 2012. (EUROSTAT, 2014). The use of renewable energy plant level is influenced by several factors. The most important of these is the cost savings and efficiency gains. Hungarian investments in renewable energy production usually have high associated costs and the payback period is substantially more than five years, depending on the support rate. For example, the payback period is also influenced by the green electricity generated feed prices, which is one of the lowest in Hungary compared the Member States of the European Union. Consequently, it is important to increase the production of green energy. Nowadays, predictable biogas energy is an outstanding type of decentralized energy production. It follows directly that agricultural by-products can be used to produce energy and they also create jobs by the construction of a biogas plant. It is important to dispose of and destroy hazardous and noxious substances in energy production. It follows from this that the construction of biogas plants have a positive impact, in addition to green energy which is prepared to reduce the load on the environment. The production of biogas and green electricity is one of the most environment friendly forms of energy production. Biogas production also has other important ecological effects, such as the substitution of

  10. Guide biogas. From production to utilization. 5. compl. rev. ed.; Leitfaden Biogas. Von der Gewinnung zur Nutzung

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-07-01

    The book under consideration is a guide for biogas and consists of the following contributions: (a) Targets of the guide (M. Kaltschmitt); (b) Fundamentals of anaerobic fermentation (J. Friehe); (c) Systems engineering for supplying biogas (J. Postel); (d) Description of selected substrates (J. Friehe); (e) Operation of biogas plants (J. Liebetrau); (f) Gas processing and possibilities of utilization (M. Wetthaeuser); (g) Legal and administrative framework conditions (H. von Bredow); (g) Economy (S. Hartmann); (h) Company organisation (G. Reinhold); (i) Quality and utilization of fermentation residues (H. Doehler); (j) Implementation of a project (E. Fischer); (k) Position and significance of biogas as a renewable energy resource in Germany (M. Kaltschmitt); (l) Project examples (J. Friehe).

  11. 低成本绿色循环工艺发酵生产丙酸联产维生素B12%Green and inexpensive circulation process for propionic acid and vitamin B12 production by Propionibacterium freudenreichii CCTCC M207015

    Institute of Scientific and Technical Information of China (English)

    陈飞; 张力; 冯小海; 吴波; 徐虹

    2011-01-01

    对提取维生素B12后的费氏丙酸杆菌废菌体进行水解处理,考察以菌体水解液作为N源用于丙酸发酵的可行性.利用正交设计得到了提取维生素B12后的废菌体水解优化条件.基于此,构建利用植物纤维床反应器固定化生产丙酸联产维生素B12的低成本绿色循环工艺.结果表明:在4.5L的发酵体系中,单批次总糖质量浓度为200 g/L,发酵进行了5批次共1192h,丙酸生成总量为2 328.75 g,单批次丙酸质量浓度103.50 g/L,丙酸生产效率达0.43 g/(L·h),干菌质量浓度达到19.52 g/L.将菌体注入微好氧发酵罐中发酵获得112.8 mg/L维生素B12.%Waste propionibacterium cells recovered from vitamin B12 extraction were used as nitrogen source for propionic acid fermentation. The optimizing conditions of bacteria hydrolysis were determined by the orthogonal design. Based on the above results, an immobilized fermentation unit with plant fibrous-bed bioreactor( PFB) combined with membrane separation was constructed and applied in the joint production of propionic acid and vitamin B12. By using hydrolyzed waste cells as alternative nitrogen source, propionic acid and vitamin B12 were produced with the green and inexpensive circulation process. The results showed that propionic acid yield reached a total of 2 328. 75 g with a working volume of 4. 5 L after five batches (1 192 h) in PFB immobilized coupling fermentation (single-batch glucose concentration was 200 g/L), single-batch propionic acid concentration was reached 103. 50 g/L with productivity of 0.43 g/(L·h). With the separation combined with fermentation, cell concentration gradually increased and cell dry weight reached 19. 52 g/L The whole cells were washed into the micro-aerobic bio-reactor to synthesis 112. 8 mg/L vitamin B12.

  12. Optimization of biogas production from manure

    DEFF Research Database (Denmark)

    Kaparaju, Prasad Laxmi-Narasimha; Boe, Kanokwan; Buendia, Inmaculada M.

    The main objective of the project was to improve biogas production from manures. This objective was addressed by investigating 1) the effect of different reactor configurations, 2) operational procedures, aiming to selectively retain/return degradable material in the reactor and 3) different...... process. In the second experiment, the effect of temperature (10 & 55°C) and microbial activity on passive separation of digested cow manure was investigated in vertical columns (100 cm) with an aim to improve solids retention time within the reactor and improve biogas production. Results showed...... improved from 2.5 to 14.6% when the reactor was operated under intermittent mixing compared to continuous mixing. The effect of mixing intensities (minimal, gentle or vigorous) in batch assays at 55°C showed that when the process was overloaded by high substrate to inoculum ratio (40/60), gentle (35 times...

  13. 21 CFR 582.3784 - Sodium propionate.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Sodium propionate. 582.3784 Section 582.3784 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS SUBSTANCES GENERALLY RECOGNIZED AS SAFE Chemical Preservatives §...

  14. 21 CFR 582.3081 - Propionic acid.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Propionic acid. 582.3081 Section 582.3081 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS SUBSTANCES GENERALLY RECOGNIZED AS SAFE Chemical Preservatives §...

  15. 21 CFR 582.3221 - Calcium propionate.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Calcium propionate. 582.3221 Section 582.3221 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS SUBSTANCES GENERALLY RECOGNIZED AS SAFE Chemical Preservatives §...

  16. Dynamic Biogas Upgrading for Integration of Renewable Energy from Wind, Biomass and Solar

    DEFF Research Database (Denmark)

    Jurgensen, Lars

    The Sabatier process is investigated as a storage scheme for renewable energy. Hydrogen derived from fluctuating renewable energy sources like wind and solar is converted to methane by the hydrogenation/methanation of carbon oxides. Biogas from anaerobic digestion is considered in this study...... as a high concentrated source of carbon dioxide. By using the Sabatier process, the CO2 content of the biogas is converted to CH4, which is a new upgrading process for biogas. By switching between (i) this upgrading process during periods of extensive electricity production from wind and solar, and (ii......) combined heat and power production from biogas during periods of electricity demand, bioenergy utilization becomes a dynamic process. In such a process scheme, biomass, wind, and solar could be integrated in a local context. This thesis aims to demonstrate the feasibility of the dynamic biogas upgrading...

  17. 40 CFR 721.8660 - Propionic acid methyl ester (generic).

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Propionic acid methyl ester (generic... Substances § 721.8660 Propionic acid methyl ester (generic). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as a propionic acid methyl...

  18. Analysis of biogas production through anaerobics digestion using cow dung and various co-substrates

    Directory of Open Access Journals (Sweden)

    Dhanapal Thamilselvan

    2016-01-01

    Full Text Available Biodegradable waste is a sustainable energy resource. In coming years biogas technology can be very useful worldwide, since biogas can be obtained from biodegradable waste material. This technology is based on waste reduction and also is helpful in the clean-up process of India. In this experiment, we have made single-phase biogas set-ups by using two-liter bottles. The fermentation time of the anaerobic digestion for the efficient use of gas as a fuel is about sixteen days. In our biogas digester set-ups for waste decomposion anaerobic co-digestion process is utilized. The primary feed stock is cow dung, whereas the grass, fruit, and vegetable waste are used as co-subtracts. The pH value was maintained at the range level of 6.5 to 6.9. The output biogas yield was 1.59 ml, 1.28 ml, 1.03 ml, and 0.95 ml, within an approximate period of sixteen days. Biogas obtained from cow dung and grass waste is almost identical as biogas obtained from the experimental set-up 1 (pure cow dung. Main performance characteristics of biogas formation were presented in this paper. In order to analyze a daily biogas formation, the pH value, temperature, and hydraulic retention time were changed in this experiment.

  19. Simultaneous hydrogen utilization and in situ biogas upgrading in an anaerobic reactor.

    Science.gov (United States)

    Luo, Gang; Johansson, Sara; Boe, Kanokwan; Xie, Li; Zhou, Qi; Angelidaki, Irini

    2012-04-01

    The possibility of converting hydrogen to methane and simultaneous upgrading of biogas was investigated in both batch tests and fully mixed biogas reactor, simultaneously fed with manure and hydrogen. Batch experiments showed that hydrogen could be converted to methane by hydrogenotrophic methanogenesis with conversion of more than 90% of the consumed hydrogen to methane. The hydrogen consumption rates were affected by both P(H₂) (hydrogen partial pressure) and mixing intensity. Inhibition of propionate and butyrate degradation by hydrogen (1 atm) was only observed under high mixing intensity (shaking speed 300 rpm). Continuous addition of hydrogen (flow rate of 28.6 mL/(L/h)) to an anaerobic reactor fed with manure, showed that more than 80% of the hydrogen was utilized. The propionate and butyrate level in the reactor was not significantly affected by the hydrogen addition. The methane production rate of the reactor with H₂ addition was 22% higher, compared to the control reactor only fed with manure. The CO₂ content in the produced biogas was only 15%, while it was 38% in the control reactor. However, the addition of hydrogen resulted in increase of pH (from 8.0 to 8.3) due to the consumption of bicarbonate, which subsequently caused slight inhibition of methanogenesis.

  20. 沼液堆肥化与牛粪堆肥化的发酵特性及腐熟进程%Fermentation Process and Maturation Characteristics for Biogas Slurry and Cattle Manure Compost

    Institute of Scientific and Technical Information of China (English)

    赵洪颜; 李杰; 刘晶晶; 袁旭峰; 王小芬; 崔宗均

    2012-01-01

    This experiment evaluated biogas slurry compost, and was particularly interested in the changes in maturation time and composition characteristics that resulted from the application of nitrogen additives. We investigated changes in various fermentation and maturation processes in both biogas slurry and leaf composts, and we used cattle and leaf compost as the control. Results demonstrated that the duration of the thermophilic phase (more than 50 t) for biogas slurry compost was 8 days longer than the according duration for cattle manure compost. For the biogas compost, hemicellulose and cellulose concentrations decreased from 12.1% and 20.5%, to 6.5% and 9.8%, respectively; meanwhile, concentrations for the cattle manure compost decreased to 9.6% and 15.9%. Biogas slurry compost decomposed completely. We assessed compost maturity using the following measured values :C/N, temperature, soluble sugar content, water content, and the germination index. As indicated by the germination index results, biogas slurry compost and cattle manure compost reached standard maturity within 30 d and 45 d, respectively.%为评价沼液作为堆肥含氮添加剂的应用效果,开发沼液的处理应用技术,以牛粪树叶堆肥为对照,将沼液和树叶混合堆制发酵,探讨其发酵特性与腐熟进程.研究结果表明,环境温度一直在10℃以下,沼液堆肥化和牛粪堆肥化均能经历35 d以上的堆温超过50 ℃的高温发酵;而沼液堆肥化超过50 ℃的高温期持续时间比牛粪堆肥化少8d;经60d的发酵沼液堆肥化的半纤维素含量从发酵初期的12.14%下降到6.53%,纤维素含量由20.5%下降到9.8%;而牛粪堆肥化的半纤维素含量从12.8%下降到9.56%,纤维素含量由21.5%下降到15.9%.可见沼液堆肥化的分解更彻底.从C/N、温度、可溶性糖含量、含水量、种子发芽指数综合评价两种堆肥的腐熟度,沼液堆肥化进入腐熟状态约经30 d,而牛

  1. BIOGAS PROCTION FROM ANAEROBIC CO-DIGESTION OF COW DUNG AND ORGANIC WASTES (NAPIER PAK CHONG I AND FOOD WASTE IN THAILAND: TEMPERATURE EFFECT ON BIOGAS PRODUCT

    Directory of Open Access Journals (Sweden)

    Lertluck Saitawee

    2014-01-01

    Full Text Available Biogas production has been attracting increasing attention as a biofuel of the future because biogas technology not only constitutes a biofuel source, but also can be applied in the various environmental pollutants. Anaerobic digestion of high solid slurries (such as food waste and cow dung is typically performed in continuously reactor (by force substrate flow to avoid problems with a thick floating layer or large amounts of sediments. Temperature also seems to have profound influence on the biogas production. The objective of the study was to identify the optimum biogas production for anaerobic co-digestion of cow dung and organic wastes (napierpakchong I and food waste. Influence of temperature (psyhrophilic temperature 25°C and thermoplilic temperature 45°C and active biogas process on single substrate (food waste feed and co-digestion of cow dung and organic wastes (napierpakchong I and food waste was used, within the reactor was studies in 1.80 cm high over a 45 day. Results showed that best digestion was achieved when digested of cow dung, napierpakchong I and food waste on 1:1:1 and thermoplilic temperature. Maximum biogas production (R4, biogas yield, methane content and %VS reduction was found that 70 L/day, 70 L/VS feed, 65 and 80%, respectively. The result showed that the biogas production increased progressively withhigher temperature.The increased in biogas production in thermophilic temperature and psyhrophilic temperature could be up 28.01 and 26%, respectively. The biogas yield increased 12.5% of co-digestion system, which compared to thermophilic temperature and psyhrophilic temperature (R4 and R2. This behavior might be due to the higher degradability. Therefore, temperature of digester can be used effectively as an operating strategy to optimize biogas production.

  2. Treatment of Biogas for Use as Energy

    OpenAIRE

    Koller, J.

    2010-01-01

    The biogas generated in biogas plants offers significant potential for the production of energy from renewable energy sources. The number biogas plants in the Czech Republic is expected to exceed one hundred in the near future. Substrates from agriculture, industry and municipal wastes are used for biogas production. Biogas plants usually use co-generation units to generate electricity and heat. Increased effectiveness can be achieved by using heat as a source of energy for producing renewabl...

  3. Realtime control of biogas reactors. Technical report

    Energy Technology Data Exchange (ETDEWEB)

    Poulsen, Allan K.

    2010-12-15

    In this project several online methods were connected to a biogas pilot plant designed and built by Xergi A/S (Foulum, Denmark). The pilot plant was composed of two stainless steel tanks used as substrate storage and as digester, respectively. The total volume of the reactor tank was 300 L, the working volume 200 L and the headspace volume 100 L. The process temperature in the biogas reactor was maintained at 52 {+-} 0.5 deg. C during normal operating conditions. The biogas production was measured with a flow meter and a controller was used for automatic control of temperature, effluent removal, feeding and for data logging. A NIRS (near infrared spectrometer) was connected to a recurrent loop measuring on the slurry while a {mu}-GC (micro gas chromatograph) and a MIMS (membrane inlet mass spectrometer) enabled online measurements of the gas phase composition. During the project period three monitoring campaigns were accomplished. The loading rate of the biogas reactor was increased stepwise during the periods while the process was monitored. In the first two campaigns the load was increased by increasing the mass of organic material added to the reactor each day. However, this increasing amount changed the retention time in the reactor and in order to keep the retention time constant an increasing amount of inhibitor of the microbial process was instead added in the third campaign and as such maintaining a constant organic load mass added to the reactor. The effect is similar to an increase in process load, while keeping the load of organic material and hence retention time constant. Methods have been developed for the following online technologies and each technology has been evaluated with regard to future use as a tool for biogas process monitoring: 1) {mu}-GC was able to quantitative monitor important gas phase parameters in a reliable, fast and low-maintenance way. 2) MIMS was able to quantitative monitor gas phase composition in a reliable and fast manner

  4. Inducting biogas. Future prospects; Einspeisung von Biogas. Zukunftsperspektiven

    Energy Technology Data Exchange (ETDEWEB)

    Edelmann, W.

    2008-07-01

    Biogas is a very environmentally friendly source of energy as long as it is produced from refuse and sewage. If on the other hand energy plants are added, the ecological balance is unfavourable. Using photovoltaic methods for the same surface area, 100 times more solar energy can be produced than with renewable raw materials. One can therefore assure that in the future, traffic will run on electricity and biogas from natural resources will take on an important role as a supply of raw materials for chemical synthesis. It would appear to be a good idea for this purpose to clean biogas and introduce it into the network, at least for larger plants. (author)

  5. Effect of substrate and cation requirement on anaerobic volatile fatty acid conversion rates at elevated biogas pressure.

    Science.gov (United States)

    Lindeboom, Ralph E F; Ferrer, Ivet; Weijma, Jan; van Lier, Jules B

    2013-12-01

    This work studied the anaerobic conversion of neutralized volatile fatty acids (VFA) into biogas under Autogenerative High Pressure Digestion (AHPD) conditions. The effects of the operating conditions on the biogas quality, and the substrate utilisation rates were evaluated using 3 AHPD reactors (0.6 L); feeding a concentration of acetate and VFA (1-10 g COD/L) corresponding to an expected pressure increase of 1-20 bar. The biogas composition improved with pressure up to 4.5 bar (>93% CH4), and stabilized at 10 and 20 bar. Both, acetotrophic and hydrogenotrophic methanogenic activity was observed. Substrate utilisation rates of 0.2, 0.1 and 0.1 g CODCH4/g VSS/d for acetate, propionate and butyrate were found to decrease by up to 50% with increasing final pressure. Most likely increased Na(+)-requirement to achieve CO2 sequestration at higher pressure rather than end-product inhibition was responsible.

  6. PRELIMINARY STUDY ON BIOGAS PRODUCTION OF BIOGAS FROM MUNICIPAL SOLID WASTE (MSW LEACHATE

    Directory of Open Access Journals (Sweden)

    WAN AZLINA WAN AB KARIM GHANI

    2009-12-01

    Full Text Available Laboratory-scale digesters were operated to study the effect of leachate chemical oxygen demand strength on biogas (methane production. Three sets of experiment were performed using municipal solid waste leachate slurry with two different chemical oxygen demand strength strengths namely 3000 and 21000 mg/L (referred as low and high strength, respectively. The experiments were conducted at a controlled temperature of 35°C and pH ranging from 6.8 to 7.3 over 20 days period. The process performance was evaluated based on the biogas production and pollutants removal efficiencies. Results showed that the high and low strength samples performed quite similarly but with different biogas production rate observed. The biochemical oxygen demand in the effluent removed up to 80%, but the performance of other parameters such as chemical oxygen demand, total suspended solid and volatile suspended solid was slightly decreased which contributes 33 to 46%, 21 to 37% and 20 to 35%, respectively. From this study, it can be concluded that this method not only contributed to renewable biogas production but also improved the effluent quality.

  7. Advanced Conversion of Organic Waste into Biogas

    Energy Technology Data Exchange (ETDEWEB)

    Offenbacher, Elmar [BDI-BioEnergy International AG, Grambach/Graz (Austria)

    2012-11-01

    Day by day, every human generates significant amounts of organic waste that most of the time ends on landfills. Disposing of organic residues is not just a waste of energy resources but also a burden to the environment as anthropogenic emissions of greenhouse gases are produced. In contrast to waste combustion that can't generate any energy out of organic waste but the contrary, anaerobic digestion is the most suitable technology for the sustainable and efficient conversion of all kind of organic waste into valuable biogas. Biogas generated from organic waste typically consists of 55-60% methane (CH{sub 4}) and provides an energy content of more than 20 MJ/Nm{sup 3}. The average biogas yield is around 150 Nm{sup 3} per ton of organic waste that can be converted into 350 kW of electricity plus the same amount of process heat. In other words a typical household could recover about one twentieth of its power consumption just out of the organic waste it is producing. Anaerobic digestion significantly reduces the amount of waste going to landfill as well as the uncontrolled emissions of methane. The BDI High Load Hybrid Reactor merges the core concepts of CSTR and UASB fermenters while providing a two phase anaerobic digestion system. The first process step accommodates hydrolysis and acidification to break down the complex organic molecules into simple sugars, amino acids, and fatty acids under acid conditions. In the second stage acetic acids are finally converted into methane (CH{sub 4}), carbon dioxide (CO{sub 2}) and water. This two-phase concept ensures maximum yield of biogas generated, paired with high loading rates and feedstock flexibility.

  8. Performance of the biogas project in Ziyang sugar factory

    Energy Technology Data Exchange (ETDEWEB)

    Dezhao He [Chengdu Biogas Research Inst., Chengdu (China)

    2000-07-01

    Located in Houjiaping town, Ziyang county, Ziyang Sugar Factory was installed in 1958 as a state enterprise, which mainly processes sugar cane to produce sugar. Sideline products include alcohol and paper. Nowadays, its daily capacity of sugar cane extraction is 1,000 tons and potable alcohol production is 15 - 20 tons. Its annual output value is 25 million Yuan. This plant is one of the backbones in Sichuan sugar cane processing enterprises. The biogas project of the Ziyang Sugar Factory was one of the large biogas installations in China, completed during the Seventh Five-year Plan. The distillery wastewater (slops) from the alcoholic fermentation process of starch (fresh potato, dry potato, kernel and Chinese sorghum) and sugar molasses as substrates is disposed of. The slop has a low pH, a high organic concentration, a high content of suspended solids, a dark colour and a high temperature. Its daily discharge quantity is 200 tons corresponding to 2/3 of total wastewater in that plant. It is a serious source of water pollution when it is directly discharged into Tuojiang River. Therefore, due to its high concentration of polluting substances, anaerobic treatment of distillery wastewater has been decided. This is the first case of wastewater treatment in Nudging city. The construction of this biogas installation started in July 1987. On November 25, 1988, the digester began to produce biogas. Up to now, the digesters have properly operated for more than one year. Besides its use as daily household fuel for the 810 employees, biogas is also supplied to the plant cafeteria as cooking fuel and to some production purposes within the plant, which has achieved obvious economic benefits. The designed capacity of daily biogas production for this biogas plant is 3,000 - 4,000 m{sup 3}. (orig.)

  9. International scientific conference biogas science 2009. Vol. 3. Poster; Internationale Wissenschaftstagung Biogas Science 2009. Bd. 3. Poster

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-12-15

    Within the international conference of the Bavarian State Research Center for Agriculture (Munich, Federal Republic of Germany) at 2nd to 4th December, 2009, in Erding (Federal Republic of Germany), the following lectures were held: (1) Experiments with weed seeds in the silage and fermentation process for biogas (P.R. Westermann et al.); (2) Documentation and production of quality silage from the harvest to the storage (K. Kellner); (3) Energy losses during the storage of co-substrates and possibilities of avoidance (H. Lindorfer et al.); (4) Two harvests a year for the biomass production? (J. Moeser et al.); (5) Effects of limonene on anaerobic co-digestion of citrus waste (M.B. Ruiz Fuertes et al.); (6) Biogas from genetically modified Bt-maize - potentials and limitations (U. Schoebinger et al.); (7) Green rye as a winter intercrop for the generation of biogas (E. Sticksel et al.); (8) Potential of energy yield and climate effects by means of biogas generation from vegetable coupled products (W. Stinner et al.); (9) The evaluation of the potential of gas generation from renewable raw materials (F. Weissbach); (10) Production of biogas from grass silage: Investigations of process stability (D. Andrade et al.); (11) Optimising biological desulphurisation with the addition of humic substances (U. Gayh et al.); (12) Thermophilic digestion of cellulose - investigation of the inhibitory state (K. Galkowska et al.); (13) In-situ methane enhancement system using differential solubility of biogas (J.J. Ho Kang); (14) Development of a new biogas process for the efficient utilization of renewable raw materials on thermophilic basis (C. Martin-Perez et al.); (15) Determination of a maximal space pollution of a mono fermentation of maize in a one-step or two-step system at 40 C and at 50 C in laboratory scale (M. Reuter et al.); (16) Anaerobic digestion of rye silage by a two-phase biogas process (S. Zielonka et al.); (17) Improvement of the efficiency of agricultural

  10. The future of biogas in Europe: visions and targets until 2020

    Energy Technology Data Exchange (ETDEWEB)

    Holm Nielsen, J.B. [Aalborg Univ., Esbjerg (Denmark). ACABS Research Group]|[Southern Denmark Univ., Esbjerg (Denmark). Bioenergy Dept.; Oleskowicz-Popiel, P. [Southern Denmark Univ., Esbjerg (Denmark). Bioenergy Dept.

    2007-07-01

    Biogas can be produced of nearly all kinds of organic materials. It is closely linked to agricultural activities and human consumption. Wherever there is a large population, and thereby a comprehensive quality food production of a broad mixture of vegetable and animal foods, the right conditions exist for biogas production. In the future the large volume of biogas will be integrated into the European farming systems. There are quite a few biogas process volumes at the current wastewater treatment plants, landfill gas installations, and industrial biowaste processing facilities. However, the largest volume of produced biogas will, by 2020, originate from farm biogas and from large co-digestion biogas plants, integrated into the farming- and food-processing structures. The EU policy concerning renewable energy (RES) has set forward a fixed goal of supplying 20% of the European energy demands from RES. It is without doubt, that a major part of the renewable energy will originate from European farming and forestry: as biomass conversion to gaseous, liquid and solid biofuels. The gaseous part - the biogas production - has its own, more and more consolidated platform. The forecasts look promising. At least 25% of all bioenergy in the future can originate from biogas, produces from wet organic materials, like animal manure, whole crop silages, wet organic food/feed wastes etc. The forecasts for a very flexible utilisation of biogas are prosperous, but it implicates that the biogas is to be cooled, dried, cleaned and upgraded to natural gas quality, in order for the application and utilisation routes to be plentiful. (orig.)

  11. Dutch gas distribution grid goes green: decision support tool for local biogas utilization

    NARCIS (Netherlands)

    Weidenaar, T.D.

    2011-01-01

    A Decision Support Tool (DST) has been developed that will aid Distribution Service Operators (DSOs) in their decision making process on which investments to make in the gas distribution grid in order to facilitate the use of biogas. The DST considers both the conversion of biogas to electricity as

  12. Improving biogas yields using an innovative pretreatment concept for conversion of the fiber fraction of manure

    DEFF Research Database (Denmark)

    Biswas, Rajib; Uellendahl, Hinrich; Ahring, Birgitte Kiær

    A new concept to enable economically feasible operation of manure based biogas plants was tested in lab-scale. Wet explosion (WEx) was implemented as treatment of the residual manure fibers separated after the anaerobic digestion process for enhancing the biogas production before reintroducing...

  13. Anaerobic Digestion of Saline Creeping Wild Ryegrass for Biogas Production and Pretreatment of Particleboard Material

    Science.gov (United States)

    The objective of this research was to develop an integrated process to produce biogas and high-quality particleboard using saline creeping wild ryegrass (CWR), Leymus triticoides through anaerobic digestion (AD). Besides producing biogas, AD also serves as a pretreatment method to remove the wax la...

  14. Biogas production and biogas as vehicle fuel - Swedish experiences

    Energy Technology Data Exchange (ETDEWEB)

    Lindberg, A.E. [VBB Viak AB, Stockholm (Sweden)

    1997-08-01

    In Sweden there are totally about 220 biogas plants in operation. The major part of these plants (134) are represented by sewage sludge treatment facilities at waste water treatment plants. At 60 sites the biogas is generated from landfills or cell digesters at landfills. In 1996, the amount produced had a total energy content of about 1,35 TWh (or 4 900 PJ). (EG)

  15. Enhancement and Optimization Mechanisms of Biogas Production for Rural Household Energy in Developing Countries: A review

    Directory of Open Access Journals (Sweden)

    Yitayal Addis Alemayehu

    2015-10-01

    Full Text Available Anaerobic digestion is common but vital process used for biogas and fertilizer production as well as one method for waste treatment. The process is currently used in developing countries primarily for biogas production in the household level of rural people. The aim of this review is to indicate possible ways of including rural households who own less than four heads of cattle for the biogas programs in developing countries. The review provides different research out puts on using biogas substrates other than cow dung or its mix through different enhancement and optimization mechanisms. Many biodegradable materials have been studied for alternative methane production. Therefore, these substrates could be used for production by addressing the optimum conditions for each factor and each processes for enhanced and optimized biogas production.

  16. Reactor performances and microbial communities of biogas reactors: effects of inoculum sources.

    Science.gov (United States)

    Han, Sheng; Liu, Yafeng; Zhang, Shicheng; Luo, Gang

    2016-01-01

    Anaerobic digestion is a very complex process that is mediated by various microorganisms, and the understanding of the microbial community assembly and its corresponding function is critical in order to better control the anaerobic process. The present study investigated the effect of different inocula on the microbial community assembly in biogas reactors treating cellulose with various inocula, and three parallel biogas reactors with the same inoculum were also operated in order to reveal the reproducibility of both microbial communities and functions of the biogas reactors. The results showed that the biogas production, volatile fatty acid (VFA) concentrations, and pH were different for the biogas reactors with different inocula, and different steady-state microbial community patterns were also obtained in different biogas reactors as reflected by Bray-Curtis similarity matrices and taxonomic classification. It indicated that inoculum played an important role in shaping the microbial communities of biogas reactor in the present study, and the microbial community assembly in biogas reactor did not follow the niche-based ecology theory. Furthermore, it was found that the microbial communities and reactor performances of parallel biogas reactors with the same inoculum were different, which could be explained by the neutral-based ecology theory and stochastic factors should played important roles in the microbial community assembly in the biogas reactors. The Bray-Curtis similarity matrices analysis suggested that inoculum affected more on the microbial community assembly compared to stochastic factors, since the samples with different inocula had lower similarity (10-20 %) compared to the samples from the parallel biogas reactors (30 %).

  17. Nitrogen availability of biogas residues

    Energy Technology Data Exchange (ETDEWEB)

    El-Sayed Fouda, Sara

    2011-09-07

    The objectives of this study were to characterize biogas residues either unseparated or separated into a liquid and a solid phase from the fermentation of different substrates with respect to their N and C content. In addition, short and long term effects of the application of these biogas residues on the N availability and N utilization by ryegrass was investigated. It is concluded that unseparated or liquid separated biogas residues provide N at least corresponding to their ammonium content and that after the first fertilizer application the C{sub org}:N{sub org} ratio of the biogas residues was a crucial factor for the N availability. After long term application, the organic N accumulated in the soil leads to an increased release of N.

  18. BIOGAS PRODUCTION FROM CATCH CROPS

    DEFF Research Database (Denmark)

    Molinuevo-Salces, Beatriz; Larsen, Søren U.; Ahring, Birgitte Kiær

    2014-01-01

    Catch crop cultivation combined with its use for biogas production would increase renewable energy production in the form of methane, without interfering with the production of food and fodder crops. The low biomass yield of catch crops is the main limiting factor for using these crops as co......-substrate in manure-based biogas plants and the profit obtained from the sale of biogas barely compensates for the harvest costs. A new agricultural strategy to harvest catch crops together with the residual straw of the main crop was investigated to increase the biomass and thereby the methane yield per hectare...... biomass. Leaving the straw on the field until harvest of the catch crop in the autumn could benefit biogas production due to the organic matter degradation of the straw taking place on the field during the autumn months. This new agricultural strategy may be a good alternative to achieve economically...

  19. Biogas from renewable resources through dry anaerobic digestion; Biogas aus NaWaRos durch Trockenfermentation

    Energy Technology Data Exchange (ETDEWEB)

    Heiermann, M. [ATB, Potsdam (Germany). Abt. Technikbewertung und Stoffkreislaeufe; Linke, B. [ATB, Potsdam (Germany). Abt. Bioverfahrenstechnik; Kessler, U. [Agrargenossenschaft Pirow e.G. (Germany). Biogasanlage; Loock, R. [Ingenieurbuero Loock Consultants, Hamburg (Germany)

    2007-07-01

    The functionality, performance and operational safety of anaerobic digestion using the dry-wet simultaneous technique of Loock Consultants were investigated at the biogas pilot plant in Pirow (State Brandenburg). In addition to determining process parameters and the input and output balance of the digester, chemical characterisation of the substrates and their biogas production potential were determined in the laboratory. The results reveal that a substrate mixture of 60% maize silage, 13% poultry manure and 27% digested material on a mass basis deliver a methane yield of 90 m{sup 3}t{sup -1} fresh matter, if conducted as a three-week batch process. A specific methane yield performance of 0.34 m{sup 3}kg{sup -1} VS is attained, as with dry anaerobic digestion of maize silage, with the standard wet process. (orig.)

  20. Application of a qualitative image analysis on the evaluation of microbial process parameters of biogas plants; Einsatz einer quantitativen Bildanalyse zur Beurteilung mikrobieller Prozessparameter von Biogasanlagen

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Yong Sung; Scherer, Paul [Hamburg Univ. of Applied Sciences, Hamburg-Bergedorf (Germany). Faculty of Life Sciences

    2013-10-01

    To evaluate efficiency and microbial activity of biogas or anaerobic waste water treatment plants, the number of microorganisms per gram or per milliliter is supposed to be a crucial factor. Since some years ago our research group at HAW-Hamburg has struggled to develop a simple and rapid technique for quantification and classification of environmental microbes with a semi-automatic digital image analysis. For detection of methanogens, the methanogenic fluorescence coenzyme F420 was used, which represents the vitality of methanogens. Furthermore this technique has been supplemented with morphological classification resulting in a Quantitative Microscopic Fingerprinting (QMF). The technique facilitates to find out microbial reasons for some problems of reactor performances. In addition QMF allows differentiating between H{sub 2}-CO{sub 2} and acetate consuming methanogens according to their morphology. At the moment, this study focusses on some relationships between QMF and plant operation parameters. As an example, a thermophilic biogas plant fed by 65% liquid cow manure, maize silage, grass silage and solid cow manure was analyzed for more than 22 weeks. Here some basic background and methodical procedures were presented as well as validation of this technique. (orig.)

  1. Environmental and economic analysis of application of water hyacinth for eutrophic water treatment coupled with biogas production.

    Science.gov (United States)

    Wang, Zanxin; Calderon, Margaret M

    2012-11-15

    The proliferation of water hyacinth is currently controlled by removing it from a water body and disposing it by landfill in China. Using water hyacinth to remove nutrients from water bodies and to produce biogas is another technically feasible option for the control of water hyacinth, but its environmental and economic performances are not well understood. This study collected data from an experimental biogas plant to develop a lifecycle analysis and a cost benefit analysis for the control of water hyacinth proliferation in a eutrophic lake in China. Comparison was made between the alternative option of using water hyacinth for biogas production and the current practice of disposing it in landfills. The results reveal that the biogas option is economically feasible with a positive energy balance. The removal of water hyacinth to produce biogas can contribute to water quality improvement and GHG emission reduction whose values, however, depend on the processing scale of the biogas plant. Since both the current approach and the biogas option can remove nutrients from water bodies, the additional value of water quality improvement resulting from the biogas option is only possible when the processing scale of the biogas plant is greater than the amount of water hyacinth disposed by landfill. The emission of methane deserves attention when water hyacinth is disposed by landfill. The biogas option can respond to China's policies on water pollution control, renewable energy development, and energy saving and emission reduction.

  2. Glidarc assisted production of synthesis gas from biogas

    Energy Technology Data Exchange (ETDEWEB)

    Czernichowski, A. [Orleans Univ., Department of Physics, 45 - Orleans (France); Czernichowski, M.; Wesolowska, K. [Etudes Chimiques et Physiques (ECP), 45 - La Ferte Saint Aubin (France)

    2003-09-01

    We present an emerging biogas reformer based on a direct use of high-voltage discharges (called GlidArc) that strike in the flow of such widely available and renewable feedstock without any gas separation or purification. A poor biogas (containing only 35-50 vol.% of methane) is partially converted into hydrogen and carbon monoxide (SynGas). Such upgraded biogas can, for example, be used as fuel in Internal Combustion Engines, be considered as source of Hydrogen for PEM fuel cells or be consumed in other specific fuel cells. Any level of impurities is accepted for our reformer where the discharges provide all necessary energy and catalytic assistance for endothermic process of so-called 'dry' reforming of CH{sub 4}+CO{sub 2} into H{sub 2}+CO. Our tests with biogas are performed in a 1.4-L reactor working at atmospheric pressure at up to 0.6 kW electric power. Such input is fully sufficient to process a flow of a poor biogas presenting up to 7 kW of thermal power. (authors)

  3. Effect of whey storage on biogas produced by co-digestion of sewage sludge and whey.

    Science.gov (United States)

    Powell, N; Broughton, A; Pratt, C; Shilton, A

    2013-01-01

    Biogas production from municipal anaerobic digesters could potentially be boosted via co-digestion with organic wastes such as whey. The challenge is that whey production is seasonal. This research examined the effect of storing whey at ambient temperature on: (1) whey composition; (2) biogas production from co-digestion of the stored whey with municipal primary sludge. Whey storage resulted in acidification with formation of acetate, propionate and butyrate and a 9% reduction in total chemical oxygen demand (COD) over the 9-month trial. A control digester fed with primary sludge produced 0.18-0.23 m3 CH4/kgCOD(added). Co-digestion of fresh whey and sludge increased biogas production and the methane contribution from the whey was 0.29 m3CH4/kgCOD(added). When the fresh whey was substituted with stored whey, methane production by the whey remained at 0.29 m3CH4/kgCOD(added). The ability to store whey at ambient temperature and allow co-digestion year round will significantly improve the economics of biogas production from whey.

  4. Biogas from fibrous digestate and wood. New lignin extraction (LX) process for energy and raw material production from plant residues; Biogas aus ''ausgegorenem'' Gaerrest und Holz. Das neue Lignin-Extraktions-(LX)-Verfahren zur Energie- und Rohstoffproduktion aus pflanzlichen Reststoffen

    Energy Technology Data Exchange (ETDEWEB)

    Streffer, R.M.F. [maxbiogas GmbH, Marienwerder (Germany)

    2011-07-01

    75% of plant biomass on earth is made of cellulose and lignine, the lignocelluloses. In a simplified view the lignin wraps in plant biomass the substances easily degraded by microorganisms like cellulose. The LX process utilizes plant biomass and separates it to lignine and pretreated LX-substrate with a reduced lignine content, which is fed back to the fermentation process to be degraded. Combining a biogas plant with the LX process allows even the degradation of fibrous plant parts and it is possible to digest wood. E.g. the fibrous digest is fermented more efficient than maize silage. The LX process has therefore the potential to be able to produce in future economically either energy as wells as resources form plant residues. (orig.) [German] 75% der pflanzlichen Biomasse auf der Welt bestehen aus Zellulose und Lignin, der Lignocellulose. Lignin umhuellt, vereinfacht beschrieben, im pflanzlichen Substrat die leicht durch Mikroorganismen abbaubaren Stoffe, wie Zellulose. Das LX-Verfahren verwertet pflanzliche Biomasse und erzeugt daraus Lignin und stark im Ligningehalt reduziertes, sogenanntes ''aufgeschlossenes'', LX-Substrat, dass dann dem weiteren Abbauprozess zugefuehrt wird. Kombiniert man zum Beispiel eine Biogasanlage mit dem LX-Verfahren, so koennen selbst faserige Pflanzenbestandteile und erstmalig auch Holz vergoren werden. Beispielsweise wird ''ausgegorener'' Gaerrest effizienter fermentiert als Maissilage. Damit hat das LX-Verfahren das Potenzial, kuenftig sowohl Energie als auch Rohstoffe aus pflanzlichen Reststoffen wirtschaftlich herstellen zu koennen.

  5. Enzyme research and applications in biotechnological intensification of biogas production.

    Science.gov (United States)

    Parawira, Wilson

    2012-06-01

    Biogas technology provides an alternative source of energy to fossil fuels in many parts of the world. Using local resources such as agricultural crop remains, municipal solid wastes, market wastes and animal waste, energy (biogas), and manure are derived by anaerobic digestion. The hydrolysis process, where the complex insoluble organic materials are hydrolysed by extracellular enzymes, is a rate-limiting step for anaerobic digestion of high-solid organic solid wastes. Biomass pretreatment and hydrolysis are areas in need of drastic improvement for economic production of biogas from complex organic matter such as lignocellulosic material and sewage sludge. Despite development of pretreatment techniques, sugar release from complex biomass still remains an expensive and slow step, perhaps the most critical in the overall process. This paper gives an updated review of the biotechnological advances to improve biogas production by microbial enzymatic hydrolysis of different complex organic matter for converting them into fermentable structures. A number of authors have reported significant improvement in biogas production when crude and commercial enzymes are used in the pretreatment of complex organic matter. There have been studies on the improvement of biogas production from lignocellulolytic materials, one of the largest and renewable sources of energy on earth, after pretreatment with cellulases and cellulase-producing microorganisms. Lipids (characterised as oil, grease, fat, and free long chain fatty acids, LCFA) are a major organic compound in wastewater generated from the food processing industries and have been considered very difficult to convert into biogas. Improved methane yield has been reported in the literature when these lipid-rich wastewaters are pretreated with lipases and lipase-producing microorganisms. The enzymatic treatment of mixed sludge by added enzymes prior to anaerobic digestion has been shown to result in improved degradation of the

  6. [Effect of pretreatment on storage and biogas production of baling wheat straw].

    Science.gov (United States)

    Ma, Hui-Juan; Chen, Guang-Yin; Du, Jing; Chang, Zhi-Zhou; Ye, Xiao-Mei

    2013-08-01

    Long-term storage of crop straw is very important for biogas plant while pretreatment is always used to improve biogas production of crop straw. Feasibility of integrating the storage with pretreatment of baling wheat straw was studied. Changes of physicochemical properties and the biogas productivity of wheat straw obtained before and after 120 days storage were analyzed. The results showed that it was feasible to directly bale wheat straw for storage (control) and storage treatment had little effect on the physicochemical properties, structure and biogas productivity of wheat straw. After 120 day's storage, biogas production potential of the surface wheat straw of pile was decreased by 7.40%. Integrating NaOH pretreatment with straw storage was good for biogas production of wheat straw and the total solid (TS) biogas yield was increased by 7.02%-8.31% (compared to that of wheat straw without storage) and 5.68% -16.96% (compared to that of storage without alkaline pretreatment), respectively. Storage with urea treatment was adverse to biogas production of wheat straw and the contents of cellulose and hemicellulose of wheat straw were decreased by 18.25%-27.22% and 5.31%-16.15% and the TS biogas yield was decreased by 2.80%-7.71% after 120 day's storage. Exposing wheat straw to the air during the storage process was adverse to the conserving of organic matter and biogas utilization of wheat straw, but the influence was very slight and the TS biogas yield of wheat straw obtained from pile surface of control and urea treatment was decreased by 7.40% and 4.25%, respectively.

  7. Biogas Production from Energy Crops and Agriculture Residues

    DEFF Research Database (Denmark)

    Wang, Guangtao

    In this thesis, the feasibility of utilizing energy crops (willow and miscanthus) and agriculture residues (wheat straw and corn stalker) in an anaerobic digestion process for biogas production was evaluated. Potential energy crops and agriculture residues were screened according...... to their suitability for biogas production. Moreover, pretreatment of these biomasses by using wet explosion method was studied and the effect of the wet explosion process was evaluated based on the increase of (a) sugar release and (b) methane potential when comparing the pretreated biomass and raw biomass. Ensiling...

  8. Monitoring of biogas plants - experiences in laboratory and full scale

    Directory of Open Access Journals (Sweden)

    B. Habermann

    2015-04-01

    Full Text Available To control and regulate the biogas process there are online process parameters and offline process parameters, which basically don’t differ between pilot biogas plants and industrial biogas plants. Generally, temperature, pH-value, volume flow rate and sometimes redox potential are measured online. An online-measurement of the dissolved volatile fatty acids and an online-detection of dissolved hydrogen both directly in the liquid phase as well as near-infrared spectroscopy are under development. FOS/TAC-analysis is the most common offline-analysis of the biogas process and normally it is carried out by the plant operator directly at the biogas plant. For example dry matter, organic dry matter, nitrogen and fatty acids are other analyses, which are carried out but by a laboratory. Microbiological analyses of biogas plants are very expensive and time-consuming and are therefore in Germany very rare. Microbiological analyses are mainly for research purposes. For example the Fluorescence in situ Hybridiation (FISH is used for characterization of the populations. Electric-optical measurement should be established as a new method to investigate the vitality of the methane producing microorganisms. In a cooperation project, which is promoted by the German ministry for technology, between IASP and Chair of Bioprocess Engineering at TU Berlin, this method is proper investigated using a device from the firm EloSystems. The microorganisms are brought in an electrical field of different frequencies. In this field the microorganisms direct themselves differently according to their physiological state. At the end of this project an early detection of process disturbance will be possible with the help of this method. In this presentation the result of the first tests are presented.

  9. Evaluation of energy efficiency of various biogas production and utilization pathways

    Energy Technology Data Exchange (ETDEWEB)

    Poeschl, Martina; Ward, Shane [Charles Parsons Energy Research Programme, Bioresources Research Centre, School of Agriculture, Food Science and Veterinary Medicine, University College Dublin, Belfield, Dublin 4 (Ireland); Owende, Philip [Charles Parsons Energy Research Programme, Bioresources Research Centre, School of Agriculture, Food Science and Veterinary Medicine, University College Dublin, Belfield, Dublin 4 (Ireland); School of Informatics and Engineering, Institute of Technology Blanchardstown, Blanchardstown Road North, Dublin 15 (Ireland)

    2010-11-15

    The energy efficiency of different biogas systems, including single and co-digestion of multiple feedstock, different biogas utilization pathways, and waste-stream management strategies was evaluated. The input data were derived from assessment of existing biogas systems, present knowledge on anaerobic digestion process management and technologies for biogas system operating conditions in Germany. The energy balance was evaluated as Primary Energy Input to Output (PEIO) ratio, to assess the process energy efficiency, hence, the potential sustainability. Results indicate that the PEIO correspond to 10.5-64.0% and 34.1-55.0% for single feedstock digestion and feedstock co-digestion, respectively. Energy balance was assessed to be negative for feedstock transportation distances in excess of 22 km and 425 km for cattle manure and for Municipal Solid Waste, respectively, which defines the operational limits for respective feedstock transportation. Energy input was highly influenced by the characteristics of feedstock used. For example, agricultural waste, in most part, did not require pre-treatment. Energy crop feedstock required the respect cultivation energy inputs, and processing of industrial waste streams included energy-demanding pre-treatment processes to meet stipulated hygiene standards. Energy balance depended on biogas yield, the utilization efficiency, and energy value of intended fossil fuel substitution. For example, obtained results suggests that, whereas the upgrading of biogas to biomethane for injection into natural gas network potentially increased the primary energy input for biogas utilization by up to 100%; the energy efficiency of the biogas system improved by up to 65% when natural gas was substituted instead of electricity. It was also found that, system energy efficiency could be further enhanced by 5.1-6.1% through recovery of residual biogas from enclosed digestate storage units. Overall, this study provides bases for more detailed assessment

  10. Efficient Heat Use from Biogas CHP Plants. Case Studies from Biogas Plants in Latvia

    OpenAIRE

    Dzene, Ilze; Slotiņa, Lāsma

    2013-01-01

    This paper is focusing on efficient heat use from biogas plants. It gives an overview about various biogas heat use options and specifically addresses biogas heat use market in Latvia. In the end three examples from typical agricultural biogas plants in Latvia and their heat use plans are described.

  11. Biogas production from Eichhornia crassipes aquatic plant; Producao de biogas a partir da planta aquatica Eichhornia crassipes

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Roberto Guimaraes; Silva, Jose Goncalves da; Fernandes Filho, Jorge; Pereira, Maria Cristina Duarte Eiras [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Dept. de Engenharia Mecanica. Programa de Pos-Graduacao em Engenharia Mecanica]. E-mail: temrobe@vm.uff.br; Melo, Ricardo Bichara de [Light Servicos de Eletricidade S.A., Rio de Janeiro, RJ (Brazil)]. E-mail: rbmelo@light.com.br

    2004-07-01

    Virtually all plants and waste plants and animals may in some way be used as an energy source. The anaerobic digestion of these materials is an option, resulting in the biogas. Besides the gas obtained in the process, is produced, inside the biodigester, an excellent fertilizer. The aquatic plant Eichhornia crassipes is found in large quantities in various water bodies, such as reservoirs, lakes and ponds, becoming mostly often a big problem and it is necessary its systematic removal of water. The bench biodigester used in the experiment of biodigestion of aquatic plants is composed of a reactor containing the biomass, where the biogas is produced, and a reservoir to monitor the production of biogas. The reactor is located within a receptacle containing water that can be heated by an electrical resistance, with the purpose of maintaining the temperature inside the reactor around 35 deg C. The results of analysis of gas of the reactor made in a gas chromatograph to CG MASTER of double ionization detector with a flame and thermal conductivity, show a percentage of 50% of methane in the biogas. The process of biodigestion of aquatic plant Eichhornia crassipes shows potential to obtain biogas, with considerable levels of methane in order to make its exploitation. Also, were analyzed the biomass in the biodigester for determination of humid, total organic matter, mineral and organic carbon residue.

  12. Biodigestion of the aquatics plants mixtures and biogas production; Biodigestao de misturas de plantas aquaticas e producao de biogas

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Roberto Guimaraes; Abreu, Fernando Luiz Barbuda de; Fernandes Filho, Jorge; Pereira, Maria Cristina Duarte Eiras [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Dept. de Engenharia Mecanica. Programa de Pos-Graduacao em Engenharia Mecanica]. E-mail: temrobe@vm.uff.br; Melo, Ricardo Bichara de [Light Servicos de Eletricidade S.A., Rio de Janeiro, RJ (Brazil). Gerencia de Estudos e Gestao de Geracao]. E-mail: rbmelo@light.com.br

    2004-07-01

    Several systems of generating electricity using water storage reservoirs. One problem that occurs constantly in these reservoirs is the accumulation of aquatic plants, such as Eichhornia crassipes, Eichhornia azurea, Pistia stratiotes and Salvinia that may cause serious problems for the system. Periodically, the biomass must be removed and disposed of appropriate form, so that does not cause contamination of soil, groundwater or allowing the proliferation of vectors. One possible destination is the use of biomass in a process of biodigestion, resulting in biogas. The bench of biodigester used in the experiment of biodigestion of aquatic plants is composed of a reactor containing the biomass, where the biogas is produced and a reservoir for the monitoring the production of biogas. The reactor is located inside a container containing water that can be heated by an electrical resistance, with the aim of maintaining the temperature inside the reactor around 35 deg C. The results of analysis of gas of the reactor was obtained using a gas chromatograph to CG MASTER of double ionization detector with a flame and thermal conductivity. These results show a percentage of 50% of methane in the biogas. Also, were analyzed the biomass in the biodigester for determination of humidity, total organic matter, waste mineral and organic carbon. The process of biodigestion of the mixture of aquatic plants: Eichhornia crassipes, Eichhornia azurea and Pistia stratiotes and Salvinia shows potential for obtaining biogas, with considerable levels of methane, in order to facilitate its recovery.

  13. Electricity production from biogas in Serbia: Assessment of emissions reduction

    Directory of Open Access Journals (Sweden)

    Cvetković Slobodan M.

    2016-01-01

    Full Text Available Biogas represents a promising source for the production of clean energy. The objective of this paper was to quantify the potential for the reduction of emissions to the environment during the production of electricity from biogas in comparison with environmental effects of the production of the same amount of electricity from fossil resources (coal from Kolubara basin and natural gas. Basis for comparison of environmental impacts in this work was the annual production of electricity in biogas plants of the total capacity of 80 MW. This study has shown that the annual production of electricity from biogas power plants of 80 MW results in: substitution of up to 840 kt of coal from Kolubara basin and 123.2 million m3 of natural gas; reduction in emissions of greenhouse gases in the range of 491.16 kt - 604.97 kt CO2-eq, depending on the energy efficiency of the process of electricity production from biogas; reduction in emissions of greenhouse gases up to 92.37 kt CO2-eq compared to the use of natural gas for electricity generation.

  14. Energy balance model of a SOFC cogenerator operated with biogas

    Science.gov (United States)

    Van herle, Jan; Maréchal, F.; Leuenberger, S.; Favrat, D.

    A small cogeneration system based on a Solid Oxide Fuel Cell (SOFC) fed on the renewable energy source biogas is presented. An existing farm biogas production site (35 m 3 per day), currently equipped with a SOFC demonstration stack, is taken for reference. A process flow diagram was defined in a software package allowing to vary system operating parameters like the fuel inlet composition, reforming technology, stack temperature and stack current (or fuel conversion). For system reforming simplicity, a base case parameter set was defined as the fuel inlet of 60% CH 4:40% CO 2 mixed with air in a 1:1 ratio, together with 800 °C operating temperature and 80% fuel conversion. A model stack, consisting of 100 series elements of anode supported electrolyte cells of 100 cm 2 each, was calculated to deliver 3.1 kW el and 5.16 kW th from an input of 1.5 N m 3/h of biogas (8.95 kW LHV), corresponding to 33.8 and 57.6% electrical and thermal efficiencies (Lower Heating Values (LHVs)), respectively. The incidence on the efficiencies of the model system was examined by the variation of a number of parameters such as the CO 2 content in the biogas, the amount of air addition to the biogas stream, the addition of steam to the fuel inlet, the air excess ratio λ and the stack operating temperature, and the results discussed.

  15. Quantifying physical structure changes and non-uniform water flow in cattle manure during dry anaerobic digestion process at lab scale: Implication for biogas production.

    Science.gov (United States)

    André, L; Durante, M; Pauss, A; Lespinard, O; Ribeiro, T; Lamy, E

    2015-09-01

    The aim of this study was to investigate and quantify non-uniform water flow during dry AD and its implication for biogas production. Laboratory tracer experiments were performed on cattle manure over the course of AD. The evolution of the permeability, the dry bulk density, the dry porosity, the total and volatile solid contents of cattle manure at different stages of AD, revealed waste structure changes, impacting water flow and methane production. Tracer experiments and numerical modeling performed by using a physical non-equilibrium model indicated non-uniform preferential flow patterns during degradation. According to literature, the increase of inoculum recirculation frequency improved methane production rate. However, these results demonstrated that this improvement occurs only at the beginning of manure degradation. After 19 days of degradation the inoculum recirculation and the flow patterns modification had no effect on methane production rate.

  16. Engineering Escherichia coli for high-level production of propionate.

    Science.gov (United States)

    Akawi, Lamees; Srirangan, Kajan; Liu, Xuejia; Moo-Young, Murray; Perry Chou, C

    2015-07-01

    Mounting environmental concerns associated with the use of petroleum-based chemical manufacturing practices has generated significant interest in the development of biological alternatives for the production of propionate. However, biological platforms for propionate production have been limited to strict anaerobes, such as Propionibacteria and select Clostridia. In this work, we demonstrated high-level heterologous production of propionate under microaerobic conditions in engineered Escherichia coli. Activation of the native Sleeping beauty mutase (Sbm) operon not only transformed E. coli to be propionogenic (i.e., propionate-producing) but also introduced an intracellular "flux competition" between the traditional C2-fermentative pathway and the novel C3-fermentative pathway. Dissimilation of the major carbon source of glycerol was identified to critically affect such "flux competition" and, therefore, propionate synthesis. As a result, the propionogenic E. coli was further engineered by inactivation or overexpression of various genes involved in the glycerol dissimilation pathways and their individual genetic effects on propionate production were investigated. Generally, knocking out genes involved in glycerol dissimilation (except glpA) can minimize levels of solventogenesis and shift more dissimilated carbon flux toward the C3-fermentative pathway. For optimal propionate production with high C3:C2-fermentative product ratios, glycerol dissimilation should be channeled through the respiratory pathway and, upon suppressed solventogenesis with minimal production of highly reduced alcohols, the alternative NADH-consuming route associated with propionate synthesis can be critical for more flexible redox balancing. With the implementation of various biochemical and genetic strategies, high propionate titers of more than 11 g/L with high yields up to 0.4 g-propionate/g-glycerol (accounting for ~50 % of dissimilated glycerol) were achieved, demonstrating the

  17. Kinetics of propionate conversion in anaerobic continuously stirred tank reactors

    DEFF Research Database (Denmark)

    Bangsø Nielsen, Henrik; Mladenovska, Zuzana; Ahring, Birgitte Kiær

    2008-01-01

    The kinetic parameters of anaerobic propionate degradation by biomass from 7 continuously stirred tank reactors differing in temperature, hydraulic retention time and substrate composition were investigated. In substrate-depletion experiments (batch) the maximum propionate degradation rate, A......-m, was estimated. The results demonstrate that the rate of endogenous substrate (propionate) production should be taken into account when estimating kinetic parameters in biomass from manure-based anaerobic reactors....

  18. Modelling anaerobic digestion in a biogas reactor: ADM1 model development with lactate as an intermediate (Part I).

    Science.gov (United States)

    Satpathy, Preseela; Biernacki, Piotr; Uhlenhut, Frank; Cypionka, Heribert; Steinigeweg, Sven

    2016-12-05

    The Anaerobic Digestion Model No. 1 (ADM1) was extended to include lactate, a crucial metabolic product during sugar fermentation. This study tests the validity of the modified ADM1 model in improving the predictions of a standard biogas reactor. This reactor was prepared in the laboratory with simple organic substrates with an intention to represent an 'average biogas plant'. Kinetic parameters were determined from a lactic acid enriched steady-state reactor. The parameters were adjusted further in order to acquire satisfying simulation results systematically with the batch experiments and then against the standard biogas reactor. Arresting methanogenesis revealed that lactate degradation occurred majorly via acetate followed by propionate, and a non-negligible proportion of butyrate too was found, which were further updated in the model. The modified ADM1 provided a successful correlation with the experimental results for the batch and continuous experiments. We justified that inclusion of lactate in the model resulted in optimized simulation for both biogas and methane content in the standard biogas reactor.

  19. A concise biogas plant construction suitable for Ghana and other tropical countries

    Energy Technology Data Exchange (ETDEWEB)

    Gbagbo, J.K.N.

    1997-04-01

    This report is intended to be used by people in the field of biogas for workshops, technicians, teachers to educate as well as to carry out hands on constructions in Ghana and other tropical countries. Chapter 1, discusses the biogas technology, what a biogas plant is, and how it functions. Chapter 2, describes the entire process. Chapter 3, discusses the necessary conditions for fermentation. Chapter 4, the measuring parameters for monitoring the system. Chapter 5, describes the various types of biogas plants suitable for tropical countries. Chapter 6, describes a planning guide for Ghana and other tropical countries. Chapter 7, discusses digester sizing and finally, Chapter 8, describes a concise biogas plant construction suitable for the rural areas of Ghana and other tropical countries. (au)

  20. Anaerobic digestion foaming in full-scale biogas plants: a survey on causes and solutions.

    Science.gov (United States)

    Kougias, P G; Boe, K; O-Thong, S; Kristensen, L A; Angelidaki, I

    2014-01-01

    Anaerobic digestion foaming is a common operation problem in biogas plants with negative impacts on the biogas plants economy and environment. A survey of 16 Danish full-scale biogas plants on foaming problems revealed that most of them had experienced foaming in their processes up to three times per year. Foaming incidents often lasted from one day to three weeks, causing 20-50% biogas production loss. One foaming case at Lemvig biogas plant has been investigated and the results indicated that the combination of feedstock composition and mixing pattern of the reactor was the main cause of foaming in this case. Moreover, no difference in bacterial communities between the foaming and non-foaming reactors was observed, showing that filamentous bacteria were not the main reason for foaming in this case.

  1. PREDICTION OF COMBUSTION CHARACTERISTICS OF A TYPICAL BIOGAS BURNER USING CFD

    Directory of Open Access Journals (Sweden)

    K. MADHUSOODAN PILLAI

    2012-07-01

    Full Text Available Biogas is obtained from anaerobic digestion of biodegradable materials such as agricultural waste, animal waste, and othertype of household solid waste and its main constituents are CH4 and CO2. Effects of the concentration of each species are very important in the biogas combustion. The present study focuses on the effect of inlet velocities of methane and air on the flame temperature in a biogas burner lamp. The model of biogas burner lamp is constructed by using the CFD software GAMBIT and the simulation process was performed by using Fluent Software. The flame temperature obtained is 2172 k when the inlet velocities of methane and air are 0.2m/s and 0.8 m/s respectively. Results of this study will provide valuable data for biogas burner lamp manufacturers.

  2. Potential bioetanol and biogas production using lignocellulosic biomass from winter rye, oilseed rape and faba bean

    DEFF Research Database (Denmark)

    Petersson, Anneli; Thomsen, Mette Hedegaard; Hauggaard-Nielsen, Henrik

    2007-01-01

    to be optimal for pretreatment of corn stover (195 degrees C, 15 min, 2 g l(-1) Na2CO3 and 12 bar oxygen). It was shown that pretreatment was necessary for ethanol production from all raw materials and gave increased biogas yield from winter rye straw. Neither biogas productivity nor yield from oilseed rape......) faba bean straw (Viciafaba L.). Their composition with regard to cellulose, hemicellulose, lignin, extractives and ash was evaluated, as well as their potential as raw materials for ethanol and biogas production. The materials were pretreated by wet oxidation using parameters previously found...... be concluded that all three materials are possible raw materials for either biogas or ethanol production; however, improvement of biogas productivity or ethanol yield is necessary before an economical process can be achieved....

  3. Innovative test method for the estimation of the foaming tendency of substrates for biogas plants.

    Science.gov (United States)

    Moeller, Lucie; Eismann, Frank; Wißmann, Daniel; Nägele, Hans-Joachim; Zielonka, Simon; Müller, Roland A; Zehnsdorf, Andreas

    2015-07-01

    Excessive foaming in anaerobic digestion occurs at many biogas plants and can cause problems including plugged gas pipes. Unfortunately, the majority of biogas plant operators are unable to identify the causes of foaming in their biogas reactor. The occurrence of foaming is often related to the chemical composition of substrates fed to the reactor. The consistency of the digestate itself is also a crucial part of the foam formation process. Thus, no specific recommendations concerning substrates can be given in order to prevent foam formation in biogas plants. The safest way to avoid foaming is to test the foaming tendency of substrates on-site. A possible solution is offered by an innovative foaming test. With the help of this tool, biogas plant operators can evaluate the foaming disposition of new substrates prior to use in order to adjust the composition of substrate mixes.

  4. Biogas and Fuel Cells Workshop Summary Report: Proceedings from the Biogas and Fuel Cells Workshop, Golden, Colorado, June 11-13, 2012

    Energy Technology Data Exchange (ETDEWEB)

    2013-01-01

    The U.S. Department of Energy (DOE) National Renewable Energy Laboratory (NREL) held a Biogas and Fuel Cells Workshop June 11-13, 2012, in Golden, Colorado, to discuss biogas and waste-to-energy technologies for fuel cell applications. The overall objective was to identify opportunities for coupling renewable biomethane with highly efficient fuel cells to produce electricity; heat; combined heat and power (CHP); or combined heat, hydrogen and power (CHHP) for stationary or motive applications. The workshop focused on biogas sourced from wastewater treatment plants (WWTPs), landfills, and industrial facilities that generate or process large amounts of organic waste, including large biofuel production facilities (biorefineries).

  5. Biogas recirculation for simultaneous calcium removal and biogas purification within an expanded granular sludge bed system treating leachate.

    Science.gov (United States)

    Luo, Jinghuan; Lu, Xueqin; Liu, Jianyong; Qian, Guangren; Lu, Yongsheng

    2014-12-01

    Biogas, generated from an expanded granular sludge bed (EGSB) reactor treating municipal solid waste (MSW) leachate, was recirculated for calcium removal from the leachate via a carbonation process with simultaneous biogas purification. Batch trials were performed to optimize the solution pH and imported biogas (CO2) for CaCO3 precipitation. With applicable pH of 10-11 obtained, continuous trials achieved final calcium concentrations of 181-375 mg/L (removal efficiencies≈92.8-96.5%) in the leachate and methane contents of 87.1-91.4% (purification efficiencies≈65.4-82.2%) in the biogas. Calcium-balance study indicates that 23-986 mg Ca/d was released from the bio-system under the carbonized condition where CaCO3 precipitating was moved outside the bioreactor, whereas 7918-9517 mg Ca/d was trapped into the system for the controlled one. These findings demonstrate that carbonation removal of calcium by biogas recirculation could be a promising alternative to pretreat calcium-rich MSW leachate and synergistically to improve methane content.

  6. Biogas and Hydrogen Systems Market Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Milbrandt, Anelia [National Renewable Energy Lab. (NREL), Golden, CO (United States); Bush, Brian [National Renewable Energy Lab. (NREL), Golden, CO (United States); Melaina, Marc [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2016-03-31

    This analysis provides an overview of the market for biogas-derived hydrogen and its use in transportation applications. It examines the current hydrogen production technologies from biogas, capacity and production, infrastructure, potential and demand, as well as key market areas. It also estimates the production cost of hydrogen from biogas and provides supply curves at a national level and at point source.

  7. Bounded Biofuels? Sustainability of Global Biogas Developments

    NARCIS (Netherlands)

    Mol, A.P.J.

    2014-01-01

    Compared to liquid biofuels biogas has hardly drawn any attention from social sciences researchers lately. Although the share of biogas and liquid biofuels in the energy portfolio of many countries are comparable, biogas systems are strongly place-based and are non-controversial in terms of sustaina

  8. Impact of CAD-deficiency in flax on biogas production.

    Science.gov (United States)

    Wróbel-Kwiatkowska, Magdalena; Jabłoński, Sławomir; Szperlik, Jakub; Dymińska, Lucyna; Łukaszewicz, Marcin; Rymowicz, Waldemar; Hanuza, Jerzy; Szopa, Jan

    2015-12-01

    Global warming and the reduction in our fossil fuel reservoir have forced humanity to look for new means of energy production. Agricultural waste remains a large source for biofuel and bioenergy production. Flax shives are a waste product obtained during the processing of flax fibers. We investigated the possibility of using low-lignin flax shives for biogas production, specifically by assessing the impact of CAD deficiency on the biochemical and structural properties of shives. The study used genetically modified flax plants with a silenced CAD gene, which encodes the key enzyme for lignin synthesis. Reducing the lignin content modified cellulose crystallinity, improved flax shive fermentation and optimized biogas production. Chemical pretreatment of the shive biomass further increased biogas production efficiency.

  9. Biogas Production from Cow Manure

    Directory of Open Access Journals (Sweden)

    Dewi Artanti Putri

    2012-07-01

    Full Text Available The production of biogas from livestock waste manure in particular is one of the alternative utilization of organic wastes that can be implemented in Indonesia since there is a huge potential of bio-energy in Indonesia. This study utilizes cow manure as the raw material for making biogas and it is coupled with a cow rumen fluid and water. The objective of this study is to determine the effect of manure, rumen, and water composition in biogas production. The research was conducted in anaerobic for 60 days. The composition of manure, water, and the rumen were vary following the variable and ratio; variable A (manure and water; variable B (manure and rumen. The results indicate that the variable A (manure and water with a 1:3 ratio, and the variable B (manure and rumen with a 1:2 ratio produced the highest volume of biogas compared to other ratios. The highest biogas production occurred on average at day 23.

  10. Perancangan dan Implementasi Sistem Monitoring Produksi Biogas pada Biodigester

    Directory of Open Access Journals (Sweden)

    Rocky Alfanz

    2016-03-01

    Full Text Available Biogas is one of the flammable natural gas. The most observed content of biogas in this study is methane (CH4, hydrogen (H2 and carbon dioxide (CO2. Therefore, biogas can be developed and used as an alternative energy. Nowadays, the used of plant biodigester, as the biogas producer, is still in very simple design. So, the system design should be developed to assist the monitoring process of biogas production. In this study, a system is design which can do the data acquisition using MQ4 sensor of methane, MQ8 sensor of hydrogen and MG811 sensor of carbon dioxide also the parameter which influencing to the process of biogas production such as temperature, humidity and pressure. Based on the measurement of methane, it is spotted that the highest point of methane production occured at 10:00 a.m. The details were the temperature 34 °C, humidity 67% RH, and pressure 100,6 kPa which can produce 95.672 ppm of methane. In the measurement of hydrogen, it is figured out that the highet point of hydrogen production occured at 02:00 p.m. The details were the temperature 34 °C, humidity 74% RH, and a pressure of 100,4 kPa to produce 4,738 ppm of hydrogen. Then, the highest point of the measurement of carbon dioxide production occurred at 11:00 a.m. The details were temperature 33 °C, humidity 68% RH, and a pressure of 100,5 kPa to 16,89 ppm of carbon dioxide.

  11. Biogas recovery from microwave heated sludge by anaerobic digestion

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Biogas generated from sewage sludge,livestock waste,and food waste by anaerobic digestion is a valuable renewable energy resource.However,conventional anaerobic digestion is not an efficient process.A long hydraulic retention time and low biogas recovery rate hinder the applications of those resources.An effective pretreatment method to destroy sludge microbial cells has been one of the major concerns regarding improvement of the biogas production.This article focuses on the effects of microwave heating on sludge anaerobic digestion.Volatile suspended solid(VSS) and chemical organic demand solubilization of heated sludge were investigated.Microwave heating was found to be a rapid and efficient process for releasing organic substrates from sludge.The increase of organic dissolution ratio was not obvious when holding time was over 5 min with microwave heating.The effect of the VSS solubilization was primarily dependent on heating temperature.The highest value of VSS dissolving ratio,36.4%,was obtained at 170°C for 30 min.The COD dissolving ratio was about 25% at 170°C.Total organic carbon of treated sludge liquor was 1.98 and 2.73 g/L at 150°C and 170°C for 5 min,respectively.A biochemical methane potential(BMP) test of excess sludge and a mixture of primary and excess sludge demonstrated an increase in biogas production.The total biogas from microwave treated mixture sludge increased by 12.9% to 20.2% over control after 30 days of digestion.Biogas production was 11.1% to 25.9% higher for excess sludge than for untreated sludge.The VS removal ratios of mixture sludge and excess sludge were 12% and 11% higher,respectively,compared to the untreated sludge.

  12. Biogas Digester with Simple Solar Heater

    OpenAIRE

    Kh S Karimov; Muhammad Abid

    2012-01-01

    ABSTRACT: In this research work, the design, fabrication and investigation of a biogas digester with simple solar heater are presented. For the solar heater, a built-in reverse absorber type heater was used. The maximum temperature (50°C) inside the methane tank was taken as a main parameter for the design of the digester. Then, the energy balance equation for the case of a static mass of fluid being heated was used to model the process. The parameters of thermal insulation of the methane tan...

  13. Biogas upgrading by injection of hydrogen in a two-stage Continuous Stirred-Tank Reactor system

    DEFF Research Database (Denmark)

    Bassani, Ilaria; Kougias, Panagiotis; Treu, Laura;

    An innovative method for biogas upgrading (i.e. CH4 content more than 90%) combines the coupling of H2, which could be produced by water electrolysis using surplus renewable electricity produced from wind mills, with the CO2 of the biogas. CO2 is biologically converted to CH4 by hydrogenotrophic...... methanogens. In this study, a novel serial biogas reactor system is presented, in which the produced biogas from the first stage reactor was introduced in the second stage, where also H2 was injected. The effects of the H2 addition on the process performance and on the microbial community were investigated...

  14. Electricity power generation with sewage biogas: a reality; Geracao de eletricidade com biogas de esgoto: uma realidade

    Energy Technology Data Exchange (ETDEWEB)

    Avellar, Luis Henrique Nobre; Coelho, Suani Teixeira [CENBIO - Centro Nacional de Referencia em Biomassa, Sao Paulo, SP (Brazil)]. E-mails: lavellar@amhanet.com.br; suani@iee.usp.br; Alves, Joao Wagner [CETESB- Companhia de Tecnologia e Saneamento Ambiental, Sao Paulo, SP (Brazil)]. E-mail: joaoa@cetesb.sp.gov.br

    2002-12-01

    This paper presents some characteristics and data of technical survey on the sewage material assessment and treatment in Brazil, and also environmental considerations on the anaerobic bio digestion process and energetic aspects related to the electric power generation from the biogas produced in the SABESP sewage treatment stations. This article also reports the goals of the university infra-structure project which is part of the PEREFA - Program for the Energy Rational Using of the university of Sao Paulo, SP, Brazil. One of the project goals is the elaboration of a demonstrative system allowing electric power generation from the biogas resulting from the municipal wastes treatment produced in university campus.

  15. Biogas production from catch crops

    DEFF Research Database (Denmark)

    Molinuevo-Salces, Beatriz; Larsen, Søren U.; Ahring, Birgitte Kiær

    2013-01-01

    Manure-based biogas plants in Denmark are dependent on high yielding biomass feedstock in order to secure economically feasible operation. The aim of this study was to investigate the potential of ten different catch crop species or mixtures as feedstock for biogas production in co......, being in the ranges of 1.4–3.0 t ha−1 and 0.3–1.7 t ha−1 for Holstebro and Aabenraa, respectively. Specific methane yields were in the range of 229–450 m3 t−1 of VS. Methane yields per hectare of up to 800 m3 ha−1 were obtained, making catch crops a promising source of feedstock for manure-based biogas...

  16. Agricultural biogas plants in Spain. State of the art and perspectives; Landwirtschaftliche Biogasanlagen in Spanien. Stand und Perspektiven

    Energy Technology Data Exchange (ETDEWEB)

    Blanco, D.; Escapa, A. [Bioenergia y Desarrollo Tecnologico (BYDT), Leon (Portugal)

    2011-03-15

    The contribution under consideration reports on the state of the art and perspectives of the agricultural biogas plans in Spain. The potential for agricultural biogas results from: (a) 49 million tons of residual substances per year from animal husbandry (biogas potential: 2,400 millions m{sup 3} annually); (b) 27 million tons of residual substances per year from the plant production (biogas potential: 5,000 millions m{sup 3} annually); (c) 3.3 million tons of residual substances per year from meat production (biogas potential: 100 millions m{sup 3} annually); (d) 0.5 million tons of residual substances per year from the fish processing (biogas potential: 43 millions m{sup 3} annually); (e) 3.1 million tons of residual substances per year from the milk-processing industry (biogas potential: 125,5 millions m{sup 3} annually). The author describes examples of project within the range of agricultural biogas plants and the most important legal milestones affecting the development of the biogas utilization.

  17. High-rate hydrogenotrophic methanogenesis for biogas upgrading: the role of anaerobic granules.

    Science.gov (United States)

    Xu, Heng; Gong, Shufen; Sun, Yuanzi; Ma, Hailing; Zheng, Mingyue; Wang, Kaijun

    2015-01-01

    Hydrogenotrophic methanogenesis has been proved to be a feasible biological method for biogas upgrading. To improve its performance, the feasibility of typical anaerobic granules as the inoculum was investigated in both batch and continuous experiments. The results from batch experiments showed that glucose-acclimated granules seemed to perform better than granules acclimated to acidified products (AP, i.e. acetate, propionate and ethanol) in in situ biogas upgrading systems and a slightly higher H2 consumption rate (1.5 mmol H2 g VSS(-1) h(-1)) was obtained for glucose-acclimated granules. For AP-acclimated granules, the inhibition on anaerobic digestion and pH increase (up to 9.55±0.16) took place, and the upgrading performance was adversely affected. In contrast, better performance for AP-acclimated granules was observed in ex situ systems, possibly due to their higher hydrogenotrophic methanogenic activities (HMA). Moreover, when gas-liquid mass transfer limitations were alleviated, the upgrading performance was significantly improved (three-fold) for both glucose-acclimated and AP-acclimated granules. The HMA of anaerobic granules could be further enhanced to improve biogas upgrading performance via continuous cultivation with H2/CO2 as the sole substrate. During the three months' cultivation, secondary granulation and microbial population shift were observed, but anaerobic granules still remained intact and their HMA increased from 0.2 to 0.6 g COD g VSS(-1) d(-1). It indicated that the formation of hydrogenotrophic methanogenic granules, a new type of anaerobic granules specialized for high-rate hydrogenotrophic methanogenesis and biogas upgrading, might be possible. Conclusively, anaerobic granules showed great potential for biogas upgrading.

  18. Heme electron transfer in peroxidases: the propionate e-pathway.

    Science.gov (United States)

    Guallar, Victor

    2008-10-23

    Computational modeling offers a new insight about the electron transfer pathway in heme peroxidases. Available crystal structures have revealed an intriguing arrangement of the heme propionate side chains in heme-heme and heme-substrate complexes. By means of mixed quantum mechanical/molecular mechanics calculations, we study the involvement of these propionate groups into the substrate oxidation in ascorbate peroxidase and into the heme to heme electron transfer in bacterial cytochrome c peroxidase. By selectively turning on/off different quantum regions, we obtain the electron transfer pathway which directly involves the porphyrin ring and the heme propionates. Furthermore, in ascorbate peroxidase the presence of the substrate appears to be crucial for the activation of the electron transfer channel. The results might represent a general motif for electron transfer from/to the heme group and change our view for the propionate side chains as simple electrostatic binding anchors. We name the new mechanism "the propionate e-pathway".

  19. Instrumentation, control and automation for biogas plants - a full-scale example

    Energy Technology Data Exchange (ETDEWEB)

    Wiese, J. [EnerCess GmbH, Bad Oeynhausen (Germany)

    2007-07-01

    Biogas plants win more and more importance, because of numerous ecological advantages. That means, the biogas production cycle is an integrated system of resources utilization, organic waste treatment, nutrient recycling and redistribution, and renewable energy production, which creates numerous energetic, environmental and agricultural benefits. In these plants biogas can be produced by using numerous different input substrates: Farm products: cattle and pork liquid manure, wheat, poultry excrements, maize etc.; Organic waste (primarily from food industries): canteen kitchens, food markets, viniculture, brewery, distillery etc.; Sewage sludge from wastewater treatment plants. The processes in biogas plants are similar to processes, which are well known for many decades in anaerobic wastewater/sludge treatment. But up to now, the level of instrumentation, control and automation (ICA) of full-scale biogas systems is still low. I.e. most plants are black box systems which can be analyzed and/or optimized only difficultly. Consequently, the practice shows that many biogas plants are operated suboptimal. Furthermore, for economic reasons more and more plants are operated in a critical (load) range. I.e. there is a high danger of a plant breakdown, which can cause high financial deficits. This situation is mainly caused by the fact, that most of biogas plants are still rather small plants. E.g., the average electricity production capacity of approx. 2,000 biogas plants in Germany is only approx. 125 kWel. But, as a result of technical progress and permanently rising prices for non-renewable energy, biogas plants become more and more economic reasonable. Furthermore, because of the economies of scale law more and more larger plants are built (250 - 2,000 kWel). In case of larger plants, the costs for ICA are only a small part of the total investment costs (5 - 10 %). On larger plants the operators are also usually full-time workers, which can fully concentrate upon the

  20. Pemurnian Biogas untuk meningkatkan Nilai Kalor melalui Adsorpsi Dua Tahap Susunan Seri dengan Media Karbon Aktif

    Directory of Open Access Journals (Sweden)

    YANTI SUPRIANTI

    2016-08-01

    Full Text Available Abstrak Pemerintah menargetkan peningkatan peran energi terbarukanhingga mencapai 24% pada tahun 2050. Biogas sebagai salah satu dari sumber energi terbarukan harus memiliki nilai kalor yang memadaiagar dapat bersaing dengan sumber energi fosil. Zat yang memiliki kontribusi terbesar dalam menentukan nilai kalor biogas adalah Metana (CH4. Namun, biogas juga memiliki kandungan Karbon dioksida (CO2 yang bersifat tidak terbakar. Upaya untuk meningkatkan nilai kalor biogas dapat ditempuh dengan menurunkan kandungan CO2, salah satunya melalui proses adsorpsi. Penelitian ini menggunakan kolom adsorpsi seri berukuran 2,43 L untuk meningkatkan waktu kontak antara adsorben karbon aktif dengan gas-gas kontaminan. Hasil penelitian menunjukkan bahwa kandungan CO2 dapat ditekan hingga di bawah 14% pada waktu adsorpsi 10 menit,dan diperoleh kandungan CH4 hingga minimal 78,73%. Hasil optimum kinerja kolom adsorpsi seri yaitu pada laju alir 2,4 L/menit dan waktu adsorpsi 10 menit, mampu memurnikan biogas hingga mengandung CH4 91,60%. Pada kondisi optimum tersebut, efektifitas kolom adsorpsi adalah sebesar 98,31%. Kata kunci: biogas, pemurnian, karbon aktif, waktu adsorpsi, efektifitas kolom adsorpsi. Abstract Indonesian government had targettedthe role of renewable energy, up to 24% in 2050. Biogas, as one of renewable energy, should have sufficient calorific valuein order to be efficiently used and competitive compared to fossil fuels. Methane (CH4 in biogas is the most important substance that determine biogas calorific value. On the other hand, another component of biogas, Carbon dioxide (CO2, the one that inhibit combustion process must be reduced. One of the methods to reduce CO2 content can be conducted through adsorption process. This research utilized serial adsorption column to increase contact between activated carbon as adsorbent and contaminant gases. The result showed that CO2 content can be suppressed below 14% in 10 minutes adsorption time, so

  1. Conversion regular patterns of acetic acid,propionic acid and butyric acid in UASB reactor

    Institute of Scientific and Technical Information of China (English)

    LIU Min; REN Nan-qi; CHEN Ying; ZHU Wen-fang; DING Jie

    2004-01-01

    On the basis of continuous tests and batch tests, conversion regular patterns of acetate, propionate and butyrate in activated sludge at different heights of the UASB reactor were conducted. Results indicated that the conversion capacity of the microbial is decided by the substrate characteristic when sole VFA is used as the only substrate. But when mixed substrates are used,the conversion regulations would have changed accordingly. Relationships of different substrates vary according to their locations. In the whole reactor, propionate's conversion is restrained by acetate and butyrate of high concentration. On the top and at the bottom of the reactor, conversion of acetate, but butyrate, is restrained by propionate. And in the midst, acetate's conversion is accelerated by propionate while that of butyrate is restrained. It is proved, based on the analysis of specific conversion rate, that the space distribution of the microbe is the main factor that affects substrates' conversion. The ethanol-type fermentation of the acidogenic-phase is the optimal acid-type fermentation for the two-phase anaerobic process.

  2. Comparative Studies on Methane Upgradation of Biogas by Removing of Contaminant Gases Using Combined Chemical Methods

    Directory of Open Access Journals (Sweden)

    Muhammad Rashed Al Mamun

    2015-07-01

    Full Text Available Biogas, which generated from renewable sources can be used as a sustainable energy to achieve resourceful targets of biofuel for internal combustion engines. This process can be achieved in combined absorption and adsorption chemical way. This method can be employed by aqueous solutions of calcium hydroxide, activated carbon, iron(II chloride, silica gel and sodium sulfate respectively. The presence of CO2, H2S and H2O in the biogas has lowering the calorific value and detrimental corrosion effects on the metal components. Removal of these contaminants from the biogas can therefore significantly improve the gas quality. A comparison study was investigated using combined chemical methods of improving the calorific value of biogas. Experiment results revealed that the aqueous solution used effectively in reacting with CO2 in biogas (over 85-90% removal efficiency, creating CH4 enriched biogas. The removal efficiency was the highest in method 1, where efficiency results were 91.5%, 97.1% and 91.8%, for CO2, H2S, and H2O, respectively. The corresponding CH4 enrichment was 97.5%. These results indicate that the method 1 is more suitable compare to method 2. However, both methane enrichment processes might be useful for cleaning and upgrading methane quality in biogas.

  3. Increasing the biogas yield of manure by wet explosion of the digested fiber fraction

    DEFF Research Database (Denmark)

    Biswas, Rajib; Uellendahl, Hinrich; Ahring, Birgitte Kiær

    Increasing the biodegradability of the lignocellulosic fiber fraction of manure can ensure higher methane productivity in biogas plants, leading to process profitability and thus larger production of renewable energy. A new pretreatment method, wet explosion (WEx), was investigated to treat...

  4. Modelling the Kinetics of Biogas Production from Mesophilic Anaerobic Co-Digestion of Cow Dung with Plantain Peels

    Directory of Open Access Journals (Sweden)

    Ganiyu Kayode Latinwo

    2015-02-01

    Full Text Available This work investigated the effect of plantain peels as co-substrate in the anaerobic digestion of cow dung for efficient and high biogas production. The biogas experiments were carried out in two different 5 L anaerobic digesters and incubated for 40 days at ambient mesophilic temperatures (28 oC to 34 °C. The results showed that co-digestion of cow dung with plantain peels as co-substrate reduced start-up time for biogas generation and increased biogas yield by 18% as compared to cow dung alone. Peak biogas production was obtained for both digesters at pH of 6.7 and 6.9 as well as temperature of 29 and 30oC, respectively. Modelling study revealed that exponential plot simulated better in both ascending and descending limb than the linear plot the biogas production rates in biogas production from cow dung co-digested with plantain peels and cow dung alone, respectively. Logistic growth model and modified Gompertz plot showed better correlation of cumulative biogas production than exponential rise to maximum plot. These results show that biogas production can be enhanced efficiently through co-digestion process.

  5. Economic and technical viability of the biogas generation from vinaceus in an ethanol plant; Viabilidade tecnica, economica, da geracao de biogas a partir de vinhaca em uma usina de etanol

    Energy Technology Data Exchange (ETDEWEB)

    Vianna, Luiz Felipe Peres; Almeida, Silvio Carlos Anibal de [Universidade Federal do Rio de Janeiro (DEM/EP/UFRJ), RJ (Brazil). Escola Politecnica. Dept. de Engenharia Mecanica; Pinto, Marcio Schittini; Pereira, Luiz Felipe Herrmann Telles [Acesa Bioenergia, Rio de Janeiro, RJ (Brazil)], Emails: maschittini@acesabioenergia.com; lfpereira@acesabioenergia.com

    2010-07-01

    This paper analyses the technical viability of use of vinaceus for biogas production. This paper developed by the Mechanical Engineering Department of UFRJ and the ACESA Bioenergy enterprise, analyses the generation and processing of biogas produced from bio digestion of the vinaceus. The chosen place for the study was the Mandu ethanol plant, located at Guaira, Sao Paulo, Brazil.

  6. Biogas generation in anaerobic wastewater treatment under tetracycline antibiotic pressure

    Science.gov (United States)

    Lu, Meiqing; Niu, Xiaojun; Liu, Wei; Zhang, Jun; Wang, Jie; Yang, Jia; Wang, Wenqi; Yang, Zhiquan

    2016-06-01

    The effect of tetracycline (TC) antibiotic on biogas generation in anaerobic wastewater treatment was studied. A lab-scale Anaerobic Baffled Reactor (ABR) with three compartments was used. The reactor was operated with synthetic wastewater in the absence of TC and in the presence of 250 μg/L TC for 90 days, respectively. The removal rate of TC, volatile fatty acids (VFAs), biogas compositions (hydrogen (H2), methane (CH4), carbon dioxide (CO2)), and total biogas production in each compartment were monitored in the two operational conditions. Results showed that the removal rate of TC was 14.97–67.97% in the reactor. The presence of TC had a large negative effect on CH4 and CO2 generation, but appeared to have a positive effect on H2 production and VFAs accumulation. This response indicated that the methanogenesis process was sensitive to TC presence, but the acidogenesis process was insensitive. This suggested that the presence of TC had less influence on the degradation of organic matter but had a strong influence on biogas generation. Additionally, the decrease of CH4 and CO2 generation and the increase of H2 and VFAs accumulation suggest a promising strategy to help alleviate global warming and improve resource recovery in an environmentally friendly approach.

  7. Optimization of biogas production from coffee production waste.

    Science.gov (United States)

    Battista, Federico; Fino, Debora; Mancini, Giuseppe

    2016-01-01

    This study was conducted to investigate the effects of chemical pretreatments on biogas production from coffee waste. After the preparation of a mixture of coffee waste with a TS concentration of 10%w/w, basic and acid pretreatments were conducted in batch mode and their performances were compared with the biogas produced from a mixture without any pretreatment stage. The basic pretreatment demonstrated a very good action on the hydrolysis of the lignin and cellulose, and permitted a biogas production of about 18NL/L with a methane content of almost 80%v/v. Thus, the basic pretreatment has been used to scale-up the process. The coffee refuse was has been carried out in a 45L anaerobic reactor working in continuous mode and in a mesophilic condition (35°C) with a Hydraulic Retention Time (HRT) of about 40days. A high biogas production of 1.14NL/Ld, with a methane percentage of 65%v/v was obtained, thus permitting a process yield of about 83% to be obtained.

  8. Optimization of the methanation process by the implementation of a physical-chemical co-process: application to the biogas resource made by waste water sewage sludges; Optimisation du procede de methanisation par mise en place d'un co-traitement physico-chimique: application au gisement de biogaz represente par les boues d'epuration des eaux usees

    Energy Technology Data Exchange (ETDEWEB)

    Bougrier, C.

    2005-10-15

    This work deals with the coupling of physico-chemical processes with the anaerobic digestion. This coupling aims at reducing the generation of sewage sludges and, at the same time, at improving biogas generation. In a first step, 3 cellular lysis techniques have been applied with the aim of improving the anaerobic digestion efficiency: sonication, ozonization and thermal lysis. For each technique used, the effects of pre-processing have been analyzed in terms of matter solubilization and biogas generation in discontinuous reactors. This has permitted to determine the optimum conditions of operation of each technique. In a second step, these different pre-treatments have been compared on a same sludge in order to determine the most efficient treatment. While thermal treatments lead to the highest solubilization levels, the improvements of biodegradability are of the same order of importance for the 3 techniques. The thermal treatment, with its sanitizing aptitude and the possibility to use biogas for its energy supply, seems to be the most promising. The effects of thermal lysis on the solubilization of the different sludge compounds (glucides, proteins, lipids), on the physical-chemical properties of sludges and on their anaerobic biodegradability in discontinuous and semi-continuous reactors have been studied. All sludges seem to have a similar behaviour with respect to solubilization, decantation and filtration properties with a threshold temperature of 150 deg. C. On the other hand, the impact on biodegradability is more dependent on the nature of the sludge. The most important parameter for the evaluation of the relevance of a thermal pre-processing seems to be the initial sludges biodegradability. (J.S.)

  9. Innovative test method for the estimation of the foaming tendency of substrates for biogas plants

    Energy Technology Data Exchange (ETDEWEB)

    Moeller, Lucie, E-mail: lucie.moeller@ufz.de [UFZ – Helmholtz Centre for Environmental Research, Centre for Environmental Biotechnology, Permoserstrasse 15, 04318 Leipzig (Germany); Eismann, Frank, E-mail: info@antoc.de [Eismann & Stöbe GbR, GeoPark, Geb. A12, Bautzner Strasse 67, 04347 Leipzig (Germany); Wißmann, Daniel, E-mail: d.s.wissmann@gmx.de [University of Hohenheim, State Institute of Agricultural Engineering and Bioenergy (LA740), Garbenstrasse 9, 70599 Stuttgart (Germany); Nägele, Hans-Joachim, E-mail: hajo.naegele@uni-hohenheim.de [University of Hohenheim, State Institute of Agricultural Engineering and Bioenergy (LA740), Garbenstrasse 9, 70599 Stuttgart (Germany); Zielonka, Simon, E-mail: simon.zielonka@uni-hohenheim.de [University of Hohenheim, State Institute of Agricultural Engineering and Bioenergy (LA740), Garbenstrasse 9, 70599 Stuttgart (Germany); Müller, Roland A., E-mail: roland.mueller@ufz.de [UFZ – Helmholtz Centre for Environmental Research, Centre for Environmental Biotechnology, Permoserstrasse 15, 04318 Leipzig (Germany); Zehnsdorf, Andreas, E-mail: andreas.zehnsdorf@ufz.de [UFZ – Helmholtz Centre for Environmental Research, Centre for Environmental Biotechnology, Permoserstrasse 15, 04318 Leipzig (Germany)

    2015-07-15

    Graphical abstract: Display Omitted - Highlights: • Foaming in biogas plants depends on the interactions between substrate and digestate. • Foaming tests enable the evaluation of substrate foaming tendency in biogas plants. • Leipzig foam tester enables foaming tests of substrates prior to use. - Abstract: Excessive foaming in anaerobic digestion occurs at many biogas plants and can cause problems including plugged gas pipes. Unfortunately, the majority of biogas plant operators are unable to identify the causes of foaming in their biogas reactor. The occurrence of foaming is often related to the chemical composition of substrates fed to the reactor. The consistency of the digestate itself is also a crucial part of the foam formation process. Thus, no specific recommendations concerning substrates can be given in order to prevent foam formation in biogas plants. The safest way to avoid foaming is to test the foaming tendency of substrates on-site. A possible solution is offered by an innovative foaming test. With the help of this tool, biogas plant operators can evaluate the foaming disposition of new substrates prior to use in order to adjust the composition of substrate mixes.

  10. Biogas and methane yield in response to co- and separate digestion of biomass wastes.

    Science.gov (United States)

    Adelard, Laetitia; Poulsen, Tjalfe G; Rakotoniaina, Volana

    2015-01-01

    The impact of co-digestion as opposed to separate digestion, on biogas and methane yield (apparent synergetic effects) was investigated for three biomass materials (pig manure, cow manure and food waste) under mesophilic conditions over a 36 day period. In addition to the three biomass materials (digested separately), 13 biomass mixtures (co-digested) were used. Two approaches for modelling biogas and methane yield during co-digestion, based on volatile solids concentration and ultimate gas and methane potentials, were evaluated. The dependency of apparent synergetic effects on digestion time and biomass mixture composition was further assessed using measured cumulative biogas and methane yields and specific biogas and methane generation rates. Results indicated that it is possible, based on known volatile solids concentration and ultimate biogas or methane yields for a set of biomass materials digested separately, to accurately estimate gas yields for biomass mixtures made from these materials using calibrated models. For the biomass materials considered here, modelling indicated that the addition of pig manure is the main cause of synergetic effects. Co-digestion generally resulted in improved ultimate biogas and methane yields compared to separate digestion. Biogas and methane production was furthermore significantly higher early (0-7 days) and to some degree also late (above 20 days) in the digestion process during co-digestion.

  11. CO{sub 2} separation from biogas with ceramic membranes; CO{sub 2}-Abtrennung aus Biogas mit keramischen Membranen

    Energy Technology Data Exchange (ETDEWEB)

    Fassauer, Burkhardt; Richter, Hannes; Schwarz, Bjoern; Reger-Wagner, Norman; Kaemnitz, Susanne [Fraunhofer-Institut fuer Keramische Technologien und Systeme IKTS, Dresden (Germany); Lubenau, Udo; Mothes, Raimund [DBI Gas- und Umwelttechnik GmbH, Leipzig (Germany)

    2015-07-01

    Biogas contains after the production of up to 55% CO{sub 2}. In order to use biogas as a fuel or to feed it into the natural gas network, it must be purified before. Adsorption and scrubbing processes are primarily used technically. Membrane processes offer the advantage of continuous operation and a simple modular and flexible system design, which imply relatively low investment costs and low energy needs. Moreover, membrane systems can be started up and shut down quickly without any problems. Ceramic membranes are characterised by high stability (thermal, chemical, mechanical) and very high flows in comparison to polymeric membranes. [German] Biogas enthaelt nach der Erzeugung bis zu 55 % CO{sub 2}. Um Biogas als Kraftstoff zu nutzen oder in das Erdgasnetz einspeisen zu koennen, muss es zuvor gereinigt werden. Technisch genutzt werden vor allem Adsorptions- und Waschverfahren. Membranverfahren bieten den Vorteil eines kontinuierlichen Betriebes sowie einer einfachen, modularen und flexiblen Anlagenkonzeption, die vergleichsweise niedrige Investitionskosten und einen geringen Energiebedarf bedeuten. Darueber hinaus koennen Membrananlagen schnell an- und abgefahren werden und voellig ohne Probleme abgeschaltet werden. Keramische Membranen zeichnen sich gegenueber Polymermembranen durch hohe Stabilitaet (thermisch, chemisch, mechanisch) und sehr hohe Fluesse aus.

  12. Propionate uptake by rumen microorganisms: the effect of ruminal infusion

    OpenAIRE

    Nozière, P; Gachon, S.; DOREAU, M.

    2003-01-01

    International audience; We assessed the ability of rumen microbes to significantly incorporate propionate when they are subjected in vivo to no infusion, long-term infusion of minerals, and short- and long-term infusion of high amounts of propionate. Four ruminally cannulated sheep fed 1000 g hay (8 meals per d) were used in a $4 \\times 4$ Latin square design. The treatments consisted of no infusion (C), ruminal infusion of propionate (86 g$\\cdot$d$^{-1}$) for 1 (P1) and 7 d (P7), and of mine...

  13. Biogas upgrading - Review of commercial technologies; Biogasuppgradering - Granskning av kommersiella tekniker

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, Fredric; Hulteberg, Christian; Persson, Tobias; Tamm, Daniel

    2013-04-01

    Biogas production is growing and there is an increasing demand for upgraded biogas, to be used as vehicle fuel or injected to the natural gas grid. To enable the efficient use of biogas in these applications the gas must be upgraded, i.e. the carbon dioxide, which constitutes a large part of the raw biogas from the digester, must be separated from the methane. This report aims to evaluate the biogas upgrading technologies that are commercially available and in operation today: amine scrubbers, water scrubbers, PSA units, organic scrubbers and membrane units. The technologies are described in detail by presenting the theory behind the separation mechanism, the upgrading process as a complete system, operational issues and how these are solved, and finally the most important financial data. Furthermore, the best developed cryogenic technologies, which today are being used to purify landfill gas and biogas from some specific components and to liquefy biogas, are presented. Cryogenic upgrading is an interesting possibility, but as this report shows, the technology still has some important operational issues to resolve. Technologies which are especially focused on small-scale applications are finally presented, however not in as much detail as the other, more common technologies. The report shows that for mid-scale applications, the most common options are all viable. The scrubbing technologies all perform well and have similar costs of investment and operation. The simplicity and reliability of the water scrubber has made this the preferred choice in many applications, but the high purity and very low methane slip from amine scrubbers are important characteristics. Regarding PSA and membrane units, the investment cost for these are about the same as for scrubbers. Furthermore, recent developments of the membrane units have also made it possible to reach low methane slips with this technology. Biogas production is increasing, in Sweden and globally, and the interest for

  14. CONVERSION OF ORGANIC MANURE INTO BIOGAS

    Directory of Open Access Journals (Sweden)

    Dario Brdarić

    2009-12-01

    Full Text Available Production of biogas with anaerobic degradation from organic waste is one of the pledge alternative energetic solutions, especially from organic manure made from animal farming and other residuals of agricultural production. According to 2005 livestock manufacture data daily quantity of animal excrements in Croatia, based on LSU number, is 784 015.26 m3. The aim of this paper is to determine the possibility of production of biogas from the most common types of domestic animals in Croatia. Anaerobic fermentation period of 40 days in mesophilic conditions produced from 1 kg of beef, 31 litres of biogas slurry and from pig slurry 14.83 litres of biogas. From our study it follows that the Republic of Croatia (based on the number of UG could produce 426,995,250.00 Nm3 biogas annually. Exploitation of biogas can decrease import of the referred energents, especially electric energy.

  15. Small-scale household biogas digesters

    DEFF Research Database (Denmark)

    Bruun, Sander; Jensen, Lars Stoumann; Khanh Vu, Van Thi

    2014-01-01

    There are a number of advantages to small-scale biogas production on farms, including savings on firewood or fossil fuels and reductions in odour and greenhouse gas emissions. For these reasons, governments and development aid agencies have supported the installation of biogas digesters. However......, biogas digesters are often poorly managed and there is a lack of proper distribution systems for biogas. This results in methane being released inadvertently through leaks in digesters and tubing, and intentionally when production exceeds demand. As methane has a global warming potential 25 times greater......% of the produced biogas is released, depending on the type of fuel that has been replaced. The limited information available as regards methane leaking from small-scale biogas digesters in developing countries indicates that emissions may be as high as 40%. With the best estimates of global numbers of small...

  16. The economics of biogas in Denmark

    DEFF Research Database (Denmark)

    Jacobsen, Brian H.; Laugesen, Frederik Møller; Dubgaard, Alex

    2013-01-01

    Denmark has been one of the leading European Countries in using Biogas for Combined Heat and Power (CHP), since the 1980’ties. However, in the last two decades, the increase has been limited. A new energy policy aimed at increasing the profitability of Biogas was introduced in the spring of 2012....... The analysis here shows that the new agreement will improve the profitability of biogas plants and increase the biogas production although the political ambition of an increase from 4 PJ to 14 PJ by 2020 seems unlikely. The analysis shows that biogas plants can be profitable even if the input is a mix....... Even without an investment subsidy of 30%, the case 2012, is profitable. Financing the biogas plants is a challenge. The interest used of 4.25% requires bank guaranties which in practice can be hard to get. Using a more likely interest of 7-8% reduces the yearly profit to 400.000 €. The socioeconomic...

  17. Biogas upgrading technologies:Energetic analysis and environmental impact assessment

    Institute of Scientific and Technical Information of China (English)

    Yajing Xu; Ying Huang; Bin Wu; Xiangping Zhang; Suojiang Zhang

    2015-01-01

    Biogas upgrading for removing CO2 and other trace components from raw biogas is a necessary step before the biogas to be used as a vehicle fuel or supplied to the natural gas grid. In this work, three technologies for biogas upgrading, i.e., pressured water scrubbing (PWS), monoethanolamine aqueous scrubbing (MAS) and ionic liquid scrubbing (ILS), are studied and assessed in terms of their energy consumption and environmental impacts with the process simulation and green degree method. A non-random-two-liquid and Henry's law property method for a CO2 separation system with ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([bmim][Tf2N]) is established and verified with experimental data. The assessment results indicate that the specific energy consumption of ILS and PWS is almost the same and much less than that of MAS. High purity CO2 product can be obtained by MAS and ILS methods, whereas no pure CO2 is recovered with the PWS. For the environmental aspect, ILS has the highest green degree production value, while MAS and PWS produce serious environmental impacts.

  18. Biogas yield from Sicilian kitchen waste and cheese whey

    Directory of Open Access Journals (Sweden)

    Antonio Comparetti

    2013-09-01

    Full Text Available The aim of this study is to determine the chemical composition of kitchen waste and cheese whey, as well as the biogas yield obtained from the Anaerobic Digestion (AD tests of these two raw materials. Since the separated waste collection is performed in the town of Marineo (Palermo, a sample of kitchen waste, different from food industry one and included in the Organic Fraction of Municipal Solid Waste (OFMSW, was collected from the mass stored at the households of this town. Moreover, a sample of cheese whey was collected in a Sicilian mini dairy plant, where sheep milk is processed. This investigation was carried out inside laboratory digesters of Aleksandras Stulginskis University (Lithuania. Total Solids (TS resulted 15.6% in kitchen waste and 6% in cheese whey, while both the raw materials showed a high content of organic matter, 91.1% and 79.1%, respectively. The biogas yield resulted 104.6 l kg–1 from kitchen waste and 30.6 l kg–1 from cheese whey. The biogas yield from TS resulted 672.6 l kg–1 using kitchen waste and 384.7 l kg–1 using cheese whey. The biogas yield from Volatile Solids (VS resulted 738.9 l kg–1 using kitchen waste and 410.3 l kg–1 using cheese whey.

  19. Comparison of biogas production from wild and cultivated varieties of reed canary grass.

    Science.gov (United States)

    Oleszek, Marta; Król, Aleksandra; Tys, Jerzy; Matyka, Mariusz; Kulik, Mariusz

    2014-03-01

    The chemical composition and efficiency of biogas production in the methane fermentation process of silages of wild and cultivated varieties of reed canary grass were compared. An attempt was made to answer the question on how the habitat and the way of utilization of plants affect chemical composition and biogas yield. Physicochemical properties such as dry matter, organic dry matter, protein, fat, crude fiber fraction, macro- and microelements content were considered. The anaerobic digestion process and FTIR analysis were also carried out. The results showed that the two varieties differ essentially in their physical and chemical properties. The cultivated variety was characterized by higher biogas yield (406Ndm(3)kg(-1) VS) than the wild one (120Ndm(3)kg(-1) VS). This was probably related to the chemical composition of plants, especially the high content of indigestible crude fiber fractions and ash. These components could reduce biogas quantity and quality.

  20. Biogas infrastructures from farm to regional scale, prospects of biogas transport grids

    NARCIS (Netherlands)

    Hengeveld, E.J.; Bekkering, J.; Gemert, W.J.T. van; Broekhuis, A.A.

    2016-01-01

    The volume of biogas produced in agricultural areas is expected to increase in coming years. An increasing number of local and regional initiatives show a growing interest in decentralized energy production, wherein biogas can play a role. Biogas transport from production sites to user, i.e. a CHP,

  1. System for obtaining biogas. System zur Gewinnung von Biogas

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    1985-01-17

    The invention refers to a system for obtaining biogas from organic substances in at least one drum reactor, which is situated in a container accepting a liquid and which is driven so that it rotates preferably around its horizontal drum axis. It is distinguished by the fact that for at least one drum reactor acting as the main reactor there is at least one further reactor ahead of it for the pre-treatment or pre-fermentation of the substances.

  2. Counteracting foaming caused by lipids or proteins in biogas reactors using rapeseed oil or oleic acid as antifoaming agents

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Boe, Kanokwan; Einarsdottir, E. S.;

    2015-01-01

    Foaming is one of the major operational problems in biogas plants, and dealing with foaming incidents is still based on empirical practices. Various types of antifoams are used arbitrarily to combat foaming in biogas plants, but without any scientific support this action can lead to serious...... deterioration of the methanogenic process. Many commercial antifoams are derivatives of fatty acids or oils. However, it is well known that lipids can induce foaming in manure based biogas plants. This study aimed to elucidate the effect of rapeseed oil and oleic acid on foam reduction and process performance...... in biogas reactors fed with protein or lipid rich substrates. The results showed that both antifoams efficiently suppressed foaming. Moreover rapeseed oil resulted in stimulation of the biogas production. Finally, it was reckoned that the chemical structure of lipids, and more specifically their carboxylic...

  3. Biogas in Romanian Agriculture, Present and Perspectives

    Directory of Open Access Journals (Sweden)

    Teodor Vintila

    2011-05-01

    Full Text Available In this work we have made a review of data available concerning the potential and technologies available to be applied in Romania to produce biogas in agricultural sector. Biogas application is especially interesting for medium and large farms, concentrated on specific surfaces, where a proper substrate collection can be organized. Reviewing data presenting the theoretical potential for livestock manure in Romania, we found that over 17 mil. MWh of energy from biogas can be provided in one year. It is estimated that only half of the theoretical energy potential is technically usable by biogas investments. As for the crops residues, has been shown that the theoretical biogas potential is 76,7 mil. MWh/year. However, there is a long way to be done in Romania to reach this potential, as in the present, the entire production of biogas is from industrial and municipal landfill and slurries - there are no operational on-farm biogas plants. Despite the high potential in terms of biogas production from agricultural sources, Romania has among the lowest biogas production in Europe. Although currently there are several biogas plants (not in agricultural sector totaling an installed capacity of only 4 MW, and producing in 2010 only 19 GWh electric power, the target for 2020 in Romania is 195 MWel. installed power, with an output of 950 GW electric power. The main cause of the actual situation is the lack of economic incentives similar to those offered by countries as Germany. Without a review of relevant legislation, the progress of the biogas sector in Romania will be limited. Furthermore, the development of low-cost technologies available to Romanian farmers will contribute to the development of production of renewable energy from biogas and other biofuels.

  4. Biogas potential atlas. Potential for the sustainable generation of biogas in Germany; Biogaspotenzialatlas. Potenzial zur nachhaltigen Erzeugung von Biogas in Deutschland

    Energy Technology Data Exchange (ETDEWEB)

    Erler, Ronny [DBI - Gastechnologisches Institut gGmbH, Freiberg (Germany); Krause, Hartmut

    2012-10-15

    Biogas can be produced from various agricultural, municipal or industrial accruing substrates. Different biogas potentials result depending on the substrate. As part of a research project, different potentials are recorded in a biogas potential atlas. This atlas can ultimately be helpful in selecting appropriate biogas plant locations.

  5. 城市沼渣堆肥工艺及其施肥技术的优化%Studies on Composting Process of Municipal Biogas Residues and Optimization of Fertilizer Practice

    Institute of Scientific and Technical Information of China (English)

    许文江; 章明清; 洪翠云; 李夏兰

    2016-01-01

    To study how to shorten the composting time and enhance the composting efficiency and fertilizer practice of municipal biogas residues,fertilizer test of soybean planting was carried out on aerobic composting process to advance pi-lot test of material ratio by two-step method.The results showed that adding mushroom soils,rice husk and sawdust as conditioners could improve the composting efficiency.Compare with the control group,the temperature increased by 8, 5,3 ℃ ,the water ratio of product decreased by 45%,38%,34%,the seed germination index increased by 10%,8%, 7%,and the particle size reduced by 54%,34%,20% respectively in the initial 24 h.The output of green soybean in-creased by 9 .4% than the control group when using biogas residues as organic fertilizer,and the concentrations of nitrate nitrogen and total phosphorus in soil percolating water decreased by 13.4%and 21.6% respectively.It can be clearly seen that fertilizing biogas residues as organic fertilizer is beneficial to increasing the yield of green soybean and reducing the loss of nitrogen and phosphorus in the vegetable fields.%为探讨缩短城市沼渣堆肥时间,提高堆肥效率和沼渣施肥技术,采用二步法对好氧堆肥工艺进行物料配比中试试验,开展毛豆种植的沼渣施肥试验.研究结果表明:调理剂菇土、稻壳、木屑可以促进堆肥效率;堆体初期24 h,它们比对照组的温度分别提高8,5,3℃,产品水的质量分数分别减少45%,38%,14%,种子发芽率指数分别提高10%,8%,7%,产品粒度分别减少54%,34%,20%;毛豆种植配施沼渣有机肥与对照施肥比较,产量增加9.4%,土壤渗漏水硝态氮、总磷质量浓度分别减少13.4%,21.6%,配施沼渣有机肥有利于毛豆增产和降低菜田氮磷淋失.

  6. Two-Stage Conversion of Land and Marine Biomass for Biogas and Biohydrogen Production

    OpenAIRE

    Nkemka, Valentine

    2012-01-01

    The replacement of fossil fuels by renewable fuels such as biogas and biohydrogen will require efficient and economically competitive process technologies together with new kinds of biomass. A two-stage system for biogas production has several advantages over the widely used one-stage continuous stirred tank reactor (CSTR). However, it has not yet been widely implemented on a large scale. Biohydrogen can be produced in the anaerobic two-stage system. It is considered to be a useful fuel for t...

  7. Ex-situ biogas upgrading and enhancement in different reactor systems

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Treu, Laura; Benavente, Daniela Peñailillo;

    2017-01-01

    Biogas upgrading is envisioned as a key process for clean energy production. The current study evaluates the efficiency of different reactor configurations for ex-situ biogas upgrading and enhancement, in which externally provided hydrogen and carbon dioxide were biologically converted to methane...... and Methanoculleus genera. Methanothermobacter thermautotrophicus was the predominant methanogen in the biofilm formed on top of the diffuser surface in the bubble column reactor....

  8. Distributed power generation using biogas fuelled microturbines

    Energy Technology Data Exchange (ETDEWEB)

    Pointon, K.; Langan, M.

    2002-07-01

    This research sought to analyse the market for small scale biogas fuelled distributed power generation, to demonstrate the concept of a biogas fuelled microturbine using the Capstone microturbine in conjunction with an anaerobic digester, and undertake a technico-economic evaluation of the biogas fuelled microturbine concept. Details are given of the experimental trials using continuous and batch digesters, and feedstocks ranging from cow and pig slurries to vegetable wastes and municipal solid waste. The yields of methane are discussed along with the successful operation of the microturbine with biogas fuels, and anaerobic digestion projects.

  9. Life cycle assessment of biogas upgrading technologies.

    Science.gov (United States)

    Starr, Katherine; Gabarrell, Xavier; Villalba, Gara; Talens, Laura; Lombardi, Lidia

    2012-05-01

    This article evaluates the life cycle assessment (LCA) of three biogas upgrading technologies. An in-depth study and evaluation was conducted on high pressure water scrubbing (HPWS), as well as alkaline with regeneration (AwR) and bottom ash upgrading (BABIU), which additionally offer carbon storage. AwR and BABIU are two novel technologies that utilize waste from municipal solid waste incinerators - namely bottom ash (BA) and air pollution control residues (APC) - and are able to store CO(2) from biogas through accelerated carbonation processes. These are compared to high pressure water scrubbing (HPWS) which is a widely used technology in Europe. The AwR uses an alkaline solution to remove the CO(2) and then the solution - rich in carbonate and bicarbonate ions - is regenerated through carbonation of APC. The BABIU process directly exposes the gas to the BA to remove and immediately store the CO(2), again by carbonation. It was determined that the AwR process had an 84% higher impact in all LCA categories largely due to the energy intensive production of the alkaline reactants. The BABIU process had the lowest impact in most categories even when compared to five other CO(2) capture technologies on the market. AwR and BABIU have a particularly low impact in the global warming potential category as a result of the immediate storage of the CO(2). For AwR, it was determined that using NaOH instead of KOH improves its environmental performance by 34%. For the BABIU process the use of renewable energies would improve its impact since accounts for 55% of the impact.

  10. Significant utilization of heat from biogas; Waerme aus Biogas sinnvoll nutzen

    Energy Technology Data Exchange (ETDEWEB)

    Schulz, W. [Bremer Energie-Institut, Bremen (Germany)

    2008-03-15

    Agricultural biogas facilities often are developed at remote locations. The sales potentials for the heat produced thereby are insufficient. Under this aspect, the author of the contribution under consideration reports on options for the improvement of the utilization of the available heat. The author describes the requirement profile for these options of utilization. Subsequently, ten options for utilization of heat as well as the appropriate details of application are described. In particular the following options of utilization are specified: drying plants, heating of hothouses, aquacultures, transport of latent heat, refrigeration, thermal processing of remainders of fermentation, supply of heat for laundries, production of fruit juice and vegetable juice, refinement of milk.

  11. Chronic kidney disease in an adult with propionic acidemia.

    Science.gov (United States)

    Vernon, H J; Bagnasco, S; Hamosh, A; Sperati, C J

    2014-01-01

    We report an adult male with classic propionic acidemia (PA) who developed chronic kidney disease in the third decade of his life. This diagnosis was recognized by an increasing serum creatinine and confirmed by reduced glomerular filtration on a (99m)Tc-diethylenetriamine pentaacetate (DTPA) scan. Histopathology of the kidney showed moderate glomerulo- and tubulointerstitial fibrosis with very segmental mesangial IgA deposits. This is the second reported case of kidney disease in an individual with propionic acidemia possibly indicating that chronic kidney disease may be a late-stage complication of propionic acidemia. Additionally, this is the first description of the histopathology of kidney disease in an individual with propionic acidemia. As more cases emerge, the clinical course and spectrum of renal pathology in this disorder will be better defined.

  12. Enhancement of Esterification of Propionic Acid with Isopropyl Alcohol by Pervaporation Reactor

    Directory of Open Access Journals (Sweden)

    Ajit P. Rathod

    2014-01-01

    Full Text Available With increasing cost of raw materials and energy, there is an increasing inclination of chemical process industries toward new processes that result in lesser waste generation, greater efficiency, and substantial yield of the desired products. Esterification is a chemical reaction in which two reactants carboxylic acid and alcohol react to form an ester and water. This reaction is a reversible reaction and the equilibrium conversion can be altered by varying the process parameters. Pervaporation reactor can enhance the conversion by shifting the equilibrium of reversible esterification reactions. Polyvinyl alcohol-polyether sulfone composite hydrophilic membrane was used for pervaporation-assisted esterification of propionic acid with isopropyl alcohol. The experiments were carried out in the presence of sulphuric acid as a catalyst at 50°C to 80°C with various reactants ratios. The esterification was carried out for catalyst loadings of 0.089 kmol/m3 to 0.447 kmol/m3. The molar ratios of isopropyl to propionic acid used for the experiment were 1 to 1.5. Maximum conversion was obtained for the ratio of 1.4. Also effect of other parameters such as process temperature and catalyst concentration was discussed. It was found that the use of pervaporation reactor increased the conversion of the propionic acid considerably.

  13. Enhanced biogas production from rice straw with various pretreatment : a review

    Directory of Open Access Journals (Sweden)

    Fahriya Puspita Sari

    2014-04-01

    Full Text Available Rice straw is one of organic material that can be used for sustainable production of bioenergy and biofuels such as biogas (about 50-75% CH4 and 25-50% CO2. Out of all bioconversion technologies for biogas production, anaerobic digestion (AD is a most cost-effective bioconversion technology that has been implemented worldwide for commercial production of electricity, heat, and compressed natural gas (CNG from organic materials. However, the utilization of rice straw for biogas production via anaerobic digestion has not been widely adopted because the complicated structure of the plant cell wall makes it resistant to microbial attack. Pretreatment of recalcitrant rice straw is essential to achieve high biogas yield in the AD process. A number of different pretreatment techniques involving using physical pretreatment (hydrothermal and freeze, chemical pretreatment (sodium carbonate – sodium sulfite, hydrogen peroxide, NMMO, alkaline, and dilute acid and biological pretreatment (fungal pretreatment also combined pretretment (microwave irradiation and chemical approaches have been investigated, but there is no report that systematically compares the performance of these pretreatment methods for application on rice straw for biogas production. This paper reviews the methods that have been studied for pretreatment of rice straw for delignification, reducing sugar, and conversion to biogas. It describes the AD process, structural and compositional properties of rice straw, and various pretreatment techniques, including the pretreatment process, parameters, performance, and advantages vs. drawbacks.

  14. Small-scale upgrading and refinement of biogas; Smaaskalig uppgradering och foeraedling av biogas

    Energy Technology Data Exchange (ETDEWEB)

    Blom, Helena; Mccann, Michael; Westman, Johan (Poeyry SwedPower AB, Stockholm (Sweden))

    2012-02-15

    Small-scale upgrading and refinement of biogas is a report which aims to compile the state of knowledge in small-scale biogas upgrading. The project have been a collaboration with Agrovaest and Energy Farm and was funded by the Foundation for Agricultural Research, Western Goetaland and the Agriculture Department. The technology available for small scale upgrade has been examined from the technical and economic standpoint. An economic comparison has been made and the production of upgraded biogas has been estimated for different raw gas flows. The work also contains information related to biogas production, upgrading and a comparison of liquid biogas, DME and Ecopar-diesel

  15. Observation of temperature and pH during biogas production from water hyacinth and cow manure

    Directory of Open Access Journals (Sweden)

    Nurfitri Astuti

    2013-11-01

    Full Text Available Biogas is generated from biological process of organic material by bacterial engaged. Biogas can be derived from manure, municipal waste, agricultural waste and other biomass resources. In addition to the use of cow manure as raw material for biogas production, it can also be derived from biomass containing cellulose which one is water hyacinth as an organic material that contains quite large cellulose. The abundance of water hyacinth found in Rawapening causing several negative impacts. The purpose of this study is to observe  temperature and pH on the biogas production generated from water hyacinth of Rawapening and cow manure. Biogas production process begins by chopping the leaves and stems of water hyacinth, and then mixed with cow manure and water. The results of substrate variation of water hyacinth, cow manure and water reaches optimally at 40:80:480 respectively, which produce the highest point of  biogas amounted 176.33 ml on the day 20 in 1L sized digester, the temperature of the biogas production is at 32°C.  At the initial fermentation, digester temperature of 30°C has increased over the course of the fermentation process, a peak at day 20 and then decreased to 27°C at the end of fermentation. There is a decrease in pH starting from initial fermentation at pH 6-7 and then the pH began to decline until the end of fermentation as amount of pH 5.Doi: http://dx.doi.org/10.12777/wastech.1.1.22-25Citation:  Nurfitri Astuti, N., Tri Retnaningsih Soeprobowati, T.R., and  Budiyono. 2013. Observation of temperature and pH during biogas production from water hyacinth and cow manure. Waste Technology 1(1:1-5. Doi: http://dx.doi.org/10.12777/wastech.1.1.22-25

  16. Fundamental Insights into Propionate Oxidation in Microbial Electrolysis Cells Using a Combination of Electrochemical, Molecular biology and Electron Balance Approaches

    KAUST Repository

    Rao, Hari Ananda

    2016-11-01

    Increasing demand for freshwater and energy is pushing towards the development of alternative technologies that are sustainable. One of the realistic solutions to address this is utilization of the renewable resources like wastewater. Conventional wastewater treatment processes can be highly energy demanding and can fails to recover the full potential of useful resources such as energy in the wastewater. As a consequence, there is an urgent necessity for sustainable wastewater treatment technologies that could harness such resources present in wastewaters. Advanced treatment process based on microbial electrochemical technologies (METs) such as microbial fuel cells (MFCs) and microbial electrolysis cells (MECs) have a great potential for the resources recovery through a sustainable wastewater treatment process. METs rely on the abilities of microorganisms that are capable of transferring electrons extracellularly by oxidizing the organic matter in the wastewater and producing electrical current for electricity generation (MFC) or H2 and CH4 production (MEC). Propionate is an important volatile fatty acid (VFA) (24-70%) in some wastewaters and accumulation of this VFA can cause a process failure in a conventional anaerobic digestion (AD) system. To address this issue, MECs were explored as a novel, alternative wastewater treatment technology, with a focus on a better understanding of propionate oxidation in the anode of MECs. Having such knowledge could help in the development of more robust and efficient wastewater treatment systems to recover energy and produce high quality effluents. Several studies were conducted to: 1) determine the paths of electron flow in the anode of propionate fed MECs low (4.5 mM) and high (36 mM) propionate concentrations; 2) examine the effect of different set anode potentials on the electrochemical performance, propionate degradation, electron fluxes, and microbial community structure in MECs fed propionate; and 3) examine the temporal

  17. Augmented biogas production from protein-rich substrates and associated metagenomic changes.

    Science.gov (United States)

    Kovács, Etelka; Wirth, Roland; Maróti, Gergely; Bagi, Zoltán; Nagy, Katalin; Minárovits, János; Rákhely, Gábor; Kovács, Kornél L

    2015-02-01

    This study demonstrates that appropriate adaptation of the microbial community to protein-rich biomass can lead to sustainable biogas production. The process of acclimation to these unusual mono-substrates was controlled by the protease activity of the microbial community. Meat extract (C/N=3.32) and kitchen waste (C/N=12.43) were used as biogas substrates. Metagenome analysis highlighted several mesophilic strains that displayed a preference for protein degradation. Bacillus coagulans, Bacillus subtilis and Pseudomonas fluorescens were chosen for detailed investigation. Pure cultures were added to biogas reactors fed solely with protein-rich substrates. The bioaugmentation resulted in a 50% increase in CH4 production even without any acclimation. The survival and biological activity of the added bacteria were followed in fed-batch fermenters by qPCR. Stable biogas production was observed for an extended period of time in laboratory CSTR reactors fed with biomass of low C/N.

  18. Biogas production improvement and C/N control by natural clinoptilolite addition into anaerobic co-digestion of Phragmites australis, feces and kitchen waste.

    Science.gov (United States)

    Wang, Xiaowei; Zhang, Lieyu; Xi, Beidou; Sun, Wenjun; Xia, Xunfeng; Zhu, Chaowei; He, Xiaosong; Li, Mingxiao; Yang, Tianxue; Wang, Pengfei; Zhang, Zhonglei

    2015-03-01

    Anaerobic co-digestion (A co-D) performance of Phragmites australis, feces and kitchen waste with addition of clinoptilolite (one main kind of zeolite) was investigated to evaluate the improvement of biogas/methane production and internal mechanism of nitrogen and organics control. A better biogas/methane production was observed by 10% clinoptilolite (v/v) than bentonite and diatomite, with the shortest lag phase of 0.070d(-1), the max rate of 15.89L/(kgVSday) and ultimate biogas production of 308.2L/kgVS as the modified Gompertz equation predicted. Accordingly, the content of methane in the biogas was increased from 44.10% to 65.30%. Furthermore, the clinoptilolite inhibited the acidification of digestion liquid (optimum pH 7.0-7.5) and enhanced the VFAs (acetic acid, propionic acid and butyric acid) destruction. Moreover, 10% of clinoptilolite optimally enhanced the microbial utilization of Ca(2+)/Mg(2+), controlled the C/N ratio, and improved the biogas production as well as NH3-N/NO3-N inhibition efficiency.

  19. Establishment of a biogas grid and interaction between a biogas grid and a natural gas grid

    Energy Technology Data Exchange (ETDEWEB)

    Kvist, T.

    2011-01-15

    The project has aimed to clarify the advantages and disadvantages of a large biogas net in Ringkoebing Skjern municipality in Denmark, which wants to become self-sufficient in renewable energy by 2020. It is estimated that the biogas potential in the municipality is about. 60 mill. m3 methane gas a year. Half of the methane will be generated by digesting 80 % of the area's slurry, while the other half will be produced from energy crops. It will require an area equivalent to 5 % of the municipality's farmland. The idea is to establish decentralized 60-80 and 1-3 large centralized biogas plants, and that the produced biogas is distributed to natural gas-fired decentralized power plants. Based on this framework, a number of issues for the establishment of a biogas net have been investigated. These are: - the relation between biogas production and demand; - biogas compared to the overall energy system, - purification and measurement of biogas; - conversion of natural gas-fired power plants to biogas; - the value of biogas for cogeneration plants; - design of a biogas distribution net; - ownership and accountability; - potential business models. (LN)

  20. Biogas and bioethanol production in organic farming

    Energy Technology Data Exchange (ETDEWEB)

    Oleskowicz-Popiel, P.

    2010-08-15

    The consumer demand for environmentally friendly, chemical free and healthy products, as well as concern regarding industrial agriculture's effect on the environment has led to a significant growth of organic farming. On the other hand, organic farmers are becoming interested in direct on-farm energy production which would lead them to independency from fossil fuels and decrease the greenhouse gas emissions from the farm. In the presented work, the idea of biogas and bioenergy production at the organic farm is investigated. This thesis is devoted to evaluate such a possibility, starting from the characterization of raw materials, through optimizing new processes and solutions and finally evaluating the whole on-farm biorefinery concept with the help of a simulation software. (LN)

  1. Biogas production from solid pineapple waste

    Energy Technology Data Exchange (ETDEWEB)

    Tanticharoen, M.; Bhumiratana, S.; Tientanacom, S.; Pengsobha, L.

    1984-01-01

    Solid pineapple waste composed of shell and core was used as substrate in anaerobic fermentation producing CH4. The experiments were carried out using four 30-L vessels and no mixing, a 200-L plug-flow reactor, and a 5-cubic m stirred tank. Because of high acidity of the substrate, the loading rate is as low as 2.5 g dry solid added/L-day. The average gas yield is 0.3-0.5 L/g dry substrate. A pretreatment of wet solid with sludge effluent prior loading to the digester resulted in better stability of the biodigester than without pretreatment. These studies showed that loading rate can be much higher than those previously used. The 2-stage process was tested to determine a conversion efficiency of high loading and at much shorter reactor retention times. The results of the entire program indicated that biogas production from cannery pineapple waste is technically feasible.

  2. Forecasting the potential of Danish biogas production

    DEFF Research Database (Denmark)

    Bojesen, Mikkel; Skov-Petersen, Hans; Gylling, Morten

    , except for those farms which are in the largest state class. Regional differences in development trends were documented. The strategic objective of the model is to provide data for the spatial assessment of the potential of biogas production which can form the basis for a location analysis for future...... biogas plants....

  3. Biogas i økologisk jordbrug

    DEFF Research Database (Denmark)

    Østergård, Hanne

    2011-01-01

    Klumme: Hvilke faktorer har størst betydning for udbredelse af biogas-teknologien? Offentlige tilskud er svaret fra en rundspørge.......Klumme: Hvilke faktorer har størst betydning for udbredelse af biogas-teknologien? Offentlige tilskud er svaret fra en rundspørge....

  4. The economics of biogas in Denmark

    DEFF Research Database (Denmark)

    Jacobsen, Brian H.; Laugesen, Frederik Møller; Dubgaard, Alex

    2013-01-01

    Denmark has been one of the leading European Countries in using Biogas for Combined Heat and Power (CHP), since the 1980’ties. However, in the last two decades, the increase has been limited. A new energy policy aimed at increasing the profitability of Biogas was introduced in the spring of 2012....

  5. Cavitation for improved sludge conversion into biogas

    NARCIS (Netherlands)

    Stoop, A.H.; Bakker, T.W.; Kramer, H.J.M.

    2015-01-01

    In several studies the beneficial influence of pre-treatment of waste activated sludge with cavitation on the biogas production was demonstrated. It is however, still not fully certain whether this effect should be mainly contributed to an increase in conversion rate of organics into biogas by anaer

  6. Acetate and propionate in landfill leachates: Implications for the recognition of microbiological influences on the composition of waters in sedimentary systems

    Science.gov (United States)

    Manning, D. A. C.

    1997-03-01

    Routine monitoring of landfill leachates provides information concerning aqueous systems in which anaerobic microbiological processes influence water chemistry. Propionate and acetate are substrate and product, respectively, of metabolism by bacteria that have an obligate syntrophic relationship with sulfate-reducing bacteria. The stoichiometry of the bacteriological metabolic reactions indicates a 1:1 molar proportionality for acetate and propionate. This is observed for landfill leachates, consistent with the known biological control on their organic acid anion contents. Similar data for oil-field waters show the same 1:1 molar proportionality for reservoirs where bacterial sulfate reduction is known to take place, at temperatures up to about 95 °C, in contrast to the 3:2 proportionality (acetic acid:propionic acid) observed in higher temperature systems. These observations suggest that 1:1 molar proportionality for acetate and propionate may be characteristic of natural systems where anaerobic bacterial activity occurs, including bacterial sulfate reduction.

  7. Least cost energy planning in Thailand:A case of biogas upgrading in palm oil industry

    Directory of Open Access Journals (Sweden)

    Artite Pattanapongchai

    2011-12-01

    Full Text Available Thailand is currently the world’s fourth largest producer of crude palm oil. The palm oil mill effluent is proposed to beused for biogas production. A value added option is then proposed by increasing thermal efficiency of the biogas by removingCO2 content and increasing the percentage of methane, consequently turning the biogas in to green gas. In this study, thebiogas and upgrading process for electricity generation with the subsidy or adder in the long term planning is presented. Thisanalysis uses the MARKAL-based least-cost energy system as an analytical tool. The objective of this study is to investigateupgrading biogas with a selected water scrubbing technique featuring least-cost energy planning. The co-benefit aspect ofbiogas and biogas upgrading project is analyzed by given an adder of 0.3 Baht/kWh. The target of total electricity generationfrom biogas is 60 MW in 2012. The result shows that green gas will account for approximately 44.91 million m3 in 2012 andincrease to 238.89 million m3 in 2030. The cumulative CO2 emission during 2012-2030 is 2,354.92 thousand tonnes of CO2.Results show that under the given adders the upgrading project is competitive with the conventional technologies in electricitygeneration planning.

  8. Alkaline pretreatment for enhancement of biogas production from banana stem and swine manure by anaerobic codigestion.

    Science.gov (United States)

    Zhang, Chengming; Li, Jihong; Liu, Chen; Liu, Xiaoling; Wang, Jianlong; Li, Shizhong; Fan, Guifang; Zhang, Lei

    2013-12-01

    The objective of this research was to propose and investigate the availability of digested banana stem (BS) to produce biogas. Squeezed BS with less moisture content was used for biogas production through a combination of NaOH pretreatment, solid-state fermentation, and codigestion technologies. NaOH doses were optimized according to biogas fermentation performance, and the best dose was 6% (by weight) based on the total solid (TS) of BS. Under this condition, the lignin, cellulose, and hemicellulose contents decreased from 18.36%, 32.36% and 14.6% to 17.10%, 30.07%, and 10.65%, respectively, after pretreatment. After biogas digestion, TS and volatile solid (VS) reductions of the codigestion were 48.5% and 70.4%, respectively, and the biogas and methane yields based on VS loading were 357.9 and 232.4 mL/g, which were 12.1% and 21.4%, respectively, higher than the control. Results indicated that the proposed process could be an effective method for using BS to produce biogas.

  9. Enhancement of biogas production from swine manure by a lignocellulolytic microbial consortium.

    Science.gov (United States)

    Tuesorn, Suchada; Wongwilaiwalin, Sarunyou; Champreda, Verawat; Leethochawalit, Malinee; Nopharatana, Annop; Techkarnjanaruk, Somkiet; Chaiprasert, Pawinee

    2013-09-01

    Anaerobic digestion of lignocellulosic wastes is limited by inefficient hydrolysis of recalcitrant substrates, leading to low biogas yield. In this study, the potential of a lignocellulolytic microbial consortium (LMC) for enhancing biogas production from fibre-rich swine manure (SM) was assessed. Biochemical methane potential assay showed that inoculation of structurally stable LMC to anaerobic digestion led to increase biogas production under mesophilic and thermophilic conditions. The greatest enhancement was observed at 37°C with a LMC/SM ratio of 1.5:1 mg VSS/g VS leading to biogas and methane yields of 355 and 180 ml/g VS(added) respectively, equivalent to 40% and 55% increases compared with the control. The LMC was shown to increase the efficiency of total solid, chemical oxygen demand removal and degradation of cellulose and hemicelluloses (1.87 and 1.65-fold, respectively). The LMC-supplemented process was stable over a 90 d biogas production period. This work demonstrates the potential of LMC for enhancing biogas from lignocellulosic wastes.

  10. Biogas and mineral fertiliser production from plant residues of phytoremediation

    Energy Technology Data Exchange (ETDEWEB)

    Chu, Thi Thu Ha

    2011-07-01

    The former uranium mining site in Ronneburg, Thuringia, Germany was known as a big source of uranium with more than 113,000 tons of uranium mined from 1946 to 1990. This area has been remediated since the nineties of the last century. However, nowadays the site in Ronneburg is still specially considered because of the heterogeneous contamination by many heavy metals and the vegetation can be affected. Three plant species including Indian mustard - Brassica juncea L., triticale - x. Triticosecale Wittmaek and sunflower - Helianthus annuus L. were seeded as accumulators of heavy metals and radionuclides in the phytoremediation process in 2009 and 2010 in Ronneburg. The subsequent utilization of the plant residues after phytoremediation is of special consideration. Batch fermentation of harvested plant materials under the mesophilic condition showed that all of the investigated plant materials had much higher biogas production than liquid cow manure except triticale root, of which biogas yield per volatile solid was not significantly higher than the one of sludge. The highest biogas yields (311 L{sub N}/kg FM and 807 L{sub N}/kg VS) were achieved from the spica of triticale after 42 days of retention of anaerobic digestion. Triticale shoot residues generated higher biogas and methane yields than the previously reported triticale materials that were harvested from the uncontaminated soil Triticale was considered as the highest potential species in biogas production, beside the best growth ability on the acidic soil at the test field site with highest biomass production. Biogas yield of Indian mustard shoot was also high but dramatically varied from 2009 to 2010. Digestates after anaerobic digestion of plant residues contained various macronutrients such as nitrogen, potassium, phosphorus and sulphur, and various micronutrients such as iron, manganes, zinc, etc. The accumulation levels of heavy metals in the investigated plant materials were not the hindrance factors

  11. CO2 balance in production of energy based on biogas

    DEFF Research Database (Denmark)

    Nielsen, Per Sieverts; Holm-Nielsen, J.B.

    1997-01-01

    Biogas is an essential biomass source for achieving a reduction of CO2 emission by 50% in year 2030 in Denmark. The physical potential for biogas production in Denmark is more than 10 times the present biogas production in Denmark. In Denmark the largest part of the biogas production is produced...... of increased transportation distances at large biogas plants on the total CO2 balance of the biogas plant. The advantage of constructing large biogas plants is the cost-effective possibility of using industrial organic waste to increase biogas production. In some cases co-fermentation increases biogas...... production up 100%. The present study evaluate optimal transportation strategies for biogas plants taking CO2 balances into account....

  12. Precipitation of fluticasone propionate microparticles using supercritical antisolvent

    Directory of Open Access Journals (Sweden)

    A Vatanara

    2009-03-01

    Full Text Available ABSTRACT Background: The ability of supercritical fluids (SCFs, such as carbon dioxide, to dissolve and expand or extract organic solvents and as result lower their solvation power, makes it possible the use of SCFs for the precipitation of solids from organic solutions. The process could be the injection of a solution of the substrate in an organic solvent into a vessel which is swept by a supercritical fluid. The aim of this study was to ascertain the feasibility of supercritical processing to prepare different particulate forms of fluticasone propionate (FP, and to evaluate the influence of different liquid solvents and precipitation temperatures on the morphology, size and crystal habit of particles. Method: The solution of FP in organic solvents, was precipitated by supercritical carbon dioxide (SCCO2 at two pressure and temperature levels. Effects of process parameters on the physicochemical characteristics of harvested microparticles were evaluated. Results: Particle formation was observed only at the lower selected pressure, whilst at the higher pressure, no precipitation of particles was occurred due to dissolution of FP in supercritical antisolvent. The micrographs of the produced particles showed different morphologies for FP obtained from different conditions. The results of thermal analysis of the resulted particles showed that changes in the processing conditions didn't influence thermal behavior of the precipitated particles. Evaluation of the effect of temperature on the size distribution of particles showed that increase in the temperature from 40 oC to 50 oC, resulted in reduction of the mean particle size from about 30 µm to about 12 μm. ‍Conclusion: From the results of this study it may be concluded that, processing of FP by supercritical antisolvent could be an approach for production of diverse forms of the drug and drastic changes in the physical characteristics of microparticles could be achieved by changing the

  13. Liquid membrane purification of biogas

    Energy Technology Data Exchange (ETDEWEB)

    Majumdar, S.; Guha, A.K.; Lee, Y.T.; Papadopoulos, T.; Khare, S. (Stevens Inst. of Tech., Hoboken, NJ (United States). Dept. of Chemistry and Chemical Engineering)

    1991-03-01

    Conventional gas purification technologies are highly energy intensive. They are not suitable for economic removal of CO{sub 2} from methane obtained in biogas due to the small scale of gas production. Membrane separation techniques on the other hand are ideally suited for low gas production rate applications due to their modular nature. Although liquid membranes possess a high species permeability and selectivity, they have not been used for industrial applications due to the problems of membrane stability, membrane flooding and poor operational flexibility, etc. A new hollow-fiber-contained liquid membrane (HFCLM) technique has been developed recently. This technique overcomes the shortcomings of the traditional immobilized liquid membrane technology. A new technique uses two sets of hydrophobic, microporous hollow fine fibers, packed tightly in a permeator shell. The inter-fiber space is filled with an aqueous liquid acting as the membrane. The feed gas mixture is separated by selective permeation of a species through the liquid from one fiber set to the other. The second fiber set carries a sweep stream, gas or liquid, or simply the permeated gas stream. The objectives (which were met) of the present investigation were as follows. To study the selective removal of CO{sub 2} from a model biogas mixture containing 40% CO{sub 2} (the rest being N{sub 2} or CH{sub 4}) using a HFCLM permeator under various operating modes that include sweep gas, sweep liquid, vacuum and conventional permeation; to develop a mathematical model for each mode of operation; to build a large-scale purification loop and large-scale permeators for model biogas separation and to show stable performance over a period of one month.

  14. Hygiene and sanitation requirements in Danish biogas plants

    Energy Technology Data Exchange (ETDEWEB)

    Bendixen, H.J.

    1997-08-01

    According to Danish regulations, systematic pathogen reducing treatment is required, when industrial by-products and waste products, and urban waste, ie garbage from households and sewage sludge, are processed, before being used - without restrictions - as fertilizers on agricultural land. An adequate pathogen reducing effect (PRE) can be achieved in the digestion tanks and sanitation tanks of the biogas plants, provided they are operated correctly and respect the criteria of the official requirements. The FS-method is a microbiological indicator method based on faecal streptococci (enterococci) (FS). It may be used to check the sanitation effect achieved by the treatment in a tank. The effect is expressed numerically by the log{sub 10}-reduction of the numbers of FS measured in the biomass before and after treatment. The PRE was examined in 10 large-scale biogas plants during a period of 2-3 years. It was demonstrated that properly directed and well-functioning thermophilic digestion tanks ensure the removal of most pathogenic microorganisms from organic waste and slurry. The removal of pathogens by the treatment in mesophilic digestion tanks is incomplete. Systematic studies of the processes of inactivation of bacteria and virus in slurry and in animal tissues gave evidence that the PRE is enhanced in the microbiological environment of thermophilic digestion tanks. The sanitation criteria, ie combinations of temperature/time, for the processing of biomass in digestion tanks and sanitation tanks in biogas plants are specified. (au) 19 refs.

  15. Micro-aeration for hydrogen sulfide removal from biogas

    Science.gov (United States)

    Duangmanee, Thanapong

    The presence of sulfur compounds (e.g. protein, sulfate, thiosulfate, sulfite, etc.) in the feed stream generates highly corrosive and odorous hydrogen sulfide during anaerobic digestion. The high sulfide level in the biogas stream is not only poisonous to many novel metal catalysts employed in thermo-catalytic processes but also reduces the quality of methane to produce renewable energy. This study used an innovative, low-maintenance, low-cost biological sulfide removal technology to remove sulfides simultaneously from both gas and liquid phase. ORP (Oxidation-Reduction-Potential) was used as the controlling parameter to precisely regulate air injection to the sulfide oxidizing unit (SOU). The microaeration technique provided just enough oxygen to partially oxidize sulfides to elemental sulfur without inhibiting methanogenesis. The SOU was equipped with a diffuser at the bottom for the dispersion of sulfide-laden biogas and injected air throughout the column. The SOU can be operated as a standalone unit or coupled with an anaerobic digester to simultaneously remove sulfide from the biogas and effluent. The integrated system was capable of reducing hydrogen sulfide in biogas from 2,450 to less than 2 ppmV with minimal sulfate production at the highest available sulfide loading rate of 0.24 kg/m3-day. More than 98% of sulfide removed was recovered as elemental sulfur. However, the standalone SOU was able to operate at high hydrogen sulfide loading of 1.46 kg/m 3-day at inlet sulfide concentration of 3000 ppmV and reduce the off-gas hydrogen sulfide concentrations to less than 10 ppmV. The experiment also revealed that the ORP controlled aeration was sensitive enough to prevent oxygen overdosing (dampening effect) during unexpected surges of aeration. Using generalized linear regression, a model predicting output H2S concentration based on input H2S concentrations, SOU medium heights, and biogas flow rates, was derived. With 95% confidence, output H2S concentration

  16. Comparative life cycle assessment of biogas plant configurations for a demand oriented biogas supply for flexible power generation.

    Science.gov (United States)

    Hahn, Henning; Hartmann, Kilian; Bühle, Lutz; Wachendorf, Michael

    2015-03-01

    The environmental performance of biogas plant configurations for a demand - oriented biogas supply for flexible power generation is comparatively assessed in this study. Those configurations indicate an increased energy demand to operate the operational enhancements compared to conventional biogas plants supplying biogas for baseload power generation. However, findings show that in contrast to an alternative supply of power generators with natural gas, biogas supplied on demand by adapted biogas plant configurations saves greenhouse gas emissions by 54-65 g CO(2-eq) MJ(-1) and primary energy by about 1.17 MJ MJ(-1). In this regard, configurations with flexible biogas production profit from reduced biogas storage requirements and achieve higher savings compared to configurations with continuous biogas production. Using thicker biogas storage sheeting material reduces the methane permeability of up to 6m(3) d(-1) which equals a reduction of 8% of the configuration's total methane emissions.

  17. Implementation of decentralized power generation by biogas digester: Policy and perspective

    Directory of Open Access Journals (Sweden)

    Nirmalendunath Ghosh

    2015-04-01

    Full Text Available This paper aims to evolve innovative system for fast track implementation of decentralized power generation by biogas digester across the country commensurate with estimated potential of this energy resource. The methodology is based on the principle that necessity of a process or facility for human liveli hood generates demand of a new system if that is competitive enough to impress society by its value to meet the standard of usability economically and technically in all respect. Firstly, the study described a network of communication to propagate knowledge about the benefit, cost and operation of biogas digester to serve multiple purposes among policy makers and other stakeholders all over the country through distance mode programme and training of the human resources by simulating the process for training programme. Secondly, analysis by cause and effect method focused on major issues related to implementation of power generation by biogas that identified factors corresponding to the problems. Next the study attempt to focus on supply chain management for controlling those factors supported by administration with financial, technical facilities ensuring trouble free dynamic process from procurement of substrate through input to digester till delivery of electricity to the consumers. The study identified driving variables between resource centre and delivery stage of the supply chain that has influence on methane production related to power generation. The mathematical analysis reveal that optimum yield of biogas is independent of daily feed stock and improving methane fraction of biogas is possible by monitoring temperature and pH value within limited span of Hydraulic Retention period (HRT.The study observed by mathematical analysis that cost of power generation from biogas digester is dependent on the cost of substrate for biogas generation and the other fixed cost of the process. Bio gas digester cum power generation policy has been

  18. Kinetic Model of Biogas Yield Production from Vinasse at Various Initial pH: Comparison between Modified Gompertz Model and First Order Kinetic Model

    Directory of Open Access Journals (Sweden)

    Budiyono

    2014-04-01

    Full Text Available Anaerobic treatment using anaerobic digestion can convert organic materials of vinasse into biogas. The purpose of this study was modeling kinetic of biogas production using modified Gompertz model and first order kinetic model at variation of initial pH. Substrates were consisted of two kinds of compositions, which were vinasse+rumen (VR and vinasse+rumen+urea (VRU. Initial pH in each substrate was 6, 7 and 8. Degradation process was done in 30 days using batch anaerobic digesters at room temperature. Both, at VR and VRU, initial pH of 7 generated the more total biogas than the others two (initial pH of 6 and 8. Biogas formed at substrate of VRU was more than that at substrate of VR. The best condition was substrate of VRU and initial pH of 7. At best condition, kinetic constants of biogas production model using modified Gompertz were ym (biogas production potential = 6.49 mL/g VS; U (maximum biogas production rate = 1.24 mL/g VS. day; &lambda (minimum time to produce biogas = 1.79 days. Whereas kinetic constants of biogas production model using first order kinetic were ym (biogas production potential = 6.78 mL/g VS; k (biogas production rate = 0.176 /day. The difference between the predicted and measured biogas yield (fitting error was higher with the first-order kinetic model (1.54-7.50% than with the modified Gompertz model (0.76-3.14%.

  19. Ultrasound pretreatment for enhanced biogas production from olive mill wastewater.

    Science.gov (United States)

    Oz, Nilgun Ayman; Uzun, Alev Cagla

    2015-01-01

    This study investigates applicability of low frequency ultrasound technology to olive mill wastewaters (OMWs) as a pretreatment step prior to anaerobic batch reactors to improve biogas production and methane yield. OMWs originating from three phase processes are characterized with high organic content and complex nature. The treatment of the wastewater is problematic and alternative treatment options should be investigated. In the first part of the study, OMW samples were subjected to ultrasound at a frequency of 20kHz with applied powers varying between 50 and 100W under temperature controlled conditions for different time periods in order to determine the most effective sonication conditions. The level of organic matter solubilization at ultrasound experiments was assessed by calculating the ratio of soluble chemical oxygen demand/total chemical oxygen demand (SCOD/TCOD). The results revealed that the optimum ultrasonic condition for diluted OMW is 20kHz, 0.4W/mL for 10min. The application of ultrasound to OMW increased SCOD/TCOD ratio from 0.59 to 0.79. Statistical analysis (Friedman's tests) show that ultrasound was significantly effective on diluted OMW (p0.05). For raw OMW, this increase has been found to be limited due to high concentration of suspended solids (SS). In the second part of the study, biogas and methane production rates of anaerobic batch reactor fed with the ultrasound pretreated OMW samples were compared with the results of control reactor fed with untreated OMW in order to determine the effect of sonication. A nonparametric statistical procedure, Mann-Whitney U test, was used to compare biogas and methane production from anaerobic batch reactors for control and ultrasound pretreated samples. Results showed that application of low frequency ultrasound to OMW significantly improved both biogas and methane production in anaerobic batch reactor fed with the wastewater (preactor fed with ultrasound pretreated diluted OMW produced approximately 20

  20. Microbial analysis in biogas reactors suffering by foaming incidents.

    Science.gov (United States)

    Kougias, Panagiotis G; De Francisci, Davide; Treu, Laura; Campanaro, Stefano; Angelidaki, Irini

    2014-09-01

    Foam formation can lead to total failure of digestion process in biogas plants. In the present study, possible correlation between foaming and the presence of specific microorganisms in biogas reactors was elucidated. The microbial ecology of continuous fed digesters overloaded with proteins, lipids and carbohydrates before and after foaming incidents was characterized using 16S rRNA gene sequencing. Moreover, the microbial diversity between the liquid and foaming layer was assessed. A number of genera that are known to produce biosurfactants, contain mycolic acid in their cell wall, or decrease the surface tension of the media, increased their relative abundance after foam formation. Finally, a microorganism similar to widely known foaming bacteria (Nocardia and Desulfotomaculum) was found to increase its relative abundance in all reactors once foam was observed, regardless of the used substrate. These findings suggest that foaming and specific microorganisms might have direct association which requires to be further investigated.

  1. Improving aerobic stability and biogas production of maize silage using silage additives.

    Science.gov (United States)

    Herrmann, Christiane; Idler, Christine; Heiermann, Monika

    2015-12-01

    The effects of air stress during storage, exposure to air at feed-out, and treatment with silage additives to enhance aerobic stability on methane production from maize silage were investigated at laboratory scale. Up to 17% of the methane potential of maize without additive was lost during seven days exposure to air on feed-out. Air stress during storage reduced aerobic stability and further increased methane losses. A chemical additive containing salts of benzoate and propionate, and inoculants containing heterofermentative lactic acid bacteria were effective to increase aerobic stability and resulted in up to 29% higher methane yields after exposure to air. Exclusion of air to the best possible extent and high aerobic stabilities should be primary objectives when ensiling biogas feedstocks.

  2. Assessment of anaerobic co-digestion of agro wastes for biogas recovery: A bench scale application to date palm wastes

    Directory of Open Access Journals (Sweden)

    Zainab Ziad Ismail, Ali Raad Talib

    2014-01-01

    Full Text Available Anaerobic digestion is a technology widely used for treatment of organic waste to enhance biogas recovery. In this study, recycling of date palm wastes (DPWs was examined as a source for biogas production. The effects of inoculum addition, pretreatment of substrate, and temperature on the biogas production were investigated in batch mode digesters. Results revealed that the effect of inoculum addition was more significant than alkaline pretreatment of raw waste materials. The biogas recovery from inoculated DPWs exceeds its production from DPWs without inoculation by approximately 140% at mesophilic conditions. Whereby, the increase of biogas recovery from pretreated DPWs was 52% higher than its production from untreated DPWs at mesophilic conditions. The thermophilic conditions improved the biogas yield by approximately 23%. The kinetic of bio-digestion process was well described by modified Gompertz model and the experimental and predicted values of biogas production were fitted well with correlation coefficient values greater than 0.96 suggesting favorable conditions of the process.

  3. The removal of hydrogen sulfide from biogas in a microaerobic biotrickling filter using polypropylene carrier as packing material.

    Science.gov (United States)

    Zhou, Qiying; Liang, Hong; Yang, Senlin; Jiang, Xia

    2015-04-01

    Biological removal of hydrogen sulfide in biogas is an increasingly adopted alternative to the conventional physicochemical processes, because of its economic and environmental benefits. In this study, a microaerobic biofiltration system packed with polypropylene carrier was used to investigate the removal of high concentrations of H2S contained in biogas from an anaerobic digester. The results show that H2S in biogas was removed completely under different inlet concentrations of H2S from 2065 ± 234 to 7818 ± 131 ppmv, and the elimination capacity of H2S in the filter achieved about 122 g H2S/m(3)/h. It was observed that the content of CH4 in biogas increased after the biogas biodesulfurization process, which was beneficial for the further utilization of biogas. The elemental sulfur and sulfate were the main sulfur species of H2S degradation, and elemental sulfur was dominant (about 80 %) under high inlet H2S concentration. The results of terminal restriction fragment length polymorphism (T-RFLP) and fluorescence in situ hybridization (FISH) show that the population of sulfide-oxidizing bacteria (SOB) species in the filter changed with different concentrations of H2S. The microaerobic biofiltration system allows the potential use of biogas and the recovery of elemental sulfur resource simultaneously.

  4. The economics of biogas in Denmark

    DEFF Research Database (Denmark)

    Jacobsen, Brian H.; Laugesen, Frederik Møller; Dubgaard, Alex

    2014-01-01

    Denmark has been one of the leading European Countries in using Biogas for Combined Heat and Power (CHP), since the 1980s. However, in the last two decades, the increase has been limited. A new energy policy aimed at increasing the profitability of biogas was introduced in the spring of 2012....... The analysis here shows that the new agreement will improve the profitability of biogas plants and increase the biogas production although the political ambition of an increase from 4 PJ to 17 PJ by 2020 seems unlikely. The analysis shows that biogas plants can be profitable even if the input is a mix....... The analysis shows that the profit from upgrading biogas is only to be preferred if the sales price of heat or the amount sold are relatively low. The socioeconomic analyses show that the costs of biogas as a measure to reduce CO2 emissions are around €151 per tonne CO2 (€85‐266 per ton) and that using maize...

  5. Metaproteomics of complex microbial communities in biogas plants.

    Science.gov (United States)

    Heyer, Robert; Kohrs, Fabian; Reichl, Udo; Benndorf, Dirk

    2015-09-01

    Production of biogas from agricultural biomass or organic wastes is an important source of renewable energy. Although thousands of biogas plants (BGPs) are operating in Germany, there is still a significant potential to improve yields, e.g. from fibrous substrates. In addition, process stability should be optimized. Besides evaluating technical measures, improving our understanding of microbial communities involved into the biogas process is considered as key issue to achieve both goals. Microscopic and genetic approaches to analyse community composition provide valuable experimental data, but fail to detect presence of enzymes and overall metabolic activity of microbial communities. Therefore, metaproteomics can significantly contribute to elucidate critical steps in the conversion of biomass to methane as it delivers combined functional and phylogenetic data. Although metaproteomics analyses are challenged by sample impurities, sample complexity and redundant protein identification, and are still limited by the availability of genome sequences, recent studies have shown promising results. In the following, the workflow and potential pitfalls for metaproteomics of samples from full-scale BGP are discussed. In addition, the value of metaproteomics to contribute to the further advancement of microbial ecology is evaluated. Finally, synergistic effects expected when metaproteomics is combined with advanced imaging techniques, metagenomics, metatranscriptomics and metabolomics are addressed.

  6. Optimisation of biogas production from manure through serial digestion: lab-scale and pilot-scale studies.

    Science.gov (United States)

    Kaparaju, Prasad; Ellegaard, Lars; Angelidaki, Irini

    2009-01-01

    In the present study, the possibility of optimizing biogas production from manure by serial digestion was investigated. In the lab-scale experiments, process performance and biogas production of serial digestion, two methanogenic continuously stirred tank reactors (CSTR) connected in series, was compared to a conventional one-step CSTR process. The one-step process was operated at 55 degrees C with 15d HRT and 5l working volume (control). For serial digestion, the total working volume of 5l was distributed as 70/30%, 50/50%, 30/70% or 13/87% between the two methanogenic reactors, respectively. Results showed that serial digestion improved biogas production from manure compared to one-step process. Among the tested reactor configurations, best results were obtained when serial reactors were operated with 70/30% and 50/50% volume distribution. Serial digestion at 70/30% and 50/50% volume distribution produced 13-17.8% more biogas and methane and, contained low VFA and residual methane potential loss in the effluent compared to the one-step CSTR process. At 30/70% volume distribution, an increase in biogas production was also noticed but the process was very unstable with low methane production. At 13/87% volume distribution, no difference in biogas production was noticed and methane production was much lower than the one-step CSTR process. Pilot-scale experiments also showed that serial digestion with 77/23% volume distribution could improve biogas yields by 1.9-6.1% compared to one-step process. The study thus suggests that the biogas production from manure can be optimized through serial digestion with an optimal volume distribution of 70/30% or 50/50% as the operational fluctuations are typically high during full scale application. However, process temperature between the two methanogenic reactors should be as close as possible in order to derive the benefits of serial coupling.

  7. Biogas treatment arising from effluent anaerobic digestion: organic substrate with high sulphate content; Tratamiento de biogas generado por la digestion anaerobia de efluentes: sustratos organicos con elevado contenido en sulfato

    Energy Technology Data Exchange (ETDEWEB)

    Navia, R.; Vidal, G.

    2002-07-01

    Biological anaerobic treatment of waste water offers a good alternative for high organic rate effluents. However, in fermentation with high sulphate concentrations, sulphide could be detected in the biogas. The goal of this work is to analyze the biogas production from the anaerobic digestions of the effluents with high sulphate content. Treatment to remove sulphite in the biogas stream is also described. Oxidation in liquid phase and biological process are the most attractive treatments. In both cases, sulphite is converted in sulphate and sulphur, which have no problems in the environmental disposal. (Author) 47 refs.

  8. NONSTATIONARY CATALYTIC SYSTEMS FOR THE PROCESSES OF BIOGAS PRODUCTION Нестационарные каталитические системы для утилизации биогаза

    Directory of Open Access Journals (Sweden)

    Onychin E. M.

    2012-04-01

    Full Text Available The new circuit-design solutions of catalytic systems for the processes of producing biogas from organic waste are proposed. They are based on the analysis of existent tech. solutions. The interaction features of the flow of reactants to the catalytic filler in the proposed catalytic systems allow us to intensify the process of reaction, as well as to optimize the design features of catalytic systems based on the technological process

  9. Fuels made from agricultural biomass - (biogas) alternative types(Alternativne vrste goriva iz poljoprivredne biomase - biogas)

    OpenAIRE

    Jovanovska, Vangelica; Jovanovski, Nikola; Sovreski, Zlatko; Pop-Andonov, Goran; Sinani, Feta

    2013-01-01

    Biogas is a typical "product" of urban discharges, which has a great negative environmental impact. To avoid this negative effect, it can be burnt at very high temperatures, producing smoke emissions composed of CO2. A useful alternative is to use biogas as fuel to feed co-generation plants, producing electricity. At the moment biogas is used as fuel, introducing it directly in the combustion chamber. Nevertheless the heterogeneity of the gas stresses the engine, reducing its life. The new te...

  10. An alternative resource for biogas production

    Energy Technology Data Exchange (ETDEWEB)

    Patrabansh, S. [Tribhuvan Univ., Research Center for Applied Science and Technology, Kirtipur, Kathmandu (Nepal); Madan, M. [Indian Inst. of Technology, Center for Rural Development and Technology, New Delhi (India)

    2000-09-01

    Three different biomasses, namely, sericulture waste, Populus deltoides, and Eupatorium adenophorum, were studied for biogas production. It was found that these wastes produced biogas in reasonably good quantity of gas (259 l/kg of total solid in sericulture waste to 519 l/kg of total solid in E. adenophorum). The substrates were subjected to anaerobic digestion directly, without any pre-treatment, and a batch with biological treatment in triplicate set. Among the two sets, the biologically pretreated digesters gave higher yield of biogas. Chemical analysis for nitrogen content, cellulose, hemicellulose, and lignin content before and after digestion was carried out. (Author)

  11. Farm scale biogas concepts in Europe

    Energy Technology Data Exchange (ETDEWEB)

    Wellinger, A. [Nova Energie, Ettenhausen (Switzerland)

    1997-08-01

    The near future of farm scale biogas production looks bright as long as the high electricity prices are maintained by political will and subsidies remain higher than approx. 20%. If in all the number of biogas plants is growing as it is in Germany (Within the last two years about 200 new plants have been built) then biogas will add its share to a nuclear power free electricity production, as does wind energy in Germany, Holland or Denmark. The standard for manure digesters is set. There is still some way to go for solid waste digesters. However, first inputs have been given. (EG) 10 refs.

  12. Biogas entrepreneur's operational environment in Finland; Biokaasuyrittaejaen toimintaympaeristoe Suomessa. Kokemuksia MMM:n investointiavustusjaerjestelmaestae 2008-2010

    Energy Technology Data Exchange (ETDEWEB)

    Marttinen, S.; Lehtonen, H.; Luostarinen, S.; Rasi, S.

    2013-09-01

    have sufficient and predictable balance from selling electricity and heat and also partly from fertilizers produced from the digestate and gate fees obtained from waste-based materials. The investment cost of biogas plant is very high in relation to turnover, which emphasizes the significance of balance sheet. The interviewed desicion-makers found the future of biogas business positive despite the profitabilityrelated challenges. They believed that in the future, productization of the digestates will be a more important source of income for the biogas plants than energy production. This study indicated that developing energy production support system and supporting research and development on digestate processing as well as the use of recycled fertilizers are key factors needed to increase the number of agricultural biogas plants in Finland. A long-term support policy and sufficiently high support are also prerequisites for this development. Profitability of the biogas plants may be increased also by using indirect policy mechanisms. Examples of operational models and profitability calculations, based on experiences from real Finnish biogas plants, would be of practical help for those planning a biogas plant. New way of thinking, also in administration, which would see biogas plant as an integration of energy production, agriculture, waste management and nutrient recycling, could enhance the development of the biogas sector in Finland. This integrated view would also help consideration of positive environmental benefits of biogas production and use in support systems. (orig.)

  13. The biogas: a future energy alternative; Biogas: a alternativa energetica do futuro

    Energy Technology Data Exchange (ETDEWEB)

    Paixao, Carla Marques [Faculdade de Tecnologia e Ciencias, Salvador, BA (Brazil)]. E-mail: paixao_cm@yahoo.com.br; Anjos, Jose Angelo Sebastiao Araujo dos [Universidade de Salvador, BA (Brazil). Lab. de Pesquisa Ambiental e Geotecnologias (LAGEO)]. E-mail: jangello@unifacs.br; Mascarenhas, Artur Jose Santos [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil)]. E-mail: ajsmascarenhas@yahoo.com.br

    2006-01-15

    The biogas is one of the principal factors. During the last years the biogas use are intensifying himself which can make the energy alternative of the future. The methane, present in these gas, can be converted into energy, for his combustion generates a large quantity of thermal energy, which can be concerted into electrical ou mechanical energy. Being so, it is important that we aware that the caloric power of the biogas varies between 5000 to 7000 kcal/m{sup 3}, depending on the methane concentrations. Besides, the biogas purification through the removal of the carbonic gas can rising his calorific to values larger than 8700 kcal/m{sup 3}.

  14. Biogas supply to the natural gas supply grid. Study; Einspeisung von Biogas in das Erdgasnetz. Studie

    Energy Technology Data Exchange (ETDEWEB)

    Klinski, S. [DBI Gas- und Umwelttechnik GmbH, Leipzig (Germany)

    2006-07-01

    Biogas supply to the public gas grid is a new option discussed in the most recent publication of Fachagentur Nachwachsende Rohstoffe (FNR) e.V. The biogas is purified, upgraded to natural gas quality and fed into an existing gas grid. Once there, it can be transported across long distances and also used for electric power generation at the consumer side. The study investigates inhowfar and in what instances this method is feasible and promising. It discusses the technical background and the regional potential of biogas. Seven model biogas systems are presented as examples. (orig.)

  15. Environmental benefits and value chain economics at biogas production, phase II. Food waste and manure; Miljoenytte og verdikjedeoekonomi ved biogassproduksjon, fase II. Matavfall og husdyrgjoedsel

    Energy Technology Data Exchange (ETDEWEB)

    Moeller, Hanne; Arnoey, Silje; Modahl, Ingunn Saur; Morken, John; Briseid, Tormod; Hanssen, Ole Joergen; Soerby, Ivar

    2012-07-01

    The main objective has been to develop an environmental model and an economic model for the entire value chain for the production of biogas and digestate processing. The results will contribute to better decision making in the planning of new biogas plants in Norway. Shortened version.(eb)

  16. Harvesting biogas from wastewater sludge and food waste

    Science.gov (United States)

    Chua, K. H.; Cheah, W. L.; Tan, C. F.; Leong, Y. P.

    2013-06-01

    Wastewater sludge and food waste are good source of biogas. Anaerobic treatment of slude and food waste able to produce biogas which is a potential renewable energy source. This study looks into the potential biogas generation and the effects of temperature on biogas generation. A lab scale reactor was used to simulate the biogas generation. The results show that wastewater sludge able to produced upto 44.82 ml biogas/kg of sludge. When mixed with food waste at a ratio of 30:70 (food waste), the biogas generated were 219.07 ml/kg of waste. Anaerobic of food waste alone produced biogas amount to 59.75 ml/kg of food waste. Anaerobic treatment also reduces the volume of waste. The effect of temperature shows that higher temperature produces more biogas than lower temperature.

  17. Biogas production: This is how the Swedes do it

    Energy Technology Data Exchange (ETDEWEB)

    1982-01-01

    In Sweden, biogas is produced according to the Abetong-Sabema process. Thermophilic microorganisms are employed for anaerobic digestion. At 55/sup 0/C, residence time is 3 to 5 days. In contrast to other facilities in application, this means a reduction of the digestion space by a factor of six or seven and, thus, reduced investments. Desinfection of the manure takes place under these high temperatures. With a facility operating since 1978, liquid manure is pumped directly from the stable into a 20 cbm prechamber located in the interior of the gas reactor. The liquid manure is heated to 55/sup 0/C and then discharged into the 240 cbm main chamber where the liquid manure is constantly stirred in order to avoid float layers and deposits. The biogas is compressed, stored and combusted in a Fiat ''Totem'' engine producing electricity and hot water. The facility produces 210,000 cbm of biogas. 310,000 kWh of electricity and 590 kWh of heat are available as useful energy. App. 60% of the total energy can be utilized under Swedish conditions. A 40 cbm facility employs a horizontal cylindric main chamber and a separate prechamber. This facility will work without stirring.

  18. Influences of different substrates on simulated lignite biogas production

    Institute of Scientific and Technical Information of China (English)

    Wang Aikuan; Qin Yong; Shao Pei

    2015-01-01

    Using lignite samples, selected from Zhaotong basin, Yunnan province, China, as the parent source, sim-ulating experiments of lignite biogas were conducted with 0.1% methanol, 5 mg/L yeast extract and 0.2 mol/L sodium acetate solutions as the exogenous substance respectively. Variation characteristics of gas production, gas composition, VFA content and activity of coenzyme F420 in the simulated process were analyzed to discuss the influence of different substrates on lignite biogas generation. The results show that 0.1%methanol and 5 mg/L yeast extract solutions increase VFA contents in the biogas gener-ation system (p <0.05) and inhibit coenzyme F420 and methanogen activities significantly, so they decrease both gas amounts (p<0.05) and CH4 contents (p<0.05). 0.2 mol/L sodium acetate solution acti-vates coenzyme F420 and methanogen activities and improves the efficiency of enzymatic reaction, so the gas quantity (p<0.05) and the CH4 content (p<0.01) increase significantly. Therefore, sodium acetate can be one kind of good exogenous substance for the generation of lignite biogenic gas.

  19. ANAEROBIC DIGESTION MODEL ANALYSIS OF THE FERMENTATION PROCESS IN PSYCHROPHILIC AND MESOPHILIC CHAMBER IN ACCORDANCE WITH THE AMOUNT OF BIOGAS SOURCED

    OpenAIRE

    Dariusz Zdebik; Marcin Głodniok; Paweł Zawartka

    2015-01-01

    The paper presents problems concerning the modelling of anaerobic sludge stabilization, with the additional substrate (waste transported, dairy butchery sewage) in psychrophilic fermentation conditions in the range 10–20 °C and mesophilic at 35 °C. Simulation test was conducted in the two digesters. Results of the study allowed to evaluate the effectiveness of conducting these processes in separate chambers, i.e. the psychrophilic and mesophilic chamber. During the simulations, terms of obtai...

  20. 78 FR 70953 - Draft Guidance for Industry on Bioequivalence Recommendations for Fluticasone Propionate...

    Science.gov (United States)

    2013-11-27

    ... HUMAN SERVICES Food and Drug Administration Draft Guidance for Industry on Bioequivalence... Industry on Bioequivalence Recommendations for Fluticasone Propionate; Salmeterol Xinafoate'', published in... for Industry on Bioequivalence Recommendations for Fluticasone Propionate; Salmeterol...

  1. [On the nonexistence of propionic acid in various kinds of breeds (author's transl)].

    Science.gov (United States)

    Lück, E; Oeser, H; Remmert, K H; Sabel, J

    1975-05-30

    Analyses of 45 samples of sour dough and various kinds of bread have shown that no appreciable amounts of propionic acid are formed during sour dough fermentation. Bread has no natural propionic acid content.

  2. Secondary mitochondrial dysfunction in propionic aciduria: a pathogenic role for endogenous mitochondrial toxins.

    NARCIS (Netherlands)

    Schwab, M.A.; Sauer, S.W.; Okun, J.G.; Nijtmans, L.G.J.; Rodenburg, R.J.T.; Heuvel, L.P.W.J. van den; Drose, S.; Brandt, U.; Hoffmann, G.F.; Laak, H.J. ter; Kolker, S.; Smeitink, J.A.M.

    2006-01-01

    Mitochondrial dysfunction during acute metabolic crises is considered an important pathomechanism in inherited disorders of propionate metabolism, i.e. propionic and methylmalonic acidurias. Biochemically, these disorders are characterized by accumulation of propionyl-CoA and metabolites of alternat

  3. ARTICLES: Vapor-Liquid Equilibrium Data of Carbon Dioxide+Methyl Propionate and Carbon Dioxide+Propyl Propionate Systems

    Science.gov (United States)

    Xu, Wei; Xie, Chuan-xin; Li, Hong-ling; Tian, Yi-ling

    2010-06-01

    High-pressure vapor-liquid equilibrium data for the binary systems of methyl propionate+carbon dioxide and propyl propionate+carbon dioxide were measured at pressure from 1.00 MPa to 12.00 MPa and temperature in the range from 313 K to 373 K. Experimental results were correlated with the Peng-Robinson equation of state with the two-parameter van der Waals mixing rule. At the same time, the Henry's coefficient, partial molar enthalpy change and partial molar entropy change of CO2 during dissolution at different temperature were also calculated.

  4. Anaerobic digestion for closing the loop of a biorefinery for organic farming: production of biogas and organic fertilizer from process residues

    DEFF Research Database (Denmark)

    Fernandez, Maria Santamaria; Karkov Ytting, Nanna; Lübeck, Mette

    2016-01-01

    were determined in batch and reactor experiments and mass balances of the nutrients were established based on analysis of N, P, K, and S from the different process stages (screw pressing, protein precipitation and AD process). The AD process was tested in lab-scale both as co-digestion of press cake......The availability of organic animal feed for monogastric animals and organic fertilizer is in many regions a limiting factor for the further spread of organic farming. The production of these two commodities based on regionally organically grown grass biomass is the main target of a green...... cake and brown juice at 20d hydraulic retention time (HRT) methane yields of 237 to 283 L-CH4/kg-VS were achieved while mesophilic treatment of brown juice in the high-rate reactor yielded on average 202 L-CH4/kg-VS at 3 days HRT. Nutrient analysis showed that most of the nutrients of the fresh crop...

  5. Modelling anaerobic digestion in an industrial biogas digester: Application of lactate-including ADM1 model (Part II).

    Science.gov (United States)

    Satpathy, Preseela; Biernacki, Piotr; Cypionka, Heribert; Steinigeweg, Sven

    2016-12-05

    A modified Anaerobic Digestion Model No. 1 (ADM1xp) including lactate was applied to a full-scale biogas plant. This model considers monosaccharides to degrade through lactic acid, which further degrades majorly into acetate followed by propionate and butyrate. Experimental data were derived from the previous works in the same laboratory, and the proposed parameters were validated against batch experiments. After successful validation, the biogas plant bearing a fermenter size of 7 dam(3) and operated with food waste and cattle manure was simulated. The biogas production and methane content were reliably simulated, and a good fit could be obtained against the experimental data with an average difference of less than 1%. When compared to the original ADM1 model, the performance of the lactate-incorporated model was found to be improved. Inclusion of lactate as a parameter in the ADM1xp model is recommended for an increased sensitivity and enhanced prediction principally for systems dealing with high carbohydrate and lactate loads.

  6. Risk and insurance management for biogas plants

    Energy Technology Data Exchange (ETDEWEB)

    Haerig, M. [Marsh GmbH, Duesseldorf (Germany)

    2007-07-01

    The continuing negative experiences of insurers with biogas plants make it difficult for operators to get appropriate insurance cover. There are different reasons for this big number of damages. Especially in the beginning components have been rebuilt for biogas without sufficient experiences. Other damages have emerged due to improper or disregardful plant management. For that reason the insurers' standards for the biogas plant and the plant management have risen up. The following report deals with experiences of insurance for biogas plants and the resulting consequences. For that reason Marsh carried out a research project and analyzed all reported claims in the All Risk Insurance. The necessary technical minimum requirements for installation and operation are geared to the experiences with damages. But they also account for the interests of the insured. (orig.)

  7. Drijfmest verliest snel zijn waarde voor biogas

    NARCIS (Netherlands)

    Buisonjé, de F.E.; Verheijen, R.

    2014-01-01

    Drijfmest moet zo snel mogelijk de vergister in. Alleen een snelle vergisting levert een maximale hoeveelheid biogas op. Uit onderzoek blijkt dat het biogaspotentieel van drijfmest maandelijks met zo’n 30 procent afneemt.

  8. Effective green manuring via biogas production

    OpenAIRE

    Nykänen, Arja; Kymäläinen, Maritta; Lemola, Riitta

    2011-01-01

    The preliminary results show that the benefit from anaerobic digestion of the green manure leys seem to be based more on biogas energy production than for higher yields after anaerobic digestion. The N leaching risk is under determination.

  9. Cavitation for improved sludge conversion into biogas

    Science.gov (United States)

    Stoop, A. H.; Bakker, T. W.; Kramer, H. J. M.

    2015-12-01

    In several studies the beneficial influence of pre-treatment of waste activated sludge with cavitation on the biogas production was demonstrated. It is however, still not fully certain whether this effect should be mainly contributed to an increase in conversion rate of organics into biogas by anaerobic bacteria, and how much cavitation increases the total biogas yield. An increase in yield is only the case if cavitation can further disrupt otherwise inaccessible cell membrane structures and long chain organic molecules. In this study the influence of hydrodynamic cavitation on sludge that was already digested for 30 days was investigated. The total biogas yield could indeed be increased. The effect of the backpressure behind the venturi tube on the yield could not yet be established.

  10. PENGARUH SUHU DAN KONSENTRASI RUMEN SAPI TERHADAP PRODUKSI BIOGAS DARI VINASSE

    Directory of Open Access Journals (Sweden)

    Rr. Dewi Artanti Putri

    2015-07-01

    Full Text Available Vinasse merupakan limbah yang dihasilkan oleh produksi bioetanol yang mempunyai kandungan COD (Chemical Oxygen Demand yang tinggi. Dengan karakteristik tersebut vinasse lebih tepat diuraikan dengan proses anaerob menjadi biogas. Penelitian ini dilakukan untuk mengkaji pengaruh suhu dan perbandingan rumen sapi  yang dibutuhkan untuk mendapatkan biogas dengan hasil yang optimum. Suhu mempengaruhi pertumbuhan mikroorganisme dan kecepatan reaksi dalam pembentukan biogas. Rumen sapi adalah inokulum atau starter yang merupakan bahan yang perlu ditambahkan ke dalam sistem digester biogas. Percobaan dilakukan dalam digester volum 500 ml, dioperasikan pada pH 7 dengan memvariasikan perbandingan suhu,yaitu suhu ruang, suhu 50 oC, dan suhu60 oC dan variasi konsentrasi rumen sapi  5%, 10%, 15%. Proses fermentasi dilakukan dengan cara batch dengan pengukuran gas setiap 2-3 hari menggunakan metode water displacement technique sampai gas tidak terbentuk selama 60 hari. Respon yang diambil pada penelitian ini adalah volume gas yang dihasilkan berdasarkan pengaruh suhu dan konsentrasi rumen sapi terhadap produksi biogas. Perubahan suhu dan konsentrasi rumen sapi sangat mempengaruhi produksi biogas. Hasil yang terbaik dari penelitian ini adalah pada konsentrasi rumen 15% pada suhu ruang yaitu sebanyak 370 ml. Kata kunci: biogas, vinasse, suhu, rumen sapiVinasse is the waste generated by the production of bioethanol which has high content of COD (Chemical Oxygen Demand. With these characteristics, it is more appropriate to convert it into biogas through anaerobic digestion process. This study was conducted to assess the effect of temperature and the cow rumen concentration needed to obtain biogas with optimum results. Temperature affects the growth of microorganisms and speed of reaction in the formation of biogas. The cow rumen was used as inoculum or starter material that needs to be added to the biogas digester system. Experiments conducted in the digester

  11. Monitoring of sulfur dioxide emission resulting from biogas utilization on commercial pig farms in Taiwan.

    Science.gov (United States)

    Su, Jung-Jeng; Chen, Yen-Jung

    2015-01-01

    The objective of this work tends to promote methane content in biogas and evaluate sulfur dioxide emission from direct biogas combustion without desulfurization. Analytical results of biogas combustion showed that combustion of un-desulfurized biogas exhausted more than 92% of SO₂ (P biogas (P biogas before any applications.

  12. Biogas plant Brelingen under self-construction

    Energy Technology Data Exchange (ETDEWEB)

    Meier, K.

    Since July 1981, the first biogas plant of the biogas group of Hannover has been in operation. The plant has not only been constructed by means of self-construction method using partly used components (direct recycling), but it shall also make possible a biologically optimal and low cost gas production for heat generation as far as its operating method is concerned. The design of the plant is described and some of the first results are presented.

  13. White Earth Biomass/Biogas Feasibility Study

    Energy Technology Data Exchange (ETDEWEB)

    Triplett, Michael

    2015-03-12

    The White Earth Nation examined the feasibility of cost savings and fossil energy reduction through the installation of biogas/biomass boiler at the tribal casino. The study rejected biogas options due to availability and site constraints, but found a favorable environment for technical and financial feasibility of installing a 5 MMBtu hot water boiler system to offset 60-70 percent of current fuel oil and propane usage.

  14. The development of biogas technology in India

    Science.gov (United States)

    Chiranjivi, C.; Raviprasad, A.; Rao, K. V.

    Biogas from organic wastes is a potential renewable energy to meet the domestic energy needs in India. The fundamentals of bio-gasification by anaerobic digestion are presented. The production of biogas from cattle manure in small anaerobic digesters is discussed, illustrated by a popular digester model. The need for the development of community digesters for the needs of a village and its implications are mentioned. The research work on biogasification at Andhra University is summarized.

  15. Treatment of digestate from a co-digestion biogas plant by means of vacuum evaporation: tests for process optimization and environmental sustainability.

    Science.gov (United States)

    Chiumenti, A; da Borso, F; Chiumenti, R; Teri, F; Segantin, P

    2013-06-01

    Vacuum evaporation consists in the boiling of a liquid substrate at negative pressure, at a temperature lower than typical boiling temperature at atmospheric conditions. Condensed vapor represents the so called condensate, while the remaining substrate represents the concentrate. This technology is derived from other sectors and is mainly dedicated to the recovery of chemicals from industrial by-products, while it has not been widely implemented yet in the field of agricultural digestate treatment. The present paper relates on experimental tests performed in pilot-scale vacuum evaporation plants (0.100 and 0.025 m(3)), treating filtered digestate (liquid fraction of digestate filtered by a screw-press separator). Digestate was produced by a 1 MWe anaerobic digestion plant fed with swine manure, corn silage and other biomasses. Different system and process configurations were tested (single-stage and two-stage, with and without acidification) with the main objectives of assessing the technical feasibility and of optimizing process parameters for an eventual technology transfer to full scale systems. The inputs and outputs of the process were subject to characterization and mass and nutrients balances were determined. The vacuum evaporation process determined a relevant mass reduction of digestate. The single stage configuration determined the production of a concentrate, still in liquid phase, with a total solid (TS) mean concentration of 15.0%, representing, in terms of mass, 20.2% of the input; the remaining 79.8% was represented by condensate. The introduction of the second stage allowed to obtain a solid concentrate, characterized by a content of TS of 59.0% and representing 5.6% of initial mass. Nitrogen balance was influenced by digestate pH: in order to limit the stripping of ammonia and its transfer to condensate it was necessary to reduce the pH. At pH 5, 97.5% of total nitrogen remained in the concentrate. This product was characterized by very high

  16. The demonstration project of centralized biogas supply system for 500 households in Mei-long-jie-xin village, Shanghai city

    Energy Technology Data Exchange (ETDEWEB)

    Shenggen Cheng [Shanghai Biogas Production Co. (China)

    2000-07-01

    The biogas project in Mei-long-jie-xin village, Shanghai, mainly includes a 150 m{sup 3} hybrid digester and a 100 m{sup 3} deep-well-type digester with a floating gas holder. This biogas project was designed by Shanghai Biogas Production Company and is used to treat high concentration distillery wastewater. Fermentation temperature is 25 - 38 C. Daily biogas production is about 1,500 m{sup 3}, which is used as daily fuel for 500 local household residents and some civil enterprises such as a village tea-house, a primary school, a kindergarten, a village glass processing workshop in Mei-long-jie-xin village. Anaerobically digested effluent is post-treated through sedimentation, coagulation and solid/liquid separation. The COD concentration in the final effluent is already less than 350 mg/l, which could meet the requirements of the national wastewater discharge standards. In addition, separated fermentation sludge could be used as fish feed. The construction of this biogas installation started in October 1987 and was put into operation during the Chinese New Year, 1989. Initially, 230 households were connected but increased to 400 households by July of the same year. Based on this plan, by November 1990 a total of 500 households was expected to use biogas. This biogas plant is a measure to implement pollution control and re-utilize resources with considerable economic and social benefits. The successful construction of this demonstration biogas plant paved the way to extending biogas technology to suburban areas near big cities. (orig.)

  17. Budesonide and fluticasone propionate differentially affect the airway epithelial barrier

    NARCIS (Netherlands)

    Heijink, I H; Jonker, M.R.; de Vries, M; van Oosterhout, A J M; Telenga, E; Ten Hacken, N H T; Postma, D S; van den Berge, M

    2016-01-01

    BACKGROUND: COPD patients have a higher risk of pneumonia when treated with fluticasone propionate (FP) than with placebo, and a lower risk with budesonide (BUD). We hypothesized that BUD and FP differentially affect the mucosal barrier in response to viral infection and/or cigarette smoke. METHODS:

  18. Budesonide and fluticasone propionate differentially affect the airway epithelial barrier

    NARCIS (Netherlands)

    Heijink, I. H.; Jonker, M.R.; Vries, de Maaike; van Oosterhout, A. J. M.; Telenga, E.; ten Hacken, N. H. T.; Postma, D. S.; van den Berge, M.

    2016-01-01

    Background: COPD patients have a higher risk of pneumonia when treated with fluticasone propionate (FP) than with placebo, and a lower risk with budesonide (BUD). We hypothesized that BUD and FP differentially affect the mucosal barrier in response to viral infection and/or cigarette smoke. Methods:

  19. Response of preschool children with asthma symptoms to fluticasone propionate

    DEFF Research Database (Denmark)

    Roorda, R J; Mezei, G; Bisgaard, H;

    2001-01-01

    BACKGROUND: Many uncertainties remain in the diagnosis and treatment of preschool children with asthma symptoms. OBJECTIVE: We sought to determine the subgroups of preschool children (aged 12-47 months) with recurrent asthma symptoms most likely to respond to inhaled fluticasone propionate (200...... the management of preschool children with recurrent asthma symptoms....

  20. Moving bed filter for absorbing hydrogen sulphide from biogas. Filtro de lecho movil para absorber el sulphidrico del biogas

    Energy Technology Data Exchange (ETDEWEB)

    Bou, J.

    1994-01-01

    The main aim of this demonstration project is the absorption of hydrogen sulphide from the biogas-produced in a sewage plant-through a practical system which does not require constant attention, nor significant labour for the loading and unloading of the iron oxides; and the use of the biogas, when it has been purified, in thermal and cogeneration engine applications. The demonstration installation comprises a filter with a movable bed, of pyramid/trunk shape, with a square base, having a capacity of 1,000 litres, plus the two items needed for working with it: a lower and an upper hopper, for the loading and unloading of iron-oxide agglomerates. The purified biogas is used in a cogeneration unit comprising four TOTEM-FIAT sets generating 12.5 kWh of electrical power and 36.78 thermal kW each. Completing the project is a system which receives and stores the data from the range of variables monitored. The results obtained-the H[sub 2] content at the outlet from the lower filter at 300 ppm, sulphur absorption of 30% by wight in the iron oxide agglomerates, agglomerates replacement cost of 0.77 pesetas; m''3 , and 2.47-year-pay-back- confirm the viability of the process, and resure the application of this system in other sewage treatment plants. (Author)

  1. Assessment of biogas production in Argentina from co-digestion of sludge and municipal solid waste.

    Science.gov (United States)

    Morero, Betzabet; Vicentin, Rocio; Campanella, Enrique A

    2016-12-07

    In Argentina, there is an important potential to utilize organic waste to generate bioenergy. This work analyzes the environmental impacts and the energetic and economic requirements of the biogas produced by digesting the sewage sludge (SS) produced in a wastewater treatment plant in a medium city in Argentina. The SS is co-digested with the organic fraction of municipal solid waste (OFMSW), and the basis of this study is the life cycle assessment (LCA). The LCA is performed according to ISO 14040-44 using the SimaPro simulator. First, the transport of the raw materials to the biogas plant was defined. Then, the co-digestion and the biogas treatment for final use were evaluated. The co-digestion was improved with glycerol, and the generation of biogas was estimated using the GPS-X software. Two alternatives for the end use of biogas were considered: combined heat and power (CHP) and biomethane generation. For the first, H2S and water vapor were removed from the raw biogas stream, and for the second, also CO2 was removed. The H2S removal process was simulated in the SuperPro software by anaerobic biofiltration. The same software was used to simulate the removal of CO2 absorption-desorption with water as solvent. Finally, the environmental impacts related to the end use of biogas (CHP and biomethane) were evaluated. The environmental, energetic and economic analyses showed that the co-digestion of SS and OFMSW has great potential for reducing the environmental impacts and increasing the economic and energetic value of the substances via the production of biomethane, electricity and, potentially, fertilizer.

  2. Biogas Production from Thin Stillage on an Industrial Scale—Experience and Optimisation

    Directory of Open Access Journals (Sweden)

    Anna Schnürer

    2013-10-01

    Full Text Available With the increasing demand for renewable energy and sustainable waste treatment, biogas production is expanding. Approximately four billion litres of bio-ethanol are produced annually for vehicle fuel in Europe, resulting in the production of large amounts of stillage residues. This stillage is energy-rich and can be used for biogas production, but is a challenging substrate due to its high levels of nitrogen and sulphate. At the full-scale biogas production plant in Norrköping, Sweden (Svensk Biogas i Linköping AB, thin grain stillage is used as a biogas substrate. This paper describes the plant operation and strategies that have been implemented to digest thin stillage successfully. High ammonia concentrations in the digester have resulted in syntrophic acetate oxidation (SAO becoming the major pathway for acetate degradation. Therefore, a long hydraulic retention time (HRT (40–60 days is used to allow the syntrophic acetate-oxidising bacteria time to grow. The high sulphate levels in thin stillage result in high levels of hydrogen sulphide following degradation of protein and the activity of sulphate-reducing bacteria (SRB, the presence of which has been confirmed by quantitative polymerase chain reaction (qPCR analysis. To optimise biogas production and maintain a stable process, the substrate is diluted with tap water and co-digested with grain residues and glycerine to keep the ammonium nitrogen (NH4-N concentration below 6 g L−1. Combined addition of iron, hydrochloric acid and cobalt successfully precipitates sulphides, reduces ammonia toxicity and supplies microorganisms with trace element. Mesophilic temperature (38 °C is employed to further avoid ammonia toxicity. Together, these measures and doubling the digester volume have made it possible to increase annual biogas production from 27.7 TJ to 69.1 TJ.

  3. Production and use of biogas in Europe: a survey of current status and perspectives

    Directory of Open Access Journals (Sweden)

    Massimo Raboni

    2014-04-01

    Full Text Available The article presents the results of a survey carried out in the European Union (EU regarding the production and use of biogas from different sources. The EU is a world leader in the field of biogas, with a production of 10,085.8 ktoe y -1 (in 2011 in terms of primary energy, accounting for about 60% of the world’s production. Germany is the EU country that has made the greatest progress in this field with a production of as much as 5,067.6 ktoe y-1 , of which a share of 4,414.2 ktoe y-1 results from anaerobic digestion (and co-digestion processes of selected organic matrices. UK is the second largest producer with 1,764.8 ktoe y -1 , determined for 84% by landfill biogas and the remainder by biogas produced in sewage treatment plants (sludge digestion. Italy (1,095.7 ktoe y-1 and France (349.6 ktoe y -1 follow in the list of the largest producers. The trend of biogas production, in accordance with the action lines of the EU, is characterized by a progressive increase from anaerobic digestion (and co-digestion of selected organic matrices and a progressive decrease from landfills. Production in 2020 is estimated at 28.0 Mtoe y-1 in accordance with the EU Renewable Energy National Plans. The uses of biogas are mainly directed to the production of electricity and heat. There are, however, several cases of conversion of biogas into biomethane injected into the natural gas grids or used as biofuel in vehicles. In this last direction, worthy of note are a few north-central EU countries which have implemented an effective policy to promote the use of biomethane for public and private transport.

  4. 75 FR 78243 - Propionic Acid and Salts, Urea Sulfate, Methidathion, and Methyl Parathion; Registration Review...

    Science.gov (United States)

    2010-12-15

    ... AGENCY Propionic Acid and Salts, Urea Sulfate, Methidathion, and Methyl Parathion; Registration Review... pesticides propionic acid and salts, case no. 4078, urea sulfate, case no. 7213, methidathion, case no. 0034... pesticides in the table below--propionic acid and salts, case 4078, urea sulfate, case no. 7213,...

  5. Formation and suppression of foam in biogas plants; Bildung von Schaum in Biogasanlagen und seine Bekaempfung

    Energy Technology Data Exchange (ETDEWEB)

    Moeller, Lucie [Helmholtz-Zentrum fuer Umweltforschung, Leipzig (Germany); Goersch, Kati; Zehnsdorf, Andreas

    2012-07-01

    Excessive foaming in the process of anaerobic digestion is one of the most common disorders of the biological stage of the biogas production process. Especially biogas plants treating biogenic residues and waste materials are affected. A survey of fifteen operators of waste-utilizing biogas plants in Saxony, Saxony-Anhalt and Thuringia showed that 80 % of the operators have already had problems with excessive foam formation in their biogas reactor. More than half of them complained about regular foam events. The consequences of excessive foam formation may vary depending on the extent of foaming. They range from extra costs for anti-foaming agents to cleaning and repair costs in case of construction defects. Foam in the reactor may have many causes. They involve the careless application of risk substrates, inadequate plant management or technical errors and accidents. Mostly, the direct cause of foaming remains unclear. Although foam formation in the biogas reactor is a very common phenomenon, only little research has been done in this field until now. (orig.)

  6. Steam pretreatment of spruce forest residues: optimal conditions for biogas production and enzymatic hydrolysis.

    Science.gov (United States)

    Janzon, Ron; Schütt, Fokko; Oldenburg, Saskia; Fischer, Elmar; Körner, Ina; Saake, Bodo

    2014-01-16

    Steam refining of non-debarked spruce forest residues was investigated as pretreatment for enzymatic hydrolysis as well as for biogas production. Pretreatment conditions were varied in the range of 190-220 °C, 5-10 min and 0-3.7% SO₂ according to a statistical design. For both applications highest product yields were predicted at 220 °C and 2.4% SO₂, whereas the reaction time had only a minor influence. The conformity of the model results allows the conclusion that enzymatic hydrolysis is a suitable test method to evaluate the degradability of lignocellulosic biomass in the biogas process. In control experiments under optimal conditions the results of the model were verified. The yield of total monomeric carbohydrates after enzymatic hydrolysis was equivalent to 55% of all theoretically available polysaccharides. The corresponding biogas yield from the pretreated wood amounted to 304 mL/gODM. Furthermore, furans produced under optimal process conditions showed no inhibitory effect on biogas production. It can be concluded that steam refining opens the structure of wood, thus improving the enzymatic hydrolysis of the polysaccharides to fermentable monomeric sugars and subsequently enabling a higher and faster production of biogas. Anaerobic fermentation of pretreated wood is a serious alternative to alcoholic fermentation especially when low quality wood grades and residues are used. Anaerobic digestion should be further investigated in order to diversify the biorefinery options for lignocellulosic materials.

  7. Vitreous membranes used in the biogas purification; Membranas vitreas empleadas en la purificacion de biogas

    Energy Technology Data Exchange (ETDEWEB)

    Ortega Viera, L.; Rodriguez Munoz, S.; Fernandez Santana, E.; Martines Ramirez, Y.; Crespo Artigas, A.; Viera Gallardo, Y.

    2016-05-01

    In the present work 10 vitreous membranes with different masses of zinc oxide (ZnO(s)) and particle diameters charcoal (DPC) are used in the purification of biogas. The porosity and tortuosity of the membranes is obtained, showing the variation with respect to the composition thereof. From these structural features specific flow of H{sub 2}S(g) is obtained which is transferred using the Fick's diffusion equation in the membranes and its value increases with increasing mass of ZnO(s). By X-ray diffraction membrane made with 3.16 g of ZnO(s) forming zinc sulfide it is shown, so we can say that the removal of H{sub 2}S(g) occurs by a process of absorption with chemical reaction in the membranes. (Author)

  8. Biogas composition and engine performance, including database and biogas property model

    NARCIS (Netherlands)

    Bruijstens, A.J.; Beuman, W.P.H.; Molen, M. van der; Rijke, J. de; Cloudt, R.P.M.; Kadijk, G.; Camp, O.M.G.C. op den; Bleuanus, W.A.J.

    2008-01-01

    In order to enable this evaluation of the current biogas quality situation in the EU; results are presented in a biogas database. Furthermore the key gas parameter Sonic Bievo Index (influence on open loop A/F-ratio) is defined and other key gas parameters like the Methane Number (knock resistance)

  9. The production and use of biogas in 2012; Produktion och anvaendning av biogas aar 2012

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-07-01

    This report presents an annual survey on the production and use of biogas. The survey aims to provide policy makers, industry associations, researchers, journalists, municipalities and the general public information on annual production and use of biogas. Statistics are used as the basis for Sweden's overall reporting of renewable energy to the EU and as a basis in various government investigations. In the present study, a total of 242 biogas-production plants have been identified in Sweden. These produced a total of 1,589 GWh of energy. The 242 biogas-producing plants were distributed by 135 wastewater treatment plants, 55 landfills, 26 farm biogas plants, 21 co-digestion plants and five industrial plants. The main substrates for biogas production were different types of waste such as sewage sludge, manure, source separated food waste and waste from butchers and food industries. Energy crops constituted a very small fraction of the total substrate similarly no. The geographic distribution shows that most of the biogas production was centered in a few counties. Skaane, Stockholm and Vaestra Goetaland accounted for over 50 % of the country's biogas production.

  10. Eliminating methanogenic activity in hydrogen reactor to improve biogas production in a two-stage anaerobic digestion process co-digesting municipal food waste and sewage sludge.

    Science.gov (United States)

    Zhu, Heguang; Parker, Wayne; Conidi, Daniela; Basnar, Robert; Seto, Peter

    2011-07-01

    Laboratory scale two-stage anaerobic digestion process model was operated for 280 days to investigate the feasibility to produce both hydrogen and methane from a mixture feedstock (1:1 (v/v)) of municipal food waste and sewage sludge. The maximum hydrogen and methane yields obtained in the two stages were 0.93 and 9.5 mL/mL feedstock. To eliminate methanogenic activity and obtain substantial hydrogen production in the hydrogen reactor, both feedstock and mixed liquor required treatment. The heat treatment (100°C, 10 min) for feedstock and a periodical treatment (every 2-5 weeks, either heating, removal of biomass particles or flushing with air) for mixed liquor were effective in different extent. The methane production in the second stage was significantly improved by the hydrogen production in the first stage. The maximum methane production obtained in the period of high hydrogen production was more than 2-fold of that observed in the low hydrogen production period.

  11. Generation of electric power from biogas originating from sewage treatment; Geracao de energia eletrica a partir do biogas proveniente do tratamento de esgoto

    Energy Technology Data Exchange (ETDEWEB)

    Coelho, Suani Teixeira; Velazquez, Silvia Maria Stortini Gonzalez; Silva, Orlando Cristiano da; Pecora, Vanessa; Abreu, Fernando Castro de [Universidade de Sao Paulo (CENBIO/IEE/USP), Sao Paulo, SP (Brazil). Inst. de Eletrotecnica e Energia. Centro Nacional de Referencia em Biomassa], e-mails: suani@iee.usp.br, sgvelaz@iee.usp.br, gbntumbo@iee.usp.br, vpecora@iee.usp.br, fcabreu@iee.usp.br

    2006-07-01

    The main objective of the effluent treatment is to correct its undesirable characteristics, however, during this process, residues like sludge and biogas are generated, and those residues can be used as raw materials The PUREFA (Program of Rational Energy Use and Alternative Sources), compound by 14 purposes, is about a project of the USP - University of Sao Paulo, financial backer FINEP - Financier of Studies and Projects. This project had three main objectives: to implant measures of management and action of energy efficiency, to increase the distributed generation in the USP from the renewable resource and not conventional energy and to introduce incentive permanent politics to the efficient and rational use of energy. In the context, the Brazilian Reference Center on Biomass was responsible for two purposes, related to the biogas use for electricity generation. The first purpose had main objective to implant the generation system, to capture and to stock the biogas, produced by biodigester in the Technological Hydraulically Center (CTH - USP). The biodigester is a UASB (Upflow Anaerobic Sludge Blanket), whose outflow of the biogas produce is near 4 m{sup 3}/day, opera rates 24 hours per day and utilize the sewer from the residential buildings located in Sao Paulo University, inside the campus. For the biogas utilization, was made its outflow, chemical composition and heat value identifications, parameters that allowed to determinate the real potential for generation and to shown the necessity of the previous treatment, as H{sub 2}S removal. Finished this stage, was started the next purpose, regarding biogas used as fuel for electricity generation using a generator group Otto cycle. Nowadays this project is a demonstrative project. In this article the technical and environmental project results obtained will be presented. (author)

  12. Techno-economical study of biogas production improved by steam explosion pretreatment.

    Science.gov (United States)

    Shafiei, Marzieh; Kabir, Maryam M; Zilouei, Hamid; Sárvári Horváth, Ilona; Karimi, Keikhosro

    2013-11-01

    Economic feasibility of steam explosion pretreatment for improvement of biogas production from wheat straw and paper tube residuals was investigated. The process was simulated by Aspen plus ®, and the economical feasibility of five different plant capacities was studied by Aspen Process Economic Analyzer. Total project investment of a plant using paper tube residuals or wheat straw was 63.9 or 61.8 million Euros, respectively. The manufacturing cost of raw biogas for these two feedstocks was calculated to 0.36 or 0.48 €/m(3) of methane, respectively. Applying steam explosion pretreatment resulted in 13% higher total capital investment while significantly improved the economy of the biogas plant and decreased the manufacturing cost of methane by 36%. The sensitivity analysis showed that 5% improvement in the methane yield and 20% decrease in the raw material price resulted in 5.5% and 8% decrease in the manufacturing cost of methane, respectively.

  13. Behaviour of pathogenic microorganisms and parasites in biogas production from sewage sludge and municipal wastes

    Energy Technology Data Exchange (ETDEWEB)

    Walter-Matsui, R.; Seipp, M.

    With a grant from VW-Stiftung a project was investigated by the 'Medizinisches Zentrum fuer Hygiene, Philipps-Universitaet, Marburg' and the 'Faculty of Agriculture, Fayum, University Cairo'. The aim was to modify the biogas process to get an optimal amount of biogas and to kill the pathogen bacteria at the same time. The effect of different materials, for example, plant wastes, sewage sludge, cow dung and town refuse and their various amounts of dry matters (2% - 16%) were tested. Also the bactericidal effects of pH, Lactobacilli and higher temperatures were checked. It was found that only a pasteurisation before the fermentation decontaminate the sludge without declining amounts of biogas. It was also proved that the development of Schistosoma eggs was interrupted by the fermentation process.

  14. Bioethanol, biohydrogen and biogas production from wheat straw in a biorefinery concept

    DEFF Research Database (Denmark)

    Kaparaju, Prasad Laxmi-Narasimha; Serrano, Maria; Thomsen, Anne Belinda

    2009-01-01

    The production of bioethanol, biohydrogen and biogas from wheat straw was investigated within a biorefinery framework. Initially, wheat straw was hydrothermally liberated to a cellulose rich fiber fraction and a hemicellulose rich liquid fraction (hydrolysate). Enzymatic hydrolysis and subsequent......, multiple biofuels production from wheat straw can increase the efficiency for material and energy and can presumably be more economical process for biomass utilization. (C) 2008 Elsevier Ltd. All rights reserved........ Additionally, evaluation of six different wheat straw-to-biofuel production scenaria showed that either use of wheat straw for biogas production or multi-fuel production were the energetically most efficient processes compared to production of mono-fuel such as bioethanol when fermenting C6 sugars alone. Thus......The production of bioethanol, biohydrogen and biogas from wheat straw was investigated within a biorefinery framework. Initially, wheat straw was hydrothermally liberated to a cellulose rich fiber fraction and a hemicellulose rich liquid fraction (hydrolysate). Enzymatic hydrolysis and subsequent...

  15. Industrial scale garage-type dry fermentation of municipal solid waste to biogas.

    Science.gov (United States)

    Qian, M Y; Li, R H; Li, J; Wedwitschka, H; Nelles, M; Stinner, W; Zhou, H J

    2016-10-01

    The objectives of this study was to through monitoring the 1st industrial scale garage-type dry fermentation (GTDF) MSW biogas plant in Bin County, Harbin City, Heilongjiang Province, China, to investigate its anaerobic digestion (AD) performance and the stability of process. After a monitoring period of 180days, the results showed that the volumetric biogas production of the digesters and percolate tank was 0.72 and 2.22m(3) (m(3)d)(-1), respectively, and the specific biogas yield of the feedstock was about 270m(3)CH4tVS(-1), which indicated that the GTDF is appropriate for the Chinese MSW. This paper also raised some problems aimed at improving the process stability and AD efficiency.

  16. Anaerobic digestion technology in livestock manure treatment for biogas production: a review

    Energy Technology Data Exchange (ETDEWEB)

    Nasir, Ismail M. [Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Selangor (Malaysia); Mohd Ghazi, Tinia I.; Omar, Rozita

    2012-06-15

    This article reviews the potential of anaerobic digestion (AD) for biogas production from livestock manure wastes and compares the operating and performance data for various anaerobic process configurations. It examines different kinds of manure waste treatment techniques and the influence of several parameters on biogas and methane yield. The comparison indicates that a variety of different operational conditions, various reactor configurations such as batch reactors, continuously stirred tank reactor (CSTR), plug flow reactor (PFR), up-flow anaerobic sludge blanket (UASB), anaerobic sequencing batch reactor (ASBR), temperature phased anaerobic digestion (TPAD), and continuous one- and two-stage systems, present a suitable technology for the AD of livestock manure waste. Main performance indicators are biogas and methane yield, degradation of volatile solids (VS), higher loading, and process stability with a short retention time. (copyright 2012 WILEY-VCH Verlag GmbH 8 Co. KGaA, Weinheim)

  17. Unit installation and testing of demonstration of electric power generation using biogas from sewage treatment; Instalacao e testes de uma unidade de demonstracao de geracao de energia eletrica a partir de biogas de tratamento de esgoto

    Energy Technology Data Exchange (ETDEWEB)

    Coelho, Suani Teixeira; Gonzalez Velazquez, Silvia Maria Stortini; Martins, Osvaldo Stella; Costa, David Freire da; Basaglia, Fernando [Centro Nacional de Referencia em Biomassa (CENBIO), Sao Paulo, SP (Brazil)], e-mail: suani@iee.usp.br, e-mail: sgvelaz@iee.usp.br, e-mail: omartins@iee.usp.br, e-mail: davidcosta@iee.usp.br, e-mail: basaglia@iee.usp.br; Bacic, Antonio Carlos K. [Companhia de Saneamento Basico do Estado de Sao Paulo (SABESP), SP (Brazil)], e-mail: acbacic@sabesp.com.br

    2004-07-01

    This article intend to discuss the electricity generation with 30 kW (ISO) micro turbines, using biogas generated by sewage treatment process at SABESP (Basic Sanitation Company of Sao Paulo State), located at Barueri, Brazil. This project, pioneer in Latin America, is being accomplished together with BUN - Biomass Users Network of Brazil (proponent), by CENBIO - Brazilian Reference Center on Biomass (executer), with patronage of FINEP / CT-ENERG (financial backer), by means of COVENAT No: 23.01.0653.00, regarding to ENERG-BIOG Project - 'Installation and Tests of an Electric Energy Generation Demonstration Unit from Biogas Sewage Treatment'. This plant operates with anaerobic digestion process, which has as mainly products biogas (composed mainly by methane) and sludge. Currently, part of the methane produced is burnt in a boiler used to increase digesters efficiency process. The rest of the methane is burnt in flare to reduce the impacts caused by gases emissions. An alternative to flare it is the biogas conversion into electricity through engines and micro turbines. Thus, this article presents the project results, related with the exploitation of sewer biogas for power generation, as well as bigger details about purification, compression and electricity generation systems (biogas micro turbine), used in the facility. (author)

  18. The Local Initiator Role in the Adoption of Biogas Energy Innovation for Household Needs in Rural Areas

    Directory of Open Access Journals (Sweden)

    Hartiningsih

    2016-11-01

    Full Text Available The need for Kerosene is very high. When energy crisis hit Indonesia, it caused the scarcity and soaring prices of kerosene. Hence, finding alternative energy sources is needed, especially a renewable energy to households. One is which is Biogas energy. Biogas is an energy that uses simple technology, which uses raw materials of animal waste. Many rural communities do not know about it, so it requires a pioneer, called the local initiator. The local initiator is an agent of change that comes from the local community, who has the initiative to make changes and become a guide passage of the change process in an organization or community, in order to achieve the expected goals. Local initiator becomes an important factor in the success of biogas innovation adoption. Biogas is used for household needs such as cooking, water heating, and lighting. Biogas program has been reinforced by Presidential Decree No 5 of 2006, Minister of ESDM Regulation (Permen ESDM No 3 of 2013, Permen ESDM No 10 of 2015, and Minister of Rural Affairs Regulation (Permen Desa No 5 of 2015. This paper aims to examine the role of a local initiator as an agent of change and the most dominant factors in the successful adoption of biogas for the needs of rural households. This study uses a qualitative method by using a case study approach and conducting a descriptive analysis. The focus of the data analysis is only performed on the local initiator in the successful adoption of biogas in Haurngombong village in West Java and Pandua-North Lombok, NTB. The result of the study shows that the successful adoption of biogas in Haurngombong Village and Pandua Village is strongly influenced by the local initiator. The local initiator success is not determined by the position, age, and gender, but is determined by the experience in the use of biogas, biogas sector knowledge, dissemination strategies, and communication among stakeholders of biogas program. The key to the success of local

  19. Use of sewage treatment biogas for electric generation using an 30 kW (ISO); Uso do biogas de tratamento de esgoto, para geracao de energia eletrica, utilizando-se de uma microturbina de 30 kW (ISO)

    Energy Technology Data Exchange (ETDEWEB)

    Coelho, Suani T.; Velazquez, Silvia M.S.G.; Martins, Osvaldo S.; Costa, David F. [Centro Nacional de Referencia em Biomassa (CENBIO), Sao Paulo, SP (Brazil); Bacic, Antonio C.K. [Companhia de Saneamento Basico do Estado de Sao Paulo (SABESP), SP (Brazil)

    2004-07-01

    This paper intends to present some considerations directed to electricity generation with 30 kW (ISO) micro turbines, using biogas generated by sewage treatment process in SABESP (Basic Sanitation Company of Sao Paulo State), located at Barueri, Brazil. This project, pioneer in Latin America, is being accomplished together with BUN - Biomass Users Network of Brazil (proponent), in association with CENBIO - The Brazilian Reference Center on Biomass (executer), with patronage of FINEP / CT-ENERG (financial backer), by means of ACCORD No: 23.01.0653.00, regarding to ENERG-BIOG Project - 'Installation and Tests of an Electric Energy Generation Demonstration Unit from Biogas Sewage Treatment'. Thus, the contribution of this paper will be in the presentation of the project results, related with the exploitation of sewer biogas for power generation, as well as bigger details about purification, compression and electricity generation systems (biogas micro turbine) used in the installation. (author)

  20. Optimized construction of biogas plants; Optimierte Bauweise fuer Biogasanlagen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-09-19

    Within the conference of the International Trade Fair for Biogas Plant Technology at 21st February, 2012 in Berlin, the following lectures were held: (1) Optimized dimensions of containers for small systems of liquid manure (Manfred Thalmann); (2) Microferm mini biogas plants (Bart Brouwer); (3) Fermentation of stackable biomass in rural biogas plant - The DeNaBa system (Christian Deterding); (4) The Sauter Biogas System for the fermentation of liquid manure, solid dung, and other residual materials (Stefan Sauter); (5) Bio-electricity: Controllable power generation by means of biogas plants (Matthias Sonnleitner); (6) Reduction of the effort and increase of the yield using UDR fixed bed technology (Alfred van den Berg); (7) Prestressed concrete container for biogas plants: Area of application - quality - options (Harald Feldmann); (8) Corrosion protection of agricultural and communal biogas plants (Michael Normann); (9) Fundamentals of efficient and effective flow generation in biogas plants (Kay Rotalski); (10) Rotary piston screw pistons and eccentric screw pumps (Thorsten Gilles).

  1. Degradation and detoxification of tar water from a gasification plant in a biogas reactor

    Energy Technology Data Exchange (ETDEWEB)

    Angelidaki, I.; Torry-Smith, M.; Petersen, L.; Ahring, B.K. [Denmarks Technical Univ., Dept. of Environmental Science and Engineering, Lyngby (Denmark)

    1998-08-01

    During gasification of biomass, toxic tar and tar-water (TW) are produced. The produced TW is saturated by soluble phenolic compound. In this project we have attempted detoxification of the produced TW by either wet oxidation where the TW is heated under pressure and addition of excess oxygen, and then subsequent treatment of the formed wet oxidized product in a biogas reactor. Alternatively, we treated the TW directly in a biogas reactor. Reduction in phenolic compounds, which constitute the major toxic compounds in TW, was used as a success parameter evaluating the detoxification of TW. The TW could successfully be degraded in a biogas reactor when co-digested with manure at a concentration up to 5%. Wet oxidized tar water (WOTW) could be degraded when added at a concentration of 30%. A biogas potential of approx. 0.19 L CH/g-VS was achieved for both the TW and WOTW. The biogas production per kg waste was 30 and 10 L CH/kg waste for the TW and the WOTW, respectively. The reason for the much lower methane production of the WOTW was that a large part of the organic content of the TW was converted to carbon dioxide during the wet oxidation process. The effluent concentrations of phenolic were in all cases much lower than the concentrations found in normally in undigested manure, showing that biomethanation of toxic wastes in co-digestion with manure could be an easy and cheap way to detoxify specific toxic wastes. (au)

  2. Energy performance and greenhouse gas emissions of kelp cultivation for biogas and fertilizer recovery in Sweden.

    Science.gov (United States)

    Pechsiri, Joseph S; Thomas, Jean-Baptiste E; Risén, Emma; Ribeiro, Mauricio S; Malmström, Maria E; Nylund, Göran M; Jansson, Anette; Welander, Ulrika; Pavia, Henrik; Gröndahl, Fredrik

    2016-12-15

    The cultivation of seaweed as a feedstock for third generation biofuels is gathering interest in Europe, however, many questions remain unanswered in practise, notably regarding scales of operation, energy returns on investment (EROI) and greenhouse gas (GHG) emissions, all of which are crucial to determine commercial viability. This study performed an energy and GHG emissions analysis, using EROI and GHG savings potential respectively, as indicators of commercial viability for two systems: the Swedish Seafarm project's seaweed cultivation (0.5ha), biogas and fertilizer biorefinery, and an estimation of the same system scaled up and adjusted to a cultivation of 10ha. Based on a conservative estimate of biogas yield, neither the 0.5ha case nor the up-scaled 10ha estimates met the (commercial viability) target EROI of 3, nor the European Union Renewable Energy Directive GHG savings target of 60% for biofuels, however the potential for commercial viability was substantially improved by scaling up operations: GHG emissions and energy demand, per unit of biogas, was almost halved by scaling operations up by a factor of twenty, thereby approaching the EROI and GHG savings targets set, under beneficial biogas production conditions. Further analysis identified processes whose optimisations would have a large impact on energy use and emissions (such as anaerobic digestion) as well as others embodying potential for further economies of scale (such as harvesting), both of which would be of interest for future developments of kelp to biogas and fertilizer biorefineries.

  3. Influence of DNA isolation method on the investigation of archaeal diversity and abundance in biogas plants.

    Science.gov (United States)

    Theiss, Juliane; Rother, Michael; Röske, Kerstin

    2016-09-01

    Various methods are available for DNA isolation from environmental samples. Because the chemical and biological composition of samples such as soil, sludge, or plant material is different, the effectiveness of DNA isolation can vary depending on the method applied and thus, have a substantial effect on the results of downstream analysis of the microbial community. Although the process of biogas formation is being intensely investigated, a systematic evaluation of kits for DNA isolation from material of biogas plants is still lacking. Since no DNA isolation kit specifically tailored for DNA isolation from sludge of biogas plants is available, this study compares five commercially available kits regarding their influence on downstream analyses such denaturing gradient gel electrophoresis (DGGE) and quantitative real-time PCR (qPCR). The results show that not all kits are equally suited for the DNA isolation from samples of different biogas plants, but highly reproducible DGGE fingerprints as well as qPCR results across the tested samples from biogas reactors using different substrate compositions could be produced using selected kits.

  4. Where does the removal of H₂S from biogas occur in microaerobic reactors?

    Science.gov (United States)

    Ramos, I; Peña, M; Fdz-Polanco, M

    2014-08-01

    In order to maximise the efficiency of biogas desulphurisation and reduce the oxygen cost during microaerobic digestion, it is essential to know how the process occurs. For this purpose, a reactor with a total volume of 266 L, treating 10 L/d of sewage sludge, was operated with 25.0 L and without headspace. Under anaerobic conditions, the H2S concentration in the biogas varied between 0.21 and 0.38%v/v. Next, O2 was supplied from the bottom of the reactor. At 0.25-0.30 NLO₂/Lfed, the biogas was entirely desulphurised, and its O₂ content remained below 1.03%v/v, when the digester had 25.0 L of gas space. However, with almost no headspace, the H2S content in the biogas fluctuated from 0.08 to 0.21%v/v, while the average O2 concentration was 1.66%v/v. The removed H2S accumulated in the outlet pipe of the biogas in the form of S(0) due to the insufficient headspace.

  5. Modelling the Potential Biogas Productivity Range from a MSW Landfill for Its Sustainable Exploitation

    Directory of Open Access Journals (Sweden)

    Elena Cristina Rada

    2015-01-01

    Full Text Available A model of biogas generation was modified and applied to the case of a sanitary landfill in Italy. The modifications considered the role of the temperature field normally established within each layer of waste. It must be pointed out the temperature affects the anaerobic biodegradation kinetics. In order to assess the effect of moisture on the waste biodegradation rate, on the bacteria process and then on the methane production, the model was compared with the LandGEM one. Information on the initial water content came from data concerning waste composition. No additional information about the hydrological balance was available. Thus, nine sets of kinetic constants, derived by literature, were adopted for the simulations. Results showed a significant variability of the maximal hourly biogas flows on a yearly basis, with consequences for the collectable amount during the operating period of a hypothetical engine. The approach is a useful tool to assess the lowest and highest biogas productivity in order to analyze the viability of biogas exploitation for energy purposes. This is useful also in countries that must plan for biogas exploitation from old and new landfills, as a consequence of developments in the waste sector.

  6. The effects of the antibiotics ampicillin, florfenicol, sulfamethazine, and tylosin on biogas production and their degradation efficiency during anaerobic digestion.

    Science.gov (United States)

    Mitchell, Shannon M; Ullman, Jeffrey L; Teel, Amy L; Watts, Richard J; Frear, Craig

    2013-12-01

    The impacts of four common animal husbandry antibiotics (ampicillin, florfenicol, sulfamethazine, and tylosin) on anaerobic digestion (AD) treatment efficiency and the potential for antibiotic degradation during digestion were evaluated. Sulfamethazine and ampicillin exhibited no impact on total biogas production up to 280 and 350 mg/L, respectively, although ampicillin inhibited biogas production rates during early stages of AD. Tylosin reduced biogas production by 10-38% between 130 and 913 mg/L. Florfenicol reduced biogas by ≈ 5%, 40% and 75% at 6.4, 36 and 210 mg/L, respectively. These antibiotic concentrations are higher than commonly seen for mixed feedlot manure, so impacts on full scale AD should be minimal. Antibiotic degradation products were found, confirming AD effectively degraded ampicillin, florfenicol, and tylosin, although some products were persistent throughout the process. Contamination of AD solid and liquid effluents with sulfamethazine and antibiotic transformation products from florfenicol and tylosin could present an environmental concern.

  7. Energy potential and alternative usages of biogas and sludge from UASB reactors: case study of the Laboreaux wastewater treatment plant.

    Science.gov (United States)

    Rosa, A P; Conesa, J A; Fullana, A; Melo, G C B; Borges, J M; Chernicharo, C A L

    2016-01-01

    This work assessed the energy potential and alternative usages of biogas and sludge generated in upflow anaerobic sludge blanket reactors at the Laboreaux sewage treatment plant (STP), Brazil. Two scenarios were considered: (i) priority use of biogas for the thermal drying of dehydrated sludge and the use of the excess biogas for electricity generation in an ICE (internal combustion engine); and (ii) priority use of biogas for electricity generation and the use of the heat of the engine exhaust gases for the thermal drying of the sludge. Scenario 1 showed that the electricity generated is able to supply 22.2% of the STP power demand, but the thermal drying process enables a greater reduction or even elimination of the final volume of sludge to be disposed. In Scenario 2, the electricity generated is able to supply 57.6% of the STP power demand; however, the heat in the exhaust gases is not enough to dry the total amount of dehydrated sludge.

  8. Study of biogas storage; Biogas no chozo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, I.; Kimura, T.; Umeda, H. [Meiji University, Tokyo (Japan)

    1997-11-25

    Study was made on the storage method of a methane component in biogas mainly composed of CO2 and methane gases. Methane clathrate as molecular complex is one kind of clathrate compounds. Eight methane gas molecules are absorbed into 46 water molecules, or methane gas of 216 l is absorbed into water of 1 l, resulting in considerable compact methane storage. Although methane clathrate is usually stable only under a condition of low temperature and high pressure, its formation equilibrium shifts toward a low pressure/high temperature side by adding additives such as amine, ether and ketone. Acetone can shift formation pressure from 30 to 10atm at 1degC, and formation temperature from 1 to 10degC at 30atm. Although methane liquefaction is also an efficient storage method, it requires liquefaction temperature and pressure of -83degC and 45.6atm, respectively. The distance between methane molecules in clathrate lattice can be more shortened than that in high- pressure charged gas, suggesting higher storage efficiency. The study result showed that the handling of methane clathrate is possible around room temperature and pressure. 7 refs., 5 figs.

  9. State of development of biogas production in Europe

    OpenAIRE

    Torrijos, Michel

    2016-01-01

    The share of renewable energies in electricity production is still low in Europe but there is a political will to increase it in the future by the development of solar and wind energies but also by the development of electricity production from biogas. Biogas production from solid waste is developing in Europe but with important differences between countries. Germany is from far the country where biogas industry is the most developed with 62% of the European biogas plants. However, the latest...

  10. H2S removal from biogas using bioreactors: a review

    Directory of Open Access Journals (Sweden)

    E. Dumont

    2015-01-01

    Full Text Available This review aims to provide an overview of the bioprocesses used for the removal of H2S from biogas. The ability of aerobic and anoxic bioreactors (biotrickling filters, bioscrubbers, and a combination of chemical scrubbers and bioreactors to perform the degradation of H2S is considered. For each operating mode (aerobic and anoxic, the bioprocesses are presented, the operating conditions affecting performance are summarized, the state of the art of research studies is described and commercial applications are given. At laboratory-scale, whatever their operating mode, biological processes are effective for biogas cleaning and provide the same performance. The clogging of the packed bed due to the deposit of elemental sulfur S0 and biomass accumulation clearly represents the main drawback of bioprocesses. Although elimination capacities (EC determined at laboratory-scale can be very high, EC should not be higher than 90 g m-3 h-1 at industrial-scale in order to limit clogging effects. For aerobic processes, the need to control the oxygen mass transfer accurately remains a key issue for their development at full-scale. As a result, the aerobic processes alone are probably not the most suitable bioprocesses for the treatment of biogas highly loaded with H2S. For anaerobic bioprocesses using nitrate as an electron acceptor, the scale-up of the laboratory process to a full-size plant remains a challenge. However, the use of wastewater from treatment plants, which constitutes a cheap source of nitrates, represents an interesting opportunity for the development of innovative bioprocesses enabling the simultaneous removal of H2S and nitrates.

  11. Characterization of a biogas-producing microbial community by short-read next generation DNA sequencing

    Directory of Open Access Journals (Sweden)

    Wirth Roland

    2012-07-01

    Full Text Available Abstract Background Renewable energy production is currently a major issue worldwide. Biogas is a promising renewable energy carrier as the technology of its production combines the elimination of organic waste with the formation of a versatile energy carrier, methane. In consequence of the complexity of the microbial communities and metabolic pathways involved the biotechnology of the microbiological process leading to biogas production is poorly understood. Metagenomic approaches are suitable means of addressing related questions. In the present work a novel high-throughput technique was tested for its benefits in resolving the functional and taxonomical complexity of such microbial consortia. Results It was demonstrated that the extremely parallel SOLiD™ short-read DNA sequencing platform is capable of providing sufficient useful information to decipher the systematic and functional contexts within a biogas-producing community. Although this technology has not been employed to address such problems previously, the data obtained compare well with those from similar high-throughput approaches such as 454-pyrosequencing GS FLX or Titanium. The predominant microbes contributing to the decomposition of organic matter include members of the Eubacteria, class Clostridia, order Clostridiales, family Clostridiaceae. Bacteria belonging in other systematic groups contribute to the diversity of the microbial consortium. Archaea comprise a remarkably small minority in this community, given their crucial role in biogas production. Among the Archaea, the predominant order is the Methanomicrobiales and the most abundant species is Methanoculleus marisnigri. The Methanomicrobiales are hydrogenotrophic methanogens. Besides corroborating earlier findings on the significance of the contribution of the Clostridia to organic substrate decomposition, the results demonstrate the importance of the metabolism of hydrogen within the biogas producing microbial

  12. Consequential environmental life cycle assessment of a farm-scale biogas plant.

    Science.gov (United States)

    Van Stappen, Florence; Mathot, Michaël; Decruyenaere, Virginie; Loriers, Astrid; Delcour, Alice; Planchon, Viviane; Goffart, Jean-Pierre; Stilmant, Didier

    2016-06-15

    Producing biogas via anaerobic digestion is a promising technology for meeting European and regional goals on energy production from renewable sources. It offers interesting opportunities for the agricultural sector, allowing waste and by-products to be converted into bioenergy and bio-based materials. A consequential life cycle assessment (cLCA) was conducted to examine the consequences of the installation of a farm-scale biogas plant, taking account of assumptions about processes displaced by biogas plant co-products (power, heat and digestate) and the uses of the biogas plant feedstock prior to plant installation. Inventory data were collected on an existing farm-scale biogas plant. The plant inputs are maize cultivated for energy, solid cattle manure and various by-products from surrounding agro-food industries. Based on hypotheses about displaced electricity production (oil or gas) and the initial uses of the plant feedstock (animal feed, compost or incineration), six scenarios were analyzed and compared. Digested feedstock previously used in animal feed was replaced with other feed ingredients in equivalent feed diets, designed to take account of various nutritional parameters for bovine feeding. The displaced production of mineral fertilizers and field emissions due to the use of digestate as organic fertilizer was balanced against the avoided use of manure and compost. For all of the envisaged scenarios, the installation of the biogas plant led to reduced impacts on water depletion and aquatic ecotoxicity (thanks mainly to the displaced mineral fertilizer production). However, with the additional animal feed ingredients required to replace digested feedstock in the bovine diets, extra agricultural land was needed in all scenarios. Field emissions from the digestate used as organic fertilizer also had a significant impact on acidification and eutrophication. The choice of displaced marginal technologies has a huge influence on the results, as have the

  13. Biogas production from coumarin-rich plants--inhibition by coumarin and recovery by adaptation of the bacterial community.

    Science.gov (United States)

    Popp, Denny; Schrader, Steffi; Kleinsteuber, Sabine; Harms, Hauke; Sträuber, Heike

    2015-09-01

    Plants like sweet clover (Melilotus spp.) are not suitable as fodder for cattle because of harmful effects of the plant secondary metabolite coumarin. As an alternative usage, the applicability of coumarin-rich plants as substrates for biogas production was investigated. When coumarin was added to continuous fermentation processes codigesting grass silage and cow manure, it caused a strong inhibition noticeable as decrease of biogas production by 19% and increase of metabolite concentrations to an organic acids/alkalinity ratio higher than 0.3(gorganic acids) gCaCO3 (-1). Microbial communities of methanogenic archaea were dominated by the genera Methanosarcina (77%) and Methanoculleus (11%). This community composition was not influenced by coumarin addition. The bacterial community analysis unraveled a divergence caused by coumarin addition correlating with the anaerobic degradation of coumarin and the recovery of the biogas process. As a consequence, biogas production resumed similar to the coumarin-free control with a biogas yield of 0.34 LN g(volatile solids) (-1) and at initial metabolite concentrations (∼ 0.2 g(organic acids) gCaCO3 (-1)). Coumarin acts as inhibitor and as substrate during anaerobic digestion. Hence, coumarin-rich plants might be suitable for biogas production, but should only be used after adaptation of the microbial community to coumarin.

  14. Status and prospects of biogas energy use in Ukraine

    Energy Technology Data Exchange (ETDEWEB)

    Geletukha, G.; Kucheruk, P.; Matveev, Yu. [Scientific Engineering Center ' Biomass' , Kiev (Ukraine)

    2007-07-01

    The biogas technology in Ukraine is in the very beginning of the development. There are number of the barriers which hamper the development despite big biogas production potential in the country. The importance of the biogas activities in the country rises in connection with Kyoto protocol, which was ratified by Ukrainian Parliament. (orig.)

  15. Sustainable supply of biogas in Germany; Nachhaltige Biogasbereitstellung in Deutschland

    Energy Technology Data Exchange (ETDEWEB)

    Erler, Ronny [DBI - Gastechnologisches Institut gGmbH, Freiberg (Germany). Bereich Biogastechnologie; Ball, Thomas; Kiefer, Joachim [Technologiezentrum Wasser (Germany). Abt. Grundwasser und Boden; Dresen, Boris [Fraunhofer-Institut UMSICHT (Germany). Themenbereich Ressourcenmanagement; Koeppel, Wolfgang [DVGW-Forschungsstelle Karlsruhe (Germany). Gruppe Systeme und Netze

    2013-04-15

    The supply of certain substrates for biogas production is partly controversial discussed: 'Tank-or-plate' discussions, maize cultivation of the landscape and so forth. The research project 'Potential study for the sustainable production and supply of gaseous, renewable energy in Germany (Biogas Atlas)' examines the potentials of biogas production under consideration of various sustainability factors.

  16. Biogas production as affected by heavy metals in the anaerobic digestion of sludge

    Directory of Open Access Journals (Sweden)

    Hussein I. Abdel-Shafy

    2014-12-01

    The sewage sludge samples were separated from the sewage water of the pilot plant at the National Research Centre, TDC site. The effect of heavy metals on the biogas production of the anaerobic digester was studied. The inhibitory effect on the biogas production and toxic level of metals was determined in this study. The general ranking of heavy metal toxicity appears to be Hg > Cd > Cr (III. The present investigation reveals that heavy metals in addition to the anaerobic digester decreased the biogas production as an indication of efficiency of the process. A significant decrease in gas production and volatile organic matter removal was obtained. It was also noted that an accumulation of organic acid intermediates was obtained as a result of methanogenic bacterial inhibition. This accumulation was limited during the pulse feed of metals. This is due to the rapid poisoning of the active bacterial forms in the digester.

  17. Biogas final digestive byproduct applied to croplands as fertilizer contains high levels of steroid hormones.

    Science.gov (United States)

    Rodriguez-Navas, Carlos; Björklund, Erland; Halling-Sørensen, Bent; Hansen, Martin

    2013-09-01

    In this study we evaluate and demonstrate the occurrence of nine natural and one synthetic steroid hormone, including estrogens, androgens and progestagens in biogas final digestate byproduct (digestion liquid) commonly used as an agricultural fertilizer. We investigated two biogas sites that utilize different anaerobic digestion technologies (mesophilic and thermophilic) from swine manure and other organic wastes. Individual hormone concentration levels were observed up to 1478 ng g(-1) dry weight or 22.5 mg kg(-1) N with estrone and progesterone reaching highest concentration levels. Evaluation of the potential environmental burden through the application in agriculture was also assessed on the basis of predicted environmental concentrations. This study indicates that the biogas digestion process does not completely remove steroid hormones from livestock manure and use of final digestate byproduct on croplands contributes to the environmental emission of hormones.

  18. Anaerobic digestion of antibiotic residue in combination with hydrothermal pretreatment for biogas.

    Science.gov (United States)

    Zhang, Guangyi; Li, Chunxing; Ma, Dachao; Zhang, Zhikai; Xu, Guangwen

    2015-09-01

    Antibiotic residues are difficult to be treated or utilized because of their high water content and residual antibiotics. This article is devoted to investigating the possibility of biogas production from cephalosporin C residue (CPCAR), one typical type of antibiotic residues, via anaerobic digestion in combination with hydrothermal pretreatment (HTPT). The results from the bench-scale experiments showed that the combination of HTPT and anaerobic digestion can provide a viable way to convert CPCAR into biogas, and the biogas and methane yields reached 290 and 200 ml(g TS)(-1), respectively. This article further evaluated the proposed technology in terms of energy balance and technical feasibility based on theoretical calculation using the data from a pilot HTPT test. It was shown that the process is totally self-sufficient in energy and its main challenging problem of ammonia inhibition can be solved via ammonia stripping.

  19. Integration of energy, GHG and economic accounting to optimize biogas production based on co-digestion

    DEFF Research Database (Denmark)

    Fitamo, Temesgen Mathewos; Boldrin, Alessio; Baral, Khagendra Raj

    to be improved. The economic and environmental performances of the biogas chain must be optimised to ensure viable and sustainable solutions. Different types of feedstock materials will have to be considered, including Agricultural residues, agro-industrial residues and, to some extent, dedicated energy crops....... In this study, we integrated three types of analysis - energetic, GHG and economic – in order to optimise biogas production from the co-digestion of pig slurry (PS) and sugar beet pulp silage (SB). We found that the energy and GHG balances are improved when utilising SB as a co-substrate, mainly because...... of increased energy production. However, the profitability of biogas production is negatively affected when utilising SB, because of the increased costs involved in feedstock supply. The scale of the processing plant is neutral in terms of profitability when SB is added. The results indicate that medium...

  20. Ex-situ biogas upgrading and enhancement in different reactor systems.

    Science.gov (United States)

    Kougias, Panagiotis G; Treu, Laura; Benavente, Daniela Peñailillo; Boe, Kanokwan; Campanaro, Stefano; Angelidaki, Irini

    2017-02-01

    Biogas upgrading is envisioned as a key process for clean energy production. The current study evaluates the efficiency of different reactor configurations for ex-situ biogas upgrading and enhancement, in which externally provided hydrogen and carbon dioxide were biologically converted to methane by the action of hydrogenotrophic methanogens. The methane content in the output gas of the most efficient configuration was >98%, allowing its exploitation as substitute to natural gas. Additionally, use of digestate from biogas plants as a cost efficient method to provide all the necessary nutrients for microbial growth was successful. High-throughput 16S rRNA sequencing revealed that the microbial community was resided by novel phylotypes belonging to the uncultured order MBA08 and to Bacteroidales. Moreover, only hydrogenotrophic methanogens were identified belonging to Methanothermobacter and Methanoculleus genera. Methanothermobacter thermautotrophicus was the predominant methanogen in the biofilm formed on top of the diffuser surface in the bubble column reactor.

  1. Comparative biogas generation from fruit peels of fluted pumpkin (Telfairia occidentalis) and its optimization.

    Science.gov (United States)

    Dahunsi, S O; Oranusi, S; Owolabi, J B; Efeovbokhan, V E

    2016-12-01

    This study evaluated the potentials of fluted pumpkin fruit peels for biogas generation using three different pre-treatment methods (A, B, C) and the optimization of its process parameters. The physic-chemical characteristics of the substrates revealed it to be rich in nutrients and mineral elements needed by microorganisms. Gas chromatography analysis revealed the gas composition to be within the range of 58.5±2.5% Methane and 27±3% Carbon dioxide for all the three digestions. The study revealed that combination of three pre-treatment methods enhanced enormous biogas yield from the digested substrates as against the use of two methods and no pre-treatment experiment. Optimization of the generated biogas data revealed that RSM predicted higher gas yield than ANN, the latter gives higher accuracy and efficiency than the former. It is advocated that fluted pumpkin fruit peels be used for energy generation especially in the locations of its abundance.

  2. Household Biogas Digesters—A Review

    Directory of Open Access Journals (Sweden)

    Mohammad J. Taherzadeh

    2012-08-01

    Full Text Available This review is a summary of different aspects of the design and operation of small-scale, household, biogas digesters. It covers different digester designs and materials used for construction, important operating parameters such as pH, temperature, substrate, and loading rate, applications of the biogas, the government policies concerning the use of household digesters, and the social and environmental effects of the digesters. Biogas is a value-added product of anaerobic digestion of organic compounds. Biogas production depends on different factors including: pH, temperature, substrate, loading rate, hydraulic retention time (HRT, C/N ratio, and mixing. Household digesters are cheap, easy to handle, and reduce the amount of organic household waste. The size of these digesters varies between 1 and 150 m3. The common designs include fixed dome, floating drum, and plug flow type. Biogas and fertilizer obtained at the end of anaerobic digestion could be used for cooking, lighting, and electricity.

  3. Analysis of operational methane emissions from pressure relief valves from biogas storages of biogas plants.

    Science.gov (United States)

    Reinelt, Torsten; Liebetrau, Jan; Nelles, Michael

    2016-10-01

    The study presents the development of a method for the long term monitoring of methane emissions from pressure relief valves (PRV(1)) of biogas storages, which has been verified during test series at two PRVs of two agricultural biogas plants located in Germany. The determined methane emission factors are 0.12gCH4kWhel(-1) (0.06% CH4-loss, within 106days, 161 triggering events, winter season) from biogas plant A and 6.80/7.44gCH4kWhel(-1) (3.60/3.88% CH4-loss, within 66days, 452 triggering events, summer season) from biogas plant B. Besides the operational state of the biogas plant (e.g. malfunction of the combined heat and power unit), the mode of operation of the biogas flare, which can be manually or automatically operated as well as the atmospheric conditions (e.g. drop of the atmospheric pressure) can also affect the biogas emission from PRVs.

  4. Synthesis, antimicrobial evaluation and QSAR studies of propionic acid derivatives

    Directory of Open Access Journals (Sweden)

    Sanjiv Kumar

    2017-02-01

    Full Text Available A series of Schiff bases (1–17 and esters (18–24 of propionic acid was synthesized in appreciable yield and characterized by physicochemical as well as spectral means. The synthesized compounds were evaluated in vitro for their antimicrobial activity against Gram-positive bacteria Staphylococcus aureus, Bacillus subtilis, Gram negative bacterium Escherichia coli and fungal strains Candida albicans and Aspergillus niger by tube dilution method. Results of antimicrobial screening indicated that besides having good antibacterial activity, the synthesized compounds also displayed appreciable antifungal activity and compound 10 emerged as the most active antifungal agent (pMICca and pMICan = 1.93. The results of QSAR studies demonstrated that antibacterial, antifungal and overall antimicrobial activities of synthesized propionic acid derivatives were governed by the topological parameters, Kier’s alpha first order shape index (κα1 and valence first order molecular connectivity index (1χv.

  5. Formation of propionate and butyrate by the human colonic microbiota.

    Science.gov (United States)

    Louis, Petra; Flint, Harry J

    2017-01-01

    The human gut microbiota ferments dietary non-digestible carbohydrates into short-chain fatty acids (SCFA). These microbial products are utilized by the host and propionate and butyrate in particular exert a range of health-promoting functions. Here an overview of the metabolic pathways utilized by gut microbes to produce these two SCFA from dietary carbohydrates and from amino acids resulting from protein breakdown is provided. This overview emphasizes the important role played by cross-feeding of intermediary metabolites (in particular lactate, succinate and 1,2-propanediol) between different gut bacteria. The ecophysiology, including growth requirements and responses to environmental factors, of major propionate and butyrate producing bacteria are discussed in relation to dietary modulation of these metabolites. A detailed understanding of SCFA metabolism by the gut microbiota is necessary to underpin effective strategies to optimize SCFA supply to the host.

  6. Regulation and evolution of malonate and propionate catabolism in proteobacteria.

    Science.gov (United States)

    Suvorova, I A; Ravcheev, D A; Gelfand, M S

    2012-06-01

    Bacteria catabolize malonate via two pathways, encoded by the mdc and mat genes. In various bacteria, transcription of these genes is controlled by the GntR family transcription factors (TFs) MatR/MdcY and/or the LysR family transcription factor MdcR. Propionate is metabolized via the methylcitrate pathway, comprising enzymes encoded by the prp and acn genes. PrpR, the Fis family sigma 54-dependent transcription factor, is known to be a transcriptional activator of the prp genes. Here, we report a detailed comparative genomic analysis of malonate and propionate metabolism and its regulation in proteobacteria. We characterize genomic loci and gene regulation and identify binding motifs for four new TFs and also new regulon members, in particular, tripartite ATP-independent periplasmic (TRAP) transporters. We describe restructuring of the genomic loci and regulatory interactions during the evolution of proteobacteria.

  7. Towards the methane society? Use of hydrogen for upgrading biogas and synthetic methane production. Phase 1. Final report; Pae vej mod metansamfundet? - anvendelse af brint til opgradering af biogas og kunstig metanfremstilling. Fase 1. Slutrapport

    Energy Technology Data Exchange (ETDEWEB)

    Mortensen, Claus [Agro Business Park, Tjele (Denmark)

    2012-11-15

    Biogas consists of methane (CH4) and CO{sub 2}. If you react hydrogen produced with wind power with CO{sub 2} in sulfur purified biogas you get biogas upgraded to pure methane, ie. to natural gas quality. The pure methane can for example be sold via the natural gas grid or pressurized and sold for transport. The purpose of the present project is to contribute to the development of a concept and a technology that can store wind energy into the existing natural gas network through the upgrading of CO{sub 2} in biogas. Overall the project combines the technique and concept of electrolysis, biogas upgrading and natural gas network, so that: - electrolysis creates hydrogen and heat from wind turbines; - CO{sub 2} in biogas reacts with H2 from the electrolysis and produces CH4 and high-value steam by biogas reacting directly with H2 in a catalyst ; - The natural gas network is used as distribution and storage of the produced methane. The following main results are achieved in the first phase: - Design and construction of a pilot plant for the purification of biogas, which allows a Sabatier reaction later in the methanization process; - Sensitivity analyses have been carried out of methane prices, which have proven to be competitive compared to other upgrading technologies in the market; - A business plan is developed for a demonstration plant, which among other things will be used in phase 2: demonstration plant. The competitor analysis shows, among other things, a higher efficiency rate of the Danish technology than on the methanization plants being developed in Germany. (LN)

  8. An economic analysis of the electricity generation potential from biogas resources in the state of Indiana

    Science.gov (United States)

    Giraldo, Juan S.

    Anaerobic digestion is a process that is a common part of organic waste management systems and is used in concentrated animal feeding operations (CAFOs), wastewater treatment plants (WWTPs), and municipal solid waste (MSW) landfills. The process produces biogas, which contains methane, and it can be burned to generate electricity. Previous reports have indicated that based on the availability of feedstocks there is a large potential for biogas production and use for electricity generation in the state of Indiana. However, these reports varied in their consideration of important factors that affect the technical and economic feasibility of being able to develop the resources available. The goal of this thesis is to make a more targeted assessment of the electricity generation potential from biogas resources at CAFOs, WWTPs, and MSW landfills in Indiana. A capital budgeting model is used to estimate the net present value (NPV) of biogas electricity projects at facilities that are identified as technically suitable. A statewide estimate of the potential generation capacity is made by estimating the number of facilities that could profitably undertake a biogas electricity project. In addition this thesis explored the impact that different incentive policies would have on the economic viability of these projects. The results indicated that the electricity generation potential is much smaller when technical and economic factors are taken into account in addition to feedstock availability. In particular it was found that projects at hog farms are unlikely to be economically feasible in the present even when financial incentives are considered. In total, 47.94 MW of potential generating capacity is estimated from biogas production at CAFOs, WWTPs, and MSW landfills. Though results indicated that 37.10 MW of capacity are economically feasible under current operating conditions, sensitivity analysis reveals that these projects are very sensitive to capital cost assumptions

  9. Biogas production from anaerobic digestion of Spirulina maxima algal biomass

    Energy Technology Data Exchange (ETDEWEB)

    Rejean Samson; Anh LeDuy

    1982-08-01

    Spirulina maxima algal biomass could be used as the sole nutrient for the production of biogas by anaerobic digestion process. It is relatively simple to adapt the municipal sewage sludge to this new substrate. The adapted sludge is very stable. Under nonoptimal conditions, the methane yield and productivity obtained were 0.26 m/sup 3//(kg VS added day) and 0.26 m/sup 3//(kg VS added day), respectively, with the semicontinuous, daily fed, anaerobic digestion having loading rate of 0.97 kg VS/(m/sup 3/ day), retention time of 33 days and temperature of 30/sup 0/C.

  10. Biogas cleaning and upgrading with natural zeolites from tuffs.

    Science.gov (United States)

    Paolini, Valerio; Petracchini, Francesco; Guerriero, Ettore; Bencini, Alessandro; Drigo, Serena

    2016-01-01

    CO2 adsorption on synthetic zeolites has become a consolidated approach for biogas upgrading to biomethane. As an alternative to synthetic zeolites, tuff waste from building industry was investigated in this study: indeed, this material is available at a low price and contains a high fraction of natural zeolites. A selective adsorption of CO2 and H2S towards CH4 was confirmed, allowing to obtain a high-purity biomethane (CO2 zeolites from tuffs may successfully be used in a pressure/vacuum swing adsorption process.

  11. More value from food waste: Lactic acid and biogas recovery.

    Science.gov (United States)

    Kim, Mi-Sun; Na, Jeong-Geol; Lee, Mo-Kwon; Ryu, Hoyoung; Chang, Yong-Keun; Triolo, Jin M; Yun, Yeo-Myeong; Kim, Dong-Hoon

    2016-06-01

    Anaerobic digestion (AD) is one of the traditional technologies for treating organic solid wastes, but its economic benefit is sometimes questioned. To increase the economic feasibility of the treatment process, the aim of this study was to recover not only biogas from food waste but lactic acid (LA) as well. At first, LA fermentation of food waste (FW) was conducted using an indigenous mixed culture. During the operation, temperature was gradually increased from 35 °C to 55 °C, with the highest performance attained at 50 °C. At 50 °C and hydraulic retention time (HRT) of 1.0 d, LA concentration in the broth was 40 kg LA/m(3), corresponding to a yield of 1.6 mol LA/mol hexoseadded. Pyrosequencing results showed that Lactobacillus (97.6% of the total number of sequences) was the predominant species performing LA fermentation of FW. The fermented broth was then centrifuged and LA was extracted from the supernatant by the combined process of nanofiltration and water-splitting electrodialysis. The process could recover highly purified LA by removing 85% of mineral ions such as Na(+), K(+), Mg(2+), and Ca(2+) and 90% of residual carbohydrates. Meanwhile, the solid residue remained after centrifugation was further fermented to biogas by AD. At HRT 40 d (organic loading rate of 7 kg COD/m(3)/d), the highest volumetric biogas production rate of 3.5 m(3)/m(3)/d was achieved with a CH4 yield of 0.25 m(3) CH4/kg COD. The mass flow showed that 47 kg of LA and 54 m(3) of biogas could be recovered by the developed process from 1 ton of FW with COD removal efficiency of 70%. These products have a higher economic value 60 USD/ton FW compared to that of conventional AD (27 USD/ton FW).

  12. GIANT MISCANTHUS AS A SUBSTRATE FOR BIOGAS PRODUCTION

    Directory of Open Access Journals (Sweden)

    Joanna Kazimierowicz

    2015-09-01

    Full Text Available One unconventional source of energy, which may be applied in numerous production and municipal processes, is energy accumulated in plants. As a result of photosynthesis, solar energy is transformed into chemical energy accumulated in a form of carbohydrates in the plant biomass, which becomes the material that is more and more sought by power distribution companies and individual users. Currently, a lot of research on obtaining biogas from energy crops is conducted. Corn silage is used most often, however, there is a demand for alternative plants. The experiment described in this article was conducted with the use of giant Miscanthus (Miscanthus Giganteus.

  13. PENGARUH WAKTU KONTAK TERHADAP DAYA ADSORPSI KARBON AKTIF PADA PROSES PURIFIKASI CH4 DARI BIOGAS

    Directory of Open Access Journals (Sweden)

    Nani Harihastuti

    2016-11-01

    udara , maka dapat memicu efek gas rumah kaca dan pemanasan global karena biogas mengandung gas  CH4 dan CO2 yang sangat signifikan jumlahnya. Kata Kunci : waktu kontak, adsorpsi, karbon aktif, purifikasi,biogas ABSTRACT The use of biogas as a fuel directly use often problem occur that is awful odor, equipment fast burner and rusted metal, kitchen walls eroded and fire often turns off its self. This is due in a biogas other than methane (CH4 contained other gases, H2S, NH3, CO2, H2, CO and water vapor (H2O. Some gases which are impurities (H2S, NH3, CO2 and water vapor/H2O will lower the value of calories from biogas and detrimental to the environment and health. The purpose of this research is to eliminate impurities from gases biogas through a process of purification until obtained biogas which has higher heat value and enviromental friendly. The Methods undertaken by adsorption process using adsorbent activated carbon with variable time contacts, to obtain the optimum adsorption power of activated carbon toward gas impurities that are present in wastewater. The results of this research were obtained data removal/reduction of H2S gas impuritis achieve 99.99%, from 4200 ppm to be 0.22 ppm NH3 gas removal, reach the 12.7%, from 94,96 ppm be 0.65 ppm, removal of CO2 gas reached 77.48%, from levels 30, 77% to 6.93%, removal of water vapour (H2O reached 97,95%, from 0.584 mg/l be 0.012 mg/l.The increase in the concentration of methane (CH4 from 38.2% to 84.12%. Results of methane (CH4 as a result of this biogas is renewable energy sources that are safe and environmentally friendly and can be developed  in other Tofu IKM. The Time saturated activated carbon adsorbents obtained after 48 hours, the process of purification occur. Optimum active Carbon adsorption power towards each component gas impuritis is as follows against the H2S is 10.98 mg H2S/gram of activated carbon/minute, against the NH3 is 0.016 mg NH3/gram of activated carbon/minute, against CO2 is 0.090mg

  14. Methane-free biogas for direct feeding of solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Leone, P.; Lanzini, A.; Santarelli, M.; Cali, M. [Dipartimento di Energetica, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Sagnelli, F.; Boulanger, A.; Scaletta, A.; Zitella, P. [BioEnergy Lab, Environment Park S.p.A., Via Livorno 60, 10144 Turin (Italy)

    2010-01-01

    This paper deals with the experimental analysis of the performance and degradation issues of a Ni-based anode-supported solid oxide fuel cell fed by a methane-free biogas from dark-anaerobic digestion of wastes by pastry and fruit shops. The biogas is produced by means of an innovative process where the biomass is fermented with a pre-treated bacteria inoculum (Clostridia) able to completely inhibit the methanization step during the fermentation process and to produce a H{sub 2}/CO{sub 2} mixture instead of conventional CH{sub 4}/CO{sub 2} anaerobic digested gas (bio-methane). The proposed biogas production route leads to a biogas composition which avoids the need of introducing a reformer agent into or before the SOFC anode in order to reformate it. In order to analyse the complete behaviour of a SOFC with the bio-hydrogen fuel, an experimental session with several H{sub 2}/CO{sub 2} synthetic mixtures was performed on an anode-supported solid oxide fuel cell with a Ni-based anode. It was found that side reactions occur with such mixtures in the typical thermodynamic conditions of SOFCs (650-800 C), which have an effect especially at high currents, due to the shift to a mixture consisting of hydrogen, carbon monoxide, carbon dioxide and water. However, cells operated with acceptable performance and carbon deposits (typical of a traditional hydrocarbon-containing biogas) were avoided after 50 h of cell operation even at 650 C. Experiments were also performed with traditional bio-methane from anaerobic digestion with 60/40 vol% of composition. It was found that the cell performance dropped after few hours of operation due to the formation of carbon deposits. A short-term test with the real as-produced biogas was also successfully performed. The cell showed an acceptable power output (at 800 C, 0.35 W cm{sup -2} with biogas, versus 0.55 W cm{sup -2} with H{sub 2}) although a huge quantity of sulphur was present in the feeding fuel (hydrogen sulphide at 103 ppm and

  15. Methane-free biogas for direct feeding of solid oxide fuel cells

    Science.gov (United States)

    Leone, P.; Lanzini, A.; Santarelli, M.; Calì, M.; Sagnelli, F.; Boulanger, A.; Scaletta, A.; Zitella, P.

    This paper deals with the experimental analysis of the performance and degradation issues of a Ni-based anode-supported solid oxide fuel cell fed by a methane-free biogas from dark-anaerobic digestion of wastes by pastry and fruit shops. The biogas is produced by means of an innovative process where the biomass is fermented with a pre-treated bacteria inoculum (Clostridia) able to completely inhibit the methanization step during the fermentation process and to produce a H 2/CO 2 mixture instead of conventional CH 4/CO 2 anaerobic digested gas (bio-methane). The proposed biogas production route leads to a biogas composition which avoids the need of introducing a reformer agent into or before the SOFC anode in order to reformate it. In order to analyse the complete behaviour of a SOFC with the bio-hydrogen fuel, an experimental session with several H 2/CO 2 synthetic mixtures was performed on an anode-supported solid oxide fuel cell with a Ni-based anode. It was found that side reactions occur with such mixtures in the typical thermodynamic conditions of SOFCs (650-800 °C), which have an effect especially at high currents, due to the shift to a mixture consisting of hydrogen, carbon monoxide, carbon dioxide and water. However, cells operated with acceptable performance and carbon deposits (typical of a traditional hydrocarbon-containing biogas) were avoided after 50 h of cell operation even at 650 °C. Experiments were also performed with traditional bio-methane from anaerobic digestion with 60/40 vol% of composition. It was found that the cell performance dropped after few hours of operation due to the formation of carbon deposits. A short-term test with the real as-produced biogas was also successfully performed. The cell showed an acceptable power output (at 800 °C, 0.35 W cm -2 with biogas, versus 0.55 W cm -2 with H 2) although a huge quantity of sulphur was present in the feeding fuel (hydrogen sulphide at 103 ppm and mercaptans up to 10 ppm). Therefore, it

  16. Sustainable Biomass Resources for Biogas Production

    DEFF Research Database (Denmark)

    Meyer, Ane Katharina Paarup

    The aim of this thesis was to identify and map sustainable biomass resources, which can be utilised for biogas production with minimal negative impacts on the environment, nature and climate. Furthermore, the aim of this thesis was to assess the resource potential and feasibility of utilising...... such biomasses in the biogas sector. Sustainability in the use of biomass feedstock for energy production is of key importance for a stable future food and energy supply, and for the functionality of the Earths ecosystems. A range of biomass resources were assessed in respect to sustainability, availability...... from 39.3-66.9 Mtoe, depending on the availability of the residues. Grass from roadside verges and meadow habitats in Denmark represent two currently unutilised sources. If utilised in the Danish biogas sector, the results showed that the resources represent a net energy potential of 60,000 -122,000 GJ...

  17. Energetic and economic limitations of biogas utilization

    Energy Technology Data Exchange (ETDEWEB)

    Klimm, A.; Fleischhauer, W.J.

    1986-01-01

    Economic efficiency of biogas conversion plants can only be achieved from approximately 60% gas exploitation on. That presupposes use of gas in the farm itself beyond household needs, for instance to dry grain, or for supply to third parties. To secure the desired high exploitation level, it is important to remember, the animals must stay in their shelters also in summer, because this is the only way of safeguarding an appropriate supply of biomaterial. To use biogas in the household alone means also to be contented with a gas yield of little more than 40%. Biogas conversion plants for a stock of 50 to 100 large cattle must largely be erected by self-construction from, partly, used plant components. This is the only way of securing that the plant pays, for the purchase of a new plant requires some 40,000 marks additional capital.

  18. CONSIDERATIONS OVER A BIOGAS PLANT COMPONENTS

    Directory of Open Access Journals (Sweden)

    Mariana DUMITRU

    2014-04-01

    Full Text Available This paper starts from the conviction that one of the main environmental problems of today’s society is the continuously increasing production of organic wastes. In many countries, sustainable waste management have become major political priorities in order to reduce pollution and greenhouse gas emissions and to avoid, as much as possible, global climate changes. This problem becomes more and more present in our country too. Production of biogas through anaerobic digestion of animal manure and slurries as well as of a wide range of digestible organic wastes, converts these substrates into renewable energy and offers a natural fertiliser for agriculture. That is why we consider that biogas plants will be more and more used in the future. In this paper we show the different stages which must be operated in a biogas plant and the problems which can be met in each of them.

  19. Efficiency and biotechnological aspects of biogas production from microalgal substrates.

    Science.gov (United States)

    Klassen, Viktor; Blifernez-Klassen, Olga; Wobbe, Lutz; Schlüter, Andreas; Kruse, Olaf; Mussgnug, Jan H

    2016-09-20

    Photosynthetic organisms like plants and algae can harvest, convert, and store solar energy and thus represent readily available sources for renewable biofuels production on a domestic or industrial scale. Anaerobic digestion (AD) of the organic biomass yields biogas, containing methane and carbon dioxide as major constituents. Combustion of the biogas or purification of the energy-rich methane fraction can be applied to provide electricity or fuel. AD procedures have been applied for several decades with organic waste, animal products, or higher plants and more recently, utilization of photosynthetic algae as substrates have gained considerable research interest. To provide an overview of recent research efforts made to characterize the AD process of microalgal biomass, we present extended summaries of experimentally determined biochemical methane potentials (BMP), biomass pretreatment options and digestion strategies in this article. We conclude that cultivation options, biomass composition and time of harvesting, application of biomass pretreatment strategies, and parameters of the digestion process are all important factors, which can significantly affect the AD process efficiency. The transition from batch to continuous microalgal biomass digestion trials, accompanied by state-of-the-art analytical techniques, is now in demand to refine the assessments of the overall process feasibility.

  20. Metagenome changes in the mesophilic biogas-producing community during fermentation of the green alga Scenedesmus obliquus.

    Science.gov (United States)

    Wirth, Roland; Lakatos, Gergely; Böjti, Tamás; Maróti, Gergely; Bagi, Zoltán; Kis, Mihály; Kovács, Attila; Ács, Norbert; Rákhely, Gábor; Kovács, Kornél L

    2015-12-10

    A microalgal biomass offers a potential alternative to the maize silage commonly used in biogas technology. In this study, photoautotrophically grown Scenedesmus obliquus was used as biogas substrate. This microalga has a low C/N ratio of 8.5 relative to the optimum 20-30. A significant increase in the ammonium ion content was not observed. The methane content of the biogas generated from Sc. obliquus proved to be higher than that from maize silage, but the specific biogas yield was lower. Semi-continuous steady biogas production lasted for 2 months. Because of the thick cell wall of Sc. obliquus, the biomass-degrading microorganisms require additional time to digest its biomass. The methane concentration in the biogas was also high, in co-digestion (i.e., 52-56%) as in alga-fed anaerobic digestion (i.e., 55-62%). These results may be related to the relative predominance of the order Clostridiales in co-digestion and to the more balanced C/N ratio of the mixed algal-maize biomass. Predominance of the order Methanosarcinales was observed in the domain Archaea, which supported the diversity of metabolic pathways in the process.

  1. Renewable Hydrogen Potential from Biogas in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Saur, G.; Milbrandt, A.

    2014-07-01

    This analysis updates and expands upon previous biogas studies to include total potential and net availability of methane in raw biogas with respect to competing demands and includes a resource assessment of four sources of biogas: (1) wastewater treatment plants, including domestic and a new assessment of industrial sources; (2) landfills; (3) animal manure; and (4) a new assessment of industrial, institutional, and commercial sources. The results of the biogas resource assessment are used to estimate the potential production of renewable hydrogen from biogas as well as the fuel cell electric vehicles that the produced hydrogen might support.

  2. Energy-optimisation of biogas-fuelled CHP units; Energetische Optimierung von Biogas-BHKW's

    Energy Technology Data Exchange (ETDEWEB)

    Soltic, P.; Edenhauser, D.; Winkler, A.

    2008-07-15

    This illustrated final report for the Swiss Federal office of Energy (SFOE) reports on the energy-related optimisation of combined heat and power (CHP) units that are fuelled with non-processed biogas. Ways of increasing the efficiency of these units as far as the production of electricity is concerned are examined and commented on. Also, ways of using the heat generated by the CHP units to produce electricity using other, exergetic means are also described. Systems such as Stirling engines and existing and new thermo-electrical elements are discussed. The economic viability of the systems is also discussed.

  3. Propionate alters ion transport by rabbit distal colon

    Energy Technology Data Exchange (ETDEWEB)

    Horvath, P.J.; Weiser, M.M.; Duffey, M.E.

    1986-03-01

    The primary anions of the colon are short-chain fatty acids (SCFA) produced by intestinal microorganisms from endogenous secretions and dietary fiber. The effects of the SCFA propionate on ion transport by the epithelium of rabbit distal colon were studied on tissues stripped of underlying musculature and mounted in Ussing chambers. When tissues were bathed with NaCl Ringer's solutions at 37/sup 0/C (5% CO/sub 2/-21mM HCO/sub 3/, pH 7.4) replacement of 33mM Cl/sup -/ in both tissue baths by propionate reduced short-circuit current (Isc) from 86 to 35 ..mu..A/cm/sup 2/ and increased transepithelial conductance (G/sub t/) from 3.6 to 5.6mS/cm/sup 2/. Unidirectional /sup 14/C-propionate flux measurements revealed that this ion was secreted at a rate of 0.5..mu..Eq/cm/sup 2/hr. Intracellular measurements with potential and pH sensitive microelectrodes showed that propionate reduced intracellular pH (PH/sub i/) from 6.84 to 6.68 (P < 0.02), depolarized the apical membrane potential (phi/sub a/) by 4mV (P < 0.02) and decreased the membrane fractional resistance (f/sub R/) from .78 to .71 (P < 0.001). Addition of 0.1mM amiloride to the mucosal bath reversed Isc to -18..mu..A/cm/sup 2/, decreased G/sub t/ to 5.3mS/cm/sup 2/, hyperpolarized phi/sub a/ by 5mV (P < 0.05) and increased f/sub R/ to 0.85 (P < 0.001). Amiloride had no effect on pH/sub i/. These results show that propionate can be secreted by rabbit distal colon and that exposure to this SCFA causes cell acidification and electrophysiological changes consistent with H/sup +/ secretion.

  4. Macro algae as substrate for biogas production

    DEFF Research Database (Denmark)

    Møller, Henrik; Sarker, Shiplu; Gautam, Dhan Prasad

    Algae as a substrate for biogas is superior to other crops since it has a much higher yield of biomass per unit area and since algae grows in the seawater there will be no competition with food production on agricultural lands. So far, the progress in treating different groups of algae as a source...... of energy is promising. In this study 5 different algae types were tested for biogas potential and two algae were subsequent used for co-digestion with manure. Green seaweed, Ulva lactuca and brown seaweed Laminaria digitata was co-digested with cattle manure at mesophilic and thermophilic condition...

  5. The effect of electron acceptors on biogas production from tannery sludge of a Mexican wastewater plant

    Science.gov (United States)

    Effluents from the leather processing plants generally are discharged into rivers or are used to irrigate farmland. The biogas production from the digestion of sludge produced could be used as alternative sources for energy and power generation. A study was carried out to examine the effects of vari...

  6. TiO2/UV based photocatalytic pretreatment of wheat straw for biogas production

    DEFF Research Database (Denmark)

    Alvarado-Morales, Merlin; Tsapekos, Panagiotis; Awais, Muhammad

    2017-01-01

    The present study deals with the application of an advanced oxidation process combining UV irradiation in the presence of the photocatalyst titanium dioxide (TiO2), as an effective pretreatment method of wheat straw as means for increasing its biodegradability for increased biogas production...

  7. Effect of organic loading rate and feedstock composition on foaming in manure-based biogas reactors

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Boe, Kanokwan; Angelidaki, Irini

    2013-01-01

    Foaming is one of the major problems that occasionally occur in biogas plants, affecting negatively the overall digestion process. In the present study, the effect of organic loading rate (OLR) and feedstock composition on foaming was elucidated in continuous reactor experiments. By stepwise...

  8. Modelling socio-ecological systems with MAIA: A biogas infrastructure simulation

    NARCIS (Netherlands)

    Verhoog, Reinier; Ghorbani, Amineh; Dijkema, Gerard P.J.

    2016-01-01

    Similar to other renewable energy technologies, the development of a biogas infrastructure in the Netherlands is going through social, institutional and ecological evolution. To study this complex evolutionary process, we built a comprehensive agent-based model of this infrastructure. We used an age

  9. BIOLEACH: Coupled modeling of leachate and biogas production on solid waste landfills

    Science.gov (United States)

    Rodrigo-Clavero, Maria-Elena; Rodrigo-Ilarri, Javier

    2015-04-01

    One of the most important factors to address when performing the environmental impact assessment of urban solid waste landfills is to evaluate the leachate production. Leachate management (collection and treatment) is also one of the most relevant economical aspects to take into account during the landfill life. Leachate is formed as a solution of biological and chemical components during operational and post-operational phases on urban solid waste landfills as a combination of different processes that involve water gains and looses inside the solid waste mass. Infiltration of external water coming from precipitation is the most important component on this water balance. However, anaerobic waste decomposition and biogas formation processes play also a role on the balance as water-consuming processes. The production of leachate one biogas is therefore a coupled process. Biogas production models usually consider optimal conditions of water content on the solid waste mass. However, real conditions during the operational phase of the landfill may greatly differ from these optimal conditions. In this work, the first results obtained to predict both the leachate and the biogas production as a single coupled phenomenon on real solid waste landfills are shown. The model is applied on a synthetic case considering typical climatological conditions of Mediterranean catchments.

  10. Whole farm impact of anaerobic digestion and biogas use on a New York dairy farm

    Science.gov (United States)

    Anaerobic digestion of manure for biogas production is one of many options for reducing the carbon footprint of milk production. This process reduces greenhouse gas emissions but increases the potential nitrogen and phosphorus losses from the farm. An anaerobic digester component was added to the In...

  11. Metabolic and microbial community dynamics during the anaerobic digestion of maize silage in a two-phase process.

    Science.gov (United States)

    Sträuber, Heike; Lucas, Rico; Kleinsteuber, Sabine

    2016-01-01

    Two-phasic anaerobic digestion processes (hydrolysis/acidogenesis separated from acetogenesis/methanogenesis) can be used for biogas production on demand or a combined chemicals/bioenergy production. For an effective process control, detailed knowledge about the microbial catalysts and their correlation to process conditions is crucial. In this study, maize silage was digested in a two-phase process and interrelationships between process parameters and microbial communities were revealed. In the first-phase reactor, alternating metabolic periods were observed which emerged independently from the feeding frequency. During the L-period, up to 11.8 g L(-1) lactic acid was produced which significantly correlated to lactic acid bacteria of the genus Lactobacillus as the most abundant community members. During the alternating G-period, the production of volatile fatty acids (up to 5.3, 4.0 and 3.1 g L(-1) for propionic, n-butyric and n-caproic acid, respectively) dominated accompanied by a high gas production containing up to 28 % hydrogen. The relative abundance of various Clostridiales increased during this metabolic period. In the second-phase reactor, the metabolic fluctuations of the first phase were smoothed out resulting in a stable biogas production as well as stable bacterial and methanogenic communities. However, the biogas composition followed the metabolic dynamics of the first phase: the hydrogen content increased during the L-period whereas highest CH4/CO2 ratios (up to 2.8) were reached during the G-period. Aceticlastic Methanosaeta as well as hydrogenotrophic Methanoculleus and Methanobacteriaceae were identified as dominant methanogens. Consequently, a directed control of the first-phase stabilizing desired metabolic states can lead to an enhanced productivity regarding chemicals and bioenergy.

  12. Biogas production from crops and organic wastes. 2. Results of continuous digestion tests

    Energy Technology Data Exchange (ETDEWEB)

    Stewart, D.J.; Bogue, M.J.; Badger, D.M.

    1984-01-01

    Measurements were made of biogas yields from anaerobic digestion of various crops and organic wastes in 20-litre continuous digesters at 35 degrees C and at various loading rates and retention times. With a loading rate of 2.5 kg TS/cubic m digester/day and a retention time of 20 days, the mean volumes of biogas (in litres) and methane contents (% methane) obtained from each kilogram of TS added to the digester were as follows: banana (fruit plus stem) 938(53), potato waste (peelings plus rejects 820(50), meat processing waste (minced paunch contents, intestines, hearts, and lungs) 603(59), kale (whole plant) 545(53), pasture grass (ryegrass plus clover) 498(56), pressed lucerne (residue after extraction of protein) 487(63), oats 476(54), lucerne 460(56), poultry manure 439(57), maize 406(57), synthetic garbage (minced paper, food scraps, and garden rubbish) 383(48), ground barley straw 285(54), newspaper 243(52), and chopped ryegrass straw 177(62). Biogas yields per kilogram of total solids decreased as the loading rate increased. Continuous digestion was more stable than batch digestion, but biogas yields obtained by both methods were very similar. Highly digestible materials could be continuously digested, whereas they could not be batch digested. The high biogas yields obtained from digestion of banana and potato wastes resulted from almost complete destruction of volatile solids and represented respectively 99% and 95% conversion of the energy in the original material into methane. Biogas yields from continuous digestion were closely related to the proportion of soluble cell contents in the respective materials. 24 references.

  13. Nutrient removal and biogas upgrading by integrating freshwater algae cultivation with piggery anaerobic digestate liquid treatment.

    Science.gov (United States)

    Xu, Jie; Zhao, Yongjun; Zhao, Guohua; Zhang, Hui

    2015-08-01

    An integrated approach that combined freshwater microalgae Scenedesmus obliquus (FACHB-31) cultivation with piggery anaerobic digestate liquid treatment was investigated in this study. The characteristics of algal growth, biogas production, and nutrient removal were examined using photobioreactor bags (PBRbs) to cultivate S. obliquus (FACHB-31) in digestate with various digestate dilutions (the concentration levels of 3200, 2200, 1600, 1200, 800, and 400 mg L(-1) chemical oxygen demand (COD)) during 7-day period. The effects of the level of pollutants on nutrient removal efficiency and CO2 removal process were investigated to select the optimum system for effectively upgrade biogas and simultaneously reduce the nutrient content in digestate. The treatment performance displayed that average removal rates of COD, total nitrogen (TN), total phosphorous (TP), and CO2 were 61.58-75.29, 58.39-74.63, 70.09-88.79, and 54.26-73.81 %, respectively. All the strains grew well under any the dilution treatments. With increased initial nutrient concentration to a certain range, the CO4 content (v/v) of raw biogas increased. Differences in the biogas enrichment of S. obliquus (FACHB-31) in all treatments mainly resulted from variations in biomass productivity and CO2 uptake. Notably, the diluted digestate sample of 1600 mg L(-1) COD provided an optimal nutrient concentration for S. obliquus (FACHB-31) cultivation, where the advantageous nutrient and CO2 removals, as well as the highest productivities of biomass and biogas upgrading, were revealed. Results showed that microalgal biomass production offered real opportunities to address issues such as CO2 sequestration, wastewater treatment, and biogas production.

  14. Biogas production from energy crops and agriculture residues

    Energy Technology Data Exchange (ETDEWEB)

    Wang, G.

    2010-12-15

    In this thesis, the feasibility of utilizing energy crops (willow and miscanthus) and agriculture residues (wheat straw and corn stalker) in an anaerobic digestion process for biogas production was evaluated. Potential energy crops and agriculture residues were screened according to their suitability for biogas production. Moreover, pretreatment of these biomasses by using wet explosion method was studied and the effect of the wet explosion process was evaluated based on the increase of (a) sugar release and (b) methane potential when comparing the pretreated biomass and raw biomass. Ensiling of perennial crops was tested as a storage method and pretreatment method for enhancement of the biodegradability of the crops. The efficiency of the silage process was evaluated based on (a) the amount of biomass loss during storage and (b) the effect of the silage on methane potential. Co-digestion of raw and wet explosion pretreated energy crops and agriculture residues with swine manure at various volatile solids (VS) ratio between crop and manure was carried out by batch tests and continuous experiments. The efficiency of the co-digestion experiment was evaluated based on (a) the methane potential in term of ml CH4 produced per g of VS-added and (b) the amount of methane produced per m3 of reactor volume. (Author)

  15. Modulation of physicochemical and spectroscopic properties of l-serine and l-proline by propionate based food preservatives.

    Science.gov (United States)

    Banipal, Tarlok S; Kaur, Navalpreet; Kaur, Jaspreet; Komal; Banipal, Parampaul K

    2016-10-15

    To have an insight into the effect of preservatives on various ingredients of processed items, it is important to study their thermodynamic, transport and spectroscopic properties in aqueous solutions to elucidate various solute-co-solute interactions. The densities, viscosities and enthalpies of dilution of l-serine and l-proline have been determined in water and in aqueous solutions of sodium propionate and calcium propionate at different temperatures. The derived parameters elucidate the changes in taste quality and hydration number of l-serine and l-proline in the presence of the studied preservatives. Predominance of dehydration effect has been observed from calorimetry and changes in chemical shifts from nuclear magnetic resonance spectroscopy also support the above results.

  16. 高浓度沼液淹灌土水系统中氮、磷和有机物的动态变化%Dynamic Changes of Nitrogen, Phosphorus and Organic Matter in Soil-Water System in the Process of Biogas Slurry Flooding Treatment

    Institute of Scientific and Technical Information of China (English)

    李松林; 吕军; 张峰; 孙嗣旸; 邓欧平

    2011-01-01

    Through indoor-static-culture simulation experiment, we studied the dynamics of nitrogen, phosphorus and organic matter in the overlying water and the paddy soil during the flooding of high concentration biogas slurry from livestock wastewater. Results showed that the concentrations of TP and NH4+ -N in overlying water for the total biogas slurry irrigation treatment were decreased to below the allowable discharge standards in 30 days and 50 days, respectively. With the reducing of the concentration of biogas slurry irrigation, the time to meet the standards for the overlying water would be shortened. However, the concentrations of NO3--N in overlying water increased significantly after a complex process of denitrification and nitrification, and the concentration of NO3--N in the treatment of total biogas slurry irrigation increased by 44.9% after 100 days of slurry flooding. The decontamination in overlying water is mainly resulted from pollutant degradation and volatilization, and it is with only a small part remaining in the soil. Thus, in fallow period, biogas slurry irrigation in paddy field would not only digest and purify the high concentration of nitrogen, phosphorus and organic mater in the slurry, but also improve the soil nutrients properties without the risks for excessive accumulation of nitrogen, phosphorus and organic matter in paddy soil.%通过室内静置培养模拟试验,研究了高浓度沼液淹灌稻田土壤后上覆水和土壤中氮、磷和有机物的动态变化特征.结果表明,全沼液淹灌处理的上覆水中总磷和NH+4-N浓度分别在30 d和50 d内降低到允许排放标准以下;降低灌溉沼液的浓度,可缩短排放达标所需时间;但硝态氮浓度经过迅速下降后又会显著升高,全沼液灌溉处理100 d后,上覆水中NP-3-N的浓度比灌溉初期提高了44.9%.灌溉沼液中污染物浓度的降低,主要是降解和挥发作用的结果,只有少部分留在土壤中.因此,在水田休闲期进

  17. PENGARUH PENAMBAHAN EM4 (Effective Microorganism-4 PADA PEMBUATAN BIOGAS DARI ECENG GONDOK DAN RUMEN SAPI

    Directory of Open Access Journals (Sweden)

    Megawati Megawati

    2014-12-01

    Full Text Available Eceng gondok (Eichornia crassipes merupakan tanaman yang menjadi limbah perairan dan keberadaannya belum banyak dimanfaatkan. Kandungan selulosa, hemiselulosa, dan lignin di dalamnya dapat dimanfaatkan menjadi biogas melalui proses fermentasi. Penelitian ini mengkaji pengaruh EM4 (Effective Microorganism- 4 terhadap massa, nilai kalor, dan kecepatan pembentukan biogas dari eceng gondok. Percobaan dilakukan dalam anaerobic digester berukuran 4 liter, bahan baku yang digunakan adalah eceng gondok, rumen sapi, dan air dengan variabel penambahan EM4 sebesar 1% dan 0%. Fermentasi dilakukan secara batch dengan pengukuran gas (temperatur, tekanan, dan massa setiap 7 hari sekali sampai hari ke-35. Sebelum proses fermentasi, dilakukan pengujian terhadap rasio C/N campuran bahan baku. Pembakaran gas dilakukan untuk membuktikan gas yang didapat mengandung metana. Hasil Penelitian menunjukkan bahwa rasio C/N untuk variabel dengan penambahan EM4 1% sebesar 5,33 dan rasio C/N untuk variabel dengan penambahan EM4 0% sebesar 7. Jadi, penambahan EM4 dapat menurunkan rasio C/N. Sementara itu, hasil fermentasinya memperlihatkan bahwa EM4 memperkecil produksi biogas meskipun proses pembentukannya cepat. Massa total biogas yang didapat pada variabel EM4 1% sebesar 1,1 g dan variabel EM4 0% sebesar 1,55 g. Tekananbiogas mengalami fluktuasi (pada variabel EM4 1% sebesar 35,6 cmH2O, sedangkan pada variabel EM4 0% sebesar 40,6 cmH2O. Berdasarkan simulasi menggunakan chemical process simulator software, diketahui heating value biogas sebesar 39.180 kJ/kg. Water hyacinth (Eichornia crassipes is a plant that becomes waste and its existence has not been widely used. Content of cellulose, hemicellulose, and lignin in it can be converted into biogas through a process of fermentation. Study examines the effect of EM4 (Effective Microorganism-4 on the mass, heating value, and the rate of formation of biogas from water hyacinth. An experiments were performed in anaerobic

  18. Biogas. Plants, raw materials, products. 7. rev. ed.; Biogas. Pflanzen, Rohstoffe, Produkte

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-08-15

    In order to save fossil fuels and to stopp the climate change, a gradual shift to renewable energies is necessary. The federal government has aimed to a modern, environmental friendly, sustainable and secure energy supply by means of the expansion of renewable energies. Bioenergy plays a central role in the future. Biogas for renewable energies will play a special role. Biogas can be used for simultaneous production of electricity and heat, as a fuel and as a substitute for natural gas.

  19. Biogas generation in landfills. Equilibria, rates and yields

    Energy Technology Data Exchange (ETDEWEB)

    Aakesson, M.

    1997-05-01

    Landfilling in `cells` has become more common in recent years. Different waste streams are guided to different cells, among which the biocell is a landfill designed for biogas production. In this thesis, the dependence of biogas generation on waste composition was investigated. Six 8,000 m{sup 3} test cells, with contents ranging from mainly commercial waste to pure domestic waste and equipped with gas extraction systems and bottom plastic liners, were monitored for seven years. Great emphasis was given to the characterization of conversion processes and governing mechanism in the topics of bio-energetics, kinetics and capacities. A thermodynamic model, in which the oxidations of volatile fatty acids (VFA) (2biogas rates corresponded with low VFA levels. To explain the discrepancies between theoretical methane potentials and quantified yields (in this study found to be 150-200 and 40-70 Nm{sup 3}/dry tonne, respectively), the possible nutritional limitation was investigated. Pools and emissions of chemical oxygen demand, N, P and K were quantified. Biomass pools were estimated from methane yields, growth yield coefficients, and bacterial mineral contents. However, results from commercial waste test cells showed that the assimilation of P exceeded the refuse content, which suggests the turnover of microbial biomass and questions the notion of nutritional limitation. In sum, the results showed that the advantages of a reduced content of readily biodegradable material, achieved by guidance or pretreatment, encompass several aspects of the performance. 84 refs, 6 figs, 1 tab

  20. Enhanced propionic acid degradation (EPAD) system: proof of principle and feasibility.

    Science.gov (United States)

    Ma, Jingxing; Carballa, Marta; Van De Caveye, Pieter; Verstraete, Willy

    2009-07-01

    Full-scale anaerobic single-phase digesters can be confronted with process instabilities, which often result in the accumulation of propionic acid (HPr). As a solution, an enhanced propionic acid degradation (EPAD) system has been conceptually designed and experimentally tested at lab-scale. The system consisted of two components: a liquid/solid separator containing a microfiltration membrane and an up-flow anaerobic sludge bed (UASB) reactor specialized in HPr degradation. Two lab-scale continuous stirred tank reactors (CSTR) were used, i.e. the CSTR(control) and the CSTR(treatment). Firstly, the CSTRs were stressed by organic overloading to obtain high HPr levels. During the recovery period, besides stop feeding, no actions were taken to decrease the residual HPr concentration in the CSTR(control), while the CSTR(treatment) was connected to EPAD system in order to accelerate its recovery. By the end of the experiment, the CSTR(treatment) completely recovered from HPr accumulation, while no significant decrease of the HPr level in the CSTR(control) was observed. Based on the experimental results, the up-scaling of EPAD system was evaluated and it would only account for about 2% of the volume of the full-scale digester, thus suggesting that the implementation of a mobile EPAD system in full-scale practice should be feasible.

  1. Identification of Lactic Acid Bacteria and Propionic Acid Bacteria using FTIR Spectroscopy and Artificial Neural Networks

    Directory of Open Access Journals (Sweden)

    Beata Nalepa

    2012-01-01

    Full Text Available In the present study, lactic acid bacteria and propionic acid bacteria have been identified at the genus level with the use of artificial neural networks (ANNs and Fourier transform infrared spectroscopy (FTIR. Bacterial strains of the genera Lactobacillus, Lactococcus, Leuconostoc, Streptococcus and Propionibacterium were analyzed since they deliver health benefits and are routinely used in the food processing industry. The correctness of bacterial identification by ANNs and FTIR was evaluated at two stages. At first stage, ANNs were tested based on the spectra of 66 reference bacterial strains. At second stage, the evaluation involved 286 spectra of bacterial strains isolated from food products, deposited in our laboratory collection, and identified by genus-specific PCR. ANNs were developed based on the spectra and their first derivatives. The most satisfactory results were reported for the probabilistic neural network, which was built using a combination of W5W4W3 spectral ranges. This network correctly identified the genus of 95 % of the lactic acid bacteria and propionic acid bacteria strains analyzed.

  2. Sustainable protein from biogas. The perspective of susteine; Duurzaam eiwit uit biogas. Verkenning van het perspectief van susteine

    Energy Technology Data Exchange (ETDEWEB)

    Oosterhuis, N. [Easthouse Business Solutions, Rolde (Netherlands); Hooijer, H. [We-Do Interim Management and Consultancy, Culemborg (Netherlands)

    2007-12-15

    Production of single-cell protein (Susteine) on the basis of biogas (methane) from manure digestion might be an interesting option to reduce the amounts of manure from cattle, pigs and poultry and also might be an option for a sustainable production of high-value protein. An earlier made investigation leaded to the conclusion that many questions had to be answered to make a better picture of this opportunity for the Dutch agricultural society. In this study we investigated the feasibility of such a process and product. It is concluded that the product will be accepted in the market as long as the HACCP-requirements which are applicable in the feed production are fulfilled. The product as such, assuming that the quality is comparable to the product as was produced by Norferm, could get an attractive position especially in the application for piglets. A quantity of 10.000 t/y could easily be sold in this market segment. Of course the product first has to be registered, which needs additional studies. Technically we foresee no major hurdles in the production of Susteine on basis of methane from biogas. The biogas has to be purified to such a quality that SCP-production is feasible, however, technologies are available. It needs a further investigation to establish the quality requirements for such a process. The scale of operation of the biogas installation creates a financial-economic problem. In order to produce 10.000 t protein / year, a quantity of 30-35 million m{sup 3} of biogas is needed, for which 2 million ton of manure has to be digested. In case a centralized production of gas and protein is foreseen, the number of transport movements will be unacceptable. Besides the quantity of manure to be transported also approximately the same amount of digested material has to be transported. A unique opportunity in The Netherlands is the presence of a pipe network for natural gas. Such a network could serve as a transport system of locally produced, purified, biogas

  3. The influence of CO2 in biogas flammability limit and laminar burning velocity in spark ignited premix combustion at various pressures

    Science.gov (United States)

    Anggono, W.; Wardana, I. N. G.; Lawes, M.; Hughes, K. J.; Wahyudi, S.; Hamidi, N.; Hayakawa, A.

    2016-03-01

    Biogas is an alternative energy source that is sustainable and renewable containing more than 50% CH4 and its biggest impurity or inhibitor is CO2. Demands for replacing fossil fuels require an improved fundamental understanding of its combustion processes. Flammability limits and laminar burning velocities are important characteristics in these processes. Thus, this research focused on the effects of CO2 on biogas flammability limits and laminar burning velocities in spark ignited premixed combustion. Biogas was burned in a spark ignited spherical combustion bomb. Spherically expanding laminar premixed flames, freely propagating from spark ignition in initial, were continuously recorded by a high-speed digital camera. The combustion bomb was filled with biogas-air mixtures at various pressures, CO2 levels and equivalence ratios (ϕ) at ambient temperature. The results were also compared to those of the previous study into inhibitorless biogas (methane) at various pressures and equivalence ratios (ϕ). Either the flammable areas become narrower with increased percentages of carbon dioxide or the pressure become lower. In biogas with 50% CO2 content, there was no biogas flame propagation for any equivalence ratio at reduced pressure (0.5 atm). The results show that the laminar burning velocity at the same equivalence ratio declined in respect with the increased level of CO2. The laminar burning velocities were higher at the same equivalence ratio by reducing the initial pressure.

  4. Biogas - a new energy source saves fossil resources; Biogas - mit neuer Energie Ressourcen schonen

    Energy Technology Data Exchange (ETDEWEB)

    Thoss, C. (comp.)

    2001-07-01

    The new German Renewable Energy Sources Act (EEG) of 2000 made conditions for biogas more favourable - small wonder, as the German Biogas Association (Fachverband Biogas e.V.) co-operated with written expert opinions and many discussions with decision-makers. The subjects discussed at the 10th Biogas Conference reflect the current situation and will provide a basis for committee work in 2001. [German] Im Jahr 2000 haben sich die gesetzlichen Rahmenbedingungen fuer den Biogasbereich mit dem Inkrafttreten des erneuerbaren Energiegesetz (EEG) sehr positiv entwickelt. Der Fachverband Biogas e.V. hat mit schriftlichen Stellungnahmen und in vielen Gespraechen mit Entscheidungstraegern diese Bedingungen mitgestaltet. In Zukunft gibt es noch viele Aufgaben fuer eine effektive Interessenvertretung der Biogasbranche auf Laender- und Bundesebene. Die Themen, die auf der 10. Biogastagung diskutiert werden, spiegeln die Fragen wieder, die unter Experten derzeit intensiv diskutiert werden. Die Ergebnisse des Erfahrungsaustausches auf dieser Tagung werden die Grundlage fuer die Arbeit der Gremien im Fachverband Biogas im Jahr 2001 sein. Mit dem vorliegenden Tagungsband ist es gelungen, die Basis fuer die fachlichen Gespraeche waehrend und nach der Tagung schaffen. (orig.)

  5. Bio-Propane from glycerol for biogas addition

    Energy Technology Data Exchange (ETDEWEB)

    Brandin, Jan; Hulteberg, Christian; Liljegren Nilsson, Andreas (Biofuel-Solution AB, Malmoe (Sweden))

    2008-11-15

    hydrogen have to be externally produced which is the case of the propane produced. The production of ethane from acrolein was shown with a yield of 75%, while starting from glycerol yielded 65-70% ethane using the purposely developed catalyst. However, in light of this there are still work to be performed with optimizing catalyst compositions and process conditions to further improve the process yield. The economic feasibility and the glycerol supply side of the proposed process have been investigated as well within the scope of the report. After an initial overview of the glycerol supply, it is apparent that at least the addition of alkanes to biogas can be saturated by glycerol for the Swedish market situation at the moment and for a foreseeable future. The current domestic glycerol production would sustain the upgraded biogas industry for quite some time, if necessary. However, from a cost standpoint a lower grade glycerol should perhaps be considered. In the cost aspect, three different configurations have been compared. The three alternatives are ethane production, propane production with internal hydrogen supply and propane production with external hydrogen supply. The base case calculations are based on carburating the upgraded biogas, before introducing it to the natural gas grid, from a 24 GWh biogas production facility. This means that the production units supply an acceptable Wobbe index of the final upgraded biogas. The annual cost in table ES1 is the yearly cost of carburating the gas at a 24 GWh biogas site. From the base case, it is obvious that there are differences in glycerol consumption depending on what alternative is chosen. There are also investment cost differences. To further investigate the volatility of the prices, a blend of Monte Carlo techniques were used to generate multiple data sets. The conclusions from the simulations were that the ethane producing facility has a stronger dependence on the feedstock; it is hence more sensitive to changes

  6. Effect of ferrous chloride on biogas production and enzymatic activities during anaerobic fermentation of cow dung and Phragmites straw.

    Science.gov (United States)

    Zhang, Huayong; Tian, Yonglan; Wang, Lijun; Mi, Xueyue; Chai, Yang

    2016-06-01

    The effect of ferrous (added as FeCl2) on the anaerobic co-digestion of Phragmites straw and cow dung was studied by investigating the biogas properties, pH values, organic matter degradation (COD) and enzyme activities (cellulase, protease and dehydrogenase) at different stages of mesophilic fermentation. The results showed that Fe(2+) addition increased the cumulative biogas yields by 18.1 % by extending the peak period with high daily biogas yields. Meanwhile, the methane (CH4) contents in the Fe(2+) added groups were generally higher than the control group before the 15th day. The pH values were not significantly impacted by Fe(2+) concentrations during the fermentation process. The COD concentrations, cellulase, protease and dehydrogenase activities varied with the added Fe(2+) concentrations and the stages of the fermentation process. At the beginning stage of fermentation (4th day), Fe(2+) addition increased the biogas production by improving the cellulase and dehydrogenase activities which caused a decline in COD. At the peak stage of fermentation (8th day), Fe(2+) addition enhanced the cellulase and protease activities, and resulted in lower COD contents than the control group. When the biogas yields decreased again (13th day), the COD contents varied similar with the protease and dehydrogenase activities, whilst cellulase activities were not sensitive to Fe(2+) concentrations. At the end of fermentation (26th day), Fe(2+) addition decreased the cellulase activities, led to lower COD contents and finally resulted the lower biogas yields than the control group. Taking the whole fermentation process into account, the promoting effect of Fe(2+) addition on biogas yields was mainly attributed to the extension of the gas production peak stage and the improvement of cellulase activities.

  7. Opinions on biogas in organic farming

    DEFF Research Database (Denmark)

    Heiske, Stefan; Østergård, Hanne

    2011-01-01

    The application of biogas technologies in organic farming involves many considerations: Benefits like improved fertilizer supply and fossil fuel savings are opposed to concerns about economical risks and incompliance with organic principles. A questionnaire developed by Risø DTU gives an idea about...

  8. Biogas Purification up to Final Product

    Directory of Open Access Journals (Sweden)

    Yu. Losiuk

    2012-01-01

    Full Text Available The paper considers main technological methods for biogas purification from impurities that permit to increase energy value of the product and decrease its corrosion activity.  While evaluating economic efficiency due to introduction of the corresponding purification technology, in addition, it is necessary to take into account an ecological factor.

  9. Biogas for Javanese villages - a simple unit

    Energy Technology Data Exchange (ETDEWEB)

    Steward, J.; Richmond, B.

    1980-09-01

    Java is on the verge of suffering severe ecological damage due to deforestation as villagers attempt to meet a desperate need for food and firewood. In an attempt to alleviate this situation a biogas unit has been developed suited to local conditions with the potential for distribution to Javanese village farmers. The design, construction and operation of one such unit is described.

  10. Bio-gas production from alligator weeds

    Science.gov (United States)

    Latif, A.

    1976-01-01

    Laboratory experiments were conducted to study the effect of temperature, sample preparation, reducing agents, light intensity and pH of the media, on bio-gas and methane production from the microbial anaerobic decomposition of alligator weeds (Alternanthera philoxeroides. Efforts were also made for the isolation and characterization of the methanogenic bacteria.

  11. Comparative analysis of taxonomic, functional, and metabolic patterns of microbiomes from 14 full-scale biogas reactors by metagenomic sequencing and radioisotopic analysis

    DEFF Research Database (Denmark)

    Luo, Gang; Fotidis, Ioannis; Angelidaki, Irini

    2016-01-01

    Background Biogas production is a very complex process due to the high complexity in diversity and interactions of the microorganisms mediating it, and only limited and diffuse knowledge exists about the variation of taxonomic and functional patterns of microbiomes across different biogas reactors......, and their relationships with the metabolic patterns. The present study used metagenomic sequencing and radioisotopic analysis to assess the taxonomic, functional, and metabolic patterns of microbiomes from 14 full-scale biogas reactors operated under various conditions treating either sludge or manure. Results...

  12. Gas chromatographic determination of propionates as paranitrobenzyl ester in bakery products.

    Science.gov (United States)

    Takatsuki, K; Sakai, K

    1982-07-01

    A procedure was developed to determine propionates used as mold inhibitors and preservatives in bakery products. Propionates were extracted from the sample with water alkalinized by potassium carbonate. Water was evaporated, and the residue was reacted with paranitrobenzyl bromide in dimethyl-formamide-water (90 + 10) at room temperature to convert propionates to paranitrobenzyl ester, which was determined with a gas chromatograph equipped with a flame ionization detector. Bakery products, such as bread, sponge cake, cookies, and biscuits, were analyzed by this procedure. Recoveries from samples fortified with propionates ranged from 94 to 101%, with a standard deviation of 3.32. The concentrations determined were 50 to 2500 micrograms/g sample.

  13. Energy and substance conversion in biogas plants. Results of measurement investigations of agricultural biogas plants in the Rheinland; Energie- und Stoffumsetzung in Biogasanlagen. Ergebnisse messtechnischer Untersuchungen an landwirtschaftlichen Biogasanlagen im Rheinland

    Energy Technology Data Exchange (ETDEWEB)

    Besgen, S.

    2005-08-15

    The current data situation on biogas technology is not extensive and is mainly based on laboratory testing. This was the starting point for a pilot project and the dissertation at hand, where data was collected from four agricultural biogas plants during a period of two years. These four plants are equipped with extensive measurement technology and are run under mesophilic temperature conditions. They utilize manure, renewable primary products and organic waste products. The measurements carried out cover balancing, i.e. determining the gas-output, production and usage of energy, as well as process analysis. The latter investigates parameters which permit statements on stability of the fermentation process and on the substances of contents of the substrate. Input and output of the plants were quantified during the measurement periods. Input is defined as organic substance, output as the production of electricity and heat from burning biogas in block-type thermal power stations. Concerning the latter, the thermal and electrical efficiency factor was calculated, indicating also the respective fuel oil proportion. Furthermore, the process energy demand in form of electricity and heat for running the plants was analysed. It was possible to define the quality of the biogas produced as well as the quantity of individual substrates based on standard gas calculations. The measurement programme gained valuable data for the practical use of biogas plants. The results will be helpful for planning and designing these plants. (orig.)

  14. The Improvement of Carburater Efficiency Using Biogas-based Venturi

    Directory of Open Access Journals (Sweden)

    Lasmi Ni Ketut

    2016-01-01

    Full Text Available The elimination of the fossil fuel subsidy by the Indonesian government has caused an increase in fuel prices, and a solution to find a relatively cheap and environmentally friendly alternative energy is needed. Biogas is one of the sources of renewable energy that has a potential to be developed, especially in farming area where the abundant animal excrement is not yet optimally used and causes environmental problems. Addressing this issue, we have developed an innovation by making a biogas and air mixer instrument through venturi pipe, using the basic theory of fluid mechanism in order to increase the use of biogas as an electricity source. Usually, biogas-based electric generators use dual fuel system such as fossil fuel and biogas to perform combustion due to the low octane contained in the biogas. By replacing the readily available manufactured venturi with the modified venturi, optimal combustion can be reached with using only single fuel of biogas. The results of the experiments show that the biogas debit on carburetor increases from 13 to 439 watts consuming biogas fuel from 0.22 to 4.96 liter/minute, respectively. The amount of combusted biogas depends on the value of the load power. Within the scope of our results, the maximum voltage reached is about 211.13 – 211.76 volts which is feasible to use for 220 volts electrical appliances

  15. Microwave Spectra of Fluorinated Propionic Acids and Their Hydrates

    Science.gov (United States)

    Obenchain, Daniel A.; Grubbs, G. S. Grubbs, Ii; Novick, Stewart E.; Cooke, Stephen A.; Serrato, Agapito Serrato, Iii; Lin, Wei

    2013-06-01

    The microwave spectra of three fluorinated propionic acids, namely pentafluoropropionic acid, 2,2,3,3-tetrafluoropropionic acid, and 2,3,3,3-tetrafluoropropionic acid have been observed and assigned. The spectra of pentafluoropropionic acid and its monohydrate were reported in this meeting last year. The conformational analysis of 2,2,3,3-tetrafluoropropionic acid and 2,3,3,3-tetrafluoropropionic acid will be compared to that of pentafluoropropionic acid. The structures of the three monohydrates will be discussed in terms of hydrogen bonding.

  16. Biogas: a renewable energy? How to master its production and to select its way of valorization?; Biogaz: une energie renouvelable? Comment maitriser sa production et choisir son mode de valorisation?

    Energy Technology Data Exchange (ETDEWEB)

    Verchin, J.C. [ATEE, CLub Biogaz, 94 - Arcueil (France); Metivier, D. [Ministere de l' Economie, des Finances et de l' Industrie, 75 - Paris (France). Direction Generale de L' Energie et des Matieres Premieres; Dumas, B. [Solagro, 31 - Toulouse (France)] [and others

    2000-12-01

    This document brings together 13 testimonies of experts about the development and valorization of biogas (methane): 1 - presentation of the Biogas Club; 2 - status of biogas regulation: French policy, the available means for developing the valorization of biogas, European overview; 3 - overview of the different methanation processes: methanation of municipal wastes, the Danish experience, the processing of municipal waste using the DRANCO system, the KOMPOGAS Compact process for small methanation facilities; 4 - the valorization techniques: power generation, the suitability of thermal valorization with medium-size waste disposal centers, the injection of methane in the French natural gas network, biogas as a local source of renewable fuel in Germany, France and Netherlands. (J.S.)

  17. Kinetics of biogas production from fermentation broth of wild cocoyam codigested with cow paunch in batch mode

    Directory of Open Access Journals (Sweden)

    I.C.E. Umeghalu

    2015-03-01

    Full Text Available Mathematical models are useful in solving the stability problems often exhibited by anaerobic digestion process. Kinetics of batch anaerobic digestion of cocoyam waste mixed with cow paunch for biogas production in batch mode was studied for 30 days hydraulic retention time (HRT. Data from cumulative biogas yield obtained during the experimental stages was fitted to C-NIKBRAN mathematical model based on first order reaction which adequately predicted the kinetic behavior of the substrate’s anaerobic biodegradability. The validity of the applied model was also verified through application of the regression model (ReG (Least Square Method using Excel Version 2003 in predicting the trend of the experimental results. Comparative analysis of Figs. 7-10 show very close alignment of curves which precisely translated into significantly similar trend of data point’s distribution for experimental (ExD, derived model (MoD and regression model-predicted (ReG results of cumulative biogas yield. Also, critical analysis of data obtained from experiment and derived model show low deviations on the part of the model-predicted values relative to values obtained from the experiment. This necessitated the introduction of correction factor, to bring the model-predicted cumulative biogas yield to those of the corresponding experimental values. Deviational analysis from strongly indicates that cumulative biogas yield was most reliable based on the associated admissible deviation of the model-predicted cumulative biogas yield from the corresponding experimental values; 9.2% within the pH range. The values of cumulative biogas yield within the highlighted deviation indicates over 90% confidence level for the applied model and over 0.9 effective dependency coefficients (EDC of cumulative biogas yield on pH, chemical oxygen demand (COD, total viable count (TVC and total dissolved solids (TDS. Also, deviation of model-predicted cumulative biogas yield from

  18. BIOGAS PRODUCTION BY ENCAPSULATED METHANE-PRODUCING BACTERIA

    Directory of Open Access Journals (Sweden)

    Mohammad J. Taherzadeh

    2011-11-01

    Full Text Available Encapsulation of methane-producing bacteria was carried out with the objective of enhancing the rate of biogas production. Encapsulation with a one-step liquid-droplet-forming technique was employed for the natural membrane, resulting in spherical capsules with an average diameter and a membrane thickness of 4.3 and 0.2 mm, respectively. The capsules were made from alginate, using chitosan or Ca2+ as counter-ions, together with the addition of carboxymethylcellulose (CMC. A Durapore® membrane (hydrophilic PVDF with a pore size of 0.1 µm was used for synthetic encapsulating sachets having width and length dimensions 3×3 and 3×6 cm2 for holding the bacteria. During the digesting process, the dissolved substrates penetrated through the capsule membrane, and biogas inside the capsules was able to escape by diffusion. The results indicate encapsulation to be a promising method of digestion, with a high density of anaerobic bacteria. The method holds considerable potential for further development of membranes and their applications.

  19. Utilization of Biodiesel By-Products for Biogas Production

    Directory of Open Access Journals (Sweden)

    Nina Kolesárová

    2011-01-01

    Full Text Available This contribution reviews the possibility of using the by-products from biodiesel production as substrates for anaerobic digestion and production of biogas. The process of biodiesel production is predominantly carried out by catalyzed transesterification. Besides desired methylesters, this reaction provides also few other products, including crude glycerol, oil-pressed cakes, and washing water. Crude glycerol or g-phase is heavier separate liquid phase, composed mainly by glycerol. A couple of studies have demonstrated the possibility of biogas production, using g-phase as a single substrate, and it has also shown a great potential as a cosubstrate by anaerobic treatment of different types of organic waste or energy crops. Oil cakes or oil meals are solid residues obtained after oil extraction from the seeds. Another possible by-product is the washing water from raw biodiesel purification, which is an oily and soapy liquid. All of these materials have been suggested as feasible substrates for anaerobic degradation, although some issues and inhibitory factors have to be considered.

  20. Membrane-based removal of volatile methylsiloxanes from biogas

    Energy Technology Data Exchange (ETDEWEB)

    Ajhar, Marc

    2011-12-16

    This work investigates the removal of volatile methylsiloxanes (VMS) from biogas using dense, rubbery membranes. It consists of the following: a) thorough overview of already established and still developing siloxane removal technologies, b) detailed investigation of a viable sampling and analytical method, c) screening of different elastomers to identify siloxane-selective membrane materials, d) design of a suitable membrane structure, i.e. theoretical considerations about the thicknesses of the active separation layer and the porous support layer, e) assessment of the siloxane separation performance of a silicone membrane module using both synthetic gas under laboratory conditions and real landfill gas, f) comparison between the state-of-the-art technology (adsorption on activated carbon) and membrane-based processes. Suitable polymers for siloxane removal from biogas exist, however, they are not commercially available as membranes. Among the elastomers studied, Pebax registered 2533 is particularly promising. The use of a membrane made of this material could potentially become new state-of-the-art technology.